cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.6084/m9.figshare.1011812
title: Mean separations for the significant individual and combined year and treatment interaction effects on daily N<sub>2</sub>O–N

description: <b>Table 2.</b> Mean separations for the significant individual and combined year and treatment interaction effects on daily N<sub>2</sub>O–N. The analysis was performed on lnN<sub>2</sub>O–N, and the data presented here are the back-transformed results. Different letters indicate statistically significant differences (LSD 5%). Without inhibitor (wo/I), and with inhibitor (w/I). <strong>Abstract</strong> Nitrification inhibitors have the potential to reduce N<sub>2</sub>O emissions from maize fields, but optimal results may depend on deployment of integrated N fertilizer management systems that increase yields achieved per unit of N<sub>2</sub>O lost. A new micro-encapsulated formulation of nitrapyrin for liquid N fertilizers became available to US farmers in 2010. Our research objectives were to (i) assess the impacts of urea–ammonium nitrate (UAN) management practices (timing, rate and nitrification inhibitor) and environmental variables on growing-season N<sub>2</sub>O fluxes and (ii) identify UAN treatment combinations that both reduce N<sub>2</sub>O emissions and optimize maize productivity. Field experiments near West Lafayette, Indiana in 2010 and 2011 examined three N rates (0, 90 and 180 kg N ha<sup>−1</sup>), two timings (pre-emergence and side-dress) and presence or absence of nitrapyrin. Mean cumulative N<sub>2</sub>O–N emissions (<em>Q</em><sub>10</sub> corrected) were 0.81, 1.83 and 3.52 kg N<sub>2</sub>O–N ha<sup>−1</sup> for the rates of 0, 90 and 180 kg N ha<sup>−1</sup>, respectively; 1.80 and 2.31 kg N<sub>2</sub>O–N ha<sup>−1</sup> for pre-emergence and side-dress timings, respectively; and 1.77 versus 2.34 kg N<sub>2</sub>O–N ha<sup>−1</sup> for with and without nitrapyrin, respectively. Yield-scaled N<sub>2</sub>O–N emissions increased with N rates as anticipated (averaging 167, 204 and 328 g N<sub>2</sub>O–N Mg grain<sup>−1</sup> for the 0, 90 and 180 kg N ha<sup>−1</sup> rates), but were 22% greater with the side-dress timing than the pre-emergence timing (when averaged across N rates and inhibitor treatments) because of environmental conditions following later applications. Overall yield-scaled N<sub>2</sub>O–N emissions were 22% lower with nitrapyrin than without the inhibitor, but these did not interact with N rate or timing.
DOI: 10.6084/m9.figshare.1011814.v1
title: Treatment mean separations for grain yield (GY), and yield-scaled N<sub>2</sub>O–N

description: <b>Table 4.</b> Treatment mean separations for grain yield (GY), and yield-scaled N<sub>2</sub>O–N. Means presented in this table are obtained from the back-transformed data for yield-scaled means. Pre-emergence (Pre), and side-dress (Side). Different letters indicate statistically significant differences within columns (Scheffe-5%). <em>p</em>-values for each variable are included at the bottom of the table. (Notes: ,, significant at 0.05, 0.01 and 0.001 probability levels, respectively.) <strong>Abstract</strong> Nitrification inhibitors have the potential to reduce N<sub>2</sub>O emissions from maize fields, but optimal results may depend on deployment of integrated N fertilizer management systems that increase yields achieved per unit of N<sub>2</sub>O lost. A new micro-encapsulated formulation of nitrapyrin for liquid N fertilizers became available to US farmers in 2010. Our research objectives were to (i) assess the impacts of urea–ammonium nitrate (UAN) management practices (timing, rate and nitrification inhibitor) and environmental variables on growing-season N<sub>2</sub>O fluxes and (ii) identify UAN treatment combinations that both reduce N<sub>2</sub>O emissions and optimize maize productivity. Field experiments near West Lafayette, Indiana in 2010 and 2011 examined three N rates (0, 90 and 180 kg N ha<sup>−1</sup>), two timings (pre-emergence and side-dress) and presence or absence of nitrapyrin. Mean cumulative N<sub>2</sub>O–N emissions (<em>Q</em><sub>10</sub> corrected) were 0.81, 1.83 and 3.52 kg N<sub>2</sub>O–N ha<sup>−1</sup> for the rates of 0, 90 and 180 kg N ha<sup>−1</sup>, respectively; 1.80 and 2.31 kg N<sub>2</sub>O–N ha<sup>−1</sup> for pre-emergence and side-dress timings, respectively; and 1.77 versus 2.34 kg N<sub>2</sub>O–N ha<sup>−1</sup> for with and without nitrapyrin, respectively. Yield-scaled N<sub>2</sub>O–N emissions increased with N rates as anticipated (averaging 167, 204 and 328 g N<sub>2</sub>O–N Mg grain<sup>−1</sup> for the 0, 90 and 180 kg N ha<sup>−1</sup> rates), but were 22% greater with the side-dress timing than the pre-emergence timing (when averaged across N rates and inhibitor treatments) because of environmental conditions following later applications. Overall yield-scaled N<sub>2</sub>O–N emissions were 22% lower with nitrapyrin than without the inhibitor, but these did not interact with N rate or timing.
DOI: 10.6084/m9.figshare.1011815.v1
title: Weather characterization for the experimental site for years 2010, 2011 and normal data from the 30 year series 1981–2010

description: <b>Table 5.</b> Weather characterization for the experimental site for years 2010, 2011 and normal data from the 30 year series 1981–2010. Precipitation (pp) in millimeters (mm) and mean temperature (temp.) in degrees centigrade (° C). <strong>Abstract</strong> Nitrification inhibitors have the potential to reduce N<sub>2</sub>O emissions from maize fields, but optimal results may depend on deployment of integrated N fertilizer management systems that increase yields achieved per unit of N<sub>2</sub>O lost. A new micro-encapsulated formulation of nitrapyrin for liquid N fertilizers became available to US farmers in 2010. Our research objectives were to (i) assess the impacts of urea–ammonium nitrate (UAN) management practices (timing, rate and nitrification inhibitor) and environmental variables on growing-season N<sub>2</sub>O fluxes and (ii) identify UAN treatment combinations that both reduce N<sub>2</sub>O emissions and optimize maize productivity. Field experiments near West Lafayette, Indiana in 2010 and 2011 examined three N rates (0, 90 and 180 kg N ha<sup>−1</sup>), two timings (pre-emergence and side-dress) and presence or absence of nitrapyrin. Mean cumulative N<sub>2</sub>O–N emissions (<em>Q</em><sub>10</sub> corrected) were 0.81, 1.83 and 3.52 kg N<sub>2</sub>O–N ha<sup>−1</sup> for the rates of 0, 90 and 180 kg N ha<sup>−1</sup>, respectively; 1.80 and 2.31 kg N<sub>2</sub>O–N ha<sup>−1</sup> for pre-emergence and side-dress timings, respectively; and 1.77 versus 2.34 kg N<sub>2</sub>O–N ha<sup>−1</sup> for with and without nitrapyrin, respectively. Yield-scaled N<sub>2</sub>O–N emissions increased with N rates as anticipated (averaging 167, 204 and 328 g N<sub>2</sub>O–N Mg grain<sup>−1</sup> for the 0, 90 and 180 kg N ha<sup>−1</sup> rates), but were 22% greater with the side-dress timing than the pre-emergence timing (when averaged across N rates and inhibitor treatments) because of environmental conditions following later applications. Overall yield-scaled N<sub>2</sub>O–N emissions were 22% lower with nitrapyrin than without the inhibitor, but these did not interact with N rate or timing.
DOI: 10.6084/m9.figshare.1011811.v1
title: Mean separations for the year and treatment effects on daily N<sub>2</sub>O–N fluxes

description: <b>Table 1.</b> Mean separations for the year and treatment effects on daily N<sub>2</sub>O–N fluxes. The analysis was performed on lnN<sub>2</sub>O–N, and the data presented here are the back-transformed results. Different letters indicate statistically significant differences (LSD 5%). ANOVA summary is pertinent for the treatment effects on lnN<sub>2</sub>O–N daily fluxes for years 2010, 2011 and both years pooled together. (Notes: ,, significant at 0.05, 0.01 and 0.001 probability levels, respectively.) <strong>Abstract</strong> Nitrification inhibitors have the potential to reduce N<sub>2</sub>O emissions from maize fields, but optimal results may depend on deployment of integrated N fertilizer management systems that increase yields achieved per unit of N<sub>2</sub>O lost. A new micro-encapsulated formulation of nitrapyrin for liquid N fertilizers became available to US farmers in 2010. Our research objectives were to (i) assess the impacts of urea–ammonium nitrate (UAN) management practices (timing, rate and nitrification inhibitor) and environmental variables on growing-season N<sub>2</sub>O fluxes and (ii) identify UAN treatment combinations that both reduce N<sub>2</sub>O emissions and optimize maize productivity. Field experiments near West Lafayette, Indiana in 2010 and 2011 examined three N rates (0, 90 and 180 kg N ha<sup>−1</sup>), two timings (pre-emergence and side-dress) and presence or absence of nitrapyrin. Mean cumulative N<sub>2</sub>O–N emissions (<em>Q</em><sub>10</sub> corrected) were 0.81, 1.83 and 3.52 kg N<sub>2</sub>O–N ha<sup>−1</sup> for the rates of 0, 90 and 180 kg N ha<sup>−1</sup>, respectively; 1.80 and 2.31 kg N<sub>2</sub>O–N ha<sup>−1</sup> for pre-emergence and side-dress timings, respectively; and 1.77 versus 2.34 kg N<sub>2</sub>O–N ha<sup>−1</sup> for with and without nitrapyrin, respectively. Yield-scaled N<sub>2</sub>O–N emissions increased with N rates as anticipated (averaging 167, 204 and 328 g N<sub>2</sub>O–N Mg grain<sup>−1</sup> for the 0, 90 and 180 kg N ha<sup>−1</sup> rates), but were 22% greater with the side-dress timing than the pre-emergence timing (when averaged across N rates and inhibitor treatments) because of environmental conditions following later applications. Overall yield-scaled N<sub>2</sub>O–N emissions were 22% lower with nitrapyrin than without the inhibitor, but these did not interact with N rate or timing.
DOI: 10.6084/m9.figshare.1011813.v1
title: Mean separation for the main-factor effects on N<sub>2</sub>O–N cumulative emissions for the 2010 and 2011 growing seasons (118 and 97 d, respectively)

description: <b>Table 3.</b> Mean separation for the main-factor effects on N<sub>2</sub>O–N cumulative emissions for the 2010 and 2011 growing seasons (118 and 97 d, respectively). Different letters indicate statistically significant differences at Scheffe-5%. <strong>Abstract</strong> Nitrification inhibitors have the potential to reduce N<sub>2</sub>O emissions from maize fields, but optimal results may depend on deployment of integrated N fertilizer management systems that increase yields achieved per unit of N<sub>2</sub>O lost. A new micro-encapsulated formulation of nitrapyrin for liquid N fertilizers became available to US farmers in 2010. Our research objectives were to (i) assess the impacts of urea–ammonium nitrate (UAN) management practices (timing, rate and nitrification inhibitor) and environmental variables on growing-season N<sub>2</sub>O fluxes and (ii) identify UAN treatment combinations that both reduce N<sub>2</sub>O emissions and optimize maize productivity. Field experiments near West Lafayette, Indiana in 2010 and 2011 examined three N rates (0, 90 and 180 kg N ha<sup>−1</sup>), two timings (pre-emergence and side-dress) and presence or absence of nitrapyrin. Mean cumulative N<sub>2</sub>O–N emissions (<em>Q</em><sub>10</sub> corrected) were 0.81, 1.83 and 3.52 kg N<sub>2</sub>O–N ha<sup>−1</sup> for the rates of 0, 90 and 180 kg N ha<sup>−1</sup>, respectively; 1.80 and 2.31 kg N<sub>2</sub>O–N ha<sup>−1</sup> for pre-emergence and side-dress timings, respectively; and 1.77 versus 2.34 kg N<sub>2</sub>O–N ha<sup>−1</sup> for with and without nitrapyrin, respectively. Yield-scaled N<sub>2</sub>O–N emissions increased with N rates as anticipated (averaging 167, 204 and 328 g N<sub>2</sub>O–N Mg grain<sup>−1</sup> for the 0, 90 and 180 kg N ha<sup>−1</sup> rates), but were 22% greater with the side-dress timing than the pre-emergence timing (when averaged across N rates and inhibitor treatments) because of environmental conditions following later applications. Overall yield-scaled N<sub>2</sub>O–N emissions were 22% lower with nitrapyrin than without the inhibitor, but these did not interact with N rate or timing.
DOI: 10.6084/m9.figshare.1011808
title: Thermal properties used in ground temperature simulations for the unburned upland and lowland sites

description: <b>Table 1.</b> Thermal properties used in ground temperature simulations for the unburned upland and lowland sites. (Note: VWC—volumetric water content (fraction of 1). UWC—unfrozen water coefficients. <em>C</em><sub>t</sub>/<em>C</em><sub>f</sub>—thawed/frozen volumetric heat capacities (J m<sup>−3</sup> K<sup>−1</sup>). <em>k</em><sub>t</sub>/<em>k</em><sub>f</sub>—thawed/frozen thermal conductivities (W m<sup>−1</sup> K<sup>−1</sup>).) <strong>Abstract</strong> Fire is an important factor controlling the composition and thickness of the organic layer in the black spruce forest ecosystems of interior Alaska. Fire that burns the organic layer can trigger dramatic changes in the underlying permafrost, leading to accelerated ground thawing within a relatively short time. In this study, we addressed the following questions. (1) Which factors determine post-fire ground temperature dynamics in lowland and upland black spruce forests? (2) What levels of burn severity will cause irreversible permafrost degradation in these ecosystems?We evaluated these questions in a transient modeling–sensitivity analysis framework to assess the sensitivity of permafrost to climate, burn severity, soil organic layer thickness, and soil moisture content in lowland (with thick organic layers, ~80 cm) and upland (with thin organic layers, ~30 cm) black spruce ecosystems. The results indicate that climate warming accompanied by fire disturbance could significantly accelerate permafrost degradation. In upland black spruce forest, permafrost could completely degrade in an 18 m soil column within 120 years of a severe fire in an unchanging climate. In contrast, in a lowland black spruce forest, permafrost is more resilient to disturbance and can persist under a combination of moderate burn severity and climate warming.
DOI: 10.6084/m9.figshare.1011812.v1
title: Mean separations for the significant individual and combined year and treatment interaction effects on daily N<sub>2</sub>O–N

description: <b>Table 2.</b> Mean separations for the significant individual and combined year and treatment interaction effects on daily N<sub>2</sub>O–N. The analysis was performed on lnN<sub>2</sub>O–N, and the data presented here are the back-transformed results. Different letters indicate statistically significant differences (LSD 5%). Without inhibitor (wo/I), and with inhibitor (w/I). <strong>Abstract</strong> Nitrification inhibitors have the potential to reduce N<sub>2</sub>O emissions from maize fields, but optimal results may depend on deployment of integrated N fertilizer management systems that increase yields achieved per unit of N<sub>2</sub>O lost. A new micro-encapsulated formulation of nitrapyrin for liquid N fertilizers became available to US farmers in 2010. Our research objectives were to (i) assess the impacts of urea–ammonium nitrate (UAN) management practices (timing, rate and nitrification inhibitor) and environmental variables on growing-season N<sub>2</sub>O fluxes and (ii) identify UAN treatment combinations that both reduce N<sub>2</sub>O emissions and optimize maize productivity. Field experiments near West Lafayette, Indiana in 2010 and 2011 examined three N rates (0, 90 and 180 kg N ha<sup>−1</sup>), two timings (pre-emergence and side-dress) and presence or absence of nitrapyrin. Mean cumulative N<sub>2</sub>O–N emissions (<em>Q</em><sub>10</sub> corrected) were 0.81, 1.83 and 3.52 kg N<sub>2</sub>O–N ha<sup>−1</sup> for the rates of 0, 90 and 180 kg N ha<sup>−1</sup>, respectively; 1.80 and 2.31 kg N<sub>2</sub>O–N ha<sup>−1</sup> for pre-emergence and side-dress timings, respectively; and 1.77 versus 2.34 kg N<sub>2</sub>O–N ha<sup>−1</sup> for with and without nitrapyrin, respectively. Yield-scaled N<sub>2</sub>O–N emissions increased with N rates as anticipated (averaging 167, 204 and 328 g N<sub>2</sub>O–N Mg grain<sup>−1</sup> for the 0, 90 and 180 kg N ha<sup>−1</sup> rates), but were 22% greater with the side-dress timing than the pre-emergence timing (when averaged across N rates and inhibitor treatments) because of environmental conditions following later applications. Overall yield-scaled N<sub>2</sub>O–N emissions were 22% lower with nitrapyrin than without the inhibitor, but these did not interact with N rate or timing.
DOI: 10.6084/m9.figshare.1011808.v1
title: Thermal properties used in ground temperature simulations for the unburned upland and lowland sites

description: <b>Table 1.</b> Thermal properties used in ground temperature simulations for the unburned upland and lowland sites. (Note: VWC—volumetric water content (fraction of 1). UWC—unfrozen water coefficients. <em>C</em><sub>t</sub>/<em>C</em><sub>f</sub>—thawed/frozen volumetric heat capacities (J m<sup>−3</sup> K<sup>−1</sup>). <em>k</em><sub>t</sub>/<em>k</em><sub>f</sub>—thawed/frozen thermal conductivities (W m<sup>−1</sup> K<sup>−1</sup>).) <strong>Abstract</strong> Fire is an important factor controlling the composition and thickness of the organic layer in the black spruce forest ecosystems of interior Alaska. Fire that burns the organic layer can trigger dramatic changes in the underlying permafrost, leading to accelerated ground thawing within a relatively short time. In this study, we addressed the following questions. (1) Which factors determine post-fire ground temperature dynamics in lowland and upland black spruce forests? (2) What levels of burn severity will cause irreversible permafrost degradation in these ecosystems?We evaluated these questions in a transient modeling–sensitivity analysis framework to assess the sensitivity of permafrost to climate, burn severity, soil organic layer thickness, and soil moisture content in lowland (with thick organic layers, ~80 cm) and upland (with thin organic layers, ~30 cm) black spruce ecosystems. The results indicate that climate warming accompanied by fire disturbance could significantly accelerate permafrost degradation. In upland black spruce forest, permafrost could completely degrade in an 18 m soil column within 120 years of a severe fire in an unchanging climate. In contrast, in a lowland black spruce forest, permafrost is more resilient to disturbance and can persist under a combination of moderate burn severity and climate warming.
DOI: 10.6084/m9.figshare.1011795
title: The change in soil organic carbon content (SOC) in the organic layer after warming from −4 to −1 ° C for each landform and OLT depth class

description: <b>Table 1.</b> The change in soil organic carbon content (SOC) in the organic layer after warming from −4 to −1 ° C for each landform and OLT depth class. Soil organic layer thickness was transformed using (2). <strong>Abstract</strong> Permafrost is tightly coupled to the organic soil layer, an interaction that mediates permafrost degradation in response to regional warming. We analyzed changes in permafrost occurrence and organic layer thickness (OLT) using more than 3000 soil pedons across a mean annual temperature (MAT) gradient. Cause and effect relationships between permafrost probability (PF), OLT, and other topographic factors were investigated using structural equation modeling in a multi-group analysis. Groups were defined by slope, soil texture type, and shallow (&lt;28 cm) versus deep organic (≥28 cm) layers. The probability of observing permafrost sharply increased by 0.32 for every 10-cm OLT increase in shallow OLT soils (OLTs) due to an insulation effect, but PF decreased in deep OLT soils (OLTd) by 0.06 for every 10-cm increase. Across the MAT gradient, PF in sandy soils varied little, but PF in loamy and silty soils decreased substantially from cooler to warmer temperatures. The change in OLT was more heterogeneous across soil texture types—in some there was no change while in others OLTs soils thinned and/or OLTd soils thickened at warmer locations. Furthermore, when soil organic carbon was estimated using a relationship with thickness, the average increase in carbon in OLTd soils was almost four times greater compared to the average decrease in carbon in OLTs soils across all soil types. If soils follow a trajectory of warming that mimics the spatial gradients found today, then heterogeneities of permafrost degradation and organic layer thinning and thickening should be considered in the regional carbon balance.
DOI: 10.6084/m9.figshare.1011781
title: Characteristics of the four components identified with the PARAFAC model in the present study, and of similar components previously identified in different aquatic systems (non-exhaustive list)

description: <b>Table 2.</b> Characteristics of the four components identified with the PARAFAC model in the present study, and of similar components previously identified in different aquatic systems (non-exhaustive list). <strong>Abstract</strong> The abundant thaw lakes and ponds in the circumarctic receive a new pool of organic carbon as permafrost peat soils degrade, which can be exposed to significant irradiance that potentially increases as climate warms and ice cover shortens. Exposure to sunlight is known to accelerate the transformation of dissolved organic matter (DOM) into molecules that can be more readily used by microbes. We sampled the water from two common classes of ponds found in the ice-wedge system of continuous permafrost regions of Canada, polygonal and runnel ponds, and followed the transformation of DOM over 12 days by looking at dissolved organic carbon (DOC) concentration and DOM absorption and fluorescence properties. The results indicate a relatively fast decay of color (3.4 and 1.6% loss d<sup>−1</sup> of absorption at 320 nm for the polygonal and runnel pond, respectively) and fluorescence (6.1 and 8.3% loss d<sup>−1</sup> of total fluorescent components, respectively) at the pond surface, faster in the case of humic-like components, but insignificant losses of DOC over the observed period. This result indicates that direct DOM mineralization (photochemical production of CO<sub>2</sub>) is apparently minor in thaw ponds compared to the photochemical transformation of DOM into less chromophoric and likely more labile molecules with a greater potential for microbial mineralization. Therefore, DOM photolysis in arctic thaw ponds can be considered as a catalytic mechanism, accelerating the microbial turnover of mobilized organic matter from thawing permafrost and the production of greenhouse gases, especially in the most shallow ponds. Under a warming climate, this mechanism will intensify as summers lengthen.