Two-Dimensional Optical Spectroscopy

Introduction Quantum Dynamics Time Evolution in Hilbert Space Time-Dependent Perturbation Theory in Hilbert Space Diagram Representation of the Time-Dependent Perturbation Theory in Hilbert Space Transition Amplitude and Probability in Hilbert Space Time Evolution in Liouville Space Time-Dependent Perturbation Theory in Liouville Space Transition Probability in Liouville Space and Pathways Linear Response Spectroscopy Linear Response Function System-Bath Interaction and Line Broadening Rotational Averaging of Tensors Linear Absorption Spectroscopy Raman Scattering Hyper-Raman Scattering IR-Raman Surface Vibrational Spectroscopy Raman-IR Surface Vibrational Spectroscopy Appendix: Nonlinear Polarization and Generated Signal Electric Field Second-Order Response Spectroscopy Second-Order Response Function Three-Level System and Line-Broadening Function Sum-Frequency Generation Difference-Frequency Generation IR-IR-vis Four-Wave Mixing Third-Order Response Spectroscopy Third-Order Response Function Four-Level System and Line-Broadening Function Short-Time Approximation to the Third-Order Response Function Third-Order Response Function of a Two-Level System Pump-Probe Spectroscopy of a Two-Level System Rephasing Photon Echo Spectroscopy of a Two-Level System Non-Rephasing Photon Echo Spectroscopy of a Two-Level System Three-Pulse Photon Echo Peak Shift (PEPS) Two-Dimensional Pump-Probe Spectroscopy Introduction to Two-Dimensional Pump-Probe Spectroscopy Two-Dimensional Pump-Probe Spectrum of 2LS Two-Dimensional Pump-Probe Spectrum of Anharmonic Oscillator Two-Dimensional Photon Echo Spectroscopy Phase and Amplitude Detection of Two-Dimensional Photon Echo Signal Field Two-Dimensional Photon Echo Spectrum: A Two-Level System Two-Dimensional Non-Rephasing Spectrum: A Two-Level System Two-Dimensional Photon Echo Spectrum: An Anharmonic Oscillator Simple Two-Dimensional Lorentzian Peak Shape Simple Two-Dimensional Gaussian Peak Shape Coupled Multi-Chromophore System Frenkel Hamiltonian in Site Representation Delocalized Exciton Representation Delocalized State Energy and Transition Dipole Matrix Element Transition FFCFs Exchange-Narrowing Effect on Absorption Spectrum Measurements of Auto and Cross FFCFs Exciton Population Transfer Two-Dimensional Spectroscopy of Coupled Dimers Model Hamiltonian of a Coupled 2LS Dimer Delocalized Excited-State Energy Fluctuations and Time-Correlation Functions Coupled 2LS Dimer: Quantum Beats at Short Time Coupled 2LS Dimer: Intermediate Time Region Coupled 2LS Dimer: Population Transfer Effects Coupled Anharmonic Oscillators: Model Hamiltonian Coupled Anharmonic Oscillators: Two-Dimensional Photon Echo Spectrum at Short Time Coupled Anharmonic Oscillators: Degenerate Case Coupled Anharmonic Oscillators: Population Transfer Effects Chemical Exchange and Two-Dimensional Spectroscopy Model System Chemical Exchange Diagrams: Two-Level System Chemical Exchange Diagrams: Anharmonic Oscillator Polarization-Controlled Two-Dimensional Spectroscopy Parallel Polarization ZZZZ-Echo: Two-Level System Perpendicular Polarization ZYYZ-Echo: Two-Level System Difference Two-Dimensional Photon Echo Spectrum: Coupled 2LS Dimer Parallel Polarization ZZZZ-Echo: Anharmonic Oscillators Perpendicular Polarization ZYYZ-Echo: Anharmonic Oscillators Difference Two-Dimensional Echo Spectrum: Coupled Anharmonic Oscillators Generalized Polarization-Controlled Two-Dimensional Spectroscopy Determination of the Angle between Any Two Transition Dipole Vectors Applications of Two-Dimensional Vibrational Spectroscopy Single Anharmonic Oscillator Systems Coupled Two-Oscillator Systems Polypeptide Secondary Structures Globular Proteins and Membrane-Bound Proteins Nucleic Acids Hydrogen-Bonding Dynamics and Chemical Exchange Solute-Solvent Complexation and Micro-Solvation Internal Rotation Transient Two-Dimensional IR Spectroscopy: Protein Folding and Unfolding Applications of Two-Dimensional Electronic Spectroscopy Application to Fenna-Matthews-Olson Light-Harvesting Complex Application to Semiconductors Two-Dimensional Second-Order Response Spectroscopy Two-Dimensional Sum-Frequency Generation Two-Dimensional SFG of Solution Sample Two-Dimensional SFG of Coupled 2LS Dimer Two-Dimensional SFG of Coupled Anharmonic Oscillators Two-Dimensional Difference-Frequency Generation IR-IR-vis SFG and DFG Other IIV Four-Wave Mixings Fifth-Order Raman Scattering Linear Optical Activity Spectroscopy Radiation-Matter Interaction Hamiltonian and Polarization Circular Dichroism and Optical Rotatory Dispersion Raman Optical Activity IR-Raman Optical Activity Spectroscopy Raman-IR Optical Activity Spectroscopy Nonlinear Optical Activity Spectroscopy Nonlinear Optical Activity Measurement Methods Rotational Averaging of Higher-Rank Tensors Two-Dimensional Optical Activity Pump-Probe: Two-Level System Two-Dimensional Optical Activity Photon Echo: Two-Level System Two-Dimensional Optical Activity Photon Echo of Coupled 2LS Dimer References appear at the end of each chapter.