cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.48420/26321476.v1
title: Uranium(III) and uranium(IV) <i>meta</i>-terphenyl thiolate complexes

description: See: 10.1021/acs.inorgchem.4c03085We report the synthesis and characterization of crystalline <i>m</i>-terphenylthiolate uranium complexes supported by the bulky ligand system, SAr<sup><em>i</em></sup><sup>Pr6</sup> (SAr<sup><em>i</em></sup><sup>Pr6</sup> = {SC<sub>6</sub>H<sub>3</sub>-2,6-(Tripp)<sub>2</sub>}; Tripp = 2,4,6-<i>i</i>Pr-C<sub>6</sub>H<sub>2</sub>). Treatment of U<sup>IV</sup>Cl<sub>4</sub> with 2 equiv of KSAr<sup><em>i</em></sup><sup>Pr6</sup> in Et<sub>2</sub>O afforded both [U<sup>IV</sup>(SAr<sup><em>i</em></sup><sup>Pr6</sup>)<sub>2</sub>(Cl)<sub>2</sub>] (<b>1</b>) and the Et<sub>2</sub>O adduct, [U<sup>IV</sup>(SAr<sup><em>i</em></sup><sup>Pr6</sup>)<sub>2</sub>(Cl)<sub>2</sub>(Et<sub>2</sub>O)<sub>2</sub>] (<b>1·Et</b><sub><strong>2</strong></sub><b>O</b>) in poor yield. The reaction between [U<sup>IV</sup>(BH<sub>4</sub>)<sub>4</sub>] and 1 equiv of KSAr<sup><em>i</em></sup><sup>Pr6</sup> in toluene gave several crystals of the double salt, [U<sup>IV</sup>(μ-SAr<sup><em>i</em></sup><sup>Pr6</sup>)(BH<sub>4</sub>)<sub>2</sub>(μ-BH<sub>4</sub>)(μ<sup>3</sup>-BH<sub>4</sub>)K]<sub>2</sub> (<b>2</b>), and exposing the crude reaction mixture to Et<sub>2</sub>O gave the disulfide dimer, (SAr<sup><em>i</em></sup><sup>Pr6</sup>)<sub>2</sub>. The reaction between [U<sup>IV</sup>(BH<sub>4</sub>)<sub>4</sub>] and 1 equiv of HSAr<sup><em>i</em></sup><sup>Pr6</sup> in hot toluene gave [U<sup>III</sup>(H<sub>3</sub>B·SAr<sup><em>i</em></sup><sup>Pr6</sup> κ<i>S</i>,<i>H</i>,<i>H</i>)(BH<sub>4</sub>)<sub>2</sub>] (<b>3</b>) which proved resistant to further substitution using either HSAr<sup><em>i</em></sup><sup>Pr6</sup> or KSAr<sup><em>i</em></sup><sup>Pr6</sup>. Two U(III) <i>mono</i>-terphenylthiolates, [U<sup>III</sup>(SAr<sup><em>i</em></sup><sup>Pr6</sup>)(BH<sub>4</sub>)<sub>2</sub>] (<b>4a</b>) and [{U<sup>III</sup>(SAr<sup><em>i</em></sup><sup>Pr6</sup>)(BH<sub>4</sub>)}<sub>2</sub>{μ-B<sub>2</sub>H<sub>6</sub>}] (<b>4b</b>), were isolated as a mixture from the reaction between [U<sup>III</sup>(BH<sub>3</sub>)<sub>3</sub>(toluene)] and 1 equiv of KSAr<sup><em>i</em></sup><sup>Pr6</sup>, while using 2 equiv of KSAr<sup><em>i</em></sup><sup>Pr6</sup> gave the <i>bis</i>-terphenylthiolate complex [U<sup>III</sup>(SAr<sup><em>i</em></sup><sup>Pr6</sup>)<sub>2</sub>(BH<sub>4</sub>)] (<b>5</b>). Complex <b>4b</b> is a rare example of a <i>nido</i>-metalloborane. Complexes <b>1</b>–<b>5</b> have been characterized variously by single-crystal and powder X-ray diffraction, multinuclear NMR spectroscopy, infrared spectroscopy, UV–Vis–NIR spectroscopy, SQUID magnetometry, and elemental analyses as appropriate. Quantum chemical calculations have been employed to interpret the nature of the U–S bonding interactions across these complexes.
DOI: 10.15468/dl.4m8935
title: Occurrence Download

description: A dataset containing 16012 species occurrences available in GBIF matching the query:
{
 "and" : [
 "HasCoordinate is true",
 "TaxonKey is Cynara cardunculus"
 ]
}

 The dataset includes 16012 records from 233 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0080898-250717081556266/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.warf8x
title: Occurrence Download

description: A dataset containing 267 species occurrences available in GBIF matching the query:
{
 "and" : [
 "GadmGid is USA.1_1",
 "OccurrenceStatus is Present",
 "TaxonKey is Pteronotropis signipinnis"
 ]
}

 The dataset includes 267 records from 12 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0081997-250717081556266/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.baz95d
title: Occurrence Download

description: A dataset containing 187 species occurrences available in GBIF matching the query:
{
 "and" : [
 "TaxonKey is Myzocallis carpini",
 "HasCoordinate is true",
 "HasGeospatialIssue is false"
 ]
}

 The dataset includes 187 records from 22 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0081999-250717081556266/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.22033/esgf/cmip6.5467
title: MIROC MIROC6 model output prepared for CMIP6 DCPP dcppA-assim

description: Coupled Model Intercomparison Project Phase 6 (CMIP6) datasets: These data include all datasets published for 'CMIP6.DCPP.MIROC.MIROC6.dcppA-assim' with the full Data Reference Syntax following the template 'mip_era.activity_id.institution_id.source_id.experiment_id.member_id.table_id.variable_id.grid_label.version'.
 
 The MIROC6 climate model, released in 2017, includes the following components:
 aerosol: SPRINTARS6.0, atmos: CCSR AGCM (T85; 256 x 128 longitude/latitude; 81 levels; top level 0.004 hPa), land: MATSIRO6.0, ocean: COCO4.9 (tripolar primarily 1deg; 360 x 256 longitude/latitude; 63 levels; top grid cell 0-2 m), seaIce: COCO4.9. 
The model was run by the JAMSTEC (Japan Agency for Marine-Earth Science and Technology, Kanagawa 236-0001, Japan), AORI (Atmosphere and Ocean Research Institute, The University of Tokyo, Chiba 277-8564, Japan), NIES (National Institute for Environmental Studies, Ibaraki 305-8506, Japan), and R-CCS (RIKEN Center for Computational Science, Hyogo 650-0047, Japan) (MIROC) in native nominal resolutions: aerosol: 250 km, atmos: 250 km, land: 250 km, ocean: 100 km, seaIce: 100 km. 

Project: These data have been generated as part of the internationally-coordinated Coupled Model Intercomparison Project Phase 6 (CMIP6; see also GMD Special Issue: http://www.geosci-model-dev.net/special_issue590.html). The simulation data provides a basis for climate research designed to answer fundamental science questions and serves as resource for authors of the Sixth Assessment Report of the Intergovernmental Panel on Climate Change (IPCC-AR6).

CMIP6 is a project coordinated by the Working Group on Coupled Modelling (WGCM) as part of the World Climate Research Programme (WCRP). Phase 6 builds on previous phases executed under the leadership of the Program for Climate Model Diagnosis and Intercomparison (PCMDI) and relies on the Earth System Grid Federation (ESGF) and the Centre for Environmental Data Analysis (CEDA) along with numerous related activities for implementation. The original data is hosted and partially replicated on a federated collection of data nodes, and most of the data relied on by the IPCC is being archived for long-term preservation at the IPCC Data Distribution Centre (IPCC DDC) hosted by the German Climate Computing Center (DKRZ).

The project includes simulations from about 120 global climate models and around 45 institutions and organizations worldwide. - Project website: https://pcmdi.llnl.gov/CMIP6.
DOI: 10.22033/esgf/cmip6.5468
title: MIROC MIROC6 model output prepared for CMIP6 DCPP dcppA-hindcast

description: Coupled Model Intercomparison Project Phase 6 (CMIP6) datasets: These data include all datasets published for 'CMIP6.DCPP.MIROC.MIROC6.dcppA-hindcast' with the full Data Reference Syntax following the template 'mip_era.activity_id.institution_id.source_id.experiment_id.member_id.table_id.variable_id.grid_label.version'.
 
 The MIROC6 climate model, released in 2017, includes the following components:
 aerosol: SPRINTARS6.0, atmos: CCSR AGCM (T85; 256 x 128 longitude/latitude; 81 levels; top level 0.004 hPa), land: MATSIRO6.0, ocean: COCO4.9 (tripolar primarily 1deg; 360 x 256 longitude/latitude; 63 levels; top grid cell 0-2 m), seaIce: COCO4.9. 
The model was run by the JAMSTEC (Japan Agency for Marine-Earth Science and Technology, Kanagawa 236-0001, Japan), AORI (Atmosphere and Ocean Research Institute, The University of Tokyo, Chiba 277-8564, Japan), NIES (National Institute for Environmental Studies, Ibaraki 305-8506, Japan), and R-CCS (RIKEN Center for Computational Science, Hyogo 650-0047, Japan) (MIROC) in native nominal resolutions: aerosol: 250 km, atmos: 250 km, land: 250 km, ocean: 100 km, seaIce: 100 km. 

Project: These data have been generated as part of the internationally-coordinated Coupled Model Intercomparison Project Phase 6 (CMIP6; see also GMD Special Issue: http://www.geosci-model-dev.net/special_issue590.html). The simulation data provides a basis for climate research designed to answer fundamental science questions and serves as resource for authors of the Sixth Assessment Report of the Intergovernmental Panel on Climate Change (IPCC-AR6).

CMIP6 is a project coordinated by the Working Group on Coupled Modelling (WGCM) as part of the World Climate Research Programme (WCRP). Phase 6 builds on previous phases executed under the leadership of the Program for Climate Model Diagnosis and Intercomparison (PCMDI) and relies on the Earth System Grid Federation (ESGF) and the Centre for Environmental Data Analysis (CEDA) along with numerous related activities for implementation. The original data is hosted and partially replicated on a federated collection of data nodes, and most of the data relied on by the IPCC is being archived for long-term preservation at the IPCC Data Distribution Centre (IPCC DDC) hosted by the German Climate Computing Center (DKRZ).

The project includes simulations from about 120 global climate models and around 45 institutions and organizations worldwide. - Project website: https://pcmdi.llnl.gov/CMIP6.
DOI: 10.22033/esgf/cmip6.5509
title: MIROC MIROC-ES2L model output prepared for CMIP6 CDRMIP esm-pi-CO2pulse

description: Coupled Model Intercomparison Project Phase 6 (CMIP6) datasets: These data include all datasets published for 'CMIP6.CDRMIP.MIROC.MIROC-ES2L.esm-pi-CO2pulse' with the full Data Reference Syntax following the template 'mip_era.activity_id.institution_id.source_id.experiment_id.member_id.table_id.variable_id.grid_label.version'.
 
 The MIROC-ES2L climate model, released in 2018, includes the following components:
 aerosol: SPRINTARS6.0, atmos: CCSR AGCM (T42; 128 x 64 longitude/latitude; 40 levels; top level 3 hPa), land: MATSIRO6.0+VISIT-e ver.1.0, ocean: COCO4.9 (tripolar primarily 1deg; 360 x 256 longitude/latitude; 63 levels; top grid cell 0-2 m), ocnBgchem: OECO ver.2.0; NPZD-type with C/N/P/Fe/O cycles, seaIce: COCO4.9. 
The model was run by the JAMSTEC (Japan Agency for Marine-Earth Science and Technology, Kanagawa 236-0001, Japan), AORI (Atmosphere and Ocean Research Institute, The University of Tokyo, Chiba 277-8564, Japan), NIES (National Institute for Environmental Studies, Ibaraki 305-8506, Japan), and R-CCS (RIKEN Center for Computational Science, Hyogo 650-0047, Japan) (MIROC) in native nominal resolutions: aerosol: 500 km, atmos: 500 km, land: 500 km, ocean: 100 km, ocnBgchem: 100 km, seaIce: 100 km. 

Project: These data have been generated as part of the internationally-coordinated Coupled Model Intercomparison Project Phase 6 (CMIP6; see also GMD Special Issue: http://www.geosci-model-dev.net/special_issue590.html). The simulation data provides a basis for climate research designed to answer fundamental science questions and serves as resource for authors of the Sixth Assessment Report of the Intergovernmental Panel on Climate Change (IPCC-AR6).

CMIP6 is a project coordinated by the Working Group on Coupled Modelling (WGCM) as part of the World Climate Research Programme (WCRP). Phase 6 builds on previous phases executed under the leadership of the Program for Climate Model Diagnosis and Intercomparison (PCMDI) and relies on the Earth System Grid Federation (ESGF) and the Centre for Environmental Data Analysis (CEDA) along with numerous related activities for implementation. The original data is hosted and partially replicated on a federated collection of data nodes, and most of the data relied on by the IPCC is being archived for long-term preservation at the IPCC Data Distribution Centre (IPCC DDC) hosted by the German Climate Computing Center (DKRZ).

The project includes simulations from about 120 global climate models and around 45 institutions and organizations worldwide. - Project website: https://pcmdi.llnl.gov/CMIP6.
DOI: 10.22033/esgf/cmip6.5510
title: MIROC MIROC-ES2L model output prepared for CMIP6 CDRMIP esm-pi-cdr-pulse

description: Coupled Model Intercomparison Project Phase 6 (CMIP6) datasets: These data include all datasets published for 'CMIP6.CDRMIP.MIROC.MIROC-ES2L.esm-pi-cdr-pulse' with the full Data Reference Syntax following the template 'mip_era.activity_id.institution_id.source_id.experiment_id.member_id.table_id.variable_id.grid_label.version'.
 
 The MIROC-ES2L climate model, released in 2018, includes the following components:
 aerosol: SPRINTARS6.0, atmos: CCSR AGCM (T42; 128 x 64 longitude/latitude; 40 levels; top level 3 hPa), land: MATSIRO6.0+VISIT-e ver.1.0, ocean: COCO4.9 (tripolar primarily 1deg; 360 x 256 longitude/latitude; 63 levels; top grid cell 0-2 m), ocnBgchem: OECO ver.2.0; NPZD-type with C/N/P/Fe/O cycles, seaIce: COCO4.9. 
The model was run by the JAMSTEC (Japan Agency for Marine-Earth Science and Technology, Kanagawa 236-0001, Japan), AORI (Atmosphere and Ocean Research Institute, The University of Tokyo, Chiba 277-8564, Japan), NIES (National Institute for Environmental Studies, Ibaraki 305-8506, Japan), and R-CCS (RIKEN Center for Computational Science, Hyogo 650-0047, Japan) (MIROC) in native nominal resolutions: aerosol: 500 km, atmos: 500 km, land: 500 km, ocean: 100 km, ocnBgchem: 100 km, seaIce: 100 km. 

Project: These data have been generated as part of the internationally-coordinated Coupled Model Intercomparison Project Phase 6 (CMIP6; see also GMD Special Issue: http://www.geosci-model-dev.net/special_issue590.html). The simulation data provides a basis for climate research designed to answer fundamental science questions and serves as resource for authors of the Sixth Assessment Report of the Intergovernmental Panel on Climate Change (IPCC-AR6).

CMIP6 is a project coordinated by the Working Group on Coupled Modelling (WGCM) as part of the World Climate Research Programme (WCRP). Phase 6 builds on previous phases executed under the leadership of the Program for Climate Model Diagnosis and Intercomparison (PCMDI) and relies on the Earth System Grid Federation (ESGF) and the Centre for Environmental Data Analysis (CEDA) along with numerous related activities for implementation. The original data is hosted and partially replicated on a federated collection of data nodes, and most of the data relied on by the IPCC is being archived for long-term preservation at the IPCC Data Distribution Centre (IPCC DDC) hosted by the German Climate Computing Center (DKRZ).

The project includes simulations from about 120 global climate models and around 45 institutions and organizations worldwide. - Project website: https://pcmdi.llnl.gov/CMIP6.
DOI: 10.22033/esgf/cmip6.5525
title: MIROC MIROC-ES2L model output prepared for CMIP6 CDRMIP esm-ssp534-over

description: Coupled Model Intercomparison Project Phase 6 (CMIP6) datasets: These data include all datasets published for 'CMIP6.CDRMIP.MIROC.MIROC-ES2L.esm-ssp534-over' with the full Data Reference Syntax following the template 'mip_era.activity_id.institution_id.source_id.experiment_id.member_id.table_id.variable_id.grid_label.version'.
 
 The MIROC-ES2L climate model, released in 2018, includes the following components:
 aerosol: SPRINTARS6.0, atmos: CCSR AGCM (T42; 128 x 64 longitude/latitude; 40 levels; top level 3 hPa), land: MATSIRO6.0+VISIT-e ver.1.0, ocean: COCO4.9 (tripolar primarily 1deg; 360 x 256 longitude/latitude; 63 levels; top grid cell 0-2 m), ocnBgchem: OECO ver.2.0; NPZD-type with C/N/P/Fe/O cycles, seaIce: COCO4.9. 
The model was run by the JAMSTEC (Japan Agency for Marine-Earth Science and Technology, Kanagawa 236-0001, Japan), AORI (Atmosphere and Ocean Research Institute, The University of Tokyo, Chiba 277-8564, Japan), NIES (National Institute for Environmental Studies, Ibaraki 305-8506, Japan), and R-CCS (RIKEN Center for Computational Science, Hyogo 650-0047, Japan) (MIROC) in native nominal resolutions: aerosol: 500 km, atmos: 500 km, land: 500 km, ocean: 100 km, ocnBgchem: 100 km, seaIce: 100 km. 

Project: These data have been generated as part of the internationally-coordinated Coupled Model Intercomparison Project Phase 6 (CMIP6; see also GMD Special Issue: http://www.geosci-model-dev.net/special_issue590.html). The simulation data provides a basis for climate research designed to answer fundamental science questions and serves as resource for authors of the Sixth Assessment Report of the Intergovernmental Panel on Climate Change (IPCC-AR6).

CMIP6 is a project coordinated by the Working Group on Coupled Modelling (WGCM) as part of the World Climate Research Programme (WCRP). Phase 6 builds on previous phases executed under the leadership of the Program for Climate Model Diagnosis and Intercomparison (PCMDI) and relies on the Earth System Grid Federation (ESGF) and the Centre for Environmental Data Analysis (CEDA) along with numerous related activities for implementation. The original data is hosted and partially replicated on a federated collection of data nodes, and most of the data relied on by the IPCC is being archived for long-term preservation at the IPCC Data Distribution Centre (IPCC DDC) hosted by the German Climate Computing Center (DKRZ).

The project includes simulations from about 120 global climate models and around 45 institutions and organizations worldwide. - Project website: https://pcmdi.llnl.gov/CMIP6.
DOI: 10.22033/esgf/cmip6.5536
title: MIROC MIROC6 model output prepared for CMIP6 FAFMIP faf-all

description: Coupled Model Intercomparison Project Phase 6 (CMIP6) datasets: These data include all datasets published for 'CMIP6.FAFMIP.MIROC.MIROC6.faf-all' with the full Data Reference Syntax following the template 'mip_era.activity_id.institution_id.source_id.experiment_id.member_id.table_id.variable_id.grid_label.version'.
 
 The MIROC6 climate model, released in 2017, includes the following components:
 aerosol: SPRINTARS6.0, atmos: CCSR AGCM (T85; 256 x 128 longitude/latitude; 81 levels; top level 0.004 hPa), land: MATSIRO6.0, ocean: COCO4.9 (tripolar primarily 1deg; 360 x 256 longitude/latitude; 63 levels; top grid cell 0-2 m), seaIce: COCO4.9. 
The model was run by the JAMSTEC (Japan Agency for Marine-Earth Science and Technology, Kanagawa 236-0001, Japan), AORI (Atmosphere and Ocean Research Institute, The University of Tokyo, Chiba 277-8564, Japan), NIES (National Institute for Environmental Studies, Ibaraki 305-8506, Japan), and R-CCS (RIKEN Center for Computational Science, Hyogo 650-0047, Japan) (MIROC) in native nominal resolutions: aerosol: 250 km, atmos: 250 km, land: 250 km, ocean: 100 km, seaIce: 100 km. 

Project: These data have been generated as part of the internationally-coordinated Coupled Model Intercomparison Project Phase 6 (CMIP6; see also GMD Special Issue: http://www.geosci-model-dev.net/special_issue590.html). The simulation data provides a basis for climate research designed to answer fundamental science questions and serves as resource for authors of the Sixth Assessment Report of the Intergovernmental Panel on Climate Change (IPCC-AR6).

CMIP6 is a project coordinated by the Working Group on Coupled Modelling (WGCM) as part of the World Climate Research Programme (WCRP). Phase 6 builds on previous phases executed under the leadership of the Program for Climate Model Diagnosis and Intercomparison (PCMDI) and relies on the Earth System Grid Federation (ESGF) and the Centre for Environmental Data Analysis (CEDA) along with numerous related activities for implementation. The original data is hosted and partially replicated on a federated collection of data nodes, and most of the data relied on by the IPCC is being archived for long-term preservation at the IPCC Data Distribution Centre (IPCC DDC) hosted by the German Climate Computing Center (DKRZ).

The project includes simulations from about 120 global climate models and around 45 institutions and organizations worldwide. - Project website: https://pcmdi.llnl.gov/CMIP6.
DOI: 10.22033/esgf/cmip6.5537
title: MIROC MIROC6 model output prepared for CMIP6 FAFMIP faf-heat

description: Coupled Model Intercomparison Project Phase 6 (CMIP6) datasets: These data include all datasets published for 'CMIP6.FAFMIP.MIROC.MIROC6.faf-heat' with the full Data Reference Syntax following the template 'mip_era.activity_id.institution_id.source_id.experiment_id.member_id.table_id.variable_id.grid_label.version'.
 
 The MIROC6 climate model, released in 2017, includes the following components:
 aerosol: SPRINTARS6.0, atmos: CCSR AGCM (T85; 256 x 128 longitude/latitude; 81 levels; top level 0.004 hPa), land: MATSIRO6.0, ocean: COCO4.9 (tripolar primarily 1deg; 360 x 256 longitude/latitude; 63 levels; top grid cell 0-2 m), seaIce: COCO4.9. 
The model was run by the JAMSTEC (Japan Agency for Marine-Earth Science and Technology, Kanagawa 236-0001, Japan), AORI (Atmosphere and Ocean Research Institute, The University of Tokyo, Chiba 277-8564, Japan), NIES (National Institute for Environmental Studies, Ibaraki 305-8506, Japan), and R-CCS (RIKEN Center for Computational Science, Hyogo 650-0047, Japan) (MIROC) in native nominal resolutions: aerosol: 250 km, atmos: 250 km, land: 250 km, ocean: 100 km, seaIce: 100 km. 

Project: These data have been generated as part of the internationally-coordinated Coupled Model Intercomparison Project Phase 6 (CMIP6; see also GMD Special Issue: http://www.geosci-model-dev.net/special_issue590.html). The simulation data provides a basis for climate research designed to answer fundamental science questions and serves as resource for authors of the Sixth Assessment Report of the Intergovernmental Panel on Climate Change (IPCC-AR6).

CMIP6 is a project coordinated by the Working Group on Coupled Modelling (WGCM) as part of the World Climate Research Programme (WCRP). Phase 6 builds on previous phases executed under the leadership of the Program for Climate Model Diagnosis and Intercomparison (PCMDI) and relies on the Earth System Grid Federation (ESGF) and the Centre for Environmental Data Analysis (CEDA) along with numerous related activities for implementation. The original data is hosted and partially replicated on a federated collection of data nodes, and most of the data relied on by the IPCC is being archived for long-term preservation at the IPCC Data Distribution Centre (IPCC DDC) hosted by the German Climate Computing Center (DKRZ).

The project includes simulations from about 120 global climate models and around 45 institutions and organizations worldwide. - Project website: https://pcmdi.llnl.gov/CMIP6.