Photovoltaic cells work effectively even in cloudy weather and unlike solar heaters, are more efficient at low temperatures. They do their job silently and there are no moving parts to wear out. It is no wonder that one marvels on how such a device would function. To understand how a solar cell works, it is necessary to go back to some basic atomic concepts. In the simplest model of the atom, electrons orbit a central nucleus, composed of protons and neutrons.
Neutrons carry no charge.
Every atom has the same number of electrons as there are protons, so, on the whole, it is electrically neutral. The electrons have discrete kinetic energy levels, which increase with the orbital radius. When atoms bond together to form a solid, the electron energy levels merge into bands. The fewer conduction electrons there are, the higher the electrical resistivity of the material. In semiconductors, the materials from which solar sells are made, the energy gap Eg is fairly small.