title: Reactions of cyclomanganated complexes with carbon disulfide: routes to η²-aryldithiocarboxylate-Mn(CO)₄ complexes and to the trithiocarbonate complex (μ₃-CS₃)₂Mn₄(CO)₁₆

authors: Mace, Wade

abstract: Reaction of cyclomanganated aryl ketones with CS₂ proceeds with insertion into the Mn–C bond to give η²-dithiocarboxylato–Mn(CO)₄ compounds. With other cyclomanganated substrates such as that from Ph₃P=S and also with Mn₂(CO)₁₀, CS₂ gives (μ₃-CS₃)₂Mn₄(CO)₁₆ with bridging trithiocarbonate ligands.

text: Reactions of cyclomanganated complexes with carbon disulfide: routes to η²-aryldithiocarboxylate-Mn(CO)₄ complexes and to the trithiocarbonate complex (μ₃-CS₃)₂Mn₄(CO)₁₆ Reaction of cyclomanganated aryl ketones with CS₂ proceeds with insertion into the Mn–C bond to give η²-dithiocarboxylato–Mn(CO)₄ compounds. With other cyclomanganated substrates such as that from Ph₃P=S and also with Mn₂(CO)₁₀, CS₂ gives (μ₃-CS₃)₂Mn₄(CO)₁₆ with bridging trithiocarbonate ligands.

year: 2002-01-01

title: Editorial

authors: Shieff, Sarah

abstract: This issue also presents new work from an unusual quarter, and in an unusual genre for JNZL. Ian Wedde's memoir 'A Little Bit Prickly...' was presented as the 9th annual Frank Sargeson Memorial Lecture at the University of Waikato on 15 September 2011. The English Programme of the University of Waikato has previously published the Sargeson lectures in its ephemeral Occasional Papers series, but we are now delighted to be able to offer these addresses a more permanent and accessible home in JNZL. Thanks indeed to Ian, New Zealand's poet laureate, for making his text available to us.

text: Editorial This issue also presents new work from an unusual quarter, and in an unusual genre for JNZL. Ian Wedde's memoir 'A Little Bit Prickly...' was presented as the 9th annual Frank Sargeson Memorial Lecture at the University of Waikato on 15 September 2011. The English Programme of the University of Waikato has previously published the Sargeson lectures in its ephemeral Occasional Papers series, but we are now delighted to be able to offer these addresses a more permanent and accessible home in JNZL. Thanks indeed to Ian, New Zealand's poet laureate, for making his text available to us.

year: 2011

title: The rhetorical organisation of Maori discourse: An illustration

authors: Crombie, Winifred

subjects: Māori medium education

abstract: Almost 20% all Māori students in New Zealand schools are involved in some form of Māori-medium education. These students need to develop competence in using the language for a wide range of purposes. They need, therefore, to understand a range of written discourse conventions. In seeking to assist them in this task, elders and scholars are turning to the works of major Māori figures of the past, works composed when the language was used widely in a range of discourse contexts. However, scholars need ways of analysing these texts and of communicating their findings to others. The primary aim of this paper is to demonstrate one such approach. A single letter of condolence written in Māori is analysed here in terms of rhetorical discourse structure. On the basis of the analysis, a number of hypotheses concerning epistolary discourse in Māori are put forward. The primary hypothesis is that letters of condolence written in Māori by highly competent users of the language are likely to be characterized by an overall Problem-Solution rhetorical prototype involving spiral multilayering.

text: The rhetorical organisation of Maori discourse: An illustration Almost 20% all Māori students in New Zealand schools are involved in some form of Māori-medium education. These students need to develop competence in using the language for a wide range of purposes. They need, therefore, to understand a range of written discourse conventions. In seeking to assist them in this task, elders and scholars are turning to the works of major Māori figures of the past, works composed when the language was used widely in a range of discourse contexts. However, scholars need ways of analysing these texts and of communicating their findings to others. The primary aim of this paper is to demonstrate one such approach. A single letter of condolence written in Māori is analysed here in terms of rhetorical discourse structure. On the basis of the analysis, a number of hypotheses concerning epistolary discourse in Māori are put forward. The primary hypothesis is that letters of condolence written in Māori by highly competent users of the language are likely to be characterized by an overall Problem-Solution rhetorical prototype involving spiral multilayering.

year: 2001-02