cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.17632/jgnvj2m4bp
title: Photochemical behavior between oxalate and Sb(V)/As(V)-bearing jarosite: Reaction mechanism, mineral transformation, and elemental fate

description: Jarosite is a common metastable iron mineral in acid sulfate-rich environments, which is known to retain antimony (Sb) and arsenic (As). Sunlight has emerged as a critical driver for the dissolution of iron minerals, especially in the presence of dissolved organic matter (DOM). However, the mechanisms governing jarosite dissolution and associated Sb/As migration under the coexistence of sunlight and DOM remain poorly understood. Here, we investigated the photochemical behavior of Sb(Ⅴ)/As(Ⅴ)-bearing jarosite with the representative DOM-oxalate (OA) under simulated sunlight. In situ attenuated total reflection-Fourier transform infrared spectroscopy (ATR-FTIR) and density functional theory (DFT) calculations revealed that oxalate was predominantly adsorbed onto the jarosite surface via mononuclear bidentate (MB) binding geometry. Under light irradiation, oxalate underwent photolysis on the jarosite surface, thereby inducing reductive dissolution of the mineral. The dissolution rate of jarosite was faster under anoxic conditions than under oxic conditions, and both rates increased with increasing oxalate dosage. Notably, high OA dosage (2.5 mM) induced jarosite transformation to humboldtine under anoxic conditions and to lepidocrocite under oxic conditions. Scanning transmission electron microscopy combined with energy-dispersive spectroscopy (STEM-EDS) showed that the formed lepidocrocite exhibited a superior capability to fix Sb and As compared to humboldtine. Chemical extraction further demonstrated that photoaged Sb preferentially partitioned into the poorly crystalline phase, whereas As tended to adsorb onto the mineral surface. These findings provide new insights into the photochemical behavior between iron minerals and DOM, and offer theoretical guidance for predicting the migration of Sb and As in sunlit environments.
Keywords: Jarosite; Oxalate; Antimony; Arsenic; Photochemical behavior.
DOI: 10.17632/jgnvj2m4bp.2
title: Photochemical behavior between oxalate and Sb(V)/As(V)-bearing jarosite: Reaction mechanism, mineral transformation, and elemental fate

description: Jarosite is a common metastable iron mineral in acid sulfate-rich environments, which is known to retain antimony (Sb) and arsenic (As). Sunlight has emerged as a critical driver for the dissolution of iron minerals, especially in the presence of dissolved organic matter (DOM). However, the mechanisms governing jarosite dissolution and associated Sb/As migration under the coexistence of sunlight and DOM remain poorly understood. Here, we investigated the photochemical behavior of Sb(Ⅴ)/As(Ⅴ)-bearing jarosite with the representative DOM-oxalate (OA) under simulated sunlight. In situ attenuated total reflection-Fourier transform infrared spectroscopy (ATR-FTIR) and density functional theory (DFT) calculations revealed that oxalate was predominantly adsorbed onto the jarosite surface via mononuclear bidentate (MB) binding geometry. Under light irradiation, oxalate underwent photolysis on the jarosite surface, thereby inducing reductive dissolution of the mineral. The dissolution rate of jarosite was faster under anoxic conditions than under oxic conditions, and both rates increased with increasing oxalate dosage. Notably, high OA dosage (2.5 mM) induced jarosite transformation to humboldtine under anoxic conditions and to lepidocrocite under oxic conditions. Scanning transmission electron microscopy combined with energy-dispersive spectroscopy (STEM-EDS) showed that the formed lepidocrocite exhibited a superior capability to fix Sb and As compared to humboldtine. Chemical extraction further demonstrated that photoaged Sb preferentially partitioned into the poorly crystalline phase, whereas As tended to adsorb onto the mineral surface. These findings provide new insights into the photochemical behavior between iron minerals and DOM, and offer theoretical guidance for predicting the migration of Sb and As in sunlit environments.
Keywords: Jarosite; Oxalate; Antimony; Arsenic; Photochemical behavior.
DOI: 10.17632/4dwjxfmv5t
title: Inorganic or organic amendments facilitated the phytostabilisation potential of Robinia pseudoacacia L. under the heavy metal-contaminated soil: plant growth, heavy metal immobilization, and microbial co-occurrence network

description: Robinia pseudoacacia L., a pioneer woody legume plant, had been confirmed as a candidate plant for the phytostabilisation of heavy metal contaminated soil. However, high levels of heavy metals in mining areas produced an adverse on plant growth. In this study, five types of inorganic or organic amendments, namely limestone (SH), hydroxyapatite (LH), biochar (SW), calcium magnesium phosphate fertilizer (GM), and organic fertilizer (YJ), were selected to assisted with R. pseudoacacia L. to improve plant growth, and further enhance the phytostabilisation potential in mining areas. The results indicated that both inorganic and organic amendments could promote the growth of R. pseudoacacia L., reduce Cd and Pb uptake in plant, immobilize the bioavailability of Cd and Pb in the soil, and change the co-occurrence network of soil microbial community structure. The growth of R. pseudoacacia L. was significantly increased under the application of inorganic or organic amendments, especially for the application of LH was significantly (p&lt; 0.05) increased by 57.2%-56.4%. Meanwhile, the diethyltriamine pentaacetic acid (DTPA) extractable Cd and Pb contents in soil with the application of LH were decreased by 16.0%-16.3% and 8.3%-8.6% relative to the control, and the Cd and Pb content in R. pseudoacacia L. roots was also significantly (p&lt; 0.05) reduced by 35.9%-76.1% and 26.3%-74.3%, respectively. Five types of inorganic or organic amendments could significantly change the microbial community structure of R. pseudoacacia L. rhizosphere soil, especially for LH. Network analysis indicated that R. pseudoacacia L. associated with inorganic amendments could promote the stability and complexity of the microbial network in the contaminated soil. These results suggested that inorganic amendments might promote plant growth and improve the complexity of rhizosphere microbial network, thereby enhancing the adaptability of R. pseudoacacia L. for the phytostabilisation of mining areas.
DOI: 10.17632/4dwjxfmv5t.1
title: Inorganic or organic amendments facilitated the phytostabilisation potential of Robinia pseudoacacia L. under the heavy metal-contaminated soil: plant growth, heavy metal immobilization, and microbial co-occurrence network

description: Robinia pseudoacacia L., a pioneer woody legume plant, had been confirmed as a candidate plant for the phytostabilisation of heavy metal contaminated soil. However, high levels of heavy metals in mining areas produced an adverse on plant growth. In this study, five types of inorganic or organic amendments, namely limestone (SH), hydroxyapatite (LH), biochar (SW), calcium magnesium phosphate fertilizer (GM), and organic fertilizer (YJ), were selected to assisted with R. pseudoacacia L. to improve plant growth, and further enhance the phytostabilisation potential in mining areas. The results indicated that both inorganic and organic amendments could promote the growth of R. pseudoacacia L., reduce Cd and Pb uptake in plant, immobilize the bioavailability of Cd and Pb in the soil, and change the co-occurrence network of soil microbial community structure. The growth of R. pseudoacacia L. was significantly increased under the application of inorganic or organic amendments, especially for the application of LH was significantly (p&lt; 0.05) increased by 57.2%-56.4%. Meanwhile, the diethyltriamine pentaacetic acid (DTPA) extractable Cd and Pb contents in soil with the application of LH were decreased by 16.0%-16.3% and 8.3%-8.6% relative to the control, and the Cd and Pb content in R. pseudoacacia L. roots was also significantly (p&lt; 0.05) reduced by 35.9%-76.1% and 26.3%-74.3%, respectively. Five types of inorganic or organic amendments could significantly change the microbial community structure of R. pseudoacacia L. rhizosphere soil, especially for LH. Network analysis indicated that R. pseudoacacia L. associated with inorganic amendments could promote the stability and complexity of the microbial network in the contaminated soil. These results suggested that inorganic amendments might promote plant growth and improve the complexity of rhizosphere microbial network, thereby enhancing the adaptability of R. pseudoacacia L. for the phytostabilisation of mining areas.
DOI: 10.17632/p5bbmmbsrt
title: Detrital Mineral Compositions of Surface Sediments from Laizhou Bay and Its Inflowing Rivers

description: Geographic Coverage:
Laizhou Bay, southern Bohai Sea, China (Latitude: ~36.5°N–37.8°N, Longitude: ~118.1°E–119.7°E)

Temporal Coverage:
River samples: April 2023 (low-water period)
Marine samples: June 2023

Data Collection Methods:

Surface sediment samples were collected from the riparian zones of seven rivers (Xiaoqing, Mi, Bailang, Yu, Di, Wei, Jiaolai) and 15 marine stations in Laizhou Bay.

Samples were treated with H₂O₂ and dilute HCl to remove organic matter and carbonates.

The ultrafine sand fraction (0.063–0.125 mm) was separated by wet sieving.

Heavy minerals were isolated using tribromomethane (density 2.89 g/cm³).

Mineral identification and counting were performed under polarizing microscopes; ≥300 grains were counted per sample.

Dataset Structure:
The dataset is provided in an Excel workbook with three sheets:

Raw Data: Full heavy mineral counts (41 minerals) for each site (55 sites total).

Screened Data: Focused dataset of 20 key minerals and grouped assemblages for provenance analysis.

Mineral Assemblage and Location: Summarized mineral groups (amphibole, epidote, mica, metallic-iron, pyroxene, stable minerals) with geographic coordinates (LON, LAT).

Variables Included:

Site identifiers (e.g., DH01, YH01, BL01, Sea, Yellow R)

Mineral abundances (%) for magnetite, ilmenite, hematite, leucoxene, zircon, titanite, apatite, tourmaline, garnet, orthopyroxene, augite, hornblende, actinolite-tremolite, epidote, (clino)zoisite, chlorite, biotite, muscovite, weathered mica, carbonate, and others.

Mineral assemblages (%) as grouped by genetic categories.

Geographic coordinates in decimal degrees (WGS84).

Data Format:
Microsoft Excel (.xlsx), comma-separated values (.csv) also available upon request.

Potential Uses:

Sediment provenance analysis in multi-source marginal seas

Comparative studies of river–sea sediment transport

Validation of sediment mixing and hydrodynamic sorting models

Background data for environmental and geological surveys in the Bohai Sea region

Data Quality:

All samples were processed following standardized laboratory protocols.

Microscopic counting was conducted by trained geologists; reproducibility was ensured by repeated counts for selected samples.

Data are presented as relative percentages; total sums are normalized to 100% per sample.

Access and Availability:
The dataset supporting this article is available in the supplementary materials and will be archived in a public repository (e.g., Zenodo, Mendeley Data) upon acceptance. Data can also be obtained by contacting the corresponding authors.
DOI: 10.17632/p5bbmmbsrt.1
title: Detrital Mineral Compositions of Surface Sediments from Laizhou Bay and Its Inflowing Rivers

description: Geographic Coverage:
Laizhou Bay, southern Bohai Sea, China (Latitude: ~36.5°N–37.8°N, Longitude: ~118.1°E–119.7°E)

Temporal Coverage:
River samples: April 2023 (low-water period)
Marine samples: June 2023

Data Collection Methods:

Surface sediment samples were collected from the riparian zones of seven rivers (Xiaoqing, Mi, Bailang, Yu, Di, Wei, Jiaolai) and 15 marine stations in Laizhou Bay.

Samples were treated with H₂O₂ and dilute HCl to remove organic matter and carbonates.

The ultrafine sand fraction (0.063–0.125 mm) was separated by wet sieving.

Heavy minerals were isolated using tribromomethane (density 2.89 g/cm³).

Mineral identification and counting were performed under polarizing microscopes; ≥300 grains were counted per sample.

Dataset Structure:
The dataset is provided in an Excel workbook with three sheets:

Raw Data: Full heavy mineral counts (41 minerals) for each site (55 sites total).

Screened Data: Focused dataset of 20 key minerals and grouped assemblages for provenance analysis.

Mineral Assemblage and Location: Summarized mineral groups (amphibole, epidote, mica, metallic-iron, pyroxene, stable minerals) with geographic coordinates (LON, LAT).

Variables Included:

Site identifiers (e.g., DH01, YH01, BL01, Sea, Yellow R)

Mineral abundances (%) for magnetite, ilmenite, hematite, leucoxene, zircon, titanite, apatite, tourmaline, garnet, orthopyroxene, augite, hornblende, actinolite-tremolite, epidote, (clino)zoisite, chlorite, biotite, muscovite, weathered mica, carbonate, and others.

Mineral assemblages (%) as grouped by genetic categories.

Geographic coordinates in decimal degrees (WGS84).

Data Format:
Microsoft Excel (.xlsx), comma-separated values (.csv) also available upon request.

Potential Uses:

Sediment provenance analysis in multi-source marginal seas

Comparative studies of river–sea sediment transport

Validation of sediment mixing and hydrodynamic sorting models

Background data for environmental and geological surveys in the Bohai Sea region

Data Quality:

All samples were processed following standardized laboratory protocols.

Microscopic counting was conducted by trained geologists; reproducibility was ensured by repeated counts for selected samples.

Data are presented as relative percentages; total sums are normalized to 100% per sample.

Access and Availability:
The dataset supporting this article is available in the supplementary materials and will be archived in a public repository (e.g., Zenodo, Mendeley Data) upon acceptance. Data can also be obtained by contacting the corresponding authors.
DOI: 10.17632/8bgmhsb9v8
title: Up-regulated lncRNA-TLR3 inhibits infectious bursal disease virus replication by promoting TLR3 expression to enhance TRIF-IRF7 mediated type-I IFN production

description: Infectious bursal disease virus (IBDV) is a highly contagious and immunosuppressive avian pathogen that causes severe economic losses to the global poultry industry. However, the molecular mechanisms underlying IBDV–host innate immune interactions remain incompletely defined. In this study, we identified an IBDV-responsive long non-coding RNA, termed lncRNA-TLR3, and its associated target gene Toll-like receptor 3 (TLR3), and systematically investigated their roles in antiviral innate immunity. We demonstrated that IBDV infection markedly upregulated TLR3 expression and activated the TRIF–IRF7 signaling cascade, leading to robust induction of type I interferons (IFN-α/β) and interferon-stimulated genes (ISGs), thereby restricting viral replication. Bioinformatic analyses and RNA fluorescence in situ hybridization (RNA-FISH) confirmed that lncRNA-TLR3 lacks protein-coding potential and is predominantly localized in the cytoplasm. Notably, lncRNA-TLR3 expression was significantly induced by IBDV infection both in vitro and in vivo. Gain- and loss-of-function assays revealed that lncRNA-TLR3 positively regulated TLR3 expression, enhanced TRIF–IRF7–mediated IFN-I and ISGs responses, and consequently suppressed IBDV replication. Rescue experiments further demonstrated that the antiviral activity of lncRNA-TLR3 is largely dependent on TLR3 signaling. Moreover, RNA-FISH assays revealed cytoplasmic colocalization of lncRNA-TLR3 and TLR3 in IBDV-infected cells and bursal tissues. Collectively, our findings identify lncRNA-TLR3 as a positive regulator of TLR3-mediated innate immunity and provide new mechanistic insights into host–IBDV interactions, highlighting lncRNA-TLR3 as a potential antiviral target in poultry.
DOI: 10.17632/8bgmhsb9v8.1
title: Up-regulated lncRNA-TLR3 inhibits infectious bursal disease virus replication by promoting TLR3 expression to enhance TRIF-IRF7 mediated type-I IFN production

description: Infectious bursal disease virus (IBDV) is a highly contagious and immunosuppressive avian pathogen that causes severe economic losses to the global poultry industry. However, the molecular mechanisms underlying IBDV–host innate immune interactions remain incompletely defined. In this study, we identified an IBDV-responsive long non-coding RNA, termed lncRNA-TLR3, and its associated target gene Toll-like receptor 3 (TLR3), and systematically investigated their roles in antiviral innate immunity. We demonstrated that IBDV infection markedly upregulated TLR3 expression and activated the TRIF–IRF7 signaling cascade, leading to robust induction of type I interferons (IFN-α/β) and interferon-stimulated genes (ISGs), thereby restricting viral replication. Bioinformatic analyses and RNA fluorescence in situ hybridization (RNA-FISH) confirmed that lncRNA-TLR3 lacks protein-coding potential and is predominantly localized in the cytoplasm. Notably, lncRNA-TLR3 expression was significantly induced by IBDV infection both in vitro and in vivo. Gain- and loss-of-function assays revealed that lncRNA-TLR3 positively regulated TLR3 expression, enhanced TRIF–IRF7–mediated IFN-I and ISGs responses, and consequently suppressed IBDV replication. Rescue experiments further demonstrated that the antiviral activity of lncRNA-TLR3 is largely dependent on TLR3 signaling. Moreover, RNA-FISH assays revealed cytoplasmic colocalization of lncRNA-TLR3 and TLR3 in IBDV-infected cells and bursal tissues. Collectively, our findings identify lncRNA-TLR3 as a positive regulator of TLR3-mediated innate immunity and provide new mechanistic insights into host–IBDV interactions, highlighting lncRNA-TLR3 as a potential antiviral target in poultry.
DOI: 10.15468/dl.mzrw7m
title: Occurrence Download

description: A dataset containing 206256 species occurrences available in GBIF matching the query:
{
 "TaxonKey" : [
 "is Syzygium"
 ]
}

 The dataset includes 206256 records from 1005 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0069040-251120083545085/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.vud3ze
title: Occurrence Download

description: A dataset containing 280182 species occurrences available in GBIF matching the query:
{
 "and" : [
 "OccurrenceStatus is Present",
 "TaxonKey is Frullaniaceae"
 ]
}

 The dataset includes 280182 records from 925 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0069047-251120083545085/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.13140/rg.2.2.25415.47521
title: Acrylamide Patent Analysis Database
DOI: 10.5517/ccwr0wh
title: CCDC 826487: Experimental Crystal Structure Determination

description: Related Article: R.S.Ghadwal, R.Azhakar, K.Propper, J.J.Holstein, B.Dittrich, H.W.Roesky|2011|Inorg.Chem.|50|8502|doi:10.1021/ic201096c
description: An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
DOI: 10.5517/ccwr0xj
title: CCDC 826488: Experimental Crystal Structure Determination

description: Related Article: R.S.Ghadwal, R.Azhakar, K.Propper, J.J.Holstein, B.Dittrich, H.W.Roesky|2011|Inorg.Chem.|50|8502|doi:10.1021/ic201096c
description: An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
DOI: 10.13140/rg.2.2.17184.15360
title: Selection of Transformers and Testing Techniques
DOI: 10.13140/rg.2.2.20495.15523
title: Leveraging Terminology Services for FAIR Semantic Data Integration across NFDI Domains.pdf.pdf
DOI: 10.5517/ccxlw9n
title: CCDC 852292: Experimental Crystal Structure Determination

description: Related Article: A.M.A.Aznan, Z.Abdullah, S.W.Ng, E.R.T.Tiekink|2011|Acta Crystallogr.,Sect.E:Struct.Rep.Online|67|o3076|doi:10.1107/S1600536811044011
description: An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
DOI: 10.13140/rg.2.2.12989.84960
title: Doppler spread, time spread, coherence time, and coherence frequency
DOI: 10.5517/ccxlwbp
title: CCDC 852293: Experimental Crystal Structure Determination

description: Related Article: S.B.Nasir, Z.A.Fairuz, Z.Abdullah, S.W.Ng, E.R.T.Tiekink|2011|Acta Crystallogr.,Sect.E:Struct.Rep.Online|67|o3077|doi:10.1107/S1600536811044047
description: An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
DOI: 10.5517/ccxlwcq
title: CCDC 852294: Experimental Crystal Structure Determination

description: Related Article: Z.A.Fairuz, Z.Aiyub, Z.Abdullah, S.W.Ng, E.R.T.Tiekink|2011|Acta Crystallogr.,Sect.E:Struct.Rep.Online|67|o3078|doi:10.1107/S1600536811044059
description: An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
DOI: 10.13140/rg.2.2.14038.42563
title: Linear functionals and filtering of random processes
DOI: 10.13140/rg.2.2.19910.45124
title: Reviewer Certificate for one international research paper
DOI: 10.5517/ccxlwdr
title: CCDC 852295: Experimental Crystal Structure Determination

description: Related Article: S.B.Nasir, Z.A.Fairuz, Z.Abdullah, S.W.Ng, E.R.T.Tiekink|2011|Acta Crystallogr.,Sect.E:Struct.Rep.Online|67|o3079|doi:10.1107/S1600536811044060
description: An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.
DOI: 10.13140/rg.2.2.28482.56001
title: british companys private army artillery officers brilliantly made use of artillery suffering lowest casualties while indo pak commanders were incompetent and foolhardy and suffered unnecessary losses at bara pind and mandiala etc.
DOI: 10.5517/ccxlwfs
title: CCDC 852296: Experimental Crystal Structure Determination

description: Related Article: A.M.A.Aznan, Z.Abdullah, S.W.Ng, E.R.T.Tiekink|2011|Acta Crystallogr.,Sect.E:Struct.Rep.Online|67|o3080|doi:10.1107/S1600536811044175
description: An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.