title: Study of metal scrambling in the trinuclear {Pt₂Se₂M} (M = Pt, Pd, Au) system using an electrospray mass spectrometry (ESMS) directed synthetic methodology; isolation and crystallographic characterization of {Pt₂(µ₃-Se)₂(PPh₃)₄[Pt(cod)]}{PF₆}₂ and {Pt(μ₃-Se)₂(PPh₃)₂[Pt(cod)]₂}{PF₆}₂ (cod = Cyclo-octa-1,5-diene)

authors: Yeo, Jeremy S.L.

subjects: chemistry

abstract: Pt₂(μ-Se)₂(PPh₃)₄ reacts with PtCl₂(cod) to give {Pt₂(μ₃-Se)₂(PPh₃)₄[Pt(cod)]}²⁺ and an unexpected cod-rich product that arises from metal scrambling, viz. {Pt(μ₃-Se)₂(PPh₃)₂[Pt(cod)]₂}²⁺. The formation of these species was detected and followed by electrospray mass spectrometry (ESMS) and subsequently verified by batch synthesis and crystallographic characterization. Other metal-scrambled aggregate products were successfully detected.

text: Study of metal scrambling in the trinuclear {Pt₂Se₂M} (M = Pt, Pd, Au) system using an electrospray mass spectrometry (ESMS) directed synthetic methodology; isolation and crystallographic characterization of {Pt₂(µ₃-Se)₂(PPh₃)₄[Pt(cod)]}{PF₆}₂ and {Pt(μ₃-Se)₂(PPh₃)₂[Pt(cod)]₂}{PF₆}₂ (cod = Cyclo-octa-1,5-diene) Pt₂(μ-Se)₂(PPh₃)₄ reacts with PtCl₂(cod) to give {Pt₂(μ₃-Se)₂(PPh₃)₄[Pt(cod)]}²⁺ and an unexpected cod-rich product that arises from metal scrambling, viz. {Pt(μ₃-Se)₂(PPh₃)₂[Pt(cod)]₂}²⁺. The formation of these species was detected and followed by electrospray mass spectrometry (ESMS) and subsequently verified by batch synthesis and crystallographic characterization. Other metal-scrambled aggregate products were successfully detected.

year: 2002

title: Netball in the lives of New Zealand Women: An Intergenerational Study

authors: Marfell, Amy Elizabeth

subjects: netball

abstract: This thesis explores the netball experiences of a selection of New Zealand women whom have participated or continue to participate in netball during four distinct historical periods. Adopting an interdisciplinary approach, it sheds light on the broader socio-cultural and political changes that have influenced and shaped women’s experiences of netball throughout history. Drawing upon data gathered from primary and secondary sources and four focus groups, I examine the lived experiences of women who played netball during the 1940’s, 1970’s, 1990’s and the early 21st century. In so doing I reveal how broader shifts in gender relations have impacted women’s netball experiences, focusing particularly on their initial involvement, participation at recreational and competitive levels, and ultimate withdrawal. Moreover, an intergenerational discussion of these women’s experiences reveals some of the differences evident between the experiences of women during these four historical junctures. Exploring women’s netball experiences in relation to broader social change, time and context both within and across generations, this thesis provides unique insights into the changing nature and dynamics of netball in New Zealand, shifting social constructions of femininity and women’s sporting identities, as well as women’s unique and diverse experiences and understandings of their participation.

text: Netball in the lives of New Zealand Women: An Intergenerational Study This thesis explores the netball experiences of a selection of New Zealand women whom have participated or continue to participate in netball during four distinct historical periods. Adopting an interdisciplinary approach, it sheds light on the broader socio-cultural and political changes that have influenced and shaped women’s experiences of netball throughout history. Drawing upon data gathered from primary and secondary sources and four focus groups, I examine the lived experiences of women who played netball during the 1940’s, 1970’s, 1990’s and the early 21st century. In so doing I reveal how broader shifts in gender relations have impacted women’s netball experiences, focusing particularly on their initial involvement, participation at recreational and competitive levels, and ultimate withdrawal. Moreover, an intergenerational discussion of these women’s experiences reveals some of the differences evident between the experiences of women during these four historical junctures. Exploring women’s netball experiences in relation to broader social change, time and context both within and across generations, this thesis provides unique insights into the changing nature and dynamics of netball in New Zealand, shifting social constructions of femininity and women’s sporting identities, as well as women’s unique and diverse experiences and understandings of their participation.

year: 2011

title: How Maori have been affected through the notion and practice of schooling: A theoretical analysis

authors: Williamson, Laurie Thomas

abstract: Education has always been associated according to the public with a necessary function to equip individuals to fit into society when they reach adulthood. The fact that it functions with efficiency is attributed in part to the implementation of social norms, which "impose uniformity of behaviour" (Young 2006, p. 1).

This thesis delves into how Maori have been positioned under a mainstream schooling discourse which has put them at a disadvantage since the implementation of a discourse requires the subjugation of those who are not the majority power holders to assimilate into someone else's discourse. The effect of assimilation into a mainstream discourse has political implications for Maori, as schools are the gateway towards social stratification. This thesis will look at the historical and developmental concept of schooling within a western context, moving towards the development of formal schooling in New Zealand and also look at the sociological and political impact of schooling upon Maori students.

I will also differentiate between the terms schooling and education to suggest Maori forms of educational discourse has been marginalised in favour of assimilation into a supposedly equitable rigid, formal system of schooling. I will illustrate the broader concept of education that takes place outside of schools formal boundaries as a way to contrast the level of control and regulation the government initiates within the formal schooling environment. I will also look at the way schools have been used from its colonial beginnings in New Zealand as a way to civilise or impose one cultural practice on another as a way of breaking down uncivilised beliefs and traditions.

text: How Maori have been affected through the notion and practice of schooling: A theoretical analysis Education has always been associated according to the public with a necessary function to equip individuals to fit into society when they reach adulthood. The fact that it functions with efficiency is attributed in part to the implementation of social norms, which "impose uniformity of behaviour" (Young 2006, p. 1).

This thesis delves into how Maori have been positioned under a mainstream schooling discourse which has put them at a disadvantage since the implementation of a discourse requires the subjugation of those who are not the majority power holders to assimilate into someone else's discourse. The effect of assimilation into a mainstream discourse has political implications for Maori, as schools are the gateway towards social stratification. This thesis will look at the historical and developmental concept of schooling within a western context, moving towards the development of formal schooling in New Zealand and also look at the sociological and political impact of schooling upon Maori students.

I will also differentiate between the terms schooling and education to suggest Maori forms of educational discourse has been marginalised in favour of assimilation into a supposedly equitable rigid, formal system of schooling. I will illustrate the broader concept of education that takes place outside of schools formal boundaries as a way to contrast the level of control and regulation the government initiates within the formal schooling environment. I will also look at the way schools have been used from its colonial beginnings in New Zealand as a way to civilise or impose one cultural practice on another as a way of breaking down uncivilised beliefs and traditions.

year: 2012