cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.17632/rjm3gknm27.1
title: Full-Self-Powered Humidity Sensor Based on Electrochemical Aluminum–Water Reaction

description: This dataset contains raw data from the measurements presented as the figures in the article: Full-Self-Powered Humidity Sensor Based on Electrochemical Aluminum–Water Reaction
DOI: 10.17632/hsj6hrysxh.2
title: Dataset of calcareous nannoplankton and smaller benthic foraminifera from a nummulitic accumulation (Bartonian, Eocene, Transylvanian Basin, Romania)

description: Data reported herein, have been obtained from the micropaleontological analysis of the middle Eocene (Bartonian) calcareous nannoplankton and smaller benthic foraminifera record from nine representative areas located in the Gilău and Meseș area from the Transylvanian Basin, Romania. The micropaleontological data comprise raw species counts (Tables 1, 2), relative abundances (Tables 3, 4) and ARCSIN-normalized values used to perform multivariate analysis (Tables 5, 6) for both calcareous nannoplankton and smaller benthic foraminiferal assemblages. The ARCSIN-normalized datasets (Tables 5, 6) include only taxa with more than ~2% relative abundance (Table 5, calcareous nannoplankton) and only taxa having more than 1% relative abundance (Table 6, smaller benthic foraminfiera ). The calculated abundance data of smaller benthic foraminiferal taxa, groups and microhabitats, the calculated benthic foraminifera dissolved oxygen index – BFOI are presented in Table 7, whilst the diversity indices of smaller benthic foraminifera are included in Table 8. Same background color in each table represents the same outcrop and the samples are stored in case of each outcrop in stratigraphic order (samples with the same style – italic and bold – belong to the same stratigraphic level). In the case of the calcareous nannoplankton datasets (Tables 1, 3, 5) the samples written with red had less than 50 specimens and they were excluded from the statistical analysis.
DOI: 10.17632/c6pdfrwxgj.6
title: Landscape and Selection of Vaccine Epitopes in SARS-CoV-2

description: Early in the pandemic, we designed a SARS-CoV-2 peptide vaccine containing epitope regions optimized for concurrent B cell, CD4+ T cell, and CD8+ T cell stimulation. The rationale for this design was to drive both humoral and cellular immunity with high specificity while avoiding undesired effects such as antibody-dependent enhancement (ADE). In this study, we combine computational prediction of T cell epitopes, recently published B cell epitope mapping studies, and epitope accessibility to select candidate peptide vaccines for SARS-CoV-2. We begin with an exploration of the space of possible T cell epitopes in SARS-CoV-2 with interrogation of predicted HLA-I and HLA-II ligands, overlap between predicted ligands, protein source, as well as concurrent human/murine coverage. Beyond MHC affinity, T cell vaccine candidates were further refined by predicted immunogenicity, viral source protein abundance, sequence conservation, coverage of high frequency HLA alleles and co-localization of CD4+ and CD8+ T cell epitopes. B cell epitope regions were chosen from linear epitope mapping studies of convalescent patient serum, followed by filtering to select regions with surface accessibility, high sequence conservation, spatial localization near functional domains of the spike glycoprotein, and avoidance of glycosylation sites. From 58 initial candidates, three B cell epitope regions were identified. By combining these B cell and T cell analyses, as well as a manufacturability heuristic, we propose a set of SARS-CoV-2 vaccine peptides for use in subsequent murine studies. The immunogenicity of the selected peptides was validated using ELISpot and ELISA following murine vaccination. We also curated a dataset of almost a thousand observed T-cell epitopes from convalescent COVID-19 patients across eight studies. Our vaccine selection process appears to be effective at predicting recurrent T-cell epitopes and strong T-cell responses were observed in mice following vaccination. Humoral responses were deficient, likely due to the unrestricted conformational space inhabited by linear vaccine peptides. Overall, we find our selection process and vaccine formulation to be appropriate for identifying T-cell epitopes and eliciting T-cell responses against those epitopes.
DOI: 10.17632/mhndxw46x9.1
title: Home Bias in Emerging Markets Research Dataset

description: This dataset is created to investigate home bias in emerging markets. The research hypothesis is whether emerging markets show home bias or not. The dataset includes data from open sources such as International Monetary Fund (CPIS), The World Bank, World Federation of Exchanges, Bank of International Settlements, The Central Bank of Russian Federation and some other websites (cited in References).
DOI: 10.17632/6dpvtyfnkb.1
title: ВКР. Бондарев А. э611мирэк

description: Данные демонстрируют влияние новой волны протекционизма на мировую торговлю
DOI: 10.17632/bz9tvmkh3y.1
title: Chilblain COVID

description: Supplemental documents "SARS-CoV-2-SPECIFIC T CELL IMMUNITY IN PEDIATRIC PATIENTS WITH CHILBLAIN LESIONS DURING THE COVID-19 PANDEMIC: A CASE SERIES"
DOI: 10.17632/2rty7jbm7g.1
title: Comparison of the Metabolic Profiles in the Plasma and Urine Samples between Autistic and Typically Developing Boys: A Preliminary Study

description: Introduction: Autism spectrum disorder (ASD) is defined as a pervasive developmental disorder which is caused by genetic and environmental risk factors. Besides the core behavioral symptoms, accumulated results indicate children with ASD also share some metabolic abnormalities. Objectives: To analyze the comprehensive metabolic profiles in both of the first-morning urine and plasma samples collected from the same cohort of autistic boys. Methods: In this study, 30 autistic boys and 30 tightly matched healthy control (HC) boys (age range: 2.4 ~ 6.7 years) were recruited. First-morning urine and plasma samples were collected and the liquid chromatography–mass spectrometry (LC-MS) was applied to obtain the untargeted metabolic profiles. The acquired data were processed by multivariate analysis and the screened metabolites were grouped by metabolic pathway. Results: Different discriminating metabolites were found in plasma and urine samples. Notably, taurine and catechol levels were decreased in urine but increased in plasma in the same cohort of ASD children. Enriched pathway analysis revealed that perturbations in taurine and hypotaurine metabolism, phenylalanine metabolism and arginine and proline metabolism could be found in both of the plasma and urine samples. Conclusion: These preliminary results suggest that a series of common metabolic perturbations exist in children with ASD, and confirmed the importance to have a comprehensive analysis of the metabolites in different biological samples to reveal the full picture of the complex metabolic patterns associated with ASD. Further targeted analyses are needed to validate these results in a larger cohort. Note: Other data used in this study are available from the corresponding author upon request. (zhangrong@bjmu.edu.cn)
DOI: 10.17632/9dxfcfgxxf.1
title: ilknur Paçalı

description: The data of this research were obtained from Turkish teachers working in state secondary schools in the province of Siirt, Turkey for the opinions of teachers about the distance education process in Turkish teaching. The data of the study were collected through interviews, one of the qualitative research data collection methods. In this context, semi-structured interview forms were used. In order to preserve the originality of the researcher data, the files whose data language is Turkish were uploaded to the system. Data obtained from the research; codes, categories and themes were created and reflected in the findings. Research data; Teachers' Opinions on Distance Education in Teaching Basic Language Skills, Teachers' Views on the Practices Used in Distance Education, Teachers' Views on the Benefits of Distance Education, Teachers' Views on the Problems Encountered in Distance Education, and Teachers' Views on Solving the Problems Encountered in Distance Education and Presented in the article. Within the scope of the research findings; In the distance education activities in Turkish teaching, the studies on listening, speaking and reading skills have been fruitful, but there are deficiencies in the field of writing skills; It was concluded that students' not having equal opportunities and lack of technological infrastructure hinders the distance education process, but students who have these conditions have increased their interest in Turkish lessons.
DOI: 10.17632/cgsrt49p5x.1
title: Changes In Health Insurance Coverage, Access To Care, And Income-Based Disparities Among US Adults, 2011–17

description: Griffith, KN, Jones, DK, Bor, JH, & Sommers, BD. (2020). “Changes in health insurance coverage, access to care, and income-based disparities among US adults, 2011–17.” Health Affairs 39(2), 319-326. These materials are provided for public use without restriction. Please cite this work if it these materials are referenced in any publications. For comments, corrections, or questions please email Dr. Kevin Griffith: kevin.griffith@vumc.org
DOI: 10.6084/m9.figshare.13148375
title: A Co(II) coordination complex: local analgesia activity by reducing content of local acetylcholine

description: A new Co(II)-containing coordination complex with the chemical formula of [CoL<sub>2</sub>(SCN)<sub>2</sub>](H<sub>2</sub>O)<sub>2</sub> (<b>1</b>) has been assembled from the Co(NO<sub>3</sub>)<sub>2</sub>·6H<sub>2</sub>O with a tripyridyltriazole ligand 3-(2-pyridyl)-4-(4-pyridyl)-5-(3-pyridyl)-1,2,4-triazole by introduction of the NH<sub>4</sub>SCN as the additive reagent. Complex <b>1</b> has been studied via the single-crystal X-ray diffraction, elemental analysis, powder X-ray diffraction (PXRD) along with the thermogravimetric (TG) analysis. Furthermore, its local anesthesia activity was evaluated. Firstly, the hot plate analgesic experiment was performed, and the local anesthesia activity was assessed. In addition to this, the levels of the acetylcholine in local were also measured with ELISA detection kit. A new Co(II)-containing coordination complex has been assembled from the Co(NO<sub>3</sub>)<sub>2</sub>·6H<sub>2</sub>O with a tripyridyltriazole ligand 3-(2-pyridyl)-4-(4-pyridyl)-5-(3-pyridyl)-1,2,4-triazole by introduction of the NH<sub>4</sub>SCN as the additive reagent. The local anesthesia activity of <b>1</b> was evaluated via hot plate analgesic experiment. The ELISA study was performed to measure the content of acetylcholine in local.
DOI: 10.6084/m9.figshare.13148375.v1
title: A Co(II) coordination complex: local analgesia activity by reducing content of local acetylcholine

description: A new Co(II)-containing coordination complex with the chemical formula of [CoL<sub>2</sub>(SCN)<sub>2</sub>](H<sub>2</sub>O)<sub>2</sub> (<b>1</b>) has been assembled from the Co(NO<sub>3</sub>)<sub>2</sub>·6H<sub>2</sub>O with a tripyridyltriazole ligand 3-(2-pyridyl)-4-(4-pyridyl)-5-(3-pyridyl)-1,2,4-triazole by introduction of the NH<sub>4</sub>SCN as the additive reagent. Complex <b>1</b> has been studied via the single-crystal X-ray diffraction, elemental analysis, powder X-ray diffraction (PXRD) along with the thermogravimetric (TG) analysis. Furthermore, its local anesthesia activity was evaluated. Firstly, the hot plate analgesic experiment was performed, and the local anesthesia activity was assessed. In addition to this, the levels of the acetylcholine in local were also measured with ELISA detection kit. A new Co(II)-containing coordination complex has been assembled from the Co(NO<sub>3</sub>)<sub>2</sub>·6H<sub>2</sub>O with a tripyridyltriazole ligand 3-(2-pyridyl)-4-(4-pyridyl)-5-(3-pyridyl)-1,2,4-triazole by introduction of the NH<sub>4</sub>SCN as the additive reagent. The local anesthesia activity of <b>1</b> was evaluated via hot plate analgesic experiment. The ELISA study was performed to measure the content of acetylcholine in local.
DOI: 10.6084/m9.figshare.14198160
title: Synthesis, X-ray crystal structures, and electrochemistry of two diiron ethane-1,2-dithiolate complexes containing tris(4-trifluoromethylphenyl)phosphine or triethyl phosphite

description: Two diiron ethane-1,2-dithiolate complexes were prepared and structurally characterized. Reactions of the parent complex [Fe<sub>2</sub>(CO)<sub>6</sub>(<i>μ</i>-SCH<sub>2</sub>CH<sub>2</sub>S)] (<b>1</b>) with tris(4-trifluoromethylphenyl)phosphine or triethyl phosphite and Me<sub>3</sub>NO·2H<sub>2</sub>O as the oxidative reagent resulted in the formation of the phosphine-substituted analog [Fe<sub>2</sub>(CO)<sub>5</sub>{P(4-C<sub>6</sub>H<sub>4</sub>CF<sub>3</sub>)<sub>3</sub>}(<i>μ</i>-SCH<sub>2</sub>CH<sub>2</sub>S)] (<b>2</b>) and phosphite-substituted analogue [Fe<sub>2</sub>(CO)<sub>5</sub>{P(OCH<sub>2</sub>CH<sub>3</sub>)<sub>3</sub>}(<i>μ</i>-SCH<sub>2</sub>CH<sub>2</sub>S)] (<b>3</b>) in 84% and 78% yields, respectively. The new complexes <b>2</b> and <b>3</b> were characterized by elemental analysis, IR, NMR spectroscopy, and single crystal X-ray diffraction analysis. Moreover, the electrochemical properties of both complexes were studied by cyclic voltammetry.
DOI: 10.6084/m9.figshare.14198160.v1
title: Synthesis, X-ray crystal structures, and electrochemistry of two diiron ethane-1,2-dithiolate complexes containing tris(4-trifluoromethylphenyl)phosphine or triethyl phosphite

description: Two diiron ethane-1,2-dithiolate complexes were prepared and structurally characterized. Reactions of the parent complex [Fe<sub>2</sub>(CO)<sub>6</sub>(<i>μ</i>-SCH<sub>2</sub>CH<sub>2</sub>S)] (<b>1</b>) with tris(4-trifluoromethylphenyl)phosphine or triethyl phosphite and Me<sub>3</sub>NO·2H<sub>2</sub>O as the oxidative reagent resulted in the formation of the phosphine-substituted analog [Fe<sub>2</sub>(CO)<sub>5</sub>{P(4-C<sub>6</sub>H<sub>4</sub>CF<sub>3</sub>)<sub>3</sub>}(<i>μ</i>-SCH<sub>2</sub>CH<sub>2</sub>S)] (<b>2</b>) and phosphite-substituted analogue [Fe<sub>2</sub>(CO)<sub>5</sub>{P(OCH<sub>2</sub>CH<sub>3</sub>)<sub>3</sub>}(<i>μ</i>-SCH<sub>2</sub>CH<sub>2</sub>S)] (<b>3</b>) in 84% and 78% yields, respectively. The new complexes <b>2</b> and <b>3</b> were characterized by elemental analysis, IR, NMR spectroscopy, and single crystal X-ray diffraction analysis. Moreover, the electrochemical properties of both complexes were studied by cyclic voltammetry.
DOI: 10.6084/m9.figshare.13160228
title: Influences of mixed solvent DMF/H<sub>2</sub>O or DMA/H<sub>2</sub>O on the topologies of coordination polymers

description: Four coordination polymers were prepared by solvent-thermal method with Zn(NO<sub>3</sub>)<sub>2</sub>·6H<sub>2</sub>O and H<sub>2</sub>dmbdc (H<sub>2</sub>dmbdc= 2,5-dimethylbenzenedicarboxylic acid) or H<sub>2</sub>ip(H<sub>2</sub>ip = isophthalic acid). Complex <b>1</b>, [Zn<sub>3</sub>(dmbdc)<sub>3</sub>(dmf)<sub>2</sub>]<sub>n</sub> shows 2D (3,6) net with trizinc secondary building units (SBUs) was obtained in DMF; Complex <b>2,</b> {[Zn<sub>4</sub>O(dmbdc)<sub>3</sub>(dmf)NH(CH<sub>3</sub>)<sub>2</sub>]·DMF}<sub>n</sub> was synthesized in DMF/H<sub>2</sub>O (volume ratio 1:1), and Complex 2 is 3D porous framework with Zn<sub>4</sub>O tetrahedral SBUs; however, only Complex <b>3</b>, [Zn<sub>3</sub>(dmbdc)<sub>3</sub>(dma)<sub>2</sub>]<sub>n</sub> was obtained in DMA and DMA/H<sub>2</sub>O (volume ratio 1:1), and Complex <b>3</b> is isomorphic to <b>1</b> except the DMF was replaced with DMA; Complex <b>4</b>, {[Zn<sub>4</sub>O(H<sub>2</sub>O)(ip)<sub>3</sub> (dma)]·2DMA}<sub>n</sub> also contain Zn<sub>4</sub>O tetrahedral SBUs in both DMA and DMA/H<sub>2</sub>O(1:1). Therefore, the change of single solvent (DMF or DMA) have not obvious effect on the structures of coordination polymers, however, there are evident change in the topology of coordination polymers when we make use of water mixed with the different polarity solvents DMF or DMA.
DOI: 10.6084/m9.figshare.13160228.v1
title: Influences of mixed solvent DMF/H<sub>2</sub>O or DMA/H<sub>2</sub>O on the topologies of coordination polymers

description: Four coordination polymers were prepared by solvent-thermal method with Zn(NO<sub>3</sub>)<sub>2</sub>·6H<sub>2</sub>O and H<sub>2</sub>dmbdc (H<sub>2</sub>dmbdc= 2,5-dimethylbenzenedicarboxylic acid) or H<sub>2</sub>ip(H<sub>2</sub>ip = isophthalic acid). Complex <b>1</b>, [Zn<sub>3</sub>(dmbdc)<sub>3</sub>(dmf)<sub>2</sub>]<sub>n</sub> shows 2D (3,6) net with trizinc secondary building units (SBUs) was obtained in DMF; Complex <b>2,</b> {[Zn<sub>4</sub>O(dmbdc)<sub>3</sub>(dmf)NH(CH<sub>3</sub>)<sub>2</sub>]·DMF}<sub>n</sub> was synthesized in DMF/H<sub>2</sub>O (volume ratio 1:1), and Complex 2 is 3D porous framework with Zn<sub>4</sub>O tetrahedral SBUs; however, only Complex <b>3</b>, [Zn<sub>3</sub>(dmbdc)<sub>3</sub>(dma)<sub>2</sub>]<sub>n</sub> was obtained in DMA and DMA/H<sub>2</sub>O (volume ratio 1:1), and Complex <b>3</b> is isomorphic to <b>1</b> except the DMF was replaced with DMA; Complex <b>4</b>, {[Zn<sub>4</sub>O(H<sub>2</sub>O)(ip)<sub>3</sub> (dma)]·2DMA}<sub>n</sub> also contain Zn<sub>4</sub>O tetrahedral SBUs in both DMA and DMA/H<sub>2</sub>O(1:1). Therefore, the change of single solvent (DMF or DMA) have not obvious effect on the structures of coordination polymers, however, there are evident change in the topology of coordination polymers when we make use of water mixed with the different polarity solvents DMF or DMA.
DOI: 10.6084/m9.figshare.13317538
title: Hydrothermal synthesis, structure and properties of a new 3D two-fold Co-based coordination framework

description: A new 3D coordination polymer, [Co<sub>2</sub>(MIP)<sub>2</sub>(BMIP)]<i><sub>n</sub></i> (<b>1</b>), [H<sub>2</sub>MIP = 5-methyl-isophthalic acid, BMIP = 1,5-bis-(2-methyl-imidazol)pentane] has been synthesized and characterized by single crystal X-ray diffraction analysis. The results of structural analyses show that <b>1</b> has a two-fold interpenetrated 3D network with a <b>pcu</b> topology. In addition, the luminescent, electrochemical properties and degradation of MB and MO of the complex were studied. The photocatalytic mechanism was proposed and confirmed by trapping experiments of radical species.
DOI: 10.6084/m9.figshare.13317538.v1
title: Hydrothermal synthesis, structure and properties of a new 3D two-fold Co-based coordination framework

description: A new 3D coordination polymer, [Co<sub>2</sub>(MIP)<sub>2</sub>(BMIP)]<i><sub>n</sub></i> (<b>1</b>), [H<sub>2</sub>MIP = 5-methyl-isophthalic acid, BMIP = 1,5-bis-(2-methyl-imidazol)pentane] has been synthesized and characterized by single crystal X-ray diffraction analysis. The results of structural analyses show that <b>1</b> has a two-fold interpenetrated 3D network with a <b>pcu</b> topology. In addition, the luminescent, electrochemical properties and degradation of MB and MO of the complex were studied. The photocatalytic mechanism was proposed and confirmed by trapping experiments of radical species.
DOI: 10.6084/m9.figshare.13312078
title: Structural characterization and anti-cancer activity of a Cu(II)-based coordination polymer

description: By using a mixed-ligand approach, a new Cu(II)-based coordination polymer (CP) with the chemical formula of {[Cu<sub>2</sub>(ptd)<sub>2</sub>(IPA)<sub>2</sub>]·2H<sub>2</sub>O}<i><sub>n</sub></i> (<b>1</b>, ptd = 4′-(4-pyridine)4,2′:2′,4′′-terpyridine, H<sub>2</sub>IPA = isophthalic acid) has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, IR spectroscopic, elemental and thermogravimetric analyses. Furthermore, the anticancer activity of the compound on the CHO cancer cell was determined, the CCK-8 assay was performed to explore the inhibitory activity of the compound on the cell viability. the IC<sub>50</sub> values were calculated at the same time. The suppression of the compound on the cancer cell migration and invasion ability was also determined with trans-well assay.
DOI: 10.6084/m9.figshare.13312078.v1
title: Structural characterization and anti-cancer activity of a Cu(II)-based coordination polymer

description: By using a mixed-ligand approach, a new Cu(II)-based coordination polymer (CP) with the chemical formula of {[Cu<sub>2</sub>(ptd)<sub>2</sub>(IPA)<sub>2</sub>]·2H<sub>2</sub>O}<i><sub>n</sub></i> (<b>1</b>, ptd = 4′-(4-pyridine)4,2′:2′,4′′-terpyridine, H<sub>2</sub>IPA = isophthalic acid) has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, IR spectroscopic, elemental and thermogravimetric analyses. Furthermore, the anticancer activity of the compound on the CHO cancer cell was determined, the CCK-8 assay was performed to explore the inhibitory activity of the compound on the cell viability. the IC<sub>50</sub> values were calculated at the same time. The suppression of the compound on the cancer cell migration and invasion ability was also determined with trans-well assay.
DOI: 10.17632/8xfnk93bmd.1
title: Visual Supports Survey Results

description: The research hypotheses are: 1. The use of visual supports for children will be effective in improving patient experience during their visit to the paediatric emergency department during the COVID-19 pandemic. 2. The visual supports would be more effective for children with special educational needs, compared to those who are typically developing. A ‘Special Care Kit’ was created to provide resources to support children (both neurotypical and those with developmental needs), as well as their caregivers during their visits to healthcare facilities for COVID-19 related issues. The kit comprises a series of visual supports in the form of visual schedules, social stories, pictorial boards and animated videos with the aim of illustrating and explaining the different COVID-19 processes in a developmentally appropriate manner. The kit was made available online for free. Physical copies were also distributed to community clinics managing COVID-19 suspects, ambulances and hospital emergency departments. We conducted a short study to assess the effectiveness of the ‘Special Care Kit’ in improving the experience of children and caregivers during their COVID-19 related healthcare encounters. This was assessed through voluntary, anonymous surveys completed by parents or caregivers who had a COVID-19 related healthcare consult in an emergency department of a tertiary hospital from June to December 2020. All children and their accompanying caregivers were shown a relevant aspect of the kit prior to or during their medical encounter. Information collected included demographic data, developmental diagnosis, how the child usually communicates, as well as qualitative feedback on the supports. Descriptive statistics were used to analyse results. A total of 46 caregivers took part in the study. The mean age of patients was 5.1 years. Six (13.0%) patients had developmental difficulties (four patients had speech and language delay, two patients had autism spectrum disorder) with three of them being pre-verbal (using pictures or pointing and gestures to communicate). The rest of the patients were reported to have appropriate development. Almost all (98.0%, 45/46) caregivers felt that the Special Care Kit helped their child have a better healthcare experience, with thirty-nine percent (18/46) of them noting that their child was calmer and took the whole experience better than expected. Sixty-one percent (28/46) of caregivers felt that their child had a better understanding of what was going to happen during the encounter, and twenty-eight percent (13/46) felt that the supports helped with the communication between the medical team and the family. The majority (91.0%, 42/46) would like to have access to other similar supports during their child’s future healthcare visits.