1990L0128 — EN — 01.04.1996 — 001.001 — 1
This document is meant purely as a documentation tool and the institutions do not assume any liability for its contents
►B COMMISSION DIRECTIVE
of 23February 1990
relating to plastics materials and articles intended to come into contact with foodstuffs
(90/128/EEC)
(OJ L 75, 21.3.1990, p. 19)
Amended by:
OfficialJournal
No page date
►M1 Commission Directive 92/39/EEC of 14 May 1992 L 168 21 23.6.1992
►M2 Commission Directive 93/9/EEC of 15 March 1993 L 90 26 14.4.1993
►M3 Commission Directive 95/3/EC of 14 February 1995 L 41 44 23.2.1995
►M4 Commission Directive 96/11/EC of 5 March 1996 L 61 26 12.3.1996
Corrected by:
►C1 Corrigendum, OJ L 349, 13.12.1990, p. 26 (90/128)
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COMMISSION DIRECTIVE
of 23February 1990
relating to plastic materials and articles intended to come into
contact with foodstuffs
(90/128/EEC)
THE COMMISSION OF THE EUROPEAN COMMUNITIES,
Having regard to the Treaty establishing the European Economic
Community,
Having regard to CouncilDirective 89/109/EEC of 21 December 1988
on the approximation of the laws of the Member States relating tomaterials and articles intended to come into contact with foodstuffs (
1),
and in particular Article 3 thereof,
Whereas Article 2 of Directive 89/109/EEC lays down that materials
and articles, in their finished state, must not transfer their constituents tofoodstuffs in quantities which could endanger human health or bringabout an unacceptable change in the composition of the foodstuffs;
Whereas, in order to achieve this objective in the case of plastics
materials and articles, a suitable instrument is a specific Directivewithin the meaning of Article 3 of Directive 89/109/EEC, the generalprovisions of which are also applicable to the case in question;
Whereas the scope of this Directive must coincide with that of Council
Directive 82/711/EEC (
2);
Whereas since the rules established in this Directive are not suitable for
ion-exchange resins, these materials and articles will be covered by asubsequent specific Directive;
Whereas the establishment of a list of approved substances accompa-
nied by a limit on overall migration and, where necessary, by otherspecific restrictions will be sufficient to achieve the objective laid downin Article 2 of Directive 89/109/EEC;
Whereas the stage reached in the work at Community level does not yet
permit adoption of a complete list of the authorized substances applic-able to all types of plastics materials and articles and therefore thesubstances which are currently used in at least one Member State cancontinue to be used pending a decision on inclusion in the Communitylist; whereas this Directive will accordingly be extended in due courseto the substances and sectors provisionally excluded;
Whereas the overall migration limit is a measure of the inertness of the
materialand prevents an unacceptabl e change in the composition of thefoodstuffs, and, moreover, reduces the need for a large number ofspecific migration limits or other restrictions, thus giving effectivecontrol;
Whereas Directive 82/711/EEC lays down the basic rules necessary for
testing migration of the constituents of plastics materials and articlesand CouncilDirective 85/572/EEC (
3) establishes the list of simulants to
be used in the migration tests;
Whereas CouncilDirective 78/142/EEC (4) lays down limits for the
quantity of vinyl chloride present in plastics materials and articlesprepared with this substance and for the quantity of vinylchl oridereleased by these materials and articles, and Commission Directives
(1) OJ No L 40, 11. 2. 1989, p. 38.
(2) OJ No L 297, 23. 10. 1982, p. 26.
(3) OJ No L 372, 31. 12. 1985, p. 14.
(4) OJ No L 44, 15. 2. 1978, p. 15.
1990L0128 — EN — 01.04.1996 — 001.001 — 3
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80/766/EEC (1) and 81/432/EEC (2) establish the Community methods
of analysis for controlling these limits;
Whereas Commission Directive 80/590/EEC (3) determines the symbol
that may accompany any materialand articl e intended to come intocontact with foodstuffs;
Whereas in view of potential liability, there is a need for the written
declaration provided for in Article 6 (5) of Directive 89/109/EEC when-ever professional use is made of plastics materials and articles whichare not by their nature clearly intended for food use;
Whereas, in accordance with Article 3 of Directive 89/109/EEC, the
Scientific Committee for Food has been consulted on the provisionsliable to affect public health;
Whereas the measures provided for in this Directive are in accordance
with the opinion of the Standing Committee on Foodstuffs,
HAS ADOPTED THIS DIRECTIVE:
Article 1
1. This Directive is a specific Directive within the meaning of Article
3 of Directive 89/109/EEC.
2. This Directive shall apply to plastics materials and articles and
parts thereof:
(a) consisting exclusively of plastics; or
(b) composed of two or more layers of materials, each consisting
exclusively of plastics, which are bound together by means ofadhesives or by any other means,
which, in the finished product state, are intended to come into contact or
are brought into contact with foodstuffs and are intended for thatpurpose.
3. For the purposes of this Directive, ‘plastics'shall mean the organic
macromolecular compounds obtained by polymerization, polycondensa-tion, polyaddition or any other similar process from molecules with alower molecular weight or by chemical alteration of natural macromole-cules. Silicones and other similar macromolecular compounds shall alsobe regarded as plastics. Other substances or matter may be added tosuch macromolecular compounds.
However, the following shall not be regarded as ‘plastics':
(i) varnished or unvarnished regenerated cellulose film, covered by
CouncilDirective 83/229/EEC (
4), as amended by Directive 86/
388/EEC (5);
(ii) elastomers and natural and synthetic rubber;
(iii) paper and paperboard, whether modified or not by the addition of
plastics;
(iv) surface coatings obtained from:
— paraffin waxes, including synthetic paraffin waxes, and/or
micro-crystalline waxes,
— mixtures of the waxes listed in the first indent with each other
and/or with plastics;
(v) ion-exchange resins.
4. This Directive shall not apply, until further action by the Commis-
sion, to materials and articles composed of two or more layers, one ormore of which does not consist exclusively of plastics, even if the one
(1) OJ No L 213, 16. 8. 1980, p. 42.
(2) OJ No L 167, 24. 6. 1981, p. 6.
(3) OJ No L 151, 19. 6. 1980, p. 21.
(4) OJ No L 123, 11. 5. 1983, p. 31.
(5) OJ No L 228, 14. 8. 1986, p. 32.
1990L0128 — EN — 01.04.1996 — 001.001 — 4
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intended to come into direct contact with foodstuffs does consist exclu-sively of plastics.
Article 2
Plastics materials and articles shall not transfer their constituents to
foodstuffs in quantities exceeding 10 milligrams per square decimetre ofsurface area of materialor articl e (mg/dm
2) (overall migration limit).
However, this limit shall be 60 milligrams of the constituents releasedper kilogram of foodstuff (mg/kg) in the following cases:
(a) articles which are containers or are comparable to containers or
which can be filled, with a capacity of not less than 500 millilitres(ml) and not more than 10 litres (l);
(b) articles which can be filled and for which it is impracticable to
estimate the surface area in contact with foodstuffs;
(c) caps, gaskets, stoppers or similar devices for sealing.
Article 3
1. Only those monomers and other starting substances listed in
Annex II, Sections A and B may be used for the manufacture of plasticsmaterials and articles subject to the restrictions specified.
2. From the date of notification of this Directive, the list in Annex II,
Section A may be amended:
— either by adding substances listed in Annex II, Section B, according
to the criteria in Annex II of Directive 89/109/EEC, or
— by including ‘new substances', i. e. substances which are listed
neither in Section A nor in Section B of Annex II, according toArticle 3 of Directive 89/109/EEC.
3. From the date of notification of this Directive no Member State
shall authorize any new substance for use within its territory exceptunder the procedure in Article 4 of Directive 89/109/EEC.
▼
M4
4. As from 1 January 2002, only those monomers and other startingsubstances listed in Annex II, Section A, shall be used for the manufac-ture of plastic materials and articles, subject to the restrictions specifiedtherein. However, the substances listed in Annex II, Section B, may bedeleted before the abovementioned date if the data requested for inclu-sion in Section A are not supplied in time to permit their evaluation bythe Scientific Committee for Food.
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5. However the lists appearing in Annex II, Sections A and B do notyet include monomers and other starting substances used only in themanufacture of:
— surface coatings obtained from resinous or polymerized products in
liquid, powder or dispersion form, such as varnishes, lacquers,paints, etc.,
— silicones,— epoxy resins,— products obtained by means of bacterialfermentation,— adhesives and adhesion promoters,— printing inks.
▼
M3
Article 3a
An incomplete list of additives which may be used for the manufacture
of plastics materials and articles is set out in Annex III.
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Article 4
The specific migration limits in the list set out in Annex II are
expressed in mg/kg. However, such limits are expressed in mg/dm2in
the following cases:
(a) articles which are containers or are comparable to containers or
which can be filled, with a capacity of less than 500 ml or morethan 10 l;
(b) sheet, film or other materials which cannot be filled or for which it
is impracticable to estimate the relationship between the surfacearea of such materials and the quantity of foodstuff in contacttherewith.
In these cases, the limits set out in Annex II, expressed in mg/kg shall
be divided by the conventionalconversion factor of 6 in order toexpress them in mg/dm
2.
Article 5
1. Verification of compliance with the migration limits shall be
carried out in accordance with the rules laid down in Directives 82/711/EEC and 85/572/EEC and the further provisions set out in Annex I.
2. The verification of compliance with the specific migration limits
provided for in paragraph 1 shall not be compulsory, if it can beestablished that compliance with the overall migration limit laid downin Article 2 implies that the specific migration limits are not exceeded.
▼
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3. The verification of compliance with the specific migration limitsprovided for in paragraph 1 shall not be compulsory, if it can beestablished that, by assuming complete migration of the residualsubstance in the material or article, it cannot exceed the specific limit ofmigration.
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Article 6
1. At the marketing stages other than the retailstages, the pl astics
materials and articles which are intended to be placed in contact withfoodstuffs shall be accompanied by a written declaration in accordancewith Article 6 (5) of Directive 89/109/EEC.
2. Paragraph 1 does not apply to plastics materials and articles which
by their nature are clearly intended to come into contact with foodstuffs.
Article 7
1. The Member States shall bring into force the laws, regulations and
administrative provisions necessary to comply with this Directive notlater than 31 December 1990. They shall forthwith inform the Commis-sion thereof.
2. Member States shall:
— permit the trade in and use of plastics materials and articles
complying with this Directive before 1 January 1991,
— prohibit trade in and use of plastics materials and articles intended
to come into contact with foodstuffs and which do not comply withthis Directive as from 1 January 1993.
Article 8
This Directive is addressed to the Member States.
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ANNEX I
FURTHER PROVISIONS APPLICABLE WHEN CHECKING COMPLI-
ANCE WITH THE MIGRATION LIMITS
General provisions
1. When comparing the results of the migration tests specified in the Annex to
Directive 82/711/EEC, the specific gravity of all the simulants should conven-tionally be assumed to be 1. Milligrams of substance(s) released per litre ofsimulant (mg/l) will thus correspond numerically to milligrams ofsubstance(s) released per kilogram of simulant and, taking into account theprovisions laid down in Directive 85/572/EEC, to milligrams of substance(s)released per kilogram of foodstuff.
2. Where the migration tests are carried out on samples taken from the material
or article or on samples manufactured for the purpose, and the quantities offoodstuff or simulant placed in contact with the sample differ from thoseempl oyed in the actualconditions under which the materialor articl e is used,the results obtained should be corrected by applying the following formula:
M=m.a
2
a1.q. 1 000
Where:
M is the migration in mg/kg;m is the mass in mg of substance released by the sample as determined by
the migration test;
a
1is the surface area in dm2of the sample in contact with the foodstuff or
simulant during the migration test;
a2is the surface area in dm2of the materialor articl e in realconditions of
use;
q is the quantity in grams of foodstuff in contact with the materialor articl e
in realconditions of use.
3. The determination of migration is carried out on the materialor articl e or, if
that is impracticable, using either specimens taken from the material or articleor, where appropriate, specimens representative of this materialor articl e.
The sample shall be placed in contact with the foodstuff or simulant in a
manner representing the contact conditions in actualuse. For this purpose, thetest shall be performed in such a way that only those parts of the sampleintended to come into contact with foodstuffs in actualuse wil lbe in contactwith the foodstuff or simulant. This condition is particularly important in thecase of materials and articles comprising several layers, for closures, etc.
The migration testing of caps, gaskets, stoppers or similar devices for sealing
must be carried out on these articles by applying them to the containers forwhich they are intended in a manner which corresponds to the conditions ofclosing in normal or foreseeable use.
It shall in all cases be permissible to demonstrate compliance with migration
limits by the use of a more severe test.
4. In accordance with the provisions set out in Article 5 of the present Directive,
the sample of the material or article is placed in contact with the foodstuff orappropriate simulant for a period and at a temperature which are chosen byreference to the contact conditions in actualuse, in accordance with the rul eslaid down in Directives 82/711/EEC and 85/572/EEC. At the end of theprescribed time, the anal yticaldetermination of the totalquantity ofsubstances (overall migration) and/or the specific quantity of one or moresubstances (specific migration) released by the sample is carried out on thefoodstuff or simulant.
5. Where a materialor articl e is intended to come into repeated contact with
foodstuffs, the migration test(s) shall be carried out three times on a singlesample in accordance with the conditions laid down in Directive 82/711/EECusing another sample of the food or simulant(s) on each occasion. Its compli-ance shall be checked on the basis of the level of the migration found in thethird test. However, if there is conclusive proof that the level of the migrationdoes not increase in the second and third tests and if the migration limit(s) is(are) not exceeded on the first test, no further test is necessary.
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Special provisions relating to overall migration
6. If the aqueous simulants specified in Directives 82/711/EEC and 85/572/EEC
are used, the anal yticaldetermination of the totalquantity of substancesreleased by the sample may be carried out by evaporation of the simulant andweighing of the residue.
If rectified olive oil or any of its substitutes is used, the procedure given
below may be followed.
The sample of the material or article is weighed before and after contact with
the simulant. The simulant absorbed by the sample is extracted and deter-mined quantitatively. The quantity of simulant found is subtracted from theweight of the sample measured after contact with the simulant. The differencebetween the initialand corrected finalweights represents the overal lmigrationof the sample examined.
Where a materialor articl e is intended to come into repeated contact with
foodstuffs and it is technically impossible to carry out the test described inparagraph 5, modifications to that test are acceptable, provided that theyenable the level of migration occurring during the third test to be determined.One of these possible modifications is described below.
The test is carried out on three identical samples of the material or article.
One of these shall be subjected to the appropriate test and the overall migra-tion determined (M
1). The second and third samples shall be subjected to the
same conditions of temperature but the period of contact shall be two andthree times that specified and overall migration determined in each case (M
2and M3, respectively).
The material or article shall be deemed to be in compliance provided that
either M1or M3—M2do not exceed the overall migration limit.
7. A material or article that exceeds the overall migration limit by an amount not
greater than the analytical tolerance mentioned below should therefore bedeemed to be in compliance with this Directive.
The following analytical tolerances have been observed:
— 20 mg/kg or 3 mg/dm
2in migration tests using rectified olive oil or
substitutes,
— 6 mg/kg or 1 mg/dm2in migration tests using the other simulants
referred to in Directives 82/711/EEC and 85/572/EEC.
8. Without prejudice to the provisions of Article 3 (2) of Directive 82/711/EEC,
migration tests using rectified olive oil or substitutes shall not be carried outto check compliance with the overall migration limit in cases where there isconclusive proof that the specified analytical method is inadequate from atechnicalstandpoint.
In any such case, for substances exempt from specific migration limits or
other restrictions in the list provided in Annex II, a generic specific migrationlimit of 60 mg/kg or 10 mg/dm
2, according to the case, is applied. However
the sum of all specific migration determined shall not exceed the overallmigration limit.
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ANNEX II
LIST OF MONOMERS AND OTHER STARTING SUBSTANCES WHICH
MAY BE USED IN THE MANUFACTURE OF PLASTIC MATERIALS
AND ARTICLES
General introduction
1. This Annex contains the list of monomers or other starting substances. The
list includes:
— substances undergoing polymerization, which includes polycondensation,
polyaddition or any other similar process, to manufacture macromole-cules,
— natural or synthetic macromolecular substances used in the manufacture of
modified macromolecules, if the monomers or the other startingsubstances required to synthesize them are not included in the list,
— substances used to modify existing natural or synthetic macromolecular
substances.
2. The list does not include the salts (including double salts and acid salts) of
aluminium, ammonium, calcium, iron, magnesium, potassium, sodium andzinc of the authorized acids, phenols or alcohols which are also authorized.However, names containing ‘… acid(s), salts' appear in the lists if the corre-sponding free acid(s) is (are) not mentioned. In such cases, the meaning of theterm ‘salts' is ‘salts of aluminium, ammonium, calcium, iron, magnesium,potassium, sodium and zinc'.
3. The list also does not include the following substances although they may be
present:
(a) substances which could be present in the finished product as:
— impurities in the substances used,— reaction intermediates,— decomposition products;
(b) oligomers and natural or synthetic macromolecular substances as well as
their mixtures, if the monomers or starting substances required to synthe-size them are included in the list;
(c) mixtures of the authorized substances.
The materials and articles which contain the substance indicated under (a), (b)
and (c) shall comply with the requirements stated in Article 2 of Directive89/109/EEC.
4. Substances shal lbe of good technicalqual ity ►
M3as regards the purity
criteria◄.
5. The list contains the following information:
— column 1 (PM/REF. No): the EEC packaging material references number
of the substance on the list,
— column 2 (CAS No): the CAS (Chemical Abstracts Service) Registry
number,
— column 3 (Name): the chemical name,— column 4 (Restrictions). These may include:
— specific migration limit (SML),— maximum permitted quantity of the ‘residual'substance in the material
or article (QM),
— any other restriction specifically mentioned.
6. If a substance appearing on the list as an individual compound is also covered
by a generic term, the restrictions applying to this substance shall be thoseindicated for the individualcompound.
7. Where there is any inconsistency between the CAS number and the chemical
name, the chemicalname shal ltake precedence over the CAS number. If thereis an inconsistency between the CAS number reported in EINECS and theCAS Registry, the CAS number in the CAS Registry shall apply.
8. A number of abbreviations or expressions are used in column 4 of the table,
the meanings of which are as follows:
DL = detection limit of the method of analysis;
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PM/REF No CAS No Name Restrictions
(1) (2) (3) (4)FP = finished materialor articl e;
NCO = isocyanate moiety;
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ND = not detectable.
For the purpose of this Directive ‘not detectable'means that the
substance should not be detected by a validated method ofanalysis which should detect it at the detection limit (DL)specified.
If such a method does not currently exist, an analytical method
with appropriate performance characteristics at the detectionlimit may be used, pending the development of a validatedmethod.
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QM = maximum permitted quantity of the ‘residual' substance in the
materialor articl e;
QM (T) = maximum permitted quantity of the ‘residual' substance in the
materialor articl e expressed as totalof moiety or substance(s)indicated.
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For the purpose of this Directive ‘QM (T)' means that the
maximum permitted quantity of the ‘residual' substance in thematerial or article should be determined by a validated methodof analysis at the specified limit. If such a method does notcurrently exist, an analytical method with appropriateperformance characteristics at the specified limit may be used,pending the development of a validated method.
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SML = specific migration limit in food or in food simulant, unless it is
specified otherwise.
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For the purpose of this Directive ‘SML' means that the specific
migration of the substance should be determined by a validatedmethod of analysis at the specified limit. If such a method doesnot currently exist, an analytical method with appropriateperformance characteristics at the specified limit may be used,pending the development of a validated method.
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SML (T) = specific migration limit in food or in food simulant expressed
as totalof moiety or substance(s) indicated.
▼M2
For the purpose of this Directive ‘SML (T)' menas that the
specific migration of the substances should be determined by avalidated method of analysis at the specified limit. If such amethod does not currently exist, an analytical method withappropriate performance characteristics at the specified limitmay be used, pending the development of a validated method.
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SECTION A
LIST OF AUTHORIZED MONOMERS AND OTHER STARTING
SUBSTANCES
10030 000514-10-3 Abietic acid
10060 000075-07-0 Acetaldehyde
10090 000064-19-7 Acetic acid
10120 000108-05-4 Acetic acid, vinylester SML = 12 mg/kg
10150 000108-24-7 Acetic anhydride
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PM/REF No CAS No Name Restrictions
(1) (2) (3) (4)
10210 000074-86-2 Acetylene
▼M1
10630 000079-06-1 Acrylamide SML = ND (DL
= 0,01 mg/kg)
▼M3
10660 015214-89-8 2-Acrylamido-2-methylpropane-sulphonic acidSML = 0,05 mg/kg
▼C1
10690 000079-10-7 Acrylic acid
▼M2
10750 002495-35-4 Acrylic acid, benzyl ester
▼C1
10780 000141-32-2 Acrylic acid n-butyl ester
10810 002998-08-5 Acrylic acid, sec-butyl ester
10840 001663-39-4 Acrylic acid tert-butyl ester
11470 000140-88-5 Acrylic acid ethyl ester
000818-61-1 Acrylic acid hydroxyethyl ester See ‘Acrylic acid, monoester
with ethyleneglycol'
11590 00106-63-8 Acrylic acid, isobutyl ester
11680 000689-12-3 Acrylic acid, isopropyl ester
11710 000096-33-3 Acrylic acid, methyl ester
11830 000818-61-1 Acrylic acid, monoester with ethy-leneglycol
▼M2
11890 002499-59-4 Acrylic acid, n-octyl ester
▼C1
11980 000925-60-0 Acrylic acid, propyl ester
12100 000107-13-1 Acrylonitrile SML = not detectable (DL
= 0,020 mg/kg, analyticaltolerance included)
12130 000124-04-9 Adipic acid
▼M1
12280 002035-75-8 Adipic anhydride
▼C1
12310 Albumin
12340 Albumin, coagulated by formalde-hyde
12375 Alcohols aliphatic, monohydric,saturated, linear, primary(C4-C22)
▼M1
12670 002855-13-2 1-Amino-3-aminomethyl-3,5,5-trimethylcyclohexaneSML = 6 mg/kg
12788 002432-99-7 11-Aminoundecanoic acid ►M2SML = 5 mg/kg ◄
▼M3
12789 007664-41-7 Ammonia
▼C1
12820 000123-99-9 Azelaic acid
▼M1
12970 004196-95-6 Azelaic anhydride
▼C1
13000 001477-55-0 1,3-Benzenedimethanamine SML = 0,05 mg/kg
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PM/REF No CAS No Name Restrictions
(1) (2) (3) (4)
13090 000065-85-0 Benzoic acid
13150 000100-51-6 Benzylal cohol
000111-46-6 Bis(2-hydroxyethyl) ether See ‘Diethyleneglycol'
000077-99-6 2,2-Bis(hydroxymethyl)-1-butanol See ‘1,1,1-Trimethylolpropane'
13390 000105-08-8 1,4-Bis(hydroxymethyl)
cyclohexane
13480 000080-05-7 2,2-Bis(4-hydroxyphenyl)propane SML = 3 mg/kg
13510 001675-54-3 2,2 Bis(4-hydroxyphenyl)propanebis(2,3-epoxypropyl) etherQM = 1 mg/kg de FP or SML
= not detectable (DL= 0,020 mg/kg, analyticaltolerance included)
000110-98-5 Bis(hydroxypropyl) ether See ‘Dipropyleneglycol'
005124-30-1 Bis(4-isocyanatocyclohexyl)methaneSee ‘Dicyclohexylmethane-
4,4 /prime1-diisocyanate'
▼M1
13530 038103-06-9 2,2-Bis(4-hydroxyphenyl)propanebis(phthalic anhydride)SML = 0,05 mg/kg
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13600 047465-97-4 3,3-Bis(3-methyl-4-hydroxyphenyl)-2-indolinoneSML = 1,8 mg/kg
000080-05-7 BisphenolA See ‘2,2-Bis(4-hydroxyphenyl )
propane'
001675-54-3 BisphenolA bis(2,3-epoxypropyl )etherSee ‘2,2-Bis(4-hydroxyphenyl)
propane-bis(2,3-epoxypropyl)ether'
▼M1
13614 038103-06-9 BisphenolA bis(phthal ic anhy-dride)See 13530
▼C1
13630 000106-99-0 Butadiene QM = 1 mg/kg in FP or SML
= not detectable (DL= 0,020 mg/kg, analyticaltolerance included)
13690 000107-88-0 1,3-Butanediol
13840 000071-36-3 1-Butanol
13870 000106-98-9 1-Butene
13900 000107-01-7 2-Butene
14110 000123-72-8 Butyraldehyde
14140 000107-92-6 Butyric acid
14170 000106-31-0 Butyric anhydride
14200 000105-60-2 Caprolactam SML(T) = 15 mg/kg
14230 002123-24-2 Caprolactam, sodium salt SML(T) = 15 mg/kg
(expressed as caprolactam)
14320 000124-07-2 Caprylic acid
14350 000630-08-0 Carbon monoxide
14380 000075-44-5 Carbonylchl oride QM = 1 mg/kg in FP
▼M3
14411 008001-79-4 Castor oil
▼C1
14500 009004-34-6 Cellulose
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PM/REF No CAS No Name Restrictions
(1) (2) (3) (4)
14530 007782-50-5 Chlorine
000106-89-8 1-Chloro-2,3-epoxypropane See ‘Epichlorhydrin'
14680 000077-92-9 Citric acid
14710 000108-39-4 m-Cresol
14740 000095-48-7 o-Cresol
14770 00106-44-5 p-Cresol
000105-08-8 1,4-Cyclohexanedimethanol See ‘1,4-Bis(hydroxymethyl)
cyclohexane'
14950 003173-53-3 Cyclohexyl isocyanate QM(T) = 1 mg/kg in FP
(expressed as NCO)
▼M3
15070 001647-16-1 1,9-Decadiene SML = 0,05 mg/kg
▼M2
15095 000334-48-5 Decanoic acid
▼C1
15100 000112-30-1 1-Decanol
000107-15-3 1,2-Diaminoethane See ‘Ethylenediamine'
000124-09-4 1,6-Diaminohexane See ‘Hexamethylenediamine'
▼M1
15250 000110-60-1 1,4-Diaminobutane
▼M2
15565 000106-46-7 1,4-Dichlorobenzene SML = 12 mg/kg
▼C1
15700 005124-30-1 Dicyclohexylmethane-4,4 /prime1-diiso-
cyanateQM(T) = 1 mg/kg in FP
(expressed as NCO)
15760 000111-46-6 Diethyleneglycol SML(T) = 30 mg/kg alone or
with ethyleneglycol
▼M2
15790 000111-40-0 Diethylenetriamine SML = 5 mg/kg
15820 000345-92-6 4,4 /prime1-Difluorobenzophenone SML = 0,05 mg/kg
▼C1
15880 000120-80-9 1,2-Dihydroxybenzene SML = 6 mg/kg
15910 000108-46-3 1,3-Dihydroxybenzene SML = 2,4 mg/kg
15940 000123-31-9 1,4-Dihydroxybenzene SML = 0,6 mg/kg
15970 000611-99-4 4,4 /prime1-Dihydroxybenzophenone SML = 6 mg/kg
16000 000092-88-6 4,4 /prime1-DihydroxydiphenylSML = 6 mg/kg
16150 000108-01-0 Dimethylaminoethanol SML = 18 mg/kg
16240 000091-97-4 3,3 /prime1-Dimethyl-4,4 /prime1-diisocyanatobi-
phenylQM(T) = 1 mg/kg in FP
(expressed as NCO)
16480 000126-58-9 Dipentaerythritol
16570 004128-73-8 Diphenylether 4,4 /prime1-diisocyanate QM(T) = 1 mg/kg in FP
(expressed as NCO)
16600 005873-54-1 Diphenylmethane 2,4 /prime1-diisocya-
nateQM(T) = 1 mg/kg in FP
(expressed as NCO)
16630 000101-68-8 Diphenylmethane 4,4 /prime1-diisocya-
nateQM(T) = 1 mg/kg in FP
(expressed as NCO)
16660 000110-98-5 Dipropyleneglycol
16750 000106-89-8 Epichlorohydrin QM = 1 mg/kg in FP
16780 000064-17-5 Ethanol
16950 000074-85-1 Ethylene
16960 000107-15-3 Ethylenediamine SML = 12 mg/kg
16990 000107-21-1 Ethyleneglycol SML(T) = 30 mg/kg alone or
with diethyleneglycol
17005 000151-56-4 Ethyleneimine ►M1SML = ND (DL
= 0,01 mg/kg) ◄
1990L0128 — EN — 01.04.1996 — 001.001 — 13
▼C1
PM/REF No CAS No Name Restrictions
(1) (2) (3) (4)
17020 000075-21-8 Ethylene oxide QM = 1 mg/kg in FP
▼M3
17050 000104-76-7 2-Ethyl-1-hexanol SML = 30 mg/kg
▼M2
17160 000097-53-0 EugenolSML = 0,01 mg/kg
▼C1
17170 061788-47-4 Fatty acids, coco
17200 068308-53-2 Fatty acids, soya
17230 061790-12-3 Fatty acids, tall oil
17260 000050-00-0 Formaldehyde SML = 15 mg/kg
17290 000110-17-8 Fumaric acid
17530 000050-99-7 Glucose
18010 000110-94-1 Glutaric acid
▼M1
18070 000108-55-4 Glutaric anhydride
▼C1
18100 000056-81-5 Glycerol
▼M1
18250 000115-28-6 Hexachloroendomethylenetetrahy-drophthalic acidSML = ND (DL
= 0,01 mg/kg)
18280 000115-27-5 Hexachloroendomethylenetetrahy-drophthalic anhydrideSML = ND (DL
= 0,01 mg/kg)
▼C1
18310 036653-82-4 1-Hexadecanol
▼M1
18430 000116-15-4 Hexafluoropropylene SML = ND (LD
= 0,01 mg/kg)
▼C1
18460 000124-09-4 Hexamethylenediamine SML = 2,4 mg/kg
18640 000822-06-0 Hexamethylene diisocyanate QM(T) = 1 mg/kg in FP
(expressed as NCO)
18670 000100-97-0 Hexamethylenetetramine ►M1SML (T) = 15 mg/kg
(expressed as formalde-hyde)◄
000123-31-9 Hydroquinone See ‘1,4-Dihydroxybenzene'
18880 000099-96-7 P-Hydroxybenzoic acid
19000 000115-11-7 Isobutene
▼M2
19210 001459-93-4 Isophthalic acid, dimethyl ester SML = 0,05 mg/kg
▼M3
19270 000097-65-4 Itaconic acid
▼M4
19460 000050-21-5 Lactic acid
▼M1
19470 000143-07-7 Lauric acid
▼M4
19480 002146-71-6 Lauric acid, vinylester
▼C1
19510 011132-73-3 Lignocellulose
19540 000110-16-7 Maleic acid SML(T) = 30 mg/kg
19960 000108-31-6 Maleic anhydride SML(T) = 30 mg/kg
(expressed as maleic acid)
000108-78-1 Melamine See ‘2,4,6-Triamino-1,3,5-tria-
zine'
20020 000079-41-4 Methacrylic acid
▼M2
20080 002495-37-6 Methacrylic acid, benzyl ester
1990L0128 — EN — 01.04.1996 — 001.001 — 14
PM/REF No CAS No Name Restrictions
(1) (2) (3) (4)
▼C1
20110 000097-88-1 Methacrylic acid, butyl ester
20140 002998-18-7 Methacrylic acid, sec-butyl ester
20170 000585-07-9 Methacrylic acid, tert-butyl ester
20890 000097-63-2 Methacrylic acid, ethyl ester
21010 000097-86-9 Methacrylic acid, isobutyl ester
21100 004655-34-9 Methacrylic acid, isopropyl ester
21130 000080-62-6 Methacrylic acid, methyl ester
▼M1
21190 000868-77-9 Methacrylic acid, monoester withethyleneglycol
▼M2
21280 002177-70-0 Methacrylic acid, phenyl ester
▼C1
21340 002210-28-8 Methacrylic acid, propyl ester
21460 000760-93-0 Methacrylic anhydride
21490 000126-98-7 Methacrylonitrile SML = non detectable (DL
= 0,020 mg/kg, analyticaltolerance included)
21550 000067-56-1 Methanol
▼M1
21940 000924-42-5 N-Methylolacrylamide SML = ND (DL
= 0,01 mg/kg)
▼C1
22150 000691-37-2 4-Methyl-1-pentene ►M1SML = 0,02 mg/kg ◄
▼M1
22350 000544-63-8 Myristic acid
▼M2
22390 000840-65-3 2,6-Naphthalenedicarboxylic acid,dimethylesterSML = 0,05 mg/kg
▼C1
22420 003173-72-6 1,5-Napthalene diisocyanate QM(T) = 1 mg/kg in FP
(expressed as NCO)
22450 009004-70-0 Nitrocellulose
22480 000143-08-8 1-Nonanol
22570 000112-96-9 Octadecylisocyanate QM(T) = 1 mg/kg in FP
(expressed as NCO)
22600 000111-87-5 1-Octanol
22660 000111-66-0 1-Octene SML = 15 mg/kg
▼M1
22763 000112-80-1 Oleic acid
▼C1
22780 000057-10-3 Palmitic acid
22840 000115-77-5 Pentaerythritol
22870 000071-41-0 1-Pentanol
22960 000108-95-2 Phenol
23050 000108-45-2 1,3-Phenylenediamine QM = 1 mg/kg in FP
000075-44-5 Phosgene See ‘Carbonylchl oride'
23170 007664-38-2 Phosphoric acid
Phthalic acid See ‘Terephthalic acid'
▼M1
23200 000088-99-3 o-Phthalic acid
23230 000131-17-9 Phthalic acid, diallyl ester SML = ND (DL
= 0,01 mg/kg)
▼C1
23380 000085-44-9 Phthalic anhydride
1990L0128 — EN — 01.04.1996 — 001.001 — 15
▼C1
PM/REF No CAS No Name Restrictions
(1) (2) (3) (4)
23470 000080-56-8 alpha-Pinene
23500 000127-91-3 beta-Pinene
23590 025322-68-3 Polyethyleneglycol
23650 025322-69-4 Polypropyleneglycol (Molecular
weight greater than 400)
▼M4
23651 025322-69-4 Polypropyleneglycol
▼C1
23740 000057-55-6 1,2-Propanediol
23800 000071-23-8 1-Propanol
23830 000067-63-0 2-Propanol
23860 000123-38-6 Propionaldehyde
23890 000079-09-4 Propionic acid
23950 000123-62-6 Propionic anhydride
23980 000115-07-1 Propylene
24010 000075-56-9 Propylene oxide QM = 1 mg/kg in FP
000120-80-9 PyrocatecholSee ‘1,2-Dihydroxybenzene'
▼M2
24057 000089-32-7 Pyromellitic anhydride SML = 0,05 mg/kg (expressed
as pyromellitic acid)
▼C1
24070 073138-82-6 Resin acids and rosin acids
000108-46-3 ResorcinolSee ‘1,3-Dihydroxybenzene'
24100 008050-09-7 Rosin
24130 008050-09-7 Rosin gum ►M3See ‘Rosin' ◄
24160 008052-10-6 Rosin tall oil
24190 009014-63-5 Rosin wood
24250 009006-04-6 Rubber, natural
▼M1
24270 000069-72-7 Salicylic acid
▼C1
24280 000111-20-6 Sebacic acid
▼M1
24430 002561-88-8 Sebacic anhydride
▼M2
24475 001313-82-2 Sodium sulphide
▼C1
24490 000050-70-4 Sorbitol
24520 008001-22-7 Soybean oil
▼M2
24540 009005-25-8 Starch, edible
▼C1
24550 000057-11-4 Stearic acid
24610 000100-42-5 Styrene
24820 000110-15-6 Succinic acid
▼M1
24850 000108-30-5 Succinic anhydride
▼C1
24880 000057-50-1 Sucrose
▼M1
24887 006362-79-4 5-Sulphoisophthalic acid, monoso-dium salt►
M3SML = 5 mg/kg ◄
▼M2
24888 003965-55-7 5-Sulphoisophthalic acid, monoso-dium salt, dimethyl esterSML = 0,05 mg/kg
1990L0128 — EN — 01.04.1996 — 001.001 — 16
PM/REF No CAS No Name Restrictions
(1) (2) (3) (4)
PM/REF No CAS No Name Restrictions
(1) (2) (3) (4)▼C1
24910 000100-21-0 Terephthalic acid SML = 7,5 mg/kg
▼M2
24940 000100-20-9 Terephtalic acid dichloride SML(T) = 7,5 mg/kg
(expressed as terephtalic acid)
▼C1
24970 000120-61-6 Terephthalic acid, dimethyl ester
25090 000112-60-7 Tetraethyleneglycol
▼M2
25120 000116-14-3 Tetrafluoroethylene SML = 0,05 mg/kg
▼C1
25150 000109-99-9 Tetrahydrofuran SML = 0,6 mg/kg
25180 000102-60-3 N,N,N /prime1,N/prime1-Tetrakis(2-
hydroxypropyl)ethylenediamine
25210 000584-84-9 2,4-Toluene diisocyanate QM(T) = 1 mg/kg in FP
(expressed as NCO)
25240 000091-08-7 2,6-Toluene diisocyanate QM(T) = 1 mg/kg in FP
(expressed as NCO)
25270 026747-90-0 2,4-Toluene diisocyanate dimer QM(T) = 1 mg/kg in FP
(expressed as NCO)
25360 Trialkyl(C5-C15)acetic acid, 2,3-epoxypropylesterSML = 6 mg/kg
25420 000108-78-1 2,4,6-Triamino-1,3,5-triazine SML = 30 mg/kg
25510 000112-27-6 Triethyleneglycol
25600 000077-99-6 1,1,1-Trimethylolpropane SML = 6 mg/kg
▼M1
25910 024800-44-0 Tripropyleneglycol
▼C1
25960 000057-13-6 Urea
26050 000075-01-4 Vinylchl oride See CouncilDirective 78/
142/EEC
26110 000075-35-4 Vinylidene chloride QM = 5 mg/kg in FP or SML
= not detectable (DL= 0,05 mg/kg)
▼M3
26140 000075-38-7 Vinylidene fluoride SML = 5 mg/kg
▼C1
SECTION B
LIST OF MONOMERS AND OTHER STARTING SUBSTANCES WHICH
MAY CONTINUE TO BE USED PENDING A DECISION ON INCLU-
SION IN SECTION A
000542-02-9 Acetoguanamine See ‘2,4-Diamino-6-methyl-
1,3,5-triazine'
▼M2
10599/90A 061788-89-4 Acids, fatty, unsaturated (C18),dimers, distilled
10599/91 061788-89-4 Acids, fatty, unsaturated (C18),dimers, non-distilled
10599/92A 068783-41-5 Acids, fatty, unsaturated (C18),dimers, hydrogenated, distilled
10599/93 068783-41-5 Acids, fatty, unsaturated (C18),dimers, hydrogenated, non-distilled
1990L0128 — EN — 01.04.1996 — 001.001 — 17
PM/REF No CAS No Name Restrictions
(1) (2) (3) (4)
▼M1
11000 050976-02-8 Acrylic acid, dicyclopentadienylester
11245 002156-97-0 Acrylic acid, dodecyl ester
▼C1
11500 000103-11-7 Acrylic acid, 2-ethylhexyl ester
11530 000999-61-1 Acrylic acid, 2-hydroxypropylester
▼M1
12265 004074-90-2 Adipic acid, divinylester
▼C1
12910 001732-10-1 Azelaic acid, dimethyl ester
13030 000528-44-9 1,2,4-Benzenetricarboxylic acid See ‘Trimellitic acid'
13060 004422-95-1 1,3,5-Benzenetricarboxylic acidtrichloride
000091-76-9 Benzoguanamine See ‘2,4-Diamino-6-phenyl-
1,3,5-triazine'
13570 000080-09-1 BisphenolS See ‘4,4-Dihydroxydiphenyl
sulphone'
13720 000110-63-4 1,4-Butanediol
13780 002425-79-8 1,4-Butanediolbis(2,3-epoxypropyl) etherQM(T) = 5 mg/kg in FP
(expressed as epoxy)
13810 000505-65-7 1,4-Butanediolformal
▼M1
13932 000598-32-3 3-Buten-2-ol
▼C1
14020 000098-54-4 4-tert-Butylphenol
14260 000502-44-3 Caprolactone
14470 000115-28-6 Chlorendic acid See ‘Hexachloroendo-methyle-
netetrahydrophthalic acid'
14800 003724-65-0 Crotonic acid
15130 000872-05-9 1-Decene
15310 000091-76-9 2,4-Diamino-6-phenyl-1,3,5-tria-zine
15370 003236-53-1 1,6-Diamino-2,2,4-trimethyl-hexane
15400 003236-54-2 1,6-Diamino-2,4,4-trimethyl-hexane
15610 000080-07-9 4,4 /prime1-Dichlorodiphenyl sulphone
15730 000077-73-6 Dicyclopentadiene
16090 000080-09-1 4,4 /prime1-Dihydroxydiphenylsul phone
16210 006864-37-5 3,3 /prime1-Dimethyl-4,4 /prime1-diaminodicy-
clohexylmethane
16360 000576-26-1 2,6-Dimethylphenol
16390 000126-30-7 2,2-Dimethyl-1,3-propanediol
16450 000646-06-0 1,3-Dioxolane
16540 000102-09-0 Diphenylcarbonate
16690 001321-74-0 Divinylbenzene
▼M1
16697 000693-23-2 Dodecanedioic acid
▼C1
17110 016219-75-3 5-Ethylidenebi-cyclo[2.2.1]hept-2-ene
18220 068564-88-5 N-Heptylaminoundecanoic acid
18370 000592-45-0 1,4-Hexadiene
▼M1
18441 000085-42-7 Hexahydrophthalic anhydride
1990L0128 — EN — 01.04.1996 — 001.001 — 18
PM/REF No CAS No Name Restrictions
(1) (2) (3) (4)
▼C1
18700 000629-11-8 1,6-Hexanediol
18820 000592-41-6 1-Hexene
19060 000109-53-5 Isobutylvinylether
19150 000121-91-5 Isophthalic acid
19180 000099-63-8 Isophthalic acid dichloride
19240 000078-79-5 Isoprene See ‘2-Methyl-1,3-butadiene'
▼M1
19490 000947-04-6 Laurolactam
▼C1
19570 000999-21-3 Maleic acid, diallyl ester
19600 000105-76-0 Maleic acid, dibutyl ester
19990 000079-39-0 Methacrylamide
20050 000096-05-9 Methacrylic acid, allyl ester
20260 000101-43-9 Methacrylic acid, cyclohexyl ester
20380 001189-08-8 Methacrylic acid, diester with 1,3-butanediol
20410 002082-81-7 Methacrylic acid, diester with 1,4-butanediol
20440 000097-90-5 Methacrylic acid, diester withethyleneglycol
20530 002867-47-2 Methacrylic acid, 2-(dimethyla-mino)ethylester
20590 000106-91-2 Methacrylic acid, 2,3-epoxypropylesterQM(T) = 5 mg/kg in FP
(expressed as epoxy)
21370 010595-80-9 Methacrylic acid, 2-sulphoethylester
21400 054276-35-6 Methacrylic acid, sulphopropylester
21520 001561-92-8 Methallylsulphonic acid, sodiumsaltQM = 5 mg/kg in FP
21640 000078-79-5 2-Methyl-1,3-butadiene
21730 000563-45-1 3-Methyl-1-butene
21820 000505-65-7 1,4-(Methylenedioxy)butane See ‘1,4-Butanediol formal'
21970 000923-02-4 N-Methylolmethacrylamide
22210 000098-83-9 alpha-Methylstyrene
22360 001141-38-4 2,6-Naphtalenedicarboxylic acid
000126-30-7 Neopentylglycol See ‘2,2-Dimethyl-1,3-propane-
diol'
▼M1
22428 051000-52-3 Neodecanoic, vinylester
▼C1
22540 000498-66-8 Norbornene See ‘Bicyclo[2.2.1]hept-2-ene'
22720 000140-66-9 4-tert-Octylphenol
22900 000109-67-1 1-Pentene
▼M1
22937 001623-05-8 Perfluoropropyl perfluorovinylether
▼C1
23140 000092-69-3 Phthalic acids See ‘Iso- or o-phthalic acid'
1990L0128 — EN — 01.04.1996 — 001.001 — 19
▼C1
PM/REF No CAS No Name Restrictions
(1) (2) (3) (4)
23770 000504-63-2 1,3-Propanediol
23920 000105-38-4 Propionic acid, vinylester
24370 000106-79-6 Sebacic acid, dimethylester
24760 026914-43-2 Styrenesulphonic acid
▼M1
25380 Trialkyl (C5-C15) acetic acid,vinylester (= vinylversatate)
▼C1
25390 000101-37-1 Triallyl cyanurate
25450 026896-48-0 Tricyclodecanedimethanol
25540 000528-44-9 Trimellitic acid QM(T) = 5 mg/kg in FP
25550 000552-30-7 Trimellitic anhydride QM(T) = 5 mg/kg in FP
(expressed as trimellitic acid)
25810 015625-89-5 1,1,1-Trimethylolpropane triacry-late
25840 003290-92-4 1,1,1-Trimethylolpropane trime-thacrylate
25900 000110-88-3 Trioxane
000102-71-6 Tris(2-hydroxyethyl)amine See ‘Triethanolamine'
26170 003195-78-6 N-Vinyl-N-methylacetamide QM = 5 mg/kg in FP
26230 000088-12-0 Vinylpyrrolidone
26290 000622-97-9 p-Vinyltoluene See ‘ p-Methylstyrene'
26320 000105-67-9 m-Xylenol See ‘2,4-Dimethylphenol'
000526-75-0 o-Xylenol See ‘2,3-Dimethylphenol'
000095-87-4 p-Xylenol See ‘2,5-Dimethylphenol'
▼M1
▼M2
▼M3
▼M4
1990L0128 — EN — 01.04.1996 — 001.001 — 20
PM/Ref No CAS No Name Restrictions
(1) (2) (3) (4)▼M3
ANNEX III
INCOMPLETE LIST OF ADDITIVES WHICH MAY BE USED IN THE
MANUFACTURE OF PLASTICS MATERIALS AND ARTICLES
General introduction
1. This Annex contains the list of:
(a) substances which are incorporated into plastics to achieve a technical
effect in the finished product. They are intended to be present in thefinished articles;
(b) substances used to provide a suitable medium in which polymerization
occurs (e.g. emulsifiers, surfactants, buffering agents etc.).
The list does not include the substances which directly influence the forma-
tion of polymers (e.g. the catalytic system).
2. The list does not include the salts (including double salts and acid salts) of
aluminium, ammonium, calcium, iron, magnesium, potassium, sodium andzinc of the authorized acids, phenols or alcohols which are also authorized.However, names containing ‘…acid(s), salts' appear in the lists if the corre-sponding free acid(s) is (are) not mentioned. In such cases, the meaning of theterm ‘salts' is ‘salts of aluminium, ammonium, calcium, iron, magnesium,potassium, sodium and zinc'.
3. The list does not include the following substances although they may be
present:
(a) substances which could be present in the finished product such as:
— impurities in the substances used,— reaction intermediates,— decomposition products;
(b) mixtures of the authorized substances.
The materials and articles which contain the substances indicated in (a) and
(b) shall comply with the requirements stated in Article 2 of Directive89/109/EEC.
4. Substances shal lbe of good technicalqual ity as regards the purity criteria.5. The list contains the following information:
— column 1 (PM-REF No): the EEC packaging material reference number of
the substances on the list,
— column 2 (CAS No): the CAS (Chemical Abstracts Service) registry
number,
— column 3 (Name): the chemical name,— column 4 (Restrictions). These may include:
— specific migration limit (SML),— maximum permitted quantity of the ‘residual', substance in the
materialor articl e (QM),
— any other restriction specifically mentioned.
6. If a substance appearing on the list as an individual compound is also covered
by a generic term, the restrictions applying to this substance shall be thoseindicated for the individualcompound.
7. Where there is any inconsistency between the CAS number and the chemical
name, the chemicalname shal ltake precedence over the CAS number. If thereis an inconsistency between the CAS number reported in Einecs and the CASregistry, the CAS number in the CAS registry shall apply.
Incomplete list of additives
30000 000064-19-7 Acetic acid
30045 000123-86-4 Acetic acid, butylester
30140 000141-78-6 Acetic acid, ethylester
30280 000108-24-7 Acetic anhydride
30295 000067-64-1 Acetone
1990L0128 — EN — 01.04.1996 — 001.001 — 21
▼M3
PM/Ref No CAS No Name Restrictions
(1) (2) (3) (4)
30370 — Acetylacetic acid, salts
30400 — Acetylated glycerides
30960 — Acids aliphatic monocarboxylic
(C6-C22) esters with polyglycerol
31328 — Acids, fatty, from animalorvegetable food fats and oils
31730 000124-04-9 Adipic acid
33120 — Alcohols, aliphatic, monohydric,saturated, linear, primary (C
4-C24)
33350 009005-32-7 Alginic acid
▼M4
34281 — Alkyl(C8-C22) sulphoric acids,
linear, primary, with an evennumber of carbon atoms
34475 — Aluminium calcium hydroxidephosphite, hydrate
▼M3
34480 — Aluminium fibers, flakes andpowders
34560 021645-51-2 Aluminium hydroxide
34690 011097-59-9 Aluminium magnesium carbonatehydroxide
34720 001344-28-1 Aluminium oxide
35120 013560-49-1 3-Aminocrotonic acid, diester withthiobis (2-hydroxyethyl) ether
35320 007664-41-7 Ammonia
35440 012124-97-9 Ammonium bromide
35600 001336-21-6 Ammonium hydroxide
35840 000506-30-9 Arachidic acid
35845 007771-44-0 Arachidonic acid
36000 000050-81-7 Ascorbic acid
36080 000137-66-6 Ascorbylpal mitate
36160 010605-09-1 Ascorbylstearate
36880 008012-89-3 Beeswax
36960 003061-75-4 Behenamide
37040 000112-85-6 Behenic acid
37280 001302-78-9 Bentonite
37600 000065-85-0 Benzoic acid
37680 000136-60-7 Benzoic acid, butylester
37840 000093-89-0 Benzoic acid, ethylester
38080 000093-58-3 Benzoic acid, methylester
38160 002315-68-6 Benzoic acid, propylester
38950 079072-96-1 Bis (4-ethylbenzylidene) sorbitol
39890 087826-41-3 Bis (methylbenzylidene) sorbitol
069158-41-4
054686-97-4
40400 010043-11-5 Boron nitride
40570 000106-97-8 Butane
41040 005743-36-2 Calcium butyrate
41280 001305-62-0 Calcium hydroxide
41520 001305-78-8 Calcium oxide
41600 012004-14-7 Calcium sulphoaluminate
037293-22-4
1990L0128 — EN — 01.04.1996 — 001.001 — 22
▼M3
PM/Ref No CAS No Name Restrictions
(1) (2) (3) (4)
41760 008006-44-8 Candelilla wax
41960 000124-07-2 Caprylic acid
42160 000124-38-9 Carbon dioxide
42500 — Carbonic acid, salts
42640 009000-11-7 Carboxymethylcellulose
42720 008015-86-9 Carnauba wax
42800 009000-71-9 Casein
42960 064147-40-6 Castor oil, dehydrated
43200 — Castor oil, mono- and diglycerides
43280 009004-34-6 Cellulose
43300 009004-36-8 Cellulose acetate butyrate
43360 068442-85-3 Cellulose, regenerated
43440 008001-75-0 Ceresin
44160 000077-92-9 Citric acid
44640 000077-93-0 Citric acid, triethylester
45280 — Cotton fibers
45560 014464-46-1 Cristobalite
45760 000108-91-8 Cyclohexylamine
45920 009000-16-2 Dammar
45940 000334-48-5 n-Decanoic acid
46070 010016-20-3 alpha-Dextrin
46080 007585-39-9 beta-Dextrin
46375 061790-53-2 Diatomaceous earth
▼M4
46380 068855-54-9 Diatomaceous earth, soda ashflux-calcined
▼M3
46480 032647-67-9 Dibenzylidene sorbitol
46790 004221-80-1 3,5-Di-tert-butyl-4-hydroxyben-zoic acid, 2,4-di-tert-butylphenylester
46800 067845-93-6 3,5-Di-tert-butyl-4-hydroxyben-zoic acid, hexadecylester
46870 003135-18-0 3,5-Di-tert-butyl-4-hydroxyben-zylphosphonic acid, dioctadecylester
47440 000461-58-5 Dicyanodiamide
49540 000067-68-5 Dimethylsul phoxide
51200 000126-58-9 Dipentaerythritol
51760 025265-71-8 Dipropyleneglycol
000110-98-5
52640 016389-88-1 Dolomite
▼M4
52720 000112-84-5 Erucamide
▼M3
52730 000112-86-7 Erucic acid
52800 000064-17-5 Ethanol
53270 037205-99-5 Ethylcarboxymethylcellulose
53280 009004-57-3 Ethylcellulose
53360 000110-31-6 N,N /prime1-Ethylenebisoleamide
53440 005518-18-3 N,N /prime1-Ethylenebispalmitamide
53520 000110-30-5 N,N /prime1-Ethylenebisstearamide
53600 000060-00-4 Ethylenediaminetetraacetic acid
1990L0128 — EN — 01.04.1996 — 001.001 — 23
▼M3
PM/Ref No CAS No Name Restrictions
(1) (2) (3) (4)
54005 005136-44-7 Ethylene-N-palmitamide-N /prime1
-stearamide
54260 009004-58-4 Ethylhydroxyethylcellulose
54270 — Ethylhydroxymethylcellulose
54280 — Ethylhydroxypropylcellulose
54450 — Fats and oils, from animal orvegetable food sources
54480 — Fats and oils, hydrogenated, fromanimalor vegetabl e food sources
55040 000064-18-6 Formic acid
55120 000110-17-8 Fumaric acid
55190 029204-02-2 Gadoleic acid
55440 009000-70-8 Gelatin
▼M4
55520 — Glass fibres
55600 — Glass microballs
▼M3
55680 000110-94-1 Glutaric acid
55920 000056-81-5 Glycerol
56020 099880-64-5 Glycerol dibehenate
56360 — Glycerol, esters with acetic acid
▼M4
56486 — Glycerol, esters with acids,aliphatic, saturated, linear, with aneven number of carbonatoms(C
14-C18) and with acids,
aliphatic, unsaturated, linear, withan even number of carbon atoms(C
16-C18)
▼M3
56487 — Glycerol, esters with butyric acid
56490 — Glycerol, esters with erucic acid
56495 — Glycerol, esters with 12-hydroxys-tearic acid
56500 — Glycerol, esters with lauric acid
56510 — Glycerol, esters with linoleic acid
56520 — Glycerol, esters with myristic acid
56540 — Glycerol, esters with oleic acid
56550 — Glycerol, esters with palmitic acid
56565 — Glycerol, esters with nonanoicacid
56570 — Glycerol, esters with propionicacid
56580 — Glycerol, esters with ricinoleicacid
56585 — Glycerol, esters with stearic acid
56610 030233-64-8 Glycerol monobehenate
56720 026402-23-3 Glycerol monohexanoate
56800 030899-62-8 Glycerol monolaurate diacetate
56880 026402-26-6 Glycerol monooctanoate
57040 — Glycerol monooleate, ester withascorbic acid
57120 — Glycerol monooleate, ester withcitric acid
57200 — Glycerol monopalmitate, esterwith ascorbic acid
1990L0128 — EN — 01.04.1996 — 001.001 — 24
▼M3
PM/Ref No CAS No Name Restrictions
(1) (2) (3) (4)
57280 — Glycerol monopalmitate, ester
with citric acid
57600 — Glycerol monostearate, ester withascorbic acid
57680 — Glycerol monostearate, ester withcitric acid
57920 000620-67-7 Glycerol triheptanoate
58300 — Glycine, salts
58320 007782-42-5 Graphite
58400 009000-30-0 Guar gum
58480 009000-01-5 Gum arabic
58720 000111-14-8 Heptanoic acid
59360 000142-62-1 Hexanoic acid
59760 019569-21-2 Huntite
59990 007647-01-0 Hydrochloric acid
60030 012072-90-1 Hydromagnesite
60080 012304-65-3 Hydrotalcite
60160 000120-47-8 4-Hydroxybenzoic acid, ethylester
60180 004191-73-5 4-Hydroxybenzoic acid, isopropylester
60200 000099-76-3 4-Hydroxybenzoic acid, methylester
60240 000094-13-3 4-Hydroxybenzoic acid, propylester
60560 009004-62-0 Hydroxyethylcellulose
60880 009032-42-2 Hydroxyethylmethylcellulose
61120 009005-27-0 Hydroxyethylstarch
61390 037353-59-6 Hydroxymethylcellulose
61680 009004-64-2 Hydroxypropylcellulose
61800 009049-76-7 Hydroxypropylstarch
61840 000106-14-9 12-Hydroxystearic acid
62140 006303-21-5 Hypophosphorous acid
62240 001332-37-2 Iron oxide
62450 000078-78-4 Isopentane
62640 008001-39-6 Japan Wax
62720 001332-58-7 Kaolin
62800 — Kaolin, calcined
62960 000050-21-5 Lactic acid
63040 000138-22-7 Lactic acid, butylester
63280 000143-07-7 Lauric acid
63760 008002-43-5 Lecithin
63840 000123-76-2 Levulinic acid
63920 000557-59-5 Lignoceric acid
64015 000060-33-3 Linoleic acid
64150 028290-79-1 Linolenic acid
64500 — Lysine, salts
64640 001309-42-8 Magnesium hydroxide
64720 001309-48-4 Magnesium oxide
65020 006915-15-7 Malic acid
65040 000141-82-2 Malonic acid
65520 000087-78-5 Mannitol
1990L0128 — EN — 01.04.1996 — 001.001 — 25
▼M3
PM/Ref No CAS No Name Restrictions
(1) (2) (3) (4)
66200 037206-01-2 Methylcarboxymethylcellulose
66240 009004-67-5 Methylcellulose
66640 009004-59-5 Methylethylcellulose
66695 — Methylhydroxymethylcellulose
66700 009004-65-3 Methylhydroxypropylcellulose
67120 012001-26-2 Mica
67200 001317-33-5 Molybdenum disulphide
67840 — Montanic acids and/or their esters
with ethyleneglycol and/or with1,3-butanedioland/or withglycerol
67850 008002-53-7 Montan wax
67891 000544-63-8 Myristic acid
68040 003333-62-8 7-[2-H-Naphto-(1,2-D)triazol-2-yl]-3-phenylcoumarin
68125 068187-64-4 Nepheline syenite
▼M4
68960 000301-02-0 Oleamide
▼M3
69040 000112-80-1 Oleic acid
69760 000143-28-2 Oleyl alcohol
70000 070331-94-1 2,2 /prime1-Oxamidobis[ethyl-3-(3,5-di-
tert-butyl-4-hydroxy-phenyl)propionate]
70240 012198-93-5 Ozokerite
70400 000057-10-3 Palmitic acid
71020 000373-49-9 Palmitoleic acid
71440 009000-69-5 Pectin
71600 000115-77-5 Pentaerythritol
71680 006683-19-8 Pentaerythritoltetrakis[3-(3,5-di-tert-butyl-4-hydroxy-phenyl)propionate]
71720 000109-66-0 Pentane
72640 007664-38-2 Phosphoric acid
74240 031570-04-4 Phosphorous acid,tris(2,4-di-tert-butylphenyl)ester
74480 000088-99-3 o-Phthalic acid
76320 000085-44-9 Phthalic anhydride
76720 009016-00-6 Polydimethylsiloxane
063148-62-9
76960 025322-68-3 Polyethyleneglycol
77600 061788-85-0 Polyethyleneglycol ester of hydro-genated castor oil
77702 — Polyethyleneglycol esters ofaliphatic monocarboxylic acids(C
6-C22), and their ammonium and
sodium sulphates
79040 009005-64-5 Polyethyleneglycol sorbitan mono-laureate
79120 009005-65-6 Polyethyleneglycol sorbitan mono-oleate
79200 009005-66-7 Polyethyleneglycol sorbitanmonopalmitate
79280 009005-67-8 Polyethyleneglycol sorbitan mono-stearate
1990L0128 — EN — 01.04.1996 — 001.001 — 26
▼M3
PM/Ref No CAS No Name Restrictions
(1) (2) (3) (4)
79360 009005-70-3 Polyethyleneglycol sorbitan trio-
leate
79440 009005-71-4 Polyethyleneglycol sorbitan tris-tearate
80240 029894-35-7 Polyglycerol ricinoleate
80640 — Polyoxyalkyl(C2-C4)dime-
thylpolysiloxane
80720 008017-16-1 Polyphosphoric acids
▼M4
80800 025322-69-4 Polypropyleneglycol
▼M3
81520 007758-02-3 Potassium bromide
81600 001310-58-3 Potassium hydroxide
81840 000057-55-6 1,2-Propanediol
81882 000067-63-0 2-Propanol
82000 000079-09-4 Propionic acid
82080 009005-37-2 1,2-Propyleneglycol alginate
82240 022788-19-8 1,2-Propyleneglycol dilaurate
82400 000105-62-4 1,2-Propyleneglycol dioleate
82560 033587-20-1 1,2-Propyleneglycol dipalmitate
82720 006182-11-2 1,2-Propyleneglycol distearate
82800 027194-74-7 1,2-Propyleneglycol monolaurate
82960 001330-80-9 1,2-Propyleneglycol monooleate
83120 029013-28-3 1,2-Propyleneglycol monopalmi-tate
83300 001323-39-3 1,2-Propyleneglycol monostearate
83320 — Propylhydroxyethylcellulose
83325 — Propylhydroxymethylcellulose
83330 — Propylhydroxypropylcellulose
83440 002466-09-3 Pyrophosphoric acid
83455 013445-56-2 Pyrophosphorous acid
83460 012269-78-2 Pyrophyllite
83470 014808-60-7 Quartz
83610 073138-82-6 Resin acids and rosin acids
83840 008050-09-7 Rosin
84000 008050-31-5 Rosin, ester with glycerol
84080 008050-26-8 Rosin, ester with pentaerythritol
84210 065997-06-0 Rosin, hydrogenated
84240 065997-13-9 Rosin, hydrogenated, ester withglycerol
84320 008050-15-5 Rosin, hydrogenated, ester withmethanol
84400 064365-17-9 Rosin, hydrogenated, ester withpentaerythritol
84560 009006-04-6 Rubber, natural
84640 000069-72-7 Salicylic acid
85600 — Silicates, natural
85980 — Silicic acid, salts
86000 — Silicic acid, silylated
86160 000409-21-2 Silicon carbide
86240 007631-86-9 Silicon dioxide
86560 007647-15-6 Sodium bromide
1990L0128 — EN — 01.04.1996 — 001.001 — 27
▼M3
PM/Ref No CAS No Name Restrictions
(1) (2) (3) (4)
86720 001310-73-2 Sodium hydroxide
87200 000110-44-1 Sorbic acid
87280 029116-98-1 Sorbitan dioleate
87520 062568-11-0 Sorbitan monobehenate
87600 001338-39-2 Sorbitan monolaurate
87680 001338-43-8 Sorbitan monooleate
87760 026266-57-9 Sorbitan monopalmitate
87840 001338-41-6 Sorbitan monostearate
87920 061752-68-9 Sorbitan tetrastearate
88080 026266-58-0 Sorbitan trioleate
88160 054140-20-4 Sorbitan tripalmitate
88240 026658-19-5 Sorbitan tristearate
88320 000050-70-4 Sorbitol
88600 026836-47-5 Sorbitolmonostearate
88800 009005-25-8 Starch, edible
88880 068412-29-3 Starch, hydrolysed
▼M4
88960 000124-26-5 Stearamide
▼M3
89040 000057-11-4 Stearic acid
90720 058446-52-9 Stearoylbenzoylmethane
90800 005793-94-2 Stearoyl-2-lactylic acid, calciumsalt
90960 000110-15-6 Succinic acid
91200 000126-13-6 Sucrose acetate isobutyrate
91360 000126-14-7 Sucrose octaacetate
91840 007704-34-9 Sulphur
91920 007664-93-9 Sulphuric acid
92080 014807-96-6 Talc
92160 000087-69-4 Tartaric acid
92195 — Taurine, salts
92205 057569-40-1 Terephthalic acid, diester with2,2 /prime1-methylenebis(4-methyl-
6-tert-butylphenol)
92350 000112-60-7 Tetraethyleneglycol
92640 000102-60-3 N,N,N /prime1,N/prime1-Tetrakis(2-
hydroxypropyl)ethylenediamine
93440 013463-67-7 Titanium dioxide
93520 000059-02-9 alpha-Tocopherol
010191-41-0
93680 009000-65-1 Tragacanth gum
94320 000112-27-6 Triethyleneglycol
95200 001709-70-2 1,3,5-Trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxy-benzyl)benzene
95905 013983-17-0 Wollastonite
95920 — Wood flour and fibres, untreated
95935 011138-66-2 Xanthan gum
96190 020427-58-1 Zinc hydroxide
96240 001314-13-2 Zinc oxide
96320 001314-98-3 Zinc sulphide