Ozone in the upper atmosphere, where it occurs naturally in what is known as the ozone layer, shields the Earth from the sun's dangerous ultraviolet rays. However, at ground level where it is a pollutant with highly toxic effects, ozone damages human health, the environment, crops, and a wide range of natural and artificial materials. Ground-level ozone can irritate the respiratory tract, cause chest pain, persistent cough, an inability to take a deep breath, and an increased susceptibility to lung infection. Ozone can damage trees and plants and reduce visibility. It is also a product of reactions between chemicals that are produced by burning coal, gasoline, other fuels, and chemicals found in paints and hair sprays.
Oxidation occurs readily during hot weather.
Vehicles and industries are major sources of ground-level ozone. Nitrogen oxides react with volatile organic compounds to form smog. In high doses, smog can harm humans by causing breathing difficulty for asthmatics, coughs in children, and general illness of the respiratory system. Acid rain can harm vegetation and run into lakes and rivers which changes the chemistry of the water, and makes it potentially uninhabitable for all but acid-tolerant bacteria. Nitrogen oxides are produced from burning fuels, including gasoline and coal.