Molecules vibration spectra. Relaxation processes, light scattering, optic activity. Solid samples NMR spectra. The course provides properties study of some elements by means laboratory exercises, as preparations and characterisations of inorganic compounds. Inorganic polymers and polyoxoanions synthesis.
Oxidation states stabilization in block d elements.
Stoichiometry determination methods in complexes. Macrocyclic ligands complexes preparation. Approach to spectroscopic techniques. Aminic macrocyclic and macropolycyclic synthesis templated by 3d metals, such as cyclam, azacyclam, sarcophagine. Redox reactivity characterisation of metals by means spectrophotometric techniques.