cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.6084/m9.figshare.5668981
title: Electrochemical Study of the AISI 409 Ferritic Stainless Steel: Passive Film Stability and Pitting Nucleation and Growth

description: The aim of the present work was to study the passive film stability and pitting corrosion behavior of the AISI 409 stainless steel. The electrochemical tests were carried out in 0.1 M NaCl solution at room temperature. The general electrochemical behavior was assessed using electrochemical impedance spectroscopy (EIS) measurements whereas the semiconducting properties of the passive film were evaluated by the Mott-Schottky approach. Pitting corrosion was investigated using potentiodynamic and potentiostatic polarization tests. Surface morphology was examined using confocal laser scanning microscopy and scanning electron microscopy (SEM). Energy dispersive X-ray spectroscopy (EDS) analyses were carried out to identify the composition of precipitates that could act as preferential sites for the onset of pitting corrosion. The results showed that the passive film presents n-type semiconductive behavior. Grain boundaries played an important role as pitting initiation sites for the AISI 409 stainless steel.
DOI: 10.6084/m9.figshare.5668981.v1
title: Electrochemical Study of the AISI 409 Ferritic Stainless Steel: Passive Film Stability and Pitting Nucleation and Growth

description: The aim of the present work was to study the passive film stability and pitting corrosion behavior of the AISI 409 stainless steel. The electrochemical tests were carried out in 0.1 M NaCl solution at room temperature. The general electrochemical behavior was assessed using electrochemical impedance spectroscopy (EIS) measurements whereas the semiconducting properties of the passive film were evaluated by the Mott-Schottky approach. Pitting corrosion was investigated using potentiodynamic and potentiostatic polarization tests. Surface morphology was examined using confocal laser scanning microscopy and scanning electron microscopy (SEM). Energy dispersive X-ray spectroscopy (EDS) analyses were carried out to identify the composition of precipitates that could act as preferential sites for the onset of pitting corrosion. The results showed that the passive film presents n-type semiconductive behavior. Grain boundaries played an important role as pitting initiation sites for the AISI 409 stainless steel.
DOI: 10.6084/m9.figshare.5668978
title: Influence of packing and dispersion of particles on the cement content of concretes

description: Abstract Due to environmental issues, the concrete chain seeks to reduce CO2 emissions. However, growing demand from developing countries causes the increase of CO2 emissions in production to exceed decreases generated by industrial actions, such as improving kilns and clinker replacement. New strategies are important. Changes in the concrete formulation, making it more efficient, can help if these changes produce concrete with the same performance and lower cement consumption. In this regard, the improvement of packing and dispersion of particles increases this efficiency. The better the packing, the lower the volume of voids between particles, thereby requiring lower fluid content (water) to permit flow. The dispersion of the particles also decreases the water content for the same fluidity. The less the water content, the smaller the water/cement (w/c) ratio, and the greater the resistance. Thus, both strategies increase the efficiency by uncoupling obtaining fluidity from the water content. This study investigated the influence of packing and dispersion on the efficiency of cement use in concrete. The increase of packing and the complete dispersion of fine particles has been shown to improve efficiency, as measured by the ratio between binder consumption and compressive strength (the performance parameter used in most practical applications).
DOI: 10.6084/m9.figshare.5668978.v1
title: Influence of packing and dispersion of particles on the cement content of concretes

description: Abstract Due to environmental issues, the concrete chain seeks to reduce CO2 emissions. However, growing demand from developing countries causes the increase of CO2 emissions in production to exceed decreases generated by industrial actions, such as improving kilns and clinker replacement. New strategies are important. Changes in the concrete formulation, making it more efficient, can help if these changes produce concrete with the same performance and lower cement consumption. In this regard, the improvement of packing and dispersion of particles increases this efficiency. The better the packing, the lower the volume of voids between particles, thereby requiring lower fluid content (water) to permit flow. The dispersion of the particles also decreases the water content for the same fluidity. The less the water content, the smaller the water/cement (w/c) ratio, and the greater the resistance. Thus, both strategies increase the efficiency by uncoupling obtaining fluidity from the water content. This study investigated the influence of packing and dispersion on the efficiency of cement use in concrete. The increase of packing and the complete dispersion of fine particles has been shown to improve efficiency, as measured by the ratio between binder consumption and compressive strength (the performance parameter used in most practical applications).
DOI: 10.6084/m9.figshare.5668972
title: NEOTROPICAL TREE PRODUCTION: INSIGHTS INTO GERMINATION, GROWTH AND OUTPLANTING FOR Maytenus boaria

description: ABSTRACT Knowledge about tree production practices is essential to support forest restoration projects, but is still lacking for many tree species. Maytenus boaria is a neotropical tree distributed across the temperate and subtropical South American mountains. In central Argentina, it is mainly restricted to the most preserved forest remnants. Attempts to plant this species have had little success due to difficulties in seedling production and low seedling survival. We set up four trials aiming to identify the constraints of seedling production and outplanting. Under greenhouse conditions, we evaluated (i) pre-germination treatments and (ii) seedling response to inoculation with arbuscular mycorrhizal fungi (AMF). In the field, we planted M. boaria saplings as well as saplings of the most abundant tree in our study site and recorded (iii) survival and height for 10 years. Finally, (iv) we quantified natural recruitment in an attempt to determine M. boaria regeneration niche. Germination varied from 13.1 to 29.2% among treatments. Depulped seeds stratified at 5 ºC showed the highest germination (29.2%). Shoot phosphorus concentration in AMF-treated seedlings was significantly higher (45%) than in non-inoculated seedlings. Survival of M. boaria saplings was similar to that of the most abundant tree in our study site, but their lower height suggested limited growth. We recorded low abundance of M. boaria seedlings in the field; therefore, we were unable to identify the characteristics of its regeneration niche. Reforestation activities should include seed depulping and stratification at 5 ºC to improve germination. The capacity of AMF to enhance nutrition should be evaluated under field conditions.
DOI: 10.6084/m9.figshare.5668972.v1
title: NEOTROPICAL TREE PRODUCTION: INSIGHTS INTO GERMINATION, GROWTH AND OUTPLANTING FOR Maytenus boaria

description: ABSTRACT Knowledge about tree production practices is essential to support forest restoration projects, but is still lacking for many tree species. Maytenus boaria is a neotropical tree distributed across the temperate and subtropical South American mountains. In central Argentina, it is mainly restricted to the most preserved forest remnants. Attempts to plant this species have had little success due to difficulties in seedling production and low seedling survival. We set up four trials aiming to identify the constraints of seedling production and outplanting. Under greenhouse conditions, we evaluated (i) pre-germination treatments and (ii) seedling response to inoculation with arbuscular mycorrhizal fungi (AMF). In the field, we planted M. boaria saplings as well as saplings of the most abundant tree in our study site and recorded (iii) survival and height for 10 years. Finally, (iv) we quantified natural recruitment in an attempt to determine M. boaria regeneration niche. Germination varied from 13.1 to 29.2% among treatments. Depulped seeds stratified at 5 ºC showed the highest germination (29.2%). Shoot phosphorus concentration in AMF-treated seedlings was significantly higher (45%) than in non-inoculated seedlings. Survival of M. boaria saplings was similar to that of the most abundant tree in our study site, but their lower height suggested limited growth. We recorded low abundance of M. boaria seedlings in the field; therefore, we were unable to identify the characteristics of its regeneration niche. Reforestation activities should include seed depulping and stratification at 5 ºC to improve germination. The capacity of AMF to enhance nutrition should be evaluated under field conditions.
DOI: 10.6084/m9.figshare.5668969
title: Characterization of test specimens produced in reduced size for X-ray microtomography (µ-CT) tests

description: Abstract The need to use reduced sample sizes, in order to attain improved spatial resolution in (µ-CT) tests applied in Portland cement composites, makes researchers perform the fractionation of materials to obtain samples with dimensions compatible with the capacity of the scanning equipment, which might cause alterations in the microstructure under analysis. Therefore, a test specimen (TS) with dimensions compatible with the scanning capacity of a microtomography system that operates with an X-ray tube and voltage ranging from 20 to 100 kV was proposed. Axial compression strength tests were made and their total porosity was assessed by an apparent density and solid fraction density ratio, which were obtained by means of mercury and helium pycnometry and µ-CT technique, respectively. The adoption of that TS has shown to be viable for providing a sample with a higher level of representation.
DOI: 10.6084/m9.figshare.5668969.v1
title: Characterization of test specimens produced in reduced size for X-ray microtomography (µ-CT) tests

description: Abstract The need to use reduced sample sizes, in order to attain improved spatial resolution in (µ-CT) tests applied in Portland cement composites, makes researchers perform the fractionation of materials to obtain samples with dimensions compatible with the capacity of the scanning equipment, which might cause alterations in the microstructure under analysis. Therefore, a test specimen (TS) with dimensions compatible with the scanning capacity of a microtomography system that operates with an X-ray tube and voltage ranging from 20 to 100 kV was proposed. Axial compression strength tests were made and their total porosity was assessed by an apparent density and solid fraction density ratio, which were obtained by means of mercury and helium pycnometry and µ-CT technique, respectively. The adoption of that TS has shown to be viable for providing a sample with a higher level of representation.
DOI: 10.6084/m9.figshare.5668963
title: Unknown Unknowns in Innovative Projects: Early Signs Sensemaking

description: Abstract This study aims to understand early signs’ sensemaking relevance to identifying unknown unknowns on innovative projects. When managing these projects, early signs of changes in the environment, combined with a sensemaking process, can help identify them prior to their occurrence and mitigate unwanted effects of these uncertainties. To this end, we conducted a field research to assess 16 projects, totaling 35 events representative of this kind of uncertainty. Based on in-depth interviews, we performed an initial qualitative analysis, and then applied non-parametric statistical tests. Early signs perception in cases where external factors may cause the occurrence of unknown unknowns show that this perception and the search for information are relevant to identifying unk unks. Furthermore, some biases, such as overconfidence and unrealistic optimism, can hinder it. There was a high prevalence of project managers detecting early signs of change in their projects at the beginning of the project. However, the majority of perceived early signs can be considered to be the first symptoms of a problem. Thus, as a contribution, we suggest: learning processes, which can provide sensemaking for early signs in unknown unknowns; project managers stimulating their team to be alert to environmental changes that may affect the project; and discussion of early signs perceived by the team during stakeholder management.
DOI: 10.6084/m9.figshare.5668963.v1
title: Unknown Unknowns in Innovative Projects: Early Signs Sensemaking

description: Abstract This study aims to understand early signs’ sensemaking relevance to identifying unknown unknowns on innovative projects. When managing these projects, early signs of changes in the environment, combined with a sensemaking process, can help identify them prior to their occurrence and mitigate unwanted effects of these uncertainties. To this end, we conducted a field research to assess 16 projects, totaling 35 events representative of this kind of uncertainty. Based on in-depth interviews, we performed an initial qualitative analysis, and then applied non-parametric statistical tests. Early signs perception in cases where external factors may cause the occurrence of unknown unknowns show that this perception and the search for information are relevant to identifying unk unks. Furthermore, some biases, such as overconfidence and unrealistic optimism, can hinder it. There was a high prevalence of project managers detecting early signs of change in their projects at the beginning of the project. However, the majority of perceived early signs can be considered to be the first symptoms of a problem. Thus, as a contribution, we suggest: learning processes, which can provide sensemaking for early signs in unknown unknowns; project managers stimulating their team to be alert to environmental changes that may affect the project; and discussion of early signs perceived by the team during stakeholder management.
DOI: 10.6084/m9.figshare.5668960
title: Cancellation of elective surgeries in a Brazilian public hospital: reasons and estimated reduction

description: ABSTRACT Objective: To characterize cancellations of elective surgeries according to clinical and non-clinical reasons, as well as to verify seasonal influence and determine the estimated reduction of the index. Method: Quantitative, descriptive and retrospective study with secondary data extracted from the Public Hospital of the State of São Paulo database. Results: Out of the 8,443 (100%) elective surgeries scheduled, 7,870 (93.21%) were performed and 573 (6.79%) were canceled. Out of these 573 (100%) people, 48.33% were canceled for clinical reasons and 46.40% were for non-clinical reasons. Among the non-clinical reasons for surgery cancellations, those related to medical reasons stood out: at the request of the surgeon/change of approach (17.93%), followed by non-hospitalized patient (8.96%). There was no indication of seasonality regarding the reasons for cancellation in the assessed period. Conclusion: Although the rate of elective surgeries cancellations is lower than that of other hospitals with similar characteristics, it is still possible to reduce it from 6.79% to 1.36%, considering that 80% of the reasons for cancellation are avoidable.
DOI: 10.6084/m9.figshare.5668960.v1
title: Cancellation of elective surgeries in a Brazilian public hospital: reasons and estimated reduction

description: ABSTRACT Objective: To characterize cancellations of elective surgeries according to clinical and non-clinical reasons, as well as to verify seasonal influence and determine the estimated reduction of the index. Method: Quantitative, descriptive and retrospective study with secondary data extracted from the Public Hospital of the State of São Paulo database. Results: Out of the 8,443 (100%) elective surgeries scheduled, 7,870 (93.21%) were performed and 573 (6.79%) were canceled. Out of these 573 (100%) people, 48.33% were canceled for clinical reasons and 46.40% were for non-clinical reasons. Among the non-clinical reasons for surgery cancellations, those related to medical reasons stood out: at the request of the surgeon/change of approach (17.93%), followed by non-hospitalized patient (8.96%). There was no indication of seasonality regarding the reasons for cancellation in the assessed period. Conclusion: Although the rate of elective surgeries cancellations is lower than that of other hospitals with similar characteristics, it is still possible to reduce it from 6.79% to 1.36%, considering that 80% of the reasons for cancellation are avoidable.
DOI: 10.6084/m9.figshare.5668954
title: Beer sample decomposition using a reflux system for the monoelementar determination by F AAS/AES and multielementar determination by MIP OES

description: Abstract This study describes the development of an analytical method for the analysis of beer samples by atomic spectrometric techniques. The samples were prepared by acid decomposition using a reflux system, and the determinations carried out by F AAS (Fe, Mg and Zn), F AES (Na) and MIP OES (Ca, Fe, K, Mg, Mn, Na, Ni and Zn). The best conditions for sample decomposition were obtained by way of studies using a central rotational compound design: 10.0 mL of degassed beer followed by the addition of 5.0 mL of HNO3 and 2.0 mL H2O2 and a heating step in the digester block at 160 °C for 93 min. The quantification limits of the method were ≤ 0.100 mg L-1 for all the analytes investigated, regardless of the analytical technique used, values below those established by the Brazilian Health Surveillance Agency for Zn and Ni, for example. The comparative study of the different techniques showed that, according to the t-test at a 90% level of confidence, there was no significant difference for the determinations of Fe, Mg, Na and Zn in the beer samples. The sample preparation method was shown to be simple, fast, low-cost and reliable for the analysis of beers by the different atomic spectrometry techniques.
DOI: 10.6084/m9.figshare.5668954.v1
title: Beer sample decomposition using a reflux system for the monoelementar determination by F AAS/AES and multielementar determination by MIP OES

description: Abstract This study describes the development of an analytical method for the analysis of beer samples by atomic spectrometric techniques. The samples were prepared by acid decomposition using a reflux system, and the determinations carried out by F AAS (Fe, Mg and Zn), F AES (Na) and MIP OES (Ca, Fe, K, Mg, Mn, Na, Ni and Zn). The best conditions for sample decomposition were obtained by way of studies using a central rotational compound design: 10.0 mL of degassed beer followed by the addition of 5.0 mL of HNO3 and 2.0 mL H2O2 and a heating step in the digester block at 160 °C for 93 min. The quantification limits of the method were ≤ 0.100 mg L-1 for all the analytes investigated, regardless of the analytical technique used, values below those established by the Brazilian Health Surveillance Agency for Zn and Ni, for example. The comparative study of the different techniques showed that, according to the t-test at a 90% level of confidence, there was no significant difference for the determinations of Fe, Mg, Na and Zn in the beer samples. The sample preparation method was shown to be simple, fast, low-cost and reliable for the analysis of beers by the different atomic spectrometry techniques.
DOI: 10.6084/m9.figshare.5668951
title: Hematological changes associated with hemoplasma infection in cats in Rio de Janeiro, Brazil

description: Abstract This study aimed to detect Mycoplasma spp. in naturally infected cats from Rio de Janeiro and to evaluate hematological abnormalities and factors associated with this infection. Out of the 197 cats sampled, 11.2% presented structures compatible with hemoplasma organisms on blood smears. In contrast, 22.8% were positive for Mycoplasma spp. by means of 16S rRNA gene real-time polymerase chain reaction, which reflects the weak concordance between techniques. The infection rates, by means of 16S rRNA gene conventional polymerase chain reaction, was 4.6%, 4.6% and 11.7% for Mycoplasma haemofelis (Mhf), ‘Candidatus Mycoplasma turicensis’ (CMt) and ‘Candidatus Mycoplasma haemominutum’ (CMhm), respectively. Mhf and CMhm infections are more frequent in the summer (p&gt;0.05). Presence of anemia (p &lt; 0.02), lymphocytosis (p &lt; 0.03), thrombocytopenia (p &lt; 0.04) and activated monocytes (p &lt; 0.04) was associated with Mhf infection. No hematological abnormality was associated with CMt or CMhm infection. Male cats were more prone to be infected by Mhf or CMhm (p &lt; 0.01). Adult cats had more chance to be infected by CMhm. Three hemoplasma species occur in the metropolitan region of Rio de Janeiro and Mhf seems to be the most pathogenic of them. Anemia is the most important hematological abnormality.
DOI: 10.6084/m9.figshare.5668951.v1
title: Hematological changes associated with hemoplasma infection in cats in Rio de Janeiro, Brazil

description: Abstract This study aimed to detect Mycoplasma spp. in naturally infected cats from Rio de Janeiro and to evaluate hematological abnormalities and factors associated with this infection. Out of the 197 cats sampled, 11.2% presented structures compatible with hemoplasma organisms on blood smears. In contrast, 22.8% were positive for Mycoplasma spp. by means of 16S rRNA gene real-time polymerase chain reaction, which reflects the weak concordance between techniques. The infection rates, by means of 16S rRNA gene conventional polymerase chain reaction, was 4.6%, 4.6% and 11.7% for Mycoplasma haemofelis (Mhf), ‘Candidatus Mycoplasma turicensis’ (CMt) and ‘Candidatus Mycoplasma haemominutum’ (CMhm), respectively. Mhf and CMhm infections are more frequent in the summer (p&gt;0.05). Presence of anemia (p &lt; 0.02), lymphocytosis (p &lt; 0.03), thrombocytopenia (p &lt; 0.04) and activated monocytes (p &lt; 0.04) was associated with Mhf infection. No hematological abnormality was associated with CMt or CMhm infection. Male cats were more prone to be infected by Mhf or CMhm (p &lt; 0.01). Adult cats had more chance to be infected by CMhm. Three hemoplasma species occur in the metropolitan region of Rio de Janeiro and Mhf seems to be the most pathogenic of them. Anemia is the most important hematological abnormality.
DOI: 10.6084/m9.figshare.5668948
title: Size Reduced Iron Nitroprusside Particles: an Electrochemical Mediator for the Quantification of Peroxodisulfate and Nitrite

description: Iron nitroprusside (FeNP) particles have been synthesized from drop by drop (n-FeNP) and bulk mixing (BM) (b-FeNP) methods. FeNP particles obtained from both methods were characterized using X-ray diffraction (XRD) and scanning electron microscopy (SEM). n-FeNP particles were used in constructing modified carbon paste electrode (CPE), which has been further used for electrochemical studies. The effect of pH and electrolyte cation on the electrochemical behavior of n-FeNP modified CPE has been studied in detail. Oxidation of nitrite and reduction of peroxodisulfate reactions have been electrocatalyzed at two redox centers of n-FeNP modified CPE. Based on the electrochemical experiments conducted and Tafel plots, mechanism for both the reactions has been proposed. Both the analytes were estimated in soil and ground water samples using n-FeNP modified CPE and the results were validated with the help of standard methods.