title: Assessment of the Potential of Waste Copper Chromium and Arsenic (CCA)-Treated Timber Fibre Reinforced Polypropylene Composites for Construction

authors: Nelson, Jacob

abstract: This paper investigates the potential of recycling waste copper chromium and arsenic (CCA)-treated timber for use as a reinforcement material in wood–plastic composites (WPCs) produced for use in construction, including an assessment of mechanical properties and the leaching of heavy metals. Wood flour was obtained through mechanical grinding, and fibres were obtained through alkaline digestion followed by bleaching. Composites produced with 40 wt.% bleached fibres showed increased tensile strength from 18.5 MPa for the polypropylene used as the matrix to 27.6 MPa. Likewise, the Young’s modulus was increased from 0.84 to 2.33 GPa. The treatment of fibres was found to reduce arsenic concentration by up to 99.9%. Furthermore, the arsenic in the leachate from composites was found to decrease from 41.29 to 0.07 ppb when comparing CCA-treated wood flour composites to bleached fibre composites. The composites’ material properties indicate that the use of end-of-life CCA-treated timber could be used to produce a composite material that could be used in New Zealand’s building sector to meet the requirements of semi-structural applications.

text: Assessment of the Potential of Waste Copper Chromium and Arsenic (CCA)-Treated Timber Fibre Reinforced Polypropylene Composites for Construction This paper investigates the potential of recycling waste copper chromium and arsenic (CCA)-treated timber for use as a reinforcement material in wood–plastic composites (WPCs) produced for use in construction, including an assessment of mechanical properties and the leaching of heavy metals. Wood flour was obtained through mechanical grinding, and fibres were obtained through alkaline digestion followed by bleaching. Composites produced with 40 wt.% bleached fibres showed increased tensile strength from 18.5 MPa for the polypropylene used as the matrix to 27.6 MPa. Likewise, the Young’s modulus was increased from 0.84 to 2.33 GPa. The treatment of fibres was found to reduce arsenic concentration by up to 99.9%. Furthermore, the arsenic in the leachate from composites was found to decrease from 41.29 to 0.07 ppb when comparing CCA-treated wood flour composites to bleached fibre composites. The composites’ material properties indicate that the use of end-of-life CCA-treated timber could be used to produce a composite material that could be used in New Zealand’s building sector to meet the requirements of semi-structural applications.

year: 2023

title: Validation and Cultural Adaptation of the Motors of COVID-19 Vaccination Acceptance Scale (MoVac-COVID19S) in German

authors: Adu, Peter

abstract: <jats:p> Abstract: Background: Context-specific standardized psychometric instruments are essential for ensuring valid and reliable assessment of health outcomes across diverse populations to aid the advancement of research and health-related interventions. However, instruments measuring attitudes toward vaccinations are lacking in the extant literature. Therefore, we performed a cross-cultural adaptation of the Motors of COVID-19 Vaccination Acceptance Scale (MoVac-COVID19S) in Germany. Method: During the months of June and July 2022, 475 individuals aged 18 years and older from the general population of Germany participated in an online cross-sectional survey. Participants responded to five demographic questions, a measure of COVID-19 vaccine uptake willingness, and the MoVac-COVID19S. Confirmatory Factor Analysis (CFA) fit indices were used to evaluate the factor structures of the MoVac-COVID19S. Results: The CFA revealed that all examined factor structures of both the 9-item and 12-item versions of the MoVac-COVID19S were acceptable among the sample. Overall, CFI, GFI, and TLI values were higher than 0.95; RMSEA and SRMR values were all less than 0.08 for all the estimated models. The one-factor model of the 9-item version of the MoVac-COVID19S exhibited best fits indices compared to the one-factor and four-factor structures of the 12-item version of the scale. The bifactor model revealed that the general factor explained a higher percentage of the Explained Common Variance (ECV; ranging from 55% to 94%) in the majority of the items, compared to the specific factors. The scale was found to demonstrate convergent validity with related measures. Conclusion: The German version of the MoVac-COVID19S should be considered a unidimensional rather than a multidimensional measure. Although the 9-item version of the scale performed better among the sample compared to the 12-item version, the overall scores of both versions were found to be valid and reliable measures of attitudes toward COVID-19 vaccinations. The MoVac-COVID19S has the potential to be adapted for assessing attitudes toward any future vaccination programs. Limitations: While our study sampled only the general German population, the criticisms of CFA warrant further research using advanced methods, such as the Rasch model, and subgroups. </jats:p>

text: Validation and Cultural Adaptation of the Motors of COVID-19 Vaccination Acceptance Scale (MoVac-COVID19S) in German <jats:p> Abstract: Background: Context-specific standardized psychometric instruments are essential for ensuring valid and reliable assessment of health outcomes across diverse populations to aid the advancement of research and health-related interventions. However, instruments measuring attitudes toward vaccinations are lacking in the extant literature. Therefore, we performed a cross-cultural adaptation of the Motors of COVID-19 Vaccination Acceptance Scale (MoVac-COVID19S) in Germany. Method: During the months of June and July 2022, 475 individuals aged 18 years and older from the general population of Germany participated in an online cross-sectional survey. Participants responded to five demographic questions, a measure of COVID-19 vaccine uptake willingness, and the MoVac-COVID19S. Confirmatory Factor Analysis (CFA) fit indices were used to evaluate the factor structures of the MoVac-COVID19S. Results: The CFA revealed that all examined factor structures of both the 9-item and 12-item versions of the MoVac-COVID19S were acceptable among the sample. Overall, CFI, GFI, and TLI values were higher than 0.95; RMSEA and SRMR values were all less than 0.08 for all the estimated models. The one-factor model of the 9-item version of the MoVac-COVID19S exhibited best fits indices compared to the one-factor and four-factor structures of the 12-item version of the scale. The bifactor model revealed that the general factor explained a higher percentage of the Explained Common Variance (ECV; ranging from 55% to 94%) in the majority of the items, compared to the specific factors. The scale was found to demonstrate convergent validity with related measures. Conclusion: The German version of the MoVac-COVID19S should be considered a unidimensional rather than a multidimensional measure. Although the 9-item version of the scale performed better among the sample compared to the 12-item version, the overall scores of both versions were found to be valid and reliable measures of attitudes toward COVID-19 vaccinations. The MoVac-COVID19S has the potential to be adapted for assessing attitudes toward any future vaccination programs. Limitations: While our study sampled only the general German population, the criticisms of CFA warrant further research using advanced methods, such as the Rasch model, and subgroups. </jats:p>

year: 2023-12-01

title: Blue-lip'd cannibal ladies: The allure of the exotic in the illicit Resolution Journal of Gunner John Marra

authors: Ryan, Tom

subjects: John Marra

abstract: Discusses the history and content of the “Journal of the Resolution’s Voyage”, an unauthorized and illicitly published account of Cook’s second voyage of exploration in the Antipodes, by Gunner John Marra of the Resolution’s crew.

text: Blue-lip'd cannibal ladies: The allure of the exotic in the illicit Resolution Journal of Gunner John Marra Discusses the history and content of the “Journal of the Resolution’s Voyage”, an unauthorized and illicitly published account of Cook’s second voyage of exploration in the Antipodes, by Gunner John Marra of the Resolution’s crew.

year: 2001