title: cyclo-Tetra-μ-oxido-tetrakis[3-nitro-4-hydroxyphenylarsenic(III)]

authors: Lloyd, Nicholas C.

subjects: metal-organic compound

abstract: The title compound, [As₄O₄(C₆H₄NO₃)₄], has an eight-membered As₄O₄ ring with a slightly twisted boat-chair conformation. The aryl groups complete the threefold coordination for each As atom. Each OH group forms a strong intramolecular O-H⋯O hydrogen bond to the adjacent NO₂ group, with only weak C-H⋯O, O⋯As [3.036 (6)-3.184 (6) Å] and O⋯O [2.921 (10)-2.930 (10) Å] interactions between tetramers.

text: cyclo-Tetra-μ-oxido-tetrakis[3-nitro-4-hydroxyphenylarsenic(III)] The title compound, [As₄O₄(C₆H₄NO₃)₄], has an eight-membered As₄O₄ ring with a slightly twisted boat-chair conformation. The aryl groups complete the threefold coordination for each As atom. Each OH group forms a strong intramolecular O-H⋯O hydrogen bond to the adjacent NO₂ group, with only weak C-H⋯O, O⋯As [3.036 (6)-3.184 (6) Å] and O⋯O [2.921 (10)-2.930 (10) Å] interactions between tetramers.

year: 2007

title: Compact nonlinear model of an implantable electrode array for spinal cord stimulation (SCS)

authors: Scott, Jonathan B.

subjects: electrical stimulation

abstract: We describe the construction of a model of the electrode-electrolyte interface and surrounding electrolyte in the case of a platinum-electrode array intended for spinal-cord stimulation (SCS) application. We show that a finite, two dimensional, resistor array provides a satisfactory model of the bulk electrolyte, and we identify the complexity required of that resistor array. The electrode-electrolyte interface is modelled in a fashion suitable for commonly-available, compact simulators using a nonlinear extension of the model of Franks et al. that incorporates diodes and a memristor. The electrode-electrolyte interface model accounts for the nonlinear current-overpotential characteristic and diffusion-limiting effects. We characterise a commercial, implantable, electrode array, fit the model to it, and show that the model successfully predicts subtle operational characteristics.

text: Compact nonlinear model of an implantable electrode array for spinal cord stimulation (SCS) We describe the construction of a model of the electrode-electrolyte interface and surrounding electrolyte in the case of a platinum-electrode array intended for spinal-cord stimulation (SCS) application. We show that a finite, two dimensional, resistor array provides a satisfactory model of the bulk electrolyte, and we identify the complexity required of that resistor array. The electrode-electrolyte interface is modelled in a fashion suitable for commonly-available, compact simulators using a nonlinear extension of the model of Franks et al. that incorporates diodes and a memristor. The electrode-electrolyte interface model accounts for the nonlinear current-overpotential characteristic and diffusion-limiting effects. We characterise a commercial, implantable, electrode array, fit the model to it, and show that the model successfully predicts subtle operational characteristics.

year: 2013

title: Te mana o te wahine: Young mothers healthcare experiences in pregnancy, birth, and into motherhood

authors: Kolo, Mia Elaine

subjects: Health

abstract: In Aotearoa-New Zealand being a young mother is often associated with clinical and societal ‘risks.’ Younger women have higher rates of maternal depression and suicide, complications during birth, and their babies are more likely to be born preterm, and of smaller gestational age and weight (Perinatal and Maternal Mortality Review Committee, 2012; Te Whatu Ora - Health New Zealand, 2023b, 2023a). Research also indicates that young mothers experience stigmatisation and discrimination that they attribute to their age and/or ethnicity (Adcock, 2016; Makowharemahihi et al., 2014; Rawiri, 2007; Ware, 2019).
In discussion with researchers, discrimination was the topic that young mothers at He Puaawai Teen Parent Centre wanted to talk about. They shared a strong desire to see change in the way that doctors, nurses, and midwives service young parents and were passionate about ensuring that future young mothers had more support. Thus, in responding to their call, 22 parents, including two fathers attending (or recent school-leavers of) He Puaawai Teen Parent Centre volunteered to participate in this study. This qualitative kaupapa Māori study employed a series of wānanga, individual kōrero, and an investigator-triangulation thematic analysis. The research questions explored both the positive and negative healthcare experiences of this cohort during pregnancy, birth, and into motherhood.
The aim of this study was to listen and learn about the experiences of these young parents and co-design informational and/or educational materials to help healthcare practitioners better understand and support young mothers/parents. To spread awareness of the experiences of these young parents, the co-design materials and findings of this study were disseminated via various healthcare seminars and meetings around the Waikato region. The findings of this study contribute to previous research that revealed over the last 20 years young parents have continued to report predominantly negative experiences in their maternity journey. Participants of this study reported experiences of unsolicited judgement and advice, a general lack of manaakitanga (care, empathy, respect), communication, and support from doctors, nurses, and midwives. The relatively small number of positive experiences shared in this study emphasises the importance of manaakitanga regardless of age. An unexpected finding was the impact that receptionists had on young parents’ healthcare experiences, as the face and entry point of healthcare services.

text: Te mana o te wahine: Young mothers healthcare experiences in pregnancy, birth, and into motherhood In Aotearoa-New Zealand being a young mother is often associated with clinical and societal ‘risks.’ Younger women have higher rates of maternal depression and suicide, complications during birth, and their babies are more likely to be born preterm, and of smaller gestational age and weight (Perinatal and Maternal Mortality Review Committee, 2012; Te Whatu Ora - Health New Zealand, 2023b, 2023a). Research also indicates that young mothers experience stigmatisation and discrimination that they attribute to their age and/or ethnicity (Adcock, 2016; Makowharemahihi et al., 2014; Rawiri, 2007; Ware, 2019).
In discussion with researchers, discrimination was the topic that young mothers at He Puaawai Teen Parent Centre wanted to talk about. They shared a strong desire to see change in the way that doctors, nurses, and midwives service young parents and were passionate about ensuring that future young mothers had more support. Thus, in responding to their call, 22 parents, including two fathers attending (or recent school-leavers of) He Puaawai Teen Parent Centre volunteered to participate in this study. This qualitative kaupapa Māori study employed a series of wānanga, individual kōrero, and an investigator-triangulation thematic analysis. The research questions explored both the positive and negative healthcare experiences of this cohort during pregnancy, birth, and into motherhood.
The aim of this study was to listen and learn about the experiences of these young parents and co-design informational and/or educational materials to help healthcare practitioners better understand and support young mothers/parents. To spread awareness of the experiences of these young parents, the co-design materials and findings of this study were disseminated via various healthcare seminars and meetings around the Waikato region. The findings of this study contribute to previous research that revealed over the last 20 years young parents have continued to report predominantly negative experiences in their maternity journey. Participants of this study reported experiences of unsolicited judgement and advice, a general lack of manaakitanga (care, empathy, respect), communication, and support from doctors, nurses, and midwives. The relatively small number of positive experiences shared in this study emphasises the importance of manaakitanga regardless of age. An unexpected finding was the impact that receptionists had on young parents’ healthcare experiences, as the face and entry point of healthcare services.

year: 2024