cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.6084/m9.figshare.7186934.v1
title: Emerald from the Fazenda Bonfim Deposit, northeastern Brazil: chemical, fluid inclusions and oxygen isotope data

description: ABSTRACT: The Fazenda Bonfim emerald deposit, State of Rio Grande do Norte, is within the regional geological domain known as Seridó Mobile Belt, Borborema Tectonic Province. It was formed from metasomatic fluids interaction at along lithological contacts between Be-rich albite-granite intrusions and Cr (±V)-rich mafic-ultramafic host-rocks, enclosed in the lens-shaped “hornfels” phlogopite schist. Emerald crystals display relatively high contents of Mg and Na, as well as trace amounts of Ca, K, Cs, Li, P, Sc, Ti, Mn, Co, Ni, Zn, Ga and Rb. Cr is the main chromophore element, followed by Fe and some V. Display also concentric growth zones and randomly-oriented mineral micro-inclusions, indicative for static growth. This zoning is linked to cationic substitution of alkalis accompanied by Cr loss, which favors irregular coloration of crystals. Metasomatic fluids contemporaneous with emerald growth are aqueous (H 2 O+NaCl), with low to moderate salinity and low density, although trace amounts of CO 2 ± CH 4 were also observed. These fluids showed a field-trapped between 375-430ºC and 200-600 bars, based on combination of fluid inclusions isochores. In addition, oxygen isotope data (δ 18 O = 6.9-7.4‰) suggest an igneous-metasomatic source for fluids and emerald components.
DOI: 10.6084/m9.figshare.7185683
title: The Mata Azul pegmatitic field, Tocantins/Goiás, central Brazil: geology, genesis and mineralization

description: ABSTRACT: In Goiás and Tocantins States, Central Brazil, several granitic pegmatites were characterized and grouped for the first time. These pegmatites had been intensely explored by hand in the past, producing mainly gemstone varieties of tourmaline and beryl. Barren, beryl- and tourmaline-bearing pegmatites occur across an area of 2,000 km 2 where they intrude regional metasedimentary rocks and peraluminous granites. K-feldspar (mostly altered to kaolin), quartz and mica (mainly muscovite) are the major minerals. The main accessory minerals are beryl, tourmaline, garnet, albite, Fe-Mn phosphate aggregates, and trilithionite. The paragneiss surrounding the barren pegmatites was affected by thermal metamorphism and later hydrothermal alteration, producing Ca-silicates, Ti-Nb-Y oxides and sulfides. Leucogranites of the Mata Azul Suite are peraluminous and syn- to post-orogenic with geochemical characteristics of the LCT granite-pegmatite group. LA-ICP-MS U-Pb geochronology in monazite yields an age of 519 ± 2.8 Ma. Additionally, U-Th-Pb chemical dating of uraninite reveals a maximum age between 500 and 560 Ma. These ages, the field relationships, the mineralogy and the geochemical data suggest that the granites of the Mata Azul Suite are the probable sources of the studied pegmatites. The mineral associations and the mineral chemistry are used to define the degree of fractionation of the pegmatites. We propose that the group of studied pegmatites represents a pegmatitic field, called the Mata Azul Suite Pegmatitic Field.
DOI: 10.6084/m9.figshare.7187117
title: Tafonomy of macroinvertebrates and Albian marine ingression as recorded by the Romualdo Formation (Cretaceous, Araripe Basin, Brazil)

description: ABSTRACT: The Romualdo Formation, Araripe Basin, crops out in the municipality of Exu, Pernambuco State, exposing coquinas. Fauna survey, taphonomic analysis of the macrobenthos, and identification of sedimentary facies of the outcrop were carried out to contribute to paleoenvironmental understanding of the Romualdo Formation. The association of molluscs (Cerithium sp., Tylostoma ranchariensis, Aguileria dissita, Brachidontes araripensis and unidentified cassiopids) and echinoids of the species Bothryopneustes araripensis suggests sedimentation in the marine environment. The taphonomic similarities made possible the grouping of coquinas into two types. Coquinas type 1 exhibit characteristics of transport and reworking of bioclast generated by storms in proximal setting. Coquinas type 2 demonstrates echinoids in situ and articulated with spines connected to shells, suggesting a fast sedimentation by distal tempestite. Regarding sedimentary facies, the concentrations of invertebrates would have been formed in the transitional offshore zone of siliclastic platform. The results presented here evidence a broader distribution of echinoids and expand the geographic limits of the shallow marine environment in the Romualdo Formation.
DOI: 10.6084/m9.figshare.7187117.v1
title: Tafonomy of macroinvertebrates and Albian marine ingression as recorded by the Romualdo Formation (Cretaceous, Araripe Basin, Brazil)

description: ABSTRACT: The Romualdo Formation, Araripe Basin, crops out in the municipality of Exu, Pernambuco State, exposing coquinas. Fauna survey, taphonomic analysis of the macrobenthos, and identification of sedimentary facies of the outcrop were carried out to contribute to paleoenvironmental understanding of the Romualdo Formation. The association of molluscs (Cerithium sp., Tylostoma ranchariensis, Aguileria dissita, Brachidontes araripensis and unidentified cassiopids) and echinoids of the species Bothryopneustes araripensis suggests sedimentation in the marine environment. The taphonomic similarities made possible the grouping of coquinas into two types. Coquinas type 1 exhibit characteristics of transport and reworking of bioclast generated by storms in proximal setting. Coquinas type 2 demonstrates echinoids in situ and articulated with spines connected to shells, suggesting a fast sedimentation by distal tempestite. Regarding sedimentary facies, the concentrations of invertebrates would have been formed in the transitional offshore zone of siliclastic platform. The results presented here evidence a broader distribution of echinoids and expand the geographic limits of the shallow marine environment in the Romualdo Formation.
DOI: 10.6084/m9.figshare.7186769
title: Incised valley paleoenvironments interpreted by seismic stratigraphic approach in Patos Lagoon, Southern Brazil

description: ABSTRACT: The Rio Grande do Sul (RS) coastal plain area (33,000 km 2 ) had its physiography modified several times through the Quaternary, responding to allogenic and autogenic forcings. The Patos Lagoon covers a significant area of RS coastal plain (10,000 km 2 ), where incised valleys were identified in previous works. About 1,000 km of high resolution (3.5 kHz) seismic profiles, radiocarbon datings, Standard Penetration Test (SPT) and gravity cores were analyzed to interpret the paleoenvironmental evolution as preserved in incised valley infills. Seismic facies were recognized by seismic parameters. The sediment cores were used to ground-truth the seismic interpretations and help in the paleoenvironmental identification. Key surfaces were established to detail the stratigraphical framework, and seismic facies were grouped into four seismic units, which one classified in respective system tracts within three depositional sequences. The oldest preserved deposits are predominantly fluvial and estuarine facies, representing the falling stage and lowstand system tracts. The Holocene transgressive records are dominated by muddy material, mainly represented by estuarine facies with local variations. The transgression culminated in Late Holocene deposits of Patos Lagoon, representing the highstand system tract. The depositional pattern of the vertical succession was controlled by eustatic variations, while the autogenic forcing (paleogeography and sediment supply) modulated the local facies variation.
DOI: 10.6084/m9.figshare.7186769.v1
title: Incised valley paleoenvironments interpreted by seismic stratigraphic approach in Patos Lagoon, Southern Brazil

description: ABSTRACT: The Rio Grande do Sul (RS) coastal plain area (33,000 km 2 ) had its physiography modified several times through the Quaternary, responding to allogenic and autogenic forcings. The Patos Lagoon covers a significant area of RS coastal plain (10,000 km 2 ), where incised valleys were identified in previous works. About 1,000 km of high resolution (3.5 kHz) seismic profiles, radiocarbon datings, Standard Penetration Test (SPT) and gravity cores were analyzed to interpret the paleoenvironmental evolution as preserved in incised valley infills. Seismic facies were recognized by seismic parameters. The sediment cores were used to ground-truth the seismic interpretations and help in the paleoenvironmental identification. Key surfaces were established to detail the stratigraphical framework, and seismic facies were grouped into four seismic units, which one classified in respective system tracts within three depositional sequences. The oldest preserved deposits are predominantly fluvial and estuarine facies, representing the falling stage and lowstand system tracts. The Holocene transgressive records are dominated by muddy material, mainly represented by estuarine facies with local variations. The transgression culminated in Late Holocene deposits of Patos Lagoon, representing the highstand system tract. The depositional pattern of the vertical succession was controlled by eustatic variations, while the autogenic forcing (paleogeography and sediment supply) modulated the local facies variation.
DOI: 10.6084/m9.figshare.7591367
title: Gold deposits in poly-deformed metasedimentary rocks: a case study of the C1-Santaluz gold deposit, Itapicuru Greenstone Belt, Northeast of Brazil

description: ABSTRACT: The C1-Santaluz gold deposit is located in the Itapicuru greenstone belt in Bahia State, Brazil. Metavolcanic and metasedimentary rocks dominate at the base and top, respectively. The ore minerals related to the auriferous mineralization are pyrite, arsenopyrite, sphalerite, chalcopyrite and stibnite. Arsenopyrite is related to, and associated with the presence of gold in quartz veins, a feature which is detected by scanning electron microscope analyses. The deposit is structurally complex, with tree deformational phases being recognized: D n-1 , D n , and D n+1 . Phases D n-1 and D n have a direct relation to the mineralization, and mineralized quartz veins are parallel to the S n foliation (S 0 //S n-1 //S n ). The intersection between the S 0 //S n-1 bedding and the S n foliation generates an intersection lineation parallel to the D n fold axis, plunging to the NW, which has favored an increase in the volume of mineralized bodies.
DOI: 10.6084/m9.figshare.7591367.v1
title: Gold deposits in poly-deformed metasedimentary rocks: a case study of the C1-Santaluz gold deposit, Itapicuru Greenstone Belt, Northeast of Brazil

description: ABSTRACT: The C1-Santaluz gold deposit is located in the Itapicuru greenstone belt in Bahia State, Brazil. Metavolcanic and metasedimentary rocks dominate at the base and top, respectively. The ore minerals related to the auriferous mineralization are pyrite, arsenopyrite, sphalerite, chalcopyrite and stibnite. Arsenopyrite is related to, and associated with the presence of gold in quartz veins, a feature which is detected by scanning electron microscope analyses. The deposit is structurally complex, with tree deformational phases being recognized: D n-1 , D n , and D n+1 . Phases D n-1 and D n have a direct relation to the mineralization, and mineralized quartz veins are parallel to the S n foliation (S 0 //S n-1 //S n ). The intersection between the S 0 //S n-1 bedding and the S n foliation generates an intersection lineation parallel to the D n fold axis, plunging to the NW, which has favored an increase in the volume of mineralized bodies.
DOI: 10.6084/m9.figshare.7591490
title: The 9 Mile Deposit of the Barama-Mazaruni Greenstone Belt of the Guiana Shield: geochemistry, geochronology and regional significance

description: ABSTRACT: The granitoid and greenstone-hosted 9 Mile Deposit, located in the Paleoproterozoic Barama-Mazaruni Greenstone Belt of the Guiana Shield, is one of a series of gold deposits within the NW-SE trending Makapa-Kuribrong Shear Zone (MKSZ), which extends from Venezuela, through Guyana, and French Guiana. The 9 Mile Deposit is underlain by the upper section of a shallowly-dipping meta-rhyolite rock, which was intruded by a host granodiorite and subsequently intruded by of a series of mafic dykes. Auriferous quartz veins are associated with the NE-SW thrust which was crosscut by a steep E-W shear zone, at least 12 km in length. Field relationships and lithogeochemical data suggest that the granodiorite was crustally derived and emplaced in a volcanic arc or syn- to late-collisional setting. U-Pb (SHRIMP II) dating of zircons indicates the granodiorite intruded at approximately 2.15, Ga suggesting it is a local representative of a regional suite of syn- to late-tectonic granitoid plutons emplaced during the main phase of Trans-Amazonian Orogeny.
DOI: 10.6084/m9.figshare.7591490.v1
title: The 9 Mile Deposit of the Barama-Mazaruni Greenstone Belt of the Guiana Shield: geochemistry, geochronology and regional significance

description: ABSTRACT: The granitoid and greenstone-hosted 9 Mile Deposit, located in the Paleoproterozoic Barama-Mazaruni Greenstone Belt of the Guiana Shield, is one of a series of gold deposits within the NW-SE trending Makapa-Kuribrong Shear Zone (MKSZ), which extends from Venezuela, through Guyana, and French Guiana. The 9 Mile Deposit is underlain by the upper section of a shallowly-dipping meta-rhyolite rock, which was intruded by a host granodiorite and subsequently intruded by of a series of mafic dykes. Auriferous quartz veins are associated with the NE-SW thrust which was crosscut by a steep E-W shear zone, at least 12 km in length. Field relationships and lithogeochemical data suggest that the granodiorite was crustally derived and emplaced in a volcanic arc or syn- to late-collisional setting. U-Pb (SHRIMP II) dating of zircons indicates the granodiorite intruded at approximately 2.15, Ga suggesting it is a local representative of a regional suite of syn- to late-tectonic granitoid plutons emplaced during the main phase of Trans-Amazonian Orogeny.
DOI: 10.6084/m9.figshare.7591346
title: First Lu-Hf, δ18O and trace elements in zircon signatures from the Statherian Espinhaço anorogenic province (Eastern Brazil): geotectonic implications of a silicic large igneous province

description: ABSTRACT: The Espinhaço rift system encompasses taphrogenetic events from the Statherian to Tonian in the São Francisco-Congo (SFC) paleocontinent. The magmatism is represented mainly by metamorphosed anorogenic granites and rhyolites with subordinate amphibolites. Zircon U-Pb (LA-ICPMS and SHRIMP) ages from felsic (1748 ± 3 Ma and 1740 ± 8 Ma) and mafic (1725 ± 4 Ma) rock samples, coupled with previous studies suggest that the Espinhaço igneous province erupted from ca. 1.79 Ga to ca. 1.70 Ga. The felsic rocks show characteristics of A-type magmas. The negative εHf(t) data for meta-rhyolite zircons (-12.32 to -17.58), the moderate δ 18 O values (7.02 to 7.98) and the REE patterns suggest crustal melting related to an extensional environment. The mafic rock shows negative values of εHf(t) in zircons (-4.05 to -8.25) and moderate δ 18 O values (5.56 to 7.87). The results disclose a basaltic magmatism in continental intraplate setting whose parental magma could have been derived from the subcontinental lithospheric mantle with contamination of crustal material. These data coupled with coeval Espinhaço magmatism and mafic dyke swarms found to the south of the Espinhaço rift system reinforce the evidence of a long-lived Statherian silicic large igneous province (SLIP) on the SFC paleocontinental block.
DOI: 10.6084/m9.figshare.7591484
title: The São Jerônimo da Serra Site, Rio do Rasto Formation (Middle/Upper Permian), Paraná Basin, Brazil: faciological and taphonomic context

description: ABSTRACT: In this contribution, we present an analysis of the main faciological features of the São Jerônimo da Serra Site, related to the Morro Pelado Member of Rio do Rasto Formation (Middle/Upper Permian), from Paraná State, Brazil, integrated to its taphonomic context. The outcrop, rich in vertebrates and bivalves remains, presents a succession of red siltstones bedded with fine to medium sandstones in which three architectural elements were observed: SF (sheetflood deposits), FF (fine of flood plain) and CS (crevasse). These data, allied to the taphonomic signatures of fossils assigned to eight levels, allowed the identification of three taphofacies. The taphofacies I is characterized by preserved bones in floodplain facies, with different articulation grades and absence of any sign of transport. The taphofacies II is composed by small isolated or fragmented bones and fish scales deposited in terminal splay facies. The taphofacies III is characterized by sandy layers with bivalve shells and fish scales, preserved in crevasse-splay deposits. The obtained data shows that the studied sedimentary succession was generated on a dry trend environment, with sporadic water supply, which conditioned the fossil preservation.
DOI: 10.6084/m9.figshare.7591484.v1
title: The São Jerônimo da Serra Site, Rio do Rasto Formation (Middle/Upper Permian), Paraná Basin, Brazil: faciological and taphonomic context

description: ABSTRACT: In this contribution, we present an analysis of the main faciological features of the São Jerônimo da Serra Site, related to the Morro Pelado Member of Rio do Rasto Formation (Middle/Upper Permian), from Paraná State, Brazil, integrated to its taphonomic context. The outcrop, rich in vertebrates and bivalves remains, presents a succession of red siltstones bedded with fine to medium sandstones in which three architectural elements were observed: SF (sheetflood deposits), FF (fine of flood plain) and CS (crevasse). These data, allied to the taphonomic signatures of fossils assigned to eight levels, allowed the identification of three taphofacies. The taphofacies I is characterized by preserved bones in floodplain facies, with different articulation grades and absence of any sign of transport. The taphofacies II is composed by small isolated or fragmented bones and fish scales deposited in terminal splay facies. The taphofacies III is characterized by sandy layers with bivalve shells and fish scales, preserved in crevasse-splay deposits. The obtained data shows that the studied sedimentary succession was generated on a dry trend environment, with sporadic water supply, which conditioned the fossil preservation.
DOI: 10.6084/m9.figshare.7591346.v1
title: First Lu-Hf, δ18O and trace elements in zircon signatures from the Statherian Espinhaço anorogenic province (Eastern Brazil): geotectonic implications of a silicic large igneous province

description: ABSTRACT: The Espinhaço rift system encompasses taphrogenetic events from the Statherian to Tonian in the São Francisco-Congo (SFC) paleocontinent. The magmatism is represented mainly by metamorphosed anorogenic granites and rhyolites with subordinate amphibolites. Zircon U-Pb (LA-ICPMS and SHRIMP) ages from felsic (1748 ± 3 Ma and 1740 ± 8 Ma) and mafic (1725 ± 4 Ma) rock samples, coupled with previous studies suggest that the Espinhaço igneous province erupted from ca. 1.79 Ga to ca. 1.70 Ga. The felsic rocks show characteristics of A-type magmas. The negative εHf(t) data for meta-rhyolite zircons (-12.32 to -17.58), the moderate δ 18 O values (7.02 to 7.98) and the REE patterns suggest crustal melting related to an extensional environment. The mafic rock shows negative values of εHf(t) in zircons (-4.05 to -8.25) and moderate δ 18 O values (5.56 to 7.87). The results disclose a basaltic magmatism in continental intraplate setting whose parental magma could have been derived from the subcontinental lithospheric mantle with contamination of crustal material. These data coupled with coeval Espinhaço magmatism and mafic dyke swarms found to the south of the Espinhaço rift system reinforce the evidence of a long-lived Statherian silicic large igneous province (SLIP) on the SFC paleocontinental block.
DOI: 10.6084/m9.figshare.7591436
title: Ionic content in an ice core from the West Antarctic Ice Sheet: 1882-2008 A.D.

description: ABSTRACT: The study of atmospheric aerosols through polar ice cores is one of the most common and robust tools for the investigation of past changes in the circulation and chemistry of the atmosphere. Only a few subannual resolution records are available for the development of paleochemical and environmental interpretations. Here, we report the ionic content record for the period of 1882-2008 A.D. in an ice core recovered at the ice divide of the West Antarctic Ice Sheet. The ion concentrations found in the core were determined by ion chromatography on more than 2,000 samples and the basic statistics were calculated for major inorganic and organic ions. The dating of the core layers was based on the seasonality of SO 4 2- , NO 3 - , and Na + , checked by the identification of the Krakatau (1883), Agung (1963) and Pinatubo/Hudson (1991) volcanic eruption signals. Significant aerosol input events were identified and grouped considering the ions present, their provenance and the season. The ionic balance, together with the decomposition of some origin indicators, showed that 36% of the ionic charge is derived from sea salt aerosols, 13% from mineral dust, and 17% from biogenic marine activity, while 34% are mainly products of chemical reactivity in the atmosphere.
DOI: 10.6084/m9.figshare.7591436.v1
title: Ionic content in an ice core from the West Antarctic Ice Sheet: 1882-2008 A.D.

description: ABSTRACT: The study of atmospheric aerosols through polar ice cores is one of the most common and robust tools for the investigation of past changes in the circulation and chemistry of the atmosphere. Only a few subannual resolution records are available for the development of paleochemical and environmental interpretations. Here, we report the ionic content record for the period of 1882-2008 A.D. in an ice core recovered at the ice divide of the West Antarctic Ice Sheet. The ion concentrations found in the core were determined by ion chromatography on more than 2,000 samples and the basic statistics were calculated for major inorganic and organic ions. The dating of the core layers was based on the seasonality of SO 4 2- , NO 3 - , and Na + , checked by the identification of the Krakatau (1883), Agung (1963) and Pinatubo/Hudson (1991) volcanic eruption signals. Significant aerosol input events were identified and grouped considering the ions present, their provenance and the season. The ionic balance, together with the decomposition of some origin indicators, showed that 36% of the ionic charge is derived from sea salt aerosols, 13% from mineral dust, and 17% from biogenic marine activity, while 34% are mainly products of chemical reactivity in the atmosphere.