title: Anodically polarized nickel electrodes in DMSO or DMF solutions of pseudohalide ions: IR spectroelectrochemical studies

authors: Alwis, L. K. H. K.

subjects: chemistry

abstract: A novel subtractively normalized interfacial Fourier transform infrared spectroscopic (SNIFTIRS) investigation of anodically polarized nickel electrodes in pseudohalide-containing DMF or DMSO solutions (i.e. OCN⁻, SCN⁻, SeCN⁻), in supporting electrolyte, tetrabutylammonium perchlorate (TBAP), is presented. In general, the data showed that nickel demonstrated irreversible anodic dissolution in all solutions studied at very high values of the applied potential, > +500 mV (AgCl/Ag). The predominant speciation of nickel in these systems was as complex ions consisting of Ni²⁺ ion complexed to pseudohalide ions and solvent molecules. Insoluble films and dissolved CO₂ were also detected, though mostly in the Ni/OCN⁻ systems studied. Ni(II)/pseudohalide complex ion species detected were modeled using solutions containing Ni²⁺ ion mixed with pseudohalide ion in different mole ratios. In general, the Ni/OCN⁻ electrochemical system behaved differently relative to those of Ni/SCN⁻ and Ni/SeCN⁻ due to the difference in colors observed in cell solutions after SNIFTIRS experiments which was mirrored in the model solutions. Ni(II)-cyanate species had a different, coordination geometry and gave a characteristic bright blue color due possibly to Ni(NCO)₄²⁻ ion while Ni(II) thiocyanate and selenocyanate complex ion species had octahedral coordination geometries containing solvent and one coordinated pseudohalide ion and formed greeny yellow solutions.

text: Anodically polarized nickel electrodes in DMSO or DMF solutions of pseudohalide ions: IR spectroelectrochemical studies A novel subtractively normalized interfacial Fourier transform infrared spectroscopic (SNIFTIRS) investigation of anodically polarized nickel electrodes in pseudohalide-containing DMF or DMSO solutions (i.e. OCN⁻, SCN⁻, SeCN⁻), in supporting electrolyte, tetrabutylammonium perchlorate (TBAP), is presented. In general, the data showed that nickel demonstrated irreversible anodic dissolution in all solutions studied at very high values of the applied potential, > +500 mV (AgCl/Ag). The predominant speciation of nickel in these systems was as complex ions consisting of Ni²⁺ ion complexed to pseudohalide ions and solvent molecules. Insoluble films and dissolved CO₂ were also detected, though mostly in the Ni/OCN⁻ systems studied. Ni(II)/pseudohalide complex ion species detected were modeled using solutions containing Ni²⁺ ion mixed with pseudohalide ion in different mole ratios. In general, the Ni/OCN⁻ electrochemical system behaved differently relative to those of Ni/SCN⁻ and Ni/SeCN⁻ due to the difference in colors observed in cell solutions after SNIFTIRS experiments which was mirrored in the model solutions. Ni(II)-cyanate species had a different, coordination geometry and gave a characteristic bright blue color due possibly to Ni(NCO)₄²⁻ ion while Ni(II) thiocyanate and selenocyanate complex ion species had octahedral coordination geometries containing solvent and one coordinated pseudohalide ion and formed greeny yellow solutions.

year: 2013

title: Low-cost semantic enhancement to digital library metadata and indexing: simple yet effective strategies

authors: Hinze, Annika

subjects: computer science

abstract: Most existing digital libraries use traditional lexically-based retrieval techniques. For established systems, completely replacing, or even making significant changes to the document retrieval mechanism (document analysis, indexing strategy, query processing and query interface) would require major technological effort, and would most likely be disruptive. In this paper, we describe ways to use the results of semantic analysis and disambiguation, while retaining an existing keyword-based search and lexicographic index. We engineer this so the output of semantic analysis (performed off-line) is suitable for import directly into existing digital library metadata and index structures, and thus incorporated without the need for architecture modifications.

text: Low-cost semantic enhancement to digital library metadata and indexing: simple yet effective strategies Most existing digital libraries use traditional lexically-based retrieval techniques. For established systems, completely replacing, or even making significant changes to the document retrieval mechanism (document analysis, indexing strategy, query processing and query interface) would require major technological effort, and would most likely be disruptive. In this paper, we describe ways to use the results of semantic analysis and disambiguation, while retaining an existing keyword-based search and lexicographic index. We engineer this so the output of semantic analysis (performed off-line) is suitable for import directly into existing digital library metadata and index structures, and thus incorporated without the need for architecture modifications.

year: 2016

title: Māori data sovereignty and privacy

authors: Kukutai, Tahu

abstract: Privacy is a fundamental human right. One of its most important aspects is information privacy – providing individuals with control over the way in which their personal data is collected, used, disclosed and otherwise handled. Existing information privacy regulation neither recognises nor protects the collective privacy rights of Indigenous peoples. This paper explores Indigenous data
privacy, and the challenges and opportunities, in the context of Aotearoa. It has two aims: to identify gaps in existing data privacy approaches with regards to Indigenous data, and to provide a foundation for progressing alternative privacy paradigms. We argue that while personal data protection is necessary, it is insufficient to meet the needs of Māori and Aotearoa more broadly. In so doing, we draw on three areas of research: Indigenous and Māori data sovereignty; data and information privacy,
including collective privacy; and Māori and Indigenous privacy perspectives. We examine key features of the Aotearoa privacy context – including the Privacy Act 2020 (NZ) – and consider the implications of te Tiriti o Waitangi and tikanga Māori for alternative privacy approaches. Future options, including legal and extra-legal measures, are proposed.

text: Māori data sovereignty and privacy Privacy is a fundamental human right. One of its most important aspects is information privacy – providing individuals with control over the way in which their personal data is collected, used, disclosed and otherwise handled. Existing information privacy regulation neither recognises nor protects the collective privacy rights of Indigenous peoples. This paper explores Indigenous data
privacy, and the challenges and opportunities, in the context of Aotearoa. It has two aims: to identify gaps in existing data privacy approaches with regards to Indigenous data, and to provide a foundation for progressing alternative privacy paradigms. We argue that while personal data protection is necessary, it is insufficient to meet the needs of Māori and Aotearoa more broadly. In so doing, we draw on three areas of research: Indigenous and Māori data sovereignty; data and information privacy,
including collective privacy; and Māori and Indigenous privacy perspectives. We examine key features of the Aotearoa privacy context – including the Privacy Act 2020 (NZ) – and consider the implications of te Tiriti o Waitangi and tikanga Māori for alternative privacy approaches. Future options, including legal and extra-legal measures, are proposed.

year: 2023