cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.17188/1204735
title: Materials Data on Tb2Se2O7 by Materials Project

description: Tb2Se2O7 is Zircon-like structured and crystallizes in the tetragonal P4_2/ncm space group. The structure is three-dimensional. Tb3+ is bonded in a 8-coordinate geometry to eight O2- atoms. There are a spread of Tb–O bond distances ranging from 2.27–2.54 Å. Se4+ is bonded in a trigonal non-coplanar geometry to three O2- atoms. All Se–O bond lengths are 1.74 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded to four equivalent Tb3+ atoms to form edge-sharing OTb4 tetrahedra. In the second O2- site, O2- is bonded in a distorted trigonal planar geometry to two equivalent Tb3+ and one Se4+ atom. In the third O2- site, O2- is bonded in a 3-coordinate geometry to two equivalent Tb3+ and one Se4+ atom.
DOI: 10.17188/1204736
title: Materials Data on Cs2PdCl4 by Materials Project

description: Cs2PdCl4 crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. Cs1+ is bonded in a body-centered cubic geometry to eight Cl1- atoms. There are four shorter (3.61 Å) and four longer (3.62 Å) Cs–Cl bond lengths. Pd2+ is bonded in a square co-planar geometry to four Cl1- atoms. All Pd–Cl bond lengths are 2.34 Å. There are two inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded to four equivalent Cs1+ and one Pd2+ atom to form a mixture of distorted corner, edge, and face-sharing ClCs4Pd square pyramids. In the second Cl1- site, Cl1- is bonded to four equivalent Cs1+ and one Pd2+ atom to form a mixture of distorted corner, edge, and face-sharing ClCs4Pd square pyramids.
DOI: 10.17188/1204737
title: Materials Data on Ca3BN3 by Materials Project

description: Ca3BN3 crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. there are two inequivalent Ca2+ sites. In the first Ca2+ site, Ca2+ is bonded to six N3- atoms to form CaN6 octahedra that share corners with four equivalent CaN6 octahedra, edges with four equivalent CaN6 octahedra, and edges with eight equivalent CaN5 square pyramids. The corner-sharing octahedral tilt angles are 0°. There are four shorter (2.53 Å) and two longer (2.73 Å) Ca–N bond lengths. In the second Ca2+ site, Ca2+ is bonded to five N3- atoms to form distorted CaN5 square pyramids that share corners with five equivalent CaN5 square pyramids, edges with four equivalent CaN6 octahedra, and edges with four equivalent CaN5 square pyramids. There are one shorter (2.26 Å) and four longer (2.57 Å) Ca–N bond lengths. B3+ is bonded in a linear geometry to two equivalent N3- atoms. Both B–N bond lengths are 1.35 Å. There are two inequivalent N3- sites. In the first N3- site, N3- is bonded in a distorted single-bond geometry to five Ca2+ and one B3+ atom. In the second N3- site, N3- is bonded to six Ca2+ atoms to form a mixture of corner and edge-sharing NCa6 octahedra. The corner-sharing octahedral tilt angles are 0°.
DOI: 10.17188/1204738
title: Materials Data on Sr2AuN by Materials Project

description: Sr2AuN crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. there are two inequivalent Sr2+ sites. In the first Sr2+ site, Sr2+ is bonded in a 5-coordinate geometry to one Au1- and four equivalent N3- atoms. The Sr–Au bond length is 3.35 Å. There are two shorter (2.60 Å) and two longer (2.68 Å) Sr–N bond lengths. In the second Sr2+ site, Sr2+ is bonded in a distorted L-shaped geometry to six equivalent Au1- and two equivalent N3- atoms. There are two shorter (3.30 Å) and four longer (3.47 Å) Sr–Au bond lengths. Both Sr–N bond lengths are 2.59 Å. Au1- is bonded in a 9-coordinate geometry to seven Sr2+ and two equivalent Au1- atoms. Both Au–Au bond lengths are 3.06 Å. N3- is bonded to six Sr2+ atoms to form a mixture of corner and edge-sharing NSr6 octahedra. The corner-sharing octahedral tilt angles are 18°.
DOI: 10.17188/1204739
title: Materials Data on RbBF4 by Materials Project

description: RbBF4 crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Rb1+ is bonded in a 12-coordinate geometry to ten F1- atoms. There are a spread of Rb–F bond distances ranging from 2.97–3.24 Å. B3+ is bonded in a tetrahedral geometry to four F1- atoms. There are a spread of B–F bond distances ranging from 1.41–1.43 Å. There are three inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to three equivalent Rb1+ and one B3+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Rb1+ and one B3+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to three equivalent Rb1+ and one B3+ atom.
DOI: 10.17188/1204740
title: Materials Data on RbHfF5 by Materials Project

description: RbHfF5 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. Rb1+ is bonded in a 11-coordinate geometry to eleven F1- atoms. There are a spread of Rb–F bond distances ranging from 2.82–3.29 Å. Hf4+ is bonded in a 8-coordinate geometry to eight F1- atoms. There are a spread of Hf–F bond distances ranging from 2.01–2.25 Å. There are five inequivalent F1- sites. In the first F1- site, F1- is bonded in a distorted trigonal planar geometry to one Rb1+ and two equivalent Hf4+ atoms. In the second F1- site, F1- is bonded in a distorted bent 150 degrees geometry to two equivalent Rb1+ and two equivalent Hf4+ atoms. In the third F1- site, F1- is bonded in a distorted single-bond geometry to three equivalent Rb1+ and one Hf4+ atom. In the fourth F1- site, F1- is bonded in a distorted single-bond geometry to three equivalent Rb1+ and one Hf4+ atom. In the fifth F1- site, F1- is bonded in a distorted bent 150 degrees geometry to two equivalent Rb1+ and two equivalent Hf4+ atoms.
DOI: 10.17188/1204741
title: Materials Data on Y2P4O13 by Materials Project

description: Y2P4O13 crystallizes in the orthorhombic C222_1 space group. The structure is three-dimensional. Y3+ is bonded to seven O2- atoms to form distorted YO7 pentagonal bipyramids that share corners with five PO4 tetrahedra, edges with two equivalent YO7 pentagonal bipyramids, and an edgeedge with one PO4 tetrahedra. There are a spread of Y–O bond distances ranging from 2.23–2.53 Å. There are two inequivalent P5+ sites. In the first P5+ site, P5+ is bonded to four O2- atoms to form PO4 tetrahedra that share corners with three equivalent YO7 pentagonal bipyramids, a cornercorner with one PO4 tetrahedra, and an edgeedge with one YO7 pentagonal bipyramid. There are a spread of P–O bond distances ranging from 1.51–1.63 Å. In the second P5+ site, P5+ is bonded to four O2- atoms to form PO4 tetrahedra that share corners with two equivalent YO7 pentagonal bipyramids and corners with two PO4 tetrahedra. There are a spread of P–O bond distances ranging from 1.50–1.60 Å. There are seven inequivalent O2- sites. In the first O2- site, O2- is bonded in a 1-coordinate geometry to two equivalent Y3+ and one P5+ atom. In the second O2- site, O2- is bonded in a bent 150 degrees geometry to two equivalent P5+ atoms. In the third O2- site, O2- is bonded in a bent 120 degrees geometry to two P5+ atoms. In the fourth O2- site, O2- is bonded in a linear geometry to one Y3+ and one P5+ atom. In the fifth O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one Y3+ and one P5+ atom. In the sixth O2- site, O2- is bonded in a bent 150 degrees geometry to one Y3+ and one P5+ atom. In the seventh O2- site, O2- is bonded in a 1-coordinate geometry to two equivalent Y3+ and one P5+ atom.
DOI: 10.17188/1204742
title: Materials Data on Mg5(Si8Pt5)2 by Materials Project

description: Mg5(Pt5Si8)2 crystallizes in the cubic F-43m space group. The structure is three-dimensional. there are two inequivalent Mg2+ sites. In the first Mg2+ site, Mg2+ is bonded in a 6-coordinate geometry to six Pt1- atoms. There are three shorter (2.81 Å) and three longer (2.96 Å) Mg–Pt bond lengths. In the second Mg2+ site, Mg2+ is bonded in a tetrahedral geometry to four equivalent Pt1- atoms. All Mg–Pt bond lengths are 2.79 Å. There are two inequivalent Pt1- sites. In the first Pt1- site, Pt1- is bonded in a 7-coordinate geometry to four Mg2+ and three equivalent Si atoms. All Pt–Si bond lengths are 2.40 Å. In the second Pt1- site, Pt1- is bonded in a 8-coordinate geometry to two equivalent Mg2+ and six Si atoms. There are two shorter (2.41 Å) and four longer (2.63 Å) Pt–Si bond lengths. There are two inequivalent Si sites. In the first Si site, Si is bonded in a 6-coordinate geometry to three Pt1- and three equivalent Si atoms. There are one shorter (2.38 Å) and two longer (2.50 Å) Si–Si bond lengths. In the second Si site, Si is bonded in a distorted trigonal planar geometry to three equivalent Pt1- atoms.
DOI: 10.17188/1204744
title: Materials Data on Ti5FeSb2 by Materials Project

description: Ti5FeSb2 crystallizes in the tetragonal I4/mcm space group. The structure is three-dimensional. there are two inequivalent Ti sites. In the first Ti site, Ti is bonded in a 6-coordinate geometry to two equivalent Fe and four equivalent Sb atoms. Both Ti–Fe bond lengths are 2.55 Å. There are a spread of Ti–Sb bond distances ranging from 2.81–3.11 Å. In the second Ti site, Ti is bonded in a 6-coordinate geometry to two equivalent Ti and four equivalent Sb atoms. Both Ti–Ti bond lengths are 2.57 Å. All Ti–Sb bond lengths are 2.75 Å. Fe is bonded in a 10-coordinate geometry to eight equivalent Ti and two equivalent Fe atoms. Both Fe–Fe bond lengths are 2.57 Å. Sb is bonded in a 10-coordinate geometry to ten Ti atoms.
DOI: 10.17188/1204745
title: Materials Data on Ho6FeBi2 by Materials Project

description: Ho6FeBi2 crystallizes in the hexagonal P-62m space group. The structure is three-dimensional. there are two inequivalent Ho sites. In the first Ho site, Ho is bonded in a 4-coordinate geometry to two equivalent Fe and two equivalent Bi atoms. Both Ho–Fe bond lengths are 2.82 Å. Both Ho–Bi bond lengths are 3.29 Å. In the second Ho site, Ho is bonded in a 5-coordinate geometry to one Fe and four equivalent Bi atoms. The Ho–Fe bond length is 3.23 Å. All Ho–Bi bond lengths are 3.30 Å. Fe is bonded in a 9-coordinate geometry to nine Ho atoms. Bi is bonded in a 9-coordinate geometry to nine Ho atoms.
DOI: 10.17188/1204746
title: Materials Data on RbTaO3 by Materials Project

description: RbTaO3 is Pb(Zr_(1-x)Ti_x)O3-like structured and crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. there are two inequivalent Rb1+ sites. In the first Rb1+ site, Rb1+ is bonded in a 4-coordinate geometry to eight O2- atoms. There are a spread of Rb–O bond distances ranging from 2.69–3.15 Å. In the second Rb1+ site, Rb1+ is bonded in a 4-coordinate geometry to four O2- atoms. There are two shorter (2.81 Å) and two longer (2.88 Å) Rb–O bond lengths. There are two inequivalent Ta5+ sites. In the first Ta5+ site, Ta5+ is bonded to six O2- atoms to form a mixture of edge and corner-sharing TaO6 octahedra. The corner-sharing octahedral tilt angles are 4°. There are a spread of Ta–O bond distances ranging from 1.94–2.08 Å. In the second Ta5+ site, Ta5+ is bonded to six O2- atoms to form a mixture of distorted edge and corner-sharing TaO6 octahedra. The corner-sharing octahedral tilt angles are 4°. There are a spread of Ta–O bond distances ranging from 1.83–2.35 Å. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded to one Rb1+ and three Ta5+ atoms to form distorted edge-sharing ORbTa3 trigonal pyramids. In the second O2- site, O2- is bonded in a linear geometry to two equivalent Rb1+ and two Ta5+ atoms. In the third O2- site, O2- is bonded in a distorted single-bond geometry to three Rb1+ and one Ta5+ atom. In the fourth O2- site, O2- is bonded in a 2-coordinate geometry to two Rb1+ and two Ta5+ atoms.
DOI: 10.17188/1204747
title: Materials Data on UP2O7 by Materials Project

description: UP2O7 crystallizes in the orthorhombic Pna2_1 space group. The structure is three-dimensional. there are two inequivalent U4+ sites. In the first U4+ site, U4+ is bonded in a 6-coordinate geometry to eight O2- atoms. There are a spread of U–O bond distances ranging from 2.24–2.73 Å. In the second U4+ site, U4+ is bonded in a 6-coordinate geometry to eight O2- atoms. There are a spread of U–O bond distances ranging from 2.25–2.84 Å. There are four inequivalent P5+ sites. In the first P5+ site, P5+ is bonded to four O2- atoms to form corner-sharing PO4 tetrahedra. There are a spread of P–O bond distances ranging from 1.50–1.59 Å. In the second P5+ site, P5+ is bonded to four O2- atoms to form corner-sharing PO4 tetrahedra. There are a spread of P–O bond distances ranging from 1.52–1.63 Å. In the third P5+ site, P5+ is bonded to four O2- atoms to form corner-sharing PO4 tetrahedra. There are a spread of P–O bond distances ranging from 1.51–1.61 Å. In the fourth P5+ site, P5+ is bonded in a tetrahedral geometry to four O2- atoms. There are a spread of P–O bond distances ranging from 1.53–1.57 Å. There are fourteen inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted linear geometry to one U4+ and one P5+ atom. In the second O2- site, O2- is bonded in a distorted bent 150 degrees geometry to two U4+ and one P5+ atom. In the third O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one U4+ and one P5+ atom. In the fourth O2- site, O2- is bonded in a 2-coordinate geometry to one U4+ and one P5+ atom. In the fifth O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one U4+ and one P5+ atom. In the sixth O2- site, O2- is bonded in a 1-coordinate geometry to two U4+ and one P5+ atom. In the seventh O2- site, O2- is bonded in a distorted linear geometry to one U4+ and one P5+ atom. In the eighth O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one U4+ and one P5+ atom. In the ninth O2- site, O2- is bonded in a linear geometry to one U4+ and one P5+ atom. In the tenth O2- site, O2- is bonded in a 1-coordinate geometry to two U4+ and one P5+ atom. In the eleventh O2- site, O2- is bonded in a 2-coordinate geometry to two U4+ and one P5+ atom. In the twelfth O2- site, O2- is bonded in a bent 150 degrees geometry to two P5+ atoms. In the thirteenth O2- site, O2- is bonded in a distorted linear geometry to one U4+ and one P5+ atom. In the fourteenth O2- site, O2- is bonded in a distorted bent 150 degrees geometry to two P5+ atoms.
DOI: 10.17188/1204748
title: Materials Data on BaAgBi by Materials Project

description: BaAgBi crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. Ba is bonded in a 5-coordinate geometry to six equivalent Ag and five equivalent Bi atoms. All Ba–Ag bond lengths are 3.80 Å. There are three shorter (3.37 Å) and two longer (3.52 Å) Ba–Bi bond lengths. Ag is bonded in a 8-coordinate geometry to six equivalent Ba and two equivalent Ag atoms. Both Ag–Ag bond lengths are 3.52 Å. Bi is bonded to five equivalent Ba atoms to form a mixture of edge and corner-sharing BiBa5 trigonal bipyramids.
DOI: 10.17188/1204749
title: Materials Data on Tb(NiB)2 by Materials Project

description: Tb(NiB)2 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. Tb3+ is bonded in a 6-coordinate geometry to six equivalent B3- atoms. There are a spread of Tb–B bond distances ranging from 2.71–2.88 Å. Ni+1.50+ is bonded in a 4-coordinate geometry to four equivalent B3- atoms. There are a spread of Ni–B bond distances ranging from 2.03–2.07 Å. B3- is bonded in a 8-coordinate geometry to three equivalent Tb3+, four equivalent Ni+1.50+, and one B3- atom. The B–B bond length is 1.75 Å.
DOI: 10.17188/1204750
title: Materials Data on Th2Al7 by Materials Project

description: Th2Al7 crystallizes in the orthorhombic Pbam space group. The structure is three-dimensional. Th is bonded in a 8-coordinate geometry to fourteen Al atoms. There are a spread of Th–Al bond distances ranging from 3.26–3.37 Å. There are three inequivalent Al sites. In the first Al site, Al is bonded in a 10-coordinate geometry to four equivalent Th and six Al atoms. There are a spread of Al–Al bond distances ranging from 2.64–2.91 Å. In the second Al site, Al is bonded in a distorted q6 geometry to four equivalent Th and six Al atoms. Both Al–Al bond lengths are 2.95 Å. In the third Al site, Al is bonded in a distorted q6 geometry to four equivalent Th and seven Al atoms. Both Al–Al bond lengths are 2.94 Å.
DOI: 10.17188/1204751
title: Materials Data on Al23V4 by Materials Project

description: Al23V4 crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. there are two inequivalent V sites. In the first V site, V is bonded to twelve Al atoms to form VAl12 cuboctahedra that share corners with six equivalent VAl10V2 cuboctahedra and edges with eighteen AlAl9V3 cuboctahedra. There are six shorter (2.59 Å) and six longer (2.85 Å) V–Al bond lengths. In the second V site, V is bonded to two equivalent V and ten Al atoms to form distorted VAl10V2 cuboctahedra that share corners with four VAl12 cuboctahedra, corners with four equivalent AlAl10V2 cuboctahedra, edges with four equivalent AlAl10V2 cuboctahedra, faces with two equivalent VAl10V2 cuboctahedra, and faces with eight AlAl9V3 cuboctahedra. Both V–V bond lengths are 2.64 Å. There are a spread of V–Al bond distances ranging from 2.53–2.79 Å. There are five inequivalent Al sites. In the first Al site, Al is bonded to three equivalent V and nine Al atoms to form distorted AlAl9V3 cuboctahedra that share corners with six equivalent AlAl10V2 cuboctahedra, edges with three equivalent VAl12 cuboctahedra, edges with three equivalent AlAl10V2 cuboctahedra, faces with three equivalent VAl10V2 cuboctahedra, and faces with seven AlAl9V3 cuboctahedra. There are a spread of Al–Al bond distances ranging from 2.77–2.97 Å. In the second Al site, Al is bonded to two equivalent V and ten Al atoms to form distorted AlAl10V2 cuboctahedra that share corners with two equivalent VAl10V2 cuboctahedra, corners with four AlAl9V3 cuboctahedra, an edgeedge with one AlAl9V3 cuboctahedra, edges with four VAl10V2 cuboctahedra, faces with three equivalent VAl10V2 cuboctahedra, and faces with nine AlAl9V3 cuboctahedra. There are a spread of Al–Al bond distances ranging from 2.80–2.89 Å. In the third Al site, Al is bonded in a 12-coordinate geometry to two equivalent V and ten Al atoms. There are four shorter (2.82 Å) and two longer (2.90 Å) Al–Al bond lengths. In the fourth Al site, Al is bonded in a 11-coordinate geometry to one V and ten Al atoms. There are a spread of Al–Al bond distances ranging from 2.74–2.98 Å. In the fifth Al site, Al is bonded in a 12-coordinate geometry to two V and ten Al atoms. Both Al–Al bond lengths are 2.89 Å.
DOI: 10.17188/1204752
title: Materials Data on Al4W by Materials Project

description: Al4W crystallizes in the monoclinic Cm space group. The structure is three-dimensional. there are two inequivalent W sites. In the first W site, W is bonded in a 10-coordinate geometry to ten Al atoms. There are a spread of W–Al bond distances ranging from 2.56–2.83 Å. In the second W site, W is bonded in a 11-coordinate geometry to eleven Al atoms. There are a spread of W–Al bond distances ranging from 2.55–2.85 Å. There are seven inequivalent Al sites. In the first Al site, Al is bonded in a 4-coordinate geometry to four W atoms. In the second Al site, Al is bonded in a 1-coordinate geometry to four W atoms. In the third Al site, Al is bonded in a distorted linear geometry to two W atoms. In the fourth Al site, Al is bonded in a 3-coordinate geometry to three W atoms. In the fifth Al site, Al is bonded in a 3-coordinate geometry to three W atoms. In the sixth Al site, Al is bonded in a 2-coordinate geometry to two equivalent W atoms. In the seventh Al site, Al is bonded in a 2-coordinate geometry to two equivalent W atoms.
DOI: 10.6084/m9.figshare.13621169.v9
title: Speedtest Open Data - Four International cities - MEL, BKK, SHG, LAX

description: This dataset compares four cities broadband internet speeds:- Melbourne, AU- Bangkok, TH- Shanghai, CN- Los Angeles, US<br>ERRATA:1.Data is for Q3 2020, but some files are labelled incorrectly as 02-20 of June 20. They all should read Sept 20, or 09-20 as Q3 20, rather than Q2. Will rename and reload.Amended in v7.<br>2. LAX file named 0320, when should be Q320.Amended in v8.<br><br>*lines of data for each geojson file; a line equates to a 600m^2 location, inc total tests, devices used, and average upload and download speed- MEL 16181 lines- SHG 31745 lines- BKK 29296 lines- LAX 15899 lines<br>Geojsons of these 2* by 2* extracts for MEL, BKK, SHG now added, and LAX added v6..<br>This dataset unpacks, geospatially, data summaries provided in Speedtest Global Index (linked below). See Jupyter Notebook (*.ipynb) to interrogate geo data. See link to install Jupyter.<br>** To DoWill add Google Map versions so everyone can see without installing Jupyter.- Link to Google Map (BKK) added below. Key:Green &gt; 100Mbps(Superfast). Black &gt; 500Mbps (Ultrafast). CSV provided. Code in Speedtestv1.1.ipynb Jupyter Notebook.<br>** Pythonmelb = au_tiles.cx[144:146 , -39:-37] #Lat/Lon extract<br>shg = tiles.cx[120:122 , 30:32] #Lat/Lon extract<br>bkk = tiles.cx[100:102 , 13:15] #Lat/Lon extract<br>lax = tiles.cx[-118:-120, 33:35] #lat/Lon<br>Histograms, and data visualisations will be provided.Data Sourced from - This is an extract of Speedtest Open data available at Amazon WS (link below - opendata.aws).<br>**VERSIONSv9 Add Histogram for Four Cities. Add NBN-Intl.v1.1.ipynb (Jupyter Notebook).v8 Renamed LAX file to Q3, rather than 03.v7 Amended file names of BKK files to correctly label as Q3, not Q2 or 06.v6 Added LAX file.v5 Add screenshot of BKK Google Map.v4 Add BKK Google map(link below), and BKK csv mapping files. v3 replaced MEL map with big key version. Prev key was very tiny in top right corner.v2 Uploaded MEL, SHG, BKK data and Jupyter Notebookv1 Metadata record<br>** LICENCEAWS data licence on Speedtest data is "CC BY-NC-SA 4.0", so use of this data must be:- non-commercial (NC)- reuse must be share-alike (SA)(add same licence).This restricts the standard CC-BY Figshare licence.<br>
DOI: 10.17188/1204753
title: Materials Data on Al5W by Materials Project

description: Al5W crystallizes in the hexagonal P6_322 space group. The structure is three-dimensional. there are two inequivalent W sites. In the first W site, W is bonded to twelve Al atoms to form WAl12 cuboctahedra that share corners with six equivalent WAl12 cuboctahedra, corners with twelve AlAl9W3 cuboctahedra, edges with six equivalent WAl12 cuboctahedra, and faces with eight AlAl9W3 cuboctahedra. There are six shorter (2.75 Å) and six longer (2.84 Å) W–Al bond lengths. In the second W site, W is bonded to twelve Al atoms to form WAl12 cuboctahedra that share corners with six equivalent WAl12 cuboctahedra, corners with twelve AlAl9W3 cuboctahedra, edges with six equivalent WAl12 cuboctahedra, and faces with eight AlAl9W3 cuboctahedra. There are six shorter (2.75 Å) and six longer (2.84 Å) W–Al bond lengths. There are three inequivalent Al sites. In the first Al site, Al is bonded to three equivalent W and nine Al atoms to form distorted AlAl9W3 cuboctahedra that share corners with nine WAl12 cuboctahedra, corners with nine equivalent AlAl9W3 cuboctahedra, edges with six equivalent AlAl9W3 cuboctahedra, faces with three equivalent WAl12 cuboctahedra, and faces with five AlAl9W3 cuboctahedra. There are six shorter (2.77 Å) and three longer (2.84 Å) Al–Al bond lengths. In the second Al site, Al is bonded to three equivalent W and nine Al atoms to form distorted AlAl9W3 cuboctahedra that share corners with three equivalent WAl12 cuboctahedra, corners with fifteen AlAl9W3 cuboctahedra, edges with six equivalent AlAl9W3 cuboctahedra, faces with three equivalent AlAl9W3 cuboctahedra, and faces with five WAl12 cuboctahedra. All Al–Al bond lengths are 2.75 Å. In the third Al site, Al is bonded in a distorted bent 150 degrees geometry to two W and four Al atoms.