title: Synthesis of Poly(galactaramides) from Alkylene- and Substituted Alkylenediammonium Galactarates

authors: Kiely, Donald E.

subjects: polyamides

abstract: Polyhydroxypolyamides (PHPAs) represent a class of synthetic polyamides derived from aldaric acid and diamine monomer units. This paper describes the synthesis of some poly(galactaramides), a class of polyhydroxypolyamides, that employs alkylene and substituted alkylenediammonium galactarate salts, with 1:1 molar equivalency of the diacid and diamine monomer components, as precursors for the polyamides. The salts were treated with acid/alcohol and then base in order to initiate the polymerization in methanol. The polyamides, labeled as prepolyamides, precipitated from solution and were then subjected to a second polymerization (postpolymerization) in a different solvent to produce a generally larger polyamide, labeled as a postpolyamide.

text: Synthesis of Poly(galactaramides) from Alkylene- and Substituted Alkylenediammonium Galactarates Polyhydroxypolyamides (PHPAs) represent a class of synthetic polyamides derived from aldaric acid and diamine monomer units. This paper describes the synthesis of some poly(galactaramides), a class of polyhydroxypolyamides, that employs alkylene and substituted alkylenediammonium galactarate salts, with 1:1 molar equivalency of the diacid and diamine monomer components, as precursors for the polyamides. The salts were treated with acid/alcohol and then base in order to initiate the polymerization in methanol. The polyamides, labeled as prepolyamides, precipitated from solution and were then subjected to a second polymerization (postpolymerization) in a different solvent to produce a generally larger polyamide, labeled as a postpolyamide.

year: 2009

title: Correlating tephras and cryptotephras using glass compositional analyses and numerical and statistical methods: review and evaluation

authors: Lowe, David J.

subjects: Tephra

abstract: We define tephras and cryptotephras and their components (mainly ash-sized particles of glass ± crystals in distal deposits) and summarize the basis of tephrochronology as a chronostratigraphic correlational and dating tool for palaeoenvironmental, geological, and archaeological research. We then document and appraise recent advances in analytical methods used to determine the major, minor, and trace elements of individual glass shards from tephra or cryptotephra deposits to aid their correlation and application. Protocols developed recently for the electron probe microanalysis of major elements in individual glass shards help to improve data quality and standardize reporting procedures. A narrow electron beam (diameter ~3-5 μm) can now be used to analyze smaller glass shards than previously attainable. Reliable analyses of ‘microshards’ (defined here as glass shards <32 µm in diameter) using narrow beams are useful for fine-grained samples from distal or ultra-distal geographic locations, and for vesicular or microlite-rich glass shards or small melt inclusions. Caveats apply, however, in the microprobe analysis of very small microshards (<=~5 µm in diameter), where particle geometry becomes important, and of microlite-rich glass shards where the potential problem of secondary fluorescence across phase boundaries needs to be recognised. Trace element analyses of individual glass shards using laser ablation inductively coupled plasma-mass spectrometry (LA-ICP-MS), with crater diameters of 20 μm and 10 μm, are now effectively routine, giving detection limits well below 1 ppm. Smaller ablation craters (<10 μm) can be subject to significant element fractionation during analysis, but the systematic relationship of such fractionation with glass composition suggests that analyses for some elements at these resolutions may be quantifiable. In undertaking analyses, either by microprobe or LA-ICP-MS, reference material data acquired using the same procedure, and preferably from the same analytical session, should be presented alongside new analytical data. 
In part 2 of the review, we describe, critically assess, and recommend ways in which tephras or cryptotephras can be correlated (in conjunction with other information) using numerical or statistical analyses of compositional data. Statistical methods provide a less subjective means of dealing with analytical data pertaining to tephra components (usually glass or crystals/phenocrysts) than heuristic alternatives. They enable a better understanding of relationships among the data from multiple viewpoints to be developed and help quantify the degree of uncertainty in establishing correlations. In common with other scientific hypothesis testing, it is easier to infer using such analysis that two or more tephras are different rather than the same. Adding stratigraphic, chronological, spatial, or palaeoenvironmental data (i.e. multiple criteria) is usually necessary and allows for more robust correlations to be made. A two-stage approach is useful, the first focussed on differences in the mean composition of samples, or their range, which can be visualised graphically via scatterplot matrices or bivariate plots coupled with the use of statistical tools such as distance measures, similarity coefficients, hierarchical cluster analysis (informed by distance measures or similarity or cophenetic coefficients), and principal components analysis (PCA). Some statistical methods (cluster analysis, discriminant analysis) are referred to as ‘machine learning’ in the computing literature. The second stage examines sample variance and the degree of compositional similarity so that sample equivalence or otherwise can be established on a statistical basis. This stage may involve discriminant function analysis (DFA), support vector machines (SVMs), canonical variates analysis (CVA), and ANOVA or MANOVA (or its two-sample special case, the Hotelling two-sample T² test). Randomization tests can be used where distributional assumptions such as multivariate normality underlying parametric tests are doubtful.
Compositional data may be transformed and scaled before being subjected to multivariate statistical procedures including calculation of distance matrices, hierarchical cluster analysis, and PCA. Such transformations may make the assumption of multivariate normality more appropriate. A sequential procedure using Mahalanobis distance and the Hotelling two-sample T² test is illustrated using glass major element data from trachytic to phonolitic Kenyan tephras. All these methods require a broad range of high-quality compositional data which can be used to compare ‘unknowns’ with reference (training) sets that are sufficiently complete to account for all possible correlatives, including tephras with heterogeneous glasses that contain multiple compositional groups. Currently, incomplete databases are tending to limit correlation efficacy. The development of an open, online global database to facilitate progress towards integrated, high-quality tephrostratigraphic frameworks for different regions is encouraged.

text: Correlating tephras and cryptotephras using glass compositional analyses and numerical and statistical methods: review and evaluation We define tephras and cryptotephras and their components (mainly ash-sized particles of glass ± crystals in distal deposits) and summarize the basis of tephrochronology as a chronostratigraphic correlational and dating tool for palaeoenvironmental, geological, and archaeological research. We then document and appraise recent advances in analytical methods used to determine the major, minor, and trace elements of individual glass shards from tephra or cryptotephra deposits to aid their correlation and application. Protocols developed recently for the electron probe microanalysis of major elements in individual glass shards help to improve data quality and standardize reporting procedures. A narrow electron beam (diameter ~3-5 μm) can now be used to analyze smaller glass shards than previously attainable. Reliable analyses of ‘microshards’ (defined here as glass shards <32 µm in diameter) using narrow beams are useful for fine-grained samples from distal or ultra-distal geographic locations, and for vesicular or microlite-rich glass shards or small melt inclusions. Caveats apply, however, in the microprobe analysis of very small microshards (<=~5 µm in diameter), where particle geometry becomes important, and of microlite-rich glass shards where the potential problem of secondary fluorescence across phase boundaries needs to be recognised. Trace element analyses of individual glass shards using laser ablation inductively coupled plasma-mass spectrometry (LA-ICP-MS), with crater diameters of 20 μm and 10 μm, are now effectively routine, giving detection limits well below 1 ppm. Smaller ablation craters (<10 μm) can be subject to significant element fractionation during analysis, but the systematic relationship of such fractionation with glass composition suggests that analyses for some elements at these resolutions may be quantifiable. In undertaking analyses, either by microprobe or LA-ICP-MS, reference material data acquired using the same procedure, and preferably from the same analytical session, should be presented alongside new analytical data. 
In part 2 of the review, we describe, critically assess, and recommend ways in which tephras or cryptotephras can be correlated (in conjunction with other information) using numerical or statistical analyses of compositional data. Statistical methods provide a less subjective means of dealing with analytical data pertaining to tephra components (usually glass or crystals/phenocrysts) than heuristic alternatives. They enable a better understanding of relationships among the data from multiple viewpoints to be developed and help quantify the degree of uncertainty in establishing correlations. In common with other scientific hypothesis testing, it is easier to infer using such analysis that two or more tephras are different rather than the same. Adding stratigraphic, chronological, spatial, or palaeoenvironmental data (i.e. multiple criteria) is usually necessary and allows for more robust correlations to be made. A two-stage approach is useful, the first focussed on differences in the mean composition of samples, or their range, which can be visualised graphically via scatterplot matrices or bivariate plots coupled with the use of statistical tools such as distance measures, similarity coefficients, hierarchical cluster analysis (informed by distance measures or similarity or cophenetic coefficients), and principal components analysis (PCA). Some statistical methods (cluster analysis, discriminant analysis) are referred to as ‘machine learning’ in the computing literature. The second stage examines sample variance and the degree of compositional similarity so that sample equivalence or otherwise can be established on a statistical basis. This stage may involve discriminant function analysis (DFA), support vector machines (SVMs), canonical variates analysis (CVA), and ANOVA or MANOVA (or its two-sample special case, the Hotelling two-sample T² test). Randomization tests can be used where distributional assumptions such as multivariate normality underlying parametric tests are doubtful.
Compositional data may be transformed and scaled before being subjected to multivariate statistical procedures including calculation of distance matrices, hierarchical cluster analysis, and PCA. Such transformations may make the assumption of multivariate normality more appropriate. A sequential procedure using Mahalanobis distance and the Hotelling two-sample T² test is illustrated using glass major element data from trachytic to phonolitic Kenyan tephras. All these methods require a broad range of high-quality compositional data which can be used to compare ‘unknowns’ with reference (training) sets that are sufficiently complete to account for all possible correlatives, including tephras with heterogeneous glasses that contain multiple compositional groups. Currently, incomplete databases are tending to limit correlation efficacy. The development of an open, online global database to facilitate progress towards integrated, high-quality tephrostratigraphic frameworks for different regions is encouraged.

year: 2017

title: Faith, politics and reconciliation: the Roman Catholic Church, New Zealand Maori and indigenous Australians

authors: O'Sullivan, Dominic

abstract: The Roman Catholic Church claims from Jesus Christ a mission to teach consistently religious ideals in accordance with its understanding of God’s constant truth. These ideals include the belief that human creation in the image and likeness of God establishes rights to dignity, to culture, to religious freedom, to self-determination and a share in the common good. These ideals form the basis of the unique contribution to human affairs which the Church claims it can make. Although these are religious goals for the Church, they require political realisation, which means that the Church cannot but be alert to the formation of alliances of common intellectual aspiration around concrete political issues so that secular expression and context can be given to the magisterium (the Church’s body of teaching). At the same time the Catholic hierarchy is conscious of a need for caution in how it responds to political events lest that religious mission be compromised by a perception of it as a partisan political lobby group, thus lessening its capacity to make its unique contribution to human affairs. 

The Second Vatican Council reaffirmed that the Church’s religious objectives do not exist in isolation from the political order because human law, which is developed through the secular political process, should conform to the religious natural law. Prior to the Council’s reaffirmation the Australian and New Zealand Churches generally, but not exclusively, understated or misunderstood this relationship and became impotent in challenging secular objectives inconsistent with religious aspiration. In contrast when the Church has accepted the relationship, as it has since the Second Vatican Council, it has positioned itself to identify opportunities to give secular context and expression to religious thought. Such opportunities increased from the 1960s onwards as political developments in both Australia and New Zealand saw a secular questioning of racism and a broadening of the parameters of secular political debate to the extent that established Catholic thought was shifted from the fringes to the widening mainstream of public opinion on indigenous policy. 

Although the Second Vatican Council required attention to the relationship between religious ends and political means, the changing secular environment was a significant factor in encouraging public advocacy in support of indigenous aspiration, which peaked in Australia in the 1990s with substantial Church interest in the native title debate and with the Church playing a leading role in the entrenchment of reconciliation - a religious concept - on the Australian political landscape. In New Zealand there has been an equal but less vocal interest in reconciliation because the political process itself established the Treaty of Waitangi as a political context for reconciliation and a context around which the Church has been able to focus its interest in the advancement of Maori aspiration. Yet, while the Treaty of Waitangi and the associated bicultural discourse have provided contexts for the expression of religious principle, they have also detracted from the Church’s use of its own magisterium as the moral authority for the articulation of its aspirations for Maori.

text: Faith, politics and reconciliation: the Roman Catholic Church, New Zealand Maori and indigenous Australians The Roman Catholic Church claims from Jesus Christ a mission to teach consistently religious ideals in accordance with its understanding of God’s constant truth. These ideals include the belief that human creation in the image and likeness of God establishes rights to dignity, to culture, to religious freedom, to self-determination and a share in the common good. These ideals form the basis of the unique contribution to human affairs which the Church claims it can make. Although these are religious goals for the Church, they require political realisation, which means that the Church cannot but be alert to the formation of alliances of common intellectual aspiration around concrete political issues so that secular expression and context can be given to the magisterium (the Church’s body of teaching). At the same time the Catholic hierarchy is conscious of a need for caution in how it responds to political events lest that religious mission be compromised by a perception of it as a partisan political lobby group, thus lessening its capacity to make its unique contribution to human affairs. 

The Second Vatican Council reaffirmed that the Church’s religious objectives do not exist in isolation from the political order because human law, which is developed through the secular political process, should conform to the religious natural law. Prior to the Council’s reaffirmation the Australian and New Zealand Churches generally, but not exclusively, understated or misunderstood this relationship and became impotent in challenging secular objectives inconsistent with religious aspiration. In contrast when the Church has accepted the relationship, as it has since the Second Vatican Council, it has positioned itself to identify opportunities to give secular context and expression to religious thought. Such opportunities increased from the 1960s onwards as political developments in both Australia and New Zealand saw a secular questioning of racism and a broadening of the parameters of secular political debate to the extent that established Catholic thought was shifted from the fringes to the widening mainstream of public opinion on indigenous policy. 

Although the Second Vatican Council required attention to the relationship between religious ends and political means, the changing secular environment was a significant factor in encouraging public advocacy in support of indigenous aspiration, which peaked in Australia in the 1990s with substantial Church interest in the native title debate and with the Church playing a leading role in the entrenchment of reconciliation - a religious concept - on the Australian political landscape. In New Zealand there has been an equal but less vocal interest in reconciliation because the political process itself established the Treaty of Waitangi as a political context for reconciliation and a context around which the Church has been able to focus its interest in the advancement of Maori aspiration. Yet, while the Treaty of Waitangi and the associated bicultural discourse have provided contexts for the expression of religious principle, they have also detracted from the Church’s use of its own magisterium as the moral authority for the articulation of its aspirations for Maori.

year: 2003