title: A computational study of the oxidation of SO₂ to SO₃ by gas-phase organic oxidants

authors: Kurten, Theo

subjects: chemistry

abstract: We have studied the oxidation of SO₂ to SO₃ by four peroxyradicals and two carbonyl oxides (Criegee intermediates) using both density functional theory, B3LYP, and explicitly correlated coupled cluster theory, CCSD(T)-F12. All the studied peroxyradicals react very slowly with SO₂  due to energy barriers (activation energies) of around 10 kcal/mol or more. We find that water molecules are not able to catalyze these reactions. The reaction of stabilized Criegee intermediates with SO₂  is predicted to be fast, as the transition states for these oxidation reactions are below the free reactants in energy. The atmospheric relevance of these reactions depends on the lifetimes of the Criegee intermediates, which, at present, is highly uncertain.

text: A computational study of the oxidation of SO₂ to SO₃ by gas-phase organic oxidants We have studied the oxidation of SO₂ to SO₃ by four peroxyradicals and two carbonyl oxides (Criegee intermediates) using both density functional theory, B3LYP, and explicitly correlated coupled cluster theory, CCSD(T)-F12. All the studied peroxyradicals react very slowly with SO₂  due to energy barriers (activation energies) of around 10 kcal/mol or more. We find that water molecules are not able to catalyze these reactions. The reaction of stabilized Criegee intermediates with SO₂  is predicted to be fast, as the transition states for these oxidation reactions are below the free reactants in energy. The atmospheric relevance of these reactions depends on the lifetimes of the Criegee intermediates, which, at present, is highly uncertain.

year: 2011

title: Conscious enterprise emergence: Shared value creation through expanded conscious awareness

authors: Pavlovich, Kathryn

subjects: conscious enterprise

abstract: We propose conscious awareness as a mechanism for creating "shared value"; a form of value that Porter describes as putting social and community needs before profit. We explore the mechanism empirically in an entrepreneurial context and find that spiritual practices increase conscious awareness which, in turn, shapes entrepreneurial intentions and venture characteristics focused on shared value.

text: Conscious enterprise emergence: Shared value creation through expanded conscious awareness We propose conscious awareness as a mechanism for creating "shared value"; a form of value that Porter describes as putting social and community needs before profit. We explore the mechanism empirically in an entrepreneurial context and find that spiritual practices increase conscious awareness which, in turn, shapes entrepreneurial intentions and venture characteristics focused on shared value.

year: 2013

title: Site-specific performance rituals in the Anthropocene

authors: Claus, Johanna

abstract: In this creative practice PhD, I investigated site-specific performance rituals in the Anthropocene. Driven by the urge to respond to the challenges of the current time, I examined how different seasonal rituals might be expressed in specific sites in Aotearoa, New Zealand. Furthermore, including participants from diverse cultural backgrounds, and carrying an awareness of the complexities of colonialism, I analysed insights from key ritual experts to enhance my understanding of ritual practices within the specific socio-cultural and environmental context of Aotearoa. Inspired by critical posthumanist philosophies, I viewed ritual practices through a lens that considered the interconnectedness of technology, culture, and nature, moving beyond essentialist and dualistic tendencies. Inspired by (Haraway, 2007) and Braidotti (2019), I embraced a perspective of ‘staying with the trouble’ and ‘radical hope’ as a strategy to inspire commitments to safeguarding life on Earth amid increasing societal divisions, and environmental disasters.
Working at the intersection of various disciplines, I crafted a qualitative research design that embraced multiple ways of knowing through creative practice research. I gathered insights from four ritual experts grounded in mātauranga Māori or neo-Paganism through in-depth interviews, to comprehend multifaceted and culturally sensitive approaches to ritual practices in Aotearoa. Moreover, the creative investigation of four seasonal performance rituals served as the primary mode of inquiry (Niedderer & Roworth-Stokes, 2007; Skains, 2018). The methods used for these rituals included contemporary performance practices, eco-somatic movement, improvisation, site-specific dance, audience participation, and others.
The rich knowledge gained throughout these investigations is conveyed through the documentation of four seasonal rituals, presented in video works alongside this thesis. The findings are articulated in two empirical chapters, one focusing on the findings and analysis of the expert interviews and the other on the findings and analysis of four performance rituals, revealing nuanced and complex insights into the creation of site-specific performance rituals in the Anthropocene. Navigating site-specific performance practices as an immigrant necessitated continuous critical self-reflection on biases and assumptions, leading to intricate explorations of embodiment, identity, culture, nature, and the more-than-human world within a posthuman context. Operating in the liminal space of this tension alongside performer participants, ritual experts, and audience members yielded the articulation of my findings: a ritual score capable of accommodating the complexities of the Anthropocene.

text: Site-specific performance rituals in the Anthropocene In this creative practice PhD, I investigated site-specific performance rituals in the Anthropocene. Driven by the urge to respond to the challenges of the current time, I examined how different seasonal rituals might be expressed in specific sites in Aotearoa, New Zealand. Furthermore, including participants from diverse cultural backgrounds, and carrying an awareness of the complexities of colonialism, I analysed insights from key ritual experts to enhance my understanding of ritual practices within the specific socio-cultural and environmental context of Aotearoa. Inspired by critical posthumanist philosophies, I viewed ritual practices through a lens that considered the interconnectedness of technology, culture, and nature, moving beyond essentialist and dualistic tendencies. Inspired by (Haraway, 2007) and Braidotti (2019), I embraced a perspective of ‘staying with the trouble’ and ‘radical hope’ as a strategy to inspire commitments to safeguarding life on Earth amid increasing societal divisions, and environmental disasters.
Working at the intersection of various disciplines, I crafted a qualitative research design that embraced multiple ways of knowing through creative practice research. I gathered insights from four ritual experts grounded in mātauranga Māori or neo-Paganism through in-depth interviews, to comprehend multifaceted and culturally sensitive approaches to ritual practices in Aotearoa. Moreover, the creative investigation of four seasonal performance rituals served as the primary mode of inquiry (Niedderer & Roworth-Stokes, 2007; Skains, 2018). The methods used for these rituals included contemporary performance practices, eco-somatic movement, improvisation, site-specific dance, audience participation, and others.
The rich knowledge gained throughout these investigations is conveyed through the documentation of four seasonal rituals, presented in video works alongside this thesis. The findings are articulated in two empirical chapters, one focusing on the findings and analysis of the expert interviews and the other on the findings and analysis of four performance rituals, revealing nuanced and complex insights into the creation of site-specific performance rituals in the Anthropocene. Navigating site-specific performance practices as an immigrant necessitated continuous critical self-reflection on biases and assumptions, leading to intricate explorations of embodiment, identity, culture, nature, and the more-than-human world within a posthuman context. Operating in the liminal space of this tension alongside performer participants, ritual experts, and audience members yielded the articulation of my findings: a ritual score capable of accommodating the complexities of the Anthropocene.

year: 2024-05-27