Document ID: EPA-HQ-OPPT-2003-0025-0003
Agency: epa
Document Type: Supporting & Related Material
Title: 
Posted Date: 2003-05-21T04:00Z

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n
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roved.
O.
M.
B.
No.
2070­
0012.
Approval
Expires
10­
31­
96.'
.
S.
ENVIRONMENTAL
PROTECTION
AGENCY
AGENCY
USE
ONLY
PREMANUFACTURE
NOTICE
2003APR
24
All/
O:
48
.
You
must
provide
all
information
requested
m
not
have
actual
dara
.
Before
you
complete
this
form,
you
should
mad
the
"
Instn~
ctioas
Manual
for
Ptunanufk.
ture
Notification"
(
tbt
Inrtructioos
Manual
is
availabk
fiwm
the
Toxic
Substances
Control
Act
(
TSCA)
ItAmation
Stice
by
callinp
202­
554­
1404,
or
faxing
202­
554­
5603).
.
If
a
user
fee
has
been
mtniacd
for
this
notice
(
40
CFR
700.49,
indicate
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above
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TS­
user
fee
identifiwion
number
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have
generated.
Remember,
your
usu
fee
ID
numba
must
also
appear
on
your
cotresponding
fbe
remittance,
which
is
sent
to
EPA,
HQ
Accounting
Opaatioos
Branch
(
P&
226),
P.
O.
360399M.
Pittsburgh,
PA
152X­
6399,
Attn.
TSCA
User
fee.

OFTONAL
IWORMATION
TEST
DATA
AND
OTHER
DATA
You
are
req&
d
to
submit
eIi
test
deta
in
your
poseessioa
or
control
and
to
provide
a
description
of
ail
other
data
known
to
or
roasonabiy
ascutainabls
by
you,
if
tbasc
dam
M
r&
ted
to
the
tie&
h
pnd
eawircmmenti
effect
on
the
menufecture,
processing
distribution
in
commuze.
use,
or
dlsposrJ
of
the
new
cheakal
substance.
Steoderd
titcnture
citations
may
be
submitted
for
btp
ia
the
open
.
.
scientific
litomture.
CornDine
.
gbe
You
should
ckarly
identify
whether
test
data
is
on
the
substance
or
on
an
analog.
Also,
the
chemical
coznposjti~
of
the
tested
material
should
be
c­
Following
am
examples
of
kst
data
and
other
data.
Data
should
be
submitted
eccordii
to
the
requirements
of
9720.50
ofthe
Pnmenufaotum
Notiftwion
Rule
(
40
CFR
Pert
720).

TCSI
Data
(
CbskBolow
any`
iocludcd
ia
this
aotice)

­
En­
ulfitcdaa`
a
yes
­
otherdam
q
Yes
­
Health
effects
data
cl
Yet
Risk­
Woo
*
Envimnmeatal
effkcte
dam
u
Yes
sm~~
vitymImionehipr
*
Phy.
tiaaucllemiwl
ProFaIlirc*
IXI
Yes
Test
data
not
in
the
possession
aooabulofthemdmtitter
l
A
physicat
and
chamicel
pmpsrtisa
work~
Is+
t
is
lowtad
on
the
last
page
of
this
form.

TYPE
OF
NOTICE
(
Cheek
Only
One)

q
PMN
(
Remaufacaue
Notice)

cl
SNUN
(
Sigttifican~
New
Use
Notice)

Ix)
TMEA
(
Test
Marketing
Exemptioa
Apphb'on)

cl
LVE
(
Low
Volume
Exemption)
@
40
CFR
72X5o(
c~
I)
7
q
LORE­
X
(
Low
RalcptdLow
Expmrc
Excmp!
ion)
@
40
CFR
6?
5qc)(
Z)

0
LVE
Modifiution
q
L0KE.
X
Modification
IS
THLS
A
CONSOLIDATED
Ph4N7
q
*
u
#
ofchanicak
EPA
FORM
77
lo­
25
(
Rev.
5­
95)
Replaces
previous
editions
of
EPA
Form
77
1
O­
25
,?:+.
>;
,,....,
;:
,,
:.`,.:*,~:
s:.
,:;".,*;,`.,
;.
c;.?+
c
.+.
I>
n
..
instructions,
searc;.:
ns
existin2
data
sources.
gathering
and
maintalr.
irlg
:
he
data
needed,
2nd
com7ieting
and
reviewing
the
collection
of
infomation.
Send
comments
regarding
the
burden
estimate
or
any
orher
qect
ofthis
coilxiion
31infomarion,
includinz
suggestions
for
reducing
this
SurdEn,
:
o
Chief,
Infomation
Poiicy
Branch,
PM­
213,
U.
S.
Environnenrai
P:
otec:
ion
Agency,
$
01
,
M.
St.,
S.
W.,
Washinson,
D.
C
20460;
and
TOthe
Office
of
Management
and
Budget,
Paperwork
ReducTion
.
kt
!
3070­
0012),
Wzshington,
D.
C.
20503.
.
~

.
~...
~
.

CERT~
FICATION
I
certify
that
to
the
best
of
my
knowledge
and
belief
1.
The
company
named
in
Part
I,
section
A,
subsection
1a
of
this
notice
form
intends
TOmanufacture
or
import
for
a
commercial
purpose,
other
than
insmall
quantities
solely
for
research
and
development,
the
substance
identified
in
Part
I,
Section
B.

2.
All
infomation
provided
in
this
notice
is
complete
and
truthful
as
of
the
date
of
submission.

3.
I
am
submitting
with
ths
notice
all
test
data
in
my
possession
or
control
and
a
description
of
all
other
data
lcnown
to
or
reasonably
ascertainable
by
me
as
required
by
$
720.50
of
the
Premanufacture
Notification
Rule.

Additional
Certification
Statements:

If
you
are
submitting
a
PMN,
Intermediate
PMN,
Consolidated
P.
W,
or
SNCX,
check
the
following
user
fee
certification
statement
that
applies:

The
Company
named
in
Part
I,
Section
A
has
remitted
the
fee
of
$
2500
specified
in
40
CFR
700.45(
b),
or
17
The
Company
named
in
Part
I,
Section
A
has
remitted
the
fee
of
$
1000
for
an
Intexinediate
PAW(
defmed
@
40
CFR
700.43)
in
accordance
with40
CFR
700.45(
b),
or
0
The
Company
named
in
Part
I
Section
A
is
a
smdl
business
concern
under
40
CFR
700.43
and
has
remitted
a
fee
of
$
100
in
accordance
uith
40
CFR
700.45@).

If
you
are
submitting
a
low
volume
exemption
(
ZVE)
application
in
accordance
with
40
CFR
723.50(~)(
1)
or
a
Low
release
and
low
exposure
exemption
(
LoRex)
application
in
accordance
with40
CFR
723.50(~)(
2),
check
the
following
certification
statements:

The
manufacturer
submitting
this
notice
inrends
to
manufacture
or
import
the
new
chemical
substanc,*
for
commercial
purposes,
other
than
in
small
quantities
solely
for
research
and
development,
under
the
tern
of
40
CFR
723.50.

The
manufacturer
is
familiar
withthe
terms
of
this
section
and
will
comply
with
those
terms;
and
I
of
the
statements
you
make
?@
is
notice
should
reflect
your
best
prediction
of
the
anticipated
facts
regarding
rhe
chemical
substance
owin:
and
willf
misinterpretation
is
subject
to
criminal
penal­
pursuant
to
1s
USC
1001.
~
I
Confidential
Date
Signnature
of
agent
­(
if
applicable)
Date
I
b.
.4:
ent
(
if
Yame
of
authorized
nt?
icial
Position
applicable)

Company
Mailing
address
(
number
and
street)

City,
State,
ZIP
Code
Telephone
Area
Code
Number
,_
If
you
are
subn
oint
Submitter
(
if
applicable)

i
l
.
Technical
I
If
you
prewousiy
submined
XI
exemption
appiicat~
onfor
tkchemical
substance
co\.?
rzd
by
rhis
notice,
enter
the
extlmpdon
number
assigned
by
EPA.
If
you
previously
submitted
a
?
MN
for
this
substance
enter
the
PhQ4
nunbe:
arsiped
by
E?.%
(
i
e.
wiihdmum
or
incomplei­).
+
If
you
have
womined
a
norice
of
Bona
fide
intent
to
manufacture
or
import
assigned
by
E?.%.
___
I_,

Type
of
Nctice
­
Mark
(
X)
1.
@
Manufacture
Oniy
2.

jJ
ind
ding
Option
Mark
(
X)
for
the
chcrciczi
substance
covered
by
this
norice,
enter
the
notice
number
illariC(
X)
@
g
if
none
Mark(
S)
_
I___)

if
none
Import
I
Only
1I
3.
Both
a
Binding
Oprion
iIh/
Iar!
i
is)
i
I
CIS
I
or
2
chemical
substances
(
for
dciinitions
of
class
i
and
class
2
su'csrances,
see
the
Instrucrions
Manuai)

Ii
a.
Class
of
substance
­
Mark
[
X7
I
class
1
or
2
class
3
u
Method
1
(
CAS
Inventory
Expert
Service
­
a
copy
of
the
Identification
uMethod
2
(
Other
Source)
report
obtained
from
the
CAS
Inventory
Expert
Services
must
be
CAS#

e.
For
a
class
1
substance,
provide
a
complete
and
correct
chemical
structure
diagram.
For
a
class
2
substance
­(
1)
List
the
immediate
precursor
substances
with
their
respective
CAS
Registryiu'umbers.
(
2)
Describe
the
nature
of
the
reaction
or
process.
(
3)
Indicate
the
range
of
composition
and
the
typical
composition
(
where
appropriate).
(
4)
Provide
a
correct
representative
or
partial
chemical
structure
diagram.
ar
cnmnlete
a<
can
he
known.
if
one
can
he
reasonahlv
;
Lxertained.

3
Mark
(
X)
this
box
if
you
attach
a
continuation
sheet.
.,
.
­
Part
I
­­
GENERAL
INFOR%
lATION­­
Continued
Section
B
­
CHE,
MlCAL
IDEXTITY
ISFORMATION
­­
Continued
2.
Polymers
(
For
a
definition
of
polymcr,
see
the
Instructions
Manual.)

a.
Indicate
the
number­
average
weight
of
the
lowest
molecular
wight
composition
of
the
polymer
you
intend
to
manufacture.
Indicate
maximum
weight
percent
of
low
molecular
wcight
species
(
not
including
residual
monomers,
reactants,
or
solvents)
below
500
and
below
1.000
absolute
molecular
weight
of
that
composition.

Descrihe
ihe
methods
of
measurement
or
the
basis
for
your
estimates:
GPC
[
71
Other
0:
(
Specify)

i)
lowest
number
average
molecular
weight:

ii)
maximum
weight
YObelow
500
molecular
weight:

iii)
maximum
weight
%
I
below
1000
molecular
weight:

Monomer
or
other
reactant
and
CAS
Regishy
Number
Confi­
Typical
Identity
Confi­
Maximum
dential
composition
Mark
(
X)
dential
residual
(
1)
(
2)
(
3
1
(
4)
(
5)
(
6)
Conii­

Confidential
(
7)
X
%
X
YQ
x
X
IxI
%
I
c
Please
identify
which
method
you
used
to
develop
or
obtain
the
specified
chemical
identity
information
reported
in
this
notice
(
check
one)

@
Method
1
(
CAS
Inventory
Expert
Service
­
a
copy
of
the
identification
report
17Method
2
(
other
source)

e
Provide
a
correct
representative
or
partial
chemical
structure
diagram,
as
complete
as
can
be
known,
if
one
can
be
reasonably
ascertained
a
Mark
(
X)
this
box
if
you
attach
a
continuation
sheet.

EPA
FORM
7710­
25
(
Rev.
5­
95)
Page
5
.,,
,
j
,,,.
_,__
.,
.*­,,:­,,
I
',,'
I/,.
,'&.'

Part
I
­­
GENEM,
L
INFORMATION
­­
Continued
Section
B
­
CHEMICM~
IUE,
XTITY
1SFOR.
MATION
­
Continued
3.
Impurities
(
a)
­
Identify
each
impurin.
that
may
be
reasonably
anticipated
to
be
present
in
the
chemical
substance
as
manufactured
for
cornmerciai
purpose.
Provide
the
CAS
Registry
Number
if
available.
If
there
are
unidentified
impurities,
enter
"
unidentified."

percrn
t
dentiai
(
a)
(
b)
None
known
'%,

II
%

I
7
2
Mark
(
X)
this
box
if
you
attach
a
continuation
sheet.
Synonyms
­
Enter
any
chemical
synonyms
for
the
new
chemical
identified
in
subsection
1
or
2.

3
Mark
(
X)
this
box
if
you
attach
a
continuation
sheet.

.
Trade
identification
­
List
trade
names
for
the
new
chemical
substance
identified
in
subsection
I
or
2
r]
Mark
(
X)
this
box
if
you
attach
a
continuation
sheet
Genenc
chemical
name
­
If
you
claim
chemical
identify
as
confidential,
you
must
provide
a
genenc
name
for
your
substance
that
reveals
the
specific
chemical
identity
of
the
new
chemical
substance
to
the
maximum
extent
possible
Refer
to
the
TSCA
Chemical
Substance
Inventory,
19S5
Edition,
Appendlx
B
for
guidance
on
developing
genenc
names
Isocyanate
functional
polyester
polyether
Byproduct
CAS
Regis0
Number
(
1)
(
2)

done
known
Confidential
X
Confidenaal
2
Mark
iX)
this
box
if
you
attach
a
continuation
sheet
I
I
EPA
FORbl
7710­
15
(
Rey.
5­
95)
Page
6
,
..
..
.
I
­,
L
Maximum
first
12­
month
production
(
k3 
yr)
Maximum
12­
monthproduction
(
kg! 
yr)
Conti­
Bind:
ng
(
100%
new
chemical
substance
basis)
(
100%
new
chemical
substance
basis)
dentiai
0p:
ion
Xlark
(
x)

I
Category
of
use
(
1)
CBI
Binding
Produc­
CBI
%
in
CBI
%
of
substance
expected
per
use
CBI
(
by
function
and
application
Le.
a
dispersive
dye
Mark
(
x)
ulation
Site­
Con­*
Indus­
Corn­
Binding
for
finishing
polyester
fibers)
(
2)
(
3)
(
4)
(
5)
(
6)
(
7)
limited
sumer
trial
merciai
Option
(
9)
X
96
x
80­
X
100
OLl
Option
tion
%
Form­(
8)

Oh
Oh
9;
o/,

o/,
Oh
o/
n
Oh
Oh
Oh
o/
n
Oh
I
for
the
safe
handing.
transport,
use,
or
disposal
of
the
neu
substance
List
in
part
I11
hazard
information
you
include
9Marh
(
x)
thls
box
lfyou
attach
hazard
information
See
attached
Material
Safety
Data
Sheet
 PA
FORM
7710­
35
(
Re\
5­
95)
Page
7
Part
TI­­
HUMAN
EXPOSGRE
AND
ENVIRONMENTAL
RELEASE
!
rhe
 
Confidential 
bo\
ncu
to
any
!
wm\
ou
I
Section
.
A
­­
INDUSTRIAL
SITES
CONTROLLED
BY
THE
SUBMITTER
Mar!.
\
S)

I.
Operation
description
Confia
Identip
­­
Enter
the
identity
of
the
site
at
which
the
operation
will
occur.
dcn
t
i
al
Morris,
II6
1360
If
the
same
operation
will
occur
at
more
than
one
site,
enter
the
number
of
sites.
Identie
the
I
I
I
additional
sitks
on
a
continuation
sheet,
and
if
any
of
the
sites
have
significantly
different
production
rates
or
operations,
include
all
the
information
requested
in
this
section
for
those
­
sites
as
attachments.

c]
Mark
(
X)
this
box
if
you
attach
a
continuation
sheet
Maximum
kgbatch
(
100%
new
chemical
Houm 
batch
Batchesiyear
x
substance)

1.
Batch
Maximum
kdbatch
(
100%
new
chemical
Hours/
batch
Batchesiyear
substance)

2.
Continuous
d.
Process
description
Mark
(
X)
to
indicate
your
willingness
to
have
your
process
description
binding.

(
1)
Diagram
the
major
unit
operation
steps
and
chemical
conversions.
include
interim
storage
and
transport
containers
(
specie­
e.
g.
5
gallon
pails,
55
gallon
drum,
rail
car,
tank
truck,
etc.).
(
2)
Provide
the
identiry,
the
approximate
weight
(
by
kg/
day
or
kgbatch
on
a
100%
new
chemicalsubstance
basis),
and
entrq.
point
of
all
starting
materials
and
feedstocks
(
including
reactants,
solvents,
catalysts,
etc.).
and
of
all
products,
recycle
streams,
and
wastes.
Include
cleaning
chemicals
(
note
frequency
if
not
used
daily
or
per
batch.).
(
3)
Identify
by
number
the
points
of
release,
including
small
or
intermittent
releases,
to
the
environment
of
the
new
chemical
substance.

3Mark
t
X)
this
bok
if
you
attach
a
continuation
sheet
,

EPA
FORM
7710­
35
(
Rev
5­
95)
Page
8
Part
11­­
HUMAN
EXPOSURE
AND
ENVIRONMENTAL
RELEASE
­­
Continued
Section
A
­­
INDUSTRIAL
SITES
CONTROLLED
BY
THE
SCBMITTER
­­
Continued
Worker
activity
CBI
Protective
Equipmentl
Binding
Physical
forms(
s)
B~
ndln~
CBI
#
of
CBI
Masirnu
duration
CBJ
m
(
i,
e.,
bag
dumping,
filling
drums)
Enzineering
Controls
Option
and
%
new
Oprion
Workers
Hrsiday
Dayslyr
Mark
(
Y.)
Mark
(
XI
0)
Exposed
0)
(
2)
(
3)
(
4)
(
5)
(
6)
(
8)
(
9)
(
10)
01)
(
13
sampling
Gloves
and
safety
Solid/
liquid
X
X
alasses
970?
Drumming
Gloves
and
safety
Liquid
X
X
alasses
97%
Changing
filters
Gloves
and
safety
liquid
X
X
alasses
97%

I
Release
Amount
of
new
substance
CBI
Media
of
Control
technology
and
efficiency
(
you
may
wish
to
optionally
attach
efficiency
data)
CBI
Vumber
released
release
(
1)
(
24
(
2b)
e
6.
rwcl,
il 
r
Bindiny
(?>
(
4)
1
/
in\
I
Mark
(
X)
I
(<
h)
1
\
VI
\­,
\­­,
\­ 
I
ic\

I
1
kglbatch
Land
I
2
20
Stack
Fuel
program
with
approved
disposal
0
kglbatch
kgjbatch
Air
company
3
12
Land
kglbatch
­__­~

7)
Mark
(
X)
the
POTW
provide
nameis)
below
CB1
[
3
Navigable
Other
­
Specify
provide
NPDES
t!
CBI­
estination(
s)
of
waterway
:
leases
to
water
J
Mark
iX)
this
box
if
!
ou
attach
a
continuation
sheet
EPA
FORM
7710­
15
(
Rev.
5­
95)
Page
9
Duration
CBI
of
Exposure
1­
2
250
Protective
Equip.
/
%
in
CBI
Release
Amount
of
CBI
.
Media
ofRelease
&
Control
Fom­
Number
New
Physical
Form
and
%
dation
Substance
Technolog
Released
(
6)
(
loa)
(
lob)
(
11)
(
12)

Ventilation,
closed
5
solid
purge
kg/
day
and
adhesive
Part
II­­
HUMAN
EXPOSURE:
AND
ENVIRONMEXTAL
RELEASE
­­
Continued
Section
B
­
IXDUSTRIAL
SITES
COSTROLLED
BY
OTHERS
Complete
section
B
for
typical
processing
or
use
operations
involving
the
new
chemical
substance
dt
sites
you
do
not
control
importers
do
nor
have
to
complet~
thli
section
for
operations
outside
the
US.;
however.
you
must
report
any
processins
or
use
activities
after
import.
See
the
instructions
bfanual
Coruplere
n
sepnrnrc
secrion
B
for
each
ppe
ofprocessing
or
tisc
opcmzion
involving
!
he
new
chemical
subsrance.
If
the
same
operation
is
performed
31
more
than
one
site
describe
t11c
typical
operation
common
to
these
sites.
Identify
additional
sites
on
a
continuation
sheet.
1.
Operation
Description
­­
TOclaim
information
in
this
section
as
confidential,
circle
or
bracket
the
specific
information
that
you
claim
as
confidential.
(
1)
­­
Diagram
the
major
unit
operation
steps
and
chemical
conversions,
including
interim
storage
and
transport
containers
(
specify
­
e.
g.
5
yallon
pails.
55
gallon
drums,
rail
cars,
tank
mucks,
etc).
On
the
diagram,
identify
by
letter
and
briefly
descnbe
each
worker
activity.
(
2)
­­
Provide
the
identity,
the
approximate
weight
(
by
kgday
or
kghatch,
on
an
100%
new
chemical
substance
basis),
and
entry
point
of
all
feedstocks
(
including
reactants,
solvents
and
catalysts,
etc)
and
ali
products,
recycle
streams,
and
wastes.
Include
cleaning
chemicals
(
note
frequency
if
not
used
daily
or
per
batch).
(
3)
­­
identify
by
number
the
points
of
release,
including
small
or
intermittent
releases,
to
the
cnvironment
of
the
new
chemical
substance.
(
4)
Please
enter
the
*
of
sites
(
remember
to
identify
the
locations
of
these
sites
on
a
continuation
sheet):

1
X
ofsites
­

13)
and(
lS)­­
Mark
.
ener
#
of
CBI
CBI
of
Workers
of
Engineering
Controls/
Fomkt
Exposed
Exposure
1
ulation
I
I
Number
1
New
vity
new
substance
(~,

A
150­
90­
100
tI
1
application
system
I
~

__
~

t)
­­
B!
QTOduCtS.
(
15)
3lid
reacted
adhesive
and
cleaning
material
(
purge)
used
in
a
fuel
program
by
an
approved
disposal
company.

EPA
FORM
7710­
15
(
Rev.
5­
93
Page
IO
I
'
.
ii
I_

0PTTONAL
POLLUTION
PIRE)
VE?%
TIONINFORVLIITION
To
claim
information
in
this
section
3s
confidential
circle
or
bracket
the
specific
information
that
you
claim
as
confidential.
In
this
section
you
may
provide
infomation
not
reported
elsewhere
in
rhis
form
rezarding
your
t'fforts
to
reduce
or
minimize
potential
risks
associated
with
activities
surrounding
manufacturing,
processing,
use
and
disposal
of
the
PMXsubstance.
Please
include
new
information
pertinent
to
pollution
prevention,
including
source
reduction,
recycling
activities
and
safer
processes
or
products
available
due
to
the
new
chemical
substance.
Source
reduction
includes
the
reduction
in
the
amount
or
toxicity
of
chemical
wastes
by
technological
modification,
process
and
procedure
modification,
product
reformulation,
raw
materials
substitution,
and/
or
inventory
control.
Recycling
refers
to
the
reclamation
of
usehl
chemical
components
fi­
om
wastes
that
would
otherwise
be
treated
or
reieased
as
air
emissions
or
water
discharges,
or
land
disposal.
Descriptions
of
pollution
prevention,
source
reduction
and
recycling
should
emphasize
potential
risk
reduction
subsequent
to
compliance
with
existing
regulatory
requirements
and
can
be
either
quantitative
or
qualitative.
The
EPA
is
interested
in
the
infomation
to
assess
overall
net
reductions
in
toxicity
or
environmental
releases
and
exposures,
not
the
shifting
of
risks
to
other
environmental
media
or
non­
environmental
areas
(
e.
g.,
occupational
or
consumer
exposuri).
In
addition,
information
on
the
relative
cost
or
performance
characteristics
of
the
PMN
substance
to
potential
alternatives
may
be
provided.
All
information
provided
in
this
section
will
be
taken
into
consideration
during
the
review
of
this
substance.
See
Instructions
Manual
and
Pollution
Prevention
Guidance
manual
for
guidance
and
iolume
manufactured;
(
3)
a
reduction
in
the
generation
of
waste
materials
through
recycling,
source
reduction
or
other
means;
(
4)
a
­
eduction
in
potential
toxicity
or
human
exposure
and/
or
environmental
release;
(
5)
an
increase
in
product
performance,
a
decrease
in
.
he
cost
of
production
andor
improved
operation
efficiency
of
the
new
chemical
substance
in
comparison
to
existing
chemical
;
ubstances
used
in
similar
application;
or
(
6)
the
extent
to
which
the
new
chemical
substance
may
be
a
substitute
for
an
existing
iubstance
that
poses
a
greater
overall
risk
to
human
health
or
the
environment.
~
'.

]
Mark
(
X)
this
box
if
you
attach
a
continuation
sheet.

EPA
FORM
7710­
35
(
Rev.
5­
95)
Page
1I
Part
I11
­­
LIST
OF
ATTACH3lENTS
GPC
Attachment
name
Attachment
Confi­
page
nurnbeds)
dential
Material
Safetv
Data
Sheet
IMSDS)
14­
21
A
Infrared
Spectrum
22
k
Analysis
1I
23­
24
I
b
A
Continuation
Sheet
for
Part
1,
Section
B.
2.
e
II
25
k
CAS
Inventory
Expert
Service
Report
26
I.
x
Test
Marketing
Plan
27­
28
k
Product
Bulletin
29­
30
L
!
r]
Marh
(
X)
this
box
if
you
attach
a
ContinLiation
sheet
Enter
the
attachment
name
and
number
EP.
4
FOFW
77
10­
23
(
Rev
5­
95)
Page
12
i
PHYSICAL
AND
CI3EMIC.
a
PROFERTIES
WORKSHEET
To
ass~
ri Pi\',
rcvIew
of
phyical
and
chcmical
properties
data,
plcase
complete
the
folIo~%
ing
worksheet
for
data
you
Drovide
and
is
not
a
substitute
for
submission
of'
test
data.
Property
Mark
Page
Value
Measured
o$
Conri
x)
if
number
Estimate
dcntlai
>
lark
(
S
(
8)
provided
(
b)
!
C)
(
M
orE)
(
dl
Physical
state
of
neat
substance
Vapor
pressure
@,
Temperature
Density/
relative
density
Solubility
@
Temperature
Solvent
­(
SI
­
m
­(
g)

"
C
Ton
gJcm3
"
C
I
git
Solubility
in
water
@
Temperature
"
C
git
Melting
temperature
.~
"
C
Boiling
/
sublimation
temperature@
torrpressure
"
C
Spectra
Dissociation
constant
Particle
size
distribution
Octanol
/
water
partition
coefficient
..
.,
a1
Henry's
Law
constant
ATTACHMENT
PAGE
13
.­­­­­__­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­
Material
Safety
Cata
ShEet
INFORMATION
TELEPHONZ
NO.
1­
919­
433­
1334
MSDS
No:
5959
j
7
i
c
IForb0
Adhesives,
LLC
P.
O.
Box
110447
ALL
CHEMICXG
EMERGENCIES
Research
Triangle
Park,
NC
27709­
0447
1­
800­
424­
9300
1.
PRODUCT
IDENTIFICATION
i­
Trade
Name:
L
Chemical
Family:
Polyurethane
Intended
Use:
Hot
melt
adhesive
WPA
Hazard
Classification
Health
Hazard:
Fire
Hazard:
Reactivity:
Special
Hazard:

HMLS
Hazard
Classification:

Health:
Flammability:
Reactivity:
Personal
Protection:
2
1
1
2*
1
1
Moderate
Hazard/
Chronic
Effect
Slight
Hazard
Slight
Hazard
2.
COMPOSITION
/
INFORMATION
ON
INGREDIENTS
ACGIH
TLV
OSHA
­
2s
No.
Name
?
wA
STEL
PEL
AMOUNT
101688
4,4'­
Methylenediphen
0.005
ppm
NE
0.02
ppm
2.00
­
3.00
%
yl
Diisocyanate
?
roprietary
Experimental
NE
.
NE
NE
97.00
­
99.00
Polyurethane
Resin
Refer
to
Section
8,
Subheading
"
Exposure
Guidelines",
for
additional
information
concerning
exposure
limits.

._________­____­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­

HAZARDS
IDENTIFICATION
mergency
Overview:
Appearance:
Blue
Solid
at
room
temperature.
Slight
Aromatic
odor
Vapors
may
irritate
eyes,
nose,
throat,
and
skin.
Inhalation
may
cause
an
allergic
respiratory
reaction.
Contact
may
cause
skin
sensitization,
an
allergic
reaction
which
becomes
evident
on
re­
exposure
to
this
,
material.
mte(
s)
of
Entry:
Inhalation
of
vapors
and
fumes,
and
skin
contact.
=
ut@
Exposure:
IN  ALATION:
Harmful
if
inhaled.
Inhalation
of
vapor
or
ae'rosol
­
may
cause
irritation
to
the
respiratory
tract
(
nose,
throat,
and
lungs).
IEhalation
/
Z
xrzy
cause
asthma­
like
symptoms,
including
coughing,
wheezing,
tightness
of
.­­
4
'
.­
Material
Safety
Data
Sheet
I
<'
­,
7
1
kt
LP.
TFOFNATfON
TI'EILZIPIIO~
HO.
1­
919­
433­
1334
L,
,
x­>­\­/\­/
\
I
1.4
MSDS
NO:
5939
c
1I
.
J
1­
7
Forbo
Acihesives,
LLC
P.
O.
Box
110447
ALL
CHrnIC>
L
dm2
Xesearch
Triansle
Park,
NC
27709­
0447
1­
800­
424­
93
Effective
Cate:
02/
07/
03
chest,
shortness
of
breath,
headache
and
reduced
lung
function.
Persons
with
preexisting,
non­
specific
bronchial
hyperreactivity
can
respond
to
concentrations
below
the
Threshold
Limit
Value
(
TLV)
with
similar
symptoms
as
well
as
asthma
attack.
Exposure
well
above
the
TLV
may
lead
to
bronchitis,
bronchial
spasms
and
pulmonary
edema
(
fluid
in
the
lungs).
These
effects
are
usually
reversible.
Chemical
hypersensitivity
pneumonitis,
with
flu­
like
symptoms
(
i.
e.
fever,
chills),
ha5
also
been
reported.
These
symptoms
can
be
delayed
up
to
several
hours
after
exposure.
SKIN:
Contact
may
cause
skin
irritation.
Contact
may
cause
skin
sensitization,
an
allergic
reaction
which
becomes
evident
on
re­
exposure
to
this
material.
Contact
with
this
material
in
a
molten
(
heated)
state
my
cause
severe
burns.
EYES:
Direct
contact
with
this
material
causes
eye
irritation.
High
vapor
concentrations
may
be
irritating.
INGESTION:
Ingestion
is
not
an
anticipated
route
of
exposure
for
this
material
in
industrial
use.
Chronic
Exposure:
Chronic
overexposure
to
isocyanate
has
been
reported
to
cause
lung
damage,
including
decrease
in
lung
function,
which
may
be
permanent.
Prolonged
or
repeated
exposure
may
cause
respiratory
sensitization,
an
allergic
reaction
that
becomes
evident
on
re­
exposure
to
this
material.
Carcinogenicity:
This
material
does
not
contain
0.1%
or
more
of
any
chemical
listed
by
the
International
Agency
 or
Research
on
Cancer
(
IARC),
the
National
Toxicology
Program
(
NTP),
or
regulated
by
the
Occupational
Safety
and
Health
Administration
(
OSHA)
as
a
carcinogen.

4.
FIRST
AID
MEASURES
Eye
Contact:
Immediately
flush
eyes
with
large
quantities
of
clean
water
for
at
least
15
minutes.
Get
immediate
medical
attention.
Skin
Contact:
Wash
skin
with
soap
and
water.
Remove
contaminated
clothing.
Get
medical
attention
if
irritation
develops
or
persists.
Wash
contaminated
clothing
before
reuse.
BURNS:
For
contact
with
hot
material,
imediately
immerse
the
exposed
skin
area
in
large
amounts
of
cold
water
(
or
flush
the
skin
area
with
cold
water)
to
dissipate
heat.
Do
not
remove
material
from
skin
and
do
not
remove
clothing.
Cover
affected
area
with
clean
sheeting
or
gauze.
IMM3DIATELY
SEEK
MEDICAL
ATTENTION.
Zngestion:
Do
not
induce
vomiting.
Give
the
victim
one
or
two
glasses
of
water
or
milk
to
drink.
Never
give
anything
by
mouth
to
an
unconscious
person.
Seek
medical
attention.
Inhalation:
Reimove
victim
to
fresh
air.
Keep
warm
and
qyiet.
If
not
breathing,
give
artificial
respiration.
If
breathing
is
difficult,
give
oxygen
by
trained
personnel.
GET
IMMEDIATE
KEDICAL
PTTEmION.
Is'

­
­­
i!
.­
Material
Safety
Data
Sheet
.'+
,,­;,
(;,
;;
7/,­'
\,,­,
INFORKATION
TELEPEIONE
NO.
1­
919­
433­
1334
1
L
'
i
,
i_

MSDS
NO:
5985
t
7­'
\
\
J'

Forbo
Adhesives,
LLC
P.
O.
Box
1134117
ALL
CHE24ICAL
EMERGENCIES
Research
Trizngle
Park,
NC
27709­
0447
1­
8
00­
424
­
93,
OOt­
y
;.
vuE\
iTAit*
is
Effective
Date:
02/
07/
03
5.
FIRE
FIGHTING
MZASURES
Flash
Point:
>
350
degrees
F
(>
177
degrees
C)
Flash
Point
Method
Used:
SetaFlash
Closed
Cup
Flammable
Limits
in
Air
(
Lower):
Not
available
Flammable
Limits
in
Air
(
Upper):
Not
available
Autoignition:
464
degrees
F
(
240
degrees
C)
4,4'­
Diphenyhethane
Diisocyanate
General
Hazards;
Containers
of
this
material
may
build
up
pressure
if
exposed
to
heat
(
fire).
See
information
in
Fire
Fighting
Instructions
(
below)
in
this
section.
Fire
Fighting
Extinguishing
Media:
Use
alcohol
foam,
dry
chemical,
carbon
dioxide
or
any
Class
B
fire
extinguishing
agent.
Water
may
be
unsuitable
in
extinguishing
a
fire
with
this
material.
However,
water
may
be
used
to
cool
and
prevent
the
rupture
of
containers
that
are
exposed
to
the
heat
of
a
fire.
Fire
Fighting
Equipment:
Wear
self­
containedbreathing
apparatus
(
SCBA)
and
full
fire­
fighting
protective
clothing.
Thoroughly
decontaminate
all
protective
equipment
after
use.
Fire
Fighting
Instructions:
Evacuate
all
persons
from
the
fire
area
to
an
explosion­
protectedlocation.
Move
non­
burning
material,
as
feasible,
to
a
safe
location
as
soon
as
possible.
Fire
fighters
should
be
protected
from
potential
explosion
hazard
while
extinguishing
the
blaze.
Containers
of
this
material
may
build
up
pressure
if
exposed
to
heat
(
fire).
Use
water
spray
to
cool
fire­
exposed
containers.
If
water
is
used
for
fire
fighting,
use
a
generous
amount.
The
reaction
between
this
material
and
water
may
be
vigorous.
Excess
water
limits
the
hazard
of
this
reaction.
Fire
and
Explosion
Hazards:
Closed
containers
may
rupture
when
exposed
to
extreme
heat.
Contact
of
this
material
with
water
releases
carbon
dioxide
(
a
gas).
Do
NOT
reseal
containers
that
have
been
contaminated
with
water.
Carbon
dioxide
may
increase
the
pressure
in
closed
containers
of
wet
material
and
cause
a
rupture
or
explosion.
lazardous
Combustion
Products:
Combustion
may
produce
isocyanate
vapors.
Cornbustion
may
produce
carbon
monoxide,
carbon
dioxide
and
irritating
or
toxic
vapors
and
gases.

;.
ACCIDENTAL
RELEASE
MEASURES
.
ccidentalRelease
Measures:
Vacuum
or
sweep
up
the
material
and
place
it
in
a
chexrnical
waste
container.
FOR
SMALL
SPILLS:
If
the
material
is
molten
(
hot),
allow
it
to
cool
ad
solidify,
scrape
it
up,
and
place
it
in
a
chemical
waste
container.
Decontaminate
with
a
5%
ammonia
solution.
WGE
SPILL:
Persons
not
wearing
protective
equipment
(
see
Section
8)
should
be
excluded
from
the
16
area
of
the
spill
­
til
clezn­
up
has
hen
comleted.
Ve,
ctil_
ate
Phi
=?
a=
­­
I
..­,

­
Material
Safety
Data
Sheet
+(
Z>,..\::
b
1NFOR.
MATION
TELEPHOm
NO.
1­
919­
433­
1334
­
1
(;
f
I
*­

MSDS
No:
5989
i
21
\
i
'
JForbo
F!
cihesives,
LLC
P.
O.
Box
110447
ALL
CHrnIC­
XL4
mRGENCIES
Research
Triagle
Park,
NC
27709­
0447
1­
800­
424­
9300
Effective
Date:
02/
07/
03
Page
4
decrease
the
airborne
concentration
of
vapors
or
gases.
Contain
and
absorb
large
spills
of
hot
material
with
inert
material
(
e.
g.,
dry
sand
or
earth),
then
place
in
a
chemical
waste
container.
Prevent
spilled
material
from
1)
contaminating
soil,
2)
entering
sanitary
sewers,
storn
sewers,
aqd
drainage
systems,
and
3)
entering
bodies
of
water
or
ditches
that
lead
to
waterways.
Immediately
notify
authorities
of
any
reportable
spill
as
may
be
required
pursuant
to
regulations.

7.
HANDLING
AND
STORAGE
s
I
Signal
Word:
0
WARNLNG
Hand1ing
Information:
Avoid
inhalation
and
contact
with
eyes,
skin,
and
clothing.
Wash
hands
thoroughly
after
handling
and
before
eating
or
drinking.
Remove
and
wash
contaminated
clothing
before
reuse.
Use
with
adequate
ventilation.
Avoid
breathing
vapor
or
fumes.
Do
not
allow
water
to
contact
the
material.
It
may
react
violently
with
water.
Do
not
use
this
material
if
it
is
wetted
or
mixed
with
water.
Water
will
boil
at
glue­
pot
temperatures
and
cause
dangerous
spattering
of
molten
material.
Empty
drums
should
be
completely
drained,
properly
bunged,
and
promptly
returned
to
a
dm
reconditioner
or
properly
disposed.
Storage
Information:
Store
in
a
cool,
well
ventilated
space
away
from
incompatible
materials.
Keep
container
closed
when
not
in
use.
Keep
contents
away
from
moisture.
Due
to
reaction
with
water,
producing
carbon
dioxide
gas,
a
hazardous
build­
up
of
pressure
could
result
if
contaminated
containers
are
re­
sealed.

8.
EXPOSURE
CONTROLS
/
PERSONAL
PROTECTION
Exposure
Guidell
7
nes:
The
Occupational
Safety
and
Health
Administration
(
OSHA),
has
established
for
4,4'­
DiphenylmethaneDiisocyanate
(
MDI),
a
Permissible
Exposure
Limit
(
PEL)
of
0.02
ppm
ceiling,
not
to
be
exceeded
at
any
time.
The
,
American
Conference
of
Governmental
Industrial
Hygenists
(
ACGIH)
have
established,
for
4,4'­
DiphenylmethaneDiisocyanate,
a
Threshold
Limit
Value
(
TLV)
of
0.
005
ppm
Time
Weighted
Average
(
TWA)
for
an
8­
hourworkday
and
a
40­
hour
work
week.
Zngineering
Controls:
Use
process
enclosures,
Local
exhaust
ventilation,
or
other
engineerizg
controls
to
maintain
airborne
concentrations
below
regulatory
and
recornended
occupational
exposure
limits.
See
occupational
exposure
limits
in
Section
2
and
under
Exposure
Guidelines
in
Section
8.
*
e
Protection:
Wear
1)
safety
glasses
with
side
shields
and
a
faceshield
or
2)
goggles
and
a
faceshield.
Facilities
storing
or
utilizing
this
material
should
be
17
equipped
with
zn
eyewash
station
and
safety
shower.
kin
Protection:
,
><
lh
.
if,,
_
c.
_­­_______________­_­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­
Haterial
Safety
Data
Sheet
INFORMATION
TELE3HOm
NO.
1­
919­
433­
1334
,­­­\
MSDS
No:
5989
i
d
.­
iForbo
Adhesives,
LLC
P.
O.
Box
110447
­
9LL
CH,"
MiC,
aJI
,
DERGENCIES
Research
Triangle
?
ark,
NC
27709­
0447
1­
800­
424­
9300
Effective
Date:
02/
07/
03
Page
5
splashing
is
likely,
wear
impervious
clothing
and
boots
to
prevent
repeated
or
prolonged
skin
contact.
Consult
your
supplier
of
personal
protective
equipment
for
additional
instructions
on
proper
usage.
Respiratory
Protection:
If
airborne
concentrations
exceed
or
are
expected
to
exceed
the
TLV:
Wear
a
NIOSH/
MSHA­
approved
(
or
equivalent)
full­
facepieceair­
supplied
respirator
in
the
positive
pressure
mode
with
emergency
escape
provisions.
A
respiratory
protection
program
that
meets
OSHA's
29
CF'R
1910.134
and
ANSI
288.2
requirements
must
be
followed
whenever
workplace
conditions
warrant
a
respirator's
use.

9.
PHYSIC&
AND
CHMICAL
PROPERTIES
Color:
Blue
Odor:
Slight
Aromatic
Odor
Threshold:
Not
available
Physical
State:
Solid
at
room
temperature
Solubility
in
Water:
Insoluble
Vapor
Pressure:
Not
available
Specific
Gravity:
1.1
(
Water
=
1)
at
25
degrees
C
(
77
degrees
F)
Boiling
Point:
>
300
degrees
F
(
r
149
degrees
C)
Melting
Point:
Not
available
Freezing
Point:
Not
available
Evaporation
Rate:
Non­
volatile
Vapor
Density:
Not
available
%
Volatile:
Negligible
pH
:
Not
applicable
Coefficient
of
water/
oil:
Not
available
10.
STABILITY
AND
REACTIVITY
Stability:
Stable
at
normal
temperatures
and
storage
conditions.
See
Section
7
for
storage
information.
Incompatibility:
Avoid
contact
with
water,
amines,
and
alcohols.
Hazardous
Decomposition
Products:
Thermal
decomposition
may
produce
various
hyc3rocarbons
and
irritating,
acrid
vapors.
Xazardous
Polymerization:
May
occur.
Contact
with
moisture,
other
materials
which
react
with
isocyanates,
or
temperatures
above
400
F
(
204
C),
may
cause
polymerization.
londitions
to
Avoid:
Temperatures
above
ambient.
Freezing
tenperatures
(
less
than
32
degrees
F
or
0
degrees
C).
Contact
with
water.
18
­­­­__­_________­­_­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­
____________________­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­
I
.­­.
­­
Material
Safety
Data
Sheet
i
1­
l
a
,
1­
.*,

INFORM­
4TION
TE'LgPRONX
NO.*
1­
919­
433­
1334
._
cMSDS
50:
5989
t
7
i
dForbo
Adhesives,
LLC
P.
O.
sox
110447
ALL
C"
rnIC*
U
mIZG"
NC1ES
Research
Triangle
Park,
NC
27709­
0447
1­
800­
424­
9300
­
Effective
Date:
02/
07/
03
11.
TOXICOLOGIC,
RL
INFORMATION
Acute
Eye
Toxicity:
Diphenylmethane
diisocyanate:
100
mg/
24
hr
(
rabbit)
moderate
reaction,
Acute
Inhalation
Toxicity:
Diphenylmethane
diisocyanate:
inhalation
LCSO
(
rat),
178
mg/
m3
/
4
hr.
Acute
Oral
Toxicity:
Diphenylmethane
diisocyanate:
oral
LD50
(
rat),
>
4.7
g
/
kg.;
(
mouse)
2.2
53
/
kg­
Chronic/
Carcinogenicity:
This
material
does
not
contain
0.1%
or
more
of
any
chemical
listed
by
the
International
Agency
for
Research
on
Cancer
{
IARC),
the
National
Toxicology
Program
(
NTP),
or
regulated
by
the
United
States
Occupational
Safety
and
Health
Administration
(
OSHA)
as
a
carcinogen.
Chronic
overexposure
to
isocyanates
has
been
reported
to
cause
lung
damage,
including
decrease
in
lung
function,
which
may
be
permanent.
Sensitization:
MDI
has
been
shown
to
produce
derxnal
sensitization
in
laboratory
animals.
Evidence
of
respiratory
sensitization
has
also
been
observed
in
guinea
pigs.
In
addition,
there
is
some
evidence
suggestive
of
cross­
sensitization
between
different
types
of
diisocyanates.
Animal
studies
have
shown
that
respiratory
sensitization
can
be
induced
by
skin
contact
with
known
respiratory
sensitizers,
including
diisocyanates.
Reproduction:
No
known
or
reported
effects.
Mutagenicity:
This
product
is
not
known
or
reported
to
be
mutagenic.

____________________­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­­

ECOLOGICAL
INFOWATION
Ecotoxicity:
No
data
is
available
for
this
product.
Znvironmental
Fate:
No
data
is
available
for
this
product.

L3.
DISPOSAL
CONSiDEitATIONS
?
aste
Disposal
Method:
Not
a
RCRA
hazardous
waste.
Disposal
of
this
material
is
not
regulated
under
RCRA.
Consult
federal,
state
and
local
regulations
to
ensure
that
.
thismaterial
and
its
containers,
if
discarded,
is
disposed
of
in
compliance
with
all
regulatory
requirements.
"
Bnpty
containers",
as
defined
under
40
CFR
261.7
or
other
applicable
state
or
provincial
regulations
or
transportation
regulations,
are
not
classified
as
hazardous
wastes.
CIL4
iiazard
Class:
14
NOT
A
2CRA
HAZARDOUS
WASTE:
When
discarded
in
its
purchased
form,
this
material
would
not
be
regulated
as
a
RCR9
Xazardous
waste
under
40
CFR­
251.
I
Material
Safety
Data
Sheet
INFORMATION
TELEPHONE
NO.
1­
919­
433­
1334
rT
3
MSDS
No:
5985
­!
3
iJ
Forbo
Adhesives,
LLC
P.
O.
Box
119047
ALL
CE7MICFL
ENZBGENCIES
Research
Triangle
Park,
NC
27705­
044.7
1­
800­
424­
9300
Effective
Date:
02/
07/
03
Page
7
DOT
/
IATA
1
IMDG
/
TDG:
Proper
Shipping
Name:

15.
REGULATORY
INFORNaTION
Occupational
Safety
and
Health
Act
(
OSEA):
This
material
is
classified
as
a
hazardous
chemical
under
the
criteria
of
the
US
Occupational
Safety
and
Health
Administration
(
OSHA)
Hazard
Communication
Standard,
29
CFR
1910.1200.
SARA
Title
111:
Section
304
­
CERCLA:
Methylene
diphenyl
diisocyanate
(
CAS#
101­
68­
8):
Reportable
Quantity
=
5000
lbs.
SARA
Title
111:
Section
311/
312
­
Hazard
Communication
Standard
(
HCS):
This
material
is
classified
as
an
IMMEDIATE
MEAI;
TH
HAZARD.
DELAYED
HEALTH
RAZAXD,
and
REACTIVITY
HAZARD
under
the
US
Superfund
Amendment
and
Reauthorization
Act
(
Section
311/
312).
SARA
Title
111:
Section
313
Toxic
Chemical
List
(
TCL):
Diphenyhethane
Diisocyanate
(
101­
68­
8)
TSCA
Section
8(
b)
­
Inventory
Status:
This
material
is
supplied
under
the
Research
and
Development
Exemption
(
Section
(
5)
(
h)(
3)),
of
the
US
Toxic
Substances
Control
Act
(
TSCA)
.
This
material
contains
a
component
that
is
NOT
listed
on
the
TSCA
inventory.
It
may
be
used
ONLY
for
research
and
development
purposes.
rSCA
Section
12(
b)
­
Export
Notification:
This
material
does
not
contain
any
components
that
arf?
subject
to
the
US
Toxic
Substances
Control
Act
(
TSCA)
Section
12(
b)
Export
Notification
requirements.
 
anadian
Inventory
Status:
This
material
contains
components
that
are
NOT
listed
on
the
Canadian
Domestic
Substances
List
(
DSL)
or
the
Canadian
Non­
Domestic
Substances
List
(
NDSL)
.
!
anadian
WmrLS:
This
material
is
classified
by
the
Canadian
Workplace
Hazardous
Material
Information
System
as:
D2A
(
materials
causing
other
toxic
effects,
very
toxic
material)
D2B
(
materials
causing
other
toxic
effects,
toxic
material)
DlA
(
materials
causing
immediate
and
serious
toxic
effects,
very
toxic
material)
alifornia
Proposition
65:
This
product
is
not
known
to
contain
any
chemicals
listed
by
the
State
of
California
(
SafeDrinking
Water
and
Toxic
Enforcement
Act
of
1986)
to
cause
cancer
or
reproductive
toxicity.
iditiozal
Cznadia?
Regulatory
Inf3rmatiozl:
go
This
product:
coctains
the
following
c:
lernical(
s)
listsd
on
the
hTW 
S
r\

Material
Safety
Data
Sheet
INFORMZiTION
TELEPHONE
NO.
1­
919­
43
3
­
133
4
y­
2
6,
CC
FMSDS
No:
5989
I
II
­\
d1
Forbo
Adhesives,
ZLC
&

P.
O.
BGX
110447
ALL
CHXMICEJ;
EMERGENCIES
Research
Triangle
Park,
NC
27709­
0447
1­
800­
424­
9300
­

Effective
Date:
02/
07/
03
Page
8
­

Ingredient
Disclosure
List
at
or
above
the
specified
concentration
limit:
Diphenylmethane
Diisocyanate
(
CAS#
101­
68­
8)

16.
OTHER
INFORMATION
MSDS
NO:
5989
Reason
Issued:
New
Issue
Prepared
By:
Product
Safety
and
Compliance
Department
Approved
By:
Title:
Supersedes
Rate:
09/
24/
02
Disclaimer:
This
information
is
provided
in
good
faith
and
is
correct
to
the
best
of
Forbo s
knowledge
as
of
the
date
hereof
and
is
designed
to
assist
our
customers;
however,
Forbo
makes
no
representation
as
to
its
completeness
or
accuracy.
Our
products
are
intended
for
sale
to
industrial
and
comercial
customers.
We
require
customers
to
inspect
and
test
our
products
before
use
and
to
satisfy
themselves
as
to
suitability
for
their
specific
applications.
Any
use
which
Forbo
customers
or
third
parties
make
of
this
information,
or
any
reliance
on,
or
decisions
made
based
upon
it,
are
the
responsibility
of
such
customer
or
third
party.
Forbo
disclaims
responsibility
for
damages,
or
liability,
of
any
kind
resulting
from
the
use
of
this
information.
TEERE
ARE
NO
WARRANTIES
OR
REPRESENTATIONS,
EXPRESS
OR
IMPLIED,
I
ILITY
OR
FITNESS
FOR
A
PARTICULAR
PURPOSE
WITH
RESPECT
TO
 $
3IS
ION
OR
TO
THE
PRODUCT
IT
DESCRIGES.
IN
NO
EVENT
SRXLL
FO­
0
BE
LIABLE
FOR
SPECIAL,
INCIDENTAL,
OR
CONSEQUENTIAL
DAMAGES.
cli
Products
HOT
MELT
POLYURETHANE
REACTIVE
ADHE~
sIVE
1
DESCRIPTION
c­
21sa
single­
component,
fully
reactive
hot
melt
adhesive
that
cross­
links
through
a
chemical
reaction
with
moisture
found
in
the
surrounding
air
and
substrates,
to
produce
a
thermoset
adhesive.

1
APPLICATION
­.

F&
as
specifically
developed
for
use
in
bonding
and
wrapping
stiffvinyls,
stiff
veneers
and
high
pressure
laminates
(
HPL).
It
has
rapid
set
time
and
green
strength
development.

SUGGESTED
APPLICATION
METHOD
Roll
Coater
or
slot
die
SUGGESTED
APPLICATION
TEMPERATURE
250
OF
L
FEATURES
&
BENEFiTS
Ii
9
Patented
Fully
Reactive
Technology
9
In
addition
to
the
many
other
benefits
of
this
technology,
bonded
assemblies
including
9
Excellent
Cold
Resistance
0
Excellent
Creep
Resistance
0
Excellent
Environmental
Resistance
Versatility
darkly
colored
materials,
posses
exceptional
heat
resistance.

Adheres
to
many
substrates
at
temperatures
as
low
as
­
3PF
without
exhibiting
any
signs
of
bond
failure.

Cured
adhesive
film
is
extremely
tough
yet
flexible.
This
allows
for
differences
in
thermal
expansion
and
contraction
of
various
substrates
without
sacrificing
bond
performance.

Cures
to
form
a
very
strong
bond
that
is
resistant
to
heat,
cold,
moisture,
and
many
solvents.

Adheres
to
a
wide
variety
of
core
stocks
and
skins.

..
I
Products
p.
2
A
1
TYPICAL
PROPERTIES
Viscosity
@
250
OF
28,000
cps
Open
Time
60
sec.
Green
Strength
Build
250
psi
@?
15
sec.
s
Tensile
Strength
not
available
Elongation
not
available
I
2%
Secant
Modulus
not
available
ON
Softening
Point
150
OF
(
prior
to
full
cure).
Cure
Rate*
75%
in
4­
6
hours
*
dependent
upon
moisture
and
temperature
I
PACKAGlNG
FORM
1
Non­
returnable55
gallon
metal
drums
(
400
and
450
Ibs.
net)
or
5
gallon
metal
pails
(
40
Ibs.
net).
Also
available
in
drums
or
pails
with
plastic
liners.

1
STORAGE
To
ensure
maximum
stability,
product
should
be
stored
in
the
original
closed
container
in
an
interior
location
capable
of
maintaininga
constant
temperature.

1
IMPORTANT
SAFETY
INFORMATION
1
Before
using
this
or
any
other
chemical
product,
be
sure
to
read
and
understand
the
information
on
the
Material
Safety
Data
Sheet
and
Product
Labels.
Remain
aware
of
potential
hazards
and
follow
all
precautionarymeasures,
handling
instructions,
and
disposal
considerations
outlined
in
the
MSDS
and
labels.

For
help
in
a
Chemical
Emergency,
call
CHEMTRECat
1­
800­
424­
9300.

I
USE
PRECAUTION
I
Product
is
ready
to
use
as
received;
do
not
dilute
hot
melt
adhesive.
Confirm
compatibility
before
making
hot
melt
adhesive
changes.

1
TECHNICAL
SUPPORT
I
forbo
Adhesives'
technical
support
staff
has
extensive
practical
experience
with
adhesives
and
manufacturing
techniques.
Please
do
not
hesitate
to
request
our
assistance
through
your
sales
representative,
or
send
us
an
e­
mail
at
swift@
forbo­
adhesives.
corn.

Rev
0502