DOI: 10.6084/m9.figshare.27266563
title: Rodingitization of Neoproterozoic Al-Barramiya ophiolite metagabbro in the Eastern Desert of Egypt, Arabian-Nubian Shield

description: The present work studies the rodingite that is recorded for the first time as being associated to Al-Barramiya Neoproterozoic ophiolite at Eastern Desert of Egypt, Arabian-Nubian Shield (ANS). Al-Barramiya ophiolite is one of the most important ophiolitic sequences exposed in the ANS. It is affected by different styles of alterations included carbonatization, listvenitization, chloritization and rodingitization. The Neoproterozoic ophiolitic rocks of Al-Barramiya district consists of serpentinized peridotite and metagabbros. Serpentinized peridotites are highly altered to assemblages of talc-carbonate rocks, listvenite and magnesite, while metagabbro is partly converted into rodingite. The field studies indicate that serpentinite and rodingite in Al-Barramiya area display high-strain cataclastic deformation. Rodingite consists of garnet, diopside, vesuvianite and chlorite with minor epidote, prehnite, actinolite and opaque minerals. The garnets and vesuvianite are mostly concentrated near the peripheries of the studied rodingite masses, while clinopyroxene, chlorite, epidote and prehnite gradually increase inwards due to progressive decreasing water/rock ratio as fluids originally buffered by serpentinite move towards equilibrium with gabbroic bulk chemistry. Some rodingite samples preserve a few relics of igneous textures of ophiolitic metagabbros. Garnets are distinguished into andradite, hydroandradite and grossular. Pyroxene is represented mainly by secondary clinopyroxene beside primary fresh relics of diopside; the latter has high Mg# (0.92–0.97) similar to ophiolitic clinopyroxene in the ANS. Rodingite is enriched in CaO, Fe<sub>2</sub>O<sub>3</sub> and MgO but depleted in SiO<sub>2</sub>, Al<sub>2</sub>O<sub>3</sub> and Na<sub>2</sub>O compared to associated metagabbro. The association of rodingite with serpentinites and metagabbros suggests that Al-Barramiya rodingite is genetically related to serpentinization of ultramafic rocks. The rodingitization occurred during ocean floor alteration contemporaneous with the serpentinization process. The superposition of cataclastic deformation on the altered rocks indicates that alteration preceded obduction and occurred on the seafloor of the suprasubduction zone where Al-Barramiya ophiolite was originally emplaced. During serpentinization the olivine in the peridotite broke down and released Mg<sup>2+</sup> in the metasomatic fluids and clinopyroxene broke down producing Ca-rich fluids. These fluids react with the mafic protoliths and enrich them in MgO and CaO. Also, serpentinization fluids react with the plagioclase of the metagabbro, releasing Ca from the mafic source and concentrated it in the rodingitized samples. The positive Eu anomalies beside high Sr contents of the rodingite can be inherited from a plagioclase-rich protolith such as ophiolitic metagabbro. The enrichment of rodingite in Th and U indicates two distinct solutions affected the gabbroic protolith because the alteration of depleted peridotite to serpentinite cannot be an efficient source to enrich these elements. The present study indicates that the rodingitization process underwent lower greenschist facies conditions associating metamorphism that caused serpentinization and released Ca-rich metasomatic fluids.