Take them on a tour of the city. Teach them how to use the bus system and read the bus schedules. Buy them an alarm clock and teach them how to use it. Show them how to use the library and get a library card. Help them get a driver's license and price insurance.
Role play contacts with police, bank tellers, doctors and others.
Role play several different styles of job interviews. Help them put together a resume and an application fact sheet. Make a list of important phone numbers. Teach them how to cook five good meals. Teach them how to store food.