title: Cycloaurated triphenylphosphine-sulfide and –selenide

authors: Kilpin, Kelly Joan

subjects: gold complexes

abstract: The first examples of cycloaurated phosphine sulfides and triphenylphosphine selenide have been synthesised; these complexes are fairly rare examples of gold(III) complexes with potentially reducing sulfur- and selenium-donor ligands. The cycloaurated complex (AuCl₂ (2-C₆H₄P(S)Ph₂) was synthesised in good yield by transmetallation of the organomercury precursor Hg(2-C₆H₄P(S)Ph₂)₂ with Me₄N[AuCl₄]. A route to the chloro-mercury analogue ClHg(2-C₆H₄P(S)Ph₂) was developed by reaction of the cyclomanganated triphenylphosphine sulfide (CO)₄Mn(2-C₆H₄P(S)Ph₂) with HgCl₂; this mercury substrate was also used in the synthesis of AuCl₂(2-C₆H₄P(S)Ph₂). The cycloaurated triphenylphosphine selenide complex AuCl₂(2-C₆H₄P(Se)Ph₂) was synthesised by an analogous methodology using the new phosphine selenide Hg(2-C₆H₄P(Se)Ph₂)₂ [prepared from Hg(2-C₆H₄PPh₂)₂ and elemental Se under sonication]. The phosphonamidic analogue AuCl₂(2-C₆H₄P(S)(Net₂)₂) has also been synthesised from PhP(S)(Net₂)₂via lithiation and mercuration. X-Ray crystal structures of several compounds are reported, and show the presence of puckered ring systems.

text: Cycloaurated triphenylphosphine-sulfide and –selenide The first examples of cycloaurated phosphine sulfides and triphenylphosphine selenide have been synthesised; these complexes are fairly rare examples of gold(III) complexes with potentially reducing sulfur- and selenium-donor ligands. The cycloaurated complex (AuCl₂ (2-C₆H₄P(S)Ph₂) was synthesised in good yield by transmetallation of the organomercury precursor Hg(2-C₆H₄P(S)Ph₂)₂ with Me₄N[AuCl₄]. A route to the chloro-mercury analogue ClHg(2-C₆H₄P(S)Ph₂) was developed by reaction of the cyclomanganated triphenylphosphine sulfide (CO)₄Mn(2-C₆H₄P(S)Ph₂) with HgCl₂; this mercury substrate was also used in the synthesis of AuCl₂(2-C₆H₄P(S)Ph₂). The cycloaurated triphenylphosphine selenide complex AuCl₂(2-C₆H₄P(Se)Ph₂) was synthesised by an analogous methodology using the new phosphine selenide Hg(2-C₆H₄P(Se)Ph₂)₂ [prepared from Hg(2-C₆H₄PPh₂)₂ and elemental Se under sonication]. The phosphonamidic analogue AuCl₂(2-C₆H₄P(S)(Net₂)₂) has also been synthesised from PhP(S)(Net₂)₂via lithiation and mercuration. X-Ray crystal structures of several compounds are reported, and show the presence of puckered ring systems.

year: 2010

title: Policy solutions to social housing stigmatisation in Aotearoa

authors: Southey, Kim

abstract: This policy brief discusses social housing stigmatisation as a process and experience that has detrimental effects on social housing tenants. The brief also highlights the role social housing policy must play in addressing stigmatisation, thereby, ensuring the wellbeing and community inclusion of social housing residents. The discussion and recommendations in this brief are based on a review of evidence for the WERO (Working to End Racial Oppression) research project, examining how neighbours’ perceptions as well as policies and practices of social housing provision impact social housing tenants’ experiences of wellbeing and neighbourhood inclusion.

text: Policy solutions to social housing stigmatisation in Aotearoa This policy brief discusses social housing stigmatisation as a process and experience that has detrimental effects on social housing tenants. The brief also highlights the role social housing policy must play in addressing stigmatisation, thereby, ensuring the wellbeing and community inclusion of social housing residents. The discussion and recommendations in this brief are based on a review of evidence for the WERO (Working to End Racial Oppression) research project, examining how neighbours’ perceptions as well as policies and practices of social housing provision impact social housing tenants’ experiences of wellbeing and neighbourhood inclusion.

year: 2025-02

title: Kaitiakitanga: protecting New Zealand's native biodiversity

authors: Morad, Munir

subjects: geography

abstract: Species diversity is a very important component of a healthy ecosystem, and a necessary condition for long-term sustainable development. However, it is widely recognised that species extinction is on the increase in New Zealand, as biological diversity comes under pressure from landuse activity and environmental change.

text: Kaitiakitanga: protecting New Zealand's native biodiversity Species diversity is a very important component of a healthy ecosystem, and a necessary condition for long-term sustainable development. However, it is widely recognised that species extinction is on the increase in New Zealand, as biological diversity comes under pressure from landuse activity and environmental change.

year: 2000