title: Book review: Bring on the books for everybody: How literary culture became popular culture

authors: Hight, Craig

subjects: United States

abstract: Abstract:
Review(s) of: Bring on the Books for Everybody: How Literary Culture Became Popular Culture, by Collins, Jim, Duke University Press, Durham, NC, 2010, ISBN 9 7808 2234 6067, 288 pp.

text: Book review: Bring on the books for everybody: How literary culture became popular culture Abstract:
Review(s) of: Bring on the Books for Everybody: How Literary Culture Became Popular Culture, by Collins, Jim, Duke University Press, Durham, NC, 2010, ISBN 9 7808 2234 6067, 288 pp.

year: 2011

title: Sulphate partitioning into calcite: Experimental verification of pH control and application to seasonality in speleothems

authors: Wynn, Peter M.

subjects: Science & Technology

abstract: Carbonate-associated sulphate (CAS) is a useful carrier of palaeoenvironmental information throughout the geologic record, particularly through its stable isotope composition. However, a paucity of experimental data restricts quantitative understanding of sulphate incorporation into carbonates, and consequently CAS concentrations and their diagenetic modifications are rarely interpreted. However, in the case of calcite speleothems, the remarkably high-resolution CAS records which are obtainable via modern microanalytical techniques represent a potentially invaluable source of palaeoenvironmental information. Here, we describe the results of controlled experiments of sulphate co-precipitation with calcite in freshwater solutions where pH, saturation state, and sulphate concentration were varied independently of each other. Solution pH is confirmed as the principal control on sulphate incorporation into calcite. The relative efficiency of incorporation was calculated as a partition coefficient Dₛₒ₄=(mSO₄/mCO₃)solid/(mSO₄/mCO₃)solution. High crystal growth rates (driven by either pH or saturation state) encouraged higher values of Dₛₒ₄ because of an increasing concentration of defect sites on crystal surfaces. At low growth rates, Dₛₒ₄ was reduced due to an inferred competition between sulphate and bicarbonate at the calcite surface. These experimental results are applied to understand the incorporation of sulphate into speleothem calcite. The experimentally determined pH-dependence suggests that strong seasonal variations in cave air PCO₂ could account for annual cycles in sulphate concentration observed in stalagmites. Our new experimentally determined values of Dₛₒ₄ were compared with Dₛₒ₄ values calculated from speleothem-drip water monitoring from two caves within the Austrian and Italian Alps. At Obir cave, Austria, Dₛₒ₄ (×10⁵) varies between 11.1 (winter) and 9.0 (summer) and the corresponding figures for Ernesto cave, Italy, are 15.4 (winter) and 14.9 (summer). These values approximate predicted Dₛₒ₄ values based on our chamber experiments containing both low (2 ppm) and high (20 ppm) sulphate concentrations. Our experimental values of Dₛₒ₄ obtained at crystal growth rates typical of stalagmites, closely match those observed in other cave sites from around the world. This validates the universality of the controls behind Dₛₒ₄ and will enhance the use of speleothem CAS as a palaeoenvironmental proxy.

text: Sulphate partitioning into calcite: Experimental verification of pH control and application to seasonality in speleothems Carbonate-associated sulphate (CAS) is a useful carrier of palaeoenvironmental information throughout the geologic record, particularly through its stable isotope composition. However, a paucity of experimental data restricts quantitative understanding of sulphate incorporation into carbonates, and consequently CAS concentrations and their diagenetic modifications are rarely interpreted. However, in the case of calcite speleothems, the remarkably high-resolution CAS records which are obtainable via modern microanalytical techniques represent a potentially invaluable source of palaeoenvironmental information. Here, we describe the results of controlled experiments of sulphate co-precipitation with calcite in freshwater solutions where pH, saturation state, and sulphate concentration were varied independently of each other. Solution pH is confirmed as the principal control on sulphate incorporation into calcite. The relative efficiency of incorporation was calculated as a partition coefficient Dₛₒ₄=(mSO₄/mCO₃)solid/(mSO₄/mCO₃)solution. High crystal growth rates (driven by either pH or saturation state) encouraged higher values of Dₛₒ₄ because of an increasing concentration of defect sites on crystal surfaces. At low growth rates, Dₛₒ₄ was reduced due to an inferred competition between sulphate and bicarbonate at the calcite surface. These experimental results are applied to understand the incorporation of sulphate into speleothem calcite. The experimentally determined pH-dependence suggests that strong seasonal variations in cave air PCO₂ could account for annual cycles in sulphate concentration observed in stalagmites. Our new experimentally determined values of Dₛₒ₄ were compared with Dₛₒ₄ values calculated from speleothem-drip water monitoring from two caves within the Austrian and Italian Alps. At Obir cave, Austria, Dₛₒ₄ (×10⁵) varies between 11.1 (winter) and 9.0 (summer) and the corresponding figures for Ernesto cave, Italy, are 15.4 (winter) and 14.9 (summer). These values approximate predicted Dₛₒ₄ values based on our chamber experiments containing both low (2 ppm) and high (20 ppm) sulphate concentrations. Our experimental values of Dₛₒ₄ obtained at crystal growth rates typical of stalagmites, closely match those observed in other cave sites from around the world. This validates the universality of the controls behind Dₛₒ₄ and will enhance the use of speleothem CAS as a palaeoenvironmental proxy.

year: 2018

title: Factors of desistance in violent offenders: Interpretative phenomenological analysis of the Tai Aroha programme

authors: Beattie, Christopher James

subjects: Desistance

abstract: The phenomenon of desistance from crime is central to the process of rehabilitation. This study examines desistance narratives from the Tai Aroha programme to identify the aspects of participation in a community-based special treatment unit that are effective from the perspective of participants. A review of desistance literature is presented in a New Zealand context. Interpretative phenomenological analysis was used to present common themes in 64 exit interviews of individuals who completed this programme over a period of 6 years. These themes were compared to the factors of desistance identified in the literature review. The three key concepts that emerged from this study as factors of desistance evident in the Tai Aroha programme were the Morphic Self, Family and Whanau, and Mindfulness. The concept of the Morphic Self is a perspective on the process of identity change as experienced by participants, and is a key product of this research. Three other factors were identified as prerequisites for successful completion of the programme that also therefore contribute to desistance: Motivation, Sobriety, and Peers and Support. Also identified from this research were aspects of the experience termed Elements of Influence, which are the facets of the participants, the programme and the interactions between the two that can be considered in order to improve the delivery of the programme and therefore promote desistance. A distinctive quality of the Tai Aroha programme that was influential in the successful promotion of desistance was its strong commitment to tikanga Māori and the incorporation of these cultural values into the lifestyle and therapeutic approaches adopted by the facilitators.

text: Factors of desistance in violent offenders: Interpretative phenomenological analysis of the Tai Aroha programme The phenomenon of desistance from crime is central to the process of rehabilitation. This study examines desistance narratives from the Tai Aroha programme to identify the aspects of participation in a community-based special treatment unit that are effective from the perspective of participants. A review of desistance literature is presented in a New Zealand context. Interpretative phenomenological analysis was used to present common themes in 64 exit interviews of individuals who completed this programme over a period of 6 years. These themes were compared to the factors of desistance identified in the literature review. The three key concepts that emerged from this study as factors of desistance evident in the Tai Aroha programme were the Morphic Self, Family and Whanau, and Mindfulness. The concept of the Morphic Self is a perspective on the process of identity change as experienced by participants, and is a key product of this research. Three other factors were identified as prerequisites for successful completion of the programme that also therefore contribute to desistance: Motivation, Sobriety, and Peers and Support. Also identified from this research were aspects of the experience termed Elements of Influence, which are the facets of the participants, the programme and the interactions between the two that can be considered in order to improve the delivery of the programme and therefore promote desistance. A distinctive quality of the Tai Aroha programme that was influential in the successful promotion of desistance was its strong commitment to tikanga Māori and the incorporation of these cultural values into the lifestyle and therapeutic approaches adopted by the facilitators.

year: 2018