title: Identification of the dimethylamine-trimethylamine complex in the gas phase

authors: Du, Lin

subjects: chemistry

abstract: We have identified the dimethylamine-trimethylamine complex (DMA-TMA) at room temperature in the gas phase. The Fourier transform infrared (FTIR) spectrum of DMA-TMA in the NH-stretching fundamental region was obtained by spectral subtraction of spectra of each monomer. Explicitly correlated coupled cluster calculations were used to determine the minimum energy structure and interaction energy of DMA-TMA. Frequencies and intensities of NH-stretching transitions were also calculated at this level of theory with an anharmonic oscillator local mode model. The fundamental NH-stretching intensity in DMA-TMA is calculated to be approximately 700 times larger than that of the DMA monomer. The measured and calculated intensity is used to determine a room temperature equilibrium constant of DMA-TMA of 1.7 × 10⁻³ atm⁻¹ at 298 K.

text: Identification of the dimethylamine-trimethylamine complex in the gas phase We have identified the dimethylamine-trimethylamine complex (DMA-TMA) at room temperature in the gas phase. The Fourier transform infrared (FTIR) spectrum of DMA-TMA in the NH-stretching fundamental region was obtained by spectral subtraction of spectra of each monomer. Explicitly correlated coupled cluster calculations were used to determine the minimum energy structure and interaction energy of DMA-TMA. Frequencies and intensities of NH-stretching transitions were also calculated at this level of theory with an anharmonic oscillator local mode model. The fundamental NH-stretching intensity in DMA-TMA is calculated to be approximately 700 times larger than that of the DMA monomer. The measured and calculated intensity is used to determine a room temperature equilibrium constant of DMA-TMA of 1.7 × 10⁻³ atm⁻¹ at 298 K.

year: 2012

title: Video-based detection of shorelines at complex mesomacro tidal beaches

authors: Almar, Rafael

subjects: intertidal beach morphology

abstract: Remote video imagery is widely used to acquire measurements of intertidal topography by means of shoreline detection, but, up to now, problems of accuracy were still encountered in the challenging case of energetic waves in nonuniform, mesomacro tidal environments. Unique, simultaneous, video-based and global positioning system (GPS)based measurements of shoreline were undertaken at Truc Vert (France), a beach with such characteristics. An innovative video method, referred to herein as the Minimum Shoreline Variability (MSV) method, was developed to cope with highly variable spatiotemporal shoreline properties. The comparison of video-based and GPS-derived shoreline data sets showed that using images averaged over short periods (30 s), rather than the traditionally used 10-min averaged images, significantly improved the accuracy of shoreline determination. A local video-derived, swash-based shoreline correction was also developed to correct for the MSV error, which was found to be linearly correlated to local swash length. By combining shorter time-averaged images and video derived local swash correction factors, the horizontal root mean square error associated with MSV shorelines was reduced to 1.2 m, which is equivalent to errors reported at more uniform, microtidal, and less-energetic beaches.

text: Video-based detection of shorelines at complex mesomacro tidal beaches Remote video imagery is widely used to acquire measurements of intertidal topography by means of shoreline detection, but, up to now, problems of accuracy were still encountered in the challenging case of energetic waves in nonuniform, mesomacro tidal environments. Unique, simultaneous, video-based and global positioning system (GPS)based measurements of shoreline were undertaken at Truc Vert (France), a beach with such characteristics. An innovative video method, referred to herein as the Minimum Shoreline Variability (MSV) method, was developed to cope with highly variable spatiotemporal shoreline properties. The comparison of video-based and GPS-derived shoreline data sets showed that using images averaged over short periods (30 s), rather than the traditionally used 10-min averaged images, significantly improved the accuracy of shoreline determination. A local video-derived, swash-based shoreline correction was also developed to correct for the MSV error, which was found to be linearly correlated to local swash length. By combining shorter time-averaged images and video derived local swash correction factors, the horizontal root mean square error associated with MSV shorelines was reduced to 1.2 m, which is equivalent to errors reported at more uniform, microtidal, and less-energetic beaches.

year: 2012

title: Leadership: Going beyond personal will and professional skills to give life to Ka Hikitia

authors: Berryman, Mere

subjects: education policy

abstract: This paper investigates the Ka Hikitia Māori education policy and its subsequent influence in effecting system change towards Māori students’ achievement. It discusses how a Request for Proposal to the Ministry of Education’s Building on Success was conceptualised to support English-medium secondary schools across New Zealand to address this policy. The result, Kia Eke Panuku, is a professional learning and development response that works with Strategic Change Leadership Teams to create culturally responsive and relational contexts for learning, focused on Māori students enjoying and achieving educational success as Māori. It is argued that neither a political mandate for change nor a set of learned strategies by school personnel will truly bring about a changed reality for Māori students. Rather the reform must be led by transformative leaders who are driven by both the moral imperative to change and a keen sense of urgency to see this happen in our schools for Māori students and their home communities.
The major issues raised in this paper, and the solutions that have been reached thus far, can help inform others who are trying to raise the participation, inclusion and achievement of students who may currently be marginalised from formal education settings.

text: Leadership: Going beyond personal will and professional skills to give life to Ka Hikitia This paper investigates the Ka Hikitia Māori education policy and its subsequent influence in effecting system change towards Māori students’ achievement. It discusses how a Request for Proposal to the Ministry of Education’s Building on Success was conceptualised to support English-medium secondary schools across New Zealand to address this policy. The result, Kia Eke Panuku, is a professional learning and development response that works with Strategic Change Leadership Teams to create culturally responsive and relational contexts for learning, focused on Māori students enjoying and achieving educational success as Māori. It is argued that neither a political mandate for change nor a set of learned strategies by school personnel will truly bring about a changed reality for Māori students. Rather the reform must be led by transformative leaders who are driven by both the moral imperative to change and a keen sense of urgency to see this happen in our schools for Māori students and their home communities.
The major issues raised in this paper, and the solutions that have been reached thus far, can help inform others who are trying to raise the participation, inclusion and achievement of students who may currently be marginalised from formal education settings.

year: 2015