Get medical aid. Toluene sensitizes the heart to endogenous catelcholamines. No specific antidote exists. Water runoff can cause environmental damage. Dike and collect water used to fight fire.
Vapors can travel to a source of ignition and flash back.
Can release vapors that form explosive mixtures at temperatures above the flashpoint. Use water spray to keep fire-exposed containers cool. Water may be ineffective. Material is lighter than water and a fire may be spread by the use of water. Use dry chemical, carbon dioxide, or alcohol-resistant foam.