cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.6084/m9.figshare.6693317.v1
title: Chitosan/NaF Particles Prepared Via Ionotropic Gelation: Evaluation of Particles Size and Morphology

description: The aim of this work was to perform an analysis of the influence of Sodium Fluoride (NaF) on chitosan particles size and morphology produced via ionotropic gelation with higher rotational stirring speed. Samples were characterized by Fourier Transform Infrared Spectroscopy (FTIR), Dynamic Light Scattering (DLS), Zeta Potential (ζ), Scanning Electron Microscopy and Energy Dispersive Spectroscopy (SEM/EDS). Chitosan/TPP particles diameter obtained was in the order of 3.8 µm. When NaF was added in different concentration (0.05%, 0.2% and 2%), the particle size diameter values, Zeta Potential and Poly Dispersive Index measures consequently decreased. Even so, no further modification in morphology was found. An exception was made for the samples with higher NaF concentration. After 21 days, occurred an increase in the particle size diameter. In the future, the proposed methodology could provide a dentistry application, especially on delivering particles of NaF.
DOI: 10.6084/m9.figshare.6832439
title: Fracture Behavior and Fatigue Performance of Inconel 625

description: Inconel 625 is a nickel-based highly-resistant superalloy widely used in aerospace components, in the nuclear industry, and especially in the maritime industry. Materials such as Inconel 625 have been widely used in oil exploration of Brazilian pre-salt layers due to their excellent resistance to corrosion under tension, pitting and crevice corrosion by chloride and sulphide ions, and also because they are resistant to microbiological corrosion. All components used in the exploration of crude oil in these environments suffer mechanical fatigue from oceanic oscillations that naturally occur. Samples were precisely machined and tested under uniaxial tension and cyclic tension-compression fatigue following determinations of the ASTM E8M and ASTM E466 standards respectively, at a loading ratio of R = -1. Tensile strengths of 586, 472, 382 and 306 MPa were selected according to the yield strength of the material for raising the S-N curve. A macro and microstructural characterization regarding failure modes was performed revealing that fatigue striations predominated in the stable region of crack growth, whereas microvoids coalescence prevailed in the fast fracture zone. Inconel 625 presented a refined microstructure composed of equiaxial grains with a mean size of 14 µm, typical of refining obtained by hardening followed by recrystallization. The precipitation of MC type carbides (M=Mo or M=Nb) and Cr23C6 dispersed in the austenitic matrix of Inconel 625 controls a secondary alloy hardening mechanism.
DOI: 10.6084/m9.figshare.6832433
title: Measurement of Residual Stresses in Welded Joints by DCP Method

description: Residual stresses on welded joints have been studied by several methods. In this present work, residual stresses was measured by a novel methodology under development named Displacement of Coordinated Points (DCP). To evaluate anisotropy effects in steel plates, two directions of the weld bead were considered: Welding was performed in both parallel and transversal direction of rolled steel plate ASTM A131 grade AH36.The experiments showed higher values of the residual stress in the transversal direction of the lamination when compared with the longitudinal direction, evidencing the anisotropy effect of the material. It was also observed that the increasing in heat input induces higher residual stress.
DOI: 10.6084/m9.figshare.6832433.v1
title: Measurement of Residual Stresses in Welded Joints by DCP Method

description: Residual stresses on welded joints have been studied by several methods. In this present work, residual stresses was measured by a novel methodology under development named Displacement of Coordinated Points (DCP). To evaluate anisotropy effects in steel plates, two directions of the weld bead were considered: Welding was performed in both parallel and transversal direction of rolled steel plate ASTM A131 grade AH36.The experiments showed higher values of the residual stress in the transversal direction of the lamination when compared with the longitudinal direction, evidencing the anisotropy effect of the material. It was also observed that the increasing in heat input induces higher residual stress.
DOI: 10.6084/m9.figshare.20020733.v1
title: Kinetic and Thermodynamic Study in Pozzolanic Chemical Systems as an Alternative for Chapelle Test

description: Important properties in cementitious materials, such as concrete, are related to the presence of additives that influence the rigidity and the physical and chemical resistances. For the evaluation of the additive effectiveness, known as pozzolanic activity, a simple procedure, the Chapelle test, is commonly used, and it essentially consists in a reaction between the additive with calcium oxide in aqueous medium. However, such procedure presents limitations in terms of processing time and lack of information regarding the reactions kinetics. In this sense, a simple method based on the kinetic and thermodynamic principles of chemical reactions is proposed, which can be performed using conventional electronic pH sensors. The study provides an alternative methodology with many advantages over the traditional procedure, such as energy and time-savings, more robustness and more confidence. In this paper, three types of silica nanoparticles that can be used as low-cost additives were characterized in relation to their morphology and crystallinity by XRD and SEM, the particles average diameters were obtained and the particles were used for studying the chemical process that takes place during the Chapelle test. Results and the semi-empirical analysis provided strong evidence that the process is an acid-base 1:1 reaction and it was verified that the mean reaction times varied from 64 to 195 min. It is a remarkable result, since the proposed analysis can be performed with simple, fast and low-cost instrumentation and needs only a worksheet software, whereas the Chapelle test takes 16 hours and provides no dynamic information. Besides the limitation that the methodology is not able to quantify and to elucidate the effects of the specific surface area of the particles, which needs a complete BET study, the research provides a significant contribution for the understanding of the pozzolanic process, of great importance in both concrete and ceramic research.
DOI: 10.6084/m9.figshare.20020733
title: Kinetic and Thermodynamic Study in Pozzolanic Chemical Systems as an Alternative for Chapelle Test

description: Important properties in cementitious materials, such as concrete, are related to the presence of additives that influence the rigidity and the physical and chemical resistances. For the evaluation of the additive effectiveness, known as pozzolanic activity, a simple procedure, the Chapelle test, is commonly used, and it essentially consists in a reaction between the additive with calcium oxide in aqueous medium. However, such procedure presents limitations in terms of processing time and lack of information regarding the reactions kinetics. In this sense, a simple method based on the kinetic and thermodynamic principles of chemical reactions is proposed, which can be performed using conventional electronic pH sensors. The study provides an alternative methodology with many advantages over the traditional procedure, such as energy and time-savings, more robustness and more confidence. In this paper, three types of silica nanoparticles that can be used as low-cost additives were characterized in relation to their morphology and crystallinity by XRD and SEM, the particles average diameters were obtained and the particles were used for studying the chemical process that takes place during the Chapelle test. Results and the semi-empirical analysis provided strong evidence that the process is an acid-base 1:1 reaction and it was verified that the mean reaction times varied from 64 to 195 min. It is a remarkable result, since the proposed analysis can be performed with simple, fast and low-cost instrumentation and needs only a worksheet software, whereas the Chapelle test takes 16 hours and provides no dynamic information. Besides the limitation that the methodology is not able to quantify and to elucidate the effects of the specific surface area of the particles, which needs a complete BET study, the research provides a significant contribution for the understanding of the pozzolanic process, of great importance in both concrete and ceramic research.
DOI: 10.6084/m9.figshare.20020739
title: The Effectiveness of Back Pressure in Superplastic Blow Forming of Aluminum Alloy AA 5083 Performed at Very Favorable Conditions for Cavitation Growth

description: Many components for aerospace and automotive industries are currently manufactured using superplastic forming, being the fine-grained aluminum alloy AA5083 widely used for this proposes. However, the development of cavitation voids is inherent in this process and reduces the ductility of the alloy. Back pressure can be used to diminish the growth of cavitation void. The experimental conditions used in this work are in the best condition for nucleation and grow of cavitation, because of the coarse grain size (81 µm), large second phase particles (9 µm) and elevated test temperature (570ºC) in a AA 5083. Domes were formed at 570ºC and at a strain rate of 5x10-5 s-1 by blow forming with and without back-pressure. They were compared in terms of their final shape, thickness distribution, and quantity of cavitation voids. The effectiveness of the usage of back pressure to reducing the quantity of cavitation void was analyzed.
DOI: 10.6084/m9.figshare.20020739.v1
title: The Effectiveness of Back Pressure in Superplastic Blow Forming of Aluminum Alloy AA 5083 Performed at Very Favorable Conditions for Cavitation Growth

description: Many components for aerospace and automotive industries are currently manufactured using superplastic forming, being the fine-grained aluminum alloy AA5083 widely used for this proposes. However, the development of cavitation voids is inherent in this process and reduces the ductility of the alloy. Back pressure can be used to diminish the growth of cavitation void. The experimental conditions used in this work are in the best condition for nucleation and grow of cavitation, because of the coarse grain size (81 µm), large second phase particles (9 µm) and elevated test temperature (570ºC) in a AA 5083. Domes were formed at 570ºC and at a strain rate of 5x10-5 s-1 by blow forming with and without back-pressure. They were compared in terms of their final shape, thickness distribution, and quantity of cavitation voids. The effectiveness of the usage of back pressure to reducing the quantity of cavitation void was analyzed.
DOI: 10.6084/m9.figshare.20020740
title: Characterization of Phase Transformations and Microstructural Changes in an API 5CT L80 Steel Grade During Ni Alloy Laser Cladding

description: The superficial coatings in micro-alloyed steel pipes has been a pointed way to decrease the corrosion problems in oil and gas industry. However, little emphasis has been given to the substrate. The effects of the deposition method on the steel microstructure and properties are still not well described. In this context, this work studied the effect of Ni superalloys clads on the phase transformations, microstructure and hardness of the heat-affected zone (HAZ) of an API steel. The underestimate of the HAZ might be dangerous, since, despite the coating good corrosion performance, the substrate HAZ may present a weak region, which may lead to an in-service coating tearing. In this work, Inconel 625 and Hastelloy C276 superalloys were clad on the steel surface by a laser deposition. Dilatometry, optical and scanning electron microscopy, and computational simulation were applied. The studied steel was originally constituted by tempered martensite. The austentizing temperature had a strong influence on the austenite grain size and on the steel CCT diagram. Due to that, the laser superalloy deposits promoted a complex HAZ, where grain growth occurred. A post-cladding heat treatment was proposed to homogenize the steel microstructure and to decrease the hardness gradient at the superalloy-steel interface.
DOI: 10.6084/m9.figshare.6943838
title: Effect of Preparation Method on the Electrical and Mechanical Properties of PVC/Carbon Nanotubes Nanocomposites

description: The biggest challenge for the development of carbon nanotubes polymeric nanocomposites is in the suitable dispersion and distribution of the nanometric particles along the polymer matrix. Several preparation methods have been used to obtain nanocomposites, highlighting the mixture with polymer solution followed by solvent evaporation and the hot compacting. The first one has the advantage of allowing dispersion of the nanotubes in a low viscosity medium, while the second method is more environmental favorable due to reduced use of solvent. The aim of this work was to evaluate the influence of the preparation method on the electrical resistivity of PVC/carbon nanotubes nanocomposites, containing from 0.05 to 1.00%w of carbon nanotubes. The results showed a percolation threshold of 0.4%w and 0.15%w of nanotubes for the polymer solution method and hot compacting, respectively, and an electrical resistivity reduction of eight and nine orders of magnitude, respectively, compared to pure PVC. The tensile strength of PVC/MWNT nanocomposites was not affected by the presence or content of carbon nanotubes compared to PVC without addition of nanoparticles, regardless of the material preparation method, however the deformation at beak was largely reduced.
DOI: 10.6084/m9.figshare.20020742
title: Conductive Composites Based on Polyurethane and Nanostructured Conductive Filler of Montmorillonite/Polypyrrole for Electromagnetic Shielding Applications

description: In this study, composites based on polyurethane (PU) derived from castor oil and montmorillonite/polypyrrole doped with dodecylbenzenesulfonic acid (MMt-PPy.DBSA) were developed. In order to investigate the potential use of these materials for electromagnetic shielding applications, the electrical and mechanical properties of PU/MMt-PPy.DBSA composites were determined and compared with composites containing neat PPy.DBSA. The electrical conductivity of PU/MMt-PPy.DBSA composites was found to be higher than those for PU/PPy.DBSA with a similar filler content. Additionally, with a higher conductive additive content, significant increases in the tensile stress (σ) and elastic modulus (E) were observed, suggesting that MMt-PPy.DBSA acts as reinforcing agent for the PU matrix. The electromagnetic interference shielding effectiveness (EMI SE) of composites is mainly dependent on the morphology and filler content. The PU/MMt-PPy.DBSA composite containing 25 wt % of MMt-PPy.DBSA showed a maximum EMI SE of -21 dB, which is similar to the value required for commercial applications (-20 dB). The results revealed that PU/MMt-PPy.DBSA composites are promising materials for electromagnetic shielding applications.
DOI: 10.6084/m9.figshare.20020742.v1
title: Conductive Composites Based on Polyurethane and Nanostructured Conductive Filler of Montmorillonite/Polypyrrole for Electromagnetic Shielding Applications

description: In this study, composites based on polyurethane (PU) derived from castor oil and montmorillonite/polypyrrole doped with dodecylbenzenesulfonic acid (MMt-PPy.DBSA) were developed. In order to investigate the potential use of these materials for electromagnetic shielding applications, the electrical and mechanical properties of PU/MMt-PPy.DBSA composites were determined and compared with composites containing neat PPy.DBSA. The electrical conductivity of PU/MMt-PPy.DBSA composites was found to be higher than those for PU/PPy.DBSA with a similar filler content. Additionally, with a higher conductive additive content, significant increases in the tensile stress (σ) and elastic modulus (E) were observed, suggesting that MMt-PPy.DBSA acts as reinforcing agent for the PU matrix. The electromagnetic interference shielding effectiveness (EMI SE) of composites is mainly dependent on the morphology and filler content. The PU/MMt-PPy.DBSA composite containing 25 wt % of MMt-PPy.DBSA showed a maximum EMI SE of -21 dB, which is similar to the value required for commercial applications (-20 dB). The results revealed that PU/MMt-PPy.DBSA composites are promising materials for electromagnetic shielding applications.
DOI: 10.6084/m9.figshare.6943874
title: The effect of the austenite grain refinement on the tensile and impact properties of cast Hadfield steel

description: This paper studied the effect of the austenite grain refinement on the tensile and impact properties of a cast Hadfield steel (12 % Mn, 1.2 %C and 0.65 % Si). The austenite grain refinement was obtained by hafnium inoculation. Microstructural characterization showed that the Hf-refined cast Hadfield steel featured a grain size of 600 µm, while the non-refined condition presented a grain size of 3000 µm. Mechanical test results indicated that the austenite grain refinement promoted an increase in the values of the yield stress (6%), the ultimate tensile strength (37%), the toughness (88%), the work-hardening coefficient (50%) and the Charpy absorbed energy (15%). Microscopic characterization of the fractured test-pieces indicated that the grain refinement increased the proportion of plastic deformation by the twinning mechanism and furthermore improved the values of the mechanical properties of the cast Hadfield steel considerably.
DOI: 10.6084/m9.figshare.6943874.v1
title: The effect of the austenite grain refinement on the tensile and impact properties of cast Hadfield steel

description: This paper studied the effect of the austenite grain refinement on the tensile and impact properties of a cast Hadfield steel (12 % Mn, 1.2 %C and 0.65 % Si). The austenite grain refinement was obtained by hafnium inoculation. Microstructural characterization showed that the Hf-refined cast Hadfield steel featured a grain size of 600 µm, while the non-refined condition presented a grain size of 3000 µm. Mechanical test results indicated that the austenite grain refinement promoted an increase in the values of the yield stress (6%), the ultimate tensile strength (37%), the toughness (88%), the work-hardening coefficient (50%) and the Charpy absorbed energy (15%). Microscopic characterization of the fractured test-pieces indicated that the grain refinement increased the proportion of plastic deformation by the twinning mechanism and furthermore improved the values of the mechanical properties of the cast Hadfield steel considerably.
DOI: 10.6084/m9.figshare.6943826
title: Heat Treatment of Sintered Valve Seat Inserts

description: The characterization of sintered valve seat inserts (VSIs) after being subjected to different heat treatment operations has been carried out. The VSIs were obtained from three different alloys by mixing iron powder with AISI M3:2, AISI M2 high-speed steels, and AISI D2 tool steel. After sintering, the VSI were quenched in air followed by double tempering at seven different temperatures. The cooling rate during air quenching was measured by means of a thermocouple type k attached to a data acquisition system. The characterization of the mechanical and physical properties of the VSIs was achieved by measuring relative density, apparent hardness and crush radial strength. The resulting microstructures for the sintered parts were interpreted using the isothermal and continuous cooling transformation diagrams for similar alloys. The VSI obtained with AISI M3:2 and AISI M2 high-speed steels after air quenching and double tempering at 600 ºC showed the best results in terms of apparent hardness and crush radial strength.
DOI: 10.6084/m9.figshare.6943826.v1
title: Heat Treatment of Sintered Valve Seat Inserts

description: The characterization of sintered valve seat inserts (VSIs) after being subjected to different heat treatment operations has been carried out. The VSIs were obtained from three different alloys by mixing iron powder with AISI M3:2, AISI M2 high-speed steels, and AISI D2 tool steel. After sintering, the VSI were quenched in air followed by double tempering at seven different temperatures. The cooling rate during air quenching was measured by means of a thermocouple type k attached to a data acquisition system. The characterization of the mechanical and physical properties of the VSIs was achieved by measuring relative density, apparent hardness and crush radial strength. The resulting microstructures for the sintered parts were interpreted using the isothermal and continuous cooling transformation diagrams for similar alloys. The VSI obtained with AISI M3:2 and AISI M2 high-speed steels after air quenching and double tempering at 600 ºC showed the best results in terms of apparent hardness and crush radial strength.
DOI: 10.6084/m9.figshare.6968138
title: Analysis of β´(Cu4Ti) Precipitation During Isothermal Aging of a Cu-4wt.%Ti Alloy

description: This work analyzed experimental and numerically the growth kinetics of β´precipitation of a Cu-4wt.%Ti alloy after aging at 400, 500 and 600 ºC for times from 0.0166 h to 200 h. Results indicated that the precipitation process is almost controlled by nucleation and growth during aging at 400 ºC, originating a slow growth kinetics of precipitation. In contrast, the coarsening of precipitates dominates the precipitation process during aging at 500 and 600 ºC. The interfacial energy of interface between the a matrix phase and β´ precipitates was determined to be about 0.1135, 0.0980 and 0.0725 Jm-2 for aging at 400, 500 and 600 ºC, respectively. These values suggest a coherent interface which is in agreement with the flat faces of β´ cuboid precipitates. Calculated Time-Temperature-Precipitation diagram for the β´ precipitation indicated good agreement with experimental results. Precipitation hardening was higher for the slower growth kinetics of precipitation.
DOI: 10.6084/m9.figshare.6968138.v1
title: Analysis of β´(Cu4Ti) Precipitation During Isothermal Aging of a Cu-4wt.%Ti Alloy

description: This work analyzed experimental and numerically the growth kinetics of β´precipitation of a Cu-4wt.%Ti alloy after aging at 400, 500 and 600 ºC for times from 0.0166 h to 200 h. Results indicated that the precipitation process is almost controlled by nucleation and growth during aging at 400 ºC, originating a slow growth kinetics of precipitation. In contrast, the coarsening of precipitates dominates the precipitation process during aging at 500 and 600 ºC. The interfacial energy of interface between the a matrix phase and β´ precipitates was determined to be about 0.1135, 0.0980 and 0.0725 Jm-2 for aging at 400, 500 and 600 ºC, respectively. These values suggest a coherent interface which is in agreement with the flat faces of β´ cuboid precipitates. Calculated Time-Temperature-Precipitation diagram for the β´ precipitation indicated good agreement with experimental results. Precipitation hardening was higher for the slower growth kinetics of precipitation.