## 3 Results
### Volatile Aroma Compound Profiles
#### 3.1.3 Aldehydes
& MS & 1051 & 0.25 & 5.31 & 0.55 & 0.03 & 0.04 & 0.25 \\ hexanal (mg/kg) & S,LRLMS & 1070 & 0.24 b  & 0.29 b  & 0.27 b  & 0.44  & 0.53 a  & 0.20 b  \\ (Z)-2-pentanal & LRLMS & 1093 & 117.3 ab  & 7.43 c  & 16.92 a  & 8.09 b  & 5.29  & 5.70 c  \\ (E)-2-pentanal & S,LRLMS & 1115 & 52.30 a  & 48.87 a  & 34.67 a  & 39.40 b  & 24.74 b  & 42.38 b  \\ (E)-3-hexanal & LRLMS & 1125 & 57.10 a  & 42.81 b  & 43.82 a  & 23.48 c  & 35.30 b  \\ (Z)-3-hexanal (mg/kg) & LRLMS & 1130 & 1.36 a  & 0.40 d [FOOTNOTE:d]Footnote d:  
\begin{table}
\begin{tabular}{c c c c c c c c c} \hline \hline \multicolumn{1}{c}{**Compound**} & \multicolumn{1}{c}{**ID**} & \multicolumn{1}{c}{**LRI**} & \multicolumn{6}{c}{**Variety**} \\ \cline{3-10}  & & & **Buza** & **I. bijelica** & **Rosinjola** & **Oblica** & **Lastovka** & **Lecino** \\ \hline \multicolumn{1}{c}{(_Z_)-cienolone} & MS & 2002 & 0.20 b  & 0.13 c  & 0.19 b  & 0.04 d  & 0.03 d  & 0.28 a  \\ \multicolumn{1}{c}{1-(2,6,6-trimethyl-1-cyclohex-1-yf1)-1-penten-3-one} & MS & 2056 & 0.18 c  & 0.25 b  & 0.14 e  & 0.51 a  & 0.47 e  & 0.12 c  \\ \multicolumn{1}{c}{4+ethoxy-2’-4 hydroxyacetacetophenone} & MS & 2081 & 0.26 h  & 0.12 c  & 0.90 a  & 0.24 h  & 0.26 h  & 0.41 b  \\ \multicolumn{1}{c}{_alcohols_} & & & & & & & & & \\ \multicolumn{1}{c}{2-methyl-2-propanol} & & & & & & & & & \\ \multicolumn{1}{c}{1-methoxy-2-propanol (mg/kg)} & MS & 917 & 0.15 b  & 0.12 h  & 0.18 b  & 0.15 b  & 0.23 a  & 0.14 b  \\ \multicolumn{1}{c}{3-pentanol} & & & & & & & & & \\ \multicolumn{1}{c}{2-pentanol} & & & & & & & & & \\ \multicolumn{1}{c}{1-penten-3-olol} & & & & & & & & & \\ \multicolumn{1}{c}{1-penten-3-olol} & & & & & & & & & \\ \multicolumn{1}{c}{1-penten-3-ol} & & & & & & & & & \\ \multicolumn{1}{c}{3-methyl-1-butanol} & & & & & & & & & \\ \multicolumn{1}{c}{1-penten-1} & & & & & & & & & \\ \multicolumn{1}{c}{5-methyl-1-1} & & & & & & & & & \\ \multicolumn{1}{c}{1-penten-1} & & & & & & & & & \\ \multicolumn{1}{c}{5-methyl-1-1} & & & & & & & & & \\ \multicolumn{1}{c}{1-penten-1} & & & & & & & & & \\ \multicolumn{1}{c}{5-methyl-1-1} & & & & & & & & & \\ \multicolumn{1}{c}{1-penten-1} & & & & & & & & & \\ \multicolumn{1}{c}{5-methyl-1-1} & & & & & & & & & \\ \multicolumn{1}{c}{5-methyl-1-1} & & & & & & & & & \\ \multicolumn{1}{c}{5-methyl-1-1} & & & & & & & & & \\ \multicolumn{1}{c}{5-methyl-1-1} & & & & & & & & & \\ \multicolumn{1}{c}{5-methyl-1-1} & & & & & & & & & \\ \multicolumn{1}{c}{5-methyl-1-1} & & & & & & & & & \\ \multicolumn{1}{c}{5-methyl-1-1} & & & & & & & & & \\ \multicolumn{1}{c}{5-methyl-1-1} & & & & & & & & & \\ \multicolumn{1}{c}{5-methyl-1-1} & & & & & & & & & \\ \multicolumn{1}{c}{5-methyl-1-1} & & & & & & & & & \\ \multicolumn{1}{c}{5-methyl-1-1} & & & & & & & & & \\ \multicolumn{1}{c}{5-methyl-1-1} & & & & & & & & & \\ \multicolumn{1}{c}{5-methyl-1-1} & & & & & & & & & \\ \multicolumn{1}{c}{5-methyl-1-1-1} & & & & & & & & & \\ \multicolumn{1}{c}{5-methyl-1-1-1} & & & & & & & & & \\ \multicolumn{1}{c}{5-methyl-1-1-1} & & & & & & & & & \\ \multicolumn{1}{c}{5-methyl-1-1-1} & & & & & & & & & \\ \multicolumn{1}{c}{5-methyl-1-1-1} & & & & & & & & & & \\ \multicolumn{1}{c}{5-methyl-1-1-1-1} & & & & & & & & & \\ \multicolumn{1}{c}{5-methyl-1-  
\begin{table}
\begin{tabular}{c c c c c c c c c} \hline \hline \multicolumn{1}{c}{**Compound**} & \multicolumn{1}{c}{**ID**} & \multicolumn{1}{c}{**LRI**} & \multicolumn{6}{c}{**Variety**} \\ \cline{3-10}  & & & **Buza** & **I. biplica** & **Rosinjola** & **Oblica** & **Lastovka** & **Lecino** \\ \hline octanoic acid (mg/kg) & S,LRLMS & 2033 & 0.48\({}^{\text{b}}\) & 7.82\({}^{\text{a}}\) & 1.29\({}^{\text{b}}\) & 1.65\({}^{\text{b}}\) & 1.47\({}^{\text{b}}\) & 0.59\({}^{\text{b}}\) \\ sorbic acid & LRLMS & 2048 & 7.83\({}^{\text{b}}\) & 4.94\({}^{\text{b}}\) & 14.78\({}^{\text{a}}\) & 8.44\({}^{\text{b}}\) & 4.58\({}^{\text{b}}\) & 1.04\({}^{\text{c}}\) \\ nonanoic acid (mg/kg) & S,LRLMS & 2139 & 41.76\({}^{\text{b}}\) & 43.43\({}^{\text{a}}\) & 5.30\({}^{\text{b}}\) & 41.10\({}^{\text{b}}\) & 55.83\({}^{\text{b}}\) & 29.51\({}^{\text{b}}\) \\ decanoic acid (mg/kg) & S,LRLMS & 2244 & 0.07\({}^{\text{b}}\) & 0.43\({}^{\text{a}}\) & 0.14\({}^{\text{b}}\) & 0.02\({}^{\text{b}}\) & 0.06\({}^{\text{b}}\) & 0.06\({}^{\text{b}}\) \\ _esters_ & & & & & & & & \\ ally acetate & LRLMS & 805 & 53.61 & 58.55 & 69.96 & 43.21 & 30.69 & 37.81 \\ methyl acetate & LRLMS & 816 & 91.00\({}^{\text{b}}\) & 166.56\({}^{\text{a}}\) & 101.38\({}^{\text{b}}\) & 59.88\({}^{\text{b}}\) & 115.21\({}^{\text{ab}}\) & 81.99\({}^{\text{b}}\) \\
1,1,1-trimethethoxyethane & MS & 871 & 61.25\({}^{\text{b}}\) & 328.53\({}^{\text{a}}\) & 117.33\({}^{\text{a}}\) & 50.70\({}^{\text{b}}\) & 85.45\({}^{\text{b}}\) & 24.70\({}^{\text{b}}\) \\ ethyl3-methylbutanoate & LRLMS & 1042 & 0.90 & 0.64 & 0.55 & 0.70 & 0.70 & 0.51 \\ isomanyl acetate & S,LRLMS & 1114 & 4.91\({}^{\text{a}}\) & 4.92\({}^{\text{a}}\) & 2.26\({}^{\text{b}}\) & 2.88\({}^{\text{b}}\) & 3.19\({}^{\text{b}}\) & 1.69\({}^{\text{b}}\) \\ methyl3-methyl-2-butanoate & LRLMS & 1157 & 3.79 & 0.85 & 2.84 & 2.61 & 2.86 & 1.75 \\ methyl hexanoate & LRLMS & 1178 & 1.29 & 1.01 & 2.05 & 1.51 & 1.02 & 1.29 \\ ethyl hexanoate & S,LRLMS & 1228 & 0.06 & 0.23 & 0.31 & 0.50 & 0.35 & 0.12 \\ hexyl acetate & S,LRLMS & 1265 & 21.75\({}^{\text{b}}\) & 89.41\({}^{\text{a}}\) & 2.562\({}^{\text{b}}\) & 11.18\({}^{\text{b}}\) & 91.10\({}^{\text{a}}\) & 13.11\({}^{\text{b}}\) \\ (Z)-3-hexen-1-yard acetate (mg/kg) & S,LRLMS & 1309 & 0.27\({}^{\text{b}}\) & 0.62\({}^{\text{a}}\) & 0.20\({}^{\text{b}}\) & 0.05\({}^{\text{b}}\) & 0.26\({}^{\text{b}}\) & 0.09\({}^{\text{b}}\) \\ (Z)-2-hexen-1-yard acetate & LRLMS & 1326 & 1.52\({}^{\text{b}}\) & 4.02\({}^{\text{a}}\) & 1.44\({}^{\text{b}}\) & 0.91\({}^{\text{b}}\) & 1.75\({}^{\text{b}}\) & 0.91\({}^{\text{b}}\) \\ (E)-3-hexenly-bwenty 10000 & LRLMS & 1454 & 2.23\({}^{\text{b}}\) & 0.88\({}^{\text{c}}\) & 2.34\({}^{\text{a}}\) & 1.47\({}^{\text{b}}\) & 2.94\({}^{\text{a}}\) & 1.71\({}^{\text{ac}}\) \\
3-hydroxy-24-4-trimethymethyl2-methylpropionate & MS & 1854 & 0.37\({}^{\text{c}}\) & 0.16\({}^{\text{c}}\) & 4.94\({}^{\text{a}}\) & 1.06\({}^{\text{c}}\) & 0.95\({}^{\text{b}}\) & 1.54\({}^{\text{b}}\) \\ methyl cinnanoylglycionate & MS & 1960 & 3.44\({}^{\text{b}}\) & 3.34\({}^{\text{b}}\) & 6.22\({}^{\text{a}}\) & 2.62\({}^{\text{c}}\) & 2.25\({}^{\text{c}}\) & 3.33\({}^{\text{b}}\) \\ triacetin & LRLMS & 2049 & 1.09\({}^{\text{b}}\) & 0.41\({}^{\text{c}}\) & 5.19\({}^{\text{a}}\) & 1.44\({}^{\text{b}}\) & 1.02\({}^{\text{b}}\) & 1.77\({}^{\text{b}}\) \\
2-propyl pentanoate & MS & 2074 & 3.07\({}^{\text{b}}\) & 1.38\({}^{\text{c}}\) & 7.81\({}^{\text{a}}\) & 3.79\({}^{\text{b}}\) & 2.39\({}^{\text{b}}\) & 0.80\({}^{\text{d}}\) \\ methyl3-oxo-2-pentyl-cyclopentaneacetate & MS & 2257 & 7.59\({}^{\text{ab}}\) & 3.69\({}^{\text{c}}\) & 12.29\({}^{\text{a}}\) & 8.44\({}^{\text{ab}}\) & 8.06\({}^{\text{ab}}\) & 6.03\({}^{\text{bc}}\) \\ _benzoids_ & & & & & & & & \\ benzene & LRLMS & 926 & 9.83 & 14.67 & 14.44 & 12.05 & 11.62 & 10.10 \\ toluene (mg/kg) & LRLMS & 1027 & 0.10 & 0.17 & 0.07 & 0.40 & 0.17 & 0.10 \\ _m-x_ylene & LRLMS & 1122 & 22.55 & 19.69 & 15.30 & 105.52 & 26.14 & 17.65 \\ _p-x_ylene (mg/kg) & LRLMS & 1128 & 0.06 & 0.06 & 0.05 & 0.22 & 0.07 & 0.05 \\ o-xylene (mg/kg) & LRLMS & 1172 & 0.03 & 0.03 & 0.02 & 0.11 & 0.04 & 0.03 \\ _p-_ethylbutuene & LRLMS & 1213 & 16.73 & 17.37 & 11.75 & 56.70 & 14.44 & 11.29 \\
1,3,5-trimethlybenzene (mesitylene) & LRLMS & 1235 & 11.77 & 11.52 & 12.45 & 32.07 & 9.69 & 8.84 \\
2-ethylbutuene & LRLMS & 1251 & 7.00 & 6.28 & 5.39 & 18.11 & 5.10 & 4.07 \\ _p-_c_p_-c_p_c_ & S,LRLMS & 1262 & 1.51 & 1.57 & 2.15 & 2.87 & 31.68 & 4.46 \\ _m-_c_p_-c_ &  
\begin{table}
\begin{tabular}{c c c c c c c c c} \hline \hline \multicolumn{1}{c}{**Compound**} & \multicolumn{1}{c}{**ID**} & \multicolumn{6}{c}{**LRI**} & \multicolumn{6}{c}{**Variety**} \\ \cline{5-10}  & & & **Buza** & **L. bijelica** & **Rosinjola** & **Oblica** & **Lastovka** & **Leccino** \\ \hline
5-ethyl-2(5H)-furanone (mg/kg) & LRIMS & 1733 & 0.19 \({}^{\rm a}\) & 0.08 \({}^{\rm b}\) & 0.19 \({}^{\rm a}\) &