title: Kinematics of recreational male runners in "super", minimalist and habitual shoes

authors: Hébert-Losier, Kim

subjects: Science & Technology

abstract: We conducted an exploratory analysis to compare running kinematics of 16 male recreational runners wearing Nike Vaporfly 4% (VP4), Saucony Endorphin racing flat (FLAT), and their habitual (OWN) footwear. We also explored potential relationships between kinematic and physiological changes. Runners (age: 33 ± 12 y, V _O2peak: 55.2 ± 4.3 ml · kg−1·min−1) attended 3 sessions after completing an V _ O2peak test in which sagittal plane 3D kinematics at submaximal running speeds (60%, 70% and 80% ʋ V _ O2peak) were collected alongside economy measures. Kinematics were compared using notched boxplots, and between-shoe kinematic differences were plotted against between-shoe economy differences. Across intensities, VP4 involved longer flight times (6.7 to 10.0 ms) and lower stance hip range of motion (~3°), and greater vertical pelvis displacement than FLAT (~0.4 cm). Peak dorsiflexion angles (~2°), ankle range of motion (1.0° to 3.9°), and plantarflexion velocities (11.3 to 89.0 deg · sec−1) were greatest in FLAT and lowest in VP4. Foot-ground angles were smaller in FLAT (2.5° to 3.6°). Select kinematic variables were moderately related to economy, with higher step frequencies and longer step lengths in VP4 and FLAT associated with improved economy versus OWN. Footwear changes from OWN altered running kinematics. The most pronounced differences were observed in ankle, spatiotemporal, and foot-ground angle variables.

text: Kinematics of recreational male runners in "super", minimalist and habitual shoes We conducted an exploratory analysis to compare running kinematics of 16 male recreational runners wearing Nike Vaporfly 4% (VP4), Saucony Endorphin racing flat (FLAT), and their habitual (OWN) footwear. We also explored potential relationships between kinematic and physiological changes. Runners (age: 33 ± 12 y, V _O2peak: 55.2 ± 4.3 ml · kg−1·min−1) attended 3 sessions after completing an V _ O2peak test in which sagittal plane 3D kinematics at submaximal running speeds (60%, 70% and 80% ʋ V _ O2peak) were collected alongside economy measures. Kinematics were compared using notched boxplots, and between-shoe kinematic differences were plotted against between-shoe economy differences. Across intensities, VP4 involved longer flight times (6.7 to 10.0 ms) and lower stance hip range of motion (~3°), and greater vertical pelvis displacement than FLAT (~0.4 cm). Peak dorsiflexion angles (~2°), ankle range of motion (1.0° to 3.9°), and plantarflexion velocities (11.3 to 89.0 deg · sec−1) were greatest in FLAT and lowest in VP4. Foot-ground angles were smaller in FLAT (2.5° to 3.6°). Select kinematic variables were moderately related to economy, with higher step frequencies and longer step lengths in VP4 and FLAT associated with improved economy versus OWN. Footwear changes from OWN altered running kinematics. The most pronounced differences were observed in ankle, spatiotemporal, and foot-ground angle variables.

year: 2022-06-15

title: Cycloaurated gold(III) complexes with monoanionic thiourea ligands

authors: Smith, Tiffany Sharee

subjects: gold complexes

abstract: Using a simple one-pot procedure, reaction of cycloaurated gold(III) dihalide complexes [LAuCl₂] (L = 2-benzylpyridyl, 2-anilinopyridyl) with trisubstituted thioureas PhNHC(S)NR₂ (R = Me, Cy) and Me3N in methanol, followed by addition of excess NaBPh₄ gave the salts [Lau{SC(-NR₂)NPh}]⁺BPH₄⁻ containing N,S-chelated thiourea monoanion ligands. The compounds were obtained in good yields, and were characterised by ESI MS, elemental microanalysis and in two cases by X-ray structure determinations. The series of complexes was extended by additional microscale reactions of LAuCl₂ complexes (L = 2-benzylpyridyl, 2-anilinopyridyl, 2-benzoylpyridyl or picolinamide) with a wide range of trisubstituted thioureas, with products identified by ESI MS.

text: Cycloaurated gold(III) complexes with monoanionic thiourea ligands Using a simple one-pot procedure, reaction of cycloaurated gold(III) dihalide complexes [LAuCl₂] (L = 2-benzylpyridyl, 2-anilinopyridyl) with trisubstituted thioureas PhNHC(S)NR₂ (R = Me, Cy) and Me3N in methanol, followed by addition of excess NaBPh₄ gave the salts [Lau{SC(-NR₂)NPh}]⁺BPH₄⁻ containing N,S-chelated thiourea monoanion ligands. The compounds were obtained in good yields, and were characterised by ESI MS, elemental microanalysis and in two cases by X-ray structure determinations. The series of complexes was extended by additional microscale reactions of LAuCl₂ complexes (L = 2-benzylpyridyl, 2-anilinopyridyl, 2-benzoylpyridyl or picolinamide) with a wide range of trisubstituted thioureas, with products identified by ESI MS.

year: 2013-11

title: Memento Mori : Memento Maori – moko and memory

authors: Te Awekotuku, Ngahuia

subjects: tangi

abstract: Moko patterns, mau moko, “wearing ink” is often explained as an act of remembrance, a symbol of honour or success, of grieving or loss. Memento mori, remembering the dead and remembrance of death, pervades the Maori world, and is profoundly expressed in customary practice – haehae, upoko tuhi, and ta moko. These embodied and visceral experiences are described in waiata tangi, in whai korero, in moteatea, in the traditional context, and graphically recorded on the living flesh in our contemporary world. Mau moko celebrates identity, so modern memorial ornamentation mourns and reflects on this in ‘memento mori’; and also reinforces and engages reality in the correspondent notion of ‘memento Maori’; an assertion that claims dominion and understanding across generations, across time, across space.

text: Memento Mori : Memento Maori – moko and memory Moko patterns, mau moko, “wearing ink” is often explained as an act of remembrance, a symbol of honour or success, of grieving or loss. Memento mori, remembering the dead and remembrance of death, pervades the Maori world, and is profoundly expressed in customary practice – haehae, upoko tuhi, and ta moko. These embodied and visceral experiences are described in waiata tangi, in whai korero, in moteatea, in the traditional context, and graphically recorded on the living flesh in our contemporary world. Mau moko celebrates identity, so modern memorial ornamentation mourns and reflects on this in ‘memento mori’; and also reinforces and engages reality in the correspondent notion of ‘memento Maori’; an assertion that claims dominion and understanding across generations, across time, across space.

year: 2009-11