title: An eco-profile of thermoplastic protein derived from blood meal Part 1: allocation issues

authors: Bier, James Michael

subjects: Allocation

abstract: Purpose
A renewable thermoplastic called Novatein Thermoplastic Protein (NTP) has been developed from blood meal—a low-value by-product of the meat processing industry. The aim of this research was to develop a non-renewable energy and greenhouse gas emission eco-profile for cradle to gate production of NTP. Environmental impacts of supplying blood meal as a raw material were investigated using different allocation methods for farming and blood meal production. These included mass, economic, treating low-value by-products as waste and system expansion by substitution. In part 2, the entire system will be analysed on a cradle to gate basis and include the production of thermoplastic (NTP).
Methods
A theoretical NTP production facility was analysed for non-renewable primary energy use and greenhouse gas emissions. Data for feedstocks and process steps were obtained from published papers, government agency reports and engineering models. Mass and economic allocation models treating low-value by-products as waste and substitution were applied, and a sensitivity analysis was used to evaluate the impact of different methods of allocation on environmental impact.
Results and discussion
Non-renewable energy use in blood meal production varied between 5 (substitution) and 38 MJ (simple mass allocation) per kg of NTP. Greenhouse gas emissions varied between 0.4 (substitution), or even less if the biogenic carbon content is considered a credit, and 14 kg (mass allocation) CO2e per kg NTP.
Conclusions
It was concluded that both mass allocation and a waste assumption should be considered for the cradle to gate system. Mass allocation is common in other attributional studies and allows for a more transparent comparison. The most appropriate treatment of allocation in an attributional profile was to consider blood as a waste with regard to farming and meat processing, but include blood drying. This takes into account the motivations for farming and meat processing, but also recognises that there are other treatment options for blood that do not produce blood meal used in manufacturing NTP. This would allow NTP to be compared to other bioplastics as well as identifying hot spots in its cradle to gate production. It was also anticipated that results may be adapted in future cradle to grave assessments as product systems are developed.

text: An eco-profile of thermoplastic protein derived from blood meal Part 1: allocation issues Purpose
A renewable thermoplastic called Novatein Thermoplastic Protein (NTP) has been developed from blood meal—a low-value by-product of the meat processing industry. The aim of this research was to develop a non-renewable energy and greenhouse gas emission eco-profile for cradle to gate production of NTP. Environmental impacts of supplying blood meal as a raw material were investigated using different allocation methods for farming and blood meal production. These included mass, economic, treating low-value by-products as waste and system expansion by substitution. In part 2, the entire system will be analysed on a cradle to gate basis and include the production of thermoplastic (NTP).
Methods
A theoretical NTP production facility was analysed for non-renewable primary energy use and greenhouse gas emissions. Data for feedstocks and process steps were obtained from published papers, government agency reports and engineering models. Mass and economic allocation models treating low-value by-products as waste and substitution were applied, and a sensitivity analysis was used to evaluate the impact of different methods of allocation on environmental impact.
Results and discussion
Non-renewable energy use in blood meal production varied between 5 (substitution) and 38 MJ (simple mass allocation) per kg of NTP. Greenhouse gas emissions varied between 0.4 (substitution), or even less if the biogenic carbon content is considered a credit, and 14 kg (mass allocation) CO2e per kg NTP.
Conclusions
It was concluded that both mass allocation and a waste assumption should be considered for the cradle to gate system. Mass allocation is common in other attributional studies and allows for a more transparent comparison. The most appropriate treatment of allocation in an attributional profile was to consider blood as a waste with regard to farming and meat processing, but include blood drying. This takes into account the motivations for farming and meat processing, but also recognises that there are other treatment options for blood that do not produce blood meal used in manufacturing NTP. This would allow NTP to be compared to other bioplastics as well as identifying hot spots in its cradle to gate production. It was also anticipated that results may be adapted in future cradle to grave assessments as product systems are developed.

year: 2011

title: Rubidium-templated bowl-shaped isopolyoxoantimonates [RbH₁₁˗ₓ(RSb)₁₄O₃₄]ₓ˗ derived from arylstibonic acids

authors: Nicholson, Brian K.

subjects: Polyoxometalates

abstract: Arylstibonic acids, RSbO₃H₂ (R = p-MeC₆H₄- or p-ClC₆H₄-) when neutralised in the presence of Rb⁺ give isopolyoxometalates derived from [RbH₁₁(RSb) ₁₄O₃₄]. The X-ray crystal structures of four examples were determined and all gave the same basic framework with a bowl-shaped Sb14 polyhedron cradling the Rb⁺ in an 11-coordinate embrace. All were further linked into chains in the lattice by an intermolecular interaction involving a second Rb⁺, coordinated to three O atoms of one polyoxometalate and to an aryl group of an adjacent unit via an η⁶ interaction. One example has the same basic structure but with one framework O atom replaced by a Br.

text: Rubidium-templated bowl-shaped isopolyoxoantimonates [RbH₁₁˗ₓ(RSb)₁₄O₃₄]ₓ˗ derived from arylstibonic acids Arylstibonic acids, RSbO₃H₂ (R = p-MeC₆H₄- or p-ClC₆H₄-) when neutralised in the presence of Rb⁺ give isopolyoxometalates derived from [RbH₁₁(RSb) ₁₄O₃₄]. The X-ray crystal structures of four examples were determined and all gave the same basic framework with a bowl-shaped Sb14 polyhedron cradling the Rb⁺ in an 11-coordinate embrace. All were further linked into chains in the lattice by an intermolecular interaction involving a second Rb⁺, coordinated to three O atoms of one polyoxometalate and to an aryl group of an adjacent unit via an η⁶ interaction. One example has the same basic structure but with one framework O atom replaced by a Br.

year: 2013

title: Talking About Race and Positionality in Psychology: Asians as Tangata Tiriti

authors: Tan, Kyle K. H.

subjects: tangata whenua

abstract: The article discusses the dominance of Western, educated, industrialized, rich, and democratic (WEIRD) perspectives in the field of psychology in Aotearoa New Zealand. This has resulted in a racial hierarchy of knowledge, with Indigenous and culturally diverse epistemologies marginalized. The lack of diversity in the curriculum and the limited representation of non-Pākehā (non-New Zealand European) psychologists in the country have led to calls for a more inclusive environment.

The first perspective proposed is to understand Asians as a racialized group with diverse experiences. Asians in Aotearoa come from various backgrounds and face different degrees of racism and acculturation. The notion of 'Asian' may be used to marginalize the interests of Māori, perpetuating institutional racism. The concept of 'Asianisations' describes different forms of racial marginalization experienced by Asians in the country.

The second perspective emphasizes the positionality of Asians as tangata Tiriti (people of the Treaty). Te Tiriti o Waitangi, the Treaty between the British Crown and Māori chiefs, is seen as granting tangata Tiriti equal rights and privileges alongside Pākehā and Māori. As tangata Tiriti, Asians have a responsibility to uphold Tiriti principles, which include partnership, active protection, equity, and options to address Māori inequities. Asian psychologists can engage in culturally safe care for Māori clients and collaborate with and empower Māori leadership in research.

The article highlights the need for Asian psychologists to reflect on their positionality, power structures, and biases within the discipline and society. It encourages them to challenge the dominance of WEIRD psychology and work towards decolonizing the field. By doing so, they can contribute to the flourishing of Kaupapa Māori psychology and develop culturally informed practices that draw on the richness of Asian cultures.

text: Talking About Race and Positionality in Psychology: Asians as Tangata Tiriti The article discusses the dominance of Western, educated, industrialized, rich, and democratic (WEIRD) perspectives in the field of psychology in Aotearoa New Zealand. This has resulted in a racial hierarchy of knowledge, with Indigenous and culturally diverse epistemologies marginalized. The lack of diversity in the curriculum and the limited representation of non-Pākehā (non-New Zealand European) psychologists in the country have led to calls for a more inclusive environment.

The first perspective proposed is to understand Asians as a racialized group with diverse experiences. Asians in Aotearoa come from various backgrounds and face different degrees of racism and acculturation. The notion of 'Asian' may be used to marginalize the interests of Māori, perpetuating institutional racism. The concept of 'Asianisations' describes different forms of racial marginalization experienced by Asians in the country.

The second perspective emphasizes the positionality of Asians as tangata Tiriti (people of the Treaty). Te Tiriti o Waitangi, the Treaty between the British Crown and Māori chiefs, is seen as granting tangata Tiriti equal rights and privileges alongside Pākehā and Māori. As tangata Tiriti, Asians have a responsibility to uphold Tiriti principles, which include partnership, active protection, equity, and options to address Māori inequities. Asian psychologists can engage in culturally safe care for Māori clients and collaborate with and empower Māori leadership in research.

The article highlights the need for Asian psychologists to reflect on their positionality, power structures, and biases within the discipline and society. It encourages them to challenge the dominance of WEIRD psychology and work towards decolonizing the field. By doing so, they can contribute to the flourishing of Kaupapa Māori psychology and develop culturally informed practices that draw on the richness of Asian cultures.

year: 2023-07-24