Annexes A and B to Council Directive 94/55/EC as announced in Commission Directive 2001/7/EC adapting for the third time to technical progress Council Directive 94/55/EC on the approximation of the laws of the Member States with regard to the transport of dangerous goods by road
Date: 2004-01-26
Institutions: European Commission
Subjects: approximation of laws, intra-EU transport, road transport, transport of dangerous goods, transport safety

I(Actswhosepublicationisobligatory)AnnexesAandBtoCouncilDirective94/55/EC(*)asannouncedinCommissionDirective2001/7/EC(**)adaptingforthethirdtimetotechnicalprogressCouncilDirective94/55/EContheapproximationofthelawsoftheMemberStateswithregardtothetransportofdangerousgoodsbyroad(1)OfficialJournaloftheEuropeanUnionEN26.1.2004L18/1(*)OJL319,12.12.1994,p.7.(**)OJL30,1.2.2001,p.43.(1)TextwithEEArelevance.ANNEXAGENERALPROVISIONSANDPROVISIONSCONCERNINGDANGEROUSSUBSTANCESANDARTICLESOfficialJournaloftheEuropeanUnionEN26.1.2004L18/2Part1GENERALPROVISIONSCHAPTER1.1Scopeandapplicability1.1.1.StructureAnnexesAandBtothisDirectivearegroupedintonineparts.AnnexAconsistsofParts1to7,andAnnexBofParts8and9.Eachpartissubdividedintochaptersandeachchapterintosectionsandsubsections.Withineachpartthenumberofthepartisincludedwiththenumbersofthechapters,sectionsandsubsections,forexamplePart4,Chapter2,Section1isnumbered‘4.2.1’.1.1.2.Scope1.1.2.1.ForthepurposesofArticle3ofthisDirective,AnnexAspecifies:(a)dangerousgoodswhicharebarredfrominternationalcarriage;(b)dangerousgoodswhichareauthorisedforinternationalcarriageandtheconditionsattachingtothem(includingexemptions)particularlywithregardto:—classificationofgoods,includingclassificationcriteriaandrelevanttestmethods,—useofpackagings(includingmixedpacking),—useoftanks(includingfilling),—consignmentprocedures(includingmarkingandlabellingofpackagesandplacardingandmarkingofmeansoftransportaswellasdocumentationandinformationrequired),—provisionsconcerningtheconstruction,testingandapprovalofpackagingsandtanks,—useofmeansoftransport(includingloading,mixedloadingandunloading).1.1.2.2.AnnexAcontainscertainprovisionswhich,accordingtoArticle3ofthisDirective,pertaintoAnnexBortobothAnnexesAandB,asfollows:1.1.1.Structure1.1.2.3.(ScopeofAnnexB)1.1.2.4.1.1.3.1.Exemptionsrelatedtothenatureofthetransportoperation1.1.3.6.Exemptionsrelatedtoquantitiescarriedpertransportunit1.1.4.Applicabilityofotherregulations1.1.4.5.Carriageotherthanbyroad1.2.Definitionsandunitsofmeasurements1.3.Trainingofpersonsinvolvedinthecarriageofdangerousgoods1.4.Safetyobligationsoftheparticipants1.5.Derogations1.6.Transitionalmeasures1.8.Checksandothersupportmeasurestoensurecompliancewithsafetyrequirements1.9.TransportrestrictionsbythecompetentauthoritiesChapter3.1.Chapter3.2.columns1,2,14,15and19(applicationofprovisionsofParts8and9toindividualsubstancesorarticles).1.1.2.3.ForthepurposesofArticle3ofthisDirective,AnnexBspecifiestheconditionsregardingtheconstruction,equipmentandoperationofvehiclescarryingdangerousgoodsauthorisedforcarriage:—requirementsforvehiclecrews,equipment,operationanddocumentation,—requirementsconcerningtheconstructionandapprovalofvehicles.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/31.1.2.4.InArticle3oftheDirective,theword‘vehicles’neednotrefertooneandthesamevehicle.AninternationaltransportoperationmaybeperformedbyseveraldifferentvehiclesprovidedthattheoperationtakesplaceontheterritoryofatleasttwoMemberStates,betweentheconsignorandtheconsigneeindicatedinthetransportdocument.1.1.3.Exemptions1.1.3.1.ExemptionsrelatedtothenatureofthetransportoperationTheprovisionslaiddowninthisDirectivedonotapplyto:(a)thecarriageofdangerousgoodsbyprivateindividualswherethegoodsinquestionarepackagedforretailsaleandareintendedfortheirpersonalordomesticuseorforleisureorsportingactivities;(b)thecarriageofmachineryorequipmentnotspecifiedinthisDirectiveandwhichhappentocontaindangerousgoodsintheirinternaloroperationalequipment;(c)thecarriageundertakenbyenterpriseswhichisancillarytotheirmainactivity,suchasdeliveriestobuildingorcivilengineeringsites,orinrelationtosurveying,repairsandmaintenance,inquantitiesofnotmorethan450litresperpackagingandwithinthemaximumquantitiesspecifiedin1.1.3.6.Carriageundertakenbysuchenterprisesfortheirsupplyorexternalorinternaldistributiondoesnotfallwithinthescopeofthisexemption;(d)thecarriageundertakenby,orunderthesupervisionof,theemergencyservices,inparticularbybreakdownvehiclescarryingvehicleswhichhavebeeninvolvedinaccidentsorhavebrokendownandcontaindangerousgoods;(e)emergencytransportintendedtosavehumanlivesorprotecttheenvironmentprovidedthatallmeasuresaretakentoensurethatsuchtransportiscarriedoutincompletesafety.NOTE:Forradioactivematerialsee2.2.7.1.2.1.1.3.2.ExemptionsrelatedtothecarriageofgasesTheprovisionslaiddowninthisDirectivedonotapplytothecarriageof:(a)gasescontainedinthetanksofavehicle,performingatransportoperationanddestinedforitspropulsionorfortheoperationofanyofitsequipment(e.g.refrigeratingequipment);(b)gasescontainedinthefueltanksofvehiclestransported.Thefuelcockbetweengastankandengineshallbeclosedandtheelectriccontactopen;(c)gasesofgroupsAandO(accordingto2.2.2.1),ifthepressureofthegasinthereceptacleortankatatemperatureof15°Cdoesnotexceed200kPa(2bar)andifthegasiscompletelyinthegaseousstateduringcarriage.Thisincludeseverykindofreceptacleortank,e.g.alsopartsofmachineryandapparatus;(d)gasescontainedintheequipmentusedfortheoperationofthevehicle(e.g.fireextinguishersorinflatedpneumatictyres,evenassparepartsorasaload);(e)gasescontainedinthespecialequipmentofvehiclesandnecessaryfortheoperationofthisspecialequipmentduringtransport(coolingsystems,fish-tanks,heaters,etc.)aswellassparereceptaclesforsuchequipmentoruncleanedemptyexchangereceptacles,transportedinthesametransportunit;(f)uncleanedemptyfixedpressuretankswhicharecarriedonconditionthattheyarehermeticallyclosed;and(g)gasescontainedinfoodstuffsorbeverages.1.1.3.3.ExemptionsrelatedtothecarriageofliquidfuelsTheprovisionslaiddowninthisDirectivedonotapplytothecarriageof:(a)fuelcontainedinthetanksofavehicleperformingatransportoperationanddestinedforitspropulsionorfortheoperationofanyofitsequipment.Thefuelmaybecarriedinfixedfueltanks,directlyconnectedtothevehicle'sengineand/orauxiliaryequipment,whichcomplywiththepertinentlegalprovisions,ormaybecarriedinportablefuelcontainers(suchasjerricans).OfficialJournaloftheEuropeanUnionEN26.1.2004L18/4Thetotalcapacityofthefixedtanksshallnotexceed1500litrespertransportunitandthecapacityofatankfittedtoatrailershallnotexceed500litres.Amaximumof60litrespertransportunitmaybecarriedinportablefuelcontainers.Theserestrictionsshallnotapplytovehiclesoperatedbytheemergencyservices;(b)fuelcontainedinthetanksofvehiclesorofothermeansofconveyance(suchasboats)whicharecarriedasaload,whereitisdestinedfortheirpropulsionortheoperationofanyoftheirequipment.Anyfuelcocksbetweentheengineorequipmentandthefueltankshallbeclosedduringcarriageunlessitisessentialfortheequipmenttoremainoperational.Whereappropriate,thevehiclesorothermeansofconveyanceshallbeloadeduprightandsecuredagainstfalling.1.1.3.4.ExemptionsrelatedtospecialprovisionsortodangerousgoodspackedinlimitedquantitiesNOTE:Forradioactivematerialsee2.2.7.1.2.1.1.3.4.1.CertainspecialprovisionsofChapter3.3exemptpartiallyortotallythecarriageofspecificdangerousgoodsfromtherequirementsofthisDirective.Theexemptionapplieswhenthespecialprovisionisreferredtoincolumn6ofTableAofChapter3.2againstthedangerousgoodsentryconcerned.1.1.3.4.2.CertaindangerousgoodspackedinlimitedquantitiesmaybesubjecttoexemptionsprovidedthattheconditionsofChapter3.4aremet.1.1.3.5.ExemptionsrelatedtoemptyuncleanedpackagingsEmptyuncleanedpackagings(includingIBCsandlargepackagings)whichhavecontainedsubstancesofclasses2,3,4.1,5.1,6.1,8and9arenotsubjecttotheconditionsofthisDirectiveifadequatemeasureshavebeentakentonullifyanyhazard.Hazardsarenullifiedifadequatemeasureshavebeentakentonullifyallhazardsofclasses1to9.1.1.3.6.Exemptionsrelatedtoquantitiescarriedpertransportunit1.1.3.6.1.Forthepurposesofthissubsection,dangerousgoodsareassignedtotransportcategories0,1,2,3,or4,asindicatedincolumn15ofTableAofChapter3.2.Emptyuncleanedpackagingshavingcontainedsubstancesassignedtotransportcategory‘0’arealsoassignedtotransportcategory‘0’.Emptyuncleanedpackagingshavingcontainedsubstancesassignedtoatransportcategoryotherthan‘0’areassignedtotransportcategory‘4’.1.1.3.6.2.Wherethequantityofdangerousgoodscarriedonatransportunitdoesnotexceedthevaluesindicatedincolumn3ofthetablein1.1.3.6.3foragiventransportcategory(whenthedangerousgoodscarriedinthetransportunitbelongtothesamecategory)orthevaluecalculatedinaccordancewith1.1.3.6.4(whenthedangerousgoodscarriedinthetransportunitbelongtodifferenttransportcategories),theymaybecarriedinpackagesinonetransportunitwithoutapplicationofthefollowingprovisions:—Chapter1.3,—Chapter5.3,—Section5.4.3,—Chapter7.2,exceptfor7.2.3,V5,V7andV8of7.2.4,—CV1of7.5.11,—Part8exceptfor8.1.2.1(a)and(c),8.1.4.1(a),8.3.4,Chapter8.4,S1(3)and(6),S2(1)and(3),S4andS14toS21ofChapter8.5,—Part9.NOTE:Fortheinformationinthetransportdocumentsee5.4.1.1.10.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/51.1.3.6.3.Wherethedangerousgoodscarriedinthetransportunitbelongtothesamecategory,themaximumtotalquantitypertransportunitisindicatedincolumn3ofthetablebelow.Transportcate-gorySubstancesorarticlesPackinggrouporclassificationcode/grouporUNNoMaximumtotalquantitypertransportunit(1)(2)(3)0Class1:1.1A/1.1L/1.2L/1.3L/1.4LandUNNo0190Class3:UNNo3343Class4.2:SubstancesbelongingtopackinggroupIClass4.3:UNNos1183,1242,1295,1340,1390,1403,1928,2813,2965,2968,2988,3129,3130,3131,3134,3148and3207Class6.1:UNNos1051,1613,1614and3294Class6.2:UNNos2814and2900(riskgroups3and4)Class7:UNNos2912to2919,2977,2978and3321to3333Class9:UNNos2315,3151,3152andequipmentcontainingsuchsubstancesormixturesandemptyuncleanedpackagingshavingcontainedsubstancesclassifiedinthistransportcategory01SubstancesandarticlesbelongingtopackinggroupIandnotclassifiedintransportcategory0andsubstancesandarticlesofthefollowingclasses:Class1:1.1Bto1.1J(a)/1.2Bto1.2J/1.3C/1.3G/1.3H/1.3J/1.5D(a)Class2:groupsT,TC(a),TO,TF,TOCandTFCClass4.1:UNNos3221to3224and3231to3240Class5.2:UNNos3101to3104and3111to3120202SubstancesorarticlesbelongingtopackinggroupIIandnotclassifiedintransportcategories0,1or4andsubstancesofthefollowingclasses:Class1:1.4Bto1.4Gand1.6NClass2:groupFClass4.1:UNNos3225to3230Class5.2:UNNos3105to3110Class6.1:substancesandarticlesbelongingtopackinggroupIIIClass6.2:UNNos2814and2900(riskgroup2)Class9:UNNo32453333SubstancesandarticlesbelongingtopackinggroupIIIandnotclassifiedintransportcategories0,2or4andsubstancesandarticlesofthefollowingclasses:Class2:groupsAandOClass8:UNNos2794,2795,2800and3028Class9:UNNos2990and307210004Class1:1.4SClass4.1:UNNos1331,1345,1944,1945,2254and2623Class4.2:UNNos1361and1362packinggroupIIIClass7:UNNos2908to2911Class9:UNNo3268andempty,uncleanedpackagingshavingcontaineddangerousgoods,exceptforthoseclassifiedintransportcategory0unlimited(a)ForUNNos0081,0082,0084,0241,0331,0332,0482,1005and1017,thetotalmaximumquantitypertransportunitshallbe50kg.Intheabovetable,‘maximumtotalquantitypertransportunit’means:—forarticles,grossmassinkilograms(forarticlesofClass1,netmassinkgoftheexplosivesubstance),—forsolids,liquefiedgases,refrigeratedliquefiedgasesandgasesdissolvedunderpressure,netmassinkilograms,—forliquidsandcompressedgases,nominalcapacityofreceptacles(seedefinitionin1.2.1)inlitres.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/61.1.3.6.4.Wheredangerousgoodsofdifferenttransportcategoriesarecarriedinthesametransportunit,thesumof—thequantityofsubstancesandarticlesoftransportcategory1multipliedby50,—thequantityofsubstancesandarticlesoftransportcategory1referredtoinnote(a)tothetablein1.1.3.6.3multipliedby20,—thequantityofsubstancesandarticlesoftransportcategory2multipliedby3,and—thequantityofsubstancesandarticlesoftransportcategory3shallnotexceed1000.1.1.3.6.5.Forthepurposesofthissubsection,dangerousgoodsexemptedinaccordancewith1.1.3.2to1.1.3.5shallnotbetakenintoaccount.1.1.4.Applicabilityofotherregulations1.1.4.1.(Reserved)1.1.4.2.CarriageinatransportchainincludingmaritimeoraircarriagePackages,containers,portabletanksandtank-containers,whichdonotentirelymeettherequirementsforpacking,mixedpacking,marking,labellingofpackagesorplacardingandorangeplatemarking,ofthisDirective,butareinconformitywiththerequirementsoftheIMDGcodeortheICAOtechnicalinstructionsshallbeacceptedforcarriageinatransportchainincludingmaritimeoraircarriagesubjecttothefollowingconditions:(a)ifthepackagesarenotmarkedandlabelledinaccordancewiththisDirective,theyshallbearmarkingsanddangerlabelsinaccordancewiththerequirementsoftheIMDGcodeortheICAOtechnicalinstructions;(b)therequirementsoftheIMDGcodeortheICAOtechnicalinstructionsshallbeapplicabletomixedpackingwithinapackage;(c)forcarriageinatransportchainincludingmaritimecarriage,ifthecontainers,portabletanksortank-containersarenotmarkedandplacardedinaccordancewithChapter5.3ofthisAnnex,theyshallbemarkedandplacardedinaccordancewithChapter5.3oftheIMDGcode.Insuchcase,only5.3.2.1.1ofthisAnnexisapplicabletothemarkingofthevehicleitself.Forempty,uncleanedportabletanksandtank-containers,thisrequirementshallapplyuptoandincludingthesubsequenttransfertoacleaningstation.Thisderogationdoesnotapplyinthecaseofgoodsclassifiedasdangerousgoodsinclasses1to8ofthisDirectiveandconsideredasnon-dangerousgoodsaccordingtotheapplicablerequirementsoftheIMDGcodeortheICAOtechnicalinstructions.NOTE:Fortheinformationinthetransportdocumentsee5.4.1.1.7;forthecontainerpackingcertificate,see5.4.2.1.1.4.3.UseofportabletanksapprovedformaritimetransportPortabletankswhichdonotmeettherequirementsofChapters6.7or6.8,butwhichhavebeenbuiltandapprovedbefore1January2003inaccordancewiththeprovisions(includingtransitionalprovisions)oftheIMDGcode(amendment29-98)maybeuseduntil31December2009providedtheyarefoundtomeettheapplicableinspectionandtestprovisionsoftheIMDGcode(amendment29-98)andthattheinstructionsreferredtoincolumns12and14ofChapter3.2oftheIMDGcode(amendment30-00)arefullycompliedwith.Theymaycontinuetobeusedafter31December2009iftheymeettheapplicableinspectionandtestprovisionsoftheIMDGcode,butprovidedthattheinstructionsofcolumns10and11ofChapter3.2ofthisDirectiveandofChapter4.2arecompliedwith.NOTE:Fortheinformationinthetransportdocument,see5.4.1.1.8.1.1.4.4.(Reserved)1.1.4.5.Carriageotherthanbyroad1.1.4.5.1.IfthevehiclecarryingoutatransportoperationsubjecttotherequirementsofthisDirectiveisconveyedoverasectionofthejourneyotherwisethanbyroadhaulage,thenanynationalorinternationalregulationswhich,onthesaidsection,governthecarriageofdangerousgoodsbythemodeoftransportusedforconveyingtheroadvehicleshallalonebeapplicabletothesaidsectionofthejourney.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/71.1.4.5.2.Inthecasesreferredtoin1.1.4.5.1,theMemberStatesinvolvedmayagreetoapplytherequirementsofthisDirectivetothesectionofajourneywhereavehicleisconveyedotherwisethanbyroadhaulage,supplemented,iftheyconsideritnecessary,byadditionalrequirements,unlesssuchagreementsbetweentheMemberStatesinvolvedwouldcontraveneclausesoftheinternationalconventionsgoverningthecarriageofdangerousgoodsbythemodeoftransportusedforconveyingtheroadvehicleonthesaidsectionofthejourney,e.g.theInternationalConventionfortheSafetyofLifeatSea(SOLAS),towhichtheseMemberStateswouldalsobeContractingParties.1.1.4.5.3.IncaseswhereatransportoperationsubjecttotheprovisionsofthisDirectiveislikewisesubjectoverthewholeorapartoftheroadjourneytotheprovisionsofaninternationalconventionwhichregulatesthecarriageofdangerousgoodsbyamodeoftransportotherthanroadcarriagebyvirtueofclausesextendingtheapplicabilityofthatconventiontocertainmotor-vehicleservices,thentheprovisionsofthatinternationalconventionshallapplyoverthejourneyinquestionconcurrentlywiththoseofthisDirectivewhicharenotincompatiblewiththem;theotherclausesofthisDirectiveshallnotapplyoverthejourneyinquestion.CHAPTER1.2Definitionsandunitsofmeasurement1.2.1.DefinitionsNOTE:Thissectioncontainsallgeneralorspecificdefinitions.ForthepurposesofthisDirective:AAerosol,see‘Aerosoldispenser’.Aerosoldispensermeansanynon-refillablereceptaclemadeofmetal,glassorplastics,containing,underpressure,agasoramixtureofgases,withorwithoutaliquid,pasteorpowder,andfittedwithareleasedeviceallowingthecontentstobeejectedassolidorliquidparticlesinsuspensioninagas,asafoam,pasteorpowderorinaliquidstateorinagaseousstate.BBagmeansaflexiblepackagingmadeofpaper,plasticsfilm,textiles,wovenmaterialorothersuitablematerial.Battery-vehiclemeansavehiclecontainingelementswhicharelinkedtoeachotherbyamanifoldandpermanentlyfixedtoatransportunit.Thefollowingelementsareconsideredtobeelementsofabattery-vehicle:cylinders,tubes,bundlesofcylinders(alsoknownasframes),pressuredrumsaswellastanksdestinedforthecarriageofgasesofClass2withacapacityofmorethan450litres.Biological/technicalnamemeansanamecurrentlyusedinscientificandtechnicalhandbooks,journalsandtexts.Tradenamesshallnotbeusedforthispurpose.Body(forallcategoriesofIBCotherthancompositeIBCs)meansthereceptacleproper,includingopeningsandclosures,butdoesnotincludeserviceequipment.Boxmeansapackagingwithcompleterectangularorpolygonalfaces,madeofmetal,wood,plywood,reconstitutedwood,fibreboard,plasticsorothersuitablematerial.Smallholesforpurposesofeaseofhandlingoropeningortomeetclassificationrequirements,arepermittedaslongastheydonotcompromisetheintegrityofthepackagingduringcarriage.Bundleofcylinders(frame)meansatransportableassemblyofcylinderswhichareinterconnectedbyamanifoldandheldfirmlytogether.CCalculationpressuremeansatheoreticalpressureatleastequaltothetestpressurewhich,accordingtothedegreeofdangerexhibitedbythesubstancebeingcarried,maytoagreaterorlesserdegreeexceedtheworkingpressure.Itisusedsolelytodeterminethethicknessofthewallsoftheshell,independentlyofanyexternalorinternalreinforcingdevice(seealso‘Dischargepressure’,‘Fillingpressure’,‘Maximumworkingpressure(gaugepressure)’and‘Testpressure’).NOTE:Forportabletanks,seeChapter6.7.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8Carriagemeansthechangeofplaceofdangerousgoods,includingstopsmadenecessarybytransportconditionsandincludinganyperiodspentbythedangerousgoodsinvehicles,tanksandcontainersmadenecessarybytrafficconditionsbefore,duringandafterthechangeofplace.Thisdefinitionalsocoverstheintermediatetemporarystorageofdangerousgoodsinordertochangethemodeormeansoftransport(transhipment).Thisshallapplyprovidedthattransportdocumentsshowingtheplaceofdispatchandtheplaceofreceptionarepresentedonrequestandprovidedthatpackagesandtanksarenotopenedduringintermediatestorage,excepttobecheckedbythecompetentauthorities.Carriageinbulkmeansthecarriageofunpackagedsolidsorarticlesinvehiclesorcontainers.Thetermdoesnotapplytopackagedgoodsnortosubstancescarriedintanks.Carriermeanstheenterprisewhichcarriesoutthetransportoperationwithorwithoutatransportcontract.Closedcontainermeansatotallyenclosedcontainerhavingarigidroof,rigidsidewalls,rigidendwallsandafloor.Thetermincludescontainerswithanopeningroofwheretheroofcanbeclosedduringtransport.Closedvehiclemeansavehiclehavingabodycapableofbeingclosed.Closuremeansadevicewhichclosesanopeninginareceptacle.Collectiveentrymeansanentryforawelldefinedgroupofsubstancesorarticles(see2.1.1.2,B,CandD).Combinationpackagingmeansacombinationofpackagingsfortransportpurposes,consistingofoneormoreinnerpackagingssecuredinanouterpackinginaccordancewith4.1.1.5.NOTE:The‘inners’of‘combinationpackagings’arealwaystermed‘innerpackagings’andnot‘innerreceptacles’.Aglassbottleisanexampleofsuchan‘innerpackaging’.Combustionheatermeansadevicedirectlyusingliquidorgaseousfuelandnotusingthewasteheatfromtheengineusedforpropulsionofthevehicle.CompetentauthoritymeanstheauthorityorauthoritiesoranyotherbodyorbodiesdesignatedassuchineachStateandineachspecificcaseinaccordancewithdomesticlaw.Complianceassurance(radioactivematerial)meansasystematicprogrammeofmeasuresappliedbyacompetentauthoritywhichisaimedatensuringthattherequirementsofthisDirectivearemetinpractice.CompositeIBCwithplasticsinnerreceptaclemeansanIBCcomprisingstructuralequipmentintheformofarigidoutercasingencasingaplasticsinnerreceptacletogetherwithanyserviceorotherstructuralequipment.Itissoconstructedthattheinnerreceptacleandoutercasingonceassembledform,andareusedas,anintegratedsingleunittobefilled,stored,transportedoremptiedassuch.NOTE:‘Plastics’,whenusedinconnectionwithinnerreceptaclesforcompositeIBCs,istakentoincludeotherpolymericmaterialssuchasrubber,etc.Compositepackaging(plasticsmaterial)isapackagingconsistingofaninnerplasticsreceptacleandanouterpackaging(madeofmetal,fibreboard,plywood,etc.).Onceassembledsuchapackagingremainsthereafteraninseparableunit;itisfilled,stored,despatchedandemptiedassuch.NOTE:Seenoteunder‘Compositepackagings(glass,porcelainorstoneware)’.Compositepackaging(glass,porcelainorstoneware)isapackagingconsistingofaninnerglass,porcelainorstonewarereceptacleandanouterpackaging(madeofmetal,wood,fibreboard,plasticsmaterial,expandedplasticsmaterial,etc.).Onceassembled,suchapackagingremainsthereafteraninseparableunit;itisfilled,stored,despatchedandemptiedassuch.NOTE:The‘inners’of‘compositepackagings’arenormallytermed‘innerreceptacles’.Forexample,the‘inner’ofa6HA1(compositepackaging,plasticsmaterial)issuchan‘innerreceptacle’sinceitisnormallynotdesignedtoperformacontainmentfunctionwithoutits‘outerpackaging’andisnotthereforean‘innerpackaging’.Consigneemeanstheconsigneeaccordingtothecontractforcarriage.Iftheconsigneedesignatesathirdpartyinaccordancewiththeprovisionsapplicabletothecontractforcarriage,thispersonshallbedeemedtobetheconsigneewithinthemeaningofthisDirective.Ifthetransportoperationtakesplacewithoutacontractforcarriage,theenterprisewhichtakeschargeofthedangerousgoodsonarrivalshallbedeemedtobetheconsignee.Consignmentmeansanypackageorpackages,orloadofdangerousgoods,presentedbyaconsignorforcarriage.Consignormeanstheenterprisewhichconsignsdangerousgoodseitheronitsownbehalforforathirdparty.Ifthetransportoperationiscarriedoutunderacontractforcarriage,consignormeanstheconsignoraccordingtothecontractforcarriage.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/9Containermeansanarticleoftransportequipment(liftvanorothersimilarstructure):—ofapermanentcharacterandaccordinglystrongenoughtobesuitableforrepeateduse,—speciallydesignedtofacilitatethecarriageofgoods,byoneormoremeansoftransport,withoutbreakageofload,—fittedwithdevicespermittingitsreadystowageandhandling,particularlywhenbeingtransloadedfromonemeansoftransporttoanother,—sodesignedastobeeasytofillandempty(seealso‘Closedcontainer’,‘Largecontainer’,‘Opencontainer’,‘Sheetedcontainer’and‘Smallcontainer’).Aswapbodyisacontainerwhich,inaccordancewithEuropeanstandardEN283(1991edition)hasthefollowingcharacteristics:—fromthepointofviewofmechanicalstrength,itisonlybuiltforcarriageonawagonoravehicleonlandorbyroll-onroll-offship,—itcannotbestacked,—itcanberemovedfromvehiclesbymeansofequipmentonboardthevehicleandonitsownsupports,andcanbereloaded.NOTE:Theterm‘container’doesnotcoverconventionalpackagings,IBCs,tank-containersorvehicles.Controltemperaturemeansthemaximumtemperatureatwhichtheorganicperoxideortheself-reactivesubstancecanbesafelycarried.CSCmeanstheInternationalConventionforSafeContainers(Geneva,1972)asamendedandpublishedbytheInternationalMaritimeOrganisation(IMO),London.Cratemeansanouterpackagingwithincompletesurfaces.Cryogenicreceptaclemeansatransportablethermallyinsulatedreceptacleforrefrigeratedliquefiedgasesofacapacityofnotmorethan1000litres.Cylindermeansatransportablepressurereceptacleofacapacitynotexceeding150litres(seealso‘Bundleofcylinders(frame)’).DDangerousgoodsmeansthosesubstancesandarticlesthecarriageofwhichisprohibitedbythisDirective,orauthorisedonlyundertheconditionsprescribedtherein.Dangerousreactionmeans:(a)combustionorevolutionofconsiderableheat;(b)evolutionofflammable,asphyxiant,oxidisingortoxicgases;(c)theformationofcorrosivesubstances;(d)theformationofunstablesubstances;or(e)dangerousriseinpressure(fortanksonly).Demountabletankmeansatank,otherthanafixedtank,aportabletank,atank-containeroranelementofabattery-vehicleoraMEGCwhichhasacapacityofmorethan450litres,isnotdesignedforthecarriageofgoodswithoutbreakageofload,andnormallycanonlybehandledwhenitisempty.Dischargepressuremeansthemaximumpressureactuallybuiltupinthetankwhenitisbeingdischargedunderpressure(seealso‘Calculationpressure’,‘Fillingpressure’,‘Maximumworkingpressure(gaugepressure)’and‘Testpressure’).Drummeansaflat-endedorconvex-endedcylindricalpackagingmadeoutofmetal,fibreboard,plastics,plywoodorothersuitablematerials.Thisdefinitionalsoincludespackagingsofothershapes,e.g.round,taper-neckedpackagingsorpail-shapedpackagings.Woodenbarrelsandjerricansarenotcoveredbythisdefinition.EECDirectivemeansprovisionsdecidedbythecompetentinstitutionsoftheEuropeanCommunityandwhicharebinding,astotheresulttobeachieved,uponeachMemberStatetowhichitisaddressed,butshallleavetothenationalauthoritiesthechoiceofformandmethods.ECERegulationmeansaregulationannexedtotheAgreementconcerningtheadoptionofuniformtechnicalprescriptionsforwheeledvehiclesequipmentandpartswhichcanbefittedandorusedonwheeledvehiclesandtheconditionsforreciprocalrecognitionofapprovalsgrantedonthebasisoftheseprescriptions(1958Agreement,asamended).OfficialJournaloftheEuropeanUnionEN26.1.2004L18/10Emergencytemperaturemeansthetemperatureatwhichemergencyproceduresshallbeimplementedintheeventoflossoftemperaturecontrol.Enterprisemeansanynaturalperson,anylegalperson,whetherprofit-makingornot,anyassociationorgroupofpersonswithoutlegalpersonality,whetherprofit-makingornot,oranyofficialbody,whetherithaslegalpersonalityitselforisdependentonanauthoritythathassuchpersonality.FFibreboardIBCmeansafibreboardbodywithorwithoutseparatetopandbottomcaps,ifnecessaryaninnerliner(butnoinnerpackagings),andappropriateserviceandstructuralequipment.Fillermeansanyenterprisewhichloadsdangerousgoodsintoatank(tank-vehicle,demountabletank,portabletankortank-container)and/orintoavehicle,largecontainerorsmallcontainerforcarriageinbulk,orintoabattery-vehicleorMEGC.Fillingpressuremeansthemaximumpressureactuallybuiltupinthetankwhenitisbeingfilledunderpressure(seealso‘Calculationpressure’,‘Dischargepressure’,‘Maximumworkingpressure(gaugepressure)’and‘Testpressure’).Fixedtankmeansatankhavingacapacityofmorethan1000litreswhichispermanentlyattachedtoavehicle(whichthenbecomesatank-vehicle)orisanintegralpartoftheframeofsuchvehicle.Flammablecomponent(foraerosolsandgascartridges)meansagaswhichisflammableinairatnormalpressureorasubstanceorapreparationinliquidformwhichhasaflash-pointlessthanorequalto100°C.Flash-pointmeansthelowesttemperatureofaliquidatwhichitsvapoursformaflammablemixturewithair.FlexibleIBCmeansabodyconstitutedoffilm,wovenfabricoranyotherflexiblematerialorcombinationsthereof,andifnecessary,aninnercoatingorliner,togetherwithanyappropriateserviceequipmentandhandlingdevices.Frame(Class2),see‘Bundleofcylinders’.Fullloadmeansanyloadoriginatingfromoneconsignorforwhichtheuseofavehicleorofalargecontainerisexclusivelyreservedandalloperationsfortheloadingandunloadingofwhicharecarriedoutinconformitywiththeinstructionsoftheconsignororoftheconsignee.NOTE:ThecorrespondingtermforClass7is‘exclusiveuse’,see2.2.7.2.GGasmeansasubstancewhich:(a)at50°Chasavapourpressuregreaterthan300kPa(3bar);or(b)iscompletelygaseousat20°Cunderstandardpressureof101,3kPa.Gascartridgemeansanynon-refillablereceptaclecontaining,underpressure,agasoramixtureofgases.Itmaybefittedwithavalve.HHandlingdevice(forflexibleIBCs)meansanysling,loop,eyeorframeattachedtothebodyoftheIBCorformedfromthecontinuationoftheIBCbodymaterial.Hermeticallyclosedtankmeansatankwhoseopeningsarehermeticallyclosedandwhichisnotequippedwithsafetyvalves,burstingdiscsorothersimilarsafetydevices.Tankshavingsafetyvalvesprecededbyaburstingdiscshallbedeemedtobehermeticallyclosed.IIBC,see‘Intermediatebulkcontainer’.ICAOtechnicalinstructionsmeansthetechnicalinstructionsfortheSafeTransportofDangerousGoodsbyAir,whichcomplementAnnex18totheChicagoConventiononInternationalCivilAviation(Chicago1944),publishedbytheInternationalCivilAviationOrganisation(ICAO)inMontreal.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/11IMDGcodemeanstheInternationalMaritimeDangerousGoodsCode,fortheimplementationofChapterVII,PartA,oftheInternationalConventionfortheSafetyofLifeatSea,1974(SOLASConvention),publishedbytheInternationalMaritimeOrganisation(IMO),London.Innerpackagingmeansapackagingforwhichanouterpackagingisrequiredforcarriage.Innerreceptaclemeansareceptaclewhichrequiresanouterpackaginginordertoperformitscontainmentfunction.Intermediatebulkcontainer(IBC)meansarigid,orflexibleportablepackaging,otherthanthosespecifiedinChapter6.1,that:(a)hasacapacityof:(i)notmorethan3m3forsolidsandliquidsofpackinggroupsIIandIII;(ii)notmorethan1.5m3forsolidsofpackinggroupIwhenpackedinflexible,rigidplastics,composite,fibreboardandwoodenIBCs;(iii)notmorethan3m3forsolidsofpackinggroupIwhenpackedinmetalIBCs;(iv)notmorethan3m3forradioactivematerialofClass7;(b)isdesignedformechanicalhandling;(c)isresistanttothestressesproducedinhandlingandtransportasdeterminedbythetestsspecifiedinChapter6.5(seealso‘CompositeIBCwithplasticsinnerreceptacle’,‘FibreboardIBC’,‘FlexibleIBC’,‘MetalIBC’,‘RigidplasticsIBC’and‘WoodenIBC’).NOTES:1.Portabletanksortank-containersthatmeettherequirementsofChapter6.7or6.8respectivelyarenotconsideredtobeintermediatebulkcontainers(IBCs).2.Intermediatebulkcontainers(IBCs)whichmeettherequirementsofChapter6.5arenotconsideredtobecontainersforthepurposesofthisDirective.Intermediatepackagingmeansapackagingplacedbetweeninnerpackagingsorarticles,andanouterpackaging.JJerricanmeansametalorplasticspackagingofrectangularorpolygonalcross-sectionwithoneormoreorifices.LLargecontainermeans(a)acontainerhavinganinternalvolumeofmorethan3m3;(b)inthemeaningoftheCSC,acontainerofasizesuchthattheareaenclosedbythefourouterbottomcornersiseither(i)atleast14m2(150squarefeet)or(ii)atleast7m2(75squarefeet)iffittedwithtopcornerfittings.NOTE:Forradioactivematerialsee2.2.7.1.2.Largepackagingmeansapackagingconsistingofanouterpackagingwhichcontainsarticlesorinnerpackagingsandwhich:(a)isdesignedformechanicalhandling;(b)exceeds400kgnetmassor450litrescapacitybuthasavolumeofnotmorethan3m3.Leakproofnesstestmeansatesttodeterminetheleakproofnessofatank,apackagingoranIBCandoftheequipmentandclosuredevices.NOTE:Forportabletanks,seeChapter6.7.Light-gaugemetalpackagingmeansapackagingofcircular,elliptical,rectangularorpolygonalcross-section(alsoconical)andtaper-neckedandpail-shapedpackagingmadeofmetal,havingawallthicknessoflessthan0.5mm(e.g.tinplate),flatorconvexbottomedandwithoneormoreorifices,whichisnotcoveredbythedefinitionsfordrumsorjerricans.Linermeansatubeorbaginsertedintoapackaging,includinglargepackagingsorIBCs,butnotforminganintegralpartofit,includingtheclosuresofitsopenings.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/12Liquidmeansasubstancewhichat50°Chasavapourpressureofnotmorethan300kPa(3bar),whichisnotcompletelygaseousat20°Cand101,3kPa,andwhich(a)hasameltingpointorinitialmeltingpointof20°Corlessatapressureof101,3kPa,or(b)isliquidaccordingtotheASTMD4359-90testmethodor(c)isnotpastyaccordingtothecriteriaapplicabletothetestfordeterminingfluidity(penetrometertest)describedin2.3.4.NOTE:‘Carriageintheliquidstate’,forthepurposeoftankrequirements,means:—carriageofliquidsaccordingtotheabovedefinition,or—solidshandedoverforcarriageinthemoltenstate.Loadermeansanyenterprisewhichloadsdangerousgoodsintoavehicleorlargecontainer.MManualoftestsandcriteriameansthethirdrevisededitionoftheUnitedNationsRecommendationsontheTransportofDangerousGoods,ManualofTestsandCriteria,publishedbytheUnitedNationsOrganisation(ST/SG/AC.10/11/Rev.3).Massofpackagemeansgrossmassofthepackageunlessotherwisestated.Themassofcontainersandtanksusedforthecarriageofgoodsisnotincludedinthegrossmass.Maximumcapacitymeansthemaximuminnervolumeofreceptaclesorpackagingsincludingintermediatebulkcontainers(IBCs)andlargepackagingsexpressedincubicmetresorlitres.Maximumnetmassmeansthemaximumnetmassofcontentsinasinglepackagingormaximumcombinedmassofinnerpackagingsandthecontentsthereofexpressedinkilograms.Maximumpermissiblegrossmass(a)(forallcategoriesofIBCsotherthanflexibleIBCs)meansthemassofthebody,itsserviceequipmentandstructuralequipmentandthemaximumpermissibleload;(b)(fortanks)meansthetareofthetankandtheheaviestloadauthorisedforcarriage.NOTE:Forportabletanks,seeChapter6.7.Maximumpermissibleload(forflexibleIBCs)meansthemaximumnetmassforwhichtheIBCisintendedandwhichitisauthorisedtocarry.Maximumworkingpressure(gaugepressure)meansthehighestofthefollowingthreepressures:(a)thehighesteffectivepressureallowedinthetankduringfilling(maximumfillingpressureallowed);(b)thehighesteffectivepressureallowedinthetankduringdischarge(maximumdischargepressureallowed);and(c)theeffectivegaugepressuretowhichthetankissubjectedbyitscontents(includingsuchextraneousgasesasitmaycontain)atthemaximumworkingtemperature.UnlessthespecialrequirementsprescribedinChapter4.3provideotherwise,thenumericalvalueofthisworkingpressure(gaugepressure)shallnotbelowerthanthevapourpressure(absolutepressure)ofthefillingsubstanceat50°C.Fortanksequippedwithsafetyvalves(withorwithoutburstingdisc),themaximumworkingpressure(gaugepressure)shallhoweverbeequaltotheprescribedopeningpressureofsuchsafetyvalves(seealso‘Calculationpressure’,‘Dischargepressure’,‘Fillingpressure’and‘Testpressure’).NOTE:Forportabletanks,seeChapter6.7.MEGC,see‘Multiple-elementgascontainer’.MetalIBCmeansametalbodytogetherwithappropriateserviceandstructuralequipment.Mildsteelmeansasteelhavingaminimumtensilestrengthbetween360N/mm2and440N/mm2.NOTE:Forportabletanks,seeChapter6.7.Multiple-elementgascontainer(MEGC)meansaunitcontainingelementswhicharelinkedtoeachotherbyamanifoldandmountedonaframe.Thefollowingelementsareconsideredtobeelementsofamultiple-elementgascontainer:cylinders,tubes,pressuredrumsandbundlesofcylindersaswellastanksforthecarriageofgasesofClass2havingacapacityofmorethan450litres.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/13NNominalcapacityofthereceptaclemeansthenominalvolumeofthedangeroussubstancecontainedinthereceptacleexpressedinlitres.Forcompressedgascylindersthenominalcapacityshallbethewatercapacityofthecylinder.N.O.S.entry(nototherwisespecifiedentry)meansacollectiveentrytowhichsubstances,mixtures,solutionsorarticlesmaybeassignedifthey:(a)arenotmentionedbynameinTableAofChapter3.2,and(b)exhibitchemical,physicaland/ordangerouspropertiescorrespondingtotheClass,classificationcode,packinggroupandthenameanddescriptionofthen.o.s.entry.OOpencontainermeansanopentopcontaineroraplatformbasedcontainer.Openvehiclemeansavehicletheplatformofwhichhasnosuperstructureorismerelyprovidedwithsideboardsandatailboard.Outerpackagingmeanstheouterprotectionofthecompositeorcombinationpackagingtogetherwithanyabsorbentmaterials,cushioningandanyothercomponentsnecessarytocontainandprotectinnerreceptaclesorinnerpackagings.Overpackmeansanenclosureusedbyasingleconsignortocontainoneormorepackages,consolidatedintoasingleuniteasiertohandleandstowduringcarriage.Examplesofoverpacks:(a)aloadingtraysuchasapallet,onwhichseveralpackagesareplacedorstackedandsecuredbyaplasticstrip,shrinkorstretchwrappingorotherappropriatemeans;or(b)anouterprotectivepackagingsuchasaboxoracrate.PPackagemeansthecompleteproductofthepackingoperation,consistingofthepackagingorlargepackagingorIBCanditscontentspreparedfordispatch.Thetermincludesreceptaclesforgasesasdefinedinthissectionaswellasarticleswhich,becauseoftheirsize,massorconfigurationmaybecarriedunpackagedorcarriedincradles,cratesorhandlingdevices.Thetermdoesnotapplytogoodswhicharecarriedinbulk,ortosubstancescarriedintanks.NOTE:Forradioactivematerial,see2.2.7.2.Packagingmeansthereceptacleandanyothercomponentsormaterialsnecessaryforthereceptacletoperformitscontainmentfunction(seealso‘Combinationpackaging’,‘Compositepackaging(plasticsmaterial)’,‘Compositepackaging(glass,porcelainorstoneware)’,‘Innerpackaging’,‘Intermediatebulkcontainer(IBC)’,‘Intermediatepackaging’,‘Largepackaging’,‘Light-gaugemetalpackaging’,‘Outerpackaging’,‘Reconditionedpackaging’,‘Remanufacturedpackaging’,‘Reusedpackaging’,‘Salvagepackaging’and‘Sift-proofpackaging’).NOTE:Forradioactivematerial,see2.2.7.2.Packermeansanyenterprisewhichputsdangerousgoodsintopackagings,includinglargepackagingsandintermediatebulkcontainers(IBCs)and,wherenecessary,preparespackagesforcarriage.Packinggroupmeansagrouptowhich,forpackingpurposes,certainsubstancesmaybeassignedinaccordancewiththeirdegreeofdanger.ThepackinggroupshavethefollowingmeaningswhichareexplainedmorefullyinPart2:—PackinggroupI:substancespresentinghighdanger,—PackinggroupII:substancespresentingmediumdanger,and—PackinggroupIII:substancespresentinglowdanger.NOTE:Certainarticlescontainingdangerousgoodsareassignedtoapackinggroup.Portabletankmeansamultimodaltankhavingacapacityofmorethan450litresinaccordancewiththedefinitionsinChapter6.7ortheIMDGcodeandindicatedbyaportabletankinstruction(T-code)inColumn(10)ofTableAofChapter3.2.Portabletankoperator,see‘Tank-container/portabletankoperator’.Pressuredrummeansawelded,transportablepressurereceptacleofacapacityexceeding150litresandofnotmorethan1000litres(e.g.cylindricalreceptaclesequippedwithrollinghoops,receptaclesonskidsandreceptaclesinframes).Pressurisedgascartridge,see‘Aerosoldispenser’.ProtectedIBC(formetalIBCs)meansanIBCprovidedwithadditionalprotectionagainstimpact,theprotectiontakingtheformof,forexample,amultilayer(sandwich)ordouble-wallconstruction,oraframewithametallattice-workcasing.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/14QQualityassurancemeansasystematicprogrammeofcontrolsandinspectionsappliedbyanyorganisationorbodywhichisaimedatprovidingconfidencethatthesafetyprescriptionsinthisDirectivearemetinpractice.RReceptacle(Class1)includesboxes,bottles,cans,drums,jarsandtubes,includinganymeansofclosureusedintheinnerorintermediatepackaging.Receptaclemeansacontainmentvesselforreceivingandholdingsubstancesorarticles,includinganymeansofclosing.Thisdefinitiondoesnotapplytoshells(seealso‘Cryogenicreceptacle’,‘Innerreceptacle’,‘Rigidinnerreceptacle’and‘Gascartridge’).NOTE:ReceptaclesforgasesofClass2arecylinders,tubes,pressuredrums,cryogenicreceptaclesandbundlesofcylinders(frames).Reconditionedpackagingmeansinparticular(a)metaldrumsthatare:(i)cleanedtooriginalmaterialsofconstruction,withallformercontents,internalandexternalcorrosion,andexternalcoatingsandlabelsremoved;(ii)restoredtooriginalshapeandcontour,withchimes(ifany)straightenedandsealedandallnon-integralgasketsreplaced;and(iii)inspectedaftercleaningbutbeforepainting,withrejectionofpackagingswithvisiblepitting,significantreductioninthematerialthickness,metalfatigue,damagedthreadsorclosuresorothersignificantdefects;(b)plasticsdrumsandjerricansthat:(i)arecleanedtooriginalmaterialsofconstruction,withallformercontents,externalcoatingsandlabelsremoved;(ii)haveallnon-integralgasketsreplaced;and(iii)areinspectedaftercleaningwithrejectionofpackagingswithvisibledamagesuchastears,creasesorcracks,ordamagedthreadsorclosuresorothersignificantdefects.Recycledplasticsmaterialmeansmaterialrecoveredfromusedindustrialpackagingsthathasbeencleanedandpreparedforprocessingintonewpackagings.Reel(Class1)meansadevicemadeofplastics,wood,fibreboard,metalorothersuitablematerialcomprisingacentralspindlewith,orwithout,sidewallsateachendofthespindle.Articlesandsubstancescanbewoundontothespindleandmayberetainedbysidewalls.Referencesteelmeansasteelwithatensilestrengthof370N/mm2andanelongationatfractureof27%.Remanufacturedpackagingmeansinparticular(a)metaldrumsthat:(i)areproducedasaUNtypecomplyingwiththerequirementsofChapter6.1fromanon-UNtype;(ii)areconvertedfromoneUNtypecomplyingwiththerequirementsofChapter6.1toanotherUNtype;or(iii)undergothereplacementofintegralstructuralcomponents(suchasnon-removableheads);(b)plasticsdrumsthat:(i)areconvertedfromoneUNtypetoanotherUNtype(e.g.1H1to1H2);or(ii)undergothereplacementofintegralstructuralcomponents.RemanufactureddrumsaresubjecttotherequirementsofChapter6.1whichapplytonewdrumsofthesametype.Reusedpackagingmeansapackagingwhichhasbeenexaminedandfoundfreeofdefectsaffectingtheabilitytowithstandtheperformancetests.Thetermincludesthosewhicharerefilledwiththesameorsimilarcompatiblecontentsandarecarriedwithindistributionchainscontrolledbytheconsignoroftheproduct.RIDmeansRegulationsconcerningtheInternationalCarriageofDangerousGoodsbyRail(Annex1toAppendixB(UniformRulesConcerningtheContractforInternationalCarriageofGoodsbyRail)(CIM)ofCOTIF(Conventionconcerninginternationalcarriagebyrail)).Rigidinnerreceptacle(forcompositeIBCs)meansareceptaclewhichretainsitsgeneralshapewhenemptywithoutitsclosuresinplaceandwithoutbenefitoftheoutercasing.Anyinnerreceptaclethatisnot‘rigid’isconsideredtobe‘flexible’.RigidplasticsIBCmeansarigidplasticsbody,whichmayhavestructuralequipmenttogetherwithappropriateserviceequipment.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/15SSafetyvalvemeansaspring-loadeddevicewhichisactivatedautomaticallybypressurethepurposeofwhichistoprotectthetankagainstunacceptableexcessinternalpressure.SADTsee‘Self-acceleratingdecompositiontemperature’.SalvagepackagingmeansaspecialpackagingconformingtotheapplicablerequirementsofChapter6.1intowhichdamaged,defectiveorleakingdangerousgoodspackages,ordangerousgoodsthathavespilledorleakedareplacedforpurposesofcarriageforrecoveryordisposal.Self-acceleratingdecompositiontemperature(SADT),meansthelowesttemperatureatwhichself-acceleratingdecompositionmayoccurwithsubstanceinthepackagingasusedduringcarriage.ProvisionsfordeterminingtheSADTandtheeffectsofheatingunderconfinementarecontainedinPartIIoftheManualofTestsandCriteria.Serviceequipment(a)ofthetankmeansfillingandemptying,venting,safety,heatingandheatinsulatingdevicesandmeasuringinstruments;(b)oftheelementsofabattery-vehicleorofaMEGCmeansfillingandemptyingdevices,includingthemanifold,safetydevicesandmeasuringinstruments;(c)ofanIBCmeansthefillinganddischargedevicesandanypressure-relieforventing,safety,heatingandheatinsulatingdevicesandmeasuringinstruments.NOTE:Forportabletanks,seeChapter6.7.Sheetedcontainermeansanopencontainerequippedwithasheettoprotectthegoodsloaded.Sheetedvehiclemeansanopenvehicleprovidedwithasheettoprotecttheload.Shellmeansthesheathingcontainingthesubstance(includingtheopeningsandtheirclosures).NOTES:1.Thisdefinitiondoesnotapplytoreceptacles.2.Forportabletanks,seeChapter6.7.Sift-proofpackagingmeansapackagingimpermeabletodrycontents,includingfinesolidmaterialproducedduringcarriage.Smallcontainermeansacontainerhavinganinternalvolumeofnotlessthan1m3andnotmorethan3m3.NOTE:Forradioactivematerial,see2.2.7.2.Smallreceptaclecontaininggas,see‘Gascartridge’.Solidmeans:(a)asubstancewithameltingpointorinitialmeltingpointofmorethan20°Catapressureof101,3kPa,or(b)asubstancewhichisnotliquidaccordingtotheASTMD4359-90testmethodorwhichispastyaccordingtothecriteriaapplicabletothetestfordeterminingfluidity(penetrometertest)describedin2.3.4.Structuralequipment(a)fortanksofatank-vehicleordemountabletank,meanstheexternalorinternalreinforcing,fastening,protectiveorstabilisingmembersoftheshell;(b)fortanksofatank-container,meanstheexternalorinternalreinforcing,fastening,protectiveorstabilisingmembersoftheshell;(c)forelementsofabattery-vehicleoranMEGCmeanstheexternalorinternalreinforcing,fastening,protectiveorstabilisingmembersoftheshellorreceptacle;(d)forIBCsotherthanflexibleIBCsmeansthereinforcing,fastening,handling,protectiveorstabilisingmembersofthebody(includingthebasepalletforcompositeIBCswithplasticsinnerreceptacle).NOTE:Forportabletanks,seeChapter6.7.Swap-body,see‘Container’.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/16TTankmeansashell,includingitsserviceandstructuralequipment.Whenusedalone,thetermtankmeansatank-container,portabletank,demountabletankorfixedtankasdefinedinthispart,includingtanksformingelementsofbattery-vehiclesorMEGCs(seealso‘Demountabletank’,‘Fixedtank’,‘Portabletank’and‘Multiple-elementgascontainer’).NOTE:Forportabletanks,see6.7.4.1.Tank-containermeansanarticleoftransportequipmentmeetingthedefinitionofacontainer,andcomprisingashellanditemsofequipment,includingtheequipmenttofacilitatemovementofthetank-containerwithoutsignificantchangeofattitude,usedforthecarriageofgases,liquid,powderyorgranularsubstancesandhavingacapacityofmorethan0.45m3(450litres).NOTE:IBCswhichmeettherequirementsofChapter6.5arenotconsideredtobetank-containers.Tank-container/portabletankoperatormeansanyenterpriseinwhosenamethetank-container/portabletankisregistered.Tankswapbodyisconsideredtobeatank-container.Tank-vehiclemeansavehiclebuilttocarryliquids,gasesorpowderyorgranularsubstancesandcomprisingoneormorefixedtanks.Inadditiontothevehicleproper,ortheunitsofrunninggearusedinitsstead,atank-vehiclecomprisesoneormoreshells,theiritemsofequipmentandthefittingsforattachingthemtothevehicleortotherunning-gearunits.Technical/biologicalnamemeansanamecurrentlyusedinscientificandtechnicalhandbooks,journalsandtexts.Tradenamesshallnotbeusedforthispurpose.Testpressuremeansthehighesteffectivepressurewhicharisesinthetankduringthepressuretest(seealso‘Calculationpressure’,‘Dischargepressure’,‘Fillingpressure’and‘Maximumworkingpressure(gaugepressure)’).NOTE:Forportabletanks,seeChapter6.7.Transportunitmeansamotorvehiclewithoutanattachedtrailer,oracombinationconsistingofamotorvehicleandanattachedtrailer.Tray(Class1)meansasheetofmetal,plastics,fibreboardorothersuitablematerialwhichisplacedintheinner,intermediateorouterpackagingandachievesaclose-fitinsuchpackaging.Thesurfaceofthetraymaybeshapedsothatpackagingsorarticlescanbeinserted,heldsecureandseparatedfromeachother.Tube(Class2)meansaseamlesstransportablepressurereceptacleofacapacityexceeding150litresandofnotmorethan5000litres.UUndertaking,see‘Enterprise’.UNModelRegulationsmeanstheModelRegulationsannexedtothe11threvisededitionoftheRecommendationsontheTransportofDangerousGoodspublishedbytheUnitedNations(ST/SG/AC.10/1/Rev.11).UNNomeansthefour-figureidentificationnumberofthesubstanceorarticletakenfromtheUNModelRegulations.VVacuum-operatedwastetankmeansafixedordemountabletankprimarilyusedforthecarriageofdangerouswastes,withspecialconstructionalfeaturesand/orequipmenttofacilitatetheloadingandunloadingofwastesasspecifiedinChapter6.10.AtankwhichfullycomplieswiththerequirementsofChapter6.7or6.8isnotconsideredtobeavacuum-operatedwastetank.Vacuumvalvemeansaspring-loadeddevicewhichisactivatedautomaticallybypressurethepurposeofwhichistoprotectthetankagainstunacceptablenegativeinternalpressure.Vehiclesee‘Battery-vehicle’,‘Closedvehicle’,‘Openvehicle’,‘Sheetedvehicle’and‘Tank-vehicle’.WWastesmeanssubstances,solutions,mixturesorarticlesforwhichnodirectuseisenvisagedbutwhicharetransportedforreprocessing,dumping,eliminationbyincinerationorothermethodsofdisposal.Woodenbarrelmeansapackagingmadeofnaturalwood,ofroundcross-section,havingconvexwalls,consistingofstavesandheadsandfittedwithhoops.WoodenIBCmeansarigidorcollapsiblewoodenbody,togetherwithaninnerliner(butnoinnerpackaging)andappropriateserviceandstructuralequipment.Wovenplastics(forflexibleIBCs)meansamaterialmadefromstretchtapesormonofilamentsofsuitableplasticsmaterial.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/171.2.2.Unitsofmeasurement1.2.2.1.ThefollowingunitsofmeasurementareapplicableinthisDirective(a):MeasurementofSIUnit(b)AcceptablealternativeunitRelationshipbetweenunitsLengthm(metre)Aream2(squaremetre)Volumem3(cubicmetre)1(c)(litre)1l=10-3m3Times(second)min.(minute)1min.=60sh(hour)1h=3600sd(day)1d=86400sMasskg(kilogram)g(gramme)1g=10-3kgt(ton)1t=103kgMassdensitykg/m3kg/l1kg/l=103kg/m3TemperatureK(kelvin)°C(degreeCelsius)0°C=273,15KTemperaturedifferenceK(kelvin)°C(degreeCelsius)1°C=1KForceN(newton)1N=1kg.m/s2PressurePa(pascal)bar(bar)1Pa=1N/m21bar=105PaStressN/m2N/mm21N/mm2=1MPaWorkkWh(kilowatthours)1kWh=3,6MJEnergyJ(joule)1J=1N.m=1W.sQuantityofheateV(electronvolt)1eV=0,1602.10-18JPowerW(watt)1W=1J/s=1N.m/sKinematicviscositym2/smm2/s1mm2/s=10-6m2/sDynamicviscosityPa.smPa.s1mPa.s=10-3Pa.sActivityBq(becquerel)DoseequivalentSv(sievert)(a)ThefollowingroundfiguresareapplicablefortheconversionoftheunitshithertousedintoSIUnits.Force1kg=9,807N1N=0,102kgStress1kg/mm2=9,807N/mm21N/mm2=0,102kg/mm2Pressure1Pa=1N/m2=10-5bar=1,02.10-5kg/cm2=0,75.10-2torr1bar=105Pa=1,02kg/cm2=750torr1kg/cm2=9,807.104Pa=0,9807bar=736torr1torr=1,33.102Pa=1,33.10-3bar=1,36.10-3kg/cm2Energy,Work,Quantityofheat1J=1Nm=0,278.10-6kWh=0,102kgm=0,239.10-3kcal1kWh=3,6.106J=367.103kgm=860kcal1kgm=9,807J=2,72.10-6kWh=2,34.10-3kcal1kcal=4,19.103J=1,16.10-3kWh=427kgmPower1W=0,102kgm/s=0,86kcal/h1kgm/s=9,807W=8,43kcal/h1kcal/h=1,16W=0,119kgm/sKinematicviscosity1m2/s=104St(stokes)1St=10-4m2/sDynamicviscosity1Pa.s=1Ns/m2=10P(poise)=0,102kgs/m21P=0,1Pa.s=0,1Ns/m2=1,02.10-2kgs/m21kgs/m2=9,807Pa.s=9,807Ns/m2=98,07P(b)TheInternationalSystemofUnits(SI)istheresultofdecisionstakenattheGeneralConferenceonWeightsandMeasures(Address:PavillondeBreteuil,ParcdeSt-Cloud,F-92310Sèvres).(c)Theabbreviation‘L’forlitremayalsobeusedinplaceoftheabbreviation‘l’whenatypewritercannotdistinguishbetweenfigure‘1’andletter‘l’.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/18Thedecimalmultiplesandsubmultiplesofaunitmaybeformedbyprefixesorsymbols,havingthefollowingmeanings,placedbeforethenameorsymboloftheunit:FactorPrefixSymbol1000000000000000000=1018quintillionexaE1000000000000000=1015quadrillionpetaP1000000000000=1012trillionteraT1000000000=109billiongigaG1000000=106millionmegaM1000=103thousandkilok100=102hundredhectoh10=101tendecada0,1=10-1tenthdecid0,01=10-2hundredthcentic0,001=10-3thousandthmillim0,000001=10-6millionthmicroμ0,000000001=10-9billionthnanon0,000000000001=10-12trillionthpicop0,000000000000001=10-15quadrillionthfemtof0,000000000000000001=10-18quintillionthattoaNOTE:109=1billionisUnitedNationsusageinEnglish.Byanalogy,sois10-9=1billionth.1.2.2.2.Unlessexpresslystatedotherwise,thesign‘%’inthisDirectiverepresents:(a)inthecaseofmixturesofsolidsorofliquids,andalsointhecaseofsolutionsandofsolidswettedbyaliquid,apercentagemassbasedonthetotalmassofthemixture,thesolutionorthewettedsolid;(b)inthecaseofmixturesofcompressedgases,whenfilledbypressure,theproportionofthevolumeindicatedasapercentageofthetotalvolumeofthegaseousmixture,or,whenfilledbymass,theproportionofthemassindicatedasapercentageofthetotalmassofthemixture;(c)inthecaseofmixturesofliquefiedgasesandgasesdissolvedunderpressure,theproportionofthemassindicatedasapercentageofthetotalmassofthemixture.1.2.2.3.Pressuresofallkindsrelatingtoreceptacles(suchastestpressure,internalpressure,safetyvalveopeningpressure)arealwaysindicatedingaugepressure(pressureinexcessofatmosphericpressure);however,thevapourpressureofsubstancesisalwaysexpressedinabsolutepressure.1.2.2.4.WherethisDirectivespecifiesadegreeoffillingforreceptacles,thisisalwaysrelatedtoareferencetemperatureofthesubstancesof15°C,unlesssomeothertemperatureisindicated.CHAPTER1.3Trainingofpersonsinvolvedinthecarriageofdangerousgoods1.3.1.ScopeandapplicabilityPersonsemployedbytheparticipantsreferredtoinChapter1.4,whosedutiesconcernthecarriageofdangerousgoods,shallreceivetrainingintherequirementsgoverningthecarriageofsuchgoodsappropriatetotheirresponsibilitiesandduties.NOTES:1.Withregardtothetrainingforthesafetyadviser,see1.8.3.2.Withregardtothetrainingofthevehiclecrew,seeChapter8.2.1.3.2.NatureofthetrainingThetrainingshalltakethefollowingform,appropriatetotheresponsibilityanddutiesoftheindividualconcerned.1.3.2.1.GeneralawarenesstrainingPersonnelshallbefamiliarwiththegeneralrequirementsoftheprovisionsforthecarriageofdangerousgoods.1.3.2.2.Function-specifictrainingPersonnelshallreceivedetailedtraining,commensuratedirectlywiththeirdutiesandresponsibilitiesintherequirementsoftheregulationsconcerningthecarriageofdangerousgoods.Wherethecarriageofdangerousgoodsinvolvesamultimodaltransportoperation,thepersonnelshallbemadeawareoftherequirementsconcerningothertransportmodes.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/191.3.2.3.SafetytrainingCommensuratewiththedegreeofriskofinjuryorexposurearisingfromanincidentinvolvingthecarriageofdangerousgoods,includingloadingandunloading,personnelshallreceivetrainingcoveringthehazardsanddangerspresentedbydangerousgoods.Thetrainingprovidedshallaimtomakepersonnelawareofthesafehandlingandemergencyresponseprocedures.1.3.2.4.TrainingforClass7ForthepurposeofClass7,personnelshallreceiveappropriatetrainingconcerningtheradiationhazardsinvolvedandtheprecautionstobeobservedinordertoensurerestrictionoftheirexposureandthatofotherpersonswhomightbeaffectedbytheiractions.1.3.3.DocumentationDetailsofallthetrainingundertakenshallbekeptbyboththeemployerandtheemployeeandshallbeverifieduponcommencinganewemployment.Thetrainingshallbeperiodicallysupplementedwithrefreshertrainingtotakeaccountofchangesinregulations.CHAPTER1.4Safetyobligationsoftheparticipants1.4.1.Generalsafetymeasures1.4.1.1.Theparticipantsinthecarriageofdangerousgoodsshalltakeappropriatemeasuresaccordingtothenatureandtheextentofforeseeabledangers,soastoavoiddamageorinjuryand,ifnecessary,tominimisetheireffects.Theyshall,inallevents,complywiththerequirementsofthisDirectiveintheirrespectivefields.1.4.1.2.Whenthereisanimmediateriskthatpublicsafetymaybejeopardised,theparticipantsshallimmediatelynotifytheemergencyservicesandshallmakeavailabletothemtheinformationtheyrequiretotakeaction.1.4.1.3.ThisDirectivemayspecifycertainoftheobligationsfallingtothevariousparticipants.IfaMemberStateconsidersthatnolesseningofsafetyisinvolved,itmayinitsdomesticlegislationtransfertheobligationsfallingtoaspecificparticipanttooneorseveralotherparticipants,providedthattheobligationsof1.4.2and1.4.3aremet.ThesederogationsshallbecommunicatedbytheMemberStatetotheSecretariatoftheUnitedNationsEconomicCommissionforEuropewhichwillbringthemtotheattentionoftheMemberStates.Therequirementsof1.2.1,1.4.2and1.4.3concerningthedefinitionsofparticipantsandtheirrespectiveobligationsshallnotaffecttheprovisionsofdomesticlawconcerningthelegalconsequences(criminalnature,liability,etc.)stemmingfromthefactthattheparticipantinquestionise.g.alegalentity,aself-employedworker,anemployeroranemployee.1.4.2.Obligationsofthemainparticipants1.4.2.1.Consignor1.4.2.1.1.TheconsignorofdangerousgoodsisrequiredtohandoverforcarriageonlyconsignmentswhichconformtotherequirementsofthisDirective.Inthecontextof1.4.1,heshallinparticular:(a)ascertainthatthedangerousgoodsareclassifiedandauthorisedforcarriageinaccordancewiththisDirective;(b)furnishthecarrierwithinformationanddataand,ifnecessary,therequiredtransportdocumentsandaccompanyingdocuments(authorisations,approvals,notifications,certificates,etc.),takingintoaccountinparticulartherequirementsofChapter5.4andofthetablesinPart3;(c)useonlypackagings,largepackagings,intermediatebulkcontainers(IBCs)andtanks(tank-vehicles,demountabletanks,battery-vehicles,MEGCs,portabletanksandtank-containers)approvedforandsuitedtothecarriageofthesubstancesconcernedandbearingthemarkingsprescribedbythisDirective;(d)complywiththerequirementsonthemeansofdispatchandonforwardingrestrictions;(e)ensurethatevenemptyuncleanedandnotdegassedtanks(tank-vehicles,demountabletanks,battery-vehicles,MEGCs,portabletanksandtank-containers)oremptyuncleanedvehiclesandlargeandsmallbulkcontainersareappropriatelymarkedandlabelledandthatemptyuncleanedtanksareclosedandpresentthesamedegreeofleakproofnessasiftheywerefull.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/201.4.2.1.2.Iftheconsignorusestheservicesofotherparticipants(packer,loader,filler,etc.),heshalltakeappropriatemeasurestoensurethattheconsignmentmeetstherequirementsofthisDirective.Hemay,however,inthecaseof1.4.2.1.1(a),(b),(c)and(e),relyontheinformationanddatamadeavailabletohimbyotherparticipants.1.4.2.1.3.Whentheconsignoractsonbehalfofathirdparty,thelattershallinformtheconsignorinwritingthatdangerousgoodsareinvolvedandmakeavailabletohimalltheinformationanddocumentsheneedstoperformhisobligations.1.4.2.2.Carrier1.4.2.2.1.Inthecontextof1.4.1,whereappropriate,thecarriershallinparticular:(a)ascertainthatthedangerousgoodstobecarriedauthorisedforcarriageinaccordancewiththisDirective;(b)ascertainthattheprescribeddocumentationisonboardthetransportunit;(c)ascertainvisuallythatthevehiclesandloadshavenoobviousdefects,leakagesorcracks,missingequipment,etc.;(d)ascertainthatthedateofthenexttestfortank-vehicles,battery-vehicles,fixedtanks,demountabletanks,portabletanks,tank-containersandMEGCshasnotexpired;(e)verifythatthevehiclesarenotoverloaded;(f)ascertainthatthedangerlabelsandmarkingsprescribedforthevehicleshavebeenaffixed;(g)ascertainthattheequipmentprescribedinthewritteninstructionsforthedriverisonboardthevehicle.Whereappropriate,thisshallbedoneonthebasisofthetransportdocumentsandaccompanyingdocuments,byavisualinspectionofthevehicleorthecontainersand,whereappropriate,theload.1.4.2.2.2.Thecarriermay,however,inthecaseof1.4.2.2.1(a),(b),(e)and(f),relyoninformationanddatamadeavailabletohimbyotherparticipants.1.4.2.2.3.IfthecarrierobservesaninfringementoftherequirementsofthisDirective,inaccordancewith1.4.2.2.1,heshallnotforwardtheconsignmentuntilthematterhasbeenrectified.1.4.2.2.4.If,duringthejourney,aninfringementwhichcouldjeopardisethesafetyoftheoperationisobserved,theconsignmentshallbehaltedassoonaspossiblebearinginmindtherequirementsoftrafficsafety,ofthesafeimmobilisationoftheconsignment,andofpublicsafety.Thetransportoperationmayonlybecontinuedoncetheconsignmentcomplieswithapplicableregulations.Thecompetentauthority(ies)concernedbytherestofthejourneymaygrantanauthorisationtopursuethetransportoperation.Incasetherequiredcompliancecannotbeachievedandnoauthorisationisgrantedfortherestofthejourney,thecompetentauthority(ies)shallprovidethecarrierwiththenecessaryadministrativeassistance.Thesameshallapplyincasethecarrierinformsthis/thesecompetentauthority(ies)thatthedangerousnatureofthegoodscarriedwasnotcommunicatedtohimbytheconsignorandthathewishes,byvirtueofthelawapplicableinparticulartothecontractofcarriage,tounload,destroyorrenderthegoodsharmless.1.4.2.3.Consignee1.4.2.3.1.Theconsigneehastheobligationnottodeferacceptanceofthegoodswithoutcompellingreasonsandtoverify,afterunloading,thattherequirementsofthisDirectiveconcerninghimhavebeencompliedwith.Inthecontextof1.4.1,heshallinparticular:(a)carryoutinthecasesprovidedforbythisDirectivetheprescribedcleaninganddecontaminationofthevehiclesandcontainers;(b)ensurethatthecontainersoncecompletelyunloaded,cleanedanddecontaminated,nolongerbeardangermarkingsconformingtoChapter5.3.1.4.2.3.2.Iftheconsigneemakesuseoftheservicesofotherparticipants(unloader,cleaner,decontaminationfacility,etc.)heshalltakeappropriatemeasurestoensurethattherequirementsofthisDirectivehavebeencompliedwith.1.4.2.3.3.IftheseverificationsbringtolightaninfringementoftherequirementsofthisDirective,theconsigneeshallreturnthecontainertothecarrieronlyaftertheinfringementhasbeenremedied.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/211.4.3.ObligationsoftheotherparticipantsAnon-exhaustivelistoftheotherparticipantsandtheirrespectiveobligationsisgivenbelow.TheobligationsoftheotherparticipantsflowfromSection1.4.1insofarastheyknoworshouldhaveknownthattheirdutiesareperformedaspartofatransportoperationsubjecttothisDirective.1.4.3.1.Loader1.4.3.1.1.Inthecontextof1.4.1,theloaderhasthefollowingobligationsinparticular:(a)heshallhandthedangerousgoodsovertothecarrieronlyiftheyareauthorisedforcarriageinaccordancewiththisDirective;(b)heshall,whenhandingoverforcarriagepackeddangerousgoodsoruncleanedemptypackagings,checkwhetherthepackagingisdamaged.Heshallnothandoverapackagethepackagingofwhichisdamaged,especiallyifitisnotleakproof,andthereareleakagesorthepossibilityofleakagesofthedangeroussubstance,untilthedamagehasbeenrepaired;thisobligationalsoappliestoemptyuncleanedpackagings;(c)heshall,whenloadingdangerousgoodsinavehicle,oralargeorsmallcontainer,complywiththespecialrequirementsconcerningloadingandhandling;(d)heshall,afterloadingdangerousgoodsintoacontainercomplywiththerequirementsconcerningdangermarkingsconformingtoChapter5.3;(e)heshall,whenloadingpackages,complywiththeprohibitionsonmixedloadingtakingintoaccountdangerousgoodsalreadyinthevehicleorlargecontainerandrequirementsconcerningtheseparationoffoodstuffs,otherarticlesofconsumptionoranimalfeedstuffs.1.4.3.1.2.Theloadermay,however,inthecaseof1.4.3.1.1(a),(d)and(e),relyoninformationanddatamadeavailabletohimbyotherparticipants.1.4.3.2.PackerInthecontextof1.4.1,thepackershallcomplywithinparticular:(a)therequirementsconcerningpackingconditions,ormixedpackingconditionsand,(b)whenhepreparespackagesforcarriage,therequirementsconcerningmarkingandlabellingofthepackages.1.4.3.3.FillerInthecontextof1.4.1,thefillerhasthefollowingobligationsinparticular:(a)heshallascertainpriortothefillingoftanksthatboththeyandtheirequipmentaretechnicallyinasatisfactorycondition;(b)heshallascertainthatthedateofthenexttestfortank-vehicles,battery-vehicles,demountabletanks,portabletanks,tank-containersandMEGCshasnotexpired;(c)heshallonlyfilltankswiththedangerousgoodsauthorisedforcarriageinthosetanks;(d)heshall,infillingthetank,complywiththerequirementsconcerningdangerousgoodsinadjoiningcompartments;(e)heshall,duringthefillingofthetank,observethemaximumpermissibledegreeoffillingorthemaximumpermissiblemassofcontentsperlitreofcapacityforthesubstancebeingfilled;(f)heshall,afterfillingthetank,checktheleakproofnessoftheclosingdevices;(g)heshallensurethatnodangerousresidueofthefillingsubstanceadherestotheoutsideofthetanksfilledbyhim;(h)heshall,inpreparingthedangerousgoodsforcarriage,ensurethattheorangeplatesandplacardsorlabelsprescribedareaffixedonthetanks,onthevehiclesandonthelargeandsmallcontainersforcarriageinbulkinaccordancewiththerequirements.1.4.3.4.Tank-container/portabletankoperatorInthecontextof1.4.1,thetank-container/portabletankoperatorshallinparticular:(a)ensurecompliancewiththerequirementsforconstruction,equipment,testsandmarking;(b)ensurethatthemaintenanceofshellsandtheirequipmentiscarriedoutinsuchawayastoensurethat,undernormaloperatingconditions,thetank-container/portabletanksatisfiestherequirementsofthisDirectiveuntilthenextinspection;(c)haveanexceptionalcheckmadewhenthesafetyoftheshelloritsequipmentisliabletobeimpairedbyarepair,analterationoranaccident.1.4.3.5.(Reserved)OfficialJournaloftheEuropeanUnionEN26.1.2004L18/22CHAPTER1.5Derogations1.5.1.Temporaryderogations1.5.1.1.ForthepurposeofadaptingtherequirementsofthisDirectivetotechnologicalandindustrialdevelopments,thecompetentauthoritiesoftheMemberStatesmayagreedirectlyamongthemselvestoauthorisecertaintransportoperationsintheirterritoriesbytemporaryderogationfromtherequirementsofthisDirective,providedthatsafetyisnotcompromisedthereby.NOTE:‘Specialarrangement’inaccordancewith1.7.4isnotconsideredtobeatemporaryderogationinaccordancewiththissection.1.5.1.2.Theperiodofvalidityofthetemporaryderogationshallnotbemorethanfiveyearsfromthedateofitsentryintoforce.ThetemporaryderogationshallautomaticallyceaseasfromthedateoftheentryintoforceofarelevantamendmenttothisDirective.1.5.1.3.TransportoperationsonthebasisoftemporaryderogationsshallconstitutetransportoperationsinthesenseofthisDirective.1.5.2.(Reserved)CHAPTER1.6Transitionalmeasures1.6.1.General1.6.1.1.Unlessotherwiseprovided,thesubstancesandarticlesofthisDirectivemaybecarrieduntil31December2002inaccordancewiththerequirementsofthisDirectiveapplicableupto30June2001.1.6.1.2.Thedangerlabelswhichuntil31December1998conformedtothemodelsprescribeduptothatdatemaybeuseduntilstocksareexhausted.1.6.1.3.SubstancesandarticlesofClass1,belongingtothearmedforcesofaMemberState,thatwerepackagedpriorto1January1990inaccordancewiththerequirementsofADRineffectatthattimemaybecarriedafter31December1989providedthepackagingsmaintaintheirintegrityandaredeclaredinthetransportdocumentasmilitarygoodspackagedpriorto1January1990.Theotherrequirementsapplicableasfrom1January1990forthisclassshallbecompliedwith.1.6.1.4.SubstancesandarticlesofClass1thatwerepackagedbetween1January1990and31December1996inaccordancewiththerequirementsofADRineffectatthattimemaybecarriedafter31December1996,providedthepackagingsmaintaintheirintegrityandaredeclaredinthetransportdocumentasgoodsofClass1packagedbetween1January1990and31December1996.1.6.1.5.(Reserved)1.6.2.ReceptaclesforClass21.6.2.1.Receptaclesbuiltbefore1January1997andwhichdonotconformtotherequirementsofthisDirectiveapplicableasfrom1January1997,butthecarriageofwhichwaspermittedundertherequirementsofADRapplicableupto31December1996,maycontinuetobetransportedafterthatdateiftheperiodictestrequirementsinpackinginstructionsP200andP203arecompliedwith.1.6.2.2.Cylindersinaccordancewiththedefinitionin1.2.1whichweresubmittedtoaninitialinspectionorperiodicinspectionbefore1January1997maybetransportedemptyanduncleanedwithoutalabeluntilthedateofthenextrefillingorthenextperiodicinspection.1.6.3.Fixedtanks(tank-vehicles),demountabletanksandbattery-vehicles1.6.3.1.Fixedtanks(tank-vehicles),demountabletanksandbattery-vehiclesbuiltbeforetheentryintoforceoftherequirementsapplicableasfrom1October1978maybekeptinserviceiftheequipmentoftheshellmeetstherequirementsofChapter6.8.Thethicknessoftheshellwall,exceptinthecaseofshellsintendedforthecarriageofrefrigeratedliquefiedgasesofClass2,shallbeappropriatetoacalculationpressureofnotlessthan0,4MPa(4bar)(gaugepressure)inthecaseofmildsteelorofnotlessthan200kPa(2bar)(gaugepressure)inthecaseofaluminiumandaluminiumalloys.Forotherthancircularcross-sectionsoftanks,thediametertobeusedasabasisforcalculationshallbethatofacirclewhoseareaisequaltothatoftheactualcross-sectionofthetank.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/231.6.3.2.Theperiodictestsforfixedtanks(tank-vehicles),demountabletanksandbattery-vehicleskeptinserviceunderthesetransitionalrequirementsshallbeconductedinaccordancewiththerequirementsof6.8.2.4and6.8.3.4andwiththepertinentspecialrequirementsforthevariousclasses.Unlesstheearlierrequirementsprescribedahighertestpressure,atestpressureof200kPa(2bar)(gaugepressure)shallsufficeforaluminiumshellsandaluminiumalloyshells.1.6.3.3.Fixedtanks(tank-vehicles),demountabletanksandbattery-vehicleswhichmeetthetransitionalrequirementsin1.6.3.1and1.6.3.2maybeuseduntil30September1993forthecarriageofthedangerousgoodsforwhichtheyhavebeenapproved.Thistransitionalperiodshallnotapplytofixedtanks(tank-vehicles),demountabletanksandbattery-vehiclesintendedforthecarriageofsubstancesofClass2,ortofixedtanks(tank-vehicles),demountabletanksandbattery-vehicleswhosewallthicknessanditemsofequipmentmeettherequirementsofChapter6.8.1.6.3.4.(a)Fixedtanks(tank-vehicles),demountabletanksandbattery-vehiclesconstructedbefore1May1985inaccordancewiththerequirementsofADRinforcebetween1October1978and30April1985butnotconformingtotherequirementsapplicableasfrom1May1985maycontinuetobeusedafterthatdate.(b)Fixedtanks(tank-vehicles),demountabletanksandbattery-vehicles,constructedbetween1May1985andtheentryintoforceoftherequirementsapplicableasfrom1January1988whichdonotconformtothoserequirementsbutwereconstructedaccordingtotherequirementsofADRinforceuntilthatdate,maycontinuetobeusedafterthatdate.1.6.3.5.Fixedtanks(tank-vehicles),demountabletanksandbattery-vehicles,constructedbefore1January1993inaccordancewiththerequirementsinforceupto31December1992butwhichdonotconformtotherequirementsapplicableasfrom1January1993maystillbeused.1.6.3.6.(a)Fixedtanks(tank-vehicles),demountabletanksandbattery-vehiclesconstructedbetween1January1978and31December1984,ifusedafter31December2004,shallconformtotherequirementsofmarginal211127(5),applicableasfrom1January1990,concerningshellthicknessandprotectionagainstdamage.(b)Fixedtanks(tank-vehicles),demountabletanksandbattery-vehiclesconstructedbetween1January1985and31December1989,ifusedafter31December2010,shallconformtotherequirementsofmarginal211127(5),applicableasfrom1January1990,concerningshellthicknessandprotectionagainstdamage.1.6.3.7.Fixedtanks(tank-vehicles),demountabletanksandbattery-vehiclesconstructedbefore1January1999inaccordancewiththerequirementsinforceupto31December1998butwhichdonot,however,conformtotherequirementsapplicableasfrom1January1999maystillbeused.1.6.3.8.Fixedtanks(tank-vehicles)demountabletanksandbattery-vehiclesintendedforthecarriageofsubstancesofClass2,whichwerebuiltpriorto1January1997,maycarrymarkingsconformingtotherequirementsapplicableupto31December1996,untilthenextperiodictest.However,forthepropershippingnamesrequiredin6.8.3.5.2or6.8.3.5.3,itisnotnecessarytotakeaccountofsubsequentadaptationsofthepropershippingnamesofthesegases,providedthatthepropershippingnameinforceappearsontheshellorontheplateatlatestafterthedatefollowingthenextperiodictest.1.6.3.9.(Reserved)1.6.3.10.Fixedtanks(tank-vehicles)anddemountabletanksconstructedbefore1January1995,whichwereintendedforthecarriageofsubstancesofUNNo3256,butwhichdonot,however,conformtotherequirementsapplicableasfrom1January1995,maystillbeuseduntil31December2004.1.6.3.11.Fixedtanks(tank-vehicles)anddemountabletanksconstructedbefore1January1997inaccordancewiththerequirementsinforceupto31December1996butwhichdonot,however,conformtotherequirementsofmarginals211332and211333applicableasfrom1January1997,maystillbeused.1.6.3.12.Fixedtanks(tank-vehicles)anddemountabletanksintendedforthecarriageofUNNo2401piperidineconstructedbefore1January1999inaccordancewiththerequirementsofmarginal211322inforceupto31December1998,butwhichdonot,however,conformtotherequirementsapplicableasfrom1January1999,maycontinuetobeuseduntil31December2004.1.6.3.13.Fixedtanks(tank-vehicles)anddemountabletanksintendedforthecarriageofsubstancesofUNNo3257constructedbefore1January1997whichdonothoweverconformtotherequirementsapplicableasfrom1January1997,maycontinuetobeuseduntil31December2006.1.6.3.14.(Reserved)OfficialJournaloftheEuropeanUnionEN26.1.2004L18/241.6.3.15.Fixedtanks(tank-vehicles)anddemountabletanksintendedforthecarriageofsubstanceswiththefollowingUNNos:1092,1098,1135,1143,1182,1199,1238,1251,1605,1647,1695,1809,2295,2337,2407,2438,2477,2487,2488,2558,2606,2644,2646,2686,3023,3289and3290,constructedbefore1January1997inaccordancewiththerequirementsinforceupto31December1996,butwhichdonotconformwiththerequirementsapplicableasfrom1January1997maycontinuetobeuseduntil31December2002.1.6.3.16.Battery-vehiclesfirstregisteredbefore1July1997whichdonotmeettherequirementsof9.2.2,maycontinuetobeuseduntil31December2004.1.6.3.17.(Reserved)1.6.3.18.Fixedtanks(tank-vehicles),demountabletanksandbattery-vehiclesconstructedbefore1January2003inaccordancewiththerequirementsinforceupto30June2001,butwhichdonot,however,conformtotherequirementsapplicableasfrom1July2001,maystillbeused.Assignmenttothetankcodeinthedesigntypeapprovalsandtherelevantmarkingsshallbecarriedoutpriorto1January2009.1.6.3.19.Fibre-reinforcedplastics(FRP)tanksFRPtankswhichhavebeenconstructedbefore1July2002inconformitywithadesigntypeapprovedbefore1July2001inaccordancewiththerequirementsofAppendixB.1cwhichwereinforceuntil30June2001maycontinuetobeuseduntiltheendoftheirlifetimeprovidedthatalltherequirementsinforceupto30June2001havebeenandcontinuetobecompliedwith.However,asfrom1July2001,nonewdesigntypemaybeapprovedinaccordancewiththerequirementsinforceuntil30June2001.1.6.4.Tank-containersandMEGCs1.6.4.1.Tank-containersconstructedbefore1January1988inaccordancewiththerequirementsinforceupto31December1987butwhichdonot,however,conformtotherequirementsapplicableasfrom1January1988,maystillbeused.1.6.4.2.Tank-containersconstructedbefore1January1993inaccordancewiththerequirementsinforceupto31December1992butwhichdonot,however,conformtotherequirementsapplicableasfrom1January1993,maystillbeused.1.6.4.3.Tank-containersconstructedbefore1January1999inaccordancewiththerequirementsinforceupto31December1998butwhichdonot,however,conformtotherequirementsapplicableasfrom1January1999,maystillbeused.1.6.4.4.(Reserved)1.6.4.5.Tank-containersintendedforthecarriageofsubstancesofClass2,whichwereconstructedbefore1January1997,maybearmarkingsconformingtotherequirementsapplicableupto31December1996untilthenextperiodictest.However,forthepropershippingnamesrequiredin6.8.3.5.2or6.8.3.5.3,itisnotnecessarytotakeaccountofsubsequentadaptationsofthepropershippingnamesofthesegases,providedthatthepropershippingnameinforceappearsontheshellorontheplateatlatestafterthedatefollowingthenextperiodictest.1.6.4.6.Tank-containerswhichwereintendedforthecarriageofsubstancesofUNNo3256,constructedbefore1January1995,butwhichdonot,however,conformwiththerequirementsapplicableasfrom1January1995,maystillbeuseduntil31December2004.1.6.4.7.Tank-containersconstructedbefore1January1997inaccordancewiththerequirementsinforceupto31December1996butwhichdonot,however,conformtotherequirementsofmarginals212332and212333applicableasfrom1January1997,maystillbeused.1.6.4.8.(Reserved)1.6.4.9.Tank-containersintendedforthecarriageofUNNo2401piperidine,builtbefore1January1999inaccordancewiththerequirementsofmarginal212322applicableupto31December1998,butwhichdonot,however,conformtotherequirementsapplicableasfrom1January1999,maycontinuetobeuseduntil31December2003.1.6.4.10.Tank-containerswhichwereintendedforthecarriageofsubstancesofUNNo3257,builtbefore1January1997,butwhichdonotconform,however,withtherequirementsapplicableasfrom1January1997,maystillbeuseduntil31December2006.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/251.6.4.11.Tank-containersintendedforthecarriageofsubstanceswiththefollowingUNNos:1092,1098,1135,1143,1182,1199,1238,1251,1605,1647,1695,1809,2295,2337,2407,2438,2477,2487,2488,2558,2606,2644,2646,2686,3023,3289and3290,constructedbefore1January1997inaccordancewiththerequirementsinforceupto31December1996,butwhichdonotconformtotherequirementsapplicableasfrom1January1997maycontinuetobeuseduntil31December2001.1.6.4.12.Tank-containersandMEGCsconstructedbefore1July2003inaccordancewiththerequirementsapplicableupto30June2001,butwhichdonot,however,conformtotherequirementsapplicableasfrom1July2001,maystillbeused.Assignmenttothetankcodesinthedesigntypeapprovalsandtherelevantmarkingsshallbecarriedoutpriorto1January2008.1.6.5.Vehicles1.6.5.1.Transportunitsintendedforthecarriageoftank-containersorportabletanksexceeding3000litrescapacityfirstregisteredbefore1July1997whichdonotcomplywiththerequirementsof9.1.2and9.2.2maycontinuetobeuseduntil31December2004.Thesetransportunitsshallbesubject,untilthatdate,totheprovisionsofmarginal10283whichwereinforceuntil31December1996,andmaybeissuedwithacertificateinaccordancewiththemodelshowninAppendixB.3applicableupto30June2001.1.6.5.2.Vehiclescarryingdemountabletanksandvehiclesintendedforthecarriageoftank-containersorportabletanksregisteredbefore1January1995,whichwereused,beforethatdate,forthecarriageofsubstancesofUNNo3256andwhichdonotfullycomplywiththerequirementsof9.2.2,9.2.3,9.2.5,and9.7.6maycontinuetobeuseduntil31December2004.Whenacertificateofapprovalisrequiredinaccordancewith9.1.2.1.2,thiscertificateshallbearamentionindicatingthatthevehiclehasbeenapprovedonthebasisof1.6.5.2.1.6.5.3.Vehiclescarryingdemountabletanksandvehiclesintendedforthecarriageoftank-containersorportabletanksregisteredbefore1January1997,whichwereused,beforethatdate,forthecarriageofsubstancesofUNNo3257andwhichdonotfullycomplywiththerequirementsof9.2.2,9.2.3,9.2.5,and9.7.6maycontinuetobeuseduntil31December2006.Whenacertificateofapprovalisrequiredinaccordancewith9.1.2.1.2,thiscertificateshallbearamentionindicatingthatthevehiclehasbeenapprovedonthebasisof1.6.5.3.1.6.5.4.Asregardstheconstructionofbasevehicles,therequirementsinforceupto30June2001maybeapplieduntil31December2002.1.6.6.Class71.6.6.1.Packagesnotrequiringcompetentauthorityapprovalofdesignunderthe1985and1985(asamended1990)editionsofIAEASafetySeriesNo6Exceptedpackages,industrialpackagestypeIP-1,typeIP-2andtypeIP-3andtypeApackagesthatdidnotrequireapprovalofdesignbythecompetentauthorityandwhichmeettherequirementsofthe1985or1985(asamended1990)EditionsofIAEARegulationsfortheSafeTransportofRadioactiveMaterial(IAEASafetySeriesNo6)maycontinuetobeusedsubjecttothemandatoryprogrammeofqualityassuranceinaccordancewiththerequirementsof1.7.3andtheactivitylimitsandmaterialrestrictionsof2.2.7.7.Anypackagingmodified,unlesstoimprovesafety,ormanufacturedafter31December2003,shallmeettherequirementsofthisDirective.Packagespreparedforcarriagenotlaterthan31December2003underthe1985or1985(asamended1990)EditionsofIAEASafetySeriesNo6maycontinueintransport.PackagespreparedforcarriageafterthisdateshallmeettherequirementsofthisDirective.1.6.6.2.Packagesapprovedunderthe1973,1973(asamended),1985and1985(asamended1990)editionsofIAEASafetySeriesNo61.6.6.2.1.Packagingsmanufacturedtoapackagedesignapprovedbythecompetentauthorityundertheprovisionsofthe1973or1973(asamended)EditionsofIAEASafetySeriesNo6maycontinuetobeused,subjecttomultilateralapprovalofpackagedesign,themandatoryprogrammeofqualityassuranceinaccordancewiththeapplicablerequirementsof1.7.3andtheactivitylimitsandmaterialrestrictionsof2.2.7.7.Nonewmanufactureofsuchpackagingshallbepermittedtocommence.Changesinthedesignofthepackagingorinthenatureorquantityoftheauthorisedradioactivecontentswhich,asdeterminedbythecompetentauthority,wouldsignificantlyaffectsafetyshallrequirethattherequirementsofthisDirectivebemet.Aserialnumberaccordingtotheprovisionof5.2.1.7.5shallbeassignedtoandmarkedontheoutsideofeachpackaging.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/261.6.6.2.2.Packagingsmanufacturedtoapackagedesignapprovedbythecompetentauthorityundertheprovisionsofthe1985or1985(asamended1990)EditionsofIAEASafetySeriesNo6maycontinuetobeuseduntil31December2003,subjecttothemandatoryprogrammeofqualityassuranceinaccordancewiththerequirementsof1.7.3andtheactivitylimitsandmaterialrestrictionsof2.2.7.7.Afterthisdateusemaycontinuesubject,additionally,tomultilateralapprovalofpackagedesign.Changesinthedesignofthepackagingorinthenatureorquantityoftheauthorisedradioactivecontentswhich,asdeterminedbythecompetentauthority,wouldsignificantlyaffectsafetyshallrequirethattherequirementsofthisDirectivebemet.Allpackagingsforwhichmanufacturebeginsafter31December2006shallmeettherequirementsofthisDirective.1.6.6.3.Specialformradioactivematerialapprovedunderthe1973,1973(asamended),1985and1985(asamended1990)EditionsofIAEASafetySeriesNo6Specialformradioactivematerialmanufacturedtoadesignwhichhadreceivedunilateralapprovalbythecompetentauthorityunderthe1973,1973(asamended),1985or1985(asamended1990)EditionsofIAEASafetySeriesNo6maycontinuetobeusedwhenincompliancewiththemandatoryprogrammeofqualityassuranceinaccordancewiththeapplicablerequirementsof1.7.3.Allspecialformradioactivematerialmanufacturedafter31December2003shallmeettherequirementsofthisDirective.1.6.6.4.ForthecarriageofClass7material,thetransitionalmeasuresof1.6.1.1shallbeapplicableupto31December2001only,exceptwithrespecttotheapplicationofChapters1.4and1.8forwhichtheyshallremainapplicableuntil31December2002.CHAPTER1.7GeneralrequirementsconcerningClass71.7.1.General1.7.1.1.ThisDirectiveestablishesstandardsofsafetywhichprovideanacceptablelevelofcontroloftheradiation,criticalityandthermalhazardstopersons,propertyandtheenvironmentthatareassociatedwiththecarriageofradioactivematerial.ThesestandardsarebasedontheIAEARegulationsfortheSafeTransportofRadioactiveMaterial(ST-1),IAEA,Vienna(1996).ExplanatorymaterialonST-1canbefoundin‘AdvisorymaterialfortheIAEAregulationsforthesafetransportofradioactivematerial(1996edition)’,SafetyStandardSeriesNoST-2,IAEA,Vienna(tobepublished).1.7.1.2.TheobjectiveofthisDirectiveistoprotectpersons,propertyandtheenvironmentfromtheeffectsofradiationduringthecarriageofradioactivematerial.Thisprotectionisachievedbyrequiring:(a)containmentoftheradioactivecontents;(b)controlofexternalradiationlevels;(c)preventionofcriticality;and(d)preventionofdamagecausedbyheat.Theserequirementsaresatisfiedfirstlybyapplyingagradedapproachtocontentslimitsforpackagesandvehiclesandtoperformancestandardsappliedtopackagedesignsdependinguponthehazardoftheradioactivecontents.Secondly,theyaresatisfiedbyimposingrequirementsonthedesignandoperationofpackagesandonthemaintenanceofpackagings,includingaconsiderationofthenatureoftheradioactivecontents.Finally,theyaresatisfiedbyrequiringadministrativecontrolsincluding,whereappropriate,approvalbycompetentauthorities.1.7.1.3.ThisDirectiveappliestothecarriageofradioactivematerialbyroadincludingcarriagewhichisincidentaltotheuseoftheradioactivematerial.Carriagecomprisesalloperationsandconditionsassociatedwithandinvolvedinthemovementofradioactivematerial;theseincludethedesign,manufacture,maintenanceandrepairofpackaging,andthepreparation,consigning,loading,carriageincludingin-transitstorage,unloadingandreceiptatthefinaldestinationofloadsofradioactivematerialandpackages.AgradedapproachisappliedtotheperformancestandardsinthisDirectivethatischaracterisedbythreegeneralseveritylevels:(a)routineconditionsofcarriage(incidentfree);(b)normalconditionsofcarriage(minormishaps);(c)accidentconditionsofcarriage.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/271.7.2.Radiationprotectionprogramme1.7.2.1.Thecarriageofradioactivematerialshallbesubjecttoaradiationprotectionprogrammewhichshallconsistofsystematicarrangementsaimedatprovidingadequateconsiderationofradiationprotectionmeasures.1.7.2.2.Thenatureandextentofthemeasurestobeemployedintheprogrammeshallberelatedtothemagnitudeandlikelihoodofradiationexposures.Theprogrammeshallincorporatetherequirementsin1.7.2.3,and1.7.2.4,CV33(1.1)and(1.4)of7.5.11andapplicableemergencyresponseprocedures.Programmedocumentsshallbeavailable,onrequest,forinspectionbytherelevantcompetentauthority.1.7.2.3.Protectionandsafetyshallbeoptimisedinorderthatthemagnitudeofindividualdoses,thenumberofpersonsexposed,andthelikelihoodofincurringexposureshallbekeptaslowasreasonablyachievable,economicandsocialfactorsbeingtakenintoaccount,anddosestopersonsshallbebelowtherelevantdoselimits.Astructuredandsystematicapproachshallbeadoptedandshallincludeconsiderationoftheinterfacesbetweencarriageandotheractivities.1.7.2.4.Foroccupationalexposuresarisingfromtransportactivities,whereitisassessedthattheeffectivedose:(a)ismostunlikelytoexceed1mSvinayear,nospecialworkpatterns,detailedmonitoring,doseassessmentprogrammesorindividualrecordkeepingshallberequired;(b)islikelytobebetween1mSvand6mSvinayear,adoseassessmentprogrammeviaworkplacemonitoringorindividualmonitoringshallbeconducted;(c)islikelytoexceed6mSvinayear,individualmonitoringshallbeconducted.Whenindividualmonitoringorworkplacemonitoringisconducted,appropriaterecordsshallbekept.1.7.3.QualityassuranceQualityassuranceprogrammesbasedoninternational,nationalorotherstandardsacceptabletothecompetentauthorityshallbeestablishedandimplementedforthedesign,manufacture,testing,documentation,use,maintenanceandinspectionofallspecialformradioactivematerial,lowdispersibleradioactivematerialandpackagesandforcarriageandin-transitstorageoperationstoensurecompliancewiththerelevantprovisionsofthisDirective.Certificationthatthedesignspecificationhasbeenfullyimplementedshallbeavailabletothecompetentauthority.Themanufacturer,consignororusershallbepreparedtoprovidefacilitiesforcompetentauthorityinspectionduringmanufactureanduseandtodemonstratetoanycognisantcompetentauthoritythat:(a)themanufacturingmethodsandmaterialsusedareinaccordancewiththeapproveddesignspecifications;and(b)allpackagingsareperiodicallyinspectedand,asnecessary,repairedandmaintainedingoodconditionsothattheycontinuetocomplywithallrelevantrequirementsandspecifications,evenafterrepeateduse.Wherecompetentauthorityapprovalisrequired,suchapprovalshalltakeintoaccountandbecontingentupontheadequacyofthequalityassuranceprogramme.1.7.4.Specialarrangement1.7.4.1.Specialarrangementshallmeanthoseprovisions,approvedbythecompetentauthority,underwhichconsignmentswhichdonotsatisfyalltherequirementsofthisDirectiveapplicabletoradioactivematerialmaybetransported.NOTE:Specialarrangementisnotconsideredtobeatemporaryderogationinaccordancewith1.5.1.1.7.4.2.ConsignmentsforwhichconformitywithanyprovisionapplicabletoClass7isimpracticableshallnotbetransportedexceptunderspecialarrangement.ProvidedthecompetentauthorityissatisfiedthatconformitywiththeClass7provisionsofthisDirectiveisimpracticableandthattherequisitestandardsofsafetyestablishedbythisDirectivehavebeendemonstratedthroughalternativemeansthecompetentauthoritymayapprovespecialarrangementtransportoperationsforsingleoraplannedseriesofmultipleconsignments.Theoveralllevelofsafetyincarriageshallbeatleastequivalenttothatwhichwouldbeprovidedifalltheapplicablerequirementshadbeenmet.Forinternationalconsignmentsofthistype,multilateralapprovalshallberequired.1.7.5.RadioactivematerialpossessingotherdangerouspropertiesInadditiontotheradioactiveandfissileproperties,anysubsidiaryriskofthecontentsofthepackage,suchasexplosiveness,flammability,pyrophoricity,chemicaltoxicityandcorrosiveness,shallalsobetakenintoaccountinthedocumentation,packing,labelling,marking,placarding,stowage,segregationandcarriage,inordertobeincompliancewithallrelevantprovisionsfordangerousgoodsofthisDirective.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/28CHAPTER1.8Checksandothersupportmeasurestoensurecompliancewithsafetyrequirements1.8.1.Administrativecontrolsofdangerousgoods1.8.1.1.ThecompetentauthoritiesoftheMemberStatesmay,ontheirnationalterritory,atanytime,conductspotcheckstoverifywhethertherequirementsconcerningthecarriageofdangerousgoodshavebeenmet.Thesechecksshall,however,bemadewithoutendangeringpersons,propertyortheenvironmentandwithoutmajordisruptionofroadservices.1.8.1.2.Participantsinthecarriageofdangerousgoods(Chapter1.4)shall,withoutdelay,inthecontextoftheirrespectiveobligations,providethecompetentauthoritiesandtheiragentswiththenecessaryinformationforcarryingoutthechecks.1.8.1.3.Thecompetentauthoritiesmayalso,forthepurposesofcarryingoutchecksonthepremisesoftheenterprisesparticipatinginthecarriageofdangerousgoods(Chapter1.4),makeinspections,consultthenecessarydocumentsandremovesamplesofdangerousgoodsorpackagingsforexamination,providedthatsafetyisnotjeopardisedthereby.Theparticipantsinthecarriageofdangerousgoods(Chapter1.4)shallalsomakethevehiclesorpartsofvehiclesandtheequipmentandinstallationsaccessibleforthepurposeofcheckingwherethisispossibleandreasonable.Theymay,iftheydeemnecessary,designateapersonfromtheenterprisetoaccompanytherepresentativeofthecompetentauthority.1.8.1.4.IfthecompetentauthoritiesobservethattherequirementsofthisDirectivehavenotbeenmet,theymayprohibitaconsignmentorinterruptatransportoperationuntilthedefectsobservedarerectified,ortheymayprescribeotherappropriatemeasures.Immobilisa-tionmaytakeplaceonthespotoratanotherplaceselectedbytheauthoritiesforsafetyreasons.Thesemeasuresshallnotcauseamajordisruptioninroadservices.1.8.2.Mutualadministrativesupport1.8.2.1.TheMemberStatesshallagreeonmutualadministrativesupportfortheimplementationofthisDirective.1.8.2.2.WhenaMemberStatehasreasonstoobservethatthesafetyofthecarriageofdangerousgoodsonitsterritoryiscompromisedasaresultofveryseriousorrepeatedinfringementsbyanenterprisewhichhasitsheadquartersontheterritoryofanotherMemberState,itshallnotifythecompetentauthoritiesofthisMemberStateofsuchinfringements.ThecompetentauthoritiesoftheMemberStateontheterritoryofwhichtheveryseriousorrepeatedinfringementswereobservedmayrequestthecompetentauthoritiesoftheMemberStateontheterritoryofwhichtheenterprisehasitsheadquarterstotakeappropriatemeasuresagainsttheoffender(s).Thetransmissionofdatareferringtopersonsshallnotbepermittedunlessitisnecessaryfortheprosecutionofveryseriousorrepeatedinfringements.1.8.2.3.TheauthoritiesnotifiedshallcommunicatetothecompetentauthoritiesoftheMemberStateontheterritoryofwhichtheinfringementswereobserved,themeasureswhichhave,ifnecessary,beentakenwithrespecttotheenterprise.1.8.3.SafetyadviserNOTE:TheprovisionsofSection1.8.3areonlyapplicableifthecompetentauthoritiesofthecountryorcountriestowhichthevariousparticipantsinatransportchainareaccountablehavetakenthenecessaryadministrativemeasurestoallowtheirimplementation.ThesemeasuresshallhavebeentakentoallowtheapplicationofSection1.8.3atlatestby1January2003.1.8.3.1.Eachundertaking,theactivitiesofwhichincludethecarriage,ortherelatedpacking,loading,fillingorunloading,ofdangerousgoodsbyroadshallappointoneormoresafetyadvisersforthecarriageofdangerousgoods,responsibleforhelpingtopreventtherisksinherentinsuchactivitieswithregardtopersons,propertyandtheenvironment.1.8.3.2.ThecompetentauthoritiesoftheMemberStatesmayprovidethattheserequirementsshallnotapplytoundertakings:(a)theactivitiesofwhichconcernquantitiesineachtransportunitsmallerthanthosereferredtoin1.1.3,2.2.7.1.2andinChapters3.3and3.4,or(b)themainorsecondaryactivitiesofwhicharenotthecarriageortherelatedloadingorunloadingofdangerousgoodsbutwhichoccasionallyengageinthenationalcarriageortherelatedloadingorunloadingofdangerousgoodsposinglittledangerorriskofpollution.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/291.8.3.3.Themaintaskoftheadvisershallbe,undertheresponsibilityoftheheadoftheundertaking,toseekbyallappropriatemeansandbyallappropriateaction,withinthelimitsoftherelevantactivitiesofthatundertaking,tofacilitatetheconductofthoseactivitiesinaccordancewiththerequirementsapplicableandinthesafestpossibleway.Withregardtotheundertaking'sactivities,theadviserhasthefollowingdutiesinparticular:—monitoringcompliancewiththerequirementsgoverningthecarriageofdangerousgoods,—advisinghisundertakingonthecarriageofdangerousgoods,—preparinganannualreporttothemanagementofhisundertakingoralocalpublicauthority,asappropriate,ontheundertaking=sactivitiesinthecarriageofdangerousgoods.Suchannualreportsshallbepreservedforfiveyearsandmadeavailabletothenationalauthoritiesattheirrequest.Theadviser'sdutiesalsoincludemonitoringthefollowingpracticesandproceduresrelatingtotherelevantactivitiesoftheundertaking:—theproceduresforcompliancewiththerequirementsgoverningtheidentificationofdangerousgoodsbeingtransported,—theundertaking=spracticeintakingaccount,whenpurchasingmeansoftransport,ofanyspecialrequirementsinconnectionwiththedangerousgoodsbeingtransported,—theproceduresforcheckingtheequipmentusedinconnectionwiththecarriage,loadingorunloadingofdangerousgoods,—thepropertrainingoftheundertaking'semployeesandthemaintenanceofrecordsofsuchtraining,—theimplementationofproperemergencyproceduresintheeventofanyaccidentorincidentthatmayaffectsafetyduringthecarriage,loadingorunloadingofdangerousgoods,—investigatingand,whereappropriate,preparingreportsonseriousaccidents,incidentsorseriousinfringementsrecordedduringthecarriage,loadingorunloadingofdangerousgoods,—theimplementationofappropriatemeasurestoavoidtherecurrenceofaccidents,incidentsorseriousinfringements,—theaccounttakenofthelegalprescriptionsandspecialrequirementsassociatedwiththecarriageofdangerousgoodsinthechoiceanduseofsubcontractorsorthirdparties,—verificationthatemployeesinvolvedinthecarriage,loadingorunloadingofdangerousgoodshavedetailedoperationalproceduresandinstructions,—theintroductionofmeasurestoincreaseawarenessoftherisksinherentinthecarriage,loadingandunloadingofdangerousgoods,—theimplementationofverificationprocedurestoensurethepresenceonboardmeansoftransportofthedocumentsandsafetyequipmentwhichmustaccompanytransportandthecomplianceofsuchdocumentsandequipmentwiththeregulations,—theimplementationofverificationprocedurestoensurecompliancewiththerequirementsgoverningloadingandunloading.1.8.3.4.Theadvisermayalsobetheheadoftheundertaking,apersonwithotherdutiesintheundertaking,orapersonnotdirectlyemployedbythatundertaking,providedthatthatpersoniscapableofperformingthedutiesofadviser.1.8.3.5.Eachundertakingconcernedshall,onrequest,informthecompetentauthorityorthebodydesignatedforthatpurposebyeachMemberStateoftheidentityofitsadviser.1.8.3.6.Wheneveranaccidentaffectspersons,propertyortheenvironmentorresultsindamagetopropertyortheenvironmentduringcarriage,loadingorunloadingcarriedoutbytheundertakingconcerned,theadvisershall,aftercollectingalltherelevantinformation,prepareanaccidentreporttothemanagementoftheundertakingortoalocalpublicauthority,asappropriate.Thatreportshallnotreplaceanyreportbythemanagementoftheundertakingwhichmightberequiredunderanyotherinternationalornationallegislation.1.8.3.7.Anadvisershallholdavocationaltrainingcertificate,validfortransportbyroad.ThatcertificateshallbeissuedbythecompetentauthorityorthebodydesignatedforthatpurposebyeachMemberState.1.8.3.8.Toobtainacertificate,acandidateshallundergotrainingandpassanexaminationapprovedbythecompetentauthorityoftheMemberState.1.8.3.9.Themainaimsofthetrainingshallbetoprovidecandidateswithsufficientknowledgeoftherisksinherentinthecarriageofdangerousgoods,ofthelaws,regulationsandadministrativeprovisionsapplicabletothemodesoftransportconcernedandofthedutieslistedin1.8.3.3.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/301.8.3.10.Theexaminationshallbeorganisedbythecompetentauthorityorbyanexaminingbodydesignatedbythecompetentauthority.Theexaminingbodyshallbedesignatedinwriting.Thisapprovalmaybeoflimiteddurationandshallbebasedonthefollowingcriteria:—competenceoftheexaminingbody,—specificationsoftheformoftheexaminationstheexaminingbodyisproposing,—measuresintendedtoensurethatexaminationsareimpartial,—independenceofthebodyfromallnaturalorlegalpersonsemployingsafetyadvisers.1.8.3.11.Theaimoftheexaminationistoascertainwhethercandidatespossessthenecessarylevelofknowledgetocarryoutthedutiesincumbentuponasafetyadviseraslistedin1.8.3.3,forthepurposeofobtainingthecertificateprescribedinsub-section1.8.3.7,anditshallcoveratleastthefollowingsubjects:(a)knowledgeofthetypesofconsequenceswhichmaybecausedbyanaccidentinvolvingdangerousgoodsandknowledgeofthemaincausesofaccidents;(b)requirementsundernationallaw,internationalconventionsandagreements,withregardtothefollowinginparticular:—classificationofdangerousgoods(procedureforclassifyingsolutionsandmixtures,structureofthelistofsubstances,classesofdangerousgoodsandprinciplesfortheirclassification,natureofdangerousgoodstransported,physical,chemicalandtoxicologicalpropertiesofdangerousgoods),—generalpackingprovisions,provisionsfortanksandtank-containers(types,code,marking,construction,initialandperiodicinspectionandtesting),—markingandlabelling,placardingandorangeplatesmarking(markingandlabellingofpackages,placingandremovalofplacardsandorangeplates),—particularsintransportdocuments(informationrequired),—methodofconsignmentandrestrictionsondispatch(fullload,carriageinbulk,carriageinintermediatebulkcontainers,carriageincontainers,carriageinfixedordemountabletanks),—transportofpassengers,—prohibitionsandprecautionsrelatingtomixedloading,—segregationofgoods,—limitationofthequantitiescarriedandquantitiesexemptions,—handlingandstowage(loadingandunloading,fillingratios,stowageandsegregation),—cleaningand/ordegassingbeforeloadingandafterunloading,—crews,vocationaltraining,—vehicledocuments(transportdocument,instructionsinwriting,vehicleapprovalcertificate,drivertrainingcertificate,copiesofanyderogations,otherdocuments),—instructionsinwriting(implementationoftheinstructionsandcrewprotectionequipment),—supervisionrequirements(parking),—trafficregulationsandrestrictions,—operationaldischargesoraccidentalleaksofpollutants,—requirementsrelatingtotransportequipment.1.8.3.12.Theexaminationshallconsistofawrittentestwhichmaybesupplementedbyanoralexamination.Thewrittenexaminationshallconsistoftwoparts:(a)candidatesshallreceiveaquestionnaire.Itshallincludeatleast20openquestionscoveringatleastthesubjectsmentionedinthelistin1.8.3.11.However,multiplechoicequestionsmaybeused.Inthiscase,twomultiplechoicequestionscountasoneopenquestion.Amongstthesesubjectsparticularattentionshallbepaidtothefollowingsubjects:—generalpreventiveandsafetymeasures,—classificationofdangerousgoods,—generalpackingprovisions,includingtanks,tank-containers,tank-vehicles,etc.,—dangermarkingsandlabels,—informationintransportdocument,—handlingandstowage,—crew,vocationaltraining,—vehicledocumentsandtransportcertificates,—instructionsinwriting,—requirementsconcerningtransportequipment;OfficialJournaloftheEuropeanUnionEN26.1.2004L18/31(b)candidatesshallundertakeacasestudyinkeepingwiththedutiesoftheadviserreferredtoin1.8.3.3,inordertodemonstratethattheyhavethenecessaryqualificationstofulfilthetaskofadviser.1.8.3.13.TheMemberStatesmaydecidethatcandidateswhointendworkingforundertakingsspecialisinginthecarriageofcertaintypesofdangerousgoodsneedonlybequestionedonthesubstancesrelatingtotheiractivities.Thesetypesofgoodsare:—Class1,—Class2,—Class7,—Classes3,4.1,4.2,4.3,5.1,5.2,6.1,6.2,8and9,—UNNos1202,1203and1223.Thecertificateprescribedin1.8.3.7shallclearlyindicatethatitisonlyvalidforonetypeofthedangerousgoodsreferredtointhissubsectionandonwhichtheadviserhasbeenquestionedundertheconditionsdefinedin1.8.3.12.1.8.3.14.Thecompetentauthorityortheexaminingbodyshallkeeparunninglistofthequestionsthathavebeenincludedintheexamination.1.8.3.15.Thecertificateprescribedin1.8.3.7shalltaketheformlaiddownin1.8.3.18andshallberecognisedbyallMemberStates.1.8.3.16.Thecertificateshallbevalidforfiveyears.Theperiodofvalidityofacertificateshallbeextendedautomaticallyforfiveyearsatatimewhere,duringthefinalyearbeforeitsexpiry,itsholderhasfollowedrefreshercoursesorpassedanexaminationbothofwhichshallbeapprovedbythecompetentauthority.1.8.3.17.Therequirementssetoutin1.8.3.1to1.8.3.16shallbeconsideredtohavebeenfulfillediftherelevantconditionsofCouncilDirective96/35/ECof3June1996ontheappointmentandvocationalqualificationofsafetyadvisersforthetransportofdangerousgoodsbyroad,railandinlandwaterway(1)andofDirective2000/18/ECoftheEuropeanParliamentandoftheCouncilof17April2000onminimumexaminationrequirementsforsafetyadvisersforthetransportofdangerousgoodsbyroad,railorinlandwaterway(2)areapplied.1.8.3.18.FormofcertificateOfficialJournaloftheEuropeanUnionEN26.1.2004L18/32(1)OJL145,19.6.1996,p.10.(2)OJL118,19.5.2000,p.41.1.8.4.(Reserved)1.8.5.Notificationsofoccurrencesinvolvingdangerousgoods1.8.5.1.IfaseriousaccidentorincidenttakesplaceduringthecarriageofdangerousgoodsontheterritoryofaMemberState,thecarrierisrequiredtomakeareporttothecompetentauthorityoftheMemberStateconcerned.1.8.5.2.(Reserved)CHAPTER1.9Transportrestrictionsbythecompetentauthorities1.9.1.InaccordancewithArticle5(1)ofthisDirective,theentryofdangerousgoodsintotheterritoryofMemberStatesmaybesubjecttoregulationsorprohibitionsimposedforreasonsotherthansafetyduringcarriage.Suchregulationsorprohibitionsshallbepublishedinanappropriateform.1.9.2.Subjecttotheprovisionsof1.9.3,aMemberStatemayapplytovehiclesengagedintheinternationalcarriageofdangerousgoodsbyroadonitsterritorycertainadditionalprovisionsnotincludedinthisDirective,providedthatthoseprovisionsdonotconflictwithArticle2(2)oftheAgreement,andarecontainedinitsdomesticlegislationapplyingequallytovehiclesengagedinthedomesticcarriageofdangerousgoodsbyroadontheterritoryofthatMemberState.1.9.3.Additionalprovisionsfallingwithinthescopeof1.9.2areasfollows:(a)additionalsafetyrequirementsorrestrictionsconcerningvehiclesusingcertainstructuressuchasbridgesortunnels,vehiclesusingcombinedtransportmodessuchasferriesortrains,orvehiclesenteringorleavingportsorothertransportterminals;(b)requirementsforvehiclestofollowprescribedroutestoavoidcommercialorresidentialareas,environmentallysensitiveareas,industrialzonescontaininghazardousinstallationsorroadspresentingseverephysicalhazards;(c)emergencyrequirementsregardingrouteingorparkingofvehiclescarryingdangerousgoodsresultingfromextremeweatherconditions,earthquake,accident,industrialaction,civildisorderormilitaryhostilities;(d)restrictionsonmovementofdangerousgoodstrafficoncertaindaysoftheweekoryear.1.9.4.(Reserved)OfficialJournaloftheEuropeanUnionEN26.1.2004L18/33Part2CLASSIFICATIONCHAPTER2.1Generalprovisions2.1.1.Introduction2.1.1.1.TheclassesofdangerousgoodsaccordingtothisDirectivearethefollowing:Class1ExplosivesubstancesandarticlesClass2GasesClass3FlammableliquidsClass4.1Flammablesolids,self-reactivesubstancesandsoliddesensitisedexplosivesClass4.2SubstancesliabletospontaneouscombustionClass4.3Substanceswhich,incontactwithwater,emitflammablegasesClass5.1OxidisingsubstancesClass5.2OrganicperoxidesClass6.1ToxicsubstancesClass6.2InfectioussubstancesClass7RadioactivematerialClass8CorrosivesubstancesClass9Miscellaneousdangeroussubstancesandarticles2.1.1.2.EachentryinthedifferentclasseshasbeenassignedaUNnumber.Thefollowingtypesofentriesareused:A.singleentriesforwelldefinedsubstancesorarticlesincludingentriesforsubstancescoveringseveralisomers,e.g.:UNNo1090ACETONEUNNo1104AMYLACETATESUNNo1194ETHYLNITRITESOLUTIONB.genericentriesforawelldefinedgroupofsubstancesorarticles,whicharenotn.o.sentries,e.g.:UNNo1133ADHESIVESUNNo1266PERFUMERYPRODUCTSUNNo2757CARBAMATEPESTICIDE,SOLID,TOXICUNNo3101ORGANICPEROXIDETYPEB,LIQUIDC.specificn.o.sentriescoveringagroupofsubstancesorarticlesofaparticularchemicalortechnicalnature,nototherwisespecified,e.g.:UNNo1477NITRATES,INORGANIC,N.O.SUNNo1987ALCOHOLS,FLAMMABLE,N.O.SD.generaln.o.sentriescoveringagroupofsubstancesorarticleshavingoneormoredangerousproperties,nototherwisespecified,e.g.:UNNo1325FLAMMABLESOLID,ORGANIC,N.O.SUNNo1993FLAMMABLELIQUID,N.O.STheentriesdefinedunderB.,C.andD.aredefinedascollectiveentries.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/342.1.1.3.Forpackingpurposes,certainsubstancesmaybeassignedtopackinggroupsinaccordancewiththeirdegreeofdanger.Thepackinggroupshavethefollowingmeanings:packinggroupI:substancespresentinghighdanger;packinggroupII:substancespresentingmediumdanger;packinggroupIII:substancespresentinglowdanger.2.1.2.Principlesofclassification2.1.2.1.Thedangerousgoodscoveredbytheheadingofaclassaredefinedonthebasisoftheirpropertiesaccordingtosubsection2.2.x.1oftherelevantclass.Assignmentofdangerousgoodstoaclassandapackinggroupismadeaccordingtothecriteriamentionedinthesamesubsection2.2.x.1.Assignmentofoneorseveralsubsidiaryrisk(s)toadangeroussubstanceorarticleismadeaccordingtothecriteriaoftheclassorclassescorrespondingtothoserisks,asmentionedintheappropriatesubsection(s)2.2.x.1.2.1.2.2.AlldangerousgoodsentriesarelistedinTableAofChapter3.2inthenumericalorderoftheirUNnumber.Thistablecontainsrelevantinformationonthegoodslisted,suchasname,class,packinggroup(s),label(s)tobeaffixed,packingandcarriageprovisions.2.1.2.3.Dangerousgoodswhicharelistedordefinedinsubsection2.2.x.2ofeachclassarenottobeacceptedforcarriage.2.1.2.4.Goodsnotmentionedbyname,i.e.goodsnotlistedassingleentriesinTableAofChapter3.2andnotlistedordefinedinoneoftheabovementionedsubsections2.2.x.2shallbeassignedtotherelevantclassinaccordancewiththeprocedureofsection2.1.3.Inaddition,thesubsidiaryrisk(ifany)andthepackinggroup(ifany)shallbedetermined.Oncetheclass,subsidiaryrisk(ifany)andpackinggroup(ifany)havebeenestablishedtherelevantUNnumbershallbedetermined.Thedecisiontreesinsubsections2.2.x.3(listofcollectiveentries)attheendofeachclassindicatetherelevantparametersforselectingtherelevantcollectiveentry(UNnumber).Inallcasesthemostspecificcollectiveentrycoveringthepropertiesofthesubstanceorarticleshallbeselected,accordingtothehierarchyindicatedin2.1.1.2bythelettersB,CandDrespectively.IfthesubstanceorarticlecannotbeclassifiedunderentriesoftypeBorCaccordingto2.1.1.2,then,andonlythenshallitbeclassifiedunderanentryoftypeD.2.1.2.5.OnthebasisofthetestproceduresofChapter2.3andthecriteriasetoutinsubsections2.2.x.1ofclasseswhenitissospecified,itmaybedeterminedthatasubstance,solutionormixtureofacertainclass,mentionedbynameinTableAofChapter3.2,doesnotmeetthecriteriaofthatclass.Insuchacase,thesubstance,solutionormixtureisdeemednottobelongtothatclass.2.1.2.6.Forthepurposesofclassification,substanceswithameltingpointorinitialmeltingpointof20°Corloweratapressureof101,3kPashallbeconsideredtobeliquids.AviscoussubstanceforwhichaspecificmeltingpointcannotbedeterminedshallbesubjectedtotheASTMD4359-90testortothetestfordeterminingfluidity(penetrometertest)prescribedin2.3.4.2.1.3.Classificationofsubstances,includingsolutionsandmixtures(suchaspreparationsandwastes),notmentionedbyname2.1.3.1.Substancesincludingsolutionsandmixturesnotmentionedbynameshallbeclassifiedaccordingtotheirdegreeofdangeronthebasisofthecriteriamentionedinsubsection2.2.x.1ofthevariousclasses.Thedanger(s)presentedbyasubstanceshallbedeterminedonthebasisofitsphysicalandchemicalcharacteristicsandphysiologicalproperties.Suchcharacteristicsandpropertiesshallalsobetakenintoaccountwhensuchexperienceleadstoamorestringentassignment.2.1.3.2.AsubstancenotmentionedbynameinTableAofChapter3.2presentingasinglehazardshallbeclassifiedintherelevantclassunderacollectiveentrylistedinsubsection2.2.x.3ofthatclass.2.1.3.3.AsolutionormixturecontainingonlyonedangeroussubstancementionedbynameinTableAofChapter3.2,togetherwithoneormorenon-dangeroussubstance(s),shallberegardedasthedangeroussubstancelistedbyname,unless:(a)thesolutionormixtureisspecificallymentionedbynameinTableAofChapter3.2;or(b)itisquiteclearfromtheentryforthedangeroussubstancethatitisapplicableonlytothepureortechnicallypuresubstance;or(c)theclass,physicalstateorpackinggroupofthesolutionormixtureisdifferentfromthatofthedangeroussubstance.Inthecasesreferredtounder(b)or(c),thesolutionormixtureshallbeclassifiedasasubstancenotmentionedbynameintherelevantclassunderacollectiveentrylistedinsub-section2.2.x.3ofthatclasstakingaccountofthesubsidiaryriskspresentedbythatsolutionormixture,ifany,unlessthesolutionormixturedonotmeetthecriteriaofanyclass,inwhichcasetheyarenotsubjecttothisDirective.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/352.1.3.4.Solutionsandmixturescontainingoneofthefollowingsubstancesmentionedbynameshallalwaysbeclassifiedunderthesameentryasthesubstancetheycontain,providedtheydonothavethehazardcharacteristicsasindicatedin2.1.3.5:—Class3UNNo1921PROPYLENEIMINE,STABILISED;UNNo2481ETHYLISOCYANATE;UNNo3064NITROGLYCERINSOLUTIONINALCOHOLwithmorethan1%butnotmorethan5%nitroglycerine,—Class6.1UNNo1051HYDROGENCYANIDE,STABILISED,containingnotmorethan3%water;UNNo1185ETHYLENEIMINE,STABILISED;UNNo1259NICKELCARBONYL;UNNo1613HYDROGENCYANIDE,AQUEOUSSOLUTION(hydrocyanicacid),withnotmorethan20%hydrogencyanide;UNNo1614HYDROGENCYANIDE,STABILISED,containingnotmorethan3%waterandabsorbedinaporousinertmaterial;UNNo1994IRONPENTACARBONYL;UNNo2480METHYLISOCYANATE;UNNo3294HYDROGENCYANIDE,SOLUTIONINALCOHOL,withnotmorethan45%hydrogencyanide,—Class8UNNo1052HYDROGENFLUORIDE,ANHYDROUS;UNNo1744BROMINEorUNNo1744BROMINESOLUTION;UNNo1790HYDROFLUORICACIDwithmorethan85%hydrogenfluoride;UNNo2576PHOSPHORUSOXYBROMIDE,MOLTEN,—Class9UNNo2315POLYCHLORINATEDBIPHENYLS;UNNo3151POLY-HALOGENATEDBIPHENYLS,LIQUIDorUNNo3151POLYHALOGENATEDTERPHENYLS,LIQUID;UNNo3152POLYHALOGENATEDBIPHENYLS,SOLIDorUNNo3152POLY-HALOGENATEDTERPHENYLS,SOLID,unlesstheycontainoneofthesubstancesofClass3orClass6.1orClass8listedabove;inwhichcasetheyshallbeclassifiedaccordingly.2.1.3.5.SubstancesnotmentionedbynameinTableAofChapter3.2,havingmorethanonehazardcharacteristicandsolutionsormixturescontainingseveraldangeroussubstancesshallbeclassifiedunderacollectiveentry(see2.1.2.4)andpackinggroupoftheappropriateclassinaccordancewiththeirhazardcharacteristics.Suchclassificationaccordingtothehazardcharacteristicsshallbecarriedoutasfollows.2.1.3.5.1.Thephysicalandchemicalcharacteristicsandphysiologicalpropertiesshallbedeterminedbymeasurementorcalculationandthesubstance,solutionormixtureshallbeclassifiedaccordingtothecriteriamentionedinsubsection2.2.x.1ofthevariousclasses.2.1.3.5.2.Ifthisdeterminationisnotpossiblewithoutdisproportionatecostoreffort(asforsomekindsofwastes),thesubstance,solutionormixtureshallbeclassifiedintheclassofthecomponentpresentingthemajorhazard.2.1.3.5.3.Ifthehazardcharacteristicsofthesubstance,solutionormixturefallwithinmorethanoneclassorgroupofsubstanceslistedbelowthenthesubstance,solutionormixtureshallbeclassifiedintheclassorgroupofsubstancescorrespondingtothemajorhazardonthebasisofthefollowingorderofprecedence:(a)materialofClass7(apartfromradioactivematerialinexceptedpackageswheretheotherhazardouspropertiestakeprecedence);(b)substancesofClass1;(c)substancesofClass2;(d)liquiddesensitisedexplosivesofClass3;(e)self-reactivesubstancesandsoliddesensitisedexplosivesofClass4.1;(f)pyrophoricsubstancesofClass4.2;(g)substancesofClass5.2;(h)substancesofClass6.1orClass3which,onthebasisoftheirinhalationtoxicity,aretobeclassifiedunderpackinggroupI(substancesmeetingtheclassificationcriteriaofClass8andhavinganinhalationtoxicityofdustandmist(LC50)intherangeofpackinggroupIandatoxicitythroughoralingestionordermalcontactonlyintherangeofpackinggroupIIIorless,shallbeallocatedtoClass8);(i)infectioussubstancesofClass6.2.2.1.3.5.4.Ifthehazardcharacteristicsofthesubstancefallwithinmorethanoneclassorgroupofsubstancesnotlistedin2.1.3.5.3above,thesubstanceshallbeclassifiedinaccordancewiththesameprocedurebuttherelevantclassshallbeselectedaccordingtothePrecedenceofhazardstableat2.1.3.9.2.1.3.6.Themostspecificapplicablecollectiveentry(see2.1.2.4)shallalwaysbeused,i.e.ageneraln.o.sentryshallonlybeusedifagenericentryoraspecificn.o.sentrycannotbeused.2.1.3.7.Solutionsandmixturesofoxidisingsubstancesorsubstanceswithanoxidisingsubsidiaryriskmayhaveexplosiveproperties.InsuchacasetheyarenottobeacceptedforcarriageunlesstheymeettherequirementsforClass1.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/362.1.3.8.ForthepurposesofthisDirective,substances,solutionsandmixtures(suchaspreparationsandwastes)whichcannotbeassignedtoClasses1to8orClass9entriesotherthanUNNos3077and3082,butwhichmaybeassignedtoUNNo3077or3082onthebasisofthetestmethodsandcriteriaofsection2.3.5shallbeconsideredtobepollutanttotheaquaticenvironment.Solutionsandmixtures(suchaspreparationsandwastes)forwhichnodataconformingtotheclassificationcriteriaareavailableshallbeconsideredtobepollutanttotheaquaticenvironmentiftheLC50(seedefinitionin2.3.4.7)evaluatedaccordingtothefollowingformula:LC50¼LC50ofthepollutantx100percentageofthepollutantðbymassÞisequaltoorlowerthan:(a)1mg/l;or(b)10mg/lifthepollutantisnotreadilybiodegradableor,beingbiodegradable,hasalogPow≥3,0(seealso2.3.5.6).OfficialJournaloftheEuropeanUnionEN26.1.2004L18/372.1.3.9.TableofprecedenceofhazardsClassandpackinggroup4.1,II4.1,III4.2,II4.2,III4.3,I4.3,II4.3,III5.1,I5.1,II5.1,III6.1,IDERMAL6.1,IORAL6.1,II6.1,III8,I8,II8,III93,ISOLLIQ4.13,ISOLLIQ4.13,ISOLLIQ4.23,ISOLLIQ4.23,I4.3,I4.3,I4.3,ISOLLIQ5.1,I3,ISOLLIQ5.1,I3,ISOLLIQ5.1,I3,I3,I3,I3,I3,I3,I3,I3,I3,I3,IISOLLIQ4.13,IISOLLIQ4.13,IISOLLIQ4.23,IISOLLIQ4.23,II4.3,I4.3,II4.3,IISOLLIQ5.1,I3,ISOLLIQ5.1,II3,IISOLLIQ5.1,II3,II3,I3,I3,II3,II8,I3,II3,II3,II3,IIISOLLIQ4.13,IISOLLIQ4.13,IIISOLLIQ4.23,IISOLLIQ4.23,III4.3,I4.3,II4.3,IIISOLLIQ5.1,I3,ISOLLIQ5.1,II3,IISOLLIQ5.1,III3,III6.1,I6.1,I6.1,II3,III(*)8,I8,II3,III3,III4.1,II4.2,II4.2,II4.3,I4.3,II4.3,II5.1,I4.1,II4.1,II6.1,I6.1,ISOLLIQ4.1,II6.1,IISOLLIQ4.1,II6.1,II8,ISOLLIQ4.1,II8,IISOLLIQ4.1,II8,II4.1,II4.1,III4.2,II4.2,III4.3,I4.3,II4.3,III5.1,I4.1,II4.1,III6.1,I6.1,I6.1,IISOLLIQ4.1,III6.1,III8,I8,IISOLLIQ4.1,III8,III4.1,III4.2,II4.3,I4.3,II4.3,II5.1,I4.2,II4.2,II6.1,I6.1,I4.2,II4.2,II8,I4.2,II4.2,II4.2,II4.2,III4.3,I4.3,II4.3,III5.1,I5.1,II4.2,III6.1,I6.1,I6.1,II4.2,III8,I8,II4.2,III4.2,III4.3,I5.1,I4.3,I4.3,I6.1,I4.3,I4.3,I4.3,I4.3,I4.3,I4.3,I4.3,I4.3,II5.1,I4.3,II4.3,II6.1,I4.3,I4.3,II4.3,II8,I4.3,II4.3,II4.3,II4.3,III5.1,I5.1,II4.3,III6.1,I6.1,I6.1,II4.3,III8,I8,II4.3,III4.3,III5.1,I5.1,I5.1,I5.1,I5.1,I5.1,I5.1,I5.1,I5.1,I5.1,II6.1,I5.1,I5.1,II5.1,II8,I5.1,II5.1,II5.1,II5.1,III6.1,I6.1,I6.1,II5.1,III8,I8,II5.1,III5.1,III6.1,IDERMALSOLLIQ6.1,I8,I6.1,I6.1,I6.1,I6.1,IORALSOLLIQ6.1,I8,I6.1,I6.1,I6.1,IOfficialJournaloftheEuropeanUnionEN26.1.2004L18/38Classandpackinggroup4.1,II4.1,III4.2,II4.2,III4.3,I4.3,II4.3,III5.1,I5.1,II5.1,III6.1,IDERMAL6.1,IORAL6.1,II6.1,III8,I8,II8,III96.1,IIINHALSOLLIQ6.1,I8,I6.1,II6.1,II6.1,II6.1,IIDERMALSOLLIQ6.1,I8,ISOLLIQ6.1,II8,II6.1,II6.1,II6.1,IIORAL8.1SOLLIQ6.1,II8,II6.1,II6.1,II6.1,III8,I8,II8,III6.1,III8,I8,I8,II8,II8,III8,IIISOL=SolidsubstancesandmixturesLIQ=Liquidsubstances,mixturesandsolutionsDERMAL=DermaltoxicityORAL=OraltoxicityINHAL=Inhalationtoxicity(*)Class6.1forpesticidesOfficialJournaloftheEuropeanUnionEN26.1.2004L18/39NOTE1.ExamplestoexplaintheuseofthetableClassificationofasinglesubstanceDescriptionofthesubstancetobeclassified:anaminenotmentionedbynamemeetingthecriteriaforClass3,packinggroupIIaswellasthoseforClass8,packinggroupI.Procedure:theintersectionofline3IIwithcolumn8Igives8I.ThisaminehasthereforetobeclassifiedinClass8under:UNNo2734AMINESLIQUID,CORROSIVE,FLAMMABLE,N.O.SorUNNo2734POLYAMINES,LIQUID,CORROSIVE,FLAMMABLE,N.O.S,packinggroupIClassificationofamixtureDescriptionofthemixturetobeclassified:MixtureconsistingofaflammableliquidclassifiedinClass3,packinggroupIII,atoxicsubstanceinClass6.1,packinggroupIIandacorrosivesubstanceinClass8,packinggroupI.Procedure:theintersectionofline3IIIwithcolumn6.1IIgives6.1II.Theintersectionofline6.1IIwithcolumn8ILIQgives8I.ThismixturenotfurtherdefinedhasthereforetobeclassifiedinClass8under:UNNo2922CORROSIVELIQUID,TOXIC,N.O.S,packinggroupI2.Examplesfortheclassificationofmixturesandsolutionsunderaclassandapackinggroup:aphenolsolutionofClass6.1,(II),inbenzeneofClass3,(II)istobeclassifiedinClass3,(II);thissolutionistobeclassifiedunderUNNo1992FLAMMABLELIQUID,TOXIC,N.O.S,Class3,(II),byvirtueofthetoxicityofthephenol.AsolidmixtureofsodiumarsenateofClass6.1,(II)andsodiumhydroxideofClass8,(II)istobeclassifiedunderUNNo3290TOXICSOLID,CORROSIVE,INORGANIC,N.O.S,inClass6.1,(II).AsolutionofcrudeorrefinednaphthaleneofClass4.1,(III)inpetrolofClass3,(II),istobeclassifiedunderUNNo3295HYDROCARBONS,LIQUID,N.O.SinClass3,(II).AmixtureofhydrocarbonsofClass3,(III),andofpolychlorinatedbiphenyls(PCB)ofClass9,(II),istobeclassifiedunderUNNo2315POLYCHLORINATEDBIPHENYLSinClass9,(II).AmixtureofpropyleneimineofClass3,andpolychlorinatedbiphenyls(PCB)ofClass9,(II),istobeclassifiedunderUNNo1921PROPYLENEIMINE,INHIBITEDinClass3.2.1.4.Classificationofsamples2.1.4.1.Whentheclassofasubstanceisuncertainanditisbeingcarriedforfurthertesting,atentativeclass,propershippingnameandUNnumbershallbeassignedonthebasisoftheconsignor'sknowledgeofthesubstanceandapplicationof:(a)theclassificationcriteriaofChapter2.2;and(b)therequirementsofthisChapter.Themostseverepackinggrouppossibleforthepropershippingnamechosenshallbeused.Wherethisprovisionisusedthepropershippingnameshallbesupplementedwiththeword‘sample’(e.g.,‘FLAMMABLELIQUID,N.O.SSample’).Incertaininstances,whereaspecificpropershippingnameisprovidedforasampleofasubstanceconsideredtomeetcertainclassificationcriteria(e.g.,GASSAMPLE,NON-PRESSURISED,FLAMMABLE,UNNo3167)thatpropershippingnameshallbeused.WhenanN.O.Sentryisusedtocarrythesample,thepropershippingnameneednotbesupplementedwiththetechnicalnameasrequiredbyspecialprovision274ofChapter3.3.2.1.4.2.Samplesofthesubstanceshallbecarriedinaccordancewiththerequirementsapplicabletothetentativeassignedpropershippingnameprovided:(a)thesubstanceisnotconsideredtobeasubstancenotacceptedforcarriagebysubsections2.2.x.2ofChapter2.2orbyChapter3.2;(b)thesubstanceisnotconsideredtomeetthecriteriaforClass1orconsideredtobeaninfectioussubstanceoraradioactivematerial;(c)thesubstanceisincompliancewith2.2.41.1.15or2.2.52.1.9ifitisaself-reactivesubstanceoranorganicperoxide,respectively;(d)thesampleiscarriedinacombinationpackagingwithanetmassperpackagenotexceeding2,5kg;and(e)thesampleisnotpackedtogetherwithothergoods.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/40CHAPTER2.2Class-specificprovisions2.2.1.Class1Explosivesubstancesandarticles2.2.1.1.Criteria2.2.1.1.1.TheheadingofClass1covers:(a)Explosivesubstances:solidorliquidsubstances(ormixturesofsubstances)capablebychemicalreactionofproducinggasesatsuchatemperatureandpressureandatsuchaspeedastocausedamagetothesurroundings.Pyrotechnicsubstances:substancesormixturesofsubstancesdesignedtoproduceaneffectbyheat,light,sound,gasorsmokeoracombinationoftheseastheresultofnon-detonatingself-sustainingexothermicchemicalreactions.NOTE1.Substanceswhicharenotthemselvesexplosivebutwhichmayformanexplosivemixtureofgas,vapourordustarenotsubstancesofClass1.2.AlsoexcludedfromClass1are:water-oralcohol-wettedexplosivesofwhichthewateroralcoholcontentexceedsthelimitsspecifiedandthosecontainingplasticisers,theseexplosivesareassignedtoClass3orClass4.1,andthoseexplosiveswhich,onthebasisoftheirpredominanthazard,areassignedtoClass5.2.(b)Explosivearticles:articlescontainingoneormoreexplosiveorpyrotechnicsubstances.NOTEDevicescontainingexplosiveorpyrotechnicsubstancesinsuchsmallquantityorofsuchacharacterthattheirinadvertentoraccidentalignitionorinitiationduringcarriagewouldnotcauseanymanifestationexternaltothedevicebyprojection,fire,smoke,heatorloudnoisearenotsubjecttotherequirementsofClass1.(c)Substancesandarticlesnotmentionedabovewhicharemanufacturedwithaviewtoproducingapracticaleffectbyexplosionorapyrotechniceffect.2.2.1.1.2.AnysubstanceorarticlehavingorsuspectedofhavingexplosivepropertiesshallbeconsideredforassignmenttoClass1inaccordancewiththetests,proceduresandcriteriaprescribedinPartI,Manualoftestsandcriteria.AsubstanceorarticleassignedtoClass1canonlybeacceptedforcarriagewhenithasbeenassignedtoanameorn.o.sentrylistedinTableAofChapter3.2andmeetsthecriteriaoftheManualoftestsandcriteria.2.2.1.1.3.ThesubstancesandarticlesofClass1shallbeassignedtoaUNnumberandanameorn.o.sentrylistedinTableAofChapter3.2.InterpretationofthenamesofsubstancesandarticlesinTableAofChapter3.2shallbebasedontheglossaryin2.2.1.1.7.Samplesofneworexistingexplosivesubstancesorarticlescarriedforpurposesincluding:testing,classification,researchanddevelopmentqualitycontrol,orasacommercialsample,otherthaninitiatingexplosive,maybeassignedtoUNNo0190SAMPLES,EXPLOSIVE.TheassignmentofexplosivesubstancesandarticlesnotmentionedbynameassuchinTableAofChapter3.2toann.o.sentryofClass1orUNNo0190SAMPLES,EXPLOSIVEaswellastheassignmentofcertainsubstancesthecarriageofwhichissubjecttoaspecificauthorisationbythecompetentauthorityaccordingtothespecialprovisionsreferredtoincolumn6ofTableAofChapter3.2shallbemadebythecompetentauthorityofthecountryoforigin.Thiscompetentauthorityshallalsoapproveinwritingtheconditionsofcarriageofthesesubstancesandarticles.IfthecountryoforiginisnotaMemberState,theclassificationandtheconditionsofcarriageshallberecognisedbythecompetentauthorityofthefirstcountryMemberStatereachedbytheconsignment.2.2.1.1.4.SubstancesandarticlesofClass1shallhavebeenassignedtoadivisioninaccordancewith2.2.1.1.5andtoacompatibilitygroupinaccordancewith2.2.1.1.6.ThedivisionshallbebasedontheresultsofthetestsdescribedinSection2.3.1applyingthedefinitionsin2.2.1.1.5.Thecompatibilitygroupshallbedeterminedinaccordancewiththedefinitionsin2.2.1.1.6.Theclassificationcodeshallconsistofthedivisionnumberandthecompatibilitygroupletter.2.2.1.1.5.DefinitionofdivisionsDivision1.1Substancesandarticleswhichhaveamassexplosionhazard(amassexplosionisanexplosionwhichaffectsalmosttheentireloadvirtuallyinstantaneously).Division1.2Substancesandarticleswhichhaveaprojectionhazardbutnotamassexplosionhazard.Division1.3Substancesandarticleswhichhaveafirehazardandeitheraminorblasthazardoraminorprojectionhazardorboth,butnotamassexplosionhazard:(a)combustionofwhichgivesrisetoconsiderableradiantheat;or(b)whichburnoneafteranother,producingminorblastorprojectioneffectsorboth.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/41Division1.4Substancesandarticleswhichpresentonlyaslightriskofexplosionintheeventofignitionorinitiationduringcarriage.Theeffectsarelargelyconfinedtothepackageandnoprojectionoffragmentsofappreciablesizeorrangeistobeexpected.Anexternalfireshallnotcausevirtuallyinstantaneousexplosionofalmosttheentirecontentsofthepackage.Division1.5Veryinsensitivesubstanceshavingamassexplosionhazardwhicharesoinsensitivethatthereisverylittleprobabilityofinitiationoroftransitionfromburningtodetonationundernormalconditionsofcarriage.Asaminimumrequirementtheymustnotexplodeintheexternalfiretest.Division1.6Extremelyinsensitivearticleswhichdonothaveamassexplosionhazard.Thearticlescontainonlyextremelyinsensitivedetonatingsubstancesanddemonstrateanegligibleprobabilityofaccidentalinitiationorpropagation.NOTETheriskfromarticlesofDivision1.6islimitedtotheexplosionofasinglearticle.2.2.1.1.6.DefinitionofcompatibilitygroupsofsubstancesandarticlesAPrimaryexplosivesubstanceBArticlecontainingaprimaryexplosivesubstanceandnothavingtwoormoreeffectiveprotectivefeatures.Somearticles,suchasdetonatorsforblasting,detonatorassembliesforblastingandprimers,cap-type,areincluded,eventhoughtheydonotcontainprimaryexplosives.CPropellantexplosivesubstanceorotherdeflagratingexplosivesubstanceorarticlecontainingsuchexplosivesubstance.DSecondarydetonatingexplosivesubstanceorblackpowderorarticlecontainingasecondarydetonatingexplosivesubstance,ineachcasewithoutmeansofinitiationandwithoutapropellingcharge,orarticlecontainingaprimaryexplosivesubstanceandhavingtwoormoreeffectiveprotectivefeatures.EArticlecontainingasecondarydetonatingexplosivesubstance,withoutmeansofinitiation,withapropellingcharge(otherthanonecontainingaflammableliquidorgelorhypergolicliquids).FArticlecontainingasecondarydetonatingexplosivesubstancewithitsownmeansofinitiation,withapropellingcharge(otherthanonecontainingaflammableliquidorgelorhypergolicliquids)orwithoutapropellingcharge.GPyrotechnicsubstance,orarticlecontainingapyrotechnicsubstance,orarticlecontainingbothanexplosivesubstanceandanilluminating,incendiary,tear-orsmoke-producingsubstance(otherthanawater-activatedarticleoronewhichcontainswhitephosphorus,phosphides,apyrophoricsubstance,aflammableliquidorgelorhypergolicliquids).HArticlecontainingbothanexplosivesubstanceandwhitephosphorus.JArticlecontainingbothanexplosivesubstanceandaflammableliquidorgel.KArticlecontainingbothanexplosivesubstanceandatoxicchemicalagent.LExplosivesubstanceorarticlecontaininganexplosivesubstanceandpresentingaspecialrisk(e.g.duetowateractivationorthepresenceofhypergolicliquids,phosphidesorapyrophoricsubstance)necessitatingisolationofeachtype.NArticlescontainingonlyextremelyinsensitivedetonatingsubstances.SSubstanceorarticlesopackedordesignedthatanyhazardouseffectsarisingfromaccidentalfunctioningareconfinedwithinthepackageunlessthepackagehasbeendegradedbyfire,inwhichcaseallblastorprojectioneffectsarelimitedtotheextentthattheydonotsignificantlyhinderorpreventfire-fightingorotheremergencyresponseeffortsintheimmediatevicinityofthepackage.NOTE1.Eachsubstanceorarticle,packedinaspecifiedpackaging,maybeassignedtoonecompatibilitygrouponly.SincethecriterionofcompatibilitygroupSisempirical,assignmenttothisgroupisnecessarilylinkedtothetestsforassignmentofaclassificationcode.2.ArticlesofcompatibilitygroupsDandEmaybefittedorpackedtogetherwiththeirownmeansofinitiationprovidedthatsuchmeanshaveatleasttwoeffectiveprotectivefeaturesdesignedtopreventanexplosionintheeventofaccidentalfunctioningofthemeansofinitiation.SuchpackagesshallbeassignedtocompatibilitygroupsDorE.3.ArticlesofcompatibilitygroupsDandEmaybepackedtogetherwiththeirownmeansofinitiation,whichdonothavetwoeffectiveprotectivefeatures(i.e.meansofinitiationassignedtocompatibilitygroupB),providedthattheycomplywithmixedpackingprovisionMP21ofSection4.1.10.SuchpackagesshallbeassignedtocompatibilitygroupsDorE.4.Articlesmaybefittedorpackedtogetherwiththeirownmeansofignitionprovidedthatthemeansofignitioncannotfunctionduringnormalconditionsofcarriage.5.ArticlesofcompatibilitygroupsC,DandEmaybepackedtogether.SuchpackagesshallbeassignedtocompatibilitygroupE.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/422.2.1.1.7.GlossaryofnamesNOTE1.Thedescriptionsintheglossaryarenotintendedtoreplacethetestprocedures,nortodeterminethehazardclassificationofasubstanceorarticleofClass1.AssignmenttothecorrectdivisionandadecisiononwhethercompatibilitygroupSisappropriateshallbebasedontestingoftheproductinaccordancewiththeManualoftestsandcriteria,PartIorbyanalogywithsimilarproductswhichhavealreadybeentestedandassignedinaccordancewiththeproceduresoftheManualoftestsandcriteria.2.ThefiguresgivenafterthenamesrefertotherelevantUNnumbers(column2ofTableAofChapter3.2).Fortheclassificationcode,see2.2.1.1.4.AIRBAGINFLATORS,PYROTECHNICorAIRBAGMODULES,PYROTECHNICorSEAT-BELTPRETENSIONERS,PYROTECHNIC:UNNo0503Articleswhichcontainpyrotechnicsubstancesandareusedaslife-savingvehicleairbagsorseatbelts.AMMUNITION,ILLUMINATING,withorwithoutburster,expellingchargeorpropellingcharge:UNNos0171,0254,0297Ammunitiondesignedtoproduceasinglesourceofintenselightforlightingupanarea.Thetermincludesilluminatingcartridges,grenadesandprojectiles;andilluminatingandtargetidentificationbombs.NOTEThefollowingarticles:CARTRIDGES,SIGNAL;SIGNALDEVICESHAND;SIGNALS,DISTRESS;FLARES,AERIAL;FLARES,SURFACEarenotincludedinthisdefinition.Theyarelistedseparately.AMMUNITION,INCENDIARY,liquidorgel,withburster,expellingchargeorpropellingcharge:UNNo0247Ammunitioncontainingliquidorgelatinousincendiarysubstance.Exceptwhentheincendiarysubstanceisanexplosiveperse,italsocontainsoneormoreofthefollowing:apropellingchargewithprimerandignitercharge;afusewithbursterorexpellingcharge.AMMUNITION,INCENDIARY,WHITEPHOSPHORUSwithburster,expellingchargeorpropellingcharge:UNNos0243,0244Ammunitioncontainingwhitephosphorusasincendiarysubstance.Italsocontainsoneormoreofthefollowing:apropellingchargewithprimerandignitercharge;afusewithbursterorexpellingcharge.AMMUNITION,INCENDIARYwithorwithoutburster,expellingchargeorpropellingcharge:UNNos0009,0010,0300Ammunitioncontainingincendiarycomposition.Exceptwhenthecompositionisanexplosiveperse,italsocontainsoneormoreofthefollowing:apropellingchargewithprimerandignitercharge;afusewithbursterorexpellingcharge.AMMUNITION,PRACTICE:UNNos0362,0488Ammunitionwithoutamainburstingcharge,containingabursterorexpellingcharge.Normallyitalsocontainsafuseandapropellingcharge.NOTEGRENADES,PRACTICEarenotincludedinthisdefinition.Theyarelistedseparately.AMMUNITION,PROOF:UNNo0363Ammunitioncontainingpyrotechnicsubstances,usedtotesttheperformanceorstrengthofnewammunition,weaponcomponentsorassemblies.AMMUNITION,SMOKE,WHITEPHOSPHORUS,withburster,expellingchargeorpropellingcharge:UNNos0245,0246Ammunitioncontainingwhitephosphorusasasmoke-producingsubstance.Italsocontainsoneormoreofthefollowing:apropellingchargewithprimerandignitercharge;afusewithbursterorexpellingcharge.Thetermincludesgrenades,smoke.AMMUNITION,SMOKEwithorwithoutburster,expellingchargeorpropellingcharge:UNNos0015,0016,0303Ammunitioncontainingasmoke-producingsubstancesuchaschlorosulphonicacidmixtureortitaniumtetrachloride;orasmoke-producingpyrotechniccompositionbasedonhexachloroethaneorredphosphorus.Exceptwhenthesubstanceisanexplosiveperse,theammunitionalsocontainsoneormoreofthefollowing:apropellingchargewithprimerandignitercharge;afusewithbursterorexpellingcharge.Thetermincludesgrenades,smoke.NOTESIGNALS,SMOKEarenotincludedinthisdefinition.Theyarelistedseparately.AMMUNITION,TEAR-PRODUCING,withburster,expellingchargeorpropellingcharge:UNNos0018,0019,0301Ammunitioncontainingatear-producingsubstance.Italsocontainsoneormoreofthefollowing:apyrotechnicsubstance;apropellingchargewithprimerandignitercharge;afusewithbursterorexpellingcharge.ARTICLES,EXPLOSIVE,EXTREMELYINSENSITIVE(ARTICLESEEI):UNNo0486Articlescontainingonlyextremelyinsensitivedetonatingsubstances(EIDS)whichdemonstrateanegligibleprobabilityofaccidentalinitiationorpropagationundernormalconditionsoftransport,andwhichhavepassedtestseries7.ARTICLES,PYROPHORIC:UNNo0380Articleswhichcontainapyrophoricsubstance(capableofspontaneousignitionwhenexposedtoair)andanexplosivesubstanceorcomponent.Thetermexcludesarticlescontainingwhitephosphorus.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/43ARTICLES,PYROTECHNIC,fortechnicalpurposes:UNNos0428,0429,0430,0431,0432Articleswhichcontainpyrotechnicsubstancesandareusedfortechnicalpurposessuchasheatgeneration,gasgeneration,theatricaleffects,etc.NOTEThefollowingarticles:allammunition;CARTRIDGES,SIGNAL;CUTTERS,CABLE,EXPLOSIVE;FIREWORKS;FLARES,AERIAL;FLARES,SURFACE;RELEASEDEVICES,EXPLOSIVE;RIVETS,EXPLOSIVE;SIGNALDEVICES,HAND;SIGNALS,DISTRESS;SIGNALS,RAILWAYTRACK,EXPLOSIVES;SIGNALS,SMOKEarenotincludedinthisdefinition.Theyarelistedseparately.BLACKPOWDER(GUNPOWDER),COMPRESSEDorBLACKPOWDER(GUNPOWDER),INPELLETS:UNNo0028Substanceconsistingofapelletisedformofblackpowder.BLACKPOWDER(GUNPOWDER),granularorasmeal:UNNo0027Substanceconsistingofanintimatemixtureofcharcoalorothercarbonandeitherpotassiumnitrateorsodiumnitrate,withorwithoutsulphur.BOMBS,WITHFLAMMABLELIQUID,withburstingcharge:UNNos0399,0400Articleswhicharedroppedfromaircraft,consistingofatankfilledwithinflammableliquidandburstingcharge.BOMBS,PHOTO-FLASH:UNNo0038Explosivearticleswhicharedroppedfromaircrafttoprovidebrief,intenseilluminationforphotography.Theycontainachargeofdetonatingexplosivewithoutmeansofinitiationorwithmeansofinitiationcontainingtwoormoreeffectiveprotectivefeatures.BOMBS,PHOTO-FLASH:UNNo0037Explosivearticleswhicharedroppedfromaircrafttoprovidebrief,intenseilluminationforphotography.Theycontainachargeofdetonatingexplosivewithmeansofinitiationnotcontainingtwoormoreeffectiveprotectivefeatures.BOMBS,PHOTO-FLASH:UNNos0039,0299Explosivearticleswhicharedroppedfromaircrafttoprovidebrief,intenseilluminationforphotography.Theycontainaphoto-flashcomposition.BOMBS,withburstingcharge:UNNos0034;0035Explosivearticleswhicharedroppedfromaircraft,withoutmeansofinitiationorwithmeansofinitiationcontainingtwoormoreeffectiveprotectivefeatures.BOMBSwithburstingcharge:UNNos0033,0291Explosivearticleswhicharedroppedfromaircraft,withmeansofinitiationnotcontainingtwoormoreeffectiveprotectivefeatures.BOOSTERS,WITHDETONATOR:UNNos0225,0268Articlesconsistingofachargeofdetonatingexplosivewithmeansofinitiation.Theyareusedtoincreasetheinitiatingpowerofdetonatorsordetonatingcord.BOOSTERS,withoutdetonator:UNNos0042,0283Articlesconsistingofachargeofdetonatingexplosivewithoutmeansofinitiation.Theyareusedtoincreasetheinitiatingpowerofdetonatorsordetonatingcord.BURSTERS,explosive:UNNo0043Articlesconsistingofasmallchargeofexplosiveusedtoopenprojectilesorotherammunitioninordertodispersetheircontents.CARTRIDGES,FLASH:UNNos0049,0050Articlesconsistingofacasing,aprimerandflashpowder,allassembledinonepiecereadyforfiring.CARTRIDGESFORWEAPONS,BLANK:UNNos0326,0413,0327,0338,0014Ammunitionconsistingofaclosedcartridgecasewithacentreorrimfireprimerandachargeofsmokelessorblackpowderbutnoprojectile.Itproducesaloudnoiseandisusedfortraining,saluting,propellingcharge,starterpistols,etc.Thetermincludesammunition,blank.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/44CARTRIDGESFORWEAPONS,INERTPROJECTILE:UNNos0328,0417,0339,0012Ammunitionconsistingofaprojectilewithoutburstingchargebutwithapropellingchargewithorwithoutaprimer.Thearticlesmayincludeatracer,providedthatthepredominanthazardisthatofthepropellingcharge.CARTRIDGESFORWEAPONS,withburstingcharge:UNNos0006,0321,0412Ammunitionconsistingofaprojectilewithaburstingchargewithoutmeansofinitiationorwithmeansofinitiationcontainingtwoormoreeffectiveprotectivefeatures;andapropellingchargewithorwithoutaprimer.Thetermincludesfixed(assembled)ammunition,semi-fixed(partiallyassembled)ammunitionandseparateloadingammunitionwhenthecomponentsarepackedtogether.CARTRIDGESFORWEAPONS,withburstingcharge:UNNos0005,0007,0348Ammunitionconsistingofaprojectilewithaburstingchargewithmeansofinitiationnotcontainingtwoormoreeffectiveprotectivefeatures,andapropellingchargewithorwithoutaprimer.Thetermincludesfixed(assembled)ammunition,semi-fixed(partiallyassembled)ammunitionandseparateloadingammunitionwhenthecomponentsarepackedtogether.CARTRIDGES,OILWELL:UNNos0277,0278Articlesconsistingofathincasingoffibreboard,metalorothermaterialcontainingonlypropellantpowderwhichprojectsahardenedprojectiletoperforateanoilwellcasing.NOTECHARGES,SHAPEDarenotincludedinthisdefinition.Theyarelistedseparately.CARTRIDGES,POWERDEVICE:UNNos0275,0276,0323,0381Articlesdesignedtoaccomplishmechanicalactions.Theyconsistofacasingwithachargeofdeflagratingexplosiveandameansofignition.Thegaseousproductsofthedeflagrationproduceinflation,linearorrotarymotionoractivatediaphragms,valvesorswitchesorprojectfasteningdevicesorextinguishingagents.CARTRIDGES,SIGNAL:UNNos0054,0312,0405Articlesdesignedtofirecolouredflaresorothersignalsfromsignalpistols,etc.CARTRIDGESSMALLARMS:UNNos0417,0339,0012Ammunitionconsistingofacartridgecasefittedwithacentreorrimfireprimerandcontainingbothapropellingchargeandsolidprojectile.Theyaredesignedtobefiredinweaponsofcalibrenotlargerthan19,1mm.Shotguncartridgesofanycalibreareincludedinthisdescription.NOTECARTRIDGES,SMALLARMS,BLANK,arenotincludedinthisdefinition.Theyarelistedseparately.Somemilitarysmallarmscartridgesarenotincludedinthisdefinition.TheyarelistedunderCARTRIDGESFORWEAPONS,INERTPROJECTILE.CARTRIDGES,SMALLARMS,BLANK:UNNos0014,0327,0338Ammunitionconsistingofaclosedcartridgecasewithacentreorrimfireprimerandachargeofsmokelessorblackpowder.Thecartridgecasescontainnoprojectiles.Thecartridgesaredesignedtobefiredfromweaponswithacalibreofatmost19,1mmandservetoproducealoudnoiseandareusedfortraining,saluting,propellingcharge,starterpistols,etc.CASES,CARTRIDGE,EMPTY,WITHPRIMER:UNNos0379;0055Articlesconsistingofacartridgecasemadefrommetal,plasticsorothernon-inflammablematerial,inwhichtheonlyexplosivecomponentistheprimer.CASES,COMBUSTIBLE,EMPTY,WITHOUTPRIMER:UNNos0447,0446Articlesconsistingofacartridgecasemadepartlyorentirelyfromnitrocellulose.CHARGES,BURSTING,PLASTICSBONDED:UNNos0457,0458,0459,0460Articlesconsistingofachargeofdetonatingexplosive,plasticsbonded,manufacturedinaspecificformwithoutacasingandwithoutmeansofinitiation.Theyaredesignedascomponentsofammunitionsuchaswarheads.CHARGES,DEMOLITION:UNNo0048Articlescontainingachargeofadetonatingexplosiveinacasingoffibreboard,plastics,metalorothermaterial.Thearticlesarewithoutmeansofinitiationorwithmeansofinitiationcontainingtwoormoreeffectiveprotectivefeatures.NOTEThefollowingarticles:BOMBS;MINES;PROJECTILESarenotincludedinthisdefinition.Theyarelistedseparately.CHARGES,DEPTH:UNNo0056Articlesconsistingofachargeofdetonatingexplosivecontainedinadrumorprojectilewithoutmeansofinitiationorwithmeansofinitiationcontainingtwoormoreeffectiveprotectivefeatures.Theyaredesignedtodetonateunderwater.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/45CHARGES,EXPLOSIVEwithoutdetonator:UNNos0442,0443,0444,0445Articlesconsistingofachargeofdetonatingexplosivewithoutmeansofinitiation,usedforexplosivewelding,jointing,formingandothermetallurgicalprocesses.CHARGES,PROPELLING,FORCANNON:UNNos0242,0279,0414Chargesofpropellantinanyphysicalformforseparate-loadingammunitionforcannon.CHARGES,PROPELLING:UNNos0271,0272,0415,0491Articlesconsistingofachargeofapropellantchargeinanyphysicalform,withorwithoutacasing,asacomponentofrocketmotorsorforreducingthedragofprojectiles.CHARGES,SHAPED,COMMERCIAL,withoutdetonator:UNNos0059,0439,0440,UN0441Articlesconsistingofacasingcontainingachargeofdetonatingexplosivewithacavitylinedwithrigidmaterial,withoutmeansofinitiation.Theyaredesignedtoproduceapowerful,penetratingjeteffect.CHARGES,SHAPED,FLEXIBLE,LINEAR:UNNos0237,0288ArticlesconsistingofaV-shapedcoreofadetonatingexplosivecladbyaflexiblesheath.CHARGES,SUPPLEMENTARY,EXPLOSIVE:UNNo0060Articlesconsistingofasmallremovableboosterplacedinthecavityofaprojectilebetweenthefuseandtheburstingcharge.COMPONENTS,EXPLOSIVETRAIN,N.O.S:UNNos0382,0383,0384,0461Articlescontaininganexplosivedesignedtotransmitdetonationordeflagrationwithinanexplosivetrain.CONTRIVANCES,WATER-ACTIVATEDwithburster,expellingchargeorpropellingcharge:UNNos0248,0249Articleswhosefunctioningdependsonphysicochemicalreactionoftheircontentswithwater.CORD,DETONATING,flexible:UNNos0065,0289Articleconsistingofacoreofdetonatingexplosiveenclosedinspunfabricandaplasticsorothercovering.Thecoveringisnotnecessaryifthespunfabricissift-proof.CORD(FUSE)DETONATING,metalclad:UNNos0102,0290Articleconsistingofacoreofdetonatingexplosivecladbyasoftmetaltubewithorwithoutprotectivecovering.CORD(FUSE)DETONATING,MILDEFFECT,metalclad:UNNo0104Articleconsistingofacoreofdetonatingexplosivecladbyasoftmetaltubewithorwithoutaprotectivecovering.Thequantityofexplosivesubstanceissosmallthatonlyamildeffectismanifestedoutsidethecord.CORD,IGNITER:UNNo0066Articleconsistingoftextileyarnscoveredwithblackpowderoranotherfastburningpyrotechniccompositionandofaflexibleprotectivecovering;oritconsistsofacoreofblackpowdersurroundedbyaflexiblewovenfabric.Itburnsprogressivelyalongitslengthwithanexternalflameandisusedtotransmitignitionfromadevicetoachargeorprimer.CUTTERS,CABLE,EXPLOSIVE:UNNo0070Articlesconsistingofaknife-edgeddevicewhichisdrivenbyasmallchargeofdeflagratingexplosiveintoananvil.DETONATORASSEMBLIES,NON-ELECTRIC,forblasting:UNNos0360,0361,0500Non-electricdetonatorsassembledwithandactivatedbysuchmeansassafetyfuse,shocktube,flashtubeordetonatingcord.Theymaybeofinstantaneousdesignorincorporatedelayelements.Detonatingrelaysincorporatingdetonatingcordareincluded.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/46DETONATORS,ELECTRIC,forblasting:UNNos0030,0255,0456Articlesspeciallydesignedfortheinitiationofblastingexplosives.Thesedetonatorsmaybeconstructedtodetonateinstantaneouslyormaycontainadelayelement.Electricdetonatorsareactivatedbyanelectriccurrent.DETONATORSFORAMMUNITION:UNNos0073,0364,0365,0366Articlesconsistingofasmallmetalorplasticstubecontainingexplosivessuchasleadazide,PETNorcombinationsofexplosives.Theyaredesignedtostartadetonationtrain.DETONATORS,NON-ELECTRIC,forblasting:UNNos0029,0267,0455Articlesspeciallydesignedfortheinitiationofblastingexplosives.Thesedetonatorsmaybeconstructedtodetonateinstantaneouslyormaycontainadelayelement.Non-electricdetonatorsareactivatedbysuchmeansasshocktube,flashtube,safetyfuse,otherigniferousdeviceorflexibledetonatingcord.Detonatingrelayswithoutdetonatingcordareincluded.EXPLOSIVE,BLASTING,TYPEA:UNNo0081Substancesconsistingofliquidorganicnitratessuchasnitroglycerineoramixtureofsuchingredientswithoneormoreofthefollowing:nitrocellulose;ammoniumnitrateorotherinorganicnitrates;aromaticnitro-derivatives,orcombustiblematerials,suchaswood-mealandaluminiumpowder.Theymaycontaininertcomponentssuchaskieselguhr,andadditivessuchascolouringagentsandstabilisers.Suchexplosivesshallbeinpowdery,gelatinousorelasticform.Thetermincludesdynamite;gelatine,blastingandgelatinedynamites.EXPLOSIVE,BLASTING,TYPEB:UNNos0082,0331Substancesconsistingof(a)amixtureofammoniumnitrateorotherinorganicnitrateswithanexplosivesuchastrinitrotoluene,withorwithoutothersubstancessuchaswood-mealandaluminiumpowder;or(b)amixtureofammoniumnitrateorotherinorganicnitrateswithothercombustiblesubstanceswhicharenotexplosiveingredients.Inbothcasestheymaycontaininertcomponentssuchaskieselguhr,andadditivessuchascolouringagentsandstabilisers.Suchexplosivesmustnotcontainnitroglycerine,similarliquidorganicnitratesorchlorates.EXPLOSIVE,BLASTING,TYPEC:UNNo0083Substancesconsistingofamixtureofeitherpotassiumorsodiumchlorateorpotassium,sodiumorammoniumperchloratewithorganicnitro-derivativesorcombustiblematerialssuchaswood-mealoraluminiumpowderorahydrocarbon.Theymaycontaininertcomponentssuchaskieselguhrandadditivessuchascolouringagentsandstabilisers.Suchexplosivesmustnotcontainnitroglycerineorsimilarliquidorganicnitrates.EXPLOSIVE,BLASTING,TYPED:UNNo0084Substancesconsistingofamixtureoforganicnitratedcompoundsandcombustiblematerialssuchashydrocarbonsandaluminiumpowder.Theymaycontaininertcomponentssuchaskieselguhrandadditivessuchascolouringagentsandstabilisers.Suchexplosivesmustnotcontainnitroglycerine,similarliquidorganicnitrates,chloratesandammoniumnitrate.Thetermgenerallyincludesplasticexplosives.EXPLOSIVES,BLASTING,TYPEE:UNNos0241,0332Substancesconsistingofwaterasanessentialingredientandhighproportionsofammoniumnitrateorotheroxidisers,someorallofwhichareinsolution.Theotherconstituentsmayincludenitro-derivativessuchastrinitrotoluene,hydrocarbonsoraluminiumpowder.Theymaycontaininertcomponentssuchaskieselguhrandadditivessuchascolouringagentsandstabilisers.Thetermincludesexplosives,emulsion,explosives,slurryandexplosives,watergel.FIREWORKS:UNNos0333,0334,0335,0336,0337Pyrotechnicarticlesdesignedforentertainment.FLARES,AERIAL:UNNos0093,0403,0404,0420,0421;Articlescontainingpyrotechnicsubstanceswhicharedesignedtobedroppedfromanaircrafttoilluminate,identify,signalorwarn.FLARES,SURFACE:UNNos0092,0418,0419Articlescontainingpyrotechnicsubstanceswhicharedesignedforuseonthesurfacetoilluminate,identify,signalorwarn.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/47FLASHPOWDER:UNNos0094,0305Pyrotechnicsubstancewhich,whenignited,producesanintenselight.FRACTURINGDEVICES,EXPLOSIVE,withoutdetonator,foroilwells:UNNo0099Articlesconsistingofachargeofdetonatingexplosivecontainedinacasingwithoutmeansofinitiation.Theyareusedtofracturetherockaroundadrillshafttoassisttheflowofcrudeoilfromtherock.FUSE,IGNITER,tubular,metalclad:UNNo0103Articleconsistingofametaltubewithacoreofdeflagratingexplosive.FUSE,NON-DETONATING:UNNo0101Articleconsistingofcottonyarnsimpregnatedwithfineblackpowder.Itburnswithanexternalflameandisusedinignitiontrainsforfireworksetc.Itcanbeenclosedinapapertubetoobtainaninstantaneousorquickmatcheffect.FUSE,SAFETY:UNNo0105Articleconsistingofacoreoffinegrainedblackpowdersurroundedbyaflexiblewovenfabricwithoneormoreprotectiveoutercoverings.Whenignited,itburnsatapredeterminedratewithoutanyexternalexplosiveeffect.FUSES,DETONATING:UNNos0106,0107,0257,0367Articleswithexplosivecomponentsdesignedtoproduceadetonationinammunition.Theyincorporatemechanical,electrical,chemicalorhydrostaticcomponentstoinitiatethedetonation.Theygenerallyincorporateprotectivefeatures.FUSES,DETONATING,withprotectivefeatures:UNNos0408,0409,0410Articleswithexplosivecomponentsdesignedtoproduceadetonationinammunition.Theyincorporatemechanical,electrical,chemicalorhydrostaticcomponentstoinitiatethedetonation.Thedetonatingfusemustincorporatetwoormoreeffectiveprotectivefeatures.FUSES,IGNITING:UNNos0316,0317,0368Articleswithprimaryexplosivecomponentsdesignedtoproduceadeflagrationinammunition.Theyincorporatemechanical,electrical,chemicalorhydrostaticcomponentstostartthedeflagration.Theygenerallyincorporateprotectivefeatures.GRENADES,handorrifle,withburstingcharge:UNNos0284,0285Articleswhicharedesignedtobethrownbyhandortobeprojectedbyarifle.Theyarewithoutmeansofinitiationorwithmeansofinitiationcontainingtwoormoreeffectiveprotectivefeatures.GRENADES,handorrifle,withburstingcharge:UNNos0292,0293Articleswhicharedesignedtobethrownbyhandortobeprojectedbyarifle.Theyarewithmeansofinitiationnotcontainingtwoormoreeffectiveprotectivefeatures.GRENADES,PRACTICE,handorrifle:UNNos0110,0372,0318,0452Articleswithoutamainburstingchargewhicharedesignedtobethrownbyhandortobeprojectedbyarifle.Theycontaintheprimingdeviceandmaycontainaspottingcharge.HEXOTONAL:UNNo0393Substanceconsistingofanintimatemixtureofcyclotrimethylene-trinitramine(RDX),trinitrotoluene(TNT)andaluminium.HEXOLITE(HEXOTOL),dryorwettedwithlessthan15%water,bymass:UNNo0118Substanceconsistingofanintimatemixtureofcyclotrimethylene-trinitramine(RDX)andtrinitrotoluene(TNT).Thetermincludes‘CompositionB’.IGNITERS:UNNos0121,0314,0315,0325,0454Articlescontainingoneormoreexplosivesubstancesdesignedtoproduceadeflagrationinanexplosivetrain.Theymaybeactuatedchemically,electricallyormechanically.NOTEThefollowingarticles:CORD,IGNITER;FUSE,IGNITER;FUSE,INSTANTANEOUS,NON-DETONATING;FUSES,IGNITING;LIGHTERS,FUSE;PRIMERS,CAPTYPE;PRIMERS,TUBULARarenotincludedinthisdefinition.Theyarelistedseparately.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/48JETPERFORATINGGUNS,CHARGED,oilwell,withoutdetonator:UNNos0124,0494Articlesconsistingofasteeltubeormetallicstrip,intowhichareinsertedshapedchargesconnectedbydetonatingcord,withoutmeansofinitiation.LIGHTERS,FUSE:UNNo0131Articlesofvariousdesignactuatedbyfriction,percussionorelectricityandusedtoignitesafetyfuse.MINES,withburstingcharge:UNNos0137,0138Articlesconsistingnormallyofmetalorcompositionreceptaclesfilledwithadetonatingexplosive,withoutmeansofinitiationorwithmeansofinitiationcontainingtwoormoreeffectiveprotectivefeatures.Theyaredesignedtobeoperatedbythepassageofships,vehiclesorpersonnel.Thetermincludes‘Bangaloretorpedoes’.MINES,withburstingcharge:UNNos0136,0294Articlesconsistingnormallyofmetalorcompositionreceptaclesfilledwithadetonatingexplosive,withmeansofinitiationnotcontainingtwoormoreeffectiveprotectivefeatures.Theyaredesignedtobeoperatedbythepassageofships,vehiclesorpersonnel.Thetermincludes‘Bangaloretorpedoes’.OCTOLITE(OCTOL),dryorwettedwithlessthan15%water,bymass:UNNo0266Substanceconsistingofanintimatemixtureofcyclotetramethylene-tetranitramine(HMX)andtrinitrotoluene(TNT).OCTONAL:UNNo0496Substanceconsistingofanintimatemixtureofcyclotetramethylenetetranitramine(HMX),trinitrotoluene(TNT)andaluminium.PENTOLITE,dryorwettedwithlessthan15%water,bymass:UNNo0151Substanceconsistingofanintimatemixtureofpentaerythritetetranitrate(PETN)andtrinitrotoluene(TNT).POWDERCAKE(POWDERPASTE),WETTEDwithnotlessthan17%alcohol,bymass.POWDERCAKE(POWDERPASTE),WETTEDwithnotlessthan25%water,bymass:UNNos0433,0159Substanceconsistingofnitrocelluloseimpregnatedwithnotmorethan60%ofnitroglycerineorotherliquidorganicnitratesoramixtureofthese.POWDER,SMOKELESS:UNNos0160,0161Substancebasedonnitrocelluloseusedaspropellant.Thetermincludespropellantswithasinglebase(nitrocellulose(NC)alone),thosewithadoublebase(suchasNCandnitroglycerine/(NG))andthosewithatriplebase(suchasNC/NG/nitroguanidine).NOTECast,pressedorbag-chargesofsmokelesspowderarelistedunderCHARGES,PROPELLING,orCHARGES,PROPELLING,FORCANNON.PRIMERS,CAPTYPE:UNNos0044,0377,0378Articlesconsistingofametalorplasticscapcontainingasmallamountofprimaryexplosivemixturethatisreadilyignitedbyimpact.Theyserveasignitingelementsinsmallarmscartridgesandinpercussionprimersforpropellingcharges.PRIMERS,TUBULAR:UNNos0319,0320,0376Articlesconsistingofaprimerforignitionandanauxiliarychargeofdeflagratingexplosivesuchasblackpowderusedtoignitethepropellingchargeinacartridgecaseforcannonetc.PROJECTILES,inertwithtracer:UNNos0345,0424,0425Articlessuchasashellorbullet,whichareprojectedfromacannonorothergun,rifleorothersmallarm.PROJECTILES,withbursterorexpellingcharge:UNNos0346,0347Articlessuchasashellorbullet,whichareprojectedfromacannonorothergun.Theyarewithoutmeansofinitiationorwithmeansofinitiationcontainingtwoormoreeffectiveprotectivefeatures.Theyareusedtoscatterdyesforspottingorotherinertmaterials.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/49PROJECTILES,withbursterorexpellingcharge:UNNos0426,0427Articlessuchasashellorbullet,whichareprojectedfromacannonorothergun.Theyarewithmeansofinitiationnotcontainingtwoormoreeffectiveprotectivefeatures.Theyareusedtoscatterdyesforspottingorotherinertmaterials.PROJECTILES,withbursterorexpellingcharge:UNNos0434,0435Articlessuchasashellorbullet,whichareprojectedfromacannonorothergun,rifleorothersmallarm.Theyareusedtoscatterdyesforspottingorotherinertmaterials.PROJECTILES,withburstingcharge:UNNos0168,0169,0344Articlessuchasashellorbullet,whichareprojectedfromacannonorothergun.Theyarewithoutmeansofinitiationorwithmeansofinitiationcontainingtwoormoreeffectiveprotectivefeatures.PROJECTILES,withburstingcharge:UNNos0167,0324Articlessuchasashellorbullet,whichareprojectedfromacannonorothergun.Theyarewithmeansofinitiationnotcontainingtwoormoreeffectiveprotectivefeatures.PROPELLANT,LIQUID:UNNos0495,0497Substanceconsistingofadeflagratingliquidexplosive,usedforpropulsion.PROPELLANT,SOLID:UNNos0498,0499,0501Substanceconsistingofadeflagratingsolidexplosive,usedforpropulsion.RELEASEDEVICES,EXPLOSIVE:UNNo0173Articlesconsistingofasmallchargeofexplosivewithmeansofinitiationandrodsorlinks.Theysevertherodsorlinkstoreleaseequipmentquickly.RIVETS,EXPLOSIVE:UNNo0174Articlesconsistingofasmallchargeofexplosiveinsideametallicrivet.ROCKETMOTORS:UNNos0186,0280,0281Articlesconsistingofachargeofexplosive,generallyasolidpropellant,containedinacylinderfittedwithoneormorenozzles.Theyaredesignedtopropelarocketoraguidedmissile.ROCKETMOTORS,LIQUIDFUELLED:UNNos0395,0396Articlesconsistingofaliquidfuelwithinacylinderfittedwithoneormorenozzles.Theyaredesignedtopropelarocketoraguidedmissile.ROCKETMOTORSWITHHYPERGOLICLIQUIDSwithorwithoutexpellingcharge:UNNos0322,0250Articlesconsistingofahypergolicfuelcontainedinacylinderfittedwithoneormorenozzles.Theyaredesignedtopropelarocketoraguidedmissile.ROCKETS,LINETHROWING:UNNos0238,0240,0453Articlesconsistingofarocketmotorwhichisdesignedtoextendaline.ROCKETS,LIQUIDFUELLED,withburstingcharge:UNNos0397,0398Articlesconsistingofaliquidfuelwithinacylinderfittedwithoneormorenozzlesandfittedwithawarhead.Thetermincludesguidedmissiles.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/50ROCKETSwithburstingcharge:UNNos0181,0182Articlesconsistingofarocketmotorandawarheadwithoutmeansofinitiationorwithmeansofinitiationcontainingtwoormoreeffectiveprotectivefeatures.Thetermincludesguidedmissiles.ROCKETS,withburstingcharge:UNNos0180,0295Articlesconsistingofarocketmotorandawarheadwithmeansofinitiationnotcontainingtwoormoreeffectiveprotectivefeatures.Thetermincludesguidedmissiles.ROCKETS,withexpellingcharge:UNNos0436,0437,0438Articlesconsistingofarocketmotorandachargetoexpelthepayloadfromarockethead.Thetermincludesguidedmissiles.ROCKETS,withinerthead:UNNos0183,0502Articlesconsistingofarocketmotorandaninerthead.Thetermincludesguidedmissiles.SAMPLES,EXPLOSIVE,otherthaninitiatingexplosiveUNNo0190Neworexistingexplosivesubstancesorarticles,notyetassignedtoanameinTableAofChapter3.2andcarriedinconformitywiththeinstructionsofthecompetentauthorityandgenerallyinsmallquantities,interalia,forthepurposesoftesting,classification,researchanddevelopment,orqualitycontrol,orascommercialsamples.NOTEExplosivesubstancesorarticlesalreadyassignedtoanothernameinTableAofChapter3.2arenotincludedinthisdefinition.SIGNALDEVICES,HAND:UNNos0191,0373Portablearticlescontainingpyrotechnicsubstanceswhichproducevisualsignalsorwarnings.Thetermincludessmallsurfaceflaressuchashighwayorrailwayflaresandsmalldistressflares.SIGNALS,DISTRESS,ship:UNNos0194,0195Articlescontainingpyrotechnicsubstancesdesignedtoproducesignalsbymeansofsound,flameorsmokeoranycombinationthereof.SIGNALS,RAILWAYTRACK,EXPLOSIVE:UNNos0192,0193,0492,0493Articlescontainingapyrotechnicsubstancewhichexplodeswithaloudreportwhenthearticleiscrushed.Theyaredesignedtobeplacedonarail.SIGNALS,SMOKE:UNNos0196,0197,0313,0487Articlescontainingpyrotechnicsubstanceswhichemitsmoke.Inadditiontheymaycontaindevicesforemittingaudiblesignals.SOUNDINGDEVICES,EXPLOSIVE:UNNos0374,0375Articlesconsistingofachargeofdetonatingexplosive,withoutmeansofinitiationorwithmeansofinitiationcontainingtwoormoreeffectiveprotectivefeatures.Theyaredroppedfromshipsandfunctionwhentheyreachapredetermineddepthortheseabed.SOUNDINGDEVICES,EXPLOSIVE:UNNos0204,0296Articlesconsistingofachargeofdetonatingexplosivewithmeansofinitiationnotcontainingtwoormoreeffectiveprotectivefeatures.Theyaredroppedfromshipsandfunctionwhentheyreachapredetermineddepthortheseabed.SUBSTANCES,EXPLOSIVE,VERYINSENSITIVE(Substances,EVI),N.O.S:UNNo0482Substancespresentingamassexplosionhazardbutwhicharesoinsensitivethatthereisverylittleprobabilityofinitiationoroftransitionfromburningtodetonationundernormalconditionsoftransport,andwhichhavepassedtestseries5.TORPEDOES,LIQUIDFUELLED,withinerthead:UNNo0450Articlesconsistingofaliquidexplosivesystemtopropelthetorpedothroughthewater,withaninerthead.TORPEDOES,LIQUIDFUELLED,withorwithoutburstingcharge:UNNo0449Articlesconsistingofeitheraliquidexplosivesystemtopropelthetorpedothroughthewater,withorwithoutawarhead;oraliquidnon-explosivesystemtopropelthetorpedothroughthewater,withawarhead.TORPEDOES,withburstingcharge:UNNo0451Articlesconsistingofanon-explosivesystemtopropelthetorpedothroughthewater,andawarheadwithoutmeansofinitiationorwithmeansofinitiationcontainingtwoormoreeffectiveprotectivefeatures.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/51TORPEDOES,withburstingcharge:UNNo0329Articlesconsistingofanexplosivesystemtopropelthetorpedothroughthewater,andawarheadwithoutmeansofinitiationorwithmeansofinitiationcontainingtwoormoreeffectiveprotectivefeatures.TORPEDOES,withburstingcharge:UNNo0330Articlesconsistingofanexplosiveornon-explosivesystemtopropelthetorpedothroughthewater,andawarheadwithmeansofinitiationnotcontainingtwoormoreeffectiveprotectivefeatures.TRACERSFORAMMUNITION:UNNos0212,0306Sealedarticlescontainingpyrotechnicsubstances,designedtorevealthetrajectoryofaprojectile.TRITONAL:UNNo0390Substanceconsistingoftrinitrotoluene(TNT)mixedwithaluminium.WARHEADS,ROCKET,withbursterorexpellingcharge:UNNo0370Articlesconsistingofaninertpayloadandasmallchargeofdetonatingordeflagratingexplosive,withoutmeansofinitiationorwithmeansofinitiationcontainingtwoormoreeffectiveprotectivefeatures.Theyaredesignedtobefittedtoarocketmotortoscatterinertmaterial.Thetermincludeswarheadsforguidedmissiles.WARHEADS,ROCKET,withbursterorexpellingcharge:UNNo0371Articlesconsistingofaninertpayloadandasmallchargeofdetonatingordeflagratingexplosive,withmeansofinitiationnotcontainingtwoormoreeffectiveprotectivefeatures.Theyaredesignedtobefittedtoarocketmotortoscatterinertmaterial.Thetermincludeswarheadsforguidedmissiles.WARHEADS,ROCKET,withburstingcharge:UNNos0286,0287Articlesconsistingofadetonatingexplosive,withoutmeansofinitiationorwithmeansofinitiationcontainingtwoormoreeffectiveprotectivefeatures.Theyaredesignedtobefittedtoarocket.Thetermincludeswarheadsforguidedmissiles.WARHEADS,ROCKET,withburstingcharge:UNNo0369Articlesconsistingofadetonatingexplosive,withmeansofinitiationnotcontainingtwoormoreeffectiveprotectivefeatures.Theyaredesignedtobefittedtoarocket.Thetermincludeswarheadsforguidedmissiles.WARHEADS,TORPEDO,withburstingcharge:UNNo0221Articlesconsistingofadetonatingexplosive,withoutmeansofinitiationorwithmeansofinitiationcontainingtwoormoreeffectiveprotectivefeatures.Theyaredesignedtobefittedtoatorpedo.2.2.1.2.Substancesandarticlesnotacceptedforcarriage2.2.1.2.1.ExplosivesubstanceswhichareundulysensitiveaccordingtothecriteriaoftheManualoftestsandcriteria,PartI,orareliabletospontaneousreaction,aswellasexplosivesubstancesandarticleswhichcannotbeassignedtoanameorn.o.sentrylistedinTableAofChapter3.2,shallnotbeacceptedforcarriage.2.2.1.2.2.ArticlesofcompatibilitygroupKshallnotbeacceptedforcarriage(1.2K,UNNo0020and1.3K,UNNo0021).2.2.1.3.ListofcollectiveentriesClassificationcode(see2.2.1.1.4)UNNoNameofthesubstanceorarticle1.1A0473SUBSTANCES,EXPLOSIVE,N.O.S1.1B0461COMPONENTS,EXPLOSIVETRAIN,N.O.S1.1C0474SUBSTANCES,EXPLOSIVE,N.O.S0497PROPELLANT,LIQUID0498PROPELLANT,SOLID0462ARTICLES,EXPLOSIVE,N.O.S1.1D0475SUBSTANCES,EXPLOSIVE,N.O.S0463ARTICLES,EXPLOSIVE,N.O.S1.1E0464ARTICLES,EXPLOSIVE,N.O.S1.1F0465ARTICLES,EXPLOSIVE,N.O.S1.1G0476SUBSTANCES,EXPLOSIVE,N.O.SOfficialJournaloftheEuropeanUnionEN26.1.2004L18/52Classificationcode(see2.2.1.1.4)UNNoNameofthesubstanceorarticle1.1L0357SUBSTANCES,EXPLOSIVE,N.O.S0354ARTICLES,EXPLOSIVE,N.O.S1.2B0382COMPONENTS,EXPLOSIVETRAIN,N.O.S1.2C0466ARTICLES,EXPLOSIVE,N.O.S1.2D0467ARTICLES,EXPLOSIVE,N.O.S1.2E0468ARTICLES,EXPLOSIVE,N.O.S1.2F0469ARTICLES,EXPLOSIVE,N.O.S1.2L0358SUBSTANCES,EXPLOSIVE,N.O.S0248CONTRIVANCES,WATER-ACTIVATEDwithburster,expellingchargeorpropellingcharge0355ARTICLES,EXPLOSIVE,N.O.S1.3C0132DEFLAGRATINGMETALSALTSOFAROMATICNITRO-DERIVATIVES,N.O.S0477SUBSTANCES,EXPLOSIVE,N.O.S0495PROPELLANT,LIQUID0499PROPELLANT,SOLID0470ARTICLES,EXPLOSIVE,N.O.S1.3G0478SUBSTANCES,EXPLOSIVE,N.O.S1.3L0359SUBSTANCES,EXPLOSIVE,N.O.S0249CONTRIVANCES,WATER-ACTIVATEDwithburster,expellingchargeorpropellingcharge0356ARTICLES,EXPLOSIVE,N.O.S1.4B0350ARTICLES,EXPLOSIVE,N.O.S0383COMPONENTS,EXPLOSIVETRAIN,N.O.S1.4C0479SUBSTANCES,EXPLOSIVE,N.O.S0351ARTICLES,EXPLOSIVE,N.O.S1.4D0480SUBSTANCES,EXPLOSIVE,N.O.S0352ARTICLES,EXPLOSIVE,N.O.S1.4E0471ARTICLES,EXPLOSIVE,N.O.S1.4F0472ARTICLES,EXPLOSIVE,N.O.S1.4G0485SUBSTANCES,EXPLOSIVE,N.O.S0353ARTICLES,EXPLOSIVE,N.O.S1.4S0481SUBSTANCES,EXPLOSIVE,N.O.S0349ARTICLES,EXPLOSIVE,N.O.S0384COMPONENTS,EXPLOSIVETRAIN,N.O.S1.5D0482SUBSTANCES,EXPLOSIVE,VERYINSENSITIVE(SUBSTANCES,EVI)N.O.S1.6N0486ARTICLES,EXPLOSIVE,EXTREMELYINSENSITIVE(ARTICLES,EEI)0190SAMPLES,EXPLOSIVEotherthaninitiatingexplosiveNOTEDivisionandcompatibilitygroupshallbedefinedasdirectedbythecompetentauthorityandaccordingtotheprinciplesin2.2.1.1.4.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/532.2.2.Class2Gases2.2.2.1.Criteria2.2.2.1.1.TheheadingofClass2coverspuregases,mixturesofgases,mixturesofoneormoregaseswithoneormoreothersubstancesandarticlescontainingsuchsubstances.Agasisasubstancewhich:(a)at50°Chasavapourpressuregreaterthan300kPa(3bar);or(b)iscompletelygaseousat20°Catthestandardpressureof101,3kPa.NOTE1.UNNo1052HYDROGENFLUORIDEisneverthelessclassifiedinClass8.2.Apuregasmaycontainothercomponentsderivingfromitsproductionprocessoraddedtopreservethestabilityoftheproduct,providedthatthelevelofthesecomponentsdoesnotchangeitsclassificationoritsconditionsofcarriage,suchasfillingratio,fillingpressure,testpressure.3.NOSentriesin2.2.2.3maycoverpuregasesaswellasmixtures.2.2.2.1.2.ThesubstancesandarticlesofClass2aresubdividedasfollows:1.compressedgases:gaseshavingacriticaltemperaturebelow20°C;2.liquefiedgases:gaseshavingacriticaltemperatureof20°Corabove;3.refrigeratedliquefiedgases:gaseswhichwhencarriedarepartiallyliquidbecauseoftheirlowtemperature;4.gasesdissolvedunderpressure:gaseswhichwhencarriedaredissolvedinasolvent;5.aerosoldispensersandreceptacles,small,containinggas(gascartridges);6.otherarticlescontaininggasunderpressure;7.non-pressurisedgasessubjecttospecialrequirements(gassamples).2.2.2.1.3.SubstancesandarticlesofClass2areassignedtooneofthefollowinggroupsaccordingtotheirhazardousproperties,asfollows:Aasphyxiant;Ooxidising;Fflammable;Ttoxic;TFtoxic,flammable;TCtoxic,corrosive;TOtoxic,oxidising;TFCtoxic,flammable,corrosive;TOCtoxic,oxidising,corrosive.Forgasesandgasmixturespresentinghazardouspropertiesassociatedwithmorethanonegroupaccordingtothecriteria,thegroupsdesignatedbyletterTtakeprecedenceoverallothergroups.ThegroupsdesignatedbyletterFtakeprecedenceoverthegroupsdesignatedbylettersAorO.NOTE1.IntheUNmodelregulations,theIMDGcodeandtheICAOtechnicalInstructions,gasesareassignedtooneofthefollowingthreedivisions,basedontheprimaryhazard:Division2.1:flammablegases(correspondingtothegroupsdesignatedbythecapitalletterF);Division2.2:non-flammable,non-toxicgases(correspondingtothegroupsdesignatedbythecapitallettersAorO);Division2.3:toxicgases(correspondingtothegroupsdesignatedbythecapitalletterT(i.e.T,TF,TC,TO,TFCandTOC).OfficialJournaloftheEuropeanUnionEN26.1.2004L18/542.Aerosolsandreceptacles,small,containinggasshallbeassigned,accordingtothehazardofthecontents,tothelettersAtoTOC.Thecontentsareconsideredtobeflammableiftheyincludemorethan45%bymass,ormorethan250g,offlammablecomponents.Flammablecomponentsaregaseswhichareflammableinairatnormalpressureorsubstancesorpreparationsinliquidformwhichhaveaflash-pointlessthanorequalto100°C.3.Corrosivegasesareconsideredtobetoxic,andarethereforeassignedtothegroupTC,TFCorTOC.4.Mixturescontainingmorethan21%oxygenbyvolumeshallbeclassifiedasoxidising.2.2.2.1.4.IfamixtureofClass2mentionedbynameinTableAofChapter3.2meetsdifferentcriteriaasmentionedin2.2.2.1.2and2.2.2.1.5,thismixtureshallbeclassifiedaccordingtothecriteriaandassignedtoanappropriateN.O.Sentry.2.2.2.1.5.SubstancesandarticlesofClass2whicharenotmentionedbynameinTableAofChapter3.2shallbeclassifiedunderacollectiveentrylistedin2.2.2.3inaccordancewith2.2.2.1.2and2.2.2.1.3.Thefollowingcriteriashallapply.AsphyxiantgasesGaseswhicharenon-oxidising,non-flammableandnon-toxicandwhichdiluteorreplaceoxygennormallyintheatmosphere.FlammablegasesGaseswhichat20°Candastandardpressureof101,3kPa:(a)areignitablewheninamixtureof13%orlessbyvolumewithair;or(b)haveaflammablerangewithairofatleast12percentagepointsregardlessofthelowerflammablelimit.Flammabilityshallbedeterminedbytestsorbycalculation,inaccordancewithmethodsadoptedbyISO(seeISO10156:1996).Whereinsufficientdataareavailabletousethesemethods,testsbyacomparablemethodrecognisedbythecompetentauthorityofthecountryoforiginmaybeused.IfthecountryoforiginisnotaMemberStatethesemethodsshallberecognisedbythecompetentauthorityofthefirstcountryMemberStatereachedbytheconsignment.OxidisinggasesGases,whichmay,generallybyprovidingoxygen,causeorcontributetothecombustionofothermaterialmorethanairdoes.OxidisingabilityisdeterminedeitherbytestsorbycalculationmethodsadoptedbyISO(seeISO10156:1996).ToxicgasesNOTEGasesmeetingthecriteriafortoxicityinpartorcompletelyowingtotheircorrosivityaretobeclassifiedastoxic.Seealsothecriteriaundertheheading‘Corrosivegases’forapossiblesubsidiarycorrosivityrisk.Gaseswhich:(a)areknowntobesotoxicorcorrosivetohumansastoposeahazardtohealth;or(b)arepresumedtobetoxicorcorrosivetohumansbecausetheyhaveaLC50valueforacutetoxicityequaltoorlessthan5000ml/m3(ppm)whentestedinaccordancewith2.2.61.1.Inthecaseofgasmixtures(includingvapoursofsubstancesfromotherclasses)thefollowingformulamaybeused:OfficialJournaloftheEuropeanUnionEN26.1.2004L18/55wherefi=molefractionoftheithcomponentsubstanceofthemixture.Ti=toxicityindexoftheithcomponentsubstanceofthemixture.TheTiequalstheLC50valueasfoundinISO10298:1995.WhennoLC50valueislistedinISO10298:1995,aLC50valueavailableinscientificliteratureshallbeused.WhentheLC50valueisunknown,thetoxicityindexisdeterminedbyusingthelowestLC50valueofsubstancesofsimilarphysiologicalandchemicaleffects,orthroughtestingifthisistheonlypracticalpossibility.CorrosivegasesGasesorgasmixturesmeetingthecriteriafortoxicitycompletelyowingtotheircorrosivityaretobeclassifiedastoxicwithasubsidiarycorrosivityrisk.Agasmixturethatisconsideredtobetoxicduetothecombinedeffectsofcorrosivityandtoxicityhasasubsidiaryriskofcorrosivitywhenthemixtureisknownbyhumanexperiencetobedestructivetotheskin,eyesormucousmembranesorwhentheLC50valueofthecorrosivecomponentsofthemixtureisequaltoorlessthan5000ml/m3(ppm)whentheLC50iscalculatedbytheformula:wherefci=molefractionoftheithcorrosivecomponentsubstanceofthemixtureTci=toxicityindexoftheithcorrosivecomponentsubstanceofthemixture.TheTciequalstheLC50valueasfoundinISO10298:1995.WhennoLC50valueislistedinISO10298:1995,aLC50valueavailableinscientificliteratureshallbeused.WhentheLC50valueisunknownthetoxicityindexisdeterminedbyusingthelowestLC50valueofsubstancesofsimilarphysiologicalandchemicaleffects,orthroughtestingifthisistheonlypracticalpossibility.2.2.2.2.Gasesnotacceptedforcarriage2.2.2.2.1.ChemicallyunstablesubstancesofClass2shallnotbeacceptedforcarriage,unlessthenecessarystepshavebeentakentopreventallpossibilityofadangerousreactione.g.decomposition,dismutationorpolymerisationundernormalconditionsduringtransport.Tothisendparticularcareshallbetakentoensurethatreceptaclesandtanksdonotcontainanysubstancesliabletopromotethesereactions.2.2.2.2.2.Thefollowingsubstancesandmixturesshallnotbeacceptedforcarriage:—UNNo2186HYDROGENCHLORIDE,REFRIGERATEDLIQUID,—UNNo2421NITROGENTRIOXIDE,—UNNo2455METHYLNITRITE,—refrigeratedliquefiedgaseswhichcannotbeassignedtoclassificationcodes3A,3Oor3F,—gasesdissolvedunderpressurewhichcannotbeclassifiedunderUNNos1001,2073or3318.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/562.2.2.3.ListofcollectiveentriesCompressedgasesClassificationcodeUNNoNameofthesubstanceorarticle1A1979RAREGASESMIXTURE,COMPRESSED1980RAREGASESANDOXYGENMIXTURE,COMPRESSED1981RAREGASESANDNITROGENMIXTURE,COMPRESSED1956COMPRESSEDGAS,N.O.S1O3156COMPRESSEDGAS,OXIDISING,N.O.S1F1964HYDROCARBONGASMIXTURE,COMPRESSED,N.O.S1954COMPRESSEDGAS,FLAMMABLE,N.O.S1T1955COMPRESSEDGAS,TOXIC,N.O.S1TF1953COMPRESSEDGAS,TOXIC,FLAMMABLE,N.O.S1TC3304COMPRESSEDGAS,TOXIC,CORROSIVE,N.O.S1TO3303COMPRESSEDGAS,TOXIC,OXIDISING,N.O.S1TFC3305COMPRESSEDGAS,TOXIC,FLAMMABLE,CORROSIVE,N.O.S1TOC3306COMPRESSEDGAS,TOXIC,OXIDISING,CORROSIVE,N.O.SLiquefiedgasesClassificationcodeUNNoNameofthesubstanceorarticle2A1058LIQUEFIEDGASES,non-flammable,chargedwithnitrogen,carbondioxideorair1078REFRIGERANTGAS,N.O.Ssuchasmixturesofgases,IndicatedbytheletterR.,whichas:MixtureF1,haveavapourpressureat70°Cnotexceeding1,3MPa(13bar)andadensityat50°Cnotlowerthanthatofdichlorofluoromethane(1,30kg/l);MixtureF2,haveavapourpressureat70°Cnotexceeding1,9MPa(19bar)andadensityat50°Cnotlowerthanthatofdichlorodifluoromethane(1,21kg/l);MixtureF3,haveavapourpressureat70°Cnotexceeding3MPa(30bar)andadensityat50°Cnotlowerthanthatofchlorodifluoromethane(1,09kg/l).NOTETrichlorofluoromethane(RefrigerantgasR11),1,1,2-trichloro-1,2,2-trifluoroethane(RefrigerantgasR113),1,1,1-trichloro-2,2,2-trifluoroethane(RefrigerantgasR113a),1-chloro-1,2,2-trifluoroethane(RefrigerantgasR133)and1-chloro-1,1,2-trifluoroethane(RefrigerantgasR133b)arenotsubstancesofClass2.Theymay,however,enterintothecompositionofmixturesF1toF3.1968INSECTICIDEGAS,N.O.S3163LIQUEFIEDGAS,N.O.S2O3157LIQUEFIEDGAS,OXIDISING,N.O.SOfficialJournaloftheEuropeanUnionEN26.1.2004L18/57LiquefiedgasesClassificationcodeUNNoNameofthesubstanceorarticle2F1010Mixturesof1,3-BUTADIENEANDHYDROCARBONS,STABILISED,havingavapourpressureat70°Cnotexceeding1,1MPa(11bar)andadensityat50°Cnotlowerthan0,525kg/l.NOTE1,2-butadiene,stabilisedand1,3-butadiene,stabilisedareclassifiedunderUNNo1010,seeTableAofChapter3.21060METHYLACETYLENEANDPROPADIENEMIXTURE,STABILISEDsuchasmixturesofmethyla-cetyleneandpropadienewithhydrocarbons,whichas:MixtureP1,containnotmorethan63%methylacetyleneandpropadienebyvolumeandnotmorethan24%propaneandpropylenebyvolume,thepercentageofC4-saturatedhydro-carbonsbeingnotlessthan14%byvolume;andasMixtureP2,containnotmorethan48%methylacetyleneandpropadienebyvolumeandnotmorethan50%propaneandpropylenebyvolume,thepercentageofC4-saturatedhydro-carbonsbeingnotlessthan5%byvolume,aswellasmixturesofpropadienewith1to4%methylacetylene1965HYDROCARBONGASMIXTURE,LIQUEFIED,N.O.Ssuchasmixtures,whichas:MixtureA,haveavapourpressureat70°Cnotexceeding1,1MPa(11bar)andadensityat50°Cnotlowerthan0,525kg/l;MixtureA01,haveavapourpressureat70°Cnotexceeding1,6MPa(16bar)andarelativedensityat50°Cnotlowerthan0,516kg/l;MixtureA02,haveavapourpressureat70°Cnotexceeding1,6MPa(16bar)andarelativedensityat50°Cnotlowerthan0,505kg/l;MixtureA0,haveavapourpressureat70°Cnotexceeding1,6MPa(16bar)andadensityat50°Cnotlowerthan0,495kg/l;MixtureA1,haveavapourpressureat70°Cnotexceeding2,1MPa(21bar)andadensityat50°Cnotlowerthan0,485kg/l;MixtureB1haveavapourpressureat70°Cnotexceeding2,6MPa(26bar)andarelativedensityat50°Cnotlowerthan0,474kg/l;MixtureB2haveavapourpressureat70°Cnotexceeding2,6MPa(26bar)andarelativedensityat50°Cnotlowerthan0,463kg/l;MixtureB,haveavapourpressureat70°Cnotexceeding2,6MPa(26bar)andadensityat50°Cnotlowerthan0,450kg/l;MixtureC,haveavapourpressureat70°Cnotexceeding3,1MPa(31bar)andarelativedensityat50°Cnotlowerthan0,440kg/l;NOTE1.Inthecaseoftheforegoingmixtures,theuseofthefollowingnamescustomaryinthetradeispermittedfordescribingthesesubstances:formixtureA01,A02andA0:BUTANE;formixtureC:PROPANE.2.UNNo1075PETROLEUMGASES,LIQUEFIEDmaybeusedasanalternativeentryforUNNo1965HYDROCARBONGASMIXTURELIQUEFIED,N.O.Sforcarriagepriortoorfollowingmaritimeoraircarriage.3354INSECTICIDEGAS,FLAMMABLE,N.O.S3161LIQUEFIEDGAS,FLAMMABLE,N.O.S2T1967INSECTICIDEGAS,TOXIC,N.O.S3162LIQUEFIEDGAS,TOXIC,N.O.S2TF3355INSECTICIDEGAS,TOXIC,FLAMMABLE,N.O.S3160LIQUEFIEDGAS,TOXIC,FLAMMABLE,N.O.SOfficialJournaloftheEuropeanUnionEN26.1.2004L18/58LiquefiedgasesClassificationcodeUNNoNameofthesubstanceorarticle2TC3308LIQUEFIEDGAS,TOXIC,CORROSIVE,N.O.S2TO3307LIQUEFIEDGAS,TOXIC,OXIDISING,N.O.S2TFC3309LIQUEFIEDGAS,TOXIC,FLAMMABLE,CORROSIVE,N.O.S2TOC3310LIQUEFIEDGAS,TOXIC,OXIDISING,CORROSIVE,N.O.SRefrigeratedliquefiedgasesClassificationcodeUNNoNameofthesubstanceorarticle3A3158GAS,REFRIGERATEDLIQUID,N.O.S3O3311GAS,REFRIGERATEDLIQUID,OXIDISING,N.O.S3F3312GAS,REFRIGERATEDLIQUID,FLAMMABLE,N.O.SGases,dissolvedunderpressureClassificationcodeUNNoNameofthesubstanceorarticle4OnlysubstanceslistedinTableAofChapter3.2aretobeacceptedforcarriageAerosolsandreceptacles,small,containinggasClassificationcodeUNNoNameofthesubstanceorarticle51950AEROSOLS2037RECEPTACLES,SMALLCONTAININGGAS(GASCARTRIDGES)withoutareleasedevice,non-refillableOtherarticlescontaininggasunderpressureClassificationcodeUNNoNameofthesubstanceorarticle6A3164ARTICLES,PRESSURISED,PNEUMATIC(containingnon-flammablegas)or3164ARTICLES,PRESSURISED,HYDRAULIC(containingnon-flammablegas)6F3150DEVICES,SMALL,HYDROCARBONGASPOWEREDor3150HYDROCARBONGASREFILLSFORSMALLDEVICES,withreleasedeviceOfficialJournaloftheEuropeanUnionEN26.1.2004L18/59GassamplesClassificationcodeUNNoNameofthesubstanceorarticle7F3167GASSAMPLE,NON-PRESSURISED,FLAMMABLE,N.O.S,notrefrigeratedliquid7T3169GASSAMPLE,NON-PRESSURISED,TOXIC,N.O.S,notrefrigeratedliquid7TF3168GASSAMPLE,NON-PRESSURISED,TOXIC,FLAMMABLE,N.O.S,notrefrigeratedliquid2.2.3.Class3Flammableliquids2.2.3.1.Criteria2.2.3.1.1.TheheadingofClass3coverssubstancesandarticlescontainingsubstancesofthisclasswhich:—areliquidsaccordingtosubparagraph(a)ofthedefinitionfor‘liquid’in1.2.1;—haveat50°Cavapourpressureofnotmorethan300kPa(3bar)andarenotcompletelygaseousat20°Candatstandardpressureof101,3kPa;and—haveaflash-pointofnotmorethan61°C(see2.3.3.1fortherelevanttest).TheheadingofClass3alsocoversliquidsubstancesandmoltensolidsubstanceswithaflash-pointofmorethan61°Candwhicharecarriedorhandedoverforcarriagewhilstheatedattemperaturesequaltoorhigherthantheirflash-point.ThesesubstancesareassignedtoUNNo3256.TheheadingofClass3alsocoversliquiddesensitisedexplosives.Liquiddesensitisedexplosivesareexplosivesubstanceswhicharedissolvedorsuspendedinwaterorotherliquidsubstances,toformanhomogeneousliquidmixturetosuppresstheirexplosiveproperties.SuchentriesinTableAofChapter3.2areUNNos1204,2059,3064,3343and3357.NOTE1.Substanceshavingaflash-pointabove35°C,non-toxicandnon-corrosive,which,underthesustainedcombustibilitytestconditionsgiveninsubsection32.5.2ofPartIIIoftheManualoftestsandcriteriadonotsustaincombustionarenotsubstancesofClass3;if,however,thesesubstancesarehandedoverforcarriageandcarriedwhilstheatedattemperaturesequaltoorhigherthantheirflash-point,theyaresubstancesofClass3.2.Byderogationfromparagraph2.2.3.1.1,dieselfuel,gasoil,heatingoil(light)havingaflash-pointabove61°Candnotmorethan100°CshallbedeemedsubstancesofClass3,UNNo1202.3.Liquidswhicharehighlytoxiconinhalation,havingaflash-pointbelow23°Candtoxicsubstances,havingaflash-pointof23°CorabovearesubstancesofClass6.1(see2.2.61.1).4.Flammableliquidsubstancesandpreparations,usedaspesticides,whicharehighlytoxic,toxicorslightlytoxicandhaveaflash-pointof23°CorabovearesubstancesofClass6.1(see2.2.61.1).5.Corrosiveliquidshavingaflash-pointof23°CorabovearesubstancesofClass8(see2.2.8.1).6.UNNo2734AMINES,LIQUID,CORROSIVE,FLAMMABLE,N.O.S,UNNo2734POLYAMINES,LIQUID,CORROSIVE,FLAMMABLE,N.O.SandUNNo2920CORROSIVELIQUID,FLAMMABLE,N.O.SaresubstancesofClass8(see2.2.8.1).7.Pharmaceuticalproductsreadyforuse,e.g.cosmetics,drugsandmedicines,whicharesubstancesmanufacturedandpackedinpackagingsofatypeintendedforretailsaleordistributionforpersonalorhouseholdconsumptionarenotsubjecttotheprovisionsofthisDirective.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/602.2.3.1.2.ThesubstancesandarticlesofClass3aresubdividedasfollows:Fflammableliquids,withoutsubsidiaryrisk:F1flammableliquidshavingaflash-pointoforbelow61°C;F2flammableliquidshavingaflash-pointabove61°Cwhicharecarriedorhandedoverforcarriageatorabovetheirflash-point(elevatedtemperaturesubstances);FTflammableliquids,toxic:FT1flammableliquids,toxic;FT2Pesticides;FCflammableliquids,corrosive;FTCflammableliquids,toxic,corrosive;Dliquiddesensitisedexplosives.2.2.3.1.3.SubstancesandarticlesclassifiedinClass3arelistedinTableAofChapter3.2.SubstancesnotmentionedbynameinTableAofChapter3.2shallbeassignedtotherelevantentryof2.2.3.3andtherelevantpackinggroupinaccordancewiththeprovisionsofthissection.Flammableliquidsshallbeassignedtooneofthefollowingpackinggroupsaccordingtothedegreeofdangertheypresentforcarriage:PackinggroupI:substancespresentinghighdanger:flammableliquidshavingaboilingpointorinitialboilingpointnotexceeding35°C,andflammableliquidshavingaflash-pointbelow23°C,whichareeitherhighlytoxicaccordingtothecriteriaof2.2.61.1orhighlycorrosiveaccordingtothecriteriaof2.2.8.1;PackinggroupII:substancespresentingmediumdanger:flammableliquidshavingaflash-pointbelow23°CwhicharenotclassifiedunderpackinggroupI,withtheexceptionofsubstancesof2.2.3.1.4;PackinggroupIII:substancespresentinglowdanger:flammableliquidshavingaflash-pointof23°Cto61°Cinclusiveandsubstancesof2.2.3.1.4.2.2.3.1.4.Liquidorviscousmixturesandpreparations,includingthosecontainingnomorethan20%nitrocellulosewithanitrogencontentnotexceeding12,6%(bydrymass),shallbeassignedtopackinggroupIIIonlyifthefollowingrequirementsaremet:(a)theheightoftheseparatedlayerofsolventislessthan3%ofthetotalheightofthesampleinthesolvent-separationtest(seeManualoftestsandcriteria,PartIII,subsection32.5.1);and(b)theviscosity(1)andflash-pointareinaccordancewiththefollowingtable.Kinematicviscosity(extrapolated)<(atnear-zeroshearrate)mm2/sat23°CFlowtimetinaccordancewithISO2431:1993Flash-pointin°CinsJetdiameterinmm20<v≤8020<t≤604above1780<v≤13560<t≤1004above10135<v≤22020<t≤326above5220<v≤30032<t≤446above–1300<v≤70044<t≤1006above–5700<v100<t6–5andbelowNOTEMixturescontainingmorethan20%butnotmorethan55%nitrocellulosewithanitrogencontentnotexceeding12,6%bydrymassaresubstancesassignedtoUNNo2059.Mixtureshavingaflash-pointbelow23°Candcontaining:—morethan55%nitrocellulose,whatevertheirnitrogencontent;or—notmorethan55%nitrocellulosewithanitrogencontentabove12,6%bydrymass,aresubstancesofClass1(UNNo0340or0342)orofClass4.1(UNNo2555,2556or2557).OfficialJournaloftheEuropeanUnionEN26.1.2004L18/61(1)Viscositydetermination:Wherethesubstanceconcernedisnon-Newtonian,orwhereaflowcupmethodofviscositydeterminationisotherwiseunsuitable,avariableshear-rateviscometershallbeusedtodeterminethedynamicviscositycoefficientofthesubstance,at23°C,atanumberofshearrates.Thevaluesobtainedareplottedagainstshearrateandthenextrapolatedtozeroshearrate.Thedynamicviscositythusobtained,dividedbythedensity,givestheapparentkinematicviscosityatnear-zeroshearrate.2.2.3.1.5.Non-toxicandnon-corrosivesolutionsandhomogeneousmixtureshavingaflash-pointof23°Corabove(viscoussubstances,suchaspaintsorvarnishes,excludingsubstancescontainingmorethan20%nitrocellulose)packedinreceptaclesoflessthan450litrescapacity,arenotsubjecttothisDirectiveif,inthesolvent-separationtest(seeManualoftestsandcriteria,PartIII,subsection32.5.1),theheightoftheseparatedlayerofsolventislessthan3%ofthetotalheight,andifthesubstancesat23°Chave,intheflowcupconformingtoISO2431:1993havingajet6mmindiameter,aflowtimeof:(a)notlessthan60seconds,or(b)notlessthan40secondsandcontainnotmorethan60%ofsubstancesofClass3.2.2.3.1.6.IfsubstancesofClass3,asaresultofadmixtures,comeintocategoriesofriskdifferentfromthosetowhichthesubstancesmentionedbynameinTableAofChapter3.2belong,thesemixturesorsolutionsshallbeassignedtotheentriestowhichtheybelongonthebasisoftheiractualdegreeofdanger.NOTEFortheclassificationofsolutionsandmixtures(suchaspreparationsandwastes)seealso2.1.3.2.2.3.1.7.OnthebasisofthetestproceduresinaccordancewithSection2.3.2,andthecriteriasetoutin2.2.3.1.1,itmayalsobedeterminedwhetherthenatureofasolutionoramixturementionedbynameorcontainingasubstancementionedbynameissuchthatthesolutionormixtureisnotsubjecttotheprovisionsforthisClass(seealso2.1.3).2.2.3.2.Substancesnotacceptedforcarriage2.2.3.2.1.SubstancesofClass3whichareliabletoformperoxideseasily(ashappenswithethersorwithcertainheterocyclicoxygenatedsubstances)shallnotbeacceptedforcarriageiftheirperoxidecontent,calculatedashydrogenperoxide(H2O2),exceeds0,3%.Theperoxidecontentshallbedeterminedasindicatedin2.3.3.2.2.2.3.2.2.ThechemicallyunstablesubstancesofClass3shallnotbeacceptedforcarriageunlessthenecessarystepshavebeentakentopreventtheirdangerousdecompositionorpolymerisationduringcarriage.Tothisend,itshallbeensuredinparticularthatreceptaclesandtanksdonotcontainanysubstanceliabletopromotethesereactions.2.2.3.2.3.LiquiddesensitisedexplosivesotherthanthoselistedinTableAofChapter3.2shallnotbeacceptedforcarriageassubstancesofClass3.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/622.2.3.3.ListofcollectiveentriesOfficialJournaloftheEuropeanUnionEN26.1.2004L18/632.2.41.Class4.1Flammablesolids,self-reactivesubstanceandsoliddesensitisedexplosives2.2.41.1.Criteria2.2.41.1.1.TheheadingofClass4.1coversflammablesubstancesandarticles,desensitisedexplosiveswhicharesolidsaccordingtosubparagraph(a)ofthedefinition‘solid’in1.2.1andself-reactiveliquidsorsolids.ThefollowingareassignedtoClass4.1:—readilyflammablesolidsubstancesandarticles(seeparagraphs2.2.41.1.3to2.2.41.1.8),—self-reactivesolidsorliquids(seeparagraphs2.2.41.1.9to2.2.41.1.17),—soliddesensitisedexplosives(see2.2.41.1.18),—substancesrelatedtoself-reactivesubstances(see2.2.41.1.19).2.2.41.1.2.ThesubstancesandarticlesofClass4.1aresubdividedasfollows:Fflammablesolids,withoutsubsidiaryrisk:F1organic;F2organic,molten;F3inorganic;FOflammablesolids,oxidising;FTflammablesolids,toxic:FT1organic,toxic;FT2inorganic,toxic;FCflammablesolids,corrosive:FC1organic,corrosive;FC2inorganic,corrosive;Dsoliddesensitisedexplosiveswithoutsubsidiaryrisk;DTsoliddesensitisedexplosives,toxic;SRself-reactivesubstances:SR1notrequiringtemperaturecontrol;SR2requiringtemperaturecontrol.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/64FlammablesolidsDefinitionandproperties2.2.41.1.3.Flammablesolidsarereadilycombustiblesolidsandsolidswhichmaycausefirethroughfriction.Readilycombustiblesolidsarepowdered,granular,orpastysubstanceswhicharedangerousiftheycanbeeasilyignitedbybriefcontactwithanignitionsource,suchasaburningmatch,andiftheflamespreadsrapidly.Thedangermaycomenotonlyfromthefirebutalsofromtoxiccombustionproducts.Metalpowdersareespeciallydangerousbecauseofthedifficultyofextinguishingafiresincenormalextinguishingagentssuchascarbondioxideorwatercanincreasethehazard.Classification2.2.41.1.4.SubstancesandarticlesclassifiedasflammablesolidsofClass4.1arelistedinTableAofChapter3.2.TheassignmentoforganicsubstancesandarticlesnotmentionedbynameinTableAofChapter3.2totherelevantentryofsubsection2.2.41.3inaccordancewiththeprovisionsofChapter2.1canbebasedonexperienceorontheresultsofthetestproceduresinaccordancewithPartIII,subsection33.2.1oftheManualoftestsandcriteria.TheassignmentofinorganicsubstancesnotmentionedbynameshallbebasedontheresultsofthetestproceduresinaccordancewithPartIII,subsection33.2.1oftheManualoftestsandcriteria;experienceshallalsobetakenintoaccountwhenitleadstoamorestringentassignment.2.2.41.1.5.Whensubstancesnotmentionedbynameareassignedtooneoftheentrieslistedin2.2.41.3onthebasisofthetestproceduresinaccordancewiththeManualoftestsandcriteria,PartIII,subsection33.2.1,thefollowingcriteriaapply.(a)Withtheexceptionofmetalpowdersorpowdersofmetalalloys,powdery,granularorpastysubstancesshallbeclassifiedasreadilyflammablesubstancesofClass4.1iftheycanbeeasilyignitedbybriefcontactwithanignitionsource(e.g.aburningmatch),orif,intheeventofignition,theflamespreadsrapidly,theburningtimeislessthan45secondsforameasureddistanceof100mmortherateofburningisgreaterthan2,2mm/s.(b)MetalpowdersorpowdersofmetalalloysshallbeassignedtoClass4.1iftheycanbeignitedbyaflameandthereactionspreadsoverthewholelengthofthesamplein10minutesorless.SolidswhichmaycausefirethroughfrictionshallbeclassifiedinClass4.1byanalogywithexistingentries(e.g.matches)orinaccordancewithanyappropriatespecialprovision.2.2.41.1.6.OnthebasisofthetestprocedureinaccordancewiththeManualoftestsandcriteria,PartIII,Section33.2.1andthecriteriasetoutin2.2.41.1.4and2.2.41.1.5,itmayalsobedeterminedwhetherthenatureofasubstancementionedbynameissuchthatthesubstanceisnotsubjecttotheprovisionsforthisclass.2.2.41.1.7.IfsubstancesofClass4.1,asaresultofadmixtures,comeintodifferentcategoriesofriskfromthosetowhichthesubstancesmentionedbynameinTableAofChapter3.2belong,thesemixturesshallbeassignedtotheentriestowhichtheybelongonthebasisoftheiractualdegreeofdanger.NOTEFortheclassificationofsolutionsandmixtures(suchaspreparationsandwastes),seealso2.1.3.Assignmentofpackinggroups2.2.41.1.8.FlammablesolidsclassifiedunderthevariousentriesinTableAofChapter3.2shallbeassignedtopackinggroupsIIorIIIonthebasisoftestproceduresoftheManualoftestsandcriteria,PartIII,subsection33.2.1,inaccordancewiththefollowingcriteria.(a)Readilyflammablesolidswhich,whentested,haveaburningtimeoflessthan45secondsoverameasureddistanceof100mmshallbeassignedto:packinggroupII:iftheflamepassesthewettedzone;OfficialJournaloftheEuropeanUnionEN26.1.2004L18/65packinggroupIII:ifthewettedzonestopstheflameforatleastfourminutes;(b)Metalpowdersorpowdersofmetalalloysshallbeassignedto:packinggroupII:if,whentested,thereactionspreadsoverthewholelengthofthesampleinfiveminutesorless;packinggroupIII:if,whentested,thereactionspreadsoverthewholelengthofthesampleinmorethanfiveminutes.Forsolidswhichmaycausefirethroughfriction,thepackinggroupshallbeassignedbyanalogywithexistingentriesorinaccordancewithanyspecialprovision.Self-reactivesubstancesDefinitions2.2.41.1.9.ForthepurposesofthisDirective,self-reactivesubstancesarethermallyunstablesubstancesliabletoundergoastronglyexothermicdecompositionevenwithoutparticipationofoxygen(air).Substancesarenotconsideredtobeself-reactivesubstancesofClass4.1,if:(a)theyareexplosivesaccordingtothecriteriaofClass1;(b)theyareoxidisingsubstancesaccordingtotheassignmentprocedureofClass5.1(see2.2.51.1);(c)theyareorganicperoxidesaccordingtothecriteriaofClass5.2(see2.2.52.1);(d)theirheatofdecompositionislessthan300J/g;or(e)theirself-acceleratingdecompositiontemperature(SADT)(seeNote2)isgreaterthan75°Cfora50kgpackage.NOTE1.Theheatofdecompositioncanbedeterminedusinganyinternationallyrecognisedmethode.g.differentialscanningcalorimetryandadiabaticcalorimetry.2.Theself-acceleratingdecompositiontemperature(SADT)isthelowesttemperatureatwhichself-acceleratingdecompositionmayoccurwithasubstanceinthepackagingasusedduringcarriage.RequirementsforthedeterminationoftheSADTaregivenintheManualoftestsandcriteria,PartII,Chapter20andSection28.4.3.Anysubstancewhichshowsthepropertiesofaself-reactivesubstanceshallbeclassifiedassuch,evenifthissubstancegivesapositivetestresultaccordingto2.2.42.1.5forinclusioninClass4.2.Properties2.2.41.1.10.Thedecompositionofself-reactivesubstancescanbeinitiatedbyheat,contactwithcatalyticimpurities(e.g.acids,heavy-metalcompounds,bases),frictionorimpact.Therateofdecompositionincreaseswithtemperatureandvarieswiththesubstance.Decomposition,particularlyifnoignitionoccurs,mayresultintheevolutionoftoxicgasesorvapours.Forcertainself-reactivesubstances,thetemperatureshallbecontrolled.Someself-reactivesubstancesmaydecomposeexplosively,particularlyifconfined.Thischaracteristicmaybemodifiedbytheadditionofdiluentsorbytheuseofappropriatepackagings.Certainself-reactivesubstancesburnvigorously.Self-reactivesubstancesare,forexample,somecompoundsofthetypeslistedbelow:—aliphaticazocompounds(-C-N=N-C-)—organicazides(-C-N3)OfficialJournaloftheEuropeanUnionEN26.1.2004L18/66—diazoniumsalts(-CN2+Z-)—N-nitrosocompounds(-N-N=O)and—aromaticsulphohydrazides(-SO2-NH-NH2).Thislistisnotexhaustiveandsubstanceswithotherreactivegroupsandsomemixturesofsubstancesmayhavesimilarproperties.Classification2.2.41.1.11.Self-reactivesubstancesareclassifiedintoseventypesaccordingtothedegreeofdangertheypresent.Thetypesofself-reactivesubstancesrangefromtypeA,whichisnotacceptedforcarriageinthepackaginginwhichitistested,totypeG,whichisnotsubjecttotheprovisionsforself-reactivesubstancesofClass4.1.TheclassificationoftypesBtoFisdirectlyrelatedtothemaximumquantityallowedinonepackaging.Theprinciplestobeappliedforclassificationaswellastheapplicableclassificationprocedures,testmethodsandcriteriaandanexampleofasuitabletestreportaregiveninPartIIoftheManualoftestsandcriteria.2.2.41.1.12.Substanceswhichhavealreadybeenclassifiedandassignedtotheappropriatecollectiveentryarelistedin2.2.41.4togetherwiththeapplicableUNnumber,packingmethodand,whereappropriate,controlandemergencytemperatures.Thecollectiveentriesspecify:—self-reactivesubstancestypesBtoF,see2.2.41.1.11,—physicalstate(liquid/solid),and—temperaturecontrol(whenrequired),see2.2.41.1.17.Theclassificationoftheself-reactivesubstanceslistedin2.2.41.4isbasedonthetechnicallypuresubstance(exceptwhereaconcentrationoflessthan100%isspecified).2.2.41.1.13.Classificationofself-reactivesubstancesorformulationsofself-reactivesubstancesnotlistedin2.2.41.4andassignmenttoacollectiveentryshallbemadebythecompetentauthorityofthecountryoforiginonthebasisofatestreport.Thestatementofapprovalshallcontaintheclassificationandtherelevantconditionsofcarriage.IfthecountryoforiginisnotaMemberState,theclassificationandtheconditionsofcarriageshallberecognisedbythecompetentauthorityofthefirstcountryMemberStatereachedbytheconsignment.2.2.41.1.14.Activators,suchaszinccompounds,maybeaddedtosomeself-reactivesubstancestochangetheirreactivity.Dependingonboththetypeandtheconcentrationoftheactivator,thismayresultinadecreaseinthermalstabilityandachangeinexplosiveproperties.Ifeitherofthesepropertiesisaltered,thenewformulationshallbeassessedinaccordancewiththeclassificationprocedure.2.2.41.1.15.Samplesofself-reactivesubstancesorformulationsofself-reactivesubstancesnotlistedin2.2.41.4,forwhichacompletesetoftestresultsisnotavailableandwhicharetobecarriedforfurthertestingorevaluation,shallbeassignedtooneoftheappropriateentriesforself-reactivesubstancestypeCprovidedthefollowingconditionsaremet:—theavailabledataindicatesthatthesamplewouldbenomoredangerousthanself-reactivesubstancestypeB,—thesampleispackagedinaccordancewithpackingmethodOP2andthequantitypertransportunitislimitedto10kg,—theavailabledataindicatethatthecontroltemperature,ifany,issufficientlylowtopreventanydangerousdecompositionandsufficientlyhightopreventanydangerousphaseseparation.Desensitisation2.2.41.1.16.Inordertoensuresafetyduringcarriage,self-reactivesubstancesareinmanycasesdesensitisedbyuseofadiluent.Whereapercentageofasubstanceisstipulated,thisreferstothepercentagebymass,roundedtothenearestwholenumber.Ifadiluentisused,theself-reactivesubstanceshallbetestedwiththediluentpresentintheconcentrationandformusedincarriage.Diluentswhichmayallowaself-reactivesubstancetoconcentratetoadangerousextentintheeventofleakagefromapackagingshallnotbeused.Anydiluentshallbecompatiblewiththeself-reactivesubstance.Inthisregard,compatiblediluentsarethosesolidsorliquidswhichhavenodetrimentalinfluenceonthethermalstabilityandhazardtypeoftheself-reactivesubstance.Liquiddiluentsinformulationsrequiringtemperaturecontrol(see2.2.41.1.14)shallhaveaboilingpointofatleast60°Candaflash-pointnotlessthan5°C.Theboilingpointoftheliquidshallbeatleast50°Chigherthanthecontroltemperatureoftheself-reactivesubstance.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/67Temperaturecontrolrequirements2.2.41.1.17.Certainself-reactivesubstancesmayonlybecarriedundertemperaturecontrolledconditions.Thecontroltemperatureisthemaximumtemperatureatwhichtheself-reactivesubstancecanbesafelycarried.Itisassumedthatthetemperatureoftheimmediatesurroundingsofapackageonlyexceeds55°Cduringcarriageforarelativelyshorttimeina24hourperiod.Intheeventoflossoftemperaturecontrol,itmaybenecessarytoimplementemergencyprocedures.Theemergencytemperatureisthetemperatureatwhichsuchproceduresshallbeimplemented.ThecontrolandemergencytemperaturesarederivedfromtheSADT(seetable1).TheSADTshallbedeterminedinordertodecidewhetherasubstanceshallbesubjectedtotemperaturecontrolduringcarriage.ProvisionsforthedeterminationoftheSADTaregivenintheManualoftestsandcriteria,PartII,Chapter20andSection28.4.Table1DERIVATIONOFCONTROLANDEMERGENCYTEMPERATURESTypeofreceptacleSADT(a)ControltemperatureEmergencytemperatureSinglepackagingsandIBCs≤20°C20°CbelowSADT10°CbelowSADT>20°C≤35°C15°CbelowSADT10°CbelowSADT>35°C10°CbelowSADT5°CbelowSADTTanks<50°C10°CbelowSADT5°CbelowSADT(a)SADTofthesubstanceaspackagedforcarriage.Self-reactivesubstanceswithanSADTnotgreaterthan55°Cshallbesubjecttotemperaturecontrolduringcarriage.Whereapplicable,controlandemergencytemperaturesarelistedin2.2.41.4.Theactualtemperatureduringcarriagemaybelowerthanthecontroltemperaturebutshallbeselectedsoastoavoiddangerousseparationofphases.Soliddesensitisedexplosives2.2.41.1.18.Soliddesensitisedexplosivesaresubstanceswhicharewettedwithwateroralcoholsoraredilutedwithothersubstancestosuppresstheirexplosiveproperties.SuchentriesinTableAofChapter3.2are:UNNos1310,1320,1321,1322,1336,1337,1344,1347,1348,1349,1354,1355,1356,1357,1517,1571,2555,2556,2557,2852,2907,3270,3317and3319;and,ifspecialprovision15ofChapter3.3iscompliedwith:UNNos0154,0155,0209,0214,0215,0234;and,ifspecialprovision18ofChapter3.3.iscompliedwith:UNNo0220.Substancesrelatedtoself-reactivesubstances2.2.41.1.19.Substancesthat:(a)havebeenprovisionallyacceptedintoClass1accordingtotestseries1and2butexemptedfromClass1bytestseries6;(b)arenotself-reactivesubstancesofClass4.1;and(c)arenotsubstancesofClass5.1or5.2arealsoassignedtoClass4.1.UNNos2956,3241,3242and3251aresuchentries.2.2.41.2.Substancesnotacceptedforcarriage2.2.41.2.1.ThechemicallyunstablesubstancesofClass4.1shallnotbeacceptedforcarriageunlessthenecessarystepshavebeentakentopreventtheirdangerousdecompositionorpolymerisationduringcarriage.Tothisend,itshallinparticularbeensuredthatreceptaclesandtanksdonotcontainanysubstanceliabletopromotethesereactions.2.2.41.2.2.Flammablesolids,oxidising,assignedtoUNNo3097shallnotbeacceptedforcarriageunlesstheymeettherequirementsforClass1(seealso2.1.3.7).2.2.41.2.3.Thefollowingsubstancesshallnotbeacceptedforcarriage:—self-reactivesubstancesoftypeA(seeManualoftestsandcriteria,PartII,paragraph20.4.2(a)),—phosphorussulphideswhicharenotfreefromyellowandwhitephosphorus,—soliddensitisedexplosivesotherthanthoselistedinTableAofChapter3.2,—inorganicflammablesubstancesinthemoltenformotherthanUNNo2448SULPHUR,MOLTEN,—bariumazidewithawatercontentlessthan50%(mass).OfficialJournaloftheEuropeanUnionEN26.1.2004L18/682.2.41.3.ListofcollectiveentriesOfficialJournaloftheEuropeanUnionEN26.1.2004L18/692.2.41.4.Listofself-reactivesubstances(cont'd)SELF-REACTIVESUBSTANCEConcentration(%)PackingmethodControltemperature(°C)Emergencytemperature(°C)UNgenericentryRemarksAZODICARBONAMIDEFORMULATIONTYPEB,TEMPERATURECONTROLLED<100OP53232(1)(2)AZODICARBONAMIDEFORMULATIONTYPEC<100OP63224(3)AZODICARBONAMIDEFORMULATIONTYPEC,TEMPERATURECONTROLLED<100OP63234(4)AZODICARBONAMIDEFORMULATIONTYPED<100OP73226(5)AZODICARBONAMIDEFORMULATIONTYPED,TEMPERATURECONTROLLED<100OP73236(6)2,2′-AZODI(2,4-DIMETHYL-4-METHOXY-VALERONITRILE)100OP7-5+532362,2′-AZODI(2,4-DIMETHYL-VALERONI-TRILE)100OP7+10+1532362,2′-AZODI(ETHYL-2-METHYLPROPIO-NATE)100OP7+20+2532351,1-AZODI(HEXAHYDROBENZONITRILE)100OP732262,2′-AZODI(ISOBUTYRONITRILE100OP6+40+4532342,2′-AZODI(ISOBUTYRONITRILE),asawaterbasedpaste≤50OP632242,2′-AZODI(2-METHYLBUTYRO-NITRILE)100OP7+35+403236BENZENE-1,3-DISULPHOHYDRAZIDE,asapaste52OP73226BENZENESULPHOHYDRAZIDE100OP732264-(BENZYL(ETHYL)AMINO)-3-ETHOXY-BENZENEDIAZONIUMZINCCHLORIDE100OP732264-(BENZYL(METHYL)AMINO)-3-ETHOXY-BENZENEDIAZONIUMZINCCHLORIDE100OP7+40+4532363-CHLORO-4-DIETHYLAMINOBENZENE-DIAZONIUMZINCCHLORIDE100OP732262-DIAZO-1-NAPHTHOL-4-SULPHOCHLORIDE100OP53222(2)2-DIAZO-1-NAPHTHOL-5-SULPHOCHLORIDE1000P53222(2)OfficialJournaloftheEuropeanUnionEN26.1.2004L18/70SELF-REACTIVESUBSTANCEConcentration(%)PackingmethodControltemperature(°C)Emergencytemperature(°C)UNgenericentryRemarks2,5-DIETHOXY-4-MORPHOLINO-BENZE-NEDIAZONIUMZINCCHLORIDE67-100OP7+35+4032362,5-DIETHOXY-4-MORPHOLINO-BENZE-NEDIAZONIUMZINCCHLORIDE66OP7+40+4532362,5-DIETHOXY-4-MORPHOLINO-BENZE-NEDIAZONIUMTETRAFLUOROBORATE100OP7+30+3532362,5-DIETHOXY-4-(PHENYLSULPHONYL)-BENZENEDIAZONIUMZINCCHLORIDE67OP7+40+453236DIETHYLENEGLYCOLBIS(ALLYLCARBO-NATE)+DI-ISOPROPYLPEROXYDICAR-BONATE≥88+≤12OP8-10032372,5-DIMETHOXY-4-(4-METHYL-PHENYL-SULPHONYL)BENZENE-DIAZONIUMZINCCHLORIDE79OP7+40+4532364-DIMETHYLAMINO-6-(2-DIMETHYL-AMINOETHOXY)TOLUENE-2-DIAZO-NIUMZINCCHLORIDE100OP7+40+453236N,N′-DINITROSO-N,N′-DIMETHYLTEREPHTHALAMIDE,asapaste72OP63224N,N′-DINITROSOPENTAMETHYLENE-TETRAMINE82OP63224(7)DIPHENYLOXIDE-4,4′-DI-SULPHOHYDRA-ZIDE100OP732264-DIPROPYLAMINOBENZENE-DIAZO-NIUMZINCCHLORIDE100OP732262-(N,N-ETHOXYCARBONYL-PHENYLA-MINO)-3-METHOXY-4-(N-METHYL-N-CYCLOHEXYLAMINO)BENZENEDIAZO-NIUMZINCCHLORIDE63-92OP7+40+4532362-(N,N-ETHOXYCARBONYL-PHENYLA-MINO)-3-METHOXY-4-(N-METHYL-N-CYCLOHEXYLAMINO)BENZENEDIAZO-NIUMZINCCHLORIDE62OP7+35+403236N-FORMYL-2-(NITROMETHYLENE)-1,3-PERHYDROTHIAZINE100OP7+45+5032362-(2-HYDROXYETHOXY)-1-(PYRROLIDIN-1-YL)BENZENE-4-DIAZONIUMZINCCHLORIDE100OP7+45+5032363-(2-HYDROXYETHOXY)-4-(PYRROLIDIN-1-YL)BENZENEDIAZONIUMZINCCHLORIDE100OP7+40+4532362-(N,N-METHYLAMINOETHYL-CARBONYL)-4-(3,4-DIMETHYL-PHENYL-SULPHONYL)BENZENE-DIAZONIUMHYDROGENSULPHATE96OP7+45+503236OfficialJournaloftheEuropeanUnionEN26.1.2004L18/71SELF-REACTIVESUBSTANCEConcentration(%)PackingmethodControltemperature(°C)Emergencytemperature(°C)UNgenericentryRemarks4-METHYLBENZENESULPHONYL-HYDRA-ZIDE100OP732263-METHYL-4-(PYRROLIDIN-1-YL)BENZE-NEDIAZONIUMTETRAFLUOROBORATE95OP6+45+5032344-NITROSOPHENOL100OP7+35+403236SELF-REACTIVELIQUID,SAMPLEOP23223(8)SELF-REACTIVELIQUID,SAMPLE,TEMPERATURECONTROLLEDOP23233(8)SELF-REACTIVESOLID,SAMPLEOP23224(8)SELF-REACTIVESOLID,SAMPLE,TEMPERATURECONTROLLEDOP23234(8)SODIUM2-DIAZO-1-NAPHTHOL-4-SULPHONATE100OP73226SODIUM2-DIAZO-1-NAPHTHOL-5-SULPHONATE100OP73226TETRAMINEPALLADIUM(II)NITRATE100OP6+30+353234(1)Azodicarbonamideformulationswhichfulfilthecriteriaofparagraph20.4.2(b)oftheManualoftestsandcriteria.Thecontrolandemergencytemperaturesshallbedeterminedbytheproceduregivenin2.2.41.1.17.(2)‘EXPLOSIVE’subsidiaryrisklabelrequired(ModelNo1,see5.2.2.2.2).(3)Azodicarbonamideformulationswhichfulfilthecriteriaofparagraph20.4.2(c)oftheManualoftestsandcriteria.(4)Azodicarbonamideformulationswhichfulfilthecriteriaofparagraph20.4.2(c)oftheManualoftestsandcriteria.Thecontrolandemergencytemperaturesshallbedeterminedbytheproceduregivenin2.2.41.1.17.(5)Azodicarbonamideformulationswhichfulfilthecriteriaofparagraph20.4.2(d)oftheManualoftestsandcriteria.(6)Azodicarbonamideformulationswhichfulfilthecriteriaofparagraph20.4.2(d)oftheManualoftestsandcriteria.Thecontrolandemergencytemperaturesshallbedeterminedbytheproceduregivenin2.2.41.1.17.(7)Withacompatiblediluenthavingaboilingpointofnotlessthan150°C.(8)See2.2.41.1.16.2.2.42.Class4.2Substancesliabletospontaneouscombustion2.2.42.1.Criteria2.2.42.1.1.TheheadingofClass4.2covers:—pyrophoricsubstanceswhicharesubstances,includingmixturesandsolutions(liquidorsolid),whicheveninsmallquantitiesigniteoncontactwithairwithinfiveminutes.ThesearetheClass4.2substancesthemostliabletospontaneouscombustion,and—self-heatingsubstancesandarticleswhicharesubstancesandarticles,includingmixturesandsolutions,which,oncontactwithair,withoutenergysupply,areliabletoself-heating.Thesesubstanceswilligniteonlyinlargeamounts(kilograms)andafterlongperiodsoftime(hoursordays).OfficialJournaloftheEuropeanUnionEN26.1.2004L18/722.2.42.1.2.ThesubstancesandarticlesofClass4.2aresubdividedasfollows:Ssubstancesliabletospontaneouscombustion,withoutsubsidiaryrisk:S1organic,liquid;S2organic,solid;S3inorganic,liquid;S4inorganic,solid;SWsubstancesliabletospontaneouscombustion,which,incontactwithwater,emitflammablegases;SOsubstancesliabletospontaneouscombustion,oxidising;STsubstancesliabletospontaneouscombustion,toxic:ST1organic,toxic,liquid;ST2organic,toxic,solid;ST3inorganic,toxic,liquid;ST4inorganic,toxic,solid;SCsubstancesliabletospontaneouscombustion,corrosive:SC1organic,corrosive,liquid;SC2organic,corrosive,solid;SC3inorganic,corrosive,liquid;SC4inorganic,corrosive,solid.Properties2.2.42.1.3.Self-heatingofthesesubstances,leadingtospontaneouscombustion,iscausedbyreactionofthesubstancewithoxygen(intheair)andtheheatdevelopednotbeingconductedawayrapidlyenoughtothesurroundings.Spontaneouscombustionoccurswhentherateofheatproductionexceedstherateofheatlossandtheauto-ignitiontemperatureisreached.Classification2.2.42.1.4.SubstancesandarticlesclassifiedinClass4.2arelistedinTableAofChapter3.2.TheassignmentofsubstancesandarticlesnotmentionedbynameinTableAofChapter3.2totherelevantspecificN.O.Sentryof2.2.42.3inaccordancewiththeprovisionsofChapter2.1canbebasedonexperienceortheresultsofthetestproceduresinaccordancewiththeManualoftestsandcriteria,PartIII,Section33.3.AssignmenttogeneralN.O.SentriesofClass4.2shallbebasedontheresultsofthetestproceduresinaccordancewiththeManualoftestsandcriteria,PartIII,Section33.3;experienceshallalsobetakenintoaccountwhenitleadstoamorestringentassignment.2.2.42.1.5.Whensubstancesorarticlesnotmentionedbynameareassignedtooneoftheentrieslistedin2.2.42.3onthebasisofthetestproceduresinaccordancewiththeManualoftestsandcriteria,PartIII,Section33.3,thefollowingcriteriashallapply:(a)solidsliabletospontaneouscombustion(pyrophoric)shallbeassignedtoClass4.2whentheyigniteonfallingfromaheightof1morwithinfiveminutes;OfficialJournaloftheEuropeanUnionEN26.1.2004L18/73(b)liquidsliabletospontaneouscombustion(pyrophoric)shallbeassignedtoClass4.2when:(i)onbeingpouredonaninertcarrier,theyignitewithinfiveminutes,or(ii)intheeventofanegativeresultofthetestaccordingto(i),whenpouredonadry,indentedfilterpaper(WhatmanNo3filter),theyigniteorcarboniseitwithinfiveminutes;(c)substancesinwhich,ina10cmsamplecube,at140°Ctesttemperature,spontaneouscombustionorariseintemperaturetoover200°Cisobservedwithin24hoursshallbeassignedtoClass4.2.Thiscriterionisbasedonthetemperatureofthespontaneouscombustionofcharcoal,whichisat50°Cforasamplecubeof27m3.Substanceswithatemperatureofspontaneouscombustionhigherthan50°Cforavolumeof27m3arenottobeassignedtoClass4.2.NOTE1.Substancescarriedinpackageswithavolumeofnotmorethan3m3areexemptedfromClass4.2if,testedwitha10cmsamplecubeat120°C,nospontaneouscombustionnorariseintemperaturetoover180°Cisobservedwithin24hours.2.Substancescarriedinpackageswithavolumeofnotmorethan450litresareexemptedfromClass4.2if,testedwitha10cmsamplecubeat100°C,nospontaneouscombustionnorariseintemperaturetoover160°Cisobservedwithin24hours.2.2.42.1.6.IfsubstancesofClass4.2,asaresultofadmixtures,comeintodifferentcategoriesofriskfromthosetowhichthesubstancesmentionedbynameinTableAofChapter3.2belong,thesemixturesshallbeassignedtotheentriestowhichtheybelongonthebasisoftheiractualdegreeofdanger.NOTEFortheclassificationofsolutionsandmixtures(suchaspreparationsandwastes),seealso2.1.3.2.2.42.1.7.OnthebasisofthetestprocedureintheManualoftestsandcriteria,PartIII,section33.3andthecriteriasetoutin2.2.42.1.5,itmayalsobedeterminedwhetherthenatureofasubstancementionedbynameissuchthatthesubstanceisnotsubjecttotheprovisionsforthisClass.Assignmentofpackinggroups2.2.42.1.8.SubstancesandarticlesclassifiedunderthevariousentriesinTableAofChapter3.2shallbeassignedtopackinggroupsI,IIorIIIonthebasisoftestproceduresoftheManualoftestsandcriteria,PartIII,Section33.3,inaccordancewiththefollowingcriteria:(a)substancesliabletospontaneouscombustion(pyrophoric)shallbeassignedtopackinggroupI;(b)self-heatingsubstancesandarticlesinwhich,ina2,5cmsamplecube,at140°Ctesttemperature,spontaneouscombustionorariseintemperaturetoover200°Cisobservedwithin24hours,shallbeassignedtopackinggroupII.Substanceswithatemperatureofspontaneouscombustionhigherthan50°Cforavolumeof450litresarenottobeassignedtopackinggroupII;(c)slightlyself-heatingsubstancesinwhich,ina2,5cmsamplecube,thephenomenareferredtounder(b)arenotobserved,inthegivenconditions,butinwhichina10cmsamplecubeat140°Ctesttemperaturespontaneouscombustionorariseintemperaturetoover200°Cisobservedwithin24hours,shallbeassignedtopackinggroupIII.2.2.42.2.SubstancesnotacceptedforcarriageThefollowingsubstancesshallnotbeacceptedforcarriage:—UNNo3255tert-BUTYLHYPOCHLORITE,and—self-heatingsolids,oxidising,assignedtoUNNo3127unlesstheymeettherequirementsforClass1(see2.1.3.7).OfficialJournaloftheEuropeanUnionEN26.1.2004L18/742.2.42.3.ListofcollectiveentriesOfficialJournaloftheEuropeanUnionEN26.1.2004L18/752.2.43.Class4.3Substanceswhich,incontactwithwater,emitflammablegases2.2.43.1.Criteria2.2.43.1.1.TheheadingofClass4.3coverssubstanceswhichreactwithwatertoemitflammablegasesliabletoformexplosivemixtureswithair,andarticlescontainingsuchsubstances.2.2.43.1.2.SubstancesandarticlesofClass4.3aresubdividedasfollows:Wsubstanceswhich,incontactwithwater,emitflammablegases,withoutsubsidiaryrisk,andarticlescontainingsuchsubstances:W1liquid;W2solid;W3articles;WF1substanceswhich,incontactwithwater,emitflammablegases,liquid,flammable;WF2substanceswhich,incontactwithwater,emitflammablegases,solid,flammable;WSsubstanceswhich,incontactwithwater,emitflammablegases,solid,self-heating;WOsubstanceswhich,incontactwithwater,emitflammablegases,oxidising,solid;WTsubstanceswhich,incontactwithwater,emitflammablegases,toxic:WT1liquid;WT2solid;WCsubstanceswhich,incontactwithwater,emitflammablegases,corrosive:WC1liquid;WC2solid;WFCsubstanceswhich,incontactwithwater,emitflammablegases,flammable,corrosive.Properties2.2.43.1.3.Certainsubstancesincontactwithwatermayemitflammablegasesthatcanformexplosivemixtureswithair.Suchmixturesareeasilyignitedbyallordinarysourcesofignition,forexamplenakedlights,sparkinghandtoolsorunprotectedlightbulbs.Theresultingblastwaveandflamesmayendangerpeopleandtheenvironment.Thetestmethodreferredtoin2.2.43.1.4isusedtodeterminewhetherthereactionofasubstancewithwaterleadstothedevelopmentofadangerousamountofgaseswhichmaybeflammable.Thistestmethodshallnotbeappliedtopyrophoricsubstances.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/76Classification2.2.43.1.4.SubstancesandarticlesclassifiedinClass4.3arelistedinTableAofChapter3.2.TheassignmentofsubstancesandarticlesnotmentionedbynameinTableAofChapter3.2totherelevantentryof2.2.43.3inaccordancewiththeprovisionsofChapter2.1shallbebasedontheresultsofthetestprocedureinaccordancewiththeManualoftestsandcriteria,PartIII,Section33.4;experienceshallalsobetakenintoaccountwhenitleadstoamorestringentassignment.2.2.43.1.5.Whensubstancesnotmentionedbynameareassignedtooneoftheentrieslistedin2.2.43.3onthebasisofthetestprocedureinaccordancewiththeManualoftestsandcriteria,PartIII,Section33.4,thefollowingcriteriashallapply.AsubstanceshallbeassignedtoClass4.3if:(a)spontaneousignitionofthegasemittedtakesplaceinanystepofthetestprocedure;or(b)thereisanevolutionofflammablegasatarategreaterthan1litreperkilogramofthesubstancetobetestedperhour.2.2.43.1.6.IfsubstancesofClass4.3,asaresultofadmixtures,comeintodifferentcategoriesofriskfromthosetowhichthesubstancesmentionedbynameinTableAofChapter3.2belong,thesemixturesshallbeassignedtotheentriestowhichtheybelongonthebasisoftheiractualdegreeofdanger.NOTEFortheclassificationofsolutionsandmixtures(suchaspreparationsandwastes)seealso2.1.3.2.2.43.1.7.OnthebasisofthetestproceduresinaccordancewiththeManualoftestsandcriteria,PartIII,Section33.4,andthecriteriasetoutin2.2.43.1.5,itmayalsobedeterminedwhetherthenatureofasubstancementionedbynameissuchthatthesubstanceisnotsubjecttotheprovisionsforthisclass.Assignmentofpackinggroups2.2.43.1.8.SubstancesandarticlesclassifiedunderthevariousentriesinTableAofChapter3.2shallbeassignedtopackinggroupsI,IIorIIIonthebasisoftestproceduresoftheManualoftestsandcriteria,PartIII,Section33.4,inaccordancewiththefollowingcriteria.(a)packinggroupIshallbeassignedtoanysubstancewhichreactsvigorouslywithwateratambienttemperatureandgenerallydemonstratesatendencyforthegasproducedtoignitespontaneously,oronewhichreactsreadilywithwateratambienttemperaturessuchthattherateofevolutionofflammablegasisequaltoorgreaterthan10litresperkilogramofsubstanceoveranyoneminuteperiod.(b)packinggroupIIshallbeassignedtoanysubstancewhichreactsreadilywithwateratambienttemperaturesuchthatthemaximumrateofevolutionofflammablegasisequaltoorgreaterthan20litresperkilogramofsubstanceperhour,andwhichdoesnotmeetthecriteriaofpackinggroupI.(c)packinggroupIIIshallbeassignedtoanysubstancewhichreactsslowlywithwateratambienttemperaturesuchthatthemaximumrateofevolutionofflammablegasisgreaterthan1litreperkilogramofsubstanceperhour,andwhichdoesnotmeetthecriteriaofpackinggroupIorII.2.2.43.2.SubstancesnotacceptedforcarriageWater-reactivesolids,flammable,assignedtoUNNo3132,water-reactivesolids,oxidising,assignedtoUNNo3133andwater-reactivesolids,self-heating,assignedtoUNNo3135shallnotbeacceptedforcarriageunlesstheymeettherequirementsforClass1(seealso2.1.3.7).OfficialJournaloftheEuropeanUnionEN26.1.2004L18/772.2.43.3.ListofcollectiveentriesOfficialJournaloftheEuropeanUnionEN26.1.2004L18/782.2.51.Class5.1Oxidisingsubstances2.2.51.1.Criteria2.2.51.1.1.TheheadingofClass5.1coverssubstanceswhich,whileinthemselvesnotnecessarilycombustible,may,generallybyyieldingoxygen,causeorcontributetothecombustionofothermaterial,andarticlescontainingsuchsubstances.2.2.51.1.2.ThesubstancesofClass5.1andarticlescontainingsuchsubstancesaresubdividedasfollows:Ooxidisingsubstanceswithoutsubsidiaryriskorarticlescontainingsuchsubstances:O1liquid;O2solid;O3articles;OFoxidisingsubstances,solid,flammable;OSoxidisingsubstances,solid,self-heating;OWoxidisingsubstances,solidwhich,incontactwithwater,emitflammablegases;OToxidisingsubstances,toxic:OT1liquid;OT2solid;OCoxidisingsubstances,corrosive:OC1liquid;OC2solid;OTCoxidisingsubstances,toxic,corrosive.2.2.51.1.3.SubstancesandarticlesclassifiedinClass5.1arelistedinTableAofChapter3.2.TheassignmentofsubstancesandarticlesnotmentionedbynameinTableAofChapter3.2totherelevantentryof2.2.51.3inaccordancewiththeprovisionsofChapter2.1canbebasedonthetests,methodsandcriteriain2.2.51.1.6to2.2.51.1.9andtheManualoftestsandcriteria,PartIII,Section34.4.Intheeventofdivergencebetweentestresultsandknownexperience,judgmentbasedonknownexperienceshalltakeprecedenceovertestresults.2.2.51.1.4.IfsubstancesofClass5.1,asaresultofadmixtures,comeintodifferentcategoriesofriskfromthosetowhichthesubstancesmentionedbynameinTableAofChapter3.2belong,thesemixturesorsolutionsshallbeassignedtotheentriestowhichtheybelongonthebasisoftheiractualdegreeofdanger.NOTEFortheclassificationofsolutionsandmixtures(suchaspreparationsandwastes)seealsoSection2.1.3.2.2.51.1.5.OnthebasisofthetestproceduresintheManualoftestsandcriteria,PartIII,Section34.4andthecriteriasetoutin2.2.51.1.6to2.2.51.1.9itmayalsobedeterminedwhetherthenatureofasubstancementionedbynameinTableAofChapter3.2issuchthatthesubstanceisnotsubjecttotheprovisionsforthisclass.OxidisingsolidsClassification2.2.51.1.6.WhenoxidisingsolidsubstancesnotmentionedbynameinTableAofChapter3.2areassignedtooneoftheentrieslistedin2.2.51.3onthebasisofthetestprocedureinaccordancewiththeManualoftestsandcriteria,PartIII,subsection34.4.1,thefollowingcriteriashallapply.AsolidsubstanceshallbeassignedtoClass5.1if,inthe4:1orthe1:1sample-to-celluloseratio(bymass)tested,itignitesorburnsorexhibitsmeanburningtimesequaltoorlessthanthatofa3:7mixture(bymass)ofpotassiumbromateandcellulose.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/79Assignmentofpackinggroups2.2.51.1.7.OxidisingsolidsclassifiedunderthevariousentriesinTableAofChapter3.2shallbeassignedtopackinggroupI,IIorIIIonthebasisoftestproceduresoftheManualoftestsandcriteria,PartIII,subsection34.4.1,inaccordancewiththefollowingcriteria.(a)PackinggroupI:anysubstancewhich,inthe4:1or1:1sample-to-celluloseratio(bymass)tested,exhibitsameanburningtimelessthanthemeanburningtimeofa3:2mixture,bymass,ofpotassiumbromateandcellulose.(b)PackinggroupII:anysubstancewhich,inthe4:1or1:1sample-to-celluloseratio(bymass)tested,exhibitsameanburningtimeequaltoorlessthanthemeanburningtimeofa2:3mixture(bymass)ofpotassiumbromateandcelluloseandthecriteriaforpackinggroupIarenotmet.(c)PackinggroupIII:anysubstancewhich,inthe4:1or1:1sample-to-celluloseratio(bymass)tested,exhibitsameanburningtimeequaltoorlessthanthemeanburningtimeofa3:7mixture(bymass)ofpotassiumbromateandcelluloseandthecriteriaforpackinggroupsIandIIarenotmet.OxidisingliquidsClassification2.2.51.1.8.WhenoxidisingliquidsubstancesnotmentionedbynameinTableAofChapter3.2areassignedtooneoftheentrieslistedinsubsection2.2.51.3onthebasisofthetestprocedureinaccordancewiththeManualoftestsandcriteria,PartIII,subsection34.4.2,thefollowingcriteriashallapply.AliquidsubstanceshallbeassignedtoClass5.1if,inthe1:1mixture,bymass,ofsubstanceandcellulosetested,itexhibitsapressureriseof2070kPagaugeormoreandameanpressurerisetimeequaltoorlessthanthemeanpressurerisetimeofa1:1mixture,bymass,of65%aqueousnitricacidandcellulose.Assignmentofpackinggroups2.2.51.1.9.OxidisingliquidsclassifiedunderthevariousentriesinTableAofChapter3.2shallbeassignedtopackinggroupI,IIorIIIonthebasisoftestproceduresoftheManualoftestsandcriteria,PartIII,Section34.4.2,inaccordancewiththefollowingcriteria.(a)PackinggroupI:anysubstancewhich,inthe1:1mixture,bymass,ofsubstanceandcellulosetested,spontaneouslyignites;orthemeanpressurerisetimeofa1:1mixture,bymass,ofsubstanceandcelluloseislessthanthatofa1:1mixture,bymass,of50%perchloricacidandcellulose.(b)PackinggroupII:anysubstancewhich,inthe1:1mixture,bymass,ofsubstanceandcellulosetested,exhibitsameanpressurerisetimelessthanorequaltothemeanpressurerisetimeofa1:1mixture,bymass,of40%aqueoussodiumchloratesolutionandcellulose;andthecriteriaforpackinggroupIarenotmet.(c)PackinggroupIII:anysubstancewhich,inthe1:1mixture,bymass,ofsubstanceandcellulosetested,exhibitsameanpressurerisetimelessthanorequaltothemeanpressurerisetimeofa1:1mixture,bymass,of65%aqueousnitricacidandcellulose;andthecriteriaforpackinggroupsIandIIarenotmet.2.2.51.2.Substancesnotacceptedforcarriage2.2.51.2.1.ThechemicallyunstablesubstancesofClass5.1shallnotbeacceptedforcarriageunlessthenecessarystepshavebeentakentopreventtheirdangerousdecompositionorpolymerisationduringcarriage.Tothisenditshallinparticularbeensuredthatreceptaclesdonotcontainanymaterialliabletopromotethesereactions.2.2.51.2.2.Thefollowingsubstancesandmixturesshallnotbeacceptedforcarriage:—oxidisingsolids,self-heating,assignedtoUNNo3100,oxidisingsolids,water-reactive,assignedtoUNNo3121andoxidisingsolids,flammable,assignedtoUNNo3137,unlesstheymeettherequirementsforClass1(seealso2.1.3.7),—hydrogenperoxide,notstabilisedorhydrogenperoxide,aqueoussolutions,notstabilisedcontainingmorethan60%hydrogenperoxide,—tetranitromethanenotfreefromcombustibleimpurities,—perchloricacidsolutionscontainingmorethan72%(mass)acid,ormixturesofperchloricacidwithanyliquidotherthanwater,—chloricacidsolutioncontainingmorethan10%chloricacidormixturesofchloricacidwithanyliquidotherthanwater,—halogenatedfluorcompoundsotherthanUNNos1745BROMINEPENTAFLUORIDE;1746BROMINETRIFLUORIDEand2495IODINEPENTAFLUORIDEofClass5.1aswellasUNNos1749CHLORINETRIFLUORIDEand2548CHLORINEPENTAFLUORIDEofClass2,OfficialJournaloftheEuropeanUnionEN26.1.2004L18/80—ammoniumchlorateanditsaqueoussolutionsandmixturesofachloratewithanammoniumsalt,—ammoniumchloriteanditsaqueoussolutionsandmixturesofachloritewithanammoniumsalt,—mixturesofahypochloritewithanammoniumsalt,—ammoniumbromateanditsaqueoussolutionsandmixturesofabromatewithanammoniumsalt,—ammoniumpermanganateanditsaqueoussolutionsandmixturesofapermanganatewithanammoniumsalt,—ammoniumnitratecontainingmorethan0,2%combustiblesubstances(includinganyorganicsubstancecalculatedascarbon)unlessitisaconstituentofasubstanceorarticleofClass1,—fertilisershavinganammoniumnitratecontent(indeterminingtheammoniumnitratecontent,allnitrateionsforwhichamolecularequivalentofammoniumionsispresentinthemixtureshallbecalculatedasammoniumnitrate)oracontentincombustiblesubstancesexceedingthevaluesspecifiedforthevariousAMMONIUMNITRATEFERTILISERgradeslistedunderUNNos2067to2070exceptundertheconditionsapplicabletoClass1,—ammoniumnitratefertiliserswhichareassignedtothecollectiveentryUNNo2072AMMONIUMNITRATEFERTILISER,N.O.S,—ammoniumnitriteanditsaqueoussolutionsandmixturesofaninorganicnitritewithanammoniumsalt,—mixturesofpotassiumnitrate,sodiumnitriteandanammoniumsalt.2.2.51.3.ListofcollectiveentriesOfficialJournaloftheEuropeanUnionEN26.1.2004L18/812.2.52.Class5.2Organicperoxides2.2.52.1.Criteria2.2.52.1.1.TheheadingofClass5.2coversorganicperoxidesandformulationsoforganicperoxides.2.2.52.1.2.ThesubstancesofClass5.2aresubdividedasfollows:P1organicperoxides,notrequiringtemperaturecontrol;P2organicperoxides,requiringtemperaturecontrol.Definition2.2.52.1.3.Organicperoxidesareorganicsubstanceswhichcontainthebivalent-O-O-structureandmaybeconsideredderivativesofhydrogenperoxide,whereoneorbothofthehydrogenatomshavebeenreplacedbyorganicradicals.Properties2.2.52.1.4.Organicperoxidesareliabletoexothermicdecompositionatnormalorelevatedtemperatures.Thedecompositioncanbeinitiatedbyheat,contactwithimpurities(e.g.acids,heavy-metalcompounds,amines),frictionorimpact.Therateofdecompositionincreaseswithtemperatureandvarieswiththeorganicperoxideformulation.Decompositionmayresultintheevolutionofharmful,orflammable,gasesorvapours.Forcertainorganicperoxidesthetemperatureshallbecontrolledduringcarriage.Someorganicperoxidesmaydecomposeexplosively,particularlyifconfined.Thischaracteristicmaybemodifiedbytheadditionofdiluentsorbytheuseofappropriatepackagings.Manyorganicperoxidesburnvigorously.Contactoforganicperoxideswiththeeyesistobeavoided.Someorganicperoxideswillcauseseriousinjurytothecornea,evenafterbriefcontact,orwillbecorrosivetotheskin.NOTETestmethodsfordeterminingtheflammabilityoforganicperoxidesaresetoutintheManualoftestsandcriteria,PartIII,subsection32.4.Becauseorganicperoxidesmayreactvigorouslywhenheated,itisrecommendedtodeterminetheirflash-pointusingsmallsamplesizessuchasdescribedinISO3679:1983.Classification2.2.52.1.5.AnyorganicperoxideshallbeconsideredforclassificationinClass5.2unlesstheorganicperoxideformulationcontains:(a)notmorethan1,0%availableoxygenfromtheorganicperoxideswhencontainingnotmorethan1,0%hydrogenperoxide;(b)notmorethan0,5%availableoxygenfromtheorganicperoxideswhencontainingmorethan1,0%butnotmorethan7,0%hydrogenperoxide.NOTETheavailableoxygencontent(%)ofanorganicperoxideformulationisgivenbytheformula16(cid:1)Σni(cid:1)cimi(cid:1)(cid:2)where:ni=numberofperoxygengroupspermoleculeoforganicperoxidei;ci=concentration(mass%)oforganicperoxidei;andmi=molecularmassoforganicperoxidei.2.2.52.1.6.Organicperoxidesareclassifiedintoseventypesaccordingtothedegreeofdangertheypresent.ThetypesoforganicperoxiderangefromtypeA,whichisnotacceptedforcarriageinthepackaginginwhichitistested,totypeG,whichisnotsubjecttotheprovisionsofClass5.2.TheclassificationoftypesBtoFisdirectlyrelatedtothemaximumquantityallowedinonepackaging.Theprinciplestobeappliedtotheclassificationofsubstancesnotlistedin2.2.52.4aresetoutintheManualoftestsandcriteria,PartII.2.2.52.1.7.Organicperoxidesandformulationsoforganicperoxideswhichhavealreadybeenclassifiedandassignedtotheappropriategenericentryarelistedin2.2.52.4togetherwiththeapplicableUNnumber,packingmethodandwhereappropriate,controlandemergencytemperatures.Thesegenericentriesspecify:—thetype(BtoF)oforganicperoxide(see2.2.52.1.6above),—physicalstate(liquid/solid),and—temperaturecontrol(whenrequired),see2.2.52.1.15to2.2.52.1.18.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/82Mixturesoftheseformulationsmaybeclassifiedasthesametypeoforganicperoxideasthatofthemostdangerouscomponentandbecarriedundertheconditionsofcarriagegivenforthistype.However,astwostablecomponentscanformathermallylessstablemixture,theself-acceleratingdecompositiontemperature(SADT)ofthemixtureshallbedeterminedand,ifnecessary,thecontrolandemergencytemperaturesderivedfromtheSADTinaccordanceparagraph2.2.52.1.16.2.2.52.1.8.Classificationoforganicperoxides,formulationsormixturesoforganicperoxidesnotlistedin2.2.52.4andassignmenttoacollectiveentryshallbemadebythecompetentauthorityofthecountryoforigin.Thestatementofapprovalshallcontaintheclassificationandtherelevantconditionsofcarriage.IfthecountryoforiginisnotaMemberState,theclassificationandconditionsofcarriageshallberecognisedbythecompetentauthorityofthefirstcountryMemberStatereachedbytheconsignment.2.2.52.1.9.Samplesoforganicperoxidesorformulationsoforganicperoxidesnotlistedin2.2.52.4,forwhichacompletesetoftestresultsisnotavailableandwhicharetobecarriedforfurthertestingorevaluation,shallbeassignedtooneoftheappropriateentriesfororganicperoxidestypeCprovidedthefollowingconditionsaremet:—theavailabledataindicatethatthesamplewouldbenomoredangerousthanorganicperoxidestypeB,—thesampleispackagedinaccordancewithpackingmethodOP2andthequantitypertransportunitislimitedto10kg,—theavailabledataindicatethatthecontroltemperature,ifany,issufficientlylowtopreventanydangerousdecompositionandsufficientlyhightopreventanydangerousphaseseparation.Desensitisationoforganicperoxides2.2.52.1.10.Inordertoensuresafetyduringcarriage,organicperoxidesareinmanycasesdesensitisedbyorganicliquidsorsolids,inorganicsolidsorwater.Whereapercentageofasubstanceisstipulated,thisreferstothepercentagebymass,roundedtothenearestwholenumber.Ingeneral,desensitisationshallbesuchthat,incaseofspillage,theorganicperoxidewillnotconcentratetoadangerousextent.2.2.52.1.11.Unlessotherwisestatedfortheindividualorganicperoxideformulation,thefollowingdefinition(s)shallapplytodiluentsusedfordesensitisation:—diluentstypeAareorganicliquidswhicharecompatiblewiththeorganicperoxideandwhichhaveaboilingpointofnotlessthan150°C.TypeAdiluentsmaybeusedfordesensitizingallorganicperoxides,—diluentstypeBareorganicliquidswhicharecompatiblewiththeorganicperoxideandwhichhaveaboilingpointoflessthan150°Cbutnotlessthan60°Candaflash-pointofnotlessthan5°C.TypeBdiluentsmaybeusedfordesensitisationofallorganicperoxidesprovidedthattheboilingpointoftheliquidisatleast60°ChigherthantheSADTina50kgpackage.2.1.52.1.12.Diluents,otherthantypeAortypeB,maybeaddedtoorganicperoxideformulationsaslistedin2.2.52.4providedthattheyarecompatible.However,replacementofallorpartofatypeAortypeBdiluentbyanotherdiluentwithdifferingpropertiesrequiresthattheorganicperoxideformulationbereassessedinaccordancewiththenormalacceptanceprocedureforClass5.2.2.2.52.1.13.Watermayonlybeusedforthedesensitisationoforganicperoxideswhicharelistedin2.2.52.4orinthecompetentauthoritydecisionaccordingto2.2.52.1.8asbeing‘withwater’or‘asastabledispersioninwater’.Samplesoforganicperoxidesorformulationsoforganicperoxidesnotlistedin2.2.52.4mayalsobedesensitisedwithwaterprovidedtherequirementsof2.2.52.1.9aremet.2.2.52.1.14.Organicandinorganicsolidsmaybeusedfordesensitisationoforganicperoxidesprovidedthattheyarecompatible.Compatibleliquidsandsolidsarethosewhichhavenodetrimentalinfluenceonthethermalstabilityandhazardtypeoftheorganicperoxideformulation.Temperaturecontrolrequirements2.2.52.1.15.Certainorganicperoxidesmayonlybecarriedundertemperature-controlledconditions.Thecontroltemperatureisthemaximumtemperatureatwhichtheorganicperoxidecanbesafelycarried.Itisassumedthatthetemperatureoftheimmediatesurroundingsofapackageonlyexceeds55°Cduringcarriageforarelativelyshorttimeina24hourperiod.Intheeventoflossoftemperaturecontrol,itmaybenecessarytoimplementemergencyprocedures.Theemergencytemperatureisthetemperatureatwhichsuchproceduresshallbeimplemented.2.2.52.1.16.ThecontrolandemergencytemperaturesarederivedfromtheSADTwhichisdefinedasthelowesttemperatureatwhichself-acceleratingdecompositionmayoccurwithasubstanceinthepackagingasusedduringcarriage(seeTable1).TheSADTshallbedeterminedinordertodecidewhetherasubstanceshallbesubjectedtotemperaturecontrolduringcarriage.ProvisionsforthedeterminationoftheSADTaregivenintheManualoftestsandcriteria,PartII,Sections20and28.4.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/83Table1DERIVATIONOFCONTROLANDEMERGENCYTEMPERATURESTypeofreceptacleSADT(a)ControltemperatureEmergencytemperatureSinglepackagingsandIBCs≤20°C20°CbelowSADT10°CbelowSADT>20°C≤35°C15°CbelowSADT10°CbelowSADT>35°C10°CbelowSADT5°CbelowSADTTanks<50°C10°CbelowSADT5°CbelowSADT(a)SADTofthesubstanceaspackagedforcarriage.2.2.52.1.17.Thefollowingorganicperoxidesshallbesubjecttotemperaturecontrolduringcarriage:—organicperoxidestypesBandCwithanSADT<50°C;—organicperoxidestypeDshowingamediumeffectwhenheatedunderconfinementwithanSADT<50°CorshowingalowornoeffectwhenheatedunderconfinementwithanSADT<45°C;and—organicperoxidestypesEandFwithanSADT<45°C.NOTEProvisionsforthedeterminationoftheeffectsofheatingunderconfinementaregivenintheManualoftestsandcriteria,PartII,Section20andsubsection28.4.2.2.52.1.18.Whereapplicable,controlandemergencytemperaturesarelistedin2.2.52.4.Theactualtemperatureduringcarriagemaybelowerthanthecontroltemperaturebutshallbeselectedsoastoavoiddangerousseparationofphases.2.2.52.2.SubstancesnotacceptedforcarriageOrganicperoxides,typeA,shallnotbeacceptedforcarriageundertheprovisionsofClass5.2(seeManualoftestsandcriteria,PartII,paragraph20.4.3(a)).2.2.52.3.ListofcollectiveentriesOfficialJournaloftheEuropeanUnionEN26.1.2004L18/842.2.52.4.ListofcurrentlyassignedorganicperoxidesNOTEInthefollowingtable,inthecolumn‘Packingmethod’,(a)Theletters‘OP’followedbyafigurerefertothepackingmethod(see4.1.4.1,packinginstructionP520and4.1.7.1).(b)Theletter‘N’indicatesthatcarriageinIBCsisauthorised(see4.1.4.1,packinginstructionIBC520and4.1.7.2).(c)Theletter‘M’indicatesthatcarriageintanksisauthorised(see4.2.1.13and4.2.4.1,portabletankinstructionT23;4.3.2and4.3.4.1.3(e),tankcodeL4BNforliquidsandS4ANforsolids).OrganicperoxideConcentration(%)DiluenttypeA(%)DiluenttypeB(%)(1)Inertsolid(%)Water(%)PackingmethodControltempera-ture°CEmergencytempera-ture°CNumber(Genericentry)SubsidiaryrisksandremarksACETYLACETONEPEROXIDE≤42≥48≥8OP73105(2)"asapaste≤32OP73106(20)ACETYLBENZOYLPEROXIDE≤45≥55OP73105ACETYLCYCLOHEXANESULPHONYLPEROXIDE≤82≥12OP4-1003112(3)"≤32≥68OP7-1003115tert-AMYLHYDROPEROXIDE≤88≥6≥6OP83107tert-AMYLPEROXYACETATE≤62≥38OP83107tert-AMYLPEROXYBENZOATE≤100OP53103tert-AMYLPEROXY-2-ETHYLHEXANOATE≤100OP7+20+253115tert-AMYLPEROXY-2-ETHYLHEXYLCARBONATE≤100OP73105tert-AMYLPEROXYNEODECANOATE≤77≥23OP70+103115tert-AMYLPEROXYPIVALATE≤77≥23OP5+10+153113tert-AMYLPEROXY-3,5,5-TRIMETHYLHEXANOATE≤100OP53101(3)tert-BUTYLCUMYLPEROXIDE>42-100OP73105"≤42≥58OP73106n-BUTYL-4,4-DI-(tert-BUTYLPEROXY)VALERATE>52-100OP53103"≤52≥48OP73106"≤42≥58OP83108tert-BUTYLHYDROPEROXIDE>79-90≥10OP53103(13)OfficialJournaloftheEuropeanUnionEN26.1.2004L18/85OrganicperoxideConcentration(%)DiluenttypeA(%)DiluenttypeB(%)(1)Inertsolid(%)Water(%)PackingmethodControltempera-ture°CEmergencytempera-ture°CNumber(Genericentry)Subsidiaryrisksandremarks"≤80≥20OP73105(4)(13)"≤79>14OP83107(1)(3)(23)"≤72≥28OP8,N,M3109(13)tert-BUTYLHYDROPEROXIDE+DI-tert-BUTYLPEROXIDE<82+>9≥7OP53103(13)tert-BUTYLMONOPEROXYMALEATE>52-100OP53102(3)"≤52≥48OP63103"≤52≥48OP83108"asapaste≤52OP83108tert-BUTYLMONOPEROXYPHTHALATE≤100OP53102(3)tert-BUTYLPEROXYACETATE>52-77≥23OP53101(3)">32-52≥48OP63103"≤32≥68OP8,N3109"(intanks)≤32≥68M+30+353119"≤22≥78OP83109(25)tert-BUTYLPEROXYBENZOATE>77-100<22OP53103">52-77≥23OP73105"≤52≥48OP73106tert-BUTYLPEROXYBUTYLFUMARATE≤52≥48OP73105tert-BUTYLPEROXYCROTONATE≤77≥23OP73105tert-BUTYLPEROXYDIETHYLACETATE≤100OP5+20+253113OfficialJournaloftheEuropeanUnionEN26.1.2004L18/86OrganicperoxideConcentration(%)DiluenttypeA(%)DiluenttypeB(%)(1)Inertsolid(%)Water(%)PackingmethodControltempera-ture°CEmergencytempera-ture°CNumber(Genericentry)Subsidiaryrisksandremarkstert-BUTYLPEROXYDIETHYLACETATE+tert-BUTYLPEROXY-BENZOATE≤33+≤33≥33OP73105tert-BUTYLPEROXY-2-ETHYLHEXANOATE>52-100OP6+20+253113">32-52≥48OP8+30+353117"≤52≥48OP8+20+253118"≤32≥68OP8+40+453119"(inIBCs)≤32≥68N+30+353119"(intanks)≤32≥68M+15+203119tert-BUTYLPEROXY-2-ETHYLHEXANOATE+2,2-DI-(tert-BUTYLPEROXY)BUTANE≤12+≤14≥14≥60OP73106"≤31+≤36≥33OP7+35+403115tert-BUTYLPEROXY-2-ETHYLHEXYLCARBONATE≤100OP73105tert-BUTYLPEROXYISOBUTYRATE>52-77≥23OP5+15+203111(3)"≤52≥48OP7+15+203115tert-BUTYLPEROXYISOPROPYLCARBONATE≤77≥23OP531031-(2-tert-BUTYLPEROXYISOPROPYL)-3-ISOPROPENYLBENZENE≤77≥23OP73105"≤42≥58OP83108tert-BUTYLPEROXY-2-METHYLBENZOATE≤100OP53103tert-BUTYLPEROXYNEODECANOATE>77-100OP7-5+53115"≤77≥23OP70+103115"asastabledispersioninwater(inIBCs)≤42N-5+53119"asastabledispersioninwater≤52OP80+103117OfficialJournaloftheEuropeanUnionEN26.1.2004L18/87OrganicperoxideConcentration(%)DiluenttypeA(%)DiluenttypeB(%)(1)Inertsolid(%)Water(%)PackingmethodControltempera-ture°CEmergencytempera-ture°CNumber(Genericentry)Subsidiaryrisksandremarks"asastabledispersioninwater(frozen)≤42OP80+103118"≤32≥68OP8,N0+103119tert-BUTYLPEROXYNEOHEPTANOATE≤77≥23OP70+1031153-tert-BUTYLPEROXY-3-PHENYLPHTHALIDE≤100OP73106tert-BUTYLPEROXYPIVALATE>67-77≥23OP50+103113">27-67≥33OP70+103115"≤27≥73OP8+30+353119"(inIBCs)≤27≥73N+10+153119"(intanks)≤27≥73M+5+103119tert-BUTYLPEROXYSTEARYLCARBONATE≤100OP73106tert-BUTYLPEROXY-3,5,5-TRIMETHYLHEXANOATE>32-100OP73105"≤32≥68OP8,N3109"(intanks)≤32≥68M+35+4031193-CHLOROPEROXYBENZOICACID>57-86≥14OP13102(3)"≤57≥3≥40OP73106"≤77≥6≥17OP73106CUMYLHYDROPEROXIDE>90-98≤10OP83107(13)"≤90≥10OP8,M,N3109(13)(18)CUMYLPEROXYNEODECANOATE≤77≥23OP7-1003115"asastabledispersioninwater≤52OP8-1003119OfficialJournaloftheEuropeanUnionEN26.1.2004L18/88OrganicperoxideConcentration(%)DiluenttypeA(%)DiluenttypeB(%)(1)Inertsolid(%)Water(%)PackingmethodControltempera-ture°CEmergencytempera-ture°CNumber(Genericentry)Subsidiaryrisksandremarks"asastabledispersioninwater(inIBCs)≤52N-15-53119CUMYLPEROXYNEOHEPTANOATE≤77≥23OP7-1003115CUMYLPEROXYPIVALATE≤77≥23OP7-5+53115CYCLOHEXANONEPEROXIDE(S)≤91≥9OP63104(13)"≤72≥28OP73105(5)"asapaste≤72OP73106(5)(20)"≤32≥68ExemptDIACETONEALCOHOLPEROXIDES≤57≥26≥8OP7+40+453115(6)DIACETYLPEROXIDE≤27≥73OP7+20+253115(7)(13)DI-tert-AMYLPEROXIDE≤100OP831071,1-DI-(tert-AMYLPEROXY)CYCLOHEXANE≤82≥18OP63103DIBENZOYLPEROXIDE>51-100≤48OP23102(3)">77-94≥6OP43102(3)"≤77≥23OP63104"≤62≥28≥10OP73106"asapaste>52-62OP73106(20)">35-52≥48OP73106">36-42≥18≤40OP83107">36-42≥58OP83107"asapaste≤56.5≥15OP83108OfficialJournaloftheEuropeanUnionEN26.1.2004L18/89OrganicperoxideConcentration(%)DiluenttypeA(%)DiluenttypeB(%)(1)Inertsolid(%)Water(%)PackingmethodControltempera-ture°CEmergencytempera-ture°CNumber(Genericentry)Subsidiaryrisksandremarks"asapaste≤52OP83108(20)"asastabledispersioninwater≤42OP8,N3109"≤35≥65ExemptDIBENZYLPEROXYDICARBONATE≤87≥13OP5+25+303112(3)DI-(4-tert-BUTYLCYCLOHEXYL)PEROXYDICARBONATE≤100OP6+30+353114"asastabledispersioninwater≤42OP8,N+30+353119DI-tert-BUTYLPEROXIDE>32-100OP83107"≤52≥48OP8,N3109(25)"≤32≥68M3109DI-tert-BUTYLPEROXYAZELATE≤52≥48OP731052,2-DI-(tert-BUTYLPEROXY)BUTANE≤52≥48OP631031,1-DI-(tert-BUTYLPEROXY)CYCLOHEXANE>80-100OP53101(3)">52-80≥20OP53103">42-52≥48OP73105"≤42≥13≥45OP73106"≤27≥36OP83107(21)"≤42≥58OP8,N3109"≤13≥13≥74OP83109DI-n-BUTYLPEROXYDICARBONATE>27-52≥48OP7-15-53115"≤27≥73OP8-1003117OfficialJournaloftheEuropeanUnionEN26.1.2004L18/90OrganicperoxideConcentration(%)DiluenttypeA(%)DiluenttypeB(%)(1)Inertsolid(%)Water(%)PackingmethodControltempera-ture°CEmergencytempera-ture°CNumber(Genericentry)Subsidiaryrisksandremarks"asastabledispersioninwater(frozen)≤42OP8-15-53118DI-sec-BUTYLPEROXYDICARBONATE>52-100OP4-20-103113"≤52≥48OP7-15-53115DI-(2-tert-BUTYLPEROXYISOPROPYL)BENZENE(S)>42-100≤57OP73106"≤42≥58ExemptDI-(tert-BUTYLPEROXY)PHTHALATE>42-52≥48OP73105"asapaste≤52OP73106(20)"≤42≥58OP831072,2-DI-(tert-BUTYLPEROXY)PROPANE≤52≥48OP73105"≤42≥13≥45OP731061,1-DI-(tert-BUTYLPEROXY)-3,3,5-TRIMETHYLCYCLOHEXANE>90-100OP53101(3)">57-90≥10OP53103"≤77≥23OP73105"≤57≥43OP73106"≤57≥43OP83107"≤32≥26≥42OP83107DICETYLPEROXYDICARBONATE≤100OP7+30+353116"asastabledispersioninwater≤42OP8,N+30+353119DI-4-CHLOROBENZOYLPEROXIDE≤77≥23OP53102(3)"asapaste≤52OP73106(20)OfficialJournaloftheEuropeanUnionEN26.1.2004L18/91OrganicperoxideConcentration(%)DiluenttypeA(%)DiluenttypeB(%)(1)Inertsolid(%)Water(%)PackingmethodControltempera-ture°CEmergencytempera-ture°CNumber(Genericentry)Subsidiaryrisksandremarks"≤32≥68ExemptDICUMYLPEROXIDE>42-100≤57OP8,M3110(12)"≤52≥48ExemptDICYCLOHEXYLPEROXYDICARBONATE>91-100OP3+5+103112(3)"≤91≥9OP5+5+103114DIDECANOYLPEROXIDE≤100OP6+30+3531142,2-DI-(4,4-DI(tert-BUTYLPEROXY)CYCLOHEXYL)PROPANE≤42≥58OP73106"≤22≥78OP83107DI-2,4-DICHLOROBENZOYLPEROXIDE≤77≥23OP53102(3)"asapastewithsiliconoil≤52OP73106DI-(2-ETHOXYETHYL)PEROXYDICARBONATE≤52≥48OP7-1003115DI-(2-ETHYLHEXYL)PEROXYDICARBONATE>77-100OP5-20-103113"≤77≥23OP7-15-53115"asastabledispersioninwater≤62OP8-15-53117"asastabledispersioninwater(inIBCs)≤52N-20-103119"asastabledispersioninwater≤52OP8-15-53119"asastabledispersioninwater(frozen)≤42OP8-15-53118DIETHYLPEROXYDICARBONATE≤27≥73OP7-10031152,2-DIHYDROPEROXYPROPANE≤27≥73OP53102(3)DI-(1-HYDROXYCYCLOHEXYL)PEROXIDE≤100OP73106OfficialJournaloftheEuropeanUnionEN26.1.2004L18/92OrganicperoxideConcentration(%)DiluenttypeA(%)DiluenttypeB(%)(1)Inertsolid(%)Water(%)PackingmethodControltempera-ture°CEmergencytempera-ture°CNumber(Genericentry)SubsidiaryrisksandremarksDIISOBUTYRYLPEROXIDE>32-52≥48OP5-20-103111(3)"≤32≥68OP7-20-103115DI-ISOPROPYLBENZENEDIHYDROPEROXIDE≤82≥5≥5OP73106(24)DIISOPROPYLPEROXYDICARBONATE>52-100OP2-15-53112(3)"≤52≥48OP7-20-103115DIISOTRIDECYLPEROXYDICARBONATE≤100OP7-1003115DILAUROYLPEROXIDE≤100OP73106"asastabledispersioninwater≤42OP8,N3109DI-(3-METHOXYBUTYL)PEROXYDICARBONATE≤52≥48OP7-5+53115DI-(2-METHYLBENZOYL)PEROXIDE≤87≥13OP5+30+353112(3)DI-(3-METHYLBENZOYL)PEROXIDE+BENZOYL(3-METHYL-BENZOYL)PEROXIDE+DIBENZOYLPEROXIDE≤20+≤18+≤4≥58OP7+35+403115DI-(4-METHYLBENZOYL)PEROXIDEasapastewithsiliconoil≤52OP731062,5-DIMETHYL-2,5-DI-(BENZOYLPEROXY)HEXANE>82-100OP53102(3)"≤82≥18OP73106"≤82≥18OP531042,5-DIMETHYL-2,5-DI-(tert-BUTYLPEROXY)HEXANE>52-100OP73105"≤52≥48OP73106"asapaste≤47OP83108"≤52≥48OP83109"≤77≥23OP83108OfficialJournaloftheEuropeanUnionEN26.1.2004L18/93OrganicperoxideConcentration(%)DiluenttypeA(%)DiluenttypeB(%)(1)Inertsolid(%)Water(%)PackingmethodControltempera-ture°CEmergencytempera-ture°CNumber(Genericentry)Subsidiaryrisksandremarks2,5-DIMETHYL-2,5-DI-(tert-BUTYLPEROXY)HEXYNE-3>52-86≥14OP53103(26)"≤52≥48OP73106">86-100OP53101(3)2,5-DIMETHYL-2,5-DI-(2-ETHYLHEXANOYLPEROXY)HEXANE≤100OP5+20+2531132,5-DIMETHYL-2,5-DIHYDROPEROXYHEXANE≤82≥18OP631042,5-DIMETHYL-2,5-DI-(3,5,5-TRIMETHYLHEXANOYLPEROXY)-HEXANE≤77≥23OP731051,1-DIMETHYL-3-HYDROXYBUTYLPEROXYNEOHEPTANOATE≤52≥48OP80+103117DIMYRISTYLPEROXYDICARBONATE≤100OP7+20+253116"asastabledispersioninwater≤42OP8+20+253119"asastabledispersioninwater(inIBCs)≤42N+15+203119DI-(2-NEODECANOYLPEROXYISOPROPYL)BENZENE≤52≥48OP7-1003115DI-n-NONANOYLPEROXIDE≤100OP70+103116DI-n-OCTANOYLPEROXIDE≤100OP5+10+153114DIPEROXYAZELAICACID≤27≥73OP7+35+403116DIPEROXYDODECANEDIACID>13-42≥58OP7+40+453116"≤13≥87ExemptDI-(2-PHENOXYETHYL)PEROXYDICARBONATE>85-100OP53102(3)"≤85≥15OP73106DIPROPIONYLPEROXIDE≤27≥73OP8+15+203117DI-n-PROPYLPEROXYDICARBONATE≤100OP3-25-153113OfficialJournaloftheEuropeanUnionEN26.1.2004L18/94OrganicperoxideConcentration(%)DiluenttypeA(%)DiluenttypeB(%)(1)Inertsolid(%)Water(%)PackingmethodControltempera-ture°CEmergencytempera-ture°CNumber(Genericentry)Subsidiaryrisksandremarks"≤77≥23OP5-20-103113DISTEARYLPEROXYDICARBONATE≤87≥13OP73106DISUCCINICACIDPEROXIDE>72-100OP43102(3)(17)"≤72≥28OP7+10+153116DI-(3,5,5-TRIMETHYLHEXANOYL)PEROXIDE>38-82≥18OP70+103115"asastabledispersioninwater≤52OP8,N+10+153119"≤38≥62OP8+20+253119"(inIBCs)≤38≥62N+10+153119"(intanks)≤38≥62M0+53119DI-(3,5,5-TRIMETHYL-1,2-DIOXOLANYL-3)PEROXIDEasapaste≤52OP7+30+353116(20)ETHYL3,3-DI-(tert-AMYLPEROXY)BUTYRATE≤67≥33OP73105ETHYL3,3-DI-(tert-BUTYLPEROXY)BUTYRATE>77-100OP53103"≤77≥23OP73105"≤52≥48OP731063,3,6,6,9,9-HEXAMETHYL-1,2,4,5-TETRAOXACYCLONONANE>52-100OP43102(3)"≤52≥48OP73105"≤52≥48OP73106tert-HEXYLPEROXYNEODECANOATE≤71≥29OP70+103115tert-HEXYLPEROXYPIVALATE≤72≥28OP7+10+153115ISOPROPYLsec-BUTYLPEROXYDICARBONATE+DI-sec-BUTYLPEROXYDICARBONATE+DI-ISOPROPYLPEROXYDICARBO-NATE≤32+≤15-18+≤12-15≥38OP7-20-103115OfficialJournaloftheEuropeanUnionEN26.1.2004L18/95OrganicperoxideConcentration(%)DiluenttypeA(%)DiluenttypeB(%)(1)Inertsolid(%)Water(%)PackingmethodControltempera-ture°CEmergencytempera-ture°CNumber(Genericentry)SubsidiaryrisksandremarksISOPROPYLsec-BUTYLPEROXYDICARBONATE+DI-sec-BUTYLPEROXYDICARBONATE+DI-ISOPROPYLPEROXYDICARBO-NATE≤52+≤28+≤22OP5-20-103111(3)ISOPROPYLCUMYLHYDROPEROXIDE≤72≥28OP8,M,N3109(13)p-MENTHYLHYDROPEROXIDE>72-100OP73105(13)"≤72≥28OP8,M,N3109(27)METHYLCYCLOHEXANONEPEROXIDE(S)≤67≥33OP7+35+403115METHYLETHYLKETONEPEROXIDE(S)≤52≥48OP53101(3)(8)(13)"≤45≥55OP73105(9)"≤40≥60OP83107(10)"≤37≥55≥8OP73105(9)METHYLISOBUTYLKETONEPEROXIDE(S)≤62≥19OP73105(22)ORGANICPEROXIDE,LIQUID,SAMPLEOP23103(11)ORGANICPEROXIDE,LIQUID,SAMPLE,TEMPERATURECONTROLLEDOP23113(11)ORGANICPEROXIDE,SOLID,SAMPLEOP23104(11)ORGANICPEROXIDE,SOLID,SAMPLE,TEMPERATURECONTROLLEDOP23114(11)PEROXYACETICACID,TYPED,stabilized≤43OP73105(13)(14)(19)PEROXYACETICACID,TYPEE,stabilized≤43OP83107(13)(15)(19)PEROXYACETICACID,TYPEF,stabilized≤43OP8,N3109(13)(16)(19)PINANYLHYDROPEROXIDE56-100OP73105(13)"<56>44OP8,M3109TETRAHYDRONAPHTHYLHYDROPEROXIDE≤100OP73106OfficialJournaloftheEuropeanUnionEN26.1.2004L18/96OrganicperoxideConcentration(%)DiluenttypeA(%)DiluenttypeB(%)(1)Inertsolid(%)Water(%)PackingmethodControltempera-ture°CEmergencytempera-ture°CNumber(Genericentry)Subsidiaryrisksandremarks1,1,3,3-TETRAMETHYLBUTYLHYDROPEROXIDE≤100OP731051,1,3,3-TETRAMETHYLBUTYLPEROXY-2ETHYLHEXANOATE≤100OP7+20+2531151,1,3,3-TETRAMETHYLBUTYLPEROXYNEODECANOATE≤72≥28OP7-5+53115"asastabledispersioninwater≤52OP8,N-5+531191,1,3,3-TETRAMETHYLBUTYLPEROXYPHENOACETATE≤37≥63OP7-10031153,6,9-TRIETHYL-3,6,9-TRIMETHYL-1,4,7-TRIPEROXONANE≤42≥58OP73105(28)(1)DiluenttypeBmayalwaysbereplacedbydiluenttypeA.(2)Availableoxygen≤4,7%.(3)‘EXPLOSIVE’subsidiaryrisklabelrequired(ModelNo1,see5.2.2.2.2).(4)Diluentmaybereplacedbydi-tert-butylperoxide.(5)Availableoxygen≤9%.(6)With≤9%hydrogenperoxide;availableoxygen≤10%.(7)Onlynon-metallicpackagingsallowed.(8)Availableoxygen>10%.(9)Availableoxygen≤10%.(10)Availableoxygen≤8.2%.(11)See2.2.52.1.9.(12)Upto2000kgperreceptacleassignedtoORGANICPEROXIDETYPEFonthebasisoflargescaletrials.(13)‘CORROSIVE’subsidiaryrisklabelrequired(ModelNo8,see5.2.2.2.2).(14)PeroxyaceticacidformulationswhichfulfilthecriteriaoftheManualoftestsandcriteria,paragraph20.4.3(d).(15)PeroxyaceticacidformulationswhichfulfilthecriteriaoftheManualoftestsandcriteria,paragraph20.4.3(e).(16)PeroxyaceticacidformulationswhichfulfilthecriteriaoftheManualoftestsandcriteria,paragraph20.4.3(f).(17)Additionofwatertothisorganicperoxidewilldecreaseitsthermalstability.(18)No‘CORROSIVE’subsidiaryrisklabel(ModelNo8,see5.2.2.2.2)requiredforconcentrationsbelow80%.(19)Mixtureswithhydrogenperoxide,waterandacid(s).(20)WithdiluenttypeA,withorwithoutwater.(21)With≥36%,bymass,ethylbenzeneinadditiontodiluenttypeA.(22)With≥19%,bymass,methylisobutylketoneinadditiontodiluenttypeA.(23)With<6%di-tert-butylperoxide.(24)With≤8%1-isopropylhydroperoxy-4-isopropylhydroxybenzene.(25)DiluenttypeBwithboilingpoint>110°C.(26)With<0,5%hydroperoxidescontent.(27)Forconcentrationsmorethan56%,‘CORROSIVE’subsidiaryrisklabelrequired(ModelNo8,see5.2.2.2.2).(28)Availableactiveoxygen≤7,6%indiluentTypeAhavinga95%boil-offpointintherangeof200to260°C.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/972.2.61.Class6.1Toxicsubstances2.2.61.1.Criteria2.2.61.1.1.TheheadingofClass6.1coverssubstancesofwhichitisknownbyexperienceorregardingwhichitispresumedfromexperimentsonanimalsthatinrelativelysmallquantitiestheyareablebyasingleactionorbyactionofshortdurationtocausedamagetohumanhealth,ordeath,byinhalation,bycutaneousabsorptionorbyingestion.2.2.61.1.2.SubstancesofClass6.1aresubdividedasfollows:Ttoxicsubstanceswithoutsubsidiaryrisk:T1organic,liquid;T2organic,solid;T3organometallicsubstances;T4inorganic,liquid;T5inorganic,solid;T6liquid,usedaspesticides;T7solid,usedaspesticides;T8samples;T9othertoxicsubstances;TFtoxicsubstances,flammable:TF1liquid;TF2liquid,usedaspesticides;TF3solid;TStoxicsubstances,self-heating,solid;TWtoxicsubstances,which,incontactwithwater,emitflammablegases:TW1liquid;TW2solid;TOtoxicsubstances,oxidising:TO1liquid;TO2solid;TCtoxicsubstances,corrosive:TC1organic,liquid;TC2organic,solid;TC3inorganic,liquid;TC4inorganic,solid;TFCtoxicsubstances,flammable,corrosive.Definitions2.2.61.1.3.ForthepurposesofthisDirective:LD50foracuteoraltoxicityisthatdoseofthesubstanceadministeredwhichismostlikelytocausedeathwithin14daysinonehalfofbothmaleandfemaleyoungadultalbinorats.Thenumberofanimalstestedshallbesufficienttogiveastatisticallysignificantresultandbeinconformitywithgoodpharmacologicalpractice.Theresultisexpressedinmilligramsperkgbodymass;OfficialJournaloftheEuropeanUnionEN26.1.2004L18/98LD50foracutedermaltoxicityisthatdoseofthesubstancewhich,administeredbycontinuouscontactfor24hourswiththebareskinofalbinorabbits,ismostlikelytocausedeathwithin14daysinonehalfoftheanimalstested.Thenumberofanimalstestedshallbesufficienttogiveastatisticallysignificantresultandbeinconformitywithgoodpharmacologicalpractice.Theresultisexpressedinmilligramsperkgbodymass;LC50foracutetoxicityoninhalationisthatconcentrationofvapour,mistordustwhich,administeredbycontinuousinhalationtobothmaleandfemaleyoungadultalbinoratsforonehour,ismostlikelytocausedeathwithin14daysinonehalfoftheanimalstested.Asolidsubstanceshallbetestedifatleast10%(bymass)ofitstotalmassislikelytobedustinarespirablerange,e.g.theaerodynamicdiameterofthatparticle-fractionis10µmorless.Aliquidsubstanceshallbetestedifamistislikelytobegeneratedinaleakageofthetransportcontainment.Bothforsolidandliquidsubstancesmorethan90%(bymass)ofaspecimenpreparedforinhalationtoxicityshallbeintherespirablerangeasdefinedabove.Theresultisexpressedinmilligramsperlitreofairfordustsandmistsorinmillilitrespercubicmetreofair(partspermillion)forvapours.Classificationandassignmentofpackinggroups2.2.61.1.4.SubstancesofClass6.1shallbeclassifiedinthreepackinggroupsaccordingtothedegreeofdangertheypresentforcarriage,asfollows:PackinggroupI:highlytoxicsubstancesPackinggroupII:toxicsubstancesPackinggroupIII:slightlytoxicsubstances.2.2.61.1.5.Substances,mixtures,solutionsandarticlesclassifiedinClass6.1arelistedinTableAofChapter3.2.Theassignmentofsubstances,mixturesandsolutionsnotmentionedbynameinTableAofChapter3.2totherelevantentryofsubsection2.2.61.3andtotherelevantpackinggroupinaccordancewiththeprovisionsofChapter2.1,shallbemadeaccordingtothefollowingcriteriain2.2.61.1.6to2.2.61.1.11.2.2.61.1.6.Toassessthedegreeoftoxicity,accountshallbetakenofhumanexperienceofinstancesofaccidentalpoisoning,aswellasspecialpropertiespossessedbyanyindividualsubstances:liquidstate,highvolatility,anyspeciallikelihoodofcutaneousabsorption,andspecialbiologicaleffects.2.2.61.1.7.Intheabsenceofobservationsonhumans,thedegreeoftoxicityshallbeassessedusingtheavailabledatafromanimalexperimentsinaccordancewiththetable.PackinggroupOraltoxicityLD50(mg/kg)DermaltoxicityLD50(mg/kg)ToxicityoninhalationofdustsandmistsLC50(mg/l)HighlytoxicI≤5≤40≤0,5ToxicII>5-50>40-200>0,5-2SlightlytoxicIII(a)solids:>50-200liquids:>50-500>200-1000>2-10(a)TeargasesshallbeincludedinpackinggroupIIevenifdataconcerningtheirtoxicitycorrespondtopackinggroupIIIcriteria.2.2.61.1.7.1.Whereasubstanceexhibitsdifferentdegreesoftoxicityfortwoormorekindsofexposure,itshallbeclassifiedunderthehighestsuchdegreeoftoxicity.2.2.61.1.7.2.SubstancesmeetingthecriteriaofClass8andwithaninhalationtoxicityofdustsandmists(LC50)leadingtopackinggroupIshallonlybeacceptedforanallocationtoClass6.1ifthetoxicitythroughoralingestionordermalcontactisatleastintherangeofpackinggroupsIorII.OtherwiseanassignmenttoClass8shallbemadeifappropriate(seefootnote6in2.2.8.1.4).OfficialJournaloftheEuropeanUnionEN26.1.2004L18/992.2.61.1.7.3.ThecriteriaforinhalationtoxicityofdustsandmistsarebasedonLC50datarelatingtoone-hourexposure,andwheresuchinformationisavailableitshallbeused.However,whereonlyLC50datarelatingtofour-hourexposureareavailable,suchfigurescanbemultipliedbyfourandtheproductsubstitutedintheabovecriteria,i.e.LC50valuemultipliedbyfour(fourhour)isconsideredtheequivalentofLC50(onehour).Inhalationtoxicityofvapours2.2.61.1.8.Liquidsgivingofftoxicvapoursshallbeclassifiedintothefollowinggroupswhere‘V’isthesaturatedvapourconcentration(inml/m3ofair)(volatility)at20°Candstandardatmosphericpressure:PackinggroupHighlytoxicIWhereV≥10LC50andLC50≤1000ml/m3ToxicIIWhereV≥LC50andLC50≤3000ml/m3andthecriteriaforpackinggroupIarenotmetSlightlytoxicIIIWhereV≥1/5LC50andLC50≤5000ml/m3andthecriteriaforpackinggroupsIandIIarenotmetThesecriteriaforinhalationtoxicityofvapoursarebasedonLC50datarelatingtoonehourexposure,andwheresuchinformationisavailable,itshallbeused.However,whereonlyLC50datarelatingtofour-hourexposuretothevapoursareavailable,suchfigurescanbemultipliedbytwoandtheproductsubstitutedintheabovecriteria,i.e.LC50(fourhour)×2isconsideredtheequivalentofLC50(onehour).OfficialJournaloftheEuropeanUnionEN26.1.2004L18/100GROUPBORDERLINESINHALATIONTOXICITYOFVAPOURSInthisfigure,thecriteriaareexpressedingraphicalform,asanaidtoeasyclassification.However,duetoapproximationsinherentintheuseofgraphs,substancesfallingonorneargroupborderlinesshallbecheckedusingnumericalcriteria.Mixturesofliquids2.2.61.1.9.Mixturesofliquidswhicharetoxiconinhalationshallbeassignedtopackinggroupsaccordingtothefollowingcriteria.2.2.61.1.9.1.IfLC50isknownforeachofthetoxicsubstancesconstitutingthemixture,thepackinggroupmaybedeterminedasfollows:(a)calculationoftheLC50ofthemixture:OfficialJournaloftheEuropeanUnionEN26.1.2004L18/101wherefi=molarfractionofconstituentiofthemixtureLC50i=averagelethalconcentrationofconstituentiinml/m3(b)calculationofvolatilityofeachmixtureconstituent:Vi¼Pi(cid:1)106101;3(ml/m3)wherePi=partialpressureofconstituentiinkPaat20°Candatstandardatmosphericpressure(c)calculationoftheratioofvolatilitytoLC50:(d)thevaluescalculatedforLC50(mixture)andRarethenusedtodeterminethepackinggroupofthemixture:PackinggroupIR≥10andLC50(mixture)≤1000ml/m3PackinggroupIIR≥1andLC50(mixture)≤3000ml/m3,ifthemixturedoesnotmeetthecriteriaforpackinggroupIPackinggroupIIIR≥1/5andLC50(mixture)≤5000ml/m3,ifthemixturedoesnotmeetthecriteriaofpackinggroupIorII.2.2.61.1.9.2.IntheabsenceofLC50dataonthetoxicconstituentsubstances,themixturemaybeassignedtoagroupbasedonthefollowingsimplifiedthresholdtoxicitytests.Whenthesethresholdtestsareused,themostrestrictivegroupshallbedeterminedandusedforcarryingthemixture.2.2.61.1.9.3.AmixtureisassignedtopackinggroupIonlyifitmeetsbothofthefollowingcriteria:(a)asampleoftheliquidmixtureisvaporisedanddilutedwithairtocreateatestatmosphereof1000ml/m3vaporisedmixtureinair.Tenalbinorats(fivemaleandfivefemale)areexposedtothetestatmosphereforonehourandobservedfor14days.Iffiveormoreoftheanimalsdiewithinthe14-dayobservationperiod,themixtureispresumedtohaveanLC50equaltoorlessthan1000ml/m3;(b)asampleofvapourinequilibriumwiththeliquidmixtureisdilutedwithnineequalvolumesofairtoformatestatmosphere.Tenalbinorats(fivemaleandfivefemale)areexposedtothetestatmosphereforonehourandobservedfor14days.Iffiveormoreoftheanimalsdiewithinthe14-dayobservationperiod,themixtureispresumedtohaveavolatilityequaltoorgreaterthan10timesthemixtureLC50.2.2.61.1.9.4.AmixtureisassignedtopackinggroupIIonlyifitmeetsbothofthefollowingcriteria,anddoesnotmeetthecriteriaforpackinggroupI:(a)asampleoftheliquidmixtureisvaporisedanddilutedwithairtocreateatestatmosphereof3000ml/m3vaporisedmixtureinair.Tenalbinorats(fivemaleandfivefemale)areexposedtothetestatmosphereforonehourandobservedfor14days.Iffiveormoreoftheanimalsdiewithinthe14-dayobservationperiod,themixtureispresumedtohaveanLC50equaltoorlessthan3000ml/m3;(b)asampleofthevapourinequilibriumwiththeliquidmixtureisusedtoformatestatmosphere.Tenalbinorats(fivemaleandfivefemale)areexposedtothetestatmosphereforonehourandobservedfor14days.Iffiveormoreoftheanimalsdiewithinthe14-dayobservationperiod,themixtureispresumedtohaveavolatilityequaltoorgreaterthanthemixtureLC50.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/1022.2.61.1.9.5.AmixtureisassignedtopackinggroupIIIonlyifitmeetsbothofthefollowingcriteria,anddoesnotmeetthecriteriaforpackinggroupsIorII:(a)asampleoftheliquidmixtureisvaporisedanddilutedwithairtocreateatestatmosphereof5000ml/m3vaporisedmixtureinair.Tenalbinorats(fivemaleandfivefemale)areexposedtothetestatmosphereforonehourandobservedfor14days.Iffiveormoreoftheanimalsdiewithinthe14-dayobservationperiod,themixtureispresumedtohaveanLC50equaltoorlessthan5000ml/m3;(b)thevapourconcentration(volatility)oftheliquidmixtureismeasuredandifthevapourconcentrationisequaltoorgreaterthan1000ml/m3,themixtureispresumedtohaveavolatilityequaltoorgreaterthan1/5themixtureLC50.Methodsfordeterminingoralanddermaltoxicityofmixtures2.2.61.1.10.WhenclassifyingandassigningtheappropriatepackinggrouptomixturesinClass6.1inaccordancewiththeoralanddermaltoxicitycriteria(see2.2.61.1.3),itisnecessarytodeterminetheacuteLD50ofthemixture.2.2.61.1.10.1.Ifamixturecontainsonlyoneactivesubstance,andtheLD50ofthatconstituentisknown,intheabsenceofreliableacuteoralanddermaltoxicitydataontheactualmixturetobecarried,theoralordermalLD50maybeobtainedbythefollowingmethod:LD50valueofpreparation¼LD50valueofactivesubstancepercentageofsubstancebymass2.2.61.1.10.2.Ifamixturecontainsmorethanoneactiveconstituent,therearethreepossibleapproachesthatmaybeusedtodeterminetheoralordermalLD50ofthemixture.Thepreferredmethodistoobtainreliableacuteoralanddermaltoxicitydataontheactualmixturetobecarried.Ifreliable,accuratedataisnotavailable,theneitherofthefollowingmethodsmaybeperformed:(a)classifytheformulationaccordingtothemosthazardousconstituentofthemixtureasifthatconstituentwerepresentinthesameconcentrationasthetotalconcentrationofallactiveconstituents;or(b)Applytheformula:CATAþCBTBþ:::þCZTZ¼100TMwhere:C=thepercentageconcentrationofconstituentA,B,...ZinthemixtureT=theoralLD50valuesofconstituentA,B,...ZTM=theoralLD50valueofthemixture.NOTEThisformulacanalsobeusedfordermaltoxicitiesprovidedthatthisinformationisavailableonthesamespeciesforallconstituents.Theuseofthisformuladoesnottakeintoaccountanypotentiationorprotectivephenomena.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/103Classificationofpesticides2.2.61.1.11.AllactivepesticidesubstancesandtheirpreparationsforwhichtheLC50and/orLD50valuesareknownandwhichareclassifiedinClass6.1shallbeclassifiedunderappropriatepackinggroupsinaccordancewiththecriteriagivenin2.2.61.1.6to2.2.61.1.9.Substancesandpreparationswhicharecharacterisedbysubsidiaryrisksshallbeclassifiedaccordingtotheprecedenceofhazardtablein2.1.3.9withtheassignmentofappropriatepackinggroups.2.2.61.1.11.1.IftheoralordermalLD50valueforapesticidepreparationisnotknown,buttheLD50valueofitsactivesubstance(s)isknown,theLD50valueforthepreparationmaybeobtainedbyapplyingtheproceduresin2.2.61.1.10.NOTELD50toxicitydataforanumberofcommonpesticidesmaybeobtainedfromthemostcurrenteditionofthedocument‘TheWHOrecommendedclassificationofpesticidesbyhazardandguidelinestoclassification’availablefromtheInternationalProgrammeonChemicalSafety,WorldHealthOrganisation(WHO),1211Geneva27,Switzerland.WhilethatdocumentmaybeusedasasourceofLD50dataforpesticides,itsclassificationsystemshallnotbeusedforpurposesoftransportclassificationof,orassignmentofpackinggroupsto,pesticides,whichshallbeinaccordancewiththerequirementsofthisDirective.2.2.61.1.11.2.Thepropershippingnameusedinthecarriageofthepesticideshallbeselectedonthebasisoftheactiveingredient,ofthephysicalstateofthepesticideandanysubsidiaryrisksitmayexhibit(see3.1.2).2.2.61.1.12.IfsubstancesofClass6.1,asaresultofadmixtures,comeintocategoriesofriskdifferentfromthosetowhichthesubstancesmentionedbynameinTableAofChapter3.2belong,thesemixturesorsolutionsshallbeassignedtotheentriestowhichtheybelongonthebasisoftheiractualdegreeofdanger.NOTEFortheclassificationofsolutionsandmixtures(suchaspreparationsandwastes),seealso2.1.3.2.2.61.1.13.Onthebasisofthecriteriaof2.2.61.1.6to2.2.61.1.11,itmayalsobedeterminedwhetherthenatureofasolutionormixturementionedbynameorcontainingasubstancementionedbynameissuchthatthesolutionormixtureisnotsubjecttotherequirementsforthisClass.2.2.61.1.14.Substances,solutionsandmixtures,withtheexceptionofsubstancesandpreparationsusedaspesticides,whichdonotmeetthecriteriaofDirectives67/548/EEC(1)or88/379/EEC(2)asamendedandwhicharenotthereforeclassifiedashighlytoxic,toxicorharmfulaccordingtothesedirectives,asamended,maybeconsideredassubstancesnotbelongingtoClass6.1.2.2.61.2.Substancesnotacceptedforcarriage2.2.61.2.1.ChemicallyunstablesubstancesofClass6.1shallnotbeacceptedforcarriageunlessthenecessarystepshavebeentakentopreventtheirdangerousdecompositionorpolymerisationduringcarriage.Tothisend,itshallinparticularbeensuredthatreceptaclesandtanksdonotcontainanysubstance(s)likelytocausesuchareaction.2.2.61.2.2.Thefollowingsubstancesandmixturesshallnotbeacceptedforcarriage:—hydrogencyanide,anhydrousorinsolution,whichdonotmeetthedescriptionsofUNNos1051,1613,1614and3294,—metalcarbonyls,havingaflash-pointbelow23°C,otherthanUNNos1259NICKELCARBONYLand1994IRONPENTACAR-BONYL,—2,3,7,8-TETRACHLORODIBENZO-P-DIOXINE(TCDD)inconcentrationsconsideredhighlytoxicinaccordancewiththecriteriain2.2.61.1.7,—UNNo2249DICHLORODIMETHYLETHER,SYMMETRICAL,—preparationsofphosphideswithoutadditivesinhibitingtheemissionoftoxicflammablegases.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/104(1)CouncilDirective67/548/EECof27June1967ontheapproximationoflaws,regulationsandadministrativeprovisionsrelatingtotheclassification,packagingandlabellingofdangeroussubstances(OJL196,16.8.1967,p.1).(2)CouncilDirective88/379/EEContheapproximationoflaws,regulationsandadministrativeprovisionsrelatingtotheclassification,packagingandlabellingofdangerouspreparations(OJL187,16.7.1988,p.14).2.2.61.3.ListofcollectiveentriesOfficialJournaloftheEuropeanUnionEN26.1.2004L18/105OfficialJournaloftheEuropeanUnionEN26.1.2004L18/106OfficialJournaloftheEuropeanUnionEN26.1.2004L18/1072.2.62.Class6.2Infectioussubstances2.2.62.1.Criteria2.2.62.1.1.TheheadingofClass6.2coversinfectioussubstances.Infectioussubstancesarethosesubstancesknownorreasonablyexpectedtocontainpathogens.Pathogensaredefinedasmicro-organisms(includingbacteria,viruses,rickettsia,parasites,fungi)orrecombinantmicro-organisms(hybridormutant),thatareknownorreasonablyexpectedtocauseinfectiousdiseaseinanimalsorhumans.Forthepurposesofthisclass,viruses,micro-organismsaswellasarticlescontaminatedwiththeseshallbeconsideredassubstancesofthisClass.NOTE1.Substancesreferredtoabovearenotsubjecttotherequirementsapplicabletothisclassiftheyareunlikelytocausehumanoranimaldisease.2.Infectioussubstancesaresubjecttotherequirementsapplicabletothisclassonlyiftheyarecapableofspreadingdiseasetohumansoranimalswhenexposuretothemoccurs.3.Geneticallymodifiedmicro-organismsandorganisms,biologicalproducts,diagnosticspecimensandinfectedliveanimalsshallbeassignedtothisclassiftheymeettheconditionsforthisclass.4.Toxinsfromplant,animalorbacterialsourceswhichdonotcontainanyinfectioussubstancesororganismsorwhicharenotcontainedinthemaresubstancesofClass6.1,UNNo3172.2.2.62.1.2.SubstancesofClass6.2aresubdividedasfollows:I1infectioussubstancesaffectinghumans;I2infectioussubstancesaffectinganimalsonly;I3clinicalwaste.Definitionsandclassification2.2.62.1.3.InfectioussubstancesshallbeclassifiedinClass6.2andassignedtoUNNo2814or2900,asappropriate,onthebasisoftheirallocationtooneofthreeriskgroupsbasedoncriteriadevelopedbytheWorldHealthOrganisation(WHO)andpublishedintheWHO‘Laboratorybiosafetymanual,secondedition(1993)’.Ariskgroupischaracterisedbythepathogenicityoftheorganism,themodeandrelativeeaseoftransmission,thedegreeofrisktobothanindividualandacommunity,andthereversibilityofthediseasethroughtheavailabilityofknownandeffectivepreventiveagentsandtreatment.Thecriteriaforeachriskgroupaccordingtothelevelofriskareasfollows:a)riskgroup4:apathogenthatusuallycausesserioushumanoranimaldiseaseandthatcanbereadilytransmittedfromoneindividualtoanother,directlyorindirectly,andforwhicheffectivetreatmentandpreventivemeasuresarenotusuallyavailable(i.e.,highindividualandcommunityrisk),b)riskgroup3:apathogenthatusuallycausesserioushumanoranimaldiseasebutdoesnotordinarilyspreadfromoneinfectedindividualtoanother,andforwhicheffectivetreatmentandpreventivemeasuresareavailable(i.e.highindividualriskandlowcommunityrisk),c)riskgroup2:apathogenthatcancausehumanoranimaldiseasebutisunlikelytobeaserioushazard,and,whilecapableofcausingseriousinfectiononexposure,forwhicheffectivetreatmentandpreventivemeasuresareavailableandtheriskofspreadofinfectionislimited(i.e.moderateindividualriskandlowcommunityrisk).NOTERiskgroup1includesmicro-organismsthatareunlikelytocausehumanoranimaldisease(i.e.no,orverylow,individualorcommunityrisk).Substancescontainingonlysuchmicro-organismsarenotconsideredinfectioussubstancesforthepurposesoftheseprovisions.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/1082.2.62.1.4.Infectioussubstancesaffectinganimalsonly(groupI2in2.2.62.1.2)andofriskgroup2areassignedtopackinggroupII.2.2.62.1.5.Biologicalproductsarethoseproductsderivedfromlivingorganisms,thataremanufacturedanddistributedinaccordancewiththerequirementsofnationalgovernmentalauthoritieswhichmayhavespeciallicensingrequirements,andareusedeitherforprevention,treatment,ordiagnosisofdiseaseinhumansoranimals,orfordevelopment,experimentalorinvestigationalpurposesrelatedthereto.Theyinclude,butarenotlimitedto,finishedorunfinishedproductssuchasvaccinesanddiagnosticproducts.ForthepurposesofthisDirective,biologicalproductsaredividedintothefollowinggroups:(a)thosewhichcontainpathogensinriskgroup1;thosewhichcontainpathogensundersuchconditionsthattheirabilitytoproducediseaseisverylowtonone;andthoseknownnottocontainpathogens.SubstancesinthisgrouparenotconsideredinfectioussubstancesforthepurposesofthisDirective;(b)thosemanufacturedandpackagedinaccordancewiththerequirementsofnationalgovernmentalhealthauthoritiesandcarriedforthepurposesoffinalpackagingordistribution,anduseforpersonalhealthcarebymedicalprofessionalsorindividuals.SubstancesinthisgrouparenotsubjecttotheregulationsapplicabletoClass6.2;(c)thoseknownorreasonablyexpectedtocontainpathogensinriskgroups2,3,or4andwhichdonotmeetthecriteriaofparagraph(b).SubstancesinthisgroupshallbeclassifiedinClass6.2underUNNo2814or2900,asappropriate.NOTESomelicensedbiologicalproductsmaypresentabiohazardincertainpartsoftheworldonly.Inthatcasecompetentauthoritiesmayrequirethesebiologicalproductstocomplywiththerequirementsforinfectioussubstancesormayimposeotherrestrictions.2.2.62.1.6.Diagnosticspecimensareanyhumanoranimalmaterialincluding,butnotlimitedto,excreta,secreta,bloodanditscomponents,tissueandtissuefluidsbeingcarriedforpurposesofdiagnosisorresearch,butexcludingliveinfectedanimals.ForthepurposesofthisDirective,diagnosticspecimensaredividedintothefollowinggroups:(a)thoseknownorreasonablyexpectedtocontainpathogensinriskgroups2,3or4andthosewherearelativelylowprobabilityexiststhatpathogensofriskgroup4arepresent.SuchsubstancesshallbeclassifiedinClass6.2underUNNo2814or2900,asappropriate.Specimenscarriedforthepurposesofinitialorconfirmatorytestingforthepresenceofpathogensfallwithinthisgroup;(b)thosewherearelativelylowprobabilityexiststhatpathogensofriskgroup2or3arepresent.SuchsubstancesshallbeclassifiedinClass6.2underUNNo2814or2900,asappropriate.Specimenscarriedforthepurposeofinitialdiagnosisforotherthanthepresenceofpathogensorspecimenscarriedforroutinescreeningfallwithinthisgroup;(c)thoseknownnottocontainpathogens.SuchsubstancesarenotconsideredassubstancesofClass6.2.2.2.62.1.7.Geneticallymodifiedmicro-organismsandorganisms(1)aremicro-organismsandorganismsinwhichthegeneticmaterialhasbeendeliberatelyalteredbytechnicalmethodsorbymeansthatcannotoccurnaturallyinnature.ForthepurposesofthisDirective,geneticallymodifiedmicro-organismsandorganismsaredividedintothefollowinggroups:(a)geneticallymodifiedmicro-organismswhichmeetthedefinitionofaninfectioussubstancegivenin2.2.62.1.1shallbeclassifiedinClass6.2andassignedtoUNNo2814or2900;(b)geneticallymodifiedorganisms,whichareknownorsuspectedtobedangeroustohumans,animalsortheenvironment,shallbecarriedinaccordancewithconditionsspecifiedbythecompetentauthorityofthecountryoforigin;(c)animalswhichcontainorarecontaminatedwithgeneticallymodifiedmicro-organismsandorganismsthatmeetthedefinitionofaninfectioussubstanceshallbecarriedinaccordancewithconditionsspecifiedbythecompetentauthorityofthecountryoforigin;OfficialJournaloftheEuropeanUnionEN26.1.2004L18/109(1)SeealsoDirective90/219/EEC(OJL117,8.5.1990,p.1).(d)exceptwhenauthorisedforunconditionalusebytheGovernmentsofthecountriesoforigin,transitanddestination,geneticallymodifiedmicro-organismswhichdonotmeetthedefinitionofinfectioussubstancesbutwhicharecapableofalteringanimals,plantsormicrobiologicalsubstancesinawaynotnormallytheresultofnaturalreproductionshallbeclassifiedinClass9andassignedtoUNNo3245.NOTEGeneticallymodifiedmicro-organismswhichareinfectiouswithinthemeaningofthisClassshallnotbeassignedtoUNNo3291.2.2.62.1.8.Diagnosticspecimensreferredtoin2.2.62.1.6(b)neednotmeettherequirementsforinfectioussubstanceswhenthefollowingconditionsaremet:a)—theprimaryreceptacle(s)donotcontainmorethan100ml,—theouterpackagingdoesnotcontainmorethan500ml,—theprimaryreceptacle(s)areleakproof;and—thepackagingincludes:(i)aninnerpackagingcomprising:—watertightprimaryreceptacle(s),—awatertightsecondarypackaging,—absorbentmaterialinsufficientquantitytoabsorbtheentirecontentsplacedbetweentheprimaryreceptacle(s)andthesecondarypackaging;ifseveralprimaryreceptaclesareplacedinasinglesecondarypackaging,theyshallbeindividuallywrappedsoastopreventcontactbetweenthem,(ii)anouterpackagingofadequatestrengthforitscapacity,massandintendeduse,andwithminimumexternaldimensionsof100mm;(b)thepackagingscomplywithENstandard829:1996.2.2.62.1.9.Wastesarewastesderivedfromthemedicaltreatmentofanimalsorhumansorfrombio-researchwherethereisarelativelylowprobabilitythatinfectioussubstancesarepresent.TheyshallbeassignedtoUNNo3291.WastescontaininginfectioussubstanceswhichcanbespecifiedshallbeassignedtoUNNo2814or2900accordingtotheirdegreeofdanger(see2.2.62.1.3).Decontaminatedwasteswhichpreviouslycontainedinfectioussubstancesareconsiderednon-dangerousunlessthecriteriaofanotherclassaremet.2.2.62.1.10.ClinicalwastesassignedtoUNNo3291areassignedtopackinggroupII.2.2.62.1.11.Forthecarriageofsubstancesofthisclass,themaintenanceofaspecifiedtemperaturemaybenecessary.2.2.62.2.SubstancesnotacceptedforcarriageLivevertebrateorinvertebrateanimalsshallnotbeusedtocarryaninfectiousagentunlesstheagentcannotbecarriedbyanyothermeans.Suchanimalsshallbepacked,marked,indicated,andcarriedinaccordancewiththerelevantregulationsgoverningthecarriageofanimals(1).2.2.62.3.ListofcollectiveentriesOfficialJournaloftheEuropeanUnionEN26.1.2004L18/110(1)Suchregulationsarecontainedin,e.g.Directive91/628/EEC(OJL340,11.12.1991,p.17)andintheRecommendationsoftheCouncilofEurope(MinisterialCommittee)onthecarriageofcertainanimalspecies.2.2.7.Class7Radioactivematerial2.2.7.1.DefinitionofClass72.2.7.1.1.Radioactivematerialmeansanymaterialcontainingradionuclideswhereboththeactivityconcentrationandthetotalactivityintheconsignmentexceedthevaluesspecifiedin2.2.7.7.2.1to2.2.7.7.2.6.2.2.7.1.2.ThefollowingradioactivematerialsarenotincludedinClass7forthepurposesofthisDirective:(a)radioactivematerialthatisanintegralpartofthemeansoftransport;(b)radioactivematerialmovedwithinanestablishmentwhichissubjecttoappropriatesafetyregulationsinforceintheestablishmentandwherethemovementdoesnotinvolvepublicroadsorrailways;(c)radioactivematerialimplantedorincorporatedintoapersonorliveanimalfordiagnosisortreatment;(d)radioactivematerialinconsumerproductswhichhavereceivedregulatoryapproval,followingtheirsaletotheenduser;(e)naturalmaterialandorescontainingnaturallyoccurringradionuclideswhicharenotintendedtobeprocessedforuseoftheseradionuclidesprovidedtheactivityconcentrationofthematerialdoesnotexceed10timesthevaluesspecifiedin2.2.7.7.2.2.2.7.2.DefinitionsA1andA2A1meanstheactivityvalueofspecialformradioactivematerialwhichislistedinTable2.2.7.7.2.1orderivedin2.2.7.7.2andisusedtodeterminetheactivitylimitsfortherequirementsofthisDirective.A2meanstheactivityvalueofradioactivematerial,otherthanspecialformradioactivematerial,whichislistedinTable2.2.7.7.2.1orderivedin2.2.7.7.2andisusedtodeterminetheactivitylimitsfortherequirementsofthisDirective.Specificactivityofaradionuclidemeanstheactivityperunitofmassofthatradionuclide.Specificactivityofamaterialmeanstheactivitybyunitofmassorvolumeofthematerialinwhichtheradionuclidesareonthewholeuniformlydistributed.ApprovalMultilateralapprovalmeansapprovalbytherelevantcompetentauthoritybothofthecountryoforiginofthedesignorshipmentandofeachcountrythroughorintowhichtheconsignmentistobecarried.Unilateralapprovalmeansanapprovalofadesignwhichisrequiredtobegivenbythecompetentauthorityofthecountryoforiginofthedesignonly.IfthecountryoforiginisnotaMemberState,theapprovalshallrequirevalidationbythecompetentauthorityofthefirstcountryMemberStatereachedbytheconsignment(see6.4.22.6).Confinementsystemmeanstheassemblyoffissilematerialandpackagingcomponentsspecifiedbythedesignerandagreedtobythecompetentauthorityasintendedtopreservecriticalitysafety.Containmentsystemmeanstheassemblyofcomponentsofthepackagingspecifiedbythedesignerasintendedtoretaintheradioactivematerialduringcarriage.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/111ContaminationContaminationmeansthepresenceofaradioactivesubstanceonasurfaceinquantitiesinexcessof0,4Bq/cm2forbetaandgammaemittersandlowtoxicityalphaemitters,or0,04Bq/cm2forallotheralphaemitters.Non-fixedcontaminationmeanscontaminationthatcanberemovedfromasurfaceduringroutineconditionsofcarriage.Fixedcontaminationmeanscontaminationotherthannon-fixedcontamination.Criticalitysafetyindex(CSI)assignedtoapackage,overpackorcontainercontainingfissilematerialmeansanumberwhichisusedtoprovidecontrolovertheaccumulationofpackages,overpacksorcontainerscontainingfissilematerial.Designmeansthedescriptionofspecialformradioactivematerial,lowdispersibleradioactivematerial,packageorpackagingwhichenablessuchanitemtobefullyidentified.Thedescriptionmayincludespecifications,engineeringdrawings,reportsdemonstratingcompliancewithregulatoryrequirements,andotherrelevantdocumentation.Exclusiveusemeansthesoleuse,byasingleconsignor,ofavehicleorofalargecontainer,inrespectofwhichallinitial,intermediateandfinalloadingandunloadingiscarriedoutinaccordancewiththedirectionsoftheconsignororconsignee.Fissilematerialmeansuranium-233,uranium-235,plutonium-239,plutonium-241,oranycombinationoftheseradionuclides.Exceptedfromthisdefinitionis:(a)naturaluraniumordepleteduraniumwhichisunirradiated,and(b)naturaluraniumordepleteduraniumwhichhasbeenirradiatedinthermalreactorsonly.Largecontainermeansacontainerwhichisnotasmallcontaineraccordingtothedefinitionsofthissubsection.Lowdispersibleradioactivematerialmeanseitherasolidradioactivematerialorasolidradioactivematerialinasealedcapsule,thathaslimiteddispersibilityandisnotinpowderform.NOTELowdispersibleradioactivematerialmaybecarriedbyairintypeB(U)orB(M)packagesinquantitiesasauthorisedforthepackagedesignasspecifiedinthecertificateofapproval.Thisdefinitionisincludedheresincesuchpackagescarryinglowdispersibleradioactivematerialmayalsobecarriedbyroad.Lowspecificactivity(LSA)material,see2.2.7.3.Lowtoxicityalphaemittersare:naturaluranium;depleteduranium;naturalthorium;uranium-235oruranium-238;thorium-232;thorium-228andthorium-230whencontainedinoresorphysicalandchemicalconcentrates;oralphaemitterswithahalf-lifeoflessthan10days.Maximumnormaloperatingpressuremeansthemaximumpressureaboveatmosphericpressureatmeansea-levelthatwoulddevelopinthecontainmentsysteminaperiodofoneyearundertheconditionsoftemperatureandsolarradiationcorrespondingtoenvironmentalconditionsintheabsenceofventing,externalcoolingbyanancillarysystem,oroperationalcontrolsduringcarriage.Packageinthecaseofradioactivematerialmeansthepackagingwithitsradioactivecontentsaspresentedforcarriage.ThetypesofpackagescoveredbythisDirective,whicharesubjecttotheactivitylimitsandmaterialrestrictionsof2.2.7.7andmeetthecorrespondingrequirements,are:(a)exceptedpackage;(b)industrialpackagetype1(typeIP-1);(c)industrialpackagetype2(typeIP-2);(d)industrialpackagetype3(typeIP-3);(e)typeApackage;(f)typeB(U)package;(g)typeB(M)package;(h)typeCpackage.Packagescontainingfissilematerialoruraniumhexafluoridearesubjecttoadditionalrequirements(see2.2.7.7.1.7and2.2.7.7.1.8).NOTE:For‘packages’forotherdangerousgoodsseedefinitionsunder1.2.1.Packaginginthecaseofradioactivematerialmeanstheassemblyofcomponentsnecessarytoenclosetheradioactivecontentscompletely.Itmay,inparticular,consistofoneormorereceptacles,absorbentmaterials,spacingstructures,radiationshieldingandserviceequipmentforfilling,emptying,ventingandpressurerelief;devicesforcooling,absorbingmechanicalshocks,handlingandtie-down,thermalinsulation;andservicedevicesintegraltothepackage.Thepackagingmaybeabox,drumorsimilarreceptacle,ormayalsobeacontainer,tankorintermediatebulkcontainer(IBC).NOTE:For‘packagings’forotherdangerousgoodsseedefinitionsunder1.2.1.Radiationlevelmeansthecorrespondingdoserateexpressedinmillisievertsperhour.Radioactivecontentsmeantheradioactivematerialtogetherwithanycontaminatedoractivatedsolids,liquids,andgaseswithinthepackaging.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/112Shipmentmeansthespecificmovementofaconsignmentfromorigintodestination.Smallcontainermeansacontainerwhichhaseitheranoverallouterdimensionlessthan1,5m,oraninternalvolumeofnotmorethan3m3.Specialformradioactivematerial,see2.2.7.4.1.Specificactivityofaradionuclidemeanstheactivityperunitmassofthatnuclide.Thespecificactivityofamaterialshallmeantheactivityperunitmassorvolumeofthematerialinwhichtheradionuclidesareessentiallyuniformlydistributed.Surfacecontaminatedobject(SCO),see2.2.7.5.Transportindex(TI)assignedtoapackage,overpackorcontainer,ortounpackagedLSA-IorSCO-I,meansanumberwhichisusedtoprovidecontroloverradiationexposure.Unirradiatedthoriummeansthoriumcontainingnotmorethan10-7gofuranium-233pergramofthorium-232.Unirradiateduraniummeansuraniumcontainingnotmorethan2×103Bqofplutoniumpergramofuranium-235,notmorethan9×106Bqoffissionproductspergramofuranium-235andnotmorethan5×10-3gofuranium-236pergramofuranium-235.Uranium-natural,depleted,enrichedmeansthefollowing:Naturaluraniummeanschemicallyseparateduraniumcontainingthenaturallyoccurringdistributionofuraniumisotopes(approxi-mately99,28%uranium-238,and0,72%uranium-235bymass).Depleteduraniummeansuraniumcontainingalessermasspercentageofuranium-235thaninnaturaluranium.Enricheduraniummeansuraniumcontainingagreatermasspercentageofuranium-235than0,72%.Inallcases,averysmallmasspercentageofuranium-234ispresent.2.2.7.3.Lowspecificactivity(LSA)material,determinationofgroups2.2.7.3.1.Radioactivematerialwhichbyitsnaturehasalimitedspecificactivity,orradioactivematerialforwhichlimitsofestimatedaveragespecificactivityapply,istermedlowspecificactivityorLSAmaterial.ExternalshieldingmaterialssurroundingtheLSAmaterialshallnotbeconsideredindeterminingtheestimatedaveragespecificactivity.2.2.7.3.2.LSAmaterialshallbeinoneofthreegroups:(a)LSA-I(i)uraniumandthoriumoresandconcentratesofsuchores,andotherorescontainingnaturallyoccurringradionuclideswhichareintendedtobeprocessedfortheuseoftheseradionuclides;(ii)solidunirradiatednaturaluraniumordepleteduraniumornaturalthoriumortheirsolidorliquidcompoundsormixtures;(iii)radioactivematerialforwhichtheA2valueisunlimited,excludingfissilematerialinquantitiesnotexceptedunder6.4.11.2;or(iv)otherradioactivematerialinwhichtheactivityisdistributedthroughoutandtheestimatedaveragespecificactivitydoesnotexceed30timesthevaluesforactivityconcentrationspecifiedin2.2.7.7.2.1to2.2.7.7.2.6,excludingfissilematerialinquantitiesnotexceptedunder6.4.11.2.(b)LSA-II(i)waterwithtritiumconcentrationupto0,8TBq/l;or(ii)othermaterialinwhichtheactivityisdistributedthroughoutandtheestimatedaveragespecificactivitydoesnotexceed10-4A2/gforsolidsandgases,and10-5A2/gforliquids.(c)LSA-III—Solids(e.g.consolidatedwastes,activatedmaterials),excludingpowders,inwhich:(i)theradioactivematerialisdistributedthroughoutasolidoracollectionofsolidobjects,orisessentiallyuniformlydistributedinasolidcompactbindingagent(suchasconcrete,bitumen,ceramic,etc.);(ii)theradioactivematerialisrelativelyinsoluble,oritisintrinsicallycontainedinarelativelyinsolublematrix,sothat,evenunderlossofpackaging,thelossofradioactivematerialperpackagebyleachingwhenplacedinwaterforsevendayswouldnotexceed0,1A2;and(iii)theestimatedaveragespecificactivityofthesolid,excludinganyshieldingmaterial,doesnotexceed2×10-3A2/g.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/1132.2.7.3.3.LSA-IIImaterialshallbeasolidofsuchanaturethatiftheentirecontentsofapackageweresubjectedtothetestspecifiedin2.2.7.3.4theactivityinthewaterwouldnotexceed0,1A2.2.2.7.3.4.LSA-IIImaterialshallbetestedasfollows:asolidmaterialsamplerepresentingtheentirecontentsofthepackageshallbeimmersedforsevendaysinwateratambienttemperature.Thevolumeofwatertobeusedinthetestshallbesufficienttoensurethatattheendofthesevendaytestperiodthefreevolumeoftheunabsorbedandunreactedwaterremainingshallbeatleast10%ofthevolumeofthesolidtestsampleitself.ThewatershallhaveaninitialpHof6-8andamaximumconductivityof1mS/mat20°C.Thetotalactivityofthefreevolumeofwatershallbemeasuredfollowingthesevendayimmersionofthetestsample.2.2.7.3.5.Demonstrationofcompliancewiththeperformancestandardsin2.2.7.3.4shallbeinaccordancewith6.4.12.1and6.4.12.2.2.2.7.4.Requirementsforspecialformradioactivematerial2.2.7.4.1.Specialformradioactivematerialmeanseither:(a)anindispersiblesolidradioactivematerial;or(b)asealedcapsulecontainingradioactivematerialthatshallbesomanufacturedthatitcanbeopenedonlybydestroyingthecapsule.Specialformradioactivematerialshallhaveatleastonedimensionnotlessthan5mm.2.2.7.4.2.Specialformradioactivematerialshallbeofsuchanatureorshallbesodesignedthatifitissubjectedtothetestsspecifiedin2.2.7.4.4to2.2.7.4.8,itshallmeetthefollowingrequirements:(a)itwouldnotbreakorshatterundertheimpact,percussionandbendingtests2.2.7.4.5(a)(b)(c),2.2.7.4.6(a)asapplicable;(b)itwouldnotmeltordisperseintheapplicableheattest2.2.7.4.5(d)or2.2.7.4.6(b)asapplicable;and(c)theactivityinthewaterfromtheleachingtestsspecifiedin2.2.7.4.7and2.2.7.4.8wouldnotexceed2kBq;oralternativelyforsealedsources,theleakagerateforthevolumetricleakageassessmenttestspecifiedinISO9978:1992‘Radiationprotection—sealedradioactivesources—leakagetestmethods’,wouldnotexceedtheapplicableacceptancethresholdacceptabletothecompetentauthority.2.2.7.4.3.Demonstrationofcompliancewiththeperformancestandardsin2.2.7.4.2shallbeinaccordancewith6.4.12.1and6.4.12.2.2.2.7.4.4.Specimensthatcompriseorsimulatespecialformradioactivematerialshallbesubjectedtotheimpacttest,thepercussiontest,thebendingtest,andtheheattestspecifiedin2.2.7.4.5oralternativetestsasauthorisedin2.2.7.4.6.Adifferentspecimenmaybeusedforeachofthetests.Followingeachtest,aleachingassessmentorvolumetricleakagetestshallbeperformedonthespecimenbyamethodnolesssensitivethanthemethodsgivenin2.2.7.4.7forindispersiblesolidmaterialor2.2.7.4.8forencapsulatedmaterial.2.2.7.4.5.Therelevanttestmethodsare:(a)impacttest:thespecimenshalldropontothetargetfromaheightof9m.Thetargetshallbeasdefinedin6.4.14;(b)percussiontest:thespecimenshallbeplacedonasheetofleadwhichissupportedbyasmoothsolidsurfaceandstruckbytheflatfaceofamildsteelbarsoastocauseanimpactequivalenttothatresultingfromafreedropof1,4kgthrough1m.Thelowerpartofthebarshallbe25mmindiameterwiththeedgesroundedofftoaradiusof(3,0±0,3)mm.Thelead,ofhardnessnumber3,5to4,5ontheVickersscaleandnotmorethan25mmthick,shallcoveranareagreaterthanthatcoveredbythespecimen.Afreshsurfaceofleadshallbeusedforeachimpact.Thebarshallstrikethespecimensoastocausemaximumdamage;(c)bendingtest:thetestshallapplyonlytolong,slendersourceswithbothaminimumlengthof10cmandalengthtominimumwidthratioofnotlessthan10.Thespecimenshallberigidlyclampedinahorizontalpositionsothatonehalfofitslengthprotrudesfromthefaceoftheclamp.Theorientationofthespecimenshallbesuchthatthespecimenwillsuffermaximumdamagewhenitsfreeendisstruckbytheflatfaceofasteelbar.Thebarshallstrikethespecimensoastocauseanimpactequivalenttothatresultingfromafreeverticaldropof1,4kgthrough1m.Thelowerpartofthebarshallbe25mmindiameterwiththeedgesroundedofftoaradiusof(3,0±0,3)mm;OfficialJournaloftheEuropeanUnionEN26.1.2004L18/114(d)heattest:thespecimenshallbeheatedinairtoatemperatureof800°Candheldatthattemperatureforaperiodof10minutesandshallthenbeallowedtocool.2.2.7.4.6.Specimensthatcompriseorsimulateradioactivematerialenclosedinasealedcapsulemaybeexceptedfrom:(a)thetestsprescribedin2.2.7.4.5(a)and2.2.7.4.5(b)providedthemassofthespecialformradioactivematerialislessthan200gandtheyarealternativelysubjectedtotheClass4impacttestprescribedinISO2919:1980‘Radiationprotection—sealedradioactivesources—generalrequirementsandclassification’;and(b)thetestprescribedin2.2.7.4.5(d)providedtheyarealternativelysubjectedtotheClass6temperaturetestspecifiedinISO2919:19801980‘Radiationprotection—sealedradioactivesources—generalrequirementsandclassification’.2.2.7.4.7.Forspecimenswhichcompriseorsimulateindispersiblesolidmaterial,aleachingassessmentshallbeperformedasfollows:(a)thespecimenshallbeimmersedforsevendaysinwateratambienttemperature.Thevolumeofwatertobeusedinthetestshallbesufficienttoensurethatattheendofthesevendaytestperiodthefreevolumeoftheunabsorbedandunreactedwaterremainingshallbeatleast10%ofthevolumeofthesolidtestsampleitself.ThewatershallhaveaninitialpHof6-8andamaximumconductivityof1mS/mat20°C;(b)thewaterwithspecimenshallthenbeheatedtoatemperatureof(50±5)°Candmaintainedatthistemperatureforfourhours;(c)theactivityofthewatershallthenbedetermined;(d)thespecimenshallthenbekeptforatleastsevendaysinstillairatnotlessthan30°Candrelativehumiditynotlessthan90%;(e)thespecimenshallthenbeimmersedinwaterofthesamespecificationasinparagraph(a)andthewaterwiththespecimenheatedto(50±5)°Candmaintainedatthistemperatureforfourhours;(f)theactivityofthewatershallthenbedetermined.2.2.7.4.8.Forspecimenswhichcompriseorsimulateradioactivematerialenclosedinasealedcapsule,eitheraleachingassessmentoravolumetricleakageassessmentshallbeperformedasfollows:(a)theleachingassessmentshallconsistofthefollowingsteps:(i)thespecimenshallbeimmersedinwateratambienttemperature.ThewatershallhaveaninitialpHof6-8withamaximumconductivityof1mS/mat20°C;(ii)thewaterandspecimenshallbeheatedtoatemperatureof(50±5)°Candmaintainedatthistemperatureforfourhours;(iii)theactivityofthewatershallthenbedetermined;(iv)thespecimenshallthenbekeptforatleastsevendaysinstillairatnotlessthan30°Candrelativehumidityofnotlessthan90%;(v)theprocessin(i),(ii)and(iii)shallberepeated;(b)thealternativevolumetricleakageassessmentshallcompriseanyofthetestsprescribedinISO9978:1992‘Radiationprotection—sealedradioactivesources—Leakagetestmethods’,whichareacceptabletothecompetentauthority.2.2.7.5.Surfacecontaminatedobject(SCO),determinationofgroupsSurfacecontaminatedobject(SCO)meansasolidobjectwhichisnotitselfradioactivebutwhichhasradioactivematerialdistributedonitssurfaces.SCOisclassifiedinoneoftwogroups:(a)SCO-I:asolidobjectonwhich:(i)thenon-fixedcontaminationontheaccessiblesurfaceaveragedover300cm2(ortheareaofthesurfaceiflessthan300cm2)doesnotexceed4Bq/cm2forbetaandgammaemittersandlowtoxicityalphaemitters,or0,4Bq/cm2forallotheralphaemitters;and(ii)thefixedcontaminationontheaccessiblesurfaceaveragedover300cm2(ortheareaofthesurfaceiflessthan300cm2)doesnotexceed4×104Bq/cm2forbetaandgammaemittersandlowtoxicityalphaemitters,or4×103Bq/cm2forallotheralphaemitters;andOfficialJournaloftheEuropeanUnionEN26.1.2004L18/115(iii)thenon-fixedcontaminationplusthefixedcontaminationontheinaccessiblesurfaceaveragedover300cm2(ortheareaofthesurfaceiflessthan300cm2)doesnotexceed4×104Bq/cm2forbetaandgammaemittersandlowtoxicityalphaemitters,or4×103Bq/cm2forallotheralphaemitters;(b)SCO-II:asolidobjectonwhicheitherthefixedornon-fixedcontaminationonthesurfaceexceedstheapplicablelimitsspecifiedforSCO-Iin(a)aboveandonwhich:(i)thenon-fixedcontaminationontheaccessiblesurfaceaveragedover300cm2(ortheareaofthesurfaceiflessthan300cm2)doesnotexceed400Bq/cm2forbetaandgammaemittersandlowtoxicityalphaemitters,or40Bq/cm2forallotheralphaemitters;and(ii)thefixedcontaminationontheaccessiblesurface,averagedover300cm2(ortheareaofthesurfaceiflessthan300cm2)doesnotexceed8×105Bq/cm2forbetaandgammaemittersandlowtoxicityalphaemitters,or8×104Bq/cm2forallotheralphaemitters;and(iii)thenon-fixedcontaminationplusthefixedcontaminationontheinaccessiblesurfaceaveragedover300cm2(ortheareaofthesurfaceiflessthan300cm2)doesnotexceed8×105Bq/cm2forbetaandgammaemittersandlowtoxicityalphaemitters,or8×104Bq/cm2forallotheralphaemitters.2.2.7.6.Determinationoftransportindex(TI)andcriticalitysafetyindex(CSI)2.2.7.6.1.Determinationoftransportindex2.2.7.6.1.1.Thetransportindex(TI)forapackage,overpackorcontainer,orforunpackagedLSA-IorSCO-I,shallbethenumberderivedinaccordancewiththefollowingprocedure:(a)determinethemaximumradiationlevelinunitsofmillisievertsperhour(mSv/h)atadistanceof1mfromtheexternalsurfacesofthepackage,overpack,container,orunpackagedLSA-IandSCO-I.Thevaluedeterminedshallbemultipliedby100andtheresultingnumberisthetransportindex.Foruraniumandthoriumoresandtheirconcentrates,themaximumradiationlevelatanypoint1mfromtheexternalsurfaceoftheloadmaybetakenas:0,4mSv/hfororesandphysicalconcentratesofuraniumandthorium;0,3mSv/hforchemicalconcentratesofthorium;0,02mSv/hforchemicalconcentratesofuranium,otherthanuraniumhexafluoride;(b)fortanks,containersandunpackagedLSA-IandSCO-I,thevaluedeterminedinstep(a)aboveshallbemultipliedbytheappropriatefactorfromTable2.2.7.6.1.1;(c)thevalueobtainedinsteps(a)and(b)aboveshallberoundeduptothefirstdecimalplace(e.g.1,13becomes1,2),exceptthatavalueof0,05orlessmaybeconsideredaszero.Table2.2.7.6.1.1MULTIPLICATIONFACTORSFORLARGEDIMENSIONLOADSSizeofload(a)Multiplicationfactorsizeofload≤1m211m2<sizeofload≤5m225m2<sizeofload≤20m2320m2<sizeofload10(a)Largestcross-sectionalareaoftheloadbeingmeasured.2.2.7.6.1.2.Thetransportindexforeachoverpack,container,vehicleshallbedeterminedaseitherthesumoftheTIsofallthepackagescontained,orbydirectmeasurementofradiationlevel,exceptinthecaseofnon-rigidoverpacksforwhichthetransportindexshallbedeterminedonlyasthesumoftheTIsofallthepackages.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/1162.2.7.6.2.Determinationofcriticalitysafetyindex(CSI)2.2.7.6.2.1.Thecriticalitysafetyindex(CSI)forpackagescontainingfissilematerialshallbeobtainedbydividingthenumber50bythesmallerofthetwovaluesofNderivedin6.4.11.11and6.4.11.12(i.e.CSI=50/N).Thevalueofthecriticalitysafetyindexmaybezero,providedthatanunlimitednumberofpackagesissubcritical(i.e.Niseffectivelyequaltoinfinityinbothcases).2.2.7.6.2.2.ThecriticalitysafetyindexforeachconsignmentshallbedeterminedasthesumoftheCSIsofallthepackagescontainedinthatconsignment.2.2.7.7.Activitylimitsandmaterialrestrictions2.2.7.7.1.Contentslimitsforpackages2.2.7.7.1.1.GeneralThequantityofradioactivematerialinapackageshallnotexceedtherelevantlimitsforthepackagetypeasspecifiedbelow.2.2.7.7.1.2.Exceptedpackages2.2.7.7.1.2.1.Forradioactivematerialotherthanarticlesmanufacturedofnaturaluranium,depleteduraniumornaturalthorium,anexceptedpackageshallnotcontainactivitiesgreaterthanthefollowing:(a)wheretheradioactivematerialisenclosedinorisincludedasacomponentpartofaninstrumentorothermanufacturedarticle,suchasaclockorelectronicapparatus,thelimitsspecifiedincolumns2and3ofTable2.2.7.7.1.2.1foreachindividualitemandeachpackage,respectively;and(b)wheretheradioactivematerialisnotsoenclosedinorisnotincludedasacomponentofaninstrumentorothermanufacturedarticle,thepackagelimitsspecifiedincolumn4ofTable2.2.7.7.1.2.1.Table2.2.7.7.1.2.1ACTIVITYLIMITSFOREXCEPTEDPACKAGESPhysicalstateofcontentsInstrumentsorarticleMaterialsPackagelimitsItemlimits(a)Packagelimits(a)Solids—specialform10-2A1A110-3A1—otherform10-2A2A210-3A2Liquids10-3A210-1A210-4A2Gases—tritium2×10-2A22×10-1A22×10-2A2—specialform10-3A110-2A110-3A1—otherforms10-3A210-2A210-3A2(a)Formixturesofradionuclides,see2.2.7.7.2.4to2.2.7.7.2.6.2.2.7.7.1.2.2.Forarticlesmanufacturedofnaturaluranium,depleteduraniumornaturalthorium,anexceptedpackagemaycontainanyquantityofsuchmaterialprovidedthattheoutersurfaceoftheuraniumorthoriumisenclosedinaninactivesheathmadeofmetalorsomeothersubstantialmaterial.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/1172.2.7.7.1.3.IndustrialpackagesTheradioactivecontentsinasinglepackageofLSAmaterialorinasinglepackageofSCOshallbesorestrictedthattheradiationlevelspecifiedin4.1.9.2.1shallnotbeexceeded,andtheactivityinasinglepackageshallalsobesorestrictedthattheactivitylimitsforavehiclespecifiedin7.5.11,CV33(2)shallnotbeexceeded.2.2.7.7.1.4.TypeApackages2.2.7.7.1.4.1.TypeApackagesshallnotcontainactivitiesgreaterthanthefollowing:(a)forspecialformradioactivematerial—A1;or(b)forallotherradioactivematerial—A2.2.2.7.7.1.4.2.Formixturesofradionuclideswhoseidentitiesandrespectiveactivitiesareknown,thefollowingconditionshallapplytotheradioactivecontentsofaTypeApackage:whereB(i)istheactivityofradionuclideiasspecialformradioactivematerialandA1(i)istheA1valueforradionuclidei;andC(j)istheactivityofradionuclidejasotherthanspecialformradioactivematerialandA2(j)istheA2valueforradionuclidej.2.2.7.7.1.5.TypeB(U)andTypeB(M)packages2.2.7.7.1.5.1.TypeB(U)andTypeB(M)packagesshallnotcontain:(a)activitiesgreaterthanthoseauthorisedforthepackagedesign;(b)radionuclidesdifferentfromthoseauthorisedforthepackagedesign;or(c)contentsinaform,oraphysicalorchemicalstatedifferentfromthoseauthorisedforthepackagedesign;asspecifiedintheircertificatesofapproval.2.2.7.7.1.6.TypeCpackagesNOTETypeCpackagesmaybetransportedbyaircarryingradioactivematerialinquantitiesexceedingeither3000A1or100000A2,whicheveristhelowerforspecialformradioactivematerial,or3000A2forallotherradioactivematerial.WhilstTypeCpackagesarenotrequiredforcarriageofradioactivematerialbyroadinsuchquantities(TypeB(U)orTypeB(M)packagessuffice),thefollowingrequirementsarepresentedsincesuchpackagesmayalsobecarriedbyroad.TypeCpackagesshallnotcontain:(a)activitiesgreaterthanthoseauthorisedforthepackagedesign;(b)radionuclidesdifferentfromthoseauthorisedforthepackagedesign;or(c)contentsinaform,orphysicalorchemicalstatedifferentfromthoseauthorisedforthepackagedesign;asspecifiedintheircertificatesofapproval.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/1182.2.7.7.1.7.PackagescontainingfissilematerialPackagescontainingfissilematerialshallnotcontain:(a)amassoffissilematerialdifferentfromthatauthorisedforthepackagedesign;(b)anyradionuclideorfissilematerialdifferentfromthoseauthorisedforthepackagedesign;or(c)contentsinaformorphysicalorchemicalstate,orinaspatialarrangement,differentfromthoseauthorisedforthepackagedesign;asspecifiedintheircertificatesofapprovalwhereappropriate.2.2.7.7.1.8.PackagescontaininguraniumhexafluorideThemassofuraniumhexafluorideinapackageshallnotexceedavaluethatwouldleadtoanullagesmallerthan5%atthemaximumtemperatureofthepackageasspecifiedfortheplantsystemswherethepackageshallbeused.Theuraniumhexafluorideshallbeinsolidformandtheinternalpressureofthepackageshallbebelowatmosphericpressurewhenpresentedforcarriage.2.2.7.7.2.Activitylevels2.2.7.7.2.1.ThefollowingbasicvaluesforindividualradionuclidesaregiveninTable2.2.7.7.2.1:(a)A1andA2inTBq;(b)activityconcentrationforexemptmaterialinBq/g;and(c)activitylimitsforexemptconsignmentsinBq.Table2.2.7.7.2.1RadionuclideA1A2ActivityconcentrationforexemptmaterialActivitylimitforanexemptconsignment(atomicnumber)(TBq)(TBq)(Bq/g)(Bq)Actinium(89)Ac-225(a)8Η10-16Η10-31Η1011Η104Ac-227(a)9Η10-19Η10-51Η10-11Η103Ac-2286Η10-15Η10-11Η1011Η106Silver(47)Ag-1052Η1002Η1001Η1021Η106Ag-108m(a)7Η10-17Η10-11Η101(b)1Η106(b)Ag-110m(a)4Η10-14Η10-11Η1011Η106Ag-1112Η1006Η10-11Η1031Η106Aluminium(13)Al-261Η10-11×10-11×1011×105Americium(95)Am-2411×1011×10-31×1001×104Am-242m(a)1×1011×10-31×100(b)1×104(b)Am-243(a)5×1001×10-31×100(b)1×103(b)OfficialJournaloftheEuropeanUnionEN26.1.2004L18/119RadionuclideA1A2ActivityconcentrationforexemptmaterialActivitylimitforanexemptconsignment(atomicnumber)(TBq)(TBq)(Bq/g)(Bq)Argon(18)Ar-374×1014×1011×1061×108Ar-392×1014×1011×1071×104Ar-413×10-13×10-11×1021×109Arsenic(33)As-723×10-13×10-11×1011×105As-734×1014×1011×1031×107As-741×1009×10-11×1011×106As-763×10-13×10-11×1021×105As-772×1017×10-11×1031×106Astatine(85)At-211(a)2×1015×10-11×1031×107Gold(79)Au-1937×1002×1001×1021×107Au-1941×1001×1001×1011×106Au-1951×1016×1001×1021×107Au-1981×1006×10-11×1021×106Au-1991×1016×10-11×1021×106Barium(56)Ba-131(a)2×1002×1001×1021×106Ba-1333×1003×1001×1021×106Ba-133m2×1016×10-11×1021×106Ba-140(a)5×10-13×10-11×101(b)1×105(b)Beryllium(4)Be-72×1012×1011×1031×107Be-104×1016×10-11×1041×106Bismuth(83)Bi-2057×10-17×10-11×1011×106Bi-2063×10-13×10-11×1011×105OfficialJournaloftheEuropeanUnionEN26.1.2004L18/120RadionuclideA1A2ActivityconcentrationforexemptmaterialActivitylimitforanexemptconsignment(atomicnumber)(TBq)(TBq)(Bq/g)(Bq)Bi-2077×10-17×10-11×1011×106Bi-2101×1006×10-11×1031×106Bi-210m(a)6×10-12×10-21×1011×105Bi-212(a)7×10-16×10-11×101(b)1×105(b)Berkelium(97)Bk-2478×1008×10-41×1001×104Bk-249(a)4×1013×10-11×1031×106Bromine(35)Br-764×10-14×10-11×1011×105Br-773×1003×1001×1021×106Br-824×10-14×10-11×1011×106Carbon(6)C-111×1006×10-11×1011×106C-144×1013×1001×1041×107Calcium(20)Ca-41UnlimitedUnlimited1×1051×107Ca-454×1011×1001×1041×107Ca-47(a)3×1003×10-11×1011×106Cadmium(48)Cd-1093×1012×1001×1041×106Cd-113m4×1015×10-11×1031×106Cd-115(a)3×1004×10-11×1021×106Cd-115m5×10-15×10-11×1031×106Cerium(58)Ce-1397×1002×1001×1021×106Ce-1412×1016×10-11×1021×107Ce-1439×10-16×10-11×1021×106Ce-144(a)2×10-12×10-11×102(b)1×105(b)OfficialJournaloftheEuropeanUnionEN26.1.2004L18/121RadionuclideA1A2ActivityconcentrationforexemptmaterialActivitylimitforanexemptconsignment(atomicnumber)(TBq)(TBq)(Bq/g)(Bq)Californium(98)Cf-2484×1016×10-31×1011×104Cf-2493×1008×10-41×1001×103Cf-2502×1012×10-31×1011×104Cf-2517×1007×10-41×1001×103Cf-2525×10-23×10-31×1011×104Cf-253(a)4×1014×10-21×1021×105Cf-2541×10-31×10-31×1001×103Chlorine(17)Cl-361×1016×10-11×1041×106Cl-382×10-12×10-11×1011×105Curium(96)Cm-2404×1012×10-21×1021×105Cm-2412×1001×1001×1021×106Cm-2424×1011×10-21×1021×105Cm-2439×1001×10-31×1001×104Cm-2442×1012×10-31×1011×104Cm-2459×1009×10-41×1001×103Cm-2469×1009×10-41×1001×103Cm-247(a)3×1001×10-31×1001×104Cm-2482×10-23×10-41×1001×103Cobalt(27)Co-555×10-15×10-11×1011×106Co-563×10-13×10-11×1011×105Co-571×1011×1011×1021×106OfficialJournaloftheEuropeanUnionEN26.1.2004L18/122RadionuclideA1A2ActivityconcentrationforexemptmaterialActivitylimitforanexemptconsignment(atomicnumber)(TBq)(TBq)(Bq/g)(Bq)Co-581×1001×1001×1011×106Co-58m4×1014×1011×1041×107Co-604×10-14×10-11×1011×105Chromium(24)Cr-513×1013×1011×1031×107Caesium(55)Cs-1294×1004×1001×1021×105Cs-1313×1013×1011×1031×106Cs-1321×1001×1001×1011×105Cs-1347×10-17×10-11×1011×104Cs-134m4×1016×10-11×1031×105Cs-1354×1011×1001×1041×107Cs-1365×10-15×10-11×1011×105Cs-137(a)2×1006×10-11×101(b)1×104(b)Copper(29)Cu-646×1001×1001×1021×106Cu-671×1017×10-11×1021×106Dysprosium(66)Dy-1592×1012×1011×1031×107Dy-1659×10-16×10-11×1031×106Dy-166(a)9×10-13×10-11×1031×106Erbium(68)Er-1694×1011×1001×1041×107Er-1718×10-15×10-11×1021×106OfficialJournaloftheEuropeanUnionEN26.1.2004L18/123RadionuclideA1A2ActivityconcentrationforexemptmaterialActivitylimitforanexemptconsignment(atomicnumber)(TBq)(TBq)(Bq/g)(Bq)Europium(63)Eu-1472×1002×1001×1021×106Eu-1485×10-15×10-11×1011×106Eu-1492×1012×1011×1021×107Eu-150(shortlived)2×1007×10-11×1031×106Eu-150(longlived)7×10-17×10-11×1011×106Eu-1521×1001×1001×1011×106Eu-152m8×10-18×10-11×1021×106Eu-1549×10-16×10-11×1011×106Eu-1552×1013×1001×1021×107Eu-1567×10-17×10-11×1011×106Fluorine(9)F-181×1006×10-11×1011×106Iron(26)Fe-52(a)3×10-13×10-11×1011×106Fe-554×1014×1011×1041×106Fe-599×10-19×10-11×1011×106Fe-60(a)4×1012×10-11×1021×105Gallium(31)Ga-677×1003×1001×1021×106Ga-685×10-15×10-11×1011×105Ga-724×10-14×10-11×1011×105Gadolinium(64)Gd-146(a)5×10-15×10-11×1011×106Gd-1482×1012×10-31×1011×104Gd-1531×1019×1001×1021×107Gd-1593×1006×10-11×1031×106OfficialJournaloftheEuropeanUnionEN26.1.2004L18/124RadionuclideA1A2ActivityconcentrationforexemptmaterialActivitylimitforanexemptconsignment(atomicnumber)(TBq)(TBq)(Bq/g)(Bq)Germanium(32)Ge-68(a)5×10-15×10-11×1011×105Ge-714×1014×1011×1041×108Ge-773×10-13×10-11×1011×105Hafnium(72)Hf-172(a)6×10-16×10-11×1011×106Hf-1753×1003×1001×1021×106Hf-1812×1005×10-11×1011×106Hf-182UnlimitedUnlimited1×1021×106Mercury(80)Hg-194(a)1×1001×1001×1011×106Hg-195m(a)3×1007×10-11×1021×106Hg-1972×1011×1011×1021×107Hg-197m1×1014×10-11×1021×106Hg-2035×1001×1001×1021×105Holmium(67)Ho-1664×10-14×10-11×1031×105Ho-166m6×10-15×10-11×1011×106Iodine(53)I-1236×1003×1001×1021×107I-1241×1001×1001×1011×106I-1252×1013×1001×1031×106I-1262×1001×1001×1021×106I-129UnlimitedUnlimited1×1021×105OfficialJournaloftheEuropeanUnionEN26.1.2004L18/125RadionuclideA1A2ActivityconcentrationforexemptmaterialActivitylimitforanexemptconsignment(atomicnumber)(TBq)(TBq)(Bq/g)(Bq)I-1313×1007×10-11×1021×106I-1324×10-14×10-11×1011×105I-1337×10-16×10-11×1011×106I-1343×10-13×10-11×1011×105I-135(a)6×10-16×10-11×1011×106Indium(49)In-1113×1003×1001×1021×106In-113m4×1002×1001×1021×106In-114m(a)1×1015×10-11×1021×106In-115m7×1001×1001×1021×106Iridium(77)Ir-189(a)1×1011×1011×1021×107Ir-1907×10-17×10-11×1011×106Ir-1921×100(c)6×10-11×1011×104Ir-1943×10-13×10-11×1021×105Potassium(19)K-409×10-19×10-11×1021×106K-422×10-12×10-11×1021×106K-437×10-16×10-11×1011×106Krypton(36)Kr-794x1001x1001x1031x105Kr-814×1014×1011×1041×107Kr-851×1011×1011×1051×104Kr-85m8×1003×1001×1031×1010OfficialJournaloftheEuropeanUnionEN26.1.2004L18/126RadionuclideA1A2ActivityconcentrationforexemptmaterialActivitylimitforanexemptconsignment(atomicnumber)(TBq)(TBq)(Bq/g)(Bq)Kr-872×10-12×10-11×1021×109Lanthanum(57)La-1373×1016×1001×1031×107La-1404×10-14×10-11×1011×105Lutetium(71)Lu-1726×10-16×10-11×1011×106Lu-1738×1008×1001×1021×107Lu-1749×1009×1001×1021×107Lu-174m2×1011×1011×1021×107Lu-1773×1017×10-11×1031×107Magnesium(12)Mg-28(a)3×10-13×10-11×1011×105Manganese(25)Mn-52(a)3×10-13×10-11×1011×105Mn-53UnlimitedUnlimited1×1041×109Mn-541×1001×1001×1011×106Mn-563×10-13×10-11×1011×105Molybdenum(42)Mo-934×1012×1011×1031×108Mo-99(a)1×1006×10-11×1021×106Nitrogen(7)N-139×10-16×10-11×1021×109Sodium(11)Na-225×10-15×10-11×1011×106Na-242×10-12×10-11×1011×105OfficialJournaloftheEuropeanUnionEN26.1.2004L18/127RadionuclideA1A2ActivityconcentrationforexemptmaterialActivitylimitforanexemptconsignment(atomicnumber)(TBq)(TBq)(Bq/g)(Bq)Niobium(41)Nb-93m4×1013×1011×1041×107Nb-947×10-17×10-11×1011×106Nb-951×1001×1001×1011×106Nb-979×10-16×10-11×1011×106Neodymium(60)Nd-1476×1006×10-11×1021×106Nd-1496×10-15×10-11×1021×106Nickel(28)Ni-59UnlimitedUnlimited1×1041×108Ni-634×1013×1011×1051×108Ni-654×10-14×10-11×1011×106Neptunium(93)Np-2354×1014×1011×1031×107Np-236(short-lived)2×1012×1001×1031×107Np-236(long-lived)9×1002×10-21×1021×105Np-2372×1012×10-31×1001×103Np-2397×1004×10-11×1021×107Osmium(76)Os-1851×1001×1001×1011×106Os-1911×1012×1001×1021×107Os-191m4×1013×1011×1031×107Os-1932×1006×10-11×1021×106Os-194(a)3×10-13×10-11×1021×105Phosphorus(15)P-325×10-15×10-11×1031×105P-334×1011×1001×1051×108OfficialJournaloftheEuropeanUnionEN26.1.2004L18/128RadionuclideA1A2ActivityconcentrationforexemptmaterialActivitylimitforanexemptconsignment(atomicnumber)(TBq)(TBq)(Bq/g)(Bq)Protactinium(91)Pa-230(a)2×1007×10-21×1011×106Pa-2314×1004×10-41×1001×103Pa-2335×1007×10-11×1021×107Lead(82)Pb-2011×1001×1001×1011×106Pb-2024×1012×1011×1031×106Pb-2034×1003×1001×1021×106Pb-205UnlimitedUnlimited1×1041×107Pb-210(a)1×1005×10-21×101(b)1×104(b)Pb-212(a)7×10-12×10-11×101(b)1×105(b)Palladium(46)Pd-103(a)4×1014×1011×1031×108Pd-107UnlimitedUnlimited1×1051×108Pd-1092×1005×10-11×1031×106Promethium(61)Pm-1433×1003×1001×1021×106Pm-1447×10-17×10-11×1011×106Pm-1453×1011×1011×1031×107Pm-1474×1012×1001×1041×107Pm-148m(a)8×10-17×10-11×1011×106Pm-1492×1006×10-11×1031×106Pm-1512×1006×10-11×1021×106Polonium(84)Po-2104×1012×10-21×1011×104Praseodymium(59)Pr-1424×10-14×10-11×1021×105Pr-1433×1006×10-11×1041×106OfficialJournaloftheEuropeanUnionEN26.1.2004L18/129RadionuclideA1A2ActivityconcentrationforexemptmaterialActivitylimitforanexemptconsignment(atomicnumber)(TBq)(TBq)(Bq/g)(Bq)Platinum(78)Pt-188(a)1×1008×10-11×1011×106Pt-1914×1003×1001×1021×106Pt-1934×1014×1011×1041×107Pt-193m4×1015×10-11×1031×107Pt-195m1×1015×10-11×1021×106Pt-1972×1016×10-11×1031×106Pt-197m1×1016×10-11×1021×106Plutonium(94)Pu-2363×1013×10-31×1011×104Pu-2372×1012×1011×1031×107Pu-2381×1011×10-31×1001×104Pu-2391×1011×10-31×1001×104Pu-2401×1011×10-31×1001×103Pu-241(a)4×1016×10-21×1021×105Pu-2421×1011×10-31×1001×104Pu-244(a)4×10-11×10-31×1001×104Radium(88)Ra-223(a)4×10-17×10-31×102(b)1×105(b)Ra-224(a)4×10-12×10-21×101(b)1×105(b)Ra-225(a)2×10-14×10-31×1021×105Ra-226(a)2×10-13×10-31×101(b)1×104(b)Ra-228(a)6×10-12×10-21×101(b)1×105(b)OfficialJournaloftheEuropeanUnionEN26.1.2004L18/130RadionuclideA1A2ActivityconcentrationforexemptmaterialActivitylimitforanexemptconsignment(atomicnumber)(TBq)(TBq)(Bq/g)(Bq)Rubidium(37)Rb-812×1008×10-11×1011×106Rb-83(a)2×1002×1001×1021×106Rb-841×1001×1001×1011×106Rb-865×10-15×10-11×1021×105Rb-87UnlimitedUnlimited1×1041×107Rb(nat)UnlimitedUnlimited1×1041×107Rhenium(75)Re-1841×1001×1001×1011×106Re-184m3×1001×1001×1021×106Re-1862×1006×10-11×1031×106Re-187UnlimitedUnlimited1×1061×109Re-1884×10-14×10-11×1021×105Re-189(a)3×1006×10-11×1021×106Re(nat)UnlimitedUnlimited1×1061×109Rhodium(45)Rh-992×1002×1001×1011×106Rh-1014×1003×1001×1021×107Rh-1025×10-15×10-11×1011×106Rh-102m2×1002×1001×1021×106Rh-103m4×1014×1011×1041×108Rh-1051×1018×10-11×1021×107OfficialJournaloftheEuropeanUnionEN26.1.2004L18/131RadionuclideA1A2ActivityconcentrationforexemptmaterialActivitylimitforanexemptconsignment(atomicnumber)(TBq)(TBq)(Bq/g)(Bq)Radon(86)Rn-222(a)3×10-14×10-31×101(b)1×108(b)Ruthenium(44)Ru-975×1005×1001×1021×107Ru-103(a)2×1002×1001×1021×106Ru-1051×1006×10-11×1011×106Ru-106(a)2×10-12×10-11×102(b)1×105(b)Sulphur(16)S-354×1013×1001×1051×108Antimony(51)Sb-1224×10-14×10-11×1021×104Sb-1246×10-16×10-11×1011×106Sb-1252×1001×1001×1021×106Sb-1264×10-14×10-11×1011×105Scandium(21)Sc-445×10-15×10-11×1011×105Sc-465×10-15×10-11×1011×106Sc-471×1017×10-11×1021×106Sc-483×10-13×10-11×1011×105Selenium(34)Se-753×1003×1001×1021×106Se-794×1012×1001×1041×107Silicon(14)Si-316×10-16×10-11×1031×106Si-324×1015×10-11×1031×106OfficialJournaloftheEuropeanUnionEN26.1.2004L18/132RadionuclideA1A2ActivityconcentrationforexemptmaterialActivitylimitforanexemptconsignment(atomicnumber)(TBq)(TBq)(Bq/g)(Bq)Samarium(62)Sm-1451×1011×1011×1021×107Sm-147UnlimitedUnlimited1×1011×104Sm-1514×1011×1011×1041×108Sm-1539×1006×10-11×1021×106Tin(50)Sn-113(a)4×1002×1001×1031×107Sn-117m7×1004×10-11×1021×106Sn-119m4×1013×1011×1031×107Sn-121m(a)4×1019×10-11×1031×107Sn-1238×10-16×10-11×1031×106Sn-1254×10-14×10-11×1021×105Sn-126(a)6×10-14×10-11×1011×105Strontium(38)Sr-82(a)2×10-12×10-11×1011×105Sr-852×1002×1001×1021×106Sr-85m5×1005×1001×1021×107Sr-87m3×1003×1001×1021×106Sr-896×10-16×10-11×1031×106Sr-90(a)3×10-13×10-11×102(b)1×104(b)Sr-91(a)3×10-13×10-11×1011×105Sr-92(a)1×1003×10-11×1011×106Tritium(1)T(H-3)4×1014×1011×1061×109Tantalum(73)Ta-178(long-lived)1×1008×10-11×1011×106Ta-1793×1013×1011×1031×107Ta-1829×10-15×10-11×1011×104OfficialJournaloftheEuropeanUnionEN26.1.2004L18/133RadionuclideA1A2ActivityconcentrationforexemptmaterialActivitylimitforanexemptconsignment(atomicnumber)(TBq)(TBq)(Bq/g)(Bq)Terbium(65)Tb-1574×1014×1011×1041×107Tb-1581×1001×1001×1011×106Tb-1601×1006×10-11×1011×106Technetium(43)Tc-95m(a)2×1002×1001×1011×106Tc-964×10-14×10-11×1011×106Tc-96m(a)4×10-14×10-11×1031×107Tc-97UnlimitedUnlimited1×1031×108Tc-97m4×1011×1001×1031×107Tc-988×10-17×10-11×1011×106Tc-994×1019×10-11×1041×107Tc-99m1×1014×1001×1021×107Tellurium(52)Te-1212×1002×1001×1011×106Te-121m5×1003×1001×1021×105Te-123m8×1001×1001×1021×107Te-125m2×1019×10-11×1031×107Te-1272×1017×10-11×1031×106Te-127m(a)2×1015×10-11×1031×107Te-1297×10-16×10-11×1021×106Te-129m(a)8×10-14×10-11×1031×106Te-131m(a)7×10-15×10-11×1011×106Te-132(a)5×10-14×10-11×1021×107Thorium(90)Th-2271×1015×10-31×1011×104Th-228(a)5×10-11×10-31×100(b)1×104(b)Th-2295×1005×10-41×100(b)1×103(b)OfficialJournaloftheEuropeanUnionEN26.1.2004L18/134RadionuclideA1A2ActivityconcentrationforexemptmaterialActivitylimitforanexemptconsignment(atomicnumber)(TBq)(TBq)(Bq/g)(Bq)Th-2301×1011×10-31×1001×104Th-2314×1012×10-21×1031×107Th-232UnlimitedUnlimited1×1011×104Th-234(a)3×10-13×10-11×103(b)1×105(b)Th(nat)UnlimitedUnlimited1×100(b)1×103(b)Titanium(22)Ti-44(a)5×10-14×10-11×1011×105Thallium(81)Tl-2009×10-19×10-11×1011×106Tl-2011×1014×1001×1021×106Tl-2022×1002×1001×1021×106Tl-2041×1017×10-11×1041×104Thulium(69)Tm-1677×1008×10-11×1021×106Tm-1703×1006×10-11×1031×106Tm-1714×1014×1011×1041×108Uranium(92)U-230(fastlungabsorption)(a)(d)4×1011×10-11×101(b)1×105(b)U-230(mediumlungabsorp-tion)(a)(e)4×1014×10-31×1011×104U-230(slowlungabsorption)(a)(f)3×1013×10-31×1011×104U-232(fastlungabsorption)(d)4×1011×10-21×100(b)1×103(b)U-232(mediumlungabsorp-tion)(e)4×1017×10-31×1011×104U-232(slowlungabsorption)(f)1×1011×10-31×1011×104U-233(fastlungabsorption)(d)4×1019×10-21×1011×104OfficialJournaloftheEuropeanUnionEN26.1.2004L18/135RadionuclideA1A2ActivityconcentrationforexemptmaterialActivitylimitforanexemptconsignment(atomicnumber)(TBq)(TBq)(Bq/g)(Bq)U-233(mediumlungabsorp-tion)(e)4×1012×10-21×1021×105U-233(slowlungabsorption)(f)4×1016×10-31×1011×105U-234(fastlungabsorption)(d)4×1019×10-21×1011×104U-234(mediumlungabsorp-tion)(e)4×1012×10-21×1021×105U-234(slowlungabsorption)(f)4×1016×10-31×1011×105U-235(alllungabsorptiontypes)(a)(d)(e)(f)UnlimitedUnlimited1×101(b)1×104(b)U-236(fastlungabsorption)(d)UnlimitedUnlimited1×1011×104U-236(mediumlungabsorp-tion)(e)4×1012×10-21×1021×105U-236(slowlungabsorption)(f)4×1016×10-31×1011×104U-238(alllungabsorptiontypes)(d)(e)(f)UnlimitedUnlimited1×101(b)1×104(b)U(nat)UnlimitedUnlimited1×100(b)1×103(b)U(enrichedto20%orless)(g)UnlimitedUnlimited1×1001×103U(dep)UnlimitedUnlimited1×1001×103Vanadium(23)V-484×10-14×10-11×1011×105V-494×1014×1011×1041×107Tungsten(74)W-178(a)9×1005×1001×1011×106W-1813×1013×1011×1031×107OfficialJournaloftheEuropeanUnionEN26.1.2004L18/136RadionuclideA1A2ActivityconcentrationforexemptmaterialActivitylimitforanexemptconsignment(atomicnumber)(TBq)(TBq)(Bq/g)(Bq)W-1854×1018×10-11×1041×107W-1872×1006×10-11×1021×106W-188(a)4×10-13×10-11×1021×105Xenon(54)Xe-122(a)4×10-14×10-11×1021×109Xe-1232×1007×10-11×1021×109Xe-1274×1002×1001×1031×105Xe-131m4×1014×1011×1041×104Xe-1332×1011×1011×1031×104Xe-1353×1002×1001×1031×1010Yttrium(39)Y-87(a)1×1001×1001×1011×106Y-884×10-14×10-11×1011×106Y-903×10-13×10-11×1031×105Y-916×10-16×10-11×1031×106Y-91m2×1002×1001×1021×106Y-922×10-12×10-11×1021×105Y-933×10-13×10-11×1021×105Ytterbium(70)Yb-1694×1001×1001×1021×107Yb-1753×1019×10-11×1031×107Zinc(30)Zn-652×1002×1001×1011×106Zn-693×1006×10-11×1041×106Zn-69m(a)3×1006×10-11×1021×106Zirconium(40)Zr-883×1003×1001×1021×106Zr-93UnlimitedUnlimited1×103(b)1×107(b)OfficialJournaloftheEuropeanUnionEN26.1.2004L18/137RadionuclideA1A2ActivityconcentrationforexemptmaterialActivitylimitforanexemptconsignment(atomicnumber)(TBq)(TBq)(Bq/g)(Bq)Zr-95(a)2×1008×10-11×1011×106Zr-97(a)4×10-14×10-11×101(b)1×105(b)(a)A1and/orA2valuesincludecontributionsfromdaughternuclideswithhalf-liveslessthan10days.Parentnuclidesandtheirprogenyincludedinsecularequilibriumarelistedinthefollowing:Sr-90Zr-93Zr-97Ru-106Cs-137Ce-134Ce-144Ba-140Bi-212Pb-210Pb-212Rn-220Rn-222Ra-223Y-90Nb-93mNb-97Rh-106Ba-137mLa-134Pr-144La-140Tl-208(0,36),Po-212(0,64)Bi-210,Po-210Bi-212,Tl-208(0,36),Po-212(0,64)Po-216Po-218,Pb-214,Bi-214,Po-214Rn-219,Po-215,Pb-211,Bi-211,Tl-207(b)Ra-224Ra-226Ra-228Th-226Th-228Th-229Th-natTh-234U-230U-232U-235U-238U-natU-240Np-237Am-242mAm-243Rn-220,Po-216,Pb-212,Bi-212,Tl-208(0,36),Po-212(0,64)Rn-222,Po-218,Pb-214,Bi-214,Po-214,Pb-210,Bi-210,Po-210Ac-228Ra-222,Rn-218,Po-214Ra-224,Rn-220,Po-216,Pb212,Bi-212,Tl208(0,36),Po-212(0,64)Ra-225,Ac-225,Fr-221,At-217,Bi-213,Po-213,Pb-209Ra-228,Ac-228,Th-228,Ra-224,Rn-220,Po-216,Pb-212,Bi-212,l208(0,36),Po-212(0,64)Pa-234mTh-226,Ra-222,Rn-218,Po-214Th-228,Ra-224,Rn-220,Po-216,Pb-212,Bi-212,Tl-208(0,36),Po-212(0,64)Th-231Th-234,Pa-234mTh-234,Pa-234m,U-234,Th-230,Ra-226,Rn-222,Po-218,Pb-214,Bi-214,Po-214,Pb-210,Bi-210,Po-210Np-240mPa-233Am-242Np-239(c)Thequantitymaybedeterminedfromameasurementoftherateofdecayorameasurementoftheradiationlevelataprescribeddistancefromthesource.(d)ThesevaluesapplyonlytocompoundsofuraniumthattakethechemicalformofUF6,UO2F2andUO2(NO3)2inbothnormalandaccidentconditionsofcarriage.(e)ThesevaluesapplyonlytocompoundsofuraniumthattakethechemicalformofUO3,UF4,UCl4andhexavalentcompoundsinbothnormalandaccidentconditionsofcarriage.(f)Thesevaluesapplytoallcompoundsofuraniumotherthanthosespecifiedin(d)and(e)above.(g)Thesevaluesapplytounirradiateduraniumonly.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/1382.2.7.7.2.2.ForindividualradionuclideswhicharenotlistedinTable2.2.7.7.2.1thedeterminationofthebasicradionuclidevaluesreferredtoin2.2.7.7.2.1shallrequirecompetentauthorityapprovalor,forinternationalcarriage,multilateralapproval.Wherethechemicalformofeachradionuclideisknown,itispermissibletousetheA2valuerelatedtoitssolubilityclassasrecommendedbytheInternationalCommissiononRadiologicalProtection,ifthechemicalformsunderbothnormalandaccidentconditionsofcarriagearetakenintoconsideration.Alternatively,theradionuclidevaluesinTable2.2.7.7.2.2maybeusedwithoutobtainingcompetentauthorityapproval.Table2.2.7.7.2.2BASICRADIONUCLIDEVALUESFORUNKNOWNRADIONUCLIDESORMIXTURESRadioactivecontentsA1A2ActivityconcentrationforexemptmaterialActivitylimitforanexemptconsignmentTBqTBqBq/gBqOnlybetaorgammaemittingnuclidesareknowntobepresent0,10,021×1011×104Onlyalphaemittingnuclidesareknowntobepresent0,29×1059×1011×103Norelevantdataareavailable0,0019×1059×1011×1032.2.7.7.2.3.InthecalculationsofA1andA2foraradionuclidenotinTable2.2.7.7.2.1,asingleradioactivedecaychaininwhichtheradionuclidesarepresentintheirnaturallyoccurringproportions,andinwhichnodaughternuclidehasahalf-lifeeitherlongerthan10daysorlongerthanthatoftheparentnuclide,shallbeconsideredasasingleradionuclide;andtheactivitytobetakenintoaccountandtheA1orA2valuetobeappliedshallbethosecorrespondingtotheparentnuclideofthatchain.Inthecaseofradioactivedecaychainsinwhichanydaughternuclidehasahalf-lifeeitherlongerthan10daysorgreaterthanthatoftheparentnuclide,theparentandsuchdaughternuclidesshallbeconsideredasmixturesofdifferentnuclides.2.2.7.7.2.4.Formixturesofradionuclides,thedeterminationofthebasicradionuclidevaluesreferredtoin2.2.7.7.2.1maybedeterminedasfollows:where,f(i)isthefractionofactivityoractivityconcentrationofradionuclideiinthemixture;X(i)istheappropriatevalueofA1orA2,ortheactivityconcentrationforexemptmaterialortheactivitylimitforanexemptconsignmentasappropriatefortheradionuclidei;andXmisthederivedvalueofA1orA2,ortheactivityconcentrationforexemptmaterialortheactivitylimitforanexemptconsignmentinthecaseofamixture.2.2.7.7.2.5.Whentheidentityofeachradionuclideisknownbuttheindividualactivitiesofsomeoftheradionuclidesarenotknown,theradionuclidesmaybegroupedandthelowestradionuclidevalue,asappropriate,fortheradionuclidesineachgroupmaybeusedinapplyingtheformulasin2.2.7.7.2.4and2.2.7.7.1.4.2.Groupsmaybebasedonthetotalalphaactivityandthetotalbeta/gammaactivitywhentheseareknown,usingthelowestradionuclidevaluesforthealphaemittersorbeta/gammaemitters,respectively.2.2.7.7.2.6.Forindividualradionuclidesorformixturesofradionuclidesforwhichrelevantdataarenotavailable,thevaluesshowninTable2.2.7.7.2.2shallbeused.2.2.7.8.Limitsontransportindex(TI),criticalitysafetyindex(CSI),radiationlevelsforpackagesandoverpacks2.2.7.8.1.Exceptforconsignmentsunderexclusiveuse,thetransportindexofanypackageoroverpackshallnotexceed10,norshallthecriticalitysafetyindexofanypackageoroverpackexceed50.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/1392.2.7.8.2.Exceptforpackagesoroverpackscarriedunderexclusiveusebyroadundertheconditionsspecifiedin7.5.11,CV33(3.5)(a),themaximumradiationlevelatanypointonanyexternalsurfaceofapackageoroverpackshallnotexceed2mSv/h.2.2.7.8.3.Themaximumradiationlevelatanypointonanyexternalsurfaceofapackageunderexclusiveuseshallnotexceed10mSv/h.2.2.7.8.4.PackagesandoverpacksshallbeassignedtoeithercategoryI-WHITE,II-YELLOWorIII-YELLOWinaccordancewiththeconditionsspecifiedinTable2.2.7.8.4andwiththefollowingrequirements:(a)forapackageoroverpack,boththetransportindexandthesurfaceradiationlevelconditionsshallbetakenintoaccountindeterminingwhichistheappropriatecategory.Wherethetransportindexsatisfiestheconditionforonecategorybutthesurfaceradiationlevelsatisfiestheconditionforadifferentcategory,thepackageoroverpackshallbeassignedtothehighercategory.Forthispurpose,categoryI-WHITEshallberegardedasthelowestcategory;(b)thetransportindexshallbedeterminedfollowingtheproceduresspecifiedin2.2.7.6.1.1and2.2.7.6.1.2;(c)ifthesurfaceradiationlevelisgreaterthan2mSv/h,thepackageoroverpackshallbecarriedunderexclusiveuseandundertheprovisionsof7.5.11,CV33(3.5)(a);(d)apackagecarriedunderaspecialarrangementshallbeassignedtocategoryIII-YELLOW;(e)anoverpackwhichcontainspackagescarriedunderspecialarrangementshallbeassignedtocategoryIII-YELLOW.Table2.2.7.8.4CATEGORIESOFPACKAGESANDOVERPACKSConditionsTransportindex(TI)MaximumradiationlevelatanypointonexternalsurfaceCategory0(a)Notmorethan0,005mSv/hI-WHITEMorethan0butnotmorethan1(a)Morethan0,005mSv/hbutnotmorethan0,5mSv/hII-YELLOWMorethan1butnotmorethan10Morethan0,5mSv/hbutnotmorethan2mSv/hIII-YELLOWMorethan10Morethan2mSv/hbutnotmorethan10mSv/hIII-YELLOW(b)(a)IfthemeasuredTIisnotgreaterthan0,05,thevaluequotedmaybezeroinaccordancewith2.2.7.6.1.1(c).(b)Shallalsobecarriedunderexclusiveuse.2.2.7.9.Requirementsandcontrolsforcarriageofexceptedpackages2.2.7.9.1.Exceptedpackageswhichmaycontainradioactivematerialinlimitedquantities,instruments,manufacturedarticlesasspecifiedin2.2.7.7.1.2andemptypackagingsasspecifiedin2.2.7.9.6maybecarriedunderthefollowingconditions:(a)theapplicablerequirementsspecifiedin2.2.7.9.2,3.3.1(specialprovisions172or290),4.1.9.1.2,5.2.1.2,5.2.1.7.1,5.2.1.7.2,5.2.1.7.3,5.4.1.2.5.1(a),7.5.11CV33(5.2)and,asapplicable2.2.7.9.3to2.2.7.9.6;(b)therequirementsforexceptedpackagesspecifiedin6.4.4;(c)iftheexceptedpackagecontainsfissilematerial,oneofthefissileexceptionsprovidedby6.4.11.2shallapplyandtherequirementof6.4.7.2shallbemet.2.2.7.9.2.Theradiationlevelatanypointontheexternalsurfaceofanexceptedpackageshallnotexceed5µSv/h.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/1402.2.7.9.3.Radioactivematerialwhichisenclosedinorisincludedasacomponentpartofaninstrumentorothermanufacturedarticle,withactivitynotexceedingtheitemandpackagelimitsspecifiedincolumns2and3respectivelyofTable2.2.7.7.1.2.1,maybecarriedinanexceptedpackageprovidedthat:(a)theradiationlevelat10cmfromanypointontheexternalsurfaceofanyunpackagedinstrumentorarticleisnotgreaterthan0,1mSv/h;and(b)eachinstrumentorarticle(exceptradioluminescenttime-piecesordevices)bearsthemarking‘RADIOACTIVE’;and(c)theactivematerialiscompletelyenclosedbynon-activecomponents(adeviceperformingthesolefunctionofcontainingradioactivematerialshallnotbeconsideredtobeaninstrumentormanufacturedarticle).2.2.7.9.4.Radioactivematerialinformsotherthanasspecifiedin2.2.7.9.3,withanactivitynotexceedingthelimitspecifiedincolumn4ofTable2.2.7.7.1.2.1,maybecarriedinanexceptedpackageprovidedthat:(a)thepackageretainsitsradioactivecontentsunderroutineconditionsofcarriage;and(b)thepackagebearsthemarking‘RADIOACTIVE’onaninternalsurfaceinsuchamannerthatawarningofthepresenceofradioactivematerialisvisibleonopeningthepackage.2.2.7.9.5.Amanufacturedarticleinwhichthesoleradioactivematerialisunirradiatednaturaluranium,unirradiateddepleteduraniumorunirradiatednaturalthoriummaybecarriedasanexceptedpackageprovidedthattheoutersurfaceoftheuraniumorthoriumisenclosedinaninactivesheathmadeofmetalorsomeothersubstantialmaterial.2.2.7.9.6.Anemptypackagingwhichhadpreviouslycontainedradioactivematerialmaybecarriedasanexceptedpackageprovidedthat:(a)itisinawellmaintainedconditionandsecurelyclosed;(b)theoutersurfaceofanyuraniumorthoriuminitsstructureiscoveredwithaninactivesheathmadeofmetalorsomeothersubstantialmaterial;(c)thelevelofinternalnon-fixedcontaminationdoesnotexceed100timesthelevelsspecifiedin4.1.9.1.2;and(d)anylabelswhichmayhavebeendisplayedonitinconformitywith5.2.2.1.11.1arenolongervisible.2.2.7.9.7.Thefollowingprovisionsdonotapplytoexceptedpackagesandthecontrolsforcarriageofexceptedpackages:2.2.7.4.1,2.2.7.4.2,4.1.9.1.3,4.1.9.1.4,5.1.3.2,5.1.5.1.1,5.1.5.1.2,5.2.2.1.11.1,5.4.1.2.5.1exceptfor(a),5.4.1.2.5.2,5.4.1.3,6.4.6.1,7.5.11CV33exceptforparagraph(5.2).2.2.7.10.(Reserved)2.2.8.Class8Corrosivesubstances2.2.8.1.Criteria2.2.8.1.1.TheheadingofClass8coverssubstancesandarticlescontainingsubstancesofthisClasswhichbychemicalactionattackepithelialtissue—ofskinormucousmembranes—withwhichtheyareincontact,orwhichintheeventofleakagearecapableofdamagingordestroyingothergoods,ormeansoftransport,andmayalsocauseotherhazards.TheheadingofthisClassalsocoversothersubstanceswhichformacorrosiveliquidonlyinthepresenceofwater,orwhichproducecorrosivevapourormistinthepresenceofnaturalmoistureoftheair.2.2.8.1.2.SubstancesandarticlesofClass8aresubdividedasfollows:C1-C10Corrosivesubstanceswithoutsubsidiaryrisk:C1-C4Acidsubstances:C1inorganic,liquid;C2inorganic,solid;C3organic,liquid;C4organic,solid;OfficialJournaloftheEuropeanUnionEN26.1.2004L18/141C5-C8Basicsubstances:C5inorganic,liquid;C6inorganic,solid;C7organic,liquid;C8organic,solid;C9-C10othercorrosivesubstances:C9liquid;C10solid;C11Articles;CFCorrosivesubstances,flammable:CF1liquid;CF2solid;CSCorrosivesubstances,self-heating:CS1liquid;CS2solid;CWCorrosivesubstanceswhich,incontactwithwater,emitflammablegases:CW1liquid;CW2solid;COCorrosivesubstances,oxidising:CO1liquid;CO2solid;CTCorrosivesubstances,toxic:CT1liquid;CT2solid;CFTCorrosivesubstances,flammable,liquid,toxic;COTCorrosivesubstances,oxidising,toxic.Classificationandassignmentofpackinggroups2.2.8.1.3.SubstancesofClass8shallbeclassifiedinthreepackinggroupsaccordingtothedegreeofdangertheypresentforcarriage,asfollows:packinggroupI:highlycorrosivesubstancespackinggroupII:corrosivesubstancespackinggroupIII:slightlycorrosivesubstances.2.2.8.1.4.SubstancesandarticlesclassifiedinClass8arelistedinTableAofChapter3.2.AllocationofsubstancestopackinggroupsI,IIandIIIhasbeenmadeonthebasisofexperiencetakingintoaccountsuchadditionalfactorsasinhalationrisk(1)andreactivitywithwater(includingtheformationofdangerousdecompositionproducts).OfficialJournaloftheEuropeanUnionEN26.1.2004L18/142(1)AsubstanceorpreparationmeetingthecriteriaofClass8havinganinhalationtoxicityofdustsandmists(LC50)intherangeofpackinggroupI,buttoxicitythroughoralingestionordermalcontactonlyintherangeofpackinggroupIIIorless,shallbeallocatedtoClass8.2.2.8.1.5.Substances,includingmixtures,notmentionedbynameinTableAofChapter3.2canbeassignedtotherelevantentryofsubsection2.2.8.3,andtotherelevantpackinggrouponthebasisofthelengthoftimeofcontactnecessarytoproducefullthicknessdestructionofhumanskininaccordancewiththecriteriaofparagraph(a)to(c)below.Substanceswhicharejudgednottocausefullthicknessdestructionofhumanskinshallstillbeconsideredfortheirpotentialtocausecorrosiontocertainmetalsurfaces.Inassigningthepackinggroup,accountshallbetakenofhumanexperienceininstancesofaccidentalexposure.Intheabsenceofhumanexperience,thegroupingshallbebasedondataobtainedfromexperimentsinaccordancewithOECDGuideline404(1).(a)packinggroupIisassignedtosubstancesthatcausefullthicknessdestructionofintactskintissuewithinanobservationperiodupto60minutesstartingaftertheexposuretimeofthreeminutesorless.(b)packinggroupIIisassignedtosubstancesthatcausefullthicknessdestructionofintactskintissuewithinanobservationperiodupto14daysstartingaftertheexposuretimeofmorethanthreeminutesbutnotmorethan60minutes.(c)packinggroupIIIisassignedtosubstancesthat:—causefullthicknessdestructionofintactskintissuewithinanobservationperiodupto14daysstartingaftertheexposuretimeofmorethan60minutesbutnotmorethanfourhours,or—arejudgednottocausefullthicknessdestructionofintactskintissue,butwhichexhibitacorrosionrateonsteeloraluminiumsurfacesexceeding6.25mmayearatatesttemperatureof55°C.Forthepurposesoftestingsteel,typeP235(ISO9328(II):1991)orasimilartype,andfortestingaluminium,non-cladtypes7075-T6orAZ5GU-T6shallbeused.AnacceptabletestisprescribedinASTMG31-72(Reapproved1990).2.2.8.1.6.IfsubstancesofClass8,asaresultofadmixtures,comeintocategoriesofriskdifferentfromthosetowhichthesubstancesmentionedbynameinTableAofChapter3.2belong,thesemixturesorsolutionsshallbeassignedtotheentriestowhichtheybelong,onthebasisoftheiractualdegreeofdanger.NOTEFortheclassificationofsolutionsandmixtures(suchaspreparationsandwastes),seealso2.1.3.2.2.8.1.7.Onthebasisofthecriteriasetoutinparagraph2.2.8.1.5,itmayalsobedeterminedwhetherthenatureofasolutionormixturementionedbynameorcontainingasubstancementionedbynameissuchthatthesolutionormixtureisnotsubjecttotheprovisionsforthisClass.2.2.8.1.8.Substances,solutionsandmixtures,which—donotmeetthecriteriaofDirectives67/548/EEC(2)or88/379/EEC(3)asamendedandthereforearenotclassifiedascorrosiveaccordingtothesedirectives,asamended,and—donotexhibitacorrosiveeffectonsteeloraluminium,maybeconsideredassubstancesnotbelongingtoClass8.NOTEUNNo1910calciumoxideandUNNo2812sodiumaluminate,listedintheUNModelRegulations,arenotsubjecttotheprovisionsofthisDirective.2.2.8.2.Substancesnotacceptedforcarriage2.2.8.2.1.ThechemicallyunstablesubstancesofClass8shallnotbeacceptedforcarriageunlessthenecessarystepshavebeentakentopreventtheirdangerousdecompositionorpolymerisationduringcarriage.Tothisenditshallinparticularbeensuredthatreceptaclesandtanksdonotcontainanysubstanceliabletopromotethesereactions.2.2.8.2.2.Thefollowingsubstancesshallnotbeacceptedforcarriage:—UNNo1798NITROHYDROCHLORICACID,—chemicallyunstablemixturesofspentsulphuricacid,—chemicallyunstablemixturesofnitratingacidormixturesofresidualsulphuricandnitricacids,notdenitrated,—perchloricacidaqueoussolutionwithmorethan72%pureacid,bymass,ormixturesofperchloricacidwithanyliquidotherthanwater.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/143(1)OECDguidelinesforTestingofChemicals,No404‘Acutedermalirritation/corrosion’(1992).(2)CouncilDirective67/548/EECof27June1967ontheapproximationoflaws,regulationsandadministrativeprovisionsrelatingtotheclassification,packagingandlabellingofdangeroussubstances(OJL196,16.8.1967).(3)CouncilDirective88/379/EEContheapproximationoflaws,regulationsandadministrativeprovisionsrelatingtotheclassification,packagingandlabellingofdangerouspreparations(OJL187,16.7.1988,p.14).2.2.8.3.ListofcollectiveentriesOfficialJournaloftheEuropeanUnionEN26.1.2004L18/1442.2.9.Class9Miscellaneousdangeroussubstancesandarticles2.2.9.1.Criteria2.2.9.1.1.TheheadingofClass9coverssubstancesandarticleswhich,duringcarriage,presentadangernotcoveredbytheheadingofotherclasses.2.2.9.1.2.ThesubstancesandarticlesofClass9aresubdividedasfollows:M1substanceswhich,oninhalationasfinedust,mayendangerhealth;M2substancesandapparatuswhich,intheeventoffire,mayformdioxins;M3substancesevolvingflammablevapour;OfficialJournaloftheEuropeanUnionEN26.1.2004L18/145M4lithiumbatteries;M5life-savingappliances;M6-M8environmentallyhazardoussubstances:M6pollutanttotheaquaticenvironment,liquid;M7pollutanttotheaquaticenvironment,solid;M8geneticallymodifiedmicro-organismsandorganisms;M9-M10elevatedtemperaturesubstances:M9liquid;M10solid;M11Othersubstancespresentingadangerduringcarriage,butnotmeetingthedefinitionsofanotherclass.Definitionsandclassification2.2.9.1.3.SubstancesandarticlesclassifiedinClass9arelistedinTableAofChapter3.2.TheassignmentofsubstancesandarticlesnotmentionedbynameinTableAofChapter3.2totherelevantentryofthatTableorofsubsection2.2.9.3shallbedoneinaccordancewith2.2.9.1.4to2.2.9.1.14below.Substanceswhich,oninhalationasfinedust,mayendangerhealth2.2.9.1.4.Substanceswhich,oninhalationasfinedust,mayendangerhealthincludeasbestosandmixturescontainingasbestos.Substancesandapparatuswhich,intheeventoffire,mayformdioxins2.2.9.1.5.Substancesandapparatuswhich,intheeventoffire,mayformdioxinsincludepolychlorinatedbiphenyls(PCBs)andterphenyls(PCTs)andpolyhalogenatedbiphenylsandterphenylsandmixturescontainingthesesubstances,aswellasapparatussuchastransformers,condensersandapparatuscontainingthosesubstancesormixtures.NOTEMixtureswithaPCBorPCTcontentofnotmorethan50mg/kgarenotsubjecttotheprovisionsofthisDirective.Substancesevolvingflammablevapour2.2.9.1.6.Substancesevolvingflammablevapourincludepolymerscontainingflammableliquidswithaflash-pointnotexceeding55°C.Lithiumbatteries2.2.9.1.7.LithiumcellsandbatteriesmaybeassignedtoClass9iftheymeettherequirementsofspecialprovision230ofChapter3.3.TheyarenotsubjecttotheprovisionsofthisDirectiveiftheymeettherequirementsofspecialprovision188ofChapter3.3.TheyshallbeclassifiedinaccordancewiththeproceduresofSection38.3oftheManualoftestsandcriteria.Life-savingappliances2.2.9.1.8.Life-savingappliancesincludelife-savingappliancesandmotorvehiclecomponentswhichmeetthedefinitionsofspecialprovisions170,171or235ofChapter3.3.Environmentallyhazardoussubstances2.2.9.1.9.Environmentallyhazardoussubstancesincludeliquidorsolidsubstancespollutanttotheaquaticenvironmentandsolutionsandmixturesofsuchsubstances(suchaspreparationsandwastes),whichcannotbeclassifiedintheotherclassesorunderanyotherentryofClass9listedinTableAofChapter3.2.Italsoincludesgeneticallymodifiedmicro-organismsandorganisms.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/146Pollutantstotheaquaticenvironment2.2.9.1.10.AssignmentofasubstancetotheentriesUNNo3082ENVIRONMENTALLYHAZARDOUSSUBSTANCE,LIQUID,N.O.SandUNNo3077ENVIRONMEN-TALLYHAZARDOUSSUBSTANCE,SOLID,N.O.Saspollutanttotheaquaticenvironmentshallbeasindicatedin2.3.5.SubstancesalreadyclassifiedasenvironmentallyhazardouswithUNNos3077and3082arelistedin2.2.9.4.Geneticallymodifiedmicro-organismsororganisms2.2.9.1.11.Geneticallymodifiedmicro-organismsaremicro-organismsinwhichthegeneticmaterialhasbeendeliberatelyalteredbytechnicalmeansorbysuchmeansthatcannotoccurnaturally.Geneticallymodifiedmicro-organismswithinthemeaningofClass9arethosewhicharenotdangerousforhumansandanimals,butwhichcouldalteranimals,plants,microbiologicalsubstancesandecosystemsinsuchawayascannotoccurnaturally.NOTE1.Geneticallymodifiedmicro-organismswhichareinfectiousaresubstancesofClass6.2,UNNos2814and2900.2.Geneticallymodifiedmicro-organismswhichhavereceivedaconsentfordeliberatereleaseintotheenvironment(1)arenotsubjecttotheprovisionsforthisclass.3.Livevertebrateorinvertebrateanimalsshallnotbeusedtocarrygeneticallymodifiedmicro-organismsclassifiedinClass9unlessthesubstancecanbecarriednootherway.2.2.9.1.12.Geneticallymodifiedorganisms,whichareknownorsuspectedtobedangeroustotheenvironmentshallbecarriedinaccordancewithconditionsspecifiedbythecompetentauthorityofthecountryoforigin.Elevatedtemperaturesubstances2.2.9.1.13.Elevatedtemperaturesubstancesincludesubstanceswhicharecarriedorhandedoverforcarriageintheliquidstateatorabove100°Cand,inthecaseofthosewithaflash-point,belowtheirflash-point.Theyalsoincludesolidswhicharecarriedorhandedoverforcarriageatorabove240°C.NOTEElevatedtemperaturesubstancesmaybeassignedtoClass9onlyiftheydonotmeetthecriteriaofanyotherclass.Othersubstancespresentingadangerduringcarriagebutnotmeetingthedefinitionsofanotherclass.2.2.9.1.14.ThefollowingothermiscellaneoussubstancesnotmeetingthedefinitionsofanotherclassareassignedtoClass9:—solidammoniacompoundshavingaflash-pointbelow61°C—lowhazarddithionites—highlyvolatileliquids—substancesemittingnoxiousfumes—substancescontainingallergens—chemicalkitsandfirstaidkitsNOTEUNNo1845carbondioxide,solid(dryice),UNNo2071ammoniumnitratefertilisers,UNNo2216fishmeal(fishscrap),stabilised,UNNo2807magnetisedmaterial,UNNo3166engines,internalcombustion,includingwhenfittedinmachineryorvehicles,UNNo3171battery-poweredvehicleor3171battery-poweredequipment(wetbattery),UNNo3334aviationregulatedliquid,n.o.sandUNNo3335aviationregulatedsolid,nos,listedintheUNModelRegulations,arenotsubjecttotheprovisionsofthisDirective.Assignmentofthepackinggroups2.2.9.1.15.ThesubstancesandarticlesofClass9listedassuchinTableAofChapter3.2shallbeassignedtooneofthefollowingpackinggroupsaccordingtotheirdegreeofdanger:packinggroupII:substancespresentingmediumdangerpackinggroupIII:substancespresentinglowdanger2.2.9.2.SubstancesandarticlesnotacceptedforcarriageThefollowingsubstancesandarticlesshallnotbeacceptedforcarriage:—lithiumbatterieswhichdonotmeettherelevantconditionsofspecialprovisions188,230,287or636ofChapter3.3,—uncleanedemptycontainmentvesselsforapparatussuchastransformersandcondenserscontainingsubstancesassignedtoUNNos2315,3151or3152.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/147(1)SeeinparticularpartCofDirective90/220/EEC(OJL117,8.5.1990,p.18),whichsetsouttheauthorisationproceduresfortheEuropeanCommunity.2.2.9.3.Listofcollectiveentries2.2.9.4.SubstancesalreadyclassifiedasenvironmentallyhazardouswhichdonotbelongtoanyotherclassnortoClass9entriesotherthantheentriesUNNo3077or3082UNNo3082ENVIRONMENTALLYHAZARDOUSSUBSTANCE,LIQUID,N.O.S—Pollutanttotheaquaticenvironment,liquid—alcoholC6-C17(secondary)poly(3-6)ethoxylate—alcoholC12-C15poly(1-3)ethoxylate—alcoholC13-C15poly(1-6)ethoxylateOfficialJournaloftheEuropeanUnionEN26.1.2004L18/148—alpha-cypermethrin—butylbenzylphthalate—chlorinatedparaffins(C10-C13)—1-chlorooctane—cresyldiphenylphosphate—cyfluthrin—decylacrylate—di-n-butylphthalate—1,6-dichlorohexane—diisopropylbenzenes—isodecylacrylate—isodecyldiphenylphosphate—isoctylnitrate—malathion—resmethrin—triarylphosphates—tricresylphosphates—triethylbenzene—trixylenylphosphateUNNo3077ENVIRONMENTALLYHAZARDOUSSUBSTANCE,SOLID,N.O.S—Pollutanttotheaquaticenvironment,solid—chlorohexidine—chlorinatedparaffins(C10-C13)—p-dichlorobenzene—diphenyl—diphenylether—fenbutadinoxide—mercurouschloride(calomel)—tributyltinphosphate—zincbromideCHAPTER2.3TESTMETHODS2.3.0.GeneralUnlessotherwiseprovidedforinChapter2.2orinthischapter,thetestmethodstobeusedfortheclassificationofdangerousgoodsarethosedescribedintheManualoftestsandcriteria.2.3.1.ExudationtestforblastingexplosivesofTypeA2.3.1.1.BlastingexplosivesoftypeA(UNNo0081)shall,iftheycontainmorethan40%liquidnitricester,inadditiontothetestingspecifiedintheManualoftestsandcriteria,satisfythefollowingexudationtest.2.3.1.2.Theapparatusfortestingblastingexplosiveforexudation(figures1to3)consistsofahollowbronzecylinder.Thiscylinder,whichisclosedatoneendbyaplateofthesamemetal,hasaninternaldiameterof15,7mmandadepthof40mm.Itispiercedby20holes0,5mmindiameter(foursetsoffiveholes)onthecircumference.Abronzepiston,cylindricallyfashionedoveralengthof48mmandhavingatotallengthof52mm,slidesintotheverticallyplacedcylinder.Thepiston,whosediameteris15,6mm,isloadedwithamassof2220gsothatapressureof120kPa(1,20bar)isexertedonthebaseofthecylinder.2.3.1.3.Asmallplugofblastingexplosiveweighing5to8g,30mmlongand15mmindiameter,iswrappedinveryfinegauzeandplacedinthecylinder;thepistonanditsloadingmassarethenplacedonitsothattheblastingexplosiveissubjectedtoapressureof120kPa(1,20bar).Thetimetakenfortheappearanceofthefirstsignsofoilydroplets(nitroglycerine)attheouterorificesofthecylinderholesisnoted.2.3.1.4.Theblastingexplosiveisconsideredsatisfactoryifthetimeelapsingbeforetheappearanceoftheliquidexudationsismorethanfiveminutes,thetesthavingbeencarriedoutatatemperatureof15°Cto25°C.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/149TestofblastingexplosiveforexudationFigure1:Bell-formcharge,mass2220g,capableofbeingsuspendedfromabronzepistonFigure2:Cylindricalbronzepiston,dimensionsinmmFigure3:Hollowbronzecylinder,closedatoneend;PlanandcutdimensionsinmmFigures1to3(1)4seriesof5holesat0,5Ν(2)copper(3)ironplatewithcentreconeattheinferiorface(4)4openings,approximately46x56,setatevenintervalsontheperipheryOfficialJournaloftheEuropeanUnionEN26.1.2004L18/1502.3.2.TestsrelatingtonitratedcellulosemixturesofClass4.12.3.2.1.Nitrocelluloseheatedforhalfanhourat132°Cshallnotgiveoffvisibleyellowish-brownnitrousfumes(nitrousgases).Theignitiontemperatureshallbeabove180°C.See2.3.2.3to2.3.2.8,2.3.2.9(a)and2.3.2.10.2.3.2.2.3gofplasticisednitrocellulose,heatedforonehourat132°C,shallnotgiveoffvisibleyellowish-brownnitrousfumes(nitrousgases).Theignitiontemperatureshallbeabove170°C.See2.3.2.3to2.3.2.8,2.3.2.9(b)and2.3.2.10below.2.3.2.3.Thetestproceduressetoutbelowaretobeappliedwhendifferencesofopinionariseastotheacceptabilityofsubstancesforcarriagebyroad.2.3.2.4.Ifothermethodsortestproceduresareusedtoverifytheconditionsofstabilityprescribedaboveinthissection,thosemethodsshallleadtothesamefindingsascouldbereachedbythemethodsspecifiedbelow.2.3.2.5.Incarryingoutthestabilitytestsbyheatingdescribedbelow,thetemperatureoftheovencontainingthesampleundertestshallnotdeviatebymorethan2°Cfromtheprescribedtemperature;theprescribeddurationofa30-minuteor60-minutetestshallbeobservedtowithintwominutes.Theovenshallbesuchthattherequiredtemperatureisrestorednotmorethanfiveminutesafterinsertionofthesample.2.3.2.6.Beforeundergoingthetestsin2.3.2.9and2.3.2.10,thesamplesshallbedriedfornotlessthan15hoursattheambienttemperatureinavacuumdesiccatorcontainingfusedandgranulatedcalciumchloride,thesamplesubstancebeingspreadinathinlayer;forthispurpose,substanceswhichareneitherinpowderformnorfibrousshallbeground,orgrated,orcutintosmallpieces.Thepressureinthedesiccatorshallbebroughtbelow6,5kPa(0,065bar).2.3.2.7.Beforebeingdriedasprescribedin2.3.2.6,substancesconformingto2.3.2.2shallundergopreliminarydryinginawell-ventilatedoven,withitstemperaturesetat70°C,untilthelossofmassperquarter-hourislessthan0,3%oftheoriginalmass.2.3.2.8.Weaklynitratednitrocelluloseconformingto2.3.2.1shallfirstundergopreliminarydryingasprescribedin2.3.2.7;dryingshallthenbecompletedbykeepingthenitrocelluloseforatleast15hoursoverconcentratedsulphuricacidinadesiccator.2.3.2.9.Testofchemicalstabilityunderheat(a)Testofthesubstancelistedinparagraph2.3.2.1.(i)Ineachoftwoglasstesttubeshavingthefollowingdimensions:length350mminternaldiameter16mmthicknessofwall1,5mmisplaced1gofsubstancedriedovercalciumchloride(ifnecessarythedryingshallbecarriedoutafterreducingthesubstancetopiecesweighingnotmorethan0,05geach).Bothtesttubes,completelycoveredwithloose-fittingclosures,arethensoplacedinanoventhatatleastfour-fifthsoftheirlengthisvisible,andarekeptataconstanttemperatureof132°Cfor30minutes.Itisobservedwhethernitrousgasesintheformofyellowish-brownfumesclearlyvisibleagainstawhitebackgroundaregivenoffduringthistime.(ii)Intheabsenceofsuchfumesthesubstanceisdeemedtobestable.(b)Testofplasticisednitrocellulose(see2.3.2.2).(i)3gofplasticisednitrocelluloseareplacedinglasstesttubes,similartothosereferredtoin(a),whicharethenplacedinanovenkeptataconstanttemperatureof132°C.(ii)Thetesttubescontainingtheplasticisednitrocellulosearekeptintheovenforonehour.Duringthistimenoyellowish-brownnitrousfumes(nitrousgases)shallbevisible.Observationandappraisalasin(a).2.3.2.10.Ignitiontemperature(see2.3.2.1and2.3.2.2)(a)Theignitiontemperatureisdeterminedbyheating0,2gofsubstanceenclosedinaglasstesttubeimmersedinaWood'salloybath.Thetesttubeisplacedinthebathwhenthelatterhasreached100°C.Thetemperatureofthebathisthenprogressivelyincreasedby5°Cperminute;(b)Thetesttubesmusthavethefollowingdimensions:length125mminternaldiameter15mmthicknessofwall0,5mmOfficialJournaloftheEuropeanUnionEN26.1.2004L18/151andshallbeimmersedtoadepthof20mm.(c)Thetestshallberepeatedthreetimes,thetemperatureatwhichignitionofthesubstanceoccurs,i.e.,sloworrapidcombustion,deflagrationordetonation,beingnotedeachtime.(d)Thelowesttemperaturerecordedinthethreetestsistheignitiontemperature.2.3.3.TestsrelatingtoflammableliquidsofClasses3,6.1and82.3.3.1.Testfordeterminingflash-point2.3.3.1.1.Theflash-pointshallbedeterminedbymeansofoneofthefollowingtypesofapparatus:(a)Abel;(b)Abel-Pensky;(c)tag;(d)Pensky-Martens;(e)apparatusinaccordancewithISO3679:1983orISO3680:1983.2.3.3.1.2.Todeterminetheflash-pointofpaints,gumsandsimilarviscousproductscontainingsolvents,onlyapparatusandtestmethodssuitablefordeterminingtheflash-pointforviscousliquidsshallbeused,inaccordancewiththefollowingstandards:(a)InternationalStandardISO3679:1983;(b)InternationalStandardISO3680:1983;(c)InternationalStandardISO1523:1983;(d)GermanStandardDIN53213:1978,Part1.2.3.3.1.3.Thetestprocedureshallbeeitheraccordingtoanequilibriummethodoraccordingtoanon-equilibriummethod.2.3.3.1.4.Fortheprocedureaccordingtoanequilibriummethod,see:(a)InternationalStandardISO1516:1981;(b)InternationalStandardISO3680:1983;(c)InternationalStandardISO1523:1983;(d)InternationalStandardISO3679:1983.2.3.3.1.5.Theprocedureaccordingtoanon-equilibriummethodshallbe:(a)fortheAbelapparatus,see:(i)BritishStandardBS2000Part170:1995;(ii)FrenchStandardNFMO7-011:1988;(iii)FrenchStandardNFT66-009:1969;(b)fortheAbel-Penskyapparatus,see:(i)GermanStandardDIN51755,Part1:1974(fortemperaturesfrom5°Cto65°C);(ii)GermanStandardDIN51755,Part2:1978(fortemperaturesbelow5°C);(iii)FrenchStandardNFMO7-036:1984;(c)forthetagapparatus,seeAmericanStandardASTMD56:1993;(d)forthePensky-Martensapparatus,see:(i)InternationalStandardISO2719:1988;(ii)EuropeanStandardEN22719ineachofitsnationalversions(e.g.BS2000,part404/EN22719):1994;(iii)AmericanStandardASTMD93:1994;(iv)InstituteofPetroleumStandardIP34:1988.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/1522.3.3.1.6.Thetestmethodslistedin2.3.3.1.4and2.3.3.1.5shallonlybeusedforflash-pointrangeswhicharespecifiedintheindividualmethods.Thepossibilityofchemicalreactionsbetweenthesubstanceandthesampleholdershallbeconsideredwhenselectingthemethodtobeused.Theapparatusshall,asfarasisconsistentwithsafety,beplacedinadraught-freeposition.Forsafety,amethodutilisingasmallsamplesize,around2ml,shallbeusedfororganicperoxidesandself-reactivesubstances(alsoknownas‘energetic’substances),orfortoxicsubstances.2.3.3.1.7.Whentheflash-point,determinedbyanon-equilibriummethodinaccordancewith2.3.3.1.5isfoundtobe23±2°Cor61±2°C,itshallbeconfirmedforeachtemperaturerangebyanequilibriummethodinaccordancewith2.3.3.1.4.2.3.3.1.8.Intheeventofadisputeastotheclassificationofaflammableliquid,theclassificationproposedbytheconsignorshallbeacceptedifacheck-testoftheflash-point,yieldsaresultnotdifferingbymorethan2°Cfromthelimits(23°Cand61°Crespectively)statedin2.2.3.1.Ifthedifferenceismorethan2°C,asecondcheck-testshallbecarriedout,andthelowestfigureoftheflash-pointsobtainedineithercheck-testshallbeadopted.2.3.3.2.TestfordeterminingperoxidecontentTodeterminetheperoxidecontentofaliquid,theprocedureisasfollows:Aquantityp(about5g,weighedtothenearest0,01g)oftheliquidtobetitratedisplacedinanErlenmeyerflask;20cm3ofaceticanhydrideandabout1gofpowderedsolidpotassiumiodideareadded;theflaskisshakenand,after10minutes,heatedfor3minutestoabout60°C.Whenithasbeenlefttocoolfor5minutes,25cm3ofwaterareadded.Afterthis,itisleftstandingforhalfanhour,thentheliberatediodineistitratedwithadecinormalsolutionofsodiumthiosulphate,noindicatorbeingadded;completediscolorationindicatestheendofthereaction.Ifnisthenumberofcm3ofthiosulphatesolutionrequired,thepercentageofperoxide(calculatedasH2O2)presentinthesampleisobtainedbytheformula:17n100p2.3.4.TestfordeterminingfluidityTodeterminethefluidityofliquid,viscousorpastysubstancesandmixtures,thefollowingtestmethodshallbeused.2.3.4.1.TestapparatusCommercialpenetrometerconformingtoISO2137:1985,withaguiderodof47,5g±0,05g;sievediscofduraluminwithconicalboresandamassof102,5g±0,05g(seeFigure1);penetrationvesselwithaninsidediameterof72mmto80mmforreceptionofthesample.2.3.4.2.TestprocedureThesampleispouredintothepenetrationvesselnotlessthanhalfanhourbeforethemeasurement.Thevesselisthenhermeticallyclosedandleftstandinguntilthemeasurement.Thesampleinthehermeticallyclosedpenetrationvesselisheatedto35°C±0,5°Candisplacedonthepenetrometertableimmediatelypriortomeasurement(notmorethantwominutes).ThepointSofthesievediscisthenbroughtintocontactwiththesurfaceoftheliquidandtherateofpenetrationismeasured.2.3.4.3.EvaluationoftestresultsAsubstanceispastyif,afterthecentreShasbeenbroughtintocontactwiththesurfaceofthesample,thepenetrationindicatedbythedialgauge:(a)afteraloadingtimeof5s±0,1s,islessthan15,0mm±0,3mm;or(b)afteraloadingtimeof5s±0,1s,isgreaterthan15,0mm±0,3mm,buttheadditionalpenetrationafteranother55s±0,5sislessthan5,0mm±0,5mm.NOTEInthecaseofsampleshavingaflowpoint,itisoftenimpossibletoproduceasteadylevelsurfaceinthepenetrationvesseland,hence,toestablishsatisfactoryinitialmeasuringconditionsforthecontactofthepointS.Furthermore,withsomesamples,theimpactofthesievedisccancauseanelasticdeformationofthesurfaceand,inthefirstfewseconds,simulateadeeperpenetration.Inallthesecases,itmaybeappropriatetomaketheevaluationin2.3.4.2.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/153Figure1—PenetrometerOfficialJournaloftheEuropeanUnionEN26.1.2004L18/1542.3.5.Testfordeterminingtheecotoxicity,persistenceandbioaccumulationofsubstancesintheaquaticenvironmentforassignmenttoClass9NOTEThetestmethodsusedshallbethoseadoptedbytheOrganisationforEconomicCooperationandDevelopment(OECD)andtheEuropeanCommission(EC).Ifothermethodsareused,theyshallbeinternationallyrecognised,beequivalenttotheOECD/ECtestsandbereferencedintestreports.2.3.5.1.AcutetoxicityforfishTheobjectistodeterminetheconcentrationwhichcauses50%mortalityinthetestspecies;thisisthe(LC50)value,namely,theconcentrationofthesubstanceinwaterwhichwillcausethedeathof50%ofatestgroupoffishduringacontinuousperiodoftestingofatleast96hours.Appropriatetypesoffishinclude:stripedbrill(Brachydaniorerio),fatheadminnow(Pimephalespromelas)andrainbowtrout(Oncorhynchusmykiss).Thefishareexposedtothetestsubstanceaddedtothewaterinvaryingconcentrations(+1control).Observationsarerecordedatleastevery24hours.Attheendofthe96-houractivityand,ifpossible,ateachobservation,theconcentrationcausingthedeathof50%ofthefishiscalculated.Thenoobservedeffectconcentration(NOEC)at96hoursisalsodetermined.2.3.5.2.AcutetoxicityfordaphniaTheobjectistodeterminetheeffectiveconcentrationofthesubstanceinwaterwhichrenders50%ofthedaphniaunabletoswim(EC50).Theappropriatetestorganismsaredaphniamagnaanddaphniapulex.Thedaphniaareexposedfor48hourstothetestsubstanceaddedtothewaterinvaryingconcentrations.Thenoobservedeffectconcentration(NOEC)at48hoursisalsodetermined.2.3.5.3.AlgalgrowthinhibitionTheobjectistodeterminetheeffectofachemicalonthegrowthofalgaeunderstandardconditions.Thechangeinbiomassandtherateofgrowthwithalgaeunderthesameconditions,butwithoutthepresenceofthetestchemical,arecomparedover72hours.Theresultsareexpressedastheeffectiveconcentrationwhichreducestherateofalgalgrowthby50%,IC50r,andalsotheformationofthebiomass,IC50b.2.3.5.4.TestsforreadybiodegradabilityTheobjectistodeterminethedegreeofbiodegradationunderstandardaerobicconditions.Thetestsubstanceisaddedinlowconcentrationstoanutrientsolutioncontainingaerobicbacteria.Theprogressofdegradationisfollowedfor28daysbydeterminingtheparameterspecifiedinthetestmethodused.Severalequivalenttestmethodsareavailable.Theparametersincludereductionofdissolvedorganiccarbon(DOC),carbondioxide(CO2)generationofoxygen(O2)depletion.Asubstanceisconsideredtobereadilybiodegradableifwithinnotmorethan28daysthefollowingcriteriaaresatisfied,within10daysfromwhendegradationfirstreaches10%:reductionofDOC:70%generationofCO2:60%oftheoreticalCO2productiondepletionofO2:60%oftheoreticalO2requirement.Thetestmaybecontinuedbeyond28daysiftheabovecriteriaarenotsatisfied,buttheresultwillrepresenttheinherentbiodegradabilityofthetestsubstance.Forassignmentpurposes,the‘ready’resultisnormallyrequired.WhereonlyCODandBOD5dataareavailable,asubstanceisconsideredtobereadilybiodegradableif:DBO5DCO≥0;5OfficialJournaloftheEuropeanUnionEN26.1.2004L18/155BOD(biochemicaloxygendemand)isdefinedasthemassofdissolvedoxygenrequiredbyaspecificvolumeofsolutionofthesubstancefortheprocessofbiochemicaloxidationunderprescribedconditions.TheresultisexpressedasgramsofBODpergramoftestsubstance.Thenormaltestperiodisfivedays(BOD5)usinganationalstandardtestprocedure.COD(chemicaloxygendemand)isameasureoftheoxidisabilityofasubstance,expressedastheequivalentamountinoxygenofanoxidisingreagentconsumedbythesubstanceunderfixedlaboratoryconditions.TheresultsareexpressedingramsofCODpergramofsubstance.Anationalstandardproceduremaybeused.2.3.5.5.Testsforbioaccumulationpotential2.3.5.5.1.Theobjectistodeterminethepotentialforbioaccumulationeitherbytheratioatequilibriumoftheconcentration(c)ofasubstanceinasolventtothatinwaterorbythebioconcentrationfactor(BCF).2.3.5.5.2.Theratioatequilibriumoftheconcentration(c)ofasubstanceinasolventtothatinwaterisnormallyexpressedasalog10.Thesolventandwatershallhavenegligiblemiscibilityandthesubstanceshallnotioniseinwater.Thesolventnormallyusedisn-octanol.Inthecaseofn-octanolandwater,theresultis:logPow¼log10cocw(cid:3)(cid:4)wherePowisthepartitioncoefficientobtainedbydividingtheconcentrationofthesubstanceinn-octanol(co)bytheconcentrationofthesubstanceinwater(Cw).IflogPow≥3,0thenthesubstancehasapotentialtobioaccumulate.2.3.5.5.3.Thebioconcentrationfactor(BCF)isdefinedastheratiooftheconcentrationofthetestsubstanceinthetestfish(cf)totheconcentrationinthetestwater(cw)atsteadystate:BCF¼cfðÞcwðÞ:Theprincipleofthetestinvolvesexposingfishtoasolutionordispersionatknownconcentrationsofthetestsubstanceinwater.Continuousflow,staticorsemi-staticproceduresmaybeusedaccordingtothetestprocedureselected,basedonthepropertiesofthetestsubstances.Fishareexposedtothetestsubstancesoveragivenperiodoftime,followedbyaperiodofnofurtherexposure.Duringthesecondperiod,measurementsaremadeoftherateofincreaseinthewaterofthetestsubstance(i.e.therateofexcretionordepuration).(FulldetailsofthevarioustestproceduresandthecalculationmethodfortheBCFaregivenintheOECDGuidelinesfortestingofchemicals,methods305Ato305E,12May1981).2.3.5.5.4.AsubstancemayhavealogPowgreaterthan3andaBCFlessthan100whichwouldindicatelittleornopotentialtobioaccumulate.Incasesofdoubt,theBCFvaluetakesprecedenceoverlogPow,asindicatedintheflowchartoftheprocedurein2.3.5.7.2.3.5.6.CriteriaAsubstancemayberegardedasapollutanttotheaquaticenvironmentifitsatisfiesoneofthefollowingcriteria:Thelowestofthevaluesofthe96-hourLC50forfish,the48-hourEC50fordaphniaorthe72-hourIC50foralgae—islessthanorequalto1mg/l,—isgreaterthan1mg/lbutlessthanorequalto10mg/l,andthesubstanceisnotbiodegradable,—isgreaterthan1mg/lbutlessthanorequalto10mg/l,andthelogPowisgreaterthanorequalto3,0(unlesstheexperimentallydeterminedBCFislessthanorequalto100).OfficialJournaloftheEuropeanUnionEN26.1.2004L18/1562.3.5.7.ProceduretobefollowedOfficialJournaloftheEuropeanUnionEN26.1.2004L18/157Part3DANGEROUSGOODSLIST,SPECIALPROVISIONSANDEXEMPTIONSRELATEDTODANGEROUSGOODSPACKEDINLIMITEDQUANTITIESChapter3.1General3.1.1.IntroductionInadditiontotheprovisionsreferredtoorgiveninthetablesofthispart,thegeneralrequirementsofeachpart,chapterand/orsectionaretobeobserved.Thesegeneralrequirementsarenotgiveninthetables.Whenageneralrequirementiscontradictorytoaspecialprovision,thespecialprovisionprevails.3.1.2.Propershippingname3.1.2.1.ThepropershippingnameisthatportionoftheentrymostaccuratelydescribingthegoodsinTableAinChapter3.2,whichisshowninuppercasecharacters(plusanynumbers,Greekletters,‘sec’,‘tert’,andtheletters‘m’,‘n’,‘o’,‘p’,whichformanintegralpartofthename).Analternativepropershippingnamemaybeshowninbracketsfollowingthemainpropershippingname(e.g.,ETHANOL(ETHYLALCOHOL)).Portionsofanentryappearinginlowercaseneednotbeconsideredaspartofthepropershippingname.3.1.2.2.Whenconjunctionssuchas‘and’or‘or’areinlowercaseorwhensegmentsofthenamearepunctuatedbycommas,theentirenameoftheentryneednotnecessarilybeshowninthetransportdocumentorpackagemarkings.ThisisthecaseparticularlywhenacombinationofseveraldistinctentriesarelistedunderasingleUNnumber.Examplesillustratingtheselectionofthepropershippingnameforsuchentriesare:(a)UNNo1057LIGHTERSorLIGHTERREFILLS—Thepropershippingnameisthemostappropriateofthefollowingpossiblecombinations:LIGHTERSLIGHTERREFILLS;(b)UNNo3207ORGANOMETALLICCOMPOUNDorCOMPOUNDSOLUTIONorCOMPOUNDDISPERSION,WATER-REACTIVE,FLAMMABLE,N.O.S.Thepropershippingnameisthemostappropriateofthefollowingpossiblecombinations:ORGANOMETALLICCOMPOUND,WATER-REACTIVE,FLAMMABLE,N.O.S.ORGANOMETALLICCOMPOUNDSOLUTION,WATER-REACTIVE,FLAMMABLE,N.O.S.ORGANOMETALLICCOMPOUNDDISPERSION,WATER-REACTIVE,FLAMMABLE,N.O.S.eachsupplementedwiththetechnicalnameofthegoods(see3.1.2.6.1).3.1.2.3.Propershippingnamesmaybeusedinthesingularorpluralasappropriate.Inaddition,whenqualifyingwordsareusedaspartofthepropershippingname,theirsequenceondocumentationorpackagemarkingsisoptional.Forinstance,‘DIMETHYLAMINEAQUEOUSSOLUTION’mayalternativelybeshown‘AQUEOUSSOLUTIONOFDIMETHYLAMINE’.CommercialormilitarynamesforgoodsofClass1whichcontainthepropershippingnamesupplementedbyadditionaldescriptivetextmaybeused.3.1.2.4.UnlessitisalreadyincludedincapitallettersinthenameindicatedinTableAinChapter3.2,thequalifyingword‘LIQUID’or‘SOLID’,asappropriate,shallbeaddedaspartofthepropershippingnamewhenasubstancementionedbynamemay,duetothedifferingphysicalstatesofthevariousisomersofthesubstance,beeitheraliquidorasolid(e.g.DINITROTOLUENES,LIQUID;DINITROTO-LUENES,SOLID).3.1.2.5.UnlessitisalreadyincludedincapitallettersinthenameindicatedinTableAinChapter3.2,thequalifyingword‘MOLTEN’shallbeaddedaspartofthepropershippingnamewhenasubstance,whichisasolidinaccordancewiththedefinitionin1.2.1,isofferedforcarriageinthemoltenstate(e.g.ALKYLPHENOL,SOLID,N.O.S.,MOLTEN).OfficialJournaloftheEuropeanUnionEN26.1.2004L18/1583.1.2.6.Genericor‘nototherwisespecified’(N.O.S.)names3.1.2.6.1.Forthepurposesofdocumentationandmarkingofpackages,whenan‘N.O.S.’or‘generic’propershippingnameisused,thepropershippingnameshallbesupplementedwiththetechnicalnameofthegoods,unlessanationallaworinternationalconventionprohibitsitsdisclosureifitisacontrolledsubstance.Theparticular‘N.O.S.’or‘generic’entriesforwhichthissupplementaryinformationisconsiderednecessaryhavebeenallocatedspecialprovision274incolumn6ofTableAinChapter3.2.3.1.2.6.1.1.Thetechnicalnameshallbeshowninparenthesesimmediatelyfollowingthepropershippingname.Itshallbearecognisedchemicalorothernamecurrentlyusedinscientificandtechnicalhandbooks,journalsandtexts.Tradenamesshallnotbeusedforthispurpose.Inthecaseofpesticides,onlyISOcommonname(s),othername(s)intheWHORecommendedclassificationofpesticidesbyhazardandguidelinestoclassification,orthename(s)oftheactivesubstance(s)maybeused.3.1.2.6.1.2.Whenamixtureofdangerousgoodsisdescribedbyoneofthe‘N.O.S.’or‘generic’entriestowhichspecialprovision274hasbeenallocatedincolumn6ofTableAinChapter3.2,notmorethanthetwoconstituentswhichmostpredominantlycontributetothehazardorhazardsofamixtureneedtobeshown,excludingcontrolledsubstanceswhentheirdisclosureisprohibitedbynationallaworinternationalconvention.Ifapackagecontainingamixtureislabelledwithanysubsidiaryrisklabel,oneofthetwotechnicalnamesshowninparenthesesshallbethenameoftheconstituentwhichcompelstheuseofthesubsidiaryrisklabel.Note:see5.4.1.2.2.3.1.2.6.1.3.ExamplesillustratingtheselectionofthepropershippingnamesupplementedwiththetechnicalnameofgoodsforsuchN.O.S.entriesare:UNNo2003METALALKYL,WATER-REACTIVE,N.O.S.(trimethylgallium)UNNo2902PESTICIDE,LIQUID,TOXIC,N.O.S.(drazoxolon).3.1.2.7.MixturesandsolutionscontainingonedangeroussubstanceWhenmixturesandsolutionshavetoberegardedasthedangeroussubstancementionedbynameinaccordancewiththeclassificationrequirementsof2.1.3.3,thequalifyingword‘SOLUTION’or‘MIXTURE’,asappropriate,shallbeaddedaspartofthepropershippingname,e.g.‘ACETONESOLUTION’.Inaddition,theconcentrationofthesolutionormixturemayalsobeindicated,e.g.‘ACETONE75%SOLUTION’.Chapter3.2Dangerousgoodslist3.2.1.TableA:DangerousgoodslistExplanationsAsarule,eachrowofTableAofthischapterdealswiththesubstance(s)orarticle(s)coveredbyaspecificUNnumber.However,whensubstancesorarticlesbelongingtothesameUNnumberhavedifferentchemicalproperties,physicalpropertiesand/orcarriageconditions,severalconsecutiverowsmaybeusedforthatUNnumber.EachcolumnofTableAisdedicatedtoaspecificsubjectasindicatedintheexplanatorynotesbelow.Theintersectionofcolumnsandrows(cell)containsinformationconcerningthesubjecttreatedinthatcolumn,forthesubstance(s)orarticle(s)ofthatrow:—thefirstfourcellsidentifythesubstance(s)orarticle(s)belongingtothatrow(additionalinformationinthatrespectmaybegivenbythespecialprovisionsreferredtoincolumn6;—thefollowingcellsgivetheapplicablespecialprovisions,eitherintheformofcompleteinformationorincodedform.Thecodescross-refertodetailedinformationthatistobefoundinthepart,chapter,sectionand/orsubsectionindicatedintheexplanatorynotesbelow.Anemptycellmeanseitherthatthereisnospecialprovisionandthatonlythegeneralrequirementsapply,orthatthecarriagerestrictionindicatedintheexplanatorynotesisinforce.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/159Theapplicablegeneralrequirementsarenotreferredtointhecorrespondingcells.Theexplanatorynotesbelowindicateforeverycolumnthepart(s),chapter(s),section(s)and/orsubsection(s)wherethesearetobefound.Explanatorynotesforeachcolumn:column1‘UNNo’ContainstheUNnumber:—ofthedangeroussubstanceorarticleifthesubstanceorarticlehasbeenassigneditsownspecificUNnumber,or—ofthegenericorn.o.s.entrytowhichthedangeroussubstancesorarticlesnotmentionedbynameshallbeassignedinaccordancewiththecriteria(decisiontrees)ofPart2.column2‘Nameanddescription’Contains,inuppercasecharacters,thenameofthesubstanceorarticle,ifthesubstanceorarticlehasbeenassigneditsownspecificUNnumber,orofthegenericorn.o.s.entrytowhichithasbeenassignedinaccordancewiththecriteria(‘decisiontrees’)ofPart2.Thisnameshallbeusedasthepropershippingnameor,whenapplicable,aspartofthepropershippingname(see3.1.2forfurtherdetailsonthepropershippingname).Adescriptivetextinlowercasecharactersisaddedafterthepropershippingnametoclarifythescopeoftheentryiftheclassificationand/orcarriageconditionsofthesubstanceorarticlemaybedifferentundercertainconditions.column(3a)‘Class’Containsthenumberoftheclass,whoseheadingcoversthedangeroussubstanceorarticle.ThisclassnumberisassignedinaccordancewiththeproceduresandcriteriaofPart2.column(3b)‘Classificationcode’Containstheclassificationcodeofthedangeroussubstanceorarticle.—fordangeroussubstancesorarticlesofClass1,thecodeconsistsofadivisionnumberandcompatibilitygroupletter,whichareassignedinaccordancewiththeproceduresandcriteriaof2.2.1.1.4,—fordangeroussubstancesorarticlesofClass2,thecodeconsistsofanumberandhazardouspropertygroup,whichareexplainedin2.2.2.1.2and2.2.2.1.3,—fordangeroussubstancesorarticlesofClasses3,4.1,4.2,4.3,5.1,5.2,6.1,6.2,8and9,thecodesareexplainedin2.2.×.1.2(1),—dangeroussubstancesorarticlesofClass7donothaveaclassificationcode.column4‘Packinggroup’Containsthepackinggroupnumber(s)(I,IIorIII)assignedtothedangeroussubstance.ThesepackinggroupnumbersareassignedonthebasisoftheproceduresandcriteriaofPart2.Certainarticlesandsubstancesarenotassignedtopackinggroups.column5‘Labels’Containsthemodelnumberofthelabels/placards(see5.2.2.2and5.3.1.7)thathavetobeaffixedtopackages,containers,tank-containers,portabletanks,MEGCsandvehicles.However:—forsubstancesorarticlesofClass7,7XmeanslabelmodelNo7A,7Bor7Casappropriateaccordingtothecategory(see2.2.7.8.4and5.2.2.1.11.1)orplacardNo7D(see5.3.1.1.3and5.3.1.7.2),—labelsofmodelNo11arenotindicatedinthiscolumn;5.2.2.1.12istobeconsultedineverycase.Thegeneralprovisionsonlabelling/placarding(e.g.numberoflabels,theirlocation)aretobefoundin5.2.2.1forpackages,andin5.3.1,forcontainers,tank-containers,MEGCs,portabletanksandvehicles.Note:Specialprovisions,indicatedincolumn6,maychangetheabovelabellingprovisions.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/160(1)x=theclassnumberofthedangeroussubstanceorarticle,withoutdividingpointifapplicable.column6‘Specialprovisions’Containsthenumericcodesofspecialprovisionsthathavetobemet.Theseprovisionsconcernawidearrayofsubjects,mainlyconnectedwiththecontentsofcolumns1to5(e.g.carriageprohibitions,exemptionsfromrequirements,explanationsconcerningtheclassificationofcertainformsofthedangerousgoodsconcernedandadditionallabellingormarkingprovisions),andarelistedinChapter3.3innumericalorder.Ifcolumn6isempty,nospecialprovisionsapplytothecontentsofcolumns1to5forthedangerousgoodsconcerned.column7‘Limitedquantities’Containsanalphanumericcodewiththefollowingmeaning:—‘LQ0’signifiesthatnoexemptionfromtheprovisionsofthisDirectiveexistsforthedangerousgoodspackedinlimitedquantities,—alltheotheralphanumericcodesstartingwiththeletters‘LQ’signifythattheprovisionsofthisDirectivearenotapplicableiftheconditionsindicatedinchapter3.4arefulfilled(generalconditionsof3.4.1andconditionsof3.4.3,3.4.4,3.4.5and3.4.6,asappropriate,fortherelevantcode).column8‘Packinginstructions’Containsthealphanumericcodesoftheapplicablepackinginstructions:—alphanumericcodesstartingwiththeletter‘P’,whichreferstopackinginstructionsforpackagingsandreceptacles(exceptIBCsandlargepackagings),or‘R’,whichreferstopackinginstructionsforlightgaugemetalpackagings.Thesearelistedin4.1.4.1innumericalorder,andspecifythepackagingsandreceptaclesthatareauthorised.Theyalsoindicatewhichofthegeneralpackingprovisionsof4.1.1,4.1.2and4.1.3,andwhichofthespecialpackingprovisionsof4.1.5,4.1.6,4.1.7,4.1.8and4.1.9havetobemet.Ifcolumn8doesnotcontainacodestartingwiththeletters‘P’or‘R’,thedangerousgoodsconcernedmaynotbecarriedinpackagings,—alphanumericcodesstartingwiththeletters‘IBC’refertopackinginstructionsforIBCs.Thesearelistedin4.1.4.2innumericalorder,andspecifytheIBCsthatareauthorised.Theyalsoindicatewhichofthegeneralpackingprovisionsof4.1.1,4.1.2and4.1.3,andwhichofthespecialpackingprovisionsof4.1.5,4.1.6,4.1.7,4.1.8and4.1.9havetobemet.Ifcolumn8doesnotcontainacodestartingwiththeletters‘IBC’,thedangerousgoodsconcernedmaynotbecarriedinIBCs,—alphanumericcodesstartingwiththeletters‘LP’refertopackinginstructionsforlargepackagings.Thesearelistedin4.1.4.3innumericalorder,andspecifythelargepackagingsthatareauthorised.Theyalsoindicatewhichofthegeneralpackingprovisionsof4.1.1,4.1.2and4.1.3,andwhichofthespecialpackingprovisionsof4.1.5,4.1.6,4.1.7,4.1.8and4.1.9havetobemet.Ifcolumn8doesnotcontainacodestartingwiththeletters‘LP’,thedangerousgoodsconcernedcannotbecarriedinlargepackagings,—alphanumericalcodesstartingwithletters‘PR’refertopackinginstructionsforparticularpressurereceptacles.Thesearelistedin4.1.4.4innumericalorder,andspecifythepressurereceptaclesthatareauthorised.Theyalsoindicatewhichofthegeneralpackingprovisionsof4.1.1,4.1.2and4.1.3,andwhichofthespecialpackingprovisionsof4.1.5,4.1.6,4.1.7,4.1.8and4.1.9havetobemet.Note:Specialpackingprovisions,indicatedincolumn9a,maychangetheabovepackinginstructions.column9a‘Specialpackingprovisions’Containsthealphanumericcodesoftheapplicablespecialpackingprovisions:—alphanumericcodesstartingwiththeletters‘PP’or‘RR’refertospecialpackingprovisionsforpackagingsandreceptacles(exceptIBCsandlargepackagings)thathaveadditionallytobemet.Thesearetobefoundin4.1.4.1,attheendoftherelevantpackinginstruction(withtheletter‘P’or‘R’)referredtoincolumn8.Ifcolumn9adoesnotcontainacodestartingwiththeletters‘PP’or‘RR’,noneofthespecialpackingprovisionslistedattheendoftherelevantpackinginstructionapply,OfficialJournaloftheEuropeanUnionEN26.1.2004L18/161—alphanumericcodesstartingwiththeletter‘B’refertospecialpackingprovisionsforIBCsthathaveadditionallytobemet.Thesearetobefoundin4.1.4.2,attheendoftherelevantpackinginstruction(withtheletters‘IBC’)referredtoincolumn8.Ifcolumn9adoesnotcontainacodestartingwiththeletter‘B’,noneofthespecialpackingprovisionslistedattheendoftherelevantpackinginstructionapply,—alphanumericcodesstartingwiththeletter‘L’refertospecialpackingprovisionsforlargepackagingsthathaveadditionallytobemet.Thesearetobefoundin4.1.4.3,attheendoftherelevantpackinginstruction(withtheletters‘LP’)referredtoincolumn8.Ifcolumn9adoesnotcontainacodestartingwiththeletter‘L’,noneofthespecialpackingprovisionslistedattheendoftherelevantpackinginstructionapply.column9b‘Mixedpackingprovisions’Containsthealphanumericcodesstartingwiththeletters‘MP’oftheapplicablemixedpackingprovisions.Thesearelistedin4.1.10innumericalorder.Ifcolumn9bdoesnotcontainacodestartingwiththeletters‘MP’,onlythegeneralrequirementsapply(see4.1.1.5and4.1.1.6).column10‘Portabletanksinstructions’Containsanalphanumericcodeassignedtoaportabletankinstruction,inaccordancewith4.2.4.2.1to4.2.4.2.4and4.2.4.2.6.Thisportabletankinstructioncorrespondstotheleaststringentprovisionsthatareacceptableforthecarriageofthesubstanceinportabletanks.Thecodesidentifyingtheotherportabletankinstructionsthatarealsopermittedforthecarriageofthesubstancearetobefoundin4.2.4.2.5.Ifnocodeisgiven,carriageinportabletanksisnotpermitted.Thegeneralrequirementsforthedesign,construction,equipment,typeapproval,testingandmarkingofportabletanksaretobefoundinchapter6.7.Thegeneralrequirementsfortheuse(e.g.filling)aretobefoundin4.2.1to4.2.3.Note:Specialprovisions,indicatedincolumn11,maychangetheaboverequirements.column11‘Portabletankspecialprovisions’Containsthealphanumericcodesoftheportabletankspecialprovisionsthathaveadditionallytobemet.Thesecodes,startingwiththeletters‘TP’refertospecialprovisionsfortheconstructionoruseoftheseportabletanks.Theyaretobefoundin4.2.4.3.column12‘TankcodesforADRtanks’Containsanalphanumericcodedescribingatanktype,inaccordancewith4.3.3.1.1(forgasesofclass2)or4.3.4.1.1(forsubstancesofclasses3to9).ThistanktypecorrespondstotheleaststringenttankprovisionsthatareacceptableforthecarriageoftherelevantsubstanceinADRtanks.Thecodesdescribingtheotherpermittedtanktypesaretobefoundin4.3.3.1.2(forgasesofclass2)or4.3.4.1.2(forsubstancesofclasses3to9).Ifnocodeisgiven,carriageinADRtanksisnotpermitted.Ifinthiscolumnatankcodeforsolids(S)andforliquids(L)isindicated,thismeansthatthissubstancemaybecarriedinthesolidortheliquid(molten)state.Ingeneralthisprovisionisapplicabletosubstanceshavingmeltingpointsfrom20°Cto180°C.Thegeneralrequirementsfortheconstruction,equipment,typeapproval,testingandmarkingthatarenotindicatedinthetankcodearetobefoundin6.8.1,6.8.2,6.8.3and6.8.5.Thegeneralrequirementsfortheuse(e.g.maximumdegreeoffilling,minimumtestpressure)aretobefoundin4.3.1to4.3.4.Theindicationofa‘(M)’afterthetankcodemeansthatthesubstancecanalsobecarriedinbattery-vehiclesorMEGCs.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/162Theindicationofa‘(+)’afterthetankcodemeansthatthealternativeuseoftanksandthehierarchyof4.3.4.1.3isnotapplicable.Forfibre-reinforcedplastictanks,see4.4.1andchapter6.9;forvacuumoperatedwastetanks,see4.5.1andchapter6.10.Note:Specialprovisions,indicatedincolumn13,maychangetheaboverequirements.column13‘SpecialprovisionsforADRtanks’ContainsthealphanumericcodesofthespecialprovisionsforADRtanksthathaveadditionallytobemet:—alphanumericcodesstartingwiththeletters‘TU’refertospecialprovisionsfortheuseofthesetanks.Thesearetobefoundin4.3.5,—alphanumericcodesstartingwiththeletters‘TC’refertospecialprovisionsfortheconstructionofthesetanks.Thesearetobefoundin6.8.4(a),—alphanumericcodesstartingwiththeletters‘TE’refertospecialprovisionsconcerningtheitemsofequipmentofthesetanks.Thesearetobefoundin6.8.4(b),—alphanumericcodesstartingwiththeletters‘TA’refertospecialprovisionsforthetypeapprovalofthesetanks.Thesearetobefoundin6.8.4(c),—alphanumericcodesstartingwiththeletters‘TT’refertospecialprovisionsforthetestingofthesetanks.Thesearetobefoundin6.8.4(d),—alphanumericcodesstartingwiththeletters‘TM’refertospecialprovisionsforthemarkingofthesetanks.Thesearetobefoundin6.8.4(e).column14‘Vehiclefortankcarriage’Containsacodedesignatingthevehicle(see9.1.1)tobeusedforthecarriageofthesubstanceintankinaccordancewith7.4.2.TherequirementsconcerningtheconstructionandapprovalofvehiclesaretobefoundinChapters9.1,9.2and9.7.column15‘Transportcategory’Containsafigureindicatingthetransportcategorytowhichthesubstanceorarticleisassignedforthepurposesofexemptionrelatedtoquantitiescarriedpertransportunit(see1.1.3.6).column16‘Specialprovisionsforcarriage—Packages’Containsthealphanumericcode(s),startingwithletter‘V’,oftheapplicablespecialprovisions(ifany)forcarriageinpackages.Thesearelistedin7.2.4.Generalprovisionsconcerningthecarriageinpackagesaretobefoundinchapters7.1and7.2.Note:Inaddition,specialprovisionsindicatedincolumn18,concerningloading,unloadingandhandling,shallbeobserved.column17‘Specialprovisionsforcarriage—Bulk’Containsthealphanumericcode(s),startingwithletters‘VV’,oftheapplicablespecialprovisionsforcarriageinbulk.Thesearelistedin7.3.3.Ifnocodeisgiven,carriageinbulkisnotpermitted.Generalprovisionsconcerningthecarriageinbulkaretobefoundinchapters7.1and7.3.Note:Inaddition,specialprovisionsindicatedincolumn18,concerningloading,unloadingandhandling,shallbeobserved.column18‘Specialprovisionsforcarriage—Loadingandunloading’Containsthealphanumericcode(s),startingwithletters‘CV’,oftheapplicablespecialprovisionsforloading,unloadingandhandling.Thesearelistedin7.5.11.Ifnocodeisgiven,onlythegeneralprovisionsapply(see7.5.1to7.5.10).OfficialJournaloftheEuropeanUnionEN26.1.2004L18/163column19‘Specialprovisionsforcarriage—Operation’Containsthealphanumericcode(s),startingwithletter‘S’,oftheapplicablespecialprovisionsforoperationwhicharelistedinchapter8.5.Theseprovisionsshallbeappliedinadditiontotherequirementsofchapters8.1to8.4butintheeventofconflictwiththerequirementsofchapters8.1to8.4,thespecialprovisionsshalltakeprecedence.column20‘Hazardidentificationnumber’Containsatwoorthree-figurenumber(insomecasesprefixedbytheletter‘X’)whichshallappearontheupperpartoftheorange-colouredplatewhenrequiredforcarriageintankorinbulkaccordingto5.3.2.1.Themeaningofthehazardidentificationnumbersisexplainedin5.3.2.3.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/164UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)0004AMMONIUMPICRATEdryorwettedwithlessthan10%water,bymass11.1D1LQ0P112(a)(b)(c)PP26MP201V2V3CV1CV2CV3S10005CARTRIDGESFORWEAPONSwithburstingcharge11.1F1LQ0P130MP231V2CV1CV2CV3S10006CARTRIDGESFORWEAPONSwithburstingcharge11.1E1LQ0P130LP101PP67L1MP211V2CV1CV2CV3S10007CARTRIDGESFORWEAPONSwithburstingcharge11.2F1LQ0P130MP231V2CV1CV2CV3S10009AMMUNITION,INCENDIARYwithorwithoutburster,expellingchargeorpropellingcharge11.2G1LQ0P130LP101PP67L1MP231V2CV1CV2CV3S10010AMMUNITION,INCENDIARYwithorwithoutburster,expellingchargeorpropellingcharge11.3G1LQ0P130LP101PP67L1MP231V2CV1CV2CV3S10012CARTRIDGESFORWEAPONS,INERTPROJEC-TILEorCARTRIDGES,SMALLARMS11.4S1.4LQ0P130MP23MP244V2CV1CV2CV3S1OfficialJournaloftheEuropeanUnionEN26.1.2004L18/165UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)0014CARTRIDGESFORWEAPONS,BLANKorCARTRIDGES,SMALLARMS,BLANK11.4S1.4LQ0P130MP23MP244V2CV1CV2CV3S10015AMMUNITION,SMOKEwithorwithoutburster,expellingchargeorpropellingcharge11.2G1+8204LQ0P130LP101PP67L1MP231V2CV1CV2CV3S10016AMMUNITION,SMOKEwithorwithoutburster,expellingchargeorpropellingcharge11.3G1+8204LQ0P130LP101PP67L1MP231V2CV1CV2CV3S10018AMMUNITION,TEAR-PRODUCINGwithburster,expellingchargeorpropel-lingcharge11.2G1+6.1+8LQ0P130LP101PP67L1MP231V2CV1CV2CV3CV28S10019AMMUNITION,TEAR-PRODUCINGwithburster,expellingchargeorpropel-lingcharge11.3G1+6.1+8LQ0P130LP101PP67L1MP231V2CV1CV2CV3CV28S10020AMMUNITION,TOXICwithburster,expellingchargeorpropellingcharge11.2KCARRIAGEPROHIBITED0021AMMUNITION,TOXICwithburster,expellingchargeorpropellingcharge11.3KCARRIAGEPROHIBITEDOfficialJournaloftheEuropeanUnionEN26.1.2004L18/166UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)0027BLACKPOWDER(GUNPOWDER),granularorasameal11.1D1LQ0P113PP50MP20MP241V2V3CV1CV2CV3S10028BLACKPOWDER(GUNPOWDER),COMPRESSEDorBLACKPOWDER(GUNPOWDER),INPELLETS11.1D1LQ0P113PP51MP20MP241V2CV1CV2CV3S10029DETONATORS,NON-ELEC-TRICforblasting11.1B1LQ0P131PP68MP231V2CV1CV2CV3S10030DETONATORS,ELECTRICforblasting11.1B1LQ0P131MP231V2CV1CV2CV3S10033BOMBSwithburstingcharge11.1F1LQ0P130MP231V2CV1CV2CV3S10034BOMBSwithburstingcharge11.1D1LQ0P130LP101PP67L1MP211V2CV1CV2CV3S10035BOMBSwithburstingcharge11.2D1LQ0P130LP101PP67L1MP211V2CV1CV2CV3S10037BOMBS,PHOTO-FLASH11.1F1LQ0P130MP231V2CV1CV2CV3S1OfficialJournaloftheEuropeanUnionEN26.1.2004L18/167UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)0038BOMBS,PHOTO-FLASH11.1D1LQ0P130LP101PP67L1MP211V2CV1CV2CV3S10039BOMBS,PHOTO-FLASH11.2G1LQ0P130LP101PP67L1MP231V2CV1CV2CV3S10042BOOSTERSwithoutdeto-nator11.1D1LQ0P132MP211V2CV1CV2CV3S10043BURSTERS,explosive11.1D1LQ0P133PP69MP211V2CV1CV2CV3S10044PRIMERS,CAPTYPE11.4S1.4LQ0P133MP23MP244V2CV1CV2CV3S10048CHARGES,DEMOLITION11.1D1LQ0P130LP101PP67L1MP211V2CV1CV2CV3S10049CARTRIDGES,FLASH11.1G1LQ0P135MP231V2CV1CV2CV3S10050CARTRIDGES,FLASH11.3G1LQ0P135MP231V2CV1CV2CV3S1OfficialJournaloftheEuropeanUnionEN26.1.2004L18/168UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)0054CARTRIDGES,SIGNAL11.3G1LQ0P135MP23MP241V2CV1CV2CV3S10055CASES,CARTRIDGE,EMPTY,WITHPRIMER11.4S1.4LQ0P136MP234V2CV1CV2CV3S10056CHARGES,DEPTH11.1D1LQ0P130LP101PP67L1MP211V2CV1CV2CV3S10059CHARGES,SHAPEDwithoutdetonator11.1D1LQ0P137PP70MP211V2CV1CV2CV3S10060CHARGES,SUPPLEMEN-TARY,EXPLOSIVE11.1D1LQ0P132MP211V2CV1CV2CV3S10065CORD,DETONATING,flex-ible11.1D1LQ0P139PP71PP72MP211V2CV1CV2CV3S10066CORD,IGNITER11.4G1.4LQ0P140MP232V2CV1CV2CV3S10070CUTTERS,CABLE,EXPLO-SIVE11.4S1.4LQ0P134LP102MP234V2CV1CV2CV3S1OfficialJournaloftheEuropeanUnionEN26.1.2004L18/169UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)0072CYCLOTRIMETHYLENE-TRINITRAMINE(CYCLO-NITE;HEXOGEN;RDX),WETTEDwithnotlessthan15%water,bymass11.1D1266LQ0P112(a)PP45MP201V2CV1CV2CV3S10073DETONATORSFORAMMU-NITION11.1B1LQ0P133MP231V2CV1CV2CV3S10074DIAZODINITROPHENOL,WETTEDwithnotlessthan40%water,ormixtureofalcoholandwater,bymass11.1A1266LQ0P110(b)PP42MP200V2CV1CV2CV3S10075DIETHYLENEGLYCOLDINI-TRATE,DESENSITISEDwithnotlessthan25%non-volatile,water-insolublephlegmatiser,bymass11.1D1266LQ0P115PP53PP54PP57PP58MP201V2CV1CV2CV3S10076DINITROPHENOL,dryorwettedwithlessthan15%water,bymass11.1D1+6.1LQ0P112(a)(b)(c)PP26MP201V2V3CV1CV2CV3CV28S10077DINITROPHENOLATES,alkalimetals,dryorwettedwithlessthan15%water,bymass11.3C1+6.1LQ0P114(a)(b)PP26MP201V2V3CV1CV2CV3CV28S1OfficialJournaloftheEuropeanUnionEN26.1.2004L18/170UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)0078DINITRORESORCINOL,dryorwettedwithlessthan15%water,bymass11.1D1LQ0P112(a)(b)(c)PP26MP201V2V3CV1CV2CV3S10079HEXANITRODIPHENYL-AMINE(DIPICRYLAMINE;HEXYL)11.1D1LQ0P112(b)(c)MP201V2V3CV1CV2CV3S10081EXPLOSIVE,BLASTING,TYPEA11.1D1616617LQ0P116PP63PP66MP201V2V3CV1CV2CV3S10082EXPLOSIVE,BLASTING,TYPEB11.1D1617LQ0P116IBC100PP61PP62PP65B9MP201V2V3CV1CV2CV3S10083EXPLOSIVE,BLASTING,TYPEC11.1D1267617LQ0P116MP201V2V3CV1CV2CV3S10084EXPLOSIVE,BLASTING,TYPED11.1D1617LQ0P116MP201V2CV1CV2CV3S10092FLARES,SURFACE11.3G1LQ0P135MP231V2CV1CV2CV3S1OfficialJournaloftheEuropeanUnionEN26.1.2004L18/171UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)0093FLARES,AERIAL11.3G1LQ0P135MP231V2CV1CV2CV3S10094FLASHPOWDER11.1G1LQ0P113PP49MP201V2V3CV1CV2CV3S10099FRACTURINGDEVICES,EXPLOSIVEwithoutdeto-nator,foroilwells11.1D1LQ0P134LP102MP211V2CV1CV2CV3S10101FUSE,NON-DETONATING11.3G1LQ0P140PP74PP75MP231V2CV1CV2CV3S10102CORD(FUSE),DETO-NATING,metalclad11.2D1LQ0P139PP71MP211V2CV1CV2CV3S10103FUSE,IGNITER,tubular,metalclad11.4G1.4LQ0P140MP232V2CV1CV2CV3S10104CORD(FUSE),DETO-NATING,MILDEFFECT,metalclad11.4D1.4LQ0P139PP71MP212V2CV1CV2CV3S10105FUSE,SAFETY11.4S1.4LQ0P140PP73MP234V2CV1CV2CV3S1OfficialJournaloftheEuropeanUnionEN26.1.2004L18/172UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)0106FUSES,DETONATING11.1B1LQ0P141MP231V2CV1CV2CV3S10107FUSES,DETONATING11.2B1LQ0P141MP231V2CV1CV2CV3S10110GRENADES,PRACTICE,handorrifle11.4S1.4LQ0P141MP234V2CV1CV2CV3S10113GUANYLNITROSAMINO-GUANYLIDENEHYDRA-ZINE,WETTEDwithnotlessthan30%water,bymass11.1A1266LQ0P110(b)PP42MP200V2CV1CV2CV3S10114GUANYLNITROSAMINO-GUANYLTETRAZENE(TETRAZENE),WETTEDwithnotlessthan30%water,ormixtureofalcoholandwater,bymass11.1A1266LQ0P110(b)PP42MP200V2CV1CV2CV3S10118HEXOLITE(HEXOTOL),dryorwettedwithlessthan15%water,bymass11.1D1LQ0P112MP201V2V3CV1CV2CV3S1OfficialJournaloftheEuropeanUnionEN26.1.2004L18/173UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)0121IGNITERS11.1G1LQ0P142MP231V2CV1CV2CV3S10124JETPERFORATINGGUNS,CHARGED,oilwell,withoutdetonator11.1D1LQ0P101MP211V2CV1CV2CV3S10129LEADAZIDE,WETTEDwithnotlessthan20%water,ormixtureofalcoholandwater,bymass11.1A1266LQ0P110(b)PP42MP200V2CV1CV2CV3S10130LEADSTYPHNATE(LEADTRINITRORESORCINATE),WETTEDwithnotlessthan20%water,ormixtureofalcoholandwater,bymass11.1A1266LQ0P110(b)PP42MP200V2CV1CV2CV3S10131LIGHTERS,FUSE11.4S1.4LQ0P142MP234V2CV1CV2CV3S10132DEFLAGRATINGMETALSALTSOFAROMATICNITRODERIVATIVES,N.O.S.11.3C1274LQ0P114(a)(b)PP26MP21V2V3CV1CV2CV3S1OfficialJournaloftheEuropeanUnionEN26.1.2004L18/174UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)0133MANNITOLHEXANITRATE(NITROMANNITE),WETTEDwithnotlessthan40%water,ormixtureofalcoholandwater,bymass11.1D1266LQ0P112(a)MP201V2CV1CV2CV3S10135MERCURYFULMINATE,WETTEDwithnotlessthan20%water,ormixtureofalcoholandwater,bymass11.1A1266LQ0P110(b)PP42MP200V2CV1CV2CV3S10136MINESwithburstingcharge11.1F1LQ0P130MP231V2CV1CV2CV3S10137MINESwithburstingcharge11.1D1LQ0P130LP101PP67L1MP211V2CV1CV2CV3S10138MINESwithburstingcharge11.2D1LQ0P130LP101PP67L1MP211V2CV1CV2CV3S10143NITROGLYCERINE,DESEN-SITISEDwithnotlessthan40%non-volatilewater-insolublephlegmatiser,bymass11.1D1+6.1266271LQ0P115PP53PP54PP57PP58MP201V2CV1CV2CV3CV28S1OfficialJournaloftheEuropeanUnionEN26.1.2004L18/175UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)0144NITROGLYCERINESOLU-TIONINALCOHOLwithmorethan1%butnotmorethan10%nitrogly-cerine11.1D1500LQ0P115PP45PP55PP56PP59PP60MP201V2CV1CV2CV3S10146NITROSTARCH,dryorwettedwithlessthan20%water,bymass11.1D1LQ0P112MP201V2V3CV1CV2CV3S10147NITROUREA11.1D1LQ0P112(b)MP201V2V3CV1CV2CV3S10150PENTAERYTHRITETETRA-NITRATE(PENTAERY-THRITOLTETRANITRATE;PETN),WETTEDwithnotlessthan25%water,bymass,orDESENSITISEDwithnotlessthan15%phlegmatiser,bymass11.1D1266LQ0P112(a)(b)MP201V2V3CV1CV2CV3S10151PENTOLITE,dryorwettedwithlessthan15%water,bymass11.1D1LQ0P112MP201V2V3CV1CV2CV3S10153TRINITROANILINE(PICRA-MIDE)11.1D1LQ0P112(b)(c)MP201V2V3CV1CV2CV3S1OfficialJournaloftheEuropeanUnionEN26.1.2004L18/176UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)0154TRINITROPHENOL(PICRICACID),dryorwettedwithlessthan30%water,bymass11.1D115LQ0P112(a)(b)(c)PP26MP201V2V3CV1CV2CV3S10154TRINITROPHENOL(PICRICACID)wettedwithnotlessthan10%water,bymass4.1DI4.115LQ0P406MP21S170155TRINITROCHLOROBEN-ZENE(PICRYLCHLORIDE)11.1D115LQ0P112(b)(c)MP201V2V3CV1CV2CV3S10155TRINITROCHLOROBEN-ZENE(PICRYLCHLORIDE)wettedwithnotlessthan10%water,bymass4.1DI4.115LQ0P406MP21S170159POWDERCAKE(POWDERPASTE),WETTEDwithnotlessthan25%water,bymass11.3C1266LQ0P111PP43MP201V2CV1CV2CV3S10160POWDER,SMOKELESS11.1C1LQ0P114(b)PP50PP52MP20MP241V2V3CV1CV2CV3S10161POWDER,SMOKELESS11.3C1LQ0P114(b)PP50PP52MP20MP241V2V3CV1CV2CV3S10167PROJECTILESwithburstingcharge11.1F1LQ0P130MP231V2CV1CV2CV3S1OfficialJournaloftheEuropeanUnionEN26.1.2004L18/177UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)0168PROJECTILESwithburstingcharge11.1D1LQ0P130LP101PP67L1MP211V2CV1CV2CV3S10169PROJECTILESwithburstingcharge11.2D1LQ0P130LP101PP67L1MP211V2CV1CV2CV3S10171AMMUNITION,ILLUMI-NATINGwithorwithoutburster,expellingchargeorpropellingcharge11.2G1LQ0P130LP101PP67L1MP231V2CV1CV2CV3S10173RELEASEDEVICES,EXPLO-SIVE11.4S1.4LQ0P134LP102MP234V2CV1CV2CV3S10174RIVETS,EXPLOSIVE11.4S1.4LQ0P134LP102MP234V2CV1CV2CV3S10180ROCKETSwithburstingcharge11.1F1LQ0P130MP231V2CV1CV2CV3S10181ROCKETSwithburstingcharge11.1E1LQ0P130LP101PP67L1MP211V2CV1CV2CV3S10182ROCKETSwithburstingcharge11.2E1LQ0P130LP101PP67L1MP211V2CV1CV2CV3S1OfficialJournaloftheEuropeanUnionEN26.1.2004L18/178UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)0183ROCKETSwithinerthead11.3C1LQ0P130LP101PP67L1MP221V2CV1CV2CV3S10186ROCKETMOTORS11.3C1LQ0P130LP101PP67L1MP22MP241V2CV1CV2CV3S10190SAMPLES,EXPLOSIVE,otherthaninitiatingexplosive116274LQ0P101MP20V2CV1CV2CV3S10191SIGNALDEVICES,HAND11.4G1.4LQ0P135MP23MP242V2CV1CV2CV3S10192SIGNALS,RAILWAYTRACK,EXPLOSIVE11.1G1LQ0P135MP231V2CV1CV2CV3S10193SIGNALS,RAILWAYTRACK,EXPLOSIVE11.4S1.4LQ0P135MP234V2CV1CV2CV3S10194SIGNALS,DISTRESS,ship11.1G1LQ0P135MP23MP241V2CV1CV2CV3S10195SIGNALS,DISTRESS,ship11.3G1LQ0P135MP23MP241V2CV1CV2CV3S1OfficialJournaloftheEuropeanUnionEN26.1.2004L18/179UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)0196SIGNALS,SMOKE11.1G1LQ0P135MP231V2CV1CV2CV3S10197SIGNALS,SMOKE11.4G1.4LQ0P135MP23MP242V2CV1CV2CV3S10204SOUNDINGDEVICES,EXPLOSIVE11.2F1LQ0P134LP102MP231V2CV1CV2CV3S10207TETRANITROANILINE11.1D1LQ0P112(b)(c)MP201V2V3CV1CV2CV3S10208TRINITROPHENYLMETHYL-NITRAMINE(TETRYL)11.1D1LQ0P112(b)(c)MP201V2V3CV1CV2CV3S10209TRINITROTOLUENE(TNT),dryorwettedwithlessthan30%water,bymass11.1D115LQ0P112(b)(c)PP46MP201V2V3CV1CV2CV3S10209TRINITROTOLUENE(TNT),wettedwithnotlessthan10%water,bymass4.1DI4.115LQ0P406MP21S170212TRACERSFORAMMUNI-TION11.3G1LQ0P133PP69MP231V2CV1CV2CV3S1OfficialJournaloftheEuropeanUnionEN26.1.2004L18/180UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)0213TRINITROANISOLE11.1D1LQ0P112(b)(c)MP201V2V3CV1CV2CV3S10214TRINITROBENZENE,dryorwettedwithlessthan30%water,bymass11.1D115LQ0P112MP201V2V3CV1CV2CV3S10214TRINITROBENZENE,wettedwithnotlessthan10%water,bymass4.1DI4.115LQ0P406MP21S170215TRINITROBENZOICACID,dryorwettedwithlessthan30%water,bymass11.1D115LQ0P112MP201V2V3CV1CV2CV3S10215TRINITROBENZOICACID,wettedwithnotlessthan10%water,bymass4.1DI4.115LQ0P406MP21S170216TRINITRO-m-CRESOL11.1D1LQ0P112(b)(c)PP26MP201V2V3CV1CV2CV3S10217TRINITRONAPHTHALENE11.1D1LQ0P112(b)(c)MP201V2V3CV1CV2CV3S10218TRINITROPHENETOLE11.1D1LQ0P112(b)(c)MP201V2V3CV1CV2CV3S1OfficialJournaloftheEuropeanUnionEN26.1.2004L18/181UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)0219TRINITRORESORCINOL(STYPHNICACID),dryorwettedwithlessthan20%water,ormixtureofalcoholandwater,bymass11.1D1LQ0P112(a)(b)(c)PP26MP201V2V3CV1CV2CV3S10220UREANITRATE,dryorwettedwithlessthan20%water,bymass11.1D118LQ0P112MP201V2V3CV1CV2CV3S10220UREANITRATE,wettedwithnotlessthan10%water,bymass4.1DI4.118LQ0P406MP21S170221WARHEADS,TORPEDOwithburstingcharge11.1D1LQ0P130LP101PP67L1MP211V2CV1CV2CV3S10222AMMONIUMNITRATEwithmorethan0,2%combus-tiblesubstances,includinganyorganicsubstancecalcu-latedascarbon,totheexclusionofanyotheraddedsubstance11.1D1LQ0P112(b)(c)PP47MP201V2V3CV1CV2CV3S1OfficialJournaloftheEuropeanUnionEN26.1.2004L18/182UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)0223AMMONIUMNITRATEFERTILISER,whichismoreliabletoexplodethanammoniumnitratewith0,2%combustiblesubstances,includinganyorganicsubstancecalculatedascarbon,totheexclusionofanyotheraddedsubstance11.1D1LQ0P112(b)(c)PP47MP201V2V3CV1CV2CV3S10224BARIUMAZIDE,dryorwettedwithlessthan50%water,bymass11.1A1+6.1LQ0P110(b)PP42MP200V2V3CV1CV2CV3CV28S10225BOOSTERSWITHDETO-NATOR11.1B1LQ0P133PP69MP231V2CV1CV2CV3S10226CYCLOTETRAMETHYLENE-TETRANITRAMINE(HMX;OCTOGEN),WETTEDwithnotlessthan15%water,bymass11.1D1266LQ0P112(a)PP45MP201V2CV1CV2CV3S10234SODIUMDINITRO-o-CRESOLATE,dryorwettedwithlessthan15%water,bymass11.3C115LQ0P114(a)(b)PP26MP201V2V3CV1CV2CV3S1OfficialJournaloftheEuropeanUnionEN26.1.2004L18/183UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)0234SODIUMDINITRO-o-CRESOLATE,WETTEDwithnotlessthan10%water,bymass4.1DTI4.1+6.115LQ0P406MP21CV13CV28S17S200235SODIUMPICRAMATE,dryorwettedwithlessthan20%water,bymass11.3C1LQ0P114(a)(b)PP26MP201V2V3CV1CV2CV3S10236ZIRCONIUMPICRAMATE,dryorwettedwithlessthan20%water,bymass11.3C1LQ0P114(a)(b)PP26MP201V2V3CV1CV2CV3S10237CHARGES,SHAPED,FLEX-IBLE,LINEAR11.4D1.4LQ0P138MP212V2CV1CV2CV3S10238ROCKETS,LINE-THROWING11.2G1LQ0P130MP23MP241V2CV1CV2CV3S10240ROCKETS,LINE-THROWING11.3G1LQ0P130MP23MP241V2CV1CV2CV3S10241EXPLOSIVE,BLASTING,TYPEE11.1D1617LQ0P116IBC100PP61PP62PP65B10MP201V2CV1CV2CV3S1OfficialJournaloftheEuropeanUnionEN26.1.2004L18/184UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)0242CHARGES,PROPELLING,FORCANNON11.3C1LQ0P130MP221V2CV1CV2CV3S10243AMMUNITION,INCENDIARY,WHITEPHOSPHORUSwithburster,expellingchargeorpropel-lingcharge11.2H1LQ0P130LP101PP67L1MP231V2CV1CV2CV3S10244AMMUNITION,INCENDIARY,WHITEPHOSPHORUSwithburster,expellingchargeorpropel-lingcharge11.3H1LQ0P130LP101PP67L1MP231V2CV1CV2CV3S10245AMMUNITION,SMOKE,WHITEPHOSPHORUSwithburster,expellingchargeorpropellingcharge11.2H1LQ0P130LP101PP67L1MP231V2CV1CV2CV3S10246AMMUNITION,SMOKE,WHITEPHOSPHORUSwithburster,expellingchargeorpropellingcharge11.3H1LQ0P130LP101PP67L1MP231V2CV1CV2CV3S10247AMMUNITION,INCENDIARY,liquidorgel,withburster,expellingchargeorpropellingcharge11.3J1LQ0P101MP231V2CV1CV2CV3S1OfficialJournaloftheEuropeanUnionEN26.1.2004L18/185UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)0248CONTRIVANCES,WATER-ACTIVATEDwithburster,expellingchargeorpropel-lingcharge11.2L1274LQ0P144PP77MP10V2CV1CV2CV3CV4S10249CONTRIVANCES,WATER-ACTIVATEDwithburster,expellingchargeorpropel-lingcharge11.3L1274LQ0P144PP77MP10V2CV1CV2CV3CV4S10250ROCKETMOTORSWITHHYPERGOLICLIQUIDSwithorwithoutexpellingcharge11.3L1LQ0P101MP10V2CV1CV2CV3CV4S10254AMMUNITION,ILLUMI-NATINGwithorwithoutburster,expellingchargeorpropellingcharge11.3G1LQ0P130LP101PP67L1MP231V2CV1CV2CV3S10255DETONATORS,ELECTRICforblasting11.4B1.4LQ0P131MP232V2CV1CV2CV3S10257FUSES,DETONATING11.4B1.4LQ0P141MP232V2CV1CV2CV3S10266OCTOLITE(OCTOL),dryorwettedwithlessthan15%water,bymass11.1D1LQ0P112MP201V2V3CV1CV2CV3S1OfficialJournaloftheEuropeanUnionEN26.1.2004L18/186UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)0267DETONATORS,NON-ELEC-TRICforblasting11.4B1.4LQ0P131PP68MP232V2CV1CV2CV3S10268BOOSTERSWITHDETO-NATOR11.2B1LQ0P133PP69MP231V2CV1CV2CV3S10271CHARGES,PROPELLING11.1C1LQ0P143PP76MP221V2CV1CV2CV3S10272CHARGES,PROPELLING11.3C1LQ0P143PP76MP221V2CV1CV2CV3S10275CARTRIDGES,POWERDEVICE11.3C1LQ0P134LP102MP221V2CV1CV2CV3S10276CARTRIDGES,POWERDEVICE11.4C1.4LQ0P134LP102MP222V2CV1CV2CV3S10277CARTRIDGES,OILWELL11.3C1LQ0P134LP102MP221V2CV1CV2CV3S10278CARTRIDGES,OILWELL11.4C1.4LQ0P134LP102MP222V2CV1CV2CV3S1OfficialJournaloftheEuropeanUnionEN26.1.2004L18/187UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)0279CHARGES,PROPELLING,FORCANNON11.1C1LQ0P130MP221V2CV1CV2CV3S10280ROCKETMOTORS11.1C1LQ0P130LP101PP67L1MP221V2CV1CV2CV3S10281ROCKETMOTORS11.2C1LQ0P130LP101PP67L1MP221V2CV1CV2CV3S10282NITROGUANIDINE(PICRITE),dryorwettedwithlessthan20%water,bymass11.1D1LQ0P112MP201V2V3CV1CV2CV3S10283BOOSTERSwithoutdeto-nator11.2D1LQ0P132MP211V2CV1CV2CV3S10284GRENADES,handorrifle,withburstingcharge11.1D1LQ0P141MP211V2CV1CV2CV3S10285GRENADES,handorrifle,withburstingcharge11.2D1LQ0P141MP211V2CV1CV2CV3S10286WARHEADS,ROCKETwithburstingcharge11.1D1LQ0P130LP101PP67L1MP211V2CV1CV2CV3S1OfficialJournaloftheEuropeanUnionEN26.1.2004L18/188UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)0287WARHEADS,ROCKETwithburstingcharge11.2D1LQ0P130LP101PP67L1MP211V2CV1CV2CV3S10288CHARGES,SHAPED,FLEX-IBLE,LINEAR11.1D1LQ0P138MP211V2CV1CV2CV3S10289CORD,DETONATING,flex-ible11.4D1.4LQ0P139PP71PP72MP212V2CV1CV2CV3S10290CORD(FUSE),DETO-NATING,metalclad11.1D1LQ0P139PP71MP211V2CV1CV2CV3S10291BOMBSwithburstingcharge11.2F1LQ0P130MP231V2CV1CV2CV3S10292GRENADES,handorrifle,withburstingcharge11.1F1LQ0P141MP231V2CV1CV2CV3S10293GRENADES,handorrifle,withburstingcharge11.2F1LQ0P141MP231V2CV1CV2CV3S10294MINESwithburstingcharge11.2F1LQ0P130MP231V2CV1CV2CV3S1OfficialJournaloftheEuropeanUnionEN26.1.2004L18/189UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)0295ROCKETSwithburstingcharge11.2F1LQ0P130MP231V2CV1CV2CV3S10296SOUNDINGDEVICES,EXPLOSIVE11.1F1LQ0P134LP102MP231V2CV1CV2CV3S10297AMMUNITION,ILLUMI-NATINGwithorwithoutburster,expellingchargeorpropellingcharge11.4G1.4LQ0P130LP101PP67L1MP232V2CV1CV2CV3S10299BOMBS,PHOTO-FLASH11.3G1LQ0P130LP101PP67L1MP231V2CV1CV2CV3S10300AMMUNITION,INCENDIARYwithorwithoutburster,expellingchargeorpropellingcharge11.4G1.4LQ0P130LP101PP67L1MP232V2CV1CV2CV3S10301AMMUNITION,TEAR-PRODUCINGwithburster,expellingchargeorpropel-lingcharge11.4G1.4+6.1+8LQ0P130LP101PP67L1MP232V2CV1CV2CV3CV28S10303AMMUNITION,SMOKEwithorwithoutburster,expellingchargeorpropellingcharge11.4G1.4+8204LQ0P130LP101PP67L1MP232V2CV1CV2CV3S1OfficialJournaloftheEuropeanUnionEN26.1.2004L18/190UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)0305FLASHPOWDER11.3G1LQ0P113PP49MP201V2V3CV1CV2CV3S10306TRACERSFORAMMUNI-TION11.4G1.4LQ0P133PP69MP232V2CV1CV2CV3S10312CARTRIDGES,SIGNAL11.4G1.4LQ0P135MP23MP242V2CV1CV2CV3S10313SIGNALS,SMOKE11.2G1LQ0P135MP231V2CV1CV2CV3S10314IGNITERS11.2G1LQ0P142MP231V2CV1CV2CV3S10315IGNITERS11.3G1LQ0P142MP231V2CV1CV2CV3S10316FUSES,IGNITING11.3G1LQ0P141MP231V2CV1CV2CV3S10317FUSES,IGNITING11.4G1.4LQ0P141MP232V2CV1CV2CV3S1OfficialJournaloftheEuropeanUnionEN26.1.2004L18/191UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)0318GRENADES,PRACTICE,handorrifle11.3G1LQ0P141MP231V2CV1CV2CV3S10319PRIMERS,TUBULAR11.3G1LQ0P133MP231V2CV1CV2CV3S10320PRIMERS,TUBULAR11.4G1.4LQ0P133MP232V2CV1CV2CV3S10321CARTRIDGESFORWEAPONSwithburstingcharge11.2E1LQ0P130LP101PP67L1MP211V2CV1CV2CV3S10322ROCKETMOTORSWITHHYPERGOLICLIQUIDSwithorwithoutexpellingcharge11.2L1LQ0P101MP10V2CV1CV2CV3CV4S10323CARTRIDGES,POWERDEVICE11.4S1.4LQ0P134LP102MP234V2CV1CV2CV3S10324PROJECTILESwithburstingcharge11.2F1LQ0P130MP231V2CV1CV2CV3S10325IGNITERS11.4G1.4LQ0P142MP232V2CV1CV2CV3S1OfficialJournaloftheEuropeanUnionEN26.1.2004L18/192UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)0326CARTRIDGESFORWEAPONS,BLANK11.1C1LQ0P130MP221V2CV1CV2CV3S10327CARTRIDGESFORWEAPONS,BLANKorCARTR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hflammablesolvents(vapourpressureat50°Cmorethan175kPa)3F1I3640LQ3P001MP7MP17L4BNFL1S2S20331266PERFUMERYPRODUCTSwithflammablesolvents(vapourpressureat50°Cmorethan110kPabutnotmorethan175kPa)3F1I3640LQ3P001MP7MP17L1,5BNFL1S2S20331266PERFUMERYPRODUCTSwithflammablesolvents(vapourpressureat50°Cmorethan110kPabutnotmorethan175kPa)3F1II3640LQ6P001MP19T4TP1TP8L1,5BNFL2S2S2033OfficialJournaloftheEuropeanUnionEN26.1.2004L18/259UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)1266PERFUMERYPRODUCTSwithflammablesolvents(vapourpressureat50°Cnotmorethan110kPa)3F1II3640LQ6P001IBC02R001MP19T4TP1TP8LGBFFL2S2S20331266PERFUMERYPRODUCTSwithflammablesolvents3F1III3640LQ7P001IBC03LP01R001MP19T2TP1LGBFFL3S2301266PERFUMERYPRODUCTSwithflammablesolvents(havingaflash-pointbelow23°Candviscousaccordingto2.2.3.1.4)(vapourpres-sureat50°Cmorethan175kPa)3F1III3640LQ7P001LP01R001MP19T2TP1L4BNFL3S2331266PERFUMERYPRODUCTSwithflammablesolvents(havingaflash-pointbelow23°Candviscousaccordingto2.2.3.1.4)(vapourpres-sureat50°Cmorethan110kPabutnotmorethan175kPa)3F1III3640LQ7P001LP01R001MP19T2TP1L1,5BNFL3S233OfficialJournaloftheEuropeanUnionEN26.1.2004L18/260UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)1266PERFUMERYPRODUCTSwithflammablesolvents(havingaflash-pointbelow23°Candviscousaccordingto2.2.3.1.4)(vapourpres-sureat50°Cnotmorethan110kPa)3F1III3640LQ7P001IBC02LP01R001MP19T2TP1LGBFFL3S2331267PETROLEUMCRUDEOIL(vapourpressureat50°Cmorethan175kPa)3F1I3640LQ3P001MP7MP17T11TP1TP8L4BNFL1S2S20331267PETROLEUMCRUDEOIL(vapourpressureat50°Cmorethan110kPabutnotmorethan175kPa)3F1I3640LQ3P001MP7MP17T11TP1TP8L1,5BNFL1S2S20331267PETROLEUMCRUDEOIL(vapourpressureat50°Cmorethan110kPabutnotmorethan175kPa)3F1II3640LQ4P001MP19T4TP1TP8L1.5BNFL2S2S20331267PETROLEUMCRUDEOIL(vapourpressureat50°Cnotmorethan110kPa)3F1II3640LQ4P001IBC02R001MP19T4TP1TP8LGBFFL2S2S2033OfficialJournaloftheEuropeanUnionEN26.1.2004L18/261UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)1267PETROLEUMCRUDEOIL3F1III3LQ7P001IBC03LP01R001MP19T2TP1LGBFFL3S2301268PETROLEUMDISTILLATES,N.O.S.orPETROLEUMPRODUCTS,N.O.S.(vapourpressureat50°Cmorethan175kPa)3F1I3274640LQ3P001MP7MP17T11TP1TP8TP9L4BNFL1S2S20331268PETROLEUMDISTILLATES,N.O.S.orPETROLEUMPRODUCTS,N.O.S.(vapourpressureat50°Cmorethan110kPabutnotmorethan175kPa)3F1II3274640LQ4P001MP19T7TP1TP8TP9TP28L1.5BNFL2S2S20331268PETROLEUMDISTILLATES,N.O.S.orPETROLEUMPRODUCTS,N.O.S.(vapourpressureat50°Cnotmorethan110kPa)3F1II3274640LQ4P001IBC02R001MP19T7TP1TP8TP9TP28LGBFFL2S2S2033OfficialJournaloftheEuropeanUnionEN26.1.2004L18/262UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)1268PETROLEUMDISTILLATES,N.O.S.orPETROLEUMPRODUCTS,N.O.S.3F1III3274LQ7P001IBC03LP01R001MP19T4TP1TP9TP29LGBFFL3S2301272PINEOIL3F1III3LQ7P001IBC03LP01R001MP19T2TP1LGBFFL3S2301274n-PROPANOL(PROPYLALCOHOL,NORMAL)3F1II3LQ4P001IBC02R001MP19T4TP1LGBFFL2S2S20331274n-PROPANOL(PROPYLALCOHOL,NORMAL)3F1III3LQ7P001IBC03LP01R001MP19T2TP1LGBFFL3S2301275PROPIONALDEHYDE3F1II3LQ4P001IBC02R001MP19T7TP1LGBFFL2S2S20331276n-PROPYLACETATE3F1II3LQ4P001IBC02R001MP19T4TP1LGBFFL2S2S20331277PROPYLAMINE3FCII3+8LQ4P001IBC02MP19T7TP1L4BHTE1TE15FL2S2S20338OfficialJournaloftheEuropeanUnionEN26.1.2004L18/263UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)1278PROPYLCHLORIDE3F1II3LQ4P001IBC02B8MP19T7TP2L1.5BNFL2S2S203312791,2-DICHLOROPROPANE3F1II3LQ4P001IBC02R001MP19T4TP1LGBFFL2S2S20331280PROPYLENEOXIDE3F1I3LQ3P001MP7MP17T11TP2TP7L1.5BNFL1S2S20331281PROPYLFORMATES3F1II3LQ4P001IBC02R001MP19T4TP1LGBFFL2S2S20331282PYRIDINE3F1II3LQ4P001IBC02R001MP19T4TP2LGBFFL2S2S20331286ROSINOIL(vapourpressureat50°Cmorethan175kPa)3F1I3640LQ3P001MP7MP17L4BNFL1S2S20331286ROSINOIL(vapourpressureat50°Cmorethan110kPabutnotmorethan175kPa)3F1I3640LQ3P001MP7MP17L1,5BNFL1S2S20331286ROSINOIL(vapourpressureat50°Cmorethan110kPabutnotmorethan175kPa)3F1II3640LQ6P001MP19T4TP1L1,5BNFL2S2S2033OfficialJournaloftheEuropeanUnionEN26.1.2004L18/264UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)1286ROSINOIL(vapourpressureat50°Cnotmorethan110kPa)3F1II3640LQ6P001IBC02R001MP19T4TP1LGBFFL2S2S20331286ROSINOIL(nonviscous)3F1III3640LQ7P001IBC03LP01R001MP19T2TP1LGBFFL3S2301286ROSINOIL(havingaflash-pointbelow23°Candviscousaccordingto2.2.3.1.4)(vapourpressureat50°Cmorethan175kPa)3F1III3640LQ7P001LP01R001MP19T2TP1L4BNFL3S2331286ROSINOIL(havingaflash-pointbelow23°Candviscousaccordingto2.2.3.1.4)(vapourpressureat50°Cmorethan110kPabutnotmorethan175kPa)3F1III3640LQ7P001LP01R001MP19T2TP1L1,5BNFL3S233OfficialJournaloftheEuropeanUnionEN26.1.2004L18/265UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)1286ROSINOIL(havingaflash-pointbelow23°Candviscousaccordingto2.2.3.1.4)(vapourpressureat50°Cnotmorethan110kPa)3F1III3640LQ7P001IBC02LP01R001MP19T2TP1LGBFFL3S2331287RUBBERSOLUTION(vapourpressureat50°Cmorethan175kPa)3F1I3640LQ3P001MP7MP17L4BNFL1S2S20331287RUBBERSOLUTION(vapourpressureat50°Cmorethan110kPabutnotmorethan175kPa)3F1I3640LQ3P001MP7MP17L1,5BNFL1S2S20331287RUBBERSOLUTION(vapourpressureat50°Cmorethan110kPabutnotmorethan175kPa)3F1II3640LQ6P001MP19T4TP1TP8L1,5BNFL2S2S20331287RUBBERSOLUTION(vapourpressureat50°Cnotmorethan110kPa)3F1II3640LQ6P001IBC02R001MP19T4TP1TP8LGBFFL2S2S2033OfficialJournaloftheEuropeanUnionEN26.1.2004L18/266UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)1287RUBBERSOLUTION(nonviscous)3F1III3640LQ7P001IBC03LP01R001MP19T2TP1LGBFFL3S2301287RUBBERSOLUTION(havingaflash-pointbelow23°Candviscousaccordingto2.2.3.1.4)(vapourpressureat50°Cmorethan175kPa)3F1III3640LQ7P001LP01R001MP19T2TP1L4BNFL3S2331287RUBBERSOLUTION(havingaflash-pointbelow23°Candviscousaccordingto2.2.3.1.4)(vapourpressureat50°Cmorethan110kPabutnotmorethan175kPa)3F1III3640LQ7P001LP01R001MP19T2TP1L1,5BNFL3S2331287RUBBERSOLUTION(havingaflash-pointbelow23°Candviscousaccordingto2.2.3.1.4)(vapourpressureat50°Cnotmorethan110kPa)3F1III3640LQ7P001IBC02LP01R001MP19T2TP1LGBFFL3S2331288SHALEOIL3F1II3LQ4P001IBC02R001MP19T4TP1TP8LGBFFL2S2S2033OfficialJournaloftheEuropeanUnionEN26.1.2004L18/267UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)1288SHALEOIL3F1III3LQ7P001IBC03LP01R001MP19T2TP1LGBFFL3S2301289SODIUMMETHYLATESOLUTIONinalcohol3FCII3+8LQ4P001IBC02MP19T7TP1TP8L4BHTE1TE15FL2S2S203381289SODIUMMETHYLATESOLUTIONinalcohol3FCIII3+8LQ7P001IBC02R001MP19T4TP1L4BNFL3S2381292TETRAETHYLSILICATE3F1III3LQ7P001IBC03LP01R001MP19T2TP1LGBFFL3S2301293TINCTURES,MEDICINAL3F1II3LQ4P001IBC02R001MP19T4TP1TP8LGBFFL2S2S20331293TINCTURES,MEDICINAL3F1III3LQ7P001IBC03LP01R001MP19T2TP1LGBFFL3S2301294TOLUENE3F1II3LQ4P001IBC02R001MP19T4TP1LGBFFL2S2S2033OfficialJournaloftheEuropeanUnionEN26.1.2004L18/268UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)1295TRICHLOROSILANE4.3WFCI4.3+3+8LQ0P401PR2MP2T14TP2TP7TP13L10DHTU14TU25TE1TM2TM3FL0CV23S2S20X3381296TRIETHYLAMINE3FCII3+8LQ4P001IBC02MP19T7TP1L4BHTE1TE15FL2S2S203381297TRIMETHYLAMINE,AQUEOUSSOLUTION,notmorethan50%trimethyla-mine,bymass3FCI3+8LQ3P001MP7MP17T11TP1L10CHTU14TE1FL1S2S203381297TRIMETHYLAMINE,AQUEOUSSOLUTION,notmorethan50%trimethyla-mine,bymass3FCII3+8LQ4P001IBC02MP19T7TP1L4BHTE1TE15FL2S2S203381297TRIMETHYLAMINE,AQUEOUSSOLUTION,notmorethan50%trimethyla-mine,bymass3FCIII3+8LQ7P001IBC03R001MP19T7TP1L4BNFL3S2381298TRIMETHYLCHLORO-SILANE3FCII3+8LQ4P001IBC02MP19T7TP2TP13L4BHTE1TE15FL2S2S20X3381299TURPENTINE3F1III3LQ7P001IBC03LP01R001MP19T2TP1LGBFFL3S230OfficialJournaloftheEuropeanUnionEN26.1.2004L18/269UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)1300TURPENTINESUBSTITUTE3F1II3LQ4P001IBC02R001MP19T4TP1LGBFFL2S2S20331300TURPENTINESUBSTITUTE3F1III3LQ7P001IBC03LP01R001MP19T2TP1LGBFFL3S2301301VINYLACETATE,STABI-LISED3F1II3LQ4P001IBC02R001MP19T4TP1LGBFFL2S2S203391302VINYLETHYLETHER,ST-ABILISED3F1I3LQ3P001MP7MP17T11TP2L1.5BNFL1S2S203391303VINYLIDENECHLORIDE,STABILISED3F1I3LQ3P001MP7MP17T12TP2TP7L4BNFL1S2S203391304VINYLISOBUTYLETHER,STABILISED3F1II3LQ4P001IBC02R001MP19T4TP1LGBFFL2S2S203391305VINYLTRICHLOROSILANE,STABILISED3FCI3+8LQ3P001MP7MP17T11TP2TP13L10CHTU14TE1FL1S2S20X338OfficialJournaloftheEuropeanUnionEN26.1.2004L18/270UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)1306WOODPRESERVATIVES,LIQUID(vapourpressureat50°Cmorethan110kPabutnotmorethan175kPa)3F1II3640LQ6P001MP19T4TP1TP8L1,5BNFL2S2S20331306WOODPRESERVATIVES,LIQUID(vapourpressureat50°Cnotmorethan110kPa)3F1II3640LQ6P001IBC02R001MP19T4TP1TP8LGBFFL2S2S20331306WOODPRESERVATIVES,LIQUID(nonviscous)3F1III3640LQ7P001IBC03LP01R001MP19T2TP1LGBFFL3S2301306WOODPRESERVATIVES,LIQUID(havingaflash-pointbelow23°Candviscousaccordingto2.2.3.1.4)(vapourpressureat50°Cmorethan175kPa)3F1III3640LQ7P001LP01R001MP19T2TP1L4BNFL3S233OfficialJournaloftheEuropeanUnionEN26.1.2004L18/271UNNoNameanddescript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2MP15L4BHTU15TE1TE15AT2CV13CV28S9S19601556ARSENICCOMPOUND,LIQUID,N.O.S.,inorganic,including:Arsenates,n.o.s.,Arsenites,n.o.s.;andArsenicsulphides,n.o.s.6.1T4III6.143274LQ19P001IBC03LP01R001MP15L4BHTU15TE1TE15AT2CV13CV28S9601557ARSENICCOMPOUND,SOLID,N.O.S.,inorganic,including:Arsenates,n.o.s.;Arsenites,n.o.s.;andArsenicsulphides,n.o.s.6.1T5I6.143274LQ0P002IBC07B1MP18S10AHTU15TE1AT1CV1CV13CV28S9S17S2066OfficialJournaloftheEuropeanUnionEN26.1.2004L18/298UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)1557ARSENICCOMPOUND,SOLID,N.O.S.,inorganic,including:Arsenates,n.o.s.;Arsenites,n.o.s.;andArsenicsulphides,n.o.s.6.1T5II6.143274LQ18P002IBC08B2B4MP10SGAHL4BHTU15TE1TE15AT2CV13CV28S9S19601557ARSENICCOMPOUND,SOLID,N.O.S.,inorganic,including:Arsenates,n.o.s.;Arsenites,n.o.s.;andArsenicsulphides,n.o.s.6.1T5III6.143274LQ9P002IBC08LP02R001B3MP10SGAHTU15TE1TE15AT2VV9bCV13CV28S9601558ARSENIC6.1T5II6.1LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S19601559ARSENICPENTOXIDE6.1T5II6.1LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S19601560ARSENICTRICHLORIDE6.1T4I6.1LQ0P602MP18T14TP2TP13L10CHTU14TU15TE1AT1CV1CV13CV28S9S17S20661561ARSENICTRIOXIDE6.1T5II6.1LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S19601562ARSENICALDUST6.1T5II6.1LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S1960OfficialJournaloftheEuropeanUnionEN26.1.2004L18/299UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)1564BARIUMCOMPOUND,N.O.S.6.1T5II6.1177274513587LQ18P002IBC08B2B4MP10SGAHL4BHTU15TE1TE15AT2CV13CV28S9S19601564BARIUMCOMPOUND,N.O.S.6.1T5III6.1177274513587LQ9P002IBC08LP02R001B3MP10SGAHL4BHTU15TE1TE15AT2VV9aCV13CV28S9601565BARIUMCYANIDE6.1T5I6.1LQ0P002IBC07B1MP18S10AHTU15TE1AT1CV1CV13CV28S9S17S20661566BERYLLIUMCOMPOUND,N.O.S.6.1T5II6.1274514LQ18P002IBC08B2B4MP10SGAHL4BHTU15TE1TE15AT2CV13CV28S9S19601566BERYLLIUMCOMPOUND,N.O.S.6.1T5III6.1274514LQ9P002IBC08LP02R001B3MP10SGAHL4BHTU15TE1TE15AT2VV9bCV13CV28S9601567BERYLLIUMPOWDER6.1TF3II6.1+4.1LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S19641569BROMOACETONE6.1TF1II6.1+3LQ17P602MP15T10TP2TP13L4BHTU15TE1TE15FL2CV13CV28S2S9S19631570BRUCINE6.1T2I6.143LQ0P002IBC07B1MP18S10AHL10CHTU14TU15TE1AT1CV1CV13CV28S9S17S2066OfficialJournaloftheEuropeanUnionEN26.1.2004L18/300UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)1571BARIUMAZIDE,WETTEDwithnotlessthan50%water,bymass4.1DTI4.1+6.1568LQ0P406MP21CV28S171572CACODYLICACID6.1T5II6.1LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S19601573CALCIUMARSENATE6.1T5II6.1LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S19601574CALCIUMARSENATEANDCALCIUMARSENITEMIXTURE,SOLID6.1T5II6.1LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S19601575CALCIUMCYANIDE6.1T5I6.1LQ0P002IBC07B1MP18S10AHTU15TE1AT1CV1CV13CV28S9S17S20661577CHLORODINITROBEN-ZENES,LIQUID6.1T1II6.1279LQ17P001IBC02MP15T7TP2L4BHTU15TE1TE15AT2CV13CV28S9S19601577CHLORODINITROBEN-ZENES,SOLID6.1T2II6.1279LQ18P002IBC08B2B4MP10T7TP2SGAHTU15TE1TE15AT2CV13CV28S9S19601578CHLORONITROBENZENES,liquid6.1T1II6.1279LQ17P001IBC02MP15T7TP2L4BHTU15TE1TE15AT2CV13CV28S9S1960OfficialJournaloftheEuropeanUnionEN26.1.2004L18/301UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-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3CV28S9S19601601DISINFECTANT,SOLID,TOXIC,N.O.S.6.1T2III6.1274LQ9P002IBC08LP02R001B3MP10SGAHTU15TE1TE15AT2VV9bCV13CV28S960OfficialJournaloftheEuropeanUnionEN26.1.2004L18/305UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)1602DYE,LIQUID,TOXIC,N.O.S.orDYEINTERMEDIATE,LIQUID,TOXIC,N.O.S.6.1T1I6.1274LQ0P001MP8MP17L10CHTU14TU15TE1AT1CV1CV13CV28S9S17S20661602DYE,LIQUID,TOXIC,N.O.S.orDYEINTERMEDIATE,LIQUID,TOXIC,N.O.S.6.1T1II6.1274LQ17P001IBC02MP15L4BHTU15TE1TE15AT2CV13CV28S9S19601602DYE,LIQUID,TOXIC,N.O.S.orDYEINTERMEDIATE,LIQUID,TOXIC,N.O.S.6.1T1III6.1274LQ19P001IBC03LP01R001MP15L4BHTU15TE1TE15AT2CV13CV28S9601603ETHYLBROMOACETATE6.1TF1II6.1+3LQ17P001IBC02MP15T7TP2L4BHTU15TE1TE15FL2CV13CV28S2S9S19631604ETHYLENEDIAMINE8CF1II8+3LQ22P001IBC02MP15T7TP2L4BNFL2S2831605ETHYLENEDIBROMIDE6.1T1I6.1LQ0P601PR3MP8MP17T14TP2TP13L10CHTU14TU15TE1AT1CV1CV13CV28S9S17S20661606FERRICARSENATE6.1T5II6.1LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S1960OfficialJournaloftheEuropeanUnionEN26.1.2004L18/306UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)1607FERRICARSENITE6.1T5II6.1LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S19601608FERROUSARSENATE6.1T5II6.1LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S19601611HEXAETHYLTETRAPHO-SPHATE6.1T1II6.1LQ17P001IBC02MP15L4BHTU15TE1TE15AT2CV13CV28S9S19601612HEXAETHYLTETRAPHO-SPHATEANDCOMPRESSEDGASMIXTURE21T2.3LQ0P200MP9CxBH(M)TE1AT1V7CV9CV10CV28S7S17261613HYDROCYANICACID,AQUEOUSSOLUTION(HYDROGENCYANIDE,AQUEOUSSOLUTION)withnotmorethan20%hydrogencyanide6.1TF1I6.1+348LQ0P601PR3MP8MP17T14TP2TP13L15DH(+)TU14TU15TE1FL0CV1CV13CV28S2S9S176631614HYDROGENCYANIDE,STABILISED,containinglessthan3%waterandabsorbedinaporousinertmaterial6.1TF1I6.1+3603LQ0P200MP20CV1CV13CV28S2S9S10S171616LEADACETATE6.1T5III6.1LQ9P002IBC08LP02R001B3MP10SGAHL4BHTU15TE1TE15AT2VV9bCV13CV28S960OfficialJournaloftheEuropeanUnionEN26.1.2004L18/307UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)1617LEADARSENATES6.1T5II6.1LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S19601618LEADARSENITES6.1T5II6.1LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S19601620LEADCYANIDE6.1T5II6.1LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S19601621LONDONPURPLE6.1T5II6.143LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S19601622MAGNESIUMARSENATE6.1T5II6.1LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S19601623MERCURICARSENATE6.1T5II6.1LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S19601624MERCURICCHLORIDE6.1T5II6.1LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S19601625MERCURICNITRATE6.1T5II6.1LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S1960OfficialJournaloftheEuropeanUnionEN26.1.2004L18/308UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)1626MERCURICPOTASSIUMCYANIDE6.1T5I6.1LQ0P002IBC07B1MP18S10AHTU15TE1AT1CV1CV13CV28S9S17S20661627MERCUROUSNITRATE6.1T5II6.1LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S19601629MERCURYACETATE6.1T5II6.1LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S19601630MERCURYAMMONIUMCHLORIDE6.1T5II6.1LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S19601631MERCURYBENZOATE6.1T5II6.1LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S19601634MERCURYBROMIDES6.1T5II6.1LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S19601636MERCURYCYANIDE6.1T5II6.1LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S19601637MERCURYGLUCONATE6.1T5II6.1LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S1960OfficialJournaloftheEuropeanUnionEN26.1.2004L18/309UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)1638MERCURYIODIDE6.1T5II6.1LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S19601639MERCURYNUCLEATE6.1T5II6.1LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S19601640MERCURYOLEATE6.1T5II6.1LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S19601641MERCURYOXIDE6.1T5II6.1LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S19601642MERCURYOXYCYANIDE,DESENSITISED6.1T5II6.1LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S19601643MERCURYPOTASSIUMIODIDE6.1T5II6.1LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S19601644MERCURYSALICYLATE6.1T5II6.1LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S19601645MERCURYSULPHATE6.1T5II6.1LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S1960OfficialJournaloftheEuropeanUnionEN26.1.2004L18/310UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)1646MERCURYTHIOCYANATE6.1T5II6.1LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S19601647METHYLBROMIDEANDETHYLENEDIBROMIDEMIXTURE,LIQUID6.1T1I6.1LQ0P602MP8MP17L10CHTU14TU15TE1AT1CV1CV13CV28S9S17S20661648ACETONITRILE3F1II3LQ4P001IBC02R001MP19T7TP2LGBFFL2S2S20331649MOTORFUELANTI-KNOCKMIXTURE6.1T3I6.1162LQ0P602MP8MP17T14TP2TP13L10CHTU14TU15TE1TT6AT1CV1CV13CV28S9S17S20661650beta-NAPHTHYLAMINE6.1T2II6.1LQ18P002IBC08B2B4MP10T7TP2SGAHL4BHTU15TE1TE15AT2CV13CV28S9S19601651NAPHTHYLTHIOUREA6.1T2II6.143LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S19601652NAPHTHYLUREA6.1T2II6.1LQ18P002IBC08B2B4MP10SGAHTU15TE1TE15AT2CV13CV28S9S19601653NICKELCYANIDE6.1T5II6.1LQ18P002IBC08B2B4MP10SGAHL4BHTU15TE1TE15AT2CV13CV28S9S1960OfficialJournaloftheEuropeanUnionEN26.1.2004L18/311UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)1654NICOTINE6.1T1II6.1LQ17P001IBC02MP15L4BHTU15TE1TE15AT2CV13CV28S9S19601655NICOTINECOMPOUND,SOLID,N.O.S.orNICOTINEPREPARATION,SOLID,N.O.S.6.1T2I6.143274LQ0P002IBC07B1MP18S10AHTU15TE1AT1CV1CV13CV28S9S17S20661655NICOTINECOMPOUND,SOLID,N.O.S.orNICOTINEPREPARATION,SOLID,N.O.S.6.1T2II6.143274LQ18P002IBC08B2B4MP10SGAHL4BHTU15TE1TE15AT2CV13CV28S9S19601655NICOTINECOMPOUND,SOLID,N.O.S.orNICOTINEPREPARATION,SOLID,N.O.S.6.1T2III6.143274LQ9P002IBC08LP02R001B3MP10SGAHTU15TE1TE15AT2VV9bCV13CV28S9601656NICOTINEHYDRO-CHLORIDE,liquidorNICO-TINEHYDROCHLORIDESOLUTION6.1T1II6.143LQ17P001IBC02MP15L4BHTU15TE1TE15AT2CV13CV28S9S19601656NICOTINEHYDRO-CHLORIDE,solid6.1T2II6.143LQ18P001IBC02MP10SGAHTU15TE1TE15AT2CV13CV28S9S19601657NICOTINESALICYLATE,solid6.1T2II6.1LQ18P002IBC08B2B4MP10SGAHL4BHTU15TE1TE15AT2CV13CV28S9S1960OfficialJournaloftheEuropeanUnionEN26.1.2004L18/312UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingpr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Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)1950AEROSOLS25T2.3190625LQ1P204MP91CV9CV12CV28S71950AEROSOLS25TC2.3+8190625LQ1P204MP91CV9CV12CV28S71950AEROSOLS25TF2.3+2.1190625LQ1P204MP91CV9CV12CV28S2S71950AEROSOLS25TFC2.3+2.1+8190625LQ1P204MP91CV9CV12CV28S2S71950AEROSOLS25TO2.3+5.1190625LQ1P204MP91CV9CV12CV28S71950AEROSOLS25TOC2.3+5.1+8190625LQ1P204MP91CV9CV12CV28S71951ARGON,REFRIGERATEDLIQUID23A2.2593LQ1P203MP9T75RxBN(M)TU19AT3V5V7CV9CV11S20221952ETHYLENEOXIDEANDCARBONDIOXIDEMIXTUREwithnotmorethan9%ethyleneoxide22A2.2LQ1P200MP9PxBN(M)AT3V7CV9CV1020OfficialJournaloftheEuropeanUnionEN26.1.2004L18/347UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)1953COMPRESSEDGAS,TOXIC,FLAMMABLE,N.O.S.21TF2.3+2.1274LQ0P200MP9CxBH(M)TU6TE1FL1V7CV9CV10CV28S2S7S172631954COMPRESSEDGAS,FLAM-MABLE,N.O.S.21F2.1274LQ0P200MP9CxBN(M)FL2V7CV9CV10S2231955COMPRESSEDGAS,TOXIC,N.O.S.21T2.3274LQ0P200MP9CxBH(M)TU6TE1AT1V7CV9CV10CV28S7S17261956COMPRESSEDGAS,N.O.S.21A2.2274567LQ1P200MP9CxBN(M)AT3V7CV9CV10201957DEUTERIUM,COMPRESSED21F2.1LQ0P200MP9CxBN(M)FL2V7CV9CV10S22319581,2-DICHLORO-1,1,2,2-TETRAFLUOROETHANE(REFRIGERANTGASR114)22A2.2LQ1P200MP9T50PxBN(M)AT3V7CV9CV102019591,1-DIFLUOROETHYLENE(REFRIGERANTGASR1132a)22F2.1LQ0P200MP9PxBN(M)FL2V7CV9CV10S2S202391961ETHANE,REFRIGERATEDLIQUID23F2.1LQ0P203MP9T75RxBN(M)TU18FL2V5V7CV9CV11S2S172231962ETHYLENE,COMPRESSED21F2.1LQ0P200MP9CxBN(M)FL2V7CV9CV10S2231963HELIUM,REFRIGERATEDLIQUID23A2.2593LQ1P203MP9T75RxBN(M)TU19AT3V5V7CV9CV11S2022OfficialJournaloftheEuropeanUnionEN26.1.2004L18/348UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)1964HYDROCARBONGASMIXTURE,COMPRESSED,N.O.S.21F2.1274LQ0P200MP9CxBN(M)FL2V7CV9CV10S2231965HYDROCARBONGASMIXTURE,LIQUEFIED,N.O.S.suchasmixturesA,A01,A02,A1,B1,B2,BorC22F2.1274583LQ0P200MP9T50PxBN(M)FL2V7CV9CV10S2S20231966HYDROGEN,REFRIGER-ATEDLIQUID23F2.1LQ0P203MP9T75TP23RxBN(M)TU18FL2V5V7CV9CV11S2S172231967INSECTICIDEGAS,TOXIC,N.O.S.22T2.3274LQ0P200MP9PxBH(M)TU6TE1AT1V7CV9CV10CV28S7S17261968INSECTICIDEGAS,N.O.S.22A2.2274LQ1P200MP9PxBN(M)AT3V7CV9CV10201969ISOBUTANE22F2.1LQ0P200MP9T50PxBN(M)FL2V7CV9CV10S2S20231970KRYPTON,REFRIGERATEDLIQUID23A2.2593LQ1P203MP9T75RxBN(M)TU19AT3V5V7CV9CV11S2022OfficialJournaloftheEuropeanUnionEN26.1.2004L18/349UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)1971METHANE,COMPRESSEDorNATURALGAS,COMPRESSEDwithhighmethanecontent21F2.1LQ0P200MP9CxBN(M)FL2V7CV9CV10S2231972METHANE,REFRIGERATEDLIQUIDorNATURALGAS,REFRIGERATEDLIQUIDwithhighmethanecontent23F2.1LQ0P203MP9T75RxBN(M)TU18FL2V5V7CV9CV11S2S172231973CHLORODIFLUOROME-THANEANDCHLOROPEN-TAFLUORO-ETHANEMIXTUREwithfixedboilingpoint,withapproximately49%chlorodifluoromethane(REFRIGERANTGASR502)22A2.2LQ1P200MP9T50PxBN(M)AT3V7CV9CV10201974CHLORODIFLUORO-BROMO-METHANE(REFRIGERANTGASR12B1)22A2.2LQ1P200MP9T50PxBN(M)AT3V7CV9CV10201975NITRICOXIDEANDDINI-TROGENTETROXIDEMIXTURE(NITRICOXIDEANDNITROGENDIOXIDEMIXTURE)22TOC2.3+5.1+8LQ0P200MP91V7CV9CV10CV28S7S171976OCTAFLUOROCYCLOBU-TANE(REFRIGERANTGASRC318)22A2.2LQ1P200MP9T50PxBN(M)AT3V7CV9CV1020OfficialJournaloftheEuropeanUnionE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FOR-MATE6.1TFCII6.1+3+8LQ17P001MP15T20TP2TP13L4BHTU15TE1TE15FL2CV13CV28S2S9S196382744CYCLOBUTYLCHLORO-FORMATE6.1TFCII6.1+3+8LQ17P001IBC01MP15T7TP2TP13L4BHTU15TE1TE15FL2CV13CV28S2S9S196382745CHLOROMETHYLCHLORO-FORMATE6.1TC1II6.1+8LQ17P001IBC02MP15T7TP2TP13L4BHTU15TE1TE15AT2CV13CV28S9S19682746PHENYLCHLOROFORMATE6.1TC1II6.1+8LQ17P001IBC02MP15T7TP2TP13L4BHTU15TE1TE15AT2CV13CV28S9S1968OfficialJournaloftheEuropeanUnionEN26.1.2004L18/437UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)2747tert-BUTYLCYCLOHEXYLCHLOROFORMATE6.1T1III6.1LQ19P001IBC03LP01R001MP15T4TP1L4BHTU15TE1TE15AT2CV13CV28S96027482-ETHYLHEXYLCHLORO-FORMATE6.1TC1II6.1+8LQ17P001IBC02MP15T7TP2TP13L4BHTU15TE1TE15AT2CV13CV28S9S19682749TETRAMETHYLSILANE3F1I3LQ3P001MP7MP12T14TP2L4BNFL1S2S203327501,3-DICHLOROPROPANOL-26.1T1II6.1LQ17P001IBC02MP15T7TP2L4BHTU15TE1TE15AT2CV13CV28S9S19602751DIETHYLTHIOPHOSPHORYLCHLORIDE8C3II8LQ22P001IBC02MP15T7TP2L4BNAT28027521,2-EPOXY-3-ETHOXYPRO-PANE3F1III3LQ7P001IBC03LP01R001MP19T2TP1LGBFFL3S2302753N-ETHYLBENZYLTOLUI-DINES,LIQUID6.1T1III6.1LQ19P001IBC03LP01R001MP15T7TP1L4BHTU15TE1TE15AT2CV13CV28S9602753N-ETHYLBENZYLTOLUI-DINES,SOLID6.1T2III6.1LQ9P002IBC08LP02R001B3MP10T7TP1SGAHL4BHTU15TE1TE15AT2VV9bCV13CV28S960OfficialJournaloftheEuropeanUnionEN26.1.2004L18/438UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)2754N-ETHYLTOLUIDINES6.1T1II6.1LQ17P001IBC02MP15T7TP2L4BHTU15TE1TE15AT2CV13CV28S9S19602757CARBAMATEPESTICIDE,SOLID,TOXIC6.1T7I6.161LQ0P002IBC07B1MP18S10AHL10CHTU14TU15TE1AT1CV1CV13CV28S9S17S20662757CARBAMATEPESTICIDE,SOLID,TOXIC6.1T7II6.161LQ18P002IBC08B2B4MP10SGAHL4BHTU15TE1TE15AT2CV13CV28S9S19602757CARBAMATEPESTICIDE,SOLID,TOXIC6.1T7III6.161LQ9P002IBC08LP02R001B3MP10SGAHTU15TE1TE15AT2VV9bCV13CV28S9602758CARBAMATEPESTICIDE,LIQUID,FLAMMABLE,TOXIC3FT2I3+6.161LQ3P001MP7MP17T14TP2TP9TP13TP27L10CHTU14TU15TE1FL1CV13CV28S2S193362758CARBAMATEPESTICIDE,LIQUID,FLAMMABLE,TOXIC3FT2II3+6.161LQ4P001IBC02R001MP19T11TP2TP13TP27L4BHTU15TE1TE15FL2CV13CV28S2S193362759ARSENICALPESTICIDE,SOLID,TOXIC6.1T7I6.161LQ0P002IBC07B1MP18S10AHL10CHTU14TU15TE1AT1CV1CV13CV28S9S17S2066OfficialJournaloftheEuropeanUnionEN26.1.2004L18/439UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)2759ARSENICALPESTICIDE,SOLID,TOXIC6.1T7II6.161LQ18P002IBC08B2B4MP10SGAHL4BHTU15TE1TE15AT2CV13CV28S9S19602759ARSENICALPESTICIDE,SOLID,TOXIC6.1T7III6.161LQ9P002IBC08LP02R001B3MP10SGAHTU15TE1TE15AT2VV9bCV13CV28S9602760ARSENICALPESTICIDE,LIQUID,FLAMMABLE,TOXIC3FT2I3+6.161LQ3P001MP7MP17T14TP2TP9TP13TP27L10CHTU14TU15TE1FL1CV13CV28S2S193362760ARSENICALPESTICIDE,LIQUID,FLAMMABLE,TOXIC3FT2II3+6.161LQ4P001IBC02R001MP19T11TP2TP13TP27L4BHTU15TE1TE15FL2CV13CV28S2S193362761ORGANOCHLORINEPESTI-CIDE,SOLID,TOXIC6.1T7I6.161LQ0P002IBC07B1MP18S10AHL10CHTU14TU15TE1AT1CV1CV13CV28S9S17S20662761ORGANOCHLORINEPESTI-CIDE,SOLID,TOXIC6.1T7II6.161LQ18P002IBC08B2B4MP10SGAHL4BHTU15TE1TE15AT2CV13CV28S9S1960OfficialJournaloftheEuropeanUnionEN26.1.2004L18/440UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)2761ORGANOCHLORINEPESTI-CIDE,SOLID,TOXIC6.1T7III6.161LQ9P002IBC08LP02R001B3MP10SGAHTU15TE1TE15AT2VV9bCV13CV28S9602762ORGANOCHLORINEPESTI-CIDE,LIQUID,FLAMMABLE,TOXIC3FT2I3+6.161LQ3P001MP7MP17T14TP2TP9TP13TP27L10CHTU14TU15TE1TE15FL1CV13CV28S2S193362762ORGANOCHLORINEPESTI-CIDE,LIQUID,FLAMMABLE,TOXIC3FT2II3+6.161LQ4P001IBC02R001MP19T11TP2TP13TP27L4BHTU15TE1TE15FL2CV13CV28S2S193362763TRIAZINEPESTICIDE,SOLID,TOXIC6.1T7I6.161LQ0P002IBC07B1MP18S10AHL10CHTU14TU15TE1AT1CV1CV13CV28S9S17S20662763TRIAZINEPESTICIDE,SOLID,TOXIC6.1T7II6.161LQ18P002IBC08B2B4MP10SGAHL4BHTU15TE1TE15AT2CV13CV28S9S19602763TRIAZINEPESTICIDE,SOLID,TOXIC6.1T7III6.161LQ9P002IBC08R001B3MP10SGAHTU15TE1TE15AT2VV9bCV13CV28S960OfficialJournaloftheEuropeanUnionEN26.1.2004L18/441UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)2764TRIAZINEPESTICIDE,LIQUID,FLAMMABLE,TOXIC3FT2I3+6.161LQ3P001MP7MP17T14TP2TP9TP13TP27L10CHTU14TU15TE1FL1CV13CV28S2S193362764TRIAZINEPESTICIDE,LIQUID,FLAMMABLE,TOXIC3FT2II3+6.161LQ4P001IBC02R001MP19T11TP2TP13TP27L4BHTU15TE1TE15FL2CV13CV28S2S193362771THIOCARBAMATEPESTI-CIDE,SOLID,TOXIC6.1T7I6.161LQ0P002IBC07B1MP18S10AHL10CHTU14TU15TE1AT1CV1CV13CV28S9S17S20662771THIOCARBAMATEPESTI-CIDE,SOLID,TOXIC6.1T7II6.161LQ18P002IBC08B2B4MP10SGAHL4BHTU15TE1TE15AT2CV13CV28S9S19602771THIOCARBAMATEPESTI-CIDE,SOLID,TOXIC6.1T7III6.161LQ9P002IBC08LP02R001B3MP10SGAHL4BHTU15TE1TE15AT2VV9bCV13CV28S9602772THIOCARBAMATEPESTI-CIDE,LIQUID,FLAMMABLE,TOXIC3FT2I3+6.161LQ3P001MP7MP17T14TP2TP9TP13TP27L10CHTU14TU15TE1FL1CV13CV28S2S19336OfficialJournaloftheEuropeanUnionEN26.1.2004L18/442UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)2772THIOCARBAMATEPESTI-CIDE,LIQUID,FLAMMABLE,TOXIC3FT2II3+6.161LQ4P001IBC02R001MP19T11TP2TP13TP27L4BHTU15TE1TE15FL2CV13CV28S2S193362775COPPER-BASEDPESTICIDE,SOLID,TOXIC6.1T7I6.161LQ0P002IBC07B1MP18S10AHL10CHTU14TU15TE1AT1CV1CV13CV28S9S17S20662775COPPER-BASEDPESTICIDE,SOLID,TOXIC6.1T7II6.161LQ18P002IBC08B2B4MP10SGAHL4BHTU15TE1TE15AT2CV13CV28S9S19602775COPPER-BASEDPESTICIDE,SOLID,TOXIC6.1T7III6.161LQ9P002IBC08LP02R001B3MP10SGAHTU15TE1TE15AT2VV9bCV13CV28S9602776COPPER-BASEDPESTICIDE,LIQUID,FLAMMABLE,TOXIC3FT2I3+6.161LQ3P001MP7MP17T14TP2TP9TP13TP27L10CHTU14TU15TE1FL1CV13CV28S2S193362776COPPER-BASEDPESTICIDE,LIQUID,FLAMMABLE,TOXIC3FT2II3+6.161LQ4P001IBC02R001MP19T11TP2TP13TP27L4BHTU15TE1TE15FL2CV13CV28S2S19336OfficialJournaloftheEuropeanUnionEN26.1.2004L18/443UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)2777MERCURY-BASEDPESTI-CIDE,SOLID,TOXIC6.1T7I6.161LQ0P002IBC07B1MP18S10AHL10CHTU14TU15TE1AT1CV1CV13CV28S9S17S20662777MERCURY-BASEDPESTI-CIDE,SOLID,TOXIC6.1T7II6.161LQ18P002IBC08B2B4MP10SGAHL4BHTU15TE1TE15AT2CV13CV28S9S19602777MERCURY-BASEDPESTI-CIDE,SOLID,TOXIC6.1T7III6.161LQ9P002IBC08LP02R001B3MP10SGAHTU15TE1TE15AT2VV9bCV13CV28S9602778MERCURY-BASEDPESTI-CIDE,LIQUID,FLAMMABLE,TOXIC3FT2I3+6.161LQ3P001MP7MP17T14TP2TP9TP13TP27L10CHTU14TU15TE1FL1CV13CV28S2S193362778MERCURY-BASEDPESTI-CIDE,LIQUID,FLAMMABLE,TOXIC3FT2II3+6.161LQ4P001IBC02R001MP19T11TP2TP13TP27L4BHTU15TE1TE15FL2CV13CV28S2S193362779SUBSTITUTEDNITRO-PHENOLPESTICIDE,SOLID,TOXIC6.1T7I6.161LQ0P002IBC07B1MP18S10AHL10CHTU14TU15TE1AT1CV1CV13CV28S9S17S20662779SUBSTITUTEDNITRO-PHENOLPESTICIDE,SOLID,TOXIC6.1T7II6.161LQ18P002IBC08B2B4MP10SGAHL4BHTU15TE1TE15AT2CV13CV28S9S1960Offici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P2TP13TP27L4BHTU15TE1TE15AT2CV13CV28S9S19602788ORGANOTINCOMPOUND,LIQUID,N.O.S.6.1T3III6.143274LQ19P001IBC03LP01R001MP15T7TP2TP28L4BHTU15TE1TE15AT2CV13CV28S9602789ACETICACID,GLACIALorACETICACIDSOLUTION,morethan80%acid,bymass8CF1II8+3LQ22P001IBC02MP15T7TP2L4BNFL2S2832790ACETICACIDSOLUTION,notlessthan50%butnotmorethan80%acid,bymass8C3II8LQ22P001IBC02MP15T7TP2L4BNAT280OfficialJournaloftheEuropeanUnionEN26.1.2004L18/448UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)2790ACETICACIDSOLUTION,notlessthan10%butnotmorethan50%acid,bymass8C3III8597LQ19P001IBC03LP01R001MP15T4TP1L4BNAT3802793FERROUSMETALBORINGS,SHAVINGS,TURNINGSorCUTTINGSinaformliabletoself-heating4.2S4III4.2107592LQ0P003IBC08LP02R001PP20B3B6MP143V1VV4402794BATTERIES,WET,FILLEDWITHACID,electricstorage8C118295598LQ0P801P801a3VV14802795BATTERIES,WET,FILLEDWITHALKALI,electricstorage8C118295598LQ0P801P801a3VV14802796SULPHURICACIDwithnotmorethan51%acidorBATTERYFLUID,ACID8C1II8LQ22P001IBC02MP15T8TP2TP12L4BNAT2802797BATTERYFLUID,ALKALI8C5II8LQ22P001IBC02T7TP2L4BNAT2802798PHENYLPHOSPHORUSDICHLORIDE8C3II8LQ22P001IBC02MP15T7TP2L4BNAT280OfficialJournaloftheEuropeanUnionEN26.1.2004L18/449UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)2799PHENYLPHOSPHORUSTHIODICHLORIDE8C3II8LQ22P001IBC02MP15T7TP2L4BNAT2802800BATTERIES,WET,NON-SPILLABLE,electricstorage8C118238295598LQ0P003P801aPP163VV14802801DYE,LIQUID,CORROSIVE,N.O.S.orDYEINTER-MEDIATE,LIQUID,CORRO-SIVE,N.O.S.8C9I8274LQ20P001MP8MP17T14TP2TP9TP27L10BHTE1AT1S20882801DYE,LIQUID,CORROSIVE,N.O.S.orDYEINTER-MEDIATE,LIQUID,CORRO-SIVE,N.O.S.8C9II8274LQ22P001IBC02MP15T11TP2TP27L4BNAT2802801DYE,LIQUID,CORROSIVE,N.O.S.orDYEINTER-MEDIATE,LIQUID,CORRO-SIVE,N.O.S.8C9III8274LQ19P001IBC03LP01R001MP15T7TP1TP28L4BNAT3802802COPPERCHLORIDE8C2III8LQ24P002IBC08LP02R001B3MP10SGAVAT3VV9b802803GALLIUM8C10III8LQ24P800PP41MP10SGAVL4BNAT3VV9b80OfficialJournaloftheEuropeanUnionEN26.1.2004L18/450UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)2805LITHIUMHYDRIDE,FUSEDSOLID4.3W2II4.3LQ11P410IBC04MP14SGANAT2CV234232806LITHIUMNITRIDE4.3W2I4.3LQ0P403IBC04B1MP21CV23S2S202807Magnetisedmaterial9M11NOTSUBJECTTOADR2809MERCURY8C9III8599LQ19P800MP15L4BNAT3802810TOXICLIQUID,ORGANIC,N.O.S.6.1T1I6.1274614LQ0P001MP8MP17T14TP2TP9TP13TP27L10CHTU14TU15TE1AT1CV1CV13CV28S9S17S20662810TOXICLIQUID,ORGANIC,N.O.S.6.1T1II6.1274614LQ17P001IBC02MP15T11TP2TP13TP27L4BHTU15TE1TE15AT2CV13CV28S9S19602810TOXICLIQUID,ORGANIC,N.O.S.6.1T1III6.1274614LQ19P001IBC03LP01R001MP15T7TP1TP28L4BHTU15TE1TE15AT2CV13CV28S9602811TOXICSOLID,ORGANIC,N.O.S.6.1T2I6.1274614LQ0P002IBC02MP18S10AHTU15TE1AT1CV1CV13CV28S9S17S20662811TOXICSOLID,ORGANIC,N.O.S.6.1T2II6.1274614LQ18P002IBC08B2B4MP10SGAHL4BHTU15TE1TE15AT2CV13CV28S9S19602811TOXICSOLID,ORGANIC,N.O.S.6.1T2III6.1274614LQ9P002IBC08LP02R001B3MP10SGAHTU15TE1TE15AT2VV9bCV13CV28S960OfficialJournaloftheEuropeanUnionEN26.1.2004L18/451UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8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efortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)2915RADIOACTIVEMATERIAL,TYPEAPACKAGE,non-specialform,nonfissileorfissile-excepted77X172LQ0See2.7and4.1.9See4.1.9.1.30CV33S6S11S12S13S212916RADIOACTIVEMATERIAL,TYPEB(U)PACKAGE,nonfissileorfissile-excepted77X172LQ0See2.7and4.1.9See4.1.9.1.30CV33S6S11S13S212917RADIOACTIVEMATERIAL,TYPEB(M)PACKAGE,nonfissileorfissile-excepted77X172LQ0See2.7and4.1.9See4.1.9.1.30CV33S6S11S13S212919RADIOACTIVEMATERIAL,TRANSPORTEDUNDERSPECIALARRANGEMENT,nonfissileorfissile-excepted77X172LQ0See2.7and4.1.9See4.1.9.1.3CV33S6S11S13S212920CORROSIVELIQUID,FLAM-MABLE,N.O.S.8CF1I8+3274LQ20P001MP8MP17T14TP2TP9TP27L10BHTE1FL1S2S208832920CORROSIVELIQUID,FLAM-MABLE,N.O.S.8CF1II8+3274LQ22P001IBC02MP15T11TP2TP27L4BNFL2S283OfficialJournaloftheEuropeanUnionEN26.1.2004L18/464UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)2921CORROSIVESOLID,FLAM-MABLE,N.O.S.8CF2I8+4.1274LQ21P002IBC05MP18S10ANL10BHTE1AT1S208842921CORROSIVESOLID,FLAM-MABLE,N.O.S.8CF2II8+4.1274LQ23P002IBC08B2B4MP10SGANL4BNAT2842922CORROSIVELIQUID,TOXIC,N.O.S.8CT1I8+6.1274LQ20P001MP8MP17T14TP2TP9TP13TP27L10BHTE1AT1CV13CV28S208862922CORROSIVELIQUID,TOXIC,N.O.S.8CT1II8+6.1274LQ22P001IBC02MP15T7TP2L4BNAT2CV13CV28862922CORROSIVELIQUID,TOXIC,N.O.S.8CT1III8+6.1274LQ19P001IBC03R001MP15T7TP1TP28L4BNAT3CV13CV28862923CORROSIVESOLID,TOXIC,N.O.S.8CT2I8+6.1274LQ21P002IBC05MP18S10ANL10BHTE1AT1CV13CV28S208862923CORROSIVESOLID,TOXIC,N.O.S.8CT2II8+6.1274LQ23P002IBC08B2B4MP10SGANL4BNAT2CV13CV28862923CORROSIVESOLID,TOXIC,N.O.S.8CT2III8+6.1274LQ24P002IBC08R001B3MP10SGAVL4BNAT3VV9bCV13CV28862924FLAMMABLELIQUID,CORROSIVE,N.O.S.3FCI3+8274LQ3P001MP7MP17T14TP2TP9L10CHTU14TE1FL1S2S20338OfficialJournaloftheEuropeanUnionEN26.1.2004L18/465UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)2924FLAMMABLELIQUID,CORROSIVE,N.O.S.3FCII3+8274LQ4P001IBC02MP19T11TP2TP27L4BHTE1FL2S2S203382924FLAMMABLELIQUID,CORROSIVE,N.O.S.3FCIII3+8274LQ7P001IBC03R001MP19T7TP1TP28L4BNFL3S2382925FLAMMABLESOLID,CORROSIVE,ORGANIC,N.O.S.4.1FC1II4.1+8274LQ0P002IBC06B2MP10SGANAT2482925FLAMMABLESOLID,CORROSIVE,ORGANIC,N.O.S.4.1FC1III4.1+8274LQ0P002IBC06R001MP10SGANAT3482926FLAMMABLESOLID,TOXIC,ORGANIC,N.O.S.4.1FT1II4.1+6.1274LQ0P002IBC06B2MP10SGANAT2CV28462926FLAMMABLESOLID,TOXIC,ORGANIC,N.O.S.4.1FT1III4.1+6.1274LQ0P002IBC06R001MP10SGANAT3CV28462927TOXICLIQUID,CORRO-SIVE,ORGANIC,N.O.S.6.1TC1I6.1+8274LQ0P001MP8MP17T14TP2TP9TP13TP27L10CHTU14TU15TE1TE19AT1CV1CV13CV28S9S176682927TOXICLIQUID,CORRO-SIVE,ORGANIC,N.O.S.6.1TC1II6.1+8274LQ17P001IBC02MP15T11TP2TP27L4BHTU15TE1TE19AT2CV13CV28S9S1968OfficialJournaloftheEuropeanUnionEN26.1.2004L18/466UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)2928TOXICSOLID,CORROSIVE,ORGANIC,N.O.S.6.1TC2I6.1+8274LQ0P002IBC05MP18S10AHTU14TU15TE1TE19AT1CV1CV13CV28S9S176682928TOXICSOLID,CORROSIVE,ORGANIC,N.O.S.6.1TC2II6.1+8274LQ18P002IBC06B2MP10SGAHL4BHTU15TE1TE19AT2CV13CV28S9S19682929TOXICLIQUID,FLAM-MABLE,ORGANIC,N.O.S.6.1TF1I6.1+3274LQ0P001MP8MP17T14TP2TP9TP13TP27L10CHTU14TU15TE1TE19FL1CV1CV13CV28S2S9S176632929TOXICLIQ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UORIDE,nonfissileorfissile-excepted77X+8172LQ0See2.7and4.1.9See4.1.9.1.30CV33S6S11S13S212983ETHYLENEOXIDEANDPROPYLENEOXIDEMIXTURE,notmorethan30%ethyleneoxide3FT1I3+6.1LQ0P200MP7MP17T14TP2TP7TP13L10CHTU14TU15TE1FL1CV13CV28S2S193362984HYDROGENPEROXIDE,AQUEOUSSOLUTIONwithnotlessthan8%butlessthan20%hydrogenperoxide(stabilisedasneces-sary)5.1O1III5.165LQ13P504IBC02R001B5MP15T4TP1TP6TP24LGBVTU3TC2TE8TE11TT1AT3CV24502985CHLOROSILANES,FLAM-MABLE,CORROSIVE,N.O.S.3FCII3+8274548LQ4P001IBC02MP19T11TP2TP13TP27L4BHTE1FL2S2S20X338OfficialJournaloftheEuropeanUnionEN26.1.2004L18/471UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)2986CHLOROSILANES,CORRO-SIVE,FLAMMABLE,N.O.S.8CF1II8+3274548LQ22P001IBC02MP15T11TP2TP27L4BNFL2S2X832987CHLOROSILANES,CORRO-SIVE,N.O.S.8C3II8274548LQ22P001IBC02MP15T14TP2TP27L4BNAT2X802988CHLOROSILANES,WATER-REACTIVE,FLAMMABLE,CORROSIVE,N.O.S.4.3WFCI4.3+3+8274549LQ0P401PR2MP2T10TP2TP7TP9TP13L10DHTU14TU26TE1TM2TM3FL0V1CV23S2X3382989LEADPHOSPHITE,DIBASIC4.1F3II4.1LQ8P002IBC08B2B4MP11SGANAT2402989LEADPHOSPHITE,DIBASIC4.1F3III4.1LQ9P002IBC08LP02R001B3MP11SGAVAT3VV1402990LIFE-SAVINGAPPLIANCES,SELF-INFLATING9M59296635LQ0P9053V12991CARBAMATEPESTICIDE,LIQUID,TOXIC,FLAM-MABLE6.1TF2I6.1+361LQ0P001MP8MP17T14TP2TP9TP13TP27L10CHTU14TU15TE1TE19FL1CV1CV13CV28S2S9S17663OfficialJournaloftheEuropeanUnionEN26.1.2004L18/472UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)2991CARBAMATEPESTICIDE,LIQUID,TOXIC,FLAM-MABLE6.1TF2II6.1+361LQ17P001IBC02MP15T11TP2TP13TP27L4BHTU15TE1TE19FL2CV13CV28S2S9S19632991CARBAMATEPESTICIDE,LIQUID,TOXIC,FLAM-MABLE6.1TF2III6.1+361LQ19P001IBC03R001MP15T7TP2TP28L4BHTU15TE1TE19FL2CV13CV28S2S9632992CARBAMATEPESTICIDE,LIQUID,TOXIC6.1T6I6.161LQ0P001MP8MP17T14TP2TP9TP13TP27L10CHTU14TU15TE1TE19AT1CV1CV13CV28S9S17662992CARBAMATEPESTICIDE,LIQUID,TOXIC6.1T6II6.161LQ17P001IBC02MP15T11TP2TP13TP27L4BHTU15TE1TE19AT2CV13CV28S9S19602992CARBAMATEPESTICIDE,LIQUID,TOXIC6.1T6III6.161LQ19P001IBC03LP01R001MP15T7TP2TP28L4BHTU15TE1TE19AT2CV13CV28S960OfficialJournaloftheEuropeanUnionEN26.1.2004L18/473UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)2993ARSENICALPESTICIDE,LIQUID,TOXIC,FLAM-MABLE6.1TF2I6.1+361LQ0P001MP8MP17T14TP2TP9TP13TP27L10CHTU14TU15TE1TE19FL1CV1CV13CV28S2S9S176632993ARSENICALPESTICIDE,LIQUID,TOXIC,FLAM-MABLE6.1TF2II6.1+361LQ17P001IBC02MP15T11TP2TP13TP27L4BHTU15TE1TE19FL2CV13CV28S2S9S19632993ARSENICALPESTICIDE,LIQUID,TOXIC,FLAM-MABLE6.1TF2III6.1+361LQ19P001IBC03R001MP15T7TP2TP28L4BHTU15TE1TE19FL2CV13CV28S2S9632994ARSENICALPESTICIDE,LIQUID,TOXIC6.1T6I6.161LQ0P001MP8MP17T14TP2TP9TP13TP27L10CHTU14TU15TE1TE19AT1CV1CV13CV28S9S17662994ARSENICALPESTICIDE,LIQUID,TOXIC6.1T6II6.161LQ17P001IBC02MP15T11TP2TP13TP27L4BHTU15TE1TE19AT2CV13CV28S9S19602994ARSENICALPESTICIDE,LIQUID,TOXIC6.1T6III6.161LQ19P001IBC03LP01R001MP15T7TP2TP28L4BHTU15TE1TE19AT2CV13CV28S960OfficialJournaloftheEuropeanUnionEN26.1.2004L18/474UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4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STICIDE,LIQUID,TOXIC6.1T6I6.161LQ0P001MP8MP17T14TP2TP9TP13TP27L10CHTU14TU15TE1AT1CV1CV13CV28S9S17S20663026COUMARINDERIVATIVEPESTICIDE,LIQUID,TOXIC6.1T6II6.161LQ17P001IBC02MP15T11TP2TP27L4BHTU15TE1TE15AT2CV13CV28S9S19603026COUMARINDERIVATIVEPESTICIDE,LIQUID,TOXIC6.1T6III6.161LQ19P001IBC03LP01R001MP15T7TP1TP28L4BHTU15TE1TE15AT2CV13CV28S9603027COUMARINDERIVATIVEPESTICIDE,SOLID,TOXIC6.1T7I6.161LQ0P002IBC07B1MP18T14TP2TP9TP27S10AHL10CHTU14TU15TE1AT1CV1CV13CV28S9S17S20663027COUMARINDERIVATIVEPESTICIDE,SOLID,TOXIC6.1T7II6.161LQ18P002IBC08B2B4MP10T11TP2TP27SGAHL4BHTU15TE1TE15AT2CV13CV28S9S1960OfficialJournaloftheEuropeanUnionEN26.1.2004L18/486UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)3027COUMARINDERIVATIVEPESTICIDE,SOLID,TOXIC6.1T7III6.161LQ9P002IBC08LP02R001B3MP10T7TP1TP28SGAHTU15TE1TE15AT2VV9bCV13CV28S9603028BATTERIES,DRY,CONTAININGPOTASSIUMHYDROXIDESOLID,electricstorage8C118295598LQ0P801P801a3VV14803048ALUMINIUMPHOSPHIDEPESTICIDE6.1T7I6.161153LQ0P002IBC07B1MP18S10AHTU15TE1AT1CV1CV13CV28S9S17S206423049METALALKYLHALIDES,WATER-REACTIVE,N.O.S.orMETALARYLHALIDES,WATER-REACTIVE,N.O.S.4.2SWI4.2+4.3274527LQ0P400PR1MP2T21TP2TP7TP9L21DHTU4TU14TU22TC1TE1TM1AT0V1S20X3333050METALALKYLHYDRIDES,WATER-REACTIVE,N.O.S.orMETALARYLHYDRIDES,WATER-REACTIVE,N.O.S.4.2SWI4.2+4.3274527LQ0P400PR1MP2T21TP2TP7L21DHTU4TU14TU22TC1TE1TM1AT0V1S20X3333051ALUMINIUMALKYLS4.2SWI4.2+4.3274LQ0P400PR1MP2T21TP2TP7TP9L21DHTU4TU14TU22TC1TE1TM1AT0V1S20X333OfficialJournaloftheEuropeanUnionEN26.1.2004L18/487UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)3052ALUMINIUMALKYLHALIDES,LIQUID4.2SWI4.2+4.3274LQ0P400PR1MP2T21TP2TP7L21DHTU4TU14TU22TC1TE1TM1AT0V1S20X3333052ALUMINIUMALKYLHALIDES,SOLID4.2SWI4.2+4.3274LQ0P400PR1MP2T21TP2TP7L21DHTU4TU14TU22TC1TE1TM1AT0V1S20X3333053MAGNESIUMALKYLS4.2SWI4.2+4.3274LQ0P400PR1MP2T21TP2TP7L21DHTU4TU14TU22TC1TE1TM1AT0V1S20X3333054CYCLOHEXYLMERCAPTAN3F1III3LQ7P001IBC03LP01R001MP19T2TP1LGBFFL3S23030552-(2-AMINOETHOX-Y)ETHANOL8C7III8LQ19P001IBC03LP01R001MP15T4TP1L4BNAT380OfficialJournaloftheEuropeanUnionEN26.1.2004L18/488UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)3056n-HEPTALDEHYDE3F1III3LQ7P001IBC03LP01R001MP19T2TP1LGBFFL3S2303057TRIFLUOROACETYLCHLORIDE22TC2.3+8LQ0P200MP9T50TP21PxBH(M)TE1AT1V7CV9CV10CV28S7S172683064NITROGLYCERIN,SOLU-TIONINALCOHOLwithmorethan1%butnotmorethan5%nitrogly-cerine3DII3LQ0P300MP22S2S193065ALCOHOLICBEVERAGES,withmorethan70%alcoholbyvolume3F1II3144145247LQ5P001IBC02R001PP2MP19T4TP1LGBFFL2S2S20333065ALCOHOLICBEVERAGES,withmorethan24%butnotmorethan70%alcoholbyvolume3F1III3144145247LQ7P001IBC03R001PP2MP19T2TP1LGBFFL3S2303066PAINT(includingpaint,lacquer,enamel,stain,shellac,varnish,polish,liquidfillerandliquidlacquerbase)orPAINTRELATEDMATE-RIAL(includingpaintthin-ningandreducingcompound)8C9II8163LQ22P001IBC02MP15T7TP2L4BNAT280OfficialJournaloftheEuropeanUnionEN26.1.2004L18/489UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)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YPEC,TEMPERATURECONTROLLED4.1SR24.1194274LQ0P520PP21MP21V8CV15CV20CV21CV22S4S8S17S18OfficialJournaloftheEuropeanUnionEN26.1.2004L18/524UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)3235SELF-REACTIVELIQUIDTYPED,TEMPERATURECONTROLLED4.1SR24.1194274LQ0P520MP21V8CV15CV21CV22S4S183236SELF-REACTIVESOLIDTYPED,TEMPERATURECONTROLLED4.1SR24.1194274LQ0P520MP21V8CV15CV21CV22S4S183237SELF-REACTIVELIQUIDTYPEE,TEMPERATURECONTROLLED4.1SR24.1194274LQ0P520MP21V8CV15CV21CV22S4S193238SELF-REACTIVESOLIDTYPEE,TEMPERATURECONTROLLED4.1SR24.1194274LQ0P520MP21V8CV15CV21CV22S4S193239SELF-REACTIVELIQUIDTYPEF,TEMPERATURECONTROLLED4.1SR24.1194274LQ0P520MP2T231V8CV15CV21CV22S43240SELF-REACTIVESOLIDTYPEF,TEMPERATURECONTROLLED4.1SR24.1194274LQ0P520MP2T23ST(+)1V8CV15CV21CV22S432412-BROMO-2-NITROPRO-PANE-1,3-DIOL4.1SR1III4.1638LQ0P520IBC08PP22B3MP23CV14S143242AZODICARBONAMIDE4.1SR1II4.1215638LQ0P409MP22CV14S143243SOLIDSCONTAININGTOXICLIQUID,N.O.S.6.1T9II6.1217274LQ18P002IBC02PP9MP15SGAHTU15TE1TE15AT2VV10CV13CV28S9S1960OfficialJournaloftheEuropeanUnionEN26.1.2004L18/525UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)3244SOLIDSCONTAININGCORROSIVELIQUID,N.O.S.8C10II8218274LQ23P002IBC05PP9MP10SGAVAT2VV9803245GENETICALLYMODIFIEDMICRO-ORGANISMS9M89219634637LQ0P904IBC08MP62V1CV1CV13CV26CV27CV28S173246METHANESULPHONYLCHLORIDE6.1TC1I6.1+8LQ0P001MP8MP17T14TP2TP12TP13L10CHTU14TU15TE1AT1CV1CV13CV28S9S17S206683247SODIUMPEROXOBORATE,ANHYDROUS5.1O2II5.1LQ11P002IBC08B4MP2SGANTU3AT2CV24503248MEDICINE,LIQUID,FLAM-MABLE,TOXIC,N.O.S.3FT1II3+6.1220221274601LQ0P001PP6MP19L4BHTU15TE1TE15FL2CV13CV28S2S193363248MEDICINE,LIQUID,FLAM-MABLE,TOXIC,N.O.S.3FT1III3+6.1220221274601LQ7P001R001PP6MP19L4BHTU15TE1TE15FL3CV13CV28S2363249MEDICINE,SOLID,TOXIC,N.O.S.6.1T2II6.1221274601LQ18P002PP6MP10SGAHL4BHTU15TE1TE15AT2CV13CV28S9S1960OfficialJournaloftheEuropeanUnionEN26.1.2004L18/526UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)3249MEDICINE,SOLID,TOXIC,N.O.S.6.1T2III6.1221274601LQ9P002LP02R001PP6MP10SGAHTU15TE1TE15AT2VV9bCV13CV28S9603250CHLOROACETICACID,MOLTEN6.1TC1II6.1+8LQ0T7TP3L4BHTU15TC4TE1TE15AT2V4CV13CV28S9S19683251ISOSORBIDE-5-MONONI-TRATE4.1SR1III4.1226638LQ0P409MP23CV14S143252DIFLUOROMETHANE(REFRIGERANTGASR32)22F2.1LQ0P200MP9T50PxBN(M)FL2V7CV9CV10S2S20233253DISODIUMTRIOXOSILI-CATE8C6III8LQ24P002IBC08LP02R001B3MP10SGAVAT3VV9b803254TRIBUTYLPHOSPHANE4.2S1I4.2LQ0P400MP20V13255tert-BUTYLHYPOCHLORITE4.2SC1CARRIAGEPROHIBITEDOfficialJournaloftheEuropeanUnionEN26.1.2004L18/527UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)3256ELEVATEDTEMPERATURELIQUID,FLAMMABLE,N.O.S.withflash-pointabove61°C,atoraboveitsflash-point3F2III3274560LQ0P099IBC99MP2T3TP3TP29LGAVTU35TE2FL3S2303257ELEVATEDTEMPERATURELIQUID,N.O.S.,atorabove100°Candbelowitsflash-point(includingmoltenmetals,moltensalts,etc.)9M9III9274580643LQ0P099IBC99T3TP3TP29LGAVTU35TC7TE2TE14TE18AT3VV129932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TP27L4BHTU15TE1TE19FL2CV13CV28S2S9S1963OfficialJournaloftheEuropeanUnionEN26.1.2004L18/535UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)3280ORGANOARSENICCOMPOUND,N.O.S.,liquid6.1T3I6.1274LQ0P001MP8MP17T14TP2TP9TP13TP27L10CHTU14TU15TE1TE19AT1CV1CV13CV28S9S17663280ORGANOARSENICCOMPOUND,N.O.S.,liquid6.1T3II6.1274LQ17P001IBC02MP15T11TP2TP27L4BHTU15TE1TE19AT2CV13CV28S9S19603280ORGANOARSENICCOMPOUND,N.O.S.,liquid6.1T3III6.1274LQ19P001IBC03LP01R001MP15T7TP1TP28L4BHTU15TE1TE19AT2CV13CV28S9603280ORGANOARSENICCOMPOUND,N.O.S.,solid6.1T3I6.1274LQ0P002IBC07B1MP18T14TP2TP9TP27S10AHL10CHTU14TU15TE1TE19AT1CV1CV13CV28S9S17663280ORGANOARSENICCOMPOUND,N.O.S.,solid6.1T3II6.1274LQ18P002IBC08B2B4MP10T11TP2TP27SGAHL4BHTU15TE1TE19AT2CV13CV28S9S19603280ORGANOARSENICCOMPOUND,N.O.S.,solid6.1T3III6.1274LQ19P002IBC08LP02R001B3MP10T7TP1TP28SGAHL4BHTU15TE1TE19AT2VV9bCV13CV28S9603281METALCARBONYLS,N.O.S.,liquid6.1T3I6.1274562LQ0P601MP8MP17T14TP2TP9TP13TP27L10CHTU14TU15TE1TE19AT1CV1CV13CV28S9S1766OfficialJournaloftheEuropeanUnionEN26.1.2004L18/536UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)3281METALCARBONYLS,N.O.S.,liquid6.1T3II6.1274562LQ17P001IBC02MP15T11TP2TP27L4BHTU15TE1TE19AT2CV13CV28S9S19603281METALCARBONYLS,N.O.S.,liquid6.1T3III6.1274562LQ19P001IBC03LP01R001MP15T7TP1TP28L4BHTU15TE1TE19AT2CV13CV28S9603281METALCARBONYLS,N.O.S.,solid6.1T3I6.1274562LQ0P002IBC07B1MP18T14TP2TP9TP27S10AHL10CHTU14TU15TE1TE19AT1CV1CV13CV28S9S17663281METALCARBONYLS,N.O.S.,solid6.1T3II6.1274562LQ18P002IBC08B2B4MP10T11TP2TP27SGAHL4BHTU15TE1TE19AT2CV13CV28S9S19603281METALCARBONYLS,N.O.S.,solid6.1T3III6.1274562LQ9P002IBC08LP02R001B3MP10T7TP1TP28SGAHL4BHTU15TE1TE19AT2VV9bCV13CV28S9603282ORGANOMETALLICCOMPOUND,TOXIC,N.O.S.,liquid6.1T3I6.1274562LQ0P001MP8MP17T14TP2TP9TP13TP27L10CHTU14TU15TE1TE19AT1CV1CV13CV28S9S17663282ORGANOMETALLICCOMPOUND,TOXIC,N.O.S.,liquid6.1T3II6.1274562LQ17P001IBC02MP15T11TP2TP27L4BHTU15TE1TE19AT2CV13CV28S9S1960OfficialJournaloftheEuropeanUnionEN26.1.2004L18/537UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)3282ORGANOMETALLICCOMPOUND,TOXIC,N.O.S.,liquid6.1T3III6.1274562LQ19P001IBC03LP01R001MP15T7TP1TP28L4BHTU15TE1TE19AT2CV13CV28S9603282ORGANOMETALLICCOMPOUND,TOXIC,N.O.S.,solid6.1T3I6.1274562LQ0P002IBC07B1MP18T14TP2TP9TP27S10AHL10CHTU14TU15TE1TE19AT1CV1CV13CV28S9S17663282ORGANOMETALLICCOMPOUND,TOXIC,N.O.S.,solid6.1T3II6.1274562LQ18P002IBC08B2B4MP10T11TP2TP27SGAHL4BHTU15TE1TE19AT2CV13CV28S9S19603282ORGANOMETALLICCOMPOUND,TOXIC,N.O.S.,solid6.1T3III6.1274562LQ9P002IBC08LP02R001B3MP10T7TP1TP28SGAHL4BHTU15TE1TE19AT2VV9bCV13CV28S9603283SELENIUMCOMPOUND,N.O.S.6.1T5I6.1274563LQ0P002IBC07B1MP18T14TP2TP9TP27S10AHL10CHTU14TU15TE1TE19AT1CV1CV13CV28S9S17663283SELENIUMCOMPOUND,N.O.S.6.1T5II6.1274563LQ18P002IBC07MP10T11TP2TP27SGAHL4BHTU15TE1TE19AT2CV13CV28S9S19603283SELENIUMCOMPOUND,N.O.S.6.1T5III6.1274563LQ9P002IBC07R001MP10T7TP1TP28SGAHL4BHTU15TE1TE19AT2VV9bCV13CV28S960OfficialJournaloftheEuropeanUnionEN26.1.2004L18/538UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Pac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ethan175kPa)3F1II3274640LQ4P001MP19T7TP1TP8TP28L1.5BNFL2S2S20333295HYDROCARBONS,LIQUID,N.O.S.(vapourpressureat50°Cnotmorethan110kPa)3F1II3274640LQ4P001IBC02R001MP19T7TP1TP8TP28LGBFFL2S2S2033OfficialJournaloftheEuropeanUnionEN26.1.2004L18/542UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)3295HYDROCARBONS,LIQUID,N.O.S.3F1III3274LQ7P001IBC03LP01R001MP19T4TP1TP29LGBFFL3S2303296HEPTAFLUOROPROPANE(REFRIGERANTGASR227)22A2.2LQ1P200MP9T50PxBN(M)AT3V7CV9CV10203297ETHYLENEOXIDEANDCHLOROTETRAFLUORO-ETHANEMIXTUREwithnotmorethan8,8%ethyleneoxide22A2.2LQ1P200MP9T50PxBN(M)AT3V7CV9CV10203298ETHYLENEOXIDEANDPENTAFLUOROETHANEMIXTUREwithnotmorethan7,9%ethyleneoxide22A2.2LQ1P200MP9T50PxBN(M)AT3V7CV9CV10203299ETHYLENEOXIDEANDTETRAFLUOROETHANEMIXTUREwithnotmorethan5,6%ethyleneoxide22A2.2LQ1P200MP9T50PxBN(M)AT3V7CV9CV10203300ETHYLENEOXIDEANDCARBONDIOXIDEMIXTUREwithmorethan87%ethyleneoxide22TF2.3+2.1LQ0P200MP9PxBH(M)TE1FL1V7CV9CV10S2S7S17263OfficialJournaloftheEuropeanUnionEN26.1.2004L18/543UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)3301CORROSIVELIQUID,SELF-HEATING,N.O.S.8CS1I8+4.2274LQ20P001MP8MP17L10BHTE1AT1S208843301CORROSIVELIQUID,SELF-HEATING,N.O.S.8CS1II8+4.2274LQ22P001MP15L4BNAT28433022-DIMETHYLAMINOETHYLACRYLATE6.1T1II6.1LQ17P001IBC02MP15T7TP2L4BHTU15TE1TE19AT2CV13CV28S9S19603303COMPRESSEDGAS,TOXIC,OXIDISING,N.O.S.21TO2.3+5.1274LQ0P200MP9CxBH(M)TU6TE1AT1V7CV9CV10S7S172653304COMPRESSEDGAS,TOXIC,CORROSIVE,N.O.S.21TC2.3+8274LQ0P200MP9CxBH(M)TU6TE1AT1V7CV9CV10S7S172683305COMPRESSEDGAS,TOXIC,FLAMMABLE,CORROSIVE,N.O.S.21TFC2.3+2.1+8274LQ0P200MP9CxBH(M)TU6TE1FL1V7CV9CV10S2S7S172633306COMPRESSEDGAS,TOXIC,OXIDISING,CORROSIVE,N.O.S.21TOC2.3+5.1+8274LQ0P200MP9CxBH(M)TU6TE1AT1V7CV9CV10S7S17265OfficialJournaloftheEuropeanUnionEN26.1.2004L18/544UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)3307LIQUEFIEDGAS,TOXIC,OXIDISING,N.O.S.22TO2.3+5.1274LQ0P200MP9PxBH(M)TU6TE1AT1V7CV9CV10S7S172653308LIQUEFIEDGAS,TOXIC,CORROSIVE,N.O.S.22TC2.3+8274LQ0P200MP9PxBH(M)TU6TE1AT1V7CV9CV10S7S172683309LIQUEFIEDGAS,TOXIC,FLAMMABLE,CORROSIVE,N.O.S.22TFC2.3+2.1+8274LQ0P200MP9PxBH(M)TU6TE1FL1V7CV9CV10S2S7S172633310LIQUEFIEDGAS,TOXIC,OXIDISING,CORROSIVE,N.O.S.22TOC2.3+5.1+8274LQ0P200MP9PxBH(M)TU6TE1AT1V7CV9CV10S7S172653311GAS,REFRIGERATEDLIQUID,OXIDISING,N.O.S.23O2.2+5.1274LQ0P203MP9T75TP22RxBN(M)TU7TU19AT3V5V7CV9CV11S202253312GAS,REFRIGERATEDLIQUID,FLAMMABLE,N.O.S.23F2.1274LQ0P203MP9T75RxBN(M)TU18FL2V5V7CV9CV11S2S172233313ORGANICPIGMENTS,SELF-HEATING4.2S2II4.2LQ0P002IBC08B2MP14SGAVAT2V1403313ORGANICPIGMENTS,SELF-HEATING4.2S2III4.2LQ0P002IBC08LP02R001B3MP14SGAVAT3V140OfficialJournaloftheEuropeanUnionEN26.1.2004L18/545UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)3314PLASTICSMOULDINGCOMPOUNDindough,sheetorextrudedropeformevolvingflammablevapour9M3III207633LQ27P002IBC08R001PP14B6MP103V1VV3903315CHEMICALSAMPLE,TOXIC,liquidorsolid6.1T8I6.1250LQ0P099MP8MP171CV1CV13CV28S9S173316CHEMICALKITorFIRSTAIDKIT9M11II9251LQ0P9012V13316CHEMICALKITorFIRSTAIDKIT9M11III9251LQ0P9013V133172-AMINO-4,6-DINITRO-PHENOL,WETTEDwithnotlessthan20%water,bymass4.1DI4.1LQ0P406PP26MP21S173318AMMONIASOLUTION,rela-tivedensitylessthan0,880at15°Cinwater,withmorethan50%ammonia24TC2.3+823LQ0P200MP9T50PxBH(M)TE1AT1CV9CV10S7268OfficialJournaloftheEuropeanUnionEN26.1.2004L18/546UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)3319NITROGLYCERINEMIXTURE,DESENSITISED,SOLID,N.O.S.withmorethan2%butnotmorethan10%nitroglycerine,bymass4.1DII4.1272274LQ0P099IBC99MP203320SODIUMBOROHYDRIDEANDSODIUMHYDROXIDESOLUTION,withnotmorethan12%sodiumborohy-drideandnotmorethan40%sodiumhydroxidebymass8C5II8LQ22P001IBC02MP15T7TP2L4BNAT2803320SODIUMBOROHYDRIDEANDSODIUMHYDROXIDESOLUTION,withnotmorethan12%sodiumborohy-drideandnotmorethan40%sodiumhydroxidebymass8C5III8LQ19P001IBC03LP01R001MP15T4TP2L4BNAT3803321RADIOACTIVEMATERIAL,LOWSPECIFICACTIVITY(LSA-II),nonfissileorfissile-excepted77X172LQ0See2.7and4.1.9See4.1.9.1.3T5TP4L2,65CN(+)S2,65AN(+)TU36TM7TT7AT0CV33S6S11S13S2170OfficialJournaloftheEuropeanUnionEN26.1.2004L18/547UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)3322RADIOACTIVEMATERIAL,LOWSPECIFICACTIVITY(LSA-III),nonfissileorfissile-excepted77X172LQ0See2.7and4.1.9See4.1.9.1.3T5TP4L2,65CN(+)S2,65AN(+)TU36TM7TT7AT0CV33S6S11S13S21703323RADIOACTIVEMATERIAL,TYPECPACKAGE,nonfissileorfissile-excepted77X172LQ0See2.7and4.1.9See4.1.9.1.30CV33S6S11S13S213324RADIOACTIVEMATERIAL,LOWSPECIFICACTIVITY(LSA-II),FISSILE77X+7E172LQ0See2.7and4.1.9See4.1.9.1.30CV33S6S11S13S213325RADIOACTIVEMATERIAL,LOWSPECIFICACTIVITY,(LSA-III),FISSILE77X+7E172LQ0See2.7and4.1.9See4.1.9.1.30CV33S6S11S12S13S213326RADIOACTIVEMATERIAL,SURFACECONTAMINATEDOBJECTS(SCO-IorSCO-II),FISSILE77X+7E172LQ0See2.7and4.1.9See4.1.9.1.30CV33S6S11S13S213327RADIOACTIVEMATERIAL,TYPEAPACKAGE,FISSILE,non-specialform77X+7E172LQ0See2.7and4.1.9See4.1.9.1.3CV33S6S11S13S21OfficialJournaloftheEuropeanUnionEN26.1.2004L18/548UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)3328RADIOACTIVEMATERIAL,TYPEB(U)PACKAGE,FISSILE77X+7E172LQ0See2.7and4.1.9See4.1.9.1.3S6S11S13S213329RADIOACTIVEMATERIAL,TYPEB(M)PACKAGE,FISSILE77X+7E172LQ0See2.7and4.1.9See4.1.9.1.3S6S11S13S213330RADIOACTIVEMATERIAL,TYPECPACKAGE,FISSILE77X+7E172LQ0See2.7and4.1.9See4.1.9.1.30CV33S6S11S13S213331RADIOACTIVEMATERIAL,TRANSPORTEDUNDERSPECIALARRANGEMENT,FISSILE77X+7E172LQ0See2.7and4.1.9See4.1.9.1.30CV33S6S11S13S213332RADIOACTIVEMATERIAL,TYPEAPACKAGE,SPECIALFORM,nonfissileorfissile-excepted77X172LQ0See2.7and4.1.9See4.1.9.1.30CV33S6S11S12S13S213333RADIOACTIVEMATERIAL,TYPEAPACKAGE,SPECIALFORM,FISSILE77X+7E172LQ0See2.7and4.1.9See4.1.9.1.30CV33S6S11S13S213334Aviationregulatedliquid,n.o.s.9M11NOTSUBJECTTOADROfficialJournaloftheEuropeanUnionEN26.1.2004L18/549UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)3335Aviationregulatedsolid,n.o.s.9M11NOTSUBJECTTOADR3336MERCAPTANS,LIQUID,FLAMMABLE,N.O.S.orMERCAPTANMIXTURE,LIQUID,FLAMMABLE,N.O.S.3F1I3274LQ3P001MP7MP17T11TP2L1,5BNFL1S2S20333336MERCAPTANS,LIQUID,FLAMMABLE,N.O.S.orMERCAPTANMIXTURE,LIQUID,FLAMMABLE,N.O.S.(vapourpressureat50°Cmorethan110kPabutnotmorethan175kPa)3F1II3274640LQ4P001MP19T7TP1TP8TP28L1,5BNFL2S2S20333336MERCAPTANS,LIQUID,FLAMMABLE,N.O.S.orMERCAPTANMIXTURE,LIQUID,FLAMMABLE,N.O.S.(vapourpressureat50°Cnotmorethan110kPa)3F1II3274640LQ4P001IBC02R001MP19T7TP1TP8TP28LGBFFL2S2S20333336MERCAPTANS,LIQUID,FLAMMABLE,N.O.S.orMERCAPTANMIXTURE,LIQUID,FLAMMABLE,N.O.S.3F1III3274LQ7P001IBC03LP01R001MP19T4TP1TP29LGBFFL3S230OfficialJournaloftheEuropeanUnionEN26.1.2004L18/550UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)3337REFRIGERANTGASR404A22A2.2LQ1P200MP9T50PxBN(M)AT3V7CV9CV10203338REFRIGERANTGASR407A(Difluoromethane,penta-fluoroethane,and1,1,1,2-tetrafluoroethanezeotropicmixturewithapproximately20%difluoromethaneand40%pentafluoroethane)22A2.2LQ1P200MP9T50PxBN(M)AT3V7CV9CV10203339REFRIGERANTGASR407B(Difluoromethane,penta-fluoroethane,and1,1,1,2-tetrafluoroethanezeotropicmixturewithapproximately10%difluoromethaneand70%pentafluoroethane22A2.2LQ1P200MP9T50PxBN(M)AT3V7CV9CV10203340REFRIGERANTGASR407C(Difluoromethane,penta-fluoroethane,and1,1,1,2-tetrafluoroethanezeotropicmixturewithapproximately23%difluoromethaneand25%pentafluoroethane)22A2.2LQ1P200MP9T50PxBN(M)AT3V7CV9CV1020OfficialJournaloftheEuropeanUnionEN26.1.2004L18/551UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)3341THIOUREADIOXIDE4.2S2II4.2LQ0P002IBC06B2MP14SGAVAT2V1403341THIOUREADIOXIDE4.2S2III4.2LQ0P002IBC08LP02R001B3MP14SGAVAT3V1403342XANTHATES4.2S2II4.2LQ0P002IBC06B2MP14SGAVAT2V1403342XANTHATES4.2S2III4.2LQ0P002IBC08LP02R001B3MP14SGAVAT3V1403343NITROGLYCERINEMIXTURE,DESENSITISED,LIQUID,FLAMMABLE,N.O.S.withnotmorethan30%nitroglycerine,bymass3D3274278LQ0P099MP20S23344PENTAERYTHRITETETRA-NITRATEMIXTURE,DESEN-SITISED,SOLID,N.O.S.withmorethan10%butnotmorethan20%PETN,bymass4.1DII4.1272274LQ0P099MP20OfficialJournaloftheEuropeanUnionEN26.1.2004L18/552UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)3345PHENOXYACETICACIDDERIVATIVEPESTICIDE,SOLID,TOXIC6.1T7I6.161LQ0P002IBC07B1MP18S10AHL10CHTU14TU15TE1TE19AT1CV1CV13CV28S9S17663345PHENOXYACETICACIDDERIVATIVEPESTICIDE,SOLID,TOXIC6.1T7II6.161LQ18P002IBC08B2B4MP10SGAHL4BHTU15TE1TE19AT2CV13CV28S9S19603345PHENOXYACETICACIDDERIVATIVEPESTICIDE,SOLID,TOXIC6.1T7III6.161LQ9P002IBC08LP02R001B3MP10SGAHL4BHTU15TE1TE19AT2VV9bCV13CV28S9603346PHENOXYACETICACIDDERIVATIVEPESTICIDE,LIQUID,FLAMMABLE,TOXIC3FT2I3+6.161LQ3P001MP7MP17T14TP2TP9TP13TP27L10CHTU14TU15TE1FL1CV13CV28S2S193363346PHENOXYACETICACIDDERIVATIVEPESTICIDE,LIQUID,FLAMMABLE,TOXIC3FT2II3+6.161LQ4P001IBC02R001MP19T11TP2TP13TP27L4BHTU15TE1FL2CV13CV28S2S19336OfficialJournaloftheEuropeanUnionEN26.1.2004L18/553UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)3347PHENOXYACETICACIDDERIVATIVEPESTICIDE,LIQUID,TOXIC,FLAM-MABLE6.1TF2I6.1+361LQ0P001MP8MP17T14TP2TP9TP13TP27L10CHTU14TU15TE1TE19FL1CV1CV13CV28S2S9S176633347PHENOXYACETICACIDDERIVATIVEPESTICIDE,LIQUID,TOXIC,FLAM-MABLE6.1TF2II6.1+361LQ17P001IBC02MP15T11TP2TP13TP27L4BHTU15TE1TE19FL2CV13CV28S2S9S19633347PHENOXYACETICACIDDERIVATIVEPESTICIDE,LIQUID,TOXIC,FLAM-MABLE6.1TF2III6.1+361LQ19P001IBC03R001MP15T7TP2TP28L4BHTU15TE1TE19FL2CV13CV28S2S9633348PHENOXYACETICACIDDERIVATIVEPESTICIDE,LIQUID,TOXIC6.1T6I6.161LQ0P001MP8MP17T14TP2TP9TP13TP27L10CHTU14TU15TE1TE19AT1CV1CV13CV28S9S17663348PHENOXYACETICACIDDERIVATIVEPESTICIDE,LIQUID,TOXIC6.1T6II6.161LQ17P001IBC02MP15T11TP2TP27L4BHTU15TE1TE19AT2CV13CV28S9S1960OfficialJournaloftheEuropeanUnionEN26.1.2004L18/554UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)3348PHENOXYACETICACIDDERIVATIVEPESTICIDE,LIQUID,TOXIC6.1T6III6.161LQ19P001IBC03LP01R001MP15T7TP2TP28L4BHTU15TE1TE19AT2CV13CV28S9603349PYRETHROIDPESTICIDE,SOLID,TOXIC6.1T7I6.161LQ0P002IBC07B1MP18S10AHL10CHTU14TU15TE1TE19AT1CV1CV13CV28S9S17663349PYRETHROIDPESTICIDE,SOLID,TOXIC6.1T7II6.161LQ18P002IBC08B2B4MP10SGAHL4BHTU15TE1TE19AT2CV13CV28S9S19603349PYRETHROIDPESTICIDE,SOLID,TOXIC6.1T7III6.161LQ9P002IBC08LP02R001B3MP10SGAHL4BHTU15TE1TE19AT2VV9bCV13CV28S9603350PYRETHROIDPESTICIDE,LIQUID,FLAMMABLE,TOXIC3FT2I3+6.161LQ3P001MP7MP17T14TP2TP9TP13TP27L10CHTU14TU15TE1FL1CV13CV28S2S193363350PYRETHROIDPESTICIDE,LIQUID,FLAMMABLE,TOXIC3FT2II3+6.161LQ4P001IBC02R001MP19T11TP2TP13TP27L4BHTU15TE1FL2CV13CV28S2S193363351PYRETHROIDPESTICIDE,LIQUID,TOXIC,FLAM-MABLE6.1TF2I6.1+361LQ0P001MP8MP17T14TP2TP9TP13TP27L10CHTU14TU15TE1TE19FL1CV1CV13CV28S2S9S17663OfficialJournaloftheEuropeanUnionEN26.1.2004L18/555UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)3351PYRETHROIDPESTICIDE,LIQUID,TOXIC,FLAM-MABLE6.1TF2II6.1+361LQ17P001IBC02MP15T11TP2TP13TP27L4BHTU15TE1TE19FL2CV13CV28S2S9S19633351PYRETHROIDPESTICIDE,LIQUID,TOXIC,FLAM-MABLE6.1TF2III6.1+361LQ19P001IBC03R001MP15T7TP2TP28L4BHTU15TE1TE19FL2CV13CV28S2S9633352PYRETHROIDPESTICIDE,LIQUID,TOXIC6.1T6I6.161LQ0P001MP8MP17T14TP2TP9TP13TP27L10CHTU14TU15TE1TE19AT1CV1CV13CV28S9S17663352PYRETHROIDPESTICIDE,LIQUID,TOXIC6.1T6II6.161LQ17P001IBC02MP15T11TP2TP27L4BHTU15TE1TE19AT2CV13CV28S9S19603352PYRETHROIDPESTICIDE,LIQUID,TOXIC6.1T6III6.161LQ19P001IBC03LP01R001MP15T7TP2TP28L4BHTU15TE1TE19AT2CV13CV28S9603353AIRBAGINFLATORS,COMPRESSEDGASorAIRBAGMODULES,COMPRESSEDGASorSEAT-BELTPRETEN-SIONERS,COMPRESSEDGAS26A2.2280289LQ0P202MP93CV9OfficialJournaloftheEuropeanUnionEN26.1.2004L18/556UNNoNameanddescription3.1.2Class2.2Classifica-tionCode2.2Packinggroup2.1.1.3Labels5.2.2Specialprovi-sions3.3Limitedquantities3.4.6PackagingUNPortabletankADRtankVehiclefortankcarriage9.1.1.2Transportcategory1.1.3.6SpecialprovisionsforcarriageHazardidentifica-tionNo5.3.2.3Packinginstruc-tions4.1.4Specialpackingprovi-sions4.1.4Mixedpackingprovi-sions4.1.10Instruc-tions4.2.4.2Specialprovi-sions4.2.4.3Tankcode4.3Specialprovi-sions4.3.5,6.8.4Packages7.2.4Bulk7.3.3Loading,unloadingandhandling7.5.11Operation8,5(1)(2)(3a)(3b)(4)(5)(6)(7)(8)(9a)(9b)(10)(11)(12)(13)(14)(15)(16)(17)(18)(19)(20)3354INSECTICIDEGAS,FLAM-MABLE,N.O.S.22F2.1274LQ0P200MP9PxBN(M)FL2V7CV9CV10S2S7S20233355INSECTICIDEGAS,TOXIC,FLAMMABLE,N.O.S.22TF2.3+2.1274LQ0P200MP9PxBH(M)TU6TE1FL1V7CV9CV10S2S7S172633356OXYGENGENERATOR,CHEMICAL5.1O3II5.1284LQ0P500MP22CV243357NITROGLYCERINEMIXTURE,DESENSITISED,LIQUID,N.O.S.withnotmorethan30%nitrogly-cerine,bymass3DII3274288LQ4P099MP22S23358REFRIGERATINGMACHINEScontainingflam-mable,non-toxic,liquefiedgas26F2.1291LQ0P003PP32MP92CV9S2OfficialJournaloftheEuropeanUnionEN26.1.2004L18/557CHAPTER3.3Specialprovisionsapplicabletocertainarticlesorsubstances3.3.1.Whencolumn6ofTableAofChapter3.2indicatesthataspecialprovisionisrelevanttoasubstanceorarticle,themeaningandrequirementsofthatspecialprovisionareassetoutbelow.15Forsmallquantitiesofnotmorethan500gperpackage,thissubstance,withnotlessthan10%water,bymass,mayalsobeclassifiedinClass4.1,subjecttopackinginstructionP406of4.1.4.1.16Samplesofneworexistingexplosivesubstancesorarticlesmaybecarriedasdirectedbythecompetentauthorities(see2.2.1.1.3)forpurposesincluding:testing,classification,researchanddevelopment,qualitycontrol,orasacommercialsample.Explosivesampleswhicharenotwettedordesensitisedshallbelimitedto10kginsmallpackagesasspecifiedbythecompetentauthorities.Explosivesampleswhicharewettedordesensitisedshallbelimitedto25kg.18Forquantitiesofnotmorethan11,5kgperpackage,thissubstance,withnotlessthan10%water,bymass,mayalsobeclassifiedinClass4.1,subjecttopackinginstructionP406of4.1.4.1.23Eventhoughthissubstancehasaflammabilityhazard,itonlyexhibitssuchhazardunderextremefireconditionsinconfinedareas.32ThissubstanceisnotsubjecttotherequirementsofthisDirectivewheninanyotherform.36ThissubstanceistobeclassifiedunderUNNo1373ifitcontainsmorethan5%animalorvegetableoil.37ThissubstanceisnotsubjecttotherequirementsofthisDirectivewhencoated.38ThissubstanceisnotsubjecttotherequirementsofthisDirectivewhenitcontainsnotmorethan0,1%calciumcarbide.39ThissubstanceisnotsubjecttotherequirementsofthisDirectivewhenitcontainslessthan30%ornotlessthan90%silicon.43Whenofferedforcarriageaspesticides,thesesubstancesshallbecarriedundertherelevantpesticideentryandinaccordancewiththerelevantpesticideprovisions(see2.2.61.1.10to2.2.61.1.11.2).45Antimonysulphidesandoxideswhichcontainnotmorethan0,5%ofarseniccalculatedonthetotalmassarenotsubjecttotherequirementsofthisDirective.47FerricyanidesandferrocyanidesarenotsubjecttotherequirementsofthisDirective.48Thecarriageofthissubstance,whenitcontainsmorethan20%hydrocyanicacid,isprohibited.59ThesesubstancesarenotsubjecttotherequirementsofthisDirectivewhentheycontainnotmorethan50%magnesium.60Iftheconcentrationismorethan72%,thecarriageofthissubstanceisprohibited.61ThetechnicalnamewhichshallsupplementthepropershippingnameshallbetheISOcommonname(seealsoISO1750:1981‘Pesticidesandotheragrochemicals—commonnames’,asamended),othernamelistedintheWHO‘Recommendedclassificationofpesticidesbyhazardandguidelinestoclassification’orthenameoftheactivesubstance(seealso3.1.2.6.1.1).62ThissubstanceisnotsubjecttotherequirementsofthisDirectivewhenitcontainsnotmorethan4%sodiumhydroxide.65Hydrogenperoxideaqueoussolutionswithlessthan8%hydrogenperoxidearenotsubjecttotherequirementsofthisDirective.103Thecarriageofammoniumnitritesandmixturesofaninorganicnitritewithanammoniumsaltisprohibited.105NitrocellulosemeetingthedescriptionsofUNNo2556orUNNo2557maybeclassifiedinClass4.1.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/558107TheconsignmentisnotsubjecttotherequirementsofthisDirectiveiftheconsignordeclaresthatithasnoself-heatingproperties.113Thecarriageofchemicallyunstablemixturesisprohibited.119Refrigeratingmachinesincludemachinesorotherapplianceswhichhavebeendesignedforthespecificpurposeofkeepingfoodorotheritemsatalowtemperatureinaninternalcompartment,andairconditioningunits.RefrigeratingmachinesarenotsubjecttotherequirementsofthisDirectiveifcontaininglessthan12kgofgasinClass2,groupAorOaccordingto2.2.2.1.3,orifcontaininglessthan12lammoniasolution(UNNo2672).122Thesubsidiaryrisks,controlandemergencytemperaturesifany,andtheUNnumber(genericentry)foreachofthecurrentlyassignedorganicperoxideformulationsaregivenin2.2.52.4.127Otherinertmaterialorinertmaterialmixturemaybeused,providedthisinertmaterialhasidenticalphlegmatisingproperties.131ThephlegmatisedsubstanceshallbesignificantlylesssensitivethandryPETN.135ThedihydratedsodiumsaltofdichloroisocyanuricacidisnotsubjecttotherequirementsofthisDirective.138p-BromobenzylcyanideisnotsubjecttotherequirementsofthisDirective.141ProductswhichhaveundergonesufficientheattreatmentsothattheypresentnohazardduringcarriagearenotsubjecttotherequirementsofthisDirective.142Solventextractedsoyabeanmealcontainingnotmorethan1,5%oiland11%moisture,whichissubstantiallyfreeofflammablesolvent,isnotsubjecttotherequirementsofthisDirective.144Anaqueoussolutioncontainingnotmorethan24%alcoholbyvolumeisnotsubjecttotherequirementsofthisDirective.145AlcoholicbeveragesofpackinggroupIII,whencarriedinreceptaclesof250litresorless,arenotsubjecttotherequirementsofthisDirective.152Theclassificationofthissubstancewillvarywithparticlesizeandpackaging,butborderlineshavenotbeenexperimentallydetermined.Appropriateclassificationsshallbemadeinaccordancewith2.2.1.153Thisentryappliesonlyifitisdemonstrated,onthebasisoftests,thatthesubstanceswhenincontactwithwaterarenotcombustiblenorshowatendencytoauto-ignitionandthatthemixtureofgasesevolvedisnotflammable.162Mixtureswithaflash-pointofnotmorethan61°CshallbearalabelconformingtomodelNo3.163AsubstancementionedbynameinTableAofChapter3.2shallnotbecarriedunderthisentry.Substancescarriedunderthisentrymaycontain20%orlessnitrocelluloseprovidedthenitrocellulosecontainsnotmorethan12,6%nitrogen(bydrymass).168Asbestoswhichisimmersedorfixedinanaturalorartificialbinder(suchascement,plastics,asphalt,resinsormineralore)insuchawaythatnoescapeofhazardousquantitiesofrespirableasbestosfibrescanoccurduringcarriageisnotsubjecttotherequirementsofthisDirective.ManufacturedarticlescontainingasbestosandnotmeetingthisprovisionareneverthelessnotsubjecttotherequirementsofthisDirectivewhenpackedsothatnoescapeofhazardousquantitiesofrespirableasbestosfibrescanoccurduringcarriage.169Phthalicanhydrideinthesolidstateandtetrahydrophthalicanhydrides,withnotmorethan0,05%maleicanhydride,arenotsubjecttotherequirementsofthisDirective.Phthalicanhydridemoltenatatemperatureaboveitsflash-point,withnotmorethan0,05%maleicanhydride,shallbeclassifiedunderUNNo3256.172Forradioactivematerialwithasubsidiaryrisk:(a)thepackagesshallbelabelledwithalabelcorrespondingtoeachsubsidiaryriskexhibitedbythematerial;correspondingplacardsshallbeaffixedtovehiclesorcontainersinaccordancewiththerelevantprovisionsof5.3.1;(b)theradioactivematerialshallbeallocatedtopackinggroupsI,IIorIII,asandifappropriate,byapplicationofthegroupingcriteriaprovidedinPart2correspondingtothenatureofthepredominantsubsidiaryrisk.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/559Thedescriptionrequiredin5.4.1.2.5.1(e)shallincludeadescriptionofthesesubsidiaryrisks(e.g.‘Subsidiaryrisk:3,6.1’),thenameoftheconstituentswhichmostpredominantlycontributetothis(these)subsidiaryrisk(s),andwhereapplicable,thepackinggroup.177BariumsulphateisnotsubjecttotherequirementsofthisDirective.178ThisdesignationshallbeusedonlywhennootherappropriatedesignationexistsinTableAofChapter3.2,andonlywiththeapprovalofthecompetentauthorityofthecountryoforigin(see2.2.1.1.3).181PackagescontainingthistypeofsubstanceshallbearalabelconformingtomodelNo1unlessthecompetentauthorityofthecountryoforiginhaspermittedthislabeltobedispensedwithforthespecificpackagingemployedbecausetestdatahaveprovedthatthesubstanceinthispackagingdoesnotexhibitexplosivebehaviour(see5.2.2.1.9).182Thegroupofalkalimetalsincludeslithium,sodium,potassium,rubidiumandcaesium.183Thegroupofalkalineearthmetalsincludesmagnesium,calcium,strontiumandbarium.186Indeterminingtheammoniumnitratecontent,allnitrateionsforwhichamolecularequivalentofammoniumionsispresentinthemixtureshallbecalculatedasammoniumnitrate.188LithiumcellsandbatteriesofferedforcarriagearenotsubjecttotherequirementsofthisDirectiveiftheymeetthefollowingprovisions:(a)foralithiummetalorlithiumalloycellwithaliquidcathode,thelithiumcontentisnotmorethan0,5g,foralithiummetalorlithiumalloycellwithasolidcathode,thelithiumcontentisnotmorethan1g,andforalithium-ioncell,theequivalentlithiumcontentisnotmorethan1,5g;(b)foralithiummetalorlithiumalloybatterywithliquidcathodes,theaggregatelithiumcontentisnotmorethan1g,foralithiummetalorlithiumalloybatterywithsolidcathodes,theaggregatelithiumcontentisnotmorethan2g,andforalithium-ionbattery,theaggregateequivalentlithiumcontentisnotmorethan8g;(c)eachcellorbatterycontainingaliquidcathodeishermeticallysealed;(d)cellsareseparatedsoastopreventshortcircuits;(e)batteriesareseparatedsoastopreventshortcircuitsandarepackedinstrongpackagings,exceptwheninstalledinelectronicdevices;and(f)if,whenfullycharged,theaggregatelithiumcontentoftheanodesinaliquidcathodebatteryismorethan0,5g,oroftheaggregatelithiumcontentoftheanodesinasolidcathodebatteryismorethan1g,itdoesnotcontainaliquidorgaswhichisconsidereddangerousunlesstheliquidorgas,iffree,wouldbecompletelyabsorbedorneutralisedbyothermaterialsinthebattery.LithiumcellsandlithiumbatteriesarealsonotsubjecttotherequirementsofthisDirectiveiftheymeetthefollowingprovisions:(g)thelithiumcontentoftheanodeofeachcell,whenfullycharged,isnotmorethan5g;(h)theaggregatelithiumcontentoftheanodesofeachbattery,whenfullycharged,isnotmorethan25g;(i)eachcellorbatteryisofthetypeprovedtobenon-dangerousbytestinginaccordancewithtestsintheManualoftestsandcriteria,PartIII,subsection38.3;suchtestingshallbecarriedoutoneachtypepriortotheinitialcarriageofthattype;and(j)cellsandbatteriesaredesignedorpackedinsuchawayastopreventshortcircuitsunderconditionsnormallyencounteredduringcarriage.AsusedaboveandelsewhereinthisDirective,‘lithiumcontent’meansthemassoflithiumintheanodeofalithiummetalorlithiumalloycell,exceptinthecaseofalithium-ioncellthe‘equivalentlithiumcontent’ingramsiscalculatedtobe0,3timestheratedcapacityinampere-hours.190Aerosoldispensersshallbeprovidedwithprotectionagainstinadvertentdischarge.Aerosolswithacapacitynotexceeding50mlcontainingonlynon-toxicconstituentsarenotsubjecttotherequirementsofthisDirective.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/560191Receptacles,small,withacapacitynotexceeding50ml,containingonlynon-toxicconstituentsarenotsubjecttotherequirementsofthisDirective.193AmmoniumnitratefertilisersofthiscompositionandwithintheselimitsarenotsubjecttotherequirementsofthisDirectiveifshownbyatroughtest(seeManualoftestsandcriteria,PartIII,subsection38.2)nottobeliabletoself-sustainingdecompositionandprovidedthattheydonotcontainanexcessofnitrategreaterthan10%bymass(calculatedaspotassiumnitrate).194Thecontrolandemergencytemperatures,ifany,andtheUNnumber(genericentry)foreachofthecurrentlyassignedself-reactivesubstancesaregivenin2.2.41.4.196Thisformulationshallfulfilthecriteriagiveninparagraph20.4.2(g)ofPartIIoftheManualoftestsandcriteria,exceptthatadiluentoftypeAisnotrequiredfordesensitisation.FormulationsnotmeetingthesecriteriashallbecarriedundertheprovisionsofClass5.2,(see2.2.52.4).198Nitrocellulosesolutionscontainingnotmorethan20%nitrocellulosemaybecarriedaspaintorprintingink,asapplicable(seeUNNos1210,1263and3066).199Leadcompoundswhich,whenmixedinaratioof1:1000with0,07Mhydrochloricacidandstirredforonehouratatemperatureof23°C±2°C,exhibitasolubilityof5%orlessareconsideredinsoluble.SeeISO3711:1990‘Leadchromatepigmentsandleadchromate—molybdatepigments—Specificationsandmethodsoftest’.203Thisentryshallnotbeusedforpolychlorinatedbiphenyls,UNNo2315.204Articlescontainingsmoke-producingsubstance(s)corrosiveaccordingtothecriteriaforclass8shallbelabelledwithalabelconformingtomodelNo8.205ThisentryshallnotbeusedforUNNo3155PENTACHLOROPHENOL.207Polymericbeadsandmouldingcompoundsmaybemadefrompolystyrene,poly(methylmethacrylate)orotherpolymericmaterial.208Thecommercialgradeofcalciumnitratefertiliser,whenconsistingmainlyofadoublesalt(calciumnitrateandammoniumnitrate)containingnotmorethan10%ammoniumnitrateandatleast12%waterofcrystallisation,isnotsubjecttotherequirementsofthisDirective.210Toxinsfromplant,animalorbacterialsourceswhichcontaininfectioussubstances,ortoxinsthatarecontainedininfectioussubstances,shallbeclassifiedinClass6.2.215ThisentryonlyappliestothetechnicallypuresubstanceortoformulationsderivedfromithavinganSADThigherthan75°Candthereforedoesnotapplytoformulationswhichareself-reactivesubstances(forself-reactivesubstances,see2.2.41.4).216MixturesofsolidswhicharenotsubjecttotherequirementsofthisDirectiveandflammableliquidsmaybecarriedunderthisentrywithoutfirstapplyingtheclassificationcriteriaofClass4.1,providedthereisnofreeliquidvisibleatthetimethesubstanceisloadedoratthetimethepackaging,vehicleorcontainerisclosed.217MixturesofsolidswhicharenotsubjecttotherequirementsofthisDirectiveandtoxicliquidsmaybecarriedunderthisentrywithoutfirstapplyingtheclassificationcriteriaofClass6.1,providedthereisnofreeliquidvisibleatthetimethesubstanceisloadedoratthetimethepackaging,vehicleorcontainerisclosed.ThisentryshallnotbeusedforsolidscontainingapackinggroupIliquid.218MixturesofsolidswhicharenotsubjecttotherequirementsofthisDirectiveandcorrosiveliquidsmaybecarriedunderthisentrywithoutfirstapplyingtheclassificationcriteriaofclass8,providedthereisnofreeliquidvisibleatthetimethesubstanceisloadedoratthetimethepackaging,vehicleorcontainerisclosed.219Geneticallymodifiedmicro-organismswhichareinfectiousshallbecarriedasUNNos2814or2900.220Onlythetechnicalnameoftheflammableliquidcomponentofthissolutionormixtureshallbeshowninparenthesesimmediatelyfollowingthepropershippingname.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/561221SubstancesincludedunderthisentryshallnotbeofpackinggroupI.222Wheretheterm‘water-reactive’isusedtodescribeasubstanceinthisDirective,itmeansasubstancewhichincontactwithwateremitsflammablegas.224Unlessitcanbedemonstratedbytestingthatthesensitivityofthesubstanceinitsfrozenstateisnogreaterthaninitsliquidstate,thesubstanceshallremainliquidduringnormaltransportconditions.Itshallnotfreezeattemperaturesabove-15°C.225Fireextinguishersunderthisentrymayincludeinstalledactuatingcartridges(cartridges,powerdeviceofclassificationcode1.4Cor1.4S),withoutchangingtheclassificationofclass2,groupAorOaccordingto2.2.2.1.3providedthetotalquantityofdeflagrating(propellant)explosivesdoesnotexceed3,2gperextinguishingunit.226Formulationsofthissubstancecontainingnotlessthan30%non-volatile,non-flammablephlegmatiserarenotsubjecttotherequirementsofthisDirective.227ThissubstancemaybecarriedunderprovisionsotherthanthoseofClass1onlyifitissopackedthatthepercentageofwaterwillnotfallbelowthatstatedatanytimeduringcarriage.Whenphlegmatisedwithwaterandinorganicinertmaterialthecontentofureanitratemaynotexceed75%bymassandthemixtureshallnotbecapableofbeingdetonatedbytheSeries1,type(a),testintheManualoftestsandcriteria,Part1.228Mixturesnotmeetingthecriteriaforflammablegases(see2.2.2.1.5)shallbecarriedunderUNNo3163.230Thisentryappliestocellsandbatteriescontaininglithiuminanyform,includinglithiumpolymerandlithiumioncellsandbatteries.Lithiumcellsandbatteriesmaybecarriedunderthisentryiftheymeetthefollowingprovisions:(a)eachcellorbatterytypehasbeendeterminedtomeetthecriteriaforassignmenttoClass9onthebasisoftestscarriedoutinaccordancewiththeManualoftestsandcriteria,PartIII,subsection38.3;(b)eachcellandbatteryincorporatesasafetyventingdeviceorisdesignedtoprecludeaviolentruptureundernormalconditionsofcarriage;(c)eachcellandbatteryisequippedwithaneffectivemeansofpreventingexternalshortcircuits;(d)eachbatterycontainingcellsorseriesofcellsconnectedinparallelisequippedwitheffectivemeansasnecessarytopreventdangerousreversecurrentflow(e.g.diodes,fuses,etc.).235ThisentryappliestoarticleswhichmaybeclassifiedinClass1inaccordancewith2.2.1.1whichareusedaslife-savingvehicleairbagsorseat-belts,whencarriedascomponentpartsandwhenthesearticlesaspresentedforcarriagehavebeentestedinaccordancewithtestseries6(c)ofSection16ofPartIoftheManualoftestsandcriteria,withnoexplosionofthedevice,nofragmentationofdevicecasings,andnoprojectionhazardorthermaleffectwhichwouldsignificantlyhinderfire-fightingorotheremergencyresponseeffortsintheimmediatevicinity.Iftheairbaginflatorunitsatisfactorilypassestheseries6(c)test,itisnotnecessarytorepeatthetestontheairbagmoduleitself.236Polyesterresinkitsconsistoftwocomponents:abasematerial(Class3,packinggroupIIorIII)andanactivator(organicperoxide).TheorganicperoxideshallbetypeD,EorF,notrequiringtemperaturecontrol.PackinggroupshallbeIIorIII,accordingtothecriteriaforClass3,appliedtothebasematerial.Thequantitylimitreferredtoincolumn7ofTableAofChapter3.2appliestothebasematerial.237Themembranefilters,includingpaperseparators,coatingorbackingmaterials,etc.,thatarepresentincarriage,shallnotbeliabletopropagateadetonationastestedbyoneofthetestsdescribedintheManualoftestsandcriteria,PartI,testseries1(a).Inadditionthecompetentauthoritymaydetermine,onthebasisoftheresultsofsuitableburningrateteststakingaccountofthestandardtestsintheManualoftestsandcriteria,PartIII,subsection33.2.1,thatnitrocellulosemembranefiltersintheforminwhichtheyaretobecarriedarenotsubjecttotherequirementsapplicabletoflammablesolidsinclass4.1.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/562238(a)Batteriescanbeconsideredasnon-spillableprovidedthattheyarecapableofwithstandingthevibrationandpressuredifferentialtestsgivenbelow,withoutleakageofbatteryfluid.Vibrationtest:thebatteryisrigidlyclampedtotheplatformofavibrationmachineandasimpleharmonicmotionhavinganamplitudeof0,8mm(1,6mmmaximumtotalexcursion)isapplied.Thefrequencyisvariedattherateof1Hz/minbetweenthelimitsof10Hzand55Hz.Theentirerangeoffrequenciesandreturnistraversedin95±5minutesforeachmountingposition(directionofvibration)ofthebattery.Thebatteryistestedinthreemutuallyperpendicularpositions(toincludetestingwithfillopeningsandvents,ifany,inaninvertedposition)forequaltimeperiods.Pressuredifferentialtest:followingthevibrationtest,thebatteryisstoredforsixhoursat24°C±4°Cwhilesubjectedtoapressuredifferentialofatleast88kPa.Thebatteryistestedinthreemutuallyperpendicularpositions(toincludetestingwithfillopeningsandvents,ifany,inaninvertedposition)foratleastsixhoursineachposition.(b)Non-spillablebatteriesarenotsubjecttotherequirementsofthisDirectiveif,atatemperatureof55°C,theelectrolytewillnotflowfromarupturedorcrackedcaseandthereisnofreeliquidtoflowandif,aspackagedforcarriage,theterminalsareprotectedfromshortcircuit.239Batteriesorcellsshallnotcontaindangeroussubstancesotherthansodium,sulphurand/orpolysulphides.Batteriesorcellsshallnotbeofferedforcarriageatatemperaturesuchthatliquidelementalsodiumispresentinthebatteryorcellunlessapprovedandundertheconditionsestablishedbythecompetentauthorityofthecountryoforigin.IfthecountryoforiginisnotpartytothisDirective,theapprovalandconditionsofcarriageshallberecognizedbythecompetentauthorityofthefirstcountrypartytothisDirectivereachedbytheconsignment.Cellsshallconsistofhermeticallysealedmetalcasingswhichfullyenclosethedangeroussubstancesandwhicharesoconstructedandclosedastopreventthereleaseofthedangeroussubstancesundernormalconditionsofcarriage.Batteriesshallconsistofcellssecuredwithinandfullyenclosedbyametalcasingsoconstructedandclosedastopreventthereleaseofthedangeroussubstancesundernormalconditionsofcarriage.241Theformulationshallbepreparedsothatitremainshomogeneousanddoesnotseparateduringcarriage.Formulationswithlownitrocellulosecontentsandnotshowingdangerouspropertieswhentestedfortheirliabilitytodetonate,deflagrateorexplodewhenheatedunderdefinedconfinementbytestsoftestseries1(a),2(b)and2(c)respectivelyintheManualoftestsandcriteria,PartIandnotbeingaflammablesolidwhentestedinaccordancewithtestNo1intheManualoftestsandcriteria,PartIII,subsection33.2.1.4(chips,ifnecessary,crushedandsievedtoaparticlesizeoflessthan1,25mm)arenotsubjecttotherequirementsofthisDirective.244Thisentryincludese.g.aluminiumdross,aluminiumskimmings,spentcathodes,spentpotliner,andaluminiumsaltslags.247Alcoholicbeveragescontainingmorethan24%alcoholbutnotmorethan70%byvolume,whencarriedaspartofthemanufacturingprocess,maybecarriedinwoodencaskswithacapacityofnotmorethan500litresdeviatingfromtherequirementsofChapter6.1,onthefollowingconditions:(a)thecasksshallbecheckedandtightenedbeforefilling;(b)sufficientullage(notlessthan3%)shallbelefttoallowfortheexpansionoftheliquid;(c)thecasksshallbecarriedwiththebungholespointingupwards;(d)thecasksshallbecarriedincontainersmeetingtherequirementsoftheCSC.Eachcaskshallbesecuredincustom-madecradlesandbewedgedbyappropriatemeanstopreventitfrombeingdisplacedinanywayduringcarriage.249Ferrocerium,stabilisedagainstcorrosion,withaminimumironcontentof10%isnotsubjecttotherequirementsofthisDirective.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/563250ThisentrymayonlybeusedforsamplesofchemicalstakenforanalysisinconnectionwiththeimplementationoftheConventionontheProhibitionoftheDevelopment,Production,StockpilingandUseofChemicalWeaponsandontheirDestruction.ThecarriageofsubstancesunderthisentryshallbeinaccordancewiththechainofcustodyandsecurityproceduresspecifiedbytheOrganisationfortheProhibitionofChemicalWeapons.ThechemicalsamplemayonlybecarriedprovidingpriorapprovalhasbeengrantedbythecompetentauthorityortheDirectorGeneraloftheOrganisationfortheProhibitionofChemicalWeaponsandprovidingthesamplecomplieswiththefollowingprovisions:(a)itshallbepackedaccordingtopackinginstruction623intheICAOtechnicalinstructions(seeS-3-8ofthesupplement);and(b)duringcarriage,acopyofthedocumentofapprovalfortransport,showingthequantitylimitationsandthepackingprovisionsshallbeattachedtothetransportdocument.251TheentryCHEMICALKITorFIRSTAIDKITisintendedtoapplytoboxes,casesetc.containingsmallquantitiesofvariousdangerousgoodswhichareusedformedical,analyticalortestingpurposes.Suchkitsmaynotcontaindangerousgoodsforwhichthecode‘LQ0’hasbeenindicatedincolumn7ofTableAofChapter3.2.Componentsshallnotreactdangerously(see‘dangerousreaction’in1.2.1).Thetotalquantityofdangerousgoodsinanyonekitshallnotexceedeither1lor1kg.Thepackinggroupassignedtothekitasawholeshallbethemoststringentpackinggroupassignedtoanyindividualsubstanceinthekit.Kitswhicharecarriedonboardvehiclesforfirst-aidoroperatingpurposesarenotsubjecttotherequirementsofthisDirective.252Providedtheammoniumnitrateremainsinsolutionunderallconditionsofcarriage,aqueoussolutionsofammoniumnitrate,withnotmorethan0,2%combustiblematerial,inaconcentrationnotexceeding80%,arenotsubjecttotherequirementsofthisDirective.266Thissubstance,whencontaininglessalcohol,waterorphlegmatiserthanspecified,shallnotbecarriedunlessspecificallyauthorisedbythecompetentauthority(see2.2.1.1).267Anyexplosives,blasting,typeCcontainingchloratesshallbesegregatedfromexplosivescontainingammoniumnitrateorotherammoniumsalts.268Theword‘AGENT’maybeusedinsteadof‘EXPLOSIVE’whenapprovedbythecompetentauthority(see2.2.1.1).270AqueoussolutionsofClass5.1inorganicsolidnitratesubstancesareconsideredasnotmeetingthecriteriaofClass5.1iftheconcentrationofthesubstancesinsolutionattheminimumtemperatureencounteredduringcarriageisnotgreaterthan80%ofthesaturationlimit.271Lactoseorglucoseorsimilarmaterials,maybeusedasaphlegmatiserprovidedthatthesubstancecontainsnotlessthan90%,bymass,ofphlegmatiser.ThecompetentauthoritymayauthorisethesemixturestobeclassifiedinClass4.1onthebasisofatestseries6(c)ofSection16ofPartIoftheManualoftestsandcriteriaonatleastthreepackagesaspreparedforcarriage.Mixturescontainingatleast98%,bymass,ofphlegmatiserarenotsubjecttotherequirementsofthisDirective.Packagescontainingmixtureswithnotlessthan90%,bymass,ofphlegmatiserneednotbearalabelconformingtomodelNo6.1.272ThissubstanceshallnotbecarriedundertheprovisionsofClass4.1unlessspecificallyauthorisedbythecompetentauthority(seeUNNo0143).273Manebandmanebpreparationsstabilisedagainstself-heatingneednotbeclassifiedinClass4.2whenitcanbedemonstratedbytestingthatacubicvolumeof1m3ofsubstancedoesnotself-igniteandthatthetemperatureatthecentreofthesampledoesnotexceed200°C,whenthesampleismaintainedatatemperatureofnotlessthan75°C±2°Cforaperiodof24hours.274Theprovisionsof3.1.2.6.1apply.278ThesesubstancesshallnotbeclassifiedandcarriedunlessauthorisedbythecompetentauthorityonthebasisofresultsfromSeries2testsandaSeries6(c)testofPartIoftheManualoftestsandcriteriaonpackagesaspreparedforcarriage(see2.2.1.1).Thecompetentauthorityshallassignthepackinggrouponthebasisof2.2.3criteriaandthepackagetypeusedfortheSeries6(c)test.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/564279ThesubstanceisassignedtothisclassificationorpackinggroupbasedonhumanexperienceratherthanthestrictapplicationofclassificationcriteriasetoutinthisDirective.280Thisentryappliestoarticleswhichareusedaslifesavingvehicleairbaginflatorsorairbagmodulesorseat-beltpretensioners,containingagasoramixtureofcompressedgasesclassifiedunderClass2,groupAorOaccordingto2.2.2.1.3,andwithorwithoutsmallquantitiesofpyrotechnicmaterial.Forunitswithpyrotechnicmaterial,initiatedexplosiveeffectsshallbecontainedwithinthepressurevesselsuchthattheunitmaybeexcludedfromClass1inaccordancewiththenoteunder2.2.1.1.1(b),inconjunctionwith16.6.1.4.7(a)(ii)oftheManualoftestsandcriteria,PartI.Inaddition,unitsshallbedesignedorpackagedforcarriagesothatwhenengulfedinafiretherewillbenofragmentationofthepressurevesselorprojectionhazard.Thisshallbedeterminedbyanalysis.282Suspensionswithaflash-pointofnotmorethan61°C,shallbearalabelconformingtomodelNo3.283Articles,containinggas,intendedtofunctionasshockabsorbers,includingimpactenergy-absorbingdevices,orpneumaticspringsarenotsubjecttotherequirementsofthisDirectiveprovided:(a)eacharticlehasagasspacecapacitynotexceeding1,6litresandachargepressurenotexceeding280barwheretheproductofthecapacity(litres)andchargepressure(bars)doesnotexceed80(i.e.0,5litresgasspaceand160barchargepressure,1litregasspaceand80barchargepressure,1,6litresgasspaceand50barchargepressure,0,28litresgasspaceand280barchargepressure);(b)eacharticlehasaminimumburstpressureoffourtimesthechargepressureat20°Cforproductsnotexceeding0,5litresgasspacecapacityandfivetimeschargepressureforproductsgreaterthan0,5litresgasspacecapacity;(c)eacharticleismanufacturedfrommaterialwhichwillnotfragmentuponrupture;(d)eacharticleismanufacturedinaccordancewithaqualityassurancestandardacceptabletothecompetentauthority;and(e)thedesigntypehasbeensubjectedtoafiretestdemonstratingthatthearticlerelievesitspressurebymeansofafiredegradablesealorotherpressurereliefdevice,suchthatthearticlewillnotfragmentandthatthearticledoesnotrocket.Seealso1.1.3.2(d)forequipmentusedfortheoperationofthevehicle.284Anoxygengenerator,chemical,containingoxidisingsubstancesshallmeetthefollowingconditions:(a)thegeneratorwhencontaininganexplosiveactuatingdeviceshallonlybecarriedunderthisentrywhenexcludedfromclass1inaccordancewiththenoteunderparagraph2.2.1.1.1(b);(b)thegenerator,withoutitspackaging,shallbecapableofwithstandinga1,8mdroptestontoarigid,non-resilient,flatandhorizontalsurface,inthepositionmostlikelytocausedamage,withoutlossofitscontentsandwithoutactuation;(c)whenageneratorisequippedwithanactuatingdevice,itshallhaveatleasttwopositivemeansofpreventingunintentionalactuation.286Nitrocellulosemembranefilterscoveredbythisentry,eachwithamassnotexceeding0,5g,arenotsubjecttotherequirementsofthisDirectivewhencontainedindividuallyinanarticleorasealedpacket.287New,uncycledandunchargedlithiumioncellsandbatteriesarenotsubjecttotherequirementsofthisDirective:(a)iftheelectrolytedoesnotmeetthedefinitionofanyclassinthisDirective;or(b)iftheelectrolytemeetsthedefinitionofaclassinthisDirective,itwillnotflowfromarupturedorcrackedcaseandthereisnofreeliquidtoflow.288ThesesubstancesshallnotbeclassifiedandcarriedunlessauthorisedbythecompetentauthorityonthebasisofresultsfromSeries2testsandaseries6(c)testofPartIoftheManualoftestsandCriteriaonpackagesaspreparedforcarriage(see2.2.1.1).OfficialJournaloftheEuropeanUnionEN26.1.2004L18/565289Airbagsorseat-beltsinstalledinvehiclesorincompletedvehiclecomponentssuchassteeringcolumns,doorpanels,seats,etc.arenotsubjecttotherequirementsofthisDirective.290WhenthismaterialmeetsthedefinitionsandcriteriaofotherclassesasdefinedinPart2,itshallbeclassifiedinaccordancewiththepredominantsubsidiaryrisk.SuchmaterialshallbedeclaredunderthepropershippingnameandUNnumberappropriateforthematerialinthatpredominantClass,withtheadditionofthenameapplicabletothismaterialaccordingtocolumn2ofTableAofChapter3.2,andshallbecarriedinaccordancewiththeprovisionsapplicabletothatUNnumber.Inaddition,allotherrequirementsspecifiedin2.2.7.9.1shallapply,except5.2.1.7.2and5.4.1.2.5.1(a).291Flammableliquefiedgasesshallbecontainedwithinrefrigeratingmachinecomponents.Thesecomponentsshallbedesignedandtestedtoatleastthreetimestheworkingpressureofthemachinery.Therefrigeratingmachinesshallbedesignedandconstructedtocontaintheliquefiedgasandprecludetheriskofburstingorcrackingofthepressureretainingcomponentsduringnormalconditionsofcarriage.RefrigeratingmachinesarenotsubjecttotherequirementsofthisDirectiveifcontaininglessthan12kgofgas.292Onlymixtureswithnotmorethan23,5%oxygenmaybecarriedunderthisentry.AlabelconformingtomodelNo5.1isnotrequiredforanyconcentrationswithinthislimit.293Thefollowingdefinitionsapplytomatches:(a)fuseematchesarematchestheheadsofwhicharepreparedwithafriction-sensitiveignitercompositionandapyrotechniccompositionwhichburnswithlittleornoflame,butwithintenseheat;(b)safetymatchesarematcheswhicharecombinedwithorattachedtothebox,bookorcardthatcanbeignitedbyfrictiononlyonapreparedsurface;(c)strikeanywherematchesarematchesthatcanbeignitedbyfrictiononasolidsurface;(d)waxvestamatchesarematchesthatcanbeignitedbyfrictioneitheronapreparedsurfaceoronasolidsurface.295Batteriesneednotbeindividuallymarkedandlabelledifthepalletbearstheappropriatemarkandlabel.296Thesearticlesmaycontain:(a)Class2compressedgasesgroupAorO,accordingto2.2.2.1.3;(b)signaldevices(Class1)whichmayincludesmokeandilluminationsignalflares;(c)electricstoragebatteries;(d)firstaidkits;(e)strikeanywherematches.297-499(Reserved)500UNNo3064nitroglycerine,solutioninalcoholwithmorethan1%butnotmorethan5%nitroglycerine,packedinaccordancewithpackinginstructionP300of4.1.4.1,isasubstanceofClass3.501Fornaphthalene,molten,seeUNNo2304.502UNNo2006plastics,nitrocellulose-based,self-heating,n.o.s.,and2002celluloidscraparesubstancesofclass4.2.503Forphosphorus,whiteoryellow,molten,seeUNNo2447.504UNNo1847potassiumsulphide,hydratedwithnotlessthan30%waterofcrystallisation,UNNo1849sodiumsulphide,hydratedwithnotlessthan30%waterofcrystallisationandUNNo2949sodiumhydrosulphidewithnotlessthan25%waterofcrystallisationaresubstancesofClass8.505UNNo2004magnesiumdiamideisasubstanceofClass4.2.506AlkalineearthmetalsandalkalineearthmetalalloysinpyrophoricformaresubstancesofClass4.2.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/566UNNo1869magnesiumormagnesiumalloyscontainingmorethan50%magnesiumaspellets,turningsorribbons,aresubstancesofClass4.1.507UNNo3048aluminiumphosphidepesticides,withadditivesinhibitingtheemissionoftoxicflammablegasesaresubstancesofClass6.1.508UNNo1871titaniumhydrideandUNNo1437zirconiumhydridearesubstancesofClass4.1.UNNo2870aluminiumborohydrideisasubstanceofClass4.2.509UNNo1908chloritesolutionisasubstanceofClass8.510UNNo1755chromicacidsolutionisasubstanceofClass8.511UNNo1625mercuricnitrate,UNNo1627mercurousnitrateandUNNo2727thalliumnitratearesubstancesofClass6.1.Thoriumnitrate,solid,uranylnitratehexahydratesolutionanduranylnitrate,solidaresubstancesofClass7.512UNNo1730antimonypentachloride,liquid,UNNo1731antimonypentachloridesolution,UNNo1732antimonypentafluorideandUNNo1733antimonytrichloridearesubstancesofClass8.513UNNo1571bariumazide,wetted,isasubstanceofClass4.1.UNNo1445bariumchlorate,UNNo1446bariumnitrate,UNNo1447bariumperchlorate,UNNo1448bariumpermanganateandUNNo1449bariumperoxidearesubstancesofClass5.1.514UNNo2464berylliumnitrateisasubstanceofClass5.1.515UNNo1581chloropicrinandmethylbromidemixtureandUNNo1582chloropicrinandmethylchloridemixturearesubstancesofClass2.516UNNo1912methylchlorideandmethylenechloridemixtureisasubstanceofClass2.517UNNo1690sodiumfluoride,UNNo1812potassiumfluoride,UNNo2505ammoniumfluoride,UNNo2674sodiumfluorosilicateandUNNo2856fluorosilicates,n.o.s.aresubstancesofClass6.1.518UNNo1463chromiumtrioxide,anhydrous(chromicacid,solid)isasubstanceofClass5.1.519UNNo1048hydrogenbromide,anhydrous,isasubstanceofClass2.520UNNo1050hydrogenchloride,anhydrous,isasubstanceofClass2.521SolidchloritesandhypochloritesaresubstancesofClass5.1.522UNNo1873perchloricacidaqueoussolutionwithmorethan50%butnotmorethan72%pureacid,bymassaresubstancesofClass5.1.Perchloricacidsolutionscontainingmorethan72%pureacid,bymass,ormixturesofperchloricacidwithanyliquidotherthanwater,arenottobeacceptedforcarriage.523UNNo1382anhydrouspotassiumsulphideandUNNo1385anhydroussodiumsulphideandtheirhydrateswithlessthan30%waterofcrystallisation,andUNNo2318sodiumhydrosulphidewithlessthan25%waterofcrystallisationaresubstancesofClass4.2.524UNNo2858finishedzirconiumproductsofathicknessof18:mormorearesubstancesofClass4.1.525Solutionsofinorganiccyanideswithatotalcyanideioncontentofmorethan30%shallbeclassifiedinpackinggroupI,solutionswithatotalcyanideioncontentofmorethan3%andnotmorethan30%inpackinggroupIIandsolutionswithacyanideioncontentofmorethan0,3%andnotmorethan3%inpackinggroupIII.526UNNo2000celluloidisassignedtoClass4.1.527Organometalliccompoundsandtheirsolutions,notspontaneouslyflammable,butwhich,incontactwithwater,emitflammablegases,aresubstancesofClass4.3,UNNo3207.Flammablesolutionscontainingorganometalliccompoundswhicharenotspontaneouslyflammableandwhich,incontactwithwater,donotemitflammablegases,aresubstancesofClass3.528UNNo1353fibresorfabricsimpregnatedwithweaklynitratedcellulose,non-selfheatingarearticlesofClass4.1.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/567529UNNo0135mercuryfulminate,wettedwithnotlessthan20%water,ormixtureofalcoholandwater,bymass,isasubstanceofClass1.Mercurouschloride(calomel)isasubstanceofClass9(UNNo3077).530UNNo3293hydrazine,aqueoussolutionwithnotmorethan37%hydrazine,bymass,isasubstanceofClass6.1.531Mixtureshavingaflash-pointbelow23°Candcontainingmorethan55%nitrocellulose,whateveritsnitrogencontentorcontainingnotmorethan55%nitrocellulosewithanitrogencontentabove12,6%(bydrymass),aresubstancesofClass1(seeUNNos0340or0342)orofClass4.1.532UNNo2672ammoniasolutioncontainingnotlessthan10%butnotmorethan35%ammoniaisasubstanceofClass8.533UNNo1198formaldehydesolutions,flammablearesubstancesofClass3.Formaldehydesolutions,non-flammable,withlessthan25%formaldehydearenotsubjecttotherequirementsofthisDirective.534Whileinsomeclimaticconditions,petrol(gasoline)mayhaveavapourpressureat50°Cofmorethan110kPa(1,10bar)butnotmorethan150kPa(1,50bar)itistocontinuetobeconsideredasasubstancehavingavapourpressureat50°Cofnotmorethan110kPa(1,10bar).535UNNo1469leadnitrateandUNNo1470leadperchloratearesubstancesofClass5.1.536Fornaphthalene,solid,seeUNNo1334.537UNNo2869titaniumtrichloridemixture,notpyrophoric,isasubstanceofClass8.538Forsulphur(inthesolidstate),seeUNNo1350.539Solutionsofisocyanateshavingaflash-pointofnotlessthan23°CaresubstancesofClass6.1.540UNNo1326hafniumpowder,wetted,UNNo1352titaniumpowder,wettedorUNNo1358zirconiumpowder,wetted,withnotlessthan25%water,aresubstancesofClass4.1.541Nitrocellulosemixtureswithawatercontent,alcoholcontentorplasticisercontentlowerthanthestatedlimitsaresubstancesofClass1.542Talccontainingtremoliteand/oractinoliteiscoveredbythisentry.543UNNo1005ammonia,anhydrous,UNNo3318ammoniasolutionwithmorethan50%ammoniaandUNNo2073ammoniasolution,withmorethan35%butnotmorethan50%ammonia,aresubstancesofClass2.Ammoniasolutionswithnotmorethan10%ammoniaarenotsubjecttotherequirementsofthisDirective.544UNNo1032dimethylamine,anhydrous,UNNo1036ethylamine,UNNo1061methylamine,anhydrousandUNNo1083trimethylamine,anhydrous,aresubstancesofClass2.545UNNo0401dipicrylsulphide,wettedwithlessthan10%waterbymassisasubstanceofClass1.546UNNo2009zirconium,dry,finishedsheets,striporcoiledwire,inthicknessesoflessthan18:m,isasubstanceofClass4.2.Zirconium,dry,finishedsheets,striporcoiledwire,inthicknessesof254:mormore,isnotsubjecttotherequirementsofthisDirective.547UNNo2210maneborUNNo2210manebpreparationsinself-heatingformaresubstancesofClass4.2.548Chlorosilaneswhich,incontactwithwater,emitflammablegases,aresubstancesofClass4.3.549Chlorosilaneshavingaflash-pointoflessthan23°Candwhich,incontactwithwater,donotemitflammablegasesaresubstancesofClass3.Chlorosilaneshavingaflash-pointequaltoorgreaterthan23°Candwhich,incontactwithwater,donotemitflammablegasesaresubstancesofClass8.550UNNo1333ceriuminslabs,rodsoringotsisasubstanceofClass4.1.551Solutionsoftheseisocyanateshavingaflash-pointbelow23°CaresubstancesofClass3.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/568552Metalsandmetalalloysinpowderedorotherflammableform,liabletospontaneouscombustion,aresubstancesofClass4.2.Metalsandmetalalloysinpowderedorotherflammableformwhich,incontactwithwater,emitflammablegasesaresubstancesofClass4.3.553Thismixtureofhydrogenperoxideandperoxyaceticacidshall,inlaboratorytesting(seeManualoftestsandcriteria,PartII,Section20),neitherdetonateinthecavitatedstatenordeflagrateatallandshallshownoeffectwhenheatedunderconfinementnoranyexplosivepower.Theformulationshallbethermallystable(self-acceleratingdecompositiontemperature60°Corhigherfora50kgpackage),andaliquidcompatiblewithperoxyaceticacidshallbeusedfordesensitization.FormulationsnotmeetingthesecriteriaaretoberegardedassubstancesofClass5.2(seeManualoftestsandcriteria,PartII,paragraph20.4.3(g)).554Metalhydrideswhich,incontactwithwater,emitflammablegasesaresubstancesofClass4.3.UNNo2870aluminiumborohydrideorUNNo2870aluminiumborohydrideindevicesisasubstanceofClass4.2.555Dustandpowderofmetalsinnon-spontaneouslycombustibleform,non-toxicwhichnevertheless,incontactwithwater,emitflammablegases,aresubstancesofClass4.3.556OrganometalliccompoundsandtheirsolutionswhichignitespontaneouslyaresubstancesofClass4.2.Flammablesolutionswithorganometalliccompoundsinconcentrationswhich,incontactwithwater,neitheremitflammablegasesindangerousquantitiesnorignitespontaneouslyaresubstancesofClass3.557DustandpowderofmetalsinpyrophoricformaresubstancesofClass4.2.558MetalsandmetalalloysinpyrophoricformaresubstancesofClass4.2.Metalsandmetalalloyswhich,incontactwithwater,donotemitflammablegasesandarenotpyrophoricorself-heating,butwhichareeasilyignited,aresubstancesofClass4.1.559Mixturesofahypochloritewithanammoniumsaltarenottobeacceptedforcarriage.UNNo1791hypochloritesolutionisasubstanceofClass8.560UNNo3257elevatedtemperatureliquid,n.o.s.,atorabove100°Cand,forasubstancewithaflash-point,belowitsflash-point(includingmoltenmetalsandmoltensalts)isasubstanceofClass9.561ChloroformateshavingpredominantlycorrosivepropertiesaresubstancesofClass8.562SpontaneouslycombustibleorganometalliccompoundsaresubstancesofClass4.2.Water-reactiveorganometalliccompounds,flammable,aresubstancesofClass4.3.563UNNo1905selenicacidisasubstanceofClass8.564UNNo2443vanadiumoxytrichloride,UNNo2444vanadiumtetrachlorideandUNNo2475vanadiumtrichloridearesubstancesofClass8.565Unspecifiedwastesresultingfrommedical/veterinarytreatmentofhumans/animalsorfrombiologicalresearch,andwhichareunlikelytocontainsubstancesofClass6.2shallbeassignedtothisentry.DecontaminatedclinicalwastesorwastesresultingfrombiologicalresearchwhichpreviouslycontainedinfectioussubstancesarenotsubjecttotherequirementsofClass6.2.566UNNo2030hydrazinehydrateandUNNo2030hydrazineaqueoussolution,withmorethan37%andnotmorethan64%hydrazine,bymass,aresubstancesofClass8.567Mixturescontainingmorethan21%oxygenbyvolumeshallbeclassifiedasoxidising.568BariumazidewithawatercontentlowerthanthestatedlimitisasubstanceofClass1,UNNo0224.569-579(Reserved)580Tank-vehicles,specialisedvehiclesandspeciallyequippedvehiclesshallbearonbothsidesandattherearthemarkreferredtoin5.3.3.Tank-containers,portabletanks,specialcontainersandspeciallyequippedcontainersshallbearthismarkonbothsidesandateachend.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/569581Thisentrycoversmixturesofmethylacetyleneandpropadienewithhydrocarbons,whichas:mixtureP1,containnotmorethan63%methylacetyleneandpropadienebyvolumeandnotmorethan24%propaneandpropylenebyvolume,thepercentageofC4-saturatedhydrocarbonsbeingnotlessthan14%byvolume;andasmixtureP2,containnotmorethan48%methylacetyleneandpropadienebyvolumeandnotmorethan50%propaneandpropylenebyvolume,thepercentageofC4-saturatedhydrocarbonsbeingnotlessthan5%byvolume;aswellasmixturesofpropadienewith1to4%methylacetylene.Whenrelevant,inordertomeettherequirementsforthetransportdocument(5.4.1.1),theterm‘mixtureP1’or‘mixtureP2’maybeusedastechnicalname.582Thisentrycovers,interalia,mixturesofgasesindicatedbytheletterR...,whichas:mixtureF1,haveavapourpressureat70°Cnotexceeding1,3MPa(13bar)andadensityat50°Cnotlowerthanthatofdichlorodifluoromethane(1,30kg/l);mixtureF2,haveavapourpressureat70°Cnotexceeding1,9MPa(19bar)andadensityat50°Cnotlowerthanthatofdichloridifluoromethane(1,21kg/l);mixtureF3,haveavapourpressureat70°Cnotexceeding3MPa(30bar)andadensityat50°Cnotlowerthanthatofchlorodifluoromethane(1,09kg/l).Note:Trichlorofluoromethane(refrigerantgasR11),1,1,2-trichloro-1,2,2-trifluoroethane(refrigerantgasR113),1,1,1-trichloro-2,2,2-trifluor-oethane(refrigerantgasR113a),1-chloro-1,2,2-trifluoroethane(refrigerantgasR133)and1-chloro-1,1,2-trifluoroethane(refrigerantgasR133b)arenotsubstancesofClass2.Theymay,however,enterintothecompositionofmixturesF1toF3.Whenrelevant,inordertomeettherequirementsforthetransportdocument(5.4.1.1),theterm‘mixtureF1’,‘mixtureF2’or‘mixtureF3’maybeusedastechnicalname.583Thisentrycovers,interalia,mixtureswhichas:—mixtureA,haveavapourpressureat70°Cnotexceeding1,1MPa(11bar)andadensityat50°Cnotlowerthan0,525kg/l;—mixtureA01,haveavapourpressureat70°Cnotexceeding1,6MPa(16bar)andarelativedensityat50°Cnotlowerthan0,516kg/l;—mixtureA02,haveavapourpressureat70°Cnotexceeding1,6MPa(16bar)andarelativedensityat50°Cnotlowerthan0,505kg/l;—mixtureA0,haveavapourpressureat70°Cnotexceeding1,6MPa(16bar)andadensityat50°Cnotlowerthan0,495kg/l;—mixtureA1,haveavapourpressureat70°Cnotexceeding2,1MPa(21bar)andadensityat50°Cnotlowerthan0,485kg/l;—mixtureB1haveavapourpressureat70°Cnotexceeding2,3MPa(23bar)andarelativedensityat50°Cnotlowerthan0,474kg/l;—mixtureB2haveavapourpressureat70°Cnotexceeding2,6MPa(26bar)andarelativedensityat50°Cnotlowerthan0,463kg/l;—mixtureB,haveavapourpressureat70°Cnotexceeding2,6MPa(26bar)andadensityat50°Cnotlowerthan0,450kg/l;—mixtureC,haveavapourpressureat70°Cnotexceeding3,1MPa(31bar)andarelativedensityat50°Cnotlowerthan0,440kg/l.Whenrelevant,inordertomeettherequirementsforthetransportdocument(5.4.1.1),thefollowingtermsmaybeusedastechnicalname:—‘mixtureA’or‘butane’,—‘mixtureA01’or‘butane’,—‘mixtureA02’or‘butane’,—‘mixtureA0’or‘butane’,—‘mixtureA1’,—‘mixtureB1’,—‘mixtureB2’,—‘mixtureB’,—‘mixtureC’or‘Propane’.Forcarriageintanks,thetradenames‘butane’or‘propane’maybeusedonlyasacomplement.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/570584ThisgasisnotsubjecttotherequirementsofthisDirectivewhen:—itisinthegaseousstate,—itcontainsnotmorethan0,5%air,—itiscontainedinmetalcapsules(sodors,sparklets)freefromdefectswhichmayimpairtheirstrength,—theleakproofnessoftheclosureofthecapsuleisensured,—acapsulecontainsnotmorethan25gofthisgas,—acapsulecontainsnotmorethan0,75gofthisgaspercm3ofcapacity.585CinnabarisnotsubjecttotherequirementsofthisDirective.586Hafnium,titaniumandzirconiumpowdersshallcontainavisibleexcessofwater.Hafnium,titaniumandzirconiumpowders,wetted,mechanicallyproduced,ofaparticlesizeof53µmandover,orchemicallyproduced,ofaparticlesizeof840µmandover,arenotsubjecttotherequirementsofthisDirective.587BariumstearateandbariumtitanatearenotsubjecttotherequirementsofthisDirective.588SolidhydratedformsofaluminiumbromideandaluminiumchloridearenotsubjecttotherequirementsofthisDirective.589Calciumhypochloritemixtures,dry,containingnotmorethan10%availablechlorinearenotsubjecttotherequirementsofthisDirective.590FerricchloridehexahydrateisnotsubjecttotherequirementsofthisDirective.591Leadsulphatewithnotmorethan3%freeacidisnotsubjecttotherequirementsofthisDirective.592Uncleanedemptypackagings(includingemptyIBCsandlargepackagings),emptytank-vehicles,emptydemountabletanks,emptyportabletanks,emptytank-containersandemptysmallcontainerswhichhavecontainedthissubstancearenotsubjecttotherequirementsofthisDirective.593Thisgas,intendedforthecoolingofe.g.medicalorbiologicalspecimens,ifcontainedindoublewallreceptacleswhichcomplywiththeprovisionsofpackinginstructionP203(11)of4.1.4.1isnotsubjecttotherequirementsofthisDirective.594Thefollowingarticles,manufacturedandfilledaccordingtotheregulationsofthemanufacturingStateandpackagedinstrongouterpackagings,arenotsubjecttotherequirementsofthisDirective:—UNNo1044fireextinguishersprovidedwithprotectionagainstinadvertentdischarge;—UNNo3164articles,pressurizedpneumaticorhydraulic,designedtowithstandstressesgreaterthantheinternalgaspressurebyvirtueoftransmissionofforce,intrinsicstrengthorconstruction.595MixtureswithaPCBorPCTcontentofnotmorethan50mg/kgarenotsubjecttotherequirementsofthisDirective.596Cadmiumpigments,suchascadmiumsulphides,cadmiumsulphoselenidesandcadmiumsaltsofhigherfattyacids(e.g.cadmiumstearate),arenotsubjecttotherequirementsofthisDirective.597Aceticacidsolutionswithnotmorethan10%pureacidbymass,arenotsubjecttotherequirementsofthisDirective.598ThefollowingarenotsubjecttotherequirementsofthisDirective:(a)newstoragebatterieswhen:—theyaresecuredinsuchawaythattheycannotslip,fallorbedamaged,—theyareprovidedwithcarryingdevices,unlesstheyaresuitablystacked,e.g.onpallets,—therearenodangeroustracesofalkalisoracidsontheoutside,—theyareprotectedagainstshortcircuits.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/571(b)usedstoragebatterieswhen:—theircasesareundamaged,—theyaresecuredinsuchawaythattheycannotleak,slip,fallorbedamaged,e.g.bystackingonpallets,—therearenodangeroustracesofalkalisoracidsontheoutsideofthearticles,—theyareprotectedagainstshortcircuits.‘Usedstoragebatteries’meansstoragebatteriescarriedforrecyclingattheendoftheirnormalservicelife.599Manufacturedarticlesorinstrumentscontainingnotmorethan1kgofmercuryarenotsubjecttotherequirementsofthisDirective.600Vanadiumpentoxide,fusedandsolidified,isnotsubjecttotherequirementsofthisDirective.601Pharmaceuticalproductsreadyforuse,e.g.cosmetics,drugsandmedicines,whicharesubstancesmanufacturedandpackedinpackagingsofatypeintendedforretailsaleordistributionforpersonalorhouseholdconsumptionarenotsubjecttotherequirementsofthisDirective.602Phosphorussulphideswhicharenotfreefromyellowandwhitephosphorusarenottobeacceptedforcarriage.603AnhydroushydrogencyanidenotmeetingthedescriptionforUNNo1051orUNNo1614isnottobeacceptedforcarriage.Hydrogencyanide(hydrocyanicacid)containinglessthan3%waterisstable,ifthepH-valueis2,5±0,5andtheliquidisclearandcolourless.604Ammoniumbromateanditsaqueoussolutionsandmixturesofabromatewithanammoniumsaltarenottobeacceptedforcarriage.605Ammoniumchlorateanditsaqueoussolutionsandmixturesofachloratewithanammoniumsaltarenottobeacceptedforcarriage.606Ammoniumchloriteanditsaqueoussolutionsandmixturesofachloritewithanammoniumsaltarenottobeacceptedforcarriage.607Mixturesofpotassiumnitrateandsodiumnitritewithanammoniumsaltarenottobeacceptedforcarriage.608Ammoniumpermanganateanditsaqueoussolutionsandmixturesofapermanganatewithanammoniumsaltarenottobeacceptedforcarriage.609Tetranitromethanenotfreefromcombustibleimpuritiesisnottobeacceptedforcarriage.610Thecarriageofthissubstance,whenitcontainsmorethan45%hydrogencyanideisprohibited.611Ammoniumnitratecontainingmorethan0,2%combustiblesubstances(includinganyorganicsubstancecalculatedascarbon)isnottobeacceptedforcarriageunlessitisaconstituentofasubstanceorarticleofClass1.612(Reserved)613Chloricacidsolutioncontainingmorethan10%chloricacidandmixturesofchloricacidwithanyliquidotherthanwaterisnottobeacceptedforcarriage.6142,3,7,8-tetrachlorodibenzo-p-dioxin(TCDD)inconcentrationsconsideredhighlytoxicaccordingtothecriteriain2.2.61.1isnottobeacceptedforcarriage.615(Reserved)616Substancescontainingmorethan40%liquidnitricestersshallsatisfytheexudationtestspecifiedin2.3.1.617Inadditiontothetypeofexplosive,thecommercialnameoftheparticularexplosiveshallbemarkedonthepackageandshallbespecifiedinthetransportdocument.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/572618Inreceptaclescontaining1,2-butadiene,theoxygenconcentrationinthegaseousphaseshallnotexceed50ml/m3.619-622(Reserved)623UNNo1829sulphurtrioxideshallbeinhibited.Sulphurtrioxide,99,95%pureorabove,maybecarriedwithoutinhibitorintanksbyroadprovidedthatitstemperatureismaintainedatorabove32,5°C.Forthecarriageofthissubstancewithoutinhibitorintanksataminimumtemperatureof32,5°C,thespecification‘Transportunderminimumtemperatureoftheproductof32,5°C’shallappearinthetransportdocument.624FertilisershavinganammoniumnitratecontentoracontentincombustiblesubstancesexceedingthevaluesshownarenottobeacceptedforcarriageexceptundertheconditionsapplicabletoClass1.FertilisershavinganammoniumnitratecontentbelowthelimitvaluesindicatedarenotsubjecttotherequirementsofthisDirective.Ammoniumnitratefertilisers,uniformnon-segregatingmixturesofnitrogen/phosphateornitrogen/potashtypesorcompletefertilisersofnitrogen/phosphate/potashtypewhosemolecularexcessofnitrateionsoverammoniumions(calculatedaspotassiumnitrate)islessthan10%arenotsubjecttotherequirementsofthisDirectiveprovidedthat:(a)theirammoniumnitratecontentisnotmorethan70%andtheirtotalcontentofcombustiblematerialisnotmorethan0,4%,or(b)theirammoniumnitratecontentisnotmorethan45%irrespectiveoftheircontentofcombustiblematerial.625Packagescontainingthesearticlesshallbeclearlymarkedasfollows:‘UNNo1950AEROSOLS’626-627(Reserved)628Uniformnon-segregatingmixturesofammoniumnitratewithaddedmatterwhichisinorganicandchemicallyinerttowardsammoniumnitrate,withnotlessthan90%ammoniumnitrateandnotmorethan0,2%combustiblematerial(includingorganicmaterialcalculatedascarbon),orwithmorethan70%butlessthan90%ammoniumnitrateandnotmorethan0,4%totalcombustiblematerial.629Uniformnon-segregatingmixturesofammoniumnitratewithcalciumcarbonateand/ordolomite,withmorethan80%butlessthan90%ammoniumnitrateandnotmorethan0,4%totalcombustiblematerial.630Uniformnon-segregatingmixturesofammoniumnitrateandammoniumsulphate,withmorethan45%butnotmorethan70%ammoniumnitrateandnotmorethan0,4%totalcombustiblematerial.631Uniformnon-segregatingmixturesofnitrogen/phosphateornitrogen/potashtypesorcompletefertilisersofnitrogen/phosphate/potashtype,withmorethan70%butlessthan90%ammoniumnitrateandnotmorethan0,4%totalcombustiblematerial.632Consideredtobespontaneouslyflammable(pyrophoric).633Packagesandsmallcontainerscontainingthissubstanceshallbearthefollowingmarking:‘Keepawayfromanysourceofignition’.Thismarkingshallbeinanofficiallanguageoftheforwardingcountry,andalso,ifthatlanguageisnotEnglish,FrenchorGerman,inEnglish,FrenchorGerman,unlessanyagreementsconcludedbetweenthecountriesconcernedinthetransportoperationprovideotherwise.634Packagescontainingsubstancescarriedinrefrigeratedliquidnitrogenshall,inaddition,bearalabelconformingtomodelNo2.2.635PackagescontainingthesearticlesneednotbearalabelconformingtomodelNo9unlessthearticleisfullyenclosedbypackaging,cratesorothermeansthatpreventthereadyidentificationofthearticle.636(a)Withtheapprovalofthecompetentauthorityofthecountryoforigin,thequantityoflithiumorlithiumalloyineachcellmayberaisedto60gandapackagemaycontainupto2500goflithiumorlithiumalloy;thecompetentauthorityshalldeterminetheconditionsofcarriageaswellasthetypeanddurationofthetest.IfthecountryoforiginisnotpartytothisDirective,theapprovalshallberecognisedbythecompetentauthorityofthefirstcountrypartytothisDirectivereachedbytheconsignment.Insuchacase,acopyoftheapprovalwiththeconditionsofcarriageshallbeattachedtothetransportdocument.Thisapprovalshallbedrawnupinanofficiallanguageoftheforwardingcountryandalso,ifthatlanguageisnotEnglish,FrenchorGerman,inEnglish,FrenchorGerman,unlessanyagreementsconcludedbetweenthecountriesconcernedinthetransportoperationprovideotherwise.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/573(b)Cellscontainedinequipmentshallnotbecapableofbeingdischargedduringcarriagetotheextentthattheopencircuitvoltagefallsbelow2voltsortwothirdsofthevoltageoftheundischargedcell,whicheveristhelower.(c)Packagescontainingusedcellsorbatteriesinunmarkedpackagingsshallbeartheinscription:‘Usedlithiumcells’.(d)Articleswhichdonotmeettherequirementsofthisspecialprovisionand/orspecialprovisions188,230,287asappropriatearenottobeacceptedforcarriage.637Geneticallymodifiedmicro-organismsarethosewhicharenotdangerousforhumansandanimals,butwhichcouldalteranimals,plants,microbiologicalsubstancesandecosystemsinsuchawayascannotoccurnaturally.Geneticallymodifiedmicro-organismswhichhavereceivedaconsentfordeliberatereleaseintotheenvironment(1)arenotsubjecttotherequirementsofClass9.LivevertebrateorinvertebrateanimalsshallnotbeusedtocarrythesesubstancesclassifiedunderthisUNnumberunlessthesubstancecanbecarriedinnootherway.ForthecarriageofeasilyperishablesubstancesunderthisUNnumberappropriateinformationshallbegiven,e.g.:‘Coolat+2°/+4°C’or‘Carryinfrozenstate’or‘Donotfreeze’.638Substancesrelatedtoself-reactivesubstances(see2.2.41.1.19).639See2.2.2.3,classificationcode2F,UNNo1965,Note2.640Thephysicalandtechnicalcharacteristicsmentionedincolumn2ofTableAofChapter3.2,whichwereintendedtoestablishdifferentconditionsofcarriageforthesamepackinggroup,shallalsobementionedadditionallyinthetransportdocument.641SulphurisnotsubjecttotherequirementsofthisDirectivewhenithasbeenformedtospecificshape(e.g.pellets,granules,pastillesorflakes).642Exceptasauthorisedunder1.1.4.2,thisentryoftheUNmodelregulationsshallnotbeusedforthecarriageoffertiliserammoniatingsolutionswithfreeammonia.643StoneoraggregateasphaltmixtureisnotsubjecttotherequirementsforClass9.(1)SeeinparticularPartCofDirective90/220/EEC(OJL117,8.5.1990,p.18),whichsetsouttheauthorisationproceduresfortheEuropeanCommunity.CHAPTER3.4Exemptionsrelatedtodangerousgoodspackedinlimitedquantities3.4.1.Packagingsusedinaccordancewith3.4.3to3.4.6below,needonlytoconformtothegeneralprovisionsof4.1.1.1,4.1.1.2and4.1.1.43.4.2.Whenthecode‘LQ0’isshownincolumn7ofTableAinChapter3.2foragivensubstanceorarticle,thatsubstanceorarticleisnotexemptedfromanyoftheapplicableprovisionsofAnnexesAandBwhenitispackedinlimitedquantities,unlessotherwisespecifiedintheseannexes.3.4.3.UnlessotherwiseprovidedinthisChapter,whenoneofthecodes‘LQ1’or‘LQ2’isshownincolumn7ofTableAinChapter3.2foragivensubstanceorarticle,theprovisionsofotherChaptersofthisDirectivedonotapplytothecarriageofthatsubstanceorarticle,provided:(a)theprovisionsof3.4.5(a)to(c)areobserved;withrespecttotheseprovisions,articlesareconsideredtobeinnerpackagings;(b)innerpackagingsmeettheconditionsof6.2.1.2when‘LQ1’isshown,andtheconditionsof6.2.1.2,6.2.4.1and6.2.4.2when‘LQ2’isshown.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/5743.4.4.Unlessotherwiseprovidedinthischapter,whenoneofthecodes‘LQ3’,‘LQ20’,‘LQ21’or‘LQ29’isshownincolumn7ofTableAinChapter3.2foragivensubstance,theprovisionsofotherchaptersofthisDirectivedonotapplytothecarriageofthatsubstance,provided:(a)thesubstanceiscarriedincombinationpackagings,thefollowingouterpackagingsbeingallowed:—steeloraluminiumdrumswithremovablehead;—steeloraluminiumjerricanswithremovablehead;—plywoodorfibredrums;—plasticsdrumsorjerricanswithremovablehead;—boxesofnaturalwood,plywood,reconstitutedwood,fibreboard,plastics,steeloraluminium;(b)themaximumquantityperinnerpackagingandperpackage,prescribedfortherelevantcodeinthesecondandthirdcolumnofthetablein3.4.6,arenotexceeded;(c)eachpackageisclearlyanddurablymarkedwith:(i)theUNnumberofthegoodscontainedtherein,asgivenincolumn1ofTableAinChapter3.2,precededbytheletters‘UN’;(ii)inthecaseofdifferentgoodswithdifferentUNnumberswithinasinglepackage:—theUNnumbersofthegoodscontainedtherein,precededbytheletters‘UN’,or—theletters‘LQ’(1).Thesemarkingsshallbedisplayedwithinadiamond-shapedareasurroundedbyalinethatmeasuresatleast100mmx100mm.Ifthesizeofthepackagesorequires,thedimensionsmaybereduced,providedthemarkingsremainclearlyvisible.3.4.5.UnlessotherwiseprovidedinthisChapter,whenoneofthecodes‘LQ4’to‘LQ19’and‘LQ22’to‘LQ28’isshownincolumn7ofTableAinChapter3.2foragivensubstance,theprovisionsofotherChaptersofthisDirectivedonotapplytothecarriageofthatsubstance,provided:(a)thesubstanceiscarried:—incombinationpackagings,correspondingtotheprescriptionsof3.4.4(a),or—inmetalorplasticsinnerpackagingswhicharenotliabletobreakorbeeasilypunctured,placedinshrink-wrappedorstretch-wrappedtrays;(b)themaximumquantityperinnerpackagingandperpackage,prescribedfortherelevantcodeinthetablein3.4.6(inthesecondandthirdcolumninthecaseofcombinationpackagings,andinthefourthandfifthcolumninthecaseofshrink-wrappedorstretch-wrappedtrays),arenotexceeded;(c)eachpackageisclearlyanddurablymarkedasindicatedin3.4.4(c).3.4.6.TABLECodeCombinationpackagingsInnerpackagingsplacedinshrink-wrappedorstretch-wrappedtraysInnerpackagingMaximumcontentsPackageMaximumgrossmass(kg)/contents(l)InnerpackagingMaximumcontentsPackageMaximumgrossmass(kg)/contents(l)LQ0Noexemptionundertheconditionsof3.4.2.LQ1120ml30kg120ml20kgLQ21l30kg1l20kgLQ3(a)500ml1lNotallowedNotallowedLQ43l12l1l12land20kgLQ55l1l20kgLQ6(a)5l20l1l20land20kgOfficialJournaloftheEuropeanUnionEN26.1.2004L18/575(1)Theletters‘LQ’areanabbreviationoftheEnglishwords‘LimitedQuantities’.CodeCombinationpackagingsInnerpackagingsplacedinshrink-wrappedorstretch-wrappedtraysInnerpackagingMaximumcontentsPackageMaximumgrossmass(kg)/contents(l)InnerpackagingMaximumcontentsPackageMaximumgrossmass(kg)/contents(l)LQ7(a)5l45l5l20kgLQ83kg12kg500g12kgLQ96kg24kg3kg20kgLQ10500ml30kg500ml20kgLQ11(b)500g30kg500g20kgLQ121kg30kg1kg20kgLQ131l30kg1l20kgLQ14(b)25ml30kg25ml20kgLQ15(b)100g30kg100g20kgLQ16(b)125ml30kg125ml20kgLQ17500ml2l100ml2lLQ181kg4kg500g4kgLQ193l12l1l12land20kgLQ20100ml400mlNotallowedNotallowedLQ21500g2kgNotallowedNotallowedLQ221l4l500ml4land20kgLQ233kg12kg1kg12kgLQ246kg24kg2kg20kgLQ251kg4kg1kg20kgLQ26500ml2l500ml2lLQ276kg24kg6kg20kgLQ283l12l3l12land20kgLQ29500ml(perapparatus)ifpackedinleakproofpacka-gingsandconformingto3.4.4(c)only2lifpackedinleakproofpackagingsandconformingto3.4.4(c)onlyNotallowedNotallowed(a)InthecaseofhomogenousmixturesofClass3containingwater,thequantitiesspecifiedrelateonlytothesubstanceofClass3containedinthosemixtures.(b)ForClass5.2thesequantitiesofsubstancesmaybepackedtogetherwithotherarticlesorsubstances,providedtheywillnotinteractdangerouslyintheeventofleakage.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/576OfficialJournaloftheEuropeanUnionEN26.1.2004L18/577Part4PACKINGANDTANKPROVISIONSCHAPTER4.1Useofpackagings,includingintermediatebulkcontainers(IBCs)andlargepackagingsIntroductorynotes1.PackinggroupsDangeroussubstancesofallclassesotherthanthoseofClasses1,2,5.2,6.2and7andthantheself-reactivesubstancesofClass4.1haveforpackingpurposesbeenassignedtothreepackinggroupsinaccordancewiththedegreeofdangertheypresent,i.e.:PackinggroupI:substancespresentinghighdanger;PackinggroupII:substancespresentingmediumdanger;andPackinggroupIII:substancespresentinglowdanger.ThepackinggrouptowhichasubstanceisassignedisindicatedinTableAofChapter3.2.2.Explosives,self-reactivesubstancesandorganicperoxidesUnlessspecificprovisiontothecontraryismadeinthisDirective,thepackagings,includingIBCsandlargepackagings,usedforgoodsofClass1,self-reactivesubstancesofClass4.1andorganicperoxidesofClass5.2shallcomplywiththerequirementsforthemediumdangergroup(packinggroupII).4.1.1.Generalprovisionsforthepackingofdangerousgoods,otherthangoodsofClass2,6.2or7,inpackagings,includingIBCsandlargepackagingsNoteSomeofthesegeneralprovisionsmayapplytothepackingofgoodsofClasses2,6.2and7.Refertosections4.1.6(Class2),4.1.8(Class6.2),4.1.9(Class7)andtotheapplicablepackinginstructioninSection4.1.4.4.1.1.1.Dangerousgoodsshallbepackedingoodqualitypackagings,includingIBCsandlargepackagings,whichshallbestrongenoughtowithstandtheshocksandloadingsnormallyencounteredduringcarriage,includingtranshipmentbetweentransportunitsand/orwarehousesaswellasanyremovalfromapalletoroverpackforsubsequentmanualormechanicalhandling.Packagings,includingIBCsandlargepackagings,shallbeconstructedandclosedsoastopreventanylossofcontentswhenpreparedfortransportwhichmightbecausedundernormalconditionsoftransport,byvibration,orbychangesintemperature,humidityorpressure(resultingfromaltitude,forexample).Nodangerousresidueshalladheretotheoutsideofpackagings,IBCsandlargepackagingsduringcarriage.Theseprovisionsapply,asappropriate,tonew,reused,reconditionedorremanufacturedpackagingsandtonewandreusedIBCsandlargepackagings.4.1.1.2.Partsofpackagings,includingIBCsandlargepackagings,whichareindirectcontactwithdangerousgoods:(a)shallnotbeaffectedorsignificantlyweakenedbythosedangerousgoods;and(b)shallnotcauseadangerouseffecte.g.catalysingareactionorreactingwiththedangerousgoods.Wherenecessary,theyshallbeprovidedwithasuitableinnercoatingortreatment.4.1.1.3.UnlessprovidedelsewhereinthisDirective,eachpackaging,includingIBCsandlargepackagings,exceptinnerpackagings,shallconformtoadesigntypesuccessfullytestedinaccordancewiththerequirementsof6.1.5,6.5.4or6.6.5,respectively.Thepackagingsforwhichthetestisnotrequiredarementionedunder6.1.1.3.4.1.1.4.Whenfillingpackagings,includingIBCsandlargepackagings,withliquids,sufficientullage(outage)shallbelefttoensurethatneitherleakagenorpermanentdistortionofthepackagingoccursasaresultofanexpansionoftheliquidcausedbytemperatureslikelytooccurduringtransport.Unlessspecificrequirementsareprescribed,liquidsshallnotcompletelyfillapackagingatatemperatureof55°C.However,sufficientullageshallbeleftinanIBCtoensurethatatthemeanbulktemperatureof50°Citisnotfilledtomorethan98%ofitswatercapacity.Forafillingtemperatureof15°C,themaximumdegreeoffillingshallbedeterminedasfollows,unlessotherwiseprovidedunderaparticularclass,either:(a)Boilingpoint(initialboilingpoint)ofthesubstancein°C<60≥60<100≥100<200≥200<300≥300Degreeoffillingasapercentageofthecapacityofthepackaging9092949698orOfficialJournaloftheEuropeanUnionEN26.1.2004L18/578(b)Degreeoffilling¼981þα50(cid:1)tfðÞ%ofthecapacityofthepackagingInthisformulaαrepresentsthemeancoefficientofcubicexpansionoftheliquidsubstancebetween15°Cand50°C;thatistosay,foramaximumriseintemperatureof35°C,αiscalculatedaccordingtotheformulaα¼d15(cid:1)d5035(cid:2)d50d15andd50beingtherelativedensities(1)oftheliquidat15°Cand50°CandtFthemeantemperatureoftheliquidatthetimeoffilling.4.1.1.5.Innerpackagingsshallbepackedinanouterpackaginginsuchawaythat,undernormalconditionsofcarriage,theycannotbreak,bepuncturedorleaktheircontentsintotheouterpackaging.Innerpackagingsthatareliabletobreakorbepuncturedeasily,suchasthosemadeofglass,porcelainorstonewareorofcertainplasticsmaterials,etc.,shallbesecuredinouterpackagingswithsuitablecushioningmaterial.Anyleakageofthecontentsshallnotsubstantiallyimpairtheprotectivepropertiesofthecushioningmaterialoroftheouterpackaging.4.1.1.6.Dangerousgoodsshallnotbepackedtogetherinthesameouterpackagingorinlargepackagings,withdangerousorothergoodsiftheyreactdangerouslywitheachotherandcause:(a)combustionorevolutionofconsiderableheat;(b)evolutionofflammable,asphyxiant,oxidisingortoxicgases;(c)theformationofcorrosivesubstances;or(d)theformationofunstablesubstances.NoteFormixedpackingspecialprovisions,see4.1.10.4.1.1.7.Theclosuresofpackagingscontainingwettedordilutedsubstancesshallbesuchthatthepercentageofliquid(water,solventorphlegmatiser)doesnotfallbelowtheprescribedlimitsduringtransport.4.1.1.7.1.WheretwoormoreclosuresystemsarefittedinseriesonanIBC,thatnearesttothesubstancebeingcarriedshallbeclosedfirst.4.1.1.8.Liquidsmayonlybefilledintoinnerpackagingswhichhaveanappropriateresistancetointernalpressurethatmaybedevelopedundernormalconditionsofcarriage.Wherepressuremaydevelopinapackagebytheemissionofgasfromthecontents(asaresultoftemperatureincreaseorothercause),thepackagingmaybefittedwithavent,providedthatthegasemittedwillnotcausedangeronaccountofitstoxicity,itsflammability,thequantityreleased,etc.Aventingdeviceshallbefittedifdangerousoverpressuremaydevelopduetonormaldecompositionofsubstances.Theventshallbesodesignedthat,whenthepackagingisintheattitudeinwhichitisintendedtobecarried,leakagesofliquidandthepenetrationofforeignmatterarepreventedundernormalconditionsofcarriage.4.1.1.9.New,remanufacturedorreusedpackagings,includingIBCsandlargepackagings,orreconditionedpackagingsandrepairedIBCsshallbecapableofpassingthetestsprescribedin6.1.5,6.5.4or6.6.5,respectively.Beforebeingfilledandhandedoverforcarriage,everypackaging,includingIBCsandlargepackagings,shallbeinspectedtoensurethatitisfreefromcorrosion,contaminationorotherdamageandeveryIBCshallbeinspectedwithregardtotheproperfunctioningofanyserviceequipment.Anypackagingwhichshowssignsofreducedstrengthascomparedwiththeapproveddesigntypeshallnolongerbeusedorshallbesoreconditioned,thatitisabletowithstandthedesigntypetests.AnyIBCwhichshowssignsofreducedstrengthascomparedwiththetesteddesigntypeshallnolongerbeusedorshallbesorepairedthatitisabletowithstandthedesigntypetests.4.1.1.10.Liquidsshallbefilledonlyintopackagings,includingIBCs,whichhaveanappropriateresistancetotheinternalpressurethatmaydevelopundernormalconditionsofcarriage.PackagingsandIBCsmarkedwiththehydraulictestpressureprescribedin6.1.3.1(d)and6.5.2.2.1,respectivelyshallbefilledonlywithaliquidhavingavapourpressure:(a)suchthatthetotalgaugepressureinthepackagingorIBC(i.e.thevapourpressureofthefillingsubstanceplusthepartialpressureofairorotherinertgases,less100kPa)at55°C,determinedonthebasisofamaximumdegreeoffillinginaccordancewith4.1.1.4andafillingtemperatureof15°C,willnotexceedtwo-thirdsofthemarkedtestpressure;or(b)at50°Clessthanfourseventhsofthesumofthemarkedtestpressureplus100kPa;or(c)at55°Clessthantwothirdsofthesumofthemarkedtestpressureplus100kPa.MetalIBCsintendedforthecarriageofliquidsshallnotbeusedtocarryliquidshavingavapourpressureofmorethan110kPa(1,1bar)at50°Cor130kPa(1,3bar)at55°C.(1)Relativedensity(d)isconsideredtobesynonymouswithspecificgravity(SG)andwillbeusedthroughoutthischapter.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/579Examplesofrequiredmarkedtestpressuresforpackagings,includingIBCs,calculatedasin4.1.1.10(c)UNNoNameClassPackinggroupVp55(kPa)Vp55×1.5(kPa)(Vp55×1.5)minus100(kPa)Requiredminimumtestpressuregaugeunder6.1.5.5.4(c)(kPa)Minimumtestpressure(gauge)tobemarkedonthepackaging(kPa)2056Tetrahydrofuran3II7010551001002247n-Decane3III1,42,1–97,91001001593Dichloromethane6.1III1642461461461501155Diethylether3I199299199199250Notes1.Forpureliquidsthevapourpressureat55°C(Vp55)canoftenbeobtainedfromscientifictables.2.Thetablereferstotheuseof4.1.1.10(c)only,whichmeansthatthemarkedtestpressureshallexceed1,5timesthevapourpressureat55°Cless100kPa.When,forexample,thetestpressureforn-decaneisdeterminedaccordingto6.1.5.5.4(a),theminimummarkedtestpressuremaybelower.3.Fordiethylethertherequiredminimumtestpressureunder6.1.5.5.5is250kPa.4.1.1.11.Emptypackagings,includingIBCsandlargepackagings,thathavecontainedadangeroussubstancearesubjecttothesamerequirementsasthoseforafilledpackaging,unlessadequatemeasureshavebeentakentonullifyanyhazard.4.1.1.12.Everypackagings,includingIBCs,intendedtocontainliquidsshallsuccessfullyundergoasuitableleakproofnesstest,andbecapableofmeetingtheappropriatetestlevelindicatedin6.1.5.4.3or6.5.4.7forthevarioustypesofIBCs:(a)beforeitisfirstusedforcarriage;(b)afterremanufacturingorreconditioningofanypackaging,beforeitisreusedforcarriage;(c)aftertherepairofanyIBC,beforeitisreusedforcarriage.Forthistestthepackaging,orIBC,neednothaveitsclosuresfitted.TheinnerreceptacleofacompositepackagingorIBCmaybetestedwithouttheouterpackaging,providedthetestresultsarenotaffected.Thistestisnotrequiredfor:—innerpackagingsofcombinationpackagingsorlargepackagings,—innerreceptaclesofcompositepackagings(glass,porcelainorstoneware)markedwiththesymbol‘RID/ADR’inaccordancewith6.1.3.1(a)(ii),—lightgaugemetalpackagingsmarkedwiththesymbol‘RID/ADR’inaccordancewith6.1.3.1(a)(ii).4.1.1.13.Packagings,includingIBCs,usedforsolidswhichmaybecomeliquidattemperatureslikelytobeencounteredduringcarriageshallalsobecapableofcontainingthesubstanceintheliquidstate.4.1.1.14.Packagings,includingIBCs,usedforpowderyorgranularsubstancesshallbesift-prooforshallbeprovidedwithaliner.4.1.1.15.Forplasticsdrumsandjerricans,rigidplasticsIBCsandcompositeIBCswithplasticsinnerreceptacles,unlessotherwiseapprovedbythecompetentauthority,theperiodofusepermittedforthecarriageofdangeroussubstancesshallbefiveyearsfromthedateofmanufactureofthereceptacles,exceptwhereashorterperiodofuseisprescribedbecauseofthenatureofthesubstancetobecarried.4.1.1.16.Packagingsmarkedinaccordancewith6.1.3butwhichwereapprovedinaStatewhichisnotaContractingPartytothisDirectivemayneverthelessbeusedforcarriageunderthisDirective.4.1.1.17.Useofsalvagepackagings4.1.1.17.1.Damaged,defectiveorleakingpackages,ordangerousgoodsthathavespilledorleakedmaybecarriedinsalvagepackagingsmentionedin6.1.5.1.11.Thisdoesnotpreventtheuseofbiggersizepackagingsofappropriatetypeandperformancelevelundertheconditionsof4.1.1.17.2.4.1.1.17.2.Appropriatemeasuresshallbetakentopreventexcessivemovementofthedamagedorleakingpackageswithinasalvagepackaging.Whenthesalvagepackagingcontainsliquids,sufficientinertabsorbentmaterialshallbeaddedtoeliminatethepresenceoffreeliquid.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/5804.1.2.AdditionalgeneralprovisionsfortheuseofIBCs4.1.2.1.WhenIBCsareusedforthecarriageofliquidswithaflash-pointof61°C(closedcup)orlower,orofpowdersliabletodustexplosion,measuresshallbetakentopreventadangerouselectrostaticdischarge.4.1.2.2.TheperiodictestingandinspectionrequirementsforIBCsareprovidedinChapter6.5.AnIBCshallnotbefilledandofferedforcarriageafterthedateofexpiryofthelastperiodictestrequiredby6.5.4.14.3,orthedateofexpiryofthelastperiodicinspectionrequiredby6.5.1.6.4.However,anIBCfilledpriortothedateofexpiryofthelastperiodictestorinspectionmaybecarriedforaperiodnottoexceedthreemonthsbeyondthedateofexpiryofthelastperiodictestorinspection.Inaddition,anIBCmaybecarriedafterthedateofexpiryofthelastperiodictestorinspection:(a)afteremptyingbutbeforecleaning,forpurposesofperformingtherequiredtestorinspectionpriortorefilling;and(b)unlessotherwiseapprovedbythecompetentauthority,foraperiodnottoexceedsixmonthsbeyondthedateofexpiryofthelastperiodictestorinspectioninordertoallowthereturnofdangerousgoodsorresiduesforproperdisposalorrecycling.NoteFortheparticularsinthetransportdocument,see5.4.1.1.11.4.1.2.3.IBCsoftype31HZ2shallbefilledtoatleast80%ofthevolumeoftheoutercasingandalwaysbecarriedinclosedvehiclesorcontainers.4.1.3.Generalprovisionsconcerningpackinginstructions4.1.3.1.PackinginstructionsapplicabletodangerousgoodsofClasses1to9arespecifiedinSection4.1.4.Theyaresubdividedinthreesubsectionsdependingonthetypeofpackagingstowhichtheyapply:Subsection4.1.4.1forpackagingsotherthanIBCsandlargepackagings;thesepackinginstructionsaredesignatedbyanalphanu-mericcodestartingwiththeletter‘P’or‘R’forpackagingsspecifictothisDirective;Subsection4.1.4.2forIBCs;thesearedesignatedbyanalphanumericcodestartingwiththeletters‘IBCs’;Subsection4.1.4.3forlargepackagings;thesearedesignatedbyanalphanumericcodestartingwiththeletters‘LP’.Generally,packinginstructionsspecifythatthegeneralprovisionsof4.1.1,4.1.2or4.1.3,asappropriate,areapplicable.TheymayalsorequirecompliancewiththespecialprovisionsofSections4.1.5,4.1.6,4.1.7,4.1.8or4.1.9whenappropriate.Specialpackingprovisionsmayalsobespecifiedinthepackinginstructionforindividualsubstancesorarticles.Theyarealsodesignatedbyanalphanumericcodecomprisingtheletters:‘PP’:forpackagingsotherthanIBCsandlargepackagings,or‘RR’forspecialprovisionsspecifictothisDirective;‘B’:forIBCs;‘L’:forlargepackagings.Unlessotherwisespecified,eachpackagingshallconformtotheapplicablerequirementsofPart6.Generallypackinginstructionsdonotprovideguidanceoncompatibilityandtheusershallnotselectapackagingwithoutcheckingthatthesubstanceiscompatiblewiththepackagingmaterialselected(e.g.glassreceptaclesareunsuitableformostfluorides).Whereglassreceptaclesarepermittedinthepackinginstructionsporcelain,earthenwareandstonewarepackagingsarealsoallowed.4.1.3.2.Column8ofTableAofChapter3.2showsforeacharticleorsubstancethepackinginstruction(s)thatshallbeused.Columns9aand9bindicatethespecialpackingprovisionsandthemixedpackingprovisions(see4.1.10)applicabletospecificsubstancesorarticles.4.1.3.3.Eachpackinginstructionshows,whereapplicable,theacceptablesingleandcombinationpackagings.Forcombinationpackagings,theacceptableouterpackagings,innerpackagingsandwhenapplicablethemaximumquantitypermittedineachinnerorouterpackaging,areshown.Maximumnetmassandmaximumcapacityareasdefinedin1.2.1.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/5814.1.3.4.Thefollowingpackagingsshallnotbeusedwhenthesubstancesbeingcarriedareliabletobecomeliquidduringcarriage:Packagings—Drums:1Dand1G—Boxes:4A,4B,4C1,4C2,4D,4F,4G,4H1and4H2—Bags:5L1,5L2,5L3,5H1,5H2,5H3,5H4,5M1and5M2—Compositepackagings:6HC,6HD2,6HG1,6HG2,6HD1,6PC,6PD1,6PD2,6PG1,6PG2and6PH1IBCs—ForsubstancesofpackinggroupI:AlltypesofIBC—ForsubstancesofpackinggroupsIIandIII:—Wooden:11C,11Dand11F—Fibreboard:11G—Flexible:13H1,13H2,13H3,13H4,13H5,13L1,13L2,13L3,13L4,13M1and13M2—Composite:11HZ2,21HZ2and31HZ2Forthepurposesofthisparagraph,substancesandmixturesofsubstanceshavingameltingpointequaltoorlessthan45°Cshallbetreatedassolidsliabletobecomeliquidduringtransport.4.1.3.5.WherethepackinginstructionsinthisChapterauthorisetheuseofaparticulartypeofouterpackaginginacombinationpackaging(e.g.4G),packagingsbearingthesamepackagingidentificationcodefollowedbytheletters‘V’,‘U’or‘W’markedinaccordancewiththerequirementsofPart6(e.g.4GV,4GUor4GW)mayalsobeusedunderthesameconditionsandlimitationsapplicabletotheuseofthattypeofouterpackagingaccordingtotherelevantpackinginstructions.Forexample,acombinationpackagingmarkedwiththepackagingcode‘4GV’maybeusedwheneveracombinationpackagingmarked‘4G’isauthorised,providedtherequirementsintherelevantpackinginstructionregardingtypesofinnerpackagingsandquantitylimitationsarerespected.4.1.3.6.GascylindersandgasreceptaclesapprovedbythecompetentauthorityareauthorisedforthetransportofanyliquidorsolidsubstanceassignedtopackinginstructionP001orP002unlessotherwiseindicatedinthepackinginstructionorbyaspecialprovisionincolumn9aofTableAofChapter3.2.Thecapacityofgascylindersshallnotexceed450litres.Thecapacityforgasreceptaclesshallnotexceed1000litres.4.1.3.7.PackagingsorIBCsnotspecificallyauthorisedintheapplicablepackinginstructionshallnotbeusedforthecarriageofasubstanceorarticleunlessspecificallyallowedunderatemporaryderogationagreedbetweenMemberStatesinaccordancewith1.5.1.4.1.4.ListofpackinginstructionsNoteAlthoughthefollowingpackinginstructionsusethesamenumberingsystemasusedintheIMDGcodeandtheUNmodelregulations,readersshouldbeawarethatsomeofthedetailsmaybedifferent.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/5824.1.4.1.Packinginstructionsconcerningtheuseofpackagings(exceptIBCsandlargepackagings)P001PACKINGINSTRUCTION(LIQUIDS)P001Thefollowingpackagingsareauthorisedprovidedthegeneralprovisionsof4.1.1and4.1.3aremet:CombinationpackagingsMaximumcapacity/Netmass(see4.1.3.3.)InnerpackagingsOuterpackagingsPackinggroupIPackinggroupIIPackinggroupIIIGlass10lPlastics30lMetal40lDrumssteel(1A2)250kg400kg400kgaluminium(1B2)250kg400kg400kgmetalotherthansteeloraluminium(1N2)250kg400kg400kgplastics(1H2)250kg400kg400kgplywood(1D)150kg400kg400kgfibre(1G)75kg400kg400kgBoxessteel(4A)250kg400kg400kgaluminium(4B)250kg400kg400kgnaturalwood(4C1,4C2)150kg400kg400kgplywood(4D)150kg400kg400kgreconstitutedwood(4F)75kg400kg400kgfibreboard(4G)75kg400kg400kgexpandedplastics(4H1)60kg60kg60kgsolidplastics(4H2)150kg400kg400kgJerricanssteel(3A2)120kg120kg120kgaluminium(3B2)120kg120kg120kgplastics(3H2)120kg120kg120kgMaximumcapacity/Netmass(see4.1.3.3.)PackinggroupIPackinggroupIIPackinggroupIIISinglepacka-gings:Drumssteel,non-removablehead(1A1)250l450l450lsteel,removablehead(1A2)250l(a)450l450laluminium,non-removablehead(1B1)250l450l450laluminium,removablehead(1B2)250l(a)450l450lmetalotherthansteeloraluminium,non-removablehead(1N1)250l450l450lmetalotherthansteeloraluminium,removablehead(1N2)250l(a)450l450lplastics,non-removablehead(1H1)250l450l450lplastics,removablehead(1H2)250l(a)450l450lJerricanssteel,non-removablehead(3A1)60l60l60lsteel,removablehead(3A2)60l(a)60l60laluminium,non-removablehead(3B1)60l60l60laluminium,removablehead(3B2)60l(a)60l60lplastics,non-removablehead(3H1)60l60l60lplastics,removablehead(3H2)60l(a)60l60lCompositepackagingsplasticsreceptaclewithoutersteeloraluminiumdrum(6HA1,6HB1)250l250l250lplasticsreceptaclewithouterfibre,plasticsorplywooddrum(6HG1,6HH1,6HD1)120l250l250lplasticsreceptaclewithoutersteeloraluminiumcrateorboxorplasticsreceptaclewithouterwooden,plywood,fibreboardorsolidplasticsbox(6HA2,6HB2,6HC,6HD2,6HG2or6HH2)60l60l60lglassreceptaclewithoutersteel,aluminium,fibreboard,plywood,solidplasticsorexpandedplasticsdrum(6PA1,6PB1,6PG1,6PD1,6PH1or6PH2)orwithoutersteeloraluminiumcrateorboxorwithouterwoodenorfibreboardboxorwithouterwickerworkhamper(6PA2,6PB2,6PC,6PG2or6PD2)60l60l60lOfficialJournaloftheEuropeanUnionEN26.1.2004L18/583P001PACKINGINSTRUCTION(LIQUIDS)P001Additionalrequirement:ForsubstancesofClass3,packinggroupIII,whichgiveoffsmallquantitiesofcarbondioxideornitrogen,thepackagingsshallbevented.Specialpackingprovisions:PP1ForUNNos1133,1210,1263and1866,substancesofpackinggroupsIIandIIImaybecarriedinquantitiesof5litresorlessperpackaginginmetalorplasticspackagingswhicharenotrequiredtomeettheperformancetestsofChapter6.1,providedthatsuchpackagingsarecarried:(a)inpalletisedloads,apalletboxorunitloaddevice,e.g.individualpackagingsplacedorstackedandsecuredbystrapping,shrinkorstretch-wrappingorothersuitablemeanstoapallet;or(b)asinnerpackagingsofcombinationpackagingswithamaximumnetmassof40kg.PP2ForUNNos3065and1170,woodenbarrels(2C1and2C2)maybeused.PP4ForUNNo1774,packagingsshallmeetthepackinggroupIIperformancelevel.PP5ForUNNo1204,packagingsshallbesoconstructedthatexplosionisnotpossiblebyreasonofincreasedinternalpressure.Gascylindersandgasreceptaclesshallnotbeusedforthesesubstances.PP6ForUNNos1851and3248,themaximumnetquantityperpackageshallbe5l.PP10ForUNNo1791,packinggroupII,thepackagingshallbevented.PP31ForUNNo1131,packagingsshallbehermeticallysealed.PP33ForUNNo1308,packinggroupsIandII,onlycombinationpackagingswithamaximumgrossmassof75kgallowed.SpecialpackingprovisionsspecifictoRIDandADRRR1ForUNNo1790withnotmorethan85%hydrofluoricacidandUNNo2031containingmorethan55%pureacid,thepermissibleperiodofuseforplasticsdrumsandjerricansusedassinglepackagingsshallbetwoyearsfromthedateofmanufacture.RR2ForUNNo1261,removableheadpackagingsarenotpermitted.(a)Onlysubstanceswithaviscosityofmorethan2680mm2/sareauthorised.P002PACKINGINSTRUCTION(SOLIDS)P002Thefollowingpackagingsareauthorisedprovidedthegeneralprovisionsof4.1.1and4.1.3aremet:CombinationpackagingsMaximumcapacity/Netmass(see4.1.3.3.)InnerpackagingsOuterpackagingsPackinggroupIPackinggroupIIPackinggroupIIIGlass10kgPlastics(a)50kgMetal50kgPaper(a)(b)(c)50kgFibre(a)(b)(c)50kgDrumssteel(1A2)400kg400kg400kgaluminium(1B2)400kg400kg400kgmetal,otherthansteeloraluminium(1N2)400kg400kg400kgplastics(1H2)400kg400kg400kgplywood(1D)400kg400kg400kgfibre(1G)400kg400kg400kgBoxessteel(4A)400kg400kg400kgaluminium(4B)400kg400kg400kgnaturalwood(4C1)250kg400kg400kgnaturalwoodwithsiftproofwalls(4C2)250kg400kg400kgplywood(4D)250kg400kg400kgreconstitutedwood(4F)125kg400kg400kgfibreboard(4G)125kg400kg400kgexpandedplastics(4H1)60kg60kg60kgsolidplastics(4H2)250kg400kg400kgJerricanssteel(3A2)120kg120kg120kgaluminium(3B2)120kg120kg120kgplastics(3H2)120kg120kg120kgOfficialJournaloftheEuropeanUnionEN26.1.2004L18/584P002PACKINGINSTRUCTION(SOLIDS)P002Singlepackagings:Maximumcapacity/Netmass(see4.1.3.3.)PackinggroupIPackinggroupIIPackinggroupIIIDrumssteel(1A1or1A2)(d)400kg400kg400kgaluminium(1B1or1B2)(d)400kg400kg400kgmetal,otherthansteeloraluminium(1N1or1N2)(d)400kg400kg400kgplastics(1H1or1H2)(d)400kg400kg400kgfibre(1G)(e)400kg400kg400kgplywood(1D)(e)400kg400kg400kgJerricanssteel(3A1or3A2)(d)120kg120kg120kgaluminium(3B1or3B2)(d)120kg120kg120kgplastics(3H1or3H2)(d)120kg120kg120kgBoxessteel(4A)(e)Notallowed400kg400kgaluminium(4B)(e)Notallowed400kg400kgnaturalwood(4C1)(e)Notallowed400kg400kgplywood(4D)(e)Notallowed400kg400kgreconstitutedwood(4F)(e)Notallowed400kg400kgnaturalwoodwithsift-proofwalls(4C2)(e)Notallowed400kg400kgfibreboard(4G)(e)Notallowed400kg400kgsolidplastics(4H2)(e)Notallowed400kg400kgBagsbags(5H3,5H4,5L3,5M2)(e)Notallowed50kg50kgCompositepackagingsplasticsreceptaclewithoutersteel,aluminium,plywood,fibreorplasticsdrum6HA1,6HB1,6HG1(e),6HD1(e)or6HH1400kg400kg400kgplasticsreceptaclewithoutersteeloraluminiumcrateorbox,woodenbox,plywoodbox,fibreboardboxorsolidplasticsbox6HA2,6HB2,6HC,6HD2(e),6HG2(e)or6HH275kg75kg75kgglassreceptaclewithoutersteel,aluminiumplywoodorfibredrum6PA1,6PB1,6PD1(e)or6PG1(e)orwithoutersteeloraluminiumcrateorboxorwithouterwooden,orfibreboardboxorwithouterwickerworkhamper6PA2,6PB2,6PC,6PD2(e)or6PG2(e)orwithoutersolidplasticsorexpandedplasticspackaging6PH2or6PH1(e)75kg75kg75kgSpecialpackingprovisions:PP6ForUNNo3249,themaximumnetmassperpackageshallbe5kg.PP7ForUNNo2000,celluloidmayalsobetransportedunpackedonpallets,wrappedinplasticfilmandsecuredbyappropriatemeans,suchassteelbandsasafullloadinclosedvehiclesorcontainers.Eachpalletshallnotexceed1000kg.PP8ForUNNo2002,packagingsshallbesoconstructedthatexplosionisnotpossiblebyreasonofincreasedinternalpressure.Gascylindersandgasreceptaclesshallnotbeusedforthesesubstances.PP9ForUNNos3175,3243and3244,packagingsshallconformtoadesigntypethathaspassedaleakproofnesstestatthepackinggroupIIperformancelevel.PP11ForUNNo1309,packinggroupIII,andUNNo1362,5H1,5L1and5M1bagsareallowediftheyareoverpackedinplasticbagsorarewrappedinshrinkorstretchwraponpallets.PP12ForUNNos1361,2213andUNNo3077,5H1,5L1and5M1bagsareallowedwhencarriedinclosedvehiclesorcontainers.PP13ForarticlesclassifiedunderUNNo2870,onlycombinationpackagingsmeetingthepackinggroupIperformancelevelareauthorised.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/585P002PACKINGINSTRUCTION(SOLIDS)P002PP14ForUNNos2211,2698and3314,packagingsarenotrequiredtomeettheperformancetestsinChapter6.1.PP15ForUNNos1324and2623,packagingsshallmeetthepackinggroupIIIperformancelevel.PP20ForUNNo2217,anysift-proof,tearproofreceptaclemaybeused.PP30ForUNNo2471,paperorfibreinnerpackagingsarenotpermitted.PP34ForUNNo2969(aswholebeans),5H1,5L1and5M1bagsarepermitted.PP37ForUNNos2590and2212,5M1bagsarepermitted.Packagesshallbecarriedinclosedvehiclesorcontainersorasstretchorshrink-wrappedunitloads.PP38ForUNNo1309,packinggroupII,bagsarepermittedonlyinclosedvehiclesorcontainers.(a)Theseinnerpackagingsshallbesift-proof.(b)Theseinnerpackagingsshallnotbeusedwhenthesubstancesbeingcarriedmaybecomeliquidduringcarriage(see4.1.3.4).(c)ThesepackagingsshallnotbeusedforsubstancesofpackinggroupIthatmaybecomeliquidduringcarriage(see4.1.3.4).(d)Thesepackagingsshallnotbeusedwhensubstancesbeingcarriedmaybecomeliquidduringcarriage(see4.1.3.4).(e)TheseinnerpackagingsshallnotbeusedforsubstancesofpackinggroupI.P003PACKINGINSTRUCTIONP003Dangerousgoodsshallbeplacedinsuitableouterpackagings.Thepackagingsshallmeettheprovisionsof4.1.1.1,4.1.1.2,4.1.1.4,4.1.1.8and4.1.3andbesodesignedthattheymeettheconstructionrequirementsof6.1.4.Outerpackagingsconstructedofsuitablematerialofadequatestrengthanddesigninrelationtothepackagingcapacityanditsintendeduseshallbeused.Wherethispackinginstructionisusedforthetransportofarticlesorinnerpackagingsofcombinationpackagings,thepackagingshallbedesignedandconstructedtopreventinadvertentdischargeofarticlesduringnormalconditionsofcarriage.Specialpackingprovisions:PP16ForUNNo2800,batteriesshallbeprotectedfromshortcircuitsandshallbesecurelypackedinstrongouterpackagings.Notes1.Non-spillablebatterieswhichareanintegralpartof,andnecessaryfor,theoperationofmechanicalorelectronicequipmentshallbesecurelyfastenedinthebatteryholderontheequipmentandprotectedinsuchamannerastopreventdamageandshortcircuits.2.Forusedbatteries(UNNo2800),seeP801a.PP19ForUNNos1364and1365,carriageasbalesisauthorised.PP20ForUNNos1363,1386,1408and2793anysift-proof,tearproofreceptaclemaybeused.PP32UNNos2857and3358maybecarriedunpackaged,incratesorinappropriateoverpacks.P099PACKINGINSTRUCTIONP099Onlypackagingswhichareapprovedbythecompetentauthoritymaybeused.P101PACKINGINSTRUCTIONP101Onlypackagingswhichareapprovedbythecompetentauthorityofthecountryoforiginmaybeused.IfthecountryoforiginisnotaMemberState,thepackagingshallbeapprovedbythecompetentauthorityofthefirstMemberStatereachedbytheconsignment.TheState'sdistinguishingsignformotorvehiclesininternationaltrafficofthecountryforwhichtheauthorityacts,shallbemarkedonthetransportdocumentsasfollows:‘Packagingapprovedbythecompetentauthorityof...’(see5.4.1.2.1(c))OfficialJournaloftheEuropeanUnionEN26.1.2004L18/586P110(a)PACKINGINSTRUCTIONP110(a)RESERVEDNoteThispackinginstructionintheUNmodelregulationsisnotadmittedforcarriageunderthisDirective.P110(b)PACKINGINSTRUCTIONP110(b)Thefollowingpackagingsareauthorised,providedthegeneralpackingprovisionsof4.1.1,4.1.3andspecialpackingprovisionsof4.1.5aremet:InnerpackagingsandarrangementsIntermediatepackagingsandarrange-mentsOuterpackagingsandarrangementsReceptaclesmetalwoodrubber,conductiveplastics,conductiveBagsrubber,conductiveplastics,conductiveDividingpartitionsmetalwoodplasticsfibreboardBoxesnaturalwood,sift-proofwall(4C2)plywood(4D)reconstitutedwood(4F)Specialpackingprovision:PP42ForUNNos0074,0113,0114,0129,0130,0135and0224,thefollowingconditionsshallbemet:(a)innerpackagingsshallnotcontainmorethan50gofexplosivesubstance(quantitycorrespondingtodrysubstance);(b)compartmentsbetweendividingpartitionsshallnotcontainmorethanoneinnerpackaging,firmlyfitted;and(c)theouterpackagingmaybepartitionedintoupto25compartments.P111PACKINGINSTRUCTIONP111Thefollowingpackagingsareauthorised,providedthegeneralpackingprovisionsof4.1.1,4.1.3andspecialpackingprovisionsof4.1.5aremet:InnerpackagingsandarrangementsIntermediatepackagingsandarrange-mentsOuterpackagingsandarrangementsBagspaper,waterproofedplasticstextile,rubberisedNotnecessaryBoxessteel(4A)aluminium(4B)naturalwood,ordinary(4C1)naturalwood,sift-proof(4C2)plywood(4D)reconstitutedwood(4F)fibreboard(4G)plastics,expanded(4H1)plastics,solid(4H2)Sheetsplasticstextile,rubberisedDrumssteel,removablehead(1A2)aluminium,removablehead(1B2)plywood(1D)fibreboard(1G)plastics,removablehead(1H2)Specialpackingprovision:PP43ForUNNo0159,innerpackagingsarenotrequiredwhenmetal(1A2or1B2)orplastics(1H2)drumsareusedasouterpackagings.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/587P112(a)PACKINGINSTRUCTIONP112(a)(Solidwetted,1.1D)Thefollowingpackagingsareauthorised,providedthegeneralpackingprovisionsof4.1.1,4.1.3andspecialpackingprovisionsof4.1.5aremet:InnerpackagingsandarrangementsIntermediatepackagingsandarrange-mentsOuterpackagingsandarrangementsBagspaper,multiwall,waterresistantplasticstextiletextile,rubberisedwovenplasticsReceptaclesmetalplasticsBagsplasticstextile,plasticcoatedorlinedReceptaclesmetalplasticsBoxessteel(4A)aluminium(4B)naturalwood,ordinary(4C1)naturalwood,sift-proof(4C2)plywood(4D)reconstitutedwood(4F)fibreboard(4G)plastics,expanded(4H1)plastics,solid(4H2)Drumssteel,removablehead(1A2)aluminium,removablehead(1B2)fibre(1G)plastics,removablehead(1H2)Additionalrequirement:Intermediatepackagingsarenotrequiredifleakproofremovableheaddrumsareusedastheouterpackaging.Specialpackingprovisions:PP26ForUNNos0004,0076,0078,0154,0219and0394,packagingsshallbeleadfree.PP45ForUNNos0072and0226,intermediatepackagingsarenotrequired.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/588P112(b)PACKINGINSTRUCTIONP112(b)(Soliddry,otherthanpowder1.1D)Thefollowingpackagingsareauthorised,providedthegeneralpackingprovisionsof4.1.1,4.1.3andspecialpackingprovisionsof4.1.5aremet:InnerpackagingsandarrangementsIntermediatepackagingsandarrange-mentsOuterpackagingsandarrangementsBagspaper,kraftpaper,multiwall,waterresistantplasticstextiletextile,rubberisedwovenplasticsBags(forUNNo0150only)plasticstextile,plasticcoatedorlinedBagswovenplastics,sift-proof(5H2)wovenplastics,water-resistant(5H3)plastics,film(5H4)textile,sift-proof(5L2)ortextile,waterresistant(5L3)paper,multiwall,waterresistant(5M2)Boxessteel(4A)aluminium(4B)naturalwood,ordinary(4C1)naturalwood,sift-proof(4C2)plywood(4D)reconstitutedwood(4F)fibreboard(4G)plastics,expanded(4H1)plastics,solid(4H2)Drumssteel,removablehead(1A2)aluminium,removablehead(1B2)fibre(1G)plastics,removablehead(1H2)Specialpackingprovisions:PP26ForUNNos0004,0076,0078,0154,0216,0219and0386,packagingsshallbeleadfree.PP46ForUNNos0209,bags,sift-proof(5H2)arerecommendedforflakeorprilledTNTinthedrystateandamaximumnetmassof30kg.PP47ForUNNos0222and0223,innerpackagingsarenotrequiredwhentheouterpackagingisabag.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/589P112(c)PACKINGINSTRUCTIONP112(c)(Soliddrypowder1.1D)Thefollowingpackagingsareauthorised,providedthegeneralpackingprovisionsof4.1.1,4.1.3andspecialpackingprovisionsof4.1.5aremet:InnerpackagingsandarrangementsIntermediatepackagingsandarrange-mentsOuterpackagingsandarrangementsBagspaper,multiwall,waterresistantplasticswovenplasticsReceptaclesfibreboardmetalplasticswoodBagspaper,multiwall,waterresistantwithinnerliningplasticsReceptaclesmetalplasticsBoxessteel(4A)naturalwood,ordinary(4C1)naturalwood,sift-proof(4C2)plywood(4D)reconstitutedwood(4F)fibreboard(4G)plastics,solid(4H2)Drumssteel,removablehead(1A2)aluminium,removablehead(1B2)fibre(1G)Additionalrequirements:1.Innerpackagingsarenotrequiredifdrumsareusedastheouterpackaging.2.Thepackagingshallbesift-proof.Specialpackingprovisions:PP26ForUNNos0004,0076,0078,0154,0216,0219and0386,packagingsshallbeleadfree.PP46ForUNNo0209,bags,sift-proof(5H2)arerecommendedforflakeorprilledTNTinthedrystateandamaximumnetmassof30kg.PP48ForUNNo0504,metalpackagingsshallnotbeused.P113PACKINGINSTRUCTIONP113Thefollowingpackagingsareauthorised,providedthegeneralpackingprovisionsof4.1.1,4.1.3andspecialpackingprovisionsof4.1.5aremet:InnerpackagingsandarrangementsIntermediatepackagingsandarrange-mentsOuterpackagingsandarrangementsBagspaperplasticstextile,rubberisedReceptaclesfibreboardmetalplasticswoodNotnecessaryBoxessteel(4A)naturalwood,ordinary(4C1)naturalwood,sift-proofwalls(4C2)plywood(4D)reconstitutedwood(4F)fibreboard(4G)plastics,solid(4H2)Drumssteel,removablehead(1A2)aluminium,removablehead(1B2)fibre(1G)Additionalrequirement:Thepackagingshallbesift-proof.Specialpackingprovisions:PP49ForUNNos0094and0305,nomorethan50gofsubstanceshallbepackedinaninnerpackaging.PP50ForUNNo0027,innerpackagingsarenotnecessarywhendrumsareusedasouterpackagings.PP51ForUNNo0028,paperkraftorwaxedpapersheetsmaybeusedasinnerpackagings.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/590P114(a)PACKINGINSTRUCTIONP114(a)(Solidwetted)Thefollowingpackagingsareauthorised,providedthegeneralpackingprovisionsof4.1.1,4.1.3andspecialpackingprovisionsof4.1.5aremet:InnerpackagingsandarrangementsIntermediatepackagingsandarrange-mentsOuterpackagingsandarrangementsBagsplasticstextilewovenplasticsReceptaclesmetalplasticsBagsplasticstextile,plasticcoatedorlinedReceptaclesmetalplasticsBoxessteel(4A)naturalwood,ordinary(4C1)naturalwood,sift-proofwalls(4C2)plywood(4D)reconstitutedwood(4F)fibreboard(4G)plastics,solid(4H2)Drumssteel,removablehead(1A2)aluminium,removablehead(1B2)plywood(1D)fibre(1G)plastics,removablehead(1H2)Additionalrequirement:Intermediatepackagingsarenotrequiredifleakproofremovableheaddrumsareusedasouterpackagings.Specialpackingprovisions:PP26ForUNNos0077,0132,0234,0235and0236,packagingsshallbeleadfree.PP43ForUNNo0342,innerpackagingsarenotrequiredwhenmetal(1A2or1B2)orplastics(1H2)drumsareusedasouterpackagings.P114(b)PACKINGINSTRUCTIONP114(b)(Soliddry)Thefollowingpackagingsareauthorised,providedthegeneralpackingprovisionsof4.1.1,4.1.3andspecialpackingprovisionsof4.1.5aremet:InnerpackagingsandarrangementsIntermediatepackagingsandarrange-mentsOuterpackagingsandarrangementsBagspaper,kraftplasticstextile,sift-proofwovenplastics,sift-proofReceptaclesfibreboardmetalpaperplasticswovenplastics,sift-proofNotnecessaryBoxesnaturalwood,ordinary(4C1)naturalwood,sift-proofwalls(4C2)plywood(4D)reconstitutedwood(4F)fibreboard(4G)Drumssteel,removablehead(1A2)aluminium,removablehead(1B2)plywood(1D)fibre(1G)plastics,removablehead(1H2)Specialpackingprovisions:PP26ForUNNos0077,0132,0234,0235and0236,packagingsshallbeleadfree.PP50ForUNNos0160and0161,innerpackagingsarenotrequiredifdrumsareusedasouterpackagings.PP52ForUNNos0160and0161,whenmetaldrums(1A2or1B2)areusedasouterpackagings,metalpackagingsshallbesoconstructedthattheriskofexplosion,byreasonofincreasedinternalpressurefrominternalorexternalcausesisprevented.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/591P115PACKINGINSTRUCTIONP115Thefollowingpackagingsareauthorised,providedthegeneralpackingprovisionsof4.1.1,4.1.3andspecialpackingprovisionsof4.1.5aremet:InnerpackagingsandarrangementsIntermediatepackagingsandarrange-mentsOuterpackagingsandarrangementsReceptaclesplasticsBagsplasticsinmetalreceptaclesDrumsmetalBoxesnaturalwood,ordinary(4C1)naturalwood,sift-proofwalls(4C2)plywood(4D)reconstitutedwood(4F)Drumssteel,removablehead(1A2)aluminium,removablehead(1B2)plywood(1D)fibre(1G)Specialpackingprovisions:PP45ForUNNo0144,intermediatepackagingsarenotrequired.ForUNNos0075,0143,0495and0497,whenboxesareusedasouterpackagings,innerpackagingsshallhavetapedscrewcapclosuresandbenotmorethan5litrescapacityeach.Innerpackagingsshallbesurroundedwithnon-combustibleabsorbentcushioningmaterials.Theamountofabsorbentcushioningmaterialshallbesufficienttoabsorbtheliquidcontents.Metalreceptaclesshallbecushionedfromeachother.Netmassofpropellantislimitedto30kgforeachpackagewhenouterpackagingsareboxes.PP54ForUNNos0075,0143,0495and0497,whendrumsareusedasouterpackagingsandwhenintermediatepackagingsaredrums,theyshallbesurroundedwithnon-combustiblecushioningmaterialinaquantitysufficienttoabsorbtheliquidcontents.Acompositepackagingconsistingofaplasticsreceptacleinametaldrummaybeusedinsteadoftheinnerandintermediatepackagings.Thenetvolumeofpropellantineachpackageshallnotexceed120litres.PP55ForUNNo0144,absorbentcushioningmaterialshallbeinserted.PP56ForUNNo0144,metalreceptaclesmaybeusedasinnerpackagings.PP57ForUNNos0075,0143,0495and0497,bagsshallbeusedasintermediatepackagingswhenboxesareusedasouterpackagings.PP58ForUNNos0075,0143,0495and0497,drumsshallbeusedasintermediatepackagingswhendrumsareusedasouterpackagings.PP59ForUNNo0144,fibreboardboxes(4G)maybeusedasouterpackagings.PP60ForUNNo0144,aluminiumdrums,removablehead(1B2)shallnotbeused.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/592P116PACKINGINSTRUCTIONP116Thefollowingpackagingsareauthorised,providedthegeneralpackingprovisionsof4.1.1,4.1.3andspecialpackingprovisionsof4.1.5aremet:InnerpackagingsandarrangementsIntermediatepackagingsandarrange-mentsOuterpackagingsandarrangementsBagspaper,waterandoilresistantplasticstextile,plasticcoatedorlinedwovenplastics,sift-proofReceptaclesfibreboard,waterresistantmetalplasticswood,sift-proofSheetspaper,waterresistantpaper,waxedplasticsNotnecessaryBagswovenplastics(5H1)paper,multiwall,waterresistant(5M2)plastics,film(5H4)textile,sift-proof(5L2)textile,waterresistant(5L3)Boxessteel(4A)aluminium(4B)naturalwood,ordinary(4C1)naturalwood,sift-proofwalls(4C2)plywood(4D)reconstitutedwood(4F)fibreboard(4G)plastics,solid(4H2)Drumssteel,removablehead(1A2)aluminium,removablehead(1B2)fibre(1G)plastics,removablehead(1H2)Jerricanssteel,removablehead(3A2)plastics,removablehead(3H2)Specialpackingprovisions:PP61ForUNNos0082,0241,0331and0332,innerpackagingsarenotrequiredifleakproofremovableheaddrumsareusedasouterpackagings.PP62ForUNNos0082,0241,0331and0332,innerpackagingsarenotrequiredwhentheexplosiveiscontainedinamaterialimpervioustoliquid.ForUNNo0081,innerpackagingsarenotrequiredwhencontainedinrigidplasticwhichisimpervioustonitricesters.PP64ForUNNo0331,innerpackagingsarenotrequiredwhenbags(5H2),(5H3)or(5H4)areusedasouterpackagings.PP65ForUNNos0082,0241,0331and0332,bags(5H2or5H3)maybeusedasouterpackagings.PP66ForUNNo0081,bagsshallnotbeusedasouterpackagings.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/593P130PACKINGINSTRUCTIONP130Thefollowingpackagingsareauthorised,providedthegeneralpackingprovisionsof4.1.1,4.1.3andspecialpackingprovisionsof4.1.5aremet:InnerpackagingsandarrangementsIntermediatepackagingsandarrange-mentsOuterpackagingsandarrangementsNotnecessaryNotnecessaryBoxessteel(4A)aluminium(4B)naturalwood,ordinary(4C1)naturalwood,sift-proofwalls(4C2)plywood(4D)reconstitutedwood(4F)fibreboard(4G)plastics,expanded(4H1)plastics,solid(4H2)Drumssteel,removablehead(1A2)aluminium,removablehead(1B2)fibre(1G)plastics,removablehead(1H2)Specialpackingprovision:PP67ThefollowingappliestoUNNos0006,0009,0010,0015,0016,0018,0019,0034,0035,0038,0039,0048,0056,0137,0138,0168,0169,0171,0181,0182,0183,0186,0221,0243,0244,0245,0246,0254,0280,0281,0286,0287,0297,0299,0300,0301,0303,0321,0328,0329,0344,0345,0346,0347,0362,0363,0370,0412,0424,0425,0434,0435,0436,0437,0438,0451,0488and0502:largeandrobustexplosivesarticles,normallyintendedformilitaryuse,withouttheirmeansofinitiationorwiththeirmeansofinitiationcontainingatleasttwoeffectiveprotectivefeatures,maybecarriedunpackaged.Whensucharticleshavepropellingchargesorareself-propelled,theirignitionsystemsshallbeprotectedagainststimuliencounteredduringnormalconditionsofcarriage.AnegativeresultinTestSeries4onanunpackagedarticleindicatesthatthearticlecanbeconsideredforcarriageunpackaged.Suchunpackagedarticlesmaybefixedtocradlesorcontainedincratesorothersuitablehandlingdevices.P131PACKINGINSTRUCTIONP131Thefollowingpackagingsareauthorised,providedthegeneralpackingprovisionsof4.1.1,4.1.3andspecialpackingprovisionsof4.1.5aremet:InnerpackagingsandarrangementsIntermediatepackagingsandarrange-mentsOuterpackagingsandarrangementsBagspaperplasticsReceptaclesfibreboardmetalplasticswoodReelsNotnecessaryBoxessteel(4A)aluminium(4B)naturalwood,ordinary(4C1)naturalwood,sift-proofwalls(4C2)plywood(4D)reconstitutedwood(4F)fibreboard(4G)Drumssteel,removablehead(1A2)aluminium,removablehead(1B2)fibre(1G)plastics,removablehead(1H2)Specialpackingprovision:PP68ForUNNos0029,0267and0455,bagsandreelsshallnotbeusedasinnerpackagings.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/594P132(a)PACKINGINSTRUCTIONP132(a)(Articlesconsistingofclosedmetal,plasticsorfibreboardcasingsthatcontainadetonatingexplosive,orconsistingofplastics-bondeddetonatingexplosives)Thefollowingpackagingsareauthorised,providedthegeneralpackingprovisionsof4.1.1,4.1.3andspecialpackingprovisionsof4.1.5aremet:InnerpackagingsandarrangementsIntermediatepackagingsandarrange-mentsOuterpackagingsandarrangementsNotnecessaryNotnecessaryBoxessteel(4A)aluminium(4B)wood,natural,ordinary(4C1)wood,natural,sift-proofwalls(4C2)plywood(4D)reconstitutedwood(4F)fibreboard(4G)plastics,solid(4H2)P132(b)PACKINGINSTRUCTIONP132(b)(Articleswithoutclosedcasings)Thefollowingpackagingsareauthorised,providedthegeneralpackingprovisionsof4.1.1,4.1.3andspecialpackingprovisionsof4.1.5aremet:InnerpackagingsandarrangementsIntermediatepackagingsandarrange-mentsOuterpackagingsandarrangementsReceptaclesfibreboardmetalplasticsSheetspaperplasticsNotnecessaryBoxessteel(4A)aluminium(4B)naturalwood,ordinary(4C1)naturalwood,sift-proofwalls(4C2)plywood(4D)reconstitutedwood(4F)fibreboard(4G)plastics,solid(4H2)OfficialJournaloftheEuropeanUnionEN26.1.2004L18/595P133PACKINGINSTRUCTIONP133Thefollowingpackagingsareauthorised,providedthegeneralpackingprovisionsof4.1.1,4.1.3andspecialpackingprovisionsof4.1.5aremet:InnerpackagingsandarrangementsIntermediatepackagingsandarrange-mentsOuterpackagingsandarrangementsReceptaclesfibreboardmetalplasticswoodTrays,fittedwithdividingpartitionsfibreboardplasticswoodReceptaclesfibreboardmetalplasticswoodBoxessteel(4A)aluminium(4B)naturalwood,ordinary(4C1)naturalwood,sift-proofwalls(4C2)plywood(4D)reconstitutedwood(4F)fibreboard(4G)plastics,solid(4H2)Additionalrequirement:Receptaclesareonlyrequiredasintermediatepackagingswhentheinnerpackagingsaretrays.Specialpackingprovision:PP69ForUNNos0043,0212,0225,0268and0306,traysshallnotbeusedasinnerpackagings.P134PACKINGINSTRUCTIONP134Thefollowingpackagingsareauthorised,providedthegeneralpackingprovisionsof4.1.1,4.1.3andspecialpackingprovisionsof4.1.5aremet:InnerpackagingsandarrangementsIntermediatepackagingsandarrange-mentsOuterpackagingsandarrangementsBagswaterresistantReceptaclesfibreboardmetalplasticswoodSheetsfibreboard,corrugatedTubesfibreboardNotnecessaryBoxessteel(4A)aluminium(4B)naturalwood,ordinary(4C1)naturalwood,sift-proofwalls(4C2)plywood(4D)reconstitutedwood(4F)fibreboard(4G)plastics,expanded(4H1)plastics,solid(4H2)Drumssteel,removablehead(1A2)aluminium,removablehead(1B2)OfficialJournaloftheEuropeanUnionEN26.1.2004L18/596P135PACKINGINSTRUCTIONP135Thefollowingpackagingsareauthorised,providedthegeneralpackingprovisionsof4.1.1,4.1.3andspecialpackingprovisionsof4.1.5aremet:InnerpackagingsandarrangementsIntermediatepackagingsandarrange-mentsOuterpackagingsandarrangementsBagspaperplasticsReceptaclesfibreboardmetalplasticswoodSheetspaperplasticsNotnecessaryBoxessteel(4A)aluminium(4B)naturalwood,ordinary(4C1)naturalwood,sift-proofwalls(4C2)plywood(4D)reconstitutedwood(4F)fibreboard(4G)plastics,expanded(4H1)plastics,solid(4H2)Drumssteel,removablehead(1A2)aluminium,removablehead(1B2)fibre(1G)plastics,removablehead(1H2)P136PACKINGINSTRUCTIONP136Thefollowingpackagingsareauthorised,providedthegeneralpackingprovisionsof4.1.1,4.1.3andspecialpackingprovisionsof4.1.5aremet:InnerpackagingsandarrangementsIntermediatepackagingsandarrange-mentsOuterpackagingsandarrangementsBagsplasticstextileBoxesfibreboardplasticswoodDividingpartitionsintheouterpackagingsNotnecessaryBoxessteel(4A)aluminium(4B)naturalwood,ordinary(4C1)naturalwood,sift-proofwalls(4C2)plywood(4D)reconstitutedwood(4F)fibreboard(4G)plastics,solid(4H2)Drumssteel,removablehead(1A2)aluminium,removablehead(1B2)fibre(1G)plastics,removablehead(1H2)OfficialJournaloftheEuropeanUnionEN26.1.2004L18/597P137PACKINGINSTRUCTIONP137Thefollowingpackagingsareauthorised,providedthegeneralpackingprovisionsof4.1.1,4.1.3andspecialpackingprovisionsof4.1.5aremet:InnerpackagingsandarrangementsIntermediatepackagingsandarrange-mentsOuterpackagingsandarrangementsBagsplasticsBoxesfibreboardTubesfibreboardmetalplasticsDividingpartitionsintheouterpackagingsNotnecessaryBoxessteel(4A)aluminium(4B)naturalwood,ordinary(4C1)naturalwood,sift-proofwalls(4C2)plywood(4D)reconstitutedwood(4F)fibreboard(4G)Drumssteel,removablehead(1A2)aluminium,removablehead(1B2)plywood(1D)fibre(1G)plastics,removablehead(1H2)Specialpackingprovision:PP70ForUNNos0059,0439,0440and0441,whentheshapedchargesarepackedsingly,theconicalcavityshallfacedownwardsandthepackagemarked‘THISSIDEUP’.Whentheshapedchargesarepackedinpairs,theconicalcavitiesshallfaceinwardstominimisethejettingeffectintheeventofaccidentalinitiation.P138PACKINGINSTRUCTIONP138Thefollowingpackagingsareauthorised,providedthegeneralpackingprovisionsof4.1.1,4.1.3andspecialpackingprovisionsof4.1.5aremet:InnerpackagingsandarrangementsIntermediatepackagingsandarrange-mentsOuterpackagingsandarrangementsBagsplasticsNotnecessaryBoxessteel(4A)aluminium(4B)naturalwood,ordinary(4C1)naturalwood,sift-proofwalls(4C2)plywood(4D)reconstitutedwood(4F)fibreboard(4G)plastics,solid(4H2)Drumssteel,removablehead(1A2)aluminium,removablehead(1B2)Additionalrequirement:Iftheendsofthearticlesaresealed,innerpackagingsarenotnecessary.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/598P139PACKINGINSTRUCTIONP139Thefollowingpackagingsareauthorised,providedthegeneralpackingprovisionsof4.1.1,4.1.3andspecialpackingprovisionsof4.1.5aremet:InnerpackagingsandarrangementsIntermediatepackagingsandarrange-mentsOuterpackagingsandarrangementsBagsplasticsReceptaclesfibreboardmetalplasticswoodReelsSheetspaperplasticsNotnecessaryBoxessteel(4A)aluminium(4B)naturalwood,ordinary(4C1)naturalwood,sift-proofwalls(4C2)plywood(4D)reconstitutedwood(4F)fibreboard(4G)plastics,solid(4H2)Drumssteel,removablehead(1A2)aluminium,removablehead(1B2)plywood(1D)fibre(1G)plastics,removablehead(1H2)Specialpackingprovisions:PP71ForUNNos0065,0102,0104,0289and0290,theendsofthedetonatingcordshallbesealed,forexample,byaplugfirmlyfixedsothattheexplosivecannotescape.Theendsofflexibledetonatingcordshallbefastenedsecurely.PP72ForUNNos0065and0289,innerpackagingsarenotrequiredwhentheyareincoils.P140PACKINGINSTRUCTIONP140Thefollowingpackagingsareauthorised,providedthegeneralpackingprovisionsof4.1.1,4.1.3andspecialpackingprovisionsof4.1.5aremet:InnerpackagingsandarrangementsIntermediatepackagingsandarrange-mentsOuterpackagingsandarrangementsBagsplasticsReelsSheetspaper,kraftplasticsNotnecessaryBoxessteel(4A)aluminium(4B)naturalwood,ordinary(4C1)naturalwood,sift-proofwalls(4C2)plywood(4D)reconstitutedwood(4F)fibreboard(4G)plastics,solid(4H2)Drumssteel,removablehead(1A2)aluminium,removablehead(1B2)fibre(1G)Specialpackingprovisions:PP73ForUNNo0105,noinnerpackagingsarerequirediftheendsaresealed.PP74ForUNNo0101,thepackagingshallbesift-proofexceptwhenthefuseiscoveredbyapapertubeandbothendsofthetubearecoveredwithremovablecaps.PP75ForUNNo0101,steeloraluminiumboxesordrumsshallnotbeused.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/599P141PACKINGINSTRUCTIONP141Thefollowingpackagingsareauthorised,providedthegeneralpackingprovisionsof4.1.1,4.1.3andspecialpackingprovisionsof4.1.5aremet:InnerpackagingsandarrangementsIntermediatepackagingsandarrange-mentsOuterpackagingsandarrangementsReceptaclesfibreboardmetalplasticswoodTrays,fittedwithdividingpartitionsplasticswoodDividingpartitionsintheouterpackagingsNotnecessaryBoxessteel(4A)aluminium(4B)naturalwood,ordinary(4C1)naturalwood,sift-proofwalls(4C2)plywood(4D)reconstitutedwood(4F)fibreboard(4G)plastics,solid(4H2)Drumssteel,removablehead(1A2)aluminium,removablehead(1B2)fibre(1G)plastics,removablehead(1H2)P142PACKINGINSTRUCTIONP142Thefollowingpackagingsareauthorised,providedthegeneralpackingprovisionsof4.1.1,4.1.3andspecialpackingprovisionsof4.1.5aremet:InnerpackagingsandarrangementsIntermediatepackagingsandarrange-mentsOuterpackagingsandarrangementsBagspaperplasticsReceptaclesfibreboardmetalplasticswoodSheetspaperTrays,fittedwithdividingpartitionsplasticsNotnecessaryBoxessteel(4A)aluminium(4B)naturalwood,ordinary(4C1)naturalwood,sift-proofwalls(4C2)plywood(4D)reconstitutedwood(4F)fibreboard(4G)plastics,solid(4H2)Drumssteel,removablehead(1A2)aluminium,removablehead(1B2)fibre(1G)plastics,removablehead(1H2)OfficialJournaloftheEuropeanUnionEN26.1.2004L18/600P143PACKINGINSTRUCTIONP143Thefollowingpackagingsareauthorised,providedthegeneralpackingprovisionsof4.1.1,4.1.3andspecialpackingprovisionsof4.1.5aremet:InnerpackagingsandarrangementsIntermediatepackagingsandarrange-mentsOuterpackagingsandarrangementsBagspaper,kraftplasticstextiletextile,rubberisedReceptaclesfibreboardmetalplasticsTrays,fittedwithdividingpartitionsplasticswoodNotnecessaryBoxessteel(4A)aluminium(4B)naturalwood,ordinary(4C1)naturalwood,sift-proofwalls(4C2)plywood(4D)reconstitutedwood(4F)fibreboard(4G)plastics,solid(4H2)Drumssteel,removablehead(1A2)aluminium,removablehead(1B2)plywood(1D)fibre(1G)plastics,removablehead(1H2)Additionalrequirement:Insteadoftheaboveinnerandouterpackagings,compositepackagings(6HH2)(plasticsreceptaclewithoutersolidplasticsbox)maybeused.Specialpackingprovision:PP76ForUNNos0271,0272,0415and0491,whenmetalpackagingsareused,metalpackagingsshallbesoconstructedthattheriskofexplosion,byreasonofincreaseininternalpressurefrominternalorexternalcausesisprevented.P144PACKINGINSTRUCTIONP144Thefollowingpackagingsareauthorised,providedthegeneralpackingprovisionsof4.1.1,4.1.3andspecialpackingprovisionsof4.1.5aremet:InnerpackagingsandarrangementsIntermediatepackagingsandarrange-mentsOuterpackagingsandarrangementsReceptaclesfibreboardmetalplasticsDividingpartitionsintheouterpackagingsNotnecessaryBoxessteel(4A)aluminium(4B)naturalwood,ordinarywithmetalliner(4C1)plywood(4D)withmetallinerreconstitutedwood(4F)withmetallinerplastics,expanded(4H1)Specialpackingprovision:PP77ForUNNos0248and0249,packagingsshallbeprotectedagainsttheingressofwater.Whenwater-activatedcontrivancesaretransportedunpackaged,theyshallbeprovidedwithatleasttwoindependentprotectivefeatureswhichpreventtheingressofwater.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/601P200PACKINGINSTRUCTIONP200Typeofpackagings:Cylinder,tubes,pressuredrumsandbundlesofcylindersCylinder,tubes,pressuredrumsandbundlesofcylindersareauthorisedprovidedthespecialpackingprovisionsof4.1.6andtheprovisionslistedbelowunderA,B,CandDaremet:A.General1)Receptaclesshallbesoclosedandleakproofastopreventescapeofthegases.B.Testpressureandfillingratios2)Theminimumtestpressurerequiredforis1MPa(10bar).3)Forcompressedgaseshavingacriticaltemperaturebelow–50°Ctheinternalpressure(testpressure)tobeappliedinthehydraulicpressuretestshallbeatleastoneandone-halftimesthefillingpressureat15°C.4)Forcompressedgaseshavingacriticaltemperatureof–50°Coraboveandforliquefiedgaseshavingacriticaltemperaturebelow70°C,thedegreeoffillingshallbesuchthattheinternalpressureat65°Cdoesnotexceedthetestpressureofthereceptacles.Forgasesandgasmixtureswithinsufficientdata,themaximumfillingdegree(FD)shallbedeterminedasfollows:FD=8,5×10-4×dg×PewhereFD=maximumfillingdegree(inkg.l-1)dg=gasdensity(at15°C,1bar)(inkg/m3)Pe=minimumtestpressure(inbar)Ifthedensityofthegasisunknown,themaximumfillingdegreeshallbedeterminedasfollows:FD¼Pe(cid:2)MM(cid:2)10(cid:1)3R(cid:2)338whereFD=maximumfillingdegree(inkg.l-1)Pe=minimumtestpressure(inbar)MM=molecularmass(ing.mol-1)R=8,31451×10-2bar.l.mol-1.K-1(gasconstant)(Forgasmixturestheaveragemolecularmassistobetaken,takingintoaccounttheconcentrationsofthevariouscomponents).5)Forliquefiedgaseshavingacriticaltemperatureof70°Corabove,themaximummassofcontentsperlitreofcapacity(degreeoffilling)equals0,95timesthedensityoftheliquidphaseat50°C(inkg/l);inaddition,thevapourphaseshallnotdisappearbelow60°C.Thetestpressurewillbeatleastequaltothevapourpressureoftheliquidat70°C,minus100kPa(1bar).Forpuregaseswithinsufficientdatathemaximumfillingdegreeshallbedeterminedasfollows:FD=(0,0032×BP–0,24)×d1whereFD=maximumfillingdegree(inkg.l-1)BP=boilingpoint(inKelvin)d1=densityoftheliquidatboilingpoint(inkg.l)-16)ForUNNo1001acetylene,dissolved,onceequilibriumhasbeenachievedat15°C,thefillingpressureshallnotexceedthevalueprescribedbythecompetentauthorityfortheporousmass.Thequantityofsolventandthequantityofacetyleneshalllikewisecorrespondtothefiguresspecifiedintheapproval.7)Othertestpressuresanddegreesoffillingmaybeusedprovidedtheysatisfythegeneralrequirementsoutlinedinthepreviousparagraphsofthissection.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/602P200PACKINGINSTRUCTIONP200C.Periodicinspections8)Refillablereceptaclesshallbesubjectedtoperiodicinspectionsinaccordancewiththeprovisionsof6.2.1.6.9)Ifspecialrequirementsforcertainsubstancesdonotappearinthetablebelow,periodicinspectionsshallbecarriedout:(a)everythreeyearsinthecaseofreceptaclesintendedforthecarriageofgasesofclassificationcodes1TC,1TFC,1TOC,2TC,2TFCand2TOC;(b)everyfiveyearsinthecaseofreceptaclesintendedforthecarriageofgasesofclassificationcodes1T,1TF,1TO,2T,2TFand2TOandgasesofclassificationcodes4A,4Fand4C;(c)every10yearsinthecaseofreceptaclesintendedforthecarriageofgasesofclassificationcodes1A,1O,1F,2A,2Oand2F.Byderogationfromthisparagraph,theperiodicinspectionofreceptacleswhichmakeuseofcompositematerials(compositereceptacles)shallbecarriedoutatintervalsdeterminedbythecompetentauthorityoftheMemberStatewhichhasapprovedthetechnicalcodeforthedesignandconstruction.D.Table10)Thefollowingtable:—identifieswhattypesofreceptaclesareauthorisedforwhatgases,—identifiesthetestpressure,degreeoffillingandlimitationofcapacityforthedifferentgases,aswellasrestrictionsconcerningtoxicgaseswithaLC50lessthan200ppm,—referstoadditionalrequirementsthatareproductspecific.11)Keysforthecolumn‘receptacles’(1)cylinders;(2)tubes;(3)pressuredrums;(5)bundlesofcylinders.12)Keysforthecolumn‘Specialrequirements’:a:Aluminiumalloysnotallowedincontactwithgas.b:Valvesmadeofcopperarenotaccepted.c:Metalpartsincontactwiththecontentsshallnotcontainmorethan70%copper.d:Noreceptaclemaycontainmorethan5kgofthesubstance.e:Thevalveoutletsshallbefittedwithplugsorcap-nutsensuringgas-tightness.f:Thenecessarystepstopreventdangerousreactions(e.g.polymerisation,decomposition,etc.)duringcarriageshallbetaken.Ifnecessary,stabilisationoradditionofaninhibitorisrequired.g:TheuseoftestpressuresotherthanthoseindicatedareallowedprovidedtheprovisionsofP200(4)arefollowed.h:Ifamonolithicmaterialisusedasaporousmass,theintervalbetweeninspectionsmaybeextendedto10years.i:Maximumfillingaccordingtothefiguresspecifiedintheapproval.j:ThetestpressureanddegreeoffillingshallbecalculatedinaccordancewiththeprovisionsofP200(3),(4)or(5).k:Theintervalbetweentestsmaybeextendedto10yearswhenreceptaclesaremadeofaluminiumalloys.l:Eachcylinderinaframe(bundle)shallbefittedwithanindividualvalvethatshallbeclosedduringcarriage.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/603P200PACKINGINSTRUCTIONP200m:Theintervalbetweeninspectionsforsteelcylindersmaybeextendedto15years:(a)withtheagreementofthecompetentauthority(authorities)ofthecountry(countries)wheretheperiodicinspectionandthecarriagetakeplace;and(b)inaccordancewiththerequirementsofatechnicalcodeorastandardrecognisedbythecompetentauthority,orstandardEN1440:1996‘Transportablerefillableweldedcylindersforliquefiedpetroleumgas(LPG)—Periodicrequalification’.n:(1)Allowedforcarriageincapsulesunderthefollowingconditions:(a)themassofgasshallnotexceed150gpercapsule;(b)thecapsulesshallbefreefromfaultsliabletoimpairthestrength;(c)theleakproofnessoftheclosureshallbeensuredbyanadditionaldevice(cap,crown,seal,binding,etc.)capableofpreventinganyleakageoftheclosureduringcarriage;(d)thecapsulesshallbeplacedinanouterpackagingofsufficientstrength.Apackageshallnotweighmorethan75kg.(2)Notallowedforcarriageincapsules:(a)methylsilaneormixturesthereof,assignedtoUNNo3161;(b)dimethylsilane,trimethylsilaneormixturesthereof,assignedtoUNNo3309;(c)mixturesofUNNo1589cyanogenchloride,UNNo2188arsine,UNNo2202hydrogenselenide,UNNo2189dichlorosilane.z:InthecaseofreceptaclesforthecarriageofgasesunderaN.O.Sentry,thefollowingrequirementsshallbetakenintoaccountasapplicable:1)thematerialsofwhichthereceptaclesandtheirclosuresaremadeshallnotbeliabletoattackbythecontentsorformharmfulordangerouscompoundstherewith;2)thespecialrequirementsofeachcomponentshallbetakenintoaccountwhenselectingandfillingthereceptacles;3)thetestpressureanddegreeoffillingistobecalculatedinaccordancewiththerequirementsofP200(3),(4)or(5);4)toxicgasesandgasmixtureswithaLC50lessthan200ppmarenotallowedfortransportintubesandpressuredrums;5)thevalvesofreceptaclesfortoxicgasesandgasmixtureswithaLC50lessthan200ppmorofpyrophoricgasesorflammablemixturesofgasescontainingmorethan1%ofpyrophoriccompoundsshallbefittedwithgastightplugsorcap-nuts.Whenthesereceptaclesaremanifoldedinabundle,eachofthemshallbefittedwithanindividualvalvethatshallbeclosedduringcarriage;6)thenecessarystepstopreventdangerousreactions(i.e.polymerisation,decomposition)duringcarriageshallbetaken.Ifnecessary,stabilisationoradditionofaninhibitorisrequired;7)othercriteriamaybeusedforfillingofweldedsteelcylindersintendedforthecarriageofsubstancesofUNNo1965:(a)withtheagreementofthecompetentauthoritiesofthecountrieswherethetransportiscarriedout;and(b)incompliancewiththeprovisionsofanationalcodeorstandardrecognisedbythecompetentauthoritiesorstandardEN1439:1996‘Transportablerefillablesteelcylindersforliquefiedpetroleumgases(LPG)—Proceduresforcheckingbefore,duringandafterrefilling)’.WhenthecriteriaforfillingaredifferentfromthoseinP200(5),thetransportdocumentshallincludethestatement‘CarriageinaccordancewithpackinginstructionP200,specialrequirementz’andtheindicationofthereferencetemperatureusedforthecalculationofthefillingfactor(seealso5.4.1.1.12).OfficialJournaloftheEuropeanUnionEN26.1.2004L18/604P200PACKINGINSTRUCTIONP200E.Referencetostandards13)Theapplicablerequirementsofthispackinginstructionareconsideredtohavebeencompliedwithifthefollowingstandards,asrelevant,areapplied:ApplicablerequirementsReferenceTitleofdocumentP200(6)EN1801:1998Transportablegascylinders—Fillingconditionsforsingleacetylenecylinders(includinglistofpermissibleporousmasses)P200(6)EN12755:2000Transportablegascylinders—FillingconditionsforacetylenebundlesUNNoNameanddescriptionClassifica-tioncodePackingTestFillingSpecialrequire-mentsTypeofreceptaclePressure(Pe)Period(years)(a)Maximumfillingdegreekg/lormaximumfillingpres-sureMPa×fillingpressureMPa1001ACETYLENE,DISSOLVED4F(1),(5)6,05c,h,i1002AIR,COMPRESSED1A(1),(2),(3),(5)1,5102/3Pe1005AMMONIA,ANHY-DROUS2TC(1),(2),(3),(5)3,350,53b,n1006ARGON,COMPRESSED1A(1),(2),(3),(5)1,5102/3Pe1008BORONTRIFLUORIDE,COMPRESSED1TC(1),(2),(3),(5)(1),(2),(3),(5)22,530,0330,7150,86gg1009BROMOTRIFLUOROME-THANE(REFRIGERANTGASR13B1)2A(1),(2),(3),(5)4,2101,13g,n(1),(2),(3),(5)12,0101,44g,n(1),(2),(3),(5)25,0101,60g,n10101,2-BUTADIENE,INHIB-ITED,or2F(1),(2),(3),(5)1,0100,59f,n10101,3-BUTADIENE,INHIB-ITED,or(1),(2),(3),(5)1,0100,55f,n1010MIXTURESOF1,3-BUTADIENEANDHYDROCARBONS,INHIBITED(1),(2),(3),(5)1,0100,55f,j,n1011BUTANE2F(1),(2),(3),(5)1,0100,51n1012BUTYLENESMIXTUREor2F(1),(2),(3),(5)1,0100,5j,n10121-BUTYLENEor(1),(2),(3),(5)1,0100,531012CIS-2-BUTENEor(1),(2),(3),(5)1,0100,551012TRANS-2-BUTYLENE(1),(2),(3),(5)1,0100,54OfficialJournaloftheEuropeanUnionEN26.1.2004L18/605P200PACKINGINSTRUCTIONP200UNNoNameanddescriptionClassifica-tioncodePackingTestFillingSpecialrequire-mentsTypeofreceptaclePressure(Pe)Period(years)(a)Maximumfillingdegreekg/lormaximumfillingpres-sureMPa×fillingpressureMPa1013CARBONDIOXIDE2A(1),(2),(3),(5)19,0100,66g,n(1),(2),(3),(5)25,0100,75g,n1014CARBONDIOXIDEANDOXYGENMIXTURE,COMPRESSED1O(1),(2),(3),(5)1,5102/3Pe1015CARBONDIOXIDEANDNITROUSOXIDEMIXTURE2A(1),(3),(5)25,0100,751016CARBONMONOXIDE,COMPRESSED1TF(1),(2),(3),(5)1,552/3Pek1017CHLORINE2TC(1),(2),(3),(5)2,251,25a,n1018CHLORODIFLUORO-METHANE(REFRIG-ERANTGASR22)2A(1),(2),(3),(5)2,9101,03n1020CHLOROPENTA-FLUORO-ÉTHANE(GAZRÉFRIGÉRANTR115)2A(1),(2),(3),(5)2,5101,08n10211-CHLORO-1,2,2,2-TETRAFLUOROETHANE(REFRIGERANTGASR124)2A(1),(2),(3),(5)1,2101,2n1022CHLOROTRIFLUORO-METHANE(REFRIG-ERANTGASR13)2A(1),(2),(3),(5)10,0100,83g,n(1),(2),(3),(5)12,0100,90g,n(1),(2),(3),(5)19,0101,04g,n(1),(2),(3),(5)25,0101,10g,n1023COALGAS,COMPRESED1TF(1),(2),(3),(5)1,552/3Pe1026CYANOGEN2TF(1),(2),(3),(5)10,050,70k,n1027CYCLOPROPANE2F(1),(2),(3),(5)2,0100,53n1028DICHLORODIFLUORO-METHANE(REFRIG-ERANTGASR12)2A(1),(2),(3),(5)1,8101,15nOfficialJournaloftheEuropeanUnionEN26.1.2004L18/606P200PACKINGINSTRUCTIONP200UNNoNameanddescriptionClassifica-tioncodePackingTestFillingSpecialrequire-mentsTypeofreceptaclePressure(Pe)Period(years)(a)Maximumfillingdegreekg/lormaximumfillingpres-sureMPa×fillingpressureMPa1029DICHLOROFLUOROME-THANE(REFRIGERANTGASR21)2A(1),(2),(3),(5)1,0101,23n10301,1-DIFLUOROETHANE(REFRIGERANTGASR152a)2F(1),(2),(3),(5)1,8100,79n1032DIMETHYLAMINE,ANHYDROUS2F(1),(2),(3),(5)1,0100,59b,n1033DIMETHYLETHER2F(1),(2),(3),(5)1,8100,58n1035ETHANE2F(1),(2),(3),(5)9,5100,25g,n(1),(2),(3),(5)12100,29g,n(1),(2),(3),(5)30100,39g,n1036ETHYLAMINE2F(1),(2),(3),(5)1,0100,61b,n1037ETHYLCHLORIDE2F(1),(2),(3),(5)1,0100,80a,n1039ETHYLMETHYLETHER2F(1),(2),(3),(5)1,0100,64n1040ETHYLENEOXIDEorETHYLENEOXIDEWITHNITROGENuptoatotalpressureof1MPa(10bar)at50°C2TF(1),(2),(3),(5)1,550,78f,n1041ETHYLENEOXIDEANDCARBONDIOXIDEMIXTUREwithmorethan9%ethyleneoxidebutnotmorethan87%2F(1),(2),(3),(5)19100,66g,n(1),(2),(3),(5)25100,75g,n1045FLUORINE,COMPRESSED1TOC(1),(5)20,052,8MPaa,d,e,l1046HELIUM,COMPRESSED1A(1),(2),(3),(5)1,5102/3Pe1048HYDROGENBROMIDE,ANHYDROUS2TC(1),(2),(3),(5)6,031,54a,n1049HYDROGEN,COMPRESSED1F(1),(2),(3),(5)1,5102/3PeOfficialJournaloftheEuropeanUnionEN26.1.2004L18/607P200PACKINGINSTRUCTIONP200UNNoNameanddescriptionClassifica-tioncodePackingTestFillingSpecialrequire-mentsTypeofreceptaclePressure(Pe)Period(years)(a)Maximumfillingdegreekg/lormaximumfillingpres-sureMPa×fillingpressureMPa1050HYDROGENCHLORIDE,ANHYDROUS2TC(1),(2),(3),(5)10,030,30a,g,n(1),(2),(3),(5)12,030,56a,g,n(1),(2),(3),(5)15,030,67a,g,n(1),(2),(3),(5)20,030,74a,g,n1053HYDROGENSULPHIDE2TF(1),(2),(3),(5)5,550,67k,n1055ISOBUTYLENE2F(1),(2),(3),(5)1,0100,52n1056KRYPTON,COMPRESSED1A(1),(2),(3),(5)1,5102/3Pe1058LIQUEFIEDGASES,non-flammable,chargedwithnitrogen,carbondioxideorair2A(1),(2),(3),(5)1,510j,n1060METHYLACETYLENEANDPROPADIENEMIXTURE,STABILISED2F(1),(2),(3),(5)10c,f,j,nPropadienewith1%to4%methylacetylene(1),(2),(3),(5)2,2100,50c,f,nMixtureP1(1),(2),(3),(5)3,0100,49c,f,nMixtureP2(1),(2),(3),(5)2,4100,47c,f,n1061METHYLAMINE,ANHY-DROUS2F(1),(2),(3),(5)1,3100,58b,n1062METHYLBROMIDE2T(1),(2),(3),(5)1,051,51a1063METHYLCHLORIDE(REFRIGERANTGASR40)2F(1),(2),(3),(5)1,7100,81a,n1064METHYLMERCAPTAN2TF(1),(2),(3),(5)1,050,78k,n1065NEON,COMPRESSED1A(1),(2),(3),(5)1,5102/3Pe1066NITROGEN,COMPRESSED1A(1),(2),(3),(5)1,5102/3Pe1067DINITROGENTETR-OXIDE(NITROGENDIOXIDE)2TOC(1),(3),(5)1,031,30e,lOfficialJournaloftheEuropeanUnionEN26.1.2004L18/608P200PACKINGINSTRUCTIONP200UNNoNameanddescriptionClassifica-tioncodePackingTestFillingSpecialrequire-mentsTypeofreceptaclePressure(Pe)Period(years)(a)Maximumfillingdegreekg/lormaximumfillingpres-sureMPa×fillingpressureMPa1069NITROSYLCHLORIDE2TC(1),(5)1,331,10e,l,n1070NITROUSOXIDE2O(1),(2),(3),(5)18,0100,68g(1),(2),(3),(5)22,5100,74g(1),(2),(3),(5)25,0100,70g1071OILGAS,COMPRESSED1TF(1),(2),(3),(5)1,552/3Pe1072OXYGEN,COMPRESSED1O(1),(2),(3),(5)1,5102/3Pe1076PHOSGENE2TC(1),(3),(5)2,031,23e,l,n1077PROPYLENE2F(1),(2),(3),(5)3,0100,43n1078REFRIGERANTGASES,N.O.S.2A(1),(2),(3),(5)10n,zMixtureF1(1),(2),(3),(5)1,2101,23MixtureF2(1),(2),(3),(5)1,8101,15MixtureF3(1),(2),(3),(5)2,9101,031079SULPHURDIOXIDE2TC(1),(2),(3),(5)1,431,23n1080SULPHURHEXA-FLUORIDE2A(1),(2),(3),(5)7,0101,04g,n(1),(2),(3),(5)14,0101,33g,n(1),(2),(3),(5)16,0101,37g,n1081TETRAFLUOROETHY-LENE,INHIBITED2F(1),(2),(3),(5)20,0100,5MPaf,n1082TRIFLUOROCHLORO-ETHYLENE,INHIBITED2TF(1),(2),(3),(5)1,951,13f,k,n1083TRIMETHYLAMINE,ANHYDROUS2F(1),(2),(3),(5)1,0100,56b,n1085VINYLBROMIDE,INHIBITED2F(1),(2),(3),(5)1,0101,37a,f,n1086VINYLCHLORIDE,INHIBITED2F(1),(2),(3),(5)1,2100,81a,f,nOfficialJournaloftheEuropeanUnionEN26.1.2004L18/609P200PACKINGINSTRUCTIONP200UNNoNameanddescriptionClassifica-tioncodePackingTestFillingSpecialrequire-mentsTypeofreceptaclePressure(Pe)Period(years)(a)Maximumfillingdegreekg/lormaximumfillingpres-sureMPa×fillingpressureMPa1087VINYLMETHYLETHER,INHIBITED2F(1),(2),(3),(5)1,0100,67f,n1581CHLOROPICRINANDMETHYLBROMIDEMIXTURE2T(1),(2),(3),(5)1,051,51a1582CHLOROPICRINANDMETHYLCHLORIDEMIXTURE2T(1),(2),(3),(5)1,750,81a1589CYANOGENCHLORIDE,INHIBITED2TC(1),(5)2,031,03e,f,l1612HEXAETHYLTETRA-PHOSPHATEANDCOMPRESSEDGASMIXTURE1T(1),(2),(3),(5)1,552/3Pe1660NITRICOXIDE,COMPRESSED1TOC(1),(5)1,532/3Pee,l1741BORONTRICHLORIDE2TC(1),(2),(3),(5)1,031,19n1749CHLORINETRIFLUORIDE2TOC(1),(2),(3),(5)3,031,40a1858HEXAFLUOROPROPY-LENE(REFRIGERANTGASR1216)2A(1),(2),(3),(5)2,2101,11n1859SILICONTETRA-FLUORIDE,COMPRESSED1TC(1),(2),(3),(5)2030,74g(1),(2),(3),(5)3031,1g1860VINYLFLUORIDE,INHIBITED2F(1),(2),(3),(5)25,0100,64a,f,g,n1911DIBORANE,COMPRESSED1TF(1),(5)25,050,072e,f,l1912METHYLCHLORIDEANDMETHYLENECHLORIDEMIXTURE2F(1),(2),(3),(5)1,7100,81a,n1952CARBONDIOXIDEANDETHYLENEOXIDEMIXTUREwithnotmorethan9%ethyleneoxide2A(1),(2),(3),(5)19100,66n(1),(2),(3),(5)25100,75nOfficialJournaloftheEuropeanUnionEN26.1.2004L18/610P200PACKINGINSTRUCTIONP200UNNoNameanddescriptionClassifica-tioncodePackingTestFillingSpecialrequire-mentsTypeofreceptaclePressure(Pe)Period(years)(a)Maximumfillingdegreekg/lormaximumfillingpres-sureMPa×fillingpressureMPa1953COMPRESSEDGAS,TOXIC,FLAMMABLE,N.O.S.1TF(1),(2),(3),(5)1,552/3Pez1954COMPRESSEDGAS,FLAMMABLE,N.O.S.1F(1),(2),(3),(5)1,5102/3Pez1955COMPRESSEDGAS,TOXIC,N.O.S.1T(1),(2),(3),(5)1,552/3Pez1956COMPRESSEDGAS,N.O.S.1A(1),(2),(3),(5)1,5102/3Pez1957DEUTERIUM,COMPRESSED1F(1),(2),(3),(5)1,5102/3Pe1958DICHLOROTETRA-FLUORO-ETHANE(REFRIGERANTGASR114)2A(1),(2),(3),(5)1,0101,30n19591,1-DIFLUOROETHY-LENE(REFRIGERANTGASR1132a)2F(1),(2),(3),(5)25100,77g,n1962ETHYLENE,COMPRESSED1F(1),(2),(3),(5)22,5100,34g(1),(2),(3),(5)30100,37g1964HYDROCARBONGASMIXTURE,COMPRESSED,N.O.S.1F(1),(2),(3),(5)1,5102/3Pez1965HYDROCARBONGASMIXTURE,LIQUEFIED,N.O.S.2F(1),(2),(3),(5)10(b)m,n,zMixtureA(1),(2),(3),(5)1,0100,50MixtureAO1(1),(2),(3),(5)1,5100,49MixtureAO2(1),(2),(3),(5)1,5100,48MixtureAO(1),(2),(3),(5)1,5100,47MixtureA1(1),(2),(3),(5)2,0100,46MixtureB1(1),(2),(3),(5)2,5100,45MixtureB2(1),(2),(3),(5)2,5100,44MixtureB(1),(2),(3),(5)2,5100,43MixtureC(1),(2),(3),(5)3,0100,42OfficialJournaloftheEuropeanUnionEN26.1.2004L18/611P200PACKINGINSTRUCTIONP200UNNoNameanddescriptionClassifica-tioncodePackingTestFillingSpecialrequire-mentsTypeofreceptaclePressure(Pe)Period(years)(a)Maximumfillingdegreekg/lormaximumfillingpres-sureMPa×fillingpressureMPa1967INSECTICIDEGAS,TOXIC,N.O.S.2T(1),(2),(3),(5)5z1968INSECTICIDEGAS,N.O.S.2A(1),(2),(3),(5)10n,z1969ISOBUTANE2F(1),(2),(3),(5)1,0100,49n1971METHANE,COMPRESSEDorNATURALGAS,COMPRESSEDwithhighmethanecontent1F(1),(2),(3),(5)1,5102/3Pe1973CHLORODIFLUOROME-THANEANDCHLORO-PENTAFLUORO-ETHANEMIXTUREwithfixedboilingpoint,withapproximately49%chlorodifluoromethane(REFRIGERANTGASR502)2A(1),(2),(3),(5)3,1101,05n1974CHLORODIFLUORO-BROMO-METHANE(R12B1)2A(1),(2),(3),(5)1,0101,61n1975NITRICOXIDEANDDINITROGENTETR-OXIDEMIXTURE(NITRICOXIDEANDNITROGENDIOXIDEMIXTURE)2TOC(1),(2),(3),(5)3e,j,l1976OCTAFLUOROCYCLO-BUTANE(REFRIGERANTGASRC318)2A(1),(2),(3),(5)1,1101,34n1978PROPANE2F(1),(2),(3),(5)2,5100,42n1979RAREGASESMIXTURE,COMPRESSED1A(1),(2),(3),(5)1,5102/3Pe1980RAREGASESANDOXYGENMIXTURE,COMPRESSED1A(1),(2),(3),(5)1,5102/3Pe1981RAREGASESANDNITROGENMIXTURE,COMPRESSED1A(1),(2),(3),(5)1,5102/3PeOfficialJournaloftheEuropeanUnionEN26.1.2004L18/612P200PACKINGINSTRUCTIONP200UNNoNameanddescriptionClassifica-tioncodePackingTestFillingSpecialrequire-mentsTypeofreceptaclePressure(Pe)Period(years)(a)Maximumfillingdegreekg/lormaximumfillingpres-sureMPa×fillingpressureMPa1982TETRAFLUOROME-THANE,COMPRESSED(REFRIGERANTGASR14,COMPRESSED)1A(1),(2),(3),(5)20100,62g(1),(2),(3),(5)30100,94g19831-CHLORO-2,2,2-TRIFLUOROETHANE(REFRIGERANTGASR133a)2A(1),(2),(3),(5)1,0101,18n1984TRIFLUOROMETHANE(REFRIGERANTGASR23)2A(1),(2),(3),(5)19,0100,87g,n(1),(2),(3),(5)25,0100,95g,n2034HYDROGENANDMETHANEMIXTURE,COMPRESSED1F(1),(2),(3),(5)1,5102/3Pe20351,1,1-TRIFLUOR-OETHANE(REFRIG-ERANTGASR143a)2F(1),(2),(3),(5)3,5100,75n2036XENON,COMPRESSED1A(1),(2),(3),(5)13101,24g20442,2-DIMETHYLPROPANE2F(1),(2),(3),(5)1,0100,53n2073AMMONIASOLUTION,relativedensitylessthan0,88at15°Cwithmorethan35%andnotmorethan40%ammoniawithmorethan40%andnotmorethan50%ammonia4A(1),(2),(3),(5)1,050,80(1),(2),(3),(5)1,050,772188ARSINE2TF(1),(5)4,251,10e,l2189DICHLOROSILANE2TFC(1),(2),(3),(5)130,902190OXYGENDIFLUORIDE1TOC(1),(5)20,032,8MPaa,d,e,l2191SULPHURYLFLUORIDE2T(1),(2),(3),(5)5,051,10k2192GERMANE(c)2TF(1),(5)25,051,02e,g,l,n2193HEXAFLUOROETHANE,COMPRESSED(REFRIG-ERANTGASR116,COMPRESSED)1A(1),(2),(3),(5)20101,10gOfficialJournaloftheEuropeanUnionEN26.1.2004L18/613P200PACKINGINSTRUCTIONP200UNNoNameanddescriptionClassifica-tioncodePackingTestFillingSpecialrequire-mentsTypeofreceptaclePressure(Pe)Period(years)(a)Maximumfillingdegreekg/lormaximumfillingpres-sureMPa×fillingpressureMPa2194SELENIUMHEXA-FLUORIDE2TC(1),(5)3,631,46e,g,l,n2195TELLURIUMHEXA-FLUORIDE2TC(1),(5)2,031,0e,l,n2196TUNGSTENHEXA-FLUORIDE2TC(1),(5)1,032,70a,e,l,n2197HYDROGENIODIDE,ANHYDROUS2TC(1),(2),(3),(5)2,332,25a,n2198PHOSPHORUSPENTA-FLUORIDE,COMPRESSED1TC(1),(5)2030,9e,g,l(1),(5)3031,34e,g,l2199PHOSPHINE(c)2TF(1),(5)22,550,30e,g,l2200PROPADIENE,INHIB-ITED2F(1),(2),(3),(5)2,2100,50f,n2202HYDROGENSELENIDE,ANHYDROUS2TF(1),(5)3,151,60e,l2203SILANE,COMPRES-SED(c)1F(1),(2),(3),(5)22,5100,32e,g,l(1),(2),(3),(5)25,0100,41e,g,l2204CARBONYLSULPHIDE2TF(1),(2),(3),(5)2,650,84k,n2417CARBONYLFLUORIDE,COMPRESSED1TC(1),(2),(3),(5)(1),(2),(3),(5)203030,470,7gg2418SULPHURTETRA-FLUORIDE2TC(1),(5)3,030,91e,l,n2419BROMOTRIFLUORO-ETHYLENE2F(1),(2),(3),(5)1,0101,19n2420HEXAFLUOROACETONE2TC(1),(2),(3),(5)2,231,08n2422OCTAFLUOROBUT-2-ENE(REFRIGERANTGASR1318)2A(1),(2),(3),(5)1,2101,34n2424OCTAFLUOROPROPANE(REFRIGERANTGASR218)2A(1),(2),(3),(5)2,5101,09nOfficialJournaloftheEuropeanUnionEN26.1.2004L18/614P200PACKINGINSTRUCTIONP200UNNoNameanddescriptionClassifica-tioncodePackingTestFillingSpecialrequire-mentsTypeofreceptaclePressure(Pe)Period(years)(a)Maximumfillingdegreekg/lormaximumfillingpres-sureMPa×fillingpressureMPa2451NITROGENTRIFLUORIDE1O(1),(2),(3),(5)20100,5g(1),(2),(3),(5)300,75g2452ETHYLACETYLENE,INHIBITED2F(1),(2),(3),(5)1,0100,57c,f,n2453ETHYLFLUORIDE(REFRIGERANTGASR161)2F(1),(2),(3),(5)3,0100,57n2454METHYLFLUORIDE(REFRIGERANTGASR41)2F(1),(2),(3),(5)30,0100,36n25171-CHLORO-1,1-DIFLUOROETHANE(REFRIGERANTGASR142(b)2F(1),(2),(3),(5)1,0100,99n2534METHYLCHLOROSI-LANE2TFC(1),(2),(3),(5)3j,n2548CHLORINEPENTA-FLUORIDE2TOC(1),(5)1,331,49a,e,l2599CHLOROTRIFLUORO-METHANEANDTRIFLUOROMETHANE,AZEOTROPICMIXTUREwithapproximately60%chlorotrifluoro-methane(REFRIGERANTGASR503)2A(1),(2),(3),(5)4,2100,20n(1),(2),(3),(5)10,0100,66(1),(2),(3),(5)10,0100,662600CARBONMONOXIDEANDHYDROGENMIXTURE,COMPRESSED1TF(1),(2),(3),(5)1,552/3Pek2601CYCLOBUTANE2F(1),(2),(3),(5)1,0100,63n2602DICHLORODIFLUORO-METHANEAND1,1-DIFLUOROETHANE,AZEOTROPICMIXTUREwithapproximately74%dichlorodifluoromethane(REFRIGERANTGASR500)2A(1),(2),(3),(5)2,2101,01n2676STIBINE2TF(1),(5)2,051,2e,l,n2901BROMINECHLORIDE2TOC(1),(2),(3),(5)1,031,5aOfficialJournaloftheEuropeanUnionEN26.1.2004L18/615P200PACKINGINSTRUCTIONP200UNNoNameanddescriptionClassifica-tioncodePackingTestFillingSpecialrequire-mentsTypeofreceptaclePressure(Pe)Period(years)(a)Maximumfillingdegreekg/lormaximumfillingpres-sureMPa×fillingpressureMPa3057TRIFLUOROACETYLCHLORIDE2TC(1),(2),(3),(5)1,731,17n3070ETHYLENEOXIDEANDDICHLORODIFLUORO-METHANEMIXTUREwithnotmorethan12,5%ethyleneoxide2A(1),(2),(3),(5)1,8101,09n3083PERCHLORYLFLUORIDE2TO(1),(2),(3),(5)3,351,21k3153PERFLUORO(METHYLVINYLETHER)2F(1),(2),(3),(5)2,0100,75n3154PERFLUORO(ETHYLVINYLETHER)2F(1),(2),(3),(5)1,0100,98n3156COMPRESSEDGAS,OXIDISING,N.O.S.1O(1),(2),(3),(5)1,5102/3Pez3157LIQUEFIEDGAS,OXIDISING,N.O.S.2O(1),(2),(3),(5)10z31591,1,1,2-TETRAFLUOR-OETHANE(REFRIG-ERNATGASR134a)2A(1),(2),(3),(5)2,2101,04n3160LIQUEFIEDGAS,TOXIC,FLAMMABLE,N.O.S.2TF(1),(2),(3),(5)5n,z3161LIQUEFIEDGAS,FLAM-MABLE,N.O.S.2F(1),(2),(3),(5)10n,z3162LIQUEFIEDGAS,TOXIC,N.O.S.2T(1),(2),(3),(5)5z3163LIQUEFIEDGAS,N.O.S.2A(1),(2),(3),(5)10n,z3220PENTAFLUOROETHANE(REFRIGERANTGASR125)2A(1),(2),(3),(5)4,9100,95g,n(1),(2),(3),(5)3,6100,72g,n3252DIFLUOROMETHANE(REFRIGERANTGASR32)2F(1),(2),(3),(5)4,8100,78n3296HEPTAFLUOROPRO-PANE(REFRIGERANTGASR227)2A(1),(2),(3),(5)1,5101,2nOfficialJournaloftheEuropeanUnionEN26.1.2004L18/616P200PACKINGINSTRUCTIONP200UNNoNameanddescriptionClassifica-tioncodePackingTestFillingSpecialrequire-mentsTypeofreceptaclePressure(Pe)Period(years)(a)Maximumfillingdegreekg/lormaximumfillingpres-sureMPa×fillingpressureMPa3297ETHYLENEOXIDEANDCHLOROTETRA-FLUORO-ETHANEMIXTUREwithnotmorethan8,8%ethyleneoxide2A(1),(2),(3),(5)1,0101,16n3298ETHYLENEOXIDEANDPENTAFLUOROETHANEMIXTUREwithnotmorethan7,9%ethyleneoxide2A(1),(2),(3),(5)2,6101,02n3299ETHYLENEOXIDEANDTETRAFLUOROETHANEMIXTUREwithnotmorethan5,6%ethyleneoxide2A(1),(2),(3),(5)1,7101,03n3300ETHYLENEOXIDEANDCARBONDIOXIDEMIXTUREwithmorethan87%ethyleneoxide2TF(1),(2),(3),(5)2,850,73f,n3303COMPRESSEDGAS,TOXIC,OXIDISING,N.O.S.1TO(1),(2),(3),(5)1,552/3Pez3304COMPRESSEDGAS,TOXIC,CORROSIVE,N.O.S.1TC(1),(2),(3),(5)1,532/3Pez3305COMPRESSEDGAS,TOXIC,FLAMMABLE,CORROSIVE,N.O.S.1TFC(1),(2),(3),(5)1,532/3Pez3306COMPRESSEDGAS,TOXIC,OXIDISING,CORROSIVE,N.O.S.1TOC(1),(2),(3),(5)1,532/3Pez3307LIQUEFIEDGAS,TOXIC,OXIDISING,N.O.S.2TO(1),(2),(3),(5)5z3308LIQUEFIEDGAS,TOXIC,CORROSIVE,N.O.S.2TC(1),(2),(3),(5)3z,n3309LIQUEFIEDGAS,TOXIC,FLAMMABLE,CORRO-SIVE,N.O.S.2TFC(1),(2),(3),(5)3n,zOfficialJournaloftheEuropeanUnionEN26.1.2004L18/617P200PACKINGINSTRUCTIONP200UNNoNameanddescriptionClassifica-tioncodePackingTestFillingSpecialrequire-mentsTypeofreceptaclePressure(Pe)Period(years)(a)Maximumfillingdegreekg/lormaximumfillingpres-sureMPa×fillingpressureMPa3310LIQUEFIEDGAS,TOXIC,OXIDISING,CORRO-SIVE,N.O.S.2TOC(1),(2),(3),(5)3z3318AMMONIASOLUTION,relativedensitylessthan0,880at15°Cinwater,withmorethan50%ammonia4TC(1),(2),(3),(5)5j3337REFRIGERANTGASR404A2A(1),(2),(3),(5)3,5100,84n3338REFRIGERANTGASR407A2A(1),(2),(3),(5)3,5100,95n3339REFRIGERANTGASR407B2A(1),(2),(3),(5)3,7100,95n3340REFRIGERANTGASR407C2A(1),(2),(3),(5)3,4100,95n3354INSECTICIDEGAS,FLAMMABLE,N.O.S.2F(1),(2),(3),(5)10n,zOfficialJournaloftheEuropeanUnionEN26.1.2004L18/618P200PACKINGINSTRUCTIONP200UNNoNameanddescriptionClassifica-tioncodePackingTestFillingSpecialrequire-mentsTypeofreceptaclePressure(Pe)Period(years)(a)Maximumfillingdegreekg/lormaximumfillingpres-sureMPa×fillingpressureMPa3355INSECTICIDEGAS,TOXIC,FLAMMABLE,N.O.S.2TF(1),(2),(3),(5)5n,z(a)Notapplicableforreceptaclesmadeofcompositematerials.(b)FormixturesofUNNo1965,themaximumpermissiblefillingmassperlitreofcapacityisasfollows:(c)Consideredaspyrophoric.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/619P201PACKINGINSTRUCTIONP201ThisinstructionappliestoUNNos3167,3168and3169.Thefollowingpackagingsareauthorised:1)Compressedgascylindersandgasreceptaclesconformingtotheconstruction,testingandfillingrequirementsapprovedbythecompetentauthority.2)Fornon-toxicgases,combinationpackagingswithhermeticallysealedinnerpackagingsofglassormetalwithamaximumcapacityof5litresperpackagewhichmeetthepackinggroupIIIperformancelevel.3)Fortoxicgases,combinationpackagingswithhermeticallysealedinnerpackagingsofglassormetalwithamaximumcapacityof1litreperpackagewhichmeetthepackinggroupIIIperformancelevel.P202PACKINGINSTRUCTIONP202ThisinstructionappliestoUNNo3353.Thefollowingpackagingsareauthorised:PackagingsconformingtothepackinggroupIIIperformancelevel.Airbaginflatorsormodulesorseatbeltspretensionersmaybecarriedunpackagedindedicatedhandlingdevices,vehiclesorclosedvehiclesorcontainerswhenmovedfromwheretheyaremanufacturedtoanassemblyplant.Additionalrequirements:1.Thepackagingshallbedesignedandconstructedtopreventinadvertentoperationduringnormalconditionsofcarriage.2.Thepressurevesselshallbeinaccordancewiththerequirementsofthecompetentauthorityforthegas(es)containedinthepressurevessel.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/620P203PACKINGINSTRUCTIONP203Typeofpackagings:CryogenicreceptaclesGeneralinstructions1)Thespecialpackingprovisionsof4.1.6shallbemet.2)Thereceptaclesshallbesoinsulatedthattheycannotbecomecoatedwithdeworhoar-frost.3)Inthecaseofreceptaclesintendedforthecarriageofgasesofclassificationcode3O,thematerialusedtoensuretheleakproofnessofthejointsorforthemaintenanceoftheclosuresshallbecompatiblewiththecontents.Particularinstructionsforclosedcryogenicreceptacles4)Thereceptaclesshallbefittedwithsafetyvalves.5)Forrefrigeratedliquefiedgasesofclassificationcodes3Aand3Othedegreeoffilling,atthefillingtemperatureandatapressureof0,1MPa(1bar)shallnotexceed98%ofthecapacity.6)Forrefrigeratedliquefiedgasesofclassificationcode3Fthedegreeoffillingshallremainbelowthelevelatwhich,ifthecontentswereraisedtothetemperatureatwhichthevapourpressureequalledtheopeningpressureofthereliefvalve,thevolumewouldreach95%ofthecapacityatthattemperature.7)Receptaclesshallbesubjectedtoperiodicinspectionsinaccordancewiththeprovisionsof6.2.1.6.8)Periodicinspectionsshallbecarriedoutevery10years.Byderogationfromthisdate,theperiodicinspectionofreceptacleswhichmakeuseofcompositematerials(compositereceptacles)maybecarriedoutatintervalsdeterminedbythecompetentauthorityoftheMemberStatewhichhasapprovedthetechnicalcodeforthedesignandconstruction.Particularinstructionsforopencryogenicreceptacles9)Opencryogenicreceptaclesarenotallowedforflammablerefrigeratedliquefiedgasesofclassificationcode3F,andUNNo2187carbondioxide,refrigeratedliquidanditsmixtures.10)Thereceptaclesshallbeequippedwithdeviceswhichpreventtheliquidfromsplashingout.11)Glassreceptaclesshallbedouble-walledvacuuminsulatedandsurroundedbyanabsorbentinsulatingmaterial;theyshallbeprotectedbyiron-wirebasketsandplacedinmetalcases.Themetalcasesfortheglassreceptaclesandtheotherreceptaclesshallbefittedwithmeansofhandling.12)Theopeningsofthereceptaclesshallbefittedwithdevicesallowinggasestoescape,preventinganysplashingoutoftheliquid,andsofixedthattheycannotfallout.13)InthecaseofUNNo1073oxygenrefrigeratedliquidandmixturesthereof,thedevicesreferredtoaboveandtheabsorbentinsulatingmaterialsurroundingtheglassreceptaclesshallbemadeofincombustiblematerials.Referencetostandards(reserved)OfficialJournaloftheEuropeanUnionEN26.1.2004L18/621P204PACKINGINSTRUCTIONP204ThispackinginstructionappliestoUNNo1950aerosolsandUNNo2037receptacles,small,containinggas(gascartridges)1)Thespecialpackingprovisionsof4.1.6shallbemetwhenapplicable.2)Receptaclesshallbesoclosedandleakproofastopreventescapeofthegases.3)ForUNNo1950aerosolsandUNNo2037receptacles,small,containinggas(gascartridges):(a)theinternalpressureat50°Cshallexceedneithertwothirdsofthetestpressurenor1,32MPa(13,2bar).(b)theyshallbesofilledthatat50°Ctheliquidphasedoesnotexceed95%oftheircapacity.(c)theyshallsatisfyatightness(leakproofness)testinahot-waterbath:—thetemperatureofthebathandthedurationofthetestshallbesuchthattheinternalpressureofeachreceptaclereachesatleast90%oftheinternalpressurethatwouldbereachedat55°C,—however,ifthecontentsaresensitivetoheatorifthereceptaclesaremadeofaplasticsmaterialwhichsoftensatthistemperature,thetemperatureofthebathshallbefrom20°Cto30°C;inaddition,onereceptacleoutofevery2000shallbetestedatthetemperatureprescribedintheforegoingindent,—noleakageorpermanentdeformationshalloccur.Theprovisionconcerningpermanentdeformationisnotapplicabletoreceptacleswhich,beingmadeofplasticsmaterial,soften.TherequirementsofinstructionP204(3)(c)aredeemedtobemetifthefollowingstandardsarecompliedwith:—foraerosoldispensers(UNNo1950aerosols):AnnextoCouncilDirective75/324/EEC(a)asmodifiedbyCommissionDirective94/1/EC(b),—forUNNo2037gascartridgescontainingUNNo1965hydrocarbongasmixture,liquefied.EN417:1992non-refillablemetallicgascartridgesforliquefiedpetroleumgases,withorwithoutavalve,forusewithportableappliances—Construction,inspection,testingandmarking.4)ForUNNo1950aerosols,onlynon-pyrophoricandnon-toxicgasesmaybeusedaspropellants,asconstituentsofpropellants,orasfillergases.5)Allcompressedandliquefiedgases,exceptthepyrophoricgasesandverytoxicgases(gaseswithanLC50lowerthan200ppm),shallbeacceptedasfillinggasesforUNNo2037gascartridges.6)Aerosolsandgascartridgesshallbeplacedinwoodenboxesorstrongfibreboardormetalboxes;UNNo1950aerosolsmadeofglassorsyntheticmaterialandliabletoshattershallbeseparatedfromoneanotherbyinterposedsheetsoffibreboardorofanothersuitablematerial.7)Apackageshallnotweighmorethan50kgiffibreboardboxesareusedormorethan75kgifotherpackagingsareused.8)Inthecaseofcarriagebyfullload,metalarticlesmayalsobepackedasfollows:thearticlesshallbegroupedtogetherinunitsontraysandheldinpositionwithanappropriateplasticscover;theseunitsshallbestackedandsuitablysecuredonpallets.(a)OJL147,9.6.1975,p.40.(b)OJL23,28.1.1994,p.28.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/622P205PACKINGINSTRUCTIONP205ThispackinginstructionappliestoUNNo1057lightersorlighterrefills1)Thespecialpackingprovisionsof4.1.6.1shallbemetwhenapplicable.2)Thearticlesshallcomplywiththeprovisionsofthecountryinwhichtheywerefilled.3)Lightersandlighterrefillsshallbeprovidedwithprotectionagainstinadvertentdischarge.4)Theliquidportionofthegasshallnotexceed85%ofthecapacityofthereceptacleat15°C.5)Thereceptacles,includingtheclosures,shallbecapableofwithstandinganinternalpressureoftheliquefiedpetroleumgasat55°C.6)Thevalvemechanismsandignitiondevicesshallbesecurelysealed,tapedorotherwisefastenedordesignedtopreventoperationorleakageofthecontentsduringcarriage.7)Thelightersorlighterrefillsshallbetightlypackedtopreventinadvertentoperationofthereleasedevices.8)Lightersshallcontainnotmorethan10gofliquefiedpetroleumgas.Lighterrefillsshallcontainnotmorethan65gofliquefiedpetroleumgas.9)Thelightersandlighterrefillsshallbepackedinstrongouterpackagingsconformingto6.1.4consistingofnaturalwoodboxes(4C1,4C2),plywoodboxes(4D)orreconstitutedwoodboxes(4F)withamaximumgrossmassof75kg,orfibreboardboxes(4G)withamaximumgrossmassof40kg.ThepackagingsshallbetestedandapprovedinaccordancewithChapter6.1forpackinggroupII.Nevertheless,ifthesepackagingshaveamaximumgrossmassofnotmorethan2kg,compliancewiththegeneralprovisionsof4.1.1.1,4.1.1.2and4.1.1.5to4.1.1.7issufficient.P206PACKINGINSTRUCTIONP206ThispackinginstructionappliestoUNNo3150devices,small,hydrocarbongaspoweredorhydrocarbongasrefillsforsmalldevices1)Thespecialpackingprovisionsof4.1.6whenapplicableshallbemet.2)Thearticlesshallcomplywiththeprovisionsofthecountryinwhichtheywerefilled.3)Thedevicesandrefillsshallbepackedinouterpackagingsconformingto6.1.4testedandapprovedinaccordancewithChapter6.1forpackinggroupII.P300PACKINGINSTRUCTIONP300ThisinstructionappliestoUNNo3064.Thefollowingpackagingsareauthorised,providedthatthegeneralprovisionsof4.1.1and4.1.3aremet:Combinationpackagingsconsistingofinnermetalcansofnotmorethan1litrecapacityeachandouterwoodenboxes(4C1,4C2,4Dor4F)containingnotmorethan5litresofsolution.Additionalrequirements:1)Metalcansshallbecompletelysurroundedwithabsorbentcushioningmaterial.2)Woodenboxesshallbecompletelylinedwithsuitablematerialimpervioustowaterandnitroglycerine.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/623P301PACKINGINSTRUCTIONP301ThisinstructionappliestoUNNo3165.Thefollowingpackagingsareauthorised,providedthatthegeneralprovisionsof4.1.1and4.1.3aremet:1)aluminiumpressurevesselmadefromtubingandhavingweldedheads.Primarycontainmentofthefuelwithinthisvesselshallconsistofaweldedaluminiumbladderhavingamaximuminternalvolumeof46litres.Theoutervesselshallhaveaminimumdesigngaugepressureof1275kPaandaminimumburstgaugepressureof2755kPa.Eachvesselshallbeleakcheckedduringmanufactureandbeforedispatchandshallbefoundleakproof.Thecompleteinnerunitshallbesecurelypackedinnon-combustiblecushioningmaterial,suchasvermiculite,inastrongoutertightlyclosedmetalpackagingwhichwilladequatelyprotectallfittings.Maximumquantityoffuelperunitandpackageis42litres;2)aluminiumpressurevessel.Primarycontainmentofthefuelwithinthisvesselshallconsistofaweldedvapourtightfuelcompartmentwithanelastomericbladderhavingamaximuminternalvolumeof46litres.Thepressurevesselshallhaveaminimumdesigngaugepressureof2860kPaandaminimumburstgaugepressureof5170kPa.Eachvesselshallbeleak-checkedduringmanufactureandbeforedispatchandshallbesecurelypackedinnon-combustiblecushioningmaterialsuchasvermiculite,inastrongoutertightlyclosedmetalpackagingwhichwilladequatelyprotectallfittings.Maximumquantityoffuelperunitandpackageis42litres.P302PACKINGINSTRUCTIONP302ThisinstructionappliestoUNNo3269.Thefollowingpackagingsareauthorised,providedthegeneralprovisionsof4.1.1and4.1.3aremet:CombinationpackagingswhichmeetthepackinggroupIIorIIIperformancelevelaccordingtothecriteriaforClass3,appliedtothebasematerial.Thebasematerialandtheactivator(organicperoxide)shallbeeachseparatelypackedininnerpackagings.Thecomponentsmaybeplacedinthesameouterpackagingprovidedtheywillnotinteractdangerouslyintheeventofaleakage.Theactivatorshallhaveamaximumquantityof125mlperinnerpackagingifliquid,and500gramsperinnerpackagingifsolid.P400PACKINGINSTRUCTIONP400Thefollowingpackagingsareauthorised,providedthatthegeneralprovisionsof4.1.1and4.1.3aremet(seealsotheTablein4.1.4.4):(1)steelgascylindersandgasreceptacles,whichshallcomplywiththeappropriaterequirementsintheTableof4.1.4.4.Valvesshallbeprotectedwithsteelvalveprotectioncapsorcollarsorthegascylindersorreceptaclesshallbeoverpackedinstrongwood,fibreboardorplasticsboxes.Cylindersandgasreceptaclesshallbesecuredtopreventmovementintheboxandshallbepackagedandcarriedsothatthepressurereliefdevicesremaininthevapourspaceofthecylinderduringnormalconditionsofhandlingandcarriage;(2)boxes(4A,4B,4C1,4C2,4D,4For4G),drums(1A2,1B2,1N2,1Dor1G)orjerricans(3A2or3B2)enclosinghermeticallysealedmetalcanswithinnerpackagingsofglassormetal,withacapacityofnotmorethan1litreeach,havingthreadedclosureswithgaskets.Innerpackagingsshallbecushionedonallsideswithdry,absorbent,non-combustiblematerialinaquantitysufficienttoabsorbtheentirecontents.Innerpackagingsshallnotbefilledtomorethan90%oftheircapacity.Outerpackagingsshallhaveamaximumnetmassof125kg;(3)steel,aluminiumormetaldrums(1A2,1B2or1N2),jerricans(3A2or3B2)orboxes(4Aor4B)withamaximumnetmassof150kgeachwithhermeticallysealedinnermetalcansnotmorethan4lcapacityeach,withthreadedclosuresfittedwithgaskets.Innerpackagingsshallbecushionedonallsideswithdry,absorbent,non-combustiblematerialinaquantitysufficienttoabsorbtheentirecontents.Eachlayerofinnerpackagingsshallbeseparatedbyadividingpartitioninadditiontocushioningmaterial.Innerpackagingsshallnotbefilledtomorethan90%oftheircapacity.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/624P401PACKINGINSTRUCTIONP401Thefollowingpackagingsareauthorised,providedthatthegeneralprovisionsof4.1.1and4.1.3aremet(seealsotheTablein4.1.4.4):(1)steelgascylindersandgasreceptacles,whichshallcomplywiththeappropriaterequirementsintheTableof4.1.4.4.Valvesshallbeprotectedwithsteelvalveprotectioncapsorcollarsorthegascylindersorreceptaclesshallbeoverpackedinstrongwood,fibreboardorplasticsboxes.Cylindersandgasreceptaclesshallbesecuredtopreventmovementintheboxandshallbepackagedandcarriedsothatthepressurereliefdevicesremaininthecylinderduringnormalconditionsofhandlingandcarriage;(2)combinationpackagingswithinner1packagingsofglassmetalorplasticswhichhavethreadedclosuressurroundedininertcushioningandabsorbentmaterialinaquantitysufficienttoabsorbtheentirecontents.InnerpackagingOuterpackaging1l30kg(maximumnetmass)P402PACKINGINSTRUCTIONP402Thefollowingpackagingsareauthorised,providedthatthegeneralprovisionsof4.1.1and4.1.3aremet(seealsotheTablein4.1.4.4):(1)steelgascylindersandgasreceptacles,whichshallcomplywiththeappropriaterequirementsintheTableof4.1.4.4.Valvesshallbeprotectedwithsteelvalveprotectioncapsorcollarsorthegascylindersorreceptaclesshallbeoverpackedinstrongwood,fibreboardorplasticsboxes.Cylindersandgasreceptaclesshallbesecuredtopreventmovementintheboxandshallbepackagedandtransportedsothatthepressurereliefdevicesremaininthevapourspaceofthecylinderduringnormalconditionsofhandlingandcarriage.Fillingshallnotbegreaterthan90%ofthecapacityofthecylinder;(2)combinationpackagingswithinnerpackagingsofglass,metalorplasticswhichhavethreadedclosuressurroundedininertcushioningandabsorbentmaterialinaquantitysufficienttoabsorbtheentirecontents.Innerpackaging(maximumnetmass)Outerpackaging(maximumnetmass)10kg(glass)125kg15kg(metalorplastics)125kgSpecialpackingprovisionPP78ForUNNo3130,theopeningsofreceptaclesshallbetightlyclosedbymeansoftwodevicesinseries,oneofwhichshallbescrewedorsecuredinanequivalentmanner.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/625P403PACKINGINSTRUCTIONP403Thefollowingpackagingsareauthorised,providedthatthegeneralprovisionsof4.1.1and4.1.3aremet:Combinationpackagings:InnerpackagingsOuterpackagingsMaximumnetmassGlass2kgPlastics15kgMetal20kgInnerpackagingsshallhavethreadedclosuresDrumssteel(1A2)400kgaluminium(1B2)400kgmetal,otherthansteeloraluminium(1N2)400kgplastics(1H2)400kgplywood(1D)400kgfibre(1G)400kgBoxessteel(4A)400kgaluminium(4B)400kgnaturalwood(4C1)250kgnaturalwoodwithsiftproofwalls(4C2)250kgplywood(4D)250kgreconstitutedwood(4F)125kgfibreboard(4G)125kgexpandedplastics(4H1)60kgsolidplastics(4H2)250kgJerricanssteel(3A2)120kgaluminium(3B2)120kgplastics(3H2)120kgSinglepackagings:MaximumnetmassDrumssteel(1A1,1A2)250kgaluminium(1B1,1B2)250kgmetalotherthansteeloraluminium(1N1,1N2)250kgplastics(1H1,1H2)250kgJerricanssteel(3A1,3A2)120kgaluminium(3B1,3B2)120kgplastics(3H1,3H2)120kgCompositepackagingsplasticsreceptaclewithoutersteeloraluminiumdrums(6HA1or6HB1)250kgplasticsreceptaclewithouterfibre,plasticsorplywooddrums(6HG1,6HH1or6HD1)75kgplasticsreceptaclewithoutersteeloraluminiumcrateorboxorwithouterwooden,plywood,fibreboardorsolidplasticsboxes(6HA2,6HB2,6HC,6HD2,6HG2or6HH2)75kgAdditionalrequirement:Packagingsshallbehermeticallysealed.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/626P404PACKINGINSTRUCTIONP404Thisinstructionappliestopyrophoricsolids:UNNos1370,1383,1854,1855,2005,2008,2545,2546,2846,2881,3052,3200and3203.Thefollowingpackagingsareauthorised,providedthatthegeneralprovisionsof4.1.1and4.1.3aremet:(1)CombinationpackagingsOuterpackagings:(1A2,1B2,1N2,1H2,1D,4A,4B,4C1,4C2,4D,4For4H2)Innerpackagings:Metalpackagingswithacapacityofnotmorethan15kgeach.Innerpackagingsshallbehermeticallysealedandhavethreadedclosures;(2)Metalpackagings:(1A1,1A2,1B1,1N1,1N2,3A1,3A2,3B1and3B2)Maximumgrossmass:150kg;(3)Compositepackagings:Plasticsreceptaclewithoutersteeloraluminiumdrum(6HA1or6HB1)Maximumgrossmass:150kg.P405PACKINGINSTRUCTIONP405ThisinstructionappliestoUNNo1381.Thefollowingpackagingsareauthorised,providedthatthegeneralprovisionsof4.1.1and4.1.3aremet:(1)ForUNNo1381,phosphorus,wet:(a)combinationpackagingsouterpackagings:(4A,4B,4C1,4C2,4Dor4F)maximumnetmass:75kginnerpackagings:(i)hermeticallysealedmetalcans,withamaximumnetmassof15kg;or(ii)glassinnerpackagingscushionedonallsideswithdry,absorbent,non-combustiblematerialinaquantitysufficienttoabsorbtheentirecontentswithamaximumnetmassof2kg;or(b)drums(1A1,1A2,1B1,1B2,1N1or1N2);maximumnetmass:400kgjerricans(3A1or3B1);maximumnetmass:120kg.Thesepackagingsshallbecapableofpassingtheleakproofnesstestspecifiedin6.1.5.4atthepackinggroupIIperformancelevel;(2)ForUNNo1381,dryphosphorus:(a)whenfused,drums(1A2,1B2or1N2)withamaximumnetmassof400kg;or(b)inprojectilesorhardcasedarticleswhencarriedwithoutClass1components:asspecifiedbythecompetentauthority.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/627P406PACKINGINSTRUCTIONP406Thefollowingpackagingsareauthorised,providedthatthegeneralprovisionsof4.1.1and4.1.3aremet:(1)Combinationpackagingsouterpackagings:(4C1,4C2,4D,4F,4G,4H1,4H2,1G,1D,1H2or3H2)innerpackagings:water-resistantpackagings;(2)plastics,plywoodorfibreboarddrums(1H2,1Dor1G)orboxes(4A,4B,4C1,4D,4F,4C2,4Gand4H2)withawaterresistantinnerbag,plasticsfilmliningorwaterresistantcoating;(3)metaldrums(1A1,1A2,1B1,1B2,1N1or1N2),plasticsdrums(1H1or1H2),metaljerricans(3A1,3A2,3B1or3B2),plasticsjerricans(3H1or3H2),plasticsreceptaclewithoutersteeloraluminiumdrums(6HA1or6HB1),plasticsreceptaclewithouterfibre,plasticsorplywooddrums(6HG1,6HH1or6HD1),plasticsreceptaclewithoutersteeloraluminiumcrateorboxorwithouterwooden,plywood,fibreboardorsolidplasticsboxes(6HA2,6HB2,6HC,6HD2,6HG2or6HH2).Additionalrequirements:1.Packagingsshallbedesignedandconstructedtopreventthelossofwateroralcoholcontentorthecontentofthephlegmatiser.2.Packagingsshallbesoconstructedandclosedsoastoavoidanexplosiveoverpressureorpressurebuild-upofmorethan300kPa(3bar).3.Thetypeofpackagingandmaximumpermittedquantityperpackagingarelimitedwhenthispackinginstructionisappliedinaccordancewithspecialprovisions15or18ofChapter3.3.Specialpackingprovisions:PP24ForUNNo2852,thequantitycarriedshallnotexceed500gperpackage.PP25ForUNNo1347,thequantitycarriedshallnotexceed15kgperpackage.PP26ForUNNos1310,1320,1321,1322,1344,1347,1348,1349,1517,2907,3317and3344packagingsshallbeleadfree.P407PACKINGINSTRUCTIONP407ThisinstructionappliestoUNNos1331,1944,1945and2254.Thefollowingpackagingsareauthorised,providedthatthegeneralprovisionsof4.1.1and4.1.3aremet:Combinationpackagingscomprisingsecurelyclosedinnerpackagingstopreventaccidentalignitionundernormalconditionsoftransport.Themaximumnetmassoftheouterpackagingsshallnotexceed45kgexceptforfibreboardboxeswhichshallnotexceed30kg.Additionalrequirement:Matchesshallbetightlypacked.Specialpackingprovision:PP27UNNo1331,Strike-anywherematchesshallnotbepackedinthesameouterpackagingwithanyotherdangerousgoodsotherthansafetymatchesorwaxvestamatches,whichshallbepackedinseparateinnerpackagings.Innerpackagingsshallnotcontainmorethan700strike-anywherematches.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/628P408PACKINGINSTRUCTIONP408ThisinstructionappliestoUNNo3292.Thefollowingpackagingsareauthorised,providedthatthegeneralprovisionsof4.1.1and4.1.3aremet:(1)forcells:outerpackagingswithsufficientcushioningmaterialtopreventcontactbetweencellsandbetweencellsandtheinternalsurfacesoftheouterpackagingandtoensurethatnodangerousmovementofthecellswithintheouterpackagingoccursduringcarriage.PackagingsshallconformtothepackinggroupIIperformancelevel;(2)forbatteries:batteriesmaybecarriedunpackedorinprotectiveenclosures(e.g.infullyenclosedorwoodenslattedcrates).Theterminalsshallnotsupporttheweightofotherbatteriesormaterialspackedwiththebatteries.Additionalrequirement:Batteriesshallbeprotectedagainstshortcircuitandshallbeisolatedinsuchamannerastopreventshortcircuits.P409PACKINGINSTRUCTIONP409ThisinstructionappliestoUNNos2956,3242and3251.Thefollowingpackagingsareauthorised,providedthatthegeneralprovisionsof4.1.1and4.1.3aremet:(1)Fibredrum(1G)whichmaybefittedwithalinerorcoating;maximumnetmass:50kg;(2)Combinationpackagings:Fibreboardbox(4G)withasingleinnerplasticbag;maximumnetmass:50kg;(3)Combinationpackagings:fibreboardbox(4G)orfibredrum(1G)withplasticsinnerpackagingseachcontainingamaximumof5kg;maximumnetmass:25kg.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/629P410PACKINGINSTRUCTIONP410Thefollowingpackagingsareauthorised,providedthatthegeneralprovisionsof4.1.1and4.1.3aremet:Combinationpackagings:InnerpackagingsOuterpackagingsMaximumnetmassPackinggroupIIPackinggroupIIIGlass10kgPlastics(a)30kgMetal40kgPaper(a)(b)10kgFibre(a)(b)10kgDrumssteel(1A2)400kg400kgaluminium(1B2)400kg400kgmetalotherthansteeloraluminium(1N2)400kg400kgplastics(1H2)400kg400kgplywood(1D)400kg400kgfibre(1G)(a)400kg400kgBoxessteel(4A)400kg400kgaluminium(4B)400kg400kgnaturalwood(4C1)400kg400kgnaturalwoodwithsift-proofwalls(4C2)400kg400kgplywood(4D)400kg400kgreconstitutedwood(4F)400kg400kgfibreboard(4G)(a)400kg400kgexpandedplastics(4H1)60kg60kgsolidplastics(4H2)400kg400kgJerricanssteel(3A2)120kg120kgaluminium(3B2)120kg120kgplastics(3H2)120kg120kgSinglepackagings:PackinggroupIIPackinggroupIIIDrumssteel(1A1or1A2)400kg400kgaluminium(1B1or1B2)400kg400kgmetalotherthansteeloraluminium(1N1or1N2)400kg400kgplastics(1H1or1H2)400kg400kgJerricanssteel(3A1or3A2)120kg120kgaluminium(3B1or3B2)120kg120kgplastics(3H1or3H2)120kg120kgBoxessteel(4A)(c)400kg400kgaluminium(4B)(c)400kg400kgnaturalwood(4C1)(c)400kg400kgplywood(4D)(c)400kg400kgreconstitutedwood(4F)(c)400kg400kgnaturalwoodwithsift-proofwalls(4C2)(c)400kg400kgfibreboard(4G)(c)400kg400kgsolidplastics(4H2)(c)400kg400kgBagsBags(5H3,5H4,5L3,5M2)(c)(d)50kg50kgCompositepackagingsplasticsreceptaclewithoutersteel,aluminium,plywood,fibreorplasticsdrum(6HA1,6HB1,6HG1,6HD1,or6HH1)400kg400kgplasticsreceptaclewithoutersteeloraluminiumcrateorbox,orouterwooden,plywood,fibreboardorsolidplasticsbox(6HA2,6HB2,6HC,6HD2,6HG2or6HH2)75kg75kgglassreceptaclewithoutersteel,aluminium,plywoodorfibredrum(6PA1,6PB1,6PD1or6PG1)oroutersteeloraluminiumcrateorboxorwithouterwoodenorfibreboardboxorwithouterwickerworkhamper(6PA2,6PB2,6PC,6PD2,or6PG2)orwithoutersolidorexpandedplasticspackaging(6PH1or6PH2)75kg75kgOfficialJournaloftheEuropeanUnionEN26.1.2004L18/630P410PACKINGINSTRUCTIONP410Specialpackingprovisions:PP39ForUNNo1378,formetalpackagingsaventingdeviceisrequired.PP40ForUNNos1326,1352,1358,1395,1396,1404,1436,1437,1485,1495,1871,2805,3182and3247,packinggroupII,bagsarenotallowed.(a)Theseinnerpackagingsshallbesift-proof.(b)Theseinnerpackagingsshallnotbeusedwhenthesubstancesbeingcarriedmaybecomeliquidduringcarriage.(c)Thesepackagingsshallnotbeusedwhenthesubstancesbeingcarriedmaybecomeliquidduringcarriage.(d)ThesepackagingsshallonlybeusedforpackinggroupIIsubstanceswhencarriedinaclosedvehicleorcontainer.P411PACKINGINSTRUCTIONP411ThisinstructionappliestoUNNo3270.Thefollowingpackagingsareauthorised,providedthatthegeneralprovisionsof4.1.1and4.1.3aremet:(1)fibreboardboxwithamaximumgrossmassof30kg;(2)otherpackagings,providedthatexplosionisnotpossiblebyreasonofincreasedinternalpressure.Maximumnetmassshallnotexceed30kg.P500PACKINGINSTRUCTIONP500ThisinstructionappliestoUNNo3356.Thegeneralprovisionsof4.1.1and4.1.3shallbemet.PackagingsshallconformtothepackinggroupIIperformancelevel.Thegenerator(s)shallbecarriedinapackagewhichmeetsthefollowingrequirementswhenonegeneratorinthepackageisactuated:(a)othergeneratorsinthepackagewillnotbeactuated;(b)packagingmaterialwillnotignite;and(c)theoutsidesurfacetemperatureofthecompletedpackageshallnotexceed100°C.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/631P501PACKINGINSTRUCTIONP501ThisinstructionappliestoUNNo2015.Thefollowingpackagingsareauthorised,providedthatthegeneralprovisionsof4.1.1and4.1.3aremet:Combinationpackagings:Innerpacka-gingmaximumcapacityOuterpacka-gingmaximumnetmass(1)Boxes(4A,4B,4C1,4C2,4D,4H2)ordrums(1A2,1B2,1N2,1H2,1D)orjerricans(3A2,3B2,3H2)withglass,plasticsormetalinnerpackagings5l125kg(2)Fibreboardbox(4G)orfibredrum(1G),withplasticsormetalinnerpackagingseachinaplasticsbag2l50kgSinglepackagings:MaximumcapacityDrums250lsteel(1A1)aluminium(1B1)metalotherthansteeloraluminium(1N1)plastics(1H1)Jerricans60lsteel(3A1)aluminium(3B1)plastics(3H1)Compositepackagingsplasticsreceptaclewithoutersteeloraluminiumdrum(6HA1,6HB1)250lplasticsreceptaclewithouterfibre,plasticsorplywooddrum(6HG1,6HH1,6HD1)250lplasticsreceptaclewithoutersteeloraluminiumcrateorboxorplasticsreceptaclewithouterwooden,plywood,fibreboardorsolidplasticsbox(6HA2,6HB2,6HC,6HD2,6HG2or6HH2)60lglassreceptaclewithoutersteel,aluminium,fibre,plywood,solidplasticsorexpandedplasticsdrum(6PA1,6PB1,6PG1,6PD1,6PH1or6PH2)orwithoutersteeloraluminiumcrateorboxorwithouterwoodenorfibreboardboxorwithouterwickerworkhamper(6PA2,6PB2,6PC,6PG2or6PD2)60lAdditionalrequirements:1.Packagingsshallhaveamaximumfillingdegreeof90%.2.Packagingsshallbevented.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/632P502PACKINGINSTRUCTIONP502Thefollowingpackagingsareauthorised,providedthatthegeneralprovisionsof4.1.1and4.1.3aremet:Combinationpackagings:InnerpackagingsOuterpackagingsMaximumnetmassGlass5lMetal5lPlastics5lDrumssteel(1A2)125kgaluminium(1B2)125kgmetalotherthansteeloraluminium(1N2)125kgplastics(1H2)125kgplywood(1D)125kgfibre(1G)125kgBoxessteel(4A)125kgaluminium(4B)125kgnaturalwood(4C1)125kgnaturalwoodwithsift-proofwalls(4C2)125kgplywood(4D)125kgreconstitutedwood(4F)125kgfibreboard(4G)125kgexpandedplastics(4H1)60kgsolidplastics(4H2)125kgSinglepackagings:MaximumcapacityDrumssteel(1A1)250laluminium(1B1)plastics(1H1)Jerricanssteel(3A1)60laluminium(3B1)plastics(3H1)Compositepackagingsplasticsreceptaclewithoutersteeloraluminiumdrum(6HA1,6HB1)250lplasticsreceptaclewithouterfibre,plasticsorplywooddrum(6HG1,6HH1,6HD1)250lplasticsreceptaclewithoutersteeloraluminiumcrateorboxorplasticsreceptaclewithouterwooden,plywood,fibreboardorsolidplasticsbox(6HA2,6HB2,6HC,6HD2,6HG2or6HH2)60lglassreceptaclewithoutersteel,aluminium,fibre,plywood,solidplasticsorexpandedplasticsdrum(6PA1,6PB1,6PG1,6PD1,6PH1or6PH2)orwithoutersteeloraluminiumcrateorboxorwithouterwoodenorfibreboardboxorwithouterwickerworkhamper(6PA2,6PB2,6PC,6PG2or6PD2)60lSpecialpackingprovision:PP28ForUNNo1873,onlyglassinnerpackagingsandglassinnerreceptaclesareauthorisedrespectivelyforcombinationpackagingsandcompositepackagings.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/633P503PACKINGINSTRUCTIONP503Thefollowingpackagingsareauthorised,providedthatthegeneralprovisionsof4.1.1and4.1.3aremet:Combinationpackagings:InnerpackagingsOuterpackagingsMaximumnetmassGlass5kgMetal5kgPlastics5kgDrumssteel(1A2)125kgaluminium(1B2)125kgmetalotherthansteeloraluminium(1N2)125kgplastics(1H2)125kgplywood(1D)125kgfibre(1G)125kgBoxessteel(4A)125kgaluminium(4B)125kgnaturalwood(4C1)125kgnaturalwoodwithsift-proofwalls(4C2)125kgplywood(4D)125kgreconstitutedwood(4F)125kgfibreboard(4G)40kgexpandedplastics(4H1)60kgsolidplastics(4H2)125kgSinglepackagings:Metaldrums(1A1,1A2,1B1,1B2,1N1or1N2)withamaximumnetmassof250kg.Fibreboard(1G)orplywooddrums(1D)fittedwithinnerlinerswithamaximumnetmassof200kg.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/634P504PACKINGINSTRUCTIONP504Thefollowingpackagingsareauthorised,providedthatthegeneralprovisionsof4.1.1and4.1.3aremet:Combinationpackagings:Maximumnetmass(1)Glassreceptacleswithamaximumcapacityof5litresin1A2,1B2,1N2,1H2,1D,1G,4A,4B,4C1,4C2,4D,4F,4G,4H2outerpackagings75kg(2)Plasticsreceptacleswithamaximumcapacityof30litresin1A2,1B2,1N2,1H2,1D,1G,4A,4B,4C1,4C2,4D,4F,4G,4H2outerpackagings75kg(3)Metalreceptacleswithamaximumcapacityof40litresin1G,4For4Gouterpackagings125kg(4)Metalreceptacleswithamaximumcapacityof40litresin1A2,1B2,1N2,1H2,1D,4A,4B,4C1,4C2,4D,4H2outerpackagings225kgSinglepackagings:MaximumcapacityDrumssteel,non-removablehead(1A1)250lsteel,removablehead(1A2)250laluminium,non-removablehead(1B1)250laluminium,removablehead(1B2)250lmetalotherthansteeloraluminium,non-removablehead(1N1)250lmetalotherthansteeloraluminium,removablehead(1N2)250lplastics,non-removablehead(1H1)250lplastics,removablehead(3H2)250lJerricanssteel,non-removablehead(3A1)60lenacieràdessusamovible(3A2)60laluminium,non-removablehead(3B1)60lenaluminiumàdessusamovible(3B2)60lplastics,non-removablehead(3H1)60lenplastiqueàdessusamovible(3H2)60lCompositepackagings:plasticsreceptaclewithoutersteeloraluminiumdrum(6HA1,6HB1)250lplasticsreceptaclewithouterfibre,plasticsorplywooddrum(6HG1,6HH1,6HD1)120lplasticsreceptaclewithoutersteeloraluminiumcrateorboxorplasticsreceptaclewithouterwooden,plywood,fibreboardorsolidplasticsbox(6HA2,6HB2,6HC,6HD2,6HG2or6HH2)60lglassreceptaclewithoutersteel,aluminium,fibre,plywood,solidplasticsorexpandedplasticsdrum(6PA1,6PB1,6PG1,6PD1,6PH1or6PH2)orwithoutersteeloraluminiumcrateorboxorwithouterwoodenfibreboardboxorwithouterwickerworkhamper(6PA2,6PB2,6PC,6PG2or6PD2)60lSpecialpackingprovisions:PP10ForUNNo2014PGIIandUNNo2984PGIII,thepackagingshallbevented.PP29ForUNNo2014,maximumdegreeoffillingshallbe90%.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/635P520PACKINGINSTRUCTIONP520ThisinstructionappliestoorganicperoxidesofClass5.2andself-reactivesubstancesofClass4.1Thepackagingslistedbelowareauthorisedprovidedthegeneralprovisionsof4.1.1and4.1.3andspecialprovisionsof4.1.7aremet:ThepackingmethodsaredesignatedOP1toOP8.Thepackingmethodsappropriatefortheindividualcurrentlyassignedorganicperoxidesandself-reactivesubstancesarelistedin4.1.7.1.3,2.2.41.4and2.2.52.4.Thequantitiesspecifiedforeachpackingmethodarethemaximumquantitiesauthorisedperpackage.Thefollowingpackagingsareauthorised:(1)combinationpackagingswithouterpackagingscomprisingboxes(4A,4B,4C1,4C2,4D,4F,4G,4H1and4H2),drums(1A2,1B2,1G,1H2and1D),jerricans(3A2,3B2and3H2);(2)singlepackagingsconsistingofdrums(1A1,1A2,1B1,1B2,1G,1H1,1H2and1D)andjerricans(3A1,3A2,3B1,3B2,3H1and3H2);(3)compositepackagingswithplasticsinnerreceptacles(6HA1,6HA2,6HB1,6HB2,6HC,6HD1,6HD2,6HG1,6HG2,6HH1and6HH2).Maximumquantityperpackaging/package(a)forpackingmethodsOP1toOP8PackingmethodMaximumquantityOP1OP2(a)OP3OP4(a)OP5OP6OP7OP8Maximummass(kg)forsolidsandforcombinationpackagings(liquidandsolid)0,50,5/1055/25255050200(b)Maximumcontentsinlitresforliquids(c)0,5—5—306060225(d)(a)Iftwovaluesaregiven,thefirstappliestothemaximumnetmassperinnerpackagingandthesecondtothemaximumnetmassofthecompletepackage.(b)60kgforjerricans/100kgforboxes.(c)Viscoussubstancesshallbetreatedassolidswhentheydonotmeetthecriteriaprovidedinthedefinitionfor‘liquids’presentedin1.2.1.(d)60litresforjerricans.Additionalrequirements:1.Metalpackagings,includinginnerpackagingsofcombinationpackagingsandouterpackagingsofcombinationorcompositepackagingsmayonlybeusedforpackingmethodsOP7andOP8.2.Incombinationpackagings,glassreceptaclesmayonlybeusedasinnerpackagingswithmaximumcontentsof0,5kgforsolidsor0,5litreforliquids.3.Incombinationpackagings,cushioningmaterialsshallnotbereadilycombustible.4.Thepackagingofanorganicperoxideorself-reactivesubstancerequiredtobearan‘EXPLOSIVE’subsidiaryrisklabelshallalsocomplywiththeprovisionsgivenin4.1.5.10and4.1.5.11.Specialpackingprovisions:PP21Forcertainself-reactivesubstancesoftypesBorC,UNNos3221,3222,3223,3224,3231,3232,3233and3234,asmallerpackagingthanthatallowedbypackingmethodsOP5orOP6respectivelyshallbeused(see4.1.6and2.2.41.4).PP22UNNo3241,2-Bromo-2-nitropropane-1,3-diol,shallbepackedinaccordancewithpackingmethodOP6.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/636P600PACKINGINSTRUCTIONP600ThisinstructionappliestoUNNos1700,2016and2017.Thefollowingpackagingsareauthorised,providedthegeneralprovisionsof4.1.1and4.1.3aremet:outerpackagings(1A2,1B2,1N2,1H2,1D,1G,4A,4B,4C1,4C2,4D,4F,4G,4H2)meetingthepackinggroupIIperformancelevel.Thearticlesshallbeindividuallypackagedandseparatedfromeachotherusingpartitions,dividers,innerpackagingsorcushioningmaterialtopreventinadvertentdischargeduringnormalconditionsofcarriage.Maximumnetmass:75kgP601PACKINGINSTRUCTIONP601Thefollowingpackagingsareauthorisedprovidedthegeneralprovisionsof4.1.1and4.1.3aremet(seealsotheTableof4.1.4.4):(1)combinationpackagingsconsistingofglassinnerpackagingsnotexceeding1litreincapacitypackedwithabsorbentmaterialsufficienttoabsorbtheentirecontentsandinertcushioningmaterialplacedinmetalreceptacleswhichareindividuallypackedin1A2,1B2,1N2,1H2,1D,1G,4A,4B,4C1,4C2,4D,4F,4Gor4H2outerpackagingswithamaximumgrossmassof15kg.Innerpackagingsshallnotbefilledtomorethan90%oftheircapacity.Theclosureofeachinnerpackagingshallbephysicallyheldinplacebyanymeanscapableofpreventingback-offorlooseningoftheclosurebyimpactorvibrationduringcarriage;(2)combinationpackagingsconsistingofmetalinnerpackagingsoradditionally,forUNNo1744only,inpolyvinylidenefluoride(PVDF)innerpackagings,notexceeding5litresincapacityindividuallypackedwithabsorbentmaterialsufficienttoabsorbthecontentsandinertcushioningmaterialin1A2,1B2,1N2,1H2,1D,1G,4A,4B,4C1,4C2,4D,4F,4Gor4H2outerpackagingswithamaximumgrossmassof75kg.Innerpackagingsshallnotbefilledtomorethan90%oftheircapacity.Theclosureofeachinnerpackagingshallbephysicallyheldinplacebyanymeanscapableofpreventingback-offorlooseningoftheclosurebyimpactorvibrationduringcarriage;(3)combinationpackagings:outerpackagings:Plasticorsteeldrums,removablehead(1A2or1H2)testedinaccordancewiththetestrequirementsin6.1.5ascombinationpackagingsasassembledforcarriage;innerpackagings:drumsandcompositepackagings(1A1,1B1,1N1,1H1or6HA1)meetingtherequirementsofChapter6.1forsinglepackagings,subjecttothefollowingconditions:(a)thehydraulicpressuretestshallbeconductedatapressureofatleast0,3MPa(gaugepressure);(b)thedesignandproductionleakproofnesstestsshallbeconductedatatestpressureof30kPa;(c)theyshallbeisolatedfromtheouterdrumbytheuseofinertshock-mitigatingcushioningmaterialwhichsurroundstheinnerpackagingonallsides;(d)theircapacityshallnotexceed125litres;and(e)closuresshallbeofascrewcaptypethatare:(i)physicallyheldinplacebyanymeanscapableofpreventingback-offorlooseningoftheclosurebyimpactorvibrationduringcarriage;and(ii)providedwithacapseal;(f)theinnerpackagingshallbetestedperiodicallyatleasteveryfiveyearsaccordingto(a)and(b);(g)thecompletepackagingshallbevisuallyinspectedtothesatisfactionofthecompetentauthorityatleasteverythreeyears;(h)theouterandinnerpackagingshallbearinclearlylegibleanddurablecharacters:(i)thedate(month,year)oftheinitialtestandthelatestperiodictestandinspection;(ii)thestampoftheexpertwhocarriedoutthetestandinspection;(4)gascylindersandgasreceptacles,whichshallcomplywiththeappropriaterequirementsoftheTableof4.1.4.4.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/637P602PACKINGINSTRUCTIONP602Thefollowingpackagingsareauthorisedprovidedthegeneralprovisionsof4.1.1and4.1.3aremet:(1)combinationpackagingsconsistingofglassinnerpackagingspackedwithabsorbentmaterialsufficienttoabsorbtheentirecontentsandinertcushioningmaterialplacedinmetalreceptacleswhichareindividuallypackedin1A2,1B2,1N2,1H2,1D,1G,4A,4B,4C1,4C2,4D,4F,4Gor4H2outerpackagingswithamaximumgrossmassof50kg.Innerpackagingsshallnotbefilledtomorethan90%oftheircapacity.Theclosureofeachinnerpackagingshallbephysicallyheldinplacebyanymeanscapableofpreventingback-offorlooseningoftheclosurebyimpactorvibrationduringcarriage.Innerpackagingsshallnotexceed1litreincapacity;(2)combinationpackagingsconsistingofmetalinnerpackagingsindividuallypackedwithabsorbentmaterialsufficienttoabsorbtheentirecontentsandinertcushioningmaterialin1A2,1B2,1N2,1H2,1D,1G,4A,4B,4C1,4C2,4D,4F,4Gor4H2outerpackagingswithamaximumgrossmassof75kg.Innerpackagingsshallnotbefilledtomorethan90%oftheircapacity.Theclosureofeachinnerpackagingshallbephysicallyheldinplacebyanymeanscapableofpreventingback-offorlooseningoftheclosurebyimpactorvibrationduringcarriage.Innerpackagingsshallnotexceed5litresincapacity;(3)drumsandcompositepackagings(1A1,1B1,1N1,1H1or6HA1),subjecttothefollowingconditions:(a)thehydraulicpressuretestshallbeconductedatapressureofatleast0,3MPa(gaugepressure);(b)thedesignandproductionleakproofnesstestsshallbeconductedatatestpressureof30kPa;and(c)closuresshallbeofascrewcaptypethatare:(i)physicallyheldinplacebyanymeanscapableofpreventingback-offorlooseningoftheclosurebyimpactorvibrationduringcarriage;and(ii)providedwithacapseal;(4)gascylindersandgasreceptacleswithaminimumtestpressureof1MPa(gaugepressure)conformingtotheprovisionsofP200.Nocylindermaybeequippedwithanypressurereliefdevice.Gascylindersandgasreceptaclesshallhavetheirvalvesprotected.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/638P620PACKINGINSTRUCTIONP620ThisinstructionappliestoUNNos2814and2900.Thefollowingpackagingsareauthorisedprovidedthespecialpackingprovisionsof4.1.8aremet:PackagingsmeetingtherequirementsofChapter6.3andapprovedaccordinglyconsistingof:(a)innerpackagingscomprising:(i)leakproofprimaryreceptacle(s);(ii)aleakproofsecondarypackaging;(iii)otherthanforsolidinfectioussubstances,anabsorbentmaterialinsufficientquantitytoabsorbtheentirecontentsplacedbetweentheprimaryreceptacle(s)andthesecondarypackaging;ifmultipleprimaryreceptaclesareplacedinasinglesecondarypackaging,theyshallbeindividuallywrappedsoastopreventcontactbetweenthem;(b)anouterpackagingofadequatestrengthforitscapacity,massandintendeduse.Thesmallestexternaldimensionshallbeatleast100mm.Additionalrequirements:1.Innerpackagingscontaininginfectioussubstancesshallnotbeconsolidatedwithinnerpackagingscontainingunrelatedtypesofgoods.Completepackagesmaybeoverpackedinaccordancewiththeprovisionsof1.2.1and5.1.2;suchanoverpackmaycontaindryice.2.Otherthanforexceptionalconsignments,e.g.wholeorganswhichrequirespecialpackaging,thefollowingadditionalrequirementsshallapply:(a)lyophilisedsubstances:primaryreceptaclesshallbeflame-sealedglassampoulesorrubber-stopperedglassvialsfittedwithmetalseals;(b)liquidorsolidsubstances:(i)substancesconsignedatambienttemperaturesoratahighertemperature.Primaryreceptaclesshallbeofglass,metalorplastics.Positivemeansofensuringaleakproofsealshallbeprovided,e.g.aheatseal,askirtedstopperorametalcrimpseal.Ifscrewcapsareused,theyshallbereinforcedwithadhesivetape;(ii)substancesconsignedrefrigeratedorfrozen.Ice,dryiceorotherrefrigerantshallbeplacedaroundthesecondarypackaging(s)oralternativelyinanoverpackwithoneormorecompletepackagesmarkedinaccordancewith6.3.1.1.Interiorsupportsshallbeprovidedtosecuresecondarypackaging(s)orpackagesinpositionaftertheiceordryicehasdissipated.Ificeisused,theouterpackagingoroverpackshallbeleakproof.Ifdryiceisused,theouterpackagingoroverpackshallpermitthereleaseofcarbondioxidegas.Theprimaryreceptacleandthesecondarypackagingshallmaintaintheirintegrityatthetemperatureoftherefrigerantused;(iii)substancesconsignedinliquidnitrogen.Plasticsprimaryreceptaclescapableofwithstandingverylowtemperatureshallbeused.Thesecondarypackagingshallalsobecapableofwithstandingverylowtemperatures,andinmostcaseswillneedtobefittedovertheprimaryreceptacleindividually.ProvisionsfortheconsignmentofliquidnitrogenshallalsobefulfilledinaccordancewiththerequirementsofP200.Theprimaryreceptacleandthesecondarypackagingshallmaintaintheirintegrityatthetemperatureoftheliquidnitrogen.3.Whatevertheintendedtemperatureoftheconsignment,theprimaryreceptacleorthesecondarypackagingshallbecapableofwithstandingwithoutleakageaninternalpressureproducingapressuredifferentialofnotlessthan95kPaandtemperaturesintherange–40°Cto+55°C.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/639P621PACKINGINSTRUCTIONP621ThisinstructionappliestoUNNo3291.Thefollowingpackagingsareauthorisedprovidedthegeneralprovisionsof4.1.1and4.1.3aremet:(1)rigid,leakproofpackagingsmeetingtherequirementsofChapter6.1forsolids,atthepackinggroupIIperformancelevel,providedthereissufficientabsorbentmaterialtoabsorbtheentireamountofliquidpresentandthepackagingiscapableofretainingliquids;(2)forpackagescontaininglargerquantitiesofliquid,rigidpackagingsmeetingtherequirementsofChapter6.1atthepackinggroupIIperformancelevelforliquids.Additionalrequirement:PackagingsintendedtocontainsharpobjectssuchasbrokenglassandneedlesshallberesistanttopunctureandretainliquidsundertheperformancetestconditionsinChapter6.1.P650PACKINGINSTRUCTIONP650ThisinstructionappliestodiagnosticspecimensDiagnosticspecimensmaybecarriedineither:(1)packagingsthatmeetthefollowingconditions:(a)theprimaryreceptaclesdonotcontainmorethan100ml;(b)theouterpackagingdoesnotcontainmorethan500ml;(c)theprimaryreceptaclesareleakproof;and(d)thepackagingsareinaccordancewithP620.However,theyneednotbesubjectedtothetests;or(2)packagingsthatcomplywithstandardEN829:1996.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/640P800PACKINGINSTRUCTIONP800ThisinstructionappliestoUNNos2809and2803.Thefollowingpackagingsareauthorised,providedthegeneralprovisionsof4.1.1and4.1.3aremet:(1)cylindersinaccordancewithP200;or(2)steelflasksorbottleswiththreadedclosureswithacapacitynotexceeding2,5l;or(3)combinationpackagingswhichconformtothefollowingrequirements:(a)innerpackagingsshallcompriseglass,metalorrigidplasticsintendedtocontainliquidswithamaximumnetmassof15kgeach;(b)theinnerpackagingsshallbepackedwithsufficientcushioningmaterialtopreventbreakage;(c)eithertheinnerpackagingsortheouterpackagingsshallhaveinnerlinersorbagsofstrongleakproofandpuncture-resistantmaterialimpervioustothecontentsandcompletelysurroundingthecontentstopreventitfromescapingfromthepackageirrespectiveofitspositionororientation;(d)thefollowingouterpackagingsandmaximumnetmassesareauthorised:Outerpackaging:MaximumnetmassDrumssteel(1A2)400kgmetalotherthansteeloraluminium(1N2)400kgplastics(1H2)400kgplywood(1D)400kgfibre(1G)400kgBoxessteel(4A)400kgnaturalwood(4C1)250kgnaturalwoodwithsift-proofwalls(4C2)250kgplywood(4D)250kgreconstitutedwood(4F)125kgfibreboard(4G)125kgexpandedplastics(4H1)60kgsolidplastics(4H2)125kgSpecialpackingprovision:PP41ForUNNo2803,whenitisnecessarytocarrygalliumatlowtemperaturesinordertomaintainitinacompletelysolidstate,theabovepackagingsmaybeoverpackedinastrong,water-resistantouterpackagingwhichcontainsdryiceorothermeansofrefrigeration.Ifarefrigerantisused,alloftheabovematerialsusedinthepackagingofgalliumshallbechemicallyandphysicallyresistanttotherefrigerantandshallhaveimpactresistanceatthelowtemperaturesoftherefrigerantemployed.Ifdryiceisused,theouterpackagingshallpermitthereleaseofcarbondioxidegas.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/641P801PACKINGINSTRUCTIONP801ThisinstructionappliestonewbatteriesassignedtoUNNos2794,2795or3028.Thefollowingpackagingsareauthorised,providedthegeneralprovisionsof4.1.1and4.1.3aremet:(1)rigidouterpackagings;(2)woodenslattedcrates;(3)pallets.Additionalrequirements:1.Batteriesshallbeprotectedagainstshortcircuits.2.Batteriesstackedshallbeadequatelysecuredintiersseparatedbyalayerofnonconductivematerial.3.Batteryterminalsshallnotsupporttheweightofothersuperimposedelements.4.Batteriesshallbepackagedorsecuredtopreventinadvertentmovement.Anycushioningmaterialusedshallbeinert.P801aPACKINGINSTRUCTIONP801aThisinstructionappliestousedbatteriesofUNNos2794,2795,2800and3028.Stainlesssteelorsolidplasticsbatteryboxesofacapacityofupto1m3areauthorisedprovidedthefollowingprovisionsaremet:(1)thebatteryboxesshallberesistanttothecorrosivesubstancescontainedinthestoragebatteries;(2)undernormalconditionsofcarriage,nocorrosivesubstanceshallleakfromthebatteryboxesandnoothersubstance(e.g.water)shallenterthebatteryboxes.Nodangerousresiduesofcorrosivesubstancescontainedinthestoragebatteriesshalladheretotheoutsideofthebatteryboxes;(3)thebatteryboxesshallnotbeloadedwithstoragebatteriestoaheightgreaterthantheheightoftheirsides;(4)nostoragebatterycontainingsubstancesorotherdangerousgoodswhichmayreactdangerouslywithoneanothershallbeplacedinabatterybox;(5)thebatteryboxesshallbeeither:(a)covered;or(b)carriedinclosedorsheetedvehiclesorcontainers.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/642P802PACKINGINSTRUCTIONP802Thefollowingpackagingsareauthorised,providedthegeneralprovisionsof4.1.1and4.1.3aremet:(1)combinationpackagings:—outerpackagings:1A2,1B2,1N2,1H2,1D,4A,4B,4C1,4C2,4D,4F,or4H2;—maximumnetmass:75kg.—innerpackagings:glassorplastics;maximumcapacity:10litres;(2)combinationpackagings:—outerpackagings:1A2,1B2,1N2,1H2,1D,1G,4A,4B,4C1,4C2,4D,4F,4Gor4H2;—maximumnetmass:125kg.—innerpackagings:metal;maximumcapacity:40litres;(3)compositepackagings:Glassreceptaclewithoutersteel,aluminium,plywoodorsolidplasticsdrum(6PA1,6PB1,6PD1,or6PH2)orwithoutersteeloraluminiumcrateorboxorwithouterwoodenboxorwithouterwickerworkhamper(6PA2,6PB2,6PCor6PD2);maximumcapacity:60litres;(4)austeniticsteeldrums(1A1)withamaximumcapacityof250litres;(5)gascylindersconformingtotheconstruction,testingandfillingrequirementsapprovedbythecompetentauthority.P803PACKINGINSTRUCTIONP803ThisinstructionappliestoUNNo2028.Thefollowingpackagingsareauthorised,providedthegeneralprovisionsof4.1.1and4.1.3aremet:(1)drums(1A2,1B2,1N2,1H2,1D,1G);(2)boxes(4A,4B,4C1,4C2,4D,4F,4G,4H2).Maximumnetmass:75kg.Thearticlesshallbeindividuallypackagedandseparatedfromeachotherusingpartitions,dividers,innerpackagingsorcushioningmaterialtopreventinadvertentdischargeduringnormalconditionsofcarriage.P900PACKINGINSTRUCTIONP900(Reserved)P901PACKINGINSTRUCTIONP901ThisinstructionappliestoUNNo3316.Thefollowingpackagingsareauthorised,providedthegeneralprovisionsof4.1.1and4.1.3aremet:packagingsconformingtotheperformancelevelconsistentwiththepackinggroupassignedtothekitasawhole(see3.3.1,specialprovision251).Maximumquantityofdangerousgoodsperouterpackaging:10kg.Additionalrequirement:Dangerousgoodsinkitsshallbepackedininnerpackagingswhichshallnotexceedeither250mlor250gandshallbeprotectedfromothermaterialsinthekit.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/643P902PACKINGINSTRUCTIONP902ThisinstructionappliestoUNNo3268.Thefollowingpackagingsareauthorised,providedthegeneralprovisionsof4.1.1and4.1.3aremet:packagingsconformingtothepackinggroupIIIperformancelevel.Eachpackagingshallconformtospecialprovision235(see3.3.1)andshallconformtothepackinggroupIIIperformancelevel.Thepackagingshallbedesignedandconstructedtopreventmovementofthearticlesandinadvertentdischargeduringnormalconditionsofcarriage;thearticlesmayalsobecarriedunpackagedindedicatedhandlingdevices,vehiclesorcontainerswhenmovedfromwheretheyaremanufacturedtoanassemblyplant.P903PACKINGINSTRUCTIONP903ThisinstructionappliestoUNNos3090and3091.Thefollowingpackagingsareauthorised,providedthegeneralprovisionsof4.1.1and4.1.3aremet:packagingsconformingtopackinggroupIIperformancelevel;whenlithiumcellsandbatteriesarepackedwithequipment,theyshallbepackedininnerfibreboardpackagingsthatmeettherequirementsforpackinggroupII.WhenlithiumcellsandbatteriesincludedinClass9arecontainedinequipment,theequipmentshallbepackedinstrongouterpackagingsinsuchamannerastopreventaccidentaloperationduringcarriage.Additionalrequirement:Batteriesshallbeprotectedagainstshortcircuit.P903aPACKINGINSTRUCTIONP903aThisinstructionappliestousedcellsandbatteriesofUNNos3090and3091.Thefollowingpackagingsareauthorised,providedthegeneralprovisionsof4.1.1and4.1.3aremet:packagingsconformingtopackinggroupIIperformancelevel;non-approvedpackagingsshall,however,bepermittedprovidedthat:—theymeetthegeneralprovisionsof4.1.1and4.1.3;—thecellsandbatteriesarepackedandstowedsoastopreventanyriskofshortcircuits;—thepackagesweighnotmorethan30kg.Additionalrequirement:Batteriesshallbeprotectedagainstshortcircuit.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/644P904PACKINGINSTRUCTIONP904ThisinstructionappliestoUNNo3245.Thefollowingpackagingsareauthorised,providedthegeneralprovisionsof4.1.1and4.1.3aremet:(1)packagingsaccordingtoP001orP002;(2)outerpackagings,whichneednotconformtothepackagingtestrequirementsofPart6,butconformingtothefollowing:(a)aninnerpackagingcomprising:(i)awatertightprimaryreceptacle(s);(ii)awatertightsecondarypackagingwhichisleakproof;(iii)absorbentmaterialinsufficientquantitytoabsorbtheentirecontentsplacedbetweentheprimaryreceptacle(s)andthesecondarypackaging;ifseveralprimaryreceptaclesareplacedinasinglesecondarypackaging,theyshallbeindividuallywrappedsoastopreventcontactbetweenthem;(b)anouterpackagingofadequatestrengthforitscapacity,massandintendeduse,andwithaminimumexternaldimensionof100mm;(3)forsubstancesconsignedinliquidnitrogen:Plasticsprimaryreceptaclescapableofwithstandingverylowtemperaturesshallbeused.Thesecondarypackagingshallalsobecapableofwithstandingverylowtemperatures,andinmostcaseswillneedtobefittedovertheprimaryreceptacleindividually.ProvisionsfortheconsignmentofliquidnitrogenshallalsobefulfilledinaccordancewiththerequirementsofP200.Theprimaryreceptacleandthesecondarypackagingshallmaintaintheirintegrityatthetemperatureoftheliquidnitrogen.P905PACKINGINSTRUCTIONP905ThisinstructionappliestoUNNos3072and2990.Anysuitablepackagingisauthorised,providedthegeneralprovisionsof4.1.1and4.1.3aremet,exceptthatpackagingsneednotconformtotherequirementsofPart6.Whenthelife-savingappliancesareconstructedtoincorporateorarecontainedinrigidouterweatherproofcasings(suchasforlifeboats),theymaybecarriedunpackaged.Additionalrequirements:1.Alldangeroussubstancesandarticlescontainedasequipmentwithintheappliancesshallbesecuredtopreventinadvertentmovementandinaddition:(a)signaldevicesofClass1shallbepackedinplasticsorfibreboardinnerpackagings;(b)non-flammable,nontoxicgasesshallbecontainedincylindersasspecifiedbythecompetentauthority,whichmaybeconnectedtotheappliance;(c)electricstoragebatteries(Class8)andlithiumbatteries(Class9)shallbedisconnectedorelectricallyisolatedandsecuredtopreventanyspillageofliquid;and(d)smallquantitiesofotherdangeroussubstances(forexampleinClasses3,4.1and5.2)shallbepackedinstronginnerpackagings.2.Preparationfortransportandpackagingshallincludeprovisionstopreventanyaccidentalinflationoftheappliance.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/645P906PACKINGINSTRUCTIONP906ThisinstructionappliestoUNNos2315,3151and3152.Thefollowingpackagingsareauthorised,providedthegeneralprovisionsof4.1.1and4.1.3aremet:(1)forliquidsandsolidscontainingorcontaminatedwithPCBs:PackagingsinaccordancewithP001orP002,asappropriate;(2)fortransformersandcondensersandotherdevices:leakproofpackagingswhicharecapableofcontaining,inadditiontothedevices,atleast1,25timesthevolumeoftheliquidPCBspresentinthem.Thereshallbesufficientabsorbentmaterialinthepackagingstoabsorbatleast1,1timesthevolumeofliquidwhichiscontainedinthedevices.Ingeneral,transformersandcondensersshallbecarriedinleakproofmetalpackagingswhicharecapableofholding,inadditiontothetransformersandcondensers,atleast1,25timesthevolumeoftheliquidpresentinthem.Notwithstandingtheabove,liquidsandsolidsnotpackagedinaccordancewithP001andP002andunpackagedtransformersandcondensersmaybecarriedincargotransportunitsfittedwithaleakproofmetaltraytoaheightofatleast800mm,containingsufficientinertabsorbentmaterialtoabsorbatleast1,1timesthevolumeofanyfreeliquid.Additionalrequirement:Adequateprovisionsshallbetakentosealthetransformersandcondenserstopreventleakageduringnormalconditionsofcarriage.R001PACKINGINSTRUCTIONR001R001Thefollowingpackagingsareauthorisedprovidedthegeneralprovisionsof4.1.1and4.1.3aremet:LightgaugemetalpackagingsMaximumcapacity/maximumnetmassPackinggroupIPackinggroupIIPackinggroupIIISteelnon-removablehead(0A1)Notallowed40l/50kg40l/50kgSteelremovablehead(0A2)(a)Notallowed40l/50kg40l/50kg(a)NotallowedforUNNo1261NITROMETHANENotes1.Thisinstructionappliestosolidsandliquids(providedthedesigntypeistestedandmarkedappropriately).2.ForClass3,packinggroupII,thesepackagingsmaybeusedonlyforsubstanceswithnosubsidiaryriskandavapourpressureofnotmorethan110kPaat50°Candforslightlytoxicpesticides.Specialpackingprovision:RR3ForUNNos1204and3256,lightgaugemetalpackagingsarenotpermitted.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/6464.1.4.2.PackinginstructionsconcerningtheuseofIBCsIBC01PACKINGINSTRUCTIONIBC01ThefollowingIBCsareauthorised,providedthegeneralprovisionsof4.1.1,4.1.2and4.1.3aremet:metal(31A,31Band31N).Additionalrequirement:Onlyliquidswithavapourpressurelessthanorequalto110kPaat50°C,or130kPaat55°C,areauthorised.Specialpackingprovision:B12ForUNNo3130,theopeningsofreceptaclesforthissubstanceshallbetightlyclosedbymeansoftwodevicesinseries,oneofwhichshallbescrewedorsecuredinanequivalentmanner.IBC02PACKINGINSTRUCTIONIBC02ThefollowingIBCsareauthorised,providedthegeneralprovisionsof4.1.1,4.1.2and4.1.3aremet:(1)metal(31A,31Band31N);(2)rigidplastics(31H1and31H2);(3)composite(31HZ1).Additionalrequirement:Onlyliquidswithavapourpressurelessthanorequalto110kPaat50°C,or130kPaat55°C,areauthorised.Specialpackingprovisions:B5ForUNNos1791,2014and3149,IBCsshallbeprovidedwithadevicetoallowventingduringcarriage.TheinlettotheventingdeviceshallbesitedinthevapourspaceoftheIBCundermaximumfillingconditionsduringcarriage.B7ForUNNos1222and1865,IBCswithacapacitygreaterthan450litresarenotpermittedduetothesubstance'spotentialforexplosionwhencarriedinlargevolumes.B8ThepureformofthissubstanceshallnotbetransportedinIBCssinceitisknowntohaveavapourpressureofmorethan110kPaat50°Cor130kPaat55°C.B11Bottomopeningsarepermittedprovidedtheyarefittedwithtwoclosuredevicesinseries.IBC03PACKINGINSTRUCTIONIBC03ThefollowingIBCsareauthorised,providedthegeneralprovisionsof4.1.1,4.1.2and4.1.3aremet:(1)metal(31A,31Band31N);(2)rigidplastics(31H1and31H2);(3)composite(31HZ1,31HA2,31HB2,31HN2,31HD2and31HH2).Additionalrequirement:Onlyliquidswithavapourpressurelessthanorequalto110kPaat50°C,or130kPaat55°C,areauthorised.Specialpackingprovision:B8ThepureformofthissubstanceshallnotbecarriedinIBCssinceitisknowntohaveavapourpressureofmorethan110kPaat50°Cor130kPaat55°C.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/647IBC04PACKINGINSTRUCTIONIBC04ThefollowingIBCsareauthorised,providedthegeneralprovisionsof4.1.1,4.1.2and4.1.3aremet:metal(11A,11B,11N,21A,21B,21N,31A,31Band31N).Specialpackingprovision:B1ForpackinggroupIsubstances,IBCsshallbecarriedinclosedvehiclesorcontainers.IBC05PACKINGINSTRUCTIONIBC05ThefollowingIBCsareauthorised,providedthegeneralprovisionsof4.1.1,4.1.2and4.1.3aremet:(1)metal(11A,11B,11N,21A,21B,21N,31A,31Band31N);(2)rigidplastics(11H1,11H2,21H1,21H2,31H1and31H2);(3)composite(11HZ1,21HZ1and31HZ1).Specialpackingprovisions:B1ForpackinggroupIsubstances,IBCsshallbecarriedinclosedvehiclesorcontainers.B2ForpackinggroupIIsolidsubstances,IBCsotherthanmetalorrigidplasticsIBCsshallbecarriedinclosedvehiclesorcontainers.IBC06PACKINGINSTRUCTIONIBC06ThefollowingIBCsareauthorised,providedthegeneralprovisionsof4.1.1,4.1.2and4.1.3aremet:(1)metal(11A,11B,11N,21A,21B,21N,31A,31Band31N);(2)rigidplastics(11H1,11H2,21H1,21H2,31H1and31H2);(3)composite(11HZ1,11HZ2,21HZ1,21HZ2,31HZ1and31HZ2).Additionalrequirement:CompositeIBCs11HZ2,21HZ2and31HZ2shallnotbeusedwhenthesubstancesbeingcarriedmaybecomeliquidduringcarriage.Specialpackingprovisions:B1ForpackinggroupIsubstances,IBCsshallbetransportedinclosedvehiclesorcontainers.B2ForpackinggroupIIsolidsubstances,IBCsotherthanmetalorrigidplasticsIBCsshallbecarriedinclosedvehiclesorcontainers.IBC07PACKINGINSTRUCTIONIBC07ThefollowingIBCsareauthorised,providedthegeneralprovisionsof4.1.1,4.1.2and4.1.3aremet:(1)metal(11A,11B,11N,21A,21B,21N,31A,31Band31N);(2)rigidplastics(11H1,11H2,21H1,21H2,31H1and31H2);(3)composite(11HZ1,11HZ2,21HZ1,21HZ2,31HZ1and31HZ2);(4)wooden(11C,11Dand11F).Additionalrequirement:LinersofwoodenIBCsshallbesift-proof.Specialpackingprovisions:B1ForpackinggroupIsubstances,IBCsshallbecarriedinclosedvehiclesorcontainers.B2ForpackinggroupIIsolidsubstances,IBCsotherthanmetalorrigidplasticsIBCsshallbecarriedinclosedvehiclesorcontainers.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/648IBC08PACKINGINSTRUCTIONIBC08ThefollowingIBCsareauthorised,providedthegeneralprovisionsof4.1.1,4.1.2and4.1.3aremet:(1)metal(11A,11B,11N,21A,21B,21N,31A,31Band31N);(2)rigidplastics(11H1,11H2,21H1,21H2,31H1and31H2);(3)composite(11HZ1,11HZ2,21HZ1,21HZ2,31HZ1and31HZ2);(4)fibreboard(11G);(5)wooden(11C,11Dand11F);(6)flexible(13H1,13H2,13H3,13H4,13H5,13L1,13L2,13L3,13L4,13M1or13M2).Specialpackingprovisions:B2ForpackinggroupIIsolidsubstances,IBCsotherthanmetalorrigidplasticsIBCsshallbecarriedinclosedvehiclesorcontainers.B3FlexibleIBCsshallbesift-proofandwater-resistantorshallbefittedwithasift-proofandwater-restistantliner.B4Flexible,fibreboardorwoodenIBCsshallbesift-proofandwater-resistantorshallbefittedwithasift-proofandwater-resistantliner.B6ForUNNos1363,1364,1365,1386,1841,2211,2217,2793and3314,IBCsarenotrequiredtomeettheIBCtestingrequirementsofChapter6.5.IBC99PACKINGINSTRUCTIONIBC99OnlyIBCswhichareapprovedbythecompetentauthoritymaybeused.IBC100PACKINGINSTRUCTIONIBC100ThisinstructionappliestoUNNos0082,0241,0331and0332.ThefollowingIBCsareauthorised,providedthegeneralprovisionsof4.1.1,4.1.2and4.1.3andspecialprovisionsof4.1.5aremet:(1)metal(11A,11B,11N,21A,21B,21N,31A,31Band31N);(2)flexible(13H2,13H3,13H4,13L2,13L3,13L4and13M2);(3)rigidplastics(11H1,11H2,21H1,21H2,31H1and31H2);(4)composite(11HZ1,11HZ2,21HZ1,21HZ2,31HZ1and31HZ2).Additionalrequirements:1.IBCsshallonlybeusedforfreeflowingsubstances.2.FlexibleIBCsshallonlybeusedforsolids.Specialpackingprovisions:B9ForUNNo0082,thispackinginstructionmayonlybeusedwhenthesubstancesaremixturesofammoniumnitrateorotherinorganicnitrateswithothercombustiblesubstanceswhicharenotexplosiveingredients.Suchexplosivesshallnotcontainnitroglycerine,similarliquidorganicnitrates,orchlorates.MetalIBCsarenotauthorised.B10ForUNNo0241,thispackinginstructionmayonlybeusedforsubstanceswhichconsistofwaterasanessentialingredientandhighproportionsofammoniumnitrateorotheroxidisingsubstancessomeorallofwhichareinsolution.Theotherconstituentsmayincludehydrocarbonsoraluminiumpowder,butshallnotincludenitro-derivativessuchastrinitrotoluene.MetalIBCsarenotauthorised.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/649IBC520PACKINGINSTRUCTIONIBC520Thisinstructionappliestoorganicperoxidesandself-reactivesubstancesoftypeF.TheIBCslistedbelowareauthorisedfortheformulationslisted,providedthegeneralprovisionsof4.1.1,4.1.2and4.1.3andspecialprovisionsof4.1.7.2aremet.Forformulationsnotlistedbelow,onlyIBCswhichareapprovedbythecompetentauthoritymaybeused(see4.1.7.2.2).UNNoOrganicperoxideTypeofIBCMaximumquantity(litres)ControltemperatureEmergencytemperature3109ORGANICPEROXIDE,TYPEF,LIQUIDtert-Butylhydroperoxide,notmorethan72%withwater31A1250tert-Butylperoxyacetate,notmorethan32%indiluenttypeA31A31HA112501000tert-Butylperoxy-3,5,5-trimethylhex-anoate,notmorethan32%indiluenttypeA31A31HA112501000Cumylhydroperoxide,notmorethan90%indiluenttypeA31HA11250Dibenzoylperoxide,notmorethan42%asastabledispersioninwater31H11000Di-tert-butylperoxide,notmorethan52%indiluenttypeA31A31HA1125010001,1-Di-(tert-butylperoxy)cyclohexane,notmorethan42%indiluenttypeA31H11000Dilauroylperoxide,notmorethan42%,stabledispersion,inwater31HA11000Isopropylcumylhydroperoxide,notmorethan72%indiluenttypeA31HA11250p-Menthylhydroperoxide,notmorethan72%indiluenttypeA31HA11250Peroxyaceticacid,stabilised,notmorethan17%31H131HA131A150015001500OfficialJournaloftheEuropeanUnionEN26.1.2004L18/650IBC520PACKINGINSTRUCTIONIBC520UNNoOrganicperoxideTypeofIBCMaximumquantity(litres)ControltemperatureEmergencytemperature3119ORGANICPEROXIDE,TYPEF,LIQUID,TEMPERATURECONTROLLEDtert-Butylperoxy-2-ethylhexanoate,notmorethan32%indiluenttypeB31HA131A10001250+30°C+30°C+35°C+35°Ctert-Butylperoxyneodecanoate,notmorethan32%indiluenttypeA31A12500°C+10°Ctert-Butylperoxyneodecanoate,notmorethan42%stabledispersion,inwater31A1250–5°C+5°Ctert-Butylperoxypivalate,notmorethan27%indiluenttypeB31HA131A10001250+10°C+10°C+15°C+15°CCumylperoxyneodecanoate,notmorethan52%,stabledispersion,inwater31A1250–15°C–5°CDi-(4-tert-butylcyclohexyl)peroxydicarbo-nate,notmorethan42%,stabledisper-sion,inwater31HA11000+30°C+35°CDicetylperoxydicarbonate,notmorethan42%,stabledispersion,inwater31HA11000+30°C+35°CDi-(2-ethylhexyl)peroxydicarbonate,notmorethan52%,stabledispersion,inwater31A1250–20°C–10°CDimyristylperoxydicarbonate,notmorethan42%,stabledispersion,inwater31HA11000+15°C+20°CDi-(3,5,5-trimethylhexanoyl)peroxide,notmorethan38%indiluenttypeA31HA131A10001250+10°C+10°C+15°C+15°CDi-(3,5,5-trimethylhexanoyl)peroxide,notmorethan52%,stabledispersion,inwater31A1250+10°C+15°C1,1,3,3-Tetramethylbutylperoxyneode-canoate,notmorethan52%,stabledispersion,inwater31A1250–5°C+5°COfficialJournaloftheEuropeanUnionEN26.1.2004L18/651IBC520PACKINGINSTRUCTIONIBC520Additionalrequirements:1.IBCsshallbeprovidedwithadevicetoallowventingduringcarriage.Theinlettothepressure-reliefdeviceshallbesitedinthevapourspaceoftheIBCundermaximumfillingconditionsduringcarriage.2.TopreventexplosiveruptureofmetalIBCsorcompositeIBCswithcompletemetalcasing,theemergency-reliefdevicesshallbedesignedtoventallthedecompositionproductsandvapoursevolvedduringself-acceleratingdecompositionorduringaperiodofnotlessthanonehouroffire-engulfmentascalculatedbytheformulain4.2.1.13.8.Thecontrolandemergencytemperaturesspecifiedinthispackinginstructionarebasedonanon-insulatedIBC.WhenconsigninganorganicperoxideinanIBCinaccordancewiththisinstruction,itistheresponsibilityoftheconsignortoensurethat:(a)thepressureandemergencyreliefdevicesinstalledontheIBCaredesignedtotakeappropriateaccountoftheself-acceleratingdecompositionoftheorganicperoxideandoffire-engulfment;and(b)whenapplicable,thecontrolandemergencytemperaturesindicatedareappropriate,takingintoaccountthedesign(e.g.insulation)oftheIBCtobeused.IBC620PACKINGINSTRUCTIONIBC620ThisinstructionappliestoUNNo3291.ThefollowingIBCsareauthorised,providedthegeneralprovisionsof4.1.1,4.1.2and4.1.3aremet:rigid,leakproofIBCsconformingtothepackinggroupIIperformancelevel.Additionalrequirements:1.ThereshallbesufficientabsorbentmaterialtoabsorbtheentireamountofliquidpresentintheIBC.2.IBCsshallbecapableofretainingliquids.3.IBCsintendedtocontainsharpobjectssuchasbrokenglassandneedlesshallberesistanttopuncture.4.1.4.3.PackinginstructionsconcerningtheuseoflargepackagingsLP01PACKINGINSTRUCTION(LIQUIDS)LP01Thefollowinglargepackagingsareauthorisedprovidedthegeneralprovisionof4.1.1and4.1.3aremet:InnerpackagingsLargeouterpackagingsPackinggroupIPackinggroupIIPackinggroupIIIGlass10lPlastics30lMetal40lSteel(50A)Aluminium(50B)Metalotherthansteeloralumi-nium(50N)Rigidplastics(50H)Naturalwood(50C)Plywood(50D)Reconstitutedwood(50F)Fibreboard(50G)NotallowedNotallowedMaximumcapacity:3m3OfficialJournaloftheEuropeanUnionEN26.1.2004L18/652LP02PACKINGINSTRUCTION(SOLIDS)LP02Thefollowinglargepackagingsareauthorisedprovidedthegeneralprovisionsof4.1.1and4.1.3aremet:InnerpackagingsLargeouterpackagingsPackinggroupIPackinggroupIIPackinggroupIIIGlass10KgPlastics(a)50KgMetal50KgPaper(a)(b)50KgFibre(a)(b)50KgSteel(50A)Aluminium(50B)Metalotherthansteeloralumi-nium(50N)Rigidplastics(50H)Naturalwood(50C)Plywood(50D)Reconstitutedwood(50F)Fibreboard(50G)NotallowedNotallowedMaximumcapacity:3m3(a)Theseinnerpackagingsshallnotbeusedwhenthesubstancesbeingcarriedmaybecomeliquidduringcarriage.(b)Theseinnerpackagingsshallbesift-proof.LP99PACKINGINSTRUCTIONLP99Onlylargepackagingswhichareapprovedbythecompetentauthoritymaybeused(see4.1.3.7).LP101PACKINGINSTRUCTIONLP101Thefollowingpackagingsareauthorised,providedthegeneralprovisionsof4.1.1and4.1.3andspecialprovisionsof4.1.5aremet:InnerpackagingsIntermediatepackagingsLargepackagingsNotnecessaryNotnecessarySteel(50A)Aluminium(50B)Metalotherthansteeloraluminium(50N)Rigidplastics(50H)Naturalwood(50C)Plywood(50D)Reconstitutedwood(50F)Fibreboard(50G)Specialpackingprovision:L1ForUNNos0006,0009,0010,0015,0016,0018,0019,0034,0035,0038,0039,0048,0056,0137,0138,0168,0169,0171,0181,0182,0183,0186,0221,0243,0244,0245,0246,0254,0280,0281,0286,0287,0297,0299,0300,0301,0303,0321,0328,0329,0344,0345,0346,0347,0362,0363,0370,0412,0424,0425,0434,0435,0436,0437,0438,0451,0488and0502:largeandrobustexplosivesarticles,normallyintendedformilitaryuse,withouttheirmeansofinitiationorwiththeirmeansofinitiationcontainingatleasttwoeffectiveprotectivefeatures,maybecarriedunpackaged.Whensucharticleshavepropellingchargesorareself-propelled,theirignitionsystemsshallbeprotectedagainststimuliencounteredduringnormalconditionsofcarriage.Anegativeresultintestseries4onanunpackagedarticleindicatesthatthearticlecanbeconsideredforcarriageunpackaged.Suchunpackagedarticlesmaybefixedtocradlesorcontainedincratesorothersuitablehandlingdevices.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/653LP102PACKINGINSTRUCTIONLP102Thefollowingpackagingsareauthorised,providedthegeneralprovisionsof4.1.1and4.1.3andspecialprovisionsof4.1.5aremet:InnerpackagingsIntermediatepackagingsOuterpackagingsBagswaterresistantReceptaclesfibreboardmetalplasticswoodSheetsfibreboard,corrugatedTubesfibreboardNotnecessarySteel(50A)Aluminium(50B)Metalotherthansteeloraluminium(50N)Rigidplastics(50H)Naturalwood(50C)Plywood(50D)Reconstitutedwood(50F)Fibreboard(50G)LP621PACKINGINSTRUCTIONLP621ThisinstructionappliestoUNNo3291.Thefollowinglargepackagingsareauthorised,providedthegeneralprovisionsof4.1.1and4.1.3andthespecialprovisionsof4.1.8aremet:(1)forclinicalwasteplacedininnerpackagings:rigid,leakprooflargepackagingsconformingtotherequirementsofChapter6.6forsolids,atthepackinggroupIIperformancelevel,providedthereissufficientabsorbentmaterialtoabsorbtheentireamountofliquidpresentandthelargepackagingiscapableofretainingliquids;(2)forpackagescontaininglargerquantitiesofliquid:largerigidpackagingsconformingtotherequirementsofChapter6.6,atthepackinggroupIIperformancelevel,forliquids.Additionalrequirement:LargepackagingsintendedtocontainsharpobjectssuchasbrokenglassandneedlesshallberesistanttopunctureandretainliquidsundertheperformancetestconditionsinChapter6.6.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/6544.1.4.4.ParticularrequirementsapplicabletotheuseofpressurereceptaclesforsubstancesotherthanthoseofClass2WhengascylindersorgasreceptaclesareusedaspackagingforsubstancesassignedtopackinginstructionsP400,P401,P402orP601,theyshallbeconstructed,tested,filledandmarkedaccordingtothecorrespondingrequirements(PR1toPR6)asmentionedinthetablebelowforeachUNnumber.TableLISTOFPARTICULARREQUIREMENTS(PR)FORGASCYLINDERSANDRECEPTACLESRequire-mentcodeUNNosApplicableconstruction,testing,fillingandmarkingrequirementsPR11366137013801389139114111421192820032445284528703049305030513052305330763129313031483194320332073254ThesubstancesclassifiedundertheseUNnumbersshallbepackedinhermeticallyclosingmetalreceptacleswhicharenotaffectedbythecontentsandhaveacapacityofnotmorethan450litresThereceptaclesshallbesubjectedtotheinitialtestandperiodictestseveryfiveyearsatapressureofnotlessthan1MPa(10bar)(gaugepressure)Thereceptaclesshallnotbefilledtomorethan90%oftheircapacity;however,aspaceofatleast5%shallremainemptyforsafetywhentheliquidisatanaveragetemperatureof50°CDuringcarriage,theliquidshallbeunderalayerofinertgasthegaugepressureofwhichshallbenotlessthan50kPa(0,5bar).Thereceptaclesshallcarryadataplatewiththefollowingparticularsenteredinadurableform:—substanceorsubstances(a)acceptedforcarriage,—tare(b)ofthereceptacle,includingaccessories,—testpressure(b)(gaugepressure),—date(month,year)ofthelasttestundergone,—stampoftheexpertwhocarriedoutthetest,—capacity(b)ofthereceptacle,—maximummassoffillingallowed(b)PR21183124212952988ThesubstancesclassifiedundertheseUNnumbersshallbepackedincorrosion-resistantsteelreceptacleswithamaximumcapacityof450litres.TheclosingdeviceofthereceptacleshallbeprotectedbyacapThereceptaclesshallbesubjectedtotheinitialtestandperiodictestseveryfiveyearsatapressureofnotlessthan0,4MPa(4bar)(gaugepressure)Themaximumpermissiblemassoffillingperlitreofcapacityfortrichlorosilane,ethyldichlorosilaneandmethyldichlorosilaneshallnotexceed1,14kg,0,93kgor0,95kgrespectively,ifthefillingiscarriedoutbymass;ifthefillingisbyvolume,thedegreeoffillingshallnotexceed85%Thereceptaclesshallalsocarryaplateshowingthefollowingparticularsinadurableform:—descriptionofthesubstance(s)acceptedforcarriage,orforchlorosilanes:‘chlorosilanes,Class4.3’,—tare(b)ofthereceptacle,includingaccessories,—testpressure(b)(gaugepressure),—date(month,year)ofthelasttestundergone,—stampoftheexpertwhocarriedoutthetest,—capacity(b)ofthereceptacle,—maximumdegreeoffillingallowedbymass(b)foreachsubstanceacceptedforcarriageOfficialJournaloftheEuropeanUnionEN26.1.2004L18/655Require-mentcodeUNNosApplicableconstruction,testing,fillingandmarkingrequirementsPR31092125112591605161319943294ThesubstancesclassifiedundertheseUNnumbersshallbepackedinmetalreceptaclesfittedwithcompletelyleakproofclosingdeviceswhichshall,ifnecessary,besecuredagainstmechanicaldamagebyprotectivecaps.Steelreceptaclesofacapacitynotexceeding150litresshallhaveaminimumwallthicknessof3mm,andlargersteelreceptaclesandreceptaclesmadeofothermaterialsshallhavewallsatleastthickenoughtoguaranteeequivalentmechanicalstrengthThemaximumcapacityofreceptaclespermittedshallbe250litresThemassofthecontentsshallbenotmorethan1kgofliquidperlitreofcapacityBeforebeingusedforthefirsttime,thereceptaclesshallundergoahydraulicpressuretestatapressureofnotlessthan1MPa(10bar)(gaugepressure)ThepressuretestshallberepeatedeveryfiveyearsandshallincludeameticulousinspectionoftheinsideofthereceptacleandacheckofthetareThereceptaclesshallbearthefollowingparticularsinclearlylegibleanddurablecharacters:—substanceorsubstances(a)acceptedforcarriage,—thenameoftheownerofthereceptacle,—thetare(b)ofthereceptacle,includingsuchfittingsandaccessoriesasvalves,protectivecaps,etc,—thedate(month,year)oftheinitialtestandofthemostrecenttest,andthestampoftheexpertwhocarriedoutthetest,—themaximumpermissiblemassofthecontentsofthereceptacleinkg,—theinternalpressure(testpressure)tobeappliedinthehydraulicpressuretestPR41185ThesubstancesclassifiedunderthisUNnumbershallbepackedinsteelreceptaclesofsufficientthickness,whichshallbeclosedbyascrew-threadedbungandascrew-threadedprotectivecaporequivalentdeviceleakproofbothtoliquidandtovapourThereceptaclesshallinitiallyandperiodically,atleasteveryfiveyears,betestedatapressureofatleast1MPa(10bar)(gaugepressure)inaccordancewith6.2.1.5and6.2.1.6Themassofthecontentsshallnotexceed0,67kgperlitreofcapacity.Apackageshallnotweighmorethan75kgReceptaclesshallbear,inclearlylegibleanddurablecharacters:—thenameormarkofthemanufacturerandthenumberofthereceptacle,—theword‘ethyleneimine’,—thetare(b)ofthereceptacleanditsmaximumpermittedmasswhenfilled,—thedate(monthandyear)oftheinitialtestandofthemostrecenttestundergone,—thestampoftheexpertwhocarriedoutthetestsandexaminationsOfficialJournaloftheEuropeanUnionEN26.1.2004L18/656Require-mentcodeUNNosApplicableconstruction,testing,fillingandmarkingrequirementsPR524802481ThesubstancesclassifiedundertheseUNnumbersshallbepackedinreceptaclesmadeofpurealuminiumhavingawallthicknessofnotlessthan5mmorinreceptaclesofstainlesssteel.ThereceptaclesshallbefullyweldedTheyshallinitiallyandperiodically,atleasteveryfiveyears,betestedatapressureofatleast0,5MPa(5bar)(gaugepressure)inaccordancewith6.2.1.5and6.2.1.6Theyshallbesoclosedastobeleakproofbymeansoftwoclosuresoneabovetheother,oneofwhichshallbescrew-threadedorsecuredinanequallyeffectivemannerThedegreeoffillingshallbenotmorethan90%Drumsweighingmorethan100kgshallbefittedwithrollinghoopsorstiffeningribsThereceptaclesshallbear,inclearlylegibleanddurablecharacters:—thenameormarkofthemanufacturerandthenumberofthereceptacle,—substanceorsubstances(a)acceptedforcarriage,—thetare(b)ofthereceptacleanditsmaximumpermittedmasswhenfilled,—thedate(monthandyear)oftheinitialtestandofthemostrecenttestundergone,—thestampoftheexpertwhocarriedoutthetestsandexaminationsPR61744Brominecontaininglessthan0,005%water,orbetween0,005%and0,2%water,providedthatinthelattercasemeasuresaretakentopreventcorrosionoftheliningofthereceptacles,maybecarriedinreceptaclessatisfyingthefollowingconditions:(a)thereceptaclesshallbemadeofsteelandbeequippedwithaleakproofliningmadeofleadorofsomeothermaterialaffordingequivalentprotectionandwithahermeticclosure;receptaclesmadeofmonelmetalornickel,orwithanickellining,shallalsobepermitted;(b)thecapacityofthereceptaclesshallnotexceed450litres;(c)thereceptaclesshallnotbefilledtomorethan92%oftheircapacityormorethan2,86kgperlitreofcapacity;(d)thereceptaclesshallbeweldedanddesignedforacalculationpressureofnotlessthan2,1MPa(21bar)gaugepressure.ThematerialsandworkmanshipshallinotherrespectsmeettherelevantrequirementsofChapter6.2.Theinitialtestofunlinedsteelreceptaclesshallbesubjecttotherequirementsof6.2.1.5;(e)theclosuresshallprojectaslittleaspossiblefromthereceptacleandbefittedwithprotectivecaps.Theclosuresandcapsshallbefittedwithgasketsmadeofamaterialnotcapableofbeingattackedbybromine.Theclosuresshallbeintheupperpartofthereceptaclesinsuchamannerthattheycaninnocasebeinpermanentcontactwiththeliquidphase;(f)thereceptaclesshallbeprovidedwithfittingsenablingthemtostandstablyupright,andwithliftingattachments(rings,flanges,etc.)atthetop,whichshallbetestedattwicetheworkingload.Beforebeingputintoservice,thereceptaclesshallbesubjectedtoaleakproofnesstestatapressureofatleast200kPa(2bar)gaugepressureTheleakproofnesstestshallberepeatedeverytwoyearsandshallbeaccompaniedbyaninternalinspectionofthereceptacleandacheckofitstareThetestandtheinspectionshallbecarriedoutunderthesupervisionofanexpertapprovedbythecompetentauthorityThereceptaclesshallbear,inclearlylegibleanddurablecharacters:—thenameorthemarkofthemanufacturerandthenumberofthereceptacle,—theword‘Bromine’,—tare(b)massofthereceptacleandthepermissiblemaximummassdofthefilledreceptacle,—date(month,year)oftheinitialtestandofthelatestperiodicaltest,—stampoftheexpertwhocarriedoutthetestsandexaminations(a)Thenamemaybereplacedbyagenericdescriptioncoveringsubstancesofasimilarnatureandalsocompatiblewiththecharacteristicsofthereceptacle.(b)Theunitsofmeasurementtobeaddedeachtimeafterthenumericalvalues.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/6574.1.5.SpecialpackingprovisionsforgoodsofClass14.1.5.1.Thegeneralprovisionsofsection4.1.1shallbemet.4.1.5.2.AllpackagingsforClass1goodsshallbesodesignedandconstructedthat:(a)theywillprotecttheexplosives,preventthemescapingandcausenoincreaseintheriskofunintendedignitionorinitiationwhensubjectedtonormalconditionsofcarriageincludingforeseeablechangesintemperature,humidityandpressure;(b)thecompletepackagecanbehandledsafelyinnormalconditionsofcarriage;and(c)thepackageswillwithstandanyloadingimposedonthembyforeseeablestackingtowhichtheywillbesubjectduringcarriagesothattheydonotaddtotheriskpresentedbytheexplosives,thecontainmentfunctionofthepackagingsisnotharmed,andtheyarenotdistortedinawayortoanextentwhichwillreducetheirstrengthorcauseinstabilityofastack.4.1.5.3.Allexplosivesubstancesandarticles,aspreparedforcarriage,shallhavebeenclassifiedinaccordancewiththeproceduresdetailedin2.2.1.4.1.5.4.Class1goodsshallbepackedinaccordancewiththeappropriatepackinginstructionshownincolumn8ofTableAofChapter3.2,asdetailedin4.1.4.4.1.5.5.Packagings,includingIBCsandlargepackagingsshallconformtotherequirementsofChapter6.1,6.5or6.6,respectively,andshallmeetthetestrequirementsof6.1.5,6.5.4or6.6.5,respectively,forpackinggroupII,subjectto4.1.1.13,6.1.2.4and6.5.1.4.4.PackagingsotherthanmetalpackagingsmeetingthetestcriteriaofpackinggroupImaybeused.Toavoidunnecessaryconfinement,metalpackagingsofpackinggroupIshallnotbeused.4.1.5.6.Theclosuredeviceofpackagingscontainingliquidexplosivesshallensureadoubleprotectionagainstleakage.4.1.5.7.Theclosuredeviceofmetaldrumsshallincludeasuitablegasket;ifaclosuredeviceincludesascrew-thread,theingressofexplosivesubstancesintothescrew-threadshallbeprevented.4.1.5.8.Packagingsforwatersolublesubstancesshallbewaterresistant.Packagingsfordesensitisedorphlegmatisedsubstancesshallbeclosedtopreventchangesinconcentrationduringcarriage.4.1.5.9.Whenthepackagingincludesadoubleenvelopefilledwithwaterwhichmayfreezeduringtransport,asufficientquantityofananti-freezeagentshallbeaddedtothewatertopreventfreezing.Anti-freezethatcouldcreateafirehazardbecauseofitsinherentflammabilityshallnotbeused.4.1.5.10.Nails,staplesandotherclosuredevicesmadeofmetalwithoutprotectivecoveringshallnotpenetratetotheinsideoftheouterpackagingunlesstheinnerpackagingadequatelyprotectstheexplosivesagainstcontactwiththemetal.4.1.5.11.Innerpackagings,fittingsandcushioningmaterialsandtheplacingofexplosivesubstancesorarticlesinpackagesshallbeaccomplishedinamannerwhichpreventstheexplosivesubstancesorarticlesfrombecominglooseintheouterpackagingundernormalconditionsofcarriage.Metalliccomponentsofarticlesshallbepreventedfrommakingcontactwithmetalpackagings.Articlescontainingexplosivesubstancesnotenclosedinanoutercasingshallbeseparatedfromeachotherinordertopreventfrictionandimpact.Padding,trays,partitioningintheinnerorouterpackaging,mouldingsorreceptaclesmaybeusedforthispurpose.4.1.5.12.Packagingsshallbemadeofmaterialscompatiblewith,andimpermeableto,theexplosivescontainedinthepackage,sothatneitherinteractionbetweentheexplosivesandthepackagingmaterials,norleakage,causestheexplosivetobecomeunsafetocarriage,orthehazarddivisionorcompatibilitygrouptochange.4.1.5.13.Theingressofexplosivesubstancesintotherecessesofseamedmetalpackagingsshallbeprevented.4.1.5.14.Plasticspackagingsshallnotbeliabletogenerateoraccumulatesufficientstaticelectricitysothatadischargecouldcausethepackagedexplosivesubstancesorarticlestoinitiate,igniteorfunction.4.1.5.15.Largeandrobustexplosivesarticles,normallyintendedformilitaryuse,withouttheirmeansofinitiationorwiththeirmeansofinitiationcontainingatleasttwoeffectiveprotectivefeatures,maybecarriedunpackaged.Whensucharticleshavepropellingchargesorareself-propelled,theirignitionsystemsshallbeprotectedagainststimuliencounteredduringnormalconditionsofcarriage.AnegativeresultinTestSeries4onanunpackagedarticleindicatesthatthearticlecanbeconsideredforcarriageunpackaged.Suchunpackagedarticlesmaybefixedtocradlesorcontainedincratesorothersuitablehandling,storageorlaunchingdevicesinsuchawaythattheywillnotbecomelooseduringnormalconditionsofcarriage.WheresuchlargeexplosivearticlesareaspartoftheiroperationalsafetyandsuitabilitytestssubjectedtotestregimesthatmeettheintentionsofthisDirectiveandsuchtestshavebeensuccessfullyundertaken,thecompetentauthoritymayapprovesucharticlestobecarriedinaccordancewithADR.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/6584.1.5.16.Explosivesubstancesshallnotbepackedininnerorouterpackagingswherethedifferencesininternalandexternalpressures,duetothermalorothereffects,couldcauseanexplosionorruptureofthepackage.4.1.5.17.Wheneverlooseexplosivesubstancesortheexplosivesubstanceofanuncasedorpartlycasedarticlemaycomeintocontactwiththeinnersurfaceofmetalpackagings(1A2,1B2,4A,4Bandmetalreceptacles),themetalpackagingshallbeprovidedwithaninnerlinerorcoating(see4.1.1.2).4.1.5.18.PackinginstructionP101maybeusedforanyexplosiveprovidedthepackaginghasbeenapprovedbyacompetentauthorityregardlessofwhetherthepackagingcomplieswiththepackinginstructionassignmentincolumn8ofTableAofChapter3.2.4.1.6.SpecialpackingprovisionsforgoodsofClass24.1.6.1.Receptacles,includingtheirclosures,shallbeselectedtocontainagasoramixtureofgasesaccordingtotherequirementsof6.2.1.2‘Materialsofreceptacles’andtherequirementsoftherelevantpackinginstructionsof4.1.4.4.1.6.2.Achangeofuseofarefillablereceptacleshallincludeemptying,purgingandevacuationoperationstotheextentnecessaryforsafeoperation(seealsotableofstandardsattheendofthissection).Notes1.RefillablereceptaclesforthetransportofgasesofClass2shallbeperiodicallyinspectedaccordingtotheperiodicitysetoutintherelevantpackinginstructions(P200orP203)andaccordingtotheprovisionsdetailedin6.2.1.6‘Periodicinspection’.2.ReceptaclesreadyforshipmentshallbemarkedandlabelledaccordingtotheprovisionssetoutinChapter5.24.1.6.3.Receptaclesexceptopencryogenicreceptacles,includingtheirclosures,shallconformtothedesign,construction,inspectionandtestingrequirementsdetailedinChapter6.2.Whenouterpackagingsareprescribed,thereceptaclesshallbefirmlysecuredtherein.Unlessotherwisespecifiedintherelevantpackinginstructions,receptaclesmaybeenclosedinouterpackagingseithersinglyoringroups.4.1.6.4.Valves(cocks)shallbeeffectivelyprotectedfromdamagewhichcouldcausegasreleaseifthereceptaclefalls,andduringcarriageandstacking.Thisrequirementisdeemedtobecompliedwithifoneormoreofthefollowingconditionsarefulfilled(seealsotableofstandardsattheendofthissection):(a)valvesareplacedinsidetheneckofthereceptacleandprotectedbyascrew-threadedplug;(b)valvesareprotectedbycaps.Capsshallpossessvent-holesofsufficientcross-sectionalareatoevacuategasesifleakageoccursatthevalves;(c)valvesareprotectedbyshroudsorguards;(d)valvesaredesignedandconstructedinsuchawaythattheirabilitytowithstanddamagewithoutleakageofproducthasbeendemonstrated;(e)valvesareplacedinsideaprotectiveframe;(f)receptaclesarecarriedinprotectiveboxesorframes.4.1.6.5.Receptacles,containingpyrophoricgasesorverytoxicgases(gaseswithanLC50lowerthan200ppm)shallhavetheirvalve(s)openingsfittedwithgas-tightplugsorcapnutswhichshallbemadeofamaterialnotliabletoattackbythecontentsofthereceptacle.4.1.6.6.Receptaclesmaybecarriedaftertheexpiryofthetimelimitsetfortheperiodictestprescribedforthepurposeofundergoingthetest.4.1.6.7.Requirementsofthefollowingpackingprovisionsareconsideredtohavebeencompliedwithifthefollowingstandards,asrelevant,areapplied:Applic-ablepara-graphsReferenceTitleofdocument4.1.6.2EN1795:1997Gascylinders(excludingLPG)—Proceduresforchangeofgasservice.4.1.6.4EN962:1996/A2:2000Valveprotectioncapsandvalveguardsforindustrialandmedicalgascylinders—Design,constructionandtests4.1.7.Specialpackingprovisionsfororganicperoxides(Class5.2)andself-reactivesubstancesofClass4.14.1.7.1.Useofpackagings4.1.7.1.1.Packagingsfororganicperoxidesandself-reactivesubstancesshallmeettherequirementsofChapter6.1orofChapter6.6atthepackinggroupIIperformancelevel.Toavoidunnecessaryconfinement,metalpackagingsmeetingthetestcriteriaofpackinggroupIshallnotbeused.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/6594.1.7.1.2.Thepackingmethodsfororganicperoxidesandself-reactivesubstancesarelistedinpackinginstruction520andaredesignatedOP1toOP8.Thequantitiesspecifiedforeachpackingmethodarethemaximumquantitiesauthorisedperpackage.4.1.7.1.3.Thepackingmethodsappropriatefortheindividualcurrentlyassignedorganicperoxidesandself-reactivesubstancesarelistedin2.2.41.4and2.2.52.4.4.1.7.1.4.Forneworganicperoxides,newself-reactivesubstancesornewformulationsofcurrentlyassignedorganicperoxidesorself-reactivesubstances,thefollowingprocedureshallbeusedtoassigntheappropriatepackingmethod:(a)ORGANICPEROXIDE,TYPEBorSELF-REACTIVESUBSTANCE,TYPEB:packingmethodOP5shallbeassigned,providedthattheorganicperoxide(orself-reactivesubstance)satisfiesthecriteriaof20.4.3(b)(resp.20.4.2(b))oftheManualoftestsandcriteriainapackagingauthorisedbythepackingmethod.Iftheorganicperoxide(orself-reactivesubstance)canonlysatisfythesecriteriainasmallerpackagingthanthoseauthorisedbypackingmethodOP5(namelyoneofthepackagingslistedforOP1toOP4),thenthecorrespondingpackingmethodwiththelowerOPnumberisassigned;(b)ORGANICPEROXIDE,TYPECorSELF-REACTIVESUBSTANCE,TYPEC:packingmethodOP6shallbeassigned,providedthattheorganicperoxide(orself-reactivesubstance)satisfiesthecriteriaof20.4.3(c)(resp.20.4.2(c))oftheManualoftestsandcriteriainapackagingauthorisedbythepackingmethod.Iftheorganicperoxide(orself-reactivesubstance)canonlysatisfythesecriteriainasmallerpackagingthanthoseauthorisedbypackingmethodOP6thenthecorrespondingpackingmethodwiththelowerOPnumberisassigned;(c)ORGANICPEROXIDE,TYPEDorSELF-REACTIVESUBSTANCE,TYPED:packingmethodOP7shallbeassignedtothistypeoforganicperoxideorself-reactivesubstance;(d)ORGANICPEROXIDE,TYPEEorSELF-REACTIVESUBSTANCE,TYPEE:packingmethodOP8shallbeassignedtothistypeoforganicperoxideorself-reactivesubstance;(e)ORGANICPEROXIDE,TYPEForSELF-REACTIVESUBSTANCE,TYPEF:packingmethodOP8shallbeassignedtothistypeoforganicperoxideorself-reactivesubstance.4.1.7.2.Useofintermediatebulkcontainers4.1.7.2.1.Thecurrentlyassignedorganicperoxidesspecificallylistedinthetableof2.2.52.4andindicatedwiththeletter‘N’inthe‘Packingmethod’columnofthattablemaybecarriedinIBCsinaccordancewithpackinginstructionIBC520.4.1.7.2.2.Otherorganicperoxidesandself-reactivesubstancesoftypeFmaybecarriedinIBCsunderconditionsestablishedbythecompetentauthorityofthecountryoforiginwhen,onthebasisoftheappropriatetests,thatcompetentauthorityissatisfiedthatsuchcarriagemaybesafelyconducted.Thetestsundertakenshallincludethosenecessary:(a)toprovethattheorganicperoxide(orself-reactivesubstance)complieswiththeprinciplesforclassificationgivenin20.4.3(f)(resp.20.4.2(f)oftheManualoftestsandcriteria,exitboxFofFigure20.1(b)oftheManual;(b)toprovethecompatibilityofallmaterialsnormallyincontactwiththesubstanceduringcarriage;(c)todetermine,whenapplicable,thecontrolandemergencytemperaturesassociatedwiththecarriageoftheproductintheIBCconcernedasderivedfromtheSADT;(d)todesign,whenapplicable,pressureandemergencyreliefdevices;and(e)todetermineifanyspecialprovisionsarenecessaryforsafecarriageofthesubstance.IfthecountryoforiginisnotaMemberState,theclassificationandtransportconditionsshallberecognizedbythecompetentauthorityofthefirstMemberStatereachedbytheconsignment.4.1.8.Specialpackingprovisionsforinfectioussubstances(Class6.2)4.1.8.1.Consignorsofinfectioussubstancesshallensurethatpackagesarepreparedinsuchamannerthattheyarriveattheirdestinationingoodconditionandpresentnohazardtopersonsoranimalsduringcarriage.4.1.8.2.Thedefinitionsin1.2.1andthegeneralprovisionsof4.1.1.1to4.1.1.14,except4.1.1.3and4.1.1.9to4.1.1.12,applytoinfectioussubstancespackages.4.1.8.3.Anitemisedlistofcontentsshallbeenclosedbetweenthesecondarypackagingandtheouterpackaging.4.1.8.4.Beforeanemptypackagingisreturnedtotheconsignor,orsentelsewhere,itshallbethoroughlydisinfectedorsterilisedandanylabelormarkingindicatingthatithadcontainedaninfectioussubstanceshallberemovedorobliterated.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/6604.1.9.SpecialpackingprovisionsforClass74.1.9.1.General4.1.9.1.1.Radioactivematerial,packagingsandpackagesshallmeettherequirementsofChapter6.4.Thequantityofradioactivematerialinapackageshallnotexceedthelimitsspecifiedin2.2.7.7.1.4.1.9.1.2.Thenon-fixedcontaminationontheexternalsurfacesofanypackageshallbekeptaslowaspracticableand,underroutineconditionsoftransport,shallnotexceedthefollowinglimits:(a)4Bq/cm2forbetaandgammaemittersandlowtoxicityalphaemitters;and(b)0,4Bq/cm2forallotheralphaemitters.Theselimitsareapplicablewhenaveragedoveranyareaof300cm2ofanypartofthesurface.4.1.9.1.3.Apackageshallnotcontainanyotheritemsexceptsucharticlesanddocumentsasarenecessaryfortheuseoftheradioactivematerial.Thisrequirementshallnotprecludethecarriageoflowspecificactivitymaterialorsurfacecontaminatedobjectswithotheritems.Thecarriageofsucharticlesanddocumentsinapackage,oroflowspecificactivitymaterialorsurfacecontaminatedobjectswithotheritemsmaybepermittedprovidedthatthereisnointeractionbetweenthemandthepackagingoritsradioactivecontentsthatwouldreducethesafetyofthepackage.4.1.9.1.4.Exceptasprovidedin7.5.11,CV33,thelevelofnon-fixedcontaminationontheexternalandinternalsurfacesofoverpacks,containers,tanksandintermediatebulkcontainersshallnotexceedthelimitsspecifiedin4.1.9.1.2.4.1.9.1.5.Radioactivematerialwithasubsidiaryriskshallbecarriedinpackagings,IBCsortanksfullycomplyingwiththerequirementsoftherelevantchaptersofPart6asappropriate,aswellasapplicablerequirementsofChapters4.1or4.2forthatsubsidiaryrisk.4.1.9.2.RequirementsandcontrolsforcarriageofLSAmaterialandSCO4.1.9.2.1.ThequantityofLSAmaterialorSCOinasingleindustrialpackageType1(TypeIP-1),industrialpackageType2(TypeIP-2),industrialpackageType3(TypeIP-3),orobjectorcollectionofobjects,whicheverisappropriate,shallbesorestrictedthattheexternalradiationlevelat3mfromtheunshieldedmaterialorobjectorcollectionofobjectsdoesnotexceed10mSv/h.4.1.9.2.2.LSAmaterialandSCOwhichisorcontainsfissilematerialshallmeettheapplicablerequirementsof7.5.11,CV33and6.4.11.1.4.1.9.2.3.LSAmaterialandSCOingroupsLSA-IandSCO-Imaybecarriedunpackagedunderthefollowingconditions:(a)allunpackagedmaterialotherthanorescontainingonlynaturallyoccurringradionuclidesshallbecarriedinsuchamannerthatunderroutineconditionsofcarriagetherewillbenoescapeoftheradioactivecontentsfromtheconveyancenorwilltherebeanylossofshielding;(b)eachconveyanceshallbeunderexclusiveuse,exceptwhenonlycarryingSCO-Ionwhichthecontaminationontheaccessibleandtheinaccessiblesurfacesisnotgreaterthan10timestheapplicablelevelspecifiedin2.2.7.2;and(c)forSCO-Iwhereitissuspectedthatnon-fixedcontaminationexistsoninaccessiblesurfacesinexcessofthevaluesspecifiedin2.2.7.5(a)(i),measuresshallbetakentoensurethattheradioactivematerialisnotreleasedintothevehicle.4.1.9.2.4.LSAmaterialandSCO,exceptasotherwisespecifiedin4.1.9.2.3,shallbepackagedinaccordancewiththetablebelow:IndustrialpackagerequirementsforLSAmaterialandSCORadioactivecontentsIndustrialpackagetypeExclusiveuseNotunderexclusiveuseLSA-ISolid(a)TypeIP-1TypeIP-1LiquidTypeIP-1TypeIP-2LSA-IISolidTypeIP-2TypeIP-2LiquidandgasTypeIP-2TypeIP-3OfficialJournaloftheEuropeanUnionEN26.1.2004L18/661RadioactivecontentsIndustrialpackagetypeExclusiveuseNotunderexclusiveuseLSA-IIITypeIP-2TypeIP-3SCO-I(a)TypeIP-1TypeIP-1SCO-IITypeIP-2TypeIP-2(a)Undertheconditionsspecifiedin4.1.9.2.3,LSA-ImaterialandSCO-Imaybecarriedunpackaged.4.1.10.Specialprovisionsformixedpacking4.1.10.1.Whenmixedpackingispermittedinaccordancewiththeprovisionsofthissection,differentdangerousgoodsordangerousgoodsandothergoodsmaybepackedtogetherincombinationpackagingsconformingto6.1.4.2.1,providedthattheydonotreactdangerouslywithoneanotherandthatallotherrelevantprovisionsofthisChapterarecompliedwith.Notes1.Seealso4.1.1.5and4.1.1.6.2.ForgoodsofClass7,see4.1.9.4.1.10.2.ExceptforpackagescontainingClass1goodsonlyorClass7goodsonly,ifwoodenorfibreboardboxesareusedasouterpackagings,apackagecontainingdifferentgoodspackedtogethershallnotweighmorethan100kg.4.1.10.3.Unlessotherwiseprescribedbyaspecialprovisionapplicableaccordingto4.1.10.4,dangerousgoodsofthesameclassandthesameclassificationcodemaybepackedtogether.4.1.10.4.Whenindicatedforagivenentryincolumn9bofTableAofChapter3.2,thefollowingspecialprovisionsshallapplytothemixedpackingofthegoodsassignedtothatentrywithothergoodsinthesamepackage.MP1Mayonlybepackedtogetherwithgoodsofthesametypewithinthesamecompatibilitygroup.MP2Shallnotbepackedtogetherwithothergoods.MP3MixedpackingofUNNo1873withUNNo1802ispermitted.MP4ShallnotbepackedtogetherwithgoodsofotherclassesorwithgoodswhicharenotsubjecttotherequirementsofthisDirective.However,ifthisorganicperoxideisahardenerorcompoundsystemforClass3substances,mixedpackingispermittedwiththesesubstancesofClass3.MP5UNNo2814andUNNo2900maybepackedtogetherinacombinationpackaginginconformitywithP620.Theyshallnotbepackedtogetherwithothergoods;thisdoesnotapplytodiagnosticspecimenspackedinaccordancewithP621ortosubstancesaddedascoolants,e.g.ice,dryiceorrefrigeratedliquidnitrogen.MP6Shallnotbepackedtogetherwithothergoods.Thisdoesnotapplytosubstancesaddedascoolants,e.g.ice,dryiceorrefrigeratedliquidnitrogen.MP7May—inquantitiesnotexceeding5litresperinnerpackaging—bepackedtogetherinacombinationpackagingconformingto6.1.4.21:—withgoodsofthesameclasscoveredbyotherclassificationcodeswhenmixedpackingisalsopermittedforthese;or—withgoodswhicharenotsubjecttotherequirementsofthisDirective,providedtheydonotreactdangerouslywithoneanother.MP8May—inquantitiesnotexceeding3litresperinnerpackaging—bepackedtogetherinacombinationpackagingconformingto6.1.4.21:—withgoodsofthesameclasscoveredbyotherclassificationcodeswhenmixedpackingisalsopermittedforthese;or—withgoodswhicharenotsubjecttotherequirementsofthisDirective,providedtheydonotreactdangerouslywithoneanother.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/662MP9Maybepackedtogetherinanouterpackagingforcombinationpackagingsinaccordancewith6.1.4.21:—withothergoodsofClass2;—withgoodsofotherclasses,whenthemixedpackingisalsopermittedforthese;or—withgoodswhicharenotsubjecttotherequirementsofthisDirective,providedtheydonotreactdangerouslywithoneanother.MP10May—inquantitiesnotexceeding5kgperinnerpackaging—bepackedtogetherinacombinationpackagingconformingto6.1.4.21:—withgoodsofthesameclasscoveredbyotherclassificationcodesorwithgoodsofotherclasses,whenmixedpackingisalsopermittedforthese;or—withgoodswhicharenotsubjecttotherequirementsofthisDirective,providedtheydonotreactdangerouslywithoneanother.MP11May—inquantitiesnotexceeding5kgperinnerpackaging—bepackedtogetherinacombinationpackagingconformingto6.1.4.21:—withgoodsofthesameclasscoveredbyotherclassificationcodesorwithgoodsofotherclasses(exceptsubstancesofpackinggroupIorIIofClass5.1whenmixedpackingisalsopermittedforthese;or—withgoodswhicharenotsubjecttotherequirementsofthisDirective,providedtheydonotreactdangerouslywithoneanother.MP12May—inquantitiesnotexceeding5kgperinnerpackaging—bepackedtogetherinacombinationpackagingconformingto6.1.4.21:—withgoodsofthesameclasscoveredbyotherclassificationcodesorwithgoodsofotherclasses(exceptsubstancesofpackinggroupIorIIofClass5.1whenmixedpackingisalsopermittedforthese;or—withgoodswhicharenotsubjecttotherequirementsofthisDirective,providedtheydonotreactdangerouslywithoneanother.Packagingsshallnotweighmorethan45kg.Iffibreboardboxesareusedasouterpackagingshowever,apackageshallnotweighmorethan27kg.MP13May—inquantitiesnotexceeding3kgperinnerpackagingandperpackage—bepackedtogetherinacombinationpackagingconformingto6.1.4.21:—withgoodsofthesameclasscoveredbyotherclassificationcodesorwithgoodsofotherclasses,whenmixedpackingisalsopermittedforthese;or—withgoodswhicharenotsubjecttotherequirementsofthisDirective,providedtheydonotreactdangerouslywithoneanother.MP14May—inquantitiesnotexceeding6kgperinnerpackaging—bepackedtogetherinacombinationpackagingconformingto6.1.4.21:—withgoodsofthesameclasscoveredbyotherclassificationcodesorwithgoodsofotherclasses,whenmixedpackingisalsopermittedforthese;or—withgoodswhicharenotsubjecttotherequirementsofthisDirective,providedtheydonotreactdangerouslywithoneanother.MP15May—inquantitiesnotexceeding3litresperinnerpackaging—bepackedtogetherinacombinationpackagingconformingto6.1.4.21:—withgoodsofthesameclasscoveredbyotherclassificationcodesorwithgoodsofotherclasses,whenmixedpackingisalsopermittedforthese;or—withgoodswhicharenotsubjecttotherequirementsofthisDirective,providedtheydonotreactdangerouslywithoneanother.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/663MP16May—inquantitiesnotexceeding3litresperinnerpackagingandperpackage—bepackedtogetherinacombinationpackagingconformingto6.1.4.21:—withgoodsofthesameclasscoveredbyotherclassificationcodesorwithgoodsofotherclasses,whenmixedpackingisalsopermittedforthese;or—withgoodswhicharenotsubjecttotherequirementsofthisDirective,providedtheydonotreactdangerouslywithoneanother.MP17May—inquantitiesnotexceeding0,5litreperinnerpackagingand1litreperpackage—bepackedtogetherinacombinationpackagingconformingto6.1.4.21:—withgoodsofotherclasses,exceptClass7,whenmixedpackingisalsopermittedforthese;or—withgoodswhicharenotsubjecttotherequirementsofthisDirective,providedtheydonotreactdangerouslywithoneanother.MP18May—inquantitiesnotexceeding0,5kgperinnerpackagingand1kgperpackage—bepackedtogetherinacombinationpackagingconformingto6.1.4.21:—withgoodsorarticlesofotherclasses,exceptClass7,whenmixedpackingisalsopermittedforthese;or—withgoodswhicharenotsubjecttotherequirementsofthisDirective,providedtheydonotreactdangerouslywithoneanother.MP19May—inquantitiesnotexceeding5litresperinnerpackaging—bepackedtogetherinacombinationpackagingconformingto6.1.4.21:—withgoodsofthesameclasscoveredbyotherclassificationcodesorwithgoodsofotherclasses,whenmixedpackingisalsopermittedforthese;or—withgoodswhicharenotsubjecttotherequirementsofthisDirective,providedtheydonotreactdangerouslywithoneanother.MP20MaybepackedtogetherwithsubstancescoveredbythesameUNnumber.ShallnotbepackedtogetherwithgoodsandarticlesofClass1havingdifferentUNnumbers.ShallnotbepackedtogetherwithgoodsofotherclassesorwithgoodswhicharenotsubjecttotherequirementsofthisDirective.MP21MaybepackedtogetherwitharticlescoveredbythesameUNnumber.ShallnotbepackedtogetherwithgoodsofClass1havingdifferentUNnumbers,exceptfor(a)theirownmeansofiniation,providedthat(i)themeansofiniationwillnotfunctionundernormalconditionsofcarriage;or(ii)suchmeanshaveatleasttwoeffectiveprotectivefeatureswhichpreventexplosionofanarticleintheeventofaccidentalfunctioningofthemeansofinitiation;or(iii)whensuchmeansdonothavetwoeffectiveprotectivefeatures(i.e.meansofinitiationassignedtocompatibilitygroupB),intheopinionofthecompetentauthorityofthecountryoforigin(1),theaccidentalfunctioningofthemeansofinitiationdoesnotcausetheexplosionofanarticleundernormalconditionsofcarriage;(b)articlesofcompatibilitygroupsC,DandE.ShallnotbepackedtogetherwithgoodsofotherclassesorwithgoodswhicharenotsubjecttotherequirementsofthisDirective.Whengoodsarepackedtogetherinaccordancewiththisspecialprovision,accountshallbetakenofapossibleamendmentoftheclassificationofpackagesinaccordancewith2.2.1.1.Forthedescriptionofthegoodsinthetransportdocument,see5.4.1.2.1(b).(1)IfthecountryoforiginisnotaMemberState,theapprovalshallrequirevalidationbythecompetentauthorityofthefirstMemberStatereachedbytheconsignment.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/664MP22MaybepackedtogetherwitharticlescoveredbythesameUNnumber.ShallnotbepackedtogetherwithgoodsofClass1havingdifferentUNnumbers,exceptfor(a)theirownmeansofiniation,providedthatthemeansofiniationwillnotfunctionundernormalconditionsofcarriage;(b)articlesofcompatibilitygroupsC,DandE.ShallnotbepackedtogetherwithgoodsofotherclassesorwithgoodswhicharenotsubjecttotherequirementsofthisDirective.Whengoodsarepackedtogetherinaccordancewiththisspecialprovision,accountshallbetakenofapossibleamendmentoftheclassificationofpackagesinaccordancewith2.2.1.1.Forthedescriptionofthegoodsinthetransportdocument,see5.4.1.2.1(b).MP23MaybepackedtogetherwitharticlescoveredbythesameUNnumber.ShallnotbepackedtogetherwithgoodsandarticlesofClass1havingdifferentUNnumbers;however,exceptionismadefortheirownmeansofiniation,providedthatthemeansofiniationwillnotfunctionundernormalconditionsofcarriage.ShallnotbepackedtogetherwithgoodsofotherclassesorwithgoodswhicharenotsubjecttotherequirementsofthisDirective.Whengoodsarepackedtogetherinaccordancewiththisspecialprovision,accountshallbetakenofapossibleamendmentoftheclassificationofpackagesinaccordancewith2.2.1.1.Forthedescriptionofthegoodsinthetransportdocument,see5.4.1.2.1(b).MP24MaybepackedtogetherwithgoodswiththeUNnumbersshowninthetablebelow,underthefollowingconditions:—ifaletterAisindicatedinthetable,thegoodswiththoseUNnumbersmaybeincludedinthesamepackagewithoutanyspeciallimitationofmass;—ifaletterBisindicatedinthetable,thegoodswiththoseUNnumbersmaybeincludedinthesamepackageuptoatotalmassof50kgofexplosivesubstances.Whengoodsarepackedtogetherinaccordancewiththisspecialprovision,accountshallbetakenofapossibleamendmentoftheclassificationofpackagesinaccordancewith2.2.1.1.Forthedescriptionofthegoodsinthetransportdocument,see5.4.1.2.1(b).OfficialJournaloftheEuropeanUnionEN26.1.2004L18/665CHAPTER4.2UseofportabletanksNote:Forfixedtanks(tank-vehicles),demountabletanksandtank-containersandtank-swapbodies,withshellsmadeofmetallicmaterials,andbattery-vehiclesandmultipleelementgascontainers(MEGCs),seeChapter4.3;forfibre-reinforcedplasticstanks,seeChapter4.4;forvacuumoperatedwastetanks,seeChapter4.5.4.2.1.GeneralprovisionsfortheuseofportabletanksforthecarriageofsubstancesofClasses3to94.2.1.1.ThissectionprovidesgeneralprovisionsapplicabletotheuseofportabletanksforthecarriageofsubstancesofClasses3,4.1,4.2,4.3,5.1,5.2,6.1,6.2,7,8and9.Inadditiontothesegeneralprovisions,portabletanksshallconformtothedesign,construction,inspectionandtestingrequirementsdetailedin6.7.2.SubstancesshallbecarriedinportabletanksconformingtotheapplicableportabletankinstructionidentifiedinColumn(10)oftheTableAofChapter3.2anddescribedin4.2.4.2.6(T1toT23)andtheportabletankspecialprovisionsassignedtoeachsubstanceinColumn(11)ofTableAofChapter3.2anddescribedin4.2.4.3.4.2.1.2.Duringcarriage,portabletanksshallbeadequatelyprotectedagainstdamagetotheshellandserviceequipmentresultingfromlateralandlongitudinalimpactandoverturning.Iftheshellandserviceequipmentaresoconstructedastowithstandimpactoroverturningitneednotbeprotectedinthisway.Examplesofsuchprotectionaregivenin6.7.2.17.5.4.2.1.3.Certainsubstancesarechemicallyunstable.Theyareacceptedforcarriageonlywhenthenecessarystepshavebeentakentopreventtheirdangerousdecomposition,transformationorpolymerizationduringcarriage.Tothisend,careshallinparticularbetakentoensurethatshellsdonotcontainanysubstancesliabletopromotethesereactions.4.2.1.4.Thetemperatureoftheoutersurfaceoftheshellexcludingopeningsandtheirclosuresorofthethermalinsulationshallnotexceed70°Cduringcarriage.Whensubstancesarecarriedatelevatedtemperaturesineitherliquidorsolidstate,theshellshallbethermallyinsulatedtomeetthiscondition.4.2.1.5.Emptyportabletanksnotcleanedandnotgas-freeshallcomplywiththesameprovisionsasportabletanksfilledwiththeprevioussubstance.4.2.1.6.Substancesshallnotbecarriedinthesameorinadjoiningcompartmentsofshellswhentheymayreactdangerouslywitheachother(seedefinitionfor‘dangerousreaction’in1.2.1)4.2.1.7.Thedesignapprovalcertificate,thetestreportandthecertificateshowingtheresultsoftheinitialinspectionandtestforeachportabletankissuedbythecompetentauthorityoritsauthorisedbodyshallberetainedbytheauthorityorbodyandtheowner.Ownersshallbeabletoprovidethisdocumentationupontherequestofanycompetentauthority.4.2.1.8.Unlessthenameofthesubstance(s)beingcarriedappearsonthemetalplatedescribedin6.7.2.20.2acopyofthecertificatespecifiedin6.7.2.18.1shallbemadeavailableupontherequestofacompetentauthorityoritsauthorisedbodyandreadilyprovidedbytheconsignor,consigneeoragent,asappropriate.4.2.1.9.Degreeoffilling4.2.1.9.1.Priortofilling,theconsignorshallensurethattheappropriateportabletankisusedandthattheportabletankisnotfilledwithsubstanceswhichincontactwiththematerialsoftheshell,gaskets,serviceequipmentandanyprotectivelinings,arelikelytoreactdangerouslywiththemtoformdangerousproductsorappreciablyweakenthesematerials.Theconsignormayneedtoconsultthemanufacturerofthesubstanceinconjunctionwiththecompetentauthorityforguidanceonthecompatibilityofthesubstancewiththeportabletankmaterials.4.2.1.9.1.1.Portabletanksshallnotbefilledabovetheextentprovidedin4.2.1.9.2to4.2.1.9.6.Theapplicabilityof4.2.1.9.2,4.2.1.9.3or4.2.1.9.5.1toindividualsubstancesisspecifiedintheapplicableportabletankinstructionorspecialprovisionsin4.2.4.2.6or4.2.4.3andColumn(10)or(11)ofTableAofChapter3.2.4.2.1.9.2.Themaximumdegreeoffilling(in%)forgeneraluseisdeterminedbytheformula:Degreeoffilling¼971þαtr(cid:1)tfðÞOfficialJournaloftheEuropeanUnionEN26.1.2004L18/666OfficialJournaloftheEuropeanUnionEN26.1.2004L18/6674.2.1.9.3.Themaximumdegreeoffilling(in%)forliquidsofClass6.1andClass8,inpackinggroupsIandII,andliquidswithanabsolutevapourpressureofmorethan175kPa(1,75bar)at65°C,isdeterminedbytheformula:Degreeoffilling¼951þαtr(cid:1)tfðÞ4.2.1.9.4.Intheseformulae,αisthemeancoefficientofcubicalexpansionoftheliquidbetweenthemeantemperatureoftheliquidduringfilling(tf)andthemaximummeanbulktemperatureduringcarriage(tr)(bothin°C).Forliquidscarriedunderambientconditionsαcouldbecalculatedbytheformula:α¼d15(cid:1)d5035d50inwhichd15andd50arethedensitiesoftheliquidat15°Cand50°C,respectively.4.2.1.9.4.1.Themaximummeanbulktemperature(tr)shallbetakenas50°Cexceptthat,forjourneysundertemperateorextremeclimaticconditions,thecompetentauthoritiesconcernedmayagreetoalowerorrequireahighertemperature,asappropriate.4.2.1.9.5.Theprovisionsof4.2.1.9.2to4.2.1.9.4.1donotapplytoportabletankswhichcontainsubstancesmaintainedatatemperatureabove50°Cduringcarriage(e.g.bymeansofaheatingdevice).Forportabletanksequippedwithaheatingdevice,atemperatureregulatorshallbeusedtoensurethemaximumdegreeoffillingisnotmorethan95%fullatanytimeduringcarriage.4.2.1.9.5.1.Themaximumdegreeoffilling(in%)forliquidscarriedunderelevatedtemperatureconditionsisdeterminedbytheformula:Degreeoffilling¼95drdfinwhichdfanddrarethedensitiesoftheliquidatthemeantemperatureoftheliquidduringfillingandthemaximummeanbulktemperatureduringcarriagerespectively.4.2.1.9.6.Portabletanksshallnotbeofferedforcarriage:(a)Withadegreeoffilling,forliquidshavingaviscositylessthan2680mm2/sat20°Cormaximumtemperatureofthesubstanceduringcarriageinthecaseoftheheatedsubstance,ofmorethan20%butlessthan80%unlesstheshellsofportabletanksaredivided,bypartitionsorsurgeplates,intosectionsofnotmorethan7500litrescapacity;(b)Withresidueofsubstancespreviouslycarriedadheringtotheoutsideoftheshellorserviceequipment;(c)Whenleakingordamagedtosuchanextentthattheintegrityoftheportabletankoritsliftingorsecuringarrangementsmaybeaffected;and(d)Unlesstheserviceequipmenthasbeenexaminedandfoundtobeingoodworkingorder.4.2.1.9.7.Forkliftpocketsofportabletanksshallbeclosedoffwhenthetankisfilled.Thisprovisiondoesnotapplytoportabletankswhichaccordingto6.7.3.13.4neednotbeprovidedwithameansofclosingofftheforkliftpockets.4.2.1.10.AdditionalprovisionsapplicabletothecarriageofClass3substancesinportabletanks4.2.1.10.1.Allportabletanksintendedforthecarriageofflammableliquidsshallbeclosedandbefittedwithreliefdevicesinaccordancewith6.7.2.8to6.7.2.15.4.2.1.10.1.1.Forportabletanksintendedforuseonlyonland,openventingsystemsmaybeusedifallowedaccordingtoChapter4.3.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/6684.2.1.11.AdditionalprovisionsapplicabletothecarriageofClasses4.1,4.2or4.3substances(otherthanClass4.1self-reactivesubstances)inportabletanks(Reserved)Note:ForClass4.1self-reactivesubstances,see4.2.1.13.1.4.2.1.12.AdditionalprovisionsapplicabletothecarriageofClass5.1substancesinportabletanks(Reserved)4.2.1.13.AdditionalprovisionsapplicabletothecarriageofClass5.2substancesandClass4.1self-reactivesubstancesinportabletanks4.2.1.13.1.Eachsubstanceshallhavebeentestedandareportsubmittedtothecompetentauthorityofthecountryoforiginforapproval.Notificationthereofshallbesenttothecompetentauthorityofthecountryofdestination.Thenotificationshallcontainrelevanttransportinformationandthereportwithtestresults.Thetestsundertakenshallincludethosenecessary:(a)Toprovethecompatibilityofallmaterialsnormallyincontactwiththesubstanceduringcarriage;(b)Toprovidedataforthedesignofthepressureandemergencyreliefdevicestakingintoaccountthedesigncharacteristicsoftheportabletank.Anyadditionalprovisionnecessaryforsafecarriageofthesubstanceshallbeclearlydescribedinthereport.4.2.1.13.2.ThefollowingprovisionsapplytoportabletanksintendedforthecarriageofTypeForganicperoxidesorTypeFself-reactivesubstanceswithaSelf-AcceleratingDecompositionTemperature(SADT)of55°Cormore.IncaseofconflicttheseprovisionsprevailoverthosespecifiedinSection6.7.2.Emergenciestobetakenintoaccountareself-acceleratingdecompositionofthesubstanceandfire-engulfmentasdescribedin4.2.1.13.8.4.2.1.13.3.Theadditionalprovisionsforcarriageoforganicperoxidesorself-reactivesubstanceswithaSADTlessthan55°Cinportabletanksshallbespecifiedbythecompetentauthorityofthecountryoforigin.Notificationthereofshallbesenttothecompetentauthorityofthecountryofdestination.4.2.1.13.4.Theportabletankshallbedesignedforatestpressureofatleast0,4MPa(4bar).4.2.1.13.5.Portabletanksshallbefittedwithtemperaturesensingdevices.4.2.1.13.6.Portabletanksshallbefittedwithpressure-reliefdevicesandemergency-reliefdevices.Vacuum-reliefdevicesmayalsobeused.Pressure-reliefdevicesshalloperateatpressuresdeterminedaccordingtoboththepropertiesofthesubstanceandtheconstructioncharacteristicsoftheportabletank.Fusibleelementsarenotallowedintheshell.4.2.1.13.7.Thepressure-reliefdevicesshallconsistofspring-loadedvalvesfittedtopreventsignificantbuild-upwithintheportabletankofthedecompositionproductsandvapoursreleasedatatemperatureof50°C.Thecapacityandstart-to-dischargepressureofthereliefvalvesshallbebasedontheresultsofthetestsspecifiedin4.2.1.13.1.Thestart-to-dischargepressureshall,however,innocasebesuchthatliquidwouldescapefromthevalve(s)iftheportabletankwereoverturned.4.2.1.13.8.Theemergency-reliefdevicesmaybeofthespring-loadedorfrangibletypes,oracombinationofthetwo,designedtoventallthedecompositionproductsandvapoursevolvedduringaperiodofnotlessthanonehourofcompletefire-engulfmentascalculatedbythefollowingformula:q=70691×F×A0,82where:q=heatabsorption[W]A=wettedarea[m2]F=insulationfactorF=1fornon-insulatedshells,orOfficialJournaloftheEuropeanUnionEN26.1.2004L18/669F¼U923(cid:1)TðÞ47032forinsulatedshellswhere:K=heatconductivityofinsulationlayer[Wm-1K-1]L=thicknessofinsulationlayer[m]U=K/L=heattransfercoefficientoftheinsulation[Wm-2K-1]T=temperatureofthesubstanceatrelievingconditions[K]Thestart-to-dischargepressureoftheemergency-reliefdevice(s)shallbehigherthanthatspecifiedin4.2.1.13.7andbasedontheresultsofthetestsreferredtoin4.2.1.13.1.Theemergency-reliefdevicesshallbedimensionedinsuchawaythatthemaximumpressureintheportabletankneverexceedsthetestpressureofthetank.Note:Anexampleofamethodtodeterminethesizeofemergency-reliefdevicesisgiveninAppendix5ofthe‘Manualoftestsandcriteria’.4.2.1.13.9.Forinsulatedportabletanksthecapacityandsettingofemergency-reliefdevice(s)shallbedeterminedassumingalossofinsulationfrom1%ofthesurfacearea.4.2.1.13.10.Vacuum-reliefdevicesandspring-loadedvalvesshallbeprovidedwithflamearresters.Dueattentionshallbepaidtothereductionofthereliefcapacitycausedbytheflamearrester.4.2.1.13.11.Serviceequipmentsuchasvalvesandexternalpipingshallbesoarrangedthatnosubstanceremainsinthemafterfillingtheportabletank.4.2.1.13.12.Portabletanksmaybeeitherinsulatedorprotectedbyasun-shield.IftheSADTofthesubstanceintheportabletankis55°Corless,ortheportabletankisconstructedofaluminium,theportabletankshallbecompletelyinsulated.Theoutersurfaceshallbefinishedinwhiteorbrightmetal.4.2.1.13.13.Thedegreeoffillingshallnotexceed90%at15C.4.2.1.13.14.Themarkingasrequiredin6.7.2.20.2shallincludetheUNnumberandthetechnicalnamewiththeapprovedconcentrationofthesubstanceconcerned.4.2.1.13.15.Organicperoxidesandself-reactivesubstancesspecificallylistedinportabletankinstructionT23in4.2.4.2.6maybecarriedinportabletanks.4.2.1.14.AdditionalprovisionsapplicabletothecarriageofClass6.1substancesinportabletanks(Reserved)4.2.1.15.AdditionalprovisionsapplicabletothecarriageofClass7substancesinportabletanks4.2.1.15.1.Portabletanksusedforthecarriageofradioactivematerialshallnotbeusedforthecarriageofothergoods.4.2.1.15.2.Thedegreeoffillingforportabletanksshallnotexceed90%or,alternatively,anyothervalueapprovedbythecompetentauthority.4.2.1.16.AdditionalprovisionsapplicabletothecarriageofClass8substancesinportabletanks4.2.1.16.1.Pressure-reliefdevicesofportabletanksusedforthecarriageofClass8substancesshallbeinspectedatintervalsnotexceedingoneyear.4.2.1.17.AdditionalprovisionsapplicabletothecarriageofClass9substancesinportabletanks(Reserved)OfficialJournaloftheEuropeanUnionEN26.1.2004L18/6704.2.2.Generalprovisionsfortheuseofportabletanksforthecarriageofnon-refrigeratedliquefiedgases4.2.2.1.Thissectionprovidesgeneralprovisionsapplicabletotheuseofportabletanksforthecarriageofnon-refrigeratedliquefiedgases.4.2.2.2.Portabletanksshallconformtothedesign,construction,inspectionandtestingrequirementsdetailedin6.7.3.Non-refrigeratedliquefiedgasesshallbecarriedinportabletanksconformingtoportabletankinstructionT50asdescribedin4.2.4.2.6andanyportabletankspecialprovisionsassignedtospecificnon-refrigeratedliquefiedgasesinColumn(11)ofTableAofChapter3.2anddescribedin4.2.4.3.4.2.2.3.Duringcarriage,portabletanksshallbeadequatelyprotectedagainstdamagetotheshellandserviceequipmentresultingfromlateralandlongitudinalimpactandoverturning.Iftheshellandserviceequipmentaresoconstructedastowithstandimpactoroverturningitneednotbeprotectedinthisway.Examplesofsuchprotectionaregivenin6.7.3.13.5.4.2.2.4.Certainnon-refrigeratedliquefiedgasesarechemicallyunstable.Theyareacceptedforcarriageonlywhenthenecessarystepshavebeentakentopreventtheirdangerousdecomposition,transformationorpolymerizationduringcarriage.Tothisend,careshallinparticularbetakentoensurethatportabletanksdonotcontainanynon-refrigeratedliquefiedgasesliabletopromotethesereactions.4.2.2.5.Unlessthenameofthegas(es)beingcarriedappearsonthemetalplatedescribedin6.7.3.16.2,acopyofthecertificatespecifiedin6.7.3.14.1shallbemadeavailableuponacompetentauthorityrequestandreadilyprovidedbytheconsignor,consigneeoragent,asappropriate.4.2.2.6.Emptyportabletanksnotcleanedandnotgas-freeshallcomplywiththesameprovisionsasportabletanksfilledwiththepreviousnon-refrigeratedliquefiedgas.4.2.2.7.Filling4.2.2.7.1.Priortofillingtheconsignorshallensurethattheportabletankisapprovedforthenon-refrigeratedliquefiedgastobecarriedandthattheportabletankisnotloadedwithnon-refrigeratedliquefiedgaseswhichincontactwiththematerialsoftheshell,gaskets,serviceequipmentandanyprotectivelinings,arelikelytoreactdangerouslywiththemtoformdangerousproductsorappreciablyweakenthesematerials.Duringfilling,thetemperatureofthenon-refrigeratedliquefiedgasshallfallwithinthelimitsofthedesigntemperaturerange.4.2.2.7.2.Themaximummassofnon-refrigeratedliquefiedgasperlitreofshellcapacity(kg/l)shallnotexceedthedensityofthenon-refrigeratedliquefiedgasat50°Cmultipliedby0,95.Furthermore,theshellshallnotbeliquid-fullat60°C.4.2.2.7.3.Portabletanksshallnotbefilledabovetheirmaximumpermissiblegrossmassandthemaximumpermissibleloadmassspecifiedforeachgastobecarried.4.2.2.8.Portabletanksshallnotbeofferedforcarriage:(a)Inanullageconditionliabletoproduceanunacceptablehydraulicforceduetosurgewithintheshell;(b)Whenleaking;(c)Whendamagedtosuchanextentthattheintegrityofthetankoritsliftingorsecuringarrangementsmaybeaffected;and(d)Unlesstheserviceequipmenthasbeenexaminedandfoundtobeingoodworkingorder.4.2.2.9.Forkliftpocketsofportabletanksshallbeclosedoffwhenthetankisfilled.Thisprovisiondoesnotapplytoportabletankswhichaccordingto6.7.4.12.4neednotbeprovidedwithameansofclosingofftheforkliftpockets.4.2.3.Generalprovisionsfortheuseofportabletanksforthecarriageofrefrigeratedliquefiedgases4.2.3.1.Thissectionprovidesgeneralprovisionsapplicabletotheuseofportabletanksforthecarriageofrefrigeratedliquefiedgases.4.2.3.2.Portabletanksshallconformtothedesign,construction,inspectionandtestingrequirementsdetailedin6.7.4.RefrigeratedliquefiedgasesshallbecarriedinportabletanksconformingtoportabletankinstructionT75asdescribedin4.2.4.2.6andtheportabletankspecialprovisionsassignedtoeachsubstanceinColumn(11)ofTableAofChapter3.2anddescribedin4.2.4.3.4.2.3.3.Duringcarriage,portabletanksshallbeadequatelyprotectedagainstdamagetotheshellandserviceequipmentresultingfromlateralandlongitudinalimpactandoverturning.Iftheshellandserviceequipmentaresoconstructedastowithstandimpactoroverturningitneednotbeprotectedinthisway.Examplesofsuchprotectionareprovidedin6.7.4.12.5.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/6714.2.3.4.Unlessthenameofthegas(es)beingcarriedappearsonthemetalplatedescribedin6.7.4.15.2,acopyofthecertificatespecifiedin6.7.4.13.1shallbemadeavailableuponacompetentauthorityrequestandreadilyprovidedbytheconsignor,consigneeoragent,asappropriate.4.2.3.5.Emptyportabletanksnotcleanedandnotgas-freeshallcomplywiththesameprovisionsasportabletanksfilledwiththeprevioussubstance.4.2.3.6.Filling4.2.3.6.1.Priortofillingtheconsignorshallensurethattheportabletankisapprovedfortherefrigeratedliquefiedgastobecarriedandthattheportabletankisnotloadedwithrefrigeratedliquefiedgaseswhichincontactwiththematerialsoftheshell,gaskets,serviceequipmentandanyprotectivelinings,arelikelytoreactdangerouslywiththemtoformdangerousproductsorappreciablyweakenthesematerials.Duringfilling,thetemperatureoftherefrigeratedliquefiedgasshallbewithinthelimitsofthedesigntemperaturerange.4.2.3.6.2.Inestimatingtheinitialdegreeoffillingthenecessaryholdingtimefortheintendedjourneyincludinganydelayswhichmightbeencounteredshallbetakenintoconsideration.Theinitialdegreeoffillingoftheshell,exceptasprovidedforin4.2.3.6.3and4.2.3.6.4,shallbesuchthatifthecontents,excepthelium,weretoberaisedtoatemperatureatwhichthevapourpressureisequaltothemaximumallowableworkingpressure(MAWP)thevolumeoccupiedbyliquidwouldnotexceed98%.4.2.3.6.3.Shellsintendedforthecarriageofheliumcanbefilleduptobutnotabovetheinletofthepressure-reliefdevice.4.2.3.6.4.Ahigherinitialdegreeoffillingmaybeallowed,subjecttoapprovalbythecompetentauthority,whentheintendeddurationofcarriageisconsiderablyshorterthantheholdingtime.4.2.3.7.Actualholdingtime4.2.3.7.1.Theactualholdingtimeshallbecalculatedforeachjourneyinaccordancewithaprocedurerecognizedbythecompetentauthority,onthebasisofthefollowing:(a)Thereferenceholdingtimefortherefrigeratedliquefiedgastobecarried(see6.7.4.2.8.1)(asindicatedontheplatereferredtoin6.7.4.15.1);(b)Theactualfillingdensity;(c)Theactualfillingpressure;(d)Thelowestsetpressureofthepressurelimitingdevice(s).4.2.3.7.2.Theactualholdingtimeshallbemarkedeitherontheportabletankitselforonametalplatefirmlysecuredtotheportabletank,inaccordancewith6.7.4.15.2.4.2.3.8.Portabletanksshallnotbeofferedforcarriage:(a)Inanullageconditionliabletoproduceanunacceptablehydraulicforceduetosurgewithintheshell;(b)Whenleaking;(c)Whendamagedtosuchanextentthattheintegrityoftheportabletankoritsliftingorsecuringarrangementsmaybeaffected;(d)Unlesstheserviceequipmenthasbeenexaminedandfoundtobeingoodworkingorder;(e)Unlesstheactualholdingtimefortherefrigeratedliquefiedgasbeingcarriedhasbeendeterminedinaccordancewith4.2.3.7andtheportabletankismarkedinaccordancewith6.7.4.15.2;and(f)Unlessthedurationofcarriage,aftertakingintoconsiderationanydelayswhichmightbeencountered,doesnotexceedtheactualholdingtime.4.2.3.9.Forkliftpocketsofportabletanksshallbeclosedoffwhenthetankisfilled.Thisprovisiondoesnotapplytoportabletankswhichaccordingto6.7.4.12.4,neednotbeprovidedwithameansofclosingofftheforkliftpockets.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/6724.2.4.Portabletankinstructionsandspecialprovisions4.2.4.1.General4.2.4.1.1.Thissectionincludestheportabletankinstructionsandspecialprovisionsapplicabletodangerousgoodsauthorisedtobecarriedinportabletanks.Eachportabletankinstructionisidentifiedbyanalpha-numericcode(e.g.T1).Column(10)ofTableAofChapter3.2indicatestheportabletankinstructionthatshallbeusedforeachsubstancepermittedforcarriageinaportabletank.WhennoportabletankinstructionappearsinColumn(10)foraspecificdangerousgoodsentrythencarriageofthesubstanceinportabletanksisnotpermittedunlessacompetentauthorityapprovalisgrantedasdetailedin6.7.1.3.PortabletankspecialprovisionsareassignedtospecificdangerousgoodsinColumn(11)ofTableAofChapter3.2.Eachportabletankspecialprovisionisidentifiedbyanalpha-numericcode(e.g.TP1).Alistingoftheportabletankspecialprovisionsisprovidedin4.2.4.3.4.2.4.2.Portabletankinstructions4.2.4.2.1.PortabletankinstructionsapplytodangerousgoodsofClasses2to9.Portabletankinstructionsprovidespecificinformationrelevanttoportabletanksprovisionsapplicabletospecificsubstances.TheseprovisionsshallbemetinadditiontothegeneralprovisionsinthisChapterandthegeneralrequirementsinChapter6.7.4.2.4.2.2.ForsubstancesofClasses3to9,theportabletankinstructionsindicatetheapplicableminimumtestpressure,theminimumshellthickness(inreferencesteel),bottomopeningrequirementsandpressurereliefrequirements.InportabletankinstructionT23,self-reactivesubstancesofClass4.1andClass5.2organicperoxidespermittedtobecarriedinportabletanksarelistedalongwiththeapplicablecontrolandemergencytemperatures.4.2.4.2.3.Non-refrigeratedliquefiedgasesareassignedtoportabletankinstructionT50.T50providesthemaximumallowableworkingpressures,therequirementsfortheopeningsbelowliquidlevel,pressure-reliefrequirementsandmaximumfillingdensityrequirementsfornon-refrigeratedliquefiedgasespermittedforcarriageinportabletanks.4.2.4.2.4.RefrigeratedliquefiedgasesareassignedtoportabletankinstructionT75.4.2.4.2.5.DeterminationoftheappropriateportabletankinstructionsWhenaspecificportabletankinstructionisspecifiedinColumn(10)ofTableAofChapter3.2foraspecificdangerousgoodsentryadditionalportabletankswhichpossesshigherminimumtestpressures,greatershellthicknesses,morestringentbottomopeningandpressure-reliefdevicearrangementsmaybeused.Thefollowingguidelinesapplytodeterminingtheappropriateportabletankswhichmaybeusedforcarriageofparticularsubstances:PortabletankinstructionspecifiedPortabletankinstructionsalsopermittedT1T2,T3,T4,T5,T6,T7,T8,T9,T10,T11,T12,T13,T14,T15,T16,T17,T18,T19,T20,T21,T22T2T4,T5,T6,T7,T8,T9,T10,T11,T12,T13,T14,T15,T16,T17,T18,T19,T20,T21,T22T3T4,T5,T6,T7,T8,T9,T10,T11,T12,T13,T14,T15,T16,T17,T18,T19,T20,T21,T22T4T5,T6,T7,T8,T9,T10,T11,T12,T13,T14,T15,T16,T17,T18,T19,T20,T21,T22T5T10,T14,T19,T20,T22T6T7,T8,T9,T10,T11,T12,T13,T14,T15,T16,T17,T18,T19,T20,T21,T22T7T8,T9,T10,T11,T12,T13,T14,T15,T16,T17,T18,T19,T20,T21,T22T8T9,T10,T13,T14,T19,T20,T21,T22OfficialJournaloftheEuropeanUnionEN26.1.2004L18/673PortabletankinstructionspecifiedPortabletankinstructionsalsopermittedT9T10,T13,T14,T19,T20,T21,T22T10T14,T19,T20,T22T11T12,T13,T14,T15,T16,T17,T18,T19,T20,T21,T22T12T14,T16,T18,T19,T20,T22T13T14,T19,T20,T21,T22T14T19,T20,T22T15T16,T17,T18,T19,T20,T21,T22T16T18,T19,T20,T22T17T18,T19,T20,T21,T22T18T19,T20,T22T19T20,T22T20T22T21T22T22NoneT23None4.2.4.2.6.PortabletankinstructionsT1-T22PORTABLETANKINSTRUCTIONST1-T22TheseportabletankinstructionsapplytoliquidandsolidsubstancesofClasses3to9.ThegeneralprovisionsofSection4.2.1andtherequirementsofSection6.7.2shallbemet.PortabletankinstructionMinimumtestpressure(bar)Minimumshellthickness(inmm-referencesteel)(see6.7.2.4)Pressure-reliefrequirements(see6.7.2.8)Bottomopeningrequire-ments(see6.7.2.6)T11,5See6.7.2.4.2NormalSee6.7.2.6.2T21,5See6.7.2.4.2NormalSee6.7.2.6.3T32,65See6.7.2.4.2NormalSee6.7.2.6.2OfficialJournaloftheEuropeanUnionEN26.1.2004L18/674T1-T22PORTABLETANKINSTRUCTIONST1-T22TheseportabletankinstructionsapplytoliquidandsolidsubstancesofClasses3to9.ThegeneralprovisionsofSection4.2.1andtherequirementsofSection6.7.2shallbemet.PortabletankinstructionMinimumtestpressure(bar)Minimumshellthickness(inmm-referencesteel)(see6.7.2.4)Pressure-reliefrequirements(see6.7.2.8)Bottomopeningrequire-ments(see6.7.2.6)T42,65See6.7.2.4.2NormalSee6.7.2.6.3T52,65See6.7.2.4.2See6.7.2.8.3NotallowedT64See6.7.2.4.2NormalSee6.7.2.6.2T74See6.7.2.4.2NormalSee6.7.2.6.3T84See6.7.2.4.2NormalNotallowedT946mmNormalNotallowedT1046mmSee6.7.2.8.3NotallowedT116See6.7.2.4.2NormalSee6.7.2.6.3T126See6.7.2.4.2See6.7.2.8.3See6.7.2.6.3T1366mmNormalNotallowedT1466mmSee6.7.2.8.3NotallowedT1510See6.7.2.4.2NormalSee6.7.2.6.3T1610See6.7.2.4.2See6.7.2.8.3See6.7.2.6.3T17106mmNormalSee6.7.2.6.3T18106mmSee6.7.2.8.3See6.7.2.6.3T19106mmSee6.7.2.8.3NotallowedT20108mmSee6.7.2.8.3NotallowedT211010mmNormalNotallowedT221010mmSee6.7.2.8.3NotallowedOfficialJournaloftheEuropeanUnionEN26.1.2004L18/675T23PORTABLETANKINSTRUCTIONT23Thisportabletankinstructionappliestoself-reactivesubstancesofClass4.1andorganicperoxidesofClass5.2.ThegeneralprovisionsofSection4.2.1andtherequirementsofSection6.7.2shallbemet.Theadditionalprovisionsspecifictoself-reactivesubstancesofClass4.1andorganicperoxidesofClass5.2in4.2.1.13shallalsobemet.UNNoSubstanceMinimumtestpressure(bar)Minimumshellthick-ness(mm-referencesteel)Bottomopeningrequire-mentsPressure-reliefrequire-mentsDegreeoffillingControltemperatureEmergencytemperature3109ORGANICPEROXIDE,TYPEF,LIQUIDtert-Butylhydro-perox-ide(a),notmorethan72%withwaterCumylhydro-peroxide,notmorethan90%indiluenttypeADi-tert-butylperoxide,notmorethan32%indiluenttypeAIsopropylcumylhydro-peroxide,notmorethan72%indiluenttypeAp-Menthylhydro-peroxide,notmorethan72%indiluenttypeAPinanylhydro-peroxide,notmorethan50%indiluenttypeA4See6.7.2.4.2See6.7.2.6.3See6.7.2.8.24.2.1.13.64.2.1.13.74.2.1.13.8See4.2.1.13.133110ORGANICPEROXIDETYPEF,SOLIDDicumylperoxide(b)4See6.7.2.4.2See6.7.2.6.3See6.7.2.8.24.2.1.13.64.2.1.13.74.2.1.13.8See4.2.1.13.13OfficialJournaloftheEuropeanUnionEN26.1.2004L18/676T23PORTABLETANKINSTRUCTIONT23Thisportabletankinstructionappliestoself-reactivesubstancesofClass4.1andorganicperoxidesofClass5.2.ThegeneralprovisionsofSection4.2.1andtherequirementsofSection6.7.2shallbemet.Theadditionalprovisionsspecifictoself-reactivesubstancesofClass4.1andorganicperoxidesofClass5.2in4.2.1.13shallalsobemet.UNNoSubstanceMinimumtestpressure(bar)Minimumshellthick-ness(mm-referencesteel)Bottomopeningrequire-mentsPressure-reliefrequire-mentsDegreeoffillingControltemperatureEmergencytemperature3119ORGANICPEROXIDE,TYPEF,LIQUID,TEMPERATURECONTROLLED4See6.7.2.4.2See6.7.2.6.3See6.7.2.8.24.2.1.13.64.2.1.13.74.2.1.13.8See4.2.1.13.13(c)(c)tert-Butylperoxyace-tate,notmorethan32%indiluenttypeB+30°C+35°Ctert-Butylperoxy-2-ethylhexanoate,notmorethan32%indiluenttypeB+15°C+20°Ctert-Butylperoxypiva-late,notmorethan27%indiluenttypeB+5°C+10°Ctert-Butylperoxy-3,5,5-trimethyl-hexanoate,notmorethan32%indiluenttypeB+35°C+40°CDi-(3,5,5-trimethyl-hexanoyl)peroxide,notmorethan38%indiluenttypeA0°C+5°C3120ORGANICPEROXIDE,TYPEF,SOLID,TEMPERATURECONTROLLED4See6.7.2.4.2See6.7.2.6.3See6.7.2.8.24.2.1.13.64.2.1.13.74.2.1.13.8See4.2.1.13.13(c)(c)3229SELF-REACTIVELIQUIDTYPEF4See6.7.2.4.2See6.7.2.6.3See6.7.2.8.24.2.1.13.64.2.1.13.74.2.1.13.8See4.2.1.13.133230SELF-REACTIVESOLIDTYPEF4See6.7.2.4.2See6.7.2.6.3See6.7.2.8.24.2.1.13.64.2.1.13.74.2.1.13.8See4.2.1.13.13OfficialJournaloftheEuropeanUnionEN26.1.2004L18/677T23PORTABLETANKINSTRUCTIONT23Thisportabletankinstructionappliestoself-reactivesubstancesofClass4.1andorganicperoxidesofClass5.2.ThegeneralprovisionsofSection4.2.1andtherequirementsofSection6.7.2shallbemet.Theadditionalprovisionsspecifictoself-reactivesubstancesofClass4.1andorganicperoxidesofClass5.2in4.2.1.13shallalsobemet.UNNoSubstanceMinimumtestpressure(bar)Minimumshellthick-ness(mm-referencesteel)Bottomopeningrequire-mentsPressure-reliefrequire-mentsDegreeoffillingControltemperatureEmergencytemperature3239SELF-REACTIVELIQUIDTYPEF,TEMPERATURECONTROLLED4See6.7.2.4.2See6.7.2.6.3See6.7.2.8.24.2.1.13.64.2.1.13.74.2.1.13.8See4.2.1.13.13(c)(c)3240SELF-REACTIVESOLIDTYPEF,TEMPERA-TURECONTROLLED4See6.7.2.4.2See6.7.2.6.3See6.7.2.8.24.2.1.13.64.2.1.13.74.2.1.13.8See4.2.1.13.13(c)(c)(a)Providedthatstepshavebeentakentoachievethesafetyequivalenceof65%tert-Butylhydroperoxideand35%water.(b)Maximumquantityperportabletank:2000kg.(c)Asapprovedbythecompetentauthority.T50PORTABLETANKINSTRUCTIONT50Thisportabletankinstructionappliestonon-refrigeratedliquefiedgases.ThegeneralprovisionsofSection4.2.2andtherequirementsofSection6.7.3shallbemet.UNNoNon-refrigeratedliquefiedgasesMaximumallowableworkingpres-sure(bar)a)smallb)barec)sunshieldd)insulatedOpeningsbelowliquidlevelPressure-reliefrequirements(see6.7.3.7)Maximumfillingdensity(kg/l)1005Ammonia,anhydrous29,025,722,019,7AllowedSee6.7.3.7.30,531009Bromotrifluoromethane(RefrigerantgasR13B1)38,034,730,027,5AllowedNormal1,131010Butadienes,stabilised7,57,07,07,0AllowedNormal0,551011Butane7,07,07,07,0AllowedNormal0,51OfficialJournaloftheEuropeanUnionEN26.1.2004L18/678T50PORTABLETANKINSTRUCTIONT50Thisportabletankinstructionappliestonon-refrigeratedliquefiedgases.ThegeneralprovisionsofSection4.2.2andtherequirementsofSection6.7.3shallbemet.UNNoNon-refrigeratedliquefiedgasesMaximumallowableworkingpres-sure(bar)a)smallb)barec)sunshieldd)insulatedOpeningsbelowliquidlevelPressure-reliefrequirements(see6.7.3.7)Maximumfillingdensity(kg/l)1012Butylene8,07,07,07,0AllowedNormal0,531017Chlorine19,017,015,013,5NotallowedSee6.7.3.7.31,251018Chlorodifluoromethane(RefrigerantgasR22)26,024,021,019,0AllowedNormal1,031020Chloropentafluoroethane(RefrigerantgasR115)23,020,018,016,0AllowedNormal1,0610211-Chloro-1,2,2,2-tetrafluor-oethane(RefrigerantgasR124)10,39,87,97,0AllowedNormal1,201027Cyclopropane18,016,014,513,0AllowedNormal0,531028Dichlorodifluoromethane(RefrigerantgasR12)16,015,013,011,5AllowedNormal1,151029Dichlorofluoromethane(RefrigerantgasR21)7,07,07,07,0AllowedNormal1,2310301,1-Difluoroethane(Refrig-erantgasR152a)16,014,012,411,0AllowedNormal0,791032Dimethylamine,anhydrous7,07,07,07,0AllowedNormal0,59OfficialJournaloftheEuropeanUnionEN26.1.2004L18/679T50PORTABLETANKINSTRUCTIONT50Thisportabletankinstructionappliestonon-refrigeratedliquefiedgases.ThegeneralprovisionsofSection4.2.2andtherequirementsofSection6.7.3shallbemet.UNNoNon-refrigeratedliquefiedgasesMaximumallowableworkingpres-sure(bar)a)smallb)barec)sunshieldd)insulatedOpeningsbelowliquidlevelPressure-reliefrequirements(see6.7.3.7)Maximumfillingdensity(kg/l)1033Dimethylether15,513,812,010,6AllowedNormal0,581036Ethylamine7,07,07,07,0AllowedNormal0,611037Ethylchloride7,07,07,07,0AllowedNormal0,801040Ethyleneoxidewithnitrogenuptoatotalpressureof1MPa(10bar)at50°C———10,0NotallowedSee6.7.3.7.30,781041Ethyleneoxideandcarbondioxidemixturewithmorethan9%butnotmorethan87%ethyleneoxideSeeMAWPdefinitionin6.7.3.1AllowedNormalSee4.2.2.71055Isobutylene8,17,07,07,0AllowedNormal0,521060Methyllacetyleneandpropa-dienemixture,stabilised28,024,522,020,0AllowedNormal0,431061Methylamine,anhydrous10,89,67,87,0AllowedNormal0,581062Methylbromide7,07,07,07,0NotallowedSee6.7.3.7.31,511063Methylchloride(RefrigerantgasR40)14,512,711,310,0AllowedNormal0,81OfficialJournaloftheEuropeanUnionEN26.1.2004L18/680T50PORTABLETANKINSTRUCTIONT50Thisportabletankinstructionappliestonon-refrigeratedliquefiedgases.ThegeneralprovisionsofSection4.2.2andtherequirementsofSection6.7.3shallbemet.UNNoNon-refrigeratedliquefiedgasesMaximumallowableworkingpres-sure(bar)a)smallb)barec)sunshieldd)insulatedOpeningsbelowliquidlevelPressure-reliefrequirements(see6.7.3.7)Maximumfillingdensity(kg/l)1064Methylmercaptan7,07,07,07,0NotallowedSee6.7.3.7.30,781067Dinitrogentetroxide7,07,07,07,0NotallowedSee6.7.3.7.31,301075Petroleumgas,liquefiedSeeMAWPdefinitionin6.7.3.1AllowedNormalSee4.2.2.71077Propylene28,024,522,020,0AllowedNormal0,431078Refrigerantgas,n.o.s.SeeMAWPdefinitionin6.7.3.1AllowedNormalSee4.2.2.71079Sulphurdioxide11,610,38,57,6NotallowedSee6.7.3.7.31,231082Trifluorochloroethylene,stabi-lised(RefrigerantgasR1113)17,015,013,111,6NotallowedSee6.7.3.7.31,131083Trimethylamine,anhydrous7,07,07,07,0AllowedNormal0,561085Vinylbromide,stabilised7,07,07,07,0AllowedNormal1,371086Vinylchloride,stabilised10,69,38,07,0AllowedNormal0,811087Vinylmethylether,stabilised7,07,07,07,0AllowedNormal0,67OfficialJournaloftheEuropeanUnionEN26.1.2004L18/681T50PORTABLETANKINSTRUCTIONT50Thisportabletankinstructionappliestonon-refrigeratedliquefiedgases.ThegeneralprovisionsofSection4.2.2andtherequirementsofSection6.7.3shallbemet.UNNoNon-refrigeratedliquefiedgasesMaximumallowableworkingpres-sure(bar)a)smallb)barec)sunshieldd)insulatedOpeningsbelowliquidlevelPressure-reliefrequirements(see6.7.3.7)Maximumfillingdensity(kg/l)1581Chloropicrinandmethylbromidemixture7,07,07,07,0NotallowedSee6.7.3.7.31,511582Chloropicrinandmethylchloridemixture19,216,915,113,1NotallowedSee6.7.3.7.30,811858Hexafluoropropylene(Refrig-erantgasR1216)19,216,915,113,1AllowedNormal1,111912Methylchlorideandmethy-lenechloridemixture15,213,011,610,1AllowedNormal0,8119581,2-Dichloro-1,1,2,2-tetra-fluoroethane(RefrigerantgasR114)7,07,07,07,0AllowedNormal1,301965Hydrocarbongas,mixtureliquefied,n.o.s.SeeMAWPdefinitionin6.7.3.1AllowedNormalSee4.2.2.71969Isobutane8,57,57,07,0AllowedNormal0,491973Chlorodifluoromethaneandchloropentafluoroethanemixturewithfixedboilingpoint,withapproximately49%chlorodifluoromethane(RefrigerantgasR502)28,325,322,820,3AllowedNormal1,051974Chlorodifluorobromomethane(RefrigerantgasR12B1)7,47,07,07,0AllowedNormal1,611976Octafluorocyclobutane(RefrigerantgasRC318)8,87,87,07,0AllowedNormal1,34OfficialJournaloftheEuropeanUnionEN26.1.2004L18/682T50PORTABLETANKINSTRUCTIONT50Thisportabletankinstructionappliestonon-refrigeratedliquefiedgases.ThegeneralprovisionsofSection4.2.2andtherequirementsofSection6.7.3shallbemet.UNNoNon-refrigeratedliquefiedgasesMaximumallowableworkingpres-sure(bar)a)smallb)barec)sunshieldd)insulatedOpeningsbelowliquidlevelPressure-reliefrequirements(see6.7.3.7)Maximumfillingdensity(kg/l)1978Propane22,520,418,016,5AllowedNormal0,4219831-Chloro-2,2,2-trifluoroethane(RefrigerantgasR133a)7,07,07,07,0AllowedNormal1,1820351,1,1-Trifluoroethane(Refrig-erantgasR143a)31,027,524,221,8AllowedNormal0,762424Octafluoropropane(Refrig-erantgasR218)23,120,818,616,6AllowedNormal1,0725171-Chloro-1,1-difluoroethane(RefrigerantgasR142b)8,97,87,07,0AllowedNormal0,992602Dichlorodifluoromethaneanddifluoroethaneazeotropicmixturewithapproximately74%dichlorodifluoro-methane(RefrigerantgasR500)20,018,016,014,5AllowedNormal1,013057Trifluoroacetylchloride14,612,911,39,9Notallowed6.7.3.7.31,173070Ethyleneoxideanddichloro-difluoromethanemixturewithnotmorethan12,5%ethy-leneoxide14,012,011,09,0Allowed6.7.3.7.31,093153Perfluoro(methylvinylether)14,313,411,210,2AllowedNormal1,1431591,1,1,2-Tetrafluoroethane(RefrigerantgasR134a)17,715,713,812,1AllowedNormal1,04OfficialJournaloftheEuropeanUnionEN26.1.2004L18/683T50PORTABLETANKINSTRUCTIONT50Thisportabletankinstructionappliestonon-refrigeratedliquefiedgases.ThegeneralprovisionsofSection4.2.2andtherequirementsofSection6.7.3shallbemet.UNNoNon-refrigeratedliquefiedgasesMaximumallowableworkingpres-sure(bar)a)smallb)barec)sunshieldd)insulatedOpeningsbelowliquidlevelPressure-reliefrequirements(see6.7.3.7)Maximumfillingdensity(kg/l)3161Liquefiedgas,flammable,n.o.s.SeeMAWPdefinitionin6.7.3.1AllowedNormalSee4.2.2.73163Liquefiedgas,n.o.s.SeeMAWPdefinitionin6.7.3.1AllowedNormalSee4.2.2.73220Pentafluoroethane(RefrigerantgasR125)34,430,827,524,5AllowedNormal0,953252Difluoromethane(RefrigerantgasR32)43,039,034,430,5AllowedNormal0,783296Heptafluoropropane(Refrig-erantgasR227)16,014,012,511,0AllowedNormal1,203297Ethyleneoxideandchlorote-trafluoroethanemixture,withnotmorethan8,8%ethy-leneoxide8,17,07,07,0AllowedNormal1,163298Ethyleneoxideandpenta-fluoroethanemixture,withnotmorethan7,9%ethyleneoxide25,923,420,918,6AllowedNormal1,023299Ethyleneoxideandtetrafluor-oethanemixture,withnotmorethan5,6%ethyleneoxide16,714,712,911,2AllowedNormal1,033318Ammoniasolution,relativedensitylessthan0,880at15°Cinwater,withmorethan50%ammoniaSeeMAWPdefinitionin6.7.3.1AllowedSee6.7.3.7.3See4.2.2.73337RefrigerantgasR404A31,628,325,322,5AllowedNormal0,843338RefrigerantgasR407A31,328,125,122,4AllowedNormal0,95OfficialJournaloftheEuropeanUnionEN26.1.2004L18/684T50PORTABLETANKINSTRUCTIONT50Thisportabletankinstructionappliestonon-refrigeratedliquefiedgases.ThegeneralprovisionsofSection4.2.2andtherequirementsofSection6.7.3shallbemet.UNNoNon-refrigeratedliquefiedgasesMaximumallowableworkingpres-sure(bar)a)smallb)barec)sunshieldd)insulatedOpeningsbelowliquidlevelPressure-reliefrequirements(see6.7.3.7)Maximumfillingdensity(kg/l)3339RefrigerantgasR407B33,029,626,523,6AllowedNormal0,953340RefrigerantgasR407C29,926,823,921,3AllowedNormal0,95T75PORTABLETANKINSTRUCTIONT75Thisportabletankinstructionappliestorefrigeratedliquefiedgases.ThegeneralprovisionsofSection4.2.3andtherequirementsofSection6.7.4shallbemet.4.2.4.3.PortabletankspecialprovisionsPortabletankspecialprovisionsareassignedtocertainsubstancestoindicateprovisionswhichareinadditiontoorinlieuofthoseprovidedbytheportabletankinstructionsortherequirementsinChapter6.7.Portabletankspecialprovisionsareidentifiedbyanalphanumericcodebeginningwiththeletters‘TP’(tankprovision)andareassignedtospecificsubstancesincolumn11ofTableAofChapter3.2.Thefollowingisalistoftheportabletankspecialprovisions:TP1Thedegreeoffillingprescribedin4.2.1.9.2shallnotbeexceededDegreeoffilling¼971þαtr(cid:1)tfðÞ(cid:1)(cid:2)TP2Thedegreeoffillingprescribedin4.2.1.9.3shallnotbeexceededDegreeoffilling¼951þαtr(cid:1)tfðÞ(cid:1)(cid:2)TP3Forliquidscarriedunderelevatedtemperatureconditionsthedegreeoffillingprescribedin4.2.1.9.5.1shallnotbeexceededDegreeoffilling¼95drdf(cid:1)(cid:2)TP4Thedegreeoffillingshallnotexceed90%or,alternatively,anyothervalueapprovedbythecompetentauthority(see4.2.1.15.2).TP5(Reserved)TP6Topreventthetankburstinginanyevent,includingfireengulfment,itshallbeprovidedwithpressure-reliefdeviceswhichareadequateinrelationtothecapacityofthetankandtothenatureofthesubstancecarried.Thedeviceshallalsobecompatiblewiththesubstance.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/685TP7Airshallbeeliminatedfromthevapourspacebynitrogenorothermeans.TP8Thetestpressuremaybereducedto1,5barwhentheflash-pointofthesubstancescarriedisgreaterthan0°C.TP9Asubstanceunderthisdescriptionshallonlybecarriedinaportabletankunderanapprovalgrantedbythecompetentauthority.TP10Aleadlining,notlessthan5mmthick,whichshallbetestedannually,oranothersuitableliningmaterialapprovedbythecompetentauthorityisrequired.TP12Thissubstanceishighlycorrosivetosteel.TP13Self-containedbreathingapparatusshallbeprovidedwhenthissubstanceiscarried.TP16Thetankshallbefittedwithaspecialdevicetopreventunder-pressureandexcesspressureduringnormalcarriageconditions.Thisdeviceshallbeapprovedbythecompetentauthority.Pressure-reliefrequirementsareasindicatedin6.7.2.8.3topreventcrystallisationoftheproductinthepressure-reliefvalve.TP17Onlyinorganicnon-combustiblematerialsshallbeusedforthermalinsulationofthetank.TP18Temperatureshallbemaintainedbetween18°Cand40°C.Portabletankscontainingsolidifiedmethacrylicacidshallnotbereheatedduringcarriage.TP19Thecalculatedshellthicknessshallbeincreasedby3mm.Shellthicknessshallbeverifiedultrasonicallyatintervalsmidwaybetweenperiodichydraulictests.TP20Thissubstanceshallonlybecarriedininsulatedtanksunderanitrogenblanket.TP21Theshellthicknessshallbenotlessthan8mm.Tanksshallbehydraulicallytestedandinternallyinspectedatintervalsnotexceeding2,5years.TP22Lubricantforjointsorotherdevicesshallbeoxygencompatible.TP23Carriagepermittedunderspecialconditionsprescribedbythecompetentauthorities.TP24Theportabletankmaybefittedwithadevicelocatedundermaximumfillingconditionsinthevapourspaceoftheshelltopreventthebuildupofexcesspressureduetotheslowdecompositionofthesubstancecarried.Thisdeviceshallalsopreventanunacceptableamountofleakageofliquidinthecaseofoverturningorentryofforeignmatterintothetank.Thisdeviceshallbeapprovedbythecompetentauthorityoritsauthorisedbody.TP25Sulphurtrioxide99,95%pureandabovemaybecarriedintankswithoutaninhibitorprovidedthatitismaintainedatatemperatureequaltoorabove32,5°C.TP26Whencarriedunderheatedconditions,theheatingdeviceshallbefittedoutsidetheshell.ForUN3176thisrequirementonlyapplieswhenthesubstancereactsdangerouslywithwater.TP27Aportabletankhavingaminimumtestpressureof4barmaybeusedifitisshownthatatestpressureof4barorlessisacceptableaccordingtothetestpressuredefinitionin6.7.2.1.TP28Aportabletankhavingaminimumtestpressureof2,65barmaybeusedifitisshownthatatestpressureof2,65barorlessisacceptableaccordingtothetestpressuredefinitionin6.7.2.1.TP29Aportabletankhavingaminimumtestpressureof1,5barmaybeusedifitisshownthatatestpressureof1,5barorlessisacceptableaccordingtothetestpressuredefinitionin6.7.2.1.CHAPTER4.3Useoffixedtanks(tank-vehicles),demountabletanks,tank-containersandtankswapbodieswithshellsmadeofmetallicmaterials,andbattery-vehiclesandmultiple-elementgascontainers(MEGCs)Note:ForportabletanksseeChapter4.2;forfibre-reinforcedplasticstanks,seeChapter4.4;forvacuum-operatedwastetanks,seeChapter4.5.4.3.1.Scope4.3.1.1.Provisionswhichtakeupthewholewidthofthepageapplybothtofixedtanks(tank-vehicles),demountabletanksandbattery-vehicles,andtotank-containers,tankswapbodiesandMEGCs.Provisionscontainedinasinglecolumnapplyonlyto:—fixedtanks(tank-vehicles),demountabletanksandbattery-vehicles(left-handcolumn),—tank-containers,tankswapbodiesandMEGCs(right-handcolumn).OfficialJournaloftheEuropeanUnionEN26.1.2004L18/6864.3.1.2.Theseprovisionsapplyto:fixedtanks(tank-vehicles),demountabletanksandbattery-vehiclestank-containers,tankswapbodiesandMEGCsusedforthecarriageofgaseous,liquid,powderyorgranularsubstances.4.3.1.3.Section4.3.2liststheprovisionsapplicabletofixedtanks(tank-vehicles),demountabletanks,tank-containersandtankswapbodies,intendedforthecarriageofsubstancesofallclasses,andtobattery-vehiclesandMEGCsintendedforthecarriageofgasesofClass2.Sections4.3.3and4.3.4containspecialprovisionsaddingtooramendingtheprovisionsofSection4.3.2.4.3.1.4.Forrequirementsconcerningtheconstruction,equipment,type-approval,testsandmarking,seeChapter6.8.4.3.1.5.FortransitionalmeasuresconcerningtheapplicationofthisChapter,see:1.6.3.1.6.44.3.2.Provisionsapplicabletoallclasses4.3.2.1.Use4.3.2.1.1.AsubstancesubjecttothisDirectivemaybecarriedinfixedtanks(tank-vehicles),demountabletanks,battery-vehicles,tank-containers,tankswapbodiesandMEGCsonlywhenprovisionismadeforatankcodeaccordingto4.3.3.1.1and4.3.4.1.1incolumn12ofTableAinChapter3.2.4.3.2.1.2.Therequiredtypeoftank,battery-vehicleandMEGCisgivenincodeformincolumn12ofTableAinChapter3.2.Theidentificationcodesappearingtherearemadeupoflettersornumbersinagivenorder.Theexplanationsforreadingthefourpartsofthecodearegivenin4.3.3.1.1(whenthesubstancetobecarriedbelongstoClass2)andin4.3.4.1.1(whenthesubstancetobecarriedbelongstoClasses3to9)(1)4.3.2.1.3.Therequiredtypeaccordingto4.3.2.1.2correspondstotheleaststringentconstructionrequirementswhichareacceptableforthedangeroussubstanceinquestionunlessotherwiseprescribedinthischapterorinChapter6.8.Itispossibletousetankscorrespondingtocodesprescribingahigherminimumcalculationpressure,ormorestringentrequirementsforfillingordischargeopeningsorforsafetyvalves/devices(see4.3.3.1.1forClass2and4.3.4.1.1forClasses3to9).4.3.2.1.4.Forcertainsubstances,tanks,battery-vehiclesorMEGCsaresubjecttoadditionalprovisionswhichareincludedasspecialprovisionsincolumn13ofTableAinChapter3.2.4.3.2.1.5.Tanks,battery-vehiclesandMEGCsshallnotbeloadedwithanydangeroussubstancesotherthanthoseforthecarriageofwhichtheyhavebeenapprovedaccordingto6.8.2.3.1andwhich,incontactwiththematerialsoftheshell,gaskets,equipmentandprotectivelinings,arenotliabletoreactdangerouslywiththem(see‘dangerousreaction’in1.2.1),toformdangerousproductsorappreciablytoweakenthesematerial(2).4.3.2.1.6.Foodstuffsshallnotbecarriedintanksusedfordangeroussubstancesunlessthenecessarystepshavebeentakentopreventanyharmtopublichealth.4.3.2.2.Degreeoffilling4.3.2.2.1.Thefollowingdegreesoffillingshallnotbeexceededintanksintendedforthecarriageofliquidsatambienttemperatures:(a)forflammablesubstanceswithoutadditionalrisks(e.g.toxicityorcorrosivity),intankswithaventingsystemorwithsafetyvalves(evenwhereprecededbyaburstingdisc):Degreeoffilling¼1001þα50(cid:1)tfðÞ%ofcapacity(1)AnexceptionismadefortanksintendedforthecarriageofsubstancesofClasses5.2or7(see4.3.4.1.3).(2)Itmaybenecessarytoconsultthemanufacturerofthesubstanceandthecompetentauthorityforguidanceonthecompatibilityofthesubstancewiththematerialsofthetank,battery-vehicleorMEGC.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/687(b)fortoxicorcorrosivesubstances(whetherflammableornot)intankswithaventingsystemorwithsafetyvalves(evenwhereprecededbyaburstingdisc):Degreeoffilling¼981þα50(cid:1)tfðÞ%ofcapacity(c)forflammablesubstancesandforslightlytoxicorcorrosivesubstances(whetherflammableornot)inhermeticallyclosedtankswithoutasafetydevice:Degreeoffilling¼971þα50(cid:1)tfðÞ%ofcapacity(d)forhighlytoxic,toxic,highlycorrosiveorcorrosivesubstances(whetherflammableornot)inhermeticallyclosedtankswithoutasafetydevice:Degreeoffilling¼951þα50(cid:1)tfðÞ%ofcapacity4.3.2.2.2.Intheseformulae,αisthemeancoefficientofcubicalexpansionoftheliquidbetween15°Cand50°C,i.e.foramaximumvariationintemperatureof35°C.αiscalculatedbytheformula:α¼d15(cid:1)d5035d50whered15andd50aretherelativedensitiesoftheliquidat15°Cand50°Crespectively.tFisthemeantemperatureoftheliquidduringfilling.4.3.2.2.3.Theprovisionsof4.3.2.2.1(a)to(d)shallnotapplytotankswhosecontentsare,bymeansofaheatingdevice,maintainedatatemperatureabove50°Cduringcarriage.Inthiscasethedegreeoffillingattheoutsetshallbesuch,andthetemperaturesoregulated,thatthetankisnotfulltomorethan95%ofitscapacityandthatthefillingtemperatureisnotexceeded,atanytimeduringcarriage.4.3.2.2.4.Whereshellsintendedforthecarriageofliquids(1)arenotdividedbypartitionsorsurgeplatesintosectionsofnotmorethan7500litrescapacity,theyshallbefilledtonotlessthan80%ornotmorethan20%oftheircapacity.4.3.2.3.Operation4.3.2.3.1.Thethicknessofthewallsoftheshellshallnot,throughoutitsuse,fallbelowtheminimumfigureprescribedin:6.8.2.1.17to6.8.2.1.216.8.2.1.17to6.8.1.204.3.2.3.2.Duringcarriagetank-containers/MEGCsshallbeloadedonthecarryingvehicleinsuchawayastobeadequatelyprotectedbythefittingsofthecarryingvehicleorofthetank-container/MEGCitselfagainstlateralandlongitudinalimpactandagainstover-turning(2).Ifthetank-containers/MEGCs,includingtheserviceequipment,aresoconstructedastowithstandimpactorover-turningtheyneednotbeprotectedinthisway.(1)Underthisprovision,substanceswhosekinematicviscosityat20°Cisbelow2680mm2/sshallbedeemedtobeliquids.(2)Examplesofprotectionofshells:—protectionagainstlateralimpactmay,forexample,consistoflongitudinalbarsprotectingtheshellonbothsidesatthelevelofthemedianline,—protectionagainstoverturningmay,forexample,consistofreinforcingringsorbarsfixedtransversallyinrelationtotheframe,—protectionagainstrearimpact,may,forexample,consistofabumperorframe.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/6884.3.2.3.3.Duringfillinganddischargeoftanks,battery-vehiclesandMEGCs,appropriatemeasuresshallbetakentopreventthereleaseofdangerousquantitiesofgasesandvapours.Tanks,battery-vehiclesandMEGCsshallbeclosedsothatthecontentscannotspilloutuncontrolled.Theopeningsofbottom-dischargetanksshallbeclosedbymeansofscrew-threadedplugs,blankflangesorotherequallyeffectivedevices.Theleakproofnessoftheclosuresofthetanks,andofthebattery-vehiclesandMEGCsshallbecheckedbythefillerafterthetankisfilled.Thisappliesinparticulartotheupperpartofthediptube.4.3.2.3.4.Whereseveralclosuresystemsarefittedinseries,thatnearesttothesubstancebeingcarriedshallbeclosedfirst.4.3.2.3.5.Nodangerousresidueofthefillingsubstanceshalladheretotheoutsideofthetankduringcarriage.4.3.2.3.6.Substanceswhichmayreactdangerouslywitheachothershallnotbecarriedinadjoiningcompartmentsoftanks.Substanceswhichmayreactdangerouslywitheachothermaybecarriedinadjoiningcompartmentsoftanks,whenthesecompartmentsareseparatedbyapartitionwithawallthicknessequaltoorgreaterthanthatofthetankitself.Theymayalsobecarriedseparatedbyanemptyspaceoranemptycompartmentbetweenloadedcompartments.4.3.2.4.Emptytanks,battery-vehiclesandMEGCs,uncleanedNote:Foremptytanks,battery-vehiclesandMEGCs,uncleaned,specialprovisionsTU1,TU2,TU4andTU16mayapply.4.3.2.4.1.Nodangerousresidueofthefillingsubstanceshalladheretotheoutsideofthetankduringcarriage.4.3.2.4.2.Tobeacceptedforcarriage,emptytanks,battery-vehiclesandMEGCs,uncleaned,shallbeclosedinthesamemannerandbeleakprooftothesamedegreeasiftheywerefull.4.3.2.4.3.Whereemptytanks,battery-vehiclesandMEGCs,uncleaned,arenotclosedinthesamemannerandarenotleakprooftothesamedegreeasiftheywerefullandwheretheprovisionsofthisDirectivecannotbecompliedwith,theyshallbecarried,withdueregardtoadequatesafety,tothenearestsuitableplacewherecleaningorrepaircanbecarriedout.CarriageisadequatelysafeifsuitablemeasureshavebeentakentoensureequivalentsafetycommensuratewiththeprovisionsofthisDirectiveandtopreventtheuncontrolledreleaseofthedangerousgoods.4.3.2.4.4.Emptyfixedtanks(tank-vehicles),demountabletanks,battery-vehicles,tank-containers,tankswapbodiesandMEGCs,uncleaned,mayalsobecarriedaftertheexpiryoftheperiodsestablishedin6.8.2.4.2and6.8.2.4.3forundergoingtheinspection.4.3.3.SpecialprovisionsapplicabletoClass24.3.3.1.Codingandhierarchyoftanks4.3.3.1.1.Codingoftanks,battery-vehiclesandMEGCsThefourpartsofthecodes(tankcodes)givenincolumn12ofTableAinChapter3.2havethefollowingmeanings:PartDescriptionTankCode1Typesoftank,battery-vehicleorMEGCC=tank,battery-vehicleorMEGCforcompressedgasesP=tank,battery-vehicleorMEGCforliquefiedgasesorgasesdissolvedunderpressureR=tankforrefrigeratedliquefiedgases2CalculationpressureX=valueoftheminimumrelevanttestpressureaccordingtothetablein4.3.3.2.5or22=minimumcalculationpressureinbar3Openings(see6.8.2.2and6.8.3.2)B=tankwithbottomfillingordischargeopeningswiththreeclosuresorbattery-vehicleorMEGCwithopeningsbelowthesurfaceoftheliquidorforcompressedgasesC=tankwithtopfillingordischargeopeningswiththreeclosureswithonlycleaningopeningsbelowthesurfaceoftheliquidD=tankwithtopfillingordischargeopeningswiththreeclosuresorbattery-vehicleorMEGCwithnoopeningsbelowthesurfaceoftheliquidOfficialJournaloftheEuropeanUnionEN26.1.2004L18/689PartDescriptionTankCode4Safetyvalves/devicesN=tank,battery-vehicleorMEGCwithsafetyvalveaccordingto6.8.3.2.9or6.8.3.2.10whichisnothermeticallyclosedH=hermeticallyclosedtank,battery-vehicleorMEGC(see1.2.1)Note:1.ThespecialprovisionTU17indicatedincolumn13ofTableAinChapter3.2forcertaingasesmeansthatthegasmayonlybecarriedinabattery-vehicleorMEGC.2.Thepressuresindicatedonthetankitselforonthepanelshallbenotlessthanthevalueof‘X’ortheminimumcalculationpressure.4.3.3.1.2.HierarchyoftanksTankcodeOthertankcode(s)permittedforthesubstancesunderthiscodeC*BNC#BN,C#CN,C#DN,C#BH,C#CH,C#DHC*BHC#BH,C#CH,C#DHC*CNC#CN,C#DN,C#CH,C#DHC*CHC#CH,C#DHC*DNC#DN,C#DHC*DHC#DHP*BNP#BN,P#CN,P#DN,P#BH,P#CH,P#DHP*BHP#BH,P#CH,P#DHP*CNP#CN,P#DN,P#CH,P#DHP*CHP#CH,P#DHP*DNP#DN,P#DHP*DHP#DHR*BNR#BN,R#CN,R#DNR*CNR#CN,R#DNR*DNR#DNThefigurerepresentedby‘#’shallbeequaltoorgreaterthanthefigurerepresentedby‘*’.Note:Thishierarchydoesnottakeanyspecialprovisionsintoaccount(see4.3.5and6.8.4)foreachentry.4.3.3.2.Fillingconditionsandtestpressures4.3.3.2.1.Thetestpressurefortanksintendedforthecarriageofcompressedgaseshavingacriticaltemperaturebelow-50°Cshallbeatleastoneandonehalftimesthefillingpressureat15°C.4.3.3.2.2.Thetestpressurefortanksintendedforthecarriageof:—compressedgaseshavingacriticaltemperatureof–50°Corabove,—liquefiedgaseshavingacriticaltemperaturebelow–70°C,and—gasesdissolvedunderpressureshallbesuchthat,whentheshellisfilledtothemaximummassofthecontentsperlitreofcapacity,thepressurereachedintheshellbythesubstanceat55°Cfortankswiththermalinsulationor65°Cforshellswithoutthermalinsulationdoesnotexceedthetestpressure.4.3.3.2.3.Thetestpressurefortanksintendedforthecarriageofliquefiedgaseshavingacriticaltemperatureof70°Corabovewillbe:(a)ifthetankisequippedwiththermalinsulation,atleastequaltothevapourpressure,reducedby0,1MPa(1bar)oftheliquidat60°C,butnotlessthan1MPa(10bar);(b)ifthetankisnotequippedwiththermalinsulation,atleastequaltothevapourpressure,reducedby0,1MPa(1bar),oftheliquidat65°C,butnotlessthan1MPa(10bar).Themaximumpermissiblemassofcontentsperlitreofcapacityiscalculatedasfollows:Maximumpermissiblemassofcontentsperlitreofcapacity=0,95xdensityoftheliquidphaseat50°C(inkg/l);Moreoverthevapourphaseshallnotdisappearbelow60°C.Iftheshellsarenotmorethan1,5mindiameter,thevaluesofthetestpressureandmaximumpermissiblemassofcontentsperlitreofcapacityconformingtopackinginstructionP200in4.1.4.1shallbeapplicable.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/6904.3.3.2.4.Thetestpressurefortanksintendedforthecarriageofrefrigeratedliquefiedgasesshallbenotlessthan1,3timesthemaximumpermittedworkingpressureindicatedonthetankbutnotlessthan300kPa(3bar)(gaugepressure);fortankswithvacuuminsulationthetestpressureshallbenotlessthan1,3timesthemaximumpermittedworkingpressureincreasedby100kPa(1bar).4.3.3.2.5.Tableofgasesandgasmixtureswhichmaybecarriedinfixedtanks(tank-vehicles),battery-vehicles,demountabletanks,tank-containersandMEGCsindicatingtheminimumtestpressurefortanksandasfarasapplicable,maximumpermissiblemassofcontentsperlitreofcapacityInthecaseofgasesandgasmixturesclassifiedundern.o.s.entries,thevaluesofthetestpressureandmaximumpermissiblemassofcontentsperlitreofcapacityshallbeprescribedbytheexpertapprovedbythecompetentauthority.Whenshellsforcompressedorliquefiedgaseshavingacriticaltemperatureof–50°Coraboveandbelow70°Chavebeensubjectedtoatestpressurelowerthanshowninthetable,andthetanksarefittedwiththermalinsulation,alowermaximumloadmaybeprescribedbytheexpertapprovedbythecompetentauthority,providedthatthepressurereachedinthetankbythesubstanceat55°Cdoesnotexceedthetestpressurestampedonthetank.UNNoNameClassificationcodeMinimumtestpressurefortanksMaximumpermissiblemassofcontentsperlitreofcapa-cityWiththermalinsulationWithoutthermalinsulationMPabarMPabarkg1001Acetylene,dissolved4Fonlyinbattery-vehiclesandMEGCscomposedofreceptacles1002Air,compressed1Asee4.3.3.2.11003Air,refrigeratedliquid3Osee4.3.3.2.41005Ammonia,anhydrous2TC2,6262,9290,531006Argon,compressed1Asee4.3.3.2.11008Borontrifluoride,compressed1TC22,522522,52250,71530300303000,861009Bromotrifluoromethane(RefrigerantgasR13B1)2A121201,504,2421,13121201,44252501,6010101,3-butadiene,stabilisedor1,2-butadiene,stabi-lisedormixturesof1,3-butadieneandhydrocar-bons,stabilised2F1101100,551101100,591101100,501011Butane2F1101100,5110121-butyleneortrans-2-butyleneorcis-2-butyleneorbutylenesmixture2F1101100,531101100,541101100,551101100,501013Carbondioxide2A191900,7322,52250,78191900,66252500,751014Carbondioxideandoxygenmixturescompressed1Osee4.3.3.2.11015Carbondioxideandnitrousoxidemixture2Asee4.3.3.2.2or4.3.3.2.31016Carbonmonoxide,compressed1TFsee4.3.3.2.1OfficialJournaloftheEuropeanUnionEN26.1.2004L18/691UNNoNameClassificationcodeMinimumtestpressurefortanksMaximumpermissiblemassofcontentsperlitreofcapa-cityWiththermalinsulationWithoutthermalinsulationMPabarMPabarkg1017Chlorine2TC1,7171,9191,251018Chlorodifluoromethane(RefrigerantgasR22)2A2,4242,6261,031020Chloropentafluoroethane(RefrigerantgasR115)2A2202,3231,0810211-chloro-1,2,2,2-tetra-fluoroethane(RefrigerantgasR124)2A1101,1111,21022Chlorotrifluoromethane(RefrigerantgasR13)2A121200,9622,52251,12101000,83121200,90191901,04252501,101023Coalgas,compressed1TFsee4.3.3.2.11026Cyanogen2TF10100101000,701027Cyclopropane2F1,61,61,81,80,531028Dichlorodifluoromethane(RefrigerantgasR12)2A1,5151,6161,151029Dichlorofluoromethane(RefrigerantgasR21)2A1101101,2310301,1-difluoroethane(Refrig-erantgasR152a)2F1,4141,6160,791032Dimethylamine,anhy-drous2F1101100,591033Dimethylether2F1,4141,6160,581035Ethane2F121200,329,5950,25121200,29303000,391036Ethylamine2F1101100,611037Ethylchloride2F1101100,81038Ethylene,refrigeratedliquid3Fsee4.3.3.2.41039Ethylmethylether2F1101100,641040Ethyleneoxidewithnitrogenuptoatotalpressureof1MPa(10bar)at50°C2TF1,5151,5150,781041Ethyleneoxideandcarbondioxidemixture,withmorethan9%butnotmorethan87%ethyleneoxide2F2,4242,6260,731046Helium,compressed1Asee4.3.3.2.11048Hydrogenbromide,anhy-drous2TC5505,5551,541049Hydrogen,compressed1Fsee4.3.3.2.1OfficialJournaloftheEuropeanUnionEN26.1.2004L18/692UNNoNameClassificationcodeMinimumtestpressurefortanksMaximumpermissiblemassofcontentsperlitreofcapa-cityWiththermalinsulationWithoutthermalinsulationMPabarMPabarkg1050Hydrogenchloride,anhy-drous2TC121200,69101000,30121200,56151500,67202000,741053Hydrogensulphide2TF4,5455500,671055Isobutylene2F1101100,521056Krypton,compressed1Asee4.3.3.2.11058Liquefiedgases,nonflammable,chargedwithnitrogen,carbondioxideorair2A1,5xfillingpressuresee4.3.3.2.2or4.3.3.2.31060Methylacetyleneandpropadienemixture,stabi-lised:2Fsee4.3.3.2.2or4.3.3.2.3mixtureP12,5252,8280,49mixtureP22,2222,3230,47propadienewith1%to4%methylacetylene2,2222,2220,501061Methylamine,anhydrous2F1101,1110,581062Methylbromide2T1101101,511063Methylchloride(Refrig-erantgasR40)2F1,3131,5150,811064Methylmercaptan2TF1101100,781065Neon,compressed1Asee4.3.3.2.11066Nitrogen,compressed1Asee4.3.3.2.11067Dinitrogentetroxide(nitrogendioxide)2TOConlyinbattery-vehiclesandMEGCscomposedofreceptacles1070Nitrousoxide2O22,52250,78181800,6822,52250,74252500,751071Oilgas,compressed1TFsee4.3.3.2.11072Oxygen,compressed1Osee4.3.3.2.11073Oxygen,refrigeratedliquid3Osee4.3.3.2.41076Phosgene2TConlyinbattery-vehiclesandMEGCscomposedofreceptacles1077Propylene2F2,5252,7270,431078Refrigerantgases,n.o.s.suchas:2AmixtureF11101,1111,23mixtureF21,5151,6161,15mixtureF32,4242,7271,03othermixturessee4.3.3.2.2or4.3.3.2.3OfficialJournaloftheEuropeanUnionEN26.1.2004L18/693UNNoNameClassificationcodeMinimumtestpressurefortanksMaximumpermissiblemassofcontentsperlitreofcapa-cityWiththermalinsulationWithoutthermalinsulationMPabarMPabarkg1079Sulphurdioxide2TC1101,2121,231080Sulphurhexafluoride2A121201,347701,04141401,33161601,371082Trifluorochloroethylene,stabilised2TF1,5151,7171,131083Trimethylamine,anhy-drous2F1101100,561085Vinylbromide,stabilised2F1101101,371086Vinylchloride,stabilised2F1101,1110,811087Vinylmethylether,stabi-lised2F1101100,671581Chloropicrinandmethylbromidemixture2T1101101,511582Chloropicrinandmethylchloridemixture2T1,3131,5150,811612Hexaethyltetraphosphateandcompressedgasmixture1Tsee4.3.3.2.11749Chlorinetrifluoride2TOC3303301,401858Hexafluoropropylene(RefrigerantgasR1216)2A1,7171,9191,111859Silicontetrafluoride,compressed1TC20200202000,7430300303001,101860Vinylfluoride,stabilised2F121200,5822,52250,65252500,641912Methylchlorideandmethylenechloridemixture2F1,3131,5150,811913Neon,refrigeratedliquid3Asee4.3.3.2.41951Argon,refrigeratedliquid3Asee4.3.3.2.41952Ethyleneoxideandcarbondioxidemixture,withnotmorethan9%ethyleneoxide2A19190191900,6625250252500,751953Compressedgas,toxic,flammable,n.o.s.(a)1TFsee4.3.3.2.1or4.3.3.2.21954Compressedgas,flam-mablen.o.s.1Fsee4.3.3.2.1or4.3.3.2.21955Compressedgas,toxic,n.o.s.(a)1Tsee4.3.3.2.1or4.3.3.2.21956Compressedgas,n.o.s.1Asee4.3.3.2.1or4.3.3.2.21957Deuterium,compressed1Fsee4.3.3.2.1OfficialJournaloftheEuropeanUnionEN26.1.2004L18/694UNNoNameClassificationcodeMinimumtestpressurefortanksMaximumpermissiblemassofcontentsperlitreofcapa-cityWiththermalinsulationWithoutthermalinsulationMPabarMPabarkg19581,2-dichloro-1,1,2,2-tetra-fluoroethane(RefrigerantgasR114)2A1101101,319591,1-difluoroethylene(RefrigerantgasR1132a)2F121200,6622,52250,78252500,771961Ethane,refrigeratedliquid3Fsee4.3.3.2.41962Ethylene,compressed1F121200,2522,52250,3622,52250,34303000,371963Helium,refrigeratedliquid3Asee4.3.3.2.41964Hydrocarbongasmixture,compressed,n.o.s.1Fsee4.3.3.2.1or4.3.3.2.21965Hydrocarbongasmixture,liquefied,n.o.s.2FMixtureA1101100,50MixtureA011,2121,4140,49MixtureA021,2121,4140,48MixtureA01,2121,4140,47MixtureA11,6161,8180,46MixtureB12202,3230,45MixtureB22202,3230,44MixtureB2202,3230,43MixtureC2,5252,7270,42Othermixturessee4.3.3.2.2or4.3.3.2.31966Hydrogen,refrigeratedliquid3Fsee4.3.3.2.41967Insecticidegas,toxic,n.o.s.(a)2Tsee4.3.3.2.2or4.3.3.2.31968Insecticidegas,n.o.s.2Asee4.3.3.2.2or4.3.3.2.31969Isobutane2F1101100,491970Krypton,refrigeratedliquid3Asee4.3.3.2.41971Methane,compressedornaturalgas,compressedwithhighmethanecontent1Fsee4.3.3.2.11972Methane,refrigeratedliquidornaturalgas,refrigeratedliquidwithhighmethanecontent3Fsee4.3.3.2.4OfficialJournaloftheEuropeanUnionEN26.1.2004L18/695UNNoNameClassificationcodeMinimumtestpressurefortanksMaximumpermissiblemassofcontentsperlitreofcapa-cityWiththermalinsulationWithoutthermalinsulationMPabarMPabarkg1973Chlorodifluoromethaneandchloropentafluor-oethanemixturewithfixedboilingpoint,withapproximately49%chlorodifluoromethane(RefrigerantgasR502)2A2,5252,8281,051974Chlorodifluorobromome-thane(RefrigerantgasR12B1)2A1101101,611976Octafluorocyclobutane(RefrigerantgasRC318)2A1101101,341977Nitrogen,refrigeratedliquid3Asee4.3.3.2.41978Propane2F2,1212,3230,421979Raregasesmixture,compressed1Asee4.3.3.2.11980Raregasesandoxygenmixture,compressed1Asee4.3.3.2.11981Raregasesandnitrogenmixture,compressed1Asee4.3.3.2.11982Tetrafluoromethane,compressed(RefrigerantgasR14,compresed)1A20200202000,6230300303000,9419831-chloro-2,2,2-trifluor-oethane(RefrigerantgasR133a)2A1101101,181984Trifluoromethane(Refrig-erantgasR23)2A191900,92252500,99191900,87252500,952034Hydrogenandmethanemixture,compressed1Fsee4.3.3.2.120351,1,1-trifluoroethane(RefrigerantgasR143a)2F2,8283,2320,792036Xenon,compressed1A121201,30131301,2420442,2-dimethylpropane2F1101100,532073Ammoniasolutions,rela-tivedensitylessthan0,880at15°Cinwater,4Awithmorethan35%andnotmorethan40%ammonia1101100,80withmorethan40%andnotmorethan50%ammonia1,2121,2120,772187Carbondioxide,refriger-atedliquid3Asee4.3.3.2.4OfficialJournaloftheEuropeanUnionEN26.1.2004L18/696UNNoNameClassificationcodeMinimumtestpressurefortanksMaximumpermissiblemassofcontentsperlitreofcapa-cityWiththermalinsulationWithoutthermalinsulationMPabarMPabarkg2189Dichlorosilane2TFC1101100,902191Sulfurylfluoride2T5505501,12193Hexafluoroethane,compressed(RefrigerantgasR116compressed)1A161601,28202001,34202001,102197Hydrogeniodide,anhy-drous2TC1,9192,1212,252200Propadiene,stabilised2F1,8182,0200,502201Nitrousoxide,refrigeratedliquid3Osee4.3.3.2.42203Silane,compressed(b)1F22,522522,52250,3225250252500,412204Carbonylsulphide2TF2,7273,0300,842417Carbonylfluoride,compressed1TC20200202000,4730300303000,702419Bromotrifluoroethylene2F1101101,192420Hexafluoroacetone2TC1,6161,8181,082422Octafluorobut-2-ene(RefrigerantgasR1318)2A1101101,342424Octafluoropropane(RefrigerantgasR218)2A2,1212,3231,072451Nitrogentrifluoride,compressed1O20200202000,5030300303000,752452Ethylacetylene,stabilised2F1101100,572453Ethylfluoride(RefrigerantgasR161)2F2,1212,5250,572454Methylfluoride(Refrig-erantgasR41)2F30300303000,3625171-chloro-1,1-difluor-oethane(RefrigerantgasR142b)2F1101100,992591Xenon,refrigeratedliquid3Asee4.3.3.2.42599Chlorotrifluoromethaneandtrifluoromethane,azeotropicmixturewithapproximately60%chlorotrifluoromethane(RefrigerantgasR503)2A3,1313,1310,114,2420,21101000,764,2420,20101000,662600Carbonmonoxideandhydrogenmixture,compressed1TFsee4.3.3.2.12601Cyclobutane2F1101100,632602Dichlorodifluoromethaneanddifluoro-1,1ethane,azeotropicmixturewithapproximately74%dichlorodifluoromethane(RefrigerantgasR500)2A1,8182201,01OfficialJournaloftheEuropeanUnionEN26.1.2004L18/697UNNoNameClassificationcodeMinimumtestpressurefortanksMaximumpermissiblemassofcontentsperlitreofcapa-cityWiththermalinsulationWithoutthermalinsulationMPabarMPabarkg2901Brominechloride2TOC1101101,503057Trifluoroacetylchloride2TC1,3131,5151,173070Ethyleneoxideanddichlorodifluoromethanemixturewithnotmorethan12,5%ethyleneoxide2A1,5151,6161,093083Perchlorylfluoride2TO2,7273,0301,213136Trifluoromethane,refiger-atedliquid3ASee4.3.3.2.43138Ethylene,acetylenepropy-leneinmixture,refriger-atedliquid,containingatleast71,5%ethylenewithnotmorethan22,5%acetyleneandnotmorethan6%propylene3Fsee4.3.3.2.43153Perfluoro(methylvinylether)2F1,4141,5151,143154Perfluoro(ethylvinylether)2F1101100,983156Compressedgas,oxidising,n.o.s.1Osee4.3.3.2.1or4.3.3.2.23157Liquefiedgas,oxidising,n.o.s.2Osee4.3.3.2.2or4.3.3.2.33158Gas,refrigeratedliquid,n.o.s.3Asee4.3.3.2.431591,1,1,2-tetrafluoroethane(RefrigerantgasR134a)2A1,6161,8181,043160Liquefiedgas,toxic,flam-mable,n.o.s.(a)2TFsee4.3.3.2.2or4.3.3.2.33161Liquefiedgas,flammable,n.o.s.2Fsee4.3.3.2.2or4.3.3.2.33162Liquefiedgas,toxic,n.o.s.(a)2Tsee4.3.3.2.2or4.3.3.2.33163Liquefiedgas,n.o.s.2Asee4.3.3.2.2or4.3.3.2.33220Pentafluoroethane(Refrig-erantgasR125)2A4,1414,9490,953252Difluoromethane(Refrig-erantgasR32)2F3,9394,3430,783296Heptafluoropropane(RefrigerantgasR227)2A1,4141,6161,203297Ethyleneoxideandchlor-otetrafluoroethanemixture,withnotmorethan8,8%ethyleneoxide2A1101101,16OfficialJournaloftheEuropeanUnionEN26.1.2004L18/698UNNoNameClassificationcodeMinimumtestpressurefortanksMaximumpermissiblemassofcontentsperlitreofcapa-cityWiththermalinsulationWithoutthermalinsulationMPabarMPabarkg3298Ethyleneoxideandpenta-fluoroethanemixture,withnotmorethan7,9%ethyleneoxide2A2,4242,6261,023299Ethyleneoxideandtetra-fluoroethanemixture,withnotmorethan5,6%ethyleneoxide2A1,5151,7171,033300Ethyleneoxideandcarbondioxidemixture,withmorethan87%ethyleneoxide2TF2,8282,8280,733303Compressedgas,toxic,oxidising,n.o.s.(a)1TOsee4.3.3.2.1or4.3.3.2.23304Compressedgas,toxic,corrosive,n.o.s.(a)1TCsee4.3.3.2.1or4.3.3.2.23305Compressedgas,toxic,flammable,corrosive,n.o.s.(a)1TFCsee4.3.3.2.1or4.3.3.2.23306Compressedgas,toxic,oxidising,corrosive,n.o.s.(a)1TOCsee4.3.3.2.1or4.3.3.2.23307Liquefiedgas,toxic,oxidising,n.o.s.(a)2TOsee4.3.3.2.2or4.3.3.2.33308Liquefiedgas,toxic,corrosive,n.o.s.(a)2TCsee4.3.3.2.2or4.3.3.2.33309Liquefiedgas,toxic,flam-mable,corrosive,n.o.s.(a)2TFCsee4.3.3.2.2or4.3.3.2.33310Liquefiedgas,toxic,oxidising,corrosive,n.o.s.(a)2TOCsee4.3.3.2.2or4.3.3.2.33311Gas,refrigeratedliquid,oxidising,n.o.s.3Osee4.3.3.2.43312Gas,refrigeratedliquid,flammable,n.o.s.3Fsee4.3.3.2.43318Ammoniasolutions,rela-tivedensitylessthan0,880at15°Cinwater,withmorethan50%ammonia4TCsee4.3.3.2.23337RefrigerantgasR404A2A2,9293,2320,843338RefrigerantgasR407A2A2,8283,2320,953339RefrigerantgasR407B2A3,0303,3330,953340RefrigerantgasR407C2A2,7273,0300,95OfficialJournaloftheEuropeanUnionEN26.1.2004L18/699UNNoNameClassificationcodeMinimumtestpressurefortanksMaximumpermissiblemassofcontentsperlitreofcapa-cityWiththermalinsulationWithoutthermalinsulationMPabarMPabarkg3354Insecticidegas,flammable,n.o.s.2Fsee4.3.3.2.2or4.3.3.2.33355Insecticidegas,toxic,flammable,n.o.s.(a)2TFsee4.3.3.2.2or4.3.3.2.3(a)AllowedifLC50equaltoorgreaterthan200ppm.(b)Consideredaspyrophoric.4.3.3.3.Operation4.3.3.3.1.Whentanks,battery-vehiclesorMEGCsareapprovedfordifferentgases,thechangeofuseshallincludeemptying,purgingandevacuationoperationstotheextentnecessaryforsafeoperation.4.3.3.3.2.Whentanks,battery-vehiclesorMEGCsarehandedoverforcarriage,onlytheparticularsspecifiedin6.8.3.5.6applicabletothegasloadedorjustdischargedshallbevisible;allparticularsconcerningothergasesshallbecoveredup.4.3.3.3.3.Alltheelementsofabattery-vehicleorMEGCshallcontainonlyoneandthesamegas.4.3.3.4.(Reserved)4.3.4.SpecialprovisionsapplicabletoClasses3to94.3.4.1.Coding,rationalisedapproachandhierarchyoftanks4.3.4.1.1.CodingoftanksThefourpartsofthecodes(tankcodes)givenincolumn12ofTableAinChapter3.2havethefollowingmeanings:PartDescriptionTankcode1TypesoftankL=tankforsubstancesintheliquidstate(liquidsorsolidshandedoverforcarriageinthemoltenstate)S=tankforsubstancesinthesolidstate(powderyorgranular)2CalculationpressureG=minimumcalculationpressureaccordingtothegeneralrequirementsof6.8.2.1.14or1,5;2,65;4;10;15or21=minimumcalculationpressureinbar(see6.8.2.1.14)3Openings(see6.8.2.2.3)A=tankwithbottom-fillinganddischargeopeningswith2closuresB=tankwithbottom-fillinganddischargeopeningswith3closuresC=tankwithtop-fillinganddischargeopeningswithonlycleaningopeningsbelowthesurfaceoftheliquidD=tankwithtop-fillinganddischargeopeningswithnoopeningsbelowthesurfaceoftheliquidOfficialJournaloftheEuropeanUnionEN26.1.2004L18/700PartDescriptionTankcode4Safetyvalves/devicesV=tankwithaventingsystembutnoflametrap;ornon-explosion-pressureprooftankF=tankwithaventingsystemfittedwithaflametrapaccordingto6.8.2.2.6orexplosion-pressureprooftankN=tankwithasafetyvalveaccordingto6.8.2.2.7or6.8.2.2.8andnothermeticallyclosed;thesetanksmaybefittedwithpressurereliefvalvesH=hermeticallyclosedtank(see1.2.1)4.3.4.1.2.RationalisedapproachforassignmentofADRtankcodestogroupsofsubstancesandhierarchyoftanks.Note:Certainsubstancesandgroupsofsubstancesarenotincludedintherationalisedapproach,see4.3.4.1.3RationalisedapproachHierarchyoftanksTankcodeGroupofpermittedsubstancesOthertankcodespermittedforsubstancesunderthiscodeClassClassificationcodePackinggroupLIQUIDSLGAV39F2M9IIIIIILGAH;LGBV;LGBF;LGBH;L1.5AH;L1.5BN;L1.5BH;L4BN;L4BH;L4DH;L10BH;L10CH;L10DH;L15CH;L21DHLGBV4.15.199F2O1M6M11noneIIIIIIIIILGBF;LGBH;L1.5BN;L1.5BH;L4BV;L4BN;L4BH;L4DH;L10BH;L10CH;L10DH;L15CH;L21DHandgroupsofpermittedsubstancesfortankcodeLGAVLGBF33F1F1IIvapourpres-sureat50°C≤1,1barIIILGBH;L1.5BN;L1.5BH;L4BN;L4BH;L4DH;L10BH;L10CH;L10DH;L15CH;L21DHandgroupsofpermittedsubstancesfortankcodesLGAVandLGBVL1.5BN3F1I,II1,1bar<vapourpressureat50°C≤1,75barL1.5BH;L4BN;L4BH;L4DH;L10BH;L10CH;L10DH;L15CH;L21DH.andgroupsofpermittedsubstancesfortankcodesLGAV,LGBVandLGBFOfficialJournaloftheEuropeanUnionEN26.1.2004L18/701RationalisedapproachHierarchyoftanksTankcodeGroupofpermittedsubstancesOthertankcodespermittedforsubstancesunderthiscodeClassClassificationcodePackinggroupL4BV5.1O1L4BN335.188F1FCO1C1C3C4C5C7C8C9C10CF1CF2CS1CS2CW1CW2CO1CO2CT1CT2CFTM11IVapourpres-sureat50°C>1,75barIIII,IIII,IIIII,IIIII,IIIII,IIIII,IIIII,IIIII,IIIII,IIIIIIIIIIIIIIIIIIIII,IIIII,IIIIIIIIL4BH;L4DH;L10BH;L10CH;L10DH;L15CH;L21DH.andgroupsofpermittedsubstancesfortankcodesLGAV,LGBV,LGBFandL1.5BNL4BH36.16.29FT1FT2FCFTCT1T2T3T4T6T7TF1TF2TF3TSTW1TO1TC1TC2TC3TFCRiskgroup2I3M2II,IIIIIIIIIII,IIIII,IIIII,IIIII,IIIII,IIIII,IIIIIII,IIIIIIIIIIIIIIIIIIIIIIIL4DH;L10BH;L10CH;L10DH;L15CH;L21DH.andgroupsofpermittedsubstancesfortankcodesLGAV,LGBV,LGBF,L1.5BNandL4BNOfficialJournaloftheEuropeanUnionEN26.1.2004L18/702RationalisedapproachHierarchyoftanksTankcodeGroupofpermittedsubstancesOthertankcodespermittedforsubstancesunderthiscodeClassClassificationcodePackinggroupL4DH4.24.38S1S3ST1ST3SC1SC3W1WF1WT1WC1CT1II,IIIII,IIIII,IIIII,IIIII,IIIII,IIIII,IIIII,IIIII,IIIII,IIIII,IIIL10DH;L21DHandgroupsofpermittedsubstancesfortankcodesLGAV,LGBV,LGBF,L1.5BN,L4BNandL4BHL10BH8C1C3C4C5C7C8C9C10CF1CF2CS1CW1CO1CO2CT1CT2COTIIIIIIIIIIIIIIIIIL10CH;L10DH;L15CHandL21DHandgroupsofpermittedsubstancesfortankcodesLGAV,LGBV,LGBF,L1.5BN,L4BN,andL4BHL10CH36.1FT1FT2FCFTCT1T2T3T4T6T7TF1TF2TF3TSTW1TO1TC1TC2TC3TC4TFCIIIIIIIIIIIIIIIIIIIIIL10DH;L15CH;L21DHandgroupsofpermittedsubstancesfortankcodesLGAV,LGBV,LGBF,L1.5BN,L4BN,L4BH,andL10BHOfficialJournaloftheEuropeanUnionEN26.1.2004L18/703RationalisedapproachHierarchyoftanksTankcodeGroupofpermittedsubstancesOthertankcodespermittedforsubstancesunderthiscodeClassClassificationcodePackinggroupL10DH4.35.18W1WF1WT1WC1WFCOTCCT1IIIIIIIL21DHandgroupsofpermittedsubstancesfortankcodesLGAV,LGBV,LGBF,L1.5BN,L4BN,L4BH,L4DH,L10BHandL10CHL15CH36.1FT1TF1IIL21DHandgroupsofpermittedsubstancesfortankcodesLGAV,LGBV,LGBF,L1.5BN,L4BN,L4BH,L10BHandL10CHL21DH4.2S1S3SWST3IIIIandgroupsofpermittedsubstancesfortankcodesLGAV,LGBV,LGBF,L1.5BN,L4BN,L4BH,L4DH,L10BH,L10CH,L10DHandL15CHSOLIDSSGAV4.14.25.189F1F3S2O2C2C4C6C8C10CT2M7M11IIIIIIIIIII,IIIII,IIIIIIIIIIIIII,IIIIIIIIIII,IIISGAN;SGAH;S4AH;S10AN;S10AH.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/704RationalisedapproachHierarchyoftanksTankcodeGroupofpermittedsubstancesOthertankcodespermittedforsubstancesunderthiscodeClassClassificationcodePackinggroupSGAN4.14.24.35.189F1F3FT1FT2FC1FC2S2S2S4ST2ST4SC2SC4W2WSWT2WC2O2OT2OC2C2C4C6C8C10CF2CS2CW2CO2CT2M3IIIIII,IIIII,IIIII,IIIII,IIIII,IIIII,IIIII,IIIII,IIIII,IIIII,IIIII,IIIII,IIIII,IIIII,IIIII,IIIII,IIIII,IIIIIIIIIIIIIIIIIIIIIIIIIISGAH;S4AH;S10AN;S10AH.andgroupsofpermittedsubstancesfortankcodesSGAVSGAH6.19T2T3T5T7T9TF3TSTW2TO2TC2TC4M1II,IIIII,IIIII,IIIII,IIIIIIIIIIIIIIIIIII,IIIS4AH;S10AHandgroupsofpermittedsubstancesfortankscodesSGAVandSGANS4AH6.29I3M2IIIIS10AHandgroupsofpermittedsubstancesfortankscodesSGAV,SGANandSGAHOfficialJournaloftheEuropeanUnionEN26.1.2004L18/705RationalisedapproachHierarchyoftanksTankcodeGroupofpermittedsubstancesOthertankcodespermittedforsubstancesunderthiscodeClassClassificationcodePackinggroupS10AN8C2C4C6C8C10CF2CS2CW2CO2CT2IIIIIIIIIIS10AHandgroupsofpermittedsubstancesfortankcodesSGAVandSGANS10AH6.1T2T3T5T7TSTW2TO2TC2TC4IIIIIIIIIandgroupsofpermittedsubstancesfortankcodesSGAV,SGAN,SGAHandS10ANNote:Thishierarchydoesnottakeaccountofanyspecialprovisionsforeachentry(see4.3.5and6.8.4)4.3.4.1.3.Thefollowingsubstancesandgroupsofsubstances,wherea‘(+)’appearsincolumn12ofTableAinChapter3.2,aresubjecttospecialprovisions.Inthatcasethealternativeuseofthetanksforothersubstancesandgroupsofsubstancesisnotpermittedandthehierarchyof4.3.4.1.2isnotapplicable(seealso6.8.4).Therequirementsforthesetanksaregivenbythefollowingtankcodessupplementedbytherelevantspecialprovisionsindicatedincolumn13ofTableAinChapter3.2(a)Class4.1:UNNo2448sulphur,molten:codeLGBV;(b)Class4.2:UNNo1381phosphorus,whiteoryellow,dry,orunderwaterorinsolutionandUNNo2447phosphorus,whiteoryellowmolten:codeL10DH;(c)Class4.3:UNNo1389alkalimetalamalgam,UNNo1391alkalimetaldispersionoralkalineearthmetaldispersion,UNNo1392alkalineearthmetalamalgam,UNNo1415lithium,UNNo1420potassiummetalalloys,UNNo1421alkalimetalalloy,liquid,n.o.s,UNNo1422potassiumsodiumalloys,UNNo1428sodiumandUNNo2257potassium:codeL10BN;UNNo1407caesiumandUNNo1423rubidium:codeL10CH;(d)Class5.1:UNNo1873perchloricacid5072%:codeL4DN;UNNo2015hydrogenperoxidewithmorethan70%hydrogenperoxide:codeL4DV;UNNo2015hydrogenperoxidewith60-70%hydrogenperoxide:codeL4BV;UNNo2014hydrogenperoxide,aqueoussolutionwith20-60%hydrogenperoxide,andUNNo3149hydrogenperoxideandperoxyaceticacidmixture,stabilised:codeL4BV;OfficialJournaloftheEuropeanUnionEN26.1.2004L18/706(e)Class5.2:UNNo3109organicperoxidetypeF,liquidandUNNo3119organicperoxide,typeF,liquidtemperaturecontrolled:codeL4BN;UNNo3110organicperoxide,typeF,solidandUNNo3120organicperoxide,typeF,solid,temperaturecontrolled:codeS4AN;(f)Class6.1:UNNo1613hydrogencyanide,aqueoussolutionandUNNo3294hydrogencyanidesolutioninalcohol:codeL15DH;(g)Class7:Allsubstances:specialtanks;Minimumrequirementsforliquids:codeL2,65CN;forsolids:codeS2,65ANNotwithstandingthegeneralrequirementsofthisparagraph,tanksusedforradioactivematerialmayalsobeusedforthecarriageofothergoodsprovidedtherequirementsof5.1.3.2arecompliedwith.(h)Class8:UNNo1052hydrogenfluoride,anhydrousandUNNo1790hydrofluoricacid,solution,withmorethan85%hydrofluoricacid:codeL21DH;UNNo1744bromineorbrominesolution:codeL21DH;UNNo1791hypochloritesolutionandUNNo1908chloritesolution:codeL4BV.4.3.4.2.Generalprovisions4.3.4.2.1.Wherehotsubstancesareloaded,thetemperatureoftheoutersurfaceofthetankorofthethermalinsulationshallnotexceed70°Cduringcarriage.4.3.4.2.2.Theconnectingpipesbetweenindependentbutinterconnectedtanksofatransportunitshallbeemptyduringcarriage.Flexiblefillinganddischargepipeswhicharenotpermanentlyconnectedtotheshellsshallbeemptyduringcarriage.4.3.4.2.3.(Reserved)4.3.5.SpecialprovisionsWhentheyareshownunderanentryincolumn13ofTableofAinChapter3.2,thefollowingspecialprovisionsapply:TU1Thetanksshallnotbehandedoverforcarriageuntilthesubstancehassolidifiedcompletelyandbeencoveredbyaninertgas.Uncleanedemptytankswhichhavecontainedthesesubstancesshallbefilledwithaninertgas.TU2Thesubstanceshallbecoveredbyaninertgas.Uncleanedemptytankswhichhavecontainedthesesubstancesshallbefilledwithaninertgas.TU3Theinsideoftheshellandallpartsliabletocomeintocontactwiththesubstanceshallbekeptclean.Nolubricantcapableofcombiningdangerouslywiththesubstanceshallbeusedforpumps,valvesorotherdevices.TU4Duringcarriage,thesesubstancesshallbeunderalayerofinertgas,thegaugepressureofwhichshallnotbelessthan50kPa(0,5bar).Uncleanedemptytankswhichhavecontainedthesesubstancesshallwhenhandedoverforcarriagebefilledwithaninertgasatagaugepressureofatleast50kPa(0,5bar).TU5(Reserved)TU6Notauthorisedforcarriageintanks,battery-vehiclesandMEGCswhenhavingaLC50lowerthan200ppm.TU7Thematerialsusedtoensureleakproofnessofthejointsorforthemaintenanceoftheclosuresshallbecompatiblewiththecontents.TU8Analuminium-alloytankshallnotbeusedforcarriageunlessthetankisreservedsolelyforsuchcarriageandtheacetaldehydeisfreefromacid.TU9UNNo1203petrol(gasoline)withavapourpressureat50°Cofmorethan110kPa(1,1bar)butnotabove150kPa(1,5bar)mayalsobecarriedintanksdesignedaccordingto6.8.2.1.14(a)andhavingequipmentconformingto6.8.2.2.6.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/707TU10(Reserved)TU11Duringfilling,thetemperatureofthissubstanceshallnotexceed60°C.Amaximumfillingtemperatureof80°Cisallowedprovidedthatsmoulderspotsarepreventedduringfillingandthetanksarehermeticallyclosed.Afterfilling,thetanksshallbepressurised(e.g.withcompressedair)tochecktightness.Itshallbeensuredthatnodepressurisationtakesplaceduringcarriage.Beforedischarge,itshallbecheckedifpressureinthetanksisstillaboveatmospheric.Ifthisisnotthecase,aninertgasshallbeintroducedintothetankspriortodischarge.TU12Intheeventofachangeofuse,shellsandequipmentshallbethoroughlycleansedofallresiduesbeforeandafterthecarriageofthissubstance.TU13Tanksshallbefreefromimpuritiesatthetimeoffilling.Serviceequipmentsuchasvalvesandexternalpipingshallbeemptiedafterfillingordischarging.TU14Theclosuresofthetanksshallbeprotectedwithlockedcapsduringcarriage.TU15Tanksshallnotbeusedforthecarriageoffoodstuffs,articlesofconsumptionoranimalfeeds.TU16Uncleanedemptytanks,shall,whenhandedoverforcarriage,either:—befilledwithnitrogen,or—befilledwithwatertonotlessthan96%andnotmorethan98%oftheircapacity;between1Octoberand31March,thiswatershallcontainsufficientanti-freezeagenttomakeitimpossibleforthewatertofreezeduringcarriage;theanti-freezeagentshallbefreefromcorrosiveactionandnotliabletoreactwithphosphorus.TU17Onlytobecarriedinbattery-vehiclesorMEGCstheelementsofwhicharecomposedofreceptacles.TU18Thedegreeoffillingshallremainbelowthelevelatwhich,ifthecontentswereraisedtoatemperatureatwhichthevapourpressureequalledtheopeningpressureofthesafetyvalve,thevolumeoftheliquidwouldreach95%ofthetank'scapacityatthattemperature.Theprovisionin4.3.2.3.4shallnotapply.TU19Tanksmaybefilledto98%atthefillingtemperatureandpressure.Theprovisionin4.3.2.3.4shallnotapply.TU20(Reserved)TU21Thesubstanceshall,ifwaterisusedasaprotectiveagent,becoveredwithadepthofnotlessthan12cmofwateratthetimeoffilling;thedegreeoffillingatatemperatureof60°Cshallnotexceed98%.Ifnitrogenisusedasaprotectiveagent,thedegreeoffillingatatemperatureof60°Cshallnotexceed96%.Theremainingspaceshallbefilledwithnitrogeninsuchawaythat,evenaftercooling,thepressureatnotimefallsbelowatmosphericpressure.Thetankshallbeclosedinsuchawaythatnoleakageofgasoccurs.TU22Tanksshallbefilledtonotmorethan90%oftheircapacity;aspaceof5%shallremainemptyforwhentheliquidisatanaveragetemperatureof50°C.TU23Thedegreeoffillingshallnotexceed0,93kgperlitreofcapacity,iffillingisbymass.Iffillingisbyvolume,thedegreeoffillingshallnotexceed85%.TU24Thedegreeoffillingshallnotexceed0,95kgperlitreofcapacity,iffillingisbymass.Iffillingisbyvolume,thedegreeoffillingshallnotexceed85%.TU25Thedegreeoffillingshallnotexceed1,14kgperlitreofcapacity,iffillingisbymass.Iffillingisbyvolume,thedegreeoffillingshallnotexceed85%.TU26Thedegreeoffillingshallnotexceed85%.TU27Tanksshallnotbefilledtomorethan98%oftheircapacity.TU28Tanksshallbefilledtonotmorethan95%oftheircapacityatareferencetemperatureof15°C.TU29Tanksshallbefilledtonotmorethan97%oftheircapacityandthemaximumtemperatureafterfillingshallnotexceed140°C.TU30Tanksshallbefilledassetoutinthetestreportforthetypeapprovalofthetankbutshallbefilledtonotmorethan90%oftheircapacity.TU31Tanksshallnotbefilledtomorethan1kgperlitreofcapacity.TU32Tanksshallnotbefilledtomorethan88%oftheircapacity.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/708TU33Tanksshallbefilledtonotlessthan88%andnotmorethan92%oftheircapacityorto2,86kgperlitreofcapacity.TU34Tanksshallnotbefilledtomorethan0,84kgperlitreofcapacity.TU35Emptytank-vehicles,emptydemountabletanksandemptytank-containers,uncleaned,whichhavecontainedthesesubstancesarenotsubjecttotherequirementsofthisDirectiveifadequatemeasureshavebeentakentonullifyanyhazard.TU36Thedegreeoffillingaccordingto4.3.2.2,atthereferencetemperatureof15°C,shallnotexceed93%ofthecapacity.CHAPTER4.4Useoffibre-reinforcedplastics(FRP)tanksNote:Forportabletanks,seeChapter4.2;forfixedtanks(tank-vehicles),demountabletanksandtank-containersandtankswapbodies,withshellsmadeofmetallicmaterials,andbattery-vehiclesandmultipleelementsgascontainers(MEGCs),seeChapter4.3;forvacuumoperatedwastecontainers,seeChapter4.5.4.4.1.GeneralThecarriageofdangeroussubstancesinfibre-reinforcedplastics(FRP)tanksispermittedonlywhenthefollowingconditionsaremet:(a)thesubstanceisclassifiedinClass3,5.1,6.1,6.2,8or9;(b)themaximumvapourpressure(absolutepressure)at50°Cofthesubstancedoesnotexceed110kPa(1,1bar);(c)thecarriageofthesubstanceinmetallictanksisauthorisedaccordingto4.3.2.1.1;(d)thecalculationpressurespecifiedforthatsubstanceinpart2ofthetankcodegivenincolumn12ofTableAinChapter3.2doesnotexceed4bar(seealso4.3.4.1.1)and,(e)thetankcomplieswiththeprovisionsofChapter6.9applicableforthecarriageofthesubstance.4.4.2.Operation4.4.2.1.Theprovisionsof4.3.2.1.5to4.3.2.2.4,4.3.2.3.3to4.3.2.3.6,4.3.2.4.1,4.3.2.4.2and4.3.4.2shallapply.4.4.2.2.Thetemperatureofthesubstancecarriedshallnotexceed,atthetimeoffilling,themaximumservicetemperatureindicatedonthetankplatereferredtoin6.9.6.4.4.2.3.Whenapplicabletocarriageinmetallictanks,thespecialprovisions(TU)of4.3.5shallalsoapply,asindicatedincolumn13ofTableAinChapter3.2.CHAPTER4.5UseofvacuumoperatedwastetanksNote:Forportabletanks,seeChapter4.2;forfixedtanks(tank-vehicles),demountabletanksandtank-containersandtankswapbodies,withshellsmadeofmetallicmaterials,andbattery-vehiclesandmultipleelementsgascontainers(MEGCs),seeChapter4.3;forfibrereinforcedplasticstanks,seeChapter4.4.4.5.1.Use4.5.1.1.SubstancesinClasses3,4.1,5.1,6.1,6.2,8and9maybecarriedinvacuum-operatedwastetanksconformingtoChapter6.10iftheircarriageinfixedordemountabletanksispermittedaccordingtoChapter4.3.4.5.2.Operation4.5.2.1.TheprovisionsofChapter4.3applytothecarriageinvacuumoperatedwastetanksandaresupplementedbytheprovisionsof4.5.2.2to4.5.2.4below.4.5.2.2.Forcarriageofliquidsclassifiedasflammable,vacuum-operatedwastetanksshallbefilledthroughfillingswhichdischargeintothetankatalowlevel.Provisionsshallbemadetominimisetheproductionofspray.4.5.2.3.Whendischargingflammableliquidswithaflash-pointbelow23°Cbyusingairpressure,themaximumallowedpressureis100kPa(1bar).4.5.2.4.Theuseoftanksfittedwithaninternalpistonoperatingasacompartmentwallisallowedonlywhenthesubstancesoneithersideofthewall(piston)donotreactdangerouslywitheachother(see4.3.2.3.6).Part5CONSIGNMENTPROCEDURESCHAPTER5.1Generalprovisions5.1.1.ApplicationandgeneralprovisionsThispartsetsforththeprovisionsfordangerousgoodsconsignmentsrelativetomarking,labelling,anddocumentation,and,whereappropriate,authorisationofconsignmentsandadvancenotifications.5.1.2.Useofoverpacks5.1.2.1.Anoverpackshallbemarkedandlabelled,asrequiredforpackagesbyChapter5.2,foreachitemofdangerousgoodscontainedintheoverpack,unlessmarkingsandlabelsrepresentativeofalldangerousgoodscontainedintheoverpackarevisible.Ifaspecificlabelisrequiredfordifferentpackages,itonlyneedstobeappliedonce.5.1.2.2.EachpackageofdangerousgoodscontainedinanoverpackshallcomplywithallapplicableprovisionsofthisDirective.Theintendedfunctionofeachpackageshallnotbeimpairedbytheoverpack.5.1.2.3.Theprohibitionsonmixedloadingalsoapplytotheseoverpacks.5.1.3.Emptyuncleanedpackagings(includingIBCsandlargepackagings),tanks,vehiclesandcontainersforcarriageinbulk5.1.3.1.Emptyuncleanedpackagings(includingIBCsandlargepackagings),tanks(includingtank-vehicles,battery-vehicles,demountabletanks,portabletanks,tank-containers,MEGCs),vehiclesandcontainersforcarriageinbulkhavingcontaineddangerousgoodsofthedifferentclassesotherthanClass7,shallbemarkedandlabelledasiftheywerefull.NoteFordocumentation,seeChapter5.4.5.1.3.2.TanksandIBCsusedforthecarriageofradioactivematerialshallnotbeusedforthestorageorcarriageofothergoodsunlessdecontaminatedbelowthelevelof0,4Bq/cm2forbetaandgammaemittersandlowtoxicityalphaemittersand0,04Bq/cm2forallotheralphaemitters.5.1.4.MixedpackingWhentwoormoredangerousgoodsarepackedwithinthesameouterpackaging,thepackageshallbelabelledandmarkedasrequiredforeachsubstanceorarticle.Ifthesamelabelisrequiredfordifferentgoods,itonlyneedstobeappliedonce.5.1.5.GeneralprovisionsforClass75.1.5.1.Requirementsbeforeshipments5.1.5.1.1.RequirementsbeforethefirstshipmentofapackageBeforethefirstshipmentofanypackage,thefollowingrequirementsshallbefulfilled:(a)ifthedesignpressureofthecontainmentsystemexceeds35kPa(gauge),itshallbeensuredthatthecontainmentsystemofeachpackageconformstotheapproveddesignrequirementsrelatingtothecapabilityofthatsystemtomaintainitsintegrityunderthatpressure;(b)foreachTypeB(U),TypeB(M)andTypeCpackageandforeachpackagecontainingfissilematerial,itshallbeensuredthattheeffectivenessofitsshieldingandcontainmentand,wherenecessary,theheattransfercharacteristicsandtheeffectivenessoftheconfinementsystem,arewithinthelimitsapplicabletoorspecifiedfortheapproveddesign;OfficialJournaloftheEuropeanUnionEN26.1.2004L18/709(c)forpackagescontainingfissilematerial,where,inordertocomplywiththerequirementsof6.4.11.1,neutronpoisonsarespecificallyincludedascomponentsofthepackage,checksshallbeperformedtoconfirmthepresenceanddistributionofthoseneutronpoisons.5.1.5.1.2.RequirementsbeforeeachshipmentofapackageBeforeeachshipmentofanypackage,thefollowingrequirementsshallbefulfilled:(a)foranypackageitshallbeensuredthatalltherequirementsspecifiedintherelevantprovisionsofthisDirectivehavebeensatisfied;(b)itshallbeensuredthatliftingattachmentswhichdonotmeettherequirementsof6.4.2.2havebeenremovedorotherwiserenderedincapableofbeingusedforliftingthepackage,inaccordancewith6.4.2.3;(c)foreachTypeB(U),TypeB(M)andTypeCpackageandforeachpackagecontainingfissilematerial,itshallbeensuredthatalltherequirementsspecifiedintheapprovalcertificateshavebeensatisfied;(d)eachTypeB(U),TypeB(M)andTypeCpackageshallbehelduntilequilibriumconditionshavebeenapproachedcloselyenoughtodemonstratecompliancewiththerequirementsfortemperatureandpressureunlessanexemptionfromtheserequirementshasreceivedunilateralapproval;(e)foreachTypeB(U),TypeB(M)andTypeCpackage,itshallbeensuredbyinspectionand/orappropriateteststhatallclosures,valves,andotheropeningsofthecontainmentsystemthroughwhichtheradioactivecontentsmightescapeareproperlyclosedand,whereappropriate,sealedinthemannerforwhichthedemonstrationsofcompliancewiththerequirementsof6.4.8.7weremade;(f)foreachspecialformradioactivematerial,itshallbeensuredthatalltherequirementsspecifiedinthespecialformapprovalcertificateandtherelevantprovisionsofthisDirectivehavebeensatisfied;(g)forpackagescontainingfissilematerialthemeasurementspecifiedin6.4.11.4(b)andtheteststodemonstrateclosureofeachpackageasspecifiedin6.4.11.7shallbeperformedwhereapplicable;(h)foreachlowdispersibleradioactivematerial,itshallbeensuredthatalltherequirementsspecifiedintheapprovalcertificateandtherelevantprovisionsofthisDirectivehavebeensatisfied.5.1.5.2.Approvalofshipmentsandnotification5.1.5.2.1.GeneralInadditiontotheapprovalforpackagedesignsdescribedinChapter6.4,multilateralshipmentapprovalisalsorequiredincertaincircumstances(5.1.5.2.2and5.1.5.2.3).Insomecircumstancesitisalsonecessarytonotifycompetentauthoritiesofashipment(5.1.5.2.4).5.1.5.2.2.ShipmentapprovalsMultilateralapprovalshallberequiredfor:(a)theshipmentofTypeB(M)packagesnotconformingwiththerequirementsof6.4.7.5ordesignedtoallowcontrolledintermittentventing;(b)theshipmentofTypeB(M)packagescontainingradioactivematerialwithanactivitygreaterthan3000A1or3000A2,asappropriate,or1000TBq,whicheveristhelower;(c)theshipmentofpackagescontainingfissilematerialsifthesumofthecriticalitysafetyindexesofthepackagesexceeds50;exceptthatacompetentauthoritymayauthorisecarriageintoorthroughitscountrywithoutshipmentapproval,byaspecificprovisioninitsdesignapproval(see5.1.5.3.1).OfficialJournaloftheEuropeanUnionEN26.1.2004L18/7105.1.5.2.3.ShipmentapprovalbyspecialarrangementProvisionsmaybeapprovedbyacompetentauthorityunderwhichaconsignment,whichdoesnotsatisfyalloftheapplicablerequirementsofthisDirectivemaybecarriedunderspecialarrangement(see1.7.4).5.1.5.2.4.NotificationsNotificationtocompetentauthoritiesisrequiredasfollows:(a)beforethefirstshipmentofanypackagerequiringcompetentauthorityapproval,theconsignorshallensurethatcopiesofeachapplicablecompetentauthoritycertificateapplyingtothatpackagedesignhavebeensubmittedtothecompetentauthorityofeachcountrythroughorintowhichtheconsignmentistobecarried.Theconsignorisnotrequiredtoawaitanacknowledgementfromthecompetentauthority,noristhecompetentauthorityrequiredtomakesuchacknowledgementofreceiptofthecertificate;(b)foreachofthefollowingtypesofshipments:(i)TypeCpackagescontainingradioactivematerialwithanactivitygreaterthan3000A1or3000A2,asappropriate,or1000TBq,whicheveristhelower;(ii)TypeB(U)packagescontainingradioactivematerialwithanactivitygreaterthan3000A1or3000A2,asappropriate,or1000TBq,whicheveristhelower;(iii)TypeB(M)packages;(iv)Shipmentunderspecialarrangement.Theconsignorshallnotifythecompetentauthorityofeachcountrythroughorintowhichtheconsignmentistobecarried.Thisnotificationshallbeinthehandsofeachcompetentauthoritypriortothecommencementoftheshipment,andpreferablyatleastsevendaysinadvance;(c)theconsignorisnotrequiredtosendaseparatenotificationiftherequiredinformationhasbeenincludedintheapplicationforshipmentapproval;(d)theconsignmentnotificationshallinclude:(i)sufficientinformationtoenabletheidentificationofthepackageorpackagesincludingallapplicablecertificatenumbersandidentificationmarks;(ii)informationonthedateofshipment,theexpecteddateofarrivalandproposedrouteing;(iii)thename(s)oftheradioactivematerial(s)ornuclide(s);(iv)descriptionsofthephysicalandchemicalformsoftheradioactivematerial,orwhetheritisspecialformradioactivematerialorlowdispersibleradioactivematerial;and(v)themaximumactivityoftheradioactivecontentsduringcarriageexpressedinbecquerels(Bq)withanappropriateSIprefix(see1.2.2.1).Forfissilematerial,themassoffissilematerialingrams(g),ormultiplesthereof,maybeusedinplaceofactivity.5.1.5.3.Certificatesissuedbythecompetentauthority5.1.5.3.1.Certificatesissuedbythecompetentauthorityarerequiredforthefollowing:(a)designsfor:(i)specialformradioactivematerial;(ii)lowdispersibleradioactivematerial;(iii)packagescontaining0,1kgormoreofuraniumhexafluoride;(iv)allpackagescontainingfissilematerialunlessexceptedby6.4.11.2;(v)TypeB(U)packagesandTypeB(M)packages;(vi)TypeCpackages;(b)specialarrangements;(c)certainshipments(see5.1.5.2.2).Thecertificatesshallconfirmthattheapplicablerequirementsaremet,andfordesignapprovalsshallattributetothedesignanidentificationmark.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/711Thepackagedesignandshipmentapprovalcertificatesmaybecombinedintoasinglecertificate.Certificatesandapplicationsforthesecertificatesshallbeinaccordancewiththerequirementsin6.4.23.5.1.5.3.2.Theconsignorshallbeinpossessionofacopyofeachapplicablecertificate.Theconsignorshallalsohaveacopyofanyinstructionswithregardtotheproperclosingofthepackageandanypreparationforshipmentbeforemakinganyshipmentunderthetermsofthecertificates.5.1.5.3.3.Forpackagedesignswhereacompetentauthorityissuedcertificateisnotrequired,theconsignorshall,onrequest,makeavailableforinspectionbythecompetentauthority,documentaryevidenceofthecomplianceofthepackagedesignwithalltheapplicablerequirements.5.1.5.4.SummaryofapprovalandpriornotificationrequirementsNotes1.Beforefirstshipmentofanypackagerequiringcompetentauthorityapprovalofthedesign,theconsignorshallensurethatacopyoftheapprovalcertificateforthatdesignhasbeensubmittedtothecompetentauthorityofeachcountryenroute(see5.1.5.2.4(a)).2.Notificationrequiredifcontentsexceed3×103A1,or3×103A2,or1000TBq;(see5.1.5.2.4(b)).3.Multilateralapprovalofshipmentrequiredifcontentsexceed3×103A1,or3×103A2,or1000TBq,orifcontrolledintermittentventingisallowed(see5.1.5.2).4.Seeapprovalandpriornotificationprovisionsfortheapplicablepackageforcarryingthismaterial.SubjectUNNoCompetentauthorityapprovalrequiredConsignorrequiredtonotifythecompetentauthori-tiesofthecountryoforiginandofthecountriesenroute(a)beforeeachship-mentReferenceCountryoforiginCountriesenroute(a)CalculationofunlistedA1andA2values—YesYesNo—Exceptedpackages2908,2909,2910,2911——packagedesignNoNoNo—shipmentNoNoNoLSAmaterial(b)andSCO(b)Industrialpackagestypes1,2or3,non-fissileandfissileexcepted2912,2913,3321,3322——packagedesignNoNoNo—shipmentNoNoNoTypeApackages(b),non-fissileandfissileexcepted2915,3332——packagedesignNoNoNo—shipmentNoNoNoTypeB(U)packages(b),non-fissileandfissileexcepted29165.1.5.2.4(b),5.1.5.3.1(a)OfficialJournaloftheEuropeanUnionEN26.1.2004L18/712SubjectUNNoCompetentauthorityapprovalrequiredConsignorrequiredtonotifythecompetentauthori-tiesofthecountryoforiginandofthecountriesenroute(a)beforeeachship-mentReferenceCountryoforiginCountriesenroute(a)—packagedesignYesNoSeeNote1—shipmentNoNoSeeNote2TypeB(M)packages(b),non-fissileandfissileexcepted29175.1.5.2.4(b),5.1.5.3.1(a),5.1.5.2.2—packagedesignYesYesNo—shipmentSeeNote3SeeNote3YesTypeCpackages(b),non-fissileandfissileexcepted33235.1.5.2.4(b),5.1.5.3.1(a)—packagedesignYesNoSeeNote1—shipmentNoNoSeeNote2Packagesforfissilematerial2977,3324,3325,3326,3327,3328,3329,3330,3331,33335.1.5.3.1(a),5.1.5.2.2,6.4.22.4—packagedesignYes(c)Yes(c)No—shipment:sumofcriticalitysafetyindexesnotmorethan50No(d)No(d)SeeNote2sumofcriticalitysafetyindexesgreaterthan50YesYesSeeNote2Specialformradioactivematerial1.6.5.4,5.1.5.3.1(a)—design—YesNoNo—shipmentSeeNote4SeeNote4SeeNote4SeeNote4Lowdispersableradioactivematerial5.1.5.3.1(a),6.4.22.3OfficialJournaloftheEuropeanUnionEN26.1.2004L18/713SubjectUNNoCompetentauthorityapprovalrequiredConsignorrequiredtonotifythecompetentauthori-tiesofthecountryoforiginandofthecountriesenroute(a)beforeeachship-mentReferenceCountryoforiginCountriesenroute(a)—design—YesNoNo—shipmentSeeNote4SeeNote4SeeNote4SeeNote4Packagescontaining0,1kgormoreofuraniumhexa-fluoride5.1.5.3.1(a),6.4.22.3—design—YesNoNo—shipmentSeeNote4SeeNote4SeeNote4SeeNote4SpecialArrangement2919,33315.1.5.3.1(b),5.1.5.2.4(b)—shipmentYesYesYesApprovedpackagesdesignssubjectedtotransitionalmeasures—See1.6.5See1.6.5SeeNote11.6.5.2,1.6.5.3,5.1.5.2.4(b),5.1.5.3.1(a),5.1.5.2.2.(a)Countriesfrom,throughorintowhichtheconsignmentiscarried.(b)Iftheradioactivecontentsarefissilematerialwhichisnotexceptedfromtheprovisionsforpackagescontainingfissilematerial,thentheprovisionsforfissilematerialpackagesapply(see6.4.11).(c)Designsofpackagesforfissilematerialmayalsorequireapprovalinrespectofoneoftheotheritemsinthetable.(d)Shipmentsmay,however,requireapprovalinrespectofoneoftheotheritemsinthetable.CHAPTER5.2Markingandlabelling5.2.1.MarkingofpackagesNoteFormarkingsrelatedtotheconstruction,testingandapprovalofpackagings,largepackagings,gasreceptaclesandIBCs,seepart6.5.2.1.1.UnlessprovidedotherwiseinthisDirective,theUNnumbercorrespondingtothedangerousgoodscontained,precededbytheletters‘UN’shallbeclearlyanddurablymarkedoneachpackage.Inthecaseofunpackagedarticlesthemarkingshallbedisplayedonthearticle,onitscradleoronitshandling,storageorlaunchingdevice.5.2.1.2.Allpackagemarkingsrequiredbythischapter:(a)shallbereadilyvisibleandlegible;(b)shallbeabletowithstandopenweatherexposurewithoutasubstantialreductionineffectiveness.5.2.1.3.Salvagepackagingsshalladditionallybemarkedwiththeword‘SALVAGE’.5.2.1.4.Intermediatebulkcontainersofmorethan450litrescapacityshallbemarkedontwooppositesides.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/7145.2.1.5.AdditionalprovisionsforgoodsofClass1ForgoodsofClass1,packagesshall,inaddition,bearthepropershippingnameasdeterminedinaccordancewith3.1.2.Themarking,whichshallbeclearlylegibleandindelible,shallbeinanofficiallanguageofthecountryoforiginandalso,ifthatlanguageisnotEnglish,FrenchorGerman,inEnglish,FrenchorGermanunlessanyagreementsconcludedbetweenthecountriesconcernedinthetransportoperationprovideotherwise.5.2.1.6.AdditionalprovisionsforgoodsofClass2Refillablereceptaclesshallbearthefollowingparticularsinclearlylegibleanddurablecharacters:(a)theUNnumberandthepropershippingnameofthegasormixtureofgases,asdeterminedinaccordancewith3.1.2.InthecaseofgasesclassifiedunderanN.O.S.entry,onlythetechnicalname(1)ofthegashastobeindicatedinadditiontotheUNnumber.Inthecaseofmixtures,notmorethanthetwoconstituentswhichmostpredominantlycontributetothehazardshavetobeindicated;(b)forcompressedgasesfilledbymassandforliquefiedgases,eitherthemaximumfillingmassandthetareofthereceptaclewithfittingsandaccessoriesasfittedatthetimeoffilling,orthegrossmass;(c)thedate(year)ofthenextperiodicinspection.Thesemarkscaneitherbeengravedorindicatedonadurableinformationdiskorlabelattachedonthereceptacleorindicatedbyanadherentandclearlyvisiblemarkingsuchasbyprintingorbyanyequivalentprocess.Notes1.Seealso6.2.1.7.1.2.Fornon-refillablereceptacles,see6.2.1.7.2.5.2.1.7.SpecialmarkingprovisionsforgoodsofClass75.2.1.7.1.Eachpackageshallbelegiblyanddurablymarkedontheoutsideofthepackagingwithanidentificationofeithertheconsignororconsignee,orboth.5.2.1.7.2.Foreachpackage,otherthanexceptedpackages,theUNnumberprecededbytheletters‘UN’andthepropershippingnameshallbelegiblyanddurablymarkedontheoutsideofthepackaging.InthecaseofexceptedpackagesonlytheUNnumber,precededbytheletters‘UN’,isrequired.5.2.1.7.3.Eachpackageofgrossmassexceeding50kgshallhaveitspermissiblegrossmasslegiblyanddurablymarkedontheoutsideofthepackaging.5.2.1.7.4.Eachpackagewhichconformsto:(a)anindustrialpackageType1,anindustrialpackageType2oranindustrialpackageType3designshallbelegiblyanddurablymarkedontheoutsideofthepackagingwith‘TYPEIP-1’,‘TYPEIP-2’or‘TYPEIP-3’asappropriate;(b)aTypeApackagedesignshallbelegiblyanddurablymarkedontheoutsideofthepackagingwith‘TYPEA’;(c)anindustrialpackageType2,anindustrialpackageType3oraTypeApackagedesignshallbelegiblyanddurablymarkedontheoutsideofthepackagingwiththeinternationalvehicleregistrationcode(VRIcode)(2)ofthecountryoforiginofdesignandthenameofthemanufacturers,orotheridentificationofthepackagingspecifiedbythecompetentauthority.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/715(1)Insteadofthetechnicalnametheuseofoneofthefollowingnamesispermitted:—forUNNo1078refrigerantgas,N.O.S.:mixtureF1,mixtureF2,mixtureF3,—forUNNo1060methylacetyleneandpropadienemixtures,stabilised:mixtureP1,mixtureP2,—forUNNo1965hydrocarbongasmixture,liquefied,N.O.S.:mixtureAorbutane,mixtureA01orbutane,mixtureA02orbutane,mixtureA0orbutane,mixtureA1,mixtureB1,mixtureB2,mixtureB,mixtureCorpropane.(2)DistinguishingsignformotorvehiclesininternationaltrafficprescribedintheViennaConventiononRoadTraffic(1968).5.2.1.7.5.Eachpackagewhichconformstoadesignapprovedbythecompetentauthorityshallbelegiblyanddurablymarkedontheoutsideofthepackagingwith:(a)theidentificationmarkallocatedtothatdesignbythecompetentauthority;(b)aserialnumbertouniquelyidentifyeachpackagingwhichconformstothatdesign;(c)inthecaseofaTypeB(U)orTypeB(M)packagedesign,with‘TYPEB(U)’or‘TYPEB(M)’;and(d)inthecaseofaTypeCpackagedesign,with‘TYPEC’.5.2.1.7.6.EachpackagewhichconformstoaTypeB(U),TypeB(M)orTypeCpackagedesignshallhavetheoutsideoftheoutermostreceptaclewhichisresistanttotheeffectsoffireandwaterplainlymarkedbyembossing,stampingorothermeansresistanttotheeffectsoffireandwaterwiththetrefoilsymbolshowninthefigurebelow.BasictrefoilsymbolwithproportionsbasedonacentralcircleofradiusXTheminimumallowablesizeofXshallbe4mm5.2.1.7.7.WhereLSA-IorSCO-Imaterialiscontainedinreceptaclesorwrappingmaterialsandiscarriedunderexclusiveuseaspermittedby4.1.9.2.3,theoutersurfaceofthesereceptaclesorwrappingmaterialsmaybearthemarking‘RADIOACTIVELSA-I’or‘RADIOACTIVESCO-I’,asappropriate.5.2.2.Labellingofpackages5.2.2.1.Labellingprovisions5.2.2.1.1.ForeacharticleorsubstancelistedinTableAofChapter3.2,thelabelsshownincolumn5shallbeaffixedunlessotherwiseprovidedforbyaspecialprovisionincolumn6.5.2.2.1.2.Indelebiledangermarkingscorrespondingexactlytotheprescribedmodelsmaybeusedinsteadoflabels.5.2.2.1.3to5.2.2.1.5.(Reserved)5.2.2.1.6.Eachlabelshall:(a)beaffixedtothesamesurfaceofthepackage,ifthedimensionsofthepackageallow;forpackagesofClass1and7,nearthemarkindicatingthepropershippingname;(b)besoplacedonthepackagethatitisnotcoveredorobscuredbyanypartorattachmenttothepackagingoranyotherlabelormarking;andOfficialJournaloftheEuropeanUnionEN26.1.2004L18/716(c)bedisplayednexttoeachotherwhenmorethanonelabelisrequired.Whereapackageisofsuchanirregularshapeorsmallsizethatalabelcannotbesatisfactorilyaffixed,thelabelmaybeattachedtothepackagebyasecurelyaffixedtagorothersuitablemeans.5.2.2.1.7.Intermediatebulkcontainersofmorethan450litrescapacityshallbelabelledontwooppositesides.5.2.2.1.8.(Reserved)5.2.2.1.9.Specialprovisionsforthelabellingofself-reactivesubstancesandorganicperoxides(a)ThelabelconformingtomodelNo4.1alsoimpliesthattheproductmaybeflammableandhencenolabelconformingtomodelNo3isrequired.Inaddition,alabelconformingtomodelNo1shallbeappliedforself-reactivesubstancesTypeB,unlessthecompetentauthorityhaspermittedthislabeltobedispensedwithforaspecificpackagingbecausetestdatahaveproventhattheself-reactivesubstanceinsuchapackagingdoesnotexhibitexplosivebehaviour.(b)ThelabelconformingtomodelNo5.2alsoimpliesthattheproductmaybeflammableandhencenolabelconformingtomodelNo3isrequired.Inaddition,thefollowinglabelsshallbeapplied:(i)alabelconformingtomodelNo1fororganicperoxidestypeB,unlessthecompetentauthorityhaspermittedthislabeltobedispensedwithforaspecificpackagingbecausetestdatahaveproventhattheorganicperoxideinsuchapackagingdoesnotexhibitexplosivebehaviour;(ii)alabelconformingtomodelNo8isrequiredwhenPackingGroupIorIIcriteriaofClass8aremet.Forself-reactivesubstancesandorganicperoxidesmentionedbyname,thelabelstobeaffixedareindicatedinthelistfoundin2.2.41.4and2.2.52.4respectively.5.2.2.1.10.SpecialprovisionsforthelabellingofinfectioussubstancespackagesInadditiontothelabelconformingtomodelNo6.2,infectioussubstancespackagesshallbearanyotherlabelrequiredbythenatureofthecontents.5.2.2.1.11.Specialprovisionsforthelabellingofradioactivematerial5.2.2.1.11.1.Exceptasprovidedforlargecontainersandtanksinaccordancewith5.3.1.1.3,eachpackage,overpackandcontainercontainingradioactivematerialshallbearatleasttwolabelswhichconformtothemodelsNos7A,7B,and7Casappropriateaccordingtothecategory(see2.2.7.8.4)ofthatpackage,overpackorcontainer.Labelsshallbeaffixedtotwooppositesidesontheoutsideofthepackageorontheoutsideofallfoursidesofthecontainer.Eachoverpackcontainingradioactivematerialshallbearatleasttwolabelsonoppositesidesoftheoutsideoftheoverpack.Inaddition,eachpackage,overpackandcontainercontainingfissilematerial,otherthanfissilematerialexceptedunder6.4.11.2shallbearlabelswhichconformtomodelNo7E;suchlabels,whereapplicableshallbeaffixedadjacenttothelabelsforradioactivematerial.Labelsshallnotcoverthemarkingsspecifiedin5.2.1.Anylabelswhichdonotrelatetothecontentsshallberemovedorcovered.5.2.2.1.11.2.EachlabelconformingtomodelsNos7A,7B,and7Cshallbecompletedwiththefollowinginformation.(a)Contents:(i)exceptforLSA-Imaterial,thename(s)oftheradionuclide(s)astakenfromTable2.2.7.7.2.1,usingthesymbolsprescribedtherein.Formixturesofradionuclides,themostrestrictivenuclidesshallbelistedtotheextentthespaceonthelinepermits.ThegroupofLSAorSCOshallbeshownfollowingthename(s)oftheradionuclide(s).Theterms‘LSA-II’,‘LSA-III’,‘SCO-I’and‘SCO-II’shallbeusedforthispurpose;(ii)forLSA-Imaterial,onlytheterm‘LSA-I’isnecessary;thenameoftheradionuclideisnotnecessary;(b)activity:themaximumactivityoftheradioactivecontentsduringcarriageexpressedinbecquerels(Bq)withtheappropriateSIprefix(see1.2.2.1).Forfissilematerial,themassoffissilematerialingrams(g),ormultiplesthereof,maybeusedinplaceofactivity;(c)foroverpacksandcontainersthe‘contents’and‘activity’entriesonthelabelshallbeartheinformationrequiredinpoints(a)and(b),respectively,totalledtogetherfortheentirecontentsoftheoverpackorcontainerexceptthatonlabelsforoverpacksorcontainerscontainingmixedloadsofpackagescontainingdifferentradionuclides,suchentriesmayread‘Seetransportdocuments’;(d)transportindex:see2.2.7.6.1.1and2.2.7.6.1.2(notransportindexentryisrequiredforcategoryI-WHITE).5.2.2.1.11.3.EachlabelconformingtothemodelNo7Eshallbecompletedwiththecriticalitysafetyindex(CSI)asstatedinthecertificateofapprovalforspecialarrangementorthecertificateofapprovalforthepackagedesignissuedbythecompetentauthority.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/7175.2.2.1.11.4.Foroverpacksandcontainers,thecriticalitysafetyindex(CSI)onthelabelshallbeartheinformationrequiredin5.2.2.1.11.3totalledtogetherforthefissilecontentsoftheoverpackorcontainer.5.2.2.1.12.AdditionallabellingWiththeexceptionofClasses1and7,labelconformingtomodelNo11illustratedin5.2.2.2.2shallbedisplayedontwooppositesidesofapackageonthefollowingpackages:—packagescontainingliquidsinreceptacles,theclosuresofwhicharenotvisiblefromtheoutside,—packagescontainingventedreceptaclesorventedreceptacleswithoutouterpackaging,and—packagescontainingrefrigeratedliquefiedgases.5.2.2.2.Provisionsforlabels5.2.2.2.1.Labelsshallsatisfytheprovisionsbelowandconform,intermsofcolour,symbolsandgeneralformat,tothemodelsshownin5.2.2.2.2.5.2.2.2.1.1.Labels,exceptlabelsconformingtomodelNo11,shallbeintheformofasquaresetatanangleof45°(diamond-shaped)withminimumdimensionsof100mmby100mm.Theyhavealineofthesamecolourasthesymbol,5mminsidetheedgeandrunningparallelwithit.LabelsconformingtomodelNo11shallberectangular,ofstandardformatA5(148×210mm).Ifthesizeofthepackagesorequires,thedimensionsofthelabelsmaybereduced,providedthattheyremainclearlyvisible.5.2.2.2.1.2.GascylindersforClass2may,onaccountoftheirshape,orientationandsecuringmechanismsforcarriage,bearlabelsrepresentativeofthosespecifiedinthissection,whichhavebeenreducedinsize,accordingtothedimensionsoutlinedinISO7225:1994,‘Gascylinders—Precautionarylabels’,fordisplayonthenon-cylindricalpart(shoulder)ofsuchcylinders.5.2.2.2.1.3.Labels,exceptlabelconformingtomodelNo11,aredividedintohalves.Withtheexceptionofdivisions1.4,1.5and1.6,theupperhalfofthelabelisreservedforthepictorialsymbolandthelowerhalffortextsandtheclassnumberandthecompatibilitygroupletterasappropriate.NoteForlabelsofClasses1,2,3,5.1,5.2,7,8and9,therespectiveclassnumbershallbeshowninthebottomcorner.ForlabelsofClasses4.1,4.2and4.3andofClasses6.1and6.2onlyfigures4and6respectivelyshallbeshowninthebottomcorner(see5.2.2.2.2).5.2.2.2.1.4.Exceptfordivisions1.4,1.5and1.6,labelsforClass1showinthelowerhalfthedivisionnumberandcompatibilitygroupletterforthesubstanceorarticle.Labelsfordivisions1.4,1.5and1.6showintheupperhalfthedivisionnumberandinthelowerhalfthecompatibilitygroupletter.5.2.2.2.1.5.OnlabelsotherthanthoseformaterialofClass7,theoptionalinsertionofanytext(otherthantheclassnumber)inthespacebelowthesymbolshallbeconfinedtoparticularsindicatingthenatureoftheriskandprecautionstobetakeninhandling.5.2.2.2.1.6.Thesymbols,textandnumbersshallbeclearlylegibleandindelibleandshallbeshowninblackonalllabelsexceptfor:(a)theClass8label,wherethetext(ifany)andclassnumbershallappearinwhite;and(b)labelswithentirelygreen,redorbluebackgroundswheretheymaybeshowninwhite.5.2.2.2.1.7.Alllabelsshallbeabletowithstandopenweatherexposurewithoutasubstantialreductionineffectiveness.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/7185.2.2.2.2.SpecimenlabelsOfficialJournaloftheEuropeanUnionEN26.1.2004L18/719OfficialJournaloftheEuropeanUnionEN26.1.2004L18/720OfficialJournaloftheEuropeanUnionEN26.1.2004L18/721OfficialJournaloftheEuropeanUnionEN26.1.2004L18/722OfficialJournaloftheEuropeanUnionEN26.1.2004L18/723CHAPTER5.3Placardingandmarkingofcontainers,MEGCs,tank-containers,portabletanksandvehiclesNoteFormarkingandplacardingofcontainers,MEGCs,tank-containersandportabletanksforcarriageinatransportchainincludingamaritimejourney,seealso1.1.4.2.Iftheprovisionsof1.1.4.2(c)areapplied,only5.3.1.3and5.3.2.1.1ofthischapterareapplicable.5.3.1.Placarding5.3.1.1.Generalprovisions5.3.1.1.1.Asandwhenrequiredinthissection,placardsshallbeaffixedtotheexteriorsurfaceofcontainers,MEGCs,tank-containers,portabletanksandvehicles.Placardsshallcorrespondtothelabelsrequiredincolumn5and,whereappropriate,column6ofTableAofChapter3.2forthedangerousgoodscontainedinthecontainer,MEGC,tank-container,portabletankorvehicleandshallconformtothespecificationsgivenin5.3.1.7.5.3.1.1.2.ForClass1,compatibilitygroupsshallnotbeindicatedonplacardsifthetransportunitorcontaineriscarryingsubstancesorarticlesbelongingtotwoormorecompatibilitygroups.Transportunitsorcontainerscarryingsubstancesorarticlesofdifferentdivisionsshallbearonlyplacardsconformingtothemodelofthemostdangerousdivisionintheorder:1.1(mostdangerous),1.5,1.2,1.3,1.6,1.4(leastdangerous).When1.5Dsubstancesarecarriedwithsubstancesorarticlesofdivision1.2,thetransportunitorcontainershallbeplacardedasdivision1.1.5.3.1.1.3.ForClass7,theprimaryriskplacardshallconformtomodelNo7Dasspecifiedin5.3.1.7.2.Thisplacardisnotrequiredforvehiclesorcontainerscarryingexceptedpackagesandforsmallcontainers.WherebothClass7labelsandplacardswouldberequiredtobeaffixedtovehicles,containers,MEGCs,tank-containersorportabletanks,anenlargedlabelcorrespondingtothelabelrequiredmaybedisplayedinsteadofplacardNo7Dtoservebothpurposes.5.3.1.1.4.Containers,MEGCs,tank-containers,portabletanksorvehiclescontaininggoodsofmorethanoneclassneednotbearasubsidiaryriskplacardifthehazardrepresentedbythatplacardisalreadyindicatedbyaprimaryorsubsidiaryriskplacard.5.3.1.1.5.Placardswhichdonotrelatetothedangerousgoodsbeingcarried,orresiduesthereof,shallberemovedorcovered.5.3.1.2.Placardingofcontainers,MEGCs,tank-containersandportabletanksNoteThissubsectiondoesnotapplytoswap-bodies,excepttankswapbodiesorswap-bodiescarriedincombinedroad/railtransport.Theplacardsshallbeaffixedtobothsidesandateachendofthecontainer,MEGC,tank-containerorportabletank.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/7245.3.1.3.Placardingofvehiclescarryingcontainers,MEGCs,tank-containersorportabletanksNoteThissubsectiondoesnotapplytotheplacardingofvehiclescarryingswap-bodiesotherthantankswap-bodiesorthanswap-bodiescarriedincombinedroad/railtransport;forsuchvehicles,see5.3.1.5.Iftheplacardsaffixedtothecontainers,MEGCs,tank-containersorportabletanksarenotvisiblefromoutsidethecarryingvehicles,thesameplacardsshallalsobeaffixedtobothsidesandattherearofthevehicle.Otherwise,noplacardneedbeaffixedonthecarryingvehicle.5.3.1.4.Placardingofvehiclesforcarriageinbulk,tank-vehicles,batteryvehiclesandvehicleswithdemountabletanksPlacardsshallbeaffixedtobothsidesandattherearofthevehicle.NoteWhen,inthecourseofajourneycoveredbythisDirective,orattheendofsuchajourney,atanksemi-trailerisseparatedfromitstractortobeloadedonboardashiporaninlandnavigationvessel,placardsshallalsobedisplayedatthefrontofthesemi-trailer.5.3.1.5.PlacardingofvehiclescarryingpackagesonlyNoteThissubsectionappliesalsotovehiclescarryingswap-bodiesloadedwithpackages,exceptforcombinedroad/railtransport;forcombinedroad/railtransport,see5.3.1.2and5.3.1.3.5.3.1.5.1.ForvehiclescarryingpackagescontainingsubstancesorarticlesofClass1,placardsshallbeaffixedtobothsidesandattherearofthevehicle.5.3.1.5.2.ForvehiclescarryingradioactivematerialofClass7inpackagingsorIBCs(otherthanexceptedpackages),placardsshallbeaffixedtobothsidesandattherearofthevehicle.NoteIf,duringajourneycoveredbythisDirective,avehiclecarryingpackagescontainingdangerousgoodsofclassesotherthanClasses1and7isloadedonboardashipforseatransportorifthejourneycoveredbythisDirectiveprecedesavoyagebysea,placardsshallbeaffixedtobothsidesandattherearofthevehicle.Placardsmayremainaffixedtobothsidesandattherearofthevehicleafteraseavoyage.5.3.1.6.Placardingofemptytank-vehicles,battery-vehicles,MEGCs,tank-containers,portabletanksandemptyvehiclesandcontainersforcarriageinbulk5.3.1.6.1.Emptytank-vehicles,vehicleswithdemountabletanks,battery-vehicles,MEGCs,tank-containersandportabletanksuncleanedandnotdegassed,andemptyvehiclesandcontainersforcarriageinbulk,uncleaned,shallcontinuetodisplaytheplacardsrequiredforthepreviousload.5.3.1.7.Specificationsforplacards5.3.1.7.1.Exceptasprovidedin5.3.1.7.2fortheClass7placard,aplacardshall:(a)benotlessthan250mmby250mm,withalineofthesamecolourasthesymbolrunning12,5mminsidetheedgeandparallelwithit;(b)correspondtothelabelrequiredforthedangerousgoodsinquestionwithrespecttocolourandsymbol(see5.2.2.2);and(c)displaythenumbers(andforgoodsofClass1,thecompatibilitygroupletter)prescribedforthedangerousgoodsinquestionin5.2.2.2forthecorrespondinglabel,indigitsnotlessthan25mmhigh.5.3.1.7.2.TheClass7placardshallbenotlessthan250mmby250mmwithablacklinerunning5mminsidetheedgeandparallelwithitandisotherwiseasshownbelow(ModelNo7D).Thenumber‘7’shallnotbelessthan25mmhigh.Thebackgroundcolouroftheupperhalfoftheplacardshallbeyellowandofthelowerhalfwhite,thecolourofthetrefoilandtheprintingshallbeblack.Theuseoftheword‘RADIOACTIVE’inthebottomhalfisoptionaltoallowtheuseofthisplacardtodisplaytheappropriateUNnumberfortheconsignment.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/7255.3.1.7.3.Fortankswithacapacityofnotmorethan3m3andforsmallcontainers,placardsmaybereplacedbylabelsconformingto5.2.2.2.5.3.1.7.4.ForClasses1and7,ifthesizeandconstructionofthevehiclearesuchthattheavailablesurfaceareaisinsufficienttoaffixtheprescribedplacards,theirdimensionsmaybereducedto100mmoneachside.5.3.2.Orange-colouredplatemarking5.3.2.1.Generalorange-colouredplatemarkingprovisions5.3.2.1.1.Transportunitscarryingdangerousgoodsshalldisplaytworectangularreflectorisedorange-colouredplatesconformingto5.3.2.2.1,setinaverticalplane.Theyshallbeaffixedoneatthefrontandtheotherattherearofthetransportunit,bothperpendiculartothelongitudinalaxisofthetransportunit.Theyshallbeclearlyvisible.5.3.2.1.2.Whenahazardidentificationnumberisindicatedincolumn20ofTableAofChapter3.2,tank-vehiclesortransportunitshavingoneormoretankscarryingdangerousgoodsshallinadditiondisplayonthesidesofeachtankortankcompartment,clearlyvisibleandparalleltothelongitudinalaxisofthevehicle,orange-colouredplatesidenticalwiththoseprescribedin5.3.2.1.1.Theseorange-colouredplatesshallbearthehazardidentificationnumberandtheUNnumberprescribedrespectivelyincolumns20and1ofTableAofChapter3.2foreachofthesubstancescarriedinthetankorinacompartmentofthetank.5.3.2.1.3.Fortank-vehiclesortransportunitshavingoneormoretankscarryingsubstanceswithUNNos1202,1203or1223,oraviationfuelclassedunderUNNos1268or1863,butnootherdangeroussubstance,theorange-colouredplatesprescribedin5.3.2.1.2neednotbeaffixediftheplatesaffixedtothefrontandrearinaccordancewith5.3.2.1.1bearthehazardidentificationnumberandtheUNnumberprescribedforthemosthazardoussubstancecarried,i.e.thesubstancewiththelowestflash-point.5.3.2.1.4.Whenahazardidentificationnumberisindicatedincolumn20ofTableAofChapter3.2,transportunitsandcontainerscarryingdangeroussolidsubstancesinbulkshallinadditiondisplayonthesidesofeachtransportunitorcontainer,clearlyvisibleandparalleltothelongitudinalaxisofthevehicle,orange-colouredplatesidenticalwiththoseprescribedin5.3.2.1.1.Theseorange-colouredplatesshallbearthehazardidentificationnumberandtheUNnumberprescribedrespectivelyincolumns20and1ofTableAofChapter3.2foreachofthesubstancescarriedinbulkinthetransportunitorinthecontainer.5.3.2.1.5.Forcontainerscarryingdangeroussolidsubstancesinbulkandfortanks-containers,MEGCsandportabletanks,theplatesprescribedin5.3.2.1.2and5.3.2.1.4maybereplacedbyaself-adhesivesheet,bypaintorbyanyotherequivalentprocess,providedthematerialusedforthispurposeisweather-resistantandensuresdurablemarking.Inthiscase,theprovisionsofthelastsentenceof5.3.2.2.2,concerningresistancetofire,shallnotapply.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/7265.3.2.1.6.Fortransportunitscarryingonlyonesubstance,theorange-colouredplatesprescribedin5.3.2.1.2and5.3.2.1.4shallnotbenecessaryprovidedthatthosedisplayedatthefrontandrearinaccordancewith5.3.2.1.1bearthehazardidentificationnumberandtheUNnumberprescribedrespectivelyincolumns20and1ofTableAofChapter3.2.5.3.2.1.7.Theaboverequirementsarealsoapplicabletoemptyfixedordemountabletanks,tank-containers,MEGCs,portabletanksandbattery-vehicles,uncleanedandnotdegassedandemptyvehiclesandemptycontainersforcarriageinbulk,uncleaned.5.3.2.1.8.Orange-colouredplateswhichdonotrelatetodangerousgoodscarried,orresiduesthereof,shallberemovedorcovered.Ifplatesarecovered,thecoveringshallbetotalandremaineffectiveafter15minutesengulfmentinfire.5.3.2.2.Specificationsfortheorange-colouredplates5.3.2.2.1.Thereflectorisedorange-colouredplatesshallbeof40cmbaseandnotlessthan30cmhigh;theyshallhaveablackbordernotmorethan15mmwide.Ifthesizeandconstructionofthevehiclearesuchthattheavailablesurfaceareaisinsufficienttoaffixtheseorange-colouredplates,theirdimensionsmaybereducedto300mmforthebase,120mmfortheheightand10mmfortheblackborder.NoteThecolouroftheorangeplatesinconditionsofnormaluseshouldhavechromaticitycoordinateslyingwithintheareaonthechromaticitydiagramformedbyjoiningthefollowingcoordinates.Chromaticitycoordinatesofpointsatthecornersoftheareaonthechromaticitydiagramx0,520,520,5780,618y0,380,400,4220,38Luminancefactorofreflectorisedcolour:ß≥0,12.ReferencecentreE,standardilluminantC,normalincidence45°,viewedat0°.Co-efficientofreflexluminousintensityatanangleofilluminationof5°,viewedat0,2°:notlessthan20candelasperluxperm2.5.3.2.2.2.ThehazardidentificationnumberandtheUNnumbershallconsistofblackdigits100mmhighandof15mmstrokethickness.Thehazard-identificationnumbershallbeinscribedintheupperpartoftheplateandtheUNnumberinthelowerpart;theyshallbeseparatedbyahorizontalblackline,15mminstrokewidth,extendingfromsidetosideoftheplateatmid-height(see5.3.2.2.3).ThehazardidentificationnumberandtheUNnumbershallbeindelibleandshallremainlegibleafter15minutesengulfmentinfire.5.3.2.2.3.Exampleoforange-colouredplatewithhazardidentificationnumberandUNnumberOfficialJournaloftheEuropeanUnionEN26.1.2004L18/7275.3.2.3.Meaningofhazardidentificationnumbers5.3.2.3.1.Thehazardidentificationnumberconsistsoftwoorthreefigures.Ingeneral,thefiguresindicatethefollowinghazards:2emissionofgasduetopressureortochemicalreaction3flammabilityofliquids(vapours)andgasesorself-heatingliquid4flammabilityofsolidsorself-heatingsolid5oxidising(fire-intensifying)effect6toxicityorriskofinfection7radioactivity8corrosivity9riskofspontaneousviolentreactionNoteTheriskofspontaneousviolentreactionwithinthemeaningoffigure9includesthepossibilityfollowingfromthenatureofasubstanceofariskofexplosion,disintegrationandpolymerizationreactionfollowingthereleaseofconsiderableheatorflammableand/ortoxicgases.Doublingofafigureindicatesanintensificationofthatparticularhazard.Wherethehazardassociatedwithasubstancecanbeadequatelyindicatedbyasinglefigure,thisisfollowedbyzero.Thefollowingcombinationsoffigures,however,haveaspecialmeaning:22,323,333,362,382,423,44,446,462,482,539,606,623,642,823,842,90and99,see5.3.2.3.2below.Ifahazardidentificationnumberisprefixedbytheletter‘X’,thisindicatesthatthesubstancewillreactdangerouslywithwater.Forsuchsubstances,watermayonlybeusedbyapprovalofexperts.5.3.2.3.2.Thehazardidentificationnumberslistedincolumn20ofTableAofChapter3.2havethefollowingmeanings:20asphyxiantgasorgaswithnosubsidiaryrisk22refrigeratedliquefiedgas,asphyxiant223refrigeratedliquefiedgas,flammable225refrigeratedliquefiedgas,oxidising(fire-intensifying)23flammablegas239flammablegas,whichcanspontaneouslyleadtoviolentreaction25oxidising(fire-intensifying)gas26toxicgas263toxicgas,flammable265toxicgas,oxidising(fire-intensifying)268toxicgas,corrosive30flammableliquid(flash-pointbetween23°Cand61°C,inclusive)orflammableliquidorsolidinthemoltenstatewithaflash-pointabove61°C,heatedtoatemperatureequaltooraboveitsflash-point,orself-heatingliquid323flammableliquidwhichreactswithwater,emittingflammablegasesX323flammableliquidwhichreactsdangerouslywithwater,emittingflammablegases(1)33highlyflammableliquid(flash-pointbelow23°C)333pyrophoricliquidX333pyrophoricliquidwhichreactsdangerouslywithwater(1)OfficialJournaloftheEuropeanUnionEN26.1.2004L18/728336highlyflammableliquid,toxic338highlyflammableliquid,corrosiveX338highlyflammableliquid,corrosive,whichreactsdangerouslywithwater(1)339highlyflammableliquidwhichcanspontaneouslyleadtoviolentreaction36flammableliquid(flash-pointbetween23°Cand61°C,inclusive),slightlytoxic,orself-heatingliquid,toxic362flammableliquid,toxic,whichreactswithwater,emittingflammablegasesX362flammableliquidtoxic,whichreactsdangerouslywithwater,emittingflammablegases(1)368flammableliquid,toxic,corrosive38flammableliquid(flash-pointbetween23°Cand61°C,inclusive),slightlycorrosiveorself-heatingliquid,corrosive382flammableliquid,corrosive,whichreactswithwater,emittingflammablegasesX382flammableliquid,corrosive,whichreactsdangerouslywithwater,emittingflammablegases(1)39flammableliquid,whichcanspontaneouslyleadtoviolentreaction40flammablesolid,orself-reactivesubstance,orself-heatingsubstance423solidwhichreactswithwater,emittingflammablegasesX423flammablesolidwhichreactsdangerouslywithwater,emittingflammablegases(1)43spontaneouslyflammable(pyrophoric)solid44flammablesolid,inthemoltenstateatanelevatedtemperature446flammablesolid,toxic,inthemoltenstate,atanelevatedtemperature46flammableorself-heatingsolid,toxic462toxicsolidwhichreactswithwater,emittingflammablegasesX462solidwhichreactsdangerouslywithwater,emittingtoxicgases(1)48flammableorself-heatingsolid,corrosive482corrosivesolidwhichreactswithwater,emittingflammablegasesX482solidwhichreactsdangerouslywithwater,emittingcorrosivegases(1)50oxidising(fire-intensifying)substance539flammableorganicperoxide55stronglyoxidising(fire-intensifying)substance556stronglyoxidising(fire-intensifying)substance,toxic558stronglyoxidising(fire-intensifying)substance,corrosive559stronglyoxidising(fire-intensifying)substance,whichcanspontaneouslyleadtoviolentreaction56oxidisingsubstance(fire-intensifying),toxic568oxidisingsubstance(fire-intensifying),toxic,corrosive58oxidisingsubstance(fire-intensifying),corrosive59oxidisingsubstance(fire-intensifying)whichcanspontaneouslyleadtoviolentreactionOfficialJournaloftheEuropeanUnionEN26.1.2004L18/72960toxicorslightlytoxicsubstance606infectioussubstance623toxicliquid,whichreactswithwater,emittingflammablegases63toxicsubstance,flammable(flash-pointbetween23°Cand61°C,inclusive)638toxicsubstance,flammable(flash-pointbetween23°Cand61°C,inclusive),corrosive639toxicsubstance,flammable(flash-pointnotabove61°C)whichcanspontaneouslyleadtoviolentreaction64toxicsolid,flammableorself-heating642toxicsolid,whichreactswithwater,emittingflammablegases65toxicsubstance,oxidising(fire-intensifying)66highlytoxicsubstance663highlytoxicsubstance,flammable(flash-pointnotabove61°C)664highlytoxicsolid,flammableorself-heating665highlytoxicsubstance,oxidising(fire-intensifying)668highlytoxicsubstance,corrosive669highlytoxicsubstancewhichcanspontaneouslyleadtoviolentreaction68toxicsubstance,corrosive69toxicorslightlytoxicsubstance,whichcanspontaneouslyleadtoviolentreaction70radioactivematerial72radioactivegas723radioactivegas,flammable73radioactiveliquid,flammable(flash-pointnotabove61°C)74radioactivesolid,flammable75radioactivematerial,oxidising(fire-intensifying)76radioactivematerial,toxic78radioactivematerial,corrosive80corrosiveorslightlycorrosivesubstanceX80corrosiveorslightlycorrosivesubstance,whichreactsdangerouslywithwater(1)823corrosiveliquidwhichreactswithwater,emittingflammablegases83corrosiveorslightlycorrosivesubstance,flammable(flash-pointbetween23°Cand61°C,inclusive)X83corrosiveorslightlycorrosivesubstance,flammable,(flash-pointbetween23°Cand61°C,inclusive),whichreactsdangerouslywithwater(1)839corrosiveorslightlycorrosivesubstance,flammable(flash-pointbetween23°Cand61°Cinclusive)whichcanspontaneouslyleadtoviolentreactionX839corrosiveorslightlycorrosivesubstance,flammable(flash-pointbetween23°Cand61°Cinclusive),whichcanspontaneouslyleadtoviolentreactionandwhichreactsdangerouslywithwater(1)84corrosivesolid,flammableorself-heatingOfficialJournaloftheEuropeanUnionEN26.1.2004L18/730842corrosivesolidwhichreactswithwater,emittingflammablegases85corrosiveorslightlycorrosivesubstance,oxidising(fire-intensifying)856corrosiveorslightlycorrosivesubstance,oxidising(fire-intensifying)andtoxic86corrosiveorslightlycorrosivesubstance,toxic88highlycorrosivesubstanceX88highlycorrosivesubstance,whichreactsdangerouslywithwater(1)883highlycorrosivesubstance,flammable(flash-pointbetween23°Cand61°Cinclusive)884highlycorrosivesolid,flammableorself-heating885highlycorrosivesubstance,oxidising(fire-intensifying)886highlycorrosivesubstance,toxicX886highlycorrosivesubstance,toxic,whichreactsdangerouslywithwater(1)89corrosiveorslightlycorrosivesubstance,whichcanspontaneouslyleadtoviolentreaction90environmentallyhazardoussubstance;miscellaneousdangeroussubstances99miscellaneousdangeroussubstancecarriedatanelevatedtemperature.(1)Waternottobeusedexceptwithapprovalofexperts.5.3.3.MarkforelevatedtemperaturesubstancesTank-vehicles,tank-containers,portabletanks,specialvehiclesorcontainersorespeciallyequippedvehiclesorcontainersforwhichamarkforelevatedtemperaturesubstancesisrequiredaccordingtospecialprovision580incolumn6ofTableAofChapter3.2shallbearonbothsidesandattherearforvehicles,andonbothsidesandateachendforcontainers,tank-containersandportabletanks,atriangularshapedmarkwithsidesofatleast250mm,tobeshowninred,asreproducedbelow.CHAPTER5.4Documentation5.4.0.AnycarriageofgoodsgovernedbythisDirectiveshallbeaccompaniedbythedocumentationprescribedinthisChapter,asappropriate,unlessexemptedunder1.1.3.1to1.1.3.5.Notes1.Forthelistofdocumentationtobecarriedonboardtransportunits,see8.1.2.2.Theuseofelectronicdataprocessing(EDP)orelectronicdatainterchange(EDI)techniquesasanaidtoorinsteadofpaperdocumentationispermitted,providedthattheproceduresusedforthecapture,storageandprocessingofelectronicdatameetthelegalrequirementsasregardstheevidentialvalueandavailabilityofdataduringtransportinamanneratleastequivalenttothatofpaperdocumentation.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/7315.4.1.Dangerousgoodstransportdocumentandrelatedinformation5.4.1.1.Generalinformationrequiredinthetransportdocument5.4.1.1.1.Thetransportdocument(s)shallcontainthefollowinginformationforeachdangeroussubstance,materialorarticleofferedforcarriage:(a)theUNnumber;(b)thepropershippingnamesupplemented,whenapplicable(see3.1.2.6),withthetechnical,chemicalorbiologicalname,asdeterminedinaccordancewith3.1.2;(c)theclassofthegoods,orforsubstancesandarticlesofClass1thedivision,followedimmediatelybythecompatibilitygroupletter;(d)whereassigned,thepackinggroupforthesubstanceorarticle;(e)theinitialsADRorRID;(f)thenumberandadescriptionofthepackages;(g)thetotalquantityofdangerousgoodscoveredbythedescription(asavolumeorasagrossmass,orasanetmassasappropriate);NoteInthecaseofapplicationof1.1.3.6thetotalquantityofdangerousgoodscarriedpertransportunitshallbeexpressedasavaluecalculatedinaccordancewiththeprovisionsof1.1.3.6.(h)thenameandaddressoftheconsignor;(i)thenameandaddressoftheconsignee(s);(j)adeclarationasrequiredbythetermsofanyspecialagreement.Thelocationandorderinwhichtheelementsofinformationrequiredappearinthetransportdocumentisleftoptional,exceptthat(a),(b),(c),(d)and(e)shallappearinthatsequence,e.g.:‘1098ALLYLALCOHOL,6.1,I,ADR’.5.4.1.1.2.Theinformationrequiredonatransportdocumentshallbelegible.5.4.1.1.3.SpecialprovisionsforwasteIfwastecontainingdangerousgoods(otherthanradioactivewaste)isbeingcarried,theUNnumberandthepropershippingnameshallbeprecededbytheword‘WASTE’,unlessthistermispartofthepropershippingname,e.g.:‘WASTE,1230METHANOL,3,II,ADR’,or‘WASTE,1993FLAMMABLELIQUID,N.O.S.,(tolueneandethylalcohol),3,II,ADR’.5.4.1.1.4.SpecialprovisionsfordangerousgoodspackedinlimitedquantitiesNoinformationisrequiredinthetransportdocument,ifany,forcarriageofdangerousgoodspackedinlimitedquantitiesaccordingtoChapter3.4.5.4.1.1.5.SpecialprovisionsforsalvagepackagingsWhendangerousgoodsarecarriedinasalvagepackaging,thewords‘SALVAGEPACKAGE’shallbeaddedafterthedescriptionofthegoodsinthetransportdocument.5.4.1.1.6.Specialprovisionsforemptyuncleanedpackagings,vehicles,containers,tanks,battery-vehiclesandMEGCsForemptymeansofcontainment,uncleaned,thedescriptioninthetransportdocumentshallbe‘EMPTYPACKAGING’,‘EMPTYRECEPTACLE’,‘EMPTYIBC’,‘EMPTYVEHICLE’,‘EMPTYTANK-VEHICLE’,‘EMPTYDEMOUNTABLETANK’,‘EMPTYPORTABLETANK’,‘EMPTYTANK-CONTAINER’,‘EMPTYCONTAINER’,‘EMPTYBATTERY-VEHICLE’,‘EMPTYMEGC’,asappropriate,followedbytheclassnumberandtheletters‘ADRorRID’.Seeexampleasfollows:‘EMPTYPACKAGING,3,ADR’OfficialJournaloftheEuropeanUnionEN26.1.2004L18/732Inthecaseofemptygasreceptacleswithacapacityofmorethan1000litres,emptytank-vehicles,battery-vehicles,demountabletanks,portabletanks,tank-containers,MEGCs,vehiclesandcontainersforcarriageinbulk,uncleaned,thisdescriptionshallbefollowedbythewords‘lastload’togetherwiththeUNnumberandpropershippingnameofthegoodslastloaded.Seeexampleasfollows:‘EMPTYTANK-VEHICLE,2,ADR,LASTLOAD:1017CHLORINE’Ifemptytanks,battery-vehiclesandMEGCs,uncleaned,arecarriedtothenearestplacewherecleaningorrepaircanbecarriedoutinaccordancewiththeprovisionsof4.3.2.4.3or7.5.8.1,thefollowingadditionalentryshallbemadeinthetransportdocument:‘CARRIAGEINACCORDANCEWITH4.3.2.4.3’or‘CARRIAGEINACCORDANCEWITH7.5.8.1’.5.4.1.1.7.SpecialprovisionsforcarriageinatransportchainincludingmaritimeoraircarriageForcarriageinaccordancewith1.1.4.2,astatementshallbeincludedinthetransportdocument,asfollows:‘CARRIAGEINACCORDANCEWITH1.1.4.2’.5.4.1.1.8.SpecialprovisionsforuseofportabletanksapprovedformaritimecarriageForcarriageinaccordancewith1.1.4.3,astatementshallbeincludedinthetransportdocument,asfollows:‘CARRIAGEINACCORDANCEWITH1.1.4.3’.5.4.1.1.9.(Reserved)5.4.1.1.10.Specialprovisionsforexemptionsrelatedtoquantitiescarriedpertransportunit5.4.1.1.10.1.Inthecaseofexemptionsprovidedforin1.1.3.6,thetransportdocumentshallbearthefollowinginscription:‘Loadnotexceedingtheexemptionlimitsprescribedin1.1.3.6.’5.4.1.1.10.2.Whereconsignmentsfrommorethanoneconsignorarecarriedinthesametransportunit,thetransportdocumentsaccompanyingtheseconsignmentsneednotbeartheinscriptionmentionedin5.4.1.1.10.1.5.4.1.1.11.SpecialprovisionsforthecarriageofIBCsafterthedateofexpiryofthelastperiodictestinspectionForcarriageinaccordancewith4.1.2.2,astatementtothiseffectshallbeincludedinthetransportdocument,asfollows:‘CARRIAGEINACCORDANCEWITH4.1.2.2’5.4.1.1.12.(Reserved)5.4.1.1.13.Specialprovisionsforcarriageinmulti-compartmenttank-vehiclesortransportunitswithmorethanonetankWhenbyderogationfrom5.3.2.1.2amulti-compartmenttank-vehicleoratransportunitwithmorethanonetankismarkedinaccordancewith5.3.2.1.3,thesubstancescontainedineachtankorineachcompartmentofatankshallbespecifiedinthetransportdocument.5.4.1.2.Additionalorspecialinformationrequiredforcertainclasses5.4.1.2.1.SpecialprovisionsforClass1(a)Thetransportdocumentshallindicate,inadditiontotherequirementsin5.4.1.1.1(g):—thetotalnetmass,inkg,ofexplosivecontents(1)foreachsubstanceorarticlecoveredbyadescription,—thetotalnetmass,inkg,ofexplosivecontents(1)forallsubstancesandarticlescoveredbythetransportdocument.(b)Formixedpackingoftwodifferentgoods,thedescriptionofthegoodsinthetransportdocumentshallincludetheUNnumbersandnamesprintedincapitalsincolumns1and2ofTableAofChapter3.2ofbothsubstancesorarticles.Ifmorethantwodifferentgoodsarecontainedinthesamepackageinconformitywiththemixedpackingprovisionsgivenin4.1.10specialprovisionsMP1,MP2andMP20toMP24,thetransportdocumentshallindicateunderthedescriptionofthegoodstheUNnumbersofallthesubstancesandarticlescontainedinthepackage,intheform,‘GOODSOFUNNOS...’.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/733(1)Forarticles,‘explosivecontents’meanstheexplosivesubstancecontainedinthearticle.(c)Forthecarriageofsubstancesandarticlesassignedtoann.o.s.entryortheentry‘0190SAMPLES,EXPLOSIVE’orpackedconformingtopackinginstructionP101,acopyofthecompetentauthorityapprovalwiththeconditionsofcarriageshallbeattachedtothetransportdocument.Itshallbeinanofficiallanguageoftheforwardingcountryandalso,ifthatlanguageisnotEnglish,FrenchorGerman,inEnglish,FrenchorGermanunlessagreements,ifany,concludedbetweenthecountriesconcernedinthetransportoperationprovideotherwise.(d)IfpackagescontainingsubstancesandarticlesofcompatibilitygroupsBandDareloadedtogetherinthesamevehicleinaccordancewiththerequirementsof7.5.2.2,theapprovalcertificateoftheprotectivecontainer/separatecompartmentinaccordancewith7.5.2.2,footnote(a)tothetable,shallbeattachedtothetransportdocument.(e)WhenexplosivesubstancesorarticlesarecarriedinpackagingsconformingtopackinginstructionP101,thetransportdocumentshallbeartheinscription‘PACKAGINGAPPROVEDBYTHECOMPETENTAUTHORITYOF...’(see4.1.4.1,packinginstructionP101).NoteThecommercialortechnicalnameofthegoodsmaybeenteredadditionallytothepropershippingnameinthetransportdocument.5.4.1.2.2.AdditionalprovisionsforClass2(a)Forthecarriageofmixtures(see2.2.2.1.1)intanks(demountabletanks,fixedtanks,portabletanks,tank-containersorelementsofbattery-vehiclesorofMEGCs),thecompositionofthemixtureasapercentageofthevolumeorasapercentageofthemassshallbegiven.Constituentsbelow1%neednotbeindicated(seealso3.1.2.6.1.2);(b)forthecarriageofcylinders,tubes,pressuredrums,cryogenicreceptaclesandbundlesofcylindersundertheconditionsof4.1.6.6,thefollowingentryshallbeincludedinthetransportdocument:‘Carriageinaccordancewith4.1.6.6’.5.4.1.2.3.Additionalprovisionsforself-reactivesubstancesofClass4.1andorganicperoxidesofClass5.25.4.1.2.3.1.Forself-reactivesubstancesofClass4.1andfororganicperoxidesofClass5.2thatrequiretemperaturecontrolduringcarriage,thecontrolandemergencytemperaturesshallbeindicatedinthetransportdocument,asfollows:‘Controltemperature:...°CEmergencytemperature:...°C’.5.4.1.2.3.2.Whenforcertainself-reactivesubstancesofClass4.1andcertainorganicperoxidesofClass5.2thecompetentauthorityhaspermittedthelabelconformingtomodelNo1tobedispensedwithforaspecificpackaging(see5.2.2.1.9),astatementtothiseffectshallbeincludedinthetransportdocument,asfollows:‘ThelabelconformingtomodelNo1isnotrequired’.5.4.1.2.3.3.Whenorganicperoxidesandself-reactivesubstancesarecarriedunderconditionswhereapprovalisrequired(fororganicperoxidessee2.2.52.1.8,4.1.7.2.2andspecialprovisionTA2of6.8.4;forself-reactivesubstancessee2.2.41.1.13and4.1.7.2.2,astatementtohiseffectshallbeincludedinthetransportdocument,e.g.‘Carriageinaccordancewith2.2.52.1.8’.Acopyoftheapprovalofthecompetentauthoritywiththeconditionsofcarriageshallbeattachedtothetransportdocument.5.4.1.2.3.4.Whenasampleofanorganicperoxide(see2.2.52.1.9)oraself-reactivesubstance(see2.2.41.1.15)iscarried,astatementtothiseffectshallbeincludedinthetransportdocument,e.g.‘Carriageinaccordancewith2.2.52.1.9’.5.4.1.2.3.5.Whenself-reactivesubstancestypeG(seeManualoftestsandcriteria,PartII,paragraph20.4.2(g))arecarried,thefollowingstatementmaybegiveninthetransportdocument:‘Notaself-reactivesubstanceofClass4.1’.WhenorganicperoxidestypeG(seeManualoftestsandcriteria,PartII,paragraph20.4.3(g))arecarried,thefollowingstatementmaybegiveninthetransportdocument:‘NotasubstanceofClass5.2’.5.4.1.2.4.AdditionalprovisionsforClass6.2(a)Iftheinfectioussubstanceisageneticallymodifiedsubstance,thewords‘GENETICALLYMODIFIEDMICRO-ORGANISMS’shallbeaddedinthetransportdocument;(b)fordiagnosticspecimenswhichareofferedforcarriageundertheconditionsof2.2.62.1.8,thepropershippingnameshallbe:‘DIAGNOSTICSPECIMEN,CONTAINING...’(theinfectioussubstancedeterminingtheclassificationtobeentered);(c)forthecarriageofeasilyperishablesubstances,appropriateinformationshallbeprovided,e.g.‘COOLAT+2/+4°C’or‘CARRYINFROZENSTATE’or‘DONOTFREEZE’.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/7345.4.1.2.5.SpecialprovisionsforClass75.4.1.2.5.1.Theconsignorshallincludeinthetransportdocumentswitheachconsignmentthefollowinginformation,asapplicableintheordergiven:(a)theUNnumberassignedtothematerialprecededbytheletters‘UN’;(b)thepropershippingname;(c)theclassnumber‘7’;(d)thenameorsymbolofeachradionuclideor,formixturesofradionuclides,anappropriategeneraldescriptionoralistofthemostrestrictivenuclides;(e)adescriptionofthephysicalandchemicalformofthematerial,oranotationthatthematerialisspecialformradioactivematerialorlowdispersibleradioactivematerial.Agenericchemicaldescriptionisacceptableforchemicalform;(f)themaximumactivityoftheradioactivecontentsduringcarriageexpressedinbecquerels(Bq)withanappropriateSIprefix(see1.2.2.1).Forfissilematerial,themassoffissilematerialingrams(g),orappropriatemultiplesthereof,maybeusedinplaceofactivity;(g)thecategoryofthepackage,i.e.I-WHITE,II-YELLOW,III-YELLOW;(h)thetransportindex(categoriesII-YELLOWandIII-YELLOWonly);(i)forconsignmentsincludingfissilematerialotherthanconsignmentsexceptedunder6.4.11.2,thecriticalitysafetyindex;(j)theidentificationmarkforeachcompetentauthorityapprovalcertificate(specialformradioactivematerial,lowdispersibleradioactivematerial,specialarrangement,packagedesign,orshipment)applicabletotheconsignment;(k)forconsignmentsofpackagesinanoverpackorcontainer,adetailedstatementofthecontentsofeachpackagewithintheoverpackorcontainerand,whereappropriate,ofeachoverpackorcontainerintheconsignment.Ifpackagesaretoberemovedfromtheoverpackorcontaineratapointofintermediateunloading,appropriatetransportdocumentsshallbemadeavailable;(l)whereaconsignmentisrequiredtobeshippedunderexclusiveuse,thestatement‘EXCLUSIVEUSESHIPMENT’;and(m)forLSA-IIandLSA-IIIsubstances,SCO-IandSCO-II,thetotalactivityoftheconsignmentasamultipleofA2.5.4.1.2.5.2.Theconsignorshallprovideinthetransportdocumentsastatementregardingactions,ifany,thatarerequiredtobetakenbythecarrier.Thestatementshallbeinthelanguagesdeemednecessarybythecarrierortheauthoritiesconcerned,andshallincludeatleastthefollowinginformation:(a)supplementaryrequirementsforloading,stowage,carriage,handlingandunloadingofthepackage,overpackorcontainerincludinganyspecialstowageprovisionsforthesafedissipationofheat(seespecialprovisionCV33(3.2)of7.5.11),orastatementthatnosuchrequirementsarenecessary;(b)restrictionsonthemodeofcarriageorvehicleandanynecessaryroutinginstructions;(c)emergencyarrangementsappropriatetotheconsignment.5.4.1.2.5.3.Theapplicablecompetentauthoritycertificatesneednotnecessarilyaccompanytheconsignment.Theconsignorshallmakethemavailabletothecarrier(s)beforeloadingandunloading.5.4.1.3.(Reserved)5.4.1.4.Formatandlanguage5.4.1.4.1.Thedocumentcontainingtheinformationin5.4.1.1and5.4.1.2maybethatalreadyrequiredbyotherregulationsinforceforcarriagebyanothermodeofcarriage.Incaseofmultipleconsignees,thenameandaddressoftheconsigneesandthequantitiesdeliveredenablingthenatureandquantitiescarriedtobeevaluatedatanytime,maybeenteredinotherdocumentswhicharetobeusedorinanyotherdocumentsmademandatoryaccordingtootherspecificregulationsandwhichshallbeonboardthevehicle.Theparticularstobeenteredinthedocumentshallbedraftedinanofficiallanguageoftheforwardingcountry,andalso,ifthatlanguageisnotEnglish,French,orGerman,inEnglish,FrenchorGerman,unlessinternationalroadcarriagetariffs,ifany,oragreementsconcludedbetweenthecountriesconcernedinthetransportoperation,provideotherwise.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/7355.4.1.4.2.Ifbyreasonofthesizeoftheload,aconsignmentcannotbeloadedinitsentiretyonasingletransportunit,atleastasmanyseparatedocuments,orcopiesofthesingledocument,shallbemadeoutastransportunitsloaded.Furthermore,inallcases,separatetransportdocumentsshallbemadeoutforconsignmentsorpartsofconsignmentswhichmaynotbeloadedtogetheronthesamevehiclebyreasonoftheprohibitionssetforthin7.5.2.Theinformationrelativetothehazardsofthegoodstobecarried(asindicatedin5.4.1.1)maybeincorporatedin,orcombinedwith,anexistingtransportorcargohandlingdocument.Thelayoutoftheinformationinthedocument(ortheorderoftransmissionofthecorrespondingdatabyelectronicdateprocessing(EDP)orelectronicdateinterchange(EDI)techniques)shallbeasprovidedin5.4.1.1.1.Whenanexistingtransportdocumentorcargohandlingdocumentcannotbeusedforthepurposesofdangerousgoodsdocumenta-tionformultimodaltransport,theuseofdocumentscorrespondingtotheexampleshownin5.4.4isconsideredadvisable(1).5.4.1.5.Non-dangerousgoodsWhengoodsmentionedbynameinTableAofChapter3.2,arenotsubjecttothisDirectivebecausetheyareconsideredasnon-dangerousaccordingtoPart2,theconsignormayenterinthetransportdocumentastatementtothateffect,e.g.:‘NotgoodsofClass....’NoteThisprovisionmaybeusedinparticularwhentheconsignorconsidersthat,duetothechemicalnatureofthegoods(e.g.solutionsandmixtures)carriedortothefactthatsuchgoodsaredeemeddangerousforotherregulatorypurposestheconsignmentmightbesubjecttocontrolduringthejourney.5.4.2.ContainerpackingcertificateIfthecarriageofdangerousgoodsinalargecontainerprecedesavoyagebysea,acontainerpackingcertificateconformingtoSection5.4.2oftheIMDGcode(2)shallbeprovidedwiththetransportdocument(3).Thefunctionsofthetransportdocumentrequiredunder5.4.1andofthecontainerpackingcertificateasprovidedabovemaybeincorporatedintoasingledocument;ifnot,thesedocumentsshallbeattachedonetotheother.Ifthesefunctionsareincorporatedintoasingledocument,theinclusioninthetransportdocumentofastatementthattheloadingofthecontainerhasbeencarriedoutinaccordancewiththeapplicablemodalregulationstogetherwiththeidentificationofthepersonresponsibleforthecontainerpackingcertificateshallbesufficient.NoteThecontainerpackingcertificateisnotrequiredforportabletanks,tank-containersandMEGCs.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/736(1)Ifused,therelevantrecommendationsoftheUN/ECEWorkingPartyonFacilitationofInternationalTradeProceduresmaybeconsulted,inparticularRecommendationNo1(UnitedNationsLay-outKeyforTradeDocuments)(ECE/TRADE/137,edition96.1),RecommendationNo11(DocumentaryAspectsoftheInternationalTransportofDangerousGoods)ECE/TRADE/204,edition96.1)andRecommendationNo22(Lay-outKeyforstandardConsignmentInstructions)(ECE/TRADE/168,edition96.1).RefertotheTradedataelementsdirectory,VolumeIII,TradeFacilitationRecommendations(ECE/TRADE/200)(UnitedNationspublicationSalesNoE.96.II.E.13).(2)GuidelinesforuseinpracticeandintrainingforloadinggoodsintransportunitshavealsobeendrawnupbytheInternationalMaritimeOrganisation(IMO),theInternationalLabourOrganisation(ILO)andtheUnitedNationsEconomicCommissionforEurope(UN/ECE)andhavebeenpublishedbyIMO(‘IMO/ILO/UN-ECEGuidelinesforPackingofCargoTransportUnits(CTUs)’).(3)Section5.4.2oftheIMDGcoderequiresthefollowing:‘5.4.2.Container/vehiclepackingcertificate5.4.2.1.Whenpackagescontainingdangerousgoodsarepackedontoorintoanyunit,suchas,freightcontainer,flat,trailerorothervehicleintendedfortransportbysea,thoseresponsibleforthepackingoftheunitshallprovidea“container/vehiclepackingcertificate”specifyingthecontainer/vehicle/unitidentificationnumber(s)andcertifyingthattheoperationhasbeencarriedoutinaccordancewiththefollowingconditions:1.thecargotransportunitwasclean,dryandapparentlyfittoreceivethegoods;2.iftheconsignmentsincludegoodsofClass1,otherthandivision1.4,thecargotransportunitisstructurallyserviceableinconformitywith7.4.10(oftheIMDGcode).3.goods,whichshouldbesegregated,havenotbeenpackedtogetherontoorinthecargotransportunit(unlessapprovedbythecompetentauthorityconcernedinaccordancewith7.2.2.3(oftheIMDGcode);4.allpackageshavebeenexternallyinspectedfordamage,leakageorsifting,andonlysoundpackageshavebeenloaded;5.drumshavebeenstowedinanuprightposition,unlessotherwiseauthorisedbythecompetentauthority;6.allpackageshavebeenproperlypackedontoorinthecargotransportunitandsecured;7.whendangerousgoodsaretransportedinbulkpackagings,thecargohasbeenevenlydistributed;8.thecargotransportunitandthepackagesthereinareproperlymarked,labelled,andplacarded;9.whensolidcarbondioxide(CO2-dryice)isusedforcoolingpurposes,thecargotransportunitisexternallymarkedorlabelledinaconspicuousplace,suchas,atthedoorend,withthewords:“DANGEROUSCO2GAS(DRYICE)INSIDE.VENTILATETHOROUGHLYBEFOREENTERING”;10.thedangerousgoodstransportdocumentrequiredin5.4.1(oftheIMDGcode)hasbeenreceivedforeachdangerousgoodsconsignmentpackedontoorinthecargotransportunit.5.4.2.2.Thefunctionsofthedangerousgoodstransportdocumentrequiredin5.4.1(oftheIMDGCode)andofthecontainer/vehiclepackingcertificaterequiredin5.4.2.1(oftheIMDGCode)maybeincorporatedintoasingledocument;ifnot,thesedocumentsshallbeattachedonetotheother.Ifthesefunctionsareincorporatedintoasingledocument,suchas,adangerousgoodsdeclaration,ashippingnote,etc.,theinclusionofasigneddeclarationphrasesuchas“Itisdeclaredthatthepackingofthegoodsintotheunithasbeencarriedoutinaccordancewiththeprovisionsof5.4.2.1”willsuffice.Thepersonsigningthisdeclarationshallbeidentifiedonthedocument.NoteThecontainerpackingcertificateisnotrequiredforportabletanks,tank-containersandMEGCs.’5.4.3.Instructionsinwriting5.4.3.1.Asaprecautionagainstanyaccidentoremergencythatmayoccurorariseduringcarriage,thedrivershallbegiveninstructionsinwriting,specifyingconciselyforeachdangeroussubstanceorarticlecarriedorforeachgroupofgoodspresentingthesamedangerstowhichthesubstance(s)orarticle(s)carriedbelong(s):(a)thenameofthesubstanceorarticleorgroupofgoods,theclassandtheUNnumberorforagroupofgoodstheUNnumbersofthegoodsforwhichtheseinstructionsareintendedorareapplicable;(b)thenatureofthedangerinherentinthesegoodsaswellasthemeasurestobetakenbythedriverandthepersonalprotectionequipmenttobeusedbythedriver;(c)thegeneralactionstobetaken,e.g.towarntheroadusersandpassers-byandcallthepolice/firebrigade;(d)theadditionalactionstobetakentodealwithminorleakagesorspillagestopreventtheirescalation,ifthiscanbeachievedwithoutpersonalrisk;(e)thespecialactionstobetakenforcertaingoods,ifapplicable;(f)thenecessaryequipmentforgeneraland,ifapplicable,additionaland/orspecialactions.5.4.3.2.Theseinstructionsshallbeprovidedbytheconsignorandshallbehandedouttothedriveratthelatestwhenthedangerousgoodsareloadedonthevehicle.Informationonthecontentoftheinstructionsshallbesuppliedtothecarrieratthelatestwhenthecarriageorderisgiven,soastoenablehimtotakethenecessarystepstoensurethattheemployeesconcernedareawareoftheseinstructionsandarecapableofcarryingthemoutproperlyandtoensurethatthenecessaryequipmentisonboardthevehicle.5.4.3.3.Theconsignorshallberesponsibleforthecontentoftheseinstructions.Theyshallbeprovidedinalanguagethedriver(s)takingoverthedangerousgoodsis(are)abletoreadandtounderstand,andinalllanguagesofthecountriesoforigin,transitanddestination.Inthecaseofcountrieswithmorethanoneofficiallanguage,thecompetentauthorityshallspecifytheofficiallanguageorlanguagesapplicablethroughouttheterritoryorineachregionorpartoftheterritory.5.4.3.4.Theseinstructionsshallbekeptreadilyidentifiableinthedriver'scab.5.4.3.5.Instructionsinwritingaccordingtothissectionwhicharenotapplicabletothegoodswhichareonboardofthevehicle,shallbekeptseparatefrompertinentdocumentsinsuchawayastopreventconfusion.5.4.3.6.Thecarriershallensurethatthedriversconcernedunderstandandarecapableofcarryingouttheseinstructionsproperly.5.4.3.7.Incaseofmixedloadsofpackagedgoodsincludingdangerousgoodswhichbelongtodifferentgroupsofgoodspresentingthesamedangers,theinstructionsinwritingmayberestrictedtooneinstructionperclassofdangerousgoodscarriedonboardofthevehicle.Insuchcasenonameofgoods,orUNnumberhastobementionedintheinstructions.5.4.3.8.Theseinstructionsshallbedraftedaccordingtothefollowingformat:LOAD—Mentionofthepropershippingnameofthesubstanceorarticle,orthenameofthegroupofgoodspresentingthesamedangers,theclassandtheUNnumberorforagroupofgoodstheUNnumbersofthegoodsforwhichtheseinstructionsareintendedorareapplicable,—descriptionshallberestrictedtoe.g.thephysicalstatewithindicationofanycolourandmentionofanyodour,toaididentificationofleakagesorspillages.NATUREOFDANGERShortenumerationofdangers:—maindanger,—additionaldangersincludingpossibledelayedeffectsanddangersfortheenvironment,—behaviourunderfireorheating(decomposition,explosion,developmentoftoxicfumes,etc.),—ifapplicable,itshallbementionedherethatthegoodscarriedreactdangerouslywithwater.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/737PERSONALPROTECTIONMentionofthepersonalprotectionintendedforthedriverinaccordancewiththerequirementsof8.1.5.GENERALACTIONSTOBETAKENBYDRIVERMentionofthefollowinginstructions:—stoptheengine,—nonakedlights.Nosmoking,—markroadsandwarnotherroadusersorpassers-by,—informthepublicaboutthehazardandgiveadvicetokeepupwind,—notifypoliceandfirebrigadeassoonaspossible.ADDITIONALAND/ORSPECIALACTIONSTOBETAKENBYTHEDRIVERAppropriateinstructionsshallbeincludedhereaswellasthelistofequipmentnecessaryforthedrivertoperformtheadditionaland/orspecialactionsaccordingtotheclass(es)ofthegoodsbeingcarried(e.g.shovel,collectingcontainer,etc.).Itisconsideredthatdriversofvehiclesshouldbeinstructedandtrainedtotakeadditionalactionswithminorleakagesorspillagestopreventtheirescalation,providedthatthiscanbeachievedwithoutpersonalrisk.Itisconsideredthatanyspecialactionrecommendedbytheconsignorrequiresaspecialtrainingofthedriver.Ifapplicable,appropriateinstructionsshallbeincludedhereaswellasthelistofequipmentneededforthesespecialactions.FIREInformationforthedriverincaseoffire:driversshouldbeinstructedduringtrainingtodealwithminorvehiclefires.Theyshallnotattempttodealwithanyfireinvolvingtheload.FIRSTAIDInformationforthedriverincaseofcontactwiththecarriedgood(s).ADDITIONALINFORMATION5.4.4.ExampleofamultimodaldangerousgoodsformExampleofaformwhichmaybeusedasacombineddangerousgoodsdeclarationandcontainerpackingcertificateformultimodalcarriageofdangerousgoods.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/738OfficialJournaloftheEuropeanUnionEN26.1.2004L18/739OfficialJournaloftheEuropeanUnionEN26.1.2004L18/740CHAPTER5.5Specialprovisions5.5.1.Specialprovisionsfortheconsignmentofinfectioussubstancesinriskgroups3and45.5.1.1.Unlessaninfectioussubstancecannotbeconsignedbyanyothermeans,livevertebrateorinvertebrateanimalsshallnotbeusedtoconsignsuchasubstance.Suchanimalsshallbepacked,marked,indicated,andcarriedinaccordancewiththerelevantregulationsgoverningthecarriageofanimals(1).5.5.1.2.Thetransportofinfectioussubstancesrequirescoordinatedactionbytheconsignor,thecarrierandtheconsigneetoensuresafetyandarrivalontimeandinpropercondition.Tothisend,thefollowingmeasuresshallbetaken:(a)advancearrangementsbetweenconsignor,carrierandconsignee:dispatchofinfectioussubstancesshallnottakeplacebeforeadvancearrangementshavebeenmadebetweenconsignor,carrierandconsigneeorbeforetheconsigneehasconfirmedwithhiscompetentauthoritiesthatthesubstancescanlegallybeimportedandthatnodelaywillbeincurredinthedeliveryoftheconsignmenttoitsdestination;(b)preparationofdispatchdocuments:inordertosecuretransmissionwithouthindranceitisnecessarytopreparealldispatchdocuments,includingthetransportdocument(seeChapter5.4),instrictaccordancewithrulesgoverningtheacceptanceofthegoodstobedispatched;(c)routing:transportshallbebythequickestpossiblerouting.Iftranshipmentisnecessary,precautionsshallbetakentoensurespecialcare,expeditioushandlingandmonitoringofthesubstancesintransit;(d)timelynotificationofalltransportdatabyconsignortoconsignee:theconsignorshallnotifytheconsigneeinadvanceoftransportdetails,suchas:meansoftransport,transportdocumentnumberanddateandhourofexpectedarrivalatthepointofdestination,sothattheconsignmentcanbecollectedpromptly.Themostrapidmeansofcommunicationshallbeusedforthisnotification.5.5.1.3.Deadanimalswhichareknownorreasonablybelievedtocontainaninfectioussubstanceshallbepacked,marked,labelledandcarriedinaccordancewiththeconditions(2)specifiedbythecompetentauthorityofthecountryoforigin(3).5.5.2.Specialprovisionsforfumigatedcontainersandvehicles5.5.2.1.Transportdocumentsassociatedwithcontainersandvehiclesthathavebeenfumigatedshallshowthedateoffumigationandthetypeandamountofthefumigantused.Theseparticularsshallbedraftedinanofficiallanguageoftheforwardingcountryandalso,ifthelanguageisnotEnglish,FrenchorGerman,inEnglish,FrenchorGerman,unlessagreements,ifany,concludedbetweenthecountriesconcernedinthetransportoperationprovideotherwise.Inaddition,instructionsfordisposalofanyresidualfumigantincludingfumigationdevices(ifused)shallbeprovided.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/741(1)Regulationsgoverningthecarriageofliveanimalsarecontainedin,e.g.Directive91/628/EECof19November1991ontheprotectionofanimalsduringtransport(OJL340,11.12.1991,p.17)andintheRecommendationsoftheCouncilofEurope(MinisterialCommittee)onthecarriageofcertainanimalspecies.(2)SuchRegulationsarecontainede.g.intheCouncilDirective90/667/EECof27.11.1990,layingdowntheveterinaryrulesforthedisposalandprocessingofanimalwaste,foritsplacingonthemarketandforthepreventionofpathogensinfeedstuffsofanimalorfishoriginandamendingDirective90/425/EEC(OJL363,27.12.1990,p.51).(3)IfthecountryoforiginisnotaMemberState,thecompetentauthorityofthefirstMemberStatereachedbytheconsignment.5.5.2.2.Awarningsignasspecifiedinthefigurebelowshallbeplacedoneachfumigatedcontainerorvehicleinalocationwhereitwillbeeasilyseenbypersonsattemptingtoentertheinteriorofcontainerorvehicle.Theparticularsconcerningthewarningsignshallbedraftedinalanguageconsideredappropriatebytheconsignor.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/742PART6REQUIREMENTSFORTHECONSTRUCTIONANDTESTINGOFPACKAGINGS,INTERMEDIATEBULKCONTAINERS(IBCS),LARGEPACKAGINGSANDTANKSCHAPTER6.1Requirementsfortheconstructionandtestingofpackagings6.1.1.General6.1.1.1.Therequirementsofthischapterdonotapplyto:(a)packagescontainingradioactivematerialofClass7,unlessotherwiseprovided(see4.1.9);(b)packagescontaininginfectioussubstancesofClass6.2,unlessotherwiseprovided(seeChapter6.3,noteandpackinginstructionP621of4.1.4.1);(c)receptaclescontaininggasesofClass2;(d)packageswhosenetmassexceeds400kg;(e)packagingswithacapacityexceeding450litres.6.1.1.2.Therequirementsforpackagingsin6.1.4arebasedonpackagingscurrentlyused.Inordertotakeintoaccountprogressinscienceandtechnology,thereisnoobjectiontotheuseofpackagingshavingspecificationsdifferentfromthosein6.1.4,providedthattheyareequallyeffective,acceptabletothecompetentauthorityandablesuccessfullytowithstandthetestsdescribedin6.1.1.3and6.1.5.Methodsoftestingotherthanthosedescribedinthischapterareacceptable,providedtheyareequivalent,andarerecognisedbythecompetentauthority.6.1.1.3.Everypackagingintendedtocontainliquidsshallsuccessfullyundergoasuitableleakproofnesstest,andbecapableofmeetingtheappropriatetestlevelindicatedin6.1.5.4.3:(a)beforeitisfirstusedforcarriage;(b)afterremanufacturingorreconditioning,beforeitisreusedforcarriage;Forthistest,packagingsneednothavetheirownclosuresfitted.Theinnerreceptacleofcompositepackagingsmaybetestedwithouttheouterpackagingprovidedthetestresultsarenotaffected.Thistestisnotnecessaryfor:—innerpackagingsofcombinationpackagings,—innerreceptaclesofcompositepackagings(glass,porcelainorstoneware),markedwiththesymbol‘RID/ADR’accordingto6.1.3.1(a)(ii),—lightgaugemetalpackagings,markedwiththesymbol‘RID/ADR’accordingto6.1.3.1(a)(ii).6.1.1.4.Packagingsshallbemanufacturedandtestedunderaqualityassuranceprogrammewhichsatisfiesthecompetentauthorityinordertoensurethateachmanufacturedpackagingmeetstherequirementsofthischapter.6.1.2.Codefordesignatingtypesofpackagings6.1.2.1.Thecodeconsistsof:(a)anArabicnumeralindicatingthekindofpackaging,e.g.drum,jerrican,etc.,followedby:(b)acapitalletter(s)inLatincharactersindicatingthenatureofthematerial,e.g.steel,wood,etc.,followedwherenecessaryby:(c)anArabicnumeralindicatingthecategoryofpackagingwithinthekindtowhichthepackagingbelongs.6.1.2.2.Inthecaseofcompositepackagings,twocapitallettersinLatincharactersareusedinsequenceinthesecondpositionofthecode.Thefirstindicatesthematerialoftheinnerreceptacleandthesecondthatoftheouterpackaging.6.1.2.3.Inthecaseofcombinationpackagingsandinfectioussubstancespackagingsmarkedinaccordancewith6.3.1.1,onlythecodenumberfortheouterpackagingisused.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/7436.1.2.4.Theletters‘T’,‘V’or‘W’mayfollowthepackagingcode.Theletter‘T’signifiesasalvagepackagingconformingtotherequirementsof6.1.5.1.11.Theletter‘V’signifiesaspecialpackagingconformingtotherequirementsof6.1.5.1.7.Theletter‘W’signifiesthatthepackaging,althoughofthesametypeindicatedbythecode,ismanufacturedtoaspecificationdifferenttothatin6.1.4andisconsideredequivalentundertherequirementsof6.1.1.2.6.1.2.5.Thefollowingnumeralsshallbeusedforthekindsofpackaging:1.Drum2.Woodenbarrel3.Jerrican4.Box5.Bag6.Compositepackaging7.(reserved)0.Lightgaugemetalpackagings6.1.2.6.Thefollowingcapitallettersshallbeusedforthetypesofmaterial:A.Steel(alltypesandsurfacetreatments)B.AluminiumC.NaturalwoodD.PlywoodF.ReconstitutedwoodG.FibreboardH.PlasticsmaterialL.TextileM.Paper,multiwallN.Metal(otherthansteeloraluminium)P.Glass,porcelainorstoneware6.1.2.7.Thefollowingtableindicatesthecodestobeusedfordesignatingtypesofpackagingsdependingonthekindofpackagings,thematerialusedfortheirconstructionandtheircategory;italsoreferstothesubsectionstobeconsultedfortheappropriaterequirements:KindMaterialCategoryCodeSubsection1.DrumsA.Steelnon-removablehead1A16.1.4.1removablehead1A2B.Aluminiumnon-removablehead1B16.1.4.2removablehead1B2D.Plywood1D6.1.4.5G.Fibre1G6.1.4.7.H.Plasticsnon-removablehead1H16.1.4.8removablehead1H2N.Metal,otherthansteeloraluminiumnon-removablehead1N16.1.4.3removablehead1N2OfficialJournaloftheEuropeanUnionEN26.1.2004L18/744KindMaterialCategoryCodeSubsection2.BarrelsC.Woodenbungtype2C16.1.4.6removablehead2C23.JerricansA.Steelnon-removablehead3A16.1.4.4removablehead3A2B.Aluminiumnon-removablehead3B16.1.4.4removablehead3B2H.Plasticsnon-removablehead3H16.1.4.8removablehead3H24.BoxesA.Steel4A6.1.4.14B.Aluminium4B6.1.4.14C.Naturalwoodordinary4C16.1.4.9withsift-proofwalls4C2D.Plywood4D6.1.4.10F.Reconstitutedwood4F6.1.4.11G.Fibreboard4G6.1.4.12H.Plasticsexpanded4H16.1.4.13solid4H25.BagsH.Wovenplasticswithoutinnerlinerorcoating5H16.1.4.16sift-proof5H2waterresistant5H3H.Plasticsfilm5H46.1.4.17L.Textilewithoutinnerlinerorcoating5L16.1.4.15sift-proof5L2waterresistant5L3M.Papermultiwall5M16.1.4.18multiwall,waterresis-tant5M2OfficialJournaloftheEuropeanUnionEN26.1.2004L18/745KindMaterialCategoryCodeSubsection6.CompositepackagingsH.Plasticsreceptaclewithoutersteeldrum6HA16.1.4.19withoutersteelcrateorbox6HA26.1.4.19withouteraluminiumdrum6HB16.1.4.19withouteraluminiumcrateorbox6HB26.1.4.19withouterwoodenbox6HC6.1.4.19withouterplywooddrum6HD16.1.4.19withouterplywoodbox6HD26.1.4.19withouterfibredrum6HG16.1.4.19withouterfibreboardbox6HG26.1.4.19withouterplasticsdrum6HH16.1.4.19withoutersolidplasticsbox6HH26.1.4.19P.Glass,porcelainorstonewarereceptaclewithoutersteeldrum6PA16.1.4.20withoutersteelcrateorbox6PA26.1.4.20withouteraluminiumdrum6PB16.1.4.20withouteraluminiumcrateorbox6PB26.1.4.20withouterwoodenbox6PC6.1.4.20withouterplywooddrum6PD16.1.4.20withouterwickerworkhamper6PD26.1.4.20withouterfibredrum6PG16.1.4.20withouterfibreboardbox6PG26.1.4.20withouterexpandedplasticspackaging6PH16.1.4.20withoutersolidplasticspackaging6PH26.1.4.20OfficialJournaloftheEuropeanUnionEN26.1.2004L18/746KindMaterialCategoryCodeSubsection0.LightgaugemetalpackagingsA.Steelnon-removablehead0A16.1.4.22removablehead0A26.1.3.MarkingNOTES1.Themarkingindicatesthatthepackagingwhichbearsitcorrespondstoasuccessfullytesteddesigntypeandthatitcomplieswiththerequirementsofthischapterwhicharerelatedtothemanufacture,butnottotheuse,ofthepackaging.Initself,therefore,themarkdoesnotnecessarilyconfirmthatthepackagingmaybeusedforanysubstance:generallythetypeofpackaging(e.g.steeldrum),itsmaximumcapacityand/ormass,andanyspecialrequirementsarespecifiedforeachsubstanceinTableAofChapter3.2.2.Themarkingisintendedtobeofassistancetopackagingmanufacturers,reconditioners,packagingusers,carriersandregulatoryauthorities.Inrelationtotheuseofanewpackaging,theoriginalmarkingisameansforitsmanufacturer(s)toidentifythetypeandtoindicatethoseperformancetestregulationsthathavebeenmet.3.Themarkingdoesnotalwaysprovidefulldetailsofthetestlevels,etc.,andthesemayneedtobetakenfurtherintoaccount,e.g.byreferencetoatestcertificate,totestreportsortoaregisterofsuccessfullytestedpackagings.Forexample,apackaginghavingan‘X’or‘Y’markingmaybeusedforsubstancestowhichapackinggrouphavingalesserdegreeofdangerhasbeenassignedwiththerelevantmaximumpermissiblevalueoftherelativedensity(1)determinedbytakingintoaccountthefactor1,5or2,25indicatedinthepackagingtestrequirementsin6.1.5asappropriate,i.e.GroupIpackagingtestedforproductsofrelativedensity1,2couldbeusedasaGroupIIpackagingforproductsofrelativedensity1,8oraGroupIIIpackagingforproductsofrelativedensity2,7,providedofcoursethatalltheperformancecriteriacanstillbemetwiththehigherrelativedensityproduct.6.1.3.1.EachpackagingintendedforuseaccordingtothisDirectiveshallbearmarkingswhicharedurable,legibleandplacedinalocationandofsuchasizerelativetothepackagingastobereadilyvisible.Forpackageswithagrossmassofmorethan30kg,themarkingsoraduplicatethereofshallappearonthetoporonasideofthepackaging.Letters,numeralsandsymbolsshallbeatleast12mmhigh,exceptforpackagingsof30litresor30kgcapacityorless,whentheyshallbeatleast6mminheightandforpackagingsof5litresor5kgorlesswhentheyshallbeofanappropriatesize.Themarkingshallshow:a)(i)TheUnitedNationspackagingsymbolThisshallnotbeusedforanypurposeotherthancertifyingthatapackagingcomplieswiththerelevantrequirementsinthischapter.Forembossedmetalpackagingsthecapitalletters‘UN’maybeappliedinsteadofthesymbol;or(ii)thesymbol‘RID/ADR’forpackagingsapprovedforrailtransportaswellasroadtransport.Forcompositepackagings(glass,porcelainorstoneware)andlightgaugemetalpackagings,conformingtosimplifiedconditions(see6.1.1.3,6.1.5.3.1(e),6.1.5.3.4(c),6.1.5.4,6.1.5.5.1and6.1.5.6);(b)thecodedesignatingthetypeofpackagingaccordingto6.1.2;(c)acodeintwoparts:(i)aletterdesignatingthepackinggroup(s)forwhichthedesigntypehasbeensuccessfullytested:XforpackinggroupsI,IIandIII;YforpackinggroupsIIandIII;ZforpackinggroupIIIonly;(ii)therelativedensity,roundedofftothefirstdecimal,forwhichthedesigntypehasbeentestedforpackagingswithoutinnerpackagingsintendedtocontainliquids;thismaybeomittedwhentherelativedensitydoesnotexceed1,2.Forpackagingsintendedtocontainsolidsorinnerpackagings,themaximumgrossmassinkilograms.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/747(1)Relativedensity(d)isconsideredtobesynonymouswithspecificgravity(SG)andisusedthroughoutthistext.Forlight-gaugemetalpackagings,markedwiththesymbol‘RID/ADR’accordingto6.1.3.1(a)(ii)intendedtocontainliquidshavingaviscosityat23°Cexceeding200mm2/s,themaximumgrossmassinkg;(d)eithertheletter‘S’denotingthatthepackagingisintendedforthecarriageofsolidsorinnerpackagingsor,forpackagings(otherthancombinationpackagings)intendedtocontainliquids,thehydraulictestpressurewhichthepackagingwasshowntowithstandinkParoundeddowntothenearest10kPa.Forlight-gaugemetalpackagings,markedwiththesymbol‘RID/ADR’,accordingto6.1.3.1(a)(ii)intendedtocontainliquidshavingaviscosityat23°Cexceeding200mm2/s,theletter‘S’.NOTETherequirementsofsubparagraph(d)donotapplytopackagingsintendedforthecarriageofsubstancesclassifiedunderUNNo2814or2900ofClass6.2.(e)thelasttwodigitsoftheyearduringwhichthepackagingwasmanufactured.PackagingsoftypeslHand3Hshallalsobeappropriatelymarkedwiththemonthofmanufacture;thismaybemarkedonthepackaginginadifferentplacefromtheremainderofthemarking.Anappropriatemethodis:(f)theStateauthorisingtheallocationofthemark,indicatedbythedistinguishingsignformotorvehiclesininternationaltraffic(1);(g)thenameofthemanufacturerorotheridentificationofthepackagingspecifiedbythecompetentauthority.6.1.3.2.Everyreusablepackagingliabletoundergoareconditioningprocesswhichmightobliteratethepackagingmarkingsshallbearthemarksindicatedin6.1.3.1(a)to(e)inapermanentform.Marksarepermanentiftheyareabletowithstandthereconditioningprocess(e.g.embossed).Forpackagingsotherthanmetaldrumsofacapacitygreaterthan100litres,thesepermanentmarksmayreplacethecorrespondingdurablemarkingsprescribedin6.1.3.1.6.1.3.2.1.Inadditiontothedurablemarkingsprescribedin6.1.3.1,everynewmetaldrumofacapacitygreaterthan100litresshallbearthemarksdescribedin6.1.3.1(a)to(e)onthebottom,withanindicationofthenominalthicknessofatleastthemetalusedinthebody(inmm,to0,1mm),inpermanentform(e.g.embossed).Whenthenominalthicknessofeitherheadofametaldrumisthinnerthanthatofthebody,thenominalthicknessofthetophead,body,andbottomheadshallbemarkedonthebottominpermanentform(e.g.embossed),forexample‘1,0-1,2-1,0’or‘0,9-1,0-1,0’.NominalthicknessofmetalshallbedeterminedaccordingtotheappropriateISOstandard,forexampleISO3574:1999forsteel.Themarksindicatedin6.1.3.1(f)and(g)shallnotbeappliedinapermanentformexceptasprovidedin6.1.3.2.3.6.1.3.2.2.Forremanufacturedmetaldrums,ifthereisnochangetothepackagingtypeandnoreplacementorremovalofintegralstructuralcomponents,therequiredmarkingsneednotbepermanent.Everyotherremanufacturedmetaldrumshallbearthemarkingsin6.1.3.1(a)to(e)inapermanentform(e.g.embossed)onthetopheadorside.6.1.3.2.3.Metaldrumsmadefrommaterials(e.g.stainlesssteel)designedtobereusedrepeatedlymaybearthemarkingsindicatedin6.1.3.1(f)and(g)inapermanentform(e.g.embossed).6.1.3.2.4.Themarkinginaccordancewith6.1.3.1isvalidforonlyonedesigntypeorseriesofdesigntypes.Differentsurfacetreatmentsmayfallwithinthesamedesigntype.A‘seriesofdesigntypes’meanspackagingsofthesamestructuraldesign,wallthickness,materialandcross-section,whichdifferonlyintheirlesserdesignheightsfromthedesigntypeapproved.Theclosuresofreceptaclesshallbeidentifiableasthosereferredtointhetestreport.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/748(1)DistinguishingsignformotorvehiclesininternationaltrafficprescribedinViennaConventiononRoadTraffic(1968).6.1.3.3.Markingshallbeappliedinthesequenceofthesubparagraphsin6.1.3.1;forexamples,see6.1.3.7.Anyadditionalmarkingsauthorisedbyacompetentauthorityshallstillenablethepartsofthemarktobecorrectlyidentifiedwithreferenceto6.1.3.1.6.1.3.4.Afterreconditioningapackaging,thereconditionershallapplytoitadurablemarkingshowing,inthefollowingsequence:(h)theStateinwhichthereconditioningwascarriedout,indicatedbythedistinguishingsignformotorvehiclesininternationaltraffic(1);(i)thenameorauthorisedsymbolofthereconditioner;(j)theyearofreconditioning;theletter‘R’;and,foreverypackagingsuccessfullypassingtheleakproofnesstestin6.1.1.3,theadditionalletter‘L’.6.1.3.5.When,afterreconditioning,themarkingsrequiredby6.1.3.1(a)to(d)nolongerappearonthetopheadorthesideofametaldrum,thereconditioneralsoshallapplytheminadurableformfollowedby6.1.3.4(h),(i)and(j).Thesemarkingsshallnotidentifyagreaterperformancecapabilitythanthatforwhichtheoriginaldesigntypehadbeentestedandmarked.6.1.3.6.Packagingsmanufacturedwithrecycledplasticsmaterialasdefinedin1.2.1shallbemarked‘REC’.Thismarkshallbeplacednearthemarkprescribedin6.1.3.1.6.1.3.7.ExamplesofmarkingsforNEWpackagings4G/Y145/S/83asin6.1.3.1(a)(i),(b),(c),(d)and(e)ForanewfibreboardboxNL/VL823asin6.1.3.1(f)and(g)1A1/Y1.4/150/83asin6.1.3.1(a)(i),(b),(c),(d)and(e)ForanewsteeldrumtocontainliquidsNL/VL824asin6.1.3.1(f)and(g)1A2/Y150/S/83asin6.1.3.1(a)(i),(b),(c),(d)and(e)Foranewsteeldrumtocontainsolids,orinnerpackagingsNL/VL825asin6.1.3.1(f)and(g)4HW/Y136/S/83asin6.1.3.1(a)(i),(b),(c),(d)and(e)Foranewplasticsboxofequivalentspecifi-cationNL/VL826asin6.1.3.1(f)and(g)lA2/Y/100/91asin6.1.3.1(a)(i),(b),(c),(d)and(e)ForaremanufacturedsteeldrumtocontainliquidsUSA/MM5asin6.1.3.1(f)and(g)RID/ADR/0A1/100/83asin6.1.3.1(a)(ii),(b),(c),(d)and(e)Foranewlightgaugemetalpackaging,non-removableheadNL/VL/123asin6.1.3.1(f)and(g)RID/ADR/0A2/Y20/S/83asin6.1.3.1(a)(ii),(b),(c),(d)and(e)Foranewlightgaugemetalpackaging,removablehead,intendedtocontainsolids,orliquidswithaviscosityat23°Cexceeding200mm2/s.NL/VL/124asin6.1.3.1(f)and(g)OfficialJournaloftheEuropeanUnionEN26.1.2004L18/749(1)DistinguishingsignformotorvehiclesininternationaltrafficprescribedinViennaConventiononRoadTraffic(1968).6.1.3.8.ExamplesofmarkingsforRECONDITIONEDpackagings1A1/Y1.4/150/83asin6.1.3.1(a)(i),(b),(c),(d)and(e)NL/RB/85/RLasin6.1.3.4(h),(i)and(j)1A2/Y150/S/83asin6.1.3.1(a)(i),(b),(c),(d)and(e)USA/RB/85Rasin6.1.3.4(h),(i)and(j)6.1.3.9.ExampleofmarkingforSALVAGEpackagings1A2T/Y/300/94asin6.1.3.1(a)(i),(b),(c),(d)and(e)USA/abcasin6.1.3.1(f)and(g)NOTEThemarkings,forwhichexamplesaregivenin6.1.3.7,6.1.3.8and6.1.3.9maybeappliedinasinglelineorinmultiplelinesprovidedthecorrectsequenceisrespected.6.1.3.10.CertificationByaffixingmarkinginaccordancewith6.1.3.1,itiscertifiedthatmass-producedpackagingscorrespondtotheapproveddesigntypeandthattherequirementsreferredtointheapprovalhavebeenmet.6.1.4.Requirementsforpackagings6.1.4.1.Steeldrums1A1non-removablehead1A2removablehead6.1.4.1.1.Bodyandheadsshallbeconstructedofsteelsheetofasuitabletypeandofadequatethicknessinrelationtothecapacityofthedrumandtoitsintendeduse.6.1.4.1.2.Bodyseamsshallbeweldedondrumsintendedtocontainmorethan40litresofliquid.Bodyseamsshallbemechanicallyseamedorweldedondrumsintendedtocontainsolidsor40litresorlessofliquids.6.1.4.1.3.Chimesshallbemechanicallyseamedorwelded.Separatereinforcingringsmaybeapplied.6.1.4.1.4.Thebodyofadrumofacapacitygreaterthan60litresshall,ingeneral,haveatleasttwoexpandedrollinghoopsor,alternatively,atleasttwoseparaterollinghoops.Ifthereareseparaterollinghoopstheyshallbefittedtightlyonthebodyandsosecuredthattheycannotshift.Rollinghoopsshallnotbespotwelded.6.1.4.1.5.Openingsforfilling,emptyingandventinginthebodiesorheadsofnon-removablehead(1A1)drumsshallnotexceed7cmindiameter.Drumswithlargeropeningsareconsideredtobeoftheremovableheadtype(1A2).Closuresforopeningsinthebodiesandheadsofdrumsshallbesodesignedandappliedthattheywillremainsecureandleakproofundernormalconditionsofcarriage.Closureflangesmaybemechanicallyseamedorweldedinplace.Gasketsorothersealingelementsshallbeusedwithclosures,unlesstheclosureisinherentlyleakproof.6.1.4.1.6.Closuredevicesforremovablehead(1A2)drumsshallbesodesignedandappliedthattheywillremainsecureanddrumswillremainleakproofundernormalconditionsofcarriage.Gasketsorothersealingelementsshallbeusedwithallremovableheads.6.1.4.1.7.Ifmaterialsusedforbody,heads,closuresandfittingsarenotinthemselvescompatiblewiththecontentstobecarried,suitableinternalprotectivecoatingsortreatmentsshallbeapplied.Thesecoatingsortreatmentsshallretaintheirprotectivepropertiesundernormalconditionsofcarriage.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/7506.1.4.1.8.Maximumcapacityofdrum:450litres.6.1.4.1.9.Maximumnetmass:400kg.6.1.4.2.Aluminiumdrums1B1non-removablehead1B2removablehead6.1.4.2.1.Bodyandheadsshallbeconstructedofaluminiumatleast99%pureorofanaluminiumbasealloy.Materialshallbeofasuitabletypeandofadequatethicknessinrelationtothecapacityofthedrumandtoitsintendeduse.6.1.4.2.2.Allseamsshallbewelded.Chimeseams,ifany,shallbereinforcedbytheapplicationofseparatereinforcingrings.6.1.4.2.3.Thebodyofadrumofacapacitygreaterthan60litresshall,ingeneral,haveatleasttwoexpandedrollinghoopsor,alternatively,atleasttwoseparaterollinghoops.Ifthereareseparaterollinghoopstheyshallbefittedtightlyonthebodyandsosecuredthattheycannotshift.Rollinghoopsshallnotbespotwelded.6.1.4.2.4.Openingsforfilling,emptyingandventinginthebodiesorheadsofnon-removablehead(1B1)drumsshallnotexceed7cmindiameter.Drumswithlargeropeningsareconsideredtobeoftheremovableheadtype(1B2).Closuresforopeningsinthebodiesandheadsofdrumsshallbesodesignedandappliedthattheywillremainsecureandleakproofundernormalconditionsofcarriage.Closureflangesshallbeweldedinplacesothattheweldprovidesaleakproofseam.Gasketsorothersealingelementsshallbeusedwithclosures,unlesstheclosureisinherentlyleakproof.6.1.4.2.5.Closuredevicesforremovablehead(1B2)drumsshallbesodesignedandappliedthattheywillremainsecureanddrumswillremainleakproofundernormalconditionsofcarriage.Gasketsorothersealingelementsshallbeusedwithallremovableheads.6.1.4.2.6.Maximumcapacityofdrum:450litres.6.1.4.2.7.Maximumnetmass:400kg.6.1.4.3.Drumsofmetalotherthanaluminiumorsteel1N1non-removablehead1N2removablehead6.1.4.3.1.Thebodyandheadsshallbeconstructedofametalorofametalalloyotherthansteeloraluminium.Materialshallbeofasuitabletypeandofadequatethicknessinrelationtothecapacityofthedrumandtoitsintendeduse.6.1.4.3.2.Chimeseams,ifany,shallbereinforcedbytheapplicationofseparatereinforcingrings.Allseams,ifany,shallbejoined(welded,soldered,etc.)inaccordancewiththetechnicalstateoftheartfortheusedmetalormetalalloy.6.1.4.3.3.Thebodyofadrumofacapacitygreaterthan60litresshall,ingeneral,haveatleasttwoexpandedrollinghoopsor,alternatively,atleasttwoseparaterollinghoops.Ifthereareseparaterollinghoopstheyshallbefittedtightlyonthebodyandsosecuredthattheycannotshift.Rollinghoopsshallnotbespotwelded.6.1.4.3.4.Openingsforfilling,emptyingandventinginthebodiesorheadsofnon-removablehead(1N1)drumsshallnotexceed7cmindiameter.Drumswithlargeropeningsareconsideredtobeoftheremovableheadtype(1N2).Closuresforopeningsinthebodiesandheadsofdrumsshallbesodesignedandappliedthattheywillremainsecureandleakproofundernormalconditionsofcarriage.Closureflangesshallbejoinedinplace(welded,soldered,etc.)inaccordancewiththetechnicalstateoftheartfortheusedmetalormetalalloysothattheseamjoinisleakproof.Gasketsorothersealingelementsshallbeusedwithclosures,unlesstheclosureisinherentlyleakproof.6.1.4.3.5.Closuredevicesforremovablehead(1N2)drumsshallbesodesignedandappliedthattheywillremainsecureanddrumswillremainleakproofundernormalconditionsofcarriage.Gasketsorothersealingelementsshallbeusedwithallremovableheads.6.1.4.3.6.Maximumcapacityofdrum:450litres.6.1.4.3.7.Maximumnetmass:400kg.6.1.4.4.Steeloraluminiumjerricans3A1steel,non-removablehead3A2steel,removableheadOfficialJournaloftheEuropeanUnionEN26.1.2004L18/7513B1aluminium,non-removablehead3B2aluminium,removablehead6.1.4.4.1.Bodyandheadsshallbeconstructedofsteelsheet,ofaluminiumatleast99%pureorofanaluminiumbasealloy.Materialshallbeofasuitabletypeandofadequatethicknessinrelationtothecapacityofthejerricanandtoitsintendeduse.6.1.4.4.2.Chimesofsteeljerricansshallbemechanicallyseamedorwelded.Bodyseamsofsteeljerricansintendedtocontainmorethan40litresofliquidshallbewelded.Bodyseamsofsteeljerricansintendedtocontain40litresorlessshallbemechanicallyseamedorwelded.Foraluminiumjerricans,allseamsshallbewelded.Chimeseams,ifany,shallbereinforcedbytheapplicationofaseparatereinforcingring.6.1.4.4.3.Openingsinnon-removableheadjerricans(3A1and3B1)shallnotexceed7cmindiameter.Jerricanswithlargeropeningsareconsideredtobeoftheremovableheadtype(3A2and3B2).Closuresshallbesodesignedthattheywillremainsecureandleakproofundernormalconditionsofcarriage.Gasketsorothersealingelementsshallbeusedwithclosures,unlesstheclosureisinherentlyleakproof.6.1.4.4.4.Ifmaterialsusedforbody,heads,closuresandfittingsarenotinthemselvescompatiblewiththecontentstobecarried,suitableinternalprotectivecoatingsortreatmentsshallbeapplied.Thesecoatingsortreatmentsshallretaintheirprotectivepropertiesundernormalconditionsofcarriage.6.1.4.4.5.Maximumcapacityofjerrican:60litres.6.1.4.4.6.Maximumnetmass:120kg.6.1.4.5.Plywooddrums1D6.1.4.5.1.Thewoodusedshallbewellseasoned,commerciallydryandfreefromanydefectlikelytolessentheeffectivenessofthedrumforthepurposeintended.Ifamaterialotherthanplywoodisusedforthemanufactureoftheheads,itshallbeofaqualityequivalenttotheplywood.6.1.4.5.2.Atleasttwo-plyplywoodshallbeusedforthebodyandatleastthree-plyplywoodfortheheads;thepliesshallbefirmlygluedtogetherbyawaterresistantadhesivewiththeirgraincrosswise.6.1.4.5.3.Thebodyandheadsofthedrumandtheirjoinsshallbeofadesignappropriatetothecapacityofthedrumandtoitsintendeduse.6.1.4.5.4.Inordertopreventsiftingofthecontents,lidsshallbelinedwithkraftpaperorsomeotherequivalentmaterialwhichshallbesecurelyfastenedtothelidandextendtotheoutsidealongitsfullcircumference.6.1.4.5.5.Maximumcapacityofdrum:250litres.6.1.4.5.6.Maximumnetmass:400kg.6.1.4.6.Woodenbarrels2C1bungtype2C2removablehead6.1.4.6.1.Thewoodusedshallbeofgoodquality,straightgrained,wellseasonedandfreefromknots,bark,rottenwood,sapwoodorotherdefectslikelytolessentheeffectivenessofthebarrelforthepurposeintended.6.1.4.6.2.Thebodyandheadsshallbeofadesignappropriatetothecapacityofthebarrelandtoitsintendeduse.6.1.4.6.3.Stavesandheadsshallbesawnorcleftwiththegrainsothatnoannualringextendsovermorethanhalfthethicknessofastaveorhead.6.1.4.6.4.Barrelhoopsshallbeofsteelorironofgoodquality.Thehoopsofremovablehead(2C2)barrelsmaybeofasuitablehardwood.6.1.4.6.5.Woodenbarrels2C1:thediameterofthebungholeshallnotexceedhalfthewidthofthestaveinwhichitisplaced.6.1.4.6.6.Woodenbarrels2C2:headsshallfittightlyintothecrozes.6.1.4.6.7.Maximumcapacityofbarrel:250litres.6.1.4.6.8.Maximumnetmass:400kg.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/7526.1.4.7.Fibredrums1G6.1.4.7.1.Thebodyofthedrumshallconsistofmultiplepliesofheavypaperorfibreboard(withoutcorrugations)firmlygluedorlaminatedtogetherandmayincludeoneormoreprotectivelayersofbitumen,waxedkraftpaper,metalfoil,plasticsmaterial,etc.6.1.4.7.2.Headsshallbeofnaturalwood,fibreboard,metal,plywood,plasticsorothersuitablematerialandmayincludeoneormoreprotectivelayersofbitumen,waxedkraftpaper,metalfoil,plasticsmaterial,etc.6.1.4.7.3.Thebodyandheadsofthedrumandtheirjoinsshallbeofadesignappropriatetothecapacityofthedrumandtoitsintendeduse.6.1.4.7.4.Theassembledpackagingshallbesufficientlywaterresistantsoasnottodelaminateundernormalconditionsofcarriage.6.1.4.7.5.Maximumcapacityofdrum:450litres.6.1.4.7.6.Maximumnetmass:400kg.6.1.4.8.Plasticdrumsandjerricans1H1drums,non-removablehead1H2drums,removablehead3H1jerricans,non-removablehead3H2jerricans,removablehead6.1.4.8.1.Thepackagingshallbemanufacturedfromsuitableplasticsmaterialandbeofadequatestrengthinrelationtoitscapacityandintendeduse.Exceptforrecycledplasticsmaterialasdefinedin1.2.1,nousedmaterialotherthanproductionresiduesorregrindfromthesamemanufacturingprocessmaybeused.Thepackagingshallbeadequatelyresistanttoageingandtodegradationcausedeitherbythesubstancecontainedorbyultravioletradiation.Anypermeationofthesubstancecontainedinthepackage,orrecycledplasticsmaterialusedtoproducenewpackaging,shallnotconstituteadangerundernormalconditionsofcarriage.6.1.4.8.2.Ifprotectionagainstultravioletradiationisrequired,itshallbeprovidedbytheadditionofcarbonblackorothersuitablepigmentsorinhibitors.Theseadditivesshallbecompatiblewiththecontentsandremaineffectivethroughoutthelifeofthepackaging.Whereuseismadeofcarbonblack,pigmentsorinhibitorsotherthanthoseusedinthemanufactureofthetesteddesigntype,retestingmaybewaivedifthecarbonblackcontentdoesnotexceed2%bymassorifthepigmentcontentdoesnotexceed3%bymass;thecontentofinhibitorsofultravioletradiationisnotlimited.6.1.4.8.3.Additivesservingpurposesotherthanprotectionagainstultravioletradiationmaybeincludedinthecompositionoftheplasticsmaterialprovidedthattheydonotadverselyaffectthechemicalandphysicalpropertiesofthematerialofthepackaging.Insuchcircumstances,retestingmaybewaived.6.1.4.8.4.Thewallthicknessateverypointofthepackagingshallbeappropriatetoitscapacityandintendeduse,takingintoaccountthestressestowhicheachpointisliabletobeexposed.6.1.4.8.5.Openingsforfilling,emptyingandventinginthebodiesorheadsofnon-removableheaddrums(1H1)andjerricans(3H1)shallnotexceed7cmindiameter.Drumsandjerricanswithlargeropeningsareconsideredtobeoftheremovableheadtype(1H2and3H2).Closuresforopeningsinthebodiesorheadsofdrumsandjerricansshallbesodesignedandappliedthattheywillremainsecureandleakproofundernormalconditionsofcarriage.Gasketsorothersealingelementsshallbeusedwithclosuresunlesstheclosureisinherentlyleakproof.6.1.4.8.6.Closuredevicesforremovableheaddrumsandjerricans(1H2and3H2)shallbesodesignedandappliedthattheywillremainsecureandleakproofundernormalconditionsofcarriage.Gasketsshallbeusedwithallremovableheadsunlessthedrumorjerricandesignissuchthat,wheretheremovableheadisproperlysecured,thedrumorjerricanisinherentlyleakproof.6.1.4.8.7.Themaximumpermissiblepermeabilityforflammableliquidsshallbe0,008g/l.hat23°C(see6.1.5.8).6.1.4.8.8.Whererecycledplasticsmaterialisusedforproductionofnewpackaging,thespecificpropertiesoftherecycledmaterialshallbeassuredanddocumentedregularlyaspartofaqualityassuranceprogrammerecognisedbythecompetentauthority.Thequalityassuranceprogrammeshallincludearecordofproperpre-sortingandverificationthateachbatchofrecycledplasticsmaterialhasthepropermeltflowrate,density,andtensileyieldstrength,consistentwiththatofthedesigntypemanufacturedfromsuchrecycledmaterial.Thisnecessarilyincludesknowledgeaboutthepackagingmaterialfromwhichtherecycledplasticshavebeenderived,aswellastheawarenessofthepriorcontentsofthosepackagingsifthosepriorcontentsmightreducethecapabilityofnewpackagingproducedusingthatmaterial.Inaddition,thepackagingmanufacturer'squalityassuranceprogrammeunder6.1.1.4shallincludeperformanceofthemechanicaldesigntypetestin6.1.5onpackagingsmanufacturedfromeachbatchofrecycledplasticsmaterial.Inthistesting,stackingperformancemaybeverifiedbyappropriatedynamiccompressiontestingratherthanstaticloadtesting.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/7536.1.4.8.9.Maximumcapacityofdrumsandjerricans:1H1,1H2:450litres3H1,3H2:60litres.6.1.4.8.10.Maximumnetmass:1H1,1H2:400kg3H1,3H2:120kg.6.1.4.9.Boxesofnaturalwood4C1ordinary4C2withsift-proofwalls6.1.4.9.1.Thewoodusedshallbewellseasoned,commerciallydryandfreefromdefectsthatwouldmateriallylessenthestrengthofanypartofthebox.Thestrengthofthematerialusedandthemethodofconstructionshallbeappropriatetothecapacityandintendeduseofthebox.Thetopsandbottomsmaybemadeofwaterresistantreconstitutedwoodsuchashardboard,particleboardorothersuitabletype.6.1.4.9.2.Fasteningsshallberesistanttovibrationexperiencedundernormalconditionsofcarriage.Endgrainnailingshallbeavoidedwheneverpracticable.Joinswhicharelikelytobehighlystressedshallbemadeusingclenchedorannularringnailsorequivalentfastenings.6.1.4.9.3.Box4C2:eachpartshallconsistofonepieceorbeequivalentthereto.Partsareconsideredequivalenttoonepiecewhenoneofthefollowingmethodsofgluedassemblyisused:Lindermannjoint,tongueandgroovejoint,shiplaporrabbetjointorbuttjointwithatleasttwocorrugatedmetalfastenersateachjoint.6.1.4.9.4.Maximumnetmass:400kg.6.1.4.10.Plywoodboxes4D6.1.4.10.1.Plywoodusedshallbeatleastthree-ply.Itshallbemadefromwellseasonedrotarycut,slicedorsawnveneer,commerciallydryandfreefromdefectsthatwouldmateriallylessenthestrengthofthebox.Thestrengthofthematerialusedandthemethodofconstructionshallbeappropriatetothecapacityandintendeduseofthebox.Alladjacentpliesshallbegluedwithwaterresistantadhesive.Othersuitablematerialsmaybeusedtogetherwithplywoodintheconstructionofboxes.Boxesshallbefirmlynailedorsecuredtocornerpostsorendsorbeassembledbyequallysuitabledevices.6.1.4.10.2.Maximumnetmass:400kg.6.1.4.11.Reconstitutedwoodboxes4F6.1.4.11.1.Thewallsofboxesshallbemadeofwaterresistantreconstitutedwoodsuchashardboard,particleboardorothersuitabletype.Thestrengthofthematerialusedandthemethodofconstructionshallbeappropriatetothecapacityoftheboxesandtotheirintendeduse.6.1.4.11.2.Otherpartsoftheboxesmaybemadeofothersuitablematerial.6.1.4.11.3.Boxesshallbesecurelyassembledbymeansofsuitabledevices.6.1.4.11.4.Maximumnetmass:400kg.6.1.4.12.Fibreboardboxes4G6.1.4.12.1.Strongandgoodqualitysolidordouble-facedcorrugatedfibreboard(singleormultiwall)shallbeused,appropriatetothecapacityoftheboxandtoitsintendeduse.Thewaterresistanceoftheoutersurfaceshallbesuchthattheincreaseinmass,asdeterminedinatestcarriedoutoveraperiodof30minutesbytheCobbmethodofdeterminingwaterabsorption,isnotgreaterthan155g/m2,seeISO535:1991.Itshallhaveproperbendingqualities.Fibreboardshallbecut,creasedwithoutscoring,andslottedsoastopermitassemblywithoutcracking,surfacebreaksorunduebending.Theflutingofcorrugatedfibreboardshallbefirmlygluedtothefacings.6.1.4.12.2.Theendsofboxesmayhaveawoodenframeorbeentirelyofwoodorothersuitablematerial.Reinforcementsofwoodenbattensorothersuitablematerialmaybeused.6.1.4.12.3.Manufacturingjoinsinthebodyofboxesshallbetaped,lappedandglued,orlappedandstitchedwithmetalstaples.Lappedjoinsshallhaveanappropriateoverlap.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/7546.1.4.12.4.Whereclosingiseffectedbygluingortaping,awaterresistantadhesiveshallbeused.6.1.4.12.5.Boxesshallbedesignedsoastoprovideagoodfittothecontents.6.1.4.12.6.Maximumnetmass:400kg.6.1.4.13.Plasticsboxes4H1expandedplasticsboxes4H2solidplasticsboxes6.1.4.13.1.Theboxshallbemanufacturedfromsuitableplasticsmaterialandbeofadequatestrengthinrelationtoitscapacityandintendeduse.Theboxshallbeadequatelyresistanttoageingandtodegradationcausedeitherbythesubstancecontainedorbyultravioletradiation.6.1.4.13.2.Anexpandedplasticsboxshallcomprisetwopartsmadeofamouldedexpandedplasticsmaterial,abottomsectioncontainingcavitiesfortheinnerpackagingsandatopsectioncoveringandinterlockingwiththebottomsection.Thetopandbottomsectionsshallbedesignedsothattheinnerpackagingsfitsnugly.Theclosurecapforanyinnerpackagingshallnotbeincontactwiththeinsideofthetopsectionofthisbox.6.1.4.13.3.Fordispatch,anexpandedplasticsboxshallbeclosedwithaself-adhesivetapehavingsufficienttensilestrengthtopreventtheboxfromopening.Theadhesivetapeshallbeweatherresistantanditsadhesivecompatiblewiththeexpandedplasticsmaterialofthebox.Otherclosingdevicesatleastequallyeffectivemaybeused.6.1.4.13.4.Forsolidplasticsboxes,protectionagainstultravioletradiation,ifrequired,shallbeprovidedbytheadditionofcarbonblackorothersuitablepigmentsorinhibitors.Theseadditivesshallbecompatiblewiththecontentsandremaineffectivethroughoutthelifeofthebox.Whereuseismadeofcarbonblack,pigmentsorinhibitorsotherthanthoseusedinthemanufactureofthetesteddesigntype,retestingmaybewaivedifthecarbonblackcontentdoesnotexceed2%bymassorifthepigmentcontentdoesnotexceed3%bymass;thecontentofinhibitorsofultravioletradiationisnotlimited.6.1.4.13.5.Additivesservingpurposesotherthanprotectionagainstultravioletradiationmaybeincludedinthecompositionoftheplasticsmaterialprovidedthattheydonotadverselyaffectthechemicalorphysicalpropertiesofthematerialofthebox.Insuchcircumstances,retestingmaybewaived.6.1.4.13.6.Solidplasticsboxesshallhaveclosuredevicesmadeofasuitablematerialofadequatestrengthandsodesignedastopreventtheboxfromunintentionalopening.6.1.4.13.7.Whererecycledplasticsmaterialisusedforproductionofnewpackaging,thespecificpropertiesoftherecycledmaterialshallbeassuredanddocumentedregularlyaspartofaqualityassuranceprogrammerecognisedbythecompetentauthority.Thequalityassuranceprogrammeshallincludearecordofproperpre-sortingandverificationthateachbatchofrecycledplasticsmaterialhasthepropermeltflowrate,density,andtensileyieldstrength,consistentwiththatofthedesigntypemanufacturedfromsuchrecycledmaterial.Thisnecessarilyincludesknowledgeaboutthepackagingmaterialfromwhichtherecycledplasticshavebeenderived,aswellastheawarenessofthepriorcontentsofthosepackagingsifthosepriorcontentsmightreducethecapabilityofnewpackagingproducedusingthatmaterial.Inaddition,thepackagingmanufacturer'squalityassuranceprogrammeunder6.1.1.4shallincludeperformanceofthemechanicaldesigntypetestin6.1.5onpackagingsmanufacturedfromeachbatchofrecycledplasticsmaterial.Inthistesting,stackingperformancemaybeverifiedbyappropriatedynamiccompressiontestingratherthanstaticloadtesting.6.1.4.13.8.Maximumnetmass:4H1:60kg4H2:400kg.6.1.4.14.Steeloraluminiumboxes4Asteel4Baluminium6.1.4.14.1.Thestrengthofthemetalandtheconstructionoftheboxshallbeappropriatetothecapacityoftheboxandtoitsintendeduse.6.1.4.14.2.Boxesshallbelinedwithfibreboardorfeltpackingpiecesorshallhaveaninnerlinerorcoatingofsuitablematerial,asrequired.Ifadoubleseamedmetallinerisused,stepsshallbetakentopreventtheingressofsubstances,particularlyexplosives,intotherecessesoftheseams.6.1.4.14.3.Closuresmaybeofanysuitabletype;theyshallremainsecuredundernormalconditionsofcarriage.6.1.4.14.4.Maximumnetmass:400kg.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/7556.1.4.15.Textilebags5L1withoutinnerlinerorcoating5L2sift-proof5L3waterresistant6.1.4.15.1.Thetextilesusedshallbeofgoodquality.Thestrengthofthefabricandtheconstructionofthebagshallbeappropriatetothecapacityofthebagandtoitsintendeduse.6.1.4.15.2.Bags,sift-proof,5L2:thebagshallbemadesift-proof,forexamplebytheuseof:(a)paperbondedtotheinnersurfaceofthebagbyawaterresistantadhesivesuchasbitumen;or(b)plasticsfilmbondedtotheinnersurfaceofthebag;or(c)oneormoreinnerlinersmadeofpaperorplasticsmaterial.6.1.4.15.3.Bags,waterresistant,5L3:topreventtheentryofmoisturethebagshallbemadewaterproof,forexamplebytheuseof:(a)separateinnerlinersofwaterresistantpaper(e.g.waxedkraftpaper,tarredpaperorplastics-coatedkraftpaper);or(b)plasticsfilmbondedtotheinnersurfaceofthebag;or(c)oneormoreinnerlinersmadeofplasticsmaterial.6.1.4.15.4.Maximumnetmass:50kg.6.1.4.16.Wovenplasticsbags5H1withoutinnerlinerorcoating5H2sift-proof5H3waterresistant6.1.4.16.1.Bagsshallbemadefromstretchedtapesormonofilamentsofasuitableplasticsmaterial.Thestrengthofthematerialusedandtheconstructionofthebagshallbeappropriatetothecapacityofthebagandtoitsintendeduse.6.1.4.16.2.Ifthefabriciswovenflat,thebagsshallbemadebysewingorsomeothermethodensuringclosureofthebottomandoneside.Ifthefabricistubular,thebagshallbeclosedbysewing,weavingorsomeotherequallystrongmethodofclosure.6.1.4.16.3.Bags,sift-proof,5H2:thebagshallbemadesift-proof,forexamplebymeansof:(a)paperoraplasticsfilmbondedtotheinnersurfaceofthebag;or(b)oneormoreseparateinnerlinersmadeofpaperorplasticsmaterial.6.1.4.16.4.Bags,waterresistant,5H3:topreventtheentryofmoisture,thebagshallbemadewaterproof,forexamplebymeansof:(a)separateinnerlinersofwaterresistantpaper(e.g.waxedkraftpaper,double-tarredkraftpaperorplastics-coatedkraftpaper);or(b)plasticsfilmbondedtotheinneroroutersurfaceofthebag;or(c)oneormoreinnerplasticsliners.6.1.4.16.5.Maximumnetmass:50kg.6.1.4.17.Plasticsfilmbags5H46.1.4.17.1.Bagsshallbemadeofasuitableplasticsmaterial.Thestrengthofthematerialusedandtheconstructionofthebagshallbeappropriatetothecapacityofthebagandtoitsintendeduse.Joinsandclosuresshallwithstandpressuresandimpactsliabletooccurundernormalconditionsofcarriage.6.1.4.17.2.Maximumnetmass:50kg.6.1.4.18.Paperbags5M1multiwall5M2multiwall,waterresistantOfficialJournaloftheEuropeanUnionEN26.1.2004L18/7566.1.4.18.1.Bagsshallbemadeofasuitablekraftpaperorofanequivalentpaperwithatleastthreeplies.Thestrengthofthepaperandtheconstructionofthebagsshallbeappropriatetothecapacityofthebagandtoitsintendeduse.Joinsandclosuresshallbesift-proof.6.1.4.18.2.Bags5M2:topreventtheentryofmoisture,abagoffourpliesormoreshallbemadewaterproofbytheuseofeitherawaterresistantplyasoneofthetwooutermostpliesorawaterresistantbarriermadeofasuitableprotectivematerialbetweenthetwooutermostplies;abagofthreepliesshallbemadewaterproofbytheuseofawaterresistantplyastheoutermostply.Wherethereisadangerofthesubstancecontainedreactingwithmoistureorwhereitispackeddamp,awaterproofplyorbarrier,suchasdouble-tarredkraftpaper,plastics-coatedkraftpaper,plasticsfilmbondedtotheinnersurfaceofthebag,oroneormoreinnerplasticsliners,shallalsobeplacednexttothesubstance.Joinsandclosuresshallbewaterproof.6.1.4.18.3.Maximumnetmass:50kg.6.1.4.19.Compositepackagings(plasticsmaterial)6HA1plasticsreceptaclewithoutersteeldrum6HA2plasticsreceptaclewithoutersteelcrateorbox6HB1plasticsreceptaclewithouteraluminiumdrum6HB2plasticsreceptaclewithouteraluminiumcrateorbox6HCplasticsreceptaclewithouterwoodenbox6HD1plasticsreceptaclewithouterplywooddrum6HD2plasticsreceptaclewithouterplywoodbox6HG1plasticsreceptaclewithouterfibredrum6HG2plasticsreceptaclewithouterfibreboardbox6HH1plasticsreceptaclewithouterplasticsdrum6HH2plasticsreceptaclewithoutersolidplasticsbox6.1.4.19.1.Innerreceptacle6.1.4.19.1.1.Therequirementsof6.1.4.8.1and6.1.4.8.4to6.1.4.8.7applytoplasticsinnerreceptacles.6.1.4.19.1.2.Theplasticsinnerreceptacleshallfitsnuglyinsidetheouterpackaging,whichshallbefreeofanyprojectionthatmightabradetheplasticsmaterial.6.1.4.19.1.3.Maximumcapacityofinnerreceptacle:6HA1,6HB1,6HD1,6HG1,6HH1:250litres6HA2,6HB2,6HC,6HD2,6HG2,6HH2:60litres.6.1.4.19.1.4.Maximumnetmass:6HA1,6HB1,6HD1,6HG1,6HH1:400kg6HA2,6HB2,6HC,6HD2,6HG2,6HH2:75kg.6.1.4.19.2.Outerpackaging6.1.4.19.2.1.Plasticsreceptaclewithoutersteeloraluminiumdrum6HA1or6HB1;therelevantrequirementsof6.1.4.1or6.1.4.2,asappropriate,applytotheconstructionoftheouterpackaging.6.1.4.19.2.2.Plasticsreceptaclewithoutersteeloraluminiumcrateorbox6HA2or6HB2;therelevantrequirementsof6.1.4.14applytotheconstructionoftheouterpackaging.6.1.4.19.2.3.Plasticsreceptaclewithouterwoodenbox6HC;therelevantrequirementsof6.1.4.9applytotheconstructionoftheouterpackaging.6.1.4.19.2.4.Plasticsreceptaclewithouterplywooddrum6HD1;therelevantrequirementsof6.1.4.5applytotheconstructionoftheouterpackaging.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/7576.1.4.19.2.5.Plasticsreceptaclewithouterplywoodbox6HD2;therelevantrequirementsof6.1.4.10applytotheconstructionoftheouterpackaging.6.1.4.19.2.6.Plasticsreceptaclewithouterfibredrum6HG1;therequirementsof6.1.4.7.1to6.1.4.7.4applytotheconstructionoftheouterpackaging.6.1.4.19.2.7.Plasticsreceptaclewithouterfibreboardbox6HG2;therelevantrequirementsof6.1.4.12applytotheconstructionoftheouterpackaging.6.1.4.19.2.8.Plasticsreceptaclewithouterplasticsdrum6HH1;therequirementsof6.1.4.8.1to6.1.4.8.6applytotheconstructionoftheouterpackaging.6.1.4.19.2.9.Plasticsreceptacleswithoutersolidplasticsbox(includingcorrugatedplasticsmaterial)6HH2;therequirementsof6.1.4.13.1and6.1.4.13.4to6.1.4.13.6applytotheconstructionoftheouterpackaging.6.1.4.20.Compositepackagings(glass,porcelainorstoneware)6PA1receptaclewithoutersteeldrum6PA2receptaclewithoutersteelcrateorbox6PB1receptaclewithouteraluminiumdrum6PB2receptaclewithouteraluminiumcrateorbox6PCreceptaclewithouterwoodenbox6PD1receptaclewithouterplywooddrum6PD2receptaclewithouterwickerworkhamper6PG1receptaclewithouterfibredrum6PG2receptaclewithouterfibreboardbox6PH1receptaclewithouterexpandedplasticspackaging6PH2receptaclewithoutersolidplasticspackaging6.1.4.20.1.Innerreceptacle6.1.4.20.1.1.Receptaclesshallbeofasuitableform(cylindricalorpear-shaped)andbemadeofgoodqualitymaterialfreefromanydefectthatcouldimpairtheirstrength.Thewallsshallbesufficientlythickateverypointandfreefrominternalstresses.6.1.4.20.1.2.Screw-threadedplasticsclosures,groundglassstoppersorclosuresatleastequallyeffectiveshallbeusedasclosuresforreceptacles.Anypartoftheclosurelikelytocomeintocontactwiththecontentsofthereceptacleshallberesistanttothosecontents.Careshallbetakentoensurethattheclosuresaresofittedastobeleakproofandaresuitablysecuredtopreventanylooseningduringcarriage.Ifventedclosuresarenecessary,theyshallcomplywith4.1.1.8.6.1.4.20.1.3.Thereceptacleshallbefirmlysecuredintheouterpackagingbymeansofcushioningand/orabsorbentmaterials.6.1.4.20.1.4.Maximumcapacityofreceptacle:60litres.6.1.4.20.1.5.Maximumnetmass:75kg.6.1.4.20.2.Outerpackaging6.1.4.20.2.1.Receptaclewithoutersteeldrum6PA1;therelevantrequirementsof6.1.4.1applytotheconstructionoftheouterpackaging.Theremovablelidrequiredforthistypeofpackagingmayneverthelessbeintheformofacap.6.1.4.20.2.2.Receptaclewithoutersteelcrateorbox6PA2;therelevantrequirementsof6.1.4.14applytotheconstructionoftheouterpackaging.Forcylindricalreceptaclestheouterpackagingshall,whenupright,riseabovethereceptacleanditsclosure.Ifthecratesurroundsapear-shapedreceptacleandisofmatchingshape,theouterpackagingshallbefittedwithaprotectivecover(cap).6.1.4.20.2.3.Receptaclewithouteraluminiumdrum6PB1;therelevantrequirementsof6.1.4.2applytotheconstructionoftheouterpackaging.6.1.4.20.2.4.Receptaclewithouteraluminiumcrateorbox6PB2;therelevantrequirementsof6.1.4.14applytotheconstructionoftheouterpackaging.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/7586.1.4.20.2.5.Receptaclewithouterwoodenbox6PC;therelevantrequirementsof6.1.4.9applytotheconstructionoftheouterpackaging.6.1.4.20.2.6.Receptaclewithouterplywooddrum6PD1;therelevantrequirementsof6.1.4.5applytotheconstructionoftheouterpackaging.6.1.4.20.2.7.Receptaclewithouterwickerworkhamper6PD2.Thewickerworkhampershallbeproperlymadewithmaterialofgoodquality.Itshallbefittedwithaprotectivecover(cap)soastopreventdamagetothereceptacle.6.1.4.20.2.8.Receptaclewithouterfibredrum6PG1;therelevantrequirementsof6.1.4.7.1to6.1.4.7.4applytotheconstructionoftheouterpackaging.6.1.4.20.2.9.Receptaclewithouterfibreboardbox6PG2;therelevantrequirementsof6.1.4.12applytotheconstructionoftheouterpackaging.6.1.4.20.2.10.Receptaclewithouterexpandedplasticsorsolidplasticspackaging(6PH1or6PH2);thematerialsofbothouterpackagingsshallmeettherelevantrequirementsof6.1.4.13.Outersolidplasticspackagingshallbemanufacturedfromhighdensitypolyethyleneorsomeothercomparableplasticsmaterial.Theremovablelidforthistypeofpackagingmayneverthelessbeintheformofacap.6.1.4.21.CombinationpackagingsTherelevantrequirementsofsection6.1.4fortheouterpackagingstobeused,areapplicable.NOTEFortheinnerandouterpackagingstobeused,seetherelevantpackinginstructionsinChapter4.1.6.1.4.22.Lightgaugemetalpackagings0A1non-removable-head0A2removable-head6.1.4.22.1.Thesheetmetalforthebodyandendsshallbeofsuitablesteel,andofagaugeappropriatetothecapacityandintendeduseofthepackaging.6.1.4.22.2.Thejointsshallbewelded,atleastdouble-seamedbyweltingorproducedbyamethodensuringasimilardegreeofstrengthandleakproofness.6.1.4.22.3.Innercoatingsofzinc,tin,lacquer,etc.shallbetoughandshalladheretothesteelateverypoint,includingtheclosures.6.1.4.22.4.Openingsforfilling,emptyingandventinginthebodiesorheadsofnon-removablehead(0A1)packagingsshallnotexceed7cmindiameter.Packagingswithlargeropeningsshallbeconsideredtobeoftheremovable-headtype(0A2).6.1.4.22.5.Theclosuresofnon-removable-headpackagings(0A1)shalleitherbeofthescrew-threadedtypeorbecapableofbeingsecuredbyascrewabledeviceoradeviceatleastequallyeffective.Theclosuresofremovable-headpackagings(0A2)shallbesodesignedandfittedthattheystayfirmlyclosedandthepackagingsremainleakproofinnormalconditionsofcarriage.6.1.4.22.6.Maximumcapacityofpackagings:40litres.6.1.4.22.7.Maximumnetmass:50kg.6.1.5.Testrequirementsforpackagings6.1.5.1.Performanceandfrequencyoftests6.1.5.1.1.Thedesigntypeofeachpackagingshallbetestedasprovidedin6.1.5inaccordancewithproceduresestablishedandapprovedbythecompetentauthority.6.1.5.1.2.Testsshallbesuccessfullyperformedoneachpackagingdesigntypebeforesuchpackagingisused.Apackagingdesigntypeisdefinedbythedesign,size,materialandthickness,mannerofconstructionandpacking,butmayincludevarioussurfacetreatments.Italsoincludespackagingswhichdifferfromthedesigntypeonlyintheirlesserdesignheight.6.1.5.1.3.Testsshallberepeatedonproductionsamplesatintervalsestablishedbythecompetentauthority.Forsuchtestsonpaperorfibreboardpackagings,preparationatambientconditionsisconsideredequivalenttotherequirementsof6.1.5.2.3.6.1.5.1.4.Testsshallalsoberepeatedaftereachmodificationwhichaltersthedesign,materialormannerofconstructionofapackaging.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/7596.1.5.1.5.Thecompetentauthoritymaypermittheselectivetestingofpackagingsthatdifferonlyinminorrespectsfromatestedtype,e.g.smallersizesofinnerpackagingsorinnerpackagingsoflowernetmassandpackagingssuchasdrums,bagsandboxeswhichareproducedwithsmallreductionsinexternaldimension(s).6.1.5.1.6.Whereanouterpackagingofacombinationpackaginghasbeensuccessfullytestedwithdifferenttypesofinnerpackagings,avarietyofsuchdifferentinnerpackagingsmayalsobeassembledinthisouterpackaging.Inaddition,providedanequivalentlevelofperformanceismaintained,thefollowingvariationsininnerpackagingsareallowedwithoutfurthertestingofthepackage:(a)Innerpackagingsofequivalentorsmallersizemaybeusedprovided:(i)theinnerpackagingsareofsimilardesigntothetestedinnerpackagings(e.g.shape:round,rectangular,etc.);(ii)thematerialofconstructionoftheinnerpackagings(glass,plastics,metal,etc.)offersresistancetoimpactandstackingforcesequaltoorgreaterthanthatoftheoriginallytestedinnerpackaging;(iii)theinnerpackagingshavethesameorsmalleropeningsandtheclosureisofsimilardesign(e.g.screwcap,frictionlid,etc.);(iv)sufficientadditionalcushioningmaterialisusedtotakeupvoidspacesandtopreventsignificantmovementoftheinnerpackagings;and(v)innerpackagingsareorientedwithintheouterpackaginginthesamemannerasinthetestedpackage.(b)Alessernumberofthetestedinnerpackagings,orofthealternativetypesofinnerpackagingsidentifiedinpoint(a),maybeusedprovidedsufficientcushioningisaddedtofillthevoidspace(s)andtopreventsignificantmovementoftheinnerpackagings.6.1.5.1.7.Articlesorinnerpackagingsofanytypeforsolidsorliquidsmaybeassembledandcarriedwithouttestinginanouterpackagingunderthefollowingconditions:(a)theouterpackagingshallhavebeensuccessfullytestedinaccordancewith6.1.5.3withfragile(e.g.glass)innerpackagingscontainingliquidsusingthepackinggroupIdropheight;(b)thetotalcombinedgrossmassofinnerpackagingsshallnotexceedonehalfthegrossmassofinnerpackagingsusedforthedroptestinpoint(a);(c)thethicknessofcushioningmaterialbetweeninnerpackagingsandbetweeninnerpackagingsandtheoutsideofthepackagingshallnotbereducedbelowthecorrespondingthicknessesintheoriginallytestedpackaging;andifasingleinnerpackagingwasusedintheoriginaltest,thethicknessesofcushioningbetweeninnerpackagingsshallnotbelessthanthethicknessofcushioningbetweentheoutsideofthepackagingandtheinnerpackagingintheoriginaltest.Ifeitherfewerorsmallerinnerpackagingsareused(ascomparedtotheinnerpackagingsusedinthedroptest),sufficientadditionalcushioningmaterialshallbeusedtotakeupvoidspaces;(d)theouterpackagingshallhavepassedsuccessfullythestackingtestin6.1.5.6whileempty.Thetotalmassofidenticalpackagesshallbebasedonthecombinedmassofinnerpackagingsusedforthedroptestinpoint(a);(e)innerpackagingscontainingliquidsshallbecompletelysurroundedwithasufficientquantityofabsorbentmaterialtoabsorbtheentireliquidcontentsoftheinnerpackagings;(f)iftheouterpackagingisintendedtocontaininnerpackagingsforliquidsandisnotleakproof,orisintendedtocontaininnerpackagingsforsolidsandisnotsiftproof,ameansofcontaininganyliquidorsolidcontentsintheeventofleakageshallbeprovidedintheformofaleakproofliner,plasticsbagorotherequallyefficientmeansofcontainment.Forpackagingscontainingliquids,theabsorbentmaterialrequiredinpoint(e)shallbeplacedinsidethemeansofcontainingtheliquidcontents;(g)packagingsshallbemarkedinaccordancewith6.1.3ashavingbeentestedtopackinggroupIperformanceforcombinationpackagings.Themarkedgrossmassinkilogramsshallbethesumofthemassoftheouterpackagingplusonehalfofthemassoftheinnerpackaging(s)asusedforthedroptestreferredtoinpoint(a).Suchapackagemarkshallalsocontainaletter‘V’asdescribedin6.1.2.4.6.1.5.1.8.Thecompetentauthoritymayatanytimerequireproof,bytestsinaccordancewiththissection,thatserially-producedpackagingsmeettherequirementsofthedesigntypetests.Forverificationpurposesrecordsofsuchtestsshallbemaintained.6.1.5.1.9.Ifaninnertreatmentorcoatingisrequiredforsafetyreasons,itshallretainitsprotectivepropertiesevenafterthetests.6.1.5.1.10.Providedthevalidityofthetestresultsisnotaffectedandwiththeapprovalofthecompetentauthority,severaltestsmaybemadeononesample.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/7606.1.5.1.11.SalvagepackagingsSalvagepackagings(see1.2.1)shallbetestedandmarkedinaccordancewiththerequirementsapplicabletopackinggroupIIpackagingsintendedforthecarriageofsolidsorinnerpackagings,exceptasfollows:(a)thetestsubstanceusedinperformingthetestsshallbewater,andthepackagingsshallbefilledtonotlessthan98%oftheirmaximumcapacity.Itispermissibletouseadditives,suchasbagsofleadshot,toachievetherequisitetotalpackagemasssolongastheyareplacedsothatthetestresultsarenotaffected.Alternatively,inperformingthedroptest,thedropheightmaybevariedinaccordancewith6.1.5.3.4(b);(b)packagingsshall,inaddition,havebeensuccessfullysubjectedtotheleakproofnesstestat30kPa,withtheresultsofthistestreflectedinthetestreportrequiredby6.1.5.9,and(c)packagingsshallbemarkedwiththeletter‘T’asdescribedin6.1.2.4.6.1.5.2.Preparationofpackagingsfortesting6.1.5.2.1.Testsshallbecarriedoutonpackagingspreparedasforcarriageincluding,withrespecttocombinationpackagings,theinnerpackagingsused.Innerorsinglereceptaclesorpackagingsshallbefilledtonotlessthan98%oftheirmaximumcapacityforliquidsor95%forsolids.Forcombinationpackagingswheretheinnerpackagingisdesignedtocarryliquidsandsolids,separatetestingisrequiredforbothliquidandsolidcontents.Thesubstancesorarticlestobecarriedinthepackagingsmaybereplacedbyothersubstancesorarticlesexceptwherethiswouldinvalidatetheresultsofthetests.Forsolids,whenanothersubstanceisuseditshallhavethesamephysicalcharacteristics(mass,grainsize,etc.)asthesubstancetobecarried.Itispermissibletouseadditives,suchasbagsofleadshot,toachievetherequisitetotalpackagemass,solongastheyareplacedsothatthetestresultsarenotaffected.6.1.5.2.2.Inthedroptestsforliquids,whenanothersubstanceisused,itshallbeofsimilarrelativedensityandviscositytothoseofthesubstancebeingcarried.Watermayalsobeusedfortheliquiddroptestundertheconditionsin6.1.5.3.4.6.1.5.2.3.Paperorfibreboardpackagingsshallbeconditionedforatleast24hoursinanatmospherehavingacontrolledtemperatureandrelativehumidity(r.h.).Therearethreeoptions,oneofwhichshallbechosen.Thepreferredatmosphereis23±2°Cand50%±2%r.h.Thetwootheroptionsare20±2°Cand65%±2%r.h.or27±2°Cand65%±2%r.h.NOTEAveragevaluesshallfallwithintheselimits.Short-termfluctuationsandmeasurementlimitationsmaycauseindividualmeasurementstovarybyupto±5%relativehumiditywithoutsignificantimpairmentoftestreproducibility.6.1.5.2.4.Bung-typebarrelsmadeofnaturalwoodshallbeleftfilledwithwaterforatleast24hoursbeforethetests.6.1.5.2.5.Tocheckthattheirchemicalcompatibilitywiththeliquidsissufficient,plasticsdrumsandjerricansinaccordancewith6.1.4.8andifnecessarycompositepackagings(plasticsmaterial)inaccordancewith6.1.4.19shallbesubjectedtostorageatambienttemperatureforsixmonths,duringwhichtimethetestsamplesshallbekeptfilledwiththegoodstheyareintendedtocarry.Forthefirstandlast24hoursofstorage,thetestsamplesshallbeplacedwiththeclosuredownwards.However,packagingsfittedwithaventshallbesoplacedoneachoccasionforfiveminutesonly.Afterthisstoragethetestsamplesshallundergothetestsprescribedin6.1.5.3to6.1.5.6.Whenitisknownthatthestrengthpropertiesoftheplasticsmaterialoftheinnerreceptaclesofcompositepackagings(plasticsmaterial)arenotsignificantlyalteredbytheactionofthefillingsubstance,itshallnotbenecessarytocheckthatthechemicalcompatibilityissufficient.Asignificantalterationinstrengthpropertiesmeans:(a)distinctembrittlement;or(b)aconsiderabledecreaseinelasticity,unlessrelatedtoanotlessthanproportionateincreaseintheelongationunderload.Wherethebehaviouroftheplasticsmaterialhasbeenestablishedbyothermeans,theabovecompatibilitytestmaybedispensedwith.Suchproceduresshallbeatleastequivalenttotheabovecompatibilitytestandberecognisedbythecompetentauthority.NOTEForplasticsdrumsandjerricansandcompositepackagings(plasticsmaterial)madeofhighoraveragemolecularmasspolyethylene,seealso6.1.5.2.6below.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/7616.1.5.2.6.Forhighmolecularmasspolyethylenedrumsandjerricansinaccordancewith6.1.4.8andifnecessarycompositepackagingsofhighmolecularmasspolyethyleneinaccordancewith6.1.4.19,conformingtothefollowingspecifications:—relativedensityat23°Cafterthermalconditioningforonehourat100°C≥0,940,inaccordancewithISOstandard1183,—meltflowrateat190°C/21,6kgload≤12g/10min,inaccordancewithISOstandard1133;forjerricansinaccordancewith6.1.4.8ofpackinggroupsIIandIIIand,ifnecessary,forcompositepackagingsinaccordancewith6.1.4.19inaveragemolecularmasspolyethylenemeetingthefollowingspecifications:—relativedensityat23°Cafterthermalconditioningforonehourat100°C≥0,940,inaccordancewithISOstandard1183,—meltflowrateat190°C/2160kgload≤0,5g/10minand≥0,1g/10min,inaccordancewithISOstandard1133,—meltflowrateat190°C/5kgload≤3g/10minand≥0,5g/10min,inaccordancewithISOstandard1133,chemicalcompatibilitywiththeliquidslistedin6.1.6.2maybeverifiedasfollowswithstandardliquids(see6.1.6.1).Thesufficientchemicalcompatibilityofthesepackagingsmaybeverifiedbystorageforthreeweeksat40°Cwiththeappropriatestandardliquid;wherethisstandardliquidiswater,proofofchemicalcompatibilityisnotrequired.Forthefirstandlast24hoursofstorage,thetestsamplesshallbeplacedwiththeclosuredownwards.However,packagingsfittedwithaventshallbesoplacedoneachoccasionforfiveminutesonly.Afterthisstorage,thetestsamplesshallundergothetestsprescribedin6.1.5.3to6.1.5.6.Whenapackagingdesign-typehassatisfiedtheapprovaltestswithastandardliquid,thecomparablefillingsubstanceslistedin6.1.6.2maybeacceptedforcarriagewithoutfurthertesting,subjecttothefollowingconditions:—therelativedensitiesofthefillingsubstancesshallnotexceedthatusedtodeterminetheheightforthedroptestandthemassforthestackingtest,—thevapourpressuresofthefillingsubstancesat50°Cor55°Cshallnotexceedthatusedtodeterminethepressurefortheinternalpressuretest.Thecompatibilitytestfortert-Butylhydroperoxidewithmorethan40%peroxidecontentandperoxyaceticacidsofClass5.2,shallnotbecarriedoutusingstandardliquids.Forthesesubstances,proofofsufficientchemicalcompatibilityofthetestsamplesshallbeprovidedduringastorageperiodofsixmonthsatambienttemperaturewiththesubstancestheyareintendedtocarry.Theprocedureinaccordancewiththisparagraphalsoappliestohighdensity,highoraveragemolecularmasspolyethylenepackagings,theinternalsurfaceofwhichisfluorinated.6.1.5.2.7.Fordrumsandjerricansconformingto6.1.4.8,andwherenecessarycompositepackagingsconformingto6.1.4.19,madeofhighoraveragemolecularmasspolyethylene,whichhavepassedthetestin6.1.5.2.6,fillingsubstancesotherthanthoselistedin6.1.6.2mayalsobeapproved.Suchapprovalshallbebasedonlaboratorytestsprovingthattheeffectofsuchfillingsubstancesonthetestspecimensislessthanthatofthestandardliquids.Theprocessesofdeteriorationtobetakenintoaccountshallbethefollowing:softeningthroughswelling,crackingunderstressandmoleculardegradation.Thesameconditionsasthosesetoutin6.1.5.2.6shallapplywithrespecttorelativedensityandvapourpressure.6.1.5.2.8.Providedthatthestrengthpropertiesoftheplasticsinnerpackagingsofacombinationpackagingarenotsignificantlyalteredbytheactionofthefillingsubstance,proofofchemicalcompatibilityisnotnecessary.Asignificantalterationinstrengthpropertiesmeans:(a)distinctembrittlement;(b)aconsiderabledecreaseinelasticity,unlessrelatedtoanotlessthanproportionateincreaseinelasticelongation.6.1.5.3.Droptest(1)6.1.5.3.1.Numberoftestsamples(perdesigntypeandmanufacturer)anddroporientationForotherthanflatdropsthecentreofgravityshallbeverticallyoverthepointofimpact.Wheremorethanoneorientationispossibleforagivendroptest,theorientationmostlikelytoresultinfailureofthepackagingshallbeused.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/762(1)SeeISOstandard2248.PackagingNumberoftestsamplesDroporientation(a)SteeldrumsAluminiumdrumsDrumsofmetalotherthansteeloraluminiumSteeljerricansAluminiumjerricansPlywooddrumsWoodenbarrelsFibredrumsPlasticsdrumsandjerricansCompositepackagingswhichareintheshapeofadrumLightgaugemetalpackagingsSix(threeforeachdrop)Firstdrop(usingthreesamples):thepackagingshallstrikethetargetdiagonallyonthechimeor,ifthepackaginghasnochime,onacircumferentialseamoranedgeSeconddrop(usingtheotherthreesamples):thepackagingshallstrikethetargetontheweakestpartnottestedbythefirstdrop,forexampleaclosureor,forsomecylindricaldrums,theweldedlong-itudinalseamofthedrumbody(b)BoxesofnaturalwoodPlywoodboxesReconstitutedwoodboxesFibreboardboxesPlasticsboxesSteeloraluminiumboxesCompositepackagingswhichareintheshapeofaboxFive(oneforeachdrop)Firstdrop:flatonthebottomSeconddrop:flatonthetopThirddrop:flatonthelongsideFourthdrop:flatontheshortsideFifthdrop:onacorner(c)Bags—single-plywithasideseamThree(threedropsperbag)Firstdrop:flatonawidefaceSeconddrop:flatonanarrowfaceThirddrop:onanendofthebag(d)Bags—single-plywithoutasideseam,ormultiplyThree(twodropsperbag)Firstdrop:flatonawidefaceSeconddrop:onanendofthebag(e)Compositepackagings(glass,stonewareorporcelain),markedwiththesymbol‘RID/ADR’accordingto6.1.3.1(a)(ii)andwhichareintheshapeofadrumorboxThree(oneforeachdrop)Diagonallyonthebottomchime,or,ifthereisnochime,onacircumferentialseamorthebottomedge6.1.5.3.2.SpecialpreparationoftestsamplesforthedroptestThetemperatureofthetestsampleanditscontentsshallbereducedto–18°Corlowerforthefollowingpackagings:(a)plasticsdrums(see6.1.4.8);(b)plasticsjerricans(see6.1.4.8);(c)plasticsboxesotherthanexpandedplasticsboxes(see6.1.4.13);(d)compositepackagings(plasticsmaterial)(see6.1.4.19)and;(e)combinationpackagingswithplasticsinnerpackagings,otherthanplasticsbagsintendedtocontainsolidsorarticles.Wheretestsamplesarepreparedinthisway,theconditioningin6.1.5.2.3maybewaived.Testliquidsshallbekeptintheliquidstatebytheadditionofanti-freezeifnecessary.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/7636.1.5.3.3.TargetThetargetshallbearigid,non-resilient,flatandhorizontalsurface.6.1.5.3.4.DropheightForsolidsandliquids,ifthetestisperformedwiththesolidorliquidtobecarriedorwithanothersubstancehavingessentiallythesamephysicalcharacteristics:PackinggroupIPackinggroupIIPackinggroupIII1,8m1,2m0,8mForliquidsifthetestisperformedwithwater:(a)wherethesubstancestobecarriedhavearelativedensitynotexceeding1,2:PackinggroupIPackinggroupIIPackinggroupIII1,8m1,2m0,8m(b)wherethesubstancestobecarriedhavearelativedensityexceeding1,2,thedropheightshallbecalculatedonthebasisoftherelativedensity(d)ofthesubstancetobecarried,roundeduptothefirstdecimal,asfollows:PackinggroupIPackinggroupIIPackinggroupIIId×1,5(m)d×1,0(m)d×0,67(m)(c)forlight-gaugemetalpackagings,markedwithsymbol‘RID/ADR’accordingto6.1.3.1(a)(ii)intendedforthecarriageofsubstanceshavingaviscosityat23°Cgreaterthan200mm2/s(correspondingtoaflowtimeof30secondswithanISOflowcuphavingajetorificeof6mmdiameterinaccordancewithISOstandard2431:1993)(i)iftherelativedensitydoesnotexceed1,2:PackinggroupIIPackinggroupIII0,6m0,4m(ii)wherethesubstancestobecarriedhavearelativedensity(d)exceeding1,2thedropheightshallbecalculatedonthebasisoftherelativedensity(d)ofthesubstancetobecarried,roundeduptothefirstdecimalplace,asfollows:PackinggroupIIPackinggroupIIId×0,5(m)d×0,33(m)6.1.5.3.5.Criteriaforpassingthetest6.1.5.3.5.1.Eachpackagingcontainingliquidshallbeleakproofwhenequilibriumhasbeenreachedbetweentheinternalandexternalpressures,howeverforinnerpackagingsofcombinationpackagingsandexceptforinnerreceptaclesofcompositepackagings(glass,porcelainorstoneware),markedwiththesymbol‘RID/ADR’accordingto6.1.3.1(a)(ii)itisnotnecessarythatthepressuresbeequalised.6.1.5.3.5.2.Whereapackagingforsolidsundergoesadroptestanditsupperfacestrikesthetarget,thetestsamplepassesthetestiftheentirecontentsareretainedbyaninnerpackagingorinnerreceptacle(e.g.aplasticsbag),eveniftheclosureisnolongersift-proof.6.1.5.3.5.3.Thepackagingorouterpackagingofacompositeorcombinationpackagingshallnotexhibitanydamageliabletoaffectsafetyduringcarriage.Thereshallbenoleakageofthefillingsubstancefromtheinnerreceptacleorinnerpackaging(s).OfficialJournaloftheEuropeanUnionEN26.1.2004L18/7646.1.5.3.5.4.Neithertheoutermostplyofabagnoranouterpackagingmayexhibitanydamageliabletoaffectsafetyduringcarriage.6.1.5.3.5.5.Aslightdischargefromtheclosure(s)uponimpactisnotconsideredtobeafailureofthepackagingprovidedthatnofurtherleakageoccurs.6.1.5.3.5.6.NoruptureispermittedinpackagingsforgoodsofClass1whichwouldpermitthespillageoflooseexplosivesubstancesorarticlesfromtheouterpackaging.6.1.5.4.LeakproofnesstestTheleakproofnesstestshallbeperformedonalldesigntypesofpackagingsintendedtocontainliquids;however,thistestisnotrequiredfor—innerpackagingsofcombinationpackagings,—innerreceptaclesofcompositepackagings(glass,porcelainorstoneware),markedwiththesymbol‘RID/ADR’accordingto6.1.3.1(a)(ii),—lightgaugemetalpackagings,markedwiththesymbol‘RID/ADR’accordingto6.1.3.1(a)(ii)intendedforsubstanceswithaviscosityat23°Cexceeding200mm2/s.6.1.5.4.1.Numberoftestsamples:threetestsamplesperdesigntypeandmanufacturer.6.1.5.4.2.Specialpreparationoftestsamplesforthetest:eitherventedclosuresshallbereplacedbysimilarnon-ventedclosuresortheventshallbesealed.6.1.5.4.3.Testmethodandpressuretobeapplied:thepackagingsincludingtheirclosuresshallberestrainedunderwaterforfiveminuteswhileaninternalairpressureisapplied,themethodofrestraintshallnotaffecttheresultsofthetest.Theairpressure(gauge)tobeappliedshallbe:PackinggroupIPackinggroupIIPackinggroupIIINotlessthan30kPa(0,3bar)Notlessthan20kPa(0,2bar)Notlessthan20kPa(0,2bar)Othermethodsatleastequallyeffectivemaybeused.6.1.5.4.4.CriterionforpassingthetestThereshallbenoleakage.6.1.5.5.Internalpressure(hydraulic)test6.1.5.5.1.PackagingstobetestedTheinternalpressure(hydraulic)testshallbecarriedoutonalldesigntypesofmetal,plasticsandcompositepackagingsintendedtocontainliquids.Thistestisnotrequiredfor:—innerpackagingsofcombinationpackagings,—innerreceptaclesofcompositepackagings(glass,porcelainorstoneware),markedwiththesymbol‘RID/ADR’accordingto6.1.3.1(a)(ii),—lightgaugemetalpackagings,markedwiththesymbol‘RID/ADR’accordingto6.1.3.1(a)(ii)intendedforsubstanceswithaviscosityat23°Cexceeding200mm2/s.6.1.5.5.2.Numberoftestsamples:threetestsamplesperdesigntypeandmanufacturer.6.1.5.5.3.Specialpreparationofpackagingsfortesting:eitherventedclosuresshallbereplacedbysimilarnon-ventedclosuresortheventshallbesealed.6.1.5.5.4.Testmethodandpressuretobeapplied:metalpackagingsandcompositepackagings(glass,porcelainorstoneware),includingtheirclosures,shallbesubjectedtothetestpressureforfiveminutes.Plasticspackagingsandcompositepackagings(plasticsmaterial)includingtheirclosuresshallbesubjectedtothetestpressurefor30minutes.Thispressureistheonetobeincludedinthemarkingrequiredby6.1.3.1(d).Themannerinwhichthepackagingsaresupportedshallnotinvalidatethetest.Thetestpressureshallbeappliedcontinuouslyandevenly;itshallbekeptconstantthroughoutthetestperiod.Thehydraulicpressure(gauge)applied,asdeterminedbyanyoneofthefollowingmethods,shallbe:(a)notlessthanthetotalgaugepressuremeasuredinthepackaging(i.e.thevapourpressureofthefillingsubstanceandthepartialpressureoftheairorotherinertgases,minus100kPa)at55°C,multipliedbyasafetyfactorof1,5;thistotalgaugepressureshallbedeterminedonthebasisofamaximumdegreeoffillinginaccordancewith4.1.1.4andafillingtemperatureofl5°C;orOfficialJournaloftheEuropeanUnionEN26.1.2004L18/765(b)notlessthan1,75timesthevapourpressureat50°Cofthesubstancetobecarried,minus100kPabutwithaminimumtestpressureof100kPa;or(c)notlessthan1,5timesthevapourpressureat55°Cofthesubstancetobecarried,minus100kPabutwithaminimumtestpressureof100kPa.6.1.5.5.5.Inaddition,packagingsintendedtocontainsubstancesofpackinggroupIshallbetestedtoaminimumtestpressureof250kPa(gauge)foratestperiodoffiveor30minutesdependinguponthematerialofconstructionofthepackaging.6.1.5.5.6.Criterionforpassingthetest:nopackagingmayleak.6.1.5.6.StackingtestAlldesigntypesofpackagingsotherthanbagsandotherthannon-stackablecompositepackagings(glass,porcelain,orstoneware),markedwiththesymbol‘RID/ADR’accordingto6.1.3.1(a)(ii)shallbesubjectedtoastackingtest.6.1.5.6.1.Numberoftestsamples:threetestsamplesperdesigntypeandmanufacturer.6.1.5.6.2.Testmethod:thetestsampleshallbesubjectedtoaforceappliedtothetopsurfaceofthetestsampleequivalenttothetotalweightofidenticalpackageswhichmightbestackedonitduringcarriage;wherethecontentsofthetestsamplearenon-dangerousliquidswithrelativedensitydifferentfromthatoftheliquidtobecarried,theforceshallbecalculatedinrelationtothelatter.Theminimumheightofthestackincludingthetestsampleshallbethreemetres.Thedurationofthetestshallbe24hoursexceptthatplasticsdrums,jerricans,andcompositepackagings6HH1and6HH2intendedforliquidsshallbesubjectedtothestackingtestforaperiodof28daysatatemperatureofnotlessthan40°C.Forthetestinaccordancewith6.1.5.2.5,theoriginalfillingsubstanceshallbeused.Forthetestinaccordancewith6.1.5.2.6,astackingtestshallbecarriedoutwithastandardliquid.6.1.5.6.3.Criteriaforpassingthetest:notestsampleshallleak.Incompositepackagingsorcombinationpackagings,thereshallbenoleakageofthefillingsubstancefromtheinnerreceptacleorinnerpackaging.Notestsampleshallshowanydeteriorationwhichcouldadverselyaffecttransportsafetyoranydistortionliabletoreduceitsstrengthorcauseinstabilityinstacksofpackages.Plasticspackagingsshallbecooledtoambienttemperaturebeforetheassessment.6.1.5.7.Cooperagetestforbungtypewoodenbarrels6.1.5.7.1.Numberofsamples:onebarrel.6.1.5.7.2.Methodoftesting:removeallhoopsabovethebilgeofanemptybarrelatleasttwodaysold.6.1.5.7.3.Criterionforpassingtest:thediameterofthecrosssessionoftheupperpartofthebarrelshallnotincreasebymorethan10%.6.1.5.8.Supplementarypermeabilitytestforplasticsdrumsandjerricansinaccordancewith6.1.4.8andforcompositepackagings(plasticsmaterial)inaccordancewith6.1.4.19intendedforthecarriageofliquidshavingaflash-point≤61°C,otherthan6HA1packagingsPolyethylenepackagingsneedbesubjectedtothistestonlyiftheyaretobeapprovedforthecarriageofbenzene,toluene,xyleneormixturesandpreparationscontainingthosesubstances.6.1.5.8.1.Numberoftestsamples:threepackagingsperdesigntypeandmanufacturer.6.1.5.8.2.SpecialpreparationofthetestsampleforthetestThetestsamplesaretobepre-storedwiththeoriginalfillingsubstanceinaccordancewith6.1.5.2.5,or,forhighmolecularmasspolyethylenepackagings,withthestandardliquidmixtureofhydrocarbons(whitespirit)inaccordancewith6.1.5.2.6.6.1.5.8.3.TestmethodThetestsamplesfilledwiththesubstanceforwhichthepackagingistobeapprovedshallbeweighedbeforeandafterstoragefor28daysat23°Cand50%relativeatmospherichumidity.Forhighmolecularmasspolyethylenepackagings,thetestmaybecarriedoutwiththestandardliquidmixtureofhydrocarbons(whitespirit)inplaceofbenzene,tolueneorxylene.6.1.5.8.4.Criterionforpassingthetest:permeabilityshallnotexceed0,008g/l.h.6.1.5.9.Testreport6.1.5.9.1.Atestreportcontainingatleastthefollowingparticularsshallbedrawnupandshallbeavailabletotheusersofthepackaging:1.nameandaddressofthetestfacility;2.nameandaddressofapplicant(whereappropriate);3.auniquetestreportidentification;OfficialJournaloftheEuropeanUnionEN26.1.2004L18/7664.dateofthetestreport;5.manufacturerofthepackaging;6.descriptionofthepackagingdesigntype(e.g.dimensions,materials,closures,thickness,etc.),includingmethodofmanufacture(e.g.blowmoulding)andwhichmayincludedrawing(s)and/orphotograph(s);7.maximumcapacity;8.characteristicsoftestcontents,e.g.viscosityandrelativedensityforliquidsandparticlesizeforsolids;9.testdescriptionsandresults;10.thetestreportshallbesignedwiththenameandstatusofthesignatory.6.1.5.9.2.Thetestreportshallcontainstatementsthatthepackagingpreparedasforcarriagewastestedinaccordancewiththeappropriaterequirementsofthissectionandthattheuseofotherpackagingmethodsorcomponentsmayrenderitinvalid.Acopyofthetestreportshallbeavailabletothecompetentauthority.6.1.6.Standardliquidsforverifyingthechemicalcompatibilityofhighoraveragemolecularmasspolyethylenepackagingsinaccordancewith6.1.5.2.6andlistofsubstancestowhichthestandardliquidsmayberegardedasequivalents6.1.6.1.Standardliquidsforverifyingthechemicalcompatibilityofhighoraveragemolecularmasspolyethylenepackagingsinaccordancewith6.1.5.2.6Thefollowingstandardliquidsshallbeusedforthisplasticsmaterial.(a)Wettingsolutionforsubstancescausingseverecrackinginpolyethyleneunderstress,inparticularforallsolutionsandpreparationscontainingwettingagents.Anaqueoussolutionof1to10%ofawettingagentshallbeused.Thesurfacetensionofthissolutionshallbe31to35mN/mat23°C.Thestackingtestshallbecarriedoutonthebasisofarelativedensityofnotlessthan1,20.Acompatibilitytestwithaceticacidisnotrequiredifadequatechemicalcompatibilityisprovedwithawettingsolution.Forfillingsubstancescausingcrackinginpolyethyleneunderstresswhichisresistanttothewettingsolution,adequatechemicalcompatibilitymaybeprovedafterpreliminarystoringforthreeweeksat40°Cinaccordancewith6.1.5.2.6,butwiththeoriginalfillingmatter.(b)Aceticacidforsubstancesandpreparationscausingcrackinginpolyethyleneunderstress,inparticularformonocarboxylicacidsandmonovalentalcohols.Aceticacidin98to100%concentrationshallbeused.Relativedensity=1,05.Thestackingtestshallbecarriedoutonthebasisofarelativedensitynotlessthan1,1.Inthecaseoffillingsubstancescausingpolyethylenetoswellmorethanaceticacidandtosuchanextentthatthepolyethylenemassisincreasedbyupto4%,adequatechemicalcompatibilitymaybeprovedafterpreliminarystoringforthreeweeksat40°C,inaccordancewith6.1.5.2.6butwiththeoriginalfillingmatter.(c)Normalbutylacetate/normalbutylacetate-saturatedwettingsolutionforsubstancesandpreparationscausingpolyethylenetoswelltosuchanextentthatthepolyethylenemassisincreasedbyabout4%andatthesametimecausingcrackingunderstress,inparticularforphytosanitaryproducts,liquidpaintsandesters.Normalbutylacetatein98to100%concentrationshallbeusedforpreliminarystorageinaccordancewith6.1.5.2.6.Forthestackingtestinaccordancewith6.1.5.6,atestliquidconsistingofa1to10%aqueouswettingsolutionmixedwith2%normalbutylacetateconformingto(a)aboveshallbeused.Thestackingtestshallbecarriedoutonthebasisofarelativedensitynotlessthan1,0.Inthecaseoffillingsubstancescausingpolyethylenetoswellmorethannormalbutylacetateandtosuchanextentthatthepolyethylenemassisincreasedbyupto7,5%,adequatechemicalcompatibilitymaybeprovedafterpreliminarystoringforthreeweeksat40°C,inaccordancewith6.1.5.2.6butwiththeoriginalfillingmatter.(d)Mixtureofhydrocarbons(whitespirit)forsubstancesandpreparationscausingpolyethylenetoswell,inparticularforhydrocarbons,estersandketones.Amixtureofhydrocarbonshavingaboilingrange160°Cto220°C,relativedensity0,78-0,80,flash-point>50°Candanaromaticcontent16%to21%shallbeused.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/767Thestackingtestshallbecarriedoutonthebasisofarelativedensitynotlessthan1,0.Inthecaseoffillingsubstancescausingpolyethylenetoswelltosuchanextentthatthepolyethylenemassisincreasedbymorethan7,5%,adequatechemicalcompatibilitymaybeprovedafterpreliminarystoringforthreeweeksat40°C,inaccordancewith6.1.5.2.6butwiththeoriginalfillingmatter.(e)Nitricacidforallsubstancesandpreparationshavinganoxidisingeffectonpolyethyleneandcausingmoleculardegradationidenticaltoorlessthan55%nitricacid.Nitricacidinaconcentrationofnotlessthan55%shallbeused.Thestackingtestshallbecarriedoutonthebasisofarelativedensityofnotlessthan1,4.Inthecaseoffillingsubstancesmorestronglyoxidisingthan55%nitricacidorcausingdegradationofthemolecularmassproceedinaccordancewith6.1.5.2.5.Theperiodofuseshallbedeterminedinsuchcasesbyobservingthedegreeofdamage(e.g.twoyearsfornitricacidinnotlessthan55%concentration).(f)Waterforsubstanceswhichdonotattackpolyethyleneinanyofthecasesreferredtounder(a)to(e),inparticularforinorganicacidsandlyes,aqueoussalinesolutions,polyvalentalcoholsandorganicsubstancesinaqueoussolution.Thestackingtestshallbecarriedoutonthebasisofarelativedensityofnotlessthan1,2.6.1.6.2.Listofsubstancestowhichthestandardliquidsmayberegardedasequivalentsforthepurposesof6.1.5.2.6Class3SubstanceStandardliquidFlammableliquidsofpackinggroupII,withoutsubsidiaryrisk(classificationcodeF1,packinggroupII)Substanceshavingavapourpressureat50°Cofnotmorethan110kPa(1,1bar)—CrudepetroleumandothercrudeoilsMixtureofhydrocarbons—HydrocarbonsMixtureofhydrocarbons—HalogenatedsubstancesMixtureofhydrocarbons—AlcoholsAceticacid—EthersMixtureofhydrocarbons—AldehydesMixtureofhydrocarbons—KetonesMixtureofhydrocarbons—EstersNormalbutylacetatewheretheswellingeffectisupto4%(mass):othercases,mixtureofhydrocarbonsMixturesofabovementionedsubstanceshavingaboilingpointorinitialboilingpointexceeding35°C,containingnotmorethan55%nitrocellulosewithanitrogencontentnotexceeding12,6%(UNNo2059)Normalbutylacetate/normalbutylacetate-saturatedwettingsolutionandmixtureofhydrocarbonsViscoussubstancesthatmeettheclassificationcriteriaof2.2.3.1.4MixtureofhydrocarbonsFlammableliquidsofpackinggroupII,toxic(classificationcodeFT1,packinggroupII)Methanol(UNNo1230)AceticacidFlammableliquidsofpackinggroupIII,withoutsubsidiaryrisk(classificationcodeF1,packinggroupIII)—Petroleum,solventnaphthaMixtureofhydrocarbons—Whitespirit(turpentinesubstitute)MixtureofhydrocarbonsOfficialJournaloftheEuropeanUnionEN26.1.2004L18/768SubstanceStandardliquid—HydrocarbonsMixtureofhydrocarbons—HalogenatedsubstancesMixtureofhydrocarbons—AlcoholsAceticacid—EthersMixtureofhydrocarbons—AldehydesMixtureofhydrocarbons—KetonesMixtureofhydrocarbons—EstersNormalbutylacetatewheretheswellingeffectisupto4%(mass):othercases,mixtureofhydrocarbons—NitrogenoussubstancesMixtureofhydrocarbonsMixturesofabovementionedsubstancescontainingnotmorethan55%nitrocellulosewithanitrogencontentnotexceeding12,6%(UNNo2059)Normalbutylacetate/normalbutylacetate-saturatedwettingsolutionandmixtureofhydrocarbonsClass5.1Oxidisingliquids,corrosive(classificationcodeOC1)Hydrogenperoxides,aqueoussolutionswithnotlessthan20%butnotmorethan60%hydrogenperoxide(UNNo2014)(1)WaterPerchloricacidwithmorethan50%butnotmorethan72%acid(mass)(UNNo1873)NitricacidOxidisingliquids,withoutsubsidiaryrisk(classificationcodeO1)Hydrogenperoxide,aqueoussolutionswithnotlessthan8%butlessthan20%hydrogenperoxide(UNNo2984)(1)WaterCalciumchloratesolution(UNNo2429)WaterPotassiumchloratesolution(UNNo2427)WaterSodiumchloratesolution(UNNo2428)Water(1)Testtobeperformedonlywithavent.Class5.2NOTEtert-butylhydroperoxidewithmorethan40%peroxidecontentandperoxyaceticacidsareexcludedAllorganicperoxidesinatechnicallypureformorinsolutioninsolventswhich,asfarastheircompatibilityisconcerned,arecoveredbythestandardliquid‘mixtureofhydrocarbons’inthislist(UNNos3101,3103,3105,3107,3109,3111,3113,3115,3117,3119)Normalbutylacetate/wettingsolutionwith2%normalbutylacetateandmixtureofhydrocarbonsandnitricacidat55%Compatibilityofventsandgasketswithorganicperoxidesmaybeverified,alsoindependentlyofthedesigntypetest,bylaboratorytestswithnitricacid.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/769Class6.1Toxicorganicliquidswithoutsubsidiaryrisk(classificationcodeT1)Aniline(UNNo1547)AceticacidFurfurylalcohol(UNNo2874)AceticacidPhenolsolution(UNNo2821,packinggroupIII)AceticacidToxicorganicliquids,corrosive(classificationcodeTC1)Cresols(UNNo2076)orcresylicacid(UNNo2022)AceticacidClass6.2Allinfectioussubstances(UNNos2814and2900,riskgroup2,andUNNo3291)consideredtobeliquidsinaccordancewith2.1.2.6WaterClass8Corrosiveacidinorganicliquids,withoutsubsidiaryrisk(classificationcodeC2)Sulphuricacid(UNNos1830and2796)WaterSulphuricacid,spent(UNNo1832)WaterNitricacid(UNNo2031)withnotmorethan55%acidNitricacidPerchloricacidwithnotmorethan50%acid,bymassinaqueoussolution(UNNo1802)NitricacidHydrochloricacid(UNNo1789)withnotmorethan36%pureacidWaterHydrobromicacid(UNNo1788)WaterHydriodicacid(UNNo1787)WaterHydrofluoricacid(UNNo1790)withnotmorethan60%hydrogenfluoride(1)WaterFluoroboricacid(UNNo1775)withnotmorethan50%pureacidWaterFluorosilicicacid(UNNo1778)WaterChromicacidsolution(UNNo1755)withnotmorethan30%pureacidNitricacidPhosphoricacid(UNNo1805)WaterCorrosiveacidorganicliquids(classificationcodeC3)Acrylicacid(UNNo2218),Formicacid(UNNo1779),Aceticacid(UNNos2789and2790),Thioglycolicacid(UNNo1940)AceticacidOfficialJournaloftheEuropeanUnionEN26.1.2004L18/770Methacrylicacid(UNNo2531),Propionicacid(UNNo1848)AceticacidAlkylphenols,liquid,n.o.s.(UNNo3145,packinggroupIII)AceticacidCorrosivebasicinorganicliquids,withoutsubsidiaryrisk(classificationcodeC5)Sodiumhydroxidesolution(UNNo1824),Potassiumhydroxidesolution(UNNo1814)WaterAmmoniasolution(UNNo2672)WaterHydrazine,aqueoussolutionswithnotmorethan64%hydrazine,bymass(UNNo2030)WaterOthercorrosiveliquids(classificationcodeC9)Chloritesolution(UNNo1906)andhypochloritesolution(2)(UNNo1791,packinggroupIII)NitricacidFormaldehydesolutions(UNNo2209)Water(1)Maximum60litres;permissibleperiodofusetwoyears.(2)Testtobecarriedoutonlywithvent.Ifthetestiscarriedoutwithnitricacidasthestandardliquid,anacid-resistantventandgasketshallbeused.Forhypochloritesolutions,ventsandgasketsofthesamedesigntype,resistanttohypochlorite(e.g.ofsiliconerubber)butnotresistanttonitricacid,arealsopermitted.CHAPTER6.2Requirementsfortheconstructionandtestingofreceptaclesforgases,aerosoldispensersandsmallreceptaclescontaininggas(gascartridges)6.2.1.GeneralrequirementsforreceptaclesforgasesNOTEForaerosoldispensersandsmallreceptaclescontaininggas(gascartridges)see6.2.46.2.1.1.Designandconstruction6.2.1.1.1.Receptaclesandtheirclosuresshallbedesigned,calculated,manufactured,testedandequippedinsuchawayastowithstandallconditionstowhichtheywillbesubjectedduringtheirnormaluseandduringnormalconditionsofcarriage.Inthedesignofpressurereceptacles,allrelevantfactorsshallbetakenintoaccountsuchas:—internalpressure,—ambientandoperationaltemperatures,includingduringcarriage,—dynamicloads.Normallythewallthicknessshallbedeterminedbycalculation,accompanied,ifneeded,byexperimentalstressanalysis.Thewallthicknessmaybedeterminedbyexperimentalmeans.Appropriatedesigncalculationsforthepressureenvelopeandsupportingcomponentsshallbeusedtoensurethesafetyofthereceptaclesconcerned.Theminimumwallthicknesstowithstandpressureshallbecalculatedinparticularwithregardto:—thecalculationpressures,whichshallnotbelessthanthetestpressure,—thecalculationtemperaturesallowingforappropriatesafetymargins,—themaximumstressesandpeakstressconcentrationswherenecessary,—factorsinherenttothepropertiesofthematerial.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/771ThetestpressureofreceptaclesisprescribedinpackinginstructionP200in4.1.4.1forcylinders,tubes,pressuredrumsandbundlesofcylinders.Thetestpressureforcryogenicreceptacles,closed,shallnotbelessthan1,3timesthemaximumworkingpressureincreasedby1barforvacuuminsulatedreceptacles.Materialcharacteristicstobeconsideredare,whenapplicable:—yieldstress,—tensilestrength,—time-dependentstrength,—fatiguedata,—Young'smodulus(modulusofelasticity),—appropriateamountofplasticstrain,—impactstrength,—fractureresistance.6.2.1.1.2.ReceptaclesforUNNo1001,acetylene,dissolved,shallbefilledentirelywithaporousmaterial,uniformlydistributed,ofatype-approvedbythecompetentauthorityandwhich:(a)doesnotattackthereceptaclesorformharmfulordangerouscompoundseitherwiththeacetyleneorwiththesolvent;(b)iscapableofpreventingthespreadofdecompositionoftheacetyleneinthemass.Thesolventshallnotattackthereceptacles.6.2.1.2.MaterialsofreceptaclesThematerialsofwhichthereceptaclesandtheirclosuresaremadeaswellasallsubstancesthatmightcomeintocontactwiththecontentsshallnotbeliabletoattackthecontentsorformharmfulordangerouscompoundstherewith.Thefollowingmaterialsmaybeused:(a)carbonsteelforcompressed,liquefied,refrigeratedliquefiedgasesandgasesdissolvedunderpressure;(b)alloysteel(specialsteels),nickel,nickelalloy(suchasmonel)forcompressed,liquefied,refrigeratedliquefiedgasesandgasesdissolvedunderpressure;(c)copperfor:(i)gasesofclassificationcodes1A,1O,1Fand1TF,whosefillingpressurereferredtoatemperatureof15°Cdoesnotexceed2MPa(20bar);(ii)gasesofclassificationcode2AandalsoUNNo1033dimethylether;UNNo1037ethylchloride;UNNo1063methylchloride;UNNo1079sulphurdioxide;UNNo1085vinylbromide;UNNo1086vinylchloride;andUNNo3300ethyleneoxideandcarbondioxidemixturewithmorethan87%ethyleneoxide;(iii)gasesofclassificationcodes3A,3Oand3F;(d)aluminiumalloy:seespecialrequirement‘a’ofpackinginstructionP200(12)in4.1.4.1;(e)compositematerialforcompressed,liquefied,refrigeratedliquefiedgasesandgasesdissolvedunderpressure;(f)syntheticmaterialsforrefrigeratedliquefiedgases;and(g)glassfortherefrigeratedliquefiedgasesofclassificationcode3AotherthanUNNo2187carbondioxide,refrigerated,liquidormixturesthereof,andgasesofclassificationcode3O.6.2.1.3.Serviceequipment6.2.1.3.1.OpeningsApartfromamanholewhich,ifprovided,shallbeclosedbyaneffectiveclosureandapartfromthenecessaryorificefortheremovalofdeposits,pressuredrumsshallnotbeequippedwithmorethantwoopeningsoneforthefillingandoneforthedischarge.Cylindersandpressuredrums,intendedforthecarriageofgasesofclassificationcode2Fmaybeprovidedwithotheropeningsintendedinparticularforverifyingtheleveloftheliquidandthegaugepressure.6.2.1.3.2.Fittings(a)Ifcylindersarefittedwithadevicetopreventrolling,thisdeviceshallnotbeintegralwiththevalvecap.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/772(b)Pressuredrumswhicharecapableofbeingrolledshallbeequippedwithrollinghoopsorbeotherwiseprotectedagainstdamageduetorolling(e.g.bycorrosionresistantmetalsprayedontothereceptaclesurface).(c)Pressuredrumsandcryogenicreceptacles,whicharenotcapableofbeingrolled,shallbefittedwithdevices(skids,rings,straps,)ensuringthattheycanbesafelyhandledbymechanicalmeansandsoarrangedasnottoimpairthestrengthof,norcauseunduestressesin,thewallofthereceptacle.(d)Bundlesofcylindersshallbefittedwithappropriatedevicesensuringthattheycanbehandledandcarriedsafely.Themanifoldshallhaveatleastthesametestpressureasthecylinders.Themanifoldandthemastercockshallbesituatedsoastobeprotectedagainstanydamage.6.2.1.3.3.SafetyvalvesCryogenicreceptacles,closed,shallbefittedwithoneormorepressurereliefdevicestoprotectthevesselagainstexcesspressure.Excesspressuremeansapressureinexcessof110%ofthemaximumworkingpressureduetonormalheatleakorinexcessofthetestpressureduetothelossofvacuumforvacuuminsulatedreceptaclesorduetothefailureintheopenpositionofapressurebuildupsystem.6.2.1.4.Approvalofreceptacles6.2.1.4.1.Theconformityofreceptacles,havingatestpressurecapacityproductofmorethan150MPa.litre(1500bar.litre)withtheprovisionsofClass2,shallbeassessedbyoneofthefollowingmethods.(a)Singlereceptaclesshallbeexamined,testedandapprovedbyatestingandcertifyingbodyapprovedbythecompetentauthorityofthecountryofapproval(1),onthebasisofthetechnicaldocumentationanddeclarationofthemanufactureroncompliancewiththerelevantprovisionsofClass2.Thetechnicaldocumentationshallincludefullspecificationsondesignandconstruction,andfulldocumentationonthemanufacturingandtesting;or(b)theconstructionofthereceptaclesshallbetestedandapprovedbyatestingandcertifyingbodyapprovedbythecompetentauthorityofthecountryofapproval(1)onthebasisofthetechnicaldocumentationwithregardtotheircompliancewiththerelevantprovisionsofClass2.Receptaclesshallfurthermorebedesigned,manufacturedandtestedaccordingtoacomprehensivequalityassuranceprogrammefordesign,manufacture,finalinspectionandtesting.ThequalityassuranceprogrammeshallguaranteetheconformityofthereceptacleswiththerelevantprovisionsofClass2andshallbeapprovedandsupervisedbyatestingandcertifyingbodyapprovedbythecompetentauthorityofthecountryofapproval(1);or(c)thedesigntypeofthereceptaclesshallbeapprovedbyatestingandcertifyingbodyapprovedbythecompetentauthorityofthecountryofapproval(1).Anyreceptacleofthisdesignshallbemanufacturedandtestedaccordingtoaqualityassuranceprogrammeforproduction,finalinspectionandtesting,whichshallbeapprovedandsupervisedbyatestingandcertifyingbodyapprovedbythecompetentauthorityofthecountryofapproval(1);or(d)thedesigntypeofthereceptaclesshallbeapprovedbyatestingandcertifyingbodyapprovedbythecompetentauthorityofthecountryofapproval(1).Anyreceptacleofthisdesignshallbetestedunderthesupervisionofatestingandcertifyingbodyapprovedbythecompetentauthorityofthecountryofapproval(1)onthebasisofadeclarationofthemanufactureroncompliancewiththeapproveddesignandtherelevantprovisionsofClass2.6.2.1.4.2.Theconformityofreceptacleshavingatestpressurecapacityproductofmorethan30MPa.litre(300bar.litre)andnotmorethan150MPa.litre(1500bar.litre)withtheprovisionsofClass2shallbeassessedbyoneofthemethodsdescribedin6.2.1.4.1orbyoneofthefollowingmethods:(a)thereceptaclesshallbedesigned,manufacturedandtestedaccordingtoacomprehensivequalityassuranceprogrammefortheirdesign,manufacture,finalinspectionandtesting,approvedandsupervisedbyatestingandcertifyingbodyapprovedbythecompetentauthorityofthecountryofapproval(1);or(b)thedesigntypeofthereceptacleshallbeapprovedbyatestingandcertifyingbodyapprovedbythecompetentauthorityofthecountryofapproval(1).Thecomplianceofanyreceptaclewiththeapproveddesignshallbedeclaredinwritingbythemanufactureronthebasisofhisqualityassuranceprogrammeforfinalinspectionandtestingofreceptacles,approvedandsupervisedbyatestingandcertifyingbodyapprovedbythecompetentauthorityofthecountryofapproval(1);orOfficialJournaloftheEuropeanUnionEN26.1.2004L18/773(1)IfthecountryofapprovalisnotaMemberState,thecompetentauthorityofaMemberState.(c)thedesigntypeofthereceptacleshallbeapprovedbyatestingandcertifyingbodyapprovedbythecompetentauthorityofthecountryofapproval(1).Thecomplianceofanyreceptaclewiththeapproveddesignshallbedeclaredinwritingbythemanufacturerandallreceptaclesofthistypeshallbetestedunderthesupervisionofatestingandcertifyingbodyapprovedbythecompetentauthorityofthecountryofapproval(1);6.2.1.4.3.Theconformityofreceptacles,havingatestpressurecapacityproductofnotmorethan30MPa.litre(300bar.litre)withtheprovisionsofClass2shallbeassessedbyoneofthemethodsdescribedin6.2.1.4.1or6.2.1.4.2orbyoneofthefollowingmethods:(a)thecomplianceofanyreceptaclewithadesign,fullyspecifiedintechnicaldocumentation,shallbedeclaredinwritingbythemanufacturerandreceptaclesofthisdesignshallbetestedunderthesupervisionofatestingandcertifyingbodyapprovedbythecompetentauthorityofthecountryofapproval(1);or(b)thedesigntypeofthereceptaclesshallbeapprovedbyatestingandcertifyingbodyapprovedbythecompetentauthorityofthecountryofapproval(1).Thecomplianceofallreceptacleswiththeapproveddesignshallbedeclaredinwritingbythemanufacturerandallreceptaclesofthistypeshallbetestedindividually.6.2.1.4.4.Therequirementsof6.2.1.4.1to6.2.1.4.3shallbedeemedtobecompliedwith:(a)asregardsthequalityassurancesystemsmentionedin6.2.1.4.1and6.2.1.4.2,iftheyconformtotherelevantEuropeanStandardoftheENISO9000series;(b)intheirentirety,iftherelevantconformityassessmentproceduresofCouncilDirective1999/36/EC(2)havebeencompliedwithasfollows:(i)forthereceptacleslistedunder6.2.1.4.1,themodulesG,orH1,orBincombinationwithD,orBincombinationwithF;(ii)forthereceptacleslistedunder6.2.1.4.2,themodulesH,orBincombinationwithE,orBincombinationC1,orB1incombinationwithF,orB1incombinationwithD;(iii)forthereceptacleslistedunder6.2.1.4.3,themodulesA1,orD1,orE1.6.2.1.4.5.RequirementsformanufacturersThemanufacturershallbetechnicallycompetentandshallpossessallsuitablemeansrequiredforthesatisfactorymanufactureofreceptacles;thisrelatesinparticulartoqualifiedpersonnel:(a)tosupervisetheentiremanufacturingprocess;(b)tocarryoutjoiningofmaterials;(c)tocarryouttherelevanttests.Theproficiencytestofamanufacturershallinallinstancesbecarriedoutbyatestingandcertifyingbodyapprovedbythecompetentauthorityofthecountryofapproval1.Theparticularcertificationprocessthemanufacturerintendstoapplyshallbetakenintoconsideration.6.2.1.4.6.RequirementsfortestingandcertifyingbodiesTestingandcertifyingbodiesshallbeindependentfrommanufacturingenterprisesandtechnologicallycompetenttothedegreerequired.TheserequirementsshallbedeemedtobemetifthebodieshavebeenapprovedonthebasisofanaccreditationprocedureinaccordancewiththerelevantEuropeanstandardsofseriesEN45000.6.2.1.5.Initialinspection6.2.1.5.1.Receptaclesshallbesubjectedtoinitialinspectioninaccordancewiththefollowingspecifications:onanadequatesampleofreceptacles:(a)testingofthematerialofconstructioninrespectatleastofyieldstress,tensilestrength,andpermanentelongationatfracture;(b)measurementofwallthicknessatthethinnestpoint,andcalculationofthestress;(c)checkingthehomogeneityofthematerialforeachmanufacturingbatch,andexaminationoftheexternalandinternalconditionofthereceptacles;OfficialJournaloftheEuropeanUnionEN26.1.2004L18/774(1)IfthecountryofapprovalisnotaMemberState,thecompetentauthorityofaMemberState.(2)CouncilDirective1999/36/ECconcerningtransportablepressureequipment(OJL138,1.6.1999).forallreceptacles:(d)ahydraulicpressuretest.Receptaclesshallwithstandthetestpressurewithoutundergoingpermanentdeformationorexhibitingcracks;NOTEWiththeagreementofthetestingandcertifyingbodyapprovedbythecompetentauthorityofthecountryofapproval(1),thehydraulicpressuretestmaybereplacedbyatestusingagas,wheresuchoperationdoesnotentailanydanger.(e)anexaminationofthemarkingsonthereceptacles,see6.2.1.7;(f)inaddition,receptaclesintendedforthecarriageofUNNo1001acetylene,dissolved,shallhaveaninspectionofthenatureoftheporousmaterialandthequantityofsolvent.6.2.1.5.2.Specificprovisionsapplyingtoaluminiumalloyreceptacles(a)Inadditiontotheinitialinspectionrequiredby6.2.1.5.1,itisnecessarytotestforpossibleintercrystallinecorrosionoftheinsidewallofthereceptacleswhereuseismadeofanaluminiumalloycontainingcopper,orwhereuseismadeofanaluminiumalloycontainingmagnesiumandmanganeseandthemanganesecontentisgreaterthan3,5%orthemanganesecontentlowerthan0,5%.(b)Inthecaseofanaluminium/copperalloythetestshallbecarriedoutbythemanufactureratthetimeofapprovalofanewalloybythecompetentauthority;itshallthereafterberepeatedinthecourseofproduction,foreachpourofthealloy.(c)Inthecaseofanaluminium/magnesiumalloythetestshallbecarriedoutbythemanufactureratthetimeofapprovalofanewalloyandofthemanufacturingprocessbythecompetentauthority.Thetestshallberepeatedwheneverachangeismadeinthecompositionofthealloyorinthemanufacturingprocess.6.2.1.6.Periodicinspection6.2.1.6.1.Refillablereceptaclesshallbesubjectedtoperiodicinspectionsunderthesupervisionofatestingandcertifyingbodyapprovedbythecompetentauthorityofthecountryofapproval(1),inaccordancewiththeperiodicitiesdefinedintherelevantpackinginstructionP200orP203in4.1.4.1andinaccordancewiththefollowingspecifications:(a)externalexaminationofthereceptacle,equipmentandmarkings;(b)internalexaminationofthereceptacle(e.g.byweighing,examinationoftheinternalcondition,checksofwallthickness);(c)thehydraulicpressuretestand,ifnecessary,inspectionofthecharacteristicsofthematerialbysuitabletests;NOTES1.Withtheagreementofthetestingandcertifyingbodyapprovedbythecompetentauthorityofthecountryofapproval(1),thehydraulicpressuretestmaybereplacedbyatestusingagas,wheresuchoperationdoesnotentailanydanger,orbyanequivalentmethodbasedonultrasound.2.Withtheagreementofthetestingandcertifyingbodyapprovedbythecompetentauthorityofthecountryofapproval(1),thehydraulicpressuretestofcylindersandtubesmaybereplacedbyanequivalentmethodbasedonacousticemission.3.Withtheagreementofthetestingandcertifyingbodyapprovedbythecompetentauthorityofthecountryofapproval(1),thehydraulicpressuretestofeachweldedsteelcylinderintendedforthecarriageofgasesofUNNo1965,hydrocarbongasmixtureliquefied,n.o.s.,withacapacitybelow6,5lmaybereplacedbyanothertestensuringanequivalentlevelofsafety.6.2.1.6.2.ForreceptaclesintendedforthecarriageofUNNo1001acetylene,dissolved,onlytheexternalcondition(corrosion,deformation)andtheconditionoftheporousmass(loosening,settlement)shallbeexamined.6.2.1.6.3.Byderogationfrom6.2.1.6.1(c)closedcryogenicreceptaclesshallbesubjectedtoexternalinspectionandtoaleakproofnesstest.Theleakproofnesstestshallbecarriedoutwiththegascontainedinthereceptacleorwithaninertgas.Checkingshallbeperformedbymeansofapressuregaugeorbyvacuummeasurement.Thethermalinsulationneednotberemoved.6.2.1.7.Markingofreceptacles6.2.1.7.1.Refillablereceptaclesshallbearthefollowingparticularsinclearlylegibleanddurablecharacters:(a)themanufacturer'snameormark;(b)theapprovalnumber(ifthedesigntypeofthereceptacleisapprovedaccordingto6.2.1.4);(c)themanufacturer'sserialorbatchnumber;(d)thetareofthereceptaclewithoutfittingsandaccessories,whenthecheckofwallthicknessrequiredduringtheperiodicinspectionisperformedbyweighing;(e)thetestpressure(gaugepressure);OfficialJournaloftheEuropeanUnionEN26.1.2004L18/775(1)IfthecountryofapprovalisnotaMemberState,thecompetentauthorityofaMemberState.(f)thedate(monthandyear)oftheinitialinspectionandthemostrecentperiodicinspection;NOTEThemonthneednotbeindicatedforgasesforwhichtheintervalbetweenperiodicinspectionis10yearsormore(see4.1.4.1packinginstructionsP200(9)andP203(8)).(g)thestampoftheexpertwhocarriedoutthetestsandinspections;(h)inthecaseofUNNo1001acetylene,dissolved:thepermittedfillingpressure(see4.1.4.1,packinginstructionP200(6))andthetotalofthemassof:theemptyreceptacle,thefittingsandaccessories,theporousmassandthesolvent;(i)thewatercapacityinlitres;(j)forcompressedgasesfilledbypressure,themaximumfillingpressureat15°Callowedforthereceptacle;Thesemarksshallbeimmovablyaffixed,e.g.engraved,eitheronareinforcedpartofthereceptacle,onaring,oronimmovablyaffixedattachments.Theycanalsobeengravedonthereceptacledirectly,provideditcanbedemonstratedthatthestrengthofthereceptacleisnotimpairedbythemarking.NOTESeealso5.2.1.6.6.2.1.7.2.Non-refillablereceptaclesshallbearthefollowingparticularsinclearlylegibleanddurablecharacters:(a)themanufacturer'snameormark;(b)theapprovalnumber(ifthedesigntypeofthereceptacleisapprovedaccordingto6.2.1.4);(c)themanufacturer'sserialorbatchnumber;(d)thetestpressure(gaugepressure);(e)thedate(monthandyear)ofmanufacture;(f)thestampoftheexpertwhocarriedouttheinitialinspection;(g)theUNnumberandthepropershippingnameasdeterminedinaccordancewithChapter3.1.InthecaseofgasesclassifiedunderanN.O.S.entry,onlytheUNnumberandthetechnicalname(1)ofthegashavetobeindicated;Inthecaseofmixtures,notmorethanthetwoconstituentswhichmostpredominantlycontributetothehazardshavetobeindicated;(h)Thewords‘DONOTREFILL’;thismarkingshallbeaminimumof6mminheight.Themarksmentionedinthisparagraph,otherthan(g),shallbeimmovablyaffixed,e.g.engraved,eitheronareinforcedpartofthereceptacle,onaring,oronimmovablyaffixedattachments.Theycanalsobeengravedonthereceptacledirectly,provideditcanbedemonstratedthatthestrengthofthereceptacleisnotimpairedbythemarking.6.2.2.Receptaclesdesigned,constructedandtestedaccordingtostandardsTherequirementsof6.2.1areconsideredtohavebeencompliedwithifthefollowingstandards,asrelevant,areapplied:ReferenceTitleofdocumentApplicablesubsectionsandparagraphsformaterialsEN1797-1:1998Cryogenicvessels-Gas/materialcompatibility—Part1:Oxygencompatibility6.2.1.2ENISO11114-1:1997Transportablegascylinders—Compatibilityofcylinderandvalvematerialswithgascontents—Part1:Metallicmaterials6.2.1.2ENISO11114-2:2000Transportablegascylinders—Compatibilityofcylinderandvalvematerialswithgascontents—Part2:Non-metallicmaterials6.2.1.2OfficialJournaloftheEuropeanUnionEN26.1.2004L18/776(1)Insteadofthetechnicalnametheuseofoneofthefollowingnamesispermitted:—forUNNo1078refrigerantgas,n.o.s.:mixtureF1,mixtureF2,mixtureF3,—forUNNo1060methylacetyleneandpropadienemixtures,stabilized:mixtureP1,mixtureP2,—forUNNo1965hydrocarbongasmixture,liquefied,n.o.s.:mixtureAorbutane,mixtureA01orbutane,mixtureA02orbutane,mixtureA0orbutane,mixtureA1,mixtureB1,mixtureB2,mixtureB,mixtureCorpropane.ReferenceTitleofdocumentApplicablesubsectionsandparagraphsEN1252-1:1998Cryogenicvessels-Materials—Part1:Toughnessrequirementsfortemperaturebelow–80°C6.2.1.2forcylindersAnnexI,Parts1to3to84/525/EECCouncilDirectiveontheapproximationofthelawsoftheMemberStatesrelatingtoseamlesssteelgascylinders6.2.1.1and6.2.1.5AnnexI,Parts1to3to84/526/EECCouncilDirectiveontheapproximationofthelawsoftheMemberStatesrelatingtoweldedunalloyedsteelgascylinders6.2.1.1and6.2.1.5AnnexI,Parts1to3to84/527/EECCouncilDirectiveontheapproximationofthelawsoftheMemberStatesrelatingtoseamless,unalloyedaluminiumandaluminiumalloygascylinders6.2.1.1and6.2.1.5EN1442:1998Transportablerefillableweldedsteelcylindersforliquefiedpetroleumgas(LPG)—Designandconstruction6.2.1.1,6.2.1.5and6.2.1.7EN1800:1998/AC:1999Transportablegascylinders—Acetylenecylinders-Basicrequirementsanddefinitions6.2.1.1.2EN1964-1:1999Transportablegascylinders—Specificationsforthedesignandconstructionofrefillabletransportableseamlesssteelgascylindersofcapacityfrom0,5litresupto150litres—Part1:CylindersmadeofseamlesssteelwithaRmvalueoflessthan1100pa6.2.1.1and6.2.1.5EN1975:1999(exceptAnnexG)Transportablegascylinders—Specificationsforthedesignandconstructionofrefillabletransportableseamlessaluminiumandaluminiumalloygascylindersofcapacityfrom0,5litresupto150litres6.2.1.1and6.2.1.5ENISO11120:1999Gascylinders—Refillableseamlesssteeltubesforcompressedgastransportofwatercapacitybetween150litresand3000litres—Design,constructionandtesting6.2.1.1and6.2.1.5EN1964-3:2000Transportablegascylinders-Specificationsforthedesignandconstructionofrefillabletransportableseamlesssteelgascylindersofcapacityfrom0,5litreupto150litre—Part3:Cylindersmadeofstainlesssteel6.2.1.1and6.2.1.5EN12862:2000Transportablegascylinders—Specificationsforthedesignandconstructionofrefillabletransportableweldedaluminiumalloygascylinders6.2.1.1and6.2.1.5EN1251-1:2000Cryogenicvessels—Transportable,vacuuminsulated,ofnotmorethan1000litresvolume—Part1:Fundamentalrequirements6.2.1.7.1EN1251-2:2000Cryogenicvessels—Transportable,vacuuminsulated,ofnotmorethan1000litresvolume—Part2:Design,fabrication,inspectionandtesting6.2.1.1and6.2.1.5EN1251-3:2000Cryogenicvessels—Transportable,vacuuminsulated,ofnotmorethan1000litresvolume—Part3:Operationalrequirements6.2.1.6OfficialJournaloftheEuropeanUnionEN26.1.2004L18/777ReferenceTitleofdocumentApplicablesubsectionsandparagraphsforclosuresEN849:1996(exceptAnnexA)Transportablegascylinders—Cylindervalves:Specificationandtypetesting6.2.1.1formarkingsEN1089-1:1996Transportablegascylinders—Gascylinderidentification(excludingLPG)—Part1:Stampmarking6.2.1.7.1except(b)and6.2.1.7.2except(b)6.2.3.Requirementsforreceptaclesnotdesigned,constructedandtestedaccordingtostandardsReceptaclesnotdesigned,constructedandtestedaccordingtostandardslistedinthetableof6.2.2shallbedesigned,constructedandtestedinaccordancewiththeprovisionsofatechnicalcodeprovidingthesamelevelofsafetyandrecognisedbythecompetentauthority.Therequirementsof6.2.1andthefollowingrequirementshowevershallbemet:6.2.3.1.Metalcylinders,tubes,pressuredrumsandbundlesofcylindersAtthetestpressure,thestressinthemetalatthemostseverelystressedpointofthereceptacleshallnotexceed77%oftheguaranteedminimumyieldstress(Re).‘Yieldstress’meansthestressatwhichapermanentelongationoftwoperthousand(i.e.0,2%)or,forausteniticsteels,1%ofthegaugelengthonthetest-piece,hasbeenproduced.NOTEInthecaseofsheet-metaltheaxisofthetensiletest-pieceshallbeatrightanglestothedirectionofrolling.Thepermanentelongationatfracture,shallbemeasuredonatest-pieceofcircularcross-sectioninwhichthegaugelength‘l’isequaltofivetimesthediameter‘d’(l=5d);iftestpiecesofrectangularcross-sectionareused,thegaugelength‘l’shallbecalculatedbytheformula:whereFoindicatestheinitialcross-sectionalareaofthetest-pieceReceptaclesandtheirclosuresshallbemadeofsuitablematerialswhichshallberesistanttobrittlefractureandtostresscorrosioncrackingbetween–20°Cand+50°C.Forweldedreceptaclesonlymaterialsoffaultlessweldabilitywhoseadequateimpactstrengthatanambienttemperatureof–20°Ccanbeguaranteed,particularlyintheweldseamsandthezonesadjacentthereto,shallbeused.Weldsshallbeskilfullymadeandshallaffordthefullestsafety.Anyadditionalthicknesstoallowforcorrosionshallnotbetakenintoconsiderationincalculatingthethicknessofthewalls.6.2.3.2.Additionalprovisionsrelatingtoaluminium-alloyreceptaclesforcompressedgases,liquefiedgases,gasesdissolvedunderpressureandnon-pressurisedgasessubjecttospecialrequirements(gassamples)aswellasarticlescontaininggasunderpressureotherthanaerosoldispensersandsmallreceptaclescontaininggas(gascartridges)6.2.3.2.1.Thematerialsofaluminium-alloyreceptacleswhicharetobeacceptedshallsatisfythefollowingrequirements:ABCDTensilestrength,Rm,inMPa(=N/mm2)49to186196to372196to372343to490Yieldstress,Re,inMpa(=N/mm2)(permanentsetg=0,2%)10to16759to314137to334206to412Permanentelongationatfracture(l=5d)inpercent12to4012to3012to3011to16OfficialJournaloftheEuropeanUnionEN26.1.2004L18/778ABCDBendtest(diameterofformerd=n×e,whereeisthethicknessofthetestpiece)n=5(Rm≤98)n=6(Rm>98)n=6(Rm≤325)n=7(Rm>325)n=6(Rm≤325)n=7(Rm>325)n=7(Rm≤392)n=8(Rm>392)AluminiumAssociationSeriesNumber(a)1000500060002000(a)See‘aluminiumstandardsanddata’,Fifthedition,January1976,publishedbytheAluminiumAssociation,750ThirdAvenue,NewYork.Theactualpropertieswilldependonthecompositionofthealloyconcernedandonthefinaltreatmentofthereceptacle,butwhateveralloyisusedthethicknessofthereceptacleshallbecalculatedbyoneofthefollowingformulae:wheree=minimumthicknessofreceptaclewall,inmm;PMpa=testpressure,inMPaPbar=testpressure,inbarD=nominalexternaldiameterofthereceptacle,inmm;andRe=guaranteedminimumproofstresswith0,2%proofstress,inMpa(=N/mm2)Inaddition,thevalueoftheminimumguaranteedproofstress(Re)introducedintotheformulaisinnocasetobegreaterthan0,85timestheguaranteedminimumtensilestrength(Rm),whateverthetypeofalloyused.NOTES1.Theabovecharacteristicsarebasedonpreviousexperiencewiththefollowingmaterialsusedforreceptacles:ColumnA:Aluminium,unalloyed,99,5gpure;ColumnB:Alloysofaluminiumandmagnesium;ColumnC:Alloysofaluminium,siliconandmagnesium,suchasISO/R209-Al-Si-Mg(AluminiumAssociation6351);ColumnD:Alloysofaluminium,copperandmagnesium.2.Thepermanentelongationatfractureismeasuredbymeansoftest-piecesofcircularcross-sectioninwhichthegaugelength‘l’isequaltofivetimesthediameter‘d’(l=5d);iftest-piecesofrectangularsectionareusedthegaugelengthshallbecalculatedbytheformula:whereFoistheinitialcross-sectionareaofthetest-piece.3.a)Thebendtest(seediagram)shallbecarriedoutonspecimensobtainedbycuttingintotwoequalpartsofwidth3e,butinnocaselessthan25mm,anannularsectionofacylinder.Thespecimensshallnotbemachinedelsewherethanontheedges.(b)Thebendtestshallbecarriedoutbetweenamandrelofdiameter(d)andtwocircularsupportsseparatedbyadistanceof(d+3e).Duringthetesttheinnerfacesshallbeseparatedbyadistancenotgreaterthanthediameterofthemandrel.(c)Thespecimenshallnotexhibitcrackswhenithasbeenbentinwardsaroundthemandreluntiltheinnerfacesareseparatedbyadistancenotgreaterthanthediameterofthemandrel.(d)Theratio(n)betweenthediameterofthemandrelandthethicknessofthespecimenshallconformtothevaluesgiveninthetable.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/7796.2.3.2.2.Alowerminimumelongationvalueisacceptableonconditionthatanadditionaltestapprovedbythecompetentauthorityofthecountryinwhichthereceptaclesaremadeprovesthatsafetyofcarriageisensuredtothesameextentasinthecaseofreceptaclesconstructedtocomplywiththecharacteristicsgiveninthetablein6.2.3.2.1(seealsoannexGtoEN1975:1999).6.2.3.2.3.Thewallthicknessofthereceptaclesatthethinnestpointshallbethefollowing:—wherethediameterofthereceptacleislessthan50mm:notlessthan1,5mm,—wherethediameterofthereceptacleisfrom50to150mm:notlessthan2mm,and—wherethediameterofthereceptacleismorethan150mm:notlessthan3mm.6.2.3.2.4.Theendsofthereceptaclesshallhaveasemicircular,ellipticalor‘basket-handle’section;theyshallaffordthesamedegreeofsafetyasthebodyofthereceptacle.6.2.3.3.ReceptaclesincompositematerialsForcompositecylinders,tubes,pressuredrumsandbundlesofcylinderswhichmakeuseofcompositematerialsi.e.comprisingalinerhoopwrappedorfullywrappedwithreinforcementmaterial,theconstructionshallbesuchthataminimumburstratio(burstpressuredividedbytestpressure)is:—1,67forhoopwrappedreceptacles,—2,00forfullywrappedreceptacles.6.2.3.4.ClosedcryogenicreceptaclesThefollowingrequirementsapplytotheconstructionofclosedcryogenicreceptaclesforrefrigeratedliquefiedgases.6.2.3.4.1.Allthemechanicalandtechnologicalcharacteristicsofthemetalusedshallbeestablishedforeachreceptacleattheinitialinspection;withregardtotheimpactstrength,see6.8.5.3.6.2.3.4.2.Ifothermaterialsareused,theyshallresistbrittlefractureatthelowestworkingtemperatureofthereceptacleanditsfittings.6.2.3.4.3.Receptaclesshallbefittedwithasafetyvalvewhichshallbecapableofopeningattheworkingpressureshownonthereceptacle.Thevalvesshallbesoconstructedastoworkperfectlyevenattheirlowestworkingtemperature.Theirreliabilityoffunctioningatthattemperatureshallbeestablishedandcheckedbytestingeachvalveorasampleofvalvesofthesametypeofconstruction.6.2.3.4.4.Theventsandsafetyvalvesofreceptaclesshallbesodesignedastopreventtheliquidfromsplashingout.6.2.3.4.5.Receptacleswhosefillingismeasuredbyvolumeshallbeprovidedbyalevelindicator.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/7806.2.3.4.6.Thereceptaclesshallbethermallyinsulated.Thethermalinsulationshallbeprotectedagainstimpactbymeansofcontinuoussheathing.Ifthespacebetweenthereceptacleandthesheathingisairless(vacuum-insulation),theprotectivesheathingshallbedesignedtowithstandwithoutdeformationanexternalpressureofatleast100kPa(1bar).Ifthesheathingissoclosedastobegas-tight(e.g.inthecaseofvacuum-insulation),adeviceshallbeprovidedtopreventanydangerouspressurefromdevelopingintheinsulatinglayerintheeventofinadequategas-tightnessofthereceptacleoritsfittings.Thedeviceshallpreventmoisturefrompenetratingintotheinsulation.6.2.4.Generalrequirementsforaerosoldispensersandsmallreceptaclescontaininggas(gascartridges)6.2.4.1.Designandconstruction6.2.4.1.1.Aerosoldispensers(UNNo1950aerosols)containingonlyagasoramixtureofgases,andsmallreceptaclescontaininggas(gascartridges)(UNNo2037),shallbemadeofmetal.Thisrequirementshallnotapplytoaerosolsandsmallreceptaclescontaininggas(gascartridges)withamaximumcapacityof100mlforUNNo1011butane.Otheraerosoldispensers(UNNo1950aerosols)shallbemadeofmetal,syntheticmaterialorglass.Receptaclesmadeofmetalandhavinganoutsidediameterofnotlessthan40mmshallhaveaconcavebottom.6.2.4.1.2.Thecapacityofreceptaclesmadeofmetalshallnotexceed1000ml;thatofreceptaclesmadeofsyntheticmaterialorofglassshallnotexceed500ml.6.2.4.1.3.Eachmodelofreceptacles(aerosoldispensersorcartridges)shall,beforebeingputintoservice,satisfyahydraulicpressuretestcarriedoutinconformitywith6.2.4.2.6.2.4.1.4.Thereleasevalvesanddispersaldevicesofaerosoldispensers(UNNo1950aerosols)andthevalvesofUNNo2037smallreceptaclescontaininggas(gascartridges)shallensurethatthereceptaclesaresoclosedastobeleakproofandshallbeprotectedagainstaccidentalopening.Valvesanddispersaldeviceswhichcloseonlybytheactionoftheinternalpressurearenottobeaccepted.6.2.4.2.Initialtesting6.2.4.2.1.Theinternalpressuretobeapplied(testpressure)shallbe1,5timestheinternalpressureat50°C,withaminimumpressureof1MPa(10bar).6.2.4.2.2.Thehydraulicpressuretestsshallbecarriedoutonatleastfiveemptyreceptaclesofeachmodel:(a)untiltheprescribedtestpressureisreached,bywhichtimenoleakageorvisiblepermanentdeformationshallhaveoccurred;and(b)untilleakageorburstingoccurs;thedishedend,ifany,shallyieldfirstandthereceptacleshallnotleakorburstuntilapressure1,2timesthetestpressurehasbeenreachedorpassed.6.2.4.3.ReferencetostandardsTherequirementsofthisparagrapharedeemedtobemetifthefollowingstandardsarecompliedwith:—foraerosoldispensers(UNNo1950aerosols):AnnextoCouncilDirective75/324/EEC(1)asamendedbyCommissionDirective94/1/EC(2),—forUNNo2037,smallrecipientscontaininggas(gascartridges)containingUNNo1965,hydrocarbongasmixturen.o.s.liquefied:EN417:1992non-refillablemetallicgascartridgesforliquefiedpetroleumgases,withorwithoutavalve,forusewithportableappliances—Construction,inspection,testingandmarking.CHAPTER6.3Requirementsfortheconstructionandtestingofpackagingsforclass6.2substancesNOTETherequirementsofthischapterdonotapplytopackagingsusedforthecarriageofClass6.2substancesaccordingtopackinginstructionP621of4.1.4.1.6.3.1.General6.3.1.1.Apackagingthatmeetstherequirementsofthissectionandof6.3.2may,afterdecisionbythecompetentauthority,bemarkedwith:(a)theUnitedNationspackagingsymbol;OfficialJournaloftheEuropeanUnionEN26.1.2004L18/781(1)OJL147,9.6.1975,p.40.(2)OJL23,28.1.1994,p.28.(b)thecodedesignatingthetypeofpackagingaccordingtotherequirementsof6.1.2;(c)thetext‘CLASS6.2’;(d)thelasttwodigitsoftheyearofmanufactureofthepackaging;(e)thestateauthorisingtheallocationofthemark,indicatedbythedistinguishingsignformotorvehiclesininternationaltraffic(1);(f)thenameofthemanufacturerorotheridentificationofthepackagingspecifiedbythecompetentauthority;(g)forpackagingsmeetingtherequirementsof6.3.2.9,theletter‘U’,insertedimmediatelyfollowingthemarkingrequiredin(b).6.3.1.2.Exampleofmarking4G/CLASS6.2/92asin6.3.1.1(a),(b),(c)and(d)S/SP-9989-ERIKSSONasin6.3.1.1(e),(f)6.3.2.Testrequirementsforpackagings6.3.2.1.Otherthanforpackagingsforliveanimalsandorganisms,samplesofeachpackagingshallbepreparedfortestingasdescribedin6.3.2.2andthensubjectedtothetestsin6.3.2.4to6.3.2.6.Ifthenatureofthepackagingmakesitnecessary,equivalentpreparationandtestsarepermitted,providedthatthesemaybedemonstratedtobeatleastaseffective.6.3.2.2.Samplesofeachpackagingshallbepreparedasforcarriage,exceptthatthesubstancetobecarriedshallbereplacedbywateror,whereconditioningat–18°Cisspecified,bywater/anti-freeze.Eachprimaryreceptacleshallbefilledto98%capacity.6.3.2.3.TestsrequiredMaterialofTestsrequiredouterpackagingOtherReferto6.3.2.5Referto6.3.2.6innerpacka-gingFibre-boardPlasticsPlasticsOther(a)(b)(c)(d)xxxxwhendryiceisusedxxxxxxxxxxxxxxxxxxxxx6.3.2.4.Packagingspreparedasforcarriageshallbesubjectedtothetestsin6.3.2.3,which,fortestpurposes,categorisespackagingsaccordingtotheirmaterialcharacteristics.Forouterpackagings,theheadingsinthetablerelatetofibreboardorsimilarmaterialswhoseperformancemayberapidlyaffectedbymoisture;plasticswhichmayembrittleatlowtemperatureandothermaterialssuchasmetalwhoseperformanceisnotaffectedbymoistureortemperature.Ifaprimaryreceptacleandasecondarypackagingaremadeofdifferentmaterials,thematerialoftheprimaryreceptacledeterminestheappropriatetest.Ininstanceswhereaprimaryreceptacleismadeoftwomaterials,thematerialmostliabletodamageshalldeterminetheappropriatetests.6.3.2.5.(a)Samplesshallbesubjectedtofree-falldropsontoarigid,non-resilient,flat,horizontalsurfacefromaheightof9m.Wherethesamplesareintheshapeofabox,fiveshallbedroppedinsequence:(i)oneflatontothebase,(ii)oneflatontothetop,OfficialJournaloftheEuropeanUnionEN26.1.2004L18/782(1)DistinguishingsignformotorvehiclesininternationaltrafficprescribedinViennaConventiononRoadTraffic(1968).(iii)oneflatontothelongside,(iv)oneflatontotheshortside,(v)oneontoacorner.Wherethesamplesareintheshapeofadrum,threeshallbedroppedinsequence:(vi)onediagonallyontothetopchime,withthecentreofgravitydirectlyabovethepointofimpact,(vii)onediagonallyontothebasechime,(viii)oneflatontotheside.Followingtheappropriatedropsequence,thereshallbenoleakagefromtheprimaryreceptacle(s)whichshallremainprotectedbyabsorbentmaterialinthesecondarypackaging.NOTEWhilethesampleshallbereleasedintherequiredorientation,itisacceptedthatforaerodynamicreasonstheimpactmaynottakeplaceinthatorientation.(b)Thesamplesshallbesubjectedtoawaterspraythatsimulatesexposuretorainfallofapproximately5cmperhourforatleastonehour.Itshallthenbesubjectedtothetestdescribedin(a).(c)Thesamplesshallbeconditionedinanatmosphereof–18°Corlessforaperiodofatleast24hoursandwithin15minutesofremovalfromthatatmospherebesubjectedtothetestdescribedin(a).Wherethesamplescontaindryice,theconditioningperiodmaybereducedtofourhours.(d)Wherethepackagingisintendedtocontaindryice,atestadditionaltothatspecifiedin(a)or(b)or(c)shallbecarriedout.Onesampleshallbestoredsothatallthedryicedissipatesandthenbesubjectedtothetestdescribedin(a).6.3.2.6.Packagingswithagrossmassof7kgorlessshallbesubjectedtothetestsdescribedin(a)belowandpackagingswithagrossmassexceeding7kgtothetestsin(b)below.(a)Samplesshallbeplacedonalevelhardsurface.Acylindricalsteelrodwithamassofatleast7kg,adiameternotexceeding38mmandwhoseimpactendedgeshavearadiusnotexceeding6mm,shallbedroppedinaverticalfreefallfromaheightof1m,measuredfromtheimpactendtotheimpactsurfaceofthesample.Onesampleshallbeplacedonitsbase.Asecondsampleshallbeplacedinanorientationperpendiculartothatusedforthefirst.Ineachinstancethesteelrodshallbeaimedtoimpacttheprimaryreceptacle.Followingeachimpact,penetrationofthesecondarypackagingisacceptable,providedthatthereisnoleakagefromtheprimaryreceptacle(s).(b)Samplesshallbedroppedontotheendofacylindricalsteelrod.Therodshallbesetverticallyinalevelhardsurface.Itshallhaveadiameterof38mmandtheedgesoftheupperendaradiusnotexceeding6mm.Therodshallprotrudefromthesurfaceadistanceatleastequaltothatbetweentheprimaryreceptacle(s)andtheoutersurfaceoftheouterpackagingwithaminimumof200mm.Onesampleshallbedroppedinaverticalfreefallfromaheightof1m,measuredfromthetopofthesteelrod.Asecondsampleshallbedroppedfromthesameheightinanorientationperpendiculartothatusedforthefirst.Ineachinstance,thepackagingshallbesoorientatedthatthesteelrodcouldpenetratetheprimaryreceptacle(s).Followingeachimpact,thereshallbenoleakagefromtheprimaryreceptacle(s).6.3.2.7.Thecompetentauthoritymaypermittheselectivetestingofpackagingsthatdifferonlyinminorrespectsfromatestedtype,e.g.smallersizesofinnerpackagingsorinnerpackagingsoflowernetmass;andpackagingssuchasdrums,bagsandboxeswhichareproducedwithsmallreductionsinexternaldimension(s).6.3.2.8.Providedanequivalentlevelofperformanceismaintained,thefollowingvariationsintheprimaryreceptaclesplacedwithinasecondarypackagingareallowedwithouttheneedforfurthertestingofthecompletedpackaging:(a)Primaryreceptaclesofequivalentorsmallersizeascomparedtothetestedprimaryreceptaclesmaybeusedprovided:(i)theprimaryreceptaclesareofsimilardesigntotheprimaryreceptacletested(e.g.shape:round,rectangular,etc.);(ii)thematerialofconstructionoftheprimaryreceptacles(e.g.glass,plastics,metal)offersresistancetoimpactandstackingforcesequivalenttoorbetterthanthatoftheprimaryreceptaclesoriginallytested;(iii)theprimaryreceptacleshavethesameorsmalleropeningsandtheclosureisofequivalentdesign(e.g.screwcap,frictionlid,etc.);(iv)sufficientadditionalcushioningmaterialisusedtotakeupemptyspacesandtopreventsignificantmovementoftheprimaryreceptacles;and(v)primaryreceptaclesareorientedwithinthesecondarypackagingsinthesamemannerasinthetestedpackage.(b)Alessernumberofthetestedprimaryreceptacles,orofthealternativetypesofprimaryreceptaclesidentifiedin(a),maybeusedprovidedsufficientcushioningisaddedtofillthevoidspace(s)andtopreventsignificantmovementoftheprimaryreceptacles.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/7836.3.2.9.Innerreceptaclesofanytypemaybeassembledwithinanintermediate(secondary)packagingandcarriedwithouttestingintheouterpackagingunderthefollowingconditions:(a)theintermediate/outerpackagingcombinationshallhavebeensuccessfullytestedinaccordancewith6.3.2.3withfragile(e.g.glass)innerreceptacles;(b)thetotalcombinedgrossmassofinnerreceptaclesshallnotexceedonehalfthegrossmassofinnerreceptaclesusedforthedroptestin(a);(c)thethicknessofcushioningbetweeninnerreceptaclesandbetweeninnerreceptaclesandtheoutsideoftheintermediatepackagingshallnotbereducedbelowthecorrespondingthicknessesintheoriginallytestedpackaging;andifasingleinnerreceptaclewasusedintheoriginaltest,thethicknessofcushioningbetweeninnerreceptaclesshallnotbelessthanthethicknessofcushioningbetweentheoutsideoftheintermediatepackagingandtheinnerreceptacleintheoriginaltest.Wheneitherfewerorsmallerinnerreceptaclesareused(ascomparedtotheinnerreceptaclesusedinthedroptest),sufficientadditionalcushioningmaterialshallbeusedtotakeupthevoid;(d)theouterpackagingshallhavesuccessfullypassedthestackingtestin6.1.5.6whileempty.Thetotalmassofidenticalpackagesshallbebasedonthecombinedmassofinnerreceptaclesusedinthedroptestin(a);(e)forinnerreceptaclescontainingliquids,anadequatequantityofabsorbentmaterialtoabsorbtheentireliquidcontentoftheinnerreceptaclesshallbepresent;(f)iftheouterpackagingisintendedtocontaininnerreceptaclesforliquidsandisnotleakproof,orisintendedtocontaininnerreceptaclesforsolidsandisnotsiftproof,ameansofcontaininganyliquidorsolidcontentsintheeventofleakageshallbeprovidedintheformofaleakproofliner,plasticsbagorotherequallyeffectivemeansofcontainment;(g)inadditiontothemarkingsprescribedin6.3.1.1(a)to(f),packagingsshallbemarkedinaccordancewith6.3.1.1(g).CHAPTER6.4Requirementsfortheconstruction,testingandapprovalofpackagesandmaterialofclass76.4.1.(Reserved)6.4.2.Generalrequirements6.4.2.1.Thepackageshallbesodesignedinrelationtoitsmass,volumeandshapethatitcanbeeasilyandsafelycarried.Inaddition,thepackageshallbesodesignedthatitcanbeproperlysecuredinoronthevehicleduringcarriage.6.4.2.2.Thedesignshallbesuchthatanyliftingattachmentsonthepackagewillnotfailwhenusedintheintendedmannerandthat,iffailureoftheattachmentsshouldoccur,theabilityofthepackagetomeetotherrequirementsofthisAnnexwouldnotbeimpaired.Thedesignshalltakeaccountofappropriatesafetyfactorstocoversnatchlifting.6.4.2.3.Attachmentsandanyotherfeaturesontheoutersurfaceofthepackagewhichcouldbeusedtoliftitshallbedesignedeithertosupportitsmassinaccordancewiththerequirementsof6.4.2.2orshallberemovableorotherwiserenderedincapableofbeingusedduringcarriage.6.4.2.4.Asfaraspracticable,thepackagingshallbesodesignedandfinishedthattheexternalsurfacesarefreefromprotrudingfeaturesandcanbeeasilydecontaminated.6.4.2.5.Asfaraspracticable,theouterlayerofthepackageshallbesodesignedastopreventthecollectionandtheretentionofwater.6.4.2.6.Anyfeaturesaddedtothepackageatthetimeofcarriagewhicharenotpartofthepackageshallnotreduceitssafety.6.4.2.7.Thepackageshallbecapableofwithstandingtheeffectsofanyacceleration,vibrationorvibrationresonancewhichmayariseunderroutineconditionsofcarriagewithoutanydeteriorationintheeffectivenessoftheclosingdevicesonthevariousreceptaclesorintheintegrityofthepackageasawhole.Inparticular,nuts,boltsandothersecuringdevicesshallbesodesignedastopreventthemfrombecominglooseorbeingreleasedunintentionally,evenafterrepeateduse.6.4.2.8.Thematerialsofthepackagingandanycomponentsorstructuresshallbephysicallyandchemicallycompatiblewitheachotherandwiththeradioactivecontents.Accountshallbetakenoftheirbehaviourunderirradiation.6.4.2.9.Allvalvesthroughwhichtheradioactivecontentscouldotherwiseescapeshallbeprotectedagainstunauthorisedoperation.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/7846.4.2.10.Thedesignofthepackageshalltakeintoaccountambienttemperaturesandpressuresthatarelikelytobeencounteredinroutineconditionsofcarriage.6.4.2.11.Forradioactivematerialhavingotherdangerouspropertiesthepackagedesignshalltakeintoaccountthoseproperties;see2.1.3.5.3and4.1.9.1.5.6.4.3.(Reserved)6.4.4.RequirementsforexceptedpackagesAnexceptedpackageshallbedesignedtomeettherequirementsspecifiedin6.4.2.6.4.5.Requirementsforindustrialpackages6.4.5.1.IndustrialpackagesTypes1,2,and3(TypesIP-1,IP-2,andIP-3)shallmeettherequirementsspecifiedin6.4.2and6.4.7.2.6.4.5.2.AnindustrialpackageType2(TypeIP-2)shall,ifitweresubjectedtothetestsspecifiedin6.4.15.4and6.4.15.5,prevent:(a)lossordispersaloftheradioactivecontents;and(b)lossofshieldingintegritywhichwouldresultinmorethana20%increaseintheradiationlevelatanyexternalsurfaceofthepackage.6.4.5.3.AnindustrialpackageType3(TypeIP-3)shallmeetalltherequirementsspecifiedin6.4.7.2to6.4.7.15.6.4.5.4.AlternativerequirementsforindustrialpackagesTypes2and3(TypesIP-2andIP-3)6.4.5.4.1.PackagesmaybeusedasIndustrialpackageType2(TypeIP-2)providedthat:(a)theysatisfytherequirementsof6.4.5.1;(b)theyaredesignedtoconformtothestandardsprescribedinChapter6.1orotherrequirementsatleastequivalenttothosestandards;and(c)whensubjectedtothetestsrequiredforpackinggroupsIorIIinChapter6.1,theywouldprevent:(i)lossordispersaloftheradioactivecontents;and(ii)lossofshieldingintegritywhichwouldresultinmorethana20%increaseintheradiationlevelatanyexternalsurfaceofthepackage.6.4.5.4.2.Tank-containersandportabletanksmayalsobeusedasindustrialpackageTypes2or3(TypesIP-2orIP-3),providedthat:(a)theysatisfytherequirementsof6.4.5.1;(b)theyaredesignedtoconformtothestandardsprescribedinChapter6.7orChapter6.8,orotherrequirementsatleastequivalenttothosestandards,andarecapableofwithstandingatestpressureof265kPa;and(c)Theyaredesignedsothatanyadditionalshieldingwhichisprovidedshallbecapableofwithstandingthestaticanddynamicstressesresultingfromhandlingandroutineconditionsofcarriageandofpreventingalossofshieldingintegritywhichwouldresultinmorethana20%increaseintheradiationlevelatanyexternalsurfaceoftheportabletanksortank-containers.6.4.5.4.3.Tanks,otherthanportabletanksandtank-containers,mayalsobeusedasindustrialpackageTypes2or3(TypesIP-2orIP-3)forcarryingLSA-IandLSA-IIliquidsandgasesasprescribedinTable4.1.9.2.4,providedthattheyconformtostandardsatleastequivalenttothoseprescribedin6.4.5.4.2.6.4.5.4.4.ContainersmayalsobeusedasindustrialpackageTypes2or3(TypesIP-2orIP-3),providedthat:(a)theradioactivecontentsarerestrictedtosolidmaterials;(b)theysatisfytherequirementsof6.4.5.1;and(c)theyaredesignedtoconformtoISO1496-1:1990:‘Series1containers—Specificationsandtesting—Part1:generalcargocontainers’excludingdimensionsandratings.Theyshallbedesignedsuchthatifsubjectedtothetestsprescribedinthatdocumentandtheaccelerationsoccurringduringroutineconditionsofcarriagetheywouldprevent:(i)lossordispersaloftheradioactivecontents;and(ii)lossofshieldingintegritywhichwouldresultinmorethana20%increaseintheradiationlevelatanyexternalsurfaceofthecontainers.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/7856.4.5.4.5.MetalintermediatebulkcontainersmayalsobeusedasindustrialpackageType2or3(TypeIP-2orIP-3)providedthat:(a)theysatisfytherequirementsof6.4.5.1;and(b)theyaredesignedtoconformtothestandardsandtestsprescribedinChapter6.5forpackinggroupsIorII,butwiththedroptestconductedinthemostdamagingorientation,theywouldprevent:(i)lossordispersaloftheradioactivecontents;and(ii)lossofshieldingintegritywhichwouldresultinmorethana20%increaseintheradiationlevelatanyexternalsurfaceoftheintermediatebulkcontainer.6.4.6.Requirementsforpackagescontaininguraniumhexafluoride6.4.6.1.Exceptasallowedin6.4.6.4,uraniumhexafluorideshallbepackagedandcarriedinaccordancewiththeprovisionsofISO7195:1993‘Packagingofuraniumhexafluoride(UF6)fortransport’,andtherequirementsof6.4.6.2and6.4.6.3.ThepackageshallalsomeettherequirementsprescribedelsewhereinthisDirectivewhichpertaintotheradioactiveandfissilepropertiesofthematerial.6.4.6.2.Eachpackagedesignedtocontain0,1kgormoreofuraniumhexafluorideshallbedesignedsothatitwouldmeetthefollowingrequirements:(a)withstandwithoutleakageandwithoutunacceptablestress,asspecifiedinISO7195:1993,thestructuraltestasspecifiedin6.4.21.5;(b)withstandwithoutlossordispersaloftheuraniumhexafluoridethetestspecifiedin6.4.15.4;and(c)withstandwithoutruptureofthecontainmentsystemthetestspecifiedin6.4.17.3.6.4.6.3.Packagesdesignedtocontain0,1kgormoreofuraniumhexafluorideshallnotbeprovidedwithpressurereliefdevices.6.4.6.4.Subjecttotheapprovalofthecompetentauthority,packagesdesignedtocontain0,1kgormoreofuraniumhexafluoridemaybecarriedif:(a)thepackagesaredesignedtorequirementsotherthanthosegiveninISO7195:1993and6.4.6.2and6.4.6.3but,notwithstanding,therequirementsof6.4.6.2and6.4.6.3aremetasfaraspracticable;(b)thepackagesaredesignedtowithstandwithoutleakageandwithoutunacceptablestressatestpressurelessthan2,76MPaasspecifiedin6.4.21.5;or(c)forpackagesdesignedtocontain9000kgormoreofuraniumhexafluoride,thepackagesdonotmeettherequirementof6.4.6.2(c).6.4.7.RequirementsforTypeApackages6.4.7.1.TypeApackagesshallbedesignedtomeetthegeneralrequirementsof6.4.2andof6.4.7.2to6.4.7.17.6.4.7.2.Thesmallestoverallexternaldimensionofthepackageshallnotbelessthan10cm.6.4.7.3.Theoutsideofthepackageshallincorporateafeaturesuchasaseal,whichisnotreadilybreakableandwhich,whileintact,willbeevidencethatithasnotbeenopened.6.4.7.4.Anytie-downattachmentsonthepackageshallbesodesignedthat,undernormalandaccidentconditionsofcarriage,theforcesinthoseattachmentsshallnotimpairtheabilityofthepackagetomeettherequirementsofthisDirective.6.4.7.5.Thedesignofthepackageshalltakeintoaccounttemperaturesrangingfrom–40Cto+70Cforthecomponentsofthepackaging.Attentionshallbegiventofreezingtemperaturesforliquidsandtothepotentialdegradationofpackagingmaterialswithinthegiventemperaturerange.6.4.7.6.Thedesignandmanufacturingtechniquesshallbeinaccordancewithnationalorinternationalstandards,orotherrequirements,acceptabletothecompetentauthority.6.4.7.7.Thedesignshallincludeacontainmentsystemsecurelyclosedbyapositivefasteningdevicewhichcannotbeopenedunintentionallyorbyapressurewhichmayarisewithinthepackage.6.4.7.8.Specialformradioactivematerialmaybeconsideredasacomponentofthecontainmentsystem.6.4.7.9.Ifthecontainmentsystemformsaseparateunitofthepackage,itshallbecapableofbeingsecurelyclosedbyapositivefasteningdevicewhichisindependentofanyotherpartofthepackaging.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/7866.4.7.10.Thedesignofanycomponentofthecontainmentsystemshalltakeintoaccount,whereapplicable,theradiolyticdecompositionofliquidsandothervulnerablematerialsandthegenerationofgasbychemicalreactionandradiolysis.6.4.7.11.Thecontainmentsystemshallretainitsradioactivecontentsunderareductionofambientpressureto60kPa.6.4.7.12.Allvalves,otherthanpressurereliefvalves,shallbeprovidedwithanenclosuretoretainanyleakagefromthevalve.6.4.7.13.Aradiationshieldwhichenclosesacomponentofthepackagespecifiedasapartofthecontainmentsystemshallbesodesignedastopreventtheunintentionalreleaseofthatcomponentfromtheshield.Wheretheradiationshieldandsuchcomponentwithinitformaseparateunit,theradiationshieldshallbecapableofbeingsecurelyclosedbyapositivefasteningdevicewhichisindependentofanyotherpackagingstructure.6.4.7.14.Apackageshallbesodesignedthatifitweresubjectedtothetestsspecifiedin6.4.15,itwouldprevent:(a)lossordispersaloftheradioactivecontents;and(b)lossofshieldingintegritywhichwouldresultinmorethana20%increaseintheradiationlevelatanyexternalsurfaceofthepackage.6.4.7.15.Thedesignofapackageintendedforliquidradioactivematerialshallmakeprovisionforullagetoaccommodatevariationsinthetemperatureofthecontents,dynamiceffectsandfillingdynamics.TypeApackagestocontainliquids6.4.7.16.ATypeApackagedesignedtocontainliquidsshall,inaddition:(a)beadequatetomeettheconditionsspecifiedin6.4.7.14aboveifthepackageissubjectedtothetestsspecifiedin6.4.16;andeitherb)(i)beprovidedwithsufficientabsorbentmaterialtoabsorbtwicethevolumeoftheliquidcontents.Suchabsorbentmaterialshallbesuitablypositionedsoastocontacttheliquidintheeventofleakage;or(ii)beprovidedwithacontainmentsystemcomposedofprimaryinnerandsecondaryoutercontainmentcomponentsdesignedtoensureretentionoftheliquidcontents,withinthesecondaryoutercontainmentcomponents,eveniftheprimaryinnercomponentsleak.TypeApackagestocontaingas6.4.7.17.Apackagedesignedforgasesshallpreventlossordispersaloftheradioactivecontentsifthepackageweresubjectedtothetestsspecifiedin6.4.16.ATypeApackagedesignedfortritiumgasorfornoblegasesshallbeexceptedfromthisrequirement.6.4.8.RequirementsforTypeB(U)packages6.4.8.1.TypeB(U)packagesshallbedesignedtomeettherequirementsspecifiedin6.4.2,andof6.4.7.2to6.4.7.15,exceptasspecifiedin6.4.7.14(a),and,inaddition,therequirementsspecifiedin6.4.8.2to6.4.8.15.6.4.8.2.Apackageshallbesodesignedthat,undertheambientconditionsspecifiedin6.4.8.4and6.4.8.5heatgeneratedwithinthepackagebytheradioactivecontentsshallnot,undernormalconditionsofcarriage,asdemonstratedbythetestsin6.4.15,adverselyaffectthepackageinsuchawaythatitwouldfailtomeettheapplicablerequirementsforcontainmentandshieldingifleftunattendedforaperiodofoneweek.Particularattentionshallbepaidtotheeffectsofheat,whichmay:(a)alterthearrangement,thegeometricalformorthephysicalstateoftheradioactivecontentsor,iftheradioactivematerialisenclosedinacanorreceptacle(forexample,cladfuelelements),causethecan,receptacleorradioactivematerialtodeformormelt;or(b)lessentheefficiencyofthepackagingthroughdifferentialthermalexpansionorcrackingormeltingoftheradiationshieldingmaterial;or(c)incombinationwithmoisture,acceleratecorrosion.6.4.8.3.Apackageshallbesodesignedthat,undertheambientconditionspecifiedin6.4.8.4,thetemperatureoftheaccessiblesurfacesofapackageshallnotexceed50°C,unlessthepackageiscarriedunderexclusiveuse.6.4.8.4.Theambienttemperatureshallbeassumedtobe38C.6.4.8.5.ThesolarinsolationconditionsshallbeassumedtobeasspecifiedinTable6.4.8.5.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/787Table6.4.8.5:InsolationdataFormandlocationofsurfaceInsolationfor12hoursperday(W/m2)Flatsurfacescarriedhorizontally:—basenone—othersurfaces800Flatsurfacesnotcarriedhorizontally:—eachsurface200(a)Curvedsurfaces400(a)(a)Alternatively,asinefunctionmaybeused,withanabsorptioncoefficientadoptedandtheeffectsofpossiblereflectionfromneighbouringobjectsneglected.6.4.8.6.Apackagewhichincludesthermalprotectionforthepurposeofsatisfyingtherequirementsofthethermaltestspecifiedin6.4.17.3shallbesodesignedthatsuchprotectionwillremaineffectiveifthepackageissubjectedtothetestsspecifiedin6.4.15and6.4.17.2(a)and(b)or6.4.17.2(b)and(c),asappropriate.Anysuchprotectionontheexteriorofthepackageshallnotberenderedineffectivebyripping,cutting,skidding,abrasionorroughhandling.6.4.8.7.Apackageshallbesodesignedthat,ifitweresubjectedto:(a)thetestsspecifiedin6.4.15,itwouldrestrictthelossofradioactivecontentstonotmorethan10-6A2perhour;and(b)thetestsspecifiedin6.4.17.1,6.4.17.2(b),6.4.17.3,and6.4.17.4andthetestsin(i)6.4.17.2(c),whenthepackagehasamassnotgreaterthan500kg,anoveralldensitynotgreaterthan1000kg/m3basedontheexternaldimensions,andradioactivecontentsgreaterthan1000A2notasspecialformradioactivematerial,or(ii)6.4.17.2(a),forallotherpackages,itwouldmeetthefollowingrequirements:—retainsufficientshieldingtoensurethattheradiationlevelat1mfromthesurfaceofthepackagewouldnotexceed10mSv/hwiththemaximumradioactivecontentswhichthepackageisdesignedtocontain,and—restricttheaccumulatedlossofradioactivecontentsinaperiodofoneweektonotmorethan10A2forkrypton-85andnotmorethanA2forallotherradionuclides.Wheremixturesofdifferentradionuclidesarepresent,theprovisionsof2.2.7.7.2.4to2.2.7.7.2.6shallapplyexceptthatforkrypton-85aneffectiveA2(i)valueequalto10A2maybeused.Forcase(a),theassessmentshalltakeintoaccounttheexternalcontaminationlimitsof4.1.9.1.2.6.4.8.8.Apackageforradioactivecontentswithactivitygreaterthan105A2shallbesodesignedthatifitweresubjectedtotheenhancedwaterimmersiontestspecifiedin6.4.18,therewouldbenoruptureofthecontainmentsystem.6.4.8.9.Compliancewiththepermittedactivityreleaselimitsshalldependneitheruponfiltersnoruponamechanicalcoolingsystem.6.4.8.10.Apackageshallnotincludeapressurereliefsystemfromthecontainmentsystemwhichwouldallowthereleaseofradioactivematerialtotheenvironmentundertheconditionsofthetestsspecifiedin6.4.15and6.4.17.6.4.8.11.Apackageshallbesodesignedthatifitwereatthemaximumnormaloperatingpressureanditweresubjectedtothetestsspecifiedin6.4.15and6.4.17,thelevelofstrainsinthecontainmentsystemwouldnotattainvalueswhichwouldadverselyaffectthepackageinsuchawaythatitwouldfailtomeettheapplicablerequirements.6.4.8.12.Apackageshallnothaveamaximumnormaloperatingpressureinexcessofagaugepressureof700kPa.6.4.8.13.Themaximumtemperatureofanysurfacereadilyaccessibleduringcarriageofapackageshallnotexceed85Cintheabsenceofinsolationundertheambientconditionsspecifiedin6.4.8.4.Thepackageshallbecarriedunderexclusiveuse,asspecifiedin6.4.8.3,ifthismaximumtemperatureexceeds50C.Accountmaybetakenofbarriersorscreensintendedtogiveprotectiontopersonswithouttheneedforthebarriersorscreensbeingsubjecttoanytest.6.4.8.14.(Reserved)6.4.8.15.Apackageshallbedesignedforanambienttemperaturerangefrom–40Cto+38C.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/7886.4.9.RequirementsforTypeB(M)packages6.4.9.1.TypeB(M)packagesshallmeettherequirementsforTypeB(U)packagesspecifiedin6.4.8.1,exceptthatforpackagestobecarriedsolelywithinaspecifiedcountryorsolelybetweenspecifiedcountries,conditionsotherthanthosegivenin6.4.7.5,6.4.8.4,6.4.8.5,and6.4.8.8to6.4.8.15abovemaybeassumedwiththeapprovalofthecompetentauthoritiesofthesecountries.Notwithstanding,therequirementsforTypeB(U)packagesspecifiedin6.4.8.8to6.4.8.15shallbemetasfaraspracticable.6.4.9.2.IntermittentventingofTypeB(M)packagesmaybepermittedduringcarriage,providedthattheoperationalcontrolsforventingareacceptabletotherelevantcompetentauthorities.6.4.10.(Reserved)6.4.11.Requirementsforpackagescontainingfissilematerial6.4.11.1.Fissilematerialshallbecarriedsoasto:(a)maintainsub-criticalityduringnormalandaccidentconditionsofcarriage;inparticular,thefollowingcontingenciesshallbeconsidered:(i)waterleakingintooroutofpackages;(ii)thelossofefficiencyofbuilt-inneutronabsorbersormoderators;(iii)rearrangementofthecontentseitherwithinthepackageorasaresultoflossfromthepackage;(iv)reductionofspaceswithinorbetweenpackages;(v)packagesbecomingimmersedinwaterorburiedinsnow;and(vi)temperaturechanges;and(b)meettherequirements:(i)of6.4.7.2forfissilematerialcontainedinpackages;(ii)prescribedelsewhereinthisDirectivewhichpertaintotheradioactivepropertiesofthematerial;and(iii)specifiedin6.4.11.3to6.4.11.12,unlessexceptedby6.4.11.2.6.4.11.2.Fissilematerialmeetingoneoftheprovisions(a)to(d)ofthisparagraphisexceptedfromtherequirementtobecarriedinpackagesthatcomplywith6.4.11.3to6.4.11.12aswellastheotherrequirementsofthisDirectivethatapplytofissilematerial.Onlyonetypeofexceptionisallowedperconsignment.(a)Amasslimitperconsignmentsuchthat:massofuranium(cid:1)235ðgÞXþmassofotherfissilematerialðgÞY<1whereXandYarethemasslimitsdefinedinTable6.4.11.2,providedthateither:(i)eachindividualpackagecontainsnotmorethan15goffissilematerial;forunpackagedmaterial,thisquantitylimitationshallapplytotheconsignmentbeingcarriedinoronthevehicle;or(ii)thefissilematerialisahomogeneoushydrogenoussolutionormixturewheretheratiooffissilenuclidestohydrogenislessthan5%bymass;or(iii)thereisnotmorethan5goffissilematerialinany10litrevolumeofmaterial.Neitherberylliumnordeuteriumshallbepresentinquantitiesexceeding0,1%ofthefissilematerialmass;(b)Uraniumenrichedinuranium-235toamaximumof1%bymass,andwithatotalplutoniumanduranium-233contentnotexceeding1%ofthemassofuranium-235,providedthatthefissilematerialisdistributedessentiallyhomogeneouslythroughoutthematerial.Inaddition,ifuranium-235ispresentinmetallic,oxideorcarbideforms,itshallnotformalatticearrangement;(c)Liquidsolutionsofuranylnitrateenrichedinuranium-235toamaximumof2%bymass,withatotalplutoniumanduranium-233contentnotexceeding0,002%ofthemassofuranium,andwithaminimumnitrogentouraniumatomicratio(N/U)of2;(d)Packagescontaining,individually,atotalplutoniummassnotmorethan1kg,ofwhichnotmorethan20%bymassmayconsistofplutonium-239,plutonium-241oranycombinationofthoseradionuclides.Table6.4.11.2:ConsignmentmasslimitsforexceptionsfromtherequirementsforpackagescontainingfissilematerialFissilematerialFissilematerialmass(g)mixedwithsubstanceshavinganaveragehydrogendensitylessthanorequaltowaterFissilematerialmass(g)mixedwithsubstanceshavinganaveragehydrogendensitygreaterthanwaterUranium-235(X)400290OfficialJournaloftheEuropeanUnionEN26.1.2004L18/789FissilematerialFissilematerialmass(g)mixedwithsubstanceshavinganaveragehydrogendensitylessthanorequaltowaterFissilematerialmass(g)mixedwithsubstanceshavinganaveragehydrogendensitygreaterthanwaterOtherfissilematerial(Y)2501806.4.11.3.Wherethechemicalorphysicalform,isotopiccomposition,massorconcentration,moderationratioordensity,orgeometricconfigurationisnotknown,theassessmentsof6.4.11.7to6.4.11.12shallbeperformedassumingthateachparameterthatisnotknownhasthevaluewhichgivesthemaximumneutronmultiplicationconsistentwiththeknownconditionsandparametersintheseassessments.6.4.11.4.Forirradiatednuclearfueltheassessmentsof6.4.11.7to6.4.11.12shallbebasedonanisotopiccompositiondemonstratedtoprovide:(a)themaximumneutronmultiplicationduringtheirradiationhistory;or(b)aconservativeestimateoftheneutronmultiplicationforthepackageassessments.Afterirradiationbutpriortoshipment,ameasurementshallbeperformedtoconfirmtheconservatismoftheisotopiccomposition.6.4.11.5.Thepackaging,afterbeingsubjectedtothetestsspecifiedin6.4.15,mustpreventtheentryofa10cmcube.6.4.11.6.Thepackageshallbedesignedforanambienttemperaturerangeof–40°Cto+38°Cunlessthecompetentauthorityspecifiesotherwiseinthecertificateofapprovalforthepackagedesign.6.4.11.7.Forapackageinisolation,itshallbeassumedthatwatercanleakintooroutofallvoidspacesofthepackage,includingthosewithinthecontainmentsystem.However,ifthedesignincorporatesspecialfeaturestopreventsuchleakageofwaterintooroutofcertainvoidspaces,evenasaresultoferror,absenceofleakagemaybeassumedinrespectofthosevoidspaces.Specialfeaturesshallincludethefollowing:(a)multiplehighstandardwaterbarriers,eachofwhichwouldremainwatertightifthepackageweresubjecttothetestsprescribedin6.4.11.12(b),ahighdegreeofqualitycontrolinthemanufacture,maintenanceandrepairofpackagingsandteststodemonstratetheclosureofeachpackagebeforeeachshipment;or(b)forpackagescontaininguraniumhexafluorideonly:(i)packageswhere,followingthetestsprescribedin6.4.11.12(b),thereisnophysicalcontactbetweenthevalveandanyothercomponentofthepackagingotherthanatitsoriginalpointofattachmentandwhere,inaddition,followingthetestprescribedin6.4.17.3thevalvesremainleaktight;and(ii)ahighdegreeofqualitycontrolinthemanufacture,maintenanceandrepairofpackagingscoupledwithteststodemonstrateclosureofeachpackagebeforeeachshipment.6.4.11.8.Itshallbeassumedthattheconfinementsystemshallbecloselyreflectedbyatleast20cmofwaterorsuchgreaterreflectionasmayadditionallybeprovidedbythesurroundingmaterialofthepackaging.However,whenitcanbedemonstratedthattheconfinementsystemremainswithinthepackagingfollowingthetestsprescribedin6.4.11.12(b),closereflectionofthepackagebyatleast20cmofwatermaybeassumedin6.4.11.9(c).6.4.11.9.Thepackageshallbesubcriticalundertheconditionsof6.4.11.7and6.4.11.8withthepackageconditionsthatresultinthemaximumneutronmultiplicationconsistentwith:(a)routineconditionsofcarriage(incidentfree);(b)thetestsspecifiedin6.4.11.11(b);(c)thetestsspecifiedin6.4.11.12(b).6.4.11.10.(Reserved)6.4.11.11.Fornormalconditionsofcarriageanumber‘N’shallbederived,suchthatfivetimes‘N’shallbesub-criticalforthearrangementandpackageconditionsthatprovidethemaximumneutronmultiplicationconsistentwiththefollowing:(a)thereshallnotbeanythingbetweenthepackages,andthepackagearrangementshallbereflectedonallsidesbyatleast20cmofwater;and(b)thestateofthepackagesshallbetheirassessedordemonstratedconditioniftheyhadbeensubjectedtothetestsspecifiedin6.4.15.6.4.11.12.Foraccidentconditionsofcarriageanumber‘N’shallbederived,suchthattwotimes‘N’shallbesub-criticalforthearrangementandpackageconditionsthatprovidethemaximumneutronmultiplicationconsistentwiththefollowing:(a)hydrogenousmoderationbetweenpackages,andthepackagearrangementreflectedonallsidesbyatleast20cmofwater;andOfficialJournaloftheEuropeanUnionEN26.1.2004L18/790(b)thetestsspecifiedin6.4.15followedbywhicheverofthefollowingisthemorelimiting:(i)thetestsspecifiedin6.4.17.2(b)and,either6.4.17.2(c)forpackageshavingamassnotgreaterthan500kgandanoveralldensitynotgreaterthan1000kg/m3basedontheexternaldimensions,or6.4.17.2(a)forallotherpackages;followedbythetestspecifiedin6.4.17.3andcompletedbythetestsspecifiedin6.4.19.1to6.4.19.3;or(ii)thetestspecifiedin6.4.17.4;and(c)Whereanypartofthefissilematerialescapesfromthecontainmentsystemfollowingthetestsspecifiedin6.4.11.12(b),itshallbeassumedthatfissilematerialescapesfromeachpackageinthearrayandallofthefissilematerialshallbearrangedintheconfigurationandmoderationthatresultsinthemaximumneutronmultiplicationwithclosereflectionbyatleast20cmofwater.6.4.12.Testproceduresanddemonstrationofcompliance6.4.12.1.Demonstrationofcompliancewiththeperformancestandardsrequiredin2.2.7.3.3,2.2.7.3.4,2.2.7.4.1,2.2.7.4.2,and6.4.2to6.4.11mustbeaccomplishedbyanyofthemethodslistedbeloworbyacombinationthereof:(a)performanceoftestswithspecimensrepresentingLSA-IIImaterial,orspecialformradioactivematerial,orwithprototypesorsamplesofthepackaging,wherethecontentsofthespecimenorthepackagingforthetestsshallsimulateascloselyaspracticabletheexpectedrangeofradioactivecontentsandthespecimenorpackagingtobetestedshallbepreparedaspresentedforcarriage;(b)referencetoprevioussatisfactorydemonstrationsofasufficientlysimilarnature;(c)performanceoftestswithmodelsofappropriatescaleincorporatingthosefeatureswhicharesignificantwithrespecttotheitemunderinvestigationwhenengineeringexperiencehasshownresultsofsuchteststobesuitablefordesignpurposes.Whenascalemodelisused,theneedforadjustingcertaintestparameters,suchaspenetratordiameterorcompressiveload,shallbetakenintoaccount;(d)calculation,orreasonedargument,whenthecalculationproceduresandparametersaregenerallyagreedtobereliableorconservative.6.4.12.2.Afterthespecimen,prototypeorsamplehasbeensubjectedtothetests,appropriatemethodsofassessmentshallbeusedtoassurethattherequirementsforthetestprocedureshavebeenfulfilledincompliancewiththeperformanceandacceptancestandardsprescribedin2.2.7.3.3,2.2.7.3.4,2.2.7.4.1,2.2.7.4.2,and6.4.2to6.4.11.6.4.12.3.Allspecimensshallbeinspectedbeforetestinginordertoidentifyandrecordfaultsordamageincludingthefollowing:(a)divergencefromthedesign;(b)defectsinmanufacture;(c)corrosionorotherdeterioration;and(d)distortionoffeatures.Thecontainmentsystemofthepackageshallbeclearlyspecified.Theexternalfeaturesofthespecimenshallbeclearlyidentifiedsothatreferencemaybemadesimplyandclearlytoanypartofsuchspecimen.6.4.13.TestingtheintegrityofthecontainmentsystemandshieldingandevaluatingcriticalitysafetyAftereachoftheapplicabletestsspecifiedin6.4.15to6.4.21:(a)faultsanddamageshallbeidentifiedandrecorded;(b)itshallbedeterminedwhethertheintegrityofthecontainmentsystemandshieldinghasbeenretainedtotheextentrequiredin6.4.2to6.4.11forthepackageundertest;and(c)forpackagescontainingfissilematerial,itshallbedeterminedwhethertheassumptionsandconditionsusedintheassessmentsrequiredby6.4.11.1to6.4.11.12foroneormorepackagesarevalid.6.4.14.TargetfordroptestsThetargetforthedroptestsspecifiedin2.2.7.4.5(a),6.4.15.4,6.4.16(a),6.4.17.2shallbeaflat,horizontalsurfaceofsuchacharacterthatanyincreaseinitsresistancetodisplacementordeformationuponimpactbythespecimenwouldnotsignificantlyincreasethedamagetothespecimen.6.4.15.Testsfordemonstratingabilitytowithstandnormalconditionsofcarriage6.4.15.1.Thetestsare:thewaterspraytest,thefreedroptest,thestackingtestandthepenetrationtest.Specimensofthepackageshallbesubjectedtothefreedroptest,thestackingtestandthepenetrationtest,precededineachcasebythewaterspraytest.Onespecimenmaybeusedforallthetests,providedthattherequirementsof6.4.15.2arefulfilled.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/7916.4.15.2.Thetimeintervalbetweentheconclusionofthewaterspraytestandthesucceedingtestshallbesuchthatthewaterhassoakedintothemaximumextent,withoutappreciabledryingoftheexteriorofthespecimen.Intheabsenceofanyevidencetothecontrary,thisintervalshallbetakentobetwohoursifthewatersprayisappliedfromfourdirectionssimultaneously.Notimeintervalshallelapse,however,ifthewatersprayisappliedfromeachofthefourdirectionsconsecutively.6.4.15.3.Waterspraytest:thespecimenshallbesubjectedtoawaterspraytestthatsimulatesexposuretorainfallofapproximately5cmperhourforatleastonehour.6.4.15.4.Freedroptest:thespecimenshalldropontothetargetsoastosuffermaximumdamageinrespectofthesafetyfeaturestobetested.(a)TheheightofdropmeasuredfromthelowestpointofthespecimentotheuppersurfaceofthetargetshallbenotlessthanthedistancespecifiedinTable6.4.15.4fortheapplicablemass.Thetargetshallbeasdefinedin6.4.14.(b)Forrectangularfibreboardorwoodpackagesnotexceedingamassof50kg,aseparatespecimenshallbesubjectedtoafreedropontoeachcornerfromaheightof0,3m.(c)Forcylindricalfibreboardpackagesnotexceedingamassof100kg,aseparatespecimenshallbesubjectedtoafreedropontoeachofthequartersofeachrimfromaheightof0,3m.Table6.4.15.4:FreedropdistancefortestingpackagestonormalconditionsofcarriagePackagemass(kg)Freedropdistance(m)Packagemass<50001,25000Packagemass<100000,910000Packagemass<150000,615000Packagemass0,36.4.15.5.Stackingtest:Unlesstheshapeofthepackagingeffectivelypreventsstacking,thespecimenshallbesubjected,foraperiodof24h,toacompressiveloadequaltothegreaterofthefollowing:(a)theequivalentoffivetimesthemassoftheactualpackage;and(b)theequivalentof13kPamultipliedbytheverticallyprojectedareaofthepackage.Theloadshallbeapplieduniformlytotwooppositesidesofthespecimen,oneofwhichshallbethebaseonwhichthepackagewouldtypicallyrest.6.4.15.6.Penetrationtest:Thespecimenshallbeplacedonarigid,flat,horizontalsurfacewhichwillnotmovesignificantlywhilethetestisbeingcarriedout.(a)Abarof3,2cmindiameterwithahemisphericalendandamassof6kgshallbedroppedanddirectedtofall,withitslongitudinalaxisvertical,ontothecentreoftheweakestpartofthespecimen,sothat,ifitpenetratessufficientlyfar,itwillhitthecontainmentsystem.Thebarshallnotbesignificantlydeformedbythetestperformance.(b)Theheightofdropofthebarmeasuredfromitslowerendtotheintendedpointofimpactontheuppersurfaceofthespecimenshallbe1m.6.4.16.AdditionaltestsforTypeApackagesdesignedforliquidsandgasesAspecimenorseparatespecimensshallbesubjectedtoeachofthefollowingtestsunlessitcanbedemonstratedthatonetestismoresevereforthespecimeninquestionthantheother,inwhichcaseonespecimenshallbesubjectedtothemoreseveretest.(a)Freedroptest:thespecimenshalldropontothetargetsoastosufferthemaximumdamageinrespectofcontainment.Theheightofthedropmeasuredfromthelowestpartofthespecimentotheuppersurfaceofthetargetshallbe9m.Thetargetshallbeasdefinedin6.4.14;(b)Penetrationtest:thespecimenshallbesubjectedtothetestspecifiedin6.4.15.6exceptthattheheightofdropshallbeincreasedto1,7mfromthe1mspecifiedin6.4.15.6(b).6.4.17.Testsfordemonstratingabilitytowithstandaccidentconditionsincarriage6.4.17.1.Thespecimenshallbesubjectedtothecumulativeeffectsofthetestsspecifiedin6.4.17.2and6.4.17.3,inthatorder.Followingthesetests,eitherthisspecimenoraseparatespecimenshallbesubjectedtotheeffect(s)ofthewaterimmersiontest(s)asspecifiedin6.4.17.4and,ifapplicable,6.4.18.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/7926.4.17.2.Mechanicaltest:themechanicaltestconsistsofthreedifferentdroptests.Eachspecimenshallbesubjectedtotheapplicabledropsasspecifiedin6.4.8.7or6.4.11.12.Theorderinwhichthespecimenissubjectedtothedropsshallbesuchthat,oncompletionofthemechanicaltest,thespecimenshallhavesufferedsuchdamageaswillleadtothemaximumdamageinthethermaltestwhichfollows.(a)FordropI,thespecimenshalldropontothetargetsoastosufferthemaximumdamage,andtheheightofthedropmeasuredfromthelowestpointofthespecimentotheuppersurfaceofthetargetshallbe9m.Thetargetshallbeasdefinedin6.4.14;(b)fordropII,thespecimenshalldropsoastosufferthemaximumdamageontoabarrigidlymountedperpendicularlyonthetarget.Theheightofthedropmeasuredfromtheintendedpointofimpactofthespecimentotheuppersurfaceofthebarshallbe1m.Thebarshallbeofsolidmildsteelofcircularsection,(15,0cm±0,5cm)indiameterand20cmlongunlessalongerbarwouldcausegreaterdamage,inwhichcaseabarofsufficientlengthtocausemaximumdamageshallbeused.Theupperendofthebarshallbeflatandhorizontalwithitsedgesroundedofftoaradiusofnotmorethan6mm.Thetargetonwhichthebarismountedshallbeasdescribedin6.4.14;(c)fordropIII,thespecimenshallbesubjectedtoadynamiccrushtestbypositioningthespecimenonthetargetsoastosuffermaximumdamagebythedropofa500kgmassfrom9montothespecimen.Themassshallconsistofasolidmildsteelplate1mby1mandshallfallinahorizontalattitude.Theheightofthedropshallbemeasuredfromtheundersideoftheplatetothehighestpointofthespecimen.Thetargetonwhichthespecimenrestsshallbeasdefinedin6.4.14.6.4.17.3.Thermaltest:thespecimenshallbeinthermalequilibriumunderconditionsofanambienttemperatureof38°C,subjecttothesolarinsolationconditionsspecifiedinTable6.4.8.5andsubjecttothedesignmaximumrateofinternalheatgenerationwithinthepackagefromtheradioactivecontents.Alternatively,anyoftheseparametersareallowedtohavedifferentvaluespriortoandduringthetest,providingdueaccountistakenoftheminthesubsequentassessmentofpackageresponse.Thethermaltestshallthenconsistof:(a)exposureofaspecimenforaperiodof30minutestoathermalenvironmentwhichprovidesaheatfluxatleastequivalenttothatofahydrocarbonfuel/airfireinsufficientlyquiescentambientconditionstogiveaminimumaverageflameemissivitycoefficientof0,9andanaveragetemperatureofatleast800°C,fullyengulfingthespecimen,withasurfaceabsorptivitycoefficientof0,8orthatvaluewhichthepackagemaybedemonstratedtopossessifexposedtothefirespecified,followedby,(b)exposureofthespecimentoanambienttemperatureof38°C,subjecttothesolarinsolationconditionsspecifiedinTable6.4.8.5andsubjecttothedesignmaximumrateofinternalheatgenerationwithinthepackagebytheradioactivecontentsforasufficientperiodtoensurethattemperaturesinthespecimenareeverywheredecreasingand/orareapproachinginitialsteadystateconditions.Alternatively,anyoftheseparametersareallowedtohavedifferentvaluesfollowingcessationofheating,providingdueaccountistakenoftheminthesubsequentassessmentofpackageresponse.Duringandfollowingthetestthespecimenshallnotbeartificiallycooledandanycombustionofmaterialsofthespecimenshallbepermittedtoproceednaturally.6.4.17.4.Waterimmersiontest:thespecimenshallbeimmersedunderaheadofwaterofatleast15mforaperiodofnotlessthaneighthoursintheattitudewhichwillleadtomaximumdamage.Fordemonstrationpurposes,anexternalgaugepressureofatleast150kPashallbeconsideredtomeettheseconditions.6.4.18.EnhancedwaterimmersiontestforTypeB(U)andTypeB(M)packagescontainingmorethan105A2Enhancedwaterimmersiontest:Thespecimenshallbeimmersedunderaheadofwaterofatleast200mforaperiodofnotlessthanonehour.Fordemonstrationpurposes,anexternalgaugepressureofatleast2MPashallbeconsideredtomeettheseconditions.6.4.19.Waterleakagetestforpackagecontainingfissilematerial6.4.19.1.Packagesforwhichwaterin-leakageorout-leakagetotheextentwhichresultsingreatestreactivityhasbeenassumedforpurposesofassessmentunder6.4.11.7to6.4.11.12shallbeexceptedfromthetest.6.4.19.2.Beforethespecimenissubjectedtothewaterleakagetestspecifiedbelow,itshallbesubjectedtothetestsin6.4.17.2(b),andeither6.4.17.2(a)or(c)asrequiredby6.4.11.12,andthetestspecifiedin6.4.17.3.6.4.19.3.Thespecimenshallbeimmersedunderaheadofwaterofatleast0,9mforaperiodofnotlessthan8hoursandintheattitudeforwhichmaximumleakageisexpected.6.4.20.(Reserved)6.4.21.Inspectionsforpackagingsdesignedtocontain0,1kgormoreofuraniumhexafluoride6.4.21.1.Everymanufacturedpackaginganditsserviceandstructuralequipmentshall,eitherjointlyorseparately,undergoaninspectioninitiallybeforebeingputintoserviceandperiodicallythereafter.Theseinspectionsshallbeperformedandcertifiedbyagreementwiththecompetentauthority.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/7936.4.21.2.Theinitialinspectionshallconsistofacheckofthedesigncharacteristics,astructuraltest,aleakproofnesstest,awatercapacitytestandacheckofsatisfactoryoperationoftheserviceequipment.6.4.21.3.Theperiodicinspectionsshallconsistofavisualexamination,astructuraltest,aleakproofnesstestandacheckofsatisfactoryoperationoftheserviceequipment.Themaximumintervalsforperiodicinspectionsshallbefiveyears.Packagingswhichhavenotbeeninspectedwithinthisfive-yearperiodshallbeexaminedbeforecarriageinaccordancewithaprogrammeapprovedbythecompetentauthority.Theyshallnotberefilledbeforecompletionofthefullprogrammeforperiodicinspections.6.4.21.4.Thecheckofdesigncharacteristicsshalldemonstratecompliancewiththedesigntypespecificationsandthemanufacturingprogramme.6.4.21.5.Fortheinitialstructuraltest,packagingsdesignedtocontain0,1kgormoreofuraniumhexaflourideshallbetestedhydraulicallyataninternalpressureofatleast1,38Mpabut,whenthetestpressureislessthan2,76MPa,thedesignshallrequiremultilateralapproval.Forretestingpackagings,anyotherequivalentnon-destructivetestingmaybeappliedsubjecttomultilateralapproval.6.4.21.6.Theleakproofnesstestshallbeperformedinaccordancewithaprocedurewhichiscapableofindicatingleakagesinthecontainmentsystemwithasensitivityof0,1Pa.l/s(10-6bar.l/s).6.4.21.7.Thewatercapacityofthepackagingsshallbeestablishedwithanaccuracyof±0,25%atareferencetemperatureof15°C.Thevolumeshallbestatedontheplatedescribedin6.4.21.8.6.4.21.8.Aplatemadeofnon-corrodingmetalshallbedurablyattachedtoeverypackaginginareadilyaccessibleplace.Themethodofattachingtheplatemustnotimpairthestrengthofthepackaging.Thefollowingparticulars,atleast,shallbemarkedontheplatebystampingorbyanyotherequivalentmethod:—approvalnumber,—manufacturer'sserialnumber,—maximumworkingpressure(gaugepressure),—testpressure(gaugepressure),—contents:uraniumhexafluoride,—capacityinlitres,—maximumpermissiblefillingmassofuraniumhexafluoride,—taremass,—date(month,year)oftheinitialtestandthemostrecentperiodictest,—stampoftheexpertwhoperformedthetests.6.4.22.Approvalsofpackagedesignsandmaterials6.4.22.1.Theapprovalofdesignsforpackagescontaining0,1kgormoreofuraniumhexafluoriderequiresthat:(a)eachdesignthatmeetstherequirementsof6.4.6.4shallrequiremultilateralapproval;(b)after31December2003,eachdesignthatmeetstherequirementsof6.4.6.1to6.4.6.3shallrequireunilateralapprovalbythecompetentauthorityofthecountryoforiginofthedesign.6.4.22.2.EachTypeB(U)andTypeCpackagedesignshallrequireunilateralapproval,exceptthat:(a)apackagedesignforfissilematerial,whichisalsosubjectto6.4.22.4,6.4.23.7,and5.1.5.3.1shallrequiremultilateralapproval;and(b)aTypeB(U)packagedesignforlowdispersibleradioactivematerialshallrequiremultilateralapproval.6.4.22.3.EachTypeB(M)packagedesign,includingthoseforfissilematerialwhicharealsosubjecttotherequirementsof6.4.22.4,6.4.23.7,and5.1.5.3.1andthoseforlowdispersibleradioactivematerial,shallrequiremultilateralapproval.6.4.22.4.Eachpackagedesignforfissilematerialwhichisnotexceptedaccordingto6.4.11.2fromtherequirementsthatapplyspecificallytopackagescontainingfissilematerialshallrequiremultilateralapproval.6.4.22.5.Thedesignforspecialformradioactivematerialshallrequireunilateralapproval.Thedesignforlowdispersibleradioactivematerialshallrequiremultilateralapproval(seealso6.4.23.8).6.4.22.6.AnydesignthatrequiresunilateralapprovaloriginatinginaMemberStateshallbeapprovedbythecompetentauthorityofthiscountry;ifthecountrywherethepackagehasbeendesignedisnotaMemberState,carriageispossibleonconditionthat:(a)acertificatehasbeensuppliedbythiscountry,provingthatthepackagesatisfiesthetechnicalrequirementsofthisDirective,andthatthiscertificateiscountersignedbythecompetentauthorityofthefirstMemberStatereachedbytheconsignment;OfficialJournaloftheEuropeanUnionEN26.1.2004L18/794(b)ifnocertificateandnoexistingpackagedesignapprovalbyaMemberStatehasbeensupplied,thepackagedesignisapprovedbythecompetentauthorityofthefirstMemberStatereachedbytheconsignment.6.4.22.7.Fordesignsapprovedunderthetransitionalmeasuressee1.6.5.6.4.23.Applicationsandapprovalsforradioactivematerialcarriage6.4.23.1.(Reserved)6.4.23.2.Anapplicationforshipmentapprovalshallinclude:(a)theperiodoftime,relatedtotheshipment,forwhichtheapprovalissought;(b)theactualradioactivecontents,theexpectedmodesofcarriage,thetypeofvehicle,andtheprobableorproposedroute;and(c)thedetailsofhowtheprecautionsandadministrativeoroperationalcontrols,referredtointhepackagedesignapprovalcertificatesissuedunder5.1.5.3.1,aretobeputintoeffect.6.4.23.3.AnapplicationforapprovalofshipmentsunderspecialarrangementshallincludealltheinformationnecessarytosatisfythecompetentauthoritythattheoveralllevelofsafetyincarriageisatleastequivalenttothatwhichwouldbeprovidedifalltheapplicablerequirementsofthisDirectivehadbeenmet.Theapplicationshallalsoinclude:(a)astatementoftherespectsinwhich,andofthereasonswhy,theconsignmentcannotbemadeinfullaccordancewiththeapplicablerequirementsofthisDirective;and(b)astatementofanyspecialprecautionsorspecialadministrativeoroperationalcontrolswhicharetobeemployedduringcarriagetocompensateforthefailuretomeettheapplicablerequirementsofthisDirective.6.4.23.4.AnapplicationforapprovalofTypeB(U)orTypeCpackagedesignshallinclude:(a)adetaileddescriptionoftheproposedradioactivecontentswithreferencetotheirphysicalandchemicalstatesandthenatureoftheradiationemitted;(b)adetailedstatementofthedesign,includingcompleteengineeringdrawingsandschedulesofmaterialsandmethodsofmanufacture;(c)astatementofthetestswhichhavebeendoneandtheirresults,orevidencebasedoncalculativemethodsorotherevidencethatthedesignisadequatetomeettheapplicablerequirements;(d)theproposedoperatingandmaintenanceinstructionsfortheuseofthepackaging;(e)ifthepackageisdesignedtohaveamaximumnormaloperatingpressureinexcessof100kPagauge,aspecificationofthematerialsofmanufactureofthecontainmentsystem,thesamplestobetaken,andtheteststobemade;(f)wheretheproposedradioactivecontentsareirradiatedfuel,astatementandajustificationofanyassumptioninthesafetyanalysisrelatingtothecharacteristicsofthefuelandadescriptionofanypre-shipmentmeasurementasrequiredby6.4.11.4(b);(g)anyspecialstowageprovisionsnecessarytoensurethesafedissipationofheatfromthepackageconsideringthevariousmodesofcarriagetobeusedandtypeofvehicleorcontainer;(h)Aareproducibleillustration,notlargerthan21cmby30cm,showingthemake-upofthepackage;and(i)aspecificationoftheapplicablequalityassuranceprogrammeasrequiredby1.7.3.6.4.23.5.AnapplicationforapprovalofaTypeB(M)packagedesignshallinclude,inadditiontothegeneralinformationrequiredforpackageapprovalin6.4.23.4forTypeB(U)packages:(a)alistoftherequirementsspecifiedin6.4.7.5,6.4.8.4,6.4.8.5and6.4.8.8to6.4.8.15withwhichthepackagedoesnotconform;(b)anyproposedsupplementaryoperationalcontrolstobeappliedduringcarriagenotregularlyprovidedforinthisAnnex,butwhicharenecessarytoensurethesafetyofthepackageortocompensateforthedeficiencieslistedin(a);(c)astatementrelativetoanyrestrictionsonthemodeofcarriageandtoanyspecialloading,carriage,unloadingorhandlingprocedures;and(d)Therangeofambientconditions(temperature,solarradiation)whichareexpectedtobeencounteredduringcarriageandwhichhavebeentakenintoaccountinthedesign.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/7956.4.23.6.Theapplicationforapprovalofdesignsforpackagescontaining0,1kgormoreofuraniumhexafluorideshallincludeallinformationnecessarytosatisfythecompetentauthoritythatthedesignmeetstheapplicablerequirementsof6.4.6.1,andadescriptionoftheapplicablequalityassuranceprogrammeasrequiredin1.7.3.6.4.23.7.Anapplicationforafissilepackageapprovalshallincludeallinformationnecessarytosatisfythecompetentauthoritythatthedesignmeetstheapplicablerequirementsof6.4.11.1,andaspecificationoftheapplicablequalityassuranceprogrammeasrequiredby1.7.3.6.4.23.8.Anapplicationforapprovalofdesignforspecialformradioactivematerialanddesignforlowdispersibleradioactivematerialshallinclude:(a)adetaileddescriptionoftheradioactivematerialor,ifacapsule,thecontents;particularreferenceshallbemadetobothphysicalandchemicalstates;(b)adetailedstatementofthedesignofanycapsuletobeused;(c)astatementofthetestswhichhavebeendoneandtheirresults,orevidencebasedoncalculativemethodstoshowthattheradioactivematerialiscapableofmeetingtheperformancestandards,orotherevidencethatthespecialformradioactivematerialorlowdispersibleradioactivematerialmeetstheapplicablerequirementsofthisDirective;(d)aspecificationoftheapplicablequalityassuranceprogrammeasrequiredin1.7.3;and(e)anyproposedpre-shipmentactionsforuseintheconsignmentofspecialformradioactivematerialorlowdispersibleradioactivematerial.6.4.23.9.Eachapprovalcertificateissuedbyacompetentauthorityshallbeassignedanidentificationmark.Theidentificationmarkshallbeofthefollowinggeneralisedtype:VRI/number/typecode(a)exceptasprovidedin6.4.23.10(b),VRIrepresentstheinternationalvehicleregistrationidentificationcodeofthecountryissuingthecertificate(1);(b)thenumbershallbeassignedbythecompetentauthority,andshallbeuniqueandspecificwithregardtotheparticulardesignorshipment.Theshipmentapprovalidentificationmarkshallbeclearlyrelatedtothedesignapprovalidentificationmark;(c)thefollowingtypecodesshallbeusedintheorderlistedtoindicatethetypesofapprovalcertificatesissued:AFTypeApackagedesignforfissilematerialB(U)TypeB(U)packagedesign[B(U)Fifforfissilematerial]B(M)TypeB(M)packagedesign[B(M)Fifforfissilematerial]CTypeCpackagedesign(CFifforfissilematerial)IFIndustrialpackagedesignforfissilematerialSSpecialformradioactivematerialLDLowdispersibleradioactivematerialTShipmentXSpecialarrangement.Inthecaseofpackagedesignsfornon-fissileorfissileexcepteduraniumhexafluoride,wherenoneoftheabovecodesapply,thenthefollowingtypecodesshallbeused:H(U)unilateralapprovalH(M)multilateralapproval;(d)forpackagedesignandspecialformradioactivematerialapprovalcertificates,otherthanthoseissuedundertransitionalpackagingtheprovisionsof1.6.5.2to1.6.5.4,andforlowdispersibleradioactivematerialapprovalcertificates,thesymbols‘-96’shallbeaddedtothetypecode.6.4.23.10.Thesetypecodesshallbeappliedasfollows:(a)eachcertificateandeachpackageshallbeartheappropriateidentificationmark,comprisingthesymbolsprescribedin6.4.23.9(a),(b),(c)and(d)above,exceptthat,forpackages,onlytheapplicabledesigntypecodesincluding,ifapplicable,thesymbols‘-96’,shallappearfollowingthesecondstroke,thatis,the‘T’or‘X’shallnotappearintheidentificationmarkingonthepackage.Wherethedesignapprovalandshipmentapprovalarecombined,theapplicabletypecodesdonotneedtoberepeated.Forexample:OfficialJournaloftheEuropeanUnionEN26.1.2004L18/796(1)SeeViennaConventiononRoadTraffic(1968).A/132/B(M)F-96:ATypeB(M)packagedesignapprovedforfissilematerial,requiringmultilateralapproval,forwhichthecompetentauthorityofAustriahasassignedthedesignnumber132(tobemarkedonboththepackageandonthepackagedesignapprovalcertificate);A/132/B(M)F-96T:Theshipmentapprovalissuedforapackagebearingtheidentificationmarkelaboratedabove(tobemarkedonthecertificateonly);A/137/X:AspecialarrangementapprovalissuedbythecompetentauthorityofAustria,towhichthenumber137hasbeenassigned(tobemarkedonthecertificateonly);A/139/IF-96:AnindustrialpackagedesignforfissilematerialapprovedbythecompetentauthorityofAustria,towhichpackagedesignnumber139hasbeenassigned(tobemarkedonboththepackageandonthepackagedesignapprovalcertificate);andA/145/H(U)-96:ApackagedesignforfissileexcepteduraniumhexafluorideapprovedbythecompetentauthorityofAustria,towhichpackagedesignnumber145hasbeenassigned(tobemarkedonboththepackageandonthepackagedesignapprovalcertificate);(b)wheremultilateralapprovaliseffectedbyvalidationaccordingto6.4.23.16,onlytheidentificationmarkissuedbythecountryoforiginofthedesignorshipmentshallbeused.Wheremultilateralapprovaliseffectedbyissueofcertificatesbysuccessivecountries,eachcertificateshallbeartheappropriateidentificationmarkandthepackagewhosedesignwassoapprovedshallbearallappropriateidentificationmarks.Forexample:A/132/B(M)F-96CH/28/B(M)F-96wouldbetheidentificationmarkofapackagewhichwasoriginallyapprovedbyAustriaandwassubsequentlyapproved,byseparatecertificate,bySwitzerland.Additionalidentificationmarkswouldbetabulatedinasimilarmanneronthepackage;(c)therevisionofacertificateshallbeindicatedbyaparentheticalexpressionfollowingtheidentificationmarkonthecertificate.Forexample,A/132/B(M)F-96(Rev.2)wouldindicaterevision2oftheAustrianpackagedesignapprovalcertificate;orA/132/B(M)F-96(Rev.0)wouldindicatetheoriginalissuanceoftheAustrianpackagedesignapprovalcertificate.Fororiginalissuances,theparentheticalentryisoptionalandotherwordssuchas‘originalissuance’mayalsobeusedinplaceof‘Rev.0’.Certificaterevisionnumbersmayonlybeissuedbythecountryissuingtheoriginalapprovalcertificate;(d)additionalsymbols(asmaybenecessitatedbynationalregulations)maybeaddedinbracketstotheendoftheidentificationmark;forexample,A/132/B(M)F-96(SP503);(e)itisnotnecessarytoaltertheidentificationmarkonthepackagingeachtimethatarevisiontothedesigncertificateismade.Suchre-markingshallberequiredonlyinthosecaseswheretherevisiontothepackagedesigncertificateinvolvesachangeinthelettertypecodesforthepackagedesignfollowingthesecondstroke.6.4.23.11.Eachapprovalcertificateissuedbyacompetentauthorityforspecialformradioactivematerialorlowdispersibleradioactivematerialshallincludethefollowinginformation:(a)typeofcertificate;(b)thecompetentauthorityidentificationmark;(c)theissuedateandanexpirydate;(d)listofapplicablenationalandinternationalregulations,includingtheeditionoftheIAEARegulationsfortheSafeTransportofRadioactiveMaterialunderwhichthespecialformradioactivematerialorlowdispersibleradioactivematerialisapproved;(e)theidentificationofthespecialformradioactivematerialorlowdispersibleradioactivematerial;(f)adescriptionofthespecialformradioactivematerialorlowdispersibleradioactivematerial;(g)designspecificationsforthespecialformradioactivematerialorlowdispersibleradioactivematerialwhichmayincludereferencestodrawings;(h)aspecificationoftheradioactivecontentswhichincludestheactivitiesinvolvedandwhichmayincludethephysicalandchemicalform;(i)aspecificationoftheapplicablequalityassuranceprogrammeasrequiredin1.7.3;(j)referencetoinformationprovidedbytheapplicantrelatingtospecificactionstobetakenpriortoshipment;(k)ifdeemedappropriatebythecompetentauthority,referencetotheidentityoftheapplicant;(l)signatureandidentificationofthecertifyingofficial.6.4.23.12.Eachapprovalcertificateissuedbyacompetentauthorityforaspecialarrangementshallincludethefollowinginformation:(a)typeofcertificate;OfficialJournaloftheEuropeanUnionEN26.1.2004L18/797(b)thecompetentauthorityidentificationmark;(c)theissuedateandanexpirydate;(d)mode(s)ofcarriage;(e)anyrestrictionsonthemodesofcarriage,typeofvehicle,container,andanynecessaryroutinginstructions;(f)listofapplicablenationalandinternationalregulations,includingtheeditionoftheIAEARegulationsfortheSafeTransportofRadioactiveMaterialunderwhichthespecialarrangementisapproved;(g)thefollowingstatement:‘Thiscertificatedoesnotrelievetheconsignorfromcompliancewithanyrequirementofthegovernmentofanycountrythroughorintowhichthepackagewillbecarried.’;(h)referencestocertificatesforalternativeradioactivecontents,othercompetentauthorityvalidation,oradditionaltechnicaldataorinformation,asdeemedappropriatebythecompetentauthority;(i)descriptionofthepackagingbyareferencetothedrawingsoraspecificationofthedesign.Ifdeemedappropriatebythecompetentauthority,areproducibleillustration,notlargerthan21cmby30cm,showingthemake-upofthepackageshallalsobeprovided,accompaniedbyabriefdescriptionofthepackaging,includingmaterialsofmanufacture,grossmass,generaloutsidedimensionsandappearance;(j)aspecificationoftheauthorisedradioactivecontents,includinganyrestrictionsontheradioactivecontentswhichmightnotbeobviousfromthenatureofthepackaging.Thisshallincludethephysicalandchemicalforms,theactivitiesinvolved(includingthoseofthevariousisotopes,ifappropriate),amountsingrams(forfissilematerial),andwhetherspecialformradioactivematerialorlowdispersibleradioactivematerial,ifapplicable;(k)additionally,forpackagescontainingfissilematerial:(i)adetaileddescriptionoftheauthorisedradioactivecontents;(ii)thevalueofthecriticalitysafetyindex;(iii)referencetothedocumentationthatdemonstratesthecriticalitysafetyofthecontents;(iv)anyspecialfeatures,onthebasisofwhichtheabsenceofwaterfromcertainvoidspaceshasbeenassumedinthecriticalityassessment;(v)anyallowance(basedon6.4.11.4(b))forachangeinneutronmultiplicationassumedinthecriticalityassessmentasaresultofactualirradiationexperience;and(vi)theambienttemperaturerangeforwhichthespecialarrangementhasbeenapproved;(l)adetailedlistingofanysupplementaryoperationalcontrolsrequiredforpreparation,loading,carriage,unloadingandhandlingoftheconsignment,includinganyspecialstowageprovisionsforthesafedissipationofheat;(m)ifdeemedappropriatebythecompetentauthority,reasonsforthespecialarrangement;(n)descriptionofthecompensatorymeasurestobeappliedasaresultoftheshipmentbeingunderspecialarrangement;(o)referencetoinformationprovidedbytheapplicantrelatingtotheuseofthepackagingorspecificactionstobetakenpriortotheshipment;(p)astatementregardingtheambientconditionsassumedforpurposesofdesignifthesearenotinaccordancewiththosespecifiedin6.4.8.4,6.4.8.5,and6.4.8.15,asapplicable;(q)anyemergencyarrangementsdeemednecessarybythecompetentauthority;(r)aspecificationoftheapplicablequalityassuranceprogrammeasrequiredin1.7.3;(s)ifdeemedappropriatebythecompetentauthority,referencetotheidentityoftheapplicantandtotheidentityofthecarrier;(t)signatureandidentificationofthecertifyingofficial.6.4.23.13.Eachapprovalcertificateforashipmentissuedbyacompetentauthorityshallincludethefollowinginformation:(a)typeofcertificate;(b)thecompetentauthorityidentificationmark(s);(c)theissuedateandanexpirydate;(d)listofapplicablenationalandinternationalregulations,includingtheeditionoftheIAEARegulationsfortheSafeTransportofRadioactiveMaterialunderwhichtheshipmentisapproved;(e)anyrestrictionsonthemodesofcarriage,typeofvehicle,container,andanynecessaryrouteinginstructions;OfficialJournaloftheEuropeanUnionEN26.1.2004L18/798(f)thefollowingstatement:‘Thiscertificatedoesnotrelievetheconsignorfromcompliancewithanyrequirementofthegovernmentofanycountrythroughorintowhichthepackagewillbecarried.’;(g)adetailedlistingofanysupplementaryoperationalcontrolsrequiredforpreparation,loading,carriage,unloadingandhandlingoftheconsignment,includinganyspecialstowageprovisionsforthesafedissipationofheatormaintenanceofcriticalitysafety;(h)referencetoinformationprovidedbytheapplicantrelatingtospecificactionstobetakenpriortoshipment;(i)referencetotheapplicabledesignapprovalcertificate(s);(j)aspecificationoftheactualradioactivecontents,includinganyrestrictionsontheradioactivecontentswhichmightnotbeobviousfromthenatureofthepackaging.Thisshallincludethephysicalandchemicalforms,thetotalactivitiesinvolved(includingthoseofthevariousisotopes,ifappropriate),amountsingrams(forfissilematerial),andwhetherspecialformradioactivematerialorlowdispersibleradioactivematerial,ifapplicable;(k)anyemergencyarrangementsdeemednecessarybythecompetentauthority;(l)aspecificationoftheapplicablequalityassuranceprogrammeasrequiredin1.7.3;(m)ifdeemedappropriatebythecompetentauthority,referencetotheidentityoftheapplicant;(n)signatureandidentificationofthecertifyingofficial.6.4.23.14.Eachapprovalcertificateofthedesignofapackageissuedbyacompetentauthorityshallincludethefollowinginformation:(a)typeofcertificate;(b)thecompetentauthorityidentificationmark;(c)theissuedateandanexpirydate;(d)anyrestrictiononthemodesofcarriage,ifappropriate;(e)listofapplicablenationalandinternationalregulations,includingtheeditionoftheIAEARegulationsfortheSafeTransportofRadioactiveMaterialunderwhichthedesignisapproved;(f)thefollowingstatement;‘Thiscertificatedoesnotrelievetheconsignorfromcompliancewithanyrequirementofthegovernmentofanycountrythroughorintowhichthepackagewillbecarried.’;(g)referencestocertificatesforalternativeradioactivecontents,othercompetentauthorityvalidation,oradditionaltechnicaldataorinformation,asdeemedappropriatebythecompetentauthority;(h)astatementauthorisingshipmentwhereshipmentapprovalisrequiredunder5.1.5.2.2,ifdeemedappropriate;(i)identificationofthepackaging;(j)descriptionofthepackagingbyareferencetothedrawingsorspecificationofthedesign.Ifdeemedappropriatebythecompetentauthority,areproducibleillustration,notlargerthan21cmby30cm,showingthemake-upofthepackageshouldalsobeprovided,accompaniedbyabriefdescriptionofthepackaging,includingmaterialsofmanufacture,grossmass,generaloutsidedimensionsandappearance;(k)specificationofthedesignbyreferencetothedrawings;(l)aspecificationoftheauthorisedradioactivecontent,includinganyrestrictionsontheradioactivecontentswhichmightnotbeobviousfromthenatureofthepackaging.Thisshallincludethephysicalandchemicalforms,theactivitiesinvolved(includingthoseofthevariousisotopes,ifappropriate),amountsingrams(forfissilematerial),andwhetherspecialformradioactivematerialorlowdispersibleradioactivematerial,ifapplicable;(m)additionally,forpackagescontainingfissilematerial:(i)adetaileddescriptionoftheauthorisedradioactivecontents;(ii)thevalueofthecriticalitysafetyindex;(iii)referencetothedocumentationthatdemonstratesthecriticalitysafetyofthecontents;(iv)anyspecialfeatures,onthebasisofwhichtheabsenceofwaterfromcertainvoidspaceshasbeenassumedinthecriticalityassessment;(v)anyallowance(basedon6.4.11.4(b))forachangeinneutronmultiplicationassumedinthecriticalityassessmentasaresultofactualirradiationexperience;and(vi)theambienttemperaturerangeforwhichthepackagedesignhasbeenapproved;(n)forTypeB(M)packages,astatementspecifyingthoserequirementsof6.4.7.5,6.4.8.4,6.4.8.5and6.4.8.8to6.4.8.15withwhichthepackagedoesnotconformandanyamplifyinginformationwhichmaybeusefultoothercompetentauthorities;OfficialJournaloftheEuropeanUnionEN26.1.2004L18/799(o)adetailedlistingofanysupplementaryoperationalcontrolsrequiredforpreparation,loading,carriage,unloadingandhandlingoftheconsignment,includinganyspecialstowageprovisionsforthesafedissipationofheat;(p)referencetoinformationprovidedbytheapplicantrelatingtotheuseofthepackagingorspecificactionstobetakenpriortoshipment;(q)astatementregardingtheambientconditionsassumedforpurposesofdesignifthesearenotinaccordancewiththosespecifiedin6.4.8.4,6.4.8.5and6.4.8.15,asapplicable;(r)aspecificationoftheapplicablequalityassuranceprogrammeasrequiredin1.7.3;(s)anyemergencyarrangementsdeemednecessarybythecompetentauthority;(t)ifdeemedappropriatebythecompetentauthority,referencetotheidentityoftheapplicant;(u)signatureandidentificationofthecertifyingofficial.6.4.23.15.Thecompetentauthorityshallbeinformedoftheserialnumberofeachpackagingmanufacturedtoadesignapprovedbythem.Thecompetentauthorityshallmaintainaregisterofsuchserialnumbers.6.4.23.16.Multilateralapprovalmaybebyvalidationoftheoriginalcertificateissuedbythecompetentauthorityofthecountryoforiginofthedesignorshipment.Suchvalidationmaytaketheformofanendorsementontheoriginalcertificateortheissuanceofaseparateendorsement,Annex,supplement,etc.,bythecompetentauthorityofthecountrythroughorintowhichtheshipmentismade.CHAPTER6.5Requirementsfortheconstructionandtestingofintermediatebulkcontainers(IBCs)6.5.1.GeneralrequirementsapplicabletoalltypesofIBCs6.5.1.1.Scope6.5.1.1.1.Therequirementsofthischapterapplytointermediatebulkcontainers(IBCs)theuseofwhichisexpresslyauthorisedforthecarriageofcertaindangerousgoodsaccordingtothepackinginstructionsindicatedinColumn8ofTableAinChapter3.2.Portabletanksandtank-containerswhichmeettherequirementsofChapter6.7or6.8respectivelyarenotconsideredtobeIBCs.IBCswhichmeettherequirementsofthischapterarenotconsideredtobecontainersforthepurposesofthisDirective.ThelettersIBConlywillbeusedintherestofthetexttorefertointermediatebulkcontainers.6.5.1.1.2.Exceptionally,IBCsandtheirserviceequipmentnotconformingstrictlytotherequirementsherein,buthavingacceptablealternatives,maybeconsideredbythecompetentauthorityforapproval.Inaddition,inordertotakeintoaccountprogressinscienceandtechnology,theuseofalternativearrangementswhichofferatleastequivalentsafetyinuseinrespectofcompatibilitywiththepropertiesofthesubstancescarriedandequivalentorsuperiorresistancetoimpact,loadingandfire,maybeconsideredbythecompetentauthority.6.5.1.1.3.Theconstruction,equipment,testing,markingandoperationofIBCsshallbesubjecttoacceptancebythecompetentauthorityofthecountryinwhichtheIBCsareapproved.6.5.1.2.(Reserved)6.5.1.3.(Reserved)6.5.1.4.DesignatorycodesystemforIBCs6.5.1.4.1.ThecodeshallconsistoftwoArabicnumeralsasspecifiedin(a),followedbyacapitalletter(s)specifiedin(b),followed,whenspecifiedinanindividualsection,byanArabicnumeralindicatingthecategoryofIBC.a)TypeForsolids,loadedordischargedForliquidsbygravityunderpressureofmorethan10kPa(0,1bar)Rigid112131Flexible13——OfficialJournaloftheEuropeanUnionEN26.1.2004L18/800(b)MaterialsA.Steel(alltypesandsurfacetreatments)B.AluminiumC.NaturalwoodD.PlywoodF.ReconstitutedwoodG.FibreboardH.PlasticsmaterialL.TextileM.Paper,multiwallN.Metal(otherthansteeloraluminium).6.5.1.4.2.ForcompositeIBCs,twocapitallettersinLatincharactersshallbeusedinsequenceinthesecondpositionofthecode.ThefirstshallindicatethematerialoftheinnerreceptacleoftheIBCandthesecondthatoftheouterpackagingoftheIBC.6.5.1.4.3.ThefollowingtypesandcodesofIBCareassigned:MaterialCategoryCodeSubsectionMetal6.5.3.1A.Steelforsolids,loadedordischargedbygravity11Aforsolids,loadedordischargedunderpressure21Aforliquids31AB.Aluminiumforsolids,loadedordischargedbygravity11Bforsolids,loadedordischargedunderpressure21Bforliquids31BN.Otherthansteeloraluminiumforsolids,loadedordischargedbygravity11Nforsolids,loadedordischargedunderpressure21Nforliquids31NFlexible6.5.3.2H.Plasticswovenplasticswithoutcoatingorliner13H1wovenplastics,coated13H2wovenplasticswithliner13H3wovenplastics,coatedandwithliner13H4plasticsfilm13H5L.Textilewithoutcoatingorliner13L1coated13L2withliner13L3coatedandwithliner13L4M.Papermultiwall13M1multiwall,waterresistant13M2H.Rigidplasticsforsolids,loadedordischargedbygravity,fittedwithstructuralequipment11H16.5.3.3forsolids,loadedordischargedbygravity,freestanding11H2forsolids,loadedordischargedunderpressure,fittedwithstructuralequipment21H1forsolids,loadedordischargedunderpressure,freestanding21H2forliquids,fittedwithstructuralequipment31H1forliquids,freestanding31H2OfficialJournaloftheEuropeanUnionEN26.1.2004L18/801MaterialCategoryCodeSubsectionHZ.Compositewithplas-ticsinnerreceptacle(*)forsolids,loadedordischargedbygravity,withrigidplasticsreceptacle11HZ16.5.3.4forsolids,loadedordischargedbygravity,withflexibleplasticsreceptacle11HZ2forsolids,loadedordischargedunderpressure,withrigidplasticsreceptacle21HZ1forsolids,loadedordischargedunderpressure,withflexibleplasticsreceptacle21HZ2forliquids,withrigidplasticsreceptacle31HZ1forliquids,withflexibleplasticsreceptacle31HZ2G.Fibreboardforsolids,loadedordischargedbygravity11G6.5.3.5Wooden6.5.3.6C.Naturalwoodforsolids,loadedordischargedbygravitywithinnerliner11CD.Plywoodforsolids,loadedordischargedbygravity,withinnerliner11DF.Reconstitutedwoodforsolids,loadedordischargedbygravity,withinnerliner11F(*)Thecodeshallbecompletedbyreplacingtheletter‘Z’byacapitalletterinaccordancewith6.5.1.4.1(b)toindicatethenatureofthematerialusedfortheoutercasing.6.5.1.4.4.Theletter‘W’mayfollowtheIBCcode.Theletter‘W’signifiesthattheIBC,althoughofthesametypeindicatedbythecode,ismanufacturedtoaspecificationdifferentfromthosein6.5.3andisconsideredequivalentinaccordancewiththerequirementsin6.5.1.1.26.5.1.5.Constructionrequirements6.5.1.5.1.IBCsshallberesistanttooradequatelyprotectedfromdeteriorationduetotheexternalenvironment.6.5.1.5.2.IBCsshallbesoconstructedandclosedthatnoneofthecontentscanescapeundernormalconditionsofcarriageincludingtheeffectofvibration,orbychangesintemperature,humidityorpressure.6.5.1.5.3.IBCsandtheirclosuresshallbeconstructedofmaterialscompatiblewiththeircontents,orbeprotectedinternally,sothattheyarenotliable:(a)tobeattackedbythecontentssoastomaketheirusedangerous;(b)tocausethecontentstoreactordecompose,orformharmfulordangerouscompoundswiththeIBCs.6.5.1.5.4.Gaskets,whereused,shallbemadeofmaterialsnotsubjecttoattackbythecontentsoftheIBCs.6.5.1.5.5.Allserviceequipmentshallbesopositionedorprotectedastominimisetheriskofescapeofthecontentsowingtodamageduringhandlingandcarriage.6.5.1.5.6.IBCs,theirattachmentsandtheirserviceandstructuralequipmentshallbedesignedtowithstand,withoutlossofcontents,theinternalpressureofthecontentsandthestressesofnormalhandlingandcarriage.IBCsintendedforstackingshallbedesignedforstacking.AnyliftingorsecuringfeaturesofIBCsshallbeofsufficientstrengthtowithstandthenormalconditionsofhandlingandcarriagewithoutgrossdistortionorfailureandshallbesopositionedthatnounduestressiscausedinanypartoftheIBC.6.5.1.5.7.WhereanIBCconsistsofabodywithinaframeworkitshallbesoconstructedthat:(a)thebodydoesnotchafeorrubagainsttheframeworksoastocausematerialdamagetothebody;(b)thebodyisretainedwithintheframeworkatalltimes;OfficialJournaloftheEuropeanUnionEN26.1.2004L18/802(c)theitemsofequipmentarefixedinsuchawaythattheycannotbedamagediftheconnectionsbetweenbodyandframeallowrelativeexpansionormovement.6.5.1.5.8.Whereabottomdischargevalveisfitted,itshallbecapableofbeingmadesecureintheclosedpositionandthewholedischargesystemshallbesuitablyprotectedfromdamage.Valveshavingleverclosuresshallbeabletobesecuredagainstaccidentalopeningandtheopenorclosedpositionshallbereadilyapparent.ForIBCscontainingliquids,asecondarymeansofsealingthedischargeapertureshallalsobeprovided,e.g.ablankflangeorequivalentdevice.6.5.1.5.9.EachIBCshallbecapableofpassingtherelevantperformancetests.6.5.1.6.Testing,certificationandinspection6.5.1.6.1.Qualityassurance:theIBCsshallbemanufacturedandtestedunderaqualityassuranceprogrammewhichsatisfiesthecompetentauthority,inordertoensurethateachmanufacturedIBCmeetstherequirementsofthischapter.6.5.1.6.2.Testrequirements:IBCsshallbesubjecttodesigntypetestsand,ifapplicable,toinitialandperiodictestsinaccordancewith6.5.4.14.6.5.1.6.3.Certification:inrespectofeachdesigntypeofIBCacertificateandmark(asin6.5.2)shallbeissuedattestingthatthedesigntype,includingitsequipment,meetsthetestrequirements.6.5.1.6.4.Inspection:everymetal,rigidplasticsandcompositeIBCshallbeinspectedtothesatisfactionofthecompetentauthority(a)beforeitisputintoservice,andthereafteratintervalsnotexceedingfiveyears,withregardto:(i)conformitytodesigntypeincludingmarking;(ii)internalandexternalcondition;(iii)properfunctioningofserviceequipment.Thermalinsulation,ifany,needberemovedonlytotheextentnecessaryforaproperexaminationofthebodyoftheIBC.(b)atintervalsofnotmorethantwoandahalfyears,withregardto:(i)externalcondition;(ii)properfunctioningofserviceequipment.Thermalinsulation,ifany,needberemovedonlytotheextentnecessaryforaproperexaminationofthebodyoftheIBC.Areportofeachinspectionshallbekeptbytheowneratleastuntilthedateofthenextinspection.6.5.1.6.5.WhenthestructureofanIBCisimpairedasaresultofimpact,(e.g.accident)oranyothercause,itshallberepairedandthensubjectedtothefulltestingandinspectionassetoutin6.5.4.14.3and6.5.1.6.4(a).6.5.1.6.6.Thecompetentauthoritymayatanytimerequireproof,bytestsinaccordancewiththischapter,thatIBCsmeettherequirementsofthedesigntypetests.6.5.2.Marking6.5.2.1.Primarymarking6.5.2.1.1.EachIBCmanufacturedandintendedforuseaccordingtothisDirectiveshallbearmarkingswhicharedurable,legibleandplacedinalocationsoastobereadilyvisible.Letters,numeralsandsymbolsshallbeatleast12mmhighandshallshow:(a)theUnitedNationspackagingsymbol:FormetalIBCsonwhichthemarkingisstampedorembossed,thecapitalletters‘UN’maybeappliedinsteadofthesymbol;(b)thecodedesignatingthetypeofIBCaccordingto6.5.1.4;(c)acapitalletterdesignatingthepackinggroup(s)forwhichthedesigntypehasbeenapproved:(i)XforpackinggroupsI,IIandIII(IBCsforsolidsonly);(ii)YforpackinggroupsIIandIII;(iii)ZforpackinggroupIIIonly;(d)themonthandyear(lasttwodigits)ofmanufacture;(e)theStateauthorisingtheallocationofthemark;indicatedbythedistinguishingsignformotorvehiclesininternationaltraffic(1);OfficialJournaloftheEuropeanUnionEN26.1.2004L18/803(1)DistinguishingsignformotorvehiclesininternationaltrafficprescribedinViennaConventiononRoadTraffic(1968).(f)thenameorsymbolofthemanufacturerandotheridentificationoftheIBCasspecifiedbythecompetentauthority;(g)thestackingtestloadinkg.ForIBCsnotdesignedforstacking,thefigure‘0’shallbeshown;(h)themaximumpermissiblegrossmassor,forflexibleIBCs,themaximumpermissibleload,inkg.Theprimarymarkingrequiredaboveshallbeappliedinthesequenceofthesubparagraphsbelow.Themarkingrequiredby6.5.2.2andanyfurthermarkingauthorisedbyacompetentauthorityshallstillenablethepartsofthemarktobecorrectlyidentified.ExamplesofmarkingsforvarioustypesofIBCinaccordancewith(a)to(h)above:11A/Y/0289NL/Mulder007/5500/1500ForametalIBCforsolidsdischargedforinstancebygravityandmadefromsteel/forpackinggroupsIIandIII/manufacturedinFebruary1989/authorisedbytheNether-lands/manufacturedbyMulderandofadesigntypetowhichthecompetentauthorityhasallocatedserialnumber007/thestackingtestloadinkg/themaximumpermissiblegrossmassinkg.13H3/Z/0389F/Meunier1713/0/1500ForaflexibleIBCforsolidsdischargedforinstancebygravityandmadefromwovenplasticswithaliner/notdesignedtobestacked.31H1/Y/0489GB/9099/10800/1200ForarigidplasticsIBCforliquidsmadefromplasticswithstructuralequipmentwithstandingthestackload.31HA1/Y/0591D/Muller/1683/10800/1200ForacompositeIBCforliquidswitharigidplasticsinnerreceptacleandasteeloutercasing.11C/X/0193S/Aurigny9876/3000/910ForawoodenIBCforsolidswithaninnerlinerauthorisedforpackinggroupIsolids.6.5.2.2.Additionalmarking6.5.2.2.1.EachIBCshallbearthemarkingsrequiredin6.5.2.1and,inaddition,thefollowinginformationwhichmayappearonacorrosion-resistantplatepermanentlyattachedinaplacereadilyaccessibleforinspection:AdditionalmarkingCategoryofIBCMetalRigidplasticsCompositeFibreboardWoodenCapacityinlitres(a)at20°CXXXTaremassinkg(a)XXXXXTest(gauge)pressure,inkPaorbar(a),ifapplicableXXMaximumloading/dischargepres-sureinkPaorbar(a),ifapplicableXXXBodymaterialanditsminimumthicknessinmmXDateoflastleakproofnesstest,ifapplicable(monthandyear)XXXOfficialJournaloftheEuropeanUnionEN26.1.2004L18/804AdditionalmarkingCategoryofIBCMetalRigidplasticsCompositeFibreboardWoodenDateoflastinspection(monthandyear)XXXSerialnumberofthemanufacturerX(a)Theunitusedshallbeindicated.6.5.2.2.2.Inadditiontothemarkingsrequiredin6.5.2.1,flexibleIBCsmaybearapictogramindicatingrecommendedliftingmethods.6.5.2.2.3.TheinnerreceptacleofcompositeIBCsshallbemarkedwithatleastthefollowinginformation:(a)thenameorsymbolofthemanufacturerandotheridentificationoftheIBCasspecifiedbythecompetentauthorityasin6.5.2.1.1(f);(b)thedateofmanufacture,asin6.5.2.1.1(d);(c)thedistinguishingsignoftheStateauthorisingtheallocationofthemark,asin6.5.2.1.1(e).6.5.2.2.4.WhereacompositeIBCsisdesignedinsuchamannerthattheoutercasingisintendedtobedismantledforcarriagewhenempty(suchasforreturnoftheIBCforreusetotheoriginalconsignor),eachofthepartsintendedtobedetachedwhensodismantledshallbemarkedwiththemonthandyearofmanufactureandthenameorsymbolofthemanufacturerandotheridentificationoftheIBCasspecifiedbythecompetentauthority(6.5.2.1.1(f)).6.5.2.3.ConformitytodesigntypeThemarkingindicatesthatIBCscorrespondtoasuccessfullytesteddesigntypeandthattherequirementsreferredtointhecertificatehavebeenmet.6.5.3.SpecificrequirementsforIBCs6.5.3.1.SpecificrequirementsformetalIBCs6.5.3.1.1.TheserequirementsapplytometalIBCsintendedforthecarriageofsolidsandliquids.TherearethreecategoriesofmetalIBCs:(a)thoseforsolidswhichareloadedordischargedbygravity(11A,11B,11N);(b)thoseforsolidswhichareloadedordischargedatagaugepressuregreaterthan10kPa(0,1bar)(21A,21B,21N);and(c)thoseforliquids(31A,31B,31N).6.5.3.1.2.Bodiesshallbemadeofsuitableductilemetalinwhichtheweldabilityhasbeenfullydemonstrated.Weldsshallbeskilfullymadeandaffordcompletesafety.Low-temperatureperformanceofthematerialshallbetakenintoaccountwhenappropriate.6.5.3.1.3.Careshallbetakentoavoiddamagebygalvanicactionduetothejuxtapositionofdissimilarmetals.6.5.3.1.4.AluminiumIBCsintendedforthecarriageofflammableliquidsshallhavenomovableparts,suchascovers,closures,etc.,madeofunprotectedsteelliabletorust,whichmightcauseadangerousreactionbycomingintofrictionalorpercussivecontactwiththealuminium.6.5.3.1.5.MetalIBCsshallbemadeofmetalswhichmeetthefollowingrequirements:(a)forsteeltheelongationatfracture,in%,shallnotbelessthan10000RmwhereRm=guaranteedminimumtensilestrengthofthesteeltobeused,inN/mm2;(b)foraluminiumanditsalloytheelongationatfracture,in%,shallnotbelessthan100006RmOfficialJournaloftheEuropeanUnionEN26.1.2004L18/805Specimensusedtodeterminetheelongationatfractureshallbetakentransverselytothedirectionofrollingandbesosecuredthat:Lo=5dorLo¼5;65ﬃﬃﬃﬃApwhere:Lo=gaugelengthofthespecimenbeforethetestd=diameterA=cross-sectionalareaoftestspecimen.6.5.3.1.6.Minimumwallthickness:(a)forareferencesteelhavingaproductofRm×Ao=10000,thewallthicknessshallnotbelessthan:Capacity(C)inlitresWallthickness(T)inmmTypes11A,11B,11NTypes21A,21B,21N,31A,31B,31NUnprotectedProtectedUnprotectedProtectedC≤10002,01,52,52,01000<C≤2000e=C/2000+1,5e=C/2000+1,0e=C/2000+2,0e=C/2000+1,52000<C≤3000e=C/2000+1,5e=C/2000+1,0e=C/1000+1,0e=C/2000+1,5where:Ao=minimumelongation(asapercentage)ofthereferencesteeltobeusedonfractureundertensilestress(see6.5.3.1.5);(b)formetalsotherthanthereferencesteeldescribedin(a),theminimumwallthicknessisgivenbythefollowingequivalenceformula:where:e1=requiredequivalentwallthicknessofthemetaltobeused(inmm);e0=requiredminimumwallthicknessforthereferencesteel(inmm);Rm1=guaranteedminimumtensilestrengthofthemetaltobeused(inN/mm2)(see(c));A1=minimumelongation(asapercentage)ofthemetaltobeusedonfractureundertensilestress(see6.5.3.1.5).However,innocaseshallthewallthicknessbelessthan1,5mm.(c)Forpurposesofthecalculationdescribedin(b),theguaranteedminimumtensilestrengthofthemetaltobeused(Rm1)shallbetheminimumvalueaccordingtonationalorinternationalmaterialstandards.However,forausteniticsteels,thespecifiedvalueforRmaccordingtothematerialstandardsmaybeincreasedbyupto15%whenagreatervalueisattestedinthematerialinspectioncertificate.Whennomaterialstandardexistsforthematerialinquestion,thevalueofRmshallbetheminimumvalueattestedinthematerialinspectioncertificate.6.5.3.1.7.Pressure-reliefrequirements:IBCsforliquidsshallbecapableofreleasingasufficientamountofvapourintheeventoffireengulfmenttoensurethatnoruptureofthebodywilloccur.Thiscanbeachievedbyconventionalpressurereliefdevicesorbyotherconstructionalmeans.Thestart-to-dischargepressureshallnotbehigherthan65kPa(0,65bar)andnolowerthanthetotalgaugepressureexperiencedintheIBC(i.e.thevapourpressureofthefillingsubstanceplusthepartialpressureoftheairorotherinertgases,minus100kPa(1bar))at55°C,determinedonthebasisofamaximumdegreeoffillingasdefinedin4.1.1.4.Therequiredreliefdevicesshallbefittedinthevapourspace.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8066.5.3.2.SpecificrequirementsforflexibleIBCs6.5.3.2.1.TheserequirementsapplytoflexibleIBCsofthefollowingtypes:13H1wovenplasticswithoutcoatingorliner13H2wovenplastics,coated13H3wovenplasticswithliner13H4wovenplastics,coatedandwithliner13H5plasticsfilm13L1textilewithoutcoatingorliner13L2textile,coated13L3textilewithliner13L4textile,coatedandwithliner13M1paper,multiwall13M2paper,multiwall,waterresistantFlexibleIBCsareintendedforthecarriageofsolidsonly.6.5.3.2.2.Bodiesshallbemanufacturedfromsuitablematerials.ThestrengthofthematerialandtheconstructionoftheflexibleIBCshallbeappropriatetoitscapacityanditsintendeduse.6.5.3.2.3.AllmaterialsusedintheconstructionofflexibleIBCsoftypes13M1and13M2shall,aftercompleteimmersioninwaterfornotlessthan24hours,retainatleast85%ofthetensilestrengthasmeasuredoriginallyonthematerialconditionedtoequilibriumat67%relativehumidityorless.6.5.3.2.4.Seamsshallbeformedbystitching,heatsealing,gluingoranyequivalentmethod.Allstitchedseam-endsshallbesecured.6.5.3.2.5.FlexibleIBCsshallprovideadequateresistancetoageingandtodegradationcausedbyultravioletradiationortheclimaticconditions,orbythesubstancecontained,therebyrenderingthemappropriatetotheirintendeduse.6.5.3.2.6.ForflexibleplasticsIBCswhereprotectionagainstultravioletradiationisrequired,itshallbeprovidedbytheadditionofcarbonblackorothersuitablepigmentsorinhibitors.Theseadditivesshallbecompatiblewiththecontentsandremaineffectivethroughoutthelifeofthebody.Whereuseismadeofcarbonblack,pigmentsorinhibitorsotherthanthoseusedinthemanufactureofthetesteddesigntype,retestingmaybewaivedifchangesinthecarbonblackcontent,thepigmentcontentortheinhibitorcontentdonotadverselyaffectthephysicalpropertiesofthematerialofconstruction.6.5.3.2.7.Additivesmaybeincorporatedintothematerialofthebodytoimprovetheresistancetoageingortoserveotherpurposes,providedthatthesedonotadverselyaffectthephysicalorchemicalpropertiesofthematerial.6.5.3.2.8.NomaterialrecoveredfromusedreceptaclesshallbeusedinthemanufactureofIBCbodies.Productionresiduesorscrapfromthesamemanufacturingprocessmay,however,beused.Componentpartssuchasfittingsandpalletbasesmayalsobeusedprovidedsuchcomponentshavenotinanywaybeendamagedinprevioususe.6.5.3.2.9.Whenfilled,theratioofheighttowidthshallbenotmorethan2:1.6.5.3.2.10.Thelinershallbemadeofasuitablematerial.ThestrengthofthematerialusedandtheconstructionofthelinershallbeappropriatetothecapacityoftheIBCandtheintendeduse.Joinsandclosuresshallbesift-proofandcapableofwithstandingpressuresandimpactsliabletooccurundernormalconditionsofhandlingandcarriage.6.5.3.3.SpecificrequirementsforrigidplasticsIBCs6.5.3.3.1.TheserequirementsapplytorigidplasticsIBCsforthecarriageofsolidsorliquids.RigidplasticsIBCsareofthefollowingtypes:11H1fittedwithstructuralequipmentdesignedtowithstandthewholeloadwhenIBCsarestacked,forsolidswhichareloadedordischargedbygravity11H2freestanding,forsolidswhichareloadedordischargedbygravity21H1fittedwithstructuralequipmentdesignedtowithstandthewholeloadwhenIBCsarestacked,forsolidswhichareloadedordischargedunderpressure21H2freestanding,forsolidswhichareloadedordischargedunderpressureOfficialJournaloftheEuropeanUnionEN26.1.2004L18/80731H1fittedwithstructuralequipmentdesignedtowithstandthewholeloadwhenIBCsarestacked,forliquids31H2freestanding,forliquids.6.5.3.3.2.Thebodyshallbemanufacturedfromsuitableplasticsmaterialofknownspecificationsandbeofadequatestrengthinrelationtoitscapacityanditsintendeduse.Thematerialshallbeadequatelyresistanttoageingandtodegradationcausedbythesubstancecontainedor,whererelevant,byultravioletradiation.Lowtemperatureperformanceshallbetakenintoaccountwhenappropriate.Anypermeationofthesubstancecontainedshallnotconstituteadangerundernormalconditionsofcarriage.6.5.3.3.3.Whereprotectionagainstultravioletradiationisrequired,itshallbeprovidedbytheadditionofcarbonblackorothersuitablepigmentsorinhibitors.Theseadditivesshallbecompatiblewiththecontentsandremaineffectivethroughoutthelifeofthebody.Whereuseismadeofcarbonblack,pigmentsorinhibitorsotherthanthoseusedinthemanufactureofthetesteddesigntype,retestingmaybewaivedifchangesinthecarbonblackcontent,thepigmentcontentortheinhibitorcontentdonotadverselyaffectthephysicalpropertiesofthematerialofconstruction.6.5.3.3.4.Additivesmaybeincorporatedinthematerialofthebodytoimprovetheresistancetoageingortoserveotherpurposes,providedthatthesedonotadverselyaffectthephysicalorchemicalpropertiesofthematerial.6.5.3.3.5.NousedmaterialotherthanproductionresiduesorregrindfromthesamemanufacturingprocessmaybeusedinthemanufactureofrigidplasticsIBCs.6.5.3.3.6.AreliefdeviceshallbefittedtoeachIBCintendedforthecarriageofliquids,capableofreleasingsufficientvapourtopreventthebodyoftheIBCfromrupturingifitissubjectedtoaninternalpressureinexcessofthatforwhichitwashydraulicallytested.Thiscanbeachievedbyconventionalreliefdevicesorbyothermeansofconstruction.Thestart-to-dischargepressureshallnotbehigherthanthepressureusedinthehydraulicpressuretest.6.5.3.4.SpecificrequirementsforcompositeIBCswithplasticsinnerreceptacles6.5.3.4.1.TheserequirementsapplytocompositeIBCsforthecarriageofsolidsandliquidsofthefollowingtypes:11HZ1compositeIBCswitharigidplasticsinnerreceptacle,forsolidsloadedordischargedbygravity11HZ2compositeIBCswithaflexibleplasticsinnerreceptacle,forsolidsloadedordischargedbygravity21HZ1compositeIBCswitharigidplasticsinnerreceptacle,forsolidsloadedordischargedunderpressure21HZ2compositeIBCswithaflexibleplasticsinnerreceptacle,forsolidsloadedordischargedunderpressure31HZ1compositeIBCswitharigidplasticsinnerreceptacle,forliquids31HZ2compositeIBCswithaflexibleplasticsinnerreceptacle,forliquids.Thiscodeshallbecompletedbyreplacingtheletter‘Z’byacapitalletterinaccordancewith6.5.1.4.1(b)toindicatethenatureofthematerialusedfortheoutercasing.6.5.3.4.2.Theinnerreceptacleisnotintendedtoperformacontainmentfunctionwithoutitsoutercasing.A‘rigid’innerreceptacleisareceptaclewhichretainsitsgeneralshapewhenemptywithoutclosuresinplaceandwithoutbenefitoftheoutercasing.Anyinnerreceptaclethatisnot‘rigid’isconsideredtobe‘flexible’.6.5.3.4.3.Theoutercasingnormallyconsistsofrigidmaterialformedsoastoprotecttheinnerreceptaclefromphysicaldamageduringhandlingandcarriagebutisnotintendedtoperformthecontainmentfunction.Itincludesthebasepalletwhereappropriate.6.5.3.4.4.AcompositeIBCwithafullyenclosingoutercasingshallbesodesignedthattheintegrityoftheinnerreceptaclemaybereadilyassessedfollowingtheleakproofnessandhydraulicpressuretests.6.5.3.4.5.IBCsoftype31HZ2shallbelimitedtoacapacityofnotmorethan1250litres.6.5.3.4.6.Theinnerreceptacleshallbemanufacturedfromsuitableplasticsmaterialofknownspecificationsandbeofadequatestrengthinrelationtoitscapacityanditsintendeduse.Thematerialshallbeadequatelyresistanttoageingandtodegradationcausedbythesubstancecontainedor,whererelevant,byultravioletradiation.Lowtemperatureperformanceshallbetakenintoaccountwhenappropriate.Anypermeationofthesubstancecontainedshallnotconstituteadangerundernormalconditionsofcarriage.6.5.3.4.7.Whereprotectionagainstultravioletradiationisrequired,itshallbeprovidedbytheadditionofcarbonblackorothersuitablepigmentsorinhibitors.Theseadditivesshallbecompatiblewiththecontentsandremaineffectivethroughoutthelifeoftheinnerreceptacle.Whereuseismadeofcarbonblack,pigmentsorinhibitors,otherthanthoseusedinthemanufactureofthetesteddesigntype,retestingmaybewaivedifchangesincarbonblackcontent,thepigmentcontentortheinhibitorcontentdonotadverselyaffectthephysicalpropertiesofthematerialofconstruction.6.5.3.4.8.Additivesmaybeincorporatedinthematerialoftheinnerreceptacletoimprovetheresistancetoageingortoserveotherpurposes,providedthatthesedonotadverselyaffectthephysicalorchemicalpropertiesofthematerial.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8086.5.3.4.9.Nousedmaterialotherthanproductionresiduesorregrindfromthesamemanufacturingprocessmaybeusedinthemanufactureofinnerreceptacles.6.5.3.4.10.AreliefdeviceshallbefittedtoeachIBCintendedforthecarriageofliquids,capableofreleasingsufficientvapourtopreventtheinnerreceptacleoftheIBCfromrupturingifitissubjectedtoaninternalpressureinexcessofthatforwhichitwashydraulicallytested.Thiscanbeachievedbyconventionalreliefdevicesorbyothermeansofconstruction.6.5.3.4.11.TheinnerreceptacleofIBCstype31HZ2shallconsistofatleastthreepliesoffilm.6.5.3.4.12.ThestrengthofthematerialandtheconstructionoftheoutercasingshallbeappropriatetothecapacityofthecompositeIBCanditsintendeduse.6.5.3.4.13.Theoutercasingshallbefreeofanyprojectionthatmightdamagetheinnerreceptacle.6.5.3.4.14.Metaloutercasingsshallbeconstructedofasuitablemetalofadequatethickness.6.5.3.4.15.Outercasingsofnaturalwoodshallbeofwellseasonedwood,commerciallydryandfreefromdefectsthatwouldmateriallylessenthestrengthofanypartofthecasing.Thetopsandbottomsmaybemadeofwaterresistantreconstitutedwoodsuchashardboard,particleboardorothersuitabletype.6.5.3.4.16.Outercasingsofplywoodshallbemadeofwellseasonedrotarycut,slicedorsawnveneer,commerciallydryandfreefromdefectsthatwouldmateriallylessenthestrengthofthecasing.Alladjacentpliesshallbegluedwithwaterresistantadhesive.Othersuitablematerialsmaybeusedwithplywoodfortheconstructionofcasings.Casingsshallbefirmlynailedorsecuredtocornerpostsorendsorbeassembledbyequallysuitabledevices.6.5.3.4.17.Thewallsofoutercasingsofreconstitutedwoodshallbemadeofwaterresistantreconstitutedwoodsuchashardboard,particleboardorothersuitabletype.Otherpartsofthecasingsmaybemadeofothersuitablematerial.6.5.3.4.18.Forfibreboardoutercasings,strongandgoodqualitysolidordouble-facedcorrugatedfibreboard(singleormultiwall)shallbeusedappropriatetothecapacityofthecasingandtoitsintendeduse.Thewaterresistanceoftheoutersurfaceshallbesuchthattheincreaseinmass,asdeterminedinatestcarriedoutover30minutesbytheCobbmethodofdeterminingwaterabsorption,isnotgreaterthan155g/m2(seeISO535:1991).Itshallhaveproperbendingqualities.Fibreboardshallbecut,creasedwithoutscoring,andslottedsoastopermitassemblywithoutcracking,surfacebreaksorunduebending.Theflutingofcorrugatedfibreboardshallbefirmlygluedtothefacings.6.5.3.4.19.Theendsoffibreboardoutercasingsmayhaveawoodenframeorbeentirelyofwood.Reinforcementsofwoodenbattensmaybeused.6.5.3.4.20.Manufacturingjoinsinthefibreboardoutercasingshallbetaped,lappedandglued,orlappedandstitchedwithmetalstaples.Lappedjoinsshallhaveanappropriateoverlap.Whereclosingiseffectedbygluingortaping,awaterresistantadhesiveshallbeused.6.5.3.4.21.Wheretheoutercasingisofplasticsmaterial,therelevantrequirementsof6.5.3.4.6to6.5.3.4.9apply,ontheunderstandingthat,inthiscase,therequirementsapplicabletotheinnerreceptacleareapplicabletotheoutercasingofcompositeIBCs.6.5.3.4.22.TheoutercasingofanIBCtype31HZ2shallenclosetheinnerreceptacleonallsides.6.5.3.4.23.AnyintegralpalletbaseformingpartofanIBCoranydetachablepalletshallbesuitableformechanicalhandlingwiththeIBCfilledtoitsmaximumpermissiblegrossmass.6.5.3.4.24.ThepalletorintegralbaseshallbedesignedsoastoavoidanyprotrusionofthebaseoftheIBCthatmightbeliabletodamageinhandling.6.5.3.4.25.Theoutercasingshallbesecuredtoanydetachablepallettoensurestabilityinhandlingandcarriage.Whereadetachablepalletisused,itstopsurfaceshallbefreefromsharpprotrusionsthatmightdamagetheIBC.6.5.3.4.26.Strengtheningdevicessuchastimbersupportstoincreasestackingperformancemaybeusedbutshallbeexternaltotheinnerreceptacle.6.5.3.4.27.WhereIBCsareintendedforstacking,thebearingsurfaceshallbesuchastodistributetheloadinasafemanner.SuchIBCsshallbedesignedsothattheloadisnotsupportedbytheinnerreceptacle.6.5.3.5.SpecificrequirementsforfibreboardIBCs6.5.3.5.1.TheserequirementsapplytofibreboardIBCsforthecarriageofsolidswhichareloadedordischargedbygravity.FibreboardIBCsareofthefollowingtype:11G.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8096.5.3.5.2.FibreboardIBCsshallnotincorporatetopliftingdevices.6.5.3.5.3.Thebodyshallbemadeofstrongandgoodqualitysolidordouble-facedcorrugatedfibreboard(singleormultiwall),appropriatetothecapacityoftheIBCandtoitsintendeduse.Thewaterresistanceoftheoutersurfaceshallbesuchthattheincreaseinmass,asdeterminedinatestcarriedoutoveraperiodof30minutesbytheCobbmethodofdeterminingwaterabsorption,isnotgreaterthan155g/m2(seeISO535:1991).Itshallhaveproperbendingqualities.Fibreboardshallbecut,creasedwithoutscoring,andslottedsoastopermitassemblywithoutcracking,surfacebreaksorunduebending.Theflutingorcorrugatedfibreboardshallbefirmlygluedtothefacings.6.5.3.5.4.Thewalls,includingtopandbottom,shallhaveaminimumpunctureresistanceof15JmeasuredaccordingtoISO3036:1975.6.5.3.5.5.ManufacturingjoinsinthebodyofIBCsshallbemadewithanappropriateoverlapandshallbetaped,glued,stitchedwithmetalstaplesorfastenedbyothermeansatleastequallyeffective.Wherejoinsareeffectedbygluingortaping,awaterresistantadhesiveshallbeused.Metalstaplesshallpasscompletelythroughallpiecestobefastenedandbeformedorprotectedsothatanyinnerlinercannotbeabradedorpuncturedbythem.6.5.3.5.6.Thelinershallbemadeofasuitablematerial.ThestrengthofthematerialusedandtheconstructionofthelinershallbeappropriatetothecapacityoftheIBCandtheintendeduse.Joinsandclosuresshallbesiftproofandcapableofwithstandingpressuresandimpactsliabletooccurundernormalconditionsofhandlingandcarriage.6.5.3.5.7.AnyintegralpalletbaseformingpartofanIBCoranydetachablepalletshallbesuitableformechanicalhandlingwiththeIBCfilledtoitsmaximumpermissiblegrossmass.6.5.3.5.8.ThepalletorintegralbaseshallbedesignedsoastoavoidanyprotrusionofthebaseoftheIBCthatmightbeliabletodamageinhandling.6.5.3.5.9.Thebodyshallbesecuredtoanydetachablepallettoensurestabilityinhandlingandcarriage.Whereadetachablepalletisused,itstopsurfaceshallbefreefromsharpprotrusionsthatmightdamagetheIBC.6.5.3.5.10.Strengtheningdevicessuchastimbersupportstoincreasestackingperformancemaybeusedbutshallbeexternaltotheliner.6.5.3.5.11.WhereIBCsareintendedforstacking,thebearingsurfaceshallbesuchastodistributetheloadinasafemanner.6.5.3.6.SpecificrequirementsforwoodenIBCs6.5.3.6.1.TheserequirementsapplytowoodenIBCsforthecarriageofsolidswhichareloadedordischargedbygravity.WoodenIBCsareofthefollowingtypes:11CNaturalwoodwithinnerliner11DPlywoodwithinnerliner11FReconstitutedwoodwithinnerliner.6.5.3.6.2.WoodenIBCsshallnotincorporatetopliftingdevices.6.5.3.6.3.ThestrengthofthematerialsusedandthemethodofconstructionofthebodyshallbeappropriatetothecapacityandintendeduseoftheIBC.6.5.3.6.4.Naturalwoodshallbewellseasoned,commerciallydryandfreefromdefectsthatwouldmateriallylessenthestrengthofanypartoftheIBC.EachpartoftheIBCshallconsistofonepieceorbeequivalentthereto.Partsareconsideredequivalenttoonepiecewhenasuitablemethodofgluedassemblyisused(asforinstanceLindermannjoint,tongueandgroovejoint,shiplaporrabbetjoint);orbuttjointwithatleasttwocorrugatedmetalfastenersateachjoint,orwhenothermethodsatleastequallyeffectiveareused.6.5.3.6.5.Bodiesofplywoodshallbeatleastthree-ply.Theyshallbemadeofwellseasonedrotarycut,slicedorsawnveneer,commerciallydryandfreefromdefectsthatwouldmateriallylessenthestrengthofthebody.Alladjacentpliesshallbegluedwithwaterresistantadhesive.Othersuitablematerialsmaybeusedwithplywoodfortheconstructionofthebody.6.5.3.6.6.Bodiesofreconstitutedwoodshallbemadeofwaterresistantreconstitutedwoodsuchashardboard,particleboardorothersuitabletype.6.5.3.6.7.IBCsshallbefirmlynailedorsecuredtocornerpostsorendsorbeassembledbyequallysuitabledevices.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8106.5.3.6.8.Thelinershallbemadeofasuitablematerial.ThestrengthofthematerialusedandtheconstructionofthelinershallbeappropriatetothecapacityoftheIBCandtheintendeduse.Joinsandclosuresshallbesiftproofandcapableofwithstandingpressuresandimpactsliabletooccurundernormalconditionsofhandlingandcarriage.6.5.3.6.9.AnyintegralpalletbaseformingpartofanIBCoranydetachablepalletshallbesuitableformechanicalhandlingwiththeIBCfilledtoitsmaximumpermissiblegrossmass.6.5.3.6.10.ThepalletorintegralbaseshallbedesignedsoastoavoidanyprotrusionofthebaseoftheIBCthatmightbeliabletodamageinhandling.6.5.3.6.11.Thebodyshallbesecuredtoanydetachablepallettoensurestabilityinhandlingandcarriage.Whereadetachablepalletisused,itstopsurfaceshallbefreefromsharpprotrusionsthatmightdamagetheIBC.6.5.3.6.12.Strengtheningdevicessuchastimbersupportstoincreasestackingperformancemaybeusedbutshallbeexternaltotheliner.6.5.3.6.13.WhereIBCsareintendedforstacking,thebearingsurfaceshallbesuchastodistributetheloadinasafemanner.6.5.4.TestrequirementsforIBCs6.5.4.1.Performanceandfrequencyoftests6.5.4.1.1.ThedesigntypeofeachIBCshallbetestedinaccordancewithproceduresestablishedandapprovedbythecompetentauthorityforeachIBCdesigntypebeforesuchanIBCisused.AnIBCdesigntypeisdefinedbythedesign,size,materialandthickness,mannerofconstructionandmeansoffillinganddischargingbutmayincludevarioussurfacetreatments.ItalsoincludesIBCswhichdifferfromthedesigntypeonlyintheirlesserexternaldimensions.6.5.4.1.2.TestsshallbecarriedoutonIBCspreparedforcarriage.IBCsshallbefilledasindicatedintherelevantsections.ThesubstancestobecarriedintheIBCsmaybereplacedbyothersubstancesexceptwherethiswouldinvalidatetheresultsofthetests.Forsolids,whenanothersubstanceisuseditshallhavethesamephysicalcharacteristics(mass,grainsize,etc.)asthesubstancetobecarried.Itispermissibletouseadditives,suchasbagsofleadshot,toachievetherequisitetotalpackagemass,solongastheyareplacedsothatthetestresultsarenotaffected.6.5.4.1.3.Inthedroptestsforliquids,whenanothersubstanceisused,itsrelativedensityandviscosityshallbesimilartothoseofthesubstancetobecarried.Watermayalsobeusedfortheliquiddroptestunderthefollowingconditions:(a)wherethesubstancestobecarriedhavearelativedensitynotexceeding1,2,thedropheightsshallbethoseshowninthetablein6.5.4.9.4;(b)wherethesubstancestobecarriedhavearelativedensityexceeding1,2,thedropheightsshallbecalculatedonthebasisoftherelativedensity(d)ofthesubstancetobecarriedroundeduptothefirstdecimalasfollows:PackinggroupIPackinggroupIIPackinggroupIIId×1,5md×1,0md×0,67m6.5.4.2.Designtypetests6.5.4.2.1.OneIBCofeachdesigntype,size,wallthicknessandmannerofconstructionshallbesubmittedtothetestslistedintheordershownin6.5.4.3.5andassetoutin6.5.4.5to6.5.4.12.Thesedesigntypetestsshallbecarriedoutasrequiredbythecompetentauthority.6.5.4.2.2.ThecompetentauthoritymaypermittheselectivetestingofIBCswhichdifferonlyinminorrespectsfromatestedtype,e.g.withsmallreductionsinexternaldimensions.6.5.4.2.3.Ifdetachablepalletsareusedinthetests,thetestreportissuedinaccordancewith6.5.4.13shallincludeatechnicaldescriptionofthepalletsused.6.5.4.3.PreparationofIBCsfortesting6.5.4.3.1.PaperandfibreboardIBCsandcompositeIBCswithfibreboardoutercasingsshallbeconditionedforatleast24hoursinanatmospherehavingacontrolledtemperatureandrelativehumidity(r.h.).Therearethreeoptions,oneofwhichshallbechosen.Thepreferredatmosphereis23±2°Cand50%±2%r.h.Thetwootheroptionsare20±2°Cand65%±2%r.h.;or27±2°Cand65%±2%r.h.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/811NOTEAveragevaluesshallfallwithintheselimits.Short-termfluctuationsandmeasurementlimitationsmaycauseindividualmeasurementstovarybyupto5%relativehumiditywithoutsignificantimpairmentoftestreproducibility.6.5.4.3.2.AdditionalstepsshallbetakentoascertainthattheplasticsmaterialusedinthemanufactureofrigidplasticsIBCs(types31H1and31H2)andcompositeIBCs(types31HZ1and31HZ2)compliesrespectivelywiththerequirementsin6.5.3.3.2to6.5.3.3.4and6.5.3.4.6to6.5.3.4.9.6.5.4.3.3.Toprovethereissufficientchemicalcompatibilitywiththecontainedgoods,thesampleIBCshallbesubjectedtoapreliminarystorageforsixmonths,duringwhichthesamplesshallremainfilledwiththesubstancestheyareintendedtocontainorwithsubstanceswhichareknowntohaveatleastassevereastress-cracking,weakeningormoleculardegradationinfluenceontheplasticsmaterialsinquestion,andafterwhichthesamplesshallbesubmittedtotheapplicabletestslistedinthetablein6.5.4.3.5.6.5.4.3.4.Wherethesatisfactorybehaviouroftheplasticsmaterialhasbeenestablishedbyothermeans,theabovecompatibilitytestmaybedispensedwith.Suchproceduresshallbeatleastequivalenttotheabovecompatibilitytestandrecognisedbythecompetentauthority.6.5.4.3.5.DesigntypetestsrequiredandsequentialorderTypeofIBCBottomliftToplift(a)Stacking(b)Leakproof-nessHydraulicpressureDropTearToppleRighting(e)Metal:11A,11B,11N,21A,1a(a)2a(a)3a——4a(e)———21B,21N,31A,31B,31N1a(a)2a(a)3a4a5a6a(e)———Flexibled(d)—x(c)x——xxxxRigidplas-tics:11H1,11H2,21H1,1a(a)2a3a——4a———21H2,31H1,31H21a(a)2a3a4a5a6a———Composite:11HZ1,11HZ2,1a(a)2a3a——4a(e)———21HZ1,21HZ2,31HZ1,31HZ21a(a)2a3a4a5a6a(e)———Fibreboard1a—2a——3a———Wooden1a—2a——3a———(a)WhenIBCsaredesignedforthismethodofhandling.(b)WhenIBCsaredesignedtobestacked.(c)WhenIBCsaredesignedtobeliftedfromthetoportheside.(d)Requiredtestindicatedbyx;anIBCwhichhaspassedonetestmaybeusedforothertests,inanyorder.(e)AnotherIBCofthesamedesignmaybeusedforthedroptest.6.5.4.4.Bottomlifttest6.5.4.4.1.ApplicabilityForallfibreboardandwoodenIBCs,andforalltypesofIBCwhicharefittedwithmeansofliftingfromthebase,asadesigntypetest.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8126.5.4.4.2.PreparationofIBCsfortestTheIBCshallbeloadedto1,25timesitsmaximumpermissiblegrossmass,theloadbeingevenlydistributed.6.5.4.4.3.MethodoftestingTheIBCshallberaisedandloweredtwicebyalifttruckwiththeforkscentrallypositionedandspacedatthreequartersofthedimensionofthesideofentry(unlessthepointsofentryarefixed).Theforksshallpenetratetothreequartersofthedirectionofentry.Thetestshallberepeatedfromeachpossibledirectionofentry.6.5.4.4.4.CriteriaforpassingthetestNopermanentdeformationwhichrenderstheIBC,includingthebasepallet,ifany,unsafeforcarriageandnolossofcontents.6.5.4.5.Toplifttest6.5.4.5.1.ApplicabilityForalltypesofIBCwhicharedesignedtobeliftedfromthetopandforflexibleIBCsdesignedtobeliftedfromthetoportheside,asadesigntypetest.6.5.4.5.2.PreparationofIBCsfortestMetal,rigidplasticsandcompositeIBCsshallbeloadedtotwicetheirmaximumpermissiblegrossmass.FlexibleIBCsshallbefilledtosixtimestheirmaximumpermissibleload,theloadbeingevenlydistributed.6.5.4.5.3.MethodsoftestingMetalandflexibleIBCsshallbeliftedinthemannerforwhichtheyaredesigneduntilclearofthefloorandmaintainedinthatpositionforaperiodoffiveminutes.RigidplasticsandcompositeIBCsshallbelifted:(a)byeachpairofdiagonallyoppositeliftingdevices,sothatthehoistingforcesareappliedvertically,foraperiodoffiveminutes;and(b)byeachpairofdiagonallyoppositeliftingdevices,sothatthehoistingforcesareappliedtowardthecentreat45ºtothevertical,foraperiodoffiveminutes.6.5.4.5.4.OthermethodsoftoplifttestingandpreparationatleastequallyeffectivemaybeusedforflexibleIBCs.6.5.4.5.5.Criteriaforpassingthetest(a)Metal,rigidplasticsandcompositeIBCs:nopermanentdeformationwhichrenderstheIBC,includingthebasepallet,ifany,unsafeforcarriageandnolossofcontents.(b)FlexibleIBCs:nodamagetotheIBCoritsliftingdeviceswhichrenderstheIBCunsafeforcarriageorhandling.6.5.4.6.Stackingtest6.5.4.6.1.ApplicabilityForalltypesofIBCwhicharedesignedtobestackedoneachother,asadesigntypetest.6.5.4.6.2.PreparationofIBCsfortestIBCs,otherthanflexibleIBCs,shallbeloadedtotheirmaximumpermissiblegrossmass.FlexibleIBCsshallbefilledtonotlessthan95%oftheircapacityandtotheirmaximumpermissibleload,theloadbeingevenlydistributed.6.5.4.6.3.Methodoftesting(a)TheIBCshallbeplacedonitsbaseonlevelhardgroundandsubjectedtoauniformlydistributedsuperimposedtestload(see6.5.4.6.4).IBCsshallbesubjectedtothetestloadforaperiodofatleast:(i)fiveminutes,formetalIBCs;OfficialJournaloftheEuropeanUnionEN26.1.2004L18/813(ii)28daysat40ºC,forrigidplasticsIBCsoftypes11H2,21H2and31H2andforcompositeIBCswithoutercasingsofplasticsmaterialwhichbearthestackingload(i.e.,types11HH1,11HH2,21HH1,21HH2,31HH1and31HH2);(iii)24hours,forallothertypesofIBCs;(b)Theloadshallbeappliedbyoneofthefollowingmethods:(i)oneormoreIBCsofthesametypefilledtothemaximumpermissiblegrossmassand,inthecaseofflexibleIBCs,themaximumpermissibleloadandstackedonthetestIBC;(ii)appropriateweightsloadedontoeitheraflatplateorareproductionofthebaseoftheIBC,whichisstackedonthetestIBC.6.5.4.6.4.CalculationofsuperimposedtestloadTheloadtobeplacedontheIBCshallbe1,8timesthecombinedmaximumpermissiblegrossmassofthenumberofsimilarIBCsthatmaybestackedontopoftheIBCduringcarriage.6.5.4.6.5.Criteriaforpassingthetest(a)AlltypesofIBCotherthanflexibleIBCs:nopermanentdeformationwhichrenderstheIBCincludingthebasepallet,ifany,unsafeforcarriageandnolossofcontents.(b)FlexibleIBCs:nodeteriorationofthebodywhichrenderstheIBCunsafeforcarriageandnolossofcontents.6.5.4.7.Leakproofnesstest6.5.4.7.1.ApplicabilityForthosetypesofIBCusedforliquidsorforsolidsloadedordischargedunderpressure,asadesigntypetestandperiodictest.6.5.4.7.2.PreparationofIBCsfortestThetestshallbecarriedoutbeforethefittingofanythermalinsulationequipment.Ventedclosuresshalleitherbereplacedbysimilarnon-ventedclosuresortheventshallbesealed.6.5.4.7.3.MethodoftestingandpressuretobeappliedThetestshallbecarriedoutforaperiodofatleast10minutesusingairatagaugepressureofnotlessthan20kPa(0,2bar).TheairtightnessoftheIBCshallbedeterminedbyasuitablemethodsuchasbyair-pressuredifferentialtestorbyimmersingtheIBCinwateror,formetalIBCs,bycoatingtheseamsandjointswithasoapsolution.Inthecaseofimmersingacorrectionfactorshallbeappliedforthehydrostaticpressure.Othermethodsatleastequallyeffectivemaybeused.6.5.4.7.4.CriterionforpassingthetestNoleakageofair.6.5.4.8.Internalpressure(hydraulic)test6.5.4.8.1.ApplicabilityForthosetypesofIBCsusedforliquidsorforsolidsloadedordischargedunderpressure,asadesigntypetest.6.5.4.8.2.PreparationofIBCsfortestThetestshallbecarriedoutbeforethefittingofanythermalinsulationequipment.Pressure-reliefdevicesshallberemovedandtheiraperturesplugged,orshallberenderedinoperative.6.5.4.8.3.MethodoftestingThetestshallbecarriedoutforaperiodofatleast10minutesapplyingahydraulicpressurenotlessthanthatindicatedin6.5.4.8.4.TheIBCsshallnotbemechanicallyrestrainedduringthetest.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8146.5.4.8.4.Pressurestobeapplied6.5.4.8.4.1.MetalIBCs:(a)forIBCsoftypes21A,21Band21N,forpackinggroupIsolids,a250kPa(2,5bar)gaugepressure;(b)forIBCsoftypes21A,21B,21N,31A,31Band31N,forpackinggroupsIIorIIIsubstances,a200kPa(2bar)gaugepressure;(c)inaddition,forIBCsoftypes31A,31Band31N,a65kPa(0,65bar)gaugepressure.Thistestshallbeperformedbeforethe200kPa(2bar)test.6.5.4.8.4.2.RigidplasticsandcompositeIBCs:(a)forIBCsoftypes21H1,2lH2,21HZ1and21HZ2:75kPa(0,75bar)(gauge);(b)forIBCsoftypes31H1,31H2,31HZ1and31HZ2:whicheveristhegreateroftwovalues,thefirstasdeterminedbyoneofthefollowingmethods:(i)thetotalgaugepressuremeasuredintheIBC(i.e.thevapourpressureofthefillingsubstanceandthepartialpressureoftheairorotherinertgases,minus100kPa)at55°Cmultipliedbyasafetyfactorof1,5;thistotalgaugepressureshallbedeterminedonthebasisofamaximumdegreeoffillinginaccordancewith4.1.1.4andafillingtemperatureof15°C;(ii)1,75timesthevapourpressureat50°Cofthesubstancetobecarriedminus100kPa,butwithaminimumtestpressureof100kPa;(iii)1,5timesthevapourpressureat55ECofthesubstancetobecarriedminus100kPa,butwithaminimumtestpressureof100kPa;andthesecondasdeterminedbythefollowingmethod:(iv)twicethestaticpressureofthesubstancetobecarried,withaminimumoftwicethestaticpressureofwater.6.5.4.8.5.Criteriaforpassingthetest(s):(a)forIBCsoftypes21A,21B,21N,31A,31Band31N,whensubjectedtothetestpressurespecifiedin6.5.4.8.4.1(a)or(b):noleakage;(b)forIBCsoftypes31A,31Band31N,whensubjectedtothetestpressurespecifiedin6.5.4.8.4.1(c):nopermanentdeformationwhichrenderstheIBCunsafeforcarriageandnoleakage;(c)forrigidplasticsandcompositeIBCs:nopermanentdeformationwhichwouldrendertheIBCunsafeforcarriageandnoleakage.6.5.4.9.Droptest6.5.4.9.1.ApplicabilityForalltypesofIBCs,asadesigntypetest.6.5.4.9.2.PreparationofIBCsfortest(a)metalIBCs:theIBCshallbefilledtonotlessthan95%ofitscapacityforsolidsor98%forliquidsinaccordancewiththedesigntype.Pressure-reliefdevicesshallberemovedandtheiraperturesplugged,orshallberenderedinoperative;(b)flexibleIBCs:theIBCshallbefilledtonotlessthan95%ofitscapacityandtoitsmaximumpermissibleload,theloadbeingevenlydistributed;(c)rigidplasticsandcompositeIBCs:theIBCshallbefilledtonotlessthan95%ofitscapacityforsolidsor98%forliquidsinaccordancewiththedesigntype.Arrangementsprovidedforpressurereliefmayberemovedandpluggedorrenderedinoperative.TestingofIBCsshallbecarriedoutwhenthetemperatureofthetestsampleanditscontentshasbeenreducedtominus18°Corlower.WheretestsamplesofcompositeIBCsarepreparedinthiswaytheconditioningspecifiedin6.5.4.3.1maybewaived.Testliquidsshallbekeptintheliquidstate,ifnecessarybytheadditionofanti-freeze.Thisconditioningmaybedisregardedifthematerialsinquestionareofsufficientductilityandtensilestrengthatlowtemperatures;(d)fibreboardandwoodenIBCs:TheIBCshallbefilledtonotlessthan95%ofitscapacityinaccordancewiththedesigntype.6.5.4.9.3.MethodoftestingTheIBCshallbedroppedonitsbaseontoarigid,non-resilient,smooth,flatandhorizontalsurfaceinsuchamannerastoensurethatthepointofimpactisthatpartofthebaseoftheIBCconsideredtobethemostvulnerable.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/815IBCsof0,45m3orlesscapacityshallalsobedropped:(a)metalIBCs:onthemostvulnerablepartotherthanthepartofthebasetestedinthefirstdrop;(b)flexibleIBCs:onthemostvulnerableside;(c)rigidplastics,composite,fibreboardandwoodenIBCs:flatonaside,flatonthetopandonacorner.ThesameordifferentIBCsmaybeusedforeachdrop.6.5.4.9.4.DropheightPackinggroupIPackinggroupIIPackinggroupIII1,8m1,2m0,8m6.5.4.9.5.Criteriaforpassingthetest(s):(a)metalIBCs:nolossofcontents;(b)flexibleIBCs:nolossofcontents.Aslightdischarge,e.g.fromclosuresorstitchholes,uponimpactshallnotbeconsideredtobeafailureoftheIBCprovidedthatnofurtherleakageoccursaftertheIBChasbeenraisedclearoftheground;(c)rigidplastics,composite,fibreboardandwoodenIBCs:nolossofcontents.AslightdischargefromaclosureuponimpactshallnotbeconsideredtobeafailureoftheIBCprovidedthatnofurtherleakageoccurs.6.5.4.10.Teartest6.5.4.10.1.ApplicabilityForalltypesofflexibleIBCs,asadesigntypetest.6.5.4.10.2.PreparationofIBCsfortestTheIBCshallbefilledtonotlessthan95%ofitscapacityandtoitsmaximumpermissibleload,theloadbeingevenlydistributed.6.5.4.10.3.MethodoftestingOncetheIBCisplacedontheground,a100mmknifescore,completelypenetratingthewallofawideface,ismadeata45°angletotheprincipalaxisoftheIBC,halfwaybetweenthebottomsurfaceandthetoplevelofthecontents.TheIBCshallthenbesubjectedtoauniformlydistributedsuperimposedloadequivalenttotwicethemaximumpermissibleload.Theloadshallbeappliedforatleastfiveminutes.AnIBCwhichisdesignedtobeliftedfromthetoporthesideshallthen,afterremovalofthesuperimposedload,beliftedclearofthefloorandmaintainedinthatpositionforaperiodoffiveminutes.6.5.4.10.4.CriteriaforpassingthetestThecutshallnotpropagatemorethan25%ofitsoriginallength.6.5.4.11.Toppletest6.5.4.11.1.ApplicabilityForalltypesofflexibleIBC,asadesigntypetest.6.5.4.11.2.PreparationofIBCsfortestTheIBCshallbefilledtonotlessthan95%ofitscapacityandtoitsmaximumpermissibleload,theloadbeingevenlydistributed.6.5.4.11.3.MethodoftestingTheIBCshallbecausedtotoppleontoanypartofitstopontoarigid,non-resilient,smooth,flatandhorizontalsurface.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8166.5.4.11.4.ToppleheightPackinggroupIPackinggroupIIPackinggroupIII1,8m1,2m0,8m6.5.4.11.5.CriteriaforpassingthetestNolossofcontents.Aslightdischarge,e.g.fromclosuresorstitchholes,uponimpactshallnotbeconsideredtobeafailureoftheIBCprovidedthatnofurtherleakageoccurs.6.5.4.12.Rightingtest6.5.4.12.1.ApplicabilityForallflexibleIBCsdesignedtobeliftedfromthetoporside,asadesigntypetest.6.5.4.12.2.PreparationofIBCsfortestTheIBCshallbefilledtonotlessthan95%ofitscapacityandtoitsmaximumpermissibleload,theloadbeingevenlydistributed.6.5.4.12.3.MethodoftestingTheIBC,lyingonitsside,shallbeliftedataspeedofatleast0,1m/stouprightposition,clearofthefloor,byoneliftingdeviceorbytwoliftingdeviceswhenfourareprovided.6.5.4.12.4.CriteriaforpassingthetestNodamagetotheIBCoritsliftingdeviceswhichrenderstheIBCunsafeforcarriageorhandling.6.5.4.13.Testreport6.5.4.13.1.AtestreportcontainingatleastthefollowingparticularsshallbedrawnupandshallbemadeavailabletotheusersoftheIBC:1.nameandaddressofthetestfacility;2.nameandaddressofapplicant(whereappropriate);3.auniquetestreportidentification;4.dateofthetestreport;5.manufactureroftheIBC;6.descriptionoftheIBCdesigntype(e.g.dimensions,materials,closures,thickness,etc.)includingmethodofmanufacture(e.g.blowmoulding)andwhichmayincludedrawing(s)and/orphotograph(s);7.maximumcapacity;8.characteristicsoftestcontents,e.g.viscosityandrelativedensityforliquidsandparticlesizeforsolids;9.testdescriptionsandresults;10.thetestreportshallbesignedwiththenameandstatusofthesignatory.6.5.4.13.2.ThetestreportshallcontainstatementsthattheIBCpreparedasforcarriagewastestedinaccordancewiththeappropriaterequirementsofthischapterandthattheuseofotherpackagingmethodsorcomponentsmayrenderitinvalid.Acopyofthetestreportshallbeavailabletothecompetentauthority.6.5.4.14.Initialandperiodictestingofindividualmetal,rigidplasticsandcompositeIBCs6.5.4.14.1.Thesetestsshallbecarriedoutasrequiredbythecompetentauthority.6.5.4.14.2.EachIBCshallcorrespondinallrespectstoitsdesigntype.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8176.5.4.14.3.Eachmetal,rigidplasticsandcompositeIBCforliquids,orforsolidswhichareloadedordischargedunderpressure,shallbesubjectedtotheleakproofnesstest,asaninitialtest(i.e.,beforetheIBCisfirstusedforcarriage)andatintervalsofnotmorethantwoandahalfyears.6.5.4.14.4.Thisleakproofnesstestshallalsoberepeatedafteranyrepair,beforeitisreusedforcarriage.6.5.4.14.5.TheresultsoftestsshallberecordedintestreportstobekeptbytheowneroftheIBC.CHAPTER6.6Requirementsfortheconstructionandtestingoflargepackagings6.6.1.General6.6.1.1.Therequirementsofthischapterdonotapplyto:—packagingsforClass2,exceptlargepackagingsforarticles,includingaerosols;—packagingsforClass6.2,exceptlargepackagingsforclinicalwasteofUNNo3291;—Class7packagescontainingradioactivematerial.6.6.1.2.Largepackagingsshallbemanufacturedandtestedunderaqualityassuranceprogrammewhichsatisfiesthecompetentauthorityinordertoensurethateachmanufacturedpackagingmeetstherequirementsofthischapter.6.6.2.CodefordesignatingtypesoflargepackagingsThecodeusedforlargepackagingsconsistof:(a)twoArabicnumerals:50forrigidlargepackagings;or51forflexiblelargepackagings;and(b)acapitalletterinLatincharacterindicatingthenatureofthematerial,e.g.wood,steeletc.Thecapitallettersusedshallbethoseshownin6.1.2.6.6.6.3.Marking6.6.3.1.Primarymarking.EachlargepackagingmanufacturedandintendedforuseinaccordancewiththeprovisionsofthisDirectiveshallbeardurableandlegiblemarkingsshowing:(a)theUnitedNationspackagingsymbolformetallargepackagingsonwhichthemarkingisstampedorembossed,thecapitalletters‘UN’maybeappliedinsteadofthesymbol;(b)thenumber‘50’designatingalargerigidpackagingor‘51’forflexiblelargepackagings,followedbythematerialtypeinaccordancewith6.5.1.4.1(b);(c)acapitalletterdesignatingthepackinggroup(s)forwhichthedesigntypehasbeenapproved:XforpackinggroupsI,IIandIIIYforpackinggroupsIIandIIIZforpackinggroupIIIonly;(d)themonthandyear(lasttwodigits)ofmanufacture;(e)theStateauthorisingtheallocationofthemark;indicatedbythedistinguishingsignformotorvehiclesininternationaltraffic(1);(f)thenameorsymbolofthemanufacturerandotheridentificationofthelargepackagingsasspecifiedbythecompetentauthority;(g)thestackingtestloadinkg.Forlargepackagingsnotdesignedforstackingthefigure‘0’shallbeshown;(h)Themaximumpermissiblegrossmassinkilograms.Theprimarymarkingrequiredaboveshallbeappliedinthesequenceofthesub-paragraphs.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/818(1)DistinguishingsignformotorvehiclesininternationaltrafficprescribedintheViennaConventiononRoadTraffic(1968).6.6.3.2.Examplesofthemarking50A/X/0596/N/PQRS2500/1000Foralargesteelpackagingsuitableforstacking;stackingload:2500kg;maximumgrossmass:1000kg.50H/Y/0495/D/ABCD9870/800Foralargeplasticspackagingnotsuitableforstacking;maximumgrossmass:800kg.51H/Z/0697/S/19990/500Foralargeflexiblepackagingnotsuitableforstacking;maximumgrossmass:500kg.6.6.4.Specificrequirementsforlargepackagings6.6.4.1.Specificrequirementsformetallargepackagings50Asteel50Baluminium50Nmetal(otherthansteeloraluminium)6.6.4.1.1.Thelargepackagingshallbemadeofsuitableductilemetalinwhichtheweldabilityhasbeenfullydemonstrated.Weldsshallbeskilfullymadeandaffordcompletesafety.Low-temperatureperformanceshallbetakenintoaccountwhenappropriate.6.6.4.1.2.Careshallbetakentoavoiddamagebygalvanicactionduetothejuxtapositionofdissimilarmetals.6.6.4.2.Specificrequirementsforflexiblemateriallargepackagings51Hflexibleplastics51Mflexiblepaper6.6.4.2.1.Thelargepackagingshallbemanufacturedfromsuitablematerials.Thestrengthofthematerialandtheconstructionoftheflexiblelargepackagingsshallbeappropriatetoitscapacityanditsintendeduse.6.6.4.2.2.Allmaterialsusedintheconstructionofflexiblelargepackagingsoftypes51Mshall,aftercompleteimmersioninwaterfornotlessthan24hours,retainatleast85%ofthetensilestrengthasmeasuredoriginallyonthematerialconditionedtoequilibriumat67%relativehumidityorless.6.6.4.2.3.Seamsshallbeformedbystitching,heatsealing,glueingoranyequivalentmethod.Allstitchedseam-endsshallbesecured.6.6.4.2.4.Flexiblelargepackagingsshallprovideadequateresistancetoageingandtodegradationcausedbyultravioletradiationortheclimaticconditions,orbythesubstancecontained,therebyrenderingthemappropriatetotheirintendeduse.6.6.4.2.5.Forplasticsflexiblelargepackagingswhereprotectionagainstultravioletradiationisrequired,itshallbeprovidedbytheadditionofcarbonblackorothersuitablepigmentsorinhibitors.Theseadditivesshallbecompatiblewiththecontentsandremaineffectivethroughoutthelifeofthelargepackaging.Whereuseismadeofcarbonblack,pigmentsorinhibitorsotherthanthoseusedinthemanufactureofthetesteddesigntype,retestingmaybewaivedifchangesinthecarbonblackcontent,thepigmentcontentortheinhibitorcontentdonotadverselyaffectthephysicalpropertiesofthematerialofconstruction.6.6.4.2.6.Additivesmaybeincorporatedintothematerialofthelargepackagingtoimprovetheresistancetoageingortoserveotherpurposes,providedthatthesedonotadverselyaffectthephysicalorchemicalpropertiesofthematerial.6.6.4.2.7.Whenfilled,theratioofheighttowidthshallbenotmorethan2:1.6.6.4.3.Specificrequirementsforplasticslargepackagings50HrigidplasticsOfficialJournaloftheEuropeanUnionEN26.1.2004L18/8196.6.4.3.1.Thelargepackagingshallbemanufacturedfromsuitableplasticsmaterialofknownspecificationsandbeofadequatestrengthinrelationtoitscapacityanditsintendeduse.Thematerialshallbeadequatelyresistanttoageingandtodegradationcausedbythesubstancecontainedor,whererelevant,byultravioletradiation.Lowtemperatureperformanceshallbetakenintoaccountwhenappropriate.Anypermeationofthesubstancecontainedshallnotconstituteadangerundernormalconditionsofcarriage.6.6.4.3.2.Whereprotectionagainstultravioletradiationisrequired,itshallbeprovidedbytheadditionofcarbonblackorothersuitablepigmentsorinhibitors.Theseadditivesshallbecompatiblewiththecontentsandremaineffectivethroughoutthelifeoftheouterpackaging.Whereuseismadeofcarbonblack,pigmentsorinhibitorsotherthanthoseusedinthemanufactureofthetesteddesigntype,retestingmaybewaivedifchangesinthecarbonblackcontent,thepigmentcontentortheinhibitorcontentdonotadverselyaffectthephysicalpropertiesofthematerialofconstruction.6.6.4.3.3.Additivesmaybeincorporatedinthematerialofthelargepackagingtoimprovetheresistancetoageingortoserveotherpurposes,providedthatthesedonotadverselyaffectthephysicalorchemicalpropertiesofthematerial.6.6.4.4.Specificrequirementsforfibreboardlargepackagings50Grigidfibreboard6.6.4.4.1.Strongandgoodqualitysolidordouble-facedcorrugatedfibreboard(singleormultiwall)shallbeused,appropriatetothecapacityofthelargepackagingsandtotheirintendeduse.Thewaterresistanceoftheoutersurfaceshallbesuchthattheincreaseinmass,asdeterminedinatestcarriedoutoveraperiodof30minutesbytheCobbmethodofdeterminingwaterabsorption,isnotgreaterthan155g/m2—seeISO535:1991.Itshallhaveproperbendingqualities.Fibreboardshallbecut,creasedwithoutscoring,andslottedsoastopermitassemblywithoutcracking,surfacebreaksorunduebending.Theflutingorcorrugatedfibreboardshallbefirmlygluedtothefacings.6.6.4.4.2.Thewalls,includingtopandbottom,shallhaveaminimumpunctureresistanceof15JmeasuredaccordingtoISO3036:1975.6.6.4.4.3.Manufacturingjoinsintheouterpackagingoflargepackagingsshallbemadewithanappropriateoverlapandshallbetaped,glued,stitchedwithmetalstaplesorfastenedbyothermeansatleastequallyeffective.Wherejoinsareeffectedbygluingortaping,awaterresistantadhesiveshallbeused.Metalstaplesshallpasscompletelythroughallpiecestobefastenedandbeformedorprotectedsothatanyinnerlinercannotbeabradedorpuncturedbythem.6.6.4.4.4.Anyintegralpalletbaseformingpartofalargepackagingoranydetachablepalletshallbesuitableformechanicalhandlingwiththelargepackagingfilledtoitsmaximumpermissiblegrossmass.6.6.4.4.5.Thepalletorintegralbaseshallbedesignedsoastoavoidanyprotrusionofthebaseofthelargepackagingthatmightbeliabletodamageinhandling.6.6.4.4.6.Thebodyshallbesecuredtoanydetachablepallettoensurestabilityinhandlingandcarriage.Whereadetachablepalletisused,itstopsurfaceshallbefreefromsharpprotrusionsthatmightdamagethelargepackaging.6.6.4.4.7.Strengtheningdevicessuchastimbersupportstoincreasestackingperformancemaybeusedbutshallbeexternaltotheliner.6.6.4.4.8.Wherelargepackagingsareintendedforstacking,thebearingsurfaceshallbesuchastodistributetheloadinasafemanner.6.6.4.5.Specificrequirementsforwoodenlargepackagings50Cnaturalwood50Dplywood50Freconstitutedwood6.6.4.5.1.Thestrengthofthematerialsusedandthemethodofconstructionshallbeappropriatetothecapacityandintendeduseofthelargepackagings.6.6.4.5.2.Naturalwoodshallbewellseasoned,commerciallydryandfreefromdefectsthatwouldmateriallylessenthestrengthofanypartofthelargepackagings.Eachpartofthelargepackagingsshallconsistofonepieceorbeequivalentthereto.PartsareconsideredequivalenttoonepiecewhenasuitablemethodofgluedassemblyisusedasforinstanceLindermannjoint,tongueandgroovejoint,shiplaporrabbetjoint;orbuttjointwithatleasttwocorrugatedmetalfastenersateachjoint,orwhenothermethodsatleastequallyeffectiveareused.6.6.4.5.3.Largepackagingsofplywoodshallbeatleastthree-ply.Theyshallbemadeofwellseasonedrotarycut,slicedorsawnveneer,commerciallydryandfreefromdefectsthatwouldmateriallylessenthestrengthofthelargepackaging.Alladjacentpliesshallbegluedwithwaterresistantadhesive.Othersuitablematerialsmaybeusedwithplywoodfortheconstructionofthelargepackaging.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8206.6.4.5.4.Largepackagingsofreconstitutedwoodshallbemadeofwaterresistantreconstitutedwoodsuchashardboard,particleboardorothersuitabletype.6.6.4.5.5.Largepackagingsshallbefirmlynailedorsecuredtocornerpostsorendsorbeassembledbyequallysuitabledevices.6.6.4.5.6.Anyintegralpalletbaseformingpartofalargepackagingoranydetachablepalletshallbesuitableformechanicalhandlingwiththelargepackagingfilledtoitsmaximumpermissiblegrossmass.6.6.4.5.7.Thepalletorintegralbaseshallbedesignedsoastoavoidanyprotrusionofthebaseofthelargepackagingthatmightbeliabletodamageinhandling.6.6.4.5.8.Thebodyshallbesecuredtoanydetachablepallettoensurestabilityinhandlingandcarriage.Whereadetachablepalletisused,itstopsurfaceshallbefreefromsharpprotrusionsthatmightdamagethelargepackaging.6.6.4.5.9.Strengtheningdevicessuchastimbersupportstoincreasestackingperformancemaybeusedbutshallbeexternaltotheliner.6.6.4.5.10.Wherelargepackagingsareintendedforstacking,thebearingsurfaceshallbesuchastodistributetheloadinasafemanner.6.6.5.Testrequirementsforlargepackagings6.6.5.1.Performanceandfrequencyoftest6.6.5.1.1.Thedesigntypeofeachlargepackagingshallbetestedasprovidedin6.6.5.3inaccordancewithproceduresestablishedandapprovedbythecompetentauthority.6.6.5.1.2.Testsshallbesuccessfullyperformedoneachlargepackagingdesigntypebeforesuchapackagingisused.Alargepackagingdesigntypeisdefinedbythedesign,size,materialandthickness,mannerofconstructionandpacking,butmayincludevarioussurfacetreatments.Italsoincludeslargepackagingswhichdifferfromthedesigntypeonlyintheirlesserdesignheight.6.6.5.1.3.Testsshallberepeatedonproductionsamplesatintervalsestablishedbythecompetentauthority.Forsuchtestsonfibreboardlargepackagings,preparationatambientconditionsisconsideredequivalenttotheprovisionsof6.6.5.2.3.6.6.5.1.4.Testsshallalsoberepeatedaftereachmodificationwhichaltersthedesign,materialormannerofconstructionoflargepackagings.6.6.5.1.5.Thecompetentauthoritymaypermittheselectivetestingoflargepackagingsthatdifferonlyinminorrespectsfromatestedtype,e.g.smallersizesofinnerpackagingsorinnerpackagingsoflowernetmass;andlargepackagingswhichareproducedwithsmallreductionsinexternaldimension(s).6.6.5.1.6.Wherealargepackaginghasbeensuccessfullytestedwithdifferenttypesofinnerpackagings,avarietyofsuchdifferentinnerpackagingsmayalsobeassembledinthislargepackaging.Inaddition,providedanequivalentlevelofperformanceismaintained,thefollowingvariationsininnerpackagingsareallowedwithoutfurthertestingofthepackage:(a)Innerpackagingsofequivalentorsmallersizemaybeusedprovided:(i)theinnerpackagingsareofsimilardesigntothetestedinnerpackagings(e.g.shape—round,rectangular,etc);(ii)thematerialofconstructionoftheinnerpackagings(glass,plastics,metal,etc.)offersresistancetoimpactandstackingforcesequaltoorgreaterthanthatoftheoriginallytestedinnerpackaging;(iii)theinnerpackagingshavethesameorsmalleropeningsandtheclosureisofsimilardesign(e.g.screwcap,frictionlid,etc);(iv)sufficientadditionalcushioningmaterialisusedtotakeupvoidspacesandtopreventsignificantmovementoftheinnerpackagings;and(v)innerpackagingsareorientedwithinthelargepackagingsinthesamemannerasinthetestedpackage;(b)Alessernumberofthetestedinnerpackagings,orofthealternativetypesofinnerpackagingsidentifiedin(a),maybeusedprovidedsufficientcushioningisaddedtofillthevoidspace(s)andtopreventsignificantmovementoftheinnerpackagings.6.6.5.1.7.Thecompetentauthoritymayatanytimerequireproof,bytestsinaccordancewiththissection,thatserially-producedlargepackagingsmeettherequirementsofthedesigntypetests.6.6.5.1.8.Providedthevalidityofthetestresultsisnotaffectedandwiththeapprovalofthecompetentauthority,severaltestsmaybemadeononesample.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8216.6.5.2.Preparationfortesting6.6.5.2.1.Testsshallbecarriedoutonlargepackagingspreparedasforcarriageincludingtheinnerpackagingsorarticlesused.Innerpackagingsshallbefilledtonotlessthan98%oftheirmaximumcapacityforliquidsor95%forsolids.Forlargepackagingswheretheinnerpackagingsaredesignedtocarryliquidsandsolids,separatetestingisrequiredforbothliquidandsolidcontents.Thesubstancesintheinnerpackagingsorthearticlestobecarriedinthelargepackagingsmaybereplacedbyothermaterialorarticlesexceptwherethiswouldinvalidatetheresultsofthetests.Whenotherinnerpackagingsorarticlesareusedtheyshallhavethesamephysicalcharacteristics(mass,etc.)astheinnerpackagingsorarticlestobecarried.Itispermissibletouseadditives,suchasbagsofleadshot,toachievetherequisitetotalpackagemass,solongastheyareplacedsothatthetestresultsarenotaffected.6.6.5.2.2.Largepackagingsmadeofplasticsmaterialsandlargepackagingscontaininginnerpackagingsofplasticmaterials—otherthanbagsintendedtocontainsolidsorarticles—shallbedroptestedwhenthetemperatureofthetestsampleanditscontentshasbeenreducedto–18°Corlower.Thisconditioningmaybedisregardedifthematerialsinquestionareofsufficientductilityandtensilestrengthatlowtemperatures.Wheretestsamplearepreparedinthisway,theconditioningin6.6.5.2.3maybewaived.Testliquidsshallbekeptintheliquidstatebytheadditionofanti-freezeifnecessary.6.6.5.2.3.Largepackagingsoffibreboardshallbeconditionedforatleast24hoursinanatmospherehavingacontrolledtemperatureandrelativehumidity(r.h).Therearethreeoptions,oneofwhichshallbechosen.Thepreferredatmosphereis23°C±2°Cand50%±2%r.h.Thetwootheroptionsare:20°C±2°Cand65%±2%r.h.;or27°C±2°Cand65%±2%r.h.NOTEAveragevaluesshallfallwithintheselimits.Shorttermfluctuationsandmeasurementlimitationsmaycauseindividualmeasurementstovarybyupto±5%relativehumiditywithoutsignificantimpairmentoftestreproducibility.6.6.5.3.Testrequirements6.6.5.3.1.Bottomlifttest6.6.5.3.1.1.ApplicabilityForalltypesoflargepackagingswhicharefittedwithmeansofliftingfromthebase,asadesigntypetest.6.6.5.3.1.2.PreparationoflargepackagingsfortestThelargepackagingsshallbeloadedto1,25timesitsmaximumpermissiblegrossmass,theloadbeingevenlydistributed.6.6.5.3.1.3.MethodoftestingThelargepackagingsshallberaisedandloweredtwicebyalifttruckwiththeforkscentrallypositionedandspacedatthreequartersofthedimensionofthesideofentry(unlessthepointsofentryarefixed).Theforksshallpenetratetothreequartersofthedirectionofentry.Thetestshallberepeatedfromeachpossibledirectionofentry.6.6.5.3.1.4.CriteriaforpassingthetestNopermanentdeformationwhichrendersthelargepackagingsunsafeforcarriageandnolossofcontents.6.6.5.3.2.Toplifttest6.6.5.3.2.1.ApplicabilityFortypesoflargepackagingswhichareintendedtobeliftedfromthetopandfittedwithmeansoflifting,asadesigntypetest.6.6.5.3.2.2.PreparationoflargepackagingsfortestThelargepackagingsshallbeloadedtotwiceitsmaximumpermissiblegrossmass.6.6.5.3.2.3.MethodoftestingThelargepackagingsshallbeliftedinthemannerforwhichitisdesigneduntilclearofthefloorandmaintainedinthatpositionforaperiodoffiveminutes.6.6.5.3.2.4.CriteriaforpassingthetestNopermanentdeformationwhichrendersthelargepackagingsunsafeforcarriageandnolossofcontents.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8226.6.5.3.3.Stackingtest6.6.5.3.3.1.ApplicabilityForalltypesoflargepackagingswhicharedesignedtobestackedoneachother,asadesigntypetest.6.6.5.3.3.2.PreparationoflargepackagingsfortestThelargepackagingsshallbefilledtoitsmaximumpermissiblegrossmass.6.6.5.3.3.3.MethodoftestingThelargepackagingsshallbeplacedonitsbaseonlevelhardgroundandsubjectedtoauniformlydistributedsuperimposedtestload(see6.6.5.3.3.4)foraperiodofatleastfiveminutes,largepackagingsofwood,fibreboardandplasticmaterialsforaperiodof24h.6.6.5.3.3.4.CalculationofsuperimposedtestloadTheloadtobeplacedonthelargepackagingsshallbe1,8timesthecombinedmaximumpermissiblegrossmassofthenumberofsimilarlargepackagingsthatmustbestackedontopofthelargepackagingsduringcarriage.6.6.5.3.3.5.CriteriaforpassingthetestNopermanentdeformationwhichrendersthelargepackagingsunsafeforcarriageandnolossofcontents.6.6.5.3.4.Droptest6.6.5.3.4.1.ApplicabilityForalltypesoflargepackagingsasadesigntypetest.6.6.5.3.4.2.PreparationoflargepackagingsfortestingThelargepackagingsshallbefilledinaccordancewith6.6.5.2.16.6.5.3.4.3.MethodoftestingThelargepackagingsshallbedroppedontoarigid,non-resilient,smooth,flatandhorizontalsurface,insuchamannerastoensurethatthepointofimpactisthatpartofthebaseofthelargepackagingsconsideredtobethemostvulnerable.6.6.5.3.4.4.DropheightPackinggroupIPackinggroupIIPackinggroupIII1,8m1,2m0,8mNOTELargepackagingsforsubstancesandarticlesofClass1,self-reactivesubstancesofClass4.1andorganicperoxidesofClass5.2shallbetestedatthepackinggroupIIperformancelevel.6.6.5.3.4.5.Criteriaforpassingthetest6.6.5.3.4.5.1.Thelargepackagingsshallnotexhibitanydamageliabletoaffectsafetyduringcarriage.Thereshallbenoleakageofthefillingsubstancefrominnerpackaging(s)orarticle(s).6.6.5.3.4.5.2.NoruptureispermittedinlargepackagingsforarticlesofClass1whichwouldpermitthespillageoflooseexplosivesubstancesorarticlesfromthelargepackagings.6.6.5.3.4.5.3.Wherealargepackagingundergoesadroptestthesamplepassesthetestiftheentirecontentsareretainedeveniftheclosureisnolongersift-proof.6.6.5.4.Certificationandtestreport6.6.5.4.1.Inrespectofeachdesigntypeoflargepackagingsacertificateandmark(asin6.6.3)shallbeissuedattestingthatthedesigntypeincludingitsequipmentmeetsthetestrequirements.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8236.6.5.4.2.Atestreportcontainingatleastthefollowingparticularsshallbedrawnupandshallbeavailabletotheusersofthelargepackagings:1.nameandaddressofthetestfacility;2.nameandaddressofapplicant(whereappropriate);3.auniquetestreportidentification;4.dateofthetestreport;5.manufacturerofthelargepackagings;6.descriptionofthelargepackagingsdesigntype(e.g.dimensions,materials,closures,thickness,etc)and/orphotograph(s);7.maximumcapacity/maximumpermissiblegrossmass;8.characteristicsoftestcontents,e.g.typesanddescriptionsofinnerpackagingsorarticlesused;9.testdescriptionsandresults;10.thetestreportshallbesignedwiththenameandstatusofthesignatory.6.6.5.4.3.Thetestreportshallcontainstatementsthatthelargepackagingspreparedasforcarriagewastestedinaccordancewiththeappropriateprovisionsofthischapterandthattheuseofotherpackagingmethodsorcomponentsmayrenderitinvalid.Acopyofthetestreportshallbeavailabletothecompetentauthority.CHAPTER6.7Requirementsforthedesign,construction,inspectionandtestingofportabletanksNOTEForfixedtanks(tank-vehicles),demountabletanksandtank-containersandtankswapbodies,withshellsmadeofmetallicmaterials,andbattery-vehiclesandmultipleelementgascontainers(MEGCs),seeChapter6.8;forfibre-reinforcedplasticstanks,seeChapter6.9;forvacuumoperatedwastetanks,seeChapter6.10.6.7.1.Applicationandgeneralrequirements6.7.1.1.TherequirementsofthischapterapplytoportabletanksintendedforthecarriageofdangerousgoodsofClasses2,3,4.1,4.2,4.3,5.1,5.2,6.1,6.2,7,8and9,byallmodesofcarriage.Inadditiontotherequirementsofthischapter,unlessotherwisespecified,theapplicablerequirementsoftheInternationalConventionforSafeContainers(CSC)1972,asamended,shallbefulfilledbyanymultimodalportabletankwhichmeetsthedefinitionofa‘container’withinthetermsofthatConvention.Additionalrequirementsmayapplytooffshoreportabletanksthatarehandledinopenseas.6.7.1.2.Inrecognitionofscientificandtechnologicaladvances,thetechnicalrequirementsofthischaptermaybevariedbyalternativearrangements.Thesealternativearrangementsshallofferalevelofsafetynotlessthanthatgivenbytherequirementsofthischapterwithrespecttothecompatibilitywithsubstancescarriedandtheabilityoftheportabletanktowithstandimpact,loadingandfireconditions.Forinternationalcarriage,alternativearrangementportabletanksshallbeapprovedbytheapplicablecompetentauthorities.6.7.1.3.Whenasubstanceisnotassignedaportabletankinstruction(T1toT23,T50orT75)inColumn10ofTableAofinChapter3.2,interimapprovalforcarriagemaybeissuedbythecompetentauthorityofthecountryoforigin.Theapprovalshallbeincludedinthedocumentationoftheconsignmentandcontainasaminimumtheinformationnormallyprovidedintheportabletankinstructionsandtheconditionsunderwhichthesubstanceshallbecarried.6.7.2.Requirementsforthedesign,construction,inspectionandtestingofportabletanksintendedforthecarriageofsubstancesofClasses3to96.7.2.1.DefinitionsForthepurposesofthissection:Portabletankmeansamultimodaltankhavingacapacityofmorethan450litresusedforthecarriageofsubstancesofClasses3to9.Theportabletankincludesashellfittedwithserviceequipmentandstructuralequipmentnecessaryforthecarriageofdangeroussubstances.Theportabletankshallbecapableofbeingfilledanddischargedwithouttheremovalofitsstructuralequipment.Itshallpossessstabilisingmembersexternaltotheshell,andshallbecapableofbeingliftedwhenfull.Itshallbedesignedprimarilytobeloadedontoatransportvehicleorshipandshallbeequippedwithskids,mountingsoraccessoriestofacilitatemechanicalhandling.Tank-vehicles,tank-wagons,non-metallictanksandintermediatebulkcontainers(IBCs)arenotconsideredtofallwithinthedefinitionforportabletanks;Shellmeansthepartoftheportabletankwhichretainsthesubstanceintendedforcarriage(tankproper),includingopeningsandtheirclosures,butdoesnotincludeserviceequipmentorexternalstructuralequipment;OfficialJournaloftheEuropeanUnionEN26.1.2004L18/824Serviceequipmentmeansmeasuringinstrumentsandfilling,discharge,venting,safety,heating,coolingandinsulatingdevices;Structuralequipmentmeansthereinforcing,fastening,protectiveandstabilisingmembersexternaltotheshell;Maximumallowableworkingpressure(MAWP)meansapressurethatshallbenotlessthanthehighestofthefollowingpressuresmeasuredatthetopoftheshellwhileinoperatingposition:(a)themaximumeffectivegaugepressureallowedintheshellduringfillingordischarge;or(b)themaximumeffectivegaugepressuretowhichtheshellisdesignedwhichshallbenotlessthanthesumof:(i)theabsolutevapourpressure(inbar)ofthesubstanceat65°C,minus1bar;and(ii)thepartialpressure(inbar)ofairorothergasesintheullagespacebeingdeterminedbyamaximumullagetemperatureof65°Candaliquidexpansionduetoanincreaseinmeanbulktemperatureoftr–tf(tf=fillingtemperature,usually15°C;tr=maximummeanbulktemperature,50°C);Designpressuremeansthepressuretobeusedincalculationsrequiredbyarecognisedpressurevesselcode.Thedesignpressureshallbenotlessthanthehighestofthefollowingpressures:(a)themaximumeffectivegaugepressureallowedintheshellduringfillingordischarge;or(b)thesumof:(i)theabsolutevapourpressure(inbar)ofthesubstanceat65°C,minus1bar;(ii)thepartialpressure(inbar)ofairorothergasesintheullagespacebeingdeterminedbyamaximumullagetemperatureof65°Candaliquidexpansionduetoanincreaseinmeanbulktemperatureoftr–tf(tf=fillingtemperatureusually15°C;tr=maximummeanbulktemperature,50°C);and(iii)aheadpressuredeterminedonthebasisofthedynamicforcesspecifiedin6.7.2.2.12,butnotlessthan0,35bar;(c)twothirdsoftheminimumtestpressurespecifiedintheapplicableportabletankinstructionin4.2.4.2.6;Testpressuremeansthemaximumgaugepressureatthetopoftheshellduringthehydraulicpressuretestequaltonotlessthan1,5timesthedesignpressure.Theminimumtestpressureforportabletanksintendedforspecificsubstancesisspecifiedintheapplicableportabletankinstructionin4.2.4.2.6;Leakproofnesstestmeansatestusinggassubjectingtheshellanditsserviceequipmenttoaneffectiveinternalpressureofnotlessthan25%oftheMAWP;Maximumpermissiblegrossmass(MPGM)meansthesumofthetaremassoftheportabletankandtheheaviestloadauthorisedforcarriage;Referencesteelmeansasteelwithatensilestrengthof370N/mm2andanelongationatfractureof27%;Mildsteelmeansasteelwithaguaranteedminimumtensilestrengthof360N/mm2to440N/mm2andaguaranteedminimumelongationatfractureconformingto6.7.2.3.3.3;Designtemperaturerangefortheshellshallbe–40°Cto50°Cforsubstancescarriedunderambientconditions.Forsubstanceshandledunderelevatedtemperatureconditionsthedesigntemperatureshallbenotlessthanthemaximumtemperatureofthesubstanceduringfilling,dischargeorcarriage.Moreseveredesigntemperaturesshallbeconsideredforportabletankssubjectedtosevereclimaticconditions.6.7.2.2.Generaldesignandconstructionrequirements6.7.2.2.1.Shellsshallbedesignedandconstructedinaccordancewiththerequirementsofapressurevesselcoderecognisedbythecompetentauthority.Shellsshallbemadeofmetallicmaterialssuitableforforming.Thematerialsshallinprincipleconformtonationalorinternationalmaterialstandards.Forweldedshellsonlyamaterialwhoseweldabilityhasbeenfullydemonstratedshallbeused.Weldsshallbeskilfullymadeandaffordcompletesafety.Whenthemanufacturingprocessorthematerialsmakeitnecessary,theshellsshallbesuitablyheat-treatedtoguaranteeadequatetoughnessintheweldandintheheataffectedzones.Inchoosingthematerial,thedesigntemperaturerangeshallbetakenintoaccountwithrespecttoriskofbrittlefracture,tostresscorrosioncrackingandtoresistancetoimpact.Whenfinegrainsteelisused,theguaranteedvalueoftheyieldstrengthshallbenotmorethan460N/mm2andtheguaranteedvalueoftheupperlimitofthetensilestrengthshallbenotmorethan725N/mm2accordingtothematerialspecification.Aluminiummayonlybeusedasaconstructionmaterialwhenindicatedinaportabletankspecialprovisionassignedtoaspecificsubstanceincolumn11ofTableAofChapter3.2orwhenapprovedbythecompetentauthority.Whenaluminiumisauthorised,itshallbeinsulatedtopreventsignificantlossofphysicalpropertieswhensubjectedtoaheatloadof110kW/m2foraperiodofnotlessthan30minutes.Theinsulationshallremaineffectiveatalltemperatureslessthan649°Candshallbejacketedwithamaterialwithameltingpointofnotlessthan700°C.Portabletankmaterialsshallbesuitablefortheexternalenvironmentinwhichtheymaybecarried.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8256.7.2.2.2.Portabletankshells,fittings,andpipeworkshallbeconstructedfrommaterialswhichare:(a)substantiallyimmunetoattackbythesubstance(s)intendedtobecarried;or(b)properlypassivatedorneutralizedbychemicalreaction;or(c)linedwithcorrosion-resistantmaterialdirectlybondedtotheshellorattachedbyequivalentmeans.6.7.2.2.3.Gasketsshallbemadeofmaterialsnotsubjecttoattackbythesubstance(s)intendedtobecarried.6.7.2.2.4.Whenshellsarelined,theliningshallbesubstantiallyimmunetoattackbythesubstance(s)intendedtobecarried,homogeneous,nonporous,freefromperforations,sufficientlyelasticandcompatiblewiththethermalexpansioncharacteristicsoftheshell.Theliningofeveryshell,shellfittingsandpipingshallbecontinuous,andshallextendaroundthefaceofanyflange.Whereexternalfittingsareweldedtothetank,theliningshallbecontinuousthroughthefittingandaroundthefaceofexternalflanges.6.7.2.2.5.Jointsandseamsintheliningshallbemadebyfusingthematerialtogetherorbyotherequallyeffectivemeans.6.7.2.2.6.Contactbetweendissimilarmetalswhichcouldresultindamagebygalvanicactionshallbeavoided.6.7.2.2.7.Thematerialsoftheportabletank,includinganydevices,gaskets,liningsandaccessories,shallnotadverselyaffectthesubstance(s)intendedtobecarriedintheportabletank.6.7.2.2.8.Portabletanksshallbedesignedandconstructedwithsupportstoprovideasecurebaseduringcarriageandwithsuitableliftingandtie-downattachments.6.7.2.2.9.Portabletanksshallbedesignedtowithstand,withoutlossofcontents,atleasttheinternalpressureduetothecontents,andthestatic,dynamicandthermalloadsduringnormalconditionsofhandlingandcarriage.Thedesignshalldemonstratethattheeffectsoffatigue,causedbyrepeatedapplicationoftheseloadsthroughtheexpectedlifeoftheportabletank,havebeentakenintoaccount.6.7.2.2.10.Ashellwhichistobeequippedwithavacuum-reliefdeviceshallbedesignedtowithstand,withoutpermanentdeformation,anexternalpressureofnotlessthan0,21barabovetheinternalpressure.Thevacuum-reliefdeviceshallbesettorelieveatavacuumsettingnotgreaterthanminus(–)0,21barunlesstheshellisdesignedforahigherexternaloverpressure,inwhichcasethevacuum-reliefpressureofthedevicetobefittedshallbenotgreaterthanthetankdesignvacuumpressure.Ashellthatisnottobefittedwithavacuum-reliefdeviceshallbedesignedtowithstand,withoutpermanentdeformationanexternalpressureofnotlessthan0,4barabovetheinternalpressure.6.7.2.2.11.Vacuum-reliefdevicesusedonportabletanksintendedforthecarriageofsubstancesmeetingtheflash-pointcriteriaofClass3,includingelevatedtemperaturesubstancescarriedatorabovetheirflash-point,shallpreventtheimmediatepassageofflameintotheshell,ortheportabletankshallhaveashellcapableofwithstanding,withoutleakageaninternalexplosionresultingfromthepassageofflameintotheshell.6.7.2.2.12.Portabletanksandtheirfasteningsshall,underthemaximumpermissibleload,becapableofabsorbingthefollowingseparatelyappliedstaticforces:(a)inthedirectionoftravel:twicetheMPGMmultipliedbytheaccelerationduetogravity(g)(1);(b)horizontallyatrightanglestothedirectionoftravel:theMPGM(whenthedirectionoftravelisnotclearlydetermined,theforcesshallbeequaltotwicetheMPGM)multipliedbytheaccelerationduetogravity(g)(1);(c)verticallyupwards:theMPGMmultipliedbytheaccelerationduetogravity(g)(1);and(d)verticallydownwards:twicetheMPGM(totalloadingincludingtheeffectofgravity)multipliedbytheaccelerationduetogravity(g)(1).6.7.2.2.13.Undereachoftheforcesin6.7.2.2.12,thesafetyfactortobeobservedshallbeasfollows:(a)formetalshavingaclearlydefinedyieldpoint,asafetyfactorof1,5inrelationtotheguaranteedyieldstrength;or(b)formetalswithnoclearlydefinedyieldpoint,asafetyfactorof1,5inrelationtotheguaranteed0,2%proofstrengthand,forausteniticsteels,the1%proofstrength.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/826(1)Forcalculationpurposesg=9,81m/s2.6.7.2.2.14.Thevaluesofyieldstrengthorproofstrengthshallbethevaluesaccordingtonationalorinternationalmaterialstandards.Whenausteniticsteelsareused,thespecifiedminimumvaluesofyieldstrengthorproofstrengthaccordingtothematerialstandardsmaybeincreasedbyupto15%whenthesegreatervaluesareattestedinthematerialinspectioncertificate.Whennomaterialstandardexistsforthemetalinquestion,thevalueofyieldstrengthorproofstrengthusedshallbeapprovedbythecompetentauthority.6.7.2.2.15.Portabletanksshallbecapableofbeingelectricallyearthedwhenintendedforthecarriageofsubstancesmeetingtheflash-pointcriteriaofClass3includingelevatedtemperaturesubstancescarriedatorabovetheirflash-point.Measuresshallbetakentopreventdangerouselectrostaticdischarge.6.7.2.2.16.Whenrequiredforcertainsubstancesbytheapplicableportabletankinstructionindicatedincolumn10ofTableAofChapter3.2anddescribedin4.2.4.2.6orbyaportabletankspecialprovisionindicatedincolumn11ofTableAofChapter3.2anddescribedin4.2.4.3,portabletanksshallbeprovidedwithadditionalprotection,whichmaytaketheformofadditionalshellthicknessorahighertestpressure,theadditionalshellthicknessorhighertestpressurebeingdeterminedinthelightoftheinherentrisksassociatedwiththecarriageofthesubstancesconcerned.6.7.2.3.Designcriteria6.7.2.3.1.Shellsshallbeofadesigncapableofbeingstress-analysedmathematicallyorexperimentallybyresistancestraingauges,orbyothermethodsapprovedbythecompetentauthority.6.7.2.3.2.Shellsshallbedesignedandconstructedtowithstandahydraulictestpressurenotlessthan1,5timesthedesignpressure.Specificrequirementsarelaiddownforcertainsubstancesintheapplicableportabletankinstructionindicatedincolumn10ofTableAofChapter3.2anddescribedin4.2.4.2.6orbyaportabletankspecialprovisionindicatedincolumn11ofTableAofChapter3.2anddescribedin4.2.4.3.Attentionisdrawntotheminimumshellthicknessrequirementsspecifiedin6.7.2.4.1to6.7.2.4.10.6.7.2.3.3.Formetalsexhibitingaclearlydefinedyieldpointorcharacterizedbyaguaranteedproofstrength(0,2%proofstrength,generally,or1%proofstrengthforausteniticsteels)theprimarymembranestresso(sigma)intheshellshallnotexceed0,75Reor0,50Rm,whicheverislower,atthetestpressure,where:Re=yieldstrengthinN/mm2,or0,2%proofstrengthor,forausteniticsteels,1%proofstrength;Rm=minimumtensilestrengthinN/mm2.6.7.2.3.3.1.ThevaluesofReandRmtobeusedshallbethespecifiedminimumvaluesaccordingtonationalorinternationalmaterialstandards.Whenausteniticsteelsareused,thespecifiedminimumvaluesforReandRmaccordingtothematerialstandardsmaybeincreasedbyupto15%whengreatervaluesareattestedinthematerialinspectioncertificate.Whennomaterialstandardexistsforthemetalinquestion,thevaluesofReandRmusedshallbeapprovedbythecompetentauthorityoritsauthorisedbody.6.7.2.3.3.2.SteelswhichhaveaRe/Rmratioofmorethan0,85arenotallowedfortheconstructionofweldedshells.ThevaluesofReandRmtobeusedindeterminingthisratioshallbethevaluesspecifiedinthematerialinspectioncertificate.6.7.2.3.3.3.Steelsusedintheconstructionofshellsshallhaveanelongationatfracture,in%,ofnotlessthan10000/Rmwithanabsoluteminimumof16%forfinegrainsteelsand20%forothersteels.Aluminiumandaluminiumalloysusedintheconstructionofshellsshallhaveanelongationatfracture,in%,ofnotlessthan10000/6Rmwithanabsoluteminimumof12%.6.7.2.3.3.4.Forthepurposeofdeterminingactualvaluesformaterials,itshallbenotedthatforsheetmetal,theaxisofthetensiletestspecimenshallbeatrightangles(transversely)tothedirectionofrolling.ThepermanentelongationatfractureshallbemeasuredontestspecimensofrectangularcrosssectionsinaccordancewithISO6892:1998usinga50mmgaugelength.6.7.2.4.Minimumshellthickness6.7.2.4.1.Theminimumshellthicknessshallbethegreaterthicknessbasedon:(a)theminimumthicknessdeterminedinaccordancewiththerequirementsof6.7.2.4.2to6.7.2.4.10;(b)theminimumthicknessdeterminedinaccordancewiththerecognisedpressurevesselcodeincludingtherequirementsin6.7.2.3;and(c)theminimumthicknessspecifiedintheapplicableportabletankinstructionindicatedincolumn10ofTableAofChapter3.2anddescribedin4.2.4.2.6orbyaportabletankspecialprovisionindicatedincolumn11ofTableAofChapter3.2anddescribedin4.2.4.3.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8276.7.2.4.2.Thecylindricalportions,ends(heads)andmanholecoversofshellsnotmorethan1,80mindiametershallbenotlessthan5mmthickinthereferencesteelorofequivalentthicknessinthemetaltobeused.Shellsmorethan1,80mindiametershallbenotlessthan6mmthickinthereferencesteelorofequivalentthicknessinthemetaltobeused,exceptthatforpowderedorgranularsolidsubstancesofpackinggroupIIorIIItheminimumthicknessrequirementmaybereducedtonotlessthan5mmthickinthereferencesteelorofequivalentthicknessinthemetaltobeused.6.7.2.4.3.Whenadditionalprotectionagainstshelldamageisprovided,portabletankswithtestpressureslessthan2,65barmayhavetheminimumshellthicknessreduced,inproportiontotheprotectionprovided,asapprovedbythecompetentauthority.However,shellsnotmorethan1,80mindiametershallbenotlessthan3mmthickinthereferencesteelorofequivalentthicknessinthemetaltobeused.Shellsmorethan1,80mindiametershallbenotlessthan4mmthickinthereferencesteelorofequivalentthicknessinthemetaltobeused.6.7.2.4.4.Thecylindricalportions,ends(heads)andmanholecoversofallshellsshallbenotlessthan3mmthickregardlessofthematerialofconstruction.6.7.2.4.5.Theadditionalprotectionreferredtoin6.7.2.4.3maybeprovidedbyoverallexternalstructuralprotection,suchassuitable‘sandwich’constructionwiththeoutersheathing(jacket)securedtotheshell,doublewallconstructionorbyenclosingtheshellinacompleteframeworkwithlongitudinalandtransversestructuralmembers.6.7.2.4.6.Theequivalentthicknessofametalotherthanthethicknessprescribedforthereferencesteelin6.7.2.4.2shallbedeterminedusingthefollowingformula:where:e1=requiredequivalentthickness(inmm)ofthemetaltobeused;e0=minimumthickness(inmm)ofthereferencesteelspecifiedintheapplicableportabletankinstructionindicatedincolumn10ofTableAofChapter3.2anddescribedin4.2.4.2.6orbyaportabletankspecialprovisionindicatedincolumn11ofTableAofChapter3.2anddescribedin4.2.4.3;Rm1=guaranteedminimumtensilestrength(inN/mm2)ofthemetaltobeused(see6.7.2.3.3);A1=guaranteedminimumelongationatfracture(in%)ofthemetaltobeusedaccordingtonationalorinternationalstandards.6.7.2.4.7.Whenintheapplicableportabletankinstructionin4.2.4.2.6,aminimumthicknessof8mm,10mmisspecified,itshallbenotedthatthesethicknessesarebasedonthepropertiesofthereferencesteelandashelldiameterof1,80m.Whenametalotherthanmildsteel(see6.7.2.1)isusedortheshellhasadiameterofmorethan1,80m,thethicknessshallbedeterminedusingthefollowingformula:where:e1=requiredequivalentthickness(inmm)ofthemetaltobeused;e0=minimumthickness(inmm)ofthereferencesteelspecifiedintheapplicableportabletankinstructionindicatedincolumn10ofTableAofChapter3.2anddescribedin4.2.4.2.6orbyaportabletankspecialprovisionindicatedincolumn11ofTableAofChapter3.2anddescribedin4.2.4.3;d1=diameteroftheshell(inm),butnotlessthan1,80m;Rm1=guaranteedminimumtensilestrength(inN/mm2)ofthemetaltobeused(see6.7.2.3.3);A1=guaranteedminimumelongationatfracture(in%)ofthemetaltobeusedaccordingtonationalorinternationalstandards.6.7.2.4.8.Innocaseshallthewallthicknessbelessthanthatprescribedin6.7.2.4.2,6.7.2.4.3and6.7.2.4.4.Allpartsoftheshellshallhaveaminimumthicknessasdeterminedby6.7.2.4.2to6.7.2.4.4.Thisthicknessshallbeexclusiveofanycorrosionallowance.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8286.7.2.4.9.Whenmildsteelisused(see6.7.2.1),calculationusingtheformulain6.7.2.4.6isnotrequired.6.7.2.4.10.Thereshallbenosuddenchangeofplatethicknessattheattachmentoftheends(heads)tothecylindricalportionoftheshell.6.7.2.5.Serviceequipment6.7.2.5.1.Serviceequipmentshallbesoarrangedastobeprotectedagainsttheriskofbeingwrenchedoffordamagedduringhandlingandcarriage.Whentheconnectionbetweentheframeandtheshellallowsrelativemovementbetweenthesubassemblies,theequipmentshallbesofastenedastopermitsuchmovementwithoutriskofdamagetoworkingparts.Theexternaldischargefittings(pipesockets,shut-offdevices),theinternalstop-valveanditsseatingshallbeprotectedagainstthedangerofbeingwrenchedoffbyexternalforces(forexampleusingshearsections).Thefillinganddischargedevices(includingflangesorthreadedplugs)andanyprotectivecapsshallbecapableofbeingsecuredagainstunintendedopening.6.7.2.5.2.Allopeningsintheshell,intendedforfillingordischargingtheportabletankshallbefittedwithamanuallyoperatedstop-valvelocatedasclosetotheshellasreasonablypracticable.Otheropenings,exceptforopeningsleadingtoventingorpressure-reliefdevices,shallbeequippedwitheitherastop-valveoranothersuitablemeansofclosurelocatedasclosetotheshellasreasonablypracticable.6.7.2.5.3.Allportabletanksshallbefittedwithamanholeorotherinspectionopeningsofasuitablesizetoallowforinternalinspectionandadequateaccessformaintenanceandrepairoftheinterior.Compartmentedportabletanksshallhaveamanholeorotherinspectionopeningsforeachcompartment.6.7.2.5.4.Asfarasreasonablypracticable,externalfittingsshallbegroupedtogether.Forinsulatedportabletanks,topfittingsshallbesurroundedbyaspillcollectionreservoirwithsuitabledrains.6.7.2.5.5.Eachconnectiontoaportabletankshallbeclearlymarkedtoindicateitsfunction.6.7.2.5.6.Eachstop-valveorothermeansofclosureshallbedesignedandconstructedtoaratedpressurenotlessthantheMAWPoftheshelltakingintoaccountthetemperaturesexpectedduringcarriage.Allstop-valveswithscrewedspindlesshallclosebyaclockwisemotionofthehandwheel.Forotherstop-valvestheposition(openandclosed)anddirectionofclosureshallbeclearlyindicated.Allstop-valvesshallbedesignedtopreventunintentionalopening.6.7.2.5.7.Nomovingparts,suchascovers,componentsofclosures,etc.,shallbemadeofunprotectedcorrodiblesteelwhentheyareliabletocomeintofrictionalorpercussivecontactwithaluminiumportabletanksintendedforthecarriageofsubstancesmeetingtheflash-pointcriteriaofClass3includingelevatedtemperaturesubstancescarriedatorabovetheirflash-point.6.7.2.5.8.Pipingshallbedesigned,constructedandinstalledsoastoavoidtheriskofdamageduetothermalexpansionandcontraction,mechanicalshockandvibration.Allpipingshallbeofasuitablemetallicmaterial.Weldedpipejointsshallbeusedwhereverpossible.6.7.2.5.9.Jointsincoppertubingshallbebrazedorhaveanequallystrongmetalunion.Themeltingpointofbrazingmaterialsshallbenolowerthan525°C.Thejointsshallnotdecreasethestrengthofthetubingasmayhappenwhencuttingthreads.6.7.2.5.10.TheburstpressureofallpipingandpipefittingsshallbenotlessthanthehighestoffourtimestheMAWPoftheshellorfourtimesthepressuretowhichitmaybesubjectedinservicebytheactionofapumporotherdevice(exceptpressure-reliefdevices).6.7.2.5.11.Ductilemetalsshallbeusedintheconstructionofvalvesandaccessories.6.7.2.6.Bottomopenings6.7.2.6.1.Certainsubstancesshallnotbecarriedinportabletankswithbottomopenings.Whentheapplicableportabletankinstructionidentifiedincolumn10ofTableAofChapter3.2anddescribedin4.2.4.2.6indicatesthatbottomopeningsareprohibitedthereshallbenoopeningsbelowtheliquidleveloftheshellwhenitisfilledtoitsmaximumpermissiblefillinglimit.Whenanexistingopeningiscloseditshallbeaccomplishedbyinternallyandexternallyweldingoneplatetotheshell.6.7.2.6.2.Bottomdischargeoutletsforportabletankscarryingcertainsolid,crystallizableorhighlyviscoussubstancesshallbeequippedwithnotlessthantwoseriallyfittedandmutuallyindependentshut-offdevices.Thedesignoftheequipmentshallbetothesatisfactionofthecompetentauthorityoritsauthorisedbodyandshallinclude:(a)anexternalstop-valvefittedasclosetotheshellasreasonablypracticable;and(b)aliquidtightclosureattheendofthedischargepipe,whichmaybeaboltedblankflangeorascrewcap.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8296.7.2.6.3.Everybottomdischargeoutlet,exceptasprovidedin6.7.2.6.2,shallbeequippedwiththreeseriallyfittedandmutuallyindependentshut-offdevices.Thedesignoftheequipmentshallbetothesatisfactionofthecompetentauthorityoritsauthorisedbodyandinclude:(a)aself-closinginternalstop-valve,thatisastop-valvewithintheshellorwithinaweldedflangeoritscompanionflange,suchthat:(i)thecontroldevicesfortheoperationofthevalvearedesignedsoastopreventanyunintendedopeningthroughimpactorotherinadvertentact;(ii)thevalvemaybeoperablefromaboveorbelow;(iii)ifpossible,thesettingofthevalve(openorclosed)shallbecapableofbeingverifiedfromtheground;(iv)exceptforportabletankshavingacapacityofnotmorethan1000litres,itshallbepossibletoclosethevalvefromanaccessiblepositionoftheportabletankthatisremotefromthevalveitself;and(v)thevalveshallcontinuetobeeffectiveintheeventofdamagetotheexternaldeviceforcontrollingtheoperationofthevalve;(b)anexternalstop-valvefittedasclosetotheshellasreasonablypracticable;and(c)aliquidtightclosureattheendofthedischargepipe,whichmaybeaboltedblankflangeorascrewcap.6.7.2.6.4.Foralinedshell,theinternalstop-valverequiredby6.7.2.6.3(a)maybereplacedbyanadditionalexternalstop-valve.Themanufacturershallsatisfytherequirementsofthecompetentauthorityoritsauthorisedbody.6.7.2.7.Safety-reliefdevices6.7.2.7.1.Allportabletanksshallbefittedwithatleastonepressure-reliefdevice.Allreliefdevicesshallbedesigned,constructedandmarkedtothesatisfactionofthecompetentauthorityoritsauthorisedbody.6.7.2.8.Pressure-reliefdevices6.7.2.8.1.Everyportabletankwithacapacitynotlessthan1900litresandeveryindependentcompartmentofaportabletankwithasimilarcapacity,shallbeprovidedwithoneormorepressure-reliefdevicesofthespring-loadedtypeandmayinadditionhaveafrangiblediscorfusibleelementinparallelwiththespring-loadeddevicesexceptwhenprohibitedbyreferenceto6.7.2.8.3intheapplicableportabletankinstructionin4.2.4.2.6.Thepressure-reliefdevicesshallhavesufficientcapacitytopreventruptureoftheshellduetooverpressurizationorvacuumresultingfromfilling,discharging,orfromheatingofthecontents.6.7.2.8.2.Pressure-reliefdevicesshallbedesignedtopreventtheentryofforeignmatter,theleakageofliquidandthedevelopmentofanydangerousexcesspressure.6.7.2.8.3.Whenrequiredforcertainsubstancesbytheapplicableportabletankinstructionindicatedincolumn10ofTableAofChapter3.2anddescribedin4.2.4.2.6,portabletanksshallhaveapressure-reliefdeviceapprovedbythecompetentauthority.Unlessaportabletankindedicatedserviceisfittedwithanapprovedreliefdeviceconstructedofmaterialscompatiblewiththesubstancecarried,thereliefdeviceshallcompriseafrangiblediscprecedingaspring-loadedpressure-reliefdevice.Whenafrangiblediscisinsertedinserieswiththerequiredpressure-reliefdevice,thespacebetweenthefrangiblediscandthepressure-reliefdeviceshallbeprovidedwithapressuregaugeorsuitabletell-taleindicatorforthedetectionofdiscrupture,pinholing,orleakagewhichcouldcauseamalfunctionofthepressure-reliefsystem.Thefrangiblediscshallruptureatanominalpressure10%abovethestarttodischargepressureofthereliefdevice.6.7.2.8.4.Everyportabletankwithacapacitylessthan1900litresshallbefittedwithapressure-reliefdevicewhichmaybeafrangiblediscwhenthisdisccomplieswiththerequirementsof6.7.2.11.1.Whennospring-loadedpressure-reliefdeviceisused,thefrangiblediscshallbesettoruptureatanominalpressureequaltothetestpressure.6.7.2.8.5.Whentheshellisfittedforpressuredischarge,theinletlineshallbeprovidedwithasuitablepressure-reliefdevicesettooperateatapressurenothigherthantheMAWPoftheshell,andastop-valveshallbefittedasclosetotheshellasreasonablypracticable.6.7.2.9.Settingofpressure-reliefdevices6.7.2.9.1.Itshallbenotedthatthepressure-reliefdevicesshalloperateonlyinconditionsofexcessiveriseintemperature,sincetheshellshallnotbesubjecttounduefluctuationsofpressureduringnormalconditionsofcarriage(see6.7.2.12.2).OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8306.7.2.9.2.Therequiredpressure-reliefdeviceshallbesettostart-to-dischargeatanominalpressureoffivesixthsofthetestpressureforshellshavingatestpressureofnotmorethan4,5barand110%oftwo-thirdsofthetestpressureforshellshavingatestpressureofmorethan4,5bar.Afterdischargethedeviceshallcloseatapressurenotmorethan10%belowthepressureatwhichthedischargestarts.Thedeviceshallremainclosedatalllowerpressures.Thisrequirementdoesnotpreventtheuseofvacuum-relieforcombinationpressure-reliefandvacuum-reliefdevices.6.7.2.10.Fusibleelements6.7.2.10.1.Fusibleelementsshalloperateatatemperaturebetween110°Cand149°Conconditionthatthepressureintheshellatthefusingtemperaturewillbenotmorethanthetestpressure.Theyshallbeplacedatthetopoftheshellwiththeirinletsinthevapourspaceandinnocaseshalltheybeshieldedfromexternalheat.Fusibleelementsshallnotbeutilisedonportabletankswithatestpressurewhichexceeds2,65bar.Fusibleelementsusedonportabletanksintendedforthecarriageofelevatedtemperaturesubstancesshallbedesignedtooperateatatemperaturehigherthanthemaximumtemperaturethatwillbeexperiencedduringcarriageandshallbetothesatisfactionofthecompetentauthorityoritsauthorisedbody.6.7.2.11.Frangiblediscs6.7.2.11.1.Exceptasspecifiedin6.7.2.8.3,frangiblediscsshallbesettoruptureatanominalpressureequaltothetestpressurethroughoutthedesigntemperaturerange.Particularattentionshallbegiventotherequirementsof6.7.2.5.1and6.7.2.8.3iffrangiblediscsareused.6.7.2.11.2.Frangiblediscsshallbeappropriateforthevacuumpressureswhichmaybeproducedintheportabletank.6.7.2.12.Capacityofpressure-reliefdevices6.7.2.12.1.Thespring-loadedpressure-reliefdevicerequiredby6.7.2.8.1shallhaveaminimumcrosssectionalflowareaequivalenttoanorificeof31,75mmdiameter.Vacuum-reliefdevices,whenused,shallhaveacrosssectionalflowareanotlessthan284mm2.6.7.2.12.2.Thecombineddeliverycapacityofthereliefdevicesinconditionofcompletefireengulfmentoftheportabletankshallbesufficienttolimitthepressureintheshellto20%abovethestart-to-dischargepressureofthepressurelimitingdevice.Emergencypressure-reliefdevicesmaybeusedtoachievethefullreliefcapacityprescribed.Thesedevicesmaybefusible,springloadedorfrangibledisccomponents,oracombinationofspring-loadedandfrangiblediscdevices.Thetotalrequiredcapacityofthereliefdevicesmaybedeterminedusingtheformulain6.7.2.12.2.1orthetablein6.7.2.12.2.3.6.7.2.12.2.1.Todeterminethetotalrequiredcapacityofthereliefdevices,whichshallberegardedasbeingthesumoftheindividualcapacitiesofallthecontributingdevices,thefollowingformulashallbeused:where:Q=minimumrequiredrateofdischargeincubicmetresofairpersecond(m3/s)atstandardconditions:1barand0°C(273K);F=isacoefficientwiththefollowingvalue:foruninsulatedshells:F=1;forinsulatedshells:F¼U649–tðÞ13;6butinnocaseislessthan0,25where:U=thermalconductanceoftheinsulation,inkW×m–2×K–1,at38°C;t=actualtemperatureofthesubstanceduringfilling(in°C);whenthistemperatureisunknown,lett=15°C;ThevalueofFgivenaboveforinsulatedshellsmaybetakenprovidedthattheinsulationisinaccordancewith6.7.2.12.2.4;A=totalexternalsurfaceareaofshellinm2;Z=thegascompressibilityfactorintheaccumulatingcondition(whenthisfactorisunknown,letZ=1,0);T=absolutetemperatureinKelvin(°C+273)abovethepressure-reliefdevicesintheaccumulatingcondition;L=thelatentheatofvaporizationoftheliquid,inkJ/kg,intheaccumulatingcondition;M=molecularmassofthedischargedgas;OfficialJournaloftheEuropeanUnionEN26.1.2004L18/831C=aconstantwhichisderivedfromoneofthefollowingformulaeasafunctionoftheratiokofspecificheats:k¼cpcvwhere:cpisthespecificheatatconstantpressure;andcvisthespecificheatatconstantvolume.Whenk>1:Whenk=1orkisunknown:whereeisthemathematicalconstant2,7183Cmayalsobetakenfromthefollowingtable:kCkCkC1,000,6071,260,6601,520,7041,020,6111,280,6641,540,7071,040,6151,300,6671,560,7101,060,6201,320,6711,580,7131,080,6241,340,6741,600,7161,100,6281,360,6781,620,7191,120,6331,380,6811,640,7221,140,6371,400,6851,660,7251,160,6411,420,6881,680,7281,180,6451,440,6911,700,7311,200,6491,460,6952,000,7701,220,6521,480,6982,200,7931,240,6561,500,7016.7.2.12.2.2.Asanalternativetotheformulaabove,shellsdesignedforthecarriageofliquidsmayhavetheirreliefdevicessizedinaccordancewiththetablein6.7.2.12.2.3.ThistableassumesaninsulationvalueofF=1andshallbeadjustedaccordinglywhentheshellisinsulated.Othervaluesusedindeterminingthistableare:M=86,7L=334,94kJ/kgZ=1T=394KC=0,6076.7.2.12.2.3.Minimumrequiredrateofdischarge,Q,incubicmetresperairpersecondat1barand0°C(273K)AExposedarea(squaremetres)Q(Cubicmetresofairpersecond)AExposedarea(squaremetres)Q(Cubicmetresofairpersecond)20,23037,52,53930,320402,677OfficialJournaloftheEuropeanUnionEN26.1.2004L18/832AExposedarea(squaremetres)Q(Cubicmetresofairpersecond)AExposedarea(squaremetres)Q(Cubicmetresofairpersecond)40,40542,52,81450,487452,94960,56547,53,08270,641503,21580,71552,53,34690,788553,476100,85957,53,605120,998603,733141,13262,53,860161,263653,987181,39167,54,112201,517704,23622,51,670754,483251,821804,72627,51,969854,967302,115905,20632,52,258955,442352,4001005,6766.7.2.12.2.4.Insulationsystems,usedforthepurposeofreducingventingcapacity,shallbeapprovedbythecompetentauthorityoritsauthorisedbody.Inallcases,insulationsystemsapprovedforthispurposeshall:(a)remaineffectiveatalltemperaturesupto649°C;and(b)bejacketedwithamaterialhavingameltingpointof700°Corgreater.6.7.2.13.Markingofpressure-reliefdevices6.7.2.13.1.Everypressure-reliefdeviceshallbeclearlyandpermanentlymarkedwiththefollowingparticulars:(a)thepressure(inbarorkPa)ortemperature(in°C)atwhichitissettodischarge;(b)theallowabletoleranceatthedischargepressureforspring-loadeddevices;(c)thereferencetemperaturecorrespondingtotheratedpressureforfrangiblediscs;(d)theallowabletemperaturetoleranceforfusibleelements;and(e)theratedflowcapacityofthedeviceinstandardcubicmetresofairpersecond(m3/s);OfficialJournaloftheEuropeanUnionEN26.1.2004L18/833Whenpracticable,thefollowinginformationshallalsobeshown:(f)themanufacturer'snameandrelevantcataloguenumberofthedevice.6.7.2.13.2.Theratedflowcapacitymarkedonthepressure-reliefdevicesshallbedeterminedaccordingtoISO4126-1:1991.6.7.2.14.Connectionstopressure-reliefdevices6.7.2.14.1.Connectionstopressure-reliefdevicesshallbeofsufficientsizetoenabletherequireddischargetopassunrestrictedtothesafetydevice.Nostop-valveshallbeinstalledbetweentheshellandthepressure-reliefdevicesexceptwhereduplicatedevicesareprovidedformaintenanceorotherreasonsandthestop-valvesservingthedevicesactuallyinusearelockedopenorthestop-valvesareinterlockedsothatatleastoneoftheduplicatedevicesisalwaysinuse.Thereshallbenoobstructioninanopeningleadingtoaventorpressure-reliefdevicewhichmightrestrictorcut-offtheflowfromtheshelltothatdevice.Ventsorpipesfromthepressure-reliefdeviceoutlets,whenused,shalldelivertherelievedvapourorliquidtotheatmosphereinconditionsofminimumback-pressureontherelievingdevices.6.7.2.15.Sitingofpressure-reliefdevices6.7.2.15.1.Eachpressure-reliefdeviceinletshallbesituatedontopoftheshellinapositionasnearthelongitudinalandtransversecentreoftheshellasreasonablypracticable.Allpressure-reliefdeviceinletsshallundermaximumfillingconditionsbesituatedinthevapourspaceoftheshellandthedevicesshallbesoarrangedastoensuretheescapingvapourisdischargedunrestrictedly.Forflammablesubstances,theescapingvapourshallbedirectedawayfromtheshellinsuchamannerthatitcannotimpingeupontheshell.Protectivedeviceswhichdeflecttheflowofvapourarepermissibleprovidedtherequiredrelief-devicecapacityisnotreduced.6.7.2.15.2.Arrangementsshallbemadetopreventaccesstothepressure-reliefdevicesbyunauthorisedpersonsandtoprotectthedevicesfromdamagecausedbytheportabletankoverturning.6.7.2.16.Gaugingdevices6.7.2.16.1.Glasslevel-gaugesandgaugesmadeofotherfragilematerial,whichareindirectcommunicationwiththecontentsofthetankshallnotbeused.6.7.2.17.Portabletanksupports,frameworks,liftingandtie-downattachments6.7.2.17.1.Portabletanksshallbedesignedandconstructedwithasupportstructuretoprovideasecurebaseduringcarriage.Theforcesspecifiedin6.7.2.2.12andthesafetyfactorspecifiedin6.7.2.2.13shallbeconsideredinthisaspectofthedesign.Skids,frameworks,cradlesorothersimilarstructuresareacceptable.6.7.2.17.2.Thecombinedstressescausedbyportabletankmountings(e.g.cradles,framework,etc.)andportabletankliftingandtie-downattachmentsshallnotcauseexcessivestressinanyportionoftheshell.Permanentliftingandtie-downattachmentsshallbefittedtoallportabletanks.Preferablytheyshallbefittedtotheportabletanksupportsbutmaybesecuredtoreinforcingplateslocatedontheshellatthepointsofsupport.6.7.2.17.3.Inthedesignofsupportsandframeworkstheeffectsofenvironmentalcorrosionshallbetakenintoaccount.6.7.2.17.4.Forkliftpocketsshallbecapableofbeingclosedoff.Themeansofclosingforkliftpocketsshallbeapermanentpartoftheframeworkorpermanentlyattachedtotheframework.Singlecompartmentportabletankswithalengthlessthan3,65mneednothaveclosedoffforkliftpocketsprovidedthat:(a)theshellincludingallthefittingsarewellprotectedfrombeinghitbytheforkliftblades;and(b)thedistancebetweenthecentresoftheforkliftpocketsisatleasthalfofthemaximumlengthoftheportabletank.6.7.2.17.5.Whenportabletanksarenotprotectedduringcarriage,accordingto4.2.1.2,theshellsandserviceequipmentshallbeprotectedagainstdamagetotheshellandserviceequipmentresultingfromlateralorlongitudinalimpactoroverturning.Externalfittingsshallbeprotectedsoastoprecludethereleaseoftheshellcontentsuponimpactoroverturningoftheportabletankonitsfittings.Examplesofprotectioninclude:(a)protectionagainstlateralimpactwhichmayconsistoflongitudinalbarsprotectingtheshellonbothsidesatthelevelofthemedianline;(b)protectionoftheportabletankagainstoverturningwhichmayconsistofreinforcementringsorbarsfixedacrosstheframe;(c)protectionagainstrearimpactwhichmayconsistofabumperorframe;(d)protectionoftheshellagainstdamagefromimpactoroverturningbyuseofanISOframeinaccordancewithISO1496-3:1995.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8346.7.2.18.Designapproval6.7.2.18.1.Thecompetentauthorityoritsauthorisedbodyshallissueadesignapprovalcertificateforanynewdesignofaportabletank.Thiscertificateshallattestthataportabletankhasbeensurveyedbythatauthority,issuitableforitsintendedpurposeandmeetstherequirementsofthischapterandwhereappropriate,theprovisionsforsubstancesprovidedinChapter4.2andinTableAofChapter3.2.Whenaseriesofportabletanksaremanufacturedwithoutchangeinthedesign,thecertificateshallbevalidfortheentireseries.Thecertificateshallrefertotheprototypetestreport,thesubstancesorgroupofsubstancesallowedtobecarried,thematerialsofconstructionoftheshellandlining(whenapplicable)andanapprovalnumber.TheapprovalnumbershallconsistofthedistinguishingsignormarkoftheStateinwhoseterritorytheapprovalwasgranted,i.e.thedistinguishingsignforuseininternationaltrafficasprescribedbytheConventiononRoadTraffic,Vienna1968,andaregistrationnumber.Anyalternativearrangementsaccordingto6.7.1.2shallbeindicatedonthecertificate.Adesignapprovalmayservefortheapprovalofsmallerportabletanksmadeofmaterialsofthesamekindandthickness,bythesamefabricationtechniquesandwithidenticalsupports,equivalentclosuresandotherappurtenances.6.7.2.18.2.Theprototypetestreportforthedesignapprovalshallincludeatleastthefollowing:(a)theresultsoftheapplicableframeworktestspecifiedinISO1496-3:1995;(b)theresultsoftheinitialinspectionandtestaccordingto6.7.2.19.3;and(c)theresultsoftheimpacttestin6.7.2.19.1,whenapplicable.6.7.2.19.Inspectionandtesting6.7.2.19.1.ForportabletanksmeetingthedefinitionofcontainerintheCSC,aprototyperepresentingeachdesignshallbesubjectedtoanimpacttest.Theprototypeportabletankshallbeshowntobecapableofabsorbingtheforcesresultingfromanimpactnotlessthanfourtimes(4g)theMPGMofthefullyloadedportabletankatadurationtypicalofthemechanicalshocksexperiencedinrailtransport.Thefollowingisalistingofstandardsdescribingmethodsacceptableforperformingtheimpacttest:—AssociationofAmericanRailroads,ManualofStandardsandRecommendedPractices,SpecificationsforAcceptabilityofTankContainers(AAR.600),1992—CanadianStandardsAssociation(CSA),HighwayTanksandPortableTanksfortheTransportationofDangerousGoods(B620-1987)—DeutscheBahnAGZentralbereichTechnik,MindenPortabletanks,longitudinaldynamicimpacttest—SociéténationaledescheminsdeferfrançaisC.N.E.S.T.002-1966.Tankcontainers,longitudinalexternalstressesanddynamicimpacttests—Spoornet,SouthAfricaEngineeringDevelopmentCentre(EDC)TestingofISOTankContainersMethodEDC/TES/023/000/1991-066.7.2.19.2.Theshellanditemsofequipmentofeachportabletankshallbeinspectedandtestedbeforebeingputintoserviceforthefirsttime(initialinspectionandtest)andthereafteratnotmorethanfive-yearintervals(five-yearperiodicinspectionandtest)withanintermediateperiodicinspectionandtest(2,5-yearperiodicinspectionandtest)midwaybetweenthefive-yearperiodicinspectionsandtests.The2,5-yearinspectionandtestmaybeperformedwithinthreemonthsofthespecifieddate.Anexceptionalinspectionandtestshallbeperformedregardlessofthedateofthelastperiodicinspectionandtestwhennecessaryaccordingto6.7.2.19.7.6.7.2.19.3.Theinitialinspectionandtestofaportabletankshallincludeacheckofthedesigncharacteristics,aninternalandexternalexaminationoftheportabletankanditsfittingswithdueregardtothesubstancestobecarried,andapressuretest.Beforetheportabletankisplacedintoservice,aleakproofnesstestandacheckofthesatisfactoryoperationofallserviceequipmentshallalsobeperformed.Whentheshellanditsfittingshavebeenpressure-testedseparately,theyshallbesubjectedtogetherafterassemblytoaleakproofnesstest.6.7.2.19.4.Thefive-yearperiodicinspectionandtestshallincludeaninternalandexternalexaminationand,asageneralrule,ahydraulicpressuretest.Sheathing,thermalinsulationandthelikeshallberemovedonlytotheextentrequiredforreliableappraisaloftheconditionoftheportabletank.Whentheshellandequipmenthavebeenpressure-testedseparately,theyshallbesubjectedtogetherafterassemblytoaleakproofnesstest.6.7.2.19.5.Theintermediate2,5-yearperiodicinspectionandtestshallatleastincludeaninternalandexternalexaminationoftheportabletankanditsfittingswithdueregardtothesubstancesintendedtobecarried,aleakproofnesstestandacheckofthesatisfactoryoperationofallserviceequipment.Sheathing,thermalinsulationandthelikeshallberemovedonlytotheextentrequiredforreliableappraisaloftheconditionoftheportabletank.Forportabletanksintendedforthecarriageofasinglesubstance,the2,5-yearinternalexaminationmaybewaivedorsubstitutedbyothertestmethodsorinspectionproceduresspecifiedbythecompetentauthorityoritsauthorisedbody.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8356.7.2.19.6.Aportabletankmaynotbefilledandofferedforcarriageafterthedateofexpiryofthelastfive-yearor2,5-yearperiodicinspectionandtestasrequiredby6.7.2.19.2.However,aportabletankfilledpriortothedateofexpiryofthelastperiodicinspectionandtestmaybecarriedforaperiodnottoexceedthreemonthsbeyondthedateofexpiryofthelastperiodictestorinspection.Inaddition,aportabletankmaybecarriedafterthedateofexpiryofthelastperiodictestandinspection:(a)afteremptyingbutbeforecleaning,forpurposesofperformingthenextrequiredtestorinspectionpriortorefilling;and(b)unlessotherwiseapprovedbythecompetentauthority,foraperiodnottoexceedsixmonthsbeyondthedateofexpiryofthelastperiodictestorinspection,inordertoallowthereturnofdangerousgoodsforproperdisposalorrecycling.Referencetothisexemptionshallbementionedinthetransportdocument.6.7.2.19.7.Theexceptionalinspectionandtestisnecessarywhentheportabletankshowsevidenceofdamagedorcorrodedareas,orleakage,orotherconditionsthatindicateadeficiencythatcouldaffecttheintegrityoftheportabletank.Theextentoftheexceptionalinspectionandtestshalldependontheamountofdamageordeteriorationoftheportabletank.Itshallincludeatleastthe2,5-yearinspectionandtestaccordingto6.7.2.19.5.6.7.2.19.8.Theinternalandexternalexaminationsshallensurethat:(a)theshellisinspectedforpitting,corrosion,orabrasions,dents,distortions,defectsinweldsoranyotherconditions,includingleakage,thatmightrendertheportabletankunsafeforcarriage;(b)thepiping,valves,heating/coolingsystem,andgasketsareinspectedforcorrodedareas,defects,oranyotherconditions,includingleakage,thatmightrendertheportabletankunsafeforfilling,dischargeorcarriage;(c)devicesfortighteningmanholecoversareoperativeandthereisnoleakageatmanholecoversorgaskets;(d)missingorlooseboltsornutsonanyflangedconnectionorblankflangearereplacedortightened;(e)allemergencydevicesandvalvesarefreefromcorrosion,distortionandanydamageordefectthatcouldpreventtheirnormaloperation.Remoteclosuredevicesandself-closingstop-valvesshallbeoperatedtodemonstrateproperoperation;(f)linings,ifany,areinspectedinaccordancewithcriteriaoutlinedbytheliningmanufacturer;(g)requiredmarkingsontheportabletankarelegibleandinaccordancewiththeapplicablerequirements;and(h)theframework,supportsandarrangementsforliftingtheportabletankareinasatisfactorycondition.6.7.2.19.9.Theinspectionsandtestsin6.7.2.19.1,6.7.2.19.3,6.7.2.19.4,6.7.2.19.5and6.7.2.19.7shallbeperformedorwitnessedbyanexpertapprovedbythecompetentauthorityoritsauthorisedbody.Whenthepressuretestisapartoftheinspectionandtest,thetestpressureshallbetheoneindicatedonthedataplateoftheportabletank.Whileunderpressure,theportabletankshallbeinspectedforanyleaksintheshell,pipingorequipment.6.7.2.19.10.Inallcaseswhencutting,burningorweldingoperationsontheshellhavebeeneffected,thatworkshallbetotheapprovalofthecompetentauthorityoritsauthorisedbodytakingintoaccountthepressurevesselcodeusedfortheconstructionoftheshell.Apressuretesttotheoriginaltestpressureshallbeperformedaftertheworkiscompleted.6.7.2.19.11.Whenevidenceofanyunsafeconditionisdiscovered,theportabletankshallnotbereturnedtoserviceuntilithasbeencorrectedandthetestisrepeatedandpassed.6.7.2.20.Marking6.7.2.20.1.Everyportabletankshallbefittedwithacorrosionresistantmetalplatepermanentlyattachedtotheportabletankinaconspicuousplacereadilyaccessibleforinspection.Whenforreasonsofportabletankarrangementstheplatecannotbepermanentlyattachedtotheshell,theshellshallbemarkedwithatleasttheinformationrequiredbythepressurevesselcode.Asaminimumatleastthefollowinginformationshallbemarkedontheplatebystampingorbyanyothersimilarmethod.CountryofmanufactureApprovalCountryApprovalNumberForalternativearrangements(see6.7.1.2)‘AA’Manufacturer'snameormarkOfficialJournaloftheEuropeanUnionEN26.1.2004L18/836Manufacturer'sserialnumberAuthorisedbodyforthedesignapprovalOwner'sregistrationnumberYearofmanufacturePressurevesselcodetowhichtheshellisdesignedTestpressure…bar/kPa(gaugepressure)(1)MAWP…bar/kPa(gaugepressure)(1)Externaldesignpressure(2)…bar/kPa(gaugepressure)(1)Designtemperaturerange…°Cto…°CWatercapacityat20°C…litresWatercapacityofeachcompartmentat20°C…litresInitialpressuretestdateandwitnessidentificationMAWPforheating/coolingsystem…bar/kPa(gaugepressure)(1)Shellmaterial(s)andmaterialstandardreference(s)Equivalentthicknessinreferencesteel…mmLiningmaterial(whenapplicable)Dateandtypeofmostrecentperiodictest(s)Month…Year…Testpressure…bar/kPa(gaugepressure)(1)Stampofexpertwhoperformedorwitnessedthemostrecenttest6.7.2.20.2.Thefollowingparticularsshallbemarkedeitherontheportabletankitselforonametalplatefirmlysecuredtotheportabletank:NameoftheoperatorNameofsubstance(s)beingcarriedandmaximummeanbulktemperaturewhenhigherthan50°CMaximumpermissiblegrossmass(MPGM)…kgUnladen(tare)mass…kgNOTEFortheidentificationofthesubstancesbeingcarried,seealsoPart5.6.7.2.20.3.Ifaportabletankisdesignedandapprovedforhandlinginopenseas,thewords‘OFFSHOREPORTABLETANK’shallbemarkedontheidentificationplate.6.7.3.Requirementsforthedesign,construction,inspectionandtestingofportabletanksintendedforthecarriageofnon-refrigeratedliquefiedgases6.7.3.1.DefinitionsForthepurposesofthissection:Portabletankmeansamultimodaltankhavingacapacityofmorethan450litresusedforthecarriageofnon-refrigeratedliquefiedgasesofClass2.Theportabletankincludesashellfittedwithserviceequipmentandstructuralequipmentnecessaryforthecarriageofgases.Theportabletankshallbecapableofbeingfilledanddischargedwithouttheremovalofitsstructuralequipment.Itshallpossessstabilisingmembersexternaltotheshell,andshallbecapableofbeingliftedwhenfull.Itshallbedesignedprimarilytobeloadedontoatransportvehicleorshipandshallbeequippedwithskids,mountingsoraccessoriestofacilitatemechanicalhandling.Tank-vehicles,tank-wagons,non-metallictanks,intermediatebulkcontainers(IBCs),gascylindersandlargereceptaclesarenotconsideredtofallwithinthedefinitionforportabletanks;Shellmeansthepartoftheportabletankwhichretainsthenon-refrigeratedliquefiedgasintendedforcarriage(tankproper),includingopeningsandtheirclosures,butdoesnotincludeserviceequipmentorexternalstructuralequipment;OfficialJournaloftheEuropeanUnionEN26.1.2004L18/837(1)Theunitusedshallbemarked.(2)See6.7.2.2.10.Serviceequipmentmeansmeasuringinstrumentsandfilling,discharge,venting,safetyandinsulatingdevices;Structuralequipmentmeansthereinforcing,fastening,protectiveandstabilisingmembersexternaltotheshell;Maximumallowableworkingpressure(MAWP)meansapressurethatshallbenotlessthanthehighestofthefollowingpressuresmeasuredatthetopoftheshellwhileinoperatingposition,butinnocaselessthan7bar:(a)themaximumeffectivegaugepressureallowedintheshellduringfillingordischarge;or(b)themaximumeffectivegaugepressuretowhichtheshellisdesigned,whichshallbe:(i)foranon-refrigeratedliquefiedgaslistedintheportabletankinstructionT50in4.2.4.2.6,theMAWP(inbar)giveninT50portabletankinstructionforthatgas;(ii)forothernon-refrigeratedliquefiedgases,notlessthanthesumof:—theabsolutevapourpressure(inbar)ofthenon-refrigeratedliquefiedgasatthedesignreferencetemperatureminus1bar,and—thepartialpressure(inbar)ofairorothergasesintheullagespacebeingdeterminedbythedesignreferencetemperatureandtheliquidphaseexpansionduetoanincreaseofthemeanbulktemperatureoftr–tf(tf=fillingtemperature,usually15°C,tr=maximummeanbulktemperature,50°C);Designpressuremeansthepressuretobeusedincalculationsrequiredbyarecognisedpressurevesselcode.Thedesignpressureshallbenotlessthanthehighestofthefollowingpressures:(a)themaximumeffectivegaugepressureallowedintheshellduringfillingordischarge;or(b)thesumof:(i)themaximumeffectivegaugepressuretowhichtheshellisdesignedasdefinedin(b)oftheMAWPdefinition(seeabove);and(ii)aheadpressuredeterminedonthebasisofthedynamicforcesspecifiedin6.7.3.2.9,butnotlessthan0,35bar;Testpressuremeansthemaximumgaugepressureatthetopoftheshellduringthepressuretest;Leakproofnesstestmeansatestusinggassubjectingtheshellanditsserviceequipmenttoaneffectiveinternalpressureofnotlessthan25%oftheMAWP;Maximumpermissiblegrossmass(MPGM)meansthesumofthetaremassoftheportabletankandtheheaviestloadauthorisedforcarriage;Referencesteelmeansasteelwithatensilestrengthof370N/mm2andanelongationatfractureof27%;Mildsteelmeansasteelwithaguaranteedminimumtensilestrengthof360N/mm2to440N/mm2andaguaranteedminimumelongationatfractureconformingto6.7.3.3.3.3;Designtemperaturerangefortheshellshallbe–40°Cto50°Cfornon-refrigeratedliquefiedgasescarriedunderambientconditions.Moreseveredesigntemperaturesshallbeconsideredforportabletankssubjectedtosevereclimaticconditions;DesignreferencetemperaturemeansthetemperatureatwhichthevapourpressureofthecontentsisdeterminedforthepurposeofcalculatingtheMAWP.Thedesignreferencetemperatureshallbelessthanthecriticaltemperatureofthenon-refrigeratedliquefiedgasintendedtobecarriedtoensurethatthegasatalltimesisliquefied.Thisvalueforeachportabletanktypeisasfollows:(a)shellwithadiameterof1,5metresorless:65°C;(b)shellwithadiameterofmorethan1,5metres:(i)withoutinsulationorsunshield:60°C;(ii)withsunshield(see6.7.3.2.12):55°C;and(iii)withinsulation(see6.7.3.2.12):50°C;Fillingdensitymeanstheaveragemassofnon-refrigeratedliquefiedgasperlitreofshellcapacity(kg/l).ThefillingdensityisgiveninportabletankinstructionT50in4.2.4.2.6.6.7.3.2.Generaldesignandconstructionrequirements6.7.3.2.1.Shellsshallbedesignedandconstructedinaccordancewiththerequirementsofapressurevesselcoderecognisedbythecompetentauthority.Shellsshallbemadeofsteelsuitableforforming.Thematerialsshallinprincipleconformtonationalorinternationalmaterialstandards.Forweldedshells,onlyamaterialwhoseweldabilityhasbeenfullydemonstratedshallbeused.Weldsshallbeskilfullymadeandaffordcompletesafety.Whenthemanufacturingprocessorthematerialsmakeitnecessary,theshellsshallbesuitabilityheat-treatedtoguaranteeadequatetoughnessintheweldandintheheataffectedzones.Inchoosingthematerialthedesigntemperaturerangeshallbetakenintoaccountwithrespecttoriskofbrittlefracture,tostresscorrosioncrackingandtoresistancetoimpact.Whenfinegrainsteelisused,theguaranteedvalueoftheyieldstrengthshallbenotmorethan460N/mm2andtheguaranteedvalueoftheupperlimitofthetensilestrengthshallbenotmorethan725N/mm2accordingtothematerialspecification.Portabletankmaterialsshallbesuitablefortheexternalenvironmentinwhichtheymaybecarried.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8386.7.3.2.2.Portabletankshells,fittingsandpipeworkshallbeconstructedofmaterialswhichare:(a)substantiallyimmunetoattackbythenon-refrigeratedliquefiedgas(es)intendedtobecarried;or(b)properlypassivatedorneutralisedbychemicalreaction.6.7.3.2.3.Gasketsshallbemadeofmaterialscompatiblewiththenon-refrigeratedliquefiedgas(es)intendedtobecarried.6.7.3.2.4.Contactbetweendissimilarmetalswhichcouldresultindamagebygalvanicactionshallbeavoided.6.7.3.2.5.Thematerialsoftheportabletank,includinganydevices,gaskets,andaccessories,shallnotadverselyaffectthenon-refrigeratedliquefiedgas(es)intendedforcarriageintheportabletank.6.7.3.2.6.Portabletanksshallbedesignedandconstructedwithsupportstoprovideasecurebaseduringcarriageandwithsuitableliftingandtie-downattachments.6.7.3.2.7.Portabletanksshallbedesignedtowithstand,withoutlossofcontents,atleasttheinternalpressureduetothecontents,andthestatic,dynamicandthermalloadsduringnormalconditionsofhandlingandcarriage.Thedesignshalldemonstratethattheeffectsoffatigue,causedbyrepeatedapplicationoftheseloadsthroughtheexpectedlifeoftheportabletank,havebeentakenintoaccount.6.7.3.2.8.Shellsshallbedesignedtowithstandanexternalpressureofatleast0,4bar(gaugepressure)abovetheinternalpressurewithoutpermanentdeformation.Whentheshellistobesubjectedtoasignificantvacuumbeforefillingorduringdischargeitshallbedesignedtowithstandanexternalpressureofatleast0,9bar(gaugepressure)abovetheinternalpressureandshallbeprovenatthatpressure.6.7.3.2.9.Portabletanksandtheirfasteningsshall,underthemaximumpermissibleload,becapableofabsorbingthefollowingseparatelyappliedstaticforces:(a)inthedirectionoftravel:twicetheMPGMmultipliedbytheaccelerationduetogravity(g)(1);(b)horizontallyatrightanglestothedirectionoftravel:theMPGM(whenthedirectionoftravelisnotclearlydetermined,theforcesshallbeequaltotwicetheMPGM)multipliedbytheaccelerationduetogravity(g)(1);(c)verticallyupwards:theMPGMmultipliedbytheaccelerationduetogravity(g)(1);and(d)verticallydownwards:twicetheMPGM(totalloadingincludingtheeffectofgravity)multipliedbytheaccelerationduetogravity(g)(1).6.7.3.2.10.Undereachoftheforcesin6.7.3.2.9,thesafetyfactortobeobservedshallbeasfollows:(a)forsteelshavingaclearlydefinedyieldpoint,asafetyfactorof1,5inrelationtotheguaranteedyieldstrength;or(b)forsteelswithnoclearlydefinedyieldpoint,asafetyfactorof1,5inrelationtotheguaranteed0,2%proofstrengthand,forausteniticsteels,the1%proofstrength.6.7.3.2.11.Thevaluesofyieldstrengthorproofstrengthshallbethevaluesaccordingtonationalorinternationalmaterialstandards.Whenausteniticsteelsareused,thespecifiedminimumvaluesofyieldstrengthandproofstrengthaccordingtothematerialstandardsmaybeincreasedbyupto15%whenthesegreatervaluesareattestedinthematerialinspectioncertificate.Whennomaterialstandardexistsforthesteelinquestion,thevalueofyieldstrengthorproofstrengthusedshallbeapprovedbythecompetentauthority.6.7.3.2.12.Whentheshellsintendedforthecarriageofnon-refrigeratedliquefiedgasesareequippedwiththermalinsulation,thethermalinsulationsystemsshallsatisfythefollowingrequirements:(a)itshallconsistofashieldcoveringnotlessthantheupperthirdbutnotmorethantheupperhalfofthesurfaceoftheshellandseparatedfromtheshellbyanairspaceabout40mmacross;(b)itshallconsistofacompletecladdingofadequatethicknessofinsulatingmaterialsprotectedsoastopreventtheingressofmoistureanddamageundernormalconditionsofcarriageandsoastoprovideathermalconductanceofnotmorethan0,67(W.m–2.K–1);(c)whentheprotectivecoveringissoclosedastobegas-tight,adeviceshallbeprovidedtopreventanydangerouspressurefromdevelopingintheinsulatinglayerintheeventofinadequategastightnessoftheshellorofitsitemsofequipment;and(d)thethermalinsulationshallnotinhibitaccesstothefittingsanddischargedevices.6.7.3.2.13.Portabletanksintendedforthecarriageofflammablenon-refrigeratedliquefiedgasesshallbecapableofbeingelectricallyearthed.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/839(1)Forcalculationpurposesg=9,81m/s2.6.7.3.3.Designcriteria6.7.3.3.1.Shellsshallbeofacircularcross-section.6.7.3.3.2.Shellsshallbedesignedandconstructedtowithstandatestpressurenotlessthan1,3timesthedesignpressure.TheshelldesignshalltakeintoaccounttheminimumMAWPvaluesprovidedinportabletankinstructionT50in4.2.4.2.6foreachnon-refrigeratedliquefiedgasintendedforcarriage.Attentionisdrawntotheminimumshellthicknessrequirementsfortheseshellsspecifiedin6.7.3.4.6.7.3.3.3.Forsteelsexhibitingaclearlydefinedyieldpointorcharacterisedbyaguaranteedproofstrength(0,2%proofstrength,generally,or1%proofstrengthforausteniticsteels)theprimarymembranestressΣ(sigma)intheshellshallnotexceed0,75Reor0,50Rm,whicheverislower,atthetestpressure,where:Re=yieldstrengthinN/mm2,or0,2%proofstrengthor,forausteniticsteels,1%proofstress;Rm=minimumtensilestrengthinN/mm2.6.7.3.3.3.1.ThevaluesofReandRmtobeusedshallbethespecifiedminimumvaluesaccordingtonationalorinternationalmaterialstandards.Whenausteniticsteelsareused,thespecifiedminimumvaluesforReandRmaccordingtothematerialstandardsmaybeincreasedbyupto15%whenthesegreatervaluesareattestedinthematerialinspectioncertificate.Whennomaterialstandardexistsforthesteelinquestion,thevaluesofReandRmusedshallbeapprovedbythecompetentauthorityoritsauthorisedbody.6.7.3.3.3.2.SteelswhichhaveaRe/Rmratioofmorethan0,85arenotallowedfortheconstructionofweldedshells.ThevaluesofReandRmtobeusedindeterminingthisratioshallbethevaluesspecifiedinthematerialinspectioncertificate.6.7.3.3.3.3.Steelsusedintheconstructionofshellsshallhaveanelongationatfracture,in%,ofnotlessthan10000/Rmwithanabsoluteminimumof16%forfinegrainsteelsand20%forothersteels.6.7.3.3.3.4.Forthepurposeofdeterminingactualvaluesformaterials,itshallbenotedthatforsheetmetal,theaxisofthetensiletestspecimenshallbeatrightangles(transversely)tothedirectionofrolling.ThepermanentelongationatfractureshallbemeasuredontestspecimensofrectangularcrosssectionsinaccordancewithISO6892:1998usinga50mmgaugelength.6.7.3.4.Minimumshellthickness6.7.3.4.1.Theminimumshellthicknessshallbethegreaterthicknessbasedon:(a)theminimumthicknessdeterminedinaccordancewiththerequirementsin6.7.3.4;and(b)theminimumthicknessdeterminedinaccordancewiththerecognisedpressurevesselcodeincludingtherequirementsin6.7.3.3.6.7.3.4.2.Thecylindricalportions,ends(heads)andmanholecoversofshellsofnotmorethan1,80mindiametershallbenotlessthan5mmthickinthereferencesteelorofequivalentthicknessinthesteeltobeused.Shellsofmorethan1,80mindiametershallbenotlessthan6mmthickinthereferencesteelorofequivalentthicknessinthesteeltobeused.6.7.3.4.3.Thecylindricalportions,ends(heads)andmanholecoversofallshellsshallbenotlessthan4mmthickregardlessofthematerialofconstruction.6.7.3.4.4.Theequivalentthicknessofasteelotherthanthethicknessprescribedforthereferencesteelin6.7.3.4.2shallbedeterminedusingthefollowingformula:where:e1=requiredequivalentthickness(inmm)ofthesteeltobeused;e0=minimumthickness(inmm)forthereferencesteelspecifiedin6.7.3.4.2;Rm1=guaranteedminimumtensilestrength(inN/mm2)ofthesteeltobeused(see6.7.3.3.3);A1=guaranteedminimumelongationatfracture(in%)ofthesteeltobeusedaccordingtonationalorinternationalstandards.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8406.7.3.4.5.Innocaseshallthewallthicknessbelessthanthatprescribedin6.7.3.4.1to6.7.3.4.3.Allpartsoftheshellshallhaveaminimumthicknessasdeterminedby6.7.3.4.1to6.7.3.4.3.Thisthicknessshallbeexclusiveofanycorrosionallowance.6.7.3.4.6.Whenmildsteelisused(see6.7.3.1),calculationusingtheformulain6.7.3.4.4isnotrequired.6.7.3.4.7.Thereshallbenosuddenchangeofplatethicknessattheattachmentoftheends(heads)tothecylindricalportionoftheshell.6.7.3.5.Serviceequipment6.7.3.5.1.Serviceequipmentshallbesoarrangedastobeprotectedagainsttheriskofbeingwrenchedoffordamagedduringhandlingandcarriage.Whentheconnectionbetweentheframeandtheshellallowsrelativemovementbetweenthesubassemblies,theequipmentshallbesofastenedastopermitsuchmovementwithoutriskofdamagetoworkingparts.Theexternaldischargefittings(pipesockets,shut-offdevices),theinternalstop-valveanditsseatingshallbeprotectedagainstthedangerofbeingwrenchedoffbyexternalforces(forexampleusingshearsections).Thefillinganddischargedevices(includingflangesorthreadedplugs)andanyprotectivecapsshallbecapableofbeingsecuredagainstunintendedopening.6.7.3.5.2.Allopeningswithadiameterofmorethan1,5mminshellsofportabletanks,exceptopeningsforpressure-reliefdevices,inspectionopeningsandclosedbleedholes,shallbefittedwithatleastthreemutuallyindependentshut-offdevicesinseries,thefirstbeinganinternalstop-valve,excessflowvalveorequivalentdevice,thesecondbeinganexternalstop-valveandthethirdbeingablankflangeorequivalentdevice.6.7.3.5.2.1.Whenaportabletankisfittedwithanexcessflowvalve,theexcessflowvalveshallbesofittedthatitsseatingisinsidetheshellorinsideaweldedflangeor,whenfittedexternally,itsmountingsshallbedesignedsothatintheeventofimpactitseffectivenessshallbemaintained.Theexcessflowvalvesshallbeselectedandfittedsoastocloseautomaticallywhentheratedflowspecifiedbythemanufacturerisreached.Connectionsandaccessoriesleadingtoorfromsuchavalveshallhaveacapacityforaflowmorethantheratedflowoftheexcessflowvalve.6.7.3.5.3.Forfillinganddischargeopenings,thefirstshut-offdeviceshallbeaninternalstop-valveandthesecondshallbeastop-valveplacedinanaccessiblepositiononeachdischargeandfillingpipe.6.7.3.5.4.Forfillinganddischargebottomopeningsofportabletanksintendedforthecarriageofflammableand/ortoxicnon-refrigeratedliquefiedgasestheinternalstop-valveshallbeaquickclosingsafetydevicewhichclosesautomaticallyintheeventofunintendedmovementoftheportabletankduringfillingordischargeorfireengulfment.Exceptforportabletankshavingacapacityofnotmorethan1000litres,itshallbepossibletooperatethisdevicebyremotecontrol.6.7.3.5.5.Inadditiontofilling,dischargeandgaspressureequalisingorifices,shellsmayhaveopeningsinwhichgauges,thermometersandmanometerscanbefitted.Connectionsforsuchinstrumentsshallbemadebysuitableweldednozzlesorpocketsandnotbescrewedconnectionsthroughtheshell.6.7.3.5.6.Allportabletanksshallbefittedwithmanholesorotherinspectionopeningsofsuitablesizetoallowforinternalinspectionandadequateaccessformaintenanceandrepairoftheinterior.6.7.3.5.7.Externalfittingsshallbegroupedtogethersofarasreasonablypracticable.6.7.3.5.8.Eachconnectiononaportabletankshallbeclearlymarkedtoindicateitsfunction.6.7.3.5.9.Eachstop-valveorothermeansofclosureshallbedesignedandconstructedtoaratedpressurenotlessthantheMAWPoftheshelltakingintoaccountthetemperaturesexpectedduringcarriage.Allstop-valveswithascrewedspindleshallclosebyaclockwisemotionofthehandwheel.Forotherstop-valvestheposition(openandclosed)anddirectionofclosureshallbeclearlyindicated.Allstop-valvesshallbedesignedtopreventunintentionalopening.6.7.3.5.10.Pipingshallbedesigned,constructedandinstalledsoastoavoidtheriskofdamageduetothermalexpansionandcontraction,mechanicalshockandvibration.Allpipingshallbeofsuitablemetallicmaterial.Weldedpipejointsshallbeusedwhereverpossible.6.7.3.5.11.Jointsincoppertubingshallbebrazedorhaveanequallystrongmetalunion.Themeltingpointofbrazingmaterialsshallbenolowerthan525°C.Thejointsshallnotdecreasethestrengthoftubingasmayhappenwhencuttingthreads.6.7.3.5.12.TheburstpressureofallpipingandpipefittingsshallbenotlessthanthehighestoffourtimestheMAWPoftheshellorfourtimesthepressuretowhichitmaybesubjectedinservicebytheactionofapumporotherdevice(exceptpressure-reliefdevices).6.7.3.5.13.Ductilemetalsshallbeusedintheconstructionofvalvesandaccessories.6.7.3.6.Bottomopenings6.7.3.6.1.Certainnon-refrigeratedliquefiedgasesshallnotbecarriedinportabletankswithbottomopeningswhenportabletankinstructionT50in4.2.4.2.6indicatesthatbottomopeningsarenotallowed.Thereshallbenoopeningsbelowtheliquidleveloftheshellwhenitisfilledtoitsmaximumpermissiblefillinglimit.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8416.7.3.7.Pressure-reliefdevices6.7.3.7.1.Portabletanksshallbeprovidedwithoneormorespring-loadedpressure-reliefdevices.Thepressure-reliefdevicesshallopenautomaticallyatapressurenotlessthantheMAWPandbefullyopenatapressureequalto110%oftheMAWP.Thesedevicesshall,afterdischarge,closeatapressurenotlowerthan10%belowthepressureatwhichdischargestartsandshallremainclosedatalllowerpressures.Thepressure-reliefdevicesshallbeofatypethatwillresistdynamicforcesincludingliquidsurge.Frangiblediscsnotinserieswithaspring-loadedpressure-reliefdevicearenotpermitted.6.7.3.7.2.Pressure-reliefdevicesshallbedesignedtopreventtheentryofforeignmatter,theleakageofgasandthedevelopmentofanydangerousexcesspressure.6.7.3.7.3.Portabletanksintendedforthecarriageofcertainnon-refrigeratedliquefiedgasesidentifiedinportabletankinstructionT50in4.2.4.2.6shallhaveapressure-reliefdeviceapprovedbythecompetentauthority.Unlessaportabletankindedicatedserviceisfittedwithanapprovedreliefdeviceconstructedofmaterialscompatiblewiththeload,suchdeviceshallcompriseafrangiblediscprecedingaspring-loadeddevice.Thespacebetweenthefrangiblediscandthedeviceshallbeprovidedwithapressuregaugeorasuitabletell-taleindicator.Thisarrangementpermitsthedetectionofdiscrupture,pinholingorleakagewhichcouldcauseamalfunctionofthepressure-reliefdevice.Thefrangiblediscsshallruptureatanominalpressure10%abovethestart-to-dischargepressureofthereliefdevice.6.7.3.7.4.Inthecaseofmultipurposeportabletanks,thepressure-reliefdevicesshallopenatapressureindicatedin6.7.3.7.1forthegashavingthehighestmaximumallowablepressureofthegasesallowedtobecarriedintheportabletank.6.7.3.8.Capacityofreliefdevices6.7.3.8.1.Thecombineddeliverycapacityofthereliefdevicesshallbesufficientthat,intheeventoftotalfireengulfment,thepressure(includingaccumulation)insidetheshelldoesnotexceed120%oftheMAWP.Spring-loadedreliefdevicesshallbeusedtoachievethefullreliefcapacityprescribed.Inthecaseofmultipurposetanks,thecombineddeliverycapacityofthepressure-reliefdevicesshallbetakenforthegaswhichrequiresthehighestdeliverycapacityofthegasesallowedtobecarriedinportabletanks.6.7.3.8.1.1.Todeterminethetotalrequiredcapacityofthereliefdevices,whichshallberegardedasbeingthesumoftheindividualcapacitiesoftheseveraldevices,thefollowingformulae(1)shallbeused:where:Q=minimumrequiredrateofdischargeincubicmetresofairpersecond(m3/s)atstandardconditions:1barand0°C(273K);F=isacoefficientwiththefollowingvalue:foruninsulatedshells:F=1;forinsulatedshells:F¼U649(cid:1)tðÞ13;6butinnocaseislessthan0,25where:U=thermalconductanceoftheinsulation,inKw.m–2.K–1,at38°C;t=actualtemperatureofthenon-refrigeratedliquefiedgasduringfilling(°C);whenthistemperatureisunknown,lett=15°C;ThevalueofFgivenaboveforinsulatedshellsmaybetakenprovidedthattheinsulationisinaccordancewith6.7.3.8.1.2;A=totalexternalsurfaceareaofshellinsquaremetres;Z=thegascompressibilityfactorintheaccumulatingcondition(whenthisfactorisunknown,letZ=1,0);T=absolutetemperatureinKelvin(°C+273)abovethepressure-reliefdevicesintheaccumulatingcondition;L=thelatentheatofvaporisationoftheliquid,inkJ/kg,intheaccumulatingcondition;M=molecularmassofthedischargedgas;OfficialJournaloftheEuropeanUnionEN26.1.2004L18/842(1)Thisformulaappliesonlytonon-refrigeratedliquefiedgaseswhichhavecriticaltemperatureswellabovethetemperatureattheaccumulatingcondition.Forgaseswhichhavecriticaltemperaturesnearorbelowthetemperatureattheaccumulatingcondition,thecalculationofthepressure-reliefdevicedeliverycapacityshallconsiderfurtherthermodynamicpropertiesofthegas(seeforexampleCGAS-1.2-1995).C=aconstantwhichisderivedfromoneofthefollowingformulaeasafunctionoftheratiokofspecificheatsk¼cpcvwherecpisthespecificheatatconstantpressure;andcvisthespecificheatatconstantvolume.whenk>1:whenk=1orKisunknown:whereeisthemathematicalconstant2,7183Cmayalsobetakenfromthefollowingtable:kCkCkC1,000,6071,260,6601,520,7041,020,6111,280,6641,540,7071,040,6151,300,6671,560,7101,060,6201,320,6711,580,7131,080,6241,340,6741,600,7161,100,6281,360,6781,620,7191,120,6331,380,6811,640,7221,140,6371,400,6851,660,7251,160,6411,420,6881,680,7281,180,6451,440,6911,700,7311,200,6491,460,6952,000,7701,220,6521,480,6982,200,7931,240,6561,500,7016.7.3.8.1.2.Insulationsystems,usedforthepurposeofreducingtheventingcapacity,shallbeapprovedbythecompetentauthorityoritsauthorisedbody.Inallcases,insulationsystemsapprovedforthispurposeshall:(a)remaineffectiveatalltemperaturesupto649°C;and(b)bejacketedwithamaterialhavingameltingpointof700°Corgreater.6.7.3.9.Markingofpressure-reliefdevices6.7.3.9.1.Everypressure-reliefdeviceshallbeplainlyandpermanentlymarkedwiththefollowingparticulars:(a)thepressure(inbarorkPa)atwhichitissettodischarge;(b)theallowabletoleranceatthedischargepressureforspring-loadeddevices;(c)thereferencetemperaturecorrespondingtotheratedpressureforfrangiblediscs;and(d)theratedflowcapacityofthedeviceinstandardcubicmetresofairpersecond(m3/s).Whenpracticable,thefollowinginformationshallalsobeshown:(e)themanufacturer'snameandrelevantcataloguenumberofthedevice.6.7.3.9.2.Theratedflowcapacitymarkedonthepressure-reliefdevicesshallbedeterminedaccordingtoISO4126-1:1991.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8436.7.3.10.Connectionstopressure-reliefdevices6.7.3.10.1.Connectionstopressure-reliefdevicesshallbeofsufficientsizetoenabletherequireddischargetopassunrestrictedtothesafetydevice.Nostop-valveshallbeinstalledbetweentheshellandthepressure-reliefdevicesexceptwhenduplicatedevicesareprovidedformaintenanceorotherreasonsandthestop-valvesservingthedevicesactuallyinusearelockedopenorthestop-valvesareinterlockedsothatatleastoneoftheduplicatedevicesisalwaysoperableandcapableofmeetingtherequirementsof6.7.3.8.Thereshallbenoobstructioninanopeningleadingtoaventorpressure-reliefdevicewhichmightrestrictorcut-offtheflowfromtheshelltothatdevice.Ventsfromthepressure-reliefdevices,whenused,shalldelivertherelievedvapourorliquidtotheatmosphereinconditionsofminimumback-pressureontherelievingdevice.6.7.3.11.Sitingofpressure-reliefdevices6.7.3.11.1.Eachpressure-reliefdeviceinletshallbesituatedontopoftheshellinapositionasnearthelongitudinalandtransversecentreoftheshellasreasonablypracticable.Allpressurereliefdeviceinletsshallundermaximumfillingconditionsbesituatedinthevapourspaceoftheshellandthedevicesshallbesoarrangedastoensurethattheescapingvapourisdischargedunrestrictedly.Forflammablenon-refrigeratedliquefiedgases,theescapingvapourshallbedirectedawayfromtheshellinsuchamannerthatitcannotimpingeupontheshell.Protectivedeviceswhichdeflecttheflowofvapourarepermissibleprovidedtherequiredrelief-devicecapacityisnotreduced.6.7.3.11.2.Arrangementsshallbemadetopreventaccesstothepressure-reliefdevicesbyunauthorisedpersonsandtoprotectthedevicesfromdamagecausedbytheportabletankoverturning.6.7.3.12.Gaugingdevices6.7.3.12.1.Unlessaportabletankisintendedtobefilledbyweightitshallbeequippedwithoneormoregaugingdevices.Glasslevel-gaugesandgaugesmadeofotherfragilematerial,whichareindirectcommunicationwiththecontentsoftheshellshallnotbeused.6.7.3.13.Portabletanksupports,frameworks,liftingandtie-downattachments6.7.3.13.1.Portabletanksshallbedesignedandconstructedwithasupportstructuretoprovideasecurebaseduringcarriage.Theforcesspecifiedin6.7.3.2.9andthesafetyfactorspecifiedin6.7.3.2.10shallbeconsideredinthisaspectofthedesign.Skids,frameworks,cradlesorothersimilarstructuresareacceptable.6.7.3.13.2.Thecombinedstressescausedbyportabletankmountings(e.g.cradles,frameworks,etc.)andportabletankliftingandtie-downattachmentsshallnotcauseexcessivestressinanyportionoftheshell.Permanentliftingandtie-downattachmentsshallbefittedtoallportabletanks.Preferablytheyshallbefittedtotheportabletanksupportsbutmaybesecuredtoreinforcingplateslocatedontheshellatthepointsofsupport.6.7.3.13.3.Inthedesignofsupportsandframeworkstheeffectsofenvironmentalcorrosionshallbetakenintoaccount.6.7.3.13.4.Forkliftpocketsshallbecapableofbeingclosedoff.Themeansofclosingforkliftpocketsshallbeapermanentpartoftheframeworkorpermanentlyattachedtotheframework.Singlecompartmentportabletankswithalengthlessthan3,65mneednothaveclosedoffforkliftpocketsprovidedthat:(a)theshellandallthefittingsarewellprotectedfrombeinghitbytheforkliftblades;and(b)thedistancebetweenthecentresoftheforkliftpocketsisatleasthalfofthemaximumlengthoftheportabletank.6.7.3.13.5.Whenportabletanksarenotprotectedduringcarriage,accordingto4.2.2.3,theshellsandserviceequipmentshallbeprotectedagainstdamagetotheshellandserviceequipmentresultingfromlateralorlongitudinalimpactoroverturning.Externalfittingsshallbeprotectedsoastoprecludethereleaseoftheshellcontentsuponimpactoroverturningoftheportabletankonitsfittings.Examplesofprotectioninclude:(a)protectionagainstlateralimpactwhichmayconsistoflongitudinalbarsprotectingtheshellonbothsidesatthelevelofthemedianline;(b)protectionoftheportabletankagainstoverturningwhichmayconsistofreinforcementringsorbarsfixedacrosstheframe;(c)protectionagainstrearimpactwhichmayconsistofabumperorframe;(d)protectionoftheshellagainstdamagefromimpactoroverturningbyuseofanISOframeinaccordancewithISO1496-3:1995.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8446.7.3.14.Designapproval6.7.3.14.1.Thecompetentauthorityoritsauthorisedbodyshallissueadesignapprovalcertificateforanynewdesignofaportabletank.Thiscertificateshallattestthataportabletankhasbeensurveyedbythatauthority,issuitableforitsintendedpurposeandmeetstherequirementsofthischapterandwhereappropriatetheprovisionsforgasesprovidedinportabletankinstructionT50in4.2.4.2.6.Whenaseriesofportabletanksaremanufacturedwithoutchangeinthedesign,thecertificateshallbevalidfortheentireseries.Thecertificateshallrefertotheprototypetestreport,thegasesallowedtobecarried,thematerialsofconstructionoftheshellandanapprovalnumber.TheapprovalnumbershallconsistofthedistinguishingsignormarkoftheStateinwhoseterritorytheapprovalwasgranted,i.e.thedistinguishingsignforuseininternationaltraffic,asprescribedbytheConventiononRoadTraffic,Vienna1968,andaregistrationnumber.Anyalternativearrangementsaccordingto6.7.1.2shallbeindicatedonthecertificate.Adesignapprovalmayservefortheapprovalofsmallerportabletanksmadeofmaterialsofthesamekindandthickness,bythesamefabricationtechniquesandwithidenticalsupports,equivalentclosuresandotherappurtenances.6.7.3.14.2.Theprototypetestreportforthedesignapprovalshallincludeatleastthefollowing:(a)theresultsoftheapplicableframeworktestspecifiedinISO1496-3:1995;(b)theresultsoftheinitialinspectionandtestin6.7.3.15.3;and(c)theresultsoftheimpacttestin6.7.3.15.1,whenapplicable.6.7.3.15.Inspectionandtesting6.7.3.15.1.ForportabletanksmeetingthedefinitionofcontainerintheCSC,aprototyperepresentingeachdesignshallbesubjectedtoanimpacttest.Theprototypeportabletankshallbeshowntobecapableofabsorbingtheforcesresultingfromanimpactnotlessthanfourtimes(4g)theMPGMofthefullyloadedportabletankatadurationtypicalofthemechanicalshocksexperiencedinrailtransport.Thefollowingisalistingofstandardsdescribingmethodsacceptableforperformingtheimpacttest:—AssociationofAmericanRailroads,ManualofStandardsandRecommendedPractices,SpecificationsforAcceptabilityofTankContainers(AAR.600),1992—CanadianStandardsAssociation(CSA),HighwayTanksandPortableTanksfortheTransportationofDangerousGoods(B620-1987)—DeutscheBahnAGZentralbereichTechnik,MindenPortabletanks,longitudinaldynamicimpacttest—SociéténationaledescheminsdeferfrançaisC.N.E.S.T.002-1966Tankcontainers,longitudinalexternalstressesanddynamicimpacttests—Spoornet,SouthAfricaEngineeringDevelopmentCentre(EDC)TestingofISOTankContainersMethodEDC/TES/023/000/1991-066.7.3.15.2.Theshellanditemsofequipmentofeachportabletankshallbeinspectedandtestedbeforebeingputintoserviceforthefirsttime(initialinspectionandtest)andthereafteratnotmorethanfive-yearintervals(five-yearperiodicinspectionandtest)withanintermediateperiodicinspectionandtest(2,5-yearperiodicinspectionandtest)midwaybetweenthefive-yearperiodicinspectionsandtests.The2,5-yearinspectionandtestmaybeperformedwithinthreemonthsofthespecifieddate.Anexceptionalinspectionandtestshallbeperformedregardlessofthelastperiodicinspectionandtestwhennecessaryaccordingto6.7.3.15.7.6.7.3.15.3.Theinitialinspectionandtestofaportabletankshallincludeacheckofthedesigncharacteristics,aninternalandexternalexaminationoftheportabletankanditsfittingswithdueregardtothenon-refrigeratedliquefiedgasestobecarried,andapressuretestreferringtothetestpressuresaccordingto6.7.3.3.2.Thepressuretestmaybeperformedasahydraulictestorbyusinganotherliquidorgaswiththeagreementofthecompetentauthorityoritsauthorisedbody.Beforetheportabletankisplacedintoservice,aleakproofnesstestandatestofthesatisfactoryoperationofallserviceequipmentshallalsobeperformed.Whentheshellanditsfittingshavebeenpressure-testedseparately,theyshallbesubjectedtogetherafterassemblytoaleakproofnesstest.Allweldssubjecttofullstresslevelintheshellshallbeinspectedduringtheinitialtestbyradiographic,ultrasonic,oranothersuitablenon-destructivetestmethod.Thisdoesnotapplytothejacket.6.7.3.15.4.Thefive-yearperiodicinspectionandtestshallincludeaninternalandexternalexaminationand,asageneralrule,ahydraulicpressuretest.Sheathing,thermalinsulationandthelikeshallberemovedonlytotheextentrequiredforreliableappraisaloftheconditionoftheportabletank.Whentheshellandequipmenthavebeenpressure-testedseparately,theyshallbesubjectedtogetherafterassemblytoaleakproofnesstest.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8456.7.3.15.5.Theintermediate2,5-yearperiodicinspectionandtestshallatleastincludeaninternalandexternalexaminationoftheportabletankanditsfittingswithdueregardtothenon-refrigeratedliquefiedgasesintendedtobecarried,aleakproofnesstestandacheckofthesatisfactoryoperationofallserviceequipment.Sheathingthermalinsulationandthelikeshallberemovedonlytotheextentrequiredforreliableappraisaloftheconditionoftheportabletank.Forportabletanksintendedforthecarriageofasinglenon-refrigeratedliquefiedgas,the2,5-yearinternalexaminationmaybewaivedorsubstitutedbyothertestmethodsorinspectionproceduresspecifiedbythecompetentauthorityoritsauthorisedbody.6.7.3.15.6.Aportabletankmaynotbefilledandofferedforcarriageafterthedateofexpiryofthelastfive-yearor2,5-yearperiodicinspectionandtestasrequiredby6.7.3.15.2.Howeveraportabletankfilledpriortothedateofexpiryofthelastperiodicinspectionandtestmaybecarriedforaperiodnottoexceedthreemonthsbeyondthedateofexpiryofthelastperiodictestorinspection.Inaddition,aportabletankmaybecarriedafterthedateofexpiryofthelastperiodictestandinspection:(a)afteremptyingbutbeforecleaning,forpurposesofperformingthenextrequiredtestorinspectionpriortorefilling;and(b)unlessotherwiseapprovedbythecompetentauthority,foraperiodnottoexceedsixmonthsbeyondthedateofexpiryofthelastperiodictestorinspection,inordertoallowthereturnofdangerousgoodsforproperdisposalorrecycling.Referencetothisexemptionshallbementionedinthetransportdocument.6.7.3.15.7.Theexceptionalinspectionandtestisnecessarywhentheportabletankshowsevidenceofdamagedorcorrodedareas,orleakage,orotherconditionsthatindicateadeficiencythatcouldaffecttheintegrityoftheportabletank.Theextentoftheexceptionalinspectionandtestshalldependontheamountofdamageordeteriorationoftheportabletank.Itshallincludeatleastthe2,5-yearinspectionandtestaccordingto6.7.3.15.5.6.7.3.15.8.theinternalandexternalexaminationsshallensurethat:(a)theshellisinspectedforpitting,corrosion,orabrasions,dents,distortions,defectsinweldsoranyotherconditions,includingleakage,thatmightrendertheportabletankunsafeforcarriage;(b)thepiping,valves,andgasketsareinspectedforcorrodedareas,defects,oranyotherconditions,includingleakage,thatmightrendertheportabletankunsafeforfilling,dischargeorcarriage;(c)devicesfortighteningmanholecoversareoperativeandthereisnoleakageatmanholecoversorgaskets;(d)missingorlooseboltsornutsonanyflangedconnectionorblankflangearereplacedortightened;(e)allemergencydevicesandvalvesarefreefromcorrosion,distortionandanydamageordefectthatcouldpreventtheirnormaloperation.Remoteclosuredevicesandself-closingstop-valvesshallbeoperatedtodemonstrateproperoperation;(f)requiredmarkingsontheportabletankarelegibleandinaccordancewiththeapplicablerequirements;and(g)theframework,thesupportsandthearrangementsforliftingtheportabletankareinsatisfactorycondition.6.7.3.15.9.Theinspectionsandtestsin6.7.3.15.1,6.7.3.15.3,6.7.3.15.4,6.7.3.15.5and6.7.3.15.7shallbeperformedorwitnessedbyanexpertapprovedbythecompetentauthorityoritsauthorisedbody.Whenthepressuretestisapartoftheinspectionandtest,thetestpressureshallbetheoneindicatedonthedataplateoftheportabletank.Whileunderpressure,theportabletankshallbeinspectedforanyleaksintheshell,pipingorequipment.6.7.3.15.10.Inallcaseswhencutting,burningorweldingoperationsontheshellhavebeeneffected,thatworkshallbetotheapprovalofthecompetentauthorityoritsauthorisedbodytakingintoaccountthepressurevesselcodeusedfortheconstructionoftheshell.Apressuretesttotheoriginaltestpressureshallbeperformedaftertheworkiscompleted.6.7.3.15.11.Whenevidenceofanyunsafeconditionisdiscovered,theportabletankshallnotbereturnedtoserviceuntilithasbeencorrectedandthepressuretestisrepeatedandpassed.6.7.3.16.Marking6.7.3.16.1.Everyportabletankshallbefittedwithacorrosionresistantmetalplatepermanentlyattachedtotheportabletankinaconspicuousplacereadilyaccessibleforinspection.Whenforreasonsofportabletankarrangements,theplatecannotbepermanentlyattachedtotheshell,theshellshallbemarkedwithatleasttheinformationrequiredbythepressurevesselcode.Asaminimumatleastthefollowinginformationshallbemarkedontheplatebystampingorbyanyothersimilarmethod:OfficialJournaloftheEuropeanUnionEN26.1.2004L18/846CountryofmanufactureApprovalCountryApprovalNumberForalternativearrangements(see6.7.1.2)‘AA’Manufacturer'snameormarkManufacturer'sserialnumberAuthorisedbodyforthedesignapprovalOwner'sregistrationnumberYearofmanufacturePressurevesselcodetowhichtheshellisdesignedTestpressure…bar/kPa(gaugepressure)(1)MAWP…bar/kPa(gaugepressure)(1)Externaldesignpressure(2)…bar/kPa(gaugepressure)(1)Designtemperaturerange…°Cto…°CDesignreferencetemperature…°CWatercapacityat20°C…litresInitialpressuretestdateandwitnessidentificationShellmaterial(s)andmaterialstandardreference(s)Equivalentthicknessinreferencesteel…mmDateandtypeofmostrecentperiodictest(s)Month…Year…Testpressure…bar/kPa(gaugepressure)(1)Stampofexpertwhoperformedorwitnessedthemostrecenttest6.7.3.16.2.Thefollowinginformationshallbemarkedeitherontheportabletankitselforonametalplatefirmlysecuredtotheportabletank:NameoftheoperatorNameofnon-refrigeratedliquefiedgas(es)permittedforcarriageMaximumpermissibleloadmassforeachnon-refrigeratedliquefiedgaspermitted…kgMaximumpermissiblegrossmass(MPGM)…kgUnladen(tare)mass…kgNOTEFortheidentificationofthenon-refrigeratedliquefiedgasesbeingcarried,seealsoPart5.6.7.3.16.3.Ifaportabletankisdesignedandapprovedforhandlinginopenseas,thewords‘OFFSHOREPORTABLETANK’shallbemarkedontheidentificationplate.6.7.4.Requirementsforthedesign,construction,inspectionandtestingofportabletanksintendedforthecarriageofrefrigeratedliquefiedgases6.7.4.1.DefinitionsForthepurposesofthissection:Portabletankmeansathermallyinsulatedmultimodaltankhavingacapacityofmorethan450litresfittedwithserviceequipmentandstructuralequipmentnecessaryforthecarriageofrefrigeratedliquefiedgases.Theportabletankshallbecapableofbeingfilledanddischargedwithouttheremovalofitsstructuralequipment.Itshallpossessstabilisingmembersexternaltothetank,andshallbecapableofbeingliftedwhenfull.Itshallbedesignedprimarilytobeloadedontoatransportvehicleorshipandshallbeequippedwithskids,mountingsoraccessoriestofacilitatemechanicalhandling.Tank-vehicles,tank-wagons,non-metallictanks,intermediatebulkcontainers(IBCs),gascylindersandlargereceptaclesarenotconsideredtofallwithinthedefinitionforportabletanks;OfficialJournaloftheEuropeanUnionEN26.1.2004L18/847(1)Theunitusedshallbemarked.(2)See6.7.2.2.10.Tankmeansaconstructionwhichnormallyconsistsofeither:(a)ajacketandoneormoreinnershellswherethespacebetweentheshell(s)andthejacketisexhaustedofair(vacuuminsulation)andmayincorporateathermalinsulationsystem;or(b)ajacketandaninnershellwithanintermediatelayerofsolidthermallyinsulatingmaterial(e.g.solidfoam);Shellmeansthepartoftheportabletankwhichretainstherefrigeratedliquefiedgasintendedforcarriage,includingopeningsandtheirclosures,butdoesnotincludeserviceequipmentorexternalstructuralequipment;Jacketmeanstheouterinsulationcoverorcladdingwhichmaybepartoftheinsulationsystem;Serviceequipmentmeansmeasuringinstrumentsandfilling,discharge,venting,safety,pressurising,coolingandthermalinsulationdevices;Structuralequipmentmeansthereinforcing,fastening,protectiveandstabilisingmembersexternaltotheshell;Maximumallowableworkingpressure(MAWP)meansthemaximumeffectivegaugepressurepermissibleatthetopoftheshellofaloadedportabletankinitsoperatingpositionincludingthehighesteffectivepressureduringfillinganddischarge;Testpressuremeansthemaximumgaugepressureatthetopoftheshellduringthepressuretest;Leakproofnesstestmeansatestusinggassubjectingtheshellanditsserviceequipment,toaneffectiveinternalpressurenotlessthan90%oftheMAWP;Maximumpermissiblegrossmass(MPGM)meansthesumofthetaremassoftheportabletankandtheheaviestloadauthorisedforcarriage;Holdingtimemeansthetimethatwillelapsefromtheestablishmentoftheinitialfillingconditionuntilthepressurehasrisenduetoheatinfluxtothelowestsetpressureofthepressurelimitingdevice(s);Referencesteelmeansasteelwithatensilestrengthof370N/mm2andanelongationatfractureof27%;Minimumdesigntemperaturemeansthetemperaturewhichisusedforthedesignandconstructionoftheshellnothigherthanthelowest(coldest)temperature(servicetemperature)ofthecontentsduringnormalconditionsoffilling,dischargeandcarriage.6.7.4.2.Generaldesignandconstructionrequirements6.7.4.2.1.Shellsshallbedesignedandconstructedinaccordancewiththerequirementsofapressurevesselcoderecognisedbythecompetentauthority.Shellsandjacketsshallbemadeofmetallicmaterialssuitableforforming.Jacketsshallbemadeofsteel.Non-metallicmaterialsmaybeusedfortheattachmentsandsupportsbetweentheshellandjacket,providedtheirmaterialpropertiesattheminimumdesigntemperatureareproventobesufficient.Thematerialsshallinprincipleconformtonationalorinternationalmaterialstandards.Forweldedshellsandjacketsonlymaterialswhoseweldabilityhasbeenfullydemonstratedshallbeused.Weldsshallbeskilfullymadeandaffordcompletesafety.Whenthemanufacturingprocessorthematerialsmakeitnecessary,theshellshallbesuitablyheattreatedtoguaranteeadequatetoughnessintheweldandintheheataffectedzones.Inchoosingthematerial,theminimumdesigntemperatureshallbetakenintoaccountwithrespecttoriskofbrittlefracture,tohydrogenembrittlement,tostresscorrosioncrackingandtoresistancetoimpact.Whenfinegrainsteelisused,theguaranteedvalueoftheyieldstrengthshallbenotmorethan460N/mm2andtheguaranteedvalueoftheupperlimitofthetensilestrengthshallbenotmorethan725N/mm2inaccordancewiththematerialspecifications.Portabletankmaterialsshallbesuitablefortheexternalenvironmentinwhichtheymaybecarried.6.7.4.2.2.Anypartofaportabletank,includingfittings,gasketsandpipe-work,whichcanbeexpectednormallytocomeintocontactwiththerefrigeratedliquefiedgascarriedshallbecompatiblewiththatrefrigeratedliquefiedgas.6.7.4.2.3.Contactbetweendissimilarmetalswhichcouldresultindamagebygalvanicactionshallbeavoided.6.7.4.2.4.Thethermalinsulationsystemshallincludeacompletecoveringoftheshell(s)witheffectiveinsulatingmaterials.Externalinsulationshallbeprotectedbyajacketsoastopreventtheingressofmoistureandotherdamageundernormalcarriageconditions.6.7.4.2.5.Whenajacketissoclosedastobegas-tight,adeviceshallbeprovidedtopreventanydangerouspressurefromdevelopingintheinsulationspace.6.7.4.2.6.Portabletanksintendedforthecarriageofrefrigeratedliquefiedgaseshavingaboilingpointbelowminus(–)182°Catatmosphericpressureshallnotincludematerialswhichmayreactwithoxygenoroxygenenrichedatmospheresinadangerousmanner,whenlocatedinpartsofthethermalinsulationwhenthereisariskofcontactwithoxygenorwithoxygenenrichedfluid.6.7.4.2.7.Insulatingmaterialsshallnotdeteriorateundulyinservice.6.7.4.2.8.Areferenceholdingtimeshallbedeterminedforeachrefrigeratedliquefiedgasintendedforcarriageinaportabletank.6.7.4.2.8.1.Thereferenceholdingtimeshallbedeterminedbyamethodrecognisedbythecompetentauthorityonthebasisofthefollowing:(a)theeffectivenessoftheinsulationsystem,determinedinaccordancewith6.7.4.2.8.2;OfficialJournaloftheEuropeanUnionEN26.1.2004L18/848(b)thelowestsetpressureofthepressurelimitingdevice(s);(c)theinitialfillingconditions;(d)anassumedambienttemperatureof30°C;(e)thephysicalpropertiesoftheindividualrefrigeratedliquefiedgasintendedtobecarried.6.7.4.2.8.2.Theeffectivenessoftheinsulationsystem(heatinfluxinwatts)shallbedeterminedbytypetestingtheportabletankinaccordancewithaprocedurerecognisedbythecompetentauthority.Thistestshallconsistofeither:(a)aconstantpressuretest(forexampleatatmosphericpressure)whenthelossofrefrigeratedliquefiedgasismeasuredoveraperiodoftime;or(b)aclosedsystemtestwhentheriseinpressureintheshellismeasuredoveraperiodoftime.Whenperformingtheconstantpressuretest,variationsinatmosphericpressureshallbetakenintoaccount.Whenperformingeithertestscorrectionsshallbemadeforanyvariationoftheambienttemperaturefromtheassumedambienttemperaturereferencevalueof30°C.NOTEForthedeterminationoftheactualholdingtimebeforeeachjourney,referto4.2.3.7.6.7.4.2.9.Thejacketofavacuum-insulateddouble-walltankshallhaveeitheranexternaldesignpressurenotlessthan100kPa(1bar)(gaugepressure)calculatedinaccordancewitharecognisedtechnicalcodeoracalculatedcriticalcollapsingpressureofnotlessthan200kPa(2bar)(gaugepressure).Internalandexternalreinforcementsmaybeincludedincalculatingtheabilityofthejackettoresisttheexternalpressure.6.7.4.2.10.Portabletanksshallbedesignedandconstructedwithsupportstoprovideasecurebaseduringcarriageandwithsuitableliftingandtie-downattachments.6.7.4.2.11.Portabletanksshallbedesignedtowithstand,withoutlossofcontents,atleasttheinternalpressureduetothecontents,andthestatic,dynamicandthermalloadsduringnormalconditionsofhandlingandcarriage.Thedesignshalldemonstratethattheeffectsoffatigue,causedbyrepeatedapplicationoftheseloadsthroughtheexpectedlifeoftheportabletank,havebeentakenintoaccount.6.7.4.2.12.Portabletanksandtheirfasteningsunderthemaximumpermissibleloadshallbecapableofabsorbingthefollowingseparatelyappliedstaticforces:(a)inthedirectionoftravel:twicetheMPGMmultipliedbytheaccelerationduetogravity(g)(1);(b)horizontallyatrightanglestothedirectionoftravel:theMPGM(whenthedirectionoftravelisnotclearlydetermined,theforcesshallbeequaltotwicetheMPGM)multipliedbytheaccelerationduetogravity(g)(1);(c)verticallyupwards:theMPGMmultipliedbytheaccelerationduetogravity(g)(1);and(d)verticallydownwards:twicetheMPGM(totalloadingincludingtheeffectofgravity)multipliedbytheaccelerationduetogravity(g)(2).6.7.4.2.13.Undereachoftheforcesin6.7.4.2.12,thesafetyfactortobeobservedshallbeasfollows:(a)formaterialshavingaclearlydefinedyieldpoint,asafetyfactorof1,5inrelationtotheguaranteedyieldstrength;and(b)formaterialswithnoclearlydefinedyieldpoint,asafetyfactorof1,5inrelationtotheguaranteed0,2%proofstrengthor,incaseofausteniticsteels,the1%proofstrength.6.7.4.2.14.Thevaluesofyieldstrengthorproofstrengthshallbethevaluesaccordingtonationalorinternationalmaterialstandards.Whenausteniticsteelsareused,thespecifiedminimumvaluesaccordingtothematerialstandardsmaybeincreasedbyupto15%whengreatervaluesareattestedinthematerialinspectioncertificate.Whennomaterialstandardexistsforthemetalinquestion,orwhennon-metallicmaterialsareusedthevaluesofyieldstrengthorproofstrengthshallbeapprovedbythecompetentauthority.6.7.4.2.15.Portabletanksintendedforthecarriageofflammablerefrigeratedliquefiedgasesshallbecapableofbeingelectricallyearthed.6.7.4.3.Designcriteria6.7.4.3.1.Shellsshallbeofacircularcrosssection.6.7.4.3.2.Shellsshallbedesignedandconstructedtowithstandatestpressurenotlessthan1,3timestheMAWP.Forshellswithvacuuminsulationthetestpressureshallnotbelessthan1,3timesthesumoftheMAWPand100kPa(1bar).Innocaseshallthetestpressurebelessthan300kPa(3bar)(gaugepressure).Attentionisdrawntotheminimumshellthicknessrequirements,specifiedin6.7.4.4.2to6.7.4.4.7.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/849(1)Forcalculationpurposesg=9,81m/s2.6.7.4.3.3.Formetalsexhibitingaclearlydefinedyieldpointorcharacterizedbyaguaranteedproofstrength(0,2%proofstrength,generally,or1%proofstrengthforausteniticsteels)theprimarymembranestressσ(sigma)intheshellshallnotexceed0,75Reor0,50Rm,whicheverislower,atthetestpressure,where:Re=yieldstrengthinN/mm2,or0,2%proofstrengthor,forausteniticsteels,1%proofstrength;Rm=minimumtensilestrengthinN/mm2.6.7.4.3.3.1.ThevaluesofReandRmtobeusedshallbethespecifiedminimumvaluesaccordingtonationalorinternationalmaterialstandards.Whenausteniticsteelsareused,thespecifiedminimumvaluesforReandRmaccordingtothematerialstandardsmaybeincreasedbyupto15%whengreatervaluesareattestedinthematerialinspectioncertificate.Whennomaterialstandardexistsforthemetalinquestion,thevaluesofReandRmusedshallbeapprovedbythecompetentauthorityoritsauthorisedbody.6.7.4.3.3.2.SteelswhichhaveaRe/Rmratioofmorethan0,85arenotallowedfortheconstructionofweldedshells.ThevaluesofReandRmtobeusedindeterminingthisratioshallbethevaluesspecifiedinthematerialinspectioncertificate.6.7.4.3.3.3.Steelsusedintheconstructionofshellsshallhaveanelongationatfracture,in%,ofnotlessthan10000/Rmwithanabsoluteminimumof16%forfinegrainsteelsand20%forothersteels.Aluminiumandaluminiumalloysusedintheconstructionofshellsshallhaveanelongationatfracture,in%,ofnotlessthan10000/6Rmwithanabsoluteminimumof12%.6.7.4.3.3.4.Forthepurposeofdeterminingactualvaluesformaterials,itshallbenotedthatforsheetmetal,theaxisofthetensiletestspecimenshallbeatrightangles(transversely)tothedirectionofrolling.ThepermanentelongationatfractureshallbemeasuredontestspecimensofrectangularcrosssectionsinaccordancewithISO6892:1988usinga50mmgaugelength.6.7.4.4.Minimumshellthickness6.7.4.4.1.Theminimumshellthicknessshallbethegreaterthicknessbasedon:(a)theminimumthicknessdeterminedinaccordancewiththerequirementsin6.7.4.4.2to6.7.4.4.7;or(b)theminimumthicknessdeterminedinaccordancewiththerecognisedpressurevesselcodeincludingtherequirementsin6.7.4.3.6.7.4.4.2.Shellsofnotmorethan1,80mindiametershallbenotlessthan5mmthickinthereferencesteelorofequivalentthicknessinthemetaltobeused.Shellsofmorethan1,80mindiametershallbenotlessthan6mmthickinthereferencesteelorofequivalentthicknessinthemetaltobeused.6.7.4.4.3.Shellsofvacuum-insulatedtanksofnotmorethan1,80mindiametershallbenotlessthan3mmthickinthereferencesteelorofequivalentthicknessinthemetaltobeused.Suchshellsofmorethan1,80mindiametershallbenotlessthan4mmthickinthereferencesteelorofequivalentthicknessinthemetaltobeused.6.7.4.4.4.Forvacuum-insulatedtanks,theaggregatethicknessofthejacketandtheshellshallcorrespondtotheminimumthicknessprescribedin6.7.4.4.2,thethicknessoftheshellitselfbeingnotlessthantheminimumthicknessprescribedin6.7.4.4.3.6.7.4.4.5.Shellsshallbenotlessthan3mmthickregardlessofthematerialofconstruction.6.7.4.4.6.Theequivalentthicknessofametalotherthanthethicknessprescribedforthereferencesteelin6.7.4.4.2and6.7.4.4.3shallbedeterminedusingthefollowingformula:where:e1=requiredequivalentthickness(inmm)ofthemetaltobeused;e0=minimumthickness(inmm)ofthereferencesteelspecifiedin6.7.4.4.2and6.7.4.4.3;Rm1=guaranteedminimumtensilestrength(inN/mm2)ofthemetaltobeused(see6.7.4.3.3);A1=guaranteedminimumelongationatfracture(in%)ofthemetaltobeusedaccordingtonationalorinternationalstandards.6.7.4.4.7.Innocaseshallthewallthicknessbelessthanthatprescribedin6.7.4.4.1to6.7.4.4.5.Allpartsoftheshellshallhaveaminimumthicknessasdeterminedby6.7.4.4.1to6.7.4.4.6.Thisthicknessshallbeexclusiveofanycorrosionallowance.6.7.4.4.8.Thereshallbenosuddenchangeofplatethicknessattheattachmentoftheends(heads)tothecylindricalportionoftheshell.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8506.7.4.5.Serviceequipment6.7.4.5.1.Serviceequipmentshallbesoarrangedastobeprotectedagainsttheriskofbeingwrenchedoffordamagedduringhandlingandcarriage.Whentheconnectionbetweentheframeandthetankorthejacketandtheshellallowsrelativemovement,theequipmentshallbesofastenedastopermitsuchmovementwithoutriskofdamagetoworkingparts.Theexternaldischargefittings(pipesockets,shut-offdevices),thestop-valveanditsseatingshallbeprotectedagainstthedangerofbeingwrenchedoffbyexternalforces(forexampleusingshearsections).Thefillinganddischargedevices(includingflangesorthreadedplugs)andanyprotectivecapsshallbecapableofbeingsecuredagainstunintendedopening.6.7.4.5.2.Eachfillinganddischargeopeninginportabletanksusedforthecarriageofflammablerefrigeratedliquefiedgasesshallbefittedwithatleastthreemutuallyindependentshut-offdevicesinseries,thefirstbeingastop-valvesituatedascloseasreasonablypracticabletothejacket,thesecondbeingastop-valveandthethirdbeingablankflangeorequivalentdevice.Theshut-offdeviceclosesttothejacketshallbeaquickclosingdevice,whichclosesautomaticallyintheeventofunintendedmovementoftheportabletankduringfillingordischargeorfireengulfment.Thisdeviceshallalsobepossibletooperatebyremotecontrol.6.7.4.5.3.Eachfillinganddischargeopeninginportabletanksusedforthecarriageofnon-flammablerefrigeratedliquefiedgasesshallbefittedwithatleasttwomutuallyindependentshut-offdevicesinseries,thefirstbeingastop-valvesituatedascloseasreasonablypracticabletothejacket,thesecondablankflangeorequivalentdevice.6.7.4.5.4.Forsectionsofpipingwhichcanbeclosedatbothendsandwhereliquidproductcanbetrapped,amethodofautomaticpressurereliefshallbeprovidedtopreventexcesspressurebuild-upwithinthepiping.6.7.4.5.5.Vacuuminsulatedtanksneednothaveanopeningforinspection.6.7.4.5.6.Externalfittingsshallbegroupedtogethersofarasreasonablypracticable.6.7.4.5.7.Eachconnectiononaportabletankshallbeclearlymarkedtoindicateitsfunction.6.7.4.5.8.Eachstop-valveorothermeansofclosureshallbedesignedandconstructedtoaratedpressurenotlessthantheMAWPoftheshelltakingintoaccountthetemperatureexpectedduringcarriage.Allstop-valveswithascrewedspindleshallbeclosedbyaclockwisemotionofthehandwheel.Inthecaseofotherstop-valvestheposition(openandclosed)anddirectionofclosureshallbeclearlyindicated.Allstop-valvesshallbedesignedtopreventunintentionalopening.6.7.4.5.9.Whenpressure-buildingunitsareused,theliquidandvapourconnectionstothatunitshallbeprovidedwithavalveasclosetothejacketasreasonablypracticabletopreventthelossofcontentsincaseofdamagetothepressure-buildingunit.6.7.4.5.10.Pipingshallbedesigned,constructedandinstalledsoastoavoidtheriskofdamageduetothermalexpansionandcontraction,mechanicalshockandvibration.Allpipingshallbeofasuitablematerial.Topreventleakageduetofire,onlysteelpipingandweldedjointsshallbeusedbetweenthejacketandtheconnectiontothefirstclosureofanyoutlet.Themethodofattachingtheclosuretothisconnectionshallbetothesatisfactionofthecompetentauthorityoritsauthorisedbody.Elsewherepipejointsshallbeweldedwhennecessary.6.7.4.5.11.Jointsincoppertubingshallbebrazedorhaveanequallystrongmetalunion.Themeltingpointofbrazingmaterialsshallbenolowerthan525°C.Thejointsshallnotdecreasethestrengthofthetubingasmayhappenwhencuttingthreads.6.7.4.5.12.Thematerialsofconstructionofvalvesandaccessoriesshallhavesatisfactorypropertiesatthelowestoperatingtemperatureoftheportabletank.6.7.4.5.13.TheburstpressureofallpipingandpipefittingsshallbenotlessthanthehighestoffourtimestheMAWPoftheshellorfourtimesthepressuretowhichitmaybesubjectedinservicebytheactionofapumporotherdevice(exceptpressure-reliefdevices).6.7.4.6.Pressure-reliefdevices6.7.4.6.1.Everyshellshallbeprovidedwithnotlessthantwoindependentspring-loadedpressure-reliefdevices.Thepressure-reliefdevicesshallopenautomaticallyatapressurenotlessthantheMAWPandbefullyopenapressureequalto110%oftheMAWP.Thesedevicesshall,afterdischarge,closeatapressurenotlowerthan10%belowthepressureatwhichdischargestartsandshallremainclosedatalllowerpressures.Thepressure-reliefdevicesshallbeofthetypethatwillresistdynamicforcesincludingsurge.6.7.4.6.2.Shellsfornon-flammablerefrigeratedliquefiedgasesandhydrogenmayinadditionhavefrangiblediscsinparallelwiththespring-loadeddevicesasspecifiedin6.7.4.7.2and6.7.4.7.3.6.7.4.6.3.Pressure-reliefdevicesshallbedesignedtopreventtheentryofforeignmatter,theleakageofgasandthedevelopmentofanydangerousexcesspressure.6.7.4.6.4.Pressure-reliefdevicesshallbeapprovedbythecompetentauthorityoritsauthorisedbody.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8516.7.4.7.Capacityandsettingofpressure-reliefdevices6.7.4.7.1.Inthecaseofthelossofvacuuminavacuum-insulatedtankoroflossof20%oftheinsulationofatankinsulatedwithsolidmaterials,thecombinedcapacityofallpressure-reliefdevicesinstalledshallbesufficientsothatthepressure(includingaccumulation)insidetheshelldoesnotexceed120%oftheMAWP.6.7.4.7.2.Fornon-flammablerefrigeratedliquefiedgases(exceptoxygen)andhydrogen,thiscapacitymaybeachievedbytheuseoffrangiblediscsinparallelwiththerequiredsafety-reliefdevices.Frangiblediscsshallruptureatnominalpressureequaltothetestpressureoftheshell.6.7.4.7.3.Underthecircumstancesdescribedin6.7.4.7.1and6.7.4.7.2togetherwithcompletefireengulfmentthecombinedcapacityofallpressure-reliefdevicesinstalledshallbesufficienttolimitthepressureintheshelltothetestpressure.6.7.4.7.4.Therequiredcapacityofthereliefdevicesshallbecalculatedinaccordancewithawell-establishedtechnicalcoderecognisedbythecompetentauthority(1).6.7.4.8.Markingofpressure-reliefdevices6.7.4.8.1.Everypressure-reliefdeviceshallbeplainlyandpermanentlymarkedwiththefollowingparticulars:(a)thepressure(inbarorkPa)atwhichitissettodischarge;(b)theallowabletoleranceatthedischargepressureforspring-loadeddevices;(c)thereferencetemperaturecorrespondingtotheratedpressureforfrangiblediscs;and(d)theratedflowcapacityofthedeviceinstandardcubicmetersofairpersecond(m3/s).Whenpracticable,thefollowinginformationshallalsobeshown:(e)themanufacturer'snameandrelevantcataloguenumberofthedevice.6.7.4.8.2.Theratedflowcapacitymarkedonthepressure-reliefdevicesshallbedeterminedaccordingtoISO4126-1:1991.6.7.4.9.Connectionstopressure-reliefdevices6.7.4.9.1.Connectionstopressure-reliefdevicesshallbeofsufficientsizetoenabletherequireddischargetopassunrestrictedtothesafetydevice.Nostop-valveshallbeinstalledbetweentheshellandthepressure-reliefdevicesexceptwhenduplicatedevicesareprovidedformaintenanceorotherreasonsandthestop-valvesservingthedevicesactuallyinusearelockedopenorthestop-valvesareinterlockedsothattherequirementsof6.7.4.7arealwaysfulfilled.Thereshallbenoobstructioninanopeningleadingtoaventorpressure-reliefdevicewhichmightrestrictorcut-offtheflowfromtheshelltothatdevice.Pipeworktoventthevapourorliquidfromtheoutletofthepressure-reliefdevices,whenused,shalldelivertherelievedvapourorliquidtotheatmosphereinconditionsofminimumback-pressureontherelievingdevice.6.7.4.10.Sitingofpressure-reliefdevices6.7.4.10.1.Eachpressure-reliefdeviceinletshallbesituatedontopoftheshellinapositionasnearthelongitudinalandtransversecentreoftheshellasreasonablypracticable.Allpressure-reliefdeviceinletsshallundermaximumfillingconditionsbesituatedinthevapourspaceoftheshellandthedevicesshallbesoarrangedastoensurethattheescapingvapourisdischargedunrestrictedly.Forrefrigeratedliquefiedgases,theescapingvapourshallbedirectedawayfromthetankandinsuchamannerthatitcannotimpingeuponthetank.Protectivedeviceswhichdeflecttheflowofvapourarepermissibleprovidedtherequiredrelief-devicecapacityisnotreduced.6.7.4.10.2.Arrangementsshallbemadetopreventaccesstothedevicesbyunauthorisedpersonsandtoprotectthedevicesfromdamagecausedbytheportabletankoverturning.6.7.4.11.Gaugingdevices6.7.4.11.1.Unlessaportabletankisintendedtobefilledbyweight,itshallbeequippedwithoneormoregaugingdevices.Glasslevel-gaugesandgaugesmadeofotherfragilematerial,whichareindirectcommunicationwiththecontentsoftheshellshallnotbeused.6.7.4.11.2.Aconnectionforavacuumgaugeshallbeprovidedinthejacketofavacuum-insulatedportabletank.6.7.4.12.Portabletanksupports,frameworks,liftingandtie-downattachments6.7.4.12.1.Portabletanksshallbedesignedandconstructedwithasupportstructuretoprovideasecurebaseduringcarriage.Theforcesspecifiedin6.7.4.2.12andthesafetyfactorspecifiedin6.7.4.2.13shallbeconsideredinthisaspectofthedesign.Skids,frameworks,cradlesorothersimilarstructuresareacceptable.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/852(1)SeeforexampleCGApamphletS-1.2-1995.6.7.4.12.2.Thecombinedstressescausedbyportabletankmountings(e.g.cradles,frameworks,etc.)andportabletankliftingandtie-downattachmentsshallnotcauseexcessivestressinanyportionofthetank.Permanentliftingandtie-downattachmentsshallbefittedtoallportabletanks.Preferablytheyshallbefittedtotheportabletanksupportsbutmaybesecuredtoreinforcingplateslocatedonthetankatthepointsofsupport.6.7.4.12.3.Inthedesignofsupportsandframeworkstheeffectsofenvironmentalcorrosionshallbetakenintoaccount.6.7.4.12.4.Forkliftpocketsshallbecapableofbeingclosedoff.Themeansofclosingforkliftpocketsshallbeapermanentpartoftheframeworkorpermanentlyattachedtotheframework.Singlecompartmentportabletankswithalengthlessthan3,65mneednothaveclosedoffforkliftpocketsprovidedthat:(a)thetankandallthefittingsarewellprotectedfrombeinghitbytheforkliftblades;and(b)thedistancebetweenthecentresoftheforkliftpocketsisatleasthalfofthemaximumlengthoftheportabletank.6.7.4.12.5.Whenportabletanksarenotprotectedduringcarriage,accordingto4.2.3.3,theshellsandserviceequipmentshallbeprotectedagainstdamagetotheshellandserviceequipmentresultingfromlateralorlongitudinalimpactoroverturning.Externalfittingsshallbeprotectedsoastoprecludethereleaseoftheshellcontentsuponimpactoroverturningoftheportabletankonitsfittings.Examplesofprotectioninclude:(a)protectionagainstlateralimpactwhichmayconsistoflongitudinalbarsprotectingtheshellonbothsidesatthelevelofthemedianline;(b)protectionoftheportabletankagainstoverturningwhichmayconsistofreinforcementringsorbarsfixedacrosstheframe;(c)protectionagainstrearimpactwhichmayconsistofabumperorframe;(d)protectionoftheshellagainstdamagefromimpactoroverturningbyuseofanISOframeinaccordancewithISO1496-3:1995;(e)protectionoftheportabletankfromimpactoroverturningbyavacuuminsulationjacket.6.7.4.13.Designapproval6.7.4.13.1.Thecompetentauthorityoritsauthorisedbodyshallissueadesignapprovalcertificateforanynewdesignofaportabletank.Thiscertificateshallattestthataportabletankhasbeensurveyedbythatauthority,issuitableforitsintendedpurposeandmeetstherequirementsofthischapter.Whenaseriesofportabletanksaremanufacturedwithoutchangeinthedesign,thecertificateshallbevalidfortheentireseries.Thecertificateshallrefertotheprototypetestreport,therefrigeratedliquefiedgasesallowedtobecarried,thematerialsofconstructionoftheshellandjacketandanapprovalnumber.TheapprovalnumbershallconsistofthedistinguishingsignormarkoftheStateinwhoseterritorytheapprovalwasgranted,i.e.thedistinguishingsignforuseininternationaltraffic,asprescribedbytheConventiononRoadTraffic,Vienna1968,andaregistrationnumber.Anyalternativearrangementsaccordingto6.7.1.2shallbeindicatedonthecertificate.Adesignapprovalmayservefortheapprovalofsmallerportabletanksmadeofmaterialsofthesamekindandthickness,bythesamefabricationtechniquesandwithidenticalsupports,equivalentclosuresandotherappurtenances.6.7.4.13.2.Theprototypetestreportforthedesignapprovalshallincludeatleastthefollowing:(a)theresultsoftheapplicableframeworktestspecifiedinISO1496-3:1995;(b)theresultsoftheinitialinspectionandtestin6.7.4.14.3;and(c)theresultsoftheimpacttestin6.7.4.14.1,whenapplicable.6.7.4.14.Inspectionandtesting6.7.4.14.1.ForportabletanksmeetingthedefinitionofcontainerintheCSC,aprototyperepresentingeachdesignshallbesubjectedtoanimpacttest.Theprototypeportabletankshallbeshowntobecapableofabsorbingtheforcesresultingfromanimpactnotlessthanfourtimes(4g)theMPGMofthefullyloadedportabletankatadurationtypicalofthemechanicalshocksexperiencedinrailtransport.Thefollowingisalistingofstandardsdescribingmethodsacceptableforperformingtheimpacttest:—AssociationofAmericanRailroads,ManualofStandardsandRecommendedPractices,SpecificationsforAcceptabilityofTankContainers(AAR.600),1992—CanadianStandardsAssociation(CSA),HighwayTanksandPortableTanksfortheTransportationofDangerousGoods(B620-1987)—DeutscheBahnAGZentralbereichTechnik,MindenPortabletanks,longitudinaldynamicimpacttestOfficialJournaloftheEuropeanUnionEN26.1.2004L18/853—SociéténationaledescheminsdeferfrançaisC.N.E.S.T.002-1966Tankcontainers,longitudinalexternalstressesanddynamicimpacttests—Spoornet,SouthAfricaEngineeringDevelopmentCentre(EDC)TestingofISOTankContainersMethodEDC/EST/023/000/1991-066.7.4.14.2.Thetankanditemsofequipmentofeachportabletankshallbeinspectedandtestedbeforebeingputintoserviceforthefirsttime(initialinspectionandtest)andthereafteratnotmorethanfive-yearintervals(five-yearperiodicinspectionandtest)withanintermediateperiodicinspectionandtest(2,5-yearperiodicinspectionandtest)midwaybetweenthefive-yearperiodicinspectionsandtests.The2,5-yearinspectionandtestmaybeperformedwithinthreemonthsofthespecifieddate.Anexceptionalinspectionandtestshallbeperformedregardlessofthelastperiodicinspectionandtestwhennecessaryaccordingto6.7.4.14.7.6.7.4.14.3.Theinitialinspectionandtestofaportabletankshallincludeacheckofthedesigncharacteristics,aninternalandexternalexaminationoftheportabletankshellanditsfittingswithdueregardtotherefrigeratedliquefiedgasestobecarried,andapressuretestreferringtothetestpressuresaccordingto6.7.4.3.2.Thepressuretestmaybeperformedasahydraulictestorbyusinganotherliquidorgaswiththeagreementofthecompetentauthorityoritsauthorisedbody.Beforetheportabletankisplacedintoservice,aleakproofnesstestandacheckofthesatisfactoryoperationofallserviceequipmentshallalsobeperformed.Whentheshellanditsfittingshavebeenpressure-testedseparately,theyshallbesubjectedtogetherafterassemblytoaleakproofnesstest.Allweldssubjecttofullstresslevelshallbeinspectedduringtheinitialtestbyradiographic,ultrasonic,oranothersuitablenon-destructivetestmethod.Thisdoesnotapplytothejacket.6.7.4.14.4.Thefive-and2,5-yearperiodicinspectionandtestshallincludeanexternalexaminationoftheportabletankanditsfittingswithdueregardtotherefrigeratedliquefiedgasescarried,aleakproofnesstest,acheckofthesatisfactoryoperationofallserviceequipmentandavacuumreading,whenapplicable.Inthecaseofnon-vacuuminsulatedtanks,thejacketandinsulationshallberemovedduringa2,5-yearandafive-yearperiodicinspectionbutonlytotheextentnecessaryforareliableappraisal.6.7.4.14.5.Inaddition,atthefive-yearperiodicinspectionandtestofnon-vacuuminsulatedtanksthejacketandinsulationshallberemoved,butonlytotheextentnecessaryforareliableappraisal.6.7.4.14.6.Aportabletankmaynotbefilledandofferedforcarriageafterthedateofexpiryofthelastfive-yearor2,5-yearperiodicinspectionandtestasrequiredby6.7.4.14.2.Howeveraportabletankfilledpriortothedateofexpiryofthelastperiodicinspectionandtestmaybecarriedforaperiodnottoexceedthreemonthsbeyondthedateofexpiryofthelastperiodictestorinspection.Inaddition,aportabletankmaybecarriedafterthedateofexpiryofthelastperiodictestandinspection:(a)afteremptyingbutbeforecleaning,forpurposesofperformingthenextrequiredtestorinspectionpriortorefilling;and(b)unlessotherwiseapprovedbythecompetentauthority,foraperiodnottoexceedsixmonthsbeyondthedateofexpiryofthelastperiodictestorinspection,inordertoallowthereturnofdangerousgoodsforproperdisposalorrecycling.Referencetothisexemptionshallbementionedinthetransportdocument.6.7.4.14.7.Theexceptionalinspectionandtestisnecessarywhentheportabletankshowsevidenceofdamagedorcorrodedareas,leakage,oranyotherconditionsthatindicateadeficiencythatcouldaffecttheintegrityoftheportabletank.Theextentoftheexceptionalinspectionandtestshalldependontheamountofdamageordeteriorationoftheportabletank.Itshallincludeatleastthe2,5-yearinspectionandtestaccordingto6.7.4.14.4.6.7.4.14.8.Theinternalexaminationduringtheinitialinspectionandtestshallensurethattheshellisinspectedforpitting,corrosion,orabrasions,dents,distortions,defectsinweldsoranyotherconditions,thatmightrendertheportabletankunsafeforcarriage.6.7.4.14.9.Theexternalexaminationshallensurethat:(a)theexternalpiping,valves,pressurising/coolingsystemswhenapplicableandgasketsareinspectedforcorrodedareas,defects,oranyotherconditions,includingleakage,thatmightrendertheportabletankunsafeforfilling,dischargeorcarriage;(b)thereisnoleakageatanymanholecoversorgaskets;(c)missingorlooseboltsornutsonanyflangedconnectionorblankflangearereplacedortightened;(d)allemergencydevicesandvalvesarefreefromcorrosion,distortionandanydamageordefectthatcouldpreventtheirnormaloperation.Remoteclosuredevicesandself-closingstop-valvesshallbeoperatedtodemonstrateproperoperation;OfficialJournaloftheEuropeanUnionEN26.1.2004L18/854(e)requiredmarkingsontheportabletankarelegibleandinaccordancewiththeapplicablerequirements;and(f)theframework,thesupportsandthearrangementsforliftingtheportabletankareinsatisfactorycondition.6.7.4.14.10.Theinspectionsandtestsin6.7.4.14.1,6.7.4.14.3,6.7.4.14.4,6.7.4.14.5and6.7.4.14.7shallbeperformedorwitnessedbyanexpertapprovedbythecompetentauthorityoritsauthorisedbody.Whenthepressuretestisapartoftheinspectionandtest,thetestpressureshallbetheoneindicatedonthedataplateoftheportabletank.Whileunderpressure,theportabletankshallbeinspectedforanyleaksintheshell,pipingorequipment.6.7.4.14.11.Inallcaseswhencutting,burningorweldingoperationsontheshellofaportabletankhavebeeneffected,thatworkshallbetotheapprovalofthecompetentauthorityoritsauthorisedbodytakingintoaccountthepressurevesselcodeusedfortheconstructionoftheshell.Apressuretesttotheoriginaltestpressureshallbeperformedaftertheworkiscompleted.6.7.4.14.12.Whenevidenceofanyunsafeconditionisdiscovered,theportabletankshallnotbereturnedtoserviceuntilithasbeencorrectedandthetestisrepeatedandpassed.6.7.4.15.Marking6.7.4.15.1.Everyportabletankshallbefittedwithacorrosionresistantmetalplatepermanentlyattachedtotheportabletankinaconspicuousplacereadilyaccessibleforinspection.Whenforreasonsofportabletankarrangements,theplatecannotbepermanentlyattachedtotheshell,theshellshallbemarkedwithatleasttheinformationrequiredbythepressurevesselcode.Asaminimumatleastthefollowinginformationshallbemarkedontheplatebystampingorbyanyothersimilarmethod:CountryofmanufactureApprovalCountryApprovalNumberIncaseofalternativearrangements(see6.7.1.2)‘AA’Manufacturer'snameormarkManufacturer'sserialnumberAuthorisedbodyforthedesignapprovalOwner'sregistrationnumberYearofmanufacturePressurevesselcodetowhichthetankisdesignedTestpressure…bar/kPa(gaugepressure)(1)MAWP…bar/kPa(gaugepressure)(1)Minimumdesigntemperature…°CWatercapacityat20°C…litresInitialpressuretestdateandwitnessidentificationShellmaterial(s)andmaterialstandardreference(s)Equivalentthicknessinreferencesteel…mmDateandtypeofmostrecentperiodictest(s)Month…Year…Testpressure…bar/kPa(gaugepressure)(1)StampofexpertwhoperformedorwitnessedthemostrecenttestThename,infull,ofthegas(es)forwhosecarriagetheportabletankisapprovedEither‘thermallyinsulated’or‘vacuuminsulated’Effectivenessoftheinsulationsystem(heatinflux)…Watts(W)Referenceholdingtime…days(orhours)andinitialpressure…bar/kPa(gaugepressure)(1)anddegreeoffilling…inkgforeachrefrigeratedliquefiedgaspermittedforcarriage.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/855(1)Theunitusedshallbemarked.6.7.4.15.2.Thefollowingparticularsshallbedurablymarkedeitherontheportabletankitselforonametalplatefirmlysecuredtotheportabletank.NameoftheownerandtheoperatorNameoftherefrigeratedliquefiedgasbeingcarried(andminimummeanbulktemperature)Maximumpermissiblegrossmass(MPGM)…kgUnladen(tare)mass…kgActualholdingtimeforgasbeingcarried…days(orhours)NOTEFortheidentificationoftherefrigeratedliquefiedgas(es)beingcarried,seealsoPart5.6.7.4.15.3.Ifaportabletankisdesignedandapprovedforhandlinginopenseas,thewords‘OFFSHOREPORTABLETANK’shallbemarkedontheidentificationplate.CHAPTER6.8Requirementsfortheconstruction,equipment,type-approval,inspectionsandtests,andmarkingoffixedtanks(tank-vehicles),demoun-tabletanksandtank-containersandtankswapbodies,withshellsmadeofmetallicmaterials,andbattery-vehiclesandmultipleelementgascontainers(MEGCs)NOTEForportabletanksseeChapter6.7,forfibre-reinforcedplasticstanksseeChapter6.9,forvacuumoperatedwastetanksseeChapter6.10.6.8.1.Scope6.8.1.1.Therequirementsacrossthewholewidthofthepageapplybothtofixedtanks(tank-vehicles),todemountabletanksandbattery-vehicles,andtotank-containers,tankswapbodiesandMEGCs.Thosecontainedinasinglecolumnapplyonly:—tofixedtanks(tank-vehicles),todemountabletanksandbattery-vehicles(lefthandcolumn),—totank-containers,tankswapbodiesandMEGCs(righthandcolumn).6.8.1.2.Theserequirementsshallapplyto—fixedtanks(tank-vehicles),demountabletanksandbattery-vehicles—tank-containers,tankswapbodiesandMEGCsusedforthecarriageofgaseous,liquid,powderyorgranularsubstances.6.8.1.3.Section6.8.2setsouttherequirementsapplicabletofixedtanks(tank-vehicles),todemountabletanks,tank-containers,tankswapbodiesintendedforthecarriageofsubstancesofallclassesandbattery-vehiclesandMEGCsforgasesofClass2.Sections6.8.3to6.8.5containspecialrequirementssupplementingormodifyingtherequirementsofsection6.8.2.6.8.1.4.Forprovisionsconcerninguseofthesetanks,seeChapter4.3.6.8.2.Requirementsapplicabletoallclasses6.8.2.1.ConstructionBasicprinciples6.8.2.1.1.Shells,theirattachmentsandtheirserviceandstructuralequipmentshallbedesignedtowithstandwithoutlossofcontents(otherthanquantitiesofgasescapingthroughanydegassingvents):—staticanddynamicstressesinnormalconditionsofcarriageasdefinedin6.8.2.1.2and6.8.2.1.13,—prescribedminimumstressesasdefinedin6.8.2.1.15.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8566.8.2.1.2.Thetanksandtheirfasteningsshallbecapableofabsorbing,underthemaximumpermissibleload,theforcesexertedby:—inthedirectionoftravel:twicethetotalmass,—atrightanglestothedirectionoftravel:thetotalmass,—verticallyupwards:thetotalmass,—verticallydownwards:twicethetotalmass.Tank-containersandtheirfasteningsshall,underthemaximumpermissibleloadbecapableofabsorbingtheforcesequaltothoseexertedby:—inthedirectionoftravel:twicethetotalmass,—horizontallyatrightanglestothedirectionoftravel:thetotalmass;(wherethedirectionoftravelisnotclearlydetermined,twicethetotalmassineachdirection),—verticallyupwards:thetotalmass,—verticallydownwards:twicethetotalmass.6.8.2.1.3.Thewallsoftheshellsshallhaveatleastthethicknessspecifiedin6.8.2.1.17and6.8.2.1.216.8.2.1.17to6.8.2.1.20.6.8.2.1.4.Shellsshallbedesignedandconstructedinaccordancewiththerequirementsofatechnicalcoderecognisedbythecompetentauthority,inwhichthematerialischosenandtheshellthicknessdeterminedtakingintoaccountmaximumandminimumfillingandworkingtemperatures,butthefollowingminimumrequirementsof6.8.2.1.6to6.8.2.1.26shallbemet.6.8.2.1.5.Tanksintendedtocontaincertaindangeroussubstancesshallbeprovidedwithadditionalprotection.Thismaytaketheformofadditionalthicknessoftheshell(increasedcalculationpressure)determinedinthelightofthedangersinherentinthesubstancesconcernedorofaprotectivedevice(seethespecialprovisionsof6.8.4).6.8.2.1.6.Weldsshallbeskilfullymadeandshallaffordthefullestsafety.Theexecutionandcheckingofweldsshallcomplywiththerequirementsof6.8.2.1.23.6.8.2.1.7.Measuresshallbetakentoprotectshellsagainsttheriskofdeformationasaresultofanegativeinternalpressure.Materialsforshells6.8.2.1.8.Shellsshallbemadeofsuitablemetallicmaterialswhich,unlessothertemperaturerangesareprescribedinthevariousclasses,shallberesistanttobrittlefractureandtostresscorrosioncrackingbetween–20Cand+50C.6.8.2.1.9.Thematerialsofshellsoroftheirprotectiveliningswhichareincontactwiththecontentsshallnotcontainsubstancesliabletoreactdangerously(see‘Dangerousreaction’in1.2.1)withthecontents,toformdangerouscompounds,orsubstantiallytoweakenthematerial.Ifcontactbetweenthesubstancecarriedandthematerialusedfortheconstructionoftheshellentailsaprogressivedecreaseintheshellthickness,thisthicknessshallbeincreasedatmanufacturebyanappropriateamount.Thisadditionalthicknesstoallowforcorrosionshallnotbetakenintoconsiderationincalculatingtheshellthickness.6.8.2.1.10.Forweldedshellsonlymaterialsoffaultlessweldabilitywhoseadequateimpactstrengthatanambienttemperatureof–20ºCcanbeguaranteed,particularlyintheweldseamsandthezonesadjacentthereto,shallbeused.Iffine-grainedsteelisused,theguaranteedvalueoftheyieldstrengthReshallnotexceed460N/mm2andtheguaranteedvalueoftheupperlimitoftensilestrengthRmshallnotexceed725N/mm2,inaccordancewiththespecificationsofthematerial.6.8.2.1.11.RatiosofRe/Rmexceeding0,85arenotallowedforsteelsusedintheconstructionofweldedtanks.Re=apparentyieldstrengthforsteelshavingaclearly-definedyieldpointorguaranteed0,2%proofstrengthforsteelswithnoclearly-definedyieldpoint(1%forausteniticsteels)Rm=tensilestrength.Thevaluesspecifiedintheinspectioncertificateforthematerialshallbetakenasabasisindeterminingthisratioineachcase.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8576.8.2.1.12.Forsteel,theelongationatfracture,in%shallbenotlessthan10000determinedtensilestrengthinN=mm2butinanycaseforfine-grainedsteelsitshallbenotlessthan16%andnotlessthan20%forothersteels.Foraluminiumalloystheelongationatfractureshallbenotlessthan12%(1).Calculationoftheshellthickness6.8.2.1.13.Thepressureonwhichtheshellthicknessisbasedshallnotbelessthanthecalculationpressure,butthestressesreferredtoin6.8.2.1.1shallalsobetakenintoaccount,and,ifnecessary,thefollowingstresses:Inthecaseofvehiclesinwhichthetankconstitutesastressedself-supportingmember,theshellshallbedesignedtowithstandthestressesthusimposedinadditiontostressesfromothersources.Underthesestresses,thestressatthemostseverelystressedpointoftheshellanditsfasteningsshallnotexceedthevalueσdefinedin6.8.2.1.16.Undereachofthesestressesthesafetyfactorstobeobservedshallbethefollowing:—formetalshavingaclearly-definedyieldpoint:asafetyfactorof1,5inrelationtotheapparentyieldstrength;or—formetalswithnoclearly-definedyieldpoint:asafetyfactorof1,5inrelationtotheguaranteed0,2%proofstrength(1%maximumelongationforausteniticsteels).6.8.2.1.14.Thecalculationpressureisinthesecondpartofthecode(see4.3.4.1)accordingtocolumn12ofTableAofChapter3.2.When‘G’appears,thefollowingrequirementsshallapply:(a)gravity-dischargeshellsintendedforthecarriageofsubstanceshavingavapourpressurenotexceeding110kPa(1,1bar)(absolutepressure)at50ºCshallbedesignedforacalculationpressureoftwicethestaticpressureofthesubstancetobecarriedbutnotlessthantwicethestaticpressureofwater.(b)pressure-filledorpressure-dischargeshellsintendedforthecarriageofsubstanceshavingavapourpressurenotexceeding110kPa(1,1bar)(absolutepressure)at50ºCshallbedesignedforacalculationpressureequalto1,3timesthefillingordischargepressure.Whenthenumericalvalueoftheminimumcalculationpressureisgiven(gaugepressure)theshellshallbedesignedforthispressurewhichshallnotbelessthan1,3timesthefillingordischargepressure.Thefollowingminimumrequirementsshallapplyinthesecases:(c)shellsintendedforthecarriageofsubstanceshavingavapourpressureofmorethan110kPa(1,1bar)butnotmorethan175kPa(1,75bar)(absolutepressure)at50°Cshall,whatevertheirfillingordischargesystem,bedesignedforacalculationpressureofnotlessthan150kPa(1,5bar)gaugepressureor1,3timesthefillingordischargepressure,whicheveristhehigher;(d)shellsintendedforthecarriageofsubstanceshavingavapourpressureofmorethan175kPa(1,75bar)(absolutepressure)at50°Cshall,whatevertheirfillingordischargesystem,bedesignedforacalculationpressureequalto1,3timesthefillingordischargepressurebutnotlessthan0,4MPa(4bar)(gaugepressure).6.8.2.1.15.Atthetestpressure,thestressσatthemostseverelystressedpointoftheshellshallnotexceedthematerial-dependentlimitsprescribedbelow.Allowanceshallbemadeforanyweakeningduetothewelds.6.8.2.1.16.Forallmetalsandalloys,thestressσatthetestpressureshallbelowerthanthesmallerofthevaluesgivenbythefollowingformulae:σ≤0,75Reorσ≤0,5RmwhereRe=apparentyieldstrengthforsteelshavingaclearly-definedyieldpointorguaranteed0,2%proofstrengthforsteelswithnoclearly-definedyieldpoint(1%forausteniticsteels)OfficialJournaloftheEuropeanUnionEN26.1.2004L18/858(1)Inthecaseofsheetmetaltheaxisofthetensiletest-pieceshallbeatrightanglestothedirectionofrolling.Thepermanentelongationatfractureshallbemeasuredontest-piecesofcircularcross-sectioninwhichthegaugelengthlisequaltofivetimesthediameterd(l=5d);iftest-piecesofrectangularsectionareused,thegaugelengthshallbecalculatedbytheformulal¼5;65ﬃﬃﬃﬃﬃFopwhereFoindicatestheinitialcross-sectionareaofthetest-piece.Rm=tensilestrength.ThevaluesofReandRmtobeusedshallbespecifiedminimumvaluesaccordingtomaterialstandards.Ifnomaterialstandardexistsforthemetaloralloyinquestion,thevaluesofReandRmusedshallbeapprovedbythecompetentauthorityorbyabodydesignatedbythatauthority.Whenausteniticsteelsareused,thespecifiedminimumvaluesaccordingtothematerialstandardsmaybeexceededbyupto15%ifthesehighervaluesareattestedintheinspectioncertificate.Minimumshellthickness6.8.2.1.17.Theshellthicknessshellshallnotbelessthanthegreaterofthevaluesdeterminedbythefollowingformulae:e¼PTD2σλe¼PCD2σwhere:e=minimumshellthicknessinmmPT=testpressureinMPaPC=calculationpressureinMPaasspecifiedin6.8.2.1.14D=internaldiameterofshellinmmσ=permissiblestress,asdefinedin6.8.2.1.16,inN/mm2λ=acoefficientnotexceedingorequalto1,allowingforanyweakeningduetowelds,andlinkedtotheinspectionmethodsdefinedin6.8.2.1.23.Thethicknessshallinnocasebelessthanthatdefinedin6.8.2.1.18to6.8.2.1.21.6.8.2.1.18to6.8.2.1.20.6.8.2.1.18.Shellsofcircularcross-section(1)notmorethan1,80mindiameterotherthanthosereferredtoin6.8.2.1.21,shallnotbelessthan5mmthickifofmildsteel(2),orofequivalentthicknessifofanothermetal.Wherethediameterismorethan1,80m,thisthicknessshallbeincreasedto6mmexceptinthecaseofshellsintendedforthecarriageofpowderyorgranularsubstances,iftheshellisofmildsteel(2),ortoanequivalentthicknessifofanothermetal.Shellsshallbenotlessthan5mmthickifofmildsteel(2)(inconformitywiththerequirementsof6.8.2.1.11and6.8.2.1.12)orofequivalentthicknessifofanothermetal.Wherethediameterismorethan1,80m,thisthicknessshallbeincreasedto6mmexceptinthecaseoftanksintendedforthecarriageofpowderyorgranularsubstances,iftheshellisofmildsteel(2)ortoanequivalentthicknessifofanothermetal.Whateverthemetalused,theshellthicknessshallinnocasebelessthan3mm.‘Equivalentthickness’meansthethicknessobtainedbythefollowingformula(3):OfficialJournaloftheEuropeanUnionEN26.1.2004L18/859(1)Forshellsnotofacircularcross-section,forexamplebox-shapedorellipticalshells,theindicateddiametersshallcorrespondtothosecalculatedonthebasisofacircularcross-sectionofthesamearea.Forsuchshapesofcross-sectiontheradiusofconvexityoftheshellwallshallnotexceed2000mmatthesidesor3000mmatthetopandbottom.(2)Forthedefinitionsof‘mildsteel’and‘referencesteel’see1.2.1.(3)Thisformulaisderivedfromthegeneralformula:wheree1=minimumshellthicknessforthemetalchosen,inmm;e0=minimumshellthicknessformildsteel,inmm,accordingto6.8.2.1.18and6.8.2.1.19;Rm0=370(tensilestrengthforreferencesteel,seedefinition1.2.1,inN/mm2);A0=27(elongationatfractureforreferencesteel,in%);Rm1=minimumtensilestrengthofthemetalchosen,inN/mm2;andA1=minimumelongationatfractureofthemetalchosenundertensilestress,in%6.8.2.1.19.Whereprotectionofthetankagainstdamagethroughlateralimpactoroverturningisprovidedaccordingto6.8.2.1.20,thecompetentauthoritymayallowtheaforesaidminimumthick-nessestobereducedinproportiontotheprotectionprovided;however,thesaidthicknessesshallnotbelessthan3mminthecaseofmildsteel(1),orthananequivalentthicknessinthecaseofothermaterials,forshellsnotmorethan1,80mindiameter.Forshellswithadiameterexceeding1,80mtheaforesaidminimumthicknessshallbeincreasedto4mminthecaseofmildsteel(1)andtoanequivalentthicknessinthecaseofothermetals.Whereprotectionofthetankagainstdamageisprovidedaccordingto6.8.2.1.20,thecompetentauthoritymayallowtheaforesaidminimumthicknessestobereducedinproportiontotheprotectionprovided;however,thesaidthicknessesshallbenotlessthan3mminthecaseofmildsteel(1),orthananequivalentthicknessinthecaseofothermaterials,forshellsnotmorethan1,80mindiameter.Forshellsofadiameterexceeding1,80mthisminimumthicknessshallbeincreasedto4mminthecaseofmildsteel(1),andtoanequivalentthicknessinthecaseofothermetals.Equivalentthicknessmeansthethicknessgivenbytheformulain6.8.2.1.18.Exceptincasesforwhich6.8.2.1.21provide,thethicknessofshellswithprotectionagainstdamageinaccordancewith6.8.2.1.20(a)or(b)shallnotbelessthanthevaluesgiveninthetablebelow.Diameterofshell≤1.80m>1.80mMinimumthicknessofshellsStainlessausteniticsteels2,5mm3mmOthersteels3mm4mmAluminiumalloys4mm5mmPurealumi-niumof99,80%6mm8mmEquivalentthicknessmeansthethicknessgivenbytheformulain6.8.2.1.18.6.8.2.1.20.Fortanksbuiltafter1January1990,thereisprotectionagainstdamageasreferredtoin6.8.2.1.19whenthefollowingmeasuresorequivalentmeasuresareadopted.(a)Fortanksintendedforthecarriageofpowderyorgranularsubstances,theprotectionagainstdamageshallsatisfythecompetentauthority.(b)Fortanksintendedforthecarriageofothersubstances,thereisprotectionagainstdamagewhen:1.Forshellswithacircularorellipticalcross-sectionhavingamaximumradiusofcurvatureof2m,theshellisequippedwithstrengtheningmemberscomprisingparti-tions,surge-platesorexternalorinternalrings,soplacedthatatleastoneofthefollowingconditionsismet:—distancebetweentwoadjacentstrengtheningelementsofnotmorethan1,75m,—volumecontainedbetweentwopartitionsorsurge-platesofnotmorethan7500l.Theverticalcross-sectionofaring,withtheassociatedcoupling,shallhaveasectionmodulusofatleast10cm3.Theprotectionreferredtoin6.8.2.1.19mayconsistof:—overallexternalstructuralprotectionasin‘sandwich’construc-tionwherethesheathingissecuredtotheshell,or—astructureinwhichtheshellissupportedbyacompleteskeletonincludinglongitudinalandtransversestructuralmembers,or—double-wallconstruction.Wherethetanksaremadewithdoublewalls,thespacebetweenbeingevacuatedofair,theaggregatethicknessoftheoutermetalwallandtheshellwallshallcorrespondtotheminimumwallthicknessprescribedin6.8.2.1.18,thethicknessofthewalloftheshellitselfbeingnotlessthantheminimumthicknessprescribedin6.8.2.1.19.Wheretanksaremadewithdoublewallswithanintermediatelayerofsolidmaterialsatleast50mmthick,theouterwallshallhaveathicknessofnotlessthan0,5mmifitismadeofmildsteel(1)oratleast2mmifitismadeofaplasticsmaterialreinforcedwithglassfibre.Solidfoamwithanimpactabsorptioncapacitysuchasthat,forexample,ofpolyurethanefoam,maybeusedastheintermediatelayerofsolidmaterial.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/860(1)Forthedefinitionsof‘mildsteel’and‘referencesteel’see1.2.1.Externalringsshallnothaveprojectingedgeswitharadiusoflessthan2,5mm.Partitionsandsurge-platesshallconformtotherequire-mentsof6.8.2.1.22.Thethicknessofthepartitionsandsurge-platesshallinnocasebelessthanthatoftheshell.2.Fortanksmadewithdoublewalls,thespacebetweenbeingevacuatedofair,theaggregatethicknessoftheoutermetalwallandtheshellwallcorrespondstothewallthicknessprescribedin6.8.2.1.18,andthethicknessofthewalloftheshellitselfisnotlessthantheminimumthicknessprescribedin6.8.2.1.19.3.Fortanksmadewithdoublewallshavinganintermediatelayerofsolidmaterialsatleast50mmthick,theouterwallhasathicknessofatleast0,5mmofmildsteel(1)oratleast2mmofaplasticsmaterialreinforcedwithglassfibre.Solidfoam(withanimpactabsorptioncapacitylikethat,forexample,ofpolyurethanefoam)maybeusedastheintermediatelayerofsolidmaterial.4.Shellsofformsotherthanin1,especiallybox-shapedshells,areprovided,allroundthemid-pointoftheirverticalheightandoveratleast30%oftheirheightwithaprotectiondesignedinsuchawayastoofferspecificresilienceatleastequaltothatofashellconstructedinmildsteel(1)ofathicknessof5mm(forashelldiameternotexceeding1,80m)or6mm(forashelldiameterexceeding1,80m).Theprotectionshallbeappliedinadurablemannertotheoutsideoftheshell.Thisrequirementshallbeconsideredtohavebeenmetwithoutfurtherproofofthespecificresiliencewhentheprotectioninvolvestheweldingofaplateofthesamematerialastheshelltotheareatobestrengthened,sothattheminimumwallthicknessisinaccordancewith6.8.2.1.18.Thisprotectionisdependentuponthepossiblestressesexertedonmildsteelshellsintheeventofanaccident,wheretheendsandwallshaveathicknessofatleast5mmforadiameternotexceeding1,80moratleast6mmforadiameterexceeding1,80m.Ifanothermetalisused,theequivalentthicknessshallbeobtainedinaccordancewiththeformulain6.8.2.1.18.Fordemountabletanksthisprotectionisnotrequiredwhentheyareprotectedonallsidesbythedropsidesofthecarryingvehicle.6.8.2.1.21.Thethicknessofshellsdesignedinaccordancewith6.8.2.1.14(a)whicheitherareofnotmorethan5000litrescapacityoraredividedintoleakproofcompartmentsofnotmorethan5000litresunitcapacitymaybeadjustedtoalevelwhich,unlessprescribedotherwisein6.8.3or6.8.4,shallhowevernotbelessthantheappropriatevalueshowninthefollowingtable:Maximumradiusofcurvatureofshell(m)Capacityofshellorshellcompartment(m3)Minimumthickness(mm)Mildsteel≤2≤5,03OfficialJournaloftheEuropeanUnionEN26.1.2004L18/861(1)Forthedefinitionsof‘mildsteel’and‘referencesteel’see1.2.1.Maximumradiusofcurvatureofshell(m)Capacityofshellorshellcompartment(m3)Minimumthickness(mm)Mildsteel2-3≤3,53>3,5but≤5,04Whereametalotherthanmildsteel(1)isused,thethicknessshallbedeterminedbytheequivalenceformulagivenin6.8.2.1.18.Thethicknessofthepartitionsandsurge-platesshallinnocasebelessthanthatoftheshell.6.8.2.1.22.Surge-platesandpartitionsshallbedished,withadepthofdishofnotlessthan10cm,orshallbecorrugated,profiledorotherwisereinforcedtogiveequivalentstrength.Theareaofthesurgeplateshallbeatleast70%ofthecross-sectionalareaofthetankinwhichthesurge-plateisfitted.Weldingandinspectionofwelds6.8.2.1.23.Themanufacturer'squalificationforperformingweldingoperationsshallbeonerecognisedbythecompetentauthority.Weldingshallbeperformedbyskilledweldersusingaweldingprocesswhoseeffectiveness(includinganyheattreatmentsrequired)hasbeendemonstratedbytest.Non-destructivetestsshallbecarriedoutbyradiographyorbyultrasoundandmustconfirmthatthequalityoftheweldingisappropriatetothestresses.Thefollowingchecksshallbecarriedoutinaccordancewiththevalueofthecoefficientusedindeterminingthethicknessoftheshellin6.8.2.1.17:λ=0,8:theweldbeadsshallsofaraspossiblebeinspectedvisuallyonbothfacesandshallbesubjectedtoanon-destructivespotcheckwithparticularattentiontoconnections;λ=0,9:alllongitudinalbeadsthroughouttheirlength,allconnections,25%ofcircularbeads,andweldsfortheassemblyoflarge-diameteritemsofequipmentshallbesubjectedtonon-destructivechecks.Beadsshallbecheckedvisuallyonbothsidesasfaraspossible;λ=1:allbeadsshallbesubjectedtonon-destructivechecksandaresofaraspossibleinspectedvisuallyonbothsides.Aweldtest-pieceshallbetaken.Wherethecompetentauthorityhasdoubtsregardingthequalityofweldbeads,itmayrequireadditionalchecks.Otherconstructionrequirements6.8.2.1.24.Theprotectiveliningshallbesodesignedthatitsleakproofnessremainsintact,whateverthedeformationliabletooccurinnormalconditionsofcarriage(see6.8.2.1.2).6.8.2.1.25.Thethermalinsulationshallbesodesignedasnottohinderaccessto,ortheoperationof,fillinganddischargedevicesandsafetyvalves.6.8.2.1.26.Ifshellsintendedforthecarriageofflammableliquidshavingaflash-pointofnotmorethan61ºCarefittedwithnon-metallicprotectivelinings(innerlayers),theshellsandtheprotectiveliningsshallbesodesignedthatnodangerofignitionfromelectrostaticchargescanoccur.6.8.2.1.27.Shellsintendedforthecarriageofliquidshavingaflash-pointofnotmorethan61°Corforthecarriageofflammablegases,orofUNNo1361carbonorUNNo1361carbonblack,packinggroupII,shallbelinkedtothechassisbymeansofatleastonegoodelectricalconnection.Anymetalcontactcapableofcausingelectrochemicalcorrosionshallbeavoided.Shellsshallbeprovidedwithatleastoneearthfittingclearlymarkedwiththesymbol,capableofbeingelectricallyconnected.Allpartsofatank-containerintendedforthecarriageofliquidshavingaflash-pointofnotmorethan61°C,flammablegases,orUNNo1361carbonorUNNo1361carbonblack,packinggroupII,shallbecapableofbeingelectricallyearthed.Anymetalcontactcapableofcausingelectrochemicalcorrosionshallbeavoided.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/862(1)Forthedefinitionsof‘mildsteel’and‘referencesteel’see1.2.1.6.8.2.1.28.ProtectionoffittingsmountedontheupperpartofthetankThefittingsandaccessoriesmountedontheupperpartofthetankshallbeprotectedagainstdamagecausedbyoverturning.Thisprotectionmaytaketheformofstrengtheningrings,protec-tivecanopiesortransverseorlongitudinalmemberssoshapedthateffectiveprotectionisgiven.6.8.2.2.Itemsofequipment6.8.2.2.1.Suitablenon-metallicmaterialsmaybeusedtomanufactureserviceandstructuralequipment.Theitemsofequipmentshallbesoarrangedastobeprotectedagainsttheriskofbeingwrenchedoffordamagedduringcarriageorhandling.Theyshallexhibitasuitabledegreeofsafetycomparabletothatoftheshellsthemselves,andshallinparticular:—becompatiblewiththesubstancescarried,and—meettherequirementsof6.8.2.1.1.Asmanyoperatingpartsaspossibleshallbeservedbythesmallestpossiblenumberofopeningsintheshell.Theleakproof-nessoftheserviceequipmentincludingtheclosure(cover)oftheinspectionopeningsshallbeensuredevenintheeventofover-turningofthetank,takingintoaccounttheforcesgeneratedbyanimpact(suchasaccelerationanddynamicpressure).Limitedreleaseofthetankcontentsduetoapressurepeakduringtheimpactishoweverallowed.Theleakproofnessoftheserviceequipmentshallbeensuredevenintheeventoftheoverturningofthetank-container.Thegasketsshallbemadeofamaterialcompatiblewiththesubstancecarriedandshallbereplacedassoonastheireffectivenessisimpaired,forexampleasaresultofageing.Gasketsensuringtheleakproofnessoffittingsrequiringmanipulationduringnormaluseoftanksshallbesodesignedandarrangedthatmanipulationofthefittingsincorporatingthemdoesnotdamagethem.6.8.2.2.2.Eachbottom-fillingorbottom-dischargeopeningintankswhicharereferredto,incolumn12ofTableAofChapter3.2,withatankcodeincludingtheletter‘A’initsthirdpart(see4.3.4.1.1)shallbeequippedwithatleasttwomutuallyindependentclosures,mountedinseries,comprising—anexternalstop-valvewithpipingmadeofamalleablemetalmaterialand—aclosingdeviceattheendofeachpipewhichmaybeascrew-threadedplug,ablankflangeoranequivalentdevice.Eachbottom-fillingorbottom-dischargeopeningintankswhicharereferredto,inColumn12ofTableAofChapter3.2,withatankcodeincludingtheletter‘B’initsthirdpart(see4.3.3.1.1or4.3.4.1.1)shallbeequippedwithatleastthreemutuallyindependentclosures,mountedinseries,comprising—aninternalstop-valve,i.e.astop-valvemountedinsidetheshellorinaweldedflangeorcompanionflange;—anexternalstop-valveoranequivalentdevice(1)oneattheendofeachpipeasnearaspossibletotheshelland—aclosingdeviceattheendofeachpipe,whichmaybeascrew-threadedplug,ablankflangeoranequivalentdevice.However,inthecaseoftanksintendedforthecarriageofcertaincrystallisableorhighlyviscoussubstancesandshellsfittedwithaneboniteorthermoplasticcoating,theinternalstop-valvemaybereplacedbyanexternalstop-valveprovidedwithadditionalprotection.Theinternalstop-valveshallbeoperableeitherfromaboveorfrombelow.Itssetting,openorclosed,shallsofaraspossibleineachcasebecapableofbeingverifiedfromtheground.Internalstop-valvecontroldevicesshallbesodesignedastopreventanyunintendedopeningthroughimpactoraninadvertentact.Theinternalshut-offdeviceshallcontinuetobeeffectiveintheeventofdamagetotheexternalcontroldevice.Inordertoavoidanylossofcontentsintheeventofdamagetotheexternalfittings(pipes,lateralshut-offdevices),theinternalstop-valveanditsseatingshallbeprotectedagainstthedangerofbeingwrenchedoffbyexternalstressesorshallbesodesignedastoresistthem.Thefillinganddischargedevices(includingflangesorthreadedplugs)andprotectivecaps(ifany)shallbecapableofbeingsecuredagainstanyunintendedopening.Thepositionand/ordirectionofclosureofshut-offdevicesshallbeclearlyapparent.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/863(1)Inthecaseoftank-containersoflessthan1m3capacity,theexternalstop-valveorotherequivalentdevicemaybereplacedbyablankflange.AllopeningsoftankswhicharereferredtoinColumn12ofTableAofChapter3.2,byatankcodeincludingletter‘C’or‘D’initsthirdpart(see4.3.3.1.1and4.3.4.1.1)shallbesituatedabovethesurfaceleveloftheliquid.Thesetanksshallhavenopipesorpipeconnectionsbelowthesurfaceleveloftheliquid.Thecleaningopenings(fist-holes)are,however,permittedinthelowerpartoftheshellfortanksreferredtobyatankcodeincludingletter‘C’initsthirdpart.Thisopeningshallbecapableofbeingsealedbyaflangesoclosedastobeleakproofandwhosedesignshallbeapprovedbythecompetentauthorityorbyabodydesignatedbythatauthority.6.8.2.2.3.Unlessotherwiseprescribedintheprovisionsof6.8.4,tanksmayhavevalvestoavoidanunacceptablenegativeinternalpressure,withoutinterveningburstingdiscs.6.8.2.2.4.Theshelloreachofitscompartmentsshallbeprovidedwithanopeninglargeenoughtopermitinspection.6.8.2.2.5.(Reserved)6.8.2.2.6.Tanksintendedforthecarriageofliquidshavingavapourpressureofnotmorethan110kPa(1,1bar)(absolute)at50°Cshallhaveaventingsystemandasafetydevicetopreventthecontentsfromspillingoutifthetankoverturns;otherwisetheyshallconformto6.8.2.2.7or6.8.2.2.8.6.8.2.2.7.Tanksintendedforthecarriageofliquidshavingavapourpressureofmorethan110kPa(1,1bar)butnotexceeding175kPa(1,75bar)(absolute)at50°Cshallhaveasafetyvalvesetatnotlessthan150kPa(1,5bar)(gaugepressure)andwhichshallbefullyopenatapressurenotexceedingthetestpressure;otherwisetheyshallconformto6.8.2.2.8.6.8.2.2.8.Tanksintendedforthecarriageofliquidshavingavapourpressureofmorethan175kPa(1,75bar)butnotexceeding300kPa(3bar)(absolute)at50ºCshallhaveasafetyvalvesetatnotlessthan300kPa(3bar)gaugepressureandwhichshallbefullyopenatapressurenotexceedingthetestpressure;otherwisetheyshallbehermeticallyclosed(1).6.8.2.2.9.Movablepartssuchascovers,closures,etc.,whichareliabletocomeintofrictionalorpercussivecontactwithaluminiumshellsintendedforthecarriageofflammableliquidshavingaflash-pointofnotmorethan61°Corforthecarriageofflammablegasesshallnotbemadeofunprotectedcorrodiblesteel.6.8.2.3.Type-approval6.8.2.3.1.Thecompetentauthorityorabodydesignatedbythatauthorityshallissueinrespectofeachnewtypeoftank-vehicle,tank-container,battery-vehicleorMEGCacertificateattestingthatthetype,includingfastenings,whichithasinspectedissuitableforthepurposeforwhichitisintendedandmeetstheconstructionrequirementsof6.8.2.1,theequipmentrequirementsof6.8.2.2andthespecialconditionsfortheclassesofsubstancescarried.Thecertificateshallshow:—theresultsofthetest,—anapprovalnumberforthetype,Theapprovalnumbershallconsistofthedistinguishingsign(2)oftheStateinwhoseterritorytheapprovalwasgrantedandaregistrationnumber.—thetankcodeinaccordancewith4.3.3.1.1or4.3.4.1.1,—specialconstruction(TC)andequipment(TE)requirementsapplicabletothetype,—ifrequired,thesubstancesand/orgroupofsubstancesforthecarriageofwhichthetankhasbeenapproved.Theseshallbeshownwiththeirchemicalnameorthecorrespondingcollectiveentry(see2.1.1.2),togetherwiththeirclassification(class,classificationcodeandpackinggroup).WiththeexceptionofsubstancesofClass2andthoselistedin4.3.4.1.3,thelistingofapprovedsubstancesmaybedispensedwith.Insuchcases,groupsofsubstancespermittedonthebasisofthetankcodeshownintherationalisedapproachin4.3.4.1.2shallbeacceptedforcarriagetakingintoaccountanyrelevantspecialprovision.Thesubstancesreferredtointhecertificateorthegroupsofsubstancesapprovedaccordingtotherationalisedapproachshall,ingeneral,becompatiblewiththecharacteristicsofthetank.Areservationshallbeincludedinthecertificateifitwasnotpossibletoinvestigatethiscompatibilityexhaustivelywhenthetype-approvalwasissued.6.8.2.3.2.Ifthetanks,battery-vehiclesorMECGsaremanufacturedinserieswithoutmodificationthisapprovalshallbevalidforthetanks,battery-vehiclesorMECGsmanufacturedinseriesoraccordingtotheprototype.Atype-approvalmayhoweverservefortheapprovaloftankswithlimitedvariationsofthedesignthateitherreducetheloadsandstressesonthetanks(e.g.reducedpressure,reducedmass,reducedvolume)orincreasethesafetyofthestructure(e.g.increasedshellthickness,moresurge-plates,decreaseddiameterofopenings).Thelimitedvariationsshallbeclearlydescribedinthetype-approvalcertificate.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/864(1)Forthedefinitionof‘hermeticallyclosedtank’see1.2.1.(2)DistinguishingsignforuseininternationaltrafficprescribedbytheConventiononRoadTraffic(Vienna,1968).6.8.2.4.Inspectionsandtests6.8.2.4.1.Shellsandtheirequipmentshalleithertogetherorseparatelyundergoaninitialinspectionbeforebeingputintoservice.Thisinspectionshallinclude:—acheckofconformitytotheapprovedtype,—acheckofthedesigncharacteristics(1),—anexaminationoftheinternalandexternalconditions,—ahydraulicpressuretest(2)atthetestpressureindicatedontheplateprescribedin6.8.2.5.1,and—acheckofsatisfactoryoperationoftheequipment.Thehydraulicpressuretestshallbecarriedoutontheshellasawholeatthetestpressure,specifiedintheNoteto6.8.4(d),andseparatelyoneachcompartmentofcompartmentedshellsatapressureofnotlessthan1,3timesthemaximumworkingpressure.Theleakproofnesstestshallbecarriedoutseparatelyoneachcompartmentofcompartmentedshells.Thehydraulicpressuretestshallbecarriedoutbeforetheinstallationofsuchthermalequipmentasmaybenecessary.Iftheshellsandtheirequipmentaretestedseparately,theyshallbejointlysubjectedtoaleakproofnesstestafterassemblyinaccordancewith6.8.2.4.3.6.8.2.4.2.Shellsandtheirequipmentshallundergoperiodicinspectionsatfixedintervals.Theperiodicinspectionsshallinclude:anexternalandinternalexaminationand,asageneralrule,ahydraulicpressuretest(2).Sheathingforthermalorotherinsulationshallberemovedonlytotheextentrequiredforreliableappraisalofthecharacteristicsoftheshell.Thehydraulicpressuretestshallbecarriedoutontheshellasawholeatthetestpressure,specifiedintheNoteto6.8.4(d),andseparatelyoneachcompartmentofcompartmentedshellsatapressureofnotlessthan1,3timesthemaximumworkingpressure.Inthecaseoftanksintendedforthecarriageofpowderyorgranularsubstances,andwiththeagreementoftheexpertapprovedbythecompetentauthority,theperiodichydraulicpressuretestsmaybeomittedandreplacedbyleakproofnesstestsinaccordancewith6.8.2.4.3.Themaximumintervalsforinspectionshallbesixyears.Themaximumintervalsforinspectionsshallbefiveyears.6.8.2.4.3.Inaddition,aleakproofnesstestoftheshellwithitsequipmentandacheckofthesatisfactoryoperationofalltheequipmentshallbecarriedoutatleasteverythreeyears.atleasteverytwoandahalfyears.Forthispurposethetankshallbesubjectedtoaneffectiveinternalpressureequaltothemaximumworkingpressure,butnotlessthan20kPa(0,2bar)(gaugepressure).Fortanksequippedwithventingsystemsandasafetydevicetopreventthecontentsspillingoutifthetankoverturns,thepressuretestshallbeequaltothestaticpressureofthefillingsubstance.Theleakproofnesstestshallbecarriedoutseparatelyoneachcompartmentofcompartmentedshells.6.8.2.4.4.Whenthesafetyofthetankorofitsequipmentmayhavebeenimpairedasaresultofrepairs,alterationsoraccident,anexceptionalcheckshallbecarriedout.6.8.2.4.5.Thetests,inspectionsandchecksinaccordancewith6.8.2.4.1to6.8.2.4.4shallbecarriedoutbytheexpertapprovedbythecompetentauthority.Certificatesshallbeissuedshowingtheresultsoftheseoperations.Thesecertificatesshallrefertothelistofthesubstancespermittedforcarriageinthistankortothetankcodeinaccordancewith6.8.2.3.6.8.2.5.Marking6.8.2.5.1.Everytankshallbefittedwithacorrosion-resistantmetalplatepermanentlyattachedtothetankinaplacereadilyaccessibleforinspection.Thefollowingparticularsatleastshallbemarkedontheplatebystampingorbyanyothersimilarmethod.Theseparticularsmaybeengraveddirectlyonthewallsoftheshellitself,ifthewallsaresoreinforcedthatthestrengthoftheshellisnotimpaired(3):—approvalnumber,OfficialJournaloftheEuropeanUnionEN26.1.2004L18/865(1)Thecheckofthedesigncharacteristicsshallalsoinclude,forshellsrequiringatestpressureof1MPa(10bar)orhigher,thetakingofweldtest-pieces(worksamples)inaccordancewith6.8.2.1.23andthetestsprescribedin6.8.5.(2)Inspecialcasesandwiththeagreementoftheexpertapprovedbythecompetentauthority,thehydraulicpressuretestmaybereplacedbyapressuretestusinganotherliquidorgas,wheresuchanoperationdoesnotpresentanydanger.(3)Addtheunitsofmeasurementafterthenumericalvalues.—manufacturer'snameormark,—manufacturer'sserialnumber,—yearofmanufacture,—testpressure(gaugepressure),—capacity—inthecaseofmultiple-elementshells,thecapacityofeachelement,—designtemperature(onlyifabove+50ºCorbelow–20ºC),—date(monthandyear)ofinitialtestandmostrecentperiodictestinaccordancewith6.8.2.4.1and6.8.2.4.2,—stampoftheexpertwhocarriedoutthetests,—materialoftheshellandreferencetomaterialsstandards,ifavailableand,whereappropriate,theprotectivelining,—testpressureontheshellasawholeandtestpressurebycompartmentinMPaorbar(gaugepressure)wherethepressurebycompartmentislessthanthepressureontheshell.Inaddition,themaximumworkingpressureallowedshallbeinscribedonpressure-filledorpressure-dischargetanks.6.8.2.5.2.Thefollowingparticularsshallbeinscribedonthetank-vehicleitselforonaplate(1):—nameofowneroroperator,—unladenmass,and—maximumpermissiblemass.Theseparticularsshallnotberequiredinthecaseofavehiclecarryingdemountabletanks.Thefollowingparticularsshallbeinscribedeitheronthetank-containeritselforonaplate(1):—namesofownerandofoperator,—capacityoftheshell,—tare,—maximumpermissibleladenmass,—propershippingnameofsubstancecarried(2),—tankcodeaccordingto4.3.4.1.1.6.8.2.6.Requirementsfortankswhicharedesigned,constructedandtestedaccordingtostandards(Reserved)6.8.2.7.Requirementsfortankswhicharenotdesigned,constructedandtestedaccordingtostandardsTankswhicharenotdesigned,constructedandtestedinaccordancewiththestandardssetoutin6.8.2.6shallbedesigned,constructedandtestedinaccordancewiththerequirementsofatechnicalcoderecognisedbythecompetentauthority.Theyshall,however,complywiththeminimumrequirementsof6.8.2.6.8.3.SpecialrequirementsapplicabletoClass26.8.3.1.Constructionofshells6.8.3.1.1.Shellsintendedforthecarriageofcompressedorliquefiedgasesorgasesdissolvedunderpressureshallbemadeofsteel.Inthecaseofweldlessshells,byderogationfrom6.8.2.1.12aminimumelongationatfractureof14%andalsoastresslowerthanorequaltolimitshereaftergivenaccordingtothematerialmaybeaccepted:(a)whentheratioRe/Rm(oftheminimumguaranteedcharacteristicsafterheattreatment)ishigherthan0,66withoutexceeding0,85:σ≤0,75Re;(b)whentheratioRe/Rm(oftheminimumguaranteedcharacteristicsafterheattreatment)ishigherthan0,85:σ≤0,5Rm.6.8.3.1.2.Therequirementsof6.8.5applytothematerialsandconstructionofweldedshells.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/866(1)Addtheunitsofmeasurementafterthenumericalvalues.(2)Acollectivedescriptioncoveringagroupofsubstancesofasimilarnatureandequallycompatiblewiththecharacteristicsofthetankmaybegiveninsteadofthename.6.8.3.1.3.(Reserved)Constructionofbattery-vehiclesandMEGCs6.8.3.1.4.Cylinders,tubes,pressuredrumsandbundlesofcylinders,aselementsofabattery-vehicleorMEGC,shallbeconstructedinaccordancewithChapter6.2.NOTE1.Bundlesofcylinderswhicharenotelementsofabattery-vehicleorofaMEGCshallbesubjecttotherequirementsofChapter6.2.2.Tanksaselementsofbattery-vehiclesandMEGCsshallbeconstructedinaccordancewith6.8.2.1and6.8.3.1.3.Demountabletanks(1)arenottobeconsideredelementsofbattery-vehiclesorMEGCs.6.8.3.1.5.Elementsandtheirfasteningsshallbecapableofabsorbingunderthemaximumpermissibleloadtheforcesdefinedin6.8.2.1.2.Undereachforcethestressatthemostseverelystressedpointoftheelementanditsfasteningsshallnotexceedthevaluedefinedin6.2.3.1forcylinders,tubes,pressuredrumsandbundlesofcylindersandfortanksthevalueofdefinedin6.8.2.1.16.6.8.3.2.Itemsofequipment6.8.3.2.1.Thedischargepipesoftanksshallbecapableofbeingclosedbyblankflangesorsomeotherequallyreliabledevice.Fortanksintendedforthecarriageofrefrigeratedliquefiedgases,theseblankflangesorotherequallyreliabledevicesmaybefittedwithpressure-releaseopeningsofamaximumdiameterof1,5mm.6.8.3.2.2.Shellsintendedforthecarriageofliquefiedgasesmaybeprovidedwith,inadditiontotheopeningsprescribedin6.8.2.2.2and6.8.2.2.4,openingsforthefittingofgauges,thermometers,manometersandwithbleedholes,asrequiredfortheiroperationandsafety.6.8.3.2.3.Fillinganddischargeopeningsoftankswithacapacitygreaterthan1m3intendedforthecarriageofliquefiedflammableand/ortoxicgasesshallbeequippedwithaninstant-closinginternalsafetydevicewhichclosesautomaticallyintheeventofanunintendedmovementoftheshelloroffire.Itshallalsobepossibletooperatetheclosingdevicebyremotecontrol.6.8.3.2.4.Allopenings,otherthanthoseaccommodatingsafetyvalvesandclosedbleedholes,oftanksintendedforthecarriageofliquefiedflammableand/ortoxicgasesshall,iftheirnominaldiameterismorethan1,5mm,shallbeequippedwithaninternalshut-offdevice.6.8.3.2.5.Notwithstandingtherequirementsof6.8.2.2.2,6.8.3.2.3and6.8.3.2.4,tanksintendedforthecarriageofrefrigeratedliquefiedgasesmaybeequippedwithexternaldevicesinplaceofinternaldevicesiftheexternaldevicesaffordprotectionagainstexternaldamageatleastequivalenttothataffordedbythewalloftheshell.6.8.3.2.6.Ifthetanksareequippedwithgaugesindirectcontactwiththesubstancecarried,thegaugesshallnotbemadeofatransparentmaterial.Iftherearethermometers,theyshallnotprojectdirectlyintothegasorliquidthroughtheshell.6.8.3.2.7.Fillinganddischargeopeningssituatedintheupperpartoftanksshallbeequippedwith,inadditiontowhatisprescribedin6.8.3.2.3,asecond,external,closingdevice.Thisdeviceshallbecapableofbeingclosedbyablankflangeorsomeotherequallyreliabledevice.6.8.3.2.8.Safetyvalvesshallmeettherequirementsof6.8.3.2.9to6.8.3.2.12below.6.8.3.2.9.Tanksintendedforthecarriageofcompressedorliquefiedgasesorgasesdissolvedunderpressure,maybefittedwithnotmorethantwosafetyvalveswhoseaggregateclearcross-sectionalareaofpassageattheseatingorseatingsshallbenotlessthan20cm2per30m3orpartthereofoftheshell'scapacity.Thesevalvesshallbecapableofopeningautomaticallyunderapressurebetween0,9and1,0timesthetestpressureofthetanktowhichtheyarefitted.Theyshallbeofsuchatypeastoresistdynamicstresses,includingliquidsurge.Theuseofdeadweightorcounterweightvalvesisprohibited.6.8.3.2.10.Wheretanksareintendedforcarriagebysea,therequirementsof6.8.3.2.9shallnotprohibitthefittingofsafetyvalvesconformingtotheIMDGcode.6.8.3.2.11.Tanksintendedforthecarriageofrefrigeratedliquefiedgasesshallbeequippedwithtwoindependentsafetyvalves,eachsodesignedastoallowthegasesformedbyevaporationduringnormaloperationtoescapefromthetankinsuchawaythatthepressuredoesnotatanytimeexceedbymorethan10%theworkingpressureindicatedonthetank.Oneofthetwosafetyvalvesmaybereplacedbyaburstingdiscwhichshallbesuchastoburstatthetestpressure.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/867(1)Forthedefinitionof‘demountabletank’see1.2.1.Intheeventoflossofthevacuuminadouble-walledtank,orofdestructionof20%oftheinsulationofasingle-walledtank,thesafetyvalveandtheburstingdiscshallpermitanoutflowsuchthatthepressureintheshellcannotexceedthetestpressure.6.8.3.2.12.Thesafetyvalvesoftanksintendedforthecarriageofrefrigeratedliquefiedgasesshallbecapableofopeningattheworkingpressureindicatedonthetank.Theyshallbesodesignedastofunctionfaultlesslyevenattheirlowestworkingtemperature.Thereliabilityoftheiroperationatthattemperatureshallbeestablishedandcheckedeitherbytestingeachvalveorbytestingaspecimenvalveofeachdesign-type.6.8.3.2.13.Thevalvesofdemountabletanksthatcanberolledshallbeprovidedwithprotectivecaps.Thermalinsulation6.8.3.2.14.Iftanksintendedforthecarriageofliquefiedgasesareequippedwiththermalinsulation,suchinsulationshallconsistofeither:—asunshieldcoveringnotlessthantheupperthirdbutnotmorethantheupperhalfofthetanksurfaceandseparatedfromtheshellbyanairspaceatleast4cmacross,or—acompletecladding,ofadequatethickness,ofinsulatingmaterials.6.8.3.2.15.Tanksintendedforthecarriageofrefrigeratedliquefiedgasesshallbethermallyinsulated.Thermalinsulationshallbeensuredbymeansofacontinuoussheathing.Ifthespacebetweentheshellandthesheathingisundervacuum(vacuuminsulation),theprotectivesheathingshallbesodesignedastowithstandwithoutdeformationanexternalpressureofatleast100kPa(1bar)(gaugepressure).Byderogationfromthedefinitionof‘calculationpressure’in1.2.1,externalandinternalreinforcingdevicesmaybetakenintoaccountinthecalculations.Ifthesheathingissoclosedastobegas-tight,adeviceshallbeprovidedtopreventanydangerouspressurefromdevelopingintheinsulatinglayerintheeventofinadequategas-tightnessoftheshellorofitsitemsofequipment.Thedeviceshallpreventtheinfiltrationofmoistureintotheheat-insulatingsheath.6.8.3.2.16.Tanksintendedforthecarriageofliquefiedgaseshavingaboilingpointbelow–182ºCatatmosphericpressureshallnotincludeanycombustiblematerialeitherinthethermalinsulationorinthemeansofattachment.Themeansofattachmentforvacuuminsulatedtanksmay,withtheapprovalofthecompetentauthority,containplasticssubstancesbetweentheshellandthesheathing.6.8.3.2.17.Byderogationfromtherequirementsof6.8.2.2.4shellsintendedforthecarriageofrefrigeratedliquefiedgasesneednothaveaninspectionopening.Itemsofequipmentforbattery-vehiclesandMEGCs6.8.3.2.18.Themanifoldshallbedesignedforserviceinatemperaturerangeof–20ºCto+50ºCThemanifoldshallbedesigned,constructedandinstalledsoastoavoidtheriskofdamageduetothermalexpansionandcontraction,mechanicalshockandvibration.Allpipingshallbeofsuitablemetallicmaterial.Weldedpipejointsshallbeusedwhereverpossible.Jointsincoppertubingshallbebrazedorhaveanequallystrongmetalunion.Themeltingpointofbrazingmaterialsshallbenolowerthan525ºC.Thejointsshallnotdecreasethestrengthoftubingasmayhappenwhencuttingthreads.6.8.3.2.19.ExceptforUNNo1001acetylene,dissolved,thepermissiblemaximumstressofthemanifoldingarrangementatthetestpressureofthereceptaclesshallnotexceed75%oftheguaranteedyieldstrengthofthematerial.ThenecessarywallthicknessofthemanifoldingarrangementforthecarriageofUNNo1001acetylene,dissolvedshallbecalculatedaccordingtoanapprovedcodeofpractice.NOTEFortheyieldstrength,see6.8.2.1.11.Thebasicrequirementsofthisparagraphshallbedeemedtohavebeencompliedwithifthefollowingstandardsareapplied:(Reserved).6.8.3.2.20.Byderogationfromtherequirementsof6.8.3.2.3,6.8.3.2.4and6.8.3.2.7,forcylinders,tubes,pressuredrumsandbundlesofcylinders(frames)formingabattery-vehicleorMEGC,therequiredclosingdevicesmaybeprovidedforwithinthemanifoldingarrangement.6.8.3.2.21.Ifoneoftheelementsisequippedwithasafetyvalveandshut-offdevicesareprovidedbetweentheelements,everyelementshallbesoequipped.6.8.3.2.22.Thefillinganddischargedevicesmaybeaffixedtoamanifold.6.8.3.2.23.Eachelement,includingeachindividualcylinderofabundle,intendedforthecarriageoftoxicgases,shallbecapableofbeingisolatedbyashut-offvalve.6.8.3.2.24.Battery-vehiclesorMEGCsintendedforthecarriageoftoxicgasesshallnothavesafetyvalves,unlessthesafetyvalvesareprecededbyaburstingdisc.Inthelattercase,thearrangementoftheburstingdiscandsafetyvalveshallbesatisfactorytothecompetentauthority.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8686.8.3.2.25.Whenbattery-vehiclesorMEGCsareintendedforcarriagebysea,therequirementsof6.8.3.2.24shallnotprohibitthefittingofsafetyvalvesconformingtotheIMDGcode.6.8.3.2.26.Receptacleswhichareelementsofabattery-vehicleorMEGCintendedforthecarriageofflammablegasesshallbecombinedingroupsofnotmorethan5000litreswhicharecapableofbeingisolatedbyashut-offvalve.Eachelementofabattery-vehicleorMEGCintendedforthecarriageofflammablegases,whenconsistingoftanksconformingtothischapter,shallbecapableofbeingisolatedbyashut-offvalve.6.8.3.3.Type-approvalNospecialrequirements.6.8.3.4.Inspectionsandtests6.8.3.4.1.Thematerialsofeveryweldedshellwiththeexceptionofcylinders,tubes,pressuredrumsandcylindersaspartofbundlesofcylinderswhichareelementsofabattery-vehicleorofaMEGCshallbetestedaccordingtothemethoddescribedin6.8.5.6.8.3.4.2.Thebasicrequirementsforthetestpressurearegivenin4.3.3.2.1to4.3.3.2.4andtheminimumtestpressuresaregiveninthetableofgasesandgasmixturesin4.3.3.2.5.6.8.3.4.3.Thefirsthydraulicpressuretestshallbecarriedoutbeforethermalinsulationisplacedinposition.6.8.3.4.4.Thecapacityofeachshellintendedforthecarriageofcompressedgasesfilledbymass,liquefiedgasesorgasesdissolvedunderpressureshallbedetermined,underthesupervisionofanexpertapprovedbythecompetentauthority,byweighingorvolumetricmeasurementofthequantityofwaterwhichfillstheshell;themeasurementofshellcapacityshallbeaccuratetowithin1%.Determinationbyacalculationbasedonthedimensionsoftheshellisnotpermitted.ThemaximumfillingmassesallowedinaccordancewithpackinginstructionP200orP203in4.1.4.1aswellas4.3.3.2.2and4.3.3.2.3shallbeprescribedbyanapprovedexpert.6.8.3.4.5.Checkingoftheweldsshallbecarriedoutinaccordancewiththeλ=1requirementsof6.8.2.1.23.6.8.3.4.6.Byderogationfromtherequirementsof6.8.2.4,theperiodicinspections,includingthehydraulicpressuretest,shalltakeplace:a)everythreeyearseverytwoandahalfyearsinthecaseoftanksintendedforthecarriageofUNNo1008borontrifluoride,UNNo1017chlorine,UNNo1048hydrogenbromide,anhydrous,UNNo1050hydrogenchloride,anhydrous,UNNo1053hydrogensulphide,UNNo1067dinitrogentetroxide(nitrogendioxide),UNNo1076phosgeneorUNNo1079sulphurdioxide;b)aftersixyearsaftereightyearsofserviceandthereafterevery12yearsinthecaseoftanksintendedforthecarriageofrefrigeratedliquefiedgases.Aleakproofnesstestshallbeperformedbyanapprovedexpertsixyearsaftereachperiodicinspection.Aleakproofnesstestmaybeperformed,attherequestofthecompetentauthority,betweenanytwosuccessiveinspections.6.8.3.4.7.Inthecaseofvacuum-insulatedtanks,thehydraulic-pressuretestandthecheckoftheinternalconditionmay,withtheconsentoftheapprovedexpert,bereplacedbyaleakproofnesstestandmeasurementofthevacuum.6.8.3.4.8.If,atthetimeofperiodicinspections,openingshavebeenmadeinshellsintendedforthecarriageofrefrigeratedliquefiedgases,themethodbywhichtheyarehermeticallyclosedbeforetheshellsarereturnedtoserviceshallbeapprovedbytheapprovedexpertandshallensuretheintegrityoftheshell.6.8.3.4.9.Leakproofnesstestsoftanksintendedforthecarriageofcompressed,liquefiedgasesorgasesdissolvedunderpressureshallbeperformedatapressureofnotlessthan0,4MPa(4bar)andnotmorethan0,8MPa(8bar)(gaugepressure).Inspectionsandtestsforbattery-vehiclesandMEGCs6.8.3.4.10.Theelementsanditemsofequipmentofeachbattery-vehicleorMEGCshallbeinspectedandtestedeithertogetherorseparatelybeforebeingputintoserviceforthefirsttime(initialinspectionandtest).Thereafterbattery-vehiclesorMEGCstheelementsofwhicharereceptaclesshallbeinspectedatnotmorethanfive-yearintervals.Battery-vehiclesandMEGCstheelementsofwhicharetanksshallbeinspectedaccordingto6.8.3.4.6.Anexceptionalinspectionandtestshallbeperformedregardlessofthelastperiodicinspectionandtestwhennecessaryaccordingto6.8.3.4.14.6.8.3.4.11.Theinitialinspectionshallinclude:—acheckofconformitywiththeapprovedtype,OfficialJournaloftheEuropeanUnionEN26.1.2004L18/869—acheckofthedesigncharacteristics,—anexaminationoftheinternalandexternalconditions,—ahydraulicpressuretest(1)atthetestpressureindicatedontheplateprescribedin6.8.3.5.10,—aleakproofnesstestatthemaximumworkingpressure,and—acheckofsatisfactoryoperationoftheequipment.Whentheelementsandtheirfittingshavebeenpressure-testedseparately,theyshallbesubjectedtogetherafterassemblytoaleakproofnesstest.6.8.3.4.12.Cylinders,tubesandpressuredrumsandcylindersaspartofbundlesofcylindersshallbetestedaccordingtopackinginstructionP200orP203in4.1.4.1.Thetestpressureofthemanifoldofthebattery-vehicleorMEGCshallbethesameasthatoftheelementsofthebattery-vehicleorMEGC.Thepressuretestofthemanifoldmaybeperformedasahydraulictestorbyusinganotherliquidorgaswiththeagreementofthecompetentauthorityoritsauthorisedbody.Byderogationfromthisrequirement,thetestpressureforthemanifoldofbattery-vehicleorMEGCshallnotbelessthan300barforUNNo1001acetylene,dissolved.6.8.3.4.13.Theperiodicinspectionshallincludealeakproofnesstestatthemaximumworkingpressureandanexternalexaminationofthestructure,theelementsandtheserviceequipmentwithoutdisassembling.TheelementsandthepipingshallbetestedattheperiodicitydefinedinpackinginstructionP200of4.1.4.1andinaccordancewiththerequirementsof6.2.1.5.Whentheelementsandequipmenthavebeenpressure-testedseparately,theyshallbesubjectedtogetherafterassemblytoaleakproofnesstest.6.8.3.4.14.Anexceptionalinspectionandtestisnecessarywhenthebattery-vehicleorMEGCshowsevidenceofdamagedorcorrodedareas,orleakage,oranyotherconditions,thatindicateadeficiencythatcouldaffecttheintegrityofthebattery-vehicleorMEGC.Theextentoftheexceptionalinspectionandtestand,ifdeemednecessary,thedisassemblingofelementsshalldependontheamountofdamageordeteriorationofthebattery-vehicleorMEGC.Itshallincludeatleasttheexaminationsrequiredunder6.8.3.4.15.6.8.3.4.15.Theexaminationsshallensurethat:(a)theelementsareinspectedexternallyforpitting,corrosion,orabrasions,dents,distortions,defectsinweldsoranyotherconditions,includingleakage,thatmightrenderthebattery-vehiclesorMEGCsunsafefortransport,(b)thepiping,valves,andgasketsareinspectedforcorrodedareas,defects,andotherconditions,includingleakage,thatmightrenderbattery-vehiclesorMEGCsunsafeforfilling,dischargeortransport,(c)missingorlooseboltsornutsonanyflangedconnectionorblankflangearereplacedortightened,(d)allemergencydevicesandvalvesarefreefromcorrosion,distortionandanydamageordefectthatcouldpreventtheirnormaloperation.Remoteclosuredevicesandself-closingstop-valvesshallbeoperatedtodemonstrateproperoperation,(e)requiredmarkingsonthebattery-vehiclesorMEGCsarelegibleandinaccordancewiththeapplicablerequirements,and(f)anyframework,supportsandarrangementsforliftingthebattery-vehiclesorMEGCsareinsatisfactorycondition.6.8.3.4.16.Thetests,inspectionsandchecksinaccordancewith6.8.3.4.10to6.8.3.4.15shallbecarriedoutbytheexpertapprovedbythecompetentauthority.Certificatesshallbeissuedshowingtheresultsoftheseoperations.Thesecertificatesshallrefertothelistofthesubstancespermittedforcarriageinthisbattery-vehicleorMEGCinaccordancewith6.8.2.3.1.6.8.3.5.Marking6.8.3.5.1.Thefollowingadditionalparticularsshallbemarkedbystampingorbyanyothersimilarmethodontheplateprescribedin6.8.2.5.1,ordirectlyonthewallsoftheshellitselfifthewallsaresoreinforcedthatthestrengthofthetankisnotimpaired.6.8.3.5.2.Ontanksintendedforthecarriageofonlyonesubstance:—thepropershippingnameofthegasand,inadditionforgasesclassifiedunderann.o.s.entry,thetechnicalname(2).OfficialJournaloftheEuropeanUnionEN26.1.2004L18/870(1)Inspecialcasesandwiththeagreementoftheexpertapprovedbythecompetentauthority,thehydraulicpressuretestmaybereplacedbyapressuretestusinganotherliquidorgas,wheresuchanoperationdoesnotpresentanydanger.(2)Insteadofthepropershippingnameofthen.o.s.entryfollowedbythetechnicalname,theuseofoneofthefollowingnamesispermitted:—forUNNo1078refrigerantgas,n.o.s.:mixtureF1,mixtureF2,mixtureF3,—forUNNo1060methylacetyleneandpropadienemixtures,stabilised:mixtureP1,mixtureP2,—forUNNo1965hydrocarbongasmixture,liquefied,n.o.s.:mixtureA,mixtureA01,mixtureA02,mixtureA0,mixtureA1,mixtureB1,mixtureB2,mixtureB,mixtureC.Thenamescustomaryinthetradeandmentionedin2.2.2.3,Classificationcode2F,UNNo1965,Note1maybeusedonlyasacomplement.Thisindicationshallbesupplemented:—inthecaseoftanksintendedforthecarriageofcompressedgasesfilledbyvolume(pressure),byanindicationofthemaximumfillingpressureat15°Cpermittedforthetank;and—inthecaseoftanksintendedforthecarriageofcompressedgasesfilledbymass,andofliquefiedgases,refrigeratedliquefiedgasesorgasesdissolvedunderpressurebyanindicationofthemaximumpermissibleloadmassinkgandofthefillingtemperatureifbelow–20°C.6.8.3.5.3.Onmultipurposetanks:—thepropershippingnamesofthegasesand,inadditionforgasesclassifiedunderann.o.s.entry,thetechnicalnameofthegases(1)forwhosecarriagethetankisapproved.Theseparticularsshallbesupplementedbyanindicationofthemaximumpermissibleloadmassinkgforeachgas.6.8.3.5.4.Ontanksintendedforthecarriageofrefrigeratedliquefiedgases:—themaximumworkingpressureallowed.6.8.3.5.5.Ontanksequippedwiththermalinsulation:—theinscription‘thermallyinsulated’or‘thermallyinsulatedbyvacuum’.6.8.3.5.6.Inadditiontotheparticularsprescribedin6.8.2.5.2,thefollowingshallbeinscribedonthetankitselforonaplate:thetank-containeritselforonaplate:a)—thetankcodeaccordingtothecertificate(see6.8.2.3.1)withtheactualtestpressureofthetank,—theinscription:‘minimumfillingtemperatureallowed:…’;(b)wherethetankisintendedforthecarriageofonesubstanceonly:—thepropershippingnameofthegasand,inadditionforgasesclassifiedunderann.o.s.entry,thetechnicalname(1);—forcompressedgaseswhicharefilledbymass,andforliquefiedgases,refrigeratedliquefiedgasesorgasesdissolvedunderpressure,themaximumpermissibleloadmassinkg;(c)wherethetankisamultipurposetank:—thepropershippingnameofthegasand,forgasesclassifiedunderann.o.s.entry,thetechnicalname(1)ofallgasestowhosecarriagethetankisassignedwithanindicationofthemaximumpermissibleloadmassinkgforeachofthem;(d)wheretheshellisequippedwiththermalinsulation:—theinscription‘thermallyinsulated’(or‘thermallyinsulatedbyvacuum’),inanofficiallanguageofthecountryofregistrationandalso,ifthatlanguageisnotEnglish,FrenchorGerman,inEnglish,FrenchorGerman,unlessanyagreementsconcludedbetweenthecountriesconcernedinthetransportoperationprovideotherwise.6.8.3.5.7.(Reserved)6.8.3.5.8.Theseparticularsshallnotberequiredinthecaseofavehiclecarryingdemountabletanks.6.8.3.5.9.(Reserved)OfficialJournaloftheEuropeanUnionEN26.1.2004L18/871(1)Insteadofthepropershippingnameofthen.o.s.entryfollowedbythetechnicalname,theuseofoneofthefollowingnamesispermitted:—forUNNo1078refrigerantgas,n.o.s.:mixtureF1,mixtureF2,mixtureF3,—forUNNo1060methylacetyleneandpropadienemixtures,stabilised:mixtureP1,mixtureP2,—forUNNo1965hydrocarbongasmixture,liquefied,n.o.s.:mixtureA,mixtureA01,mixtureA02,mixtureA0,mixtureA1,mixtureB1,mixtureB2,mixtureB,mixtureC.Thenamescustomaryinthetradeandmentionedin2.2.2.3,Classificationcode2F,UNNo1965,Note1maybeusedonlyasacomplement.Markingofbattery-vehiclesandMEGCs6.8.3.5.10.Everybattery-vehicleandeveryMEGCshallbefittedwithacorrosion-resistantmetalplatepermanentlyattachedinaplacereadilyaccessibleforinspection.Thefollowingparticularsatleastshallbemarkedontheplatebystampingorbyanyothersimilarmethod(1):—approvalnumber,—manufacturer'snameormark,—manufacturer'sserialnumber,—yearofmanufacture,—testpressure(gaugepressure),—designtemperature(onlyifabove+50°Corbelow–20°C),—date(monthandyear)ofinitialtestandmostrecentperiodictestinaccordancewith6.8.3.4.10to6.8.3.4.13,—stampoftheexpertwhocarriedoutthetests.6.8.3.5.11.Thefollowingparticularsshallbeinscribedonthebattery-vehicleitselforonaplate(1):—namesofownerorofoperator,—numberofelements,—totalcapacityoftheelements,andforbattery-vehiclesfilledbymass:—unladenmass,—maximumpermissiblemass.ThefollowingparticularsshallbeinscribedeitherontheMEGCitselforonaplate(1):—namesofownerandofoperator,—numberofelements,—totalcapacityoftheelements,—maximumpermissibleladenmass,—propershippingnameofsubstancecarried(2);andforMEGCsfilledbymass:—tare.6.8.3.5.12.Theframeofabattery-vehicleorMEGCshallbearnearthefillingpointaplatespecifying:—themaximumfillingpressure(1)at15°Callowedforelementsintendedforcompressedgases,—thepropershippingnameofthegasinaccordancewithChapter3.2and,inadditionforgasesclassifiedunderann.o.s.entry,thetechnicalname(3),and,inaddition,inthecaseofliquefiedgases:—thepermissiblemaximumloadperelement(1).6.8.3.5.13.Cylinders,tubesandpressuredrums,andcylindersaspartofbundlesofcylinders,shallbemarkedaccordingto6.2.1.7.ThesereceptaclesneednotbelabelledindividuallywiththedangerlabelsasrequiredinChapter5.2.Battery-vehiclesandMEGCsshallbeplacardedandmarkedaccordingtoChapter5.3.6.8.3.6.Requirementsforbattery-vehiclesandMEGCswhicharedesigned,constructedandtestedaccordingtostandards(Reserved)6.8.3.7.Requirementsforbattery-vehiclesandMEGCswhicharenotdesigned,constructedandtestedaccordingtostandardsBattery-vehiclesandMEGCswhicharenotdesigned,constructedandtestedinaccordancewiththestandardssetoutin6.8.3.6shallbedesigned,constructedandtestedinaccordancewiththerequirementsofatechnicalcoderecognisedbythecompetentauthority.Theyshall,however,complywiththeminimumrequirementsof6.8.3.6.8.4.SpecialprovisionsNOTE1.Forliquidshavingaflash-pointofnotmorethan61°Candforflammablegases,seealso6.8.2.1.26,6.8.2.1.27and6.8.2.2.9.2.Forrequirementsfortankssubjectedtoapressuretestofnotlessthan1MPa(10bar)orfortanksintendedforthecarriageofrefrigeratedliquefiedgases,see6.8.5.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/872(1)Addtheunitsofmeasurementsafterthenumericalvalues.(2)Acollectivedescriptioncoveringagroupofsubstancesofasimilarnatureandequallycompatiblewiththecharacteristicsofthetankmaybegiveninsteadofthename.(3)Insteadofthepropershippingnameofthen.o.s.entryfollowedbythetechnicalname,theuseofoneofthefollowingnamesispermitted:—forUNNo1078refrigerantgas,n.o.s.:mixtureF1,mixtureF2,mixtureF3,—forUNNo1060methylacetyleneandpropadienemixtures,stabilised:mixtureP1,mixtureP2,—forUNNo1965hydrocarbongasmixture,liquefied,n.o.s.:mixtureA,mixtureA01,mixtureA02,mixtureA0,mixtureA1,mixtureB1,mixtureB2,mixtureB,mixtureC.Thenamescustomaryinthetradeandmentionedin2.2.2.3,Classificationcode2F,UNNo1965,Note1maybeusedonlyasacomplement.Whentheyareshownunderanentryincolumn13ofTableAofChapter3.2,thefollowingspecialprovisionsapply:(a)Construction(TC)TC1Therequirementsof6.8.5areapplicabletothematerialsandconstructionoftheseshells.TC2Shells,andtheiritemsofequipment,shallbemadeofaluminiumnotlessthan99,5%pureorofsuitablesteelnotliabletocausehydrogenperoxidetodecompose.Whereshellsaremadeofaluminiumnotlessthan99,5%pure,thewallthicknessneednotexceed15mm,evenwherecalculationinaccordancewith6.8.2.1.17givesahighervalue.TC3Theshellsshallbemadeofausteniticsteel.TC4ShellsshallbeprovidedwithanenamelorequivalentprotectiveliningifthematerialoftheshellisattackedbyUNNo3250chloroaceticacid.TC5Shellsshallbeprovidedwithaleadliningnotlessthan5mmthickoranequivalentlining.TC6Wheretheuseofaluminiumisnecessaryfortanks,suchtanksshallbemadeofaluminiumnotlessthan99,5%pure;thewallthicknessneednotexceed15mmevenwherecalculationinaccordancewith6.8.2.1.17givesahighervalue.TC7Theeffectiveminimumthicknessoftheshellshallnotbelessthan3mm.(b)Itemsofequipment(TE)TE1Iftanks,battery-vehiclesorMEGCsarefittedwithsafetyvalves,aburstingdiscshallbeplacedbeforethevalves.Thearrangementoftheburstingdiscandsafetyvalveshallbesuchastosatisfythecompetentauthority.Apressuregaugeoranothersuitableindicatorshallbeprovidedinthespacebetweentheburstingdiscandthesafetyvalve,toenabledetectionofanyrupture,perforationorleakageofthediscwhichmaydisrupttheactionofthesafetyvalve.TE2Thebottomdischargesystemoftanksmayconsistofanexternalpipewithastop-valve,ifitisconstructedinametallicmaterialliabletodeformation.TE3Tanksshallinadditionmeetthefollowingrequirements.Theheatingdeviceshallnotpenetrateinto,butshallbeexteriortotheshell.However,apipeusedforextractingthephosphorusmaybeequippedwithaheatingjacket.Thedeviceheatingthejacketshallbesoregulatedastopreventthetemperatureofthephosphorusfromexceedingthefillingtemperatureoftheshell.Otherpipingshallentertheshellinitsupperpart;openingsshallbesituatedabovethehighestpermissiblelevelofthephosphorusandbecapableofbeingcompletelyenclosedunderlockablecaps.Thetankshallbeequippedwithagaugingsystemforverifyingthelevelofthephosphorusand,ifwaterisusedasaprotectiveagent,withafixedgaugemarkshowingthehighestpermissiblelevelofthewater.TE4Shellsshallbeequippedwiththermalinsulationmadeofmaterialswhicharenotreadilyflammable.TE5Ifshellsareequippedwiththermalinsulation,suchinsulationshallbemadeofmaterialswhicharenotreadilyflammable.TE6Tanksmaybeequippedwithvalvesopeningautomaticallyinwardsoroutwardsundertheeffectofadifferenceofpressureofbetween20kPaand30kPa(0,2barand0,3bar).TE7Theshell-dischargesystemshallbeequippedwithtwomutuallyindependentshut-offdevicesmountedinseries,thefirsttakingtheformofaquick-closinginternalstop-valveofanapprovedtypeandthesecondthatofanexternalstop-valve,oneateachendofthedischargepipe.Ablankflange,oranotherdeviceprovidingthesamemeasureofsecurity,shallalsobefittedattheoutletofeachexternalstop-valve.Theinternalstop-valveshallbesuchthatifthepipeiswrenchedoffthestop-valvewillremainintegralwiththeshellandintheclosedposition.TE8Theconnectionstotheexternalpipe-socketsoftanksshallbemadeofmaterialsnotliabletocausedecompositionofhydrogenperoxide.TE9Tanksshallbefittedintheirupperpartwithashut-offdevicepreventinganybuild-upofexcesspressureinsidetheshellduetothedecompositionofthesubstancescarried,anyleakageofliquid,andanyentryofforeignmatterintotheshell.TE10Theshut-offdevicesoftanksshallbesodesignedastoprecludeobstructionofthedevicesbysolidifiedammoniumnitrateduringcarriage.Wheretanksaresheathedinthermally-insulatingmaterial,thematerialshallbeofaninorganicnatureandentirelyfreefromcombustiblematter.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/873TE11Shellsandtheirserviceequipmentshallbesodesignedastopreventtheentryofforeignmatter,leakageofliquidoranybuildingupofdangerousexcesspressureinsidetheshellduetothedecompositionofthesubstancescarried.TE12Tanksshallbeequippedwiththermalinsulationcomplyingwiththerequirementsof6.8.3.2.14.IftheSADToftheorganicperoxideinthetankis55°Corless,orthetankisconstructedofaluminium,theshellshallbecompletelyinsulated.Thesunshieldandanypartofthetanknotcoveredbyit,ortheoutersheathingofacompletelagging,shallbepaintedwhiteorfinishedinbrightmetal.Thepaintshallbecleanedbeforeeachtransportjourneyandrenewedincaseofyellowingordeterioration.Thethermalinsulationshallbefreefromcombustiblematter.Tanksshallbefittedwithtemperaturesensingdevices.Tanksshallbefittedwithsafetyvalvesandemergencypressure-reliefdevices.Vacuum-reliefdevicesmayalsobeused.Emergencypressure-reliefdevicesshalloperateatpressuresdeterminedaccordingtoboththepropertiesoftheorganicperoxideandtheconstructioncharacteristicsofthetank.Fusibleelementsshallnotbepermittedinthebodyoftheshell.Tanksshallbefittedwithspring-loadedsafetyvalvestopreventsignificantpressurebuild-upwithintheshellofthedecompositionproductsandvapoursreleasedatatemperatureof50°C.Thecapacityandstart-to-dischargepressureofthesafety-valve(s)shallbebasedontheresultsofthetestsspecifiedinspecialprovisionTA2.Thestart-to-dischargepressureshallhoweverinnocasebesuchthatliquidcouldescapefromthevalve(s)ifthetankwereoverturned.Theemergency-reliefdevicesmaybeofthespring-loadedorfrangibletypesdesignedtoventallthedecompositionproductsandvapoursevolvedduringaperiodofnotlessthanonehourofcompletefire-engulfmentascalculatedbythefollowingformula:q=70961×F×A0,82where:q=heatabsorption[W]A=wettedarea[m2]F=insulationfactorF=1fornon-insulatedtanks,orF=U923–TPOðÞ47032forinsulatedtankswhere:K=heatconductivityofinsulationlayer[W·m–1·K–1]L=thicknessofinsulationlayer[m]U=K/L=heattransfercoefficientoftheinsulation[W·m–2·K–1]TPO=temperatureofperoxideatrelievingconditions[K]Thestart-to-dischargepressureoftheemergency-reliefdevice(s)shallbehigherthanthatabovespecifiedandbasedontheresultsofthetestsreferredtoinspecialprovisionTA2.Theemergency-reliefdevicesshallbedimensionedinsuchawaythatthemaximumpressureinthetankneverexceedsthetestpressureofthetank.NOTEAnexampleofamethodtodeterminethesizeofemergency-reliefdevicesisgiveninAppendix5oftheManualoftestsandcriteria.Fortanksequippedwiththermalinsulationconsistingofacompletecladding,thecapacityandsettingoftheemergency-reliefdevice(s)shallbedeterminedassumingalossofinsulationfrom1%ofthesurfacearea.Vacuum-reliefdevicesandspring-loadedsafetyvalvesoftanksshallbeprovidedwithflamearrestersunlessthesubstancestobecarriedandtheirdecompositionproductsarenon-combustible.Dueattentionshallbepaidtothereductionofthereliefcapacitycausedbytheflamearrester.TE13Tanksshallbethermallyinsulatedandfittedwithaheatingdeviceontheoutside.TE14Tanksshallbeequippedwiththermalinsulation.Theymayalsobeequippedwithpressure-releasedevicesopeningautomaticallyinwardsoroutwardsundertheeffectofadifferenceofpressureofbetween20kPaand30kPa(0,2barand0,3bar).Thethermalinsulationdirectlyincontactwiththeshellshallhaveanignitiontemperatureatleast50°Chigherthanthemaximumtemperatureforwhichthetankwasdesigned.TE15(Reserved)TE16(Reserved)TE17(Reserved)OfficialJournaloftheEuropeanUnionEN26.1.2004L18/874TE18Tanksintendedforthecarriageofsubstancesfilledatatemperaturehigherthan190ºCshallbeequippedwithdeflectorsplacedatrightanglestotheupperfillingopenings,soastoavoidasuddenlocalisedincreaseinwalltemperatureduringfilling.TE19Fittingsandaccessoriesmountedintheupperpartofthetankshallbeeither:—insertedinarecessedhousing,or—equippedwithaninternalsafetyvalve,or—shieldedbyacap,orbytransverseand/orlongitudinalmembers,orbyotherequallyeffectivedevices,soprofiledthatintheeventofoverturningthefittingsandaccessorieswillnotbedamaged.Fittingsandaccessoriesmountedinthelowerpartofthetank:Pipe-sockets,lateralshut-offdevices,andalldischargedevicesshalleitherberecessedbyatleast200mmfromtheextremeouteredgeofthetankorbeprotectedbyarailhavingacoefficientofinertiaofnotlessthan20cm3transversallytothedirectionoftravel;theirgroundclear-anceshallbenotlessthan300mmwiththetankfull.Fittingsandaccessoriesmountedontherearfaceofthetankshallbeprotectedbythebumperprescribedin9.7.6.TheirheightabovethegroundshallbesuchthattheyareadequatelyprotectedbythebumperTE20Notwithstandingtheothertank-codeswhicharepermittedinthehierarchyoftanksoftherationalisedapproachin4.3.4.1.2,tanksshallbeequippedwithasafetyvalve.(c)Typeapproval(TA)TA1Tanksshallnotbeapprovedforthecarriageoforganicsubstances.TA2Thissubstancemaybecarriedinfixedordemountabletanksortank-containersundertheconditionslaiddownbythecompetentauthorityofthecountryoforigin,if,onthebasisofthetestsmentionedbelow,thecompetentauthorityissatisfiedthatsuchatransportoperationcanbecarriedoutsafely.IfthecountryoforiginisnotaMemberState,theseconditionsshallberecognisedbythecompetentauthorityofthefirstMemberStatereachedbytheconsignment.Forthetype-approvaltestsshallbeundertaken:—toprovethecompatibilityofallmaterialsnormallyincontactwiththesubstanceduringcarriage,—toprovidedatatofacilitatethedesignoftheemergencypressure-reliefdevicesandsafetyvalvestakingintoaccountthedesigncharacteristicsofthetank,and—toestablishanyspecialrequirementsnecessaryforthesafecarriageofthesubstance.Thetestresultsshallbeincludedinthereportforthetype-approval.(d)Tests(TT)NOTETanksshallbesubjectedtotheinitialandperiodichydraulicpressuretestsatapressuredependingontheircalculationpressureatleastequaltothepressureindicatedbelow:Calculationpressure(bar)Testpressure(bar)G(1)G(1)1,51,52,652,6544104OfficialJournaloftheEuropeanUnionEN26.1.2004L18/875Calculationpressure(bar)Testpressure(bar)1542110(4(2))(1)G=minimumcalculationpressureaccordingtothegeneralrequirements6.8.2.1.14(see4.3.4.1).(2)MinimumtestpressureforUNNo1744bromineorUNNo1744brominesolution.TT1Tanksofpurealuminiumneedtobesubjectedtotheinitialandperiodichydraulicpressuretestsatapressureofonly250kPa(2,5bar)(gaugepressure).TT2Theconditionoftheliningofshellsshallbeinspectedeveryyearbyanexpertapprovedbythecompetentauthority,whoshallinspecttheinsideoftheshell.TT3Byderogationfromtherequirementsof6.8.2.4.2,periodicinspectionsshalltakeplaceatleasteveryeightyearsandshallincludeathicknesscheckusingsuitableinstruments.Forsuchtanks,theleakproofnesstestandcheckforwhichprovisionismadein6.8.2.4.3shallbecarriedoutatleasteveryfouryears.TT4(Reserved)TT5Thehydraulicpressuretestsshalltakeplaceatleasteverythreeyears.twoandahalfyears.TT6Theperiodictests,includingthehydraulicpressuretest,shallbecarriedoutatleasteverythreeyears.TT7Notwithstandingtherequirementsof6.8.2.4.2,theperiodicinternalinspectionmaybereplacedbyaprogrammeapprovedbythecompetentauthority.(e)Marking(TM)NOTETheseparticularsshallbeinanofficiallanguageofthecountryofapproval,andalso,ifthatlanguageisnotEnglish,FrenchorGerman,inEnglish,FrenchorGerman,unlessanyagreementsconcludedbetweenthecountriesconcernedinthetransportoperationprovideotherwise.TM1Tanksshallbearinadditiontotheparticularsprescribedin6.8.2.5.2,thewords:‘Donotopenduringcarriage.Liabletospontaneouscombustion’(seealsothenoteabove).TM2Tanksshallbearinadditiontotheparticularsprescribedin6.8.2.5.2,thewords:‘Donotopenduringcarriage.Givesoffflammablegasesoncontactwithwater’(seealsothenoteabove).TM3Tanksshallalsobear,ontheplateprescribedin6.8.2.5.1,thepropershippingnamesoftheapprovedsubstancesandthemaximumpermissibleloadofthetankinkg.TM4Fortanksthefollowingadditionalparticularsshallbemarkedbystampingorbyanyothersimilarmethodontheplateprescribedin6.8.2.5.2ordirectlyontheshellitself,ifthewallsaresoreinforcedthatthestrengthofthetankisnotimpaired:thechemicalnamewiththeapprovedconcentrationofthesubstanceconcerned.TM5Tanksshallbear,inadditiontotheparticularsreferredtoin6.8.2.5.1thedate(month,year)ofthemostrecentinspectionoftheinternalconditionoftheshell.TM6(Reserved)TM7Thetrefoilsymbol,asdescribedin5.2.1.7.6,shallbemarkedbystampingoranyotherequivalentmethodontheplatedescribedin6.8.2.5.1.Thistrefoilmaybeengraveddirectlyonthewallsoftheshellitself,ifthewallsaresoreinforcedthatthestrengthoftheshellisnotimpaired.6.8.5.Requirementsconcerningthematerialsandconstructionoffixedweldedtanks,demountableweldedtanks,andweldedshellsoftank-containersforwhichatestpressureofnotlessthan1MPa(10bar)isrequired,andoffixedweldedtanks,demountableweldedtanksandweldedshellsoftank-containersintendedforthecarriageofrefrigeratedliquefiedgasesofClass26.8.5.1.Materialsandshells6.8.5.1.1.(a)Shellsintendedforthecarriageof:—compressed,liquefiedgasesorgasesdissolvedunderpressureofClass2,OfficialJournaloftheEuropeanUnionEN26.1.2004L18/876—UNNos1366,1370,1380,2003,2005,2445,2845,2870,3049,3050,3051,3052,3053,3076,3194and3203ofClass4.2,and—UNNo1052hydrogenfluoride,anhydrousandUNNo1790hydrofluoricacidwithmorethan85%hydrogenfluorideofClass8shallbemadeofsteel.(b)Shellsconstructedoffine-grainedsteelsforthecarriageof:—corrosivegasesofClass2andUNNo2073ammoniasolution,and—UNNo1052hydrogenfluoride,anhydrousandUNNo1790hydrofluoricacidwithmorethan85%hydrogenfluorideofClass8shallbeheat-treatedforthermalstressrelief.(c)ShellsintendedforthecarriageofrefrigeratedliquefiedgasesofClass2,shallbemadeofsteel,aluminium,aluminiumalloy,copperorcopperalloy(e.g.brass).However,shellsmadeofcopperorcopperalloyshallbeallowedonlyforgasescontainingnoacetylene;ethylene,however,maycontainnotmorethan0,005%acetylene.(d)Onlymaterialsappropriatetothelowestandhighestworkingtemperaturesoftheshellsandoftheirfittingsandaccessoriesmaybeused.6.8.5.1.2.Thefollowingmaterialsshallbeallowedforthemanufactureofshells:(a)steelsnotsubjecttobrittlefractureatthelowestworkingtemperature(see6.8.5.2.1):—mildsteels(exceptforrefrigeratedliquefiedgasesofClass2),—fine-grainedsteels,downtoatemperatureof–60ºC,—nickelsteels(withanickelcontentof0,5to9%),downtoatemperatureof–196ºC,dependingonthenickelcontent,—austeniticchrome-nickelsteels,downtoatemperatureof–270ºC,(b)aluminiumnotlessthan99,5%pureoraluminiumalloys(see6.8.5.2.2),(c)deoxidisedcoppernotlessthan99,9%pure,orcopperalloyshavingacoppercontentofover56%(see6.8.5.2.3).6.8.5.1.3.a)Shellsmadeofsteel,aluminiumoraluminiumalloysshallbeeitherseamlessorwelded.(b)Shellsmadeofausteniticsteel,copperorcopperalloymaybehard-soldered.6.8.5.1.4.Thefittingsandaccessoriesmayeitherbescrewedtotheshellsorbesecuredtheretoasfollows:(a)shellsmadeofsteel,aluminiumoraluminiumalloy:bywelding;(b)shellsmadeofausteniticsteel,ofcopperorofcopperalloy:byweldingorhard-soldering.6.8.5.1.5.Theconstructionofshellsandtheirattachmenttothevehicle,totheunderframeorinthecontainerframeshallbesuchastoprecludewithcertaintyanysuchreductioninthetemperatureoftheload-bearingcomponentsaswouldbelikelytorenderthembrittle.Themeansofattachmentofshellsshallthemselvesbesodesignedthatevenwhentheshellisatitslowestworkingtemperaturetheystillpossessthenecessarymechanicalproperties.6.8.5.2.Testrequirements6.8.5.2.1.SteelshellsThematerialsusedforthemanufactureofshellsandtheweldbeadsshall,attheirlowestworkingtemperature,butatleastat–20ºC,meetatleastthefollowingrequirementsastoimpactstrength:—thetestsshallbecarriedoutwithtest-pieceshavingaV-shapednotch,—theminimumimpactstrength(see6.8.5.3.1to6.8.5.3.3)fortest-pieceswiththelongitudinalaxisatrightanglestothedirectionofrollingandaV-shapednotch(conformingtoISOR148)perpendiculartotheplatesurface,shallbe34J/cm2formildsteel(which,becauseofexistingISOstandards,maybetestedwithtest-pieceshavingthelongitudinalaxisinthedirectionofrolling);fine-grainedsteel;ferriticalloysteelNi<5%,ferriticalloysteel5%≤Ni≤9%;orausteniticCr-Nisteel,—inthecaseofausteniticsteels,onlytheweldbeadneedbesubjectedtoanimpact-strengthtest,—forworkingtemperaturesbelow–196ºCtheimpact-strengthtestisnotperformedatthelowestworkingtemperature,butat–196ºC.6.8.5.2.2.ShellsmadeofaluminiumoraluminiumalloyTheseamsofshellsshallmeettherequirementslaiddownbythecompetentauthority.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8776.8.5.2.3.ShellsmadeofcopperorcopperalloyItisnotnecessarytocarryoutteststodeterminewhethertheimpactstrengthisadequate.6.8.5.3.Impact-strengthtests6.8.5.3.1.Forsheetslessthan10mmbutnotlessthan5mmthick,test-pieceshavingacross-sectionof10mm×emm,where‘e’representsthethicknessofthesheet,shallbeused.Machiningto7,5mmor5mmispermittedifitisnecessary.Theminimumvalueof34J/cm2shallberequiredineverycase.NOTENoimpact-strengthtestshallbecarriedoutonsheetslessthan5mmthick,orontheirweldseams.6.8.5.3.2.a)Forthepurposeoftestingsheets,theimpactstrengthshallbedeterminedonthreetest-pieces.Test-piecesshallbetakenatrightanglestothedirectionofrolling;however,formildsteeltheymaybetakeninthedirectionofrolling.(b)Fortestingweldseamsthetest-piecesshallbetakenasfollows:whene≤10mm:threetest-pieceswiththenotchatthecentreoftheweld;threetest-pieceswiththenotchinthecentreoftheheataffectedzone(theV-notchtocrossthefusionboundaryatthecentreofthespecimen);CentreoftheweldHeataffectedzonewhen10mm<e≤20mm:threetest-piecesfromthecentreoftheweld;threetest-piecesfromtheheataffectedzone(theV-notchtocrossthefusionboundaryatthecentreofthespecimen);CentreofweldHeataffectedzoneOfficialJournaloftheEuropeanUnionEN26.1.2004L18/878whene>20mmtwosetsofthreetest-pieces,onesetontheupperface,onesetonthelowerfaceateachofthepointsindicatedbelow(theV-notchtocrossthefusionboundaryatthecentreofthespecimenforthosetakenfromtheheataffectedzone)CentreofweldHeataffectedzone6.8.5.3.3.(a)Forsheets,theaverageofthethreetestsshallmeettheminimumvalueof34J/cm2indicatedin6.8.5.2.1;notmorethanoneoftheindividualvaluesmaybebelowtheminimumvalueandthennotbelow24J/cm2.(b)Forwelds,theaveragevalueobtainedfromthethreetest-piecestakenatthecentreoftheweldshallnotbebelowtheminimumvalueof34J/cm2;notmorethanoneoftheindividualvaluesmaybebelowtheminimumvalueandthennotbelow24J/cm2.(c)Fortheheataffectedzone(theV-notchtocrossthefusionboundaryatthecentreofthespecimen)thevalueobtainedfromnotmorethanoneofthethreetest-piecesmaybebelowtheminimumvalueof34J/cm2,thoughnotbelow24J/cm2.6.8.5.3.4.Iftherequirementsprescribedin6.8.5.3.3arenotmet,oneretestonlymaybedoneif:(a)theaveragevalueofthefirstthreetestsisbelowtheminimumvalueof34J/cm2,or(b)morethanoneoftheindividualvaluesislessthantheminimumvalueof34J/cm2butnotbelow24J/cm2.6.8.5.3.5.Inarepeatedimpacttestonsheetsorwelds,noneoftheindividualvaluesmaybebelow34J/cm2.Theaveragevalueofalltheresultsoftheoriginaltestandoftheretestshouldbeequaltoormorethantheminimumof34J/cm2.Onarepeatedimpactstrengthtestontheheat-affectedzone,noneoftheindividualvaluesmaybebelow34J/cm2.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/879CHAPTER6.9Requirementsforthedesign,construction,equipment,type-approval,testingandmarkingoffibre-reinforcedplastics(FRP)tanksNOTEForportabletanksseeChapter6.7;forfixedtanks(tank-vehicles),demountabletanksandtank-containersandtankswapbodies,withshellsmadeofmetallicmaterials,andbattery-vehiclesandmultipleelementgascontainers(MEGCs)seeChapter6.8;forvacuumoperatedwastetanksseeChapter6.10.6.9.1.General6.9.1.1.FRPtanksshallbedesigned,manufacturedandtestedinaccordancewithaqualityassuranceprogrammerecognisedbythecompetentauthority;inparticular,laminationworkandweldingofthermoplasticlinersshallonlybecarriedoutbyqualifiedpersonnelinaccordancewithaprocedurerecognisedbythecompetentauthority.6.9.1.2.ForthedesignandtestingofFRPtanks,theprovisionsof6.8.2.1.1,6.8.2.1.7,6.8.2.1.13,6.8.2.1.14(a)and(b),6.8.2.1.25,6.8.2.1.27,6.8.2.1.28and6.8.2.2.3shallalsoapply.6.9.1.3.HeatingelementsshallnotbeusedforFRPtanks.6.9.1.4.Forthestabilityoftank-vehicles,therequirementsof9.7.5.1shallapply.6.9.2.Construction6.9.2.1.Shellsshallbemadeofsuitablematerials,whichshallbecompatiblewiththesubstancestobecarriedinaservicetemperaturerangeofbetween–40°Cand+50°C,unlesstemperaturerangesarespecifiedforspecificclimaticconditionsbythecompetentauthorityofthecountrywherethetransportoperationisperformed.6.9.2.2.Shellsshallconsistofthefollowingthreeelements:—internalliner,—structurallayer,—externallayer.6.9.2.2.1.Theinternallineristheinnershellwallzonedesignedastheprimarybarriertoprovideforthelong-termchemicalresistanceinrelationtothesubstancestobecarried,topreventanydangerousreactionwiththecontentsortheformationofdangerouscompoundsandanysubstantialweakeningofthestructurallayerowingtothediffusionofproductsthroughtheinternalliner.TheinternallinermayeitherbeaFRPlinerorathermoplasticliner.6.9.2.2.2.FRPlinersshallconsistof:(a)surfacelayer(‘gel-coat’):adequateresinrichsurfacelayer,reinforcedwithaveil,compatiblewiththeresinandcontents.Thislayershallhaveafibremasscontentofnotmorethan30%andhaveathicknessbetween0,25and0,60mm;(b)strengtheninglayer(s):layerorseverallayerswithaminimumthicknessof2mm,containingaminimumof900g/m2ofglassmatorchoppedfibreswithamasscontentinglassofnotlessthan30%unlessequivalentsafetyisdemonstratedforalowerglasscontent.6.9.2.2.3.Thermoplasticlinersshallconsistofthermoplasticsheetmaterialasreferredtoin6.9.2.3.4,weldedtogetherintherequiredshape,towhichthestructurallayersarebonded.Durablebondingbetweenlinersandthestructurallayershallbeachievedbytheuseofanappropriateadhesive.NOTEForthecarriageofflammableliquidstheinternallayermayrequireadditionalmeasuresinaccordancewith6.9.2.14,inordertopreventtheaccumulationofelectricalcharges.6.9.2.2.4.Thestructurallayeroftheshellisthezonespeciallydesignedaccordingto6.9.2.4to6.9.2.6towithstandthemechanicalstresses.Thispartnormallyconsistsofseveralfibrereinforcedlayersindeterminedorientations.6.9.2.2.5.Theexternallayeristhepartoftheshellwhichisdirectlyexposedtotheatmosphere.Itshallconsistofaresinrichlayerwithathicknessofatleast0,2mm.Forathicknesslargerthan0,5mm,amatshallbeused.Thislayershallhaveamasscontentinglassoflessthan30%andshallbecapableofwithstandingexteriorconditions,inparticulartheoccasionalcontactwiththesubstancetobecarried.Theresinshallcontainfillersoradditivestoprovideprotectionagainstdeteriorationofthestructurallayeroftheshellbyultra-violetradiation.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8806.9.2.3.Rawmaterials6.9.2.3.1.AllmaterialsusedforthemanufactureofFRPtanksshallbeofknownoriginandspecifications.6.9.2.3.2.ResinsTheprocessingoftheresinmixtureshallbecarriedoutinstrictcompliancewiththerecommendationsofthesupplier.Thisconcernsmainlytheuseofhardeners,initiatorsandaccelerators.Theseresinscanbe:—unsaturatedpolyesterresins,—vinylesterresins,—epoxyresins,—phenolicresins.Theheatdistortiontemperature(HDT)oftheresin,determinedinaccordancewithISO75-1:1993shallbeatleast20°Chigherthanthemaximumservicetemperatureofthetank,butshallinanycasenotbelowerthan70°C.6.9.2.3.3.ReinforcementfibresThereinforcementmaterialofthestructurallayersshallbeasuitablegradeoffibressuchasglassfibresoftypeEorECRaccordingtoISO2078:1993.Fortheinternalsurfaceliner,glassfibresoftypeCaccordingtoISO2078:1993maybeused.Thermoplasticveilsmayonlybeusedfortheinternallinerwhentheircompatibilitywiththeintendedcontentshasbeendemonstrated.6.9.2.3.4.ThermoplasticlinermaterialThermoplasticliners,suchasunplastifiedpolyvinylchloride(PVC-U),polypropylene(PP),polyvinylidenefluoride(PVDF),polytetra-fluoroethylene(PTFE),etc.maybeusedasliningmaterials.6.9.2.3.5.AdditivesAdditivesnecessaryforthetreatmentoftheresin,suchascatalysts,accelerators,hardenersandthixotropicsubstancesaswellasmaterialsusedtoimprovethetank,suchasfillers,colours,pigments,etc.shallnotcauseweakeningofthematerial,takingintoaccountlifetimeandtemperatureexpectancyofthedesign.6.9.2.4.Shells,theirattachmentsandtheirserviceandstructuralequipmentshallbedesignedtowithstandwithoutlossofcontents(otherthanquantitiesofgasescapingthroughanydegassingvents)duringthedesignlifetime:—thestaticanddynamicloadsinnormalconditionsofcarriage,—theprescribedminimumloadsasdefinedin6.9.2.5to6.9.2.10.6.9.2.5.Atthepressuresasindicatedin6.8.2.1.14(a)and(b),andunderthestaticgravityforcescausedbythecontentswithmaximumdensityspecifiedforthedesignandatmaximumfillingdegree,thedesignstressinlongitudinalandcircumferentialdirectionofanylayeroftheshellshallnotexceedthefollowingvalue:σ≤RmKwhere:Rm=thevalueoftensilestrengthgivenbytakingthemeanvalueofthetestresultsminustwicethestandarddeviationofthetestresults.Thetestsshallbecarriedout,inaccordancewiththerequirementsofEN61:1977,onnotlessthansixsamplesrepresentativeofthedesigntypeandconstructionmethod;K=S×K0×K1×K2×K3whereKshallhaveaminimumvalueof4,andS=thesafetycoefficient.Forthegeneraldesign,ifthetanksarereferredtoinColumn12ofTableAofChapter3.2byatankcodeincludingtheletter‘G’initssecondpart(see4.3.4.1.1),thevalueforSshallbeequaltoormorethan1,5.Fortanksintendedforthecarriageofsubstanceswhichrequireanincreasedsafetylevel,i.e.ifthetanksarereferredtoincolumn12ofTableAofChapter3.2byatankcodeincludingthenumber‘4’initssecondpart(see4.3.4.1.1),thevalueofSshallbemultipliedbyafactoroftwo,unlesstheshellisprovidedwithprotectionagainstdamageconsistingofacompletemetalskeletonincludinglongitudinalandtransversestructuralmembers,K0=afactorrelatedtothedeteriorationinthematerialpropertiesduetocreepandageingandasaresultofthechemicalactionofthesubstancestobecarried.Itshallbedeterminedbytheformula:K0¼1αβOfficialJournaloftheEuropeanUnionEN26.1.2004L18/881where‘α’isthecreepfactorand‘β’istheageingfactordeterminedinaccordancewithEN978:1997afterperformanceofthetestaccordingtoEN977:1997.Alternatively,aconservativevalueofK0=2maybeapplied.Inordertodetermineandtheinitialdeflectionshallcorrespondto2σ,K1=afactorrelatedtotheservicetemperatureandthethermalpropertiesoftheresin,determinedbythefollowingequation,withaminimumvalueof1:K1=1,25–0,0125(HDT–70)whereHDTistheheatdistortiontemperatureoftheresin,inºC;K2=afactorrelatedtothefatigueofthematerial;thevalueofK2=1,75shallbeusedunlessotherwiseagreedwiththecompetentauthority.Forthedynamicdesignasoutlinedin6.9.2.6thevalueofK2=1,1shallbeused,K3=afactorrelatedtocuringandhasthefollowingvalues:—1,1wherecuringiscarriedoutinaccordancewithanapprovedanddocumentedprocess—1,5inothercases.6.9.2.6.Atthedynamicstresses,asindicatedin6.8.2.1.2thedesignstressshallnotexceedthevaluespecifiedin6.9.2.5,dividedbythefactorα6.9.2.7.Atanyofthestressesasdefinedin6.9.2.5and6.9.2.6,theresultingelongationinanydirectionshallnotexceed0,2%oronetenthoftheelongationatfractureoftheresin,whicheverislower.6.9.2.8.Atthespecifiedtestpressure,whichshallnotbelessthantherelevantcalculationpressureasspecifiedin6.8.2.1.14(a)and(b)themaximumstrainintheshellshallnotbegreaterthantheelongationatfractureoftheresin.6.9.2.9.Theshellshallbecapableofwithstandingtheballdroptestaccordingto6.9.4.3.3withoutanyvisibleinternalorexternaldefects.6.9.2.10.Theoverlaylaminatesusedinthejoints,includingtheendjoints,thejointsofthesurgeplatesandthepartitionswiththeshellshallbecapableofwithstandingthestaticanddynamicstressesmentionedabove.Inordertoavoidconcentrationsofstressesintheoverlaylamination,theappliedtappershallnotbesteeperthan1:6.Theshearstrengthbetweentheoverlaylaminateandthetankcomponentstowhichitisbondedshallnotbelessthan:τ¼Ql≤τRKwhere:τR=isthebendingshearstrengthaccordingtoEN63:1977withaminimumofR=10N/mm2,ifnomeasuredvaluesareavailable;Q=istheloadperunitwidththatthejointshallcarryunderthestaticanddynamicloads;K=isthefactorcalculatedinaccordancewith6.9.2.5forthestaticanddynamicstresses;l=isthelengthoftheoverlaylaminate.6.9.2.11.Openingsintheshellshallbereinforcedtoprovideatleastthesamesafetyfactorsagainstthestaticanddynamicstressesasspecifiedin6.9.2.5and6.9.2.6asthatfortheshellitself.Thenumberofopeningsshallbeminimized.Theaxisratioofoval-shapedopeningsshallbenotmorethan2.6.9.2.12.Forthedesignofflangesandpipeworkattachedtotheshell,handlingforcesandthefasteningofboltsshallalsobetakenintoaccount.6.9.2.13.Thetankshallbedesignedtowithstand,withoutsignificantleakage,theeffectsofafullengulfmentinfirefor30minutesasspecifiedbythetestrequirementsin6.9.4.3.4.Testingmaybewaivedwiththeagreementofthecompetentauthority,wheresufficientproofcanbeprovidedbytestswithcomparabletankdesigns.6.9.2.14.Specialrequirementsforthetransportofsubstanceswithaflash-pointofnotmorethan61°CFRPtanksusedforthecarriageofsubstanceswithaflash-pointofnotmorethan61°Cshallbeconstructedsoastoensuretheeliminationofstaticelectricityfromthevariouscomponentpartssoastoavoidtheaccumulationofdangerouscharges.6.9.2.14.1.Theelectricalsurfaceresistanceoftheinsideandoutsideoftheshellasestablishedbymeasurementsshallnotbehigherthan109ohms.Thismaybeachievedbytheuseofadditivesintheresinorinterlaminateconductingsheets,suchasmetalorcarbonnetwork.6.9.2.14.2.Thedischargeresistancetoearthasestablishedbymeasurementsshallnotbehigherthan107ohms.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8826.9.2.14.3.Allcomponentsoftheshellshallbeelectricallyconnectedtoeachotherandtothemetalpartsoftheserviceandstructuralequipmentofthetankandtothevehicle.Theelectricalresistancebetweencomponentsandequipmentincontactwitheachothershallnotexceed10ohms.6.9.2.14.4.Theelectricalsurface-resistanceanddischargeresistanceshallbemeasuredinitiallyoneachmanufacturedtankoraspecimenoftheshellinaccordancewithaprocedurerecognisedbythecompetentauthority.6.9.2.14.5.Thedischargeresistancetoearthofeachtankshallbemeasuredaspartoftheperiodicinspectioninaccordancewithaprocedurerecognisedbythecompetentauthority.6.9.3.Itemsofequipment6.9.3.1.Therequirementsof6.8.2.2.1,6.8.2.2.2and6.8.2.2.4to6.8.2.2.8shallapply.6.9.3.2.Inaddition,whentheyareshownunderanentryincolumn13ofTableAofChapter3.2,thespecialprovisionsof6.8.4(b)(TE)shallalsoapply.6.9.4.Typetestingandapproval6.9.4.1.ForanydesignofaFRPtanktype,itsmaterialsandarepresentativeprototypeshallbesubjectedtothedesigntypetestingasoutlinedbelow.6.9.4.2.Materialtesting6.9.4.2.1.TheelongationatfractureaccordingtoEN61:1977andtheheatdistortiontemperatureaccordingtoISO75-1:1993shallbedeterminedfortheresinstobeused.6.9.4.2.2.Thefollowingcharacteristicsshallbedeterminedforsamplescutoutoftheshell.Samplesmanufacturedinparallelmayonlybeused,ifitisnotpossibletousecutoutsfromtheshell.Priortotesting,anylinershallberemoved.Thetestsshallcover:—thicknessofthelaminatesofthecentralshellwallandtheends,—masscontentandcompositionofglass,orientationandarrangementofreinforcementlayers,—tensilestrength,elongationatfractureandmodulusofelasticityaccordingtoEN61:1977inthedirectionofstresses.Inaddition,theelongationatfractureoftheresinshallbeestablishedbymeansofultrasound,—bendingstrengthanddeflectionestablishedbythebendingcreeptestaccordingtoEN63:1977foraperiodof1000hoursusingasamplewithaminimumwidthof50mmandasupportdistanceofatleast20timesthewallthickness.Inaddition,thecreepfactorαandtheageingfactorβshallbedeterminedbythistestandaccordingtoEN978:1997.6.9.4.2.3.TheinterlaminateshearstrengthofthejointsshallbemeasuredbytestingrepresentativesamplesinthetensiletestaccordingtoEN61:1977.6.9.4.2.4.Thechemicalcompatibilityoftheshellwiththesubstancestobecarriedshallbedemonstratedbyoneofthefollowingmethodswiththeagreementofthecompetentauthority.Thisdemonstrationshallaccountforallaspectsofthecompatibilityofthematerialsoftheshellanditsequipmentwiththesubstancestobecarried,includingchemicaldeteriorationoftheshell,initiationofcriticalreactionsofthecontentsanddangerousreactionsbetweenboth.—Inordertoestablishanydeteriorationoftheshell,representativesamplestakenfromtheshell,includinganyinternallinerswithwelds,shallbesubjectedtothechemicalcompatibilitytestaccordingtoEN977:1997foraperiodof1000hoursat50°C.Comparedwithavirginsample,thelossofstrengthandelasticitymodulusmeasuredbythebendingtestaccordingtoEN978:1997shallnotexceed25%.Cracks,bubbles,pittingeffectsaswellasseparationoflayersandlinersandroughnessshallnotbeacceptable,—certifiedanddocumenteddataofpositiveexperiencesonthecompatibilityofthefillingsubstancesinquestionwiththematerialsoftheshellwithwhichtheycomeintocontactatgiventemperatures,timesandanyotherrelevantserviceconditions,—technicaldatapublishedinrelevantliterature,standardsorothersources,acceptabletothecompetentauthority.6.9.4.3.TypetestingArepresentativeprototypetankshallbesubjectedtotestsasspecifiedbelow.Forthispurposeserviceequipmentmaybereplacedbyotheritemsifnecessary.6.9.4.3.1.Theprototypeshallbeinspectedforcompliancewiththedesigntypespecification.Thisshallincludeaninternalandexternalvisualinspectionandmeasurementofthemaindimensions.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8836.9.4.3.2.Theprototype,equippedwithstraingaugesatalllocationswhereacomparisonwiththedesigncalculationisrequired,shallbesubjectedtothefollowingloadsandthestrainsshallberecorded:—filledwithwatertothemaximumfillingdegree.Themeasuringresultsshallbeusedtocalibratethedesigncalculationaccordingto6.9.2.5,—filledwithwatertothemaximumfillingdegreeandsubjectedtoaccelerationsinallthreedirectionsbymeansofdrivingandbrakingexerciseswiththeprototypeattachedtoavehicle.Forcomparisonwiththedesigncalculationaccordingto6.9.2.6thestrainsrecordedshallbeextrapolatedinrelationtothequotientoftheaccelerationsrequiredin6.8.2.1.2andmeasured,—filledwithwaterandsubjectedtothespecifiedtestpressure.Underthisload,theshellshallexhibitnovisualdamageorleakage.6.9.4.3.3.TheprototypeshallbesubjectedtotheballdroptestaccordingtoEN976-1:1997,No6.6.Novisibledamageinsideoroutsidethetankshalloccur.6.9.4.3.4.Theprototypewithitsserviceandstructuralequipmentinplaceandfilledto80%ofitsmaximumcapacitywithwater,shallbeexposedtoafullengulfmentinfirefor30minutes,causedbyanopenheatingoilpoolfireoranyothertypeoffirewiththesameeffect.Thedimensionsofthepoolshallexceedthoseofthetankbyatleast50cmtoeachsideandthedistancebetweenfuellevelandtankshallbebetween50cmand80cm.Therestofthetankbelowliquidlevel,includingopeningsandclosures,shallremainleakproofexceptfordrips.6.9.4.4.Type-approval6.9.4.4.1.Thecompetentauthorityorabodydesignatedbythatauthorityshallissueinrespectofeachnewtypeoftankortank-containeranapprovalattestingthatthedesignissuitableforthepurposeforwhichitisintendedandmeetstheconstructionandequipmentrequirementsofthischapteraswellasthespecialprovisionsapplicabletothesubstancestobecarried.6.9.4.4.2.Theapprovalshallbebasedonthecalculationandthetestreport,includingallmaterialandprototypetestresultsanditscomparisonwiththedesigncalculation,andshallrefertothedesigntypespecificationandthequalityassuranceprogramme.6.9.4.4.3.Theapprovalshallincludethesubstancesorgroupofsubstancesforwhichcompatibilitywiththeshellisprovided.Theirchemicalnamesorthecorrespondingcollectiveentry(see2.1.1.2),andtheirclassandclassificationcodeshallbeindicated.6.9.4.4.4.Inaddition,itshallincludedesignandthresholdvalues(suchaslife-time,servicetemperaturerange,workingandtestpressures,materialdata)specifiedandallprecautionstobetakenforthemanufacture,testing,type-approval,markinganduseofanytank,manufacturedinaccordancewiththeapproveddesigntype.6.9.5.Inspections6.9.5.1.Foreverytank,manufacturedinconformitywiththeapproveddesign,materialtestsandinspectionsshallbeperformedasspecifiedbelow.6.9.5.1.1.Thematerialtestsaccordingto6.9.4.2.2,exceptforthetensiletestandforareductionofthetestingtimeforthebendingcreeptestto100hoursshallbeperformedwithsamplestakenfromtheshell.Samplesmanufacturedinparallelmayonlybeused,ifnocutoutsfromtheshellarepossible.Theapproveddesignvaluesshallbemet.6.9.5.1.2.Shellsandtheirequipmentshalleithertogetherorseparatelyundergoaninitialinspectionbeforebeingputintoservice.Thisinspectionshallinclude:—acheckofconformitytotheapproveddesign,—acheckofthedesigncharacteristics,—aninternalandexternalexamination,—ahydraulicpressuretestatthetestpressureindicatedontheplateprescribedin6.8.2.5.1,—acheckofoperationoftheequipment,—aleakproofnesstest,iftheshellanditsequipmenthavebeenpressuretestedseparately.6.9.5.2.Fortheperiodicinspectionoftankstherequirementsof6.8.2.4.2to6.8.2.4.4shallapply.6.9.5.3.Theinspectionsandtestsinaccordancewith6.9.5.1and6.9.5.2shallbecarriedoutbytheexpertapprovedbythecompetentauthority.Certificatesshallbeissuedshowingtheresultsoftheseoperations.Thesecertificatesshallrefertothelistofthesubstancespermittedforcarriageinthisshellinaccordancewith6.9.4.4.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8846.9.6.Marking6.9.6.1.Therequirementsof6.8.2.5shallapplytothemarkingofFRPtanks,withthefollowingamendments:—thetankplatemayalsobelaminatedtotheshellorbemadeofsuitableplasticsmaterials,—thedesigntemperaturerangeshallalwaysbemarked.6.9.6.2.Inaddition,whentheyareshownunderanentryincolumn13ofTableAofChapter3.2,thespecialprovisionsof6.8.4(e)(TM)shallalsoapply.CHAPTER6.10Requirementsfortheconstruction,equipment,type-approval,inspectionandmarkingofvacuum-operatedwastetanksNOTES1.ForportabletanksseeChapter6.7;forfixedtanks(tank-vehicles),demountabletanksandtankcontainersandtankswapbodies,withshellsmadeofmetallicmaterials,andbattery-vehiclesandmultipleelementgascontainers(MEGCs)seeChapter6.8;forfibre-reinforcedplastictanksseeChapter6.9.2.Thischapterappliestofixedtanksanddemountabletanks.6.10.1.General6.10.1.1.DefinitionNOTEAtankwhichfullycomplieswiththerequirementsofChapter6.8isnotconsideredtobea‘vacuum-operatedwastetank’.6.10.1.1.1.Theterm‘protectedarea’meanstheareaslocatedasfollows:(a)thelowerpartofthetankinazonewhichextendsovera60°angleoneithersideofthelowergeneratingline;(b)thetoppartofthetankinazonewhichextendsovera30°angleoneithersideofthetopgeneratingline;(c)ontheendfrontofthetankonmotorvehicles;(d)ontherearendofthetankinsidetheprotectionvolumeformedbythedevicestipulatedin9.7.6.6.10.1.2.Scope6.10.1.2.1.Thespecialrequirementsof6.10.2to6.10.4completeormodifyChapter6.8andareappliedtovacuum-operatedwastetanks.Vacuum-operatedwastetanksmaybeequippedwithopenableends,iftherequirementsofChapter4.3allowbottomdischargeofthesubstancestobecarried(indicatedbyletters‘A’or‘B’inPart3ofthetankcodegivenincolumn12ofTableAofChapter3.2,inaccordancewith4.3.4.1.1).Vacuum-operatedwastetanksshallcomplywithallrequirementsofChapter6.8,withtheexceptionofrequirementsovertakenbyaspecialprovisioninthischapter.Howevertherequirementsof6.8.2.1.19,6.8.2.1.20,and6.8.2.1.21shallnotapply.6.10.2.Construction6.10.2.1.Tanksshallbedesignedforacalculationpressureequalto1,3timesthefillingordischargepressurebutnotlessthan400kPa(4bar)(gaugepressure).ForthecarriageofsubstancesforwhichahighercalculationpressureofthetankisspecifiedinChapter6.8,thishigherpressureshallapply.6.10.2.2.Tanksshallbedesignedtowithstandanegativeinternalpressureof100kPa(1bar).6.10.3.Itemsofequipment6.10.3.1.Theitemsofequipmentshallbesoarrangedastobeprotectedagainsttheriskofbeingwrenchedoffordamagedduringcarriageorhandling.Thisrequirementcanbefulfilledbyplacingtheitemsofequipmentinasocalled‘protectedarea’(see6.10.1.1.1).6.10.3.2.Thebottomdischargeofshellsmaybeconstitutedbyexternalpipingwithastop-valvefittedasclosetotheshellaspracticableandasecondclosurewhichmaybeablankflangeorotherequivalentdevice.6.10.3.3.Thepositionandclosingdirectionofthestop-valve(s)connectedtotheshell,ortoanycompartmentinthecaseofcompartmentedshells,shallbeunambiguous,andbeabletobecheckedfromtheground.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8856.10.3.4.Inordertoavoidanylossofcontentsintheeventofdamagetotheexternalfillinganddischargefittings(pipes,lateralshut-offdevices),theinternalstop-valve,orthefirstexternalstop-valve(whereapplicable),anditsseatingsshallbeprotectedagainstthedangerofbeingwrenchedoffbyexternalstressesorshallbesodesignedastowithstandthem.Thefillinganddischargedevices(includingflangesorthreadedplugs)andprotectivecaps(ifany)shallbecapableofbeingsecuredagainstanyunintendedopening.6.10.3.5.Thetanksmaybeequippedwithopenableends.Openableendsshallcomplywiththefollowingconditions:(a)theendsshallbedesignedtobesecuredleaktightwhenclosed;(b)unintentionalopeningshallnotbepossible;(c)wheretheopeningmechanismispoweroperatedtheendshallremainsecurelyclosedintheeventofapowerfailure;(d)asafetyorbreaksealdeviceshallbeincorporatedtoensurethattheopenableendcannotbeopenedwhenthereisstillaresidualoverpressureinthetank.Thisrequirementdoesnotapplytoopenableendswhicharepower-operated,wherethemovementispositivelycontrolled.Inthiscasethecontrolsshallbeofthedead-mantypeandbesopositionedthattheoperatorcanobservethemovementoftheopenableendatalltimesandisnotendangeredduringopeningandclosingoftheopenableend,and(e)provisionsshallbemadetoprotecttheopenableendandpreventitfrombeingforcedopenduringaroll-overofthevehicle.6.10.3.6.Vacuum-operatedwastetankswhicharefittedwithaninternalpistontoassistinthecleaningofthetankordischargingshallbeprovidedwithstop-devicestopreventthepistonineveryoperationalpositionbeingejectedfromthetankwhenaforceequivalenttothemaximumallowedworkingpressureofthetankisappliedtothepiston.Themaximumallowedworkingpressurefortanksorcompartmentswithpneumaticoperatedpistonshallnotexceed100kPa(1,0bar).Theinternalpistonshallbeconstructedinamannerandofmaterialswhichwillnotcauseanignitionsourcewhenthepistonismoved.Theinternalpistonmaybeusedasacompartmentprovideditissecuredinposition.Whereanyofthemeansbywhichtheinternalpistonissecuredisexternaltothetank,itshallbeplacedinapositionnotliabletoaccidentaldamage.6.10.3.7.Thetanksmaybeequippedwithsuctionboomsif:(a)theboomisfittedwithaninternalorexternalstop-valvefixeddirectlytotheshell,ordirectlytoabendthatisweldedtotheshell;(b)thestop-valvementionedin(a)issoarrangedthatcarriagewiththevalveinanopenpositionisprevented;and(c)theboomisconstructedinsuchawaythatthetankwillnotleakasaresultofaccidentalimpactontheboom.6.10.3.8.Thetanksshallbefittedwiththefollowingadditionalserviceequipment:(a)theoutletofapump/exhausterunitshallbesoarrangedastoensurethatanyflammableortoxicvapoursaredivertedtoaplacewheretheywillnotcauseadanger;(b)adevicetopreventimmediatepassageofflameshallbefittedtoboththeinletandoutletofavacuumpump/exhausterunitwhichmaycreatesparksandwhichisfittedonatankusedforthecarriageofflammablewastes;(c)pumpswhichcandeliverapositivepressureshallhaveasafetydevicefittedinthepipeworkwhichcanbepressurised.Thesafetydeviceshallbesettodischargeatapressurenotexceedingthemaximumworkingpressureofthetank;(d)astop-valveshallbefittedbetweentheshell,ortheoutletoftheoverfillpreventiondevicefittedtotheshell,andthepipeworkconnectingtheshelltothepump/exhausterunit;(e)thetankshallbefittedwithasuitablepressure/vacuummanometerwhichshallbemountedinapositionwhereitcanbeeasilyreadbythepersonoperatingthepump/exhausterunit.Adistinguishinglineshallbemarkedonthescaletoindicatethemaximumworkingpressureofthetank;(f)thetank,orincaseofcompartmentedtanks,everycompartment,shallbeequippedwithalevelindicatingdevice.Sightglassesmaybeusedaslevelindicatingdevicesprovided:(i)theyformapartofthetankwallandhavearesistancetothepressurecomparabletothatofthetank;ortheyarefittedexternaltothetank;(ii)thetopandbottomconnectionstothetankareequippedwithshut-offvalvesfixeddirectlytotheshellandsoarrangedthatcarriagewiththevalvesinanopenpositionisprevented;OfficialJournaloftheEuropeanUnionEN26.1.2004L18/886(iii)aresuitableforoperationatthemaximumallowedworkingpressureofthetank;and(iv)areplacedinapositionwheretheywillnotbeliabletoaccidentaldamage.6.10.3.9.Shellsofvacuum-operatedwastetanksshallhaveasafetyvalveprecededbyaburstingdisc.6.10.4.InspectionVacuum-operatedwastetanksshallbesubjecttoaninternalandexternalexaminationatleasteverythreeyears.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/887Part7PROVISIONSCONCERNINGTHECONDITIONSOFCARRIAGE,LOADING,UNLOADINGANDHANDLINGCHAPTER7.1Generalprovisions7.1.1.ThecarriageofdangerousgoodsissubjecttothemandatoryuseofaparticulartypeofcarriageinaccordancewiththeprovisionsofthischapterandChapter7.2forcarriageinpackages,Chapter7.3forcarriageinbulkandChapter7.4forcarriageintanks.Inaddition,theprovisionsofChapter7.5concerningloading,unloadingandhandlingshallbeobserved.Columns16,17and18ofTableAofChapter3.2showtheparticularprovisionsofthispartthatapplytospecificdangerousgoods.7.1.2.Inadditiontotheprovisionsofthispart,vehiclesusedforthecarriageofdangerousgoodsshall,asregardstheirdesign,constructionand,ifappropriate,theirapproval,conformtotherelevantrequirementsofPart9.7.1.3.Largecontainers,portabletanksandtank-containerswhichmeetthedefinitionof‘container’givenintheCSC(1972),asamended,orinUICleaflets(1)590(updated1.1.89)and592-1to592-4(updated1.7.1994)maynotbeusedtocarrydangerousgoodsunlessthelargecontainerortheframeoftheportabletankortank-containersatisfiestheprovisionsoftheCSCorofUICleaflets590and592-1to592-4.7.1.4.Alargecontainermaybepresentedforcarriageonlyifitisstructurallyserviceable.‘Structurallyserviceable’meansthatthecontainerisfreefrommajordefectsinitsstructuralcomponents,e.g.topandbottomsiderails,doorsillandheader,floorcrossmembers,cornerposts,andcornerfittings.‘Majordefects’aredentsorbendsinstructuralmembersgreaterthan19mmindepth,regardlessoflength;cracksorbreaksinstructuralmembers;morethanonespliceoranimpropersplice(e.g.alappedsplice)intoporbottomendrailsordoorheadersormorethantwosplicesinanyonetoporbottomsiderailoranyspliceinadoorsillorcornerpost;doorhingesandhardwarethatareseized,twisted,broken,missingorotherwiseinoperative;non-closinggasketsandseals;anydistortionoftheoverallconfigurationsufficienttopreventproperalignmentofhandlingequipment,mountingandsecuringonachassisorvehicle.Inaddition,deteriorationinanycomponentofthecontainer,suchasrustedmetalinsidewallsordisintegratedfibreglassisunacceptable,regardlessofthematerialofconstruction.Normalwear,includingoxidisation(rust),slightdentsandscratchesandotherdamagethatdonotaffectserviceabilityorweather-tightnessare,however,acceptable.Priortoloadingthecontainershallalsobecheckedtoensurethatitisfreefromanyresidueofapreviousloadandthattheinteriorfloorandwallsarefreefromprotrusions.7.1.5.Largecontainersshallmeettherequirementsconcerningthebodyofthevehiclelaiddowninthispartand,ifappropriate,thoselaiddowninPart9fortheloadinquestion;thebodyofthevehicleneednotthensatisfythoseprovisions.However,largecontainerscarriedonvehicleswhoseplatformshaveinsulationandheat-resistantqualitieswhichsatisfythoserequirementsneednotthensatisfythesaidrequirements.ThisprovisionalsoappliestosmallcontainersforthecarriageofexplosivesubstancesandarticlesofClass1.7.1.6.Subjecttotheprovisionsofthelastpartofthefirstsentenceof7.1.5,thefactthatdangerousgoodsarecontainedinoneormorecontainersshallnotaffecttheconditionstobemetbythevehiclebyreasonofthenatureandquantitiesofthedangerousgoodscarried.CHAPTER7.2Provisionsconcerningcarriageinpackages7.2.1.Unlessotherwiseprovidedin7.2.2to7.2.4,packagesmaybeloaded:(a)inclosedvehiclesorinclosedcontainers;or(b)insheetedvehiclesorinsheetedcontainers;or(c)inopenvehiclesorinopencontainers.7.2.2.Packagescomprisingpackagingsmadeofmaterialssensitivetomoistureshallbeloadedontoclosedorontosheetedvehiclesorintoclosedorsheetedcontainers.7.2.3.CertainpackagingsandIBCsmayonlybecarriedinclosedvehiclesorinclosedcontainers(see4.1.2.3andpackinginstructionsP002(PP12),IBC04,IBC05,IBC06,IBC07andIBC08).OfficialJournaloftheEuropeanUnionEN26.1.2004L18/888(1)UICleafletsarepublishedbytheUnioninternationaledescheminsdefer,Servicepublications-16,rueJeanRey-F-75015Paris.7.2.4.Whentheyareshownunderanentryincolumn16ofTableAofChapter3.2,thefollowingspecialprovisionsapply:V1Packagesshallbeloadedontoclosedorsheetedvehiclesorintoclosedorsheetedcontainers.V2(1)PackagesshallonlybeloadedontoEX/IIorEX/IIIvehicleswhichsatisfytherelevantrequirementsofPart9.Thechoiceofvehicledependsonthequantitytobecarried,whichislimitedpertransportunitinaccordancewiththeprovisionsconcerningloading(see7.5.5.2).(2)Trailers,exceptsemi-trailers,whichsatisfytherequirementsforEX/IIorEX/IIIvehiclesmaybedrawnbymotorvehicleswhichdonotsatisfythoserequirements.Forcarriageincontainers,seealso7.1.3to7.1.6.WheresubstancesorarticlesofClass1inquantitiesrequiringatransportunitmadeupofEX/IIIvehicle(s)arebeingcarriedincontainerstoorfromharbourareas,railterminalsorairportsofarrivalordepartureaspartofamultimodaljourney,atransportunitmadeupofEX/IIvehicle(s)maybeusedinstead,providedthatthecontainersbeingcarriedcomplywiththeappropriaterequirementsoftheIMDGcode,theRIDortheICAOtechnicalinstructions.V3Forfree-flowingpowderysubstancesandforfireworksthefloorofacontainershallhaveanon-metallicsurfaceorcovering.V4(Reserved)V5Packagesmaynotbecarriedinsmallcontainers.V6FlexibleIBCsshallbecarriedinclosedvehiclesorinclosedcontainers,insheetedvehiclesorinsheetedcontainers.Thesheetshallbeofanimpermeableandnon-combustiblematerial.V7Ifpackagesarecarriedinaclosedvehicleorinaclosedcontainer,thevehicleorcontainershallbeprovidedwithadequateventilation.V8(1)Organicperoxidesandself-reactivesubstancesshallbeforwardedinsuchmannerthatthecontroltemperaturesindicatedin2.2.41.1.19and2.2.41.4orin2.2.52.1.16and2.2.52.4,asappropriate,areneverexceeded.(2)Themeansoftemperaturecontrolchosenforthetransportoperationdependsonanumberoffactorssuchas:—thecontroltemperature(s)ofthesubstance(s)tobecarried,—thedifferencebetweenthecontroltemperatureandtheexpectedambienttemperature,—theeffectivenessofthethermalinsulation,—thedurationofthetransportoperation,and—thesafetymargintobeallowedfordelaysenroute.(3)Suitablemethodstopreventthecontroltemperaturefrombeingexceededarelistedbelow,inascendingorderofeffectiveness:R1thermalinsulation,providedthattheinitialtemperatureofthesubstance(s)issufficientlybelowthecontroltemperature;R2thermalinsulationandcoolantsystem,providedthat:—anadequatequantityofnon-flammablecoolant(e.g.liquidnitrogenorsolidcarbondioxide),allowingareasonablemarginforpossibledelay,iscarriedorameansofreplenishmentisassured,—liquidoxygenorairisnotusedascoolant,—thereisauniformcoolingeffectevenwhenmostofthecoolanthasbeenconsumed,and—theneedtoventilatethetransportunitbeforeenteringisclearlyindicatedbyawarningonthedoor(s);R3thermalinsulationandsinglemechanicalrefrigeration,providedthatforsubstanceswithaflash-pointlowerthanthesumoftheemergencytemperatureplus5°Cexplosion­proofelectricalfittings,EExIIBT3,areusedwithinthecoolingcompartmenttopreventignitionofflammablevapoursfromthesubstances;R4thermalinsulationandcombinedmechanicalrefrigerationsystemandcoolantsystem,providedthat:—thetwosystemsareindependentofoneanother;and—therequirementsofmethodsR2andR3aremet;R5thermalinsulationanddualmechanicalrefrigerationsystem,providedthat:—apartfromtheintegralpowersupplyunit,thetwosystemsareindependentofoneanother;—eachsystemaloneiscapableofmaintainingadequatetemperaturecontrol,and—forsubstanceswithaflash-pointlowerthanthesumoftheemergencytemperatureplus5°Cexplosion-proofelectricalfittings,EExIIBT3,areusedwithinthecoolingcompartmenttopreventignitionofflammablevapoursfromthesubstances.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/889(4)MethodsR4andR5maybeusedforallorganicperoxidesandself-reactivesubstances.MethodR3maybeusedfororganicperoxidesandself-reactivesubstancesofTypesC,D,EandFand,whenthemaximumambienttemperaturetobeexpectedduringcarriagedoesnotexceedthecontroltemperaturebymorethan10°C,fororganicperoxidesandself-reactivesubstancesofTypeB.MethodR2maybeusedfororganicperoxidesandself-reactivesubstancesofTypesC,D,EandFwhenthemaximumambienttemperaturetobeexpectedduringcarriagedoesnotexceedthecontroltemperaturebymorethan30°C.MethodR1maybeusedfororganicperoxidesandself-reactivesubstancesofTypesC,D,EandFwhenthemaximumambienttemperaturetobeexpectedduringcarriageisatleast10°Cbelowthecontroltemperature.(5)Wheresubstancesarerequiredtobecarriedininsulated,refrigeratedormechanically-refrigeratedvehiclesorcontainers,thesevehiclesorcontainersshallsatisfytherequirementsofChapter9.6.(6)Ifsubstancesarecontainedinprotectivepackagingsfilledwithacoolant,theyshallbeloadedinclosedorsheetedvehiclesorclosedorsheetedcontainers.Ifthevehiclesorcontainersusedareclosedtheyshallbeadequatelyventilated.Sheetedvehiclesandcontainersshallbefittedwithsideboardsandatailboard.Thesheetsofthesevehiclesandcontainersshallbeofanimpermeableandnon-combustiblematerial.(7)Anycontrolandtemperaturesensingdevicesintherefrigerationsystemshallbereadilyaccessibleandallelectricalconnectionsshallbeweatherproof.Thetemperatureoftheairinsidethetransportunitshallbemeasuredbytwoindependentsensorsandtheoutputshallberecordedsothatanychangeintemperatureisreadilydetectable.Whensubstanceshavingacontroltemperatureoflessthan+25°Carecarried,thetransportunitshallbeequippedwithvisibleandaudiblealarms,poweredindependentlyoftherefrigerationsystemandsettooperateatorbelowthecontroltemperature.(8)Aback-uprefrigerationsystemorsparepartsshallbeavailable.CHAPTER7.3Provisionsconcerningcarriageinbulk7.3.1.Goodsmaynotbecarriedinbulkinvehiclesorcontainersunlessaspecialprovision,identifiedbythecodeVV,explicitlyauthorisingthismodeofcarriageisindicatedincolumn17ofTableAofChapter3.2forthesegoodsandunlesstheconditionsofthisspecialprovisionaresatisfied.Nevertheless,emptypackagings,uncleanedmaybecarriedinbulkifthismodeofcarriageisnotexplicitlyprohibitedbyotherprovisionsofthisDirective.NOTE:Forcarriageintanks,seeChapters4.2and4.3.7.3.2.Suitablemeasuresshallbetakenforallcarriageinbulktoensurethatnoneofthecontentscanescape.7.3.3.Whentheyareshownunderanentryincolumn17ofTableAofChapter3.2,thefollowingspecialprovisionsapply.VV1Carriageinbulkinclosedorsheetedvehicles,inclosedcontainersorinlargesheetedcontainersispermitted.VV2Carriageinbulkispermittedinclosedvehicleswithametalbody,closedmetalcontainersandinsheetedvehiclesandsheetedlargecontainerscoveredwithanon-combustiblesheetandhavingametalbodyorhavingfloorandwallsprotectedfromtheload.VV3Carriageinbulkispermittedinsheetedvehiclesandsheetedlargecontainerswithadequateventilation.VV4Carriageinbulkispermittedinclosedorsheetedvehicleswithametalbody,andinclosedmetalcontainersorinsheetedlargemetalcontainers.ForUNNos2008,2009,2210,2545,2546,2881,3189and3190,onlycarriageinbulkofsolidwasteispermitted.VV5Carriageinbulkispermittedinspeciallyequippedvehiclesandcontainers.Theopeningsusedforloadingandunloadingshallbecapableofbeingclosedhermetically.VV6(Reserved)VV7Carriageinbulkinclosedorsheetedvehicles,inclosedcontainersorinlargesheetedcontainersispermittedonlyifthesubstanceisinpieces.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/890VV8Carriageinbulkispermitted,asafullload,inclosedvehicles,closedcontainersorsheetedvehiclesorlargecontainerscoveredwithanimpermeable,non-combustiblesheet.Vehiclesandcontainersshallbesoconstructedeitherthatthesubstancescontainedcannotcomeintocontactwithwoodoranyothercombustiblematerial,orthattheentiresurfaceofthefloorandwalls,ifmadeofwoodoranothercombustiblematerialhasbeenprovidedwithanimpermeablesurfacingresistanttocombustionorhasbeencoatedwithsodiumsilicateorasimilarsubstance.VV9aCarriageinbulkispermitted,asafullload,insheetedvehicles,closedcontainersorinsheetedlargecontainerswithcompletewalls.ForsubstancesofClass8,thebodyofthevehicleorcontainershallbeequippedwithasuitableandsufficientlystoutinnerlining.VV9bCarriageinbulkoffullloads(ifClass8,onlyforwastes)ispermittedinclosedcontainersorinsheetedlargecontainerswithcompletewalls.ForwastesofClass8,containersshallbeequippedwithasuitableandsufficientlystoutinnerlining.VV10Carriageinbulkispermittedinsheetedvehicles,closedcontainersorsheetedlargecontainerswithcompletewalls.Thebodyofvehiclesorcontainersshallbeleakprooforrenderedleakproof,forexamplebymeansofasuitableandsufficientlystoutinnerlining.VV11Carriageinbulkispermittedinspeciallyequippedvehiclesandcontainersinamannerwhichavoidsriskstohumans,animalsandtheenvironment,e.g.byloadingthewastesinbagsorbyairtightconnections.VV12Substancesforwhichcarriageintank-vehicles,inportabletanksorintank-containersisunsuitablebecauseofthehightemperatureanddensityofthesubstancemaybecarriedinspecialvehiclesorcontainersinaccordancewithstandardsspecifiedbythecompetentauthorityofthecountryoforigin.IfthecountryoforiginisnotaMemberState,theconditionslaiddownshallberecognisedbythecompetentauthorityofthefirstMemberStatereachedbytheconsignment.VV13Carriageinbulkispermittedinspeciallyequippedvehiclesorcontainersinaccordancewithstandardsspecifiedbythecompetentauthorityofthecountryoforigin.IfthecountryoforiginisnotaMemberState,theconditionslaiddownshallberecognisedbythecompetentauthorityofthefirstMemberStatereachedbytheconsignment.VV14(1)Usedbatteriesmaybecarriedinbulkinspeciallyequippedvehiclesorcontainers.Largeplasticscontainersshallnotbepermitted.Smallplasticscontainersshallbecapableofwithstanding,whenfullyloaded,adropfromaheightof0,8montoahardsurfaceat–18°C,withoutbreakage.(2)Theloadcompartmentsofvehiclesorcontainersshallbeofsteelresistanttothecorrosivesubstancescontainedinthebatteries.Lessresistantsteelsmaybeusedwhenthereisasufficientlygreatwallthicknessoraplasticslining/layerresistanttothecorrosivesubstances.Thedesignoftheloadcompartmentsofvehiclesorcontainersshalltakeaccountofanyresidualcurrentsandimpactfromthebatteries.NOTE:Steelexhibitingamaximumrateofprogressivereductionof0,1mmperyearundertheeffectsofthecorrosivesubstancesmaybeconsideredasresistant.(3)Itshallbeensuredbymeansofconstructionalmeasuresthattherewillbenoleakageofcorrosivesubstancesfromtheloadcompartmentsofvehiclesorcontainersduringcarriage.Openloadcompartmentsshallbecovered.Thecovershallberesistanttothecorrosivesubstances.(4)Beforeloading,theloadcompartmentsofvehiclesorcontainers,includingtheirequipment,shallbeinspectedfordamage.Vehiclesorcontainerswithdamagedloadcompartmentsshallnotbeloaded.Theloadcompartmentsofvehiclesorcontainersshallnotbeloadedabovethetopoftheirwalls.(5)Nobatteriescontainingdifferentsubstancesandnoothergoodsliabletoreactdangerouslywitheachothershallbepresentintheloadcompartmentsofvehiclesorcontainers(see‘Dangerousreaction’in1.2.1).Duringcarriagenodangerousresidueofthecorrosivesubstancescontainedinthebatteriesshalladheretotheoutersurfaceoftheloadcompartmentsofvehiclesorcontainers.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/891CHAPTER7.4Provisionsconcerningcarriageintanks7.4.1.Goodsmaynotbecarriedintanksunlessatankcodeisindicatedincolumns12and13ofTableAofChapter3.2.ThecarriageshallbeinaccordancewiththeprovisionsofChapters4.2or4.3,andthevehicles,whethertheybetank-vehicles(withafixedordemountabletank),battery-vehiclesorvehiclescarryingtank-containersorportabletanks,shallsatisfytherelevantrequirementsofChapters9.1,9.2and9.7.2concerningthevehicletobeused,asindicatedincolumn14ofTableAofChapter3.2.7.4.2.ThevehiclesdesignatedbythecodesFL,OXorATin9.1.1.2shallbeusedasfollows:—whereaFLvehicleisprescribed,onlyanFLvehiclemaybeused,—whereaOXvehicleisprescribed,onlyanOXvehiclemaybeused,—whereaATvehicleisprescribed,AT,FLandOXvehiclesmaybeused.CHAPTER7.5Provisionsconcerningloading,unloadingandhandling7.5.1.Generalprovisionsconcerningloading,unloadingandhandling7.5.1.1.Thevehicleanditsdriver,uponarrivalattheloadingandunloadingsites,shallcomplywiththeregulatoryprovisions(especiallythoseconcerningsafety,cleanlinessandsatisfactoryoperationofthevehicleequipmentusedinloadingandunloading).7.5.1.2.Theloadingshallnotbecarriedoutifanexaminationofthedocumentsandavisualinspectionofthevehicleanditsequipmentshowthatthevehicleorthedriverdonotcomplywiththeregulatoryprovisions.7.5.1.3.Theunloadingshallnotbecarriedout,iftheabovementionedinspectionsrevealdeficienciesthatmightaffectthesafetyoftheunloading.7.5.1.4.Inaccordancewiththespecialprovisionsof7.3.3or7.5.11,inconformitywithcolumns17and18ofTableAofChapter3.2,certaindangerousgoodsshallonlybeforwardedasa‘fullload’(seedefinitionin1.2.1).Insuchacase,thecompetentauthoritiesmayrequirethevehicleorlargecontainerusedforsuchcarriagetobeloadedatonlyonepointandunloadedatonlyonepoint.7.5.2.Mixedloadingprohibition7.5.2.1.Packagesbearingdifferentdangerlabelsshallnotbeloadedtogetherinthesamevehicleorcontainerunlessmixedloadingispermittedaccordingtothefollowingtablebasedonthedangerlabelstheybear.NOTE:Inaccordancewith5.4.1.4.2,separatetransportdocumentsshallbedrawnupforconsignmentsthatcannotbeloadedtogetherinthesamevehicleorcontainer.LabelsNos11.41.51.62.1,2.2,2.334.14.1+14.24.35.15.25.2+16.16.27A,B,C891See7.5.2.2(b)1.4(a)(a)(a)(a)(a)(a)(a)(a)(a)(a)(a)(a)(b)1.5(b)1.6(b)2.1,2.2,2.3(a)XXXXXXXXXXXXOfficialJournaloftheEuropeanUnionEN26.1.2004L18/892LabelsNos11.41.51.62.1,2.2,2.334.14.1+14.24.35.15.25.2+16.16.27A,B,C893(a)XXXXXXXXXXXX4.1(a)XXXXXXXXXXXX4.1+1X4.2(a)XXXXXXXXXXXX4.3(a)XXXXXXXXXXXX5.1(a)XXXXXXXXXXXX5.2(a)XXXXXXXXXXXX5.2+1X6.1(a)XXXXXXXXXXXX6.2(a)XXXXXXXXXXXX7A,B,C(a)XXXXXXXXXXXX8(a)XXXXXXXXXXXX9(b)(a)(b)(b)(b)XXXXXXXXXXXXXMixedloadingpermitted.(a)Mixedloadingpermittedwith1.4Ssubstancesandarticles.(b)MixedloadingpermittedbetweengoodsofClass1andlife-savingappliancesofClass9(UNNos2990and3072).7.5.2.2.PackagescontainingsubstancesorarticlesofClass1,bearingalabelconformingtomodelNos1,1.4,1.5or1.6whichareassignedtodifferentcompatibilitygroupsshallnotbeloadedtogetherinthesamevehicleorcontainer,unlessmixedloadingispermittedinaccordancewiththefollowingTableforthecorrespondingcompatibilitygroups.CompatibilityGroupABCDEFGHJLNSAXBX(a)XCXXXX(b)(c)XD(a)XXXX(b)(c)XEXXXX(b)(c)XFXXGXXXXXHXXJXXOfficialJournaloftheEuropeanUnionEN26.1.2004L18/893CompatibilityGroupABCDEFGHJLNSL(d)N(b)(c)(b)(c)(b)(c)(b)XSXXXXXXXXXXXMixedloadingpermitted.(a)PackagescontainingarticlesofcompatibilitygroupBandsubstancesandarticlesofcompatibilitygroupDmaybeloadedtogetherononevehicleprovidedtheyarecarriedinseparatecontainersorcompartmentsofadesignapprovedbythecompetentauthorityorabodydesignatedbyit,suchthatthereisnodangeroftransmissionofdetonationfromthearticlesofcompatibilitygroupBtothesubstancesorarticlesofcompatibilitygroupD.(b)Differenttypesofarticlesofdivision1.6,compatibilitygroupN,maybecarriedtogetherasarticlesofdivision1.6,compatibilitygroupN,onlywhenitisprovenbytestingoranalogythatthereisnoadditionalriskofsympatheticdetonationbetweenthearticles.Otherwisetheyshouldbetreatedashazarddivision1.1.(c)WhenarticlesofcompatibilitygroupNarecarriedwithsubstancesorarticlesofcompatibilitygroupsC,DorE,thearticlesofcompatibilitygroupNshouldbeconsideredashavingthecharacteristicsofcompatibilitygroupD(d)PackagescontainingsubstancesandarticlesofCompatibilityGroupLmaybeloadedtogetherononevehicleorinonecontainerwithpackagescontainingthesametypeofsubstancesandarticlesofthatcompatibilitygroup.7.5.2.3.Forthepurposeoftheapplicationoftheprohibitionsofmixedloadingononevehicle,noaccountshallbetakenofsubstancescontainedinclosedcontainerswithcompletesides.Nevertheless,themixedloadingprohibitionslaiddownin7.5.2.1concerningmixedloadingofpackagesbearinglabelsconformingtomodelsNos1,1.4,1.5or1.6withotherpackages,andin7.5.2.2concerningmixedloadingofexplosivesofdifferentcompatibilitygroupsshallalsoapplybetweendangerousgoodscontainedinacontainerandtheotherdangerousgoodsloadedonthesamevehicle,whetherornotthelattergoodsareenclosedinoneormoreothercontainers.7.5.3.(Reserved)7.5.4.Precautionswithrespecttofoodstuffs,otherarticlesofconsumptionandanimalfeedsIfspecialprovisionCV28isindicatedforasubstanceorarticleincolumn18ofTableAofChapter3.2,precautionswithrespecttofoodstuffs,otherarticlesofconsumptionandanimalfeedsshallbetakenasfollows.Packagesaswellasuncleanedemptypackagings,includinglargepackagingsandintermediatebulkcontainers(IBCs),bearinglabelsconformingtomodelNos6.1or6.2andthosebearinglabelsconformingtomodelNo9containinggoodsofUNNos2212,2315,2590,3151,3152or3245,shallnotbestackedonorloadedinimmediateproximitytopackagesknowntocontainfoodstuffs,otherarticlesofconsumptionoranimalfeedsinvehicles,incontainersandatplacesofloading,unloadingortranshipment.Whenthesepackages,bearingthesaidlabels,areloadedinimmediateproximityofpackagesknowntocontainfoodstuffs,otherarticlesofconsumptionoranimalfeeds,theyshallbekeptapartfromthelatter:(a)bycompletepartitionswhichshouldbeashighasthepackagesbearingthesaidlabels;(b)bypackagesnotbearinglabelsconformingtomodelNos6.1,6.2or9orpackagesbearinglabelsconformingtomodelNo9butnotcontaininggoodsofUNNos2212,2315,2590,3151,3152or3245,or(c)byaspaceofatleast0,8m,unlessthepackagesbearingthesaidlabelsareprovidedwithanadditionalpackagingorarecompletelycovered(e.g.byasheeting,afibreboardcoverorothermeasures).7.5.5.Limitationofthequantitiescarried7.5.5.1.Iftheprovisionsbelowortheadditionalprovisionsof7.5.11requirealimitationofthequantityofspecificgoodsthatcanbecarried,inaccordancewiththeinformationincolumn7ofTableAofChapter3.2,thefactthatdangerousgoodsarecontainedinoneormorecontainersshallnotaffectthemasslimitationspertransportunitlaiddownbytheseprovisions.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8947.5.5.2.Limitationswithrespecttoexplosivesubstancesandarticles7.5.5.2.1.SubstancesandquantitiescarriedThetotalnetmassinkgofexplosivesubstance(orinthecaseofexplosivearticles,thetotalnetmassofexplosivesubstancecontainedinallthearticlescombined)whichmaybecarriedononetransportunitshallbelimitedasindicatedinthetable(seealso7.5.2.2asregardstheprohibitionofmixedloading).MaximumpermissiblenetmassinkgofexplosiveinClass1goodspertransportunitTransportUnitDivision1.11.21.31.41.5and1.6EmptyuncleanedpackagingsCompat-ibilitygroup1.1AOtherthan1.1AOtherthan1.4S1.4SEX/II(a)6,2510003000500015000Unlimited5000UnlimitedEX/III(a)18,7516000160001600016000Unlimited16000Unlimited(a)ForthedescriptionofEX/IIandEX/IIIvehiclesseePart9.7.5.5.2.2.WheresubstancesandarticlesofdifferentdivisionsofClass1areloadedononetransportunitinconformitywiththeprohibitionsofmixedloadingcontainedin7.5.2.2,theloadasawholeshallbetreatedasifitbelongedtothemostdangerousdivision(intheorder1.1,1.5,1.2,1.3,1.6,1.4).However,thenetmassofexplosivesofcompatibilitygroupSshallnotcounttowardsthelimitationofquantitiescarried.Wheresubstancesclassifiedas1.5Darecarriedononetransportunittogetherwithsubstancesorarticlesofdivision1.2,theentireloadshallbetreatedforcarriageasifitbelongedtodivision1.1.7.5.5.3.Limitationswithrespecttoorganicperoxidesandself-reactivesubstancesThequantityoforganicperoxidesofClass5.2andself-reactivesubstancesofClass4.1thatcanbecarriedinasingletransportunitislimitedasfollows:Organicperoxideorself-reactivesubstanceSubstancesofTypeBwithouttemperaturecontrolSubstancesofTypeCwithouttemperaturecontrolSubstancesofTypeD,EorFwithouttemperaturecontrolSubstancesofTypeBwithtemperaturecontrolSubstancesofTypeCwithtempera-turecontrolSubstancesofTypeD,EorFwithtemperaturecontrolMaximumquan-titypertransportunit1000kg(a)10000kg20000kg1000kg(b)5000kg(c)20000kg(a)5000kgiftheloadingspaceisventilatedatthetopandifthetransportunitisinsulatedwithheat-resistantmaterial(see9.3.4).(b)5000kgifthetransportunitisinsulatedwithaheat-resistantmaterial(see9.3.4).(c)10000kgifthetransportunitisinsulatedwithaheat-resistantmaterial(see9.3.4).Whensubstancesarecarriedtogetherinonetransportunit,thelimitsgivenaboveshallnotbeexceededandthetotalcontentsshallnotexceed20000kg.7.5.6.(Reserved)7.5.7.Handlingandstowage7.5.7.1.Thevariouscomponentsofaloadcomprisingdangerousgoodsshallbeproperlystowedonthevehicleorinthecontainerandsecuredbyappropriatemeanstopreventthemfrombeingsignificantlydisplacedinrelationtoeachotherandtothewallsofthevehicleorcontainer.Theloadmaybeprotected,forexample,bytheuseofsidewallfasteningstraps,slidingslatboardsandadjustablebrackets,airbagsandanti-slidelockingdevices.Theloadisalsosufficientlyprotectedwithinthemeaningofthefirstsentenceifeachlayerofthewholeloadingspaceiscompletelyfilledwithpackages.7.5.7.2.Theprovisionsof7.5.7.1alsoapplytotheloading,stowageandunloadingofcontainersontoandfromvehicles.7.5.7.3.Thedriveroranyothermemberofthecrewmaynotopenapackagecontainingdangerousgoods.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/8957.5.8.Cleaningafterunloading7.5.8.1.If,whenavehicleorcontainerwhichhascontainedpackageddangerousgoodsisunloaded,someofthecontentsarefoundtohaveescaped,thevehicleorcontainershallbecleanedassoonaspossibleandinanycasebeforereloading.Ifitisnotpossibletodothecleaninglocally,thevehicleorcontainershallbecarried,withdueregardtoadequatesafety,tothenearestsuitableplacewherecleaningcanbecarriedout.Carriageisadequatelysafeifsuitablemeasureshavebeentakentopreventtheuncontrolledreleaseofthedangerousgoodsthathaveescaped.7.5.8.2.Vehiclesorcontainerswhichhavebeenloadedwithdangerousgoodsinbulkshallbeproperlycleanedbeforereloadingunlessthenewloadconsistsofthesamedangerousgoodsastheprecedingload.7.5.9.ProhibitionofsmokingSmokingshallbeprohibitedduringhandlingoperationsinthevicinityofvehiclesorcontainersandinsidethevehiclesorcontainers.7.5.10.PrecautionsagainstelectrostaticchargesInthecaseofsubstanceswithaflash-pointof61°Corbelow,agoodelectricalconnectionfromthechassisofthevehicle,theportabletankorthetank-containertoearthshallbeestablishedbeforetanksarefilledoremptied.Inaddition,therateoffillingshallbelimited.7.5.11.AdditionalprovisionsapplicabletocertainclassesorspecificgoodsInadditiontotheprovisionsofsections7.5.1to7.5.10,thefollowingprovisionsshallapplywhentheyareshownunderanentryindicatedincolumn18ofTableAofChapter3.2.CV1(1)Thefollowingoperationsareprohibited:(a)loadingorunloadinggoodsinapublicplaceinabuilt-upareawithoutspecialpermissionfromthecompetentauthorities;(b)loadingorunloadinggoodsinapublicplaceelsewherethaninabuilt-upareawithoutpriornoticethereofhavingbeengiventothecompetentauthorities,unlesstheseoperationsareurgentlynecessaryforreasonsofsafety.(2)If,foranyreason,handlingoperationshavetobecarriedoutinapublicplace,thensubstancesandarticlesofdifferentkindsshallbeseparatedaccordingtothelabels.CV2(1)Beforeloading,theloadingsurfaceofthevehicleorcontainershallbethoroughlycleaned.(2)Theuseoffireornakedflameshallbeprohibitedonvehiclesandcontainerscarryinggoods,intheirvicinityandduringtheloadingandunloadingofthesegoods.CV3See7.5.5.2.CV4SubstancesandarticlesofcompatibilitygroupLshallonlybecarriedasafullload.CV5toCV8(Reserved)CV9Packagesshallnotbethrownorsubjectedtoimpact.Receptaclesshallbesostowedinthevehicleorcontainerthattheycannotoverturnorfall.CV10Cylindersasdefinedin1.2.1,shallbelaidparalleltooratrightanglestothelongitudinalaxisofthevehicleorcontainer;however,thosesituatedneartheforwardtransversewallshallbelaidatrightanglestothesaidaxis.Shortcylindersoflargediameter(about30cmandover)maybestowedlongitudinallywiththeirvalve-protectingdevicesdirectedtowardsthemiddleofthevehicleorcontainer.Cylinderswhicharesufficientlystableorarecarriedinsuitabledeviceseffectivelypreventingthemfromoverturningmaybeplacedupright.Cylinderswhicharelaidflatshallbesecurelyandappropriatelywedged,attachedorsecuredsothattheycannotshift.CV11Receptaclesshallalwaysbeplacedinthepositionforwhichtheyweredesignedandbeprotectedagainstanypossibilityofbeingdamagedbyotherpackages.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/896CV12Whenpalletsloadedwitharticlesarestacked,eachtierofpalletsshallbeevenlydistributedoverthelowertier,ifnecessarybytheinterpositionofamaterialofadequatestrength.CV13Ifanysubstanceshaveleakedandbeenspilledinavehicleorcontainer,itmaynotbereuseduntilafterithasbeenthoroughlycleanedand,ifnecessary,disinfectedordecontaminated.Anyothergoodsandarticlescarriedinthesamevehicleorcontainershallbeexaminedforpossiblecontamination.CV14Goodsshallbeshieldedfromdirectsunlightandheatduringcarriage.Packagesshallbestoredonlyincool,well-ventilatedplacesawayfromheatsources.CV15See7.5.5.3.CV16toCV19(Reserved)CV20TheprovisionsofChapter5.3andspecialprovisionsV1andV8(5)and(6)shallnotapplyprovidedthatthesubstanceispackagedinaccordancewithpackingmethodOP1orOP2ofpackinginstructionP520in4.1.4.1,asrequired,andthetotalquantityofsubstancestowhichthisderogationappliespertransportunitislimitedto10kg.CV21Thetransportunitshallbethoroughlyinspectedpriortoloading.Beforecarriage,thecarriershallbeinformed:—abouttheoperationoftherefrigerationsystem,includingalistofthesuppliersofcoolantavailableenroute,—procedurestobefollowedintheeventoflossoftemperaturecontrol.InthecaseoftemperaturecontrolinaccordancewithmethodsR2orR4ofspecialprovisionV8(3)ofChapter7.2,asufficientquantityofnon-flammablerefrigerant(e.g.liquidnitrogenordryice),includingareasonablemarginforpossibledelays,shallbecarriedunlessameansofreplenishmentisassured.Packagesshallbesostowedastobereadilyaccessible.Thespecifiedcontroltemperatureshallbemaintainedduringthewholetransportoperation,includingloadingandunloading,aswellasanyintermediatestops.CV22Packagesshallbeloadedsothatafreecirculationofairwithintheloadingspaceprovidesauniformtemperatureoftheload.Ifthecontentsofonevehicleorlargecontainerexceed5000kgofflammablesolidsand/ororganicperoxides,theloadshallbedividedintostacksofnotmorethan5000kgseparatedbyairspacesofatleast0,05m.CV23Whenhandlingpackages,specialmeasuresshallbetakentoensurethattheydonotcomeintocontactwithwater.CV24Beforeloading,vehiclesandcontainersshallbethoroughlycleanedandinparticularbefreeofanycombustibledebris(straw,hay,paper,etc.).Theuseofreadilyflammablematerialsforstowingpackagesisprohibited.CV25(1)Packagesshallbesostowedthattheyarereadilyaccessible.(2)Whenpackagesaretobecarriedatanambienttemperatureofnotmorethan15°Correfrigerated,thetemperatureshallbemaintainedwhenunloadingorduringstorage.(3)Packagesshallbestoredonlyincoolplacesawayfromsourcesofheat.CV26Thewoodenpartsofavehicleorcontainerwhichhavecomeintocontactwiththesesubstancesshallberemovedandburnt.CV27(1)Packagesshallbesostowedthattheyarereadilyaccessible.(2)Whenpackagesaretobecarriedrefrigerated,thefunctioningofthecoolingchainshallbeensuredwhenunloadingorduringstorage.(3)Packagesshallonlybestoredincoolplacesawayfromsourcesofheat.CV28See7.5.4.CV29toCV32(Reserved)OfficialJournaloftheEuropeanUnionEN26.1.2004L18/897CV33Notes1.‘Criticalgroup’meansagroupofmembersofthepublicwhichisreasonablyhomogeneouswithrespecttoitsexposureforagivenradiationsourceandgivenexposurepathwayandistypicalofindividualreceivingthehighesteffectivedosebythegivenexposurepathwayfromthegivensource.2.‘Membersofthepublic’meansinageneralsense,anyindividualsinthepopulationexceptwhensubjecttooccupationalormedicalexposure.3.‘Workers’areanypersonswhowork,whetherfulltime,part-timeortemporarily,foranemployerandwhohaverecognisedrightsanddutiesinrelationtooccupationalradiationprotection.(1)Segregation(1.1)Packages,overpacks,containersandtanksshallbesegregatedduringcarriage:(a)fromareaswherepersonsotherthanthosereferredtoinparagraph(c)haveregularaccess;(i)inaccordancewithTableAbelow;or(ii)byadistancecalculatedtoensuremembersofthecriticalgroupinthatareareceivelessthan1mSvperyear;and(b)fromundevelopedphotographicfilmandmailbags,inaccordancewithTableBbelow;NoteMailbagsshallbeassumedtocontainundevelopedfilmandplatesandthereforebeseparatedfromradioactivematerialinthesameway.and(c)fromworkersinregularlyoccupiedworkingareaseither;(i)inaccordancewithTableA;or(ii)byadistancecalculatedtoensurethatworkersinthatareareceivelessthan5mSvperyear;NoteWorkerssubjecttoindividualmonitoringforthepurposeofradiationprotectionshallnotbeconsideredforthepurposeofsegregation.and(d)fromotherdangerousgoodsinaccordancewith7.5.2.1.TableA:MinimumdistancesbetweenpackagesofcategoryII-YELLOWorofcategoryIII-YELLOWandpersonsSumoftransportindexesnotmorethanExposuretimeperyear(hours)AreaswheremembersofthepublichaveregularaccessRegularlyoccupiedworkingareas5025050250Segregationdistanceinmetres,noshieldingmaterialintervening,from:2130,5141,540,51,582,561,02,51237,51,032049,51,543051225405,513,52,55,5506,515,536,5OfficialJournaloftheEuropeanUnionEN26.1.2004L18/898(1.2)CategoryII-YELLOWorIII-YELLOWpackagesoroverpacksshallnotbecarriedincompartmentsoccupiedbypassengers,exceptthoseexclusivelyreservedforcouriersspeciallyauthorisedtoaccompanysuchpackagesoroverpacks.(1.3)Nopersonsotherthanthedriverandtheothermembersofthecrewshallbepermittedinvehiclescarryingpackages,overpacksorcontainersbearingcategoryII-YELLOWorIII-YELLOWlabels.(1.4)Radioactivematerialshallbesufficientlysegregatedfromundevelopedphotographicfilm.Thebasisfordeterminingsegregationdistancesforthispurposeshallbethattheradiationexposureofundevelopedphotographicfilmduetothecarriageofradioactivematerialbelimitedto0,1mSvperconsignmentofsuchfilm(seeTableB).TableB:MinimumdistancesbetweenpackagesofcategoryII-YELLOWorofcategoryIII-YELLOWandpackagesbearingtheword‘FOTO’,ormailbagsTotalnumberofpackagesnotmorethanSumoftransportindexesnotmorethanJourneyorstorageduration,inhoursCATEGORY124102448120240III-YELLOWII-YELLOWMinimumdistancesinmetres0,20,50,50,50,511230,50,50,50,511235110,50,5112357220,5111,5347944111,53469138811,524681318110101234791420220201,53469132030330302357111625354404034581318304055050346914203245(2)ActivitylimitsThetotalactivityinavehicle,forcarriageofLSAmaterialorSCOinIndustrialPackagesType1(TypeIP-1),Type2(TypeIP-2),Type3(TypeIP-3)orunpackaged,shallnotexceedthelimitsshowninTableC.TableC:VehicleactivitylimitsforLSAmaterialandSCOinindustrialpackagesorunpackagedNatureofmaterialorobjectActivitylimitforvehicleLSA-INolimitLSA-IIandLSA-IIINon-combustiblesolidsNolimitLSA-IIandLSA-IIICombustiblesolids,andallliquidsandgases100A2SCO100A2OfficialJournaloftheEuropeanUnionEN26.1.2004L18/899(3)Stowageduringcarriageandstorageintransit(3.1)Consignmentsshallbesecurelystowed.(3.2)Providedthatitsaveragesurfaceheatfluxdoesnotexceed15W/m2andthattheimmediatelysurroundingcargoisnotinbags,apackageoroverpackmaybecarriedorstoredamongpackagedgeneralcargowithoutanyspecialstowageprovisionsexceptasmaybespecificallyrequiredbythecompetentauthorityinanapplicableapprovalcertificate.(3.3)Loadingofcontainersandaccumulationofpackages,overpacksandcontainersshallbecontrolledasfollows:(a)Exceptundertheconditionofexclusiveuse,thetotalnumberofpackages,overpacksandcontainersaboardasinglevehicleshallbesolimitedthatthetotalsumofthetransportindexesaboardthevehicledoesnotexceedthevaluesshowninTableD.ForconsignmentsofLSA-Imaterialthereshallbenolimitonthesumofthetransportindexes;(b)Whereaconsignmentiscarriedunderexclusiveuse,thereshallbenolimitonthesumofthetransportindexesaboardasinglevehicle;(c)Theradiationlevelunderroutineconditionsofcarriageshallnotexceed2mSv/hatanypointon,and0,1mSv/hat2mfrom,theexternalsurfaceofthevehicle;(d)ThetotalsumofthecriticalitysafetyindexesinacontainerandaboardavehicleshallnotexceedthevaluesshowninTableE.TableD:TransportindexlimitsforcontainersandvehiclesnotunderexclusiveuseTypeofcontainerorvehicleLimitontotalsumoftransportindexesinacontaineroraboardavehicleSmallcontainer50Largecontainer50Vehicle50TableE:CriticalitysafetyindexforcontainersandvehiclescontainingfissilematerialTypeofcontainerorvehicleLimitontotalsumofcriticalitysafetyindexesNotunderexclusiveuseUnderexclusiveuseSmallcontainer50n.a.Largecontainer50100Vehicle50100(3.4)Anypackageoroverpackhavingeitheratransportindexgreaterthan10,oranyconsignmenthavingacriticalitysafetyindexgreaterthan50,shallbecarriedonlyunderexclusiveuse.(3.5)Forconsignmentsunderexclusiveuse,theradiationlevelshallnotexceed:(a)10mSv/hatanypointontheexternalsurfaceofanypackageoroverpack,andmayonlyexceed2mSv/hprovidedthat:(i)thevehicleisequippedwithanenclosurewhich,duringroutineconditionsofcarriage,preventstheaccessofunauthorisedpersonstotheinterioroftheenclosure;(ii)provisionsaremadetosecurethepackageoroverpacksothatitspositionwithinthevehicleenclosureremainsfixedduringroutineconditionsofcarriage,and(iii)thereisnoloadingorunloadingduringtheshipment;(b)2mSv/hatanypointontheoutersurfacesofthevehicle,includingtheupperandlowersurfaces,or,inthecaseofanopenvehicle,atanypointontheverticalplanesprojectedfromtheouteredgesofthevehicle,ontheuppersurfaceoftheload,andonthelowerexternalsurfaceofthevehicle;and(c)0,1mSv/hatanypoint2mfromtheverticalplanesrepresentedbytheouterlateralsurfacesofthevehicle,or,iftheloadiscarriedinanopenvehicle,atanypoint2mfromtheverticalplanesprojectedfromtheouteredgesofthevehicle.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/900(4)Segregationofpackagescontainingfissilematerialduringcarriageandstorageintransit(4.1)Thenumberofpackages,overpacksandcontainerscontainingfissilematerialstoredintransitinanyonestorageareashallbesolimitedthatthetotalsumofthecriticalitysafetyindexesinanygroupofsuchpackages,overpacksorcontainersdoesnotexceed50.Groupsofsuchpackages,overpacksandcontainersshallbestoredsoastomaintainaspacingofatleast6mfromothergroupsofsuchpackages,overpacksorcontainers.(4.2)Wherethetotalsumofthecriticalitysafetyindexesonboardavehicleorinacontainerexceeds50,aspermittedinTableE,storageshallbesuchastomaintainaspacingofatleast6mfromothergroupsofpackages,overpacksorcontainerscontainingfissilematerialorothervehiclescarryingradioactivematerial.(5)Damagedorleakingpackages,contaminatedpackagings(5.1)Ifitisevidentthatapackageisdamagedorleaking,orifitissuspectedthatthepackagemayhaveleakedorbeendamaged,accesstothepackageshallberestrictedandaqualifiedpersonshall,assoonaspossible,assesstheextentofcontaminationandtheresultantradiationlevelofthepackage.Thescopeoftheassessmentshallincludethepackage,thevehicle,theadjacentloadingandunloadingareas,and,ifnecessary,allothermaterialwhichhasbeencarriedinthevehicle.Whennecessary,additionalstepsfortheprotectionofpersonspropertyandtheenvironment,inaccordancewithprovisionsestablishedbythecompetentauthority,shallbetakentoovercomeandminimisetheconsequencesofsuchleakageordamage.(5.2)Packagesdamagedorleakingradioactivecontentsinexcessofallowablelimitsfornormalconditionsofcarriagemayberemovedtoanacceptableinterimlocationundersupervision,butshallnotbeforwardeduntilrepairedorreconditionedanddecontaminated.(5.3)Avehicleandequipmentusedregularlyforthecarriageofradioactivematerialshallbeperiodicallycheckedtodeterminethelevelofcontamination.Thefrequencyofsuchchecksshallberelatedtothelikelihoodofcontaminationandtheextenttowhichradioactivematerialiscarried.(5.4)Exceptasprovidedinparagraph(5.5),anyvehicle,orequipmentorpartthereofwhichhasbecomecontaminatedabovethelimitsspecifiedin4.1.9.1.2inthecourseofcarriageofradioactivematerial,orwhichshowsaradiationlevelinexcessof5µSv/hatthesurface,shallbedecontaminatedassoonaspossiblebyaqualifiedpersonandshallnotbere-usedunlessthenon-fixedcontaminationdoesnotexceedthelimitsspecifiedin4.1.9.1.2,andtheradiationlevelresultingfromthefixedcontaminationonsurfacesafterdecontaminationislessthan5µSv/hatthesurface.(5.5)Anoverpack,container,tank,intermediatebulkcontainerorvehiclededicatedtothecarriageofradioactivematerialunderexclusiveuseshallbeexceptedfromtherequirementsofthepreviousparagraph(5.4)andin4.1.9.1.4solelywithregardtoitsinternalsurfacesandonlyforaslongasitremainsunderthatspecificexclusiveuse.(6)OtherprovisionsWhereaconsignmentisundeliverable,theconsignmentshallbeplacedinasafelocationandthecompetentauthorityshallbeinformedassoonaspossibleandarequestmadeforinstructionsonfurtheraction.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/901ANNEXBPROVISIONSCONCERNINGTRANSPORTEQUIPMENTANDTRANSPORTOPERATIONSOfficialJournaloftheEuropeanUnionEN26.1.2004L18/902Part8REQUIREMENTSFORVEHICLECREWS,EQUIPMENT,OPERATIONANDDOCUMENTATIONCHAPTER8.1Generalrequirementsconcerningtransportunitsandequipmentonboard8.1.1.TransportunitsAtransportunitloadedwithdangerousgoodsmayinnocaseincludemorethanonetrailer(orsemi-trailer).8.1.2.Documentstobecarriedonthetransportunit8.1.2.1.Inadditiontothedocumentsrequiredunderotherregulations,thefollowingdocumentsshallbecarriedonthetransportunit:(a)thetransportdocumentsprescribedin5.4.1,coveringallthedangerousgoodscarriedand,whenappropriate,thecontainerpackingcertificateprescribedin5.4.2;(b)theinstructionsinwritingprescribedin5.4.3,relatingtoallthedangerousgoodscarried;(c)acopyofthemaintextofthespecialagreement(s)concludedinaccordancewithChapter1.5,ifcarriageiscarriedoutonthebasisofsuchagreement(s).8.1.2.2.WheretheprovisionsofthisDirectiverequirethefollowingdocumentstobedrawnup,theyshalllikewisebecarriedonthetransportunit:(a)thecertificateofapprovalreferredtoin9.1.2foreachtransportunitorelementthereof;(b)thedriver'strainingcertificateprescribedin8.2.1;(c)thepermitauthorisingthetransportoperation,asprescribedin5.4.1.2.1(c),5.4.1.2.3.3,2.2.41.1.13and2.2.52.1.8.8.1.2.3.Theinstructionsinwritingprescribedin5.4.3shallbekeptinareadilyidentifiableforminthedriver'scab.Thecarriershallensurethatthedriversconcernedunderstandandarecapableofcarryingouttheseinstructionsproperly.8.1.2.4.Instructionsinwritingwhicharenotapplicabletothegoodswhichareonboardthevehicleshallbekeptseparatefrompertinentdocumentsinsuchawayastopreventconfusion.8.1.3.PlacardingandmarkingTransportunitscarryingdangerousgoodsshallbeplacardedandmarkedinconformitywithChapter5.3.8.1.4.Fire-fightingappliances8.1.4.1.Everytransportunitcarryingdangerousgoodsshallbeequippedwith:(a)atleastoneportablefireextinguisherofminimumcapacity2kgdrypowder(orequivalentratingforsuitableextinguishants)suitableforfightingafireintheengineorcabofthetransportunit,andsuchthat,ifitisusedtofightafireinvolvingtheload,itdoesnotaggravatethefireand,ifpossible,controlsit;however,ifthevehicleisequippedwithafixedfireextinguisher,automaticoreasilybroughtintoactionforfightingafireintheengine,theportableextinguisherneednotbesuitableforfightingafireintheengine;OfficialJournaloftheEuropeanUnionEN26.1.2004L18/903(b)inadditiontotheequipmentprescribedunder(a),atleastoneportablefireextinguisherofminimumcapacity6kgdrypowder(orequivalentratingforsuitableextinguishants)suitableforfightingatyre/brakefireoroneinvolvingtheload,andsuchthat,ifitisusedtofightafireintheengineorcabofthetransportunit,itdoesnotaggravatethefire.Motorvehicleswithamaximumpermissiblemassof3,5tonnesorlessmaybeequippedwithaportablefireextinguisherofaminimumcapacityof2kgofpowder.8.1.4.2.Theextinguishingagentscontainedinthefireextinguisherswithwhichatransportunitisequippedshallbesuchthattheyarenotliabletoreleasetoxicgasesintothedriver'scaborundertheinfluenceoftheheatofthefire.8.1.4.3.Theportablefireextinguishersconformingtotheprovisionsof8.1.4.1aboveshallbefittedwithasealverifyingthattheyhavenotbeenused.Inaddition,theyshallbearamarkofcompliancewithastandardrecognisedbyacompetentauthorityandaninscriptionindicatingtheexpirydate(month,year).8.1.5.MiscellaneousequipmentEverytransportunitcarryingdangerousgoodsshallbeequippedwith:(a)foreachvehicle,atleastonescotchofasizesuitedtotheweightofthevehicleandtothediameterofthewheels;(b)thenecessaryequipmenttotakethegeneralactionsreferredtointhesafetyinstructionssetoutin5.4.3,inparticular:—twoself-standingwarningsigns(e.g.reflectiveconesortrianglesorflashingamberlightswhichareindependentfromtheelectricalequipmentofthevehicle),—asuitablewarningvestorwarningclothing(e.g.asdescribedinEuropeanStandardEN471)foreachmemberofthevehiclecrew,—apocketlamp(seealso8.3.4)foreachmemberofthevehiclecrew,—arespiratoryprotectivedeviceinconformitywithadditionalrequirementS7(seeChapter8.5)ifthisadditionalrequirementappliesaccordingtotheindicationincolumn19ofTableAofChapter3.2;(c)thenecessaryequipmenttotaketheadditionalandspecialactionsreferredtointheinstructionsinwritingsetoutin5.4.3.CHAPTER8.2Requirementsconcerningthetrainingofthevehiclecrew8.2.1.Generalrequirementsconcerningthetrainingofdrivers8.2.1.1.Driversofvehicleswithapermissiblemaximummassexceeding3,5tonnescarryingdangerousgoods,driversofvehiclesreferredtoin8.2.1.3anddriversofothervehiclesreferredtoin8.2.1.4shallholdacertificateissuedbythecompetentauthorityorbyanyorganisationrecognisedbythatauthoritystatingthattheyhaveparticipatedinatrainingcourseandpassedanexaminationontheparticularrequirementsthathavetobemetduringcarriageofdangerousgoods.8.2.1.2.Driversofvehiclesspecifiedin8.2.1.1shallattendabasictrainingcourse.Trainingshallbegivenintheformofacourseapprovedbythecompetentauthority.Itsmainobjectivesaretomakedriversawareofhazardsarisinginthecarriageofdangerousgoodsandtogivethembasicinformationindispensableforminimisingthelikelihoodofanincidenttakingplaceand,ifitdoes,toenablethemtotakemeasureswhichmayprovenecessaryfortheirownsafetyandthatofthepublicandtheenvironment,forlimitingtheeffectsofanincident.Thistraining,whichshallincludeindividualpracticalexercises,shallactasthebasisoftrainingforallcategoriesofdriverscoveringatleastthesubjectsdefinedin8.2.2.3.2.8.2.1.3.Driversofvehiclescarryingdangerousgoodsinfixedtanksordemountabletankswithacapacityexceeding1m3,driversofbattery-vehicleswithatotalcapacityexceeding1m3anddriversofvehiclescarryingdangerousgoodsintank-containers,portabletanksorMEGCswithanindividualcapacityexceeding3m3onatransportunit,shallattendaspecialisationtrainingcourseforcarriageintankscoveringatleastthesubjectsdefinedin8.2.2.3.3.8.2.1.4.Irrespectiveofthepermissiblemaximummassofthevehicle,driversofvehiclescarryingsubstancesorarticlesofClass1(seeadditionalrequirementS1inChapter8.5)orcertainradioactivematerial(seespecialprovisionsS11andS12inChapter8.5)shallattendspecialisationtrainingcoursescoveringatleastthesubjectsdefinedin8.2.2.3.4or8.2.2.3.5.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/9048.2.1.5.Bymeansofappropriateendorsementsonhiscertificatemadeeveryfiveyearsbythecompetentauthorityorbyanyorganisationrecognisedbythatauthority,avehicledrivershallbeabletoshowthathehasintheyearbeforethedateofexpiryofhiscertificatecompletedarefreshertrainingcourseandhaspassedcorrespondingexaminations.Thenewperiodofvalidityshallbeginwiththedateofexpiryofthecertificate.8.2.1.6.Initialorrefresherbasictrainingcoursesandinitialorrefresherspecialisationtrainingcoursesmaybegivenintheformofcomprehensivecourses,conductedintegrally,onthesameoccasionandbythesametrainingorganisation.8.2.1.7.Initialtrainingcourses,refreshercourses,practicalexercises,examinationsandtheroleofcompetentauthoritiesshallcomplywiththeprovisionsof8.2.2.8.2.1.8.Alltrainingcertificatesconformingtotherequirementsofthissectionandissuedinaccordancewiththemodelshownin8.2.2.8.3bythecompetentauthorityofaMemberStateorbyanyorganisationrecognisedbythatauthorityshallbeacceptedduringtheirperiodofvaliditybythecompetentauthoritiesofotherMemberStates.8.2.1.9.Thecertificateshallbepreparedinthelanguageoroneofthelanguagesofthecountryofthecompetentauthoritywhichissuedthecertificateorrecognisedtheissuingorganisationand,ifthislanguageisnotEnglish,FrenchorGerman,alsoinEnglish,FrenchorGerman,exceptwhereotherwiseprovidedbyagreementsconcludedbetweenthecountriesconcernedwiththetransportoperation.8.2.2.Specialrequirementsconcerningthetrainingofdrivers8.2.2.1.Thenecessaryknowledgeandskillsshallbeimpartedbytrainingcoveringtheoreticalcoursesandpracticalexercises.Theknowledgeshallbetestedinanexamination.8.2.2.2.Thetrainingprovidershallensurethatthetraininginstructorshaveagoodknowledgeof,andtakeintoconsideration,recentdevelopmentsinregulationsandtrainingrequirementsrelatingtothecarriageofdangerousgoods.Thetrainingshallbepractice-related.Thetrainingprogrammeshallconformwiththeapproval,onthesubjectssetoutin8.2.2.3.2to8.2.2.3.5.Theinitialtrainingandrefreshertrainingshallalsoincludeindividualpracticalexercises(see8.2.2.4.5).8.2.2.3.Structureoftraining8.2.2.3.1.Initialandrefreshertrainingshallbegivenintheformofabasiccourseand,whenapplicable,specialisationcourses.8.2.2.3.2.Subjectstobecoveredbythebasiccoursewillbe,atleast:(a)generalrequirementsgoverningthecarriageofdangerousgoods;(b)maintypesofhazard;(c)informationonenvironmentalprotectioninthecontrolofthetransferofwastes;(d)preventiveandsafetymeasuresappropriatetothevarioustypesofhazard;(e)whattodoafteranaccident(firstaid,roadsafety,basicknowledgeabouttheuseofprotectiveequipment,etc.);(f)marking,labelling,placardingandorange-colouredplatemarking;(g)whatadrivershouldandshouldnotdoduringthecarriageofdangerousgoods;(h)purposeandthemethodofoperationoftechnicalequipmentonvehicles;(i)prohibitionsonmixedloadinginthesamevehicleorcontainer;(j)precautionstobetakenduringloadingandunloadingofdangerousgoods;(k)generalinformationconcerningcivilliability;(l)informationonmultimodaltransportoperations;(m)handlingandstowageofpackages.8.2.2.3.3.Specialsubjectstobecoveredbythespecialisationcourseforcarriageintanksshallbe,atleast:(a)behaviourofvehiclesontheroad,includingmovementsoftheload;(b)specificrequirementsofthevehicles;(c)generaltheoreticalknowledgeofthevariousanddifferentfillinganddischargesystems;(d)specificadditionalprovisionsapplicabletotheuseofthosevehicles(certificatesofapproval,approvalmarking,placardingandorange-colouredplatemarking,etc.).OfficialJournaloftheEuropeanUnionEN26.1.2004L18/9058.2.2.3.4.SpecialsubjectstobecoveredbythespecialisationcourseforthecarriageofsubstancesandarticlesofClass1shallbe,atleast:(a)specifichazardsrelatedtoexplosiveandpyrotechnicalsubstancesandarticles;(b)specificrequirementsconcerningmixedloadingofsubstancesandarticlesofClass1.8.2.2.3.5.SpecialsubjectstobecoveredbythespecialisationcourseforthecarriageofradioactivematerialofClass7shallbe,atleast:(a)specifichazardsrelatedtoionisingradiation;(b)specificrequirementsconcerningpacking,handling,mixedloadingandstowageofradioactivematerial;(c)specialmeasurestobetakenintheeventofanaccidentinvolvingradioactivematerial.8.2.2.4.Initialtrainingprogramme8.2.2.4.1.Theminimumdurationofthetheoreticalelementofeachinitialcourseorpartofthecomprehensivecourseshallbeasfollows:Basiccourse18teachingunits(1)Specialisationcourseforcarriageintanks12teachingunits(1)SpecialisationcourseforcarriageofsubstancesandarticlesofClass18teachingunitsSpecialisationcourseforcarriageofradioactivematerialofClass78teachingunits8.2.2.4.2.Thetotaldurationofthecomprehensivecoursemaybedeterminedbythecompetentauthority,whoshallmaintainthedurationofthebasiccourseandthespecialisationcoursefortanks,butmaysupplementitwithshortenedspecialisationcoursesforClasses1and7.8.2.2.4.3.Teachingunitsareintendedtolast45minutes.8.2.2.4.4.Normally,notmorethaneightteachingunitsarepermittedoneachdayofthecourse.8.2.2.4.5.Theindividualpracticalexercisesshalltakeplaceinconnectionwiththetheoreticaltraining,andshallatleastcoverfirstaid,fire-fightingandwhattodoincaseofanincidentoraccident.8.2.2.5.Refreshertrainingprogramme8.2.2.5.1.Refreshertrainingcoursesundertakenatregularintervalsservethepurposeofbringingthedrivers'knowledgeuptodate;theyshallcovernewtechnical,legalandsubstance-relateddevelopments.8.2.2.5.2.Refreshercoursesshallhavebeencompletedbeforetheperiodreferredtoin8.2.1.5hasexpired.8.2.2.5.3.Thedurationofeachrefreshercourseshallbeofatleastoneday.8.2.2.5.4.Normally,notmorethaneightteachingunitsshallbepermittedoneachdayofthecourse.8.2.2.6.Approvaloftraining8.2.2.6.1.Thetrainingcoursesshallbesubjecttoapprovalbythecompetentauthority.8.2.2.6.2.Approvalshallonlybegivenwithregardtoapplicationssubmittedinwriting.8.2.2.6.3.Thefollowingdocumentsshallbeattachedtotheapplicationforapproval:(a)adetailedtrainingprogrammespecifyingthesubjectstaughtandindicatingthetimescheduleandplannedteachingmethods;(b)qualificationsandfieldsofactivitiesoftheteachingpersonnel;(c)informationonthepremiseswherethecoursestakeplaceandontheteachingmaterialsaswellasonthefacilitiesforthepracticalexercises;(d)conditionsofparticipationinthecourses,suchasnumberofparticipants.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/906(1)Additionalteachingunitsarerequiredforpracticalexercisesreferredtoin8.2.2.4.5belowwhichwillvarydependingonthenumberofdriversunderinstruction.8.2.2.6.4.Thecompetentauthorityshallorganisethesupervisionoftrainingandexaminations.8.2.2.6.5.Approvalshallbegrantedinwritingbythecompetentauthoritysubjecttothefollowingconditions:(a)thetrainingshallbegiveninconformitywiththeapplicationdocuments;(b)thecompetentauthorityshallbegrantedtherighttosendauthorisedpersonstobepresentatthetrainingcoursesandexaminations;(c)thecompetentauthorityshallbeadvisedintimeofthedatesandtheplacesoftheindividualtrainingcourses;(d)theapprovalmaybewithdrawniftheconditionsofapprovalarenotcompliedwith.8.2.2.6.6.Theapprovaldocumentshallindicatewhetherthecoursesconcernedarebasicorspecialisationcourses,initialorrefreshercourses.8.2.2.6.7.Ifthetrainingbody,afteratrainingcoursehasbeengivenapproval,intendstomakeanyalterationswithrespecttosuchdetailsaswererelevanttotheapproval,itshallseekpermissioninadvancefromthecompetentauthority.Thisappliesinparticulartochangesconcerningthetrainingprogramme.8.2.2.7.Examinations8.2.2.7.1.Examinationsfortheinitialbasiccourse8.2.2.7.1.1.Aftercompletionofthebasictraining,includingthepracticalexercises,anexaminationshallbeheldonthebasiccourse.8.2.2.7.1.2.Intheexamination,thecandidatehastoprovethathehastheknowledge,insightandskillforthepracticeofprofessionaldriverofvehiclescarryingdangerousgoodsasprovidedinthebasictrainingcourse.8.2.2.7.1.3.Forthispurposethecompetentauthority,ortheexaminationbodyapprovedbythatauthority,shallprepareacatalogueofquestionswhichrefertotheitemssummarisedin8.2.2.3.2.Questionsintheexaminationshallbedrawnfromthiscatalogue.Thecandidatesshallnothaveanyknowledgeofthequestionsselectedfromthecataloguepriortotheexamination.8.2.2.7.1.4.Asingleexaminationforcomprehensivecoursesmaybeheld.8.2.2.7.1.5.Eachcompetentauthorityshallsupervisethemodalitiesoftheexamination.8.2.2.7.1.6.Theexaminationshalltaketheformofawrittenexaminationoracombinationofawrittenandoralexamination.Eachcandidateshallbeaskedatleast25writtenquestions.Thedurationoftheexaminationshallbeatleast45minutes.Thequestionsmaybeofavaryingdegreeofdifficultyandbeallocatedadifferentweighting.8.2.2.7.2.Examinationsforinitialspecialisationcoursesforcarriageintanksorforcarriageofexplosivesubstancesandarticlesorradioactivematerial.8.2.2.7.2.1.Afterhavingsattheexaminationonthebasiccourseandafterhavingattendedthespecialisationcourseforcarriageintanksorforthecarriageofexplosiveorradioactivematerial,thecandidateshallbeallowedtotakepartinthecorrespondingexamination.8.2.2.7.2.2.Thisexaminationshallbeheldandsupervisedonthesamebasisasin8.2.2.7.1.8.2.2.7.2.3.Atleast15questionsshallbeaskedwithrespecttoeachspecialisationcourse.8.2.2.7.3.Examinationsforrefreshercourses8.2.2.7.3.1.Afterhavingundertakenarefreshertrainingcoursethecandidateshallbeallowedtotakepartinthecorrespondingexamination.8.2.2.7.3.2.Theexaminationshallbeheldandsupervisedonthesamebasisassetoutin8.2.2.7.1.8.2.2.7.3.3.Atleast15questionsshallbeaskedwithrespecttotherefreshertrainingcourse.8.2.2.8.Certificateofdriver'straining8.2.2.8.1.Accordingto8.2.1.8,thecertificateshallbeissued:(a)aftercompletionofabasictrainingcourse,providedthecandidatehassuccessfullypassedtheexaminationinaccordancewith8.2.2.7.1;(b)ifapplicable,aftercompletionofaspecialisationcourseforcarriageintanksorcarriageofexplosivesubstancesorarticlesorofradioactivematerial,orafterhavingacquiredtheknowledgereferredtoinspecialprovisionsS1andS11inChapter8.5,providedthecandidatehassuccessfullypassedanexaminationinaccordancewith8.2.2.7.2.8.2.2.8.2.Thecertificateshallberenewedifthecandidatefurnishesproofofhisparticipationinarefreshercourseinaccordancewith8.2.1.5andifhehassuccessfullypassedanexaminationinaccordancewith8.2.2.7.3.8.2.2.8.3.Thecertificateshallhavethelayoutofthemodelbelow.ItisrecommendedthattheformatshallbethesameastheEuropeannationaldrivingpermit,namelyA7(105mm×74mm),oradoublesheetthatcanbefoldedtothatformat.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/907OfficialJournaloftheEuropeanUnionEN26.1.2004L18/9088.2.3.Trainingofallpersons,otherthanthedriversreferredtoin8.2.1,involvedinthecarriageofdangerousgoodsbyroadPersonswhosedutiesconcernthecarriageofdangerousgoodsbyroadshallhavereceivedtrainingintherequirementsgoverningthecarriageofsuchgoodsappropriatetotheirresponsibilitiesanddutiesaccordingtoChapter1.3.Thisrequirementshallapplytoindividualssuchaspersonnelwhoareemployedbytheroadvehicleoperatorortheconsignor,personnelwholoadorunloaddangerousgoods,personnelinfreightforwardingorshippingagenciesanddriversnotreferredtoin8.2.1.CHAPTER8.3Miscellaneousrequirementstobecompliedwithbythevehiclecrew8.3.1.PassengersApartfrommembersofthevehiclecrew,nopassengersmaybecarriedintransportunitscarryingdangerousgoods.8.3.2.Useoffire-fightingappliancesThecrewofthevehicleshallknowhowtousethefire-fightingappliances.8.3.3.ProhibitiononopeningpackagesAdriveroradriver'sassistantmaynotopenapackagecontainingdangerousgoods.8.3.4.PortablelightingapparatusAvehiclemaynotbeenteredbypersonscarryinglightingapparatuscomprisingaflame.Inaddition,thelightingapparatususedshallnotexhibitanymetalsurfaceliabletoproducesparks.8.3.5.ProhibitiononsmokingSmokingshallbeprohibitedduringhandlingoperationsinthevicinityofvehiclesandinsidethevehicles.8.3.6.RunningtheengineduringloadingorunloadingExceptwheretheenginehastobeusedtodrivethepumpsorotherappliancesforloadingorunloadingthevehicleandthelawsofthecountryinwhichthevehicleisoperatingpermitsuchuse,theengineshallbeshutoffduringloadingandunloadingoperations.8.3.7.UseoftheparkingbrakeNotransportunitcarryingdangerousgoodsmaybeparkedwithouttheparkingbrakesbeingapplied.CHAPTER8.4RequirementsconcerningthesupervisionofvehiclesVehiclescarryingdangerousgoodsinthequantitiesshowninspecialprovisionsS1(6)andS14toS21ofChapter8.5foragivensubstanceaccordingtocolumn19ofTableAofChapter3.2shallbesupervisedoralternativelymaybeparked,unsupervised,inasecuredepotorsecurefactorypremises.Ifsuchfacilitiesarenotavailable,thevehicle,afterhavingbeenproperlysecured,maybeparkedinanisolatedpositionmeetingtherequirementsof(a),(b)or(c):(a)avehicleparksupervisedbyanattendantwhohasbeennotifiedofthenatureoftheloadandthewhereaboutsofthedriver;(b)apublicorprivatevehicleparkwherethevehicleisnotlikelytosufferdamagefromothervehicles;or(c)asuitableopenspaceseparatedfromthepublichighwayandfromdwellings,wherethepublicdoesnotnormallypassorassemble;Theparkingfacilitiespermittedin(b)shallbeusedonlyifthosedescribedin(a)arenotavailable,andthosedescribedin(c)maybeusedonlyiffacilitiesdescribedin(a)and(b)arenotavailable.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/909CHAPTER8.5AdditionalrequirementsrelatingtoparticularclassesorsubstancesInadditiontotherequirementsofChapters8.1to8.4,whenreferenceismadetothemincolumn19ofTableAofChapter3.2,thefollowingrequirementsshallapplytothecarriageofthesubstancesorarticlesconcerned.IntheeventofconflictwiththerequirementsofChapters8.1to8.4,therequirementsofthischaptershalltakeprecedence.S1:Additionalrequirementsconcerningthecarriageofexplosivesubstancesandarticles(Class1)1.Specialtrainingofdrivers(a)irrespectiveofthepermissiblemaximummassofthevehicle,therequirementsof8.2.1shallapplytodriversofvehiclescarryingsubstancesorarticlesofClass1;(b)driversofvehiclescarryingsubstancesorarticlesofClass1shallattendaspecialisationtrainingcoursecoveringatleastthesubjectsdefinedin8.2.2.3.4;(c)if,accordingtootherregulationsapplicableinaMemberState,adriverhasfollowedequivalenttrainingunderadifferentregimeorforadifferentpurpose,coveringthesubjectsreferredtoin(b),thespecialisationcoursemaybetotallyorpartiallydispensedwith.2.ApprovedofficialIfthenationalregulationssoprovide,thecompetentauthorityofaMemberStatemayrequireanapprovedofficialtobecarriedinthevehicleatthecarrier'sexpense.3.ProhibitionoffireandnakedflameTheuseoffireornakedflameshallbeprohibitedonvehiclescarryingsubstancesandarticlesofClass1,intheirvicinityandduringtheloadingandunloadingofthesesubstancesandarticles.4.Placesofloadingandunloading(a)loadingorunloadingofsubstancesandarticlesofClass1shallnottakeplaceinapublicplaceinabuilt-upareawithoutspecialpermissionfromthecompetentauthorities;(b)loadingorunloadingofsubstancesandarticlesofClass1inapublicspaceelsewherethaninabuilt-upareawithoutpriornoticethereofhavingbeengiventothecompetentauthoritiesshallbeprohibited,unlessoperationsareurgentlynecessaryforreasonsofsafety;(c)if,foranyreason,handlingoperationshavetobecarriedoutinapublicplace,thensubstancesandarticlesofdifferentkindsshallbeseparatedaccordingtothelabels;(d)whenvehiclescarryingsubstancesandarticlesofClass1areobligedtostopforloadingorunloadingoperationsinapublicplace,adistanceofatleast50mshallbemaintainedbetweenthestationaryvehicles.5.Convoys(a)WhenvehiclescarryingsubstancesandarticlesofClass1travelinconvoy,adistanceofnotlessthan50mshallbemaintainedbetweeneachtransportunitandthenext.(b)Thecompetentauthoritymaylaydownrulesfortheorderorcompositionofconvoys.6.SupervisionofvehiclesTherequirementsofChapter8.4shallbeapplicableonlywhensubstancesandarticlesofClass1havingatotalmassofexplosivesubstanceofmorethan50kgarecarriedinavehicle.Inaddition,thesesubstancesandarticlesshallbesupervisedatalltimesinordertopreventanymaliciousactandtoalertthedriverandthecompetentauthoritiesintheeventoflossorfire.Emptyuncleanedpackagingsareexempted.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/910S2:Additionalrequirementsconcerningthecarriageofflammableliquidsorgases1.PortablelampsClosedvehiclescarryingliquidshavingaflash-pointofnotmorethan61°CorflammablesubstancesorarticleofClass2,shallnotbeenteredbypersonscarryinglightingapparatusotherthanportablelampssodesignedandconstructedthattheycannotigniteanyflammablevapoursorgaseswhichmayhavepenetratedintotheinteriorofthevehicle.2.OperationofcombustionheatersduringloadingorunloadingTheoperationofcombustionheatersofvehiclesoftypeFL(seePart9)isforbiddenduringloadingandunloadingandatloadingsites.3.PrecautionsagainstelectrostaticchargesInthecaseofvehiclesoftypeFL(seePart9),agoodelectricalconnectionfromthevehiclechassistoearthshallbeestablishedbeforetanksarefilledoremptied.Inaddition,therateoffillingshallbelimited.S3:SpecialprovisionsconcerningthecarriageofinfectioussubstancesFortransportunitscarryingdangeroussubstancesofClass6.2,therequirementsof8.1.4.1(b),8.1.4.3and8.3.4shallnotapply.S4:AdditionalrequirementsconcerningcarriageundercontrolledtemperaturesMaintenanceoftheprescribedtemperatureisessentialforsafecarriage.Ingeneral,thereshallbe:—thoroughinspectionofthetransportunitpriortoloading,—instructionstothecarrierabouttheoperationoftherefrigerationsystem,includingalistofthesuppliersofcoolantavailableenroute,—procedurestobefollowedintheeventoflossofcontrol,—regularmonitoringofoperatingtemperatures,and—availabilityofaback-uprefrigerationsystemorspareparts.Thetemperatureoftheairspacewithinthetransportunitshallbemeasuredbytwoindependentsensorsandtheoutputshallbesorecordedthattemperaturechangesarereadilydetectable.Thetemperatureshallbecheckedeveryfourtosixhoursandlogged.Ifthecontroltemperatureisexceededduringcarriage,analertprocedureshallbeinitiatedinvolvinganynecessaryrepairstotherefrigerationequipmentoranincreaseinthecoolingcapacity(e.g.byaddingliquidorsolidcoolant).Thereshallalsobefrequentcheckingofthetemperatureandpreparationsforimplementationoftheemergencyprocedures.Iftheemergencytemperature(seealso2.2.41.1.17and2.2.52.1.15to2.2.52.1.18)isreached,theemergencyproceduresshallbesetinoperation.S5:SpecialprovisionscommontothecarriageofradioactivematerialofClass7inexceptedpackages(UNNos2908,2909,2910and2911)onlyTherequirementsoftheinstructionsinwritingof8.1.2.1(b)andof8.2.1,8.3.1and8.3.4shallnotapply.S6:SpecialprovisionscommontothecarriageofradioactivematerialofClass7otherthaninexceptedpackagesTheprovisionsof8.3.1shallnotapplytovehiclescarryingonlypackages,overpacksorcontainersbearingcategoryI-WHITElabels.Theprovisionsof8.3.4shallnotapplyprovidedthereisnosubsidiaryrisk.S7:OtheradditionalrequirementsorspecialprovisionsWhengasesorarticlesdesignatedwithlettersT,TO,TF,TC,TFC,TOCarebeingcarried,eachmemberofthevehiclecrewshallbeprovidedwitharespiratoryprotectivedeviceenablingthemtoescape(e.g.escapehoodormaskwithacombinedgas/particlecartridgeA1B1E1K1-P1orA2B2E2K2-P2,asdescribedinEuropeanstandardEN141).S8:Whenatransportunitisloadedwithmorethan2000kgofthesesubstances,stopsforservicerequirementsshallasfaraspossiblenotbemadenearinhabitedplacesorfrequentedplaces.Alongerstopnearsuchplacesispermissibleonlywiththeconsentofthecompetentauthorities.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/911S9:Duringthecarriageofthesesubstances,stopsforservicerequirementsshallasfaraspossiblenotbemadenearinhabitedplacesorfrequentedplaces.Alongerstopnearsuchplacesispermissibleonlywiththeconsentofthecompetentauthorities.S10:DuringtheperiodApriltoOctober,whenavehicleisstationary,thepackagesshall,ifthelegislationofthecountryinwhichthevehicleishaltedsorequires,beeffectivelyprotectedagainsttheactionofthesun,e.g.bymeansofsheetsplacednotlessthan20cmabovetheload.S11:1.Irrespectiveofthepermissiblemaximummassofthevehicle,therequirementsof8.2.1shallapply.2.Driversshallattendaspecialisationtrainingcoursecoveringatleastthesubjectsdefinedin8.2.2.3.5.3.If,accordingtootherregulationsapplicableinaMemberState,adriverhasfollowedequivalenttrainingunderadifferentregimeorforadifferentpurposecoveringthesubjectsreferredtoin(2),thespecialisationcoursemaybetotallyorpartiallydispensedwith.S12:Ifthetotalnumberofpackagescontainingradioactivematerialcarrieddoesnotexceed10,andthesumofthecarriageindicesdoesnotexceed3,specialprovisionS11neednotbeapplied.However,driversshallthenreceiveappropriatetraining,commensuratewithandappropriatetotheirduties,whichprovidesthemwithanawarenessoftheradiationhazardsinvolvedinthecarriageofradioactivematerial.Suchawarenesstrainingshallbeconfirmedbyacertificateprovidedbytheiremployer.S13:Whenaconsignmentcannotbedelivered,itshallbeplacedinasafeplace;thecompetentauthorityshouldbeinformedassoonaspossibleandrequestedforinstructionsonhowtoproceed.S14:TheprovisionsofChapter8.4concerningthesupervisionofvehiclesshallapplywhenthetotalmassofthesesubstancesinthevehicleexceeds100kg.S15:TheprovisionsofChapter8.4concerningthesupervisionofvehiclesshallapplytosubstancesofhazardgroup4whatevertheirmassandtosubstancesofhazardgroup3whenthetotalmassofsuchsubstancesinthevehicleexceeds100kg.However,theprovisionsofChapter8.4neednotbeappliedwhentheloadedcompartmentislockedandthepackagescarriedareotherwiseprotectedagainstanyillicitunloading.S16:TheprovisionsofChapter8.4concerningthesupervisionofvehiclesshallapplywhenthetotalmassofthesesubstancesinthevehicleexceeds500kg.Inaddition,vehiclescarryingmorethan500kgofthesesubstancesshallbesubjectatalltimestosupervisiontopreventanymaliciousactandtoalertthedriverandcompetentauthoritiesintheeventoflossorfire.S17:TheprovisionsofChapter8.4concerningthesupervisionofvehiclesshallapplywhenthetotalmassofthesesubstancesinthevehicleexceeds1000kg.S18:TheprovisionsofChapter8.4concerningthesupervisionofvehiclesshallapplywhenthetotalmassofsuchsubstancesinthevehicleexceeds2000kg.S19:TheprovisionsofChapter8.4concerningthesupervisionofvehiclesshallapplywhenthetotalmassofsuchsubstancesinthevehicleexceeds5000kg.S20:TheprovisionsofChapter8.4concerningthesupervisionofvehiclesshallapplywhenthetotalmassofthesesubstancesinthevehicleexceeds10000kg.S21:TheprovisionsofChapter8.4concerningthesupervisionofvehiclesshallapplytoallmaterial,inwhatevermass.Inaddition,thesegoodsshallbesubjectatalltimestosupervisiontopreventanymaliciousactandtoalertthedriverandthecompetentauthoritiesintheeventoflossorfire.However,theprovisionsofChapter8.4neednotbeappliedwhere:(a)theloadedcompartmentislockedandthepackagescarriedareotherwiseprotectedagainstillicitunloading;and(b)thedoseratedoesnotexceed5Sv/hatanyaccessiblepointontheoutersurfaceofthevehicle.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/912Part9REQUIREMENTSCONCERNINGTHECONSTRUCTIONANDAPPROVALOFVEHICLESCHAPTER9.1Generalrequirementsconcerningtheconstructionandapprovalofvehicles9.1.1.Generalprovisions9.1.1.1.ScopeTheprovisionsofpart9shallapplytovehiclesofcategoriesNandO,asdefinedinAnnex7totheConsolidatedResolutionontheConstructionofVehicles(R.E.3)(1),intendedforthecarriageofdangerousgoods.9.1.1.2.ForthepurposesofPart9:‘Vehicle’:meansanyvehicle,whethercomplete(e.g.onestagebuiltvans,lorries,tractors,trailers),incomplete(e.g.chassis,chassis-cab,trailer-chassis)or,completed(e.g.chassis-cabfittedwithabodywork),intendedforthecarriageofdangerousgoodsbyroad;‘Basevehicle’:meansachassis-cabvehicle,atractorforsemi-trailer,atrailer-chassisoratrailerwithaself-supportingbodyintendedforthecarriageofdangerousgoods,towhichtherequirementsofChapter9.2apply;‘EX/IIvehicle’or‘EX/IIIvehicle’:meansavehicleintendedforthecarriageofexplosivessubstancesandarticles(Class1);‘FLvehicle’:meansavehicleintendedforthecarriageofliquidshavingaflash-pointofnotmorethan61°C(withtheexceptionofdieselfuelcomplyingwithstandardEN590:1993,gasoil,andheatingoil(light),UNNo1202,withaflash-pointasspecifiedinstandardEN590:1993)orflammablegases,intank-containers,portabletanksorMEGCsofmorethan3m3capacity,fixedtanksordemountabletanksofmorethan1m3capacityorabattery­vehicleofmorethan1m3capacityintendedforthecarriageofflammablegases;‘OXvehicle’:meansavehicleintendedforthecarriageofhydrogenperoxide,stabilisedorhydrogenperoxide,aqueoussolutionstabilisedwithmorethan60percenthydrogenperoxide(Class5.1,UNNo2015)intank-containersorportabletanksofmorethan3m3capacity,fixedtanksordemountabletanksofmorethan1m3capacity;‘ATvehicle’:meansavehicle,otherthanFLorOX,intendedforthecarriageofdangerousgoodsintank­containers,portabletanksorMEGCsofmorethan3m3capacity,fixedtanksordemountabletanksofmorethan1m3capacityorabatteryvehicleofmorethan1m3capacityotherthananFLvehicle.9.1.1.3.Vehiclescarryingdangerousgoodsshallcomplywiththeconstructionrequirementsforwhichthispartprovides.9.1.2.ApprovalofEX/II,EX/III,FL,OXandATvehiclesNOTE:NospecialcertificatesofapprovalshallberequiredforvehiclesotherthanEX/II,EX/III,FL,OXandATvehicles,apartfromthoserequiredbythegeneralsafetyregulationsnormallyapplicabletovehiclesinthecountryoforigin.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/913(1)DocumentoftheUnitedNationsEconomicCommissionforEurope,TRANS/WP.29/78/rev.1,asamended.9.1.2.1.Singleapproval9.1.2.1.1.EX/II,EX/III,FL,OXandATvehiclesshallbesubjecttoanannualtechnicalinspectionintheircountryofregistrationtomakesurethattheyconformtotherelevantprovisionsofthispart,andtothegeneralsafetyregulations(concerningbrakes,lighting,etc.)inforceintheircountryofregistration;ifthesevehiclesaretrailersorsemi-trailerscoupledbehindadrawingvehicle,thedrawingvehicleshallbesubjecttotechnicalinspectionforthesamepurposes.Whenvehiclesarerequiredtobefittedwithanendurancebrakingsystem,themanufacturerofthevehicleorhisdulyaccreditedrepresentativeshallissueadeclarationofconformitywiththeprovisionsof9.2.3.3.Thisdeclarationshallbepresentedatthefirsttechnicalinspection.NOTE:Fortransitionalprovisions,seealso1.6.5.1.9.1.2.1.2.ConformityofEX/II,EX/III,FL,OXandATvehicleswiththerequirementsofthispartissubjecttoacertificateofapprovalissuedbythecompetentauthorityofthecountryofregistrationforeachvehiclewhoseinspectionyieldssatisfactoryresults.Itshallbedrawnupinthelanguageoroneofthelanguagesofthecountryissuingit,andalso,ifthatlanguageisnotEnglish,French,orGerman,inEnglish,FrenchorGerman,unlessagreementsconcludedbetweenthecountriesconcernedinthetransportoperationprovideotherwise.Itshallconformtothemodelshownin9.1.2.1.5.9.1.2.1.3.AcertificateofapprovalissuedbythecompetentauthoritiesofoneMemberStateforavehicleregisteredintheterritoryofthatMemberStateshallbeaccepted,solongasitsvaliditycontinues,bythecompetentauthoritiesoftheotherMemberStates.9.1.2.1.4.Thevalidityofacertificateofapprovalshallexpirenotlaterthanoneyearafterthedateofthetechnicalinspectionofthevehicleprecedingtheissueofthecertificate.Thenextapprovaltermshall,however,berelatedtothelastnominalexpirydate,ifthetechnicalinspectionisperformedwithinonemonthbeforeorafterthatdate.However,inthecaseoftankssubjecttocompulsoryperiodicinspectionthisprovisionshallnotmeanthattightness(leakproofness)tests,hydraulicpressuretestsorinternalinspectionsoftankshavetobecarriedoutatintervalsshorterthanthoselaiddowninChapters6.8and6.9.9.1.2.1.5.Thecertificateofapprovalshallhavethesamelayoutasthemodelbelow.Itsdimensionsshallbe210mm×297mm(formatA4).Bothfrontandbackshallbeused.Thecolourshallbewhite,withapinkdiagonalstripe.Theapprovalcertificateforavacuum­operatedwastetank­vehicleshallbearthefollowingremark:‘vacuum­operatedwastetank­vehicle’.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/914OfficialJournaloftheEuropeanUnionEN26.1.2004L18/915OfficialJournaloftheEuropeanUnionEN26.1.2004L18/9169.1.2.1.6.CertificatesofapprovalconformingtotherequirementsofthisDirectiveinforceupto30June2001maycontinuetobeuseduntil31December2003.9.1.2.2.Type-approval9.1.2.2.1.Attherequestofthemanufacturerorhisdulyaccreditedrepresentative,basevehiclesofnewmotorvehiclesandtheirtrailerswhicharesubjecttoapprovalaccordingto9.1.2.1maybetypeapprovedbyacompetentauthorityinaccordancewithECERegulationNo1052(1)orDirective98/91/EC3(2)providedthattherequirementsofthesaidRegulationorthesaidDirectivecorrespondtothoseofChapter9.2ofthispart.Thistype-approval,grantedbyoneMemberState,shallbeacceptedbytheotherMemberStatesasensuringtheconformityofthebasevehiclewhentheapprovalofthecompleteorcompletedvehicleisobtained,providedthatnomodificationofthebasevehiclealtersitsvalidity.9.1.2.2.2.Whenthebasevehiclehasbeentype-approved,compliancewith9.2.4.7.2,shallbeverifiedonthecompletedvehicle.CHAPTER9.2Requirementsconcerningtheconstructionofbasevehicles9.2.1.BasevehiclesofEX/II,EX/III,FL,OXandATvehiclesshallcomplywiththerequirementsofthisChapter,accordingtothetablebelow.ForvehiclesotherthanofEX/II,EX/III,FL,OXandAT:—therequirementsof9.2.3.1areapplicabletoallvehiclesfirstregisteredafter30June1997,—therequirementsof9.2.5areapplicabletoallmotorvehicleswithamaximummassexceeding12tonnesregisteredafter31December1987.TECHNICALSPECIFICATIONSVEHICLESEX/IIEX/IIIATFLOX9.2.2.ELECTRICALEQUIPMENT9.2.2.2.WiringXX(a)XX9.2.2.3.Batterymasterswitch9.2.2.3.1.XX9.2.2.3.2.XX9.2.2.3.3.X9.2.2.3.4.XX9.2.2.4.BatteriesXXX9.2.2.5.PermanentlyenergisedcircuitsOfficialJournaloftheEuropeanUnionEN26.1.2004L18/917(1)RegulationNo105(uniformprovisionsconcerningtheapprovalofvehiclesintendedforthecarriageofdangerousgoodswithregardtotheirspecificconstructionalfeatures).(2)Directive98/91/ECoftheEuropeanParliamentandoftheCouncilof14December1998relatingtomotorvehiclesandtheirtrailersintendedforthetransportofdangerousgoodsbyroadandamendingDirective70/156/EECrelatingtothetypeapprovalofmotorvehiclesandtheirtrailers(OJL11,16.1.1999,p.25).TECHNICALSPECIFICATIONSVEHICLESEX/IIEX/IIIATFLOX9.2.2.5.1.X9.2.2.5.2.X9.2.2.6.ElectricalinstallationatrearofcabXX9.2.3.BRAKINGEQUIPEMENT9.2.3.1.GeneralprovisionsXXXXX9.2.3.2.Anti-lockbrakingsystemX(b)(d)X(b)(d)X(b)(d)X(b)(d)9.2.3.3.EndurancebrakingsystemX(c)(d)X(c)(d)X(c)(d)X(c)(d)9.2.3.4.Emergencybrakingdevicesfortrailers9.2.3.4.1.X9.2.3.4.2.X9.2.4.PREVENTIONOFFIRERISKS9.2.4.2.Vehiclecab9.2.4.2.1.XX9.2.4.2.2.X9.2.4.3.FueltanksXXXX9.2.4.4.EngineXXXX9.2.4.5.ExhaustsystemXXX9.2.4.6.VehicleendurancebrakingXXXXOfficialJournaloftheEuropeanUnionEN26.1.2004L18/918TECHNICALSPECIFICATIONSVEHICLESEX/IIEX/IIIATFLOX9.2.4.7.Combustionheaters9.2.4.7.1.,9.2.4.7.2.,9.2.4.7.5.X(e)X(e)X(e)X(e)X(e)9.2.4.7.3.,9.2.4.7.4.X(e)9.2.4.7.6.XX9.2.5.SPEEDLIMITATIONDEVICEX(f)X(f)X(f)X(f)X(f)9.2.6.COUPLINGDEVICEOFTRAILERSXX(a)InthecaseofATvehiclescarryingtank-containers,portabletanksorMEGCs,thisrequirementshallapplyonlytovehiclesfirstregisteredafter30June1997.ApplicabletoallATvehiclescarryingtank-containers,portabletanksorMEGCsasfrom1January2005.(b)Applicabletovehiclesfirstregisteredafter30June1993inrespectofmotorvehicles(tractorsandrigidvehicles)havingamaximummassexceeding16tonnesandtrailers(i.e.fulltrailers,semi-trailersandcentre-axletrailers)withamaximummassexceeding10tonnes.Applicabletomotorvehiclesauthorisedtotowtrailerswithamaximummassexceeding10tonnes,firstregisteredafter30June1995.Applicabletoallvehicleswhicharefirstapprovedinaccordancewith9.1.2after30June2001regardlessofthedateonwhichtheywerefirstregistered.(c)Applicabletoallvehicles,exceptfortransportunitscomprisingamotorvehicleandatrailer,inwhichcasetherequirementshallapplyonlytomotorvehiclesfirstregisteredafter30June1993.(d)Mandatorycomplianceforallvehiclesasfrom1January2010.(e)Applicabletomotorvehiclesequippedafter30June1999.Mandatorycomplianceby1January2010forvehiclesequippedbefore1July1999.(f)Applicabletomotorvehicleswithamaximummassexceeding12tonnesregisteredafter31December1987.9.2.2.Electricalequipment9.2.2.1.GeneralprovisionsTheelectricalinstallationasawholeshallmeettheprovisionsof9.2.2.2to9.2.2.6inaccordancewiththetableof9.2.1.9.2.2.2.Wiring9.2.2.2.1.Thesizeofconductorsshallbelargeenoughtoavoidoverheating.Conductorsshallbeadequatelyinsulated.Allcircuitsshallbeprotectedbyfusesorautomaticcircuitbreakers,exceptforthefollowing:—fromthebatterytothecoldstartandstoppingsystemsoftheengine,—fromthebatterytothealternator,—fromthealternatortothefuseorcircuitbreakerbox,—fromthebatterytothestartermotor,—fromthebatterytothepowercontrolhousingoftheendurancebrakingsystem(see9.2.3.3),ifthissystemiselectricalorelectromagnetic,—fromthebatterytotheelectricalliftingmechanismforliftingthebogieaxle.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/919Theaboveunprotectedcircuitsshallbeasshortaspossible.9.2.2.2.2.Cablesshallbesecurelyfastenedandpositionedinsuchawaythattheconductorsareadequatelyprotectedagainstmechanicalandthermalstresses.9.2.2.3.Batterymasterswitch9.2.2.3.1.Aswitchforbreakingtheelectricalcircuitsshallbeplacedasclosetothebatteryaspracticable.9.2.2.3.2.Acontroldevicetofacilitatethedisconnectingandreconnectingfunctionsoftheswitchshallbeinstalledinthedriver'scab.Itshallbereadilyaccessibletothedriverandbedistinctivelymarked.Itshallbeprotectedagainstinadvertentoperationbyeitheraddingaprotectivecover,byusingadualmovementcontroldeviceorbyothersuitablemeans.Additionalcontroldevicesmaybeinstalledprovidedtheyaredistinctivelymarkedandprotectedagainstinadvertentoperation.9.2.2.3.3.TheswitchshallhaveacasingwithprotectiondegreeIP65inaccordancewithIECStandard529.9.2.2.3.4.ThecableconnectionsontheswitchshallhaveprotectiondegreeIP54.However,thisdoesnotapplyiftheseconnectionsarecontainedinahousingwhichmaybethebatterybox.Inthiscaseitissufficienttoinsulatetheconnectionsagainstshortcircuits,forexamplewitharubbercap.9.2.2.4.BatteriesThebatteryterminalsshallbeelectricallyinsulatedorcoveredbytheinsulatingbatteryboxcover.Ifthebatteriesarenotlocatedundertheenginebonnet,theyshallbefittedinaventedbox.9.2.2.5.Permanentlyenergisedcircuits9.2.2.5.1.(a)Thosepartsoftheelectricalinstallationincludingtheleadswhichshallremainenergisedwhenthebatterymasterswitchisopen,shallbesuitableforuseinhazardousareas.SuchequipmentshallmeetthegeneralrequirementsofIEC60079,parts0and141(1)andtheadditionalrequirementsapplicablefromIEC60079,parts1,2,5,6,7,11,15or18(2)(b)FortheapplicationofIEC60079part14(1),thefollowingclassificationshallbeused:permanentlyenergisedelectricalequipmentincludingtheleadswhichisnotsubjectto9.2.2.3and9.2.2.4shallmeettherequirementsforZone1forelectricalequipmentingeneralormeettherequirementsforZone2forelectricalequipmentsituatedinthedriver'scab.TherequirementsforexplosiongroupIIC,temperatureclassT6shallbemet.9.2.2.5.2.Bypassconnectionstothebatterymasterswitchforelectricalequipmentwhichmustremainenergisedwhenthebatterymasterswitchisopenshallbeprotectedagainstoverheatingbysuitablemeans,suchasafuse,acircuitbreakerorasafetybarrier(currentlimiter).9.2.2.6.Provisionsconcerningthatpartoftheelectricalinstallationsituatedtotherearofthedriver'scabThewholeinstallationshallbesodesigned,constructedandprotectedsuchthatitcannotprovokeanyignitionorshort-circuitundernormalconditionsofuseofvehiclesandthattheseriskscanbeminimizedintheeventofanimpactordeformation.Inparticular:OfficialJournaloftheEuropeanUnionEN26.1.2004L18/920(1)TherequirementsofIEC60079part14donottakeprecedenceovertherequirementofthispart.(2)Asanalternative,thegeneralrequirementsofEN50014andtheadditionalrequirementsofEN50015,50016,50017,50018,50019,50020or50028maybeused.9.2.2.6.1.WiringThewiringlocatedtotherearofthedriver'scabshallbeprotectedagainstimpact,abrasionandchafingduringnormalvehicleoperation.Examplesofappropriateprotectionaregiveninfigures1,2,3and4below.However,thesensorcablesofanti-lockbrakingdevicesdonotneedadditionalprotection.9.2.2.6.2.LightingLampbulbswithascrewcapshallnotbeused.9.2.2.6.3.ElectricalconnectionsElectricalconnectionsbetweenmotorvehiclesandtrailersshallhaveaprotectiondegreeIP54inaccordancewithIECstandard529andbedesignedtopreventaccidentaldisconnection.ExamplesofappropriateconnectionsaregiveninISO12098:1994andISO7638:1985.FIGURESOfficialJournaloftheEuropeanUnionEN26.1.2004L18/9219.2.3.Brakingequipment9.2.3.1.GeneralprovisionsInadditiontothefollowingtechnicalprovisions,tobeappliedinaccordancewiththetableof9.2.1,motorvehiclesandtrailersintendedforuseastransportunitsfordangerousgoodsshallfulfilallrelevanttechnicalrequirementsofECERegulationNo13(1)orDirective71/320/EEC(2),asamended,inaccordancewiththedatesofapplicationspecifiedtherein.9.2.3.2.Anti-lockbrakingsystem9.2.3.2.1.Motorvehicleshavingamaximummassexceeding16tonnes,orauthorisedtotowatrailerwithamaximummassexceeding10tonnes,shallbeequippedwithananti-lockbrakingsystemofcategory1accordingtoECERegulationNo13(3),Annex13.9.2.3.2.2.Trailershavingamaximummassexceeding10tonnesshallbeequippedwithananti-lockbrakingsystemofcategoryAaccordingtoECERegulationNo13(3),Annex13.9.2.3.3.Endurancebrakingsystem9.2.3.3.1.Endurancebrakingsystemmeansasystemintendedtostabilisevehiclespeedonalongdescent,withouttheuseoftheservice,secondaryorparkingbrakingsystems.9.2.3.3.2.Motorvehicleshavingamaximummassexceeding16tonnesorauthorizedtotowatrailerwithamaximummassexceeding10tonnesshallbefittedwithanendurancebrakingsystemwhichcomplieswiththefollowingrequirements:(a)theendurancebrakingsystemmaybeasingledeviceoracombinationofseveraldevices.Eachdevicemayhaveitsowncontrol;(b)allthreeendurancebrakingcontroloptionsprovidedforinparagraph2.14ofECERegulationNo13(3)shallbepermitted,but,inthecaseofafailureoftheanti-locksystem,integratedorcombinedretardersshallbeswitchedoffautomatically;(c)theeffectivenessoftheendurancebrakingsystemshallbecontrolledbytheanti-lockbrakingsystemsuchthattheaxle(s)brakedbytheendurancebrakingsystemcannotbelockedbytheendurancebrakingsystematspeedsabove15km/h.However,thisprovisionshallnotapplytothatpartofthebrakingsystemconstitutedbynaturalenginebraking;(d)theendurancebrakingsystemshallcompriseseveralstagesofeffectiveness,includingalowstageappropriatefortheunladencondition.Wheretheendurancebrakingsystemofamotorvehicleisconstitutedbyitsengine,thedifferentgearratiosshallbeconsideredtoprovidethedifferentstagesofeffectiveness;(e)theperformanceoftheendurancebrakingsystemshallbesuchthatitfulfilstherequirementsofECERegulationNo13(3),Annex5(TypeIIAtest),withaladenvehiclemasscomprisingtheladenmassofthemotorvehicleanditsauthorizedmaximumtowedmassbutnotexceedingatotalof44tonnes;(f)ifthemotorvehicledoesnotfulfiltheperformancerequirementsfortheendurancebrakingsystemasdefinedin(e)above,itshallatleastfulfiltherequirementsofECERegulationNo13(3),Annex5,andshallberestrictedtobeingcoupledonlytoatrailerfittedwithanendurancebrakingsystem.Suchamotorvehicleshallbefittedwithacontroldevicefortheendurancebrakingsystemonthetrailer.9.2.3.3.3.IfatrailerisequippedwithanendurancebrakingsystemitshallfulfiltherequirementsofECERegulationNo13(3),Annex5,andtheprovisionsof9.2.3.3.2(a)to(d).9.2.3.4.Emergencybrakingdevicesfortrailers9.2.3.4.1.Trailersshallbeequippedwithaneffectivesystemforbrakingorrestrainingthemiftheybecomedetachedfromthemotorvehicletowingthem.9.2.3.4.2.Trailersshallbefittedwithaneffectivebrakingdevicewhichactsonallthewheels,isactuatedbythedrawingvehicle'sservice­brakecontrolandautomaticallystopsthetrailerintheeventofbreakageofthecoupling.NOTE:Theuseoftrailersequippedonlywithaninertiabrakingsystemshallbelimitedtoamaximumloadof50kgnetexplosivemass.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/922(1)ECERegulationNo13(uniformprovisionsconcerningtheapprovalofvehiclesofcategoriesM,NandOwithregardtobraking).(2)Directive71/320/EEC(OJL202,6.9.1971).(3)ECERegulationNo13(uniformprovisionsconcerningtheapprovalofvehiclesofcategoriesM,NandOwithregardtobraking)orthecorrespondingprovisionsofDirective71/320/EEC(OJL202,6.9.1971),asamended.9.2.4.Preventionoffirerisks9.2.4.1.GeneralprovisionsThefollowingtechnicalprovisionsshallapplyinaccordancewiththetablein9.2.1.9.2.4.2.Vehiclecab9.2.4.2.1.Onlymaterialnotreadilyflammableshallbeusedintheconstructionofthedriver'scab.Thisprovisionwillbedeemedtobemetif,inaccordancewiththeprocedurespecifiedinISOstandard3795:1989,samplesofthefollowingcabcomponentshaveaburnratenotexceeding100mm/min:seatcushions,seatbacks,safetybelts,headlining,openingroofs,armrests,alltrimpanelsincludingdoor,front,rear,andsidepanels,compartmentshelves,headrestraints,floorcoverings,sunvisors,curtains,shades,wheelhousingcovers,enginecompartmentcovers,mattresscoversandanyotherinteriormaterials,includingpaddingandcrash­deployedelements,thataredesignedtoabsorbenergyoncontactbyoccupantsintheeventofacrash.9.2.4.2.2.Unlessthedriver'scabismadeofmaterialswhicharenotreadilyflammable,ashieldmadeofmetalorothersuitablematerialofthesamewidthasthetankshallbefittedattherearofthecab.Anywindowsintherearofthecaborintheshieldshallbehermeticallyclosedandmadeoffire­resistantsafetyglasswithfire­resistantframes.Furthermore,thereshallbeaclearspaceofnotlessthan15cmbetweenthetankandthecabortheshield.9.2.4.3.FueltanksThefueltanksforsupplyingtheengineofthevehicleshallmeetthefollowingrequirements:(a)intheeventofanyleakage,thefuelshalldraintothegroundwithoutcomingintocontactwithhotpartsofthevehicleortheload;(b)fueltankscontainingpetrolshallbeequippedwithaneffectiveflametrapatthefilleropeningorwithaclosureenablingtheopeningtobekepthermeticallysealed.9.2.4.4.EngineTheenginepropellingthevehicleshallbesoequippedandsituatedtoavoidanydangertotheloadthroughheatingorignition.InthecaseofEX/IIandEX/IIIvehiclestheengineshallbeofcompression­ignitionconstruction.9.2.4.5.ExhaustsystemTheexhaustsystemaswellastheexhaustpipesshallbesodirectedorprotectedtoavoidanydangertotheloadthroughheatingorignition.Partsoftheexhaustsystemsituateddirectlybelowthefueltank(diesel)shallhaveaclearanceofatleast100mmorbeprotectedbyathermalshield.9.2.4.6.VehicleendurancebrakingVehiclesequippedwithendurancebrakingsystemsemittinghightemperaturesplacedbehindtherearwallofthedriver'scabshallbeequippedwithathermalshieldsecurelyfixedandlocatedbetweenthissystemandthetankorloadsoastoavoidanyheating,evenlocal,ofthetankwallortheload.Inaddition,thethermalshieldshallprotectthebrakingsystemagainstanyoutfloworleakage,evenaccidental,oftheload.Forinstance,aprotectionincludingatwin­shellshieldshallbeconsideredsatisfactory.9.2.4.7.Combustionheaters9.2.4.7.1.(Reserved)9.2.4.7.2.Thecombustionheatersandtheirexhaustgasroutingshallbedesigned,located,protectedorcoveredsoastopreventanyunacceptableriskofheatingorignitionoftheload.Thisrequirementshallbeconsideredasfulfilledifthefueltankandtheexhaustsystemoftheapplianceconformtoprovisionssimilartothoseprescribedforfueltanksandexhaustsystemsofvehiclesin9.2.4.3and9.2.4.5respectively.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/9239.2.4.7.3.Thecombustionheatersshallbeputoutofoperationbyatleastthefollowingmethods:(a)intentionalmanualswitchingofffromthedriver'scab;(b)stoppingofthevehicleengine;inthiscasetheheatingdevicemayberestartedmanuallybythedriver;(c)startupofafeedpumponthemotorvehicleforthedangerousgoodscarried.9.2.4.7.4.Afterrunningispermittedafterthecombustionheatershavebeenputoutofoperation.Forthemethodsof9.2.4.7.3(b)and(c)thesupplyofcombustionairshallbeinterruptedbysuitablemeasuresafteranafterrunningcycleofnotmorethan40seconds.Onlyheatersshallbeusedforwhichproofhasbeenfurnishedthattheheatexchangerisresistanttothereducedafterrunningcycleof40secondsforthetimeoftheirnormaluse.9.2.4.7.5.Thecombustionheatershallbeswitchedonmanually.Programmingdevicesshallbeprohibited.9.2.4.7.6.Combustionheaterswithgaseousfuelsarenotpermitted.9.2.5.SpeedlimitationdeviceMotorvehicles(rigidvehiclesandtractorsforsemi­trailers)withamaximummassexceeding12tonnes,shallbeequippedwithaspeedlimitationdeviceaccordingtothetechnicalrequirementsofECERegulationNo89(1),asamended.ThesetspeedVasdefinedinparagraph2.1.2ofECERegulationNo89shallnotexceed85km/h.9.2.6.CouplingdevicesoftrailersCouplingdevicesoftrailersshallcomplywiththetechnicalrequirementsofECERegulationNo557(2)orDirective94/20/EC8(3),asamended,inaccordancewiththedatesofapplicationspecifiedtherein.CHAPTER9.3AdditionalrequirementsconcerningcompleteorcompletedEX/IIorEX/IIIvehicles9.3.1.MaterialstobeusedintheconstructionofvehiclebodiesNomaterialslikelytoformdangerouscompoundswiththeexplosivesubstancescarriedshallbeusedintheconstructionofthebody.9.3.2.CombustionheatersCombustionheatersshallnotbeinstalledinloadcompartmentsofEX/IIandEX/IIIvehicles.Combustionheatersshallmeettherequirementsof9.2.4.7.1,9.2.4.7.2,9.2.4.7.5,9.2.4.7.6andthefollowing:(a)theswitchmaybeinstalledoutsidethedriver'scab;(b)thedevicemaybeswitchedofffromoutsidetheloadcompartment;and(c)itisnotnecessarytoprovethattheheatexchangerisresistanttothereducedafterrunningcycle.Nofueltanks,powersources,combustionairorheatingairintakesaswellasexhausttubeoutletsrequiredfortheoperationofthecombustionheatershallbeinstalledintheloadcompartment.Itshallbeensuredthattheheatingairoutletcannotbeblockedbycargo.Thetemperaturetowhichpackagesareheatedshallnotexceed50°C.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/924(1)ECERegulationsNo89:uniformprovisionsconcerningtheapprovalof:I.Vehicleswithregardtolimitationoftheirmaximumspeed;II.Vehicleswithregardtotheinstallationofaspeedlimitationdevice(SLD)ofanapprovedtype;III.Speedlimitationdevices(SLD).Asanalternative,thecorrespondingprovisionsofCouncilDirective92/6/EECof10February1992(OJL57,2.3.1992)andCouncilDirective92/24/EECof31March1992(OJL129,14.5.1992),asamended,mayapplyprovidedthattheyhavebeenamendedinaccordancewiththelatestamendedformofECERegulationNo89applicableatthetimeofthevehicleapproval.(2)ECERegulationNo55(uniformprovisionsconcerningtheapprovalofmechanicalcouplingcomponentsofcombinationsofvehicles).(3)Directive94/20/ECoftheEuropeanParliamentandoftheCouncilof30ofMay1994(OJL195,29.7.1994).9.3.3.EX/IIvehiclesThevehiclesshallbedesigned,constructedandequippedsothattheexplosivesareprotectedfromexternalhazardsandtheweather.Theyshallbeeitherclosedorsheeted.Sheetingshallberesistanttotearingandbeofimpermeablematerial,notreadilyflammable.Itshallbetautenedsoastocoverthevehicleonallsides,withanoverlapofnotlessthan20cmdownthesidesofthevehicle,andbekeptinpositionbyalockabledevice.Theloadcarryingcompartmentofclosedvehiclesshallnothavewindowsandallopeningsshallhavelockable,close­fittingdoorsorcovers.9.3.4.EX/IIIvehiclesThesevehiclesshallbeclosed.Theloadingsurface,includingthefrontwall,shallbecontinuous.Theinsulatingandheatresistingpropertiesofthebodyshallbeatleastequivalenttothoseofapartitionconsistingofametalouterwalllinedwithalayeroffire­proofedwoodof10mmthickness;orthebodyshallbeofaconstructionwhichshallensurethatnoflamepenetrationofthewallorhotspotsofmorethan120°Contheinnerwallsurfacewilloccurwithin15minutesfromthestartofafireresultingfromtheoperationofthevehicle,suchasatyrefire.Allthedoorsshallbecapableofbeinglocked.Theyshallbesoplacedandconstructedastooverlapthejoints.9.3.5.LoadcompartmentandengineTheengineshallbeplacedforwardofthefrontwalloftheloadcompartment;itmayneverthelessbeplacedundertheloadcompartment,providedthisisdoneinsuchawaythatanyexcessheatdoesnotconstituteahazardtotheloadbyraisingthetemperatureontheinnersurfaceoftheloadcompartmentabove80°C.9.3.6.LoadcompartmentandexhaustsystemTheexhaustsystemofEX/IIandEX/IIIvehiclesorotherspartsofthesecompleteorcompletedvehiclesshallbesoconstructedandsituatedthatanyexcessheatshallnotconstituteahazardtotheloadbyraisingthetemperatureontheinnersurfaceoftheloadcompartmentabove80ºC.9.3.7.Electricalequipment9.3.7.1.TheelectricalinstallationonEX/IIIvehiclesshallmeettherequirementsof9.2.2.2,9.2.2.3,9.2.2.4,9.2.2.5.2and9.2.2.6.9.3.7.2.Theratedvoltageoftheelectricalsystemshallnotexceed24V.9.3.7.3.Theelectricalinstallationintheloadcompartmentshallbedust-protected(atleastIP54orequivalent)or,inthecaseofCompatibilityGroupJ,atleastIP65(e.g.flame-proofEexd).CHAPTER9.4Additionalrequirementsconcerningtheconstructionofthebodiesofcompleteorcompletedvehiclesintendedforthecarriageofdangerousgoodsinpackages(otherthanEX/IIandEX/IIIvehicles)9.4.1.Combustionheatersshallmeetthefollowingrequirements:(a)theswitchmaybeinstalledoutsidethedriver'scab;(b)thedevicemaybeswitchedofffromoutsidetheloadcompartment;and(c)itisnotnecessarytoprovethattheheatexchangerisresistanttothereducedafterrunningcycle.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/9259.4.2.IfthevehicleisintendedforthecarriageofdangerousgoodsforwhichalabelconformingtomodelsNos1,1.4,1.5,1.6,3,4.1,4.3,5.1or5.2isprescribed,nofueltanks,powersources,combustionairorheatingairintakesaswellasexhausttubeoutletsrequiredfortheoperationofthecombustionheatershallbeinstalledintheloadcompartment.Itshallbeensuredthattheheatingairoutletcannotbeblockedbycargo.Thetemperaturetowhichpackagesareheatedshallnotexceed50°C.Heatingdevicesinstalledinsidetheloadcompartmentsshallbedesignedsoastopreventtheignitionofanexplosiveatmosphereunderoperatingconditions.9.4.3.AdditionalrequirementsconcerningtheconstructionofthebodiesofvehiclesintendedforthecarriageofgivendangerousgoodsorspecificpackagingsmaybeincludedinPart7,Chapter7.2inaccordancewiththeindicationsincolumn16ofTableAofChapter3.2,foragivensubstance.CHAPTER9.5Additionalrequirementsconcerningtheconstructionofthebodiesofcompleteorcompletedvehiclesintendedforthecarriageofdangeroussolidsinbulk9.5.1.Combustionheatersshallmeetthefollowingrequirements:(a)theswitchmaybeinstalledoutsidethedriver'scab;(b)thedevicemaybeswitchedofffromoutsidetheloadcompartment;and(c)itisnotnecessarytoprovethattheheatexchangerisresistanttothereducedafterrunningcycle.9.5.2.IfthevehicleisintendedforthecarriageofdangerousgoodsforwhichalabelconformingtomodelNos4.1,4.3or5.1isprescribed,nofueltanks,powersources,combustionairorheatingairintakesaswellasexhausttubeoutletsrequiredfortheoperationofthecombustionheatershallbeinstalledintheloadcompartment.Itshallbeensuredthattheheatingairoutletcannotbeblockedbycargo.Thetemperaturetowhichtheloadisheatedshallnotexceed50°C.Heatingdevicesinstalledinsidetheloadcompartmentsshallbedesignedsoastopreventtheignitionofanexplosiveatmosphereunderoperatingconditions.9.5.3.AdditionalrequirementsconcerningtheconstructionofthebodiesofvehiclesintendedforthecarriageofdangeroussolidsinbulkmayappearinPart7,Chapter7.3inaccordancewiththeindicationsincolumn17ofTableAofChapter3.2,foragivensubstance.CHAPTER9.6Additionalrequirementsconcerningcompleteorcompletedvehiclesintendedforthecarriageoftemperaturecontrolledself-reactivesubstancesofClass4.1andorganicperoxidesofClass5.29.6.1.Insulated,refrigeratedandmechanically-refrigeratedvehiclesintendedforthecarriageoftemperaturecontrolledself-reactivesubstancesofClass4.1andorganicperoxidesofClass5.2shallconformtothefollowingconditions:(a)thevehicleshallbesuchandsoequippedasregardsitsinsulationandmeansofrefrigeration,thatthecontroltemperatureprescribedin2.2.41.1.17and2.2.52.1.16andin2.2.41.4and2.2.52.4forthesubstancetobecarriedisnotexceeded.Theoverallheattransfercoefficientshallbenotmorethan0,4W/m2K;(b)thevehicleshallbesoequippedthatvapoursfromthesubstancesorthecoolantcarriedcannotpenetrateintothedriver'scab;OfficialJournaloftheEuropeanUnionEN26.1.2004L18/926(c)asuitabledeviceshallbeprovidedenablingthetemperatureprevailingintheloadingspacetobedeterminedatanytimefromthecab;(d)theloadingspaceshallbeprovidedwithventsorventilatingvalvesifthereisanyriskofadangerousexcesspressurearisingtherein.Careshallbetakenwherenecessarytoensurethatrefrigerationisnotimpairedbytheventsorventilatingvalves;(e)therefrigerantshallnotbeflammable;and(f)therefrigeratingapplianceofamechanicallyrefrigeratedvehicleshallbecapableofoperatingindependentlyoftheengineusedtopropelthevehicle.9.6.2.Suitablemethods(seeV8(3))topreventthecontroltemperaturefrombeingexceededarelistedinChapter7.2(R1toR5).Dependingonthemethodused,additionalprovisionsconcerningtheconstructionofvehiclebodiesmaybeincludedinChapter7.2.CHAPTER9.7Additionalrequirementsconcerningfixedtanks(tank-vehicles)battery-vehiclesandcompleteorcompletedvehiclesusedforthecarriageofdangerousgoodsindemountabletankswithacapacitygreaterthan1m3orintank-containers,portabletanksormegcsofacapacitygreaterthan3m3(FL,OXandATvehicles)9.7.1.Generalprovisions9.7.1.1.Inadditiontothevehicleproper,ortheunitsofrunninggearusedinitsstead,atank-vehiclecomprisesoneormoreshells,theiritemsofequipmentandthefittingsforattachingthemtothevehicleortotherunning-gearunits.9.7.1.2.Oncethedemountabletankhasbeenattachedtothecarriervehicle,theentireunitshallmeettherequirementsprescribedfortank-vehicles.9.7.2.Requirementsconcerningtanks9.7.2.1.FixedtanksordemountabletanksmadeofmetalshallmeettherelevantrequirementsofChapter6.8.9.7.2.2.Elementsofbattery-vehiclesandofMEGCsshallmeettherelevantrequirementsofChapter6.2inthecaseofcylinders,tubes,pressuredrumsandbundlesofcylindersandtherequirementsofChapter6.8inthecaseoftanks.9.7.2.3.Tank-containersmadeofmetalshallmeettherequirementsofChapter6.8,portabletanksshallmeettherequirementsofChapter6.7or,ifapplicable,thoseoftheIMDGcode(see1.1.4.2).9.7.2.4.Tanksmadeoffibre­reinforcedplasticsmaterialshallmeettherequirementsofChapter6.9.9.7.2.5.Vacuum-operatedwastetank­vehiclesshallmeettherequirementsofChapter6.10.9.7.3.FasteningsFasteningsshallbedesignedtowithstandstaticanddynamicstressesinnormalconditionsofcarriage,andminimumstressesasdefinedin6.8.2.1.2,6.8.2.1.11to6.8.2.1.15and6.8.2.1.16inthecaseoftank-vehicles,battery-vehicles,andvehiclescarryingdemountabletanks.9.7.4.EarthingofFLvehiclesTanksmadeofmetaloroffibre­reinforcedplasticsmaterialofFLtank-vehiclesandbatteryelementsofFLbattery­vehiclesshallbelinkedtothechassisbymeansofatleastonegoodelectricalconnection.Anymetalcontactcapableofcausingelectrochemicalcorrosionshallbeavoided.NOTE:Seealso6.9.1.2and6.9.2.14.3.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/9279.7.5.Stabilityoftank-vehicles9.7.5.1.Theoverallwidthoftheground­levelbearingsurface(distancebetweentheouterpointsofcontactwiththegroundoftheright­handtyreandtheleft­handtyreofthesameaxle)shallbeatleastequalto90%oftheheightofthecentreofgravityoftheladentank­vehicle.Inanarticulatedvehiclethemassontheaxlesoftheload­carryingunitoftheladensemi­trailershallnotexceed60%ofthenominaltotalladenmassofthecompletearticulatedvehicle.9.7.5.2.Inaddition,tank-vehicleswithfixedtankswithacapacityofmorethan3m3intendedforthecarriageofdangerousgoodsintheliquidormoltenstatetestedwithapressureoflessthan4bar,shallcomplywiththetechnicalrequirementsofECERegulationNo111(1)forlateralstability,asamended,inaccordancewiththedatesofapplicationspecifiedtherein.Therequirementsareapplicabletotank-vehicleswhicharefirstregisteredasfrom1July2003.9.7.6.RearprotectionofvehiclesAbumpersufficientlyresistanttorearimpactshallbefittedoverthefullwidthofthetankattherearofthevehicle.Thereshallbeaclearanceofatleast100mmbetweentherearwallofthetankandtherearofthebumper(thisclearancebeingmeasuredfromtherearmostpointofthetankwallorfromprojectingfittingsoraccessoriesincontactwiththesubstancebeingcarried).Vehicleswithatiltingshellforthecarriageofpowderyorgranularsubstancesandavacuum­operatedwastetankwithatiltingshellwithreardischargedonotrequireabumperiftherearfittingsoftheshellareprovidedwithameansofprotectionwhichprotectstheshellinthesamewayasabumper.NOTES:1.Thisprovisiondoesnotapplytovehiclesusedforthecarriageofdangerousgoodsintank­containers,MEGCsorportabletanks.2.Fortheprotectionoftanksagainstdamagebylateralimpactoroverturning,see6.8.2.1.20and6.8.2.1.21or,forportabletanks,6.7.2.4.3and6.7.2.4.5.9.7.7.Combustionheaters9.7.7.1.Combustionheatersshallmeettherequirementsof9.2.4.7.1,9.2.4.7.2,9.2.4.7.5andthefollowing:(a)theswitchmaybeinstalledoutsidethedriver'scab;(b)thedevicemaybeswitchedofffromoutsidetheloadcompartment;and(c)itisnotnecessarytoprovethattheheatexchangerisresistanttothereducedafterrunningcycle.InadditionforFLvehicles,theyshallmeettherequirementsof9.2.4.7.3and9.2.4.7.4.9.7.7.2.IfthevehicleisintendedforthecarriageofdangerousgoodsforwhichalabelconformingtomodelsNos3,4.1,4.3,5.1or5.2isprescribed,nofueltanks,powersources,combustionairorheatingairintakesaswellasexhausttubeoutletsrequiredfortheoperationofthecombustionheatershallbeinstalledintheloadcompartment.Itshallbeensuredthattheheatingairoutletcannotbeblockedbycargo.Thetemperaturetowhichtheloadisheatedshallnotexceed50ºC.Heatingdevicesinstalledinsidetheloadcompartmentsshallbedesignedsoastopreventtheignitionofanexplosiveatmosphereunderoperatingconditions.9.7.8.Electricalequipment9.7.8.1.TheelectricalinstallationonFLvehiclesforwhichanapprovalaccordingto9.1.2isrequiredshallmeettherequirementsof9.2.2.2,9.2.2.3,9.2.2.4,9.2.2.5.1and9.2.2.6.Howeveradditionstoormodificationsoftheelectricalinstallationsofthevehicleshallmeettherequirementsfortheelectricalapparatusoftherelevantgroupandtemperatureclassaccordingtothesubstancestobecarried.NOTE:Fortransitionalprovisions,seealso1.6.6.9.7.8.2.ElectricalequipmentonFLvehicles,situatedinareaswhereanexplosiveatmosphereis,ormaybeexpectedtobe,presentinsuchquantitiesastorequirespecialprecautions,shallbesuitableforuseinahazardousarea.SuchequipmentshallmeetthegeneralrequirementsofIEC60079parts0and14andtheadditionalrequirementsapplicableformIEC60079parts1,2,5,6,7,11or182(2).Therequirementsfortheelectricalapparatusoftherelevantgroupandtemperatureclassaccordingtothesubstancestobecarriedshallbemet.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/928(1)ECERegulationNo111:uniformprovisionsconcerningtheapprovaloftank-vehiclesofcategoriesNandOwithregardtorolloverstability.(2)Asanalternative,thegeneralrequirementsofEN50014andtheadditionalrequirementsofEN50015,50016,50017,50018,50019,50020or50028maybeused.FortheapplicationofIEC60079part14(1),thefollowingclassificationshallbeused:ZONE0Insidetankcompartments,fittingsforfillinganddischargeandvapourrecoverylines.ZONE1Insidecabinetsforequipmentusedforfillinganddischargeandwithin0,5mofventingdevicesandpressurereliefsafetyvalves.9.7.8.3.Permanentlyenergizedelectricalequipment,includingtheleads,whichissituatedoutsideZones0and1shallmeettherequirementsforZone1forelectricalequipmentingeneralormeettherequirementsforZone2electricalequipmentsituatedinthedriver'scab.Therequirementsfortherelevantgroupofelectricalapparatusaccordingtothesubstancestobecarriedshallbemet.OfficialJournaloftheEuropeanUnionEN26.1.2004L18/929(1)Asanalternative,thegeneralrequirementsofEN50014andtheadditionalrequirementsofEN50015,50016,50017,50018,50019,50020or50028maybeused.