title: Pentaric acids and derivatives from nitric acid–oxidized pentoses

authors: Hinton, Michael R.

subjects: nitric acid

abstract: This report describes the preparation of the four stereoisomeric pentaric acids by nitric acid oxidation of d-xylose, d-arabinose, l-arabinose, and d-ribose, with xylaric, d-arabinaric, and l-arabinaric acids being made in a reactor under computer control. The pentaric acids were converted to their crystalline N,N′-dimethylpentaramides, derivatives that proved useful for isolation of the arabinaric acids from their respective oxidation mixtures. The N,N′-dimethylpentaramides were readily convertible to the corresponding pentaric acid disodium salts in aqueous sodium chloride. The 2,3,4-O-triacetyl-N,N′-dimethylpentaramides of xylaric, l-arabinaric, and ribaric acid were also prepared. Ribaric acid was isolated as crystalline 1,4(5,2)-ribarolactone and further characterized by x-ray crystallography.

text: Pentaric acids and derivatives from nitric acid–oxidized pentoses This report describes the preparation of the four stereoisomeric pentaric acids by nitric acid oxidation of d-xylose, d-arabinose, l-arabinose, and d-ribose, with xylaric, d-arabinaric, and l-arabinaric acids being made in a reactor under computer control. The pentaric acids were converted to their crystalline N,N′-dimethylpentaramides, derivatives that proved useful for isolation of the arabinaric acids from their respective oxidation mixtures. The N,N′-dimethylpentaramides were readily convertible to the corresponding pentaric acid disodium salts in aqueous sodium chloride. The 2,3,4-O-triacetyl-N,N′-dimethylpentaramides of xylaric, l-arabinaric, and ribaric acid were also prepared. Ribaric acid was isolated as crystalline 1,4(5,2)-ribarolactone and further characterized by x-ray crystallography.

year: 2013

title: Effects of surfzone wave transformation on swash dynamics

authors: Guedes, Rafael Marcondes Carvalho

subjects: swash

abstract: Swash oscillations on two natural beaches were measured to show that the shape and magnitude of energy spectra can be largely dependent on processes occurring inside the surfzone. The observations took place on a steep, intermediate beach on the east coast (Tairua Beach), and a low-sloping, dissipative beach located on the west coast of New Zealand (Ngarunui Beach, Raglan), and aimed at improving the understanding of the effects of wave breaking, beach slope, and nonlinear wave interactions on the swash oscillations. These problems were addressed by analysing datasets obtained from field experiments undertaken at these two sites.
A field experiment at Tairua Beach showed that swash oscillations were critically dependent on the stage of the tide which controlled the degree of wave energy dissipation over the sandbar crest. Under mild, near-constant offshore wave conditions, the presence of a sandbar and the tidally-controlled water depth over its crest determined whether most of the incoming waves broke before reaching the shoreline. This forced a change in the pattern of wave energy dissipation across the surfzone between low and high tide, which was reflected by changes to swash elevation (runup) on time-scales of a few hours. Significant runup height Rs, defined as 4 times the standard deviation of the waterline time series, varied by a factor of 2 between low tide, when most of the waves were breaking over the sandbar and high tide, when the waves were barely breaking. The increase in wave energy dissipation during low tide was associated with changes in swash maxima distribution, decrease in mean swash period and increasing energy at infragravity frequencies (0.004–0.05 Hz). Bispectral analysis suggested this infragravity modulation might be connected with the presence of secondary waves at the shoreline.
Swash oscillations at Tairua were not homogeneous along the beach. Alongshore variability in Rs of up to 78% was observed and was mainly driven by changes in the sea-swell (0.05–0.4 Hz) band of the swash. This variability was predominantly controlled by alongshore changes in beach face slope, although alongshore patterning in wave breaking over the sandbar caused alongshore changes in wave dissipation and also resulted in alongshore swash variation in the sea-swell bandwidth. At infragravity frequencies, alongshore swash variability was not well associated either with changes in beach slope or wave breaking and was possibly linked to the presence of low-mode edge waves, observed from frequency-wavenumber spectra of the swash time series.
A final experiment was conducted to understand the surfzone control on incident and infragravity runup on a gently-sloping beach. The observations showed that runup saturation at infragravity frequencies can occur under mild offshore energy conditions if the beach slope is sufficiently gentle. Infragravity saturation was observed for higher-frequency (> 0.025–0.035 Hz) infragravity waves, where typically less than 5% of the (linear) energy flux was reflected from the beach and where, similar to the sea-swell band, the swash energy was independent of offshore wave energy. The infragravity frequency range of saturation was determined by the tide, with saturation extending to lower frequencies at low tide when the local beach face slope over the concave-shaped profile was gentler. Runup was strongly dominated by infragravity frequencies, which accounted on average for 96% of the runup variance, and its energy levels were entirely consistent with strong infragravity wave dissipation observed in the surfzone, particularly when including the nonlinear contributions to the wave energy fluxes. Our observations show evidence of nonlinear interactions involving infragravity and high-frequency, harmonic waves, and suggest that these harmonics could play a role in the wave energy balance near the shoreline on low-sloping, dissipative beaches.

text: Effects of surfzone wave transformation on swash dynamics Swash oscillations on two natural beaches were measured to show that the shape and magnitude of energy spectra can be largely dependent on processes occurring inside the surfzone. The observations took place on a steep, intermediate beach on the east coast (Tairua Beach), and a low-sloping, dissipative beach located on the west coast of New Zealand (Ngarunui Beach, Raglan), and aimed at improving the understanding of the effects of wave breaking, beach slope, and nonlinear wave interactions on the swash oscillations. These problems were addressed by analysing datasets obtained from field experiments undertaken at these two sites.
A field experiment at Tairua Beach showed that swash oscillations were critically dependent on the stage of the tide which controlled the degree of wave energy dissipation over the sandbar crest. Under mild, near-constant offshore wave conditions, the presence of a sandbar and the tidally-controlled water depth over its crest determined whether most of the incoming waves broke before reaching the shoreline. This forced a change in the pattern of wave energy dissipation across the surfzone between low and high tide, which was reflected by changes to swash elevation (runup) on time-scales of a few hours. Significant runup height Rs, defined as 4 times the standard deviation of the waterline time series, varied by a factor of 2 between low tide, when most of the waves were breaking over the sandbar and high tide, when the waves were barely breaking. The increase in wave energy dissipation during low tide was associated with changes in swash maxima distribution, decrease in mean swash period and increasing energy at infragravity frequencies (0.004–0.05 Hz). Bispectral analysis suggested this infragravity modulation might be connected with the presence of secondary waves at the shoreline.
Swash oscillations at Tairua were not homogeneous along the beach. Alongshore variability in Rs of up to 78% was observed and was mainly driven by changes in the sea-swell (0.05–0.4 Hz) band of the swash. This variability was predominantly controlled by alongshore changes in beach face slope, although alongshore patterning in wave breaking over the sandbar caused alongshore changes in wave dissipation and also resulted in alongshore swash variation in the sea-swell bandwidth. At infragravity frequencies, alongshore swash variability was not well associated either with changes in beach slope or wave breaking and was possibly linked to the presence of low-mode edge waves, observed from frequency-wavenumber spectra of the swash time series.
A final experiment was conducted to understand the surfzone control on incident and infragravity runup on a gently-sloping beach. The observations showed that runup saturation at infragravity frequencies can occur under mild offshore energy conditions if the beach slope is sufficiently gentle. Infragravity saturation was observed for higher-frequency (> 0.025–0.035 Hz) infragravity waves, where typically less than 5% of the (linear) energy flux was reflected from the beach and where, similar to the sea-swell band, the swash energy was independent of offshore wave energy. The infragravity frequency range of saturation was determined by the tide, with saturation extending to lower frequencies at low tide when the local beach face slope over the concave-shaped profile was gentler. Runup was strongly dominated by infragravity frequencies, which accounted on average for 96% of the runup variance, and its energy levels were entirely consistent with strong infragravity wave dissipation observed in the surfzone, particularly when including the nonlinear contributions to the wave energy fluxes. Our observations show evidence of nonlinear interactions involving infragravity and high-frequency, harmonic waves, and suggest that these harmonics could play a role in the wave energy balance near the shoreline on low-sloping, dissipative beaches.

year: 2012

title: Schooling  for  'lesser beings'

authors: Holdom, Jim

subjects: Maori

abstract: Using Edward Said’s notion of ‘lesser beings’, it is argued that the political culture of schooling for Maori was and still is part of a pervasive Western European intellectual climate and culture which has a quite recent history, and which provided powerful support for the notion of Europe possessing a categorical superiority over all other continents, which in turn justified imperialism or neo-colonialism as civilising missions.
Racism and violence were endemic in colonialism and, despite the claimed moral high ground, were endemic in Aotearoa/New Zealand.  War was eulogised in the Native School system more than once.  The rise and demise of the World War II Maori War Organisation is illustrative of the rejection of Maori aspirations.  There were still no Maori in the senior echelons of the Maori Department in 1972.
The Native, later Maori, School system was overtly designed to 'Europeanise' Maori children and therefore Maori society.  Individualism was deeply embedded in English and set-tler thinking, whilst communal, ‘communist’ Maori society was to be destroyed.
The thesis examines images of colonialism, empire and imperialism in fiction and non-fiction, New Zealand and British, for adults and children, and notes the attitudes of think-ers like J S Mill and Darwin, of children’s authors Jules Verne and G H Henty, and of New Zealand author William Satchell.  The images continue, pervasive and endemic, in recent adult novels.  Science also played a role, as did history.
 Ranginui Walker, who is Maori, is the only historian to have written a history of New Zea-land which addressed the issue of waste lands, an issue on which Pakeha historians have a blind spot.  New Zealand encyclopedia do not index ‘waste land’ or ‘confiscation’.  Only two Waikato histories deal adequately, or even accurately, with confiscation, the central episode in the history of the Waikato.  Tourist material is equally illustrative.
The Native Schools section of the Education Department ran the Native Schools like a fiefdom, operating in legislative and regulatory black holes for the first thirty years and for much of the time after that.  Teachers were moved around at will.  
The practice of James H Pope, the first inspector of Native Schools, is closely and critically examined, and negatively assessed.  His official writings were consistently derogatory of Maori, and his decisions in respect of Te Kopua Native School were at times detrimental to the pupils.  Pope was a product of his times.
The Te Kopua record is closely scrutinised, and the practice of the Education Department is frequently found wanting.  It is probable that the establishment of the school was aimed to destabilise King Country Maori, not to benefit the children.  It is a story of Maori co-operation and contribution.
Part Two is a detailed partial biography of Te Kopua, it being argued that until there is a significant corpus of studies of Native Schools a valid history of the Native/Maori School system and of schooling for Maori is not possible

text: Schooling  for  'lesser beings' Using Edward Said’s notion of ‘lesser beings’, it is argued that the political culture of schooling for Maori was and still is part of a pervasive Western European intellectual climate and culture which has a quite recent history, and which provided powerful support for the notion of Europe possessing a categorical superiority over all other continents, which in turn justified imperialism or neo-colonialism as civilising missions.
Racism and violence were endemic in colonialism and, despite the claimed moral high ground, were endemic in Aotearoa/New Zealand.  War was eulogised in the Native School system more than once.  The rise and demise of the World War II Maori War Organisation is illustrative of the rejection of Maori aspirations.  There were still no Maori in the senior echelons of the Maori Department in 1972.
The Native, later Maori, School system was overtly designed to 'Europeanise' Maori children and therefore Maori society.  Individualism was deeply embedded in English and set-tler thinking, whilst communal, ‘communist’ Maori society was to be destroyed.
The thesis examines images of colonialism, empire and imperialism in fiction and non-fiction, New Zealand and British, for adults and children, and notes the attitudes of think-ers like J S Mill and Darwin, of children’s authors Jules Verne and G H Henty, and of New Zealand author William Satchell.  The images continue, pervasive and endemic, in recent adult novels.  Science also played a role, as did history.
 Ranginui Walker, who is Maori, is the only historian to have written a history of New Zea-land which addressed the issue of waste lands, an issue on which Pakeha historians have a blind spot.  New Zealand encyclopedia do not index ‘waste land’ or ‘confiscation’.  Only two Waikato histories deal adequately, or even accurately, with confiscation, the central episode in the history of the Waikato.  Tourist material is equally illustrative.
The Native Schools section of the Education Department ran the Native Schools like a fiefdom, operating in legislative and regulatory black holes for the first thirty years and for much of the time after that.  Teachers were moved around at will.  
The practice of James H Pope, the first inspector of Native Schools, is closely and critically examined, and negatively assessed.  His official writings were consistently derogatory of Maori, and his decisions in respect of Te Kopua Native School were at times detrimental to the pupils.  Pope was a product of his times.
The Te Kopua record is closely scrutinised, and the practice of the Education Department is frequently found wanting.  It is probable that the establishment of the school was aimed to destabilise King Country Maori, not to benefit the children.  It is a story of Maori co-operation and contribution.
Part Two is a detailed partial biography of Te Kopua, it being argued that until there is a significant corpus of studies of Native Schools a valid history of the Native/Maori School system and of schooling for Maori is not possible

year: 1998