cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.6084/m9.figshare.20020656.v1
title: Slag Foaming Fundamentals - A Critical Assessment

description: Slag foaming is part of steelmaking process and could bring several benefits: it helps to save energy, improves productivity, enhances the refractory service life, decreases noise pollution and protects the bath from nitrogen incorporation. Unfortunately, slag foaming is a highly dynamic process that is difficult to control. There are factors that limit the quality of the foam generated on the slag, such as: basicity, FeO content, surface tension, viscosity, carbon and oxygen injection. This paper aims to discuss the main factor that induces foaming, mathematical models proposed by different authors and the use of isothermal solubility diagram (ISD) to predict the foam quality.
DOI: 10.6084/m9.figshare.20020659
title: Analysis of Composite Membranes in the Separation of Emulsions Sunflower oil/water

description: Oil is a major pollutant of water resources, affects aquatic life, causing environmental degradation. Currently there is an increase in studies of membrane applied to separation of oil-water. Among these membranes, there are composite membranes, which show as main characteristic an association of organic and inorganic membrane properties. In a tangential flow process, the ceramic tube (support) is responsible for the mechanical strength of the membrane and the selective barrier property of the membrane is established by the polymer. The aim of this work is the application of α-alumina/polyamide 66 composite membrane in the retention of sunflower oil from oil-water emulsions and the study of resistance of such membranes in ultrafiltration processes. The α-alumina ceramic tubes were impregnated internally with a solution of polyamide 66 (PA66) (5% w/v) and tested with distilled water and sunflower oil solutions at concentrations of 50, 100 and 200 mg·L-1. Membranes impregnated with PA66 showed a sunflower oil retention between 53.5 and 99.5% and superior membrane resistance (MR) to the permeate flux (1.92 x 1013 a 5.52 x 1013) which explains the decrease in the permeate volume.
DOI: 10.6084/m9.figshare.20020659.v1
title: Analysis of Composite Membranes in the Separation of Emulsions Sunflower oil/water

description: Oil is a major pollutant of water resources, affects aquatic life, causing environmental degradation. Currently there is an increase in studies of membrane applied to separation of oil-water. Among these membranes, there are composite membranes, which show as main characteristic an association of organic and inorganic membrane properties. In a tangential flow process, the ceramic tube (support) is responsible for the mechanical strength of the membrane and the selective barrier property of the membrane is established by the polymer. The aim of this work is the application of α-alumina/polyamide 66 composite membrane in the retention of sunflower oil from oil-water emulsions and the study of resistance of such membranes in ultrafiltration processes. The α-alumina ceramic tubes were impregnated internally with a solution of polyamide 66 (PA66) (5% w/v) and tested with distilled water and sunflower oil solutions at concentrations of 50, 100 and 200 mg·L-1. Membranes impregnated with PA66 showed a sunflower oil retention between 53.5 and 99.5% and superior membrane resistance (MR) to the permeate flux (1.92 x 1013 a 5.52 x 1013) which explains the decrease in the permeate volume.
DOI: 10.6084/m9.figshare.20020660
title: Polymer Composites Reinforced with Hybrid Fiber Fabrics

description: In an effort to show the influence of the hybridization method in hybrid fabric reinforced composites within the characteristic of the fracture and the mechanical properties, two laminate reinforced with bi-directional woven were developed, where one of them was reinforced with a hybrid strand (hybrid strand composite laminate) and the other with a different strands (hybrid fabric composite laminate). Both laminates used polyester resin, Kevlar-49 and glass-E fibers, had four layers and were prepared industrially by hand lay-up manufacturing. The percentages by weight of fiberglass and Kevlar in each type of woven are equal. The hybrid strand composite laminate showed a higher tensile strength, however the hybrid fabric composite laminate showed superior properties in three-point bending test, for example, 41.7 % superiority in flexural strength. The results showed that the hybridization method in hybrid reinforced composites influences the mechanical behavior of laminates and the formation and spread of damage.
DOI: 10.6084/m9.figshare.20020660.v1
title: Polymer Composites Reinforced with Hybrid Fiber Fabrics

description: In an effort to show the influence of the hybridization method in hybrid fabric reinforced composites within the characteristic of the fracture and the mechanical properties, two laminate reinforced with bi-directional woven were developed, where one of them was reinforced with a hybrid strand (hybrid strand composite laminate) and the other with a different strands (hybrid fabric composite laminate). Both laminates used polyester resin, Kevlar-49 and glass-E fibers, had four layers and were prepared industrially by hand lay-up manufacturing. The percentages by weight of fiberglass and Kevlar in each type of woven are equal. The hybrid strand composite laminate showed a higher tensile strength, however the hybrid fabric composite laminate showed superior properties in three-point bending test, for example, 41.7 % superiority in flexural strength. The results showed that the hybridization method in hybrid reinforced composites influences the mechanical behavior of laminates and the formation and spread of damage.
DOI: 10.6084/m9.figshare.20020668
title: Phase Diagram Study for the PbO-ZnO-CaO-SiO2-"Fe2O3" System in Air with CaO/SiO2 in 1.1 and PbO/(CaO+SiO2) in 2.4 Weight Ratios

description: An experimental study on the phase equilibrium and the liquidus isotherms for the PbO-ZnO-CaO-SiO2-"Fe2O3" system with CaO/SiO2 in 1.1 and PbO/(CaO+SiO2) in 2.4 weight ratios, respectively, was carried out in the temperature range 1100-1300ºC (1373-1573 K). High temperature phases were determined by the equilibrium-quenching method. Results are presented in the form of pseudo-ternary sections "Fe2O3"-ZnO-(PbO+CaO+SiO2). X-Ray diffraction (XRD) and SEM-EDS results showed that the phase equilibria in this system are dominated by the high melting temperature spinel and zincite phases. It was observed that if the system is at a temperature below 1300ºC and the total (Fe2O3 + ZnO) is greater than 20 wt%, spinel and/or zincite will be present in the slag system. As an application of the phase diagram, the liquid phase compositions below the liquidus surface were estimated, then their viscosities were calculated using FACTSage software.
DOI: 10.6084/m9.figshare.20020668.v1
title: Phase Diagram Study for the PbO-ZnO-CaO-SiO2-"Fe2O3" System in Air with CaO/SiO2 in 1.1 and PbO/(CaO+SiO2) in 2.4 Weight Ratios

description: An experimental study on the phase equilibrium and the liquidus isotherms for the PbO-ZnO-CaO-SiO2-"Fe2O3" system with CaO/SiO2 in 1.1 and PbO/(CaO+SiO2) in 2.4 weight ratios, respectively, was carried out in the temperature range 1100-1300ºC (1373-1573 K). High temperature phases were determined by the equilibrium-quenching method. Results are presented in the form of pseudo-ternary sections "Fe2O3"-ZnO-(PbO+CaO+SiO2). X-Ray diffraction (XRD) and SEM-EDS results showed that the phase equilibria in this system are dominated by the high melting temperature spinel and zincite phases. It was observed that if the system is at a temperature below 1300ºC and the total (Fe2O3 + ZnO) is greater than 20 wt%, spinel and/or zincite will be present in the slag system. As an application of the phase diagram, the liquid phase compositions below the liquidus surface were estimated, then their viscosities were calculated using FACTSage software.
DOI: 10.6084/m9.figshare.20020674
title: Photocatalytic Performance of Titanates with Formula MTiO3 (M= Fe, Ni, and Co) Synthesized by Solvo-Combustion Method

description: This work reports the synthesis of a variety of materials with an ilmenite-type structure MTiO3 formula, where M= Fe, Co, and Ni, these materials were synthesized by the method of solvo-combustion, a simple and rapid method. These materials were characterized by X-ray Diffraction (XRD), scanning electron microscopy (SEM), FT-IR spectroscopy, thermogravimetric analysis (TGA/DTA), surface area determination by the BET method and analysis of particle size. The photocatalytic activity was measured in the degradation reactions of Rhodamine B (rhB) and tetracycline (TC). The results show that the crystallinity and surface area are factors that influence significantly on the photocatalytic activity of the synthesized titanates.
DOI: 10.6084/m9.figshare.20020674.v1
title: Photocatalytic Performance of Titanates with Formula MTiO3 (M= Fe, Ni, and Co) Synthesized by Solvo-Combustion Method

description: This work reports the synthesis of a variety of materials with an ilmenite-type structure MTiO3 formula, where M= Fe, Co, and Ni, these materials were synthesized by the method of solvo-combustion, a simple and rapid method. These materials were characterized by X-ray Diffraction (XRD), scanning electron microscopy (SEM), FT-IR spectroscopy, thermogravimetric analysis (TGA/DTA), surface area determination by the BET method and analysis of particle size. The photocatalytic activity was measured in the degradation reactions of Rhodamine B (rhB) and tetracycline (TC). The results show that the crystallinity and surface area are factors that influence significantly on the photocatalytic activity of the synthesized titanates.
DOI: 10.6084/m9.figshare.20020677
title: Thermal and Mechanical Properties of Vinyltrimethoxysilane (VTMOS) Crosslinked High Molecular Weight Polyethylene (HMWPE)

description: The use of polyethylene in sliding systems for automotive industry requires adequate mechanical properties, such as high wear resistance, besides good processing properties in conventional extrusion processes. Aiming to fulfill these requirements, crosslinks were introduced in a high molecular weight polyethylene (HMWPE) grade through a process involving grafting of vinyltrimethoxysilane (VTMOS) onto the polymer chain, promoted by dicumyl peroxide (DCP). The results obtained showed that the introduction of crosslinks improved the wear resistance of HMWPE. However, the HMWPE crosslinking led to a significant decrease in the Young’s Modulus, as a result of the reduction in crystallinity or the heterogeneous structure of the crosslinked samples. The tensile strength and the thermal properties were not affected.
DOI: 10.6084/m9.figshare.20020677.v1
title: Thermal and Mechanical Properties of Vinyltrimethoxysilane (VTMOS) Crosslinked High Molecular Weight Polyethylene (HMWPE)

description: The use of polyethylene in sliding systems for automotive industry requires adequate mechanical properties, such as high wear resistance, besides good processing properties in conventional extrusion processes. Aiming to fulfill these requirements, crosslinks were introduced in a high molecular weight polyethylene (HMWPE) grade through a process involving grafting of vinyltrimethoxysilane (VTMOS) onto the polymer chain, promoted by dicumyl peroxide (DCP). The results obtained showed that the introduction of crosslinks improved the wear resistance of HMWPE. However, the HMWPE crosslinking led to a significant decrease in the Young’s Modulus, as a result of the reduction in crystallinity or the heterogeneous structure of the crosslinked samples. The tensile strength and the thermal properties were not affected.
DOI: 10.6084/m9.figshare.20020680
title: Determination of Surface Temperature in ICP RF Plasma Treatments of Organic Materials

description: The reactions that can occur on organic materials treated in plasma enviorement are strongly affected by surface temperature, thus the sharp determination of this variable is extremely important to process control. In situ temperature measurements are often employed; however, the measured point is generally under the treated surface. If in metallic materials the high thermal conductivity minimizes this problem, in non-metallic materials processing it becomes important, because its thermal resistivity besides a high sensibility to small temperature variations. The present work uses a simulation tool to extract thermal data on Ar+O2 RF plasma processing of Stearic Acid. Experimental data were obtained by thermocouples placed inside the samples. The extrapolation of surface temperature was performed by numerical simulation with Autodesk CFD software v.15.1. Results show that the temperature of the surface reaches values higher than the ones measured inside the sample holder. This difference of temperature is in good agreement with the visual observation of the phase transformations in the treated material, showing a simple and valuable tool to better control of plasma treatments.
DOI: 10.6084/m9.figshare.20020680.v1
title: Determination of Surface Temperature in ICP RF Plasma Treatments of Organic Materials

description: The reactions that can occur on organic materials treated in plasma enviorement are strongly affected by surface temperature, thus the sharp determination of this variable is extremely important to process control. In situ temperature measurements are often employed; however, the measured point is generally under the treated surface. If in metallic materials the high thermal conductivity minimizes this problem, in non-metallic materials processing it becomes important, because its thermal resistivity besides a high sensibility to small temperature variations. The present work uses a simulation tool to extract thermal data on Ar+O2 RF plasma processing of Stearic Acid. Experimental data were obtained by thermocouples placed inside the samples. The extrapolation of surface temperature was performed by numerical simulation with Autodesk CFD software v.15.1. Results show that the temperature of the surface reaches values higher than the ones measured inside the sample holder. This difference of temperature is in good agreement with the visual observation of the phase transformations in the treated material, showing a simple and valuable tool to better control of plasma treatments.
DOI: 10.6084/m9.figshare.5907631
title: Using Severe Plastic Deformation to Fabricate Strong Metal Matrix Composites

description: The processing of bulk metals through the application of severe plastic deformation leads to significant grain refinement and a consequent strengthening of the material. High-pressure torsion (HPT) generally refers to the processing of disk samples and this technique is especially effective in producing extremely small grains. Recently, new experiments were conducted in which disks of two different alloys, based on aluminum and magnesium, were stacked together and then processed by HPT for up to 20 turns at room temperature. Analysis after processing revealed the formation of a multi-layered structure in the central region of the disks but with a true nanoscale microstructure containing different types of intermetallic compounds within an Al matrix leading to the formation of metal matrix nanocomposites at the disk edges. Measurements showed a lowering of density at the disk edges, thereby confirming the potential for using HPT to fabricate materials with exceptionally high strength-to-weight ratios.
DOI: 10.6084/m9.figshare.5907631.v1
title: Using Severe Plastic Deformation to Fabricate Strong Metal Matrix Composites

description: The processing of bulk metals through the application of severe plastic deformation leads to significant grain refinement and a consequent strengthening of the material. High-pressure torsion (HPT) generally refers to the processing of disk samples and this technique is especially effective in producing extremely small grains. Recently, new experiments were conducted in which disks of two different alloys, based on aluminum and magnesium, were stacked together and then processed by HPT for up to 20 turns at room temperature. Analysis after processing revealed the formation of a multi-layered structure in the central region of the disks but with a true nanoscale microstructure containing different types of intermetallic compounds within an Al matrix leading to the formation of metal matrix nanocomposites at the disk edges. Measurements showed a lowering of density at the disk edges, thereby confirming the potential for using HPT to fabricate materials with exceptionally high strength-to-weight ratios.
DOI: 10.6084/m9.figshare.5907472
title: Optical Properties of Blown Films of PA6/MMT Nanocomposites

description: In this work blown films of polyamide 6 (PA6) nanocomposites were produced at different processing conditions, with the addition of montmorillonite (MMT), pure and surface modified by an organic salt. The films' optical properties were evaluated according to ASTM D-1003 and the results correlated with the degree of crystallinity, nanoparticle's dispersion state and processing conditions. It was observed that the thinner the film, the lower the haze and higher the clarity, due to the presence of less internal scattering structures in the direction of the incident light. The PA6 films with the unmodified MMT had the lowest clarity values, due to nanoparticles' agglomeration. The organic modification of the montmorillonite led to its exfoliating through the PA6 matrix, resulting in an optimization of the films' optical properties (decreased haze and increased clarity) when compared to the pure PA6 films.
DOI: 10.6084/m9.figshare.5907472.v1
title: Optical Properties of Blown Films of PA6/MMT Nanocomposites

description: In this work blown films of polyamide 6 (PA6) nanocomposites were produced at different processing conditions, with the addition of montmorillonite (MMT), pure and surface modified by an organic salt. The films' optical properties were evaluated according to ASTM D-1003 and the results correlated with the degree of crystallinity, nanoparticle's dispersion state and processing conditions. It was observed that the thinner the film, the lower the haze and higher the clarity, due to the presence of less internal scattering structures in the direction of the incident light. The PA6 films with the unmodified MMT had the lowest clarity values, due to nanoparticles' agglomeration. The organic modification of the montmorillonite led to its exfoliating through the PA6 matrix, resulting in an optimization of the films' optical properties (decreased haze and increased clarity) when compared to the pure PA6 films.
DOI: 10.6084/m9.figshare.6152210
title: Physical, Chemical and Morphological Characterization of Polyamide Fabrics Treated with Plasma Discharge

description: In this work, physical, chemical and morphological modifications of three different polyamide 6.6 (PA6.6) fabrics were investigated using double barrier dielectric (DBD) plasma treatment. Several techniques of characterization were used to study the effects caused by the interaction between plasma discharge and polyamide fabrics, such as: contact angle, water drop adsorption, Energy Dispersive Spectroscopy (EDS), X-ray Photoelectron Spectroscopy (XPS), Scanning Electron Microscopy (SEM), whiteness by Berger degree and tensile strength. All analyses performed in this study showed that DBD plasma discharge, when applied on PA6.6 fiber, produces significant modifications on the surface of this substrate, without altering its intrinsic properties, thus proving the effectiveness of this important technology to the textile industry.
DOI: 10.6084/m9.figshare.6152210.v1
title: Physical, Chemical and Morphological Characterization of Polyamide Fabrics Treated with Plasma Discharge

description: In this work, physical, chemical and morphological modifications of three different polyamide 6.6 (PA6.6) fabrics were investigated using double barrier dielectric (DBD) plasma treatment. Several techniques of characterization were used to study the effects caused by the interaction between plasma discharge and polyamide fabrics, such as: contact angle, water drop adsorption, Energy Dispersive Spectroscopy (EDS), X-ray Photoelectron Spectroscopy (XPS), Scanning Electron Microscopy (SEM), whiteness by Berger degree and tensile strength. All analyses performed in this study showed that DBD plasma discharge, when applied on PA6.6 fiber, produces significant modifications on the surface of this substrate, without altering its intrinsic properties, thus proving the effectiveness of this important technology to the textile industry.
DOI: 10.6084/m9.figshare.6152213
title: Analysis of Water Barrier, Mechanical and Thermal Properties of Nanocoposites Based on Cassava Starch and Natural Clay or Modified by Anionic Exchange

description: Biopolymer films have several industrial applications because they are environmentally sustainable. Cassava starch is a biopolymer that is easily available, but has limitations: it is hydrophilic, poorly resistant and degradable. The improvement of these properties was proposed in this research from the use of bentonite clay (BT) as a filling material. The compatibilization of this in the polymer matrix was obtained by ion exchange with an organic anionic surfactant. The formation of intercalated or exfoliated starch nanocomposites in the presence of natural or modified clay was characterized by XRD, FTIR, AFM and SEM. The improvement of water vapor, thermal and mechanical properties was investigated by WVP, solubility, TGA and tensile test. The starch nanocomposites in the presence of modified clay showed a better result than those of natural clay. There was no significant difference in the color of the starch film in the presence of the natural or modified clay.
DOI: 10.6084/m9.figshare.6152213.v1
title: Analysis of Water Barrier, Mechanical and Thermal Properties of Nanocoposites Based on Cassava Starch and Natural Clay or Modified by Anionic Exchange

description: Biopolymer films have several industrial applications because they are environmentally sustainable. Cassava starch is a biopolymer that is easily available, but has limitations: it is hydrophilic, poorly resistant and degradable. The improvement of these properties was proposed in this research from the use of bentonite clay (BT) as a filling material. The compatibilization of this in the polymer matrix was obtained by ion exchange with an organic anionic surfactant. The formation of intercalated or exfoliated starch nanocomposites in the presence of natural or modified clay was characterized by XRD, FTIR, AFM and SEM. The improvement of water vapor, thermal and mechanical properties was investigated by WVP, solubility, TGA and tensile test. The starch nanocomposites in the presence of modified clay showed a better result than those of natural clay. There was no significant difference in the color of the starch film in the presence of the natural or modified clay.