Document ID: EPA-HQ-OPP-2004-0302-0002
Agency: epa
Document Type: Supporting & Related Material
Title: 
Posted Date: 2004-09-10T04:00Z

Page
1
of
5
Case
Overview
3113
A.
Chemical
Overview
The
following
active
ingredient
is
covered
by
this
Reregistration
Eligibility
Decision:

Common
Name:
Pine
Oils
Chemical
Names:
CAS
Registry
Number:
OPP
Chemical
Code:

Pine
Oil
8002­
09­
3
067002
Case
Number:
3113
Empirical
Formula
:
N/
A
(
See
Significant
Science
Issues)

Molecular
Weight:
N/
A
(
See
Significant
Science
Issues)

Trade
and
Other
Names:
Pine
Oil
Basic
Manufacturers:
Arizona
Chemical
Company,
Bush,
Boake
&
Allen,
Inc,
Dow
Brands,
Inc.,
Hercules,
Inc.,
L
&
F
Products,
Inc.,
Procter
&
Gamble
Company,
SCM
Glidco
Organics,
T
&
R
Chemicals,
Tecnal
Limited
Partnership
Percent
Active
Ingredient
in
Technical
Grade
Product:
99.999%

B.
Use
Profile
The
following
is
information
on
the
currently
registered
uses
with
an
overview
of
the
use
sites
and
application
methods.

Chemical
Name:
OPP
Chem
Code:
Pine
Oil
067002
TYPES
OF
PESTICIDE:
Disinfectant,
sanitizer,
mircobicide/
microbistat,
virucide,
insecticide.
Page
2
of
5
USE
SITES:
Indoor
Non­
Food
Eating
Establishments
(
Non­
Food
Contact)
Commercial,
Institutional
and
Industrial
Areas/
Premises
Commercial,
Institutional
or
Industrial
Equipment
Commercial
Transportation
facilities
(
Non­
Food
Contact)
Laundry
Equipment
Diapers
(
Commercial
Laundry)
Refuse
and
Solid
Waste
Transportation
and
Handling
Equipment
Hard
Non­
Porous
Surface
Treatments
Farm
Animals
(
All
or
Unspecified)
Automobiles
and
Ships
Indoor
Residential
Household
or
Domestic
Dwellings
Household
or
Domestic
Dwelling
Contents
Bathroom
Premises
Human
Bedding
Human
Grooming
Instruments
Laundry
(
Household/
Coin­
Operated)
Refuse
and
Solid
Waste
Containers
(
Garbage
Cans)
Refuse
and
Solid
Waste
Sites
Refuse
and
Solid
Waste
Transportation
and
Handling
Equipment
Hard
Porous
Surface
Treatments
Toilet
Bowls
and
Urinals
Pets
(
All
or
Unspecified)

Indoor
Medical
Barber
and
Beauty
Shop
Equipment
Barber
and
Beauty
Shop
Instruments
Cuspidors
and
Spittoons
Laundry
(
Hospital)
Household
Sickrooms
Hospitals
and
Related
Institutions
Hospital
Non­
Critical
Items
(
Items
contact
only
unbroken
skin)
Page
3
of
5
TARGET
PESTS:
Brevibacterium
ammoniagenes,
Candida
albicans,
Enterobacteraerogenes,
Escherichia
coli,
Gram­
negative
enteric
bacteria,
Household
germs,
Gram­
negative
household
germs
such
as
those
causing
Salmonellosis,
Herpes
Simplex
Types
1
and
2,
Influenza
Type
A,
Influenza
Virus
Type
A/
Brazil,
Influenza
Virus
Type
A2/
Japan,
Intestinal
bacteria,
Klebsiella
pneumoniae,
Odor
causing
bacteria,
Mold,
Mildew,
Odor
causing
bacteria,
Pseudomonas
aeruginosa,
Salmonellacholeraesuis,
Salmonella
Typhi,
Salmonella
typhosa,
Serratia
marcescens,
Shigella
sonnei,
Staphylococcus
aureus,
Streptococcus
faecalis,
Streptococcus
pyogenes,
Trichophyton
mentagrophytes.

FORMULATION
TYPES
Type:
End
Use
and
Manufacturing
Use
REGISTERED:
Form:
Liquid
RATES
OF
APPLICATION:

Indoor
Food:
If
concentrate,
add
4
Tbsp.
to
1/
4
cup
of
Pine
oil
to
One
gallon
water.
Wet
surface
thoroughly
for
10
minutes.
Rinse
with
clear
water.
If
ready­
to­
use,
apply
Pine
Oil,
let
stand
for
10
minutes
then
rinse
with
clear
water.

Indoor
Non­
Food:
Eating
Establishments:
If
concentrate,
add
4
Tbsp.
to
1/
4
cup
Pine
Oil
to
One
gallon
water.
Apply
with
mop
or
sponge.
Let
stand
10
minutes
and
wipe
off
excess.
For
heavily
soiled
areas,
up
to
½
gallon
Pine
Oil
to
½
gallon
water
may
be
used.

Commercial,
Institutional,
and
Industrial
areas
or
equipment:
If
concentrate,
add
4
Tbsp.
to
1/
4
cup
Pine
Oil
to
One
gallon
water.
Apply
with
mop
or
sponge.
Let
stand
10
minutes
and
wipe
off
excess.
For
heavily
soiled
areas,
up
to
½
gallon
Pine
Oil
to
½
gallon
water
may
be
used.

Laundry:
Use
full
strength
on
soiled
areas
and
add
½
cup
to
wash.

Indoor
Residential:
Household
and
Domestic
Dwellings
and
Contents:
If
concentrate,
add
4
Tbsp.
to
1/
4
cup
of
Pine
oil
to
One
gallon
water.
Wet
surface
thoroughly
for
10
minutes.
Rinse
with
clear
water.
If
ready­
to­
use,
apply
Pine
Oil,
let
stand
for
10
minutes
then
rinse
with
clear
water.
Page
4
of
5
Indoor
Residential(
cont):

Diapers:
Soak
in
6
Tbsp.
per
3
gallons
water.

Pet
Baths:
Use
3
Tsp
to
3
Tbsp.
per
gallon
of
water.

Garbage
Pails:
Use
2
Tbsp.
per
gallon
of
water.

Indoor
Medical:
Hospitals
and
Related
Institutions:
If
concentrate,
add
4
Tbsp.
to
1/
4
cup
of
Pine
oil
to
One
gallon
water.
Wet
surface
thoroughly
for
10
minutes.
Rinse
with
clear
water.
If
ready­
to­
use,
apply
Pine
Oil,
let
stand
for
10
minutes
then
rinse
with
clear
water.

Barber
and
Beauty
Shop
Equipment
and
Instruments:
If
concentrate,
add
4
Tbsp.
to
1/
4
cup
of
Pine
oil
to
One
gallon
water.
Wet
surface
thoroughly
for
10
minutes.
Rinse
with
clear
water.
If
ready­
to­
use,
apply
Pine
Oil,
let
stand
for
10
minutes
then
rinse
with
clear
water.

Laundry:
Use
full
strength
on
soiled
areas
and
add
½
cup
to
wash.

C.
Regulatory
History
The
first
Pine
oil
registration
was
first
issued
to
William
Cooper
and
Nephews,
Inc
in
December,
1947.
The
product
contained
70%
Pine
oil
20%
Soap
and
10%
Water
and
was
labeled
as
a
hard
surface
disinfectant
and
deodorizer.
Commercial
Standard
CS69­
38,
amended
in
1955,
separated
pine
oils
products
into
three
categories
depending
upon
concentration
and
ingredients.
As
part
of
the
Label
Improvement
Program,
initiated
in
1980,
manufacturers
of
pine
oil
products
were
required
to
revise
their
labels
to
comply
with
updated
standards.

The
CSPA
Pine
Oil
Joint
Venture
was
formed
on
October
7,
1986.
The
Joint
Venture
members
at
that
time
were:
American
Cyanamid
Arizona
Chemical
Company
Dow
Consumer
Products,
Inc.
Hercules,
Inc.
Johnson
Chemical
Company,
Inc.
Lehn
&
Fink
Products,
Inc.
Procter
&
Gamble
Company
SCM
Glidco
Organics
Sintesis
Quimica,
S.
A.
T
&
R
Chemicals
Union
Camp
Corporation
Page
5
of
5
At
this
time
there
are
currently
98
active
Pine
oil
registrations.
Of
these
98
registrations,
19
of
them
are
manufacturing­
use/
technical
grade
active
ingredient
(
MUP/
TGAI)
products.
Of
the
79
remaining
end­
use
product
(
EUP)
registrations,
all
but
three
of
them
are
Disinfectant
or
Disinfectant/
Sanitizer
products.
The
three
are:

Registrant
EPA
Reg.
No.
Product
Type
Brondow,
Inc.
2733­
1
Disinfectant/
Repellant
(
Roaches
and
Ants)

Speer
Products
11715­
290
Insecticide
(
Fly
spray
for
horses)

TFA
Products,
Inc.
70072­
1
Insecticide
(
Fire
Ant
Mounds)

The
remaining
EUPs
are
for
disinfection
of
hard,
nonporous
inanimate
surfaces.
The
typical
pesticidal
claim
relating
to
Pine
Oil
content
in
these
products
is
limited
against
bacteria,
primarily
gram­
negative
household
germs
such
as
those
causing
Salmonellosis.
In
addition,
several
labels
have
directions
for
toilet
bowl
disinfection.

There
are
no
food/
feed
uses
for
Pine
Oil.
Any
food
contact
surfaces
require
cleaning
with
a
detergent
followed
by
a
potable
water
rinse.
This
applies
even
when
the
products
are
labeled
for
use
in
Federally
inspected
meat
and
poultry
plants,
farm
premises
or
on
kitchen
countertops.

Of
the
79
remaining
end­
use
product
(
EUP)
registrations
reviewed,
a
overwhelming
majority
of
them
were
liquid
concentrates.
There
were
a
few
ready­
to­
use
products,
one
product
is
registered
as
an
emulsifiable
concentrate
and
one
product
is
registered
as
a
concentrate
that
may
be
used
at
full
strength.