title: The pluralism of commitment: The New Zealand fire service

authors: Keef, Stephen

subjects: New Zealand

abstract: This study examined the relationships between organizational commitment and three contituency-specific commitments for firefighters and station officers employed by the New Zealand Fire Service. The subjects were firefighters employed by the New Zealand Fire Service. Commitment to firefighters, station officers, senior management, and the Fire Service were measured using the Cook and Wall (1980) scale. We found that constituency-specific commitments explained approximately 30 percent of the variance in organizational commitment, four-fifths of which was explained by commitment to operational staff and the remaining fifth by commitment to senior management. The degree to which the results were a reflection of the industrial relations climate remains to be seen.

text: The pluralism of commitment: The New Zealand fire service This study examined the relationships between organizational commitment and three contituency-specific commitments for firefighters and station officers employed by the New Zealand Fire Service. The subjects were firefighters employed by the New Zealand Fire Service. Commitment to firefighters, station officers, senior management, and the Fire Service were measured using the Cook and Wall (1980) scale. We found that constituency-specific commitments explained approximately 30 percent of the variance in organizational commitment, four-fifths of which was explained by commitment to operational staff and the remaining fifth by commitment to senior management. The degree to which the results were a reflection of the industrial relations climate remains to be seen.

year: 2001

title: Development of extrudable hydrogels based on carboxymethyl cellulose–gelatin complex coacervates

authors: Gharanjig, Hamid

subjects: hydrogel

abstract: This study investigates the 3D extrusion printing of a carboxymethyl cellulose (CMC)–gelatin complex coacervate system. Various CMC–gelatin coacervate hydrogels were prepared and analyzed to achieve this goal. The impact of the CMC–gelatin ratio, pH, and total biopolymer concentration on coacervation formation and rheological properties was evaluated to characterize the printability of the samples. Turbidity results indicated that the molecular interactions between gelatin and CMC biopolymers are significantly pH-dependent, occurring within the range of pH 3.7 to pH 5.6 for the tested compositions. Confocal Laser Scanning Microscopy (CLSM) confirmed the presence of coacervates as spherical particles within the optimal coacervation range. Scanning electron microscopy micrographs supported the CLSM findings, revealing greater porosity within this optimal pH range. Rheological characterization demonstrated that all CMC–gelatin hydrogels exhibited pseudoplastic behavior, with an inverse correlation between increased coacervation and decreased shear viscosity. Additionally, the coacervates displayed lower tackiness compared to gelatin hydrogels, with the maximum tackiness normal force for various CMC–gelatin ratios ranging from 1 to 15 N, notably lower than the 29 N observed for gelatin hydrogels. Mixtures with CMC–gelatin ratios of 1:15 and 1:20 exhibited the best shear recovery behavior, maintaining higher strength after shear load. The maximum strength of the CMC–gelatin coacervate system was found at a biopolymer concentration of 6%. However, lower biopolymer content allowed for consistent extrusion. Importantly, all tested samples were successfully extruded at 22 ± 2 °C, with the 1:15 biopolymer ratio yielding the most consistent printed quality. Our research highlights the promise of the CMC–gelatin coacervate system for 3D printing applications, particularly in areas that demand precise material deposition and adjustable properties.

text: Development of extrudable hydrogels based on carboxymethyl cellulose–gelatin complex coacervates This study investigates the 3D extrusion printing of a carboxymethyl cellulose (CMC)–gelatin complex coacervate system. Various CMC–gelatin coacervate hydrogels were prepared and analyzed to achieve this goal. The impact of the CMC–gelatin ratio, pH, and total biopolymer concentration on coacervation formation and rheological properties was evaluated to characterize the printability of the samples. Turbidity results indicated that the molecular interactions between gelatin and CMC biopolymers are significantly pH-dependent, occurring within the range of pH 3.7 to pH 5.6 for the tested compositions. Confocal Laser Scanning Microscopy (CLSM) confirmed the presence of coacervates as spherical particles within the optimal coacervation range. Scanning electron microscopy micrographs supported the CLSM findings, revealing greater porosity within this optimal pH range. Rheological characterization demonstrated that all CMC–gelatin hydrogels exhibited pseudoplastic behavior, with an inverse correlation between increased coacervation and decreased shear viscosity. Additionally, the coacervates displayed lower tackiness compared to gelatin hydrogels, with the maximum tackiness normal force for various CMC–gelatin ratios ranging from 1 to 15 N, notably lower than the 29 N observed for gelatin hydrogels. Mixtures with CMC–gelatin ratios of 1:15 and 1:20 exhibited the best shear recovery behavior, maintaining higher strength after shear load. The maximum strength of the CMC–gelatin coacervate system was found at a biopolymer concentration of 6%. However, lower biopolymer content allowed for consistent extrusion. Importantly, all tested samples were successfully extruded at 22 ± 2 °C, with the 1:15 biopolymer ratio yielding the most consistent printed quality. Our research highlights the promise of the CMC–gelatin coacervate system for 3D printing applications, particularly in areas that demand precise material deposition and adjustable properties.

year: 2025-01-08

title: Tū Māori Ake: Seeking which is above.

authors: Maxwell, Te Kahautu

abstract: Te Waka Āwhina 2015 Seeking that which is above Kaupapa - Philosophy o Aotearoa “Tū Māori ake” E ngā mana, e ngā reo, e ngā karangatanga, nei rā te powhiri ki a koutou katoa ‘MĀ TE MĀORI, MŌ TE MĀORI’ Te Waka Āwhina o Aotearoa National Training Hui by Māori for Māori within local government Āwhea: 2 – 4 February 2015 Ki whea: The Gallagher Academy of Performing Arts, The University of Waikato, Hamilton Hau kāinga: Te Puku o te Ika.

text: Tū Māori Ake: Seeking which is above. Te Waka Āwhina 2015 Seeking that which is above Kaupapa - Philosophy o Aotearoa “Tū Māori ake” E ngā mana, e ngā reo, e ngā karangatanga, nei rā te powhiri ki a koutou katoa ‘MĀ TE MĀORI, MŌ TE MĀORI’ Te Waka Āwhina o Aotearoa National Training Hui by Māori for Māori within local government Āwhea: 2 – 4 February 2015 Ki whea: The Gallagher Academy of Performing Arts, The University of Waikato, Hamilton Hau kāinga: Te Puku o te Ika.

year: 2015-02-03