title: Biodegradation of bloodmeal-based thermoplastics in green-waste composting

authors: Verbeek, Casparus Johan R.

subjects: bloodmeal

abstract: Polymers that are compostable and manufactured from renewable resources have gained significant importance in recent years. The objective of this work was to assess the biodegradability of bloodmeal-based thermoplastics in a commercial green-waste composting situation. Materials plasticised with tri-ethylene–glycol lost about 45% of their original mass after 12 weeks composting while unplasticised samples lost 35%. Degradation appeared to have been in two phases; an initial loss of soluble, low molecular compounds in the mesophilic phase followed by degradation of high molecular compounds as the temperature exceeded about 40 °C in the thermophilic phase. It was found that as degradation proceeded materials became more soluble. In addition, plasticised and unplasticized samples contained about 60 wt% moisture after 4 weeks of composting conditioning at 50% relative humidity resulted in approximately 8–10 wt% moisture, unaffected by the extent of degradation. FTIR revealed that proteins underwent hydrolytic cleavage resulting in the formation of primary amines. A significant reduction in combustion temperature was observed, indicative of a reduction in covalent bonding, likely due to shorter chains lengths or less cross-linking.

text: Biodegradation of bloodmeal-based thermoplastics in green-waste composting Polymers that are compostable and manufactured from renewable resources have gained significant importance in recent years. The objective of this work was to assess the biodegradability of bloodmeal-based thermoplastics in a commercial green-waste composting situation. Materials plasticised with tri-ethylene–glycol lost about 45% of their original mass after 12 weeks composting while unplasticised samples lost 35%. Degradation appeared to have been in two phases; an initial loss of soluble, low molecular compounds in the mesophilic phase followed by degradation of high molecular compounds as the temperature exceeded about 40 °C in the thermophilic phase. It was found that as degradation proceeded materials became more soluble. In addition, plasticised and unplasticized samples contained about 60 wt% moisture after 4 weeks of composting conditioning at 50% relative humidity resulted in approximately 8–10 wt% moisture, unaffected by the extent of degradation. FTIR revealed that proteins underwent hydrolytic cleavage resulting in the formation of primary amines. A significant reduction in combustion temperature was observed, indicative of a reduction in covalent bonding, likely due to shorter chains lengths or less cross-linking.

year: 2011

title: Bis[μ-bis(diphenylphosphino)methane-К²P:P’]bis[(saccharinato-КN)-
palladium(I)] dichloromethane solvate

authors: Henderson, William

subjects: chemistry

abstract: The dimeric palladium(I) saccharinate complex [Pd₂(sac)₂(dppm)₂], has been characterized as its di¬chloro¬methane solvate, i.e. [Pd₂(C₇H₄NO₃S)₂(C₂₅H₂₂P₂)₂]•CH₂Cl₂. The complex features a Pd—Pd bond bridged by two dppm ligands, with the saccharinate ligands N-bonded trans to the Pd—Pd bond.

text: Bis[μ-bis(diphenylphosphino)methane-К²P:P’]bis[(saccharinato-КN)-
palladium(I)] dichloromethane solvate The dimeric palladium(I) saccharinate complex [Pd₂(sac)₂(dppm)₂], has been characterized as its di¬chloro¬methane solvate, i.e. [Pd₂(C₇H₄NO₃S)₂(C₂₅H₂₂P₂)₂]•CH₂Cl₂. The complex features a Pd—Pd bond bridged by two dppm ligands, with the saccharinate ligands N-bonded trans to the Pd—Pd bond.

year: 2002

title: A brief history of Whakapapa: Māori approaches to genealogy

authors: Mahuika, Nepia

subjects: whakapapa

abstract: Whakapapa is the Māori term for genealogy. It has been described by some as the skeletal structure of Maori epistemology because all things have their own genealogies. In research, whakapapa has been presented in tribal histories, Maori Land Court records, and consistently as a framework for matauranga Māori (Māori knowledge) and Māori research methodologies. This essay offers a brief overview of the ways in which whakapapa has been understood and negotiated in research particularly after the arrival of Europeans. Some early ethnographers, for instance, applied their own genealogical methods of dating to whakapapa, which influenced various Māori approaches from the twentieth century. With the advent of literacy and print, Māori experimented with new ways to record genealogy, and yet the underlying oral, ethical, and cultural practices that are crucial to whakapapa have remained integral to how it still lives and operates in Maori communities today.

text: A brief history of Whakapapa: Māori approaches to genealogy Whakapapa is the Māori term for genealogy. It has been described by some as the skeletal structure of Maori epistemology because all things have their own genealogies. In research, whakapapa has been presented in tribal histories, Maori Land Court records, and consistently as a framework for matauranga Māori (Māori knowledge) and Māori research methodologies. This essay offers a brief overview of the ways in which whakapapa has been understood and negotiated in research particularly after the arrival of Europeans. Some early ethnographers, for instance, applied their own genealogical methods of dating to whakapapa, which influenced various Māori approaches from the twentieth century. With the advent of literacy and print, Māori experimented with new ways to record genealogy, and yet the underlying oral, ethical, and cultural practices that are crucial to whakapapa have remained integral to how it still lives and operates in Maori communities today.

year: 2019