title: POSTER: No Doppelgänger: Advancing mobile networks against impersonation in adversarial scenarios

authors: Boeira, Felipe

subjects: computer science

abstract: The expansion of mobile network capabilities throughout the decades has increased people's exposure to the digital world, and the next generations of communication networks are expected to achieve ubiquitous connectivity and immersive use cases. Security and privacy concerns have arisen and are continuously taken into account in the design of mobile networks. However, a relevant limitation currently lies in the use of shared secrets for providing security and privacy to users. Ideally, we believe that users' identities should be immune to impersonation as long as their own devices remain secure, notwithstanding the network operators and other entities potentially being compromised. In this paper, we develop this idea with the objective of providing the non-repudiation property, which represents a mitigation to its dual, impersonation.

text: POSTER: No Doppelgänger: Advancing mobile networks against impersonation in adversarial scenarios The expansion of mobile network capabilities throughout the decades has increased people's exposure to the digital world, and the next generations of communication networks are expected to achieve ubiquitous connectivity and immersive use cases. Security and privacy concerns have arisen and are continuously taken into account in the design of mobile networks. However, a relevant limitation currently lies in the use of shared secrets for providing security and privacy to users. Ideally, we believe that users' identities should be immune to impersonation as long as their own devices remain secure, notwithstanding the network operators and other entities potentially being compromised. In this paper, we develop this idea with the objective of providing the non-repudiation property, which represents a mitigation to its dual, impersonation.

year: 2022-05-16

title: Synthesis and characterisation of isomeric cycloaurated complexes derived from the iminophosphorane Ph₃P=NC(O)Ph

authors: Kilpin, Kelly Joan

subjects: gold complexes

abstract: Using different organomercury substrates, two isomeric cycloaurated complexes derived from the stabilised iminophosphorane Ph₃P NC(O)Ph were prepared. Reaction of Ph₃P NC(O)Ph with PhCH₂Mn(CO)₅ gave the manganated precursor (CO)₄Mn(2-C₆H₄C(O)N PPh₃), metallated on the C(O)Ph substituent, which yielded the organomercury complex ClHg(2-C₆H₄C(O)N PPh₃) by reaction with HgCl₂ in methanol. Transmetallation of the mercurated derivative with Me₄N[AuCl₄] gave the cycloaurated iminophosphorane AuCl₂(2-C₆H₄C(O)N PPh₃) with an exo PPh₃ substituent. The endo isomer AuCl₂(2-C₆H₄Ph₂P NC(O)Ph) [aurated on a PPh₃ ring] was obtained by an independent reaction sequence, involving reaction of the diarylmercury precursor Hg(2-C₆H₄P( NC(O)Ph)Ph₂)₂ [prepared from the known compound Hg(2-C₆H₄PPh₂)₂ and PhC(O)N₃] with Me₄N[AuCl₄]. Both of the isomeric iminophosphorane derivatives were structurally characterised, together with the precursors (2-HgClC₆H₄)C(O)N PPh₃ and (CO)₄Mn(2-C₆H₄C(O)N PPh₃). The utility of ³¹P NMR spectroscopy in monitoring reaction chemistry in this system is described.

text: Synthesis and characterisation of isomeric cycloaurated complexes derived from the iminophosphorane Ph₃P=NC(O)Ph Using different organomercury substrates, two isomeric cycloaurated complexes derived from the stabilised iminophosphorane Ph₃P NC(O)Ph were prepared. Reaction of Ph₃P NC(O)Ph with PhCH₂Mn(CO)₅ gave the manganated precursor (CO)₄Mn(2-C₆H₄C(O)N PPh₃), metallated on the C(O)Ph substituent, which yielded the organomercury complex ClHg(2-C₆H₄C(O)N PPh₃) by reaction with HgCl₂ in methanol. Transmetallation of the mercurated derivative with Me₄N[AuCl₄] gave the cycloaurated iminophosphorane AuCl₂(2-C₆H₄C(O)N PPh₃) with an exo PPh₃ substituent. The endo isomer AuCl₂(2-C₆H₄Ph₂P NC(O)Ph) [aurated on a PPh₃ ring] was obtained by an independent reaction sequence, involving reaction of the diarylmercury precursor Hg(2-C₆H₄P( NC(O)Ph)Ph₂)₂ [prepared from the known compound Hg(2-C₆H₄PPh₂)₂ and PhC(O)N₃] with Me₄N[AuCl₄]. Both of the isomeric iminophosphorane derivatives were structurally characterised, together with the precursors (2-HgClC₆H₄)C(O)N PPh₃ and (CO)₄Mn(2-C₆H₄C(O)N PPh₃). The utility of ³¹P NMR spectroscopy in monitoring reaction chemistry in this system is described.

year: 2010

title: Taku haumaru me te kurī - Te Reo Maori

authors: Carter, Jennifer

subjects: dog safety tips

abstract: This safety leaflet designed to target young children aged 5-6yrs will provide an age-appropriate understanding of how to avoid pet dog attacks which can injure, maim and even kill children.    This research-based educational resource provides practical, valid and reliable guidelines for safe interaction between children and pet dogs in their homes or known to them.  
The content of this leaflet has been drawn from ‘Stories with happy endings: Preventing pet dog attacks on children’, the 2007-2008 Summer Scholarship report prepared for the Child Accident Prevention Foundation of New Zealand (CAPFNZ). Obtain a copy of the report from http://hdl.handle.net/10289/768

text: Taku haumaru me te kurī - Te Reo Maori This safety leaflet designed to target young children aged 5-6yrs will provide an age-appropriate understanding of how to avoid pet dog attacks which can injure, maim and even kill children.    This research-based educational resource provides practical, valid and reliable guidelines for safe interaction between children and pet dogs in their homes or known to them.  
The content of this leaflet has been drawn from ‘Stories with happy endings: Preventing pet dog attacks on children’, the 2007-2008 Summer Scholarship report prepared for the Child Accident Prevention Foundation of New Zealand (CAPFNZ). Obtain a copy of the report from http://hdl.handle.net/10289/768

year: 2008