cssi/SciSciGPT-SciSciNet huggingface dataset:
Climate-responsive Social Protection

In the years ahead, development efforts aiming at reducing vulnerability will increasingly have to factor in climate change, and social protection is no exception. This paper sets out the case for climate?responsive social protection and proposes a framework with principles, design features, and functions that would help Social Protection (SP) systems evolve in a climate?responsive direction. The principles comprise climate?aware planning; livelihood?based approaches that consider the full range of assets and institutions available to households and communities; and aiming for resilient communities by planning for the long term. Four design features that can help achieve this are: scalable and flexible programs that can increase coverage in response to climate disasters; climate?responsive targeting systems; investments in livelihoods that build community and household resilience; and promotion of better climate risk management.
Nucleobases as supramolecular motifs

The five main natural nucleobases adenine, cytosine, guanine, thymine and uracil are involved in the self-assembly of one of nature's most interesting and intriguing class of biopolymers, namely the nucleic acids DNA and RNA. As such, these nucleobases have held a fascination to researchers in a diverse range of fields. With the growth in the field of supramolecular chemistry and consequently a better understanding of how molecules interact with each other, more and more information is emerging on the complex supramolecular behaviour of these nucleobase. This tutorial review tries to bring together some of the basic concepts of how nucleobases can interact not only with each other, but also with other small organic molecules as well as metals and then looks at how such an understanding is starting to influence the development of new materials and polymers.
A new approach to the Ramsey-type games and the Gowers dichotomy in F -spaces

We give a new approach to the Ramsey-type results of Gowers on block bases in Banach spaces and apply our results to prove the Gowers dichotomy in F-spaces.
The Advantages of the Civil Law Judicial Design as the Model for Emerging Legal Systems

Currently, a number of societies around the world are reforming their legal systems, often upon emerging from years of oppression. Two transatlantic models, the civil law and common law, will have a great influence on these reforms. For one thing, the two basic models already cover over 70 percent of the world’s population in some 62 percent of the existing legal systems. Moreover, there will be many practical, economic advantages to westernizing a legal system, which necessarily means incorporating at least some aspects of one or both transatlantic models. The key is to extract the best features of the models and adapt them to the specific legal culture. The civil law approach to judicial design in particular has much to recommend it. A dominant feature of the civil law model is the responsibility it places on the judge in dispute resolution. True, common law judges have
Some properties of generalized factorable 2-D FIR filters

A paper by Chen and Vaidyanathan (1993) describes a method for designing multidimensional (MD) filters with spectral support in the shape of a parallelepiped, starting from M 1-D prototypes. Such filters require a number of elementary operations per input sample (OPS) that grows linearly with the size of each 1-D prototype. As a matter of fact, they belong to the general class of generalized factorable (GF) filters, which we define here. Beside the computational efficiency (in both the design and the implementation), we show in this work that GF filters share some interesting properties (relative to symmetry and frequency response constraints).
The enantioselective construction of tetracyclic diterpene skeletons with Friedel-Crafts alkylation and palladium-catalyzed cycloalkenylation reactions.

Due to the profound extent to which natural products inspire medicinal chemists in drug discovery, there is demand for innovative syntheses of these often complex materials. This article describes the synthesis of tricarbocyclic natural product architectures through an extension of the enantioselective Birch–Cope sequence with intramolecular Friedel–Crafts alkylation reactions. Additionally, palladium-catalyzed enol silane cycloalkenylation of the tricarbocyclic structures afforded the challenging bicyclo[3.2.1]octane C/D ring system found in the gibberellins and the ent-kauranes, two natural products with diverse medicinal value. In the case of the ent-kaurane derivative, an unprecedented alkene rearrangement converted four alkene isomers to one final product.
Synthesis of cyclophanes via an intermolecular Pd-catalyzed enyne-diyne cross-benzannulation approach.

Several novel types of cyclophanes were efficiently synthesized via an intermolecular palladium-catalyzed cross-benzannulation of cyclic enynes and diynes. These types of cyclophanes are not accessible through an intramolecular mode of the homo-benzannulation protocol, reported previously. Cyclic reactants (enynes and diynes) were readily prepared in reasonable yields from commercially available materials using known procedures. The fact that the cyclic Z-enyne 29, in contrast to its E-counterpart, underwent benzannulation to produce the cyclophane 28 brought additional support for the necessity of having an E-hydrogen atom at the terminal olefin moiety of nonactivated enynes, which was found previously in the benzannulation of the acyclic susbstrates.
Quantum Computing: Pro and Con

I assess the potential of quantum computation. Broad and important applications must be found to justify construction of a quantum computer; I review some of the known quantum algorithms and consider the prospects for finding new ones. Quantum computers are notoriously susceptible to making errors; I discuss recently developed fault–tolerant procedures that enable a quantum computer with noisy gates to perform reliably. Quantum computing hardware is still in its infancy; I comment on the specifications that should be met by future hardware. Over the past few years, work on quantum computation has erected a new classification of computational complexity, has generated profound insights into the nature of decoherence, and has stimulated the formulation of new techniques in high–precision experimental physics. A broad interdisciplinary effort will be needed if quantum computers are to fulfil their destiny as the world9s fastest computing devices. This paper is an expanded version of remarks that were prepared for a panel discussion at the ITP Conference on Quantum Coherence and Decoherence, December 1996.
Virtual astronomy, information technology, and the new scientific methodology

All sciences, including astronomy, are now entering the era of information abundance. The exponentially increasing volume and complexity of modern data sets promises to transform the scientific practice, but also poses a number of common technological challenges. The virtual observatory concept is the astronomical community's response to these challenges: it aims to harness the progress in information technology in the service of astronomy, and at the same time provide a valuable testbed for information technology and applied computer science. Challenges broadly fall into two categories: data handling (or "data farming"), including issues such as archives, intelligent storage, databases, interoperability, fast networks, etc., and data mining, data understanding, and knowledge discovery, which include issues such as automated clustering and classification, multivariate correlation searches, pattern recognition, visualization in highly hyperdimensional parameter spaces, etc., as well as various applications of machine learning in these contexts. Such techniques are forming a methodological foundation for science with massive and complex data sets in general, and are likely to have a much broader impact on the modern society, commerce, information economy, security, etc. There is a powerful emerging synergy between the computationally enabled science and the science-driven computing, which will drive the progress in science, scholarship, and many other venues in the 21st century.
Using Cluster Randomized Field Experiments to Study Voting Behavior

Voter mobilization experiments are often conducted using individual-level randomization, which can be difficult to implement. A simpler approach is to randomly assign voting precincts, rather than individuals nested within them, to treatment and control groups. Not only is it easier and potentially less expensive to implement, it may allow researchers to study vote preference effects without collecting survey data. This article explores various methodological concerns that researchers should consider when designing and analyzing precinct-level experiments. These concerns are illustrated using data from a precinct-level randomized field experiment conducted in Kansas City, Missouri.
The role of binding energies of neutron stars on the accretion-driven evolution

Millisecond pulsars are believed to descend from low-mass X-ray binaries. Observable parameters of binary millisecond pulsars, e.g. mass of the pulsar, mass of the companion, spin period of the pulsar, orbital period, orbital eccentricity, etc., are used to probe the past accretion history of the millisecond pulsars. However, unfortunately in these studies the binding energy of the neutron star is not commonly considered. We show that the effect of the binding energy is significant in the estimation of the amount of mass accretion, and thus should be incorporated in models for binary evolutions. Moreover, different equations of state for dense matter give different values for the accreted mass for the same amount of increase in the gravitational mass of the neutron star, implying the need of constraining dense matter equations of state even to understand the spin-up procedure properly.
Stratospheric Effects from Aviation

Present understanding indicates that there is no imminent threat of ozone reduction from any type of existing aircraft, although substantial uncertainties remain. Thus there appears to be no immediate requirement to develop regulations that would mandate a reduction in cruise-altitude emissions of subsonic or supersonic aircraft. There is a clear necessity for continued study to reduce remaining uncertainties and to establish a uniform and internationally agreed accurate emission measurement scheme. Building a framework for regulation (if necessary) of future types of high-altitude aircraft, such as those frequently referred to as a "second-generation SST," or the even higher-flying hypersonic transport (HST), is also necessary.
Volume rendering in the presence of partial volume effects

In tomographic imagery, partial volume effects (PVEs) cause several artifacts in volume renditions. In X-ray computed tomography (CT), for example, soft-tissue-like pseudo structures appear in bone-to-air and bone-to-fat interfaces. Further, skin, which is identical to soft tissue in terms of CT number, obscures the rendition of the latter. The purpose of This work is to demonstrate these phenomena and to provide effective solutions that yield significantly improved renditions. We introduce two methods that detect and classify voxels with PVE in X-ray CT. Further, a method is described to automatically peel skin so that PVE-resolved renditions of bone and soft tissue reveal considerably more detail. In the first method to address PVE, called the fraction measure (FM) method, the fraction of each tissue material in each voxel v is estimated by taking into account the intensities of the voxels neighboring v. The second method, called uncertainty principle (UP) method, is based on the following postulate (Saha and Udupa, 2001): In any acquired image, voxels with the highest uncertainty occur in the vicinity of object boundaries. The removal of skin is achieved by means of mathematical morphology. Volume renditions have been created before and after applying the methods for several patient CT datasets. A mathematical phantom experiment involving different levels of PVE has been conducted by adding different degrees of noise and blurring. A quantitative evaluation is done utilizing the mathematical phantom and clinical CT data wherein an operator carefully masked out voxels with PVE in the segmented images. All results have demonstrated the enhanced quality of display of bone and soft tissue after applying the proposed methods. The quantitative evaluations indicate that more than 98% of the voxels with PVE are removed by the two methods and the second method performs slightly better than the first. Further, skin peeling vividly reveals fine details in the soft tissue structures.
Chiral formamidines. Asymmetric synthesis of 1,1-disubstituted tetrahydroisoquinolines.

Abstract Use of a modified auxiliary allowed for the asymmetric synthesis of quaternary carbons adjacent to nitrogen in tetrahydroisoquinolines.
Multi-group full-spectrum k-distribution database for water vapor mixtures in radiative transfer calculations

A thorough investigation of the absorption coefficient dependence on temperature and pressure has been performed for water vapor and a 32-group database has been assembled for H2O mixtures at atmospheric pressure, based on the multi-group full-spectrum correlated k-distribution model. The method is fully scalable, i.e., spectral groups from the database can be combined to obtain coarser group models (N ¼ 1; 2; 4; .. .) for greater numerical efficiency (accompanied by slight loss in accuracy). The databases for CO2 and H2O, together with the random-overlap mixture model have been used to simulate a practical combustion problem. 2003 Elsevier Ltd. All rights reserved.
Applying the Generalized Waring model for investigating sources of variance in motor vehicle crash analysis

As one of the major analysis methods, statistical models play an important role in traffic safety analysis. They can be used for a wide variety of purposes, including establishing relationships between variables and understanding the characteristics of a system. The purpose of this paper is to document a new type of model that can help with the latter. This model is based on the Generalized Waring (GW) distribution. The GW model yields more information about the sources of the variance observed in datasets than other traditional models, such as the negative binomial (NB) model. In this regards, the GW model can separate the observed variability into three parts: (1) the randomness, which explains the model's uncertainty; (2) the proneness, which refers to the internal differences between entities or observations; and (3) the liability, which is defined as the variance caused by other external factors that are difficult to be identified and have not been included as explanatory variables in the model. The study analyses were accomplished using two observed datasets to explore potential sources of variation. The results show that the GW model can provide meaningful information about sources of variance in crash data and also performs better than the NB model.
An infinite surface with the lattice property I: veech groups and coding geodesics

We study the symmetries and geodesics of an infinite translation surface which arises as a limit of translation surfaces built from regular polygons, studied by Veech. We find the affine symmetry group of this infinite translation surface, and we show that this surface admits a deformation into other surfaces with topologically equivalent affine symmetries. The geodesics on these new surfaces are combinatorially the same as the geodesics on the
The genesis of public health ethics

As bioethics emerged in the 1960s and 1970s and began to have enormous impacts on the practice of medicine and research--fuelled, by broad socio-political changes that gave rise to the struggles of women, African Americans, gay men and lesbians, and the antiauthoritarianism impulse that characterised the New Left in democratic capitalist societies--little attention was given to the question of the ethics of public health. This was all the more striking since the core values and practices of public health, often entailing the subordination of the individual for the common good, seemed opposed to the ideological impulses of bioethics. Of what relevance is autonomy-focused bioethics for public health, with its mix of justifications including those that are either implicitly or explicitly paternalistic or that seek to impose strictures on individuals and communities in the name of collective welfare? To examine the deep divide between the central commitments of bioethics and the values that animate the practice of public health, we focus on a series of controversies implicating the concepts of privacy, liberty, and paternalism. Recognising the role of moral values in decision-making was a signal contribution of bioethics in its formative period. Over the past three decades a broad array of perspectives emerged under the rubric of bioethics but individualism remains central. As we commence the process of shaping an ethics of public health, it is clear that bioethics is the wrong place to start when thinking about the balances required in defence of the public's health.
Locality and low-dimensions in the prediction of natural experience from fMRI

Functional Magnetic Resonance Imaging (fMRI) provides dynamical access into the complex functioning of the human brain, detailing the hemodynamic activity of thousands of voxels during hundreds of sequential time points. One approach towards illuminating the connection between fMRI and cognitive function is through decoding; how do the time series of voxel activities combine to provide information about internal and external experience? Here we seek models of fMRI decoding which are balanced between the simplicity of their interpretation and the effectiveness of their prediction. We use signals from a subject immersed in virtual reality to compare global and local methods of prediction applying both linear and nonlinear techniques of dimensionality reduction. We find that the prediction of complex stimuli is remarkably low-dimensional, saturating with less than 100 features. In particular, we build effective models based on the decorrelated components of cognitive activity in the classically-defined Brodmann areas. For some of the stimuli, the top predictive areas were surprisingly transparent, including Wernicke's area for verbal instructions, visual cortex for facial and body features, and visual-temporal regions for velocity. Direct sensory experience resulted in the most robust predictions, with the highest correlation (c ~ 0.8) between the predicted and experienced time series of verbal instructions. Techniques based on non-linear dimensionality reduction (Laplacian eigenmaps) performed similarly. The interpretability and relative simplicity of our approach provides a conceptual basis upon which to build more sophisticated techniques for fMRI decoding and offers a window into cognitive function during dynamic, natural experience.
'I didn't buy it for myself': privacy and Ecommerce personalization

Ecommerce personalization can help web sites build and retain relationships with customers, but it also raises a number of privacy concerns. This paper outlines the privacy risks associated with personalization and describes a number of approaches to personalization system design that can reduce these risks. This paper also provides an overview of the fair information practice principles and discusses how they may be applied to the design of personalization systems, and introduces privacy laws and self-regulatory guidelines relevant to personalization. Privacy risks can be reduced when personalization system designs allow for pseudonymous interactions, client-side data stores, and task-based personalization. In addition, interfaces that allow users to control the collection and use of their profile information can further ease privacy concerns.
The incidence of high medical expenses by health status in seven developed countries

Health care policy seeks to ensure that citizens are protected from the financial risk associated with needing health care. Yet rising health care costs in many countries are leading to a greater reliance on out-of-pocket (OOP) measures. This paper uses 2010 household survey data from seven countries to measure and compare the burden OOP expenses place on individuals. It compares countries based on the extent to which citizens with health problems devote a large share of their income to OOP expenses. The paper finds that in all countries but France, and to a lesser extent Slovenia, citizens with health problems face considerably higher medical costs than do those without. As many as one-quarter of less healthy citizens in the US, Poland, Russia and Israel devote a large share of their income to OOP expenses. The paper also finds a strong cross-national correlation between the degree to which citizens face high OOP expenses, and the disparities in OOP expenses between those with and without health problems. The levels of high OOP spending uncovered, and their inequitable impact on those with health problems in the seven countries, underscore the potential for OOP measures to undermine core objectives of health care systems, including those of equitable financing, equal access, and improved health among the population.
The conversion of an aziridine plus an iminium salt to a 1,2-diamine

Abstract The conversion of an aziridine to a 1,2-diamine using lithium iodide and an iminium salt is discussed. We have found that when the aziridine is substituted by only alkyl groups, it is the less substituted carbonnitrogen bond that is broken; whereas, when the aziridine is substituted by a phenyl group at either the nitrogen or the carbon, it is the more substituted carbonnitrogen bond that is broken. For a 2,3-disubstituted aziridine, the reaction sequence goes with net retention of stereochemistry.
Singular Perturbation Theory for DC–DC Converters and Application to PFC Converters

Many control schemes for DC-DC converters begin with the assertion that inductor currents are ldquofastrdquo states and capacitor voltages are ldquoslowrdquo states. This assertion must be true for power factor correction (PFC) converters to allow independent control of current and voltage, and is important for many other applications. In the present study, singular perturbation theory is applied to two-state switching-power converters to provide rigorous justification of the timescale separation. Krylov-Bogoliubov-Mitropolsky averaging is used to include switching ripple effects. A relationship between inductance, capacitance, load resistance, and loss resistances derives from an analysis of the off-manifold dynamics of an approximate model. Similar results hold for boost, buck, and buck-boost converters. Experimental boost converters validate the results. Discrete-time analysis is also shown. Simulated PFC converters demonstrate a simple, sensorless control technique that requires timescale separation.
Global Collaborative Patents

We study the prevalence and traits of global collaborative patents for U.S. public companies, where the inventor team is located both within and outside of the United States. Collaborative patents are frequently observed when a corporation is entering into a new foreign region for innovative work, especially in settings where intellectual property protection is weak. We also connect collaborative patents to the ethnic composition of the firm's U.S. inventors and cross-border mobility of inventors within the firm. The inventor team composition has important consequences for how the new knowledge is exploited within and outside of the firm.
On output regulation for discrete-time nonlinear systems

Output regulation for a discrete-time nonlinear plant driven by an exogenous signal is addressed. In the absence of the standard exosystem hypothesis, we assume availability of the current and l past values of the exogenous signal for use in the control law. We formulate an approximate output regulation problem and characterize solvability in terms of the existence of a certain invariant manifold. The control law yields a closed-loop system with output exhibiting ultimate boundedness properties with respect to the (l + 1) difference of the exogenous signal. A perturbation analysis of robustness properties is also provided.
Offshoring: The Next Industrial Revolution?

IN FEBRUARY 2004, when N. Gregory Mankiw, a Harvard professor then serving as chairman of the White House Council of Economic Advisers, caused a national uproar with a "textbook" statement about trade, economists rushed to his defense. Mankiw was commenting on the phenomenon that has been clumsily dubbed "offshoring" (or "offshore outsourcing")-the migration of jobs, but not the people who perform them, from rich countries to poor ones. Offshoring, Mankiw said, is only "the latest manifestation of the gains from trade that economists have talked about at least since Adam Smith. ... More things are tradable than were tradable in the past, and that's a good thing." Although Democratic and Republican politicians alike excoriated Mankiw for his callous attitude toward American jobs, economists lined up to support his claim that offshoring is simply international business as usual. Their economics were basically sound: the well-known principle of comparative advantage implies that trade in new kinds of products will bring overall improvements in productivity and well-being. But Mankiw and his defenders underestimated both the importance of offshoring and its disruptive effect on wealthy countries. Sometimes a quantitative change is so large that it brings about qualitative changes,
Three-Actuator Deformable Water-Cooled Mirror

A new method for dynamically deforming a thin mirror to correct the phase aberration function for defocus and astigmatism is presented. Three piezoelectric-type actuators, attached to the back edges and parallel to the front surface of the mirror, induce edge moments that bend the mirror to its desired shape for correction of the aberrated wavefront. A three-actuator deformable water-cooled mirror breadboard has been designed and built. Major features, design constraints, and performance expectations of the deformable mirror design are described.
Dyson–Schwinger Equations: A Tool for Hadron Physics

Dyson–Schwinger equations furnish a Poincare covariant framework within which to study hadrons. A particular feature is the existence of a nonperturbative, symmetry preserving truncation that enables the proof of exact results. The gap equation reveals that dynamical chiral symmetry breaking is tied to the long-range behavior of the strong interaction, which is thereby constrained by observables, and the pion is precisely understood, and seen to exist simultaneously as a Goldstone mode and a bound state of strongly dressed quarks. The systematic error associated with the simplest truncation has been quantified, and it underpins a one-parameter model efficacious in describing an extensive body of mesonic phenomena. Incipient applications to baryons have brought successes and encountered challenges familiar from early studies of mesons, and promise a covariant field theory upon which to base an understanding of contemporary large momentum transfer data.
The Effective Field Theory of Dark Matter Direct Detection

We extend and explore the general non-relativistic effective theory of dark matter (DM) direct detection. We describe the basic non-relativistic building blocks of operators and discuss their symmetry properties, writing down all Galilean-invariant operators up to quadratic order in momentum transfer arising from exchange of particles of spin 1 or less. Any DM particle theory can be translated into the coefficients of an effective operator and any effective operator can be simply related to most general description of the nuclear response. We find several operators which lead to novel nuclear responses. These responses differ significantly from the standard minimal WIMP cases in their relative coupling strengths to various elements, changing how the results from different experiments should be compared against each other. Response functions are evaluated for common DM targets — F, Na, Ge, I, and Xe — using standard shell model techniques. We point out that each of the nuclear responses is familiar from past studies of semi-leptonic electroweak interactions, and thus potentially testable in weak interaction studies. We provide tables of the full set of required matrix elements at finite momentum transfer for a range of common elements, making a careful and fully model-independent analysis possible. Finally, we discuss embedding non-relativistic effective theory operators into UV models of dark matter.
Development of a Phase-Transfer-Catalyzed, [2,3]-Wittig Rearrangement

An investigation into the use of phase-transfer catalysis for the [2,3]-sigmatropic rearrangement of allyloxy carbonyl compounds is described. Initial studies focused on identifying viable substrate classes that would undergo selective [2,3]-rearrangement under phase-transfer catalysis. Under certain conditions, the [2,3]-sigmatropic rearrangement of allyloxy carbonyl compounds takes place in the presence of a phase-transfer agent, providing a rare example of a phase-transfer-catalyzed unimolecular reaction. In the course of this investigation, it was found that catalysis is dependent on several variables including base concentration, catalyst structure, and substrate lipophilicity. Preliminary testing of chiral, nonracemic phase-transfer catalysts has shown promising levels of enantioselectivity for future development.
Fast Convergence in the Double Oral Auction

A classical trading experiment consists of a set of unit demand buyers and unit supply sellers with identical items. Each agent’s value or opportunity cost for the item is his private information, and preferences are quasilinear. Trade between agents employs a double oral auction (DOA) in which both buyers and sellers call out bids or offers that an auctioneer recognizes. Transactions resulting from accepted bids and offers are recorded. This continues until there are no more acceptable bids or offers. Remarkably, the experiment consistently terminates in a Walrasian price. The main result of this article is a mechanism in the spirit of the DOA that converges to a Walrasian equilibrium in a polynomial number of steps, thus providing a theoretical basis for the empirical phenomenon described previously. It is well known that computation of a Walrasian equilibrium for this market corresponds to solving a maximum weight bipartite matching problem. The uncoordinated but mildly rational responses of agents thus solve in a distributed fashion a maximum weight bipartite matching problem that is encoded by their private valuations. We show, furthermore, that every Walrasian equilibrium is reachable by some sequence of responses. This is in contrast to the well-known auction algorithms for this problem that only allow one side to make offers and thus essentially choose an equilibrium that maximizes the surplus for the side making offers. Our results extend to the setting where not every agent pair is allowed to trade with each other.
Effects of Proximity to Supermarkets on a Randomized Trial Studying Interventions for Obesity.

Objectives. To determine whether proximity to a supermarket modified the effects of an obesity intervention.Methods. We examined 498 children aged 6 to 12 years with a body mass index (BMI) at or above the 95th percentile participating in an obesity trial in Massachusetts in 2011 to 2013. The practice-based interventions included computerized clinician decision support plus family self-guided behavior change or health coaching. Outcomes were 1-year change in BMI z-score, sugar-sweetened beverage intake, and fruit and vegetable intake. We examined distance to the closest supermarket as an effect modifier.Results. Distance to supermarkets was an effect modifier of 1-year change in BMI z-score and fruit and vegetable intake but not sugar-sweetened beverage intake. With each 1-mile shorter distance to a supermarket, intervention participants increased their fruit and vegetable intake by 0.29 servings per day and decreased their BMI z-score by −0.04 units relative to controls.Conclusions. Living closer to a su...
Landsat swath imaging spectrometer design

This paper describes the design of a high-throughput and high-uniformity pushbroom imaging spectrometer and telescope system that is capable of Landsat swath and resolution while providing better than 10 nm per pixel spectral resolution over the full visible to short-wave infrared band. The design is based on a 3200×480 element×18 μm pixel size focal plane array, two of which are utilized to cover the full swath. At an optical speed of F/1.8, the system is the fastest proposed to date to our knowledge. The utilization of only two Dyson-type spectrometer modules fed from the same telescope reduces system complexity while providing a solution within achievable detector technology. Two telescope designs are shown to achieve the required swath and resolution from different altitudes. Predictions of complete system response are shown. Also, it is shown that detailed ghost analysis is a requirement for this type of spectrometer and forms an essential part of a complete design.
Risk-Bearing and the Theory of Income Distribution

This paper develops the stochastic theory of distribution with a dynamic model which focuses on the role of incomplete insurance in generating inequality. Unlike previous work, our approach takes explicit account of the reason for market incompleteness in modeling agents' behaviour; in particular, the amount of risk borne is endogenous. Using a model of growth with altruism in which agents are risk-averse and there is moral hazard, we show that lineage wealth follows a Markov process which converges globally to an ergodic distribution; this also represents the long-run population distribution of wealth. We discuss the role of particular assumptions, such as availability of production loans and unboundedness of utility, in yielding the qualitative properties of the distribution of wealth, the choice of "occupation", and the prevention of poverty traps.
Exploratory synthesis: the fascinating and diverse chemistry of polar intermetallic phases.

Exploratory synthetic adventures regarding the inorganic chemistry of polar intermetallic phases have proven to be especially productive of novel compositions, new and unprecedented structures, and unusual bonding regimes. Reactions of diverse elements with widely different electronegativities allow the definition of two opposed classes of products: polycationic or polyanionic clusters or networks of metals paired with the corresponding monatomic anions or cations. These can be usefully viewed as intermetallic “salts”, redox products of simpler neutral intermetallic systems but with widely different factors governing their stabilities. Thus, combinations of rare-earth metals alone or with late transition metals form a novel variety of polymetal network structures with relatively isolated telluride (or halide) spacer anions. Similarly, extensions of traditional Zintl phases of the alkali or alkaline-earth metals from the later p elements to the earlier triels, Ga−Tl especially, yield many new and elegant p...
Pixel recurrent neural networks

Modeling the distribution of natural images is a landmark problem in unsupervised learning. This task requires an image model that is at once expressive, tractable and scalable. We present a deep neural network that sequentially predicts the pixels in an image along the two spatial dimensions. Our method models the discrete probability of the raw pixel values and encodes the complete set of dependencies in the image. Architectural novelties include fast two-dimensional recurrent layers and an effective use of residual connections in deep recurrent networks. We achieve log-likelihood scores on natural images that are considerably better than the previous state of the art. Our main results also provide benchmarks on the diverse ImageNet dataset. Samples generated from the model appear crisp, varied and globally coherent.
Trash-Talking: Competitive Incivility Motivates Rivalry, Performance, and Unethical Behavior

Abstract Trash-talking increases the psychological stakes of competition and motivates targets to outperform their opponents. In Studies 1 and 2, participants in a competition who were targets of trash-talking outperformed participants who faced the same economic incentives, but were not targets of trash-talking. Perceptions of rivalry mediate the relationship between trash-talking and effort-based performance. In Study 3, we find that targets of trash-talking were particularly motivated to punish their opponents and see them lose. In Study 4, we identify a boundary condition, and show that trash-talking increases effort in competitive interactions, but incivility decreases effort in cooperative interactions. In Study 5, we find that targets of trash-talking were more likely to cheat in a competition than were participants who received neutral messages. In Study 6, we demonstrate that trash-talking harms performance when the performance task involves creativity. Taken together, our findings reveal that trash-talking is a common workplace behavior that can foster rivalry and motivate both constructive and destructive behavior.
Semisupervised autoencoder for sentiment analysis

In this paper, we investigate the usage of autoencoders in modeling textual data. Traditional autoencoders suffer from at least two aspects: scalability with the high dimensionality of vocabulary size and dealing with task-irrelevant words. We address this problem by introducing supervision via the loss function of autoencoders. In particular, we first train a linear classifier on the labeled data, then define a loss for the autoencoder with the weights learned from the linear classifier. To reduce the bias brought by one single classifier, we define a posterior probability distribution on the weights of the classifier, and derive the marginalized loss of the autoencoder with Laplace approximation. We show that our choice of loss function can be rationalized from the perspective of Bregman Divergence, which justifies the soundness of our model. We evaluate the effectiveness of our model on six sentiment analysis datasets, and show that our model significantly outperforms all the competing methods with respect to classification accuracy. We also show that our model is able to take advantage of unlabeled dataset and get improved performance. We further show that our model successfully learns highly discriminative feature maps, which explains its superior performance.
Never Look Back: An Alternative to Centering

I propose a model for determining the hearer's attentional state which depends solely on a list of salient discourse entities (S-list). The ordering among the elements of the S-list covers also the function of the backward-looking center in the centering model. The ranking criteria for the S-list are based on the distinction between hearer-old and hearer-new discourse entities and incorporate preferences for inter- and intra-sentential anaphora. The model is the basis for an algorithm which operates incrementally, word by word.
The Pennsylvania Adoption Exchange Improves Its Matching Process

The Pennsylvania Adoption Exchange (PAE) helps caseworkers who represent children in Pennsylvania’s child welfare system by recommending prospective families for adoption. We describe PAE’s operational challenges using caseworker surveys, and analyze child outcomes through a regression analysis of data collected over multiple years. A match recommendation spreadsheet tool implemented by PAE incorporates insights from this analysis and allows PAE managers to better utilize available information. Using a discrete-event simulation of PAE, we justify the value of a statewide adoption network, and demonstrate the importance of generating better information about family preferences for increasing the percentage of children who are successfully adopted. Finally, we detail a series of simple improvements that PAE achieved by collecting more valuable information and aligning incentives for families to provide useful preference information.
Diarylation of alkenes by a Cu-catalyzed migratory insertion/cross-coupling cascade.

A strategy for the catalytic diarylation of alkenes is presented. The method involves the migratory insertion of alkenes into an Ar–Cu complex to generate a new C(sp3)–Cu complex, which subsequently undergoes reaction with an aryl iodide to constitute a vicinal diarylation of an alkene. The method provides access to benzofuran- and indoline-containing products. Furthermore, highly diastereoselective examples are presented, allowing access to complex, stereochemically rich structures from simple alkene starting materials.
An Unusual Cause Of Delirium

Sleep disordered breathing (SDB) including obstructive sleep apnea (OSA), central sleep apnea (CSA), and Cheyne-Stokes breathing is common in patients with congestive heart failure (CHF). In a study of 81 males with an ejection fraction (EF) < 45%, 51% of patients had documented SDB with the majority of cases representing CSA.1 Studies suggest that SDB is an independent risk factor for increased morbidity and mortality in the setting of CHF.2 Like OSA, CSA frequently presents with nighttime awakenings, nocturnal hypoxia, and daytime somnolence, but only OSA has been reported to present with delirium. We present a patient with clear manifestations of CSA with frank delirium that improved only after BPAP therapy. Citation: Becker K; Poon C; Zeidler M; Wang T. An unusual cause of delirium. J Clin Sleep Med 2010;6(3):290-291.
Brief vs. Comprehensive Descriptions in Measuring Intentions to Purchase

In forecasting demand for expensive consumer goods, direct questioning of potential consumers about their future purchasing plans has had considerable predictive success [1, 2, 4]. Any attempt to apply such "intention to purchase" methods to forecast demand for proposed products or services must determine some way to convey product information to the potential consumer [3]. Indeed, all the prospective consumer knows about the product or service is what he may infer from the information given to him by the researcher. This paper presents a study of the effect upon intention to purchase of this seemingly crucial element—the extent and type of description of the new service. How extensive must the description of the new service be in order to measure intention to purchase?
Prior Cardiac Surgery Is Independently Associated With Decreased Survival Following Infant Tracheostomy

INTRODUCTION: Previous reports have demonstrated that prior cardiac surgery is independently associated with in-hospital mortality after infant tracheostomy. We aimed to determine whether these infants would continue to be at increased risk for death following hospital discharge. METHODS: A retrospective review was performed on subjects < 2 y of age who recovered from tracheostomy in the pediatric ICU at our institution between January 2007 and December 2011, with follow-up to December 2013. Survival to 1 y following tracheostomy was the primary outcome variable for the study. Multivariate Cox regression analysis was then performed to determine independent risk factors for death after infant tracheostomy. RESULTS: Forty-two subjects met inclusion criteria, 18 of whom had undergone prior cardiac surgery. Twenty-six subjects (62%) were alive at 1 y post-tracheostomy. Age at tracheostomy, concomitant genetic abnormalities or prematurity, and ventilator dependence at discharge were not statistically different between survivors and those who died. Subjects who died, however, were more likely to have had cardiac surgery prior to tracheostomy (11 [69%] vs 7 [27%], P = .008) and had longer hospital stay (median 3.4 months [interquartile range: 2.6–4.6] vs 2.2 months [interquartile range: 1.1–3.5], P = .045). Multivariate Cox regression analysis revealed only prior cardiac surgery to be independently associated with decreased survival after tracheostomy (hazard ratio 4.7, 95% CI 1.3–16.4, P = .02). CONCLUSIONS: Prior cardiac surgery is independently associated with decreased survival within 1 y following tracheostomy. Clinicians and families of infants with prior cardiac surgery in whom tracheostomy after cardiac surgery is deemed necessary should consider this risk when planning long-term care.
The dark side of SSRIs: selective serotonin reuptake inhibitors.

Learn how to recognize medical and surgical complications associated with these commonly used antidepressants.
The Disordering Process in an Ll2 Ordered Alloy

The antiphase boundary (APB) structure and the disordering process have been studied by transmission electron microscopy (TEM) in a long-rangeordered alloy with Li2 structure and composition (Ni70Fe30)3(V58Al40Ti2). With an increase in temperature from a single-phase field into a two-phase field, disordering occurs both homogeneously within ordered domains and heterogeneously along APBs. Disordering continues by a ripening process with the disordered islands shrinking while the disordered bands on the prior APBs grow. The APBs are partially aligned on {100} while the material is single phase. As disordering proceeds, the degree of alignment of the disordered bands on {100} increases until complete alignment results. A correlation of the APB structure with room temperature mechanical properties indicates no dramatic change at the transition to the two-phase structure.
Value Creation: A Coordination Game

Strategy in negotiation is often modeled as an activity involving the interplay of creating and claiming behaviors. Theorists have advanced differing perspectives on what game best describes the consequences of choosing one approach over the other. David Lax and James Sebenius offer the prisoner's dilemma game as a model, whereas Richard Walton and Robert McKersie's analysis is consistent with a version of a classic coordination game — namely, the game of “chicken.” This article revisits these two perspectives and shows that the Walton–McKersie view is applicable to a broad range of contexts. In particular, it demonstrates how what is commonly called the tension between creating value and claiming is better understood as the simple tension between a high-risk and a low-risk choice.
Scanning Confocal Microscopy with A Microlens Array

Scanning confocal fluorescence microscopy is performed with a refractive microlens array. We simultaneously obtain an array of 3000 20μm x 20μm images with a lateral resolution of 645nm and observe low power optical sectioning.