Document ID: EPA-HQ-OAR-2003-0121-0007
Agency: epa
Document Type: Supporting & Related Material
Title: 
Posted Date: 2003-08-22T04:00Z

Date:
May
7,
2003
Subject:
Revised
MACT
Floor
Impacts
for
Vertical
Storage
Tanks
at
Continuous
Chemical
Manufacturing
Processes
Covered
by
the
Miscellaneous
Organic
NESHAP
From:
Melissa
Icenhour
To:
MON
Project
File
This
memorandum
describes
the
changes
to
and
the
revised
results
of
the
impacts
analysis
for
vertical
storage
tanks
associated
with
continuous
processes.
No
changes
have
been
made
to
the
MACT
floor,
but
three
changes
have
been
made
in
the
impacts
analysis.
First,
the
HAP
partial
pressures
for
tanks
that
store
multiple
HAP
originally
were
determined
by
summing
the
vapor
pressure
values
for
each
HAP
in
the
tank.
1
We
could
not
determine
the
HAP
partial
pressures
using
Raoult's
Law
because
we
do
not
have
the
liquid
composition
for
the
tanks.
However,
the
original
approach
clearly
overestimated
the
HAP
partial
pressures
for
the
tanks.
To
better
approximate
the
total
HAP
partial
pressures,
this
revised
analysis
estimates
individual
HAP
partial
pressures
using
weighted
average
vapor
pressures
based
on
the
ratio
of
the
individual
HAP
emissions
to
the
total
HAP
emissions.
This
change
reduced
the
HAP
partial
pressures
for
numerous
tanks,
including
three
tanks
for
which
the
partial
pressure
fell
below
the
MACT
floor
cut
off
of
1.0
psia.

A
second
change
concerned
the
HAP
reductions
for
tanks
that
already
have
an
add­
on
control
device
that
reduces
emissions
by
less
than
95
percent.
The
original
analysis
contained
an
error
in
the
calculation
that
resulted
in
underestimation
of
the
emission
reduction
that
would
be
achieved
by
meeting
the
MACT
floor
requirement
of
95
percent
control.
A
third
change
involves
a
storage
tank
that
is
currently
controlled
with
a
scrubber.
The
original
analysis
assumed
the
scrubber
achieves
no
control
for
all
for
one
of
the
scrubbers.
This
analysis
applies
the
assumption
consistently
for
all
of
the
scrubbers.

The
lowering
of
estimated
emission
reductions
and
costs
due
to
the
first
change
are
partially
offset
by
the
increases
associated
with
the
second
and
third
changes.
Collectively,
for
the
storage
tanks
in
the
database,
these
changes
lower
the
emission
reduction
by
less
than
1
ton
per
year,
capital
costs
are
reduced
by
about
$
35,000,
and
annual
costs
are
reduced
by
about
$
6,000
per
year.
The
database
is
assumed
to
represent
half
of
the
storage
tanks
associated
with
continuous
processes.
1
Therefore,
the
nationwide
emission
reductions
are
about
1
tpy
lower
than
in
the
original
analysis,
the
capital
costs
are
about
$
70,000
lower,
and
the
annual
costs
are
about
$
12,000
per
year
lower.
As
a
result
of
these
changes,
the
cost
effectiveness
has
also
changed
from
$
4,800
per
ton
to
$
4,700
per
ton.
2
Table
1
contains
the
specific
tank
data
for
vertical
storage
tanks
associated
with
continuous
processes.

References
1.
Memorandum
from
D.
Randall
and
J.
Fields,
MRI,
to
Miscellaneous
Organic
NESHAP
Project
File.
July
31,
1999.
MACT
Floor,
Regulatory
Alternatives,
and
Nationwide
Impacts
for
Storage
Tanks
at
Miscellaneous
Organic
Chemical
Manufacturing
Facilities
Miscellaneous
Organic
NESHAP.
3
Table
1.
Continuous
Vertical
Tanks
with
HAP
Partial
Pressure
=>
1.0
psia
and
IFR
Control
Cost
(
MACT
Floor)

Facil.
#
Tank
ID
Tank
capacity
HAP
partial
pressure
(
psia)
Uncontrolled
HAP
emissions
(
lb/
yr)
Control
device
Control
efficiency
Baseline
HAP
emissions
(
lb/
yr)
HAP
reduction
(
lb/
yr)
TCI
($)
TAC
($/
yr)
CE
($/
ton)

1
M126
CRUDE
DIBASIC
ESTER
TANK/
CDBE
TK/
PD­
20
18,000
1.93
3,880
Vapor
recovery
system
0
3,880
3,686
$
10,604
$
1,856
$
1,007
2
M126
METHANOL
TANK
41/
MEOH
TK
41/
PJ­
14I
50,000
1.93
1,340
None
0
1,340
1,273
$
13,940
$
2,797
$
4,394
3
M126
METHANOL
TANK
41/
MEOH
TK
41/
PP­
130F
50,000
1.93
1,560
None
0
1,560
1,482
$
13,940
$
2,776
$
3,746
4
M146
D­
123
CHILLED
WATER
DRUM/
5­

1­
D123/
5­
1­
11
32,000
1.93
0
None
0
0
0
$
12,393
$
2,600
$
13,684,211
5
M257
FRESH
METHANOL
TANK/
982/
982
59,000
1.93
4,640
IFR
95
232
0
$
0
$
0
NA
6
M257
MOTHER
LIQUOR
TANK­­

10.30/
985/
985
220,000
1.93
12,000
IFR
95
600
0
$
0
$
0
NA
7
M257
MOTHER
LIQUOR
TANK­­

10.31/
986/
986
220,000
1.93
12,000
IFR
95
600
0
$
0
$
0
NA
8
M257
RECOVERED
METHANOL
TANK/
983/
983
220,000
1.93
9,560
IFR
95
478
0
$
0
$
0
NA
9
M257
SEAL
FLUSH
METHANOL
TANK/
984/
984
59,000
1.93
5,200
IFR
95
260
0
$
0
$
0
NA
10
M258
DRY
METHANOL
STORAGE
TANK/
TC104DRYME/
CF104
150,000
1.93
11,600
IFR
95
580
0
$
0
$
0
NA
11
M258
SPENT
HEXANE
STORAGE
TANK/
TC102SPTHX/
CF102
500,000
2.93
27,200
IFR
95
1,360
0
$
0
$
0
NA
12
M262
HEXANE
STORAGE
TANKS
D.

705/
TANKC6D705/
34
130,900
2.93
156,000
Flare
&
condenser
100
468
0
$
0
$
0
NA
13
M262
HEXANE
STORAGE
TANKS
D.

708/
TANKC6D708/
34
40,500
2.93
9,067
Flare
&
condenser
100
27
0
$
0
$
0
NA
14
M270
HEXANE
STORAGE
TANK/
TK­

760/
1796­
04A
80,000
2.93
8,400
IFR
95
420
0
$
0
$
0
NA
15
M270
TANK
STORAGE/
TK­
401/
29
10,000
2.93
2,440
None
0
2,440
2,318
$
8,856
$
1,626
$
1,403
16
M270
TANK
STORAGE/
TK­
902/
03
12,000
2.93
723
None
0
723
687
$
8,947
$
1,808
$
5,265
17
M279
"
B"
PLANT
CONVERTIBLE
TANK/
VS­
14T/
VS­
38
110,000
1.93
2,386
Vaporcondensers
79
492
372
$
18,644
$
3,904
$
20,973
18
M279
CENTRATE
AND
WASH
TANK/
VS­

265T/
VS­
36
375,000
1.93
175
None
0
175
167
$
27,800
$
5,816
$
69,807
19
M279
INHIBITOR
STORAGE
TANK/
VS­

23T/
VS­
44
18,000
1.93
433
None
0
433
412
$
10,295
$
2,119
$
10,293
Table
1.
(
continued)

Facil.
#
Tank
ID
Tank
capacity
HAP
partial
pressure
(
psia)
Uncontrolled
HAP
emissions
(
lb/
yr)
Control
device
Control
efficiency
Baseline
HAP
emissions
(
lb/
yr)
HAP
reduction
(
lb/
yr)
TCI
($)
TAC
($/
yr)
CE
($/
ton)
4
20
M279
METHANOL
STORAGE
TANK/
VS­

15T/
VS­
37
210,000
1.93
883
None
0
883
839
$
22,924
$
4,726
$
11,265
21
M279
METHYL
ACETATE
TANK/
VS­

16T/
VS­
39
84,000
1.93
9
Vaporcondensers
77
2
2
$
17,121
$
3,592
$
4,157,655
22
M279
MILLION
GAL
VAM.
TANK/
VS­

11T/
VS­
11
1,000,000
1.61
17,270
Vaporcondensers
82
3,074
2,211
$
40,364
$
8,429
$
7,626
23
M279
POLYMER
TANK
1/
VS­
236T/
VS­
15
57,000
1.93
2,782
Vaporcondensers
89
306
167
$
14,953
$
3,135
$
37,565
24
M279
POLYMER
TANK
2/
VS­
237T/
VS­
15
57,000
1.93
7,276
Vaporcondensers
89
800
437
$
14,953
$
3,132
$
14,348
25
M279
SODIUM
METHYLATE
(
NAOME
DAY)
TANK/
VS­
20T/
VS­
42
11,000
1.93
0
None
0
0
0
$
8,903
$
1,868
NA
26
M279
VINYL
"
A"
TANK/
VS­
07T/
VS­
10
375,000
1.61
8,784
None
0
8,784
8,345
$
27,800
$
4,998
$
1,198
27
M279
VINYL
"
B"
TANK/
VS­
08T/
VS­
10
375,000
1.61
6,919
None
0
6,919
6,573
$
27,800
$
5,175
$
1,575
28
M279
VINYL
"
C"
DAY
TANK/
VS­
10T/
VS­

10
158,000
1.61
944
None
0
944
897
$
20,653
$
4,243
$
9,461
29
M279
VINYL
"
C"
TANK/
VS­
09T/
VS­
10
375,000
1.61
8,684
None
0
8,684
8,249
$
27,800
$
5,007
$
1,214
30
M279
VINYL
ACETATE
"
A"
DAY
TANK/
VS­
05T/
VS­
10
158,000
1.61
5,765
None
0
5,765
5,477
$
20,653
$
3,785
$
1,382
31
M279
VINYL
ACETATE
"
B"
DAY
TANK/
VS­
06T/
VS­
10
158,000
1.61
4,745
None
0
4,745
4,508
$
20,653
$
3,882
$
1,722
32
M279
VINYL
ACETATE
(
A
DISTILLATE)

TANK/
VS­
18T/
VS­
41
95,000
1.75
200
Vaporcondensers
83
34
24
$
17,857
$
3,746
$
312,167
33
M279
VINYL
ACETATE
(
B
DISTILLATE)

TANK/
VS­
268T/
VS­
41
95,000
1.75
358
Vaporcondensers
83
61
43
$
17,857
$
3,746
$
174,567
34
M279
WASHWATER
TANK/
VS­
218T/
VS­

366
37,000
1.93
89
None
0
89
85
$
13,079
$
2,736
$
64,719
35
M280
A
CRUDE
RECEIVER
TANK/
04TFX030A/
04TVS­
030
38,000
1.93
3
None
0
3
3
$
13,105
$
2,749
$
1,702,167
36
M280
B
CRUDE
RECEIVER
TANK/
04TFX030B/
04TVS­
030
38,000
1.93
22
None
0
22
21
$
13,105
$
2,747
$
267,739
37
M280
BIG
A
CRUDE
TANK/
04TFX034A/
04TVS­
034
552,000
1.93
84
None
0
84
80
$
31,893
$
6,683
$
167,096
38
M280
BIG
B
CRUDE
TANK/
04TFX034B/
04TVS­
034
552,000
1.93
8
None
0
8
8
$
31,893
$
6,690
$
1,676,692
Table
1.
(
continued)

Facil.
#
Tank
ID
Tank
capacity
HAP
partial
pressure
(
psia)
Uncontrolled
HAP
emissions
(
lb/
yr)
Control
device
Control
efficiency
Baseline
HAP
emissions
(
lb/
yr)
HAP
reduction
(
lb/
yr)
TCI
($)
TAC
($/
yr)
CE
($/
ton)
5
39
M280
CRUDE
KA
TANK
­
OP
1A/
06TFX044/
06TFX­
044
104,000
1.93
18
None
0
18
17
$
18,244
$
3,826
$
457,656
40
M280
E
REWORK
TANK/
04TFX026/
04TFX­
026
160,000
1.93
4
None
0
4
4
$
20,678
$
4,338
$
2,403,324
41
M280
F
CRUDE
DCH
STORAGE
TANK/
04TFX025/
04TFX­
025
160,000
1.93
22
None
0
22
21
$
20,678
$
4,336
$
407,519
42
M280
HMI
STORAGE
TANK/
04TFX033C/
04TVS­
033
19,000
1.93
5
None
0
5
5
$
10,330
$
2,167
$
912,421
43
M280
NO.
2
RECYCLE
VA
TANK/
05TFL023/
05TFL­
023
50,000
1.61
18,716
IFR
95
936
0
$
0
$
0
NA
44
M280
NO.
3
TWKA
RECEIVER
TANK
­
OP
1A/
06TFX042/
06TFX­
042
50,000
1.93
15
None
0
15
14
$
13,940
$
2,923
$
404,848
45
M280
NO.
3
TWKA
STORAGE
TANK
­
OP
1/
1A/
06TFX013/
06TFX­
013
500,000
1.93
2
None
0
2
2
$
30,975
$
6,498
$
8,550,000
46
M280
NO.
4
TWKA
RECEIVER
TANK
­
OP
1A/
06TFX043/
06TFX­
043
50,000
1.93
15
None
0
15
14
$
13,940
$
2,923
$
404,848
47
M280
RECYCLE
AQUA
COLUMN
TAILS
TANK/
04TFX031/
04TFX­
031
12,000
1.93
0
None
0
0
0
$
8,947
$
1,877
$
19,757,895
48
M280
VINYL
ACETATE
TANK/
05TFL018/
05TFL­
018
100,000
1.61
18,716
IFR
95
936
0
$
0
$
0
NA
49
M280
WASTE
COLLECTION
TANK/
11TFX076/
11TFX­
076
11,000
1.93
0
None
0
0
0
$
8,903
$
1,868
$
19,663,158
50
M280
WASTE
ORGANIC
STORAGE
TANK/
04TFX027/
04TFX­
027
18,000
1.93
215
None
0
215
204
$
10,295
$
2,139
$
20,964
51
M281
CRUDE
NPG
TANK/
OX050T191/
050T191
40,000
1.93
460
0
460
437
$
13,464
$
2,781
$
12,728
52
M281
MIX
TANK/
EP008T34/
008T34
14,000
1.93
38
0
38
36
$
9,896
$
2,073
$
114,848
53
M281
MOLTEN
STORAGE
TANK­
C­

13/
EB065T74/
030B11
93,280
2.93
562
0
562
534
$
17,829
$
3,687
$
13,812
54
M281
MOLTEN
STORAGE
TANK­
C­

13/
EB065T74/
030B11
93,280
2.93
562
Vapor
recovery
0
562
534
$
17,829
$
3,687
$
13,812
55
M281
REJECT
TANK/
OX050T138/
050T138
50,000
1.93
10
0
10
10
$
14,250
$
2,989
$
629,263
56
M281
STORAGE
TANK
40T­

114/
SD022T114/
022T114
215,000
13.29
2,300
0
2,300
2,185
$
23,288
$
4,667
$
4,272
57
M281
STORAGE
TANK
43
T­

162/
OX026T162/
027FL1
33,000
13.29
420
0
420
399
$
12,730
$
2,631
$
13,188
Table
1.
(
continued)

Facil.
#
Tank
ID
Tank
capacity
HAP
partial
pressure
(
psia)
Uncontrolled
HAP
emissions
(
lb/
yr)
Control
device
Control
efficiency
Baseline
HAP
emissions
(
lb/
yr)
HAP
reduction
(
lb/
yr)
TCI
($)
TAC
($/
yr)
CE
($/
ton)
6
58
M281
STORAGE
TANK/
EP008T51/
008T51
12,000
1.83
60
0
60
57
$
9,257
$
1,936
$
67,930
59
M281
STORAGE
TANK/
OX026T35/
027FL1
17,000
13.29
60
0
60
57
$
10,567
$
2,211
$
77,579
60
M281
TANK
STORAGE/
OX026T32/
027FL1
25,600
13.29
240
0
240
228
$
11,964
$
2,487
$
21,816
61
M283
HEXANE
STORAGE
TANK
4702/
T­

101/
T­
101
160,000
2.93
22,000
IFR
95
1,100
0
$
0
$
0
NA
62
M283
HEXANE
STORAGE
TANK
4703/
T­

102/
T­
102
53,000
2.93
18,000
IFR
95
900
0
$
0
$
0
NA
63
M289
TANK
2T­
502/
5T6030/
5T6030
85,140
2.93
320
IFR
95
16
0
$
0
$
0
NA
64
M289
TANK
2T­
503/
5T6050/
5T6050
85,140
2.93
320
IFR
95
16
0
$
0
$
0
NA
65
M289
TANK
T­
501/
5T6010/
5T6010
85,140
2.93
320
IFR
95
16
0
$
0
$
0
NA
66
M289
TANK
T­
502/
5T6020/
5T6020
85,140
2.93
120
IFR
95
6
0
$
0
$
0
NA
67
M289
TANK
T­
503/
5T6040/
5T6040
85,140
2.93
320
IFR
95
16
0
$
0
$
0
NA
68
M293
STORAGE
TANK/
130T­
F402/

130TF402
451,000
1.68
0
None
0
0
0
$
30,061
$
6,307
$
33,194,737
69
M293
STORAGE
TANK/
130T­
F622/

130TF622
24,000
1.68
507
None
0
507
482
$
11,051
$
2,270
$
9,422
70
M300
TANK
4845/
AP1T4845/
AP1T4845
21,000
1.93
318
None
0
318
302
$
10,953
$
2,268
$
15,015
71
M300
TANK
4846/
AP1T4846/
AP1T4846
42,000
1.71
81
None
0
81
77
$
13,203
$
2,762
$
71,787
72
M300
TANK
4914/
AP1T4914/
AP1T4914
109,000
2.93
200
IFR
95
10
0
$
0
$
0
NA
73
M306
TANK/
2A/
2A
20,700
2.93
1,280
None
0
1,280
1,216
$
10,943
$
2,174
$
3,576
74
M306
TANK/
2B/
2B
20,700
2.93
1,280
None
0
1,280
1,216
$
10,943
$
2,174
$
3,576
75
M343
R­
1372
SCRUBBER/
TKR372
10,000
1.93
12
None
0
12
11
$
8,856
$
1,857
$
325,789
76
M358
2­
16,900
GALLON
RESIN
STORAGE
TANKS/
17
33,800
1.93
7,765
None
0
7,765
7,377
$
12,442
$
1,873
$
508
77
M358
2­
9,800
GALLON
ROSIN
PRODUCT
TANKS/
15
19,600
1.93
3,882
None
0
3,882
3,688
$
10,351
$
1,803
$
978
78
M358
3­
150,000
GALLON
POND
PITCH/
HEADS
TANKS/
18
450,000
1.93
4,500
None
0
4,500
4,275
$
30,053
$
5,878
$
2,750
79
M358
NEW
ROSIN
TANK,
ST­
25,
PT
SOURCE
12­
87/
50
15,200
1.93
3,882
None
0
3,882
3,688
$
9,635
$
1,653
$
896
80
M358
RESIN
PRODUCT
STORAGE
TANK,
RS­
21,
PT.
SOURCE
15/
93
30,000
1.93
3,882
None
0
3,882
3,688
$
11,783
$
2,103
$
1,140
81
M358
RXN.
OIL,
HEADS
OR
PITCH
STORAGE
TANK/
23
20,000
1.93
4,500
None
0
4,500
4,275
$
10,365
$
1,747
$
817
Table
1.
(
continued)

Facil.
#
Tank
ID
Tank
capacity
HAP
partial
pressure
(
psia)
Uncontrolled
HAP
emissions
(
lb/
yr)
Control
device
Control
efficiency
Baseline
HAP
emissions
(
lb/
yr)
HAP
reduction
(
lb/
yr)
TCI
($)
TAC
($/
yr)
CE
($/
ton)
7
82
M44
1100
PROCESS
AREA/
FA1100P/
EA1100PU
10,000
1.43
2,916
None
0
2,916
2,770
$
8,856
$
1,581
$
1,141
83
M44
1100
PROCESS
AREA/
FA1100P/
EA11LD1100
10,000
1.38
108
None
0
108
103
$
8,856
$
1,848
$
36,023
84
M44
T­
352,353,&
354/
FB03T0354/
EB0300TU
30,000
1.93
130
None
0
130
124
$
11,783
$
2,460
$
39,838
85
M44
T­
352,353,&
354/
FB03T0354/
EB03CT35
4
30,000
1.93
18
Process
change
0
18
17
$
12,093
$
2,535
$
296,491
86
M44
TANK
364/
FB03T0364/
EB03CT364
48,000
1.93
113
Vaporcondensers
68
36
30
$
14,205
$
2,979
$
196,148
87
M44
TANK
T­
382/
FB03T0382/
EB03FL1
100,000
1.93
14,600
Flare­
waste
gas,
ground­

(<
30ft.)
98
292
0
$
0
$
0
NA
88
M44
TANKS
360
AND
361/
FB03T0361/
EB03CT361
250,000
1.93
7,938
Vaporcondensers
68
2,540
2,143
$
24,761
$
5,126
$
4,784
89
M44
TANKS
500­

512/
FA05T500B/
EA0500BTU
37,000
1.68
1,448
None
0
1,448
1,376
$
13,079
$
2,607
$
3,790
90
M44
TANKS
520­
529,547,551,552/
FA05T500C/
EA0500
CTU
25,000
1.68
1,450
None
0
1,450
1,378
$
11,082
$
2,187
$
3,175
91
M44
TANKS
520­
529,547,551,552/
FA05T500C/
EA05S
K501
25,000
1.68
5,040
Scrubber
0
5,040
4,788
$
11,391
$
1,911
$
798
92
M44
TANKS
530,531,532,533,534,535/
FA05T500D
/
EA0500DTU
25,000
1.73
766
None
0
766
728
$
11,082
$
2,252
$
6,189
Totals
483,887
112,870
96,872
$
1,134,616
$
228,770
$
4,723
National
Totals
967,774
225,741
193,744
$
2,269,232
$
457,540