DOI: 10.21954/ou.rd.22059263.v1
title: Assessing the volatile inventory and history of the Moon using lunar meteorites: Appendix B

description: This is a compilation of Cl and Ce isotope images of lunar brecciated samples (pristine and meteorite) used in my PhD thesis entitled ' Assessing the volatile inventory and history of the Moon using lunar meteorites'. <br> <strong>Project Level: </strong> Many <em>in situ</em> measurements of volatile elements (F, Cl, H, and S) have been collected on lunar samples. Whilst this has significantly broadened our understanding of the volatile inventories and evolution of the Moon, these studies have been focused mainly on crystalline samples from the lunar nearside which restricts our understanding of lunar geology, geochemistry, and volatiles of the regions sampled. Lunar meteorites may have been ejected from anywhere on the lunar surface, hence detailed analysis of a diverse set of lunar meteorites may expand our knowledge and challenge existing models of lunar evolution. A large proportion of lunar meteorites (and the Apollo samples) are brecciated, however. The processes which give rise to brecciation on the Moon may have led to the loss of geological context and key phases for the study of volatiles. This study primarily focuses on investigating volatiles (H, F, Cl) in apatite from five brecciated lunar meteorites to gain new insights into the history of volatiles in the Moon. This study primarily focuses on Cl and H, using the NanoSIMS 50L, Cl and H<sub>2</sub>O abundances and Cl and H isotopic compositions measured on 34 apatite grains. CeO2 abundances of apatite are used as a proxy for rare earth element contents, which are compared to Cl and H results to investigate correlations and to attempt to reconstruct parental melt H2O contents. Apatite Cl abundances range from ~ 10 to 36500 ppm and are associated with a δ<sup>37</sup>Cl range from – 1 to + 53 ‰. Apatite H<sub>2</sub>O abundances range from ~ 130 to 4500 ppm and are associated with a δD range from – 940 to + 1030 ‰. The higher δ<sup>37</sup>Cl values are associated with negative δD in some apatite grains located in highlands-type clasts as well as in isolated grains occurring within the matrix of these breccias. No obvious correlation between δD and δ<sup>37</sup>Cl is apparent, however. The heavier δ<sup>37</sup>Cl values appear to bridge the gap between existing data on Apollo and basaltic lunar meteorites and extreme δ<sup>37</sup>Cl values observed in one lunar meteorite, which supports greater heterogeneity of the lunar Cl record. Light H isotopes observed in some quartz monzodiorite clasts may indicate a significant solar wind/nebular input into the lunar precursor material and/or interaction with solar-wind derived H in the lunar regolith. <br> <strong>Data Level: </strong> Data was collected on a CAMECA NanoSIMS 50L at the Open University in isotope imaging mode. The species selected for analysis were: <sup>13</sup>C, <sup>1</sup><sup>8</sup>O, <sup>35</sup>Cl, <sup>37</sup>Cl, <sup>40</sup>Ca<sup>19</sup>F, and <sup>140</sup>Ce<sup>16</sup>O<sub>2</sub>. 100 frames were collected and these have been compressed into a single image using L'Image software (Larry Nittler, Carnegie Institute of Washington). Images for key species (<sup>37</sup>Cl, <sup>35</sup>Cl, and <sup>140</sup>Ce<sup>16</sup>O<sub>2</sub>) and ratio images (<sup>37</sup>Cl/<sup>35</sup>Cl, <sup>35</sup>Cl/<sup>18</sup>O, and <sup>140</sup>Ce<sup>16</sup>O<sub>2</sub>/<sup>18</sup>O) have been compiled in each slide of this appendix. This data is to support the Cl isotope discussion of my thesis. <br> <strong>Variable Level:</strong> Each slide has a title with the name format 'Sample Name, Apatite Name, Pit Name (Optional)' In the example 'DOM 18262 Ap1a', <em>DOM 18262</em> is the sample name, <em>Ap1</em> is the apatite name (to allow cross reference with result summarised in the thesis), and <em>a</em> is the pit name within Ap1 (where multiple NanoSIMS pits have been collected on one apatite). <br> <br>