title: IntCal09 and Marine09 radiocarbon age calibration curves, 0-50,000yeats cal BP

authors: Reimer, Paula J.

subjects: radiocarbon

abstract: The IntCal04 and Marine04 radiocarbon calibration curves have been updated from 12 cal kBP (cal kBP is here defined as thousands of calibrated years before AD 1950), and extended to 50 cal kBP, utilizing newly available data sets that meet the IntCal Working Group criteria for pristine corals and other carbonates and for quantification of uncertainty in both the 14C and calendar timescales as established in 2002. No change was made to the curves from 0–12 cal kBP. The curves were constructed using a Markov chain Monte Carlo (MCMC) implementation of the random walk model used for IntCal04 and Marine04. The new curves were ratified at the 20th International Radiocarbon Conference in June 2009 and are available in the Supplemental Material at www.radiocarbon.org.

text: IntCal09 and Marine09 radiocarbon age calibration curves, 0-50,000yeats cal BP The IntCal04 and Marine04 radiocarbon calibration curves have been updated from 12 cal kBP (cal kBP is here defined as thousands of calibrated years before AD 1950), and extended to 50 cal kBP, utilizing newly available data sets that meet the IntCal Working Group criteria for pristine corals and other carbonates and for quantification of uncertainty in both the 14C and calendar timescales as established in 2002. No change was made to the curves from 0–12 cal kBP. The curves were constructed using a Markov chain Monte Carlo (MCMC) implementation of the random walk model used for IntCal04 and Marine04. The new curves were ratified at the 20th International Radiocarbon Conference in June 2009 and are available in the Supplemental Material at www.radiocarbon.org.

year: 2009

title: Spectroscopic and synthetic studies of lichen metabolites

authors: Ronaldson, Kathlyn Joy

abstract: Lichen metabolites from various Nephroma and Pseudocyphellaria species have been subjected to a number of spectroscopic and synthetic investigations. Hypoiodite reaction of 15α-acetoxyhopan-17(21)-en-24-ol yielded a complex mixture of products, while similar reaction of 7-oxohopan-22-ol resulted in cleavage of the side-chain. Preparation of an α-sulphenylated 15-ketone was achieved as the first step in a carbonyl transposition sequence. Complete assignment of the ¹³C nmr spectra of four pentacyclic and two ring A-cleaved stictane derivatives provided evidence of the boat-ring B. The low frequency infrared spectra of a number of stictane and hopane triterpenoids yielded structurally significant correlations. Two depsidonal constituents of N. australe were demonstrated to be hypostictic acid and hyposalazinic acid. The reactions of mercuric acetate with unsaturated compounds are reviewed and anomalous products of Jones reagent oxidation investigated.

text: Spectroscopic and synthetic studies of lichen metabolites Lichen metabolites from various Nephroma and Pseudocyphellaria species have been subjected to a number of spectroscopic and synthetic investigations. Hypoiodite reaction of 15α-acetoxyhopan-17(21)-en-24-ol yielded a complex mixture of products, while similar reaction of 7-oxohopan-22-ol resulted in cleavage of the side-chain. Preparation of an α-sulphenylated 15-ketone was achieved as the first step in a carbonyl transposition sequence. Complete assignment of the ¹³C nmr spectra of four pentacyclic and two ring A-cleaved stictane derivatives provided evidence of the boat-ring B. The low frequency infrared spectra of a number of stictane and hopane triterpenoids yielded structurally significant correlations. Two depsidonal constituents of N. australe were demonstrated to be hypostictic acid and hyposalazinic acid. The reactions of mercuric acetate with unsaturated compounds are reviewed and anomalous products of Jones reagent oxidation investigated.

year: 1980

title: Waiwharangi

authors: Maxwell, Te Kahautu

abstract: Haka. Lyrics/Musical score composed by Te Kahautu Maxwell. Performed by Ōpōtiki Mai Tawhiti (Kapa Haka group) (4mins)

Waiata: Tira Aroha
Whakaeke: Haere mai rā
Mōteatea: Te Pātere a Te Turuki
Poi: Iarararararī
Waiata ā ringa: Taku Mana Māori Motuhake
Haka: Waiwharangi
Whakawātea: Āio

text: Waiwharangi Haka. Lyrics/Musical score composed by Te Kahautu Maxwell. Performed by Ōpōtiki Mai Tawhiti (Kapa Haka group) (4mins)

Waiata: Tira Aroha
Whakaeke: Haere mai rā
Mōteatea: Te Pātere a Te Turuki
Poi: Iarararararī
Waiata ā ringa: Taku Mana Māori Motuhake
Haka: Waiwharangi
Whakawātea: Āio

year: 2020-02-06