title: The digital parrot: Combining context-awareness and semantics to augment memory

authors: Schweer, Andrea

subjects: computer science

abstract: People of all ages and backgrounds are prone to forgetting information, even about their personal experiences. Existing systems to support people in remembering such information either continuously record a person’s experiences or provide means to store and retrieve clearly defined, isolated pieces of data. We propose a new approach: combining context-awareness with semantic information. We believe this approach to be superior to the existing systems in certain types of situations.
This position paper introduces this approach and our own ongoing project, the Digital Parrot.

text: The digital parrot: Combining context-awareness and semantics to augment memory People of all ages and backgrounds are prone to forgetting information, even about their personal experiences. Existing systems to support people in remembering such information either continuously record a person’s experiences or provide means to store and retrieve clearly defined, isolated pieces of data. We propose a new approach: combining context-awareness with semantic information. We believe this approach to be superior to the existing systems in certain types of situations.
This position paper introduces this approach and our own ongoing project, the Digital Parrot.

year: 2007

title: Germanium hydride derivatives of transition metal carbonyls

authors: Christie, Judy A.

abstract: Compounds of the type Fe(CO)₄(GeR₃)₂ containing two different methylgermyl substituents have been prepared and characterised. The preparation was via the exchange reaction

Fe(CO)₄(GeR₃)₂ + [Mn(CO)₅]⁻ → [Fe(CO)₄(GeR₃)]⁻ + Mn(CO)₅(GeR₃)

[Fe(CO)₄(GeR₃)]⁻ + GeXR’₃ → Fe(CO)₄(GeR₃)(GeR’₃)


The compounds characterised were Fe(CO)₄(GeMeH₂) (GeH₃) Fe(CO)₄(GeMe₂H) (GeH₃), Fe(CO)₄ (GeMe₂H) (GeMeH₂), Fe(CO)₄(GeMe₃) (GeH₃) Fe(CO)₄(GeMe₃)(GeMeH₂) and Fe(CO)₄(GeMe₃)(GeMe₂H). Of these, the species Fe(CO)₄(GeMeH₂) (GeH₃) were characterised fully by infrared, proton nmr and mass spectroscopic studies.


The self-reaction 

2Fe(CO)₄(GeR₃)₂ → [Fe(CO)₄(GeR₂)]₂ + 2GeR₄

has also been examined in some detail. The methylgermane was eliminated in preference to GeH₄ and species of the type [Fe(CO)₄(GeH₃)]₂-GeR₂ were also identified in two cases. 

Halogenation of Fe(CO)₄(GeMeH₃) (GeH₃) and Fe(CO)₄(GeMe₂H) (GeH3) was followed by ¹H nmr studies. CCℓ₄ results in the substitution of Ge-H, while HCℓ cleaves Fe-Ge bonds. 

While Fe(CO)₄(GeMe₂H) (GeMeH₂), Fe(CO)₄(GeMe₃) (GeMeH₂) and Fe(CO)₄(GeMe₃) (GeMe₂H) have been prepared, spectroscopic identification of these species is rather tenuous as these samples were found always to be contaminated with either the symmetrically substituted species Fe(CO)₄(GeR₃)₂ and/or products from the self-reaction. 

Mn(CO)₅(GeR₃) species obtained in the above syntheses react with Co₂(CO)₈ to yield the species [Co₃ (CO)₉][Mn(CO)₅]Ge, [Co₂(CO)₇[Mn(CO)₅]GeMe and possibly [Co(CO)₄][Mn(CO)₅]GeMe₂. 

These species were characterised by their infrared and mass spectroscopic properties.

text: Germanium hydride derivatives of transition metal carbonyls Compounds of the type Fe(CO)₄(GeR₃)₂ containing two different methylgermyl substituents have been prepared and characterised. The preparation was via the exchange reaction

Fe(CO)₄(GeR₃)₂ + [Mn(CO)₅]⁻ → [Fe(CO)₄(GeR₃)]⁻ + Mn(CO)₅(GeR₃)

[Fe(CO)₄(GeR₃)]⁻ + GeXR’₃ → Fe(CO)₄(GeR₃)(GeR’₃)


The compounds characterised were Fe(CO)₄(GeMeH₂) (GeH₃) Fe(CO)₄(GeMe₂H) (GeH₃), Fe(CO)₄ (GeMe₂H) (GeMeH₂), Fe(CO)₄(GeMe₃) (GeH₃) Fe(CO)₄(GeMe₃)(GeMeH₂) and Fe(CO)₄(GeMe₃)(GeMe₂H). Of these, the species Fe(CO)₄(GeMeH₂) (GeH₃) were characterised fully by infrared, proton nmr and mass spectroscopic studies.


The self-reaction 

2Fe(CO)₄(GeR₃)₂ → [Fe(CO)₄(GeR₂)]₂ + 2GeR₄

has also been examined in some detail. The methylgermane was eliminated in preference to GeH₄ and species of the type [Fe(CO)₄(GeH₃)]₂-GeR₂ were also identified in two cases. 

Halogenation of Fe(CO)₄(GeMeH₃) (GeH₃) and Fe(CO)₄(GeMe₂H) (GeH3) was followed by ¹H nmr studies. CCℓ₄ results in the substitution of Ge-H, while HCℓ cleaves Fe-Ge bonds. 

While Fe(CO)₄(GeMe₂H) (GeMeH₂), Fe(CO)₄(GeMe₃) (GeMeH₂) and Fe(CO)₄(GeMe₃) (GeMe₂H) have been prepared, spectroscopic identification of these species is rather tenuous as these samples were found always to be contaminated with either the symmetrically substituted species Fe(CO)₄(GeR₃)₂ and/or products from the self-reaction. 

Mn(CO)₅(GeR₃) species obtained in the above syntheses react with Co₂(CO)₈ to yield the species [Co₃ (CO)₉][Mn(CO)₅]Ge, [Co₂(CO)₇[Mn(CO)₅]GeMe and possibly [Co(CO)₄][Mn(CO)₅]GeMe₂. 

These species were characterised by their infrared and mass spectroscopic properties.

year: 1981

title: Replacing medical and social models of disability by a communities-based model of equal access for people of differing abilities: A Māori perspective

authors: Hickey, Huhana

subjects: New Zealand

abstract: I argue here that although the social model of disability which currently prevails in New Zealand is preferable in many ways to the earlier medical model, it is nevertheless based on a largely uni-dimensional concept of society and continues an established tradition of negativity, one that is evident in the ongoing use of the word 'disabled' itself by those who subscribe to the social model. I argue here that the social model of disability should be replaced by a communities-based model of equal access for people of differing abilities, one that is, in the New Zealand context, informed by a further developed Māori model of health and wellbeing proposed by Mason Durie, Te Whare Tapa Whā. This mode is designed in such a way as to accommodate difference and diversity. In the discussion of different models, I use the words 'disabled' and 'disability'; in other contexts, I replace 'disabled people' by 'people of differing abilities'.

text: Replacing medical and social models of disability by a communities-based model of equal access for people of differing abilities: A Māori perspective I argue here that although the social model of disability which currently prevails in New Zealand is preferable in many ways to the earlier medical model, it is nevertheless based on a largely uni-dimensional concept of society and continues an established tradition of negativity, one that is evident in the ongoing use of the word 'disabled' itself by those who subscribe to the social model. I argue here that the social model of disability should be replaced by a communities-based model of equal access for people of differing abilities, one that is, in the New Zealand context, informed by a further developed Māori model of health and wellbeing proposed by Mason Durie, Te Whare Tapa Whā. This mode is designed in such a way as to accommodate difference and diversity. In the discussion of different models, I use the words 'disabled' and 'disability'; in other contexts, I replace 'disabled people' by 'people of differing abilities'.

year: 2006-02