DOI: 10.5061/dryad.wm37pvn09
title: Data from: Compatibilization of immiscible polymer blends through pendant ionic interactions

description: This dataset accompanies the article "Compatibilization of Immiscible
 Polymer Blends through Pendant Ionic Interactions" by Jerrick Edmund,
 Kseniia M. Karnaukh, Shuyi Xie, Elizabeth A. Murphy, Allison Abdilla, Eiko
 Ino, Javier Read de Alaniz, Craig J. Hawker, and Rachel A. Segalman. The
 article demonstrates the compatibilization of immiscible
 poly(dimethylsiloxane) and poly(n-butyl acrylate) mixtures through the
 introduction of sparse pendant ionic interactions, and probes the effect
 of charge density on the physical properties of the compatibilized blends.
 This dataset contains the necessary experimental data to reproduce all the
 figures in the main text and supporting information. Small angle X-ray
 scattering patterns, small-amplitude oscillatory shear rheological curves,
 nuclear magnetic resonance spectra, size-exclusion chromatograms,
 Fourier-transform infrared spectra, and differential scanning thermograms
 are included.
description: This README.txt file was generated on 2025-05-27 by JERRICK EDMUND GENERAL
 INFORMATION 1. Title of Dataset: Compatibilization of Immiscible Polymer
 Blends through Pendant Ionic Interactions 2. Author Information A.
 Principal Investigator Contact Information Name: Rachel A. Segalman
 Institution: University of California, Santa Barbara Address: Materials
 Research Laboratory, University of California, Santa Barbara, 93106 Email:
 [segalman@ucsb.edu](mailto:segalman@ucsb.edu) B. Principal Investigator
 Contact Information Name: Craig J. Hawker Institution: University of
 California, Santa Barbara Address: Materials Research Laboratory,
 University of California, Santa Barbara, 93106 Email:
 [hawker@mrl.ucsb.edu](mailto:segalman@ucsb.edu) C. Associate or
 Co-investigator Contact Information Name: Jerrick Edmund Institution:
 University of California, Santa Barbara Address: Department of Chemical
 Engineering, University of California, Santa Barbara, 93106 Email:
 [jedmund@ucsb.edu](mailto:jedmund@ucsb.edu) D. Associate or
 Co-investigator Contact Information Name: Kseniia M. Karnaukh Institution:
 University of California, Santa Barbara Address: Department of Chemistry
 and Biochemistry, University of California, Santa Barbara, 93106 Email:
 [kkarnaukh@ucsb.edu](mailto:kkarnaukh@ucsb.edu) E. Associate or
 Co-investigator Contact Information Name: Shuyi Xie Institution:
 University of California, Santa Barbara Address: Materials Research
 Laboratory, University of California, Santa Barbara, 93106 Email:
 [shuyixie@ucsb.edu](mailto:shuyixie@ucsb.edu) F. Associate or
 Co-investigator Contact Information Name: Elizabeth A. Murphy Institution:
 University of California, Santa Barbara Address: Department of Chemistry
 and Biochemistry, University of California, Santa Barbara, 93106 Email:
 [emurphy@ucsb.edu](mailto:emurphy@ucsb.edu) G. Associate or
 Co-investigator Contact Information Name: Allison Abdilla Institution:
 University of California, Santa Barbara Address: Department of Chemistry
 and Biochemistry, University of California, Santa Barbara, 93106 Email:
 [aabdilla@chem.ucsb.edu](mailto:aabdilla@chem.ucsb.edu) H. Associate or
 Co-investigator Contact Information Name: Eiko Ino Institution: University
 of California, Santa Barbara Address: Materials Research Laboratory,
 University of California, Santa Barbara, 93106 Email:
 [eiko_ino@ucsb.edu](mailto:eiko_ino@ucsb.edu) I. Associate or
 Co-investigator Contact Information Name: Javier Read de Alaniz
 Institution: University of California, Santa Barbara Address: Department
 of Chemistry and Biochemistry, University of California, Santa Barbara,
 93106 Email: [jalaniz@ucsb.edu](mailto:jalaniz@ucsb.edu) 3. Date of data
 collection (single date, range, approximate date) 2023-01-01 to 2024-08-01
 4. Geographic location of data collection: Santa Barbara, CA 5.
 Information about funding sources that supported the collection of the
 data: This work was supported by the National Science Foundation through
 the Materials Research Science and Engineering Center (MRSEC) at UC Santa
 Barbara: NSF DMR–2308708 (IRG-1). The research reported here made use of
 the shared facilities of the Materials Research Science and Engineering
 Center (MRSEC) at UC Santa Barbara: NSF DMR–2308708. The UC Santa Barbara
 MRSEC is a member of the Materials Research Facilities Network
 ([www.mrfn.org](http://www.mrfn.org)). This work made use of facilities
 supported by an NSF Major Research Instrumentation award, MRI-1920299, for
 magnetic resonance instrumentation; and BioPACIFIC Materials Innovation
 Platform of the National Science Foundation under award No. DMR-1933487,
 for X-ray scattering instrumentation. SHARING/ACCESS INFORMATION 1.
 Licenses/restrictions placed on the data: N/A 2. Links to publications
 that cite or use the data: 3. Links to other publicly accessible locations
 of the data: N/A 4. Links/relationships to ancillary data sets: N/A 5. Was
 data derived from another source? No 6. Recommended citation for this
 dataset: DATA & FILE OVERVIEW 1. File List: Files are organized into
 folders based on figure/table number from the corresponding manuscript and
 supporting information. Files are named as
 "Figure#_SampleID.csv" A. Figure3: Small angle X-ray scattering
 patterns of (a) 1.0 mol% blend, and (b) 6.5 mol% blend at room
 temperature. a. Figure3a_1molblend.csv 1\. Variables: Scattering
 Wavevector [A-1], Intensity [arb. units] 2\. Column names: q (A-1), I
 (arb. units) b. Figure3b_6halfmolblend.csv 1\. Variables: Scattering
 Wavevector [A-1], Intensity [arb. units] 2\. Column names: q (A-1), I
 (arb. units) B. Figure4: Small angle X-ray scattering patterns of (a) 1.0
 mol% blend at room temperature (RT), 150 C, and room temperature upon
 cooling; and (b) domain sizes of 1.0 mol% blend as a function of
 temperature. a. Figure4a_1molblendVT.csv 1\. Variables: Scattering
 Wavevector [A-1], Intensity [arb. units] 2\. Column names: q_RT (A-1),
 I_RT (arb. units), q_150C (A-1), I_150C (arb. units), q_RT_cool (A-1),
 I_RT_cool (arb. units) b. Figure4b_1molblendVTdomain.csv 1\. Variables:
 Temperature [°C], Primary Peak Wavevector [A-1], Domain Size [nm] 2\.
 Column names: T (°C), q* (A–1), d (nm) C. Figure5: Small-amplitude
 oscillatory shear rheological master curves of (a) 1.0 mol% blend and its
 parent polymers, and (b) 6.5 mol% blend and its parent polymers
 constructed by time-temperature superposition, and corresponding shift
 factors for (c) 1.0 mol% blend and its parent polymers, and (d) 6.5 mol%
 blend and its parent polymers. a. Figure5a_1molmastercurves.csv 1\.
 Variables: Reduced Frequency [rad/s], Storage Modulus [Pa], Loss Modulus
 [Pa] 2\. Column names: waT_PnBA_SO3H (rad/s), G'_PnBA_SO3H (Pa),
 G''_PnBA_SO3H (Pa), waT_PDMS_Im (rad/s), G'_PDMS_Im (Pa),
 G''_PDMS_Im (Pa), waT_Blend (rad/s), G'_Blend (Pa),
 G''_Blend (Pa) b. Figure5b_6halfmastercurves.csv 1\. Variables:
 Reduced Frequency [rad/s], Storage Modulus [Pa], Loss Modulus [Pa] 2\.
 Column names: waT_PnBA_SO3H (rad/s), G'_PnBA_SO3H (Pa),
 G''_PnBA_SO3H (Pa), waT_PDMS_Im (rad/s), G'_PDMS_Im (Pa),
 G''_PDMS_Im (Pa), waT_Blend (rad/s), G'_Blend (Pa),
 G''_Blend (Pa) c. Figure5c_1molshiftfactors.csv 1\. Variables:
 Temperature – Reference Temperature [°C], Log(Shift Factor) [unitless] 2\.
 Column names: T-Tref_PnBA_SO3H (°C), log(aT)_PnBA_SO3H, T-Tref_PDMS_Im
 (°C), log(aT)_PDMS_Im, T-Tref_Blend (°C), log(aT)_Blend d.
 Figure5c_6halfmolshiftfactors.csv 1\. Variables: Temperature – Reference
 Temperature [°C], Log(Shift Factor) [unitless] 2\. Column names:
 T-Tref_PnBA_SO3H (°C), log(aT)_PnBA_SO3H, T-Tref_PDMS_Im (°C),
 log(aT)_PDMS_Im, T-Tref_Blend (°C), log(aT)_Blend D.
 FiguresS1-2,S4-8,S13-14,S16-21,S23-26,S28-31,S33,S37-40: Nuclear magnetic
 resonance (NMR) spectra of synthesized small molecules, polymers, and
 blends. a. FigureS1_PDMS1PVMS.csv 1\. Variables: Chemical Shift [ppm],
 Intensity [arb. units] 2\. Column names: Chemical Shift (ppm), Intensity
 (arb. units) b. FigureS2_PDMS7PVMS.csv 1\. Variables: Chemical Shift
 [ppm], Intensity [arb. units] 2\. Column names: Chemical Shift (ppm),
 Intensity (arb. units) c. FigureS4_ImCl.csv 1\. Variables: Chemical Shift
 [ppm], Intensity [arb. units] 2\. Column names: Chemical Shift (ppm),
 Intensity (arb. units) d. FigureS5_ImSH.csv 1\. Variables: Chemical Shift
 [ppm], Intensity [arb. units] 2\. Column names: Chemical Shift (ppm),
 Intensity (arb. units) e. FigureS6_PDMS1Im.csv 1\. Variables: Chemical
 Shift [ppm], Intensity [arb. units] 2\. Column names: Chemical Shift
 (ppm), Intensity (arb. units) f. FigureS7_PDMS6halfIm.csv 1\. Variables:
 Chemical Shift [ppm], Intensity [arb. units] 2\. Column names: Chemical
 Shift (ppm), Intensity (arb. units) g. FigureS8_PDMS6halfImCOSY.csv 1\.
 Variables: Chemical Shift [ppm], Intensity [arb. units] 2\. Column names:
 Row 1 and Column 1: Chemical Shift (ppm), Inner Rows and Columns:
 Intensity (arb. units) h. FigureS13_PnBATTC.csv 1\. Variables: Chemical
 Shift [ppm], Intensity [arb. units] 2\. Column names: Chemical Shift
 (ppm), Intensity (arb. units) i. FigureS14_PnBAH.csv 1\. Variables:
 Chemical Shift [ppm], Intensity [arb. units] 2\. Column names: Chemical
 Shift (ppm), Intensity (arb. units) j. FigureS16_Purified2CEAMaterial.csv
 1\. Variables: Chemical Shift [ppm], Intensity [arb. units] 2\. Column
 names: Chemical Shift (ppm), Intensity (arb. units) k.
 FigureS16_Starting2CEAMaterial.csv 1\. Variables: Chemical Shift [ppm],
 Intensity [arb. units] 2\. Column names: Chemical Shift (ppm), Intensity
 (arb. units) l. FigureS17_2CEA1HNMR.csv 1\. Variables: Chemical Shift
 [ppm], Intensity [arb. units] 2\. Column names: Chemical Shift (ppm),
 Intensity (arb. units) m. FigureS18_2CEA13CNMR.csv 1\. Variables: Chemical
 Shift [ppm], Intensity [arb. units] 2\. Column names: Chemical Shift
 (ppm), Intensity (arb. units) n. FigureS19_PnBA1halfCEATTC.csv 1\.
 Variables: Chemical Shift [ppm], Intensity [arb. units] 2\. Column names:
 Chemical Shift (ppm), Intensity (arb. units) o.
 FigureS20_PnBA1halfCEAH.csv 1\. Variables: Chemical Shift [ppm], Intensity
 [arb. units] 2\. Column names: Chemical Shift (ppm), Intensity (arb.
 units) p. FigureS21_PnBA1halfCEAHMethyl.csv 1\. Variables: Chemical Shift
 [ppm], Intensity [arb. units] 2\. Column names: Chemical Shift (ppm),
 Intensity (arb. units) q. FigureS23_PnBA1AMPSTTC.csv 1\. Variables:
 Chemical Shift [ppm], Intensity [arb. units] 2\. Column names: Chemical
 Shift (ppm), Intensity (arb. units) r. FigureS24_PnBA1AMPSH.csv 1\.
 Variables: Chemical Shift [ppm], Intensity [arb. units] 2\. Column names:
 Chemical Shift (ppm), Intensity (arb. units) s.
 FigureS25_PnBA1AMPSHDioxane.csv 1\. Variables: Chemical Shift [ppm],
 Intensity [arb. units] 2\. Column names: Chemical Shift (ppm), Intensity
 (arb. units) t. FigureS26_PnBA1AMPSHMethyl.csv 1\. Variables: Chemical
 Shift [ppm], Intensity [arb. units] 2\. Column names: Chemical Shift
 (ppm), Intensity (arb. units) u. FigureS28_PnBA1AMPSEtIm.csv 1\.
 Variables: Chemical Shift [ppm], Intensity [arb. units] 2\. Column names:
 Chemical Shift (ppm), Intensity (arb. units) v.
 FigureS29_PnBA6halfAMPSH.csv 1\. Variables: Chemical Shift [ppm],
 Intensity [arb. units] 2\. Column names: Chemical Shift (ppm), Intensity
 (arb. units) w. FigureS29_PnBA6halfAMPSTTC.csv 1\. Variables: Chemical
 Shift [ppm], Intensity [arb. units] 2\. Column names: Chemical Shift
 (ppm), Intensity (arb. units) x. FigureS30_PnBA6halfAMPSHDMSO.csv 1\.
 Variables: Chemical Shift [ppm], Intensity [arb. units] 2\. Column names:
 Chemical Shift (ppm), Intensity (arb. units) y.
 FigureS31_PnBA6halfAMPSHMethyl.csv 1\. Variables: Chemical Shift [ppm],
 Intensity [arb. units] 2\. Column names: Chemical Shift (ppm), Intensity
 (arb. units) z. FigureS33_PnBA6halfAMPSEtIm.csv 1\. Variables: Chemical
 Shift [ppm], Intensity [arb. units] 2\. Column names: Chemical Shift
 (ppm), Intensity (arb. units) aa. FigureS37_1Im1halfCEABlend.csv 1\.
 Variables: Chemical Shift [ppm], Intensity [arb. units] 2\. Column names:
 Chemical Shift (ppm), Intensity (arb. units) ab.
 FigureS38_1Im1AMPSBlend.csv 1\. Variables: Chemical Shift [ppm], Intensity
 [arb. units] 2\. Column names: Chemical Shift (ppm), Intensity (arb.
 units) ac. FigureS39_6halfblendsupernantant.csv 1\. Variables: Chemical
 Shift [ppm], Intensity [arb. units] 2\. Column names: Chemical Shift
 (ppm), Intensity (arb. units) ad. FigureS40_6halfblendLiTFSI.csv 1\.
 Variables: Chemical Shift [ppm], Intensity [arb. units] 2\. Column names:
 Chemical Shift (ppm), Intensity (arb. units) E.
 FiguresS3,S9,S15,S22,S27,S32: Size-exclusion chromatograms of synthesized
 polymers a. FigureS3_PDMSPVMS.csv 1\. Variables: Elution Time [min],
 Normalized Intensity [Unitless] 2\. Column names: Elution_Time_PDMS (min),
 Normalized_Intensity_PDMS, Elution_Time_PDMS_1PVMS (min),
 Normalized_Intensity_PDMS_1PVMS, Elution_Time_PDMS_7PVMS (min),
 Normalized_Intensity_PDMS_7PVMS b. FigureS9_PDMSIm.csv 1\. Variables:
 Elution Time [min], Normalized Intensity [Unitless], Intensity [arb.
 units] 2\. Column names: Elution_Time_PDMS_1Im (min),
 Normalized_Intensity_PDMS_1Im, Elution_Time_PDMS_6halfIm (min),
 Intensity_PDMS_6halfIm c. FigureS15_PnBA.csv 1\. Variables: Elution Time
 [min], Normalized Intensity [Unitless] 2\. Column names: Elution_Time_PnBA
 (min), Normalized_Intensity_PnBA d. FigureS22_PnBA1halfCEA.csv 1\.
 Variables: Elution Time [min], Normalized Intensity [Unitless] 2\. Column
 names: Elution_Time_PnBA_1halfCEA (min),
 Normalized_Intensity_PnBA_1halfCEA e. FigureS27_PnBA1AMPS.csv 1\.
 Variables: Elution Time [min], Normalized Intensity [Unitless] 2\. Column
 names: Elution_Time_PnBA_1AMPS (min), Normalized_Intensity_PnBA_1AMPS f.
 FigureS32_PnBA6halfAMPS.csv 1\. Variables: Elution Time [min], Normalized
 Intensity [Unitless] 2\. Column names: Elution_Time_PnBA_6halfAMPS (min),
 Normalized_Intensity_PnBA_6halfAMPS F. FiguresS10,S34,S41:
 Fourier-transform infrared spectra of synthesized polymers and blends a.
 FigureS10_PDMS.csv 1\. Variables: Wavenumber [cm–1], Normalized Absorbance
 [unitless] 2\. Column names: Wavenumber_PDMS (cm–1),
 Normalized_Absorbance_PDMS, Wavenumber_PDMS_1Im (cm–1),
 Normalized_Absorbance_PDMS_1Im, Wavenumber_PDMS_6halfIm (cm–1),
 Normalized_Absorbance_PDMS_6halfIm b. FigureS34_PnBA.csv 1\. Variables:
 Wavenumber [cm–1], Normalized Absorbance [unitless] 2\. Column names:
 Wavenumber_PnBA (cm–1), Normalized_Absorbance_PnBA,
 Wavenumber_PnBA_1halfCEA (cm–1), Normalized_Absorbance_PnBA_1halfCEA,
 Wavenumber_PnBA_1AMPS (cm–1), Normalized_Absorbance_PnBA_1AMPS,
 Wavenumber_PnBA_6halfAMPS (cm–1), Normalized_Absorbance_PnBA_6halfAMPS c.
 FigureS41a_COOHImBlend.csv 1\. Variables: Wavenumber [cm–1], Normalized
 Absorbance [unitless] 2\. Column names: Wavenumber_PnBA_1halfCEA (cm–1),
 Normalized_Absorbance_PnBA_1halfCEA, Wavenumber_PDMS_1Im (cm–1),
 Normalized_Absorbance_PDMS_1Im, Wavenumber_ImCOOH_Blend (cm–1),
 Normalized_Absorbance_ImCOOH_Blend d. FigureS41b_1SO3HImBlend.csv 1\.
 Variables: Wavenumber [cm–1], Normalized Absorbance [unitless] 2\. Column
 names: Wavenumber_PnBA_1AMPS (cm–1), Normalized_Absorbance_PnBA_1AMPS,
 Wavenumber_PDMS_1Im (cm–1), Normalized_Absorbance_PDMS_1Im,
 Wavenumber_1SO3HIm_Blend (cm–1), Normalized_Absorbance_1SO3HIm_Blend e.
 FigureS41c_6halfSO3HImBlend.csv 1\. Variables: Wavenumber [cm–1],
 Normalized Absorbance [unitless] 2\. Column names:
 Wavenumber_PnBA_6halfAMPS (cm–1), Normalized_Absorbance_PnBA_6halfAMPS,
 Wavenumber_PDMS_6halfIm (cm–1), Normalized_Absorbance_PDMS_6halfIm,
 Wavenumber_6halfSO3HIm_Blend (cm–1),
 Normalized_Absorbance_6halfSO3HIm_Blend G. FiguresS11,S35,S42:
 Differential scanning thermograms of synthesized polymers and blends a.
 FigureS11_PDMS.csv 1\. Variables: Temperature [°C], Normalized Heat Flow
 [W/g] 2\. Column names: Temperature_PDMS (°C), Normalized_Heat_Flow_PDMS
 (W/g), Temperature_PDMS_1Im (°C), Normalized_Heat_Flow_PDMS_1Im (W/g),
 Temperature_PDMS_6halfIm (°C), Normalized_Heat_Flow_PDMS_6halfIm (W/g) b.
 FigureS35_PnBA.csv 1\. Variables: Temperature [°C], Normalized Heat Flow
 [W/g] 2\. Column names: Temperature_PnBA (°C), Normalized_Heat_Flow_PnBA
 (W/g), Temperature_PnBA_1halfCEA (°C), Normalized_Heat_Flow_PnBA_1halfCEA
 (W/g), Temperature_PnBA_1AMPS (°C), Normalized_Heat_Flow_PnBA_1AMPS (W/g),
 Temperature_PnBA_6halfAMPS (°C), Normalized_Heat_Flow_PnBA_6halfAMPS (W/g)
 c. FigureS42a_COOHImBlend.csv 1\. Variables: Temperature [°C], Normalized
 Heat Flow [W/g] 2\. Column names: Temperature_PnBA_1halfCEA (°C),
 Normalized_Heat_Flow_PnBA_1halfCEA (W/g), Temperature_PDMS_1Im (°C),
 Normalized_Heat_Flow_PDMS_1Im (W/g), Temperature_ImCOOH_Blend (°C),
 Normalized_Heat_Flow_ImCOOH_Blend (W/g) d. FigureS42b_1SO3HImBlend.csv 1\.
 Variables: Temperature [°C], Normalized Heat Flow [W/g] 2\. Column names:
 Temperature_PnBA_1AMPS (°C), Normalized_Heat_Flow_PnBA_1AMPS (W/g),
 Temperature_PDMS_1Im (°C), Normalized_Heat_Flow_PDMS_1Im (W/g),
 Temperature_1SO3HIm_Blend (°C), Normalized_Heat_Flow_1SO3HIm_Blend (W/g)
 e. FigureS42c_6halfSO3HImBlend.csv 1\. Variables: Temperature [°C],
 Normalized Heat Flow [W/g] 2\. Column names: Temperature_PnBA_6halfAMPS
 (°C), Normalized_Heat_Flow_PnBA_6halfAMPS (W/g), Temperature_PDMS_6halfIm
 (°C), Normalized_Heat_Flow_PDMS_6halfIm (W/g),
 Temperature_6halfSO3HIm_Blend (°C), Normalized_Heat_Flow_6halfSO3HIm_Blend
 (W/g) H. FiguresS12,S36,S49-51: Small-amplitude oscillatory shear
 rheological master curves and shift factors of synthesized polymers and
 blends a. FigureS12a_PDMSmastercurves.csv 1\. Variables: Reduced Frequency
 [rad/s], Storage Modulus [Pa], Loss Modulus [Pa] 2\. Column names:
 waT_PDMS (rad/s), G'_PDMS (Pa), G''_PDMS (Pa), waT_PDMS_1Im
 (rad/s), G'_PDMS_1Im (Pa), G''_PDMS_1Im (Pa),
 waT_PDMS_6halfIm (rad/s), G'_PDMS_6halfIm (Pa),
 G''_PDMS_6halfIm (Pa) b. FigureS12b_PDMSshiftfactors.csv 1\.
 Variables: Temperature–Reference Temperature [C], Log(Shift Factor)
 [unitless] 2\. Column names: T-Tref_PDMS (°C), log(aT)_PDMS,
 T-Tref_PDMS_1Im (°C), log(aT)_PDMS_1Im, T-Tref_PDMS_6halfIm (°C),
 log(aT)_PDMS_6halfIm c. FigureS36a_PnBAmastercurves.csv 1\. Variables:
 Reduced Frequency [rad/s], Storage Modulus [Pa], Loss Modulus [Pa] 2\.
 Column names: waT_PnBA (rad/s), G'_PnBA (Pa), G''_PnBA
 (Pa), waT_PnBA_1halfCEA (rad/s), G'_PnBA_1halfCEA (Pa),
 G''_PnBA_1halfCEA (Pa), waT_PnBA_1AMPS (rad/s),
 G'_PnBA_1AMPS (Pa), G''_PnBA_1AMPS (Pa), waT_PnBA_6halfAMPS
 (rad/s), G'_PnBA_6halfAMPS (Pa), G''_PnBA_6halfAMPS (Pa) d.
 FigureS36b_PnBAshiftfactors.csv 1\. Variables: Temperature–Reference
 Temperature [C], Log(Shift Factor) [unitless] 2\. Column names:
 T-Tref_PnBA (°C), log(aT)_PnBA, T-Tref_PnBA_1halfCEA (°C),
 log(aT)_PnBA_1halfCEA, T-Tref_PnBA_1AMPS (°C), log(aT)_PnBA_1AMPS,
 T-Tref_PnBA_6halfAMPS (°C), log(aT)_PnBA_6halfAMPS e.
 FigureS49_6halfcomparison.csv 1\. Variables: Frequency [rad/s], Storage
 Modulus [Pa], Loss Modulus [Pa] 2\. Column names: w_parent_90C,
 G'_parent_90C, G''_parent_90C, w_blend_90C,
 G'_blend_90C, G''_blend_90C, w_parent_80C,
 G'_parent_80C, G''_parent_80C, w_blend_80C,
 G'_blend_80C, G''_blend_80C, w_parent_70C,
 G'_parent_70C, G''_parent_70C, w_blend_70C,
 G'_blend_70C, G''_blend_70C, w_parent_60C,
 G'_parent_60C, G''_parent_60C, w_blend_60C,
 G'_blend_60C, G''_blend_60C, w_parent_50C,
 G'_parent_50C, G''_parent_50C, w_blend_50C,
 G'_blend_50C, G''_blend_50C, w_parent_40C,
 G'_parent_40C, G''_parent_40C, w_blend_40C,
 G'_blend_40C, G''_blend_40C, w_parent_30C,
 G'_parent_30C, G''_parent_30C, w_blend_30C,
 G'_blend_30C, G''_blend_30C, w_parent_20C,
 G'_parent_20C, G''_parent_20C, w_blend_20C,
 G'_blend_20C, G''_blend_20C f.
 FigureS50a_1molblendoriginal.csv 1\. Variables: Frequency [rad/s], Storage
 Modulus [Pa], Loss Modulus [Pa] 2\. Column names: w (rad/s), G'_50C
 (Pa), G''_50C (Pa), w (rad/s), G'_50C_Post_Cool (Pa),
 G''_50C_Post_Cool (Pa), w (rad/s), G'_50C_Post_Heat (Pa),
 G''_50C_Post_Heat (Pa), w (rad/s), G'_55C (Pa),
 G''_55C (Pa), w (rad/s), G'_60C (Pa), G''_60C
 (Pa), w (rad/s), G'_65C (Pa), G''_65C (Pa), w (rad/s),
 G'_70C (Pa), G''_70C (Pa), w (rad/s), G'_75C (Pa),
 G''_75C (Pa), w (rad/s), G'_80C (Pa), G''_80C
 (Pa), w (rad/s), G'_85C (Pa), G''_85C (Pa), w (rad/s),
 G'_90C (Pa), G''_90C (Pa), w (rad/s), G'_95C (Pa),
 G''_95C (Pa), w (rad/s), G'_100C (Pa), G''_100C
 (Pa), w (rad/s), G'_105C (Pa), G''_105C (Pa), w (rad/s),
 G'_110C (Pa), G''_110C (Pa), w (rad/s), G'_115C (Pa),
 G''_115C (Pa), w (rad/s), G'_120C (Pa), G''_120C
 (Pa) g. FigureS50b_1molblendrecasted.csv 1\. Variables: Frequency [rad/s],
 Storage Modulus [Pa], Loss Modulus [Pa] 2\. Column names: w (rad/s),
 G'_50C (Pa), G''_50C (Pa), w (rad/s), G'_50C_Post_Heat
 (Pa), G''_50C_Post_Heat (Pa), w (rad/s), G'_55C (Pa),
 G''_55C (Pa), w (rad/s), G'_60C (Pa), G''_60C
 (Pa), w (rad/s) G'_65C (Pa), G''_65C (Pa), w (rad/s),
 G'_70C (Pa), G''_70C (Pa), w (rad/s), G'_75C (Pa),
 G''_75C (Pa), w (rad/s), G'_80C (Pa), G''_80C
 (Pa), w (rad/s), G'_85C (Pa), G''_85C (Pa), w (rad/s),
 G'_90C (Pa), G''_90C (Pa), w (rad/s), G'_95C (Pa),
 G''_95C (Pa), w (rad/s), G'_100C (Pa), G''_100C
 (Pa), w (rad/s), G'_105C (Pa), G''_105C (Pa), w (rad/s),
 G'_110C (Pa), G''_110C (Pa), w (rad/s), G'_115C (Pa),
 G''_115C (Pa), w (rad/s), G'_120C (Pa), G''_120C
 (Pa) h. FigureS51_6halfmolblend.csv 1\. Variables: Frequency [rad/s],
 Storage Modulus [Pa], Loss Modulus [Pa] 2\. Column names: w (rad/s),
 G'_50C (Pa), G''_50C (Pa), w (rad/s), G'_60C(Pa),
 G''_60C (Pa), w (rad/s), G'_60C_Post_Cool (Pa),
 G''_60C_Post_Cool (Pa), w (rad/s), G'_60C_Post_Heat (Pa),
 G''_60C_Post_Heat (Pa), w (rad/s), G'_70C (Pa),
 G''_70C (Pa), w (rad/s), G'_80C (Pa), G''_80C
 (Pa), w (rad/s), G'_90C (Pa), G''_90C (Pa), w (rad/s),
 G'_100C (Pa), G''_100C (Pa), w (rad/s), G'_110C (Pa),
 G''_110C (Pa), w (rad/s), G'_120C (Pa), G''_120C
 (Pa) I: FiguresS43-46,S48: Small angle X-ray scattering patterns of
 synthesized polymers and blends at room temperature, or elevated
 temperatures. a. FigureS43a_1SO3HImBlend.csv 1\. Variables: Scattering
 Wavevector [A-1], Intensity [arb. units] 2\. Column names: q_PnBA_1AMPS
 (A-1), I_PnBA_1AMPS (arb. units), q_PDMS_1Im (A-1), I_PDMS_1Im (arb.
 units), q_1SO3HIm_Blend (A-1), I_1SO3HIm_Blend (arb. units) b.
 FigureS43b_6halfSO3HImBlend.csv 1\. Variables: Scattering Wavevector
 [A-1], Intensity [arb. units] 2\. Column names: q_PnBA_6halfAMPS (A-1),
 I_PnBA_6halfAMPS (arb. units), q_PDMS_6halfIm (A-1), I_PDMS_6halfIm (arb.
 units), q_6halfSO3HIm_Blend (A-1), I_6halfSO3HIm_Blend (arb. units) c.
 FigureS44a_1SO3HImBlendR1.csv 1\. Variables: Scattering Wavevector [A-1],
 Intensity [arb. units] 2\. Column names: q_Pristine (A-1), I_Pristine
 (arb. units), q_1_Month (A-1), I_1_Month (arb. units), q_3_Months (A-1),
 I_3_Months (arb. units) d. FigureS44b_1SO3HImBlendR2.csv 1\. Variables:
 Scattering Wavevector [A-1], Intensity [arb. units] 2\. Column names:
 q_Pristine (A-1), I_Pristine (arb. units), q_1_Month (A-1), I_1_Month
 (arb. units) e. FigureS45_1SO3HImBlendR1VT.csv 1\. Variables: Scattering
 Wavevector [A-1], Intensity [arb. units] 2\. Column names: q_25C (A-1),
 I_25C (arb. units), q_50C (A-1), I_50C (arb. units), q_70C (A-1), I_70C
 (arb. units), q_90C (A-1), I_90C (arb. units), q_100C (A-1), I_100C (arb.
 units), q_110C (A-1), I_110C (arb. units), q_120C (A-1), I_120C (arb.
 units), q_130C (A-1), I_130C (arb. units), q_140C (A-1), I_140C (arb.
 units), q_150C (A-1), I_150C (arb. units), q_140C_Cool (A-1), I_140C_Cool
 (arb. units), q_130C_Cool (A-1), I_130C_Cool (arb. units), q_120C_Cool
 (A-1), I_120C_Cool (arb. units), q_100C_Cool (A-1), I_100C_Cool (arb.
 units), q_90C_Cool (A-1), I_90C_Cool (arb. units), q_70C_Cool (A-1),
 I_70C_Cool (arb. units), q_50C_Cool (A-1), I_50C_Cool (arb. units),
 q_25C_Cool (A-1), I_25C_Cool (arb. units) f.
 FigureS46_1SO3HImBlendR2VT.csv 1\. Variables: Scattering Wavevector [A-1],
 Intensity [arb. units] 2\. Column names: q_25C (A-1), I_25C (arb. units),
 q_50C (A-1), I_50C (arb. units), q_70C (A-1), I_70C (arb. units), q_90C
 (A-1), I_90C (arb. units), q_100C (A-1), I_100C (arb. units), q_110C
 (A-1), I_110C (arb. units), q_120C (A-1), I_120C (arb. units), q_130C
 (A-1), I_130C (arb. units), q_140C (A-1), I_140C (arb. units), q_150C
 (A-1), I_150C (arb. units), q_140C_Cool (A-1), I_140C_Cool (arb. units),
 q_130C_Cool (A-1), I_130C_Cool (arb. units), q_120C_Cool (A-1),
 I_120C_Cool (arb. units), q_100C_Cool (A-1), I_100C_Cool (arb. units),
 q_90C_Cool (A-1), I_90C_Cool (arb. units), q_70C_Cool (A-1), I_70C_Cool
 (arb. units), q_50C_Cool (A-1), I_50C_Cool (arb. units), q_25C_Cool (A-1),
 I_25C_Cool (arb. units) g. FigureS48_1SO3HImBlendRecast.csv 1\. Variables:
 Scattering Wavevector [A-1], Intensity [arb. units] 2\. Column names:
 q_Post_VT (A-1), I_Post_VT (arb. units), q_Recasted (A-1), I_Recasted
 (arb. units) J: FigureS47: Domain size as a function of temperature for 1
 mol% blend a. FigureS47_1molblendVTdomainR2.csv 1\. Variables: Temperature
 [°C], Primary Peak Wavevector [A-1], Domain Size [nm] 2\. Column names: T
 (°C), q* (A–1), d (nm) 2. Relationship between files, if important: N/A 3.
 Additional related data collected that was not included in the current
 data package: N/A 4. Are there multiple versions of the dataset? No
 METHODOLOGICAL INFORMATION 1. Description of methods used for
 collection/generation of data: Please refer to supporting information
 document for methodology of data generation and collection. 2. Methods for
 processing the data: Please refer to supporting information document for
 methodology of data processing. 3. Instrument- or software-specific
 information needed to interpret the data: N/A 4. Standards and calibration
 information, if appropriate: Molecular weight values reported from
 size-exclusion chromatography measurements were calibrated to known
 poly(styrene) standards with known molecular weights. 5.
 Environmental/experimental conditions: N/A 6. Describe any
 quality-assurance procedures performed on the data: N/A 7. People involved
 with sample collection, processing, analysis and/or submission: Jerrick
 Edmund, Kseniia M. Karnaukh, Shuyi Xie, Elizabeth A. Murphy, Allison
 Abdilla, Eiko Ino, Javier Read de Alaniz, Craig J. Hawker, Rachel A.
 Segalman