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Many golfers take their grip and stance first and then lower the clubhead to the ball.
This, however, makes precise clubface aim difficult. Instead, have a well-ordered plan. With the club in your leading hand only, set the bottom edge of the clubface perpendicular to your target line. This points the clubface directly at your target. Once you've correctly aimed the clubface, carefully add your trailing hand to the grip, making sure not to disrupt the clubface aim.