cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.6084/m9.figshare.5669239.v1
title: Nitrogen Fertilization of No-Tillage Winter Cereals in the South-Central Region of Paraná, Brazil

description: ABSTRACT High winter cereal yields depend on an adequate supply of nitrogen (N). We developed a system for indicating N rates for wheat and barley in the South-Central region of the state of Paraná, Brazil, using results of 72 field experiments conducted from 2007 to 2012. The N rates recommended for winter cereals were estimated to supply the amounts of N fertilizer needed to obtain increasing yields (&lt;3.5, 3.5-4.5, 4.5-5.5, and &gt;5.5 Mg ha-1) of crops grown after soybean and corn on soils with a variable organic matter content (&lt;40, 40-60, and &gt;60 g dm-3). The apparent mineralization rate of soil N was estimated to be 1 % and the N fertilization efficiency 50 %. The N rates recommended for wheat ranged from 30 to 150 kg ha-1 when cultivated after soybean, and from 30 to 170 kg ha-1 after corn. The N rates for barley ranged from 30 to 120 kg ha-1 when grown after soybean, and from 30 to 130 kg ha-1 after corn. These N rates are consistent with those indicated by the Soil Fertility Commission for the states of Rio Grande do Sul and Santa Catarina (CQFS-RS/SC, 2016), and also with the rates of maximum economic efficiency estimated in our study. The proposed N rate recommendation system can be used by agricultural technicians and producers to manage N fertilization of wheat and barley in the South-Central region of Paraná, Brazil.
DOI: 10.6084/m9.figshare.5669236
title: Nutritional Efficiency of Eucalyptus Clones Under Water Stress

description: Abstract Plant health and nutrition are strongly influenced by the availability of water. The objective of this study was to evaluate the different patterns of initial growth and nutritional efficiency of ten drought-stressed Eucalyptus clones. Water stress conditions were induced by osmotic stress, by gradual addition of polyethylene glycol 6000 over a 20-day period. Drought stress significantly reduced the dry matter of leaves, roots, and the whole plant as well as the nutritional efficiency of most clones. Clone PL040 was the least efficient in nutrient uptake and use and the most sensitive to drought stress. Interestingly, under drought stress, the drought-tolerant clones generally had high AE (absorption efficiency), but low nutrient UE (use efficiency), whereas the sensitive clones had low AE and low UE for root formation and high AE for leaf formation. In a combined evaluation of growth and nutrient use efficiency, the clones vc865, i182, i144, and gg157 were grouped as drought-tolerant; 1528 and i224 as moderately tolerant; and 1641, 3367, i042, and PL040 as drought-sensitive.
DOI: 10.6084/m9.figshare.5669236.v1
title: Nutritional Efficiency of Eucalyptus Clones Under Water Stress

description: Abstract Plant health and nutrition are strongly influenced by the availability of water. The objective of this study was to evaluate the different patterns of initial growth and nutritional efficiency of ten drought-stressed Eucalyptus clones. Water stress conditions were induced by osmotic stress, by gradual addition of polyethylene glycol 6000 over a 20-day period. Drought stress significantly reduced the dry matter of leaves, roots, and the whole plant as well as the nutritional efficiency of most clones. Clone PL040 was the least efficient in nutrient uptake and use and the most sensitive to drought stress. Interestingly, under drought stress, the drought-tolerant clones generally had high AE (absorption efficiency), but low nutrient UE (use efficiency), whereas the sensitive clones had low AE and low UE for root formation and high AE for leaf formation. In a combined evaluation of growth and nutrient use efficiency, the clones vc865, i182, i144, and gg157 were grouped as drought-tolerant; 1528 and i224 as moderately tolerant; and 1641, 3367, i042, and PL040 as drought-sensitive.
DOI: 10.6084/m9.figshare.5669230
title: Urease Inhibitor and Irrigation Management to Mitigate Ammonia Volatilization from Urea in No-Till Corn

description: ABSTRACT High nitrogen (N) losses by ammonia (NH3) volatilization from urea can compromise nitrogen fertilization efficiency and corn yield. The purpose of this study was to assess the effects of irrigation management and the addition of the urease inhibitor N-(n-butyl)thiophosphoric triamide (NBPT) on NH3-N losses from urea and on corn yield. To this end, two experiments were carried out in the 2011/12 crop season on a sandy clay loam Acrisol in the Central Basin region of Rio Grande do Sul, southern Brazil. Experiment I consisted of two different N sources (urea and urea plus the inhibitor) at a rate of 200 kg ha-1 N and two corn sowing times [viz., an early time (Sept. 3, 2011) and an intermediate time (Oct. 3, 2011)]. Experiment II considered a combination of three irrigation management systems (viz., without irrigation on the fertilization day and on the next 7 days; 20 mm of water immediately before N fertilization; and 20 mm water after N fertilization) and two N sources (urea and urea plus the inhibitor) at 150 kg ha-1 N. A control treatment without topdressed N fertilization was also performed in parallel with the two experiments. The NH3-N losses from common urea increased with increasing soil moisture in Experiment I (25 % applied N), and with irrigation before N fertilization in Experiment II (27 % applied N). The inhibitor reduced NH3-N losses from urea by 46 to 80 %. Also, irrigation after fertilization reduced ammonia volatilization by 83 % on average, with little effect from the inhibitor. The effects of the inhibitor and post-fertilization irrigation on the mitigation of NH3 losses by volatilization from urea were not additive; in addition, they led to no increase in corn yield.
DOI: 10.6084/m9.figshare.5669230.v1
title: Urease Inhibitor and Irrigation Management to Mitigate Ammonia Volatilization from Urea in No-Till Corn

description: ABSTRACT High nitrogen (N) losses by ammonia (NH3) volatilization from urea can compromise nitrogen fertilization efficiency and corn yield. The purpose of this study was to assess the effects of irrigation management and the addition of the urease inhibitor N-(n-butyl)thiophosphoric triamide (NBPT) on NH3-N losses from urea and on corn yield. To this end, two experiments were carried out in the 2011/12 crop season on a sandy clay loam Acrisol in the Central Basin region of Rio Grande do Sul, southern Brazil. Experiment I consisted of two different N sources (urea and urea plus the inhibitor) at a rate of 200 kg ha-1 N and two corn sowing times [viz., an early time (Sept. 3, 2011) and an intermediate time (Oct. 3, 2011)]. Experiment II considered a combination of three irrigation management systems (viz., without irrigation on the fertilization day and on the next 7 days; 20 mm of water immediately before N fertilization; and 20 mm water after N fertilization) and two N sources (urea and urea plus the inhibitor) at 150 kg ha-1 N. A control treatment without topdressed N fertilization was also performed in parallel with the two experiments. The NH3-N losses from common urea increased with increasing soil moisture in Experiment I (25 % applied N), and with irrigation before N fertilization in Experiment II (27 % applied N). The inhibitor reduced NH3-N losses from urea by 46 to 80 %. Also, irrigation after fertilization reduced ammonia volatilization by 83 % on average, with little effect from the inhibitor. The effects of the inhibitor and post-fertilization irrigation on the mitigation of NH3 losses by volatilization from urea were not additive; in addition, they led to no increase in corn yield.
DOI: 10.6084/m9.figshare.5669227
title: Characterization of the Austenite Reformation Mechanisms as a Function of the Initial Ferritic State in a UNS S32304 Duplex Stainless Steel

description: Aiming to better understand the effects of heat treatment parameters on Ferrite-Austenite phase transformation in a 2304 duplex stainless steel different thermal cycles were applied to this steel in a quenching dilatometer. The obtained microstructures were characterized by optical microscopy, transmission electron microscopy and electron backscatter diffraction. It was noticed that the austenite formation mechanism is strongly dependent on initial ferritized state. If the initial structure is completely ferritized, the nitrogen supersaturated solid solution leads to chromium nitrides precipitation and the rate of austenite nucleation decreases. For higher cooling rates, the ferrite grain boundaries control the austenite nucleation rate. The higher the ferrite grain size, the lower the final austenite fraction. If the steel is cooled from a partial ferritized state, the ferrite-austenite phase boundaries work as austenite nucleation site and the austenite growth rate is favored due to the high interfacial energy and the austenitic structures becomes coarser.
DOI: 10.6084/m9.figshare.5669227.v1
title: Characterization of the Austenite Reformation Mechanisms as a Function of the Initial Ferritic State in a UNS S32304 Duplex Stainless Steel

description: Aiming to better understand the effects of heat treatment parameters on Ferrite-Austenite phase transformation in a 2304 duplex stainless steel different thermal cycles were applied to this steel in a quenching dilatometer. The obtained microstructures were characterized by optical microscopy, transmission electron microscopy and electron backscatter diffraction. It was noticed that the austenite formation mechanism is strongly dependent on initial ferritized state. If the initial structure is completely ferritized, the nitrogen supersaturated solid solution leads to chromium nitrides precipitation and the rate of austenite nucleation decreases. For higher cooling rates, the ferrite grain boundaries control the austenite nucleation rate. The higher the ferrite grain size, the lower the final austenite fraction. If the steel is cooled from a partial ferritized state, the ferrite-austenite phase boundaries work as austenite nucleation site and the austenite growth rate is favored due to the high interfacial energy and the austenitic structures becomes coarser.
DOI: 10.6084/m9.figshare.5669224
title: Effect of Heat Treatments and SiC Content in the Mechanical Properties and Microstructure of Self-Lubricating Steels

description: The objective of the present work was to study the effect of heat treatments in the microstructure, graphite nodules and mechanical properties of self-lubricating steels, to achieve this, self-lubricating steels (Fe + 0.45C + 4Ni + 1Mo %wt) and additions of 2 and 3 %wt SiC were fabricated. They were consequently heat treated in 3 different conditions: martempering at 180 °C and tempering at 530 °C and 300 °C respectively and austempering at 300 °C. Hardness, yield strength, tensile strength and work hardening behavior were studied in as-sintered and heat-treated samples. The microstructure was analyzed by optical microscopy, scanning electron microscopy, Raman spectroscopy and micro-hardness. The transformation temperatures were determined using dilatometric tests. Results show that the presence of dissolved Si in the matrix due to SiC dissociation notably affects the morphology of the microstructure and transformation temperatures also affecting post heat treatment mechanical properties. The structure of graphite nodules produced by SiC dissociation is nott significantly affected by the heat treatments.
DOI: 10.6084/m9.figshare.5669224.v1
title: Effect of Heat Treatments and SiC Content in the Mechanical Properties and Microstructure of Self-Lubricating Steels

description: The objective of the present work was to study the effect of heat treatments in the microstructure, graphite nodules and mechanical properties of self-lubricating steels, to achieve this, self-lubricating steels (Fe + 0.45C + 4Ni + 1Mo %wt) and additions of 2 and 3 %wt SiC were fabricated. They were consequently heat treated in 3 different conditions: martempering at 180 °C and tempering at 530 °C and 300 °C respectively and austempering at 300 °C. Hardness, yield strength, tensile strength and work hardening behavior were studied in as-sintered and heat-treated samples. The microstructure was analyzed by optical microscopy, scanning electron microscopy, Raman spectroscopy and micro-hardness. The transformation temperatures were determined using dilatometric tests. Results show that the presence of dissolved Si in the matrix due to SiC dissociation notably affects the morphology of the microstructure and transformation temperatures also affecting post heat treatment mechanical properties. The structure of graphite nodules produced by SiC dissociation is nott significantly affected by the heat treatments.
DOI: 10.6084/m9.figshare.5669221
title: Surface Characterization of NiTi Superelastic and Shape Memory Alloys After Electrolytic Polishing

description: For the biomedical application of NiTi alloys, an excellent surface finishing process is required to guarantee high corrosion resistance and biocompatibility, eliminating the allergenic and toxic effects associated with the release of nickel ions in the body. Electropolishing is a process that can reduce surface imperfections and form a thin protective layer of TiO2, even in complex-shaped devices. The main objective of our study was to find and report suitable parameters for electrolytic polishing of NiTi wires, in both the superelastic and shape memory states. The results indicate that electropolishing in a 3.5 mol•L-1 methanolic H2SO4 electrolyte at 20ºC can effectively reduce surface roughness, remove superficial nickel-rich layers and improve corrosion resistance for austenitic and martensitic NiTi alloys.
DOI: 10.6084/m9.figshare.5669221.v1
title: Surface Characterization of NiTi Superelastic and Shape Memory Alloys After Electrolytic Polishing

description: For the biomedical application of NiTi alloys, an excellent surface finishing process is required to guarantee high corrosion resistance and biocompatibility, eliminating the allergenic and toxic effects associated with the release of nickel ions in the body. Electropolishing is a process that can reduce surface imperfections and form a thin protective layer of TiO2, even in complex-shaped devices. The main objective of our study was to find and report suitable parameters for electrolytic polishing of NiTi wires, in both the superelastic and shape memory states. The results indicate that electropolishing in a 3.5 mol•L-1 methanolic H2SO4 electrolyte at 20ºC can effectively reduce surface roughness, remove superficial nickel-rich layers and improve corrosion resistance for austenitic and martensitic NiTi alloys.
DOI: 10.6084/m9.figshare.5669218
title: Proposal of a framework for product-service systems characterization

description: Abstract Product-service systems (PSS) design raises new issues, among which the need of encompassing a life cycle perspective. The aim of this paper is to propose a conceptual framework for PSS characterization through its life cycle. The purpose is to understand the structure, the sequence, and the main characteristics of PSS life cycle phases, characterizing a PSS process model. A systematic literature review was carried out to identify the PSS life cycle phases and the conceptual elements that characterize each phase. The PSS life cycle was structured based on service life cycle from the customer perspective. Afterwards, the conceptual framework was built for PSS characterization considering business model, engineering and design aspects that may be useful to guide PSS solutions development. The paper aims to make a theoretical contribution by understanding what should be done and how to perform the activities during PSS life cycle at a systemic level.
DOI: 10.6084/m9.figshare.5669218.v1
title: Proposal of a framework for product-service systems characterization

description: Abstract Product-service systems (PSS) design raises new issues, among which the need of encompassing a life cycle perspective. The aim of this paper is to propose a conceptual framework for PSS characterization through its life cycle. The purpose is to understand the structure, the sequence, and the main characteristics of PSS life cycle phases, characterizing a PSS process model. A systematic literature review was carried out to identify the PSS life cycle phases and the conceptual elements that characterize each phase. The PSS life cycle was structured based on service life cycle from the customer perspective. Afterwards, the conceptual framework was built for PSS characterization considering business model, engineering and design aspects that may be useful to guide PSS solutions development. The paper aims to make a theoretical contribution by understanding what should be done and how to perform the activities during PSS life cycle at a systemic level.
DOI: 10.6084/m9.figshare.5669215
title: Analyzing the competences of production engineering graduates: an industry perspective

description: Abstract This paper aims at conducting an analysis the competences of production engineering graduates, building on an industry view. To this end, we conducted a survey addressing 103 medium and large companies within the Brazilian manufacturing industry. The results suggest that companies do recognize the importance of competences. Some gaps in the competences of graduates were also pointed out by respondents. This study suggests the need for the development of efforts for providing the production engineer with a better professional background. The links between university and industry are likely to contribute towards such direction, notably as a starting point for institutions and industries to foster their student’s competences, aiming their aptitude for an ever-competitive job market, which values the flexible, creative being, who is capable of creating innovative solutions.
DOI: 10.6084/m9.figshare.5669215.v1
title: Analyzing the competences of production engineering graduates: an industry perspective

description: Abstract This paper aims at conducting an analysis the competences of production engineering graduates, building on an industry view. To this end, we conducted a survey addressing 103 medium and large companies within the Brazilian manufacturing industry. The results suggest that companies do recognize the importance of competences. Some gaps in the competences of graduates were also pointed out by respondents. This study suggests the need for the development of efforts for providing the production engineer with a better professional background. The links between university and industry are likely to contribute towards such direction, notably as a starting point for institutions and industries to foster their student’s competences, aiming their aptitude for an ever-competitive job market, which values the flexible, creative being, who is capable of creating innovative solutions.
DOI: 10.6084/m9.figshare.5669212
title: Selective Surfaces of Black Chromium for Use in Solar Absorbers

description: One of the applications of selective surfaces is to improve performance of solar absorbers. The purpose of this work is to produces selective coatings with high absorption of solar radiation in the range of UV/Vis/NIR. It was prepared a selective surface composed of black chromium (Cr/Cr2O3) deposited on substrates of AISI 304 stainless steel using the technique of electrolytic deposition for application in solar thermal absorbers. The great parameters for deposition consisted of a continuous electric current of 2A for 90s, at a constant temperature of 40°C. After deposition, the samples under went to a heat treatment at 600°C for 2h for oxidation. The coatings thicknesses were determined. From the SEM analysis coupled with EDS, it was found that the microstructures reported sample of cermets. The XRD results show diffraction peaks related to metallic chromium (Cr) and chromium oxide (Cr2O3). Spectral absorptance values more 90.0% were found.
DOI: 10.6084/m9.figshare.5669212.v1
title: Selective Surfaces of Black Chromium for Use in Solar Absorbers

description: One of the applications of selective surfaces is to improve performance of solar absorbers. The purpose of this work is to produces selective coatings with high absorption of solar radiation in the range of UV/Vis/NIR. It was prepared a selective surface composed of black chromium (Cr/Cr2O3) deposited on substrates of AISI 304 stainless steel using the technique of electrolytic deposition for application in solar thermal absorbers. The great parameters for deposition consisted of a continuous electric current of 2A for 90s, at a constant temperature of 40°C. After deposition, the samples under went to a heat treatment at 600°C for 2h for oxidation. The coatings thicknesses were determined. From the SEM analysis coupled with EDS, it was found that the microstructures reported sample of cermets. The XRD results show diffraction peaks related to metallic chromium (Cr) and chromium oxide (Cr2O3). Spectral absorptance values more 90.0% were found.
DOI: 10.6084/m9.figshare.5669209
title: Assessing the service quality in Software-as-a-Service from the customers’ perspective: a methodological approach and case of use

description: Abstract Despite the advances in the evaluation of the quality of Software-as-a-Service (SaaS), new studies seem to be necessary, since the existing criticisms concerning the SERVQUAL scale and the lack of studies concerning the use of SERVPERF for this purpose. This work aims to fulfil this gap by proposing a methodological approach to assess the SaaS service quality by measuring SaaS customers’ satisfaction. Factor analysis is used to summarize the information contained in the original items into a smaller set of new dimensions and Quartile analysis is suggested to determine the most critical items. By conducting a study, the factors that most influence customer’s satisfaction are customer service, customer assistance and the reliability of SaaS. Most of the critical items are associated with the transparency and accuracy in correcting errors, the company's interest in solving customer problems, SaaS application's ability to meet business requirements, implemented updates and regularity of service performance.
DOI: 10.6084/m9.figshare.5669209.v1
title: Assessing the service quality in Software-as-a-Service from the customers’ perspective: a methodological approach and case of use

description: Abstract Despite the advances in the evaluation of the quality of Software-as-a-Service (SaaS), new studies seem to be necessary, since the existing criticisms concerning the SERVQUAL scale and the lack of studies concerning the use of SERVPERF for this purpose. This work aims to fulfil this gap by proposing a methodological approach to assess the SaaS service quality by measuring SaaS customers’ satisfaction. Factor analysis is used to summarize the information contained in the original items into a smaller set of new dimensions and Quartile analysis is suggested to determine the most critical items. By conducting a study, the factors that most influence customer’s satisfaction are customer service, customer assistance and the reliability of SaaS. Most of the critical items are associated with the transparency and accuracy in correcting errors, the company's interest in solving customer problems, SaaS application's ability to meet business requirements, implemented updates and regularity of service performance.