Document ID: EPA-HQ-OW-2003-0003-0012
Agency: epa
Document Type: Supporting & Related Material
Title: 
Posted Date: 2003-03-12T05:00Z

Episode
6000
Data
APPENDIX
B
­
3
­
1
Page
1
of
32Standard
Deviations
vs
Spike
Concentrations
(
Original
Scale)

1.4
1.2
1.0
0.8
0.6
0.4
0.06
0.05
0.04
0.03
0.02
0.01
0.0
150
100
50
0
250
200
150
100
50
0
Classicals,
Method
130.2Classicals,
130.2
HARDNESS,
MG/
LHARDNESS,
L
0
50
100
150
0.0
0.2
0.4
0.6
0.8
1.0
0
5000
10000
15000
20000
25000
0
5000
10000
15000
20000
25000
Classicals,
Method
350.3Classicals,
350.3
AMMONIA
AS
NITROGEN,
MG/
LAMMONIA
L
Metals,
Method
ICP/
MSMetals,
MS
Cd
111,
pptCd
ppt
Metals,
Method
ICP/
MSMetals,
MS
Pb
206,
pptPb
ppt
1.5
1.0
0.5
0.0
0.006
0.005
0.004
0.003
0.002
140
120
100
80
60
40
20
0
200
150
100
50
0
Classicals,
Method
160.2Classicals,
160.2
TOTAL
SUSPENDED
SOLIDS,
MG/
LTOTAL
L
0
50
100
150
200
0.0
0.2
0.4
0.6
0.8
1.0
0
5000
10000
15000
20000
25000
0
5000
10000
15000
20000
25000
Classicals,
Method
365.2Classicals,
365.2
TOTAL
PHOSPHORUS,
MG/
LTOTAL
L
Metals,
Method
ICP/
MSMetals,
MS
Cu
63,
pptCu
ppt
Metals,
Method
ICP/
MSMetals,
MS
Pb
207,
pptPb
ppt
0.4
0.3
0.2
0.1
250
200
150
100
50
0
250
200
150
100
50
0
250
200
150
100
50
0
Classicals,
Method
1677Classicals,
1677
WAD
CYANIDE,
UG/
LWAD
L
0
1020304050
0
5000
10000
15000
20000
25000
0
5000
10000
15000
20000
25000
0
5000
10000
15000
20000
25000
Metals,
Method
ICP/
MSMetals,
MS
Ag
107,
pptAg
ppt
Metals,
Method
ICP/
MSMetals,
MS
Ni
60,
pptNi
ppt
Metals,
Method
ICP/
MSMetals,
MS
Pb
208,
pptPb
ppt
Observed
Standard
Deviation
Spike
Concentration
100
0
0
5000
10000
15000
20000
25000
0
5000
10000
15000
20000
25000
300
250
Metals,
Method
ICP/
MSMetals,
MS
Zn
66,
pptZn
ppt
150
200
100
150
100
50
50
00
0
5000
10000
15000
20000
25000
0
200
400
600
800
1000
1200
Metals,
Method
1620Metals,
1620
ALUMINUM,
UG/
LALUMINUM,
L
1.2
1.2
1.0
1.0
0.8
Metals,
Method
1620Metals,
1620
ARSENIC,
UG/
LARSENIC,
L
0.8
0.6
0.6
0.4
0.4
0.2
Metals,
Method
1620Metals,
1620
BARIUM,
UG/
LBARIUM,
L
0
20
40
60
0
204060
0.20
25
20
Metals,
Method
1620Metals,
1620
BORON,
UG/
LBORON,
L
0.15
15
0.10
10
0.05
5
Metals,
Method
1620Metals,
1620
CADMIUM,
UG/
LCADMIUM,
L
0
500
1000
1500
0
5
10
15
Mon
Mar
18
16:
03:
03
2002
Spike
Concentration
Metals,
Method
ICP/
MSMetals,
MS
Sb
123,
pptSb
ppt
Metals,
Method
ICP/
MSMetals,
MS
Se
82,
pptSe
ppt
Episode
6000
Data
Page
2
of
32Standard
Deviations
vs
Spike
Concentrations
(
Original
Scale)

600
300
200
500
250
150
400
200
100
300
150
100200
50
50
0
0
5000
10000
15000
20000
25000
1.2
1.0
0.8
0.6
0.4
0
20
40
60
80
100
Metals,
Method
1620Metals,
1620
ANTIMONY,
UG/
LANTIMONY,
L
2.0
1.5
1.0
0.5
Metals,
Method
1620Metals,
1620
BERYLLIUM,
UG/
LBERYLLIUM,
L
0
102030405060
20
15
10
5
0
200
400
600
800
1000
1200
1400
c:/
pw/
ostmdl/
req004/
r004sd1.
s
Metals,
Method
1620Metals,
1620
CALCIUM,
UG/
LCALCIUM,
L
Metals,
Method
ICP/
MSMetals,
MS
Tl
205,
pptTl
ppt
Observed
Standard
Deviation
Episode
6000
Data
Page
3
of
32Standard
Deviations
vs
Spike
Concentrations
(
Original
Scale)

Metals,
Method
1620Metals,
1620
CHROMIUM,
UG/
LCHROMIUM,
L
0.2
0
20406080
300
200
100
0
0
200
400
600
800
Metals,
Method
1620Metals,
1620
IRON,
UG/
LIRON,
L
3
2
1
Metals,
Method
1620Metals,
1620
MANGANESE,
UG/
LMANGANESE,
L
0
20
40
60
80
100
120
1.5
1.0
0.5
Metals,
Method
1620Metals,
1620
SELENIUM,
UG/
LSELENIUM,
L
0
20
40
60
80
100
120
0.8
0.6
0.4
15
10
5
Metals,
Method
1620Metals,
1620
COBALT,
UG/
LCOBALT,
L
0
200
400
600
800
1000
1200
2.5
2.0
1.5
1.0
0.5
0
50
100
150
200
250
Metals,
Method
1620Metals,
1620
LEAD,
UG/
LLEAD,
L
2.0
1.5
1.0
0.5
0
50
100
150
200
6
Metals,
Method
1620Metals,
1620
MOLYBDENUM,
UG/
LMOLYBDENUM,
L
5
4
3
2
0
100
200
300
400
500
Metals,
Method
1620Metals,
1620
SILVER,
UG/
LSILVER,
L
Metals,
Method
1620Metals,
1620
COPPER,
UG/
LCOPPER,
L
0
100
200
300
Metals,
Method
1620Metals,
1620
MAGNESIUM,
UG/
LMAGNESIUM,
L
0
1000
2000
3000
4000
5000
Metals,
Method
1620Metals,
1620
NICKEL,
UG/
LNICKEL,
L
0
500
1000
1500
Metals,
Method
1620Metals,
1620
SODIUM,
UG/
LSODIUM,
L
0
1000
2000
3000
4000
10
8
6
4
2
60
50
40
30
20
30
25
20
15
10
5
70
60
50
40
30
20
Observed
Standard
Deviation
Mon
Mar
18
16:
03:
16
2002
Spike
Concentration
c:/
pw/
ostmdl/
req004/
r004sd1.
s
Episode
6000
Data
Page
4
of
32Standard
Deviations
vs
Spike
Concentrations
(
Original
Scale)
3.5
0.7
0.6
0.5
0.4
0.3
0.2
15
10
5
30
25
20
15
10
5
0
0.15
0.10
0.05
0.0
Metals,
Method
1620Metals,
1620
THALLIUM,
UG/
LTHALLIUM,
L
3.0
2.5
2.0
1.5
1.0
0.5
0
20406080
0
100
200
300
Metals,
Method
1620Metals,
1620
TIN,
UG/
LTIN,
L
2.0
1.5
1.0
0.5
Metals,
Method
1620Metals,
1620
YTTRIUM,
UG/
LYTTRIUM,
L
0
200
400
600
0
20406080
0.15
0.10
0.05
0.0
0
2004006008001000
0
2
4
6
8
10
Metals,
Method
200.8Metals,
200.8
ANTIMONY,
UG/
LANTIMONY,
L
0.15
0.10
0.05
0.0
0
5
10
15
20
012345
Metals,
Method
200.8Metals,
200.8
BERYLLIUM,
UG/
LBERYLLIUM,
L
Metals,
Method
1620Metals,
1620
VANADIUM,
UG/
LVANADIUM,
L
Metals,
Method
200.8Metals,
200.8
ALUMINUM,
UG/
LALUMINUM,
L
Metals,
Method
200.8Metals,
200.8
BARIUM,
UG/
LBARIUM,
L
4
3
2
1
14
12
10
8
6
4
2
0
1.5
1.0
0.5
0.0
0.030
0.025
0.020
0.015
0.010
0.005
0.0
Metals,
Method
1620Metals,
1620
TITANIUM,
UG/
LTITANIUM,
L
0
100
200
300
Metals,
Method
1620Metals,
1620
ZINC,
UG/
LZINC,
L
0
50
100
150
200
250
Metals,
Method
200.8Metals,
200.8
ARSENIC,
UG/
LARSENIC,
L
0
20
40
60
80
100
Metals,
Method
200.8Metals,
200.8
CADMIUM,
UG/
LCADMIUM,
L
0.0
0.5
1.0
1.5
2.0
Observed
Standard
Deviation
Mon
Mar
18
16:
03:
29
2002
Spike
Concentration
c:/
pw/
ostmdl/
req004/
r004sd1.
s
Episode
6000
Data
Page
5
of
32Standard
Deviations
vs
Spike
Concentrations
(
Original
Scale)

0.35
0.30
Metals,
Method
200.8Metals,
200.8
CHROMIUM,
UG/
LCHROMIUM,
L
0.03
0.25
0.20
0.02
0.15
0.01
0.10
0.05
0.0
0
5
101520
0.8
0.06
0.6
0.04
0.4
0.2
Metals,
Method
200.8Metals,
200.8
LEAD,
UG/
LLEAD,
L
0.02
0.0
0.0
0
1020304050
0.20
Metals,
Method
200.8Metals,
200.8
MOLYBDENUM,
UG/
LMOLYBDENUM,
L
1.0
0.8
0.15
0.6
0.10
0.4
0.05
0.2
0.0
0.0
0.0
0.2
0.4
0.6
0.8
1.0
0.025
Metals,
Method
200.8Metals,
200.8
SILVER,
UG/
LSILVER,
L
0.0020
0.020
0.0015
0.015
0.0010
0.010
0.005
0.0005
0.0
0.0
0.2
0.4
0.6
0.8
1.0
Mon
Mar
18
16:
03:
44
2002
Metals,
Method
200.8Metals,
200.8
COBALT,
UG/
LCOBALT,
L
0.0
0.2
0.4
0.6
0.8
1.0
0.0
0.5
1.0
1.5
2.0
0
2
4
6
810
0.0
0.05
0.10
0.15
0.20
Spike
Concentration
Metals,
Method
200.8Metals,
200.8
MANGANESE,
UG/
LMANGANESE,
L
Metals,
Method
200.8Metals,
200.8
NICKEL,
UG/
LNICKEL,
L
Metals,
Method
200.8Metals,
200.8
THALLIUM,
UG/
LTHALLIUM,
L
0.6
0.5
0.4
0.3
0.2
0.1
0.0
0.30
0.25
0.20
0.15
0.10
0.05
0.0
1.5
1.0
0.5
0.0
0.025
0.020
0.015
0.010
0.005
0.0
Metals,
Method
200.8Metals,
200.8
COPPER,
UG/
LCOPPER,
L
0
5
101520
0
2
4
6
810
0.0
0.2
0.4
0.6
0.8
1.0
c:/
pw/
ostmdl/
req004/
r004sd1.
s
Metals,
Method
200.8Metals,
200.8
MERCURY,
UG/
LMERCURY,
L
Metals,
Method
200.8Metals,
200.8
SELENIUM,
UG/
LSELENIUM,
L
0
20
40
60
80
100
Metals,
Method
200.8Metals,
200.8
THORIUM,
UG/
LTHORIUM,
L
Observed
Standard
Deviation
Episode
6000
Data
Page
6
of
32Standard
Deviations
vs
Spike
Concentrations
(
Original
Scale)

Observed
Standard
Deviation
0.0020
0.0015
0.0010
0.0005
0.0
0.0
0.02
0.04
0.06
0.08
0.10
Metals,
Method
200.8Metals,
200.8
URANIUM,
UG/
LURANIUM,
L
0.5
0.4
0.3
0.2
0.1
0.0
0
24
6810
Organics,
Method
502.2­
ELCDOrganics,
ELCD
1,1,1,2­
TETRACHLOROETHANE,
UG/
L1,1,1,2­
L
0.4
0.3
0.2
0.1
0.0
0
24
6810
Organics,
Method
502.2­
ELCDOrganics,
ELCD
1,1,2­
TRICHLOROETHANE,
UG/
L1,1,2­
L
0.6
0.4
0.2
0.0
0
2
4
6
810
Organics,
Method
502.2­
ELCDOrganics,
ELCD
1,2,3­
TRICHLOROBENZENE,
UG/
L1,2,3­
L
Mon
Mar
18
16:
04:
01
2002
2.5
2.0
1.5
1.0
0.5
Metals,
Method
200.8Metals,
200.8
VANADIUM,
UG/
LVANADIUM,
L
0
50
100
150
200
0.6
0.4
0.2
0.0
02
46
810
Organics,
Method
502.2­
ELCDOrganics,
ELCD
1,1,1­
TRICHLOROETHANE,
UG/
L1,1,1­
L
0.5
0.4
0.3
0.2
0.1
0.0
02
46
810
Organics,
Method
502.2­
ELCDOrganics,
ELCD
1,1­
DICHLOROETHANE,
UG/
L1,1­
L
0.5
0.4
0.3
0.2
0.1
0.0
0
2
4
6
810
Organics,
Method
502.2­
ELCDOrganics,
ELCD
1,2,4­
TRICHLOROBENZENE,
UG/
L1,2,4­
L
Spike
Concentration
6
5
4
3
2
1
0
1.4
1.2
1.0
0.8
0.6
0.4
0.2
0.0
0
0.6
0.5
0.4
0.3
0.2
0.1
0.0
0.3
0.2
0.1
0.0
Metals,
Method
200.8Metals,
200.8
ZINC,
UG/
LZINC,
L
0
50
100
150
200
Organics,
Method
502.2­
ELCDOrganics,
ELCD
1,1,2,2­
TCE+
1,2,3­
TCP,
UG/
L1,1,2,2­
L
5
10
15
20
Organics,
Method
502.2­
ELCDOrganics,
ELCD
1,1­
DICHLOROETHENE,
UG/
L1,1­
L
0
2
4
6
810
Organics,
Method
502.2­
ELCDOrganics,
ELCD
1,2­
DIBROMOETHANE,
UG/
L1,2­
L
0
2
4
6
810
c:/
pw/
ostmdl/
req004/
r004sd1.
s
Episode
6000
Data
Page
7
of
32Standard
Deviations
vs
Spike
Concentrations
(
Original
Scale)

0.5
0.4
0.3
0.2
0.1
0.0
0
2
4
6
810
Organics,
Method
502.2­
ELCDOrganics,
ELCD
1,2­
DICHLOROBENZENE,
UG/
L1,2­
L
0.4
0.3
0.2
0.1
0.0
0
2
4
6
810
Organics,
Method
502.2­
ELCDOrganics,
ELCD
1,3­
DICHLOROBENZENE,
UG/
L1,3­
L
1.2
1.0
0.8
0.6
0.4
0.2
0.0
0
2
4
6
810
Organics,
Method
502.2­
ELCDOrganics,
ELCD
2­
CHLOROTOLUENE,
UG/
L2­
L
0.5
0.4
0.3
0.2
0.1
0.0
0
2
4
6
810
Organics,
Method
502.2­
ELCDOrganics,
ELCD
BROMOCHLOROMETHANE,
UG/
LBROMOCHLOROMETHANE,
L
Mon
Mar
18
16:
04:
15
2002
0.8
0.6
0.4
0.2
0.0
0.4
0.3
0.2
0.1
0.0
1.5
1.0
0.5
0.0
0.4
0.3
0.2
0.1
0.0
Organics,
Method
502.2­
ELCDOrganics,
ELCD
1,2­
DICHLOROETHANE,
UG/
L1,2­
L
0.5
0.4
0.3
0.2
0.1
0.0
0246810
0246810
Organics,
Method
502.2­
ELCDOrganics,
ELCD
1,2­
DICHLOROPROPANE,
UG/
L1,2­
L
0.4
0.3
0.2
0.1
0.0
0246810
0246810
Organics,
Method
502.2­
ELCDOrganics,
ELCD
1,4­
DICHLOROBENZENE,
UG/
L1,4­
L
0.6
0.5
0.4
0.3
0.2
0.1
Organics,
Method
502.2­
ELCDOrganics,
ELCD
BROMOBENZENE,
UG/
LBROMOBENZENE,
L
0246810
0246810
0.3
0.2
0.1
0.0
0246810
0246810
Organics,
Method
502.2­
ELCDOrganics,
ELCD
BROMOFORM,
UG/
LBROMOFORM,
L
Spike
Concentration
c:/
pw/
ostmdl/
req004/
r004sd1.
s
Organics,
Method
502.2­
ELCDOrganics,
ELCD
1,3­
DICHLOROPROPANE,
UG/
L1,3­
L
Organics,
Method
502.2­
ELCDOrganics,
ELCD
4­
CHLOROTOLUENE,
UG/
L4­
L
Organics,
Method
502.2­
ELCDOrganics,
ELCD
BROMODICHLOROMETHANE,
UG/
LBROMODICHLOROMETHANE,
L
Observed
Standard
Deviation
Episode
6000
Data
Page
8
of
32Standard
Deviations
vs
Spike
Concentrations
(
Original
Scale)

0.5
0.25
0.20
0.15
0.10
Organics,
Method
502.2­
ELCDOrganics,
ELCD
BROMOMETHANE,
UG/
LBROMOMETHANE,
L
2
4
6
810
0.4
0.3
0.2
0.1
0.0
0
2
4
6
810
Organics,
Method
502.2­
ELCDOrganics,
ELCD
CHLOROETHANE,
UG/
LCHLOROETHANE,
L
1.2
1.0
0.8
0.6
0.4
0.2
0.0
0
5
101520
Organics,
Method
502.2­
ELCDOrganics,
ELCD
CIS­
1,2­
DCE+
2,2­
DCP,
UG/
LCIS­
L
0.4
0.3
0.2
0.1
0.0
0
2
4
6
810
Organics,
Method
502.2­
ELCDOrganics,
ELCD
DIBROMOMETHANE,
UG/
LDIBROMOMETHANE,
L
1.2
1.0
0.8
0.6
0.4
0.2
0.0
0.6
0.5
0.4
0.3
0.2
0.1
0.0
0.5
0.4
0.3
0.2
0.1
0.0
2.0
1.5
1.0
0.5
0.0
Organics,
Method
502.2­
ELCDOrganics,
ELCD
CARBONTET+
1,1­
DCP,
UG/
LCARBONTET+
L
0
5
101520
Organics,
Method
502.2­
ELCDOrganics,
ELCD
CHLOROFORM,
UG/
LCHLOROFORM,
L
02
46
810
Organics,
Method
502.2­
ELCDOrganics,
ELCD
CIS­
1,3­
DICHLOROPROPENE,
UG/
LCIS­
L
02
46
810
Organics,
Method
502.2­
ELCDOrganics,
ELCD
DICHLORODIFLUOROMETHANE,
UG/
LDICHLORODIFLUOROMETHANE,
L
02
46
810
Organics,
Method
502.2­
ELCDOrganics,
ELCD
CHLOROBENZENE,
UG/
LCHLOROBENZENE,
L
02468
Organics,
Method
502.2­
ELCDOrganics,
ELCD
CHLOROMETHANE,
UG/
LCHLOROMETHANE,
L
02468
Organics,
Method
502.2­
ELCDOrganics,
ELCD
DIBROMOCHLOROMETHANE,
UG/
LDIBROMOCHLOROMETHANE,
L
02468
Organics,
Method
502.2­
ELCDOrganics,
ELCD
HEXACHLOROBUTADIENE,
UG/
LHEXACHLOROBUTADIENE,
L
0
2
4
6
810
0.4
0.3
0.2
0.1
0.0
0.3
0.2
0.1
0.0
0.3
0.2
0.1
0.0
0.6
0.5
0.4
0.3
0.2
0.1
0.0
Observed
Standard
Deviation
Mon
Mar
18
16:
04:
28
2002
Spike
Concentration
c:/
pw/
ostmdl/
req004/
r004sd1.
s
10
10
10
Episode
6000
Data
Page
9
of
32Standard
Deviations
vs
Spike
Concentrations
(
Original
Scale)
0.6
0
2
4
6
810
Organics,
Method
502.2­
ELCDOrganics,
ELCD
METHYLENE
CHLORIDE,
UG/
LMETHYLENE
L
Organics,
Method
502.2­
ELCDOrganics,
ELCD
TRANS­
1,3­
DICHLOROPROPENE,
UG/
LTRANS­
L
0
2
4
6
810
Organics,
Method
502.2­
ELCDOrganics,
ELCD
VINYL
CHLORIDE,
UG/
LVINYL
L
0
2
46810
Organics,
Method
502.2­
PIDOrganics,
PID
1,2,4­
TRIMETHYLBENZENE,
UG/
L1,2,4­
L
0
2
4
6
810
0.5
Organics,
Method
502.2­
ELCDOrganics,
ELCD
TETRACHLOROETHENE,
UG/
LTETRACHLOROETHENE,
L
0.4
0.3
0.2
0.1
0.0
0246810
02468
Organics,
Method
502.2­
ELCDOrganics,
ELCD
TRANS­
1,2­
DICHLOROETHENE,
UG/
LTRANS­
L
0.8
0.6
0.4
0.2
0.0
0.4
0.3
0.2
0.1
0.0
0.3
0.2
0.1
0.5
0.4
0.3
0.2
0.1
0.0
0.5
0.4
0.3
0.2
0.1
0.0
0.6
0.4
0.2
0.0
0.4
0.3
0.2
0.1
0.0
0.5
0.4
0.3
0.2
0.1
0.0
Organics,
Method
502.2­
ELCDOrganics,
ELCD
TRICHLOROETHENE,
UG/
LTRICHLOROETHENE,
L
6.835908*
10^­
6
1.000055*
10^­
1
2.000041*
10^­
1
3.000027*
10^­
1
4.000013*
10^­
1
02
46
810
Organics,
Method
502.2­
PIDOrganics,
PID
1,2,3­
TRICHLOROBENZENE,
UG/
L1,2,3­
L
0
2
4
6
810
Organics,
Method
502.2­
PIDOrganics,
PID
1,2­
DICHLOROBENZENE,
UG/
L1,2­
L
0
2
4
6
810
5*
10^­
1
Organics,
Method
502.2­
ELCDOrganics,
ELCD
TRICHLOROFLUOROMETHANE,
UG/
LTRICHLOROFLUOROMETHANE,
L
02468
Organics,
Method
502.2­
PIDOrganics,
PID
1,2,4­
TRICHLOROBENZENE,
UG/
L1,2,4­
L
02468
Organics,
Method
502.2­
PIDOrganics,
PID
1,3,5­
TMB+
4­
CHLOROTOLUENE,
UG/
L1,3,5­
L
0
5
101520
Observed
Standard
Deviation
0.4
0.3
0.2
0.1
0.0
0.8
0.6
0.4
0.2
0.0
Mon
Mar
18
16:
04:
44
2002
Spike
Concentration
c:/
pw/
ostmdl/
req004/
r004sd1.
s
10
10
10
Episode
6000
Data
0.5
0.4
0.3
0.2
0.1
0.0
0
246
810
Organics,
Method
502.2­
PIDOrganics,
PID
1,3­
DICHLOROBENZENE,
UG/
L1,3­
L
0.4
0.3
0.2
0.1
0.0
0
2
4
6
810
Organics,
Method
502.2­
PIDOrganics,
PID
BROMOBENZENE,
UG/
LBROMOBENZENE,
L
0.6
0.5
0.4
0.3
0.2
0.1
0.0
0
2
4
6
810
Organics,
Method
502.2­
PIDOrganics,
PID
ETHYLBENZENE,
UG/
LETHYLBENZENE,
L
1.0
0.8
0.6
0.4
0.2
0.0
0
5
101520
Organics,
Method
502.2­
PIDOrganics,
PID
M+
P
XYLENE,
UG/
LM+
L
Mon
Mar
18
16:
05:
01
2002
0.5
0.5
0.4
0.4
0.3
Organics,
Method
502.2­
PIDOrganics,
PID
2­
CHLOROTOLUENE,
UG/
L2­
L
0.3
0.2
0.2
0.1
0.1
0.0
0
2
4
6
810
0.5
Organics,
Method
502.2­
PIDOrganics,
PID
CHLOROBENZENE,
UG/
LCHLOROBENZENE,
L
0.6
0.4
0.5
0.4
0.3
0.3
0.2
0.2
0.1
0.1
0.0
0.0
02
46810
0.5
0.5
0.4
0.4
0.3
0.3
0.2
0.2
0.1
0.1
0.0
0
5
101520
Organics,
Method
502.2­
PIDOrganics,
PID
HEXCHLOBUTADIENE+
NAPHTHALENE,
UG/
LHEXCHLOBUTADIENE+
L
0.4
0.4
0.3
0.3
0.2
Organics,
Method
502.2­
PIDOrganics,
PID
N­
BUTYLBENZENE,
UG/
LN­
L
0.2
0.1
0.1
0.0
0.0
02
46810
Spike
Concentration
Page
10
of
32Standard
Deviations
vs
Spike
Concentrations
(
Original
Scale)

Observed
Standard
Deviation
Organics,
Method
502.2­
PIDOrganics,
PID
BENZENE,
UG/
LBENZENE,
L
Organics,
Method
502.2­
PIDOrganics,
PID
CIS­
1,3­
DICHLOROPROPENE,
UG/
LCIS­
L
02
46
810
0
2
4
6
810
02
46
810
02
46810
c:/
pw/
ostmdl/
req004/
r004sd1.
s
Organics,
Method
502.2­
PIDOrganics,
PID
ISOPROPYLBENZENE,
UG/
LISOPROPYLBENZENE,
L
Organics,
Method
502.2­
PIDOrganics,
PID
N­
PROPYLBENZENE,
UG/
LN­
L
Episode
6000
Data
0.8
0.6
0.4
0.2
0.0
0
5
101520
Organics,
Method
502.2­
PIDOrganics,
PID
O­
XYLENE+
STYRENE,
UG/
LO­
L
0.5
0.4
0.3
0.2
0.1
0.0
0
24
6810
Organics,
Method
502.2­
PIDOrganics,
PID
TERT­
BUTYLBENZENE,
UG/
LTERT­
L
0.4
0.3
0.2
0.1
Organics,
Method
502.2­
PIDOrganics,
PID
TRANS­
1,3­
DICHLOROPROPENE,
UG/
LTRANS­
L
0
2
4
6
810
10
8
6
4
2
0
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
1,1,1­
TRICHLOROETHANE,
UG/
L1,1,1­
L
Mon
Mar
18
16:
05:
18
2002
1.0
0.8
0.6
0.4
0.2
0.0
0.6
0.5
0.4
0.3
0.2
0.1
0.0
0.6
0.5
0.4
0.3
0.2
0.1
0.0
10
8
6
4
2
0
Organics,
Method
502.2­
PIDOrganics,
PID
P­
ISOPROPTOL+
1,4­
DCB,
UG/
LP­
L
0
5
101520
Organics,
Method
502.2­
PIDOrganics,
PID
TETRACHLOROETHENE,
UG/
LTETRACHLOROETHENE,
L
0
2
4
6
810
Organics,
Method
502.2­
PIDOrganics,
PID
TRICHLOROETHENE,
UG/
LTRICHLOROETHENE,
L
0
24
6
810
Organics,
Method
524.2Organics,
524.2
1,1,2,2­
TETRACHLOROETHANE,
UG/
L1,1,2,2­
L
0
50
100
150
200
Spike
Concentration
Page
11
of
32Standard
Deviations
vs
Spike
Concentrations
(
Original
Scale)

Organics,
Method
502.2­
PIDOrganics,
PID
SEC­
BUTYLBENZENE,
UG/
LSEC­
L
02
46
810
0
2
4
6
810
Organics,
Method
502.2­
PIDOrganics,
PID
TOLUENE,
UG/
LTOLUENE,
L
Organics,
Method
524.2Organics,
524.2
1,1,1,2­
TETRACHLOROETHANE,
UG/
L1,1,1,2­
L
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
1,1,2­
TRICHLOROETHANE,
UG/
L1,1,2­
L
0
50
100
150
200
c:/
pw/
ostmdl/
req004/
r004sd1.
s
0.5
0.4
0.3
0.2
0.1
0.0
0.4
0.3
0.2
0.1
0.0
8
6
4
2
0
5
4
3
2
1
0
Observed
Standard
Deviation
Episode
6000
Data
8
6
4
2
0
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
1,1­
DICHLOROETHANE,
UG/
L1,1­
L
10
8
6
4
2
0
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
1,1­
DICHLOROPROPENE,
UG/
L1,1­
L
12
10
8
6
4
2
0
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
1,2,4­
TRICHLOROBENZENE,
UG/
L1,2,4­
L
6
5
4
3
2
1
0
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
1,2­
DIBROMOETHANE,
UG/
L1,2­
L
Mon
Mar
18
16:
05:
42
2002
15
10
5
0
14
12
10
8
6
4
2
0
6
5
4
3
2
1
0
12
10
8
6
4
2
0
5
Organics,
Method
524.2Organics,
524.2
1,1­
DICHLOROETHENE,
UG/
L1,1­
L
0
50
100
150
200
50
100
150
200
4
3
2
Page
12
of
32Standard
Deviations
vs
Spike
Concentrations
(
Original
Scale)

Organics,
Method
524.2Organics,
524.2
1,1­
DICHLOROPROPANONE,
UG/
L1,1­
L
6
5
4
3
2
1
0
0
50
100
150
200
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
1,2,3­
TRICHLOROPROPANE,
UG/
L1,2,3­
L
15
10
5
0
0
50
100
150
200
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
1,2­
DIBROMO­
3­
CHLOROPROPANE,
UG/
L1,2­
L
5
4
3
2
1
0
0
50
100
150
200
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
1,2­
DICHLOROETHANE,
UG/
L1,2­
L
Spike
Concentration
c:/
pw/
ostmdl/
req004/
r004sd1.
s
Organics,
Method
524.2Organics,
524.2
1,2,3­
TRICHLOROBENZENE,
UG/
L1,2,3­
L
Organics,
Method
524.2Organics,
524.2
1,2,4­
TRIMETHYLBENZENE,
UG/
L1,2,4­
L
Organics,
Method
524.2Organics,
524.2
1,2­
DICHLOROBENZENE,
UG/
L1,2­
L
Observed
Standard
Deviation
Episode
6000
Data
6
4
2
0
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
1,2­
DICHLOROPROPANE,
UG/
L1,2­
L
5
4
3
2
1
0
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
1,3­
DICHLOROPROPANE,
UG/
L1,3­
L
10
8
6
4
2
0
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
2,2­
DICHLOROPROPANE,
UG/
L2,2­
L
14
12
10
8
6
4
2
0
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
2­
HEXANONE,
UG/
L2­
L
Mon
Mar
18
16:
06:
06
2002
6
4
2
0
10
8
6
4
2
0
8
6
4
2
0
10
8
6
4
2
0
Organics,
Method
524.2Organics,
524.2
1,3,5­
TRIMETHYLBENZENE,
UG/
L1,3,5­
L
10
8
6
4
2
0
0
50
100
150
200
300
200
100
0
0
50
100
150
200
8
6
4
2
0
0
50
100
150
200
8
6
4
2
0
0
50
100
150
200
Spike
Concentration
Organics,
Method
524.2Organics,
524.2
1,4­
DICHLOROBENZENE,
UG/
L1,4­
L
Organics,
Method
524.2Organics,
524.2
2­
BUTANONE,
UG/
L2­
L
Organics,
Method
524.2Organics,
524.2
2­
NITROPROPANE,
UG/
L2­
L
Page
13
of
32Standard
Deviations
vs
Spike
Concentrations
(
Original
Scale)

Organics,
Method
524.2Organics,
524.2
1,3­
DICHLOROBENZENE,
UG/
L1,3­
L
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
1­
CHLOROBUTANE,
UG/
L1­
L
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
2­
CHLOROTOLUENE,
UG/
L2­
L
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
4­
CHLOROTOLUENE,
UG/
L4­
L
0
50
100
150
200
c:/
pw/
ostmdl/
req004/
r004sd1.
s
Observed
Standard
Deviation
Episode
6000
Data
6
5
4
3
2
1
0
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
4­
ISOPROPYLTOLUENE,
UG/
L4­
L
8
6
4
2
0
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
ACRYLONITRILE,
UG/
LACRYLONITRILE,
L
10
8
6
4
2
0
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
BROMOBENZENE,
UG/
LBROMOBENZENE,
L
8
6
4
2
0
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
BROMOFORM,
UG/
LBROMOFORM,
L
Mon
Mar
18
16:
06:
27
2002
12
10
8
6
4
2
0
0
10
8
6
4
2
0
6
5
4
3
2
1
0
10
8
6
4
2
0
Organics,
Method
524.2Organics,
524.2
4­
METHYL­
2­
PENTANONE,
UG/
L4­
L
50
100
150
200
Organics,
Method
524.2Organics,
524.2
ALLYL
CHLORIDE,
UG/
LALLYL
L
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
BROMOCHLOROMETHANE,
UG/
LBROMOCHLOROMETHANE,
L
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
BROMOMETHANE,
UG/
LBROMOMETHANE,
L
0
50
100
150
200
Spike
Concentration
12
10
8
6
4
2
0
6
5
4
3
2
1
0
6
5
4
3
2
1
0
12
10
8
6
4
2
0
Page
14
of
32Standard
Deviations
vs
Spike
Concentrations
(
Original
Scale)

Organics,
Method
524.2Organics,
524.2
ACETONE,
UG/
LACETONE,
L
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
BENZENE,
UG/
LBENZENE,
L
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
BROMODICHLOROMETHANE,
UG/
LBROMODICHLOROMETHANE,
L
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
CARBON
DISULFIDE,
UG/
LCARBON
L
0
50
100
150
200
c:/
pw/
ostmdl/
req004/
r004sd1.
s
Observed
Standard
Deviation
Episode
6000
Data
12
10
8
6
4
2
0
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
CARBON
TETRACHLORIDE,
UG/
LCARBON
L
10
8
6
4
2
0
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
CHLOROETHANE,
UG/
LCHLOROETHANE,
L
8
6
4
2
0
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
CIS­
1,2­
DICHLOROETHENE,
UG/
LCIS­
L
4
3
2
1
0
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
DIBROMOMETHANE,
UG/
LDIBROMOMETHANE,
L
Mon
Mar
18
16:
06:
40
2002
5
4
3
2
1
Organics,
Method
524.2Organics,
524.2
CHLOROACETONITRILE,
UG/
LCHLOROACETONITRILE,
L
50
100
150
200
6
4
2
0
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
CHLOROFORM,
UG/
LCHLOROFORM,
L
5
4
3
2
1
0
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
CIS­
1,3­
DICHLOROPROPENE,
UG/
LCIS­
L
15
10
5
0
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
DICHLORODIFLUOROMETHANE,
UG/
LDICHLORODIFLUOROMETHANE,
L
Spike
Concentration
8
6
4
2
0
15
10
5
0
6
5
4
3
2
1
0
8
6
4
2
0
Page
15
of
32Standard
Deviations
vs
Spike
Concentrations
(
Original
Scale)

Organics,
Method
524.2Organics,
524.2
CHLOROBENZENE,
UG/
LCHLOROBENZENE,
L
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
CHLOROMETHANE,
UG/
LCHLOROMETHANE,
L
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
DIBROMOCHLOROMETHANE,
UG/
LDIBROMOCHLOROMETHANE,
L
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
DIETHYL
ETHER,
UG/
LDIETHYL
L
0
50
100
150
200
c:/
pw/
ostmdl/
req004/
r004sd1.
s
Observed
Standard
Deviation
Episode
6000
Data
6
4
2
0
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
ETHYL
METHACRYLATE,
UG/
LETHYL
L
15
10
5
0
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
HEXACHLOROETHANE,
UG/
LHEXACHLOROETHANE,
L
5
4
3
2
1
0
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
METHACRYLONITRILE,
UG/
LMETHACRYLONITRILE,
L
8
6
4
2
0
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
METHYLACRYLATE,
UG/
LMETHYLACRYLATE,
L
Mon
Mar
18
16:
06:
53
2002
10
8
6
4
2
0
6
4
2
0
10
8
6
4
2
0
6
4
2
0
Organics,
Method
524.2Organics,
524.2
ETHYLBENZENE,
UG/
LETHYLBENZENE,
L
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
ISOPROPYLBENZENE,
UG/
LISOPROPYLBENZENE,
L
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
METHYL
IODIDE,
UG/
LMETHYL
L
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
METHYLENE
CHLORIDE,
UG/
LMETHYLENE
L
0
50
100
150
200
Spike
Concentration
15
10
Page
16
of
32Standard
Deviations
vs
Spike
Concentrations
(
Original
Scale)

Organics,
Method
524.2Organics,
524.2
HEXACHLOROBUTADIENE,
UG/
LHEXACHLOROBUTADIENE,
L
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
M+
P
XYLENE,
UG/
LM+
L
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
METHYL
TERT­
BUTYL
ETHER,
UG/
LMETHYL
L
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
METHYLMETHACRYLATE,
UG/
LMETHYLMETHACRYLATE,
L
0
50
100
150
200
c:/
pw/
ostmdl/
req004/
r004sd1.
s
5
0
6
4
2
0
8
6
4
2
0
6
5
4
3
2
1
0
Observed
Standard
Deviation
TRANS­
1,3­
DICHLOROPROPENE,
UG/
LTRANS­
L
Episode
6000
Data
6
4
2
0
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
N­
BUTYLBENZENE,
UG/
LN­
L
10
8
6
4
2
0
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
O­
XYLENE,
UG/
LO­
L
8
6
4
2
0
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
STYRENE,
UG/
LSTYRENE,
L
6
4
2
0
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
TOLUENE,
UG/
LTOLUENE,
L
Mon
Mar
18
16:
07:
07
2002
10
8
6
4
2
0
10
8
6
4
2
0
8
6
4
2
0
10
8
6
4
2
0
Organics,
Method
524.2Organics,
524.2
N­
PROPYLBENZENE,
UG/
LN­
L
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
PENTACHLOROETHANE,
UG/
LPENTACHLOROETHANE,
L
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
TERT­
BUTYLBENZENE,
UG/
LTERT­
L
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
TRANS­
1,2­
DICHLOROETHENE,
UG/
LTRANS­
L
0
50
100
150
200
Spike
Concentration
12
10
8
6
4
2
0
6
4
2
0
12
10
8
6
4
2
0
5
4
3
2
1
0
Page
17
of
32Standard
Deviations
vs
Spike
Concentrations
(
Original
Scale)

Organics,
Method
524.2Organics,
524.2
NAPHTHALENE,
UG/
LNAPHTHALENE,
L
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
SEC­
BUTYLBENZENE,
UG/
LSEC­
L
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
TETRACHLOROETHENE,
UG/
LTETRACHLOROETHENE,
L
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
0
50
100
150
200
c:/
pw/
ostmdl/
req004/
r004sd1.
s
Observed
Standard
Deviation
Episode
6000
Data
6
4
2
0
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
TRANS­
1,4­
DICHLORO­
2­
BUTENE,
UG/
LTRANS­
L
19.9990
14.9993
9.9995
4.9998
0.0
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
VINYL
CHLORIDE,
UG/
LVINYL
L
2.0
1.5
1.0
0.5
0.0
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
1,2,4­
TRICHLOROBENZENE,
NG/
UL1,2,4­
UL
2.0
1.5
1.0
0.5
0.0
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
1,3­
DICHLOROBENZENE,
NG/
UL1,3­
UL
Mon
Mar
18
16:
07:
20
2002
10
8
6
4
2
0
6
4
2
0
1.0
0.8
0.6
0.4
0.2
0.0
2.5
2.0
1.5
1.0
0.5
0.0
Organics,
Method
524.2Organics,
524.2
TRICHLOROETHENE,
UG/
LTRICHLOROETHENE,
L
0
50
100
150
200
Organics,
Method
524.2Organics,
524.2
XYLENE
(
TOTAL),
UG/
LXYLENE
L
0
50
100
150
200
Organics,
Method
1625:
T=
0Organics,
0
1,2­
DICHLOROBENZENE,
NG/
UL1,2­
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
1,4­
DICHLOROBENZENE,
NG/
UL1,4­
UL
0
20
40
60
80
100
Spike
Concentration
Page
18
of
32Standard
Deviations
vs
Spike
Concentrations
(
Original
Scale)

Organics,
Method
524.2Organics,
524.2
TRICHLOROFLUOROMETHANE,
UG/
LTRICHLOROFLUOROMETHANE,
L
0
50
100
150
200
Organics,
Method
1625:
T=
0Organics,
0
1,2,3­
TRICHLOROBENZENE,
NG/
UL1,2,3­
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
1,2­
DIPHENYLHYDRAZINE,
NG/
UL1,2­
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
2,3,6­
TRICHLOROPHENOL,
NG/
UL2,3,6­
UL
0
20
40
60
80
100
c:/
pw/
ostmdl/
req004/
r004sd1.
s
15
10
5
0
3
2
1
0
14
12
10
8
6
4
2
0
5
4
3
2
1
0
Observed
Standard
Deviation
Episode
6000
Data
Organics,
Method
1625:
T=
0Organics,
0
2,4,5­
TRICHLOROPHENOL,
NG/
UL2,4,5­
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
2,4­
DIMETHYLPHENOL,
NG/
UL2,4­
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
2,6­
DINITROTOLUENE,
NG/
UL2,6­
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
2­
NITROPHENOL,
NG/
UL2­
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
2,4,6­
TRICHLOROPHENOL,
NG/
UL2,4,6­
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
2,4­
DINITROPHENOL,
NG/
UL2,4­
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
2­
CHLORONAPHTHALENE,
NG/
UL2­
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
2­
PICOLINE,
NG/
UL2­
UL
0
20
40
60
80
100
Spike
Concentration
6
4
2
0
1.4
1.2
1.0
0.8
0.6
0.4
0.2
0.0
4
3
2
1
0
2.0
1.5
1.0
0.5
0.0
6
5
4
3
2
1
0
14
12
10
8
6
4
2
0
0.5
0.4
0.3
0.2
0.1
0.0
4
3
2
1
0
Page
19
of
32Standard
Deviations
vs
Spike
Concentrations
(
Original
Scale)

Organics,
Method
1625:
T=
0Organics,
0
2,4­
DICHLOROPHENOL,
NG/
UL2,4­
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
2,4­
DINITROTOLUENE,
NG/
UL2,4­
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
2­
CHLOROPHENOL,
NG/
UL2­
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
3,3'­
DICHLOROBENZIDINE,
NG/
UL3,3'­
UL
0
20
40
60
80
100
c:/
pw/
ostmdl/
req004/
r004sd1.
s
8
6
4
2
0
1.5
1.0
0.5
0.0
2.5
2.0
1.5
1.0
0.5
0.0
2.0
1.5
1.0
0.5
0.0
Observed
Standard
Deviation
Mon
Mar
18
16:
07:
34
2002
Episode
6000
Data
Organics,
Method
1625:
T=
0Organics,
0
4­
BROMOPHENYL
PHENYL
ETHER,
NG/
UL4­
UL
3
2
1
0
0
20
40
60
80
100
15
10
5
0
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
4­
NITROPHENOL,
NG/
UL4­
UL
3
2
1
0
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
ALPHA­
TERPINEOL,
NG/
ULALPHA­
UL
3
2
1
0
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
BENZO(
A)
ANTHRACENE,
NG/
ULBENZO(
UL
Mon
Mar
18
16:
07:
51
2002
4
2.5
Organics,
Method
1625:
T=
0Organics,
0
4­
CHLORO­
3­
METHYLPHENOL,
NG/
UL4­
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
ACENAPHTHENE,
NG/
ULACENAPHTHENE,
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
ANTHRACENE,
NG/
ULANTHRACENE,
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
BENZO(
A)
PYRENE,
NG/
ULBENZO(
UL
0
20
40
60
80
100
Spike
Concentration
2.0
1.5
1.0
0.5
0.0
6
5
4
3
2
1
0
15
10
5
0
5
4
3
2
1
0
Page
20
of
32Standard
Deviations
vs
Spike
Concentrations
(
Original
Scale)

Organics,
Method
1625:
T=
0Organics,
0
4­
CHLOROPHENYLPHENYL
ETHER,
NG/
UL4­
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
ACENAPHTHYLENE,
NG/
ULACENAPHTHYLENE,
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
BENZIDINE,
NG/
ULBENZIDINE,
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
BENZO(
B)
FLUORANTHENE,
NG/
ULBENZO(
UL
0
20
40
60
80
100
c:/
pw/
ostmdl/
req004/
r004sd1.
s
2.0
1.5
1.0
0.5
0.0
6
4
2
0
6
5
4
3
2
1
0
2.5
2.0
1.5
1.0
0.5
0.0
Observed
Standard
Deviation
BIS(
2­
CHLOROETHOXY)
METHANE,
NG/
ULBIS(
UL
BIS(
2­
ETHYLHEXYL)
PHTHALATE,
NG/
ULBIS(
UL
Episode
6000
Data
3.0
8
2.5
6
2.0
1.5
4
1.0
2
0.5
0.0
Organics,
Method
1625:
T=
0Organics,
0
BENZO(
GHI)
PERYLENE,
NG/
ULBENZO(
UL
0
0
20
40
60
80
100
5
5
4
4
3
3
2
2
1
Organics,
Method
1625:
T=
0Organics,
0
BIPHENYL,
NG/
ULBIPHENYL,
UL
1
00
0
20
40
60
80
100
3.0
5
2.5
4
2.0
3
1.5
2
1.0
1
Organics,
Method
1625:
T=
0Organics,
0
BIS(
2­
CHLOROISOPROPYL)
ETHER,
NG/
ULBIS(
UL
0.5
0
0.0
0
20
40
60
80
100
4
4
3
3
2
2
1
Organics,
Method
1625:
T=
0Organics,
0
CARBAZOLE,
NG/
ULCARBAZOLE,
UL
1
00
0
20
40
60
80
100
Mon
Mar
18
16:
08:
07
2002
Organics,
Method
1625:
T=
0Organics,
0
BENZO(
K)
FLUORANTHENE,
NG/
ULBENZO(
UL
10
8
6
4
2
0
0
20
40
60
80
100
3
2
1
0
0
20
40
60
80
100
3.0
2.5
2.0
1.5
1.0
0.5
0.0
2.0
1.5
1.0
0.5
0.0
0
20
40
60
80
100
Spike
Concentration
Organics,
Method
1625:
T=
0Organics,
0
Organics,
Method
1625:
T=
0Organics,
0
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
CHRYSENE,
NG/
ULCHRYSENE,
UL
Page
21
of
32Standard
Deviations
vs
Spike
Concentrations
(
Original
Scale)

Organics,
Method
1625:
T=
0Organics,
0
BETA­
NAPHTHYLAMINE,
NG/
ULBETA­
UL
Organics,
Method
1625:
T=
0Organics,
0
BIS(
2­
CHLOROETHYL)
ETHER,
NG/
ULBIS(
UL
0
20
40
60
80
100
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
BUTYL
BENZYL
PHTHALATE,
NG/
ULBUTYL
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
DI­
N­
BUTYL
PHTHALATE,
NG/
ULDI­
UL
0
20
40
60
80
100
c:/
pw/
ostmdl/
req004/
r004sd1.
s
Observed
Standard
Deviation
Episode
6000
Data
Organics,
Method
1625:
T=
0Organics,
0
DI­
N­
OCTYL
PHTHALATE,
NG/
ULDI­
UL
2.0
1.5
1.0
0.5
0.0
0
20
40
60
80
100
6
4
2
0
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
DIBENZOFURAN,
NG/
ULDIBENZOFURAN,
UL
3.0
2.5
2.0
1.5
1.0
0.5
0.0
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
DIMETHYL
PHTHALATE,
NG/
ULDIMETHYL
UL
5
4
3
2
1
0
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
FLUORANTHENE,
NG/
ULFLUORANTHENE,
UL
Mon
Mar
18
16:
08:
29
2002
Organics,
Method
1625:
T=
0Organics,
0
DI­
N­
PROPYLNITROSAMINE,
NG/
ULDI­
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
DIBENZOTHIOPHENE,
NG/
ULDIBENZOTHIOPHENE,
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
DIPHENYL
ETHER,
NG/
ULDIPHENYL
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
FLUORENE,
NG/
ULFLUORENE,
UL
0
20
40
60
80
100
Spike
Concentration
Page
22
of
32Standard
Deviations
vs
Spike
Concentrations
(
Original
Scale)

Organics,
Method
1625:
T=
0Organics,
0
DIBENZO(
A,
H)
ANTHRACENE,
NG/
ULDIBENZO(
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
DIETHYL
PHTHALATE,
NG/
ULDIETHYL
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
DIPHENYLAMINE,
NG/
ULDIPHENYLAMINE,
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
HEXACHLOROBENZENE,
NG/
ULHEXACHLOROBENZENE,
UL
0
20
40
60
80
100
c:/
pw/
ostmdl/
req004/
r004sd1.
s
12
10
2.5
3.0
2.5
2.0
1.5
1.0
0.5
0.0
2.5
2.0
1.5
1.0
0.5
0.0
6
4
2
0
4
3
2
1
0
8
6
4
2
0
5
4
3
2
1
0
4
3
2
1
0
8
6
4
2
0
Observed
Standard
Deviation
Episode
6000
Data
0.4
0.3
0.2
0.1
0.0
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
HEXACHLOROBUTADIENE,
NG/
ULHEXACHLOROBUTADIENE,
UL
25
20
15
10
5
0
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
INDENO(
1,2,3­
CD)
PYRENE,
NG/
ULINDENO(
UL
15
10
5
0
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
N­
DOCOSANE,
NG/
ULN­
UL
20
15
10
5
0
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
N­
HEXACOSANE,
NG/
ULN­
UL
Mon
Mar
18
16:
08:
46
2002
5
4
3
2
1
0
2.5
2.0
1.5
1.0
0.5
0.0
6
5
4
3
2
1
0
12
10
8
6
4
2
0
Organics,
Method
1625:
T=
0Organics,
0
HEXACHLOROCYCLOPENTADIENE,
NG/
ULHEXACHLOROCYCLOPENTADIENE,
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
ISOPHORONE,
NG/
ULISOPHORONE,
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
N­
DODECANE,
NG/
ULN­
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
N­
HEXADECANE,
NG/
ULN­
UL
0
20
40
60
80
100
Spike
Concentration
2.0
Page
23
of
32Standard
Deviations
vs
Spike
Concentrations
(
Original
Scale)

Organics,
Method
1625:
T=
0Organics,
0
HEXACHLOROETHANE,
NG/
ULHEXACHLOROETHANE,
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
N­
DECANE,
NG/
ULN­
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
N­
EICOSANE,
NG/
ULN­
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
N­
NITROSODIMETHYLAMINE,
NG/
ULN­
UL
0
20
40
60
80
100
c:/
pw/
ostmdl/
req004/
r004sd1.
s
1.5
1.0
0.5
0.0
25
20
15
10
5
0
8
6
4
2
0
12
10
8
6
4
2
0
Observed
Standard
Deviation
Episode
6000
Data
1.5
1.0
0.5
0.0
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
N­
NITROSODIPHENYLAMINE,
NG/
ULN­
UL
3.0
2.5
2.0
1.5
1.0
0.5
0.0
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
N­
TETRACOSANE,
NG/
ULN­
UL
1.5
1.0
0.5
0.0
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
NAPHTHALENE,
NG/
ULNAPHTHALENE,
UL
0.8
0.6
0.4
0.2
0.0
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
PENTACHLOROPHENOL,
NG/
ULPENTACHLOROPHENOL,
UL
Mon
Mar
18
16:
09:
01
2002
20
15
10
5
0
14
12
10
8
6
4
2
0
3
2
1
0
3
2
1
0
Organics,
Method
1625:
T=
0Organics,
0
N­
OCTACOSANE,
NG/
ULN­
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
N­
TETRADECANE,
NG/
ULN­
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
NITROBENZENE,
NG/
ULNITROBENZENE,
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
PHENANTHRENE,
NG/
ULPHENANTHRENE,
UL
0
20
40
60
80
100
Spike
Concentration
14
12
10
8
6
4
2
0
8
6
4
2
0
6
4
2
0
10
8
6
4
2
0
Page
24
of
32Standard
Deviations
vs
Spike
Concentrations
(
Original
Scale)

Observed
Standard
Deviation
Organics,
Method
1625:
T=
0Organics,
0
N­
OCTADECANE,
NG/
ULN­
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
N­
TRIACONTANE,
NG/
ULN­
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
P­
CYMENE,
NG/
ULP­
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
0Organics,
0
PHENOL,
NG/
ULPHENOL,
UL
0
20
40
60
80
100
c:/
pw/
ostmdl/
req004/
r004sd1.
s
PHENOL,
2­
METHYL­
4,6­
DINITRO­,
NG/
ULPHENOL,
UL
Episode
6000
Data
Organics,
Method
1625:
T=
0Organics,
0
1.5
1.0
0.5
0.0
0
20
40
60
80
100
3.0
2.5
2.0
1.5
1.0
0.5
0.0
0
20
40
60
80
100
Organics,
Method
1625:
T=
1000Organics,
1000
1,2,3­
TRICHLOROBENZENE,
NG/
UL1,2,3­
UL
10
8
6
4
2
0
0
20
40
60
80
100
Organics,
Method
1625:
T=
1000Organics,
1000
1,2­
DIPHENYLHYDRAZINE,
NG/
UL1,2­
UL
6
5
4
3
2
1
0
0
20
40
60
80
100
Organics,
Method
1625:
T=
1000Organics,
1000
2,3,6­
TRICHLOROPHENOL,
NG/
UL2,3,6­
UL
Mon
Mar
18
16:
09:
20
2002
2.0
5
Organics,
Method
1625:
T=
0Organics,
0
PYRENE,
NG/
ULPYRENE,
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
1000Organics,
1000
1,2,4­
TRICHLOROBENZENE,
NG/
UL1,2,4­
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
1000Organics,
1000
1,3­
DICHLOROBENZENE,
NG/
UL1,3­
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
1000Organics,
1000
2,4,5­
TRICHLOROPHENOL,
NG/
UL2,4,5­
UL
0
20
40
60
80
100
Spike
Concentration
Page
25
of
32Standard
Deviations
vs
Spike
Concentrations
(
Original
Scale)

Organics,
Method
1625:
T=
0Organics,
0
STYRENE,
NG/
ULSTYRENE,
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
1000Organics,
1000
1,2­
DICHLOROBENZENE,
NG/
UL1,2­
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
1000Organics,
1000
1,4­
DICHLOROBENZENE,
NG/
UL1,4­
UL
0
20
40
60
80
100
Organics,
Method
1625:
T=
1000Organics,
1000
2,4,6­
TRICHLOROPHENOL,
NG/
UL2,4,6­
UL
0
20
40
60
80
100
c:/
pw/
ostmdl/
req004/
r004sd1.
s
4
3
2
1
0
3
2
1
0
3.0
2.5
2.0
1.5
1.0
0.5
0.0
6
4
2
0
4
3
2
1
0
2.0
1.5
1.0
0.5
0.0
2.0
1.5
1.0
0.5
0.0
6
5
4
3
2
1
0
Observed
Standard
Deviation