Document ID: EPA-HQ-OPPT-2002-0006-0049
Agency: epa
Document Type: Supporting & Related Material
Title: 
Posted Date: 2002-10-16T04:00Z

Safe
Handling
I
Mixing
Program
AVANTI
INTERNATIONAL
822
Bay
Star
Blvd.
l
Webster,
TX
77598
l
(281)
486­
5600
l
800­
877­
2570
l
Fax
(281)
486­
7300
www.
AvantiGrout.
com
Hazardous
Materials
Classifications
`,
_,
2
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­.
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i
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CD
Chemical
Grout
,.
.
.
,'

'
Mixing
&
Safe
Handling
Presented
by
Jay
Guillot
t
2
ternational
History
.:
x
._
,"
,,~

Avanti
was
established
in
1978.

Avanti
is
leading
supplier
of
Acrylamide,.
Acrylic,
and
Urethane
chemical
grouts.

Avanti
also
supplies
pumps,
injection
equipment,
and
safety
gear,
1,
Personal
Safety
I
2.
Understanding
Placards
and
MSDS
3m
Personal
Protective
Equipment
­
PPE
4,
Housekeeping
5.
Storage
6&
Transportation
7.
Disposal
Issues
­
Containers
and
Grout
I.
AV­
100
AM
Powder
Mixing
2.
AV­
100
Blend
Powder
Mixing
3.
AV­
100
Liquid
Mixing
4,
AV­
118
Liquid
Mixing
5.
Grout
Additives
6.
Question
and
Answer
Session
7.
Test
for
Certification
Who
is
responsible
for
your
safety
everyday?

you
14
I
I
0
mer
.,~
",,­
I
"._

Section
3:
Physical/
Chemical
Characteristics
Appearance
and
Odor:
Odorless
white
crystalline
powder
much
like
table
salt.
Boiling
Point:
N/
L
Vapor
Pressure(
mm
Hg.):
0.03
(extremely
low)
Vapor
Density(
Air=
l):
N/
L
Specific
Gravity(
Water
=I):
l.
222g/
cm3
@
86°
F
(30%)
Melting
Point:
N/
L
Evaporation
Rate(
Butyl
Acetate=
1):
N/
L
Solubility
in
Water:
58g/
lOOg
(680F/
20°
C)
15
AV­
102
ersulfate
Section
3:
Physical/
Chemical
Characteristics
Appearance
and
Odor:
Odorless,
white
crystals.
Boiling
Point:
N/
A
Vapor
Pressure(
mm
Hg.):
N/
A
Vapor
Density(
Air=
l):
N/
A
Specific
Gravity(
Water
=
1):
1.98
Melting
Point:
Decomposes
Evaporation
Rate(
Butyl
Acetate=
1):
N/
A
Solubility
in
Water:
510/
0
@
77°
F
(25°
C)
I
,,~
"2
onomer
Section
4:
Fire
and
Explosion
Hazard
Data
I
16
Flash
Point:
273.2OF
(134°
C)
Seta
flash
Closed­
cup
Flammable
Limits:
Not
applicable,
although
dust
in
air
may
be
explosive.
Extinguishing
Media:
Water
spray,
carbon
dioxide,
or
dry
chemical.
Special
Fire
Fighting
Procedures:
Avoid
skin
contamination
and
inhalation
by
wearing
full
protective
clothing
and
self
contained
breathing
apparatus.
Approach
fire
from
upwind
to
avoid
hazardous
vapors
and
toxic
decomposition
products.
Unusual
Fire
and
Explosion
Hazards:
Thermal
decomposition
or
combustion
may
generate
toxic
gases
including
carbon
monoxide
and
ammonia.
17
rsulfate
I
/
Section
4:
Fire
and
Explosion
Hazard
Data
Flash
Point:
N/
A
Flammable
Limits:
N/
A
Extinguishing
Media:
Flood
with
water.
Special
Fire
Fighting
Procedures:
Fire
fighters
should
wear
selfcontained
breathing
apparatus
and
full
protective
clothing.
Do
not
use
carbon
dioxide
or
other
gas­
filled
fire
extinguishers,
they
will
have
no
effect
on
decomposing
Persulfate.
Use
water
sprav
to
cool
nearbv
containers
and
structures
exposed
to
fire.
Unusual
Fire
and
Explosion
Hazards:
Decomposition
of
material
releases
oxygen
that
may
intensify
fire.
The
presence
of
water
accelerates
decomposition.
1
/

x
onomer
Section
5:
Reactivity
Data
Stability:
Not
stable;
heating
to
more
than
140°
F
(60°
C)
or
exposinq
to
direct
sunliqht
may
cause
polvmerization.
Incompatibility(
Materials
to
Avoid):
Avoid
acids,
alkalis,
peroxides,
oxidizing
and
reducing
agents,
or
carbon
steel.
Decomposition:
Thermal
decomposition
or
combustion
may
generate
toxic
gases
including
carbon
monoxide,
ammonia,
and
hydrogen
cyanide.
Polymerization:
May
occur.
Store
at
80°
F
(60°
C)
with
no
exposure
to
direct
sunlight.
18
19
onium
P
,,

Section
5:
Reactivity
Data
Stability:
Stable
(becomes
unstable
in
presence
of
moisture).
Incompatibility(
Materials
to
Avoid):
Acids,
alkalis,
halides,
reducing
agents,
combustible
materials,
and
heavy
metals.
Decomposition:
Will
liberate
oxwen
that
supports
combustion,
and
oxides
of
sulfur
and
nitroaen.
Polymerization:
Will
not
occur,
20
nomer
Section
6:
Storage,
Disposal
And
Spill
Information
Storage
and
Handling:
Store
in
a
cool,
dry
place
and
away
from
heat.
Do
not
leave
product
container
open
to
atmosphere.
Take
measures
not
to
raise
dust,
mist,
or
vauor,
Disposal
Method:
Incinerate
or
treat
at
a
sewerage
plant
in
accordance
with
governmental
regulations.
Steps
to
Be
Taken
in
Case
Material
is
Released
or
Spilled:
Collect
into
a
closed
container
and
dispose
of
in
accordance
with
governmental
regulations.
Wash
out
the
area
with
nlentv
of
water.
Other
Precautions:
Wear
motective
clothinu
when
handlinq
this
product.
21
AV­
102
nium
ersulfate
ii
1
Section
6:
Storage,
Disposal
And
Spill
Information
1
Storage
and
Handling:
Store
in
a
cool,
dry
place
away
from
sources
of
heat.
Disposal
Method:
Dilute
with
plenty
of
water
and
dispose
in
accordance
with
Federal,
State
and
Local
regulations.
Steps
to
Be
Taken
in
Case
Material
is
Released
or
Spilled:
Put
material
in
an
approved
DOT
container
or
dilute
with
a
larae
cluantitv
of
water,
Other
Precautions:
u
se
protective
clothing
when
handling
this
product.

(Use
clean
plastic
or
stainless
steel
scoops
only.)
AV­
100
AM
I
i
(
5
i
22
Section
7:
Precautionary
Measures
Respiratory
Protection:
NIOSH(
National
Institute
for
Occupational
Safety
and
Health)
Approved
organic
vapor
respirator,
full
face
piece
respirator
preferred.
Ventilation:
Local
exhaust.
Protective
Clothing:
Tychem
Suit.
Eye
Protection:
Goggles,
if
using
a
half
face
piece
respirator.
Other
Protective
Equipment:
Chemical
resistant
gloves
and
boots.
Work/
Hygienic
Practices:
Shower
at
the
end
of
each
shift.
I
1
Section
7:
Precautionary
Measures
Respiratory
Protection:
Use
NIOSH
approved
respirator.
Ventilation:
Mechanical/
local
exhaust
capable
of
minimizing
dust
emissions.
Protective
Clothing:
Tychem
suit.
Eye
Protection:
Chemical
goggles
or
full
face
piece
respirator.
Other
Protective
Equipment:
Chemical
resistant
gloves
and
boots.
Work/
Hygienic
Practices:
Wash
with
soap
and
water.
Remove
contaminated
clothing.
23
n
er
24
Section
8:
Health
Related
Data
I
I
Primary
Route(
s)
of
Entry:
Skin
absorption,
Eve
contact,
and
Inhalation.
Health
Hazards:
Repeated
exposure
may
result
in
more
than
one
disease
of
the
nervous
system.
Eye
Contact:
Eye
contact
may
cause
conjunctival
irritation
and
cornea1
injury.
Skin
Contact:
Skin
contact
causes
irritation,
reddening,
and
peeling.
Inhalation:
Repeated
inhalation
affects
nervous
system.
Ingestion:
Repeated
ingestion
affects
nervous
system.
First
Aid
Procedures:
Eyes:
Flush
with
water
for
15
minutes.
Get
medical
attention.
Skin:
Wash
thoroughly
with
soap
and
water.
Get
medical
attention.
Inhalation:
Remove
to
fresh
air.
Get
medical
attention.
Ingestion:
Drink
water
and
induce
vomiting.
Take
50
grams
of
activated
charcoal
by
mouth.
Get
immediate
medical
attention.
(Never
give
anything
by
mouth
to
an
unconscious
or
convulsing
person.)
25
nium
Persulfate
Section
8:
Healt
Primary
Route(
s)
of
Entry:
Skin,
inhalation
and
Eve
contact.
Health
Hazards:
Exposure
to
high
levels
of
dust
may
cause
difficulty
in
breathing
in
sensitive
persons.
Eye
Contact:
Dust
may
irritate
the
eyes.
Skin
Contact:
Prolonged
or
repeated
contact
with
dust
may
cause
dermatitis.
Inhalation:
Breathing
dust
may
irritate
nose,
throat,
and
lungs.
Prolonged
exposure
may
cause
difficulty
in
breathing.
Ingestion:
N/
L
First
Aid
Procedures:
Eyes:
Immediately
flush
with
running
water
for
15
minutes,
lifting
upper
and
lower
eyelids
occasionally.
Get
medical
attention
if
irritation
persists.
Skin:
Immediately
wash
contaminated
area
with
water.
Remove
contaminated
clothing/
shoes
and
wash
before
reuse.
If
irritation
persists,
get
medical
attention.
Inhalation:
Remove
to
fresh
air.
If
difficulty
in
breathing
occurs,
get
immediate
medical
attention.
Ingestion:
Rinse
mouth
with
water.
Do
not
induce
vomiting.
Get
medical
attention.
(Never
give
anything
by
mouth
to
an
unconscious
or
convulsing
person.)
26
Section
9:
Toxicity
Data
,
­
I
Carcinogenicity:
This
material
is
listed
as
a
potential
carcinogen
by
the
IARC(
IWernationa/
Agency
fir
Research
on
Cancer).
In
January
1992,
American
Cyanamid
notified
EPA
that
they
had
concluded
that
"acrylamide
is
not
carcinogenic
to
mice"
and
"acrylamide
is
not
carcinogenic
in
humans
as
shown
by
two
epidemiological
studies."
LD,,:
Oral(
rat):
175
mg/
kg
27
ersulfate
,,

1
Section
9:
Toxicity
Data
Carcinogenicity:
This
material
is
not
considered
a
carcinogen.
LD,,:
Oral
(rat):
495
mg/
kg
Dermal
(rabbit):
2000
mg/
kg
28
tective
ipment
i
Respirators
Chemical
Resistant
Gloves
Chemical
Resistant
Boots
Splash
Goggles
Safety
Glasses
Chemical
Resistant
Suit
f
`:.
apor/
PlOO
Cartridges
Mliwsjil~
b>"~~~~

r­
3M
60921
BEST
COPY
AVAILABLE
i
%

32
Formaldehyde/
Organic
Vapor
1
3M
60925
1
BESTCOPYAVAILABLE
33
ong
with
this
picture?
34
ry
Protection
Standard
^
_,
",

If
you
are
required
to
wear
a
respirator,
your
employer
is
responsible
for
following:

1,
Medical
evaluation
2,
Fit
testing
3,
Training
35
BEST
COPY
AVAILABLE
Uvex
Safety
Goggles
Model
9301
36
Coolest
1
StarLite
Part
#
468M
1
37
h
Wall
Station
BEST
COPY
AVAlLABeE
Eyesaline
When
do
we
read
the
directions
for
use?
3
8
e
BEST
COPY
AVAILABLE
1
Model
727
/
3
9
BEST
COPY
AVAILABLE
N­
DEX
7005
40
t
s
i
1
SFTY­
Boots
/
DuPont
Protective
Apparel
Tip:

Beware
of
the
"Take­
Home"
Problem
"To
prevent
hazardous
materials
from
traveling
from
the
workplace
into
your
car
or
home,
always
wear
the
proper
apparel
in
the
correct
manner.
Take
care
to
doff
garments
without
contaminating
your
skin,
hair
or
street
clothing.
Showering
provides
an
added
precaution
but
cannot
totally
eliminate
contaminants
from
skin
and
hair.
And
never
take
contaminated
garments
home
for
any
reason."
42
The
best
equipment
in
the
world
will
not
protect
an
employee
unless
it
is
used
and
c
43
/
Inspect
all
PPE
before
each
use.

NEVER
use
damaged
or
contaminated
items,

1
Wear,
store,
and
clean
PPE
according
to
manufacturers
guidelines.
'

BEST
COPY
AVAILABLE
45
Which
chemicals
are
not
compatible?

Where
do
we
find
this
information?

MSDS
Sheets!
I
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1
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4
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Ali
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::

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73
I
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BEST
COPY
AVAILABLE
1
AV­
100
Liquid
in
I
BEST
COPY
AVAILABLE
93
I
AV­
100
Liquid
25
BESTCOPYAVAILABLE
BESYCOPYAVALABLE
BEST
COPY
AVAILABLE
ernational
.*,
h%
,Y
i
*W
Y
>
.^.
*

(281)
486­
5600
800­
877­
2570
Toll­
free
U.
S.
and
Canada
(281)
486­
7300
Fax
www.
AvantiGrout.
com
Hazardous
Materials
Classifications
Page
2
of
2
March
12,200l
Material
Safety
Data
Sheet
Product
Name:
Acme
/Gordon's
BARRIER
50W
Dichlobenil
Herbicide
MSDS
No.:
507­
a
Version
No.:
013
EPA
Registration
No.:
2227­
676
Handling
and
Storage
(Continued)

Precautions
to
be
Taken:
STORAGE:
Do
not
contaminate
water,
food,
or
feed
by
storage
or
disposal.

Store
product
in
original
container
only
and
in
a
locked
storage
area.
For
disposal,
rinse
thoroughly
and
securely
wrap
original
container
in
several
layers
of
newspaper
and
discard
in
trash.
Do
not
reuse
empty
container.

Other
Precautions:
NI
IK!
rx
Exp
osure
Controls/
Personal
Protection:

Ventilation
Requirements:
Good
local
ventilation
is
required.

Personal
Protective
Equipment:
CAUTION:
Harmful
if
swallowed
or
absorbed
through
the
skin.
Avoid
breathing
spray
mist.
Avoid
contact
with
skin,
eyes
or
clothing.
Wear
protective
clothing
including
rubber
gloves
when
handling.

PROTECTIVE
CLOTHING:
Wear
long
sleeves
and
pants;
chemical­
resistant
gloves
and
shoes
with
socks.

EYE
PROTECTION:
Wear
safety
glasses
or
goggles.

RESPIRATORY
PROTECTION:
If
exposure
limits
may
be
exceeded,
wear
dust/
mist
filtering
respirator
(MSHAINIOSH
approval
number
prefix
TC­
21
C),
or
a
NIOSH
approved
respirator
with
any
N,
R,
P
or
HE
filter.

IX
Physical
and
Chemical
Properties:

Boiling
Point:
Nl
Melting
Point:
Nl
Evaporation
Rate
(Butyi
Acetate
q
1)
:
NI
Vapor
Pressure
(mm
Hg.):
See
below
Vapor
Density
(Air
q
1):
Nl
Specific
Gravity
(l­
i20
q
1):
o.~~
o
Solubility
in
Water:
Wettable
powder.

Appearance
and
Odor:
Tan
powder;
aromatic.

Other
Information:
NI
Stability
and
Reactivity:

Stability:
Stable.

Incompatibility
(Materials
to
Avoid):
Strong
oxidizing
agents,
and/
or
extreme
heat.

Decomposition/
By­
Products:

Burning
may
produce
chloride
and
nitrogen
oxide
gases.

Hazardous
Polymerization:
Will
not
occur.

/XZ
Toxicological
Information:

Dermal
LDSO:
>2
g/
kg
body
weight.

XII.
Ecological
Information:

Do
not
apply
directly
to
lakes,
ponds,
or
streams.
Do
not
contaminate
water
when
disposing
of
equipment
washwater.
For
terrestrial
uses,
do
not
apply
directly
to
water,
or
to
areas
where
surface
water
is
present,
or
to
intertidal
areas
below
the
mean
high
water
mark.
Do
not
allow
spray
to
drift
onto
Ecological
Information
(Continued)

nontarget
crops
or
vegetation.

KIII.
Disposal
Considerations:

PESTICIDE
DISPOSAL:
Wastes
resulting
from
the
use
of
this
product
may
be
disposed
of
on
site
or
at
an
approved
waste
disposal
facility.

CONTAINER
DISPOSAL:
Triple
rinse
(or
equivalent).
Then
offer
for
recycling
or
reconditioning,
or
puncture
and
dispose
of
in
a
sanitary
landfill,
or
incineration,
or
if
allowed
by
state
and
local
authorities
by
burning.
If
burned
stay
out
of
smoke.

KIV.
Transport
IFformation:

The
following
guidelines
apply
for
domestic
ground
transport.
If
shipping
by
air
or
ocean,
please
contact
our
Transportation
Dept.

Freight
Class:
Herbicides,
NOI
­
NMFC
#50320
In
our
current
available
sizes,
this
product
does
not
qualify
as
a
Hazardous
Material.

bV;
Regulatory
Irzformation:

OSHA
STATUS:
This
product
is
hazardous
under
the
criteria
of
the
Federal
OSHA
Hazard
Communication
Standard
29
CFR
1910.1200.

TSCA
STATUS:
This
product
is
exempt
from
TSCA
Regulation
under
FIFRA
Section
3(
2)(
B)(
ii)
when
used
as
a
pesticide.

CERCLA
REPORTABLE
QUANTITY:
200
pounds
of
the
formulation
which
contains
100
pounds
of
Dichlobenil
SARA
TITLE
Ill:
SECTION
302
EXTREMELY
HAZARDOUS
SUBSTANCES:
None
SECTION
31
l/
312
HAZARD
CATEGORIES:
Immediate
Health
Hazard,
Delayed
Health
Hazard
SECTION
313
TOXIC
CHEMICALS:
None
RCRA
STATUS:
if
discarded
in
its
purchased
form,
this
product
would
not
be
a
hazardous
waste
either
by
listing
or
by
characteristic.
However,
under
RCRA
it
is
the
responsibility
of
the
product
user
to
determine
at
the
time
of
disposal,
whether
a
material
containing
the
product
or
derived
from
the
product
should
be
classified
as
a
hazardous
waste.
(40
CFR
261.20­
24)

/Xv7
Other
Information:

REASON
FOR
ISSUE:
To
revise
MSDS
to
the
ANSI
2400.1­
1996
format
NOTE:
NI
means
not
indicated.

The
information
and
statements
in
this
Material
Safety
Data
Sheet
are
believed
to
accurately
reflect
the
scientific
evidence
used
in
making
the
hazard
determination,
but
is
not
to
be
construed
as
a
warranty
or
representation
for
which
we
assume
legal
responsibility.
Additional
information
may
be
necessary
or
desirable
depending
on
particular,
exceptional
or
variable
conditions
or
circumstances
of
use
or
storage
or
because
of
locally
applicable
laws
or
government
regulations.
Therefore,
you
should
use
this
information
only
as
a
supplement
to
other
information
available
to
you
and
must
make
independent
determinations
of
the
suitability
of
the
information
for
your
particular
circumstances
or
conditions
and
of
the
completeness
of
the
information
available
from
all
sources
to
assure
both
the
proper
use
of
the
material
described
herein,
and
the
safety
and
health
of
employees.
Page
1
of
2
March
12,200l
Material
`Safety
Data
Sheet
Product
Name:
Acme
/Gordon's
BARRIER
50W
Dichlobenil
Herbicide
MSDS
No.:
5078
I.
Basic
Information:
Version
No.:
013
EPA
Registration
No.:
2217
I
Manufacturer:
PBl/
Gordon
Corporation
Address:
1217
West
12th
Street
City,
State
Zip:
Kansas
City,
MO
64101­
1407
Information
Contact:
Environmental;
Health,
&
Safety
Dept.

Information
Telephone
Number:
(816)
421­
4070
Emergency
Contact:
Chemtrec
Emergency
Telephone
Number:
(800)
424­
9300
1
Health
1
Flammability
0
Reactivity
E
Pen.
Protection
Last
Update:
11/
21/
00
Chemical
State:
B
Liquid
0
Gas
q
Solid
Chemical
Type:
Pure
q
Mixture
II.
Ingredients:

q
Trade
Secret
(ND
=Nor
Disclosed)

CAS
No.
Chemical
Name
%
Range
E
H
S
IARC
SARA
313
OSHA
ACGIH
O
t
h
e
r
NTP
SUB
Z
1
PEL
TLV
Limits
1194656
2,6­
Dichlorobenzonitrile
(Dichlobenil)

1332587
Kaolin
clay
14808607
Q
u
a
r
t
z
50.0
N
N
N
NN
NI
NI
NI
36.6
N
N
N
Y
N
5
mg/
m3R
2
mg/
m3R
5
mgfm3R
<2
N
Y
Y
Y
N
0.1
mg/
m3
.05
mglm3
.05
mg/
m3
EHazardous
Identification:

Hazard
Catagory:

cl
X
Acute
NChronic
q
Fire
q
Pressure
q
Reactive
Hazardous
Identification
Information:

Aromatic
tan
powder.

Irritant.
May
be
harmful
if
absorbed
through
the
skin,
or
if
swallowed.

kK
First
Aid
Measures:

Route(
s)
of
Entry:
Contact,
inhalation,
ingestion.

Health
Hazards
(Acute
and
Chronic):
EYES:
Contact
may
cause
irritation.

SKIN:
Contact
may
cause
skin
irritation.
May
be
harmful
if
absorbed
through
the
skin.

INHALATION:
May
cause
irritation
to
the
respiratory
tract.

INGESTION:
May
cause
irritation
to
the
gastrointestinal
tract.
May
be
harmful
if
swallowed.

Signs
and
Symptoms:
NI
Medical
Conditions
Generally
Aggravated
by
Exposure:
NI
Emergency
First
Aid
Procedure:
EYES:
Flush
with
clean
water
for
1
O­
1
5
minutes,
holding
lids
open.
If
irritation
persists,
seek
medical
attention.

SKIN:
Bathe
and
shampoo
with
soap
and
water
to
remove
chemicals
from
skin
and
hair.
If
irritation
persists,
seek
medical
attention.
Launder
contaminated
clothing
separately
prior
to
reuse.
First
Aid
Measures
(Continued)

INHALATION:
Remove
victim
to
fresh
air.
Apply
artificial
respiration
if
needed.
If
irritation
persists,
seek
medical
attention.

INGESTION:
Call
physician
or
Poison
Control
Center.
Drink
1
or
2
glasses
of
water
and
induce
vomiting
by
touching
back
of
throat
with
finger.
G
e
t
medical
attention.

Other
Health
Warnings:
Do
not
eat,
drink
or
smoke
when
handling
product.
Avoid
contact
with
skin,
eyes
and
clothing.

K
Fire
Fighting
Measures:

Flash
Point:
NI
F.
P.
Method:

Lower
Explosive
Limit:
NI
Upper
Explosive
Limit:
NI
Fire
Extinguishing
Media:
Foam,
C02,
Dry
Chemical,
Water.

Special
Fire
Fighting
Procedures:

Wear
self­
contained
breathing
apparatus.

Unusual
Fire
and
Explosion:
Extreme
heat
may
release
chloride
and
nitrogen
oxide
gases.
Runoff
from
fire
control
may
cause
pollution
to
surface
water.
If
pollution
occurs,
notify
local
authorities.

PT.
Accidental
Release
Measures:

Steps
to
be
Taken
in
Case
Material
is
Released
or
Spilled:
Do
not
touch
spilled
material.
See
Section
8
for
Personal
Protective
Equipment.
Contain
and
collect
the
spilled
product
for
reuse
or
disposal.
Cover
and
label
the
containers.
Wash
area
with
water
if
possible.

VTI.
Handling
and
Storage:
I
MSDS
for
Potassium
Ferricyanide
A.
R.
AVANTI
INTERNATIONAL
Page
2
of
2
a­
RECAUTIONARY
MEASURES
Respiratory
Protection:
If
material
is
heated
or
reacted
with
acid,
wear
a
NIOSH
approved
respirator
suitable
for
cyanides.
Ventilation:
Local
and
mechanical
exhaust
systems.
Protective
Clothing:
Rubber
gloves,
long­
sleeved
shirt,
trousers,
rubber
apron.
Eye
Protection:
Safety
glasses
with
side
shields.
Other
Protective
Equipment:
Eye
wash
and
safety
shower.
Work/
Hygienic
Practices:
Wash
with
soap
and
water
after
handling.

)
HEALTH
RELATED
DATA
Primary
Route(
s)
of
Entry:
Skin
absorption
and
inhalation.
Health
Hazards:
Fumes
resulting
from
thermal
decomposition
are
highly
toxic.
Eye
Contact:
May
cause
irritation.
Skin
Contact:
May
cause
irritation.
Inhalation:
May
cause
irritation.
Ingestion:
Causes
nausea
and
stomach
pain.
First
Aid
Procedures:
Eyes:
Flush
with
water
for
15
minutes.
If
irritation
develops,
get
medical
attention.
Skin:
Wash
thoroughly
with
soap
and
water.
If
irritation
develops,
get
medical
attention.
Inhalation:
Remove
to
fresh
air.
If
difficulty
in
breathing
develops,
inhale
amyl
nitrate
vapor
five
times
every
15
seconds;
give
artificial
respiration
if
necessary.
Ingestion:
If
conscious,
induce
vomiting.
(Never
give
anything
by
mouth
to
an
unconscious
or
convulsing
person.)

(
TOXICITY
DATA
*­.
D
LO:
Oral(
rat):
1600
mg/
kg
AThe
information
on
this
MSDS
is
accurate
to
the
best
of
Avanti
International's
knowledge.
Avanti
International
makes
no
express
or
implied
warranty,
and
in
no
case
shall
be
liable
for
consequential,
special
or
indirect
damages
resulting
from
the
t
use
or
handling
of
this
product.

N/
A
=Not
Applicable
N/
E
=Not
Established
N/
D
=Not
Determined
NIL
=Not
Listed
Date
Issued:
September
15,
1999
Page
1
of
2
MATERIAL
SAFETY
DATA
SHEET
AVANTI
INTERNATIONAL
CHEMTREC
Emergency
Phone:
I­
800­
424­
9300
822
Bay
Star
Blvd.
Product
Data
Information:
(281)
486­
5600
Webster,
TX
77598
1
IDENTIFICATION
Trade
Name:
Potassium
Ferricyanide
A.
R.
Ingredient(
s):
Potassium
Ferricyanide
Percent:
100
CAS
Number:
13746­
66­
2
OSHA
PEL:
N/
E
ACGIH
TLV:
N/
E
~,
HAZARD
RATINGS
NFPA:
Health:
3
Fire:
0
Reactivity:
0
Special:
None
1
PHYSICAL/
CHEMICAL
CHARACTERISTICS
Appearance
and
Odor:
Orange
to
reddish
crystals.
Boiling
Point:
N/
A
Vapor
Pressure(
mm
Hg.):
N/
A
Vapor
Density(
Air=
l):
N/
A
Specific
Gravity(
Water
=
1):
1.85
Melting
Point:
N/
L
Evaporation
Rate(
Butyl
Acetate=
l):
N/
A
Solubility
in
Water:
Soluble
j
FIRE
AND
EXPLOSION
HAZARD
DATA
Flash
Point:
N/
A
Flammable
Limits:
N/
A
Extinguishing
Media:
Use
any
material
suitable
for
products
in
the
same
area.
Special
Fire
Fighting
Procedures:
Wear
a
self­
contained
breathing
apparatus.
Unusual
Fire
and
Explosion
Hazards:
Decomposition
can
produce
toxic
fumes
of
cyanides.

/
REACTIVITY
Stability:
Stable
under
normal
conditions
Incompatibility(
Materials
to
Avoid):
Acids,
ammonia,
chromic
anhydride,
and
copper
sulfate.
Decomposition:
Will
emit
toxic
fumes
of
cyanides.
Polymerization:
N/
L
1
STORAGE,
DISPOSAL
AND
SPILL
INFORMATION
Storage
and
Handling:
Store
in
a
cool,
dry
area.
Disposal
Method:
Dispose
of
in
accordance
with
governmental
regulations.
Steps
to
Be
Taken
in
Case
Material
is
Released
or
Spilled:
Sweep
into
appropriate
containers.
Other
Precautions:
N/
L
N/
A
=Not
Applicable
N/
E
=Not
Established
N/
D
=Not
Determined
N/
L
=Not
Listed
\r5
MSDS
for
AV­
257
lcoset
AVANTI
INTERNATIONAL
Page
2
of
2
`RECAUTIONARY
MEASURES
­Respiratory
Protection:
No
respiratory
protection
should
be
needed.
Ventilation:
General
ventilation.
Protective
Clothing:
Long­
sleeved
shirt,
trousers.
Eye
Protection:
Safety
glasses.
Other
Protective
Equipment:
N/
L
Work/
Hygienic
Practices:
Wash
with
soap
and
water
after
handling.
7
[
HEALTH
RELATED
DATA
:
Primary
Route(
s)
of
Entry:
Inhalation,
skin
and
eye
contact.
Health
Hazards:
N/
L
Eye
Contact:
May
cause
temporary
eye
irritation.
Skin
Contact:
Short
single
exposure
is
not
likely
to
cause
significant
skin
irritation.
Prolonged
or
repeated
exposure
may
cause
skin
irritation.
Material
may
stick
to
skin
causing
irritation
upon
removal.
Skin
absorption
unlikely.
Inhalation:
Single
exposure
to
vapors
is
not
likely
to
be
hazardous.
Ingestion:
No
hazards
anticipated
from
swallowing
small
amounts
incidental
to
normal
handling
operations.
First
Aid
Procedures:
Eyes:
Flush
with
plenty
of
water.
Skin:
Wash
off
in
flowing
water
or
shower.
Inhalation:
Remove
to
fresh
air.
Ingestion:
Do
not
induce
vomiting
unless
directed
by
medical
personnel.
Get
medical
attention.
(Never
give
anything
by
mouth
to
an
unconscious
or
convulsing
person.)

"LTOXICITY
DATA
larcinogenicity:
N/
L
LDso:
Oral(
rat):
~5000
mg/
kg
Dermal:
N/
D
The
information
on
this
MSDS
is
accurate
to
the
best
of
Avanti
International's
knowledge.
Avanti
International
makes
no
express
or
implied
warranty,
and
in
no
case
shall
be
liable
for
consequential,
special
or
indirect
damages
resulting
from
the
use
or
handling
of
this
product.

N/
A
=Not
Applicable
N/
E
=Not
Established
N/
D
=Not
Determined
/y6
NIL
=Not
Listed
Date
issued:
June
15,200O
Page
1
of
2
~
MATERIAL
SAFETY
DATA
SHEET
I
AVANT1
INTERNATIONAL
CHEMTREC
Emergency
Phone:
I­
800­
424­
9300
822
Bay
Star
Blvd.
Product
Data
Information:
(281)
486­
5600
Webster,
TX
77598
1
IDENTIFICATION
Trade
Name:
AV­
257
lcoset
Ingredient(
s):
Proprietary
carboxylated
styrene/
butadiene
polymer
CAS
Number:
Proprietary
OSHA
PEL:
N/
L
ACGIH
TLV:
N/
L
Water
CAS
Number:
7732­
l
8­
5
Percent:
40­
62
Percent:
38­
60
1
HAZARD
RATINGS
N/
L
1
PHYSICAL/
CHEMICAL
CHARACTERISTICS
Appearance
and
Odor:
Milky
white
liquid
emulsion,
slight
odor.
Boiling
Point:
212°
F
(lOO°
C)
Vapor
Pressure(
mm
Hg.):
17.5
@
68°
F
(20°
C)
Vapor
Density:
0.624
@
80°
F
(26°
C)
Specific
Gravity(
Water
=
1):
.980
­
1.040
Melting
Point:
N/
L
Evaporation
Rate(
Butyl
Acetate):
N/
L
Solubility
in
Water:
Product
as
sold
is
dilutable.
Polymer
component
is
insoluble.

1
FIRE
AND
EXPLOSION
HAZARD
DATA
Flash
Point:
N/
A
Flammable
Limits:
N/
A
Extinguishing
Media:
Water
fog,
carbon
dioxide,
dry
chemical,
or
foam.
Special
Fire
Fighting
Procedures:
Wear
positive­
pressure,
self­
contained
breathing
apparatus
and
full
protective
gear.
Unusual
Fire
and
Explosion
Hazards:
This
material
will
not
burn
until
the
water
has
evaporated.
Residue
can
burn.
Smoke
may
contain
unidentified
toxic
and/
or
irritating
compounds.

1
REACTliflTY
Stability:
Stable.
lncompatibility(
Materials
to
Avoid):
N/
A
Decomposition:
If
burned,
smoke
may
contain
unidentified
toxic
and/
or
irritating
compounds.
Polymerization:
Will
not
occur.

1
STORAGE,
DISPOSAL
AND
SPILL
INFORMATION
Storage
and
Handling:
Store
at
temperatures
between
40°
F
and
110°
F.
May
coagulate
in
freezing
temperatures
(<
32"
F/
O"
C).
Material
may
develop
bacteria
odor
on
long­
term
storage.
Disposal
Method:
Do
not
dump
into
any
sewers,
on
the
ground,
or
into
any
body
of
water.
Any
disposal
practice
must
comply
with
Federal,
State,
and
Local
regulations.
Steps
to
Be
Taken
in
Case
Material
is
Released
or
Spilled:
Avoid
dilution
of
spill.
Collect
with
absorbent
material
and
transfer
to
appropriate
containers
for
disposal.
Water
may
be
used
for
final
cleaning
of
affected
area.
Other
Precautions:
N/
L
N/
A
=Not
Applicable
N/
E
=Not
Established
N/
D
=Not
Determined
N/
L
=Not
Listed
MSDS
for
AV­
118
Duriflex
AVANTI
INTERNATIONAL
Page
2
of
2
LsJ
ORAGE,
DISPOSAL
AND
SPILL
INFORMATION
­
~~~

`age
and
Handling:
Store
in
cool,
dry
place
(between
36°
F
and
85°
F)
in
tightly
closed
original
containers
away
from
light
and
heat.
Do
not
reuse
containers,
Disposal
Method:
Dispose
of
in
accordance
with
Federal,
State
and
Local
regulations.
If
possible,
catalyze
to
form
a
gel
for
disposal
(the
gel
formed
by
the
polymer
and
water
is
non­
hazardous).
Steps
to
Be
Taken
in
Case
Material
is
Released
or
Spilled:
Evacuate
area.
Wear
appropriate
protective
gear.
Dike
area
to
prevent
runoff.
Do
not
flush
into
drains.
If
recovery
is
not
possible,
catalyze
substance
to
form
a
gel.
Ventilate
and
wash
spill
area
with
plenty
of
water.
Large
Spill:
Pump
any
free
liquid
into
an
appropriate
closed
container.
Small
Spill:
Absorb
with
inert
absorbent
material.
Sweep
into
appropriate
closed
container.
Other
Precautions:
Do
not
let
monomeric
solution
dry
in
air.
Avoid
introducing
polymerization
catalysts
into
the
commercial
product
unless
it
is
diluted
with
water.

PRECAUTIONARY
MEASURES
Respiratory
Protection:
Wear
a
NIOSH
approved
full
face­
piece
respirator
for
organic
vapors.
If
airborne
concentrations
exceed
permissible
exposure
limits,
wear
a
NIOSH
approved
supplied
air
respirator
or
self­
contained
breathing
apparatus.
Ventilation:
Use
local
ventilation
when
possible.
Mixing
tanks
should
be
vented
to
the
outside
of
the
truck.
Protective
Clothing:
Wear
chemically
resistant
boots,
gloves,
and
chemical
suit
(Tychem
or
equivalent).
Eye
Protection:
Use
full
face­
piece
respirator
for
mixing
and
cleaning
operations,
and
chemical
splash
proof
goggles
when
not
wearing
respirator.
Other
Protective
Equipment:
Eyewash
station
and
sink
should
be
readily
available.
Work/
Hygienic
Practices:
Shower
at
the
end
of
each
shift,
Clean
and
inspect
PPE
before
reuse.
Do
not
eat,
drink,
or
smoke
in
work
area.

1
HEALTH
RELATED
DATA
Pamary
Route(
s)
of
Entry:
Skin
absorption
and
inhalation.
lth
Hazards:
Immediate
acute
health
hazard.
Delayed
chronic
health
hazard.
Prolonged
contact
may
cause
muscle
weakness,
bluish
cold
hands,
peeling
of
the
palms,
pain,
numbness,
and
a
tingling
sensation
in
the
limbs.
Accumulative
effects
may
lead
to
central
nervous
system
disturbances.
Eye
Contact:
May
cause
redness
and
irritation.
Skin
Contact:
Harmful
if
absorbed
through
the
skin;
may
cause
irritation,
redness,
and
inflammation.
Inhalation:
Vapor
or
mist
may
cause
upper
respiratory
tract
irritation.
Ingestion:
Moderately
toxic
by
ingestion;
can
cause
nausea,
diarrhea,
and
abdominal
cramps.
First
Aid
Procedures:
Eyes:
Flush
with
water
for
15
minutes.
If
irritation
persists,
get
medical
attention.
Skin:
Wash
with
soap
and
water.
Remove
contaminated
clothing.
Get
medical
attention.
Inhalation:
Remove
from
area.
If
necessary,
administer
oxygen.
If
signs
of
intoxication
exist,
get
medical
attention.
Ingestion:
Drink
l­
2
glasses
of
water
and
induce
vomiting.
Get
immediate
medical
attention.
(Never
give
anything
by
mouth
to
an
unconscious
or
convulsing
person.)
Note
to
Physician:
Treat
symptomatically;
no
specific
antidote
is
available.

[
TOXICITY
DATA
7
Carcinogenicity:
Carcinogenicity
for
this
product
has
not
been
determined.
Acrylamide
and
Formaldehyde
are
considered
probable­
or
suspected
hum&
carcinogens
by
OSHA,
NTP,
IARC
or
ACGIH.
Formaldehyde
is
a
chemical
known
to
the
state
of
California
to
cause
cancer.
LDso:
Oral
(rat):
500
mg/
kg
Dermal
(rabbit):
1830
mg/
kg
1
I
le
information
on
this
MSDS
is
accurate
to
the
best
of
Avanti
International's
knowledge.
Avanti
International
makes
no
express
or
implied
warranty,
and
in
no
case
shall
be
liable
for
consequential,
special
or
indirect
damages
resulting
from
the
use
or
handling
of
this
product.

N/
A
=Not
Applicable
N/
E
=Not
Established
N/
D
=Not
Determined
NIL
=Not
Listed
Date
Issued:
May
I%
2002
Page
1
of
2
1
MATERIAL
SAFETY
DATA
SHEET
I
AVANTI
INTERNATIONAL
CHEMTREC
Emergency
Phone:
l­
800­
424­
9300
822
Bay
Star
Blvd.
Product
Data
Information:
(281)
486­
5600
Webster,
TX
77598
j
IDENTIFICATION
Trade
Name:
AV­
118
Duriflex
Ingredient(
s):
Water
CAS
Number:
7732­
l
8­
5
OSHA
PEL:
N/
A
ACGIH
TWA:
N/
A
N­
Methylolacrylamide
CAS
Number:
924­
42­
5
OSHA
PEL:
N/
E
ACGIH
TWA:
N/
E
Acrylamide
CAS
Number:
79­
06­
I
OSHA
PEL:
0.3
mg/
m3
ACGIH
TWA:
0.03
mg/
m3
Formaldehyde
CAS
Number:
50­
00­
o
OSHA
TWA:
.75
ppm
ACGIH
STEL:
0.3
ppm
N,
N­
Methylenebisacrylamide
CAS
Number:
110­
26­
g
OSHA
PEL:
N/
E
ACGIH
TWA:
N/
E
Percent:
247
Percent:
238
Percent:
<5
Percent:
<5
Percent:
12
)
HAZARD
RATINGS
NFPA:
Health:
2
Fire:
1
Reactivity:
0
Special:
None
/
PHYSICALI6HEMICAL
CHARACTERISTICS.
Appearance
and
Odor:
Colorless
liquid,
slight
formaldehyde
odor.
Boiling
Point:
214°
F
(101°
C)
@
760mmHg
Vapor
Pressure(
mm
Hg.):
<I7
@
77°
F
(25°
C)
Vapor
Density(
Air=
l):
N/
D
Specific
Gravity(
Water
=
1):
N/
D
Melting
Point:
N/
D
Evaporation
Rate(
Butyl
Acetate=
l):
N/
A
Solubility
in
Water:
Dispersible
II
/
FIRE
AND
EXPLOSION
HAZARD
DATA
Flash
Point:
>200°
F
(93°
C)
Flammable
Limits:
N/
E
Extinguishing
Media:
Water
spray,
carbon
dioxide,
or
dry
chemical.
Special
Fire
Fighting
Procedures:
Wear
NIOSH
approved
self­
contained
breathing
apparatus
and
full
protective
clothing.
Unusual
Fire
and
Explosion
Hazards:
High
temperatures
and
fire
conditions
may
cause
rapid
and
uncontrolled
polymerization
that
can
result
in
explosions
and
the
violent
rupture
of
storage
vessels
or
containers.

/
REACTIVITY
Stability:
Stable
under
normal
handling
and
storage
conditions.
Incompatibility(
Materials
to
Avoid):
Aluminum,
iron,
copper,
bases,
acids,
oxidizing
agents,
reducing
agents,
chelating
agents,
peroxides
Decomposition:
Thermal
decomposition
may
produce
ammonia,
formaldehyde,
oxides
of
nitrogen,
and
oxides
of
carbon.
Polymerization:
May
occur.
Avoid
temperatures
above
85°
F
(29°
C)
and
incompatible
materials
N/
A
=Not
Applicable
N/
E
=Not
Established
N/
D
=Not
Determined
194
N/
L
=Not
Listed
MSDS
for
AV­
105
Ethylene
Glycol
AVANTI
INTERNATIONAL
Page
2
of
2
**
TORAGE,
DISPOSAL
AND
SPILL
INFORMATION
i
storage
and
Handling:
Keep
container
closed.
Product
may
become
a
solid
at
temperatures
below
8°
F
(­
13°
C).
Do
not
store
near
foodstuff
or
potable
water
su.
pplies.
Product
on
surfaces
can
cause
slippery
conditions.
Disposal
Method:
Dispose
of
in
accordance
with
Federal,
State,
and
Local
regulations.
Steps
to
Be
Taken
in
Case
Material
is
Released
or
Spilled:
Do
not
this
allow
material
to
enter
sewers,
public
water
supplies,
or
any
body
of
water.
Soak
small
spills
up
with
an
absorbent
material.
For
large
spills,
dike
and
pump
into
appropriate
containers
for
disposal.
Other
Precautions:
N/
L
1
PRECAUTIONARY
MEASURES
1
Respiratory
Protection:
For
most
conditions,
no
respiratory
protection
should
be
needed.
However,
if
material
is
heated
or
sprayed,
an
approved
air­
purifying
respirator
should
be
used.
Ventilation:
General
and/
or
local
exhaust
to
maintain
levels
below
exposure
limits.
Protective
Clothing:
Long­
sleeved
shirt,
trousers,
impervious
boots,
Eye
Protection:
Safety
glasses
or
full
ace
shield.
Other
Protective
Equipment:
Impervious
gloves
and
apron.
Work/
Hygienic
Practices:
Wash
thoroughly
after
handling,
and
before
eating,
drinking,
smoking
or
using
toilet
facilities.

[
HEALTH
RELATED
DATA
Primary
Route(
s)
of
Entry:
Skin
absorption,
eye
contact,
and
inhalation.
Health
Hazards:
Preexisting
skin,
eye,
and
respiratory
disorders
may
be
aggravated
by
exposure
to
this
product.
Eye
Contact:
Vapors,
mists,
and
direct
contact
may
cause
temporary
eye
irritation.
Cornea1
injury
is
unlikely.
Skin
Contact:
Essentially
nonirritating
to
the
skin,
Repeated
contact
to
large
quantities
may
result
in
absorption
of
harmful
amounts.
Contact
with
damaged
skin
may
result
in
absorption
of
harmful
amounts.
`"
3halation:
Excessive
exposure
may
cause
irritation
to
upper
respiratory
tract.
At
room
temperature,
exposures
to
vapors
dre
minimal
due
to
physical
properties;
higher
temperatures
may
generate
vapor
levels
sufficient
to
cause
adverse
effects.
Ingestion:
Single
dose
oral
toxicity
is
considered
to
be
moderate.
Small
amounts
swallowed
incidental
to
normal
handling
operations
are
not
likely
to
cause
injury;
however,
swallowing
large
amounts
may
cause
serious
injury,
even
death.
First
Aid
Procedures:
Eyes:
Flush
with
plenty
of
water.
Skin:
Wash
off
with
flowing
water.
Inhalation:
Remove
to
fresh
air.
Consult
a
physician
if
breathing
becomes
difficult.
Ingestion:
Induce
vomiting
immediately
as
directed
by
medical
personnel.
Get
medical
attention.
(Never
give
anything
by
mouth
to
an
unconscious
or
convulsing
person.)

I
TOXICITY
DATA
I
Carcinogenicity:
N/
L
LD5,
j:
Oral(
rat):
4700
mg/
kg
Dermal(
rabbit):
N/
D
,

The
information
on
this
MSDS
is
accurate
to
the
best
of
Avanti
International's
knowledge.
Avanti
International
makes
no
?xpress
or
implied
warranty,
and
in
no
case
shall
be
liable
for
consequential,
special
or
indirect
damages
resulting
from
the
,
use
or
handling
of
this
product.

N/
A
=Not
Applicable
N/
E
=Not
Established
f
PO
N/
D
=Not
Determined
N/
L
=Not
Listed
Date
issued:
September
15,
2000
Page
1
of
2
1
MATERIAL
SAFETY
DATA
SHEET
I
AVANTI
INTERNATIONAL
CHEMTREC
Emergency
Phone:
I­
800­
424­
9300
822
Bay
Star
Blvd.
Product
Data
Information:
(281)
4865600
Webster,
TX
77598
j
IDENTIFICATION
Trade
Name:
AV­
105
Ethylene
Glycol
Ingredient(
s):
Ethylene
Glycol
CAS
Number:
107­
21­
I
OSHA
PEL:
50
pprn
ACGIH
TLV:
100
mg/
m3
Percent:
>99
(
HAZARD
RATINGS
NFPA:
Health:
1
Flammability:
1
Reactivity:
0
Special:
None
PHYSICAL/
CHEMICAL
CHARACTERISTICS
Appearance
and
Odor:
Colorless
liquid,
slight
odor.
Boiling
Point:
387°
F
(197°
C)
Vapor
Pressure(
mm
Hg.):
0.12
@
77°
F
(25°
C)
Vapor
Density(
Air=
l):
2.14
Specific
Gravity(
Water
=
1):
1
.I
155
@
68/
68"
F
(20/
2O"
C)
Melting
Point:
N/
L
Evaporation
Rate(
Butyl
Acetate=
l):
N/
L
Solubility
in
Water:
Complete
1
FIRE
AND
EXPLOSION
HAZARD
DATA
Flash
Point:
247"
F/
119"
C
(Setaflash)
Flammable
Limits:
LEL:
3.2
UEL:
N/
D
Extinguishing
Media:
Water
fog
or
fine
spray,
carbon
dioxide,
dry
chemical.
Alcohol
resistent
foams
are
preferred.
Do
not
use
direct
water
stream.
Special
Fire
Fighting
Procedures:
DO
NOT
use
direct
water
stream.
Use
self­
contained
breathing
apparatus
and
full
protective
clothing.
Unusual
Fire
and
Explosion
Hazards:
N/
L
/
REACTIVITY
Stability:
Stable.
Incompatibility(
Materials
to
Avoid):
Oxidizing
materials,
strong
bases,
and
acids.
Decomposition:
Hazardous
decomposition
products
depend
upon
temperature,
air
supply,
and
the
presence
of
other
materials.
Polymerization:
Will
not
occur.

N/
A
=Not
Applicable
N/
E
=Not
Established
N/
D
=Not
Determined
N/
L
=Not
Listed
MSDS
for
AV­
103
Catalyst
SP
AVANTI
INTERNATIONAL
Page
2
of
2
,~
TORAGE,
DISPOSAL
AND
SPILL
INFORMATION
Storage
and
Handling:
Store
in
a
cool,
dry
place
away
from
sources
of
heat.
Disposal
Method:
Dilute
with
plenty
of
water
and
dispose
in
accordance
with
Federal,
State
and
Local
regulations.
Steps
to
Be
Taken
in
Case
Material
is
Released
or
Spilled:
Put
material
in
an
approved
DOT
container
(use
clean
plastic
or
stainless
steel
scoops
only)
and
dilute
with
a
large
quantity
of
water.
Other
Precautions:
N/
L
1
PRECAUTIONARY
MEASURES
Respiratory
Protection:
Use
NIOSH
approved
dust
respirator,
Ventilation:
Mechanical/
local
exhaust
capable
of
minimizing
dust
emissions.
Protective
Clothing:
Long­
sleeved
shirt,
trousers,
rubber
or
neoprene
shoes.
Eye
Protection:
Chemical
goggles
or
full
facepiece
mask.
Other
Protective
Equipment:
Rubber
or
neoprene
gloves.
Work/
Hygienic
Practices:
Wash
with
soap
and
water.
Remove
contaminated
clothing.

1
HEALTH
RELATED
DATA
Primary
Route(
s)
of
Entry:
Skin
and
eye
contact,
inhalation.
Health
Hazards:
Exposure
to
high
levels
of
dust
may
cause
difficulty
in
breathing
in
sensitive
persons.
Eye
Contact:
Dust
may
irritate
the
eyes.
Skin
Contact:
Prolonged
or
repeated
contact
with
dust
may
cause
dermatitis.
Inhalation:
Breathing
dust
may
irritate
nose,
throat,
and
lungs.
Prolonged
exposure
may
cause
difficulty
in
breathing.
Ingestion:
N/
L
First
Aid
Procedures:
Eyes:
Immediately
flush
with
running
water
for
15
minutes,
lifting
upper
and
lower
eyelids
occasionally.
Get
medical
attention
if
irritation
persists.
Skin:
Immediately
wash
contaminated
area
with
water.
Remove
contaminated
clothing/
shoes
and
wash
before
reuse.
If
irritation
persists,
get
medical
attention.
Inhalation:
Remove
to
fresh
air.
If
difficulty
in
breathing
occurs,
get
immediate
medical
attention.
Ingestion:
Rinse
mouth
with
water.
Do
not
induce
vomiting.
Get
medical
attention.
(Never
give
anything
by
mouth
to
an
unconscious
or
convulsing
person.)

j
TOXICITY
DATA
Carcinogenicity:
This
material
is
not
considered
a
carcinogen.
LD50:
Oral
(rat):
895
mg/
kg
Dermal
(rabbit):
10
g/
kg
The
information
on
this
MSDS
is
accurate
to
the
best
of
Avanti
International's
knowledge.
Avanti
International
makes
no
express
or
implied
warranty,
and
in
no
case
shall
be
liable
for
consequential,
special
or
indirect
damages
resulting
from
the
use
or
handling
of
this
product.

N/
A
=Not
Applicable
N/
E
=Not
Established
N/
D
=Not
Determined
NIL
=Not
Listed
62
Date
Issued:
June
7,200O
MATERIAL
SAFETY
DATA
SHEET
Page
1
of
2
AVANTI
INTERNATIONAL
822
Bay
Star
Blvd.
Webster,
TX
77598
CHEMTREC
Emergency
Phone:
I­
800­
424­
9300
Product
Data
Information:
(281)
486­
5600
1
IDEN~
ltiTlON
I
Trade
Name:
AV­
103
Catalyst
SP
Ingredient(
s):
Sodium
Persulfate
CAS
Number:
7775­
27­
l
OSHA
PEL:
N/
E
ACGIH
TWA:
0.1
mg/
m3
Percent:
99
HAZARD
RATINGS
NFPA
704:
Health:
1
Fire:
0
Reactivity:
1
Special:
OXY
[
PHYSICAL/
CHEMICAL
CHARACTERISTICS
Appearance
and
Odor:
Odorless,
white
crystals.
Boiling
Point:
N/
A
Vapor
Pressure(
mm
Hg.):
N/
A
Vapor
Density(
Air=
l):
N/
A
Specific
Gravity(
Water
=
1):
2.6
Melting
Point:
Decomposes
Evaporation
Rate(
Butyl
Acetate=
l):
N/
A
Solubility
in
Water:
43%
@
77°
F
(25°
C)

1
FIRE
AND
EXPLOSION
HAZARD
DATA
Flash
Point:
N/
A
Flammable
Limits:
N/
A
Extinguishing
Media:
Flood
with
water.
Special
Fire
Fighting
Procedures:
Fire
fighters
should
wear
self­
contained
breathing
apparatus
and
full
protective
clothing.
Do
not
use
carbon
dioxide
or
other
gas­
filled
fire
extinguishers,
they
will
have
no
effect
on
decomposing
persulfates.
Use
water
spray
to
cool
nearby
containers
and
structures
exposed
to
fire.
Unusual
Fire
and
Explosion
Hazards:
Decomposition
of
material
releases
oxygen
that
may
intensify
fire.
The
presence
of
water
accelerates
decomposition.

1
R
E
A
C
T
I
V
I
T
Y
Stability:
Stable
(becomes
unstable
in
presence
of
moisture).
lncompatibility(
Materials
to
Avoid):
Acids,
alkalis,
halides,
reducing
agents,
combustible
materials,
and
heavy
metals.
Decomposition:
Will
liberate
oxygen
that
supports
combustion,
and
oxides
of
sulfur
and
nitrogen.
Polymerization:
Will
not
occur.

N/
A
=Not
Applicable
N/
E
=Not
Established
N/
D
=Not
Determined
N/
L
=Not
Listed
MSDS
for
AV­
102
Catalyst
AP
AVANTI
INTERNATIONAL
Page
2
of
2
"~;
T~
RAGE,
DISPOSAL
AND
SPILL
INFORMATION
Storage
and
Handling:
Store
in
a
cool,
dry
place
away
from
sources
of
heat.
Disposal
Method:
Dilute
with
plenty
of
water
and
dispose
in
accordance
with
Federal,
State
and
Local
regulations.
Steps
to
Be
Taken
in
Case
Material
is
Released
or
Spilled:
Put
material
in
an
approved
DOT
container
(use
clean
plastic
or
stainless
steel
scoops
only)
and
dilute
with
a
large
quantity
of
water.
Other
Precautions:
N/
L
1
PRECAUTIONARY
MEASURES
Respiratory
Protection:
Use
NIOSH
approved
dust
respirator.
Ventilation:
Mechanical/
local
exhaust
capable
of
minimizing
dust
emissions.
Protective
Clothing:
Long­
sleeved
shirt,
trousers,
rubber
or
neoprene
shoes.
Eye
Protection:
Chemical
goggles
or
full
facepiece
mask.
Other
Protective
Equipment:
Rubber
or
neoprene
gloves.
Work/
Hygienic
Practices:
Wash
with
soap
and
water.
Remove
contaminated
clothing.

/
HEALTH
RELATED
DATA
1
Primary
Route(
s)
of
Entry:
Skin
and
eye
contact,
inhalation.
Health
Hazards:
Exposure
to
high
levels
of
dust
may
cause
difficulty
in
breathing
in
sensitive
persons.
Eye
Contact:
Dust
may
irritate
the
eyes.
Skin
Contact:
Prolonged
or
repeated
contact
with
dust
may
cause
dermatitis.
Inhalation:
Breathing
dust
may
irritate
nose,
throat,
and
lungs.
Prolonged
exposure
may
cause
difficulty
in
breathing.
Ingestion:
N/
L
First
Aid
Procedures:

/YUI.
Eyes:
Immediately
flush
with
running
water
for
15
minutes,
lifting
upper
and
lower
eyelids
occasionally.
Get
medical
attention
if
irritation
persists.
Skin:
Immediately
wash
contaminated
area
with
water.
Remove
contaminated
clothing/
shoes
and
wash
before
reuse.
If
irritation
persists,
get
medical
attention.
Inhalation:
Remove
to
fresh
air.
If
difficulty
in
breathing
occurs,
get
immediate
medical
attention.
Ingestion:
Rinse
mouth
with
water.
Do
not
induce
vomiting.
Get
medical
attention.
(Never
give
anything
by
mouth
to
an
unconscious
or
convulsing
person.)

1
TOXICITY
DATA
Carcinogenicity:
This
material
is
not
considered
a
carcinogen.
LD50:
Oral
(rat):
495
mg/
kg
Dermal
(rabbit):
2000
mg/
kg
The
information
on
this
MSDS
is
accurate
to
the
best
of
Avanti
International's
knowledge.
Avanti
International
makes
no
express.
or
implied
warranty,
and
in
no
case
shall
be
liable
for
consequential,
special
or
indirect
damages
resulting
from
the
use
or
handlina
of
this
DrOdUCt.

IN
A
=Not
Applicable
N/
E
=Not
Established
N/
D
=Not
Determined
N/
L
=Not
Listed
1­
5Ls
Date
Issued:
June
15,200O
MATERIAL
SAFETY
DATA
SHEET
Page
1
of
2
AVANTI
INTERNATIONAL
822
Bay
Star
Blvd.
Webster,
TX
77598
CHEMTREC
Emergency
Phone:
I­
800­
424­
9300
Product
Data
Information:
(281)
486­
5600
1
IDENTIFICATION
Trade
Name:
AV­
102
Catalyst
AP
Ingredient(
s):
Ammonium
Persulfate
CAS
Number:
7727­
54­
O
OSHA
PEL:
N/
E
ACGIH
TWA:
0.1
mg/
m3
Percent:
99
[
HAZARD
RATINGS
NFPA
704:
Health:
1
Fire:
0
Reactivity:
1
Special:
OXY
1
PHYSICAL/
CHEMICAL
CHARACTERISTICS
Appearance
and
Odor:
Odorless,
white
crystals.
Boiling
Point:
N/
A
Vapor
Pressure(
mm
Hg.):
N/
A
Vapor
Density(
Air=
l):
N/
A
Specific
Gravity(
Water
=
1):
1.98
Melting
Point:
Decomposes
Evaporation
Rate(
Butyl
Acetate=
l):
N/
A
Solubility
in
Water:
51%
@
77°
F
(25°
C)

j
FIRE
AND
EXPLOSION
HAZARD
DATA
Flash
Point:
N/
A
Flammable
Limits:
N/
A
Extinguishing
Media:
Flood
with
water.

Special
Fire
Fighting
Procedures:
Fire
fighters
should
wear
self­
contained
breathing
apparatus
and
full
protective
clothing.
Do
not
use
carbon
dioxide
or
other
gas­
filled
fire
extinguishers,
they
will
have
no
effect
on
decomposing
persulfates.
Use
water
spray
to
cool
nearby
containers
and
structures
exposed
to
fire.
Unusual
Fire
and
Explosion
Hazards:
Decomposition
of
material
releases
oxygen
that
may
intensify
fire.
The
presence
of
water
accelerates
decomposition.

)
REACTIVITY
Stability:
Stable
(becomes
unstable
in
presence
of
moisture).
Incompatibility(
Materials
to
Avoid):
Acids,
alkalis,
halides,
reducing
agents,
combustible
materials,
and
heavy
metals.
Decomposition:
Will
liberate
oxygen
that
supports
combustion,
and
oxides
of
sulfur
and
nitrogen.
Polymerization:
Will
not
occur.

N/
A
=Not
Applicable
N/
E
=Not
Established
N/
D
=Not
Determined
N/
L
=Not
Listed
MSDS
for
AV­
101
Catalyst
T
AVANTI
INTERNATIONAL
Page
2
of
2
,*
TORAGE.
DISPOSAL
AND
SPILL
INFORMATION
,

storage
and
Handling:
Store
in
a
cool,
dry,
well­
ventilated
place.
Keep
containers
tightly
closed.
Do
not
use
pressure
to
empty
containers.
Disposal
Method:
Comply
with
Federal,
State
and
Local
regulations.
Steps
to
Be
Taken
in
Case
Material
is
Released
or
Spilled:
Wear
protective
equipment
and
clothing.
For
small
spills
or
drips,
mop
or
wipe
up
and
dispose
of
in
DOT­
approved
waste
contain&
s.
For
large
spills,
same
as
above,
or
contain
by
diking
with
soil
or
other
non­
combustible
absorbent
materials,
and
then
pump
into
DOT­
approved
waste
containers.
Other
Precautions:
Keep
out
of
sewers,
storm
drains,
surface
waters
and
soil.
Do
not
cut
grind,
weld
or
drill
on
or
near
a
container.

1
PRECAUTIONARY
MEASURES
Respiratory
Protection:
NIOSH
approved
organic
cartridge
respirator.
Ventilation:
Local
exhaust.
Protective
Clothing:
Rubber
gloves,
long­
sleeved
shirt,
trousers,
rubber
apron.
Eye
Protection:
Chemical
goggles
or
full
face­
piece
respirator.
Other
Protective
Equipment:
Eyewash
and
safety
shower.
Work/
Hygienic
Practices:
Wash
thoroughly
after
handling.

j
HEALTH
RELATED
DATA
Primary
Route(
s)
of
Entry:
Skin
absorption
and
inhalation.
Health
Hazards:
Prolonged
or
repeated
exposure
may
result
in
delayed
liver
or
kidney
damage.
Eye
Contact:
Irritation.
Skin
Contact:
Dryness,
irritation,
possible
dermatitis.
A
single
prolonged
exposure
is
not
likely
to
result
in
harmful
amounts
being
absorbed.
,"""
nhalation:
Vapors
and
mists
irritate
the
nose
and
throat.
Inhalation
of
higher
concentrations
may
cause
headaches,
rausea,
vomiting
and
coma.
Ingestion:
Pain
or
discomfort
in
mouth,
chest
and
abdomen.
May
cause
nausea,
vomiting,
diarrhea,
dizziness,
faintness
and
coma.
First
Aid
Procedures:
Eyes:
Flush
with
water
for
15
minutes.
Skin:
Wash
thoroughly
with
soap
and
water.
Inhalation:
Remove
to
fresh
air.
Ingestion:
Induce
vomiting
with
water.
(Never
give
anything
by
mouth
to
an
unconscious
or
convulsing
person.)

1
TOXICITY
DATA
Carcinogenicity:
No
data
for
the
blend.
However,
the
individual
components
are
not
considered
carcinogens
by
NTP,
IARC
or
OSHA.
LDso:
No
data
found
for
the
blend;
however,
for
its
components:
Triethanolamine:
Ethylene
Glycol:
Oral(
rat):
8680
mglkg
Oral
(rat):
4700
mg/
kg
Dermal(
rabbit):
>2.0
g/
kg
Dermal
(rabbit):
19.5
g/
kg
The
information
on
this
MSDS
is
accurate
to
the
best
of
Avanti
International's
knowledge.
Avanti
International
makes
no
""
­express
or
implied
warranty,
and
in
no
case
shall
be
liable
for
consequential,
special
or
indirect
damages
resulting
from
the
Jse
or
handling
of
this
product.

N/
A
=Not
Applicable
N/
E
=Not
Established
N/
D
=Not
Determined
N/
L
=Not
Listed
Date
Issued:
September
15,
2000
MATERIAL
SAFETY
DATA
SHEET
Page
1
of
2
AVANTI
I'NTERNATIONAL
822
Bay
Star
Blvd.
Webster,
TX
77598
CHEMTREC
Emergency
Phone:
I­
800­
424­
9300
Product
Data
Information:
(281)
486­
5600
1
IDENTIFICATION
Trade
Name:
AV­
101
Catalyst
T
Ingredient(
s):
Triethanolamine
CAS
Number:
102­
71­
6
OSHA
PEL:
3
ppm
ACGIH
TLV:
3
ppm
Ethylene
Glycol
CAS
Number:
107­
21­
I
OSHA
PEL:
50
ppm
ACGIH
TLV:
50
ppm
Deionized
Water
CAS
Number:
7732­
l
8­
5
OSHA
PEL:
N/
E
Percent:
70­
80
Percent:
1
O­
20
Percent:
l­
l
0
(
HAZARD
RATINGS
NFPA:
Health:
2
Fire:
1
Reactivity:
0
Special:
None
1
[
PHYSICAL/
CHEMICAL
CHARACTERISTICS
Appearance
and
Odor:
Colorless
liquid,
slight
ammoniacal
odor.
Boiling
Point:
>387"
F
(197°
C)
Vapor
Pressure(
mm
Hg.):
Nil
Vapor
Density(
Air=
l):
6.0
est.
Specific
Gravity(
Water
=
1):
1
.I
04
Melting
Point:
N/
A
Evaporation
Rate(
Butyl
Acetate=
l):
cl
Solubility
in
Water:
Soluble
FIRE
AND
EXPLOSION
HAZARD
DATA
Flash
Point:
>24O"
F
(115°
C)
(COC)
Flammable
Limits:
LELf
i5.3
(est.)
UEL:
3.2
(est.)
Extinguishing
Media:
Water
spray,
dry
chemical,
carbon
dioxide,
alcohol
foam.
Do
not
use
direct
water
stream.
Special
Fire
Fighting
Procedures:
Wear
self­
contained
breathing
apparatus
and
full
protective
clothing.
Use
water
spray
to
cool
nearby
containers
and
structures
exposed
to
fire.
Unusual
Fire
and
Explosion
Hazards:
This
product
should
not
be
heated
above
40°
F
(4°
C)
in
the
presence
of
aluminum
due
to
excessive
corrosion
and
the
potential
for
a
chemical
reaction
releasing
flammable
hydrogen
gas.

[
REACTIVITY
Stability:
Stable
under
normal
conditions.
Avoid
exposure
to
heat,
sparks
and
open
flames.
Incompatibility(
Materials
to
Avoid):
Avoid
acids
and
oxidizing
materials.
Decomposition:
May
liberate
carbon
monoxide,
carbon
dioxide,
oxides
of
nitrogen.
Polymerization:
Will
not
occur.

N/
A
=Not
Applicable
N/
E
=Not
Established
N/
D
=Not
Determined
N/
L
=Not
Listed
\
sl
MSDS
for
AV­
100
Chemical
Grout
(Liquid)
AVANTI
INTERNATIONAL
Page
2
of
2
1
STORAGE,
DISPOSAL
AND
SPILL
INFORMATION
Storage
and
Handling:
Store
in
a
cool,
dry
place
and
away
from
heat.
Take
measures
not
to
raise
dust,
mist
and
vapor.
Provide
good
ventilation.
Wear
protective
clothing,
gloves,
boots,
goggles
and
respirators,
and
clean
them
daily
when
contaminated.
Disposal
Method:
Incinerate
or
treat
at
a
sewerage
plant
in
accordance
with
governmental
regulations.
Steps
to
Be
Taken
in
Case
Material
is
Released
or
Spilled:
Collect
into
a
closed
container
and
dispose
of
in
accordance
with
governmental
regulations.
Wash
out
the
area
with
plenty
of
water.
Do
not
create
dust.
Other
Precautions:
Store
below
104°
F
(40°
C)
with
no
exposure
to
direct
sunlight.
Do
not
leave
open
to
the
atmosphere.
Store
at
a
fixed
place.
Keep
emptied
bags
or
drums
at
a
fixed
place
until
proper
disposal.
Clean
up
the
work
area
if
contaminated.
Wash
thoroughly
in
case
of
skin
or
eye
contact.

1
PRECAUTIONARY
MEASURES
Respiratory
Protection:
Wear
a
NIOSH
approved
full
face­
piece
respirator
for
organic
vapors.
If
airborne
concentrations
exceed
permissible
exposure
limits,
wear
a
NIOSH
approved
supplied
air
respirator
or
self­
contained
breathing
apparatus.
Ventilation:
Use
local
ventilation
when
possible.
Mixing
tanks
should
be
vented
to
the
outside
of
the
truck.
Protective
Clothing:
Wear
chemically
resistant
boots,
gloves,
and
chemical
suit
(Tychem
or
equivalent).
Eye
Protection:
Use
full
face­
piece
respirator
for
mixing
and
cleaning
operations,
and
chemical
splash
proof
goggles
when
not
wearing
respirator.
Other
Protective
Equipment:
Eyewash
station
and
sink
should
be
readily
available.
Work/
Hygienic
Practices:
Shower
at
the
end
of
each
shift.
Clean
and
inspect
PPE
before
reuse.
Do
not
eat,
drink,
or
smoke
in
work
area.

*y*.
1
HEALTH
RELATED
DATA
Primary
Route(
s)
of
Entry:
Skin
absorption,
inhalation
and
ingestion.
Health
Hazards:
Repeated
exposure
affects
central
nervous
system
Eye
Contact:
Eye
irritant.
Skin
Contact:
Skin
Irritant,
causing
peeling
and
redness.
Penetrates
skin
easily.
Inhalation:
Repeated
inhalation
affects
nervous
system.
Ingestion:
Repeated
ingestion
affects
nervous
system.
First
Aid
Procedures:
Eyes:
Flush
with
water
for
15
minutes.
Skin:
Wash
thoroughly
with
soap
and
water.
Inhalation:
Remove
to
fresh
air.
Ingestion:
Induce
vomiting
with
water.
(Never
give
anything
by
mouth
to
an
unconscious
or
convulsing
person.)

1
TOXICITY
DATA
Carcinogenicity:
This
material
is
listed
as
a
potential
carcinogen
by
the
IARC.
In
January
1992,
American
Cyanamid
notified
EPA
that
they
had
concluded
that
"acrylamide
is
not
carcinogenic
to
mice"
and
"acrylamide
is
not
carcinogenic
in
humans
as
shown
by
two
epidemiological
studies."
LDsO:
(Acrylamide
Monomer)
Acute
Oral(
rat):
294
mg/
kg
Acute
Dermal(
rabbit):
252
mglkg
The
information
on
this
MSDS
is
accurate
to
the
best
of
Avanti
International's
knowledge.
Avanti
International
makes
no
express
or
implied
warranty,
and
in
no
case
shall
be
liable
for
consequential,
special
or
indirect
damages
resulting
&­­
from
the
use
or
handling
of
this
product.

N/
A
=Not
Applicable
N/
E
=Not
Established
N/
D
=Not
Determined
N/
L
=Not
Listed
6­
2
Date
Issued:
May
I%
2002
Page
1
of
2
MATERIAL
SAFETY
DATA
SHEET
/

AVANTI
INTERNATIONAL
822
Bay
Star
Blvd.
Webster,
TX
77598
CHEMTREC
Emergency
Phone:
I­
800­
424­
9300
Product
Data
information:
(281)
486­
5600
1
IDENTIFICATION
Trade
Name:
AV­
100
Chemical
Grout
(Liquid)
Ingredient(
s):
Water
CAS
Number:
7732­
l
8­
5
Acrylamide
CAS
Number:
79­
06­
l
OSHA
PEL:
0.3
mg/
m3
ACGIH
TLV:
0.03
mg/
m3
Percent:
60
Percent:
40
1
HAZARD
RATINGS
NFPA:
Health:
2
Fire:
2
Reactivity:
2
Special:
None
1
PHYSICAL/
CHEMICAL
CHARACTERISTICS
Appearance
and
Odor:
Clear,
odorless
liquid.
Boiling
Point:
212°
F
Vapor
Pressure(
mm
Hg.):
0.03
@
104°
F
(40°
C)
Vapor
Density(
Air=
l):
2.45
Specific
Gravity(
Water
=
1):
1.05
Melting
Point:
N/
A
Evaporation
Rate(
Butyl
Acetate=
l):
N/
L
Solubility
in
Water:
N/
A
1
FIRE
AND
EXPLOSION
HAZARD
DATA
Flash
Point:
N/
A.
Flammable
Limits:
N/
A
Extinguishing
Media:
Water
spray,
carbon
dioxide,
dry
chemical,
foam.
Special
Fire
Fighting
Procedures:
Avoid
skin
contamination
and
inhalation
by
wearing
full
protective
clothing
and
positive
pressure
respirator.
Approach
fire
from
upwind
to
avoid
hazardous
vapors
and
toxic
decomposition
products.
Unusual
Fire
and
Explosion
Hazards:
Thermal
decomposition
or
combustion
may
generate
toxic
gases
including
carbon
monoxide
and
ammonia.
Closed
containers
may
rupture
violently
when
heated.

1
REACTIVITY
Stability:
Stable
under
normal
conditions.
lncompatibility(
Materials
to
Avoid):
Avoid
acids,
alkalis,
peroxides,
oxidizing
and
reducing
agents,
carbon
steel
or
rust.
Decomposition:
Thermal
decomposition
or
combustion
may
generate
toxic
gases
including
carbon
monoxide
and
ammonia.
Polymerization:
May
occur.
Store
below
104°
F
(40°
C)
with
no
exposure
to
direct
sunlight.

N/
A
=Not
Applicable
N/
E
=Not
Established
N/
D
=Not
Determined
N/
L
=Not
Listed
MSDS
for
AV­
100
Chemical
Grout
AVANTI
INTERNATIONAL
Page
2
of
2
1
STORAGE,
DISPOSAL
AND
SPILL
INFORMATION
Storage
and
Handling:
Store
in
a
cool,
dry
place
and
away
from
heat.
Take
measures
not
to
raise
dust,
mist
and
vapor.
Provide
good
ventilation.
Wear
protective
clothing,
gloves,
boots,
goggles
and
respirators,
and
clean
them
daily
when
contaminated.
Disposal
Method:
Incinerate
or
treat
at
a
sewerage
plant
in
accordance
with
governmental
regulations.
Steps
to
Be
Taken
in
Case
Material
is
Released
or
Spilled:
Collect
into
a
closed
container
and
dispose
of
in
accordance
with
governmental
regulations.
Wash
out
the
area
with
plenty
of
water.
Do
not
create
dust.
Other
Precautions:
Store
below
104°
F
(40°
C)
with
no
exposure
to
direct
sunlight.
Do
not
leave
open
to
the
atmosphere.
Store
at
a
fixed
place.
Keep
emptied
bags
or
drums
at
a
fixed
place
until
proper
disposal.
Clean
up
the
work
area
if
contaminated.
Wash
thoroughly
in
case
of
skin
or
eye
contact.

/
PRECAUTIONARY
MEASURES
I
Respiratory
Protection:
Wear
a
NIOSH
approved
full
face­
piece
respirator
for
organic
vapors
and
particulates.
If
airborne
concentrations
exceed
permissible
exposure
limits,
wear
a
NIOSH
approved
supplied
air
respirator
or
selfcontained
breathing
apparatus.
Ventilation:
Use
local
ventilation
when
possible.
Mixing
tanks
should
be
vented
to
the
outside
of
the
truck.
Protective
Clothing:
Wear
chemically
resistant
boots,
gloves,
and
chemical
suit
(Tychem
or
equivalent).
Eye
Protection:
Use
full
face­
piece
respirator
for
mixing
and
cleaning
operations,
and
chemical
splash
proof
goggles
when
not
wearing
respirator.
Other
Protective
Equipment:
Eyewash
station
and
sink
should
be
readily
available.
Work/
Hygienic
Practices:
Shower
at
the
end
of
each
shift.
Clean
and
inspect
PPE
before
reuse.
Do
not
eat,
drink,
or
smoke
in
work
area.

"R­

1
HEALTH
RELATED
DATA
Primary
Route(
s)
of
Entry:
Skin
absorption,
inhalation
and
ingestion.
Health
Hazards:
Repeated
exposure
affects
central
nervous
system
Eye
Contact:
Eye
irritant.
Skin
Contact:
Skin
Irritant,
causing
peeling
and
redness.
Penetrates
skin
easily.
Inhalation:
Repeated
inhalation
affects
nervous
system.
Ingestion:
Repeated
ingestion
affects
nervous
system.
First
Aid
Procedures:
Eyes:
Flush
with
water
for
15
minutes.
Skin:
Wash
thoroughly
with
soap
and
water.
Inhalation:
Remove
to
fresh
air.
Ingestion:
Induce
vomiting
with
water.
(Never
give
anything
by
mouth
to
an
unconscious
or
convulsing
person.)
­.

/
TOXICITY
DATA
Carcinogenicity:
This
material
is
listed
as
a
potential
carcinogen
by
the
IARC.
In
January
1992,
American
Cyanamid
notified
EPA
that
they
had
concluded
that
"acrylamide
is
not
carcinogenic
to
mice"
and
"acrylamide
is
not
carcinogenic
in
humans
as
shown
by
two
epidemiological
studies."
LDxI:
(Acrylamide
Monomer)
Acute
Oral(
rat):
294
mg/
kg
Acute
Dermal(
rabbit):
252
mg/
kg
The
information
on
this
MSDS
is
accurate
to
the
best
of
Avanti
International's
knowledge.
Avanti
International
makes
am1
no
express
or
implied
warranty,
and
in
no
case
shall
be
liable
for
consequential,
special
or
indirect
damages
resulting
from
the
use
or
handling
of
this
product.

N/
A
=Not
Applicable
N/
E
=Not
Established
N/
D
=Not
Determined
N/
L
=Not
Listed
/fC
Date
issued:
May
15,
2002
Page
1
of
2
MATERIAL
SAFETY
DATA
SHEET
/

AVANTI
INTERNATIONAL
822
Bay
Star
Blvd.
Webster,
TX
77598
CHEMTREC
Emergency
Phone:
I­
800­
424­
9300
Product
Data
Information:
(281)
486­
5600
1
IDENTIF,
lCATION
Trade
Name:
AV­
100
Chemical
Grout
ingredient(
s):
Acrylamide
CAS
Number:
79­
06­
I
OSHA
PEL:
0.3
mg/
m3
ACGIH
TLV:
0.03
mg/
m3
N,
N'
Methylenebisacrylamide
CAS
Number:
11
O­
26­
9
OSHA
PEL:
N/
D
ACGIH
TWA:
N/
D
Percent:
z95
Percent:
5
1
HAZARD
RATINGS
NFPA:
Health:
2
Fire:
2
Reactivity:
2
Special:
None
1
PHYSICAL/
CHEMICAL
CHARACTERISTICS
Appearance
and
Odor:
White,
crystalline
powder,
odorless.
Boiling
Point:
N/
L
Vapor
Pressure(
mm
Hg.):
0.01
@
68°
F
(20°
C)
Vapor
Density(
Air=
l):
N/
L
Specific
Gravity(
Water
=
1):
1
.150g/
cm3
@
86°
F
(30°
C)
Melting
Point:
184°
F
(85°
C)
Evaporation
Rate(
Butyl
Acetate=
l):
N/
L
Solubility
in
Water:
2009
/lOOg
@
68°
F
(20°
C)

[
FIRE
AND
EXPLOSION
HAZARD
DATA
Flash
Point:
N/
A.
Flammable
Limits:
N/
A
Extinguishing
Media:
Water
spray,
carbon
dioxide,
dry
chemical,
foam.
Special
Fire
Fighting
Procedures:
Avoid
skin
contamination
and
inhalation
by
wearing
full
protective
clothing
and
positive
pressure
respirator,
Approach
fire
from
upwind
to
avoid
hazardous
vapors
and
toxic
decomposition
products
Unusual
Fire
and
Explosion
Hazards:
Thermal
decomposition
or
combustion
may
generate
toxic
gases
including
carbon
monoxide
and
ammonia.
Closed
containers
may
rupture
violently
when
heated.

/
REACTIVITY
Stability:
Stable
under
normal
conditions.
Incompatibility(
Materials
to
Avoid):
Avoid
acids,
alkalis,
peroxides,
oxidizing
and
reducing
agents,
carbon
steel
or
rust.
Decomposition:
Thermal
decomposition
or
combustion
may
generate
toxic
gases
including
carbon
monoxide
and
ammonia.
Polymerization:
May
occur.
Store
below
104°
F
(40°
C)
with
no
exposure
to
direct
sunlight.

N/
A
=Not
Applicable
N/
E
=Not
Established
N/
D
=Not
Determined
N/
L
=Not
Listed
MSDS
for
AV­
100
MBA
Methylenebisacrylamide
AVANTI
INTERNATIONAL
Page
2
of
2
­wr­.
/
REACTIVITY
i
Stability:
Stable.
lncompatibility(
Materials
to
Avoid):
Oxidizing
and
reducing
agents.
Decomposition:
Thermal
decomposition
or
combustion
may
produce
carbon
monoxide,
carbon
dioxide,
ammonia,
and
oxides
of
nitrogen.
Polymerization:
May
occur.

(
STORAGE,
DISPOSAL
AND
SPILL
INFORMATION
Storage
and
Handling:
Store
in
a
cool,
dry
place
and
away
from
heat.
Disposal
Method:
Dispose
of
in
accordance
with
governmental
regulations.
Steps
to
Be
Taken
in
Case
Material
is
Released
or
Spilled:
Dike
area
to
prevent
entry
into
sewers
or
waterways.
Recover
with
absorbent
material
and
place
in
approved
containers.
Other
Precautions:
Wear
protective
clothing
when
handling
this
product.

/
PRECAUTIONARY
MEASURES
Respiratory
Protection:
NIOSH
approved
respirator.
Ventilation:
Local
exhaust.
Protective
Clothing:
Long­
sleeved
shirt,
trousers.
Eye
Protection:
Goggles.
Other
Protective
Equipment:
Rubber
or
neoprene
gloves
and
boots.
Work/
Hygienic
Practices:
Shower
at
the
end
of
each
shift
and
wash
contaminated
clothes
before
re­
use.

[
HEALTH
RELATED
DATA
.
,.
CI,
b
Primary
Route(
s)
of
Entry:
Skin
absorption,
eye
contact,
and
inhalation.
Health
Hazards:
Exposure
may
aggravate
existing
liver
or
kidney
disorders.
Eye
Contact:
May
cause
irritation.
Skin
Contact:
May
cause
skin
irritation.
Inhalation:
May
produce
symptoms
of
central
nervous
system
depression
including
headache,
dizziness,
and
nausea.
Ingestion:
N/
L
First
Aid
Procedures:
Eyes:
Flush
with
water
for
15
minutes.
If
irritation
develops,
consult
a
physician.
Skin:
Wash
thoroughly
with
soap
and
water.
If
irritation
develops,
consult
a
physician.
Inhalation:
Remove
to
fresh
air.
If
breathing
is
difficult,
administer
oxygen
and
get
medical
attention.
Ingestion:
Get
medical
attention.

j
TOXICITY
DATA
LDs0:
N,
N'
Methylenebisacrylamide:
Oral(
rat)
=
390
mg/
kg
Ethylene
Glycol:
Oral(
rat)
=
4700
mg/
kg
The
information
on
this
MSDS
is
accurate
to
the
best
of
Avanti
International's
knowledge.
Avanti
International
makes
no
express
or
implied
warranty,
and
in
no
case
shall
be
liable
for
consequential,
special
or
indirect
damages
resulting
from
the
use
or
handling
of
this
product.

NIA
=Not
Applicable
N/
E
=Not
Established
N/
D
=Not
Determined
N/
L
=Not
Listed
/­
`2
Date
Issued:
September
15,
2000
Page
1
of
2
MATERIAL
SAFETY
DATA
SHEET
AVANTI
INTERNATIONAL
822
Bay
Star
Blvd.
Webster,
TX
77598
CHEMTREC
Emergency
Phone:
I­
800­
424­
9300
Product
Data
Information:
(281)
486­
5600
1
IDENTIFICATION
Trade
Name:
AV­
100
MBA
Methylenebisacrylamide
ingredient(
s):
N,
N'
Methylenebisacrylamide
CAS
Number:
11
O­
26­
9
OSHA
PEL:
N/
D
ACGIH
TWA:
N/
D
Water
CAS
Number:
7732­
l
8­
5
OSHA
PEL:
N/
A
ACGIH
TWA:
N/
A
Ethylene
Glycol
CAS
Number:
107­
21­
I
OSHA
PEL:
50
ppm
ACGIH
TWA:
N/
D
Surfactant
CAS
Number:
Proprietary
OSHA
PEL:
N/
L
ACGIH
TWA:
N/
L
Stabilizer
CAS
Number:
Proprietary
OSHA
PEL:
N/
L
ACGIH
TWA:
N/
L
Percent:
38
Percent:
38
Percent:
23
Percent:
cl
Percent:
4
1
HAZARD
RATINGS
NFPA:
N/
L
1
PHYSICAL/
CHEMICAL
CHARACTERISTICS
Appearance
and
Odor:
Viscous
white
liquid
with
mild
odor.
Boiling
Point:
N/
A
Vapor
Pressure(
mm
Hg.):
N/
L
Vapor
Density(
Air4):
N/
L
Specific
Gravity(
Water
=
I):
N/
L
Melting
Point:
N/
L
Evaporation
Rate(
Butyl
Acetate=
l):
N/
L
Solubility
in
Water:
Slight
1
FIRE
AND
EXPLOSION
HAZARD
DATA
Flash
Point:
>2OO"
F
Flammable
Limits:
N/
A
Extinguishing
Media:
Water
spray,
carbon
dioxide,
or
dry
chemical.
Special
Fire
Fighting
Procedures:
Avoid
skin
contamination
and
inhalation
by
wearing
full
protective
clothing
and
self
contained
breathing
apparatus.
Unusual
Fire
and
Explosion
Hazards:
N/
L
N/
A
=Not
Applicable
N/
E
=Not
Established
N/
D
=Not
Determined
N/
L
=Not
Listed
lb3
MSDS
for
AV­
100
AM
Acrylamide
Monomer
Page
2
of
2
AVANTI
INTERNATIONAL
rruI
/
STORAGE,
DISPOSAL
AND
SPILL
INFORMATION
Storage
and
Handling:
Store
in
a
cool,
dry
place
and
away
from
heat.
Do
not
leave
product
container
open
to
atmosphere.
Take
measures
not
to
raise
dust,
mist,
or
vapor.
Disposal
Method:
Incinerate
or
treat
at
a
sewerage
plant
in
accordance
with
governmental
regulations.
Steps
to
Be
Taken
in
Case
Material
is
Released
or
Spilled:
Collect
into
a
closed
container
and
dispose
of
in
accordance
with
governmental
regulations.
Wash
out
the
area
with
plenty
of
water.
Other
Precautions:
Wear
protective
clothing
when
handling
this
product.

/
PRECAUTIONARY
MEASURES
Respiratory
Protection:
Wear
a
NIOSH
approved
full
face­
piece
respirator
for
organic
vapors
and
particulates.
If
airborne
concentrations
exceed
permissible
exposure
limits,
wear
a
NIOSH
approved
supplied
air
respirator
or
selfcontained
breathing
apparatus.
Ventilation:
Use
local
ventilation
when
possible.
Mixing
tanks
should
be
vented
to
the
outside
of
the
truck.
Protective
Clothing:
Wear
chemically
resistant
boots,
gloves,
and
chemical
suit
(Tychem
or
equivalent).
Eye
Protection:
Use
full
face­
piece
respirator
for
mixing
and
cleaning
operations,
and
chemical
splash
proof
goggles
when
not
wearing
respirator.
Other
Protective
Equipment:
Eyewash
station
and
sink
should
be
readily
available.
Work/
Hygienic
Practices:
Shower
at
the
end
of
each
shift.
Clean
and
inspect
PPE
before
reuse.
Do
not
eat,
drink,
or
smoke
in
work
area.

1
HEALTH
RELATED
DATA
Primary
Route(
s)
of
Entry:
Skin
absorption,
eye
contact,
and
inhalation.

;­
Health
Hazards:
Repeated
exposure
may
result
in
more
than
one
disease
of
the
nervous
system.
Eye
Contact:
Eye
contact
may
cause
conjunctival
irritation
and
cornea1
injury.
Skin
Contact:
Skin
contact
causes
irritation,
reddening,
and
peeling.
Inhalation:
Repeated
inhalation
affects
nervous
system.
Ingestion:
Repeated
ingestion
affects
nervous
system.
First
Aid
Procedures:
Eyes:
Flush
with
water
for
15
minutes.
Get
medical
attention.
Skin:
Wash
thoroughly
with
soap
and
water.
Get
medical
attention.
Inhalation:
Remove
to
fresh
air.
Get
medical
attention.
Ingestion:
Drink
water
and
induce
vomiting.
Take
50
grams
of
activated
charcoal
by
mouth.
Get
immediate
medical
attention.
(Never
give
anything
by
mouth
to
an
unconscious
or
convulsing
person.)

/
TOXICITY
DATA
Carcinogenic@:
This
material
is
listed
as
a
potential
carcinogen
by
the
IARC.
In
January
1992,
American
Cyanamid
notified
EPA
that
they
had
concluded
that
"acrylamide
is
not
carcinogenic
to
mice"
and
"acrylamide
is
not
carcinogenic
in
humans
as
shown
by
two
epidemiological
studies."
LDsO:
Oral(
rat):
175
mg/
kg
The
information
on
this
MSDS
is
accurate
to
the
best
of
Avanti
International's
knowledge.
Avanti
International
makes
.­
no
express
or
implied
warranty,
and
in
no
case
shall
be
liable
for
consequential,
special
or
indirect
damages
resulting
from
the
use
or
handling
of
this
product.

N/
A
=Not
Applicable
N/
E
=Not
Established
N/
D
=Not
Determined
NIL
=Not
Listed
Date
Issued:
May
15,2002
Page
1
of
2
I
MATERIAL
SAFETY
DATA
SHEET
I
AVANT1
INTERNATIONAL
822
Bay
Star
Blvd.
Webster,
TX
77598
CHEMTREC
Emergency
Phone:
I­
800­
424­
9300
Product
Data
Information:
(281)
486­
5600
1
IDENTIFICATION
Trade
Name:
AV­
100
AM
Acrvlamide
Monomer
Ingredient(
s):
Acrylamide
CAS
Number:
79­
06­
l
OSHA
PEL:
0.30
mg/
m3
ACGIH
TWA:
0.03
mg/
m3
Percent:
nlO0
[
HAZARD
RATINGS
NFPA:
Health:
2
Fire:
2
Reactivity:
2
Special:
None
1
PHYSICAL/
CHEMICAL
CHARACTERISTICS
Appearance
and
Odor:
Odorless,
white
crystalline
powder.
Boiling
Point:
N/
L
Vapor
Pressure(
mm
Hg.):
N/
L
Vapor
Density(
Air=
l):
N/
L
Specific
Gravity(
Water
=
1):
1
.222g/
cm3
@
86°
F
(30%)
Melting
Point:
N/
L
Evaporation
Rate(
Butyl
Acetate=
l):
N/
L
Solubility
in
Water:
58g/
106g
(68"
F/
2O"
C)

1
FIRE
AND
EXPLOSION
HAZARD
DATA
Flash
Point:
273.2"
F
(134°
C)
Setaflash
Closed­
cup
Flammable
Limits:
Not
applicable,
although
dust
in
air
may
be
explosive.
Extinguishing
Media:
Water
spray,
carbon
dioxide,
or
dry
chemical.
Special
Fire
Fighting
Procedures:
Avoid
skin
contamination
and
inhalation
by
wearing
full
protective
clothing
and
self
contained
breathing
apparatus.
Approach
fire
from
upwind
to
avoid
hazardous
vapors
and
toxic
decomposition
products.
Unusual
Fire
and
Explosion
Hazards:
Thermal
decomposition
or
combustion
may
generate
toxic
gases
including
carbon
monoxide
and
ammonia.

1
R
E
A
C
T
I
V
I
N
Stability:
Not
stable;
heating
to
more
thanl40"
F
(60°
C)
or
exposing
to
direct
sunlight
may
cause
polymerization.
Incompatibility(
Materials
to
Avoid):
Avoid
acids,
alkalis,
peroxides,
oxidizing
and
reducing
agents,
or
carbon
steel.
Decomposition:
Thermal
decomposition
or
combustion
may
generate
toxic
gases
including
carbon
monoxide,
ammonia,
and
hydrogen
cyanide.
Polymerization:
May
occur.
Store
below
140°
F
(60°
C)
with
no
exposure
to
direct
sunlight.

N/
A
=Not
Applicable
N/
E
=Not
Established
N/
D
=Not
Determined
N/
L
=Not
Listed
(65
SECTION
I:
PRODUCT
IDENTIFICATION
IDENTITY
OF
THE
PRODUCT:
The
identifying
chemical
name
or
product
name
should
be
the
same
as
that
on
the
container
label.

EMERGENCY
TELEPHONE
NUMBER:
Must
be
included,
but
it
does
not
need
to
be
toll
free.

TELEPHONE
NUMBER
FOR
INFORMATION:
May
be
the
same
as
above
for
small
companies.

NAME
OF
THE
MANUFACTURER
OR
IMPORTER:
Be
sure
that
this
name
is
exactly
the
same
as
the
name
of
the
manufacturer
listed
on
the
product
label.
Small
manufacturers
sometimes
send
out
MSDS
from
the
manufacturer
of
the
raw
materials
they
mixed
to
make
the
product
or
that
they
repackaged;
this
is
improper.

ADDRESS
OF
THE
MANUFACTURER
OR
IMPORTER:
Complete
address
should
be
listed
here.

DATE
PREPARED:
MSDS
prepared
more
than
three
years
ago
are
acceptable
in
the
U.
S.,
but
an
attempt
should
be
made
to
get
an
updated
version.
Three­
year­
old
MSDS
are
invalid
in
Canada.

SIGNATURE
OF
THE
PREPARER:
Signature
is
optional.

SECTION
II:
HAZARDOUS
INGREDIENTS/
IDENTITY
INFORMATION
SPECIFIC
CHEMICAL
NAME/
IDENTITY:
Product
name
should
be
as
listed
on
the
label.

COMMON
NAME(
S):
Synonyms
should
be
listed
here.

z+.
s
CAS#:
The
number
assigned
by
the
Chemical
Abstracts
Service
for
the
chemical
or
material
is
optional.

CHEMICALS
IN
PRODUCTS
WHICH
ARE
MIXTURES:
It
used
to
be
common
for
MSDS
to
list
only
ingredients
which
had
TLVs
or
PELs.
Now
any
chemical
for
which
there
is
even
one
study
which
shows
it
may
be
capable
of
causing
harm
should
be
listed.
Toxic
chemical
comprising
more
than
1%
of
the
product
by
weight
must
be
listed.

Cancer­
causing
chemicals
which
comprise
0.1%
of
the
product
must
be
listed.

It
exposure
to
amounts
even
smaller
than
the
required
1.0
or
0.1
%
k
known
to
be
hazardous,
the
manufacturer
also
must
list
these
ingredients.
In
practice,
however,
such
hazardous
ingredients
often
go
unlisted.
For
example,
trace
amounts
of
extremely
toxic
dioxins
and
PCB's
in
many
pigments
usually
are
not
reported.
Another
example
was
seen
recently
when
interior
paint
containing
a
mercury
preservative
off­
gassed
from
walls
and
poisoned
a
young
child
and
his
family.
Investigation
revealed
that
it
was
common
practice
not
to
list
mercury
preservatives
on
MSDS
because
they
are
present
in
amounts
under
1%
withheld
by
the
manufacturer
it
they
are
trade
secrets
or
proprietary.
The
MSDS
should
state
by
whose
authority
(usually
the
state
health
department)
the
product's
identity
can
be
withheld.
Trade
secret
products
should
be
avoided
whenever
possible
since
it
is
very
difficult
and
time­
consuming
for
medical
personnel
to
get
this
data
if
there
is
an
accident
or
illness.
Even
then,
the
medical
person
must
withhold
from
the
victim
the
name
of
the
chemical
that
caused
his/
her
problem.

OSHA
PEL:
Here
the
eight­
hour
time
weighted
average
(PEL/
lWA)
should
be
listed.
The
PEL/
TWA
is
the
amount
of
the
substance
In
the
air
to
which
most
healthy
adult
workers
may
be
exposed
each
work
day,
day
after
day
without
adverse
effect.
In
general,
the
smaller
the
PEL
the
more
toxic
the
substance
although
other
factors
such
as
evaporation
rate
should
be
considered.
PELs
are
enforced
by
OSHA.

ACGIH
TLV:
Here
the
eight­
hour
time
weighted
average
(TLV/
lWA)
should
be
listed.
TLV/
TWAs
are
standards
for
workplace
air
quality
(developed
by
the
American
Conference
of
Government
Industrial
Hygienists
(ACGIH).
In
general,
the
smaller
the
TLV,
the
more
toxic
the
substance
although
other
factors
such
as
evaporation
rate
should
be
considered.
TLC
are
standards
and
are
not
enforced
by
OSHA.

OTHER
LIMITS
(OPITIONAL):
NIOSH
REL's
(Recommended
Exposure
Limits),
MRLs
(manufacturer's
recommended
limits),
MAKs
(Federal
Republic
of
Germany
Maximum
Concentration
Values
In
the
Workplace)
and
others
may
be
listed
here.

ODOR
THRESHOLD
(OPTIONAL):
The
odor
threshold
(OT)
is
required
on
Canadian
MSDS
and
is
sometimes
included
by
U.
S.
manufacturers
who
sell
to
both
countries.
OTs
are
very
useful.
They
are
the
concentrations
in
air
at
which
most
people
can
smell
the
chemicals.
If
the
OT
is
smaller
than
the
TLV,
then
the
chemical
provides
warning
before
health
effects
are
expected.
It
the
OT
is
larger
than
the
TLV,
one
is
already
at
risk
by
the
time
the
odor
can
be
detected.

PERCENT
(OPTIONAL):
If
the
percentages
are
listed,
check
to
see
if
they
add
up
to
100%.
Check
to
see
if
toxic
substances
are
a
small
or
large
proportion
of
the
product.

SECTIONIII:
PHYSICAL/
CHEMICALCHARACTERISTICS
This
section
provides
a
physical
profile
of
the
chemical
through
its
various
characteristics.
Some
physical
data
may
be
omitted
on
the
MSDS
when
it
is
not
applicable.
For
example,
some
chemicals
have
no
boiling
point
because
they
do
not
boil.
However,
this
same
chemical
may
dissociate
(break
down)
with
heat,
and
this
fact
and
the
chemicals
into
which
it
dissociates
should
appear
on
a
good
MSDS.
If
data
does
not
exist,
the
line
on
the
MSDS
where
it
ordinarily
would
appear
must
be
filled
in
to
indicate
this.
Blank
spaces
are
not
proper.

BOILING
POINT
(BP):
The
BP
is
the
temperature
at
which
the
substance
changes
rapidly,
usually
with
bubbling,
from
a
liquid
to
a
vapor.
Sometimes
called
the
"vaporization
point,"
liquids
with
low
BPS
usually
expose
workers
to
large
amounts
of
the
vapor.
If
the
vapor
is
also
flammable,
liquids
with
low
BPS
are
also
fire
hazards.
A
common
error
is
the
assumption
that
no
vapor
is
formed
(e.
g.
from
metals)
until
the
BP
is
reached.
However,
vapor
is
formed
at
far
lower
temperatures,
just
as
water
which
boils
at
212OF
evaporates
at
room
temperature.

VAPOR
PRESSURE
(mm
Hg):
VP
is
the
pressure
exerted
by
a
saturated
vapor
above
its
own
liquid
in
a
closed
container.
VPs
combined
with
evaporation
rates
are
useful
in
determining
how
quickly
materials
become
airborne,
and
thus
how
quickly
a
worker
is
exposed
to
it.
They
are
usually
reported
in
millimeters
of
mercury
(mm
Hg)
at
68OF
(ZOOC)
unless
otherwise
stated.
Substances
with
VPs
above
20mm
Hg
may
present
a
hazard
due
to
their
extreme
volatility.

VAPOR
DENSrrY
(AIR
=
1):
VD
is
the
weight
of
a
vapor
or
gas
compared
to
an
equal
volume
of
air.
Materials
with
a
VD
less
than
1.0
are
lighter
than
air.
Materials
with
a
VD
greater
than
1.0
are
heavier
than
air.
While
all
vapors
and
gases
will
mix
with
air
and
disperse,
large
quantities
of
unmixed
vapor
or
gas
in
locations
without
much
air
movement
such
as
storage
rooms
will
tend
to
rise
or
sink
depending
on
their
VD.
Flammable
vapors
that
are
heavier
than
air
can
spread
to
sources
of
ignition
and
flash
back
to
the
source.

SOLUBILIlY
IN
WATER:
This
term
represents
the
amount
by
weight
that
will
dissolve
in
water
at
ambient
temperature.
Solubility
Is
important
in
determining
suitable
clean
up
and
extinguishing
methods.
Solubility
is
usually
reported
in
grams
per
liter
(g/
l)
or
general
categories
such
as:

negligible
or
insoluble
=
<
0.1
percent
slight=
0.1
­
1.0
percent
moderate
=
1
­
10
percent
appreciable
=
>
10
percent
complete
=
soluble
in
all
proportions
APPEARANCE
AND
ODOR:
Comparing
this
description
to
the
actual
product
is
a
way
to
be
sure
the
right
MSDS
has
been
obtained.

SPECIFIC
GRAVITY
(SG):
The
SG
describes
the
heaviness
of
a
material
compared
to
a
reference
substance.
When
the
reference
substance
is
water
(Hz0
=
l),
it
indicates
whether
it
will
float
or
sink
in
water.
SG
for
solids
and
liquids
compared
to
water
numerically
equals
density
(see
above).
SG
for
gases
does
not
equal
density
because
the
density
of
air
is
not
1.0,
but
1.29.

MELTING
POINT:
This
is
only
applicable
to
solid
materials.
The
MP
is
the
temperature
at
which
a
solid
changes
to
a
liquid.

EVAPORATION
RATE:
This
is
the
rate
at
which
a
material
will
vaporize
(volatilize,
evaporate}
from
the
liquid
or
said
state
when
compared
to
another
material.
The
two
common
liquids
used
for
comparison
are
butyl
acetate
and
ethyl
ether.

WHEN
BUTYL
ACETATE
=
1.0
>
WHEN
ETHYL
ETHER
=
1.0
>3.0=
FAST
<
3.0
=
FAST
0.8
3.0
=
MEDIUM
3.0­
9.0
=
MEDIUM
~0.8
=
SLOW
>9.0
=
SLOW
SECTION
IV:
FIRE
AND
EXPLOSION
HAZARD
DATA
FLASH
POINT:
The
lowest
temperature
at
which
a
flammable
liquid
gives
of
sufficient
vapor
to
form
an
ignitable
mixture
with
air
near
its
surface
or
within
a
vessel.
Combustion
does
not
continue.
The
METHOD
USED
should
also
be
designated
here.
There
are
various
tests
for
determining
flash
point
and
these
should
also
be
designated
here
for
accuracy.
The
four
test
methods
recognized
by
the
National
Fire
Protection
Association
(NFPA)
are:
Tag
Open
Cup
test,
Tag
Closed
Cup
test,
Cleveland
Open
Cup,
and
Pensky­
Martens
closed
cup.

..
a,",
FLAMMABLE
LIMITS:
Only
applicable
to
flammable
liquids
and
gases,
these
are
the
minimum
and
maximum
concentrations
In
air
between
which
Ignition
can
occur.
Concentrations
below
the
lower
flammable
limit
(LFL
are
too
lean
to
burn,
while
concentrations
above
the
upper
flammable
limit
(UFL)
are
too
rich.
All
concentrations
in
between
can
burn
or
explode.
(Sometimes
called
lower
and
upper
explosion
limits,
LEL
and
UEL.)

EXfINGUISHING
MEDIA:
The
type
of
extinguisher
or
suppression
system
needed
to
put
out
a
fire
involving
the
substance.

SPECIAL
FIRE
FIGHTING
PROCEDURES:
Lists
any
special
methods
needed
to
fight
fires
involving
the
substance.
Peroxides
like
those
used
to
cure
polyester
resins,
for
example,
supply
oxygen
when
burned
and
cannot
be
extinguished
by
ordinary
methods
that
smother
or
cut
off
air.

UNUSUAL
FIRE
AND
EXPLOSION
HAZARD:
Unusual
hazards
such
as
those
of
some
organic
peroxides
that
ignite
spontaneously
under
certain
conditions
or
that
become
explosive
when
old.

SECTION
V:
REACTIVITY
DATA
This
section
must
be
completely
understood
before
doing
any
kind
of
experimenting
with
the
material.
Theater
craftspeople
also
should
be
aware
that
the
manufacturer
usually
has
no
liability
for
damages
cause
when
their
products
not
used
as
directed.

STABIlJTY
(Stable/
Unstable):
Stability
is
the
ability
of
the
material
to
remain
unchanged
under
reasonable
conditions
of
storage
and
use.

CONDIlIONS
TO
AVOID:
Conditions
which
will
render
a
material
more
unstable.
For
example,
storage
at
above
normal
temperatures
causes
some
materials
to
change
rapidly.

INCOMPATIBILITY:
Here
the
MSDS
should
list
substances
which
will
react
dangerously
with
the
product.
Workers
should
also
use
this
to
determine
which
substances
also
should
not
be
stored
in
proximity
to
the
product.
HAZARDOUS
DECOMPOSITION
PRODUCTS:
This
section
should
list
any
hazardous
chemicals
given
off
when
the
product
burns
or
when
it
degrades
or
decomposes
without
burning.
However,
manufacturers
often
only
report
the
results
of
high
temperature
incineration
with
all
the
oxygen
necessary
for
complete
combustion.
Under
these
conditions,
most
organic
chemicals
will
give
off
carbon
dioxide,
water,
and
a
few
other
low
molecular
weight
chemicals.
Actual
burning
in
open
air,
heating
with
torches,
hot
wire
cutting,
or
other
methods
of
rapid
decomposition
usually
will
produce
very
different
results.
Workers
should
be
aware
that
this
section
may
not
be
relevant
to
the
way
in
which
the
product
is
actually
burned
or
decomposed.

HAZARDOUS
POLYMERIZATION:
Polymerization
is
the
process
by
which
the
molecules
of
a
chemical
can
combine
to
form
larger
molecules.
Examples
include
the
setting
up
of
epoxy
or
polyester
resins.
Polymerization
is
hazardous
if
during
the
reaction
excessive
heat,
gases,
or
some
other
byproduct
is
given
off
in
amounts
sufficient
to
cause
fires,
burst
containers,
or
cause
some
other
kind
of
harm.

CONDITIONS
TO
AVOID:
Here
should
be
listed
conditions
such
as
high
temperatures
which
must
be
avoided
to
prevent
hazardous
polymerization
from
occurring.

SECTION
VI:
HEALTH
HAZARD
DATA
ROUTES
OF
ENTRY:
The
ways
chemicals
can
enter
the
body.

INHALATION:
The
most
common
route.
For
example,
vapors
or
dusts
can
be
inhaled
and
absorbed
by
the
body.

SKIN:
If
this
route
is
checked
the
material
can
be
absorbed
by
the
skin
in
significant
amounts.
Often
it
is
also
checked
if
it
only
damages
the
skin
itself.
Good
MSDS
clarify
whether
skin
damage
and/
or
absorption
can
occur.

INGESTION:
If
this
route
is
checked,
the
material
can
be
eaten,
drunk,
or
swallowed,
or
inhaled
particles
can
be
expelled
from
the
lungs
and
swallowed.

HEALTH
HAZARDS,
ACUTE
AND
CHRONIC:
This
section
usually
varies
greatly
in
quality.
Some
manufacturers
supply
detailed
data
on
both
chronic
and
acute
health
effects.
Others
provide
very
little.
Workers
should
not
consider
this
section
sufficient
and
should
supplement
it
from
additional
references.

ACUTE:
Information
about
short­
term
exposure
hazards
belong
here.
Many
MSDS
report
OSHA
and
ACGIH
shortterm
exposure
limits
(STELs)
and
Ceiling
limits
(CLs)
here.
The
OSHA
PEL/
mL
and
the
ACGIH
TLV/
STEL
usually
are
for
15­
minute
exposures,
while
the
Ceiling
limits
(PELC
and
TLVC)
are
instantaneous
limits
and
not
to
be
exceeded
at
any
time.

Other
data
commonly
found
here
are
LD50s
and
LC5Os.
The
LC50
is
the
concentration
in
the
air
that
will
kill
50
%
of
the
test
animals
when
administered
in
a
single
exposure
in
a
specific
time
period,
usually
1
hour.
LD50
it
the
single
dose
that
will
kill
50
%
of
the
test
animals
by
any
route
other
than
inhalation
such
as
by
ingestion
or
skin
contact.
These
tests
establish
the
degree
to
which
a
chemical
is
acutely
hazardous
and
determine
if
it
will
be
designated
"Nontoxic",
"Toxic"
or
"Highly
Toxic".

LABEL
DEFINITIONS
OF
TOXICITY
IN
THE
U.
S.
AND
CANADA:
ILD50
LC50
Nontoxic
>
5.0
g/
kg*
>20,000
ppm**
Toxic
0.055.0
g/
kg
200­
20,000
ppm
Highly
Toxic
<
O.
O5g/
kg
<
200
ppm
*grams
per
kilogram
of
body
weight
**
part
per
million:
part
of
substance
in
1
million
parts
of
air
As
defined
by
the
Federal
Hazardous
Substances
Act
(FHSA).
in
the
U.
S.,
and
the
Federal
Hazardous
Products
Act
in
Canada,
"nontoxic"
means
anything
the
passes
the
LD50
and
LC50
animal
tests.
Workers
need
to
know
that
long­
term
damage
such
as
cancer
and
birth
defects
are
not
detected
by
these
tests.
Since
these
tests
reflect
only
acute
hazards,
powdered
asbestos
can
legitimately
be
called
nontoxic
under
these
rules.
In
fact,
even
asbestos
is
nontoxic
because
it
won't
harm
any
animals
in
two
weeks
(the
duration
of
the
tests).

CHRONIC:
This
section
should
report
any
known
chronic
hazards
such
as
cancer,
reproductive
or
developmental
damage,
neurological
or
other
organ
damage
to
animals
or
humans
related
to
repeated
or
long
term
exposure.
Unfortunately,
a
great
number
of
the
chemicals
used
in
paints,
dyes,
and
other
theater
materials
have
never
been
studied
for
long­
term
hazards.
Failure
to
see
data
in
this
section
should
not
be
taken
to
mean
that
the
material
has
no
chronic
hazards.

CARCINOGENICTPI:
There
are
three
agencies
whose
opinions
regarding
carcinogenicity
must
be
reported
on
MSDS.
They
are
NTP
(the
National
Toxicology
Program),
IMC
(the
International
Agency
for
Research
on
Cancer),
and
OSHA.

The
cancer
ratings
assigned
by
each
agency
are
as
follows:
IARC
1.
Carcinogenic
to
humans:
sufficient
evidence
of
carcinogenicity.
2A.
Probably
carcinogenic
to
humans;
limited
human
evidence;
sufficient
evidence
in
experimental
animals.
2B.
Possibly
carcinogenic
to
humans;
limited
human
evidence
in
the
absence
of
sufficient
evidence
in
experimental
animals.
3.
Not
classifiable
as
to
carcinogenicity
to
humans.
4.
Probably
not
carcinogenic
to
humane.

NTP
1.
Known
to
be
carcinogenic,
with
evidence
from
human
studies.
2.
Reasonably
anticipated
to
be
a
carcinogen,
with
limited
evidence
in
humans
or
sufficient
evidence
in
experimental
animals.

OSHA
Carcinogens
are
defined
with
no
further
categorization.

SIGNS
AND
SYMPTOMS
OF
EXPOSURE:
These
are
usually
acute
or
sub­
acute
manifestations
of
the
chemical,
since
chronic
exposure
often
produces
no
clear
symptoms
for
years.
If
chronic
symptoms
are
given
they
usually
are
identified
as
such.

MEDICAL
CONDITIONS
AGGRAVATED
BY
EXPOSURE:
Here
the
MSDS
should
list
medical
conditions
which
are
known
or
suspected
to
be
exacerbated
by
the
chemical.
For
example,
chemicals,
which
are
respiratory
irritants,
may
aggravate
chronic
lung
conditions
such
as
asthma
or
emphysema.

EMERGENCY
AND
FIRST
AID
PROCEDURES:
Recommended
procedures
should
be
listed
here.

SECTION
VII:
PRECAUTIONS
FOR
SAFE
HANDLING
AND
USE
STEPS
TO
BE
TAKEN
IF
MATERIAL
IS
RELEASED
OR
SPILLED:
The
MSDS
should
list
preferred
methods
for
spill
control
(e.
g.
chemical
absorbents,
Fuller's
earth,
etc.)
and
protective
equipment
(respirators,
gloves,
emergency
ventilation,
etc.)
needed
to
keep
workers
safe
during
clean
up
of
large
spills
or
accidents.

WASTE
DISPOSAL
METHOD:
Unless
the
material
can
be
rendered
completely
innocuous,
the
MSDS
can
only
tell
users
to
dispose
of
the
material
In
accordance
with
local,
state,
and
federal
regulations.
Disposal
has
become
an
extraordinarily
complex
problem
and
cannot
be
addressed
in
a
few
lines
on
an
MSDS.
It
is
likely
that
substances
which
pose
severe
environmental
threats
or
whose
release
(spills)
must
be
reported
to
the
EPA
will
soon
have
to
be
identified
here.
Some
manufacturers
have
already
begun
including
this
information.

PRECAUTIONS
TO
BE
TAKEN
IN
HANDLING
AND
STORING:
Here
the
MSDS
should
list
safe
storage
conditions
(e.
g.
cool,
dry
area).
OTHER
PRECAUTIONS:
If
needed,
should
include
any
special
equipment
that
would
be
needed
or
which
is
required
to
be
in
a
storage
area
with
the
material.

SECTION
VIII:
CONTROL
MEASURES
This
section
should
provide
information
about
protective
equipment
needed
under
normal
use
of
the
product.
The
manufacturer
decides
what
constitutes
this
"Normal
use".
If
there
is
any
doubt
about
what
is
normal,
or
if
any
unusual
or
experimental
use
is
contemplated,
the
employer
should
contact
the
manufacturer
first
about
additional
protection.
Manufacturers
are
usually
not
liable
for
damages
if
their
products
are
used
other
than
directed.
For
this
reason,
questions
about
the
hazards
of
using
the
product
in
unusual
circumstances
should
be
answered
in
writing
by
the
manufacturer
or
an
industrial
hygienist.

RESPIRATORY
PROTECTION
(SPECIFIC
TYPE):
If
needed
during
normal
use,
a
good
MSDS
explains
precisely
what
type
of
respirator
is
proper.
Even
the
type
of
cartridge
type
for
air
purifying
respirators
should
be
specified.

VENTILATION:
If
needed
during
normal
use,
a
good
MSDS
specifies
the
type
of
ventilation
system
that
provides
proper
protection.
This
includes
recommendations
about
the
use
of
general
(mechanical)
ventilation,
local
exhaust
(which
captures
the
contaminants
at
their
source),
or
any
special
ventilation
system
which
might
be
needed.

EYE
PROTECTION:
If
needed,
goggles
or
face­
shields
should
be
listed
here.

OTHER
PROTECTIVE
CLOTHING
OR
EQUIPMENT:
Aprons,
boots,
gloves,
or
eye
wash
stations
should
be
listed
here
if
needed.

WORK/
HYGIENIC
PRACTICES:
Practices
such
as
proper
daily
clean
up
methods
and
equipment
after
normal
use
should
be
detailed
here.
~
~~

Respirator
Fit
Testing
Procedure
Fit
Testing
Procedures
Part
I.
OSHA­
Accepted
Fit
Test
Protocols
A.
Fit
Testing
Procedures­
General
Requirements
The
employer
shall
conduct
fit
testing
using
the
following
procedures.
The
requirements
in
this
appendix
apply
to
all
OSHA­
accepted
fit
test
methods,
both
QLFT
and
QNFT.

1)

2)

3)

4)

5)

6)

MI
7)

8)

9)
The
test
subject
shall
be
allowed
to
pick
the
most
acceptable
respirator
from
a
sufficient
number
of
respirator
models
and
sizes
so
that
the
respirator
is
acceptable
to,
and
correctly
fits,
the
user.
Prior
to
the
selection
process,
the
test
subject
shall
be
shown
how
to
put
on
a
respirator,
how
it
should
be
positioned
on
the
face,
how
to
set
strap
tension
and
how
to
determine
an
acceptable
fit.
A
mirror
shall
be
available
to
assist
the
subject
in
evaluating
the
fit
and
positioning
of
the
respirator.
This
instruction
may
not
constitute
the
subject's
formal
training
on
respirator
use,
because
it
is
only
a
review.
The
test
subject
shall
be
informed
that
he/
she
is
being
asked
to
select
the
respirator
that
provides
the
most
acceptable
fit.
Each
respirator
represents
a
different
size
and
shape,
and
if
fitted
and
used
properly,
will
provide
adequate
protection.
The
test
subject
shall
be
instructed
to
hold
each
chosen
face
piece
up
to
the
face
and
eliminate
those
that
obviously
do
not
give
an
acceptable
fit.
The
more
acceptable
face
pieces
are
noted
in
case
the
one
selected
proves
unacceptable;
the
most
comfortable
mask
is
donned
and
worn
at
least
five
minutes
to
assess
comfort.
Assistance
in
assessing
comfort
can
be
given
by
discussing
the
points
in
the
following
item
A.
6.
If
the
test
subject
is
not
familiar
with
using
a
particular
respirator,
the
test
subject
shall
be
directed
to
don
the
mask
several
times
and
to
adjust
the
straps
each
time
to
become
adept
at
setting
proper
tension
on
the
straps.
Assessment
of
comfort
shall
include
a
review
of
the
following
points
with
the
test
subject
and
allowing
the
test
subject
adequate
time
to
determine
the
comfort
of
the
respirator:
a)
Position
of
the
mask
on
the
nose
b)
Room
for
eye
protection
c)
Room
to
talk
d)
Position
of
mask
on
face
and
cheeks
The
following
criteria
shall
be
used
to
help
determine
the
adequacy
of
the
respirator
fit:
a)
Chin
properly
placed
b)
Adequate
strap
tension,
not
overly
tightened
c)
Fit
across
nose
bridge
d)
Respirator
of
proper
size
to
span
distance
from
nose
to
chin
e)
Tendency
of
respirator
to
slip
f)
Self­
observation
in
mirror
to
evaluate
fit
and
respirator
position.
The
test
subject
shall
conduct
a
user
seal
check,
either
the
negative
and
positive
pressure
seal
checks
described
in
Appendix
G3
of
this
section
or
those
recommended
by
the
respirator
manufacturer
which
provide
equivalent
protection.
hfore
conducting
the
negative
and
positive
pressure
checks,
the
subject
shall
be
told
to
seat
the
mask
on
the
face
by
moving
the
head
from
side­
to­
side
and
up
and
down
slowly
while
taking
in
a
few
slow
deep
breaths.
Another
face
piece
shall
be
selected
and
retested
if
the
test
subject
fails
the
user
seal
check
tests.
The
test
shall
not
be
conducted
if
there
is
any
hair
growth
between
the
skin
and
the
face
piece
sealing
surface,
such
as
stubble
beard
growth,
beard,
mustache
or
sideburns
which
cross
the
respirator
sealing
surface.
Any
type
of
apparel
which
interferes
with
a
satisfactory
fit
shall
be
altered
or
removed.

,/,/
SW
10)
If
a
test
subject
exhibits
difficulty
in
breathing
during
the
tests,
she
or
he
shall
be
referred
to
a
physician
or
other
licensed
health
care
professional,
as
appropriate,
to
determine
whether
the
test
subject
can
wear
a
respirator
while
performing
her
or
his
duties.
11)
If
the
employee
finds
the
fit
of
the
respirator
unacceptable,
the
test
subject
shall
be
given
the
opportunity
to
select
a
different
respirator
and
to
be
retested.
12)
Exercise
regimen.
Prior
to
the
commencement
of
the
fit
test,
the
test
subject
shall
be
given
a
description
of
the
fit
test
and
the
test
subject's
responsibilities
during
the
test
procedure.
The
description
of
the
process
shall
include
a
description
of
the
test
exercises
that
the
subject
will
be
performing.
The
respirator
to
be
tested
shall
be
worn
for
at
least
5
minutes
before
the
start
of
the
fit
test.
13)
The
fit
test
shall
be
performed
while
the
test
subject
is
wearing
any
applicable
safety
equipment
that
may
be
worn
during
actual
respirator
use
which
could
interfere
with
respirator
fit.
14)
Test
Exercises.
The
following
test
exercises
are
to
be
performed
for
all
fit
testing
methods
prescribed
in
this
appendix,
except
for
the
CNP
method.
A
separate
fit
testing
exercise
regimen
is
contained
in
the
CNP
protocol.
The
test
subject
shall
perform
exercises,
in
the
test
environment,
in
the
following
manner:
a)
Normal
breathing.
In
a
normal
standing
position,
without
talking,
the
subject
shall
breathe
normally.
b)
Deep
breathing.
In
a
normal
standing
position,
the
subject
shall
breathe
slowly
and
deeply,
taking
caution
so
as
not
to
hyperventilate.
c)
Turning
head
side
to
side.
Standing
in
place,
the
subject
shall
slowly
turn
his/
her
head
from
side
to
side
between
the
extreme
positions
on
each
side.
The
head
shall
be
held
at
each
extreme
momentarily
so
the
subject
can
inhale
at
each
side.
d)
Moving
head
up
and
down.
Standing
in
place,
the
subject
shall
slowly
move
his/
her
head
up
and
down.
The
subject
shall
be
instructed
to
inhale
in
the
up
position
(i.
e.,
when
looking
toward
the
ceiling).
e)
Talking.
The
subject
shall
talk
out
loud
slowly
and
loud
enough
so
as
to
be
heard
clearly
by
the
test
conductor.
The
subject
can
read
from
a
prepared
text
such
as
the
Rainbow
Passage,
count
backward
from
100,
or
recite
a
memorized
poem
or
song.

Rainbow
Passage
When
the
sunlight
strikes
raindrops
in
the
air,
they
act
like
a
prism
and
form
a
rainbow.
The
rainbow
is
a
division
of
white
light
into
many
beautiful
colors.
These
take
the
shape
of
a
long
round
arch,
with
its
path
high
above,
and
its
two
ends
apparently
beyond
the
horizon.
There
is,
according
to
legend,
a
boiling
pot
of
gold
at
one
end.
People
look,
but
no
one
ever
finds
it.
When
a
man
looks
for
something
beyond
reach,
his
friends
say
he
is
looking
for
the
pot
of
gold
at
the
end
of
the
rainbow.

f)
Grimace.
The
test
subject
shall
grimace
by
smiling
or
frowning.
(This
applies
only
to
QNFT
testing;
it
is
not
performed
for
QLFT)
g)
Bending
over.
The
test
subject
shall
bend
at
the
waist
as
if
he/
she
were
to
touch
his/
her
toes.
Jogging
in
place
shall
be
substituted
for
this
exercise
in
those
test
environments
such
as
shroud
type
QNFf
or
QLFf
units
that
do
not
permit
bending
over
at
the
waist.
h)
Normal
breathing.
Same
as
exercise
(1).
15)
Each
test
exercise
shall
be
performed
for
one
minute
except
for
the
grimace
exercise
which
shall
be
performed
for
15
seconds.
The
test
subject
shall
be
questioned
by
the
test
conductor
regarding
the
comfort
of
the
respirator
upon
completion
of
the
protocol.
If
it
has
become
unacceptable,
another
model
of
respirator
shall
be
tried.
The
respirator
shall
not
be
adjusted
once
the
fit
test
exercises
begin.
Any
adjustment
voids
the
test,
and
the
fit
test
must
be
repeated.

I75
Maintenance
and
Shutdown
Checklists
/fI
.­­_­.­
DAILY
SHUTDOWN
CHECKLIST
Unit
Number:
Date:

Operator:

Review
and
check
off
items
daily
to
place
equipment
in
a
shutdown
condition
at
the
end
of
day.

Q
Thoroughly
clean
the
complete
packer
assembly.

c3
Remove
the
mixing
stem
from
the
packer
(if
applicable)
and
clean.

D
Wash
off
the
quick­
disconnects
and
check
the
nipple
seals
for
cuts
or
debris.

D
Inspect
the
check
valves
for
leaking
chemical.
If
leaking
at
a
high
rate,
clean
or
disassemble
and
rebuild.

CI
Drain
the
air­
receiver
tank.

Q
Flush
out
and
clean
the
H­
block
assembly.

c1
Check
chemical
tanks
to
ensure
lids
are
closed
and
pinned,

Cl
Ensure
all
electrical
equipment
in
the
vehicle
is
turned
off.

Ll
Other
CI
Other
Q
Other
CI
Other
EXTENDED
SHUTDOWN
CHECKLIST
Unit
Number:
Date:

Operator:

0
Clear
the
quad­
hose
by
blowing
air
down
the
lines.

0
Drain
the
water
tank.

Cl
Drain
the
chemical
tanks.

II
Clear
the
air/
water
test
line
by
blowing
air
down
the
line.

Cl
Open
inline
filters
and
clean
thoroughly.

Q
Drain
air
receiver
tank.

0
Clean
packer
and
remove
the
packer
stem.

Cl
Remove
the
transducer
from
the
H­
block
assembly
and
clean
the
H­
block.

0
Perform
the
WASH
DOWN
AND
BLOW
DOWN
CHECKOFF
LIST.

Q
Other
#
Other
D
Other
Cl
Other
AVANTI
lNTERNATlONAL
WASH
DOWN
AND
BLOW
DOWN
CHECKLIST
Unit
Number:
Date:

Operator:

Wash
down
and
blow
down
procedures
are
accomplished
along
with
the
weekly
maintenance
routine
or
whenever
extended/
winter
shutdown
procedures
are
performed.
During
winter
shutdown,
wash
down
should
be
performed
first,
followed
by
a
blow
down
to
completely
dry
the
lines.

NOTE:
Be
sure
to
adhere
to
all
of
the
noted
safety
precautions
when
handling
quad­
hose
and
related
equipment.

Review
and
check
off
items
weekly
to
ensure
all
procedures
are
performed.

CI
1
Slightly
loosen
the
check
valve
on
the
blue
chemical
line.
Do
not
unscrew.

."
CC
WARNING:
Never
handle
quad­
hose
or
chemicals
without
wearing
a
minimum
of
rubber
gloves,
safety
goggles,
and
waterproof
shoes.
Follow
all
prescribed
safety
precautions.

The
quad­
hose
is
still
under
pressure.
Place
a
rag
over
the
check
valve
to
deflect
any
leaking
chemical
before
loosening
the
valve
any
further.

Cl
2
Slowly
untighten
the
check
valve
and
allow
the
pressure
to
bleed
off.
Remove
the
check
valve.

LI
3
Hang
the
quad­
hose
into
the
manhole.

CI
4
Remove
the
blue
chemical
line
from
the
discharge
side
of
the
grout
pump.

For
blow
down
(air):

CI
5
Attach
the
air
blow
down
fitting
to
the
grout
pump
end
of
the
chemical
line.

CI
6
Attach
the
high
pressure
air
line
from
the
compressor
to
the
air
blow
down
and
continue
to
supply
with
air
until
no
fluid
flows
from
the
line.

0
7
Disconnect
the
high
pressure
air
line
and
remove
the
fitting
from
the
quad­
hose
line.

WARNING:
Disconnect
the
blow
down
fitting
carefully,
back­
pressure
will
be
present.
For
wash
down
(water):

Q
8
Connect
the
water
wash
down
fitting
to
the
grout
pump
end
of
the
chemical
line.

Cl
9
Attach
a
garden
hose
to
the
end
of
the
wash
down
fitting
and
attach
the
other
end
of
the
hose
to
a
standard
external
spigot
or
the
spigot
in
the
vehicle
(if
available).

CI
10
Turn
on
the
water
until
liquid
flows
from
the
end
of
the
quad­
hose
line.
Allow
the
water
to
flow
for
five
(5)
minutes
or
until
clear.

Cl
11
Turn
off
the
water
and
disconnect
the
hose
and
fitting.

WARNING:
Disconnect
the
wash
down
fitting
carefully,
back­
pressure
will
be
present.

Repeat
for
the
red
chemical
line.

AVANTI
INTERNATlONAL
WEEKLY
MAINTENANCE
CHECKLIST
Unit
Number:
Date:

Operator:

Perform
the
following
preventive
maintenance
to
maximize
reliable
operation
of
the
equipment.
These
items
would
be
carried
out
after
the
daily
shutdown
has
been
accomplished.

tl
Remove
the
check
valves
and
quick­
disconnects
from
the
quad­
hose
ends.

0
Drain
and
flush
the
chemical
from
the
quad­
hose
(do
not
store
grout
in
the
quad­
hose
over
the
weekends).
If
using
a
water
base
grout,
the
quad­
hose,
chemical
tanks
and
pump
may
be
flushed
with
water
to
remove
the
chemical
from
the
system.

Cl
Check
the
inline
chemical
tank
filters
for
debris
and
clean.
Before
replacing
the
filters,
make
sure
the
filter
seals
are
clean,
undamaged
and
sealed
properly.

It
Visually
inspect
the
pump
assembly
and
check
the
oil
level
in
the
throat
seal
reservoir.
The
oil
level
should
be
two­
thirds
(213)
full.
If
chemical
is
visible
in
the
oil
or
the
oil
looks
milky,
tighten
the
throat
seal
bowl
clockwise
to
compress
the
seal
rings.
If
this
does
not
stop
the
contamination,
the
pump
may
need
rebuilding.

II
Check
the
packer
sleeves
for
cuts
or
tears.
Replace
if
necessary.

0
Check
for
frayed
cables.
Repair
or
replace
if
required.

Q
Ensure
all
equipment
is
clean
and
properly
stored.

CI
Perform
the
WASH
DOWN
AND
BLOW
DOWN
CHECKOFF
LIST.

0
Other
CL
Other
CI
Other
Test
Employee
Test
Name
Date
Company
1).
Who
is
directly
responsible
for
your
safety?
A.
Your
supervisor
B.
The
rig
operator
c.
You
D.
The
company
2).
Which
items
of
Personal
Protective
Equipment
(PPE)
should
be
worn
during
mixing
operations?
A.
Respirator
8.
Chemical
protective
suit
C.
Gloves
D.
All
of
the
above
3).
Where
do
you
find
the
most
complete
product
safety
information?
A.
Product
guide
B.
Material
Safety
Data
Sheets
(MSDS)
C.
Mixing
instructions
D.
Avanti
brochures
4)
When
mixing
powder
grouts,
the
main
safety
hazard
is
from
A.
Splashes
B.
Spills
C.
Inhaling
the
powder
D.
Skin
contact
5).
When
placing
the
packer
inside
the
sewer
line,
what
type
of
footwear
should
be
used?
A.
Tennis
shoes
B.
Leather
steel­
toed
boots
C.
Chemical­
resistant
steel­
toed
boots
D.
Cowboy
boots
6).
Where
should
smoking
be
allowed
during
grouting
operations?
A.
In
the
cab
of
the
truck
B.
In
the
camera
area
of
the
truck
C.
In
the
mixing
area
of
the
truck
D.
Nowhere
inside
the
truck
7).
How
often
should
work
clothes
be
washed?
A.
Weekly
B.
Daily
C.
Monthly
D.
Every
full
moon
8).
A
full
face
piece
respirator
and
approved
cartridge/
filter
can
be
used
when
the
exposure
to
a
compound
is
A.
Above
the
OSHA
PEL
B.
Below
the
OSHA
PEL
C.
Equal
to
the
OSHA
PEL
D.
The
PEL
doesn't
matter.

.
.
_
­­­­
9).
When
transporting
grouting
chemicals
in
the
grout
truck,
which
precautions
should
be
taken?
A.
Strap
securely
in
place
B.
Keep
in
original
containers
whenever
possible
C.
Keep
different
chemicals
apart
D.
All
of
the
above
10).
When
using
a
pump
to
transfer
liquids,
the
pump
parts
that
contact
the
grout
must
be
made
of
A.
Iron
B.
Any
metal
C.
Either
stainless
steel
or
plastic
D.
Titanium
11).
At
the
end
of
every
work
day
workers
should
A.
Shower
completely
and
wash
hair
thoroughly
B.
Wash
their
hands
before
going
home
C.
Shower,
wash
hair
thoroughly,
and
clean
their
PPE
(safety
equipment)
D.
Think
about
dinner
12).
PPE
should
be
inspected
and
cleaned
A.
Weekly
8.
Monthly
C.
Annually
D.
Daily
13).
When
mixing
AV­
100
products
using
the
standard
mix
instructions
with
72OF
water,
the
gel
time
should
be
approximately
A.
10
seconds
B.
2
minutes
C.
25
seconds
D.
25
minutes
14).
As
the
temperature
of
the
water
increases
by
10
degrees,
the
gel
time
A.
Decreases
by
one
half
6.
Increases
by
one
half
C.
Decreases
by
5
percent
D.
Temperature
does
not
effect
gel
time
15).
Which
additive
listed
below
is
used
to
increase
gel
times
(slow
down
gelation)?
A.
Latex
B.
Ethylene
Glycol
C.
KFe
(Potassium
Ferricyanide)
D.
AC­
50W­
A
Norosac
16).
As
a
minimum
requirement,
safety
glasses
should
be
worn
in
which
of
the
following
locations?
A.
Inside
the
grout
truck
8.
While
working
on
hose
reel
C.
When
cleaning
the
packer
D.
All
of
the
above.
17).
Routes
of
entry
for
AV­
100
products
are,
A.
Skin
6.
Eyes
C.
Inhalation
D.
All
of
the
above
18).
The
storage
area
for
chemical
grouts
and
their
additives
must
be
a
secure
area
capable
of
being
locked.
A.
True
B.
False
19).
Violent
chemical
reactions
are
possible
if
different
grout
compounds
are
mixed
together
due
to
spill
or
improper
storage.
A.
True
B.
False
20).
Empty
product
drums
may
be
used
for
other
purposes
if
properly
cleaned.
A.
True
B.
False
21).
Eyewash
stations
and
showers
should
be
available
in
or
near
the
storage
area.
A.
True
B.
False
22).
During
grouting
operations
field
personnel
can
wear
short­
sleeved
shirts.
A.
True
8.
False
23).
Once
leather
boots
have
become
contaminated
with
actylamide,
rinsing
them
off
with
water
removes
the
acrylamide.
A.
True
B.
False
24).
Sharing
PPE
with
your
coworkers
is
a
good
idea.
A.
True
B.
False
25).
Measuring
the
temperature
of
the
water
in
the
grout
tanks
is
a
good
way
to
determine
if
your
gel
times
have
decreased
substantially
during
the
day.
A.
True
B.
False
26).
Goggles
should
be
worn
instead
of
safety
glasses
when
there
is
a
higher
chance
of
being
splashed,
such
as
when
grouting
in
a
manhole
or
mixing
chemicals.
A.
True
B.
False
27).
The
effects
of
acute
exposure
are
immediate
A.
True
8.
False
28).
What
word
best
describes
exposure
to
AV­
lOO?
A.
Acute
8.
Chronic
29).
Respirator
cartridges
should
protect
against
vapors
as
well
as
particulate
matter.
A.
True
6.
False
30).
DuPont
TyChem
protective
suit
is
the
only
protective
clothing
recommended
for
mixing
AV­
100
products.
A.
True
B.
False
31).
What
property
of
AV­
100
AM
makes
it
difficult
to
be
aware
of
exposure.
A.
Odorless
B.
Powder
C.
Color
D.
All
of
the
above
32).
What
item
listed
below
in
not
covered
by
the
NFPA
placard?
A.
Health
B.
Flammability
C.
Fire
Hazard
D.
Specific
Gravity
r"

33
An
oxidizing
agent
causes
materials
that
do
not
normally
burn
to
burn
readily.
A.
True
B.
False
34).
When
added
to
the
grout
tank
AV­
257
Icoset,
A.
Inhibits
freezing
B.
Extends
Gel
time
C.
Increases
compressive
strength
D.
Inhibits
root
growth
35).
Adding
2lbs.
AV­
101
to
the
grout
tank
and
2lbs
of
AV­
102
to
the
Catalyst
tank
will,
A.
Increase
Gel
time
B.
Decrease
Gel
time
C.
Increase
the
viscosity
D.
None
of
the
above
36.
Add
the
correct
ingredients
to
each
Tank
for
a
conventional
grout
mix
using
AV­
100
or
AV­
118.

Tank
A
Tank
B
37.
Using
your
conventional
mix
above,
circle
the
correct
Tank
for
each
of
these
materials.

Tank
AV­
105
A
B
AV­
257
A
B
Kfe
A
B
Norosac
A
B
38).
If
a
cup
test
reveals
a
60
second
gel
time,
what
steps
are
needed
to
achieve
and
approximate
gel
time
of
25
seconds?

39).
What
is
the
weight
of
one
scoop
=
(W
40).
What
is
the
volume
of
one
pitcher=
(qt.)

BONUS
41)
What
factors
could
contribute
to
your
gel
time
increasing
even
though
your
temperature
and
mix
is
the
same?
Safe
Handling
and
Mixing
Program
Name
(Please
Print)
Date
Company
Signature
Test
Results
(Minimum
acceptable
score
80%)

Number
correct:

40
=
100%

39
=
98%

38
=
95%

37
=
93%

36
=
90%

35
=
88%

34
=
85%

33
=
83%

32
=
80%

rY7
.__"...­_
Employer
Certification
­
Storage
Facilities
Buyers
of
acrylamide
or
acrylic
grouting
products
from
Avanti
International
must
perform
an
on­
site
job
inspection
to
affirm
compliance
with
the
Safe
Operating
Practices
Program
on
an
annual
basis.
Each
storage
facility
and
each
operating
unit
must
be
inspected.
This
site
inspection
is
an
annual
requirement
of
the
program.

Operators,
helpers,
warehousemen,
and
shop
personnel
associated
with
grouting
operations
also
should
be
tested
annually
to
determine
their
knowledge
and
safety
awareness
of
acrylamide
and/
or
acrylic
grouts.

The
checklist
below
and
the
one
on
the
following
page
must
be
completed
and
returned
to
Avanti
International,
along
with
the
SOPP
Verification
form
in
Section
13,
before
orders
of
AV100
or
AV­
118
chemical
grouts
can
be
shipped.

Yes
N
o
Are
the
grouts
and
related
products
stored
in
bags
and
in
closed
fiber
drums?
Are
fiber
drums
being
re­
used
for
other
purposes?
Are
the
grouts,
AV­
101
Cat­
T+,
and
AV­
102
AP
stored
separately?
Is
safety
equipment
available
in
the
storage
areas?
Are
eyewashes
and
showers
readily
available?
Is
spill
clean­
up
equipment
available
in
the
storage
areas?
Are
all
storage
areas
locked?
Are
all
storage
areas
properly
ventilated?
Are
signs
posted
on
storage
areas
to
describe
the
contents?
Do
all
facilities
have
water
available
for
protection
and
flushing?

Facility
Address
Date
of
Inspection
Inspection
Performed
by
Title
Signature
of
Inspector
Describe
any
problems
noted
and
corrective
actions
taken
to
maintain
storage
areas
in
compliance
with
this
program.
Yes
Employer
Certification
­
Operating
Units/
Equipment
No
__
Is
equipment
in
good
condition
and
operating
as
designed?
__
Do
all
grout
tanks
have
covers?
­
Are
disposal
containers
for
waste
materials
on
each
unit?
­
Is
safety
equipment
for
worker
protection
on
each
unit?
Is
spill
clean­
up
equipment
available
on
each
unit?
r.
Is
water
available
for
worker
protection
and
flushing?
­
Are
all
chemicals
stored
in
tightly
closed
containers?
­
Is
ventilation
adequate
on
each
unit?
­
Is
the
power
vent
working
as
designed?
­
Is
there
an
eyewash
station
on
the
unit?
___
Are
grouts
and
additives
properly
stored
and
secured?
­
Are
MSDS
available
for
all
products
on
unit?
­
Is
there
a
cleaning
and
maintenance
schedule
for
each
unit?

Unit
Number
Date
of
Inspection
Inspection
Performed
by
Title
Signature
of
Inspector
License
Number
Describe
any
problems
noted
and
corrective
actions
taken.

I
._.."
­...­
.
.
.._.
11"
..­....,
l"
l^.­­
l..
Employee
Certification
I
I
I
I
(,
.d­..,

D
I
This
certifies
that
I
am
an
employee
of
and
I
have
received
technical
and
safety
handling
training
in
the
use
of
grout.

The
classroom
instruction
portion
of
this
program
was
completed
on
I
20
or
repeated
on
and
was
originally
prepared
by:

III
Present
Employer
a
Previous
Employer
Name
Address
I
20
City/
State
LI
Other
(Specify)

I
also
certify
that
I
have
read,
understood,
and
will
comply
with
all
of
the
sections
in
Avanti
International
Safe
Operating
Practices
Program.

Signed
Name
Home
Address
Date
Company
b
Avanti
International
AvantiGrout
News
Acrylamide
Provides
lasting
Help
for
United
States
Government
by
Brent
Keller,
M.
E.,
Industrial
Sales
Manager
Beginning
in
1985,
federal
and
state
regulatory
agencies
began
close
monitoring
of
the
waste
management
operations
at
the
United
States
Oak
Ridge
National
Laboratory
(ORNL),
as
well
as
other
Department
of
Energy
(DOE)
sites.
They
discovered
that
remote
monitoring
wells
at
ORNL
were
registering
levels
of
radioactivity
originating
from
radioactive
solid
wastes
that
had
been
deposited
in
numerous
burial
trenches
dating
back
to
1951,
including
the
active
days
of
the
Manhattan
Project.
They
concluded
that
these
agencies
of
the
United
States
government
did
not
have
adequate
solutions
for
long­
term
containment
or
abatement
of
toxic
pollution
to
the
environment.
Therefore,
a
comprehensive
study
was
undertaken
to
find
a
lasting
method
of
radioactive
waste
containment
and
environmental
remediation/
restoration.

Since
the
source
of
the
ground
and
surface
water
contamination
was
generally
known,
Oak
Ridge
engineers
immediately
began
testing
grouting
applications
and
soil
stabilization
methods
to
alter
the
localized
soil
and
reduce
permeability.
Several
different
grout
formulations
were
evaluated
for
their
ability
to
penetrate
and
reduce
hydraulic
conductivity
or
ground
water
transmission.
Lime­
fly
ash,
fly
ash­
cement­
bentonite,
and
bentonite
alone
were
unsuccessful
in
permeation
of
the
sample
columns
and
were
therefore
eliminated.
Sodium
silicate,
1,3
benzenediol,
and
polyacrylamide
acrylamide
grout
were
able
".
.
.
the
half­
life
for
the
undisrupted
to
successfully
penetrate
soil
and
sand
columns
and
reduce
hydraulic
conduc­
L­
1
Acryhmrde
grout
wus
determrnecf
to
tivities,
but
only
the
acrylamide
grout
was
able
to
reduce
the
mean
hydraulic
conductivities
from
104m/
s
to
<10­
8m/
s
(exact
reduction
was
unknown
because
performance
exceeded
capabilities
of
monitoring
equipment).
For
this
reason,
the
acrylamide
chemical
grout
was
selected
and
subjected
to
the
next
phase
of
testing.
Acrylamide
chemical
grout
had
passed
the
first
set
of
tests,
but
the
big
question
was
whether
it
could
perform
long­
term
in
the
field,
especially
in
such
a
contaminated
environment.
Two
of
the
smaller
trenches
were
chosen
for
field
testing
and
Continued
on
page
2
Avanti
International
Continued
from
page
1
Reference:
Farmer,
C.
D.,
L.
K.
Hyder,
S.
Y.
Lee,
and
injected
with
the
acrylamide
chemical
grout.
Based
on
B.
I'.
Spalding.
1986.
Demonstration
ofIn
Situ
Immobiliprevious
measurements,
it
was
concluded
that
"the
zationofBuried
Transuranic
WasteusingAcylamideGrout.

void
space
within
the
trenches
was
totally
filled
by
the
Martin
Marietta
Energy
Systems,
Inc.,
U.
S.
Dept.
of
grout
and
that
the
intratrench
hydraulic
conductivity
Energy,
under
contract
no.
DE­
AC05­
840R21400,

was
reduced
to
below
field­
measurable
values.
The
Publication
no.
RAP86­
69,
Environmental
Sciences
grout
was
also
completely
contained
within
the
two
Division
Oak
Ridge
National
Laboratory,
Oak
Ridge,

trenches
as
no
grout
constituents
were
observed
in
the
twelve
perimeter
groundwater
monitoring
wells."
These
results
proved
that
the
acrylamide
grout
had
properly
cured
and
stabilized
the
soil
even
in
the
presence
of
radioactive
waste.
The
stabilized
trenches
were
monitored
over
several
months
to
determine
the
degradation
rates
of
the
organic
acrylamide
grout.
These
rates
were
established
by
monitoring
the
rates
of
carbon
dioxide
evolution
from
amended
soils
as
microorganisms
metabolized
the
grout
as
a
carbon
and
energy
source.
Microbiological
half­
lives
were
estimated
from
this
rate
of
carbon
dioxide
evolution
and
from
samples
returned
to
the
lab
for
a
six­
month
observation
period.
Upon
the
completion
of
the
carbon
dating"
process,
the
half­
life
for
the
undisrupted
acrylamide
chemical
grout
was
determined
to
be
approximately
115
years.
Due
to
its
successful
field
demonstration
and
superior
performance
in
laboratory
degradation
studies,
the
acrylamide
chemical
grout
received
final
approval
for
use
in
immobilization
and
remediation
of
buried
radioactive
waste.
T
N
37831.
l
Full­
scale
grouting
of
the
buried
radioactive
waste
trenches
began
in
the
summer
of
1996
and
continued
to
the
end
of
that
year.
A
reduction
in
the
quantity
of
radioactive
waste
was
immediately
detected
at
adjacent
monitoring
wells,
and
a
hydrologic
monitoring
system
was
established
to
determine
the
overall
longterm
effectiveness
of
the
project.
Six
years
from
the
date
of
the
original
project,
acrylamide
chemical
grout
is
still
providing
insitu
isolation
of
buried
waste.
Calendar
of
Events
SME
February
25­
27
l
Phoenix,
AZ
Avanti
Booth
#1917
PCEE
February
28
­
Mar.
2
l
Nashville,
TN
Avanti
Booth
#906
ICRl
March
6­
8
l
Charleston,
SC
CIGMAT
March
15
l
Houston.
TX
APWA­
Florida
March
25­
28
l
Jacksonville,
FL
Avanti
Booth
#527
TEXAS
WATER
April
2­
5
l
San
Antonio,
TX
ASCE
August
4­
7
l
Cleveland,
OH
WEFTEC
September
28
­
Oct.
2
l
Chicago,
IL
At
the
onset
of
this
project,
the
DOE
required
lowlevel
waste
disposal
applications
to
have
performance
lifetimes
of
approximately
200
years
for
the
isolation
of
hazardous
radionuclides;
acrylamide
chemical
grouts
were
evaluated
using
these
government
standards
and
performed
within
the
parameters.
Avanti
International
makes
every
effort
to
enwre
the
accuracy
and
validity
of
all
editorial
and
advertising
content.
This
publication
is
independent
in
its
views
and
does
no+
support,
endorse
or
guarantee
any
data,
statements
or
opinions
which
appear
under
any
reference
or
ore
attributed
to
or
quoted
from
any
known
source.
The
views
expressed
by
@
2002
Avanti
International.
All
rights
reserved.

2
AvantiGrout
News/
Issue
1,
2002
Safe
Operating
Practices
Program
Version
2.1
0
2002
Avanti
International
822
Bay
Star
Blvd.
l
Webster,
TX
77598
l
(281)
486­
5600
l
www.
AvantiGrout.
com
..
I­­­(
,,­^.
.I__.­
.
..­..
..­
.­­
I
I
I
I
I
I
"d­
8.

II
Table
of
Contents
introduction
.
..________....___...­.­­­­­­­.­..­­­­­­­­­­....­­­­­­.­.­­.­­­­­­­..­­­­­.­.......­­­­­­.­­
­­
._______...__.______­...­­.­­­­­­­
1
Commitment
to
Safety
..________
_
.
.._______________________
_______
_
_________...

Personal
Protective
Equipment
Respiratory
Protection
Program
.._______.
_
_.__________.
_
_______._._.________.
_________._
­_­­
.________________.
1
Respirators
and
Cartridges
______________________.._
_
_____
­_­
_.__________..
_
_.____.___________________
_
.
.
.._______
1
Chemical
Protective
Clothing,
General
2
___________________...~~~..~~~~~.~..~.~~~~._.._________________~...
Chemical
Protective
Clothing,
Suits
2
_________________._..~~~~~~~...~~~.~~~.~~~~~~~~~~~~~~~.~~~~..~~~~~~..~~~.
Chemical
Protective
Clothing,
Gloves
_______
..___________
_
_________
­_
____.____
­­­
__________________......
3
Chemical
Protective
Clothing,
Boots
_____
_
________.__
_
____________________.­­­­­­­­­­­­­.
________________.
3
Chemical
Protective
Clothing,
Splash
Goggles
&
Safety
Glasses
._________________.
3
Use
and
Care
of
Personal
Protective
Equipment
._.._________..
_
_.________...._______________....
4
Recap:
PPE
as
a
Protective
System
_.___­________.__________
_
___________._______
_­
__.___._____________
­...
4
Housekeeping
Housekeeping
._._______
_
.________.__
_
________
___
_______
_
___________._________.._________.________
_
_._________________....­­­
5
AV­
100
Chemical
Grout
(AM
Powder)
Product
Descriptions
,_._________..._____­­­­­­­­­.­­..­.­­­­­­...­­­­­­­­­­..­­­­­­.­­
..________.
­.­
__._____________...
6
Storage
Requirements
________.________._.­­­­­­.­....­­­­......­­­­­­­...­­­­­.­.­­­­­­­­.­­
.____________
_
___.__..__
6
Disposal
of
Product
____._._._________._~~..~~..~~~~~~.~~..._______.._________
.._______.._._______­...­.­­­­.­­­.­­­­­
­7
Mixing
Instructions
,.__________________~~..~~~~~~...~.~..~~.~..~~~~~~~~~~
_
________.._____________
_
______________._
_
________
8
AV­
100
Chemical
Grout
[Powder
Blend)
Product
Descriptions
.___________________
_
___________.___._.___.._______._________
_­
________
­__­
__________.._.__________
11
Storage
Requirements
________.__________.______.._________.._._______
___________._______...­­­­­­­­­­.­­­..­.­
_
_____
11
Disposal
of
ProducL
________________________________________­...­­­­­.­­­....­..­
_
.________.._________~~~.
­..­
________
12
Mixing
Instructions
.____._.________
_
._________.
_
______._._______
__.__
_____
_._________.______..­­­­.­­­­­.­­­­­­­.­
____
____
13
AV­
100
Chemical
Grout
(Liquid)
Product
Descriptions
,______...__________..­.­­....­­.­­....­­­­­­­­.­.­­­..­­­­­..­­­­­..
.___________.
_
._.____________.
16
Storage
Requirements
16
____________________­­­­..­­­­­­­~....­­­­­­­­­­­­­­­~­­..­­­­­.­...­­­...­.­­­..­­­­­­­..­­­­­.
Disposal
of
Product
____________._______­.­.­­­­­­­.­­..­­­­­­­....­­­­­­
._________._______....­.­..­­­.­­...­.­­­­­­­­­.
17
Mixing
Instructions
____.._.._____.____________
_
_____
___.______.__.______­..­­­­­.­..­­­­­­­­­­­..­­­­­­­­.­.­­­
_________
18
AV­
118
Duriflex
Product
Descriptions
..________..______...
_
______._.________..
_
..__________________________
­_.­
________._...____________
21
Storage
Requirements
_____.._______.
_
____.___.________...________.
________.
_
______....__________...­­­­­­­­­­­..­...
21
Disposal
of
Product
________...
_
______._.________.._­­.­­...­­.­­­.__._.______.
_
.._____..__________....­­­­­.­­­­.­
__
._._.
22
Mixing
Instructions
______..._________...­..­..­..­­.­­..­..­­­­.­.­.­.­­.­..­.
_
______
.._____
.__.___________.__.
_
..______
23
Additives
Product
Descriptions
.
.._.________...____­­­...­­­­­­....­­......­­­­­
._________...____._____
__.._____.__.___...
______
26
Storage
Requirements
______....______......~~~.~..~.__.____.___.____..._~~~~~~~.~
.
.
..__________
­­
_____.____
________
26
Disposal
of
Product
_.______.____.______~.....___..._..___.___....~...~.....~~~~~.....
­___­
_________...__...___..­­­­­..­.
27
We
are
glad
you
have
chosen
to
work
with
Avanti
International
products
and
we
hope
you
find
this
guide
to
be
helpful
in
maintaining
a
safe
working
environment.

Avanti
International,
the
leading
supplier
of
chemical
grouts
in
the
United
States,
has
established
this
training
guide
for
the
safe
use
and
handling
of
its
acrylamide
and
acrylic
products.
This
Safe
Operating
Practices
Program
(SOPP)
has
been
developed
in
cooperation
with
our
suppliers
and
customers.
This
SOPP
is
a
tool
for
our
customers
to
protect
their
employees
and
the
environment
from
potential
hazards
associated
with
the
use
of
acrylamide
and
acrylic
chemical
grouts.

Despite
its
scope
and
breadth,
the
Avanti
International
SOPP
is
not
an
attempt
to
address
comprehensively
all
safety
considerations.
This
program
is
designed
to
be
the
minimum
standard
for
safety,
training,
and
the
use
of
personal
protective
equipment
for
the
grouting
industry
using
acrylamide
and
acrylic
chemical
grouts.
It
is
not
intended,
however,
to
cover
every
specific
situation,
problem,
or
eventuality.
Please
contact
Avanti
International
if
you
have
.questions.

This
SOPP
provides
guidance
only
and
does
not
alter
or
determine
legal
compliance
responsibilities,
which
are
set
forth
in
Occupational
Safety
and
Health
Administration
(OSHA)
standards
and
the
Occupational
Safety
and
Health
Act.
The
reader
must
refer
to
the
appropriate
standards
to
ensure
compliance.
Moreover,
because
interpretations
and
enforcement
policy
may
change
over
time,
for
additional
guidance
on
OSHA
compliance
requirements,
the
reader
should
consult
current
administrative
interpretations
and
decisions
by
the
Occupational
Safety
and
Health
Review
Commission
and
the
courts.
The
Environmental
Protection
Agency
(EPA)
has
expressed
an
interest
in
the
safe
use
and
handling
of
chemical
grouts,
and
recommendations
it
has
made
concerning
specific
items
of
personal
`protective
equipment
and
other
safety­
enhancing
measures
have
been
incorporated
into
the
SOPP.

This
SOPP
is
the
product
of
many
years
of
experience
with
chemical
grouts
and
many
hours
of
hard
work
by
Avanti
International
personnel.
We
are
pleased
to
share
it
with
our
customers
and
their
employees,
for
whom
it
was
developed.
Neither
Avanti
International,
its
employees,
or
consultants,
however,
makes
any
express
or
implied
warranty
about
the
completeness
or
accuracy
of
the
information
in
the
SOPP,
nor
assumes
any
liability
or
responsibility
for
any
use,
or
the
results
of
such
use,
of
this
information.
Also,
while
Avanti
International
will
endeavor
to
advise
its
customers
of
any
significant
changes
in
the
content
of
the
SOPP,
please
be
aware
that
the
information
is
subject
to
change
without
notice.

I
au7
Avanti
International
hereby
grants
a
nonexclusive,
royalty­
free
license
to
the
purchasers
of
its
products
to
retain
a
copy
of
the
SOPP
for
reference
and
training
purposes
and
to
reproduce
and
distribute
it
for
employee
use,
subject
to
the
following
conditions
and
limitations:

The
SOPP
is
the
copyrighted
material
of
Avanti
International.

Copies
of
the
SOPP
are
not
intended
for
sale
or
for
use
by
parties
other
than
the
purchasers
of
Avanti
International's
products
and
their
employees,
except
for
such
other
uses
as
Avanti
International
may
authorize
in
writing.

The
SOPP
may
not
be
altered,
abridged,
revised,
translated,
or
otherwise
modified
without
Avanti
International's
written
consent.
In
the
event
that
such
consent
is
given,
Avanti
International
assumes
no
responsibility
for
the
completeness,
or
overall
quality
of
any
alteration,
abridgment,
revision,
translation,
or
other
modification
of
this
SOPP.

Buyers
of
Avanti
International
acrylamide
and
acrylic
grouting
products
must
perform
an
annual
inspection
to
affirm
compliance
with
the
SOPP.
Copies
of
the
completed
employer
certification
and
SOPP
verification
forms
(in
Sections
12
and
13)
are
to
be
returned
to
Avanti
International.
Copies
of
completed
employee
certification
forms
(in
Section
11)
also
are
to
be
provided
to
Avanti
International
following
employee
training
in
the
handling
and
use
of
the
appropriate
grouting
materials,
including
review
of
the
SOPP
and
acceptable
performance
on
the
employee
test
(in
Section
10).
Each
customer
must
submit
renewals
annually
for
all
employees
involved
in
grouting
operations.
Employees
transferring
from
one
division
of
a
company
to
another
and/
or
new
employees
should
complete
the
SOPP
training
within
the
first
30
days
of
transfer
or
employment.

Thank
you
for
your
cooperation
in
maintaining
a
safe
working
environment
for
your
employees
and
for
using
Avanti
International's
acrylamide
and
acrylic
chemical
grouts
in
a
responsible
manner.
We
would
be
pleased
to
answer
any
questions
you
may
have.

Sincerely,
AVANTI
INTERNATIONAL
F.
David
Magill,
Jr.,
P.
E.
President
Personal
Protective
Equipment
The
proper
use
of
personal
protective
equipment,
commonly
called
PPE,
requires
that
employees
recognize
the
need
for
its
use.
If
employees
do
not
understand
the
reason
for
wearing
each
piece
of
equipment,
they
may
be
risking
unnecessary
exposure.
Employees
must
also
understand
the
relationship
of
how
all
of
the
PPE
works
together
to
protect
them.
Employees
must
wear
all
of
the
recommended
PPE
for
a
given
operation
to
be
properly
protected.
If,
for
example,
an
employee
is
engaged
in
an
operation
that
requires
a
chemical
suit,
respirator,
gloves,
and
boots,
and
is
not
wearing
approved
boots
but
street
shoes
and
a
chemical
spill
occurs,
the
employee
could
be
exposed
unnecessarily.
It
is
especially
important
to
train
employees
to
think
of
their
PPE
as
a
system
and
not
individual
pieces
of
equipment.
This
complete
system
approach
is
required
so
that
all
needed
equipment
is
always
worn
during
specific
operations,
such
as
mixing.

The
two
most
common
routes
of
exposure
to
chemicals
are
inhalation
hazards
(the
breathing
of
vapors
or
aerosols)
and
skin
contact.

In
order
to
protect
employees
from
inhalation
hazards,
a
respirator
must
be
worn
during
operations
that
might
expose
the
employee
to
these
hazards.
Avanti
International
highly
recommends
the
use
of
a
full
facepiece
respirator,
which
provides
increased
respiratory
protection
and
also
protects
the
face
and
eyes.

OSHA's
Respiratory
Standard
and
Respiratory
Protection
Program
When
an
employer
requires
the
use
of
a
respirator
during
specific
operations,
the
provisions
of
OSHA's
respiratory
protection
standard
must
be
met.
The
respiratory
protection
standard
requires
employee
medical
evaluations,
fit
testing,
and
respirator
training;
the
specific
requirements
can
be
found
at
http://
www.
osha.
goviTraining/
major­
req­
RPS­
191
O­
l
34.
pdf.
In
addition
to
meeting
the
terms
of
the
standard,
OSHA
requires
that
your
company
(I)
Develop
a
written
respiratory
program
with
procedures
that
are
specific
to
your
worksite;
(2)
Implement
the
program
and
update
it
as
necessary;
and
3)
Assign
a
qualified
program
administrator
to
run
and
evaluate
the
program.
The
applicable
regulations
are
at
http://
www.
osha.
gov/
SLTC/
respiratory­
advisor/
oshafiles/
wri~
enprograml
.
html.
For
assistance,
you
can
download
a
copy
of
OSHA's
Small
Entity
Compliance
Guide
at
http://
www.
oshasic
qov/
oshdoc/
additional.
html#
seoc­
rps.
The
Small
Entity
Compliance
Guide
includes
a
sample
written
respiratory
protection
program.

Respirators
and
Cartridges
Respirators
and
their
associated
cartridges
are
designed
to
protect
the
lungs.
Avanti
International
recommends
the
use
of
chemical
respirators
as
a
part
of
the
personal
protective
equipment
package
during
specific
operations.
The
specific
operations
where
chemical
respirators
must
be
worn
include
transferring
and
mixing
chemical
grouts
in
the
mixing
tanks;
and
cleaning
the
tanks,
lines
or
packers.
Manhole
grouting
with
acrylamide
also
requires
the
use
of
chemical
respirators.

Full
facepiece
respirators
offer
protection
of
the
face,
eyes
and
lungs
and
are
highly
recommended.
The
3M
brand
6800
Full
Facepiece
Respirator
used
with
the
appropriate
cartridge
filter,
or
a
comparable
product,
is
designed
to
provide
effective
protection
when
exposure
levels
of
acrylamide
are
below
the
OSHA
PEL
of
0.3
mg/
m3,
and
concentrations
of
formaldehyde
are
below
the
OSHA
PEL
of
0.75mg/
m3.

­­
p..­
The
3M
brand
60921
Organic
Vapor
Cartridge/
P100
Filter,
or
a
comparable
product,
is
designed
to
be
effective
for
use
with
AV­
100
liquids
and
powders
when
concentrations
of
acrylamide
are
below
the
OSHA
PEL
of
0.3mg/
m3.

The
3M
brand
60925
Formaldehyde/
Organic
Vapor
Cartridge/
PI
00
Filter,
or
a
comparable
product,
is
designed
to
be
effective
for
use
with
AV­
118,
when
concentrations
of
formaldehyde
are
below
the
OSHA
PEL
of
0.75mg/
m3
and
concentrations
of
acrylamide
are
below
the
OSHA
PEL
of
0.3mg/
m3.

If
a
cartridge/
filter
becomes
damaged
or
soiled,
or
if
breathing
becomes
difficult,
the
employee
should
leave
the
area
and
replace
the
cartridge/
filter.
If
used
in
an
environment
containing
oil
aerosols,
replace
the
cartridge/
filter
after
40
hours
of
use
or
30
days,
whichever
comes
first.
Employees
should
not
share
respirators
and
should
keep
their
respirator
in
a
sealed
bag
in
a
secure
location.

Chemical
Protective
Clothing,
General
(CPC)
As
noted
above,
the
various
PPE
recommendations
and
requirements
should
be
addressed
as
a
single
unit.
A
unit
approach
to
PPE
requires
that
all
PPE
recommended
for
a
specific
operation
always
be
worn
during
that
operation.
It
is
imperative
that
employees
understand
that
PPE
is
not
just
a
pair
of
goggles
and
gloves,
but
includes
suits
and
boots,
as
well
as
eye
protection,
gloves
and
respirators.

Chemical
Protective
Clothing,
Suits
­.
Chemical
suits
are
designed
as
body
protection.
Even
though
physical
contact
with
acrylamide
powder
or
liquid
is
unlikely,
chemical
suits
are
an
essential
part
of
an
employee's
personal
protective
equipment
package
during
specific
operations.
EPA
has
advised
that
the
DuPont
brand
TychemB
model
(SL)
protection
suit
provides
excellent
protection
against
potential
acrylamide
exposure
hazards.
The
Tychem@
SL
suit
is
a
lightweight,
comfortable
garment
specifically
designed
for
easy
wear.
It
has
been
tested
with
acrylamide
and
shows
an
average
normalized
breakthrough
time
in
minutes
to
be
greater
than
480.
If
other
products
offer
protection
comparable
to
that
of
TychemB
SL
in
standardized
laboratory
testing
with
acrylamide,
these
products
would
be
considered
effective
as
well.
The
specific
operations
where
TychemB
SL
or
comparable
chemical
suits
must
be
worn
include:
transferring
and
mixing
chemical
grouts
into
the
mixing
tanks;
cleaning
the
tanks,
lines
or
packers.
The
use
of
such
suits
is
also
necessary
during
all
in­
manhole
operations
that
involve
grouting
with
acrylamide.

TychemB­
type
suits
are
considered
limited­
use
disposable
garments.
DuPont
describes
the
use
characteristics
of
these
garments
as
follows:
"The
exact
number
of
wearings
cannot
be
stated
without
knowledge
of
the
specific
end
use.
However,
up
to
5
wearings,
under
controlled
conditions
through
a
structured
garment
inspection
program,
are
not
uncommon
in
light­
tomoderate
non­
hazardous
activities."
Once
a
garment
is
contaminated
or
damaged,
it
should
be
properly
disposed
of
immediately.

For
any
other
operation
in
the
truck
in
which
TychemB
or
comparable
suits
are
not
required,
the
employee
must
be
wearing
a
long­
sleeved
shirt,
full­
length
pants
and
approved
footwear
as
a
minimum
requirement.
Chemical
Protective
Clothing,
Gloves
Chemical
gloves
are
designed
as
protection
of
the
hand,
wrist
and
forearm,
and
must
be
used
for
any
operation
where
chemical
grout
is
present.
These
operations
include
transferring
and
mixing
grouts,
handling
the
packer,
and
all
cleaning
and
testing
operations.
A
suitable
glove
will
exhibit
good
resistance
to
acrylamide,
and
is
also
important
to
specify
the
proper
thickness
(gauge).
When
choosing
a
glove
it
is
important
to
specify
the
proper
thickness
(gauge).
At
this
time,
only
the
15
mil
(0.38
millimeter)
Best
brand
Nitri­
Solve@
Model
727
has
been
tested
and
reported
effective
for
exposure
to
acrylamide.
If
other
products
offer
protection
comparable
to
that
of
the
Best
Nitri­
Solve@
Model
727
gloves
in
standardized
laboratory
testing
with
acrylamide,
these
products
would
be
considered
effective
as
well.

Gloves
should
cover
the
wrist
and
forearm
and
fit
well
enough
so
the
employee
has
freedom
of
movement.
Gloves
may
be
reused
if
functioning
properly
and
previous
chemical
exposure
was
light.
Because
the
use
of
gloves
and
the
extent
of
their
exposure
is
unknown
it
would
be
prudent
to
limit
their
usage
to
5
days
or
less.
Gloves
that
are
heavily
contaminated
should
be
changed
on
a
more
frequent
basis.
Gloves
that
are
torn
or
abraded
should
be
changed
immediately,
and
disposed
of
properly.

Chemical
Protective
Clothing,
Boots
Chemical
boots
are
designed
to
protect
the
foot,
ankle
and
lower
leg,
and
must
be
used
for
any
operation
where
chemical
grout
is
present.
These
operations
include
transferring
and
mixing
grouts,
handling
the
packer,
cleaning
and
testing
operations,
and
all
in­
sewer
activities.
Boots
must
exhibit
good
resistance
to
be
effective.
Boots
should
be
cleaned
on
a
daily
basis
if
they
have
come
into
contact
with
chemical
grout.
Boots
that
are
torn
or
are
heavily
worn
should
be
replaced
immediately.

Leather
footwear
is
prohibited
if
it
can
possibly
come
into
contact
with
chemical
grouts.
Leather
absorbs
spills,
creating
a
pathway
for
exposure
and
irritation
of
the
feet
and
ankles.
Once
leather
has
become
wet
and
contaminated,
the
leather
remains
contaminated
even
after
drying.

Chemical
Protective
Clothing,
Splash
Goggles
and
Safety
Glasses
Chemical
goggles
and
safety
glasses
are
designed
as
protection
for
the
eyes.
Unvented
chemical
splash
goggles
must
be
worn
for
any
operation
where
chemical
grout
is
present
if
a
full
facepiece
respirator
is
not
being
worn.
Splash
goggles
provide
superior
eye
protection
as
compared
to
safety
glasses.
Avanti
International
recommends
such
splash
goggles
as
Uvex
futuraTM
brand
(model
9301)
or
comparable
goggles
that
are
specifically
designed
for
splash
protection.

Damaged
or
severely
scratched
goggles
must
be
discarded
immediately.
Splash
goggles
should
be
cleaned
on
a
daily
basis.

Safety
glasses
may
be
worn
for
operations
other
than
those
listed
above.
Safety
glasses
that
fully
protect
the
eye
should
be
chosen.
Offering
the
employee
a
variety
of
safety
glasses
that
are
comfortable
for
the
wearer
will
support
their
proper
and
consistent
use.
Use
and
Care
of
Personal
Protective
Equipment
Properly
maintaining
and
using
personal
protective
equipment
is
an
important
step
in
the
safe
handling
of
chemical
grouts.
General
guidelines
for
PPE
use
and
care
are
as
follows:

l
Inspect
all
PPE
before
each
use.

l
NEVER
use
damaged
or
contaminated
items.

l
Wear,
store
and
clean
PPE
according
to
manufacturers'
guidelines.

l
PPE
fit
is
extremely
important.
If
PPE
does
not
fit
well,
employees
tend
not
to
use
it,
which
defeats
its
basic
purpose.

The
best
equipment
in
the
world
will
not
protect
an
employee
unless
it
is
used
correctly
and
consistently.

Supervisors
should
recognize
the
signs
that
an
employee
is
not
properly
using
the
provided
PPE
or
is
not
following
good
safety
procedures.
No
employee
should
be
permitted
to
work
independently
with
any
of
the
chemical
grouts
until
thoroughly
and
properly
trained.
The
employee
must
be
able
to
follow
the
procedures
and
required
precautions.

Employees
MUST
do
their
part
to
support
the
effective
use
of
PPE,
as
follows:
e
Wear
clean
clothes
each
workday
and
wash
before
re­
use.

l
Shower
and
wash
hair
at
end
of
each
workday.

l
Wash
hands
and
face
before
eating,
drinking
or
smoking.

l
Keep
food
out
of
the
work
area.

l
Maintain
a
clutter­
free
workspace.

l
Consult
your
supervisor
if
you
do
not
understand
how
to
use
or
maintain
PPE
correctly.

Additional
Equipment
A
dual
32­
oz.,
wall­
mounted
eyewash
station
should
be
accessible
to
employees
and
maintained
in
good
working
order.

Recap:
PPE
as
a
Protective
System
Respirators,
chemical
protective
suits,
gloves,
boots
and
goggles
are
all
part
of
an
integrated
system
to
assure
that
operations
with
chemical
grouts
are
undertaken
and
completed
safely.
It
is
essential
that
all
elements
of
the
employees'
PPE
system
are
clean,
functioning
properly
and
property
fitted.
The
employee
is
responsible
for
determining
the
status
of
each
piece
of
his
personal
protective
equipment.
All
PPE
should
be
inspected
before
wearing
it
in
an
area
or
situation
that
may
expose
the
wearer
to
hazardous
chemicals:
If
any
one
piece
of
equipment
is
in
unsatisfactory
condition,
the
employee
should
not
begin
operations
until
the
condition
is
corrected.
PPE
should
be
cleaned
and
inspected
at
the
end
of
each
shift
and
properly
stored
for
future
use.
PPE
by
definition
is
an
employee's
last
line
of
defense
and
should
be
treated
accordingly.

Avanti
International
has
listed
specific
brands
of
PPE,
including
chemical
protective
clothing,
as
a
convenience.
It
is
the
responsibility
of
each
user
of
Avanti
grouting
products
to
determine
the
type
and
brand
of
equipment
that
is
appropriate
for
their
specific
work
environment.
To
promote
employee
safety,
however,
the
equipment
selected
should
provide
protection
at
least
equivalent
to
what
the
examples
cited
above
would
provide.
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Housekeeping
Good
housekeeping
in
the
work
area
is
as
important
as
the
safe
handling
of
chemical
grouts.
TV/
Grout
rigs
have
very
small
work
areas
and
should
be
organized
to
allow
employees
the
greatest
freedom
of
movement
and
the
ability
to
perform
their
jobs
in
a
safe
manner.
Time
allotted
to
the
maintenance
of
the
interior
of
the
truck
is
as
valuable
as
changing
the
oil
or
inspecting
the
tires.

Employees
should
become
familiar
with
the
checklist
provided
below
and
follow
it
as
a
minimum
daily
requirement
for
their
housekeeping
duties.
The
list
is
not
meant
to
be
exhaustive;
any
site­
specific
or
operation­
specific
requirements
should
be
added
by
the
employer
as
needed.
Along
with
the
proper
storage
location
for
chemicals
being
transported,
the
employees
should
have
designated
locations
for
the
disposal
of
empty
containers
and
bags.
Grouting
equipment
should
be
washed
with
clean
water
to
limit
accidental
exposure
from
the
handling
of
packers,
scoops,
mixing
paddles,
pitchers,
cameras,
and
the
hose
reel.

Good
housekeeping
in
the
cab
area
of
the
truck
is
also
important.
Employees
should
refrain
from
storing
food
and
beverages
in
the
open
cab
areas
of
the
TV/
Grout
rig.
Do
not
eat
or
drink
anywhere
in
the
TV/
Grout
rig.
Smoking
should
never
be
permitted
in
a
TV/
Grout
rig.

Daily
Housekeeping
Checklist
Clean
work
area
often
and
maintain
it
in
good
condition.
Make
sure
water
tank
is
full.
This
is
important
not
only
for
making
more
grout,
but
it
can
be
used
for
clean
up
and
also
can
be
used
in
case
of
an
emergency.
Mop
the
floors,
wash
down
outside
of
grout
tanks,
and
wash
hose
reel
and
packers
with
fresh
water,
making
sure
that
excess
water
is
directed
into
a
sanitary
sewer.
Wash
tools
used
to
work
on
pumps,
packers
and
hoses
with
fresh
water,
making
sure
that
excess
water
is
directed
into
a
sanitary
sewer.
Immediately
wash
down
any
spills,
that
cannot
be
collected
or
gelled.
Secure
door
to
control
room
during
the
mixing
process.
When
transporting
the
Triethanolamine
(Cat
T),
it
must
always
be
kept
away
from
either
Ammonium
Persulfate
(AP)
or
Sodium
Persulfate
(SP).
Seal
all
chemical
containers
immediately
after
use.
Secure
all
chemical
containers
so
as
not
to
shift
during
transit.
Always
store
chemicals
in
original
containers.
Remove
empty
containers
from
the
TV/
Grout
rig
and
d&
pose
of
properly.
Operator
should
clean
steering
wheel
to
prevent
cross
contamination.
Assistant
should
inspect
grouting
system
for
leaks
while
in
use
and
repair
as
necessary.
Chemical
protective
clothing
(CPC)
should
be
cleaned
thoroughly
at
the
end
of
each
shift.
CPC
should
be
stored
in
clean
plastic
bags
away
from
the
chemicals.
CPC
should
be
stored
outside
of
the
control
room.
CPC
should
be
thoroughly
inspected
before
being
used.

5
213
AV­
IOO
Chemical
Grout
(AM
Powder)

Product
Descriptions
AV­
100
AM
Acrylamide
Monomer
is
the
trade
name
for
an
acrylamide
grout
used
for
sewer
line
joint
sealing,
sewer
line
lateral
sealing,
manhole
sealing,
and
soil
stabilization.
AV­
100
AM
is
a
white
crystalline
acrylamide
powder
(CAS
number
79­
06­
I)
that
dissolves
completely
and
rapidly
in
water.
Mixed
in
with
the
acrylamide
is
a
small
amount
of
copper
sulfate
(blue
crystals)
that
stabilizes
the
product.
AV­
100
AM
is
sold
in
fiber
drums
containing
four
(4)
55
pound
bags.
The
two­
layer
bags
are
designed
for
the
operator
to
lower
the
inner
bag
into
the
grout
tank
during
the
product
transfer.

AV­
100
MBA
Methylenebisacrylamide
is
the
trade
name
for
Methylenebisacrylamide
(CAS
number
110­
26­
g).
AV­
100
MBA
is
a
bluish
white
liquid
that
is
a
cross­
linker
of
acrylamide.
The
AV­
100
MBA
must
be
added
to
AV­
100
AM.
The
AV­
100
MBA
liquid
is
packaged
in
64­
ounce
containers
in
an
emulsion
form
for
easier
mixing.

AV­
101
Catalyst
T+
is
the
trade
name
for
a
blend
of
Triethanolamine
(CAS
number
102­
71­
6)
and
proprietary
additives.
AV­
101
is
a
thick
colorless
liquid
that
is
used
as
an
activator.
The
proprietary
additives
decrease
the
freezing
point,
which
allows
storage
and
transportation
in
temperatures
at
or
below
freezing.
AV­
101
is
packaged
in
both
5gallon
plastic
drums
and
55­
gallon
lined
metal
drums.

AV­
102
Catalyst
AP
is
the
trade
name
for
Ammonium
Persulfate
(CAS
number
7727­
54­
O).
AV­
102
is
a
white
powder
that
is
used
as
a
polymerization
initiator.
It
is
packaged
in
50­
pound
plastic
pails
or
225
pound
coated
fiber
drums
with
a
plastic
inner
liner.

Storage
Requirements
AV­
100
AM:
Store
in
a
cool
dry
area
away
from
heat.
Provide
good
ventilation.
Keep
bags
inside
drums.
Keep
container
tightly
closed
and
in
an
upright
position.
Take
measures
not
to
raise
dust.
Wear
proper
PPE
when
handling
this
product.
Store
away
from
AV­
101
Catalyst
T+
and
AV­
102
Catalyst
AP.

AV­
100
MBA:
Store
in
a
cool
dry
area
away
from
heat.
Provide
good
ventilation.
Keep
containers
tightly
closed
and
in
an
upright
position.
Do
not
use
pressure
to
empty
containers.
Wear
proper
PPE
when
handling
this
product.
Store
away
from
AV­
101
Catalyst
T+
and
AV102
Catalyst
AP
and
AV­
103
Catalyst
SP.

AV­
101
Catalyst
T+:
Store
in
a
cool
dry
area
away
from
heat.
Provide
good
ventilation.
Keep
containers
tightly
closed
and
in
an
upright
position.
Do
not
use
pressure
to
empty
containers.
Store
away
from
acids
or
oxides
as
violent
reactions
may
occur
if
product
comes
in
contact
with
these
materials.
Do
not
store
near
AV­
100
Chemical
Grouts
or
AV­
102
Catalyst
AP.

AV­
102
Catalyst
AP:
Store
in
a
cool
dry
area
away
from
heat.
Provide
good
ventilation.
Keep
container
tightly
closed
and
in
an
upright
position.
Take
measures
not
to
raise
dust.
Wear
proper
PPE
when
handling
product.
Store
away
from
acids,
alkalis,
halides,
reducing
agents,
combustible
materials
and
heavy
metals
as
violent
reactions
may
occur
if
product
comes
in
contact
with
these
materials.
Do
not
store
near
AV­
100
Chemical
Grouts
or
AV­
101
Catalyst
T+.
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General:
Maintain
first
aid
kit,
gloves,
respirators,
aprons,
and
cleanup
equipment
in
the
storage
area
at
all
times.
An
emergency
spill
response
kit
should
also
be
readily
available.
Foam,
carbon
dioxide,
or
dry
chemical
fire
extinguishers
should
be
easily
accessible.
Provide
eyewash,
shower,
and
a
source
of
water
in
the
storage
area.
Keep
materials
in
original
packaging
whenever
possible.

Disposal
of
Product
AV­
100
AM:
Powder
product
must
be
gelled
or
properly
contained
and
incinerated.
The
best
method
for
disposal
is
to
gel
the
material,`
as
follows.
Collect
as
much
dry
AV­
100
as
possible,
taking
all
precautions
to
avoid
creating
dust
while
collecting
the
product.
Add
AV­
101
Cat
T+,
and
gel
with
water
and
AV­
102
Catalyst
AP,
in
this
order.
Gelled
(catalyzed)
materials
pose
little
risk
and
may
be
sent
to
a
landfill.
Very
small
spills
may
be
washed
down
with
water,
with
the
water
being
released
into
a
sanitary
sewer
system
for
treatment.
Keep
emptied
bags
and
drums
at
a
fixed
place
until
proper
disposal.
Drums
must
not
be
reused
for
any
other
purpose.
If
you
are
uncertain
about
how
to
properly
dispose
of
the
product,
bags,
or
drums,
contact
a
state­
registered
hazardous
materials
disposal
facility
or
an
appropriate
consultant.
State
or
local
waste
agencies
can
also
be
helpful.
Dispose
of
container
and
unused
contents
in
accordance
with
federal,
state
and
local
requirements.

AV­
100
MBA:
Whatever
cannot
be
saved
for
recovery
or
recycling
should
be
handled
in
an
appropriate
Resource
Conservation
and
Recovery
Act
(RCRA)
approved
waste
disposal
facility.
If
the
container
is
rinsed
out
properly
it
may
be
disposed
of
in
an
approved
landfill.
Processing,
use,
or
contamination
of
this
product
may
change
the
waste
management
options.
State
and
local
disposal
regulations
may
differ
from
federal
disposal
regulations.
Dispose
of
container
and
unused
contents
in
accordance
with
federal,
state
and
local
requirements.

AV­
101
Catalyst
T+:
Whatever
cannot
be
saved
for
recovery
or
recycling
should
be
handled
in
an
appropriate
RCRA­
approved
waste
disposal
facility.
If
the
container
is
rinsed
out
properly
it
may
be
disposed
of
in
an
approved
landfill.
Processing,
use,
or
contamination
of
this
product
may
change
the
waste
management
options.
State
and
local
disposal
regulations
may
differ
from
federal
disposal
regulations.
Dispose
of
container
and
unused
contents
in
accordance
with
federal,
state
and
local
requirements.

AV­
102
Catalyst
AP:
Whatever
cannot
be
saved
for
recovery
or
recycling
should
be
handled
as
hazardous
waste
and
sent
to
an
appropriate
RCRA­
approved
waste
disposal
facility.
Processing,
use,
or
contamination
of
this
product
may
change
the
waste
management
options.
State
and
local
disposal
regulations
may
differ
from
federal
disposal
regulations.
Dispose
of
container
and
unused
contents
in
accordance
w'ith
federal,
state
and
local
requirements.

Safety
Information,
Hazards
and
First
Aid
Consult
Material
Safety
Data
Sheets
(MSDS).

Shipping
Information
See
Page
35.
Mixing
Instructions
for
AV­
IOO
Chemical
Grout
(AM
Powder)
AV­
100
AM
Conventional
Mix
(11.6%
Solids,
approx.
25
Second
Gel
Time
at
72°
F)

Before
mixing
procedures
begin,
the
operator
must
determine
1)
the
necessary
gel
strength
and
gel
time
required
for
the
specific
application,
2)
the
availability
of
all
necessary
grout
components,
and
3)
that
all
safety
equipment
is
present
and
in
good
working
order.

Personal
Protective
Equipment
(PPE)
During
transfer/
mixing
operations,
the
minimum
PPE
consists
of
a
cartridge
respirator
full
facepiece
type,
a
TychemB
brand
or
equivalent
chemical
suit,
and
gloves
and
boots
that
meet
the
descriptions
in
Chapter
2.

Product
Information
A
single
55
pound
bag
of
AV­
100
AM
Acrylamide
Monomer
powder,
mixed
with
64
ounces
(2.75
pounds)
of
Methylenebisacrylamide
(MBA)
yields
a
60
gallon
batch
of
11.5%
(by
weight)
strength
acrylamide
grout.
For
best
results,
these
grouts
should
be
blended
at
concentrations
of
10%
or
greater.
Concentrations
above
10%
are
favored
for
high­
strength
gel
applications
or
to
handle
dilution
of
more
than
50%
prior
to
gelation.

Mixing
Instructions
(Conventional
Mix)

Tank
A
(Grout
Tank)
Tank
B
(Catalyst
Tank)

l
AV­
100
powder:
1
bag
l
AV­
102
AP:
5
Ibs.
(60
ounces
by
.
MBA
emulsion:
64
ounces
by
volume
volume)

l
Water:
Add
enough
water
to
make
.
AV­
101
Cat­
T:
70
ounces
by
volume
(5
Ibs.)
a
30­
gallon
batch
.
Water:
Add
enough
water
to
make
a
30­
gallon
batch.

The
above
conventional
mixture
can
be­
modified
to
meet
your
specific
application.

The
Methylenebisacrylamide
(AV­
100
MBA)
is
an
emulsion
that
is
a
required
grout
compound.
Always
use
the
complete
container
for
each
batch.
The
AV­
100
MBA
is
always
added
to
the
grout
side
tank.

The
Triethanolamine
(AV­
101
Cat­
T+)
is
a
liquid
that
is
a
required
grout
compound
and
can
be
increased
from
a
minimum
of
35
ounces
by
volume
(.
5%
by
weight,
2.5
Ibs.)
to
a
maximum
of
175
ounces
by
volume
(2.5%
by
weight,
12.5
Ibs).
Using
more
than
175
ounces
by
volume
is
not
recommended,
as
it
results
in
too
fast
a
gel
time.
The
AV­
101
Cat­
T
is
always
added
into
the
same
tank
as
the
grout.

The
Ammonium
Persulfate
(AV­
102
AP)
is
a
powder
that
is
a
required
grout
compound
and
can
be
increased
from
5
pounds
(1%
by
weight,
60
ounces
by
volume)
to
a
maximum
of
15
pounds
(3%
by
weight,
180
ounces
by
volume).
The
AV­
102
is
added
to
the
catalyst
tank.

Sodium
Persulfate
(AV­
103
SP)
is
a
powder
that
may
be
used
in
place
of
Ammonium
.Persulfate
(AV­
102
AP),
although
Avanti
International
considers
AV­
102
AP
to
be
a
more
effective
product
for
mixing
AV­
100
grouts.
The
same
amount
of
AV­
103
SP
is
used
when
replacing
AV­
102
AP.
The
AV­
103
is
added
to
the
catalyst
tank.
Storage
and
disposal
of
AV­
103
are
addressed
in
the
AV­
118
section.
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8
Grout
Transfer
Method
The
operator
and
staff
are
at
the
highest
risk
for
exposure
to
acrylamide
when
the
powdered
AV­
100
is
transferred
from
the
bag
into
the
grout
tank.
Every
precaution
should
be
taken
to
assure
that
the
operator
and
other
crewmembers
are
not
exposed
to
the
acrylamide
powder
either
in
the
air
or
spilled
in
the
vehicle.
The
following
procedure,
accompanied
by
the
wearing
of
appropriate
PPE,
effectively
reduces
the
possibility
of
chemical
exposure.

PPE
Steel­
toed
boots
and
protective
gloves
and
goggles
should
be
worn
before
moving
the
drum
containing
AV­
100
powder
from
storage.
During
the
transfer/
mixing
process
a
cartridge
respirator,
appropriate
boots
and
a
TychemB
brand
or
comparable
chemical
suit
are
required.
Gloves
approved
for
use
with
acrylamide
must
be
worn
in
order
to
keep
the
liquid
or
powder
from
coming
into
contract
with
the
skin.
Avanti
International
highly
recommends
the
use
of
a
full
face­
piece
respirator
during
transfer/
mixing
operations.

Procedure
Keep
the
bag
of
AV­
100
intact
whenever
possible.
Fill
grout
tank
with
approximately
15
gallons
of
water
before
introducing
the
AV­
100
MBA
or
AV­
100
powdered
grout.
Add
64
ounces
of
AV­
100
MBA
emulsion
to
grout
side
tank.
Add
small
amount
of
water
to
container,
rinse
to
remove
any
residue,
mix
all
thoroughly.
Do
not
let
AV­
100
MBA
contact
skin.
Place
the
neck
of
the
AV­
100
powdered
grout
bag
under
the
surface
of
the
water
as
the
grout
is
being
poured
into
the
grout
tank.
It
is
extremely
important
to
take
care
that
no
powder
is
released
into
the
air
or
spilled
during
transfer.
Empty
the
bag
of
AV­
100
powdered
grout
as
completely
as
possible
and
roll
the
bag
from
bottom
to
top
before
carefully
removing
from
the
grout
tank.
Immediately
wrap
up
the
bag
and
place
it
in
another
bag
so
that
no
powder
or
liquid
on
the
grout
bag
is
released
inside
the
vehicle.
Add
70
fluid­
ounces
by
volume
(5
Ibs.)
of
liquid
AV­
101
Cat
T+
to
the
grout
tank.
Add
5
Ibs.
(60
fluid­
ounces
by
volume)
of
powder
AV­
102
to
the
catalyst
tank.
Fill
both
tanks
to
the
30­
gallon
level
with
water.

Properly
dispose
of
the
bags
and
empty
MBA
containers,
as
described
earlier
in
this
chapter.
The
empty
bags
and
containers
must
not
be
used
for
any
other
purposes.

Field
Conditions
The
temperature
of
the
water
in
the
tanks
has
a
large
impact
on
grout
gel
times.
Therefore,
water
temperature
should
be
measured
throughout
the
day
to
help
determine
desired
grout
gel
times.
Since
the
gel
time
is
greatly
reduced
with
increasing
temperatures,
cup
tests
to
monitor
gel
times
should
be
conducted.
As
a
general
rule
of
thumb,
gel
time
is
reduced
by
one­
half
for
every
10°
F
rise
in
temperature.
Water
temperatures
can
vary
dramatically
between
early
morning
and
late
afternoon.
Trucks
parked
overnight
or
through
a
weekend
can
reach
temperatures
as
high
as
150°
F.

The
grout
side
tank
should
not
be
exposed
to
direct
sunlight
as
UV­
rays
can
accelerate
polymerization.
Optional
Additives
I
There
are
several
additives
that
can
modify
the
behavior
of
the
grout
being
used.

Ethylene
Glycol,
Liquid
(AV­
105)
Amount:
Maximum
of
2.5
gallons
per
tank.
I
Add
equal
amounts
to
both
tanks,
replaces
water.
Finish
by
filling
tanks
with
water
to
30­
gallon
I
line.
Tanks
should
not
exceed
30­
gallon
fill
line.
Result:
Enhances
grouts
ability
to
undergo
freezing
and
dehydration.
Lowers
freezing
temperature
of
the
solution.
I
Icosetilatex,
Liquid
(AV­
257)
Amount:
2
to
3
gallons.
I
Add
to
grout
side
only,
replaces
water.
Finish
by
filling
tank
with
water
to
30­
gallon
line.
Tank
should
not
exceed
30­
gallon
fill
line.
Result:
increases
compressive
and
tensile
strength,
also
increases
viscosity.
I
Potassium
Ferricyanide,
Powder
(KFe)
Amount:
Very
small
amount,
less
than
`I4
teaspoon
to
start.
Add
to
grout
side
tank.
Result:
Extends
gel
times.

Norosac,
Powder
(AC­
SOW­
A)
Amount:
3.2
ounces
by
weight.
This
is
equal
to
5­
0~
in
an
8
fluid
ounce
measuring
cup.
Add
to
grout
side
tank.
Results:
Slows
new
growth
of
roots
in
the
sewer
joints.

Additional
information
about
these
additives
is
found
in
Chapter
9.
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AV­
IOO
Chemical
Grout
(Powder
Blend)

Product
Descriptions
AV­
100
Powder
Blend
is
the
trade
name
for
an
acrylamide
grout
that
contains
MBA,
used
for
sewer
line
joint
sealing,
sewer
line
lateral
sealing,
manhole
sealing,
and
soil
stabilization.
AV100
AM
is
a
white
crystalline
acrylamide
powder
(CAS
number
79­
06­
I)
that
dissolves
completely
and
rapidly
in
water.
Mixed
in
with
the
acrylamide
is
a
small
amount
of
copper
sulfate
(blue
crystals)
that
stabilizes
the
product.
The
two­
layer
bags
are
designed
for
the
operator
to
lower
the
inner
bag
into
the
grout
tank
during
the
product
transfer.
AV­
100
Powder
Blend
is
sold
in
fiber
drums
containing
four
(4)
50
pound
bags.

AV­
101
Catalyst
T+
is
the
trade
name
for
a
blend
of
Triethanolamine
(CAS
number
102­
71­
6)
and
proprietary
additives.
AV­
101
is
a
thick
colorless
liquid
that
is
used
as
an
activator.
The
proprietary
additives
decrease
the
freezing
point,
which
allows
storage
and
transportation
in
temperatures
at
or
below
freezing.
AV­
101
is
packaged
in
both
5
gallon
plastic
drums
and
%­
gallon
lined
metal
drums.

AV­
102
Catalyst
AP
is
the
trade
name
for
Ammonium
Persulfate
(CAS
number
7727­
54­
O).
AV­
102
is
a
white
powder
that
is
used
as
a
polymerization
initiator.
It
is
packaged
in
50­
pound
plastic
pails
or
225
pound
coated
fiber
drums
with
a
plastic
inner
liner.

Storage
Requirements
AV­
100
Powder
Blend:
Store
in
a
cool
dry
area
away
from
heat.
Provide
good
ventilation.
Keep
bags
inside
drums.
Keep
container
tightly
closed
and
in
an
upright
position.
Take
measures
not
to
raise
dust.
Wear
proper
PPE
when
handling
this
product.
Store
away
from
AV­
101
Catalyst
T+
and
AV­
102
Catalyst
AP.

AV­
101
Catalyst
T+:
Store
in
a
cool
dry
area
away
from
heat.
Provide
good
ventilation.
Keep
containers
tightly
closed
and
in
an
upright
position.
Do
not
use
pressure
to
empty
containers.
Store
away
from
acids
or
oxides
as
violent
reactions
may
occur
if
product
comes
in
contact
with
these
materials.
Do
not
store
near
AV­
100
Chemical
Grouts
or
AV­
102
Catalyst
AP.

AV­
102
Catalyst
AP:
Store
in
a
cool
dry
area
away
from
heat.
Provide
good
ventilation.
Keep
container
tightly
closed
and
in
an
upright
position.
Take
measures
not
to
raise
dust.
Wear
proper
PPE
when
handling
product.
Store
away
from
acids,
alkalis,
halides,
reducing
agents,
combustible
materials
and
heavy
metals
as
violent
reactions
may
occur
if
product
comes
in
contact
with
these
materials.
Do
not
store
near
AV­
100
Chemical
Grouts
or
AV­
101
Catalyst
T+.

General
Maintain
first
aid
kit,
gloves,
respirators,
aprons,
and
cleanup
equipment
in
the
storage
area
at
all
times.
An
emergency
spill
response
kit
should
also
be
readily
available.
Foam,
carbon
dioxide,
or
dry
chemical
fire
extinguishers
should
be
easily
accessible.
Provide
eyewash,
shower,
and
a
source
of
water
in
the
storage
area.
Keep
materials
in
original
packaging
whenever
possible.
Disposal
of
Product
AV­
100
Powder
Blend:
Powder
product
must
be
gelled
or
properly
contained
and
incinerated.
The
best
method
for
disposal
is
to
gel
the
material,
as
follows.
Collect
as
much
dry
AV­
100
as
possible,
taking
all
precautions
to
avoid
creating
dust
while
collecting
the
product.
Add
AV­
101
Cat
T+,
and
gel
with
water
and
AV­
102
Catalyst
AP,
in
this
order.
Gelled
(catalyzed)
materials
pose
little
risk
and
may
be
sent
to
a
landfill.
Very
small
spills
may
be
washed
down
with
water,
with
the
water
being
released
into
a
sanitary
sewer
system
for
treatment.
Keep
emptied
bags
and
drums
at
a
fixed
place
until
proper
disposal.
Drums
must
not
be
reused
for
any
other
purpose.
If
you
are
uncertain
about
how
to
properly
dispose
of
the
product,
bags,
or
drums,
contact
a
state­
registered
hazardous
materials
disposal
facility
or
an
appropriate
consultant.
State
or
local
waste
agencies
can
also
be
helpful.
Dispose
of
container
and
unused
contents
in
accordance
with
federal,
state
and
local
requirements.

AV­
101
Catalyst
T+:
Whatever
cannot
be
saved
for
recovery
or
recycling
should
be
handled
in
an
appropriate
RCRA­
approved
waste
disposal
facility.
If
the
container
is
rinsed
out
properly
it
may
be
disposed
of
in
an
approved
landfill.
Processing,
use,
or
contamination
of
this
product
may
change
the
waste
management
options.
State
and
local
disposal
regulations
may
differ
from
federal
disposal
regulations.
Dispose
of
container
and
unused
contents
in
accordance
with
federal,
state
and
local
requirements.

AV­
102
Catalyst
AP:
Whatever
cannot
be
saved
for
recovery
or
recycling
should
be
handled
as
hazardous
waste
and
sent
to
an
appropriate
RCRA­
approved
waste
disposal
facility.
Processing,
use,
or
contamination
of
this
product
may
change
the
waste
management
options.
State
and
local
disposal
regulations
may
differ
from
federal
disposal
regulations.
Dispose
of
container
and
unused
contents
in
accordance
with
federal,
state
and
local
requirements.

Safety
Information,
Hazards
and
First
Aid
Consult
Material
Safety
Data
Sheets
(MSDS).

Shipping
Information
See
Page
35.

,"
C
Mixing
Instructions
for
AV­
IOO
Chemical
Grout
(Powder
Blend)
AV­
100
Powder
Blend
Conventional
Mix
(10.0%
Solids,
approx.
25
Second
Gel
Time
at
72°
F)

Before
mixing
procedures
begin,
the
operator
must
determine
1)
the
necessary
gel
strength
and
gel
time
required
for
the
specific
application,
2)
the
availability
of
all
necessary
grout
components,
and
3)
that
all
safety
equipment
is
present
and
in
good
working
order,

Personal
Protective
Equipment
(PPE)
During
transfer/
mixing
operations,
the
minimum
PPE
consists
of
a
cartridge
respirator
full
facepiece
type,
a
TychemB
brand
or
equivalent
chemical
suit,
and
gloves
and
boots
that
meet
the
descriptions
in
Chapter
2.

Product
Information
A
single
50
pound
bag
of
AV­
100
Powder
Blend,
containing
Methylenebisacrylamide
(MBA)
yields
a
60
gallon
batch
of
10.0%
(by
weight)
strength
acrylamide
grout.
For
best
results,
these
grouts
should
be
blended
at
concentrations
of
10%
or
greater.
Concentrations
above
10%
are
favored
for
high­
strength
gel
applications
or
to
handle
dilution
of
more
than
50%
prior
to
gelation.

Mixing
Instructions
(Conventional
Mix)

Tank
A
(Grout
Tank)
9
AV­
I
00
Powder
Blend:
1
bag
l
AV­
101
Cat­
T:
70
ounces
by
volume
(5
Ibs.)

l
Water:
Add
enough
water
to
make
a
30­
gallon
batch.
Tank
B
(Catalyst
Tank)

l
AV­
102
AP:
5
Ibs.
(60
ounces
by
volume)

l
Water:
Add
enough
water
to
make
a
30­
gallon
batch
The
above
conventional
mixture
can
be
modified
to
meet
your
specific
application.

The
Triethanolamine
(AV­
101
Cat­
T+)
is
a
liquid
that
is
a
required
grout
compound
and
can
be
increased
from
a
minimum
of
35
ounces
by
volume
(5%
by
weight,
2.5
Ibs.)
to
a
maximum
of
175
ounces
by
volume
(2.5%
by
weight,
12.5
Ibs).
Using
more
than
175
ounces
by
volume
is
not
recommended.
The
AV­
101
Cat­
T
is
always
added
into
the
same
tank
as
the
grout.

The
Ammonium
Persulfate
(AV­
102
AP)
is
a
powder
that
is
a
required
grout
compound
and
can
be
increased
from
5
pounds
(1%
by
weight,
60
ounces
by
volume)
to
a
maximum
of
15
pounds
(3%
by
weight,
180
ounces
by
volume).
The
AV­
102
is
added
to
the
catalyst
tank.
Sodium
Persulfate
(AV­
103
SP)
is
a
powder
that
may
be
used
in
place
of
Ammonium
Persulfate
(AV­
102
AP).
The
same
amount
of
AV­
103
SP
is
used
when
replacing
AV­
102
AP.
Avanti
International
prefers
AV­
102
AP
when
mixing
AV­
100
grouts.
The
AV­
103
is
added
to
the
catalyst
tank.
Storage
and
disposal
issues
of
AV­
103
are
addressed
in
the
AV118
section.

Grout
Transfer
Method
The
operator
and
staff
are
at
the
highest
risk
for
exposure
to
acrylamide
when
the
powdered
AV­
100
is
transferred
from
the
bag
into
the
grout
tank.
Every
precaution
should
be
taken
to
assure
that
the
operator
and
other
crewmembers
are
not
exposed
to
the
acrylamide
powder
either
in
the
air
or
spilled
in
the
vehicle.
The
following
procedure,
accompanied
by
the
wearing
of
appropriate
PPE,
effectively
reduces
the
possibility
of
chemical
exposure.
PPE
Steel­
toed
boots;
and
protective
gloves
and
goggles
should
be
worn
before
moving
the
drum
containing
AV­
100
powder
from
storage.
During
the
transfer/
mixing
process
a
cartridge
respirator,
appropriate
boots,
and
a
Tychem@
brand
or
equivalent
chemical
suit
are
required.
Gloves
approved
for
use
with
acrylamide
must
be
worn
in
order
to
keep
the
liquid
or
powder
from
coming
into
contract
with
the
skin.
Avanti
International
highly
recommends
the
use
of
a
full
face­
piece
respirator
during
transfer/
mixing
operations.

Procedure
l
Keep
the
bag
of
AV­
100
intact
whenever
possible.

l
Fill
grout
tank
with
approximately
15
gallons
of
water
before
introducing
the
AV­
100
Powder
Blend
grout.

l
Place
the
neck
of
the
AV­
100
Powder
Blend
grout
bag
under
the
surface
of
the
water
as
the
grout
is
being
poured
into
the
grout
tank.
­
It
is
extremely
important
to
take
care
that
no
powder
is
released
into
the
air
or
spilled
during
transfer.

l
Empty
the
bag
of
AV­
100
Powder
Blend
grout
as
completely
as
possible
and
roll
the
bag
from
bottom
to
top
before
carefully
removing
from
the
grout
tank.

l
Immediately
wrap
up
the
bag
and
place
it
in
another
bag
so
that
no
powder
or
liquid
on
the
grout
bag
is
released
inside
the
vehicle.

l
Add
70
fluid­
ounces
by
volume
(5
Ibs.)
of
liquid
AV­
101
Cat
T+
to
the
grout
tank.

l
Add
5
Ibs.
(60
fluid­
ounces
by
volume)
of
powder
AV­
102
to
the
catalyst
tank.

l
Fill
both
tanks
to
the
30­
gallon
level
with
water.

Properly
dispose
of
the
bags
and
empty
MBA
containers,
described
earlier
in
this
chapter.
The
empty
bags
and
containers
must
not
be
used
for
any
other
purposes.

Field
Conditions
The
temperature
of
the
water
in
the
tanks
has
a
large
impact
on
grout
gel
times.
Therefore,
water
temperature
should
be
measured
throughout
the
day
to
help
determine
desired
grout
gel
times.
Since
the
gel
time
is
greatly
reduced
with
increasing
temperatures,
cup
tests
to
monitor
gel
times
should
be
conducted.
As
a
general
rule
of
thumb,
gel
time
is
reduced
by
one­
half
for
every
10°
F
rise
in
temperature.
Water
temperatures
can
vary
dramatically
between
early
morning
and
late
afternoon.
Trucks
parked
overnight
or
through
a
weekend
can
reach
temperatures
as
high
as
150°
F.

The
grout
side
tank
should
not
be
exposed
to
direct
sunlight
as
UV­
rays
can
accelerate
polymerization.
Optional
Additives
There
are
several
additives
that
can
modify
the
behavior
of
the
grout
being
used.

Ethylene
Glycol,
Liquid
(AV­
105)
Amount:
Maximum
of
2.5
gallons
per
tank.
Add
equal
amounts
to
both
tanks,
replaces
water.
Finish
by
filling
tanks
with
water
to
30­
gallon
line.
Tanks
should
not
exceed
30­
gallon
fill
line.
Result:
Enhances
grouts
ability
to
undergo
freezing
and
dehydration.
Lowers
the
freezing
temperature
of
the
solution.

Icosetllatex,
Liquid
(AV­
257)
Amount:
2
to
3
gallons.
Add
to
grout
side
only,
replaces
water.
Finish
by
filling
tank
with
water
to
30­
gallon
line.
Tank
should
not
exceed
30­
gallon
fill
line.
Result:
Increases
compressive
and
tensile
strength,
also
increases
viscosity.

Potassium
Ferricyanide,
Powder
(KFe)
Amount:
Very
small
amount,
less
than
%
teaspoon
to
start.
Add
to
grout
side
tank.
Result:
Extends
gel
times.

Norosac,
Powder
(AC­
50W­
A)
Amount:
3.2
ounces
by
weight.
This
is
equal
to
5­
0~
in
an
8
fluid
ounce
measuring
cup.
Add
to
grout
side
tank.
Results:
Slows
new
growth
of
roots
in
the
sewer
joints.

Additional
information
about
these
additives
is
found
in
Chapter
9.
AV­
IOO
Chemical
Grout
(Liquid)

Product
Descriptions
AV­
100
Chemical
Grout
is
the
trade
name
for
a
liquid
acrylamide
grout
used
for
sewer
line
joint
sealing,
sewer
line
lateral
sealing,
manhole
sealing,
and
soil
stabilization.
AV­
100
is
a
clear,
watery
liquid
(CAS
number
79­
06­
I).
Included
with
the
acrylamide
is
a
small
amount
of
copper
sulfate
that
stabilizes
the
product.
AV­
100
is
sold
in
plastic
drums
containing
approximately
14
gallons.

AV­
101
Catalyst
T+
is
the
trade
name
for
a
blend
of
Triethanolamine
(CAS
number
102­
71­
6)
and
proprietary
additives.
AV­
101
is
a
thick,
colorless
liquid,
that
is
used
as
an
activator.
The
proprietary
additives
decrease
the
freezing
point,
which
allows
field
use
in
temperatures
at
or
below
freezing.
AV­
101
is
packaged
in
both
5gallon
plastic
drums
and
55gallon
lined
metal
drums.

AV­
102
Catalyst
AP
is
the
trade
name
for
Ammonium
Persulfate
(CAS
number
7727­
54­
O).
AV­
102
is
a
white
powder
that
is
uses
as
a
polymerization
initiator.
It
is
packaged
in
50­
pound
plastic
pails
or
225
pound
coated
fiber
drums
with
a
plastic
inner
liner.

Storage
Requirements
AV­
100
Chemical
Grout:
Store
in
a
cool
dry
area
away
from
heat.
Provide
good
ventilation.
Keep
container
tightly
closed
and
in
an
upright
position.
Do
not
use
pressure
to
empty
containers.
Wear
proper
PPE
when
handling
this
product.
Store
away
from
AV­
101
Catalyst
T+
and
AV­
102
Catalyst
AP.

AV­
101
Catalyst
T+:
Store
in
a
cool
dry
area
away
from
heat.
Provide
good
ventilation.
Keep
containers
tightly
closed
and
in
an
upright
position.
Do
not
use
pressure
to
empty
containers.
Store
away
from
acids
or
oxides
as
violent
reactions
may
occur
if
product
comes
in
contact
with
these
materials.
Do
not
store
near
AV­
100
Chemical
Grouts
or
AV­
102
Catalyst
AP.

AV­
402
Catalyst
AP:
Store
in
a
cool
dry
area
away
from
heat.
Provide
good
ventilation.
Keep
container
tightly
closed
and
in
an
upright
position.
Take
measures
not
to
raise
dust.
Wear
proper
PPE
when
handling
product.
Store
away
from
acids,
alkalis,
halides,
reducing
agents,
combustible
materials
and
heavy
metals
as
violent
reactions
may
occur
if
product
comes
in
contact
with
these
materials.
Do
not
store
near
AV­
100
Chemical
Grouts
or
A&
l01
Catalyst
T+.

General
Maintain
first
aid
kit,
gloves,
respirators,
aprons,
and
cleanup
equipment
in
the
storage
area
at
all
times.
An
emergency
spill
response
kit
should
also
be
readily
available.
Foam,
carbon
dioxide,
or
dry
chemical
fire
extinguishers
should
be
easily
accessible.
Provide
eyewash,
shower,
and
a
source
of
water
in
the
storage
area.
Keep
materials
in
original
packaging
whenever
possible.
Disposal
of
Product
AV­
100
Chemical
Grout:
The
best
method
for
disposal
is
to
gel
the
material.
Collect
as
much
liquid
AV­
100
as
possible,
add
AV­
101
Cat
T+,
and
gel
with
AV­
102
Catalyst
AP
mixed
with
water,
in
this
order.
Gelled
(catalyzed)
materials
pose
little
risk
and
may
be
sent
to
a
landfill.
Very
small
spills
may
be
washed
down
with
water
with
the
water
being
released
into
a
sanitary
sewer
system
for
treatment.
Keep
emptied
drums
at
a
fixed
place
until
proper
disposal.
Drums
must
not
be
reused
for
any
other
purpose.
If
you
are
uncertain
about
how
to
properly
dispose
of
the
product
or
drums,
contact
a
state
registered
hazardous
materials
disposal
facility
or
an
appropriate
consultant.
State
or
local
waste
agencies
can
also
be
helpful.
Dispose
of
container
and
unused
contents
in
accordance
with
federal,
state
and
local
requirements.

AV­
101
Catalyst
T+:
Whatever
cannot
be
saved
for
recovery
or
recycling
should
be
managed
in
an
appropriate
RCRA­
approved
waste
disposal
facility.
If
the
container
is
rinsed
out
properly
it
may
be
disposed
of
in
an
approved
landfill.
Processing,
use,
or
contamination
of
this
product
may
change
the
waste
management
options.
State
and
local
disposal
regulations
may
differ
from
federal
disposal
regulations.
Dispose
of
container
and
unused
contents
in
accordance
with
federal,
state
and
local
requirements.

AV­
102
Catalyst
AP:
Whatever
cannot
be
saved
for
recovery
or
recycling
should
be
handled
as
hazardous
waste
and
sent
to
a
RCRA­
approved
waste
facility.
Processing,
use,
or
contamination
of
this
product
may
change
the
waste
management
options.
State
and
local
disposal
regulations
may
differ
from
federal
disposal
regulations.
Dispose
of
container
and
unused
contents
in
accordance
with
federal,
state
and
local
requirements.

Safety
Information,
Hazards
and
First
Aid
Consult
Material
Safety
Data
Sheets
(MSDS).

Shipping
Information
See
Page
35.
Mixing
Instructions
for
AV­
IOO
Chemical
Grout
(Liquid)
Conventional
Mix
(10%
Solids,
approx.
25
Second
Gel
Time
at
72°
F)

Before
mixing
procedures
begin,
the
operator
must
determine
1)
the
necessary
gel
strength
and
gel
time
required
for
the
specific
application,
2)
the
availability
of
all
necessary
grout
components,
and
3)
that
all
safety
equipment
is
present
and
in
good
working
order.

Personal
Protective
Equipment
(PPE)
During
transfer/
mixing
operations,
the
minimum
PPE
consists
of
a
cartridge
respirator
full
facepiece
type,
a
TychemB
brand
or
equivalent
chemical
suit,
and
gloves
and
boots
that
meet
the
descriptions
in
Chapter
2.

Product
Information
The
15gallon
drum
contains
approximately
14
gallons
of
liquid
grout,
the
equivalent
of
a
single
50­
pound
bag
of
AV­
100
powder,
including
MBA,
dissolved
in
water.

Most
manufacturers
of
equipment
have
standardized
by
providing
two
30­
gallon
chemical
tanks.
When
properly
mixed,
one
drum
of
liquid
AV­
100
acrylamide
grout
results
in
a
10%
(by
weight)
strength
grout
solution
of
60
gallons.
Using
two
drums
of
AV­
100
acrylamide
grout
results
in
a
20%
(by
weight)
strength
grout
solution
of
60
gallons.

One
15gallon
drum
will
make
a
60­
gallon
batch
of
grout.
For
best
results,
grouts
should
be
blended
at
concentrations
of
10%
or
greater.
Concentrations
above
10%
are
favored
for
highstrength
gel
applications
or
to
handle
dilution
of
more
than
50%
prior
to
gelation.

Mixing
Instructions
(Conventional
mix)

Tank
A
(Blue
Grout
Tank)
.
AV­
100
liquid:
1
drum
l
AV­
101
Cat­
T:
70
ounces
by
volume
(5
Ibs.)

l
Water:
Add
enough
water
to
make
a
30­
gallon
batch.

The
above
conventional
mixture
can
be
mo
I
Tank
B
(Red
Tank)

l
AV­.
I02
AP:
5
Ibs.
(60
ounces
by
volume)

l
Water:
Add
enough
water
to
make
a
30­
gallon
batch
ed
to
meet
your
specific
application.

The
Triethanolamine
(AV­
101
Cat­
T)
is
a
liquid
that
is
a
required
grout
component
and
can
be
increased
from
a
minimum
of
35
ounces
by
volume
(5%
by
weight,
2.5
Ibs.)
to
a
maximum
of
175
ounces
by
volume
(2.5%
by
weight,
12.5
Ibs).
Using
more
than
175
ounces
by
volume
is
not
recommended.
The
AV­
101
Cat­
T
is
always
added
into
the
same
tank
as
the
grout.

The
Ammonium
Persulfate
(AV­
102
AP)
is
a
powder
that
is
a
required
grout
component
and
can
be
increased
from
5
pounds
(1%
by
weight,
60
ounces
by
volume)
to
a
maximum
of
15
pounds
(3%
by
weight,
180
ounces
by
volume).

Sodium
Persulfate
(AV­
103
SP)
is
a
powder
that
may
be
used
in
place
of
Ammonium
Persulfate
(AV­
102
AP).
The
same
amount
of
AV­
103
SP
is
used
when
replacing
AV­
102
AP.
Avanti
International
prefers
AV­
102
AP
when
mixing
AV­
100
grouts.
Grout
Transfer
Method
Avanti
highly
recommends
the
use
of
a
pump,
hand
or
electric,
to
transfer
liquid
grout
from
the
­l5­
gallon
drum
into
the
grout
tank.
Using
a
pump
minimizes
worker
exposure
to
grout
spills
or
splashes.
Another
benefit
of
using
a
pump
is
that
the
empty
grout
drum
will
be
rinsed
and
ready
for
disposal
or
recycling;
that
can
be
accomplished
by
adding
the
solution
mix
water
to
the
empty
grout
drum
and
pumping
it
in
the
grout
tank.
The
following
procedure,
accompanied
by
the
wearing
of
appropriate
PPE,
effectively
reduces
the
possibility
of
chemical
exposure.

PPE
Steel­
toed
boots;
and
protective
gloves
and
goggles
should
be
worn
before
moving
the
drum
containing
AV­
100
liquid
from
storage.
During
the
transfer/
mixing
process
a
cartridge
respirator,
appropriate
boots
and
a
TychemB
brand
or
equivalent
chemical
suit
are
required.
Gloves
approved
for
use
with
acrylamide
must
be
worn
in
order
to
keep
the
liquid
from
coming
into
contract
with
the
skin.
Avanti
International
highly
recommends
the
use
of
a
full
face­
piece
respirator
during
transfer/
mixing
operations.

Procedure
A
power
lift
or
two
men
should
be
used
when
lifting
the
130­
pound
grout
drum
into
the
back
of
the
grout
truck.
Place
the
15gallon
grout
drum
within
several'feet
of
the
grout­
side
mixing
tank.
Using
a
bung
tool,
remove
the
2­
inch
bung,
being
careful
not
to
let
surface
contamination
enter
the
drum.
Caution:
Wetted
pump
parts
must
be
plastic
or
stainless
steel
only.
Place
the
hand
pump
suction
tube
into
the
drum
and
secure
by
completely
threading
the
down
tube
into
the
drum.
Place
pump
discharge
hose
into
grout
tank
extending
the
hose
at
least
113
of
the
way
into
the
tank.
Caution
must
be
used
to
make
sure
the
hose
does
not
slip
out
of
the
tank
during
transfer.
Maintain
a
steady
flow
while
pumping
grout.
When
the
grout
drum
is
empty,
add
5
to
7
gallons
of
water
to
grout
drum
through
the
small
l­
inch
bung.
Pump
water
from
the
grout
drum
into
the
grout
tank.
This
process
effectively
rinses
the
drum.
Remove
hose
from
the
grout
tank.
Remove
pump
from
the
grout
drum.
Wash
and
flush
the
pump,
and
hoses.
Store
pump
and
hoses
in
a
clean
environment.
Properly
dispose
of
drum
or
call
a
drum
recycling
company.
This
empty
drum
must
not
be
used
for
any
other
purpose.
Add
70
fluid­
ounces
by
volume
(5
Ibs.)
of
liquid
AV­
101
Cat
T+
to
the
grout
tank.
Add
5
Ibs.
(60
fluid­
ounces
by
volume)
of
powder
AV­
102
to
the
catalyst
tank.
Fill
both
tanks
to
the
30­
gallon
level
with
water.

19
@z&.
7
7
Field
Conditions
The
temperature
of
the
water
in
the
tanks
has
a
very
large
impact
on
grout
gel
times.
Since
the
gel
time
is
greatly
reduced
with
increasing
temperatures,
gel
times
should
be
determined
throughout
the
day.
As
a
general
rule
of
thumb,
gel
time
is
reduced
by
one­
half
for
every
10°
F
rise
in
temperature.
Therefore,
water
temperature
should
be
measured
to
help
determine
desired
grout
gel
times.
Water
temperatures
should
also
be
monitored
throughout
grouting
operations
as
temperatures
can
vary
dramatically
between
early
morning
and
late
afternoon.
Trucks
parked
overnight
or
through
a
weekend
can
reach
temperatures
as
high
as
150°
F.

The
grout
side
tank
should
not
be
exposed
to
direct
sunlight
as
UV­
rays
can
accelerate
polymerization.

Optional
Additives
There
are
several
additives
that
can
modify
the
behavior
of
the
grout
being
used.

Ethylene
Glycol,
Liquid
(AV­
105)
Amount:
Maximum
of
2.5
gallons
per
tank.
Add
equal
amounts
to
both
tanks,
replaces
water.
Finish
by
filling
tanks
with
water
to
30­
gallon
line.
Tanks
should
not
exceed
30­
gallon
fill
line.
Result:
Enhances
grout's
ability
to
undergo
freezing
and
dehydration.
Lowers
freezing
temperature
of
the
solution.

Icoset/
Latex,
Liquid
(AV­
257)
Amount:
2
to
3
gallons.
Add
to
grout
side
only;
replaces
water.
Finish
by
filling
tank
with
water
to
30­
gallon
line.
Tank
should
not
exceed
30­
gallon
fill
line.
Result:
Increases
compressive
and
tensile
strength,
also
increases
viscosity.

Potassium
Ferricyanide,
Powder
(KFe)
Amount:
Very
small
amount,
less
than
%
teaspoon
to
start.
Add
to
grout
side
tank.
Result:
Extends
gel
times.

Norosac,
Powder
(AC­
50­
A)
Amount:
3.2
ounces
by
weight.
Add
to
grout
side
tank.
Results:
Slows
new
growth
of
roots
in
the
sewer
joints.
i
Additional
information
about
these
additives
is
found
in
Chapter
9.
AV­
118
Duriflex
Product
Descriptions
AV­
118
Duriflex
is
the
trade
name
for
an
acrylic
grout
used
for
sewer
line
joint
sealing,
sewer
line
lateral
sealing,
manhole
sealing,
and
soil
stabilization.
AV­
118
is
a
clear,
watery
liquid
containing
N­
Methylolacrylamide
(CAS
number
924­
42­
5).
Included
with
the
NMethylolacrylamide
is
5%
acrylamide
and
a
small
amount
of
copper
sulfate
that
stabilizes
the
product.
The
AV­
118
is
packaged
in
a
plastic
drum
containing
15
gallons.

AV­
101
Catalyst
T+
is
the
trade
name
for
a
blend
of
Triethanolamine
(CAS
number
102­
71­
6)
and
proprietary
additives.
AV­
101
is
a
thick,
colorless
liquid
that
is
used
as
an
initiator.
The
proprietary
additives
decrease
the
freezing
point,
which
allows
storage
and
transportation
in
temperatures
at
or
below
freezing.
AV­
101
is
packaged
in
both
5­
gallon
plastic
drums
and
X­
gallon
lined
metal
drums.

AV­
103
Catalyst
SP
is
the
trade
name
for
Sodium
Persulfate
(CAS
number
7775­
27­
l).
AV­
103
is
a
white
powder
that
is
used
as
a
polymerization
initiator.
It
is
packaged
in
25­
pound
plastic
pails,
50­
pound
plastic
pails,
and
225­
pound
coated
fiber
drums
with
a
plastic
inner
liner.

Storage
Requirements
AV­
118
Duriflek
Store
in
a
cool
dry
area
away
from
heat.
Provide
good
ventilation.
Keep
container
tightly
closed
and
in
an
upright
position.
Do
not
use
pressure
to
empty
containers.
Wear
proper
PPE
when
handling
this
product.
Store
away
from
AV­
101
Catalyst
T+
and
AV­
103
Catalyst
SP.

AV­
101
Catalyst
T+:
Store
in
a
cool
dry
area
away
from
heat.
Provide
good
ventilation.
Keep
containers
tightly
closed
and
in
an
upright
position.
Do
not
use
pressure
to
empty
containers.
Store
away
from
acids
or
oxides
as
violent
reactions
may
occur
if
product
comes
in
contact
with
these
materials.
Do
not
store
near
AV­
118
Duriflex
or
AV­
103
Catalyst
SP.

AV­
103
Catalyst
SP:
Store
in
a
cool
dry
area
away
from
heat.
Provide
good
ventilation.
Keep
container
tightly
closed
and
in
an
upright
position.
Take
measures
not
to
raise
dust.
Wear
proper
PPE
when
handling
product.
Store
away
from
acids,
alkalis,
halides,
reducing
agents,
combustible
materials
and
heavy
metals
as
violent
reactions
may
occur
if
product
comes
in
contact
with
these
materials.
Do
not
store
near
AV­
118
Duriflex
or
AV­
101
Catalyst
T+.

General:
Maintain
first
aid
kit,
gloves,
respirators,
aprons,
and
cleanup
equipment
in
the
storage
area
at
all
times.
Emergency
spill
response
kit
should
also
be
readily
available.
Foam,
carbon
dioxide,
or
dry
chemical
fire
extinguishers'should
be
easily
accessible.
Provide
eyewash,
shower,
and
a
source
of
water
in
the
storage
area.
Disposal
of
Product
AV­
il8
Duriflex:
The
best
method
for
disposal
is
to
gel
the
material.
Collect
as
much
liquid
AV­
118
as
possible,
add
AV­
101
Cat
T+,
and
gel
with
AV­
103
Catalyst
SP
mixed
with
water,
in
this
order.
Gelled
(catalyzed)
materials
pose
little
risk
and
may
be
sent
to
a
landfill.
Very
small
spills
may
be
washed
down
with
water
and
released
into
a
sanitary
sewer
system
for
treatment.
Keep
emptied
drums
at
a
fixed
place
until
proper
disposal.
Drums
must
not
be
reused
for
any
other
purpose.
If
you
are
uncertain
about
how
to
properly
dispose
of
the
product
or
drums,
contact
a
state
registered
hazardous
materials
disposal
facility
or
an
appropriate
consultant.
State
or
local
waste
agencies
can
also
be
helpful.
Dispose
of
container
and
unused
contents
in
accordance
with
federal,
state
and
local
requirements.

AV­
101
Catalyst
T+:
Whatever
cannot
be
saved
for
recovery
or
recycling
should
be
managed
in
an
appropriate
RCRA­
approved
waste
disposal
facility.
Dispose
of
properly
rinsed
container
in
an
approved
landfill.
Processing,
use,
or
contamination
of
this
product
may
change
the
waste
management
options.
State
and
local
disposal
regulations
may
differ
from
federal
disposal
regulations.
Dispose
of
container
and
unused
contents
in
accordance
with
federal,
state
and
local
requirements.

AV­
103
Catalyst
SP:
Whatever
cannot
be
saved
for
recovery
or
recycling
should
be
handled
as
hazardous
waste
and
sent
to
an
RCRA­
approved
waste
facility.
Processing,
use,
or
contamination
of
this
product
may
change
the
waste
management
options.
State
and
local
disposal
regulations
may
differ
from
federal
disposal
regulations.
Dispose
of
container
and
unused
contents
in
accordance
with
federal,
state
and
local
requirements.

Safety
Information,
Hazards
and
First
Aid
Consult
Material
Safety
Data
Sheets
(MSDS).

Shipping
Information
See
Page
35.
Mixing
Instructions
for
AV­
1
18
Duriflex
Conventional
Mix
(10%
Solids,
approx.
25
Second
Gel
Time
at
72°
F)

Before
mixing
procedures
begin,
the
operator
must
determine
1)
the
necessary
gel
strength
and
gel
time
required
for
the
specific
application,
2)
the
availability
of
all
necessary
grout
components,
and
3)
that
all
safety
equipment
is
present
and
in
good
working
order.

Personal
Protective
Equipment
(PPE)
During
transfer/
mixing
operations,
the
minimum
PPE
consists
of
a
cartridge
respirator
full
facepiece
type,
a
Tychem@
brand
or
equivalent
chemical
suit,
and
gloves
and
boots
that
meet
the
descriptions
in
Chapter
2.

Product
Information
The
15gallon
drum
contains
15
gallons
of
liquid
grout.

Most
manufacturers
of
equipment
have
standardized
by
providing
two
30­
gallon
chemical
tanks.
When
properly
mixed,
one
drum
of
liquid
AV­
118
acrylic
grout
results
in
a
10%
(by
weight)
strength
grout
solution
of
60
gallons.
Using
two
drums
of
AV­
118
acrylic
grout
results
in
a
20%
(by
weight)
strength
grout
solution
of
60
gallons.

One
15gallon
drum
will
make
a
60­
gallon
batch
of
grout.
For
best
results,
grouts
should
be
blended
at
concentrations
of
10%
or
greater.
Concentrations
above
10%
are
favored
for
highstrength
gel
applications
or
to
handle
dilution
of:
more
than
50%
prior
to
gelation.

Mixing
Instructions
(Conventional
Mix)

Tank
A
(Blue
Grout
Tank)
Tank
B
(Red
Tank)

l
AV­
118
liquid:
1
drum
.
AV­
103
SP:
5
Ibs.
(60
ounces
by
l
AV­
101
Cat­
T:
70
ounces
by
volume
volume)
(5
Ibs.)
l
Water:
Add
enough
water
to
make
l
Water:
Add
enough
water
to
make
a
30­
gallon
batch
a
30­
gallon
batch.

The
above
conventional
mixture
can
be
modified
to
meet
your
specific
application.

The
Triethanolamine
(AV­
101
Cat­
T)
is
a
liquid
that
is
a
required
grout
component
and
can
be
increased
from
a
minimum
of
35
fluid
ounces
(5%
by
weight,
2.5
Ibs.)
to
a
maximum
of
175
ounces
by
volume
(2.5%
by
weight,
12.5
Ibs).
Using
more
than
175
ounces
by
volume
is
not
recommended.
The
AV­
101
Cat­
T
is
always
added
into
the
same
tank
as
the
grout.

Sodium
Persulfate
(AV­
103
SP)
is
a
powder
that
is
a
required
grout
component
and
can
be
increased
from
5
pounds
(1%
by
weight,
60
ounces
by
volume)
to
a
maximum
of
15
pounds
(3%
by
weight,
180
ounces
by
volume).
Only
Sodium
Persulfate
may
be
used
with
AV­
118.

Grout
Transfer
Method
Avanti
highly
recommends
the
use
of
a
pump,
hand
or
electric,
to
transfer
liquid
grout
from
the
15gallon
drum
into
the
grout
tank.
Using
a
pump
minimizes
worker
exposure
to
grout
spills
or
splashes.
Another
benefit
of
using
a
pump
is
that
the
empty
grout
drum
will
be
rinsed
and
ready
for
disposal
or
recycling;
that
can
be
accomplished
by
adding
the
solution
mix
water
to
the
empty
drum
and
pumping
it
to
the
grout
tank.
The
following
procedure,
accompanied
by
the
wearing
of
appropriate
PPE,
effectively
reduces
the
possibility
of
chemical
exposure.
PPE
Steel­
toed
boots
and
protective
gloves
and
goggles
should
be
worn
before
moving
the
drum
containing
AV­
100
powder
from
storage.
During
the
transfer/
mixing
process
a
cartridge
­
respirator,
appropriate
boots
and
a
Tychem8
brand
or
equivalent
chemical
suit
are
required.
Gloves
approved
for
use
with
acrylamide
must
be
worn
in
order
to
keep
the
liquid
or
powder
from
coming
into
contract
with
the
skin.
Avanti
International
highly
recommends
the
use
of
a
full
face­
piece
respirator
during
transfer/
mixing
operations.

Procedure
A
power
lift
or
two
men
should
be
used
when
lifting
the
130­
pound
grout
drum
into
the
back
of
the
grout
truck.
Place
the
15­
gallon
grout
drum
within
several
feet
of
the
grout­
side
mixing
tank.
Using
a
bung
tool,
remove
the
2­
inch
bung,
being
careful
not
to
let
surface
contamination
enter
the
drum.
Caution:
Wetted
pump
parts
must
be
plastic
or
stainless
steel
only.
Place
the
hand
pump
suction
tube
into
the
drum
and
secure
by
completely
threading
the
down
tube
into
the
drum.
Place
pump
discharge
hose
into
grout
tank
extending
the
hose
at
least
l/
3
of
the
way
into
the
tank.
Caution
must
be
used
to
make
sure
the
hose
does
not
slip
out
of
the
tank
during
transfer.
Maintain
a
steady
flow
while
pumping
grout.
When
the
grout
drum
is
empty,
add
5
to
7
gallons
of
water
to
grout
drum
through
the
small
l­
inch
bung.
Pump
water
from
the
grout
drum
into
the
grout
tank.
This
process
effectively
rinses
the
drum.
Remove
hose
from
the
grout
tank.
Remove
pump
from
the
grout
drum.
Wash
and
flush
the
pump
and
hoses.
Store
pump
and
hoses
in
a
clean
environment.
Properly
dispose
of
drum
or
call
a
drum
recycling
company.
This
empty
drum
must
not
be
used
for
any
other
purpose.
Add
70
fluid­
ounces
by
volume
(5
Ibs.)
of
liquid
AV­
101
Cat
T+
to
the
grout
tank.
Add
5
Ibs.
(60
fluid­
ounces
by
volume)
of
powder
AV­
102
to
the
catalyst
tank.
Fill
both
tanks
to
the
30­
gallon
levei
with
water.

Field
Conditions
The
temperature
of
the
water
in
the
tanks
has
a
very
large
impact
on
grout
gel
times.
Since
the
gel
time
is
greatly
reduced
with
increasing
temperatures,
gel
times
should
be
determined
throughout
the
day.
As
a
general
rule
of
thumb,
gel
time
is
reduced
by
one­
half
for
every
10°
F
rise
in
temperature.
Therefore,
water
temperature
should
be
measured
to
help
determine
desired
grout
gel
times.
Water
temperatures
should
also
be
monitored
throughout
grouting
operations
as
temperatures
can
vary
dramatically
between
early
morning
and
late
afternoon.
Trucks
parked
overnight
or
through
a
weekend
can
reach
temperatures
as
high
as
150°
F.

The
grout
side
tank
should
not
be
exposed
to
direct
sunlight
as
UV­
rays
can
accelerate
polymerization.

24
Optional
Additives
There
are
several
additives
that
can
modify
the
behavior
of
the
grout
being
used.

Ethylene
Glycol,
Liquid
(AV­
105)
Amount:
Maximum
of
2.5
gallons
per
tank.
Add
equal
amounts
to
both
tanks;
replaces
water.
Finish
by
filling
tanks
with
water
to
30­
gallon
line.
Tanks
should
not
exceed
30­
gallon
fill
line.
Result:
Enhances
grout's
ability
to
undergo
freezing
and
dehydration.
Lowers
freezing
temperature
of
the
solution.

Icoset/
Latex,
Liquid
(AV­
257)
Amount:
2
to
3
gallons.
Add
to
grout
side
only;
replaces
water.
Finish
by
filling
tank
with
water
to
30­
gallon
line.
Tank
should
not
exceed
30­
gallon
fill
line.
Result:
Increases
compressive
and
tensile
strength,
also
increases
viscosity.

Potassium
Ferricyanide,
Powder
(KFe)
Amount:
Very
small
amount,
less
than
I4
teaspoon
to
start.
Add
to
grout
side
tank.
Result:
Extends
gel
times.

Norosac,
Powder
(AC­
50­
A)
Amount:
3.2
ounces
by
weight.
Add
to
grout
side
tank.
Results:
Slows
new
growth
of
roots
in
the
sewer.

Additional
information
about
these
additives
is
found
in
Chapter
9.
Additives
Product
Descriptions
AV­
105
Ethylene
Glycol
is
the
trade
name
for
ethylene
glycol
used
as
an
acrylamide
and
acrylic
grout
additive.
AV­
105
is
a
clear,
oily
liquid
(CAS
number
107­
21­
l)
that
enhances
grout's
ability
to
undergo
freezing
and
dehydration.
AV­
105
is
packaged
in
5gallon
pails.

AV­
257
lcoset
is
the
trade
name
for
an
acrylamide
and
acrylic
grout
additive.
AV­
257
is
a
milky­
white,
liquid
emulsion
that
increases
compressive
and
tensile
strength
while
increasing
viscosity.
AV­
257
is
packaged
in
5­
gallon
pails
and
55gallon
drums.

AC­
50W­
A
Norosac
is
the
trade
name
for
the
herbicide
dichlobenil.
AC­
50W­
A
is
a
crystalline
powder
(CAS
number
141­
30­
o)
designed
to
slow
root
growth.
AC­
50W­
A
is
packaged
in
4­
pound
bags.

Potassium
Ferricyanide
(KFe)
is
the
chemical
name
of
a
grout
additive.
KFe
is
used
to
extend
gel
times
of
acrylamide
and
acrylic
grouts.
KFe
is
an
orange,
crystalline
powder.
KFe
is
packaged
in
one­
pound
bottles.

Storage
Requirements
AV­
105
Ethylene
Glycol:
Store
in
a
cool
dry
area
away
from
heat.
Provide
good
ventilation.
Keep
containers
tightly
closed
and
in
an
upright
position.
Do
not
use
pressure
to
empty
containers.
Store
away
from
acids
or
oxides
as
violent
reactions
may
occur
if
product
contacts
these
materials.
Do
not
store
near
AV­
101
,
AV­
102,
or
AV­
103.

AV­
257
Icoset:
Store
in
a
cool
dry
area
away
from
heat.
Provide
good
ventilation.
Keep
containers
tightly
closed
and
in
an
upright
position.
Do
not
use
pressure
to
empty
containers.

AC­
50W­
A
Norosac:
Store
in
a
cool
dry
area
away
from
heat.
Provide
good
ventilation.
Keep
containers
tightly
closed.
Take
measures
not
to
raise
dust.
Wear
proper
PPE
when
handling
product.

Potassium
Ferricyanide
(KFe):
Store
in
a
cool
dry
area
away
from
heat.
Provide
good
ventilation.
Keep
container
tightly
closed
and
in
an
upright
condition.
Take
measures
not
to
raise
dust.
Wear
proper
PPE
when
handling
product.

General:
Maintain
first
aid
kit,
gloves,
respirators,
aprons,
and
cleanup
equipment
in
the
storage
area
at
all
times.
Emergency
spill
response
kit
should
also
be
readily
available.
Foam,
carbon
dioxide,
or
dry
chemical
fire
extinguishers
should
be
easily
accessible.
Provide
eyewash,
shower,
and
a
source
of
water
in
the
storage
area.

26
Disposal
of
Product
AV­
105
Ethylene
Glycol:
Whatever
cannot
be
saved
for
recovery
or
recycling
should
be
handled
in
an
appropriate
RCRA­
approved
waste
disposal
facility.
If
the
container
is
rinsed
out
properly
it
may
be
disposed
of
in
an
approved
landfill.
Processing,
use,
or
contamination
of
this
product
may
change
the
waste
management
options.
State
and
local
disposal
regulations
may
differ
from
federal
disposal
regulations.
Pails
or
drums
must
not
be
reused
for
any
other
purpose.
If
you
are
uncertain
about
how
to
properly
dispose
of
the
product
or
containers,
contact
a
state
registered
hazardous
materials
disposal
facility
or
an
appropriate
consultant.
State
or
local
waste
agencies
can
also
be
helpful.
Dispose
of
container
and
unused
contents
in
accordance
with
federal,
state,
and
local
requirements.

AV­
257
Icoset:
Whatever
cannot
be
saved
for
recovery
or
recycling
should
be
handled
in
an
appropriate
RCRA­
approved
disposal
facility.
If
the
container
is
rinsed
out
properly
it
may
be
disposed
of
in
an
approved
landfill.
State
and
local
disposal
regulations
may
differ
from
federal
disposal
regulations.
Dispose
of
container
and
unused
contents
in
accordance
with
federal,
state
and
local
requirements.

AC­
SOW­
A
Norosac:
Whatever
cannot
be
saved
for
recovery
or
recycling
should
be
handled
in
an
appropriate
RCRA­
approved
waste
disposal
facility.
Take
measures
not
to
raise
dust.
Processing,
use,
or
contamination
of
this
product
may
change
the
waste
management
options.
State
and
local
disposal
regulations
may
differ
from
federal
disposal
regulations.
Dispose
of
container
and
unused
contents
in
accordance
with
federal,
state
and
local
requirements.

Potassium
Ferricyanide
(KFe):
Whatever
cannot
be
saved
for
recovery
or
recycling
should
be
handled
as
hazardous
waste
and
sent
to
a
RCRA­
approved
waste
facility.
Take
measures
not
to
raise
dust.
Processing,
use,
or
contamination
of
this
product
may
change
the
waste
management
options.
State
and
local
disposal
regulations
may
differ
from
federal
disposal
regulations.
Dispose
of
container
and
unused
contents
in
accordance
with
federal,
state
and
local
requirements.

Safety
Information,
Hazards
and
First
Aid
Consult
Material
Safety
Data
Sheets
(MSDS).

Shipping
Information
See
Page
35.
0
Chemical
Grout
Safe
Handling
&
Mixing
Program
Date:

How
would
you
rate
the
material
presented
in
this
class?
(1
being
the
lowest,
5
being
the
highest)
1
2
3
4
5
How
would
you
rate
the
instructor?
1
2
3
4
5
Would
you
recommend
this
class
to
someone
else?
Yes
No
What
information
was
the
most
valuable
to
you?

What
information
was
the
least
valuable?

If
there
was
material
that
should
have
been
covered
today
that
wasn't,
what
was
it?

Do
you
have
any
suggestions
for
improving
this
class?

Other
Comments:
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