Give them soft, cuddly materials for bedding. Give it an article of clothing that you have worn with your scent on it. It will help the bonding process and assure it when it is alone. Good bedding materials are old towels, old sheets, blankets and even old articles of clothing. Just give him the bedding.
Skunks are talented and like to make their own beds.
It is a great deal of fun to watch them arrange their bedding. They pull the blanket backward with their front paws. Shoving it backwards. When they are young it is easier to have them in a confined space. You might want to keep them in an extra bedroom, or maybe the bathroom.