Cocoa butter

Cocoa butter, also calledtheobroma oil, is a pale-yellow, ediblefatextracted from thecocoa bean(Theobroma  cacao). It is used to makechocolate, as well as someointments,toiletries, andpharmaceuticals.Cocoa butter has a cocoaflavorandaroma. Its melting point is slightly below human body temperature. It is an essential ingredient of chocolate and related confectionary products. Cocoa butter does not containbutteror other animal products; it isvegan.
For use in chocolate manufacture, the cocoa beans are firstfermentedand then dried. The beans are then roasted and separated from their hulls to produce cocoa nibs.About 54–58% of the cocoa nibs is cocoa butter. The cocoa nibs are ground to formcocoa mass, also known as cocoa liquor or chocolate liquor. Chocolate liquor is pressed to separate the cocoa butter from the non-fat cocoa solids.Cocoa butter is sometimes deodorized to remove strong or undesirable tastes.
Cocoa butter contains a high proportion of saturated fats also with the monounsaturated oleic acid in each triglyceride. The predominant triglycerides are POS, SOS, and POP, where P = palmitic, O = oleic, and S = stearic acid residues.Cocoa butter, unlike non-fatcocoa solids, contains only traces ofcaffeineandtheobromine.
Some food manufacturers substitute less expensive materials in place of cocoa butter. Several analytical methods exist for testing for diluted cocoa butter. Adulterated cocoa butter is indicated by its lighter color and its diminishedfluorescenceuponultravioletillumination. Unlike cocoa butter, adulterated fat tends to smear and have a higher non-saponifiable content.
Owing to the high cost of cocoa butter,substitutes have been designed to use as alternatives. In the United States, 100% cocoa butter must be used as the product's fat source for the product to be called chocolate. The EU requires that alternative fats not exceed 5% of the total fat content.
Substitutes include:coconut,palm,soybean,rapeseed,cottonseedandillipeoils; andshea butter,mango kernel fatand a mixture of mango kernel fat and palm oil,andPGPR.
Cocoa butter is a major ingredient in practically all types of chocolates, especiallywhite,milk, andcouverture chocolate.This application continues to dominate the consumption of cocoa butter.
Pharmaceutical companies use cocoa butter extensively. As a nontoxic solid at room temperature that melts at body temperature, it is considered an ideal base for medicinal suppositories.
For a fat melting around body temperature, cocoa has good stability. This quality, coupled with naturalantioxidants, preventsrancidity– giving it a storage life of two to five years.The velvety texture, pleasant fragrance andemollientproperties of cocoa butter have made it a popular ingredient in products for the skin, such assoapsandlotions.
Cocoa butter was first made by boiling cocoa mass with water and skimming off the fat floating over it.In the 18th century, the first hydraulic presses were used to press cocoa butter and the (more effective)Van Houten pressbegan to be employed in the second half of the 19th century.A by-product of chocolate factories, cocoa butter was mainly used for cosmetic and pharmaceutical preparations until the late 19th century.It eventually became a common chocolate ingredient with the rise of chocolate in confectionery.
Cocoa butter typically has amelting pointof around 34–38 °C (93–100 °F), so chocolate is solid atroom temperaturebut readily melts once inside themouth. Cocoa butter displayspolymorphism, having different crystalline forms with different melting points. Conventionally the assignment of cocoa butter crystalline forms uses the nomenclature of Wille and Luttonwith forms I, II, III, IV, V, and VI having melting points 17.3, 23.3, 25.5, 27.5, 33.8, and 36.3 °C (63.1, 73.9, 77.9, 81.5, 92.8, and 97.3 °F), respectively. The production of chocolate aims to crystallise the chocolate so that the cocoa butter is predominantly in form V, which is the most stable form that can be obtained from melted cocoa butter. (Form VI either develops in solid cocoa butter after long storage or is obtained by crystallisation from solvents). A uniform form V crystal structure will result in smooth texture, sheen, and snap. This structure is obtained bychocolate tempering. Melting the cocoa butter in chocolate and then allowing it to solidify without tempering leads to the formation of unstable polymorphic forms of cocoa butter. This can easily happen when chocolate bars are allowed to melt in a hot room and lead to the formation of white patches on the surface of the chocolate called fat bloom orchocolate bloom.
Cocoa butter from different places has different properties. Malaysian and Indonesian cocoa butter generally crystallizes faster, and into a harder chocolate than Brazilian cocoa butter. Brazilian cocoa butter, after slowly crystallizing, forms a softer chocolate. West African cocoa butter has properties between the two.