DOI: 10.5281/zenodo.14257079
title: Interpolated data on bioavailable strontium in the southern Trans-Urals, 2020-2023, version 1.2. (current)

description: The Interpolated Strontium Values dataset Ver. 1.2 presents the interpolated data of strontium isotopes for the southern Trans-Urals, based on the data gathered in 2020-2023. The current dataset consists of five sets of files for two interpolations: based on grass, mollusks, soil, and water samples, as well as the average of three (excluding the mollusk dataset). Each of the five sets consists of a CSV file and a KML file where the interpolated values are presented to use with a GIS software (ordinary kriging, 5000 m x 5000 m grid). In addition,  GeoTIFF and JPEG files are provided for each set for a visual reference. 

Version 1.2 fixes bugs in GeoTIFF files. They can now be accessed in Google Earth (choose "Scale" if prompted that an imported image is too large). 

How to use it?

The data provided can be used to access interpolated background values of bioavailable strontium in the area of interest. Note that a single value is not a good enough predictor and should never be used as a proxy. Always calculate a mean of 4-6 (or more) nearby values to achieve the best guess possible. Never calculate averages from a single dataset, always rely on cross-validation by comparing data from all five datasets. Check the cross-validation rasters to make sure that the interpolation is reliable for the area of interest. 

 

References

The interpolated datasets are based upon the actual measured values, partially (2020-2022) published as follows:

Epimakhov, Andrey; Kisileva, Daria; Chechushkov, Igor; Ankushev, Maksim; Ankusheva, Polina (2022): Strontium isotope ratios (87Sr/86Sr) analysis from various sources the southern Trans-Urals. PANGAEA, https://doi.pangaea.de/10.1594/PANGAEA.950380

Kiseleva, D., Ankusheva, P., Maksim, A., Chechushkov, I., & Epimakhov, A. (2024). Strontium isotopes (87Sr/86Sr) data from southern Trans-Urals, 2023 [Data set]. Zenodo. https://doi.org/10.5281/zenodo.14257258

 

Description of the original dataset of measured strontium isotopic values

The present dataset contains measurements of bioavailable strontium isotopes (87Sr/86Sr) gathered in the southern Trans-Urals. There are two sample types, such as leached soil (n = 56) and water (n = 56), collected to measure bioavailable strontium isotopes. The analysis of Sr isotopic composition was carried out in the cleanrooms (6 and 7 ISO classes) of the Geoanalitik shared research facilities of the Institute of Geology and Geochemistry, the Ural Branch of the Russian Academy of Sciences (Ekaterinburg). Mollusk shell samples preliminarily cleaned with acetic acid, as well as vegetation samples rinsed with deionized water and ashed, were dissolved by open digestion in concentrated HNO 3 with the addition of H 2 O 2 on a hotplate at 150°C. Water samples were acidified with concentrated nitric acid and filtered. To obtain aqueous leachates, pre-ground soil samples weighing 1 g were taken into polypropylene containers, 10 ml of ultrapure water was added and shaken in for 1 hour, after which they were filtered through membrane cellulose acetate filters with a pore diameter of 0.2 μm. In all samples, the strontium content was determined by ICP-MS (NexION 300S). Then the sample volume corresponding to the Sr content of 600 ng was evaporated on a hotplate at 120°C, and the precipitate was dissolved in 7M HNO 3. Sample solutions were centrifuged at 6000 rpm, and strontium was chromatographically isolated using SR resin (Triskem). The strontium isotopic composition was measured on a Neptune Plus multicollector mass spectrometer with inductively coupled plasma (MC-ICP-MS). To correct mass bias, a combination of bracketing and internal normalization according to the exponential law 88 Sr/ 86 Sr = 8.375209 was used. The results were additionally bracketed using the NIST SRM 987 strontium carbonate reference material using an average deviation from the reference value of 0.710245 for every two samples bracketed between NIST SRM 987 measurements. The long-term reproducibility of the strontium isotopic analysis was evaluated using repeated measurements of NIST SRM 987 during 2020-2022 and yielded 87 Sr/ 86 Sr = 0.71025, 2SD = 0.00012 (104 measurements in two replicates). The within-laboratory standard uncertainty (2σ) obtained for SRM-987 was ± 0.003 %.