Fire is an equal opportunity killer.
It treats no one special in your house due to sex, age, education, or position in the family. During a fire is not a really good time to start teaching family members about the fire safety plan. While this is primarily for determining exit paths, use this to know your assets. Each room should have two ways out, be they a door or window. Once you have your exits planned out, let everyone know where they are for each room in the house.