title: Gold(III) thiosalicylate complexes containing cycloaurated 2-arylpyridine, 2-anilinopyridine and 2-benzylpyridine ligands

authors: Henderson, William

subjects: Gold

abstract: Reactions of the gold(III) dichloride complexes [(N_C)AuCl₂] ((N_C)=cycloaurated 2-phenylpyridine, 2-(p-tolyl)pyridine, 2-anilinopyridine or 2-benzylpyridine) with thiosalicylic acid (2-mercaptobenzoic acid, HSC₆H₄CO₂H) and base gives a series of gold(III) thiosalicylate complexes [(N_C)Au(SC₆H₄CO₂)]. A crystal structure determination on the 2-p-tolylpyridine derivative is reported, confirming the presence of a chelating thiosalicylate ligand, with the tolyl and thiolate groups mutually cis, together with a highly puckered gold–thiosalicylate moiety, and a twisted carboxylate group. The activity of the thiosalicylate complexes against P388 leukaemia cells has been determined.

text: Gold(III) thiosalicylate complexes containing cycloaurated 2-arylpyridine, 2-anilinopyridine and 2-benzylpyridine ligands Reactions of the gold(III) dichloride complexes [(N_C)AuCl₂] ((N_C)=cycloaurated 2-phenylpyridine, 2-(p-tolyl)pyridine, 2-anilinopyridine or 2-benzylpyridine) with thiosalicylic acid (2-mercaptobenzoic acid, HSC₆H₄CO₂H) and base gives a series of gold(III) thiosalicylate complexes [(N_C)Au(SC₆H₄CO₂)]. A crystal structure determination on the 2-p-tolylpyridine derivative is reported, confirming the presence of a chelating thiosalicylate ligand, with the tolyl and thiolate groups mutually cis, together with a highly puckered gold–thiosalicylate moiety, and a twisted carboxylate group. The activity of the thiosalicylate complexes against P388 leukaemia cells has been determined.

year: 2001-08-01

title: Tourism and spirituality: A phenomenological analysis

authors: Willson, Gregory Brian

subjects: phenomenology

abstract: Using phenomenological analysis, this paper examines the concept of 'spirituality' in the lived travel experience of an individual tourist. The paper contributes a phenomenological snippet of the tourist's 'portrait' (the individual's rich story, much like a portrait painting) to reveal the spiritual meaning Amber reportedly gained from and imbued onto her travel experiences with the tour operator, Hands up Holidays. The paper argues that when discussing the 'spiritual' dimension of tourism, one potential avenue is to seek to understand how people seek meaning and life purpose themselves, their quest for meaning, and experiences of transcendence and connectedness as subjectively lived through their travel. The paper concludes that the phenomenological view may be a useful frame through which to further examine the personal meaning of travel as lived by people, both in religious and non-religious contexts, but contextualised within the wider meaning of their lives.

text: Tourism and spirituality: A phenomenological analysis Using phenomenological analysis, this paper examines the concept of 'spirituality' in the lived travel experience of an individual tourist. The paper contributes a phenomenological snippet of the tourist's 'portrait' (the individual's rich story, much like a portrait painting) to reveal the spiritual meaning Amber reportedly gained from and imbued onto her travel experiences with the tour operator, Hands up Holidays. The paper argues that when discussing the 'spiritual' dimension of tourism, one potential avenue is to seek to understand how people seek meaning and life purpose themselves, their quest for meaning, and experiences of transcendence and connectedness as subjectively lived through their travel. The paper concludes that the phenomenological view may be a useful frame through which to further examine the personal meaning of travel as lived by people, both in religious and non-religious contexts, but contextualised within the wider meaning of their lives.

year: 2013

title: Rauaroha: He tohu Aroha rau i te akoranga

authors: Paringatai, Karyn

subjects: huarahi ako

abstract: Nö te tau 2001 i whakatüria ai e Ako Aotearoa (National Centre for Tertiary Teaching Excellence) tëtahi tohu hei whakanui i ngä mahi a te tangata e whakaako ana i te taumata takiura. Me whakaatu te kaiwhiwhi tohu i tana ü roa ki ngä taumata tiketike rawa i tana mahi whakaako. Tekau mä rua ngä kaiwhiwhi toa i ia tau, kätahi ka whiriwhirihia ai e tëtahi kömiti kaiwhakawä kia kotahi te tangata e whiwhi nei i te Tohu Tiketike o te Pirimia. Mö ngä tau e whä kua hipa ake nei i riro i ngä kaiako Mäori te tohu tiketike nei. Ko te aronga o tënei tuhinga he whakaatu i ngä ähuatanga o ënei kaiako kia märama pai atu ai te whakaaro tiketike o te Mäori ki tënei mea te ako.

text: Rauaroha: He tohu Aroha rau i te akoranga Nö te tau 2001 i whakatüria ai e Ako Aotearoa (National Centre for Tertiary Teaching Excellence) tëtahi tohu hei whakanui i ngä mahi a te tangata e whakaako ana i te taumata takiura. Me whakaatu te kaiwhiwhi tohu i tana ü roa ki ngä taumata tiketike rawa i tana mahi whakaako. Tekau mä rua ngä kaiwhiwhi toa i ia tau, kätahi ka whiriwhirihia ai e tëtahi kömiti kaiwhakawä kia kotahi te tangata e whiwhi nei i te Tohu Tiketike o te Pirimia. Mö ngä tau e whä kua hipa ake nei i riro i ngä kaiako Mäori te tohu tiketike nei. Ko te aronga o tënei tuhinga he whakaatu i ngä ähuatanga o ënei kaiako kia märama pai atu ai te whakaaro tiketike o te Mäori ki tënei mea te ako.

year: 2017