DOI: 10.6073/pasta/5d42d1e8d981036ab617dfba08d4e071
title: Uranium mobility and accumulation along the Rio Paguate, Jackpile Mine in Laguna Pueblo, NM

description: The mobility and accumulation of uranium (U) along the Rio Paguate, adjacent to the Jackpile Mine, in Laguna Pueblo, New Mexico was investigated using aqueous chemistry, electron microprobe, X-ray diﬀraction and spectroscopy analyses. Given that it is not common to identify elevated concentrations of U in surface water sources, the Rio Paguate is a unique site that concerns the Laguna Pueblo community. This study aims to better understand the solid chemistry of abandoned mine waste sediments from the Jackpile Mine and identify key hydrogeological and geochemical processes that aﬀect the fate of U along the Rio Paguate. Solid analyses using X-ray ﬂuorescence determined that sediments located in the Jackpile Mine contain ranges of 320 to 9200 mg kg-1 U. The presence of coﬃnite, a U(IV)-bearing mineral, was identiﬁed by X-ray diﬀraction analyses in abandoned mine waste solids exposed to several decades of weathering and oxidation. The dissolution of these U-bearing minerals from abandoned mine wastes could contribute to U mobility during rain events. The U concentration in surface waters sampled closest to mine wastes are highest during the southwestern monsoon season. Samples collected from September 2014 to August 2016 showed higher U concentrations in surface water adjacent to the Jackpile Mine (35.3 to 772 mg L-1) compared with those at a wetland 4.5 kilometers downstream of the mine (5.77 to 110 mg L-1). Sediments co-located in the stream bed and bank along the reach between the mine and wetland had low U concentrations (range 1–5 mg kg-1) compared to concentrations in wetland sediments with higher organic matter (14–15%) and U concentrations (2–21 mg kg-1). Approximately 10% of the total U in wetland sediments was amenable to complexation with 1 mM sodium bicarbonate in batch experiments; a decrease of U concentration in solution was observed over time in these experiments likely due to re-association with sediments in the reactor. The ﬁndings from this study provide new insights about how hydrologic events may aﬀect the reactivity of U present in mine waste solids exposed to surface oxidizing conditions, and the inﬂuence of organic-rich sediments on U accumulation in the Rio Paguate. Environmental impact: Uranium mobility and accumulation in the environment can aﬀect surface water and sediment chemistry. Here, we investigated the mobility of uranium in water and accumulation on sediments along the Rio Paguate and within a wetland and reservoir 5 km south of the Jackpile Mine. Main findings of the study suggest that ore and mine waste from surficial locations of the Jackpile Mine are the source of uranium in the surface water. Additionally, the concentration of uranium in the Rio Paguate varies seasonally, with higher concentrations during the southwestern monsoon season. The uranium concentration in surface water decreases downstream of the mine and adsorption of uranium to organic-containing sediments in a wetland 5 km downstream contributes to this decrease. These results have important implications to better understand the mobility and accumulation of uranium in the environment.