DOI: 10.5281/zenodo.8296637
title: Data for SI-Hg D2 validation report for the calibration of elemental mercury gas generators including information on repeatability, reproducibility and uncertainty evaluation at emission and ambient levels extended to the sub ng/m3 level

description: In deliverable 2 of the SI-Hg project the first validation results of the SI-Hg calibration protocol are reported. Within the SI-Hg project a protocol for the metrological calibration of elemental mercury gas generators used in the field was developed. For the validation the output of two different mercury gas generators was calibrated according to the protocol. As metrological reference standard the primary mercury gas standard from the Van Swinden Laboratory (VSL) was used. The measurements described in the protocol could be performed during the validation and the data was processed using a script to determine the output of the candidate generator and the uncertainty of the mercury concentration. Based on the validation measurements and data processing several improvements for the calibration protocol were identified and were used to improve the calibration protocol. 
In this repository data obtained during the validation is published. The files of the following comparisons between reference generator and candidate generator can be found in this repository:

VSL vs VSL

m1

09022022 calibration mercury gas generator VSL vs VSL m1
VSL_vs_VSL_m1
m2 

05072022 calibration mercury gas generator VSL vs VSL m2
VSL_vs_VSL_m2
m3

07072022 calibration mercury gas generator VSL vs VSL m3
VSL_vs_VSL_m3
VSL vs PSA before modification

m1

15032022 calibration mercury gas generator VSL vs PSA fixed m1
single_point_VSL_vs_PSA_fixed_m1_4
single_point_VSL_vs_PSA_fixed_m1_6
single_point_VSL_vs_PSA_fixed_m1_8
single_point_VSL_vs_PSA_fixed_m1_12
m2

28032022 calibration mercury gas generator VSL vs PSA fixed m2
single_point_VSL_vs_PSA_fixed_m2_4
single_point_VSL_vs_PSA_fixed_m2_6
single_point_VSL_vs_PSA_fixed_m2_8
single_point_VSL_vs_PSA_fixed_m2_12
m3 

06042022 calibration mercury gas generator VSL vs PSA fixed m3
single_point_VSL_vs_PSA_fixed_m3_4
single_point_VSL_vs_PSA_fixed_m3_6
single_point_VSL_vs_PSA_fixed_m3_8
single_point_VSL_vs_PSA_fixed_m3_12
m4 

12042022 calibration mercury gas generator VSL vs PSA fixed m4
single_point_VSL_vs_PSA_fixed_m4_4
single_point_VSL_vs_PSA_fixed_m4_6
single_point_VSL_vs_PSA_fixed_m4_8
single_point_VSL_vs_PSA_fixed_m4_12
less tubing 

14042022 calibration mercury gas generator VSL vs PSA fixed less tubing
single_point_VSL_vs_PSA_fixed_less_tubing
less tubing and air as complementary gas 

19042022 calibration mercury gas generator VSL vs PSA fixed less tubing in air
single_point_VSL_vs_PSA_fixed_less_tubing_air
VSL vs PSA after modification

m1 air as complementary gas 

Calibration PSA fixed mercury gas generator air m1 20230324
PSA_fixed_air_m1_9
PSA_fixed_air_m1_11
PSA_fixed_air_m1_14
m2 air as complementary gas 

Calibration PSA fixed mercury gas generator air m2 20230327
PSA_fixed_air_m2_9
PSA_fixed_air_m2_11
PSA_fixed_air_m2_14
m3 air as complementary gas 

Calibration PSA fixed mercury gas generator air m3 20230329
PSA_fixed_air_m3_9
PSA_fixed_air_m3_11
PSA_fixed_air_m3_14
m4 air as complementary gas 

Calibration PSA fixed mercury gas generator air m4 20230907
PSA_fixed_air_m4_9
PSA_fixed_air_m4_11
PSA_fixed_air_m4_14
m5 air as complemantary gas 

Calibration PSA fixed mercury gas generator air m5 20230911
PSA_fixed_air_m5_9
PSA_fixed_air_m5_11
PSA_fixed_air_m5_14
m1 nitrogen (N2) as complementary gas

Calibration PSA fixed mercury gas generator nitrogen m1 20230330
PSA_fixed_N2_m1_9
PSA_fixed_N2_m1_11
PSA_fixed_N2_m1_14
m2 N2 as complementary gas 

Calibration PSA fixed mercury gas generator nitrogen m2 20230331
PSA_fixed_N2_m2_9
PSA_fixed_N2_m2_11
PSA_fixed_N2_m2_14
m3 N2 as complementary gas 

Calibration PSA fixed mercury gas generator nitrogen m3 20230405
PSA_fixed_N2_m3_9
PSA_fixed_N2_m3_11
PSA_fixed_N2_m3_14
measurement at TUV

PSA_Fixed_at_TUV