title: Bioinspired surface modification of mussel shells and their application as a biogenic filler in polypropylene composites

authors: Xu, Jing

abstract: This study explores the potential of mussel shells (MS) as biogenic fillers in polymer composites. The chemical composition and crystal structures of MS were characterised. To improve MS filler dispersion and adhesion within a polypropylene (PP) matrix, three surface modification methods were evaluated: polydopamine (PDA) coating, maleic anhydride-grafted polypropylene (MAPP) modification, and PDA/MAPP co-modification. The PDA coating, inspired by the adhesive properties of mussel foot proteins, successfully functionalized the MS surface, as confirmed by X-ray photoelectron spectroscopy (XPS). Thermodynamic analysis, based on contact angle measurements, revealed that MAPP and PDA/MAPP modifications reduced surface energies and potential energy differences. These changes enhanced filler dispersion and interfacial bonding by increasing hydrophobicity and reducing agglomeration in the PP matrix. Consequently, PP composites with 20% PDA/MAPP-modified MS fillers exhibited a 2.9% increase in tensile strength and a 7.5% increase in flexural strength compared to neat PP. Scanning electron microscopy (SEM) also showed reduced filler-matrix debonding and fewer voids. The proposed mechanism attributes these macroscopic property enhancements to the ability of the PDA coating to facilitate chemical and hydrogen bonding between MS fillers and MAPP.

text: Bioinspired surface modification of mussel shells and their application as a biogenic filler in polypropylene composites This study explores the potential of mussel shells (MS) as biogenic fillers in polymer composites. The chemical composition and crystal structures of MS were characterised. To improve MS filler dispersion and adhesion within a polypropylene (PP) matrix, three surface modification methods were evaluated: polydopamine (PDA) coating, maleic anhydride-grafted polypropylene (MAPP) modification, and PDA/MAPP co-modification. The PDA coating, inspired by the adhesive properties of mussel foot proteins, successfully functionalized the MS surface, as confirmed by X-ray photoelectron spectroscopy (XPS). Thermodynamic analysis, based on contact angle measurements, revealed that MAPP and PDA/MAPP modifications reduced surface energies and potential energy differences. These changes enhanced filler dispersion and interfacial bonding by increasing hydrophobicity and reducing agglomeration in the PP matrix. Consequently, PP composites with 20% PDA/MAPP-modified MS fillers exhibited a 2.9% increase in tensile strength and a 7.5% increase in flexural strength compared to neat PP. Scanning electron microscopy (SEM) also showed reduced filler-matrix debonding and fewer voids. The proposed mechanism attributes these macroscopic property enhancements to the ability of the PDA coating to facilitate chemical and hydrogen bonding between MS fillers and MAPP.

year: 2024-10

title: The World Council of Churches in dialogue with Muslims: Retrospect and prospect

authors: Pratt, Douglas

subjects: World Council of Churches

abstract: The World Council of Churches (WCC) has been involved in a variety of inter-religious dialogue projects and initiatives over many years. Dialogue with other religions—or with the peoples of those religions—is of significance and import, not least because of the value placed upon peaceful co-existence and harmonious inter-communal relations. However, of all bi-lateral endeavours, it is arguably the arena of Christian-Muslim relations which has been, and remains, the most challenging, problematic, and pressing for the Christian community at large—and, complementarily, for the Muslim umma also. This article attempts an overview of development in Christian-Muslim dialogue undertaken under the auspices of the WCC since around the mid-twentieth century. Early explorations, when the prospect of dialogue with Muslims was being canvassed, will be discussed. A significant 1972 consultation will be noted, followed by a review of salient features pertaining to the extension of the field of engagement in Christian-Muslim dialogue, and a note on some difficulties and challenges encountered. A comment on a sequence of regional events undertaken during the 80s will precede a discussion of developments in the clarification of issues that took place during the 90s. Finally, issues and challenges that are evident in the opening years of the third millennium of the Common Era will be briefly touched on.

text: The World Council of Churches in dialogue with Muslims: Retrospect and prospect The World Council of Churches (WCC) has been involved in a variety of inter-religious dialogue projects and initiatives over many years. Dialogue with other religions—or with the peoples of those religions—is of significance and import, not least because of the value placed upon peaceful co-existence and harmonious inter-communal relations. However, of all bi-lateral endeavours, it is arguably the arena of Christian-Muslim relations which has been, and remains, the most challenging, problematic, and pressing for the Christian community at large—and, complementarily, for the Muslim umma also. This article attempts an overview of development in Christian-Muslim dialogue undertaken under the auspices of the WCC since around the mid-twentieth century. Early explorations, when the prospect of dialogue with Muslims was being canvassed, will be discussed. A significant 1972 consultation will be noted, followed by a review of salient features pertaining to the extension of the field of engagement in Christian-Muslim dialogue, and a note on some difficulties and challenges encountered. A comment on a sequence of regional events undertaken during the 80s will precede a discussion of developments in the clarification of issues that took place during the 90s. Finally, issues and challenges that are evident in the opening years of the third millennium of the Common Era will be briefly touched on.

year: 2009

title: Indigenous knowledges in health policy in Aotearoa New Zealand and Saskatchewan Canada: A comparative study

authors: Green, Jane Alison

subjects: Indigenous

abstract: For more than two decades, components of Māori knowledges in the form of Māori words and concepts have been part of health policy in Aotearoa New Zealand. Health policy that engages Māori words and concepts resonates with Māori community values and aspirations and is thought to contribute to the revitalisation of Māori knowledges. Absent from the literature is an examination of this phenomenon; specifically, the socio-political factors that facilitate and limit the engagement of Māori knowledges with health policy. Of the four settler states, only in Aotearoa New Zealand are the knowledges of the Indigenous peoples engaged with health policy. In Saskatchewan, Canada, the First Nations and Métis peoples have engaged their knowledges with federal and provincially funded health programmes and services but not health policy. This study adopts a two-country comparative policy framework to investigate and theorise the historical and contemporary socio-political factors associated with the engagement of Indigenous knowledges in health policy in Aotearoa New Zealand and Saskatchewan, Canada. An adaption is made to the Kaupapa Māori approach so that the complexities of a two-country case study approach are addressed and engagement in health policy as a strategy for knowledge revitalisation is theorised. The study also takes a path less travelled which is to investigate the impact that engagement with health policy has upon the intangible or the ontological aspects of Māori knowledges. Māori describe their knowledges as comprised of tangible and intangible elements, both of which are important. Another adaption is made to the Kaupapa Māori theoretical approach which is to add speculative inquiry. The study argues that speculative inquiry in the form of contemplative, analytical, relational and viscerally aware practices are commonplace in Māori communities. Adding speculative inquiry to an already rich theoretical body that is Kaupapa Māori research provides an opening for other Kaupapa Māori researchers to expand non-empirical inquiry. The study concludes that government policies have had a decimating effect upon Māori, First Nations and Métis knowledges. Moreover, recent reports from commissions and inquiries indicate these knowledges and associated languages continue to decline for a number of reasons, including the impact of contemporary government policies. Health policy, this study asserts, is an uncertain site from which to revitalise Māori, First Nations and Métis knowledges.

text: Indigenous knowledges in health policy in Aotearoa New Zealand and Saskatchewan Canada: A comparative study For more than two decades, components of Māori knowledges in the form of Māori words and concepts have been part of health policy in Aotearoa New Zealand. Health policy that engages Māori words and concepts resonates with Māori community values and aspirations and is thought to contribute to the revitalisation of Māori knowledges. Absent from the literature is an examination of this phenomenon; specifically, the socio-political factors that facilitate and limit the engagement of Māori knowledges with health policy. Of the four settler states, only in Aotearoa New Zealand are the knowledges of the Indigenous peoples engaged with health policy. In Saskatchewan, Canada, the First Nations and Métis peoples have engaged their knowledges with federal and provincially funded health programmes and services but not health policy. This study adopts a two-country comparative policy framework to investigate and theorise the historical and contemporary socio-political factors associated with the engagement of Indigenous knowledges in health policy in Aotearoa New Zealand and Saskatchewan, Canada. An adaption is made to the Kaupapa Māori approach so that the complexities of a two-country case study approach are addressed and engagement in health policy as a strategy for knowledge revitalisation is theorised. The study also takes a path less travelled which is to investigate the impact that engagement with health policy has upon the intangible or the ontological aspects of Māori knowledges. Māori describe their knowledges as comprised of tangible and intangible elements, both of which are important. Another adaption is made to the Kaupapa Māori theoretical approach which is to add speculative inquiry. The study argues that speculative inquiry in the form of contemplative, analytical, relational and viscerally aware practices are commonplace in Māori communities. Adding speculative inquiry to an already rich theoretical body that is Kaupapa Māori research provides an opening for other Kaupapa Māori researchers to expand non-empirical inquiry. The study concludes that government policies have had a decimating effect upon Māori, First Nations and Métis knowledges. Moreover, recent reports from commissions and inquiries indicate these knowledges and associated languages continue to decline for a number of reasons, including the impact of contemporary government policies. Health policy, this study asserts, is an uncertain site from which to revitalise Māori, First Nations and Métis knowledges.

year: 2018