title: Quinnat salmon (oncorhynchus tshawytscha) spawning in the Rangitikei river

authors: Hicks, Brendan J.

subjects: biology

abstract: The occurrence of adult quinnat salmon {Oncorhynchus tshawytscha (Walbaum)) in the Rangitikei River, North Island, New Zealand, has been confirmed on several occasions since 1922, but juvenile salmon have not previously been recorded. In late February 1981 a 79-mm-fork-length smolt was caught in a stranded side channel 180 km upstream from the mouth. This suggests that quinnat salmon can spawn successfully in this river.

text: Quinnat salmon (oncorhynchus tshawytscha) spawning in the Rangitikei river The occurrence of adult quinnat salmon {Oncorhynchus tshawytscha (Walbaum)) in the Rangitikei River, North Island, New Zealand, has been confirmed on several occasions since 1922, but juvenile salmon have not previously been recorded. In late February 1981 a 79-mm-fork-length smolt was caught in a stranded side channel 180 km upstream from the mouth. This suggests that quinnat salmon can spawn successfully in this river.

year: 1983

title: Intramolecular dehydrofluorinative coupling of η⁶-arene and fluoroarylphosphine ligands in ruthenium complexes

authors: McGibbon, Angela

subjects: ruthenium

abstract: NMR studies of reactions between a series of arene ruthenium(II) fluoroarylphosphine complexes and Proton Sponge have revealed the necessary conditions for intramolecular dehydrofluorinative ligand coupling. The complex must be cationic, and the phosphine need have only one fluoroaryl substituent. The reaction is rapid and clean for [(η⁶-toluene)RuCl(dfppe)]BF₄, [(η⁶-mesitylene)RuCl{(C₆F₅)₂PC₆H₄SMe}]BF₄ and the diastereomer of [(η⁶-toluene)RuCl{Ph₂PC₂H₄PPh(C₅F₄N-4)}]BF₄ in which the tetrafluoropyridyl substituent is close to the η6-arene. [(η⁶-p-cymene)RuCl(dfppe)]BF₄ reacts in the presence of Proton Sponge to give a mixture of unidentified compounds. The neutral complex [(η⁶-toluene)RuCl₂{Ph₂P(C₆F₅)}] and the diastereomer of [(η⁶-toluene)RuCl{Ph₂PC₂H₄PPh(C₅F₄N-4)}]BF₄ in which the tetrafluoropyridyl substituent is distant to the η⁶-arene do not undergo reaction.

text: Intramolecular dehydrofluorinative coupling of η⁶-arene and fluoroarylphosphine ligands in ruthenium complexes NMR studies of reactions between a series of arene ruthenium(II) fluoroarylphosphine complexes and Proton Sponge have revealed the necessary conditions for intramolecular dehydrofluorinative ligand coupling. The complex must be cationic, and the phosphine need have only one fluoroaryl substituent. The reaction is rapid and clean for [(η⁶-toluene)RuCl(dfppe)]BF₄, [(η⁶-mesitylene)RuCl{(C₆F₅)₂PC₆H₄SMe}]BF₄ and the diastereomer of [(η⁶-toluene)RuCl{Ph₂PC₂H₄PPh(C₅F₄N-4)}]BF₄ in which the tetrafluoropyridyl substituent is close to the η6-arene. [(η⁶-p-cymene)RuCl(dfppe)]BF₄ reacts in the presence of Proton Sponge to give a mixture of unidentified compounds. The neutral complex [(η⁶-toluene)RuCl₂{Ph₂P(C₆F₅)}] and the diastereomer of [(η⁶-toluene)RuCl{Ph₂PC₂H₄PPh(C₅F₄N-4)}]BF₄ in which the tetrafluoropyridyl substituent is distant to the η⁶-arene do not undergo reaction.

year: 2011

title: Intra-propositional relations and their signalling: An investigation of authentic Māori texts

authors: Whaanga, Hēmi

subjects: Language & education

abstract: I report here on one part of a research project that involved the investigation of a range of authentic Māori texts in terms of two types of meaning relation – those that operate within propositions (‘intra-propositional relations’) and those that link propositions or groups of propositions (‘inter-propositional relations’). The focus here is on intra-propositional relations (relationships within propositions). On the basis of the comparison of a number of intra-propositional relational models, a new model which draws inspiration from the work of Crombie is proposed and applied to a corpus of texts written in Māori, the emphasis being on the ways in which these relations are signalled in Māori.

text: Intra-propositional relations and their signalling: An investigation of authentic Māori texts I report here on one part of a research project that involved the investigation of a range of authentic Māori texts in terms of two types of meaning relation – those that operate within propositions (‘intra-propositional relations’) and those that link propositions or groups of propositions (‘inter-propositional relations’). The focus here is on intra-propositional relations (relationships within propositions). On the basis of the comparison of a number of intra-propositional relational models, a new model which draws inspiration from the work of Crombie is proposed and applied to a corpus of texts written in Māori, the emphasis being on the ways in which these relations are signalled in Māori.

year: 2010