cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.17188/1316931
title: Materials Data on CaTcN3 by Materials Project

description: CaTcN3 is Aluminum carbonitride-like structured and crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. Ca2+ is bonded in a 6-coordinate geometry to six N3- atoms. There are a spread of Ca–N bond distances ranging from 2.40–2.64 Å. Tc7+ is bonded to five N3- atoms to form distorted TcN5 trigonal bipyramids that share a cornercorner with one NCa2TcN tetrahedra, corners with two equivalent TcN5 trigonal bipyramids, and edges with two equivalent TcN5 trigonal bipyramids. There are a spread of Tc–N bond distances ranging from 1.77–2.04 Å. There are three inequivalent N3- sites. In the first N3- site, N3- is bonded to three equivalent Ca2+ and one Tc7+ atom to form distorted NCa3Tc trigonal pyramids that share corners with nine NCaTc3 tetrahedra, corners with two equivalent NCa3Tc trigonal pyramids, edges with two NCaTc3 tetrahedra, and edges with two equivalent NCa3Tc trigonal pyramids. In the second N3- site, N3- is bonded to one Ca2+ and three equivalent Tc7+ atoms to form distorted NCaTc3 tetrahedra that share corners with seven NCaTc3 tetrahedra, corners with four equivalent NCa3Tc trigonal pyramids, edges with two equivalent NCaTc3 tetrahedra, and an edgeedge with one NCa3Tc trigonal pyramid. In the third N3- site, N3- is bonded to two equivalent Ca2+, one Tc7+, and one N3- atom to form distorted NCa2TcN tetrahedra that share corners with seven NCaTc3 tetrahedra, a cornercorner with one TcN5 trigonal bipyramid, corners with five equivalent NCa3Tc trigonal pyramids, and an edgeedge with one NCa3Tc trigonal pyramid. The N–N bond length is 1.28 Å.
DOI: 10.17188/1316932
title: Materials Data on Cs2KInF6 by Materials Project

description: Cs2KInF6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Cs1+ is bonded to twelve equivalent F1- atoms to form CsF12 cuboctahedra that share corners with twelve equivalent CsF12 cuboctahedra, faces with six equivalent CsF12 cuboctahedra, faces with four equivalent KF6 octahedra, and faces with four equivalent InF6 octahedra. All Cs–F bond lengths are 3.35 Å. K1+ is bonded to six equivalent F1- atoms to form KF6 octahedra that share corners with six equivalent InF6 octahedra and faces with eight equivalent CsF12 cuboctahedra. The corner-sharing octahedral tilt angles are 0°. All K–F bond lengths are 2.61 Å. In3+ is bonded to six equivalent F1- atoms to form InF6 octahedra that share corners with six equivalent KF6 octahedra and faces with eight equivalent CsF12 cuboctahedra. The corner-sharing octahedral tilt angles are 0°. All In–F bond lengths are 2.12 Å. F1- is bonded in a distorted linear geometry to four equivalent Cs1+, one K1+, and one In3+ atom.
DOI: 10.17188/1316933
title: Materials Data on YTcN3 by Materials Project

description: YTcN3 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. there are two inequivalent Y3+ sites. In the first Y3+ site, Y3+ is bonded to six N3- atoms to form YN6 octahedra that share corners with six equivalent TcN4 tetrahedra, edges with two equivalent YN6 octahedra, and edges with three equivalent YN6 pentagonal pyramids. There are a spread of Y–N bond distances ranging from 2.29–2.48 Å. In the second Y3+ site, Y3+ is bonded to six N3- atoms to form distorted YN6 pentagonal pyramids that share corners with four equivalent TcN4 tetrahedra, edges with three equivalent YN6 octahedra, and edges with two equivalent TcN4 tetrahedra. There are a spread of Y–N bond distances ranging from 2.37–2.46 Å. Tc6+ is bonded to four N3- atoms to form TcN4 tetrahedra that share corners with three equivalent YN6 octahedra, corners with two equivalent YN6 pentagonal pyramids, corners with two equivalent TcN4 tetrahedra, and an edgeedge with one YN6 pentagonal pyramid. The corner-sharing octahedra tilt angles range from 29–67°. There are a spread of Tc–N bond distances ranging from 1.79–1.89 Å. There are three inequivalent N3- sites. In the first N3- site, N3- is bonded to three Y3+ and one Tc6+ atom to form a mixture of distorted edge and corner-sharing NY3Tc tetrahedra. In the second N3- site, N3- is bonded in a distorted T-shaped geometry to two Y3+ and one Tc6+ atom. In the third N3- site, N3- is bonded in a 3-coordinate geometry to one Y3+ and two equivalent Tc6+ atoms.
DOI: 10.17188/1316934
title: Materials Data on LaOsN3 by Materials Project

description: LaOsN3 crystallizes in the monoclinic P2_1/m space group. The structure is one-dimensional and consists of two LaOsN3 ribbons oriented in the (1, 0, 0) direction. La3+ is bonded in a 1-coordinate geometry to one N3- atom. The La–N bond length is 2.47 Å. Os6+ is bonded in a T-shaped geometry to three N3- atoms. There are a spread of Os–N bond distances ranging from 1.91–2.02 Å. There are three inequivalent N3- sites. In the first N3- site, N3- is bonded in a 2-coordinate geometry to one Os6+ and one N3- atom. The N–N bond length is 1.24 Å. In the second N3- site, N3- is bonded in a distorted linear geometry to two equivalent Os6+ atoms. In the third N3- site, N3- is bonded in a 2-coordinate geometry to one La3+ and one N3- atom.
DOI: 10.17188/1316935
title: Materials Data on Cs2NaAlH6 by Materials Project

description: Cs2NaAlH6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Cs1+ is bonded to twelve equivalent H1- atoms to form CsH12 cuboctahedra that share corners with twelve equivalent CsH12 cuboctahedra, faces with six equivalent CsH12 cuboctahedra, faces with four equivalent NaH6 octahedra, and faces with four equivalent AlH6 octahedra. All Cs–H bond lengths are 3.07 Å. Na1+ is bonded to six equivalent H1- atoms to form NaH6 octahedra that share corners with six equivalent AlH6 octahedra and faces with eight equivalent CsH12 cuboctahedra. The corner-sharing octahedral tilt angles are 0°. All Na–H bond lengths are 2.51 Å. Al3+ is bonded to six equivalent H1- atoms to form AlH6 octahedra that share corners with six equivalent NaH6 octahedra and faces with eight equivalent CsH12 cuboctahedra. The corner-sharing octahedral tilt angles are 0°. All Al–H bond lengths are 1.80 Å. H1- is bonded in a 2-coordinate geometry to four equivalent Cs1+, one Na1+, and one Al3+ atom.
DOI: 10.17188/1316936
title: Materials Data on LaCoN3 by Materials Project

description: LaCoN3 crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. La3+ is bonded in a 5-coordinate geometry to five N+1.67- atoms. There are a spread of La–N bond distances ranging from 2.42–2.81 Å. Co2+ is bonded in a distorted trigonal planar geometry to three N+1.67- atoms. There are a spread of Co–N bond distances ranging from 1.68–1.91 Å. There are three inequivalent N+1.67- sites. In the first N+1.67- site, N+1.67- is bonded to three equivalent La3+ and two equivalent Co2+ atoms to form a mixture of edge and corner-sharing NLa3Co2 trigonal bipyramids. In the second N+1.67- site, N+1.67- is bonded in a 1-coordinate geometry to one Co2+ and one N+1.67- atom. The N–N bond length is 1.18 Å. In the third N+1.67- site, N+1.67- is bonded in a 3-coordinate geometry to two equivalent La3+ and one N+1.67- atom.
DOI: 10.17188/1316937
title: Materials Data on Cs2NaCaCl6 by Materials Project

description: Cs2NaCaCl6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Cs is bonded to twelve equivalent Cl atoms to form CsCl12 cuboctahedra that share corners with twelve equivalent CsCl12 cuboctahedra, faces with six equivalent CsCl12 cuboctahedra, faces with four equivalent NaCl6 octahedra, and faces with four equivalent CaCl6 octahedra. All Cs–Cl bond lengths are 3.87 Å. Na is bonded to six equivalent Cl atoms to form NaCl6 octahedra that share corners with six equivalent CaCl6 octahedra and faces with eight equivalent CsCl12 cuboctahedra. The corner-sharing octahedral tilt angles are 0°. All Na–Cl bond lengths are 2.76 Å. Ca is bonded to six equivalent Cl atoms to form CaCl6 octahedra that share corners with six equivalent NaCl6 octahedra and faces with eight equivalent CsCl12 cuboctahedra. The corner-sharing octahedral tilt angles are 0°. All Ca–Cl bond lengths are 2.72 Å. Cl is bonded in a distorted linear geometry to four equivalent Cs, one Na, and one Ca atom.
DOI: 10.17188/1316938
title: Materials Data on YWN3 by Materials Project

description: YWN3 crystallizes in the monoclinic P2_1/m space group. The structure is three-dimensional. Y3+ is bonded in a 6-coordinate geometry to six N3- atoms. There are a spread of Y–N bond distances ranging from 2.36–2.43 Å. W6+ is bonded to five N3- atoms to form a mixture of distorted edge and corner-sharing WN5 trigonal bipyramids. There are a spread of W–N bond distances ranging from 1.85–2.19 Å. There are three inequivalent N3- sites. In the first N3- site, N3- is bonded to three equivalent Y3+ and one W6+ atom to form a mixture of distorted edge and corner-sharing NY3W trigonal pyramids. In the second N3- site, N3- is bonded to three equivalent Y3+ and one W6+ atom to form a mixture of distorted edge and corner-sharing NY3W trigonal pyramids. In the third N3- site, N3- is bonded in a distorted trigonal non-coplanar geometry to three equivalent W6+ atoms.
DOI: 10.17188/1316939
title: Materials Data on LaWN3 by Materials Project

description: LaWN3 crystallizes in the monoclinic P2_1/m space group. The structure is three-dimensional. La3+ is bonded in a 6-coordinate geometry to six N3- atoms. There are a spread of La–N bond distances ranging from 2.45–2.63 Å. W6+ is bonded to five N3- atoms to form a mixture of distorted corner and edge-sharing WN5 trigonal bipyramids. There are a spread of W–N bond distances ranging from 1.81–2.12 Å. There are three inequivalent N3- sites. In the first N3- site, N3- is bonded to three equivalent La3+ and one W6+ atom to form a mixture of distorted corner and edge-sharing NLa3W tetrahedra. In the second N3- site, N3- is bonded to one La3+ and three equivalent W6+ atoms to form a mixture of distorted corner and edge-sharing NLaW3 tetrahedra. In the third N3- site, N3- is bonded in a distorted trigonal planar geometry to two equivalent La3+ and one W6+ atom.
DOI: 10.17188/1316940
title: Materials Data on YReN3 by Materials Project

description: YReN3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Y3+ is bonded in a 8-coordinate geometry to eight N3- atoms. There are a spread of Y–N bond distances ranging from 2.36–2.66 Å. Re6+ is bonded to six N3- atoms to form corner-sharing ReN6 octahedra. The corner-sharing octahedra tilt angles range from 26–29°. There are a spread of Re–N bond distances ranging from 1.98–2.02 Å. There are two inequivalent N3- sites. In the first N3- site, N3- is bonded in a 5-coordinate geometry to three equivalent Y3+ and two equivalent Re6+ atoms. In the second N3- site, N3- is bonded to two equivalent Y3+ and two equivalent Re6+ atoms to form distorted corner-sharing NY2Re2 tetrahedra.
DOI: 10.17188/1316941
title: Materials Data on Cs2AlGaH6 by Materials Project

description: Cs2AlH6Ga crystallizes in the cubic Fm-3m space group. The structure is three-dimensional and consists of four gallium molecules and one Cs2AlH6 framework. In the Cs2AlH6 framework, Cs is bonded to twelve equivalent H atoms to form distorted CsH12 cuboctahedra that share corners with twelve equivalent CsH12 cuboctahedra, faces with six equivalent CsH12 cuboctahedra, and faces with four equivalent AlH6 octahedra. All Cs–H bond lengths are 3.09 Å. Al is bonded to six equivalent H atoms to form AlH6 octahedra that share faces with eight equivalent CsH12 cuboctahedra. All Al–H bond lengths are 1.80 Å. H is bonded in a single-bond geometry to four equivalent Cs and one Al atom.
DOI: 10.17188/1316942
title: Materials Data on CaMoN3 by Materials Project

description: CaMoN3 crystallizes in the monoclinic P2/m space group. The structure is three-dimensional. Ca2+ is bonded to six N+2.67- atoms to form CaN6 octahedra that share corners with two equivalent CaN6 octahedra, corners with two equivalent MoN5 trigonal bipyramids, edges with two equivalent CaN6 octahedra, and edges with four equivalent MoN5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 42°. There are a spread of Ca–N bond distances ranging from 2.35–2.56 Å. Mo6+ is bonded to five N+2.67- atoms to form MoN5 trigonal bipyramids that share corners with two equivalent CaN6 octahedra, corners with four equivalent MoN5 trigonal bipyramids, edges with four equivalent CaN6 octahedra, and edges with two equivalent MoN5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 49°. There are a spread of Mo–N bond distances ranging from 1.94–2.24 Å. There are three inequivalent N+2.67- sites. In the first N+2.67- site, N+2.67- is bonded in a 3-coordinate geometry to two equivalent Ca2+ and one N+2.67- atom. The N–N bond length is 1.19 Å. In the second N+2.67- site, N+2.67- is bonded to two equivalent Ca2+ and three equivalent Mo6+ atoms to form NCa2Mo3 trigonal bipyramids that share corners with four equivalent NCa2Mo3 trigonal bipyramids, corners with two equivalent NCa2Mo2 trigonal pyramids, edges with two equivalent NCa2Mo3 trigonal bipyramids, and edges with four equivalent NCa2Mo2 trigonal pyramids. In the third N+2.67- site, N+2.67- is bonded to two equivalent Ca2+ and two equivalent Mo6+ atoms to form distorted NCa2Mo2 trigonal pyramids that share corners with two equivalent NCa2Mo3 trigonal bipyramids, corners with four equivalent NCa2Mo2 trigonal pyramids, and edges with four equivalent NCa2Mo3 trigonal bipyramids.
DOI: 10.17188/1316943
title: Materials Data on HfTeSe4 by Materials Project

description: HfTeSe4 crystallizes in the monoclinic P2/m space group. The structure is two-dimensional and consists of one HfTeSe4 sheet oriented in the (1, 0, 0) direction. Hf4+ is bonded to six Se2- atoms to form HfSe6 octahedra that share edges with two equivalent HfSe6 octahedra and edges with four equivalent TeSe6 octahedra. There are two shorter (2.69 Å) and four longer (2.71 Å) Hf–Se bond lengths. Te4+ is bonded to six Se2- atoms to form TeSe6 octahedra that share edges with two equivalent TeSe6 octahedra and edges with four equivalent HfSe6 octahedra. All Te–Se bond lengths are 2.81 Å. There are two inequivalent Se2- sites. In the first Se2- site, Se2- is bonded in a 3-coordinate geometry to two equivalent Hf4+ and one Te4+ atom. In the second Se2- site, Se2- is bonded in a 3-coordinate geometry to one Hf4+ and two equivalent Te4+ atoms.
DOI: 10.17188/1316944
title: Materials Data on Te3As2 by Materials Project

description: As2Te3 crystallizes in the trigonal R-3m space group. The structure is two-dimensional and consists of three As2Te3 sheets oriented in the (0, 0, 1) direction. As3- is bonded to six Te2+ atoms to form a mixture of edge and corner-sharing AsTe6 octahedra. The corner-sharing octahedral tilt angles are 0°. There are three shorter (2.86 Å) and three longer (3.00 Å) As–Te bond lengths. There are two inequivalent Te2+ sites. In the first Te2+ site, Te2+ is bonded in a distorted T-shaped geometry to three equivalent As3- atoms. In the second Te2+ site, Te2+ is bonded to six equivalent As3- atoms to form edge-sharing TeAs6 octahedra.
DOI: 10.17188/1316945
title: Materials Data on Ag by Materials Project

description: Ag is alpha Samarium structured and crystallizes in the trigonal R-3m space group. The structure is three-dimensional. there are two inequivalent Ag sites. In the first Ag site, Ag is bonded to twelve Ag atoms to form a mixture of edge, face, and corner-sharing AgAg12 cuboctahedra. There are six shorter (2.94 Å) and six longer (2.95 Å) Ag–Ag bond lengths. In the second Ag site, Ag is bonded to twelve Ag atoms to form a mixture of edge, face, and corner-sharing AgAg12 cuboctahedra. There are three shorter (2.94 Å) and six longer (2.95 Å) Ag–Ag bond lengths.
DOI: 10.17188/1316946
title: Materials Data on Cu by Materials Project

description: Cu is Magnesium structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. Cu is bonded to twelve equivalent Cu atoms to form a mixture of face, edge, and corner-sharing CuCu12 cuboctahedra. There are six shorter (2.55 Å) and six longer (2.56 Å) Cu–Cu bond lengths.
DOI: 10.17188/1316947
title: Materials Data on BaCuAs by Materials Project

description: BaCuAs crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. Ba2+ is bonded to six equivalent As3- atoms to form a mixture of face, edge, and corner-sharing BaAs6 octahedra. The corner-sharing octahedral tilt angles are 43°. All Ba–As bond lengths are 3.43 Å. Cu1+ is bonded in a trigonal planar geometry to three equivalent As3- atoms. All Cu–As bond lengths are 2.53 Å. As3- is bonded in a 3-coordinate geometry to six equivalent Ba2+ and three equivalent Cu1+ atoms.
DOI: 10.17188/1316948
title: Materials Data on HoAu2 by Materials Project

description: HoAu2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Ho is bonded in a distorted q6 geometry to ten equivalent Au atoms. All Ho–Au bond lengths are 3.04 Å. Au is bonded in a 10-coordinate geometry to five equivalent Ho atoms.
DOI: 10.17188/1316949
title: Materials Data on Ag2GeS3 by Materials Project

description: Ag2GeS3 is Enargite-like structured and crystallizes in the orthorhombic Cmc2_1 space group. The structure is three-dimensional. Ag1+ is bonded to four S2- atoms to form AgS4 tetrahedra that share corners with five equivalent GeS4 tetrahedra and corners with seven equivalent AgS4 tetrahedra. There are a spread of Ag–S bond distances ranging from 2.55–2.61 Å. Ge4+ is bonded to four S2- atoms to form GeS4 tetrahedra that share corners with two equivalent GeS4 tetrahedra and corners with ten equivalent AgS4 tetrahedra. There are a spread of Ge–S bond distances ranging from 2.21–2.39 Å. There are two inequivalent S2- sites. In the first S2- site, S2- is bonded to two equivalent Ag1+ and two equivalent Ge4+ atoms to form corner-sharing SAg2Ge2 tetrahedra. In the second S2- site, S2- is bonded to three equivalent Ag1+ and one Ge4+ atom to form corner-sharing SAg3Ge tetrahedra.
DOI: 10.17188/1316950
title: Materials Data on P2O5 by Materials Project

description: P2O5 crystallizes in the orthorhombic Pmmm space group. The structure is three-dimensional. there are two inequivalent P5+ sites. In the first P5+ site, P5+ is bonded to six O2- atoms to form corner-sharing PO6 octahedra. The corner-sharing octahedra tilt angles range from 0–54°. There are a spread of P–O bond distances ranging from 1.55–1.84 Å. In the second P5+ site, P5+ is bonded to six O2- atoms to form a mixture of corner and edge-sharing PO6 octahedra. The corner-sharing octahedra tilt angles range from 0–54°. There is two shorter (1.63 Å) and four longer (1.91 Å) P–O bond length. There are five inequivalent O2- sites. In the first O2- site, O2- is bonded in a trigonal planar geometry to three P5+ atoms. In the second O2- site, O2- is bonded in a linear geometry to two equivalent P5+ atoms. In the third O2- site, O2- is bonded in a trigonal planar geometry to three P5+ atoms. In the fourth O2- site, O2- is bonded in a linear geometry to two equivalent P5+ atoms. In the fifth O2- site, O2- is bonded in a linear geometry to two equivalent P5+ atoms.
DOI: 10.17188/1316951
title: Materials Data on MoS2 by Materials Project

description: MoS2 crystallizes in the orthorhombic Pmmn space group. The structure is one-dimensional and consists of two MoS2 ribbons oriented in the (1, 0, 0) direction. there are eight inequivalent Mo4+ sites. In the first Mo4+ site, Mo4+ is bonded to six equivalent S2- atoms to form distorted edge-sharing MoS6 pentagonal pyramids. There are four shorter (2.41 Å) and two longer (2.42 Å) Mo–S bond lengths. In the second Mo4+ site, Mo4+ is bonded to six S2- atoms to form distorted edge-sharing MoS6 pentagonal pyramids. There are four shorter (2.41 Å) and two longer (2.42 Å) Mo–S bond lengths. In the third Mo4+ site, Mo4+ is bonded to six S2- atoms to form distorted edge-sharing MoS6 pentagonal pyramids. There are four shorter (2.41 Å) and two longer (2.42 Å) Mo–S bond lengths. In the fourth Mo4+ site, Mo4+ is bonded to six S2- atoms to form distorted edge-sharing MoS6 pentagonal pyramids. There are four shorter (2.41 Å) and two longer (2.42 Å) Mo–S bond lengths. In the fifth Mo4+ site, Mo4+ is bonded to six S2- atoms to form distorted edge-sharing MoS6 pentagonal pyramids. There are four shorter (2.41 Å) and two longer (2.42 Å) Mo–S bond lengths. In the sixth Mo4+ site, Mo4+ is bonded to six S2- atoms to form distorted edge-sharing MoS6 pentagonal pyramids. There are four shorter (2.42 Å) and two longer (2.47 Å) Mo–S bond lengths. In the seventh Mo4+ site, Mo4+ is bonded in a distorted square co-planar geometry to four equivalent S2- atoms. All Mo–S bond lengths are 2.39 Å. In the eighth Mo4+ site, Mo4+ is bonded to six S2- atoms to form distorted edge-sharing MoS6 pentagonal pyramids. There are four shorter (2.39 Å) and two longer (2.42 Å) Mo–S bond lengths. There are eight inequivalent S2- sites. In the first S2- site, S2- is bonded in a 3-coordinate geometry to three Mo4+ atoms. In the second S2- site, S2- is bonded in a 3-coordinate geometry to three Mo4+ atoms. The S–Mo bond length is 2.42 Å. In the third S2- site, S2- is bonded in an L-shaped geometry to two equivalent Mo4+ atoms. In the fourth S2- site, S2- is bonded in a 3-coordinate geometry to three Mo4+ atoms. In the fifth S2- site, S2- is bonded in a 3-coordinate geometry to three Mo4+ atoms. In the sixth S2- site, S2- is bonded in a 3-coordinate geometry to three Mo4+ atoms. In the seventh S2- site, S2- is bonded in a 3-coordinate geometry to three Mo4+ atoms. In the eighth S2- site, S2- is bonded in a 3-coordinate geometry to three Mo4+ atoms.
DOI: 10.17188/1316952
title: Materials Data on Na2Cl by Materials Project

description: Na2Cl is trigonal omega-like structured and crystallizes in the trigonal R-3m space group. The structure is two-dimensional and consists of three Na2Cl sheets oriented in the (0, 0, 1) direction. Na is bonded in a distorted T-shaped geometry to three equivalent Cl atoms. All Na–Cl bond lengths are 2.84 Å. Cl is bonded to six equivalent Na atoms to form edge-sharing ClNa6 octahedra.
DOI: 10.17188/1316954
title: Materials Data on Ag2WS4 by Materials Project

description: Ag2WS4 crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. W6+ is bonded in a tetrahedral geometry to four S2- atoms. There are a spread of W–S bond distances ranging from 2.20–2.24 Å. There are two inequivalent Ag1+ sites. In the first Ag1+ site, Ag1+ is bonded in a 5-coordinate geometry to five S2- atoms. There are a spread of Ag–S bond distances ranging from 2.54–2.91 Å. In the second Ag1+ site, Ag1+ is bonded in a 5-coordinate geometry to five S2- atoms. There are a spread of Ag–S bond distances ranging from 2.46–3.05 Å. There are three inequivalent S2- sites. In the first S2- site, S2- is bonded in a 4-coordinate geometry to one W6+ and three Ag1+ atoms. In the second S2- site, S2- is bonded in a 2-coordinate geometry to one W6+ and two Ag1+ atoms. In the third S2- site, S2- is bonded in a 3-coordinate geometry to one W6+ and two equivalent Ag1+ atoms.