cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.6084/m9.figshare.10025225
title: Catalytic Transformation Conditions of Ethanol on Dealuminated BEA Zeolites

description: Catalysis is an important tool in obtaining a range of derivative products from renewable sources, such as ethanol. Solid-state dealumination using ammonium hexafluorosilicate on the BEA zeolite under the treatment at temperature of 190 °C, 70 mol% dealumination in the presence of humidity and washing with buffer solution at 25 °C generated larger pores. The absence of washing procedure for the same sample resulted in pore blockage. Ethanol dehydration reactions showed conversion of 72% (64% ethylene and 8% diethyl ether) for this sample at 300 °C and high weight hourly space velocity (WHSV, 3247 h-1), whereas, at the same temperature but at a low WHSV (57 h-1), the conversion was 88% (49% ethylene and 39% diethyl ether). Dealuminated BEA zeolite presented better diffusion conditions, higher hydrophobicity and generated larger pores. Impregnation with H3PW12O40, H4SiW12O40 and Nb2O5 explained the selectivity, showing that Lewis acid sites from Nb2O5 favored the diethyl ether production.
DOI: 10.6084/m9.figshare.10025228.v1
title: Modeling the Potential Distribution of Mangifera indica L. under Future Climate Scenarios in the Caatinga Biome

description: Abstract Mangifera indica L. (mangueira) is an invasive exotic plant in the Northeast region of Brazil. In the state of Ceará, its presence deserves special attention in the Environmental Protection Area (EPA) of the Serra de Baturité (north sector of state). The synergism of bioinvasion with the warming of the climatic system added to the lack of knowledge about the local geographic distribution of this species limits any invasion control initiatives in the future. The objectives of this study were: 1) to model the potential geographical distribution of climatically adequate areas for M. indica in the Caatinga biome in future climatic scenarios; 2) to evaluate the spatiotemporal dynamics of the projected areas, with emphasis on the EPA of Serra de Baturité. For the modeling, we used the MaxEnt algorithm, the time slices 1961-1990 (actual state of climate), 2041-2060 (2050) and 2061-2080 (2070) and the RCP 4.5 and 8.5 scenarios of CMIP5. Five models were generated from which the models for 2070 projected contraction above 50% for areas of high potential occurrence of the target species.
DOI: 10.6084/m9.figshare.10025225.v1
title: Catalytic Transformation Conditions of Ethanol on Dealuminated BEA Zeolites

description: Catalysis is an important tool in obtaining a range of derivative products from renewable sources, such as ethanol. Solid-state dealumination using ammonium hexafluorosilicate on the BEA zeolite under the treatment at temperature of 190 °C, 70 mol% dealumination in the presence of humidity and washing with buffer solution at 25 °C generated larger pores. The absence of washing procedure for the same sample resulted in pore blockage. Ethanol dehydration reactions showed conversion of 72% (64% ethylene and 8% diethyl ether) for this sample at 300 °C and high weight hourly space velocity (WHSV, 3247 h-1), whereas, at the same temperature but at a low WHSV (57 h-1), the conversion was 88% (49% ethylene and 39% diethyl ether). Dealuminated BEA zeolite presented better diffusion conditions, higher hydrophobicity and generated larger pores. Impregnation with H3PW12O40, H4SiW12O40 and Nb2O5 explained the selectivity, showing that Lewis acid sites from Nb2O5 favored the diethyl ether production.
DOI: 10.6084/m9.figshare.10025231.v1
title: Preliminary evidence of the validity process of the Autism Diagnostic Observation Schedule (ADOS): translation, cross-cultural adaptation and semantic equivalence of the Brazilian Portuguese version

description: Abstract Objectives: To translate and back-translate the Autism Diagnostic Observation Schedule (ADOS) into Brazilian Portuguese, to assess its cross-cultural semantic equivalence, and to verify indicators of quality of the final version by analyzing the inter-rater reliability of the ADOS scores. Methods: This study had three stages: 1) translation and back-translation; 2) semantic equivalence analysis; and 3) pre-test to verify the agreement between mental health specialists and an ADOS senior examiner regarding the scoring procedure. Authorization to translate and carry out the cultural adaptation of the instrument was first obtained from the Western Psychological Services, publishers of the instrument. Results: The main preliminary results pointed to good equivalence between the original English version and the final version and the Brazilian version following the cultural adaptation process. Some semantic differences were found between the original version and the back-translation into English, but they did not interfere with the first translation into Portuguese or into the final version. One of the limitations of the study was the small sample size; for that reason, the inter-rater reliability of the ADOS scores between the specialists and the senior examiner using the kappa coefficient was adequate for 7 out of 10 areas. Conclusions: We conclude that the creation of an official Brazilian version of ADOS will help to strengthen clinical and scientific research into ASD, and deter the use of other unauthorized versions of ADOS in the country.
DOI: 10.6084/m9.figshare.10025213
title: Reconstruction of Precambrian terranes of Northeastern Brazil along Cambrian strike-slip faults: a new model of geodynamic evolution and gold metallogeny in the State of Bahia

description: Abstract The Precambrian basement of Northeastern Brazil is the product of Rhyacian block convergence. The main deformation and intrusion of crustal granitoids occurred between 2.15 and 1.8 Ga ago. This large area has been subjected to long-lasting and rather uniform stresses during the Cambrian period. Gold provinces in Bahia represent metallogenetic products of distinct tectonothermal events. Gold mineralization took place during the Paleoproterozoic collision and the Cambrian convergence, respectively, accompanied by heat flow, crustal deformation, and granite intrusion. The tectonic framework of the region was reconstructed at ca. 700 Ma ago, considering the hypothesis of wrench-fault tectonics. The new hypothesis provides geological evidence and metallogenic constraints that make further investigation necessary, with reference to well-established São Francisco Craton concept and its peripheral fold belts.
DOI: 10.6084/m9.figshare.10025216
title: Study of the Relationship Between the Variability of Vegetation and Temperature Indexes of the Northeast Region of Brazil

description: Abstract The objective of this study was to investigate the interrelation between vegetation index variability (NDVI - Normalized Difference Vegetation Index, VCI - vegetation condition index) and temperature (TCI - Temperature Condition Index). on the Northeast of Brazil, using remote sensing data, NOAA-NESDIS database, obtained in the historical series from 1982 to 2011. Some inferences were made about the variation of these indices of vegetation and temperature, associated with climatic changes, in periods seasonal and in years of climatic contrasts under the influence of El Niños, La Niñas and Pacific Normal Conditions. The output data of the compilations of the Fortran routines were made available in graphs and generated by the GridS (Grid Analysis and Display System) software. The results showed a strong positive correlation between NDVI indices associated with IVC and TCI in the NEB semi-arid region. This result is due to the low percentages of precipitation that this region possesses, being thus more evident the strong relation with these indices of vegetation and temperature in the NEB semi-arid. As for other areas of the NEB region that have the highest precipitation index, the relationship between NDVI and precipitation was not as evident in this study.
DOI: 10.6084/m9.figshare.10025210
title: Nursing protocol in vascular trauma prevention: peripheral catheterization bundle in urgency

description: ABSTRACT Objective: to create, apply and analyze in clinical practice the effectiveness of a bundle to prevent peripheral vascular trauma to approach the peripheral venous puncture process. Method: action research with 435 adult participants in an emergency service from 2011 to 2013. Creation of the bundle for prevention of vascular trauma based on scientific evidence, ease of operation, observation and measurement with implantation through an educational intervention of the team of nursing. Effectiveness analyzed by descriptive and inferential statistics using chi-square. Consecutive sample with 95% confidence interval. Results: Five stages of the bundle were related to the catheter fixation, permanence and removal process. The incidence of vascular traumas due to vein punctures reduced by 46.41% after implantation of the bundle to prevent vascular trauma associated with emergency peripheral catheterization. Conclusion: The bundle in clinical practice reduced vascular traumas by venipuncture.
DOI: 10.6084/m9.figshare.10025216.v1
title: Study of the Relationship Between the Variability of Vegetation and Temperature Indexes of the Northeast Region of Brazil

description: Abstract The objective of this study was to investigate the interrelation between vegetation index variability (NDVI - Normalized Difference Vegetation Index, VCI - vegetation condition index) and temperature (TCI - Temperature Condition Index). on the Northeast of Brazil, using remote sensing data, NOAA-NESDIS database, obtained in the historical series from 1982 to 2011. Some inferences were made about the variation of these indices of vegetation and temperature, associated with climatic changes, in periods seasonal and in years of climatic contrasts under the influence of El Niños, La Niñas and Pacific Normal Conditions. The output data of the compilations of the Fortran routines were made available in graphs and generated by the GridS (Grid Analysis and Display System) software. The results showed a strong positive correlation between NDVI indices associated with IVC and TCI in the NEB semi-arid region. This result is due to the low percentages of precipitation that this region possesses, being thus more evident the strong relation with these indices of vegetation and temperature in the NEB semi-arid. As for other areas of the NEB region that have the highest precipitation index, the relationship between NDVI and precipitation was not as evident in this study.
DOI: 10.6084/m9.figshare.10025222.v1
title: The impact of e-commerce on the sale of air tickets: the perspective of managers of travel agencies in Campo Grande, MS

description: Abstract: This work aimed to verify the impact of the internet on the air ticket sales of the travel agencies of the city of Campo Grande, MS. The approach was to identify, from the point of view of the agency manager, the influence of technology on consumer habits. The database was used as a register of the Ministry of Tourism, which includes individuals and legal entities active in the tourism sector in the state. The methodology consisted of bibliographical and field research. The results confirm the theory studied regarding the impact of the internet on ticket trading and the profile of new consumers.
DOI: 10.6084/m9.figshare.10025213.v1
title: Reconstruction of Precambrian terranes of Northeastern Brazil along Cambrian strike-slip faults: a new model of geodynamic evolution and gold metallogeny in the State of Bahia

description: Abstract The Precambrian basement of Northeastern Brazil is the product of Rhyacian block convergence. The main deformation and intrusion of crustal granitoids occurred between 2.15 and 1.8 Ga ago. This large area has been subjected to long-lasting and rather uniform stresses during the Cambrian period. Gold provinces in Bahia represent metallogenetic products of distinct tectonothermal events. Gold mineralization took place during the Paleoproterozoic collision and the Cambrian convergence, respectively, accompanied by heat flow, crustal deformation, and granite intrusion. The tectonic framework of the region was reconstructed at ca. 700 Ma ago, considering the hypothesis of wrench-fault tectonics. The new hypothesis provides geological evidence and metallogenic constraints that make further investigation necessary, with reference to well-established São Francisco Craton concept and its peripheral fold belts.
DOI: 10.6084/m9.figshare.10025204
title: Educational technology for fatigue management related to antineoplastic chemotherapy

description: ABSTRACT Objective: To construct and validate an educational technology (ET) on fatigue and non-pharmacological strategies for the management of this symptom in people with cancer undergoing outpatient antineoplastic chemotherapy. Method: This is a methodological study composed of three stages: 1) elaboration of the ET using the theoretical-methodological model of Doak, Doak and Root; 2) validation of content and appearance by seven nurses via the content validity index (CVI); and 3) a pilot test with 10 patients. Results: The ET “Knowing and coping with fatigue” contemplates the definition of fatigue, its causes and the interventions of physical exercise practice, sleep hygiene, energy conservation and behavioral intervention. The overall CVI obtained with the judges was 0.95. Conclusion: The ET presented content and appearance validity for health education regarding fatigue related to antineoplastic chemotherapy in outpatient cancer patients.
DOI: 10.6084/m9.figshare.10025207
title: APPLICATION OF SPICES ON THE DEVELOPMENT OF LATENT FINGERMARKS: AN EXPERIMENT IN CHEMISTRY TEACHING

description: The development of fingermarks is an important step in criminal cases. Latent fingermarks require applications of reagents to be developed before they can be visualized. Different techniques to enhance fingermarks’ visualization have been employed and the powder dusting is the most common among them. The use of food spices as latent fingermarks developers could be an alternative method of experiment in chemistry teaching, considering that they are low cost and accessible. In this work, an experimental methodology was developed and can be applied in undergraduate chemistry teaching for the extraction of components from food spices, their chromatographic analysis and application on the development of latent fingermarks.
DOI: 10.6084/m9.figshare.10025210.v1
title: Nursing protocol in vascular trauma prevention: peripheral catheterization bundle in urgency

description: ABSTRACT Objective: to create, apply and analyze in clinical practice the effectiveness of a bundle to prevent peripheral vascular trauma to approach the peripheral venous puncture process. Method: action research with 435 adult participants in an emergency service from 2011 to 2013. Creation of the bundle for prevention of vascular trauma based on scientific evidence, ease of operation, observation and measurement with implantation through an educational intervention of the team of nursing. Effectiveness analyzed by descriptive and inferential statistics using chi-square. Consecutive sample with 95% confidence interval. Results: Five stages of the bundle were related to the catheter fixation, permanence and removal process. The incidence of vascular traumas due to vein punctures reduced by 46.41% after implantation of the bundle to prevent vascular trauma associated with emergency peripheral catheterization. Conclusion: The bundle in clinical practice reduced vascular traumas by venipuncture.
DOI: 10.14272/fgxftibxxnbpdu-uhfffaoysa-n/chmo0000470
title: mass spectrometry (MS) ()
title: InChI=1S/C78H120N4O4/c1-53(2)67(83-79-71(9,10)45-25-46-72(79,11)12)61-37-29-57(30-38-61)65(58-31-39-62(40-32-58)68(54(3)4)84-80-73(13,14)47-26-48-74(80,15)16)66(59-33-41-63(42-34-59)69(55(5)6)85-81-75(17,18)49-27-50-76(81,19)20)60-35-43-64(44-36-60)70(56(7)8)86-82-77(21,22)51-28-52-78(82,23)24/h29-44,53-56,67-70H,25-28,45-52H2,1-24H3

description: dataset for mass spectrometry (MS) MS (FAB, 3-NBA), m/z: 1178 [M+ + H], 1021 [M+ – TEMPO], 865 [M+ – 2 TEMPO], 708 [M+ – 3 TEMPO], 567, 552 [M+ – 4 TEMPO], 537 [M+ – 4 TEMPO – CH3], 525 [M+ – 3 C13H26NO – CH3], 156 [TEMPO+], 140 [TEMPO+ – O]. HRMS–FAB (m/z): [M – TEMPO]+ calcd for C69H102N3O3, 1020.7916; found, 1020.7917.
DOI: 10.6084/m9.figshare.10025198
title: Educational hypermedia in nursing assistance at birth: building and validation of content and appearance

description: ABSTRACT Objective: to build an educational hypermedia about nursing care at usual risk birth and to perform validation of content and appearance. Method: methodological research carried out following the following stages: content and planning of modules; media production and organization of tutorial units; organization of student space, tutor and communication between them; availability of hypermedia; assessment by experts in nursing and informatics; and implementation of proposed suggestions. Results: educational hypermedia showed to be a validated material, since it presented an optimum index of global content of 0.97 and statistical significance in the binomial test for the content and appearance. Conclusion: it is believed that the use of this material with undergraduate students in nursing will contribute to the quality of obstetric care, considering that it is an illustrated technology capable of favoring teaching-learning about normal humanized childbirth.
DOI: 10.6084/m9.figshare.10025204.v1
title: Educational technology for fatigue management related to antineoplastic chemotherapy

description: ABSTRACT Objective: To construct and validate an educational technology (ET) on fatigue and non-pharmacological strategies for the management of this symptom in people with cancer undergoing outpatient antineoplastic chemotherapy. Method: This is a methodological study composed of three stages: 1) elaboration of the ET using the theoretical-methodological model of Doak, Doak and Root; 2) validation of content and appearance by seven nurses via the content validity index (CVI); and 3) a pilot test with 10 patients. Results: The ET “Knowing and coping with fatigue” contemplates the definition of fatigue, its causes and the interventions of physical exercise practice, sleep hygiene, energy conservation and behavioral intervention. The overall CVI obtained with the judges was 0.95. Conclusion: The ET presented content and appearance validity for health education regarding fatigue related to antineoplastic chemotherapy in outpatient cancer patients.
DOI: 10.6084/m9.figshare.10025207.v1
title: APPLICATION OF SPICES ON THE DEVELOPMENT OF LATENT FINGERMARKS: AN EXPERIMENT IN CHEMISTRY TEACHING

description: The development of fingermarks is an important step in criminal cases. Latent fingermarks require applications of reagents to be developed before they can be visualized. Different techniques to enhance fingermarks’ visualization have been employed and the powder dusting is the most common among them. The use of food spices as latent fingermarks developers could be an alternative method of experiment in chemistry teaching, considering that they are low cost and accessible. In this work, an experimental methodology was developed and can be applied in undergraduate chemistry teaching for the extraction of components from food spices, their chromatographic analysis and application on the development of latent fingermarks.
DOI: 10.14272/fgxftibxxnbpdu-uhfffaoysa-n/chmo0000593
title: 1H nuclear magnetic resonance spectroscopy (1H NMR) ()
title: InChI=1S/C78H120N4O4/c1-53(2)67(83-79-71(9,10)45-25-46-72(79,11)12)61-37-29-57(30-38-61)65(58-31-39-62(40-32-58)68(54(3)4)84-80-73(13,14)47-26-48-74(80,15)16)66(59-33-41-63(42-34-59)69(55(5)6)85-81-75(17,18)49-27-50-76(81,19)20)60-35-43-64(44-36-60)70(56(7)8)86-82-77(21,22)51-28-52-78(82,23)24/h29-44,53-56,67-70H,25-28,45-52H2,1-24H3

description: dataset for 1H nuclear magnetic resonance spectroscopy (1H NMR) 1H NMR (400 MHz, CD2Cl2 [5.32 ppm], ppm) δ = 6.95–6.89 (m, 16H, CarH), 4.38 (d, J = 6.1 Hz, 4H, CHO), 2.45–2.38 (m, 4H, CH(CH3)2), 1.68–0.99 (m, 60H, CH2 CH3 TEMPO), 0.84–0.80 (m, 12H, CH3 Sidechain), 0.75–0.72 (m, 12H, CH3 Sidechain), 0.55 (bs, 12H, CH3 TEMPO).
DOI: 10.6084/m9.figshare.10025195
title: DEVELOPMENT OF METHODOLOGY OF LATENT FINGERPRINT REVELATION WITH CHALCONES

description: Fingerprints are unique for each individual contributing to human identification in forensic cases. Visualization of latent fingerprints usually involves the use of a chemical substance that creates a contrast between fingerprint residues and the surface on which the print was deposited. Commercial powders used as fingerprint developers by papilloscopy have relatively high costs due to their importation and chemical composition. (E-1,3-diphenylprop-2-en-1-one, E-1-phenyl-3-(4-methylphenyl))prop-2-en-1-one but only one compound was highlighted, E-3-(3-nitrophenyl)-1-phenylprop-2-em-1-one). The composite was selected for its suitable properties (adhesion and texture) of visualization of the digital, providing the obtaining of clear revelations with identification of minutiae and singular points of the fingerprints. Identification, magnetic resonance, granulometry and contact surface evaluation with chalcones such as sebaceous and natural deposition with development in different materials such as plastic, metal and glass were applied for the application of fingerprint development. The compound was tested in eight volunteers regardless of gender and age, presenting satisfactory results for fingerprint development on glass and metal surfaces.
DOI: 10.14272/fgxftibxxnbpdu-uhfffaoysa-n/chmo0000595
title: 13C nuclear magnetic resonance spectroscopy (13C NMR) ()
title: InChI=1S/C78H120N4O4/c1-53(2)67(83-79-71(9,10)45-25-46-72(79,11)12)61-37-29-57(30-38-61)65(58-31-39-62(40-32-58)68(54(3)4)84-80-73(13,14)47-26-48-74(80,15)16)66(59-33-41-63(42-34-59)69(55(5)6)85-81-75(17,18)49-27-50-76(81,19)20)60-35-43-64(44-36-60)70(56(7)8)86-82-77(21,22)51-28-52-78(82,23)24/h29-44,53-56,67-70H,25-28,45-52H2,1-24H3

description: dataset for 13C nuclear magnetic resonance spectroscopy (13C NMR) 13C NMR (100 MHz, CD2Cl2 [54.0 ppm], ppm) δ = 143.2 (4C, Cq), 140.7 (2C, Cq), 139.3 (4C, Cq), 130.9 (8C, Car.H), 128.9 (8C, CarH), 91.5 (4C, CHO), 60.5 (4C, Cq TEMPO), 60.0 (4C, Cq TEMPO), 41.3 (8C, CH2 TEMPO), 35.1 (4C, CH3 TEMPO), 34.7 (4C, CH3 TEMPO), 32.0 (4C, CH(CH3)2), 20.8 (4C, CH3 TEMPO), 20.8 (4C, CH3 Sidechain), 20.7 (4C, CH3 TEMPO), 17.8 (4C, CH2 TEMPO), 17.5 (2C, CH3 Sidechain), 17.4 (2C, CH3 Sidechain).
DOI: 10.6084/m9.figshare.10025192
title: Impacts of health of users with HIV/AIDS in a specialized service

description: ABSTRACT Objective: to understand the perception of users of a Specialized Care Service (SAE- Serviço de Assistência Especializada) in HIV/AIDS about their oral health. Method: qualitative research that used the techniques of participant observation and focal group. For the analysis of the material produced, categories of analysis, construction of dialogical map and identification of linguistic repertoires were used. Results: impacts arising from oral health problems such as: inability to eat properly, feeling ashamed due to tooth loss, inability to perform physical exercises and, as the main barrier to access to dental treatment, fear of exposure to practices of discrimination and prejudice. Final considerations: we need the implementation of policies of Permanent Education to all professionals involved in the care for this population, to ensure users’ rights, ensure qualified care, and create security and trust relationships with individuals living with HIV/AIDS, in access to services.