cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.5281/zenodo.7360759
title: Tailoring the optical and dynamic properties of iminothioindoxyl photoswitches through acidochromism

description: Multi-responsive functional molecules are key for obtaining user-defined control of the properties and functions of chemical and biological systems. In this respect, pH-responsive photochromes, whose switching can be directed with light and acid–base equilibria, have emerged as highly attractive molecular units. The challenge in their design comes from the need to accommodate application-defined boundary conditions for both light- and protonation-responsivity. Here we combine time-resolved spectroscopic studies, on time scales ranging from femtoseconds to seconds, with density functional theory (DFT) calculations to elucidate and apply the acidochromism of a recently designed iminothioindoxyl (ITI) photoswitch. We show that protonation of the thermally stable <em>Z</em> isomer leads to a strong batochromically-shifted absorption band, allowing for fast isomerization to the metastable <em>E</em> isomer with light in the 500–600 nm region. Theoretical studies of the reaction mechanism reveal the crucial role of the acid–base equilibrium which controls the populations of the protonated and neutral forms of the <em>E</em> isomer. Since the former is thermally stable, while the latter re-isomerizes on a millisecond time scale, we are able to modulate the half-life of ITIs over three orders of magnitude by shifting this equilibrium. Finally, stable bidirectional switching of protonated ITI with green and red light is demonstrated with a half-life in the range of tens of seconds. Altogether, we designed a new type of multi-responsive molecular switch in which protonation red-shifts the activation wavelength by over 100 nm and enables efficient tuning of the half-life in the millisecond–second range. Article information: https://doi.org/10.1039/D0SC07000A
DOI: 10.5281/zenodo.7360758
title: Tailoring the optical and dynamic properties of iminothioindoxyl photoswitches through acidochromism

description: Multi-responsive functional molecules are key for obtaining user-defined control of the properties and functions of chemical and biological systems. In this respect, pH-responsive photochromes, whose switching can be directed with light and acid–base equilibria, have emerged as highly attractive molecular units. The challenge in their design comes from the need to accommodate application-defined boundary conditions for both light- and protonation-responsivity. Here we combine time-resolved spectroscopic studies, on time scales ranging from femtoseconds to seconds, with density functional theory (DFT) calculations to elucidate and apply the acidochromism of a recently designed iminothioindoxyl (ITI) photoswitch. We show that protonation of the thermally stable <em>Z</em> isomer leads to a strong batochromically-shifted absorption band, allowing for fast isomerization to the metastable <em>E</em> isomer with light in the 500–600 nm region. Theoretical studies of the reaction mechanism reveal the crucial role of the acid–base equilibrium which controls the populations of the protonated and neutral forms of the <em>E</em> isomer. Since the former is thermally stable, while the latter re-isomerizes on a millisecond time scale, we are able to modulate the half-life of ITIs over three orders of magnitude by shifting this equilibrium. Finally, stable bidirectional switching of protonated ITI with green and red light is demonstrated with a half-life in the range of tens of seconds. Altogether, we designed a new type of multi-responsive molecular switch in which protonation red-shifts the activation wavelength by over 100 nm and enables efficient tuning of the half-life in the millisecond–second range. Article information: https://doi.org/10.1039/D0SC07000A
DOI: 10.5517/ccdc.csd.cc22fkbf
title: CCDC 1919654: Experimental Crystal Structure Determination

description: Related Article: Jian-Hua Zhang, Hai-Ping Wang, Lu-Yin Zhang, Shi-Chao Wei, Zhang-Wen Wei, Mei Pan, Cheng-Yong Su|2020|Chemical Science|11|8885|doi:10.1039/D0SC03290E
description: Related Article: Jian-Hua Zhang, Hai-Ping Wang, Lu-Yin Zhang, Shi-Chao Wei, Zhang-Wen Wei, Mei Pan, Cheng-Yong Su|2020|CSD Communication|||
description: An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
DOI: 10.5517/ccdc.csd.cc25r1vv
title: CCDC 2018157: Experimental Crystal Structure Determination

description: Related Article: Song Dongdong|2020|CSD Communication|||
description: An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
DOI: 10.5517/ccdc.csd.cc24dn9j
title: CCDC 1978367: Experimental Crystal Structure Determination

description: Related Article: Miao-Miao Li|2020|CSD Communication|||
description: Related Article: Miao-Miao Li, Qin Xiong, Bao-Le Qu, Yu-Qing Xiao, Yu Lan, Liang-Qiu Lu, Wen-Jing Xiao|2020|Angew.Chem.,Int.Ed.|59|17429|doi:10.1002/anie.202006366
description: An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
DOI: 10.5517/ccdc.csd.cc25kpdv
title: CCDC 2012997: Experimental Crystal Structure Determination

description: Related Article: Hicham EL Hamdani, Mohamed EL-Amane, Mohamed Saadi, Lahcen El Ammari|2021|J.Mol.Struct.|1229|129835|doi:10.1016/j.molstruc.2020.129835
description: Related Article: Hicham EL Hamdani, Mohamed EL-Amane, Mohamed Saadi, Lahcen El Ammari|2020|CSD Communication|||
description: An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
DOI: 10.5517/ccdc.csd.cc26ghw2
title: CCDC 2039734: Experimental Crystal Structure Determination

description: Related Article: Mengjia Liu|2020|CSD Communication|||
description: Related Article: Mengjia Liu, Ying He, Chuan Shan, Lukasz Wojtas, Ion Ghiviriga, Omar Fathalla, Yu Yan, Xiaopeng Li, Xiaodong Shi|2021|Chemical Science|12|7569|doi:10.1039/D1SC00988E
description: An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
DOI: 10.5517/ccdc.csd.cc26lqbw
title: CCDC 2043778: Experimental Crystal Structure Determination

description: Related Article: Khaireddine Ezzayani, Christian Philouze, Habib Nasri|2020|CSD Communication|||
description: An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
DOI: 10.5517/ccdc.csd.cc26l9mr
title: CCDC 2043384: Experimental Crystal Structure Determination

description: Related Article: El-Mahdi Ourhzif, El Mostafa Ketatni, Mohamed Akssira, Yves Troin, Mostafa Khouili|2020|CSD Communication|||
description: Related Article: El-Mahdi Ourhzif, El Mostafa Ketatni, Mohamed Akssira, Yves Troin, Mostafa Khouili|2021|J.Mol.Struct.|1241|130511|doi:10.1016/j.molstruc.2021.130511
description: An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
DOI: 10.5517/ccdc.csd.cc26wrb6
title: CCDC 2052458: Experimental Crystal Structure Determination

description: Related Article: Fan Yin|2020|CSD Communication|||
description: Related Article: Fan Yin, Jianbo De, Han Huang, Yuan Li, Meihui Liu, Shuai Li, Chunling Gu, Jiannian Yao, Qing Liao, Hongbing Fu|2022|J.Mater.Chem.C|10|4166|doi:10.1039/D1TC05280B
description: An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
DOI: 10.5517/ccdc.csd.cc2c1z7n
title: CCDC 2176641: Experimental Crystal Structure Determination

description: Related Article: Akachukwu D. Obi, Lucas A. Freeman, Samuel J. Coates, Andrew J. H. Alexis, Nathan C. Frey, Diane A. Dickie, Charles Edwin Webster, Robert J. Gilliard, Jr.|2022|Organometallics|41|3064|doi:10.1021/acs.organomet.2c00464
description: An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
DOI: 10.5517/ccdc.csd.cc2c1z8p
title: CCDC 2176642: Experimental Crystal Structure Determination

description: Related Article: Akachukwu D. Obi, Lucas A. Freeman, Samuel J. Coates, Andrew J. H. Alexis, Nathan C. Frey, Diane A. Dickie, Charles Edwin Webster, Robert J. Gilliard, Jr.|2022|Organometallics|41|3064|doi:10.1021/acs.organomet.2c00464
description: An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
DOI: 10.5517/ccdc.csd.cc2c1z9q
title: CCDC 2176643: Experimental Crystal Structure Determination

description: Related Article: Akachukwu D. Obi, Lucas A. Freeman, Samuel J. Coates, Andrew J. H. Alexis, Nathan C. Frey, Diane A. Dickie, Charles Edwin Webster, Robert J. Gilliard, Jr.|2022|Organometallics|41|3064|doi:10.1021/acs.organomet.2c00464
description: An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
DOI: 10.5517/ccdc.csd.cc2c1zbr
title: CCDC 2176644: Experimental Crystal Structure Determination

description: Related Article: Akachukwu D. Obi, Lucas A. Freeman, Samuel J. Coates, Andrew J. H. Alexis, Nathan C. Frey, Diane A. Dickie, Charles Edwin Webster, Robert J. Gilliard, Jr.|2022|Organometallics|41|3064|doi:10.1021/acs.organomet.2c00464
description: An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
DOI: 10.5517/ccdc.csd.cc2c27mb
title: CCDC 2176901: Experimental Crystal Structure Determination

description: Related Article: Timur O. Zanakhov, Ekaterina E. Galenko, Mikhail S. Novikov, Alexander F. Khlebnikov|2022|J.Org.Chem.|87|15598|doi:10.1021/acs.joc.2c02177
description: An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
DOI: 10.5281/zenodo.7371984
title: [IO Islamic 2808] قصّۀ بهرامگور و بانوى حسن

description: <strong>Ḳiṣṣ-i-Bahrâmgûr u Bânui-Ḥasan.</strong> <strong>This manuscript is now IO Islamic 851 in the India Office collections.</strong> <strong>[metadata:</strong> <strong>Hermann Ethé</strong><strong><em>, </em></strong><strong><em>Catalogue of Persian Manuscripts in the Library of the India Office,</em></strong> <strong>2 vols. (Oxford: India Office, 1903): volume 1,</strong> <strong>number 2808 here with notations and hyperlinks].</strong> 851 The same. A much shorter version of the same story, beginning: راويان اخبار و ناقلان آثار و طوطيان شكر شكن شيرين گفتار چنين روایت كرده اند كه در زمان قديم در شهر فارس الخ. Dated the 9th of Ramaḍân, A.H. 1184 (A.D. 1770, December 27). Bibliotheca Leydeniana. No. 2808, ff. 72-93, ll. 13; Nasta’lîḳ, mixed occasionally with Shikasta; size, 8<sup>3/8</sup> in. by 6<sup>3/4</sup> in.
DOI: 10.5281/zenodo.7371983
title: [IO Islamic 2808] قصّۀ بهرامگور و بانوى حسن

description: <strong>Ḳiṣṣ-i-Bahrâmgûr u Bânui-Ḥasan.</strong> <strong>This manuscript is now IO Islamic 851 in the India Office collections.</strong> <strong>[metadata:</strong> <strong>Hermann Ethé</strong><strong><em>, </em></strong><strong><em>Catalogue of Persian Manuscripts in the Library of the India Office,</em></strong> <strong>2 vols. (Oxford: India Office, 1903): volume 1,</strong> <strong>number 2808 here with notations and hyperlinks].</strong> 851 The same. A much shorter version of the same story, beginning: راويان اخبار و ناقلان آثار و طوطيان شكر شكن شيرين گفتار چنين روایت كرده اند كه در زمان قديم در شهر فارس الخ. Dated the 9th of Ramaḍân, A.H. 1184 (A.D. 1770, December 27). Bibliotheca Leydeniana. No. 2808, ff. 72-93, ll. 13; Nasta’lîḳ, mixed occasionally with Shikasta; size, 8<sup>3/8</sup> in. by 6<sup>3/4</sup> in.
DOI: 10.34740/kaggle/dsv/4607524
title: YouTube Trending Video Dataset (updated daily)
DOI: 10.5281/zenodo.7372014
title: [IO Islamic 1627] Persian Story

description: <strong>Persian Story.</strong> <strong>This manuscript is now IO Islamic 853 in the India Office collections.</strong> <strong>[metadata:</strong> <strong>Hermann Ethé</strong><strong><em>, </em></strong><strong><em>Catalogue of Persian Manuscripts in the Library of the India Office,</em></strong> <strong>2 vols. (Oxford: India Office, 1903): volume 1,</strong> <strong>number 1627 here with notations and hyperlinks].</strong> 853 The story of the king and the seven viziers, who, under penalty of death, are ordered to state the hidden meaning of certain trees with miraculous fruit, beginning: حكايت آورده اند كه در شهرى درختان را ميوۀ بر آمده آنرا از جامه كرپاس پوشيده و از درون آن روشنائى ميدرخشيد روزى (پادشاه or سلطان add ) زير درختان آمده احوال آن پرسيد وزرا گفتند كه معلوم نيست الخ. No. 1627, ff. 106<sup>b</sup>-112<sup>b</sup>, ll. 13-14; careless Nasta’lîḳ; the last leaf written by another hand in Naskhî, ll. 23; size, 9 in. by 4<sup>7/8</sup> in.
DOI: 10.5281/zenodo.7372013
title: [IO Islamic 1627] Persian Story

description: <strong>Persian Story.</strong> <strong>This manuscript is now IO Islamic 853 in the India Office collections.</strong> <strong>[metadata:</strong> <strong>Hermann Ethé</strong><strong><em>, </em></strong><strong><em>Catalogue of Persian Manuscripts in the Library of the India Office,</em></strong> <strong>2 vols. (Oxford: India Office, 1903): volume 1,</strong> <strong>number 1627 here with notations and hyperlinks].</strong> 853 The story of the king and the seven viziers, who, under penalty of death, are ordered to state the hidden meaning of certain trees with miraculous fruit, beginning: حكايت آورده اند كه در شهرى درختان را ميوۀ بر آمده آنرا از جامه كرپاس پوشيده و از درون آن روشنائى ميدرخشيد روزى (پادشاه or سلطان add ) زير درختان آمده احوال آن پرسيد وزرا گفتند كه معلوم نيست الخ. No. 1627, ff. 106<sup>b</sup>-112<sup>b</sup>, ll. 13-14; careless Nasta’lîḳ; the last leaf written by another hand in Naskhî, ll. 23; size, 9 in. by 4<sup>7/8</sup> in.
DOI: 10.5281/zenodo.7372026
title: [IO Islamic 1255] Solomon and the Griffin

description: <strong>Solomon and the Griffin.</strong> <strong>This manuscript is now IO Islamic 854 in the India Office collections.</strong> <strong>[metadata:</strong> <strong>Hermann Ethé</strong><strong><em>, </em></strong><strong><em>Catalogue of Persian Manuscripts in the Library of the India Office,</em></strong> <strong>2 vols. (Oxford: India Office, 1903): volume 1,</strong> <strong>number 1255 here with notations and hyperlinks].</strong> 854 The story of Solomon and the Griffin, a Persian romance in prose, by an anonymous author, beginning: الحمد لله ربّ العالمين الخ بدانكه در خبر آمده است كه روزى سليمان عليه السّلام شبى بمسند بار داده نشسته بودند الخ. Numerous illustration, almost on every page. No date. No. 1255, ff. 26, ll. 19; large and distinct Nasta’lîḳ; size, 18<sup>1/4</sup> in. by 10<sup>1/4</sup> in.
DOI: 10.5281/zenodo.7372025
title: [IO Islamic 1255] Solomon and the Griffin

description: <strong>Solomon and the Griffin.</strong> <strong>This manuscript is now IO Islamic 854 in the India Office collections.</strong> <strong>[metadata:</strong> <strong>Hermann Ethé</strong><strong><em>, </em></strong><strong><em>Catalogue of Persian Manuscripts in the Library of the India Office,</em></strong> <strong>2 vols. (Oxford: India Office, 1903): volume 1,</strong> <strong>number 1255 here with notations and hyperlinks].</strong> 854 The story of Solomon and the Griffin, a Persian romance in prose, by an anonymous author, beginning: الحمد لله ربّ العالمين الخ بدانكه در خبر آمده است كه روزى سليمان عليه السّلام شبى بمسند بار داده نشسته بودند الخ. Numerous illustration, almost on every page. No date. No. 1255, ff. 26, ll. 19; large and distinct Nasta’lîḳ; size, 18<sup>1/4</sup> in. by 10<sup>1/4</sup> in.
DOI: 10.5281/zenodo.7372036
title: [IO Islamic 1369] قصّۀ پرورتى و نرورتى

description: <strong>Ḳiṣṣ-i-Parwartî u Narwartî.</strong> <strong>This manuscript is now IO Islamic 855 in the India Office collections.</strong> <strong>[metadata:</strong> <strong>Hermann Ethé</strong><strong><em>, </em></strong><strong><em>Catalogue of Persian Manuscripts in the Library of the India Office,</em></strong> <strong>2 vols. (Oxford: India Office, 1903): volume 1,</strong> <strong>number 1369 here with notations and hyperlinks].</strong> 855 Ḳiṣṣ-i-Parwartî u Narwartî ( قصّۀ پرورتى و نرورتى). The story of Narwartî and Parwartî, a Persian romance by Lâla Ranjît, beginning: خداوندا اساس كاخ تكوين و ايجاد بطرحى كه صورت ظهور يافته الخ. No date. Purchased at Ḥaidarâbâd. No. 1369, ff. 42, ll. 19; Shikasta; size, 8<sup>1/4</sup> in. by 6 in.
DOI: 10.5281/zenodo.7372035
title: [IO Islamic 1369] قصّۀ پرورتى و نرورتى

description: <strong>Ḳiṣṣ-i-Parwartî u Narwartî.</strong> <strong>This manuscript is now IO Islamic 855 in the India Office collections.</strong> <strong>[metadata:</strong> <strong>Hermann Ethé</strong><strong><em>, </em></strong><strong><em>Catalogue of Persian Manuscripts in the Library of the India Office,</em></strong> <strong>2 vols. (Oxford: India Office, 1903): volume 1,</strong> <strong>number 1369 here with notations and hyperlinks].</strong> 855 Ḳiṣṣ-i-Parwartî u Narwartî ( قصّۀ پرورتى و نرورتى). The story of Narwartî and Parwartî, a Persian romance by Lâla Ranjît, beginning: خداوندا اساس كاخ تكوين و ايجاد بطرحى كه صورت ظهور يافته الخ. No date. Purchased at Ḥaidarâbâd. No. 1369, ff. 42, ll. 19; Shikasta; size, 8<sup>1/4</sup> in. by 6 in.
DOI: 10.34740/kaggle/dsv/4607562
title: 2021 World Population (updated daily)
DOI: 10.22008/fk2/fliclc/ncsjus
title: CARRA_tp_rf_t2m_at_Zackenberg.csv

description: :unav
DOI: 10.5281/zenodo.7360135
title: Data of: Cross-sectional survey on Germans' awareness for refugees' information barriers

description: The present dataset is the result of a cross-sectional online survey, which had been conducted to examine selected predictors of Germans' problem awareness in the form of perceived information barriers that refugees face, placing an emphasis on the role of positive intercultural contact experiences. The survey content is based on an extended version of the Empathy-Attitude-Action model and was carried out with a sample of Germans. The dataset is in xlsx-format and the variable-descriptions can be found in the headings of the spreadsheet.
DOI: 10.6084/m9.figshare.21629999
title: Molecular subtype and metastasis in MBC

description: Molecular subtype and metastasis in MBC
DOI: 10.6084/m9.figshare.21629999.v1
title: Molecular subtype and metastasis in MBC

description: Molecular subtype and metastasis in MBC
DOI: 10.6084/m9.figshare.19778941.v1
title: Table S11. Source data table.

description: Source data table containing raw data.
DOI: 10.6084/m9.figshare.19778938.v1
title: Table S10. Identifiers of all proteins quantified in SomaScan.

description: Identifiers of all proteins quantified in SomaScan.
DOI: 10.6084/m9.figshare.19778911.v1
title: Table S5. 205 proteins significantly differentially expressed between MCI converters and non-converters.

description: Wilcoxon rank-sum test with false discovery rate (FDR) multiple correction was performed to compare single protein expression level between MCI converters and non-converters. UniProt ID, beta-coefficients, p-values, and FDR-corrected p-values are shown.
DOI: 10.6084/m9.figshare.19778941.v2
title: Supplementary Table 2. Source data table.

description: Source data table containing raw data.
DOI: 10.6084/m9.figshare.19778938
title: Supplementary Table 3. Identifiers of all proteins quantified in SomaScan.

description: Identifiers of all proteins quantified in SomaScan.
DOI: 10.6084/m9.figshare.19778938.v3
title: Supplementary Table 3. Identifiers of all proteins quantified in SomaScan.

description: Identifiers of all proteins quantified in SomaScan.
DOI: 10.6084/m9.figshare.19778911
title: Supplementary Table 8. 205 proteins significantly differentially expressed between MCI converters and non-converters.

description: Wilcoxon rank-sum test with false discovery rate (FDR) multiple correction was performed to compare single protein expression level between MCI converters and non-converters. UniProt ID, beta-coefficients, p-values, and FDR-corrected p-values are shown.
DOI: 10.6084/m9.figshare.19778911.v3
title: Supplementary Table 8. 205 proteins significantly differentially expressed between MCI converters and non-converters.

description: Wilcoxon rank-sum test with false discovery rate (FDR) multiple correction was performed to compare single protein expression level between MCI converters and non-converters. UniProt ID, beta-coefficients, p-values, and FDR-corrected p-values are shown.
DOI: 10.6084/m9.figshare.19778911.v2
title: Supplementary Table 8. 205 proteins significantly differentially expressed between MCI converters and non-converters.

description: Wilcoxon rank-sum test with false discovery rate (FDR) multiple correction was performed to compare single protein expression level between MCI converters and non-converters. UniProt ID, beta-coefficients, p-values, and FDR-corrected p-values are shown.