cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.6084/m9.figshare.3453689
title: Interactions between continent-like ‘drift’, rifting and mantle flow on Venus: gravity interpretations and Earth analogues

description: Regional shear zones are interpreted from Bouguer gravity data over northern polar to low southern latitudes of Venus. Offset and deflection of horizontal gravity gradient edges (‘worms’) and lineaments interpreted from displacement of Bouguer anomalies portray crustal structures, the geometry of which resembles both regional transcurrent shear zones bounding or cross-cutting cratons and fracture zones in oceanic crust on Earth. High Bouguer anomalies and thinned crust comparable to the Mid-Continent Rift in North America suggest underplating of denser, mantle-derived mafic material beneath extended crust in Sedna and Guinevere planitia on Venus. These rifts are partitioned by transfer faults and flank a zone of mantle upwelling (Eistla Regio) between colinear hot, upwelling mantle plumes. Data support the northward drift and indentation of Lakshmi Planum in western Ishtar Terra and &gt;1000 km of transcurrent displacement between Ovda and Thetis regiones. Large displacements of areas of continent-like crust on Venus are interpreted to result from mantle tractions and pressure acting against their deep lithospheric mantle ‘keels’ commensurate with extension in adjacent rifts. Displacements of Lakshmi Planum and Ovda and Thetis regiones on Venus, a planet without plate tectonics, cannot be attributed to plate boundary forces (i.e. ridge push and slab pull). Results therefore suggest that a similar, subduction-free geodynamic model may explain deformation features in Archaean greenstone terrains on Earth. Continent-like ‘drift’ on Venus also resembles models for the late Cenozoic–Recent Earth, where westward translation of the Americas and northward displacement of India are interpreted as being driven by mantle flow tractions on the keels of their Precambrian cratons.
DOI: 10.6084/m9.figshare.3453689.v1
title: Interactions between continent-like ‘drift’, rifting and mantle flow on Venus: gravity interpretations and Earth analogues

description: Regional shear zones are interpreted from Bouguer gravity data over northern polar to low southern latitudes of Venus. Offset and deflection of horizontal gravity gradient edges (‘worms’) and lineaments interpreted from displacement of Bouguer anomalies portray crustal structures, the geometry of which resembles both regional transcurrent shear zones bounding or cross-cutting cratons and fracture zones in oceanic crust on Earth. High Bouguer anomalies and thinned crust comparable to the Mid-Continent Rift in North America suggest underplating of denser, mantle-derived mafic material beneath extended crust in Sedna and Guinevere planitia on Venus. These rifts are partitioned by transfer faults and flank a zone of mantle upwelling (Eistla Regio) between colinear hot, upwelling mantle plumes. Data support the northward drift and indentation of Lakshmi Planum in western Ishtar Terra and &gt;1000 km of transcurrent displacement between Ovda and Thetis regiones. Large displacements of areas of continent-like crust on Venus are interpreted to result from mantle tractions and pressure acting against their deep lithospheric mantle ‘keels’ commensurate with extension in adjacent rifts. Displacements of Lakshmi Planum and Ovda and Thetis regiones on Venus, a planet without plate tectonics, cannot be attributed to plate boundary forces (i.e. ridge push and slab pull). Results therefore suggest that a similar, subduction-free geodynamic model may explain deformation features in Archaean greenstone terrains on Earth. Continent-like ‘drift’ on Venus also resembles models for the late Cenozoic–Recent Earth, where westward translation of the Americas and northward displacement of India are interpreted as being driven by mantle flow tractions on the keels of their Precambrian cratons.
DOI: 10.6084/m9.figshare.3453686
title: Analysis of powdered reference materials and known samples with a benchtop, field portable X-ray fluorescence (pXRF) spectrometer: evaluation of performance and potential applications for exploration lithogeochemistry

description: Powdered international reference materials and samples with previously obtained conventional geochemical data were analysed using a benchtop portable X-ray fluorescence (pXRF) spectrometer to test the abilities of pXRF in silicate rock lithogeochemistry. Results from international reference materials illustrate that pXRF can provide very precise data for many major, minor, and trace elements, generally with RSD values of &lt;7.5 % and many &lt;5 %, except at very low concentrations (i.e. approaching the limit of detection). Despite good precision, accuracy is highly variable and ranges from excellent to reasonable for many major and minor elements (±15–20 % relative difference, RD, for Al<sub>2</sub>O<sub>3</sub>, SiO<sub>2</sub>, K<sub>2</sub>O, CaO, Fe<sub>2</sub>O<sub>3</sub>, TiO<sub>2</sub>, and MnO±S), base metals (±20 % for Cu, Zn), the low field strength (LFSE) and high field strength elements (HFSE) (±15 % RD for Rb, Ba, Zr; ±20 % RD for Nb). Poor accuracy was obtained for MgO, P<sub>2</sub>O<sub>5</sub>, and the transition elements (V, Cr, Ni); Sr shows variable accuracy. Comparison of pXRF results to independent samples with data from conventional analyses illustrates very poor correlation for MgO, P<sub>2</sub>O<sub>5</sub>, V, Cr, and Ni, suggesting they have poor accuracy by pXRF. Aluminum (Al<sub>2</sub>O<sub>3</sub>), SiO<sub>2</sub>, and Zn have r<sup>2</sup> values of <em>c</em>. 0.6–0.7 illustrating reasonable correlation, whereas most other elements (S, K<sub>2</sub>O, CaO, TiO<sub>2</sub>, MnO, Fe<sub>2</sub>O<sub>3</sub>, Co, Cu, Pb, Rb, Sr, Ba, Zr, Nb, U, As, and Mo) have very good to excellent correlation between pXRF data and conventional analysis (i.e. r<sup>2</sup> &gt;0.80). In addition, many of the elements with r<sup>2</sup> &gt;0.8 have slopes that are close to 1 or within 20 % of ideal, indicating that pXRF is replicating the results of conventional analyses and likely within ±20 % of what can be obtained by conventional methods. Down-hole profiles of pXRF data and element ratios replicate the geometry of the profiles from conventional analyses and illustrate the ability of the pXRF to discriminate rock type, alteration, and mineralization in unknown samples. Portable XRF can provide fit-for-purpose data that is useful in discriminating lithogeochemical variations related to lithology, alteration, and mineralization. However, pXRF should be considered a preliminary screening tool for sample selection and not a substitute for conventional lithogeochemical methods (e.g. XRF, fusion ICP-ES and ICP-MS), particularly when important economic decisions are to be made using such data (e.g. NI-43-101 resource calculations).
DOI: 10.6084/m9.figshare.3453686.v1
title: Analysis of powdered reference materials and known samples with a benchtop, field portable X-ray fluorescence (pXRF) spectrometer: evaluation of performance and potential applications for exploration lithogeochemistry

description: Powdered international reference materials and samples with previously obtained conventional geochemical data were analysed using a benchtop portable X-ray fluorescence (pXRF) spectrometer to test the abilities of pXRF in silicate rock lithogeochemistry. Results from international reference materials illustrate that pXRF can provide very precise data for many major, minor, and trace elements, generally with RSD values of &lt;7.5 % and many &lt;5 %, except at very low concentrations (i.e. approaching the limit of detection). Despite good precision, accuracy is highly variable and ranges from excellent to reasonable for many major and minor elements (±15–20 % relative difference, RD, for Al<sub>2</sub>O<sub>3</sub>, SiO<sub>2</sub>, K<sub>2</sub>O, CaO, Fe<sub>2</sub>O<sub>3</sub>, TiO<sub>2</sub>, and MnO±S), base metals (±20 % for Cu, Zn), the low field strength (LFSE) and high field strength elements (HFSE) (±15 % RD for Rb, Ba, Zr; ±20 % RD for Nb). Poor accuracy was obtained for MgO, P<sub>2</sub>O<sub>5</sub>, and the transition elements (V, Cr, Ni); Sr shows variable accuracy. Comparison of pXRF results to independent samples with data from conventional analyses illustrates very poor correlation for MgO, P<sub>2</sub>O<sub>5</sub>, V, Cr, and Ni, suggesting they have poor accuracy by pXRF. Aluminum (Al<sub>2</sub>O<sub>3</sub>), SiO<sub>2</sub>, and Zn have r<sup>2</sup> values of <em>c</em>. 0.6–0.7 illustrating reasonable correlation, whereas most other elements (S, K<sub>2</sub>O, CaO, TiO<sub>2</sub>, MnO, Fe<sub>2</sub>O<sub>3</sub>, Co, Cu, Pb, Rb, Sr, Ba, Zr, Nb, U, As, and Mo) have very good to excellent correlation between pXRF data and conventional analysis (i.e. r<sup>2</sup> &gt;0.80). In addition, many of the elements with r<sup>2</sup> &gt;0.8 have slopes that are close to 1 or within 20 % of ideal, indicating that pXRF is replicating the results of conventional analyses and likely within ±20 % of what can be obtained by conventional methods. Down-hole profiles of pXRF data and element ratios replicate the geometry of the profiles from conventional analyses and illustrate the ability of the pXRF to discriminate rock type, alteration, and mineralization in unknown samples. Portable XRF can provide fit-for-purpose data that is useful in discriminating lithogeochemical variations related to lithology, alteration, and mineralization. However, pXRF should be considered a preliminary screening tool for sample selection and not a substitute for conventional lithogeochemical methods (e.g. XRF, fusion ICP-ES and ICP-MS), particularly when important economic decisions are to be made using such data (e.g. NI-43-101 resource calculations).
DOI: 10.6084/m9.figshare.3453680
title: Setting the stage for the genesis of the giant Bendigo ore system

description: The Ordovician sediments that host the giant Bendigo saddle reef gold deposits consist of a 3 km-thick sequence of turbiditic sandstones and interbedded siltstones and mudstones. Sedimentological studies suggest the succession formed within a major deep marine channel–levee complex similar to those described from contemporary continental margin to basin plain settings outboard of major river systems (e.g. the Amazon, Mississippi and Congo). Black shales, which are commonly the immediate host rocks to the epigenetic gold reefs, are interpreted to be over-bank deposits or abandoned channel fills, developed adjacent to active channels which were sandstone-dominated and had an incised axial thalweg marked by the coarsest-grained sediments present. Organic carbon content of the black shales at Bendigo varies from 0.2 to 2 wt%, compared with the grey shales, siltstones and sandstones, which vary from 0.05 to 0.2 wt%. Trace elements fall into two main groups: (a) elements that have a linear relationship with aluminium, and are controlled by the detrital clay content (Sn, Ba, Rb, Li, Cs, Mn, Cr and Tl); and (b) elements that show relationships with both aluminium and organic carbon (V, U, Ni, Zn, Cu, Bi, Pb, Se, Ag and Au) and are controlled by both the clay and organic matter content in the carbonaceous shales. The elements in the second group are enriched in the black shale facies. The background gold content of the black shales in the drill holes distal from mineralization averages 8.9 ppb, compared with the sandstones with 1.5 ppb. Most of the gold in the shales is present in diagenetic pyrite and marcasite, which laser ablation inductively coupled mass spectrometer (LA-ICPMS) analyses indicate varies from 5 to 3850 ppb and averages 370 ppb Au. The geochemical data suggest that this syngenetic gold was most likely sourced by erosion of the hinterland, and transported attached to detrital clay particles or as colloidal gold, by a high-volume feeder river system. High Rb/K ratios in the shales support a highly weathered source typical of a giant river system. By analogy with modern systems, following transport into deep marine channel–levee complexes via continental margin canyons, gold and other redox sensitive trace elements were ultimately trapped by reduction, adsorption and complexation with organic matter in the sub-oxic to anoxic over-bank deposits. Oxidation of much of the organic matter during diagenesis released the gold and certain trace elements (Ni, Co, Se, Ag, Cu, Bi, Pb), which became incorporated into diagenetic pyrite. Enrichment of gold in diagenetic pyrite of the black shale facies of the Ordovician turbidites at Bendigo was the first stage in a two-stage process that produced the world-class quartz–gold saddle reef deposits.
DOI: 10.6084/m9.figshare.3453680.v1
title: Setting the stage for the genesis of the giant Bendigo ore system

description: The Ordovician sediments that host the giant Bendigo saddle reef gold deposits consist of a 3 km-thick sequence of turbiditic sandstones and interbedded siltstones and mudstones. Sedimentological studies suggest the succession formed within a major deep marine channel–levee complex similar to those described from contemporary continental margin to basin plain settings outboard of major river systems (e.g. the Amazon, Mississippi and Congo). Black shales, which are commonly the immediate host rocks to the epigenetic gold reefs, are interpreted to be over-bank deposits or abandoned channel fills, developed adjacent to active channels which were sandstone-dominated and had an incised axial thalweg marked by the coarsest-grained sediments present. Organic carbon content of the black shales at Bendigo varies from 0.2 to 2 wt%, compared with the grey shales, siltstones and sandstones, which vary from 0.05 to 0.2 wt%. Trace elements fall into two main groups: (a) elements that have a linear relationship with aluminium, and are controlled by the detrital clay content (Sn, Ba, Rb, Li, Cs, Mn, Cr and Tl); and (b) elements that show relationships with both aluminium and organic carbon (V, U, Ni, Zn, Cu, Bi, Pb, Se, Ag and Au) and are controlled by both the clay and organic matter content in the carbonaceous shales. The elements in the second group are enriched in the black shale facies. The background gold content of the black shales in the drill holes distal from mineralization averages 8.9 ppb, compared with the sandstones with 1.5 ppb. Most of the gold in the shales is present in diagenetic pyrite and marcasite, which laser ablation inductively coupled mass spectrometer (LA-ICPMS) analyses indicate varies from 5 to 3850 ppb and averages 370 ppb Au. The geochemical data suggest that this syngenetic gold was most likely sourced by erosion of the hinterland, and transported attached to detrital clay particles or as colloidal gold, by a high-volume feeder river system. High Rb/K ratios in the shales support a highly weathered source typical of a giant river system. By analogy with modern systems, following transport into deep marine channel–levee complexes via continental margin canyons, gold and other redox sensitive trace elements were ultimately trapped by reduction, adsorption and complexation with organic matter in the sub-oxic to anoxic over-bank deposits. Oxidation of much of the organic matter during diagenesis released the gold and certain trace elements (Ni, Co, Se, Ag, Cu, Bi, Pb), which became incorporated into diagenetic pyrite. Enrichment of gold in diagenetic pyrite of the black shale facies of the Ordovician turbidites at Bendigo was the first stage in a two-stage process that produced the world-class quartz–gold saddle reef deposits.
DOI: 10.6084/m9.figshare.3453677
title: A Timanian foreland basin setting for the late Neoproterozoic–Early Palaeozoic cover sequences (Dividal Group) of northeastern Baltica

description: LA-ICP-MS U–Pb and Hf-isotope data on detrital zircons from the Ediacaran and Cambrian Dividal Group demonstrate that the autochthonous cover sequence above the Fennoscandian Shield in northernmost Scandinavia is not derived from an easterly Archaean and Palaeoproterozoic source within Baltica as commonly thought. Detrital zircon age populations on four samples from the Dividal Group are dominated by Mesoproterozoic zircons with relatively few Palaeoproterozoic and Archaean zircons. Two samples, from Altevann and Reisadalen have, in addition, a significant population of Ediacaran zircons (<em>c.</em> 570–560 Ma), indicating a Timanian source area for most of the lower Cambrian Dividal Group sediments. The <sup>176</sup>Hf/<sup>177</sup>Hf isotope data show the Ediacaran zircons to be derived from two separate plutonic complexes within the Timanides. It is argued that the Dividal Group sediments were deposited in a foreland basin south and SW of the Timanide Orogen. Similarities with clastic zircon age populations from Cambrian deposits in Akkajaure, Ladoga/White Sea and St Petersburg areas indicate that this foreland basin possibly extended southward for at least 1000 km. A foreland basin setting for the Ediacaran and Cambrian deposits in Central and Southern Scandinavia can thus account for the enigmatic Neoproterozoic detrital zircons in these deposits.
DOI: 10.6084/m9.figshare.3453674
title: Relief variation and erosion of the Variscan belt: detrital geochronology of the Palaeozoic sediments from the Mauges Unit (Armorican Massif, France)

description: The sediments of the Mauges Unit located in the internal zone provide an opportunity of studying the evolution of relief during Palaeozoic time. U–Pb dating on zircon and <sup>39</sup>Ar/<sup>40</sup>Ar on white mica are used to constrain the age and nature of the sources. The first relief identified is marked by an Early Devonian unconformity interpreted as the opening of a northern back-arc basin. Detrital minerals are first reworked from underlying layers indicating a local supply. Magmatic zircons at <em>c.</em> 400 Ma then record the emergence of a magmatic arc. During the Middle Devonian, the gap in the sedimentary record is attributed to an emersion followed by the disappearance of the relief during the Late Devonian. At the Devonian–Carboniferous boundary, the main collision is followed by the onset of a relief. The continental sedimentation in the Ancenis Basin (late Tournaisian–Viséan) is a coarsening-upwards megasequence indicating an increasing and/or approaching relief. The detrital minerals record the progressive exhumation of Variscan metamorphic (mica at <em>c.</em> 350 Ma) and magmatic rocks (zircons at <em>c.</em> 390–340 Ma). The Serpukhovian–Bashkirian sedimentation records the erosion of a proximal metamorphic source (Champtoceaux with micas at <em>c.</em> 350–340 Ma) showing a much shorter drainage system.
DOI: 10.6084/m9.figshare.3453674.v1
title: Relief variation and erosion of the Variscan belt: detrital geochronology of the Palaeozoic sediments from the Mauges Unit (Armorican Massif, France)

description: The sediments of the Mauges Unit located in the internal zone provide an opportunity of studying the evolution of relief during Palaeozoic time. U–Pb dating on zircon and <sup>39</sup>Ar/<sup>40</sup>Ar on white mica are used to constrain the age and nature of the sources. The first relief identified is marked by an Early Devonian unconformity interpreted as the opening of a northern back-arc basin. Detrital minerals are first reworked from underlying layers indicating a local supply. Magmatic zircons at <em>c.</em> 400 Ma then record the emergence of a magmatic arc. During the Middle Devonian, the gap in the sedimentary record is attributed to an emersion followed by the disappearance of the relief during the Late Devonian. At the Devonian–Carboniferous boundary, the main collision is followed by the onset of a relief. The continental sedimentation in the Ancenis Basin (late Tournaisian–Viséan) is a coarsening-upwards megasequence indicating an increasing and/or approaching relief. The detrital minerals record the progressive exhumation of Variscan metamorphic (mica at <em>c.</em> 350 Ma) and magmatic rocks (zircons at <em>c.</em> 390–340 Ma). The Serpukhovian–Bashkirian sedimentation records the erosion of a proximal metamorphic source (Champtoceaux with micas at <em>c.</em> 350–340 Ma) showing a much shorter drainage system.
DOI: 10.6084/m9.figshare.3453671
title: Timing of granite emplacement, crustal flow and gneiss dome formation in the Variscan segment of the Pyrenees

description: The Variscan segment of the Pyrenees is well suited to study the timing of crustal-scale deformations as crustal flow and gneiss dome formation. This has been constrained from a synthesis of available structural and geochronological data of intrusive rocks, as well as new zircon U–Pb age determinations via laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS). After a stage of moderate thickening by fold–thrust belt development in the upper crust between 323 and 308 Ma, the Variscan segment of the Pyrenees experienced crustal flow at <em>c.</em> 306 Ma and then gneiss dome formation at <em>c.</em> 304 Ma. Localization of the deformation along reverse-dextral shear zones occurred at <em>c.</em> 300 Ma. The Variscan segment of the Pyrenees recorded a high-temperature regime, which allowed crustal flow of the middle crust, but with limited amounts of heat which induced rapid cooling. The development of this enigmatic orogenic segment of the Variscan belt is closely contemporaneous with the formation of the Cantabrian Orocline and could correspond to a lithospheric-scale shear zone that accommodated buckling of the orocline. Late Variscan lithospheric delamination and asthenospheric upwelling associated with buckling in the core of the Cantabrian Orocline could explain the short-period high-temperature regime in the Variscan segment of the Pyrenees.
DOI: 10.6084/m9.figshare.3453671.v1
title: Timing of granite emplacement, crustal flow and gneiss dome formation in the Variscan segment of the Pyrenees

description: The Variscan segment of the Pyrenees is well suited to study the timing of crustal-scale deformations as crustal flow and gneiss dome formation. This has been constrained from a synthesis of available structural and geochronological data of intrusive rocks, as well as new zircon U–Pb age determinations via laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS). After a stage of moderate thickening by fold–thrust belt development in the upper crust between 323 and 308 Ma, the Variscan segment of the Pyrenees experienced crustal flow at <em>c.</em> 306 Ma and then gneiss dome formation at <em>c.</em> 304 Ma. Localization of the deformation along reverse-dextral shear zones occurred at <em>c.</em> 300 Ma. The Variscan segment of the Pyrenees recorded a high-temperature regime, which allowed crustal flow of the middle crust, but with limited amounts of heat which induced rapid cooling. The development of this enigmatic orogenic segment of the Variscan belt is closely contemporaneous with the formation of the Cantabrian Orocline and could correspond to a lithospheric-scale shear zone that accommodated buckling of the orocline. Late Variscan lithospheric delamination and asthenospheric upwelling associated with buckling in the core of the Cantabrian Orocline could explain the short-period high-temperature regime in the Variscan segment of the Pyrenees.