## 3 Results
### UPLC-MS Chemical Composition  
UPLC analyses allowed the identification of 47 non-volatile compounds listed in Table 2. Among these, \(\delta\)-9-cis-tetrahydrocannabinol, (-)- was the major detected compound in Green Poison (27.4%), in Banana Hybrid (25.4%), in Gorilla CBD (51.9%) and in Candy BUD (26.7%) while its content reached 5.0% value in V1 CBD cultivar where the principal component was ananolignan J (14.1%). \begin{table}
\begin{tabular}{l c c c c c c c} \hline
**No.** & **COMPONENT 1** & **LRI 2** & **LRI 3** & **Green** & **V1 CBD** & **Banana** & **Gorilla** & **Candy** \\  & & & & & **Poison** & **Hybrid** & **CBD** & **BUD** \\ \hline
1 & \(\alpha\)-pinene & 941 & 943 & 0.4 \(\pm\) 0.01 & 0.7 \(\pm\) 0.02 & 13.7 \(\pm\) 0.05 & 19.7 \(\pm\) 0.04 & 0.3 \(\pm\) 0.02 \\
2 & camphene & 945 & 944 & - & - & 0.2 \(\pm\) 0.02 & 0.3 \(\pm\) 0.01 & - \\
3 & \(\beta\)-myrcene & 990 & 987 & 5.9 \(\pm\) 0.01 & 29.6 \(\pm\) 0.02 & 25.0 \(\pm\) 0.07 & 40.8 \(\pm\) 0.11 & 15.9 \(\pm\) 0.02 \\
4 & limonene & 1031 & 1023 & 3.5 \(\pm\) 0.01 & 6.7 \(\pm\) 0.02 & 3.1 \(\pm\) 0.04 & 6.4 \(\pm\) 0.02 & 3.6 \(\pm\) 0.02 \\
5 & \(\gamma\)-terpinene & 1068 & 1065 & - & - & - & 0.2 \(\pm\) 0.02 & - \\
6 & fenchol & 1105 & 1100 & 0.1 \(\pm\) 0.01 & 0.3 \(\pm\) 0.01 & 0.2 \(\pm\) 0.02 & 0.5 \(\pm\) 0.02 & 0.1 \(\pm\) 0.02 \\
7 & \(\alpha\)-terpineol & 1186 & 1183 & 0.1 \(\pm\) 0.01 & 0.3 \(\pm\) 0.02 & 0.2 \(\pm\) 0.02 & 0.3 \(\pm\) 0.02 & 0.2 \(\pm\) 0.02 \\
8 & \(\beta\)-citronellol & 1216 & 1212 & - & - & - & 0.2 \(\pm\) 0.02 & - \\
9 & y-langene & 1374 & 1376 & 0.2 \(\pm\) 0.00 & - & 0.2 \(\pm\) 0.02 & - & 0.1 \(\pm\) 0.02 \\
10 & \(\alpha\)-santalene & 1418 & 1420 & - & - & 0.1 \(\pm\) 0.02 & - & 0.9 \(\pm\) 0.02 \\
11 & \(\alpha\)-bergamotene & 1433 & 1430 & - & - & 0.1 \(\pm\) 0.01 & - & 0.9 \(\pm\) 0.02 \\
12 & \(\beta\)-caryophyllene & 1447 & 1440 & 34.5 \(\pm\) 0.08 & 27.6 \(\pm\) 0.04 & 28.9 \(\pm\) 0.05 & 9.1 \(\pm\) 0.03 & 21.6 \(\pm\) 0.04 \\
13 & trans-\(\beta\)-farnesene & 1449 & 1441 & - & - & 2.4 \(\pm\) 0.03 & 4.7 \(\pm\) 0.03 & 5.3 \(\pm\) 0.03 \\
14 & humulene & 1475 & 1473 & 11.4 \(\pm\) 0.02 & 6.7 \(\pm\) 0.03 & 9.5 \(\pm\) 0.02 & 3.1 \(\pm\) 0.02 & 6.0 \(\pm\) 0.03 \\
15 & \(\gamma\)-gurjunene & 1481 & 1479 & 0.4 \(\pm\) 0.01 & 0.4 \(\pm\) 0.02 & - & 0.6 \(\pm\) 0.02 & 1.1 \(\pm\) 0.02 \\
16 & alloaromadendrene & 1484 & 1483 & - & - & - & 0.3 \(\pm\) 0.02 & - \\
17 & \(\beta\)-eudesmene & 1488 & 1486 & - & - & 1.2 \(\pm\) 0.02 & - & - \\
20 & \(\alpha\)-selinene & 1490 & 1489 & 2.5 \(\pm\) 0.01 & - & - & - & - \\
21 & \(\alpha\)-farnesene & 1493 & 1494 & - & 1.0 \(\pm\) 0.01 & 2.4 \(\pm\) 0.02 & 0.8 \(\pm\) 0.03 & 2.7 \(\pm\) 0.02 \\
22 & cis-\(\alpha\)-bisabolene & 1498 & 1496 & 6.8 \(\pm\) 0.02 & 5.9 \(\pm\) 0.02 & - & 0.7 \(\pm\) 0.03 & 2.9 \(\pm\) 0.02 \\
23 & \(\beta\)-bisabolene & 1504 & 1501 & 3.4 \(\pm\) 0.01 & 4.9 \(\pm\) 0.08 & 2.8 \(\pm\) 0.02 & - & 2.5 \(\pm\) 0.01 \\
24 & \(\delta\)-guaiene & 1510 & 1508 & - & - & 6.4 \(\pm\) 0.03 & - & 1.8 \(\pm\) 0.02 \\
25 & \(\delta\)-selinene & 1512 & 1509 & 0.6 \(\pm\) 0.01 & 0.1 \(\pm\) 0.02 & 0.3 \(\pm\) 0.02 & 0.6 \(\pm\) 0.02 & 0.2 \(\pm\) 0.02 \\
26 & \(\delta\)-cadinene & 1533 & 1530 & 2.3 \(\pm\) 0.03 & 0.8 \(\pm\) 0.01 & - & - & - \\
28 & selina-3,7(11)-diene & 1537 & 1540 & 17.1 \(\pm\) 0.06 & 12.2 \(\pm\) 0.02 & 0.7 \(\pm\) 0.02 & 8.2 \(\pm\) 0.05 & 16.7 \(\pm\) 0.02 \\
29 & guaia-3,9-diene & 1560 & 1556 & 9.3 \(\pm\) 0.01 & - & - & - & 10.2 \(\pm\) 0.02 \\
30 & \(\gamma\)-eudesmol & 1633 & 1630 & - & 0.4 \(\pm\) 0.01 & - & 1.6 \(\pm\) 0.02 & - \\
31 & guaia-1(10),11-diene & 1760 & * & 1.5 \(\pm\) 0.02 & 2.4 \(\pm\) 0.02 & - & 1.5 \(\pm\) 0.03 & 2.6 \(\pm\) 0.02 \\  & & & 100.0 & 100.0 & 97.4 & 99.6 & 95.6 \\  & & & 10.2 & 37.6 & 42.8 & 68.4 & 22.0 \\  & & Sesquiterpenoids & & 89.8 & 62.4 & 54.6 & 31.2 & 73.6 \\ \hline \end{tabular}  
* the components are reported according to their elution order on apolar column; 2 Linear Retention Indices measured on apolar column; 3 Linear Retention indices from literature;
* Not detected.  
\end{table}