title: Tidal inlet configuration and bathymetric changes resulting from active sedimentation, Buffalo Bay, New Zealand.

authors: Steeghs, Lauren

subjects: accretion

abstract: The Whitianga tidal inlet lies within Mercury Bay, on the northeast coast of New Zealand. The Whitianga Estuary harbours many recreational and commercial vessels. Terrestrial sediment inputs into the Whitianga Estuary catchment are high, due to the erodible tertiary sediments and the steep nature of the catchment, which suffers intense rainfall that results in high sediment influxes, much of which becomes deposited within the estuary. In recent years active shoals have appeared in Buffalo Bay and the inlet channel has noticeably shallowed, both of which inhibit the use of the inlet by boat traffic. The past and present bathymetry of Buffalo Bay is compared to establish changes in morphology and zones of accretion and erosion within Buffalo Bay. The outcomes of this research contribute to a larger research programme which aims to use numerical model simulations to identify sediment transport pathways and patterns within Buffalo Bay. This research will particularly provide information which can be used to calibrate a sediment transport model. Comparison of the Buffalo Bay bathymetries over the 38 year period from 1938 to 1979 and Whitianga inlet bathymetries between 1979 and 1995, show extensive accretion in the ebb discharge channel which is predominantly associated with the migration of the tidal inlet channel and growth of the ebb delta, and within the inner inlet area which are attributed to the growth of the flood delta system.

text: Tidal inlet configuration and bathymetric changes resulting from active sedimentation, Buffalo Bay, New Zealand. The Whitianga tidal inlet lies within Mercury Bay, on the northeast coast of New Zealand. The Whitianga Estuary harbours many recreational and commercial vessels. Terrestrial sediment inputs into the Whitianga Estuary catchment are high, due to the erodible tertiary sediments and the steep nature of the catchment, which suffers intense rainfall that results in high sediment influxes, much of which becomes deposited within the estuary. In recent years active shoals have appeared in Buffalo Bay and the inlet channel has noticeably shallowed, both of which inhibit the use of the inlet by boat traffic. The past and present bathymetry of Buffalo Bay is compared to establish changes in morphology and zones of accretion and erosion within Buffalo Bay. The outcomes of this research contribute to a larger research programme which aims to use numerical model simulations to identify sediment transport pathways and patterns within Buffalo Bay. This research will particularly provide information which can be used to calibrate a sediment transport model. Comparison of the Buffalo Bay bathymetries over the 38 year period from 1938 to 1979 and Whitianga inlet bathymetries between 1979 and 1995, show extensive accretion in the ebb discharge channel which is predominantly associated with the migration of the tidal inlet channel and growth of the ebb delta, and within the inner inlet area which are attributed to the growth of the flood delta system.

year: 2007

title: Development of an HPLC method to analyze four veterinary antibiotics in soils and aqueous media and validation through fate studies

authors: Srinivasan, Prakash

subjects: HPLC

abstract: A simple, yet robust analytical method was developed to detect and quantify three sulfonamides (SA), namely sulfamethoxazole (SMO), sulfachloropyridazine (SCP), and sulfamethazine (SM), and a macrolide tylosin (TT) in aqueous (calcium chloride and leachate solutions) and solid (agricultural soils) matrices using high performance liquid chromatography and ultra violet detection at 290 nm (TT) and 275 nm (SA) respectively. Chromatography was performed using a Phenomenex Onyx Monolithic C-18 column for TT and a C-18 Luna column for sulfonamides as single analytes eluted isocratically with a mobile phase consisting of acetonitrile: trifluoroacetic acid: tetrahydrofuran in the ratio 22.5:68:9.5 for TT, 40:55:5 for SMO, 32:63:5 for SCP and 31:64:5 for SM (v/v) at 1.0 mL min(-1) and an injection volume of 20 mu L. A gradient method to detect all three sulfonamides in a single run was also developed. The soil residue analysis consisted of extraction with dichloromethane and pre-concentration steps as the aqueous phase was measured directly. The limits of detection at an S/N (signal: noise) ratio of 3 were 20.0 mu g L-1 and 50 mu g L-1 for all sulfonamides and tylosin respectively. The average recoveries for all sulfonamides and tylosin in aqueous matrices ranged from 95 to 105% across the six concentrations investigated. Recoveries from the soils were slightly lower for sulfonamides and tylosin. The isocratic method was used to determine the sorption and degradation of sulfonamides in soils, while the gradient method was used to determine degradation kinetics and leachate concentrations in soils and aqueous systems.

text: Development of an HPLC method to analyze four veterinary antibiotics in soils and aqueous media and validation through fate studies A simple, yet robust analytical method was developed to detect and quantify three sulfonamides (SA), namely sulfamethoxazole (SMO), sulfachloropyridazine (SCP), and sulfamethazine (SM), and a macrolide tylosin (TT) in aqueous (calcium chloride and leachate solutions) and solid (agricultural soils) matrices using high performance liquid chromatography and ultra violet detection at 290 nm (TT) and 275 nm (SA) respectively. Chromatography was performed using a Phenomenex Onyx Monolithic C-18 column for TT and a C-18 Luna column for sulfonamides as single analytes eluted isocratically with a mobile phase consisting of acetonitrile: trifluoroacetic acid: tetrahydrofuran in the ratio 22.5:68:9.5 for TT, 40:55:5 for SMO, 32:63:5 for SCP and 31:64:5 for SM (v/v) at 1.0 mL min(-1) and an injection volume of 20 mu L. A gradient method to detect all three sulfonamides in a single run was also developed. The soil residue analysis consisted of extraction with dichloromethane and pre-concentration steps as the aqueous phase was measured directly. The limits of detection at an S/N (signal: noise) ratio of 3 were 20.0 mu g L-1 and 50 mu g L-1 for all sulfonamides and tylosin respectively. The average recoveries for all sulfonamides and tylosin in aqueous matrices ranged from 95 to 105% across the six concentrations investigated. Recoveries from the soils were slightly lower for sulfonamides and tylosin. The isocratic method was used to determine the sorption and degradation of sulfonamides in soils, while the gradient method was used to determine degradation kinetics and leachate concentrations in soils and aqueous systems.

year: 2012

title: Developing an effective education reform model for indigenous and other minoritized students

authors: Bishop, Russell

subjects: indigenous

abstract: Educational disparities between indigenous Maori students and those of the majority continue to be a major issue in New Zealand. Te Kotahitanga, an iterative research and development programme, which commenced in 2001, supports teachers to implement a relationship-based pedagogy in their classrooms in order to improve Maori students' achievement in mainstream secondary schools. This article addresses the question of how gains in Maori students' achievement can be sustained and expanded. Schools, from an earlier phase of the project, in their 6th and 7th year of the programme were examined, using a theory-based model designed to evaluate and promote dimensions necessary for effective institutional support of the teaching innovation. This article demonstrates that schools that have been the most effective implementers of the intervention have seen the greatest gains made by Maori students in the 1st year of national assessments. This article then discusses effective leadership for addressing problems schools encountered while implementing the pedagogic reform.

text: Developing an effective education reform model for indigenous and other minoritized students Educational disparities between indigenous Maori students and those of the majority continue to be a major issue in New Zealand. Te Kotahitanga, an iterative research and development programme, which commenced in 2001, supports teachers to implement a relationship-based pedagogy in their classrooms in order to improve Maori students' achievement in mainstream secondary schools. This article addresses the question of how gains in Maori students' achievement can be sustained and expanded. Schools, from an earlier phase of the project, in their 6th and 7th year of the programme were examined, using a theory-based model designed to evaluate and promote dimensions necessary for effective institutional support of the teaching innovation. This article demonstrates that schools that have been the most effective implementers of the intervention have seen the greatest gains made by Maori students in the 1st year of national assessments. This article then discusses effective leadership for addressing problems schools encountered while implementing the pedagogic reform.

year: 2012