Document ID: EPA-HQ-RCRA-2002-0025-0028
Agency: epa
Document Type: Supporting & Related Material
Title: 
Posted Date: 2002-11-16T05:00Z

CONTENTS
­
1
Revision
6
August
2002
T
A
B
L
E
O
F
C
O
N
T
E
N
T
S
­­­­­­­­­­­­­­­­­­­­­
VOLUME
ONE
SECTION
A
­­­­­­­­­­­­­­­­­­­

DISCLAIMER
ABSTRACT
TABLE
OF
CONTENTS
METHOD
INDEX
AND
CONVERSION
TABLE
PREFACE
ACKNOWLEDGEMENTS
________________________________________________
PART
I
METHODS
FOR
ANALYTES
AND
PROPERTIES
CHAPTER
ONE
­­
QUALITY
CONTROL
1.0
Introduction
2.0
QA
Project
Plan
3.0
Field
Operations
4.0
Laboratory
Operations
5.0
Definitions
6.0
References
CHAPTER
TWO
­­
CHOOSING
THE
CORRECT
PROCEDURE
2.1
Purpose
2.2
Required
Information
2.3
Implementing
the
Guidance
2.4
Characteristics
2.5
Ground
Water
2.6
References
CHAPTER
THREE
­­
INORGANIC
ANALYTES
3.1
Sampling
Considerations
3.2
Sample
Preparation
Methods
Method
3005A:
Acid
Digestion
of
Waters
for
Total
Recoverable
or
Dissolved
Metals
for
Analysis
by
FLAA
or
ICP
Spectroscopy
Method
3010A:
Acid
Digestion
of
Aqueous
Samples
and
Extracts
for
Total
Metals
for
Analysis
by
FLAA
or
ICP
Spectroscopy
Method
3015:
Microwave
Assisted
Acid
Digestion
of
Aqueous
Samples
and
Extracts
CONTENTS
­
2
Revision
6
August
2002
Method
3020A:
Acid
Digestion
of
Aqueous
Samples
and
Extracts
for
Total
Metals
for
Analysis
by
GFAA
Spectroscopy
Method
3031:
Acid
Digestion
of
Oils
for
Metals
Analysis
by
Atomic
Absorption
or
ICP
Spectrometry
Method
3040A:
Dissolution
Procedure
for
Oils,
Greases,
or
Waxes
Method
3050B:
Acid
Digestion
of
Sediments,
Sludges,
and
Soils
Method
3051:
Microwave
Assisted
Acid
Digestion
of
Sediments,
Sludges,
Soils,
and
Oils
Method
3052:
Microwave
Assisted
Acid
Digestion
of
Siliceous
and
Organically
Based
Matrices
Method
3060A:
Alkaline
Digestion
for
Hexavalent
Chromium
3.3
Methods
for
Determination
of
Inorganic
Analytes
Method
6010B:
Inductively
Coupled
Plasma­
Atomic
Emission
Spectrometry
Method
6020:
Inductively
Coupled
Plasma­
Mass
Spectrometry
Method
7000A:
Atomic
Absorption
Methods
Method
7020:
Aluminum
(
Atomic
Absorption,
Direct
Aspiration)
Method
7040:
Antimony
(
Atomic
Absorption,
Direct
Aspiration)
Method
7041:
Antimony
(
Atomic
Absorption,
Furnace
Technique)
Method
7060A:
Arsenic
(
Atomic
Absorption,
Furnace
Technique)
Method
7061A:
Arsenic
(
Atomic
Absorption,
Gaseous
Hydride)
Method
7062:
Antimony
and
Arsenic
(
Atomic
Absorption,
Borohydride
Reduction)
Method
7063:
Arsenic
in
Aqueous
Samples
and
Extracts
by
Anodic
Stripping
Voltammetry
(
ASV)
Method
7080A:
Barium
(
Atomic
Absorption,
Direct
Aspiration)
Method
7081:
Barium
(
Atomic
Absorption,
Furnace
Technique)
Method
7090:
Beryllium
(
Atomic
Absorption,
Direct
Aspiration)
Method
7091:
Beryllium
(
Atomic
Absorption,
Furnace
Technique)
Method
7130:
Cadmium
(
Atomic
Absorption,
Direct
Aspiration)
Method
7131A:
Cadmium
(
Atomic
Absorption,
Furnace
Technique)
Method
7140:
Calcium
(
Atomic
Absorption,
Direct
Aspiration)
Method
7190:
Chromium
(
Atomic
Absorption,
Direct
Aspiration)
Method
7191:
Chromium
(
Atomic
Absorption,
Furnace
Technique)
Method
7195:
Chromium,
Hexavalent
(
Coprecipitation)
Method
7196A:
Chromium,
Hexavalent
(
Colorimetric)
Method
7197:
Chromium,
Hexavalent
(
Chelation/
Extraction)
Method
7198:
Chromium,
Hexavalent
(
Differential
Pulse
Polarography)
Method
7199:
Determination
of
Hexavalent
Chromium
in
Drinking
Water,
Groundwater
and
Industrial
Wastewater
Effluents
by
Ion
Chromatography
Method
7200:
Cobalt
(
Atomic
Absorption,
Direct
Aspiration)
Method
7201:
Cobalt
(
Atomic
Absorption,
Furnace
Technique)
Method
7210:
Copper
(
Atomic
Absorption,
Direct
Aspiration)
Method
7211:
Copper
(
Atomic
Absorption,
Furnace
Technique)
Method
7380:
Iron
(
Atomic
Absorption,
Direct
Aspiration)
Method
7381:
Iron
(
Atomic
Absorption,
Furnace
Technique)
Method
7420:
Lead
(
Atomic
Absorption,
Direct
Aspiration)
Method
7421:
Lead
(
Atomic
Absorption,
Furnace
Technique)
CONTENTS
­
3
Revision
6
August
2002
NOTE:
A
suffix
of
"
A"
in
the
method
number
indicates
revision
one
(
the
method
has
been
revised
once).
A
suffix
of
"
B"
in
the
method
number
indicates
revision
two
(
the
method
has
been
revised
twice).
A
suffix
of
"
C"
in
the
method
number
indicates
revision
three
(
the
method
has
been
revised
three
times),
etc.
In
order
to
properly
document
the
method
used
for
analysis,
the
entire
method
number
including
the
suffix
letter
designation
(
e.
g.,
A,
B,
C
or
D)
must
be
identified
by
the
analyst.
A
method
reference
found
within
the
RCRA
regulations
and
the
text
of
SW­
846
methods
and
chapters
refers
to
the
latest
promulgated
revision
of
the
method,
even
though
the
method
number
does
not
include
the
appropriate
letter
suffix.
Method
7430:
Lithium
(
Atomic
Absorption,
Direct
Aspiration)
Method
7450:
Magnesium
(
Atomic
Absorption,
Direct
Aspiration)
Method
7460:
Manganese
(
Atomic
Absorption,
Direct
Aspiration)
Method
7461:
Manganese
(
Atomic
Absorption,
Furnace
Technique)
Method
7470A:
Mercury
in
Liquid
Waste
(
Manual
Cold­
Vapor
Technique)
Method
7471A:
Mercury
in
Solid
or
Semisolid
Waste
(
Manual
Cold­
Vapor
Technique)
Method
7472:
Mercury
in
Aqueous
Samples
and
Extracts
by
Anodic
Stripping
Voltammetry
(
ASV)
Method
7480:
Molybdenum
(
Atomic
Absorption,
Direct
Aspiration)
Method
7481:
Molybdenum
(
Atomic
Absorption,
Furnace
Technique)
Method
7520:
Nickel
(
Atomic
Absorption,
Direct
Aspiration)
Method
7521:
Nickel
(
Atomic
Absorption,
Furnace
Method)
Method
7550:
Osmium
(
Atomic
Absorption,
Direct
Aspiration)
Method
7580:
White
Phosphorus
(
P
4)
by
Solvent
Extraction
and
Gas
Chromatography
Method
7610:
Potassium
(
Atomic
Absorption,
Direct
Aspiration)
Method
7740:
Selenium
(
Atomic
Absorption,
Furnace
Technique)
Method
7741A:
Selenium
(
Atomic
Absorption,
Gaseous
Hydride)
Method
7742:
Selenium
(
Atomic
Absorption,
Borohydride
Reduction)
Method
7760A:
Silver
(
Atomic
Absorption,
Direct
Aspiration)
Method
7761:
Silver
(
Atomic
Absorption,
Furnace
Technique)
Method
7770:
Sodium
(
Atomic
Absorption,
Direct
Aspiration)
Method
7780:
Strontium
(
Atomic
Absorption,
Direct
Aspiration)
Method
7840:
Thallium
(
Atomic
Absorption,
Direct
Aspiration)
Method
7841:
Thallium
(
Atomic
Absorption,
Furnace
Technique)
Method
7870:
Tin
(
Atomic
Absorption,
Direct
Aspiration)
Method
7910:
Vanadium
(
Atomic
Absorption,
Direct
Aspiration)
Method
7911:
Vanadium
(
Atomic
Absorption,
Furnace
Technique)
Method
7950:
Zinc
(
Atomic
Absorption,
Direct
Aspiration)
Method
7951:
Zinc
(
Atomic
Absorption,
Furnace
Technique)

APPENDIX
­­
COMPANY
REFERENCES
CONTENTS
­
4
Revision
6
August
2002
­­­­­­­­­­­­­­­­­­­­­
VOLUME
ONE
SECTION
B
­­­­­­­­­­­­­­­­­­­

DISCLAIMER
ABSTRACT
TABLE
OF
CONTENTS
METHOD
INDEX
AND
CONVERSION
TABLE
PREFACE
ACKNOWLEDGEMENTS
CHAPTER
ONE,
REPRINTED
­­
QUALITY
CONTROL
1.0
Introduction
2.0
QA
Project
Plan
3.0
Field
Operations
4.0
Laboratory
Operations
5.0
Definitions
6.0
References
CHAPTER
FOUR
­­
ORGANIC
ANALYTES
4.1
Sampling
Considerations
4.2
Sample
Preparation
Methods
4.2.1
Extractions
and
Preparations
Method
3500B:
Organic
Extraction
and
Sample
Preparation
Method
3510C:
Separatory
Funnel
Liquid­
Liquid
Extraction
Method
3520C:
Continuous
Liquid­
Liquid
Extraction
Method
3535:
Solid­
Phase
Extraction
(
SPE)
Method
3540C:
Soxhlet
Extraction
Method
3541:
Automated
Soxhlet
Extraction
Method
3542:
Extraction
of
Semivolatile
Analytes
Collected
Using
Method
0010
(
Modified
Method
5
Sampling
Train)
Method
3545:
Pressurized
Fluid
Extraction
(
PFE)
Method
3550B:
Ultrasonic
Extraction
Method
3560:
Supercritical
Fluid
Extraction
of
Total
Recoverable
Petroleum
Hydrocarbons
Method
3561:
Supercritical
Fluid
Extraction
of
Polynuclear
Aromatic
Hydrocarbons
Method
3580A:
Waste
Dilution
Method
3585:
Waste
Dilution
for
Volatile
Organics
Method
5000:
Sample
Preparation
for
Volatile
Organic
Compounds
Method
5021:
Volatile
Organic
Compounds
in
Soils
and
Other
Solid
Matrices
Using
Equilibrium
Headspace
Analysis
Method
5030B:
Purge­
and­
Trap
for
Aqueous
Samples
CONTENTS
­
5
Revision
6
August
2002
Method
5031:
Volatile,
Nonpurgeable,
Water­
Soluble
Compounds
by
Azeotropic
Distillation
Method
5032:
Volatile
Organic
Compounds
by
Vacuum
Distillation
Method
5035:
Closed­
System
Purge­
and­
Trap
and
Extraction
for
Volatile
Organics
in
Soil
and
Waste
Samples
Method
5041A:
Analysis
for
Desorption
of
Sorbent
Cartridges
from
Volatile
Organic
Sampling
Train
(
VOST)

4.2.2
Cleanup
Method
3600C:
Cleanup
Method
3610B:
Alumina
Cleanup
Method
3611B:
Alumina
Column
Cleanup
and
Separation
of
Petroleum
Wastes
Method
3620B:
Florisil
Cleanup
Method
3630C:
Silica
Gel
Cleanup
Method
3640A:
Gel­
Permeation
Cleanup
Method
3650B:
Acid­
Base
Partition
Cleanup
Method
3660B:
Sulfur
Cleanup
Method
3665A:
Sulfuric
Acid/
Permanganate
Cleanup
4.3
Determination
of
Organic
Analytes
4.3.1
Gas
Chromatographic
Methods
Method
8000B:
Determinative
Chromatographic
Separations
Method
8011:
1,2­
Dibromoethane
and
1,2­
Dibromo­
3­
chloropropane
by
Microextraction
and
Gas
Chromatography
Method
8015B:
Nonhalogenated
Organics
Using
GC/
FID
Method
8021B:
Aromatic
and
Halogenated
Volatiles
by
Gas
Chromatography
Using
Photoionization
and/
or
Electrolytic
Conductivity
Detectors
Method
8031:
Acrylonitrile
by
Gas
Chromatography
Method
8032A:
Acrylamide
by
Gas
Chromatography
Method
8033:
Acetonitrile
by
Gas
Chromatography
with
Nitrogen­
Phosphorus
Detection
Method
8041:
Phenols
by
Gas
Chromatography
Method
8061A:
Phthalate
Esters
by
Gas
Chromatography
with
Electron
Capture
Detection
(
GC/
ECD)
Method
8070A:
Nitrosamines
by
Gas
Chromatography
Method
8081A:
Organochlorine
Pesticides
by
Gas
Chromatography
Method
8082:
Polychlorinated
Biphenyls
(
PCBs)
by
Gas
Chromatography
Method
8091:
Nitroaromatics
and
Cyclic
Ketones
by
Gas
Chromatography
Method
8100:
Polynuclear
Aromatic
Hydrocarbons
Method
8111:
Haloethers
by
Gas
Chromatography
Method
8121:
Chlorinated
Hydrocarbons
by
Gas
Chromatography:
Capillary
Column
Technique
Method
8131:
Aniline
and
Selected
Derivatives
by
Gas
Chromatography
Method
8141A:
Organophosphorus
Compounds
by
Gas
Chromatography:
Capillary
Column
Technique
CONTENTS
­
6
Revision
6
August
2002
Method
8151A:
Chlorinated
Herbicides
by
GC
Using
Methylation
or
Pentafluorobenzylation
Derivatization
4.3.2
Gas
Chromatographic/
Mass
Spectroscopic
Methods
Method
8260B:
Volatile
Organic
Compounds
by
Gas
Chromatography/
Mass
Spectrometry
(
GC/
MS)
Method
8270C:
Semivolatile
Organic
Compounds
by
Gas
Chromatography/
Mass
Spectrometry
(
GC/
MS)
Method
8275A:
Semivolatile
Organic
Compounds
(
PAHs
and
PCBs)
in
Soils/
Sludges
and
Solid
Wastes
Using
Thermal
Extraction/
Gas
Chromatography/
Mass
Spectrometry
(
TE/
GC/
MS)
Method
8280A:
The
Analysis
of
Polychlorinated
Dibenzo­
p­
Dioxins
and
Polychlorinated
Dibenzofurans
by
High
Resolution
Gas
Chromatography/
Low
Resolution
Mass
Spectrometry
(
HRGC/
LRMS)
Method
8290:
Polychlorinated
Dibenzodioxins
(
PCDDs)
and
Polychlorinated
Dibenzofurans
(
PCDFs)
by
High­
Resolution
Gas
Chromatography/
High­
Resolution
Mass
Spectrometry
(
HRGC/
HRMS)
Attachment
A:
Procedures
for
the
Collection,
Handling,
Analysis,
and
Reporting
of
Wipe
Tests
Performed
within
the
Laboratory
4.3.3
High
Performance
Liquid
Chromatographic
Methods
Method
8310:
Polynuclear
Aromatic
Hydrocarbons
Method
8315A:
Determination
of
Carbonyl
Compounds
by
High
Performance
Liquid
Chromatography
(
HPLC)
Appendix
A:
Recrystallization
of
2,4­
Dinitrophenylhydrazine
(
DNPH)
Method
8316:
Acrylamide,
Acrylonitrile
and
Acrolein
by
High
Performance
Liquid
Chromatography
(
HPLC)
Method
8318:
N­
Methylcarbamates
by
High
Performance
Liquid
Chromatography
(
HPLC)
Method
8321A:
Solvent
Extractable
Nonvolatile
Compounds
by
High
Performance
Liquid
Chromatography/
Thermospray/
Mass
Spectrometry
(
HPLC/
TS/
MS)
or
Ultraviolet
(
UV)
Detection
Method
8325:
Solvent
Extractable
Nonvolatile
Compounds
by
High
Performance
Liquid
Chromatography/
Particle
Beam/
Mass
Spectrometry
(
HPLC/
PB/
MS)
Method
8330:
Nitroaromatics
and
Nitramines
by
High
Performance
Liquid
Chromatography
(
HPLC)
Method
8331:
Tetrazene
by
Reverse
Phase
High
Performance
Liquid
Chromatography
(
HPLC)
Method
8332:
Nitroglycerine
by
High
Performance
Liquid
Chromatography
4.3.4
Infrared
Methods
Method
8410:
Gas
Chromatography/
Fourier
Transform
Infrared
(
GC/
FT­
IR)
Spectrometry
for
Semivolatile
Organics:
Capillary
Column
Method
8430:
Analysis
of
Bis(
2­
chloroethyl)
Ether
and
Hydrolysis
Products
by
Direct
Aqueous
Injection
GC/
FT­
IR
CONTENTS
­
7
Revision
6
August
2002
NOTE:
A
suffix
of
"
A"
in
the
method
number
indicates
revision
one
(
the
method
has
been
revised
once).
A
suffix
of
"
B"
in
the
method
number
indicates
revision
two
(
the
method
has
been
revised
twice).
A
suffix
of
"
C"
in
the
method
number
indicates
revision
three
(
the
method
has
been
revised
three
times),
etc.
In
order
to
properly
document
the
method
used
for
analysis,
the
entire
method
number
including
the
suffix
letter
designation
(
e.
g.,
A,
B,
C
or
D)
must
be
identified
by
the
analyst.
A
method
reference
found
within
the
RCRA
regulations
and
the
text
of
SW­
846
methods
and
chapters
refers
to
the
latest
promulgated
revision
of
the
method,
even
though
the
method
number
does
not
include
the
appropriate
letter
suffix.
Method
8440:
Total
Recoverable
Petroleum
Hydrocarbons
by
Infrared
Spectrophotometry
4.3.5
Miscellaneous
Spectrometric
Methods
Method
8520:
Continuous
Measurement
of
Formaldehyde
in
Ambient
Air
4.4
Immunoassay
Methods
Method
4000:
Immunoassay
Method
4010A:
Screening
for
Pentachlorophenol
by
Immunoassay
Method
4015:
Screening
for
2,4­
Dichlorophenoxyacetic
Acid
by
Immunoassay
Method
4020:
Screening
for
Polychlorinated
Biphenyls
by
Immunoassay
Method
4030:
Soil
Screening
for
Petroleum
Hydrocarbons
by
Immunoassay
Method
4035:
Soil
Screening
for
Polynuclear
Aromatic
Hydrocarbons
by
Immunoassay
Method
4040:
Soil
Screening
for
Toxaphene
by
Immunoassay
Method
4041:
Soil
Screening
for
Chlordane
by
Immunoassay
Method
4042:
Soil
Screening
for
DDT
by
Immunoassay
Method
4050:
TNT
Explosives
in
Soil
by
Immunoassay
Method
4051:
Hexahydro­
1,3,5­
trinitro­
1,3,5­
triazine
(
RDX)
in
Soil
by
Immunoassay
4.5
Miscellaneous
Screening
Methods
Method
3810:
Headspace
Method
3820:
Hexadecane
Extraction
and
Screening
of
Purgeable
Organics
Method
8515:
Colorimetric
Screening
Method
for
Trinitrotoluene
(
TNT)
in
Soil
Method
9078:
Screening
Test
Method
for
Polychlorinated
Biphenyls
in
Soil
Method
9079:
Screening
Test
Method
for
Polychlorinated
Biphenyls
in
Transformer
Oil
APPENDIX
­­
COMPANY
REFERENCES
CONTENTS
­
8
Revision
6
August
2002
­­­­­­­­­­­­­­­­­­­­­
VOLUME
ONE
SECTION
C
­­­­­­­­­­­­­­­­­­­

DISCLAIMER
ABSTRACT
TABLE
OF
CONTENTS
METHOD
INDEX
AND
CONVERSION
TABLE
PREFACE
CHAPTER
ONE,
REPRINTED
­­
QUALITY
CONTROL
1.0
Introduction
2.0
QA
Project
Plan
3.0
Field
Operations
4.0
Laboratory
Operations
5.0
Definitions
6.0
References
CHAPTER
FIVE
­­
MISCELLANEOUS
TEST
METHODS
Method
5050:
Bomb
Preparation
Method
for
Solid
Waste
Method
9010C:
Total
and
Amenable
Cyanide:
Distillation
Method
9012B:
Total
and
Amenable
Cyanide
(
Automated
Colorimetric,
with
Off­
Line
Distillation)
Method
9013:
Cyanide
Extraction
Procedure
for
Solids
and
Oils
Method
9014:
Titrimetric
and
Manual
Spectrophotometric
Determinative
Methods
for
Cyanide
Method
9020B:
Total
Organic
Halides
(
TOX)
Method
9021:
Purgeable
Organic
Halides
(
POX)
Method
9022:
Total
Organic
Halides
(
TOX)
by
Neutron
Activation
Analysis
Method
9023:
Extractable
Organic
Halides
(
EOX)
in
Solids
Method
9030B:
Acid­
Soluble
and
Acid­
Insoluble
Sulfides:
Distillation
Method
9031:
Extractable
Sulfides
Method
9034:
Titrimetric
Procedure
for
Acid­
Soluble
and
Acid­
Insoluble
Sulfides
Method
9035:
Sulfate
(
Colorimetric,
Automated,
Chloranilate)
Method
9036:
Sulfate
(
Colorimetric,
Automated,
Methylthymol
Blue,
AA
II)
Method
9038:
Sulfate
(
Turbidimetric)
Method
9056:
Determination
of
Inorganic
Anions
by
Ion
Chromatography
Method
9057:
Determination
of
Chloride
from
HCl/
Cl
2
Emission
Sampling
Train
(
Methods
0050
and
0051)
by
Anion
Chromatography
Method
9060A:
Total
Organic
Carbon
Method
9065:
Phenolics
(
Spectrophotometric,
Manual
4­
AAP
with
Distillation)
Method
9066:
Phenolics
(
Colorimetric,
Automated
4­
AAP
with
Distillation)
Method
9067:
Phenolics
(
Spectrophotometric,
MBTH
with
Distillation)
Method
9070A:
n­
Hexane
Extractable
Material
(
HEM)
for
Aqueous
Samples
CONTENTS
­
9
Revision
6
August
2002
Method
9071B:
n­
Hexane
Extractable
Material
(
HEM)
for
Sludge,
Sediment,
and
Solid
Samples
Method
9075:
Test
Method
for
Total
Chlorine
in
New
and
Used
Petroleum
Products
by
X­
Ray
Fluorescence
Spectrometry
(
XRF)
Method
9076:
Test
Method
for
Total
Chlorine
in
New
and
Used
Petroleum
Products
by
Oxidative
Combustion
and
Microcoulometry
Method
9077:
Test
Methods
for
Total
Chlorine
in
New
and
Used
Petroleum
Products
(
Field
Test
Kit
Methods)
Method
A:
Fixed
End
Point
Test
Kit
Method
Method
B:
Reverse
Titration
Quantitative
End
Point
Test
Kit
Method
Method
C:
Direct
Titration
Quantitative
End
Point
Test
Kit
Method
Method
9131:
Total
Coliform:
Multiple
Tube
Fermentation
Technique
Method
9132:
Total
Coliform:
Membrane­
Filter
Technique
Method
9210:
Potentiometric
Determination
of
Nitrate
in
Aqueous
Samples
with
Ion­
Selective
Electrode
Method
9211:
Potentiometric
Determination
of
Bromide
in
Aqueous
Samples
with
Ion­
Selective
Electrode
Method
9212:
Potentiometric
Determination
of
Chloride
in
Aqueous
Samples
with
Ion­
Selective
Electrode
Method
9213:
Potentiometric
Determination
of
Cyanide
in
Aqueous
Samples
and
Distillates
with
Ion­
Selective
Electrode
Method
9214:
Potentiometric
Determination
of
Fluoride
in
Aqueous
Samples
with
Ion­
Selective
Electrode
Method
9215:
Potentiometric
Determination
of
Sulfide
in
Aqueous
Samples
and
Distillates
with
Ion­
Selective
Electrode
Method
9250:
Chloride
(
Colorimetric,
Automated
Ferricyanide
AAI)
Method
9251:
Chloride
(
Colorimetric,
Automated
Ferricyanide
AAII)
Method
9253:
Chloride
(
Titrimetric,
Silver
Nitrate)
Method
9320:
Radium­
228
CHAPTER
SIX
­­
PROPERTIES
Method
1030:
Ignitability
of
Solids
Method
1120:
Dermal
Corrosion
Method
1312:
Synthetic
Precipitation
Leaching
Procedure
Method
1320:
Multiple
Extraction
Procedure
Method
1330A:
Extraction
Procedure
for
Oily
Wastes
Method
9041A:
pH
Paper
Method
Method
9045D:
Soil
and
Waste
pH
Method
9050A:
Specific
Conductance
Method
9080:
Cation­
Exchange
Capacity
of
Soils
(
Ammonium
Acetate)
Method
9081:
Cation­
Exchange
Capacity
of
Soils
(
Sodium
Acetate)
Method
9090A:
Compatibility
Test
for
Wastes
and
Membrane
Liners
Method
9095B:
Paint
Filter
Liquids
Test
Method
9096:
Liquid
Release
Test
(
LRT)
Procedure
Appendix
A:
Liquid
Release
Test
Pre­
Test
Method
9100:
Saturated
Hydraulic
Conductivity,
Saturated
Leachate
Conductivity,
and
Intrinsic
Permeability
CONTENTS
­
10
Revision
6
August
2002
NOTE:
A
suffix
of
"
A"
in
the
method
number
indicates
revision
one
(
the
method
has
been
revised
once).
A
suffix
of
"
B"
in
the
method
number
indicates
revision
two
(
the
method
has
been
revised
twice).
A
suffix
of
"
C"
in
the
method
number
indicates
revision
three
(
the
method
has
been
revised
three
times),
etc.
In
order
to
properly
document
the
method
used
for
analysis,
the
entire
method
number
including
the
suffix
letter
designation
(
e.
g.,
A,
B,
C
or
D)
must
be
identified
by
the
analyst.
A
method
reference
found
within
the
RCRA
regulations
and
the
text
of
SW­
846
methods
and
chapters
refers
to
the
latest
promulgated
revision
of
the
method,
even
though
the
method
number
does
not
include
the
appropriate
letter
suffix.
Method
9310:
Gross
Alpha
and
Gross
Beta
Method
9315:
Alpha­
Emitting
Radium
Isotopes
___________________________
PART
II
CHARACTERISTICS
CHAPTER
SEVEN
­­
CHARACTERISTICS
INTRODUCTION
AND
REGULATORY
DEFINITIONS
7.1
Ignitability
7.2
Corrosivity
7.3
Reactivity
7.4
Toxicity
Characteristic
Leaching
Procedure
CHAPTER
EIGHT
­­
METHODS
FOR
DETERMINING
CHARACTERISTICS
8.1
Ignitability
Method
1010A:
Pensky­
Martens
Closed­
Cup
Method
for
Determining
Ignitability
Method
1020B:
Small
Scale
Closed
Cup
Method
for
Determining
Ignitability
8.2
Corrosivity
Method
9040C:
pH
Electrometric
Measurement
Method
1110A:
Corrosivity
Toward
Steel
8.3
Reactivity
8.4
Toxicity
Method
1310B:
Extraction
Procedure
(
EP)
Toxicity
Test
Method
and
Structural
Integrity
Test
Method
1311:
Toxicity
Characteristic
Leaching
Procedure
APPENDIX
­­
COMPANY
REFERENCES
CONTENTS
­
11
Revision
6
August
2002
­­­­­­­­­­­­­­­­­­­­­­­­
VOLUME
TWO
­­­­­­­­­­­­­­­­­­­­­­­­

DISCLAIMER
ABSTRACT
TABLE
OF
CONTENTS
METHOD
INDEX
AND
CONVERSION
TABLE
PREFACE
CHAPTER
ONE,
REPRINTED
­­
QUALITY
CONTROL
1.0
Introduction
2.0
QA
Project
Plan
3.0
Field
Operations
4.0
Laboratory
Operations
5.0
Definitions
6.0
References
__________________
PART
III
SAMPLING
CHAPTER
NINE
­­
SAMPLING
PLAN
9.1
Design
and
Development
9.2
Implementation
CHAPTER
TEN
­­
SAMPLING
METHODS
Method
0010:
Modified
Method
5
Sampling
Train
Appendix
A:
Preparation
of
XAD­
2
Sorbent
Resin
Appendix
B:
Total
Chromatographable
Organic
Material
Analysis
Method
0011:
Sampling
for
Selected
Aldehyde
and
Ketone
Emissions
from
Stationary
Sources
Method
0020:
Source
Assessment
Sampling
System
(
SASS)
Method
0023A:
Sampling
Method
for
Polychlorinated
Dibenzo­
p­
Dioxins
and
Polychlorinated
Dibenzofuran
Emissions
from
Stationary
Sources
Method
0030:
Volatile
Organic
Sampling
Train
Method
0031:
Sampling
Method
for
Volatile
Organic
Compounds
(
SMVOC)
Method
0040:
Sampling
of
Principal
Organic
Hazardous
Constituents
from
Combustion
Sources
Using
Tedlar
®
Bags
Method
0050:
Isokinetic
HCl/
Cl
2
Emission
Sampling
Train
Method
0051:
Midget
Impinger
HCl/
Cl
2
Emission
Sampling
Train
Method
0060:
Determination
of
Metals
in
Stack
Emissions
Method
0061:
Determination
of
Hexavalent
Chromium
Emissions
from
Stationary
Sources
Method
0100:
Sampling
for
Formaldehyde
and
Other
Carbonyl
Compounds
in
Indoor
Air
CONTENTS
­
12
Revision
6
August
2002
NOTE:
A
suffix
of
"
A"
in
the
method
number
indicates
revision
one
(
the
method
has
been
revised
once).
A
suffix
of
"
B"
in
the
method
number
indicates
revision
two
(
the
method
has
been
revised
twice).
A
suffix
of
"
C"
in
the
method
number
indicates
revision
three
(
the
method
has
been
revised
three
times),
etc.
In
order
to
properly
document
the
method
used
for
analysis,
the
entire
method
number
including
the
suffix
letter
designation
(
e.
g.,
A,
B,
C
or
D)
must
be
identified
by
the
analyst.
A
method
reference
found
within
the
RCRA
regulations
and
the
text
of
SW­
846
methods
and
chapters
refers
to
the
latest
promulgated
revision
of
the
method,
even
though
the
method
number
does
not
include
the
appropriate
letter
suffix.
____________________
PART
IV
MONITORING
CHAPTER
ELEVEN
­­
GROUND
WATER
MONITORING
11.1
Background
and
Objectives
11.2
Relationship
to
the
Regulations
and
to
Other
Documents
11.3
Revisions
and
Additions
11.4
Acceptable
Designs
and
Practices
11.5
Unacceptable
Designs
and
Practices
CHAPTER
TWELVE
­­
LAND
TREATMENT
MONITORING
12.1
Background
12.2
Treatment
Zone
12.3
Regulatory
Definition
12.4
Monitoring
and
Sampling
Strategy
12.5
Analysis
12.6
References
and
Bibliography
CHAPTER
THIRTEEN
­­
INCINERATION
13.1
Introduction
13.2
Regulatory
Definition
13.3
Waste
Characterization
Strategy
13.4
Stack­
Gas
Effluent
Characterization
Strategy
13.5
Additional
Effluent
Characterization
Strategy
13.6
Selection
of
Specific
Sampling
and
Analysis
Methods
13.7
References
APPENDIX
­­
COMPANY
REFERENCES