title: New Zealand women’s employment patterns: Diversity or homogeneity?

authors: Hillcoat-Nallétamby, Sarah

abstract: New Zealand has experienced sustained increases in women’s labour force participation since the post-war period. When observed across time, work patterns provide insights to the changing overall lifetime attachment of women to the labour market. Using data from the 1995 sample survey New Zealand Women: Family, Employment, Education, we present descriptive findings on the work patterns of women born between 1936 and 1965, and depict these patterns in terms of spells in and out of work. A cohort perspective is taken. We then proceed to summarise the details of these individual work histories using summary measures which can then be correlated with potential explanatory factors. The results show that by the age of 30, successive birth cohorts have experienced: (i) increasing complexities in their work and non-work trajectories; (ii) childbearing continues to depress women’s engagement in paid work across time; and (iii) the influence of educational attainment and ethnicity seems to be changing.

text: New Zealand women’s employment patterns: Diversity or homogeneity? New Zealand has experienced sustained increases in women’s labour force participation since the post-war period. When observed across time, work patterns provide insights to the changing overall lifetime attachment of women to the labour market. Using data from the 1995 sample survey New Zealand Women: Family, Employment, Education, we present descriptive findings on the work patterns of women born between 1936 and 1965, and depict these patterns in terms of spells in and out of work. A cohort perspective is taken. We then proceed to summarise the details of these individual work histories using summary measures which can then be correlated with potential explanatory factors. The results show that by the age of 30, successive birth cohorts have experienced: (i) increasing complexities in their work and non-work trajectories; (ii) childbearing continues to depress women’s engagement in paid work across time; and (iii) the influence of educational attainment and ethnicity seems to be changing.

year: 2004

title: Synthesis study of size-controlled noble metal nanoparticle systems of Re, Ir, and Os using AOT-reverse microemulsion based methodologies

authors: Soleimani Zohr Shiri, Mohammad

abstract: This thesis presents a novel methodology for synthesizing stable, very small nanoparticles (NPs) of rhenium (Re), iridium (Ir), and osmium (Os) using a reverse microemulsion (AOT-ME) system, with AOT as the negatively charged surfactant to form and stabilize the MEs. These noble metals are among the least studied in their NP form, making this research a valuable contribution to the field.
An important initial finding was the identification of a sulfite ion impurity in commercially sourced AOT, most likely introduced during industrial preparation. The reason for the apparent ability of AOT to reduce certain metals, such as Re, was previously unknown among researchers. Although this impurity is present in low concentrations, it became significant when larger quantities of AOT were used to stabilize ME systems, acting as an unintended/hidden reducing agent. While purification with activated carbon could reduce the impurity, it came at a considerable cost of the AOT reagent.
Using the AOT-ME system, Re, Ir, and Os NPs were successfully synthesized under ambient conditions with precise control over size and size distribution. Systematic investigation of synthesis parameters—including the water-to-surfactant concentration ratio (W factor) and temperature—revealed that these factors had a significant impact on NP size and stability. Across all three metals, the effect of the W factor was consistent, with higher W values generating larger, more polydisperse particles. While the AOT-ME system effectively maintained colloidal stability and controlled particle size for all three metals, it also played a specific role in slowing the tendency of Re NPs to oxidise into perrhenate.
A range of advanced characterization techniques, including UV-Vis spectroscopy, ESI-MS, FE-SEM/EDX, and HR-TEM, were employed to thoroughly analyse the synthesized NPs. UV-Vis confirmed the successful reduction of the metal precursors, while FE-SEM/EDX provided valuable information on surface morphology and elemental composition. HR-TEM offered detailed insights into the size and crystallinity of the NPs. Additionally, ESI-MS helped investigate the chemical stability of the colloidal aqueous solutions.
This thesis contributes to the field of noble metal NP synthesis by offering a reproducible method for controlling NP size and stability within AOT-ME systems. The findings provide valuable insights for optimizing synthesis protocols and broaden the potential applications of Re, Ir, and Os NPs in catalysis and materials science.

text: Synthesis study of size-controlled noble metal nanoparticle systems of Re, Ir, and Os using AOT-reverse microemulsion based methodologies This thesis presents a novel methodology for synthesizing stable, very small nanoparticles (NPs) of rhenium (Re), iridium (Ir), and osmium (Os) using a reverse microemulsion (AOT-ME) system, with AOT as the negatively charged surfactant to form and stabilize the MEs. These noble metals are among the least studied in their NP form, making this research a valuable contribution to the field.
An important initial finding was the identification of a sulfite ion impurity in commercially sourced AOT, most likely introduced during industrial preparation. The reason for the apparent ability of AOT to reduce certain metals, such as Re, was previously unknown among researchers. Although this impurity is present in low concentrations, it became significant when larger quantities of AOT were used to stabilize ME systems, acting as an unintended/hidden reducing agent. While purification with activated carbon could reduce the impurity, it came at a considerable cost of the AOT reagent.
Using the AOT-ME system, Re, Ir, and Os NPs were successfully synthesized under ambient conditions with precise control over size and size distribution. Systematic investigation of synthesis parameters—including the water-to-surfactant concentration ratio (W factor) and temperature—revealed that these factors had a significant impact on NP size and stability. Across all three metals, the effect of the W factor was consistent, with higher W values generating larger, more polydisperse particles. While the AOT-ME system effectively maintained colloidal stability and controlled particle size for all three metals, it also played a specific role in slowing the tendency of Re NPs to oxidise into perrhenate.
A range of advanced characterization techniques, including UV-Vis spectroscopy, ESI-MS, FE-SEM/EDX, and HR-TEM, were employed to thoroughly analyse the synthesized NPs. UV-Vis confirmed the successful reduction of the metal precursors, while FE-SEM/EDX provided valuable information on surface morphology and elemental composition. HR-TEM offered detailed insights into the size and crystallinity of the NPs. Additionally, ESI-MS helped investigate the chemical stability of the colloidal aqueous solutions.
This thesis contributes to the field of noble metal NP synthesis by offering a reproducible method for controlling NP size and stability within AOT-ME systems. The findings provide valuable insights for optimizing synthesis protocols and broaden the potential applications of Re, Ir, and Os NPs in catalysis and materials science.

year: 2025

title: Antipodean settler societies and their complexities: the Waitangi process in New Zealand and native title and the stolen generations in Australia

authors: Byrnes, Giselle

subjects: native title claim

abstract: This article considers the process of determining native title claims and responding to the revelation of forced Indigenous child removal in Australia, together with the Treaty of Waitangi claims process in New Zealand; each of which can be understood more broadly as a response to the aftermath and ongoing consequences of colonisation. We undertake this analysis comparatively, through an examination of the broad sweep of colonial history in both countries, followed by a more detailed consideration of the processes in question, as they have become manifest over the last decade or so in Australia and almost 30 years in New Zealand. We compare and contrast the institutions, epistemological and political preoccupations and language in each case, revealing various latent ironies and incongruities in the systems on both sides of the Tasman Sea.

text: Antipodean settler societies and their complexities: the Waitangi process in New Zealand and native title and the stolen generations in Australia This article considers the process of determining native title claims and responding to the revelation of forced Indigenous child removal in Australia, together with the Treaty of Waitangi claims process in New Zealand; each of which can be understood more broadly as a response to the aftermath and ongoing consequences of colonisation. We undertake this analysis comparatively, through an examination of the broad sweep of colonial history in both countries, followed by a more detailed consideration of the processes in question, as they have become manifest over the last decade or so in Australia and almost 30 years in New Zealand. We compare and contrast the institutions, epistemological and political preoccupations and language in each case, revealing various latent ironies and incongruities in the systems on both sides of the Tasman Sea.

year: 2008