DOI: 10.5281/zenodo.14036321
title: Geochemistry of soils and eroded suspended sediments from two large rural catchments in southern Brazil for studies on Suspended Sediment Fingerprinting

description:  1. Introduction

This dataset comes from a research project entitled "Water and pollutants, from cropfields to cities: evaluation and improved of soil management technologies in a catchment network " supported by the Foundation for Research Support of the State of Rio Grande do Sul (FAPERGS) and National Council for Scientific and Technological Development (CNPq) (process n°10/0034-0). The project was carried out between 2010 and 2014 under the coordination of José Miguel Reichert and Danilo Rheinheimer dos Santos, professors at the Federal University of Santa Maria. One of the aims of this project was to understand the main pollutant transfer process from hillslopes to fluvial systems in large rural catchments representative of the agricultural production system in Southern Brazil. In this context, the Suspended Sediment Fingerprinting (SSF) was extremely useful for quantifying the origin of the sediment yield monitored at the outlet of these catchments. Among the various works carried out in this project, we highlight Tales Tiecher's doctoral thesis (Tiecher, 2015) that explored the SSF in many catchments, including the Conceição and Guaporé river basins.

2. Material and Methods

The catchments represent the magnitude of erosive and hydrological processes representative of Southern Brazil. The Conceição catchment has a drainage area of 804 km2 (28°27′22″S and 53°58′24″ W). According to Köppen, the climate is Cfa type, with an annual rainfall between 1,750 and 2,000 mm. Geology is riodacithe basalt, with a formation of deep and highly weathered soils (Oxisols, Ultisols, and Alfisols). The relief is characterized by gentle slopes (6–9 %) on top and hillside slopes and higher steepness (10–14%) near the drainage channels. Farming based on the production of soybeans (Glycine max) in summer and wheat (Triticumspp.), oats (Avena strigosa), and ryegrass (Lolium multiflorum) in winter. The Guaporé catchment has a drainage area of 1,980 km2 (28°54′41″S and 51°57′10″W), it covers part of the meridional plateau border. The climate is classified as Cfa, with annual rainfall varies between 1,400 and 2,000 mm. Geology is characterized by volcanic lava flows, and topography is undulating to hilly. Due to variations in landscape, several classes of soils (Entisols, Luvisol, Cambisol, Oxisol, Ultisol, and Chernosol). The land use is highly heterogeneous. In the upper third of the catchment, there is a predominance of soybean cultivated under no-tillage soil management. In the other two-thirds (middle and lower parts), land use and soil management are very heterogeneous. The main land uses are tobacco (Nicotiana tabacum) and maize (Zea mays) crops, Eucalyptus (Eucalyptus spp.), as well as pastures for dairy cattle. The contribution of unpaved roads is relevant to the sediment yield in both catchments (Didoné et al., 2014). Composite samples of potential sediment sources (cropland, unpaved roads, and stream channel banks) were collected. Sediment source samples were taken from the surface soil layer (0–0.05 m) of cropland and unpaved roads and on exposed sites located along the river channel network. Each sample was composed of at least 10 subsamples. To obtain representative samples of suspended sediment transported in the catchment’s outlet were used three strategies: (1) to collect flood suspended sediments (FSS) through the manual sampling (USDH-48) at different periods during the rising and falling stages of floods; (2) to deploy time-integrated suspended sediment samplers (TISS), by installing the device developed by Phillips et al. (2000) at different sites within the catchments; to collect fine-bed sediment (FBS) with a suction stainless sampler limiting the loss of fine material at the bed river. Source and sediment samples were oven‐dried at 50 °C, gently disaggregated using a pestle and mortar, and then sieved to 62,5 μm. The geochemical tracers evaluated were total organic carbon estimated by wet oxidation (K2Cr2O7 + H2SO4) and the total concentration of Al, Ba, Be, Ca, Co, Cr, Cu, Fe, K, La, Li, Mg, Mn, Na, Ni, P, Pb, Sr, Ti, V, and Zn using inductively coupled plasma optical emission spectrometry after microwave‐assisted digestion with concentrated HCl and HNO3 (ratio 3:1) for 9.5 min at 182 °C (Tiecher, 2015; Tiecher et al. 2017, 2018).

  3. Final remarks

            The SSF results provided by this dataset (Tiecher, 2015) combined with sediment yield monitoring were very important for the assessment and modeling studies in these two catchments that took place after that (Didoné et al., 2015; 2017). In addition, other studies have explored the same sample bank, expanding upon the array of tracer properties and increasing our understanding about the mechanisms of sediment and pollutant transfer in these catchments (Le Gall et al. 2017; Zafar et al., 2017; Ramon et al., 2020).

 4. References

 Didoné, E. J., Minella, J. P. G., Reichert, J. M., Merten G. H., Dalbianco, L., Barros, C. A. P., Ramon, R. (2014) Impact of no-tillage agricultural systems on sediment yield in two large catchments in southern Brazil. J Soils Sediments 14:1287–1297.

Didoné, E.J., Minella, J.P.G., Evrard, O. (2017). Measuring and modelling soil erosion and sediment yields in a large cultivated catchment under no-till of Southern Brazil. Soil Tillage Res. 174, 24-33. https://doi.org/10.1016/j.still.2017.05.011

Didoné, E. J.; Minela, J. P. G.; Merten, G. H. (2015). Quantifying soil erosion and sediment yield in a catchment in southern Brazil and implications for land conservation. J. Soils Sediments 11, 2334-2346. https://doi.org/10.1007/s11368-015-1160-0

le Gall, M., Evrard, O., Dapoigny, A., Tiecher, T., Zafar, M., Minella, J. P. G., Laceby, J. P., & Ayrault, S. (2017). Tracing sediment sources in a subtropical agricultural catchment of southern Brazil cultivated with conventional and conservation farming practices. Land Degradation and Development, 28(4). https://doi.org/10.1002/ldr.2662

Ramon, R., Evrard, O., Laceby, J. P., Caner, L., Inda, A. v., Barros, C. A. P., Minella, J. P. G., & Tiecher, T. (2020). Combining spectroscopy and magnetism with geochemical tracers to improve the discrimination of sediment sources in a homogeneous subtropical catchment. Catena, 195, 104800. https://doi.org/10.1016/j.catena.2020.104800

Tiecher, T. (2015). Fingerprinting sediment sources in agricultural catchments in Southern Brazil. Doctoral Dissertation in Soil Science. Universidade Federal de Santa Maria, Santa Maria, RS.

Tiecher, T., Minella, J. P. G., Caner, L., Evrard, O., Zafar, M., Capoane, V., le Gall, M., & Santos, D. R. D. (2017). Quantifying land use contributions to suspended sediment in a large cultivated catchment of Southern Brazil (Guaporé River, Rio Grande do Sul). Agriculture, Ecosystems and Environment, 237. https://doi.org/10.1016/j.agee.2016.12.004

Tiecher, T., Minella, J. P. G., Evrard, O., Caner, L., Merten, G. H., Capoane, V., Didoné, E. J., & dos Santos, D. R. (2018). Fingerprinting sediment sources in a large agricultural catchment under no-tillage in Southern Brazil (Conceição River). Land Degradation and Development, 29(4). https://doi.org/10.1002/ldr.2917.

Zafar, M., Tiecher, T., Capoane, V., Troian, A., dos Santos, D.R. (2017). Characteristics, lability and distribution of phosphorus in suspended sediment from a subtropical catchment under diverse anthropic pressure in Southern Brazil. Ecol. Eng. 100, 28–45.