cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.6084/m9.figshare.19944426
title: ECOTOXICOLOGICAL ASSESSMENT OF COAL MINING WASTE

description: ABSTRACT The disposal of large amounts of coal mining waste chemically modifies the soil, and this may change the structure and activity of soil fauna. The objective of this investigation was to study the ecotoxicological effects of depositions of pyritic waste (coal plus pyrite) in two soils collected in Santa Catarina, Argissolo Vermelho-Amarelo (Ultisol) e Nitossolo Háplico (Hapludox), at the application rates of 0, 2.5, 5, 10, and 20 % of that residue. Survival and reproduction of Enchytraeus crypticus and germination of Avena sativa and Lotus corniculatus were tested. The pH value, regardless of the type of soil, decreased as the rate of pyritic waste increased. Pyritic waste at the lowest rate resulted in negative effects on E. crypticus, as shown by reduction in the adult survival rate and no reproduction. In survival and reproduction testing of enchytraeids, the value of LC50 (estimated concentration that can cause negative effects on the survival and germination of 50 % of a group of organisms) was below 4 %, and EC50 (negative effects on reproduction) was less than 2.5 % for both soils. Exposure of A. sativa to the two soils did not have a toxic effect, nor did exposure of L. corniculatus to Hapludox. However, in the Ultisol, contamination caused effects at the lowest rate for L. corniculatus. In the seed germination test, only L. corniculatus showed sensitivity in the Ultisol (LC50&lt;4 %). High sensitivity to the application of pyritic residue adversely affects soil organisms, both in the short term and long term.
DOI: 10.6084/m9.figshare.19944426.v1
title: ECOTOXICOLOGICAL ASSESSMENT OF COAL MINING WASTE

description: ABSTRACT The disposal of large amounts of coal mining waste chemically modifies the soil, and this may change the structure and activity of soil fauna. The objective of this investigation was to study the ecotoxicological effects of depositions of pyritic waste (coal plus pyrite) in two soils collected in Santa Catarina, Argissolo Vermelho-Amarelo (Ultisol) e Nitossolo Háplico (Hapludox), at the application rates of 0, 2.5, 5, 10, and 20 % of that residue. Survival and reproduction of Enchytraeus crypticus and germination of Avena sativa and Lotus corniculatus were tested. The pH value, regardless of the type of soil, decreased as the rate of pyritic waste increased. Pyritic waste at the lowest rate resulted in negative effects on E. crypticus, as shown by reduction in the adult survival rate and no reproduction. In survival and reproduction testing of enchytraeids, the value of LC50 (estimated concentration that can cause negative effects on the survival and germination of 50 % of a group of organisms) was below 4 %, and EC50 (negative effects on reproduction) was less than 2.5 % for both soils. Exposure of A. sativa to the two soils did not have a toxic effect, nor did exposure of L. corniculatus to Hapludox. However, in the Ultisol, contamination caused effects at the lowest rate for L. corniculatus. In the seed germination test, only L. corniculatus showed sensitivity in the Ultisol (LC50&lt;4 %). High sensitivity to the application of pyritic residue adversely affects soil organisms, both in the short term and long term.
DOI: 10.6084/m9.figshare.19944427
title: Potential of Spectroradiometry to Classify Soil Clay Content

description: ABSTRACT Diffuse reflectance spectroscopy (DRS) is a fast and cheap alternative for soil clay, but needs further investigation to assess the scope of application. The purpose of the study was to develop a linear regression model to predict clay content from DRS data, to classify the soils into three textural classes, similar to those defined by a regulation of the Brazilian Ministry of Agriculture, Livestock and Food Supply. The DRS data of 412 soil samples, from the 0.0-0.5 m layer, from different locations in the state of Rio Grande do Sul, Brazil, were measured at wavelengths of 350 to 2,500 nm in the laboratory. The fitting of the linear regression model developed to predict soil clay content from the DRS data was based on a R2 value of 0.74 and 0.75, with a RMSE of 7.82 and 8.51 % for the calibration and validation sets, respectively. Soil texture classification had an overall accuracy of 79.0 % (calibration) and 80.9 % (validation). The heterogeneity of soil samples affected the performance of the prediction models. Future studies should consider a previous classification of soil samples in different groups by soil type, parent material and/or sampling region.
DOI: 10.6084/m9.figshare.19944427.v1
title: Potential of Spectroradiometry to Classify Soil Clay Content

description: ABSTRACT Diffuse reflectance spectroscopy (DRS) is a fast and cheap alternative for soil clay, but needs further investigation to assess the scope of application. The purpose of the study was to develop a linear regression model to predict clay content from DRS data, to classify the soils into three textural classes, similar to those defined by a regulation of the Brazilian Ministry of Agriculture, Livestock and Food Supply. The DRS data of 412 soil samples, from the 0.0-0.5 m layer, from different locations in the state of Rio Grande do Sul, Brazil, were measured at wavelengths of 350 to 2,500 nm in the laboratory. The fitting of the linear regression model developed to predict soil clay content from the DRS data was based on a R2 value of 0.74 and 0.75, with a RMSE of 7.82 and 8.51 % for the calibration and validation sets, respectively. Soil texture classification had an overall accuracy of 79.0 % (calibration) and 80.9 % (validation). The heterogeneity of soil samples affected the performance of the prediction models. Future studies should consider a previous classification of soil samples in different groups by soil type, parent material and/or sampling region.
DOI: 10.6084/m9.figshare.19944429
title: Planosols Developed in Different Geoenvironmental Conditions in Northeastern Brazil

description: ABSTRACT The semiarid region of northeastern Brazil has a large area occupied by Planosols, where in the State of Pernambuco these soils are mainly used for livestock farming and subsistence crops. The knowledge on these soils is limited, which compromises the understanding on their behavior, potentialities and limitations.This study aimed to analyze morphological, chemical, physical and mineralogical attributes of Planosols developed under different geoenvironmental conditions. Morphological descriptions and chemical, physical and mineralogical analyses were performed in four profiles of Planosols along a rainfall gradient. An increase in rainfall allowed for an increase in the clay content in the Bt horizon and a reduction in ESP, EC, Na+, CEC, S, pH (water and KCl) and soil density. Horizons A and E were thicker in Planosols in more humid environments. The increase in ESP associated with the presence of expansive minerals (smectite and vermiculite) allowed the development of a prismatic structure in Haplic Planosols and a columnar structure in Natric Planosols. The mineralogical assembly is indicative of poorly weathered soils. The mineralogical assemblies of the silt and clay fractions were similar in the different geoenvironments, while higher contents of easily alterable minerals were observed in the composition of the sand fraction in environments with a drier climate.
DOI: 10.6084/m9.figshare.19944429.v1
title: Planosols Developed in Different Geoenvironmental Conditions in Northeastern Brazil

description: ABSTRACT The semiarid region of northeastern Brazil has a large area occupied by Planosols, where in the State of Pernambuco these soils are mainly used for livestock farming and subsistence crops. The knowledge on these soils is limited, which compromises the understanding on their behavior, potentialities and limitations.This study aimed to analyze morphological, chemical, physical and mineralogical attributes of Planosols developed under different geoenvironmental conditions. Morphological descriptions and chemical, physical and mineralogical analyses were performed in four profiles of Planosols along a rainfall gradient. An increase in rainfall allowed for an increase in the clay content in the Bt horizon and a reduction in ESP, EC, Na+, CEC, S, pH (water and KCl) and soil density. Horizons A and E were thicker in Planosols in more humid environments. The increase in ESP associated with the presence of expansive minerals (smectite and vermiculite) allowed the development of a prismatic structure in Haplic Planosols and a columnar structure in Natric Planosols. The mineralogical assembly is indicative of poorly weathered soils. The mineralogical assemblies of the silt and clay fractions were similar in the different geoenvironments, while higher contents of easily alterable minerals were observed in the composition of the sand fraction in environments with a drier climate.
DOI: 10.6084/m9.figshare.19944432
title: Assessment of Digital Elevation Model for Digital Soil Mapping in a Watershed with Gently Undulating Topography

description: ABSTRACT Terrain attributes (TAs) derived from digital elevation models (DEMs) are frequently used in digital soil mapping (DSM) as auxiliary covariates in the construction of prediction models. The DEMs and information extracted from it may be limited with regard to the spatial resolution and error magnitude, and can differ in the behavior of terrain features. The objective of this study was to evaluate the quality and limitations of free DEM data and to evaluate a topographic survey (TS) underlying the choice of a more appropriate model, for use in DSMs at a scale of 1:10,000. The study was conducted in an area of 937 ha in the watershed of Lajeado Giruá, in southern Brazil. The DEMs: DEM-TS, DEM-Topographic Map (TM), DEM-ASTER, DEM-SRTM, and DEM-TOPODATA were evaluated with regard to the precision elevation by statistical tests based on field reference points, the root mean square error (RMSE), identification of the number and size of spurious depressions, and the application of the Brazilian Cartographic Accuracy Standards Law (BCASL) to define the scale of each DEM. In addition, the TA derived from each DEM was compared with the TA from DEM-TS, considered to be terrain reality. The results showed that the elevation data of DEM-TS had the best quality (RMSE = 1.93 m), followed by DEM-SRTM (RMSE = 5.95 m), DEM-Topographic Map (RMSE = 8.28 m), DEM-TOPODATA (RMSE = 9.78 m) and DEM-ASTER (RMSE = 15.57 m). The DEM-TS was well-represented at a 1:10,000 scale, while the DEM-Topographic Map and DEM-SRTM fitted 1:50,000, the DEM-TOPODATA 1:50,000 and the DEM-ASTER a 1:100,000 scale. The results of DEM-SRTM and DEM-TOPODATA were closest to terrain reality (DEM-TS) and had the lowest number of spurious depressions and RMSE values for each evaluated attribute, but were inadequate for not fitting detailed scales compatible with small areas. The techniques for the acquisition of elevation data of each DEM and mainly the flat to gently undulating topography were factors that influenced the results. For a DSM at a scale of 1:10,000 in similar areas, the most appropriate model is DEM-TS.
DOI: 10.6084/m9.figshare.19944432.v1
title: Assessment of Digital Elevation Model for Digital Soil Mapping in a Watershed with Gently Undulating Topography

description: ABSTRACT Terrain attributes (TAs) derived from digital elevation models (DEMs) are frequently used in digital soil mapping (DSM) as auxiliary covariates in the construction of prediction models. The DEMs and information extracted from it may be limited with regard to the spatial resolution and error magnitude, and can differ in the behavior of terrain features. The objective of this study was to evaluate the quality and limitations of free DEM data and to evaluate a topographic survey (TS) underlying the choice of a more appropriate model, for use in DSMs at a scale of 1:10,000. The study was conducted in an area of 937 ha in the watershed of Lajeado Giruá, in southern Brazil. The DEMs: DEM-TS, DEM-Topographic Map (TM), DEM-ASTER, DEM-SRTM, and DEM-TOPODATA were evaluated with regard to the precision elevation by statistical tests based on field reference points, the root mean square error (RMSE), identification of the number and size of spurious depressions, and the application of the Brazilian Cartographic Accuracy Standards Law (BCASL) to define the scale of each DEM. In addition, the TA derived from each DEM was compared with the TA from DEM-TS, considered to be terrain reality. The results showed that the elevation data of DEM-TS had the best quality (RMSE = 1.93 m), followed by DEM-SRTM (RMSE = 5.95 m), DEM-Topographic Map (RMSE = 8.28 m), DEM-TOPODATA (RMSE = 9.78 m) and DEM-ASTER (RMSE = 15.57 m). The DEM-TS was well-represented at a 1:10,000 scale, while the DEM-Topographic Map and DEM-SRTM fitted 1:50,000, the DEM-TOPODATA 1:50,000 and the DEM-ASTER a 1:100,000 scale. The results of DEM-SRTM and DEM-TOPODATA were closest to terrain reality (DEM-TS) and had the lowest number of spurious depressions and RMSE values for each evaluated attribute, but were inadequate for not fitting detailed scales compatible with small areas. The techniques for the acquisition of elevation data of each DEM and mainly the flat to gently undulating topography were factors that influenced the results. For a DSM at a scale of 1:10,000 in similar areas, the most appropriate model is DEM-TS.
DOI: 10.6084/m9.figshare.19944433.v1
title: Genesis and Classification of Soils Containing Carbonate on the Apodi Plateau, Brazil

description: ABSTRACT Information is scarce on the genesis and classification of soils derived from calcareous rocks in the Northeastern region of Brazil. This study describes the morphological, physical, chemical, mineralogical, and micromorphological properties of four soil profiles (P1-P4) located in the Apodi Plateau. A pedogenesis hypothesis and soil classification, according to the Brazilian System of Soil Classification (SiBCS), are proposed for these profiles. The interactions between parent material, surface topography and climate affected the pedogenesis processes and soil properties, although the calcareous nature of the parent material most affected the soil morphology and chemical properties. The sand fraction contained mainly quartz and calcite, and a smaller amount of mica. Smectite and interstratified illite-smectite occurred in the clay fraction of profile P1 and in some horizons of P2 (Ccmќ and Ccrќ) and P3 (2Ccrќ). Kaolinite predominated in profiles P2, P3, and P4; where as illite and vermiculite were present in the Bicќ, Bcќ, Bcmќ horizons of P2, in Bt2c of P3, and in C of P4. The mineralogy showed illite, hematite, and goethite, and anatase in a number of horizons. Micromorphological analysis of P2 indicated a strong cementation of Bcmќ and Ccmќ by calcium carbonate, and other properties indicate the formation of a petrocalcic horizon, but this horizon lacked lateral continuity in the profile. Therefore, the parapetrocalcic term is proposed for classifying P2 in the fourth level of the SiBCS. The 3Biќ-P1 horizon exhibited calcite coating and iron coating or quasi-coating, indicating distinct pedogenesis processes occurring under different environmental conditions. Likewise, the occurrence of petroplinthite in P2 indicates that climatic conditions during its formation differed from present conditions, and both situations are interpreted as evidence that the soils were formed by polygenetic processes. In the SiBCS classification, the soils are classified as Cambissolo Háplico Carbonático vertissólico (P1), Cambissolo Háplico Carbonático concrecionário (P2), Luvissolo Crômico Pálico petroplíntico (P3), and Neossolo Litólico Carbonatico típico (P4); and a new class (parapetrocálcico concrecionário) is proposed for P2 in the fourth level.
DOI: 10.6084/m9.figshare.19944433
title: Genesis and Classification of Soils Containing Carbonate on the Apodi Plateau, Brazil

description: ABSTRACT Information is scarce on the genesis and classification of soils derived from calcareous rocks in the Northeastern region of Brazil. This study describes the morphological, physical, chemical, mineralogical, and micromorphological properties of four soil profiles (P1-P4) located in the Apodi Plateau. A pedogenesis hypothesis and soil classification, according to the Brazilian System of Soil Classification (SiBCS), are proposed for these profiles. The interactions between parent material, surface topography and climate affected the pedogenesis processes and soil properties, although the calcareous nature of the parent material most affected the soil morphology and chemical properties. The sand fraction contained mainly quartz and calcite, and a smaller amount of mica. Smectite and interstratified illite-smectite occurred in the clay fraction of profile P1 and in some horizons of P2 (Ccmќ and Ccrќ) and P3 (2Ccrќ). Kaolinite predominated in profiles P2, P3, and P4; where as illite and vermiculite were present in the Bicќ, Bcќ, Bcmќ horizons of P2, in Bt2c of P3, and in C of P4. The mineralogy showed illite, hematite, and goethite, and anatase in a number of horizons. Micromorphological analysis of P2 indicated a strong cementation of Bcmќ and Ccmќ by calcium carbonate, and other properties indicate the formation of a petrocalcic horizon, but this horizon lacked lateral continuity in the profile. Therefore, the parapetrocalcic term is proposed for classifying P2 in the fourth level of the SiBCS. The 3Biќ-P1 horizon exhibited calcite coating and iron coating or quasi-coating, indicating distinct pedogenesis processes occurring under different environmental conditions. Likewise, the occurrence of petroplinthite in P2 indicates that climatic conditions during its formation differed from present conditions, and both situations are interpreted as evidence that the soils were formed by polygenetic processes. In the SiBCS classification, the soils are classified as Cambissolo Háplico Carbonático vertissólico (P1), Cambissolo Háplico Carbonático concrecionário (P2), Luvissolo Crômico Pálico petroplíntico (P3), and Neossolo Litólico Carbonatico típico (P4); and a new class (parapetrocálcico concrecionário) is proposed for P2 in the fourth level.
DOI: 10.6084/m9.figshare.19944435.v1
title: Genesis of Soils Formed from Mafic Igneous Rock in the Atlantic Forest Environment

description: ABSTRACT Different parent materials participate in the formation of soils in the hilly landscape of “Mar de Morros” in the Atlantic Forest environment. Those derived from mafic igneous rock (gabbro) frequently show erosion problems because of land use, which is aggravated by the mountainous relief and soil attributes. This study evaluated the main pedogenic processes of soils formed from mafic igneous rock (gabbro) in a toposequence in Pinheiral (RJ) by characterizing physical, chemical, mineralogical and micromorphological attributes. The profiles are located at different sections in the toposequence: summit (P1), shoulder (P2), backslope (P3) and footslope (P4).They were classified according to the Brazilian System of Soil Classification (SiBCS) and correlated to Soil Taxonomy. The soil morphology of profiles P2, P3 and P4 is expressed by a brownish-red color, blocky structure with high to moderate development, clay films and clay loam to clay texture, with a textural B horizon. P1 shows less development, with a shallow profile and the sequence of horizons A-C-Cr. The soils have a slightly low degree of weathering, identified by the presence of pyroxenes and feldspars in the sand fraction and montorillonite in the clay fraction; the sum of bases is from 15 to 24 cmolc kg-1; and cation exchange capacity (CEC) is from 12 to 22 cmolc kg-1. A significant presence of clay skins was observed in the field and was confirmed by thin section analysis, which showed features such as argillans, ferriargillans and iron nodules. The soil profile at the summit (P1) was classified as Neossolo Regolítico Órtico (Typic Udorthents), and the other profiles as Chernossolo Argilúvicos Órticos (Typic Argiudolls).
DOI: 10.6084/m9.figshare.19944435
title: Genesis of Soils Formed from Mafic Igneous Rock in the Atlantic Forest Environment

description: ABSTRACT Different parent materials participate in the formation of soils in the hilly landscape of “Mar de Morros” in the Atlantic Forest environment. Those derived from mafic igneous rock (gabbro) frequently show erosion problems because of land use, which is aggravated by the mountainous relief and soil attributes. This study evaluated the main pedogenic processes of soils formed from mafic igneous rock (gabbro) in a toposequence in Pinheiral (RJ) by characterizing physical, chemical, mineralogical and micromorphological attributes. The profiles are located at different sections in the toposequence: summit (P1), shoulder (P2), backslope (P3) and footslope (P4).They were classified according to the Brazilian System of Soil Classification (SiBCS) and correlated to Soil Taxonomy. The soil morphology of profiles P2, P3 and P4 is expressed by a brownish-red color, blocky structure with high to moderate development, clay films and clay loam to clay texture, with a textural B horizon. P1 shows less development, with a shallow profile and the sequence of horizons A-C-Cr. The soils have a slightly low degree of weathering, identified by the presence of pyroxenes and feldspars in the sand fraction and montorillonite in the clay fraction; the sum of bases is from 15 to 24 cmolc kg-1; and cation exchange capacity (CEC) is from 12 to 22 cmolc kg-1. A significant presence of clay skins was observed in the field and was confirmed by thin section analysis, which showed features such as argillans, ferriargillans and iron nodules. The soil profile at the summit (P1) was classified as Neossolo Regolítico Órtico (Typic Udorthents), and the other profiles as Chernossolo Argilúvicos Órticos (Typic Argiudolls).
DOI: 10.6084/m9.figshare.19944436.v1
title: Fuzzy Classification in the Determination of Input Application Zones

description: ABSTRACT Correctly interpreting soil fertility and its spatial distribution within an area helps to lessen losses and environmental effects associated with agriculture, to optimize fertilization and liming practices. This study is aimed at using concepts and methods from spatial and temporal analyses to soil fertility and to develop a fuzzy classification methodology in an effort to define input application zones in three conilon coffee harvests. An irregular network with georeferenced points was built in the central region of the farm. Soil samples were collected at 0.00-0.20 m depth within the projections of tree canopies. Geostatistical analysis was used to set up maps in which the variables were shown. In such maps, input and output fuzzy sets were created and applied, as well as rules of inference and determination of to-be-applied logical operators. Fuzzy classification of the area was performed in the three harvests so as to define whether or not inputs were needed. Our main findings show that the N-P-K requirement was spatially dependent in all harvests. By classifying the area using fuzzy logic, it was possible to analyze soil fertility and to indicate the regions having the smallest and greatest needs for N-P-K and liming.