As far as I know, there is no way for you to get a hold of the printed manual without paying for CHP 2.0. The extra programs that come with CHP 2.0 on the CD are obtainable on the Internet. In the file dialog box select the movie. Make sure you have flattened and processed the movie appropriately. Select General from the pop-up menu.
Libraries are collections of HTML objects.
For those familiar with the Macintosh Scrapbook, it is the same idea. By putting HTML objects you use frequently in a library, you can have ready access to them while building your page. Each library is one file. You can have as many libraries as you want. To create a library, choose New from the File menu, then choose Library from the sub-menu.