List them in reverse chronological order. Also list your ten greatest work accomplishments, and how they would benefit your new employer. Prioritize them so that the benefits are easily perceived. Stress those skills and accomplishments that have made and make you a success. Exclude information irrelevant to the job opening.
Education is usually the third heading.
Education is often less valued than work experience with the exception to jobs that require a professional degree or a specific educational background to perform the job. If this is the case than education should be the second heading. Otherwise make education the third heading. List any college or trade degrees you have earned or are in the process of earning. Mention professional registrations, certificates, courses, workshops, and academic honors or awards pertinent to the job opening.