cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.6084/m9.figshare.4443254.v1
title: Microwave assisted solid phase catalyst-free Biginelli synthesis of 3,4-dihydropyrimidin-2(1<i>H</i>)-one and 3,4-dihydropyrimidin-2(1<i>H</i>)-thione: A green approach, characterization and molecular crystal structures

description: Solid phase catalyst-free Biginelli synthesis of novel 5-carbethoxy-4-(3-bromo-4-hydroxy-5-methoxyphenyl)-6-methyl-3,4-dihydropyrimidin-2(1H)-one (C<sub>15</sub>H<sub>17</sub>BrN<sub>2</sub>O<sub>5</sub>) and 5-carbethoxy-4-(3-bromo-4-hydroxy-5-methoxyphenyl)-6-methyl-3,4-dihydropyrimidin-2(1H)-thione (C<sub>15</sub>H<sub>17</sub>BrN<sub>2</sub>O<sub>4</sub>S) has been carried out under microwave irradiation at 400W. The structures of both compounds were confirmed by <sup>1</sup>H NMR, <sup>13</sup>C NMR, Mass, FT-IR, Elemental analysis, and single crystal X-ray diffraction method. The single crystals of both compounds were obtained by crystallization in 0.35 × 0.30 × 0.25 mm dimension for (C<sub>15</sub>H<sub>17</sub>BrN<sub>2</sub>O<sub>5</sub>) and 0.35 × 0.32 × 0.30 mm dimension for (C<sub>15</sub>H<sub>17</sub>BrN<sub>2</sub>O<sub>4</sub>S). Both compounds, (C<sub>15</sub>H<sub>17</sub>BrN<sub>2</sub>O<sub>5</sub>) and (C<sub>15</sub>H<sub>17</sub>BrN<sub>2</sub>O<sub>4</sub>S) crystallizes in the monoclinic P2<sub>1</sub>/c space group and shows four and two intermolecular hydrogen bonds, respectively.
DOI: 10.3886/e118183v1-43828
title: Programs and Artificial Data for "An Estimated Structural Model of Entrepreneurial Behavior"

description: Using a rich panel of owner-operated New York dairy farms, we provide new evidence on entrepreneurial behavior. We formulate a dynamic model of farms facing uninsured risks and financial constraints. Farmers derive nonpecuniary benefits from operating their businesses. We estimate the model via simulated minimum distance, matching both production and financial data. We find that financial factors and nonpecuniary benefits are of first-order importance. Collateral constraints and liquidity restrictions inhibit borrowing and the accumulation of capital, especially among high productivity firms seeking to expand. The nonpecuniary benefits to farming are large and keep small, low-productivity farms in business. Although farmers are risk averse, eliminating uninsured production risk has only modest effects on capital and output.
description: Most of the data in this archive are artificial. We have included them to make the programs operative.
DOI: 10.3886/e119453v1
title: Data and code for "Explaining the Decline in the U.S. Employment-to-Population Ratio: A Review of the Evidence"

description: This paper first documents trends in employment rates and then reviews what is known about the various factors that have been proposed to explain the decline in the overall employment-to-population ratio between 1999 and 2018. Population aging has had a large effect on the overall employment rate over this period, but within-age-group declines in employment among young and prime age adults also have played a central role. Among the factors whose effects the evidence allows us to quantify, labor demand factors, in particular increased import competition from China and the penetration of robots into the labor market, are the most important drivers of observed within-group declines in employment. Labor supply factors, most notably increased participation in disability insurance programs, have played a less important but not inconsequential role. Increases in the real value of state minimum wages and in the share of individuals with prison records also have contributed modestly to the decline in the aggregate employment rate. In addition to the factors whose effects we roughly quantify, we identify a set of potentially important factors about which the evidence does not yet allow us to draw clear conclusions. These include the challenges associated with arranging child care, improvements in leisure technology, changing social norms, increased use of opioids, the growth in occupational licensing, and declining labor market fluidity. Our evidence-driven ranking of factors should be useful for guiding future discussions about the sources of decline in the aggregate employment-to-population ratio and consequently the likely efficacy of alternative policy approaches to increasing employment rates.
DOI: 10.3886/e120914v1
title: State-by-State Spending on Kids Dataset

description: This dataset provides a comprehensive accounting of public spending on children from 1997 through 2016. It draws on the US Census Bureau’s Annual Survey of State and Local Government Finances, as well as several federal and other noncensus sources, to capture state-by-state spending on education, income security, health, and other areas. The data were assembled by Julia Isaacs, Eleanor Lauderback, and Erica Greenberg of the Urban Institute, working in collaboration with Margot Jackson of Brown University for her study of public spending on children and class gaps in child development, with support from the Russell Sage Foundation and the National Institutes of Health.
description: Please see the data dictionary for source and imputation information. Data are limited by the categories included in source datasets and by availability in some states and years.
description: All public spending on kids in the US. Smallest Geographic Unit: State
DOI: 10.6084/m9.figshare.4441325
title: The challenges of predicting pesticide exposure of honey bees at landscape level - Public repository

description: In this directory you will find all datasets, scripts and analyses outputs from the following paper <br><br>Simon-Delso, N., San Martin, G., Bruneau, E., Delcourt, C., Hautier, L., 2017. The challenges of predicting pesticide exposure of honey bees at landscape level. Scientific Reports 7, 3801. doi:10.1038/s41598-017-03467-5 <br><br>`Bee_landscape.R` provides the code and `report_Bee_landscape.pdf` provides the ouputs of these analyses. <br><br>The `scripts` folder contains two scripts with functions that are used (sourced) in `Bee_landscape.R`. <br><br>The `data` folder provides the raw data with a `README.md` file providing detailed description of these data. <br>We were not allowed to make public the raw geodata (shapefile) used to compute the crop surfaces<br>around the apiaries. The apiaries coordinates have also been rounded to the second decimal<br>to protect the beekeepers privacy.<br><br>These raw data might look quite complex. So we have grouped most of the data in a more understandable structure in the `data_out` folder. These summary dataset are generated by the `Bee_landscape.R` script. This script is working directly with the raw data for more flexibility.<br><br><br>Summary of the paper : <br><br><br>To evaluate the risks of pesticides for pollinators, we must not only evaluate their toxicity but also understand how pollinators are exposed to these xenobiotics in the field. We focused on this last point and modeled honey bee exposure to pesticides at the landscape level. Pollen pellet samples (n = 60) from 40 Belgian apiaries were collected from late July to October 2011 and underwent palynological and pesticide residue analyses. Areas of various crops around each apiary were measured at 4 spatial scales. The most frequently detected pesticides were the fungicides boscalid (n = 19, 31.7%) and pyrimethanil (n = 10, 16.7%) and the insecticide dimethoate (n = 10, 16.7%). We were able to predict exposure probability for boscalid and dimethoate by using broad indicators of cropping intensity, but it remained difficult to identify the precise source of contamination (e.g. specific crops in which the use of the pesticide is authorized). For pyrimethanil, we were not able to build any convincing landscape model that could explain the contamination. Our results, combined with the late sampling period, strongly suggest that pesticides applied to crops unattractive to pollinators, and therefore considered of no risk for them, may be sources of exposure through weeds, drift to neighboring plants, or succeeding crops. <br><br>
DOI: 10.6084/m9.figshare.4441325.v1
title: The challenges of predicting pesticide exposure of honey bees at landscape level (Simon Delso et al. 2017)

description: In this directory you will find all datasets, scripts and analyses outputs from the following paper <br><br>Simon-Delso, N., San Martin, G., Bruneau, E., Delcourt, C., Hautier, L., 2017. The challenges of predicting pesticide exposure of honey bees at landscape level. Scientific Reports 7, 3801. doi:10.1038/s41598-017-03467-5 <br><br>`Bee_landscape.R` provides the code and `report_Bee_landscape.pdf` provides the ouputs of these analyses. <br><br>The `scripts` folder contains two scripts with functions that are used (sourced) in `Bee_landscape.R`. <br><br>The `data` folder provides the raw data with a `README.md` file providing detailed description of these data. <br>We were not allowed to make public the raw geodata (shapefile) used to compute the crop surfaces<br>around the apiaries. The apiaries coordinates have also been rounded to the second decimal<br>to protect the beekeepers privacy.<br><br>These raw data might look quite complex. So we have grouped most of the data in a more understandable structure in the `data_out` folder. These summary dataset are generated by the `Bee_landscape.R` script. This script is working directly with the raw data for more flexibility.<br><br><br>Summary of the paper : <br><br><br>To evaluate the risks of pesticides for pollinators, we must not only evaluate their toxicity but also understand how pollinators are exposed to these xenobiotics in the field. We focused on this last point and modeled honey bee exposure to pesticides at the landscape level. Pollen pellet samples (n = 60) from 40 Belgian apiaries were collected from late July to October 2011 and underwent palynological and pesticide residue analyses. Areas of various crops around each apiary were measured at 4 spatial scales. The most frequently detected pesticides were the fungicides boscalid (n = 19, 31.7%) and pyrimethanil (n = 10, 16.7%) and the insecticide dimethoate (n = 10, 16.7%). We were able to predict exposure probability for boscalid and dimethoate by using broad indicators of cropping intensity, but it remained difficult to identify the precise source of contamination (e.g. specific crops in which the use of the pesticide is authorized). For pyrimethanil, we were not able to build any convincing landscape model that could explain the contamination. Our results, combined with the late sampling period, strongly suggest that pesticides applied to crops unattractive to pollinators, and therefore considered of no risk for them, may be sources of exposure through weeds, drift to neighboring plants, or succeeding crops. <br><br>
DOI: 10.6084/m9.figshare.4440746
title: The Neogene Mediterranean origin of <i>Cyprideis torosa</i> (Jones, 1850)

description: Biometric tables and the list of the examined material
DOI: 10.6084/m9.figshare.4440746.v1
title: The Neogene Mediterranean origin of <i>Cyprideis torosa</i> (Jones, 1850)

description: Biometric tables and the list of the examined material
DOI: 10.6084/m9.figshare.4440050
title: Habitat Use and Spatial Variability of Hawkfishes with a Focus on Colour Polymorphism in Paracirrhites forsteri

description: Identifying relationships between fishes and their environment is an integral part of understanding coral reef ecosystems. However, this information is lacking for many species, particularly in understudied and remote regions. With coral reefs continuing to face environmental pressures, insight into abundance and distribution patterns along with resource use of fish communities will aid in advancing our ecological understanding and management processes. Based on ecological surveys of hawkfish assemblages (Family: Cirrhitidae) in the Red Sea, we reveal distinct patterns in the distribution and abundance across the continental shelf, wave exposure, and with depth, particularly in the four colour morphs of <i>Paracirrhites forsteri</i>. Distinct patterns were observed among hawkfishes, with higher abundance of all species recorded on reefs farther from shore and on wave exposed reef zones. <i>Cirrhitus spilotoceps</i> was only recorded on the exposed crest, but unlike the other species, did not associate with live coral colonies. Overall, the most abundant species was <i>P. forsteri. </i>This species exploited a variety of habitats but showed an affinity for complex habitats provided by live and dead coral colonies. No difference in habitat use was observed among the four colour morphs, but distinct patterns were apparent in distribution and abundance with depth. This study suggests that in addition to <i>P. forsteri</i> exhibiting diverse colour morphologies, these various morphotypes appear to have corresponding ecological differences in the Red Sea. To better understand this, further studies are needed to identify what these differences extend to and the mechanisms involved.
DOI: 10.6084/m9.figshare.4440050.v1
title: Habitat Use and Spatial Variability of Hawkfishes with a Focus on Colour Polymorphism in Paracirrhites forsteri

description: Identifying relationships between fishes and their environment is an integral part of understanding coral reef ecosystems. However, this information is lacking for many species, particularly in understudied and remote regions. With coral reefs continuing to face environmental pressures, insight into abundance and distribution patterns along with resource use of fish communities will aid in advancing our ecological understanding and management processes. Based on ecological surveys of hawkfish assemblages (Family: Cirrhitidae) in the Red Sea, we reveal distinct patterns in the distribution and abundance across the continental shelf, wave exposure, and with depth, particularly in the four colour morphs of <i>Paracirrhites forsteri</i>. Distinct patterns were observed among hawkfishes, with higher abundance of all species recorded on reefs farther from shore and on wave exposed reef zones. <i>Cirrhitus spilotoceps</i> was only recorded on the exposed crest, but unlike the other species, did not associate with live coral colonies. Overall, the most abundant species was <i>P. forsteri. </i>This species exploited a variety of habitats but showed an affinity for complex habitats provided by live and dead coral colonies. No difference in habitat use was observed among the four colour morphs, but distinct patterns were apparent in distribution and abundance with depth. This study suggests that in addition to <i>P. forsteri</i> exhibiting diverse colour morphologies, these various morphotypes appear to have corresponding ecological differences in the Red Sea. To better understand this, further studies are needed to identify what these differences extend to and the mechanisms involved.
DOI: 10.6084/m9.figshare.4440002
title: Redundant Design and Adaptive Control of an Interleaved Continuum Rigid Manipulator

description: Continuum manipulator compliance enables operation in delicate environments at the cost of challenging actuation and control. In the case of catheter ablation of atrial fibrillation, the compliance of the continuum backbone lends an inherent safety to the device. This inherent safety frustrates attempts at precise, accurate, and fast control, limiting these devices to simple, static positioning tasks. This dissertation develops Interleaved Continuum-Rigid Manipulation, by which the hysteretic nonlinearities encountered in tendon-actuated continuum manipulators are compensated by discrete rigid joints located between continuum sections. The rigid joints introduce actuation redundancy, which an interleaved controller may use to avoid continuum nonlinearities and dynamic excitations, or to prefer particular configurations that may improve task accuracy, permit greater end-effector forces, or avoid environment obstacles. Two experimental systems explore the potential of these joints to 1) correct for actuation nonlinearities and enhance manipulator performance and 2) increase the manipulator’s dexterous workspace. These experiments expose important design and control observations that were not apparent in the general robotic and continuum literature.
DOI: 10.6084/m9.figshare.4439849
title: Supplementary Material for: AQP5 Variants Affect Tumoral Expression of AQP5 and Survival in Patients with Early Breast Cancer

description: <b><i>Background:</i></b> Our previous study showed the association of AQP5 upregulation with cancer proliferation and migration in breast cancer cell lines and with unfavorable prognosis in patients with early breast cancer (EBC). In the current study, we analyzed the association of<i> AQP5</i> variants or their haplotypes with AQP5 expression and their prognostic impact for survival in patients with EBC. <b><i>Methods:</i></b> Three <i>AQP5</i> polymorphisms (rs74091166, rs3736309, and rs1964676) were selected based on the SNP database and genotyped using the Sequenom MassARRAY in 374 out of 447 patients with EBC in whom AQP5 expression had been investigated in our previous study. <b><i>Results:</i></b> The allele frequencies of the selected variants in the current study were similar to those from Asian data previously reported. In a univariate analysis, both rs74091166 and rs1964676 were statistically associated with survival as a dominant model of minor allele. Moreover, a multivariate survival analysis revealed that the CC genotype of rs1964676 is an independent prognostic marker of survival in EBC patients, regardless of stage, tumor subtype, and adjuvant treatment [hazard ratio = 0.399, 0.384, and 0.205; <i>p</i> = 0.021, 0.027, and 0.016 for disease-free survival (DFS), distant DFS, and disease-specific survival, respectively]. In particular, the CT/TT genotype of rs1964676 showed an association with strong expression of AQP5 (58.6 vs. 26.0%; <i>p</i> = 0.001), without any associations with clinical or pathological characteristics including tumor subtype, stage, or histologic grade. <b><i>Conclusion:</i></b> The current study suggests <i>AQP5 </i>rs1964676 as a new potential prognostic marker in patients with EBC involved in AQP5 expression.
DOI: 10.6084/m9.figshare.4439849.v1
title: Supplementary Material for: AQP5 Variants Affect Tumoral Expression of AQP5 and Survival in Patients with Early Breast Cancer

description: <b><i>Background:</i></b> Our previous study showed the association of AQP5 upregulation with cancer proliferation and migration in breast cancer cell lines and with unfavorable prognosis in patients with early breast cancer (EBC). In the current study, we analyzed the association of<i> AQP5</i> variants or their haplotypes with AQP5 expression and their prognostic impact for survival in patients with EBC. <b><i>Methods:</i></b> Three <i>AQP5</i> polymorphisms (rs74091166, rs3736309, and rs1964676) were selected based on the SNP database and genotyped using the Sequenom MassARRAY in 374 out of 447 patients with EBC in whom AQP5 expression had been investigated in our previous study. <b><i>Results:</i></b> The allele frequencies of the selected variants in the current study were similar to those from Asian data previously reported. In a univariate analysis, both rs74091166 and rs1964676 were statistically associated with survival as a dominant model of minor allele. Moreover, a multivariate survival analysis revealed that the CC genotype of rs1964676 is an independent prognostic marker of survival in EBC patients, regardless of stage, tumor subtype, and adjuvant treatment [hazard ratio = 0.399, 0.384, and 0.205; <i>p</i> = 0.021, 0.027, and 0.016 for disease-free survival (DFS), distant DFS, and disease-specific survival, respectively]. In particular, the CT/TT genotype of rs1964676 showed an association with strong expression of AQP5 (58.6 vs. 26.0%; <i>p</i> = 0.001), without any associations with clinical or pathological characteristics including tumor subtype, stage, or histologic grade. <b><i>Conclusion:</i></b> The current study suggests <i>AQP5 </i>rs1964676 as a new potential prognostic marker in patients with EBC involved in AQP5 expression.
DOI: 10.5519/qd.5svbh4u3
title: Query on the Natural History Museum Data Portal (data.nhm.ac.uk) (4591806 records)
DOI: 10.6084/m9.figshare.4438274
title: Biochar metaanalysis dataset

description: This set includes those data used for the publication “Biederman LA, Harpole WS. 2013. Biochar and its effects on plant productivity and nutrient cycling: a meta-analysis. <i>Global Climate Change – Bioenergy</i> 5: 202-214”. The final analysis did NOT include those studies that used activated charcoal, but since we have those data they are included here. Similarly, other information was not used in our analysis, but is included here. Please feel free to contact me with questions. Lori Biederman (lbied@iastate.edu).<br>This excel file contains 4 spreadsheets. "Data key" contains the descriptions of columns in the remaining three. "Study information" contains the citation information for the studies used in the analysis. "Data" contains the main data used in the main analysis of biochar's effect on plant and soil. "Extra" contains information about the biochar or study sites that may contribute to the results. Again, not all of these data were used in the final publication, but since they were extracted from the studies we report them here.<br>
DOI: 10.5281/zenodo.4012717
title: Oxia Planum: THEMIS and CRISM Spectral and Visual Datasets

description: Imagery and data used for analysis for geological and thermal characterization of Oxia Planum seen in "Geologic and Thermal Characterization of Oxia Planum using Mars Odyssey THEMIS Data" (C.E. Gary-Bicas and A.D. Rogers). Amongst the datasets there are THEMIS (Thermal Emission Imaging System) image stamps "oxia_THEMIS_images.zip" which contains atmospherically corrected and geo-referenced emissivity cubes, CRISM (Compact Reconnaissance Imaging Spectrometer for Mars) image stamp frt00009a16_07_if166l_trr3 (includes atmospheric correction, de-striping, and projection steps). Regions of Interest (ROIs) correspond to analyzed locations to geologic units classified in manuscript (files ending with .roi). ROI files starting with the letter "I" are associated to THEMIS stamps."units.roi" is associated to CRISM stamp within these ROIs there is a denominator spectra for correction. ROI files can be opened with HARRIS ENVI. The ".txt" files are mean spectra output files from the ROIs with spectral data for both CRISM (9a16_.txt, these are ratioed spectra using denominator) and THEMIS (####.txt where the numbers are the last 4 digits of the Stamp ID). There are 2 mineral library files corresponding to spectral libraries for each instrument. "CRISMmin.txt" corresponds to CRISM library data and "comparison_lib_themisres.hdf" to THEMIS data. There are four THEMIS thermal inertia datasets extracted from a THEMIS thermal inertia stamp and divided by the different geologic units classified in paper (####_TI.csv). Lastly, we have two sets of shapefiles that can be imported into Geographic Information Systems like ESRI ArcMap or JMARS. These shapefiles correspond to geologically designated units in the aforementioned manuscript. The zip file titled "Unit Shape Files.zip" has the geologic units individual shape files and associated files as well as crater shape files. The one titled "Unit TI Shape Files.zip" has the shape files for all the classified units in a localized region where we conducted our thermal inertia analysis. Finally the file titled "Oxia Crater Count.zip" contains crater counting data for Kilkhampton crater located in the vicinity of Oxia Planum