title: Industrial heat pump integration in non-continuous processes using thermal energy storages as utility - An NLP enhancement of the graphical approach

authors: Stampfli, Jan A.

abstract: The aim of this paper is to enhance the results of the graphical approach for Heat Pump (HP) integration in noncontinuous processes. A nonlinear programming (NLP) formulation is developed which optimizes temperature levels of condensation, evaporation, and storage temperature layers in order to further reduce total annual cost (TAC) and greenhouse gas (GHG) emissions. In addition, the NLP formulation requires low computation time given the practical approach. By its application on an AMMIX butter production of a large dairy factory, it is shown, that the temperature differences in the condenser and evaporator are reduced sharply which improves the COP of the HP from 2.2 to 3.4. As a result, the TAC can be reduced by an additional 16,721 NZD/y and the GHG emissions by an additional 29 tCO2/y in comparison to the graphical approach.

text: Industrial heat pump integration in non-continuous processes using thermal energy storages as utility - An NLP enhancement of the graphical approach The aim of this paper is to enhance the results of the graphical approach for Heat Pump (HP) integration in noncontinuous processes. A nonlinear programming (NLP) formulation is developed which optimizes temperature levels of condensation, evaporation, and storage temperature layers in order to further reduce total annual cost (TAC) and greenhouse gas (GHG) emissions. In addition, the NLP formulation requires low computation time given the practical approach. By its application on an AMMIX butter production of a large dairy factory, it is shown, that the temperature differences in the condenser and evaporator are reduced sharply which improves the COP of the HP from 2.2 to 3.4. As a result, the TAC can be reduced by an additional 16,721 NZD/y and the GHG emissions by an additional 29 tCO2/y in comparison to the graphical approach.

year: 2018

title: A zwitterionic monoalkylated derivative of [Pt₂(μ-S)₂(PPh₃)₄] from 1,3-propanesultone

authors: Ujam, Oguejiofo Theophilus

subjects: platinum complex

abstract: Reaction of dinuclear platinum(II) sulfido complex [Pt₂(μ-S)₂(PPh₃)₄] with 1,3-propanesultone gives the novel zwitterionic monoalkylated thiolate complex [Pt₂(μ-S){μ-S(CH₂)₃SO₃}•(PPh₃)₄], which was characterized by NMR spectroscopy, electrospray ionisation mass spectrometry, and a single crystal X-ray structure determination. Crystals are monoclinic, space group P2(1)/c with unit cell dimensions a = 16.8957(3) Å, b = 15.5031(3) Å, c = 28.0121(5) Å, β = 99.780(1)°, for Z = 4.

text: A zwitterionic monoalkylated derivative of [Pt₂(μ-S)₂(PPh₃)₄] from 1,3-propanesultone Reaction of dinuclear platinum(II) sulfido complex [Pt₂(μ-S)₂(PPh₃)₄] with 1,3-propanesultone gives the novel zwitterionic monoalkylated thiolate complex [Pt₂(μ-S){μ-S(CH₂)₃SO₃}•(PPh₃)₄], which was characterized by NMR spectroscopy, electrospray ionisation mass spectrometry, and a single crystal X-ray structure determination. Crystals are monoclinic, space group P2(1)/c with unit cell dimensions a = 16.8957(3) Å, b = 15.5031(3) Å, c = 28.0121(5) Å, β = 99.780(1)°, for Z = 4.

year: 2013

title: Maori perspectives of the environment: A review of resource use consent submissions made by iwi to Environment Waikato.

authors: Whangapirita, Laura

subjects: Maori

abstract: As part of our broader brief to gather, summarise, analyse and distribute information held by Environment Waikato on Maori and the environment, we reviewed and summarised iwi consent submissions made on various resource use consent applications. This report refers to values and beliefs sourced from iwi submissions held by Environment Waikato and are presented within a Maori values framework to highlight environmental perspectives of tangata whenua in the Waikato region.

text: Maori perspectives of the environment: A review of resource use consent submissions made by iwi to Environment Waikato. As part of our broader brief to gather, summarise, analyse and distribute information held by Environment Waikato on Maori and the environment, we reviewed and summarised iwi consent submissions made on various resource use consent applications. This report refers to values and beliefs sourced from iwi submissions held by Environment Waikato and are presented within a Maori values framework to highlight environmental perspectives of tangata whenua in the Waikato region.

year: 2003-11