Document ID: EPA-HQ-OPP-2004-0202-0048
Agency: epa
Document Type: Supporting & Related Material
Title: 
Posted Date: 2006-08-02T04:00Z

UNITED
STATES
ENVIRONMENTAL
PROTECTION
AGENCY
WASHINGTON
D.
C.,
20460
OFFICE
OF
PREVENTION,
PESTICIDES
AND
TOXIC
SUBSTANCES
PC
Code:
056502
DP
Barcode:
D319590
Date:
August
9,
2005
MEMORANDUM
SUBJECT:
Revised
Tier
II
Surface
Water
Exposure
Values
and
Terrestrial
Exposure
Values
for
PCNB
Based
on
Proposed
Lower
Application
Rates
(
Risk
Mitigation
Phase)

TO:
Jill
Bloom,
Chemical
Review
Manager
Special
Review
and
Reregistration
Division
cc:
Diana
Locke,
Ph.
D.,
Risk
Assessor
Sherrie
Kinard,
Chemist
RRB2/
HED
(
7509C)

FROM:
Cheryl
A.
Sutton,
Ph.
D.,
Environmental
Scientist
Thomas
M.
Steeger,
Ph.
D.,
Senior
Biologist
R.
David
Jones,
Ph.
D.,
Senior
Agronomist
Environmental
Risk
Branch
IV
Environmental
Fate
and
Effects
Division
(
7507c)

APPROVED
BY:
Elizabeth
Behl,
Branch
Chief
Environmental
Risk
Branch
IV
Environmental
Fate
and
Effects
Division
Background
The
Environmental
Fate
and
Effects
Division
(
EFED)
has
revised
the
Tier
II
surface
water
values
for
the
drinking
water
assessment
and
the
ecological
exposure
assessment
of
pentachloronitrobenzene
(
PCNB).
Also
revised
were
the
terrestrial
exposure
values
for
use
in
the
ecological
exposure
assessment.
Exposure
values
were
revised
using
the
lower
application
rates
proposed
by
the
registrants
for
cabbage,
peanuts
and
cotton.
Also
included
in
this
memo
for
use
during
Phase
Six
of
re­
registration,
i.
e.,
risk
mitigation,
are
terrestrial
and
aquatic
risk
quotients
(
RQs)
that
reflect
the
revised
estimated
environmental
concentrations
(
EECs)
associated
with
the
proposed
reductions
in
applicaton
rates.

Revised
maximum
annual
application
rates
are:
cabbage
 
22.5
lb
ai/
A/
yr
(
down
from
30
lb
ai/
A/
yr);
peanuts
 
1
lb
ai/
A/
yr
(
down
from
10
lb
ai/
A/
yr);
and
cotton
 
1.5
lb
ai/
A/
yr
(
down
from
2
lb
ai/
A/
yr).
For
each
of
these
uses,
all
modeling
(
aquatic
and
terrestrial)
is
done
assuming
that
the
maximum
application
rates
are
given
on
an
annual
basis
and
that
the
maximum
annual
rate
is
equivalent
to
the
maximum
single
application
rate
(
so
that
only
single
applications
occur
for
each
use).
It
is
important
to
note
that
if
the
revised
labels
(
not
available
to
EFED
at
the
time
of
this
review)
state
that
the
rates
are
per
season,
it
may
be
necessary
to
further
revise
the
estimated
drinking
water
concentrations
(
EDWCs)
and
EECs
reported
for
cabbage,
as
cole
crops
may
be
planted
more
than
once
per
year
in
some
regions
of
the
U.
S.
It
is
also
assumed
that
the
maximum
application
rate
given
for
each
use
(
e.
g.,
for
peanuts)
is
the
maximum
rate
across
all
labels
(
including
Special
Local
Need
labels)
for
any
type
of
soil
application
(
e.
g.,
in­
furrow,
t­
band,
etc.)
to
that
crop.

Revised
Estimated
Drinking
Water
Concentrations
Table
1
presents
the
revised
EDWCs
associated
with
the
use
of
PCNB
on
cabbage,
peanuts
and
cotton
at
the
reduced
application
rates
proposed
by
the
registrants.
Input
parameter
values
used
for
Tier
II
modeling
are
listed
at
the
end
of
the
PRZM/
EXAMS
output
file
for
each
use
(
Appendix
A).
With
the
exception
of
the
reduced
application
rates,
all
model
input
parameter
values
are
the
same
as
those
used
in
the
most
recent
estimations
of
drinking
water
exposure
concentrations
presented
in
the
July
7,
2005,
EFED
memo
"
Revised/
Refined
Tier
II
Aquatic
Exposure
Values
for
the
Drinking
Water
and
Ecological
Exposure
Assessments
of
PCNB
for
Use
During
Phase
6
 
Risk
Mitigation"
(
DP
Barcode
D318569).
The
values
to
be
used
in
the
human
health
risk
assessment
for
surface
water
sources
of
drinking
water
are
associated
with
the
highest
maximum
annual
application
rate,
i.
e.,
PCNB
use
on
cabbage
(
as
the
representative
cole
crop),
and
are
in
bold
type
in
the
table
below.

Table
1.
Revised
Tier
II
surface
water
EDWC
results
for
PCNB
plus
PCA
for
the
drinking
water
assessment.
Bolded
values
for
cabbage
are
used
in
human
health
risk
assessment.

PRZM/
EXAMS
Results
(
ppb)
Crop
(
Application
Rate;
#
Applic.
yr)
Percentage
Cropped
Area
acute
1­
in­
10
year
30­
year
average
Cabbage
(
22.5
lb
ai/
A;
1)
0.87
88.8
10.3
7.6
Peanuts
(
1
lb
ai/
A;
1)
0.87
18.3
1.7
1.2
Cotton
(
1.5
lb
ai/
A;
1)
0.87
26.9
5.7
3.8
Revised
Estimated
Environmental
Concentrations
The
revised
EECs
for
ecological
risk
assessment
associated
with
PCNB
use
on
cabbage,
peanuts
and
cotton
at
the
reduced
application
rates
proposed
by
the
registrants
are
presented
in
Table
2.
With
the
exception
of
the
reduced
application
rates,
all
PRZM/
EXAMS
input
parameter
values
are
the
same
as
those
used
in
the
most
recent
estimations
of
aquatic
exposure
concentrations
presented
in
the
July
7,
2005,
EFED
memo
"
Revised/
Refined
Tier
II
Aquatic
Exposure
Values
for
the
Drinking
Water
and
Ecological
Exposure
Assessments
of
PCNB
for
Use
During
Phase
6
 
Risk
Mitigation"
(
DP
Barcode
D318569).
The
input
parameter
values
are
listed
at
the
end
of
the
PRZM/
EXAMS
output
file
for
each
use
(
Appendix
A).

Table
2.
Revised
Tier
II
surface
water
EEC's
for
ecological
risk
assessment
based
on
PCNB1
use
on
various
crops.

Crop
(
Application
Rate;
#
Applic./
yr)
Acute
(
ppb)
1­
in­
10
Year
21­
day
Concentration
(
ppb)
1­
in­
10
Year
60­
day
Concentration
(
ppb)

Cabbage
(
22.5
lb
ai/
A;
1)
36.4
15.3
9.5
Peanuts
(
1
lb
ai/
A;
1)
8.2
3.1
1.9
Cotton
(
1.5
lb
ai/
A;
1)
12.3
6.4
4.8
1
half­
lives
are
calculated
based
on
total
residues.

Revised
Terrestrial
Exposure
Revised
terrestrial
exposure
numbers
were
generated
using
TREX
(
Version
1.22);
output
from
the
TREX
model
is
included
in
Appendix
B
and
relied
on
a
default
foliar
dissipation
half­
life
of
35
days.
Maximum
and
mean
estimated
PCNB
residues
on
avian
food
items
used
in
calculating
dietary­
based
risk
quotients
are
presented
in
Table
3.
Maximum
equivalent
doses
of
PCNB
residues
used
in
calculating
dose­
based
risk
quotients
for
mammals
are
presented
in
Table
4.

Table
3.
Maximum
and
mean
estimated
PCNB
dietary
residues
on
avian
forage
items
for
selected
uses.

Use/
App.
Method
Application
Rate
lbs.
a.
i./
A
(#
app
/
interval,
days)
Food
Items
Maximum
EEC
(
mg/
kg)
e
Mean
EEC
(
mg/
kg)
e
Short
grass
5400
1913
Tall
grass
2475
810
Broadleaf
plants/
small
insects
3038
1013
Cabbage
22.5
(
1
/
NA)

Fruits,
pods,
seeds,
and
large
insects
338
158
Short
grass
240
85
Tall
grass
110
36
Broadleaf
plants/
small
insects
135
45
Peanuts
1
(
1
/
NA)

Fruits,
pods,
seeds,
and
large
insects
15
7
Short
grass
360
128
Tall
grass
165
54
Broadleaf
plants/
small
insects
203
68
Cotton
1.5
(
1
/
NA)

Fruits,
pods,
seeds,
and
large
insects
23
11
Table
4.
Maximum
equivalent
doses
of
PCNB
in
mammalian
forage
items
for
specific
uses.

Maximum
Body
weight
(
g)
Use/
App.
Method
Application
Rate
lbs.
a.
i./
A
(#
app
/
interval,
days)
Food
Items
15
35
1000
Short
grass
5148
3558
825
Tall
grass
2360
1631
378
Broadleaf
plants/
small
insects
2896
2002
464
Cabbage
22.5
(
1
/
NA)

Fruits,
pods,
and
large
insects
322
222
52
Maximum
Body
weight
(
g)
Use/
App.
Method
Application
Rate
lbs.
a.
i./
A
(#
app
/
interval,
days)
Food
Items
15
35
1000
Seeds
(
granivores)
72
49
11
Short
grass
229
158
37
Tall
grass
105
72
17
Broadleaf
plants/
small
insects
129
89
21
Fruits,
pods,
seeds,
and
large
insects
14
9.9
2.3
Peanuts
1
(
1
/
NA)

Seeds
(
granivores)
3.2
2.2
0.51
Short
grass
343
237
55
Tall
grass
157
109
25
Broadleaf
plants/
small
insects
193
133
31
Fruits,
pods,
and
large
insects
21
15
3.4
Cotton
1.5
(
1
/
NA)

Seeds
(
granivores)
4.8
3.3
0.8
Revised
Risk
Estimation
for
Aquatic
Species
Table
5
presents
the
revised
acute
and
chronic
risk
quotients
for
freshwater
animals
exposed
to
PCNB.
Table
6
presents
the
revised
acute
risk
quotients
for
estuarine/
marine
animals
exposed
to
PCNB.
Chronic
ecological
toxicity
data
are
not
available
for
estuarine/
marine
animals
exposed
to
PCNB,
so
it
is
not
possible
to
estimate
risk
to
those
animals
at
this
time,
and
the
likelihood
of
adverse
chronic
effects
is
presumed.

Table
5.
Revised
acute
and
chronic
risk
quotients
for
freshwater
animals
exposed
to
PCNB
based
on
a
bluegill
sunfish
acute
LC50
of
100
µ
g/
L
and
chronic
NOEC
of
13
µ
g/
L
and
an
acute
Daphnia
magna
EC50
of
770
µ
g/
L
and
chronic
NOEC
of
18
µ
g/
L.

EECs
Acute
Risk
Quotients
Chronic
Risk
Quotients
Crop
(
Application
Rate;
#
Applic./
yr)
Peak
/
21­
day
Average/
60­
day
Average
(
µ
g/
L)
Freshwater
Fish
LC50
=
100
µ
g/
L
Freshwater
Invertebrate
LC50
=
770
µ
g/
L
Freshwater
Fisha
NOEC
=
13
µ
g/
L
Freshwater
Invertebrate
NOEC
=
18
µ
g/
L
Cabbage
(
22.5
lb
ai/
A;
1)
36.4
15.3
9.5
0.36a
 
 
0.05
b
 
 
 
 
0.73
 
0.85
 

Peanuts
(
1
lb
ai/
A;
1)
8.2
3.1
1.9
0.08b
 
­­
0.01
 
­­
 
 
0.15
 
0.17
 

Cotton
(
1.5
lb
ai/
A;
1)
12.3
6.4
4.8
0.12a
 
 
0.02
 
 
 
 
0.37
 
0.36
 

a
exceeds
acute
restricted
use
(
RQ
 
0.1)
and
endangered
species
level
of
concern
(
RQ
 
0.05)
b
exceeds
acute
endangered
species
level
of
concern
(
RQ
 
0.05)

Table
6.
Revised
acute
risk
quotients
for
estuarine/
marine
animals
exposed
to
PCNB
based
on
a
sheepshead
minnow
acute
LC50
of
7900
µ
g/
L
and
a
mysid
shrimp
LC50
of
12
µ
g/
L
.

EECs
Acute
Risk
Quotients
Crop
(
Application
Rate;
#
Applic./
yr)
Peak
(
µ
g/
L)
Estuarine/
marine
Fish
LC50
=
7900
µ
g/
L
Estuarine/
marine
Invertebrate
LC50
=
12
µ
g/
L
Cabbage
(
22.5
lb
ai/
A;
1)
36.4
<
0.01
3.03
a
Peanuts
(
1
lb
ai/
A;
1)
8.2
<
0.01
0.68a
Cotton
(
1.5
lb
ai/
A;
1)
12.3
<
0.01
1.03
a
a
exceeds
acute
high
risk
(
RQ
 
0.5),
restricted
use
(
RQ
 
0.1)
and
endangered
species
level
of
concern
(
RQ
 
0.05)

Revised
Risk
Estimation
for
Terrestrial
Species
As
mentioned
previously,
terrestrial
exposure
is
estimated
using
TREX.
This
model
also
calculates
risk
quotients;
output
from
the
TREX
model
is
contained
in
Appendix
B.
Acute
and
chronic
dietary­
based
risk
quotients
for
birds
based
on
maximum
PCNB
residues
are
presented
in
Table
7a.
Avian
acute
dose­
based
risk
quotients
are
also
presented
using
a
bobwhite
quail
LD50
greater
than
2250
mg/
kg
(
Table
7b).
Since
both
the
dietary­
based
and
dose­
based
risk
quotients
rely
on
avian
toxicity
endpoints
that
exceed
the
highest
concentration
tested,
all
acute
avian
RQ
values
are
less
than
the
calculated
values.

Table
7a.
Revised
avian
acute
and
chronic
dietary­
based
risk
quotients
for
selected
uses
of
nongranular
products
of
PCNB
based
on
a
bobwhite
quail
LC50
of
>
54,000
mg/
kg
diet
(
ppm)
and
NOAEC
of
600
mg/
kg
diet
(
ppm).

Use/
App.
Method
Application
Rate
lbs.
a.
i./
A
(#
app
/
interval,
days)
Food
Items
Maximum
EEC
(
mg/
kg)
Acute
RQ
(
EEC/
LC50)
Chronic
RQ
(
EEC/
NOAEC)

Short
grass
5400
<
0.10
9.0a
Tall
grass
2457
<
0.05
4.1a
Broadleaf
plants/
small
insects
3038
<
0.06
5.1a
Cabbage
22.5
(
1
/
NA)

Fruits,
pods,
seeds,
and
large
insects
338
<
0.01
0.56
Short
grass
240
<
0.01
0.40
Tall
grass
110
<
0.01
0.18
Use/
App.
Method
Application
Rate
lbs.
a.
i./
A
(#
app
/
interval,
days)
Food
Items
Maximum
EEC
(
mg/
kg)
Acute
RQ
(
EEC/
LC50)
Chronic
RQ
(
EEC/
NOAEC)

Broadleaf
plants/
small
insects
135
<
0.01
0.23
Peanuts
1
(
1
/
NA)
Fruits,
pods,
seeds,
and
large
insects
15
<
0.01
0.03
Short
grass
360
<
0.01
0.60
Tall
grass
165
<
0.01
0.28
Broadleaf
plants/
small
insects
203
<
0.01
0.34
Cotton
1.5
(
1
/
NA)

Fruits,
pods,
seeds,
and
large
insects
23
<
0.01
0.04
a
exceeds
chronic
risk
level
of
concern
(
RQ
 
1.0)
Table
7b.
Revised
acute
dose­
based
RQ
values
for
small
(
20­
g),
intermediate
(
100­
g)
and
large
(
1,000­
g)
birds
feeding
on
short
or
tall
grass,
broadleaf
plants/
small
insects,
and
fruits/
pods/
seeds/
large
insects
exposed
to
PCNB
following
single
applications
based
on
a
bobwhite
quail
LD50
>
2250
mg/
kg
bw
(
ppm).

Acute
Avian
RQ
Body
weight
(
g)
Use/
App.
Method
Application
Rate
lbs.
a.
i./
A
(#
app
/
interval,
days)
Food
Items
20
100
1000
Short
grass
<
0.31
<
0.88
<
3.9
Tall
grass
<
0.14
<
0.40
<
1.8
Broadleaf
plants/
small
insects
<
0.17
<
0.49
<
2.2
Fruits,
pods,
seeds
and
large
insects
<
0.02
<
0.05
<
0.25
Cabbage
22.5
(
1
/
NA)

Short
grass
<
0.01
<
0.04
<
0.17
Tall
grass
<
0.01
<
0.02
<
0.08
Broadleaf
plants/
small
insects
<
0.01
<
0.02
<
0.10
Fruits,
pods,
seeds
and
large
insects
<
0.01
<
0.01
<
0.01
Peanuts
1
(
1
/
NA)

Short
grass
<
0.02
<
0.06
<
0.26
Tall
grass
<
0.01
<
0.03
<
0.12
Broadleaf
plants/
small
insects
<
0.01
<
0.03
<
0.15
Fruits,
pods,
seeds
and
large
insects
<
0.01
<
0.01
<
0.02
Cotton
1.5
(
1
/
NA)

Revised
acute
(
Table
8)
and
chronic
(
Table
9)
dose­
based
risk
quotients
for
mammals
are
based
on
maximum
equivalent
doses
since
toxicity
estimates
were
based
on
oral
exposure
data.
­
8­

Table
8.
Revised
acute
dose­
based
RQ
values
for
small
(
15­
g),
intermediate
(
35­
g)
and
large
(
1,000­
g)
mammals
feeding
on
short
or
tall
grass,
broadleaf
plants/
small
insects,
fruits/
pods/
large
insects
and
seeds
exposed
to
PCNB
following
single
and
multiple
applications
based
on
a
rat
LD50
>
5,050
mg/
kg
bw
(
ppm).

Acute
Mammalian
RQ
Body
weight
(
g)
Use/
App.
Method
Application
Rate
lbs.
a.
i./
A
(#
app
/
interval,
days)
Food
Items
15
35
1000
Short
grass
0.46
a
0.40
a
0.21
a
Tall
grass
0.21
a
0.18
b
0.10
b
Broadleaf
plants/
small
insects
0.26
a
0.22
a
0.12
b
Fruits,
pods
and
large
insects
0.03
0.02
0.01
Cabbage
22.5
(
1
/
NA)

Seeds
(
granivores)
0.01
0.01
<
0.01
Short
grass
0.02
0.02
0.01
Tall
grass
0.01
0.01
<
0.01
Broadleaf
plants/
small
insects
0.01
0.01
0.01
Fruits,
pods
and
large
insects
<
0.01
<
0.01
<
0.01
Peanuts
1
(
1
/
NA)

Seeds
(
granivores)
<
0.01
<
0.01
<
0.01
Short
grass
0.03
0.03
0.01
Tall
grass
0.01
0.01
0.01
Broadleaf
plants/
small
insects
0.02
0.01
0.01
Fruits,
pods
and
large
insects
<
0.01
<
0.01
<
0.01
Cotton
1.5
(
1
/
NA)

Seeds
(
granivores)
<
0.01
<
0.01
<
0.01
a
exceeds
acute
restricted
use
(
RQ
 
0.2)
and
endangered
species
level
of
concern
(
RQ
 
0.1)
b
exceeds
acute
endangered
species
level
of
concern
(
RQ
 
0.1)
­
9­

Table
9.
Chronic
dose­
based
RQ
values
for
small
(
15­
g),
intermediate
(
35­
g)
and
large
(
1,000­
g)
mammals
feeding
on
short
or
tall
grass,
broadleaf
plants/
small
insects,
fruits/
pods/
large
insects
and
seeds
exposed
to
PCNB
following
single
and
multiple
applications
based
on
a
rat
NOEC
of
10
mg/
kg
bw
(
ppm).

Chronic
Mammalian
RQ
Body
weight
(
g)
Use/
App.
Method
Application
Rate
lbs.
a.
i./
A
(#
app
/
interval,
days)
Food
Items
15
35
1000
Short
grass
234
a
200
a
107
a
Tall
grass
107
a
92
a
49
a
Broadleaf
plants/
small
insects
132
a
113
a
60
a
Fruits,
pods
and
large
insects
15
a
13
a
6.7
a
Cabbage
22.5
(
1
/
NA)

Seeds
(
granivores)
3.3
a
2.8
a
1.5
a
Short
grass
10
a
8.9
a
4.8
a
Tall
grass
4.8
a
4.1
a
2.2
a
Broadleaf
plants/
small
insects
5.9
a
5.0
a
2.7
a
Fruits,
pods
and
large
insects
0.65
0.56
0.3
Peanuts
1
(
1
/
NA)

Seeds
(
granivores)
0.14
0.12
0.07
Short
grass
16
a
13
a
7.2
a
Tall
grass
7.2
a
6.1
a
3.3
a
Broadleaf
plants/
small
insects
8.4
a
7.5
a
4.0
a
Fruits,
pods
and
large
insects
0.98
0.8
0.5
Cotton
1.5
(
1
/
NA)

Seeds
(
granivores)
0.22
0.2
0.10
a
exceeds
chronic
risk
level
of
concern
(
RQ 
1.0)
­
10­

APPENDIX
A
PRZM/
EXAMS
MODELING
OUTPUT
FILES
I.
Estimated
Drinking
Water
Concentration
(
EDWC)
Modeling
Outputs
(
Surface
Water
Only)

1.
Cabbage
(
representative
cole
crop)
at
22.5
lb
ai/
A/
yr
stored
as
cabbage
dwa
reduced.
out
Chemical:
pcnb
PRZM
environment:
FLcabbageC.
txt
modified
Satday,
12
October
2002
at
16:
39:
00
EXAMS
environment:
ir298.
exv
modified
Thuday,
29
August
2002
at
15:
34:
12
Metfile:
w12842.
dvf
modified
Wedday,
3
July
2002
at
09:
04:
28
Water
segment
concentrations
(
ppb)

Year
Peak
96
hr
21
Day
60
Day
90
Day
Yearly
1961
57.94
49.87
26.35
11.84
8.554
2.562
1962
62.77
52.09
39.09
25.83
19.27
6.7
1963
60.99
49.79
27.3
13.92
11.75
6.973
1964
73.73
60.21
43.91
27.35
21.4
10.32
1965
66.72
53.89
28.73
18.95
15.84
7.473
1966
63.44
50.55
24.92
15.51
13.02
6.324
1967
88.83
71.31
41.08
21.23
17.29
7.239
1968
64.72
52.27
36.82
22.66
20.23
9.099
1969
74.53
63.92
37.7
24.63
20.4
11.05
1970
67.92
57.93
33.23
16.95
12.81
7.226
1971
94.2
79.05
40.1
32.81
27.11
10.83
1972
91.83
74.22
52.45
27.51
21.24
9.784
1973
64.9
51.86
34
22.35
17.18
8.082
1974
62.59
50.28
26.95
17.23
16.71
7.236
1975
63.08
51.21
30.93
25.22
20.27
8.904
1976
77.76
66.7
39.14
21.75
16.75
8.73
1977
63.82
50.89
31.05
18.28
13.81
6.206
1978
62.53
50.63
26.84
15.44
12.42
6.621
1979
125
102
51.64
32.77
26
14.93
1980
71.93
58.13
34.08
18.3
14.29
8.036
1981
77.49
62.18
43.36
27.44
20.82
9.558
1982
66.39
57.83
32.72
29.87
23.97
11.93
1983
66.43
54.41
32.86
21.16
16.89
9.935
1984
64.3
57.28
36.2
19.57
15.2
7.024
1985
116
93.89
49.25
31.77
26.49
10.62
1986
63.4
53.71
34.31
19.77
17.03
9.283
1987
65.69
53.33
33.52
20.07
16.69
9.748
1988
103
84.79
51.04
39.55
29.77
12.05
1989
64.62
52.51
40.1
25.2
19.99
9.979
1990
63.19
51.34
27
15.91
13.14
7.086
Sorted
results
Prob.
Peak
96
hr
21
Day
60
Day
90
Day
Yearly
0.032258064516129
125
102
52.45
39.55
29.77
14.93
0.0645161290322581
116
93.89
51.64
32.81
27.11
12.05
0.0967741935483871
103
84.79
51.04
32.77
26.49
11.93
0.129032258064516
94.2
79.05
49.25
31.77
26
11.05
0.161290322580645
91.83
74.22
43.91
29.87
23.97
10.83
0.193548387096774
88.83
71.31
43.36
27.51
21.4
10.62
0.225806451612903
77.76
66.7
41.08
27.44
21.24
10.32
0.258064516129032
77.49
63.92
40.1
27.35
20.82
9.979
­
11­

0.290322580645161
74.53
62.18
40.1
25.83
20.4
9.935
0.32258064516129
73.73
60.21
39.14
25.22
20.27
9.784
0.354838709677419
71.93
58.13
39.09
25.2
20.23
9.748
0.387096774193548
67.92
57.93
37.7
24.63
19.99
9.558
0.419354838709677
66.72
57.83
36.82
22.66
19.27
9.283
0.451612903225806
66.43
57.28
36.2
22.35
17.29
9.099
0.483870967741936
66.39
54.41
34.31
21.75
17.18
8.904
0.516129032258065
65.69
53.89
34.08
21.23
17.03
8.73
0.548387096774194
64.9
53.71
34
21.16
16.89
8.082
0.580645161290323
64.72
53.33
33.52
20.07
16.75
8.036
0.612903225806452
64.62
52.51
33.23
19.77
16.71
7.473
0.645161290322581
64.3
52.27
32.86
19.57
16.69
7.239
0.67741935483871
63.82
52.09
32.72
18.95
15.84
7.236
0.709677419354839
63.44
51.86
31.05
18.3
15.2
7.226
0.741935483870968
63.4
51.34
30.93
18.28
14.29
7.086
0.774193548387097
63.19
51.21
28.73
17.23
13.81
7.024
0.806451612903226
63.08
50.89
27.3
16.95
13.14
6.973
0.838709677419355
62.77
50.63
27
15.91
13.02
6.7
0.870967741935484
62.59
50.55
26.95
15.51
12.81
6.621
0.903225806451613
62.53
50.28
26.84
15.44
12.42
6.324
0.935483870967742
60.99
49.87
26.35
13.92
11.75
6.206
0.967741935483871
57.94
49.79
24.92
11.84
8.554
2.562
0.1
102.12
84.216
50.861
32.67
26.441
11.842
Average
of
yearly
averages:
8.71793333333333
Inputs
generated
by
pe4.
pl
­
8­
August­
2003
Data
used
for
this
run:
Output
File:
cabbage
dwa
reduced
Metfile:
w12842.
dvf
PRZM
scenario:
FLcabbageC.
txt
EXAMS
environment
file:
ir298.
exv
Chemical
Name:
pcnb
Description
Variable
Name
Value
Units
Comments
Molecular
weight
mwt
295.3
g/
mol
Henry's
Law
Const.
henry
4.42E­
5
atm­
m^
3/
mol
Vapor
Pressure
vapr
1.13E­
4
torr
Solubility
sol
4.4
mg/
L
Kd
Kd
mg/
L
Koc
Koc
6469.5
mg/
L
Photolysis
half­
life
kdp
1.83
days
Half­
life
Aerobic
Aquatic
Metabolism
kbacw
3110
days
Halfife
Anaerobic
Aquatic
Metabolism
kbacs
1460
days
Halfife
Aerobic
Soil
Metabolism
asm
1555
days
Halfife
Hydrolysis:
pH
5
0
days
Half­
life
Hydrolysis:
pH
7
0
days
Half­
life
Hydrolysis:
pH
9
0
days
Half­
life
Method:
CAM
4
integer
See
PRZM
manual
Incorporation
Depth:
DEPI
10
cm
Application
Rate:
TAPP
25.2
kg/
ha
Application
Efficiency:
APPEFF
0.99
fraction
Spray
Drift
DRFT
0.064
fraction
of
application
rate
applied
to
pond
Application
Date
Date
15­
08
dd/
mm
or
dd/
mmm
or
dd­
mm
or
dd­
mmm
Record
17:
FILTRA
IPSCND
3
UPTKF
­
12­

Record
18:
PLVKRT
PLDKRT
FEXTRC
0.5
Flag
for
Index
Res.
Run
IR
IR
Flag
for
runoff
calc.
RUNOFF
total
none,
monthly
or
total(
average
of
entire
run)

2.
Peanuts
at
1.0
lb
ai/
A/
yr
stored
as
peanuts
dwa
reduced.
out
Chemical:
pcnb
PRZM
environment:
NCpeanutC.
txt
modified
Satday,
12
October
2002
at
17:
12:
46
EXAMS
environment:
ir298.
exv
modified
Thuday,
29
August
2002
at
15:
34:
12
Metfile:
w13737.
dvf
modified
Wedday,
3
July
2002
at
09:
06:
30
Water
segment
concentrations
(
ppb)

Year
Peak
96
hr
21
Day
60
Day
90
Day
Yearly
1961
12.49
9.949
5.543
3.363
2.871
1.244
1962
6.896
5.606
3.244
2.418
1.999
1.356
1963
27.33
23.31
11.81
5.804
4.503
2.113
1964
22.07
17.68
10.32
5.599
4.234
1.99
1965
6.481
5.121
2.724
1.774
1.486
0.9939
1966
9.782
7.651
4.399
2.452
1.991
1.347
1967
10.95
8.886
4.983
3.926
3.127
1.688
1968
3.648
3.052
1.741
1.484
1.427
1.101
1969
13.25
11.54
6.561
3.628
3.17
1.562
1970
7.75
6.56
4.359
2.755
2.532
1.465
1971
8.787
7.142
4.267
2.989
2.469
1.363
1972
4.467
3.554
2.113
1.65
1.5
1.075
1973
8.369
6.632
3.307
2.517
2.268
1.362
1974
7.604
6.365
4.891
2.979
2.532
1.307
1975
17.31
13.42
6.582
3.791
3.358
1.962
1976
6.262
4.962
2.871
1.728
1.747
1.05
1977
6.933
5.581
3.403
2.207
1.892
1.399
1978
7.445
6.162
5.028
3.673
3.163
1.675
1979
10.32
8.585
6.004
3.819
3.15
1.974
1980
13.49
10.81
5.497
3.146
2.638
1.546
1981
8.16
6.737
3.575
2.471
2.382
1.341
1982
5.24
4.236
2.604
1.768
1.523
1.118
1983
9.103
7.207
4.168
2.503
2.08
1.284
1984
21.46
17
9.557
5.889
4.719
2.128
1985
8.124
6.469
3.815
2.424
2.169
1.47
1986
4.371
3.52
2.348
1.564
1.252
0.8034
1987
7.21
5.873
3.382
2.189
1.768
1.245
1988
3.595
2.922
1.815
1.34
1.268
0.8078
1989
5.055
4.456
3.167
2.005
1.88
1.179
1990
8.676
7.011
3.883
2.298
1.884
1.094
Sorted
results
Prob.
Peak
96
hr
21
Day
60
Day
90
Day
Yearly
0.032258064516129
27.33
23.31
11.81
5.889
4.719
2.128
0.0645161290322581
22.07
17.68
10.32
5.804
4.503
2.113
0.0967741935483871
21.46
17
9.557
5.599
4.234
1.99
0.129032258064516
17.31
13.42
6.582
3.926
3.358
1.974
0.161290322580645
13.49
11.54
6.561
3.819
3.17
1.962
0.193548387096774
13.25
10.81
6.004
3.791
3.163
1.688
0.225806451612903
12.49
9.949
5.543
3.673
3.15
1.675
0.258064516129032
10.95
8.886
5.497
3.628
3.127
1.562
­
13­

0.290322580645161
10.32
8.585
5.028
3.363
2.871
1.546
0.32258064516129
9.782
7.651
4.983
3.146
2.638
1.47
0.354838709677419
9.103
7.207
4.891
2.989
2.532
1.465
0.387096774193548
8.787
7.142
4.399
2.979
2.532
1.399
0.419354838709677
8.676
7.011
4.359
2.755
2.469
1.363
0.451612903225806
8.369
6.737
4.267
2.517
2.382
1.362
0.483870967741936
8.16
6.632
4.168
2.503
2.268
1.356
0.516129032258065
8.124
6.56
3.883
2.471
2.169
1.347
0.548387096774194
7.75
6.469
3.815
2.452
2.08
1.341
0.580645161290323
7.604
6.365
3.575
2.424
1.999
1.307
0.612903225806452
7.445
6.162
3.403
2.418
1.991
1.284
0.645161290322581
7.21
5.873
3.382
2.298
1.892
1.245
0.67741935483871
6.933
5.606
3.307
2.207
1.884
1.244
0.709677419354839
6.896
5.581
3.244
2.189
1.88
1.179
0.741935483870968
6.481
5.121
3.167
2.005
1.768
1.118
0.774193548387097
6.262
4.962
2.871
1.774
1.747
1.101
0.806451612903226
5.24
4.456
2.724
1.768
1.523
1.094
0.838709677419355
5.055
4.236
2.604
1.728
1.5
1.075
0.870967741935484
4.467
3.554
2.348
1.65
1.486
1.05
0.903225806451613
4.371
3.52
2.113
1.564
1.427
0.9939
0.935483870967742
3.648
3.052
1.815
1.484
1.268
0.8078
0.967741935483871
3.595
2.922
1.741
1.34
1.252
0.8034
0.1
21.045
16.642
9.2595
5.4317
4.1464
1.9884
Average
of
yearly
averages:
1.40143666666667
Inputs
generated
by
pe4.
pl
­
8­
August­
2003
Data
used
for
this
run:
Output
File:
peanuts
dwa
reduced
Metfile:
w13737.
dvf
PRZM
scenario:
NCpeanutC.
txt
EXAMS
environment
file:
ir298.
exv
Chemical
Name:
pcnb
Description
Variable
Name
Value
Units
Comments
Molecular
weight
mwt
295.3
g/
mol
Henry's
Law
Const.
henry
4.42E­
5
atm­
m^
3/
mol
Vapor
Pressure
vapr
1.13E­
4
torr
Solubility
sol
4.4
mg/
L
Kd
Kd
mg/
L
Koc
Koc
6469.5
mg/
L
Photolysis
half­
life
kdp
1.83
days
Half­
life
Aerobic
Aquatic
Metabolism
kbacw
3110
days
Halfife
Anaerobic
Aquatic
Metabolism
kbacs
1460
days
Halfife
Aerobic
Soil
Metabolism
asm
1555
days
Halfife
Hydrolysis:
pH
5
0
days
Half­
life
Hydrolysis:
pH
7
0
days
Half­
life
Hydrolysis:
pH
9
0
days
Half­
life
Method:
CAM
1
integer
See
PRZM
manual
Incorporation
Depth:
DEPI
0
cm
Application
Rate:
TAPP
1.12
kg/
ha
Application
Efficiency:
APPEFF
0.99
fraction
Spray
Drift
DRFT
0.064
fraction
of
application
rate
applied
to
pond
Application
Date
Date
15­
04
dd/
mm
or
dd/
mmm
or
dd­
mm
or
dd­
mmm
Record
17:
FILTRA
IPSCND
3
UPTKF
­
14­

Record
18:
PLVKRT
PLDKRT
FEXTRC
0.5
Flag
for
Index
Res.
Run
IR
IR
Flag
for
runoff
calc.
RUNOFF
total
none,
monthly
or
total(
average
of
entire
run)

3.
Cotton
at
1.5
lb
ai/
A/
yr
s
tored
as
cotton
dwa
reduced.
out
Chemical:
pcnb
PRZM
environment:
MScottonC.
txt
modified
Wedday,
22
January
2003
at
11:
52:
38
EXAMS
environment:
ir298.
exv
modified
Thuday,
29
August
2002
at
15:
34:
12
Metfile:
w03940.
dvf
modified
Wedday,
3
July
2002
at
09:
05:
46
Water
segment
concentrations
(
ppb)

Year
Peak
96
hr
21
Day
60
Day
90
Day
Yearly
1961
17.43
15.02
10.03
8.788
7.802
4.119
1962
10.81
9.077
6.376
4.6
3.961
2.867
1963
20.56
16.89
9.236
5.417
4.447
2.448
1964
24.78
20.15
10.81
6.895
6.544
4.753
1965
28.61
22.82
12.13
6.473
5.19
3.602
1966
18.87
16.49
9.947
6.941
5.722
3.463
1967
37.04
30.11
18.55
12.48
10.69
5.112
1968
14.3
12.75
9.89
7.262
6.16
3.693
1969
8.73
7.202
4.24
2.5
2.139
1.784
1970
16.79
14.31
11.22
9.026
8.179
4.47
1971
34.75
28.23
19.58
13.17
10.76
6.323
1972
12.41
10.47
7.223
4.748
4.038
2.838
1973
17.75
14.63
9.523
6.905
5.787
3.725
1974
16.25
13.17
8.09
5.738
5.186
4.024
1975
15.68
13.09
9.409
6.423
6.058
4.144
1976
26.79
22.21
15.52
11.21
10.06
5.455
1977
19.96
16.88
9.72
6.024
5.384
4.241
1978
15.36
13.65
10.76
6.799
5.729
3.51
1979
28.45
23.95
17.77
13.95
13.59
8.958
1980
30.53
25.9
17.75
14.59
12.37
7.467
1981
17.22
14.85
9.772
7.833
6.707
3.859
1982
24.1
20.18
13.29
12.09
10.23
6.289
1983
30.99
27.39
17.64
11.52
10.06
6.54
1984
11.21
9.291
5.581
4.035
3.828
3.159
1985
21.92
18.25
10.58
7.075
6.1
3.492
1986
25.99
21.37
14.32
8.773
7.484
4.113
1987
13.25
11.93
7.475
4.743
4.233
2.92
1988
12.76
10.86
7.072
6.082
5.689
3.524
1989
24
19.86
13.57
10.14
8.748
5.079
1990
14.75
12.26
7.492
5.613
4.808
3.434
Sorted
results
Prob.
Peak
96
hr
21
Day
60
Day
90
Day
Yearly
0.032258064516129
37.04
30.11
19.58
14.59
13.59
8.958
0.0645161290322581
34.75
28.23
18.55
13.95
12.37
7.467
0.0967741935483871
30.99
27.39
17.77
13.17
10.76
6.54
0.129032258064516
30.53
25.9
17.75
12.48
10.69
6.323
0.161290322580645
28.61
23.95
17.64
12.09
10.23
6.289
0.193548387096774
28.45
22.82
15.52
11.52
10.06
5.455
0.225806451612903
26.79
22.21
14.32
11.21
10.06
5.112
0.258064516129032
25.99
21.37
13.57
10.14
8.748
5.079
­
15­

0.290322580645161
24.78
20.18
13.29
9.026
8.179
4.753
0.32258064516129
24.1
20.15
12.13
8.788
7.802
4.47
0.354838709677419
24
19.86
11.22
8.773
7.484
4.241
0.387096774193548
21.92
18.25
10.81
7.833
6.707
4.144
0.419354838709677
20.56
16.89
10.76
7.262
6.544
4.119
0.451612903225806
19.96
16.88
10.58
7.075
6.16
4.113
0.483870967741936
18.87
16.49
10.03
6.941
6.1
4.024
0.516129032258065
17.75
15.02
9.947
6.905
6.058
3.859
0.548387096774194
17.43
14.85
9.89
6.895
5.787
3.725
0.580645161290323
17.22
14.63
9.772
6.799
5.729
3.693
0.612903225806452
16.79
14.31
9.72
6.473
5.722
3.602
0.645161290322581
16.25
13.65
9.523
6.423
5.689
3.524
0.67741935483871
15.68
13.17
9.409
6.082
5.384
3.51
0.709677419354839
15.36
13.09
9.236
6.024
5.19
3.492
0.741935483870968
14.75
12.75
8.09
5.738
5.186
3.463
0.774193548387097
14.3
12.26
7.492
5.613
4.808
3.434
0.806451612903226
13.25
11.93
7.475
5.417
4.447
3.159
0.838709677419355
12.76
10.86
7.223
4.748
4.233
2.92
0.870967741935484
12.41
10.47
7.072
4.743
4.038
2.867
0.903225806451613
11.21
9.291
6.376
4.6
3.961
2.838
0.935483870967742
10.81
9.077
5.581
4.03
3.828
2.448
0.967741935483871
8.73
7.202
4.24
2.5
2.139
1.784
0.1
30.944
27.241
17.768
13.101
10.753
6.5183
Average
of
yearly
averages:
4.3135
Inputs
generated
by
pe4.
pl
­
8­
August­
2003
Data
used
for
this
run:
Output
File:
cotton
dwa
reduced
Metfile:
w03940.
dvf
PRZM
scenario:
MScottonC.
txt
EXAMS
environment
file:
ir298.
exv
Chemical
Name:
pcnb
Description
Variable
Name
Value
Units
Comments
Molecular
weight
mwt
295.3
g/
mol
Henry's
Law
Const.
henry
4.42E­
5
atm­
m^
3/
mol
Vapor
Pressure
vapr
1.13E­
4
torr
Solubility
sol
4.4
mg/
L
Kd
Kd
mg/
L
Koc
Koc
6469.5
mg/
L
Photolysis
half­
life
kdp
1.83
days
Half­
life
Aerobic
Aquatic
Metabolism
kbacw
3110
days
Halfife
Anaerobic
Aquatic
Metabolism
kbacs
1460
days
Halfife
Aerobic
Soil
Metabolism
asm
1555
days
Halfife
Hydrolysis:
pH
5
0
days
Half­
life
Hydrolysis:
pH
7
0
days
Half­
life
Hydrolysis:
pH
9
0
days
Half­
life
Method:
CAM
1
integer
See
PRZM
manual
Incorporation
Depth:
DEPI
0
cm
Application
Rate:
TAPP
1.68
kg/
ha
Application
Efficiency:
APPEFF
0.99
fraction
Spray
Drift
DRFT
0.064
fraction
of
application
rate
applied
to
pond
Application
Date
Date
20­
04
dd/
mm
or
dd/
mmm
or
dd­
mm
or
dd­
mmm
Record
17:
FILTRA
IPSCND
3
UPTKF
­
16­

Record
18:
PLVKRT
PLDKRT
FEXTRC
0.5
Flag
for
Index
Res.
Run
IR
IR
Flag
for
runoff
calc.
RUNOFF
total
none,
monthly
or
total(
average
of
entire
run)

II.
Estimated
Exposure
Concentration
(
EEC)
Modeling
Outputs
(
for
Ecological
Exposure)

1.
Cabbage
(
representative
cole
crop)
at
22.5
lb
ai/
A/
yr
stored
as
cabbage
eco
reduced.
out
Chemical:
pcnb
PRZM
environment:
FLcabbageC.
txt
modified
Satday,
12
October
2002
at
16:
39:
00
EXAMS
environment:
pond298.
exv
modified
Thuday,
29
August
2002
at
16:
33:
30
Metfile:
w12842.
dvf
modified
Wedday,
3
July
2002
at
09:
04:
28
Water
segment
concentrations
(
ppb)

Year
Peak
96
hr
21
Day
60
Day
90
Day
Yearly
1961
12.7
10.68
5.333
2.577
1.949
0.6377
1962
23.56
17.52
9.545
7.143
5.621
2.177
1963
20.75
15.34
6.718
3.692
3.318
2.434
1964
23.13
17.77
11.47
8.026
6.655
3.731
1965
15.24
11.57
6.377
5.161
4.588
2.705
1966
14.4
10.74
5.111
3.994
3.609
2.211
1967
23.04
17.17
10.01
5.758
4.857
2.417
1968
18.85
14.74
9.038
6.302
6.091
3.135
1969
17.9
15.07
9.281
7.075
6.176
3.997
1970
17.09
13.64
7.95
4.651
3.763
2.758
1971
29.88
25.15
12.81
9.56
8.329
3.764
1972
28.78
21.56
14
7.977
6.514
3.605
1973
14.73
11.03
8.058
6.205
5.052
2.942
1974
22.31
16.39
7.679
5.035
4.832
2.544
1975
17.38
13.17
8.475
7.12
6.079
3.043
1976
22.22
18
9.674
6.131
5.039
3.141
1977
14.8
10.96
6.99
4.691
3.776
2.152
1978
14.12
10.66
5.424
3.758
3.28
2.225
1979
48.85
36.44
16.29
9.867
8.255
5.248
1980
18.04
13.63
8.051
4.985
4.18
3.055
1981
24.57
18.28
11.19
7.894
6.352
3.406
1982
21.1
16.43
10.51
8.87
7.383
4.305
1983
15.61
12.09
7.687
5.917
5.058
3.682
1984
16.17
13.18
8.349
5.192
4.277
2.51
1985
43.87
32.81
15.44
9.208
8.183
3.66
1986
14.76
12.01
7.997
5.313
4.921
3.429
1987
16.17
12.54
7.858
5.565
4.967
3.489
1988
37.09
28.96
15.84
11.55
9.196
4.249
1989
15.02
11.67
10.16
7.172
6.077
3.764
1990
14.53
11.09
5.647
4.176
3.659
2.561
Sorted
results
Prob.
Peak
96
hr
21
Day
60
Day
90
Day
Yearly
0.032258064516129
48.85
36.44
16.29
11.55
9.196
5.248
0.0645161290322581
43.87
32.81
15.84
9.867
8.329
4.305
0.0967741935483871
37.09
28.96
15.44
9.56
8.255
4.249
0.129032258064516
29.88
25.15
14
9.208
8.183
3.997
0.161290322580645
28.78
21.56
12.81
8.87
7.383
3.764
­
17­

0.193548387096774
24.57
18.28
11.47
8.026
6.655
3.764
0.225806451612903
23.56
18
11.19
7.977
6.514
3.731
0.258064516129032
23.13
17.77
10.51
7.894
6.352
3.682
0.290322580645161
23.04
17.52
10.16
7.172
6.176
3.66
0.32258064516129
22.31
17.17
10.01
7.143
6.091
3.605
0.354838709677419
22.22
16.43
9.674
7.12
6.079
3.489
0.387096774193548
21.1
16.39
9.545
7.075
6.077
3.429
0.419354838709677
20.75
15.34
9.281
6.302
5.621
3.406
0.451612903225806
18.85
15.07
9.038
6.205
5.058
3.141
0.483870967741936
18.04
14.74
8.475
6.131
5.052
3.135
0.516129032258065
17.9
13.64
8.349
5.917
5.039
3.055
0.548387096774194
17.38
13.63
8.058
5.758
4.967
3.043
0.580645161290323
17.09
13.18
8.051
5.565
4.921
2.942
0.612903225806452
16.17
13.17
7.997
5.313
4.857
2.758
0.645161290322581
16.17
12.54
7.95
5.192
4.832
2.705
0.67741935483871
15.61
12.09
7.858
5.161
4.588
2.561
0.709677419354839
15.24
12.01
7.687
5.035
4.277
2.544
0.741935483870968
15.02
11.67
7.679
4.985
4.18
2.51
0.774193548387097
14.8
11.57
6.99
4.691
3.776
2.434
0.806451612903226
14.76
11.09
6.718
4.651
3.763
2.417
0.838709677419355
14.73
11.03
6.377
4.176
3.659
2.225
0.870967741935484
14.53
10.96
5.647
3.994
3.609
2.211
0.903225806451613
14.4
10.74
5.424
3.758
3.318
2.177
0.935483870967742
14.12
10.68
5.333
3.692
3.28
2.152
0.967741935483871
12.7
10.66
5.111
2.577
1.949
0.6377
0.1
36.369
28.579
15.296
9.5248
8.2478
4.2238
Average
of
yearly
averages:
3.09922333333333
Inputs
generated
by
pe4.
pl
­
8­
August­
2003
Data
used
for
this
run:
Output
File:
cabbage
eco
reduced
Metfile:
w12842.
dvf
PRZM
scenario:
FLcabbageC.
txt
EXAMS
environment
file:
pond298.
exv
Chemical
Name:
pcnb
Description
Variable
Name
Value
Units
Comments
Molecular
weight
mwt
295.3
g/
mol
Henry's
Law
Const.
henry
4.42E­
5
atm­
m^
3/
mol
Vapor
Pressure
vapr
1.13E­
4
torr
Solubility
sol
4.4
mg/
L
Kd
Kd
mg/
L
Koc
Koc
6469.5
mg/
L
Photolysis
half­
life
kdp
1.83
days
Half­
life
Aerobic
Aquatic
Metabolism
kbacw
2248
days
Halfife
Anaerobic
Aquatic
Metabolism
kbacs
2004
days
Halfife
Aerobic
Soil
Metabolism
asm
1124
days
Halfife
Hydrolysis:
pH
5
0
days
Half­
life
Hydrolysis:
pH
7
0
days
Half­
life
Hydrolysis:
pH
9
0
days
Half­
life
Method:
CAM
4
integer
See
PRZM
manual
Incorporation
Depth:
DEPI
10
cm
Application
Rate:
TAPP
25.2
kg/
ha
Application
Efficiency:
APPEFF
0.99
fraction
Spray
Drift
DRFT
0.01
fraction
of
application
rate
applied
to
pond
Application
Date
Date
15­
08
dd/
mm
or
dd/
mmm
or
dd­
mm
or
dd­
mmm
­
18­

Record
17:
FILTRA
IPSCND
3
UPTKF
Record
18:
PLVKRT
PLDKRT
FEXTRC
0.5
Flag
for
Index
Res.
Run
IR
Pond
Flag
for
runoff
calc.
RUNOFF
none
none,
monthly
or
total(
average
of
entire
run)

2.
Peanuts
at
1.0
lb
ai/
A/
yr
stored
as
peanuts
eco
reduced.
out
Chemical:
pcnb
PRZM
environment:
NCpeanutC.
txt
modified
Satday,
12
October
2002
at
17:
12:
46
EXAMS
environment:
pond298.
exv
modified
Thuday,
29
August
2002
at
16:
33:
30
Metfile:
w13737.
dvf
modified
Wedday,
3
July
2002
at
09:
06:
30
Water
segment
concentrations
(
ppb)

Year
Peak
96
hr
21
Day
60
Day
90
Day
Yearly
1961
5.202
3.839
1.932
1.216
1.073
0.4878
1962
2.841
2.168
1.192
0.9264
0.7963
0.5642
1963
10.88
8.926
4.017
2.115
1.71
0.8641
1964
8.604
6.613
3.494
2.006
1.6
0.8169
1965
2.704
2.007
1.032
0.7225
0.627
0.4644
1966
3.955
2.877
1.537
0.9287
0.7885
0.5467
1967
4.224
3.212
1.719
1.381
1.151
0.6868
1968
1.591
1.242
0.7109
0.6207
0.5697
0.4861
1969
5.232
4.305
2.226
1.316
1.145
0.6292
1970
3.274
2.599
1.612
1.076
0.9819
0.6351
1971
3.466
2.645
1.496
1.076
0.9237
0.5579
1972
1.811
1.36
0.7597
0.6116
0.5753
0.457
1973
3.363
2.498
1.168
0.9628
0.8608
0.5628
1974
2.954
2.269
1.722
1.097
0.9421
0.5364
1975
6.689
4.761
2.296
1.411
1.249
0.8046
1976
2.672
1.985
1.06
0.6928
0.6932
0.463
1977
2.741
2.079
1.233
0.8043
0.7329
0.5629
1978
2.899
2.241
1.816
1.386
1.21
0.7074
1979
4.084
3.287
2.181
1.406
1.198
0.8223
1980
5.645
4.22
1.991
1.179
1.072
0.6713
1981
3.283
2.529
1.247
0.9229
0.8893
0.5555
1982
2.053
1.565
0.9309
0.6691
0.6045
0.4719
1983
3.53
2.632
1.388
0.9109
0.7929
0.5321
1984
8.383
6.203
3.237
2.14
1.784
0.898
1985
3.251
2.429
1.39
0.947
0.8519
0.6125
1986
1.716
1.316
0.7701
0.5739
0.4874
0.36
1987
2.732
2.125
1.092
0.7725
0.6561
0.4902
1988
1.476
1.131
0.6694
0.508
0.4612
0.3391
1989
2.07
1.713
1.117
0.7438
0.7039
0.4651
1990
3.375
2.542
1.345
0.8371
0.7186
0.4486
Sorted
results
Prob.
Peak
96
hr
21
Day
60
Day
90
Day
Yearly
0.032258064516129
10.88
8.926
4.017
2.14
1.784
0.898
0.0645161290322581
8.604
6.613
3.494
2.115
1.71
0.8641
0.0967741935483871
8.383
6.203
3.237
2.006
1.6
0.8223
0.129032258064516
6.689
4.761
2.296
1.411
1.249
0.8169
0.161290322580645
5.645
4.305
2.226
1.406
1.21
0.8046
­
19­

0.193548387096774
5.232
4.22
2.181
1.386
1.198
0.7074
0.225806451612903
5.202
3.839
1.991
1.381
1.151
0.6868
0.258064516129032
4.224
3.287
1.932
1.316
1.145
0.6713
0.290322580645161
4.084
3.212
1.816
1.216
1.073
0.6351
0.32258064516129
3.955
2.877
1.722
1.179
1.072
0.6292
0.354838709677419
3.53
2.645
1.719
1.097
0.9819
0.6125
0.387096774193548
3.466
2.632
1.612
1.076
0.9421
0.5642
0.419354838709677
3.375
2.599
1.537
1.076
0.9237
0.5629
0.451612903225806
3.363
2.542
1.496
0.9628
0.8893
0.5628
0.483870967741936
3.283
2.529
1.39
0.947
0.8608
0.5579
0.516129032258065
3.274
2.498
1.388
0.9287
0.8519
0.5555
0.548387096774194
3.251
2.429
1.345
0.9264
0.7963
0.5467
0.580645161290323
2.954
2.269
1.247
0.9229
0.7929
0.5364
0.612903225806452
2.899
2.241
1.233
0.9109
0.7885
0.5321
0.645161290322581
2.841
2.168
1.192
0.8371
0.7329
0.4902
0.67741935483871
2.741
2.125
1.168
0.8043
0.7186
0.4878
0.709677419354839
2.732
2.079
1.117
0.7725
0.7039
0.4861
0.741935483870968
2.704
2.007
1.092
0.7438
0.6932
0.4719
0.774193548387097
2.672
1.985
1.06
0.7225
0.6561
0.4651
0.806451612903226
2.07
1.713
1.032
0.6928
0.627
0.4644
0.838709677419355
2.053
1.565
0.9309
0.6691
0.6045
0.463
0.870967741935484
1.811
1.36
0.7701
0.6207
0.5753
0.457
0.903225806451613
1.716
1.316
0.7597
0.6116
0.5697
0.4486
0.935483870967742
1.591
1.242
0.7109
0.5739
0.4874
0.36
0.967741935483871
1.476
1.131
0.6694
0.508
0.4612
0.3391
0.1
8.2136
6.0588
3.1429
1.9465
1.5649
0.82176
Average
of
yearly
averages:
0.58333
Inputs
generated
by
pe4.
pl
­
8­
August­
2003
Data
used
for
this
run:
Output
File:
peanuts
eco
reduced
Metfile:
w13737.
dvf
PRZM
scenario:
NCpeanutC.
txt
EXAMS
environment
file:
pond298.
exv
Chemical
Name:
pcnb
Description
Variable
Name
Value
Units
Comments
Molecular
weight
mwt
295.3
g/
mol
Henry's
Law
Const.
henry
4.42E­
5
atm­
m^
3/
mol
Vapor
Pressure
vapr
1.13E­
4
torr
Solubility
sol
4.4
mg/
L
Kd
Kd
mg/
L
Koc
Koc
6469.5
mg/
L
Photolysis
half­
life
kdp
1.83
days
Half­
life
Aerobic
Aquatic
Metabolism
kbacw
2248
days
Halfife
Anaerobic
Aquatic
Metabolism
kbacs
2004
days
Halfife
Aerobic
Soil
Metabolism
asm
1124
days
Halfife
Hydrolysis:
pH
5
0
days
Half­
life
Hydrolysis:
pH
7
0
days
Half­
life
Hydrolysis:
pH
9
0
days
Half­
life
Method:
CAM
1
integer
See
PRZM
manual
Incorporation
Depth:
DEPI
0
cm
Application
Rate:
TAPP
1.12
kg/
ha
Application
Efficiency:
APPEFF
0.99
fraction
Spray
Drift
DRFT
0.01
fraction
of
application
rate
applied
to
pond
Application
Date
Date
15­
04
dd/
mm
or
dd/
mmm
or
dd­
mm
or
dd­
mmm
­
20­

Record
17:
FILTRA
IPSCND
3
UPTKF
Record
18:
PLVKRT
PLDKRT
FEXTRC
0.5
Flag
for
Index
Res.
Run
IR
Pond
Flag
for
runoff
calc.
RUNOFF
none
none,
monthly
or
total(
average
of
entire
run)

3.
Cotton
at
1.5
lb
ai/
A/
yr
stored
as
cotton
eco
reduced.
out
Chemical:
pcnb
PRZM
environment:
MScottonC.
txt
modified
Wedday,
22
January
2003
at
11:
52:
38
EXAMS
environment:
pond298.
exv
modified
Thuday,
29
August
2002
at
16:
33:
30
Metfile:
w03940.
dvf
modified
Wedday,
3
July
2002
at
09:
05:
46
Water
segment
concentrations
(
ppb)

Year
Peak
96
hr
21
Day
60
Day
90
Day
Yearly
1961
6.901
5.554
3.394
3.005
2.731
1.503
1962
4.162
3.374
2.238
1.791
1.617
1.284
1963
8.359
6.379
3.175
1.969
1.694
1.028
1964
9.719
7.439
3.792
2.663
2.546
1.861
1965
11.21
8.335
4.153
2.446
2.056
1.559
1966
7.798
6.41
3.613
2.542
2.207
1.494
1967
14.67
11.14
6.395
4.502
3.971
2.103
1968
5.617
4.816
3.65
2.779
2.412
1.641
1969
3.635
2.812
1.498
0.9791
0.8796
0.788
1970
6.483
5.212
3.902
3.191
2.928
1.715
1971
13.51
10.31
6.774
4.826
4.114
2.617
1972
5.189
4.153
2.73
1.892
1.679
1.309
1973
7.076
5.478
3.383
2.431
2.141
1.516
1974
5.997
4.648
2.872
2.218
2.056
1.686
1975
6.192
4.922
3.348
2.407
2.315
1.696
1976
10.36
8.088
5.449
4.094
3.755
2.243
1977
7.444
6.085
3.406
2.354
2.186
1.833
1978
6.045
5.2
3.82
2.576
2.248
1.517
1979
11.6
9.124
6.341
5.078
4.913
3.454
1980
11.74
9.495
6.229
5.365
4.762
3.232
1981
7.163
5.912
3.71
3.027
2.665
1.756
1982
9.742
7.561
4.831
4.255
3.704
2.463
1983
12.36
10.38
6.614
4.355
3.955
2.835
1984
4.761
3.766
2.237
1.73
1.633
1.445
1985
8.592
6.681
3.599
2.509
2.298
1.431
1986
9.885
7.647
4.935
3.209
2.832
1.721
1987
5.496
4.761
2.768
1.896
1.685
1.283
1988
5.125
4.148
2.613
2.316
2.154
1.411
1989
9.996
7.748
4.938
3.781
3.369
2.132
1990
6.163
4.855
2.874
2.186
1.952
1.516
Sorted
results
Prob.
Peak
96
hr
21
Day
60
Day
90
Day
Yearly
0.032258064516129
14.67
11.14
6.774
5.365
4.913
3.454
0.0645161290322581
13.51
10.38
6.614
5.078
4.762
3.232
0.0967741935483871
12.36
10.31
6.395
4.826
4.114
2.835
0.129032258064516
11.74
9.495
6.341
4.502
3.971
2.617
0.161290322580645
11.6
9.124
6.229
4.355
3.955
2.463
­
21­

0.193548387096774
11.21
8.335
5.449
4.255
3.755
2.243
0.225806451612903
10.36
8.088
4.938
4.094
3.704
2.132
0.258064516129032
9.996
7.748
4.935
3.781
3.369
2.103
0.290322580645161
9.885
7.647
4.831
3.209
2.928
1.861
0.32258064516129
9.742
7.561
4.153
3.191
2.832
1.833
0.354838709677419
9.719
7.439
3.902
3.027
2.731
1.756
0.387096774193548
8.592
6.681
3.82
3.005
2.665
1.721
0.419354838709677
8.359
6.41
3.792
2.779
2.546
1.715
0.451612903225806
7.798
6.379
3.71
2.663
2.412
1.696
0.483870967741936
7.444
6.085
3.65
2.576
2.315
1.686
0.516129032258065
7.163
5.912
3.613
2.542
2.298
1.641
0.548387096774194
7.076
5.554
3.599
2.509
2.248
1.559
0.580645161290323
6.901
5.478
3.406
2.446
2.207
1.517
0.612903225806452
6.483
5.212
3.394
2.431
2.186
1.516
0.645161290322581
6.192
5.2
3.383
2.407
2.154
1.516
0.67741935483871
6.163
4.922
3.348
2.354
2.141
1.503
0.709677419354839
6.045
4.855
3.175
2.316
2.056
1.494
0.741935483870968
5.997
4.816
2.874
2.218
2.056
1.445
0.774193548387097
5.617
4.761
2.872
2.186
1.952
1.431
0.806451612903226
5.496
4.648
2.768
1.969
1.694
1.411
0.838709677419355
5.189
4.153
2.73
1.896
1.685
1.309
0.870967741935484
5.125
4.148
2.613
1.892
1.679
1.284
0.903225806451613
4.761
3.766
2.238
1.791
1.633
1.283
0.935483870967742
4.162
3.374
2.237
1.73
1.617
1.028
0.967741935483871
3.635
2.812
1.498
0.979
0.8796
0.788
0.1
12.298
10.2285
6.3896
4.7936
4.0997
2.8132
Average
of
yearly
averages:
1.8024
Inputs
generated
by
pe4.
pl
­
8­
August­
2003
Data
used
for
this
run:
Output
File:
cotton
eco
reduced
Metfile:
w03940.
dvf
PRZM
scenario:
MScottonC.
txt
EXAMS
environment
file:
pond298.
exv
Chemical
Name:
pcnb
Description
Variable
Name
Value
Units
Comments
Molecular
weight
mwt
295.3
g/
mol
Henry's
Law
Const.
henry
4.42E­
5
atm­
m^
3/
mol
Vapor
Pressure
vapr
1.13E­
4
torr
Solubility
sol
4.4
mg/
L
Kd
Kd
mg/
L
Koc
Koc
6469.5
mg/
L
Photolysis
half­
life
kdp
1.83
days
Half­
life
Aerobic
Aquatic
Metabolism
kbacw
2248
days
Halfife
Anaerobic
Aquatic
Metabolism
kbacs
2004
days
Halfife
Aerobic
Soil
Metabolism
asm
1124
days
Halfife
Hydrolysis:
pH
5
0
days
Half­
life
Hydrolysis:
pH
7
0
days
Half­
life
Hydrolysis:
pH
9
0
days
Half­
life
Method:
CAM
1
integer
See
PRZM
manual
Incorporation
Depth:
DEPI
0
cm
Application
Rate:
TAPP
1.68
kg/
ha
Application
Efficiency:
APPEFF
0.99
fraction
Spray
Drift
DRFT
0.01
fraction
of
application
rate
applied
to
pond
Application
Date
Date
20­
04
dd/
mm
or
dd/
mmm
or
dd­
mm
or
dd­
mmm
­
22­

Record
17:
FILTRA
IPSCND
1
UPTKF
Record
18:
PLVKRT
PLDKRT
FEXTRC
0.5
Flag
for
Index
Res.
Run
IR
Pond
Flag
for
runoff
calc.
RUNOFF
none
none,
monthly
or
total(
average
of
entire
run)
­
23­

APPENDIX
B
TREX
(
Version
1.22)
OUTPUT.
­
24­
­
25­
­
26­
­
27­
­
28­
­
29­