cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.6084/m9.figshare.7743320.v1
title: Reduction Potential of RuIII-Based Complexes with Potential Antitumor Activity and Thermodynamics of their Hydrolysis Reactions and Interactions with Possible Biological Targets: a Theoretical Investigation

description: In this article density functional theory (DFT)-based calculations were employed to investigate the electrochemistry of the antitumor ruthenium complexes trans-tetrachloro(dimethylsulfoxide)imidazole ruthenate(III) (NAMI-A) and trans-[tetrachlorobis(1.-indazole)ruthenate(III)] (KP1019), their hydrolysis products as well as their interactions with biological S-donors and N-donors targets as cysteine, glutathione and guanine nucleobase. The compounds exhibit different electrochemical behavior upon hydrolysis. While the reduction potential of NAMI-A increases up to 0.8 V upon hydrolysis, the reduction potential of KP1019 remains almost constant after the first hydrolysis. NAMI-A and KP1019 complexes have thermodynamic preference to be reduced prior to undergoing hydrolysis and, strong preference to undergo successive hydrolysis instead of interacting with the S-donor and N-donor ligands. Interaction with S-donor ligands in the unprotonated form is highly unfavorable, with the free energy in solution (ΔGsol) ≥ 18 kcal mol-1. For both complexes, the interaction with the guanine and glutathione are of the same magnitude (ΔGsol ca. –0.6 kcal mol-1) meaning that these ligands can compete for binding to the metallodrug.
DOI: 10.6084/m9.figshare.7743308
title: Interference of Noxious Shrubs on Grazing Behavior by Bovines

description: ABSTRACT: The grazing behavior practice by bovines can be positive or negatively influenced by the pasture structure where the animal is inserted. Several factors determine the pasture structure and the presence of weeds is considered one of the most important. This study aimed to assess the effect of species with and without stiff structures over the grazing behavior of bovines in pasture areas. The experimental design was a split block design with four replications, in which treatments were arranged in a 4 x 3 factorial design: four weed species (Zanthoxylum rhoifolium, Cnidoscolus urens, Dasyphyllum brasiliensis, and Luehea divaricata) associated with three proximity strips of weeds: 0-50, 50-100, and 100-150 cm in relation to the main stem of the studied weed. Forage intake by animals was measured by determining the real forage offers at 0, 3, 6, 9, and 15 days after the beginning of animal grazing (DAP). The presence of noxious shrubs influenced bovine grazing behavior. The influence on the intake is most evident in the presence of plants that promote animal discomfort. The species Z. rhoifolium, C. urens, and D. brasiliensis were the weeds with the greatest influence on feed access among the species that have stiff structures. The negative influence on grazing behavior is higher in the proximity strip closest to the plant, i.e. 0-50 cm from the main stem of the weed.
DOI: 10.6084/m9.figshare.7743329.v1
title: Rates of Nicosulfuron Applied in Glyphosate-Tolerant and Sulfonylurea-Tolerant Soybean

description: ABSTRACT: STS cultivars tolerate up to four times higher rates of chlorimuron than those recommended for non-tolerant cultivars, without significant damage. However, few studies position the selectivity of nicosulfuron in STS cultivars. The aim of this study was to assess the selectivity of rates of the herbicide nicosulfuron applied in the post-emergence (V4) of RR/STS soybean. The experiments were conducted in the 2015/16 and 2016/17 seasons in Piracicaba, SP. In the 2016/17 season, the experiment was also conducted in Palotina, PR. Treatments consisted of six rates of the herbicide nicosulfuron (0, 50, 100, 150, 200, and 250 g a.i. ha-1). The experimental design was a randomized block design with four replications. The symptoms of injury were assessed at 7, 14, 21, and 28 days after application, as well as the assessment of variables related to the agronomic performance (plant height, number of pods per plant, yield, and one thousand-grain weight). The data were submitted to regression analysis (p&lt;0.05). The estimated rates reduced yield by 5% in relation to the rate 0 and were between 57.79 and 68.37 g a.i. ha-1. In general, the RR/STS soybean is tolerant to the application of nicosulfuron up to 57.79 g a.i. ha-1 when considering the estimated rates. Therefore, the RR/STS soybean is tolerant to the application of nicosulfuron up to 50 g a.i. ha-1, according to the applied rates.
DOI: 10.7284/106640
title: Multibeam Echosounder data collected during research cruise AMAT03RR using a Kongsberg EM120 instrument system onboard the platform RV Roger Revelle

description: Original (unprocessed) data collected during a Field_expedition
DOI: 10.6084/m9.figshare.7743311.v1
title: Temperature Dependence of Electrical Resistance in Ge-Sb-Te Thin Films

description: Nowadays, the Ge-Sb-Te system is studied extensively for use in the field of both electrical and optical non-volatile memories. The key of this application is based on the changes in the physical properties (electrical conductivity or refractive index) of these films as a result of structural transformation between amorphous and crystalline states. Both states are highly stable and it is relatively easy to change between them when they are prepared as thin films. In this work, structural and electrical behaviours with the temperature of thin films with compositions Ge13Sb5Te82, Ge1Sb2Te4, Ge2Sb2Te5, Ge1Sb4Te7 and Sb70Te30 (atomic fraction) were studied. Films were obtained by pulsed laser deposition (PLD) using a pulsed Nd:YAG laser (λ = 355 nm) and they were structurally characterized by X-ray diffraction. Temperature dependence of electrical resistance was studied for these films from room temperature to 520 K at a heating rate about 3 K/min. During crystallization, their electrical resistance falls several orders of magnitude in a narrow temperature range. The electrical conduction activation energies of the amorphous and crystalline states and the crystallization temperature were determined. The crystallization products were characterized by X-ray diffraction. The results were compared with those obtained by other authors.
DOI: 10.6084/m9.figshare.7743302
title: Growth and gas changes of melon seedlings submitted to water salinity

description: ABSTRACT The melon is an outstanding fruit crop in Brazil, mainly in the Northeast region due to favorable conditions for cultivation. Water salinity affects the growth and production of several species, but there is tolerance among cultivars of the same species. The objective of this study was to evaluate the growth and gas exchange in melon seedlings subjected to water salinity. Experiment was carried out in a greenhouse belonging to the Center of Sciences and Agri-Food Technology, Federal University of Campina Grande, Pombal, PB, Brazil, from September to October 2016. The experimental design was a randomized complete block design in a 6 x 5 factorial scheme, with four replicates, for six cultivars of melon (Natal, Solares, Goldex, Iracema, Mandacaru and Amarelo Ouro) and five irrigation water salinity levels with the following electrical conductivities: 0.3, 1.1, 1.9, 2.7 and 3.5 dS m-1. Each experimental unit consisted of a polypropylene container with a volume capacity of 0.350 dm3, which contained soil + Basaplant® commercial substrate at a ratio of 2:1. At 25 days after sowing, the plants were evaluated for growth, gas exchange and dry mass accumulation. Increased salinity of irrigation water inhibits the growth, dry mass accumulation and physiological processes of melon cultivars. The cultivar Natal showed to be more tolerant, while the cultivars Solares, Goldex, Iracema and Mandacaru were moderately sensitive and the cultivar Amarelo Ouro was more sensitive to the salinity of irrigation water.
DOI: 10.6084/m9.figshare.7743299
title: PEEK Physical Surface Modification: Evaluation Of Particles Leaching Process

description: Polyetheretherketone (PEEK) has been prominent in orthopedic implants; however, it is inert, preventing interaction between the implant and adjacent bone tissues. One way to overcome this characteristic is physical modification its on surface by particle leaching promoting greater osseointegration. The objective of this research was to develop and characterize the PEEK using a surface modification technique via particle leaching. For of the samples, a layer deposition of NaCl was used on PEEK. This was subjected to the pressure of 850 kg/cm2 by 390ºC for 20 minutes. After cooling, were subjected to leaching process particles. The results indicated a porous surface exhibiting uniform and homogeneous morphology with defined pores interconected, to in the range of 140-373 µm, with an average diameter of 273 µm. These evidenced the considerable NaCl removal after the leaching process, with cavities from ideal sizes which promotes adequate cellular accommodation and distinct roughness, giving an overall possibility of being able to obtain a material more able to receive the cells while also possibly presenting cell viability. Although the compressive strength presented low values, it can still be suitable for applications in areas with a reduced modulus of elasticity.
DOI: 10.6084/m9.figshare.7743302.v1
title: Growth and gas changes of melon seedlings submitted to water salinity

description: ABSTRACT The melon is an outstanding fruit crop in Brazil, mainly in the Northeast region due to favorable conditions for cultivation. Water salinity affects the growth and production of several species, but there is tolerance among cultivars of the same species. The objective of this study was to evaluate the growth and gas exchange in melon seedlings subjected to water salinity. Experiment was carried out in a greenhouse belonging to the Center of Sciences and Agri-Food Technology, Federal University of Campina Grande, Pombal, PB, Brazil, from September to October 2016. The experimental design was a randomized complete block design in a 6 x 5 factorial scheme, with four replicates, for six cultivars of melon (Natal, Solares, Goldex, Iracema, Mandacaru and Amarelo Ouro) and five irrigation water salinity levels with the following electrical conductivities: 0.3, 1.1, 1.9, 2.7 and 3.5 dS m-1. Each experimental unit consisted of a polypropylene container with a volume capacity of 0.350 dm3, which contained soil + Basaplant® commercial substrate at a ratio of 2:1. At 25 days after sowing, the plants were evaluated for growth, gas exchange and dry mass accumulation. Increased salinity of irrigation water inhibits the growth, dry mass accumulation and physiological processes of melon cultivars. The cultivar Natal showed to be more tolerant, while the cultivars Solares, Goldex, Iracema and Mandacaru were moderately sensitive and the cultivar Amarelo Ouro was more sensitive to the salinity of irrigation water.
DOI: 10.6084/m9.figshare.7743308.v1
title: Interference of Noxious Shrubs on Grazing Behavior by Bovines

description: ABSTRACT: The grazing behavior practice by bovines can be positive or negatively influenced by the pasture structure where the animal is inserted. Several factors determine the pasture structure and the presence of weeds is considered one of the most important. This study aimed to assess the effect of species with and without stiff structures over the grazing behavior of bovines in pasture areas. The experimental design was a split block design with four replications, in which treatments were arranged in a 4 x 3 factorial design: four weed species (Zanthoxylum rhoifolium, Cnidoscolus urens, Dasyphyllum brasiliensis, and Luehea divaricata) associated with three proximity strips of weeds: 0-50, 50-100, and 100-150 cm in relation to the main stem of the studied weed. Forage intake by animals was measured by determining the real forage offers at 0, 3, 6, 9, and 15 days after the beginning of animal grazing (DAP). The presence of noxious shrubs influenced bovine grazing behavior. The influence on the intake is most evident in the presence of plants that promote animal discomfort. The species Z. rhoifolium, C. urens, and D. brasiliensis were the weeds with the greatest influence on feed access among the species that have stiff structures. The negative influence on grazing behavior is higher in the proximity strip closest to the plant, i.e. 0-50 cm from the main stem of the weed.
DOI: 10.6084/m9.figshare.7743293
title: Temporal and spatial distribution of American tegumentary leishmaniasis in north Paraná: 2010-2015

description: Abstract INTRODUCTION: Describing the general aspects of American tegumentary leishmaniasis enables the identification of the epidemiological scenario of the disease and the development of preventive actions. METHODS: We analyzed the records of patients with American tegumentary leishmaniasis in north Paraná between 2010 and 2015. RESULTS: We identified 108 cases (mostly in 2014) with the following characteristics: male individuals, rural workers, and ages averaging 56.8 years. Isolated ulcerated lesions were predominant, and Glucantime® was the most frequently used drug. CONCLUSIONS: American tegumentary leishmaniasis remains endemic and affects mostly men found in areas surrounded by woods; its treatment is partially efficient considering its side effects and incidence of recurrences.
DOI: 10.6084/m9.figshare.7743296
title: Production and quality of okra produced with mineral and organic fertilization

description: ABSTRACT Okra, Abelmoschus esculentus (L.) Moench, is a vegetable with annual fruit native to hot regions of Africa, well adapted to the conditions of the Northeast and Southeast regions of Brazil, where it is widely used by small farmers. This study aimed to evaluate the effect of mineral and organic fertilization on the production and quality of okra fruits. The experiment was conducted in randomized block design, with three replicates and eleven treatments defined according to a Baconian matrix. Treatments consisted of doses of N (0, 100, 200 and 300 kg ha-1), P (0, 100, 200 and 300 kg ha-1) and K (0, 80, 160 and 240 kg ha-1), as well as absence and presence of organic compost (30 t ha-1). The following parameters were evaluated: plant height, stem diameter, number of leaves, production of fruits plant-1, number of fruits plant-1, fruit length and diameter and fruit quality (pH, soluble solids, titratable acidity, vitamin C and electrical conductivity). The crop is demanding in terms of K and N fertilizations, with increments of 15.8 and 36% in the mean number and diameter of fruits, respectively. Organic fertilization did not influence the vegetative growth of okra, but was beneficial to the production of fruits with higher vitamin C content, 52% higher than the contents found in fruits produced without such input.
DOI: 10.7284/106641
title: Singlebeam Echosounder data collected during research cruise AMAT03RR using a Knudsen 320B/R instrument system onboard the platform RV Roger Revelle

description: Original (unprocessed) data collected during a Field_expedition
DOI: 10.6084/m9.figshare.7743290
title: Criteria for Decision Making and Economic Threshold Level for Wild Radish in Wheat Crop

description: ABSTRACT: Weed competition limits wheat yield by reducing the availability of essential resources for its growth and development. In this sense, this study aimed to estimate the economic threshold level (ETL) of wild radish (Raphanus raphanistrum) in competition with wheat cultivars. Treatments were arranged in a factorial scheme. The factor wheat cultivar consisted of early (BRS 328), medium (BRS 177), and late (BRS Umbu) cycles and the factor wild radish population ranged from 0 to 564 plants m-2 (10 populations) for the cultivar BRS 328, 0 to 472 plants m-2 for the cultivar BRS 177 (11 populations), and 0 to 724 plants m-2 for the cultivar BRS Umbu (10 populations). The early-cycle BRS 328 presented a higher competitive ability when compared to the medium-cycle BRS 177 and late-cycle BRS Umbu. Yield losses of wheat grains due to wild radish interference can be satisfactorily estimated by the rectangular hyperbola model using the variables plant population, shoot dry matter, soil cover, and leaf area of the weed. ETL values varied as a function of the cultivar cycle, being higher for the cultivar BRS 328 (early) &gt; BRS 177 (medium) &gt; BRS Umbu (late). Wild radish is competitive in wheat crop, requiring at least 1.6 plants m-2 for control to be justified.
DOI: 10.6084/m9.figshare.7743296.v1
title: Production and quality of okra produced with mineral and organic fertilization

description: ABSTRACT Okra, Abelmoschus esculentus (L.) Moench, is a vegetable with annual fruit native to hot regions of Africa, well adapted to the conditions of the Northeast and Southeast regions of Brazil, where it is widely used by small farmers. This study aimed to evaluate the effect of mineral and organic fertilization on the production and quality of okra fruits. The experiment was conducted in randomized block design, with three replicates and eleven treatments defined according to a Baconian matrix. Treatments consisted of doses of N (0, 100, 200 and 300 kg ha-1), P (0, 100, 200 and 300 kg ha-1) and K (0, 80, 160 and 240 kg ha-1), as well as absence and presence of organic compost (30 t ha-1). The following parameters were evaluated: plant height, stem diameter, number of leaves, production of fruits plant-1, number of fruits plant-1, fruit length and diameter and fruit quality (pH, soluble solids, titratable acidity, vitamin C and electrical conductivity). The crop is demanding in terms of K and N fertilizations, with increments of 15.8 and 36% in the mean number and diameter of fruits, respectively. Organic fertilization did not influence the vegetative growth of okra, but was beneficial to the production of fruits with higher vitamin C content, 52% higher than the contents found in fruits produced without such input.
DOI: 10.6084/m9.figshare.7743284
title: Large-Scale Spatial and Temporal Variability of Larval Fish Assemblages in the Tropical Atlantic Ocean

description: Abstract This study investigated the large-scale spatial and temporal variability of larval fish assemblages in the west tropical Atlantic Ocean. The sampling was performed during four expeditions. Identification resulted in 100 taxa (64 families, 19 orders and 17 suborders). During the four periods, 80% of the total larvae taken represented eight characteristics families (Scombridae, Carangidae, Paralepididae, Bothidae, Gonostomatidae, Scaridae, Gobiidae and Myctophidae). Fish larvae showed a rather heterogeneous distribution with density at each station ranging from 0.5 to 2000 larvae per 100m3. A general trend was observed, lower densities at oceanic area and higher densities in the seamounts and islands. A gradient in temperature, salinity, phytoplankton biomass, zooplankton biomass and station depth was strongly correlated with changes in ichthyoplankton structure. Myctophidae, and Paralepididae presented increased abundance at high salinities and temperatures. Bothidae and Gobiidae were more abundant at higher phytoplankton biomass and zooplankton biomass. Scaridae, Scombridae and Gonostomatidae had higher abundances at deep offshore stations. Different events might be responsible for the formation, maintenance and breakdown of fish larvae assemblage in the tropical oceanic area of Brazil. The results suggested that the oceanographic variables (temperature, salinity, phytoplankton biomass, zooplankton biomass and station depth) played an important role on the distribution patterns of ichthyoplankton.
DOI: 10.6084/m9.figshare.7743287
title: Leaching of Imidazolinones in Irrigation Systems in Rice Cultivation: Sprinkling and Flooding

description: ABSTRACT: Herbicides of the imidazolinone group have been used in irrigated rice and presented a long persistence in the soil, especially in floodplain areas with a low drainage, and could cause environmental contamination. This study aims to evaluate the leaching and residual of herbicides belonging to the imidazolinone group in sprinkler and flood irrigation systems. The experiment was carried out under greenhouse conditions, with the application of the herbicides imazethapyr, imazethapyr + imazapic, and imazapyr + imazapic in soil irrigated by flooding and sprinkling. Subsequently, the soil was collected from the layers of 0-5, 5-10, 10-15, 15-20, and 20-25 cm and packed in 500 mL capacity plastic pots in order to sow tomato as a bioindicator plant of the presence of the herbicides belonging to the imidazolinones. Phytotoxicity, length, and shoot dry matter mass of tomato plants were evaluated at 10 and 20 days after emergence. The herbicides of the imidazolinone chemical group presented a high potential for leaching and persistence with effects for more than 180 days after application. Based on the symptoms presented by the sensitive crop, the degradation of imazethapyr, imazethapyr + imazapic, and imazapyr + imazapic in the 0-15 cm layers was higher in soil with sprinkler irrigation when compared to flood irrigation. Thus, non-flooded soils present a greater capacity to degrade the herbicides belonging to the imidazolinone chemical group.
DOI: 10.7284/106638
title: Winch data collected during research cruise AMAT03RR using a Markey DUTW-9-11 instrument system onboard the platform RV Roger Revelle

description: Original (unprocessed) data collected during a Field_expedition
DOI: 10.6084/m9.figshare.7743287.v1
title: Leaching of Imidazolinones in Irrigation Systems in Rice Cultivation: Sprinkling and Flooding

description: ABSTRACT: Herbicides of the imidazolinone group have been used in irrigated rice and presented a long persistence in the soil, especially in floodplain areas with a low drainage, and could cause environmental contamination. This study aims to evaluate the leaching and residual of herbicides belonging to the imidazolinone group in sprinkler and flood irrigation systems. The experiment was carried out under greenhouse conditions, with the application of the herbicides imazethapyr, imazethapyr + imazapic, and imazapyr + imazapic in soil irrigated by flooding and sprinkling. Subsequently, the soil was collected from the layers of 0-5, 5-10, 10-15, 15-20, and 20-25 cm and packed in 500 mL capacity plastic pots in order to sow tomato as a bioindicator plant of the presence of the herbicides belonging to the imidazolinones. Phytotoxicity, length, and shoot dry matter mass of tomato plants were evaluated at 10 and 20 days after emergence. The herbicides of the imidazolinone chemical group presented a high potential for leaching and persistence with effects for more than 180 days after application. Based on the symptoms presented by the sensitive crop, the degradation of imazethapyr, imazethapyr + imazapic, and imazapyr + imazapic in the 0-15 cm layers was higher in soil with sprinkler irrigation when compared to flood irrigation. Thus, non-flooded soils present a greater capacity to degrade the herbicides belonging to the imidazolinone chemical group.