title: Synthesis of a boronic acid anhydride based ligand and its application in beryllium coordination

authors: Buchner, Magnus R.

subjects: Science & Technology

abstract: The synthesis of a boronic acid anhydride‐based ligand containing one three‐ and one four‐coordinated boron atom is presented. This ligand was successfully employed as a tridentate κ¹N,κ²O‐ligand in the coordination of beryllium chloride and both the ligand and the resulting complex have been structurally characterized. While the boron‐element separations are within the typical range of related homo‐nuclear compounds, the corresponding beryllium‐element distances are rather long, suggesting unexpectedly high electron density at the beryllium center. Incorporation of a beryllium atom in a six‐membered ring causes no more distortion than the corresponding boron atom, suggesting that analogous ligand systems could be used in boron and beryllium coordination chemistry. The generated hetero‐tri‐nuclear complex enables the direct comparison of bond lengths and angles at beryllium and boron atoms in similar coordination environments and can act as a monomolecular model for beryllium borates.

text: Synthesis of a boronic acid anhydride based ligand and its application in beryllium coordination The synthesis of a boronic acid anhydride‐based ligand containing one three‐ and one four‐coordinated boron atom is presented. This ligand was successfully employed as a tridentate κ¹N,κ²O‐ligand in the coordination of beryllium chloride and both the ligand and the resulting complex have been structurally characterized. While the boron‐element separations are within the typical range of related homo‐nuclear compounds, the corresponding beryllium‐element distances are rather long, suggesting unexpectedly high electron density at the beryllium center. Incorporation of a beryllium atom in a six‐membered ring causes no more distortion than the corresponding boron atom, suggesting that analogous ligand systems could be used in boron and beryllium coordination chemistry. The generated hetero‐tri‐nuclear complex enables the direct comparison of bond lengths and angles at beryllium and boron atoms in similar coordination environments and can act as a monomolecular model for beryllium borates.

year: 2019

title: Continuance theory and teacher education

authors: Wright, Noeline

subjects: continuance theory

abstract: Continuance theory is usually related to the regular use of technology in the business/industry area. It attempts to explain why people either continue to use specific technologies in their work, or not. Essentially, it links to the perceived value to individuals‟ ability to work effectively, however that is understood in their workplace. In the profession of education, particularly schools and teacher education, the perceived value of continued use is not about individuals and their work, but about individuals‟ work with groups of students and what happens to learning when these digital technologies are used. Continued use is contingent on their students‟ positive responses to these technologies supporting learning. I examine, in the light of continuance theory, what happens when student teachers in an initial secondary teacher education programme report on including digital technologies on practicum. This includes reporting on the effect students‟ responses have on their subsequent attitudes and practices regarding digital technologies in learning contexts.

text: Continuance theory and teacher education Continuance theory is usually related to the regular use of technology in the business/industry area. It attempts to explain why people either continue to use specific technologies in their work, or not. Essentially, it links to the perceived value to individuals‟ ability to work effectively, however that is understood in their workplace. In the profession of education, particularly schools and teacher education, the perceived value of continued use is not about individuals and their work, but about individuals‟ work with groups of students and what happens to learning when these digital technologies are used. Continued use is contingent on their students‟ positive responses to these technologies supporting learning. I examine, in the light of continuance theory, what happens when student teachers in an initial secondary teacher education programme report on including digital technologies on practicum. This includes reporting on the effect students‟ responses have on their subsequent attitudes and practices regarding digital technologies in learning contexts.

year: 2012

title: Te taiao: Te titiro a te Māori

authors: Kirby, Dean Robert

subjects: Cosmology

abstract: Ko te kaupapa o tēnei tuhinga ko te titiro a te Māori ki te taiao. He mea tuhi i runga i te aroha, i te whakapono ki ngēnei mea, ki te ātaahua o te taiao me ngā kōrero mōna. E whakatangatatia ana ngā āhuatanga o te taiao, ngā rākau, ngā manu, ngā ika, te kohu, ngā kapua, ngā maunga, otirā ngā mea katoa. Ara noa atu ngā kōrero, he whakapapa ō rātou, he huānga tētehi mea ki tētehi, he mauri tō tēnā mea tō tēnā mea. E ora ana ngā mea katoa o te ao, ka whai tamariki, he mātua he tūpuna anō, te katoa tae atu hoki ki te tangata, he wāhanga ia nō te taiao.
Hei aha tēnei tuhinga? Ko tāna mahi he whakaatu i ngēnei āhuatanga. Ā he whakamātau hoki ki te whakautu i te pātai he aha i whērā ai te titiro a ngā tūpuna ki tō rātou taiao. He kohikohingā tēnei nō ngā kōrero maha e takoto mai naka i roto i ngā pukapuka kua tāia kētia. Ehake i te mea ka kōrerotia ngā mea katoa, otiia ka tirohia noatia ngētehi āhuatanga o tēnei hanga te taiao. Kāhore i tuhia i runga i ngā kōrero ā waha a ngētehi kaikōrero, whēnā i ngētehi atu tuhinga roa. He mahi nui tērā mā tētehi atu hei whai, heoi anō tēnei he huihuinga nō ngētehi kōrero kua tuhia i mua atu.
Ka whakarārangitia ngā kōrero neki i muri ake nei. Ko tōna timatanga kei te Ōrokohanga, ko te timatanga tērā o te taiao. Ko te whenua ka whai mai me ngā kōrero mōna. Muri iho ko te wai me ngōna āhuatanga katoa. Ko te rangi, ngā mea katoa o te rangi ka whai mai i muri i tēnā. Muri iho anō ko ngā manu, ko ngā ngārara me ngā ngāngara, ngā rākau me ngā ika. Ka mutu atu i ngā tupua, i ngā taniwha me ngā patupaiarehe, i ngā kōrero mō ngērā. E iwa wāhanga nui te katoa o tēnei tuhinga. Kei te timatanga tētehi wāhanga hei whakamārama i te tuhinga ā kei te mutunga tētehi atu wāhanga hei whakatōpū, hei whakarāpopoto i ngā kōrero o roto i te puku o te tuhinga nei.
Kei ngā wāhanga o te pukapuka nei he kōrero mō tēnā mea, mō tēnā mea i raro i tōna ūpoko anō, me ngā whakaāhua e rite ana mōna. Ko te tūmanako ka kite te kaipānui i te pūrotutanga o te taiao o te Māori.

text: Te taiao: Te titiro a te Māori Ko te kaupapa o tēnei tuhinga ko te titiro a te Māori ki te taiao. He mea tuhi i runga i te aroha, i te whakapono ki ngēnei mea, ki te ātaahua o te taiao me ngā kōrero mōna. E whakatangatatia ana ngā āhuatanga o te taiao, ngā rākau, ngā manu, ngā ika, te kohu, ngā kapua, ngā maunga, otirā ngā mea katoa. Ara noa atu ngā kōrero, he whakapapa ō rātou, he huānga tētehi mea ki tētehi, he mauri tō tēnā mea tō tēnā mea. E ora ana ngā mea katoa o te ao, ka whai tamariki, he mātua he tūpuna anō, te katoa tae atu hoki ki te tangata, he wāhanga ia nō te taiao.
Hei aha tēnei tuhinga? Ko tāna mahi he whakaatu i ngēnei āhuatanga. Ā he whakamātau hoki ki te whakautu i te pātai he aha i whērā ai te titiro a ngā tūpuna ki tō rātou taiao. He kohikohingā tēnei nō ngā kōrero maha e takoto mai naka i roto i ngā pukapuka kua tāia kētia. Ehake i te mea ka kōrerotia ngā mea katoa, otiia ka tirohia noatia ngētehi āhuatanga o tēnei hanga te taiao. Kāhore i tuhia i runga i ngā kōrero ā waha a ngētehi kaikōrero, whēnā i ngētehi atu tuhinga roa. He mahi nui tērā mā tētehi atu hei whai, heoi anō tēnei he huihuinga nō ngētehi kōrero kua tuhia i mua atu.
Ka whakarārangitia ngā kōrero neki i muri ake nei. Ko tōna timatanga kei te Ōrokohanga, ko te timatanga tērā o te taiao. Ko te whenua ka whai mai me ngā kōrero mōna. Muri iho ko te wai me ngōna āhuatanga katoa. Ko te rangi, ngā mea katoa o te rangi ka whai mai i muri i tēnā. Muri iho anō ko ngā manu, ko ngā ngārara me ngā ngāngara, ngā rākau me ngā ika. Ka mutu atu i ngā tupua, i ngā taniwha me ngā patupaiarehe, i ngā kōrero mō ngērā. E iwa wāhanga nui te katoa o tēnei tuhinga. Kei te timatanga tētehi wāhanga hei whakamārama i te tuhinga ā kei te mutunga tētehi atu wāhanga hei whakatōpū, hei whakarāpopoto i ngā kōrero o roto i te puku o te tuhinga nei.
Kei ngā wāhanga o te pukapuka nei he kōrero mō tēnā mea, mō tēnā mea i raro i tōna ūpoko anō, me ngā whakaāhua e rite ana mōna. Ko te tūmanako ka kite te kaipānui i te pūrotutanga o te taiao o te Māori.

year: 1992