title: Open platinum aggregate frameworks with overhead dithiolate bridges

authors: Chong, Siew Huay

subjects: platinum

abstract: A convenient method has been developed to bring together two discrete moieties of [Pt₂(μ-S)₂(PPh₃)₄] to give an open Pt₄ aggregate of Pt₂•••(spacer)•••Pt₂, as exemplified in the isolation of [(PPh₃)₄Pt₂(μ-S)(μ-SRS)(μ-S)Pt₂(PPh₃)₄](PF₆)₂ [R = m-CH₂C₆H₄CH₂, p-CH₂C₆H₄CH₂, CH₂C₁₀H₆CH₂, and CH₂(C₆H₄)₂CH₂]. The spacer is a dithiolate with an extended skeletal backbone formed from the alkylation of sulfide with a suitable dibromo-organic compound. This synthetic methodology can tolerate a range of conformationally contrasting thiolate substituents with different chemical functionalities. Shorter or stereochemically more restrictive spacers could opt to be an intramolecular bridge over the Pt₂ core, as given in [Pt₂(μ-S-o-CH₂C₆H₄-C₆H₄CH₂S)(PPh₃)₄](PF₆)₂. A few representative complexes have been characterized by single-crystal X-ray diffraction analysis.

text: Open platinum aggregate frameworks with overhead dithiolate bridges A convenient method has been developed to bring together two discrete moieties of [Pt₂(μ-S)₂(PPh₃)₄] to give an open Pt₄ aggregate of Pt₂•••(spacer)•••Pt₂, as exemplified in the isolation of [(PPh₃)₄Pt₂(μ-S)(μ-SRS)(μ-S)Pt₂(PPh₃)₄](PF₆)₂ [R = m-CH₂C₆H₄CH₂, p-CH₂C₆H₄CH₂, CH₂C₁₀H₆CH₂, and CH₂(C₆H₄)₂CH₂]. The spacer is a dithiolate with an extended skeletal backbone formed from the alkylation of sulfide with a suitable dibromo-organic compound. This synthetic methodology can tolerate a range of conformationally contrasting thiolate substituents with different chemical functionalities. Shorter or stereochemically more restrictive spacers could opt to be an intramolecular bridge over the Pt₂ core, as given in [Pt₂(μ-S-o-CH₂C₆H₄-C₆H₄CH₂S)(PPh₃)₄](PF₆)₂. A few representative complexes have been characterized by single-crystal X-ray diffraction analysis.

year: 2007

title: What's driving Parfit's surgery cases?

authors: Weijers, Dan M.

abstract: Presented at AXΦIV: 4th Annual Australasian Experimental Philosophy Conference  held at University of Waikato, Hamilton, New Zealand on 06 Dec 2019.

text: What's driving Parfit's surgery cases? Presented at AXΦIV: 4th Annual Australasian Experimental Philosophy Conference  held at University of Waikato, Hamilton, New Zealand on 06 Dec 2019.

year: 2019-12-07

title: A case study of Pipiri Ki A Papatūānuku

authors: Tamoko-o-te-rangi, Ormsby

subjects: environmental initiatives

abstract: This thesis is an examination and analysis of the environmental initiative Pipiri Ki A Papatūānuku, co-founded by Waimirirangi Ormsby (née Koopu-Stone) and myself, Tamoko Ormsby. The primary aim of this research was to achieve an understanding of the PKP initiative at the individual level and to inform future collective action at the community level. As such, my primary research question is:

How can Pipiri Ki A Papatūānuku inform community-scale action that contributes to our more-than-human relationship with Papatūānuku within our current capitalist settler-colonial context?

The study is part-autoethnographic in that it is informed by my personal reflections and experiences as a co-founder, operator, and participant of the initiative. In addition, the study explores the number of participants who signed up yearly for each action and employs a brief descriptive analysis of the initiative.

The literature review explores how common Western notions of environmentalism are devoid of the spiritual, cultural, and relational aspects present within indigenous and Māori knowledge systems. It touches on the histories of capitalism and colonialism and how these have led to the consumptogenic society we are in. It aims to illustrate the nexus between the Māori and Western Eurocentric worlds.

He Whatu is the framework that has emerged from this case study as the means to respond to the primary research question. The framework was developed by analyzing the key themes of PKP over the years 2017 to 2021. He Whatu has five key elements: Identity, Language, Distance, Practicality, and Influence; each with three subcategories. It is activated through provoking key conversations to inform future community action.

text: A case study of Pipiri Ki A Papatūānuku This thesis is an examination and analysis of the environmental initiative Pipiri Ki A Papatūānuku, co-founded by Waimirirangi Ormsby (née Koopu-Stone) and myself, Tamoko Ormsby. The primary aim of this research was to achieve an understanding of the PKP initiative at the individual level and to inform future collective action at the community level. As such, my primary research question is:

How can Pipiri Ki A Papatūānuku inform community-scale action that contributes to our more-than-human relationship with Papatūānuku within our current capitalist settler-colonial context?

The study is part-autoethnographic in that it is informed by my personal reflections and experiences as a co-founder, operator, and participant of the initiative. In addition, the study explores the number of participants who signed up yearly for each action and employs a brief descriptive analysis of the initiative.

The literature review explores how common Western notions of environmentalism are devoid of the spiritual, cultural, and relational aspects present within indigenous and Māori knowledge systems. It touches on the histories of capitalism and colonialism and how these have led to the consumptogenic society we are in. It aims to illustrate the nexus between the Māori and Western Eurocentric worlds.

He Whatu is the framework that has emerged from this case study as the means to respond to the primary research question. The framework was developed by analyzing the key themes of PKP over the years 2017 to 2021. He Whatu has five key elements: Identity, Language, Distance, Practicality, and Influence; each with three subcategories. It is activated through provoking key conversations to inform future community action.

year: 2023