cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.6084/m9.figshare.5668948.v1
title: Size Reduced Iron Nitroprusside Particles: an Electrochemical Mediator for the Quantification of Peroxodisulfate and Nitrite

description: Iron nitroprusside (FeNP) particles have been synthesized from drop by drop (n-FeNP) and bulk mixing (BM) (b-FeNP) methods. FeNP particles obtained from both methods were characterized using X-ray diffraction (XRD) and scanning electron microscopy (SEM). n-FeNP particles were used in constructing modified carbon paste electrode (CPE), which has been further used for electrochemical studies. The effect of pH and electrolyte cation on the electrochemical behavior of n-FeNP modified CPE has been studied in detail. Oxidation of nitrite and reduction of peroxodisulfate reactions have been electrocatalyzed at two redox centers of n-FeNP modified CPE. Based on the electrochemical experiments conducted and Tafel plots, mechanism for both the reactions has been proposed. Both the analytes were estimated in soil and ground water samples using n-FeNP modified CPE and the results were validated with the help of standard methods.
DOI: 10.6084/m9.figshare.5668945
title: Martensitic Transformation Under Compression of a Plasma Processed Polycrystalline Shape Memory CuAlNi Alloy

description: Shape memory alloys (SMA) are attracting considerable attention owing to possible applications from biomedical to aerospace. In particular, CuAlNi alloys present significant advantages associated with low cost, easy processing and superior thermo-electric conductivity over other SMAs such as the NiTi alloys. Characterization of some properties and structural changes caused by martensitic transformation are still open to investigation. The present work evaluated these characteristics in an as-cast plasma processed shape memory Cu-14wt.%Al4wt.%Ni, which was compression tested until fracture. Experimental results showed that an as-cast ingot presents not only chemical and phase homogeneity, but also microstructures composed of grains with martensitic morphology. Martensites β'1 and γ'1, as well as intermediary martensitic R and high temperature β1 were identified by X-ray diffraction tests. It was found that the compressive deformation does not interfere in the phase composition and martensite morphology. However, compression changes the volumetric fractions and crystallographic orientation of the martensites. The mechanical behavior is characterized by an apparent elastic response until the fracture. The fractured surface exhibits brittle aspect like "river patterns" and evidence of intergranular rupture.
DOI: 10.6084/m9.figshare.5668945.v1
title: Martensitic Transformation Under Compression of a Plasma Processed Polycrystalline Shape Memory CuAlNi Alloy

description: Shape memory alloys (SMA) are attracting considerable attention owing to possible applications from biomedical to aerospace. In particular, CuAlNi alloys present significant advantages associated with low cost, easy processing and superior thermo-electric conductivity over other SMAs such as the NiTi alloys. Characterization of some properties and structural changes caused by martensitic transformation are still open to investigation. The present work evaluated these characteristics in an as-cast plasma processed shape memory Cu-14wt.%Al4wt.%Ni, which was compression tested until fracture. Experimental results showed that an as-cast ingot presents not only chemical and phase homogeneity, but also microstructures composed of grains with martensitic morphology. Martensites β'1 and γ'1, as well as intermediary martensitic R and high temperature β1 were identified by X-ray diffraction tests. It was found that the compressive deformation does not interfere in the phase composition and martensite morphology. However, compression changes the volumetric fractions and crystallographic orientation of the martensites. The mechanical behavior is characterized by an apparent elastic response until the fracture. The fractured surface exhibits brittle aspect like "river patterns" and evidence of intergranular rupture.
DOI: 10.6084/m9.figshare.5668939
title: Validation of Family Management Measure for the Brazilian culture

description: ABSTRACT Etjective: To validate the Family Management Measure (FaMM) for Brazilian culture. Method: Quantitative research excerpt, following the recommendations for validation studies. The data presented refer to the last stage of the process. Results: The internal consistency of the items was analyzed through Cronbach's alpha of the six domains: Child's Daily Life (0.78); Condition Management Effort (0.51); Condition Management Ability (0.55); Family Life Difficulty (0.86); View of Condition Impact (0.56); and Parental Mutuality (0.80). Exploratory factorial analysis of the instrument was carried out, obtaining an acceptable adjustment, according to validation standards. Conclusion: The FaMM presents evidence of validation and can be used in the Brazilian culture under the name of Instrumento de Medida de Manejo Familiar, which was adjusted in eight domains, providing varied aspects of family management and a good evaluation of the fundamental aspects of family life in the context of childhood chronic conditions.
DOI: 10.6084/m9.figshare.5668939.v1
title: Validation of Family Management Measure for the Brazilian culture

description: ABSTRACT Etjective: To validate the Family Management Measure (FaMM) for Brazilian culture. Method: Quantitative research excerpt, following the recommendations for validation studies. The data presented refer to the last stage of the process. Results: The internal consistency of the items was analyzed through Cronbach's alpha of the six domains: Child's Daily Life (0.78); Condition Management Effort (0.51); Condition Management Ability (0.55); Family Life Difficulty (0.86); View of Condition Impact (0.56); and Parental Mutuality (0.80). Exploratory factorial analysis of the instrument was carried out, obtaining an acceptable adjustment, according to validation standards. Conclusion: The FaMM presents evidence of validation and can be used in the Brazilian culture under the name of Instrumento de Medida de Manejo Familiar, which was adjusted in eight domains, providing varied aspects of family management and a good evaluation of the fundamental aspects of family life in the context of childhood chronic conditions.
DOI: 10.6084/m9.figshare.5668936
title: Quality of public urban parks for physical activity practice in Bucaramanga, Colombia

description: Abstract The characteristics of parks (availability, accessibility, conservation, quality, safety, etc.) are important predictors of their use for physical activity practices. The aim of this study was to verify the association among the socioeconomic level of neighborhoods, the characteristics and quality of urban public parks for physical activity in Bucaramanga, Colombia. Cross-sectional study, conducted in 2015, in which 10 parks with structures for physical activity were evaluated. The socioeconomic level of the district was evaluated based on the neighborhoods around the parks and classified in “low” and “high”. The number of residents in the surrounding area of parks were evaluated with Geographic Information System (GIS), site characteristics and quality with the System for Observing Play and Recreation in Communities (SOPARC) and the Physical Activity Resource Assessment (PARA), respectively. The association was analyzed with Mann Whitney U test and Spearman correlation (rho) on STATA 14 and the significance level was maintained at 5%. A positive association was found between the socioeconomic level and the presence of walking paths (marginal, p=0.056), accessibility (rho=0.875; p=0.001) and general quality of parks (rho=0.657; p=0.039). The low socioeconomic level was associated with the presence of sports courts (p=0.032). These results can guide the actions of public managers for the modification of the built environment and structures of the parks for physical activity.
DOI: 10.6084/m9.figshare.5668936.v1
title: Quality of public urban parks for physical activity practice in Bucaramanga, Colombia

description: Abstract The characteristics of parks (availability, accessibility, conservation, quality, safety, etc.) are important predictors of their use for physical activity practices. The aim of this study was to verify the association among the socioeconomic level of neighborhoods, the characteristics and quality of urban public parks for physical activity in Bucaramanga, Colombia. Cross-sectional study, conducted in 2015, in which 10 parks with structures for physical activity were evaluated. The socioeconomic level of the district was evaluated based on the neighborhoods around the parks and classified in “low” and “high”. The number of residents in the surrounding area of parks were evaluated with Geographic Information System (GIS), site characteristics and quality with the System for Observing Play and Recreation in Communities (SOPARC) and the Physical Activity Resource Assessment (PARA), respectively. The association was analyzed with Mann Whitney U test and Spearman correlation (rho) on STATA 14 and the significance level was maintained at 5%. A positive association was found between the socioeconomic level and the presence of walking paths (marginal, p=0.056), accessibility (rho=0.875; p=0.001) and general quality of parks (rho=0.657; p=0.039). The low socioeconomic level was associated with the presence of sports courts (p=0.032). These results can guide the actions of public managers for the modification of the built environment and structures of the parks for physical activity.
DOI: 10.6084/m9.figshare.5668933
title: Interference periods of velvet bean in sugarcane

description: ABSTRACT: The objective of the present study was to determine the periods of interference of velvet bean on ratoons of sugarcane cultivar 'RB855536' and to identify its potential for decreasing the crop yield and the quality of the harvested product. The experiment was arranged in a randomized block design, with 18 treatments divided into two groups and four replicates per treatment. In the first group, the sugarcane was kept free from velvet bean interference for nine different periods, beginning at bud sprouting: 0-15, 0-30, 0-45, 0-60, 0-90, 0-120, 0-150, and 0-180 days after budding (DAB) and 0-harvest. In the second group, sugarcane was grown in coexistence with velvet bean during the same periods described for the first group. The critical period of interference prevention for velvet bean in ratoons of sugarcane cv. 'RB 855536' lasted 138 days, from 50 DAB (pre-interference period [PIP]) to188 DAB (total period of weed interference prevention [TPIP]). Velvet bean interference caused a 50% decrease in sugarcane yield and negatively affected the quality of the harvested product.
DOI: 10.6084/m9.figshare.5668933.v1
title: Interference periods of velvet bean in sugarcane

description: ABSTRACT: The objective of the present study was to determine the periods of interference of velvet bean on ratoons of sugarcane cultivar 'RB855536' and to identify its potential for decreasing the crop yield and the quality of the harvested product. The experiment was arranged in a randomized block design, with 18 treatments divided into two groups and four replicates per treatment. In the first group, the sugarcane was kept free from velvet bean interference for nine different periods, beginning at bud sprouting: 0-15, 0-30, 0-45, 0-60, 0-90, 0-120, 0-150, and 0-180 days after budding (DAB) and 0-harvest. In the second group, sugarcane was grown in coexistence with velvet bean during the same periods described for the first group. The critical period of interference prevention for velvet bean in ratoons of sugarcane cv. 'RB 855536' lasted 138 days, from 50 DAB (pre-interference period [PIP]) to188 DAB (total period of weed interference prevention [TPIP]). Velvet bean interference caused a 50% decrease in sugarcane yield and negatively affected the quality of the harvested product.
DOI: 10.6084/m9.figshare.5668930
title: A Prompt, Tough and Eco-Friendly (PTOCO) System for Mini-Scale Extraction of Samples for Antioxidant Capacity Assays

description: The compound extraction is an important step before analyzing composition of samples with antioxidant capacity. Several extraction conditions can be employed (temperature, polarity of solvent and extraction time, for example), and the chosen variables exert great influence upon final results. Thus, in order to execute an efficient extraction, it is needed to manage them with rigor. In this work, a new device was designed and tested. The Prompt, TOugh and eCO-friendly (PTOCO) system is the first equipment in mini-scale that allows a good control of antioxidants extraction conditions. It is a simple and cheap device that only needs small amounts of sample and solvent to obtain sufficient volumes of extract for application in routine analytical methods. Twenty experiments from an experimental design were executed using only 0.5 g of oregano and 60 mL of water. The total antioxidant capacity assays, as well as the mass spectra, confirmed the extraction efficiency.
DOI: 10.6084/m9.figshare.5668930.v1
title: A Prompt, Tough and Eco-Friendly (PTOCO) System for Mini-Scale Extraction of Samples for Antioxidant Capacity Assays

description: The compound extraction is an important step before analyzing composition of samples with antioxidant capacity. Several extraction conditions can be employed (temperature, polarity of solvent and extraction time, for example), and the chosen variables exert great influence upon final results. Thus, in order to execute an efficient extraction, it is needed to manage them with rigor. In this work, a new device was designed and tested. The Prompt, TOugh and eCO-friendly (PTOCO) system is the first equipment in mini-scale that allows a good control of antioxidants extraction conditions. It is a simple and cheap device that only needs small amounts of sample and solvent to obtain sufficient volumes of extract for application in routine analytical methods. Twenty experiments from an experimental design were executed using only 0.5 g of oregano and 60 mL of water. The total antioxidant capacity assays, as well as the mass spectra, confirmed the extraction efficiency.
DOI: 10.6084/m9.figshare.5668924
title: Evaluation of degree of conversion, microtensile bond strength and mechanical properties of three etch-and-rinse dental adhesives

description: Abstract This study evaluated microtensile bond strength (µTBS), degree of conversion, modulus of elasticity and ultramicrohardness of three etch-and-rinse adhesives systems. The materials evaluated were: Ambar (FGM), Optibond (Kerr) and Magic Bond (Vigodent). The degree of conversion was analyzed by FTIR/ATR. To evaluate bond strength (μTBS) in dentin, 15 teeth (n = 5) were restored and sliced to obtain the specimens (0.8mm2). The dynamic ultra microhardness tester was used to evaluate the hardness and modulus of elasticity. The Magic Bond adhesive system showed lower µTBS than Ambar and Optibond (p &lt;0.001). For degree of conversion, comparisons between groups of adhesive systems evaluated showed statistically significant difference (p&lt;0.001), with higher values for Ambar and Optibond when compared a Magic Bond. For modulus of elasticity and ultramicrohardness, Ambar and Magic Bond showed lower values than Optibond. The best results in all properties evaluated were obtained by the Optibond adhesive system.
DOI: 10.6084/m9.figshare.5668924.v1
title: Evaluation of degree of conversion, microtensile bond strength and mechanical properties of three etch-and-rinse dental adhesives

description: Abstract This study evaluated microtensile bond strength (µTBS), degree of conversion, modulus of elasticity and ultramicrohardness of three etch-and-rinse adhesives systems. The materials evaluated were: Ambar (FGM), Optibond (Kerr) and Magic Bond (Vigodent). The degree of conversion was analyzed by FTIR/ATR. To evaluate bond strength (μTBS) in dentin, 15 teeth (n = 5) were restored and sliced to obtain the specimens (0.8mm2). The dynamic ultra microhardness tester was used to evaluate the hardness and modulus of elasticity. The Magic Bond adhesive system showed lower µTBS than Ambar and Optibond (p &lt;0.001). For degree of conversion, comparisons between groups of adhesive systems evaluated showed statistically significant difference (p&lt;0.001), with higher values for Ambar and Optibond when compared a Magic Bond. For modulus of elasticity and ultramicrohardness, Ambar and Magic Bond showed lower values than Optibond. The best results in all properties evaluated were obtained by the Optibond adhesive system.
DOI: 10.6084/m9.figshare.5668912
title: Factors that drive zooplankton diversity in Neo-Tropical Savannah shallow lakes

description: Abstract Zooplankton is an important community in aquatic ecosystems due to its linkage between primary producers and secondary consumers also playing a key role in cycling of organic materials. Aim: Therefore, our objective was to evaluate the effects of physicochemical variables of the water on the diversity of zooplankton community in seven tropical shallow lakes of Brazilian savannah. Methods Zooplankton samples were taken using a bucket and filtered 200 L by a 64 µm-mesh-plankton-net, and preserved for subsequent identification. Water temperature, dissolved oxygen, pH, electrical conductivity, turbidity, chlorophyll-a, ammonium, nitrate, nitrite, total phosphorus, and soluble reactive phosphorus were measured. Results The turbidity (decreases the temperature, luminosity and the system productivity) and ammonium (increases the toxicity) values were the major factors responsible for structuring the zooplankton community. On the other hand, also nitrogen and phosphorus (increase the productivity) are limiting in savannah lentic systems for the zooplankton. The higher α diversity was positively associated with aquatic macrophytes (increase of niches and refuge), whereas lakes with geographic proximity increase the similarity in species composition, decreasing the β diversity. Conclusions We conclude that the deterministic processes (niche theory), due to species have different ecological requirements, are different responses to environmental gradients and increase the diversity in heterogenic lentic systems.
DOI: 10.6084/m9.figshare.5668912.v1
title: Factors that drive zooplankton diversity in Neo-Tropical Savannah shallow lakes

description: Abstract Zooplankton is an important community in aquatic ecosystems due to its linkage between primary producers and secondary consumers also playing a key role in cycling of organic materials. Aim: Therefore, our objective was to evaluate the effects of physicochemical variables of the water on the diversity of zooplankton community in seven tropical shallow lakes of Brazilian savannah. Methods Zooplankton samples were taken using a bucket and filtered 200 L by a 64 µm-mesh-plankton-net, and preserved for subsequent identification. Water temperature, dissolved oxygen, pH, electrical conductivity, turbidity, chlorophyll-a, ammonium, nitrate, nitrite, total phosphorus, and soluble reactive phosphorus were measured. Results The turbidity (decreases the temperature, luminosity and the system productivity) and ammonium (increases the toxicity) values were the major factors responsible for structuring the zooplankton community. On the other hand, also nitrogen and phosphorus (increase the productivity) are limiting in savannah lentic systems for the zooplankton. The higher α diversity was positively associated with aquatic macrophytes (increase of niches and refuge), whereas lakes with geographic proximity increase the similarity in species composition, decreasing the β diversity. Conclusions We conclude that the deterministic processes (niche theory), due to species have different ecological requirements, are different responses to environmental gradients and increase the diversity in heterogenic lentic systems.
DOI: 10.6084/m9.figshare.5668903
title: PREDICTION SPATIAL PATTERNS OF WINDTHROW PHENOMENON IN DECIDUOUS TEMPERATE FORESTS USING LOGISTIC REGRESSION AND RANDOM FOREST

description: ABSTRACT Forest management needs to evaluate various hazards where may cause economic or other losses to forest owners. The aim of this study is to prepare windthrow hazard maps based on logistic regression and random forest models in Nowshahr Forests, Mazandaran Province, Iran. First of all, 200 windthrow locations were identified from extensive field surveys and some reports. Out these, 140 (70%) locations were randomly selected as training data and the remaining 60 (30%) cases were used for the validation goals. In the next step, 10 predictive variables such as slope degree, slope aspect, altitude, Topographic Position Index (TPI), Topographic Wetness Index (TWI), distance to roads and skid trails, wind effect, soil texture, forest type and stand density were extracted from the spatial database. Subsequently, windthrow hazard maps were produced using logistic regression and RF models, and the results were plotted in ArcGIS. Finally, the area under the curves (AUC) and kappa coefficient were made for performance purposes. The validation of results presented that the area under the curve and kappa have a more accuracy for the random forest (97.5%, and 95%, respectively) than logistic regression (96.667%, and 93.333%, respectively) model. Therefore, this technique has more potentiality to be applied in the evaluation of windthrow phenomenon in forest ecosystems. Additionally, both models indicate that the spatial distribution of windthrow incidence likelihood is highly variable in this region. In general, the mentioned findings can be applied for management of future windthrow in favor of economic benefits and environmental preservation.
DOI: 10.6084/m9.figshare.5668903.v1
title: PREDICTION SPATIAL PATTERNS OF WINDTHROW PHENOMENON IN DECIDUOUS TEMPERATE FORESTS USING LOGISTIC REGRESSION AND RANDOM FOREST

description: ABSTRACT Forest management needs to evaluate various hazards where may cause economic or other losses to forest owners. The aim of this study is to prepare windthrow hazard maps based on logistic regression and random forest models in Nowshahr Forests, Mazandaran Province, Iran. First of all, 200 windthrow locations were identified from extensive field surveys and some reports. Out these, 140 (70%) locations were randomly selected as training data and the remaining 60 (30%) cases were used for the validation goals. In the next step, 10 predictive variables such as slope degree, slope aspect, altitude, Topographic Position Index (TPI), Topographic Wetness Index (TWI), distance to roads and skid trails, wind effect, soil texture, forest type and stand density were extracted from the spatial database. Subsequently, windthrow hazard maps were produced using logistic regression and RF models, and the results were plotted in ArcGIS. Finally, the area under the curves (AUC) and kappa coefficient were made for performance purposes. The validation of results presented that the area under the curve and kappa have a more accuracy for the random forest (97.5%, and 95%, respectively) than logistic regression (96.667%, and 93.333%, respectively) model. Therefore, this technique has more potentiality to be applied in the evaluation of windthrow phenomenon in forest ecosystems. Additionally, both models indicate that the spatial distribution of windthrow incidence likelihood is highly variable in this region. In general, the mentioned findings can be applied for management of future windthrow in favor of economic benefits and environmental preservation.