DOI: 10.25921/zcxs-5887
title: NOAA/WDS Paleoclimatology - Baradla Cave Geochemical Data from 129000 to 108800 Cal Yr BP

description: Studies on the last interglacial (LIG) can provide information on how our environment behaved in a period of slightly higher global temperatures at about 125 ± 4 ka, even if it is not the best analogue for the Holocene. The available LIG climate proxy records are usually better preserved and can be studied at a higher resolution than those of the preceding interglacials, allowing detailed comparisons. This paper presents complex stable hydrogen, carbon and oxygen isotope records obtained for carbonate (δ13C and δ18Ocarb) and fluid inclusion hosted water (δD and δ18Ow) of a stalagmite from the Baradla Cave system in Central Europe that covers most of the LIG, as proven by U-Th dates. Comparing its C and O isotope data with records reported for other speleothem (cave-hosted carbonate) deposits from Europe revealed the complex behavior of these climate proxies, with a concerted relative increase in 18O of carbonates from 128 to 120 ka and synchronized shifts in the opposite direction after 119 ka. The hydrogen isotope analyses of inclusion-hosted water extracted from the BAR-II stalagmite also correspond to the regional climate proxy records, with meaningful deviations from global temperature trends. Beside following the general paleotemperature pattern from the climate optimum (high δD values up to −64‰ around 120 ka) to the subsequent cooling starting at about 119 ka (low δD values down to −90‰ at about 109 ka), a period between 126.5 and 123 ka with low δD values (down to −81‰) is detected in the BAR-II stalagmite. Although the isotope shifts are muted in the C-O isotope data of carbonate due to competitive fractionation processes, the δ13C data show a positive relationship with the δD pattern, indicating humidity – and possibly temperature – variations. The periods with low δD values fit well to temperature and humidity changes inferred from proxy records from western Europe to the eastern Mediterranean. Spatial distributions of these variables show, that at about 125 ± 2 ka the Mediterranean region was characterized by warm, humid conditions and enhanced seasonality with elevated winter precipitation. The combined interpretation of stable isotope data revealed that the Alpine and Mediterranean regions behaved differently during Greenland Stadial 26 (GS26, ∼119 to 116.2 ka). While the Alpine records fluctuated in close agreement with the Central Greenland ice core δ18O data, the BAR-II stalagmite show a positive δ18Ocarb anomaly. The Baradla data indicate enhanced aridity and seasonality for a part of GS26, with the relative dominance of summer precipitation and Mediterranean moisture contribution. Following the GS26 event, the effect of long-term global cooling becomes dominant in the Baradla isotope records and leads to glacial inception at about 109 ka.
description: Data contributed as part of SISAL v3 Global Speleothem Isotope and Trace Element Database (https://doi.org/10.25921/jajq-qg60). Notes from the SISAL database: Entity BAR-II#B (SISAL entity_id = 160) had two or more isotope values (d18O and d13C) at depth_sample = 234.5, 232.4, 231.8, 222.95, 222, 183, 182.2, 179.75, 177.4, 172, 162.6, 133.4, 130.6, 129.5, 128.5, 122.4, 120.5, 114.9, 112.1, 103.6, 84.15, 82.05, 80.85, 56.05, 38.6, 20.05mm; these were averaged.\\ Entity NU2 (entity_id = 397): C14 date at 27mm was not calibrated as it was determined as the location of the 1965 bomb peak. In the original paper, only the recounted 2016 lamina data was present whereas the average of three counts is shown here to include lamina age uncertainty.