Installation should take less than one day, depending on how many windows are involved. Two very important items should be checked to make sure the installation is properly done. Make sure that both the window sashes and screen sash move smoothly and seal tightly when closed after installation. Poor installation can cause misalignment. Be sure there is a tightly caulked seal around the edge of the storm windows.
Leaks can hurt the performance of storm windows a lot.
An anodized or baked enamel finish is better. Extruded vinyl is also available, and when properly designed vinyl works fine. Quality of construction affects the strength and performance of storm windows. Corners are a good place to check construction. They should be strong and air tight.