title: Osmotic Dehydration of New Zealand Chestnuts with and without Shell and Pellicle

authors: Pontawe, Reagan Jazmin

abstract: Osmotic dehydration offers an alternative to air-drying for reducing moisture content at ambient temperature. Of four different solutes investigated, 22% (mass basis) sodium chloride (NaCl) and 60% (mass basis) sucrose solutions were the most successful, with each achieving approximately a 10% reduction in wet basis moisture content after 8 h without significant detrimental side effects, although NaCl solutions cause noticeable darkening in the pits on the surface of the chestnuts. The presence of the shell and pellicle did not significantly affect the dehydration rate. Osmotic dehydration by NaCl or sucrose prior to mechanical shell removal produced a small increase in efficiency of the shell removal process.

text: Osmotic Dehydration of New Zealand Chestnuts with and without Shell and Pellicle Osmotic dehydration offers an alternative to air-drying for reducing moisture content at ambient temperature. Of four different solutes investigated, 22% (mass basis) sodium chloride (NaCl) and 60% (mass basis) sucrose solutions were the most successful, with each achieving approximately a 10% reduction in wet basis moisture content after 8 h without significant detrimental side effects, although NaCl solutions cause noticeable darkening in the pits on the surface of the chestnuts. The presence of the shell and pellicle did not significantly affect the dehydration rate. Osmotic dehydration by NaCl or sucrose prior to mechanical shell removal produced a small increase in efficiency of the shell removal process.

year: 2016-01-01

title: Fate and effects of pulp mill effluent solids in the soil environment

authors: Fraser, Donald Scott

subjects: pulp mill effluent

abstract: The pulp and paper industry in New Zealand annually produces over one hundred thousand dry tonnes of solid waste due to the treatment of pulp and paper mill effluents, the majority of which is currently landfilled. The New Zealand Waste Management Strategy (2002) has set a target for  the diversion of commercial organic wastes from landfill to beneficial use to exceed 95% by 2010 . 

Effluents produced by softwood pulp mills, such as in New Zealand, contain high concentrations of naturally derived resin extractive compounds that are toxic to fish and other aquatic organisms. Improvements in waste water treatment technology has enabled the industry to meet rigorous discharge standards, however, this has resulted in an increase in the production of pulp mill effluent solids which require disposal. This has become an issue for the pulp and paper industry, especially as current landfill space is limited. Land application has been used for many years as a means of disposal of pulp mill wastes. While most studies investigating land application of pulp mill effluent solids have concluded that the risk posed to the environment is low, few have investigated the potential toxicity of these wastes to soil organisms, and these studies did not directly address the effects of resin extractive compounds. 

Resin extractives have been shown to be recalcitrant and to accumulate in anaerobic sediments. It is not known to what extent resin extractives are bioavailable or degradable in land applied Pulp mill effluent solids (PMES), or their potential to bioaccumulate in soil organisms.

This PhD thesis research sought to extend the knowledge on the environmental fate and effects of pulp mill effluent wastes. It focused on terrestrial systems, which have not been well studied in this respect. Four chemically distinct softwood pulp mill effluent solids, a primary treatment solid and three secondary treatment biosolids, were used to investigate their effects on soil organisms and soil functions. An interdisciplinary approach was adopted, which incorporated three main areas of study, as follows:
1. A comprehensive resin extractives analysis of the pulp mill effluent solids undertaken so that effects on soil organisms and soil functions could be related to the resin extractives chemistry of the individual pulp mill effluent solids tested. 
2.  A battery of bioassays used to investigate the toxicity of the selected pulp mill effluent solids. 
3.	A field trial set-up to investigate how pulp mill effluent solids affected soil functions and also to investigate the decomposition of pulp mill effluent solids and of resin extractives in these solids. 

Three hypotheses tested were:
 I. Pulp mill effluent solids are toxic to soil organisms.
II. Resin extractives in pulp mill effluent solids are recalcitrant in the terrestrial environment.
III. Pulp mill effluent solids will cause significant measurable negative impacts on soil functional capacity.

A wide range of resin extractives compounds were identified in pulp mill effluent solids, and concentrations of individual compounds varied widely between the different pulp mill effluent solids tested. During the two years after field application of the pulp mill effluent solids, resin extractives declined, however, decay rates of individual compounds were variable. The decay rate of compounds was influenced by the type of pulp mill effluent solids containing these compounds and not by the initial concentration of compounds. All compounds, including resin acids, degraded rapidly in the applied primary solid and in one of the applied biosolids, with average half-lives calculated ranging from three to twelve months. In the other biosolids, resin acids were recalcitrant with average half-lives calculated to be nearly ten years. 

Laboratory bioassays conducted on oats, earthworms and enchytraeid worms indicated that pulp mill effluent solids had low toxicity to these organisms. An aquatic bioassay organism, however, was acutely affected by aqueous extracts from pulp mill effluent solids. Earthworms were shown to bioaccumulate some resin extractive compounds to a limited extent, indicating that resin extractives were bioavailable in pulp mill effluent solids. Enchytraeid reproduction was reduced by exposure to some pulp mill effluent solids but this was not correlated to resin extractives concentration of the solids tested. 

Field applied pulp mill effluent solids significantly enhanced the fluxes of CO2 from the soil surface. When mass losses of pulp mill effluent solids carbon were taken into account, it was shown that these solids had little effect on soil respiration. Needle litterbags were placed above and below pulp mill effluent solids and in the litter horizon of a control treatment for 12 months. Needle litter decomposition was not significantly different between treatments, however, changes in enzyme activities were detected in litter beneath pulp mill effluent solids compared to control needle litter that had not been exposed to pulp mill effluent solids. The decomposition rate of field applied pulp mill effluent solids was slow, with half-lives extrapolated to be between five and twenty five years. The decomposition rate appeared to be influenced by the pools of carbon available for decomposition, with primary solids decaying significantly faster than biosolids due to a higher cellulose component.

The conclusions of the PhD thesis research are, therefore, that generally, pulp mill effluent solids used in the study were demonstrated to be relatively benign and appear to pose a low risk to the terrestrial ecosystem when applied to soil. However, a cautious approach is still recommended to land application, based on the extensive evidence of disruption to aquatic ecosystems, and because pulp mill effluent solids will take many years to decompose and resin acids are recalcitrant in some pulp mill effluent solids. Further research is recommended to elucidate mechanisms of action by resin extractives in soil organisms and the ultimate fate of these compounds in the soil compartment.

text: Fate and effects of pulp mill effluent solids in the soil environment The pulp and paper industry in New Zealand annually produces over one hundred thousand dry tonnes of solid waste due to the treatment of pulp and paper mill effluents, the majority of which is currently landfilled. The New Zealand Waste Management Strategy (2002) has set a target for  the diversion of commercial organic wastes from landfill to beneficial use to exceed 95% by 2010 . 

Effluents produced by softwood pulp mills, such as in New Zealand, contain high concentrations of naturally derived resin extractive compounds that are toxic to fish and other aquatic organisms. Improvements in waste water treatment technology has enabled the industry to meet rigorous discharge standards, however, this has resulted in an increase in the production of pulp mill effluent solids which require disposal. This has become an issue for the pulp and paper industry, especially as current landfill space is limited. Land application has been used for many years as a means of disposal of pulp mill wastes. While most studies investigating land application of pulp mill effluent solids have concluded that the risk posed to the environment is low, few have investigated the potential toxicity of these wastes to soil organisms, and these studies did not directly address the effects of resin extractive compounds. 

Resin extractives have been shown to be recalcitrant and to accumulate in anaerobic sediments. It is not known to what extent resin extractives are bioavailable or degradable in land applied Pulp mill effluent solids (PMES), or their potential to bioaccumulate in soil organisms.

This PhD thesis research sought to extend the knowledge on the environmental fate and effects of pulp mill effluent wastes. It focused on terrestrial systems, which have not been well studied in this respect. Four chemically distinct softwood pulp mill effluent solids, a primary treatment solid and three secondary treatment biosolids, were used to investigate their effects on soil organisms and soil functions. An interdisciplinary approach was adopted, which incorporated three main areas of study, as follows:
1. A comprehensive resin extractives analysis of the pulp mill effluent solids undertaken so that effects on soil organisms and soil functions could be related to the resin extractives chemistry of the individual pulp mill effluent solids tested. 
2.  A battery of bioassays used to investigate the toxicity of the selected pulp mill effluent solids. 
3.	A field trial set-up to investigate how pulp mill effluent solids affected soil functions and also to investigate the decomposition of pulp mill effluent solids and of resin extractives in these solids. 

Three hypotheses tested were:
 I. Pulp mill effluent solids are toxic to soil organisms.
II. Resin extractives in pulp mill effluent solids are recalcitrant in the terrestrial environment.
III. Pulp mill effluent solids will cause significant measurable negative impacts on soil functional capacity.

A wide range of resin extractives compounds were identified in pulp mill effluent solids, and concentrations of individual compounds varied widely between the different pulp mill effluent solids tested. During the two years after field application of the pulp mill effluent solids, resin extractives declined, however, decay rates of individual compounds were variable. The decay rate of compounds was influenced by the type of pulp mill effluent solids containing these compounds and not by the initial concentration of compounds. All compounds, including resin acids, degraded rapidly in the applied primary solid and in one of the applied biosolids, with average half-lives calculated ranging from three to twelve months. In the other biosolids, resin acids were recalcitrant with average half-lives calculated to be nearly ten years. 

Laboratory bioassays conducted on oats, earthworms and enchytraeid worms indicated that pulp mill effluent solids had low toxicity to these organisms. An aquatic bioassay organism, however, was acutely affected by aqueous extracts from pulp mill effluent solids. Earthworms were shown to bioaccumulate some resin extractive compounds to a limited extent, indicating that resin extractives were bioavailable in pulp mill effluent solids. Enchytraeid reproduction was reduced by exposure to some pulp mill effluent solids but this was not correlated to resin extractives concentration of the solids tested. 

Field applied pulp mill effluent solids significantly enhanced the fluxes of CO2 from the soil surface. When mass losses of pulp mill effluent solids carbon were taken into account, it was shown that these solids had little effect on soil respiration. Needle litterbags were placed above and below pulp mill effluent solids and in the litter horizon of a control treatment for 12 months. Needle litter decomposition was not significantly different between treatments, however, changes in enzyme activities were detected in litter beneath pulp mill effluent solids compared to control needle litter that had not been exposed to pulp mill effluent solids. The decomposition rate of field applied pulp mill effluent solids was slow, with half-lives extrapolated to be between five and twenty five years. The decomposition rate appeared to be influenced by the pools of carbon available for decomposition, with primary solids decaying significantly faster than biosolids due to a higher cellulose component.

The conclusions of the PhD thesis research are, therefore, that generally, pulp mill effluent solids used in the study were demonstrated to be relatively benign and appear to pose a low risk to the terrestrial ecosystem when applied to soil. However, a cautious approach is still recommended to land application, based on the extensive evidence of disruption to aquatic ecosystems, and because pulp mill effluent solids will take many years to decompose and resin acids are recalcitrant in some pulp mill effluent solids. Further research is recommended to elucidate mechanisms of action by resin extractives in soil organisms and the ultimate fate of these compounds in the soil compartment.

year: 2007

title: E hoki mai nei ki te ūkaipō | Return to your place of nourishment [Te Kōputu a te Whanga a Toi | Whakatāne Art Gallery]

authors: Apiata, Hāwea

subjects: toi Māori

abstract: E Hoki Mai Nei ki te Ūkaipō | Return to Your Place of Nourishment brings together works by four wāhine Māori artists, Aimee Ratana, Aisha Roberts, Hollie Tawhiao and Maraea Timutimu, which explore narratives of pakanga
(conflict) through toi (art). In this show, the four artists weave together their unique practices and stories to present a cohesive yet diverse examination of conflicts, with a particular focus on the artists’ own whānau, hapū, and iwi narratives.
Curated by Hāwea Apiata.

text: E hoki mai nei ki te ūkaipō | Return to your place of nourishment [Te Kōputu a te Whanga a Toi | Whakatāne Art Gallery] E Hoki Mai Nei ki te Ūkaipō | Return to Your Place of Nourishment brings together works by four wāhine Māori artists, Aimee Ratana, Aisha Roberts, Hollie Tawhiao and Maraea Timutimu, which explore narratives of pakanga
(conflict) through toi (art). In this show, the four artists weave together their unique practices and stories to present a cohesive yet diverse examination of conflicts, with a particular focus on the artists’ own whānau, hapū, and iwi narratives.
Curated by Hāwea Apiata.

year: 2025-04-17