title: Hydrogen bonding in crystalline alcohol solvates of the platinum(II) sulfido complex [Pt2( -S)2(PPh3)4]

authors: Henderson, William

subjects: Platinum complexes

abstract: Suspension of [Pt₂( -S)₂(PPh₃)₄] in lower alcohols results in recrystallisation, forming yellow to yellow-orange microcrystals of the solvates [Pt₂( -S)₂(PPh₃)₄]•nROH (R = Me, Et, nBu). The di-ethanol solvate was characterised by means of a single-crystal X-ray diffraction study and 1H NMR spectroscopy. The structure consists of an ethanol molecule hydrogen-bonded in an asymmetric bifurcated fashion to the {Pt₂S₂} group, with the second, disordered ethanol molecule involved in a cooperative hydrogen-bonding interaction with the oxygen of the first ethanol. Thermogravimetric analysis shows that the alcohol is relatively easily lost, regenerating orange, unsolvated [Pt₂( -S)₂(PPh₃)₄]. [Pt₂( -S)₂(PPh₃)₄] readily dissolves in hexafluoro-2-propanol, yielding yellow crystals of [Pt₂( -S)₂(PPh₃)₄]•6(CF₃)₂CHOH on evaporation. Characterisation by X-ray diffraction shows that the structure contains a [Pt₂ ( -S)₂(PPh₃)₄] hydrogen-bonded to a single(CF₃)₂CHOH molecule, with the additional (CF₃)₂CHOH molecules forming a discrete hydrogen-bonded pentameric cluster in the crystal.

text: Hydrogen bonding in crystalline alcohol solvates of the platinum(II) sulfido complex [Pt2( -S)2(PPh3)4] Suspension of [Pt₂( -S)₂(PPh₃)₄] in lower alcohols results in recrystallisation, forming yellow to yellow-orange microcrystals of the solvates [Pt₂( -S)₂(PPh₃)₄]•nROH (R = Me, Et, nBu). The di-ethanol solvate was characterised by means of a single-crystal X-ray diffraction study and 1H NMR spectroscopy. The structure consists of an ethanol molecule hydrogen-bonded in an asymmetric bifurcated fashion to the {Pt₂S₂} group, with the second, disordered ethanol molecule involved in a cooperative hydrogen-bonding interaction with the oxygen of the first ethanol. Thermogravimetric analysis shows that the alcohol is relatively easily lost, regenerating orange, unsolvated [Pt₂( -S)₂(PPh₃)₄]. [Pt₂( -S)₂(PPh₃)₄] readily dissolves in hexafluoro-2-propanol, yielding yellow crystals of [Pt₂( -S)₂(PPh₃)₄]•6(CF₃)₂CHOH on evaporation. Characterisation by X-ray diffraction shows that the structure contains a [Pt₂ ( -S)₂(PPh₃)₄] hydrogen-bonded to a single(CF₃)₂CHOH molecule, with the additional (CF₃)₂CHOH molecules forming a discrete hydrogen-bonded pentameric cluster in the crystal.

year: 2008

title: Time-evolving data science and artificial intelligence for Advanced Open Environmental Science (TAIAO) programme

authors: Koh, Yun Sing

subjects: computer science

abstract: New Zealand's unique ecosystems face increasing threats from climate change, impacting biodiversity and posing challenges to safety, livelihoods, and well-being. To tackle these complex issues,  advanced data science and artificial intelligence techniques can provide unique solutions. Currently, in its fourth year of a seven-year program, TAIAO focuses on methods for analyzing environmental datasets. Recognizing this urgency, the open-source TAIAO platform was developed. This platform enables new artificial intelligence research for environmental data and offers an open-access repository to enhance reproducibility in the field. This paper will showcase four environmental case studies, artificial intelligence research, platform implementation details, and future development plans.

text: Time-evolving data science and artificial intelligence for Advanced Open Environmental Science (TAIAO) programme New Zealand's unique ecosystems face increasing threats from climate change, impacting biodiversity and posing challenges to safety, livelihoods, and well-being. To tackle these complex issues,  advanced data science and artificial intelligence techniques can provide unique solutions. Currently, in its fourth year of a seven-year program, TAIAO focuses on methods for analyzing environmental datasets. Recognizing this urgency, the open-source TAIAO platform was developed. This platform enables new artificial intelligence research for environmental data and offers an open-access repository to enhance reproducibility in the field. This paper will showcase four environmental case studies, artificial intelligence research, platform implementation details, and future development plans.

year: 2024

title: Te Kāhui a Kiwa—Advancing Indigenous self determination and wellbeing through trade and can the CPTPP help

authors: Mika, Jason

abstract: This report provides an interim account of a conference held in Hamilton on 28-29 June 2023 called Te Kāhui a Kiwa—Advancing Indigenous self-determination and wellbeing through trade and can the CPTPP help. The conference was hosted by the University of Waikato, working collaboratively with Ngā Toki Whakarururanga, with funding from the Ministry of Foreign Affairs and Trade (Manatū Aorere). University kaumātua (elder) Koro Taki Turner gifted the conference its name. Kāhui refers to an assembly of stars or in this case, people, while Kiwa is short for Te Moana nui a Kiwa—the great ocean of Kiwa, the Pacific Ocean.

text: Te Kāhui a Kiwa—Advancing Indigenous self determination and wellbeing through trade and can the CPTPP help This report provides an interim account of a conference held in Hamilton on 28-29 June 2023 called Te Kāhui a Kiwa—Advancing Indigenous self-determination and wellbeing through trade and can the CPTPP help. The conference was hosted by the University of Waikato, working collaboratively with Ngā Toki Whakarururanga, with funding from the Ministry of Foreign Affairs and Trade (Manatū Aorere). University kaumātua (elder) Koro Taki Turner gifted the conference its name. Kāhui refers to an assembly of stars or in this case, people, while Kiwa is short for Te Moana nui a Kiwa—the great ocean of Kiwa, the Pacific Ocean.

year: 2023-07-13