Document ID: EPA-HQ-OPP-2007-0906-0006
Agency: epa
Document Type: Supporting & Related Material
Title: 
Posted Date: 2008-03-24T04:00Z

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

WASHINGTON, D.C.  20460

OFFICE OF PREVENTION,

PESTICIDES AND 

TOXIC SUBSTANCES

MEMORANDUM								

	

DATE:	September 6, 2007

SUBJECT: 	Tier II Drinking Water Assessment for the use of
Pyraclostrobin (P.C. Code: 099100) on Oats and Oilseed (canola and flax)
(Headline Fungicide); Corn, Soybean, and Sugar-beets (Headline
Fungicide); Fresh Herbs (crop group 19) and Tropical Fruits (avocado,
black sapote, canistel, mamey, sapote, mango, papaya sapodilla, and star
apple) (Pristine Fungicide); and Turf and Ornamentals (Insignia
Fungicide) (DP Barcodes 336190, 340588, 342584)

FROM:	Gabe Rothman, Environmental Fate and Transport Scientist

Tom Bailey, Branch Chief

Environmental Risk Branch 1

Environmental Fate and Effects Division (7507P)

TO:		Tony Kish, Risk Manager (RM-22)

John Bazuin, RM-22 Team Reviewer

	Registration Division (7507P)

	Daniel Rosenblatt,  (RM-5)

Shaja Brothers, RM-5 Team Reviewer

Interregional Research Project No. 4 (7505P)

Barry E. O’Keefe, Risk Assessor/Biologist

Registration Action Branch 3

Health Effects Division (7509P)

	

Enclosed is the Tier II drinking water assessment for proposed uses of
the active ingredient pyraclostrobin on Oats and Oilseed including
canola and flax (Section 3 request for Headline Fungicide – DP Barcode
334534); Corn, Soybean, and Sugar-beets (Section 3 request for Headline
Fungicide – DP Barcode 340588); Fresh Herbs (crop group 19) and
Tropical Fruits (avocado, black sapote, canistel, mamey, sapote, mango,
papaya sapodilla, and star apple) (IR-4 request for Pristine Fungicide
– DP Barcode 336190); and Turf and Ornamentals (Section 3 request for
Insignia Fungicide - DP Barcode 342584).  

This Tier II drinking water assessment was completed for the proposed
use of pyraclostrobin on Turf and Ornamentals, because this use
represents the highest use rate of the proposed and registered uses.  

If you have any further questions regarding this assessment, please
contact Gabriel Rothman at (703) 347-8011.



introduction

This Tier II Drinking Water Assessment for pyraclostrobin is being
submitted in order to determine if the new uses will increase the
residue concentration of pyraclostrobin in surface and ground water, to
quantify these changes, and to characterize the exposure pathways as
influenced by the fate and transport properties of pyraclostrobin.  The
new uses include the following:

Ground and Aerial Application on Oats and Oilseed including canola and
flax (Section 3 request for Headline Fungicide – DP Barcode 334534)

In-Furrow Application on Corn, Soybean, and Sugar-beets (Section 3
request for Headline Fungicide – DP Barcode 340588); Fresh Herbs (crop
group 19)

Ground and Aerial Application on Tropical Fruits (avocado, black sapote,
canistel, mamey, sapote, mango, papaya sapodilla, and star apple) (IR-4
request for Pristine Fungicide – DP Barcode 336190)

Aerial Application on Turf and Ornamentals (Section 3 request for
Insignia Fungicide - DP Barcode 342584).

This assessment was based on the application of the highest seasonal use
rate (proposed or registered) of pyraclostrobin.  The aerial application
on turf and ornamentals contains the highest seasonal application at 0.5
lbs a.i./acre with 6 maximum seasonal applications at 14 day intervals.
The proposed use rate for the aerial application on Turf and Ornamentals
is the same as for the registered use of pyraclostrobin for ground
application on turf (please see the,“Environmental Fate and Ecological
Risk Assessment for the Registration of Pyraclostrobin”, submitted
February 6, 2002.).  However, EFED believes that the aerial use of
pyraclostrobin on turf and ornamentals will possess the upper-bound
concentrations in surface and ground water since spray drift increases
and application efficiency decreases in an aerial application technique.

EXECUTIVE SUMMARY

The subject chemical addressed in this drinking water assessment is
identified by the chemical pyraclostrobin (cabamic acid,
[2-[[[1-(4-chlorophenyl)-1H-pyrazol-3-yl[oxy]methyl]phenyl]methoxy-,meth
yl ester).  The trade name for this compound is Insignia Fungicide.  The
labeled formulation of Insignia Fungicide contains the active ingredient
of pyraclostrobin by 20 percent with other ingredients accounting for
the remaining 80 percent.  

The chemical identification number is 099100.  Figure 1 shows the
chemical composition of pyraclostrobin

Figure 1.  Chemical structure of pyraclostrobin.

 

Measures of exposure for pyraclostrobin in this drinking water
assessment are obtained through modeling efforts only, since
national-scale monitoring data were not identified. The Tier II drinking
water assessment was performed using the Tier II PRZM/EXAMS (PE4V01 perl
shell with PRZM 3.12 beta dated 5/24/01 and EXAMS version 2.98, 7/18/02)
to assess surface water.  Ground water concentrations were estimated
using a Tier I SCI-GROW model (version 2.3, May 16, 2006) since a Tier
II model has not been developed to assess ground water.

Acute effects of pyraclostrobin residues in drinking water are expressed
in annual peak one-in-ten year concentrations, chronic effects in annual
average one-in-ten year concentrations, and cancer effects in 30-year
average concentrations.  The upper-bound Tier II modeling predicts that
the concentrations of pyraclostrobin in surface water are not likely to
exceed 35.6 µg/L for the peak concentration, 2.3 µg/L for the annual
average concentration, and 1.5 µg/L for the 30-year average
concentrations.  The ground water assessment was based on the latest
proposed use rate of pyraclostrobin on turf and ornamentals.  The
SCI-GROW model predicts the acute and chronic concentrations of
pyraclostrobin in shallow ground water to be 0.02 g/L (0.02 ppb).

PROBLEM FORMULATION

Pyraclostrobin is not likely to reach ground water since pyraclostrobin
is tightly bound to soils with Kocs between 6,000 mg/L and 16,000 mg/L
in all soil studies with an arithmetic mean of 9,304 mg/L and median of
7,889 mg/L.  However, EFED believes pyraclostrobin can potentially
contaminate surface water through runoff.  Laboratory and terrestrial
field studies suggest that pyraclostrobin is moderately persistent in
aerobic environments with aerobic aquatic and aerobic soil half-lives
above 80 days but more rapidly decays in an anaerobic soil environment
with half-lives around 3 days.  Pyraclostrobin is also practically
stable with respect to hydrolysis but does undergo rapid photolysis. 
Pyraclostrobin is also subject to spray drift in the proposed foliar
applications.  

This drinking water assessment only addresses the parent compound. 
Major degredates of pyraclostrobin were not found to be of toxicological
concern.  

Figure 2 is the conceptual model showing all exposure pathways from
pyraclostrobin aerial application on Turf and Ornamental effects on
drinking water.  For additional information on pyraclostrobin fate and
transport properties, please refer to the original drinking assessment
for the Florida Turf scenario included with the, “Environmental Fate
and Ecological Risk Assessment for the Registration of
Pyraclostrobin”, submitted February 6, 2002.  

Figure 2.  Conceptual model for the fate, transport, and effects
pathways for aerial application of pyraclostrobin to Turf and
Ornamentals.

Analysis

Surface Water

Two Turf scenarios and six Nursery scenarios, as a surrogate to the
Ornamentals crop group, were considered in the surface water assessment
[please see EFED policy memo titled, “Outdoor Nursery Pesticide Root
Zone Model (PRZM) Scenarios for Use in Surface Water Assessments”,
dated July 26, 2007].  A PCA factor of 1.0 was used for all scenarios
consistent with EFED policy (see EFED policy memo, “Golf Course
Adjustment Factors for Simulated Aquatic Exposure Concentrations”,
dated December 7, 2005).  

The PRZM/EXAMS fate parameters and crop-specific inputs and are shown in
Tables 1 and 2 respectively.  The only data gaps in this assessment
includes the lack of aerobic aquatic and anaerobic aquatic metabolism
studies.  Table 1 contains a description of how these data gaps are
addressed in the surface water assessment.  Another potential limitation
in this assessment is that the Nursery scenarios did not address
irrigation.  The upper-bound concentrations should simulate as much
exposure to water from sources such as irrigation channels.  However,
the PRZM model version 3.12 beta does not simulate irrigation.

The estimated concentrations of pyraclostrobin in surface water for each
scenario are shown in Table 3.  The upper-bound estimated pyraclostrobin
residue concentration in surface water appears to result from the New
Jersey Nursery scenario with 6 aerial applications of 0.5 lbs a.i./acre,
14 day intervals.  The PRZM/EXAMS output files are provided in Appendix
A.

Table 1.  PRZM/EXAMS environmental fate input parameter values for
Pyraclostrobin.

PRZM/EXAMS Input Parameter	Input Value and Unit	Comment	Source

Molecular Weight	388 g/mol

Product Chemistry

Hydrolysis (t1/2)	0 days	stable	MRID 45118627

Aerobic aquatic metabolism (t1/2)	496.28 days	No data available and
stable to hydrolysis.  Used twice the  aerobic soil metabolism half-life
of 248.14 days (based on the upper 90th percentile of the mean of half
lives in six studies) 	EFED Guidance

MRID 45118631

MRID 45118632

Table 1 (continued).  PRZM/EXAMS environmental fate input parameter
values for Pyraclostrobin. 

PRZM/EXAMS Input Parameter	Input Value and Unit	Comment	Source

Anaerobic  aquatic metabolism (t1/2)	6.6 days	No data available.  Used
twice the anaerobic soil half-life of 3.3 days (based on the upper 90th
percentile of the mean of half lives in six studies)	EFED Guidance 

MRID 45118635

MRID 45118636

Aerobic soil metabolism (t1/2)	248.14 days	Upper 90th percentile of the
mean of half-lives in six studies	MRID 45118631

MRID 45118632

MRID 45367504

Vapor Pressure at 20 ºC	1.95 x 10-8 torr

Product Chemistry

Solubility in Water at 20ºC	24.1 mg/L	Product Chemistry x 10	EFED
Guidance

Koc	9,304 ml/g	Mean of Kocs in six studies	MRID 45160502

Henry’s Law Constant 	4.13 x 10-9 atm·m3/mol	Based on solubility and
vapor pressure	EFED Guidance

Aqueous Photolysis (t1/2)	0.08 days	Maximum dark controlled aqueous
photolysis half-life of two studies	EFED Guidance

MRID 45118629

CAM	2 (linear application based on crop canopy)	aerial applied	EFED
Guidance

Spray drift fraction	0.16

EFED Guidance

Application Efficiency	0.95

EFED Guidance

Application Rate	0.5 lb a.i./A 

(0.56 kg a.i./ha)

Registration Action 7969-184 label

Applications and Intervals	6 treatments, 14 days apart

Registration Action 7969-184 label

Incorporation Depth	0 cm	Aerial application	Registration Action 7969-184
label



Table 2.  PRZM/EXAMS crop-specific input parameter values for
Pyraclostrobin.

Crop Scenario	PRZM/EXAMS Input Parameters

	Initial Application Date	Meteorological File

FL Turf	March 15	w12834.dvf

PA Turf	June 1	w14737.dvf

CA Nursery (no irrigation)1	March 15	w23188.dvf

FL Nursery (no irrigation)1	March 15	w12834.dvf

MI Nursery (no irrigation)1	June 15	w14840.dvf

NJ Nursery (no irrigation)1	May 1	w93730.dvf

OR Nursery (no irrigation)1	January 15	w24229.dvf

TN Nursery (no irrigation)1	June 1	w13882.dvf

1 Note – No irrigation scenarios used in PRZM 3.12 beta modeling.

Table 3.  Estimated concentrations of pyraclostrobin in surface water,
0.5 lb a.i./A, 6 applications, 14 days apart, aerial application.

Crop Scenario	PRZM/EXAMS Estimated Concentrations in Surface Water
(g/L)

	1-in-10 year Annual Peak (Acute)	1-in-10 year Annual Mean (Chronic)	30
year annual mean

(Cancer)

FL Turf	11.6	1.1	0.8

PA Turf	13.5	0.9	0.7

CA Nursery (no irrigation)	32.4	2.1	1.2

FL Nursery (no irrigation)	22.3	2.1	1.4

MI Nursery (no irrigation)	19.4	1.4	1.0

NJ Nursery (no irrigation)	35.6	2.3	1.5

OR Nursery (no irrigation)	6.1	0.9	0.8

TN Nursery (no irrigation)	17.3	2.2	1.5

Notes:

1. No irrigation scenarios used in PRZM 3.12 beta modeling.

2. Upper-bound estimated concentrations in surface water highlighted in
bold.

3. Maximum estimated concentrations in surface water based on PCA of 1.0
for all scenarios.

ground Water

Ground water concentrations were estimated using a Tier I SCI-GROW model
(version 2.3, May 16, 2006).  The ground water concentrations generated
by SCI-GROW are based on the largest 90-day average recorded during the
sampling period.  Since there is relatively little temporal variation in
ground water concentrations compared to surface water, the model
predicted value can be considered to represent both the acute and
chronic values.

g/L (0.02 ppb).  The SCI-GROW output files for both scenarios are
provided in Appendix B.

The ground water concentrations generated by SCI-GROW are based on the
largest 90-day average recorded during the sampling period.  Since there
is relatively little temporal variation in ground water concentrations
compared to surface water, the concentration of 0.02 µg/L can be
considered as both the acute and chronic values.

Table 4.  SCI-GROW environmental fate input parameter values for
Pyraclostrobin.

SCI-GROW Fate Input Parameter	Input Value and Unit	Comments	Source

Koc	7,889 ml/g	Median value of six studies	EFED Guidance

Application Rate	0.5 lb a.i./acre

Registration Action 7969-184 label

Number of Applications	6

Registration Action 7969-184 label

Use Rate (Maximum total per season)	3.0 lb a.i./acre/season	Based on 6
applications per season of 0.5 lb a.i./acre	Registration Action 7969-184
label

Aerobic Soil Metabolism half-life	105	Median value of six studies	EFED
Guidance

g/L)

0.02

Exposure Characterization

This assessment demonstrates that exposure of pyraclostrobin in surface
water is very sensitive to runoff.  The New Jersey Nursery scenario used
in PRZM/EXAMS to diagnose the upper-bound pyraclostrobin residue surface
water concentration reflects a region with high rainfall and high
vulnerability to runoff.

As expected, pyraclostrobin did not show high levels of ground water
concentrations.  The highly immobile property of pyraclostrobin most
probably contributes to this result.  The predicted SCI-GROW
concentration should be conservative typical of a Tier I model.  

REFERENCES

Barrett, M.  Proposal For a Method to Determine Screening Concentration
Estimates for Drinking Water Derived from Ground Water Studies. 
EFED/OPP.  September 20, 1997.

U.S. Environmental Protection Agency.  1995.  GENEEC: A Screening Model
for Pesticide Environmental Exposure Assessment. The International
Symposium on Water Quality Monitoring, April 2-5 1995.  American Society
of Agricultural Engineers. p 485.

U.S. Environmental Protection Agency.  1996. Drinking Water Regulations
and Health Advisories.  USEPA Report.  U.S. Government Printing Office,
Washington, DC.Appendix A – PRZM/EXAMS Output Files

stored as PYFLTfA.out

Chemical: pyraclostrobin

PRZM environment: FLturfC.txt	modified Monday, 16 June 2003 at 13:48:06

EXAMS environment: ir298.exv	modified Thuday, 29 August 2002 at 15:34:12

Metfile: w12834.dvf	modified Wedday, 3 July 2002 at 09:04:28

Water segment concentrations (ppb)

Year	Peak	96 hr	21 Day	60 Day	90 Day	Yearly

1961	4.055	3.221	2.231	2	1.777	0.6416

1962	4.439	3.531	2.202	2.01	1.783	0.7814

1963	8.729	6.943	3.65	2.332	2.202	0.9326

1964	9.865	8.276	4.041	2.656	2.233	1.137

1965	4.939	3.942	2.255	1.995	1.965	0.6107

1966	14.08	11.23	6.233	3.864	3.377	1.207

1967	4.771	3.798	2.172	1.975	1.855	0.696

1968	10.71	8.759	4.935	3.279	2.862	1.151

1969	6.336	5.076	2.848	2.232	2.054	0.9393

1970	4.135	3.294	2.297	2.082	1.845	0.5156

1971	4.396	3.488	2.52	2.255	1.965	0.8556

1972	6.821	5.398	3.513	2.698	2.394	1.034

1973	4.058	3.214	2.219	2.042	1.808	0.5838

1974	6.176	4.918	2.304	2.024	1.872	0.8559

1975	4.303	3.413	2.317	2.065	1.827	0.5709

1976	12.07	9.633	5.199	3.499	3.213	0.987

1977	4.06	3.554	2.337	1.977	1.823	0.7116

1978	4.692	3.69	2.792	2.292	2.099	0.7661

1979	7.901	6.253	3.908	2.65	2.264	1.094

1980	4.317	3.416	2.317	2.073	1.827	0.5181

1981	4.143	3.279	2.348	1.983	1.792	0.694

1982	6.724	5.328	3.152	2.527	2.39	0.8351

1983	4.908	3.911	3.051	2.343	2.289	0.9821

1984	9.024	7.218	3.59	2.717	2.424	0.8466

1985	4.067	3.338	2.298	2.03	1.788	0.651

1986	5.441	4.295	2.458	1.925	1.717	0.7894

1987	5.055	4.183	2.72	2.227	1.941	0.5839

1988	4.339	3.417	2.177	1.982	1.8	0.64

1989	11.68	9.5	4.698	2.045	1.798	0.9299

1990	3.954	3.125	2.157	1.959	1.747	0.5444

Sorted results

Prob.	Peak	96 hr	21 Day	60 Day	90 Day	Yearly

0.032258064516129	14.08	11.23	6.233	3.864	3.377	1.207

0.0645161290322581	12.07	9.633	5.199	3.499	3.213	1.151

0.0967741935483871	11.68	9.5	4.935	3.279	2.862	1.137

0.129032258064516	10.71	8.759	4.698	2.717	2.424	1.094

0.161290322580645	9.865	8.276	4.041	2.698	2.394	1.034

0.193548387096774	9.024	7.218	3.908	2.656	2.39	0.987

0.225806451612903	8.729	6.943	3.65	2.65	2.289	0.9821

0.258064516129032	7.901	6.253	3.59	2.527	2.264	0.9393

0.290322580645161	6.821	5.398	3.513	2.343	2.233	0.9326

0.32258064516129	6.724	5.328	3.152	2.332	2.202	0.9299

0.354838709677419	6.336	5.076	3.051	2.292	2.099	0.8559

0.387096774193548	6.176	4.918	2.848	2.255	2.054	0.8556

0.419354838709677	5.441	4.295	2.792	2.232	1.965	0.8466

0.451612903225806	5.055	4.183	2.72	2.227	1.965	0.8351

0.483870967741936	4.939	3.942	2.52	2.082	1.941	0.7894

0.516129032258065	4.908	3.911	2.458	2.073	1.872	0.7814

0.548387096774194	4.771	3.798	2.348	2.065	1.855	0.7661

0.580645161290323	4.692	3.69	2.337	2.045	1.845	0.7116

0.612903225806452	4.439	3.554	2.317	2.042	1.827	0.696

0.645161290322581	4.396	3.531	2.317	2.03	1.827	0.694

0.67741935483871	4.339	3.488	2.304	2.024	1.823	0.651

0.709677419354839	4.317	3.417	2.298	2.01	1.808	0.6416

0.741935483870968	4.303	3.416	2.297	2	1.8	0.64

0.774193548387097	4.143	3.413	2.255	1.995	1.798	0.6107

0.806451612903226	4.135	3.338	2.231	1.983	1.792	0.5839

0.838709677419355	4.067	3.294	2.219	1.982	1.788	0.5838

0.870967741935484	4.06	3.279	2.202	1.977	1.783	0.5709

0.903225806451613	4.058	3.221	2.177	1.975	1.777	0.5444

0.935483870967742	4.055	3.214	2.172	1.959	1.747	0.5181

0.967741935483871	3.954	3.125	2.157	1.925	1.717	0.5156

0.1	11.583	9.4259	4.9113	3.2228	2.8182	1.1327

					Average of yearly averages:	0.802853333333334

Inputs generated by pe4.pl - 8-August-2003

Data used for this run:

Output File: PYFLTfA

Metfile:	w12834.dvf

PRZM scenario:	FLturfC.txt

EXAMS environment file:	ir298.exv

Chemical Name:	pyraclostrobin

Description	Variable Name	Value	Units	Comments

Molecular weight	mwt	388	g/mol

Henry's Law Const.	henry	4.12e-9	atm-m^3/mol

Vapor Pressure	vapr	1.95e-08	torr

Solubility	sol	24.1	mg/L

Kd	Kd		mg/L

Koc	Koc	9304	mg/L

Photolysis half-life	kdp	0.08	days	Half-life

Aerobic Aquatic Metabolism	kbacw	496.28	days	Halfife

Anaerobic Aquatic Metabolism	kbacs	6.6	days	Halfife

Aerobic Soil Metabolism	asm	248.14	days	Halfife

Hydrolysis:	pH 7	0	days	Half-life

Method:	CAM	2	integer	See PRZM manual

Incorporation Depth:	DEPI	0	cm

Application Rate:	TAPP	0.56	kg/ha

Application Efficiency:	APPEFF	0.95	fraction

Spray Drift	DRFT	0.16	fraction of application rate applied to pond

Application Date	Date	15-03	dd/mm or dd/mmm or dd-mm or dd-mmm

Interval 1	interval	14	days	Set to 0 or delete line for single app.

Interval 2	interval	14	days	Set to 0 or delete line for single app.

Interval 3	interval	14	days	Set to 0 or delete line for single app.

Interval 4	interval	14	days	Set to 0 or delete line for single app.

Interval 5	interval	14	days	Set to 0 or delete line for single app.

Record 17:	FILTRA	

	IPSCND	1

	UPTKF	

Record 18:	PLVKRT	

	PLDKRT	

	FEXTRC	0.5

Flag for Index Res. Run	IR	IR

Flag for runoff calc.	RUNOFF	total	none, monthly or total(average of
entire run)

stored as PYPATfA.out

Chemical: pyraclostrobin

PRZM environment: PAturfC.txt	modified Satday, 12 October 2002 at
16:27:02

EXAMS environment: ir298.exv	modified Thuday, 29 August 2002 at 15:34:12

Metfile: w14737.dvf	modified Wedday, 3 July 2002 at 09:06:12

Water segment concentrations (ppb)

Year	Peak	96 hr	21 Day	60 Day	90 Day	Yearly

1961	5.327	4.292	3.326	2.529	2.17	0.5729

1962	4.942	3.975	2.671	2.358	2.092	0.6385

1963	4.076	3.392	2.376	2.115	1.916	0.6637

1964	4.115	3.318	2.351	2.146	1.905	0.5837

1965	4.099	3.315	2.334	2.107	1.9	0.5881

1966	4.059	3.26	2.319	2.08	1.914	0.675

1967	5.52	4.426	3.325	2.708	2.322	0.7096

1968	4.129	3.335	2.352	2.16	1.98	0.5956

1969	13.78	11.15	6.454	3.624	2.997	0.8004

1970	4.454	3.598	2.649	2.291	2.01	0.6999

1971	5.847	4.695	3.817	2.797	2.512	0.9384

1972	6.557	5.338	4.095	3.129	2.659	0.9371

1973	7.942	6.384	3.789	2.709	2.302	0.8121

1974	5.023	4.072	2.903	2.463	2.26	0.7387

1975	4.388	3.858	2.727	2.324	2.056	0.7881

1976	7.936	6.365	3.63	2.639	2.345	0.803

1977	4.196	3.372	2.416	2.186	1.956	0.662

1978	8.476	6.971	4.082	2.87	2.498	0.7654

1979	4.362	3.693	2.716	2.327	2.057	0.8382

1980	4.059	3.261	2.284	2.085	1.855	0.5281

1981	4.108	3.303	2.325	2.147	1.909	0.53

1982	11.77	9.751	5.243	3.349	3.058	0.8745

1983	4.179	3.488	2.362	2.152	1.915	0.6643

1984	5.127	4.141	3.187	2.662	2.375	0.7304

1985	16.54	13.18	6.406	2.967	2.699	1.143

1986	4.364	3.529	2.563	2.192	1.956	0.5999

1987	13.67	10.99	5.428	3.484	3.054	1.02

1988	4.813	3.866	2.66	2.269	2.024	0.6722

1989	4.255	3.432	2.498	2.279	2.036	0.668

1990	6.965	5.614	3.774	2.778	2.494	0.7534

Sorted results

Prob.	Peak	96 hr	21 Day	60 Day	90 Day	Yearly

0.032258064516129	16.54	13.18	6.454	3.624	3.058	1.143

0.0645161290322581	13.78	11.15	6.406	3.484	3.054	1.02

0.0967741935483871	13.67	10.99	5.428	3.349	2.997	0.9384

0.129032258064516	11.77	9.751	5.243	3.129	2.699	0.9371

0.161290322580645	8.476	6.971	4.095	2.967	2.659	0.8745

0.193548387096774	7.942	6.384	4.082	2.87	2.512	0.8382

0.225806451612903	7.936	6.365	3.817	2.797	2.498	0.8121

0.258064516129032	6.965	5.614	3.789	2.778	2.494	0.803

0.290322580645161	6.557	5.338	3.774	2.709	2.375	0.8004

0.32258064516129	5.847	4.695	3.63	2.708	2.345	0.7881

0.354838709677419	5.52	4.426	3.326	2.662	2.322	0.7654

0.387096774193548	5.327	4.292	3.325	2.639	2.302	0.7534

0.419354838709677	5.127	4.141	3.187	2.529	2.26	0.7387

0.451612903225806	5.023	4.072	2.903	2.463	2.17	0.7304

0.483870967741936	4.942	3.975	2.727	2.358	2.092	0.7096

0.516129032258065	4.813	3.866	2.716	2.327	2.057	0.6999

0.548387096774194	4.454	3.858	2.671	2.324	2.056	0.675

0.580645161290323	4.388	3.693	2.66	2.291	2.036	0.6722

0.612903225806452	4.364	3.598	2.649	2.279	2.024	0.668

0.645161290322581	4.362	3.529	2.563	2.269	2.01	0.6643

0.67741935483871	4.255	3.488	2.498	2.192	1.98	0.6637

0.709677419354839	4.196	3.432	2.416	2.186	1.956	0.662

0.741935483870968	4.179	3.392	2.376	2.16	1.956	0.6385

0.774193548387097	4.129	3.372	2.362	2.152	1.916	0.5999

0.806451612903226	4.115	3.335	2.352	2.147	1.915	0.5956

0.838709677419355	4.108	3.318	2.351	2.146	1.914	0.5881

0.870967741935484	4.099	3.315	2.334	2.115	1.909	0.5837

0.903225806451613	4.076	3.303	2.325	2.107	1.905	0.5729

0.935483870967742	4.059	3.261	2.319	2.085	1.9	0.53

0.967741935483871	4.059	3.26	2.284	2.08	1.855	0.5281

0.1	13.48	10.8661	5.4095	3.327	2.9672	0.93827

					Average of yearly averages:	0.73314

Inputs generated by pe4.pl - 8-August-2003

Data used for this run:

Output File: PYPATfA

Metfile:	w14737.dvf

PRZM scenario:	PAturfC.txt

EXAMS environment file:	ir298.exv

Chemical Name:	pyraclostrobin

Description	Variable Name	Value	Units	Comments

Molecular weight	mwt	388	g/mol

Henry's Law Const.	henry	4.12e-9	atm-m^3/mol

Vapor Pressure	vapr	1.95e-08	torr

Solubility	sol	24.1	mg/L

Kd	Kd		mg/L

Koc	Koc	9304	mg/L

Photolysis half-life	kdp	0.08	days	Half-life

Aerobic Aquatic Metabolism	kbacw	496.28	days	Halfife

Anaerobic Aquatic Metabolism	kbacs	6.6	days	Halfife

Aerobic Soil Metabolism	asm	248.14	days	Halfife

Hydrolysis:	pH 7	0	days	Half-life

Method:	CAM	2	integer	See PRZM manual

Incorporation Depth:	DEPI	0	cm

Application Rate:	TAPP	0.56	kg/ha

Application Efficiency:	APPEFF	0.95	fraction

Spray Drift	DRFT	0.16	fraction of application rate applied to pond

Application Date	Date	01-06	dd/mm or dd/mmm or dd-mm or dd-mmm

Interval 1	interval	14	days	Set to 0 or delete line for single app.

Interval 2	interval	14	days	Set to 0 or delete line for single app.

Interval 3	interval	14	days	Set to 0 or delete line for single app.

Interval 4	interval	14	days	Set to 0 or delete line for single app.

Interval 5	interval	14	days	Set to 0 or delete line for single app.

Record 17:	FILTRA	

	IPSCND	1

	UPTKF	

Record 18:	PLVKRT	

	PLDKRT	

	FEXTRC	0.5

Flag for Index Res. Run	IR	IR

Flag for runoff calc.	RUNOFF	total	none, monthly or total(average of
entire run)

stored as PYCANuA.out

Chemical: pyraclostrobin

PRZM environment: CAnursery_NirrigC.txt	modified Monday, 16 April 2007
at 14:26:46

EXAMS environment: ir298.exv	modified Thuday, 29 August 2002 at 15:34:12

Metfile: w23188.dvf	modified Wedday, 3 July 2002 at 09:04:22

Water segment concentrations (ppb)

Year	Peak	96 hr	21 Day	60 Day	90 Day	Yearly

1961	5.541	4.458	2.319	2.048	1.829	0.6103

1962	13.14	11.22	5.727	3.025	2.693	0.9693

1963	12.29	9.773	4.657	2.223	2.038	1.111

1964	4.099	3.281	2.313	2.09	1.861	0.5685

1965	24.23	19.94	13.9	8.666	5.777	2.287

1966	14.09	12.19	6.029	2.54	2.099	1.173

1967	13.28	11.53	5.79	2.931	2.001	1.289

1968	5.061	4.025	2.638	2.315	2.209	0.6328

1969	34.78	28.05	14.55	7.132	5.504	1.705

1970	15.18	12.24	6.82	3.985	3.37	1.298

1971	5.616	4.505	3.204	2.516	2.196	0.8965

1972	8.611	7.446	4.11	2.201	1.841	0.8739

1973	4.288	3.444	2.414	2.202	2.032	0.6213

1974	22.52	17.87	8.571	3.408	2.348	1.444

1975	7.449	5.987	4.242	3.712	3.23	0.9202

1976	16.62	14.69	7.797	4.091	3.832	1.385

1977	33.21	28.26	15.17	7.06	5.285	2.265

1978	9.761	8.415	4.263	2.351	2.114	1.065

1979	11.53	9.229	4.455	2.897	2.542	1.053

1980	14.09	11.41	5.76	4.398	3.704	1.298

1981	24.13	19.25	9.377	3.846	3.284	1.545

1982	23.04	18.51	10.23	5.566	4.338	1.385

1983	5.963	4.86	3.643	3.004	2.725	0.9371

1984	9.296	7.438	3.31	2.014	1.785	0.6855

1985	34.5	27.69	19.32	9.547	6.365	2.197

1986	8.375	6.708	4.639	3.537	3.01	1.47

1987	7.74	6.179	2.942	2.405	2.084	1.021

1988	25.45	20.44	11.87	6.16	4.648	1.495

1989	9.585	7.632	2.379	2.153	1.932	0.6058

1990	5.973	4.902	3.379	2.142	1.993	0.8259

Sorted results

Prob.	Peak	96 hr	21 Day	60 Day	90 Day	Yearly

0.032258064516129	34.78	28.26	19.32	9.547	6.365	2.287

0.0645161290322581	34.5	28.05	15.17	8.666	5.777	2.265

0.0967741935483871	33.21	27.69	14.55	7.132	5.504	2.197

0.129032258064516	25.45	20.44	13.9	7.06	5.285	1.705

0.161290322580645	24.23	19.94	11.87	6.16	4.648	1.545

0.193548387096774	24.13	19.25	10.23	5.566	4.338	1.495

0.225806451612903	23.04	18.51	9.377	4.398	3.832	1.47

0.258064516129032	22.52	17.87	8.571	4.091	3.704	1.444

0.290322580645161	16.62	14.69	7.797	3.985	3.37	1.385

0.32258064516129	15.18	12.24	6.82	3.846	3.284	1.385

0.354838709677419	14.09	12.19	6.029	3.712	3.23	1.298

0.387096774193548	14.09	11.53	5.79	3.537	3.01	1.298

0.419354838709677	13.28	11.41	5.76	3.408	2.725	1.289

0.451612903225806	13.14	11.22	5.727	3.025	2.693	1.173

0.483870967741936	12.29	9.773	4.657	3.004	2.542	1.111

0.516129032258065	11.53	9.229	4.639	2.931	2.348	1.065

0.548387096774194	9.761	8.415	4.455	2.897	2.209	1.053

0.580645161290323	9.585	7.632	4.263	2.54	2.196	1.021

0.612903225806452	9.296	7.446	4.242	2.516	2.114	0.9693

0.645161290322581	8.611	7.438	4.11	2.405	2.099	0.9371

0.67741935483871	8.375	6.708	3.643	2.351	2.084	0.9202

0.709677419354839	7.74	6.179	3.379	2.315	2.038	0.8965

0.741935483870968	7.449	5.987	3.31	2.223	2.032	0.8739

0.774193548387097	5.973	4.902	3.204	2.202	2.001	0.8259

0.806451612903226	5.963	4.86	2.942	2.201	1.993	0.6855

0.838709677419355	5.616	4.505	2.638	2.153	1.932	0.6328

0.870967741935484	5.541	4.458	2.414	2.142	1.861	0.6213

0.903225806451613	5.061	4.025	2.379	2.09	1.841	0.6103

0.935483870967742	4.288	3.444	2.319	2.048	1.829	0.6058

0.967741935483871	4.099	3.281	2.313	2.014	1.785	0.5685

0.1	32.434	26.965	14.485	7.1248	5.4821	2.1478

					Average of yearly averages:	1.18777

Inputs generated by pe4.pl - 8-August-2003

Data used for this run:

Output File: PYCANuA

Metfile:	w23188.dvf

PRZM scenario:	CAnursery_NirrigC.txt

EXAMS environment file:	ir298.exv

Chemical Name:	pyraclostrobin

Description	Variable Name	Value	Units	Comments

Molecular weight	mwt	388	g/mol

Henry's Law Const.	henry	4.12e-9	atm-m^3/mol

Vapor Pressure	vapr	1.95e-08	torr

Solubility	sol	24.1	mg/L

Kd	Kd		mg/L

Koc	Koc	9304	mg/L

Photolysis half-life	kdp	0.08	days	Half-life

Aerobic Aquatic Metabolism	kbacw	496.28	days	Halfife

Anaerobic Aquatic Metabolism	kbacs	6.6	days	Halfife

Aerobic Soil Metabolism	asm	248.14	days	Halfife

Hydrolysis:	pH 7	0	days	Half-life

Method:	CAM	2	integer	See PRZM manual

Incorporation Depth:	DEPI	0	cm

Application Rate:	TAPP	0.56	kg/ha

Application Efficiency:	APPEFF	0.95	fraction

Spray Drift	DRFT	0.16	fraction of application rate applied to pond

Application Date	Date	15-03	dd/mm or dd/mmm or dd-mm or dd-mmm

Interval 1	interval	14	days	Set to 0 or delete line for single app.

Interval 2	interval	14	days	Set to 0 or delete line for single app.

Interval 3	interval	14	days	Set to 0 or delete line for single app.

Interval 4	interval	14	days	Set to 0 or delete line for single app.

Interval 5	interval	14	days	Set to 0 or delete line for single app.

Record 17:	FILTRA	

	IPSCND	1

	UPTKF	

Record 18:	PLVKRT	

	PLDKRT	

	FEXTRC	0.5

Flag for Index Res. Run	IR	IR

Flag for runoff calc.	RUNOFF	total	none, monthly or total(average of
entire run)

stored as PYFLNuA.out

Chemical: pyraclostrobin

PRZM environment: FLnursery_NirrigC.txt	modified Tueday, 17 April 2007
at 08:28:20

EXAMS environment: ir298.exv	modified Thuday, 29 August 2002 at 15:34:12

Metfile: w12834.dvf	modified Wedday, 3 July 2002 at 09:04:28

Water segment concentrations (ppb)

Year	Peak	96 hr	21 Day	60 Day	90 Day	Yearly

1961	7.808	6.258	3.397	2.271	2.24	1.09

1962	9.488	7.584	4.256	3.661	3.174	1.53

1963	16.54	13.2	7.258	4.654	3.886	1.64

1964	17.71	14.9	7.522	4.841	4.641	2.107

1965	13.86	11.1	6.478	3.449	2.955	1.076

1966	24.08	19.28	11.26	7.275	6.14	2.184

1967	11.54	9.236	5.648	3.39	3.035	1.296

1968	23.05	18.92	11.08	7.478	5.652	2.215

1969	11.76	9.412	5.392	3.79	3.062	1.707

1970	5.665	4.479	2.595	2.298	2.09	0.7786

1971	9.409	7.555	3.788	2.909	2.416	1.52

1972	12.27	10.31	5.526	3.592	3.543	1.751

1973	4.712	3.844	2.7	2.287	2.067	1.046

1974	9.603	7.749	4.552	3.509	3.098	1.608

1975	5.746	4.62	2.879	2.346	2.372	1.073

1976	22.66	18.2	10.47	6.63	5.61	1.752

1977	8.251	6.584	4.479	3.095	2.279	1.307

1978	9.35	7.46	4.602	3.294	3.042	1.551

1979	11.87	10.03	6.343	3.5	3.536	2.06

1980	5.587	4.424	3.099	2.491	2.174	0.9522

1981	11.36	9.038	6.413	3.207	2.559	1.303

1982	13.3	10.58	5.575	3.754	3.81	1.565

1983	11.27	9.006	6.461	3.847	3.548	2.007

1984	15.27	12.94	6.395	3.976	3.443	1.617

1985	7.75	6.171	3.167	2.609	2.523	1.188

1986	12.27	9.915	6.618	3.842	2.908	1.4

1987	7.492	5.99	3.659	2.74	2.351	1.027

1988	7.248	5.71	2.742	2.175	2.066	1.063

1989	19.08	15.83	8.196	3.44	2.399	1.397

1990	5.182	4.108	2.359	2.074	1.879	0.9433

Sorted results

Prob.	Peak	96 hr	21 Day	60 Day	90 Day	Yearly

0.032258064516129	24.08	19.28	11.26	7.478	6.14	2.215

0.0645161290322581	23.05	18.92	11.08	7.275	5.652	2.184

0.0967741935483871	22.66	18.2	10.47	6.63	5.61	2.107

0.129032258064516	19.08	15.83	8.196	4.841	4.641	2.06

0.161290322580645	17.71	14.9	7.522	4.654	3.886	2.007

0.193548387096774	16.54	13.2	7.258	3.976	3.81	1.752

0.225806451612903	15.27	12.94	6.618	3.847	3.548	1.751

0.258064516129032	13.86	11.1	6.478	3.842	3.543	1.707

0.290322580645161	13.3	10.58	6.461	3.79	3.536	1.64

0.32258064516129	12.27	10.31	6.413	3.754	3.443	1.617

0.354838709677419	12.27	10.03	6.395	3.661	3.174	1.608

0.387096774193548	11.87	9.915	6.343	3.592	3.098	1.565

0.419354838709677	11.76	9.412	5.648	3.509	3.062	1.551

0.451612903225806	11.54	9.236	5.575	3.5	3.042	1.53

0.483870967741936	11.36	9.038	5.526	3.449	3.035	1.52

0.516129032258065	11.27	9.006	5.392	3.44	2.955	1.4

0.548387096774194	9.603	7.749	4.602	3.39	2.908	1.397

0.580645161290323	9.488	7.584	4.552	3.294	2.559	1.307

0.612903225806452	9.409	7.555	4.479	3.207	2.523	1.303

0.645161290322581	9.35	7.46	4.256	3.095	2.416	1.296

0.67741935483871	8.251	6.584	3.788	2.909	2.399	1.188

0.709677419354839	7.808	6.258	3.659	2.74	2.372	1.09

0.741935483870968	7.75	6.171	3.397	2.609	2.351	1.076

0.774193548387097	7.492	5.99	3.167	2.491	2.279	1.073

0.806451612903226	7.248	5.71	3.099	2.346	2.24	1.063

0.838709677419355	5.746	4.62	2.879	2.298	2.174	1.046

0.870967741935484	5.665	4.479	2.742	2.287	2.09	1.027

0.903225806451613	5.587	4.424	2.7	2.271	2.067	0.9522

0.935483870967742	5.182	4.108	2.595	2.175	2.066	0.9433

0.967741935483871	4.712	3.844	2.359	2.074	1.879	0.7786

0.1	22.302	17.963	10.2426	6.4511	5.5131	2.1023

					Average of yearly averages:	1.45847

Inputs generated by pe4.pl - 8-August-2003

Data used for this run:

Output File: PYFLNuA

Metfile:	w12834.dvf

PRZM scenario:	FLnursery_NirrigC.txt

EXAMS environment file:	ir298.exv

Chemical Name:	pyraclostrobin

Description	Variable Name	Value	Units	Comments

Molecular weight	mwt	388	g/mol

Henry's Law Const.	henry	4.12e-9	atm-m^3/mol

Vapor Pressure	vapr	1.95e-08	torr

Solubility	sol	24.1	mg/L

Kd	Kd		mg/L

Koc	Koc	9304	mg/L

Photolysis half-life	kdp	0.08	days	Half-life

Aerobic Aquatic Metabolism	kbacw	496.28	days	Halfife

Anaerobic Aquatic Metabolism	kbacs	6.6	days	Halfife

Aerobic Soil Metabolism	asm	248.14	days	Halfife

Hydrolysis:	pH 7	0	days	Half-life

Method:	CAM	2	integer	See PRZM manual

Incorporation Depth:	DEPI	0	cm

Application Rate:	TAPP	0.56	kg/ha

Application Efficiency:	APPEFF	0.95	fraction

Spray Drift	DRFT	0.16	fraction of application rate applied to pond

Application Date	Date	15-03	dd/mm or dd/mmm or dd-mm or dd-mmm

Interval 1	interval	14	days	Set to 0 or delete line for single app.

Interval 2	interval	14	days	Set to 0 or delete line for single app.

Interval 3	interval	14	days	Set to 0 or delete line for single app.

Interval 4	interval	14	days	Set to 0 or delete line for single app.

Interval 5	interval	14	days	Set to 0 or delete line for single app.

Record 17:	FILTRA	

	IPSCND	1

	UPTKF	

Record 18:	PLVKRT	

	PLDKRT	

	FEXTRC	0.5

Flag for Index Res. Run	IR	IR

Flag for runoff calc.	RUNOFF	total	none, monthly or total(average of
entire run)

stored as PYMINuA.out

Chemical: pyraclostrobin

PRZM environment: MInursery_NirrigC.txt	modified Tueday, 17 April 2007
at 08:27:58

EXAMS environment: ir298.exv	modified Thuday, 29 August 2002 at 15:34:12

Metfile: w14840.dvf	modified Wedday, 3 July 2002 at 09:05:38

Water segment concentrations (ppb)

Year	Peak	96 hr	21 Day	60 Day	90 Day	Yearly

1961	7.32	5.97	3.869	2.716	2.503	0.8316

1962	8.759	7.132	3.653	2.531	2.374	0.798

1963	4.651	3.715	2.538	2.245	2.032	0.7471

1964	4.89	3.944	2.717	2.214	2.013	0.6637

1965	18.53	15.18	8.281	5.128	4.124	1.399

1966	4.435	3.56	2.644	2.245	1.975	0.7272

1967	4.403	3.543	2.457	2.235	2.148	0.7706

1968	4.708	3.774	2.992	2.45	2.154	0.693

1969	5.428	4.461	2.959	2.328	2.032	0.8221

1970	6.127	5.309	3.118	2.492	2.373	0.8591

1971	4.749	3.803	2.562	2.279	1.999	0.6781

1972	13.23	10.76	5.769	3.842	3.314	1.194

1973	6.626	5.45	4.114	3.241	2.78	0.904

1974	4.925	3.979	3.028	2.341	2.106	0.7286

1975	19.47	15.92	9.874	5.188	4.246	1.374

1976	4.054	3.247	2.276	2.087	1.874	0.6787

1977	4.379	3.509	2.597	2.3	2.037	0.714

1978	7.184	5.874	4.18	3.295	2.942	1.103

1979	4.495	3.621	2.631	2.318	2.063	0.7005

1980	11.9	9.689	6.057	3.771	3.204	1.081

1981	8.269	6.758	3.75	2.715	2.595	1.058

1982	5.381	4.345	2.934	2.476	2.319	0.9237

1983	10.42	8.567	4.772	3.174	2.835	1.055

1984	4.595	3.688	2.515	2.24	2.041	0.7052

1985	12.68	10.29	5.887	4.377	3.528	1.246

1986	36.61	29.92	16.53	8.683	6.509	2.037

1987	20.17	16.37	9.785	5.135	4.098	1.266

1988	9.154	7.426	3.823	2.784	2.527	1.002

1989	10.35	8.411	5.419	3.44	2.921	0.8799

1990	4.171	3.379	2.418	2.206	2.035	0.9186

Sorted results

Prob.	Peak	96 hr	21 Day	60 Day	90 Day	Yearly

0.032258064516129	36.61	29.92	16.53	8.683	6.509	2.037

0.0645161290322581	20.17	16.37	9.874	5.188	4.246	1.399

0.0967741935483871	19.47	15.92	9.785	5.135	4.124	1.374

0.129032258064516	18.53	15.18	8.281	5.128	4.098	1.266

0.161290322580645	13.23	10.76	6.057	4.377	3.528	1.246

0.193548387096774	12.68	10.29	5.887	3.842	3.314	1.194

0.225806451612903	11.9	9.689	5.769	3.771	3.204	1.103

0.258064516129032	10.42	8.567	5.419	3.44	2.942	1.081

0.290322580645161	10.35	8.411	4.772	3.295	2.921	1.058

0.32258064516129	9.154	7.426	4.18	3.241	2.835	1.055

0.354838709677419	8.759	7.132	4.114	3.174	2.78	1.002

0.387096774193548	8.269	6.758	3.869	2.784	2.595	0.9237

0.419354838709677	7.32	5.97	3.823	2.716	2.527	0.9186

0.451612903225806	7.184	5.874	3.75	2.715	2.503	0.904

0.483870967741936	6.626	5.45	3.653	2.531	2.374	0.8799

0.516129032258065	6.127	5.309	3.118	2.492	2.373	0.8591

0.548387096774194	5.428	4.461	3.028	2.476	2.319	0.8316

0.580645161290323	5.381	4.345	2.992	2.45	2.154	0.8221

0.612903225806452	4.925	3.979	2.959	2.341	2.148	0.798

0.645161290322581	4.89	3.944	2.934	2.328	2.106	0.7706

0.67741935483871	4.749	3.803	2.717	2.318	2.063	0.7471

0.709677419354839	4.708	3.774	2.644	2.3	2.041	0.7286

0.741935483870968	4.651	3.715	2.631	2.279	2.037	0.7272

0.774193548387097	4.595	3.688	2.597	2.245	2.035	0.714

0.806451612903226	4.495	3.621	2.562	2.245	2.032	0.7052

0.838709677419355	4.435	3.56	2.538	2.24	2.032	0.7005

0.870967741935484	4.403	3.543	2.515	2.235	2.013	0.693

0.903225806451613	4.379	3.509	2.457	2.214	1.999	0.6787

0.935483870967742	4.171	3.379	2.418	2.206	1.975	0.6781

0.967741935483871	4.054	3.247	2.276	2.087	1.874	0.6637

0.1	19.376	15.846	9.6346	5.1343	4.1214	1.3632

					Average of yearly averages:	0.951956666666667

Inputs generated by pe4.pl - 8-August-2003

Data used for this run:

Output File: PYMINuA

Metfile:	w14840.dvf

PRZM scenario:	MInursery_NirrigC.txt

EXAMS environment file:	ir298.exv

Chemical Name:	pyraclostrobin

Description	Variable Name	Value	Units	Comments

Molecular weight	mwt	388	g/mol

Henry's Law Const.	henry	4.12e-9	atm-m^3/mol

Vapor Pressure	vapr	1.95e-08	torr

Solubility	sol	24.1	mg/L

Kd	Kd		mg/L

Koc	Koc	9304	mg/L

Photolysis half-life	kdp	0.08	days	Half-life

Aerobic Aquatic Metabolism	kbacw	496.28	days	Halfife

Anaerobic Aquatic Metabolism	kbacs	6.6	days	Halfife

Aerobic Soil Metabolism	asm	248.14	days	Halfife

Hydrolysis:	pH 7	0	days	Half-life

Method:	CAM	2	integer	See PRZM manual

Incorporation Depth:	DEPI	0	cm

Application Rate:	TAPP	0.56	kg/ha

Application Efficiency:	APPEFF	0.95	fraction

Spray Drift	DRFT	0.16	fraction of application rate applied to pond

Application Date	Date	15-06	dd/mm or dd/mmm or dd-mm or dd-mmm

Interval 1	interval	14	days	Set to 0 or delete line for single app.

Interval 2	interval	14	days	Set to 0 or delete line for single app.

Interval 3	interval	14	days	Set to 0 or delete line for single app.

Interval 4	interval	14	days	Set to 0 or delete line for single app.

Interval 5	interval	14	days	Set to 0 or delete line for single app.

Record 17:	FILTRA	

	IPSCND	1

	UPTKF	

Record 18:	PLVKRT	

	PLDKRT	

	FEXTRC	0.5

Flag for Index Res. Run	IR	IR

Flag for runoff calc.	RUNOFF	total	none, monthly or total(average of
entire run)

stored as PYNJNuA.out

Chemical: pyraclostrobin

PRZM environment: NJnursery_NirrigC.txt	modified Tueday, 17 April 2007
at 08:27:36

EXAMS environment: ir298.exv	modified Thuday, 29 August 2002 at 15:34:12

Metfile: w93730.dvf	modified Wedday, 3 July 2002 at 09:05:58

Water segment concentrations (ppb)

Year	Peak	96 hr	21 Day	60 Day	90 Day	Yearly

1961	5.163	4.116	2.714	2.334	2.077	0.8835

1962	11.95	9.594	4.68	3.268	2.897	1.577

1963	9.007	7.232	5.383	3.484	2.895	1.347

1964	9.432	7.814	4.173	2.797	2.756	1.317

1965	10.97	8.841	4.447	3.1	2.668	0.8337

1966	39.83	31.86	15.37	8.154	6.048	2.55

1967	35.81	30.88	15.83	7.487	5.771	2.148

1968	15.37	12.42	7.104	4.233	3.543	1.398

1969	48.57	40.12	23.36	10.89	7.952	2.473

1970	8.618	6.963	5.229	3.674	3.052	1.28

1971	20.89	16.78	11.5	7.748	5.924	2.348

1972	10.45	8.494	5.724	3.753	3.166	1.698

1973	12.88	10.31	4.966	2.773	2.476	1.339

1974	12.45	10.05	5.175	2.983	2.975	1.284

1975	11.02	8.891	5.104	4.34	4.08	1.605

1976	14.77	11.78	7.751	3.689	3.235	1.523

1977	8.242	6.648	4.544	3.005	2.766	1.498

1978	25.31	20.37	11.11	6.752	5.457	1.914

1979	33.97	27.42	13.77	6.612	5.363	2.028

1980	4.555	3.935	3.091	2.56	2.355	0.9495

1981	10.23	8.251	5.942	3.939	3.3	1.072

1982	6.649	5.384	3.595	3.033	2.623	0.9983

1983	6.504	5.213	3.395	2.721	2.399	1.212

1984	20.12	16.3	8.744	5.311	4.193	1.419

1985	6.028	4.849	3.171	2.679	2.639	0.9598

1986	8.482	7.272	4.405	2.95	2.655	1.364

1987	23.87	19.11	10.74	5.475	4.46	1.578

1988	6.759	5.448	4.05	2.76	2.562	1.144

1989	19.3	15.53	7.974	5.676	4.849	1.982

1990	13.7	11.08	6.119	3.741	3.224	1.196

Sorted results

Prob.	Peak	96 hr	21 Day	60 Day	90 Day	Yearly

0.032258064516129	48.57	40.12	23.36	10.89	7.952	2.55

0.0645161290322581	39.83	31.86	15.83	8.154	6.048	2.473

0.0967741935483871	35.81	30.88	15.37	7.748	5.924	2.348

0.129032258064516	33.97	27.42	13.77	7.487	5.771	2.148

0.161290322580645	25.31	20.37	11.5	6.752	5.457	2.028

0.193548387096774	23.87	19.11	11.11	6.612	5.363	1.982

0.225806451612903	20.89	16.78	10.74	5.676	4.849	1.914

0.258064516129032	20.12	16.3	8.744	5.475	4.46	1.698

0.290322580645161	19.3	15.53	7.974	5.311	4.193	1.605

0.32258064516129	15.37	12.42	7.751	4.34	4.08	1.578

0.354838709677419	14.77	11.78	7.104	4.233	3.543	1.577

0.387096774193548	13.7	11.08	6.119	3.939	3.3	1.523

0.419354838709677	12.88	10.31	5.942	3.753	3.235	1.498

0.451612903225806	12.45	10.05	5.724	3.741	3.224	1.419

0.483870967741936	11.95	9.594	5.383	3.689	3.166	1.398

0.516129032258065	11.02	8.891	5.229	3.674	3.052	1.364

0.548387096774194	10.97	8.841	5.175	3.484	2.975	1.347

0.580645161290323	10.45	8.494	5.104	3.268	2.897	1.339

0.612903225806452	10.23	8.251	4.966	3.1	2.895	1.317

0.645161290322581	9.432	7.814	4.68	3.033	2.766	1.284

0.67741935483871	9.007	7.272	4.544	3.005	2.756	1.28

0.709677419354839	8.618	7.232	4.447	2.983	2.668	1.212

0.741935483870968	8.482	6.963	4.405	2.95	2.655	1.196

0.774193548387097	8.242	6.648	4.173	2.797	2.639	1.144

0.806451612903226	6.759	5.448	4.05	2.773	2.623	1.072

0.838709677419355	6.649	5.384	3.595	2.76	2.562	0.9983

0.870967741935484	6.504	5.213	3.395	2.721	2.476	0.9598

0.903225806451613	6.028	4.849	3.171	2.679	2.399	0.9495

0.935483870967742	5.163	4.116	3.091	2.56	2.355	0.8835

0.967741935483871	4.555	3.935	2.714	2.334	2.077	0.8337

0.1	35.626	30.534	15.21	7.7219	5.9087	2.328

					Average of yearly averages:	1.49729333333333

Inputs generated by pe4.pl - 8-August-2003

Data used for this run:

Output File: PYNJNuA

Metfile:	w93730.dvf

PRZM scenario:	NJnursery_NirrigC.txt

EXAMS environment file:	ir298.exv

Chemical Name:	pyraclostrobin

Description	Variable Name	Value	Units	Comments

Molecular weight	mwt	388	g/mol

Henry's Law Const.	henry	4.12e-9	atm-m^3/mol

Vapor Pressure	vapr	1.95e-08	torr

Solubility	sol	24.1	mg/L

Kd	Kd		mg/L

Koc	Koc	9304	mg/L

Photolysis half-life	kdp	0.08	days	Half-life

Aerobic Aquatic Metabolism	kbacw	496.28	days	Halfife

Anaerobic Aquatic Metabolism	kbacs	6.6	days	Halfife

Aerobic Soil Metabolism	asm	248.14	days	Halfife

Hydrolysis:	pH 7	0	days	Half-life

Method:	CAM	2	integer	See PRZM manual

Incorporation Depth:	DEPI	0	cm

Application Rate:	TAPP	0.56	kg/ha

Application Efficiency:	APPEFF	0.95	fraction

Spray Drift	DRFT	0.16	fraction of application rate applied to pond

Application Date	Date	01-05	dd/mm or dd/mmm or dd-mm or dd-mmm

Interval 1	interval	14	days	Set to 0 or delete line for single app.

Interval 2	interval	14	days	Set to 0 or delete line for single app.

Interval 3	interval	14	days	Set to 0 or delete line for single app.

Interval 4	interval	14	days	Set to 0 or delete line for single app.

Interval 5	interval	14	days	Set to 0 or delete line for single app.

Record 17:	FILTRA	

	IPSCND	1

	UPTKF	

Record 18:	PLVKRT	

	PLDKRT	

	FEXTRC	0.5

Flag for Index Res. Run	IR	IR

Flag for runoff calc.	RUNOFF	total	none, monthly or total(average of
entire run)

stored as PYORNuA.out

Chemical: pyraclostrobin

PRZM environment: ORnursery_NirrigC.txt	modified Tueday, 17 April 2007
at 08:27:14

EXAMS environment: ir298.exv	modified Thuday, 29 August 2002 at 15:34:12

Metfile: w24229.dvf	modified Wedday, 3 July 2002 at 09:06:10

Water segment concentrations (ppb)

Year	Peak	96 hr	21 Day	60 Day	90 Day	Yearly

1961	5.522	4.581	3.276	2.982	2.575	0.7433

1962	5.949	4.899	3.149	2.568	2.341	0.7666

1963	5.091	4.397	3.232	2.891	2.627	0.7942

1964	5.557	4.583	3.134	2.728	2.548	0.7864

1965	5.265	4.358	3.107	2.753	2.492	0.78

1966	5.29	4.385	3.128	2.719	2.458	0.7918

1967	4.818	4.078	3.154	2.73	2.471	0.711

1968	5.713	4.674	3.729	3.035	2.646	0.8848

1969	4.9	4.057	3.087	2.745	2.504	0.8408

1970	5.736	4.742	3.768	3.394	3.008	0.8575

1971	5.051	4.181	3.027	2.674	2.532	0.7981

1972	5.263	4.354	3.324	2.866	2.663	0.7851

1973	4.502	3.728	2.758	2.492	2.271	0.782

1974	6.156	5.416	3.737	3.156	2.905	0.8691

1975	5.168	4.268	3.118	2.867	2.607	0.7587

1976	5.777	4.809	3.372	2.713	2.434	0.6745

1977	4.497	3.727	2.755	2.412	2.155	0.7383

1978	4.665	3.862	2.842	2.595	2.315	0.6871

1979	4.881	4.061	3.086	2.797	2.459	0.7367

1980	4.998	4.361	3.058	2.743	2.594	0.8778

1981	4.949	4.086	3.155	2.724	2.418	0.7936

1982	6.025	4.987	3.796	3.108	2.769	0.8909

1983	6.475	5.366	3.877	3.251	2.88	0.8886

1984	4.68	3.869	2.809	2.506	2.327	0.7894

1985	4.663	3.843	2.762	2.43	2.181	0.6749

1986	5.032	4.154	3.031	2.65	2.341	0.7016

1987	7.068	5.809	4.034	3.43	2.886	0.8749

1988	4.631	3.815	2.767	2.478	2.351	0.7523

1989	5.603	4.653	3.364	2.827	2.492	0.721

1990	4.889	4.015	2.868	2.601	2.336	0.6741

Sorted results

Prob.	Peak	96 hr	21 Day	60 Day	90 Day	Yearly

0.032258064516129	7.068	5.809	4.034	3.43	3.008	0.8909

0.0645161290322581	6.475	5.416	3.877	3.394	2.905	0.8886

0.0967741935483871	6.156	5.366	3.796	3.251	2.886	0.8848

0.129032258064516	6.025	4.987	3.768	3.156	2.88	0.8778

0.161290322580645	5.949	4.899	3.737	3.108	2.769	0.8749

0.193548387096774	5.777	4.809	3.729	3.035	2.663	0.8691

0.225806451612903	5.736	4.742	3.372	2.982	2.646	0.8575

0.258064516129032	5.713	4.674	3.364	2.891	2.627	0.8408

0.290322580645161	5.603	4.653	3.324	2.867	2.607	0.7981

0.32258064516129	5.557	4.583	3.276	2.866	2.594	0.7942

0.354838709677419	5.522	4.581	3.232	2.827	2.575	0.7936

0.387096774193548	5.29	4.397	3.155	2.797	2.548	0.7918

0.419354838709677	5.265	4.385	3.154	2.753	2.532	0.7894

0.451612903225806	5.263	4.361	3.149	2.745	2.504	0.7864

0.483870967741936	5.168	4.358	3.134	2.743	2.492	0.7851

0.516129032258065	5.091	4.354	3.128	2.73	2.492	0.782

0.548387096774194	5.051	4.268	3.118	2.728	2.471	0.78

0.580645161290323	5.032	4.181	3.107	2.724	2.459	0.7666

0.612903225806452	4.998	4.154	3.087	2.719	2.458	0.7587

0.645161290322581	4.949	4.086	3.086	2.713	2.434	0.7523

0.67741935483871	4.9	4.078	3.058	2.674	2.418	0.7433

0.709677419354839	4.889	4.061	3.031	2.65	2.351	0.7383

0.741935483870968	4.881	4.057	3.027	2.601	2.341	0.7367

0.774193548387097	4.818	4.015	2.868	2.595	2.341	0.721

0.806451612903226	4.68	3.869	2.842	2.568	2.336	0.711

0.838709677419355	4.665	3.862	2.809	2.506	2.327	0.7016

0.870967741935484	4.663	3.843	2.767	2.492	2.315	0.6871

0.903225806451613	4.631	3.815	2.762	2.478	2.271	0.6749

0.935483870967742	4.502	3.728	2.758	2.43	2.181	0.6745

0.967741935483871	4.497	3.727	2.755	2.412	2.155	0.6741

0.1	6.1429	5.3281	3.7932	3.2415	2.8854	0.8841

					Average of yearly averages:	0.780836666666667

Inputs generated by pe4.pl - 8-August-2003

Data used for this run:

Output File: PYORNuA

Metfile:	w24229.dvf

PRZM scenario:	ORnursery_NirrigC.txt

EXAMS environment file:	ir298.exv

Chemical Name:	pyraclostrobin

Description	Variable Name	Value	Units	Comments

Molecular weight	mwt	388	g/mol

Henry's Law Const.	henry	4.12e-09	atm-m^3/mol

Vapor Pressure	vapr	1.95e-08	torr

Solubility	sol	24.1	mg/L

Kd	Kd		mg/L

Koc	Koc	9304	mg/L

Photolysis half-life	kdp	0.08	days	Half-life

Aerobic Aquatic Metabolism	kbacw	496.28	days	Halfife

Anaerobic Aquatic Metabolism	kbacs	6.6	days	Halfife

Aerobic Soil Metabolism	asm	248.14	days	Halfife

Hydrolysis:	pH 7	0	days	Half-life

Method:	CAM	2	integer	See PRZM manual

Incorporation Depth:	DEPI	0	cm

Application Rate:	TAPP	0.56	kg/ha

Application Efficiency:	APPEFF	0.95	fraction

Spray Drift	DRFT	0.16	fraction of application rate applied to pond

Application Date	Date	15-01	dd/mm or dd/mmm or dd-mm or dd-mmm

Interval 1	interval	14	days	Set to 0 or delete line for single app.

Interval 2	interval	14	days	Set to 0 or delete line for single app.

Interval 3	interval	14	days	Set to 0 or delete line for single app.

Interval 4	interval	14	days	Set to 0 or delete line for single app.

Interval 5	interval	14	days	Set to 0 or delete line for single app.

Record 17:	FILTRA	

	IPSCND	1

	UPTKF	

Record 18:	PLVKRT	

	PLDKRT	

	FEXTRC	0.5

Flag for Index Res. Run	IR	IR

Flag for runoff calc.	RUNOFF	total	none, monthly or total(average of
entire run)

stored as PYTNNuA.out

Chemical: pyraclostrobin

PRZM environment: TNnursery_NirrigC.txt	modified Tueday, 17 April 2007
at 08:28:44

EXAMS environment: ir298.exv	modified Thuday, 29 August 2002 at 15:34:12

Metfile: w13882.dvf	modified Wedday, 3 July 2002 at 09:06:20

Water segment concentrations (ppb)

Year	Peak	96 hr	21 Day	60 Day	90 Day	Yearly

1961	14.02	11.31	6.548	3.098	2.73	1.125

1962	8.232	6.595	4.161	3.14	2.739	1.441

1963	10.2	8.312	6.458	4.377	3.494	1.508

1964	15	12.05	6.138	3.918	3.475	1.763

1965	7.913	6.378	3.183	2.599	2.442	1.199

1966	9.488	8.268	5.306	3.142	2.687	1.295

1967	15.83	13.43	8.227	4.847	3.816	1.443

1968	4.22	3.37	2.377	2.115	1.939	0.7924

1969	13.94	11.16	7.147	4.152	3.475	1.408

1970	9.091	7.324	5.032	3.321	2.831	1.343

1971	11.83	10.24	6.837	3.943	3.247	1.443

1972	16.34	14.19	10.71	6.094	4.956	1.831

1973	10.01	8.164	5.218	3.489	3.156	1.784

1974	13.03	10.87	7.962	4.489	3.625	1.385

1975	17.41	14.04	8.454	5.846	5.292	2.171

1976	15.16	12.13	6.499	4.809	3.82	1.299

1977	35.41	28.48	17.55	8.763	6.851	2.568

1978	5.755	5.086	3.248	2.416	2.214	0.9016

1979	26.56	22.78	12.97	7.09	5.966	2.459

1980	9.271	7.459	4.207	2.13	1.846	1.066

1981	6.442	5.537	4.036	3.017	2.82	1.131

1982	10.28	8.259	5.767	3.783	3.168	1.559

1983	8.869	7.187	5.523	2.793	1.99	1.22

1984	7.294	5.854	4.474	3.235	2.671	1.205

1985	6.91	5.562	3.788	2.842	2.524	1.083

1986	15.81	12.69	6.325	3.555	3.161	1.537

1987	7.287	5.823	4.502	3.107	2.635	1.096

1988	12.29	9.864	6.639	4.34	3.736	1.47

1989	13	11.01	7.583	5.793	4.627	1.995

1990	7.692	6.195	3.534	2.911	2.507	1.423

Sorted results

Prob.	Peak	96 hr	21 Day	60 Day	90 Day	Yearly

0.032258064516129	35.41	28.48	17.55	8.763	6.851	2.568

0.0645161290322581	26.56	22.78	12.97	7.09	5.966	2.459

0.0967741935483871	17.41	14.19	10.71	6.094	5.292	2.171

0.129032258064516	16.34	14.04	8.454	5.846	4.956	1.995

0.161290322580645	15.83	13.43	8.227	5.793	4.627	1.831

0.193548387096774	15.81	12.69	7.962	4.847	3.82	1.784

0.225806451612903	15.16	12.13	7.583	4.809	3.816	1.763

0.258064516129032	15	12.05	7.147	4.489	3.736	1.559

0.290322580645161	14.02	11.31	6.837	4.377	3.625	1.537

0.32258064516129	13.94	11.16	6.639	4.34	3.494	1.508

0.354838709677419	13.03	11.01	6.548	4.152	3.475	1.47

0.387096774193548	13	10.87	6.499	3.943	3.475	1.443

0.419354838709677	12.29	10.24	6.458	3.918	3.247	1.443

0.451612903225806	11.83	9.864	6.325	3.783	3.168	1.441

0.483870967741936	10.28	8.312	6.138	3.555	3.161	1.423

0.516129032258065	10.2	8.268	5.767	3.489	3.156	1.408

0.548387096774194	10.01	8.259	5.523	3.321	2.831	1.385

0.580645161290323	9.488	8.164	5.306	3.235	2.82	1.343

0.612903225806452	9.271	7.459	5.218	3.142	2.739	1.299

0.645161290322581	9.091	7.324	5.032	3.14	2.73	1.295

0.67741935483871	8.869	7.187	4.502	3.107	2.687	1.22

0.709677419354839	8.232	6.595	4.474	3.098	2.671	1.205

0.741935483870968	7.913	6.378	4.207	3.017	2.635	1.199

0.774193548387097	7.692	6.195	4.161	2.911	2.524	1.131

0.806451612903226	7.294	5.854	4.036	2.842	2.507	1.125

0.838709677419355	7.287	5.823	3.788	2.793	2.442	1.096

0.870967741935484	6.91	5.562	3.534	2.599	2.214	1.083

0.903225806451613	6.442	5.537	3.248	2.416	1.99	1.066

0.935483870967742	5.755	5.086	3.183	2.13	1.939	0.9016

0.967741935483871	4.22	3.37	2.377	2.115	1.846	0.7924

0.1	17.303	14.175	10.4844	6.0692	5.2584	2.1534

					Average of yearly averages:	1.4648

Inputs generated by pe4.pl - 8-August-2003

Data used for this run:

Output File: PYTNNuA

Metfile:	w13882.dvf

PRZM scenario:	TNnursery_NirrigC.txt

EXAMS environment file:	ir298.exv

Chemical Name:	pyraclostrobin

Description	Variable Name	Value	Units	Comments

Molecular weight	mwt	388	g/mol

Henry's Law Const.	henry	4.12e-9	atm-m^3/mol

Vapor Pressure	vapr	1.95e-08	torr

Solubility	sol	24.1	mg/L

Kd	Kd		mg/L

Koc	Koc	9304	mg/L

Photolysis half-life	kdp	0.08	days	Half-life

Aerobic Aquatic Metabolism	kbacw	496.28	days	Halfife

Anaerobic Aquatic Metabolism	kbacs	6.6	days	Halfife

Aerobic Soil Metabolism	asm	248.14	days	Halfife

Hydrolysis:	pH 7	0	days	Half-life

Method:	CAM	2	integer	See PRZM manual

Incorporation Depth:	DEPI	0	cm

Application Rate:	TAPP	0.56	kg/ha

Application Efficiency:	APPEFF	0.95	fraction

Spray Drift	DRFT	0.16	fraction of application rate applied to pond

Application Date	Date	01-06	dd/mm or dd/mmm or dd-mm or dd-mmm

Interval 1	interval	14	days	Set to 0 or delete line for single app.

Interval 2	interval	14	days	Set to 0 or delete line for single app.

Interval 3	interval	14	days	Set to 0 or delete line for single app.

Interval 4	interval	14	days	Set to 0 or delete line for single app.

Interval 5	interval	14	days	Set to 0 or delete line for single app.

Record
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                          VERSION 2.3

            ENVIRONMENTAL FATE AND EFFECTS DIVISION

                 OFFICE OF PESTICIDE PROGRAMS

             U.S. ENVIRONMENTAL PROTECTION AGENCY

                        SCREENING MODEL

                FOR AQUATIC PESTICIDE EXPOSURE

 

 SciGrow version 2.3

 chemical:pyraclostrobin

 time is  8/31/2007  15:16: 6

 -----------------------------------------------------------------------
-

  Application      Number of       Total Use    Koc      Soil Aerobic

  rate (lb/acre)  applications   (lb/acre/yr)  (ml/g)   metabolism
(days)

 -----------------------------------------------------------------------
-

      0.500           6.0                  3.000      7.89E+03     
105.0

 -----------------------------------------------------------------------
-

 groundwater screening cond (ppb) =   2.30E-02 

 ***********************************************************************
*

 PAGE  1 

Runoff

Erosion

Direct Contact,

Systemic Uptake

Leaching

Terrestrial 

Environments

Spray Drift

Mammals

Survival

Growth

Reproduction

Pyraclostrobin Applications to Turf and Ornamentals 

 (Aerial Application)