Thallium was discovered spectroscopically in 1861 by Crookes. The metal was isolated both by Crookes and Lamy in 1862 about the same time.
Thallium occurs in crooksite, lorandite, and hutchinsonite.
It is also present in pyrites and is recovered from the roasting of this ore in connection with the production of sulfuric acid. It is also obtained from the smelting of lead and zinc ores. Extraction is somewhat complex and depends on the source of the thallium. Manganese nodules, found on the ocean floor, contain thallium. When freshly exposed to air, thallium exhibits a metallic luster, but soon develops a bluish-gray tinge, resembling lead in appearance.