cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.6084/m9.figshare.21163150
title: Facile Synthesis, Biological Evaluation, DFT Studies and <i>in Silico</i> Prediction ADME/Pharmacokinetics Properties of <i>N</i>-(1-(2-Chlorobenzo[h]Quinolin-3-yl)-1-Substituted-vin-2-yl)Benzamide Derivatives

description: A new series of various <i>N</i>-(1-(2-chlorobenzo[<i>h</i>]quinolin-3-yl)-1-substituted-vin-2-yl)benzamide derivatives was designed and synthesized based on the 2-chlorobenzo[<i>h</i>]quinoline core as potential antioxidant and insecticidal agents. <i>In vitro</i> antioxidant activities of these compounds were evaluated and compared with commercial antioxidant (ascorbic acid). The results showed good antioxidant activities of these compounds. In addition, <i>in vitro</i> insecticidal activities revealed that most of these compounds exhibited high insecticidal activity against cotton leafworm compared with chlorpyrifos. Some compounds in these series were better than the commercial insecticidal, chlorpyrifos.
DOI: 10.6084/m9.figshare.21163150.v1
title: Facile Synthesis, Biological Evaluation, DFT Studies and <i>in Silico</i> Prediction ADME/Pharmacokinetics Properties of <i>N</i>-(1-(2-Chlorobenzo[h]Quinolin-3-yl)-1-Substituted-vin-2-yl)Benzamide Derivatives

description: A new series of various <i>N</i>-(1-(2-chlorobenzo[<i>h</i>]quinolin-3-yl)-1-substituted-vin-2-yl)benzamide derivatives was designed and synthesized based on the 2-chlorobenzo[<i>h</i>]quinoline core as potential antioxidant and insecticidal agents. <i>In vitro</i> antioxidant activities of these compounds were evaluated and compared with commercial antioxidant (ascorbic acid). The results showed good antioxidant activities of these compounds. In addition, <i>in vitro</i> insecticidal activities revealed that most of these compounds exhibited high insecticidal activity against cotton leafworm compared with chlorpyrifos. Some compounds in these series were better than the commercial insecticidal, chlorpyrifos.
DOI: 10.6084/m9.figshare.21163072
title: Melan-A expression related to apoptosis of melanocytes in segmental and non-segmental vitiligo

description: Additional data for "Melan-A expression related to apoptosis of melanocytes in segmental and non-segmental vitiligo"
DOI: 10.34730/29aa46a0ce9b4524b82a71b67d181f09
title: FAIR Digital Object

description: Internal presentation in Jülich Supercomputing centre about FAIR Digital Object and its application for TOAR database.
DOI: 10.57745/rdtthq
title: Model.R

description: :unav
DOI: 10.57745/hvpnnm
title: Sensitivity analysis.R

description: :unav
DOI: 10.57745/oznwmd
title: sensitivity_data.tab

description: :unav
DOI: 10.5281/zenodo.7096237
title: Satisfaction with Telemedicine for Cancer Pain Management: A Model of Care and Cross-Sectional Patient Satisfaction Study

description: Background: Since cancer pain requires complex modalities of care, the proper strategy for addressing its telemedicine-based management should be better defined. This study aimed to trace a pathway for a progressive implementation of the telemedicine process for the treatment of pain in the setting of cancer patients. Methods: The features of the model were investigated to dissect the dropout from the telemedicine pathway. A cross-sectional patient satisfaction study was conducted. The degree of satisfaction was evaluated through a developed 22-item questionnaire (Likert scale 0–7). Results: A total of 375 video consultations for 164 patients (mean age 62.9 years) were performed through remote consultations for cancer pain management between March 2021 and February 2022. After the exclusion of 72 patients, 92 (56.1%) were included in the analysis. The dropout ratio was 8.7%. The number of visits and pharmacological therapies for neuropathic pain correlated with the risk for readmission (p &lt; 0.05). Overall, the satisfaction was very high (mean &gt; 5.5 for all items). Conclusion: Feedback from patients reflected high satisfaction rates with the care provided. A methodological approach based on the degree of satisfaction combined with the analysis of the pathways can help to implement the quality of a service provided through telemedicine. While not without limitations, our hybrid protocol can be useful for addressing cancer pain through a patient-centered approach.
description: Please cite our work if similar analyses will be performed.
DOI: 10.5281/zenodo.7096236
title: Satisfaction with Telemedicine for Cancer Pain Management: A Model of Care and Cross-Sectional Patient Satisfaction Study

description: Background: Since cancer pain requires complex modalities of care, the proper strategy for addressing its telemedicine-based management should be better defined. This study aimed to trace a pathway for a progressive implementation of the telemedicine process for the treatment of pain in the setting of cancer patients. Methods: The features of the model were investigated to dissect the dropout from the telemedicine pathway. A cross-sectional patient satisfaction study was conducted. The degree of satisfaction was evaluated through a developed 22-item questionnaire (Likert scale 0–7). Results: A total of 375 video consultations for 164 patients (mean age 62.9 years) were performed through remote consultations for cancer pain management between March 2021 and February 2022. After the exclusion of 72 patients, 92 (56.1%) were included in the analysis. The dropout ratio was 8.7%. The number of visits and pharmacological therapies for neuropathic pain correlated with the risk for readmission (p &lt; 0.05). Overall, the satisfaction was very high (mean &gt; 5.5 for all items). Conclusion: Feedback from patients reflected high satisfaction rates with the care provided. A methodological approach based on the degree of satisfaction combined with the analysis of the pathways can help to implement the quality of a service provided through telemedicine. While not without limitations, our hybrid protocol can be useful for addressing cancer pain through a patient-centered approach.
description: Please cite our work if similar analyses will be performed.
DOI: 10.6084/m9.figshare.19601359
title: Bipolar Disorder and psychological trauma

description: Trauma symptoms, clinical characteristics, level of functioning and level of cognitive deterioration in a trauma-exposed sample of patients with Bipolar Disorder
DOI: 10.14457/tu.the.2021.607
title: Consumers' right to repair defective electronic products

description: Currently, the manufacturers attempt to restrict the owners and third-party repair shops from repairing electronic products, such as specifying the terms under warranty and limiting spare parts. Therefore, the consumers have been forced to receive authorised service only. When the consumer’s product got a defect made by themselves or others, the manufacturer will not be liable, and the consumer has four choices: 1) requiring the original equipment manufacturer or authorised provider to repair the product; 2) using the service of a third-party repairer; 3) attempting to repair it by themselves or 4) discarding and replacing. Under this condition, however, the manufacturer will not provide the spare parts and essential information to be able to repair by owners and third-party repair shops. So, there are only two choices left, requiring the original equipment manufacturer or authorised provider to repair the product or trashing it. The consumers’ right to repair seems unobvious in Thailand because Thai Civil and Commercial Code and Thai regulations relating to Consumer protection do not specify the right to repair. Consumers have to spend more money on repair services of the manufacturer. This thesis aims to study the consumer protection law in Thailand and extensively acknowledge the background, purpose, and scope of consumers’ right to repair in foreign countries. The study mainly analyses relevant laws of the United States: the Magnuson-Moss Warranty Act and the Fair repair Act. This thesis discovers that the Fair Repair Act of the United States introduced into Congress will enhance the consumers’ right to repair by forcing the manufacturer to provide their consumers and repair shop with spare parts. In Thailand, the right to repair seems alien to consumer protection law. The study finds that Thailand should adopt the right to repair to protect consumers from unfair practices. Therefore, the author would like to propose the new regulation and provisions which protect the consumer from the unfair practice of manufacturers. Firstly, the regulation should mandate the manufacturers to distribute the spare parts, equipment and information at “the equitable price”. The manufacturer has to consider the ability of users and repair shops to afford the parts, equipment, or documentary. Secondly, the regulation shall provide a specific provision to prevent consumers from unfair terms. For example, the manufacturer shall not specify the warranty clauses that compel the consumer to receive only the manufacturer’s service.
DOI: 10.14457/tu.the.2021.608
title: Effects of nitrogen, phosphorus, and sulfur doping of carbon dots from sugar on UV absorbance, photoluminescence, phenolic content, stability, and antioxidant activities

description: Carbon dots (CDs) are nanomaterials with interesting properties and have been used in a wide range of applications, such as cosmetics, composites, and electronics. Their properties are governed by the structure and composition. The presence and amount of heteroatoms in the CD core are known to significantly affect their photoluminescence. To investigate the effects of heteroatoms on other properties, in this work, CDs were synthesized from sugar via hydrothermal method and doped with nitrogen, phosphorus, and sulfur using corresponding nitric acid, phosphoric acid, and sulfuric acid. The amounts of nitrogen, phosphorus, and sulfur were controlled by the amount of acid added with respect to sugar. After purification, the UV absorbance, sun protection factor, photoluminescence, phenolic content, photostability and antioxidant activities of the all CDs were measured. The UV absorbance and sun protection factors of the CDs were also compared with avobenzone and oxybenzone, two well-known UV absorbers in sunscreens. The antioxidant activities of the CDs were tested using 2,2-diphenyl-1-picryl-hydrazyl-hydrate (DPPH) assay and compared with that of ascorbic acid a well-known antioxidants. The results from this thesis will be crucial for a number of cosmetic and pharmaceutical applications.
DOI: 10.14457/tu.the.2021.609
title: Synthesis of carbon dots from sodium polyacrylate and metal oxides for electrochemical applications

description: Various carbon-based materials and metal oxides have been used to improve the performance of electrochemical applications. However, there are both advantages and disadvantages to each kind of these electrode material. Hence, the use of multi-component electrode materials is a distinguished approach to magnifying energy storage performances by taking advantage of each component's unique functionality and synergetic effects. Noticeably, in these multi-component electrode materials, metal oxides show great potential as redox-active materials whereas carbon-based materials can increase the effective utilization of active materials and improve the electrical conductivity and structural integrity of the composite electrodes. Among several carbon-based materials, carbon dots (CDs) are a remarkable class of unique carbon nanomaterials that recently emerged as an option in electrochemical applications, owing to their excellent electron-transfer efficiency, high surface area, and unique electronic properties, low environmental hazard, and especially their notable semiconductor nanostructures. In addition to CDs, the metal oxides used in this work are TiO2 and CuO-NiO because both of them are abundant, inexpensive with low toxicity, and have simple preparation. Most prominently, they are novel materials with promising properties for electrochemical applications. Herein, we presented two projects within this thesis research based on a simple route to prepare CDs that combine with each metal oxide to study synergetic effects. In this work, CDs were synthesized from sodium polyacrylate via a one-step pyrolysis method. Sodium polyacrylate, which is a polymer widely used in diapers, cosmetics, and superabsorbent material, can be turned into useful nanomaterials. This polymer is a suitable precursor because of its high aqueous solubility, readily available, and low cost. TiO2 has not been widely investigated despite its faradaic and semiconducting properties, high stability, and long‐term electrochemical stability. Besides, CuO and NiO are also outstanding metal oxide that has been applied in a variety of electrochemical applications because of their high theoretical capacitance, low cost, chemical stability, abundant resources, environmental compatibility, and pseudocapacitive properties. However, the CuO-NiO nanocomposite is rarely applied in a supercapacitor, suggesting a novel approach to developing advanced electrode material. Consequently, the composite of carbon dots and metal oxides obtained in this work was a novel strategy to achieve a high-performance and low-cost supercapacitor.
DOI: 10.5281/zenodo.7092280
title: Semantically tagged Finnish Wikipedia 2017

description: <strong>Description of FI Wikipedia 2017 tagging</strong> <strong>Kimmo Kettunen</strong> <strong>University of Eastern Finl</strong><strong>and</strong> The tagged data contains the texts of the Finnish Wikipedia of 2017. It has been first tagged syntactically in the Language Bank of Finland using the available UD2 tagger version of the Mylly service (https://mylly.rahtiapp.fi/home). Semantic tags to the UD2 parse have been added using a lexical semantic tagger FiST (Kettunen, 2019, https://aclanthology.org/W19-0306/). This published version has been condensed to a format where each analysed word contains the 1. original running word form, 2. lemma of the word form from UD2 parse, 3. part-of-speech of the word from FiST 4. semantic tag(s) for the word from FiST, and 5. syntactic function of the word from UD2 parse. Semantic tags used are explained in this UCREL Semantic Analysis System (USAS) document: https://ucrel.lancs.ac.uk/usas/USASSemanticTagset.pdf Tagging includes all the semantic tags available for the word, as FiST does not perform disambiguation. Unknown words for the tagger are marked with tag Z99. Punctuation is tagged with PUNCT and numbers with NUMB. Lines beginning with # are output of UD2 and contain document, paragraph and sentence information. The output contains 6 415 027 sentences and 98.81 million lines. Lexical coverage of the semantic tagging is 76.59 % <strong>Examples of output</strong> # newdoc # newpar # sent_id = 1 # text = Amsterdam Amsterdam#Amsterdam#Proper#Z2 root # newpar # sent_id = 2 # text = Amsterdam on Alankomaiden pääkaupunki. Amsterdam#Amsterdam#Proper#Z2 nsubj:cop on#olla#Verb#A3+ A1.1.1 M6 Z5 cop Alankomaiden#Alankomaat#Proper#Z2 nmod:poss pääkaupunki#pääkaupunki#Noun#M7 root . PUNCT
DOI: 10.5281/zenodo.7092279
title: Semantically tagged Finnish Wikipedia 2017

description: <strong>Description of FI Wikipedia 2017 tagging</strong> <strong>Kimmo Kettunen</strong> <strong>University of Eastern Finl</strong><strong>and</strong> The tagged data contains the texts of the Finnish Wikipedia of 2017. It has been first tagged syntactically in the Language Bank of Finland using the available UD2 tagger version of the Mylly service (https://mylly.rahtiapp.fi/home). Semantic tags to the UD2 parse have been added using a lexical semantic tagger FiST (Kettunen, 2019, https://aclanthology.org/W19-0306/). This published version has been condensed to a format where each analysed word contains the 1. original running word form, 2. lemma of the word form from UD2 parse, 3. part-of-speech of the word from FiST 4. semantic tag(s) for the word from FiST, and 5. syntactic function of the word from UD2 parse. Semantic tags used are explained in this UCREL Semantic Analysis System (USAS) document: https://ucrel.lancs.ac.uk/usas/USASSemanticTagset.pdf Tagging includes all the semantic tags available for the word, as FiST does not perform disambiguation. Unknown words for the tagger are marked with tag Z99. Punctuation is tagged with PUNCT and numbers with NUMB. Lines beginning with # are output of UD2 and contain document, paragraph and sentence information. The output contains 6 415 027 sentences and 98.81 million lines. Lexical coverage of the semantic tagging is 76.59 % <strong>Examples of output</strong> # newdoc # newpar # sent_id = 1 # text = Amsterdam Amsterdam#Amsterdam#Proper#Z2 root # newpar # sent_id = 2 # text = Amsterdam on Alankomaiden pääkaupunki. Amsterdam#Amsterdam#Proper#Z2 nsubj:cop on#olla#Verb#A3+ A1.1.1 M6 Z5 cop Alankomaiden#Alankomaat#Proper#Z2 nmod:poss pääkaupunki#pääkaupunki#Noun#M7 root . PUNCT
DOI: 10.14457/tu.the.2021.610
title: การพัฒนาผลิตภัณฑ์ใหม่ในรูปแบบปุ๋ยคอกอัดเม็ดผสมจุลินทรีย์เพื่อส่งเสริมการเจริญเติบโตและการควบคุมโรคขอบใบทองของคะน้า

description: งานวิจัยนี้มีวัตถุประสงค์เพื่อคัดเลือกจุลินทรีย์ปฏิปักษ์ที่มีประสิทธิภาพในการส่งเสริมการเจริญเติบโตและควบคุมโรคขอบใบทองของคะน้า และพัฒนาผลิตภัณฑ์ใหม่ในรูปแบบปุ๋ยคอกอัดเม็ดผสมจุลินทรีย์ที่มีประสิทธิภาพในการส่งเสริมการเจริญเติบโตและควบคุมโรคขอบใบทองของคะน้า วางแผนการทดลองแบบสุ่มสมบูรณ์ (completely randomized design, CRD) โดยทำการคัดเลือกแบคทีเรียปฏิปักษ์จากดินและส่วนต่าง ๆ ของพืช ได้แบคทีเรียทั้งหมดจำนวน 102 ไอโซเลท และพบว่ามีแบคทีเรียปฏิปักษ์จำนวน 35 ไอโซเลท เกิดปฏิกิริยาการตอบสนองอย่างเฉียบพลันบนต้นมะเขือเทศ เมื่อนำไปทดสอบการยับยั้งการเจริญของเชื้อ Xanthomonas campestris pv. campestris (Xcc) พบว่า แบคทีเรียปฏิปักษ์ไอโซเลท TU125 มีประสิทธิภาพในยังยั้งการเจริญของเชื้อ Xcc สาเหตุโรคขอบใบทองของคะน้าได้ดี (27±0.00 มิลลิเมตร) นอกจากนี้ ในการทดสอบด้วยวิธี blotter method ของคะน้าอายุ 10 วัน พบว่าแบคทีเรียปฏิปักษ์ไอโซเลท TU125 ส่งผลให้ต้นกล้าคะน้ามีความสูงต้น ความยาวราก น้ำหนักสด และน้ำหนักแห้งมากที่สุด และส่งผลให้ต้นกล้าคะน้ามีปริมาณคลอโรฟิลล์-เอ คลอโรฟิลล์-บี และปริมาณคลอโรฟิลล์ทั้งหมดสูงที่สุดแตกต่างกันอย่างมีนัยสำคัญทางสถิติ (p&lt;0.05) เช่นเดียวกับการทดสอบในระดับโรงเรือนทดลอง และเมื่อทำการทดสอบประสิทธิภาพของแบคทีเรียปฏิปักษ์ในการผลิตฮอร์โมนพืชไซโตไคนินและกระตุ้นภูมิต้านทานโรคขอบใบทอง พบว่า กรรมวิธีการฉีดพ่นด้วยแบคทีเรียปฏิปักษ์ไอโซเลท TU125 ส่งผลให้ปริมาณคลอโรฟิลล์-เอ คลอโรฟิลล์-บี คลอโรฟิลล์ทั้งหมด และการสะสม salicylic acid สูงที่สุด นอกจากนี้ ยังพบว่ากรรมวิธีการฉีดพ่นด้วยแบคทีเรียปฏิปักษ์ดังกล่าว สามารถลดความรุนแรงของโรคได้สูงถึง 89.89 เปอร์เซ็นต์ เมื่อนำแบคทีเรียปฏิปักษ์ไอโซเลท TU125 ไปทดสอบการย้อมแกรม พบว่าเป็นแบคทีเรียแกรมบวก จึงนำไปทำการทดสอบและระบุชนิดของแบคทีเรียดังกล่าว พบว่า มีความใกล้เคียงกับ Bacillus amyloliquefaciens ถึง 99 เปอร์เซ็นต์ ตามฐานข้อมูลของ NCBI จากนั้นจึงนำไปผสมในผลิตภัณฑ์ใหม่ในรูปแบบปุ๋ยคอกอัดเม็ด พบว่า กรรมวิธีที่ 4 (มูลหมู + แคลเซียมฟอสเฟต + cell suspension TU125 + กรดคาซามิโน + ไทอามีน + น้ำกลั่น) คงความมีชีวิตรอดของประชากรแบคทีเรียได้สูงที่สุดในระยะเวลา 4 เดือน ซึ่งแตกต่างอย่างมีนัยสำคัญทางสถิติ (p&lt;0.05) เมื่อเปรียบเทียบกับกรรมวิธีอื่น ๆ และจากการทดสอบประสิทธิภาพของผลิตภัณฑ์ปุ๋ยคอกอัดเม็ดผสมจุลินทรีย์ในการส่งเสริมการเจริญเติบโตของคะน้า พบว่า กรรมวิธีที่มี B. amyloliquefaciens TU125 ส่งผลต่อการเจริญเติบโตได้ดีกว่ากรรมวิธีที่ไม่มีแบคทีเรียปฏิปักษ์ เมื่อถึงช่วงระยะเก็บเกี่ยวที่ 42 วัน พบว่า กรรมวิธีที่ 4 ส่งผลให้คะน้ามีการเจริญเติบโตที่ดี และเมื่อทดสอบประสิทธิภาพผลิตภัณฑ์ปุ๋ยคอกอัดเม็ดผสมจุลินทรีย์ในการผลิตฮอร์โมนพืชไซโตไคนินและควบคุมโรคขอบใบทองของคะน้า (ที่มีและไม่มีการปลูกเชื้อ Xcc) พบว่า กรรมวิธีที่มีแบคทีเรียปฏิปักษ์ไอโซเลท TU125 ส่งผลให้มีปริมาณคลอโรฟิลล์-เอ คลอโรฟิลล์-บี และคลอโรฟิลล์ทั้งหมดสูงกว่ากรรมวิธีที่ไม่มีแบคทีเรียปฏิปักษ์ ซึ่งเมื่อคะน้ามีอายุ 26-37 วันหลังปลูก กรรมวิธีที่ 4 ส่งผลให้มีปริมาณคลอโรฟิลล์การสะสม salicylic acid และสามารถลดความรุนแรงของโรคได้สูงที่สุด
DOI: 10.14457/tu.the.2021.611
title: Catalytic pyrolysis of various biomass to aromatic hydrocarbons over Ni-based catalysts

description: The non-noble Ni-based catalyst has been attentive due to its low-cost and high activity in hydro-transfer reactions. However, the selective conversion is still lower compared to noble metal-based catalysts. In this study, we would like to design the modified Ni catalyst by co-doping P and Ce to form Nickel phosphide and bimetallic catalysts, which are supported in N-doping activated carbon. Aiming to study to convert agroforestry residues into valuable chemicals, which are further applied in Jet fuel, we investigated the effect of various biomass types as well as design Ni -based catalysts on upgrading fast pyrolysis oil. In detail, the research includes three parts: Part 1: Studying pyrolysis of 20 biomass samples in Thailand using data analysis to predict the pathway of phenolic formation, which was affected by biomass type and pyrolysis temperature. We found that a significant interaction relationship between lignin, hemicellulose, and pyrolysis temperature on the fraction of phenolic and aromatic hydrocarbon with rich-lignin biomass content and high temperature (550 – 600 °C) in fast catalytic pyrolysis can be an excessive solution to convert the waste material to high alkylphenol content. The statistic was performed to predict the yield of phenolic compounds from each fraction of lignocellulose with temperature. Part 2 and 3 are the development of nickel phosphide and bi-metallic of Ni-Ce support on N-doping activated charcoal for deoxygenation of pyrolyzed vapor from biomass pyrolysis in case of full H2 and limited H2 co-feeding gas, respectively. In the detail, the Ni2P/N-doping catalyst significantly influenced by the co-ordination of N-doping activated carbon to the formation of pure Ni2P phase with small particle size. The high selective alkylphenol product (&gt;70%) was observed under mild temperature (300 – 400 °C), under atmospheric pressure in fixed-bed reactors. The Ni2P/CN50 catalyst can be applied in three cycles without treatment still performed high deoxygenation and prior better than without N-doping. Last part, the bi-metallic Ni-Ce catalysts with different Ni and Ce loading were tested with different co-feeding gas including H2, N2, CO2, and water. The estimated result is an in-situ generation of H2 by reforming and then immediately hydrodeoxygenation. The results show that the Ni-Ce bimetallic supported on N-doping activated carbon catalyst can be limited to the H2 atmosphere in hydrodeoxygenation up to 50%. However, to form full free-oxy by hydrodeoxygenation of lignin fragment under mild conditions (400 °C and 1 atm) without H2 gas co-feeding is still challenged.