title: A kraft mill-integrated hydrothermal liquefaction process for liquid fuel co-production

authors: Ong, Benjamin H.Y.

subjects: Science & Technology

abstract: There is a growing awareness of the need to mitigate greenhouse gas emissions and the inevitable depletion of fossil fuel. With the market pull for the growth in sustainable and renewable alternative energy, the challenge is to develop cost-effective, large-scale renewable energy alternatives for all energy sectors, of which transport fuels are one significant area. This work presents a summary of novel methods for integrating kraft mills with a hydrothermal liquefaction process. The application of these methods has resulted in a proposed kraft mill-integrated design that produces a liquid fuel and could provide net mitigation of 64.6 kg CO2-e/GJ, compared to conventional petrol and diesel fuels, at a minimum fuel selling price of 1.12–1.38 NZD/LGE of fuel, based on the case study. This paper concludes that a hydrothermal liquefaction process with product upgrading has promising economic potential and environmental benefits that are significantly amplified by integrating with an existing kraft mill. At the current global kraft pulp production rate, if each kraft mill transforms into a biorefinery based on hydrothermal liquefaction, the biofuel production is an estimated 290 Mt (9.9 EJ).

text: A kraft mill-integrated hydrothermal liquefaction process for liquid fuel co-production There is a growing awareness of the need to mitigate greenhouse gas emissions and the inevitable depletion of fossil fuel. With the market pull for the growth in sustainable and renewable alternative energy, the challenge is to develop cost-effective, large-scale renewable energy alternatives for all energy sectors, of which transport fuels are one significant area. This work presents a summary of novel methods for integrating kraft mills with a hydrothermal liquefaction process. The application of these methods has resulted in a proposed kraft mill-integrated design that produces a liquid fuel and could provide net mitigation of 64.6 kg CO2-e/GJ, compared to conventional petrol and diesel fuels, at a minimum fuel selling price of 1.12–1.38 NZD/LGE of fuel, based on the case study. This paper concludes that a hydrothermal liquefaction process with product upgrading has promising economic potential and environmental benefits that are significantly amplified by integrating with an existing kraft mill. At the current global kraft pulp production rate, if each kraft mill transforms into a biorefinery based on hydrothermal liquefaction, the biofuel production is an estimated 290 Mt (9.9 EJ).

year: 2020

title: Review: Fluoroarylphosphines as ligands

authors: Pollock, Ciara L.

subjects: fluoroaryl

abstract: This short review concentrates on important aspects of fluoroarylphosphines, in particular their synthesis, ligand properties and chemical and catalytic properties of their complexes. Although the electronic, steric and chemical properties of fluoroarylphosphines have been known for 30 years, their use as ligands for homogeneous catalysis and in the synthesis of elaborate multidentate ligands has occurred more recently. The number of recent reports suggests that their importance is growing.

text: Review: Fluoroarylphosphines as ligands This short review concentrates on important aspects of fluoroarylphosphines, in particular their synthesis, ligand properties and chemical and catalytic properties of their complexes. Although the electronic, steric and chemical properties of fluoroarylphosphines have been known for 30 years, their use as ligands for homogeneous catalysis and in the synthesis of elaborate multidentate ligands has occurred more recently. The number of recent reports suggests that their importance is growing.

year: 2008

title: Te Pae Mahutonga and the measurement of community capital in regional Aotearoa New Zealand

authors: Ryks, John

abstract: Regionally, iwi and hapū have limited influence over structural changes such as population decline, proximity to labour markets and ageing, and to some extent economic cycles. However, there is still considerable value in thinking about how relevant indicators might point to the regeneration and overall well-being of Māori communities. In this paper we present an exploratory framework that links Durie’s Te Pae Mahutonga model of Māori well-being to the measurement of community capital. We use Te Pae Mahutonga as the basis for developing a number of key indicators for understanding Māori well-being in the regions and apply the framework and indicators to three regional settlements in Aotearoa New Zealand: Pōkeno, Huntly and Ōpōtiki.

text: Te Pae Mahutonga and the measurement of community capital in regional Aotearoa New Zealand Regionally, iwi and hapū have limited influence over structural changes such as population decline, proximity to labour markets and ageing, and to some extent economic cycles. However, there is still considerable value in thinking about how relevant indicators might point to the regeneration and overall well-being of Māori communities. In this paper we present an exploratory framework that links Durie’s Te Pae Mahutonga model of Māori well-being to the measurement of community capital. We use Te Pae Mahutonga as the basis for developing a number of key indicators for understanding Māori well-being in the regions and apply the framework and indicators to three regional settlements in Aotearoa New Zealand: Pōkeno, Huntly and Ōpōtiki.

year: 2018