## 2 Results and Discussion
### Total Phenolics Content (TPC) and Antioxidant Activity (AA)
\begin{table}
\begin{tabular}{c c c c c c c c c} \hline \hline \multirow{2}{*}{**Compound**} & \multirow{2}{*}{**RI 1**} & \multicolumn{6}{c}{**Normalized Peak Area \%**} \\ \cline{2-9}  & & **0 h** & \multicolumn{2}{c}{**24 h**} & \multicolumn{2}{c}{**First Week**} & \multicolumn{2}{c}{**Fourth Week**} & \multicolumn{2}{c}{**Identification 2**} \\ \cline{2-9}  & & & **FP** & **NFP** & **FP** & **NFP** & **FP** & **NFP** \\ \hline
**Alcohols** & & & & & & & & \\ Ethyl alcohol & 467 & \(0.4\pm 0.1\) & \(15.5\pm 0.5^{\circ}\) & \(7.6\pm 0.3^{\circ}\) & \(32.1\pm 2.3^{\circ}\) & \(19\pm 1.8^{\circ}\) & \(40.4\pm 1.5^{\circ}\) & \(235.5\pm 0.8^{\circ}\) & MS, RI, ref \\
1-Butanol & 633 & \(3.9\pm 0.1\) & \(5.6\pm 0.1^{\circ}\) & \(3.3\pm 0.2^{\circ}\) & \(11.0\pm 0.3^{\circ}\) & \(30.0\pm 0.1^{\circ}\) & \(3.0\pm 0.1^{\circ}\) & \(8.5\pm 0.1^{\circ}\) & MS, RI, ref \\
3-Methyl-1-butanol & 726 & \(2.8\pm 0.4\) & \(2.5\pm 0.3^{\circ}\) & \(<\)0.1 & \(3.6\pm 0.5^{\circ}\) & nd & \(2.4\pm 0.1^{\circ}\) & nd & MS, RI, ref \\
2-Methyl-1-butanol & 728 & \(0.4\pm 0.1\) & \(<\)0.1 & \(0.6\pm 0.1^{\circ}\) & \(2.4\pm 0.3^{\circ}\) & \(0.3\pm 0.1^{\circ}\) & \(0.3\pm 0.1^{\circ}\) & MS, RI, ref \\
3-Methyl-3-buten-1-ol & 724 & \(1.2\pm 0.1\) & \(5.3\pm 0.3^{\circ}\) & \(3.9\pm 0.4^{\circ}\) & \(3.5\pm 0.1^{\circ}\) & nd & \(0.5\pm 0.1^{\circ}\) & \(0.3\pm 0.1^{\circ}\) & MS, RI, ref \\ (E)-3-Hexenen-1-ol & 854 & \(3.9\pm 0.1\) & \(2.3\pm 0.1^{\circ}\) & nd & \(1.3\pm 0.1^{\circ}\) & nd & \(2.3\pm 0.1^{\circ}\) & nd & MS, RI, ref \\
2-(3)-Hexenen-1-ol & 864 & \(<\)0.1 & \(0.3\pm 0.1^{\circ}\) & \(6.5\pm 0.3^{\circ}\) & \(0.5\pm 0.1^{\circ}\) & nd & \(0.4\pm 0.1^{\circ}\) & nd & MS, RI, ref \\
1-Hexenand & 869 & \(15\pm 1.2\) & \(4.8\pm 0.2^{\circ}\) & nd & \(6.5\pm 0.4^{\circ}\) & nd & \(6.6\pm 0.3^{\circ}\) & nd & MS, RI, ref \\
2-Heptanol & 903 & \(0.4\pm 0.1\) & \(<0.1^{\circ}\) & \(0.5\pm 0.1^{\circ}\) & nd & nd & nd & MS, RI, ref \\
2-Ethyl-1-hexenand & 1032 & \(0.6\pm 0.2\) & \(0.8\pm 0.1^{\circ}\) & nd & \(0.5\pm 0.1^{\circ}\) & nd & \(1.3\pm 0.1^{\circ}\) & nd & MS, RI, ref \\
1-Noranol & 1177 & \(1.9\pm 0.2\) & \(0.3\pm 0.1^{\circ}\) & nd & \(3.0\pm 0.1^{\circ}\) & nd & nd & MS, RI, ref \\ \hline
**Aldehydes** & & & & & & & & & \\ Acetaldehyde & 459 & \(-0.1\) & \(0.7\pm 0.1^{\circ}\) & \(0.3\pm 0.1^{\circ}\) & nd & \(<\)0.1 & nd & MS, RI \\
3-Methyl-butanol & 615 & \(0.9\pm 0.2\) & \(0.7\pm 0.1^{\circ}\) & \(3.5\pm 0.3^{\circ}\) & \(0.3\pm 0.1^{\circ}\) & \(2.9\pm 0.1^{\circ}\) & \(0.4\pm 0.1^{\circ}\) & MS, RI \\
2-Methyl-butanan & 630 & \(0.3\pm 0.1\) & \(0.3\pm 0.1^{\circ}\) & \(2.1\pm 0.1^{\circ}\) & \(0.3\pm 0.1^{\circ}\) & \(3.2\pm 0.1^{\circ}\) & \(<\)0.1 & \(5.1\pm 0.4^{\circ}\) & MS, RI \\ Hexanal & 795 & \(1.1\pm 0.2\) & \(0.8\pm 0.1^{\circ}\) & \(0.3\pm 0.1^{\circ}\) & \(0.3\pm 0.1^{\circ}\) & \(1.2\pm 0.1^{\circ}\) & \(0.7\pm 0.1^{\circ}\) & \(3.1\pm 0.1^{\circ}\) & MS, RI \\ Heptantal & 903 & \(<\)0.1 & \(<\)0.1 & \(7.5\pm 0.8^{\circ}\) & nd & \(12.5\pm 0.1^{\circ}\) & nd & \(12.5\pm 0.1^{\circ}\) & MS, RI \\ Benzaldehyde & 957 & \(<\)0.1 & \(<\)0.1 & \(14.1^{\circ}\) & nd & \(2.1\pm 0.1^{\circ}\) & nd & \(0.6\pm 0.1^{\circ}\) & MS, RI, ref \\ Octanal & 1004 & \(<\)0.1 & \(<\)0.1 & \(2.7\pm 0.4^{\circ}\) & nd & \(125.5\pm 0.1^{\circ}\) & nd & \(9.9\pm 0.8^{\circ}\) & MS, RI \\ Benzometaldehyde & 1042 & \(<\)0.1 & \(1.5\pm 0.1^{\circ}\) & \(12.4\pm 0.8^{\circ}\) & \(0.8^{\circ}\) & \(0.1^{\circ}\) & \(13.9\pm 0.1^{\circ}\) & \(1.2\pm 0.2^{\circ}\) & \(13.1\pm 0.3^{\circ}\) & MS, RI \\ Nonanal & 1105 & \(0.6\pm 0.1\) & \(11.4\pm 0.1^{\circ}\) & \(8.2\pm 0.4^{\circ}\) & \(5.0\pm 0.1^{\circ}\) & \(8.8\pm 0.1^{\circ}\) & \(10.7\pm 0.1^{\circ}\) & \(8.0\pm 0.4^{\circ}\) & MS, RI \\ Undecanal & 1310 & \(<\)0.1 & \(<\)0.1 & \(2.4\pm 0.4^{\circ}\) & nd & \(2.1\pm 0.1^{\circ}\) & nd & \(2.1\pm 0.3^{\circ}\) & MS, RI \\ Dodecanal & 1412 & \(<\)0.1 & \(<\)0.1 & \(4.8\pm 0.3^{\circ}\) & nd & \(1.6\pm 0.1^{\circ}\) & nd & \(2.1\pm 0.2^{\circ}\) & MS, RI \\ \hline
**Ketones** & & & & & & & & \\
2-3-Butanedione & 533 & \(0.4\pm 0.1\) & \(<\)0.1 & \(0.3\pm 0.1^{\circ}\) & \(1.2\pm 0.2^{\circ}\) & \(<\)0.1 & \(<\)0.1 & nd & MS, RI, ref \\
2-Butanone & 542 & \(2.2\pm 0.5\) & \(0.6\pm 0.1^{\circ}\) & \(1.5\pm 0.2^{\circ}\) & \(0.5\pm 0.1^{\circ}\) & \(0.5\pm 0.1^{\circ}\) & \(0.5\pm 0.1^{\circ}\) & \(0.5\pm 0.1^{\circ}\) & nd & MS, RI \\
2-Pentanone & 678 & \(2.9\pm 0.3\) & \(1.2\pm 0.2^{\circ}\) & \(0.5\pm 0.1^{\circ}\) & \(0.7\pm 0.1^{\circ}\) & \(0.2\pm 0.1^{\circ}\) & \(0.9\pm 0.1^{\circ}\) & \(0.8\pm 0.1^{\circ}\) & nd & MS, RI \\
3-Pentanone & 700 & \(2.5\pm 0.1\) & \(3.