title: Accompanied by suspicion: An ethnographic account of negotiating gender tensions and positioning in counselling practice and researching child sexuality

authors: Flanagan, Paul G.

abstract: This chapter presents my experience of journeying into research on the contentious area of sexuality in childhood.  Reflecting on experiences from professional, personal and academic contexts, I expose occasions of discomfort, unease and public questioning of my integrity – because I am male, and because of the sensitive subject area of this research: children and sexuality. Revealing a number of discursive contexts (not only am I male, but my counselling practice has largely been with children and in the area of child sexual abuse and child sexual activity) the question is boldly presented – how do I balance gender tensions and positionings?  I recognise that gender tensions are an appropriate challenge within a research and public media gaze that calls for accountability for the extent and dominance of child and sexual abuse perpetrated by males. Responding to and within constraints of others’ perceptions and maligning remarks, I acknowledge that questions of gender and safety are appropriate and hold value for me, about how I step into researcher positioning taken up in this study. A sense of advocacy and social justice underpins my commitment to this research making suspicion an uncomfortable but valuable participant to negotiate in this process.

text: Accompanied by suspicion: An ethnographic account of negotiating gender tensions and positioning in counselling practice and researching child sexuality This chapter presents my experience of journeying into research on the contentious area of sexuality in childhood.  Reflecting on experiences from professional, personal and academic contexts, I expose occasions of discomfort, unease and public questioning of my integrity – because I am male, and because of the sensitive subject area of this research: children and sexuality. Revealing a number of discursive contexts (not only am I male, but my counselling practice has largely been with children and in the area of child sexual abuse and child sexual activity) the question is boldly presented – how do I balance gender tensions and positionings?  I recognise that gender tensions are an appropriate challenge within a research and public media gaze that calls for accountability for the extent and dominance of child and sexual abuse perpetrated by males. Responding to and within constraints of others’ perceptions and maligning remarks, I acknowledge that questions of gender and safety are appropriate and hold value for me, about how I step into researcher positioning taken up in this study. A sense of advocacy and social justice underpins my commitment to this research making suspicion an uncomfortable but valuable participant to negotiate in this process.

year: 2015

title: Dimeric rhodium(III), iridium(III) and ruthenium(II) thiosalicylate complexes

authors: Henderson, William

subjects: Rhodium

abstract: Reactions of the chloride-bridged dimers [LMCl(μ-Cl)]₂ (M=Rh, Ir; L=Cp*=η⁵-C₅Me₅; M=Ru, L=η⁶-p-cymene) with two mole equivalents of thiosalicylic acid (HSC₆H₄CO₂H, H₂tsal) and excess base gives the dimeric rhodium(III), iridium(III) and ruthenium(II) thiosalicylate complexes [LM(tsal)]₂. Reaction of the complex [Cp*RhCl₂(PPh₂)] with one equivalent of H₂tsal and triethylamine in dichloromethane gives a mixture of the dimer [Cp*Rh(tsal)]₂ and the phosphine complex [Cp*Rh(tsal)(PPh₃)]; upon recrystallisation, pure dimer is obtained. A single-crystal X-ray diffraction study on the rhodium and ruthenium dimers reveals the expected thiolate-bridged M₂(μ-S)₂ unit. Electrospray mass spectrometry (ESMS) is a useful technique in studying the chemistry of the thiosalicylate complexes, all complexes giving strong [M+H]⁺ ions. With added thiosalicylic acid, cations of the type [(LM)₂(Htsal)₃]⁺ were detected in the mass spectra.

text: Dimeric rhodium(III), iridium(III) and ruthenium(II) thiosalicylate complexes Reactions of the chloride-bridged dimers [LMCl(μ-Cl)]₂ (M=Rh, Ir; L=Cp*=η⁵-C₅Me₅; M=Ru, L=η⁶-p-cymene) with two mole equivalents of thiosalicylic acid (HSC₆H₄CO₂H, H₂tsal) and excess base gives the dimeric rhodium(III), iridium(III) and ruthenium(II) thiosalicylate complexes [LM(tsal)]₂. Reaction of the complex [Cp*RhCl₂(PPh₂)] with one equivalent of H₂tsal and triethylamine in dichloromethane gives a mixture of the dimer [Cp*Rh(tsal)]₂ and the phosphine complex [Cp*Rh(tsal)(PPh₃)]; upon recrystallisation, pure dimer is obtained. A single-crystal X-ray diffraction study on the rhodium and ruthenium dimers reveals the expected thiolate-bridged M₂(μ-S)₂ unit. Electrospray mass spectrometry (ESMS) is a useful technique in studying the chemistry of the thiosalicylate complexes, all complexes giving strong [M+H]⁺ ions. With added thiosalicylic acid, cations of the type [(LM)₂(Htsal)₃]⁺ were detected in the mass spectra.

year: 2001-04-01

title: Research reflections on making visible the experiences of Kāpō Māori during and after COVID-19

authors: Masters-Awatere, Bridgette

abstract: Introduction: 
This piece reflects on our research process when undertaking face-to-face interviews with tāngata kāpō (Māori people who are blind, deafblind, low vision or vision impaired). Particular attention is given to the access requirements of tāngata kāpō and the intersections of Māori and disability. These experiences are shared as learning opportunities for others who are undertaking research in ways that are mindful of Tiriti and disability obligations, and in the current COVID-19 environment.

text: Research reflections on making visible the experiences of Kāpō Māori during and after COVID-19 Introduction: 
This piece reflects on our research process when undertaking face-to-face interviews with tāngata kāpō (Māori people who are blind, deafblind, low vision or vision impaired). Particular attention is given to the access requirements of tāngata kāpō and the intersections of Māori and disability. These experiences are shared as learning opportunities for others who are undertaking research in ways that are mindful of Tiriti and disability obligations, and in the current COVID-19 environment.

year: 2021