Neoprene gloves provide the best protection. Natural rubber gloves may be used when handling organo-phosphorus or carbamate pesticides. Be sure that they are designed for use with solvents and pesticides. Put gloves on and roll up the first inch or two of the cuff. That way when you lift your hands, any liquid on the gloves won't drip down your arm.
Hats Use a chemical-resistant hat, preferably made of washable plastic.
The hat may be a hard hat, or it may be made of flexible plastic. In either case, it should have a plastic sweatband. Wash and dry entire hat after each use and before storing. Ordinary baseball caps with cloth sweatband are dangerous as they absorb the pesticide and recontaminate the forehead each time you wear them. Even small amounts of moderately or slightly toxic pesticides may cause severe skin irritation or other illness if exposure continues for several days.