title: Predicting Recidivism in Sex Offenders Using the SVR-20: The Contribution of Age-at-release

authors: Barbaree, Howard E.

subjects: sex offender

abstract: Sex offenders (N = 468) were released from custody and recidivism outcome was recorded. The Sexual Violence Risk-20 (SVR-20) was scored for each offender and the relationship between age-at-release and SVR-20 item and total scores was examined. SVR-20 total scores were not correlated with age-at-release (r = .-057). SVR-20 scores were combined with a score representing the age of the offender at their release from custody. On the basis of ROC analysis, predictive accuracy was significantly enhanced when age-atrelease was included in the risk score. We suggest that the SVR-20, and perhaps other similar risk instruments, could be improved by including age-at-release information. We discuss the possibility that the advantage obtained by empirical actuarial instruments may be due in part to their close relation with age-at-release.

text: Predicting Recidivism in Sex Offenders Using the SVR-20: The Contribution of Age-at-release Sex offenders (N = 468) were released from custody and recidivism outcome was recorded. The Sexual Violence Risk-20 (SVR-20) was scored for each offender and the relationship between age-at-release and SVR-20 item and total scores was examined. SVR-20 total scores were not correlated with age-at-release (r = .-057). SVR-20 scores were combined with a score representing the age of the offender at their release from custody. On the basis of ROC analysis, predictive accuracy was significantly enhanced when age-atrelease was included in the risk score. We suggest that the SVR-20, and perhaps other similar risk instruments, could be improved by including age-at-release information. We discuss the possibility that the advantage obtained by empirical actuarial instruments may be due in part to their close relation with age-at-release.

year: 2008

title: Synthesis and Characterisation of Cycloaurated Gold(III) Complexes with Bidentate (O,O), (N,S) and (S,S) Chelating Ligands

authors: Smith, Tiffany Sharee

subjects: Cycloaurated Gold(III) Complexes

abstract: The reaction of C,N-coordinated gold(III) dihalides; BpAuCl₂ (Bp = 2 benzylpyridyl), AnpAuCl₂ (Anp = 2 anilinopyridyl) and TypAuCl₂ (Typ = 2 tolylpyridyl) with catecholate ligands in hot methanol and trimethylamine produced metallacycles with structural isomers of the general formula (C,N)Au{O,O}. Similarly, BpAuCl₂ and AnpAuCl₂ were reacted with thiourea ligands to form complexes giving high yield and good purity with the general formula (C,N)Au{PhNCSNR₂}+, by means of the addition of BPh₄- for precipitation. X-ray crystal structures of the compounds [AnpAu{PhNCSNMe₂}]BPh₄ and [AnpAu{PhNCSNCy₂}]BPh₄ confirmed the coordination of the thiourea to the gold centre through the N and S atoms. In both cases the geometry around the gold atom is square-planar with complex [AnpAu{PhNCSNCy₂}]BPh₄ showing a slightly more puckered conformation than [AnpAu{PhNCSNMe₂}]BPh₄ due to the sterically bulky cyclohexyl groups attached. Some thiourea derivatives were tested against P388 murine leukaemia cells with complex [AnpAu{PhNCSNHPh}]BPh₄ showing promising anti-tumour activity.

When thiourea ligands were replaced by dithiophosphinate and dithiophosphate ligands the reaction proceeded at room temperature without the need for the presence of a base. Relatively low yields of impure metallacycles with the general formula (C,N)Au{S₂PR₂}+ were obtained on the addition of BPh₄- or BF₄-. Attempts to improve purity by varying batches of starting materials, anion and solvents used were unsuccessful. X-ray crystal data from a single crystal of [(C,N)Au{S₂PPh₂}]BPh₄ shows the reduction of gold(III) to gold(I) forming a known polymeric gold(I) dithiophosphinate complex. In order to extend this study the synthesis of complexes with the general formula R₂PS₂AuCl₂ was attempted, but no new compounds were characterised.

Where possible, all new compounds reported in this thesis were characterised by ES-MS, IR, NMR, melting point and micro-elemental analysis.

text: Synthesis and Characterisation of Cycloaurated Gold(III) Complexes with Bidentate (O,O), (N,S) and (S,S) Chelating Ligands The reaction of C,N-coordinated gold(III) dihalides; BpAuCl₂ (Bp = 2 benzylpyridyl), AnpAuCl₂ (Anp = 2 anilinopyridyl) and TypAuCl₂ (Typ = 2 tolylpyridyl) with catecholate ligands in hot methanol and trimethylamine produced metallacycles with structural isomers of the general formula (C,N)Au{O,O}. Similarly, BpAuCl₂ and AnpAuCl₂ were reacted with thiourea ligands to form complexes giving high yield and good purity with the general formula (C,N)Au{PhNCSNR₂}+, by means of the addition of BPh₄- for precipitation. X-ray crystal structures of the compounds [AnpAu{PhNCSNMe₂}]BPh₄ and [AnpAu{PhNCSNCy₂}]BPh₄ confirmed the coordination of the thiourea to the gold centre through the N and S atoms. In both cases the geometry around the gold atom is square-planar with complex [AnpAu{PhNCSNCy₂}]BPh₄ showing a slightly more puckered conformation than [AnpAu{PhNCSNMe₂}]BPh₄ due to the sterically bulky cyclohexyl groups attached. Some thiourea derivatives were tested against P388 murine leukaemia cells with complex [AnpAu{PhNCSNHPh}]BPh₄ showing promising anti-tumour activity.

When thiourea ligands were replaced by dithiophosphinate and dithiophosphate ligands the reaction proceeded at room temperature without the need for the presence of a base. Relatively low yields of impure metallacycles with the general formula (C,N)Au{S₂PR₂}+ were obtained on the addition of BPh₄- or BF₄-. Attempts to improve purity by varying batches of starting materials, anion and solvents used were unsuccessful. X-ray crystal data from a single crystal of [(C,N)Au{S₂PPh₂}]BPh₄ shows the reduction of gold(III) to gold(I) forming a known polymeric gold(I) dithiophosphinate complex. In order to extend this study the synthesis of complexes with the general formula R₂PS₂AuCl₂ was attempted, but no new compounds were characterised.

Where possible, all new compounds reported in this thesis were characterised by ES-MS, IR, NMR, melting point and micro-elemental analysis.

year: 2012

title: Context counts : leading educational reform in New Zealand secondary schools

authors: Morrison, Michele

subjects: context

abstract: Educational leadership and organisational literature is replete with syntheses of effective leader behaviours, change sequences and reform models, yet few studies explore the nuanced manner in which individual leaders make sense of and respond to the dynamic influences shaping their thinking and practice over time. In posing the question, how do principals experience leadership during periods of intentional educational change, this study gains insight into the lived experience of five New Zealand secondary school principals as they lead school wide implementation of Phase 5 Te Kotahitanga, a reform initiative designed to reduce disparities in the educational achievement of indigenous Māori students through the introduction of a culturally responsive pedagogy of relations. The case narratives arising from a three year dialogue with participants examine the genesis of each principal’s commitment to equity in educational access, opportunity and outcome; their evolving thinking and practice; and the manner in which people and structures within each school field enable and constrain their leadership endeavours. Findings demonstrate that leading counter-hegemonic change is a situated, complex and demanding undertaking, the intensity of which eludes much of the leadership and change literature. Hermeneutic reading of these rich qualitative accounts of lived experience suggests that, far from being detached observers, leaders both embody and are embedded in context. This exposes the shortcomings of literature that dichotomises the two and makes Bourdieu’s lens on practice as a temporal, embodied, discursive and social activity an important heuristic through which to view the holism of change leadership. The implications arising from this study are fourfold: leadership narratives open windows to natural and vicarious meaning making, personal biography is of central rather than peripheral importance, emotional and micropolitical literacy crucial, and professional mentoring a potentially powerful catalyst in building practice wisdom.

text: Context counts : leading educational reform in New Zealand secondary schools Educational leadership and organisational literature is replete with syntheses of effective leader behaviours, change sequences and reform models, yet few studies explore the nuanced manner in which individual leaders make sense of and respond to the dynamic influences shaping their thinking and practice over time. In posing the question, how do principals experience leadership during periods of intentional educational change, this study gains insight into the lived experience of five New Zealand secondary school principals as they lead school wide implementation of Phase 5 Te Kotahitanga, a reform initiative designed to reduce disparities in the educational achievement of indigenous Māori students through the introduction of a culturally responsive pedagogy of relations. The case narratives arising from a three year dialogue with participants examine the genesis of each principal’s commitment to equity in educational access, opportunity and outcome; their evolving thinking and practice; and the manner in which people and structures within each school field enable and constrain their leadership endeavours. Findings demonstrate that leading counter-hegemonic change is a situated, complex and demanding undertaking, the intensity of which eludes much of the leadership and change literature. Hermeneutic reading of these rich qualitative accounts of lived experience suggests that, far from being detached observers, leaders both embody and are embedded in context. This exposes the shortcomings of literature that dichotomises the two and makes Bourdieu’s lens on practice as a temporal, embodied, discursive and social activity an important heuristic through which to view the holism of change leadership. The implications arising from this study are fourfold: leadership narratives open windows to natural and vicarious meaning making, personal biography is of central rather than peripheral importance, emotional and micropolitical literacy crucial, and professional mentoring a potentially powerful catalyst in building practice wisdom.

year: 2019