title: Louisa Alice Baker

authors: Moffat, Kirstine

abstract: Louisa Alice Baker was the first professional New Zealand woman novelist, publishing seventeen books between 1894 and 1913. Most of her fiction was set in the New Zealand she lived in from the ages of 7 to 38, but all of her novels were published in Britain and America where there was an appetite for colonial settings and where her preoccupation with marriage drew comparisons with Olive Schreiner and Sarah Grand. Her choice of the pseudonym “Alien” speaks of her sense of dislocation from her New Zealand home and points to a moral feminist message that challenged patriarchal hierarchies.

text: Louisa Alice Baker Louisa Alice Baker was the first professional New Zealand woman novelist, publishing seventeen books between 1894 and 1913. Most of her fiction was set in the New Zealand she lived in from the ages of 7 to 38, but all of her novels were published in Britain and America where there was an appetite for colonial settings and where her preoccupation with marriage drew comparisons with Olive Schreiner and Sarah Grand. Her choice of the pseudonym “Alien” speaks of her sense of dislocation from her New Zealand home and points to a moral feminist message that challenged patriarchal hierarchies.

year: 2019

title: Ruthenium and osmium carbonyl clusters incorporating stannylene and stannyl ligands

authors: Kabir, Shariff E.

abstract: The reaction of [Ru₃ (CO)₁₂] with Ph₃SnSPh in refluxing benzene furnished the bimetallic Ru-Sn compound [Ru₃(CO)₈(μ-SPh)₂(μ3-SnPh₂)(SnPh₃)₂] 1 which consists of a SnPh₂ stannylene bonded to three Ru atoms to give a planar tetra-metal core, with two peripheral SnPh₃ ligands. The stannylene ligand forms a very short bond to one Ru atom [Sn-Ru 2.538(1) Å] and very long bonds to the other two [Sn-Ru 3.074(1) Å]. The germanium compound [Ru₃(CO)₈(μ-SPh)₂(μ₃-GePh₂)(GePh₃)₂] 2 was obtained from the reaction of [Ru₃ (CO)₁₂] with Ph₃GeSPh and has a similar structure to that of 1 as evidenced by spectroscopic data. Treatment of [Os₃(CO)₁₀(MeCN)₂] with Ph₃SnSPh in refluxing benzene yielded the bimetallic Os-Sn compound [Os₃(CO)₉(μ-SPh)(μ₃-SnPh₂)(MeCN)(ƞ¹-C₆H₅)] 3. Cluster 3 has a superficially similar planar metal core, but with a different bonding mode with respect to that of 1. The Ph₂Sn group is bonded most closely to Os(2) and Os(3) [2.7862(3) and 2.7476(3) Å respectively] with a significantly longer bond to Os(1), 2.9981(3) Å indicating a weak back-donation to the Sn. The reaction of the bridging dppm compound [Ru₃(CO)₁₀(μ-dppm)] with Ph₃SnSPh afforded [Ru₃(CO)₆(μ-dppm)(μ₃-S)(μ₃-SPh)(SnPh₃)] 5. Compound 5 contains an open triangle of Ru atoms simultaneously capped by a sulfido and a PhS ligand on opposite sides of the cluster with a dppm ligand bridging one of the Ru-Ru edges and a Ph₃Sn group occupying an axial position on the Ru atom not bridged by the dppm ligand.

text: Ruthenium and osmium carbonyl clusters incorporating stannylene and stannyl ligands The reaction of [Ru₃ (CO)₁₂] with Ph₃SnSPh in refluxing benzene furnished the bimetallic Ru-Sn compound [Ru₃(CO)₈(μ-SPh)₂(μ3-SnPh₂)(SnPh₃)₂] 1 which consists of a SnPh₂ stannylene bonded to three Ru atoms to give a planar tetra-metal core, with two peripheral SnPh₃ ligands. The stannylene ligand forms a very short bond to one Ru atom [Sn-Ru 2.538(1) Å] and very long bonds to the other two [Sn-Ru 3.074(1) Å]. The germanium compound [Ru₃(CO)₈(μ-SPh)₂(μ₃-GePh₂)(GePh₃)₂] 2 was obtained from the reaction of [Ru₃ (CO)₁₂] with Ph₃GeSPh and has a similar structure to that of 1 as evidenced by spectroscopic data. Treatment of [Os₃(CO)₁₀(MeCN)₂] with Ph₃SnSPh in refluxing benzene yielded the bimetallic Os-Sn compound [Os₃(CO)₉(μ-SPh)(μ₃-SnPh₂)(MeCN)(ƞ¹-C₆H₅)] 3. Cluster 3 has a superficially similar planar metal core, but with a different bonding mode with respect to that of 1. The Ph₂Sn group is bonded most closely to Os(2) and Os(3) [2.7862(3) and 2.7476(3) Å respectively] with a significantly longer bond to Os(1), 2.9981(3) Å indicating a weak back-donation to the Sn. The reaction of the bridging dppm compound [Ru₃(CO)₁₀(μ-dppm)] with Ph₃SnSPh afforded [Ru₃(CO)₆(μ-dppm)(μ₃-S)(μ₃-SPh)(SnPh₃)] 5. Compound 5 contains an open triangle of Ru atoms simultaneously capped by a sulfido and a PhS ligand on opposite sides of the cluster with a dppm ligand bridging one of the Ru-Ru edges and a Ph₃Sn group occupying an axial position on the Ru atom not bridged by the dppm ligand.

year: 2008

title: Homeless lives in New Zealand: The case of central Auckland

authors: Groot, Shiloh Ann Maree

subjects: Maori

abstract: Homelessness is a pressing and increasingly visible concern in New Zealand. Many people sleeping rough are male and of Maori or Pacific descent. This research focuses on understanding the nature of resilience through the lived experiences of homeless people. To gain insights into cultures of homelessness, a qualitative case study research design was used to engage six homeless people who took part in a series of interviews and photoproduction exercises. Participants are of Maori, Pacific Island, and Pakeha ethnic backgrounds. It therefore may become important to document how homeless people see themselves in relation to their communities of origin and the wider public.

text: Homeless lives in New Zealand: The case of central Auckland Homelessness is a pressing and increasingly visible concern in New Zealand. Many people sleeping rough are male and of Maori or Pacific descent. This research focuses on understanding the nature of resilience through the lived experiences of homeless people. To gain insights into cultures of homelessness, a qualitative case study research design was used to engage six homeless people who took part in a series of interviews and photoproduction exercises. Participants are of Maori, Pacific Island, and Pakeha ethnic backgrounds. It therefore may become important to document how homeless people see themselves in relation to their communities of origin and the wider public.

year: 2008