cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.6084/m9.figshare.30655193
title: Supplementary Material for: Case report: Successful treatment with tezepelumab for an adult with refractory and severe fibrostenotic eosinophilia esophagitis

description: Introduction: Non-response to treatment in eosinophilic esophagitis (EoE) is common, and the approach to treatment-refractory patients with EoE is challenging. With increasing knowledge of EoE pathogenesis, mechanisms can be targeted by medications that are approved for other atopic diseases with a similar pathophysiology.

Case presentation: We present an adult with EoE who had longstanding symptoms prior to diagnosis, developed severe fibrostenosis with the narrow caliber phenotype requiring multiple esophageal dilations, and was previously non-responsive to proton pump inhibitors (PPIs), topical corticosteroids (tCS), and food elimination diets (FED). Because of his concomitant severe asthma, he was treated with the eosinophil-depleting biologics mepolizumab and benralizumab. These reduced eosinophil counts on esophageal biopsy, but did not improve symptoms, endoscopic features, or other histologic findings. He continued to require esophageal dilation for symptom control. His asthma control also remained suboptimal, prompting a trial of tezepelumab, an antibody against thymic stromal lymphopoietin (TSLP). In addition to controlling asthma, he improved across EoE symptom, endoscopic, and histologic metrics over a year of follow-up, including improvements in the EoE Endoscopic Reference Score, esophageal caliber, and basal zone hyperplasia, dilated intercellular spaces, and lamina propria fibrosis as measured by the EoE Histologic Scoring System.

Conclusion: This patient, who did not respond to PPI, FED, tCS, mepolizumab, or benralizumab, ultimately had response to tezepelumab across multiple outcome domains of EoE. This demonstrates proof-of-concept that targeting TSLP may be a promising modality in EoE and supports further study of this mechanism for treatment of EoE.
DOI: 10.6084/m9.figshare.30655193.v1
title: Supplementary Material for: Case report: Successful treatment with tezepelumab for an adult with refractory and severe fibrostenotic eosinophilia esophagitis

description: Introduction: Non-response to treatment in eosinophilic esophagitis (EoE) is common, and the approach to treatment-refractory patients with EoE is challenging. With increasing knowledge of EoE pathogenesis, mechanisms can be targeted by medications that are approved for other atopic diseases with a similar pathophysiology.

Case presentation: We present an adult with EoE who had longstanding symptoms prior to diagnosis, developed severe fibrostenosis with the narrow caliber phenotype requiring multiple esophageal dilations, and was previously non-responsive to proton pump inhibitors (PPIs), topical corticosteroids (tCS), and food elimination diets (FED). Because of his concomitant severe asthma, he was treated with the eosinophil-depleting biologics mepolizumab and benralizumab. These reduced eosinophil counts on esophageal biopsy, but did not improve symptoms, endoscopic features, or other histologic findings. He continued to require esophageal dilation for symptom control. His asthma control also remained suboptimal, prompting a trial of tezepelumab, an antibody against thymic stromal lymphopoietin (TSLP). In addition to controlling asthma, he improved across EoE symptom, endoscopic, and histologic metrics over a year of follow-up, including improvements in the EoE Endoscopic Reference Score, esophageal caliber, and basal zone hyperplasia, dilated intercellular spaces, and lamina propria fibrosis as measured by the EoE Histologic Scoring System.

Conclusion: This patient, who did not respond to PPI, FED, tCS, mepolizumab, or benralizumab, ultimately had response to tezepelumab across multiple outcome domains of EoE. This demonstrates proof-of-concept that targeting TSLP may be a promising modality in EoE and supports further study of this mechanism for treatment of EoE.
DOI: 10.15468/dl.6sp97u
title: Occurrence Download

description: A dataset containing 9 species occurrences available in GBIF matching the query:
{
 "and" : [
 "Country is Mexico",
 "HasCoordinate is true",
 "HasGeospatialIssue is false",
 "OccurrenceStatus is Present",
 "TaxonKey is Erythroxylon"
 ]
}

 The dataset includes 9 records from 2 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0044320-251025141854904/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.jgxmjx
title: Occurrence Download

description: A dataset containing 19316 species occurrences available in GBIF matching the query:
{
 "and" : [
 "TaxonKey is Silphium perfoliatum",
 "HasCoordinate is true"
 ]
}

 The dataset includes 19316 records from 153 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0044322-251025141854904/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.qvd92u
title: Occurrence Download

description: A dataset containing 167 species occurrences available in GBIF matching the query:
{
 "and" : [
 "Country is Australia",
 "TaxonKey is Banksia solandri"
 ]
}

 The dataset includes 167 records from 23 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0044323-251025141854904/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.14272/dtkujipuihqojn-uhfffaoysa-m.1
title: sodium 3-methylsulfanylpropane-1-sulfonate
title: InChI=1S/C4H10O3S2.Na/c1-8-3-2-4-9(5,6)7;/h2-4H2,1H3,(H,5,6,7);/q;+1/p-1

description: This is a physical chemical entity[CHEBI_24431] associated with a molecule[CHEBI_25367].
 The molecule[CHEBI_25367] can be described by the following structural desciptors[cheminf_000085]:
 InChI descriptor[cheminf_000113]: InChI=1S/C4H10O3S2.Na/c1-8-3-2-4-9(5,6)7;/h2-4H2,1H3,(H,5,6,7);/q;+1/p-1, and canonical SMILES descriptor[cheminf_000007]: CSCCCS(=O)(=O)[O-].[Na+], and by the IUPAC name[cheminf_000107]: sodium 3-methylsulfanylpropane-1-sulfonate.
 
 The physical chemical entity[CHEBI_24431] has a component solvent[CHEBI_46787] which is described by the canonical SMILES descriptor[cheminf_000007]:
 
 CC(O)=O
 
 The physical chemical entity[CHEBI_24431] has the following Sample ID as registered in the research data repository chemotion (www.chemotion-repository.net, https://doi.org/10.25504/FAIRsharing.iagXcR): CRS-58771

 The physical chemical entity[CHEBI_24431] can be described by the physical descriptors [CHEMINF_000025]:
 Melting point descriptor[CHEMINF_000256]: 
 Boiling point descriptor[CHEMINF_000257]: 
 Refractive index descriptor[CHEMINF_000253]:

 The physical chemical entity[CHEBI_24431] can be further described by the following assays[OBI:0000070][CHMO:0001133]:
 
 CHMO:0000595 | 13C nuclear magnetic resonance spectroscopy (13C NMR)
 
 CHMO:0000596 | distortionless enhancement with polarization transfer (DEPT)
 
 CHMO:0001146 | 1H--13C heteronuclear single quantum coherence (1H-13C HSQC)
 
 CHMO:0000593 | 1H nuclear magnetic resonance spectroscopy (1H NMR)
 
 CHMO:0001150 | 1H--1H correlation spectroscopy (1H-1H COSY)
 
 CHMO:0001148 | 1H--13C heteronuclear multiple bond coherence (13C-1H HMBC)
 
 CHMO:0000596 | distortionless enhancement with polarization transfer (DEPT)
 
 The physical chemical entity[CHEBI_24431] was deposited to the Molecule Archive of the Karlsruhe Insitute of Technology (KIT) with the following Sample ID: 

 Used ontologies:
 CHEBI - Chemical Entities of Biological Interest
 CHEMINF - chemical information ontology (information entities about chemical entities)
 CHMO - Chemical Methods Ontology
 OBI - Ontology for Biomedical Investigations
DOI: 10.14272/dtkujipuihqojn-uhfffaoysa-m/chmo0001146
title: 1H--13C heteronuclear single quantum coherence (1H-13C HSQC) (sodium 3-methylsulfanylpropane-1-sulfonate)
title: InChI=1S/C4H10O3S2.Na/c1-8-3-2-4-9(5,6)7;/h2-4H2,1H3,(H,5,6,7);/q;+1/p-1

description: dataset for 1H--13C heteronuclear single quantum coherence (1H-13C HSQC)
DOI: 10.14272/dtkujipuihqojn-uhfffaoysa-m/chmo0001150
title: 1H--1H correlation spectroscopy (1H-1H COSY) (sodium 3-methylsulfanylpropane-1-sulfonate)
title: InChI=1S/C4H10O3S2.Na/c1-8-3-2-4-9(5,6)7;/h2-4H2,1H3,(H,5,6,7);/q;+1/p-1

description: dataset for 1H--1H correlation spectroscopy (1H-1H COSY)
DOI: 10.14272/dtkujipuihqojn-uhfffaoysa-m/chmo0000596.1
title: distortionless enhancement with polarization transfer (DEPT) (sodium 3-methylsulfanylpropane-1-sulfonate)
title: InChI=1S/C4H10O3S2.Na/c1-8-3-2-4-9(5,6)7;/h2-4H2,1H3,(H,5,6,7);/q;+1/p-1

description: dataset for distortionless enhancement with polarization transfer (DEPT)
DOI: 10.14272/dtkujipuihqojn-uhfffaoysa-m/chmo0001148
title: 1H--13C heteronuclear multiple bond coherence (13C-1H HMBC) (sodium 3-methylsulfanylpropane-1-sulfonate)
title: InChI=1S/C4H10O3S2.Na/c1-8-3-2-4-9(5,6)7;/h2-4H2,1H3,(H,5,6,7);/q;+1/p-1

description: dataset for 1H--13C heteronuclear multiple bond coherence (13C-1H HMBC)
DOI: 10.14272/dtkujipuihqojn-uhfffaoysa-m/chmo0000595
title: 13C nuclear magnetic resonance spectroscopy (13C NMR) (sodium 3-methylsulfanylpropane-1-sulfonate)
title: InChI=1S/C4H10O3S2.Na/c1-8-3-2-4-9(5,6)7;/h2-4H2,1H3,(H,5,6,7);/q;+1/p-1

description: dataset for 13C nuclear magnetic resonance spectroscopy (13C NMR)
DOI: 10.14272/dtkujipuihqojn-uhfffaoysa-m/chmo0000596
title: distortionless enhancement with polarization transfer (DEPT) (sodium 3-methylsulfanylpropane-1-sulfonate)
title: InChI=1S/C4H10O3S2.Na/c1-8-3-2-4-9(5,6)7;/h2-4H2,1H3,(H,5,6,7);/q;+1/p-1

description: dataset for distortionless enhancement with polarization transfer (DEPT)
DOI: 10.14272/dtkujipuihqojn-uhfffaoysa-m/chmo0000593
title: 1H nuclear magnetic resonance spectroscopy (1H NMR) (sodium 3-methylsulfanylpropane-1-sulfonate)
title: InChI=1S/C4H10O3S2.Na/c1-8-3-2-4-9(5,6)7;/h2-4H2,1H3,(H,5,6,7);/q;+1/p-1

description: dataset for 1H nuclear magnetic resonance spectroscopy (1H NMR)
DOI: 10.14272/diypglyfqdsxqr-uhfffaoysa-n.1
title: 2-[[5-[14-[5-(2,2-dicyanoethenyl)thiophen-2-yl]-3,17-di(heptadecan-9-yl)-7,10,13lambda4-trithia-3,17-diazapentacyclo[9.6.0.02,9.04,8.012,16]heptadeca-1(11),2(9),4(8),5,12,13,15-heptaen-6-yl]thiophen-2-yl]methylidene]propanedinitrile
title: InChI=1S/C62H78N6S5/c1-5-9-13-17-21-25-29-47(30-26-22-18-14-10-6-2)67-51-39-55(53-35-33-49(69-53)37-45(41-63)42-64)71-59(51)61-57(67)58-62(73-61)60-52(40-56(72-60)54-36-34-50(70-54)38-46(43-65)44-66)68(58)48(31-27-23-19-15-11-7-3)32-28-24-20-16-12-8-4/h33-40,47-48H,5-32H2,1-4H3

description: This is a physical chemical entity[CHEBI_24431] associated with a molecule[CHEBI_25367].
 The molecule[CHEBI_25367] can be described by the following structural desciptors[cheminf_000085]:
 InChI descriptor[cheminf_000113]: InChI=1S/C62H78N6S5/c1-5-9-13-17-21-25-29-47(30-26-22-18-14-10-6-2)67-51-39-55(53-35-33-49(69-53)37-45(41-63)42-64)71-59(51)61-57(67)58-62(73-61)60-52(40-56(72-60)54-36-34-50(70-54)38-46(43-65)44-66)68(58)48(31-27-23-19-15-11-7-3)32-28-24-20-16-12-8-4/h33-40,47-48H,5-32H2,1-4H3, and canonical SMILES descriptor[cheminf_000007]: CCCCCCCCC(n1c2cc(sc2c2c1c1c(s2)c2c(n1C(CCCCCCCC)CCCCCCCC)cc(s2)c1ccc(s1)C=C(C#N)C#N)c1ccc(s1)C=C(C#N)C#N)CCCCCCCC, and by the IUPAC name[cheminf_000107]: 2-[[5-[14-[5-(2,2-dicyanoethenyl)thiophen-2-yl]-3,17-di(heptadecan-9-yl)-7,10,13lambda4-trithia-3,17-diazapentacyclo[9.6.0.02,9.04,8.012,16]heptadeca-1(11),2(9),4(8),5,12,13,15-heptaen-6-yl]thiophen-2-yl]methylidene]propanedinitrile.
 
 The physical chemical entity[CHEBI_24431] has a component solvent[CHEBI_46787] which is described by the canonical SMILES descriptor[cheminf_000007]:
 
 CC(O)=O
 
 The physical chemical entity[CHEBI_24431] has the following Sample ID as registered in the research data repository chemotion (www.chemotion-repository.net, https://doi.org/10.25504/FAIRsharing.iagXcR): CRS-58779

 The physical chemical entity[CHEBI_24431] can be described by the physical descriptors [CHEMINF_000025]:
 Melting point descriptor[CHEMINF_000256]: 
 Boiling point descriptor[CHEMINF_000257]: 
 Refractive index descriptor[CHEMINF_000253]:

 The physical chemical entity[CHEBI_24431] can be further described by the following assays[OBI:0000070][CHMO:0001133]:
 
 CHMO:0000596 | distortionless enhancement with polarization transfer (DEPT)
 
 CHMO:0000596 | distortionless enhancement with polarization transfer (DEPT)
 
 CHMO:0000595 | 13C nuclear magnetic resonance spectroscopy (13C NMR)
 
 CHMO:0001148 | 1H--13C heteronuclear multiple bond coherence (13C-1H HMBC)
 
 CHMO:0001150 | 1H--1H correlation spectroscopy (1H-1H COSY)
 
 CHMO:0001146 | 1H--13C heteronuclear single quantum coherence (1H-13C HSQC)
 
 CHMO:0000593 | 1H nuclear magnetic resonance spectroscopy (1H NMR)
 
 The physical chemical entity[CHEBI_24431] was deposited to the Molecule Archive of the Karlsruhe Insitute of Technology (KIT) with the following Sample ID: 

 Used ontologies:
 CHEBI - Chemical Entities of Biological Interest
 CHEMINF - chemical information ontology (information entities about chemical entities)
 CHMO - Chemical Methods Ontology
 OBI - Ontology for Biomedical Investigations
DOI: 10.14272/diypglyfqdsxqr-uhfffaoysa-n/chmo0000595
title: 13C nuclear magnetic resonance spectroscopy (13C NMR) (2-[[5-[14-[5-(2,2-dicyanoethenyl)thiophen-2-yl]-3,17-di(heptadecan-9-yl)-7,10,13lambda4-trithia-3,17-diazapentacyclo[9.6.0.02,9.04,8.012,16]heptadeca-1(11),2(9),4(8),5,12,13,15-heptaen-6-yl]thiophen-2-yl]methylidene]propanedinitrile)
title: InChI=1S/C62H78N6S5/c1-5-9-13-17-21-25-29-47(30-26-22-18-14-10-6-2)67-51-39-55(53-35-33-49(69-53)37-45(41-63)42-64)71-59(51)61-57(67)58-62(73-61)60-52(40-56(72-60)54-36-34-50(70-54)38-46(43-65)44-66)68(58)48(31-27-23-19-15-11-7-3)32-28-24-20-16-12-8-4/h33-40,47-48H,5-32H2,1-4H3

description: dataset for 13C nuclear magnetic resonance spectroscopy (13C NMR)
DOI: 10.14272/diypglyfqdsxqr-uhfffaoysa-n/chmo0000596.1
title: distortionless enhancement with polarization transfer (DEPT) (2-[[5-[14-[5-(2,2-dicyanoethenyl)thiophen-2-yl]-3,17-di(heptadecan-9-yl)-7,10,13lambda4-trithia-3,17-diazapentacyclo[9.6.0.02,9.04,8.012,16]heptadeca-1(11),2(9),4(8),5,12,13,15-heptaen-6-yl]thiophen-2-yl]methylidene]propanedinitrile)
title: InChI=1S/C62H78N6S5/c1-5-9-13-17-21-25-29-47(30-26-22-18-14-10-6-2)67-51-39-55(53-35-33-49(69-53)37-45(41-63)42-64)71-59(51)61-57(67)58-62(73-61)60-52(40-56(72-60)54-36-34-50(70-54)38-46(43-65)44-66)68(58)48(31-27-23-19-15-11-7-3)32-28-24-20-16-12-8-4/h33-40,47-48H,5-32H2,1-4H3

description: dataset for distortionless enhancement with polarization transfer (DEPT)
DOI: 10.14272/diypglyfqdsxqr-uhfffaoysa-n/chmo0000596
title: distortionless enhancement with polarization transfer (DEPT) (2-[[5-[14-[5-(2,2-dicyanoethenyl)thiophen-2-yl]-3,17-di(heptadecan-9-yl)-7,10,13lambda4-trithia-3,17-diazapentacyclo[9.6.0.02,9.04,8.012,16]heptadeca-1(11),2(9),4(8),5,12,13,15-heptaen-6-yl]thiophen-2-yl]methylidene]propanedinitrile)
title: InChI=1S/C62H78N6S5/c1-5-9-13-17-21-25-29-47(30-26-22-18-14-10-6-2)67-51-39-55(53-35-33-49(69-53)37-45(41-63)42-64)71-59(51)61-57(67)58-62(73-61)60-52(40-56(72-60)54-36-34-50(70-54)38-46(43-65)44-66)68(58)48(31-27-23-19-15-11-7-3)32-28-24-20-16-12-8-4/h33-40,47-48H,5-32H2,1-4H3

description: dataset for distortionless enhancement with polarization transfer (DEPT)
DOI: 10.14272/diypglyfqdsxqr-uhfffaoysa-n/chmo0000593
title: 1H nuclear magnetic resonance spectroscopy (1H NMR) (2-[[5-[14-[5-(2,2-dicyanoethenyl)thiophen-2-yl]-3,17-di(heptadecan-9-yl)-7,10,13lambda4-trithia-3,17-diazapentacyclo[9.6.0.02,9.04,8.012,16]heptadeca-1(11),2(9),4(8),5,12,13,15-heptaen-6-yl]thiophen-2-yl]methylidene]propanedinitrile)
title: InChI=1S/C62H78N6S5/c1-5-9-13-17-21-25-29-47(30-26-22-18-14-10-6-2)67-51-39-55(53-35-33-49(69-53)37-45(41-63)42-64)71-59(51)61-57(67)58-62(73-61)60-52(40-56(72-60)54-36-34-50(70-54)38-46(43-65)44-66)68(58)48(31-27-23-19-15-11-7-3)32-28-24-20-16-12-8-4/h33-40,47-48H,5-32H2,1-4H3

description: dataset for 1H nuclear magnetic resonance spectroscopy (1H NMR)
DOI: 10.14272/diypglyfqdsxqr-uhfffaoysa-n/chmo0001148
title: 1H--13C heteronuclear multiple bond coherence (13C-1H HMBC) (2-[[5-[14-[5-(2,2-dicyanoethenyl)thiophen-2-yl]-3,17-di(heptadecan-9-yl)-7,10,13lambda4-trithia-3,17-diazapentacyclo[9.6.0.02,9.04,8.012,16]heptadeca-1(11),2(9),4(8),5,12,13,15-heptaen-6-yl]thiophen-2-yl]methylidene]propanedinitrile)
title: InChI=1S/C62H78N6S5/c1-5-9-13-17-21-25-29-47(30-26-22-18-14-10-6-2)67-51-39-55(53-35-33-49(69-53)37-45(41-63)42-64)71-59(51)61-57(67)58-62(73-61)60-52(40-56(72-60)54-36-34-50(70-54)38-46(43-65)44-66)68(58)48(31-27-23-19-15-11-7-3)32-28-24-20-16-12-8-4/h33-40,47-48H,5-32H2,1-4H3

description: dataset for 1H--13C heteronuclear multiple bond coherence (13C-1H HMBC)
DOI: 10.14272/diypglyfqdsxqr-uhfffaoysa-n/chmo0001146
title: 1H--13C heteronuclear single quantum coherence (1H-13C HSQC) (2-[[5-[14-[5-(2,2-dicyanoethenyl)thiophen-2-yl]-3,17-di(heptadecan-9-yl)-7,10,13lambda4-trithia-3,17-diazapentacyclo[9.6.0.02,9.04,8.012,16]heptadeca-1(11),2(9),4(8),5,12,13,15-heptaen-6-yl]thiophen-2-yl]methylidene]propanedinitrile)
title: InChI=1S/C62H78N6S5/c1-5-9-13-17-21-25-29-47(30-26-22-18-14-10-6-2)67-51-39-55(53-35-33-49(69-53)37-45(41-63)42-64)71-59(51)61-57(67)58-62(73-61)60-52(40-56(72-60)54-36-34-50(70-54)38-46(43-65)44-66)68(58)48(31-27-23-19-15-11-7-3)32-28-24-20-16-12-8-4/h33-40,47-48H,5-32H2,1-4H3

description: dataset for 1H--13C heteronuclear single quantum coherence (1H-13C HSQC)
DOI: 10.14272/diypglyfqdsxqr-uhfffaoysa-n/chmo0001150
title: 1H--1H correlation spectroscopy (1H-1H COSY) (2-[[5-[14-[5-(2,2-dicyanoethenyl)thiophen-2-yl]-3,17-di(heptadecan-9-yl)-7,10,13lambda4-trithia-3,17-diazapentacyclo[9.6.0.02,9.04,8.012,16]heptadeca-1(11),2(9),4(8),5,12,13,15-heptaen-6-yl]thiophen-2-yl]methylidene]propanedinitrile)
title: InChI=1S/C62H78N6S5/c1-5-9-13-17-21-25-29-47(30-26-22-18-14-10-6-2)67-51-39-55(53-35-33-49(69-53)37-45(41-63)42-64)71-59(51)61-57(67)58-62(73-61)60-52(40-56(72-60)54-36-34-50(70-54)38-46(43-65)44-66)68(58)48(31-27-23-19-15-11-7-3)32-28-24-20-16-12-8-4/h33-40,47-48H,5-32H2,1-4H3

description: dataset for 1H--1H correlation spectroscopy (1H-1H COSY)
DOI: 10.15468/dl.x8ec5s
title: Occurrence Download

description: A dataset containing 216676 species occurrences available in GBIF matching the query:
{
 "TaxonKey" : [
 "is Canis lupus"
 ]
}

 The dataset includes 216676 records from 779 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0044263-251025141854904/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.14272/gyzqzkrfmrajka-uhfffaoysa-n/chmo0000596
title: distortionless enhancement with polarization transfer (DEPT) (2-[3,4-dibutyl-5-[5-[3,4-dibutyl-5-[9-[3,4-dibutyl-5-[5-[3,4-dibutyl-5-(2-trimethylsilylethynyl)thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]-1,10-phenanthrolin-2-yl]thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]ethynyl-trimethylsilane)
title: InChI=1S/C78H100N2S6Si2/c1-15-23-31-55-57(33-25-17-3)75(83-65(55)49-51-87(9,10)11)67-45-47-69(81-67)77-61(37-29-21-7)59(35-27-19-5)73(85-77)63-43-41-53-39-40-54-42-44-64(80-72(54)71(53)79-63)74-60(36-28-20-6)62(38-30-22-8)78(86-74)70-48-46-68(82-70)76-58(34-26-18-4)56(32-24-16-2)66(84-76)50-52-88(12,13)14/h39-48H,15-38H2,1-14H3

description: dataset for distortionless enhancement with polarization transfer (DEPT)
DOI: 10.14272/gyzqzkrfmrajka-uhfffaoysa-n/chmo0001148
title: 1H--13C heteronuclear multiple bond coherence (13C-1H HMBC) (2-[3,4-dibutyl-5-[5-[3,4-dibutyl-5-[9-[3,4-dibutyl-5-[5-[3,4-dibutyl-5-(2-trimethylsilylethynyl)thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]-1,10-phenanthrolin-2-yl]thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]ethynyl-trimethylsilane)
title: InChI=1S/C78H100N2S6Si2/c1-15-23-31-55-57(33-25-17-3)75(83-65(55)49-51-87(9,10)11)67-45-47-69(81-67)77-61(37-29-21-7)59(35-27-19-5)73(85-77)63-43-41-53-39-40-54-42-44-64(80-72(54)71(53)79-63)74-60(36-28-20-6)62(38-30-22-8)78(86-74)70-48-46-68(82-70)76-58(34-26-18-4)56(32-24-16-2)66(84-76)50-52-88(12,13)14/h39-48H,15-38H2,1-14H3

description: dataset for 1H--13C heteronuclear multiple bond coherence (13C-1H HMBC)
DOI: 10.15468/dl.edgnxh
title: Occurrence Download

description: A dataset containing 239 species occurrences available in GBIF matching the query:
{
 "Geometry" : [
 "POLYGON ((-110.8188 26.54913, -110.6688 26.54913, -110.6688 26.69913, -110.8188 26.69913, -110.8188 26.54913))"
 ]
}

 The dataset includes 239 records from 9 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0044324-251025141854904/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.14272/gyzqzkrfmrajka-uhfffaoysa-n/chmo0000595
title: 13C nuclear magnetic resonance spectroscopy (13C NMR) (2-[3,4-dibutyl-5-[5-[3,4-dibutyl-5-[9-[3,4-dibutyl-5-[5-[3,4-dibutyl-5-(2-trimethylsilylethynyl)thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]-1,10-phenanthrolin-2-yl]thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]ethynyl-trimethylsilane)
title: InChI=1S/C78H100N2S6Si2/c1-15-23-31-55-57(33-25-17-3)75(83-65(55)49-51-87(9,10)11)67-45-47-69(81-67)77-61(37-29-21-7)59(35-27-19-5)73(85-77)63-43-41-53-39-40-54-42-44-64(80-72(54)71(53)79-63)74-60(36-28-20-6)62(38-30-22-8)78(86-74)70-48-46-68(82-70)76-58(34-26-18-4)56(32-24-16-2)66(84-76)50-52-88(12,13)14/h39-48H,15-38H2,1-14H3

description: dataset for 13C nuclear magnetic resonance spectroscopy (13C NMR)
DOI: 10.14272/gyzqzkrfmrajka-uhfffaoysa-n/chmo0000596.1
title: distortionless enhancement with polarization transfer (DEPT) (2-[3,4-dibutyl-5-[5-[3,4-dibutyl-5-[9-[3,4-dibutyl-5-[5-[3,4-dibutyl-5-(2-trimethylsilylethynyl)thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]-1,10-phenanthrolin-2-yl]thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]ethynyl-trimethylsilane)
title: InChI=1S/C78H100N2S6Si2/c1-15-23-31-55-57(33-25-17-3)75(83-65(55)49-51-87(9,10)11)67-45-47-69(81-67)77-61(37-29-21-7)59(35-27-19-5)73(85-77)63-43-41-53-39-40-54-42-44-64(80-72(54)71(53)79-63)74-60(36-28-20-6)62(38-30-22-8)78(86-74)70-48-46-68(82-70)76-58(34-26-18-4)56(32-24-16-2)66(84-76)50-52-88(12,13)14/h39-48H,15-38H2,1-14H3

description: dataset for distortionless enhancement with polarization transfer (DEPT)
DOI: 10.14272/gyzqzkrfmrajka-uhfffaoysa-n/chmo0000593
title: 1H nuclear magnetic resonance spectroscopy (1H NMR) (2-[3,4-dibutyl-5-[5-[3,4-dibutyl-5-[9-[3,4-dibutyl-5-[5-[3,4-dibutyl-5-(2-trimethylsilylethynyl)thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]-1,10-phenanthrolin-2-yl]thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]ethynyl-trimethylsilane)
title: InChI=1S/C78H100N2S6Si2/c1-15-23-31-55-57(33-25-17-3)75(83-65(55)49-51-87(9,10)11)67-45-47-69(81-67)77-61(37-29-21-7)59(35-27-19-5)73(85-77)63-43-41-53-39-40-54-42-44-64(80-72(54)71(53)79-63)74-60(36-28-20-6)62(38-30-22-8)78(86-74)70-48-46-68(82-70)76-58(34-26-18-4)56(32-24-16-2)66(84-76)50-52-88(12,13)14/h39-48H,15-38H2,1-14H3

description: dataset for 1H nuclear magnetic resonance spectroscopy (1H NMR)
DOI: 10.14272/gyzqzkrfmrajka-uhfffaoysa-n/chmo0001146
title: 1H--13C heteronuclear single quantum coherence (1H-13C HSQC) (2-[3,4-dibutyl-5-[5-[3,4-dibutyl-5-[9-[3,4-dibutyl-5-[5-[3,4-dibutyl-5-(2-trimethylsilylethynyl)thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]-1,10-phenanthrolin-2-yl]thiophen-2-yl]thiophen-2-yl]thiophen-2-yl]ethynyl-trimethylsilane)
title: InChI=1S/C78H100N2S6Si2/c1-15-23-31-55-57(33-25-17-3)75(83-65(55)49-51-87(9,10)11)67-45-47-69(81-67)77-61(37-29-21-7)59(35-27-19-5)73(85-77)63-43-41-53-39-40-54-42-44-64(80-72(54)71(53)79-63)74-60(36-28-20-6)62(38-30-22-8)78(86-74)70-48-46-68(82-70)76-58(34-26-18-4)56(32-24-16-2)66(84-76)50-52-88(12,13)14/h39-48H,15-38H2,1-14H3

description: dataset for 1H--13C heteronuclear single quantum coherence (1H-13C HSQC)