title: The Characteristics and Impacts of Landfill Leachate from Horotiu, New Zealand and Maseru, Lesotho: A Comparative Study

authors: Mohobane, Thabiso

subjects: leachate

abstract: Landfills are a potential pollution threat to both ground and surface water resources. This study focuses on two landfills, the Horotiu municipal waste landfill, near Hamilton, New Zealand, and the Maseru landfill in Lesotho. The Horotiu landfill is located less than 50 metres from the Waikato River and also sits on a shallow (lt;lm to water table) aquifer.  In Lesotho, the Maseru landfill is 4 km from a river and 2 km from a water reservoir and rests on a huge aquifer. Over 5000 people depend on groundwater in the area between the landfill and the river.  The objectives of my study were to: 1. compare and contrast conditions, management, and potential environmental impacts of the Horotiu and Maseru landfills; 2. evaluate the potential for groundwater contamination as the result of leachate migration; and 3. investigate the chemical characteristics of the landfill leachates and the impacts of the landfills on groundwater quality. 

The Horotiu study was based on the leachate and groundwater quality monitoring data obtained from the Hamilton City Council. Samples were collected every three months from 1991-2006 and analysed for about 30 chemical parameters. The data for the Maseru landfill consisted of groundwater quality collected by the author during July-September 2007 and borehole pumping data obtained from the Department of Water Affairs, in Lesotho. 

At Horotiu results indicate that the leachate had high concentrations of: NH4-N (630 mg/l), TOC (405 mg/l), BOD (126 mg/l), and COD (1289 mg/l), while heavy metals were in low concentrations (lt;0.1mg/l).   Leachate quality was found to change with time and with rainfall. Groundwater samples obtained from the landfill boreholes indicated that the Horotiu landfill had an influence in the quality of groundwater. Groundwater at the down-slope side of the landfill had higher concentrations of all chemical parameters, except for NO3-N, SO4-2 and Reactive P, than the groundwater on the upstream side. The mean groundwater quality at Horotiu was within New Zealand drinking water standards though some standards were exceeded by some individual samples.  

In the Maseru landfill, the borehole water had high concentrations of chemical parameters such as EC (1580 μS/cm) and Chloride (190 mg/l), compared to the national average of 250 μS/cm and 28 mg/l. The Maseru landfill groundwater quality was within the WHO drinking water standard for all analysed chemical constituents, except lead. 

Groundwater beneath both landfills was influenced by leachate but the impacts are currently not at an alarming stage, for analysed chemical parameters. At Maseru introduction of landfill linings has potential to reduce the effect of leachate on groundwater.

text: The Characteristics and Impacts of Landfill Leachate from Horotiu, New Zealand and Maseru, Lesotho: A Comparative Study Landfills are a potential pollution threat to both ground and surface water resources. This study focuses on two landfills, the Horotiu municipal waste landfill, near Hamilton, New Zealand, and the Maseru landfill in Lesotho. The Horotiu landfill is located less than 50 metres from the Waikato River and also sits on a shallow (lt;lm to water table) aquifer.  In Lesotho, the Maseru landfill is 4 km from a river and 2 km from a water reservoir and rests on a huge aquifer. Over 5000 people depend on groundwater in the area between the landfill and the river.  The objectives of my study were to: 1. compare and contrast conditions, management, and potential environmental impacts of the Horotiu and Maseru landfills; 2. evaluate the potential for groundwater contamination as the result of leachate migration; and 3. investigate the chemical characteristics of the landfill leachates and the impacts of the landfills on groundwater quality. 

The Horotiu study was based on the leachate and groundwater quality monitoring data obtained from the Hamilton City Council. Samples were collected every three months from 1991-2006 and analysed for about 30 chemical parameters. The data for the Maseru landfill consisted of groundwater quality collected by the author during July-September 2007 and borehole pumping data obtained from the Department of Water Affairs, in Lesotho. 

At Horotiu results indicate that the leachate had high concentrations of: NH4-N (630 mg/l), TOC (405 mg/l), BOD (126 mg/l), and COD (1289 mg/l), while heavy metals were in low concentrations (lt;0.1mg/l).   Leachate quality was found to change with time and with rainfall. Groundwater samples obtained from the landfill boreholes indicated that the Horotiu landfill had an influence in the quality of groundwater. Groundwater at the down-slope side of the landfill had higher concentrations of all chemical parameters, except for NO3-N, SO4-2 and Reactive P, than the groundwater on the upstream side. The mean groundwater quality at Horotiu was within New Zealand drinking water standards though some standards were exceeded by some individual samples.  

In the Maseru landfill, the borehole water had high concentrations of chemical parameters such as EC (1580 μS/cm) and Chloride (190 mg/l), compared to the national average of 250 μS/cm and 28 mg/l. The Maseru landfill groundwater quality was within the WHO drinking water standard for all analysed chemical constituents, except lead. 

Groundwater beneath both landfills was influenced by leachate but the impacts are currently not at an alarming stage, for analysed chemical parameters. At Maseru introduction of landfill linings has potential to reduce the effect of leachate on groundwater.

year: 2008

title: Achieving reliable and repeatable electrochemical impedance spectroscopy of rechargeable batteries at extra-low frequencies

authors: Dunn, Christopher

abstract: There is a need for techniques for efficient and accurate measurement of the impedance of rechargeable batteries at extra-low frequencies (ELFs, of the order of microhertz), as these reflect real usage and cycling patterns, and their importance in fractional battery circuit modeling is becoming increasingly apparent. Major impediments include the time required to perform such measurements and “drift” in impedance values when measurements are taken from the same battery at different times. Moreover, commercial impedance analyzers are generally unable to measure at these frequencies. We describe here our use of programmable two-quadrant power supplies to deliver multiple small-signal measurement tones in the presence of large-signal “working” currents, and our use of these data to generate impedance measurements with good precision and in reasonable time. The improvement in the quality of electrochemical impedance spectroscopy (EIS) data is verified through root-mean-square error (RMSE) when fitting equivalent-circuit models (ECMs).

text: Achieving reliable and repeatable electrochemical impedance spectroscopy of rechargeable batteries at extra-low frequencies There is a need for techniques for efficient and accurate measurement of the impedance of rechargeable batteries at extra-low frequencies (ELFs, of the order of microhertz), as these reflect real usage and cycling patterns, and their importance in fractional battery circuit modeling is becoming increasingly apparent. Major impediments include the time required to perform such measurements and “drift” in impedance values when measurements are taken from the same battery at different times. Moreover, commercial impedance analyzers are generally unable to measure at these frequencies. We describe here our use of programmable two-quadrant power supplies to deliver multiple small-signal measurement tones in the presence of large-signal “working” currents, and our use of these data to generate impedance measurements with good precision and in reasonable time. The improvement in the quality of electrochemical impedance spectroscopy (EIS) data is verified through root-mean-square error (RMSE) when fitting equivalent-circuit models (ECMs).

year: 2022

title: Te Awa Tupua (Whanganui river claims settlement) Bill – the endless quest for justice

authors: Te Aho, Linda

abstract: Linda Te Aho continues her review of the new legal framework for Te Awa Tupua (the Whanganui River system) as part of the settlement of historical claims by Whanganui iwi about the Whanganui River.

text: Te Awa Tupua (Whanganui river claims settlement) Bill – the endless quest for justice Linda Te Aho continues her review of the new legal framework for Te Awa Tupua (the Whanganui River system) as part of the settlement of historical claims by Whanganui iwi about the Whanganui River.

year: 2016-08