title: Manganese carbonyl-mediated reactions of azabutadienes with phenylacetylene, methyl acrylate and other unsaturated molecules

authors: Mace, Wade

subjects: azabutadienes

abstract: Reaction of PhCH₂Mn(CO)₅ with l,4-di-aryl-1-aza-1,3-butadienes gave substituted pyrrolinonyl rings which were η⁴-coordinated to a Mn(CO)₃ group. These are formed by intramolecular CO insertion into a (non-isolated) cyclomanganated intermediate, followed by cyclisation. Other unsaturated reagents (PhC≡CH, CH2=CHCOOMe, PhNCO) gave products arising from insertion of these, including a structurally characterised tri-aryl-η⁵-azacyclohexadienyl-Mn(CO)₃ complex from the reaction with the alkyne.
PhCH₂Mn(CO)₅ reacts with l,4-di-aryl-1-aza-1,3-butadienes in the presence of unsaturated substrates to give products based on a cyclomanganated intermediate.

text: Manganese carbonyl-mediated reactions of azabutadienes with phenylacetylene, methyl acrylate and other unsaturated molecules Reaction of PhCH₂Mn(CO)₅ with l,4-di-aryl-1-aza-1,3-butadienes gave substituted pyrrolinonyl rings which were η⁴-coordinated to a Mn(CO)₃ group. These are formed by intramolecular CO insertion into a (non-isolated) cyclomanganated intermediate, followed by cyclisation. Other unsaturated reagents (PhC≡CH, CH2=CHCOOMe, PhNCO) gave products arising from insertion of these, including a structurally characterised tri-aryl-η⁵-azacyclohexadienyl-Mn(CO)₃ complex from the reaction with the alkyne.
PhCH₂Mn(CO)₅ reacts with l,4-di-aryl-1-aza-1,3-butadienes in the presence of unsaturated substrates to give products based on a cyclomanganated intermediate.

year: 2004-08-01

title: Translation and validation of the Arabic version of the Digital Stress Scale (DSS-A) with three Arabic-speaking samples

authors: Krägeloh, Christian U.

abstract: Objective: Given the ubiquitous nature of digital technologies such as smartphones, research has increasingly focused on the health outcomes of prolonged use of such technologies. The Digital Stress Scale (DSS) has been developed recently, but it is currently only available in English and Chinese, and validations in other languages are warranted. 
Methods: The 24-item DSS was translated into Arabic using the method of translation and back-translation. Using a general population sample (n = 1069) from Saudi Arabia, Oman, and Jordan, the psychometric properties of the Arabic DSS (DSS-A) were investigated using higher-order confirmatory factor analysis.
Results: The original five-factor structure was replicated for the DSS-A without the need for any modifications such as item deletion or reassignment of items to another factor. Reliability was excellent for the total scale score (α = 0.92) as well as for the five subscales (α ranged between 0.81 and 0.91). Convergent validity was supported by significant correlations between the DSS-A and psychological distress. 
Conclusion: The strong psychometric properties of the DSS-A imply that this scale can now be used with high validity and reliability to explore the role of digital stress and its sub-characteristics in Arabic-speaking populations.

text: Translation and validation of the Arabic version of the Digital Stress Scale (DSS-A) with three Arabic-speaking samples Objective: Given the ubiquitous nature of digital technologies such as smartphones, research has increasingly focused on the health outcomes of prolonged use of such technologies. The Digital Stress Scale (DSS) has been developed recently, but it is currently only available in English and Chinese, and validations in other languages are warranted. 
Methods: The 24-item DSS was translated into Arabic using the method of translation and back-translation. Using a general population sample (n = 1069) from Saudi Arabia, Oman, and Jordan, the psychometric properties of the Arabic DSS (DSS-A) were investigated using higher-order confirmatory factor analysis.
Results: The original five-factor structure was replicated for the DSS-A without the need for any modifications such as item deletion or reassignment of items to another factor. Reliability was excellent for the total scale score (α = 0.92) as well as for the five subscales (α ranged between 0.81 and 0.91). Convergent validity was supported by significant correlations between the DSS-A and psychological distress. 
Conclusion: The strong psychometric properties of the DSS-A imply that this scale can now be used with high validity and reliability to explore the role of digital stress and its sub-characteristics in Arabic-speaking populations.

year: 2023-12-01

title: The presence of the past: Maori history in contemporary reflection

authors: Mahuika, Nepia

abstract: This is the opening line of a famous saying in my tribe. For our people - Ngāti Porou - these words have become embedded in our tribal identity as important directives that we are encouraged to aspire to. In the “days destined to you”, Ngata reminds us that each generation has its own mana (or authority), our own responsibilities and challenges, our own dreams and destinies to fulfil, and our own histories to tell about Ngāti Porou: who we are, our past, present, and future. If we consider this expectant, and I think hopeful, affirmation as a gift and responsibility, then taking real ownership of the “days destined to us” requires us to know what our forebears have entrusted us with. What are those historical gifts that we might use to “centre” and assert ourselves as Māori, as Ngāti Porou? We might look at this directly, i mua: the past before us because it is our history that is so crucial to us as we walk consciously, and with determination, into the future. Our past before us helps us to know where we are going, it helps us correc our course when we stray, keeps us mindful of the “kaupapa”: whatever that might be in our generation and corner of the Maori universe. We’ve heard already today from both Enoka and Arini how Māori, in our own ways, are engaging with our past, drawing on our korero tuku iho (our oral histories passed down across the generations), on our whakairo (our carving), to illuminate the many ways Māori do, and think about, the past.

text: The presence of the past: Maori history in contemporary reflection This is the opening line of a famous saying in my tribe. For our people - Ngāti Porou - these words have become embedded in our tribal identity as important directives that we are encouraged to aspire to. In the “days destined to you”, Ngata reminds us that each generation has its own mana (or authority), our own responsibilities and challenges, our own dreams and destinies to fulfil, and our own histories to tell about Ngāti Porou: who we are, our past, present, and future. If we consider this expectant, and I think hopeful, affirmation as a gift and responsibility, then taking real ownership of the “days destined to us” requires us to know what our forebears have entrusted us with. What are those historical gifts that we might use to “centre” and assert ourselves as Māori, as Ngāti Porou? We might look at this directly, i mua: the past before us because it is our history that is so crucial to us as we walk consciously, and with determination, into the future. Our past before us helps us to know where we are going, it helps us correc our course when we stray, keeps us mindful of the “kaupapa”: whatever that might be in our generation and corner of the Maori universe. We’ve heard already today from both Enoka and Arini how Māori, in our own ways, are engaging with our past, drawing on our korero tuku iho (our oral histories passed down across the generations), on our whakairo (our carving), to illuminate the many ways Māori do, and think about, the past.

year: 2016