page_title: Samarium
section_title: Other inorganic compounds
hierarchical_section_title: Samarium / Compounds / Other inorganic compounds
caption_attribution_description: English: Yellow samarium sulfate, Sm2(SO4)3. Vial diameter 1 cm.
context_page_description: Samarium is a chemical element with the symbol Sm and atomic number 62. It is a moderately hard silvery metal that slowly oxidizes in air. Being a typical member of the lanthanide series, samarium usually assumes the oxidation state +3. Compounds of samarium(II) are also known, most notably the monoxide SmO, monochalcogenides SmS, SmSe and SmTe, as well as samarium(II) iodide. The last compound is a common reducing agent in chemical synthesis. Samarium has no significant biological role but is only slightly toxic.
  Samarium was discovered in 1879 by the French chemist Paul-Émile Lecoq de Boisbaudran and named after the mineral samarskite from which it was isolated. The mineral itself was earlier named after a Russian mine official, Colonel Vassili Samarsky-Bykhovets, who thereby became the first person to have a chemical element named after him, albeit indirectly. Although classified as a rare-earth element, samarium is the 40th most abundant element in the Earth's crust and is more common than metals such as tin.
context_section_description: Samarium carbides are prepared by melting a graphite-metal mixture in an inert atmosphere. After the synthesis, they are unstable in air and are studied also under inert atmosphere. Samarium monophosphide SmP is a semiconductor with the bandgap of 1.10 eV, the same as in silicon, and high electrical conductivity of n-type. It can be prepared by annealing at 1100 °C an evacuated quartz ampoule containing mixed powders of phosphorus and samarium. Phosphorus is highly volatile at high temperatures and may explode, thus the heating rate has to be kept well below 1 °C/min. Similar procedure is adopted for the monarsenide SmAs, but the synthesis temperature is higher at 1800 °C.
  Numerous crystalline binary compounds are known for samarium and one of the group-14, 15 or 16 element X, where X is Si, Ge, Sn, Pb, Sb or Te, and metallic alloys of samarium form another large group. They are all prepared by annealing mixed powders of the corresponding elements. Many of the resulting compounds are non-stoichiometric and have nominal compositions SmₐXb, where the b/a ratio varies between 0.5 and 3.
caption: Samarium sulfate, Sm2(SO4)3
exif: {"Image ImageDescription": "SONY DSC", "Image Make": "SONY", "Image Model": "DSLR-A300", "Image Orientation": "Horizontal (normal)", "Image XResolution": "72", "Image YResolution": "72", "Image ResolutionUnit": "Pixels/Inch", "Image Software": "Adobe Photoshop CS2 Windows", "Image DateTime": "2013:09:06 19:34:59", "Image YCbCrPositioning": "Co-sited", "Image PrintIM": "[80, 114, 105, 110, 116, 73, 77, 0, 48, 51, 48, 48, 0, 0, 6, 0, 1, 0, 22, 0, ... ]", "Image ExifOffset": "372", "Thumbnail Compression": "JPEG (old-style)", "Thumbnail XResolution": "72", "Thumbnail YResolution": "72", "Thumbnail ResolutionUnit": "Pixels/Inch", "Thumbnail JPEGInterchangeFormat": "1050", "Thumbnail JPEGInterchangeFormatLength": "4391", "EXIF ExposureTime": "1/30", "EXIF FNumber": "28/5", "EXIF ExposureProgram": "Program Normal", "EXIF ISOSpeedRatings": "100", "EXIF ExifVersion": "0221", "EXIF DateTimeOriginal": "2010:12:07 12:20:25", "EXIF DateTimeDigitized": "2010:12:07 12:20:25", "EXIF ComponentsConfiguration": "YCbCr", "EXIF CompressedBitsPerPixel": "8", "EXIF BrightnessValue": "13/2", "EXIF ExposureBiasValue": "13/10", "EXIF MaxApertureValue": "497/100", "EXIF MeteringMode": "Pattern", "EXIF LightSource": "Unknown", "EXIF Flash": "Flash did not fire, compulsory flash mode", "EXIF FocalLength": "180", "EXIF FlashPixVersion": "0100", "EXIF ColorSpace": "sRGB", "EXIF ExifImageWidth": "673", "EXIF ExifImageLength": "669", "Interoperability InteroperabilityIndex": "R98", "Interoperability InteroperabilityVersion": "[48, 49, 48, 48]", "EXIF InteroperabilityOffset": "924", "EXIF FileSource": "Digital Camera", "EXIF SceneType": "Directly Photographed", "EXIF CustomRendered": "Normal", "EXIF ExposureMode": "Auto Exposure", "EXIF WhiteBalance": "Auto", "EXIF FocalLengthIn35mmFilm": "270", "EXIF SceneCaptureType": "Standard", "EXIF Contrast": "Normal", "EXIF Saturation": "Normal", "EXIF Sharpness": "Normal"}