You'd think so, but many people neglect to check their flue before starting to burn. Be certain to open the flue. You can make sure your chimney is drawing air by lighting the end of a piece of paper. If the smoke rises rapidly up the chimney, go ahead and light your fire. Never use lighter fluid to start a hearth fire.
Lighter fluid is for charcoal grills.
Fire Starters are for fireplaces and wood-burning stoves. It is extermely hazardous to use a combustible liquid indoors. Don't even think of doing this - it has been the cause of many fires in places where they didn't belong. Use a screen to protect adjacent floors and furniture. As a fire burns, embers will make a characteristic popping sound as moisture is released from the wood.