Charcoal

Charcoalis a lightweight blackcarbonresidue produced by strongly heatingwood(or otheranimalandplantmaterials) in minimal oxygen to remove all water and volatile constituents. In the traditional version of thispyrolysisprocess, called charcoal burning, often by forming acharcoal kiln, the heat is supplied by burning part of the starting material itself, with a limited supply ofoxygen. The material can also be heated in a closedretort. Modern charcoalbriquettesused for outdoor cooking may contain many other additives, e.g.coal.
The history of wood charcoal production spans ancient times, rooted in the abundance of wood in various regions. The process typically involves stacking wood billets to form a conical pile, allowing air to enter through openings at the bottom, and igniting the pile gradually. Charcoal burners, skilled professionals tasked with managing the delicate operation, often lived in isolation to tend their wood piles. Throughout history, the extensive production of charcoal has been a significant contributor to deforestation, particularly in regions like Central Europe. However, various management practices, such ascoppicing, aimed to maintain a steady supply of wood for charcoal production. The scarcity of easily accessible wood resources eventually led to the transition to fossil fuel equivalents like coal.
Modern methods of charcoal production involve carbonizing wood in retorts, yielding higher efficiencies compared to traditional kilning methods. The properties of charcoal depend on factors such as the material charred and the temperature of carbonization.
Charcoal finds diverse applications, including metallurgical fuel in iron and steel production, industrial fuel, cooking and heating fuel, reducing agent in chemical processes, and as a raw material in pyrotechnics. It is also utilized in cosmetics, horticulture, animal husbandry, medicine, and environmental sustainability efforts, such as carbon sequestration.
However, the production and utilization of charcoal can have adverse environmental impacts, including deforestation and emissions. Illegal and unregulated charcoal production, particularly in regions like South America and Africa, poses significant challenges to environmental conservation efforts.
The production of wood charcoal in locations where there is an abundance of wood dates back to ancient times. It generally began with piling billets of wood on their ends to form a conical pile. Openings were left at the bottom to admitair, with a central shaft serving as aflue. The whole pile was covered with turf or moistenedclay. The firing began at the bottom of the flue, and the fire gradually spread outward and upward.
The traditional method inBritainused acharcoal pile or clamp.This was essentially a pile of wooden logs (e.g. seasoned oak) leaning in a circle against a chimney. The chimney consisted of 4 wooden stakes held up by some rope. In the clamp too the logs were completely covered with soil and straw allowing no air to enter. It must be lit by introducing some burning fuel into the chimney. The logs burned slowly and transformed into charcoal over a period of 5 days. If the soil covering became torn or cracked by the fire, additional soil was placed on the cracks. Once the burn was complete, the chimney was plugged to prevent air from entering.
The true art of this production method was in managing the sufficient generation of heat, by combusting part of the wood material, and the transfer of the heat to the wood in the process of being carbonized. The operation was so delicate that it was generally left tocolliers(professional charcoal burners). They often lived alone in small huts to tend their wood piles. For example, in theHarz Mountainsof Germany,charcoal burnerslived in conicalhutscalledKötenwhich still exist today.
The success of the operation depends upon the rate of thecombustion. Under average conditions wood yields about 60% charcoal byvolume, or 25% byweight;small-scale production methods often yield only about 50% by volume, while large-scale methods enabled higher yields of about 90% by the 17th century. A strong disadvantage of this production method is the huge amount of emissions that are harmful to human health and the environment (emissions of unburnt methane).As a result of the partial combustion of wood material, the efficiency of the traditional method is low.
The massive production of charcoal (at its height employing hundreds of thousands, mainly in Alpine and neighbouring forests) was a major cause ofdeforestation, especially inCentral Europe.Complaints (as early as theStuart period) about shortages may stem fromover-exploitationor the impossibility of increasing production to match growing demand. InEngland, many woods were managed ascoppices, which were cut and regrown cyclically, so that a steady supply of charcoal was available. But the increasing scarcity of easily harvested wood was a major factor behind the switch tofossil fuelequivalents, mainlycoalandbrown coalfor industrial use.
InFinlandandScandinavia, the charcoal was considered the by-product of wood tar production. The best tar came frompine, thus pinewoods were cut down for tarpyrolysis. The residual charcoal was widely used as substitute formetallurgicalcokeinblast furnacesforsmelting. Tar production led to rapid local deforestation. The end of tar production at the end of the 19th century resulted in rapid re-forestation of affected areas.
The American form of thecharcoal briquettewas first invented and patented by Ellsworth B. A. Zwoyer of Pennsylvania in 1897and was produced by theZwoyer Fuel Company. The process was further popularized byHenry Ford, who used wood and sawdust byproducts fromautomobile fabricationas afeedstock. Ford Charcoal went on to become theKingsford Company.
The modern process of carbonizing wood, either in small pieces or assawdustincast ironretorts, is extensively practiced where wood is scarce, and also for the recovery of valuable byproducts (wood spirit,pyroligneous acid,wood tar), which the process permits. The question of thetemperatureof thecarbonizationis important; according to J. Percy, wood becomes brown at 220 °C (430 °F), a deep brown-black after some time at 280 °C (540 °F), and an easily powdered mass at 310 °C (590 °F). Charcoal made at 300 °C (570 °F) is brown, soft and friable, and readily inflames at 380 °C (720 °F); made at higher temperatures it is hard and brittle, and does not fire until heated to about 700 °C (1,300 °F).
Modern methods employ retorting technology, in which process heat is recovered from, and solely provided by, the combustion of gas released during carbonization.Yields of retorting are considerably higher than those of kilning, and may reach 35%-40%.
The properties of the charcoal produced depend on the material charred. Thecharringtemperature is also important. Charcoal contains varying amounts of hydrogen and oxygen as well asashand other impurities that, together with the structure, determine the properties. The approximate composition of charcoal forgunpowdersis sometimes empirically described as C7H4O.To obtain a coal with high purity, source material should be free of non-volatile compounds.
Wood charcoal is obtained as the residue bydestructive distillationof wood such that the products are:
Charcoal has been used since earliest times for a large range of purposes including art and medicine, but by far its most important use has been as a metallurgical fuel. Charcoal is the traditional fuel of a blacksmith's forge and other applications where an intense heat is required. Charcoal was also used historically as a source of blackpigmentby grinding it up. In this form charcoal was important to early chemists and was a constituent of formulas for mixtures such asblack powder. Due to its highsurface area, charcoal can be used as a filter,catalyst, or adsorbent.
Charcoal burns at temperatures exceeding 1,100 degrees Celsius (2,010 degrees Fahrenheit).By comparison, the melting point ofironis approximately 1,200 to 1,550 °C (2,190 to 2,820 °F). Due to its porosity, it is sensitive to the flow of air and the heat generated can be moderated by controlling the air flow to the fire. For this reason charcoal is still widely used by blacksmiths. Charcoal has been used for the production of iron andsteel(where it also provided the necessary carbon) since at least 2000BCE, with artifacts having been found in Proto-Hittite layers atKaman-Kalehöyük.Charcoal briquettes can burn up to approximately 1,260 °C (2,300 °F) with a forced air blower forge.
In the 16th century, England had to pass laws to prevent the country from becoming completely denuded of trees due to production of iron.In the 19th century charcoal was largely replaced by coke in steel production due to cost, even though coke usually adds sulphur and sometimes other deleterious contaminants to the pig iron. Wooded metallurgical regions devoid of coal like Sweden, the Urals, or Siberia transitioned from charcoal in the early 20th century.
Prior to the Industrial Revolution, charcoal was occasionally used as a cookingfuel. It is counted as asmokeless fuel; that is, the carbon is sufficiently pure that burning it causes substantially less air pollution than burning the original uncarbonized organic material would. In the 20th century, clean-air legislation mandated smokeless fuels (mostly coke or charcoal) in many areas of Europe. In the 21st century, charcoal has been advocated as a way to improve the health of people burning raw biomass forcookingand/or heating. Modern "charcoal" briquettes, widely used for outdoor cooking, are made with charcoal but may also include coal as an energy source as well as accelerants, binders and filler.
To contain the charcoal and use it for cooking purposes, abarbecue grillmay be used. A small Japanese charcoal grill is known as ashichirin. Abrazieris a container used to burn charcoal or other solid fuel.
To start the charcoal burning is harder than starting a wood fire andcharcoal lighter fluidmay be employed. Achimney starterorelectric charcoal starterare tools to help with starting to light charcoal.
Approximately 75% of fuel burned inHaitiis charcoal.
Certain types of charcoal, such as wood charcoal, are used for reducing heated metallic oxides to their respective metals:
Charcoal can also be used to reduce super heated steam to hydrogen (along with the formation of carbon monoxide):
Like many other sources of carbon, charcoal can be used for the production of varioussyngascompositions; i.e., various CO + H2+ CO2+ N2mixtures. The syngas is typically used as fuel, including automotive propulsion, or as a chemical feedstock.
In times of scarce petroleum, automobiles and even buses have been converted to burn wood gas: a gas mixture consisting primarily of dilutingatmosphericnitrogen, but also containing combustible gasses (mostlycarbon monoxide) released by burning charcoal or wood in awood gas generator. In 1931,Tang Zhongmingdeveloped an automobile powered by charcoal, and these cars were popular in China until the 1950s, and inoccupied FranceduringWorld War II, where they were calledgazogènes.
Charcoal is used in the production ofblack powder, which is used extensively in the production of fireworks. It is usually ground into a fine powder, with air float grade being the finest particle size available commercially. When used in black powder compositions, it is often ball-milled with other ingredients so that they are intimately mixed together. Certain charcoals perform better when used to make black powder; these include spruce, willow, paulownia and grapevine among others.Charcoal produces fine dark orange/goldensparks. Usually, powder with a mesh size from 10 to 325 is used to obtain showers of golden sparks in pyrotechnic compositions.
Charcoal is also incorporated in multiple cosmetic products.It can be produced from regular bamboo cut into small pieces and boiled in water to remove soluble compounds.Rawbamboo charcoalis obtained after drying and carbonization in an oven at elevated temperature.The role of charcoal in cosmetics is based on its highly effective absorbing properties at a microscopic scale.
Charcoal may be used as a source of carbon in chemical reactions. One example of this is the production ofcarbon disulphidethrough the reaction of sulfur vapors with hot charcoal. In that case, the wood should be charred at high temperature to reduce the residual amounts of hydrogen and oxygen that lead to side reactions.
Charcoal may beactivatedto increase its effectiveness as a filter.Activated charcoalreadily adsorbs a wide range of organic compounds dissolved or suspended in gases and liquids. In certain industrial processes, such as the purification of sucrose from cane sugar, impurities cause an undesirable color, which can be removed with activated charcoal. It is also used to absorbodorsand toxins in gaseous solutions, as in home air purifiers and some types ofgas mask. The medical use of activated charcoal is mainly theabsorptionofpoisons.Activated charcoal is available without a prescription, so it is used for a variety of health-related applications. For example, it is often used to reduce discomfort and embarrassment due to excessive gas (flatulence) in the digestive tract.
Animal charcoal or bone black is the carbonaceousresidueobtained by the dry distillation of bones. It contains only about 10% carbon, the remaining being calcium andmagnesiumphosphates (80%) and other inorganic material originally present in the bones. It is generally manufactured from the residues obtained in theglueandgelatinindustries. Its bleaching power was applied in 1812 by Derosne for clarifyingsugarsyrup, but its use in this direction has now greatly diminished. Today it is seldom used for this purpose due to the introduction of more active and easily managed reagents, but it is still employed to some extent inlaboratorypractice. The bleaching action of the charcoal in solution diminishes as it adsorbs colored contaminants, and it must be reactivated periodically by separate washing and reheating.While wood charcoal effectively removes some pigments and contaminants from solutions, bone charcoal is generally more effective as an adsorption filter due to its increased porosity and surface area.
Charcoalis used fordrawing, making roughsketchesinpainting, and is one of the possible media used for making aparsemage. It usually must be preserved by the application of afixative. Artists generally utilize charcoal in four forms:
One additional use of charcoal was rediscovered recentlyforhorticulture. Although American gardeners have used charcoal for a short time,researchonTerra pretasoils inAmazoniahas discovered the widespread use ofbiocharbypre-Columbiannatives to ameliorate unproductivesoilinto soil rich incarbon. The technique may find modern application, both to improve soils and as a means ofcarbon sequestration.
Charcoal is mixed with feed, added tolitter, or used in the treatment ofmanure.Poultry benefits from using charcoal in this manner.
A concern that activated charcoal might be used unscrupulously to allow livestock to tolerate low quality feed contaminated withaflatoxinsresulted in the Association of American Feed Control Officials banning it in 2012 from use in commercial livestock feeds.
Charcoal in the form ofcharcoal biscuitswas consumed in the past for gastric problems. Now it can be consumed in tablet, capsule, or powder form for digestive effects.Research regarding its effectiveness is controversial.
Charcoal has been used in combination withsaccharinin research to measuremucociliarytransport time.
Charcoal has also been incorporated intotoothpasteformulas; however, there is no evidence to determine its safety and effectiveness.
Red colobusmonkeys in Africa have been observed eating charcoal for self-medication. Because their leafy diets contain high levels ofcyanide, which may lead to indigestion, they learned to consume charcoal, which absorbs the cyanide and relieves discomfort. This knowledge is transmitted from mother to infant.
Production and utilization of charcoal, like any use of woody biomass as fuel, typically results in emissions and can contribute to deforestation.
The use of charcoal as a smelting fuel has been experiencing a resurgence inSouth Americaresulting in severe environmental, social and medical problems.Charcoal production at a sub-industrial level is one of the causes of deforestation. Charcoal production is now usually illegal and nearly always unregulated, as inBrazil, where charcoal production is a large illegal industry for makingpig iron.
Massive forest destruction has been documented in areas such asVirunga National Parkin theDemocratic Republic of Congo, where it is considered a primary threat to the survival of the mountain gorillas.Similar threats are found inZambia.InMalawi, illegal charcoal trade employs 92,800 workers and is the main source of heat and cooking fuel for 90 percent of the nation's population.Some experts, such as Duncan MacQueen, Principal Researcher–Forest Team,International Institute for Environment and Development (IIED), argue that while illegal charcoal production causes deforestation, a regulated charcoal industry that required replanting and sustainable use of the forests "would give their people clean efficient energy – and their energy industries a strong competitive advantage".
Recent assessments of charcoal imported to Europe have shown that many charcoal products are produced from tropical wood, often of undeclared origin. In an analysis of barbecue charcoal marketed in Germany, theWorld Wildlife Fundfound that most products contain tropical wood. As a notable exception, reference is made to barbecue charcoal imports fromNamibia, where charcoal is typically produced from surplus biomass resulting fromwoody plant encroachment.Charcoal trafficking in Somaliais an economic and environmental issue with significant regional-security implications.
The last section of the filmLe Quattro Volte(2010) gives a good and long, if poetic, documentation of the traditional method of making charcoal.TheArthur Ransomechildren's seriesSwallows and Amazons(particularly the second book,Swallowdale) features carefully drawn vignettes of the lives and the techniques of charcoal burners at the start of the 20th century, in theLake Districtof the UK.Antonín Dvořák'soperaKing and Charcoal Burneris based on a Czech legend about a king who gets lost in a forest and is rescued by a charcoal burner.