Document ID: EPA-HQ-OW-2003-0003-0009
Agency: epa
Document Type: Supporting & Related Material
Title: 
Posted Date: 2003-03-12T05:00Z

Measured
ConcentrationAAMA
Metals
Data
APPENDIX
B
­
1
­
2
Page
1
of
13
Measurement
Results
vs
Spike
Concentrations
(
Matrix
A,
Method
EPA
200.7
ICP/
AES)

500
600
Lab:
2Lab:
2
ALUMINUM,
UG/
LALUMINUM,
L
400
400
300
400
300
200
200
200
100
100
0
Lab:
1Lab:
1
ALUMINUM,
UG/
LALUMINUM,
L
00
Lab:
3Lab:
3
ALUMINUM,
UG/
LALUMINUM,
L
0
100
200
300
400
500
0
100
200
300
400
500
0
100
200
300
400
500
600
1000
500
500
800
400
Lab:
5Lab:
5
ALUMINUM,
UG/
LALUMINUM,
L
400
600
300
300
400
200
200
Lab:
4Lab:
4
ALUMINUM,
UG/
LALUMINUM,
L
200
100
0
100
Lab:
6Lab:
6
ALUMINUM,
UG/
LALUMINUM,
L
0
100
200
300
400
500
0
100
200
300
400
500
0
100
200
300
400
500
500
Lab:
7Lab:
7
ALUMINUM,
UG/
LALUMINUM,
L
500
400
400
Lab:
8Lab:
8
ALUMINUM,
UG/
LALUMINUM,
L
600
300
300
200
400
200
100
100
200
0
0
­
100
0
Lab:
9Lab:
9
ALUMINUM,
UG/
LALUMINUM,
L
0
100
200
300
400
500
0
100
200
300
400
500
0
100
200
300
400
500
Spike
Concentration
Measured
ConcentrationAAMA
Metals
Data
Page
2
of
13
Measurement
Results
vs
Spike
Concentrations
(
Matrix
A,
Method
EPA
200.7
ICP/
AES)

600
600
Lab:
2Lab:
2
ARSENIC,
UG/
LARSENIC,
L
500
500
400
400
Lab:
1Lab:
1
ARSENIC,
UG/
LARSENIC,
L
400
300
300
200
200
200
100
100
0
00
Lab:
3Lab:
3
ARSENIC,
UG/
LARSENIC,
L
0
100
200
300
400
500
600
0
100
200
300
400
500
600
0
100
200
300
400
500
600
Lab:
4Lab:
4
ARSENIC,
UG/
LARSENIC,
L
600
600
500
500
400
400
400
Lab:
5Lab:
5
ARSENIC,
UG/
LARSENIC,
L
Lab:
6Lab:
6
ARSENIC,
UG/
LARSENIC,
L
300
300
200
200
200
100
100
0
0
0
0
100
200
300
400
500
600
0
100
200
300
400
500
600
0
100
200
300
400
500
600
600
600
Lab:
7Lab:
7
ARSENIC,
UG/
LARSENIC,
L
Lab:
8Lab:
8
ARSENIC,
UG/
LARSENIC,
L
600
500
400
400
400
300
200
200
200
100
0
00
Lab:
9Lab:
9
ARSENIC,
UG/
LARSENIC,
L
0
100
200
300
400
500
600
0
100
200
300
400
500
600
0
100
200
300
400
500
600
Wed
Mar
20
13:
31:
40
2002
Spike
Concentration
c:/
pw/
ostmdl/
req005/
r005sd1.
s
Measured
ConcentrationAAMA
Metals
Data
Page
3
of
13
Measurement
Results
vs
Spike
Concentrations
(
Matrix
A,
Method
EPA
200.7
ICP/
AES)

100
100
80
80
Lab:
1Lab:
1
CADMIUM,
UG/

LCADMIUM,
L
80
60
60
60
40
40
40
2020
Lab:
2Lab:
2
CADMIUM,
UG/

LCADMIUM,
L
20
00
0
0
20
40
60
80100
0
20
40
60
80100
0
20
40
60
80100
Lab:
3Lab:
3
CADMIUM,
UG/

LCADMIUM,
L
Lab:
4Lab:
4
CADMIUM,
UG/

LCADMIUM,
L
100
Lab:
5Lab:
5
CADMIUM,
UG/

LCADMIUM,
L
100
100
Lab:
6Lab:
6
CADMIUM,
UG/

LCADMIUM,
L
0
20
40
60
80100
0
20
40
60
80100
0
20
40
60
80100
80
80
80
60
60
60
40
40
40
20
20
20
0
00
100
100
80
80
80
60
60
60
40
40
40
20
20
20
Lab:
9Lab:
9
CADMIUM,
UG/

LCADMIUM,
L
0
Lab:
7Lab:
7
CADMIUM,
UG/

LCADMIUM,
L
0
Lab:
8Lab:
8
CADMIUM,
UG/

LCADMIUM,
L
0
0
20
40
60
80100
0
20
40
60
80100
0
20
40
60
80100
Wed
Mar
20
13:
31:
42
2002
Spike
Concentration
c:/
pw/
ostmdl/
req005/
r005sd1.
s
Measured
ConcentrationAAMA
Metals
Data
Page
4
of
13
Measurement
Results
vs
Spike
Concentrations
(
Matrix
A,
Method
EPA
200.7
ICP/
AES)

250
250
200
200
200
150
150
150
100
100
100
50
50
50
Lab:
3Lab:
3
CHROMIUM,
UG/

LCHROMIUM,
L
0
50
100
150
200
250
0
50
100
150
200
250
0
50
100
150
200
250
0
Lab:
1Lab:
1
CHROMIUM,
UG/

LCHROMIUM,
L
0
Lab:
2Lab:
2
CHROMIUM,
UG/

LCHROMIUM,
L
0
250
250
250
200
200
200
150
150
150
100
100
100
50
50
50
0
0
0
0
50
100
150
200
250
0
50
100
150
200
250
0
50
100
150
200
250
Lab:
5Lab:
5
CHROMIUM,
UG/

LCHROMIUM,
L
Lab:
6Lab:
6
CHROMIUM,
UG/

LCHROMIUM,
L
Lab:
4Lab:
4
CHROMIUM,
UG/

LCHROMIUM,
L
250
250
250
200
200
200
150
150
150
100
100
100
50
50
50
Lab:
9Lab:
9
CHROMIUM,
UG/

LCHROMIUM,
L
0
Lab:
7Lab:
7
CHROMIUM,
UG/

LCHROMIUM,
L
0
Lab:
8Lab:
8
CHROMIUM,
UG/

LCHROMIUM,
L
0
0
50
100
150
200
250
0
50
100
150
200
250
0
50
100
150
200
250
Wed
Mar
20
13:
31:
44
2002
Spike
Concentration
c:/
pw/
ostmdl/
req005/
r005sd1.
s
Measured
ConcentrationAAMA
Metals
Data
Page
5
of
13
Measurement
Results
vs
Spike
Concentrations
(
Matrix
A,
Method
EPA
200.7
ICP/
AES)

200
Lab:
1Lab:
1
COPPER,
UG/

LCOPPER,
L
200
150
150
150
100
100
100
50
50
50
00
Lab:
2Lab:
2
COPPER,
UG/

LCOPPER,
L
0
Lab:
3Lab:
3
COPPER,
UG/

LCOPPER,
L
0
50
100
150
200
0
50
100
150
200
0
50
100
150
200
300
Lab:
4Lab:
4
COPPER,
UG/

LCOPPER,
L
200
Lab:
5Lab:
5
COPPER,
UG/

LCOPPER,
L
200
250
150
150
200
150
100
100
100
50
50
50
0
00
Lab:
6Lab:
6
COPPER,
UG/

LCOPPER,
L
0
50
100
150
200
0
50
100
150
200
0
50
100
150
200
200
200
150
150
150
100
100
Lab:
7Lab:
7
COPPER,
UG/

LCOPPER,
L
Lab:
8Lab:
8
COPPER,
UG/

LCOPPER,
L
100
5050
50
000
Lab:
9Lab:
9
COPPER,
UG/

LCOPPER,
L
0
50
100
150
200
0
50
100
150
200
0
50
100
150
200
Wed
Mar
20
13:
31:
46
2002
Spike
Concentration
c:/
pw/
ostmdl/
req005/
r005sd1.
s
Measured
ConcentrationAAMA
Metals
Data
Page
6
of
13
Measurement
Results
vs
Spike
Concentrations
(
Matrix
A,
Method
EPA
200.7
ICP/
AES)

600
500
500
Lab:
2Lab:
2
LEAD,
UG/

LLEAD,
L
400
400
400
300
300
300
200
200
200
100
Lab:
1Lab:
1
LEAD,
UG/

LLEAD,
L
100
100
000
Lab:
3Lab:
3
LEAD,
UG/

LLEAD,
L
0
100
200
300
400
500
0
100
200
300
400
500
0
100
200
300
400
500
600
Lab:
4Lab:
4
LEAD,
UG/

LLEAD,
L
500
Lab:
5Lab:
5
LEAD,
UG/

LLEAD,
L
500
500
400
400
400
300
300
300
200
200
200
100
100
100
0
0
0
0
100
200
300
400
500
0
100
200
300
400
500
0
100
200
300
400
500
Lab:
6Lab:
6
LEAD,
UG/

LLEAD,
L
500
500
500
400
400
400
300
300
300
200
200
200
100
100
100
0
0
0
0
100
200
300
400
500
0
100
200
300
400
500
0
100
200
300
400
500
Lab:
8Lab:
8
LEAD,
UG/

LLEAD,
L
Lab:
9Lab:
9
LEAD,
UG/

LLEAD,
L
Lab:
7Lab:
7
LEAD,
UG/

LLEAD,
L
Wed
Mar
20
13:
31:
48
2002
Spike
Concentration
c:/
pw/
ostmdl/
req005/
r005sd1.
s
Measured
ConcentrationAAMA
Metals
Data
Page
7
of
13
Measurement
Results
vs
Spike
Concentrations
(
Matrix
A,
Method
EPA
200.7
ICP/
AES)

50
40
Lab:
2Lab:
2
MANGANESE,
UG/
LMANGANESE,
L
40
40
30
30
20
20
Lab:
1Lab:
1
MANGANESE,
UG/
LMANGANESE,
L
20
10
010
00
0
1020304050
0
1020304050
0
1020304050
Lab:
3Lab:
3
MANGANESE,
UG/
LMANGANESE,
L
250
50
50
200
40
40
150
30
30
100
20
20
50
10
10
0
0
0
0
10
20
30
40
50
0
10
20
30
40
50
0
10
20
30
40
50
Lab:
5Lab:
5
MANGANESE,
UG/
LMANGANESE,
L
Lab:
6Lab:
6
MANGANESE,
UG/
LMANGANESE,
L
Lab:
4Lab:
4
MANGANESE,
UG/
LMANGANESE,
L
50
Lab:
7Lab:
7
MANGANESE,
UG/
LMANGANESE,
L
50
Lab:
8Lab:
8
MANGANESE,
UG/
LMANGANESE,
L
50
40
40
40
30
30
30
20
20
20
10
10
10
0
0
0
0
10
20
30
40
50
0
10
20
30
40
50
0
10
20
30
40
50
Lab:
9Lab:
9
MANGANESE,
UG/
LMANGANESE,
L
Wed
Mar
20
13:
31:
50
2002
Spike
Concentration
c:/
pw/
ostmdl/
req005/
r005sd1.
s
Measured
ConcentrationAAMA
Metals
Data
Page
8
of
13
Measurement
Results
vs
Spike
Concentrations
(
Matrix
A,
Method
EPA
200.7
ICP/
AES)

2.0
2.0
Lab:
2Lab:
2
MERCURY,
UG/

LMERCURY,
L
2.0
1.5
1.5
1.5
1.0
1.0
1.0
0.5
Lab:
1Lab:
1
MERCURY,
UG/

LMERCURY,
L
0.5
0.5
0.0
0.0
0.0
Lab:
3Lab:
3
MERCURY,
UG/

LMERCURY,
L
0.0
0.5
1.0
1.5
2.0
0.0
0.5
1.0
1.5
2.0
0.0
0.5
1.0
1.5
2.0
Lab:
4Lab:
4
MERCURY,
UG/

LMERCURY,
L
2.0
2.0
8
1.5
1.5
6
Lab:
5Lab:
5
MERCURY,
UG/

LMERCURY,
L
Lab:
6Lab:
6
MERCURY,
UG/

LMERCURY,
L
1.0
1.0
4
0.5
0.5
2
0.0
0.0
0
0.0
0.5
1.0
1.5
2.0
0.0
0.5
1.0
1.5
2.0
0.0
0.5
1.0
1.5
2.0
2.0
Lab:
7Lab:
7
MERCURY,
UG/

LMERCURY,
L
2.0
2.0
1.5
1.5
1.5
1.0
1.0
1.0
0.5
0.5
0.5
0.0
0.0
Lab:
8Lab:
8
MERCURY,
UG/

LMERCURY,
L
0.0
Lab:
9Lab:
9
MERCURY,
UG/

LMERCURY,
L
0.0
0.5
1.0
1.5
2.0
0.0
0.5
1.0
1.5
2.0
0.0
0.5
1.0
1.5
2.0
Wed
Mar
20
13:
31:
52
2002
Spike
Concentration
c:/
pw/
ostmdl/
req005/
r005sd1.
s
Measured
ConcentrationAAMA
Metals
Data
Page
9
of
13
Measurement
Results
vs
Spike
Concentrations
(
Matrix
A,
Method
EPA
200.7
ICP/
AES)
250
250
250
200
200
200
150
150
150
100
100
100
50
50
0
50
Lab:
3Lab:
3
MOLYBDENUM,
UG/

LMOLYBDENUM,
L
0
Lab:
1Lab:
1
MOLYBDENUM,
UG/

LMOLYBDENUM,
L
­
50
Lab:
2Lab:
2
MOLYBDENUM,
UG/

LMOLYBDENUM,
L
0
0
50
100
150
200
250
0
50
100
150
200
250
0
50
100
150
200
250
Lab:
4Lab:
4
MOLYBDENUM,
UG/

LMOLYBDENUM,
L
250
250
250
200
200
200
150
150
150
100
100
100
50
50
50
0
0
0
0
50
100
150
200
250
0
50
100
150
200
250
0
50
100
150
200
250
Lab:
6Lab:
6
MOLYBDENUM,
UG/

LMOLYBDENUM,
L
Lab:
5Lab:
5
MOLYBDENUM,
UG/

LMOLYBDENUM,
L
250
250
200
200
200
150
150
150
100
100
100
50
50
50
0
0
0
0
50
100
150
200
250
0
50
100
150
200
250
0
50
100
150
200
250
Lab:
8Lab:
8
MOLYBDENUM,
UG/

LMOLYBDENUM,
L
Lab:
9Lab:
9
MOLYBDENUM,
UG/

LMOLYBDENUM,
L
Lab:
7Lab:
7
MOLYBDENUM,
UG/

LMOLYBDENUM,
L
Wed
Mar
20
13:
31:
54
2002
Spike
Concentration
c:/
pw/
ostmdl/
req005/
r005sd1.
s
Measured
ConcentrationAAMA
Metals
Data
Page
10
of
13
Measurement
Results
vs
Spike
Concentrations
(
Matrix
A,
Method
EPA
200.7
ICP/
AES)

200
Lab:
1Lab:
1
NICKEL,
UG/
LNICKEL,
L
200
150
150
150
100
Lab:
2Lab:
2
NICKEL,
UG/
LNICKEL,
L
100
100
50
50
50
0
00
Lab:
3Lab:
3
NICKEL,
UG/
LNICKEL,
L
0
50
100
150
200
0
50
100
150
200
0
50
100
150
200
200
200
800
150
150
600
100
100
400
50
Lab:
4Lab:
4
NICKEL,
UG/
LNICKEL,
L
50
200
0
0
Lab:
5Lab:
5
NICKEL,
UG/
LNICKEL,
L
0
Lab:
6Lab:
6
NICKEL,
UG/
LNICKEL,
L
0
50
100
150
200
0
50
100
150
200
0
50
100
150
200
200
200
150
150
Lab:
8Lab:
8
NICKEL,
UG/
LNICKEL,
L
150
100
100
100
50
Lab:
7Lab:
7
NICKEL,
UG/
LNICKEL,
L
50
50
000
Lab:
9Lab:
9
NICKEL,
UG/
LNICKEL,
L
0
50
100
150
200
0
50
100
150
200
0
50
100
150
200
Wed
Mar
20
13:
31:
56
2002
Spike
Concentration
c:/
pw/
ostmdl/
req005/
r005sd1.
s
Measured
ConcentrationAAMA
Metals
Data
Page
11
of
13
Measurement
Results
vs
Spike
Concentrations
(
Matrix
A,
Method
EPA
200.7
ICP/
AES)
Lab:
3Lab:
3
SELENIUM,
UG/

LSELENIUM,
L
1000
1000
800
800
800
600
600
600
400
400
400
200
200
Lab:
1Lab:
1
SELENIUM,
UG/

LSELENIUM,
L
Lab:
2Lab:
2
SELENIUM,
UG/

LSELENIUM,
L
200
0
00
0
200
400
600
800
1000
0
200
400
600
800
1000
0
200
400
600
800
1000
1000
800
Lab:
4Lab:
4
SELENIUM,
UG/

LSELENIUM,
L
800
800
600
600
600
400
400
400
200
200
Lab:
5Lab:
5
SELENIUM,
UG/

LSELENIUM,
L
200
0
00
Lab:
6Lab:
6
SELENIUM,
UG/

LSELENIUM,
L
0
200
400
600
800
1000
0
200
400
600
800
1000
0
200
400
600
800
1000
800
Lab:
7Lab:
7
SELENIUM,
UG/

LSELENIUM,
L
800
Lab:
8Lab:
8
SELENIUM,
UG/

LSELENIUM,
L
1000
800
600
600
600
400
400
400
200
200
200
00
0
0
200
400
600
800
1000
0
200
400
600
800
1000
0
200
400
600
800
1000
Lab:
9Lab:
9
SELENIUM,
UG/

LSELENIUM,
L
Wed
Mar
20
13:
31:
58
2002
Spike
Concentration
c:/
pw/
ostmdl/
req005/
r005sd1.
s
Measured
ConcentrationAAMA
Metals
Data
Page
12
of
13
Measurement
Results
vs
Spike
Concentrations
(
Matrix
A,
Method
EPA
200.7
ICP/
AES)

100
Lab:
1Lab:
1
SILVER,
UG/
LSILVER,
L
100
Lab:
2Lab:
2
SILVER,
UG/
LSILVER,
L
80
80
80
60
60
60
40
40
40
20
20
20
0
0
0
0
20
40
60
80
100
0
20
40
60
80
100
0
20
40
60
80
100
Lab:
3Lab:
3
SILVER,
UG/
LSILVER,
L
100
200
250
80
150
Lab:
4Lab:
4
SILVER,
UG/
LSILVER,
L
Lab:
5Lab:
5
SILVER,
UG/
LSILVER,
L
200
60
150
100
40
100
50
20
50
0
00
Lab:
6Lab:
6
SILVER,
UG/
LSILVER,
L
0
20
40
60
80100
0
20
40
60
80100
0
20
40
60
80100
Lab:
7Lab:
7
SILVER,
UG/
LSILVER,
L
100
80
80
80
60
60
60
40
40
40
20
20
20
0
0
0
0
20
40
60
80
100
0
20
40
60
80
100
0
20
40
60
80
100
Lab:
9Lab:
9
SILVER,
UG/
LSILVER,
L
Lab:
8Lab:
8
SILVER,
UG/
LSILVER,
L
Wed
Mar
20
13:
32:
00
2002
Spike
Concentration
c:/
pw/
ostmdl/
req005/
r005sd1.
s
Measured
ConcentrationAAMA
Metals
Data
Page
13
of
13
Measurement
Results
vs
Spike
Concentrations
(
Matrix
A,
Method
EPA
200.7
ICP/
AES)

250
200
200
Lab:
1Lab:
1
ZINC,
UG/
LZINC,
L
200
150
150
100
100
100
50
0
Lab:
2Lab:
2
ZINC,
UG/
LZINC,
L
50
00
0
50
100
150
200
250
0
50
100
150
200
250
0
50
100
150
200
250
Lab:
3Lab:
3
ZINC,
UG/
LZINC,
L
250
300
200
Lab:
5Lab:
5
ZINC,
UG/
LZINC,
L
200
200
Lab:
4Lab:
4
ZINC,
UG/
LZINC,
L
150
150
100
100
100
50
50
000
0
50
100
150
200
250
0
50
100
150
200
250
0
50
100
150
200
250
Lab:
6Lab:
6
ZINC,
UG/
LZINC,
L
Lab:
7Lab:
7
ZINC,
UG/
LZINC,
L
250
300
250
200
Lab:
8Lab:
8
ZINC,
UG/
LZINC,
L
250
200
200
150
150
150
Lab:
9Lab:
9
ZINC,
UG/
LZINC,
L
100
100
100
50
50
50
0
0
0
50
100
150
200
250
0
50
100
150
200
250
0
50
100
150
200
250
Wed
Mar
20
13:
32:
02
2002
Spike
Concentration
c:/
pw/
ostmdl/
req005/
r005sd1.
s