Document ID: EPA-HQ-OPP-2008-0769-0009
Agency: epa
Document Type: Supporting & Related Material
Title: 
Posted Date: 2009-12-09T05:00Z

SEQ CHAPTER \h \r 1 U. S. ENVIRONMENTAL PROTECTION AGENCY

Washington, D.C. 20460	

									            OFFICE OF

PREVENTION, PESTICIDES

AND TOXIC SUBSTANCES

								

Date: 		March 10, 2009 

PC Code: 	124002

DP Barcode: 	D357061 

MEMORANDUM 					

Subject:	Novaluron and Novaluron Degradates (Chlorophenyl urea and
Chloroaniline) Drinking Water Assessment in Support of New Use
Registration Action for Stone Fruit, Bushberries, Brassica Leafy Greens,
and Turnip Greens.

To:		George Kramer, RAB 1

		Dana Vogel, Branch Chief, RAB1

		Health Effects Division (7509P)

		Dan Rosenblatt, RM 05

		Risk Integration, Minor Use and Emergency Response Branch

Registration Division (7505P)

From:	Iwona L. Maher, Chemist, ERBI

	Faruque, Khan, Ph.D., Senior Scientist, ERBI

		Nancy Andrews, Ph.D., Branch Chief, ERBI

Environmental Fate and Effects Division (7507P)

The registrant is proposing to add four new uses:  stone fruit (group
SG-12), bushberries (subgroup SG-13-07B), brassica, leafy greens
(subgroup SG-5B), and turnip greens to the RimOn 0.83EC product label. 
Based on a review and analysis of the application information provided
on the product label for this end-use product, the annual mean estimated
drinking water concentrations (EDWC) from these new proposed uses are
expected to be lower than those from novaluron current use on apples,
with the exception of the peak EDWC being slightly higher for use on
peach, and chlorophenyl urea, novaluron degradate of concern,
concentration being slightly higher for uses on peach than apples. The
acute estimated drinking water concentration in surface water is 4.72
μg/l (peach, aerial application) exceeding the solubility of novaluron
(3 μg/L), which is expected to be an upper bound environmental
concentration.  The chronic non-cancer EDWC is not expected to exceed
0.76 μg/L, and the cancer/chronic drinking water concentration is not
expected to exceed 0.62 μg/L for use on apple via aerial application. 
An estimated peak drinking water concentration of chlorophenyl urea from
surface water sources is 4.74 μg/L, and an estimated annual average
concentration is 0.89 μg/L based on novaluron’s maximum application
rate of 0.32 lb ai/acre applied 3 times a season every 7 days (0.96 lbs
ai/year, stone fruit).  The estimated peak drinking water concentration
of chloroaniline is 11.4 μg/L exceeding the estimated solubility of
chloroaniline (10.6 μg/L), which is expected to be the upper bound
environmental concentration, and the estimated annual average
concentration is 2.6 μg/L from novaluron application rate of 0.32 lb
ai/acre applied 3 times a season every 10 days (0.96 lbs ai/year, pome
fruit).  Since it appeared that neither of the proposed (dated:  August
2, 2008) or registered (dated:  January 29, 2009) labels prohibit aerial
application to stone, or pome fruits, therefore, an aerial application
was added to modeling for both pome fruit and stone fruit uses. In
addition, the EDWCs were updated using currently approved versions of
models; i.e. the PE5 shell version (released in November 15, 2006), PRZM
v3.12.2 (May 12, 2005), EXAMS version 2.98.04.06 (April 25, 2005), and
FIRST version 1.1.1 (March 26, 2008;
http://www.epa.gov/oppefed1/models/water/first_release_notes.htm). The
SCI-GROW modeling did not require updating. 

According to the current label no more than 0.96 lbs a.i. (RimOn 0.83EC
as of January 29, 2009) may be applied to apples, pome fruits, per acre
per year, with the maximum rate per application of 0.32 lbs a.i., a
minimum intervals of 10 to 14 days between applications, and up to 3
applications per year.  The proposed maximum application rates are no
more than 0.96 lbs a.i. (RimOn 0.83EC as of August 2, 2008) applied per
acre per year (for stone fruits) with a minimum intervals of 7 to 14
days between applications, and up to 3 applications per year. Table 1
lists in details the proposed application rates for stone fruit (group
SG-12), bushberries (subgroup SG-13-07B), brassica leafy greens
(subgroup SG-5B), and turnip greens, and the currently registered
maximum application rate to pome fruits (apples). After careful review
of the labels, it was noted that it is unclear whether aerial
applications are allowed to orchard.

Table 1.  Novaluron application rates for the proposed and registered1
uses.

Crop

(Subgroup)	Maximum Application Rate2

(Lb ai/A)	Maximum Number of Applications Per Year	Minimum Interval
Between Applications	Method of Application2

	Single	Annual

	Pome Fruit 	0.324	0.972	3	10	G, A

Stone Fruit (12)	0.324	0.972	3	73	G, A

Brassica - leafy greens (5B)	

0.078	

0.234	

3	

7	

G, A

Turnip greens	0.078	0.234	3	7	G, A

Bushberries

(13-07B)	

0.195	

0.585	

3	

10	

G, A

1 – It shows only the highest maximum registered application rate for
novaluron; i.e. pome fruits per label dated January 29, 2009.

2 – It shows only the maximum application rate and minimum
reapplication intervals for novaluron proposed uses, only bold text
provides information that clearly is relied in the proposed label.

 3 – According to the proposed label the consequent applications to
stone fruit should be made in intervals from 7 to 14 day, the lowest
interval was selected.

4.59 μg/l exceeding the solubility of novaluron (3 μg/L), which is
expected to be the upper bound environmental concentration.  The chronic
non-cancer EDWC (1- in-10 year annual average concentration) is expected
not to exceed 0.76 μg/l, and the cancer/chronic drinking water
concentration (30-year annual average) is expected not to exceed 0.62
μg/l for use on apples via aerial application.  Table 2 lists the
estimated drinking water concentrations from surface water sources for
PA apple and GA peach modeled scenarios.  As no more data were submitted
for this action, the input parameters for the modeling were the same as
in the previous drinking water assessment (Maher et. al., Feb 11, 2004;
D285477).  The PRZM/EXAMS input parameters for novaluron are listed in
Table 1, Appendix A.  The PRZM/EXAMS output files are provided in
Appendix B.

Table 2. Novaluron estimated drinking water concentrations for surface
water sources.

Scenario	

Application Rate in

(lb ai/A)/

ApplicationType	

Estimated Drinking Water Concentrations from Surface Water Sources (ppb)

1 in 10 year annual      peak	

1 in 10 year annual mean	

36 year annual 

mean

PA Apples

(PCA = 0.87)

	

0.972           aerial 	

4.59*	

0.76	

0.62

	

0.972           airblast	

3.23	

0.50	

0.36

GA Peach

(PCA = 0.87)	

0.972           aerial	

4.72*	

0.51	

0.43

	0.972           airblast 	

2.42	

0.29	

0.20

*These values exceed the measured water solubility of novaluron; i.e. 3
µg/L (3 ppb). 

 μg/L, and the estimated annual average concentration is 0.89 μg/L
based on novaluron’s maximum application rate of 0.32 lb ai/acre
applied 3 times a season every 7 days (0.96 lbs ai/year, peaches).  The
estimated peak drinking water concentration of chloroaniline is 11.4
μg/L exceeding the solubility of chloroaniline (10.6 μg/L), which is
expected to be the upper bound environmental concentration, and the
estimated annual average concentration is 2.6 μg/L from novaluron
application rate of 0.32 lb ai/acre applied 3 times a season every 10
days (0.96 lbs ai/year, apples). Table 2 lists the estimated drinking
water concentrations for both degradates from novaluron proposed maximum
uses on apples and peaches. The FIRST input parameters for chlorophenyl
urea and chloroaniline are listed in Table 2 and 3 of Appendix A.  The
FIRST output files are provided in Appendix C.

Table 3. Degradates’ estimated drinking water concentrations for
surface water sources based on Tier I modeling and the highest maximum
application rate.

Novaluron Metabolite	

Crop	

Estimated Degradate Application Rate	

Estimated Drinking Water Concentrations from Surface Water Sources (ppb)

	

Peak	

Annual Average

chlorophenyl urea

	

apples:	

3 x 0.062 lb a.i./acre	

4.55	

0.86

	

peach:	

3 x 0.062 lb a.i./acre	

4.74	

0.89

chloroaniline	

apples:	

3 x 0.204 lb a.i./acre	

11.4*	

2.60

	

peach:	

3 x 0.204 lb a.i./acre

*This value exceeds the estimated water solubility of chloroaniline;
i.e. 10.6 µg/L (10.6 ppb). 

For the annual application rate of 0.96 lb a.i./acre (i.e., three
applications of 0.32 lb a.i./acre), SCI-GROW novaluron predicted ground
water concentration is 5.6 x 10-3 μg/L in drinking water from shallow
ground water sources. The predicted ground water concentration is 4.5 x
10-3 μg/L for chlorophenyl urea and 9.0 x 10-3 μg/L for chloroaniline
from novaluron’s maximum application rate (0.96 lb a.i./acre).  These
concentrations may be considered as both the peak and annual average
upper bound exposures.  The SCI-GROW input parameters and output files
are provided in the previous drinking water assessment (Maher et. al.,
February 11, 2004, D285477).

Novaluron has the potential to reach surface water through runoff weeks
to months following its application, and through spray drift during
application.  Due to its high sorptive properties (Koc = 6,680-11,813),
the chemical has low potential for leaching into ground water. Based on
laboratory and field studies, novaluron appears to be slightly mobile to
hardly mobile according to the FAO classification, and ranges from
moderately persistent to persistent in the field.  It biodegrades in
soil under aerobic conditions with half-lives of 7 to14.5 days, strongly
adsorbs to soil and sediment (simple Kd values ranged from 95 to 247),
and is stable to hydrolysis and photodegradation.  In the field,
novaluron appears to degrade with half-lives ranging from 20 to 178
days.  The laboratory and field data suggest that novaluron may be more
persistent in colder climates. At 50 oC and pH 9, novaluron hydrolyzes
very rapidly with a half-life of 1.2 days. In aerobic soils, it degrades
slower at 10 oC (i.e., half-life 31.9 days) than at 20 oC (i.e.,
half-lives from 7 to 14.5 days).  

Prior to 2004 the HED MARC concluded that parent, chlorophenyl urea (1 
[3 chloro 4 (1,1,2 trifluoro  2 trifluoromethoxyethoxy) phenyl] urea)
(275-352I), and chloroaniline
(3-chloro-4-(1,1,2-trifluoro-2-trifluoromethoxyethoxy)aniline)
(275-309I) are residues of potential concern to be included in the
drinking water assessment.  Chlorophenyl urea is a major degradate of
novaluron formed in aerobic soil metabolism and aquatic anaerobic
metabolism.  This degradate appears to be mobile (Kds = 16.7 - 61.5),
moderately persistent in soil (decline curve estimated t1/2 = 46.5 and
45.6 days; GLN 162-1), and moderately persistent in aquatic environment
(decline curve estimated half-life = 26.6 days; GLN 162-4).  It has
potential to reach surface water through runoff, and has low potential
to reach ground water resources.  The chloroaniline degradate is formed
in aerobic soil metabolism.  Although formation of chloroaniline in soil
didn’t exceed 10% of the applied dose (i.e., the maximum concentration
was 8.5% at 120 days posttreatemnt), in the environment, the major
degradate chlorophenyl urea is expected to further degrade to form
chloroaniline.

The fate and transport data submitted for novaluron were complete.  
Fate data submitted for the novaluron degradate chlorophenyl urea
(275-352I) was limited to the adsorption/desorption study. No data was
submitted for chloroaniline degradate. Recently, the registrant
submitted a runoff study "An Investigation of Buffer Efficacy in
Mitigating the potential Transport of Novaluron in Runoff Using
Simulated Rainfall on Small Plots" (MRID 47641401).  The study could
provide insight into the effectiveness of well maintained buffer strips,
but it is currently under review, and therefore, was not discussed in
this memorandum. For further information on the drinking water
assessment from novaluron use on apples refer to “Novaluron Estimated
Drinking Water Concentration for Use in the Human Health Drinking Water
Risk Assessment.” memo (Maher et. al., February 11, 2004, D285477).

 

APPENDIX A

Table 1. PRZM/EXAMS Input Parameters for Novaluron 

Parameters	Input Value and Unit	Source of Info/Reference

Maximum Application Rates 1

	

0.363 kg ai/ha

	Product Label:

RimOn 0.83EC, EPA Reg. No. 66222-35

Maximum Number of Applications	3

	Product Labels as above

Minimum Interval Between Applications	7 -10 days 	Product Labels as
above

Soil Partition Coefficient (Kd)2	165 ml/g	MRID 44961012

Molecular Weight	492.7	Registrant data

Solubility (at 25 oC) x 100	0.3 ppm	Registrant data (MRID 45638203)

Vapor Pressure	1.2 x 10-7 mm Hg	Registrant data

Henry’s Constant at 25 oC	1.974 x10-13 atm•m3/mol	Registrant data

Aerobic Soil Metabolism T1/23	15.6 days	MRIDs:  44961009 and 44961010

Foliar Dissipation Rate (PLDKRT)	0.0198	EFED’s default value of 35
days

Aqueous Photolysis (pH 5) T1/24	187 days	MRID 45638203

Hydrolysis T1/2 (pH7)	stable	MRID 44961008

Aerobic Aquatic Metabolism Half-life5	30.1 days	MRID 45638206

Anaerobic Aquatic Metabolism Half-life5	52.1 days	MRIDs:  45638205 and
45789203

First Application Date (dd-mm)	peach = GA: 21-03

apples = PA: 	Assumed based on crop profiles and probable target insect
infestation

Application Fraction (percent of applied)	Ground - 0. 99

Aerial  – 0.95	Guidance for Selecting Input Parameters in Modeling the
Environmental Fate and Transport of Pesticides; Feb. 28, 2002

Spray Drift Fraction	Airblast – 0.063 

Aerial – 0.16	Guidance for Selecting Input Parameters in Modeling the
Environmental Fate and Transport of Pesticides; Feb. 28, 2002

1 -  One planting  per year was assumed and the annual rate is assumed  
                                                 SEQ CHAPTER \h \r 1 1
One planting  per year was assumed and the annual rate is assumed to be
the seasonal rate  	 

2An average simple adsorption constant (Kd ) out of four simple
adsorption constant (Kd ) values (133, 247, 184, and 95) was used (Koc
model was not valid; MRID 44961012). 

3Since n=4: to account for the inherent variability the upper confidence
bound on the mean of the aerobic soil metabolism half-life was used

4 Individual data points were very variable so the accuracy of the
half-life is uncertain,

5Since n=2 (aerobic T1/2: 19.7 and 9.7 days; anaerobic T1/2: 50.6 and
49.2 days), the upper confidence bound on the mean aquatic metabolism
half-life was used.

Table 2. FIRST Input Parameters for
1-[3-Chloro-4-(1,1,2-trifluoro-2-trifluoromethoxyethoxy)phenyl]urea 

Parameters	

Input Value and Unit	

Source of Info/Reference

Maximum Application Rates 1

	

apples/peaches = 0.061 lb/acre 

	

rateder= ratepar* (MWdeg/MWpar) * (max. % form. rate/100)

Maximum Number of Applications 	

apples  = 3

	

Product Labels:

RimOn 0.83EC, EPA Reg. No. 66222-35

Minimum interval between applications	

apples  = 10 days

peaches = 7 days

	

Product Labels as above

Soil Partition Coefficient (Kd)2 	

16.7	

MRID 45638201 (GLN 163-1)

Aerobic Soil Metabolism T1/23	

47.1 days	

MRID 44961009

Wetted in 	

No	

Product Label

Depth of incorporation (inches)	

0	

Product Label

Method of application	

granular	

assumed; a degradate formed in soil

Solubility in water at 20 oC	

33 ppm	

MRID 45638201

Aerobic aquatic metabolism half-life4	

79.8 days	

MRID 45638206

Aqueous Photolysis T1/2	

stable	

assumed; data not available

1 – Application rate of 275-352I is based on the maximum formation
rate of 26.6 % from parent novaluron found in the aerobic soil
metabolism study (MIRD 44961009) and molecular weigh conversion (MWpar =
492.7; MWdeg = 352.6).

2 - the lowest non-sand Kf (sandy loam) was used.  Out of four Kf values
(35.1; 16.7; 61.5; and 47.6) the lowest non-sand Kf for sandy loam was
used (Kf may not equal Kd). 

3 - 275-352I first order non-linear half-lives were estimated from
formation and decline curves using the maximum concentration as the
initial concentration; since there were two valid half-lives estimated,
i.e. 46.5 and 45.9 days, therefore the upper confidence bound on the
mean metabolism half-life was used as the model input value.

4 - a first order non-linear half-life was calculated from formation and
decline curve using the maximum concentration as the initial
concentration; since there was only one valid half-life (26.6 days; in
Houghton Meadow water-loamy sand sediment) available as a model input
value t1/2 x3 = 79.8 was used.

Table 3. FIRST Input Parameters for
3-chloro-4-(1,1,2-trifluoro-2-trifluoromethoxyethoxy)aniline

Parameters	

Input Value and Unit	

Source of Info/Reference

Maximum Application Rates 1	

apples/peaches = 0.20 lb/acre 	

rateder= ratepar* (MWdeg/MWpar) * (max. % form. rate/100)

Maximum Number of Applications 	

apples  = 3	

Product Labels:

RimOn 0.83EC, EPA Reg. No. 66222-35

Minimum interval between applications	

apples  = 10 days

peaches = 7 days	

Product Labels as above

Soil Partition Coefficient (Koc)	

5899	

Estimated 2 

Aerobic Soil Metabolism T1/2	

stable	

assumed; data not available

Wetted in 	

No	

Product Label

Depth of incorporation (inches)	

0	

Product Label

Method of application	

granular	

assumed; a degradate formed in soil

Solubility in water at 25 oC	

10.6 ppm	

Estimated 2 

Aerobic aquatic metabolism half-life	

stable	

assumed; data not available

Hydrolysis T1/2 (pH7)	

stable	

assumed; data not available

Aqueous Photolysis T1/2	

stable	

assumed; data not available

1

 – Application rate of 275-309I is based on 100% formation from parent
novaluron and molecular weigh conversion (MWpar = 492.7; MWdeg = 310.6).

2 - Estimated using substructure physical/chemical property computer
program (Howard and Meylan, 1995).

APPENDIX B

PRZM/EXAMS Output Files

Novaluron aerial application to GA Peaches

stored as novGApeachIRair.out

Chemical: novaluron

PRZM environment: GAPeachesSTD.txt	modified Tueday, 29 May 2007 at
11:54:56

EXAMS environment: ir298.exv	modified Thuday, 29 August 2002 at 14:34:12

Metfile: w03813.dvf	modified Wedday, 3 July 2002 at 08:04:32

Water segment concentrations (ppb)

Year	Peak	96 hr	21 Day	60 Day	90 Day	Yearly

1961	5.273	4.759	3.783	2.478	1.904	0.5604

1962	4.989	4.513	3.496	2.2	1.654	0.4807

1963	4.543	4.068	3.108	2.015	1.539	0.4525

1964	7.004	6.315	4.63	3.134	2.453	0.7404

1965	4.659	4.183	3.219	2.023	1.525	0.4737

1966	4.613	4.145	3.184	2.024	1.552	0.467

1967	4.552	4.072	3.11	1.95	1.479	0.4481

1968	4.602	4.131	3.17	2.023	1.579	0.4737

1969	4.627	4.154	3.19	2.008	1.515	0.4463

1970	6.143	5.52	4.333	2.667	2.028	0.5941

1971	4.912	4.418	3.452	2.197	1.683	0.4943

1972	4.576	4.107	3.147	1.98	1.497	0.4395

1973	5.089	4.602	3.739	2.542	1.991	0.5958

1974	4.591	4.124	3.337	2.142	1.634	0.4872

1975	4.597	4.133	3.393	2.381	1.831	0.5532

1976	4.56	4.092	3.135	2.056	1.685	0.5245

1977	4.997	4.488	3.52	2.268	1.703	0.4953

1978	4.591	4.117	3.329	2.224	1.694	0.4948

1979	4.69	4.213	3.246	2.138	1.634	0.4837

1980	4.602	4.134	3.174	1.997	1.501	0.4286

1981	5.445	4.873	3.67	2.274	1.756	0.522

1982	5.255	4.76	3.589	2.327	1.771	0.5233

1983	4.601	4.145	3.194	2.028	1.538	0.4503

1984	4.58	4.113	3.155	1.989	1.563	0.4672

1985	4.566	4.099	3.141	1.974	1.481	0.4287

1986	4.568	4.097	3.137	1.963	1.468	0.4169

1987	4.592	4.13	3.173	2	1.5	0.4311

1988	4.582	4.115	3.157	2.021	1.531	0.4459

1989	4.579	4.116	3.174	2.026	1.539	0.4526

1990	4.564	4.104	3.149	1.989	1.495	0.4294

Sorted results

Prob.		Peak	96 hr	21 Day	60 Day	90 Day	Yearly

0.032258064516129	7.004	6.315	4.63	3.134	2.453	0.7404

0.0645161290322581	6.143	5.52	4.333	2.667	2.028	0.5958

0.0967741935483871	5.445	4.873	3.783	2.542	1.991	0.5941

0.129032258064516	5.273	4.76	3.739	2.478	1.904	0.5604

0.161290322580645	5.255	4.759	3.67	2.381	1.831	0.5532

0.193548387096774	5.089	4.602	3.589	2.327	1.771	0.5245

0.225806451612903	4.997	4.513	3.52	2.274	1.756	0.5233

0.258064516129032	4.989	4.488	3.496	2.268	1.703	0.522

0.290322580645161	4.912	4.418	3.452	2.224	1.694	0.4953

0.32258064516129	4.69	4.213	3.393	2.2	1.685	0.4948

0.354838709677419	4.659	4.183	3.337	2.197	1.683	0.4943

0.387096774193548	4.627	4.154	3.329	2.142	1.654	0.4872

0.419354838709677	4.613	4.145	3.246	2.138	1.634	0.4837

0.451612903225806	4.602	4.145	3.219	2.056	1.634	0.4807

0.483870967741936	4.602	4.134	3.194	2.028	1.579	0.4737

0.516129032258065	4.601	4.133	3.19	2.026	1.563	0.4737

0.548387096774194	4.597	4.131	3.184	2.024	1.552	0.4672

0.580645161290323	4.592	4.13	3.174	2.023	1.539	0.467

0.612903225806452	4.591	4.124	3.174	2.023	1.539	0.4526

0.645161290322581	4.591	4.117	3.173	2.021	1.538	0.4525

0.67741935483871	4.582	4.116	3.17	2.015	1.531	0.4503

0.709677419354839	4.58	4.115	3.157	2.008	1.525	0.4481

0.741935483870968	4.579	4.113	3.155	2	1.515	0.4463

0.774193548387097	4.576	4.107	3.149	1.997	1.501	0.4459

0.806451612903226	4.568	4.104	3.147	1.989	1.5	0.4395

0.838709677419355	4.566	4.099	3.141	1.989	1.497	0.4311

0.870967741935484	4.564	4.097	3.137	1.98	1.495	0.4294

0.903225806451613	4.56	4.092	3.135	1.974	1.481	0.4287

0.935483870967742	4.552	4.072	3.11	1.963	1.479	0.4286

0.967741935483871	4.543	4.068	3.108	1.95	1.468	0.4169

0.1		5.4278	4.8617	3.7786	2.5356	1.9823	0.59073

					Average of yearly averages:	0.49004

Inputs generated by pe5.pl - Novemeber 2006

Data used for this run:

Output File: novGApeachIRair

Metfile:	w03813.dvf

PRZM scenario:	GAPeachesSTD.txt

EXAMS environment file:	ir298.exv

Chemical Name:	novaluron

Description	Variable Name	Value	Units	Comments

Molecular weight	mwt	492.7	g/mol

Henry's Law Const.	henry	1.97e-13	atm-m^3/mol

Vapor Pressure	vapr	1.2e-7	torr

Solubility	sol	0.3	mg/L

Kd	Kd	165	mg/L

Koc	Koc		mg/L

Photolysis half-life	kdp	187	days	Half-life

Aerobic Aquatic Metabolism	kbacw	30.1	days	Halfife

Anaerobic Aquatic Metabolism	kbacs	52.1	days	Halfife

Aerobic Soil Metabolism	asm	15.6	days	Halfife

Hydrolysis:	pH 7	0	days	Half-life

Method:	CAM	2	integer	See PRZM manual

Incorporation Depth:	DEPI	0	cm

Application Rate:	TAPP	0.363	kg/ha

Application Efficiency:	APPEFF	0.95	fraction

Spray Drift	DRFT	.16	fraction of application rate applied to pond

Application Date	Date	21-03	dd/mm or dd/mmm or dd-mm or dd-mmm

Interval 1	interval	7	days	Set to 0 or delete line for single app.

app. rate 1	apprate	0.363	kg/ha

Interval 2	interval	7	days	Set to 0 or delete line for single app.

app. rate 2	apprate	0.363	kg/ha

Record 17:	FILTRA	

	IPSCND	1

	UPTKF	

Record 18:	PLVKRT	

	PLDKRT	0.0198

	FEXTRC	0.5

Flag for Index Res. Run	IR	Reservoir

Flag for runoff calc.	RUNOFF	total	none, monthly or total(average of
entire run)

Novaluron application to GA Peaches via airblast

stored as novGApeachIRab.out

Chemical: novaluron

PRZM environment: GAPeachesSTD.txt	modified Tueday, 29 May 2007 at
11:54:56

EXAMS environment: ir298.exv	modified Thuday, 29 August 2002 at 14:34:12

Metfile: w03813.dvf	modified Wedday, 3 July 2002 at 08:04:32

Water segment concentrations (ppb)

Year	Peak	96 hr	21 Day	60 Day	90 Day	Yearly

1961	2.542	2.299	1.945	1.283	1.001	0.2999

1962	2.21	2.014	1.575	0.9937	0.757	0.2241

1963	1.791	1.604	1.226	0.8447	0.6631	0.1996

1964	4.929	4.448	3.095	2.041	1.607	0.4964

1965	1.872	1.682	1.302	0.8241	0.6291	0.2114

1966	1.82	1.636	1.257	0.8086	0.6329	0.1946

1967	1.794	1.605	1.226	0.7753	0.5945	0.1825

1968	1.813	1.628	1.249	0.8143	0.6678	0.206

1969	1.825	1.638	1.259	0.7932	0.5985	0.1775

1970	3.437	3.099	2.51	1.514	1.164	0.3442

1971	2.134	1.924	1.539	0.9936	0.7773	0.2332

1972	1.804	1.619	1.241	0.7817	0.5909	0.1752

1973	2.792	2.528	1.895	1.356	1.098	0.3365

1974	1.994	1.801	1.452	0.9591	0.7466	0.2282

1975	2.398	2.177	1.648	1.186	0.9345	0.2901

1976	1.802	1.617	1.24	0.8885	0.7896	0.2608

1977	2.257	2.035	1.681	1.103	0.8313	0.2448

1978	1.981	1.794	1.47	1.039	0.8051	0.2394

1979	1.926	1.732	1.346	0.9459	0.7359	0.2217

1980	1.817	1.632	1.254	0.7898	0.5936	0.1706

1981	2.72	2.439	1.812	1.122	0.8949	0.277

1982	2.675	2.417	1.716	1.131	0.873	0.263

1983	1.815	1.636	1.263	0.8034	0.6176	0.1856

1984	1.805	1.621	1.243	0.785	0.6598	0.2064

1985	1.801	1.617	1.24	0.78	0.5855	0.1708

1986	1.799	1.613	1.235	0.773	0.5782	0.1646

1987	1.813	1.631	1.253	0.7902	0.5934	0.1711

1988	1.804	1.62	1.243	0.8162	0.6221	0.1822

1989	1.811	1.628	1.266	0.8209	0.6295	0.1865

1990	1.798	1.617	1.241	0.7838	0.5894	0.1696

Sorted results

Prob.		Peak	96 hr	21 Day	60 Day	90 Day	Yearly

0.032258064516129	4.929	4.448	3.095	2.041	1.607	0.4964

0.0645161290322581	3.437	3.099	2.51	1.514	1.164	0.3442

0.0967741935483871	2.792	2.528	1.945	1.356	1.098	0.3365

0.129032258064516	2.72	2.439	1.895	1.283	1.001	0.2999

0.161290322580645	2.675	2.417	1.812	1.186	0.9345	0.2901

0.193548387096774	2.542	2.299	1.716	1.131	0.8949	0.277

0.225806451612903	2.398	2.177	1.681	1.122	0.873	0.263

0.258064516129032	2.257	2.035	1.648	1.103	0.8313	0.2608

0.290322580645161	2.21	2.014	1.575	1.039	0.8051	0.2448

0.32258064516129	2.134	1.924	1.539	0.9937	0.7896	0.2394

0.354838709677419	1.994	1.801	1.47	0.9936	0.7773	0.2332

0.387096774193548	1.981	1.794	1.452	0.9591	0.757	0.2282

0.419354838709677	1.926	1.732	1.346	0.9459	0.7466	0.2241

0.451612903225806	1.872	1.682	1.302	0.8885	0.7359	0.2217

0.483870967741936	1.825	1.638	1.266	0.8447	0.6678	0.2114

0.516129032258065	1.82	1.636	1.263	0.8241	0.6631	0.2064

0.548387096774194	1.817	1.636	1.259	0.8209	0.6598	0.206

0.580645161290323	1.815	1.632	1.257	0.8162	0.6329	0.1996

0.612903225806452	1.813	1.631	1.254	0.8143	0.6295	0.1946

0.645161290322581	1.813	1.628	1.253	0.8086	0.6291	0.1865

0.67741935483871	1.811	1.628	1.249	0.8034	0.6221	0.1856

0.709677419354839	1.805	1.621	1.243	0.7932	0.6176	0.1825

0.741935483870968	1.804	1.62	1.243	0.7902	0.5985	0.1822

0.774193548387097	1.804	1.619	1.241	0.7898	0.5945	0.1775

0.806451612903226	1.802	1.617	1.241	0.785	0.5936	0.1752

0.838709677419355	1.801	1.617	1.24	0.7838	0.5934	0.1711

0.870967741935484	1.799	1.617	1.24	0.7817	0.5909	0.1708

0.903225806451613	1.798	1.613	1.235	0.78	0.5894	0.1706

0.935483870967742	1.794	1.605	1.226	0.7753	0.5855	0.1696

0.967741935483871	1.791	1.604	1.226	0.773	0.5782	0.1646

0.1		2.7848	2.5191	1.94	1.3487	1.0883	0.33284

					Average of yearly averages:	0.23045

Inputs generated by pe5.pl - Novemeber 2006

Data used for this run:

Output File: novGApeachIRab

Metfile:	w03813.dvf

PRZM scenario:	GAPeachesSTD.txt

EXAMS environment file:	ir298.exv

Chemical Name:	novaluron

Description	Variable Name	Value	Units	Comments

Molecular weight	mwt	492.7	g/mol

Henry's Law Const.	henry	1.97e-13	atm-m^3/mol

Vapor Pressure	vapr	1.2e-7	torr

Solubility	sol	0.3	mg/L

Kd	Kd	165	mg/L

Koc	Koc		mg/L

Photolysis half-life	kdp	187	days	Half-life

Aerobic Aquatic Metabolism	kbacw	30.1	days	Halfife

Anaerobic Aquatic Metabolism	kbacs	52.1	days	Halfife

Aerobic Soil Metabolism	asm	15.6	days	Halfife

Hydrolysis:	pH 7	0	days	Half-life

Method:	CAM	2	integer	See PRZM manual

Incorporation Depth:	DEPI	0	cm

Application Rate:	TAPP	0.363	kg/ha

Application Efficiency:	APPEFF	0.99	fraction

Spray Drift	DRFT	.063	fraction of application rate applied to pond

Application Date	Date	21-03	dd/mm or dd/mmm or dd-mm or dd-mmm

Interval 1	interval	7	days	Set to 0 or delete line for single app.

app. rate 1	apprate	0.363	kg/ha

Interval 2	interval	7	days	Set to 0 or delete line for single app.

app. rate 2	apprate	0.363	kg/ha

Record 17:	FILTRA	

	IPSCND	1

	UPTKF	

Record 18:	PLVKRT	

	PLDKRT	0.0198

	FEXTRC	0.5

Flag for Index Res. Run	IR	Reservoir

Flag for runoff calc.	RUNOFF	total	none, monthly or total(average of
entire run)

Novaluron aerial application to PA apples

stored as novPAappleIRair.out

Chemical: novaluron

PRZM environment: PAappleSTD.txt	modified Tueday, 29 May 2007 at
12:01:58

EXAMS environment: ir298.exv	modified Thuday, 29 August 2002 at 14:34:12

Metfile: w14751.dvf	modified Wedday, 3 July 2002 at 08:06:14

Water segment concentrations (ppb)

Year	Peak	96 hr	21 Day	60 Day	90 Day	Yearly

1961	4.963	4.521	3.403	2.564	2.077	0.651

1962	5.072	4.531	3.482	2.318	1.878	0.8061

1963	4.09	3.655	2.862	1.94	1.528	0.6636

1964	3.946	3.517	2.713	1.947	1.541	0.6112

1965	4.001	3.552	2.859	2.009	1.575	0.6256

1966	3.832	3.38	2.586	2.094	1.88	0.7718

1967	5.05	4.527	3.825	2.523	1.977	0.8605

1968	3.89	3.515	2.651	2.25	1.973	0.8396

1969	4.818	4.314	3.606	2.555	1.993	0.8561

1970	4.091	3.631	2.864	1.897	1.453	0.6143

1971	5.49	4.896	4.081	2.889	2.289	0.8168

1972	3.937	3.498	2.701	2.004	1.581	0.7035

1973	3.9	3.455	2.662	2.058	1.826	0.7489

1974	4.524	4.018	3.307	2.746	2.305	0.9623

1975	3.947	3.502	2.708	1.925	1.86	0.9065

1976	4.116	3.677	2.867	1.985	1.67	0.7852

1977	3.93	3.49	2.694	1.787	1.389	0.6128

1978	3.925	3.475	2.685	1.807	1.397	0.5376

1979	4.06	3.613	2.774	2.118	1.824	0.6991

1980	3.884	3.436	2.644	1.742	1.333	0.6066

1981	4.198	3.749	2.974	1.983	1.546	0.5872

1982	4.063	3.628	2.832	1.904	1.479	0.5867

1983	3.897	3.458	2.66	1.805	1.398	0.5459

1984	3.877	3.431	2.638	1.779	1.371	0.5299

1985	3.995	3.566	2.765	1.856	1.497	0.5688

1986	6.126	5.483	4.633	2.897	2.289	0.8473

1987	4.025	3.58	2.785	2.127	1.837	0.8242

1988	3.888	3.441	2.648	1.789	1.394	0.6445

1989	5.3	4.748	3.53	2.475	2.002	0.7588

1990	5.101	4.585	3.585	2.576	2.098	0.8736

Sorted results

Prob.		Peak	96 hr	21 Day	60 Day	90 Day	Yearly

0.032258064516129	6.126	5.483	4.633	2.897	2.305	0.9623

0.0645161290322581	5.49	4.896	4.081	2.889	2.289	0.9065

0.0967741935483871	5.3	4.748	3.825	2.746	2.289	0.8736

0.129032258064516	5.101	4.585	3.606	2.576	2.098	0.8605

0.161290322580645	5.072	4.531	3.585	2.564	2.077	0.8561

0.193548387096774	5.05	4.527	3.53	2.555	2.002	0.8473

0.225806451612903	4.963	4.521	3.482	2.523	1.993	0.8396

0.258064516129032	4.818	4.314	3.403	2.475	1.977	0.8242

0.290322580645161	4.524	4.018	3.307	2.318	1.973	0.8168

0.32258064516129	4.198	3.749	2.974	2.25	1.88	0.8061

0.354838709677419	4.116	3.677	2.867	2.127	1.878	0.7852

0.387096774193548	4.091	3.655	2.864	2.118	1.86	0.7718

0.419354838709677	4.09	3.631	2.862	2.094	1.837	0.7588

0.451612903225806	4.063	3.628	2.859	2.058	1.826	0.7489

0.483870967741936	4.06	3.613	2.832	2.009	1.824	0.7035

0.516129032258065	4.025	3.58	2.785	2.004	1.67	0.6991

0.548387096774194	4.001	3.566	2.774	1.985	1.581	0.6636

0.580645161290323	3.995	3.552	2.765	1.983	1.575	0.651

0.612903225806452	3.947	3.517	2.713	1.947	1.546	0.6445

0.645161290322581	3.946	3.515	2.708	1.94	1.541	0.6256

0.67741935483871	3.937	3.502	2.701	1.925	1.528	0.6143

0.709677419354839	3.93	3.498	2.694	1.904	1.497	0.6128

0.741935483870968	3.925	3.49	2.685	1.897	1.479	0.6112

0.774193548387097	3.9	3.475	2.662	1.856	1.453	0.6066

0.806451612903226	3.897	3.458	2.66	1.807	1.398	0.5872

0.838709677419355	3.89	3.455	2.651	1.805	1.397	0.5867

0.870967741935484	3.888	3.441	2.648	1.789	1.394	0.5688

0.903225806451613	3.884	3.436	2.644	1.787	1.389	0.5459

0.935483870967742	3.877	3.431	2.638	1.779	1.371	0.5376

0.967741935483871	3.832	3.38	2.586	1.742	1.333	0.5299

0.1		5.2801	4.7317	3.8031	2.729	2.2699	0.87229

					Average of yearly averages:	0.714866666666667

Inputs generated by pe5.pl - Novemeber 2006

Data used for this run:

Output File: novPAappleIRair

Metfile:	w14751.dvf

PRZM scenario:	PAappleSTD.txt

EXAMS environment file:	ir298.exv

Chemical Name:	novaluron

Description	Variable Name	Value	Units	Comments

Molecular weight	mwt	492.7	g/mol

Henry's Law Const.	henry	1.97e-13	atm-m^3/mol

Vapor Pressure	vapr	1.2e-7	torr

Solubility	sol	0.3	mg/L

Kd	Kd	165	mg/L

Koc	Koc		mg/L

Photolysis half-life	kdp	187	days	Half-life

Aerobic Aquatic Metabolism	kbacw	30.1	days	Halfife

Anaerobic Aquatic Metabolism	kbacs	52.1	days	Halfife

Aerobic Soil Metabolism	asm	15.6	days	Halfife

Hydrolysis:	pH 7	0	days	Half-life

Method:	CAM	2	integer	See PRZM manual

Incorporation Depth:	DEPI	0	cm

Application Rate:	TAPP	0.363	kg/ha

Application Efficiency:	APPEFF	0.95	fraction

Spray Drift	DRFT	0.16	fraction of application rate applied to pond

Application Date	Date	25-07	dd/mm or dd/mmm or dd-mm or dd-mmm

Interval 1	interval	10	days	Set to 0 or delete line for single app.

app. rate 1	apprate	0.363	kg/ha

Interval 2	interval	10	days	Set to 0 or delete line for single app.

app. rate 2	apprate	0.363	kg/ha

Record 17:	FILTRA	

	IPSCND	1

	UPTKF	

Record 18:	PLVKRT	

	PLDKRT	0.0198

	FEXTRC	0.5

Flag for Index Res. Run	IR	Reservoir

Flag for runoff calc.	RUNOFF	total	none, monthly or total(average of
entire run)

Novaluron application to GA Peaches via airblast

stored as novPAappleIRab.out

Chemical: novaluron

PRZM environment: PAappleSTD.txt	modified Tueday, 29 May 2007 at
12:01:58

EXAMS environment: ir298.exv	modified Thuday, 29 August 2002 at 14:34:12

Metfile: w14751.dvf	modified Wedday, 3 July 2002 at 08:06:14

Water segment concentrations (ppb)

Year	Peak	96 hr	21 Day	60 Day	90 Day	Yearly

1961	3.85	3.52	2.433	1.596	1.317	0.4302

1962	2.747	2.465	1.941	1.258	1.064	0.512

1963	1.701	1.524	1.22	0.84	0.6763	0.344

1964	1.56	1.39	1.074	0.8616	0.707	0.293

1965	1.761	1.581	1.29	0.9643	0.7796	0.3233

1966	3.189	2.893	2.066	1.343	1.154	0.4923

1967	3.03	2.717	2.247	1.465	1.163	0.5636

1968	3.39	3.073	2.179	1.39	1.22	0.5485

1969	3.033	2.707	2.284	1.516	1.194	0.5637

1970	1.753	1.561	1.278	0.8581	0.6653	0.3204

1971	3.606	3.227	2.545	1.894	1.509	0.533

1972	1.648	1.485	1.204	0.9553	0.7812	0.4118

1973	2.758	2.5	1.779	1.149	1.053	0.4603

1974	3.204	2.936	2.297	1.809	1.556	0.6868

1975	2.888	2.628	1.942	1.266	1.096	0.6176

1976	1.743	1.567	1.242	0.9079	0.8452	0.4843

1977	1.573	1.399	1.087	0.7273	0.5787	0.3066

1978	1.578	1.398	1.088	0.7578	0.5953	0.2372

1979	1.804	1.646	1.334	1.126	1.012	0.3993

1980	1.553	1.376	1.065	0.7078	0.544	0.3129

1981	1.82	1.629	1.344	0.894	0.7044	0.2729

1982	1.666	1.49	1.182	0.8012	0.6285	0.2612

1983	1.537	1.364	1.05	0.7425	0.5824	0.2357

1984	1.53	1.355	1.042	0.7291	0.5684	0.2279

1985	1.589	1.419	1.105	0.7468	0.6445	0.2549

1986	4.384	3.934	3.101	1.876	1.479	0.5387

1987	1.802	1.659	1.461	1.16	1.035	0.5214

1988	1.559	1.382	1.07	0.7511	0.5956	0.3428

1989	3.628	3.25	2.217	1.453	1.193	0.4532

1990	3.723	3.346	2.363	1.576	1.299	0.577

Sorted results

Prob.		Peak	96 hr	21 Day	60 Day	90 Day	Yearly

0.032258064516129	4.384	3.934	3.101	1.894	1.556	0.6868

0.0645161290322581	3.85	3.52	2.545	1.876	1.509	0.6176

0.0967741935483871	3.723	3.346	2.433	1.809	1.479	0.577

0.129032258064516	3.628	3.25	2.363	1.596	1.317	0.5637

0.161290322580645	3.606	3.227	2.297	1.576	1.299	0.5636

0.193548387096774	3.39	3.073	2.284	1.516	1.22	0.5485

0.225806451612903	3.204	2.936	2.247	1.465	1.194	0.5387

0.258064516129032	3.189	2.893	2.217	1.453	1.193	0.533

0.290322580645161	3.033	2.717	2.179	1.39	1.163	0.5214

0.32258064516129	3.03	2.707	2.066	1.343	1.154	0.512

0.354838709677419	2.888	2.628	1.942	1.266	1.096	0.4923

0.387096774193548	2.758	2.5	1.941	1.258	1.064	0.4843

0.419354838709677	2.747	2.465	1.779	1.16	1.053	0.4603

0.451612903225806	1.82	1.659	1.461	1.149	1.035	0.4532

0.483870967741936	1.804	1.646	1.344	1.126	1.012	0.4302

0.516129032258065	1.802	1.629	1.334	0.9643	0.8452	0.4118

0.548387096774194	1.761	1.581	1.29	0.9553	0.7812	0.3993

0.580645161290323	1.753	1.567	1.278	0.9079	0.7796	0.344

0.612903225806452	1.743	1.561	1.242	0.894	0.707	0.3428

0.645161290322581	1.701	1.524	1.22	0.8616	0.7044	0.3233

0.67741935483871	1.666	1.49	1.204	0.8581	0.6763	0.3204

0.709677419354839	1.648	1.485	1.182	0.84	0.6653	0.3129

0.741935483870968	1.589	1.419	1.105	0.8012	0.6445	0.3066

0.774193548387097	1.578	1.399	1.088	0.7578	0.6285	0.293

0.806451612903226	1.573	1.398	1.087	0.7511	0.5956	0.2729

0.838709677419355	1.56	1.39	1.074	0.7468	0.5953	0.2612

0.870967741935484	1.559	1.382	1.07	0.7425	0.5824	0.2549

0.903225806451613	1.553	1.376	1.065	0.7291	0.5787	0.2372

0.935483870967742	1.537	1.364	1.05	0.7273	0.5684	0.2357

0.967741935483871	1.53	1.355	1.042	0.7078	0.544	0.2279

0.1		3.7135	3.3364	2.426	1.7877	1.4628	0.57567

					Average of yearly averages:	0.41755

Inputs generated by pe5.pl - Novemeber 2006

Data used for this run:

Output File: novPAappleIRab

Metfile:	w14751.dvf

PRZM scenario:	PAappleSTD.txt

EXAMS environment file:	ir298.exv

Chemical Name:	novaluron

Description	Variable Name	Value	Units	Comments

Molecular weight	mwt	492.7	g/mol

Henry's Law Const.	henry	1.97e-13	atm-m^3/mol

Vapor Pressure	vapr	1.2e-7	torr

Solubility	sol	0.3	mg/L

Kd	Kd	165	mg/L

Koc	Koc		mg/L

Photolysis half-life	kdp	187	days	Half-life

Aerobic Aquatic Metabolism	kbacw	30.1	days	Halfife

Anaerobic Aquatic Metabolism	kbacs	52.1	days	Halfife

Aerobic Soil Metabolism	asm	15.6	days	Halfife

Hydrolysis:	pH 7	0	days	Half-life

Method:	CAM	2	integer	See PRZM manual

Incorporation Depth:	DEPI	0	cm

Application Rate:	TAPP	0.363	kg/ha

Application Efficiency:	APPEFF	0.99	fraction

Spray Drift	DRFT	0.063	fraction of application rate applied to pond

Application Date	Date	25-07	dd/mm or dd/mmm or dd-mm or dd-mmm

Interval 1	interval	10	days	Set to 0 or delete line for single app.

app. rate 1	apprate	0.363	kg/ha

Interval 2	interval	10	days	Set to 0 or delete line for single app.

app. rate 2	apprate	0.363	kg/ha

Record 17:	FILTRA	

	IPSCND	1

	UPTKF	

Record 18:	PLVKRT	

	PLDKRT	0.0198

	FEXTRC	0.5

Flag for Index Res. Run	IR	Reservoir

Flag for runoff calc.	RUNOFF	total	none, monthly or total(average of
entire run)

APPENDIX C

FIRST Output Files

Chlorophenyl Urea – novaluron application to apples

   RUN No.   1 FOR CPU              ON   apple         * INPUT VALUES * 

   --------------------------------------------------------------------

   RATE (#/AC)   No.APPS &   SOIL  SOLUBIL   APPL TYPE  %CROPPED INCORP

    ONE(MULT)    INTERVAL     Kd   (PPM )    (%DRIFT)     AREA    (IN)

   --------------------------------------------------------------------

  0.061(  0.159)   3  10      16.7   33.0   GRANUL( 0.0)  87.0     0.0

   FIELD AND RESERVOIR HALFLIFE VALUES (DAYS) 

   --------------------------------------------------------------------

   METABOLIC  DAYS UNTIL  HYDROLYSIS   PHOTOLYSIS   METABOLIC  COMBINED

    (FIELD)  RAIN/RUNOFF  (RESERVOIR)  (RES.-EFF)   (RESER.)   (RESER.) 

   --------------------------------------------------------------------

     47.10        2           0.00    0.00-    0.00   79.80      79.80

   UNTREATED WATER CONC (MICROGRAMS/LITER (PPB)) Ver 1.1.1  MAR 26,2008

   --------------------------------------------------------------------

        PEAK DAY  (ACUTE)      ANNUAL AVERAGE (CHRONIC)      

          CONCENTRATION             CONCENTRATION            

   --------------------------------------------------------------------

              4.549                      0.856

Chlorophenyl Urea – novaluron application to peaches

   RUN No.   2 FOR CPU              ON   peach         * INPUT VALUES * 

   --------------------------------------------------------------------

   RATE (#/AC)   No.APPS &   SOIL  SOLUBIL   APPL TYPE  %CROPPED INCORP

    ONE(MULT)    INTERVAL     Kd   (PPM )    (%DRIFT)     AREA    (IN)

   --------------------------------------------------------------------

  0.061(  0.166)   3   7      16.7   33.0   GRANUL( 0.0)  87.0     0.0

   FIELD AND RESERVOIR HALFLIFE VALUES (DAYS) 

   --------------------------------------------------------------------

   METABOLIC  DAYS UNTIL  HYDROLYSIS   PHOTOLYSIS   METABOLIC  COMBINED

    (FIELD)  RAIN/RUNOFF  (RESERVOIR)  (RES.-EFF)   (RESER.)   (RESER.) 

   --------------------------------------------------------------------

     47.10        2          N/A      0.00-    0.00    79.80     79.80

   UNTREATED WATER CONC (MICROGRAMS/LITER (PPB)) Ver 1.1.1  MAR 26,2008

   --------------------------------------------------------------------

        PEAK DAY  (ACUTE)      ANNUAL AVERAGE (CHRONIC)      

         
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   RUN No.   1 FOR chloroaniline    ON   apples        * INPUT VALUES * 

   --------------------------------------------------------------------

    RATE (#/AC)   No.APPS &   SOIL  SOLUBIL  APPL TYPE  %CROPPED INCORP

     ONE(MULT)    INTERVAL    Koc   (PPM )   (%DRIFT)     AREA    (IN)

   --------------------------------------------------------------------

  0.200(  0.600)   3  10    5899.0   10.6   GRANUL( 0.0)  87.0   0.0

   FIELD AND RESERVOIR HALFLIFE VALUES (DAYS) 

   --------------------------------------------------------------------

   METABOLIC  DAYS UNTIL  HYDROLYSIS   PHOTOLYSIS   METABOLIC  COMBINED

    (FIELD)  RAIN/RUNOFF  (RESERVOIR)  (RES.-EFF)   (RESER.)   (RESER.) 

   --------------------------------------------------------------------

      0.00        2          N/A      0.00-    0.00     0.00      0.00

   UNTREATED WATER CONC (MICROGRAMS/LITER (PPB)) Ver 1.1.1  MAR 26,2008

   --------------------------------------------------------------------

        PEAK DAY  (ACUTE)      ANNUAL AVERAGE (CHRONIC)      

          CONCENTRATION             CONCENTRATION            

   --------------------------------------------------------------------

             11.389                      2.604

Chloroaniline - novaluron application to peaches

   RUN No.   2 FOR chloroaniline    ON   peach         * INPUT VALUES * 

   --------------------------------------------------------------------

    RATE (#/AC)   No.APPS &   SOIL  SOLUBIL  APPL TYPE  %CROPPED INCORP

     ONE(MULT)    INTERVAL    Koc   (PPM )   (%DRIFT)     AREA    (IN)

   --------------------------------------------------------------------

  0.200(  0.600)   3   7    5899.0   10.6   GRANUL( 0.0)  87.0   0.0

   FIELD AND RESERVOIR HALFLIFE VALUES (DAYS) 

   --------------------------------------------------------------------

   METABOLIC  DAYS UNTIL  HYDROLYSIS   PHOTOLYSIS   METABOLIC  COMBINED

    (FIELD)  RAIN/RUNOFF  (RESERVOIR)  (RES.-EFF)   (RESER.)   (RESER.) 

   --------------------------------------------------------------------

      0.00        2          N/A      0.00-    0.00     0.00      0.00

   UNTREATED WATER CONC (MICROGRAMS/LITER (PPB)) Ver 1.1.1  MAR 26,2008

   --------------------------------------------------------------------

        PEAK DAY  (ACUTE)      ANNUAL AVERAGE (CHRONIC)      

          CONCENTRATION             CONCENTRATION            

   --------------------------------------------------------------------

             11.389                      2.604

 PAGE   

 PAGE   17