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AU Balling R.C. CS Arizona State Univ. DT Abstract Report LA English OS Pet. In acetonitrile hydrogenation the selectivity to primary amine decreased in the order of Ru, Ni, Rh, Pd, Pt. Ruthenium was highly selective for primary amine and platinum for tertiary amine. The metals' selectivity was related to their propensity for multiple bond formation, with the metal known for the highest propensity to form multiple bonds having the highest selectivity to primary amine.