DOI: 10.24378/exe.1363
title: Environmental Controls on the Riverine Export of Dissolved Black Carbon (dataset)

description: Each year, tropical rivers export a dissolved organic carbon (DOC) flux to the global oceans that is equivalent to ~4% of the global land sink for atmospheric CO¬2. Among the most refractory fractions of terrigenous DOC is dissolved black carbon (DBC), which constitutes ~10% of the total flux and derives from the charcoal and soot (aerosol) produced during biomass burning and fossil fuel combustion. Black carbon (BC) has disproportionate storage potential in oceanic pools and thus its export has implications for the fate and residence time of terrigenous organic carbon (OC). In contrast to bulk DOC, there is limited knowledge of the environmental factors that control riverine fluxes of DBC. We thus completed a comprehensive assessment of the factors controlling DBC export in tropical rivers with catchments distributed across environmental gradients of hydrology, topography, climate and soil properties. Generalised linear models explained 70% and 64% of the observed variance in DOC and DBC concentrations, respectively. DOC and DBC concentrations displayed coupled responses to the dominant factors controlling their riverine export (soil moisture; catchment slope, and; catchment stocks of OC or BC, respectively) but varied divergently across gradients of temperature and soil properties. DBC concentrations also varied strongly with aerosol BC deposition rate, indicating further potential for deviation of DBC fluxes from those of DOC due to secondary inputs of DBC from this unmatched source. Overall, this study identifies the specific drivers of BC dynamics in river catchments and fundamentally enhances our understanding of refractory DOC export to the global oceans.
description: This dataset contains the data used for statistical model fitting in the study by Jones et al. (2019, accepted). The original data is published across the two studies that follow: Jones, M. W., Aragão, L., Dittmar, T., Rezende, C., Almeida M., Johnson, B., Marques J., Niggemann, J., Rangel, T., and Quine, T. A. (accepted) Environmental Controls on the Riverine Export of Dissolved Black Carbon. Global Biogeochemical Cycles. Marques, J. S., Dittmar, T., Niggemann, J., Almeida, M. G., Gomez-Saez, G. V., & Rezende, C. E. (2017). Dissolved black carbon in the headwaters-to-ocean continuum of Paraíba do Sul River, Brazil. Frontiers in Earth Science, 5, 11. The dataset contains concentration data for dissolved organic carbon (DOC) and dissolved black carbon (DBC) in Brazilian river channels. It also contains the values of explanatory variables used in the model fitting process to understand variability in the measured DOC and DBC concentrations. The dataset is in the form of a .xlsx document containing the worksheets "General_Info", "FieldInfo" and "Dataset". "General_Info" contains references to the studies contributing to the dataset. "FieldInfo" contains definitions of each field in the "Dataset" worksheet. The "Dataset" worksheet contains all data values.
description: The article associated with this dataset is located in ORE at: http://hdl.handle.net/10871/37046