cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.6084/m9.figshare.3454712
title: Zircon age constraints on the provenance of Llandovery to Wenlock sandstones from the Midland Valley terrane of the Scottish Caledonides

description: <strong>Synopsis</strong> Detrital zircon populations within the Llandovery to Wenlock sandstones of the southern Midland Valley of Scotland indicate that the recycled orogenic provenance for these sedimentary rocks was essentially bimodal, comprising a younger Lower Palaeozoic component and an older predominantly Mesoproterozoic component. The Lower Palaeozoic contribution is dominated by Arenig/Llanvirn (<em>c</em>. 475 Ma) zircons interpreted as having been derived from a volcanic-plutonic source located within the Midland Valley terrane. The dominant Mesoproterozoic component within the sandstones is <em>c</em>. 1000 Ma and is thought to represent detritus shed from a Grenvillian (<em>c</em>. 1000–1800Ma) basement to the Midland Valley terrane. The scarcity of Archaean zircons precludes the Grampian metamorphic terrane Dalradian Supergroup as a supplier of sediment to the Ordovician–Silurian basins located along the southern margin of the Midland Valley. The age profiles of detrital zircon populations do not fit with a simple model of unroofing of a volcanic-arc complex. Rather they point to the periodic uplift of fault-bound, dismembered blocks of volcanic and plutonic rocks during a prolonged (Llandovery through to at least early Devonian) period of sinistral strike-slip deformation, and it was this which controlled basin development, sedimentary facies distribution and deformation along the southern side of the Midland Valley terrane. Appendices 1 & 2 can be found at http://www.geolsoc.org.uk/SUP18370
DOI: 10.6084/m9.figshare.3454715.v1
title: Exhumation of an active magmatic–hydrothermal system in a resurgent caldera environment: the example of Ischia (Italy)

description: Ischia is a rare case of a well-exposed caldera system that has experienced rapid recent resurgence, which can be used to dissect the anatomy of an otherwise inaccessible active hydrothermal system developed in a caldera-forming environment. Integrated analyses of melt and fluid inclusions, mineralogy and stable isotopic compositions of pumices, tuffs and syenitic xenoliths of the Ischia volcanic system provide strong physico-chemical constraints on the shallow magmatic reservoir and the hydrothermal system. The hydrothermal system has been exposed by the rapid uplift of the Mt. Epomeo resurgent block. The engine of the hydrothermal system of Ischia can be identified in the shallow magmatic system (at around 2 km depth) that hosts hot (<em>c</em>. 1000 °C) trachytic magma. The hydrothermal system developed principally within thick intracaldera ignimbrite deposits, and extended to a depth of at least 1 km, defining a series of facies characterized by associations of alteration mineral assemblages typical of a seawater-dominated high-temperature geothermal system.
DOI: 10.6084/m9.figshare.3454712.v1
title: Zircon age constraints on the provenance of Llandovery to Wenlock sandstones from the Midland Valley terrane of the Scottish Caledonides

description: <strong>Synopsis</strong> Detrital zircon populations within the Llandovery to Wenlock sandstones of the southern Midland Valley of Scotland indicate that the recycled orogenic provenance for these sedimentary rocks was essentially bimodal, comprising a younger Lower Palaeozoic component and an older predominantly Mesoproterozoic component. The Lower Palaeozoic contribution is dominated by Arenig/Llanvirn (<em>c</em>. 475 Ma) zircons interpreted as having been derived from a volcanic-plutonic source located within the Midland Valley terrane. The dominant Mesoproterozoic component within the sandstones is <em>c</em>. 1000 Ma and is thought to represent detritus shed from a Grenvillian (<em>c</em>. 1000–1800Ma) basement to the Midland Valley terrane. The scarcity of Archaean zircons precludes the Grampian metamorphic terrane Dalradian Supergroup as a supplier of sediment to the Ordovician–Silurian basins located along the southern margin of the Midland Valley. The age profiles of detrital zircon populations do not fit with a simple model of unroofing of a volcanic-arc complex. Rather they point to the periodic uplift of fault-bound, dismembered blocks of volcanic and plutonic rocks during a prolonged (Llandovery through to at least early Devonian) period of sinistral strike-slip deformation, and it was this which controlled basin development, sedimentary facies distribution and deformation along the southern side of the Midland Valley terrane. Appendices 1 & 2 can be found at http://www.geolsoc.org.uk/SUP18370
DOI: 10.6084/m9.figshare.3454709
title: Geochronological constraints on the evolution of the southern Dom Feliciano Belt (Uruguay)

description: New U–Pb sensitive high-resolution ion microprobe, K–Ar and Ar–Ar data from the southernmost Dom Feliciano Belt allow the identification of four major events. Orthogneisses from the Punta del Este Terrane indicate a magmatic episode at <em>c</em>. 770 Ma and high-grade metamorphism at 641 ± 17 Ma. Granitoid emplacement at 627 ± 23 Ma was roughly coeval with peak metamorphism. Volcaniclastic rocks of the Las Ventanas Formation dated at 573 ± 11 Ma can be correlated with the peripheral foreland basin (571 ± 8 Ma). Transpression and coeval high-K calc-alkaline magmatism is recorded in the Maldonado granite dated at 564 ± 7 Ma. The following events are postulated: (1) magmatism at 850–750 Ma related to rifting; (2) metamorphism and granite emplacement at 650–600 Ma; (3) molasse sequences and foreland basins at <em>c</em>. 573 Ma; (4) late magmatism at 580–560 Ma associated with transpression. The data indicate that (1) the Punta del Este Terrane could be a portion of the Coastal Terrane of the Kaoko Belt, (2) granitoid emplacement at 650–600 Ma in the Punta del Este and Nico Pérez terranes favours westward subduction, and (3) widespread post-collisional synkinematic magmatism occurred in the Dom Feliciano and Kaoko belts between 580 and 550 Ma.
DOI: 10.6084/m9.figshare.3454709.v1
title: Geochronological constraints on the evolution of the southern Dom Feliciano Belt (Uruguay)

description: New U–Pb sensitive high-resolution ion microprobe, K–Ar and Ar–Ar data from the southernmost Dom Feliciano Belt allow the identification of four major events. Orthogneisses from the Punta del Este Terrane indicate a magmatic episode at <em>c</em>. 770 Ma and high-grade metamorphism at 641 ± 17 Ma. Granitoid emplacement at 627 ± 23 Ma was roughly coeval with peak metamorphism. Volcaniclastic rocks of the Las Ventanas Formation dated at 573 ± 11 Ma can be correlated with the peripheral foreland basin (571 ± 8 Ma). Transpression and coeval high-K calc-alkaline magmatism is recorded in the Maldonado granite dated at 564 ± 7 Ma. The following events are postulated: (1) magmatism at 850–750 Ma related to rifting; (2) metamorphism and granite emplacement at 650–600 Ma; (3) molasse sequences and foreland basins at <em>c</em>. 573 Ma; (4) late magmatism at 580–560 Ma associated with transpression. The data indicate that (1) the Punta del Este Terrane could be a portion of the Coastal Terrane of the Kaoko Belt, (2) granitoid emplacement at 650–600 Ma in the Punta del Este and Nico Pérez terranes favours westward subduction, and (3) widespread post-collisional synkinematic magmatism occurred in the Dom Feliciano and Kaoko belts between 580 and 550 Ma.
DOI: 10.6084/m9.figshare.3454706
title: A magmatic age and four successive metamorphic events recorded in zircons from a single meta-anorthosite sample in the Central Zone of the Limpopo Belt, South Africa

description: Ion microprobe U–Th–Pb analyses combined with cathodoluminescence imaging of zircons from a meta-anorthosite from the Central Zone of the Limpopo Belt record five distinct events. The most concordant ages of cores of zircon yielded a weighted mean <sup>207</sup>Pb/<sup>206</sup>Pb age of 3344 ± 3.6 Ma, representing the protolith age. The unzoned overgrowths yielded four discrete groups with weighted mean <sup>207</sup>Pb/<sup>206</sup>Pb ages of 3150 ± 15 Ma, 2614 ± 4 Ma, 2488 ± 22 Ma and 2009 ± 28 Ma, representing four possible metamorphic events in the Central Zone. This is the first time that a succession of several metamorphic events has been demonstrated in a single rock-type from the Limpopo Belt.
DOI: 10.6084/m9.figshare.3454706.v1
title: A magmatic age and four successive metamorphic events recorded in zircons from a single meta-anorthosite sample in the Central Zone of the Limpopo Belt, South Africa

description: Ion microprobe U–Th–Pb analyses combined with cathodoluminescence imaging of zircons from a meta-anorthosite from the Central Zone of the Limpopo Belt record five distinct events. The most concordant ages of cores of zircon yielded a weighted mean <sup>207</sup>Pb/<sup>206</sup>Pb age of 3344 ± 3.6 Ma, representing the protolith age. The unzoned overgrowths yielded four discrete groups with weighted mean <sup>207</sup>Pb/<sup>206</sup>Pb ages of 3150 ± 15 Ma, 2614 ± 4 Ma, 2488 ± 22 Ma and 2009 ± 28 Ma, representing four possible metamorphic events in the Central Zone. This is the first time that a succession of several metamorphic events has been demonstrated in a single rock-type from the Limpopo Belt.
DOI: 10.6084/m9.figshare.3454703
title: Geochronological evolution of HP metamorphic rocks of the Adula nappe, Central Alps, in pre-Alpine and Alpine subduction cycles

description: SHRIMP dating of zircon from eclogites, their country rock gneisses and quartz veins from the northern and middle Adula nappe, Central Alps, accompanied by cathodoluminescence imaging and REE geochemistry of these dated zircon crystals revealed that the Adula nappe has been affected by two pre-Alpine high-pressure (HP) metamorphic events (northern: <em>c</em>. 330–340 Ma; middle: <em>c</em>. 370 Ma). In the northern Adula nappe, loss of radiogenic Pb of the <em>c</em>. 330–340 Ma zircon domains in combination with previous geochronological data argue for an overprinting Alpine HP event. In the middle Adula nappe, metamorphic zircon domains record in addition a 33–32 Ma event, interpreted to reflect HT metamorphism, already identified in the southern part of the nappe, where such SHRIMP ages have been related to HT (Lepontine) metamorphism. The Alpine HP event indicated by previous SHRIMP data in the southern Adula nappe at <em>c</em>. 35 Ma is not recorded in the zircons of the rocks dated herein. The absence in this dataset is probably because either no HP (<em>c</em>. 35 Ma) zircon domains were formed or such domains were completely reset during the 33–32 Ma HT event. Protolith ages of orthogneisses and eclogites are 470–457 Ma and 595–587 Ma, respectively, and maximum sedimentation ages of paragneisses 500–460 Ma. The lack of Hercynian protolith zircon ages implies pre-Hercynian formation for the precursors of the dated HP rocks. Our data suggest that the Adula nappe contains various Hercynian basement slivers that underwent subduction to HP conditions at <em>c</em>. 330–340 Ma and <em>c</em>. 370 Ma prior to the Alpine orogeny, similar to many other parts of the Hercynian basement in Central and Southern Europe.
DOI: 10.6084/m9.figshare.3454703.v1
title: Geochronological evolution of HP metamorphic rocks of the Adula nappe, Central Alps, in pre-Alpine and Alpine subduction cycles

description: SHRIMP dating of zircon from eclogites, their country rock gneisses and quartz veins from the northern and middle Adula nappe, Central Alps, accompanied by cathodoluminescence imaging and REE geochemistry of these dated zircon crystals revealed that the Adula nappe has been affected by two pre-Alpine high-pressure (HP) metamorphic events (northern: <em>c</em>. 330–340 Ma; middle: <em>c</em>. 370 Ma). In the northern Adula nappe, loss of radiogenic Pb of the <em>c</em>. 330–340 Ma zircon domains in combination with previous geochronological data argue for an overprinting Alpine HP event. In the middle Adula nappe, metamorphic zircon domains record in addition a 33–32 Ma event, interpreted to reflect HT metamorphism, already identified in the southern part of the nappe, where such SHRIMP ages have been related to HT (Lepontine) metamorphism. The Alpine HP event indicated by previous SHRIMP data in the southern Adula nappe at <em>c</em>. 35 Ma is not recorded in the zircons of the rocks dated herein. The absence in this dataset is probably because either no HP (<em>c</em>. 35 Ma) zircon domains were formed or such domains were completely reset during the 33–32 Ma HT event. Protolith ages of orthogneisses and eclogites are 470–457 Ma and 595–587 Ma, respectively, and maximum sedimentation ages of paragneisses 500–460 Ma. The lack of Hercynian protolith zircon ages implies pre-Hercynian formation for the precursors of the dated HP rocks. Our data suggest that the Adula nappe contains various Hercynian basement slivers that underwent subduction to HP conditions at <em>c</em>. 330–340 Ma and <em>c</em>. 370 Ma prior to the Alpine orogeny, similar to many other parts of the Hercynian basement in Central and Southern Europe.
DOI: 10.6084/m9.figshare.3454700
title: The hydration and alteration of perlite and rhyolite

description: The volatile concentrations and thermal characteristics of hydrothermally altered rhyolitic deposits erupted under Icelandic glaciers have been studied by combined differential scanning calorimetry–thermogravimetric analysis–mass spectrometry (DSC–TGA–MS) and X-ray diffraction (XRD). Samples range from pristine obsidians to strongly perlitized and altered fragmental deposits. Four types of samples are determined to have notable differences in total volatile concentrations: obsidians (0.44–3.04 wt%), perlites (2.15–8.15 wt%), obsidian-breccias (8.49–9.41 wt%) and hyaloclastites (3.23–7.78 wt%). DSC–TGA–MS and textural data indicate that the volatile concentration of the perlitic samples increases as the amount of perlitization increases. XRD data show that the volatile-rich samples are rich in the low-temperature zeolite minerals heulandite and mordenite. The temperature at which volatile exsolution occurs is shown to decrease as the volatile concentration increases, reflecting the speciation of water as well as zeolite mineral growth.
DOI: 10.6084/m9.figshare.3454700.v1
title: The hydration and alteration of perlite and rhyolite

description: The volatile concentrations and thermal characteristics of hydrothermally altered rhyolitic deposits erupted under Icelandic glaciers have been studied by combined differential scanning calorimetry–thermogravimetric analysis–mass spectrometry (DSC–TGA–MS) and X-ray diffraction (XRD). Samples range from pristine obsidians to strongly perlitized and altered fragmental deposits. Four types of samples are determined to have notable differences in total volatile concentrations: obsidians (0.44–3.04 wt%), perlites (2.15–8.15 wt%), obsidian-breccias (8.49–9.41 wt%) and hyaloclastites (3.23–7.78 wt%). DSC–TGA–MS and textural data indicate that the volatile concentration of the perlitic samples increases as the amount of perlitization increases. XRD data show that the volatile-rich samples are rich in the low-temperature zeolite minerals heulandite and mordenite. The temperature at which volatile exsolution occurs is shown to decrease as the volatile concentration increases, reflecting the speciation of water as well as zeolite mineral growth.
DOI: 10.6084/m9.figshare.3454697
title: Clastic domains of sandstones in central/eastern Venezuela, Trinidad, and Barbados: heavy mineral and tectonic constraints on provenance and palaeogeography

description: Current models for the tectonic evolution of northeastern South America invoke a Palaeogene phase of inter-American convergence, followed by diachronous dextral oblique collision with the Caribbean Plate, becoming strongly transcurrent in the Late Miocene. Heavy mineral analysis of Cretaceous to Pleistocene rocks from eastern Venezuela, Barbados and Trinidad allow us to define six primary clastic domains, refine our palaeogeographic maps, and relate them to distinct stages of tectonic development: (1) Cretaceous passive margin of northern South America; (2) Palaeogene clastics related to the dynamics of the Proto-Caribbean Inversion Zone before collision with the Caribbean Plate; (3) Late Eocene–Oligocene southward-transgressive clastic sediments fringing the Caribbean foredeep during initial collision; (4) Oligocene–Middle Miocene axial fill of the Caribbean foredeep; (5) Late Eocene–Middle Miocene northern proximal sedimentary fringe of the Caribbean thrustfront; and (6) Late Miocene–Recent deltaic sediments flowing parallel to the orogen during its post-collisional, mainly transcurrent stage. Domain 1–3 sediments are highly mature, comprising primary Guayana Shield-derived sediment or recycled sediment of shield origin eroded from regional Palaeogene unconformities. In Trinidad, palinspastic restoration of Neogene deformation indicates that facies changes once interpreted as north to south are in fact west to east, reflecting progradation from the Maturín Basin into central Trinidad across the NW–SE trending Bohordal marginal offset, distorted by about 70 km of dextral shear through Trinidad. There is no mineralogical indication of a northern or northwestern erosional sediment source until Oligocene onset of Domain 4 sedimentation. Paleocene–Middle Eocene rocks of the Scotland Formation sandstones in Barbados do show an immature orogenic signature, in contrast to Venezuela–Trinidad Domain 2 sediments, this requires: (1) at least a bathymetric difference, if not a tectonic barrier, between them; and (2) that the Barbados deep-water depocentre was within turbidite transport distance of the Early Palaeogene orogenic source areas of western Venezuela and/or Colombia. Domains 4–6 (from Late Oligocene) show a strong direct or recycled influence of Caribbean Orogen igneous and metamorphic terranes in addition to substantial input from the shield areas to the south. The delay in the appearance of common Caribbean detritus in the east, relative to the Paleocene and Eocene appearance of Caribbean-influenced sands in the west, reflects the diachronous, eastward migration of Caribbean foredeep subsidence and sedimentation as a response to eastward-younging collision of the Caribbean Plate and the South American margin.
DOI: 10.6084/m9.figshare.3454697.v1
title: Clastic domains of sandstones in central/eastern Venezuela, Trinidad, and Barbados: heavy mineral and tectonic constraints on provenance and palaeogeography

description: Current models for the tectonic evolution of northeastern South America invoke a Palaeogene phase of inter-American convergence, followed by diachronous dextral oblique collision with the Caribbean Plate, becoming strongly transcurrent in the Late Miocene. Heavy mineral analysis of Cretaceous to Pleistocene rocks from eastern Venezuela, Barbados and Trinidad allow us to define six primary clastic domains, refine our palaeogeographic maps, and relate them to distinct stages of tectonic development: (1) Cretaceous passive margin of northern South America; (2) Palaeogene clastics related to the dynamics of the Proto-Caribbean Inversion Zone before collision with the Caribbean Plate; (3) Late Eocene–Oligocene southward-transgressive clastic sediments fringing the Caribbean foredeep during initial collision; (4) Oligocene–Middle Miocene axial fill of the Caribbean foredeep; (5) Late Eocene–Middle Miocene northern proximal sedimentary fringe of the Caribbean thrustfront; and (6) Late Miocene–Recent deltaic sediments flowing parallel to the orogen during its post-collisional, mainly transcurrent stage. Domain 1–3 sediments are highly mature, comprising primary Guayana Shield-derived sediment or recycled sediment of shield origin eroded from regional Palaeogene unconformities. In Trinidad, palinspastic restoration of Neogene deformation indicates that facies changes once interpreted as north to south are in fact west to east, reflecting progradation from the Maturín Basin into central Trinidad across the NW–SE trending Bohordal marginal offset, distorted by about 70 km of dextral shear through Trinidad. There is no mineralogical indication of a northern or northwestern erosional sediment source until Oligocene onset of Domain 4 sedimentation. Paleocene–Middle Eocene rocks of the Scotland Formation sandstones in Barbados do show an immature orogenic signature, in contrast to Venezuela–Trinidad Domain 2 sediments, this requires: (1) at least a bathymetric difference, if not a tectonic barrier, between them; and (2) that the Barbados deep-water depocentre was within turbidite transport distance of the Early Palaeogene orogenic source areas of western Venezuela and/or Colombia. Domains 4–6 (from Late Oligocene) show a strong direct or recycled influence of Caribbean Orogen igneous and metamorphic terranes in addition to substantial input from the shield areas to the south. The delay in the appearance of common Caribbean detritus in the east, relative to the Paleocene and Eocene appearance of Caribbean-influenced sands in the west, reflects the diachronous, eastward migration of Caribbean foredeep subsidence and sedimentation as a response to eastward-younging collision of the Caribbean Plate and the South American margin.
DOI: 10.6084/m9.figshare.3454691
title: Late Cretaceous to Miocene seamount accretion and mélange formation in the Osa and Burica Peninsulas (Southern Costa Rica): episodic growth of a convergent margin

description: Multidisciplinary study of the Osa and Burica peninsulas, Costa Rica, recognizes the Osa Igneous Complex and the Osa Mélange – records of a complex Late Cretaceous–Miocene tectonic–sedimentary history. The Igneous Complex, an accretionary prism (<em>sensu stricto</em>) comprises mainly basaltic lava flows, with minor sills, gabbroic intrusives, pelagic limestones and radiolarites. Sediments or igneous rocks derived from the upper plate are absent. Four units delimited on the base of stratigraphy and geochemistry lie in contact along reactivated palaeo-décollement zones. They comprise fragments of a Coniacian–Santonian oceanic plateau (Inner Osa Igneous Complex) and Coniacian–Santonian to Middle Eocene seamounts (Outer Osa Igneous Complex). The units are unrelated to other igneous complexes of Costa Rica and Panama and are exotic with respect to the partly overthickened Caribbean Plate; they formed by multiple accretions between the Late Cretaceous and Middle Eocene, prior to the genesis of the mélange. Events of high-rate accretion alternated with periods of low-rate accretion and tectonic erosion. The NW Osa Mélange in contact with the Osa Igneous Complex has a block-in-matrix texture at various scales, produced by sedimentary processes and later tectonically enhanced. Lithologies are mainly debris flows and hemipelagic deposits. Clastic components (grains to large boulders) indicate Late Eocene mass wasting of the Igneous Complex, forearc deposits and a volcanic arc. Gravitational accumulation of a thick pile of trench sediments culminated with shallow-level accretion. Mass-wasting along the margin was probably triggered by seamount subduction and/or plate reorganization at larger scale. The study provides new geological constraints for seamount subduction and associated accretionary processes, as well as on the erosive/accretionary nature of convergent margins devoid of accreted sediments.