title: Properties of bloodmeal/linear low-density polyethylene blends compatibilized with maleic anhydride grafted polyethylene

authors: Marsilla, K. I. Ku

subjects: biopolymers and renewable polymers

abstract: Novatein thermoplastics from bloodmeal (NTP) were blended with linear low-density polyethylene (LLDPE) using maleic anhydride grafted polyethylene (PE-g-MAH) as compatibilizer. The compatibilizing effect on mechanical, morphology, thermal properties, and water absorption were studied and compared with blends without compatibilizer. The amount of polyethylene added was varied between 20 and 70% in NTP with addition of 10% compatibilizer. An improvement in compatibility between NTP and LLDPE was observed across the entire composition range and the difference were more pronounced at higher NTP contents where the tensile strength of blends was maintained and never dropped below that of pure NTP. Theoretical models were compared to the results to describe mechanical properties. A finely dispersed small particles of NTP in compatibilized blends were observed using SEM. Improved compatibility has restricted chain movement resulting in slightly elevated Tg revealed by DMA. On the other hand, water absorption of the hydrophilic NTP has been decreased when blending with hydrophobic LLDPE.

text: Properties of bloodmeal/linear low-density polyethylene blends compatibilized with maleic anhydride grafted polyethylene Novatein thermoplastics from bloodmeal (NTP) were blended with linear low-density polyethylene (LLDPE) using maleic anhydride grafted polyethylene (PE-g-MAH) as compatibilizer. The compatibilizing effect on mechanical, morphology, thermal properties, and water absorption were studied and compared with blends without compatibilizer. The amount of polyethylene added was varied between 20 and 70% in NTP with addition of 10% compatibilizer. An improvement in compatibility between NTP and LLDPE was observed across the entire composition range and the difference were more pronounced at higher NTP contents where the tensile strength of blends was maintained and never dropped below that of pure NTP. Theoretical models were compared to the results to describe mechanical properties. A finely dispersed small particles of NTP in compatibilized blends were observed using SEM. Improved compatibility has restricted chain movement resulting in slightly elevated Tg revealed by DMA. On the other hand, water absorption of the hydrophilic NTP has been decreased when blending with hydrophobic LLDPE.

year: 2013

title: Environmentally smart contracts for artists using non-fungible tokens

authors: Weijers, Dan M.

abstract: We propose Environmentally Smart Contracts, a new kind of smart contract for non-fungible tokens to solve the prudential-moral dilemma facing digital artists. The current proof-of-work-dominated non-fungible token environment requires artists to trade off the prudential benefits and the environmental costs of selling their art on blockchains. By fully correcting for environmental externalities, Environmentally Smart Contracts will allow artists to reap the sales benefits of non-fungible tokens without contributing to environmental degradation. Concrete steps to encourage the development of Environmentally Smart Contracts are discussed.

text: Environmentally smart contracts for artists using non-fungible tokens We propose Environmentally Smart Contracts, a new kind of smart contract for non-fungible tokens to solve the prudential-moral dilemma facing digital artists. The current proof-of-work-dominated non-fungible token environment requires artists to trade off the prudential benefits and the environmental costs of selling their art on blockchains. By fully correcting for environmental externalities, Environmentally Smart Contracts will allow artists to reap the sales benefits of non-fungible tokens without contributing to environmental degradation. Concrete steps to encourage the development of Environmentally Smart Contracts are discussed.

year: 2021

title: He oranga tō te wai: Māori Pedagogies - A Culturally Responsive View of Aquatic Education and Drowning Prevention in Aotearoa

authors: Haimona, Mark Waihape

abstract: Drowning is a leading cause of accidental death and hospitalisation among Māori in Aotearoa. Drowning reports (Water Safety New Zealand, 2010, 2016, 2019) indicate Māori are over-represented in drowning compared to non-Māori, and on average account for up to a quarter of all drowning fatalities each year. Māori male aged 15-44 years and Māori children under five are most at risk of drowning (WSNZ, 2018, 2). A recent Aotearoa study on children’s water survival skills suggest changes are needed to improve how children develop fundamental aquatic skills and how teachers can best teach those skills (Button et al., 2017). In particular, the teaching of water safety skills for broader use in the open water environments of Aotearoa. 
Māori pedagogies within physical education, health, and education in the outdoors (Hemara, 2000; Jackson et al, 2016; Phillips, 2018) have demonstrated the benefits of Māori teaching methods that foster positive learning outcomes for Māori. (Bishop & Berryman, 2006, 2009). As such, this research investigated core components of Māori pedagogies that can improve aquatic education for Māori. It sought to validate traditional and contemporary aquatic teachings and water safety practices that Māori exercise as an expression of ira tangata (human development) and their relationship with te ao tūroa (the long-standing world). By means of kaupapa Māori research and the development of a new framework - Tāne Whānau Mārama, this thesis offers valuable insights into the importance of culturally responsive pedagogies in aquatic education that will enhance the health, educational achievements, and well-being of Māori whānau and communities.

text: He oranga tō te wai: Māori Pedagogies - A Culturally Responsive View of Aquatic Education and Drowning Prevention in Aotearoa Drowning is a leading cause of accidental death and hospitalisation among Māori in Aotearoa. Drowning reports (Water Safety New Zealand, 2010, 2016, 2019) indicate Māori are over-represented in drowning compared to non-Māori, and on average account for up to a quarter of all drowning fatalities each year. Māori male aged 15-44 years and Māori children under five are most at risk of drowning (WSNZ, 2018, 2). A recent Aotearoa study on children’s water survival skills suggest changes are needed to improve how children develop fundamental aquatic skills and how teachers can best teach those skills (Button et al., 2017). In particular, the teaching of water safety skills for broader use in the open water environments of Aotearoa. 
Māori pedagogies within physical education, health, and education in the outdoors (Hemara, 2000; Jackson et al, 2016; Phillips, 2018) have demonstrated the benefits of Māori teaching methods that foster positive learning outcomes for Māori. (Bishop & Berryman, 2006, 2009). As such, this research investigated core components of Māori pedagogies that can improve aquatic education for Māori. It sought to validate traditional and contemporary aquatic teachings and water safety practices that Māori exercise as an expression of ira tangata (human development) and their relationship with te ao tūroa (the long-standing world). By means of kaupapa Māori research and the development of a new framework - Tāne Whānau Mārama, this thesis offers valuable insights into the importance of culturally responsive pedagogies in aquatic education that will enhance the health, educational achievements, and well-being of Māori whānau and communities.

year: 2023