title: An X-ray absorption spectroscopic study at the mercury LIII edge on phenylmercury(II) oxygen species

authors: Jackson, Wendy J.

abstract: The X-ray absorption spectra of the reference and model compounds HgCl2, PhHgCl, PhHgOAc and [(PhHg)2OH][BF4].H2O have been analysed in both the XANES and EXAFS regions, and the technique was extended to determine the structures of (PhHg)2O, PhHgOH, and the basic salts PhHgOH.PhHgNO3 and PhHgOH.(PhHg)2SO4, which were previously structurally uncharacterised. Results indicate that (PhHg)2O is a molecular species with Hg-O-Hg 135°, while PhHgOH contains the [(PhHg)2OH]+ cation and is better formulated as [(PhHg)2OH]OH. The same cation is also featured in the two basic salts.  Electrospray mass spectral studies of PhHgOH in aqueous solutions show that [PhHgOH2]+, [(PhHg)2OH]+ and [(PhHg)3O]+ co-exist in solution in a pH-dependent equilibrium.

text: An X-ray absorption spectroscopic study at the mercury LIII edge on phenylmercury(II) oxygen species The X-ray absorption spectra of the reference and model compounds HgCl2, PhHgCl, PhHgOAc and [(PhHg)2OH][BF4].H2O have been analysed in both the XANES and EXAFS regions, and the technique was extended to determine the structures of (PhHg)2O, PhHgOH, and the basic salts PhHgOH.PhHgNO3 and PhHgOH.(PhHg)2SO4, which were previously structurally uncharacterised. Results indicate that (PhHg)2O is a molecular species with Hg-O-Hg 135°, while PhHgOH contains the [(PhHg)2OH]+ cation and is better formulated as [(PhHg)2OH]OH. The same cation is also featured in the two basic salts.  Electrospray mass spectral studies of PhHgOH in aqueous solutions show that [PhHgOH2]+, [(PhHg)2OH]+ and [(PhHg)3O]+ co-exist in solution in a pH-dependent equilibrium.

year: 2000-01-01

title: Experimental and Numerical Investigations of Skim Milk Powder Stickiness and Deposition Mechanisms

authors: Zhao, SongXin

subjects: Deposition

abstract: The particle gun method and Computational Fluid Dynamics (CFD) modelling was used to study stickiness and deposition mechanisms of skim milk powder in an impingement jet hitting a stainless steel plate. The particular focus was on the effect of jet velocity and particle size distribution on deposition. Low jet velocities of 10.3, 14.8 and 19.4 m/s were studied at fine particle size levels of 30, 51, and 61 mm, using a jet-plate height to jet diameter ratio of 4. For skim milk powder with a bulk particle size (d(0.5) = 61 μm), lowering the air velocity from 19.4 m/s to 10.3 m/s increased the level of deposition and decreased the point at which deposition first occur as measured by the temperature difference between the glass transition temperature (Tg) of amorphous lactose and the air jet temperature of the particle gun. This point is called (T-Tg)critical. The critical point decreased from 39.0 °C to 18.6 °C as the velocity decreased from 19.4 to 10.3 m/s and the (T-Tg)critical obtained at the lower velocity is in closer agreement with previously reported fluid bed rig results. The (T-Tg)critical point and level of deposition was also found to be highly dependent on particle size. Increasing the average particle size from 30 μm to 61μm increased the (T-Tg)critical from 8.2 °C to 18.6 °C and 14.8 °C to 39.0 °C for jet velocities of 10.3 m/s and 19.4 m/s respectively. Levels of particle deposition also dramatically decreased for both velocity ranges. Ring shaped deposit morphologies were observed with increasing particle stickiness. Beyond (T-Tg)critical powder deposits formed at the periphery of the plate creating a large round clear zone which decreased until a striped deposit ring formed and finally deposits formed only at the centre. Particles were observed to bounce radially from the centre of the plate before sticking. Milk powder deposits are therefore governed by the kinetic energy of the impinging particle in addition to particle surface stickiness. The particle gun method was modelled using Fluent CFD software as an adhesion phenomenon arising from the particle-surface contact dynamics of a particle laden impingement jet contacting a vertical collection plate. The development of a wall boundary condition for specifying the particle-surface interaction has been the focus. A particle is captured by the wall if the impinging kinetic energy is below the prescribed critical normal kinetic energy; otherwise the particle rebounds with reduced kinetic energy. The model was developed through the User Define Function option of Fluent. The CFD model confirmed that particles rebound radially from the collection plate several times before sticking. Circular deposit morphology results from such modelled contact dynamics which are similar to the observed experimental deposits. The level of deposition predicted by CFD increased with increasing levels of critical normal kinetic energy, in the same way experimental deposits increased with increasing particle stickiness. The current model did not considered the contribution from the tangential velocity component to particle stick/rebound behaviour, but it is expected the tangential velocity may also play a significant role and should be included in future CFD models. It is recommended that the particle-surface interaction needs to be studied in more detail, preferably with imaging systems such as Particle Image Velocimetry (PIV), so that individual particle trajectory and deposition behaviour can be followed and analysed.

text: Experimental and Numerical Investigations of Skim Milk Powder Stickiness and Deposition Mechanisms The particle gun method and Computational Fluid Dynamics (CFD) modelling was used to study stickiness and deposition mechanisms of skim milk powder in an impingement jet hitting a stainless steel plate. The particular focus was on the effect of jet velocity and particle size distribution on deposition. Low jet velocities of 10.3, 14.8 and 19.4 m/s were studied at fine particle size levels of 30, 51, and 61 mm, using a jet-plate height to jet diameter ratio of 4. For skim milk powder with a bulk particle size (d(0.5) = 61 μm), lowering the air velocity from 19.4 m/s to 10.3 m/s increased the level of deposition and decreased the point at which deposition first occur as measured by the temperature difference between the glass transition temperature (Tg) of amorphous lactose and the air jet temperature of the particle gun. This point is called (T-Tg)critical. The critical point decreased from 39.0 °C to 18.6 °C as the velocity decreased from 19.4 to 10.3 m/s and the (T-Tg)critical obtained at the lower velocity is in closer agreement with previously reported fluid bed rig results. The (T-Tg)critical point and level of deposition was also found to be highly dependent on particle size. Increasing the average particle size from 30 μm to 61μm increased the (T-Tg)critical from 8.2 °C to 18.6 °C and 14.8 °C to 39.0 °C for jet velocities of 10.3 m/s and 19.4 m/s respectively. Levels of particle deposition also dramatically decreased for both velocity ranges. Ring shaped deposit morphologies were observed with increasing particle stickiness. Beyond (T-Tg)critical powder deposits formed at the periphery of the plate creating a large round clear zone which decreased until a striped deposit ring formed and finally deposits formed only at the centre. Particles were observed to bounce radially from the centre of the plate before sticking. Milk powder deposits are therefore governed by the kinetic energy of the impinging particle in addition to particle surface stickiness. The particle gun method was modelled using Fluent CFD software as an adhesion phenomenon arising from the particle-surface contact dynamics of a particle laden impingement jet contacting a vertical collection plate. The development of a wall boundary condition for specifying the particle-surface interaction has been the focus. A particle is captured by the wall if the impinging kinetic energy is below the prescribed critical normal kinetic energy; otherwise the particle rebounds with reduced kinetic energy. The model was developed through the User Define Function option of Fluent. The CFD model confirmed that particles rebound radially from the collection plate several times before sticking. Circular deposit morphology results from such modelled contact dynamics which are similar to the observed experimental deposits. The level of deposition predicted by CFD increased with increasing levels of critical normal kinetic energy, in the same way experimental deposits increased with increasing particle stickiness. The current model did not considered the contribution from the tangential velocity component to particle stick/rebound behaviour, but it is expected the tangential velocity may also play a significant role and should be included in future CFD models. It is recommended that the particle-surface interaction needs to be studied in more detail, preferably with imaging systems such as Particle Image Velocimetry (PIV), so that individual particle trajectory and deposition behaviour can be followed and analysed.

year: 2009

title: An evaluation of Te Rau Puawai workforce 100: Academic mentor's perspectives

authors: Nikora, Linda Waimarie

subjects: Maori students

abstract: To evaluate the Te Rau Puawai programme, the Ministry of Health commissioned the
Maori and Psychology Research Unit of the University of Waikato in July 2001. The
overall aim of the evaluation was to provide the Ministry with a clearer understanding
of the programme including: the perceived critical success factors, the barriers if any
regarding Te Rau Puawai, the impact of the programme, the extent to which the
programme may be transferable, gaps in the programme, and suggested
improvements.
As an integral component of the Te Rau Puawai programme and as a specialised
source of support, academic mentors were identified as an important group to receive
comment from. This report documents the evaluative exchange that occurred by way
of email questionnaire, that we had with 18 out of 46 academic mentors of Te Rau
Puawai bursars in the College of Humanities and Social Sciences responded to our
questionnaire.

text: An evaluation of Te Rau Puawai workforce 100: Academic mentor's perspectives To evaluate the Te Rau Puawai programme, the Ministry of Health commissioned the
Maori and Psychology Research Unit of the University of Waikato in July 2001. The
overall aim of the evaluation was to provide the Ministry with a clearer understanding
of the programme including: the perceived critical success factors, the barriers if any
regarding Te Rau Puawai, the impact of the programme, the extent to which the
programme may be transferable, gaps in the programme, and suggested
improvements.
As an integral component of the Te Rau Puawai programme and as a specialised
source of support, academic mentors were identified as an important group to receive
comment from. This report documents the evaluative exchange that occurred by way
of email questionnaire, that we had with 18 out of 46 academic mentors of Te Rau
Puawai bursars in the College of Humanities and Social Sciences responded to our
questionnaire.

year: 2002-05-01