title: Māori Psychology Workforce & Māori-Focussed Course Content Review

authors: Waitoki, Waikaremoana

abstract: The Ministry of Health (2014) acknowledges that inaccurate and unreliable workforce data collections have been an issue for some time. This is a particular issue for the psychology workforce, with there being no single data set able to accurately and reliably describe the psychology workforce in detail. The annual psychology workforce survey was discontinued post 2010, although District Health Board (DHB) Shared Services does provide a dataset pertaining to the DHB psychology workforce. This report details the paper presents data relating to the: Current Māori psychology workforce; and describes the inclusion of Māori focused content within university psychology department courses.

text: Māori Psychology Workforce & Māori-Focussed Course Content Review The Ministry of Health (2014) acknowledges that inaccurate and unreliable workforce data collections have been an issue for some time. This is a particular issue for the psychology workforce, with there being no single data set able to accurately and reliably describe the psychology workforce in detail. The annual psychology workforce survey was discontinued post 2010, although District Health Board (DHB) Shared Services does provide a dataset pertaining to the DHB psychology workforce. This report details the paper presents data relating to the: Current Māori psychology workforce; and describes the inclusion of Māori focused content within university psychology department courses.

year: 2015

title: Paremias xeocosmolóxicas de predición do tempo en galego e maorí (Geocosmologic paroemias of weather prediction in Galician and Maori)

authors: Lopez-Fernandez, Laura

abstract: This comparative study collects phraseological units -dictons- (Rodegem 1984 e Sevilla Muñoz 1988; 1992) related to the semantic field of weather forecast from two cultures, which have not been in contact, and which are located in the antipodes of the planet: Galician and Maori. The methodology used utilizes a diachronic analysis (although not diastratic), of geocosmological proverbs, that can be or not in use nowadays, which include dictons about atmospheric phenomena, observation of the stars and star lore, and weather forecast through observation of animals, especially birds. The dictons collected in Maori do not come from informants but from the few books and digital sources available at the moment and this represents only a fragment of their traditional oral culture, thought and legacy of the different iwis. The collected dictons in Galician have been collected from a variety of digital corpus and resources.

text: Paremias xeocosmolóxicas de predición do tempo en galego e maorí (Geocosmologic paroemias of weather prediction in Galician and Maori) This comparative study collects phraseological units -dictons- (Rodegem 1984 e Sevilla Muñoz 1988; 1992) related to the semantic field of weather forecast from two cultures, which have not been in contact, and which are located in the antipodes of the planet: Galician and Maori. The methodology used utilizes a diachronic analysis (although not diastratic), of geocosmological proverbs, that can be or not in use nowadays, which include dictons about atmospheric phenomena, observation of the stars and star lore, and weather forecast through observation of animals, especially birds. The dictons collected in Maori do not come from informants but from the few books and digital sources available at the moment and this represents only a fragment of their traditional oral culture, thought and legacy of the different iwis. The collected dictons in Galician have been collected from a variety of digital corpus and resources.

year: 2015

title: Quantifying cooperative intermolecular interactions for improved carbon dioxide capture materials

authors: Lane, Joseph R.

subjects: adsorption

abstract: We have optimized the geometry and calculated interaction energies for over 100 different complexes of CO₂ with various combinations of electron accepting (Lewis acid) and electron donating (Lewis base) molecules. We have used the recently developed explicitly correlated coupled cluster singles doubles and perturbative triples [CCSD(T)-F12] methods and the associated VXZ-F12 (where X = D,T,Q) basis sets. We observe only modest changes in the geometric parameters of CO₂ upon complexation, which suggests that the geometry of CO₂  adsorbed in a nanoporous material should be similar to that of CO₂  in gas phase. When CO₂  forms a complex with two Lewis acids via the two electron rich terminal oxygen atoms, the interaction energy is less than twice what would be expected for the same complex involving a single Lewis acid. We consider a series of complexes that exhibit simultaneous CO₂-Lewis acid and CO₂-Lewis base intermolecular interactions, with total interaction energies spanning 14.1–105.9 kJ mol⁻¹. For these cooperative complexes, we find that the total interaction energy is greater than the sum of the interaction energies of the constituent complexes. Furthermore, the intermolecular distances of the cooperative complexes are contracted as compared to the constituent complexes. We suggest that metal-organic-framework or similar nanoporous materials could be designed with adsorption sites specifically tailored for CO₂ to allow cooperative intermolecular interactions, facilitating enhanced CO₂ adsorption.

text: Quantifying cooperative intermolecular interactions for improved carbon dioxide capture materials We have optimized the geometry and calculated interaction energies for over 100 different complexes of CO₂ with various combinations of electron accepting (Lewis acid) and electron donating (Lewis base) molecules. We have used the recently developed explicitly correlated coupled cluster singles doubles and perturbative triples [CCSD(T)-F12] methods and the associated VXZ-F12 (where X = D,T,Q) basis sets. We observe only modest changes in the geometric parameters of CO₂ upon complexation, which suggests that the geometry of CO₂  adsorbed in a nanoporous material should be similar to that of CO₂  in gas phase. When CO₂  forms a complex with two Lewis acids via the two electron rich terminal oxygen atoms, the interaction energy is less than twice what would be expected for the same complex involving a single Lewis acid. We consider a series of complexes that exhibit simultaneous CO₂-Lewis acid and CO₂-Lewis base intermolecular interactions, with total interaction energies spanning 14.1–105.9 kJ mol⁻¹. For these cooperative complexes, we find that the total interaction energy is greater than the sum of the interaction energies of the constituent complexes. Furthermore, the intermolecular distances of the cooperative complexes are contracted as compared to the constituent complexes. We suggest that metal-organic-framework or similar nanoporous materials could be designed with adsorption sites specifically tailored for CO₂ to allow cooperative intermolecular interactions, facilitating enhanced CO₂ adsorption.

year: 2011