cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.14272/yaopdsfqaapoep-nryaxdjksa-n/chmo0000595
title: 13C nuclear magnetic resonance spectroscopy (13C NMR) ()
title: InChI=1S/C24H23BrO4Si/c1-30(2,3)29-20-14-8-12-18-21(26)15-9-4-5-10-16(15)22(27)24(18,20)23(28)17-11-6-7-13-19(17)25/h4-11,13-14,18,20H,12H2,1-3H3/t18-,20+,24-/m0/s1

description: dataset for 13C nuclear magnetic resonance spectroscopy (13C NMR) 13C NMR (101 MHz, CDCl3, ppm) δ = 196.9 (Cq, 1 × C=O), 196.1 (Cq, 1 × C=O), 193.6 (Cq, 1 × C=O), 138.5 (Cq, 1 × CqAr), 135.6 (+, 1 × CHAr), 135.2 (+, 1 × CHAr), 134.8 (Cq, 1 × CqAr), 134.4 (+, 1 × CHAr), 134.2 (Cq, 1 × CqAr), 132.5 (+, 1 × CHAr), 128.8 (+, 1 × C=CH), 128.0 (+, 1 × CHAr), 127.7 (+, 1 × CHAr), 127.5 (+, 1 × CHAr), 127.4 (+, 1 × C=CH), 127.1 (+, 1 × CHAr), 122.1 (Cq, 1 × CqAr), 74.2 (Cq, 1 × Cq), 66.3 (+, 1 × CH), 46.6 (+, 1 × CH), 28.4 (–, 1 × CH2), 0.9 (+, 3 × SiCH3).
DOI: 10.14272/yaopdsfqaapoep-wxvukljwsa-n.1
title: C24H23BrO4Si
title: InChI=1S/C24H23BrO4Si/c1-30(2,3)29-20-14-8-12-18-21(26)15-9-4-5-10-16(15)22(27)24(18,20)23(28)17-11-6-7-13-19(17)25/h4-11,13-14,18,20H,12H2,1-3H3/t18-,20-,24-/m0/s1

description: This dataset contains experimental data from a sample (InChI=1S/C24H23BrO4Si/c1-30(2,3)29-20-14-8-12-18-21(26)15-9-4-5-10-16(15)22(27)24(18,20)23(28)17-11-6-7-13-19(17)25/h4-11,13-14,18,20H,12H2,1-3H3/t18-,20-,24-/m0/s1). The datasets from the following experiments are available: 1H nuclear magnetic resonance spectroscopy (1H NMR) 13C nuclear magnetic resonance spectroscopy (13C NMR) fast-atom bombardment mass spectrometry (FABMS) infrared absorption spectroscopy (IR)
DOI: 10.14272/yreqdoizjyonfu-uhfffaoysa-n.1
title: C19H9BrF3NO4
title: InChI=1S/C19H9BrF3NO4/c20-14-6-5-9(24-18(28)19(21,22)23)7-12(14)17(27)13-8-15(25)10-3-1-2-4-11(10)16(13)26/h1-8H,(H,24,28)

description: This dataset contains experimental data from a sample (InChI=1S/C19H9BrF3NO4/c20-14-6-5-9(24-18(28)19(21,22)23)7-12(14)17(27)13-8-15(25)10-3-1-2-4-11(10)16(13)26/h1-8H,(H,24,28)). The datasets from the following experiments are available: atmospheric pressure chemical ionisation mass spectrometry (APCI MS) 1H nuclear magnetic resonance spectroscopy (1H NMR) infrared absorption spectroscopy (IR) 19F nuclear magnetic resonance spectroscopy (19F NMR)
DOI: 10.14272/yreqdoizjyonfu-uhfffaoysa-n/chmo0000473
title: atmospheric pressure chemical ionisation mass spectrometry (APCI MS) ()
title: InChI=1S/C19H9BrF3NO4/c20-14-6-5-9(24-18(28)19(21,22)23)7-12(14)17(27)13-8-15(25)10-3-1-2-4-11(10)16(13)26/h1-8H,(H,24,28)

description: dataset for atmospheric pressure chemical ionisation mass spectrometry (APCI MS) APCI (m/z): 452/454 (97/100) [M+H]+; – HRMS-APCI (m/z): [M+H]+ calcd for C19H10BrF3NO4, 451.9745; found, 451.9729.
DOI: 10.14272/yreqdoizjyonfu-uhfffaoysa-n/chmo0000630
title: infrared absorption spectroscopy (IR) ()
title: InChI=1S/C19H9BrF3NO4/c20-14-6-5-9(24-18(28)19(21,22)23)7-12(14)17(27)13-8-15(25)10-3-1-2-4-11(10)16(13)26/h1-8H,(H,24,28)

description: dataset for infrared absorption spectroscopy (IR) IR (ATR): ṽ = 3350 (vw), 1727 (w), 1654 (w), 1583 (w), 1542 (w), 1469 (w), 1406 (w), 1349 (vw), 1299 (w), 1136 (m), 1047 (w), 881 (w), 830 (w), 777 (w), 760 (w), 724 (w), 670 (w), 632 (w), 580 (w), 495 (w), 458 (vw) cm-1.
DOI: 10.15468/zzyqx6
title: Morphological characterization of Trichotylenchus gorganiensis n. sp. (Nematoda: Dolichodoridae) and photomicrographs of several other species of the subfamily Telotylenchinae Siddiqi, 1960

description: This dataset contains the digitized treatments in Plazi based on the original journal article Ghaderi, Reza, Karegar, Akbar, Miraeiz, Esmaeil (2018): Morphological characterization of Trichotylenchus gorganiensis n. sp. (Nematoda: Dolichodoridae) and photomicrographs of several other species of the subfamily Telotylenchinae Siddiqi, 1960. Zootaxa 4526 (4): 447-480, DOI: https://doi.org/10.11646/zootaxa.4526.4.3
DOI: 10.5281/zenodo.3814731
title: Preliminary results from the EntoGEM project May 06, 2020

description: This release of https://github.com/entogem/preliminary_results contains comparisons of the 10+-year studies identified by EntoGEM as of May 06, 2020 to the references included in 53 previous articles, commentaries, meta-analyses, and other syntheses mentioning "insect decline" in 2019 and 2020. It is <strong>not</strong> a definitive guide to studies that have been neglected by current debate surrounding insect decline, and is simply a checkpoint to verify that the community-driven approach to synthesis is helping identify studies that were previously not part of the conversation.
DOI: 10.5281/zenodo.3814732
title: Preliminary results from the EntoGEM project May 06, 2020

description: This release of https://github.com/entogem/preliminary_results contains comparisons of the 10+-year studies identified by EntoGEM as of May 06, 2020 to the references included in 53 previous articles, commentaries, meta-analyses, and other syntheses mentioning "insect decline" in 2019 and 2020. It is <strong>not</strong> a definitive guide to studies that have been neglected by current debate surrounding insect decline, and is simply a checkpoint to verify that the community-driven approach to synthesis is helping identify studies that were previously not part of the conversation.
DOI: 10.14272/wpgxnufgnkcccz-owauwmpxsa-n/chmo0000563
title: fast-atom bombardment mass spectrometry (FABMS) ()
title: InChI=1S/C25H25IO4Si/c1-15-13-14-19-21(27)16-9-5-6-10-17(16)22(28)25(19,24(15)30-31(2,3)4)23(29)18-11-7-8-12-20(18)26/h5-13,19,24H,14H2,1-4H3/t19-,24+,25-/m0/s1

description: dataset for fast-atom bombardment mass spectrometry (FABMS) FAB (m/z, 3-NBA): 472 (3) [M–TMS]+, 309 (25), 251 (26), 197 (43), 135 (100). HRMS-FAB (m/z): [M]+ calcd for C25H26O4127ISi, 545.0645; found, 545.0647
DOI: 10.14272/wpgxnufgnkcccz-owauwmpxsa-n/chmo0000630
title: infrared absorption spectroscopy (IR) ()
title: InChI=1S/C25H25IO4Si/c1-15-13-14-19-21(27)16-9-5-6-10-17(16)22(28)25(19,24(15)30-31(2,3)4)23(29)18-11-7-8-12-20(18)26/h5-13,19,24H,14H2,1-4H3/t19-,24+,25-/m0/s1

description: dataset for infrared absorption spectroscopy (IR) IR (ATR, ṽ): 2957 (w), 2857 (w), 1693 (m), 1586 (m), 1427 (w), 1299 (m), 1246 (m), 1220 (m), 1145 (w), 1112 (w), 1056 (s), 1006 (m), 955 (m), 928 (w), 895 (m), 839 (s), 771 (m), 744 (m), 699 (s), 639 (w), 602 (m), 570 (m), 503 (m), 395 (w) cm–1.
DOI: 10.14272/yaopdsfqaapoep-nryaxdjksa-n.1
title: C24H23BrO4Si
title: InChI=1S/C24H23BrO4Si/c1-30(2,3)29-20-14-8-12-18-21(26)15-9-4-5-10-16(15)22(27)24(18,20)23(28)17-11-6-7-13-19(17)25/h4-11,13-14,18,20H,12H2,1-3H3/t18-,20+,24-/m0/s1

description: This dataset contains experimental data from a sample (InChI=1S/C24H23BrO4Si/c1-30(2,3)29-20-14-8-12-18-21(26)15-9-4-5-10-16(15)22(27)24(18,20)23(28)17-11-6-7-13-19(17)25/h4-11,13-14,18,20H,12H2,1-3H3/t18-,20+,24-/m0/s1). The datasets from the following experiments are available: 1H nuclear magnetic resonance spectroscopy (1H NMR) 13C nuclear magnetic resonance spectroscopy (13C NMR) fast-atom bombardment mass spectrometry (FABMS) infrared absorption spectroscopy (IR)
DOI: 10.14272/yaopdsfqaapoep-nryaxdjksa-n/chmo0000630
title: infrared absorption spectroscopy (IR) ()
title: InChI=1S/C24H23BrO4Si/c1-30(2,3)29-20-14-8-12-18-21(26)15-9-4-5-10-16(15)22(27)24(18,20)23(28)17-11-6-7-13-19(17)25/h4-11,13-14,18,20H,12H2,1-3H3/t18-,20+,24-/m0/s1

description: dataset for infrared absorption spectroscopy (IR) IR (ATR, ṽ): 2922 (vw), 1698 (w), 1678 (w), 1593 (w), 1467 (vw), 1430 (vw), 1249 (w), 1230 (w), 1072 (w), 1052 (w), 1024 (w), 996 (vw), 945 (w), 890 (w), 841 (w), 763 (w), 683 (w), 641 (vw), 593 (vw), 515 (vw), 394 (vw) cm–1.
DOI: 10.14272/yaopdsfqaapoep-wxvukljwsa-n/chmo0000563
title: fast-atom bombardment mass spectrometry (FABMS) ()
title: InChI=1S/C24H23BrO4Si/c1-30(2,3)29-20-14-8-12-18-21(26)15-9-4-5-10-16(15)22(27)24(18,20)23(28)17-11-6-7-13-19(17)25/h4-11,13-14,18,20H,12H2,1-3H3/t18-,20-,24-/m0/s1

description: dataset for fast-atom bombardment mass spectrometry (FABMS) FAB (m/z, 3-NBA): 483 (42) [M+H]+, 183 (100) [M-C17H19O3Si]+, 393 (13) [M-OTMS]+.HRMS-FAB (m/z): [M]+ calcd for C24H2479BrO4Si, 483.0627; found, 483.0629.
DOI: 10.14272/yaopdsfqaapoep-wxvukljwsa-n/chmo0000593
title: 1H nuclear magnetic resonance spectroscopy (1H NMR) ()
title: InChI=1S/C24H23BrO4Si/c1-30(2,3)29-20-14-8-12-18-21(26)15-9-4-5-10-16(15)22(27)24(18,20)23(28)17-11-6-7-13-19(17)25/h4-11,13-14,18,20H,12H2,1-3H3/t18-,20-,24-/m0/s1

description: dataset for 1H nuclear magnetic resonance spectroscopy (1H NMR) 1H NMR (400 MHz, CDCl3, ppm) δ = 8.17–8.12 (m, 1H, CHAr), 8.06–8.00 (m, 1H, CHAr), 7.81–7.69 (m, 3H, CHAr), 7.62 (dd, 3J = 7.8 Hz, 4J = 1.3 Hz, 1H, CHAr), 7.45–7.18 (m, 2H, CHAr), 5.90 (ddd, 3J = 10.1, 4.5 Hz, 4J = 2.8 Hz, 1H, C=CH), 5.67 (ddt, 3J = 10.0, 5.0 Hz, 4J = 2.3 Hz, 1H, C=CH), 4.94 (d, 3J = 5.2 Hz, 1H, C=CH-CH), 3.89 (d, 3J = 7.1 Hz, 1H, CH2‑CH), 3.22–3.16 (m, 1H, CHH), 2.30–2.06 (m, 1H, CHH), –0.35 (s, 9H, Si(CH3)3).Impurities: spectrum contains ethyl acetate signals at 2.05 and 1.26 ppm.
DOI: 10.14272/yaopdsfqaapoep-wxvukljwsa-n/chmo0000595
title: 13C nuclear magnetic resonance spectroscopy (13C NMR) ()
title: InChI=1S/C24H23BrO4Si/c1-30(2,3)29-20-14-8-12-18-21(26)15-9-4-5-10-16(15)22(27)24(18,20)23(28)17-11-6-7-13-19(17)25/h4-11,13-14,18,20H,12H2,1-3H3/t18-,20-,24-/m0/s1

description: dataset for 13C nuclear magnetic resonance spectroscopy (13C NMR) 13C NMR (101 MHz, CDCl3, ppm) δ = 197.9 (Cq, 1 × C=O), 196.6 (Cq, 1 × C=O), 194.8 (Cq, 1 × C=O), 138.6 (Cq, 1 × CqAr), 137.6 (Cq, 1 × CqAr), 135.1 (Cq, 1 × CqAr), 134.8 (+, 1 × CHAr), 134.4 (+, 1 × CHAr), 133.3 (+, 1 × CHAr), 131.7 (+, 1 × CHAr), 130.1 (+, 1 × C=CH), 128.3 (+, 1 × CHAr), 126.9 (+, 1 × CHAr), 126.8 (+, 1 × CHAr), 126.5 (+, 1 × C=CH), 125.8 (+, 1 × CHAr), 121.2 (Cq, 1 × CqAr), 70.2 (Cq, 1 × Cq), 68.2 (+, 1 × CH), 45.9 (+, 1 × CH), 21.1 (–, 1 × CH2), –0.6 (+, 3 × SiCH3).
DOI: 10.14272/yaopdsfqaapoep-wxvukljwsa-n/chmo0000630
title: infrared absorption spectroscopy (IR) ()
title: InChI=1S/C24H23BrO4Si/c1-30(2,3)29-20-14-8-12-18-21(26)15-9-4-5-10-16(15)22(27)24(18,20)23(28)17-11-6-7-13-19(17)25/h4-11,13-14,18,20H,12H2,1-3H3/t18-,20-,24-/m0/s1

description: dataset for infrared absorption spectroscopy (IR) IR (ATR, ṽ): 3066 (vw), 3033 (vw), 2955 (vw), 2898 (vw), 1701 (m), 1672 (w), 1593 (w), 1425 (w), 1324 (vw), 1249 (m), 1160 (vw), 1076 (w), 1056 (w), 1021 (w), 935 (w), 885 (w), 839 (m), 751 (w), 737 (w), 688 (w), 641 (w), 596 (vw), 542 (vw), 483 (vw), 456 (vw), 437 (vw) cm–1.
DOI: 10.5281/zenodo.3813485
title: Dataset related to the article "Cardiac surgeon and electrophysiologist shoulder-to-shoulder approach: Hybrid room, a kingdom for two. A zero mortality transvenous lead extraction single center experience"

description: This record contains raw data related to the article "Cardiac surgeon and electrophysiologist shoulder-to-shoulder approach: Hybrid room, a kingdom for two. A zero mortality transvenous lead extraction single center experience" ABSTRACT BACKGROUND: Nowadays, transvenous lead extraction (TLE) is considered an essential technique in lead management strategy. Since 2011, a multidisciplinary approach was undertaken in our centre involving electrophysiologists, cardiac surgeons and anaesthesiologists to improve cross- unit cooperation and minimize complications and mortality. The present paper reports procedural outcomes and complications of our lead extraction experience. METHODS: We retrospectively collected and analysed data from all consecutive patients undergoing cardiac implantable electronic device leads TLE at the IRCCS Centro Cardiologico Monzino between January 2011 and November 2017. RESULTS: One-hundred fifty patients (111 males, 68 ± 13 years) underwent extraction procedures. The most common extraction indication were infections (86.7%) and TLE was carried out by laser-based approach in 88 (58.6%) patients, by mechanical dilating sheaths in 58 (38.7%) patients and by a combined approach (TLE + open surgical intervention) in 4 (2.7%) patients. Procedural success was obtained in 146 (97.3%) cases with only 3 (2.0%) major complications with 2 cases of structural injury with tamponade requiring emergent median sternotomy. Open surgery extraction was required in 4 patients, after an attempt to TLE, due to leads strict adhesion to cardiac or vascular structures, whereas in 5 (3.3%) cases, the treatment of choice was a combined approach consisting in transvenous leads extraction followed by planned surgery. CONCLUSIONS: TLE is a complex procedure that sometimes leads to fatal complications. In our single center experience, a multidisciplinary approach involving electrophysiologist, cardiac surgeon, anaesthesiologist in an operating room allows a safer approach and major complications treatment.
DOI: 10.5281/zenodo.3813486
title: Dataset related to the article "Cardiac surgeon and electrophysiologist shoulder-to-shoulder approach: Hybrid room, a kingdom for two. A zero mortality transvenous lead extraction single center experience"

description: This record contains raw data related to the article "Cardiac surgeon and electrophysiologist shoulder-to-shoulder approach: Hybrid room, a kingdom for two. A zero mortality transvenous lead extraction single center experience" ABSTRACT BACKGROUND: Nowadays, transvenous lead extraction (TLE) is considered an essential technique in lead management strategy. Since 2011, a multidisciplinary approach was undertaken in our centre involving electrophysiologists, cardiac surgeons and anaesthesiologists to improve cross- unit cooperation and minimize complications and mortality. The present paper reports procedural outcomes and complications of our lead extraction experience. METHODS: We retrospectively collected and analysed data from all consecutive patients undergoing cardiac implantable electronic device leads TLE at the IRCCS Centro Cardiologico Monzino between January 2011 and November 2017. RESULTS: One-hundred fifty patients (111 males, 68 ± 13 years) underwent extraction procedures. The most common extraction indication were infections (86.7%) and TLE was carried out by laser-based approach in 88 (58.6%) patients, by mechanical dilating sheaths in 58 (38.7%) patients and by a combined approach (TLE + open surgical intervention) in 4 (2.7%) patients. Procedural success was obtained in 146 (97.3%) cases with only 3 (2.0%) major complications with 2 cases of structural injury with tamponade requiring emergent median sternotomy. Open surgery extraction was required in 4 patients, after an attempt to TLE, due to leads strict adhesion to cardiac or vascular structures, whereas in 5 (3.3%) cases, the treatment of choice was a combined approach consisting in transvenous leads extraction followed by planned surgery. CONCLUSIONS: TLE is a complex procedure that sometimes leads to fatal complications. In our single center experience, a multidisciplinary approach involving electrophysiologist, cardiac surgeon, anaesthesiologist in an operating room allows a safer approach and major complications treatment.
DOI: 10.1285/i20705948v13n1p256
title: The security mortgage valuation in a stochastic perspective

description: The reverse mortgage market has been expanding rapidly in developed economies in recent years. Reverse mortgages provide an alternative source of funding for retirement income and health care costs. Increase in life expectancies and decrease in the real income at retirement continue to worry the those who are retired or close to retirement. Therefore, financial products that help to alleviate the “risk of living longer” continue to be attractive among the retirees. Reverse mortgage contracts involve a range of risks from the insurer's perspective. When the outstanding balance exceeds the housing value before the loan is settled, the insurer suffers an exposure to crossover risk induced by three risk factors: interest rates, house prices and mortality rates. We analyse the combined impact of these risks on the pricing and the risk profile of reverse mortgage loans in a stochastic interest-mortality-house pricing model. Our results show shows that pricing of reverse mortgages loans does not accurately assess the risks underwritten by reverse mortgages lenders and that failing to take into account mortality improvements substantially underestimates the longevity risk involved in reverse mortgage loans.
DOI: 10.14272/htuxsvmuhumuto-htapyjjxsa-n/chmo0000595
title: 13C nuclear magnetic resonance spectroscopy (13C NMR) ()
title: InChI=1S/C22H17IO3/c1-13-10-11-22(21(26)16-8-4-5-9-18(16)23)17(12-13)19(24)14-6-2-3-7-15(14)20(22)25/h2-10,17H,11-12H2,1H3/t17-,22+/m0/s1

description: dataset for 13C nuclear magnetic resonance spectroscopy (13C NMR) 13C NMR (101 MHz, CDCl3, ppm) δ = 200.8 (Cq, 1 × C=O), 196.1 (Cq, 1 × C=O), 194.5 (Cq, 1 × C=O), 142.5 (Cq, 1 × CqAr), 140.9 (+, 1 × CHAr), 135.2 (+, 1 × CHAr), 134.3 (+, 1 × CHAr), 133.0 (Cq, 1 × CqAr), 132.0 (Cq, 1 × CqAr), 131.6 (+, 1 × CHAr), 127.5 (+, 1 × CHAr), 127.4 (+, 1 × CHAr), 127.1 (+, 1 × CHAr), 126.9 (+, 1 × CHAr), 117.9 (+, 1 × C=CH), 93.2 (Cq, 1 × CqAr), 67.6 (Cq, 1 × Cq), 50.3 (+, 1 × CH), 30.4 (–, 1 × CH2), 28.9 (–, 1 × CH2), 23.2 (+, 1 × CH3). Signal missing (Cq, 1 × Cq).
DOI: 10.14272/wpgxnufgnkcccz-lqglaiqgsa-n/chmo0000563
title: fast-atom bombardment mass spectrometry (FABMS) ()
title: InChI=1S/C25H25IO4Si/c1-15-13-14-19-21(27)16-9-5-6-10-17(16)22(28)25(19,24(15)30-31(2,3)4)23(29)18-11-7-8-12-20(18)26/h5-13,19,24H,14H2,1-4H3/t19-,24-,25-/m0/s1

description: dataset for fast-atom bombardment mass spectrometry (FABMS) FAB (m/z, 3-NBA): 545 (34) [M+H]+, 455 (100) [M–OTMS]+.HRMS-FAB (m/z): [M]+ calcd for C25H26127IO4Si, 545.0645; found, 545.0643.
DOI: 10.14272/wpgxnufgnkcccz-lqglaiqgsa-n/chmo0000593
title: 1H nuclear magnetic resonance spectroscopy (1H NMR) ()
title: InChI=1S/C25H25IO4Si/c1-15-13-14-19-21(27)16-9-5-6-10-17(16)22(28)25(19,24(15)30-31(2,3)4)23(29)18-11-7-8-12-20(18)26/h5-13,19,24H,14H2,1-4H3/t19-,24-,25-/m0/s1

description: dataset for 1H nuclear magnetic resonance spectroscopy (1H NMR) 1H NMR (400 MHz, CDCl3, ppm) δ = 8.16–8.14 (m, 1H, CHAr), 8.07–8.05 (m, 2H, CHAr), 7.96 (dd, 3J = 7.9 Hz, 4J = 1.1 Hz, 1H, CHAr), 7.70–7.80 (m, 2H, CHAr), 7.41 (td, 3J = 7.6 Hz, 4J = 1.2 Hz, 1H, CHAr), 7.08 (td, 3J = 7.6 Hz, 4J = 1.6 Hz, 1H, CHAr), 5.63–5.62 (m, 1H, C=CH), 4.68 (s, 1H, CH), 3.95 (d, 3J = 7.8 Hz, 1H, COCH), 3.32–3.28 (m, 1H, CHH), 3.28–3.24 (m, 1H, CHH), 1.29 (d, 4J = 1.9 Hz, 3H, CH3), –0.38 (s, 9H, Si(CH3)3). Impurities: spectrum contains unknown impurities at 0.15 and 0.07 ppm.
DOI: 10.14272/wpgxnufgnkcccz-lqglaiqgsa-n/chmo0000595
title: 13C nuclear magnetic resonance spectroscopy (13C NMR) ()
title: InChI=1S/C25H25IO4Si/c1-15-13-14-19-21(27)16-9-5-6-10-17(16)22(28)25(19,24(15)30-31(2,3)4)23(29)18-11-7-8-12-20(18)26/h5-13,19,24H,14H2,1-4H3/t19-,24-,25-/m0/s1

description: dataset for 13C nuclear magnetic resonance spectroscopy (13C NMR) 13C NMR (101 MHz, CDCl3, ppm) δ = 198.4 (Cq, 1 × C=O), 197.4 (Cq, 1 × C=O), 194.9 (Cq, 1 × C=O), 141.5 (+, 1 × CHAr), 141.4 (Cq, 1 × CqAr), 137.3 (Cq, 1 × CqAr), 134.5 (Cq, 1 × CqAr), 134.4 (+, 1 × CHAr), 133.0 (+, 1 × CHAr), 132.8 (Cq, 1 × Cq), 131.0 (+, 1 × CHAr), 127.9 (+, 1 × CHAr), 126.9 (+, 1 × CHAr), 126.8 (+, 1 × CHAr), 126.2 (+, 1 × CHAr), 125.8 (+, 1 × C=CH), 95.1 (Cq, 1 × CqAr), 72.6 (+, 1 × CH), 71.5 (Cq, 1 × Cq), 45.0 (+, 1 × CO-CH), 21.6 (+, 1 × CH3), 20.7 (–, 1 × CH2), –0.7 (+, 3 × SiCH3).
DOI: 10.14272/wpgxnufgnkcccz-lqglaiqgsa-n/chmo0000630
title: infrared absorption spectroscopy (IR) ()
title: InChI=1S/C25H25IO4Si/c1-15-13-14-19-21(27)16-9-5-6-10-17(16)22(28)25(19,24(15)30-31(2,3)4)23(29)18-11-7-8-12-20(18)26/h5-13,19,24H,14H2,1-4H3/t19-,24-,25-/m0/s1

description: dataset for infrared absorption spectroscopy (IR) IR (ATR, ṽ): 3059 (vw), 2955 (vw), 2927 (vw), 2881 (vw), 1692 (m), 1667 (m), 1590 (w), 1422 (w), 1247 (m), 1084 (m), 1011 (w), 872 (m), 841 (m), 802 (w), 768 (m), 751 (m), 735 (m), 715 (m), 607 (m), 541 (w), 453 (w), 390 (w) cm–1.
DOI: 10.14272/wpgxnufgnkcccz-owauwmpxsa-n.1
title: C25H25IO4Si
title: InChI=1S/C25H25IO4Si/c1-15-13-14-19-21(27)16-9-5-6-10-17(16)22(28)25(19,24(15)30-31(2,3)4)23(29)18-11-7-8-12-20(18)26/h5-13,19,24H,14H2,1-4H3/t19-,24+,25-/m0/s1

description: This dataset contains experimental data from a sample (InChI=1S/C25H25IO4Si/c1-15-13-14-19-21(27)16-9-5-6-10-17(16)22(28)25(19,24(15)30-31(2,3)4)23(29)18-11-7-8-12-20(18)26/h5-13,19,24H,14H2,1-4H3/t19-,24+,25-/m0/s1). The datasets from the following experiments are available: 1H nuclear magnetic resonance spectroscopy (1H NMR) 13C nuclear magnetic resonance spectroscopy (13C NMR) fast-atom bombardment mass spectrometry (FABMS) infrared absorption spectroscopy (IR)
DOI: 10.14272/wpgxnufgnkcccz-owauwmpxsa-n/chmo0000593
title: 1H nuclear magnetic resonance spectroscopy (1H NMR) ()
title: InChI=1S/C25H25IO4Si/c1-15-13-14-19-21(27)16-9-5-6-10-17(16)22(28)25(19,24(15)30-31(2,3)4)23(29)18-11-7-8-12-20(18)26/h5-13,19,24H,14H2,1-4H3/t19-,24+,25-/m0/s1

description: dataset for 1H nuclear magnetic resonance spectroscopy (1H NMR) 1H NMR (400 MHz, CDCl3, ppm) δ = 7.96 (td, 3J = 7.5 Hz, 4J = 1.4 Hz, 2H, CHAr), 7.85 (dd, 3J = 7.9 Hz, 4J = 1.6 Hz, 1H, CHAr), 7.74 (dd, 3J = 8.0 Hz, 4J = 1.1 Hz, 1H, CHAr), 7.66 (td, 3J = 7.5 Hz, 4J = 1.3 Hz, 2H, CHAr), 7.42 (td, 3J = 7.6 Hz, 4J = 1.2 Hz, 1H, CHAr), 7.08 (ddd, 3J = 8.0, 7.4 Hz, 4J = 1.6 Hz, 1H, CHAr), 5.47 (ddt, 3J = 4.4, 3.0 Hz, 4J = 1.5 Hz, 1H, C=CH), 5.22 (s, 1H, C(OTMS)H), 3.93 (dd, 3J = 10.9, 7.0 Hz, 1H, COCH), 2.63–2.39 (m, 1H, CHH), 2.12–1.99 (m, 1H, CHH), 1.95 (s, 3H, CH3), 0.06 (s, 9H, Si(CH3)3).Impurities: spectrum contains an unknown signal at 5.30 and a water signal at 1.58 ppm.
DOI: 10.14272/wpgxnufgnkcccz-owauwmpxsa-n/chmo0000595
title: 13C nuclear magnetic resonance spectroscopy (13C NMR) ()
title: InChI=1S/C25H25IO4Si/c1-15-13-14-19-21(27)16-9-5-6-10-17(16)22(28)25(19,24(15)30-31(2,3)4)23(29)18-11-7-8-12-20(18)26/h5-13,19,24H,14H2,1-4H3/t19-,24+,25-/m0/s1

description: dataset for 13C nuclear magnetic resonance spectroscopy (13C NMR) 13C NMR (101 MHz, CDCl3, ppm) δ = 198.7 (Cq, 1 × C=O), 196.2 (Cq, 1 × C=O), 192.2 (Cq, 1 × C=O), 141.5 (+, 1 × CHAr), 140.7 (Cq, 1 × CqAr), 137.3 (Cq, 1 × CqAr), 135.6 (Cq, 1 × CqAr), 135.3 (+, 1 × CHAr), 134.9 (+, 1 × CHAr), 134.4 (+, 1 × CHAr), 133.7 (Cq, 1 × Cq), 132.1 (+, 1 × CHAr), 129.1 (+, 1 × CHAr), 127.7 (+, 1 × CHAr), 127.5 (+, 1 × CHAr), 122.0 (+, 1 × C=CH), 95.0 (Cq, 1 × CqAr), 74.1 (Cq, 1 × Cq), 71.4 (+, 1 × CH), 45.9 (+, 1 × COCH), 28.4 (–, 1 × CH2), 22.4 (+, 1 × CH3), 1.0 (+, 3 × SiCH3).
DOI: 10.1285/i20705948v13n1p268
title: Bayesian prediction modelling for two-stage experimental trials for Poisson or Gamma distributed data

description: We consider Bayesian prediction modelling to evaluate a satisfaction index after a first phase of experiment in order to decide to stop or continue at the second stage. We apply this method to Poisson and Gamma distributed outcomes in many fields such as reliability or survival analysis for early termination due to either futility or efficacy. We look at two kinds of decisions making: an hybrid Bayesian-frequentist or a full Bayesian approach.
DOI: 10.14272/htuxsvmuhumuto-htapyjjxsa-n.1
title: C22H17IO3
title: InChI=1S/C22H17IO3/c1-13-10-11-22(21(26)16-8-4-5-9-18(16)23)17(12-13)19(24)14-6-2-3-7-15(14)20(22)25/h2-10,17H,11-12H2,1H3/t17-,22+/m0/s1

description: This dataset contains experimental data from a sample (InChI=1S/C22H17IO3/c1-13-10-11-22(21(26)16-8-4-5-9-18(16)23)17(12-13)19(24)14-6-2-3-7-15(14)20(22)25/h2-10,17H,11-12H2,1H3/t17-,22+/m0/s1). The datasets from the following experiments are available: fast-atom bombardment mass spectrometry (FABMS) infrared absorption spectroscopy (IR) 1H nuclear magnetic resonance spectroscopy (1H NMR) 13C nuclear magnetic resonance spectroscopy (13C NMR)
DOI: 10.14272/htuxsvmuhumuto-htapyjjxsa-n/chmo0000563
title: fast-atom bombardment mass spectrometry (FABMS) ()
title: InChI=1S/C22H17IO3/c1-13-10-11-22(21(26)16-8-4-5-9-18(16)23)17(12-13)19(24)14-6-2-3-7-15(14)20(22)25/h2-10,17H,11-12H2,1H3/t17-,22+/m0/s1

description: dataset for fast-atom bombardment mass spectrometry (FABMS) FAB-MS (m/z, 3‑NBA): 457 (23) [M+H]+, 231 (100), 225 (21), 154 (66). HRMS-FAB (m/z): [M]+ calcd for C22H18IO3, 457.0295; found, 457.0294.