title: Equilibration of D-Glucaric Acid in Aqueous Solution

authors: Brown, Jolene Mary

subjects: D-glucaric acid

abstract: Abstract

The equilibrium of aqueous D-glucaric acid was investigated via Nuclear Magnetic Resonance (NMR) spectroscopy. The NMR spectra of all four species (D-glucaric acid, D-glucaro-1,4-lactone, D-glucaro-6,3- lactone and D-glucaro-1,4;6,3-lactone) were assigned.

A 1H NMR spectroscopy method was developed to investigate the kinetics of equilibration of the starting species (D-glucaro-1,4-lactone and D-glucaro-1,4;6,3-dilactone). The equilibration was investigated under neutral conditions as well as conditions with increasing acidity. 

Each experiment set contained 50-100 1HNMR spectroscopy experiments that were run on the same sample using a program that built in delays. Dimethyl sulfoxide was used as an internal standard, and its signal size was used as a scale to report the changes in relative concentration of the four species throughout the experiment sets.

Under neutral conditions D-glucaro-1,4-lactone is relatively stable against equilibration, while D-glucaro-1,4;6,3-dilactone is not. Under acidic conditions both compounds equilibrate within approximately 30,000 seconds. After equilibration under acidic conditions D-glucaric acid is the dominant species, while the relative concentration of D-glucaro-1,4-lactone is slightly higher than that of D-glucaro-6,3-lactone. The relative equilibrium concentration of D-glucaro-1,4;6,3-dilactone is low.

A mechanism for the equilibration of aqueous D-glucaric acid was proposed and equilibrium constants and estimates of rate constants were derived from the experimental data. These rate constants were used in MATLAB simulations that were compared to the experimental data. MATLAB simulations were used to alter the rate constants to improve the fits between experimental data and simulated data.

text: Equilibration of D-Glucaric Acid in Aqueous Solution Abstract

The equilibrium of aqueous D-glucaric acid was investigated via Nuclear Magnetic Resonance (NMR) spectroscopy. The NMR spectra of all four species (D-glucaric acid, D-glucaro-1,4-lactone, D-glucaro-6,3- lactone and D-glucaro-1,4;6,3-lactone) were assigned.

A 1H NMR spectroscopy method was developed to investigate the kinetics of equilibration of the starting species (D-glucaro-1,4-lactone and D-glucaro-1,4;6,3-dilactone). The equilibration was investigated under neutral conditions as well as conditions with increasing acidity. 

Each experiment set contained 50-100 1HNMR spectroscopy experiments that were run on the same sample using a program that built in delays. Dimethyl sulfoxide was used as an internal standard, and its signal size was used as a scale to report the changes in relative concentration of the four species throughout the experiment sets.

Under neutral conditions D-glucaro-1,4-lactone is relatively stable against equilibration, while D-glucaro-1,4;6,3-dilactone is not. Under acidic conditions both compounds equilibrate within approximately 30,000 seconds. After equilibration under acidic conditions D-glucaric acid is the dominant species, while the relative concentration of D-glucaro-1,4-lactone is slightly higher than that of D-glucaro-6,3-lactone. The relative equilibrium concentration of D-glucaro-1,4;6,3-dilactone is low.

A mechanism for the equilibration of aqueous D-glucaric acid was proposed and equilibrium constants and estimates of rate constants were derived from the experimental data. These rate constants were used in MATLAB simulations that were compared to the experimental data. MATLAB simulations were used to alter the rate constants to improve the fits between experimental data and simulated data.

year: 2007

title: Software agents in music and sound art research/creative work: Current state and a possible direction

authors: Whalley, Ian

subjects: music

abstract: Composers, musicians and computer scientists have begun to use software-based agents to create music and sound art in both linear and non-linear (non-predetermined form and/or content) idioms, with some robust approaches now drawing on various disciplines. This paper surveys recent work: agent technology is first introduced, a theoretical framework for its use in creating music/sound art works put forward, and an overview of common approaches then given. Identifying areas of neglect in recent research, a possible direction for further work is then briefly explored. Finally, a vision for a new hybrid model that integrates non-linear, generative, conversational and affective perspectives on interactivity is proposed.

text: Software agents in music and sound art research/creative work: Current state and a possible direction Composers, musicians and computer scientists have begun to use software-based agents to create music and sound art in both linear and non-linear (non-predetermined form and/or content) idioms, with some robust approaches now drawing on various disciplines. This paper surveys recent work: agent technology is first introduced, a theoretical framework for its use in creating music/sound art works put forward, and an overview of common approaches then given. Identifying areas of neglect in recent research, a possible direction for further work is then briefly explored. Finally, a vision for a new hybrid model that integrates non-linear, generative, conversational and affective perspectives on interactivity is proposed.

year: 2009

title: The coastal habitats of Tairawhiti: A review of the scientific, local, and customary knowledge

authors: Ross, Philip M.

abstract: In Aotearoa/New Zealand, regional councils and unitary authorities have a range of responsibilities for decision making in the coastal and marine area (CMA). The New Zealand Coastal Policy Statement (2010), in policy 11, sets out requirements for avoiding significant adverse effects on species, habitats and ecosystems, and section 67 of the Resource Management Act (1991) indicates that regional plans must give effect to the New Zealand Coastal Policy Statement. For regional councils to be able to successfully manage indigenous marine biodiversity (composed of species, habitats and ecosystems) they must have some understanding of the types of biodiversity present within a region’s CMA, and knowledge of the spatial distribution of that biodiversity. For regions such as Auckland and Northland biodiversity in the CMA has been relatively well described. For example, the Department of Conservation has compiled a marine habitat map for the Northland section of the Northeast Marine Bioregion, which covers an area of 1.34 million hectares of coastal habitat from Ahipara to Mangawhai (https://www.nrc.govt.nz/resource-library-summary/research-and-reports/coastal/).
This knowledge makes it much easier for councils to develop coastal plans that provide appropriate protections and management outcomes. In other regions, less information is available which can make it difficult to put in place appropriate environmental management.
The Gisborne Region (Tairawhiti) is a region for which there is comparatively little information available regarding marine biodiversity and the distribution of coastal habitats. The region has been under-represented in coastal research to date, which is largely a consequence of its remoteness to institutions conducting research in the CMA (Universities, CRIs and other research providers). Consequently the Gisborne District Council (GDC), the unitary authority responsible for Tairawhiti, does not have readily available and robust information about the marine and coastal environments of the region. This lack of knowledge spans the range of coastal habitats which GDC has the task of managing under the Resource Management Act (1991).
As a first step towards gathering the information required to better manage the Tairawhiti CMA, this report collates and summarises the available scientific, local and customary knowledge on the extent, location and state of marine and estuarine habitats within the Tairawhiti region. In addition to the collation of this information, additional objectives for this report include: identifying gaps in the information base; recording information that might explain how pressures and activities within the region may have altered coastal habitats; providing advice on priorities for additional work required to fill knowledge gaps; and where possible, include mātauranga Māori in accordance with tikanga. With this knowledge, GDC will be in a better position to facilitate the development of a Regional Plan for Tairāwhiti to set the strategic direction for growth, development and resource management over the next 30 years.

text: The coastal habitats of Tairawhiti: A review of the scientific, local, and customary knowledge In Aotearoa/New Zealand, regional councils and unitary authorities have a range of responsibilities for decision making in the coastal and marine area (CMA). The New Zealand Coastal Policy Statement (2010), in policy 11, sets out requirements for avoiding significant adverse effects on species, habitats and ecosystems, and section 67 of the Resource Management Act (1991) indicates that regional plans must give effect to the New Zealand Coastal Policy Statement. For regional councils to be able to successfully manage indigenous marine biodiversity (composed of species, habitats and ecosystems) they must have some understanding of the types of biodiversity present within a region’s CMA, and knowledge of the spatial distribution of that biodiversity. For regions such as Auckland and Northland biodiversity in the CMA has been relatively well described. For example, the Department of Conservation has compiled a marine habitat map for the Northland section of the Northeast Marine Bioregion, which covers an area of 1.34 million hectares of coastal habitat from Ahipara to Mangawhai (https://www.nrc.govt.nz/resource-library-summary/research-and-reports/coastal/).
This knowledge makes it much easier for councils to develop coastal plans that provide appropriate protections and management outcomes. In other regions, less information is available which can make it difficult to put in place appropriate environmental management.
The Gisborne Region (Tairawhiti) is a region for which there is comparatively little information available regarding marine biodiversity and the distribution of coastal habitats. The region has been under-represented in coastal research to date, which is largely a consequence of its remoteness to institutions conducting research in the CMA (Universities, CRIs and other research providers). Consequently the Gisborne District Council (GDC), the unitary authority responsible for Tairawhiti, does not have readily available and robust information about the marine and coastal environments of the region. This lack of knowledge spans the range of coastal habitats which GDC has the task of managing under the Resource Management Act (1991).
As a first step towards gathering the information required to better manage the Tairawhiti CMA, this report collates and summarises the available scientific, local and customary knowledge on the extent, location and state of marine and estuarine habitats within the Tairawhiti region. In addition to the collation of this information, additional objectives for this report include: identifying gaps in the information base; recording information that might explain how pressures and activities within the region may have altered coastal habitats; providing advice on priorities for additional work required to fill knowledge gaps; and where possible, include mātauranga Māori in accordance with tikanga. With this knowledge, GDC will be in a better position to facilitate the development of a Regional Plan for Tairāwhiti to set the strategic direction for growth, development and resource management over the next 30 years.

year: 2021