cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.25377/sussex.28615223
title: Data for paper: Reduction of Hexaazatrinaphthylenes by Masked Divalent Lanthanide Dinitrogen Reagents

description: Data for paper published in <i>Inorganic Chemistry</i> (June 25, 2025)X-ray crystallography data in .cif format.checkCIF files for X-ray crystallography data in .pdf format.EPR spectroscopy data.IR spectroscopy data.magnetic measurement data.<br><br>AbstractThe oxidation state +2 is of interest in rare-earth chemistry since it allows these conventionally redox-inactive metals to be used as reducing agents. However, the divalent oxidation state is difficult to form for most rare-earth elements, and the ensuing compounds are often unstable. Here, we describe an approach to rare-earth reduction chemistry that circumvents the divalent oxidation state by using compounds of trivalent rare earths that store reducing electrons on the dinitrogen ligand [N<sub>2</sub>]<sup>2–</sup>, akin to ‘masked’ divalent reactivity. Thus, the dinitrogen complexes(<b>1</b><sub><strong>M</strong></sub>, M = Y, Gd, Tb, Dy) reduce hexaazatrinaphthylene and its hexamethyl derivative to give trimetallic, where the [R<sub>6</sub>HAN]<sup>3–</sup> ligands (R = H, <b>2</b><sub><strong>M</strong></sub>; R = Me, <b>3</b><sub><strong>M</strong></sub>) form with <i>S</i> = 1/2, and with elimination of N<sub>2</sub>. The structures of <b>2</b><sub><strong>M</strong></sub> and <b>3</b><sub><strong>M</strong></sub> reveal that the <i>tert</i>-butyl substituents strongly influence the core geometry of these trimetallic complexes. Analysis of the magnetism and electronic structure of <b>2</b><sub><strong>Gd</strong></sub> and <b>3</b><sub><strong>Gd</strong></sub> identifies ferromagnetic metal-radical exchange, with coupling constants of <i>J</i> = +2.87 cm<sup>–1</sup> and +3.07 cm<sup>–1</sup>, respectively (–2<i>J</i> formalism). The unusual ferromagnetic exchange is a consequence of charge transfer to the gadolinium 5d, 6s and 6p orbitals from the radical ligands.
DOI: 10.25377/sussex.28615223.v1
title: Data for paper: Reduction of Hexaazatrinaphthylenes by Masked Divalent Lanthanide Dinitrogen Reagents

description: Data for paper published in <i>Inorganic Chemistry</i> (June 25, 2025)X-ray crystallography data in .cif format.checkCIF files for X-ray crystallography data in .pdf format.EPR spectroscopy data.IR spectroscopy data.magnetic measurement data.<br><br>AbstractThe oxidation state +2 is of interest in rare-earth chemistry since it allows these conventionally redox-inactive metals to be used as reducing agents. However, the divalent oxidation state is difficult to form for most rare-earth elements, and the ensuing compounds are often unstable. Here, we describe an approach to rare-earth reduction chemistry that circumvents the divalent oxidation state by using compounds of trivalent rare earths that store reducing electrons on the dinitrogen ligand [N<sub>2</sub>]<sup>2–</sup>, akin to ‘masked’ divalent reactivity. Thus, the dinitrogen complexes(<b>1</b><sub><strong>M</strong></sub>, M = Y, Gd, Tb, Dy) reduce hexaazatrinaphthylene and its hexamethyl derivative to give trimetallic, where the [R<sub>6</sub>HAN]<sup>3–</sup> ligands (R = H, <b>2</b><sub><strong>M</strong></sub>; R = Me, <b>3</b><sub><strong>M</strong></sub>) form with <i>S</i> = 1/2, and with elimination of N<sub>2</sub>. The structures of <b>2</b><sub><strong>M</strong></sub> and <b>3</b><sub><strong>M</strong></sub> reveal that the <i>tert</i>-butyl substituents strongly influence the core geometry of these trimetallic complexes. Analysis of the magnetism and electronic structure of <b>2</b><sub><strong>Gd</strong></sub> and <b>3</b><sub><strong>Gd</strong></sub> identifies ferromagnetic metal-radical exchange, with coupling constants of <i>J</i> = +2.87 cm<sup>–1</sup> and +3.07 cm<sup>–1</sup>, respectively (–2<i>J</i> formalism). The unusual ferromagnetic exchange is a consequence of charge transfer to the gadolinium 5d, 6s and 6p orbitals from the radical ligands.
DOI: 10.15468/dl.q5qxra
title: Occurrence Download

description: A dataset containing 23 species occurrences available in GBIF matching the query:
{
 "and" : [
 "TaxonKey is Oenothera macrocarpa",
 "Country is Czechia",
 "HasCoordinate is true"
 ]
}

 The dataset includes 23 records from 3 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0041205-250920141307145/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.2d6zdv
title: Occurrence Download

description: A dataset containing 4 species occurrences available in GBIF matching the query:
{
 "TaxonKey" : [
 "is Pituna xinguensis"
 ]
}

 The dataset includes 4 records from 2 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0041207-250920141307145/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.26023/wxw9-qgjr-jx0k
title: UAH Precipitation Imaging Package (PIP) Data. Version 1.0

description: This dataset contains snowflake video imagery and plots collected by the University of Alabama-Huntsville using the NASA GSFC Precipitation Imaging Package (PIP) during the Ontario Winter Lake-effect Systems (OWLeS) project from 26 December 2013 through 12 February 2014.
DOI: 10.15468/dl.7qawxq
title: Occurrence Download

description: A dataset containing 0 species occurrences available in GBIF matching the query:
{
 "and" : [
 "TaxonKey is Oenothera macrocarpa",
 "Country is Japan",
 "HasCoordinate is true"
 ]
}

 The dataset includes 0 records from 0 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0041206-250920141307145/datasets/export for details.
DOI: 10.15468/dl.th3jhb
title: Occurrence Download

description: A dataset containing 430 species occurrences available in GBIF matching the query:
{
 "and" : [
 "TaxonKey is Vespidae",
 "Year is 1972",
 "Continent is North America",
 "HasCoordinate is true"
 ]
}

 The dataset includes 430 records from 21 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0041210-250920141307145/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.26023/4fsg-x94c-r10k
title: UAH MIPS Time Lapse Camera Static Imagery. Version 1.0

description: This dataset contains static images taken with the UAH MIPS Time Lapse Camera during the Ontario Winter Lake-effect Systems (OWLeS) project from 12 December 2013 to 28 January 2014. The camera was located at the Shineman Center on the SUNY-Oswego campus pointing northward over Lake Ontario. The images are in JPEG format, tarred together in one-hour groups. This is a large dataset containing over 700 tar files.
DOI: 10.15468/dl.4wwb7y
title: Occurrence Download

description: A dataset containing 25 species occurrences available in GBIF matching the query:
{
 "and" : [
 "Country is Costa Rica",
 "TaxonKey is Senna quinquangulata"
 ]
}

 The dataset includes 25 records from 9 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0041212-250920141307145/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.r3y42e
title: Occurrence Download

description: A dataset containing 4 species occurrences available in GBIF matching the query:
{
 "and" : [
 "Country is Colombia",
 "PublishingOrg is 0e2f2e28-7790-4c82-b8fb-6ef7b4c764e2",
 "TaxonKey is Pycnoporus sanguineus"
 ]
}

 The dataset includes 4 records from 1 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0041213-250920141307145/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.26023/sysk-6nk2-360b
title: Millersville University Tethersonde Data. Version 1.0

description: This dataset contains Millersville University Tethersonde data taken during the Ontario Winter Lake-effect Systems (OWLeS) project from 10 December 2013 to 28 January 2014. The data are in ASCII text format.
DOI: 10.34740/kaggle/dsv/13245203
title: Adidas Dataset
DOI: 10.15468/dl.3cfhv5
title: Occurrence Download

description: A dataset containing 2 species occurrences available in GBIF matching the query:
{
 "and" : [
 "TaxonKey is Oenothera wienii",
 "Country is Czechia",
 "HasCoordinate is true"
 ]
}

 The dataset includes 2 records from 1 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0041215-250920141307145/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.snc32x
title: Occurrence Download

description: A dataset containing 0 species occurrences available in GBIF matching the query:
{
 "and" : [
 "TaxonKey is Oenothera wienii",
 "Country is Latvia",
 "HasCoordinate is true"
 ]
}

 The dataset includes 0 records from 0 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0041216-250920141307145/datasets/export for details.
DOI: 10.15468/dl.h82d2t
title: Occurrence Download

description: A dataset containing 357 species occurrences available in GBIF matching the query:
{
 "and" : [
 "TaxonKey is Oenothera wienii",
 "Country is Poland",
 "HasCoordinate is true"
 ]
}

 The dataset includes 357 records from 7 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0041217-250920141307145/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.26023/mh1m-ct7w-230c
title: Millersville University Flux Tower Data. Version 1.0

description: This dataset contains Millersville University Flux Tower Data collected from 4 December 2013 to 28 January 2014 as part of the Ontario Winter Lake-effect Systems (OWLeS) field campaign. These data include Excel files and PDF files containing plots of the data.
DOI: 10.15468/dl.qxk2jt
title: Occurrence Download

description: A dataset containing 359 species occurrences available in GBIF matching the query:
{
 "and" : [
 "TaxonKey is Vespidae",
 "Year is 1973",
 "Continent is Europe",
 "HasCoordinate is true"
 ]
}

 The dataset includes 359 records from 30 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0041219-250920141307145/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.26023/65b6-5ehd-wr01
title: UAH MIPS Time Lapse Camera Intraday Video Imagery. Version 1.0

description: This dataset contains 3-hour duration videos in .mp4 format taken with the UAH MIPS Time Lapse Camera during the Ontario Winter Lake-effect Systems (OWLeS) project from 12 December 2013 to 28 January 2014. The videos are tarred together by day. The camera was located at the Shineman Center on the SUNY-Oswego campus pointing northward over Lake Ontario.
DOI: 10.15468/dl.tpkk3s
title: Occurrence Download

description: A dataset containing 0 species occurrences available in GBIF matching the query:
{
 "and" : [
 "HasCoordinate is true",
 "ScientificName is Hyacinthus orientalis"
 ]
}

 The dataset includes 0 records from 0 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0041131-250920141307145/datasets/export for details.
DOI: 10.15468/dl.zhpy7d
title: Occurrence Download

description: A dataset containing 141631459 species occurrences available in GBIF matching the query:
{
 "and" : [
 "Country is Canada",
 "Geometry POLYGON((-90.70446 44.92114,-80.49989 40.00694,-59.81865 42.96201,-56.55319 48.82522,-55.87288 55.02169,-79.27535 59.29562,-92.88143 58.59376,-101.9975 57.58697,-103.76629 49.713,-90.70446 44.92114))",
 "HasCoordinate is true",
 "HasGeospatialIssue is false"
 ]
}

 The dataset includes 141631459 records from 1466 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0041157-250920141307145/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.6084/m9.figshare.26701372.v1
title: Additional file 6 of Race-specific coregulatory and transcriptomic profiles associated with DNA methylation and androgen receptor in prostate cancer

description: Additional File 6.
DOI: 10.6084/m9.figshare.26701414
title: Additional file 4 of Assessing the implementation fidelity, feasibility, and sustainability of community-based house improvement for malaria control in southern Malawi: a mixed-methods study

description: Supplementary Material 4
DOI: 10.6084/m9.figshare.26701414.v1
title: Additional file 4 of Assessing the implementation fidelity, feasibility, and sustainability of community-based house improvement for malaria control in southern Malawi: a mixed-methods study

description: Supplementary Material 4
DOI: 10.6084/m9.figshare.26701417
title: Additional file 5 of Assessing the implementation fidelity, feasibility, and sustainability of community-based house improvement for malaria control in southern Malawi: a mixed-methods study

description: Supplementary Material 5
DOI: 10.6084/m9.figshare.26701417.v1
title: Additional file 5 of Assessing the implementation fidelity, feasibility, and sustainability of community-based house improvement for malaria control in southern Malawi: a mixed-methods study

description: Supplementary Material 5
DOI: 10.6084/m9.figshare.25530452
title: Additional file 2 of Simultaneous targeted and discovery-driven clinical proteotyping using hybrid-PRM/DIA

description: Additional file 2: Table S1. List of biobanked melanoma patient samples monitored with hybrid-PRM/DIA and DIA. Table S2. Overview of jpt TAA peptide panel (heavy and light). Table S3. List of 30 AQUA peptides used as melanoma level-1/2 diagnostic markers. Table S4. PRM scheduling list of the 185 TAA peptides plus 11 retention time peptides. Table S5. Hybrid-PRM/DIA API input list for triggering of MSxPRM scans of the 185 TAA peptides. Table S6. Hybrid-PRM/DIA API input list for triggering of MSxPRM scans of the 179 TAA peptides. Table S7. Hybrid-PRM/DIA API input list for triggering of MSxPRM scans of the 120 TAA peptides. Table S8. Hybrid-PRM/DIA API input list for triggering of MSxPRM scans of the 60 TAA peptides. Table S9. Hybrid-PRM/DIA API input list for triggering of MSxPRM scans of the 30 melanoma AQUA peptides. Table S10. PRM scheduling list of the 30 melanoma AQUA peptides plus 11 iRT peptides. Table S11. List of the 65 level-1 and level-2 melanoma marker proteins/protein groups. Table S12. Quantitative protein matrix over 43 melanoma marker proteins in 95 patient samples. Values are log10-transformed and the basis of the heatmap in Fig. S4. The proteins discussed in Fig. 5B are indicated in red.
DOI: 10.6084/m9.figshare.25530452.v1
title: Additional file 2 of Simultaneous targeted and discovery-driven clinical proteotyping using hybrid-PRM/DIA

description: Additional file 2: Table S1. List of biobanked melanoma patient samples monitored with hybrid-PRM/DIA and DIA. Table S2. Overview of jpt TAA peptide panel (heavy and light). Table S3. List of 30 AQUA peptides used as melanoma level-1/2 diagnostic markers. Table S4. PRM scheduling list of the 185 TAA peptides plus 11 retention time peptides. Table S5. Hybrid-PRM/DIA API input list for triggering of MSxPRM scans of the 185 TAA peptides. Table S6. Hybrid-PRM/DIA API input list for triggering of MSxPRM scans of the 179 TAA peptides. Table S7. Hybrid-PRM/DIA API input list for triggering of MSxPRM scans of the 120 TAA peptides. Table S8. Hybrid-PRM/DIA API input list for triggering of MSxPRM scans of the 60 TAA peptides. Table S9. Hybrid-PRM/DIA API input list for triggering of MSxPRM scans of the 30 melanoma AQUA peptides. Table S10. PRM scheduling list of the 30 melanoma AQUA peptides plus 11 iRT peptides. Table S11. List of the 65 level-1 and level-2 melanoma marker proteins/protein groups. Table S12. Quantitative protein matrix over 43 melanoma marker proteins in 95 patient samples. Values are log10-transformed and the basis of the heatmap in Fig. S4. The proteins discussed in Fig. 5B are indicated in red.
DOI: 10.6084/m9.figshare.26701489
title: Additional file 3 of Updated reference values for static lung volumes from a healthy population in Austria

description: Additional file 3. LEAD Lookup tables lung volumes submitted
DOI: 10.6084/m9.figshare.26701489.v1
title: Additional file 3 of Updated reference values for static lung volumes from a healthy population in Austria

description: Additional file 3. LEAD Lookup tables lung volumes submitted
DOI: 10.15468/dl.p867uj
title: Occurrence Download

description: A dataset containing 155772 species occurrences available in GBIF matching the query:
{
 "TaxonKey" : [
 "is Glomeromycota"
 ]
}

 The dataset includes 155772 records from 330 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0072887-240626123714530/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.6084/m9.figshare.25538551
title: Additional file 1 of Mesothelin promotes brain metastasis of non-small cell lung cancer by activating MET

description: Supplementary Material 1.
DOI: 10.6084/m9.figshare.25538551.v1
title: Additional file 1 of Mesothelin promotes brain metastasis of non-small cell lung cancer by activating MET

description: Supplementary Material 1.
DOI: 10.6084/m9.figshare.25538497
title: Additional file 1 of Specific isoforms of the ubiquitin ligase gene WWP2 are targets of osteoarthritis genetic risk via a differentially methylated DNA sequence

description: Supplementary Material 1
DOI: 10.6084/m9.figshare.25538497.v1
title: Additional file 1 of Specific isoforms of the ubiquitin ligase gene WWP2 are targets of osteoarthritis genetic risk via a differentially methylated DNA sequence

description: Supplementary Material 1
DOI: 10.6084/m9.figshare.25538583
title: Additional file 2 of Specific isoforms of the ubiquitin ligase gene WWP2 are targets of osteoarthritis genetic risk via a differentially methylated DNA sequence

description: Supplementary Material 2
DOI: 10.6084/m9.figshare.25538583.v1
title: Additional file 2 of Specific isoforms of the ubiquitin ligase gene WWP2 are targets of osteoarthritis genetic risk via a differentially methylated DNA sequence

description: Supplementary Material 2
DOI: 10.6084/m9.figshare.26701501
title: Additional file 3 of Specific isoforms of the ubiquitin ligase gene WWP2 are targets of osteoarthritis genetic risk via a differentially methylated DNA sequence

description: Supplementary Material 3
DOI: 10.6084/m9.figshare.26701501.v1
title: Additional file 3 of Specific isoforms of the ubiquitin ligase gene WWP2 are targets of osteoarthritis genetic risk via a differentially methylated DNA sequence

description: Supplementary Material 3
DOI: 10.6084/m9.figshare.26701504
title: Additional file 4 of Specific isoforms of the ubiquitin ligase gene WWP2 are targets of osteoarthritis genetic risk via a differentially methylated DNA sequence

description: Supplementary Material 4
DOI: 10.6084/m9.figshare.26701504.v1
title: Additional file 4 of Specific isoforms of the ubiquitin ligase gene WWP2 are targets of osteoarthritis genetic risk via a differentially methylated DNA sequence

description: Supplementary Material 4
DOI: 10.6084/m9.figshare.26701507
title: Additional file 5 of Specific isoforms of the ubiquitin ligase gene WWP2 are targets of osteoarthritis genetic risk via a differentially methylated DNA sequence

description: Supplementary Material 5
DOI: 10.6084/m9.figshare.26701507.v1
title: Additional file 5 of Specific isoforms of the ubiquitin ligase gene WWP2 are targets of osteoarthritis genetic risk via a differentially methylated DNA sequence

description: Supplementary Material 5
DOI: 10.6084/m9.figshare.26701522
title: Additional file 9 of Specific isoforms of the ubiquitin ligase gene WWP2 are targets of osteoarthritis genetic risk via a differentially methylated DNA sequence

description: Supplementary Material 9
DOI: 10.6084/m9.figshare.26701522.v1
title: Additional file 9 of Specific isoforms of the ubiquitin ligase gene WWP2 are targets of osteoarthritis genetic risk via a differentially methylated DNA sequence

description: Supplementary Material 9
DOI: 10.6084/m9.figshare.26701525
title: Additional file 10 of Specific isoforms of the ubiquitin ligase gene WWP2 are targets of osteoarthritis genetic risk via a differentially methylated DNA sequence

description: Supplementary Material 10
DOI: 10.6084/m9.figshare.26701525.v1
title: Additional file 10 of Specific isoforms of the ubiquitin ligase gene WWP2 are targets of osteoarthritis genetic risk via a differentially methylated DNA sequence

description: Supplementary Material 10
DOI: 10.15468/dl.dkxqb8
title: Occurrence Download

description: A dataset containing 166 species occurrences available in GBIF matching the query:
{
 "and" : [
 "TaxonKey is Acacia cangaiensis Tindale & Kodela",
 "HasCoordinate is true"
 ]
}

 The dataset includes 166 records from 18 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0003866-240229165702484/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.st3drh
title: Occurrence Download

description: A dataset containing 241 species occurrences available in GBIF matching the query:
{
 "and" : [
 "HasCoordinate is true",
 "TaxonKey is Lycaon pictus (Temminck, 1820)",
 "HasGeospatialIssue is false"
 ]
}

 The dataset includes 241 records from 21 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0006471-171219132708484/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.sqsswk
title: Occurrence Download

description: A dataset containing 4 species occurrences available in GBIF matching the query:
{
 "and" : [
 "Country is Argentina",
 "TaxonKey is Lobivia silvestrii (Speg.) G.D.Rowley"
 ]
}

 The dataset includes 4 records from 2 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0098393-200613084148143/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.8j3an5
title: Occurrence Download

description: A dataset listing the 1957 species recorded in GBIF matching the query:
{
 "DatasetKey" : [
 "is WII Herbarium Dataset"
 ]
}

 The dataset's 1957 records were derived from 1 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0016985-190813142620410/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.u9djy4
title: Occurrence Download

description: A dataset containing 25 species occurrences available in GBIF matching the query:
{
 "and" : [
 "Country is China",
 "TaxonKey is Rhododendron erastum Balf.fil. & Forrest"
 ]
}

 The dataset includes 25 records from 6 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0010856-240229165702484/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.rcx7td
title: Occurrence Download

description: A dataset listing the 20 species recorded in GBIF matching the query:
{
 "and" : [
 "OccurrenceStatus is Present",
 "TaxonKey is Boa constrictor Linnaeus, 1758"
 ]
}

 The dataset's 20 records were derived from 202 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0089162-200613084148143/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.