title: A Chemical Investigation of New Zealand Unifloral Honeys

authors: Senanayake, Mahima

subjects: New Zealand Unifloral Honeys

abstract: The diethyl ether-extracted organic compounds of 155 samples of unifloral grade New Zealand kamahi and honeydew honeys, and New Zealand and Norwegian erica honeys, together with a series of active and inactive manuka honeys were analysed using combined gas chromatography/mass spectrometry. It was found that Kamahi honey is characterized by the presence of 2,6-dimethylocta-3,7-diene-2,6-diol, meliracemoic acid, and kamahines A-C and these compounds were typically present at average levels of 31, 14, and 73 mg/kg of honey, respectively. 2,6-Dimethylocta-3,7-diene-2,6-diol was isolated and the structure of this compound was defined using one- and two-dimensional NMR analyses.  

The only recognizably distinct peak present in the honeydew honey profile was indole acetic acid. In this honey, a relatively low to moderate level of indole acetic acid, ranging from 0.9 to 9.1 mg/kg honey was detected.

In the New Zealand erica honey samples, ericinic acid, isoericinic acid isomers (average levels 363 and 34 mg/kg respectively), trans,cis and trans,trans-abscisic acid isomers (average levels 302 and 224 mg/kg respectively) and benzoic acid (average level 6950 mg/kg) were identified as floral marker compounds. Ericinic acid was isolated and the structure of this acid was defined using one-and two-dimensional NMR analyses.

Low levels of ericinic and isoericinic acids (average levels of 1.1 and 0.32 mg/kg respectively) were detected in the Norwegian erica-rich honeys. The results presented here indicate that ericinic and isoericinic acids are likely to be universally present in erica honeys at levels which may range from as low as 1 mg/kg or less, as found in some Norwegian samples, to more than 100 mg/kg in some New Zealand samples.

Two groups, namely a fingerprint pattern which characterized active manuka honeys, and a fingerprint pattern that characterized inactive manuka honeys were identified. Some substances contributing to the GCMS profile were found as marker compounds for the presence of unidentified substances responsible for the UMF activity. A statistically significant correlation was found between a small set of marker compounds (i.e. phenylacetic acid, 2-methoxyacetophenone, 2-methoxybenzoic, phenyllactic, octanedioic, cis-cinnamic, trans-cinnamic, nonanedioic, 4-methoxyphenyllactic and decanedioic acids and methyl syringate) and UMF activity of manuka honey. The best-fit marker compound regression equation (R = 0.92) was obtained for a set of pooled 30 moderate to high activity (UMF gt 14.1) samples. It was shown that the marker compound regression equation is capable of predicting the approximate UMF activity in both active and inactive manuka and kanuka honey samples.

The leaf oil profiles of manuka (L. scoparium) plants that yielded active and inactive manuka honeys were characterized using an adaption of the micro-scale extraction and GC/FID or GC/MS, technique developed by Brophy et al. (1989). Six major groups of volatile (steam distillable) compounds (monoterpenes, sesquiterpene hydrocarbons, oxygenated sesquiterpenes [excluding eudesmols], eudesmols, triketones, and nor-triketones) and 3 groups of non-volatile or semi-volatile compounds (flavonoids, grandiflorone and nor-grandiflorone) were recognized in the leaf oil components. The active manuka honeys do not appear to be derived uniquely, or predominantly, from a single leaf oil chemotype.

text: A Chemical Investigation of New Zealand Unifloral Honeys The diethyl ether-extracted organic compounds of 155 samples of unifloral grade New Zealand kamahi and honeydew honeys, and New Zealand and Norwegian erica honeys, together with a series of active and inactive manuka honeys were analysed using combined gas chromatography/mass spectrometry. It was found that Kamahi honey is characterized by the presence of 2,6-dimethylocta-3,7-diene-2,6-diol, meliracemoic acid, and kamahines A-C and these compounds were typically present at average levels of 31, 14, and 73 mg/kg of honey, respectively. 2,6-Dimethylocta-3,7-diene-2,6-diol was isolated and the structure of this compound was defined using one- and two-dimensional NMR analyses.  

The only recognizably distinct peak present in the honeydew honey profile was indole acetic acid. In this honey, a relatively low to moderate level of indole acetic acid, ranging from 0.9 to 9.1 mg/kg honey was detected.

In the New Zealand erica honey samples, ericinic acid, isoericinic acid isomers (average levels 363 and 34 mg/kg respectively), trans,cis and trans,trans-abscisic acid isomers (average levels 302 and 224 mg/kg respectively) and benzoic acid (average level 6950 mg/kg) were identified as floral marker compounds. Ericinic acid was isolated and the structure of this acid was defined using one-and two-dimensional NMR analyses.

Low levels of ericinic and isoericinic acids (average levels of 1.1 and 0.32 mg/kg respectively) were detected in the Norwegian erica-rich honeys. The results presented here indicate that ericinic and isoericinic acids are likely to be universally present in erica honeys at levels which may range from as low as 1 mg/kg or less, as found in some Norwegian samples, to more than 100 mg/kg in some New Zealand samples.

Two groups, namely a fingerprint pattern which characterized active manuka honeys, and a fingerprint pattern that characterized inactive manuka honeys were identified. Some substances contributing to the GCMS profile were found as marker compounds for the presence of unidentified substances responsible for the UMF activity. A statistically significant correlation was found between a small set of marker compounds (i.e. phenylacetic acid, 2-methoxyacetophenone, 2-methoxybenzoic, phenyllactic, octanedioic, cis-cinnamic, trans-cinnamic, nonanedioic, 4-methoxyphenyllactic and decanedioic acids and methyl syringate) and UMF activity of manuka honey. The best-fit marker compound regression equation (R = 0.92) was obtained for a set of pooled 30 moderate to high activity (UMF gt 14.1) samples. It was shown that the marker compound regression equation is capable of predicting the approximate UMF activity in both active and inactive manuka and kanuka honey samples.

The leaf oil profiles of manuka (L. scoparium) plants that yielded active and inactive manuka honeys were characterized using an adaption of the micro-scale extraction and GC/FID or GC/MS, technique developed by Brophy et al. (1989). Six major groups of volatile (steam distillable) compounds (monoterpenes, sesquiterpene hydrocarbons, oxygenated sesquiterpenes [excluding eudesmols], eudesmols, triketones, and nor-triketones) and 3 groups of non-volatile or semi-volatile compounds (flavonoids, grandiflorone and nor-grandiflorone) were recognized in the leaf oil components. The active manuka honeys do not appear to be derived uniquely, or predominantly, from a single leaf oil chemotype.

year: 2006

title: The sex or the head? Feminine voices and academic women through the work of Hélène Cixous

authors: Locke, Kirsten

subjects: academic writing

abstract: Hélène Cixous is perhaps best known for her paper, ‘The Laugh of the Medusa’ (1976) and her literary contributions outside academia. In this paper, we pick up a lesser known Cixous text, ‘Le Sexe ou la tête?’ that offers an interesting and provocative perspective on the traps associated with being feminine in a masculine environment. As we converse with Cixous, weaving our own words and experiences with hers, we link her work more closely with the feminine in modern-day academia. We suggest that Cixous’s remarks on decapitation and voice offer a way forward for academic women to be; to speak; to recognise the double jeopardy of decapitation in the university; and to use laughter as a strategic, powerful, political act of resistance and subversion against oppressive masculine power structures. We draw on and seek to enact Cixous’s notion of écriture feminine—a disruptive style of writing that provides a mode of being, speaking, and writing that subverts the power of masculine norms in order to be heard and to bring possibilities for change.

text: The sex or the head? Feminine voices and academic women through the work of Hélène Cixous Hélène Cixous is perhaps best known for her paper, ‘The Laugh of the Medusa’ (1976) and her literary contributions outside academia. In this paper, we pick up a lesser known Cixous text, ‘Le Sexe ou la tête?’ that offers an interesting and provocative perspective on the traps associated with being feminine in a masculine environment. As we converse with Cixous, weaving our own words and experiences with hers, we link her work more closely with the feminine in modern-day academia. We suggest that Cixous’s remarks on decapitation and voice offer a way forward for academic women to be; to speak; to recognise the double jeopardy of decapitation in the university; and to use laughter as a strategic, powerful, political act of resistance and subversion against oppressive masculine power structures. We draw on and seek to enact Cixous’s notion of écriture feminine—a disruptive style of writing that provides a mode of being, speaking, and writing that subverts the power of masculine norms in order to be heard and to bring possibilities for change.

year: 2023-06-09

title: Strawmen and the decolonisation of the academy

authors: Tauri, Juan Marcellus

subjects: Social justice

abstract: For this piece I take as my point of departure Biko Agozino’s response to a series of questions posed by a member of the audience, to a panel he was a member of during this time in New Zealand. The panel in question was part of the launch of a new journal, Decolonisation of Criminology and Justice, at AUT University, Auckland in June 2018. Biko was invited to give a speech at the launch of the journal, and participate in a panel discussion on the broad theme of ‘decolonising criminology and criminal justice’.

text: Strawmen and the decolonisation of the academy For this piece I take as my point of departure Biko Agozino’s response to a series of questions posed by a member of the audience, to a panel he was a member of during this time in New Zealand. The panel in question was part of the launch of a new journal, Decolonisation of Criminology and Justice, at AUT University, Auckland in June 2018. Biko was invited to give a speech at the launch of the journal, and participate in a panel discussion on the broad theme of ‘decolonising criminology and criminal justice’.

year: 2019-07-10