Document ID: EPA-HQ-OPP-2005-0123-0209
Agency: epa
Document Type: Supporting & Related Material
Title: 
Posted Date: 2006-05-31T04:00Z

UNITED
STATES
ENVIRONMENTAL
PROTECTION
AGENCY
WASHINGTON,
D.
C.
20460
OFFICE
OF
PREVENTION,
PESTICIDES
AND
TOXIC
SUBSTANCES
February
22,
2002
MEMORANDUM
Subject:
Reregistration
of
Methyl
Bromide:
Product
and
Residue
Chemistry
Chapters
to
the
Reregistration
Eligibility
Document;
Chemical
No.
53201;
DP
Barcode
D271583
From:
Christine
L.
Olinger,
Chemist
Reregistration
Branch
I
Health
Effects
Division
(
7509C)

Through:
Whang
Phang
Ph.
D.,
Branch
Senior
Scientist
Reregistration
Branch
I
Health
Effects
Division
(
7509C)

and
Christina
Swartz,
Chemist
William
Hazel,
Chemist
Reregistration
Branch
I
Health
Effects
Division
(
7509C)

To:
Joseph
Nevola
Special
Review
and
Reregistration
Division
(
7508W)

Attached
are
the
Product
and
Residue
Chemistry
Chapters
to
the
Reregistration
Eligibility
Document
for
the
fumigant
methyl
bromide.
These
chapters
have
been
prepared
by
Dynamac
Corporation
under
supervision
of
HED,
and
the
review
has
been
revised
to
reflect
Division
policies.

Summary
of
Product
Chemistry
Chapter
Most
product
chemistry
requirements
have
been
satisfied
for
the
technical
and
manufacturing­
use
products.
Confirmatory
data
are
required
for
the
Albemarle
98%
FI
(
formulation
intermediate)
and
the
Great
Lakes
MPs
(
manufacturing
use
products).
2
Summary
of
Residue
Chemistry
Chapter
Sufficient
residue
chemistry
data
are
available
to
conduct
a
reasonably
reliable
dietary
exposure
assessment.
No
additional
residue
chemistry
studies
are
required,
but
the
registrants
must
modify
product
labels
so
they
are
consistent
with
the
residue
studies.

cc:
COlinger,
Reg.
Std.
File,
7509C:
RRB1:
CLOlinger:
clo:
CM#
2:
Rm
722J:
305­
5406:
2/
06/
02
RDI:
CSwartz:
12/
05/
01;
WPhang:
01/
30/
02
H
H
H
Br
METHYL
BROMIDE
REREGISTRATION
ELIGIBILITY
DECISION:

PRODUCT
CHEMISTRY
CONSIDERATIONS
PC
Code
053201;
Case
No.
0335
DP
Barcode
D271583
DESCRIPTION
OF
CHEMICAL
Methyl
bromide
[
bromomethane
(
IUPAC)]
is
an
insecticide/
rodenticide
registered
for
use
as
a
pre­
plant
soil
fumigant
and
post­
harvest
crop
storage
fumigant.

Empirical
Formula:
CH
3
Br
Molecular
Weight:
94.94
CAS
Registry
No.:
74­
83­
9
PC
Code:
053201
IDENTIFICATION
OF
ACTIVE
INGREDIENT
Methyl
bromide
is
a
colorless,
odorless
gas
at
normal
temperatures
and
pressures,
and
a
liquified
gas
under
moderate
pressure.
Methyl
bromide
has
a
specific
gravity
(
liquid)
of
1.732
at
0
C
and
760
mm
Hg,
vapor
density
(
gas)
of
3.27,
boiling
point
of
3.6
C,
octanol/
water
partition
coefficient
(
log
P
ow
)
of
1.19,
and
vapor
pressure
of
1400
mm
Hg
at
20
C.
Methyl
bromide
is
soluble
in
water
at
1.75
g/
100
mL
at
20
C,
and
is
readily
soluble
in
lower
alcohols,
ethers,
esters,
ketones,
halogenated
hydrocarbons,
aromatic
hydrocarbons,
and
carbon
disulfide.
Methyl
bromide
degrades
by
hydrolysis.

MANUFACTURING­
USE
PRODUCTS
According
to
a
search
of
the
Reference
Files
System
(
REFS)
conducted
2/
6/
02,
there
are
seven
registered
manufacturing­
use
products
(
MPs)
under
PC
Code
053201.
The
registered
MPs
listed
in
Table
1
are
subject
to
a
reregistration
eligibility
decision.
2
Table
1.
Registered
methyl
bromide
manufacturing­
use
products.

Formulation
EPA
Reg.
No.
Registrant
100%
T
15298­
4
Ameribrom,
Incorporated
99.8%
T
3377­
9
Albemarle
Corporation
1
98%
FI
2
3377­
27
100%
T
5785­
51
Great
Lakes
Chemical
Corporation
99.5%
FI
5785­
109
98%
FI
5785­
56
67%
FI
5785­
52
1
Previously
Ethyl
Corporation.
2
Although
REFS
identifies
this
product
as
a
technical,
the
Methyl
Bromide
Update
determined
that
this
product
is
actually
an
FI.

REGULATORY
BACKGROUND
The
Methyl
Bromide
Reregistration
Standard
issued
3/
28/
86
required
additional
product
chemistry
data
concerning
methyl
bromide.
The
Methyl
Bromide
Guidance
Document
dated
8/
86
required
that
all
new
product
chemistry
data
be
submitted
for
the
reregistration
of
methyl
bromide
because
new
requirements
had
been
introduced
and
previously
submitted
data
needed
to
be
updated.
Data
submitted
in
response
to
the
Guidance
Document
for
the
MPs
were
evaluated
in
Agency
reviews
and
in
the
Methyl
Bromide
Reregistration
Standard
Update
dated
6/
21/
91
with
regard
to
adequacy
in
fulfilling
product
chemistry
requirements.
Data
in
support
of
registration/
reregistration
have
been
submitted
by
the
Methyl
Bromide
Industry
Panel
(
MBIP)
which
consists
of
the
following
members:
Albemarle
Corporation,
Great
Lakes
Chemicals
Corporation,
Ameribrom,
Inc.,
and
Trical,
Inc.
The
Methyl
Bromide
Update
summarized
the
available
product
chemistry
database
and
required
additional
data
for
the
Ameribrom,
Albemarle,
and
Great
Lakes
Chemical
T/
TGAIs
and
formulation
intermediates
(
FIs).

As
a
safety
measure,
the
Guidance
Document
required
that
end­
use
products
with
methyl
bromide
as
the
active
ingredient,
which
will
be
used
for
any
purpose
other
than
the
fumigation
of
RACs
in
enclosed
chambers,
contain
0.25­
2.0%
chloropicrin
as
an
odor
warning
agent.
Chloropicrin
at
this
concentration
is
considered/
listed
as
an
inert
ingredient.

The
current
status
of
the
product
chemistry
data
requirements
for
the
methyl
bromide
T/
TGAIs
and
FIs
is
presented
in
the
attached
data
summary
tables.
Refer
to
these
tables
for
a
listing
of
the
outstanding
product
chemistry
data
requirements.
3
CONCLUSIONS
Most
pertinent
product
chemistry
requirements
data
have
been
satisfied
for
the
Ameribrom
100%
and
Albemarle
99.8%
T/
TGAIs,
and
for
the
Albemarle
98%
FI;
however,
additional
data
are
required
for
the
T/
TGAIs
concerning
oxidation/
reduction
and
UV/
vis
absorption
(
OPPTS
830.6314
and
7050)
and
for
the
Albemarle
98%
FI
concerning
oxidation/
reduction
(
OPPTS
830.6314).
All
pertinent
product
chemistry
data
requirements
have
been
satisfied
for
the
Great
Lakes
99.5%
FI.
Additional
data
are
required
for
the
remaining
Great
Lakes
MPs
as
follow:
(
i)
for
the
100%
T/
TGAI,
data
concerning
certified
limits,
oxidation/
reduction,
and
UV/
vis
absorption
(
OPPTS
830.1750,
6314,
and
7050);
(
ii)
for
the
98%
FI,
discussions/
data
concerning
formation
of
impurities,
certified
limits,
enforcement
methods,
and
oxidation/
reduction
(
OPPTS
830.1600,
1670,
1800,
and
6314);
and
(
iii)
for
the
67%
FI,
discussions/
data
concerning
formation
of
impurities,
enforcement
methods,
and
oxidation/
reduction
(
OPPTS
830.1670,
1800,
and
6314).
Provided
that
the
registrants
submit
the
data
required
in
the
attached
data
summary
tables
for
the
methyl
bromide
MPs,
and
either
certify
that
the
suppliers
of
beginning
materials
and
the
manufacturing
processes
have
not
changed
since
the
last
comprehensive
product
chemistry
reviews
or
submit
complete
updated
product
chemistry
data
packages,
the
Branch
has
no
objections
to
the
reregistration
of
methyl
bromide
with
respect
to
product
chemistry
data
requirements.
4
Case
No.
0335
PC
Code:
053201
Case
Name:
Methyl
bromide
Registrant:
Ameribrom,
Incorporated
Product(
s):
100%
T
(
EPA
Reg.
No.
15298­
4)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
40138201,
CSF
7/
2/
96
3
830.1600
Description
of
materials
used
to
produce
the
product
Y
40138201,
42500801
4
830.1620
Description
of
production
process
Y
40138201,
42500801
4
830.1670
Discussion
of
formation
of
impurities
Y
40138201
830.1700
Preliminary
analysis
Y
42500802
4
830.1750
Certified
limits
Y
40138201,
42500802
4,
CSF
7/
2/
96
3
830.1800
Enforcement
analytical
method
Y
42500802
4
830.6302
Color
Y
40138201
830.6303
Physical
state
Y
40138201
830.6304
Odor
N/
A
5
40138201
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
N/
A
6
830.6314
Oxidation/
reduction:
chemical
incompatability
N
830.6315
Flammability
N/
A
7
830.6316
Explodability
N/
A
6
830.6317
Storage
stability
Y
40832501
8
830.6319
Miscibility
N/
A
7
830.6320
Corrosion
characteristics
Y
42933201
9
830.7000
pH
N/
A
6
40138201
830.7050
UV/
visible
absorption
N
10
830.7100
Viscosity
N/
A
7
830.7200
Melting
point/
melting
range
N/
A
7
40138201
830.7220
Boiling
point/
boiling
range
N/
A
7
40138201
830.7300
Density/
relative
density/
bulk
density
N/
A
7
40138201
830.7370
Dissociation
constants
in
water
N/
A
6
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
Y
42541301
11
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
Y
40138201,
42537801
11,
43257101
12
830.7950
Vapor
pressure
N/
A
7
40138201
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.

2
Bolded
references
were
reviewed
in
the
Methyl
Bromide
Reregistration
Standard
Update
dated
6/
21/
91;
all
other
references
were
reviewed
as
noted.

3
RD
Memorandum,
D228391,
8/
5/
96,
A.
Skapars.

4
DP
Barcode
D183771,
2/
12/
93,
D.
McNeilly.
5
5
Data
are
not
required
because
methyl
bromide
is
a
hazardous
gas.

6
Data
requirements
were
waived
under
DP
Barcode
D173004,
2/
7/
92,
R.
Perfetti.

7
Data
are
not
required
because
the
TGAI/
MP
is
a
gas
at
room
temperature
and
standard
pressure.

8
MBIP
data;
DP
Barcode
D208064,
11/
15/
96,
K.
Dockter.

9
DP
Barcode
D202501,
5/
3/
94,
F.
Toghrol.

10
The
OPPTS
Series
830,
Product
Properties
Test
Guidelines
require
data
pertaining
to
UV/
visible
absorption
for
the
PAI.

11
MBIP
data;
DP
Barcodes
D184917
and
D184926,
3/
2/
93,
D.
McNeilly.

12
MBIP
data;
DP
Barcodes
D204592
and
D204938,
9/
8/
94,
F.
Toghrol.
6
Case
No.
0335
PC
Code:
053201
Case
Name:
Methyl
bromide
Registrant:
Albemarle
Corporation
Product(
s):
99.8%
T
(
EPA
Reg.
No.
3377­
9)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
40254204,
43588301
3
CSF
6/
2/
97
4,
CSF
3/
16/
00
5
830.1600
Description
of
materials
used
to
produce
the
product
Y
40254204,
43588301
3,
45080201
5
830.1620
Description
of
production
process
Y
40254204,
43588301
3,
45080201
5
830.1670
Discussion
of
formation
of
impurities
Y
40254204,
43588301
3,
45080201
5
830.1700
Preliminary
analysis
Y
40254205,
42500701
6,
43588301
3,
45080201
5
830.1750
Certified
limits
Y
40254205,
43588301
3
CSF
6/
2/
97
4,
CSF
3/
16/
00
5
830.1800
Enforcement
analytical
method
Y
42500701
6
830.6302
Color
Y
43588302
3
830.6303
Physical
state
Y
43588302
3
830.6304
Odor
N/
A
7
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
N/
A
8
830.6314
Oxidation/
reduction:
chemical
incompatability
N
9
40254206
830.6315
Flammability
N/
A
10
830.6316
Explodability
N/
A
8
40254206
830.6317
Storage
stability
Y
40832501
11
830.6319
Miscibility
N/
A
10
830.6320
Corrosion
characteristics
Y
42933201
12
830.7000
pH
N/
A
8
830.7050
UV/
visible
absorption
N
13
830.7100
Viscosity
N/
A
10
40254206
830.7200
Melting
point/
melting
range
N/
A
10
830.7220
Boiling
point/
boiling
range
N/
A
10
830.7300
Density/
relative
density/
bulk
density
N/
A
10
830.7370
Dissociation
constants
in
water
N/
A
8
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
Y
42541301
14
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
Y
42537801
14,
43257101
15
830.7950
Vapor
pressure
N/
A
10
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
Data
for
the
basic
and
alternate
formulation
have
been
reviewed.

2
Bolded
references
were
reviewed
in
the
Methyl
Bromide
Reregistration
Standard
Update
dated
6/
21/
91;
all
other
7
references
were
reviewed
as
noted.

3
DP
Barcodes
D213604
and
D228086,
11/
14/
96,
K.
Dockter.

4
RD
Memorandum,
D237440,
12/
30/
97,
B.
Kitchens.

5
RD
Memorandum,
D265672,
6/
5/
00,
B.
Kitchens.

6
DP
Barcode
D183769,
2/
11/
93,
D.
McNeilly.

7
Data
are
not
required
because
methyl
bromide
is
a
hazardous
gas.

8
Data
requirements
were
waived
under
DP
Barcode
D173004,
2/
7/
92,
R.
Perfetti.

9
Additional
data
are
required
concerning
the
procedure,
raw
data,
and
calculations
used
in
the
determination.

10
Data
are
not
required
because
the
TGAI/
MP
is
a
gas
at
room
temperature
and
standard
pressure.

11
MBIP
data;
DP
Barcode
D208064,
11/
15/
96,
K.
Dockter.

12
DP
Barcode
D202501,
5/
3/
94,
F.
Toghrol.

13
The
OPPTS
Series
830,
Product
Properties
Test
Guidelines
require
data
pertaining
to
UV/
visible
absorption
for
the
PAI.

14
MBIP
data;
DP
Barcodes
D184917
and
D184926,
3/
2/
93,
D.
McNeilly.

15
MBIP
data;
DP
Barcodes
D204592
and
D204938,
9/
8/
94,
F.
Toghrol.
8
Case
No.
0335
PC
Code:
053201
Case
Name:
Methyl
bromide
Registrant:
Albemarle
Corporation
Product(
s):
98%
FI
(
EPA
Reg.
No.
3377­
27)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
40315901,
44004101
3,
44004102
3,
CSF
6/
2/
97
4
830.1600
Description
of
materials
used
to
produce
the
product
Y
40315901,
44004101
3
830.1650
Description
of
formulation
process
Y
40315901,
44004101
3
830.1670
Discussion
of
formation
of
impurities
Y
40315901,
44004101
3
830.1700
Preliminary
analysis
Y
44004102
3
830.1750
Certified
limits
Y
44004101
3,
44004102
3,
CSF
6/
2/
97
4
830.1800
Enforcement
analytical
method
Y
44004102
3
830.6302
Color
Y
44043101
3
830.6303
Physical
state
Y
44043101
3
830.6304
Odor
N/
A
5
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
N/
A
6
830.6314
Oxidation/
reduction:
chemical
incompatability
N
7
40315903
830.6315
Flammability
N/
A
8
830.6316
Explodability
N/
A
9
40315903
830.6317
Storage
stability
Y
40832501
10
830.6319
Miscibility
N/
A
8
830.6320
Corrosion
characteristics
Y
42933201
11
830.7000
pH
N/
A
9
830.7050
UV/
visible
absorption
N/
A
6
830.7100
Viscosity
N/
A
9
40315903
830.7200
Melting
point/
melting
range
N/
A
6
830.7220
Boiling
point/
boiling
range
N/
A
6
830.7300
Density/
relative
density/
bulk
density
N/
A
8
830.7370
Dissociation
constants
in
water
N/
A
6
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
N/
A
6
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
N/
A
6
830.7950
Vapor
pressure
N/
A
6
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
Although
REFS
identifies
this
product
as
a
technical,
the
Methyl
Bromide
Update
determined
that
its
is
actually
an
FI
manufactured
from
an
EPA­
registered
product;
therefore,
all
TGAI
data
requirements
will
be
fulfilled
by
data
for
the
technical
source
product.

2
Bolded
references
were
reviewed
in
the
Methyl
Bromide
Reregistration
Standard
Update
dated
6/
21/
91;
all
other
references
were
reviewed
as
noted.
9
3
DP
Barcodes
D213604
and
D228086,
11/
14/
96,
K.
Dockter.

4
RD
Memorandum,
D237441,
12/
30/
97,
B.
Kitchens.

5
Data
are
not
required
because
methyl
bromide
is
a
hazardous
gas.

6
Data
requirements
for
the
TGAI
will
be
fulfilled
by
data
for
the
technical
source
product.

7
Additional
data
are
required
concerning
the
procedure,
raw
data,
and
calculations
used
in
the
determination.

8
Data
are
not
required
because
the
TGAI/
MP
is
a
gas
at
room
temperature
and
standard
pressure.

9
Data
requirements
were
waived
under
DP
Barcode
D173004,
2/
7/
92,
R.
Perfetti.

10
MBIP
data;
DP
Barcode
D208064,
11/
15/
96,
K.
Dockter.

11
DP
Barcode
D202501,
5/
3/
94,
F.
Toghrol.
10
Case
No.
0335
PC
Code:
053201
Case
Name:
Methyl
bromide
Registrant:
Great
Lakes
Chemical
Corporation
Product(
s):
100%
T
(
EPA
Reg.
No.
5785­
51)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
40253201,
42569603
3,
42571801
3
830.1600
Description
of
materials
used
to
produce
the
product
Y
40253201,
42571801
3
830.1620
Description
of
production
process
Y
40253201,
42571801
3
830.1670
Discussion
of
formation
of
impurities
Y
40253201
830.1700
Preliminary
analysis
Y
40253202,
42569601
3
830.1750
Certified
limits
N
4
40253202,
42569603
3,
42571801
3
830.1800
Enforcement
analytical
method
Y
40253203,42569601
3
830.6302
Color
Y
40253203
830.6303
Physical
state
Y
40253203
830.6304
Odor
N/
A
5
40253203
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
N/
A
6
42053203
830.6314
Oxidation/
reduction:
chemical
incompatability
N
7
40253203
830.6315
Flammability
N/
A
8
830.6316
Explodability
N/
A
6
40253203
830.6317
Storage
stability
Y
40253203,
40832501
9
830.6319
Miscibility
N/
A
8
830.6320
Corrosion
characteristics
Y
40253203,
42933201
10
830.7000
pH
N/
A
6
830.7050
UV/
visible
absorption
N
11
830.7100
Viscosity
N/
A
8
830.7200
Melting
point/
melting
range
N/
A
8
830.7220
Boiling
point/
boiling
range
N/
A
8
40253203
830.7300
Density/
relative
density/
bulk
density
N/
A
8
40253203
830.7370
Dissociation
constants
in
water
N/
A
6
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
Y
40253203,
42541301
12
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
Y
40253203,
42537801
12,
43257101
13
830.7950
Vapor
pressure
N/
A
8
40253203
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.

2
Bolded
references
were
reviewed
in
the
Methyl
Bromide
Reregistration
Standard
Update
dated
6/
21/
91;
all
other
references
were
reviewed
as
noted.

3
D275390,
C.
Olinger
7/
17/
01.
11
4
The
CSF
must
be
revised
to
adjust
the
proposed
upper
certified
limit
for
methyl
bromide.

5
Data
are
not
required
because
methyl
bromide
is
a
hazardous
gas.

6
Data
requirements
were
waived
under
DP
Barcode
D173004,
2/
7/
92,
R.
Perfetti.

7
Additional
data
are
required
concerning
the
procedure,
raw
data,
and
calculations
used
in
the
determination.

8
Data
are
not
required
because
the
TGAI/
MP
is
a
gas
at
room
temperature
and
standard
pressure.

9
MBIP
data;
DP
Barcode
D208064,
11/
15/
96,
K.
Dockter.

10
DP
Barcode
D196315,
1/
13/
94,
F.
Toghrol.

11
The
OPPTS
Series
830,
Product
Properties
Test
Guidelines
require
data
pertaining
to
UV/
visible
absorption
for
the
PAI.

12
MBIP
data;
DP
Barcodes
D184917
and
D184926,
3/
2/
93,
D.
McNeilly.

13
MBIP
data;
DP
Barcodes
D204592
and
D204938,
9/
8/
94,
F.
Toghrol.
12
Case
No.
0335
PC
Code:
053201
Case
Name:
Methyl
bromide
Registrant:
Great
Lakes
Chemical
Corporation
Product(
s):
99.5%
FI
(
EPA
Reg.
No.
5785­
109)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
CSF
12/
18/
99
3
830.1600
Description
of
materials
used
to
produce
the
product
N/
A
4
830.1650
Description
of
formulation
process
N/
A
4
830.1670
Discussion
of
formation
of
impurities
N/
A
4
830.1700
Preliminary
analysis
N/
A
5
830.1750
Certified
limits
Y
CSF
12/
18/
99
3
830.1800
Enforcement
analytical
method
N/
A
4
830.6302
Color
N/
A
4
830.6303
Physical
state
N/
A
4
830.6304
Odor
N/
A
6
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
N/
A
5
830.6314
Oxidation/
reduction:
chemical
incompatability
N/
A
4
830.6315
Flammability
N/
A
7
830.6316
Explodability
N/
A
8
830.6317
Storage
stability
Y
40832501
9
830.6319
Miscibility
N/
A
7
830.6320
Corrosion
characteristics
Y
42933201
10
830.7000
pH
N/
A
8
830.7050
UV/
visible
absorption
N/
A
5
830.7100
Viscosity
N/
A
7
830.7200
Melting
point/
melting
range
N/
A
5
830.7220
Boiling
point/
boiling
range
N/
A
5
830.7300
Density/
relative
density/
bulk
density
N/
A
7
830.7370
Dissociation
constants
in
water
N/
A
5
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
N/
A
5
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
N/
A
5
830.7950
Vapor
pressure
N/
A
5
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
This
product
was
registered
under
a
"
Me­
Too"
application.
The
Technical
Review
Branch
approved
bridging
data
for
an
identical
end­
use
product
(
EPA
Reg.
No.
5785­
8)
as
well
as
data
for
the
100%
T
(
EPA
Reg.
No.
5785­
51)
and
the
98%
FI
(
EPA
Reg.
No.
5785­
56)
to
fulfill
data
requirements
(
DP
Barcode
D253973,
3/
25/
99,
E.
McAndrew).
Because
the
product
is
manufactured
from
an
EPAregistered
product,
TGAI
data
requirements
will
be
fulfilled
by
data
for
the
technical
source
product.

2
All
references
were
reviewed
as
noted.
13
3
RD
Memorandum,
D253971,
4/
19/
99,
S.
Mathur.

4
Data
requirements
will
be
fulfilled
by
bridging
data
for
EPA
Reg.
Nos.
5785­
8,
5785­
51,
and/
or
5785­
56.

5
Data
requirements
for
the
TGAI
will
be
fulfilled
by
data
for
the
technical
source
product.

6
Data
are
not
required
because
methyl
bromide
is
a
hazardous
gas.

7
Data
are
not
required
because
the
TGAI/
MP
is
a
gas
at
room
temperature
and
standard
pressure.

8
Data
requirements
were
waived
under
DP
Barcode
D173004,
2/
7/
92,
R.
Perfetti.

9
MBIP
data;
DP
Barcode
D208064,
11/
15/
96,
K.
Dockter.

10
DP
Barcode
D196315,
1/
13/
94,
F.
Toghrol.
14
Case
No.
0335
PC
Code:
053201
Case
Name:
Methyl
bromide
Registrant:
Great
Lakes
Chemical
Corporation
Product(
s):
98%
FI
(
EPA
Reg.
No.
5785­
56)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
42571803
3,
CSF
8/
6/
96
3
830.1600
Description
of
materials
used
to
produce
the
product
Y
42571803
3
830.1650
Description
of
formulation
process
Y
42571803
3
830.1670
Discussion
of
formation
of
impurities
N
830.1700
Preliminary
analysis
N/
A
5
830.1750
Certified
limits
N
4
42571803
3,
CSF
8/
6/
96
3
830.1800
Enforcement
analytical
method
N
830.6302
Color
Y
42571803
3
830.6303
Physical
state
Y
42571803
3
830.6304
Odor
N/
A
6
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
N/
A
5
830.6314
Oxidation/
reduction:
chemical
incompatability
N
830.6315
Flammability
N/
A
7
830.6316
Explodability
N/
A
8
830.6317
Storage
stability
Y
40832501
9
830.6319
Miscibility
N/
A
7
830.6320
Corrosion
characteristics
Y
42933201
10
830.7000
pH
N/
A
8
830.7050
UV/
visible
absorption
N/
A
5
830.7100
Viscosity
N/
A
7
830.7200
Melting
point/
melting
range
N/
A
5
830.7220
Boiling
point/
boiling
range
N/
A
5
830.7300
Density/
relative
density/
bulk
density
N/
A
7
830.7370
Dissociation
constants
in
water
N/
A
5
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
N/
A
5
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
N/
A
5
830.7950
Vapor
pressure
N/
A
5
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
The
98%
FI
is
manufactured
from
an
EPA­
registered
product;
therefore,
all
TGAI
data
requirements
will
be
fulfilled
by
data
for
the
technical
source
product.

2
Bolded
references
were
reviewed
in
the
Methyl
Bromide
Reregistration
Standard
Update
dated
6/
21/
91;
all
other
references
were
reviewed
as
noted.

3
D275390,
C.
Olinger
7/
17/
01.

4
The
CSF
must
be
revised
to
list
the
current
sources
of
the
warning
agent
and
the
respective
EPA
Reg.
Nos.
15
5
Data
requirements
for
the
TGAI
will
be
fulfilled
by
data
for
the
technical
source
product.

6
Data
are
not
required
because
methyl
bromide
is
a
hazardous
gas.

7
Data
are
not
required
because
the
TGAI/
MP
is
a
gas
at
room
temperature
and
standard
pressure.

8
Data
requirements
were
waived
under
DP
Barcode
D173004,
2/
7/
92,
R.
Perfetti.

9
MBIP
data;
DP
Barcode
D208064,
11/
15/
96,
K.
Dockter.

10
DP
Barcode
D196315,
1/
13/
94,
F.
Toghrol.
16
Case
No.
0335
PC
Code:
053201
Case
Name:
Methyl
bromide
Registrant:
Great
Lakes
Chemical
Corporation
Product(
s):
67%
FI
(
EPA
Reg.
No.
5785­
52)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
CSF
8/
19/
97
3
830.1600
Description
of
materials
used
to
produce
the
product
Y
42571802
4
830.1650
Description
of
formulation
process
Y
42571802
4,
44230001
5
830.1670
Discussion
of
formation
of
impurities
N
830.1700
Preliminary
analysis
N/
A
6
830.1750
Certified
limits
Y
42571802
4,
CSF
8/
19/
97
3
830.1800
Enforcement
analytical
method
N
830.6302
Color
Y
42571802
4
830.6303
Physical
state
Y
42571802
4
830.6304
Odor
N/
A
7
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
N/
A
6
830.6314
Oxidation/
reduction:
chemical
incompatability
N
830.6315
Flammability
N/
A
8
830.6316
Explodability
N/
A
9
830.6317
Storage
stability
Y
40832501
10
830.6319
Miscibility
N/
A
8
830.6320
Corrosion
characteristics
Y
42933201
11
830.7000
pH
N/
A
9
830.7050
UV/
visible
absorption
N/
A
6
830.7100
Viscosity
N/
A
8
830.7200
Melting
point/
melting
range
N/
A
6
830.7220
Boiling
point/
boiling
range
N/
A
6
830.7300
Density/
relative
density/
bulk
density
N/
A
8
830.7370
Dissociation
constants
in
water
N/
A
6
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
N/
A
6
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
N/
A
6
830.7950
Vapor
pressure
N/
A
6
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
The
67%
FI
is
manufactured
from
an
EPA­
registered
product;
therefore,
all
TGAI
data
requirements
will
be
fulfilled
by
data
for
the
technical
source
product.

2
All
references
were
reviewed
as
noted.

3
RD
Letter,
11/
10/
97,
M.
Waller
4
D275390,
C.
Olinger
7/
17/
01.
17
5
RD
Memorandum,
D234151,
7/
1/
97,
A.
Smith.

6
Data
requirements
for
the
TGAI
will
be
fulfilled
by
data
for
the
technical
source
product.

7
Data
are
not
required
because
methyl
bromide
is
a
hazardous
gas.

8
Data
are
not
required
because
the
TGAI/
MP
is
a
gas
at
room
temperature
and
standard
pressure.

9
Data
requirements
were
waived
under
DP
Barcode
D173004,
2/
7/
92,
R.
Perfetti.

10
MBIP
data;
DP
Barcode
D208064,
11/
15/
96,
K.
Dockter.

11
DP
Barcode
D196315,
1/
13/
94,
F.
Toghrol.
18
AGENCY
MEMORANDA
CITED
IN
THIS
DOCUMENT
CBRS
No(
s).:
9225
and
9269
DP
Barcode(
s):
D173004
Subject:
Great
Lakes
Chemical
Corp.:
Response
to
the
Methyl
Bromide
Reregistration
Standard:
Product
and
Residue
Chemistry
Data
Waiver
Requests.
From:
R.
Perfetti
To:
W.
Burnam
and
L.
Rossi
Dated:
2/
7/
92
MRID(
s):
None
CBRS
No(
s).:
10752
DP
Barcode(
s):
D183769
Subject:
Methyl
Bromide:
Product
Chemistry
Data,
GDLN
62­
3.
From:
D.
McNeilly
To:
D.
Mackey
Dated:
2/
11/
93
MRID(
s):
42500701
CBRS
No(
s).:
10757
DP
Barcode(
s):
D183771
Subject:
Methyl
Bromide:
Product
Chemistry
Data,
Ameribrom
Corp.
Subdivision
D,
GDLNs:
61­
2,
62­
1,
62­
2,
and
62­
3.
From:
D.
McNeilly
To:
D.
Mackey
Dated:
2/
12/
93
MRID(
s):
42500801
and
42500802
CBRS
No(
s).:
10922
and
10923
DP
Barcode(
s):
D184917
and
184926
Subject:
Methyl
Bromide:
Product
Chem
Data,
GDLNs
63­
8,
63­
11.
From:
D.
McNeilly
To:
D.
Mackey
Dated:
3/
2/
93
MRID(
s):
42537801
and
42541301
19
CBRS
No(
s).:
12752
DP
Barcode(
s):
D196315
Subject:
Methyl
Bromide
Reregistration:
List
A
Chemical
No.
053201;
Case
No.
0335.
Great
Lakes
Response
to
Methyl
Bromide
Product
Chemistry
Data
Requirements
Regarding
Corrosion
Characteristics
(
GLN
No.
63­
20).
From:
F.
Toghrol
To:
L.
Rossi/
L.
Schnaubelt
Dated:
1/
13/
94
MRID(
s):
42933201
CBRS
No(
s).:
13577
DP
Barcode(
s):
D202501
Subject:
Methyl
Bromide
Reregistration:
List
A
Chemical
No.
053201;
Case
No.
0335.
Methyl
Bromide
Industry
Panel
(
MBIP)
Response
(
letter
dated
4/
25/
94)
to
Methyl
Bromide
Product
Chemistry
Data
Requirements
Regarding
Corrosion
Characteristics
(
GLN
No.
63­
20).
From:
F.
Toghrol
To:
L.
Rossi/
L.
Schnaubelt
Dated:
5/
3/
94
MRID(
s):
42933201
CBRS
No(
s).:
13922
and
13941
DP
Barcode(
s):
D204592
and
D204938
Subject:
Methyl
Bromide
Reregistration:
List
A
Chemical
No.
053201;
Case
No.
0335.
MBIP:
Response
to
Methyl
Bromide
Product
Chemistry
Data
Requirements
Regarding
Methyl
Bromide
Solubility
(
GLN
No.
63­
8).
From:
F.
Toghrol
To:
L.
Schnaubelt
Dated:
9/
8/
94
MRID(
s):
43257101
CBRS
No(
s).:
13101
DP
Barcode(
s):
D198382
Subject:
Methyl
Bromide
Reregistration:
List
A
Chemical
No.
053201;
Case
No.
0335.
Ameribrom,
Inc.:
Response
to
Methyl
Bromide
Product
Chemistry
Data
Requirements
Regarding
Methyl
Bromide
Product
Identity
and
Disclosure
of
Ingredients
and
Certification
of
Ingredient
Limits
(
GLN
No.
61­
1
and
62­
2).
From:
F.
Toghrol
To:
L.
Schnaubelt
Dated:
9/
27/
94
MRID(
s):
None
20
DP
Barcode(
s):
RD
Memorandum
D228391
Subject:
Product
Chemistry
Review;
Reg.
No.
or
File
Symbol
No.
15298­
4.
From:
A.
Skapars
To:
W.
Francis/
L.
Dobbins
Dated:
8/
5/
96
MRID(
s):
None
CBRS
No(
s).:
15331
and
17499
DP
Barcode(
s):
D213604
and
D228086
Subject:
Methyl
Bromide
Reregistration.
Albemarle
3/
13
&
15/
95
and
2/
1
&
6/
14/
96
Responses
[
Series
830
Data
&
CSF
for
the
99%
T;
3377­
9
and
Series
830
Data
for
the
98%
T;
[
3377­
27]
to
the
Agency
3/
22/
94
Letter,
RE:
the
6/
21/
91
Reregistration
Standard
Update,
and
"
as
a
Follow
up
to
the
Albemarle
2/
22/
95
Letter".
From:
K.
Dockter
To:
P.
Deschamp
Dated:
11/
14/
96
MRID(
s):
43588301,
43588302,
44004101,
44004102,
and
44043101
CBRS
No(
s).:
14482
DP
Barcode(
s):
D208064
Subject:
Methyl
Bromide
Reregistration.
CMA
9/
29/
94
Response
[
830.6317
Data
for
EPA
Reg.
No.
5785­
51­
AA]
to
R.
Perfetti
2/
7/
92
Review;
CBRS
9225.
Chemical
053201,
Case
0335.
From:
K.
Dockter
To:
P.
Deschamp
Dated:
11/
15/
96
MRID(
s):
40832501
DP
Barcode(
s):
RD
Memorandum
D234151
Subject:
Product
Chemistry
Review;
Reg./
File
Symbol
No.
5785­
52;
Product
Name:
67­
33;
Company:
Great
Lakes
Chem
Corp.
From:
A.
Smith
To:
K.
Swift
Dated:
7/
1/
97
MRID(
s):
44230001
21
DP
Barcode(
s):
RD
Letter
Subject:
Review
of
Basic
Formula
Dated
August
19,
1997;
67­
33;
EPA
Reg.
No.
5785­
52;
Your
Letter
Dated
August
19,
1997.
From:
M.
Waller
To:
P.
Bricker,
Great
Lakes
Chemical
Corporation
Dated:
11/
10/
97
MRID(
s):
None
DP
Barcode(
s):
RD
Memorandum
D237440
Subject:
Product
Chemistry
Review;
Reg./
File
Symbol
No.
3377­
9;
Product
Name:
Methyl
Bromide
Technical;
Company:
Albemarle
Corporation.
From:
B.
Kitchens
To:
M.
Waller/
T.
Stowe
Dated:
12/
30/
97
MRID(
s):
None
DP
Barcode(
s):
RD
Memorandum
D237441
Subject:
Product
Chemistry
Review;
Reg./
File
Symbol
No.
3377­
27;
Product
Name:
MB
R
98
Technical;
Company:
Albemarle
Corporation.
From:
B.
Kitchens
To:
M.
Waller/
T.
Stowe
Dated:
12/
30/
97
MRID(
s):
None
DP
Barcode(
s):
TRB
Memorandum
D253973
Subject:
Technical
Review
Branch
Similarity
Clinic
Determination.
EPA
Reg.
No.
5785­
RNO.
Methyl
Bromide
99.5.
Case
No.
064296.
From:
E.
McAndrew
To:
T.
Stowe
Dated:
3/
25/
99
MRID(
s):
None
DP
Barcode(
s):
RD
Memorandum
D253971
Subject:
Product
Chemistry
Review;
Reg./
File
Symbol
No.
5785­
RNO;
Product
Name:
Methyl
Bromide
99.5;
Company:
Great
Lakes
Chemical
Corporation.
From:
S.
Mathur
To:
M.
Waller
Dated:
4/
19/
99
MRID(
s):
None
22
DP
Barcode(
s):
RD
Memorandum
D265672
Subject:
Product
Chemistry
Review;
Reg./
File
Symbol
No.
3377­
9;
Product
Name:
Methyl
Bromide
Technical;
Company:
Albemarle
Corporation.
From:
B.
Kitchens
To:
M.
Waller/
T.
Stowe
Dated:
6/
5/
00
MRID(
s):
45080201
DP
Barcode(
s):
D275390
Subject:
Reregistration
of
Methyl
Bromide:
Product
Chemistry
Data
From:
C.
Olinger
To:
J.
Nevola
Dated:
7/
17/
01
MRID(
s):
42569601,
42569603,
42571801­
42571803
PRODUCT
CHEMISTRY
CITATIONS
Bibliographic
citations
include
only
MRIDs
containing
data
which
fulfill
data
requirements.

References
(
cited):

40138201
Ameribrom,
Inc.
(
1987)
Product
Chemistry:
Methyl
Bromide.
Unpublished
compilation.
13
p.

40253201
McAllister,
D.
(
1986)
Methyl
Bromide
­
Product
Identity:
Laboratory
Project
ID:
921­
157.
Unpublished
compilation
prepared
by
Great
Lakes
Chemical
Corp.
13
p.

40253202
McAllister,
D.
(
1986)
Methyl
Bromide
­
Analysis
and
Certification
of
Product
Ingredients:
Laboratory
Project
ID:
921­
163.
Unpublished
compilation
prepared
by
Great
Lakes
Chemical
Corp.
28
p.

40253203
McAllister,
D.
(
1986)
Methyl
Bromide
­
Physical
and
Chemical
Characteristics:
Laboratory
Project
ID:
921­
150.
Unpublished
compilation
prepared
by
Great
Lakes
Chemical
Corp.
4
p.

40254204
Ethyl
Corp.
(
1987)
Methyl
Bromide
Technical
­
Product
Chemistry.
Unpublished
compilation.
19
p.

40254205
Ethyl
Corp.
(
1987)
Methyl
Bromide
Technical
­
Product
Chemistry.
Unpublished
study.
6
p.

40254206
Ethyl
Corp.
(
1987)
Methyl
Bromide
Technical
­
Product
Chemistry.
Unpublished
study.
3
p.
23
40315901
Ethyl
Corp.
(
1987)
M­
B­
R
98
Technical
­
Product
Chemistry
Data.
Unpublished
compilation.
14
p.

40315903
Ethyl
Corp.
(
1987)
M­
B­
R
98
Technical
­
Product
Chemistry:
Physical
and
Chemical
Properties.
Unpublished
study.
3
p.

40832501
Ivancovich,
A.
(
1988)
Methyl
Bromide
Storage
Stability
Study
Longterm
Storage:
Project
ID:
B.
R.
No.
12.87.
Unpublished
study
prepared
by
Bolsa
Research
Associates.
16
p.

42500701
Ethyl
Corp.
(
1992)
Methyl
Bromide
Technical:
Product
Chemistry.
Unpublished
study.
8
p.

42500801
Cohen,
T.
(
1992)
Methyl
Bromide:
Product
Chemistry:
Lab
Project
Number:
8326/
DCI/
92­
61.
Unpublished
study
prepared
by
Bromine
Compounds
Ltd.
25
p.

42500802
Cohen,
T.
(
1992)
Methyl
Bromide:
Product
Chemistry:
Lab
Project
Number:
8326/
DCI/
92­
62.
Unpublished
study
prepared
by
Bromine
Compounds
Ltd.
19
p.

42537801
Chemical
Manufacturers
Association
(
1992)
Determination
of
Water
Solubility
of
Methyl
Bromide:
Unpublished
study
prepared
by
Great
Lakes
Corp.
16
p.

42541301
Secara,
S.
(
1990)
Methyl
Bromide
­
Octanol/
Water
Partition
Coefficient:
Lab
Project
Number:
BR
172:
90.
Unpublished
study
prepared
by
BOLSA
Research
Associates,
Inc.
11
p.

42569601
Severs,
L.
(
1992)
Method
Validation
and
Preliminary
Analysis
for
Methyl
Bromide
Formulations:
Final
Report:
Lab
Project
Number:
WILL­
12294.
Unpublished
study
prepared
by
EIL
Research
Labs.,
Inc.
84
p.

42569603
Kelley,
J.
(
1992)
Certification
of
Limits
for
Methyl
Bromide,
"
98­
2"
and
"
67­
33":
Lab
Project
Number.
Unpublished
study
prepared
by
Great
Lakes
chemical
Corp.
8
p.

42571801
McAllister,
D.
(
1992)
Product
Chemistry
Data:
Methyl
Bromide.
Unpublished
study
prepared
by
Great
Lakes
Chemical
Corp.
74
p.

42571802
McAllister,
D.
(
1992)
Product
Chemistry
Data:
Methyl
Bromide.
Unpublished
study
prepared
by
Great
Lakes
Chemical
Corp.
25
p.

42571803
McAllister,
D.
(
1992)
Product
Chemistry
Data:
Methyl
Bromide.
Unpublished
study
prepared
by
Great
Lakes
Chemical
Corp.
25
p.

42933201
Spires,
P.;
Coffey,
R.
(
1993)
Methyl
Bromide
Formulation
Corrosion
Studies:
Final
Report:
Lab
Project
Number:
MBIP­
19.0­
CORROS­
GLC.
Unpublished
study
prepared
by
Great
Lakes
Chemical
Corporation.
56
p.
24
43257101
Severs,
L.
(
1994)
Determination
of
Methyl
Bromide
Solubility
in
Petroleum­
Based
Solvents:
Final
Report:
Lab
Project
Number:
WILL­
49012.
Unpublished
study
prepared
by
WILL
Research
Labs.,
Inc.
49
p.

43588301
Daigle,
C.
(
1995)
Methyl
Bromide
Technical
­
Product
Chemistry.
Unpublished
study
prepared
by
Albemarle
Corp.
33
p.

43588302
Daigle,
C.
(
1995)
Methyl
Bromide
Technical
­
Product
Chemistry.
Unpublished
study
prepared
by
Albemarle
Corp.
3
p.

44004101
Albemarle
Corp.
(
1996)
M­
B­
R
98
Technical
­
Product
Chemistry:
(
Product
Identity
and
Composition).
Unpublished
study.
35
p.

44004102
Albemarle
Corp.
(
1996)
M­
B­
R
98
Technical
­
Product
Chemistry:
(
Analysis
and
Certification
of
Ingredients):
Lab
Project
Number:
BR726:
95.
Unpublished
study.
60
p.

44043101
Ter
Haar,
G.
(
1996)
M­
B­
R
98
Technical
­
Product
Chemistry:
(
Physical
and
Chemical
Characteristics):
Lab
Project
Number:
36MS001.187.01.
Unpublished
study
prepared
by
Albemarle
Corp.
4
p.

44230001
Howland,
M.
(
1997)
Product
Chemistry
Data.
for
67­
33:
Update
(
to
the
Manufacturing
Process).
Unpublished
study
prepared
by
Great
Lakes
Chemical
Corp.
8
p.

45080201
Card,
S.
(
2000)
Product
Chemistry­
Beginning
Materials,
Preliminary
Analysis
of
Methyl
Bromide
Technical.
Unpublished
study
prepared
by
Albemarle
Corp.
18
p.
{
OPPTS
830.1550,
830.1600,
830.1670,
830.1700,
830.1750}
METHYL
BROMIDE
REREGISTRATION
ELIGIBILITY
DECISION
RESIDUE
CHEMISTRY
CONSIDERATIONS
PC
Code
053201;
Case
No.
0335
DP
Barcode
D271583
TABLE
OF
CONTENTS
page
INTRODUCTION
.
.
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1
REGULATORY
BACKGROUND
.
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1
SUMMARY
OF
SCIENCE
FINDINGS
.
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2
OPPTS
GLN
860.1200:
Directions
for
Use
.
.
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2
OPPTS
GLN
860.1300:
Nature
of
the
Residue
in
Plants
.
.
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2
OPPTS
GLN
860.1300:
Nature
of
the
Residue
in
Livestock
.
.
.
.
.
.
.
.
.
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.
.
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.
3
OPPTS
GLN
860.1340:
Residue
Analytical
Methods
.
.
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3
OPPTS
GLN
860.1360:
Multiresidue
Method
Testing
.
.
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3
OPPTS
GLN
860.1380:
Storage
Stability
Data
.
.
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3
OPPTS
GLN
860.1500:
Magnitude
of
the
Residue
in
Crop
Plants
.
.
.
.
.
.
.
.
.
.
.
.
.
.
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.
.
4
OPPTS
GLN
860.1520:
Magnitude
of
the
Residue
in
Processed
Food/
Feed
.
.
.
.
.
.
.
.
.
.
.
.
4
OPPTS
GLN
860.1480:
Magnitude
of
the
Residue
in
Meat,
Milk,
Poultry,
and
Eggs
.
.
.
.
.
4
OPPTS
GLN
860.1400:
Magnitude
of
the
Residue
in
Water,
Fish,
Irrigated
Crops
.
.
.
.
.
.
.
4
OPPTS
GLN
860.1460:
Magnitude
of
the
Residue
in
Food­
handling
Establishments
.
.
.
.
.
.
4
OPPTS
GLN
860.1850
and
1900:
Rotational
Crops
.
.
.
.
.
.
.
.
.
.
.
.
.
.
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.
5
TOLERANCE
REASSESSMENT
SUMMARY
.
.
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21
DIETARY
EXPOSURE
ASSESSMENT
SUMMARY
.
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30
CODEX
HARMONIZATION
.
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30
AGENCY
MEMORANDA
.
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30
RESIDUE
CHEMISTRY
CITATIONS
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33
H
H
H
Br
METHYL
BROMIDE
REREGISTRATION
ELIGIBILITY
DOCUMENT
RESIDUE
CHEMISTRY
CONSIDERATIONS
PC
Code
053201;
Case
0335
DP
Barcode
D271583
INTRODUCTION
Methyl
bromide
is
an
insecticide
and
antimicrobial
pesticide
registered
for
pre­
plant
soil
fumigation
and
post­
harvest
fumigation
of
numerous
raw
agricultural
commodities
and
processed
foods
and
feeds.
Methyl
bromide
is
registered
by
members
of
the
Methyl
Bromide
Industry
Panel
(
MBIP),
which
includes
Ameribrom,
Inc.,
Albemarle
Corp.,
Great
Lakes
Chemical
Co.,
and
Tri­
Cal,
Inc.
Pressurized
gas
(
PrG)
formulations
for
commodity
fumigation
are
marketed
under
the
trade
names
Meth­
O­
Gas
and
Metabrom.

REGULATORY
BACKGROUND
Methyl
bromide
is
a
List
A
reregistration
chemical.
It
was
the
subject
of
a
Registration
Standard
issued
3/
28/
86,
a
Guidance
Document
issued
8/
86,
and
a
Registration
Standard
Update
issued
6/
21/
91.
These
documents
summarized
the
regulatory
conclusions
on
the
available
residue
chemistry
data
and
specified
that
additional
data
were
required
for
reregistration
purposes.
Several
submissions
of
data
have
been
received
since
the
Registration
Standard
Update
was
issued.
The
information
contained
in
this
document
outlines
the
current
Residue
Chemistry
Science
Assessments
with
respect
to
the
reregistration
of
methyl
bromide.

Tolerances
for
residues
of
inorganic
bromides
in/
on
plant
raw
agricultural
commodities
(
RACs)
and
processed
foods
and
feeds
that
have
been
fumigated
with
methyl
bromide
have
been
established
under
40
CFR
§
180.123.
Tolerances
for
residues
of
inorganic
bromides
in/
on
plant
RACs
grown
in
soil
fumigated
with
combinations
of
chloropicrin,
methyl
bromide,
and
propargyl
bromide
have
been
established
under
40
CFR
§
180.199.

The
EPA
has
determined
that
soil
fumigation
uses
of
methyl
bromide
are
classified
as
non­
food
uses
(
S.
Irene,
1/
31/
97).
The
Agency
has
also
approved
the
replacement
of
inorganic
bromide
tolerances
with
tolerances
for
methyl
bromide
per
se,
as
supported
by
residue
chemistry
data
(
Letter
to
MBIP,
A.
Lindsay,
7/
7/
89).
Subsequently,
in
conjunction
with
acceptance
of
plant
metabolism
data,
HED
recommended
that
methyl
bromide
per
se
is
the
residue
to
be
regulated
(
DP
Barcode
D168913,
R.
Perfetti,
9/
24/
91).
2
The
Food
Quality
Protection
Act
(
FQPA)
of
1996
has
amended
and
strengthened
the
standard
for
establishing
tolerances
under
the
Federal
Food,
Drug,
and
Cosmetic
Act
(
FFDCA).
All
future
tolerance
petitions
as
well
as
reassessment
of
established
tolerances
must
meet
the
requirements
of
the
FFDCA
as
amended
by
the
FQPA.
OPP
may
require
additional
data
to
determine
if
the
terms
of
the
amended
statute
are
met.

SUMMARY
OF
SCIENCE
FINDINGS
OPPTS
GLN
860.1200:
Directions
for
Use
A
search
of
the
Agency's
Reference
Files
System
(
REFS)
on
2/
1/
01
indicated
that
there
are
five
methyl
bromide
end­
use
products
(
EPs)
with
post­
harvest
uses
on
food/
feed
commodities
registered
to
members
of
the
MBIP.
These
EPs
are
presented
below.

Methyl
bromide
End­
Use
Products
with
Food/
Feed
Uses
Registered
to
Members
of
the
MBIP.

EPA
Reg
No.
Label
Acceptance
Date
Formulation
Class
Product
Name
5785­
11
6/
6/
97
100%
PrG
Meth­
O­
Gas
100
5785­
41
11/
4/
94
100%
PrG
Meth­
O­
Gas
Q
8622­
5
8/
96
99.7%
PrG
Ameribrom
Methyl
Bromide
Grain
Fumigant
8622­
16
8/
19/
99
100%
PrG
Metabrom
100
8622­
55
8/
19/
99
100%
PrG
Metabrom
Q
A
comprehensive
summary
of
the
registered
food/
feed
use
patterns
of
methyl
bromide,
based
on
the
product
labels
currently
registered
to
the
MBIP,
is
presented
in
Tables
A1
and
A2.
These
tables
also
indicate
any
recommended
label
changes,
such
removing
use
directions
for
commodities
that
are
no
longer
being
supported,
and
revising
exposure
rates
and
times
to
be
consistent
with
the
exposures
reflected
in
the
supporting
residue
data.
A
tabular
summary
of
the
residue
chemistry
science
assessments
for
reregistration
of
methyl
bromide
is
presented
in
Table
B.
The
conclusions
listed
in
Table
B
regarding
the
reregistration
eligibility
of
methyl
bromide
food/
feed
uses
are
based
on
the
use
patterns
registered
by
members
of
the
MBIP.
When
end­
use
product
DCIs
are
developed
(
e.
g.,
at
issuance
of
the
RED),
RD
should
require
that
all
end­
use
product
labels
(
e.
g.,
MAI
labels,
SLNs,
and
products
subject
to
the
generic
data
exemption)
be
amended
such
that
they
are
consistent
with
the
basic
producers'
labels.

OPPTS
GLN
860.1300:
Nature
of
the
Residue
in
Plants
The
qualitative
nature
of
the
residue
in
plants
is
adequately
understood,
based
on
studies
in
which
the
commodities
maize,
potato,
alfalfa,
peanuts,
almonds,
oatmeal,
apples,
oranges,
and
wheat
were
fumigated
with
radioactive
methyl
bromide
at
a
rate
equivalent
to
~
2x
the
registered
rate.
Residues
consisted
of
methyl
bromide
and
naturally
occurring
compounds
such
as
methylated
amino
acids
and
nucleotides.
The
residue
of
concern
is
methyl
bromide
per
se.

HED
has
determined
that
the
pre­
plant
soil
fumigation
use
is
a
non­
food
use.
Treated
soil
must
3
be
fumigated
for
a
minimum
of
two
weeks
to
allow
sufficient
dissipation
of
residues;
excessive
residues
of
methyl
bromide
per
se
would
be
phytotoxic.
Minimal
methyl
bromide
residues
are
available
for
uptake
by
the
plant
at
the
end
of
the
soil
aeration
period.
Considering
the
highly
reactive
nature
of
methyl
bromide,
any
residues
taken
up
by
the
plant
would
be
converted
to
natural
constituents
by
the
time
of
plant
harvest.
Therefore,
tolerances
are
not
needed
to
support
the
pre­
plant
fumigation
use
of
methyl
bromide.

OPPTS
GLN
860.1300:
Nature
of
the
Residue
in
Livestock
Animal
metabolism
data
are
not
required
for
methyl
bromide.
Potential
feed
items
with
registered
post­
harvest
or
storage
fumigation
uses
include
stored
grain,
soybeans,
and
processed
animal
feeds.
The
maximum
tolerance
for
residues
in
any
of
these
is
10
ppm,
based
on
residues
24
hours
after
the
aeration
period
that
follows
fumigation.
The
transfer
of
detectable
residues
from
feed
items
to
meat,
milk
or
eggs,
is
not
expected,
and
is
a
Category
(
3)
situation
under
40
CFR
§
180.6(
a).

OPPTS
GLN
860.1340:
Residue
Analytical
Methods
The
head­
space
procedure
of
King
et
al.
for
determining
methyl
bromide
has
been
forwarded
to
FDA
for
inclusion
in
PAM
Vol.
II.
This
method
is
adequate
for
data
collection
and
would
be
suitable
for
tolerance
enforcement
on
plant
and
processed
food
commodities.
Analytical
methods
for
secondary
residues
of
methyl
bromide
in
livestock
commodities
are
not
required.

OPPTS
GLN
860.1360:
Multiresidue
Method
Testing
FDA
multiresidue
test
methods
are
not
applicable
to
methyl
bromide.
Protocols
A
and
B
are
not
applicable
to
monohalogenated
alkanes.
Although
methyl
bromide
would
be
detectable
in
protocol
C,
residues
would
like
not
be
recovered
through
any
of
the
extraction
techniques.

OPPTS
GLN
860.1380:
Storage
Stability
Data
Methyl
bromide
residues
decline
rapidly,
e.
g.,
30%
in
rice
stored
in
dry
ice
for
40
hours.
For
the
commodity
fumigation
residue
trials,
the
registrants
agreed
to
place
residue
samples
in
impermeable
containers
at
<
3.7
C
as
soon
as
possible.
HED
has
determined
that
storage
stability
data
are
not
required
unless
samples
are
or
have
been
stored
for
longer
than
12
hours.
Most
of
the
residue
data
used
to
reassess
tolerances
were
generated
from
samples
stored
for
12
hours
or
less.
For
some
samples
stored
for
longer
intervals,
results
were
compared
with
initial
analyses
obtained
after
shorter
periods;
the
results
were
comparable.
Therefore,
there
are
no
unresolved
storage
stability
issues
related
to
samples
used
for
tolerance
reassessment.
4
OPPTS
GLN
860.1500:
Magnitude
of
the
Residue
in
Crop
Plants
Provided
that
the
specified
amendments
are
made
in
label
use
directions,
the
requirements
for
magnitude
of
the
residue
data
in/
on
plants
are
fulfilled
for
the
crop
groups
covering
commodities
labeled
for
methyl
bromide
post­
harvest
fumigation.
Adequate
data
are
available
for
carrots,
potatoes,
radishes,
sugar
beets,
turnips,
garlic,
onions
(
bulb
and
green),
celery,
lettuce
(
head
and
leaf),
spinach,
broccoli,
cabbage,
cauliflower,
beans
(
dried
and
succulent),
peas
(
dried
and
succulent),
soybeans,
peppers,
tomatoes
(
field
and
greenhouse),
cantaloupes,
cucumbers,
summer
squash,
grapefruit,
lemons,
oranges,
apples,
pears,
cherries,
peaches,
plums,
blackberries,
almonds,
pecans,
pistachios,
walnuts,
corn
(
field
and
sweet),
rice,
sorghum,
wheat,
asparagus,
blueberries,
grapes,
kiwi
fruit,
pineapple,
and
strawberries.

The
MBIP
does
not
intend
to
support
post­
harvest
fumigation
uses
of
methyl
bromide
on
alfalfa,
avocados,
coffee,
copra,
cottonseed,
mangoes,
okra,
papayas,
peanuts,
pomegranates,
or
timothy
(
DP
Barcode
D197531,
R.
Perfetti,
1/
10/
94).

OPPTS
GLN
860.1520:
Magnitude
of
the
Residue
in
Processed
Food/
Feed
The
reregistration
requirements
for
magnitude
of
the
residue
in
processed
food/
feed
commodities
are
fulfilled
for
apples,
grapes,
tomatoes,
citrus,
corn,
wheat,
and
rice.
The
available
processing
studies
indicate
that
methyl
bromide
residues
do
not
concentrate
in
any
processed
commodity.

OPPTS
GLN
860.1480:
Magnitude
of
the
Residue
in
Meat,
Milk,
Poultry,
and
Eggs
Residues
of
for
methyl
bromide
are
not
expected
in
meat,
milk,
poultry,
and
eggs
when
livestock
are
fed
raw
agricultural
commodities
treated
with
methyl
bromide.
Therefore,
tolerances
for
residues
in
livestock
commodities
are
not
needed.
Reisudes
in
some
processed
foods
derived
from
animal
products
(
e.
g.
dried
eggs,
cheeses,
and
cured
meats)
are
regulated
by
the
tolerance
for
processed
foods.

OPPTS
GLN
860.1400:
Magnitude
of
the
Residue
in
Water,
Fish,
Irrigated
Crops
As
there
are
no
aquatic
uses
of
methyl
bromide,
this
guideline
is
not
applicable.

OPPTS
GLN
860.1460:
Magnitude
of
the
Residue
in
Food­
handling
Establishments
Data
requirements
are
fulfilled
for
processed
foods
that
are
fumigated
with
methyl
bromide.
Adequate
data
are
available
on
dried
herbs
and
spices,
flour,
corn
meal,
rolled
oats,
cake
mix,
Parmesan
cheese,
dried
eggs,
chocolate
chips,
cocoa
butter,
chocolate
liquor,
instant
white
rice,
shelled
roasted
peanuts,
unpopped
popcorn,
and
country
ham.
These
data
are
also
sufficient
to
cover
residues
in
stored
animal
feeds.
5
OPPTS
GLN
860.1850
and
1900:
Rotational
Crops
These
guidelines
are
not
applicable
to
methyl
bromide.
The
agricultural
uses
of
methyl
bromide
are
non­
food
uses;
therefore,
residues
in
rotational
crops
are
also
not
of
concern.
6
continued,
footnotes
follow
Table
A1.
Post­
harvest
uses
of
methyl
bromide
on
raw
agricultural
commodities
registered
to
members
of
the
Methyl
Bromide
Industry
Panel
(
MBIP).
a
Commodity
Maximum
Dosage
(
lb
ai/
1000
ft3)
Maximum
Exposure
time
(
hours)
Recommended
label
revisions
b
Alfalfa,
hay
3
24
Remove
from
labels;
the
MBIP
is
not
supporting
this
use.

Almonds
3.5
24
Apples
5
2
Apricots
5
2
Artichokes,
Jerusalem
3.5
4
Asparagus
4
2
The
available
data
support
a
maximum
rate
of
3.5
lb
ai/
1000
ft3
for
2
hours
Barley
9
24
The
available
data
support
a
maximum
dose
of
3
lb
ai/
1000
ft3
for
24
hours.

Beans
(
all)
4
24
The
available
data
support
a
maximum
rate
of
4
lb
ai/
1000
ft3
for
2
hours
for
succulent
beans
and
for
24
hours
for
dried
beans.
Beans
(
dried)
4
24
Beets
(
roots)
3
4
Blackberries
None
None
The
available
data
would
support
a
maximum
dose
of
3
lb
ai/
1000
ft3
for
4
hours.

Blueberries
2
4
Brazil
nuts
3.5
24
Broccoli
None
None
The
available
data
would
support
a
maximum
dose
of
4
lb
ai/
1000
ft3
for
2
hours.

Bushnuts
3.5
24
Butternuts
3.5
24
Cabbage
4
4
Cantaloupes
4
2
The
available
data
support
a
maximum
dose
of
2.5
lb
ai/
1000
ft3
for
2
hours.

Carrots
4
4
Cashews
3.5
24
Cauliflower
None
None
The
available
data
would
support
a
maximum
rate
of
4
lb
ai/
10000
ft3
for
2
hours
Cherries
5
2
Chestnuts
3.5
24
Chestnuts
(
vacuum)
6
6
Table
A1.
Continued.

Commodity
Maximum
Dosage
(
lb
ai/
1000
ft3)
Maximum
Exposure
time
(
hours)
Recommended
label
revisions
b
7
continued,
footnotes
follow
Cippolini
bulbs
4
4
The
available
data
support
a
maximum
dose
of
3
lb
ai/
1000
ft3
for
6
hours.

Citron
c
3
2
Directions
should
be
clarified
to
indicate
the
use
is
on
the
citrus
fruit,
citron.

Cocoa
beans
2
24
The
available
data
support
a
maximum
of
two
applications
at
1.5
lb
ai/
1000
ft3
each
for
24
hours
with
a
minimum
retreatment
interval
of
12
days.

Cocoa
beans
(
vacuum)
1.5
12
Coffee
beans
3
24
Remove
from
labels;
the
MBIP
is
not
supporting
uses
on
coffee
beans
or
copra.
Copra
3.5
24
Corn
9
24
The
available
data
support
a
maximum
dose
of
4
lb
ai/
1000
ft3
for
24
hours.
Corn,
pop
(
vacuum)
9
3
Corn,
sweet
3
4
Cottonseed
8
24
Remove
from
labels;
MBIP
is
not
supporting
this
use.

Cucumbers
4
4
The
available
data
support
a
maximum
rate
of
2
lb
ai/
1000
ft3
for
4
hours
Eggplant
3
4
Filberts
3.5
24
Garlic
3
4
The
available
data
support
a
maximum
rate
of
2.5
lb
ai/
1000
ft3
for
4
hours
Grapefruit
3
2
Grapes
4
4
The
available
data
support
a
maximum
dose
of
4
lb
ai/
1000
ft3
for
2
hours.

Hickory
nuts
3.5
24
Honeydew
melons
4
2
The
available
data
support
a
maximum
dose
of
2.5
lb
ai/
1000
ft3
for
2
hours.

Horseradish
3
4
Kiwi
fruit
None
None
The
available
data
would
support
a
maximum
dose
of
4
lb
ai/
1000
ft3
for
3
hours.

Kumquats
3
2
Leafy
vegetables
None
None
The
available
data
would
support
a
maximum
rate
of
4
lb
ai/
1000
ft3
for
2
hours
Lemons
3
2
Table
A1.
Continued.

Commodity
Maximum
Dosage
(
lb
ai/
1000
ft3)
Maximum
Exposure
time
(
hours)
Recommended
label
revisions
b
8
continued,
footnotes
follow
Limes
3
2
Macadamia
nuts
3.5
24
Muskmelons
4
2
The
available
data
support
a
maximum
dose
of
2.5
lb
ai/
1000
ft3
for
2
hours.

Nectarines
5
2
Oats
3
24
Okra
3.5
2
Remove
from
labels;
MBIP
is
not
supporting
this
use.

Onions
3
6
Oranges
3
2
Parsnips
3
4
Peaches
5
2
Peanuts
3.5
24
Remove
from
labels;
MBIP
is
not
supporting
this
use.

Pears
5
2
Peas
(
with
pods)
3
2
Peas
(
dried)
4
24
Pecans
3.5
24
Peppers
4
2
Pimentos
2.5
3
Pineapples
6
6
The
available
residue
data
support
a
maximum
dose
of
4
lb
ai/
1000
ft3
for
2
hours
Pistachios
3.5
24
Plums
5
2
Potatoes
3
6
Pumpkins
2.5
2
Quinces
5
2
Radishes
3
4
The
available
data
support
a
maximum
dose
of
3
lb
ai/
1000
ft3
for
4
hours.

Rice
9
24
The
available
data
support
a
maximum
rate
of
3
lb
ai/
1000
ft3
for
24
hours.

Rutabagas
3
6
Rye
9
24
The
available
data
support
a
maximum
rate
of
3
lb
ai/
1000
ft3
for
24
hours.

Salsify
roots
3
3
Table
A1.
Continued.

Commodity
Maximum
Dosage
(
lb
ai/
1000
ft3)
Maximum
Exposure
time
(
hours)
Recommended
label
revisions
b
9
Sorghum
(
grain)
9
24
The
available
data
support
a
maximum
rate
of
4
lb
ai/
1000
ft3
for
24
hours.

Squash
(
summer)
4
2
The
available
data
support
a
maximum
rate
of
3
lb
ai/
1000
ft3
for
2
hours.

Squash
(
winter)
4
2
The
available
cantaloupe
data
support
a
maximum
rate
of
2.5
lb
ai/
1000
ft3
for
2
hours.

Squash,
zucchini
2.5
3
The
available
data
support
a
maximum
rate
of
3
lb
ai/
1000
ft3
for
2
hours.

Strawberries
3
4
Sugar
beets
(
roots)
3
4
The
available
data
support
a
maximum
rate
of
3
lb
ai/
1000
ft3
for
2
hours.

Sweet
potatoes
4
4.5
The
available
data
support
a
maximum
rate
of
4
lb
ai/
1000
ft3
for
4
hours.

Tangelos
3
2
Tangerines
3
2
Tomatoes
3
4
Turnips
(
roots)
3
4
Walnuts
3.5
24
Watermelons
4
2
The
available
data
support
a
maximum
dose
of
2.5
lb
ai/
1000
ft3
for
2
hours.

Wheat
3
24
Yams
4
4.5
The
available
data
support
a
maximum
dose
of
4
lb
ai/
1000
ft3
for
4
hours.

a
The
maximum
rate
and
duration
of
exposure
are
based
on
use
directions
on
one
or
more
of
the
following
labels,
registered
to
members
of
the
MBIP
for
post­
harvest
applications:
EPA
Reg.
Nos.
5785­
11
(
dated
6/
97),
5785­
41
(
dated
11/
94),
8622­
5
(
dated
1/
92),
8622­
16
(
dated
8/
99),
and
8622­
55
(
dated
8/
99).
The
labels
do
not
specify
a
maximum
number
of
applications
and
the
minimum
intervals
between
applications.
Treated
areas
must
be
aerated
until
methyl
bromide
concentration
is
#
5
ppm.
b
Post­
harvest
fumigation
uses
that
the
MBIP
is
not
supporting
are
listed
in
DP
Barcode
D197531,
R.
Perfetti,
1/
10/
94.
c
Based
upon
the
use
rate,
the
use
on
citron
is
assumed
to
be
on
the
citrus
fruit
and
not
on
citron
melons.
10
Table
A2.
Food/
feed
uses
of
methyl
bromide
registered
to
members
of
the
MBIP
on
processed
commodities.

Commodity/
structure
Maximum
Dosage
(
lb
ai/
1000
ft3)
Max.
Exposure
time
(
hours)
Recommended
label
rate
changes,
supported
by
residue
data
Chocolate
products
(
e.
g.
cocoa
butter,
chocolate
chips,
and
chocolate
liquor)
None
None
The
available
data
support
a
maximum
rate
of
1.5
lb
ai/
1000
ft3
for
24
hours
Dried
fruits
(
e.
g.,
apples,
apricots,
cherries,
dates,
peaches,
prunes,
raisins)
2
24
The
available
data
support
a
maximum
rate
of
1.5
lb
ai/
1000
ft3
for
24
hours.

Figs
(
dried)
2
24
Cheese
(
e.
g.,
Parmesan
and
Roquefort)
2
24
The
available
data
support
a
maximum
rate
of
3
lb
ai/
1000
ft3
for
24
hours.
Eggs
(
dried)
2
24
Hams
and
cured
meats
2
24
Processed
foods
2
48
Processed
grain
2
24
Prunes
5
2
The
available
data
support
a
maximum
rate
of
1.5
lb
ai/
1000
ft3
for
24
hours.

Spices
and
herbs
(
dried)
3
24
The
available
data
support
a
maximum
of
two
applications
each
at
3.5
lb
ai/
1000
ft3
for
12
hours
with
a
minimum
retreatment
interval
of
24
hours.

Animal
feed
(
e.
g.,
pet
food)
2
24
Premise
treatment
Warehouses,
grain
elevators,
grain
bins,
poultry
houses,
restaurants,
food
processing
plants
9
72
a
The
maximum
rate
and
duration
of
exposure
are
based
on
use
directions
on
one
or
more
of
the
following
labels,
registered
to
members
of
the
MBIP
for
post­
harvest
applications:
EPA
Reg.
Nos.
5785­
11
(
dated
6/
97),
5785­
41
(
dated
11/
94),
8622­
5
(
dated
1/
92),
8622­
16
(
dated
8/
99),
and
8622­
55
(
dated
8/
99).
The
labels
do
not
specify
a
maximum
number
of
applications
and
the
minimum
intervals
between
applications.
Treated
areas
must
be
aerated
until
methyl
bromide
concentration
is
#
5
ppm.
(
continued;
footnotes
follow)
11
Table
B.
Residue
Chemistry
Science
Assessments
for
Reregistration
of
Methyl
Bromide.

GLN:
Data
Requirements
Current
Tolerances,
ppm
[
40
CFR]
Must
Additional
Data
Be
Submitted?
References
1
860.1200:
Directions
for
Use
N/
A
Yes2
See
Table
A.

860.1300:
Plant
Metabolism
N/
A
No
00065237
00079550
416277013
421377014
860.1300:
Animal
Metabolism
N/
A
No
860.1340:
Residue
Analytical
Methods
­
Plant
commodities
N/
A
No
00026180
00043601
00079041
00112926
00118768
00118838
00149535
00152907
00153317
00160629
40579501
40607801
­
Animal
commodities
N/
A
No
860.1360:
Multiresidue
Methods
N/
A
N/
A
860.1380:
Storage
Stability
Data
N/
A
No
00153317
40618501
860.1500:
Crop
Field
Trials
Root
and
Tuber
Vegetables
Group
00088683
00089457
00090408
00119550
00152907
00153317
­
Carrots
30.0
[
§
180.123(
a)(
1)]
No
429496015
­
Jerusalem
artichokes
30.0
[
§
180.123(
a)(
1)]
No
­
Ginger
roots
100
[
§
180.123(
c)(
1)]
100
[
§
180.199(
c)]
No
00090408
00119550
409264016
409265016
­
Horseradish
30.0
[
§
180.123(
a)(
1)]
No
­
Parsnip
roots
30.0
[
§
180.123(
a)(
1)]
No
­
Potatoes
30.0
[
§
180.123(
a)(
1)]
No
429496015
­
Radishes
30.0
[
§
180.123(
a)(
1)]
No
429496015
­
Rutabagas
30.0
[
§
180.123(
a)(
1)]
No
Table
B.
(
continued).

GLN:
Data
Requirements
Current
Tolerances,
ppm
[
40
CFR]
Must
Additional
Data
Be
Submitted?
References
1
(
continued;
footnotes
follow)
12
­
Salsify
roots
30.0
[
§
180.123(
a)(
1)]
No
­
Sugar
beet
roots
No
429496015
­
Sweet
potatoes
30.0
[
§
180.123(
a)(
1)]
No
­
Turnips,
roots
30.0
[
§
180.123(
a)(
1)]
No
429496015
Leaves
of
Root
and
Tuber
Vegetables
Group
­
Sugar
beet
tops
No
Bulb
Vegetables
Group
00079043
00088683
00089457
00152907
00153317
­
Cippolini
50.0
[
§
180.123(
a)(
1)]
No
­
Garlic
50.0
[
§
180.123(
a)(
1)]
No
429496015
­
Onions
20.0
[
§
180.123(
a)(
1)]
300
(
dry
bulb)
[
§
180.199(
b)]
No
429496015
Leafy
Vegetables
(
Except
Brassica)
Group
00079048
00152907
00157445
­
Celery
None
No
429496015
­
Lettuce
300
[
§
180.199(
b)]
No
429496015
­
Spinach
None
No
429496015
Brassica
Leafy
Vegetables
Group
00013057
00140445
00152907
00153317
00157445
­
Broccoli
25
[
§
180.199(
a)]
No
429496015
­
Cauliflower
25
[
§
180.199(
a)]
No
429496015
­
Cabbage
50.0
[
§
180.123(
a)(
1)]
No
429496015
Table
B.
(
continued).

GLN:
Data
Requirements
Current
Tolerances,
ppm
[
40
CFR]
Must
Additional
Data
Be
Submitted?
References
1
(
continued;
footnotes
follow)
13
Legume
Vegetables
Group
00088683
00089457
00118817
00127221
00152907
00153317
­
Beans
50.0
[
§
180.123(
a)(
1)]
No
429496015
­
Beans,
green
50.0
[
§
180.123(
a)(
1)]
No
429496015
­
Beans,
lima
50.0
[
§
180.123(
a)(
1)]
No
429496015
­
Beans,
snap
50.0
[
§
180.123(
a)(
1)]
No
429496015
­
Peas
50.0
[
§
180.123(
a)(
1)]
No
429496015
­
Peas,
black­
eyed
50.0
[
§
180.123(
a)(
1)]
No
­
Soybeans
200.0
[
§
180.123(
a)(
1)]
No
429496015
Fruiting
Vegetables
(
Except
Cucurbits)
Group
00013000
00013057
00088683
00089457
00118837
00135683
00152907
00153317
­
Eggplant
20.0
[
§
180.123(
a)(
1)]
60
[
§
180.199(
a)]
No
­
Peppers
30.0
[
§
180.123(
a)(
1)]
25
[
§
180.199(
a)]
No
429496015
­
Pimentos
30.0
[
§
180.123(
a)(
1)]
No
­
Tomatoes
20.0
[
§
180.123(
a)(
1)]
40
[
§
180.199(
a)]
No
429496015
Cucurbit
Vegetables
Group
00013057
00089457
00152907
00153317
­
Cantaloupes
20.0
[
§
180.123(
a)(
1)]
No
429496015
Table
B.
(
continued).

GLN:
Data
Requirements
Current
Tolerances,
ppm
[
40
CFR]
Must
Additional
Data
Be
Submitted?
References
1
(
continued;
footnotes
follow)
14
­
Cucumbers
30.0
[
§
180.123(
a)(
1)]
No
429496015
­
Honeydew
melons
20.0
[
§
180.123(
a)(
1)]
No
­
Muskmelon
20.0
[
§
180.123(
a)(
1)]
40
[
§
180.199(
a)]
No
­
Pumpkins
20.0
[
§
180.123(
a)(
1)]
No
­
Squash,
summer
30.0
[
§
180.123(
a)(
1)]
No
429496015
­
Squash,
winter
20.0
[
§
180.123(
a)(
1)]
No
­
Squash,
zucchini
20.0
[
§
180.123(
a)(
1)]
No
­
Watermelon
20.0
[
§
180.123(
a)(
1)]
No
Citrus
Fruits
Group
10.0
[
§
180.242(
a)]
No
00066267
00089457
00153317
­
Citrus
citron
30.0
[
§
180.123(
a)(
1)]
No
­
Grapefruit
30.0
[
§
180.123(
a)(
1)]
No
429496015
­
Kumquats
30.0
[
§
180.123(
a)(
1)]
No
­
Lemons
30.0
[
§
180.123(
a)(
1)]
No
430258017
­
Limes
30.0
[
§
180.123(
a)(
1)]
No
­
Oranges
30.0
[
§
180.123(
a)(
1)]
No
429496015
­
Tangerines
30.0
[
§
180.123(
a)(
1)]
No
Pome
Fruits
Group
00088683
00118837
00153317
00160628
­
Apples
5.0
[
§
180.123(
a)(
1)]
No
429496015
Table
B.
(
continued).

GLN:
Data
Requirements
Current
Tolerances,
ppm
[
40
CFR]
Must
Additional
Data
Be
Submitted?
References
1
(
continued;
footnotes
follow)
15
­
Pears
5.0
[
§
180.123(
a)(
1)]
No
429496015
­
Quinces
5.0
[
§
180.123(
a)(
1)]
No
Stone
Fruits
Group
00089457
00149535
00153317
00160628
­
Apricots
20.0
[
§
180.123(
a)(
1)]
No
­
Cherries
20.0
[
§
180.123(
a)(
1)]
No
429496015
­
Nectarines
20.0
[
§
180.123(
a)(
1)]
No
430258017
­
Peaches
20.0
[
§
180.123(
a)(
1)]
No
429496015
430258017
­
Plums
20.0
[
§
180.123(
a)(
1)]
No
429496015
430258017
Small
Fruits
and
Berries
Group
429496015
­
Blueberries
20.0
[
§
180.123(
a)(
1)]
No
00089457
00127767
00149535
00152907
00153317
429496015
Tree
Nuts
Group
00088683
00118821
00119256
00149535
00153317
­
Almonds
200.0
[
§
180.123(
a)(
1)]
No
438850018
­
Brazil
nuts
200.0
[
§
180.123(
a)(
1)]
No
­
Bush
nuts
200.0
[
§
180.123(
a)(
1)]
No
­
Butternuts
200.0
[
§
180.123(
a)(
1)]
No
­
Cashews
200.0
[
§
180.123(
a)(
1)]
No
­
Chestnuts
200.0
[
§
180.123(
a)(
1)]
No
­
Filberts
200.0
[
§
180.123(
a)(
1)]
No
Table
B.
(
continued).

GLN:
Data
Requirements
Current
Tolerances,
ppm
[
40
CFR]
Must
Additional
Data
Be
Submitted?
References
1
(
continued;
footnotes
follow)
16
­
Hickory
nuts
200.0
[
§
180.123(
a)(
1)]
No
­
Pecans
200.0
[
§
180.123(
a)(
1)]
No
438850018
­
Pistachio
nuts
200.0
[
§
180.123(
a)(
1)]
No
438850018
­
Walnuts
200.0
[
§
180.123(
a)(
1)]
No
438850018
Cereal
Grains
Group
00088683
00089457
00090269
00109713
00118817
00118820
00118838
00149535
00153317
­
Barley
50.0
[
§
180.123(
a)(
1)]
No
­
Corn
50.0
[
§
180.123(
a)(
1)]
No
429496015
­
Corn,
pop
240.0
[
§
180.123(
a)(
1)]
No
­
Corn,
sweet
50.0
[
§
180.123(
a)(
1)]
No
429496015
­
Oats
50.0
[
§
180.123(
a)(
1)]
No
­
Rice
50.0
[
§
180.123(
a)(
1)]
No
429496015
­
Rye
50.0
[
§
180.123(
a)(
1)]
No
­
Sorghum
50.0
[
§
180.123(
a)(
1)]
No
429496015
­
Wheat
50.0
[
§
180.123(
a)(
1)]
No
429496015
Grass
Forage
and
Hay
Group
­
Timothy,
hay
50.0
[
§
180.123(
a)(
1)]
No
Non­
grass
Animal
Feeds
Group
00088683
00118830
­
Alfalfa,
hay
50.0
[
§
180.123(
a)(
1)]
No
Table
B.
(
continued).

GLN:
Data
Requirements
Current
Tolerances,
ppm
[
40
CFR]
Must
Additional
Data
Be
Submitted?
References
1
(
continued;
footnotes
follow)
17
Herbs
and
Spices
Group
400
[
§
180.123(
a)(
2)(
i)(
A)]
No
00090408
00118838
00119550
00152907
00153317
00160627
430298017
Miscellaneous
Commodities
­
Artichokes
20.0
[
§
180.123(
a)(
1)]
No
­
Asparagus
100.0
[
§
180.123(
a)(
1)]
300
[
§
180.199(
b)]
No
00079048
00090147
429496015
­
Avocados
75.0
[
§
180.123(
a)(
1)]
No
00135683
­
Cocoa
50.0
[
§
180.123(
a)(
1)]
No
00088683
00153317
430257017
­
Coffee
75.0
[
§
180.123(
a)(
1)]
No
00090408
00119550
00153317
­
Copra
100.0
[
§
180.123(
a)(
1)]
No
00089457
00118838
­
Cottonseed
200.0
[
§
180.123(
a)(
1)]
No
00088638
­
Grapes
20.0
[
§
180.123(
a)(
1)]
No
00089457
00118829
00149535
00152907
00153317
429496015
430258017
­
Kiwi
fruit
None
No
429496015
­
Mangoes
20.0
[
§
180.123(
a)(
1)]
No
­
Okra
30.0
[
§
180.123(
a)(
1)]
00152907
­
Papayas
20.0
[
§
180.123(
a)(
1)]
No
­
Peanuts
200
[
§
180.123(
a)(
1)]
No
00088683
00089066
­
Pineapples
20.0
[
§
180.123(
a)(
1)]
300
[
§
180.199(
a)]
No
00012908
429496015
Table
B.
(
continued).

GLN:
Data
Requirements
Current
Tolerances,
ppm
[
40
CFR]
Must
Additional
Data
Be
Submitted?
References
1
18
­
Pomegranates
100.0
[
§
180.123(
a)(
1)]
No
­
Strawberries
60.0
[
§
180.123(
a)(
1)]
300
[
§
180.199(
a)]
No
00012999
00013057
00089457
00096432
00118845
00149535
00152907
00153317
429496015
­
Tobacco
NA
00153317
860.1520:
Processed
Food/
Feed
125
[
§
180.123(
a)(
2)(
i)(
D)]
00088683
00109713
00118817
00118837
00118838
00153317
­
Apple
wet
pomace,
juice
None
No
432787019
433434019
­
Citrus
pulp,
juice,
oil
No
432787019
­
Corn
grain
milled
fractions
No
429638015
­
Corn,
sweet,
cannery
waste
No
432870019
­
Grape
wet
pomace,
juice
No
432787019
433434019
­
Potato
No
­
Raisins
No
438850028
­
Rice,
hulls
No
430236017
­
Soybean,
meal,
oil
No
­
Tomato,
wet
pomace,
juice
No
432474019
­
Wheat,
milled
fractions
(
exc.
flour)
No
430253017
860.1480:
Meat,
Milk,
Poultry,
and
Eggs
None
No
860.1400:
Water,
Fish,
and
Irrigated
Crops
None
N/
A
860.1460:
Food
Handling
­
Dog
Food
400
[
§
180.123(
a)(
3)(
i)]
No
­
Dried
eggs
400
[
§
180.123(
a)(
2)(
i)(
A)]
No
430251017
430252017
Table
B.
(
continued).

GLN:
Data
Requirements
Current
Tolerances,
ppm
[
40
CFR]
Must
Additional
Data
Be
Submitted?
References
1
19
1.
References
were
reviewed
in
the
Methyl
Bromide
Guidance
Document
dated
8/
86.
Bolded
references
were
reviewed
in
the
Methyl
Bromide
Reregistration
Standard
Update
(
6/
21/
91).
Other
references
were
reviewed
as
noted.

2.
Based
upon
the
available
residue
data
and/
or
changes
in
data
requirements,
the
Agency
is
recommending
changes
to
use
directions.
The
recommended
label
amendments
are
listed
in
Tables
A1
and
A2.

3.
CBRS
No.
7101,
no
DP
Barcode,
R.
Perfetti,
3/
8/
91.

4.
DP
Barcode
D168913,
R.
Perfetti,
9/
24/
91.
­
Dried
figs
250
[
§
180.123(
a)(
2)(
i)(
C)]
No
438850028
­
Fermented
malt
beverages
25
[
§
180.123(
a)(
2)(
ii)]
25
[
§
180.123(
a)(
4)]
No
­
Grain
Milled
Fractions
125
[
§
180.123(
a)(
3)(
ii)]
125
[
§
180.521(
a)(
3)]
No
­
Parmesan
cheese
and
Roquefort
cheese
325
[
§
180.123(
a)(
2)(
i)(
B)]
No
430251017
430252017
­
Processed
grain
125
180.522(
a)(
1)
No
­
Processed
herbs
and
spices
400
[
§
180.123(
a)(
2)(
i)(
A)]
No
430298017
­
Tomato
products,
concentrated
250
[
§
180.123(
a)(
2)(
i)(
C)]
No
­
Processed
foods
125
[
§
180.123(
a)(
2)(
i)(
D)]
No
430251017
430252017
4362970110
860.1850:
Confined
Rotational
Crops
N/
A
NA
860.1900:
Field
Rotational
Crops
None
NA
Table
B
(
continued).

20
5.
DP
Barcodes
D196312
and
D196317,
R.
Perfetti,
4/
7/
94.
6.
CBTS
Nos.
4764
and
4766,
S.
Malak,
8/
22/
89.

7.
DP
Barcodes
D197515,
D197516,
D197517,
D197518,
D197519,
D197520,
D197528;
R.
Perfetti;
5/
6/
94.

8.
DP
Barcode
D275389,
C.
Olinger,
7/
17/
01.

9.
DP
Barcodes
D204238,
D205160,
D205462,
D206950;
R.
Perfetti;
11/
16/
94.

10.
DP
Barcode
D215044,
B.
Cropp­
Kohlligian,
8/
15/
95.
21
TOLERANCE
REASSESSMENT
SUMMARY
Tolerances
are
currently
established
for
residues
of
inorganic
bromides
(
calculated
as
Br)
in/
on
raw
and
processed
commodities
that
have
been
fumigated
with
the
antimicrobial
agent
and
insecticide
methyl
bromide
[
40
CFR
§
180.123].
The
Agency
has
approved
the
replacement
of
inorganic
bromide
tolerances
with
tolerances
for
methyl
bromide
per
se
as
supported
by
residue
chemistry
data
(
Letter
to
MBIP,
A.
Lindsay,
7/
7/
89).
In
conjunction
with
acceptance
of
plant
metabolism
data,
HED
subsequently
recommended
that
methyl
bromide
per
se
is
the
residue
to
be
regulated
(
DP
Barcode
D168913,
R.
Perfetti,
9/
24/
91).

The
reassessed
tolerances
under
40
CFR
§
180.123(
a)
should
be
defined
in
terms
of
residues
of
methyl
bromide
per
se
resulting
from
the
post­
harvest,
stored
commodity
fumigation
use
of
products
containing
methyl
bromide.
The
post­
harvest
designation
(
POST­
H)
following
each
commodity
listing
can
be
deleted.

Tolerances
have
also
been
established
for
residues
of
inorganic
bromides
(
calculated
as
Br)
in/
on
ginger
root
grown
in
soil
fumigated
with
methyl
bromide
[
40
CFR
§
180.123(
c)]
and
in
raw
agricultural
commodities
grown
in
soil
fumigated
with
chloropicrin,
methyl
bromide,
and
propargyl
bromide
[
40
CFR
§
180.199(
a­
c)].
The
Agency
has
determined
that
soil
fumigation
uses
are
classified
as
non­
food
uses
and
do
not
require
the
establishment
of
a
tolerance
or
exemption
from
a
tolerance
(
memorandum
to
S.
Johnson,
S.
Irene,
1/
31/
97).
Therefore,
the
tolerances
in
40
CFR
§
180.123(
c)
and
§
180.199(
a­
c)
should
be
revoked.

A
summary
of
the
methyl
bromide
tolerance
reassessment
for
the
above
commodities,
with
recommended
modifications
to
commodity
definitions,
is
presented
in
Table
C.

Tolerances
Listed
Under
40
CFR
§
180.123(
a)(
1):

Provided
that
the
requested
label
amendments
are
made,
sufficient
data
are
available
to
reassess
tolerances
for
residues
in/
on
all
commodities
with
uses
being
supported
by
the
MBIP.
The
available
commodity
fumigation
data
support
lowering
all
tolerance
levels,
with
the
exception
of
those
on
apples,
pears,
and
quinces.
The
available
data
indicate
that
the
5.0
ppm
tolerances
for
residues
in/
on
apples,
pears,
and
quinces
are
inadequate
and
should
be
increased
to
8.0
ppm
and
reassigned
to
the
pome
fruits
crop
group.

Tolerances
for
residues
in/
on
individual
commodities
should
be
reassigned
to
the
appropriate
crop
group
tolerances.
However,
individual
tolerances
should
remain
for
residues
in/
on
asparagus,
cocoa
beans,
grapes,
pineapples,
and
strawberries.

Tolerances
for
residues
in/
on
the
following
commodities
should
be
revoked,
as
there
is
no
registered
use
or
the
MBIP
is
not
supporting
the
tolerance:
alfalfa
hay,
avocados,
coffee
beans,
copra,
cottonseed,
mangoes,
okra,
papayas,
peanuts,
pomegranates,
and
timothy
(
DP
Barcode
D197531,
R.
Perfetti,
1/
10/
94).
22
Tolerances
Listed
Under
40
CFR
§
180.123(
a)(
2):

Based
upon
the
available
methyl
bromide
residue
data
on
various
processed
foods
(
DP
Barcodes
D197515­
20
and
D197228,
R.
Perfetti,
5/
6/
94;
and
DP
Barcode
D215044,
R.
Perfetti,
8/
15/
95),
tolerances
for
residues
in
individual
food
items,
except
for
dried
herbs
and
spices,
should
be
reassigned
to
the
single
category
"
processed
foods,
excluding
chocolate",
under
40
CFR
§
180.123
(
a)(
2).
The
available
residue
data
on
processed
foods
support
a
separate
tolerance
for
"
chocolate,
products"
at
55.0
ppm.
Separate
tolerances
for
dried
herbs
and
spices
should
be
reassessed
to
35.0
ppm.

In
addition,
the
tolerance
for
residues
in
fermented
malt
beverages
should
be
revoked,
as
there
is
no
registered
fumigation
use
of
methyl
bromide
on
this
product.

Tolerances
Listed
Under
40
CFR
§
180.123(
a)(
3):

The
available
residue
data
for
processed
foods
(
DP
Barcode
D215044,
R.
Perfetti,
8/
15/
95)
will
also
support
separate
tolerances
for
residues
in
"
processed
feeds"
under
40
CFR
§
180.123
(
a)(
3).

Tolerances
Needed
Under
40
CFR
§
180.123(
a):

Tolerances
should
be
established
for
residues
of
methyl
bromide
per
se
in
on
the
following
crop
groups:
root
and
tuber
vegetables,
bulb
vegetables,
leafy
vegetables,
brassica
leafy
vegetables,
legume
vegetables,
fruiting
vegetables,
cucurbit
vegetables,
citrus
fruits,
pome
fruits,
stone
fruits,
berries,
tree
nuts,
and
cereal
grains.
A
separate
tolerance
should
also
be
proposed
for
kiwifruit
if
the
MBIP
intends
on
including
a
use
on
this
crop
on
their
labels.

Tolerance
Listed
Under
40
CFR
§
180.123(
c):

The
tolerance
for
a
regional
registration
for
residues
in/
on
ginger
root
should
be
revoked,
as
soil
fumigation
treatments
are
now
considered
non­
food
uses.
The
post­
harvest
use
on
ginger
root
will
be
covered
by
the
crop
group
tolerance
for
methyl
bromide
per
se
in/
on
root
and
tuber
vegetables.

Restriction
for
Peanut
Hulls
Under
40
CFR
§
180.123a:

EPA
has
determined
that
soil
fumigation
use
of
methyl
bromide
is
considered
a
non­
food
use.
Furthermore,
the
MBIP
is
not
supporting
a
post­
harvest
fumigation
use
on
peanuts
as
a
raw
agricultural
commodity.
Therefore,
this
section
should
be
deleted.

Tolerances
Listed
Under
40
CFR
§
180.199(
a):

The
tolerances
for
residues
in/
on
broccoli,
cauliflower,
eggplants,
muskmeons,
peppers,
pineapples,
strawberries,
and
tomatoes
should
be
revoked,
as
soil
fumigation
treatments
are
now
considered
non­
food
uses.
23
Tolerances
Listed
Under
40
CFR
§
180.199(
b):

The
tolerances
for
regional
registration
for
residues
in/
on
asparagus,
lettuce,
and
onions
should
be
revoked,
as
soil
fumigation
treatments
are
now
considered
non­
food
uses.

Tolerance
Listed
Under
40
CFR
§
180.199(
c):

The
tolerance
for
a
regional
registration
for
residues
in/
on
ginger
root
should
be
revoked,
as
soil
fumigation
treatments
are
now
considered
non­
food
uses.

Tolerance
Listed
Under
40
CFR
§
180.521(
a)(
3):

The
tolerance
of
125
ppm
for
residues
of
inorganic
bromides
in
milled
fractions
from
cereal
grain
should
be
revoked.
Tolerances
for
the
milled
fractions
would
be
no
higher
than
that
of
the
raw
agricultural
commodity
and
are
therefore
not
needed.

Tolerances
Listed
Under
40
CFR
§
180.522(
a):

The
tolerances
for
residues
in/
on
cereal
grains
and
fermented
malt
beverages
should
be
revoked,
as
there
are
no
registered
fumigation
uses
of
methyl
bromide
on
these
products.
24
(
continued)
Table
C.
Tolerance
Reassessment
Summary
for
Methyl
bromide.

Commodity
Current
Tolerance
(
ppm)
Tolerance
Reassessment
(
ppm)
Comment/
Correct
Commodity
Definition
Tolerances
listed
under
40
CFR
§
180.123
(
a)(
1):

Alfalfa,
hay
(
POST­
H)
50.0
Revoke
The
MBIP
is
not
supporting
this
use.

Almonds
(
POST­
H)
200.0
150.0
a
Reassign
to
crop
group
tolerance
for
residues
in/
on
the
Tree
Nuts
Group.
Commodity
fumigation
trials
support
a
decreased
tolerance
level
for
methyl
bromide.

Apples
(
POST­
H)
5.0
8.0
a
Reassign
to
crop
group
tolerance
for
residues
in/
on
the
Pome
Fruits
Group.
Commodity
fumigation
trials
support
an
increased
tolerance
level
for
methyl
bromide.

Apricots
(
POST­
H)
20.0
5.0
a
Reassign
to
crop
group
tolerance
for
residues
in/
on
the
Stone
Fruits
Group.
Commodity
fumigation
trials
support
a
decreased
tolerance
level
for
methyl
bromide.

Artichokes,
Jerusalem
(
POST­
H)
30.0
3.0
a
Reassign
to
crop
group
tolerance
for
residues
in/
on
the
Root
and
Tuber
Vegetables
Group.
Commodity
fumigation
trials
support
a
decreased
tolerance
level
for
methyl
bromide.

Asparagus
(
POST­
H)
100.0
0.05
Commodity
fumigation
trials
support
a
decreased
tolerance
level
for
methyl
bromide.

Avocados
(
POST­
H)
75.0
Revoke
No
registered
use
or
MBIP
is
not
supporting
Barley
(
POST­
H)
50.0
8.0
a
Reassign
to
crop
group
tolerance
for
residues
in/
on
the
Cereal
Grains
Group.
Commodity
fumigation
trials
support
a
decreased
tolerance
level
for
methyl
bromide.

Beans
(
POST­
H)
50.0
3.0
a
Reassign
to
crop
group
tolerance
for
residues
in/
on
the
Legume
Vegetables
Group.
Commodity
fumigation
trials
support
a
decreased
tolerance
level
for
methyl
bromide.
Beans,
green
(
POST­
H)
50.0
Beans,
lima
(
POST­
H)
50.0
Beans,
snap
(
POST­
H)
50.0
Beets,
garden,
roots
(
POST­
H)
30.0
3.0
a
See
comments
under
artichokes,
Jerusalem.

Beets,
sugar,
roots
(
POST­
H)
30.0
Blueberries
(
POST­
H)
20.0
0.5
a
Reassign
to
crop
group
tolerance
for
residues
in/
on
Berries
Crop
Group.
Commodity
fumigation
trials
support
a
decreased
tolerance
level
for
methyl
bromide.
Table
C
(
continued).

Commodity
Current
Tolerance
(
ppm)
Tolerance
Reassessment
(
ppm)
Comment/
Correct
Commodity
Definition
25
(
continued)
Brazil
nuts
(
POST­
H)
200.0
150.0
a
See
comment
under
almonds.

Bush
nuts
(
POST­
H)
200.0
Butternuts
(
POST­
H)
200.0
Cabbage
(
POST­
H)
50.0
1.0
a
Reassign
to
crop
group
tolerance
for
residues
in/
on
the
Brassica
Leafy
Vegetables
Group.
Commodity
fumigation
trials
support
a
decreased
tolerance
level.

Cantaloupes
(
POST­
H)
20.0
5.0
a
Reassign
to
crop
group
tolerance
for
residues
in/
on
the
Cucurbit
Vegetables
Group.
Commodity
fumigation
trials
support
a
decreased
tolerance
level.

Carrots
(
POST­
H)
30.0
3.0
a
See
comments
under
artichokes,
Jerusalem.

Cashews
(
POST­
H)
200.0
150.0
a
See
comments
under
almonds.

Cherries
(
POST­
H)
20.0
5.0
a
See
comments
under
apricots.

Chestnuts
(
POST­
H)
200.0
150.0
a
See
comments
under
almonds.

Cippolini,
bulbs
(
POST­
H)
50.0
2.0
a
Reassign
to
crop
group
tolerance
for
residues
in/
on
the
Bulb
Vegetables
Group.
Commodity
fumigation
trials
support
a
decreased
tolerance
level.

Citrus
citron
(
POST­
H)
30.0
2.0
a
Reassign
to
crop
tolerance
for
residues
in/
on
Citrus
Fruits
Group.
Commodity
fumigation
trials
support
a
decreased
tolerance
level.

Cocoa
beans
(
POST­
H)
50.0
8.0
Commodity
fumigation
trials
support
a
decreased
tolerance
level.

Coffee
beans
(
POST­
H)
75.0
Revoke
The
MBIP
is
not
supporting
these
uses.

Copra
(
POST­
H)
100.0
Revoke
Corn
(
POST­
H)
50.0
8.0
a
See
comments
under
barley.

Corn,
pop
(
POST­
H)
240.0
Corn,
sweet
(
K+
CWHR)(
POST­
H)
50.0
Cottonseed
(
POST­
H)
200.0
Revoke
The
MBIP
is
not
supporting
this
use.

Cucumbers
(
POST­
H)
30.0
5.0
a
See
comments
under
cantaloupe.

Cumin,
seed
(
POST­
H)
100.0
Revoke
Covered
by
tolerance
for
residues
in
herbs
and
spices.

Eggplant
(
POST­
H)
20.0
7.0
a
Reassign
to
crop
group
tolerance
for
residues
in/
on
the
Fruiting
Vegetables
Group.
Commodity
fumigation
trials
support
a
decreased
tolerance
level.

Filberts
(
Hazelnuts)
(
POST­
H)
200.0
150.0
a
See
comments
under
almonds.

Garlic
(
POST­
H)
50.0
2.0
a
See
comments
under
Cippolini
bulbs.
Table
C
(
continued).

Commodity
Current
Tolerance
(
ppm)
Tolerance
Reassessment
(
ppm)
Comment/
Correct
Commodity
Definition
26
(
continued)
Ginger,
roots
(
POST­
H)
100.0
3.0
a
See
comments
under
artichoke,
Jerusalem.

Grapefruit
(
POST­
H)
30.0
2.0
a
See
comments
under
citron.

Grape
(
POST­
H)
20.0
4.0
Commodity
fumigation
trials
support
a
decreased
tolerance
level.

Hickory
nuts
(
POST­
H)
200.0
150.0
a
See
comments
under
almond.

Honeydew
melons
(
POST­
H)
20.0
5.0
a
See
comments
under
cantaloupe.

Horseradish
(
POST­
H)
30.0
3.0
a
See
comments
under
artichokes,
Jerusalem.

Kumquats
(
POST­
H)
30.0
2.0
a
See
comments
under
citron.

Lemons
(
POST­
H)
30.0
Limes
(
POST­
H)
30.0
Macadamia
nuts
(
POST­
H)
200.0
150.0
a
See
comment
under
almonds.

Mangoes
(
POST­
H)
20.0
Revoke
No
registered
use
or
MBIP
is
not
supporting.

Muskmelons
(
POST­
H)
20.0
5.0
a
See
comments
under
cantaloupe.

Nectarines
(
POST­
H)
20.0
5.0
a
See
comments
under
apricot.

Oats
(
POST­
H)
50.0
8.0
a
See
comments
under
barley.

Okra
(
POST­
H)
30.0
Revoke
The
MBIP
is
not
supporting
this
use.

Onions
(
POST­
H)
20.0
2.0
a
See
comments
under
Cippolini
bulbs.

Oranges
(
POST­
H)
30.0
2.0
a
See
comments
under
citron.

Papayas
(
POST­
H)
20.0
Revoke
No
registered
use
or
MBIP
is
not
supporting.

Parsnips
(
POST­
H)
30.0
3.0
a
See
comments
under
artichoke,
Jerusalem.

Peaches
(
POST­
H)
20.0
5.0
a
See
comments
under
apricot.

Peanuts
(
POST­
H)
200.0
Revoke
No
registered
use
or
MBIP
is
not
supporting.

Pears
(
POST­
H)
5.0
8.0
a
See
comment
under
apples.

Peas
(
POST­
H)
50.0
3.0
a
See
comments
under
beans.

Peas,
black­
eyed
(
POST­
H)
50.0
Pecans
(
POST­
H)
200.0
150.0
a
See
comment
under
almonds.

Peppers
(
POST­
H)
30.0
7.0
a
See
comment
under
eggplants.

Pimentos
(
POST­
H)
30.0
Pineapples
(
POST­
H)
20.0
5.0
Commodity
fumigation
trials
support
a
decreased
tolerance
level.

Pistachio
nuts
(
POST­
H)
200.0
150.0
a
See
comment
under
almonds.

Plums
(
POST­
H)
20.0
5.0
a
See
comment
under
apricots.

Pomegranates
100.0
Revoke
No
registered
use
or
MBIP
is
not
supporting
Potatoes
(
POST­
H)
75.0
3.0
a
See
comments
under
artichokes,
Jerusalem.

Pumpkins
(
POST­
H)
20.0
5.0
a
See
comments
under
cantaloupes.
Table
C
(
continued).

Commodity
Current
Tolerance
(
ppm)
Tolerance
Reassessment
(
ppm)
Comment/
Correct
Commodity
Definition
27
(
continued)
Quinces
(
POST­
H)
5.0
8.0
a
See
comments
under
apples.

Radishes
(
POST­
H)
30.0
3.0
a
See
comments
under
artichokes,
Jerusalem.

Rice
(
POST­
H)
50.0
8.0
a
See
comments
under
barley.

Rutabagas
(
POST­
H)
30.0
3.0
a
See
comments
under
artichokes,
Jerusalem.

Rye
(
POST­
H)
50.0
8.0
a
See
comments
under
barley.

Salsify,
roots
(
POST­
H)
30.0
3.0
a
See
comments
under
artichokes,
Jerusalem.

Sorghum,
grain
(
POST­
H)
50.0
8.0
a
See
comments
under
barley.

Soybeans
(
POST­
H)
200.0
3.0
a
See
comments
under
beans.

Squash,
summer
(
POST­
H)
20.0
5.0
a
See
comments
under
cantaloupes.

Squash,
winter
(
POST­
H)
20.0
Squash,
zucchini
(
POST­
H)
20.0
Strawberries
(
PRE­
and
POST­
H)
60.0
0.05
Commodity
fumigation
trials
support
a
decreased
tolerance
level.

Sweet
potatoes
(
POST­
H)
75.0
3.0
a
See
comments
under
artichokes,
Jerusalem.

Tangerines
(
POST­
H)
30.0
2.0
a
See
comments
under
citron.

Timothy,
hay
(
POST­
H)
50.0
Revoke
No
registered
use
or
MBIP
is
not
supporting
Tomatoes
(
POST­
H)
20.0
7.0
a
See
comments
under
eggplants.

Turnips,
roots
(
POST­
H)
30.0
3.0
a
See
comments
under
artichokes,
Jerusalem.

Walnuts
(
POST­
H)
200.0
150.0
a
See
comments
under
almonds.

Watermelons
(
POST­
H)
20.0
5.0
a
See
comments
under
cantaloupes.

Wheat
(
POST­
H)
50.0
8.0
a
See
comments
under
barley.

Tolerances
listed
under
40
CFR
§
185.123
(
a)(
2):

Dried
eggs
400
Reassign
Reassign
to
"
processed
foods,
excluding
chocolate"
under
§
180.123
(
a)(
2).
Parmesan
cheese
325
Roquefort
cheese
325
Tomatoes,
concentrated
products
250
Figs,
dried
250
Processed
foods
other
than
those
listed
above
125
10.0
Processed
foods,
excluding
chocolate
Tolerance
level
can
be
lowered
to
cover
levels
of
methyl
bromide
detected
in
processed
food
fumigation
trials.

Herbs,
processed
400
35.0
This
tolerance
can
be
lowered
to
cover
levels
of
methyl
bromide
detected
in
processed
herb
and
spice
fumigation
trials.
Spices,
processed
400
35.0
Fermented
malt
beverages
25
Revoke
No
registered
use
Tolerances
listed
under
40
CFR
§
185.123
(
a)(
3):
Table
C
(
continued).

Commodity
Current
Tolerance
(
ppm)
Tolerance
Reassessment
(
ppm)
Comment/
Correct
Commodity
Definition
28
Dog
food
400
Reassign
Reassign
to
"
processed
feeds"
under
§
180.123
(
a)(
3).
Barley,
milled
fractions
125
Corn,
milled
fractions
125
Sorghum
(
milo),
grain,
milled
fractions
125
Oats,
milled
fractions
125
Rice,
milled
fractions
125
Rye,
milled
fractions
125
Wheat,
milled
fractions
125
Tolerance
listed
under
40
CFR
§
180.123
(
c):

Ginger,
roots
(
PRE­
and
POST­
H)
100
Revoke
Use
will
be
covered
by
tolerance
for
residues
in/
on
the
Root
and
Tuber
Vegetables
Group.

Tolerances
listed
under
40
CFR
§
180.199
(
a,
b
and
c):

Broccoli
25
Revoke
Soil
fumigation
treatments
are
considered
non­
food
uses.
Cauliflower
25
Eggplants
60
Muskmelons
40
Peppers
25
Pineapples
25
Strawberries
25
Tomatoes
40
Asparagus
300
Lettuce
300
Onions,
dry
bulb
300
Ginger,
roots
(
PRE­
and
POST­
H)
100
Revoke
See
comment
under
ginger
[
§
180.123
(
b)]

Tolerances
needed
under
40
CFR
§
180.123
(
a)(
1):

Vegetable,
root
and
tuber,
group
None
3.0
Crop
group
tolerance
recommendations
are
based
on
maximum
methyl
bromide
residues
in/
on
representative
commodities
of
each
group
in
commodity
fumigation
trials.
Vegetable,
bulb,
group
None
2.0
Vegetable,
leafy,
group
None
0.5
Vegetable,
Brassica
leafy,
group
None
1.0
Vegetable,
legume,
group
None
3.0
Vegetable,
fruiting,
group
None
7.0
Vegetable,
cucurbit,
group
None
5.0
Fruit,
citrus,
group
None
2.0
Fruit,
pome,
group
None
8.0
Fruit,
stone,
group
None
5.0
Table
C
(
continued).

Commodity
Current
Tolerance
(
ppm)
Tolerance
Reassessment
(
ppm)
Comment/
Correct
Commodity
Definition
29
Berry
group
None
0.5
Grain,
cereal,
group
None
8.0
Kiwifruit
None
5.0
The
available
data
would
support
a
tolerance
of
5.0
ppm
if
the
MBIP
intends
to
include
a
use
on
kiwifruit
on
their
labels.

Tolerances
needed
under
40
CFR
§
180.123
(
a)(
2):

Chocolate
products
None
55.0
The
available
residue
data
on
processed
foods
support
a
separate
tolerance
for
"
chocolate,
products"
at
55.0
ppm.

Tolerances
needed
under
40
CFR
§
180.123
(
a)(
3):

Processed
feeds
None
10.0
The
available
residue
data
on
processed
foods
also
supports
at
10
ppm
tolerance
for
"
processed
feeds".

a
Reassessed
tolerance
for
the
associated
crop
group.
30
DIETARY
EXPOSURE
ASSESSMENT
SUMMARY
For
reregistration
and
risk
assessment
purposes,
adequate
plant
metabolism
data
are
available.
Adequate
magnitude
of
the
residue
data
for
methyl
bromide
residues
are
also
available
for
all
the
registered
uses
the
MBIP
is
supporting.
Adequate
residue
data
are
also
available
for
all
processed
commodities.
Data
on
animal
metabolism
and
residues
in
animal
commodities
are
not
required.
A
reasonably
reliable
risk
assessment
for
the
uses
of
methyl
bromide
can
be
conducted
at
this
time
using
existing
and
reassessed
tolerances.

CODEX
HARMONIZATION
There
are
no
established
or
proposed
Codex
maximum
residue
limits
for
methyl
bromide;
therefore,
harmonization
of
U.
S.
tolerances
with
Codex
is
not
required.

AGENCY
MEMORANDA
CITED
IN
THIS
DOCUMENT
DP
Barcode:
None
Subject:
Methyl
Bromide
Registration
Standard
Administrative
Review
of
Inorganic
Bromide
Tolerances
From:
Anne
Lindsay,
RD
To:
L.
V.
White,
Methyl
bromide
Industry
Panel
Dated:
7/
7/
89
MRID(
s):
None
DP
Barcode:
None
Subject:
Methyl
Bromide
Industry
Panel:
Response
to
the
Methyl
Bromide
Registration
Standard:
Metabolism
Studies
From:
R.
B.
Perfetti,
HED
To:
R.
Engler
Dated:
3/
8/
91
MRID(
s):
41627701
DP
Barcode:
D168913
Subject:
Methyl
Bromide
Industry
Panel:
Response
to
the
Methyl
Bromide
Registration
Standard:
Metabolism
Study
From:
R.
B.
Perfetti,
HED
To:
W.
Burnam
Dated:
9/
24/
91
MRID(
s):
42137701
31
DP
Barcode:
D197531
Subject:
Methyl
Bromide
Industry
Panel:
Response
to
the
Methyl
Bromide
Registration
Standard:
Magnitude
of
the
Residue
Data
Discussions
and
Waiver
Requests
From:
R.
B.
Perfetti,
HED
To:
L.
Rossi,
SRRD
Dated:
1/
10/
94
MRID(
s):
None
DP
Barcodes:
D196317
and
D196312
Subject:
Response
to
the
Methyl
Bromide
Registration
Standard:
Residue
Data
From:
R.
B.
Perfetti,
HED
To:
L.
Rossi,
SRRD
Dated:
4/
7/
94
MRID(
s):
42949601,
42963801
DP
Barcodes:
D197515,
D197516,
D197517,
D197518,
D197519,
D197520,
and
D197228
Subject:
Response
to
the
Methyl
Bromide
Registration
Standard:
Residue
Data.
From:
R.
B.
Perfetti,
HED
To:
L.
Rossi,
SRRD
Dated:
5/
6/
94
MRID(
s):
43025301,
43025701,
43025801,
43025101,
43029801,
43025202,
43023601
DP
Barcodes:
D204238,
D205160,
D205462,
and
D206950
Subject:
Response
to
the
Methyl
Bromide
Registration
Standard:
Processing
Studies.
From:
R.
B.
Perfetti,
HED
To:
E.
Saito,
SRRD
Dated:
11/
16/
94
MRID(
s):
43287001,
43247401,
43278701,
43343401
DP
Barcode:
D215044
Subject:
Methyl
Bromide.
Magnitude
of
the
Residue
in
processed
Commodities:
Instant
White
Rice,
Shelled
Roasted
peanuts,
Unpopped
Corn,
and
Country
Ham.
From:
B.
Cropp­
Kohlligian,
HED
To:
L.
Schnaubelt/
B.
O'Keefe,
SRRD
Dated:
8/
15/
95
MRID(
s):
43628701
32
DP
Barcode:
None
Subject:
Methyl
Bromide.
Food
vs.
Non­
Food
Use
Status
for
Soil
Fumigation
Uses.
From:
S.
Irene,
HED
To:
S.
Johnson,
RD
Dated:
1/
31/
97
MRID(
s):
None
DP
Barcode:
D275389
Subject:
Methyl
Bromide.
Magnitude
of
the
Residue
in/
on
Tree
Nuts
and
Dried
Fruit.
From:
C.
Olinger,
HED
To:
J.
Nevola,
SRRD
Dated:
7/
17/
01
MRID(
s):
43885001,
43885002
33
RESIDUE
CHEMISTRY
CITATIONS
Bibliographic
citations
include
only
MRIDs
containing
data
which
fulfill
data
requirements.

References
(
cited):

00026180
Shrader,
S.
A.;
Beshgetoor,
A.
W.;
Stenger,
V.
A.
(
1942)
Determination
of
total
and
inorganic
Bromide
in
foods
fumigated
with
Methyl
bromide.
Industrial
and
Engineering
Chemistry
14(
1):
1­
4.
(
Also
In
unpublished
submission
received
Nov
11,
1966
under
464­
240;
submitted
by
Dow
Chemical
U.
S.
A.,
Midland,
Mich.;
CDL:
003480­
F)

00043601
Getzendaner,
M.
E.
(
1961)
Experimental
fumigations
with
Methyl
bromide.
Cereal
Science
Today
6(
8):
268­
270.
(
Also
in
unpublished
submission
received
Nov
11,
1966
under
464­
240;
submitted
by
Dow
Chemical
U.
S.
A.,
Midland,
Mich.;
CDL:
003480­
H)

00065237
Bridges,
R.
G.
(
1955)
The
fate
of
labelled
insecticide
residues
in
food
products.
III.­­~
N~­
Methylation
as
a
result
of
fumigating
wheat
with
Methyl
bromide.
Journal
of
the
Science
of
Food
and
Agriculture
6(
5):
261­
268.
(
Reprint;
also~
In~
unpublished
submission
received
Jun
7,
1976
under
464­
3;
submitted
by
Dow
Chemical
U.
S.
A.,
Midland,
Mich.;
CDL:
227158­
M
00012908
Dow
Chemical
Company
(
1962)
Determination
of
Inorganic
Bromide
Residue
in
Pineapple
Resulting
from
Soil
Fumigations
with
Brozone
®
,
Trizone
®
or
Dowfume
®
W­
85.
(
Unpublished
study
received
Jul
5,
1962
under
5F0426;
CDL:
090462­
K)

00012999
Dow
Chemical
Company
(
1960)
A
Study
of
Bromide
Residues
in
Strawberries
from
Preplant
Soil
Fumigation
with
Methyl
bromide.
(
Unpublished
study
received
Apr
28,
1961
under
464­
223;
CDL:
119921­
A)

00013000
Dow
Chemical
Company
(
1961)
Bromide
Residues
in
Tomatoes
from
Preplant
Soil
Fumigations
with
Brozone
®
.
(
Unpublished
study
received
Apr
28,
1961
under
464­
223;
CDL:
119921­
B)

00013057
Gregory,
R.
L.
(
1964)
Determination
of
Propargyl
bromide
and
Total
Bromide
Residues
in
Strawberries,
Muskmelons,
Tomatoes,
Broccoli,
Eggplant,
Cauliflower,
and
Peppers
Grown
on
Soil
Fumigated
with
Trizone
®
or
Propargyl
bromide.
(
Unpublished
study
received
Sep
4,
1964
under
unknown
admin.
no.;
submitted
by
Dow
Chemical
U.
S.
A.,
Midland,
Mich.;
CDL:
131472­
J)

00066267
Bistline,
F.
W.
(
1970)
Letter
sent
to
A.
E.
Willson
dated
Jul
27,
1970:
Status
report
of
tree
response
from
methyl­
bromide
soil
injections.
(
Unpublished
study
received
Jan
11,
1972
under
464­
104;
prepared
by
Coca­
Cola
Co.,
submitted
by
Dow
Chemical
U.
S.
A.,
Midland,
Mich.;
CDL:
003405­
D)
34
00079041
Abdalla,
N.
A.;
Lear,
B.
(
1975)
Determination
of
inorganic
bromide
in
soils
and
plant
tissues
with
a
bromide
selective­
ion
electrode.
Communications
in
Soil
Science
and
Plant
Analysis
6(
5):
489­
494.
(
Also
in
unpublished
submission
received
Jul
21,
1981
under
1E2541;
submitted
by
Interregional
Research
Project
No.
4,
New
Brunswick,
N.
J.;
CDL:
070192­
C)

00079043
Ferguson,
M.
P.
(
1980)
Letter
sent
to
Drew
M.
Baker
dated
Mar
14,
1980
[
Dates
of
treatment,
planting
and
harvesting
of
methyl
bromide
on
onions].
(
Unpublished
study
received
Jul
21,
1981
under
1E2541;
submitted
by
Interregional
Research
Project
No.
4,
New
Brunswick,
N.
J.;
CDL:
070192­
E)

00079048
Dow
Chemical
U.
S.
A.
(
1980)
[
Residues
of
Methyl
Bromide
in
Asparagus
and
Lettuce].
(
Compilation;
unpublished
study
received
Jul
21,
1981
under
464­
303;
CDL:
070203­
B)

00079550
Winteringham,
F.
P.
W.;
Harrison,
A.;
Bridges,
R.
G.;
et
al.
(
1955)
The
fate
of
labelled
insecticide
residues
in
food
products.
The
nature
of
methyl
bromide
residues
in
fumigated
wheat.
Journal
of
the
Science
of
Food
and
Agriculture
6(
May):
251­
261.
(
Also
in
unpublished
submission
received
Jun
7,
1976
under
464­
3;
submitted
by
Dow
Chemical
U.
S.
A.,
Midland,
Mich.;
CDL:
227157­
F)

00088683
Dow
Chemical
Company
(
1954)
The
Residues
of
Bromides
Resulting
from
the
Fumigation
with
Methyl
Bromide.
(
Unpublished
study
received
May
1,
1955
under
PP0014;
CDL:
090090­
Q)

00089066
Dow
Chemical
Company
(
1955)
Residues:
[
Methyl
Bromide].
(
Unpublished
study
received
on
unknown
date
under
PP0055;
CDL:
090053­
A)

00089457
Dow
Chemical
Company
(
1957)
[
Analyses­­
Bromide
Residues].
(
Unpublished
study
received
on
unknown
date
under
PP0175;
CDL:
090203­
A)

00090147
Seo,
S.
T.;
Balock,
J.
W.
(
1961)
Total
Bromides
in
Asparagus
Fumigated
with
Methyl
Bromide:
Special
Report
Ho­
31.
(
U.
S.
Agricultural
Research
Service,
Entomology
Research
Div.,
Fruit
and
Vegetable
Insects
Research
Branch,
Hawaii
Fruit
Fly
Investigations;
unpublished
study;
CDL:
090381­
A)

00090269
Pauling,
L.
E.;
Mejeur,
W.
H.
(
1963)
A
Study
of
Bromide
Residue
in
Milled
Fractions
of
Various
Commodities
Fumigated
with
Methyl
Bromide.
(
Unpublished
study
received
Sep
30,
1963
under
PP0345;
prepared
by
Michigan
Chemical
Corp.,
submitted
by
Dow
Chemical
Co.,
Indianapolis,
Ind.;
CDL:
090374­
E)

00090408
U.
S.
Agricultural
Research
Service,
Plant
Quarantine
Division
(
1964)
Report
on
the
Determination
of
Inorganic
Bromides
in
Products
Fumigated
with
Methyl
Bromide.
(
Unpublished
study;
CDL:
090506­
B)
35
00096432
Interregional
Research
Project
Number
4
(
1980)
[
Bromide
Residues
in
Strawberries].
Includes
method
dated
Dec
23,
1965,
and
method
dated
Oct
14,
1980.
(
Compilation;
unpublished
study,
including
published
data,
received
Feb
26,
1982
under
2E2654;
CDL:
070705­
A)

00109713
Ferguson
Fumigants
(
1963)
[
Residue
of
Bromine
Residues
in
Several
Foods].
(
Compilation;
unpublished
study
received
May
17,
1965
under
5H1774;
CDL:
221617­
A)

00112926
Interregional
Research
Project
No.
4
(
1979)
Analytical
Methods
Used
and
Recovery
Data:
[
Bromide].
(
Compilation;
unpublished
study
received
Aug
8,
1982
under
9E2139;
CDL:
071083­
A)

00118768
Interregional
Research
Project
No.
4
(
1973)
The
Results
of
Tests
on
the
Amount
of
Inorganic
Bromide,
Organic
Bromide
and
Total
Bromide
Residues
(
Calculated
as
Br.)
Remaining
in
or
on
Comb
Honey
Including
a
Description
of
the
Analytical
Methods
Used.
(
Compilation;
unpublished
study
received
Apr
13,
1973
under
3E1387;
CDL:
093700­
B)

00118817
Dow
Chemical
Co.
(
1955)
[
Bromide
Residues
in
Various
Crops].
(
Compilation;
unpublished
study
received
on
unknown
date
under
PP0014;
CDL:
094562­
A)

00118820
Dow
Chemical
Co.
(
1960)
Bromide
Residues
in
Popcorn
Resulting
from
Methyl
Bromide
Fumigations.
(
Unpublished
study
received
Jun
7,
1976
under
PP0251;
CDL:
096408­
B)

00118821
Interregional
Research
Project
No.
4
(
1977)
The
Results
of
Tests
on
the
Amount
of
Inorganic
Bromide
Residues
Remaining
in
or
on
Almond
Hulls,
Nutmeats,
and
Shells,
Including
a
Description
of
the
Analytical
Method
Used.
(
Compilation;
unpublished
study
received
Oct
12,
1978
under
9E2139;
CDL:
097456­
A)

00118829
Harris,
T.;
Thomas,
R.;
Peters,
A.
(
1963)
[
Methyl
Bromide
Residues
in
Grapes].
(
Compilation;
unpublished
study
received
on
unknown
date
under
unknown
admin.
no.;
submitted
by
?;
CDL:
124597­
A)

00118830
Hayward,
J.
(
1966)
[
Methyl
Bromide:
Residues
in
Alfalfa
and
Other
Subjects].
(
Compilation;
unpublished
study
received
Aug
8,
1966
under
unknown
admin.
no.;
submitted
by
?;
CDL:
124608­
A)

00118837
Barnes,
D.;
Stagg,
S.;
Mayer,
E.;
et
al.
(
1959)
[
Methyl
Bromide:
Residues
in
Raisins
and
Other
Crops].
(
Compilation;
unpublished
study
received
Feb
26,
1960
under
0H0116;
submitted
by
?;
CDL:
221569­
B)

00118838
Shrader,
S.;
Beshgetoor,
A.;
Stenger,
V.
(
1960)
[
Determination
of
Residues
of
Methyl
Bromide
in
Various
Products].
(
Compilation;
unpublished
study
received
Mar
8,
1961
under
0H0435;
submitted
by
?;
CDL:
221585­
A)
36
00118845
Dow
Chemical
U.
S.
A.
(
1975)
[
Methyl
Bromide
Analytical
Residue
Report­­
Strawberries].
(
Compilation;
unpublished
study
received
Mar
2,
1976
under
464­
3;
CDL:
230666­
B)

00119256
Dow
Chemical
Co.
(
1957)
The
Results
of
Tests
on
the
Amount
of
Residue
Remaining:
[
Bromides].
(
Compilation;
unpublished
study
received
on
unknown
date
under
PP0103;
CDL:
090133­
E)

00119550
U.
S.
Agricultural
Research
Service,
Pesticide
Regulations
Div.
Laboratory
(
1965)
Report
on
the
Determination
of
Inorganic
Bromides
in
Various
Products
Fumigated
with
Methyl
Bromide.
(
Unpublished
study
received
Oct
8,
1965
under
unknown
admin.
no.;
submitted
by
?;
CDL:
124610­
A)

00127221
Ford,
J.;
Mitchell,
W.;
Grubbs,
J.;
et
al.
(
1942?)
Bromide
Residues
following
Fumigation
of
Soybeans
with
Methyl
Bromide.
(
Unpublished
study
received
Oct
14,
1964
under
5F0428;
submitted
by
U.
S.
Agricultural
Research
Service,
Plant
Pest
Control
Div.,
Denver,
CO;
CDL:
092716­
A)

00127767
Interregional
Research
Project
No.
4
(
1982)
The
Results
of
Tests
on
the
Amount
of
Methyl
Bromide
Residues
Remaining
in
or
on
Blueberries,
Including
a
Description
of
the
Analytical
Method
Used.
(
Compilation;
unpublished
study
received
Mar
14,
1983
under
464­
3;
CDL:
071457­
A)

00135683
Seo,
S.;
Balock,
J.;
Burditt,
A.
(
1952?)
Bromide
Residues
in
Avocado,
Bell
Pepper
and
Tomato
Fumigated
with
Methyl
Bromide:
Special
Report
HO­
28.
(
Unpublished
study
received
Dec
26,
1961
un
der
PP0341;
prepared
by
Subtropical
Fruit
Insects
Section,
submitted
by
U.
S.
Dept.
of
Agriculture,
Entomology
Research
Div.,
Tifton,
GA;
CDL:
092624­
A)

00140445
U.
S.
Agricultural
Research
Service
(
1961)
[
Residue:
Bromide
on
Apples
and
Others].
(
Compilation;
unpublished
study
received
May
3,
1961
under
PP0326;
CDL:
092608­
A)

00149535
Ethyl
Corp.
(
1984)
Residue
Data
for
Methyl
Bromide.
Unpublished
compilation.
269
p.

00152907
Great
Lakes
Chemical
Corp.
(
1984)
Analysis
of
Methyl
Bromide
Residues
in
Fruits
and
Vegetables.
Unpublished
compilation.
57
p.

00153317
Methyl
Bromide
Industry
Panel
(
1985)
The
Results
of
Tests
on
the
Amount
of
Organic
Methyl
Bromide
Residues
Remaining
in
or
on
Various
Fumigated
Commodities
and
a
Description
of
the
Analytical
Methods
Used.
Unpublished
compilation.
600
p.

00157445
US
Dept.
of
Agriculture
(
1970)
Bromide
Residues
in
Vegetable
Samples.
Unpublished
compilation
prepared
by
Agricultural
Research
Service.
5
p.
37
00160627
DeVries,
J.;
Broge,
J.;
Schroeder,
J.
et
al.
(
1985)
Headspace
gas
chromatographic
method
for
determination
of
methyl
bromide
in
food
ingredients.
J.
Assoc.
Off.
Anal.
Chem.
68(
6):
1112­
1116
00160628
Reeves,
R.;
McDaniel,
C.;
Ford,
J.
(
1985)
Organic
and
inorganic
bromide
residues
in
spices
fumigated
with
methyl
bromide.
J.
Agric.
Food
Chem.
33(
5):
780­
783.

00160629
Tebbets,
J.;
Hartsell,
P.;
Nelson,
H.
et
al.
(
1983)
Methyl
bromide
fumigation
of
tree
fruits
for
control
of
the
Mediterranean
fruit
fly:
Concentrations,
sorption,
and
residues.
Journal
of
Agriculture
&
Food
Chemistry
31(
2):
247­
249.

40579501
Secara,
S.
(
1988)
Post
Harvest
Chamber
Fumigation
Pre­
study
using
Methyl
Bromide
as
a
Fumigant:
Laboratory
Project
ID:
B.
R.
#
15.
87.1.
Unpublished
study
prepared
by
Bolsa
Research
Associates.
33
p.

40618501
Secara,
S.
(
1988)
Residue
Chemistry:
Storage
Stability
of
Fumigated
Products:
B.
R.
#
28.88.1.
Unpublished
study
prepared
by
Bolsa
Research
Associates.
24
p.

40926401
Secara,
S.
(
1988)
Methyl
Bromide
­
Magnitude
of
Residue
on
Ginger,
Including
a
Description
of
the
Analytical
Method:
Lab.
Proj.
ID
#
10:
87:
13.
Unpublished
study
prepared
by
Bolsa
Research
Associates.
72
p.

40926501
Secara,
S.
(
1988)
Methyl
Bromide
­
Magnitude
of
Residue
on
Ginger,
Including
a
Description
of
the
Analytical
Method:
Project
ID.
10:
87:
13.
Unpublished
study
prepared
by
Bolsa
Research
Associates.
72
p.

41627701
Starratt,
A.;
Bond,
E.
(
1990)
Residues
of
Methyl
Bromide
in
Fumigated
Commodities:
Lab
Project
Number:
A.
C.
280.
Unpublished
study
prepared
by
Research
Centre,
Agriculture
Canada.
238
p.

42137701
Lamb,
J.
(
1991)
Response
to
the
March
8,
1991
EPA
Review
of
the
Methyl
Bromide
Plant
Metabolism
Study
Submitted
by
the
Methyl
Bromide
Industry
Panel
on
August
29,
1990:
Lab
Project
Number:
MB­
4.0­
JSCF.
Unpublished
study
prepared
by
Methyl
Bromide
Industry
Panel
(
CMA)
and
Jellinek,
Schwartz,
Connolly
and
Freshman,
Inc.
115
p.

42949601
Slesinski,
R.
(
1993)
Magnitude
and
Persistence
of
Methyl
Bromide
Residues
Following
Fumigation
of
Various
Food
Commodities:
Lab
Project
Number:
MEBR
93­
01.
Unpublished
study
prepared
by
Bolsa
Research
Associates;
ABC/
Del
Monte
Labs.
4171
p.

42963801
Ussary,
J.;
Moseman,
R.;
Nanke,
K.
(
1993)
Post­
Harvest
Fumigation
of
Field
Corn
Grain
with
Methyl
Bromide:
Magnitude
of
the
Residue
Processing
Study:
Final
Report:
Lab
Project
Number:
P2.
Unpublished
study
prepared
by
Webb
Technical
Group.
169
p.
38
43023601
Ussary,
J.;
Moseman,
R.;
Nanke,
K.
(
1993)
Post­
Harvest
Fumigation
of
Rice
with
Methyl
Bromide:
Magnitude
of
the
Residue
Processing
Study:
Lab
Project
Number:
P3.
Unpublished
study
prepared
by
Engineering
Biosciences
Research
Center,
Texas
A
&
M
Univ.
and
Webb
Technical
Group,
Inc.
190
p.

43025101
Lee,
H.;
Van
Natta,
K.
(
1993)
Magnitude
and
Persistence
of
Methyl
Bromide
Residues
Following
Fumigation
of
Finished
Chocolate
Products:
Lab
Project
Number:
BR600.4:
93.
Unpublished
study
prepared
by
Churchill
Nut
Co.
and
Bolsa
Research
Associates.
316
p.

43025201
Ussary,
J.;
Moseman,
R.;
Nanke,
K.
(
1993)
Fumigation
of
Processed
Foods
with
Methyl
Bromide:
Magnitude
of
the
Residues:
Final
Report:
Lab
Project
Number:
P5:
MEBR93­
01.
Unpublished
study
prepared
by
Webb
Technical
Group,
Inc.
and
Ussary
Scientific
Services.
205
p.

43025301
Ussary,
J.;
Moseman,
R.;
Nanke,
K.
(
1993)
Post­
Harvest
Fumigation
of
Wheat
with
Methyl
Bromide:
Magnitude
of
the
Residue
Processing
Study:
Final
Report:
Lab
Project
Number:
P4.
Unpublished
study
prepared
by
Webb
Technical
Group,
Inc.;
Ussary
Scientific
Services;
and
Texas
A&
M
University,
Engineering
Biosciences
Research
Center.
175
p.

43025701
Lee,
H.;
Van
Natta,
K.
(
1993)
Magnitude
and
Persistence
of
Methyl
Bromide
Residues
Following
Fumigation
of
Green
Cocoa
Beans:
Lab
Project
Number:
BR­
SSP­
002:
MEBR93­
01:
WIL­
49009.
Unpublished
study
prepared
by
Churchill
Nut
Co.
and
Bolsa
Research
Associates.
222
p.

43025801
Marulli,
A.;
Lee,
H.
(
1993)
Magnitude
and
Persistence
of
Methyl
Bromide
Residues
Following
Fumigation
of
Grape,
Peach,
Plum,
Nectarine,
and
Lemon.
Unpublished
study
prepared
by
AgFume
Services,
Inc.
and
Bolsa
Research
Associates.
330
p.

43029801
Ussary,
J.;
Moseman,
R.;
Nanke,
K.
(
1993)
Post­
Harvest
Fumigation
of
Spices
with
Methyl
Bromide:
Magnitude
of
the
Residues:
Lab
Project
Number:
P1.
Unpublished
study
prepared
by
Webb
Technical
Group,
Inc.
373
p.

43247401
Slesinski,
R.
(
1994)
Methyl
Bromide
Residues
in
Selected
Raw
and
Processed
Fractions
from
Fumigated
Apples,
Grapes
and
Tomatoes
and
in
Cannery
Waste
from
Fumigated
Beans
and
Corn:
Final
Report:
Part
1
of
3:
Methyl
Bromide
Residues
in
Fumigated
Tomatoes
and
Processed
Fractions:
Lab
Project
Number:
MEBR/
94/
02.
Unpublished
study
prepared
by
Plant
Sciences,
Inc.,
Bolsa
Research
Associates
and
National
Food
Lab.
262
p.

43278701
Slesinski,
R.
(
1994)
Determination
of
Methyl
Bromide
Residues
in
Selected
Fractions
of
Apples,
Grapes
and
Oranges
Following
Fumigation
and
Processing:
Final
Report:
Lab
Project
Number:
MEBR
94­
01.
Unpublished
study
prepared
by
Plant
Sciences,
Inc.;
National
Food
Lab.
and
Bolsa
Research
Assoc.
481
p.
39
43343401
Slesinski,
R.
(
1994)
Final
Report:
Methyl
Bromide
Residues
in
Selected
Raw
and
Processed
Fractions
from
Fumigated
Apples,
Grapes
and
Tomatoes
and
in
Cannery
Waste
from
Fumigated
Beans
and
Corn:
Part
3
of
3:
Methyl
Bromide
Residues
in
Fumigated
Apples
and
Grapes
and
Respective
Juice
Fractions:
Lab
Project
Number:
MEBR/
94/
02.
Unpublished
study
prepared
by
Plant
Sciences,
Inc.,
Bolsa
Research
Associates,
and
The
National
Food
Laboratory.
330
p.

43287001
Slesinski,
R.
(
1994)
Methyl
Bromide
Residues
in
Selected
Raw
and
Processed
Fractions
from
Fumigated
Apples,
Grapes
and
Tomatoes
and
in
Cannery
Waste
from
Fumigated
Beans
and
Corn:
Final
Report:
Part
2
of
3:
Methyl
Bromide
Residues
in
Surrogate
Cannery
Waste
from
Fumigated
Succulent
Beans
and
Sweet
Corn:
Lab
Project
Number:
MEBR/
94/
02:
MEBR/
94/
02/
B.
Unpublished
study
prepared
by
Plant
Sciences,
Inc.,
Bolsa
Research
Associates.
336
p.

43629701
Ussary,
J.;
Moseman,
R.;
Tracey,
S.
(
1995)
Fumigation
of
Processed
Foods
with
Methyl
Bromide:
Magnitude
of
the
Residues:
Final
Report:
Lab
Project
Number:
P8.
Unpublished
study
prepared
by
Webb
Technical
Group,
Inc.
145
p.

43885001
Hartsell,
P.;
Hurley,
J.
(
1995)
Magnitude
of
Organic
Bromide
Residues
on
Tree
Nut
Meats
(
Shelled
Almonds,
Pecans,
Pistachios,
and
Walnuts)
Following
Post­
Harvest
Fumigation:
Amended
Report:
Lab
Project
Number:
2B.
Unpublished
study
prepared
by
DFA
of
California.
90
p.

43885002
Hartsell,
P.;
Hurley,
J.
(
1995)
Magnitude
of
Organic
Bromide
Residues
on
Dried
Raisins,
Raisin
Waste,
Prunes,
Figs
&
Dates
Following
Post­
Harvest
Fumigation:
Amended
Report:
Lab
Project
Number:
2A.
Unpublished
study
prepared
by
DFA
of
California..
97
p.