title: New ternary powder metallurgy Ti alloys via eutectoid and isomorphous beta stabilisers additions

authors: Paul, Manpreet

subjects: Mechanical engineering

abstract: A group of new ternary Ti alloys bearing eutectoid and isomorphous beta stabilising elements was created to be manufactured through the conventional powder metallurgy route. The effect of the simultaneous addition of the same amount of Mn and Nb on the manufacturability, properties, and hardening behaviour was investigated. The ternary alloys are composed of the α-Ti and β-Ti phases and have a lamellar microstructure resulting from the slow cooling upon sintering. However, the size of the equiaxed α grains and of the α + β lamellae is monotonically reduced, especially the interlamellar spacing, as the amount of alloying elements increases. Due to their physical properties, Mn enhances and Nb hinders densification during sintering resulting in a decreasing trend of the relative density with the alloying elements content. Consequently, the resistance to plastic deformation increases (UTS, 514–726 MPa), the ductility decreases (elongation, 13.2–2.6%), and the fracture mode changes from intergranular to transgranular. The new ternary alloys share the same hardening mechanism, but the amount of deformation after necking is, generally, higher for lower amounts of Mn and Nb.

text: New ternary powder metallurgy Ti alloys via eutectoid and isomorphous beta stabilisers additions A group of new ternary Ti alloys bearing eutectoid and isomorphous beta stabilising elements was created to be manufactured through the conventional powder metallurgy route. The effect of the simultaneous addition of the same amount of Mn and Nb on the manufacturability, properties, and hardening behaviour was investigated. The ternary alloys are composed of the α-Ti and β-Ti phases and have a lamellar microstructure resulting from the slow cooling upon sintering. However, the size of the equiaxed α grains and of the α + β lamellae is monotonically reduced, especially the interlamellar spacing, as the amount of alloying elements increases. Due to their physical properties, Mn enhances and Nb hinders densification during sintering resulting in a decreasing trend of the relative density with the alloying elements content. Consequently, the resistance to plastic deformation increases (UTS, 514–726 MPa), the ductility decreases (elongation, 13.2–2.6%), and the fracture mode changes from intergranular to transgranular. The new ternary alloys share the same hardening mechanism, but the amount of deformation after necking is, generally, higher for lower amounts of Mn and Nb.

year: 2023-01-20

title: An eco-profile of thermoplastic protein derived from blood meal Part 1: allocation issues

authors: Bier, James Michael

subjects: Allocation

abstract: Purpose
A renewable thermoplastic called Novatein Thermoplastic Protein (NTP) has been developed from blood meal—a low-value by-product of the meat processing industry. The aim of this research was to develop a non-renewable energy and greenhouse gas emission eco-profile for cradle to gate production of NTP. Environmental impacts of supplying blood meal as a raw material were investigated using different allocation methods for farming and blood meal production. These included mass, economic, treating low-value by-products as waste and system expansion by substitution. In part 2, the entire system will be analysed on a cradle to gate basis and include the production of thermoplastic (NTP).
Methods
A theoretical NTP production facility was analysed for non-renewable primary energy use and greenhouse gas emissions. Data for feedstocks and process steps were obtained from published papers, government agency reports and engineering models. Mass and economic allocation models treating low-value by-products as waste and substitution were applied, and a sensitivity analysis was used to evaluate the impact of different methods of allocation on environmental impact.
Results and discussion
Non-renewable energy use in blood meal production varied between 5 (substitution) and 38 MJ (simple mass allocation) per kg of NTP. Greenhouse gas emissions varied between 0.4 (substitution), or even less if the biogenic carbon content is considered a credit, and 14 kg (mass allocation) CO2e per kg NTP.
Conclusions
It was concluded that both mass allocation and a waste assumption should be considered for the cradle to gate system. Mass allocation is common in other attributional studies and allows for a more transparent comparison. The most appropriate treatment of allocation in an attributional profile was to consider blood as a waste with regard to farming and meat processing, but include blood drying. This takes into account the motivations for farming and meat processing, but also recognises that there are other treatment options for blood that do not produce blood meal used in manufacturing NTP. This would allow NTP to be compared to other bioplastics as well as identifying hot spots in its cradle to gate production. It was also anticipated that results may be adapted in future cradle to grave assessments as product systems are developed.

text: An eco-profile of thermoplastic protein derived from blood meal Part 1: allocation issues Purpose
A renewable thermoplastic called Novatein Thermoplastic Protein (NTP) has been developed from blood meal—a low-value by-product of the meat processing industry. The aim of this research was to develop a non-renewable energy and greenhouse gas emission eco-profile for cradle to gate production of NTP. Environmental impacts of supplying blood meal as a raw material were investigated using different allocation methods for farming and blood meal production. These included mass, economic, treating low-value by-products as waste and system expansion by substitution. In part 2, the entire system will be analysed on a cradle to gate basis and include the production of thermoplastic (NTP).
Methods
A theoretical NTP production facility was analysed for non-renewable primary energy use and greenhouse gas emissions. Data for feedstocks and process steps were obtained from published papers, government agency reports and engineering models. Mass and economic allocation models treating low-value by-products as waste and substitution were applied, and a sensitivity analysis was used to evaluate the impact of different methods of allocation on environmental impact.
Results and discussion
Non-renewable energy use in blood meal production varied between 5 (substitution) and 38 MJ (simple mass allocation) per kg of NTP. Greenhouse gas emissions varied between 0.4 (substitution), or even less if the biogenic carbon content is considered a credit, and 14 kg (mass allocation) CO2e per kg NTP.
Conclusions
It was concluded that both mass allocation and a waste assumption should be considered for the cradle to gate system. Mass allocation is common in other attributional studies and allows for a more transparent comparison. The most appropriate treatment of allocation in an attributional profile was to consider blood as a waste with regard to farming and meat processing, but include blood drying. This takes into account the motivations for farming and meat processing, but also recognises that there are other treatment options for blood that do not produce blood meal used in manufacturing NTP. This would allow NTP to be compared to other bioplastics as well as identifying hot spots in its cradle to gate production. It was also anticipated that results may be adapted in future cradle to grave assessments as product systems are developed.

year: 2011

title: The “standard story” of anti-Māori talk in Pae Ora (Healthy Futures) Bill submissions

authors: Black, Rose

abstract: AIM: To review some common patterns of race talk in a sample of submissions made to the Pae Ora (Healthy Futures) Bill. This bill proposed a structural reform of the health system in Aotearoa New Zealand to address long-standing health inequities experienced by Māori, the Indigenous peoples, and other priority populations. METHOD: In a sample of 3,000 individual submissions made in late 2021, we found 2,536 explicit references to race. Utilising the “stan-dard story” frame of Pākehā/non-Maori race talk, five longer submissions that inferred that the Pae Ora bill was “racist” were analysed in detail. RESULTS: Many “standard story” race discourses were identified in the Pae Ora submissions. Three derived discourses included in this paper are: Pākehā as norm (monoculturalism or not seeing Pākehā as a culture), equality and the “Treaty” (equality for all to access healthcare), and one people (we are all New Zealanders). Sources such as the Waitangi Tribunal Wai 2575 Hauora report were drawn on to provide alternative discourses. CONCLUSION: Identifying Pākehā standard story discourses enables learning about language patterns systems draw on, and the development of tools and procedures to improve equity for Māori and eliminate institutional racism.

text: The “standard story” of anti-Māori talk in Pae Ora (Healthy Futures) Bill submissions AIM: To review some common patterns of race talk in a sample of submissions made to the Pae Ora (Healthy Futures) Bill. This bill proposed a structural reform of the health system in Aotearoa New Zealand to address long-standing health inequities experienced by Māori, the Indigenous peoples, and other priority populations. METHOD: In a sample of 3,000 individual submissions made in late 2021, we found 2,536 explicit references to race. Utilising the “stan-dard story” frame of Pākehā/non-Maori race talk, five longer submissions that inferred that the Pae Ora bill was “racist” were analysed in detail. RESULTS: Many “standard story” race discourses were identified in the Pae Ora submissions. Three derived discourses included in this paper are: Pākehā as norm (monoculturalism or not seeing Pākehā as a culture), equality and the “Treaty” (equality for all to access healthcare), and one people (we are all New Zealanders). Sources such as the Waitangi Tribunal Wai 2575 Hauora report were drawn on to provide alternative discourses. CONCLUSION: Identifying Pākehā standard story discourses enables learning about language patterns systems draw on, and the development of tools and procedures to improve equity for Māori and eliminate institutional racism.

year: 2023-07-21