Document ID: EPA-HQ-OPP-2004-0167-0012
Agency: epa
Document Type: Supporting & Related Material
Title: 
Posted Date: 2004-05-20T04:00Z

2,4­
D
Case
0073
Reregistration
Eligibility
Decision:
Product
Chemistry
Considerations
(
DP
Barcode
D287660)

July
8,
2003
Contract
No.
68­
D4­
0010
Submitted
to:
U.
S.
Environmental
Protection
Agency
Arlington,
VA
Submitted
by:
Dynamac
Corporation
20440
Century
Boulevard,
Suite
100
Germantown,
MD
20874
O
Cl
Cl
OH
O
O
Cl
Cl
O
O
Na+

O
Cl
Cl
O
O­[
NH
2(
CH
2
CH
2
OH)
2]+
O
Cl
Cl
O
O­[
NH
2(
CH
2)
2]+
2,4­
D
REREGISTRATION
ELIGIBILITY
DECISION:

PRODUCT
CHEMISTRY
CONSIDERATIONS
(
DP
BARCODE
D287660)

Case
No.
0073
DESCRIPTION
OF
CHEMICAL
2,4­
D
(
2,4­
dichlorophenoxy
acetic
acid)
is
an
herbicide,
a
plant
growth
regulator,
and
a
fungicide.
It
is
mainly
used
as
a
selective
postemergence
herbicide
for
the
control
of
certain
weed
species
on
a
variety
of
food/
feed
sites
including
field,
fruit,
and
vegetable
crops.

Chemical
structures
and
information
are
presented
below
for
2,4­
D
acid
and
those
salts
and
esters
with
registered
manufacturing­
use
and/
or
end­
use
products
(
MPs/
EPs)
being
supported
by
2,4­
D
Task
Force
II.
A
list
of
salt
and
ester
active
ingredients
which
have
been
canceled
or
which
are
not
being
supported
for
reregistration
follows.

2,4­
D
active
ingredients
with
registered
MPs/
EPs
2,4­
D
acid
Empirical
Formula:
C8H6Cl2O3
Molecular
Weight:
221.0
CAS
Registry
No.:
94­
75­
7
PC
Code:
030001
2,4­
D
sodium
salt
(
Na)
Empirical
Formula:
C8H5Cl2NaO3
Molecular
Weight:
243.03
CAS
Registry
No.:
2702­
72­
9
PC
Code:
030004
2,4­
D
diethanolamine
salt
(
DEA)
Empirical
Formula:
C12H17Cl2NO5
Molecular
Weight:
326.18
CAS
Registry
No.:
5742­
19­
8
PC
Code:
030016
2,4­
D
dimethylamine
salt
(
DMA)
Empirical
Formula:
C10H13Cl2NO3
Molecular
Weight:
266.13
CAS
Registry
No.:
2008­
39­
1
PC
Code:
030019
2,4­
D
active
ingredients
with
registered
MPs/
EPs
2
O
Cl
Cl
O
O
CH
3
CH
3
O
Cl
Cl
O
O
NH+(
CH
2
CHOHCH
3)
3
O
Cl
Cl
O
O
O
CH
3
Cl
Cl
O
O
CH
3
O
CH
3
Cl
Cl
O
O
O
­
[
NH
3
CH(
CH
3)
2]+
2,4­
D
isopropylamine
salt
(
IPA)
Empirical
Formula:
C11H15Cl2NO3
Molecular
Weight:
280.04
CAS
Registry
No.:
5742­
17­
6
PC
Code:
030025
2,4­
D
triisopropanolamine
salt
(
TIPA)
Empirical
Formula:
C17H27Cl2NO6
Molecular
Weight:
412.31
CAS
Registry
No.:
32341­
80­
3
PC
Code:
030035
2,4­
D
2­
butoxyethyl
ester
(
BEE)
Empirical
Formula:
C14H18Cl2O4
Molecular
Weight:
321.20
CAS
Registry
No.:
1929­
73­
3
PC
Code:
030053
2,4­
D
2­
ethylhexyl
ester
(
2­
EHE)
1
Empirical
Formula:
C16H22Cl2O3
Molecular
Weight:
333.27
CAS
Registry
No.:
1928­
43­
4
PC
Code:
030063
2,4­
D
isopropyl
ester
(
IPE)
Empirical
Formula:
C11H12Cl2O3
Molecular
Weight:
263.12
CAS
Registry
No.:
94­
11­
1
PC
Code:
030066
1
Formerly
identified
as
the
isooctyl
ester.
3
2,4­
D
active
ingredients
that
are
canceled
or
not
supported
for
reregistration
1:
Active
ingredient
(
PC
Code)

lithium
salt
(
030002)
ammonium
salt
(
030005)
alkanolamine
salt
of
the
ethanol
and
isopropanol
(
030010)

alkylamine
(
C12)
salt
(
030011)
alkylamine
(
C14)
salt
(
030013)
alkylamine
salt,
derived
from
tall
oil
(
030014)

diethylamine
salt
(
030017)
N,
N­
dimethyloleylamine
salt
(
030020)
ethanolamine
salt
(
030021)

heptylamine
salt
(
030023)
isopropanolamine
salt
(
030024)
morpholine
salt
(
030028)

N­
oleyl­
1,3­
propylenediamine
salt
(
030029)
octylamine
salt
(
030030)
triethanolamine
salt
(
030033)

triethylamine
salt
(
030034)
N,
N­
dimethyloleyl­
linoleylamine
salt
(
030039)
butoxyethoxypropyl
ester
(
030052)

butoxypropyl
ester
(
030055)
butyl
ester
(
030056)
isobutyl
ester
(
030062)

isooctyl
(
2­
ethyl­
4­
methylpentyl)
ester
(
030064)
isooctyl
(
2­
octyl)
ester
(
030065)
propylene
glycol
butyl
ether
ester
(
030072)

1
Source:
Status
of
Pesticide
in
Registration,
Reregistration,
and
Special
Review
(
Rainbow
Report;
1998).
The
lithium
salt
is
listed
as
unsupported
for
reregistration;
remaining
active
ingredients
have
been
canceled.

IDENTIFICATION
OF
ACTIVE
INGREDIENT
Available
data
concerning
identification
of
the
active
ingredient
are
summarized
in
Table
1
for
2,4­
D
acid,
salts,
and
esters
with
registered
MPs/
EPs.
4
(
continued;
footnotes
follow)

Table
1.
Available
data
concerning
identification
of
the
active
ingredient.
1
Active
ingredient
(
PC
Code)
Color
Physical
State
Melting
Point/

Boiling
Point
Density/
Specific
Gravity
Octanol/
Water
Partition
Coeff.
Vapor
Pressure
Solubility
2,4­
D
acid
(
030001)
white
crystalline
solid
m.
p.
138­
141
C
s.
g.=
1.416
at
25
C
Log
KO/
W
0.001
M
sol'n
pH
5
2.14
pH
7
0.177
pH
9
0.102
1.4
x
10­
7
mm
Hg
at
25
C
water
=
569
mg/
L
at
20
C
g/
100
g
at
25
C
acetone
=
85.0
benzene
=
1.07
diethyl
ether
=
220
ethanol
=
130.0
isopropanol
=
31.6
toluene
=
0.067
xylene
=
0.58
2,4­
D
Na
salt
(
030004)
white
powder
m.
p.
200
C
bulk
=
42.2
lb/
ft3
at
25
C
N/
A
2;
salt
dissociates
to
acid
in
water
water
=
4.5
g/
100
mL
at
25
C
2,4­
D
DEA
salt
(
030016)
cream
powder
m.
p.
83
C
bulk
=
0.762
g/
cm3
at
25
C
2.24
x
10­
2
at
25
C
<
1.33
x
10­
5
Pa
at
25
C
mg/
g
at
25
C
water
=
806
acetonitrile
=
47
ethanol
=
280
n­
octanol
=
36
2,4­
D
DMA
salt
(
030019)
amber
aqueous
liquid
m.
p.
118­
120
C
(
PAI)
s.
g.
=
1.23
at
20
C
N/
A;
salt
dissociates
to
acid
in
water
<
1
x
10­
7
mm
Hg
at
26
C
g/
100
mL
at
20
C
water
=
72.9
(
pH
7)

acetonitrile
=
1.06
hexane
=
3.59
methanol
=
>
50
g/
100
g
n­
octanol
=
5.41
toluene
=
0.165
Table
1
(
continued)

Active
ingredient
(
PC
Code)
Color
Physical
State
Melting
Point/

Boiling
Point
Density/
Specific
Gravity
Octanol/
Water
Partition
Coeff.
Vapor
Pressure
Solubility
5
(
continued;
footnotes
follow)

2,4­
D
IPA
salt
(
030025)
amber
aqueous
liquid
m.
p.
121
C
(
PAI)
s.
g.
=
1.15
at
20
C
N/
A;
salt
dissociates
to
acid
in
water
g/
100
mL
at
20
C
water
=
17.4
(
pH
5.3)

acetonitrile
=
2.16
hexane
=
0.00436
methanol
=
>
50
g/
100
g
n­
octanol
=
3.11
toluene
=
0.336
2,4­
D
TIPA
salt
(
030035)
amber
aqueous
liquid
m.
p.
87­
110
C
(
PAI)
s.
g.
=
1.21
at
20
C
N/
A;
salt
dissociates
to
acid
in
water
g/
100
mL
at
20
C
water
=
46.1
(
pH
7)

acetonitrile
=
12.3
Isopropanol
=
14.4
Acetone
=
11.7
methanol
=
>
50
g/
100
g
n­
octanol
=
7.6
toluene
=
0.6
2,4­
D
BEE
(
030053)
dark
amber
liquid
b.
p.
89
C
s.
g.
=
1.225
at
20
C
log
=
4.13­
4.17
at
25
C
2.4
x
10­
6
mm
Hg
at
25
C
g/
100
mL
at
20
C
water
=
insoluble
acetone
=
>
53.6
acetonitrile
=
>
48.6
hexane
=
>
46.3
methanol
=
>
49.6
2,4­
D
2­
EHE
(
030063)
dark
amber
liquid
b.
p.
300
C
s.
g.
=
1.152
at
20
C
log
=
5.78
(
temp
N/
A)
3.6
x
10­
6
mm
Hg
(
temp
N/
A)
water
=
86.7
ppb
g/
100
mL
at
20
C
acetone
=
>
54.0
acetonitrile
=
>
49.1
hexane
=
>
45.7
methanol
=
>
52.3
Table
1
(
continued)

Active
ingredient
(
PC
Code)
Color
Physical
State
Melting
Point/

Boiling
Point
Density/
Specific
Gravity
Octanol/
Water
Partition
Coeff.
Vapor
Pressure
Solubility
6
2,4­
D
IPE
(
030066)
pale
amber
liquid
b.
p.
240
C
s.
g.
=
1.252
at
25
C
253.8
±
44.4
(
temp
N/
A)
5.3
x
10­
6
mbar
water
=
0.023
g/
100
mL
fully
miscible
in
dichloromethane,
hexane,

isopropanol,
and
toluene
1
Data
assembled
from
Agency
memoranda
and
comprehensive
review
documents
referenced
herein,
including
the
2,4­
D
Reregistration
Standard.

2
N/
A
=
Not
available.
7
MANUFACTURING­
USE
PRODUCTS
A
search
of
the
Reference
Files
System
(
REFS)
conducted
3/
13/
03
identified
50
2,4­
D
MPs
registered
under
PC
Codes
030001
(
acid),
030004
(
Na
salt),
030019
(
DMA
salt),
030025
(
IPA
salt),
030035
(
TIPA
salt),
030053
(
BEE),
030063
(
2­
EHE),
and
030066
(
IPE).
In
addition,
REFS
lists
three
EPs
under
PC
Code
030016,
which
are
apparently
produced
from
unregistered
TGAIs.
The
030016
TGAIs
are
subject
to
a
reregistration
eligibility
decision
in
support
of
reregistration
of
the
diethanolamine
salt.
A
list
of
the
registered
MPs
subject
to
a
reregistration
eligibility
decision
is
presented
in
Table
2.
8
Table
2.
Registered
manufacturing­
use
products
of
2,4­
D
(
Case
0073).

Product
1
EPA
Reg.
No.
Registrant
2
Comments/
Transfers
2,4­
D
acid
(
030001)

97%
acid
T
(
r)
228­
361
NuFarm
Americas,
Inc.
Formerly
Riverdale
Chemical
Company
95%
acid
T
(
r)
228­
360
95%
acid
T
(
r)
228­
314
98.2%
acid
T
2217­
455
37.6%
acid
FI
2217­
615
26.9%
acid
FI
2217­
621
11.6%
acid
FI
2217­
567
PBI/
Gordon
Corporation
10.956%
acid
FI
2217­
593
10%
acid
FI
2217­
508
1.7%
acid
T
5481­
144
Amvac
Chemical
Corporation
This
product
is
an
MAI
which
is
also
listed
under
2,4­
D
isopropyl
ester
(
030066)

as
the
95%
IPE
T;
data
requirements
are
specified
in
the
data
summary
table
for
the
95%
IPE
T.

98%
acid
T
(
r)
7969­
171
BASF
Corporation
To
be
transferred
to
NuFarm.

97%
acid
T
(
r)
7969­
174
99.3%
acid
T
(
r)
34704­
798
Platte
Chemical
Company,

Inc.

97%
acid
T
(
r)
34704­
797
95%
acid
T
35935­
7
NuFarm
Limited
Transferred
1/
25/
96
from
Agrolinz,
Inc.,
EPA
Reg.
No.
42545­
8.

97.9%
acid
T
46146­
3
Atanor
S.
A.
Transferred
3/
2/
00
from
R.
A.
M.
Research,
Inc.,
EPA
Reg.
No.
69474­
1;

transferred
11/
28/
95
from
Albaugh,
Inc.,
EPA
Reg.
No.
42750­
31;
transferred
3/
15/
94
from
A
H
Marks
and
Company,
Ltd.
(
EPA
Reg.
No.
15440­
15).
Table
2
(
continued)

Product
1
EPA
Reg.
No.
Registrant
2
Comments/
Transfers
9
97.9%
acid
T
(
r)
48273­
22
Marman
USA,
Inc.

95%
acid
T
61272­
5
NuFarm
USA,
Inc.
Transferred
5/
5/
89
from
Platte
Chemical
Company,
Inc.,
EPA
Reg.
No.
34704­

76.

95%
acid
T
61272­
3
Transferred
1/
25/
89
from
Farmland
Industries,
Inc.,
EPA
Reg.
No.
1990­
390.

97.9%
acid
T
61469­
2
Agro­
Gor
Corporation
Transferred
5/
17/
95
from
Agrolinz,
Inc.,
EPA
Reg.
No.
42545­
30;
transferred
11/
1/
83
from
Rhone­
Poulenc
Agrochemical
Division
(
EPA
Reg.
No.
359­
579).

97.9%
acid
T
61469­
1
Transferred
1/
13/
89
from
PBI/
Gordon
Corporation,
EPA
Reg.
No.
2217­
632.

97%
acid
T
62719­
25
Dow
AgroSciences
LLC
Formerly
Dow
Chemical
Company,
EPA
Reg.
No.
464­
454
(
12/
4/
89).

85%
acid
FI
(
r)
62719­
231
74.8%
acid
T
62719­
24
This
product
is
incorrectly
identified
as
a
formulation
intermediate
in
REFS.

Formerly
Dow
Chemical
Company,
EPA
Reg.
No.
464­
453
(
12/
4/
89).

99.3%
acid
T
72868­
1
BASF
Aktiengesellschaft
Agricultural
Center
Transferred
11/
10/
99
from
Rhone­
Poulenc
AG
Co.,
EPA
Reg.
No.
264­
492;

transferred
4/
25/
88
from
Rhone­
Poulenc
Agrochemical
Division,
EPA
Reg.
No.

359­
734;
transferred
11/
13/
86
from
Maxus
Agri
Chem'l
(
EPA
Reg.
No.

39335­
30).
To
be
transferred
to
NuFarm.

98.2%
acid
T
(
r)
73754­
1
GroWell
Limited
2,4­
D
sodium
salt
(
030004)

90.6%
Na
T
228­
123
NuFarm
Americas,
Inc.
Formerly
Riverdale
Chemical
Company.

90.6%
Na
T
(
r)
35935­
19
NuFarm
Limited
Transferred
9/
4/
96
from
Riverdale
Chemical
Company,
EPA
Reg.
No.
228­
319.

2,4­
D
diethanolamine
salt
(
030016)

No
registered
manufacturing­
use
products;
however,
data
are
required
for
the
practical
equivalent
of
the
TGAI
to
support
three
end­
use
products.
Table
2
(
continued)

Product
1
EPA
Reg.
No.
Registrant
2
Comments/
Transfers
10
2,4­
D
dimethylamine
salt
(
030019)

66.3%
DMA
FI
228­
294
NuFarm
Americas,
Inc.
Formerly
Riverdale
Chemical
Company;
transferred
8/
22/
94
from
Helena
Chemical
Company,
EPA
Reg.
No.
5905­
509;
transferred
10/
2/
90
from
Setre
Chemical
Company,
EPA
Reg.
No.
38167­
25;
transferred
6/
30/
89
from
Inter­
Ag
Corporation,
EPA
Reg.
No.
57539­
24;
transferred
3/
20/
87
from
Vertac
Chemical
Corporation,
EPA
Reg.
No.
39511­
84.

31.8%
DMA
FI
239­
2485
The
Ortho
Business
Group
Formerly
Solaris
Group
of
Monsanto
Co.

66.57%
DMA
FI
2217­
665
PBI/
Gordon
Corporation
46.4%
DMA
FI
2217­
654
61.37%
DMA
FI
35935­
11
NuFarm
Limited
Transferred
1/
25/
96
from
Agrolinz,
Inc.,
EPA
Reg.
No.
42545­
36;
transferred
11/
1/
83
from
Rhone­
Poulenc
Agrochemical
Division,
EPA
Reg.
No.
359­
673.

66.18%
DMA
FI
61272­
8
NuFarm
USA,
Inc.
Transferred
5/
5/
89
from
Platte
Chemical
Company,
Inc.,
EPA
Reg.
No.
34704­

83.

67.1%
DMA
FI
62719­
27
Dow
AgroSciences
LLC
Formerly
Dow
Chemical
Company,
EPA
Reg.
No.
464­
467
(
12/
4/
89).

66.8%
DMA
FI
62719­
52
Formerly
Dow
Chemical
Company,
EPA
Reg.
No.
464­
568
(
12/
4/
89).

2,4­
D
isopropylamine
salt
(
030025)

49.9%
IPA
T
62719­
71
Dow
AgroSciences
LLC
This
product
is
incorrectly
identified
as
an
FI
in
REFS.

Formerly
Dow
Chemical
Company,
EPA
Reg.
No.
464­
596
(
12/
4/
89).

2,4­
D
triisopropanolamine
salt
(
030035)

71%
TIPA
FI
62719­
180
Dow
AgroSciences
LLC
2,4­
D
2­
butoxyethyl
ester
(
030053)

94%
BEE
T
228­
136
NuFarm
Americas,
Inc.
Formerly
Riverdale
Chemical
Company
Table
2
(
continued)

Product
1
EPA
Reg.
No.
Registrant
2
Comments/
Transfers
11
94.5%
BEE
T
62719­
33
Dow
AgroSciences
LLC
Formerly
Dow
Chemical
Company,
EPA
Reg.
No.
464­
518
(
12/
4/
89).

2,4­
D
2­
ethylhexyl
ester
(
030063)

93.3%
2­
EHE
T
2217­
706
PBI/
Gordon
Corporation
Transferred
12/
6/
83
from
Falls
Chemical,
Inc.,
EPA
Reg.
No.
40831­
119.

94%
2­
EHE
T
35935­
12
NuFarm
Limited
Transferred
1/
25/
96
from
Agrolinz,
Inc.,
EPA
Reg.
No.
42545­
40;
transferred
12/
12/
83
from
Rhone­
Poulenc
Agrochemical
Division,
EPA
Reg.
No.
359­
577.

93.3%
2­
EHE
T
46146­
5
Atanor
S.
A.
This
product
is
incorrectly
identified
as
an
FI
in
REFS.

Transferred
3/
9/
00
from
R.
A.
M.
Research
Inc.,
EPA
Reg.
No.
69474­
3;

transferred
12/
23/
99
from
PBI/
Gordon
Corp.,
EPA
Reg.
No.
2217­
804;

transferred
12/
13/
95
from
Albaugh,
Inc.,
EPA
Reg.
No.
42750­
35;
transferred
5/
18/
95
from
Helena
Chemical
Company,
EPA
Reg.
No.
5905­
500;
transferred
10/
2/
90
from
Setre
Chemical
Company,
EPA
Reg.
No.
38167­
16;
transferred
6/
30/
89
from
Inter­
Ag
Corporation,
EPA
Reg.
No.
57539­
6;
transferred
3/
20/
87
from
Vertac
Chemical
Corporation,
EPA
Reg.
No.
39511­
62.

93.3
2­
EHE
T
46146­
4
This
product
is
incorrectly
identified
as
an
FI
in
REFS.

Transferred
3/
2/
00
from
R.
A.
M.
Research,
Inc.,
EPA
Reg.
No.
69474­
2;

transferred
11/
28/
95
from
Albaugh,
Inc.,
EPA
Reg.
No.
42750­
9;
transferred
11/
17/
87
from
GB
Biosciences
Corporation,
EPA
Reg.
No.
50534­
130;

transferred
5/
8/
84
from
Occidental
Chemical
Corporation,
EPA
Reg.
No.
677­

255.

98%
2­
EHE
T
61272­
1
NuFarm
USA,
Inc.
Transferred
1/
25/
89
from
Farmland
Industries,
Inc.,
EPA
Reg.
No.
1990­
338.

95%
2­
EHE
T
61272­
7
Transferred
5/
5/
89
from
Platte
Chemical
Company,
Inc.,
EPA
Reg.
No.
34704­

81.

95.4%
2­
EHE
T
62719­
26
Dow
AgroSciences
LLC
Formerly
Dow
Chemical
Company,
EPA
Reg.
No.
464­
458
(
12/
4/
89).

93.3%
2­
EHE
T
(
r)
73754­
2
GroWell
Limited
Table
2
(
continued)

Product
1
EPA
Reg.
No.
Registrant
2
Comments/
Transfers
12
2,4­
D
isopropyl
ester
(
030066)

95%
IPE
T
5481­
144
Amvac
Chemical
Corporation
94%
IPE
FI
35935­
13
NuFarm
Limited
Transferred
1/
25/
96
from
Agrolinz,
Inc.,
EPA
Reg.
No.
42545­
50.

1
(
r)
=
Repackaged
product.

2
Dow
AgroSciences
LLC,
Agro­
Gor
Corporation
[
PBI/
Gordon
and
Atanor
S.
A.],
and
NuFarm
USA,
Inc.
are
the
current
members
of
the
Industry
Task
Force
II
on
2,4­
D
Research
Data
(
TF­
II).
13
REGULATORY
BACKGROUND
The
Product
Chemistry
Chapter
of
the
2,4­
D
Reregistration
Standard
dated
2/
16/
88
and
subsequent
Guidance
Document
dated
9/
88
required
that
updated
generic
and
product­
specific
product
chemistry
data
be
submitted
for
2,4­
D
acid
and
each
salt,
ester,
and
amine
derivative.
In
addition,
a
Data
Call­
In
(
DCI)
dated
6/
15/
87
required
analytical
chemistry
data
for
polyhalogenated
dibenzo­
p­
dioxin/
dibenzofuran
(
PHDD/
PHDF)
contaminants
in
2,4­
D
and
its
salts
and
esters.

The
current
status
of
the
product
chemistry
data
requirements
for
the
2,4­
D
acid,
salt,
and
ester
TGAIs/
MPs
is
presented
in
the
attached
data
summary
tables.
Refer
to
these
tables
for
a
listing
of
the
outstanding
product
chemistry
data
requirements.
These
requirements
pertain
to
each
product's
respective
registrant
and
not
the
Task
Force
II
as
a
whole.

We
note
that
data
submitted
by
A
H
Marks
for
an
as­
yet
unregistered
BASF
Corporation
97.5%
2­
EHE
T
(
2001;
MRIDs
45377501­
45377506)
are
not
presented
herein
because
these
are
newproduct
registration
data
and
do
not
pertain
to
the
reregistration
of
2,4­
D.

CONCLUSIONS
The
outstanding
product
chemistry
data
requirements
for
the
2,4­
D
acid,
salt,
and
ester
products
are
summarized
in
Table
3,
and
are
detailed
in
the
attached
data
summary
table.
Provided
that
the
registrants
submit
the
data
required
in
the
attached
data
summary
tables
for
their
T/
TGAI
and
FI
products,
and
either
certify
that
the
suppliers
of
beginning
materials
and
the
manufacturing
processes
for
the
2,4­
D
manufacturing­
use
products
have
not
changed
since
the
last
comprehensive
product
chemistry
reviews
or
submit
complete
updated
product
chemistry
data
packages,
HED
has
no
objections
to
the
reregistration
of
2,4­
D
and
its
salts
and
esters
with
respect
to
product
chemistry
data
requirements.
14
Table
3.
Remaining
Product
Chemistry
Data
Requirements
for
2,4­
D
acid,
salt,
and
ester
TGAIs/
MPs.

TGAI/
MP
1
EPA
Reg.
No.
Registrant
Outstanding
OPPTS
Guideline
Requirements
2
2,4­
D
acid
(
030001)

97%
acid
T
(
r)
228­
361
NuFarm
Americas,
Inc.
Repackaged
­
Data
requirements
will
be
satisfied
by
data
for
the
source
product
95%
acid
T
(
r)
228­
360
Repackaged
­
Data
requirements
will
be
satisfied
by
data
for
the
source
product
95%
acid
T
(
r)
228­
314
Repackaged
­
Data
requirements
will
be
satisfied
by
data
for
the
source
product
98.2%
acid
T
2217­
455
None
37.6%
acid
FI
2217­
615
830.1550,
1600,
1650,
1670,
1750,
1800,
6302,
6303,
6304,
6314,
6315,
6316,

6317,
6319,
6320,
7000,
7100,
7300
26.9%
acid
FI
2217­
621
11.6%
acid
FI
2217­
567
PBI/
Gordon
Corporation
10.956%
acid
FI
2217­
593
10%
acid
FI
2217­
508
1.7%
acid
T
5481­
144
Amvac
Chemical
Corporation
See
Amvac
94%
IPE
T
for
data
requirements.

98%
acid
T
(
r)
7969­
171
BASF
Corporation
Repackaged
­
Data
requirements
will
be
satisfied
by
data
for
the
source
product
97%
acid
T
(
r)
7969­
174
Repackaged
­
Data
requirements
will
be
satisfied
by
data
for
the
source
product
99.3%
acid
T
(
r)
34704­
798
Platte
Chemical
Company,
Inc.
Repackaged
­
Data
requirements
will
be
satisfied
by
data
for
the
source
product
97%
acid
T
34704­
797
Repackaged
­
Data
requirements
will
be
satisfied
by
data
for
the
source
product
95%
acid
T
35935­
7
NuFarm
Limited
830.1550,
1600,
1620,
1670,
1700,
1800,
6302,
6303,
6304,
6314,
6315,
6316,

6317,
6319,
6320,
7000,
7100,
7300
97.9%
acid
T
46146­
3
Atanor
S.
A.
830.6317,
7050
97.9%
acid
T
(
r)
48273­
22
Marman
USA,
Inc.
Repackaged
­
Data
requirements
will
be
satisfied
by
data
for
the
source
product;

however,
the
identity
of
the
source
product
must
be
confirmed.
Table
3
(
continued)

TGAI/
MP
1
EPA
Reg.
No.
Registrant
Outstanding
OPPTS
Guideline
Requirements
2
15
(
continued;
footnotes
follow)

95%
acid
T
61272­
5
NuFarm
USA,
Inc.
830.1700,
1750
95%
acid
T
61272­
3
97.9%
acid
T
61469­
2
Agro­
Gor
Corporation
830.1600,
1620,
1670,
1700,
1800,
6302,
6303,
6304,
6314,
6315,
6316,
6317,

6319,
6320,
7000,
7100,
7300
97.9%
acid
T
61469­
1
830.1620,
1670,
1700,
1800,
6302,
6303,
6304,
6314,
6315,
6316,
6317,
6319,

6320,
7000,
7100,
7300
97%
acid
T
62719­
25
Dow
AgroSciences
LLC
830.6314,
7300
85%
acid
FI
(
r)
62719­
231
Repackaged
­
Data
requirements
will
be
satisfied
by
data
for
the
source
product.

74.8%
acid
T
62719­
24
830.1700,
1750,
6317
99.3%
acid
T
72868­
1
BASF
Aktiengesellschaft
Agricultural
Center
830.6317,
6320
98.2%
acid
T
(
r)
73754­
1
GroWell
Limited
Repackaged
­
Data
requirements
will
be
satisfied
by
data
for
the
source
product
2,4­
D
sodium
salt
(
030004)

90.6%
Na
T
228­
123
NuFarm
Americas,
Inc.
830.6302,
6303,
6304,
6314,
7000,
7050,
7300,
7840
90.6%
Na
T
(
r)
35935­
19
NuFarm
Limited
Repackaged
­
Data
requirements
will
be
satisfied
by
data
for
the
source
product.

2,4­
D
diethanolamine
salt
(
030016)

DEA
TGAI
N/
A
PBI/
Gordon
Corporation
830.1700,
7050
2,4­
D
dimethylamine
salt
(
030019)

66.3%
DMA
FI
228­
294
NuFarm
Americas,
Inc.
830.1600,
1650,
1670,
1700,
1800,
6302,
6303,
6304,
6313,
6314,
6315,
6316,

6317,
6319,
6320,
7000,
7100,
7300
Table
3
(
continued)

TGAI/
MP
1
EPA
Reg.
No.
Registrant
Outstanding
OPPTS
Guideline
Requirements
2
16
(
continued;
footnotes
follow)

31.8%
DMA
FI
239­
2485
The
Ortho
Business
Group
830.1550,
1600,
1650,
1670,
1700,
1750,
1800,
6302,
6303,
6304,
6313,
6314,

6315,
6316,
6317,
6319,
6320,
7000,
7100,
7200,
7220,
7300,
7370,
7550,
7840,

7950
66.57%
DMA
FI
2217­
665
PBI/
Gordon
Corporation
830.1600,
1650,
1670,
1700,
1800,
6302,
6303,
6304,
6313,
6314,
6315,
6316,

6317,
6319,
6320,
7000,
7100,
7300
46.4%
DMA
FI
2217­
654
830.1600,
1650,
1670,
1700,
1800,
6302,
6303,
6304,
6313,
6314,
6315,
6316,

6317,
6319,
6320,
7000,
7100,
7300
61.37%
DMA
FI
35935­
11
NuFarm
Limited
830.1600,
1650,
1670,
1700,
1800,
6302,
6303,
6304,
6313,
6314,
6315,
6316,

6317,
6319,
6320,
7000,
7100,
7300
66.18%
DMA
FI
61272­
8
NuFarm
USA,
Inc.
830.1600,
1650,
1670,
1700,
1800,
6302,
6303,
6304,
6313,
6314,
6315,
6316,

6317,
6319,
6320,
7000,
7100,
7300
67.1%
DMA
FI
62719­
27
Dow
AgroSciences
LLC
830.1550,
1750,
7050
66.8%
DMA
FI
62719­
52
830.1600,
1650,
1670,
1700,
1800,
6302,
6303,
6304,
6313,
6314,
6315,
6316,

6319,
7000,
7100,
7300
2,4­
D
isopropylamine
salt
(
030025)

49.9%
IPA
T
62719­
71
Dow
AgroSciences
LLC
830.7050
2,4­
D
triisopropanolamine
salt
(
030035)

71%
TIPA
FI
62719­
180
Dow
AgroSciences
LLC
830.6313,
7050,
7840,
7950
2,4­
D
2­
butoxyethyl
ester
(
030053)

94%
BEE
T
228­
136
NuFarm
Americas,
Inc.
830.1550,
1600,
1620,
1670,
1700,
1750,
1800,
6302,
6303,
6304,
6314,
6315,

6316,
6317,
6319,
6320,
7000,
7050,
7100,
7300,
7370
94.5%
BEE
T
62719­
33
Dow
AgroSciences
LLC
830.1700,
7000,
7050,
7370
TGAI/
MP
1
EPA
Reg.
No.
Registrant
Outstanding
OPPTS
Guideline
Requirements
2
17
2,4­
D
2­
ethylhexyl
ester
(
030063)

93.3%
2­
EHE
T
2217­
706
PBI/
Gordon
Corporation
830.6314,
6315,
6316,
6317,
6319,
6320,
7050,
7100
94%
2­
EHE
T
35935­
12
NuFarm
Limited
830.1550,
1600,
1620,
1670,
1700,
1750,
1800,
6302,
6303,
6304,
6314,
6315,

6316,
6317,
6319,
6320,
7000,
7050,
7100,
7300
93.3%
2­
EHE
T
46146­
5
Atanor
S.
A.
Registration
currently
suspended;
any
further
processing
of
applications
is
on
hold
until
the
registrations
have
been
taken
out
of
suspension.

830.1550,
1600,
1620,
1670,
1700,
1750,
6313,
6314,
6315,
6316,
6317,
6319,

6320,
7050,
7100,
7370,
7840
93.3%
2­
EHE
T
46146­
4
98%
2­
EHE
T
61272­
1
NuFarm
USA,
Inc.
830.1600,
1620,
1670,
1700,
1750,
1800,
6302,
6303,
6304,
6314,
6315,
6316,

6317,
6319,
6320,
7000,
7050,
7100,
7300
95%
2­
EHE
T
61272­
7
830.1600,
1620,
1670,
1700,
1800,
6302,
6303,
6304,
6314,
6315,
6316,
6317,

6319,
6320,
7000,
7050,
7100,
7300
95.4%
2­
EHE
T
62719­
26
Dow
AgroSciences
LLC
830.1550,
1750,
6319,
7050
93.3%
2­
EHE
T(
r)
73754­
2
GroWell
Limited
Repackaged
­
Data
requirements
will
be
satisfied
by
data
for
the
source
product
2,4­
D
isopropyl
ester
(
030066)

95%
IPE
T
5481­
144
Amvac
Chemical
Corporation
830.7050
94%
IPE
FI
35935­
13
NuFarm
Limited
830.1700,
7050
1
(
r)
=
Repackaged
product.

2
Administrative
revisions
required
for
CSFs
(
e.
g.,
changes
to
update
registrant
or
Reg.
No.
or
corrections
to
nominal
concentrations
or
certified
limits)
were
not
identified
as
data
gaps
and
are
detailed
in
the
individual
data
summary
tables.
18
Case
No.
0073
Chemical
No.
030001
Case
Name:
2,4­
D
Registrant:
NuFarm
Americas,
Inc.
Product(
s):
97%
acid
T
(
EPA
Reg.
No.
228­
361)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
3
CSF
12/
2/
98
830.1600
Description
of
materials
used
to
produce
the
product
N/
A
830.1620
Description
of
production
process
N/
A
830.1670
Discussion
of
formation
of
impurities
N/
A
830.1700
Preliminary
analysis
N/
A
830.1750
Certified
limits
Y
3
CSF
12/
2/
98
830.1800
Enforcement
analytical
method
N/
A
830.6302
Color
N/
A
830.6303
Physical
state
N/
A
830.6304
Odor
N/
A
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
N/
A
830.6314
Oxidation/
reduction:
chemical
incompatibility
N/
A
830.6315
Flammability
N/
A
830.6316
Explodability
N/
A
830.6317
Storage
stability
N/
A
830.6319
Miscibility
N/
A
830.6320
Corrosion
characteristics
N/
A
830.7000
pH
N/
A
830.7050
UV/
Visible
absorption
N/
A
830.7100
Viscosity
N/
A
830.7200
Melting
point/
melting
range
N/
A
830.7220
Boiling
point/
boiling
range
N/
A
830.7300
Density/
relative
density/
bulk
density
N/
A
830.7370
Dissociation
constants
in
water
N/
A
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
N/
A
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
N/
A
830.7950
Vapor
pressure
N/
A
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
The
NuFarm
Americas
97%
T
is
repackaged
from
an
EPA­
registered
product;
all
product
chemistry
data
requirements
will
be
fulfilled
by
data
for
the
source
product.
2
The
CSF
was
obtained
from
the
product
jacket.
3
The
CSF
must
be
revised
to
reflect
the
current
registrant
name,
EPA
Reg.
No.,
and
the
nominal
concentration
and
certified
limits
of
the
active
ingredient
in
the
product,
based
on
the
actual
amount
of
active
ingredient
in
the
source
product.
19
Case
No.
0073
Chemical
No.
030001
Case
Name:
2,4­
D
Registrant:
NuFarm
Americas,
Inc.
Product(
s):
95%
acid
T
(
EPA
Reg.
No.
228­
360)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
3
CSF
11/
10/
98
830.1600
Description
of
materials
used
to
produce
the
product
N/
A
830.1620
Description
of
production
process
N/
A
830.1670
Discussion
of
formation
of
impurities
N/
A
830.1700
Preliminary
analysis
N/
A
830.1750
Certified
limits
Y
3
CSF
11/
10/
98
830.1800
Enforcement
analytical
method
N/
A
830.6302
Color
N/
A
830.6303
Physical
state
N/
A
830.6304
Odor
N/
A
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
N/
A
830.6314
Oxidation/
reduction:
chemical
incompatibility
N/
A
830.6315
Flammability
N/
A
830.6316
Explodability
N/
A
830.6317
Storage
stability
N/
A
830.6319
Miscibility
N/
A
830.6320
Corrosion
characteristics
N/
A
830.7000
pH
N/
A
830.7050
UV/
Visible
absorption
N/
A
830.7100
Viscosity
N/
A
830.7200
Melting
point/
melting
range
N/
A
830.7220
Boiling
point/
boiling
range
N/
A
830.7300
Density/
relative
density/
bulk
density
N/
A
830.7370
Dissociation
constants
in
water
N/
A
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
N/
A
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
N/
A
830.7950
Vapor
pressure
N/
A
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
This
product
is
repackaged
from
an
EPA­
registered
product;
all
product
chemistry
data
requirements
will
be
fulfilled
by
data
for
the
source
product.
2
The
CSF
was
obtained
from
the
product
jacket.
3
The
CSF
must
be
revised
to
reflect
the
current
registrant
name,
EPA
Reg.
No.,
and
the
nominal
concentration
and
certified
limits
of
the
active
ingredient
in
the
product,
based
on
the
actual
amount
of
active
ingredient
in
the
source
product.
20
Case
No.
0073
Chemical
No.
030001
Case
Name:
2,4­
D
Registrant:
NuFarm
Americas,
Inc.
Product(
s):
95%
acid
T
(
EPA
Reg.
No.
228­
314)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
CSF
4/
4/
96
830.1600
Description
of
materials
used
to
produce
the
product
N/
A
830.1620
Description
of
production
process
N/
A
830.1670
Discussion
of
formation
of
impurities
N/
A
830.1700
Preliminary
analysis
N/
A
830.1750
Certified
limits
Y
CSF
4/
4/
96
830.1800
Enforcement
analytical
method
N/
A
830.6302
Color
N/
A
830.6303
Physical
state
N/
A
830.6304
Odor
N/
A
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
N/
A
830.6314
Oxidation/
reduction:
chemical
incompatibility
N/
A
830.6315
Flammability
N/
A
830.6316
Explodability
N/
A
830.6317
Storage
stability
N/
A
830.6319
Miscibility
N/
A
830.6320
Corrosion
characteristics
N/
A
830.7000
pH
N/
A
830.7050
UV/
Visible
absorption
N/
A
830.7100
Viscosity
N/
A
830.7200
Melting
point/
melting
range
N/
A
830.7220
Boiling
point/
boiling
range
N/
A
830.7300
Density/
relative
density/
bulk
density
N/
A
830.7370
Dissociation
constants
in
water
N/
A
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
N/
A
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
N/
A
830.7950
Vapor
pressure
N/
A
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
This
product
is
repackaged
from
an
EPA­
registered
product;
all
product
chemistry
data
requirements
will
be
fulfilled
by
data
for
the
source
product.
2
The
CSF
was
obtained
from
the
product
jacket.
21
Case
No.
0073
Chemical
No.
030001
Case
Name:
2,4­
D
Registrant:
PBI/
Gordon
Corporation
Product(
s):
98.2%
acid
T
(
EPA
Reg.
No.
2217­
455)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
41219701
3,
41223801,
41926201
4,
Letter
5/
12/
92
5,
Letter
12/
3/
92
6,
CSF
10/
11/
96
(
Alt.
1)
7,
44547901
8,
CSF
9/
23/
99
(
Alt.
2)
9
CSF
9/
23/
99
(
Alt.
3)
10
830.1600
Description
of
materials
used
to
produce
the
product
Y
41223801,
41637501
11,
41790601
12,
44149301
7,
44547901
8
830.1620
Description
of
production
process
Y
41223801,
41790601
12,
44149301
7,
44547901
8
830.1670
Discussion
of
formation
of
impurities
Y
41223801,
41790601
12,
44149301
7,
44547901
8
830.1700
Preliminary
analysis
Y
41219701
3,
41926201
4,
41790602
13,
44149302
7,
44543502
8,
44543503
8,
44932701
9
830.1750
Certified
limits
Y
41219701
3,
41223801,
41926201
4,
Letter
5/
12/
92
5,
Letter
12/
3/
92
6,
CSF
10/
11/
96
(
Alt.
1)
7,
CSF
9/
23/
99
(
Alt.
2)
9
CSF
9/
23/
99
(
Alt.
3)
10
830.1800
Enforcement
analytical
method
Y
41219701
3,
41223801,
41637501
11,
41926201
4
44543502
8,
44543503
8
830.6302
Color
Y
41223801,
44543504
8
830.6303
Physical
state
Y
41223801,
44543504
8
830.6304
Odor
Y
41223801,
44543504
8
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
Y
41223801,
41745301
11,
42023601
14,
44543504
8
830.6314
Oxidation/
reduction:
chemical
incompatibility
Y
42023601
14,
Letter
12/
3/
92
6
830.6315
Flammability
N/
A
15
830.6316
Explodability
Y
41745302
11
830.6317
Storage
stability
Y
41745301
11,
41926203
4
830.6319
Miscibility
N/
A
15
830.6320
Corrosion
characteristics
Y
42023601
14
830.7000
pH
Y
41926202
4,
44543504
8
830.7050
UV/
Visible
absorption
Y
44543504
8
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
22
830.7100
Viscosity
N/
A
15
830.7200
Melting
point/
melting
range
Y
41223801,
44543504
8
830.7220
Boiling
point/
boiling
range
N/
A
15
830.7300
Density/
relative
density/
bulk
density
Y
41223801,
44543504
8
830.7370
Dissociation
constants
in
water
Y
41223801,
41308901
16,
41972501
6,
44543504
8
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
Y
41332004
16,
44543504
8
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
Y
41223801,
42023601
14,
41332002
6,
44543504
8,
45692501
17
830.7950
Vapor
pressure
Y
41223801,
44543504
8
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
There
is
a
basic
and
two
alternate
formulations
of
the
PBI/
Gordon
98.2%
T;
the
two
alternate
formulations
have
similar
purity
and
impurity
profiles
of
the
basic
formulation
and
are
acceptable
as
alternate
formulations.
2
Bolded
references
were
reviewed
under
CB
No.
6393,
4/
3/
90,
G.
Makhijani
and
under
CB
No.
7138,
11/
16/
90,
S.
Funk
for
dioxins
(
GLNs
830.
1600,
1620,
and
1670);
and
all
other
references
were
reviewed
as
noted.
Italicized
references
reflect
TGAI
and/
or
PAI
data
for
phys/
chem
requirements
which
may
be
shared
by
Task
Force
members.
3
CB
No.
5763,
2/
15/
90,
F.
Griffith.
4
D167302,
9/
25/
91,
R.
Perfetti.
5
D180997,
8/
11/
92,
S.
Funk.
6
D186542
and
D190622,
6/
1/
93,
W.
Smith.
7
RD
Memorandum,
D231434,
12/
11/
96,
A.
Smith
for
Alternate
#
1.
8
RD
Memorandum,
D245940,
6/
9/
98,
S.
Mathur
for
Alternate
#
2.
9
RD
Memorandum,
D267474,
8/
9/
00,
B.
Kitchens.
10
CSF
obtained
from
the
product
jacket,
accepted
10/
19/
99.
11
D161036,
4/
30/
91,
R.
Perfetti.
12
D172810,
1/
28/
92,
S.
Funk.
13
D162524,
11/
26/
91,
S.
Funk.
14
D170803,
7/
16/
92,
E.
Zager.
15
Data
are
not
required
because
the
T/
TGAI
is
a
solid
at
room
temperature.
16
D169647,
6/
30/
92,
S.
Funk.
17
D283959,
3/
1/
04,
W.
Hazel
(
revised
water
solubility
data
for
the
Task
Force
PAI).
23
Case
No.
0073
Chemical
No.
030001
Case
Name:
2,4­
D
Registrant:
PBI/
Gordon
Corporation
Product(
s):
37.6%
acid
FI
(
EPA
Reg.
No.
2217­
615)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
N
3
CSF
8/
14/
98
830.1600
Description
of
materials
used
to
produce
the
product
N
830.1650
Description
of
formulation
process
N
830.1670
Discussion
of
formation
of
impurities
N
830.1700
Preliminary
analysis
N/
A
830.1750
Certified
limits
N
3
CSF
8/
14/
98
830.1800
Enforcement
analytical
method
N
830.6302
Color
N
830.6303
Physical
state
N
830.6304
Odor
N
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
N/
A
830.6314
Oxidation/
reduction:
chemical
incompatibility
N
830.6315
Flammability
N
830.6316
Explodability
N
830.6317
Storage
stability
N
830.6319
Miscibility
N
830.6320
Corrosion
characteristics
N
830.7000
pH
N
830.7050
UV/
Visible
absorption
N/
A
830.7100
Viscosity
N
830.7200
Melting
point/
melting
range
N/
A
830.7220
Boiling
point/
boiling
range
N/
A
830.7300
Density/
relative
density/
bulk
density
N
830.7370
Dissociation
constants
in
water
N/
A
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
N/
A
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
N/
A
830.7950
Vapor
pressure
N/
A
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
This
product
is
formulated
from
EPA­
registered
products;
TGAI/
PAI
data
requirements
will
be
satisfied
by
data
for
the
technical
source
products.
2
The
CSF
was
obtained
from
the
product
jacket
and
was
accepted
9/
10/
98
by
S.
Stanton.
3
Because
of
differing
active
ingredient
levels
in
the
listed
source
products,
basic
and
alternate
formulation
CSFs
are
required
for
this
product.
24
Case
No.
0073
Chemical
No.
030001
Case
Name:
2,4­
D
Registrant:
PBI/
Gordon
Corporation
Product(
s):
26.9%
acid
FI
(
EPA
Reg.
No.
2217­
621)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
N
3
CSF
8/
14/
98
830.1600
Description
of
materials
used
to
produce
the
product
N
830.1650
Description
of
formulation
process
N
830.1670
Discussion
of
formation
of
impurities
N
830.1700
Preliminary
analysis
N/
A
830.1750
Certified
limits
N
3
CSF
8/
14/
98
830.1800
Enforcement
analytical
method
N
830.6302
Color
N
830.6303
Physical
state
N
830.6304
Odor
N
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
N/
A
830.6314
Oxidation/
reduction:
chemical
incompatibility
N
830.6315
Flammability
N
830.6316
Explodability
N
830.6317
Storage
stability
N
830.6319
Miscibility
N
830.6320
Corrosion
characteristics
N
830.7000
pH
N
830.7050
UV/
Visible
absorption
N/
A
830.7100
Viscosity
N
830.7200
Melting
point/
melting
range
N/
A
830.7220
Boiling
point/
boiling
range
N/
A
830.7300
Density/
relative
density/
bulk
density
N
830.7370
Dissociation
constants
in
water
N/
A
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
N/
A
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
N/
A
830.7950
Vapor
pressure
N/
A
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
This
product
is
formulated
from
EPA­
registered
products;
TGAI/
PAI
data
requirements
will
be
satisfied
by
data
for
the
technical
source
products.
2
The
CSF
was
obtained
from
the
product
jacket
and
was
accepted
9/
11/
98
by
S.
Stanton.
3
Because
of
differing
active
ingredient
levels
in
the
listed
source
products,
basic
and
alternate
formulation
CSFs
are
required
for
this
product.
25
Case
No.
0073
Chemical
No.
030001
Case
Name:
2,4­
D
Registrant:
PBI/
Gordon
Corporation
Product(
s):
11.6%
acid
FI
(
EPA
Reg.
No.
2217­
567)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
N
3
CSF
7/
23/
98
830.1600
Description
of
materials
used
to
produce
the
product
N
830.1650
Description
of
formulation
process
N
830.1670
Discussion
of
formation
of
impurities
N
830.1700
Preliminary
analysis
N/
A
830.1750
Certified
limits
N
3
CSF
7/
23/
98
830.1800
Enforcement
analytical
method
N
830.6302
Color
N
830.6303
Physical
state
N
830.6304
Odor
N
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
N/
A
830.6314
Oxidation/
reduction:
chemical
incompatibility
N
830.6315
Flammability
N
830.6316
Explodability
N
830.6317
Storage
stability
N
830.6319
Miscibility
N
830.6320
Corrosion
characteristics
N
830.7000
pH
N
830.7050
UV/
Visible
absorption
N/
A
830.7100
Viscosity
N
830.7200
Melting
point/
melting
range
N/
A
830.7220
Boiling
point/
boiling
range
N/
A
830.7300
Density/
relative
density/
bulk
density
N
830.7370
Dissociation
constants
in
water
N/
A
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
N/
A
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
N/
A
830.7950
Vapor
pressure
N/
A
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
This
product
is
formulated
from
EPA­
registered
products;
TGAI/
PAI
data
requirements
will
be
satisfied
by
data
for
the
technical
source
products.
2
The
CSF
was
obtained
from
the
product
jacket
and
was
reviewed
under
RD
memorandum
D249891,
10/
19/
98,
S.
Malak.
3
Because
of
differing
active
ingredient
levels
in
the
listed
source
products,
basic
and
alternate
formulation
CSFs
are
required
for
this
product.
26
Case
No.
0073
Chemical
No.
030001
Case
Name:
2,4­
D
Registrant:
PBI/
Gordon
Corporation
Product(
s):
10.956%
acid
FI
(
EPA
Reg.
No.
2217­
593)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
N
3
CSF
8/
14/
98
830.1600
Description
of
materials
used
to
produce
the
product
N
830.1650
Description
of
formulation
process
N
830.1670
Discussion
of
formation
of
impurities
N
830.1700
Preliminary
analysis
N/
A
830.1750
Certified
limits
N
3
CSF
8/
14/
98
830.1800
Enforcement
analytical
method
N
830.6302
Color
N
830.6303
Physical
state
N
830.6304
Odor
N
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
N/
A
830.6314
Oxidation/
reduction:
chemical
incompatibility
N
830.6315
Flammability
N
830.6316
Explodability
N
830.6317
Storage
stability
N
830.6319
Miscibility
N
830.6320
Corrosion
characteristics
N
830.7000
pH
N
830.7050
UV/
Visible
absorption
N/
A
830.7100
Viscosity
N
830.7200
Melting
point/
melting
range
N/
A
830.7220
Boiling
point/
boiling
range
N/
A
830.7300
Density/
relative
density/
bulk
density
N
830.7370
Dissociation
constants
in
water
N/
A
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
N/
A
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
N/
A
830.7950
Vapor
pressure
N/
A
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
This
product
is
formulated
from
EPA­
registered
products;
TGAI/
PAI
data
requirements
will
be
satisfied
by
data
for
the
technical
source
products.
2
The
CSF
was
obtained
from
the
product
jacket
and
was
reviewed
under
RD
memorandum
D236698,
7/
29/
97,
B.
Kitchens.
3
Because
of
differing
active
ingredient
levels
in
the
listed
source
products,
basic
and
alternate
formulation
CSFs
are
required
for
this
product.
27
Case
No.
0073
Chemical
No.
030001
Case
Name:
2,4­
D
Registrant:
PBI/
Gordon
Corporation
Product(
s):
10%
acid
FI
(
EPA
Reg.
No.
2217­
508)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
N
3
CSF
5/
5/
97
830.1600
Description
of
materials
used
to
produce
the
product
N
830.1650
Description
of
formulation
process
N
830.1670
Discussion
of
formation
of
impurities
N
830.1700
Preliminary
analysis
N/
A
830.1750
Certified
limits
N
3
CSF
5/
5/
97
830.1800
Enforcement
analytical
method
N
830.6302
Color
N
830.6303
Physical
state
N
830.6304
Odor
N
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
N/
A
830.6314
Oxidation/
reduction:
chemical
incompatibility
N
830.6315
Flammability
N
830.6316
Explodability
N
830.6317
Storage
stability
N
830.6319
Miscibility
N
830.6320
Corrosion
characteristics
N
830.7000
pH
N
830.7050
UV/
Visible
absorption
N/
A
830.7100
Viscosity
N
830.7200
Melting
point/
melting
range
N/
A
830.7220
Boiling
point/
boiling
range
N/
A
830.7300
Density/
relative
density/
bulk
density
N
830.7370
Dissociation
constants
in
water
N/
A
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
N/
A
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
N/
A
830.7950
Vapor
pressure
N/
A
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
This
product
is
formulated
from
EPA­
registered
products;
TGAI/
PAI
data
requirements
will
be
satisfied
by
data
for
the
technical
source
products.
2
The
CSF
was
obtained
from
the
product
jacket
and
was
reviewed
under
RD
memorandum
D236701,
7/
29/
97,
B.
Kitchens.
3
Because
of
differing
active
ingredient
levels
in
the
listed
source
products,
basic
and
alternate
formulation
CSFs
are
required
for
this
product.
28
Case
No.
0073
Chemical
No.
030001
Case
Name:
2,4­
D
Registrant:
BASF
Corporation
Product(
s):
98%
acid
T
(
EPA
Reg.
No.
7969­
171)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
CSF
8/
19/
98
830.1600
Description
of
materials
used
to
produce
the
product
N/
A
830.1620
Description
of
production
process
N/
A
830.1670
Discussion
of
formation
of
impurities
N/
A
830.1700
Preliminary
analysis
N/
A
830.1750
Certified
limits
Y
CSF
8/
19/
98
830.1800
Enforcement
analytical
method
N/
A
830.6302
Color
N/
A
830.6303
Physical
state
N/
A
830.6304
Odor
N/
A
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
N/
A
830.6314
Oxidation/
reduction:
chemical
incompatibility
N/
A
830.6315
Flammability
N/
A
830.6316
Explodability
N/
A
830.6317
Storage
stability
N/
A
830.6319
Miscibility
N/
A
830.6320
Corrosion
characteristics
N/
A
830.7000
pH
N/
A
830.7050
UV/
Visible
absorption
N/
A
830.7100
Viscosity
N/
A
830.7200
Melting
point/
melting
range
N/
A
830.7220
Boiling
point/
boiling
range
N/
A
830.7300
Density/
relative
density/
bulk
density
N/
A
830.7370
Dissociation
constants
in
water
N/
A
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
N/
A
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
N/
A
830.7950
Vapor
pressure
N/
A
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
This
product
is
repackaged
from
the
alternate
source
of
another
EPAregistered
2,4­
D
acid
product;
all
product
chemistry
data
requirements
will
be
fulfilled
by
data
for
the
source
product.
2
The
CSF
was
obtained
from
the
product
jacket.
29
Case
No.
0073
Chemical
No.
030001
Case
Name:
2,4­
D
Registrant:
BASF
Corporation
Product(
s):
97%
acid
T
(
EPA
Reg.
No.
7969­
174)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
3
CSF
12/
20/
98
830.1600
Description
of
materials
used
to
produce
the
product
N/
A
830.1620
Description
of
production
process
N/
A
830.1670
Discussion
of
formation
of
impurities
N/
A
830.1700
Preliminary
analysis
N/
A
830.1750
Certified
limits
Y
3
CSF
12/
20/
98
830.1800
Enforcement
analytical
method
N/
A
830.6302
Color
N/
A
830.6303
Physical
state
N/
A
830.6304
Odor
N/
A
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
N/
A
830.6314
Oxidation/
reduction:
chemical
incompatibility
N/
A
830.6315
Flammability
N/
A
830.6316
Explodability
N/
A
830.6317
Storage
stability
N/
A
830.6319
Miscibility
N/
A
830.6320
Corrosion
characteristics
N/
A
830.7000
pH
N/
A
830.7050
UV/
Visible
absorption
N/
A
830.7100
Viscosity
N/
A
830.7200
Melting
point/
melting
range
N/
A
830.7220
Boiling
point/
boiling
range
N/
A
830.7300
Density/
relative
density/
bulk
density
N/
A
830.7370
Dissociation
constants
in
water
N/
A
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
N/
A
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
N/
A
830.7950
Vapor
pressure
N/
A
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
This
product
is
repackaged
from
an
EPA­
registered
product;
all
product
chemistry
data
requirements
will
be
fulfilled
by
data
for
the
source
product.
2
The
CSF
was
obtained
from
the
product
jacket.
3
The
CSF
must
be
revised
to
reflect
the
nominal
concentration
and
certified
limits
of
the
active
ingredient
in
the
product,
based
on
the
actual
amount
of
active
ingredient
in
the
source
product.
30
Case
No.
0073
Chemical
No.
030001
Case
Name:
2,4­
D
Registrant:
Platte
Chemical
Company,
Inc.
Product(
s):
99.3%
acid
T
(
EPA
Reg.
No.
34704­
798)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
3
CSF
2/
20/
97
830.1600
Description
of
materials
used
to
produce
the
product
N/
A
830.1620
Description
of
production
process
N/
A
830.1670
Discussion
of
formation
of
impurities
N/
A
830.1700
Preliminary
analysis
N/
A
830.1750
Certified
limits
Y
3
CSF
2/
20/
97
830.1800
Enforcement
analytical
method
N/
A
830.6302
Color
N/
A
830.6303
Physical
state
N/
A
830.6304
Odor
N/
A
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
N/
A
830.6314
Oxidation/
reduction:
chemical
incompatibility
N/
A
830.6315
Flammability
N/
A
830.6316
Explodability
N/
A
830.6317
Storage
stability
N/
A
830.6319
Miscibility
N/
A
830.6320
Corrosion
characteristics
N/
A
830.7000
pH
N/
A
830.7050
UV/
Visible
absorption
N/
A
830.7100
Viscosity
N/
A
830.7200
Melting
point/
melting
range
N/
A
830.7220
Boiling
point/
boiling
range
N/
A
830.7300
Density/
relative
density/
bulk
density
N/
A
830.7370
Dissociation
constants
in
water
N/
A
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
N/
A
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
N/
A
830.7950
Vapor
pressure
N/
A
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
This
product
is
repackaged
from
an
EPA­
registered
product;
all
product
chemistry
data
requirements
will
be
fulfilled
by
data
for
the
source
product.
2
The
CSF
was
obtained
from
the
product
jacket.
3
The
source
product
listed
on
the
CSF
has
been
transferred.
An
updated
CSF
must
be
submitted
reflecting
the
current
supplier
and
EPA
Reg.
No.
of
the
source
product.
31
Case
No.
0073
Chemical
No.
030001
Case
Name:
2,4­
D
Registrant:
Platte
Chemical
Company,
Inc.
Product(
s):
97%
acid
T
(
EPA
Reg.
No.
34704­
797)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
CSF
2/
20/
97
830.1600
Description
of
materials
used
to
produce
the
product
N/
A
830.1620
Description
of
production
process
N/
A
830.1670
Discussion
of
formation
of
impurities
N/
A
830.1700
Preliminary
analysis
N/
A
830.1750
Certified
limits
Y
CSF
2/
20/
97
830.1800
Enforcement
analytical
method
N/
A
830.6302
Color
N/
A
830.6303
Physical
state
N/
A
830.6304
Odor
N/
A
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
N/
A
830.6314
Oxidation/
reduction:
chemical
incompatibility
N/
A
830.6315
Flammability
N/
A
830.6316
Explodability
N/
A
830.6317
Storage
stability
N/
A
830.6319
Miscibility
N/
A
830.6320
Corrosion
characteristics
N/
A
830.7000
pH
N/
A
830.7050
UV/
Visible
absorption
N/
A
830.7100
Viscosity
N/
A
830.7200
Melting
point/
melting
range
N/
A
830.7220
Boiling
point/
boiling
range
N/
A
830.7300
Density/
relative
density/
bulk
density
N/
A
830.7370
Dissociation
constants
in
water
N/
A
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
N/
A
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
N/
A
830.7950
Vapor
pressure
N/
A
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
This
product
is
repackaged
from
an
EPA­
registered
product;
all
product
chemistry
data
requirements
will
be
fulfilled
by
data
for
the
source
product.
2
The
CSF
was
obtained
from
the
product
jacket.
32
Case
No.
0073
Chemical
No.
030001
Case
Name:
2,4­
D
Registrant:
NuFarm
Limited
Product(
s):
95%
acid
T
(
EPA
Reg.
No.
35935­
7)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
N
3
CSF
12/
20/
88
830.1600
Description
of
materials
used
to
produce
the
product
N
830.1620
Description
of
production
process
N
830.1670
Discussion
of
formation
of
impurities
N
830.1700
Preliminary
analysis
N
830.1750
Certified
limits
Y
CSF
12/
20/
88
830.1800
Enforcement
analytical
method
N
830.6302
Color
N
830.6303
Physical
state
N
830.6304
Odor
N
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
Y
41055803
4,
41855701
5,
42023601
6,
42795401
7
830.6314
Oxidation/
reduction:
chemical
incompatibility
N
830.6315
Flammability
N
830.6316
Explodability
N
830.6317
Storage
stability
N
830.6319
Miscibility
N
830.6320
Corrosion
characteristics
N
830.7000
pH
N
830.7050
UV/
Visible
absorption
Y
44543504
8
830.7100
Viscosity
N
830.7200
Melting
point/
melting
range
Y
41055803
4,
41067001
9,
41223801
10
830.7220
Boiling
point/
boiling
range
N/
A
11
830.7300
Density/
relative
density/
bulk
density
N
830.7370
Dissociation
constants
in
water
Y
41055803
4,
41067001
9,
41972501
12,
44543504
8
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
Y
41332004
13
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
Y
41055803
4,
45692501
14
830.7950
Vapor
pressure
Y
41055803
4,
41067001
9,
44543504
8
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
This
product
was
transferred
from
Agrolinz,
Inc.
(
EPA
Reg.
No.
42545­
8).
2
The
CSF
was
reviewed
under
RD
Memorandum
D177498,
5/
22/
92,
A.
Skapars;
and
all
other
references
were
reviewed
as
noted.
Italicized
references
reflect
TGAI
and/
or
PAI
data
for
phys/
chem
requirements
which
may
be
shared
by
Task
Force
members.
3
The
label
claim
is
not
in
agreement
with
the
nominal
concentration
of
the
active
ingredient;
a
revised
CSF
and/
or
label
must
be
submitted.
In
addition,
the
CSF
must
be
revised
to
reflect
the
current
registrant
and
EPA
Reg.
No.
33
4
CB
Nos.
5454,
5455,
5489,
5540,
5541,
5542,
5543,
and
5544,
10/
25/
89,
M.
Nelson
(
TGAI
data
for
the
Dow
AgroSciences
97%
acid
T,
EPA
Reg.
No.
62719­
25).
5
Letter
dated
12/
2/
91
from
L.
Rossi
(
SRRD)
to
K.
Shearer
of
Rhone­
Poulenc
(
TGAI
data
for
the
BASF
99.3%
acid
T,
EPA
Reg.
No.
72868­
1).
6
D170803,
7/
16/
92,
E.
Zager
(
TGAI
data
for
the
PBI/
Gordon
98.2%
acid
T,
EPA
Reg.
No.
2217­
455).
7
D192560,
8/
5/
93,
F.
Toghrol
(
TGAI
data
for
the
Dow
AgroSciences
97%
acid
T,
EPA
Reg.
No.
62719­
25).
8
RD
Memorandum,
D245940,
6/
9/
98,
S.
Mathur
(
PAI
data
for
the
PBI/
Gordon
98.2%
acid
T,
EPA
Reg.
No.
2217­
455).
9
CB
5549,
9/
26/
89,
M.
Nelson
(
TGAI
data
for
the
BASF
99.3%
acid
T,
EPA
Reg.
No.
72868­
1).
10
CB
6393,
4/
3/
90,
G.
Makhijani
(
TGAI
data
for
the
PBI/
Gordon
98.2%
acid
T,
EPA
Reg.
No.
2217­
455).
11
Data
are
not
required
because
the
TGAI
is
a
solid
at
room
temperature.
12
D186542
and
D190622,
6/
1/
93,
W.
Smith
(
PAI
data
for
the
PBI/
Gordon
98.2%
acid
T,
EPA
Reg.
No.
2217­
455).
13
CB
6581,
7/
27/
90,
G.
Makhijani
(
Task
Force
PAI
data).
14
D283959,
3/
1/
04,
W.
Hazel
(
revised
water
solubility
data
for
the
Task
Force
PAI).
34
Case
No.
0073
Chemical
No.
030001
Case
Name:
2,4­
D
Registrant:
Atanor
S.
A.
Product(
s):
97.9%
acid
T
(
EPA
Reg.
No.
46146­
3)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
43516401,
43516402,
43981801
3,
CSF
2/
16/
99
4
830.1600
Description
of
materials
used
to
produce
the
product
Y
43516401
5
830.1620
Description
of
production
process
Y
43516401
5
830.1670
Discussion
of
formation
of
impurities
Y
43516401
5
830.1700
Preliminary
analysis
Y
43516401,
43516402,
43981801
3,
Report
6
830.1750
Certified
limits
Y
43516401,
43516402,
43981801
3,
CSF
2/
16/
99
4
830.1800
Enforcement
analytical
method
Y
43516401,
43516402,
43981801
3,
Report
6
830.6302
Color
Y
43516403
5,
43516404
5
830.6303
Physical
state
Y
43516403
5,
43516404
5
830.6304
Odor
Y
43516403
5,
43516404
5
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
Y
43516403
5,
43516404
5
830.6314
Oxidation/
reduction:
chemical
incompatibility
Y
43516403
5,
43516404
5
830.6315
Flammability
N/
A
7
830.6316
Explodability
Y
43516403
5,
43516404
5
830.6317
Storage
stability
N
8
43516403
5,
43516404
5
830.6319
Miscibility
N/
A
7
830.6320
Corrosion
characteristics
Y
43516403
5,
43516404
5
830.7000
pH
Y
43516403
5,
43516404
5
830.7050
UV/
Visible
absorption
N
9
830.7100
Viscosity
N/
A
7
830.7200
Melting
point/
melting
range
Y
43516403
5,
43516404
5
830.7220
Boiling
point/
boiling
range
N/
A
7
830.7300
Density/
relative
density/
bulk
density
Y
43516403
5,
43516404
5
830.7370
Dissociation
constants
in
water
Y
43516403
5,
43516404
5
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
Y
43516403
5,
43516404
5
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
Y
43516403
5,
43516404
5
830.7950
Vapor
pressure
Y
43516403
5,
43516404
5
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
This
product
was
transferred
from
R.
A.
M.
Research,
Inc.
(
EPA
Reg.
No.
69474­
1);
based
on
the
CSFs,
the
producer
did
not
change
with
the
product
transfer.
2
Bolded
references
were
reviewed
under
D215421,
6/
8/
95,
S.
Funk
for
dioxins
and
under
Registration
Memorandum,
D211526,
2/
13/
95,
A.
Smith,
for
other
reregistration
requirements;
and
all
other
references
were
reviewed
as
noted.
35
3
D226030,
9/
9/
96,
S.
Funk.
4
Letter
dated
7/
23/
99
from
J.
Miller
(
Registration
Division)
to
E.
Finkel
(
R.
A.
M.
Research,
Inc.).
We
note
that
the
CSF
should
be
updated
to
reflect
the
current
registrant
name.
5
Registration
Memorandum,
D211526,
2/
13/
95,
A.
Smith.
6
D232535
and
D232688,
2/
20/
97,
S.
Funk.
7
Data
are
not
required
because
the
T/
TGAI
is
a
solid
at
room
temperature.
8
Although
storage
stability
data
were
determined
to
be
satisfied
under
the
RD
Memorandum,
data
are
required
demonstrating
the
stability
of
the
product
in
the
typical
container
for
one
year
at
ambient
conditions.
9
The
OPPTS
Series
830,
Product
Properties
Test
Guidelines
require
data
pertaining
to
UV/
visible
absorption
for
the
PAI.
36
Case
No.
0073
Chemical
No.
030001
Case
Name:
2,4­
D
Registrant:
Marman
USA,
Inc.
Product(
s):
97.9%
acid
T
(
EPA
Reg.
No.
48273­
22)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
3
CSF
9/
17/
96
830.1600
Description
of
materials
used
to
produce
the
product
N/
A
830.1620
Description
of
production
process
N/
A
830.1670
Discussion
of
formation
of
impurities
N/
A
830.1700
Preliminary
analysis
N/
A
830.1750
Certified
limits
Y
3
CSF
9/
17/
96
830.1800
Enforcement
analytical
method
N/
A
830.6302
Color
N/
A
830.6303
Physical
state
N/
A
830.6304
Odor
N/
A
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
N/
A
830.6314
Oxidation/
reduction:
chemical
incompatibility
N/
A
830.6315
Flammability
N/
A
830.6316
Explodability
N/
A
830.6317
Storage
stability
N/
A
830.6319
Miscibility
N/
A
830.6320
Corrosion
characteristics
N/
A
830.7000
pH
N/
A
830.7050
UV/
Visible
absorption
N/
A
830.7100
Viscosity
N/
A
830.7200
Melting
point/
melting
range
N/
A
830.7220
Boiling
point/
boiling
range
N/
A
830.7300
Density/
relative
density/
bulk
density
N/
A
830.7370
Dissociation
constants
in
water
N/
A
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
N/
A
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
N/
A
830.7950
Vapor
pressure
N/
A
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
This
product
is
repackaged
from
an
EPA­
registered
product;
all
product
chemistry
data
requirements
will
be
fulfilled
by
data
for
the
source
product,
provided
the
registrant
confirms
the
identity
of
the
source
product.
The
product
jacket
contains
a
letter
dated
7/
20/
98
from
the
Registration
Division
to
the
Policy
Enforcement
Branch
which
indicates
that
the
registrant
of
the
listed
source
product
has
stated
that
they
have
never
supplied
their
registered
product
to
Marman
USA.
The
identity
of
the
source
product
must
be
confirmed.
2
The
CSF
was
obtained
from
the
product
jacket.
3
The
CSF
must
be
revised
so
that
the
name
listed
in
Box
2
is
the
name
of
the
producer
of
the
source
product
and
not
the
registrant
of
the
repackaged
product.
37
Case
No.
0073
Chemical
No.
030001
Case
Name:
2,4­
D
Registrant:
NuFarm
USA,
Inc.
Product(
s):
95%
acid
Ts
(
EPA
Reg.
Nos.
61272­
3
and
61272­
5)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
40808301
830.1600
Description
of
materials
used
to
produce
the
product
Y
40808301
830.1620
Description
of
production
process
Y
40808301
830.1670
Discussion
of
formation
of
impurities
Y
40808301
830.1700
Preliminary
analysis
N
3
40808301,
41724201
4,
41724202
4,
41349001
5
830.1750
Certified
limits
N
6
40808301
830.1800
Enforcement
analytical
method
Y
40808301
830.6302
Color
Y
40808301
830.6303
Physical
state
Y
40808301
830.6304
Odor
Y
40808301
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
Y
40808301
830.6314
Oxidation/
reduction:
chemical
incompatibility
Y
40808301
830.6315
Flammability
N/
A
7
830.6316
Explodability
Y
40808301
830.6317
Storage
stability
Y
40808301
830.6319
Miscibility
N/
A
7
830.6320
Corrosion
characteristics
Y
40808301
830.7000
pH
Y
40808301
830.7050
UV/
Visible
absorption
Y
44543504
8
830.7100
Viscosity
N/
A
7
830.7200
Melting
point/
melting
range
Y
40808301
830.7220
Boiling
point/
boiling
range
N/
A
7
830.7300
Density/
relative
density/
bulk
density
Y
40808301
830.7370
Dissociation
constants
in
water
Y
40808301
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
Y
40808301
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
Y
40808301,
45692501
9
830.7950
Vapor
pressure
Y
40808301
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
Based
on
RD
Memoranda
dated
5/
12/
93,
L.
Markman
and
11/
7/
93,
I.
Blackwell,
these
products
are
identical;
the
submitted
data
are
applicable
to
both
products.
2
Bolded
references
were
reviewed
under
Registration
Division
Memorandum,
6/
5/
92,
A.
Smith
which
stated
"
the
referenced
MRID
satisfies
the
requirements
of
40
CFR
158.150­
158.190.
The
product
chemistry
requirements
are
satisfied
for
this
product."
No
data
were
presented
in
the
review.
All
other
references
were
reviewed
as
noted.
Italicized
references
reflect
TGAI
and/
or
PAI
data
for
phys/
chem
requirements
which
may
be
shared
by
Task
Force
members.
38
3
Additional
information
concerning
the
sampling
dates
and
method
are
required
concerning
the
preliminary
analysis
for
dioxins.
4
D160163,
11/
26/
91,
S.
Funk
for
dioxins.
5
CB
No.
6295,
5/
24/
90,
S.
Funk.
6
A
revised
CSF
must
be
submitted
to
incorporate
the
results
of
the
dioxin
analyses;
upper
certified
limits
must
be
proposed
for
those
dioxin
or
dibenzofuran
compounds
present
at
greater
than
the
respective
EPA
LOQs.
7
Data
are
not
required
because
the
T/
TGAI
is
a
solid
at
room
temperature.
8
RD
Memorandum,
D245940,
6/
9/
98,
S.
Mathur
(
PAI
data
for
the
PBI/
Gordon
98.2%
acid
T,
EPA
Reg.
No.
2217­
455).
9
D283959,
3/
1/
04,
W.
Hazel
(
revised
water
solubility
data
for
the
Task
Force
PAI).
39
Case
No.
0073
Chemical
No.
030001
Case
Name:
2,4­
D
Registrant:
Agro­
Gor
Corporation
Product(
s):
97.9%
acid
T
(
EPA
Reg.
No.
61469­
2)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
3
CSF
12/
15/
93
830.1600
Description
of
materials
used
to
produce
the
product
N
830.1620
Description
of
production
process
N
830.1670
Discussion
of
formation
of
impurities
N
830.1700
Preliminary
analysis
N
4
41796201
5,
41796202
5
830.1750
Certified
limits
Y
3
CSF
12/
15/
93
830.1800
Enforcement
analytical
method
N
830.6302
Color
N
830.6303
Physical
state
N
830.6304
Odor
N
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
Y
41055803
6,
41855701
7,
420236018,
42795401
9
830.6314
Oxidation/
reduction:
chemical
incompatibility
N
830.6315
Flammability
N
830.6316
Explodability
N
830.6317
Storage
stability
N
830.6319
Miscibility
N
830.6320
Corrosion
characteristics
N
830.7000
pH
N
830.7050
UV/
Visible
absorption
Y
44543504
10
830.7100
Viscosity
N
830.7200
Melting
point/
melting
range
Y
41055803
6,
41067001
11,
41223801
12
830.7220
Boiling
point/
boiling
range
N/
A
13
830.7300
Density/
relative
density/
bulk
density
N
830.7370
Dissociation
constants
in
water
Y
41055803
6,
41067001
11,
41972501
14,
44543504
10
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
Y
41332004
15
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
Y
41055803
6,
45692501
16
830.7950
Vapor
pressure
Y
41055803
6,
41067001
11,
44543504
10
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
This
product
was
transferred
from
Agrolinz
(
EPA
Reg.
No.
42545­
30);
data
requirements
are
based
on
data
submitted
by
Agrolinz.
2
The
referenced
CSF
was
reviewed
under
CB
No.
13060,
D198004,
8/
23/
94,
L.
Cheng;
and
all
other
references
were
reviewed
as
noted.
Italicized
references
reflect
TGAI
and/
or
PAI
data
for
phys/
chem
requirements
which
may
be
shared
by
Task
Force
members.
3
The
CSF
must
be
resubmitted
to
properly
identify
the
registrant
and
EPA
Registry
number
since
the
product
transfer.
40
4
Adequate
dioxin
analysis
data
have
been
submitted;
however,
preliminary
analysis
of
five
batches
of
the
technical
product
for
all
components
present
at

0.1%
in
the
TGAI
must
be
submitted.
5
Data
reviewed
under
CB
No.
7737,
11/
26/
91,
S.
Funk
for
EPA
Reg.
No.
61469­
1;
S.
Funk
determined
(
D189025,
6/
25/
93)
that
the
data
may
be
translated
to
this
product.
6
CB
Nos.
5454,
5455,
5489,
5540,
5541,
5542,
5543,
and
5544,
10/
25/
89,
M.
Nelson
(
TGAI
data
for
the
Dow
AgroSciences
97%
acid
T,
EPA
Reg.
No.
62719­
25).
7
Letter
dated
12/
2/
91
from
L.
Rossi
(
SRRD)
to
K.
Shearer
of
Rhone­
Poulenc
(
TGAI
data
for
the
BASF
99.3%
acid
T,
EPA
Reg.
No.
72868­
1).
8
D170803,
7/
16/
92,
E.
Zager
(
TGAI
data
for
the
PBI/
Gordon
98.2%
acid
T,
EPA
Reg.
No.
2217­
455).
9
D192560,
8/
5/
93,
F.
Toghrol
(
TGAI
data
for
the
Dow
AgroSciences
97%
acid
T,
EPA
Reg.
No.
62719­
25).
10
RD
Memorandum,
D245940,
6/
9/
98,
S.
Mathur
(
PAI
data
for
the
PBI/
Gordon
98.2%
acid
T,
EPA
Reg.
No.
2217­
455).
11
CB
5549,
9/
26/
89,
M.
Nelson
(
TGAI
data
for
the
BASF
99.3%
acid
T,
EPA
Reg.
No.
72868­
1).
12
CB
6393,
4/
3/
90,
G.
Makhijani
(
TGAI
data
for
the
PBI/
Gordon
98.2%
acid
T,
EPA
Reg.
No.
2217­
455).
13
Data
are
not
required
because
the
TGAI
is
a
solid
at
room
temperature.
14
D186542
and
D190622,
6/
1/
93,
W.
Smith
(
PAI
data
for
the
PBI/
Gordon
98.2%
acid
T,
EPA
Reg.
No.
2217­
455).
15
CB
6581,
7/
27/
90,
G.
Makhijani
(
Task
Force
PAI
data).
16
D283959,
3/
1/
04,
W.
Hazel
(
revised
water
solubility
data
for
the
Task
Force
PAI).
41
Case
No.
0073
Chemical
No.
030001
Case
Name:
2,4­
D
Registrant:
Agro­
Gor
Corporation
Product(
s):
97.9%
acid
T
(
EPA
Reg.
No.
61469­
1)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
41219601
3,
CSF
2/
15/
91
830.1600
Description
of
materials
used
to
produce
the
product
Y
41246701
4,
41681901,
41796201
830.1620
Description
of
production
process
N
5
41246701
4,
41796201
830.1670
Discussion
of
formation
of
impurities
N
6
41246701
4
830.1700
Preliminary
analysis
N
7
41219601
3,
41796202
830.1750
Certified
limits
Y
41219601
3,
CSF
2/
15/
91
830.1800
Enforcement
analytical
method
N
8
41219601
3,
41796202
830.6302
Color
N
830.6303
Physical
state
N
830.6304
Odor
N
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
Y
41055803
9,
41855701
10,
4202360111,
42795401
12
830.6314
Oxidation/
reduction:
chemical
incompatibility
N
830.6315
Flammability
N
830.6316
Explodability
N
830.6317
Storage
stability
N
830.6319
Miscibility
N
830.6320
Corrosion
characteristics
N
830.7000
pH
N
830.7050
UV/
Visible
absorption
Y
44543504
13
830.7100
Viscosity
N
830.7200
Melting
point/
melting
range
Y
41055803
9,
41067001
14,
41223801
15
830.7220
Boiling
point/
boiling
range
N/
A
16
830.7300
Density/
relative
density/
bulk
density
N
830.7370
Dissociation
constants
in
water
Y
41055803
9,
41067001
14,
41972501
17,
44543504
13
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
Y
41332004
18
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
Y
41055803
9,
45692501
19
830.7950
Vapor
pressure
Y
41055803
9,
41067001
14,
44543504
13
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
2
The
bolded
references
were
reviewed
under
D162358,
11/
26/
91,
S.
Funk;
and
all
other
references
were
reviewed
as
noted.
Italicized
references
reflect
TGAI
and/
or
PAI
data
for
phys/
chem
requirements
which
may
be
shared
by
Task
Force
members.
42
3
CB
No.
5860,
2/
8/
90,
F.
Griffith.
4
CB
No.
7137,
11/
16/
90,
S.
Funk.
5
Additional
information
concerning
whether
the
production
equipment
is
used
to
produce
other
products
is
required.
6
An
adequate
discussion
has
been
submitted
for
the
possible
formation
of
dioxins/
dibenzofurans;
however,
a
discussion
is
required
concerning
the
formation
of
other
impurities
listed
on
the
CSF,
and
the
potential
for
formation
of
impurities
resulting
from
post­
production
reactions
and
cross­
contamination
from
use
of
equipment
for
other
products.
7
Adequate
dioxin
analyses
have
been
submitted;
however,
preliminary
analysis
of
five
batches
of
the
technical
product
for
all
components
present
at

0.1%
in
the
TGAI
must
be
submitted.
8
Adequate
enforcement
methods
have
been
submitted
for
dioxins/
dibenzofurans;
however,
enforcement
analytical
methods
with
supporting
validation
data
are
required
for
all
other
components
present
in
the
final
product
and
for
which
upper
certified
limits
have
been
proposed
(
active
ingredients
and
impurities
present
at

0.1%
or
of
toxicological
significance).
9
CB
Nos.
5454,
5455,
5489,
5540,
5541,
5542,
5543,
and
5544,
10/
25/
89,
M.
Nelson
(
TGAI
data
for
the
Dow
AgroSciences
97%
acid
T,
EPA
Reg.
No.
62719­
25).
10
Letter
dated
12/
2/
91
from
L.
Rossi
(
SRRD)
to
K.
Shearer
of
Rhone­
Poulenc
(
TGAI
data
for
the
BASF
99.3%
acid
T,
EPA
Reg.
No.
72868­
1).
11
D170803,
7/
16/
92,
E.
Zager
(
TGAI
data
for
the
PBI/
Gordon
98.2%
acid
T,
EPA
Reg.
No.
2217­
455).
12
D192560,
8/
5/
93,
F.
Toghrol
(
TGAI
data
for
the
Dow
AgroSciences
97%
acid
T,
EPA
Reg.
No.
62719­
25).
13
RD
Memorandum,
D245940,
6/
9/
98,
S.
Mathur
(
PAI
data
for
the
PBI/
Gordon
98.2%
acid
T,
EPA
Reg.
No.
2217­
455).
14
CB
5549,
9/
26/
89,
M.
Nelson
(
TGAI
data
for
the
BASF
99.3%
acid
T,
EPA
Reg.
No.
72868­
1).
15
CB
6393,
4/
3/
90,
G.
Makhijani
(
TGAI
data
for
the
PBI/
Gordon
98.2%
acid
T,
EPA
Reg.
No.
2217­
455).
16
Data
are
not
required
because
the
TGAI
is
a
solid
at
room
temperature.
17
D186542
and
D190622,
6/
1/
93,
W.
Smith
(
PAI
data
for
the
PBI/
Gordon
98.2%
acid
T,
EPA
Reg.
No.
2217­
455).
18
CB
6581,
7/
27/
90,
G.
Makhijani
(
Task
Force
PAI
data).
19
D283959,
3/
1/
04,
W.
Hazel
(
revised
water
solubility
data
for
the
Task
Force
PAI).
43
Case
No.
0073
Chemical
No.
030001
Case
Name:
2,4­
D
Registrant:
Dow
AgroSciences
LLC
Product(
s):
97%
acid
"
flake"
T
(
EPA
Reg.
No.
62719­
25)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
41055804,
41055805,
41220101
3,
41973501
4,
CSF
2/
6/
01
5
830.1600
Description
of
materials
used
to
produce
the
product
Y
41055804,
41496701
6
830.1620
Description
of
production
process
Y
41055801,
41496701
6
830.1670
Discussion
of
formation
of
impurities
Y
41973501
4
830.1700
Preliminary
analysis
Y
7
41055805,
41220101
3,
41496701
6,
41973501
4,
43777501
8,
44287101
9
830.1750
Certified
limits
Y
41055804,
41055805,
41220101
3,
41496701
6,
41973501
4,
CSF
2/
6/
01
5
830.1800
Enforcement
analytical
method
Y
41055802,
41220101
3,
41496701
6
830.6302
Color
Y
41055803
830.6303
Physical
state
Y
41055803
830.6304
Odor
Y
41055803
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
Y
41055803,
42795401
10
830.6314
Oxidation/
reduction:
chemical
incompatibility
N
11
830.6315
Flammability
N/
A
12
830.6316
Explodability
Y
41973501
4
830.6317
Storage
stability
Y
43260501
13
830.6319
Miscibility
N/
A
12
830.6320
Corrosion
characteristics
Y
43260501
13
830.7000
pH
N/
A
14
830.7050
UV/
Visible
absorption
Y
44543504
15
830.7100
Viscosity
N/
A
12
830.7200
Melting
point/
melting
range
Y
41055803
830.7220
Boiling
point/
boiling
range
N/
A
12
830.7300
Density/
relative
density/
bulk
density
N
11,
16
41055803
830.7370
Dissociation
constants
in
water
Y
41055803
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
Y
41055803
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
Y
41055803,
45692501
17
830.7950
Vapor
pressure
Y
41055803
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
44
2
Bolded
references
were
reviewed
under
CB
Nos.
5454,
5455,
5489,
5540,
5541,
5542,
5543,
and
5544,
10/
25/
89,
M.
Nelson;
and
all
other
references
were
reviewed
as
noted.
Italicized
references
reflect
TGAI
and/
or
PAI
data
for
phys/
chem
requirements
which
may
be
shared
by
Task
Force
members.
3
CB
No.
5826,
2/
13/
90,
F.
Griffith.
4
D167642,
D167684,
and
D167644,
9/
8/
92,
F.
Toghrol.
5
RD
Memorandum,
D273235,
4/
2/
01,
S.
Mathur.
6
CB
No.
6776,
8/
7/
90,
S.
Funk.
7
The
available
dioxin
data
are
acceptable
pending
receipt
of
additional
sampling
information.
8
D219403,
1/
3/
97,
D.
Miller.
9
D236419.
10
D192560,
8/
5/
93,
F.
Toghrol.
11
The
registrant
must
indicate
whether
data
submitted
under
D167642,
D167684,
and
D167644,
9/
8/
92,
F.
Toghrol
for
the
"
molten"
acid
(
EPA
Reg.
No.
62719­
25)
are
applicable
to
the
"
flake"
acid.
12
Data
are
not
required
because
the
T/
TGAI
is
a
solid
at
room
temperature.
13
D204466,
9/
15/
94,
F.
Toghrol.
14
Data
are
not
applicable
because
the
T/
TGAI
is
not
dispersible
in
water.
15
RD
Memorandum,
D245940,
6/
9/
98,
S.
Mathur
(
PAI
data
for
the
PBI/
Gordon
98.2%
T,
EPA
Reg.
No.
2217­
455).
16
Data
demonstrating
the
specific
gravity
at
20­
25
C
are
required.
17
D283959,
3/
1/
04,
W.
Hazel
(
revised
water
solubility
data
for
the
Task
Force
PAI).
45
Case
No.
0073
Chemical
No.
030001
Case
Name:
2,4­
D
Registrant:
Dow
AgroSciences
LLC
Product(
s):
85%
acid
FI
(
EPA
Reg.
No.
62719­
231)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
N
3
CSF
3/
17/
92
830.1600
Description
of
materials
used
to
produce
the
product
N/
A
830.1620
Description
of
production
process
N/
A
830.1670
Discussion
of
formation
of
impurities
N/
A
830.1700
Preliminary
analysis
N/
A
830.1750
Certified
limits
N
3
CSF
3/
17/
92
830.1800
Enforcement
analytical
method
N/
A
830.6302
Color
N/
A
830.6303
Physical
state
N/
A
830.6304
Odor
N/
A
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
N/
A
830.6314
Oxidation/
reduction:
chemical
incompatibility
N/
A
830.6315
Flammability
N/
A
830.6316
Explodability
N/
A
830.6317
Storage
stability
N/
A
830.6319
Miscibility
N/
A
830.6320
Corrosion
characteristics
N/
A
830.7000
pH
N/
A
830.7050
UV/
Visible
absorption
N/
A
830.7100
Viscosity
N/
A
830.7200
Melting
point/
melting
range
N/
A
830.7220
Boiling
point/
boiling
range
N/
A
830.7300
Density/
relative
density/
bulk
density
N/
A
830.7370
Dissociation
constants
in
water
N/
A
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
N/
A
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
N/
A
830.7950
Vapor
pressure
N/
A
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
According
to
the
CSF,
the
Dow
AgroSciences
85%
T
is
repackaged
from
an
EPA­
registered
product;
all
product
chemistry
data
requirements
will
be
fulfilled
by
data
for
the
source
product.
We
note
that
the
source
product
has
apparently
been
canceled;
if
the
85%
T
is
no
longer
repackaged
from
an
EPA­
registered
product,
all
product
chemistry
data
will
be
required.
2
The
CSF
was
obtained
from
the
product
jacket.
3
The
CSF
must
be
revised
to
reflect
the
current
technical
source
product;
the
listed
source
product
has
been
canceled.
46
Case
No.
0073
Chemical
No.
030001
Case
Name:
2,4­
D
Registrant:
Dow
AgroSciences
LLC
Product(
s):
74.8%
acid
"
molten"
T
(
EPA
Reg.
No.
62719­
24)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
41055801,
41055802,
41220101
3,
41973501
4,
CSF
12/
22/
98
5
830.1600
Description
of
materials
used
to
produce
the
product
Y
41055801,
41496701
6,
41973501
4
830.1620
Description
of
production
process
Y
41055801,
41496701
6,
41973501
4
830.1670
Discussion
of
formation
of
impurities
Y
41055801,
41973501
4
830.1700
Preliminary
analysis
N
7
41055802,
41220101
3,
41496701
6,
41973501
4,
43777502
8,
44228601
5
830.1750
Certified
limits
N
9
41055801,
41055802,
41220101
3,
41496701
6,
41973501
4,
CSF
12/
22/
98
5
830.1800
Enforcement
analytical
method
Y
41055802,
41220101
3,
41496701
6
830.6302
Color
Y
41055803
830.6303
Physical
state
Y
41055803
830.6304
Odor
Y
41055803
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
Y
41055803,
41973502
4
830.6314
Oxidation/
reduction:
chemical
incompatibility
Y
41973501
4
830.6315
Flammability
N/
A
10
830.6316
Explodability
Y
41973501
4
830.6317
Storage
stability
N
11
830.6319
Miscibility
N/
A
10
830.6320
Corrosion
characteristics
Y
41973501
4
830.7000
pH
N/
A
12
830.7050
UV/
Visible
absorption
Y
44543504
13
830.7100
Viscosity
N/
A
10
830.7200
Melting
point/
melting
range
Y
41055803
830.7220
Boiling
point/
boiling
range
N/
A
10
830.7300
Density/
relative
density/
bulk
density
Y
41055803,
41973501
4
830.7370
Dissociation
constants
in
water
Y
41055803
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
Y
41055803
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
Y
41055803,
45692501
14
830.7950
Vapor
pressure
Y
41055803
47
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.

2
Bolded
references
were
reviewed
under
CB
Nos.
5454,
5455,
5489,
5540,
5541,
5542,
5543,
and
5544,
10/
25/
89,
M.
Nelson;
and
all
other
references
were
reviewed
as
noted.
Italicized
references
reflect
TGAI
and/
or
PAI
data
for
phys/
chem
requirements
which
may
be
shared
by
Task
Force
members.

3
CB
No.
5826,
2/
13/
90,
F.
Griffith.

4
D167642,
D167684,
and
D167644,
9/
8/
92,
F.
Toghrol.

5
Registration
Memorandum,
D252258,
2/
2/
99,
H.
Podall.

6
CB
No.
6776,
8/
7/
90,
S.
Funk.

7
Values
given
for
the
amount
of
an
impurity
present
in
the
product
and
reported
on
the
CSF
were
not
included
in
the
preliminary
analysis
report.
This
should
be
corrected
for
the
record.

8
D219403,
1/
3/
97,
D.
Miller.

9
The
range
of
certified
limits
proposed
for
the
active
ingredient
is
wider
than
required
under
40
CFR
158.175(
b)(
2)
and
seems
excessive
for
the
variations
resulting
from
the
process
conditions.

10
Data
are
not
required
because
the
T/
TGAI
is
a
solid
at
room
temperature.

11
Study
in
progress
per
D167642,
D167684,
and
D167644,
9/
8/
92,
F.
Toghrol.

12
Data
are
not
applicable
because
the
T/
TGAI
is
not
dispersible
in
water.

13
RD
Memorandum,
D245940,
6/
9/
98,
S.
Mathur
(
PAI
data
for
the
PBI/
Gordon
98.2%
T,
EPA
Reg.
No.
2217­
455).

14
D283959,
3/
1/
04,
W.
Hazel
(
revised
water
solubility
data
for
the
Task
Force
PAI).
48
Case
No.
0073
Chemical
No.
030001
Case
Name:
2,4­
D
Registrant:
BASF
Aktiengesellschaft
Product(
s):
99.3%
acid
T
(
EPA
Reg.
No.
72868­
1)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
41067001,
41203301
3,
CSF
12/
16/
92
4
830.1600
Description
of
materials
used
to
produce
the
product
Y
41067001,
41599401
5
830.1620
Description
of
production
process
Y
41067001,
41599401
5,
41789901
6
830.1670
Discussion
of
formation
of
impurities
Y
41067001,
41599401
5,
41789901
6,
41789902
6
830.1700
Preliminary
analysis
Y
41067001,
41203301
7,
41735701
8
830.1750
Certified
limits
Y
41067001,
41203301
3,
41599401
5,
CSF
12/
16/
92
4
830.1800
Enforcement
analytical
method
Y
41067001,
41203301
3,
41599401
5,
41789902
6
830.6302
Color
Y
41067001
830.6303
Physical
state
Y
41067001
830.6304
Odor
Y
41067001
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
Y
41067001,
41855701
9
830.6314
Oxidation/
reduction:
chemical
incompatibility
Y
41067001
830.6315
Flammability
N/
A
10
830.6316
Explodability
N/
A
11
41067001
830.6317
Storage
stability
N
12
41067001
830.6319
Miscibility
N/
A
10
830.6320
Corrosion
characteristics
N
12
41067001
830.7000
pH
N/
A
13
830.7050
UV/
Visible
absorption
Y
44543504
14
830.7100
Viscosity
N/
A
10
830.7200
Melting
point/
melting
range
Y
41067001
830.7220
Boiling
point/
boiling
range
N/
A
10
830.7300
Density/
relative
density/
bulk
density
Y
41067001,
41855701
9
830.7370
Dissociation
constants
in
water
Y
41067001
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
Y
41067001
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
Y
41067001,
41332002
6,
41880601
9,
45692501
14
830.7950
Vapor
pressure
Y
41067001
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
This
product
was
transferred
from
Rhone­
Poulenc
(
EPA
Reg.
No.
264­
492).
BASF
must
confirm
that
the
manufacturing
location
and
process
have
not
changed
since
the
product
transfer,
otherwise
additional
product
chemistry
data
may
be
required.
49
2
Bolded
references
were
reviewed
under
CB
No.
5549,
9/
26/
89,
M.
Nelson;
and
all
other
references
were
reviewed
as
noted.
Italicized
references
reflect
TGAI
and/
or
PAI
data
for
phys/
chem
requirements
which
may
be
shared
by
Task
Force
members.

3
CB
No.
5750,
2/
8/
90,
F.
Griffith.

4
D189458,
8/
12/
93,
M.
Clifford.

5
CB
No.
7139,
11/
13/
90,
S.
Funk.

6
D162701,
7/
31/
91,
S.
Funk.

7
CB
No.
6584,
7/
12/
90,
S.
Funk.

8
D160520,
7/
24/
91,
S.
Funk.

9
Letter
dated
12/
2/
91
from
L.
Rossi
(
SRRD)
to
K.
Shearer
(
Rhone­
Poulenc)
states
data
requirements
are
satisfied
for
this
guideline;
the
actual
review
was
not
available.

10
Data
are
not
required
because
the
T/
TGAI
is
a
solid
at
room
temperature.

11
Data
are
not
required
because
the
MP
does
not
contain
explosive
ingredients.

12
Quantitative
data
and
methods
are
required.

13
Data
are
not
applicable
because
the
TGAI
is
not
dispersible
in
water.

14
RD
Memorandum,
D245940,
6/
9/
98,
S.
Mathur
(
PAI
data
for
the
PBI/
Gordon
98.2%
T,
EPA
Reg.
No.
2217­
455).

15
D283959,
3/
1/
04,
W.
Hazel
(
revised
water
solubility
data
for
the
Task
Force
PAI).
50
Case
No.
0073
Chemical
No.
030001
Case
Name:
2,4­
D
Registrant:
GroWell
Limited
Product(
s):
98.2%
acid
T
(
EPA
Reg.
No.
73754­
1)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
3
CSF
8/
3/
01
830.1600
Description
of
materials
used
to
produce
the
product
N/
A
830.1620
Description
of
production
process
N/
A
830.1670
Discussion
of
formation
of
impurities
N/
A
830.1700
Preliminary
analysis
N/
A
830.1750
Certified
limits
Y
3
CSF
8/
3/
01
830.1800
Enforcement
analytical
method
N/
A
830.6302
Color
N/
A
830.6303
Physical
state
N/
A
830.6304
Odor
N/
A
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
N/
A
830.6314
Oxidation/
reduction:
chemical
incompatibility
N/
A
830.6315
Flammability
N/
A
830.6316
Explodability
N/
A
830.6317
Storage
stability
N/
A
830.6319
Miscibility
N/
A
830.6320
Corrosion
characteristics
N/
A
830.7000
pH
N/
A
830.7050
UV/
Visible
absorption
N/
A
830.7100
Viscosity
N/
A
830.7200
Melting
point/
melting
range
N/
A
830.7220
Boiling
point/
boiling
range
N/
A
830.7300
Density/
relative
density/
bulk
density
N/
A
830.7370
Dissociation
constants
in
water
N/
A
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
N/
A
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
N/
A
830.7950
Vapor
pressure
N/
A
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
This
product
is
repackaged
from
an
EPA­
registered
product;
all
product
chemistry
data
requirements
will
be
fulfilled
by
data
for
the
source
product.
2
The
CSF
was
obtained
from
the
product
jacket.
3
The
CSF
must
be
revised
to
reflect
the
nominal
concentration
and
certified
limits
of
the
active
ingredient
in
the
product,
based
on
the
actual
amount
of
active
ingredient
in
the
source
product.
51
Case
No.
0073
Chemical
No.
030004
Case
Name:
2,4­
D
Registrant:
NuFarm
Americas,
Inc.
Product(
s):
90.6%
Na
T
(
EPA
Reg.
No.
228­
123)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
41123601,
Letter
4/
12/
94
3
830.1600
Description
of
materials
used
to
produce
the
product
Y
42537501
4,
Letter
4/
12/
94
3
830.1620
Description
of
production
process
Y
42537501
4
830.1670
Discussion
of
formation
of
impurities
Y
41123601,
42537501
4
830.1700
Preliminary
analysis
Y
41123601,
Letter
4/
12/
94
3
830.1750
Certified
limits
Y
5
41123601,
Letter
4/
12/
94
3
830.1800
Enforcement
analytical
method
Y
41123601,
42537501
4
830.6302
Color
N
6
41123601
830.6303
Physical
state
N
6
41123601
830.6304
Odor
N
6
41123601
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
N
830.6314
Oxidation/
reduction:
chemical
incompatibility
N
830.6315
Flammability
N/
A
7
830.6316
Explodability
Y
8
42537501
4
830.6317
Storage
stability
Y
41123601,
42227501
9
830.6319
Miscibility
N/
A
7
830.6320
Corrosion
characteristics
Y
41123601,
42227501
9
830.7000
pH
N
6
41123601
830.7050
UV/
Visible
absorption
N
10
830.7100
Viscosity
N/
A
7
830.7200
Melting
point/
melting
range
Y
42537501
4
830.7220
Boiling
point/
boiling
range
N/
A
7
830.7300
Density/
relative
density/
bulk
density
N
6
41123601
830.7370
Dissociation
constants
in
water
N/
A
11
41972501
12
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
Y
8
42537501
4
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
N
13
42537501
4
830.7950
Vapor
pressure
Y
8
42537501
4
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.

2
Bolded
references
were
reviewed
under
CB
No.
7945,
6/
1/
92;
and
all
other
references
were
reviewed
as
noted.
Italicized
references
reflect
TGAI
and/
or
PAI
data
for
phys/
chem
requirements
which
may
be
shared
by
Task
Force
members.

3
D203749,
10/
6/
94,
F.
Toghrol.

4
D184583,
2/
8/
93,
F.
Toghrol.
52
5
Pending
decision
by
SRRD/
RD
as
to
whether
upper
certified
limits
are
required
for
the
sodium
salt
impurities.

6
The
test
substance
used
for
the
determinations
must
be
identified.

7
Data
are
not
required
because
the
TGAI/
MP
is
a
solid
at
room
temperature.

8
Data
requirements
were
waived
under
D184583,
2/
8/
93,
F.
Toghrol.

9
D175577.

10
The
OPPTS
Series
830,
Product
Properties
Test
Guidelines
require
data
pertaining
to
UV/
visible
absorption
for
the
PAI.

11
Data
are
not
required
because
the
Na
salt
completely
dissociates
in
aqueous
solutions;
this
data
requirement
will
be
fulfilled
by
data
for
the
acid
source
product.

12
D186542
and
D190622,
W.
Smith
(
conductance
data
for
the
Na
salt
included
with
data
for
the
PBI/
Gordon
98.2%
acid
T,
EPA
Reg.
No.
2217­
455).

13
Additional
data
are
required
concerning
the
solvents
used,
temperatures
of
the
study,
test
substance
identification,
and
the
experimental
conditions.
53
Case
No.
0073
Chemical
No.
030004
Case
Name:
2,4­
D
Registrant:
NuFarm
Limited
Product(
s):
90.6%
Na
T
(
EPA
Reg.
No.
35935­
19)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
3
CSF
5/
7/
96
830.1600
Description
of
materials
used
to
produce
the
product
N/
A
830.1620
Description
of
production
process
N/
A
830.1670
Discussion
of
formation
of
impurities
N/
A
830.1700
Preliminary
analysis
N/
A
830.1750
Certified
limits
Y
3
CSF
5/
7/
96
830.1800
Enforcement
analytical
method
N/
A
830.6302
Color
N/
A
830.6303
Physical
state
N/
A
830.6304
Odor
N/
A
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
N/
A
830.6314
Oxidation/
reduction:
chemical
incompatibility
N/
A
830.6315
Flammability
N/
A
830.6316
Explodability
N/
A
830.6317
Storage
stability
N/
A
830.6319
Miscibility
N/
A
830.6320
Corrosion
characteristics
N/
A
830.7000
pH
N/
A
830.7050
UV/
Visible
absorption
N/
A
830.7100
Viscosity
N/
A
830.7200
Melting
point/
melting
range
N/
A
830.7220
Boiling
point/
boiling
range
N/
A
830.7300
Density/
relative
density/
bulk
density
N/
A
830.7370
Dissociation
constants
in
water
N/
A
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
N/
A
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
N/
A
830.7950
Vapor
pressure
N/
A
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
According
to
the
CSF,
the
90.6%
T
is
repackaged
from
an
EPAregistered
product;
therefore,
all
product
chemistry
data
requirements
will
be
fulfilled
by
data
for
the
source
product.
However,
the
NuFarm
90.6%
Na
T
was
transferred
from
Riverdale
Chemical
Company
(
EPA
Reg.
No.
228­
319),
and
NuFarm
must
confirm
that
the
source
product
has
not
changed
since
the
product
transfer;
otherwise,
additional
product
chemistry
data
may
be
required.
2
The
CSF
was
obtained
from
the
product
jacket.
3
The
CSF
must
be
revised
to
reflect
the
current
registrant
name,
EPA
Reg.
No.,
and
the
nominal
concentration
and
certified
limits
of
the
active
ingredient
in
the
product,
based
on
the
actual
amount
of
active
ingredient
in
the
source
product.
54
Case
No.
0073
Chemical
No.
030016
Case
Name:
2,4­
D
Registrant:
PBI/
Gordon
Corporation
Product(
s):
2,4­
D
Diethanolamine
(
DEA)
TGAI
PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
N/
A
3
830.1600
Description
of
materials
used
to
produce
the
product
Y
44184201
4
830.1620
Description
of
production
process
Y
44184201
4
830.1670
Discussion
of
formation
of
impurities
Y
44184201
4
830.1700
Preliminary
analysis
N
830.1750
Certified
limits
N/
A
3
830.1800
Enforcement
analytical
method
N/
A
3
830.6302
Color
Y
42857203
830.6303
Physical
state
Y
42857203
830.6304
Odor
Y
42857203
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
Y
42857209
830.6314
Oxidation/
reduction:
chemical
incompatibility
N/
A
3
830.6315
Flammability
N/
A
3
830.6316
Explodability
N/
A
3
830.6317
Storage
stability
N/
A
3
830.6319
Miscibility
N/
A
3
830.6320
Corrosion
characteristics
N/
A
3
830.7000
pH
Y
42857208
830.7050
UV/
Visible
absorption
N
830.7100
Viscosity
N/
A
3
830.7200
Melting
point/
melting
range
Y
42857209
830.7220
Boiling
point/
boiling
range
N/
A
5
830.7300
Density/
relative
density/
bulk
density
Y
42857204
830.7370
Dissociation
constants
in
water
N/
A
6
41972501
7
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
Y
42857207
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
Y
42857205
830.7950
Vapor
pressure
Y
42857206
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
2,4­
D
DEA
TGAI
data
are
required
to
support
the
PBI/
Gordon
EPs
(
EPA
Reg.
Nos.
2217­
703,
2217­
807,
and
2217­
813)
manufactured
by
an
integrated
system
from
2,4­
D
acid.

2
Bolded
references
were
reviewed
under
D194119,
1/
31/
94,
F.
Toghrol;
and
all
other
references
were
reviewed
as
noted.
55
3
Product­
specific
data
are
not
required
for
the
TGAI.

4
RD
Memorandum,
D232536,
6/
27/
97,
A.
Smith;
data
submitted
for
the
EP
will
also
satisfy
the
TGAI
data
requirement.

5
Data
are
not
required
because
the
TGAI
is
a
solid
at
room
temperature.

6
Data
are
not
required
because
the
DEA
salt
completely
dissociates
in
aqueous
solutions;
this
data
requirement
will
be
fulfilled
by
data
for
the
acid
source
product(
s).

7
D186542
and
D190622,
W.
Smith
(
conductance
data
for
the
DEA
salt
included
with
data
for
the
PBI/
Gordon
98.2%
acid
T,
EPA
Reg.
No.
2217­
455).
56
Case
No.
0073
Chemical
No.
030019
Case
Name:
2,4­
D
Registrant:
NuFarm
Americas,
Inc.
Product(
s):
66.3%
DMA
FI
(
EPA
Reg.
No.
228­
294)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
3
CSFs
1/
5/
81
and
1/
22/
82
830.1600
Description
of
materials
used
to
produce
the
product
N
830.1650
Description
of
formulation
process
N
830.1670
Discussion
of
formation
of
impurities
N
830.1700
Preliminary
analysis
N
830.1750
Certified
limits
Y
3
CSFs
1/
5/
81
and
1/
22/
82
830.1800
Enforcement
analytical
method
N
830.6302
Color
N
830.6303
Physical
state
N
830.6304
Odor
N
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
N
830.6314
Oxidation/
reduction:
chemical
incompatibility
N
830.6315
Flammability
N
830.6316
Explodability
N
830.6317
Storage
stability
N
830.6319
Miscibility
N
830.6320
Corrosion
characteristics
N
830.7000
pH
N
830.7050
UV/
Visible
absorption
N
830.7100
Viscosity
N
830.7200
Melting
point/
melting
range
Y
42829901
4
830.7220
Boiling
point/
boiling
range
N/
A
5
830.7300
Density/
relative
density/
bulk
density
N
830.7370
Dissociation
constants
in
water
N/
A
6
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
N/
A
7
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
Y
43358801
8
830.7950
Vapor
pressure
Y
42021001
9
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
This
product
is
manufactured
from
an
EPA­
registered
acid
product;
the
registrant
must
submit
product
chemistry
data
for
the
practical
equivalent
of
the
DMA
salt
TGAI
and
for
the
manufacturing­
use
product.
2
CSFs
for
alternate
formulations
were
obtained
from
the
product
jacket;
and
all
other
references
were
reviewed
as
noted.
Italicized
references
reflect
TGAI
and/
or
PAI
data
for
phys/
chem
requirements
which
may
be
shared
by
Task
Force
members.
3
The
CSFs
must
be
modified
to
reflect
the
current
registrant,
EPA
Reg.
No.,
and
source
products.
4
D193116,
1/
24/
94,
F.
Toghrol
(
PAI
data
for
the
Dow
AgroSciences
67.1%
DMA
FI,
EPA
Reg.
No.
62719­
27).
5
Data
are
not
required
because
the
PAI
is
a
solid
at
room
temperature.
57
6
Data
are
not
required
because
the
DMA
salt
completely
dissociates
in
aqueous
solutions;
data
for
2,4­
D
acid
were
accepted
to
fulfill
this
requirement
under
CBRS
Nos.
5454,
5455,
5489,
5540,
5541,
5542,
5543,
and
5544,
10/
25/
89,
M.
Nelson
(
data
for
the
Dow
AgroSciences
67.1%
DMA
FI,
EPA
Reg.
No.
62719­
27).
7
Data
are
not
required
for
the
DMA
salt
TGAI
because
it
is
a
polar
organic
compound;
no
additional
data
were
required
for
this
data
requirement
under
D161051,
4/
25/
91,
R.
Perfetti
(
data
for
the
Dow
AgroSciences
67.1%
DMA
FI,
EPA
Reg.
No.
62719­
27).
8
D207979,
2/
22/
96,
D.
Miller
(
TGAI
data
for
the
Dow
AgroSciences
67.1%
DMA
FI,
EPA
Reg.
No.
62719­
27).
9
D170802,
7/
24/
92,
(
PAI
data
for
the
Dow
AgroSciences
67.1%
DMA
FI,
EPA
Reg.
No.
62719­
27).
58
Case
No.
0073
Chemical
No.
030019
Case
Name:
2,4­
D
Registrant:
The
Ortho
Business
Group
Product(
s):
31.8%
DMA
FI
(
EPA
Reg.
No.
239­
2485)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
N
3
CSFs
1/
27/
95
830.1600
Description
of
materials
used
to
produce
the
product
N
830.1650
Description
of
formulation
process
N
830.1670
Discussion
of
formation
of
impurities
N
830.1700
Preliminary
analysis
N
830.1750
Certified
limits
N
3
CSFs
1/
27/
95
830.1800
Enforcement
analytical
method
N
830.6302
Color
N
830.6303
Physical
state
N
830.6304
Odor
N
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
N
830.6314
Oxidation/
reduction:
chemical
incompatibility
N
830.6315
Flammability
N
830.6316
Explodability
N
830.6317
Storage
stability
N
830.6319
Miscibility
N
830.6320
Corrosion
characteristics
N
830.7000
pH
N
830.7050
UV/
Visible
absorption
N
830.7100
Viscosity
N
830.7200
Melting
point/
melting
range
N
830.7220
Boiling
point/
boiling
range
N
830.7300
Density/
relative
density/
bulk
density
N
830.7370
Dissociation
constants
in
water
N
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
N
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
N
830.7950
Vapor
pressure
N
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
This
product
is
manufactured
from
an
EPA­
registered
acid
product;
the
registrant
must
submit
product
chemistry
data
for
the
practical
equivalent
of
the
DMA
salt
TGAI
and
for
the
manufacturing­
use
product.
2
The
CSF
was
reviewed
under
Registration
Division
memorandum
D214918,
6/
26/
95,
T.
Alston.
3
The
CSF
must
be
modified
to
include
the
DMA
salt
and
its
acid
equivalent.
59
Case
No.
0073
Chemical
No.
030019
Case
Name:
2,4­
D
Registrant:
PBI/
Gordon
Corporation
Product(
s):
66.57%
DMA
FI
(
EPA
Reg.
No.
2217­
665)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
CSFs
12/
15/
95
3
830.1600
Description
of
materials
used
to
produce
the
product
N
830.1650
Description
of
formulation
process
N
830.1670
Discussion
of
formation
of
impurities
N
830.1700
Preliminary
analysis
N
830.1750
Certified
limits
Y
CSFs
12/
15/
95
3
830.1800
Enforcement
analytical
method
N
830.6302
Color
N
830.6303
Physical
state
N
830.6304
Odor
N
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
N
830.6314
Oxidation/
reduction:
chemical
incompatibility
N
830.6315
Flammability
N
830.6316
Explodability
N
830.6317
Storage
stability
N
830.6319
Miscibility
N
830.6320
Corrosion
characteristics
N
830.7000
pH
N
830.7050
UV/
Visible
absorption
N
830.7100
Viscosity
N
830.7200
Melting
point/
melting
range
Y
42829901
4
830.7220
Boiling
point/
boiling
range
N/
A
5
830.7300
Density/
relative
density/
bulk
density
N
830.7370
Dissociation
constants
in
water
N/
A
6
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
N/
A
7
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
Y
43358801
8
830.7950
Vapor
pressure
Y
42021001
9
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
This
product
is
manufactured
from
an
EPA­
registered
acid
product;
the
registrant
must
submit
product
chemistry
data
for
the
practical
equivalent
of
the
DMA
salt
TGAI
and
for
the
manufacturing­
use
product.

2
The
CSFs
for
alternate
formulations
were
obtained
from
the
product
jacket;
and
all
other
references
were
reviewed
as
noted.
Italicized
references
reflect
TGAI
and/
or
PAI
data
for
phys/
chem
requirements
which
may
be
shared
by
Task
Force
members.
60
3
The
CSFs
for
a
basic
and
three
alternate
formulations
of
the
66.57%
FI
were
reviewed
under
Registration
Division
memorandum
D224080,
4/
10/
96,
T.
Alston.

4
D193116,
1/
24/
94,
F.
Toghrol
(
PAI
data
for
the
Dow
AgroSciences
67.1%
DMA
FI,
EPA
Reg.
No.
62719­
27).

5
Data
are
not
required
because
the
PAI
is
a
solid
at
room
temperature.

6
Data
are
not
required
because
the
DMA
salt
completely
dissociates
in
aqueous
solutions;
data
for
2,4­
D
acid
were
accepted
to
fulfill
this
requirement
under
CBRS
Nos.
5454,
5455,
5489,
5540,
5541,
5542,
5543,
and
5544,
10/
25/
89,
M.
Nelson
(
data
for
the
Dow
AgroSciences
67.1%
DMA
FI,
EPA
Reg.
No.
62719­
27).

7
Data
are
not
required
for
the
DMA
salt
TGAI
because
it
is
a
polar
organic
compound;
no
additional
data
were
required
for
this
data
requirement
under
D161051,
4/
25/
91,
R.
Perfetti
(
data
for
the
Dow
AgroSciences
67.1%
DMA
FI,
EPA
Reg.
No.
62719­
27).

8
D207979,
2/
22/
96,
D.
Miller
(
TGAI
data
for
the
Dow
AgroSciences
67.1%
DMA
FI,
EPA
Reg.
No.
62719­
27).

9
D170802,
7/
24/
92,
(
PAI
data
for
the
Dow
AgroSciences
67.1%
DMA
FI,
EPA
Reg.
No.
62719­
27).
61
Case
No.
0073
Chemical
No.
030019
Case
Name:
2,4­
D
Registrant:
PBI/
Gordon
Corporation
Product(
s):
46.4%
DMA
FI
(
EPA
Reg.
No.
2217­
654)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
3
CSF
8/
25/
81
830.1600
Description
of
materials
used
to
produce
the
product
N
830.1650
Description
of
formulation
process
N
830.1670
Discussion
of
formation
of
impurities
N
830.1700
Preliminary
analysis
N
830.1750
Certified
limits
Y
3
CSF
8/
25/
81
830.1800
Enforcement
analytical
method
N
830.6302
Color
N
830.6303
Physical
state
N
830.6304
Odor
N
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
N
830.6314
Oxidation/
reduction:
chemical
incompatibility
N
830.6315
Flammability
N
830.6316
Explodability
N
830.6317
Storage
stability
N
830.6319
Miscibility
N
830.6320
Corrosion
characteristics
N
830.7000
pH
N
830.7050
UV/
Visible
absorption
N
830.7100
Viscosity
N
830.7200
Melting
point/
melting
range
Y
42829901
4
830.7220
Boiling
point/
boiling
range
N/
A
5
830.7300
Density/
relative
density/
bulk
density
N
830.7370
Dissociation
constants
in
water
N/
A
6
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
N/
A
7
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
Y
43358801
8
830.7950
Vapor
pressure
Y
42021001
9
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
This
product
is
manufactured
from
an
EPA­
registered
acid
product;
the
registrant
must
submit
product
chemistry
data
for
the
practical
equivalent
of
the
DMA
salt
TGAI
and
for
the
manufacturing­
use
product.

2
The
CSF
obtained
from
the
product
jacket
was
reviewed
by
the
Registration
Division
under
D224080,
4/
10/
96,
T.
Alston;
and
all
other
references
were
reviewed
as
noted.
Italicized
references
reflect
TGAI
and/
or
PAI
data
for
phys/
chem
requirements
which
may
be
shared
by
Task
Force
members.
62
3
The
CSF
must
be
modified
to
reflect
the
current
registrant,
EPA
Reg.
No.,
and
sources.

4
D193116,
1/
24/
94,
F.
Toghrol
(
PAI
data
for
the
Dow
AgroSciences
67.1%
DMA
FI,
EPA
Reg.
No.
62719­
27).

5
Data
are
not
required
because
the
PAI
is
a
solid
at
room
temperature.

6
Data
are
not
required
because
the
DMA
salt
completely
dissociates
in
aqueous
solutions;
data
for
2,4­
D
acid
were
accepted
to
fulfill
this
requirement
under
CBRS
Nos.
5454,
5455,
5489,
5540,
5541,
5542,
5543,
and
5544,
10/
25/
89,
M.
Nelson
(
data
for
the
Dow
AgroSciences
67.1%
DMA
FI,
EPA
Reg.
No.
62719­
27).

7
Data
are
not
required
for
the
DMA
salt
TGAI
because
it
is
a
polar
organic
compound;
no
additional
data
were
required
for
this
data
requirement
under
D161051,
4/
25/
91,
R.
Perfetti
(
data
for
the
Dow
AgroSciences
67.1%
DMA
FI,
EPA
Reg.
No.
62719­
27).

8
D207979,
2/
22/
96,
D.
Miller
(
TGAI
data
for
the
Dow
AgroSciences
67.1%
DMA
FI,
EPA
Reg.
No.
62719­
27).

9
D170802,
7/
24/
92,
(
PAI
data
for
the
Dow
AgroSciences
67.1%
DMA
FI,
EPA
Reg.
No.
62719­
27).
63
Case
No.
0073
Chemical
No.
030019
Case
Name:
2,4­
D
Registrant:
NuFarm
Limited
Product(
s):
61.37%
DMA
FI
(
EPA
Reg.
No.
35935­
11)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
3
CSF
11/
6/
79
830.1600
Description
of
materials
used
to
produce
the
product
N
830.1650
Description
of
formulation
process
N
830.1670
Discussion
of
formation
of
impurities
N
830.1700
Preliminary
analysis
N
830.1750
Certified
limits
Y
3
CSF
11/
6/
79
830.1800
Enforcement
analytical
method
N
830.6302
Color
N
830.6303
Physical
state
N
830.6304
Odor
N
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
N
830.6314
Oxidation/
reduction:
chemical
incompatibility
N
830.6315
Flammability
N
830.6316
Explodability
N
830.6317
Storage
stability
N
830.6319
Miscibility
N
830.6320
Corrosion
characteristics
N
830.7000
pH
N
830.7050
UV/
Visible
absorption
N
830.7100
Viscosity
N
830.7200
Melting
point/
melting
range
Y
42829901
4
830.7220
Boiling
point/
boiling
range
N/
A
5
830.7300
Density/
relative
density/
bulk
density
N
830.7370
Dissociation
constants
in
water
N/
A
6
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
N/
A
7
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
Y
43358801
8
830.7950
Vapor
pressure
Y
42021001
9
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
This
product
is
manufactured
from
an
EPA­
registered
acid
product;
the
registrant
must
submit
product
chemistry
data
for
the
practical
equivalent
of
the
DMA
salt
TGAI
and
for
the
manufacturing­
use
product.

2
The
CSF
was
obtained
from
the
product
jacket;
and
all
other
references
were
reviewed
as
noted.
Italicized
references
reflect
TGAI
and/
or
PAI
data
for
phys/
chem
requirements
which
may
be
shared
by
Task
Force
members.

3
The
CSF
must
be
modified
to
reflect
the
current
registrant,
EPA
Reg.
No.,
and
source
product(
s).
64
4
D193116,
1/
24/
94,
F.
Toghrol
(
PAI
data
for
the
Dow
AgroSciences
67.1%
DMA
FI,
EPA
Reg.
No.
62719­
27).

5
Data
are
not
required
because
the
PAI
is
a
solid
at
room
temperature.

6
Data
are
not
required
because
the
DMA
salt
completely
dissociates
in
aqueous
solutions;
data
for
2,4­
D
acid
were
accepted
to
fulfill
this
requirement
under
CBRS
Nos.
5454,
5455,
5489,
5540,
5541,
5542,
5543,
and
5544,
10/
25/
89,
M.
Nelson
(
data
for
the
Dow
AgroSciences
67.1%
DMA
FI,
EPA
Reg.
No.
62719­
27).

7
Data
are
not
required
for
the
DMA
salt
TGAI
because
it
is
a
polar
organic
compound;
no
additional
data
were
required
for
this
data
requirement
under
D161051,
4/
25/
91,
R.
Perfetti
(
data
for
the
Dow
AgroSciences
67.1%
DMA
FI,
EPA
Reg.
No.
62719­
27).

8
D207979,
2/
22/
96,
D.
Miller
(
TGAI
data
for
the
Dow
AgroSciences
67.1%
DMA
FI,
EPA
Reg.
No.
62719­
27).

9
D170802,
7/
24/
92,
(
PAI
data
for
the
Dow
AgroSciences
67.1%
DMA
FI,
EPA
Reg.
No.
62719­
27).
65
Case
No.
0073
Chemical
No.
030019
Case
Name:
2,4­
D
Registrant:
NuFarm
USA,
Inc.
Product(
s):
66.18%
DMA
FI
(
EPA
Reg.
No.
61272­
8)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
CSF
1/
28/
93
830.1600
Description
of
materials
used
to
produce
the
product
N
830.1650
Description
of
formulation
process
N
830.1670
Discussion
of
formation
of
impurities
N
830.1700
Preliminary
analysis
N
830.1750
Certified
limits
Y
CSF
1/
28/
93
830.1800
Enforcement
analytical
method
N
830.6302
Color
N
830.6303
Physical
state
N
830.6304
Odor
N
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
N
830.6314
Oxidation/
reduction:
chemical
incompatibility
N
830.6315
Flammability
N
830.6316
Explodability
N
830.6317
Storage
stability
N
830.6319
Miscibility
N
830.6320
Corrosion
characteristics
N
830.7000
pH
N
830.7050
UV/
Visible
absorption
N
830.7100
Viscosity
N
830.7200
Melting
point/
melting
range
Y
42829901
3
830.7220
Boiling
point/
boiling
range
N/
A
4
830.7300
Density/
relative
density/
bulk
density
N
830.7370
Dissociation
constants
in
water
N/
A
5
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
N/
A
6
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
Y
43358801
7
830.7950
Vapor
pressure
Y
42021001
8
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
This
product
is
manufactured
from
an
EPA­
registered
acid
product;
the
registrant
must
submit
product
chemistry
data
for
the
practical
equivalent
of
the
DMA
salt
TGAI
and
for
the
manufacturing­
use
product.

2
The
CSF
was
obtained
from
the
product
jacket
and
was
reviewed
under
Registration
Division
Memorandum
D209172,
1/
17/
95,
S.
Mathur;
and
all
other
references
were
reviewed
as
noted.
Italicized
references
reflect
TGAI
and/
or
PAI
data
for
phys/
chem
requirements
which
may
be
shared
by
Task
Force
members.

3
D193116,
1/
24/
94,
F.
Toghrol
(
PAI
data
for
the
Dow
AgroSciences
67.1%
DMA
FI,
EPA
Reg.
No.
62719­
27).
66
4
Data
are
not
required
because
the
PAI
is
a
solid
at
room
temperature.

5
Data
are
not
required
because
the
DMA
salt
completely
dissociates
in
aqueous
solutions;
data
for
2,4­
D
acid
were
accepted
to
fulfill
this
requirement
under
CBRS
Nos.
5454,
5455,
5489,
5540,
5541,
5542,
5543,
and
5544,
10/
25/
89,
M.
Nelson
(
data
for
the
Dow
AgroSciences
67.1%
DMA
FI,
EPA
Reg.
No.
62719­
27).

6
Data
are
not
required
for
the
DMA
salt
TGAI
because
it
is
a
polar
organic
compound;
no
additional
data
were
required
for
this
data
requirement
under
D161051,
4/
25/
91,
R.
Perfetti
(
data
for
the
Dow
AgroSciences
67.1%
DMA
FI,
EPA
Reg.
No.
62719­
27).

7
D207979,
2/
22/
96,
D.
Miller
(
TGAI
data
for
the
Dow
AgroSciences
67.1%
DMA
FI,
EPA
Reg.
No.
62719­
27).

8
D170802,
7/
24/
92,
(
PAI
data
for
the
Dow
AgroSciences
67.1%
DMA
FI,
EPA
Reg.
No.
62719­
27).
67
Case
No.
0073
Chemical
No.
030019
Case
Name:
2,4­
D
Registrant:
Dow
AgroSciences
LLC
Product(
s):
67.1%
DMA
FI
(
EPA
Reg.
No.
62719­
27)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
N
3
41055809,
41055810,
41964401
4
830.1600
Description
of
materials
used
to
produce
the
product
Y
41055809
830.1650
Description
of
formulation
process
Y
41055809
830.1670
Discussion
of
formation
of
impurities
Y
41055809,
41964401
4,
42798101
5
830.1700
Preliminary
analysis
Y
41055810,
41964401
4,
43314701
6
830.1750
Certified
limits
N
7
41055809,
41055810,
41964401
4
830.1800
Enforcement
analytical
method
Y
41055810
830.6302
Color
Y
41055811
830.6303
Physical
state
Y
41055811
830.6304
Odor
Y
41055811
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
Y
41755701
8
830.6314
Oxidation/
reduction:
chemical
incompatibility
Y
41055811
830.6315
Flammability
Y
41055811
830.6316
Explodability
Y
41055811
830.6317
Storage
stability
Y
41055811
830.6319
Miscibility
N/
A
9
830.6320
Corrosion
characteristics
Y
41055811
830.7000
pH
Y
41055811
830.7050
UV/
Visible
absorption
N
10
830.7100
Viscosity
Y
41055811
830.7200
Melting
point/
melting
range
Y
42829901
11
830.7220
Boiling
point/
boiling
range
N/
A
12
830.7300
Density/
relative
density/
bulk
density
Y
41055811
830.7370
Dissociation
constants
in
water
N/
A
13
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
N/
A
14
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
Y
41055811,
42021002
4,
43358801
15
830.7950
Vapor
pressure
Y
42021001
4
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.

2
Bolded
references
were
reviewed
under
CB
Nos.
5454,
5455,
5489,
5540,
5541,
5542,
5543,
and
5544,
10/
25/
89,
M.
Nelson;
and
all
other
references
were
reviewed
as
noted.
68
3
Nominal
concentrations
are
required
which
reflect
the
expected
amount
of
the
impurities
in
the
final
product.

4
D170802,
7/
24/
92.

5
D192564,
9/
7/
93,
K.
Dockter.

6
D205982,
2/
14/
95,
K.
Dockter.

7
Certified
limits
are
required
for
the
active
ingredient,
and
the
registrant
must
confirm
the
certified
limits
proposed
for
the
impurities
and
confirm
the
site
of
production.

8
D161051,
4/
25/
91,
R.
Perfetti.

9
Data
are
not
required
because
the
FI
is
not
an
emulsifiable
liquid
to
be
diluted
with
petroleum
solvents.

10
The
OPPTS
Series
830,
Product
Properties
Test
Guidelines
require
data
pertaining
to
UV/
visible
absorption
for
the
PAI.

11
D193116,
1/
24/
94,
F.
Toghrol.

12
Data
are
not
required
because
the
practical
equivalent
of
the
TGAI
is
a
solid
at
room
temperature.

13
Data
are
not
required
because
the
DMA
salt
completely
dissociates
in
aqueous
solutions;
data
for
2,4­
D
acid
were
accepted
to
fulfill
this
requirement
under
CBRS
Nos.
5454,
5455,
5489,
5540,
5541,
5542,
5543,
and
5544,
10/
25/
89,
M.
Nelson
14
Data
are
not
required
for
the
DMA
salt
TGAI
because
it
is
a
polar
organic
compound;
no
additional
data
were
required
for
this
data
requirement
under
D161051,
4/
25/
91,
R.
Perfetti.

15
D207979,
2/
22/
96,
D.
Miller.
69
Case
No.
0073
Chemical
No.
030019
Case
Name:
2,4­
D
Registrant:
Dow
AgroSciences
LLC
Product(
s):
66.8%
DMA
FI
(
EPA
Reg.
No.
62719­
52)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
CSFs
4/
24/
01
830.1600
Description
of
materials
used
to
produce
the
product
N
830.1650
Description
of
formulation
process
N
830.1670
Discussion
of
formation
of
impurities
N
830.1700
Preliminary
analysis
N
830.1750
Certified
limits
Y
CSFs
4/
24/
01
830.1800
Enforcement
analytical
method
N
830.6302
Color
N
830.6303
Physical
state
N
830.6304
Odor
N
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
N
830.6314
Oxidation/
reduction:
chemical
incompatibility
N
830.6315
Flammability
N
830.6316
Explodability
N
830.6317
Storage
stability
Y
45642701
3
830.6319
Miscibility
N
830.6320
Corrosion
characteristics
Y
45642701
3
830.7000
pH
N
830.7050
UV/
Visible
absorption
N
830.7100
Viscosity
N
830.7200
Melting
point/
melting
range
Y
42829901
4
830.7220
Boiling
point/
boiling
range
N/
A
5
830.7300
Density/
relative
density/
bulk
density
N
830.7370
Dissociation
constants
in
water
N/
A
6
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
N/
A
7
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
Y
43358801
8
830.7950
Vapor
pressure
Y
42021001
9
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
This
product
is
produced
in
an
integrated
system
from
an
EPAregistered
2,4­
D
acid
product.

2
The
CSFs
for
the
basic
and
three
alternate
formulations
were
obtained
from
the
product
jacket
and
were
reviewed
by
the
Registration
Division,
letter
dated
6/
1/
01,
J.
Miller;
all
other
references
were
reviewed
as
noted.
Italicized
references
reflect
TGAI
and/
or
PAI
data
for
phys/
chem
requirements
which
may
be
shared
by
Task
Force
members
3
RD
Memorandum,
D282901,
8/
6/
02,
L.
Kutney.
70
4
D193116,
1/
24/
94,
F.
Toghrol
(
PAI
data
for
the
Dow
AgroSciences
67.1%
DMA
FI,
EPA
Reg.
No.
62719­
27).

5
Data
are
not
required
because
the
PAI
is
a
solid
at
room
temperature.

6
Data
are
not
required
because
the
DMA
salt
completely
dissociates
in
aqueous
solutions;
data
for
2,4­
D
acid
were
accepted
to
fulfill
this
requirement
under
CBRS
Nos.
5454,
5455,
5489,
5540,
5541,
5542,
5543,
and
5544,
10/
25/
89,
M.
Nelson
(
data
for
the
Dow
AgroSciences
67.1%
DMA
FI,
EPA
Reg.
No.
62719­
27).

7
Data
are
not
required
for
the
DMA
salt
TGAI
because
it
is
a
polar
organic
compound;
no
additional
data
were
required
for
this
data
requirement
under
D161051,
4/
25/
91,
R.
Perfetti
(
data
for
the
Dow
AgroSciences
67.1%
DMA
FI,
EPA
Reg.
No.
62719­
27).

8
D207979,
2/
22/
96,
D.
Miller
(
TGAI
data
for
the
Dow
AgroSciences
67.1%
DMA
FI,
EPA
Reg.
No.
62719­
27).

9
D170802,
7/
24/
92,
(
PAI
data
for
the
Dow
AgroSciences
67.1%
DMA
FI,
EPA
Reg.
No.
62719­
27).
71
Case
No.
0073
Chemical
No.
030025
Case
Name:
2,4­
D
Registrant:
Dow
AgroSciences
LLC
Product(
s):
49.9%
IPA
T
(
EPA
Reg.
No.
62719­
71)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
41055815,
41055816,
41978001
3,
44807001
4,
CSFs
5/
17/
01
5
830.1600
Description
of
materials
used
to
produce
the
product
Y
41055815
830.1620
Description
of
production
process
Y
41055815,
44727101
6,
44807001
4
830.1670
Discussion
of
formation
of
impurities
Y
41055815,
41978001
3,
42798301
7,
44727101
6,
44807001
4
830.1700
Preliminary
analysis
Y
41055816
830.1750
Certified
limits
Y
41055815,
41055816,
41978001
3,
44807001
4,
CSFs
5/
17/
01
5
830.1800
Enforcement
analytical
method
Y
41055816
830.6302
Color
Y
41055817
830.6303
Physical
state
Y
41055817
830.6304
Odor
Y
41055817
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
Y
41978002
3
830.6314
Oxidation/
reduction:
chemical
incompatibility
Y
41055817
830.6315
Flammability
Y
41055817
830.6316
Explodability
Y
41055817
830.6317
Storage
stability
Y
41055817,
43874601
8
830.6319
Miscibility
N/
A
9
830.6320
Corrosion
characteristics
Y
41055817
830.7000
pH
Y
41055817
830.7050
UV/
Visible
absorption
N
10
830.7100
Viscosity
Y
41055817
830.7200
Melting
point/
melting
range
Y
42831001
11
830.7220
Boiling
point/
boiling
range
N/
A
12
830.7300
Density/
relative
density/
bulk
density
Y
41055817
830.7370
Dissociation
constants
in
water
N/
A
13
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
N/
A
14
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
Y
41978001
3,
43358802
15
830.7950
Vapor
pressure
Y
41431101
6
72
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
This
product
is
manufactured
from
an
EPA­
registered
acid
product;
the
registrant
must
submit
product
chemistry
data
for
the
practical
equivalent
of
the
DMA
salt
TGAI
and
for
the
manufacturing­
use
product.

2
Bolded
references
were
reviewed
under
CB
Nos.
5454,
5455,
5489,
5540,
5541,
5542,
5543,
and
5544,
10/
25/
89,
M.
Nelson;
and
all
other
references
were
reviewed
as
noted.

3
D167944,
6/
30/
92,
S.
Funk.

4
RD
Memorandum,
D255728,
5/
5/
99,
S.
Mathur.

5
CSFs
dated
5/
17/
01
for
the
basic
and
three
alternate
formulations
were
obtained
from
the
product
jacket
and
reviewed
under
RD
Memorandum,
D275675,
8/
8/
01,
S.
Malak.

6
RD
Memorandum
D253591,
3/
11/
99,
S.
Mathur.

7
D192565
and
D194929,
11/
9/
93,
F.
Toghrol.

8
D221847,
3/
28/
97,
K.
Dockter.

9
Data
are
not
required
because
the
FI
is
not
an
emulsifiable
liquid
to
be
diluted
with
petroleum
solvents.

10
The
OPPTS
Series
830,
Product
Properties
Test
Guidelines
require
data
pertaining
to
UV/
visible
absorption
for
the
PAI.

11
D193112,
9/
7/
93,
K.
Dockter.

12
Data
are
not
required
because
the
practical
equivalent
of
the
TGAI
is
a
solid
at
room
temperature.

13
Data
are
not
required
because
the
IPA
salt
completely
dissociates
in
aqueous
solutions;
data
for
2,4­
D
acid
were
accepted
to
fulfill
this
requirement
under
CBRS
Nos.
5454,
5455,
5489,
5540,
5541,
5542,
5543,
and
5544,
10/
25/
89,
M.
Nelson.

14
Data
are
not
required
for
the
IPA
salt
TGAI
because
it
is
a
polar
organic
compound;
no
additional
data
were
required
for
this
data
requirement
under
D167944,
6/
30/
92,
S.
Funk.

15
D207979,
2/
22/
96,
D.
Miller.
73
Case
No.
0073
Chemical
No.
030035
Case
Name:
2,4­
D
Registrant:
Dow
AgroSciences
LLC
Product(
s):
71%
TIPA
FI
(
EPA
Reg.
No.
62719­
180)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
41055818,
41055819,
CSF
7/
9/
98
3
830.1600
Description
of
materials
used
to
produce
the
product
Y
41055818
830.1620
Description
of
production
process
Y
41055818,
44228301
4
830.1670
Discussion
of
formation
of
impurities
Y
41055818,
42798201
5,
44228301
4
830.1700
Preliminary
analysis
Y
41055819,
44620501
3
830.1750
Certified
limits
Y
41055818,
41055819,
CSF
7/
9/
98
3
830.1800
Enforcement
analytical
method
Y
41055819
830.6302
Color
Y
41055820
830.6303
Physical
state
Y
41055820
830.6304
Odor
Y
41055820
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
N
830.6314
Oxidation/
reduction:
chemical
incompatibility
Y
41055820
830.6315
Flammability
Y
41055820
830.6316
Explodability
Y
41055820
830.6317
Storage
stability
Y
41055820
830.6319
Miscibility
N/
A
6
830.6320
Corrosion
characteristics
Y
41055820
830.7000
pH
Y
41055820
830.7050
UV/
Visible
absorption
N
7
830.7100
Viscosity
Y
41055820
830.7200
Melting
point/
melting
range
Y
43325003
8
830.7220
Boiling
point/
boiling
range
N/
A
9
830.7300
Density/
relative
density/
bulk
density
Y
41055820
830.7370
Dissociation
constants
in
water
N/
A
10
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
N/
A
11
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
N
830.7950
Vapor
pressure
N
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
This
product
is
manufactured
from
an
EPA­
registered
acid
product;
the
registrant
must
submit
product
chemistry
data
for
the
practical
equivalent
of
the
DMA
salt
TGAI
and
for
the
manufacturing­
use
product.

2
Bolded
references
were
reviewed
under
CB
Nos.
5454,
5455,
5489,
5540,
5541,
5542,
5543,
and
5544,
10/
25/
89,
M.
Nelson;
and
all
other
references
were
reviewed
as
noted.
74
3
Registration
Division
Memorandum,
D250352,
10/
27/
98,
S.
Mathur.

4
Registration
Division
Memorandum,
D240644,
2/
9/
98,
S.
Mathur.

5
D192562,
9/
7/
93,
K.
Dockter.

6
Data
are
not
required
because
the
FI
is
not
an
emulsifiable
liquid
to
be
diluted
with
petroleum
solvents.

7
The
OPPTS
Series
830,
Product
Properties
Test
Guidelines
require
data
pertaining
to
UV/
visible
absorption
for
the
PAI.

8
D207072,
9/
29/
94,
F.
Toghrol.

9
Data
are
not
required
because
the
practical
equivalent
of
the
TGAI
is
a
solid
at
room
temperature.

10
Data
are
not
required
because
the
TIPA
salt
completely
dissociates
in
aqueous
solutions;
data
for
2,4­
D
acid
were
accepted
to
fulfill
this
requirement
under
CBRS
Nos.
5454,
5455,
5489,
5540,
5541,
5542,
5543,
and
5544,
10/
25/
89,
M.
Nelson.

11
The
Agency
has
determined
that
data
are
not
required
for
the
TIPA
salt
TGAI
because
it
is
a
polar
organic
compound
75
Case
No.
0073
Chemical
No.
030053
Case
Name:
2,4­
D
Registrant:
NuFarm
Americas,
Inc.
Product(
s):
94%
BEE
T
(
EPA
Reg.
No.
228­
136)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
N
CSF
11/
5/
79
830.1600
Description
of
materials
used
to
produce
the
product
N
830.1620
Description
of
production
process
N
830.1670
Discussion
of
formation
of
impurities
N
830.1700
Preliminary
analysis
N
830.1750
Certified
limits
N
CSF
11/
5/
79
830.1800
Enforcement
analytical
method
N
830.6302
Color
N
830.6303
Physical
state
N
830.6304
Odor
N
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
Y
42487901
3
830.6314
Oxidation/
reduction:
chemical
incompatibility
N
830.6315
Flammability
N
830.6316
Explodability
N
830.6317
Storage
stability
N
830.6319
Miscibility
N
830.6320
Corrosion
characteristics
N
830.7000
pH
N
830.7050
UV/
Visible
absorption
N
830.7100
Viscosity
N
830.7200
Melting
point/
melting
range
N/
A
4
830.7220
Boiling
point/
boiling
range
Y
43325001
5
830.7300
Density/
relative
density/
bulk
density
N
830.7370
Dissociation
constants
in
water
N
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
Y
Letter
6
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
Y
41669501
7,
42830901
8
830.7950
Vapor
pressure
Y
41431301
9
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.

2
The
CSF
was
obtained
from
the
product
jacket;
and
all
other
references
were
reviewed
as
noted.
Italicized
references
reflect
TGAI
and/
or
PAI
data
for
phys/
chem
requirements
which
may
be
shared
by
Task
Force
members.

3
D183498,
3/
3/
93,
K.
Dockter
(
TGAI
data
for
the
Dow
AgroSciences
94.5%
BEE
T,
EPA
Reg.
No.
62719­
33).

4
Data
are
not
required
because
the
TGAI
is
a
liquid
at
room
temperature.
76
5
D207072,
9/
29/
94,
F.
Toghrol
(
TGAI
data
for
the
Dow
AgroSciences
94.5%
BEE
T,
EPA
Reg.
No.
62719­
33).

6
D161373,
4/
16/
91,
W.
Smith
(
PAI
data
for
the
Dow
AgroSciences
94.5%
BEE
T,
EPA
Reg.
No.
62719­
33).

7
CB
7545,
2/
19/
91,
H.
Fonouni
(
PAI
data
for
the
Dow
AgroSciences
94.5%
BEE
T,
EPA
Reg.
No.
62719­
33).

8
D193113,
1/
26/
94,
F.
Toghrol
(
PAI
data
for
the
Dow
AgroSciences
94.5%
BEE
T,
EPA
Reg.
No.
62719­
33).

9
D175586,
7/
23/
92,
S.
Funk
(
PAI
data
for
the
Dow
AgroSciences
94.5%
BEE
T,
EPA
Reg.
No.
62719­
33).
77
Case
No.
0073
Chemical
No.
030053
Case
Name:
2,4­
D
Registrant:
Dow
AgroSciences
LLC
Product(
s):
94.5%
BEE
T
(
EPA
Reg.
No.
62719­
33)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
41055812,
41055813,
41961301
3,
CSF
5/
26/
98
4
830.1600
Description
of
materials
used
to
produce
the
product
Y
41055812,
44584501
4
830.1620
Description
of
production
process
Y
41055812,
44584501
4
830.1670
Discussion
of
formation
of
impurities
Y
41055812,
41961301
3,
44584501
4
830.1700
Preliminary
analysis
N
5
41055813
830.1750
Certified
limits
Y
41055812,
41055813,
41961301
3,
CSF
5/
26/
98
4
830.1800
Enforcement
analytical
method
Y
41055813
830.6302
Color
Y
41055814
830.6303
Physical
state
Y
41055814
830.6304
Odor
Y
41055814
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
Y
42487901
6
830.6314
Oxidation/
reduction:
chemical
incompatibility
Y
41055814
830.6315
Flammability
Y
41055814
830.6316
Explodability
Y
41055814
830.6317
Storage
stability
Y
41055814
830.6319
Miscibility
N/
A
7
830.6320
Corrosion
characteristics
Y
41055814
830.7000
pH
N
830.7050
UV/
Visible
absorption
N
9
830.7100
Viscosity
Y
41055814
830.7200
Melting
point/
melting
range
N/
A
10
830.7220
Boiling
point/
boiling
range
Y
42830901
11,
43325001
12
830.7300
Density/
relative
density/
bulk
density
Y
41055814
830.7370
Dissociation
constants
in
water
N
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
Y
41647001
13,
Letter
14
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
Y
41669501
15,
42830901
11
830.7950
Vapor
pressure
Y
41431301
16
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.

2
Bolded
references
were
reviewed
under
CB
Nos.
5454,
5455,
5489,
5540,
5541,
5542,
5543,
and
5544,
10/
25/
89,
M.
Nelson;
and
all
other
references
were
reviewed
as
noted.
78
3
Initially
reviewed
under
CB
Nos.
8426,
8430,
and
8433,
9/
8/
92,
F.
Toghrol;
and
re­
evaluated
under
D189600,
3/
11/
94,
F.
Toghrol.

4
Registration
Division
Memorandum,
D247475,
7/
24/
98,
A.
Smith.

5
Adequate
preliminary
analysis
data
have
been
submitted;
however,
the
registrant
must
either
conduct
analysis
of
seven
batches
of
the
technical
product
for
dioxins
and
dibenzofurans
or
present
information
to
show
that
dioxins/
dibenzofurans
will
not
form
during
manufacture.

6
D183498,
3/
3/
93,
K.
Dockter.

7
Data
are
not
required
because
the
T
is
not
an
emulsifiable
liquid
to
be
diluted
with
petroleum
solvents.

8
Data
are
not
required
because
the
BEE
TGAI
is
an
organic
liquid
which
can
not
be
diluted
or
dispersed
in
water.

9
The
OPPTS
Series
830,
Product
Properties
Test
Guidelines
require
data
pertaining
to
UV/
visible
absorption
for
the
PAI.

10
Data
are
not
required
because
the
T/
TGAI
is
a
liquid
at
room
temperature.

11
D193113,
1/
26/
94,
F.
Toghrol.

12
D207072,
9/
29/
94,
F.
Toghrol.

13
CB
No.
7206,
11/
21/
90,
H.
Fonouni.

14
D161373,
4/
16/
91,
W.
Smith.

15
CB
No.
7545,
2/
19/
91,
H.
Fonouni.

16
D175586,
7/
23/
92,
S.
Funk.
79
Case
No.
0073
Chemical
No.
030063
Case
Name:
2,4­
D
Registrant:
PBI/
Gordon
Corporation
Product(
s):
93.3%
2­
EHE
T
(
EPA
Reg.
No.
2217­
706)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
CSF
2/
1/
00
830.1600
Description
of
materials
used
to
produce
the
product
Y
44963803
3
830.1620
Description
of
production
process
Y
44963803
3
830.1670
Discussion
of
formation
of
impurities
Y
44963803
3
830.1700
Preliminary
analysis
Y
44963801
3
830.1750
Certified
limits
Y
44963804
3,
CSF
2/
1/
00
830.1800
Enforcement
analytical
method
Y
44963804
3
830.6302
Color
Y
44963802
3
830.6303
Physical
state
Y
44963802
3
830.6304
Odor
Y
44963802
3
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
Y
41968303
4,
44963802
3
830.6314
Oxidation/
reduction:
chemical
incompatibility
N
830.6315
Flammability
N
830.6316
Explodability
N
830.6317
Storage
stability
N
830.6319
Miscibility
N
830.6320
Corrosion
characteristics
N
830.7000
pH
Y
CSF
3
830.7050
UV/
Visible
absorption
N
5
830.7100
Viscosity
N
830.7200
Melting
point/
melting
range
N/
A
6
830.7220
Boiling
point/
boiling
range
Y
44963802
3
830.7300
Density/
relative
density/
bulk
density
Y
44963802
3
830.7370
Dissociation
constants
in
water
Y
41332009
7
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
Y
44963802
3
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
Y
42831101
8,
44963802
3
830.7950
Vapor
pressure
Y
44963802
3
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.

2
The
CSF
dated
2/
1/
00
was
obtained
from
the
product
jacket
and
reviewed
by
the
Registration
Division,
letter
dated
2/
14/
00,
from
J.
Miller
(
RD)
to
C.
Martens
of
PBI/
Gordon
Corporation;
all
other
references
were
reviewed
as
noted.
Italicized
references
reflect
TGAI
and/
or
PAI
data
for
phys/
chem
requirements
which
may
be
shared
by
Task
Force
members
3
RD
Letter
dated
1/
18/
00,
from
J.
Miller
(
RD)
to
C.
Martens
of
PBI/
Corporation.
80
4
D167642,
D167684,
and
D167644,
9/
8/
92,
F.
Toghrol
(
TGAI
data
for
the
Dow
AgroSciences
95.4%
2­
EHE
T,
EPA
Reg.
No.
62719­
26).

5
The
OPPTS
Series
830,
Product
Properties
Test
Guidelines
require
data
pertaining
to
UV/
visible
absorption
for
the
PAI.

6
Data
are
not
required
because
the
TGAI
is
a
liquid
at
room
temperature.

7
CB
6581,
7/
27/
90,
G.
Makhijani
(
Task
Force
submission).

8
D193115,
11/
24/
93,
F.
Toghrol
(
TGAI
data
for
the
Dow
AgroSciences
95.4%
2­
EHE
T,
EPA
Reg.
No.
62719­
26).
81
Case
No.
0073
Chemical
No.
030063
Case
Name:
2,4­
D
Registrant:
NuFarm
Limited
Product(
s):
94%
2­
EHE
T
(
EPA
Reg.
No.
35935­
12)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
N
3
CSF
12/
27/
88
(
basic)
CSF
12/
20/
88
(
alternate)
830.1600
Description
of
materials
used
to
produce
the
product
N
830.1620
Description
of
production
process
N
830.1670
Discussion
of
formation
of
impurities
N
830.1700
Preliminary
analysis
N
830.1750
Certified
limits
N
3
CSF
12/
27/
88
(
basic)
CSF
12/
20/
88
(
alternate)
830.1800
Enforcement
analytical
method
N
830.6302
Color
N
830.6303
Physical
state
N
830.6304
Odor
N
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
Y
41968303
4
830.6314
Oxidation/
reduction:
chemical
incompatibility
N
830.6315
Flammability
N
830.6316
Explodability
N
830.6317
Storage
stability
N
830.6319
Miscibility
N
830.6320
Corrosion
characteristics
N
830.7000
pH
N
830.7050
UV/
Visible
absorption
N
830.7100
Viscosity
N
830.7200
Melting
point/
melting
range
N/
A
5
830.7220
Boiling
point/
boiling
range
Y
43325002
6,
44963802
7
830.7300
Density/
relative
density/
bulk
density
N
830.7370
Dissociation
constants
in
water
Y
41332009
8
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
Y
41055808
9,
44963802
7
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
Y
41055808
9,
42831101
10,
44963802
7
830.7950
Vapor
pressure
Y
41055808
9,
44963802
7
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
This
product
is
manufactured
from
EPA­
registered
acid
products;
the
registrant
must
submit
product
chemistry
for
the
practical
equivalent
of
the
2­
EHE
TGAI
and
for
the
manufacturing­
use
product.

2
The
CSFs
were
obtained
from
the
product
jacket;
and
all
other
references
were
reviewed
as
noted.
Italicized
references
reflect
TGAI
and/
or
PAI
data
for
phys/
chem
requirements
which
may
be
shared
by
Task
Force
members.
82
3
We
note
that
the
source
of
the
technical
acid
cited
for
the
alternate
formulation
has
been
canceled;
the
CSFs
for
the
basic
and
alternate
formulations
must
be
revised
to
reflect
the
current
registrant,
EPA
Reg.
Nos.,
and
sources.

4
D167642,
D167684,
and
D167644,
9/
8/
92,
F.
Toghrol
(
TGAI
data
for
the
Dow
AgroSciences
95.4%
2­
EHE
T,
EPA
Reg.
No.
62719­
26).

5
Data
are
not
required
because
the
TGAI
is
a
liquid
at
room
temperature.

6
D207072,
9/
29/
94,
F.
Toghrol
(
TGAI
data
for
the
Dow
AgroSciences
95.4%
2­
EHE
T,
EPA
Reg.
No.
62719­
26).

7
Registration
Division
Letter
dated
1/
18/
00
(
TGAI
data
for
the
PBI/
Gordon
93.3%
2­
EHE
T,
EPA
Reg.
No.
2217­
706).

8
CB
6581,
7/
27/
90,
G.
Makhijani
(
Task
Force
submission).

9
CB
5454,
5455,
5489,
5540,
5541,
5542,
5543,
and
5544,
10/
25/
89,
M.
Nelson
(
PAI
data
for
the
Dow
AgroSciences
95.4%
2­
EHE
T,
EPA
Reg.
No.
62719­
26).

10
D193115,
11/
24/
93,
F.
Toghrol
(
TGAI
data
for
the
Dow
AgroSciences
95.4%
2­
EHE
T,
EPA
Reg.
No.
62719­
26).
83
Case
No.
0073
Chemical
No.
030063
Case
Name:
2,4­
D
Registrant:
Atanor
S.
A.
Product(
s):
93.3%
2­
EHE
Ts
(
EPA
Reg.
Nos.
46146­
4
and
46146­
5)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
N
3
CSFs
11/
21/
00
4,
Letters
5
830.1600
Description
of
materials
used
to
produce
the
product
N
830.1620
Description
of
production
process
N
830.1670
Discussion
of
formation
of
impurities
N
830.1700
Preliminary
analysis
N
830.1750
Certified
limits
N
3
CSFs
11/
21/
00
4,
Letters
5
830.1800
Enforcement
analytical
method
Y
44963804
830.6302
Color
Y
44963802
830.6303
Physical
state
Y
44963802
830.6304
Odor
Y
44963802
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
Y
44963802
830.6314
Oxidation/
reduction:
chemical
incompatibility
N
830.6315
Flammability
N
830.6316
Explodability
N
830.6317
Storage
stability
N
830.6319
Miscibility
N
830.6320
Corrosion
characteristics
N
830.7000
pH
Y
CSF
830.7050
UV/
Visible
absorption
N
6
830.7100
Viscosity
N
830.7200
Melting
point/
melting
range
N/
A
7
830.7220
Boiling
point/
boiling
range
Y
44963802
830.7300
Density/
relative
density/
bulk
density
Y
44963802
830.7370
Dissociation
constants
in
water
N
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
Y
44963802
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
N
8
44963802
830.7950
Vapor
pressure
Y
44963802
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
According
to
letters
located
in
the
product
jackets
(
dated
4/
8/
83
for
46146­
4
and
2/
13/
03
for
46146­
5,
from
J.
Miller,
RD,
to
E.
Finkel,
Agent
for
Atanor
S.
A.),
registrations
of
both
products
were
suspended
1/
9/
89
by
the
Office
of
Compliance
and
Monitoring
(
OCM)
for
failure
of
then
registrant,
Inter
Ag
Corp.,
to
submit
data.
Agency
records
do
not
show
that
the
suspensions
have
been
lifted,
and
the
Agency
has
determined
that
any
further
processing
of
applications
pertaining
to
these
products
is
on
hold
until
the
registrations
have
been
taken
out
of
suspension.

These
products
are
manufactured
from
EPA­
registered
acid
products;
the
registrant
must
submit
product
chemistry
data
for
the
practical
equivalent
of
the
2­
EHE
TGAI
and
for
the
manufacturing­
use
product.
The
registrant
is
84
requesting
"
me­
too"
registration
for
the
products,
claiming
similarity
to
EPA
Reg.
No.
2217­
706.
The
Agency
has
agreed
(
RD
Memoranda,
D288431,
H.
Podall,
4/
7/
03,
for
46146­
4
and
D288281,
4/
8/
03,
S.
Malak,
for
46146­
5)
that
the
proposed
basic
formulations
for
both
products
are
substantially
similar
to
EPA
Reg.
No.
2217­
706,
but
that
minimum
data
requirements
must
be
met
(
830.1600,
1620,
1670,
1700,
and
1750)
for
me­
too
registration
of
the
Atanor
Ts.
The
referenced
PBI/
Gordon
data
(
MRIDs
44963801,
­
02,
­
04,
pertaining
to
the
analytical
method
and
physical/
chemical
properties
will
support
a
FIFRA
sec.
3(
c)(
3)(
b)(
i)(
I)
"
me­
too"
registration
(
RD
Memorandums
D286092
for
46146­
4,
and
D286090
for
46146­
5,
11/
25/
02,
S.
Malak).

2
Bolded
references
were
submitted
by
PBI/
Gordon
(
for
the
93.3%
2­
EHE
T,
EPA
Reg.
No.
2217­
706)
and
reviewed
by
the
Registration
Division,
letter
dated
1/
18/
00,
from
J.
Miller
(
RD)
to
C.
Martens
of
PBI/
Corporation;
and
all
other
references
were
reviewed
as
noted.

3
The
CSFs
cannot
be
evaluated
until
the
outstanding
data
concerning
the
manufacturing
process
and
preliminary
analysis
of
the
TGAI
are
submitted.

4
Registration
Division
Memoranda
D286092
for
46146­
4,
and
D286090
for
46146­
5,
11/
25/
02,
S.
Malak.

5
Registration
Division
Memoranda
D288431,
H.
Podall,
4/
7/
03,
for
46146­
4
and
D288281,
4/
8/
03,
S.
Malak,
for
46146­
5.

6
The
OPPTS
Series
830,
Product
Properties
Test
Guidelines
require
data
pertaining
to
UV/
visible
absorption
for
the
PAI.

7
Data
are
not
required
because
the
T/
TGAI
is
a
liquid
at
room
temperature.

8
Additional
data
are
required
reflecting
solubility
in
solvents
other
than
water.
85
Case
No.
0073
Chemical
No.
030063
Case
Name:
2,4­
D
Registrant:
NuFarm
USA,
Inc.
Product(
s):
98%
2­
EHE
T
(
EPA
Reg.
No.
61272­
1)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
3
CSF
5/
14/
76
4
830.1600
Description
of
materials
used
to
produce
the
product
N
830.1620
Description
of
production
process
N
830.1670
Discussion
of
formation
of
impurities
N
830.1700
Preliminary
analysis
N
5
41349002,
41724201
6,
41724203
6
830.1750
Certified
limits
N
3,
7
CSF
5/
14/
76
830.1800
Enforcement
analytical
method
N
830.6302
Color
N
830.6303
Physical
state
N
830.6304
Odor
N
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
Y
41968303
8
830.6314
Oxidation/
reduction:
chemical
incompatibility
N
830.6315
Flammability
N
830.6316
Explodability
N
830.6317
Storage
stability
N
830.6319
Miscibility
N
830.6320
Corrosion
characteristics
N
830.7000
pH
N
830.7050
UV/
Visible
absorption
N
830.7100
Viscosity
N
830.7200
Melting
point/
melting
range
N/
A
9
830.7220
Boiling
point/
boiling
range
Y
43325002
10,
44963802
11
830.7300
Density/
relative
density/
bulk
density
N
830.7370
Dissociation
constants
in
water
Y
41332009
12
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
Y
41055808
13,
44963802
14
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
Y
41055808
13,
42831101
15,
44963802
14
830.7950
Vapor
pressure
Y
41055808
13,
44963802
14
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.

2
The
bolded
MRID
reference
was
reviewed
under
CB
No.
6295,
5/
24/
90,
S.
Funk;
and
all
other
references
were
reviewed
as
noted.
Italicized
references
reflect
TGAI
and/
or
PAI
data
for
phys/
chem
requirements
which
may
be
shared
by
Task
Force
members
3
The
CSF
must
be
revised
to
reflect
the
current
registrant
and
EPA
Reg.
No.
86
4
The
CSF
was
obtained
from
the
product
jacket.

5
Additional
information
concerning
the
sampling
dates
and
methods
are
required
to
support
the
submitted
dioxin/
dibenzofuran
analyses;
preliminary
analysis
of
all
ingredients
of
the
TGAI
present
at

0.1%
is
required.

6
D160163,
11/
26/
91,
S.
Funk
for
the
dioxins
6/
87
DCI
unless
otherwise
noted.
The
CSF
was
obtained
from
the
product
jacket
and
must
be
revised
to
reflect
the
current
registrant
and
EPA
Reg.
No.

7
The
CSF
must
be
revised
to
incorporate
the
results
of
the
dioxin
analyses;
upper
certified
limits
must
be
proposed
for
any
dioxin
and/
or
dibenzofuran
compounds
present
at
greater
than
the
respective
EPA
LOQs.

8
D167642,
D167684,
and
D167644,
9/
8/
92,
F.
Toghrol
(
TGAI
data
for
the
Dow
AgroSciences
95.4%
2­
EHE
T,
EPA
Reg.
No.
62719­
26).

9
Data
are
not
required
because
the
TGAI
is
a
liquid
at
room
temperature.

10
D207072,
9/
29/
94,
F.
Toghrol
(
TGAI
data
for
the
Dow
AgroSciences
95.4%
2­
EHE
T,
EPA
Reg.
No.
62719­
26).

11
Registration
Division
Letter
dated
1/
18/
00
(
TGAI
data
for
the
PBI/
Gordon
93.3%
2­
EHE
T,
EPA
Reg.
No.
2217­
706).

12
CB
6581,
7/
27/
90,
G.
Makhijani
(
Task
Force
submission).

13
CB
5454,
5455,
5489,
5540,
5541,
5542,
5543,
and
5544,
10/
25/
89,
M.
Nelson
(
PAI
data
for
the
Dow
AgroSciences
95.4%
2­
EHE
T,
EPA
Reg.
No.
62719­
26).

14
Registration
Division
Letter
dated
1/
18/
00
(
TGAI
data
for
the
PBI/
Gordon
93.3%
2­
EHE
T,
EPA
Reg.
No.
2217­
706).

15
D193115,
11/
24/
93,
F.
Toghrol
(
TGAI
data
for
the
Dow
AgroSciences
95.4%
2­
EHE
T,
EPA
Reg.
No.
62719­
26).
87
Case
No.
0073
Chemical
No.
030063
Case
Name:
2,4­
D
Registrant:
NuFarm
USA,
Inc.
Product(
s):
95%
2­
EHE
T
(
EPA
Reg.
No.
61272­
7)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
CSF
2/
28/
92
830.1600
Description
of
materials
used
to
produce
the
product
N
830.1620
Description
of
production
process
N
830.1670
Discussion
of
formation
of
impurities
N
830.1700
Preliminary
analysis
N
830.1750
Certified
limits
Y
CSF
2/
28/
92
830.1800
Enforcement
analytical
method
N
830.6302
Color
N
830.6303
Physical
state
N
830.6304
Odor
N
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
Y
41968303
3
830.6314
Oxidation/
reduction:
chemical
incompatibility
N
830.6315
Flammability
N
830.6316
Explodability
N
830.6317
Storage
stability
N
830.6319
Miscibility
N
830.6320
Corrosion
characteristics
N
830.7000
pH
N
830.7050
UV/
Visible
absorption
N
830.7100
Viscosity
N
830.7200
Melting
point/
melting
range
N/
A
4
830.7220
Boiling
point/
boiling
range
Y
43325002
5,
44963802
6
830.7300
Density/
relative
density/
bulk
density
N
830.7370
Dissociation
constants
in
water
Y
41332009
7
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
Y
41055808
8,
44963802
9
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
Y
41055808
8,
42831101
10,
44963802
9
830.7950
Vapor
pressure
Y
41055808
8,
44963802
9
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
This
product
is
manufactured
from
EPA­
registered
acid
products;
the
registrant
must
submit
product
chemistry
data
for
the
practical
equivalent
of
the
2­
EHE
TGAI
and
for
the
manufacturing­
use
product.

2
The
CSF
was
obtained
from
the
product
jacket
and
was
reviewed
under
Registration
Division
Memorandum,
D179920,
7/
30/
92,
D.
Kenny;
and
all
other
references
were
reviewed
as
noted.
Italicized
references
reflect
TGAI
and/
or
PAI
data
for
phys/
chem
requirements
which
may
be
shared
by
Task
Force
members.
88
3
D167642,
D167684,
and
D167644,
9/
8/
92,
F.
Toghrol
(
TGAI
data
for
the
Dow
AgroSciences
95.4%
2­
EHE
T,
EPA
Reg.
No.
62719­
26).

4
Data
are
not
required
because
the
TGAI
is
a
liquid
at
room
temperature.

5
D207072,
9/
29/
94,
F.
Toghrol
(
TGAI
data
for
the
Dow
AgroSciences
95.4%
2­
EHE
T,
EPA
Reg.
No.
62719­
26).

6
Registration
Division
Letter
dated
1/
18/
00
(
TGAI
data
for
the
PBI/
Gordon
93.3%
2­
EHE
T,
EPA
Reg.
No.
2217­
706).

7
CB
6581,
7/
27/
90,
G.
Makhijani
(
Task
Force
submission).

8
CB
5454,
5455,
5489,
5540,
5541,
5542,
5543,
and
5544,
10/
25/
89,
M.
Nelson
(
PAI
data
for
the
Dow
AgroSciences
95.4%
2­
EHE
T,
EPA
Reg.
No.
62719­
26).

9
Registration
Division
Letter
dated
1/
18/
00
(
TGAI
data
for
the
PBI/
Gordon
93.3%
2­
EHE
T,
EPA
Reg.
No.
2217­
706).

10
D193115,
11/
24/
93,
F.
Toghrol
(
TGAI
data
for
the
Dow
AgroSciences
95.4%
2­
EHE
T,
EPA
Reg.
No.
62719­
26).
89
Case
No.
0073
Chemical
No.
030063
Case
Name:
2,4­
D
Registrant:
Dow
AgroSciences
LLC
Product(
s):
95.4%
2­
EHE
T
(
EPA
Reg.
No.
62719­
26)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
N
3
41055806,
41055807,
41968301
4,
CSF
5/
17/
01
(
basic)
5,
CSF
5/
25/
01
(
alternate)
5
830.1600
Description
of
materials
used
to
produce
the
product
Y
41055806,
44982101
6
830.1620
Description
of
production
process
Y
41055806,
44982101
6
830.1670
Discussion
of
formation
of
impurities
Y
41055806,
41968301
4,
44982101
6
830.1700
Preliminary
analysis
Y
41055807,
45014801
7
830.1750
Certified
limits
N
8
41055806,
41055807,
41968301
4,
CSF
5/
17/
01
(
basic)
5,
CSF
5/
25/
01
(
alternate)
5
830.1800
Enforcement
analytical
method
Y
41055807,
44982102
6
830.6302
Color
Y
41055808
830.6303
Physical
state
Y
41055808
830.6304
Odor
Y
41055808
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
Y
41968303
4
830.6314
Oxidation/
reduction:
chemical
incompatibility
Y
41055808
830.6315
Flammability
Y
41055808
830.6316
Explodability
Y
41055808
830.6317
Storage
stability
Y
41055808
830.6319
Miscibility
N
830.6320
Corrosion
characteristics
Y
41055808
830.7000
pH
N/
A
9
830.7050
UV/
Visible
absorption
N
10
830.7100
Viscosity
Y
41055808
830.7200
Melting
point/
melting
range
N/
A
11
830.7220
Boiling
point/
boiling
range
Y
42831101
12,
43325002
13
830.7300
Density/
relative
density/
bulk
density
Y
41055808
830.7370
Dissociation
constants
in
water
Y
41332009
14
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
Y
41055808
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
Y
41055808,
41968302
4,
42831101
12
830.7950
Vapor
pressure
Y
41055808
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
90
2
Bolded
references
were
reviewed
under
CB
Nos.
5454,
5455,
5489,
5540,
5541­
5544,
10/
25/
89,
M.
Nelson;
and
all
other
references
were
reviewed
as
noted.
Italicized
references
reflect
TGAI
and/
or
PAI
data
for
phys/
chem
requirements
which
may
be
shared
by
Task
Force
members.

3
The
referenced
"
reacted
and
unreacted
impurities
in
2,4­
D
acid
and
other
2,4­
D
esters
associated
with
the
manufacturing
process"
must
be
listed
on
the
CSFs,
and
nominal
concentrations
must
be
included
for
each
impurity
present
at

0.1%
or
of
toxicological
concern.

4
D167642,
D167684,
and
D167644,
9/
8/
92,
F.
Toghrol.

5
RD
Memorandum,
D275778,
8/
8/
01,
S.
Malak.

6
RD
Memorandum,
D261587,
1/
11/
00,
S.
Mathur.

7
RD
Memorandum,
D262746,
4/
18/
00,
B.
Kitchens.

8
Upper
certified
limits
must
be
proposed
for
each
individual
impurity
present
at

0.1%
or
of
toxicological
concern,
and
a
lower
certified
limit
must
be
proposed
for
an
unreacted
starting
material
which
has
pesticidal
activity.

9
Data
are
not
required
because
the
TGAI
is
not
dispersible
in
water.

10
The
OPPTS
Series
830,
Product
Properties
Test
Guidelines
require
data
pertaining
to
UV/
visible
absorption
for
the
PAI.

11
Data
are
not
applicable
because
the
TGAI
is
a
liquid
at
room
temperature.

12
D193115,
11/
24/
93,
F.
Toghrol.

13
D207072,
9/
29/
94,
F.
Toghrol.

14
CB
No.
6581,
7/
27/
90,
G.
Makhijani
(
Task
Force
submission).
91
Case
No.
0073
Chemical
No.
030063
Case
Name:
2,4­
D
Registrant:
GroWell
Limited
Product(
s):
93.3%
2­
EHE
T
(
EPA
Reg.
No.
73754­
2)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
3
CSF
11/
15/
02
830.1600
Description
of
materials
used
to
produce
the
product
N/
A
830.1620
Description
of
production
process
N/
A
830.1670
Discussion
of
formation
of
impurities
N/
A
830.1700
Preliminary
analysis
N/
A
830.1750
Certified
limits
Y
3
CSF
11/
15/
02
830.1800
Enforcement
analytical
method
N/
A
830.6302
Color
N/
A
830.6303
Physical
state
N/
A
830.6304
Odor
N/
A
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
N/
A
830.6314
Oxidation/
reduction:
chemical
incompatibility
N/
A
830.6315
Flammability
N/
A
830.6316
Explodability
N/
A
830.6317
Storage
stability
N/
A
830.6319
Miscibility
N/
A
830.6320
Corrosion
characteristics
N/
A
830.7000
pH
N/
A
830.7050
UV/
Visible
absorption
N/
A
830.7100
Viscosity
N/
A
830.7200
Melting
point/
melting
range
N/
A
830.7220
Boiling
point/
boiling
range
N/
A
830.7300
Density/
relative
density/
bulk
density
N/
A
830.7370
Dissociation
constants
in
water
N/
A
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
N/
A
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
N/
A
830.7950
Vapor
pressure
N/
A
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.
This
product
is
repackaged
from
an
EPA­
registered
product;
all
product
chemistry
data
requirements
will
be
fulfilled
by
data
for
the
source
product.
2
The
CSF
was
obtained
from
the
product
jacket
and
was
accepted
11/
25/
02.
3
The
CSF
must
be
revised
to
reflect
the
nominal
concentration
and
certified
limits
of
the
active
ingredient
in
the
product,
based
on
the
actual
amount
of
active
ingredient
in
the
source
product.
92
Case
No.
0073
Chemical
No.
030066
Case
Name:
2,4­
D
Registrant:
Amvac
Chemical
Corporation
Product(
s):
95%
IPE
T
(
EPA
Reg.
No.
5481­
144)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
41015001,
42188601
3,
42786501
4,
Letter
7/
8/
94
5
830.1600
Description
of
materials
used
to
produce
the
product
Y
41015001,
42188601
3
830.1620
Description
of
production
process
Y
41015001,
42188601
3
830.1670
Discussion
of
formation
of
impurities
Y
41015001,
42188601
3,
42786501
4
830.1700
Preliminary
analysis
Y
41015002,
42188601
3
830.1750
Certified
limits
Y
41015001,
42188601
3
830.1800
Enforcement
analytical
method
Y
41015002,
42188601
3,
42786501
4
830.6302
Color
Y
41015003
830.6303
Physical
state
Y
41015003
830.6304
Odor
Y
41015003
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
Y
41015003,
42116702
3,
42786501
4
830.6314
Oxidation/
reduction:
chemical
incompatibility
Y
42786501
4
830.6315
Flammability
Y
41015003
830.6316
Explodability
Y
41015003
830.6317
Storage
stability
Y
41015003,
42786501
4
830.6319
Miscibility
N/
A
6
830.6320
Corrosion
characteristics
Y
41015003
830.7000
pH
Y
41015003
830.7050
UV/
Visible
absorption
N
7
830.7100
Viscosity
Y
41015003
830.7200
Melting
point/
melting
range
N/
A
8
830.7220
Boiling
point/
boiling
range
Y
41015003
830.7300
Density/
relative
density/
bulk
density
Y
41015003
830.7370
Dissociation
constants
in
water
Y
41015003
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
Y
41015003,
42116702
3
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
Y
41015003,
42116702
3,
42786501
4,
43302001
9,
Letter
2/
22/
95
10
830.7950
Vapor
pressure
Y
41015003
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.

2
Bolded
references
were
reviewed
under
CB
No.
5546,
10/
11/
89,
M.
Nelson;
and
all
other
references
were
reviewed
as
noted.
93
3
D174447,
9/
30/
92,
S.
Funk.

4
D192641,
3/
29/
94,
F.
Toghrol.

5
D206707,
3/
21/
96,
D.
Miller.

6
Data
are
not
required
because
the
T
is
not
an
emulsifiable
liquid
to
be
diluted
with
petroleum
solvents.

7
The
OPPTS
Series
830,
Product
Properties
Test
Guidelines
require
data
pertaining
to
UV/
visible
absorption
for
the
PAI.

8
Data
are
not
required
because
the
T/
TGAI
is
a
liquid
at
room
temperature.

9
D205626,
10/
6/
94,
F.
Toghrol.

10
D213407,
7/
12/
95,
K.
Dockter.
94
Case
No.
0073
Chemical
No.
030066
Case
Name:
2,4­
D
Registrant:
NuFarm
Limited
Product(
s):
94%
IPE
FI
(
EPA
Reg.
No.
35935­
13)

PRODUCT
CHEMISTRY
DATA
SUMMARY
Guideline
Number
Requirement
Are
Data
Requirements
Fulfilled?
1
MRID
Number
2
830.1550
Product
identity
and
composition
Y
3
40443301,
41224201
4,
CSF
2/
14/
90
5
830.1600
Description
of
materials
used
to
produce
the
product
Y
41376701
6,
40443301,
41224201
4
830.1620
Description
of
production
process
Y
41376701
6
,
40443301,
41224201
4
830.1670
Discussion
of
formation
of
impurities
Y
40443301
830.1700
Preliminary
analysis
N
7
40443301,
41206901
4
830.1750
Certified
limits
Y
40443301,
41206901
4,
CSF
2/
14/
90
5
830.1800
Enforcement
analytical
method
Y
40443301,
41206901
4
830.6302
Color
Y
40443301,
41224201
4
830.6303
Physical
state
Y
40443301,
41224201
4
830.6304
Odor
Y
40443301,
41224201
4
830.6313
Stability
to
normal
and
elevated
temperatures,
metals,
and
metal
ions
Y
40443301,
41224201
4
830.6314
Oxidation/
reduction:
chemical
incompatibility
Y
40443301,
41224201
4
830.6315
Flammability
Y
40443301,
41224201
4
830.6316
Explodability
Y
40443301,
41224201
4
830.6317
Storage
stability
Y
40443301,
41224201
4
830.6319
Miscibility
Y
40443301,
41224201
4
830.6320
Corrosion
characteristics
Y
40443301,
41224201
4
830.7000
pH
Y
40443301,
41224201
4
830.7050
UV/
Visible
absorption
N
8
830.7100
Viscosity
Y
40443301,
41224201
4
830.7200
Melting
point/
melting
range
N/
A
9
830.7220
Boiling
point/
boiling
range
Y
40443301,
41224201
4
830.7300
Density/
relative
density/
bulk
density
Y
40443301,
41224201
4
830.7370
Dissociation
constants
in
water
Y
41224201
4
830.7550
Partition
coefficient
(
n­
octanol/
water),
shake
flask
method
Y
40443301,
41224201
4
830.7840
Water
solubility:
column
elution
method;
shake
flask
method
Y
40443301,
41224201
4
830.7950
Vapor
pressure
Y
40443301,
41224201
4
1
Y
=
Yes;
N
=
No;
N/
A
=
Not
Applicable.

2
Bolded
references
were
reviewed
under
Registration
Division
Memorandum,
1/
89,
K.
Dockter;
and
all
other
references
were
reviewed
as
noted.
95
3
The
CSF
must
be
revised
to
list
2,4­
D
IPE
as
the
active
ingredient
instead
of
2,4­
D
acid.

4
Registration
Division
Memorandum,
12/
7/
89,
A.
Smith.

5
The
CSF
was
obtained
from
the
product
jacket.

6
CB
No.
6366,
7/
10/
90,
S.
Funk
for
the
dioxins
6/
87
DCI.

7
Based
on
the
submitted
manufacturing
process,
quantitative
analyses
were
required
for
dioxins/
dibenzofurans.

8
The
OPPTS
Series
830,
Product
Properties
Test
Guidelines
require
data
pertaining
to
UV/
visible
absorption
for
the
PAI.

9
Data
are
not
applicable
because
the
T/
TGAI
is
a
liquid
at
room
temperature.
96
AGENCY
MEMORANDA
CITED
IN
THIS
DOCUMENT
CBRS
No(
s):
RD
Memorandum
Subject:
Product
Chemistry
Review
on
New
Chemicals.
Gilmore
Inc.
IPE
FI
(
EPA
Reg.
No.
35935­
13).
From:
K.
Dockter
To:
R.
Mountfort
Dated:
1/
89
MRID(
s):
40443301
CBRS
No(
s):
5549
Subject:
EPA
Reg.
No.
264­
492.
2,4­
D.
Letter
of
4/
14/
89:
Product
Chemistry
Data
Submitted
in
Response
to
the
Registration
Standard.
From:
M.
Nelson
To:
C.
Grubbs
and
R.
Engler
Dated:
9/
26/
89
MRID(
s):
41067001
CBRS
No(
s):
5546
Subject:
EPA
Reg.
No.
5481­
144.
2,4­
D.
Letter
of
2/
22/
89:
Product
Chemistry
Data
Submitted
in
Response
to
the
Registration
Standard.
From:
M.
Nelson
To:
C.
Grubbs
and
R.
Engler
Dated:
10/
11/
89
MRID(
s):
41015001­
41015003
CB
No(
s):
5454,
5455,
5489,
5540,
5541,
5542,
5543,
and
5544
Subject:
2,4­
D.
EPA
Reg.
Nos.
464­
453,
464­
453,
464­
454,
464­
456,
464­
458,
464­
467,
464­
518,
and
464­
596.
Letters
of
11/
28/
88
and
3/
28/
89:
Product
Chemistry
Data
Submitted
by
Dow
Chemical
USA
in
Response
to
the
2,4­
D
Registration
Standard.
From:
M.
Nelson
To:
C.
Grubbs
and
R.
Engler
Dated:
10/
25/
89
MRID(
s):
40911901­
40911903
and
41055801­
41055820
CBRS
No(
s):
RD
Memorandum
Subject:
Product
Chemistry
Review
of
2,4­
D
Isopropyl
Ester
(
EPA
File
No.
42545­
50).
From:
A.
Smith
To:
J.
Miller
Dated:
12/
7/
89
97
MRID(
s):
41206901
and
41224201
CB
No(
s):
5750
Subject:
EPA
Reg.
No.
264­
492.
2,4­
D
Tech
Acid:
Rhone­
Poulenc
Letter
of
August
15,
1989:
Product
Chemistry
Data
Submitted
in
Response
to
the
Registration
Standard
Deficiencies.
From:
F.
Griffith
To:
V.
Prunier
and
R.
Engler
Dated:
2/
8/
90
MRID(
s):
41203301
CB
No(
s):
5860
Subject:
EPA
Reg.
No.
61469­
1.
2,4­
D
Acid.
Agro­
Gor
Corp
Letter
of
August
25,
1989:
Product
Chemistry
Data
Submitted
in
Response
to
the
Registration
Standard
Deficiencies.
From:
F.
Griffith
To:
V.
Prunier
and
R.
Engler
Dated:
2/
8/
90
MRID(
s):
41219601
CB
No(
s):
5826
Subject:
EPA
Reg.
Nos.
464­
453
and
464­
454.
2,4­
D
Tech.
Acid.
Dow
Chemical
Company
Letter
of
July
14,
1989:
Product
Chemistry
data
Submitted
in
Response
to
the
Registration
Standard
Deficiencies.
From:
F.
Griffith
To:
V.
Prunier
and
R.
Engler
Dated:
2/
13/
90
MRID(
s):
41220101
CB
No(
s):
5763
Subject:
EPA
Reg.
No.
2217­
455.
2,4­
D
Tech.
Acid.
PBI/
Gordon
Corporation
Letter
of
August
25,
1989:
Product
Chemistry
data
Submitted
in
Response
to
the
Registration
Standard
Deficiencies.
From:
F.
Griffith
To:
V.
Prunier
and
R.
Engler
Dated:
2/
15/
90
MRID(
s):
41219701
CB
No(
s):
6393
98
Subject:
Product
Chemistry
Data
­
2,4­
Dichlorophenoxy
Acetic
Acid
­
EPA
Registration
No.
2217­
455
­
PBI/
Gordon
Corporation
From:
G.
Makhijani
To:
B.
Baker
Dated:
4/
3/
90
MRID(
s):
41223801
CB
No(
s):
6295
Subject:
Analysis
Results
for
Polychlorinated
Dibenzo­
p­
Dioxins
and
Dibenzofurans
in
2,4­
D
and
2,4­
D­
2­
Ethylhexyl
Ester.
I.
D.
Nos.
61272­
3,
61272­
1.
Record
No.
259031
From:
S.
Funk
To:
E.
Feris
Dated:
5/
24/
90
MRID(
s):
41349001
and
41349002
CB
No(
s):
6366
Subject:
Product
Chemistry
Data
Review
for
2,4­
D
Esters
Technical
to
Determine
the
Potential
for
Halogenated
Dibenzo­
p­
Dioxin/
Dibenzofuran
Formation.
I.
D.
No.
42545­
LN.
Record
No.
260008.
From:
S.
Funk
To:
E.
Feris
Dated:
7/
10/
90
MRID(
s):
41376701
CB
No(
s):
6584
Subject:
Data
Call­
In
Notice
for
Analytical
Chemistry
Data
on
Polyhalogenated
Dibenzo­
p­
Dioxins
and
Dibenzofurans
in
2,4­
D.
Analytical
Results.
I.
D.
No.
359­
734.
Record
No.
262800.
From:
S.
Funk
To:
E.
Feris
Dated:
7/
12/
90
MRID(
s):
41203301
CB
No(
s):
6581
Subject:
2,4­
D
­
Product
Chemistry
Data
Octanol/
Water
Partition
Coefficient.
From:
G.
Makhijani
To:
J.
Coombs
Dated:
7/
27/
90
MRID(
s):
41332004
and
41332009
99
CB
No(
s):
6776
Subject:
2,4­
D
Analytical
Chemistry
DCI
for
Dioxins/
Dibenzofurans.
Registrant's
Response
to
Review
of
Data
Submission.
I.
D.
No.
62719­
24.
Record
No.
265975.
From:
S.
Funk
To:
E.
Feris
Dated:
8/
7/
90
MRID(
s):
41496701
CB
No(
s):
7139
Subject:
Product
Chemistry
Data
for
Technical
2,4­
Dichlorophenoxyacetic
Acid
(
2,4­
D).
Registrant's
Response
to
Deficiencies
in
the
Registration
Standard
Submission.
I.
D.
No.
264­
492.
Case
No.
818706
From:
S.
Funk
To:
E.
Feris
Dated:
11/
13/
90
MRID(
s):
41599401
CB
No(
s):
7137
Subject:
Product
Chemistry
Data
for
Technical
2,4­
Dichlorophenoxyacetic
Acid
(
2,4­
D).
Registrant's
Response
to
Deficiencies
in
the
Registration
Standard
Submission
and
Dioxin/
Dibenzofuran
Analytical
DCI
Submission.
I.
D.
No.
61469­
1.
Case
No.
818706.
From:
S.
Funk
To:
E.
Feris
Dated:
11/
16/
90
MRID(
s):
41246701
CB
No(
s):
7138
Subject:
Product
Chemistry
Data
for
Technical
2,4­
Dichlorophenoxyacetic
Acid
(
2,4­
D).
Registrant's
Response
to
Deficiencies
in
the
Registration
Standard
Submission
and
Dioxin/
Dibenzofuran
Analytical
DCI
Submission.
I.
D.
No.
2217­
455.
Case
No.
818706.
From:
S.
Funk
To:
E.
Feris
Dated:
11/
16/
90
MRID(
s):
41223801
100
CB
No(
s):
7206
Subject:
2,4­
D
Registration
Standard,
Response
to
Product
Chemistry
Data
Requirement.
I.
D.
No.
030053.
From:
H.
Fonouni
To:
J.
Coombs
Dated:
11/
21/
90
MRID(
s):
41647001
CB
No(
s):
7545
Subject:
2,4­
D,
Butoxyethyl
Ester,
Response
to
Product
Chemistry
Data
Requirement.
I.
D.
No.
030053.
From:
H.
Fonouni
To:
J.
Coombs
Dated:
2/
19/
91
MRID(
s):
41669501
DP
Barcode(
s):
D161373
Subject:
2,4­
D
Registration
Standard:
Response
to
Product
Chemistry
Data
Requirements
for
the
butoxyethyl
ester
of
2,4­
D:
DowElanco.
From:
W.
Smith
To:
J.
Coombs
Dated:
4/
16/
91
MRID(
s):
None
DP
Barcode(
s):
D161051
Subject:
DowElanco:
Response
to
the
2,4­
D
(
DMA
Salt)
Reregistration
Standard:
Product
Chemistry
From:
R.
Perfetti
To:
R.
Engler
and
L.
Rossi
Dated:
4/
25/
91
MRID(
s):
41755701
DP
Barcode(
s):
D161036
Subject:
PBI/
Gordon
Corporation:
Response
to
the
2,4­
D
Reregistration
Standard:
Product
Chemistry.
From:
R.
Perfetti
To:
R.
Engler
and
L.
Rossi
Dated:
4/
30/
91
MRID(
s):
41637501,
41745301,
and
41745302
101
DP
Barcode(
s):
D160520
Subject:
Data
Call­
In
Notice
for
Analytical
Chemistry
Data
on
Polyhalogenated
Dibenzo­
p­
Dioxins
and
Dibenzofurans
in
2,4­
D.
Additional
Analytical
Results.
I.
D.
No.
359­
734.
Chemical
No.
030001.
From:
S.
Funk
To:
E.
Feris
Dated:
7/
24/
91
MRID(
s):
41735701
DP
Barcode(
s):
D162701
Subject:
Product
Chemistry
Data
for
Technical
2,4­
D.
Registrant's
Additional
Response
to
Deficiencies
in
the
Registration
Standard
Submission.
I.
D.
No.
264­
492.
Chemical
No.
030001.
From:
S.
Funk
To:
E.
Feris
Dated:
7/
31/
91
MRID(
s):
41789901
and
41789902
DP
Barcode(
s):
D167302
Subject:
PBI/
Gordon
Corporation:
Response
to
the
2,4­
D
Reregistration
Standard:
Product
Chemistry
Data.
From:
R.
Perfetti
To:
W.
Burnam
and
L.
Rossi
Dated:
9/
25/
91
MRID(
s):
41926201­
41926203
DP
Barcode(
s):
D160163
Subject:
Analysis
of
Technical
2,4­
D
and
Technical
2,4­
D
Isooctyl
Ester
for
Polychlorinated
Dibenzo­
p­
Dioxins
and
Dibenzofurans.
Response
to
DCI.
ID
Nos.
61272­
3
and
61272­
1
From:
S.
Funk
To:
E.
Feris
Dated:
11/
26/
91
MRID(
s):
41724201­
41724203
102
DP
Barcode(
s):
D162358
Subject:
Analysis
of
Technical
2,4­
D
Acid
for
Polychlorinated
Dibenzo­
p­
Dioxins
and
Dibenzofurans.
Response
to
Review
of
DCI
Submission.
ID
No.
61469­
001.
From:
S.
Funk
To:
E.
Feris
Dated:
11/
26/
91
MRID(
s):
41796201
and
41796202
DP
Barcode(
s):
D162524
Subject:
Analysis
of
Technical
2,4­
D
Acid
for
Polychlorinated
Dibenzo­
p­
Dioxins
and
Dibenzofurans.
Response
to
DCI.
ID
No.
2217­
455.
From:
S.
Funk
To:
E.
Feris
Dated:
11/
26/
91
MRID(
s):
41790602
DP
Barcode(
s):
D172810
Subject:
Product
Chemistry
Data
for
Technical
2,4­
D
Acid.
Response
to
Deficiencies
in
Registration
Standard
Submission.
ID
No.
2217­
455.
From:
S.
Funk
To:
J.
Coombs
Dated:
1/
28/
92
MRID(
s):
41790601
DP
Barcode(
s):
RD
Memorandum;
D177498
Subject:
Product
Chemistry
Review
of
2,4­
D
acid
T
(
EPA
Reg.
No.
42545­
8).
CSF
dated
12/
20/
88.
From:
A.
Skapars
To:
not
specified
Dated:
5/
22/
92
MRID(
s):
None
CB
No(
s):
7945
DP
Barcode(
s):
Subject:
Product
Chemistry
Data
for
the
Riverdale
90.6%
Na
Salt
T
(
EPA
Reg.
No.
228­
123).
From:
To:
Dated:
6/
1/
92
MRID(
s):
41123601
103
DP
Barcode(
s):
None;
RD
Memorandum
Subject:
Product
Chemistry
Review
of
NuFarm
USA
2,4­
D
Acid
(
EPA
Reg.
No.
61272­
5).
From:
A.
Smith
To:
J.
Miller
Dated:
6/
5/
92
MRID(
s):
40808301
DP
Barcode(
s):
D167944
Subject:
2,4­
D
IPA
Product
Chemistry.
DowElanco
Response
to
CBRS
Review.
EPA
Reg.
No.
62719­
71.
From:
S.
Funk
To:
L.
Rossi
Dated:
6/
30/
92
MRID(
s):
41978001
and
41978002
DP
Barcode(
s):
D169647
Subject:
2,4­
D
Product
Chemistry.
PBI/
Gordon
Response
to
Registration
Standard.
EPA
Reg.
No.
2217­
455.
From:
S.
Funk
To:
L.
Rossi
Dated:
6/
30/
92
MRID(
s):
41308901
and
41332004
DP
Barcode(
s):
D170803
Subject:
PBI/
Gordon
Corporation:
Response
to
the
2,4­
D
Reregistration
Standard:
Product
Chemistry.
From:
E.
Zager
To:
L.
Rossi
and
E.
Saito
Dated:
7/
16/
92
MRID(
s):
42023601
DP
Barcode(
s):
D175586
Subject:
Reregistration
of
Dow
2,4­
D
BEE.
Product
Chemistry.
From:
S.
Funk
To:
J.
Coombs
Dated:
7/
23/
92
MRID(
s):
41431301
104
DP
Barcode(
s):
D170802
Subject:
From:
To:
Dated:
7/
24/
92
MRID(
s):
41964401
and
42021000­
42021002
DP
Barcode(
s):
RD
Memorandum;
D179920
Subject:
Product
Chemistry
Review
of
NuFarm
USA
2,4­
D
IOE
Technical
(
EPA
Reg.
No.
61272­
7).
From:
A.
Smith
To:
D.
Kenny
Dated:
7/
30/
92
MRID(
s):
None
DP
Barcode(
s):
D175577
Subject:
Product
Chemistry
Data
for
the
Riverdale
90.6%
2,4­
D
Sodium
Salt
T
(
EPA
Reg.
No.
228­
123).
From:
To:
Dated:
MRID(
s):
42227501
DP
Barcode(
s):
D180997
Subject:
Product
Chemistry
Data
(
GLN
61­
1,
­
2,
­
3,
62­
1,
­
2,
63­
8,
­
10,
­
11,
­
13,
­
14,
and
­
20)
for
PBI/
Gordon
Corp.
Technical
2,4­
D.
I.
D.
No.
2217­
455.
From:
S.
Funk
To:
J.
Coombs
Dated:
8/
11/
92
MRID(
s):
None
DP
Barcode(
s):
D167642,
D167684,
and
D167644
Subject:
2,4­
D
Technical
(
ID#:
030063,
030001,
and
030053).
DowElanco:
Response
to
the
2,4­
D
Product
Chemistry
Data
Requirements.
From:
F.
Toghrol
To:
L.
Rossi/
J.
Coombs
Dated:
9/
8/
92
MRID(
s):
41973501,
41973502,
41968301­
41968303,
and
41961301.
105
DP
Barcode(
s):
D174447
Subject:
2,4­
D
IPE:
Product
Chemistry
Data
for
Amvac
93%
Technical
(
5481­
144).
From:
S.
Funk
To:
L.
Rossi/
J.
Coombs
Dated:
9/
30/
92
MRID(
s):
42116702
and
42188601
DP
Barcode(
s):
D184583
Subject:
2,4­
D,
sodium
salt
Reregistration
(
a
List
A
Chemical):
Riverdale
Response
to
2,4­
D
Sodium
Salt
of
2,4­
D
90.6%
TGAI
(
EPA
Reg.
No.
228­
123).
Product
Chemistry
Data
Requirements
(
Chemical
No.
030004;
Case
0073).
From:
F.
Toghrol
To:
L.
Rossi/
W.
Waldrop
Dated:
2/
8/
93
MRID(
s):
42537501
DP
Barcode(
s):
D183498
Subject:
Reregistration
of
DowElanco
2,4­
D
BEE.
Product
Chemistry.
From:
K.
Dockter
To:
W.
Waldrop/
J.
Coombs
Dated:
3/
3/
93
MRID(
s):
42487901
DP
Barcode(
s):
D186542
and
D190622
Subject:
Reregistration
of
PBI/
Gordon
2,4­
D.
Product
Chemistry.
From:
W.
Smith
To:
W.
Waldrop/
J.
Coombs
Dated:
6/
1/
93
MRID(
s):
41332002
and
41972501
DP
Barcode(
s):
D189025
Subject:
2,4­
D
(
List
A,
Chemical
030001,
Case
0073):
Agrolinz
Response
to
Deficiency
in
the
Dibenzo­
p­
Dioxin/
Dibenzofuran
Product
Chemistry
Submission
(
MRID
42045501).
From:
S.
Funk
To:
L.
Rossi/
W.
Waldrop
Dated:
6/
25/
93
MRID(
s):
None
106
DP
Barcode(
s):
D192560
Subject:
2,4­
D
Reregistration:
List
A
Chemical
No.
030001;
Case
No.
0073).
DowElanco:
Response
to
the
97%
2,4­
D
Acid
Flake
T
(
EPA
Reg.
No.
62719­
25)
Data
Requirements
Regarding
Stability
(
Guideline
#
63­
13).
From:
F.
Toghrol
To:
L.
Rossi/
W.
Waldrop
Dated:
8/
5/
93
MRID(
s):
42795401
DP
Barcode(
s):
RD
Memorandum;
D189548
Subject:
Product
Chemistry
Review.
Rhone­
Poulenc
AG
Co.;
EPA
Reg.
No.
264­
492.
Product
Name:
Technical
2,4­
D
Acid.
From:
M.
Clifford
To:
J.
Miller
Dated:
8/
12/
93
MRID(
s):
None
DP
Barcode(
s):
D192562
Subject:
2,4­
D
Product
Chemistry.
Rereg
Case
0073.
From:
K.
Dockter
To:
J.
Coombs
Dated:
9/
7/
93
MRID(
s):
42798201
DP
Barcode(
s):
D192564
Subject:
2,4­
D
Product
Chemistry.
Rereg
Case
0073.
From:
K.
Dockter
To:
J.
Coombs
Dated:
9/
7/
93
MRID(
s):
42798101
DP
Barcode(
s):
D193112
Subject:
2,4­
D
Product
Chemistry.
Rereg
Case
0073
From:
K.
Dockter
To:
J.
Coombs
Dated:
9/
7/
93
MRID(
s):
42831001
107
DP
Barcode(
s):
D192565
and
D194929
Subject:
2,4­
D
Isopropylamine
Salt
(
IPA)
Reregistration.
List
A
Chemical
No.
030025;
Case
No.
0073.
DowElanco:
Response
to
2,4­
D
IPA
50.4%
FI
(
EPA
Reg.
No.
5481­
144)
Data
Requirements
(
GLN
Nos.
61­
1,
61­
3,
62­
2,
63­
6,
63­
8,
63­
9,
and
63­
17).
From:
F.
Toghrol
To:
L.
Rossi/
W.
Waldrop
Dated:
11/
9/
93
MRID(
s):
41431101
and
42798301
DP
Barcode(
s):
D193115
Subject:
2,4­
D
IOE
Reregistration:
List
A
Chemical
No.
030063;
Case
0073).
DowElanco:
Response
to
the
94.4%
2,4­
D
IOE
T/
MP
(
EPA
Reg.
No.
62719­
26)
Data
Requirements
Regarding
Boiling
Point
and
Solubility
(
GLN
Nos.
63­
6
and
63­
8).
From:
F.
Toghrol
To:
L.
Rossi/
W.
Waldrop
Dated:
11/
24/
93
MRID(
s):
42831101
DP
Barcode(
s):
D193116
Subject:
2,4­
D
DMA
Reregistration:
List
A
Chemical
No.
030019;
Case
0073).
DowElanco:
Response
to
Reregistration
Data
Requirements
Regarding
Melting
Point
(
GLN
No.
63­
5).
From:
F.
Toghrol
To:
L.
Rossi/
W.
Waldrop
Dated:
1/
24/
94
MRID(
s):
42829901
DP
Barcode(
s):
D193113
Subject:
2,4­
D
BEE
Reregistration:
List
A
Chemical
No.
030053;
Case
No.
0073).
DowElanco:
Response
to
the
96.4%
2,4­
D
BEE
T/
MP
(
EPA
Reg.
No.
62719­
33)
Data
Requirements
Regarding
Boiling
Point
and
Solubility
(
GLN
Nos.
63­
6
and
63­
8).
From:
F.
Toghrol
To:
L.
Rossi/
W.
Waldrop
Dated:
1/
26/
94
MRID(
s):
42830901
108
DP
Barcode(
s):
D194119
Subject:
2,4­
D,
Diethanolamine
(
DEA)
Salt
Reregistration:
List
A
Chemical
No.
030016;
Case
No.
0073).
PBI/
Gordon:
Response
to
the
2,4­
D
DEA
TGAI
Data
Requirements
Regarding
Physical
and
Chemical
Characteristics
(
GLN
Nos.
63­
2
to
63­
13).
From:
F.
Toghrol
To:
L.
Rossi/
W.
Waldrop
Dated:
1/
31/
94
MRID(
s):
42857201­
42857209
DP
Barcode(
s):
D189600
Subject:
2,4­
D,
Butoxyethyl
Ester
(
BEE)
Reregistration.
List
A
Chemical
No.
030053;
Case
No.
0073.
DowElanco:
Response
to
2,4­
D
BEE
95.5%
T/
MP
(
EPA
Reg.
No.
62719­
33)
Data
Requirements
(
GLN
Nos.
61­
1,
61­
3,
and
62­
3).
From:
F.
Toghrol
To:
L.
Rossi/
W.
Waldrop
Dated:
3/
11/
94
MRID(
s):
41961301
DP
Barcode(
s):
D192641
Subject:
2,4­
D
Isopropyl
Ester
(
IPE)
Reregistration.
List
A
Chemical
No.
030066;
Case
No.
0073.
Amvac
Chemical
Co.
Response
to
2,4­
D
IPE
93%
T/
MP
(
EPA
Reg.
No.
5481­
144)
Data
Requirements
(
GLN
Nos.
61­
1,
61­
3,
62­
3,
63­
8,
63­
13,
63­
14,
and
63­
17).
From:
F.
Toghrol
To:
L.
Rossi/
W.
Waldrop
Dated:
3/
29/
94
MRID(
s):
42786501
DP
Barcode(
s):
D198004
Subject:
2,4­
D.
Case
No.
0073.
Agrolinz's
Updated
CSF
for
EPA
Reg.
No.
42545­
30.
Levels
of
Dibenzo­
p­
Dioxin/
Dibenzofuran.
From:
L.
Cheng
To:
J.
Coombs
Dated:
8/
23/
94
MRID(
s):
None
DP
Barcode(
s):
D204466
Subject:
2,4­
D
Reregistration:
List
A
Chemical
No.
030001;
Case
No.
0073).
DowElanco:
Response
Regarding
Storage
Stability
and
Corrosion
Characteristics
(
GLN
No.
63­
17
and
63­
20).
109
From:
F.
Toghrol
To:
W.
Waldrop
Dated:
9/
15/
94
MRID(
s):
43260501
DP
Barcode(
s):
D207072
Subject:
2,4­
D
BEE,
2­
EHE,
and
TIPA
salt
Reregistration:
List
A
Case
No.
0073.
DowElanco
Response
to
the
2,4­
D
BEE
T/
MP
(
030053;
EPA
Reg.
No.
62719­
33),
2,4­
D
2­
EHE
TGAI
(
030063;
EPA
Reg.
No.
62719­
26),
and
2,4­
D
TIPA
salt
(
030035;
EPA
Reg.
No.
62719­
180)
Data
Requirements
Regarding
Melting
Point
(
GLN
63­
5)
and
Boiling
Point
(
GLN
Nos.
63­
6).
From:
F.
Toghrol
To:
W.
Waldrop/
J.
Coombs
Dated:
9/
29/
94
MRID(
s):
43325001­
43325003
DP
Barcode(
s):
D203749
Subject:
2,4­
D
Sodium
Salt
Reregistration.
List
A
Chemical
No.
030004;
Case
0073.
Riverdale
Response
to
2,4­
D
Sodium
Salt
90.6%
T/
MP
(
EPA
Reg.
No.
228­
123)
Product
Chemistry
Data
Requirements.
From:
F.
Toghrol
To:
W.
Waldrop
Dated:
10/
6/
94
MRID(
s):
None
DP
Barcode(
s):
D205626
Subject:
2,4­
D
Isopropyl
Ester
Reregistration:
List
A
Chemical
No.
030066;
Case
No.
0073.
Solubility
(
GLN
No.
63­
8)
for
Reregistration
of
Amvac's
T/
MP
(
EPA
Reg.
No.
5481­
144).
From:
F.
Toghrol
To:
W.
Waldrop/
J.
Coombs
Dated:
10/
6/
94
MRID(
s):
43302001
DP
Barcode(
s):
D208355
Subject:
2,4­
Dichlorophenoxyacetic
Acid
(
2,4­
D,
Chemical
030001,
Case
0073,
List
A).
Report
on
the
Determination
of
Chlorinated
Dioxins
and
Dibenzofurans:
Addendum.
From:
S.
Funk
To:
W.
Waldrop/
J.
Coombs
Dated:
11/
30/
94
110
MRID(
s):
None
DP
Barcode(
s):
RD
Memorandum;
D209172
Subject:
Product
Chemistry
Review
of
NuFarm
USA
2,4­
D
Dimethylamine
Salt
(
EPA
Reg.
No.
61272­
8).
From:
S.
Mathur
To:
J.
Miller
Dated:
1/
13/
95
MRID(
s):
None
DP
Barcode(
s):
RD
Memorandum;
D211526
Subject:
Product
Chemistry
Review
of
Albaugh
2,4­
D
Technical
Acid
(
EPA
Reg.
No.
42750­
31).
From:
A.
Smith
To:
D.
Kenny
Dated:
2/
13/
95
MRID(
s):
43516401­
43516404
DP
Barcode(
s):
D205982
Subject:
EPA
Reg.
#
62719­
27.
Nitrosamine
analyses
of
DowElanco's
2,4­
D
DMA
at
6
Months
Post­
Production.
From:
K.
Dockter
To:
W.
Waldrop/
J.
Coombs
Dated:
2/
14/
95
MRID(
s):
43314701
DP
Barcode(
s):
D215421
Subject:
Product
Chemistry
for
2,4­
D.
Chemical
No.
030001.
Case
No.
0073.
Registration
No.
42750­
31.
GLN's
61
and
62
Series
for
Polychlorinated
Dioxins
and
Dibenzofurans.
From:
S.
Funk
To:
W.
Waldrop/
J.
Coombs
Dated:
6/
8/
95
MRID(
s):
43516401
and
43516402
DP
Barcode(
s):
RD
Memorandum;
D214918
Subject:
Product
Chemistry
Review
of
Solaris
Group
of
Monsanto
2,4­
D
Dimethylamine
Salt
(
EPA
Reg.
No.
239­
2485).
From:
T.
Alston
To:
J.
Miller
111
Dated:
6/
26/
95
MRID(
s):
None
DP
Barcode(
s):
D213407
Subject:
Isopropyl
2,4­
D
Reregistration.
Amvac's
2/
22/
95
Response
[
Rebuttal
Letter
for
5481­
144]
to
Agency
2/
6/
95
Letter;
RE:
F.
Toghrol's
10/
11/
94
Review,
CBRS
14137
of
MRID
43302001.
From:
K.
Dockter
To:
W.
Waldrop/
J.
Coombs
Dated:
7/
12/
95
MRID(
s):
None
DP
Barcode(
s):
D218819
Subject:
2,4­
D.
(
List
A,
Chemical
030001,
Case
No.
73).
Product
Chemistry
for
Albaugh
Technical,
42750­
31.
Protocol
for
Determination
of
Polychlorinated
Dioxins
and
Dibenzofurans.
From:
S.
Funk
To:
W.
Waldrop/
J.
Coombs
Dated:
10/
2/
95
MRID(
s):
None
DP
Barcode(
s):
RD
Memorandum;
D219555
Subject:
Product
Chemistry
Review
of
DowElanco
2,4­
D
Dimethylamine
Salt
(
EPA
Reg.
No.
62719­
52).
From:
A.
Smith
To:
D.
Kenny
Dated:
10/
25/
95
MRID(
s):
None
DP
Barcode(
s):
D207979
Subject:
2,4­
D.
Review
of
Product
Chemistry.
GDLN
63­
8.
Case
0073
From:
D.
Miller
To:
J.
Coombs
Dated:
2/
22/
96
MRID(
s):
43358801
and
43358802
112
DP
Barcode(
s):
D206707
Subject:
2,4­
D
(
030066)
Product
Chemistry
Evaluation
GDLN
61­
1.
Rereg.
Case
No.
0073.
From:
D.
Miller
To:
J.
Coombs
Dated:
3/
21/
96
MRID(
s):
None
DP
Barcode(
s):
RD
Memorandum;
D224080
Subject:
Product
Chemistry
Review
of
PBI/
Gordon
2,4­
D
Dimethylamine
Salt
(
EPA
Reg.
No.
2217­
665).
From:
T.
Alston
To:
J.
Miller
Dated:
4/
10/
96
MRID(
s):
None
DP
Barcode(
s):
D226030
Subject:
2,4­
dichlorophenoxy
Acetic
Acid
(
Chemical
010001,
Case
0073,
List
A).
Product
Chemistry:
Determination
of
Polychlorinated
Dioxins
and
Dibenzofurans
in
RAM
Research,
Inc.
Technical
(
69474­
1).
From:
S.
Funk
To:
P.
Deschamp
Dated:
9/
9/
96
MRID(
s):
43981801
DP
Barcode(
s):
RD
Memorandum;
D231434
Subject:
Product
Chemistry
Review
of
2,4­
Dichlorophenoxyacetic
Acid
(
2,4­
D);
PBI/
Gordon
Corporation,
EPA
Reg.
No.
2217­
455.
From:
A.
Smith
To:
D.
Kenny
Dated:
12/
11/
96
MRID(
s):
44149301
and
44149302
DP
Barcode(
s):
D219403
Subject:
2,4­
D.
Product
Chemistry
Evaluation
for
EPA
Reg.
Nos.
62719­
24
(
molten)
and
62719­
25
(
flake)
products.
GDLNs
830.1700
and
830.1750.
From:
D.
Miller
To:
P.
Deschamp
Dated:
1/
3/
97
MRID(
s):
43777501
and
43777502
113
DP
Barcode(
s):
D232535
and
D232688
Subject:
2,4­
Dichlorophenoxy
Acetic
Acid
(
Chemical
010001,
Case
0073,
List
A).
Product
Chemistry:
Determination
of
Polychlorinated
Dioxins
and
Dibenzofurans
in
RAM
Research,
Inc.
Technical
(
69474­
1).
Registrant
Response
to
Review
(
DP
Barcode
D226030.
CBRS
17270.
MRID
43981801).
From:
S.
Funk
To:
P.
Deschamp
Dated:
2/
20/
97
MRID(
s):
None
DP
Barcode(
s):
D221847
Subject:
Isopropylamine
2,4­
dichlorophenoxyacetate
[
IPA_
2,4­
D]
Reregistration.
DowElanco
12/
11/
95
Response
[
830.6317
&
.6320
Information
for
the
MUC]
to
Agency
1/
25/
94
Letter
RE:
F.
Toghrol
11/
10/
93
Review;
CBRSs
12116
&
12529.
From:
K.
Dockter
To:
P.
Deschamp
Dated:
3/
28/
97
MRID(
s):
43874601
DP
Barcode(
s):
RD
Memorandum;
D232536
Subject:
Product
Chemistry
Review;
Reg.
No.
2217­
IRG;
Product
Name:
EH
1330
Herbicide;
Company:
PBI/
Gordon
Corporation.
From:
A.
Smith
To:
S.
Stanton
Dated:
6/
27/
97
MRID(
s):
44184201
DP
Barcode(
s):
RD
Memorandum;
D236698
Subject:
Product
Chemistry
Review
of
PBI/
Gordon
2,4­
D
Acid
(
EPA
Reg.
No.
2217­
593).
From:
B.
Kitchens
To:
S.
Hobgood
Dated:
7/
29/
97
MRID(
s):
None
DP
Barcode(
s):
RD
Memorandum;
D236701
Subject:
Product
Chemistry
Review
of
PBI/
Gordon
2,4­
D
Acid
(
EPA
Reg.
No.
2217­
508).
From:
B.
Kitchens
114
To:
S.
Hobgood
Dated:
7/
29/
97
MRID(
s):
None
DP
Barcode(
s):
RD
Memorandum;
D245940
Subject:
Product
Chemistry
Review
of
TGAI
Data
for
PBI/
Gordon
Corporation
2,4­
Dichlorophenoxyacetic
acid.
From:
S.
Mathur
To:
J.
Miller
Dated:
6/
9/
98
MRID(
s):
44543502­
44543504,
and
44547901
DP
Barcode(
s):
RD
Memorandum;
D247475
Subject:
Product
Chemistry
Review
of
Dow
Agrosciences
LLC
2,4­
D
BEE
(
EPA
Reg.
No.
62719­
33).
From:
A.
Smith
To:
M.
Cooke
Dated:
7/
24/
98
MRID(
s):
44584501
DP
Barcode(
s):
RD
Memorandum;
D249891
Subject:
Product
Chemistry
Review
of
PBI/
Gordon
2,4­
D
Acid
(
EPA
Reg.
No.
2217­
567).
From:
S.
Malak
To:
J.
Miller
Dated:
10/
19/
98
MRID(
s):
None
DP
Barcode(
s):
RD
Memorandum;
D250352
Subject:
Product
Chemistry
Review
of
Dow
Agrosciences
LLC
2,4­
D
TIPA
Salt
(
EPA
Reg.
No.
62719­
180).
From:
S.
Mathur
To:
J.
Miller
Dated:
10/
27/
98
MRID(
s):
None
115
DP
Barcode(
s):
RD
Memorandum;
D252258
Subject:
TGAI
Product
Chemistry
Review/
Action:
345,
EPA
Reg./
File
Symbol
No.
62719­
24.
Chemical
2,4­
D
Acid
for
Manufacturing
Purposes
Only.
Company:
Dow
Agrosciences
LLC.
From:
H.
Podall
To:
J.
Miller
Dated:
2/
2/
99
MRID(
s):
44228601
DP
Barcode(
s):
RD
Memorandum;
D253591
Subject:
Product
Chemistry
Review
of
Dow
Agrosciences
LLC
2,4­
D
Isopropylamine
Salt
(
EPA
Reg.
No.
62719­
71).
From:
S.
Mathur
To:
J.
Miller
Dated:
3/
11/
99
MRID(
s):
None
DP
Barcode(
s):
RD
Memorandum;
D255728
Subject:
Product
Chemistry
Review;
Reg.
No.
62719­
71;
Product
Name:
2,4­
D
Isopropylamine
salt;
Company:
Dow
AgroSciences
LLC.
From:
S.
Mathur
To:
J.
Miller
Dated:
5/
5/
99
MRID(
s):
44807001
DP
Barcode(
s):
RD
Memorandum;
D261587
Subject:
Product
Chemistry
Review
of
2,4­
D
2­
Ethylhexyl
Ester.
From:
S,
Mathur
To:
J.
Miller
Dated:
1/
11/
00
MRID(
s):
44982101
and
44982102
DP
Barcode(
s):
RD
Memorandum;
D262746
Subject:
Product
Chemistry
Review;
Reg.
No.
62719­
26;
Product
Name:
2,4­
D
2­
Ethylhexyl
Ester
Technical;
Company:
Dow
AgroSciences
LLC.
From:
B.
Kitchens
To:
J.
Miller/
S.
Stanton
Dated:
4/
18/
00
MRID(
s):
45014801
116
DP
Barcode(
s):
RD
Memorandum;
D267474
Subject:
Product
Chemistry
Review.
Reg.
No.
2217­
455;
Product
Name:
2,4­
Dichlorophenoxy
Acetic
Acid;
Company:
PBI/
Gordon
Corporation.
From:
B.
Kitchens
To:
J.
Miller/
S.
Stanton
Dated:
8/
9/
00
MRID(
s):
44932701
DP
Barcode(
s):
RD
Memorandum;
D273235
Subject:
Product
Chemistry
Review;
Reg.
No.
62719­
25;
Product
Name:
2,4­
Dichlorophenoxy
acetic
acid
Flake;
Company:
Dow
AgroSciences
LLC.
From:
S.
Mathur
To:
J.
Miller
Dated:
4/
2/
01
MRID(
s):
None
DP
Barcode(
s):
RD
Memorandum;
D275778
Subject:
Product
Chemistry
Review;
Reg.
No.
62719­
26;
Product
Name:
2,4­
D
2­
Ethylhexyl
Ester
Technical,
95.4%;
Company
Name:
Dow
AgroSciences
LLC.
From:
S.
Malak
To:
J.
Miller/
J.
Stone
Dated:
8/
8/
01
MRID(
s):
None
DP
Barcode(
s):
RD
Memorandum;
D275675
Subject:
Product
Chemistry
Review;
Reg.
No.
62719­
71;
Product
Name:
2,4­
Dichlorophenoxyacetic
acid,
isopropylamine
salt,
49.9%;
Company
Name:
Dow
AgroSciences
LLC.
From:
S.
Malak
To:
J.
Miller/
J.
Stone
Dated:
8/
8/
01
MRID(
s):
None
DP
Barcode(
s):
RD
Memorandum;
D282901
Subject:
Product
Chemistry
Review;
Reg.
No.
62719­
52;
Product
Name:
DMA­
6
Sequestered.
From:
L.
Kutney
To:
J.
Miller/
M.
Cooke
Dated:
8/
6/
02
MRID(
s):
45642701
117
DP
Barcode(
s):
RD
Memorandum;
D286090
Subject:
Product
Chemistry
Review;
Reg.
No.
46146­
5;
Product
Name:
Technical
2,4­
D
Low
Volatile
Ester,
93.3%
2,4­
D
2EHE;
Company
Name:
Atanor
S.
A.
From:
S.
Malak
To:
J.
Miller/
E.
Wilson
Dated:
11/
25/
02
MRID(
s):
None
DP
Barcode(
s):
RD
Memorandum;
D286092
Subject:
Product
Chemistry
Review;
Reg.
No.
46146­
4;
Product
Name:
Atanor
2,4­
D
Technical
Acid,
97.9%
2,4­
D
2EHE;
Company:
Atanor
S.
A.
From:
S.
Malak
To:
J.
Miller/
E.
Wilson
Dated:
11/
25/
02
MRID(
s):
None
DP
Barcode(
s):
RD
Memorandum;
D288431
Subject:
TGAI
Product
Chemistry
Review/
Action:
346.
EPA
Reg.
No.
46146­
4;
Product:
Technical
Isooctyl­
D
(
2,4­
D);
Chemical
2,4­
D­­
2EHE
­­­­­­
93.3%.
Company:
Atanor
S.
A.
(
Argentina).
From:
H.
Podall
To:
J.
Miller/
E.
Wilson
Dated:
4/
7/
03
MRID(
s):
None
DP
Barcode(
s):
RD
Memorandum;
D288281
Subject:
Product
Chemistry
Review
of
a
Technical
Grade
TGAI;
Reg.
No.
46146­
5;
Product
Name:
Technical
2,4­
D
Low
Volatile
Ester,
83.3%
2,4­
D
2­
EHE;
Company
Name:
Atanor
S.
A.
From:
S.
Malak
To:
J.
Miller/
E.
Wilson
Dated:
4/
8/
03
MRID(
s):
None
DP
Barcode(
s):
D236419
Subject:
Analysis
of
Polychlorinated
Dibenzo­
p­
Dioxins
and
Dibenzofurans
in
2,4­
D
Acid
Flake
(
EPA
Reg.
No.
62719­
25).
From:
To:
Dated:
MRID(
s):
44287101
118
DP
Barcode(
s):
D283959
Subject:
Product
Chemistry
Data
Submitted
by
the
Task
Force
II.
Water
Solubility
Data
for
the
2,4­
D
Acid
TGAI/
PAI.
From:
W.
Hazel
To:
M.
Seaton
and
J.
Miller
Dated:
3/
1/
04
MRID(
s):
45692501
PRODUCT
CHEMISTRY
CITATIONS
Bibliographic
citations
include
only
MRIDs
containing
data
which
fulfill
data
requirements.

References
(
cited):

40443301
Collins,
R.
(
1987)
Product
Chemistry:
2,4­
D
Isopropyl
Ester:
Laboratory
Project
ID:
2,4­
D
ISOPROPYL
ESTER.
Unpublished
study
prepared
by
Gilmore,
Inc.
11
p.

40808301
Allen,
W.;
Mahlburg,
W.
(
1988)
Clean
Crop
2,4­
D
Acid:
Product
Chemistry
Data:
Study
No.
88­
9A.
Unpublished
study
prepared
by
Transbas,
Inc.
Laboratory.
64
p.

41015001
Braden,
G.;
Feiler,
W.
(
1989)
Technical
Isopropyl
Ester
of
2,4­
D:
Product
Chemistry
Ingredients
Identification.
Unpublished
study
prepared
by
Amvac
Chemical
Corporation.
39
p.

41015002
Braden,
G.;
Feiler,
W.
(
1989)
Technical
Isopropyl
Ester
of
2,4­
D:
Product
Chemistry
Analysis.
Unpublished
study
prepared
by
Amvac
Chemical
Corp.
10
p.

41015003
Feiler,
W.;
Braden,
G.
(
1989)
Technical
Isopropyl
Ester
of
2,4­
D:
Product
Chemistry:
Physical
and
Chemical
Properties.
Unpublished
study
prepared
by
Amvac
Chemical
Corp.
15
p.
41055801
Dow
Chemical
Co.
(
1989)
2,4­
D
Acid:
Product
Identity
and
Composition.
Unpublished
study.
40
p.

41055802
Dow
Chemical
Co.
(
1989)
2,4­
D
Acid:
Analysis
and
Certification
of
Product
Ingredients.
Unpublished
study.
32
p.

41055803
Dow
Chemical
Co.
(
1989)
2,4­
D
Acid:
Physical
and
Chemical
Characteristics.
Unpublished
study.
6
p.

41055804
Dow
Chemical
Co.
(
1989)
2,4­
D
Acid,
Flake:
Product
Identity
and
Composition.
Unpublished
study.
14
p.

41055805
Dow
Chemical
Co.
(
1989)
2,4­
D
Acid,
Flake:
Analysis
and
Certification
of
Product
Ingredients.
Unpublished
study.
12
p.
119
41055806
Dow
Chemical
Co.
(
1989)
2,4­
D
Isooctyl
(
2­
Ethylhexyl)
Ester:
Product
Identity
and
Composition.
Unpublished
study.
26
p.

41055807
Dow
Chemical
Co.
(
1989)
2,4­
D
Isooctyl
(
2­
Ethylhexyl)
Ester:
Analysis
and
Certification
of
Product
Ingredients.
Unpublished
study.
35
p.

41055808
Dow
Chemical
Co.
(
1989)
2,4­
D
Isooctyl
(
2­
Ethylhexyl)
Ester:
Physical
and
Chemical
Characteristics.
Unpublished
study.
6
p.

41055809
Dow
Chemical
Co.
(
1989)
2,4­
D
DMA­
6
Unsequestered
Weedkiller:
Product
Identity
and
Composition.
Unpublished
study.
23
p.

41055810
Dow
Chemical
Co.
(
1989)
2,4­
D­
6
Unsequestered
Weedkiller:
Analysis
and
Certification
of
Product
Ingredients.
Unpublished
study.
22
p.

41055811
Dow
Chemical
Co.
(
1989)
2,4­
D
DMA­
6
Unsequestered
Weedkiller:
Physical
and
Chemical
Characteristics.
Unpublished
study.
6
p.

41055812
Dow
Chemical
Co.
(
1989)
2,4­
D
Butoxyethyl
Ester:
Product
Identity
and
Composition.
Unpublished
study.
27
p.

41055813
Dow
Chemical
Co.
(
1989)
2,4­
D
Butoxyethyl
Ester:
Analysis
and
Certification
of
Product
Ingredients.
Unpublished
study.
34
p.

41055814
Dow
Chemical
Co.
(
1989)
2,4­
D
Butoxyethyl
Ester:
Physical
and
Chemical
Characteristics.
Unpublished
study.
6
p.

41055815
Dow
Chemical
Co.
(
1989)
2,4­
D
Isopropylamine
Salt:
Product
Identity
and
Composition.
Unpublished
study.
22
p.

41055816
Dow
Chemical
Co.
(
1989)
2,4­
D
Isopropylamine
Salt:
Analysis
and
Certification
of
Product
Ingredients.
Unpublished
study.
26
p.

41055817
Dow
Chemical
Co.
(
1989)
2,4­
D
Isopropylamine
Salt:
Physical
and
Chemical
Characteristics.
Unpublished
study.
6
p.

41055818
Dow
Chemical
Co.
(
1989)
2,4­
D
Triisopropanolamine
Salt­
4:
Product
Identity
and
Composition.
Unpublished
study.
23
p.

41055819
Dow
Chemical
Co.
(
1989)
2,4­
D
Triisopropanolamine
Salt­
4:
Analysis
and
Certification
of
Product
Ingredients.
Unpublished
study.
22
p.

41055820
Dow
Chemical
Co.
(
1989)
2,4­
D
Triisopropanolamine
Salt­
4:
Physical
and
Chemical
Characteristics.
Unpublished
study.
6
p.
120
41067001
May
&
Baker
Ltd.
(
1988)
Product
Chemistry
Data
Requirements
under
EPA
Pesticide
Assessment
Guidelines
dated
Oct
1982
(
2,4­
Dichlorophenoxy)
acetic
Acid
2,4­
D
Technical
Acid.
Unpublished
study.
138
p.

41203301
Silvestre,
D.
(
1989)
2,4­
D
Determination
of
Polychlorinated
Dibenzo­
p­
dioxins
and
Dibenzofurans
by
GC/
MS:
Laboratory
ID:
89­
10.
Unpublished
study
prepared
by
Rhone­
Poulenc
Industrialisation.
133
p.

41206901
Fisher,
J.
(
1989)
Product
Chemistry:
Agrolinz
Isopropyl
2,4­
D
Ester
Technical:
Analytical
Methods.
Unpublished
study
prepared
by
Agrolinz,
Inc.
17
p.

41219601
Armbruster,
J.
(
1989)
EPA
Reg.
No.
61649­
001
­
Certification
of
Limits
for
Dibenzop
Dioxins/
Dibenzofurans.
Unpublished
study
prepared
by
AGRO­
GOR
Corp.
179
p.

41219701
Ambruster,
J.
(
1989)
Certification
of
Limits
for
Dibenzo­
p­
Dioxins/
Dibenzofurans.
Unpublished
study
prepared
by
PBI/
Gordon
Corp.
179
p.

41220101
Berry,
D.
(
1989)
Final
Report
of
the
Determination
of
Halogenated
Dibenzo­
p­
dioxins
and
Dibenzofurans
in
2,4­
Dichlorophenoxyacetic
Acid:
Proj.
ID
AL
89­
030290.
Unpublished
study
prepared
by
Dow
Chemical
Co.,
Analytical
Sciences
Laboratories.
168
p.

41223801
Armbruster,
J.
(
1989)
EPA
Reg.
No.
2217­
455
­
Product
Chemistry
[
of
2,4­
Dichlorophenoxyacetic
Acid].
Unpublished
study
prepared
by
Agro­
Gor
Corp.
30
p.

41224201
Fisher,
J.
(
1989)
Product
Chemistry
Data
Requirements
for
Isopropyl
2,4­
D
Ester
Technical:
Proj.
ID
P­
890824.
Unpublished
study
prepared
by
Agrolinz,
Inc.
61
p.

41246701
Armbruster,
J.
(
1989)
Product
Chemistry:
AUS
90
Technical.
Unpublished
study
prepared
by
AGRO­
GOR
Corp.
30
p.

41308901
Reim,
R.
(
1989)
Dissociation
of
2,4­
Dichlorophenoxyacetic
Acid
(
2,4­
D)
and
2,4­
D
Dimethylamine
Salt
in
Water:
Lab
Project
Number:
ML
AL
89
041014.
Unpublished
study
prepared
by
Dow
Chemical
U.
S.
A.
25
p.

41332002
Hopkins,
D.
(
1987)
2,4­
Dichlorophenoxyacetic
Acid:
Determination
of
the
Water
Solubility:
Lab
Project
Number:
ES/
DR/
0002/
2297/
8.
Unpublished
study
prepared
by
The
Dow
Chemical
Co.
14
p.

41332004
Bailey,
R.;
Hopkins,
D.
(
1987)
2,4­
Dichlorophenoxyacetic
Acid:
Determination
of
Octanol/
Water
Partition
Coefficient:
Lab
Project
Number:
ES/
DR/
0002/
2297/
9.
Unpublished
study
prepared
by
the
Dow
Chemical
Co.
12
p.

41332009
Helmer,
D.
(
1987)
Determination
of
the
Octanol/
Water
Partition
Coefficient
for
2,4­
Dichlorophenoxy
Acetic
Acid,
2­
Ethylhexyl
Ester:
Lab
Project
Number:
ML/
AL/
87/
70819.
Unpublished
study
prepared
by
Dow
Chemical
Co.
14
p.
121
41349001
Fiene,
J.;
Mahlburg,
W.
(
1990)
Determination
of
Halogenated
Dibenzo­
p­
Dioxins
and
Dibenzofurans
in
2,4­
D
Acid:
Lab
Project
Number:
90­
1.
Unpublished
study
prepared
by
Chemserv
Industries
Service
Ges.
m.
b.
H.
323
p.

41349002
Fiene,
J.;
Mahlburg,
W.
(
1989)
Determination
of
Halogenated
Dibenzo
­
p­
Dioxins
and
Dibenzofurans
in
2,4­
D
Isooctyl
Ester
Technical:
Lab
Project
Number:
90/
2.
Unpublished
study
prepared
by
Chem­
serve
Industries
Service
Ges.
m.
b.
H.
325
p.

41376701
Fisher,
J.
(
1989)
Manufacturing
Process
for
the
Production
of
Esters
of
2,4­
Dichlorophenoxyacetic
Acid:
Lab
Project
ID:
P89030L.
Unpublished
study
prepared
by
Agrolinz,
Inc.
15
p.

41431101
Chakrabarti,
A.
(
1990)
Vapor
Pressure
of
the
Isopropyl
Amine
Salt
of
2,4­
Dichlorophenoxy
Acetic
Acid
Measured
by
the
Knudsen­
Effusion/
Weight
Loss
Method:
Lab
Project
Number:
ML­
AL
89­
020235.
Unpublished
study
prepared
by
Dow
Chemical
U.
S.
A.
11
p.

41431301
Chadrabarti,
A.
(
1989)
Vapor
Pressure
of
the
Butoxyethyl
Ester
of
(
2,4­
Dichlorophenoxy)
Acetic
Acid
Measured
by
the
Knudsen­
Effusion/
Weight
Loss
Method:
Lab
Project
Number:
ML­
AL­
89­
020197.
Unpublished
study
prepared
by
Dow
Chemical
U.
S.
A.
12
p.

41496701
DowElanco
(
1990)
2,4­
D
Acid:
Product
Identity
and
Composition:
"
Amendment".
Unpublished
study
prepared
by
The
Dow
Chemical
Co.
51
p.

41599401
Buddle,
G.
(
1990)
2,4­
D
Technical
Acid
Product
Chemistry:
Supplemental
Information:
Lab
Project
Number:
ACD/
GCB/
MS/
8364.
Unpublished
study
prepared
by
Rhone­
Poulenc
Ag
Co.
10
p.

41637501
Armbruster,
J.
(
1990)
Revised
Partial
Product
Chemistry.
Unpublished
study
prepared
by
PBI/
GORDON
Corp.
18
p.

41647001
Heimerl,
J.
(
1990)
Determination
of
the
Octanol/
Water
Partition
Coefficient
of
2,4­
D
Butoxyethyl
Ester
(
2,4­
D
BEE):
Lab
Project
Number:
ML­
AL
90­
080378.
Unpublished
study
prepared
by
Dow
Chemical
USA.
22
p.

41669501
Moore,
R.
(
1990)
2,4­
Dichlorophenoxyacetic
acid,
butoxyethyl
ester:
Aqueous
Solubility:
Lab
Project
Number:
9585/
F/
02.
Unpublished
study
prepared
by
Midwest
Research
Institute.
17
p.

41681901
Armbruster,
J.
(
1990)
Revised
Partial
Product
Chemistry.
Unpublished
study
prepared
by
AGRO/
GOR
Corp.
20
p.
122
41724201
Landvoight,
W.;
Mahlburg,
W.
(
1990)
Quality
Assurance
Project
Plan
for
Determination
of
Halogenated
Dibenzo­
p­
Dioxins
and
Dibenzofurans...
in
2,4­
D...:
Lab
Project
Number:
90­
3.
Unpublished
study
prepared
by
Chemserve
Industries
Service
Ges.
m.
b.
H.
43
p.

41724202
Landvoight,
W.;
Mahlburg,
W.
(
1990)
Determination
of
Halogenated
Dibenzo­
p­
Dioxins
and
Dibenzofurans
in
2,4­
D
Acid
by
Method
of
Analysis
50288:
Lab
Project
Number:
90­
4.
Unpublished
study
prepared
by
Chemserve
Industries
Service
Ges.
m.
b.
H.
561
p.

41724203
Landvoight,
W.;
Mahlburg,
W.
(
1990)
Determination
of
Halogenated
Dibenzo­
p­
Dioxins
and
Dibenzofurans
in
2,4­
D
Isooctyl
Ester
by
Method
of
Analysis
50288:
Lab
Project
Number:
90­
5.
Unpublished
study
prepared
by
Chemserve
Industries
Service
Ges.
m.
b.
H.
423
p.
41735701
Silvestre,
D.
(
1990)
Determination
of
Polychlorinated
Dibenzo­
p­
Dioxins
and
Dibenzofurans
In
2,4­
D:
Complementary
Analytical
Raw
Data
Relative
to
Study
89­
10:
Lab
Project
Number:
343­
484.
Unpublished
study
prepared
by
Rhone­
Poulenc
Industrialisation.
100
p.

41745301
Etchepareborda,
I.;
Sancrica,
J.
(
1990)
Storage
Stability
of
Technical
2,4
Dichlorophenoxyacetic
Acid.
Unpublished
study
prepared
by
Atanor
S.
A./
Laboratorios
de
Estudios
Analiticos.
8
p.

41745302
Castaneda,
J.
(
1990)
2,4
Dichlorophenoxyacetic
Acid
Explodability:
Unpublished
study
prepared
by
Instituto
de
Desarrollo
Tecnologico/
para
la
Industria
Quimica
(
INTEC).
8
p.

41755701
Schriber,
C.
(
1990)
Chemical
Stability
of
2,4­
D
Dimethyl
Salt
Solution:
Lab
Project
Number:
GH­
C
24428.
Unpublished
study
prepared
by
DowElanco.
17
p.

41789901
Rajoharison,
G.
(
1991)
Responses
to
EPA
Queries
on
2,4­
D
Product
Chemistry:
Lab
Project
Number:
GR/
BC/
91­
189/
PTC211.
Unpublished
study
prepared
by
Rhone­
Poulenc
Chimie.
9
p.

41789902
Buddle,
G.;
Patel,
P.
(
1991)
2,4­
dichlorophenoxyacetic
acid
(
2,4­
D):
Analysis
and
Certification
of
Product
Ingredients,
Provision
of
Supplementary
Analytical
Method
Validation:
Lab
Project
Number:
P­
91­
016.
Unpublished
study
prepared
by
Rhone­
Poulenc
Agriculture
Ltd.
20
p.

41790601
Armbruster,
J.
(
1991)
Product
Chemistry:
61
&
63
Series:
(
2,4­
D
Acid,
Reg.
No.
2217­
455).
Unpublished
study
prepared
by
PBI
Gordon
Corp.
8
p.

41790602
Armbruster,
J.
(
1989)
Certification
of
Limits
for
Dibenzo­
p­
Dioxins/
Dibenzofurans.
Unpublished
study
prepared
by
PBI/
Gordon
Corp.
489
p.

41796201
Armbruster,
J.
(
1989)
EPA
Reg
No.
61469­
001­
Product
Chemistry.
Unpublished
study
prepared
by
Agro­
Gor
Corp.
8
p.
123
41796202
Armbruster,
J.
(
1989)
EPA
REG
No.
6149­
001­
Certification
of
Limits
for
Dibenzo­
p­
Dioxins/
Dibenzofurans.
Unpublished
study
prepared
by
Agro­
Gor
Corp.
489
p.

41855701
Citation
not
available
from
PDMS
41880601
Cicotti,
M.
(
1991)
Determination
of
the
Solubility
of
2,4­
D
in
Organic
Solvents
in
accordance
with
EPA
63­
8
and
BBA
Guidelines:
Lab
Project
Number:
BE/
P/
1/
91/
01/
BG.
Unpublished
study
prepared
by
Battelle
Europe.
15
p.

41926201
Etchepareborda,
I.;
Sancricca,
J.
(
1991)
Preliminary
Analysis
of
2,4
Dichlorophenoxyacetic
acid
97%.
Unpublished
study
prepared
by
Atanor
S.
A.
17
p.

41926202
Etchepareborda,
I.
(
1991)
pH
of
2,4­
Dichlorophenoxyacetic
acid
97%.
Unpublished
study
prepared
by
Atanor
S.
A.
5
p.

41926203
Etchepareborda,
I.;
Sancricca,
J.
(
1991)
Storage
Stability
(
1
year
in
commercial
packaging)
of
2,4
Dichlorophenoxyacetic
acid
97%.
Unpublished
study
prepared
by
Atanor
S.
A.
7
p.

41961301
DowElanco
(
1991)
2,4­
D
Butoxyethyl
Ester:
Response
to
2,4­
D
Task
4:
Registrants
Response
to
Product
Chemistry
Data
Requirements
DEB
No.
5454­
5455,
5440­
5544
Dated
September
22,
1989.
Unpublished
study.
11
p.

41964401
DowElanco
(
1991)
Response
to
2,4­
D
Task
4:
Registrant's
Response
to
Product
Chemistry
Data
Requirements
DEB
No.
5454­
5455,
5440­
5544
Dated
Sep.
22,
1989
(
Tinsworth
Letter
Dated
January
23,
1990)
2,4­
Dimethylamine
Salt.
Unpublished
study
prepared
by
DowElanco.
17
p.

41968301
DowElanco.
(
1991)
2,4,
D
Isooctyl
Ester
(
2­
ethylhexyl
ester):
Response
to
2,4­
D
Task
4:
Registrant's
Response
to
Product
Chemistry
Data
Requirements
DEB
No.
5454­
5455,
5489,
5440­
5544dated
September
22,
1989.
Unpublished
study.
11
p.

41968302
Helmer,
D.
(
1987)
Determination
of
the
Water
Solubility
of
2,4­
dichlorophenoxy
Acetic
Acid,
2­
ethylhexyl
Ester:
Lab
Project
No:
ML­
AL­
87­
70817.
Unpublished
study
prepared
by
Dow
Chemical
USA.
13
p.

41968303
Schriber,
C.;
Tiszai,
N.
(
1991)
Chemical
Stability
of
2,4­
D
2­
Ethyl
hexyl
Ester:
Lab
Project
Number:
90086.
Unpublished
study
prepared
by
DowElanco.
17
p.

41972501
Gallacher,
A.
(
1991)
Dissociation
of
2,4­
Dichlorophenoxyacetic
Acid
(
2,4­
D)
and
2,4­
D
Diethanolamine
Salt
in
Water:
Lab
Project
Number:
4102­
90­
0304­
AS:
4102­
90­
0304­
AS­
001.
Unpublished
study
prepared
by
Ricerca,
Inc.
231
p.
124
41973501
DowElanco
(
1991)
2,4­
D
Acid
and
2,4­
D
Acid
Flake:
Response
to
2,4­
D
Task
4:
Registrant's
Response
of
Product
Chemistry
Data
Requirements
Deb.
No.
5454­
5455,
5489,
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Dated
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Schriber,
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Chemical
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Unpublished
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41978001
DowElanco
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2,4­
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Response
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2,4­
D
Task
4:
Registrant's
Response
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Product
Chemistry
Data
Requirements
DEB
Nos.
5454­
5455,
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5544
Dated
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41978002
Schriber,
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(
1991)
Chemical
Stability
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Isopropylamine
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Lab
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Unpublished
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17
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42021001
MacDaniel,
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(
1987)
Vapor
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Unpublished
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9
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Hopkins,
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(
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2,4­
Dichlorophenoxyacetic
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Dimethylamine
ES­
DR­
0008­
3556­
3.
Unpublished
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prepared
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The
Dow
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15
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Desai,
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(
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Technical
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Physical
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Lab
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Number:
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GR­
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Unpublished
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120
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42116702
Feiler,
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(
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Technical
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2,4­
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Feiler,
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(
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Technical
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Sawyer,
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Product
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Schriber,
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Chemical
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16
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Sawyer,
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1992)
Product
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Feiler,
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Technical
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Murphy,
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Determination
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2,4­
D)
Technical
Grade
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Active
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TGAI):
Lab
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Murphy,
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Response
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Rossi
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10/
05/
02):
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2,4­
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DMA
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GM052793A.
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Murphy,
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Product
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2,4­
D
TIPA
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GM052993A.
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4
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42798301
Murphy,
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Response
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Letter
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Lois
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Rossi
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1/
08/
93):
Subject:
Product
Chemistry
Review
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DowElanco
2,4­
D
IPA
FI:
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GM052793B.
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42829901
Murphy,
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(
1993)
Determination
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Dichlorophenoxyacetic
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Dimethylamine
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2,4­
D
DMA)
Technical
Grade
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Active
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TGAI):
Lab
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Unpublished
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9
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42830901
Murphy,
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Determination
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Butoxyethyl
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2,4­
D
BEE)
Technical
Grade
Active
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TGAI):
Lab
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Unpublished
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42831001
Murphy,
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Determination
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Dichlorophenoxyacetic
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Isopropylamine
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2,4­
D
IPA)
Technical
Grade
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Active
Ingredient
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TGAI):
Lab
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Murphy,
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Determination
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Dichlorophenoxyacetic
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2­
Ethylhexyl
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2,4­
D
2­
EHE)
Technical
Grade
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Active
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TGAI):
Lab
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Malone,
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Characterization
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Acetic
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Lab
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Number:
4102­
92­
0055­
AS:
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92­
0055­
AS­
001.
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47
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42857202
Malone,
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1992)
Characterization
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2,4­
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Acetic
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Lab
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Number:
4102­
92­
0056­
AS:
4102­
92­
0056­
AS­
001.
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Wojcieck,
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Color,
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2,4­
Dichlorophenoxy)
Acetic
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Lab
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Number:
4102­
92­
0082­
AS:
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92­
0082­
AS­
001.
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24
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Wojcieck,
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(
1992)
Bulk
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Salt
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2,4­
Dichlorophenoxy)
Acetic
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Lab
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Number:
4102­
92­
0083­
AS:
4102­
92­
0083­
AS­
001.
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22
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42857205
Douglass,
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1993)
Technical
Diethanolamine
Salt
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2,4­
Dichlorophenoxy)
Acetic
Acid­­
Solubility:
Lab
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4102­
92­
0057­
AS:
4102­
92­
0057­
AS­
001.
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92
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Douglass,
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1993)
Purified
Diethanolamine
Salt
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(
2,4­
Dichlorophenoxy)
Acetic
Acid­­
Vapor
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Lab
Project
Number:
4102­
92­
0058­
AS:
4102­
92­
0058­
AS­
001.
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68
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42857207
Douglass,
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1993)
Purified
Diethanolamine
Salt
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(
2,4­
Dichlorophenoxy)
Acetic
Acid­­
Octanol/
Water
Partition
Coefficient:
Lab
Project
Number:
4102­
92­
0059­
AS:
4102­
92­
0059­
AS­
001.
Unpublished
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55
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42857208
Furlong,
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pH
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Salt
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2,4­
Dichlorophenoxy)
Acetic
Acid:
Lab
Project
Number:
4102­
92­
0088­
AS:
4102­
92­
0088­
AS­
001.
Unpublished
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27
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42857209
Malone,
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(
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Technical
Diethanolamine
Salt
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(
2,4­
Dichlorophenoxy)
Acetic
Acid­­
Stability:
Lab
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Number:
4102­
92­
0085­
AS:
4102­
92­
0085­
AS­
001.
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43260501
Krause,
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Storage
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Solubility
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43314701
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Series
62­
1:
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Product
Sample
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2,4­
Dichlorophenoxy
Acetic
Acid,
Dimethylamine­
6
(
2,4­
D
DMA­
6)
Sequestered
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19
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43325001
Kinnunen,
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Series
63:
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the
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2,4­
Dichlorophenoxyacetic
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Butoxyethyl
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2,4­
D
BEE)
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Kinnunen,
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Series
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the
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2,4­
Dichlorophenoxyacetic
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2­
Ethylhexyl
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2,4­
D
2­
EHE)
TGAI:
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Kinnunen,
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Series
63:
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the
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2,4­
Dichlorophenoxyacetic
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Triisopropanolamine
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2,4­
D)
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Lab
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Kinnunen,
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Determination
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2,4­
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Kinnunen,
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Determination
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2,4­
Dichlorophenoxyacetic
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Isopropylamine
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Lab
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GH­
C
3356.
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Haefele,
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Identity
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2,4­
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Technical
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Preliminary
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2,4­
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Acetic
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Willis,
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2,4­
D
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2,4­
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D:
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Physical
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Bulk
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Willis,
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2,4­
D
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Kinnunen,
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Preliminary
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Sample
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2,4­
Dichlorophenoxyacetic
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Kinnunen,
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Preliminary
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Krause,
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Storage
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IPA
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Manufacturing­
Use­
Concentrate
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Armbruster,
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Product
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Preliminary
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Product
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GH­
C
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Series
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2,4­
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Pryce,
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Pryce,
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Batch
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98/
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Hutchinson,
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2,4­
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98/
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2,4­
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AHM/
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98/
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Group
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C
4680.
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Hamilton,
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Group
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4
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GH­
C
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Cobb,
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Group
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Product
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Isopropylamine
Technical
Manufacturing
Use
Product
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2,4­
D
Isopropylamine
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Madsen,
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Group
A:
Product
Identity
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2,4­
D
Isopropylamine
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Technical­­
High
pH
Manufacturing
Use
Product
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2,4­
D
Isopropylamine
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Hutchinson,
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Preliminary
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dichlorophenoxyacetic
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Technical
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Active
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Sanson,
D.
(
1999)
Preliminary
Analysis
of
Technical
2,4­
Dichlorophenoxyacetic
2­
Ethylhexyl
Ester:
Lab
Project
Number:
98­
019.
Unpublished
study
prepared
by
Ricerca,
Inc.
and
University
of
Missouri
Biochemistry
Department.
153
p.

44963802
Hughes,
D.
(
1999)
Determination
of
Physico­
Chemical
Properties
of
2,4­
D
IOE
Technical
Grade
Active
Ingredient
(
TGAI)
and
2,4­
D
IOE
Purified
Active
Ingredient
(
PAI)
(
Color,
Physical
State,
Odor,
Boiling
Point,
Density,
Solubility,
Vapor
Pressure,
Octanol/
Water
Partition
Coefficient,
pH,
Stability):
Lab
Project
Number:
6993­
100.
Unpublished
study
prepared
by
Covance
Laboratories
Inc.
12
p.

44963803
Sanson,
D.
(
1999)
Product
Identity,
Composition
and
Analysis
of
Technical
2,4­
Dichlorophenoxyacetic
Acid,
2­
Ethylhexyl
Ester.
Unpublished
study
prepared
by
PBI/
Gordon
Corporation.
35
p.

44963804
Sanson,
D.
(
1999)
Certified
Limits
of
Technical
2,4­
Dichlorophenoxyacetic
Acid,
2­
Ethylhexyl
Ester
and
Enforcement
Analytical
Method
of
Technical
2,4­
Dichlorophenoxyacetic
Acid,
2­
Ethylhexyl
Ester.
Unpublished
study
prepared
by
PBI/
Gordon
Corporation.
6
p.

44982101
Madsen,
S.;
Cobb,
J.;
Hackett,
B.
et
al.
(
1999)
Group
A:
Product
Identity
and
Composition
of
2,4­
D
2­
Ethylhexyl
Ester
Technical
Grade
Active
Ingredient
and
Manufacturing
Use
Product
Containing
2,4­
D
2­
Ethylhexyl
Ester
Technical:
Lab
Project
Number:
NAFST018.
Unpublished
study
prepared
by
Dow
AgroSciences
LLC.
54
p.
130
44982102
Hamilton,
T.
(
1999)
Ester
Specific
Analytical
Method
for
Determination
of
Esters
of
2,4­
Dichlorophenoxyacetic
Acid
(
2,4­
D)
and
Related
Impurities:
Lab
Project
Number:
DECO
GL­
AL
99­
000252.
Unpublished
study
prepared
by
The
Dow
Chemical
Company.
74
p.

45014801
VanderKamp,
J.;
Kastl,
P.
(
1999)
Five
Batch
Analysis
of
2,4­
D
2­
Ethyl­
1­
Hexyl
Ester
Technical:
Lab
Project
Number:
DECO
GL­
AL
99­
002231.
Unpublished
study
prepared
by
The
Dow
Chemical
Co.
42
p.

45642701
Sarff,
P.
(
2002)
Determination
of
the
Storage
Stability
and
Corrosion
Characteristics
for
DMA­
6
Sequestered
(
2,4­
D
Dimethylamine­
6
Sequestered
Herbicide):
Lab
Project
Number:
46237:
NAFST494:
NAF­
190.
Unpublished
study
prepared
by
ABC
Laboratories,
Inc.
30
p.

45692501
Lezotte,
F.;
Van
Hoven,
R.;
Nixon,
W.
(
2002)
Determination
of
Water
Solubility
of
2,4­
D
Acid
by
the
Shake
Flask
Method:
Lab
Project
Number:
467C­
103:
467/
121801/
7840/
SUB467.
Unpublished
study
prepared
by
Wildlife
International,
Ltd.
43
p.