cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.6084/m9.figshare.5666698.v1
title: Simulation of wheat biomass yield by thermal time, rainfall and nitrogen

description: ABSTRACT Wheat biomass yield focused on the production of quality silage is dependent on rainfall, temperature and nitrogen (N). The objective of the study was to validate the use of rainfall, thermal time and N as potential variables for the composition of the multiple linear regression model and simulation of wheat biomass yield for silage production under N supply conditions during the cycle, in the systems of succession. The study was conducted in 2012, 2013 and 2014, in randomized blocks with four replicates in 4 x 3 factorial, for N-fertilizer doses (0, 30, 60, 120 kg ha-1) and forms of N supply [single application (100%) in the stage V3 (third expanded leaf); split application (70%/30%) in the stages V3/V6 (third and sixth expanded leaves); split application (70%/30%) in the stages V3/E (third expanded leaf and beginning of grain filling)], respectively, in the systems soybean/wheat and maize/wheat. Rainfall and N are potential variables in the composition of the multiple linear regression model. Multiple linear regression models are efficient in the simulation of wheat biomass yield for silage under the N supply conditions during the cycle in the succession systems.
DOI: 10.6084/m9.figshare.5666695
title: Hepatozoon canis and Leishmania spp. coinfection in dogs diagnosed with visceral leishmaniasis

description: Abstract This study describes the occurrence of dogs naturally co-infected with Hepatozoon canis and two Leishmania species: L. infantum or L. braziliensis. Four dogs serologically diagnosed with Visceral Leishmaniasis were euthanized. Liver and spleen samples were collected for histopathological analysis and DNA isolation. H. canis meronts were observed in tissues from all four dogs. H. canis infection was confirmed by PCR followed by sequencing of a fragment of 18S rRNA gene. Leishmania detection and typing was confirmed by ITS1' PCR-RFLP and parasite burden was calculated using ssrRNA quantitative qPCR. A DPP - Dual Path platform test was performed. One out (Dog #2) of four animals was asymptomatic. Dogs #1 and #4 were infected by L. infantum and were DPP test positive. Dogs #2 and #3 were infected by L. braziliensis and were DPP test negative. Furthermore, visceral dissemination was observed in Dogs #2 and #3, since L. braziliensis was detected in liver and spleen samples. The visceral dissemination of L. braziliensis associated with systemic signs suggested that this co-infection could influence the parasite burden and disease progression.
DOI: 10.6084/m9.figshare.5666695.v1
title: Hepatozoon canis and Leishmania spp. coinfection in dogs diagnosed with visceral leishmaniasis

description: Abstract This study describes the occurrence of dogs naturally co-infected with Hepatozoon canis and two Leishmania species: L. infantum or L. braziliensis. Four dogs serologically diagnosed with Visceral Leishmaniasis were euthanized. Liver and spleen samples were collected for histopathological analysis and DNA isolation. H. canis meronts were observed in tissues from all four dogs. H. canis infection was confirmed by PCR followed by sequencing of a fragment of 18S rRNA gene. Leishmania detection and typing was confirmed by ITS1' PCR-RFLP and parasite burden was calculated using ssrRNA quantitative qPCR. A DPP - Dual Path platform test was performed. One out (Dog #2) of four animals was asymptomatic. Dogs #1 and #4 were infected by L. infantum and were DPP test positive. Dogs #2 and #3 were infected by L. braziliensis and were DPP test negative. Furthermore, visceral dissemination was observed in Dogs #2 and #3, since L. braziliensis was detected in liver and spleen samples. The visceral dissemination of L. braziliensis associated with systemic signs suggested that this co-infection could influence the parasite burden and disease progression.
DOI: 10.6084/m9.figshare.5666692
title: Determination of Selenium in Bovine Semen by ICP-MS Using Formic Acid for Sample Preparation

description: Determination of Se by inductively coupled plasma mass spectrometry (ICP-MS) can be difficult due to spectral interferences; however, these interferences can be eliminated by using collision-reaction interface (CRI) technology. A simple and fast procedure for determination of total Se concentration in bovine semen by ICP-MS after sample solubilization with diluted formic acid is here proposed. Formic acid caused an increase of up to 50% in selenium net signals and the maximum gain was obtained at 10% v v-1 formic acid solution. The optimized nebulizer gas flow rates were 1.05 and 0.95 L min-1, and radio frequency applied power were 1.3 and 1.4 kW without and with CRI, respectively. Microwave-assisted acid digestion was also implemented in the preparation of semen sample for comparison of results. No statistical differences between these sample preparation strategies at 95% confidence level (t-test) were observed for 76Se+, 77Se+, 78Se+ and 82Se+ without using CRI and 82Se+ with CRI.
DOI: 10.6084/m9.figshare.5666692.v1
title: Determination of Selenium in Bovine Semen by ICP-MS Using Formic Acid for Sample Preparation

description: Determination of Se by inductively coupled plasma mass spectrometry (ICP-MS) can be difficult due to spectral interferences; however, these interferences can be eliminated by using collision-reaction interface (CRI) technology. A simple and fast procedure for determination of total Se concentration in bovine semen by ICP-MS after sample solubilization with diluted formic acid is here proposed. Formic acid caused an increase of up to 50% in selenium net signals and the maximum gain was obtained at 10% v v-1 formic acid solution. The optimized nebulizer gas flow rates were 1.05 and 0.95 L min-1, and radio frequency applied power were 1.3 and 1.4 kW without and with CRI, respectively. Microwave-assisted acid digestion was also implemented in the preparation of semen sample for comparison of results. No statistical differences between these sample preparation strategies at 95% confidence level (t-test) were observed for 76Se+, 77Se+, 78Se+ and 82Se+ without using CRI and 82Se+ with CRI.
DOI: 10.6084/m9.figshare.5666689
title: Cowper-Symonds parameters estimation for ABS material using design of experiments with finite element simulation

description: Abstract Polymers exhibit significant strain rate dependence in their mechanical strength. The impact simulations accuracy is associated with the use of mechanical properties obtained at high strain rates. These properties are often not available to engineers introducing a risk on the product development step. This paper presents a method for adjusting the parameters of the Cowper-Symonds, used for a constitutive material model, through computational experiments carried out considering the simulation of the Izod impact test.The proposed adjustment method allows reducing the Izod impact strength error from 44% to 2.4%.
DOI: 10.6084/m9.figshare.5666689.v1
title: Cowper-Symonds parameters estimation for ABS material using design of experiments with finite element simulation

description: Abstract Polymers exhibit significant strain rate dependence in their mechanical strength. The impact simulations accuracy is associated with the use of mechanical properties obtained at high strain rates. These properties are often not available to engineers introducing a risk on the product development step. This paper presents a method for adjusting the parameters of the Cowper-Symonds, used for a constitutive material model, through computational experiments carried out considering the simulation of the Izod impact test.The proposed adjustment method allows reducing the Izod impact strength error from 44% to 2.4%.
DOI: 10.6084/m9.figshare.5666686.v1
title: Interpreting a Pareto set of operating options for water grids: a framework and case study

description: Multi-objective optimisation is being increasingly applied in water supply management to identify optimal operating options. However, a key challenge in the implementation of multi-objective optimisation is interpreting the large and multidimensional Pareto-optimal set. This paper shows how cluster, visual and post-optimisation analysis can aid the decision maker in addressing this challenge. This is demonstrated for a case study based on South East Queensland Water Grid, Australia, as part of a broader operational planning framework. Firstly, cluster analysis identifies a smaller set of representative options to aid in visual analysis. Secondly, visual analysis techniques are used to identify the trade-offs between objectives, the relationships between decision variables and objective performance, and to shortlist promising operating options. Finally, post-optimisation analysis techniques identify efficient operating options from the Pareto set, based on decision-maker preferences. Together these techniques can be used to identify a shortlist of operating options, for further consideration using multicriteria analysis.
DOI: 10.6084/m9.figshare.5666683
title: Application of Response Surface Modeling and Chemometrics Methods for the Determination of Ofloxacin in Human Urine Using Dispersive Liquid-Liquid Microextraction Combined with Spectrofluorimetry

description: Dispersive liquid-liquid microextraction (DLLME) and spectrofluorimetry, coupled with chemometrics methods, are proposed in this work for the pre-concentration and determination of ofloxacin concentration in spiked human urine. Chloroform and acetonitrile were selected as the extraction and dispersive solvents by the one-variable-at-a-time process. The Box-Behnken design was used to optimize the other variables, including the volume of extraction and dispersion solvents, solution pH, and ionic strength. A linear calibration curve was obtained in the 5.0-120.0 ng mL-1 range under optimal conditions with a detection limit of 1.61 ng mL-1 and correlation coefficient of 0.9948. A relative standard deviation (RSD) of 1.13% was obtained for seven consecutive replicates. Parallel factor analysis (PARAFAC) and partial least square (PLS) modeling were applied for the multivariate calibration of the spectrofluorimetric data. To pre-process the data matrices and predict the model results, the orthogonal signal correction (OSC) was used, and the analysis results were statistically compared. The methods accuracy values for ofloxacin determination, evaluated by the root mean square errors of prediction (RMSEP) and relative standard error of prediction (RSEP), were 0.82 and 1.12 using OSC-PLS, and 0.31 and 0.42 using OSC-PARAFAC models, respectively. Ofloxacin can be reliably determined in human urine samples through the proposed procedure, according to the results.
DOI: 10.6084/m9.figshare.5666680
title: Carbon nanotube buckypaper reinforced polymer composites: a review

description: Abstract This review provides valuable information about the general characteristics, processing conditions and physical properties of carbon nanotube buckypaper (BP) and its polymer composites. Vacuum filtration is the most common technique used for manufacturing BP, since the carbon nanotubes are dispersed in aqueous solution with the aid of surfactant. Previous works have reported that mechanical properties of BP prepared by vacuum filtration technique are relatively weak. On the other hand, the incorporation of polymer materials in those nanostructures revealed a significant improvement in their mechanical behavior, since the impregnation between matrix and BP is optimized. Electrical conductivity of BP/polymer composites can reach values as high as 2000 S/m, which are several orders of magnitude greater than traditional CNT/polymer composites. Also, BP can improve remarkably the thermal stability of polymer matrices, opening new perspectives to use this material in fire retardant applications.
DOI: 10.6084/m9.figshare.5666677
title: Evaluation of Distribution and Bioaccumulation of Arsenic by ICP-MS in Tilapia (Oreochromis niloticus) Cultivated in Different Environments

description: The concentration of arsenic in tissues of tilapia was evaluated and an estimation of the risks associated with the consumption of this fish was done, taking into account the guidelines established by FAO/WHO. The inductively coupled plasma mass spectrometry (ICP-MS) technique in kinetic energy discrimination (KED) mode was employed and certified reference materials were analyzed with recoveries of 101, 110, and 80% from NIST 1640a (trace elements in water), NIST 1566b (oyster tissue), and DORM-3 (fish protein). In the consumable portion (the muscle fish tissue), the average concentration found was 0.030 ± 0.008 µg g-1, which is below the arsenic maximum level established by international regulatory agencies. The average concentration found in the viscera (stomach, gills, and liver) was 0.485 ± 0.225 µg g-1, concluding that the viscera had greater capacity for the bioaccumulation of arsenic. From this study was possible to monitor the arsenic element in different tilapia specimens evidencing its accumulation throughout the body of the fish.
DOI: 10.6084/m9.figshare.5666680.v1
title: Carbon nanotube buckypaper reinforced polymer composites: a review

description: Abstract This review provides valuable information about the general characteristics, processing conditions and physical properties of carbon nanotube buckypaper (BP) and its polymer composites. Vacuum filtration is the most common technique used for manufacturing BP, since the carbon nanotubes are dispersed in aqueous solution with the aid of surfactant. Previous works have reported that mechanical properties of BP prepared by vacuum filtration technique are relatively weak. On the other hand, the incorporation of polymer materials in those nanostructures revealed a significant improvement in their mechanical behavior, since the impregnation between matrix and BP is optimized. Electrical conductivity of BP/polymer composites can reach values as high as 2000 S/m, which are several orders of magnitude greater than traditional CNT/polymer composites. Also, BP can improve remarkably the thermal stability of polymer matrices, opening new perspectives to use this material in fire retardant applications.
DOI: 10.6084/m9.figshare.5666677.v1
title: Evaluation of Distribution and Bioaccumulation of Arsenic by ICP-MS in Tilapia (Oreochromis niloticus) Cultivated in Different Environments

description: The concentration of arsenic in tissues of tilapia was evaluated and an estimation of the risks associated with the consumption of this fish was done, taking into account the guidelines established by FAO/WHO. The inductively coupled plasma mass spectrometry (ICP-MS) technique in kinetic energy discrimination (KED) mode was employed and certified reference materials were analyzed with recoveries of 101, 110, and 80% from NIST 1640a (trace elements in water), NIST 1566b (oyster tissue), and DORM-3 (fish protein). In the consumable portion (the muscle fish tissue), the average concentration found was 0.030 ± 0.008 µg g-1, which is below the arsenic maximum level established by international regulatory agencies. The average concentration found in the viscera (stomach, gills, and liver) was 0.485 ± 0.225 µg g-1, concluding that the viscera had greater capacity for the bioaccumulation of arsenic. From this study was possible to monitor the arsenic element in different tilapia specimens evidencing its accumulation throughout the body of the fish.
DOI: 10.6084/m9.figshare.5666674
title: Quantitative Analysis of Endocrine Disruptors by Comprehensive Two-Dimensional Gas Chromatography

description: Comprehensive two-dimensional gas chromatography has been successfully applied to the analysis of various organic contaminants; however, few studies report its use in the analysis of endocrine disrupting compounds. These compounds are suspected to cause dysfunction of the endocrine system in humans and animals. This work describes the development of a method to analyse dibutylphthalate, benzylbutylphthalate, nonylphenol and octylphenol in water using solid-phase microextraction (SPME) and comprehensive two-dimensional gas chromatography with a flame ionisation detector. The merit parameters of the comprehensive two-dimensional gas chromatography with flame ionisation detector method were weighed against a gas chromatography/mass spectrometry-single ion monitoring method of endocrine disrupting compounds analysis. The compounds were evaluated over a concentration range of 0.2 to 6.0 µg L-1 . The use of a two-dimensional chromatography method proved to be advantageous in analysing endocrine disrupting compounds, according to the observed increase of the signal relative to the noise and peak resolution.
DOI: 10.6084/m9.figshare.5666674.v1
title: Quantitative Analysis of Endocrine Disruptors by Comprehensive Two-Dimensional Gas Chromatography

description: Comprehensive two-dimensional gas chromatography has been successfully applied to the analysis of various organic contaminants; however, few studies report its use in the analysis of endocrine disrupting compounds. These compounds are suspected to cause dysfunction of the endocrine system in humans and animals. This work describes the development of a method to analyse dibutylphthalate, benzylbutylphthalate, nonylphenol and octylphenol in water using solid-phase microextraction (SPME) and comprehensive two-dimensional gas chromatography with a flame ionisation detector. The merit parameters of the comprehensive two-dimensional gas chromatography with flame ionisation detector method were weighed against a gas chromatography/mass spectrometry-single ion monitoring method of endocrine disrupting compounds analysis. The compounds were evaluated over a concentration range of 0.2 to 6.0 µg L-1 . The use of a two-dimensional chromatography method proved to be advantageous in analysing endocrine disrupting compounds, according to the observed increase of the signal relative to the noise and peak resolution.
DOI: 10.6084/m9.figshare.5666671
title: Compressive strength values dispersion of side-mixed and ready-mixed concretes

description: Abstract Compressive strength testing method has been widely used as indirect way for evaluate the concrete quality, due to it simplest execution, reliability of the results achieved and low cost of execution. Independently, if the concrete was side or ready-mixed, it is necessary to achieve the compressive strength requirements stated during structure design, essentially because this parameter allows the obtainment of the average strength of the reinforced concrete structure analyzed. Following, as for ready-mixed, as for side-mixed concretes, it is need to ensure the correspondence between the concrete design parameters and the concrete mixed, namely these parameters are summarized in terms of the compressive strength and homogeneity in the different phases of the construction. This way, the present work aims to do the analysis of the dispersions of the compressive strength of concretes mixtures (corresponding to compressive strength classes of 20, 25, 30, 35 and 40 MPa), and identify some influence factors, in this case, the influence of the workers team variation. Two mixtures (35 MPa and 40 MPa) were ready-mixed, while five of the concrete mixtures were side-mixed, by five different worker’s group with same time of experience on concrete’s manufacture. The results demonstrate that the variation of the workers team presents a high influence for the homogeneity of the compressive strength of the concrete.
DOI: 10.6084/m9.figshare.5666671.v1
title: Compressive strength values dispersion of side-mixed and ready-mixed concretes

description: Abstract Compressive strength testing method has been widely used as indirect way for evaluate the concrete quality, due to it simplest execution, reliability of the results achieved and low cost of execution. Independently, if the concrete was side or ready-mixed, it is necessary to achieve the compressive strength requirements stated during structure design, essentially because this parameter allows the obtainment of the average strength of the reinforced concrete structure analyzed. Following, as for ready-mixed, as for side-mixed concretes, it is need to ensure the correspondence between the concrete design parameters and the concrete mixed, namely these parameters are summarized in terms of the compressive strength and homogeneity in the different phases of the construction. This way, the present work aims to do the analysis of the dispersions of the compressive strength of concretes mixtures (corresponding to compressive strength classes of 20, 25, 30, 35 and 40 MPa), and identify some influence factors, in this case, the influence of the workers team variation. Two mixtures (35 MPa and 40 MPa) were ready-mixed, while five of the concrete mixtures were side-mixed, by five different worker’s group with same time of experience on concrete’s manufacture. The results demonstrate that the variation of the workers team presents a high influence for the homogeneity of the compressive strength of the concrete.
DOI: 10.6084/m9.figshare.5666668
title: Patient satisfaction with pharmaceutical services in Brazilian primary health care

description: ABSTRACT OBJECTIVE To evaluate patient satisfaction with pharmaceutical services in Brazilian primary health care. METHODS This is a cross-sectional, exploratory, and evaluative study on a representative sample from the five Brazilian geopolitical regions resulting from the Pesquisa Nacional sobre Acesso, Utilização e Promoção do Uso Racional de Medicamentos – Serviços, 2015 (PNAUM – National Survey on Access, Use and Promotion of Rational Use of Medicines – Services, 2015). The outcome was the patient’s satisfaction, obtained using the item response theory. Associations were tested using Pearson’s Chi-square test with sociodemographic and health variables, and multiple logistic regression analyses were carried out. The Hosmer-Lemeshow test was used to verify the adequacy of the final model. Logistic regression results were presented as odds ratio. RESULTS The overall percentage of patients satisfied with these services was 58.4% (95%CI 54.4-62.3). The “opportunity/convenience” aspect had the lowest satisfaction percentage (49.5%; 95%CI 46.4-52.6) and “interpersonal aspects,” the highest percentage (90.5%; 95%CI 88.9-91.8), significantly higher than other aspects. Sex, age group, limitations due to disease, and self-perception of health remained associated in the final multiple logistic model regarding general satisfaction. CONCLUSIONS Most of the interviewed users were satisfied with pharmaceutical services in Brazilian cities, and the satisfaction with the customer’s service was determinant in the patient’s overall satisfaction.