DOI: 10.17188/1284301
title: Materials Data on Zn(Bi25O38)2 by Materials Project

description: Zn(Bi25O38)2 is Antimony trioxide-derived structured and crystallizes in the triclinic P1 space group. The structure is three-dimensional. Zn is bonded in a trigonal planar geometry to three O atoms. There is two shorter (1.93 Å) and one longer (1.94 Å) Zn–O bond length. There are fifty inequivalent Bi sites. In the first Bi site, Bi is bonded in a 5-coordinate geometry to five O atoms. There are a spread of Bi–O bond distances ranging from 2.12–2.76 Å. In the second Bi site, Bi is bonded in a rectangular see-saw-like geometry to four O atoms. There are a spread of Bi–O bond distances ranging from 2.11–2.38 Å. In the third Bi site, Bi is bonded in a rectangular see-saw-like geometry to four O atoms. There are a spread of Bi–O bond distances ranging from 2.12–2.39 Å. In the fourth Bi site, Bi is bonded in a distorted rectangular see-saw-like geometry to four O atoms. There are a spread of Bi–O bond distances ranging from 2.14–2.47 Å. In the fifth Bi site, Bi is bonded to five O atoms to form a mixture of distorted edge and corner-sharing BiO5 square pyramids. There are a spread of Bi–O bond distances ranging from 2.11–2.66 Å. In the sixth Bi site, Bi is bonded in a 4-coordinate geometry to four O atoms. There are a spread of Bi–O bond distances ranging from 2.14–2.46 Å. In the seventh Bi site, Bi is bonded in a 4-coordinate geometry to four O atoms. There are a spread of Bi–O bond distances ranging from 2.13–2.43 Å. In the eighth Bi site, Bi is bonded in a rectangular see-saw-like geometry to four O atoms. There are a spread of Bi–O bond distances ranging from 2.11–2.36 Å. In the ninth Bi site, Bi is bonded in a rectangular see-saw-like geometry to four O atoms. There are a spread of Bi–O bond distances ranging from 2.10–2.40 Å. In the tenth Bi site, Bi is bonded to five O atoms to form a mixture of distorted edge and corner-sharing BiO5 square pyramids. There are a spread of Bi–O bond distances ranging from 2.12–2.76 Å. In the eleventh Bi site, Bi is bonded in a 5-coordinate geometry to five O atoms. There are a spread of Bi–O bond distances ranging from 2.10–2.78 Å. In the twelfth Bi site, Bi is bonded in a 5-coordinate geometry to five O atoms. There are a spread of Bi–O bond distances ranging from 2.14–2.76 Å. In the thirteenth Bi site, Bi is bonded to five O atoms to form a mixture of distorted edge and corner-sharing BiO5 square pyramids. There are a spread of Bi–O bond distances ranging from 2.10–2.68 Å. In the fourteenth Bi site, Bi is bonded in a rectangular see-saw-like geometry to four O atoms. There are a spread of Bi–O bond distances ranging from 2.10–2.39 Å. In the fifteenth Bi site, Bi is bonded in a 4-coordinate geometry to four O atoms. There are a spread of Bi–O bond distances ranging from 2.12–2.50 Å. In the sixteenth Bi site, Bi is bonded in a 4-coordinate geometry to five O atoms. There are a spread of Bi–O bond distances ranging from 2.13–2.77 Å. In the seventeenth Bi site, Bi is bonded to five O atoms to form a mixture of distorted edge and corner-sharing BiO5 square pyramids. There are a spread of Bi–O bond distances ranging from 2.11–2.72 Å. In the eighteenth Bi site, Bi is bonded in a distorted rectangular see-saw-like geometry to four O atoms. There are a spread of Bi–O bond distances ranging from 2.11–2.44 Å. In the nineteenth Bi site, Bi is bonded to five O atoms to form distorted corner-sharing BiO5 square pyramids. There are a spread of Bi–O bond distances ranging from 2.11–2.70 Å. In the twentieth Bi site, Bi is bonded to five O atoms to form a mixture of distorted edge and corner-sharing BiO5 square pyramids. There are a spread of Bi–O bond distances ranging from 2.12–2.66 Å. In the twenty-first Bi site, Bi is bonded in a distorted rectangular see-saw-like geometry to four O atoms. There are a spread of Bi–O bond distances ranging from 2.09–2.45 Å. In the twenty-second Bi site, Bi is bonded to five O atoms to form distorted corner-sharing BiO5 square pyramids. There are a spread of Bi–O bond distances ranging from 2.12–2.79 Å. In the twenty-third Bi site, Bi is bonded in a 5-coordinate geometry to five O atoms. There are a spread of Bi–O bond distances ranging from 2.13–2.74 Å. In the twenty-fourth Bi site, Bi is bonded to five O atoms to form distorted corner-sharing BiO5 square pyramids. There are a spread of Bi–O bond distances ranging from 2.12–2.63 Å. In the twenty-fifth Bi site, Bi is bonded to five O atoms to form a mixture of distorted edge and corner-sharing BiO5 square pyramids. There are a spread of Bi–O bond distances ranging from 2.13–2.67 Å. In the twenty-sixth Bi site, Bi is bonded in a rectangular see-saw-like geometry to four O atoms. There are a spread of Bi–O bond distances ranging from 2.11–2.41 Å. In the twenty-seventh Bi site, Bi is bonded to five O atoms to form distorted corner-sharing BiO5 square pyramids. There are a spread of Bi–O bond distances ranging from 2.13–2.66 Å. In the twenty-eighth Bi site, Bi is bonded in a 4-coordinate geometry to four O atoms. There are a spread of Bi–O bond distances ranging from 2.15–2.61 Å. In the twenty-ninth Bi site, Bi is bonded to five O atoms to form distorted corner-sharing BiO5 square pyramids. There are a spread of Bi–O bond distances ranging from 2.12–2.68 Å. In the thirtieth Bi site, Bi is bonded in a rectangular see-saw-like geometry to four O atoms. There are a spread of Bi–O bond distances ranging from 2.10–2.40 Å. In the thirty-first Bi site, Bi is bonded in a 5-coordinate geometry to five O atoms. There are a spread of Bi–O bond distances ranging from 2.13–2.78 Å. In the thirty-second Bi site, Bi is bonded in a distorted rectangular see-saw-like geometry to four O atoms. There are a spread of Bi–O bond distances ranging from 2.10–2.44 Å. In the thirty-third Bi site, Bi is bonded in a rectangular see-saw-like geometry to four O atoms. There are a spread of Bi–O bond distances ranging from 2.12–2.39 Å. In the thirty-fourth Bi site, Bi is bonded in a distorted trigonal non-coplanar geometry to three O atoms. There are a spread of Bi–O bond distances ranging from 2.11–2.15 Å. In the thirty-fifth Bi site, Bi is bonded to five O atoms to form a mixture of distorted edge and corner-sharing BiO5 square pyramids. There are a spread of Bi–O bond distances ranging from 2.11–2.65 Å. In the thirty-sixth Bi site, Bi is bonded to five O atoms to form distorted corner-sharing BiO5 square pyramids. There are a spread of Bi–O bond distances ranging from 2.14–2.74 Å. In the thirty-seventh Bi site, Bi is bonded in a 5-coordinate geometry to five O atoms. There are a spread of Bi–O bond distances ranging from 2.10–2.76 Å. In the thirty-eighth Bi site, Bi is bonded in a rectangular see-saw-like geometry to four O atoms. There are a spread of Bi–O bond distances ranging from 2.13–2.43 Å. In the thirty-ninth Bi site, Bi is bonded in a 5-coordinate geometry to five O atoms. There are a spread of Bi–O bond distances ranging from 2.14–2.80 Å. In the fortieth Bi site, Bi is bonded to five O atoms to form distorted corner-sharing BiO5 square pyramids. There are a spread of Bi–O bond distances ranging from 2.12–2.64 Å. In the forty-first Bi site, Bi is bonded to five O atoms to form distorted corner-sharing BiO5 square pyramids. There are a spread of Bi–O bond distances ranging from 2.13–2.65 Å. In the forty-second Bi site, Bi is bonded to five O atoms to form a mixture of distorted edge and corner-sharing BiO5 square pyramids. There are a spread of Bi–O bond distances ranging from 2.13–2.53 Å. In the forty-third Bi site, Bi is bonded in a distorted rectangular see-saw-like geometry to four O atoms. There are a spread of Bi–O bond distances ranging from 2.13–2.49 Å. In the forty-fourth Bi site, Bi is bonded to five O atoms to form a mixture of distorted edge and corner-sharing BiO5 square pyramids. There are a spread of Bi–O bond distances ranging from 2.11–2.78 Å. In the forty-fifth Bi site, Bi is bonded in a 5-coordinate geometry to five O atoms. There are a spread of Bi–O bond distances ranging from 2.12–2.79 Å. In the forty-sixth Bi site, Bi is bonded in a distorted rectangular see-saw-like geometry to four O atoms. There are a spread of Bi–O bond distances ranging from 2.09–2.43 Å. In the forty-seventh Bi site, Bi is bonded in a 5-coordinate geometry to five O atoms. There are a spread of Bi–O bond distances ranging from 2.12–2.75 Å. In the forty-eighth Bi site, Bi is bonded to five O atoms to form a mixture of distorted edge and corner-sharing BiO5 square pyramids. There are a spread of Bi–O bond distances ranging from 2.10–2.67 Å. In the forty-ninth Bi site, Bi is bonded in a distorted rectangular see-saw-like geometry to four O atoms. There are a spread of Bi–O bond distances ranging from 2.10–2.42 Å. In the fiftieth Bi site, Bi is bonded in a distorted trigonal non-coplanar geometry to three O atoms. There are a spread of Bi–O bond distances ranging from 2.11–2.15 Å. There are seventy-six inequivalent O sites. In the first O site, O is bonded in a trigonal planar geometry to three Bi atoms. In the second O site, O is bonded in a trigonal non-coplanar geometry to three Bi atoms. In the third O site, O is bonded in a trigonal non-coplanar geometry to three Bi atoms. In the fourth O site, O is bonded in a distorted bent 120 degrees geometry to two Bi atoms. In the fifth O site, O is bonded in a distorted bent 120 degrees geometry to three Bi atoms. In the sixth O site, O is bonded in a distorted trigonal non-coplanar geometry to three Bi atoms. In the seventh O site, O is bonded in a trigonal non-coplanar geometry to three Bi atoms. In the eighth O site, O is bonded in a trigonal non-coplanar geometry to three Bi atoms. In the ninth O site, O is bonded in a distorted bent 120 degrees geometry to two Bi atoms. In the tenth O site, O is bonded in a trigonal planar geometry to three Bi atoms. In the eleventh O site, O is bonded in a trigonal planar geometry to three Bi atoms. In the twelfth O site, O is bonded in a trigonal planar geometry to three Bi atoms. In the thirteenth O site, O is bonded to one Zn and three Bi atoms to form distorted corner-sharing OZnBi3 tetrahedra. In the fourteenth O site, O is bonded in a bent 120 degrees geometry to two Bi atoms. In the fifteenth O site, O is bonded in a trigonal non-coplanar geometry to three Bi atoms. In the sixteenth O site, O is bonded to four Bi atoms to form distorted corner-sharing OBi4 tetrahedra. In the seventeenth O site, O is bonded to four Bi atoms to form corner-sharing OBi4 tetrahedra. In the eighteenth O site, O is bonded in a bent 120 degrees geometry to two Bi atoms. In the nineteenth O site, O is bonded in a distorted trigonal non-coplanar geometry to three Bi atoms. In the twentieth O site, O is bonded in a trigonal non-coplanar geometry to three Bi atoms. In the twenty-first O site, O is bonded in a distorted trigonal non-coplanar geometry to three Bi atoms. In the twenty-second O site, O is bonded in a trigonal non-coplanar geometry to three Bi atoms. In the twenty-third O site, O is bonded in a distorted trigonal non-coplanar geometry to three Bi atoms. In the twenty-fourth O site, O is bonded in a distorted trigonal non-coplanar geometry to three Bi atoms. In the twenty-fifth O site, O is bonded in a distorted bent 120 degrees geometry to three Bi atoms. In the twenty-sixth O site, O is bonded in a trigonal planar geometry to three Bi atoms. In the twenty-seventh O site, O is bonded in a trigonal planar geometry to three Bi atoms. In the twenty-eighth O site, O is bonded in a trigonal planar geometry to three Bi atoms. In the twenty-ninth O site, O is bonded to four Bi atoms to form distorted corner-sharing OBi4 tetrahedra. In the thirtieth O site, O is bonded in a distorted trigonal non-coplanar geometry to three Bi atoms. In the thirty-first O site, O is bonded in a distorted trigonal non-coplanar geometry to three Bi atoms. In the thirty-second O site, O is bonded in a trigonal non-coplanar geometry to three Bi atoms. I