## 3 Results
### Year 2021 Optimization of the Irrigation Water Volume for Each Clone
#### 3.2.4 Berry and Must Quality Parameters and Oenological Potential
\begin{table}
\begin{tabular}{c c c c c c c c c c c} \hline \hline \multicolumn{1}{c}{\multirow{2}{*}{**Clone**}} & \multicolumn{4}{c}{**Year 2021**} \\  & \multicolumn{1}{c}{**Berry**} & \multirow{2}{*}{**TSS**} & \multirow{2}{*}{**pH**} & \multicolumn{2}{c}{**Total**} & \multirow{2}{*}{**IM**} & \multicolumn{2}{c}{**Tartaric**} & \multicolumn{2}{c}{**Malic**} & \multirow{2}{*}{**Tartaric/Malic\({}_{\text{Juice}}\)**} & \multicolumn{2}{c}{**YAN**} \\  & & & & & & & & & & & & **(mg L\({}^{-1}\))** \\ \hline
4 & 1.57b & 22.4 cd & 3.95 & 3.36 & 6.5 & 2.77 ab & 2.18 abc & 1.22a & 55.5 & 70.6 bc & 112a \\
94 & 1.53b & 20.8a & 4.16 & 3.30 & 6.4 & 2.66a & 1.96 abc & 1.39 ab & 58.9 & 70.5e & 115a \\
188 & 1.46b & 21.2 ab & 4.07 & 3.21 & 6.5 & 3.12b & 2.22 bc & 1.38 ab & 58.3 & 70.2 bc & 135a \\
276 & 1.53b & 22.6d & 4.01 & 3.05 & 7.4 & 2.68a & 1.96 abc & 1.41 ab & 54.0 & 68.1a & 90a \\
360 & 1.09a & 22.1 cd & 4.19 & 3.26 & 6.9 & 3.63c & 2.36c & 1.61b & 52.4 & 67.8a & 196b \\
372 & 1.43b & 22.0 abc & 4.09 & 3.23 & 7.0 & 2.95 ab & 1.78a & 1.58b & 56.9 & 69.4 abc & 110a \\
373 & 1.57b & 22.2 cd & 4.13 & 3.26 & 6.9 & 2.99 ab & 1.82 ab & 1.59b & 57.2 & 69.0 ab & 120a \\
**Treat.** & & & & & & & & & & & \\ Control & 1.53 & 21.7 & 4.09 & 3.28 & 6.6 & 2.95 & 2.09 & 1.42 & 57.1 & 70.0 & 123 \\ Stress & 1.39 & 22.1 & 4.08 & 3.20 & 7.0 & 3.00 & 1.98 & 1.48 & 54.3 & 68.8 & 128 \\
**Clone \(\times\) Treat.** & & & & & & & & & & & \\
4 & Control & 1.62 & 23.1 & 3.91 & 3.29 & 6.7 & 2.91 & 2.35 cd & 1.26 & 56.8 ab & 70.2 cde & 110 \\ Stress & 1.52 & 21.7 & 4.00 & 3.43 & 6.4 & 2.63 & 2.00 abcd & 1.18 & 54.2 ab & 71.0 de & 114 \\
94 & Control & 1.63 & 20.8 & 4.20 & 3.39 & 6.2 & 2.73 & 2.07 abd & 1.29 & 58.7 ab & 70.7 de & 107 \\ Stress & 1.44 & 20.7 & 4.12 & 3.21 & 6.6 & 2.58 & 1.84 abc & 1.49 & 99.0b & 71.2e & 122 \\
188 & Control & 1.52 & 21.4 & 4.10 & 3.41 & 6.0 & 3.02 & 2.286 cd & 1.25 & 53.3 ab & 70.4 de & 114 \\ Stress & 1.40 & 21.0 & 4.03 & 3.02 & 7.1 & 3.22 & 2.17 dad & 1.44 & 57.2 ab & 70.0 bcde & 154 \\
276 & Control & 1.55 & 21.4 & 4.12 & 3.04 & 6.9 & 2.75 & 2.06 abcd & 1.42 & 60.8b & 70.8 de & 105 \\
360 & Control & 1.26 & 22.8 & 4.11 & 3.23 & 7.2 & 3.49 & 1.97 abd & 1.80 & 55.3 ab & 67.4 ab & 196 \\ Stress & 0.93 & 21.5 & 4.27 & 3.30 & 6.5 & 3.77 & 2.75d & 1.42 & 49.5a & 68.1 abe & 196 \\
372 & Control & 1.60 & 21.2 & 4.10 & 3.28 & 6.6 & 2.67 & 2.00 abcd & 1.46 & 59.0 ab & 71.7e & 108 \\ Stress & 1.27 & 22.8 & 4.09 & 3.17 & 7.3 & 3.24 & 1.56a & 1.70 & 54.8 ab & 67.7 ab & 113 \\
373 & Control & 1.50 & 21.4 & 4.10 & 3.31 & 6.5 & 3.06 & 1.92 abad & 1.46 & 58.9 ab & 69.7 bede & 118 \\ Stress & 1.64 & 23.0 & 4.15 & 3.21 & 7.3 & 2.93 & 1.71 ab & 1.72 & 58.5 ab & 68.3 abcd & 122 \\ \hline \multicolumn{1}{c}{**ANOVA**} & \multicolumn{1}{c}{} & \multicolumn{1}{c}{} & \multicolumn{1}{c}{} & \multicolumn{1}{c}{} & \multicolumn{1}{c}{} & \multicolumn{1}{c}{} & \multicolumn{1}{c}{} & \multicolumn{1}{c}{} & \multicolumn{1}{c}{} & \multicolumn{1}{c}{} & \multicolumn{1}{c}{} \\ Clone & *** & ** & ns & ns & ns & *** & ** & ** & ns & *** & ** \\ Treatment & ** & ns & ns & ns & ns & ns & ns & ** & *** & ns \\ Interaction & ns & ns & ns & ns & ns & ** & ns & ** & ns & \\ \hline \hline \end{tabular}
\end{table} 
Table 10: Average annual values of berry technological quality at harvest for each clone, irrigation treatment, and the interaction (clone \(\times\) irrigation treatment) during year 2021. TSS (total soluble solids, \({}^{\text{}}\)Brix), titratable acidity (g tartaric acid L\({}^{-1}\)), IM (maturity index, \({}^{\circ}\)Brix/ Titratable acidity), tartaric acid (g L\({}^{-1}\)), and malic acid (g L\({}^{-1}\)), YAN (yeast available nitrogen). 4) compared to their controls. In contrast, WS significantly decreased Cu (372) and Zn (372, and 188) (Table S4). The lowest vigor/productive clone, 360, also had the highest concentration of polyphenols, tannins, and TPI (Table 11). Indeed, seed maturity index was also the highest in this clone. In clone 276, the concentration of total and extractable anthocyanins was the highest this year.