cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.15151/esrf-es-1034080886
title: Ce distribution, speciation and redox in Moroccan sedimentary phosphate ores

description: Phosphorus is a critical resource required for the production of agricultural fertilizers and is mainly produced from sedimentary phosphates rocks. These rocks usually contain rare earth elements, and potentially become a future REE reserves. Among the various REE, the cerium (Ce) shows relatively high concentration and variable negative anomaly indicative of the oxidation of Ce3+ into Ce4+ due to either microbial activity and/or different conditions (redox, pH, depth). Hence, in this proposal, we wish to characterize the in-situ distribution, speciation, and redox of Ce in phosphate rock from Morocco using a combination of μ-XRF, HR-XANES and HR-EXAFS to elucidate, i) the in-situ distribution and the concentration of Ce, ii) the Ce bearing minerals and the enrichment process, iii) the speciation of Ce (fixation mode, oxidation state). Results will guide the possible REE recovery, as well as to understand the geochemistry of enrichments to better assess the deposition conditions.
DOI: 10.15151/esrf-es-1014492588
title: XRD and XAS investigation of cobalt-based Fischer–Tropsch synthesis catalysts.

description: This proposal aims to study cobalt nanoparticles on different supports exposed to the FT reaction conditions using synchrotron X-ray techniques such as wideangle X-ray scattering (WAXS), X-ray absorption near edge structure (XANES), and X-ray fluorescence spectroscopy (XRF). The focus will be on investigating well-defined cobalt FT catalysts, with particular attention to the cobalt particles sintering, their crystallographic structure, chemical coordination environment, and the impact of supporting material.
DOI: 10.15151/esrf-es-999309464
title: Combined in situ XAS-XES of bioinspired Cu-MOFs as methane partial oxidation catalysts

description: This proposal aims to characterize by Cu k-edge XAS, HERFD-XANES, vtc-XES and RIXS to disclose the finest details on the redox chemistry of Cu sites hosted within a selection of Cu-MOFs. In particular, structural and redox behavior will be investigated during the stepwise methane to methanol reaction. These MOFs, belonging to the UiO-6X family, have been post-synthetically treated to introduce various biomimetic anchoring site, as inspired by the histidine brace coordinating Cu in some enzymes capable of performing C-H bond oxidation. With each technique, will focus on the main reaction stages (desolvation, oxidation and reactivity with CH4). Special care will be put in characterizing the oxidized state, aiming at the identification of potentially active Cu-O species. These outcomes will provide unprecedented structural details on the local environment in such Cu-MOFs at the various reaction stages.
DOI: 10.5281/zenodo.7682976
title: MSAs generated for RoseTTAFold and AlphaFold2

description: The attached zip files contain MSAs generated for protein structures predicted by RoseTTAFold and AlphaFold2 for a study on the 15th iteration of the Critical Assessment for Structure Prediction (CASP15) available targets. Predicted structures as well as results can be found at https://github.com/Bhattacharya-Lab/CASP15
DOI: 10.5281/zenodo.7682977
title: MSAs generated for RoseTTAFold and AlphaFold2

description: The attached zip files contain MSAs generated for protein structures predicted by RoseTTAFold and AlphaFold2 for a study on the 15th iteration of the Critical Assessment for Structure Prediction (CASP15) available targets. Predicted structures as well as results can be found at https://github.com/Bhattacharya-Lab/CASP15
DOI: 10.15151/esrf-es-1033083518
title: CO2 reduction over GaZrOx oxide: disclosing catalyst structure and VO contribution through MES-PSD operando-XAS/PDF

description: In a sustainable CO2 recycling economy, we are developing GaZrOx/H-SSZ-13 combined catalyst for CO2 direct conversion to high-value products i.e., propane and propylene. We here propose to combine MES-PSD with operando-XAS/PDF at Ga and Zr K-edges to achieve an exhaustive characterization of the two catalysts and to ultimately extract the signal stemming from reactive species as well as reaction kinetics. Furthermore, this beamtime will make the most out of the recent PDF update on BM31 coupling for the first time ever this technique under high pressure/temperature to MES exploiting PSD.
DOI: 10.6084/m9.figshare.22187799
title: Almanac of Emotions for children and adolescents in times of pandemic

description: ABSTRACT The pandemic context has brought health problems, that actualize, in the subjectivity of children and adolescents in a situation of illness, a suffering that is difficult to address, but that needs to be expressed and elaborated, in favor of the flow of treatment. The Almanac of Emotions emerged from the concern of two psychologists to offer their patients – in a pediatric ward of a Hematological Center in the State of Rio de Janeiro – means of access to the symbolic expression. The desired objective was to give space for expression to the affections that children and adolescents bring to the context of treatment. Through free symbolic manifestations, we believe it is possible to represent what is happening in the subjectivity of these subjects, in relation to the following themes: pandemic, life, world, humanity, their own feelings, the treatment they undergo in the hospital, and the current changes from the pandemic. In this way, through the ‘Almanaque das Emoções’ tool, we seek to collect subjective material of children and adolescents during the context of the pandemic in hospitalization, favoring the recognition and management of children’s emotions. The analysis of the material, through the psychoanalytic approach, has favored a greater proximity to the child’s subjectivity, enabling the reception.
DOI: 10.6084/m9.figshare.22187799.v1
title: Almanac of Emotions for children and adolescents in times of pandemic

description: ABSTRACT The pandemic context has brought health problems, that actualize, in the subjectivity of children and adolescents in a situation of illness, a suffering that is difficult to address, but that needs to be expressed and elaborated, in favor of the flow of treatment. The Almanac of Emotions emerged from the concern of two psychologists to offer their patients – in a pediatric ward of a Hematological Center in the State of Rio de Janeiro – means of access to the symbolic expression. The desired objective was to give space for expression to the affections that children and adolescents bring to the context of treatment. Through free symbolic manifestations, we believe it is possible to represent what is happening in the subjectivity of these subjects, in relation to the following themes: pandemic, life, world, humanity, their own feelings, the treatment they undergo in the hospital, and the current changes from the pandemic. In this way, through the ‘Almanaque das Emoções’ tool, we seek to collect subjective material of children and adolescents during the context of the pandemic in hospitalization, favoring the recognition and management of children’s emotions. The analysis of the material, through the psychoanalytic approach, has favored a greater proximity to the child’s subjectivity, enabling the reception.
DOI: 10.6084/m9.figshare.22187802
title: Goat and sheep dairy productions in Goiás and Distrito Federal: an analysis of the competitiveness drivers

description: Abstract: The production and processing of small ruminants' milk are alternative economic activities for small rural entrepreneurs and are expanding in Brazil. This article aims to identify the current situation of the goat and sheep dairy value chains in Goiás and Distrito Federal and analyze the competitiveness of these value chains, through a comparison of their competitiveness drivers with those of other Brazilian regions, where these chains are more structured. Therefore, a questionnaire was applied with 9 key agents of these chains, within the study region, and 28 from other locations. Through the analysis of the results, the goat and sheep dairy value chains in Goiás and Distrito Federal were characterized as competitive at the time of the study. However, the "firm's management", "technology and innovation", and "quality" drivers were advertised as probable limitations that need to be improved so that these chains remain competitive.
DOI: 10.6084/m9.figshare.22187802.v1
title: Goat and sheep dairy productions in Goiás and Distrito Federal: an analysis of the competitiveness drivers

description: Abstract: The production and processing of small ruminants' milk are alternative economic activities for small rural entrepreneurs and are expanding in Brazil. This article aims to identify the current situation of the goat and sheep dairy value chains in Goiás and Distrito Federal and analyze the competitiveness of these value chains, through a comparison of their competitiveness drivers with those of other Brazilian regions, where these chains are more structured. Therefore, a questionnaire was applied with 9 key agents of these chains, within the study region, and 28 from other locations. Through the analysis of the results, the goat and sheep dairy value chains in Goiás and Distrito Federal were characterized as competitive at the time of the study. However, the "firm's management", "technology and innovation", and "quality" drivers were advertised as probable limitations that need to be improved so that these chains remain competitive.
DOI: 10.6084/m9.figshare.22187806
title: SAGE Score in Normotensive and Pre-Hypertensive Patients: A Proof of Concept

description: Abstract Background The SAGE score was developed to detect individuals at risk for increased pulse wave velocity (PWV). So far, studies have been focused on hypertensive patients. Objective To assess the ability of the score to detect non-hypertensive and pre-hypertensive patients at risk for increased PWV. Methods Retrospective cross-sectional study of analysis of central blood pressure data and calculation of the SAGE score of non-hypertensive and pre-hypertensive patients. Each score point was analyzed for sensitivity, specificity, positive and negative predictive values, using the cut-off point for positive diagnosis a PVW ≥ 10m/s, ≥9.08 m/s (75thpercentile) and ≥7.30 m/s (50thpercentile). A p&lt;0.05 was considered statistically significant. Results The sample was composed of 100 normotensive and pre-hypertensive individuals, with mean age of 52.64 ± 14.94 years and median PWV of 7.30 m/s (6.03 – 9.08). The SAGE score was correlated with age (r=0.938, p&lt;0.001), glycemia (r=0.366, p&lt;0.001) and glomerular filtration rate (r=-0.658, p&lt;0.001). The area under the ROC curve was 0.968 (p&lt;0.001) for PWV ≥ 10 m/s, 0.977 (p&lt;0.001) for PWV ≥ 9.08 m/s and 0.967 (p&lt;0.001) for PWV ≥ 7.30 m/s. The score 7 showed a specificity of 95.40% and sensitivity of 100% for PWV≥10 m/s. The cut-off point would be of five for a PWV≥9.08 m/s (sensitivity =96.00%, specificity = 94.70%), and two for a PWV ≥ 7.30 m/s. Conclusion The SAGE score could identify individuals at higher risk of arterial stiffness, using different PWV cutoff points. However, the development of a specific score for normotensive and pre-hypertensive subjects is needed.
DOI: 10.6084/m9.figshare.22187806.v1
title: SAGE Score in Normotensive and Pre-Hypertensive Patients: A Proof of Concept

description: Abstract Background The SAGE score was developed to detect individuals at risk for increased pulse wave velocity (PWV). So far, studies have been focused on hypertensive patients. Objective To assess the ability of the score to detect non-hypertensive and pre-hypertensive patients at risk for increased PWV. Methods Retrospective cross-sectional study of analysis of central blood pressure data and calculation of the SAGE score of non-hypertensive and pre-hypertensive patients. Each score point was analyzed for sensitivity, specificity, positive and negative predictive values, using the cut-off point for positive diagnosis a PVW ≥ 10m/s, ≥9.08 m/s (75thpercentile) and ≥7.30 m/s (50thpercentile). A p&lt;0.05 was considered statistically significant. Results The sample was composed of 100 normotensive and pre-hypertensive individuals, with mean age of 52.64 ± 14.94 years and median PWV of 7.30 m/s (6.03 – 9.08). The SAGE score was correlated with age (r=0.938, p&lt;0.001), glycemia (r=0.366, p&lt;0.001) and glomerular filtration rate (r=-0.658, p&lt;0.001). The area under the ROC curve was 0.968 (p&lt;0.001) for PWV ≥ 10 m/s, 0.977 (p&lt;0.001) for PWV ≥ 9.08 m/s and 0.967 (p&lt;0.001) for PWV ≥ 7.30 m/s. The score 7 showed a specificity of 95.40% and sensitivity of 100% for PWV≥10 m/s. The cut-off point would be of five for a PWV≥9.08 m/s (sensitivity =96.00%, specificity = 94.70%), and two for a PWV ≥ 7.30 m/s. Conclusion The SAGE score could identify individuals at higher risk of arterial stiffness, using different PWV cutoff points. However, the development of a specific score for normotensive and pre-hypertensive subjects is needed.
DOI: 10.6084/m9.figshare.22132466
title: Dimethyl acetamide and dimethyl sulfoxide associated at glucose and egg yolk for cryopreservation of Pseudoplatystoma corruscans semen

description: Abstract This study aimed to develop a protocol for the cryopreservation of Pseudoplatystoma corruscans semen. For this, mature males were hormonally induced with a single dose of carp pituitary extract (5 mg/kg body weight). Semen was collected and evaluated. Two cryoprotectants were tested to compose the diluents: dimethyl acetamide (DMA) and dimethyl sulfoxide (Me2SO), in two concentrations (8% and 10%), + 5.0% glucose + 10% egg yolk. The semen was diluted in a 1: 4 ratio (semen: extender), packed in 0.5 mL straws and frozen in a dry shipper container in liquid nitrogen vapors. After thawing, sperm kinetics, sperm morphology and DNA integrity of cryopreserved sperm were evaluated. Pseudoplatystoma corruscans males produced semen with sperm motility &gt; 80%. After thawing, all treatments provided semen with total sperm motility &gt; 40%, with no significant difference (P &lt; 0.05) between them, as well as between the other sperm kinetic parameters evaluated. The treatments with DMA provided a smaller fragmentation of the DNA of the gametes. Sperm malformations were identified in both fresh and cryopreserved semen, with a slight increase in these malformations being identified in sperm from thawed P. corruscans semen samples.
DOI: 10.6084/m9.figshare.22132466.v1
title: Dimethyl acetamide and dimethyl sulfoxide associated at glucose and egg yolk for cryopreservation of Pseudoplatystoma corruscans semen

description: Abstract This study aimed to develop a protocol for the cryopreservation of Pseudoplatystoma corruscans semen. For this, mature males were hormonally induced with a single dose of carp pituitary extract (5 mg/kg body weight). Semen was collected and evaluated. Two cryoprotectants were tested to compose the diluents: dimethyl acetamide (DMA) and dimethyl sulfoxide (Me2SO), in two concentrations (8% and 10%), + 5.0% glucose + 10% egg yolk. The semen was diluted in a 1: 4 ratio (semen: extender), packed in 0.5 mL straws and frozen in a dry shipper container in liquid nitrogen vapors. After thawing, sperm kinetics, sperm morphology and DNA integrity of cryopreserved sperm were evaluated. Pseudoplatystoma corruscans males produced semen with sperm motility &gt; 80%. After thawing, all treatments provided semen with total sperm motility &gt; 40%, with no significant difference (P &lt; 0.05) between them, as well as between the other sperm kinetic parameters evaluated. The treatments with DMA provided a smaller fragmentation of the DNA of the gametes. Sperm malformations were identified in both fresh and cryopreserved semen, with a slight increase in these malformations being identified in sperm from thawed P. corruscans semen samples.
DOI: 10.6084/m9.figshare.22187811
title: Use of the genogram and ecomap in the assessment of family relationships of children in situations of vulnerability and violence

description: ABSTRACT Domestic violence can be understood as a factor that generates illness in victimized children, impacting health and social development. This study sought to understand family relationships and the support network of families living in social vulnerability and violence, using genogram and ecomap instruments. This is a descriptive and exploratory research, with a qualitative approach, in which eight parents/caregivers of children assisted by non-governmental organizations were interviewd. To systematize the results, content analysis was used, and the GenoPro program was used to prepare the genograms and ecomaps. The results showed the composition of families, the support networks, attitudes, feelings, and emotions connected to family dynamics and the potential of relationships. Families showed relational weaknesses, aggravated by financial difficulties. At the same time, the support network, added to the potentials identified in the family dynamics represented an important resource for protection. It is concluded that the genogram and the ecomap are effective instruments for the identification and understanding of cases of violence and can serve as a tool in the development of social actions, in the promotion of family health, and in the strengthening of public policies, helping to guarantee the rights to life and health of the child.
DOI: 10.6084/m9.figshare.22187811.v1
title: Use of the genogram and ecomap in the assessment of family relationships of children in situations of vulnerability and violence

description: ABSTRACT Domestic violence can be understood as a factor that generates illness in victimized children, impacting health and social development. This study sought to understand family relationships and the support network of families living in social vulnerability and violence, using genogram and ecomap instruments. This is a descriptive and exploratory research, with a qualitative approach, in which eight parents/caregivers of children assisted by non-governmental organizations were interviewd. To systematize the results, content analysis was used, and the GenoPro program was used to prepare the genograms and ecomaps. The results showed the composition of families, the support networks, attitudes, feelings, and emotions connected to family dynamics and the potential of relationships. Families showed relational weaknesses, aggravated by financial difficulties. At the same time, the support network, added to the potentials identified in the family dynamics represented an important resource for protection. It is concluded that the genogram and the ecomap are effective instruments for the identification and understanding of cases of violence and can serve as a tool in the development of social actions, in the promotion of family health, and in the strengthening of public policies, helping to guarantee the rights to life and health of the child.
DOI: 10.6084/m9.figshare.22187812
title: Sociodemographic and pharmacoepidemiology profile of HIV infected children

description: ABSTRACT Antiretroviral therapy interferes with the replication of the HIV virus, stops the progression of infection, and prevents early mortality in infected children. This research investigated the sociodemographic profile and parameters related to the antiretroviral treatment of HIV positive children living in the state of Paraná. This is a descriptive observational and analytical study, carried out with secondary data from the year 2020, referring to children up to 12 years of age. The profile, prevalence, medicines in use, treatment abandonment, viral resistance, and viral suppression were investigated. A total of 148 children were identified, with a prevalence equal to 8.1/100,000 in Paraná. All infants had begun their treatment, but 17,2% abandoned it. Among children who remained on treatment, 9.8% did not achieve viral suppression and their viral loads commonly exceeded 1000 viral copies/mL. There was a predominance of drug regimens probably prescribed after treatment failures. The results indicate that Paraná presents good results in terms of rapid initiation of therapy and viral suppression in children. However, there is a considerable number of abandonments of therapy and therapeutic failures, indicating the need to strengthen the link between this population and health services.
DOI: 10.6084/m9.figshare.22187812.v1
title: Sociodemographic and pharmacoepidemiology profile of HIV infected children

description: ABSTRACT Antiretroviral therapy interferes with the replication of the HIV virus, stops the progression of infection, and prevents early mortality in infected children. This research investigated the sociodemographic profile and parameters related to the antiretroviral treatment of HIV positive children living in the state of Paraná. This is a descriptive observational and analytical study, carried out with secondary data from the year 2020, referring to children up to 12 years of age. The profile, prevalence, medicines in use, treatment abandonment, viral resistance, and viral suppression were investigated. A total of 148 children were identified, with a prevalence equal to 8.1/100,000 in Paraná. All infants had begun their treatment, but 17,2% abandoned it. Among children who remained on treatment, 9.8% did not achieve viral suppression and their viral loads commonly exceeded 1000 viral copies/mL. There was a predominance of drug regimens probably prescribed after treatment failures. The results indicate that Paraná presents good results in terms of rapid initiation of therapy and viral suppression in children. However, there is a considerable number of abandonments of therapy and therapeutic failures, indicating the need to strengthen the link between this population and health services.
DOI: 10.6084/m9.figshare.22187815
title: The Child’s Handbook and occupational therapy in Primary Health Care

description: ABSTRACT The Child Handbook (CH) is an essential instrument for monitoring child development, a theme present in the curricula of Occupational Therapy (OT) courses, a profession that has childhood as an important area of activity. However, few studies describe the profession’s actions in primary care for children’s health. This research aims to describe and analyze the actions and activities of OT students participating in the ‘Projeto Multicampi Saúde da Criança’ with mothers and children, based on the CH in the context of primary care. It is a quantitative, descriptive, and retrospective study, with data extracted from 37 field diaries. The most common actions were developmental surveillance consultations (27.4%), guidance (23.6%), health education, and home visits (12.3% each). Mapping of services, the School Health Program, therapeutic groups, matrix support, and team meetings appear to be less expressive. The data corroborate research that describes actions developed by occupational therapists in primary care and indicate that the CH provided an important range of actions in this context. It is also observed the importance of the occupational therapist in the multiprofessional team of attention to children’s health and the relevance of the ‘Projeto Multicampi Saúde da Criança’ in the formative path of the student.