Take a breath here. Your documentation plan is a work in progress for a while. Jump in and get started with some organizational system you think might work efficiently to have the papers you need available where you need them. Revise as you gain more experience with your management system. The rest will fall into place within 3 months.
Training Now determine who needs training.
Remember that all employees in your facility need to be familiar with your environmental policy and understand the environmental goals of your organization. Everyone needs to know their roles and responsibilities in helping the organization achieve its policy goals and its objectives and targets. They'll also need to understand the consequences of not following these policies. Additionally, some employees whose work is most closely associated with significant environmental aspects may need additional training to prevent or mitigate any adverse environmental impacts. It's also a requirement of ISO 14001 that you document your training records, in other words verify that employees have been trained as you deem necessary.