cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.6084/m9.figshare.5669020.v1
title: Developing Fast and Facile Method for Speciation Analysis of Vanadium (V/IV) Ions with Calmagite Immobilization on Triacetyl Cellulose Membrane in Water Samples

description: An inexpensive and fast vanadium [(IV), (V)] speciation method was performed by using optical chemical sensor that incorporates lipophilized calmagite (Cal) with cetyl pyridinium chloride (CPC) as a suitable ligand on triacetylcellulose membrane in aqueous solutions prior to UV-Vis spectrometric determination. Absorbance decrease of the optode in pH 6 at 490 nm depended on the V(V) ion concentration. The V(IV) content was found after oxidation to V(V) at the mentioned conditions. Two aliquots of sample were used for speciative determination of V(V) and V(V) + V(IV) mixture. With the optimized proposed sensor V(V) and V(IV) can be assayed with detection limits of 0.002 and 0.003 nmol L−1, respectively. The optode was tested by analysing several mixtures containing different ratios of V(V) + V(IV) and was found to be highly reproducible. The validity of the method was checked via spiked water samples with total relative standard error less than 4%.
DOI: 10.6084/m9.figshare.5669017
title: Hypertriglyceridemic waist phenotype and nutritional factors: a study with participants of ELSA-Brasil

description: ABSTRACT: Objective: To investigate the association between fat and fiber intakes and the hypertriglyceridemic waist phenotype (HWP). Methods: Cross-sectional survey conducted from the baseline of Brazilian Longitudinal Study of Health Adult (ELSA-Brasil). Anthropometric measurements were conducted and the body mass index was calculated (BMI). Participants were classified according to the presence of HWP when waist circumference ≥ 102 and ≥ 88 cm, respectively, in men and women, and triglycerides ≥ 150 mg/dL. Fat and fiber intakes were assessed using a validated food frequency questionnaire, and socioeconomic, demographic and behavioral variables were collected through a questionnaire. The χ² test, Mann-Whitney and Poisson regression were performed with significance level of 5%. Results: There was no association between fiber and fat intakes with HWP. A lower prevalence of HWP among men was observed (IRR = 0.959; 95%CI 0.948 - 0.969). A higher prevalence of HWP was observed in participants with low physical activity (OR = 1.039, 95%CI 1.021 - 1.057), smoking history (OR = 1.044, 95%CI 1.031 - 1.057), lower per capita income (IRR = 1.035; 95%CI 1.022 - 1.049) and obesity (OR = 1.32, 95%CI 1.305 - 1.341). Fat and fiber intakes were not associated with HWP. Conclusion: A higher prevalence of HWP was found in obese, but no association was found between intake of fat and fiber and phenotype.
DOI: 10.6084/m9.figshare.5669017.v1
title: Hypertriglyceridemic waist phenotype and nutritional factors: a study with participants of ELSA-Brasil

description: ABSTRACT: Objective: To investigate the association between fat and fiber intakes and the hypertriglyceridemic waist phenotype (HWP). Methods: Cross-sectional survey conducted from the baseline of Brazilian Longitudinal Study of Health Adult (ELSA-Brasil). Anthropometric measurements were conducted and the body mass index was calculated (BMI). Participants were classified according to the presence of HWP when waist circumference ≥ 102 and ≥ 88 cm, respectively, in men and women, and triglycerides ≥ 150 mg/dL. Fat and fiber intakes were assessed using a validated food frequency questionnaire, and socioeconomic, demographic and behavioral variables were collected through a questionnaire. The χ² test, Mann-Whitney and Poisson regression were performed with significance level of 5%. Results: There was no association between fiber and fat intakes with HWP. A lower prevalence of HWP among men was observed (IRR = 0.959; 95%CI 0.948 - 0.969). A higher prevalence of HWP was observed in participants with low physical activity (OR = 1.039, 95%CI 1.021 - 1.057), smoking history (OR = 1.044, 95%CI 1.031 - 1.057), lower per capita income (IRR = 1.035; 95%CI 1.022 - 1.049) and obesity (OR = 1.32, 95%CI 1.305 - 1.341). Fat and fiber intakes were not associated with HWP. Conclusion: A higher prevalence of HWP was found in obese, but no association was found between intake of fat and fiber and phenotype.
DOI: 10.6084/m9.figshare.5669014
title: Characterization of the Mandible Atta Laevigata and the Bioinspiration for the Development of a Biomimetic Surgical Clamp

description: Approximately thousand years ago it was reported the use of mandibles of ants for suture. In this sense, bioinspired components, as absorbable surgical clamps, can be designed. This study is aimed to characterize the mandible of the ant Atta laevigata in order to help the selection of candidate biomaterials for application as surgical clamps. Three pairs of mandibles were used and ten nanoindenations were performed in each pair. The average hardness for the samples in the internal and external regions were 0.36 ± 0.06 GPa and 0.19 ± 0.04 GPa, respectively and the average elastic modulus for the internal and external regions were 6.16 ± 0.23 GPa and 2.74 ± 0.44 GPa, respectively. The morphology of the mandible was observed in detail by scanning electron microscopy, as well as Energy-dispersive X-ray spectroscopy. The average roughnesses on the internal and external regions, measured by atomic force microscopy, were 6.73 ± 0.90 nm and 11.87 ± 1.42 nm, respectively. From these results, it was possible to identify biomaterials that mimic the mandible behaviour for surgical clamp.
DOI: 10.6084/m9.figshare.5669014.v1
title: Characterization of the Mandible Atta Laevigata and the Bioinspiration for the Development of a Biomimetic Surgical Clamp

description: Approximately thousand years ago it was reported the use of mandibles of ants for suture. In this sense, bioinspired components, as absorbable surgical clamps, can be designed. This study is aimed to characterize the mandible of the ant Atta laevigata in order to help the selection of candidate biomaterials for application as surgical clamps. Three pairs of mandibles were used and ten nanoindenations were performed in each pair. The average hardness for the samples in the internal and external regions were 0.36 ± 0.06 GPa and 0.19 ± 0.04 GPa, respectively and the average elastic modulus for the internal and external regions were 6.16 ± 0.23 GPa and 2.74 ± 0.44 GPa, respectively. The morphology of the mandible was observed in detail by scanning electron microscopy, as well as Energy-dispersive X-ray spectroscopy. The average roughnesses on the internal and external regions, measured by atomic force microscopy, were 6.73 ± 0.90 nm and 11.87 ± 1.42 nm, respectively. From these results, it was possible to identify biomaterials that mimic the mandible behaviour for surgical clamp.
DOI: 10.6084/m9.figshare.5669011
title: Comparative Study of Microstructure, Texture, and Formability Between 11CrTi and 11CrTi+Nb ASTM 409 Ferritic Stainless Steel

description: Stabilization of ferritic stainless steel ASTM 409, for use in automobile exhaust systems, is increasingly in demand, due to higher exhaust gas temperatures. Ti is one of the most commonly used elements. However, high concentrations cause problems during steel casting; however, stabilization with Ti and Nb represents a good alternative. The present study aims to investigate the effect of adding Nb on the microstructure, texture, and forming properties of Ti-stabilized ferritic steels. The results demonstrated that Nb-addition leads to a more deformed microstructure after hot rolling with the strongest {110}〈001〉 Goss component. In the deformed state, the steels displayed the α-fiber, but 11CrTi+Nb steel showed a more intense γ-fiber. After annealing, Nb-addition led to an increase in the γ-fiber and in average normal coefficient of anisotropy (R). Thus, it was demonstrated that the dual stabilization (Ti+Nb) of the ferritic steel was responsible for improving the recrystallization texture and forming proprieties.
DOI: 10.6084/m9.figshare.5669011.v1
title: Comparative Study of Microstructure, Texture, and Formability Between 11CrTi and 11CrTi+Nb ASTM 409 Ferritic Stainless Steel

description: Stabilization of ferritic stainless steel ASTM 409, for use in automobile exhaust systems, is increasingly in demand, due to higher exhaust gas temperatures. Ti is one of the most commonly used elements. However, high concentrations cause problems during steel casting; however, stabilization with Ti and Nb represents a good alternative. The present study aims to investigate the effect of adding Nb on the microstructure, texture, and forming properties of Ti-stabilized ferritic steels. The results demonstrated that Nb-addition leads to a more deformed microstructure after hot rolling with the strongest {110}〈001〉 Goss component. In the deformed state, the steels displayed the α-fiber, but 11CrTi+Nb steel showed a more intense γ-fiber. After annealing, Nb-addition led to an increase in the γ-fiber and in average normal coefficient of anisotropy (R). Thus, it was demonstrated that the dual stabilization (Ti+Nb) of the ferritic steel was responsible for improving the recrystallization texture and forming proprieties.
DOI: 10.6084/m9.figshare.5669008
title: Determination of the pi (π) number through square net of identical resistors

description: The number π is generally described as the value obtained from the perimeter per diameter ratio of a circumference. But this number appears in various circumstances in the sciences in general, especially when a system has periodicity. In this work we present a way to obtain this mathematical constant experimentally by measuring the equivalent resistance in an resistors infinite square grid. Measurements were made throughout the fabrication process using real resistors and simulating them in an online application. The measurements show that the greater the number of layers of the mesh, the closer the value of π is reached. We will also present other alternative ways of performing such an experiment.
DOI: 10.6084/m9.figshare.5669005
title: Health-related quality of life of patients of Brazilian primary health care

description: ABSTRACT OBJECTIVE To analyze the Health-Related Quality of Life (HRQoL) of patients of the primary health care of the Brazilian Unified Health System (SUS) and its associated factors. METHODS This is a cross-sectional study with data from the Pesquisa Nacional sobre Acesso, Utilização e Promoção do Uso Racional de Medicamentos – Serviços, 2015 (PNAUM – National Survey on Access, Use and Promotion of Rational Use of Medicines – Services, 2015). Data were collected with a questionnaire that included the EuroQol 5 Dimensions (EQ-5D) instrument. Patients from the five regions of Brazil were interviewed. Multiple linear regression was used to analyze their Health-Related Quality of Life and its associated factors. RESULTS Of the total of 8,590 patients, the most frequent dimensions were pain/discomfort (50.7%) and anxiety/depression (38.8%). About 10% of the patients reported extreme problems in these dimensions. The following factors were significantly associated with a worse quality of life: being female; having arthritis, osteoarthritis, or rheumatism; cerebrovascular accident; heart disease; depression; health self-assessment as poor or very poor; drinking alcoholic beverages once or more per month; dieting to lose weight, avoiding salt consumption, and reducing fat intake. Significant association was observed between a better quality of life and: living in the North and Southeast regions of Brazil; practicing physical activities; and having a higher educational level. No association was observed with factors related to the health services. CONCLUSIONS The Health-Related Quality of Life of patients was influenced by demographic and socioeconomic factors that were related to health conditions and lifestyle, being useful to guide specific actions for promoting health and the integral care to patients of the Brazilian Unified Health System.
DOI: 10.6084/m9.figshare.5669005.v1
title: Health-related quality of life of patients of Brazilian primary health care

description: ABSTRACT OBJECTIVE To analyze the Health-Related Quality of Life (HRQoL) of patients of the primary health care of the Brazilian Unified Health System (SUS) and its associated factors. METHODS This is a cross-sectional study with data from the Pesquisa Nacional sobre Acesso, Utilização e Promoção do Uso Racional de Medicamentos – Serviços, 2015 (PNAUM – National Survey on Access, Use and Promotion of Rational Use of Medicines – Services, 2015). Data were collected with a questionnaire that included the EuroQol 5 Dimensions (EQ-5D) instrument. Patients from the five regions of Brazil were interviewed. Multiple linear regression was used to analyze their Health-Related Quality of Life and its associated factors. RESULTS Of the total of 8,590 patients, the most frequent dimensions were pain/discomfort (50.7%) and anxiety/depression (38.8%). About 10% of the patients reported extreme problems in these dimensions. The following factors were significantly associated with a worse quality of life: being female; having arthritis, osteoarthritis, or rheumatism; cerebrovascular accident; heart disease; depression; health self-assessment as poor or very poor; drinking alcoholic beverages once or more per month; dieting to lose weight, avoiding salt consumption, and reducing fat intake. Significant association was observed between a better quality of life and: living in the North and Southeast regions of Brazil; practicing physical activities; and having a higher educational level. No association was observed with factors related to the health services. CONCLUSIONS The Health-Related Quality of Life of patients was influenced by demographic and socioeconomic factors that were related to health conditions and lifestyle, being useful to guide specific actions for promoting health and the integral care to patients of the Brazilian Unified Health System.
DOI: 10.6084/m9.figshare.5669002
title: Non-Thermal Plasma Induced Total Mineralization of Glyphosate in Water in the Presence of Iron II Ions

description: The present work focused on the mineralization of herbicide glyphosate (N-(phosphonomethyl) glycine) (C3H8NO5P) in aqueous phase by Glidarc plasma following the orthophosphates released and the reduction of the total organic carbon (TOC). Furthermore, the effect of initial concentration, pH and the degradation process of glyphosate in the presence of Fe2+ were also examined. The results showed that the efficiency of degradation increased with the presence of ferrous ions as catalysts in aqueous medium and also the release of orthophosphate is more efficient in acid medium with pH range of 3.5-6.3. The kinetics of the release of orthophosphate and the TOC removal obey the first order rate law. The ninhydrin and orthophosphates tests showed that the degradation of glyphosate in water by Glidarc plasma was mainly by OH and NO attacked with C–N and C–P bond cleavage leading to complete mineralization.
DOI: 10.6084/m9.figshare.5668999
title: Sulfonation degree effect on ion-conducting SPEEK-titanium oxide membranes properties

description: Abstract Polymeric membranes were developed using a SPEEK (sulfonated poly(ether ether ketone)) polymer matrix, containing titanium oxide (TiO2) (incorporated by sol-gel method). SPEEK with different sulfonation degrees (SD): 63% and 50% were used. The influence of sulfonation degree on membrane properties was investigated. The thermal analysis (TGA and DTGA) and X-ray diffraction (XRD) were carried out to characterize the membranes and electrochemical impedance spectroscopy (EIS) was carried out to evaluate the proton conductivity of the membranes. The proton conductivities in water were of 3.25 to 37.08 mS.cm-1. Experimental data of impedance spectroscopy were analyzed with equivalent circuits using the Zview software, and the results showed that, the best fitted was at 80 °C.
DOI: 10.6084/m9.figshare.5669002.v1
title: Non-Thermal Plasma Induced Total Mineralization of Glyphosate in Water in the Presence of Iron II Ions

description: The present work focused on the mineralization of herbicide glyphosate (N-(phosphonomethyl) glycine) (C3H8NO5P) in aqueous phase by Glidarc plasma following the orthophosphates released and the reduction of the total organic carbon (TOC). Furthermore, the effect of initial concentration, pH and the degradation process of glyphosate in the presence of Fe2+ were also examined. The results showed that the efficiency of degradation increased with the presence of ferrous ions as catalysts in aqueous medium and also the release of orthophosphate is more efficient in acid medium with pH range of 3.5-6.3. The kinetics of the release of orthophosphate and the TOC removal obey the first order rate law. The ninhydrin and orthophosphates tests showed that the degradation of glyphosate in water by Glidarc plasma was mainly by OH and NO attacked with C–N and C–P bond cleavage leading to complete mineralization.
DOI: 10.6084/m9.figshare.5668999.v1
title: Sulfonation degree effect on ion-conducting SPEEK-titanium oxide membranes properties

description: Abstract Polymeric membranes were developed using a SPEEK (sulfonated poly(ether ether ketone)) polymer matrix, containing titanium oxide (TiO2) (incorporated by sol-gel method). SPEEK with different sulfonation degrees (SD): 63% and 50% were used. The influence of sulfonation degree on membrane properties was investigated. The thermal analysis (TGA and DTGA) and X-ray diffraction (XRD) were carried out to characterize the membranes and electrochemical impedance spectroscopy (EIS) was carried out to evaluate the proton conductivity of the membranes. The proton conductivities in water were of 3.25 to 37.08 mS.cm-1. Experimental data of impedance spectroscopy were analyzed with equivalent circuits using the Zview software, and the results showed that, the best fitted was at 80 °C.
DOI: 10.6084/m9.figshare.5668993
title: Influence of physical attributes and pedotransfer function for predicting water retention in management systems

description: ABSTRACT The aims of this study were to evaluate the effects of the soil structural physical attributes on the water retention and to develop pedotransfer functions (PTFs) for the estimation of the soil water content (θ) at different matric potentials of a Dystrophic Red Latosol (Hapludox) under conventional tillage (CT) and no-tillage (NT) soil management systems. The effects of long-term CT and NT (over 25 years) management on the soil bulk density (BD), total porosity (TP), macroporosity (Ma), microporosity (Mi) and water retention were investigated. The PTFs were developed to predict θ and used to evaluate the soil water retention curve only for the NT system. The NT system was characterized by smaller values of the soil BD and higher values of the soil TP and Mi than the CT system. The NT system exhibited a higher θ retained than the CT system for the pore-size interval of 0.2–30 μm. However, the CT system exhibited a large amount of water retention for pores smaller than 0.2 μm. The PTFs were utilized to estimate θ at matric potentials of -1, -3, -6, -10, -33, -100, -400, -800, and -1,500 kPa with adequate accuracy. The soil BD, Ma, Mi and sand content were the main variables considered to estimate θ for the different matric potentials evaluated.
DOI: 10.6084/m9.figshare.5668993.v1
title: Influence of physical attributes and pedotransfer function for predicting water retention in management systems

description: ABSTRACT The aims of this study were to evaluate the effects of the soil structural physical attributes on the water retention and to develop pedotransfer functions (PTFs) for the estimation of the soil water content (θ) at different matric potentials of a Dystrophic Red Latosol (Hapludox) under conventional tillage (CT) and no-tillage (NT) soil management systems. The effects of long-term CT and NT (over 25 years) management on the soil bulk density (BD), total porosity (TP), macroporosity (Ma), microporosity (Mi) and water retention were investigated. The PTFs were developed to predict θ and used to evaluate the soil water retention curve only for the NT system. The NT system was characterized by smaller values of the soil BD and higher values of the soil TP and Mi than the CT system. The NT system exhibited a higher θ retained than the CT system for the pore-size interval of 0.2–30 μm. However, the CT system exhibited a large amount of water retention for pores smaller than 0.2 μm. The PTFs were utilized to estimate θ at matric potentials of -1, -3, -6, -10, -33, -100, -400, -800, and -1,500 kPa with adequate accuracy. The soil BD, Ma, Mi and sand content were the main variables considered to estimate θ for the different matric potentials evaluated.
DOI: 10.6084/m9.figshare.5668987
title: Impact of Ni Substitution on Structural, Electrical and Thermoelectrical Properties of Zinc Alluminium Chromites Synthesized by sol-gel Route and their Photocatalytic Investigation

description: Nanostructured nickel substituted zinc alluminium chromites (Zn1-xNixAlCrO4, where, x= 0.0, 0.25, 0.50, 0.75, 1.0) were prepared by simple, cost effective, sol-gel autocombustion method. Temperature of phase formation was analyzed by thermogravimetric and differential thermal analysis (TGA/DTA). Crystallographic studies of all the samples show formation of single cubic spinel phase only. The lattice parameter, crystallite size and X-ray density decreases with increase in Nickel content. The surface morphology of Zn1-xNixAlCrO4 shows spherical interlinked morphology while elemental studies show desired composition. The nanosize of the synthesized material was confirmed by transmission electron microscopy (TEM) which was lies in between 19-25 nm. The DC conductivity as well as thermoelectric power studies of the samples reveals their semiconducting nature. The nanocrystalline chromite has optimal charge separation, which make them to enhance their photocatalytic efficiency. 0.100gm palladium loaded nickel alluminium chromite shows excellent mineralization in water.
DOI: 10.6084/m9.figshare.5668987.v1
title: Impact of Ni Substitution on Structural, Electrical and Thermoelectrical Properties of Zinc Alluminium Chromites Synthesized by sol-gel Route and their Photocatalytic Investigation

description: Nanostructured nickel substituted zinc alluminium chromites (Zn1-xNixAlCrO4, where, x= 0.0, 0.25, 0.50, 0.75, 1.0) were prepared by simple, cost effective, sol-gel autocombustion method. Temperature of phase formation was analyzed by thermogravimetric and differential thermal analysis (TGA/DTA). Crystallographic studies of all the samples show formation of single cubic spinel phase only. The lattice parameter, crystallite size and X-ray density decreases with increase in Nickel content. The surface morphology of Zn1-xNixAlCrO4 shows spherical interlinked morphology while elemental studies show desired composition. The nanosize of the synthesized material was confirmed by transmission electron microscopy (TEM) which was lies in between 19-25 nm. The DC conductivity as well as thermoelectric power studies of the samples reveals their semiconducting nature. The nanocrystalline chromite has optimal charge separation, which make them to enhance their photocatalytic efficiency. 0.100gm palladium loaded nickel alluminium chromite shows excellent mineralization in water.