Research different homeschooling methods. Attend a homeschooling conference. Schedule your day. Before you begin to research I would send off for as many catalogs as possible. These can be coming in the mail while you are researching books and the internet.
Catalogs are a great place to learn about what choices are available for homeschooling.
I would start with Lifetime Books and Gifts . It is invaluable because there are great descriptions and reviews of the products. Alive Check my Homeschool Links page for more. This board is great for encouragement and support on those days you feel you just can't make it. Check my Homeschool Links for other support related links.