title: Processing, microstructure and high strain rate behaviour of Ti-6Al-4V Alloy produced from a blended mixture using powder compact extrusion

authors: Singh, Ajit Pal

subjects: Blended powder metallurgy

abstract: Powder compact extrusion (PCE) is an innovative way of processing titanium and titanium alloys to produce good-quality material with a wide range of compositions, microstructures and mechanical properties. This paper explores PCE processing of Ti-6Al-4V alloy prepared from a blended powder mixture, containing elemental hydride-dehydride (HDH) titanium powder and master alloy (60Al-40V) powder. The warm pressed compacts of blended powders were sintered using a vacuum sintering furnace prior to β extrusion. The resulting material was used to measure the performance under high strain rate and tri-axial stress state using Charpy v-notch testing. A comparison was made of the microstructure after vacuum sintering and hot extrusion in addition to oxygen measurements to determine the degree of oxygen pickup during each processing stage. A comprehensive study of fracture surfaces in selected samples was carried out using optical microscopy and scanning electron microscopy. Based on the results, it is clear that certain samples picked up varying amounts of interstitial impurities during processing and as a consequence a significant number of micro-cracks were observed in lamellar type microstructures. The oxygen content of all as-extruded samples was between 0.34-0.44 wt.% with resultant impact toughness in the range of 10-14 J. The best impact toughness attained for the lowest oxygen as-extruded rods was 20% lower than the literature values for wrought material. In terms of fracture behaviour, ductile dimples, cleavage facets and cracks passing through lamellar structures were observed in all samples. However, the quantity of these fracture features varied significantly in each sample.

text: Processing, microstructure and high strain rate behaviour of Ti-6Al-4V Alloy produced from a blended mixture using powder compact extrusion Powder compact extrusion (PCE) is an innovative way of processing titanium and titanium alloys to produce good-quality material with a wide range of compositions, microstructures and mechanical properties. This paper explores PCE processing of Ti-6Al-4V alloy prepared from a blended powder mixture, containing elemental hydride-dehydride (HDH) titanium powder and master alloy (60Al-40V) powder. The warm pressed compacts of blended powders were sintered using a vacuum sintering furnace prior to β extrusion. The resulting material was used to measure the performance under high strain rate and tri-axial stress state using Charpy v-notch testing. A comparison was made of the microstructure after vacuum sintering and hot extrusion in addition to oxygen measurements to determine the degree of oxygen pickup during each processing stage. A comprehensive study of fracture surfaces in selected samples was carried out using optical microscopy and scanning electron microscopy. Based on the results, it is clear that certain samples picked up varying amounts of interstitial impurities during processing and as a consequence a significant number of micro-cracks were observed in lamellar type microstructures. The oxygen content of all as-extruded samples was between 0.34-0.44 wt.% with resultant impact toughness in the range of 10-14 J. The best impact toughness attained for the lowest oxygen as-extruded rods was 20% lower than the literature values for wrought material. In terms of fracture behaviour, ductile dimples, cleavage facets and cracks passing through lamellar structures were observed in all samples. However, the quantity of these fracture features varied significantly in each sample.

year: 2016

title: Distinguishability of battery equivalent-circuit models containing CPEs: Updating the work of Berthier, Diard, & Michel

authors: Poihipi, Eden Kathleen

subjects: Constant Phase Elements

abstract: This manuscript revisits the assertion of Berthier et al. that competing fractional-element equivalent-circuit models of battery cells are indistinguishable in the presence of noise. Starting with Westerhoff’s general equivalent-circuit model (ECM) of 2016 and an idealized impedance spectrum of a lithium battery, a contemporary set of possible ECMs are chosen. Their distinguishability is investigated. Using the extended frequency range recommended by Mauracher & Karden in 1997 or Hasan & Scott in 2019, an approach is presented that permits selection of the appropriate model, even in the presence of noise. For the given frequency range, models with up to five elements or eight real parameters are studied. Fitting to measured data with straightforward numerical methods and choosing the most primitive appropriate sub-circuit is shown to reproduce the data. Typically a three-element, five-parameter ECM is shown to model real, measured data with precision comparable to individual sample error.

text: Distinguishability of battery equivalent-circuit models containing CPEs: Updating the work of Berthier, Diard, & Michel This manuscript revisits the assertion of Berthier et al. that competing fractional-element equivalent-circuit models of battery cells are indistinguishable in the presence of noise. Starting with Westerhoff’s general equivalent-circuit model (ECM) of 2016 and an idealized impedance spectrum of a lithium battery, a contemporary set of possible ECMs are chosen. Their distinguishability is investigated. Using the extended frequency range recommended by Mauracher & Karden in 1997 or Hasan & Scott in 2019, an approach is presented that permits selection of the appropriate model, even in the presence of noise. For the given frequency range, models with up to five elements or eight real parameters are studied. Fitting to measured data with straightforward numerical methods and choosing the most primitive appropriate sub-circuit is shown to reproduce the data. Typically a three-element, five-parameter ECM is shown to model real, measured data with precision comparable to individual sample error.

year: 2022

title: Recognising the negative impacts of aquatic weed management: Okawa Bay, Lake Rotoiti case study

authors: Scholes, Paul

abstract: The Te Arawa Rotorua Lakes Programme continues to implement measures to maintain and restore lake water quality in line with trophic level indices (TLI’s) for respective lakes. In Lakes Rotorua and Rotoiti this has also meant not only reducing nutrients to and in the lakes but also managing periodic cyano-bacterial (blue-green) algal blooms.
Restoration measures in the Rotorua and Rotoiti catchments have included land use management efforts to arrest nutrient inputs; diversion of Lake Rotorua waters from entering Rotoiti; sewage reticulation of lakeside communities; and treatment of inflows
with aluminium sulphate (alum). While restoration efforts have produced water quality gains in both lakes, in recent years, cyano-bacterial blooms have occurred in the shallow embayment of Lake Rotoiti, known as Okawa Bay.
These water quality gains have not come without a cost. Submerged aquatic weeds such as Hornwort are an increasing problem in the Rotorua Te Arawa Lakes and significant resources are needed to manage infestations primarily for aesthetic and recreational
amenity. Control of exotic aquatic weed is mostly with application of herbicide. Herbicide treatment leaves a decomposing biomass in the waterbody, potentially increasing the nutrient status.
We examine the impact aquatic weed decomposition has had on Okawa Bay’s nutrient status and the cyano-bacterial blooms over recent summers, and Bay of Plenty Regional Council’s response to reduce localised bloom development.

text: Recognising the negative impacts of aquatic weed management: Okawa Bay, Lake Rotoiti case study The Te Arawa Rotorua Lakes Programme continues to implement measures to maintain and restore lake water quality in line with trophic level indices (TLI’s) for respective lakes. In Lakes Rotorua and Rotoiti this has also meant not only reducing nutrients to and in the lakes but also managing periodic cyano-bacterial (blue-green) algal blooms.
Restoration measures in the Rotorua and Rotoiti catchments have included land use management efforts to arrest nutrient inputs; diversion of Lake Rotorua waters from entering Rotoiti; sewage reticulation of lakeside communities; and treatment of inflows
with aluminium sulphate (alum). While restoration efforts have produced water quality gains in both lakes, in recent years, cyano-bacterial blooms have occurred in the shallow embayment of Lake Rotoiti, known as Okawa Bay.
These water quality gains have not come without a cost. Submerged aquatic weeds such as Hornwort are an increasing problem in the Rotorua Te Arawa Lakes and significant resources are needed to manage infestations primarily for aesthetic and recreational
amenity. Control of exotic aquatic weed is mostly with application of herbicide. Herbicide treatment leaves a decomposing biomass in the waterbody, potentially increasing the nutrient status.
We examine the impact aquatic weed decomposition has had on Okawa Bay’s nutrient status and the cyano-bacterial blooms over recent summers, and Bay of Plenty Regional Council’s response to reduce localised bloom development.

year: 2015