title: Equilibrium and dynamic moisture adsorption behaviour of bloodmeal based bioplastic

authors: Lay, Mark C.

abstract: Bioplastics can be manufactured from protein or carbohydrate sources such as wheat gluten, corn, sun flower, keratin, casein, soy, gelatine and whey. A recently developed bioplastic is Novatein thermoplastic (NTP), which is produced from bloodmeal by adding water, urea, sodium sulphite, sodium dodecyl sulphate and tri-ethylene glycol (TEG), allowing it to be extruded and injection moulded. Bioplastics, compared to their petroleum counterparts, can readily adsorb or lose water, which then changes their physical properties such as tensile strength and glass transition temperature. NTP at different TEG and water contents was exposed to 20-85% relative humidity (RH) environments and change in mass recorded over 35 days to determine equilibrium and dynamic moisture adsorption behavior. Equilibrium behavior was modelled using modified Freundlich and Langmuir- Freundlich isotherms, and dynamic behavior modelled using Pilosof, Singh- ulshrestha, exponential, Langmuir-Freundlich and simple rate equations. Excellent fits were obtained for both isotherms and the last three rate equations gave best overall fits for dynamics. NTP adsorbed up to 28% by weight in water at 85% RH, reaching equilibrium within 20 days. Plastics with high TEG had a greater affinity for water but lower water adsorption rates, while dry plastic samples had a lower adsorption rate than wet samples. The two parameter Freundlich model and the exponential or simple rate model is recommended for modelling NTP equilibrium and dynamic water adsorption.

text: Equilibrium and dynamic moisture adsorption behaviour of bloodmeal based bioplastic Bioplastics can be manufactured from protein or carbohydrate sources such as wheat gluten, corn, sun flower, keratin, casein, soy, gelatine and whey. A recently developed bioplastic is Novatein thermoplastic (NTP), which is produced from bloodmeal by adding water, urea, sodium sulphite, sodium dodecyl sulphate and tri-ethylene glycol (TEG), allowing it to be extruded and injection moulded. Bioplastics, compared to their petroleum counterparts, can readily adsorb or lose water, which then changes their physical properties such as tensile strength and glass transition temperature. NTP at different TEG and water contents was exposed to 20-85% relative humidity (RH) environments and change in mass recorded over 35 days to determine equilibrium and dynamic moisture adsorption behavior. Equilibrium behavior was modelled using modified Freundlich and Langmuir- Freundlich isotherms, and dynamic behavior modelled using Pilosof, Singh- ulshrestha, exponential, Langmuir-Freundlich and simple rate equations. Excellent fits were obtained for both isotherms and the last three rate equations gave best overall fits for dynamics. NTP adsorbed up to 28% by weight in water at 85% RH, reaching equilibrium within 20 days. Plastics with high TEG had a greater affinity for water but lower water adsorption rates, while dry plastic samples had a lower adsorption rate than wet samples. The two parameter Freundlich model and the exponential or simple rate model is recommended for modelling NTP equilibrium and dynamic water adsorption.

year: 2013

title: 10-year survival comparison of two cemented implants in primary total hip arthroplasty for osteoarthritis: A New Zealand regional study

authors: Pearce, Amy

subjects: total hip replacement

abstract: Introduction
Compare 10-year survival of the cemented highly crosslinked polyethylene Exeter® Rimfit™ (Rimfit) Cup and its predecessor, the ultra-high molecular weight polyethylene Exeter® Contemporary Flanged Cup™ (ECF), both with an Exeter® V40™ stem, in primary total hip arthroplasty (THA) for osteoarthritis in the Bay of Plenty region of NZ.

Method
We extracted national registry data for THA surgeries in the region between 1 January 2003 and 30 June 2023 and report the 10-year survival and reasons for revision of the two fully cemented implants (n = 495). We compared standard Kaplan-Meier estimates using the log-rank test. Cox proportional hazard models investigated the potential influence of six patient variables on the survival of each implant: sex, age, body mass index (BMI), ethnicity, American Society of Anesthesiologists (ASA) rating, and funding source (public/private).

Results
No statistically significant difference in 10-year survival rate between the implants (p = 0.334) (ECF 95.6% [93.4, 97.9], Rimfit 97.0% [95.9, 98.2]) or statistically significant difference in revision reasons between the implants (p = 0.09) was noted. Cox regression revealed no statistically significant influence of any of the six patient variables on the 10-year survival of the ECF (p = 0.584) or Rimfit (p = 0.611).

Conclusion
Both implants exceeded 95% survival at 10-years, which is favourable compared to the corresponding 94.8% national survivorship of cemented implants in NZ. There is no statistically significant difference in the 10-year survival rate or reasons for revision of the two cemented implants compared in this region. The Rimfit appears a suitable alternative to the ECF, from a survival and revision perspective.

text: 10-year survival comparison of two cemented implants in primary total hip arthroplasty for osteoarthritis: A New Zealand regional study Introduction
Compare 10-year survival of the cemented highly crosslinked polyethylene Exeter® Rimfit™ (Rimfit) Cup and its predecessor, the ultra-high molecular weight polyethylene Exeter® Contemporary Flanged Cup™ (ECF), both with an Exeter® V40™ stem, in primary total hip arthroplasty (THA) for osteoarthritis in the Bay of Plenty region of NZ.

Method
We extracted national registry data for THA surgeries in the region between 1 January 2003 and 30 June 2023 and report the 10-year survival and reasons for revision of the two fully cemented implants (n = 495). We compared standard Kaplan-Meier estimates using the log-rank test. Cox proportional hazard models investigated the potential influence of six patient variables on the survival of each implant: sex, age, body mass index (BMI), ethnicity, American Society of Anesthesiologists (ASA) rating, and funding source (public/private).

Results
No statistically significant difference in 10-year survival rate between the implants (p = 0.334) (ECF 95.6% [93.4, 97.9], Rimfit 97.0% [95.9, 98.2]) or statistically significant difference in revision reasons between the implants (p = 0.09) was noted. Cox regression revealed no statistically significant influence of any of the six patient variables on the 10-year survival of the ECF (p = 0.584) or Rimfit (p = 0.611).

Conclusion
Both implants exceeded 95% survival at 10-years, which is favourable compared to the corresponding 94.8% national survivorship of cemented implants in NZ. There is no statistically significant difference in the 10-year survival rate or reasons for revision of the two cemented implants compared in this region. The Rimfit appears a suitable alternative to the ECF, from a survival and revision perspective.

year: 2025

title: Pinepine te Kura

authors: Maxwell, Te Kahautu

abstract: Whakaeke (entrance). Lyrics/Musical Score composed and choreographed by Te Kahautu Maxwell. Performed by Ōpōtiki Mai Tawhiti (Kapa Haka group) (3mins)

Waiata ā Tira: Aroha
Whakaeke: Pinepine Te Kura, Hau Te Kura
Mōteatea: Te Ao o Te Pārerā
Waiata ā Ringa: E pā to reo, Te Matatini, Herewini Parata
Poi: E ia e ia
Haka: Te Kōtiritiri, Te Kōtaratara
Whakawātea: Ōranga Tōiti, tōnui kōrero

text: Pinepine te Kura Whakaeke (entrance). Lyrics/Musical Score composed and choreographed by Te Kahautu Maxwell. Performed by Ōpōtiki Mai Tawhiti (Kapa Haka group) (3mins)

Waiata ā Tira: Aroha
Whakaeke: Pinepine Te Kura, Hau Te Kura
Mōteatea: Te Ao o Te Pārerā
Waiata ā Ringa: E pā to reo, Te Matatini, Herewini Parata
Poi: E ia e ia
Haka: Te Kōtiritiri, Te Kōtaratara
Whakawātea: Ōranga Tōiti, tōnui kōrero

year: 2023-02-22