title: A zwitterionic monoalkylated derivative of [Pt₂(μ-S)₂(PPh₃)₄] from 1,3-propanesultone

authors: Ujam, Oguejiofo Theophilus

subjects: platinum complex

abstract: Reaction of dinuclear platinum(II) sulfido complex [Pt₂(μ-S)₂(PPh₃)₄] with 1,3-propanesultone gives the novel zwitterionic monoalkylated thiolate complex [Pt₂(μ-S){μ-S(CH₂)₃SO₃}•(PPh₃)₄], which was characterized by NMR spectroscopy, electrospray ionisation mass spectrometry, and a single crystal X-ray structure determination. Crystals are monoclinic, space group P2(1)/c with unit cell dimensions a = 16.8957(3) Å, b = 15.5031(3) Å, c = 28.0121(5) Å, β = 99.780(1)°, for Z = 4.

text: A zwitterionic monoalkylated derivative of [Pt₂(μ-S)₂(PPh₃)₄] from 1,3-propanesultone Reaction of dinuclear platinum(II) sulfido complex [Pt₂(μ-S)₂(PPh₃)₄] with 1,3-propanesultone gives the novel zwitterionic monoalkylated thiolate complex [Pt₂(μ-S){μ-S(CH₂)₃SO₃}•(PPh₃)₄], which was characterized by NMR spectroscopy, electrospray ionisation mass spectrometry, and a single crystal X-ray structure determination. Crystals are monoclinic, space group P2(1)/c with unit cell dimensions a = 16.8957(3) Å, b = 15.5031(3) Å, c = 28.0121(5) Å, β = 99.780(1)°, for Z = 4.

year: 2013

title: 'Don't you perceive gender as different because of the chromosomes': Examining the Impact of Gender Discourses on Early Childhood Pre-Service Teachers?

authors: Lyall, Margaret Vida

subjects: gender

abstract: This thesis is a qualitative study located within the context of contemporary New Zealand early childhood education. It investigates the impact and implications on pedagogy resulting from the gender discourses held by pre-service early childhood teachers, each of whom had just begun the final semester of the 3rd year of their Bachelor of teaching early childhood education. Specifically, using data generated through focus groups, it investigates the participant’s location and framing of gender, gender development and the participant’s understandings of gender diversity. The research, which extensively used post-structural feminism and Foucault’s notion of discourse as a theoretical framework, identified the participant’s discourses around gender which were conflicting, uncontested and confused.

A series of influential discourses regarding gender were identified as potentially shaping pre-service teachers developing teacher subjectivity. I claim that the shaping of teacher subject, who are indifferent to gender, results, from a reduction of focus on gender in the early childhood sector in both professional practice and state policy. The increased dominance of the biological determinist discourse in lay society is keenly felt in these domains. The increased biologically determinist view inferring that gender difference is natural and therefore unchallengeable and the reduced focus on gender in professional and government fields decreases the importance placed on gender. As such, this thesis suggests that the importance placed on gender by the developing teacher subject may be inconsistent with the important role gender plays in the early years and may therefore inhibit pedagogy and practice.

This research has implications for policy and teacher education. The results identify early childhood teacher education as being in a unique position to attempt to mitigate such issues. Specifically this can be done by supporting the development of the reflexive skills needed for pre-service teachers to consider and challenge the gender discourses that influence them.

text: 'Don't you perceive gender as different because of the chromosomes': Examining the Impact of Gender Discourses on Early Childhood Pre-Service Teachers? This thesis is a qualitative study located within the context of contemporary New Zealand early childhood education. It investigates the impact and implications on pedagogy resulting from the gender discourses held by pre-service early childhood teachers, each of whom had just begun the final semester of the 3rd year of their Bachelor of teaching early childhood education. Specifically, using data generated through focus groups, it investigates the participant’s location and framing of gender, gender development and the participant’s understandings of gender diversity. The research, which extensively used post-structural feminism and Foucault’s notion of discourse as a theoretical framework, identified the participant’s discourses around gender which were conflicting, uncontested and confused.

A series of influential discourses regarding gender were identified as potentially shaping pre-service teachers developing teacher subjectivity. I claim that the shaping of teacher subject, who are indifferent to gender, results, from a reduction of focus on gender in the early childhood sector in both professional practice and state policy. The increased dominance of the biological determinist discourse in lay society is keenly felt in these domains. The increased biologically determinist view inferring that gender difference is natural and therefore unchallengeable and the reduced focus on gender in professional and government fields decreases the importance placed on gender. As such, this thesis suggests that the importance placed on gender by the developing teacher subject may be inconsistent with the important role gender plays in the early years and may therefore inhibit pedagogy and practice.

This research has implications for policy and teacher education. The results identify early childhood teacher education as being in a unique position to attempt to mitigate such issues. Specifically this can be done by supporting the development of the reflexive skills needed for pre-service teachers to consider and challenge the gender discourses that influence them.

year: 2013

title: The Impact of Colonisation on the Maori community: An exploration of the attitudes and perspectives held by Maori in relation to the active reclamation of Maori sovereignty/tino rangatiratanga.

authors: Baty, Tina Amy

subjects: Maori

abstract: Whāia te iti kahurangi ki te tūohu koe me he maunga teitei
Seek the treasure you value most dearly: If you bow your head, let it be to a lofty mountain
The purpose of my research was twofold. I first sort to explore the attitudes and perspectives held by Māori in relation to the active reclamation of Māori sovereignty, tino rangatiratanga. I further wanted to know how Māori sovereignty, tino rangatiratanga could lead to the improvement of Māori health.
My research collected information pertinent to these two inquiries from current literature and from interviews I conducted with five Māori individuals from different iwi, hapu groups. All whom were actively engaged with the Māori community in some form. My research data found that colonisalism has and continues to negatively impact the Māori community. This negative impact manifests in a variety of behaviours that effect Māori health and leads to poor outcomes for Māori. Māori sovereignty, tino rangatiratanga was thought of as the solution to overcome and neutralise the negative effects of colonialism experienced by Māori. Māori sovereignty, tino rangatiratanga was found to be related with Māori idenity and instrumental in all things pertinent to the Māori communities.
My research found that Māori sovereignty, tino rangatiratanga can be identified as existing on a philosophical level, governance-structural level, and on a day-to-day basis. This research found that the reclamation of Māori sovereignty, tino rangatiratanga is a process that is currently in motion. Finally, the exercising of Māori sovereignty, tino rangatiratanga in relation to Māori health provides a well-established argument that it can produce positive health benefits to the Māori community, because it is responsive to Māori and better meets the needs of our Māori community simply because it is a Māori way of being, doing and knowing.

text: The Impact of Colonisation on the Maori community: An exploration of the attitudes and perspectives held by Maori in relation to the active reclamation of Maori sovereignty/tino rangatiratanga. Whāia te iti kahurangi ki te tūohu koe me he maunga teitei
Seek the treasure you value most dearly: If you bow your head, let it be to a lofty mountain
The purpose of my research was twofold. I first sort to explore the attitudes and perspectives held by Māori in relation to the active reclamation of Māori sovereignty, tino rangatiratanga. I further wanted to know how Māori sovereignty, tino rangatiratanga could lead to the improvement of Māori health.
My research collected information pertinent to these two inquiries from current literature and from interviews I conducted with five Māori individuals from different iwi, hapu groups. All whom were actively engaged with the Māori community in some form. My research data found that colonisalism has and continues to negatively impact the Māori community. This negative impact manifests in a variety of behaviours that effect Māori health and leads to poor outcomes for Māori. Māori sovereignty, tino rangatiratanga was thought of as the solution to overcome and neutralise the negative effects of colonialism experienced by Māori. Māori sovereignty, tino rangatiratanga was found to be related with Māori idenity and instrumental in all things pertinent to the Māori communities.
My research found that Māori sovereignty, tino rangatiratanga can be identified as existing on a philosophical level, governance-structural level, and on a day-to-day basis. This research found that the reclamation of Māori sovereignty, tino rangatiratanga is a process that is currently in motion. Finally, the exercising of Māori sovereignty, tino rangatiratanga in relation to Māori health provides a well-established argument that it can produce positive health benefits to the Māori community, because it is responsive to Māori and better meets the needs of our Māori community simply because it is a Māori way of being, doing and knowing.

year: 2018