cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.6084/m9.figshare.19945249.v1
title: PHOTODEGRADATION OF RhB UNDER VISIBLE LIGHT BY PT/TIO2 NANOPARTICLES PREPARED THROUGH PHOTOREDUCTIVE DEPOSITION PROCESS

description: Pt/TiO2 nanoparticles were prepared by a simple two-step aqueous solution method, which consists of a low temperature hydrothermal step and a photoreduction deposition step. The as-prepared samples were characterized by XRD, TEM, XPS, UV-vis, and BET techniques. The as-prepared samples exhibited enhanced photocatalytic activity towards the degradation of rhodamine B (RhB) under visible light irradiation. With increasing Pt content from 0.25 to 1 wt.%, the band gap energies shift from 2.32 to 1.64 eV. The 0.75 wt.% Pt/TiO2 sample showed the best photocatalytic activity, which could be ascribed to the formation of a Schottky barrier and the localized surface plasmon resonance effect of Pt nanoparticles. And the as-prepared samples also displayed excellent stability and reusability in multiple experimental cycles.
DOI: 10.6084/m9.figshare.19945261
title: IMIDAZOLE AND CATALYSIS: A PERFFECT MATCH

description: The imidazole (IMZ) ring presents several chemical properties that turns it into a versatile acid-basic/nucleophilic catalyst. The discovery of the biological properties of histidine (amino acid with IMZ ring) instigates the study of this class of compounds. It is found in nature in several enzymes such as chymotrypsin and RNAses due to these properties. This review is focused on the catalytic role of IMZ towards the cleavage of acyl and phosphate esters and is structured in the following topics: chemical properties, biological catalysis (RNAses, phosphohistidines, chymotrypsin), intermolecular and intramolecular catalytic models and polymer and nanomaterials-based catalysts. Besides we discuss some properties such as tautomerism, stability, basicity and spectroscopic behavior, correlating with its reactivity in deacylation and dephosphorylation reactions. The main reaction mechanisms and kinetics promoted by IMZ as an acid, basic and nucleophilic catalysts are explored showing some examples. In addition, the importance of IMZ in enzymatic sites and their mechanisms and further combining properties of IMZ with some materials such as (bio)polymers, graphene, and cyclodextrines are covered. In this sense, with the wide IMZ data presented here, we are evidencing the perfect match between IMZ and catalysis.
DOI: 10.6084/m9.figshare.19945261.v1
title: IMIDAZOLE AND CATALYSIS: A PERFFECT MATCH

description: The imidazole (IMZ) ring presents several chemical properties that turns it into a versatile acid-basic/nucleophilic catalyst. The discovery of the biological properties of histidine (amino acid with IMZ ring) instigates the study of this class of compounds. It is found in nature in several enzymes such as chymotrypsin and RNAses due to these properties. This review is focused on the catalytic role of IMZ towards the cleavage of acyl and phosphate esters and is structured in the following topics: chemical properties, biological catalysis (RNAses, phosphohistidines, chymotrypsin), intermolecular and intramolecular catalytic models and polymer and nanomaterials-based catalysts. Besides we discuss some properties such as tautomerism, stability, basicity and spectroscopic behavior, correlating with its reactivity in deacylation and dephosphorylation reactions. The main reaction mechanisms and kinetics promoted by IMZ as an acid, basic and nucleophilic catalysts are explored showing some examples. In addition, the importance of IMZ in enzymatic sites and their mechanisms and further combining properties of IMZ with some materials such as (bio)polymers, graphene, and cyclodextrines are covered. In this sense, with the wide IMZ data presented here, we are evidencing the perfect match between IMZ and catalysis.
DOI: 10.6073/pasta/554a37c22fc73f7367606ad35d81ac44
title: Mohonk Preserve Grassland Field Monitoring 2017-2021

description: Between 2017-2021, Mohonk Preserve inventoried vegetation in its old-fields and grasslands. The goal was to increase understanding and knowledge of the Preserve’s vegetation communities so informed management strategies could be developed. This data provides information on species composition; occurrence frequency; vegetation type (woody, forb, grass, sedge, etc.); species percent cover (dominance); and species listed, invasive, and pollinator importance status. Five fields have been sampled thus far: Spring Farm (SF, plots [n]= 96); Glory Hill (GF, n= 45); Testimonial Gateway (TG, n= 66); Brook Farm (BF, n= 36); and Pine Farm (PF, n= 27). Soil samples were taken from three sites in 2018: Spring Farm, Glory Hill, and Testimonial Gateway. All data collection occurred between the months of May and August. There are plans to add more plots to sites Brook Farm, Pine Farm, and a field that has not yet been sampled, Klein kill Farm. There are no immediate plans to resample Spring Farm, Glory Hill, or Testimonial Gateway.
DOI: 10.6084/m9.figshare.19945264
title: A SIMPLE AND SENSITIVE LC-MS/MS METHOD FOR THE DETERMINATION OF S-PHENYLMERCAPTURIC ACID IN HUMAN URINE

description: Benzene is an important environmental and occupational pollutant, and recognized as human carcinogen. S-phenylmercapturic acid (SPMA) is a highly specific biomarker of exposure to benzene, applied in occupational toxicology to assess low levels of benzene exposure. The objective of this study was to develop and validate a one-step liquid extraction bioanalytical method for the quantification of SPMA in urine by liquid chromatography-tandem mass spectrometry (LC-MS/MS). The method was applied to the evaluation of benzene exposure in an occupational setting. The assay was linear from 0.5 to 500 ng mL-1 (r&gt;0.99), accurate (91.4-105.2%) and precise, with CV% between 4.73 and 9.96%. SPMA was stable in urine for 90 days at -20 °C. Airborne benzene concentrations, urinary levels of SPMA and t,t-MA were significantly higher in gas station workers (n=30) in comparison to outdoor workers (n=14) and individuals non-occupationally exposed to benzene (n=34). Benzene airborne levels had higher correlation with urinary SPMA (r=0.532, p&lt;0.001) than with t,t-MA (r=0.338, p=0.04), demonstrating the applicability of this biomarker for monitoring low levels of benzene exposure.
DOI: 10.6084/m9.figshare.19945264.v1
title: A SIMPLE AND SENSITIVE LC-MS/MS METHOD FOR THE DETERMINATION OF S-PHENYLMERCAPTURIC ACID IN HUMAN URINE

description: Benzene is an important environmental and occupational pollutant, and recognized as human carcinogen. S-phenylmercapturic acid (SPMA) is a highly specific biomarker of exposure to benzene, applied in occupational toxicology to assess low levels of benzene exposure. The objective of this study was to develop and validate a one-step liquid extraction bioanalytical method for the quantification of SPMA in urine by liquid chromatography-tandem mass spectrometry (LC-MS/MS). The method was applied to the evaluation of benzene exposure in an occupational setting. The assay was linear from 0.5 to 500 ng mL-1 (r&gt;0.99), accurate (91.4-105.2%) and precise, with CV% between 4.73 and 9.96%. SPMA was stable in urine for 90 days at -20 °C. Airborne benzene concentrations, urinary levels of SPMA and t,t-MA were significantly higher in gas station workers (n=30) in comparison to outdoor workers (n=14) and individuals non-occupationally exposed to benzene (n=34). Benzene airborne levels had higher correlation with urinary SPMA (r=0.532, p&lt;0.001) than with t,t-MA (r=0.338, p=0.04), demonstrating the applicability of this biomarker for monitoring low levels of benzene exposure.
DOI: 10.6084/m9.figshare.19945263
title: RECENT APPLICATIONS OF THE ORGANIC PHOTOCATALYST 1,2,3,5-TETRAKIS(CARBAZOL-9-YL)-4,6-DICIANOBENZENE IN CHEMICAL TRANSFORMATIONS

description: Ruthenium and iridium polypyridine complexes are among the most employed photocatalysts described in literature. The broad applicability is due to the redox potentials and long half-life times of the excited state which these molecules presented. The pursuit for metal-free alternatives has been intensified in the last few years, therefore, many organic fluorophores were successfully employed as photocatalysts. Among them, 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicianobenzene (4CzIPN) recently drawn attention of the community, and it’s been widely employed by distinguished research groups. Recent studies have shown that this catalyst do not only present similar properties to transition metal complexes, but also, its synthesis can be accomplished more easily and less expensive when compared with the metallic photocatalysts above mentioned. Therefore, 4CzIPN constitutes a metal-free alternative to replace transition metal complexes in conventional photochemical protocols. Moreover, it’s as a powerful ally in the development of new photochemical approaches. In this work, we aim to summarize recent applications of 4CzIPN as catalyst in the emerging field of redox photocatalysis.
DOI: 10.6084/m9.figshare.19945263.v1
title: RECENT APPLICATIONS OF THE ORGANIC PHOTOCATALYST 1,2,3,5-TETRAKIS(CARBAZOL-9-YL)-4,6-DICIANOBENZENE IN CHEMICAL TRANSFORMATIONS

description: Ruthenium and iridium polypyridine complexes are among the most employed photocatalysts described in literature. The broad applicability is due to the redox potentials and long half-life times of the excited state which these molecules presented. The pursuit for metal-free alternatives has been intensified in the last few years, therefore, many organic fluorophores were successfully employed as photocatalysts. Among them, 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicianobenzene (4CzIPN) recently drawn attention of the community, and it’s been widely employed by distinguished research groups. Recent studies have shown that this catalyst do not only present similar properties to transition metal complexes, but also, its synthesis can be accomplished more easily and less expensive when compared with the metallic photocatalysts above mentioned. Therefore, 4CzIPN constitutes a metal-free alternative to replace transition metal complexes in conventional photochemical protocols. Moreover, it’s as a powerful ally in the development of new photochemical approaches. In this work, we aim to summarize recent applications of 4CzIPN as catalyst in the emerging field of redox photocatalysis.
DOI: 10.6084/m9.figshare.23702271
title: ASE 2023 artifact

description: Please follow the instructions in `ReadMe.pdf` to replicate our results.
DOI: 10.6084/m9.figshare.23702271.v3
title: ASE 2023 artifact

description: Please follow the instructions in `ReadMe.pdf` to replicate our results.
DOI: 10.25919/bmfx-jh54
title: Parkes observations for project P1162 semester 2023APRS_10

description: Pulsar timing is a powerful tool in studying pulsar physics. Discovering more exotic pulsar systems or timing pulsars with higher precision is an essential part of pulsar astronomy. As a recently discovered millisecond pulsar, PSR J1402+13 is an interesting source for follow-up timing observations. First, its apparent spin-down rate is the highest among known millisecond pulsars. This spin-down rate, if confirmed, will place stringent constraints on the spin-up process predicted by pulsar recycling theories. Second, and more importantly, preliminary analysis shows that J1402+13 is a very promising candidate for pulsar timing arrays, with an achievable precision at the level of 6 nanoseconds for 60 minutes observation with Parkes. We have observed J1402+13 for 8 times in the past two months and propose to continue the observations in the coming semester. We apply for another 14 hours to observe the pulsar to extend the timing baseline to one year. This project will derive an ephemeris of the system, which is valuable to understand its formation and evolution history. Furthermore, the observations will allow us to evaluate the timing performance of J1402+13 and its suitability to be included in pulsar timing arrays.
DOI: 10.58109/fpth-dx17
title: A multicentre single arm study to evaluate the safety and efficacy of carfilzomib-thalidomide-dexamethasone (CarTD) for newly diagnosed transplant-eligible multiple myeloma (TE NDMM) patients refractory to initial bortezomib-based induction therapy (MM17)

description: HeSANDA 1.0.0
description: Dataset includes: 
Data for 50 patients with newly diagnosed, transplant eligible, multiple myeloma using carfilzomib-thalidomide-dexamethasone (CarTD), in a randomised trial 
Demographic data, diagnostic data, treatment data, outcome data
DOI: 10.58109/zm9j-7x33
title: A Multicentre Phase 3 Trial Comparing Elotuzumab-Cyclophosphamide-Thalidomide-Dexamethasone (E-CTD) with Cyclophosphamide-Thalidomide-Dexamethasone (CTD) for the Treatment of Relapsed and/or Refractory Multiple Myeloma (RRMM) (MM20)

description: HeSANDA 1.0.0
description: Dataset includes: 
Data for 110 patients with relapsed or refractory multiple myeloma, in a randomised controlled trial of Elotuzumab-Cyclophosphamide-Thalidomide-Dexamethasone (E-CTD) with Cyclophosphamide-Thalidomide-Dexamethasone (CTD) Demographic data, diagnostic data, treatment data, outcome data
DOI: 10.58109/s709-6h74
title: Phase III randomised trial of high dose Cyclophosphamide, Epirubicin, Vincristine and Prednisolone (CEOP) chemotherapy regimen & Filgrastim versus standard dose CEOP chemotherapy regimen in patients with non-Hodgkin’s lymphoma (NHL07)

description: HeSANDA 1.0.0
description: Dataset includes: 
Data for 247 patients with newly diagnosed non-Hodgkin’s lymphoma, randomised trial of Cyclophosphamide, Epirubicin, Vincristine and Prednisolone (CEOP) chemotherapy regimen and Filgrastim versus standard dose CEOP chemotherapy alone
Demographic data, diagnostic data, treatment data, outcome data
DOI: 10.58109/jazm-1d71
title: Rituximab in Primary Central Nervous system Lymphoma. A randomized Dutch/Belgian Hemato-Oncology Cooperative Group (HOVON) / Australasian Leukaemia and Lymphoma Group (ALLG) intergroup study (NHL24)

description: HeSANDA 1.0.0
description: Dataset includes: 
Data for 45 patients with newly diagnosed Primary Central Nervous System Lymphoma (PCNSL) assessing the addition of rituxumab vs standard chemotherapy 
Demographic data, diagnostic data, treatment data, outcome data
DOI: 10.58109/3xdt-2v79
title: A Phase II Study of Ibrutinib, Rituximab and mini-CHOP therapy in very elderly patients with newly diagnosed DLBCL (NHL29)

description: HeSANDA 1.0.0
description: Dataset includes:
Data for 80 patients aged &gt;75 years Treatment of Elderly patient cohort with newly diagnosed Diffuse large B cell lymphoma (DLBCL) with Ibrutinib, Rituximab and mini-CHOP therapy
Demographic data, diagnostic data, treatment data, outcome data
DOI: 10.5281/zenodo.4431090
title: A Test of the Cosmological Principle with Quasars

description: Dataset and mask associated with https://inspirehep.net/literature/1820376
description: Note that the final result is for the sample with W1 less than 16.4 cut applied, whereas this file includes objects with W1 less than 16.5.
DOI: 10.5281/zenodo.4431089
title: A Test of the Cosmological Principle with Quasars

description: Dataset, mask and code associated with https://inspirehep.net/literature/1820376 (https://arxiv.org/abs/2009.14826) Code and README for selecting the sample from CatWISE can be found in Generatecode.tar.gz Code and README for masking the sample, evaluating the dipole, as well as the Monte Carlos for statistical significances can be found in Resultscode.tar.gz (This github repository: https://github.com/rameez3333/CatWISEdipole ) Note that the final result is for the sample with W1 less than 16.4 cut applied, whereas this file includes objects with W1 less than 16.5. Additional code required to produce the catalog from scratch is available in "secrest+21_extra.tar.gz"
DOI: 10.5281/zenodo.8303800
title: A Test of the Cosmological Principle with Quasars

description: Dataset, mask and code associated with https://inspirehep.net/literature/1820376 (https://arxiv.org/abs/2009.14826) Code and README for selecting the sample from CatWISE can be found in Generatecode.tar.gz Code and README for masking the sample, evaluating the dipole, as well as the Monte Carlos for statistical significances can be found in Resultscode.tar.gz (This github repository: https://github.com/rameez3333/CatWISEdipole ) Note that the final result is for the sample with W1 less than 16.4 cut applied, whereas this file includes objects with W1 less than 16.5. Additional code required to produce the catalog from scratch is available in "secrest+21_extra.tar.gz"
DOI: 10.26182/r3aq-ka95
title: Evolution of CpH methylation in vertebrate brains
DOI: 10.5281/zenodo.8137336
title: Magnetically-dressed CrSBr exciton-polaritons in ultrastrong coupling regime

description: Source data for: Magnetically-dressed CrSBr exciton-polaritons in ultrastrong coupling regime
DOI: 10.5281/zenodo.8137335
title: Magnetically-dressed CrSBr exciton-polaritons in ultrastrong coupling regime

description: Source data for: Magnetically-dressed CrSBr exciton-polaritons in ultrastrong coupling regime
DOI: 10.5281/zenodo.8303726
title: the performance issue in hipster-shop

description: the performance issue in hipster-shop
DOI: 10.5281/zenodo.8303725
title: the performance issue in hipster-shop

description: the performance issue in hipster-shop
DOI: 10.5517/ccdc.csd.cc2fvxcl
title: CCDC 2260190: Experimental Crystal Structure Determination

description: Related Article: Riya Mallik, Muktashree Saha, Vandna Singh, Hari Mohan, S. Senthil Kumaran, Chandan Mukherjee|2023|J.Mater.Chem.B|11|8251|doi:10.1039/D3TB01289A
description: An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
DOI: 10.5517/ccdc.csd.cc2fhwxr
title: CCDC 2249605: Experimental Crystal Structure Determination

description: Related Article: Manas Kumar Mahish, Ennio Zangrando, Apu Patra, Pavel Vojtíšek, Subal Chandra Manna|2023|Polyhedron|243|116543|doi:10.1016/j.poly.2023.116543
description: An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
DOI: 10.5517/ccdc.csd.cc2fhwys
title: CCDC 2249606: Experimental Crystal Structure Determination

description: Related Article: Manas Kumar Mahish, Ennio Zangrando, Apu Patra, Pavel Vojtíšek, Subal Chandra Manna|2023|Polyhedron|243|116543|doi:10.1016/j.poly.2023.116543
description: An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
DOI: 10.25919/jysw-8j23
title: Parkes observations for project P1054 semester 2023APRS_12

description: With this proposal we ask time to continue our timing follow-up campaign of pulsars discovered with the MeerKAT telescope. Twenty sources have been discovered in targeted observations of Fermi unidentified point sources, one in association with a Supernova Remnant, 13 in the Magellanic Clouds, 71 in Globular Clusters and 74 in a survey of the Galactic plane. A large fraction of the new discoveries are recycled pulsars (including at least one double neutron star system and several 'spider' binaries), or young pulsars. Timing observations have an essential role in exploiting the full potential of any pulsar discovery, allowing the precise measurement of rotational, astrometric and orbital parameters which, in turn, give us powerful tools to improve our understanding of the physics in extreme environments as well as of the population of neutron stars as a whole. The UWL receiver of the Parkes telescope is a sensitive, versatile instrument that is allowing us to successfully time these new sources, in the bright-end of TRAPUM discoveries.
DOI: 10.26182/68b8-jd43
title: Human prefrontal cortex gene regulatory dynamics from gestation to adulthood at single-cell resolution
DOI: 10.6084/m9.figshare.24063702
title: Supplementary Material for: Effectiveness and factors associated with response to golimumab in Japanese patients with ulcerative colitis in real clinical practice: Phoenix Study

description: Abstract Introduction: There have been limited reports on the clinical efficacy of golimumab (GLM) in Japanese patients with ulcerative colitis (UC) in real clinical practice. This study aimed to explore the real-life effectiveness and factors associated with response to GLM in Japanese patients with UC. Methods: This observational, retrospective, multicenter study was conducted in hospitals with expertise in inflammatory bowel disease treatment. Sixty-three patients treated with GLM and active UC were included in the analysis. Clinical remission (CR) (partial Mayo score ≤2) in the induction and maintenance phases after GLM treatment and associated factors were evaluated. Results: The proportion of patients achieving CR in the induction and maintenance phases was 41.3% (26/63) and 46.0% (29/63, the last observation carried forward method was used for patients who discontinued treatment for reasons other than inadequate response), respectively. The median partial Mayo score was 5 (IQR 4-6) at baseline, 3 (IQR 1-5) in the induction phase, and 1 (IQR 0-3) in the maintenance phase. Hemoglobin, platelet, and C-reactive protein levels changed, consistent with the partial Mayo score. Multivariate logistic analysis revealed that biologic-naive status was an independent factor associated with CR in the induction (p=0.0200) and maintenance (p=0.0459) phases, and a disease duration of &gt;60 months until GLM initiation was associated with CR in the induction phase (p=0.0427). Conclusions: The effectiveness of GLM in daily clinical practice has been confirmed in Japanese patients with active UC. Biologic-naive patients responded more to GLM in the induction and maintenance phases, and patients with a disease duration of &gt;60 months until initiation of GLM were more responsive in the induction phase.