title: Platinum(II), palladium(II) and gold(III) complexes containing 1,1,4-trisubstituted thiosemicarbazide dianion ligands

authors: Henderson, William

subjects: chemistry

abstract: Reactions of cis-[PtCl₂(PPh₃)₂] or [PdCl₂(PPh₃)₂] with Ph₂N---NHC(S)NHPh and excess triethylamine, in refluxing methanol gave the complexes [M{SC(=NPh)NNPh₂}(PPh₃)₂] containing thiosemicarbazide dianion ligands. An analogous gold(III) complex containing the cyclo-aurated anilinopyridine ligand was also synthesised. A single crystal X-ray diffraction study was carried out on the complex [Pt{SC(=NPh)NNPh₂}(PPh₃)₂] which confirmed the bonding of the thiosemicarbazide dianion ligand via sulfur and the nitrogen bearing the NPh₂ substituent. In contrast, reaction of Ph₂N---NHC(S)NHMe with cis-[PtCl₂(PPh₃)₂] and excess triethylamine gave the complex [Pt{SC(=NNPh₂)NMe}(PPh₃)₂], containing a Pt---NMe group, characterized spectroscopically.

text: Platinum(II), palladium(II) and gold(III) complexes containing 1,1,4-trisubstituted thiosemicarbazide dianion ligands Reactions of cis-[PtCl₂(PPh₃)₂] or [PdCl₂(PPh₃)₂] with Ph₂N---NHC(S)NHPh and excess triethylamine, in refluxing methanol gave the complexes [M{SC(=NPh)NNPh₂}(PPh₃)₂] containing thiosemicarbazide dianion ligands. An analogous gold(III) complex containing the cyclo-aurated anilinopyridine ligand was also synthesised. A single crystal X-ray diffraction study was carried out on the complex [Pt{SC(=NPh)NNPh₂}(PPh₃)₂] which confirmed the bonding of the thiosemicarbazide dianion ligand via sulfur and the nitrogen bearing the NPh₂ substituent. In contrast, reaction of Ph₂N---NHC(S)NHMe with cis-[PtCl₂(PPh₃)₂] and excess triethylamine gave the complex [Pt{SC(=NNPh₂)NMe}(PPh₃)₂], containing a Pt---NMe group, characterized spectroscopically.

year: 2003

title: Range imager performance comparison in homodyne and heterodyne operating modes

authors: Conroy, Richard M.

subjects: three-dimensional

abstract: Range imaging cameras measure depth simultaneously for every pixel in a given field of view. In most implementations the basic operating principles are the same. A scene is illuminated with an intensity modulated light source and the reflected signal is sampled using a gain-modulated imager. Previously we presented a unique heterodyne range imaging system that employed a bulky and power hungry image intensifier as the high speed gain-modulation mechanism. In this paper we present a new range imager using an internally modulated image sensor that is designed to operate in heterodyne mode, but can also operate in homodyne mode. We discuss homodyne and heterodyne range imaging, and the merits of the various types of hardware used to implement these systems. Following this we describe in detail the hardware and firmware components of our new ranger. We experimentally compare the two operating modes and demonstrate that heterodyne operation is less sensitive to some of the limitations suffered in homodyne mode, resulting in better linearity and ranging precision characteristics. We conclude by showing various qualitative examples that demonstrate the system’s three-dimensional measurement performance.

text: Range imager performance comparison in homodyne and heterodyne operating modes Range imaging cameras measure depth simultaneously for every pixel in a given field of view. In most implementations the basic operating principles are the same. A scene is illuminated with an intensity modulated light source and the reflected signal is sampled using a gain-modulated imager. Previously we presented a unique heterodyne range imaging system that employed a bulky and power hungry image intensifier as the high speed gain-modulation mechanism. In this paper we present a new range imager using an internally modulated image sensor that is designed to operate in heterodyne mode, but can also operate in homodyne mode. We discuss homodyne and heterodyne range imaging, and the merits of the various types of hardware used to implement these systems. Following this we describe in detail the hardware and firmware components of our new ranger. We experimentally compare the two operating modes and demonstrate that heterodyne operation is less sensitive to some of the limitations suffered in homodyne mode, resulting in better linearity and ranging precision characteristics. We conclude by showing various qualitative examples that demonstrate the system’s three-dimensional measurement performance.

year: 2009

title: The challenges of culture to psychology and post-modern thinking

authors: Waldegrave, Charles

subjects: Maori

abstract: Someone at a workshop in the Waikato once said to us, “You know a Maori, if they want to, can always learn to be a psychologist, but a psychologist can’t learn to be a Maori”. Cultural knowledge may or may not be accompanied by social science knowledge. Cultural knowledge can stand on its own. Those who possess it, and choose to work in the institutions we are associated with, have gifts this country desperately needs. All our organisations require such people, and they need to be properly resourced, have employment security and control over their work. Their own work away from our organisations also requires adequate resourcing. They can heal their own in ways that we will never be able to. They will almost certainly offer the field rich alternative metaphors and meanings that can free us from the tired old medical, biological and social science ones. This also has implications for those in other branches of psychology, including research, experimental and industrial psychology. There is perhaps a unique opportunity for psychologists in this country of Aotearoa/New Zealand to recognise other ways of describing events, which will lead to creative practices and enable the health and welfare resources to get to those who most need them, on their own terms. It would also enable other people, other workers from other cultures to develop new paradigms, and new shifts in our field. This will not lead to the abandonment of social science, but it will enable that body of knowledge, to sit appropriately along side other realms of knowledge such as gender knowledge, and cultural knowledge, without dominating. A new experience for the social scientists, but I suspect a liberating one!

text: The challenges of culture to psychology and post-modern thinking Someone at a workshop in the Waikato once said to us, “You know a Maori, if they want to, can always learn to be a psychologist, but a psychologist can’t learn to be a Maori”. Cultural knowledge may or may not be accompanied by social science knowledge. Cultural knowledge can stand on its own. Those who possess it, and choose to work in the institutions we are associated with, have gifts this country desperately needs. All our organisations require such people, and they need to be properly resourced, have employment security and control over their work. Their own work away from our organisations also requires adequate resourcing. They can heal their own in ways that we will never be able to. They will almost certainly offer the field rich alternative metaphors and meanings that can free us from the tired old medical, biological and social science ones. This also has implications for those in other branches of psychology, including research, experimental and industrial psychology. There is perhaps a unique opportunity for psychologists in this country of Aotearoa/New Zealand to recognise other ways of describing events, which will lead to creative practices and enable the health and welfare resources to get to those who most need them, on their own terms. It would also enable other people, other workers from other cultures to develop new paradigms, and new shifts in our field. This will not lead to the abandonment of social science, but it will enable that body of knowledge, to sit appropriately along side other realms of knowledge such as gender knowledge, and cultural knowledge, without dominating. A new experience for the social scientists, but I suspect a liberating one!

year: 1993