cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.5281/zenodo.6407220
title: Dataset of the article 'Spectroelectrochemistry of water oxidation kinetics in molecular versus heterogeneous oxide iridium electrocatalysts'

description: Dataset of the article 'Spectroelectrochemistry of Water Oxidation Kinetics in Molecular versus Heterogeneous Oxide Iridium Electrocatalysts', https://doi.org/10.1021/jacs.2c02006. Abstract: Water oxidation is the step limiting the efficiency of electrocatalytic hydrogen production from water. Spectroelectrochemical analyzes are employed to make a direct comparison of water oxidation reaction kinetics between a molecular catalyst, the dimeric iridium catalyst [Ir<sub>2</sub>(pyalc)<sub>2</sub>(H<sub>2</sub>O)<sub>4</sub>-(µ-O)]<sup>2+</sup> (<strong>Ir<sub>Molecular</sub></strong>,<strong><sub> </sub></strong>pyalc = 2-(2’pyridinyl)-2-propanolate) immobilized on a mesoporous indium tin oxide (ITO) substrate, with that of an heterogenous electrocatalyst, an amorphous hydrous iridium (<strong>IrO<sub>x</sub></strong>) film. For both systems, four analogous redox states were detected, with the formation of Ir(4+)-Ir(5+) being the potential-determining step in both cases. However, the two systems exhibit distinct water oxidation reaction kinetics, with potential-independent first-order kinetics for <strong>Ir<sub>Molecular</sub></strong> contrasting with potential-dependent kinetics for <strong>IrO<sub>x</sub></strong>. This is attributed to water oxidation on the heterogenous catalyst requiring co-operative effects between neighboring oxidized Ir centers. The ability of <strong>Ir<sub>Molecular</sub></strong> to drive water oxidation without such co-operative effects is explained by the specific coordination environment around its Ir centers. These distinctions between molecular and heterogenous reaction kinetics are shown to explain the differences observed in their water oxidation electrocatalytic performance under different potential conditions.
DOI: 10.6084/m9.figshare.20182100
title: Buchmann_etal_ACC-3D-measurements-in-meter-per-second-squared.7z

description: Acceleration measured with 3D accelerometers at animals necks, breasts and hind legs. For details see Buchmann et. al 2022 (to be specified).
DOI: 10.6084/m9.figshare.20182100.v1
title: Buchmann_etal_ACC-3D-measurements-in-meter-per-second-squared.7z

description: Acceleration measured with 3D accelerometers at animals necks, breasts and hind legs. For details see Buchmann et. al 2022 (to be specified).
DOI: 10.48372/862241ea-4ea4-4dd0-849b-59f7ed1c8cc4
title: Macroinvertebrates data of the Italian mountain lakes from 1902 to 2016.

description: The dataset encompasses all geographic and historical data available on macroinvertebrates of the Italian mountain lakes from 1902 to 2016. The data set, divided per Italian mountain range (Alps and Apennines) and administrative region, covers more than a century of studies of many foreign and Italian scientists. The data set includes 2372 records and shows macroinvertebrate occurrence data in 176 Alpine and in 13 Apennine lakes, of which 178 of natural origin, 5 reservoirs, and 6 artificially extended. The data set lists 605 taxa, updated on the basis of their current taxonomic position. Only 353 taxa are identified at species level.
DOI: 10.5281/zenodo.5699436
title: Dataset of the article 'Redox state kinetics in water-oxidation IrOx electrocatalysts measured by operando spectroelectrochemistry'

description: Data published in the article 'Redox state kinetics in water-oxidation IrO<sub>x</sub> electrocatalysts measured by <em>operando</em> spectroelectrochemistry', https://doi.org/10.1021/acscatal.1c03290. Abstract: hydrous iridium oxides (IrO<sub>x</sub>) are the best oxygen evolution electrocatalysts available for operation in acidic environments. In this study, we employ time-resolved <em>operando</em> spectroelectrochemistry to investigate the redox states kinetics of IrO<sub>x</sub> electrocatalyst films for both water and hydrogen peroxide oxidation. Three different redox species involving Ir<sup>3+</sup>, Ir<sup>3.x+</sup>, Ir<sup>4+</sup> and Ir<sup>4.y+</sup> are identified spectroscopically and their concentrations are quantified as a function of applied potential. The generation of Ir<sup>4.y+</sup> states is found to be the potential determining step for catalytic water oxidation, whilst H<sub>2</sub>O<sub>2</sub> oxidation is observed to be driven by the generation of Ir<sup>4+</sup>states. The reaction kinetics for water oxidation, determined from the optical signal decays at open circuit, accelerate from ~ 20 s to &lt; 0.5 s with increasing applied potential above 1.3V <em>vs.</em> RHE (i.e. TOFs per active Ir state increasing from 0.05 to 2 s<sup>-1</sup>). In contrast, the reaction kinetics for H<sub>2</sub>O<sub>2</sub> are found to be almost independent of the applied potential (increasing from 0.1-0.3 s<sup>-1 </sup>over a wider potential window), indicative of a first order reaction mechanism. These spectroelectrochemical data quantify the increase of both the density of active Ir<sup>4.y+</sup> states and the TOFs of these states with applied positive potential, resulting in the observed sharp turn on of catalytic water oxidation current. We reconcile these data with the broader literature while providing a unique kinetic insight into IrO<sub>x</sub> electrocatalytic reaction mechanisms, indicating a first order reaction mechanism for H<sub>2</sub>O<sub>2</sub> oxidation driven by Ir<sup>4+</sup> states, and a higher order reaction mechanism involving the co-operative interaction of multiple Ir<sup>4.y+</sup> states for water oxidation.
DOI: 10.5281/zenodo.5699435
title: Dataset of the article 'Redox state kinetics in water-oxidation IrOx electrocatalysts measured by operando spectroelectrochemistry'

description: Data published in the article 'Redox state kinetics in water-oxidation IrO<sub>x</sub> electrocatalysts measured by <em>operando</em> spectroelectrochemistry', https://doi.org/10.1021/acscatal.1c03290. Abstract: hydrous iridium oxides (IrO<sub>x</sub>) are the best oxygen evolution electrocatalysts available for operation in acidic environments. In this study, we employ time-resolved <em>operando</em> spectroelectrochemistry to investigate the redox states kinetics of IrO<sub>x</sub> electrocatalyst films for both water and hydrogen peroxide oxidation. Three different redox species involving Ir<sup>3+</sup>, Ir<sup>3.x+</sup>, Ir<sup>4+</sup> and Ir<sup>4.y+</sup> are identified spectroscopically and their concentrations are quantified as a function of applied potential. The generation of Ir<sup>4.y+</sup> states is found to be the potential determining step for catalytic water oxidation, whilst H<sub>2</sub>O<sub>2</sub> oxidation is observed to be driven by the generation of Ir<sup>4+</sup>states. The reaction kinetics for water oxidation, determined from the optical signal decays at open circuit, accelerate from ~ 20 s to &lt; 0.5 s with increasing applied potential above 1.3V <em>vs.</em> RHE (i.e. TOFs per active Ir state increasing from 0.05 to 2 s<sup>-1</sup>). In contrast, the reaction kinetics for H<sub>2</sub>O<sub>2</sub> are found to be almost independent of the applied potential (increasing from 0.1-0.3 s<sup>-1 </sup>over a wider potential window), indicative of a first order reaction mechanism. These spectroelectrochemical data quantify the increase of both the density of active Ir<sup>4.y+</sup> states and the TOFs of these states with applied positive potential, resulting in the observed sharp turn on of catalytic water oxidation current. We reconcile these data with the broader literature while providing a unique kinetic insight into IrO<sub>x</sub> electrocatalytic reaction mechanisms, indicating a first order reaction mechanism for H<sub>2</sub>O<sub>2</sub> oxidation driven by Ir<sup>4+</sup> states, and a higher order reaction mechanism involving the co-operative interaction of multiple Ir<sup>4.y+</sup> states for water oxidation.
DOI: 10.34740/kaggle/dsv/3880134
title: Team Fight Tactics matches
DOI: 10.3886/e171721
title: US Cities' Permitting or Restriction of Housing Development

description: The data described here were used in the analysis and findings reported in<br>the article, Leon-Moreta, A, and Vittoria R. Totaro (2022). "US cities'<br>permitting or restriction of housing development." Cities 128. A STATA (V. 13)<br>do-file for calculating variables is also included. Please cite the corresponding<br>article if this dataset is used to support additional findings.<br><br>
description: <br>Cities in the United States.<br>.
DOI: 10.3886/e171721v1
title: US Cities' Permitting or Restriction of Housing Development

description: The data described here were used in the analysis and findings reported in<br>the article, Leon-Moreta, A, and Vittoria R. Totaro (2022). "US cities'<br>permitting or restriction of housing development." Cities 128. A STATA (V. 13)<br>do-file for calculating variables is also included. Please cite the corresponding<br>article if this dataset is used to support additional findings.<br><br>
description: <br>Cities in the United States.<br>.
DOI: 10.5281/zenodo.6779371
title: Effectiveness of interventions to support the transition home after acute stroke: systematic review and meta-analysis

description: Raw data used in systematic review
description: HRB Funded CDA-2019_004
DOI: 10.5281/zenodo.6779370
title: Effectiveness of interventions to support the transition home after acute stroke: systematic review and meta-analysis

description: Raw data used in systematic review
description: HRB Funded CDA-2019_004
DOI: 10.5281/zenodo.6543997
title: Training data for bathymetry estimation via EO satellite - Hel Peninsula

description: This dataset contains satellite image from Sentiel-2A (bands B2, B3, B4, B8) and reference sonar based bathymetry measurements. The reference data was acquired from Polish Maritime Administration (htttp://www.um.gdy.pl) and is publicly available. File reference_data_34.csv contains in-situ measrements aquired at northen shore of Hel Peninsula. Points coordinates are expressed in UTM34N coordinate system. The satellite and the reference datasets were preprocessed by the authors for adjust them for Machine Learning algorithms used in the research.
description: {"references": ["Andrzej Chybicki (2018) Three-Dimensional Geographically Weighted Inverse Regression (3GWR) Model for Satellite Derived Bathymetry Using Sentinel-2 Observations, Marine Geodesy, 41:1, 1-23, DOI: 10.1080/01490419.2017.1373173"]}
DOI: 10.5281/zenodo.6543996
title: Training data for bathymetry estimation via EO satellite - Hel Peninsula

description: This dataset contains satellite image from Sentiel-2A (bands B2, B3, B4, B8) and reference sonar based bathymetry measurements. The reference data was acquired from Polish Maritime Administration (htttp://www.um.gdy.pl) and is publicly available. File reference_data_34.csv contains in-situ measrements aquired at northen shore of Hel Peninsula. Points coordinates are expressed in UTM34N coordinate system. The satellite and the reference datasets were preprocessed by the authors for adjust them for Machine Learning algorithms used in the research.
description: {"references": ["Andrzej Chybicki (2018) Three-Dimensional Geographically Weighted Inverse Regression (3GWR) Model for Satellite Derived Bathymetry Using Sentinel-2 Observations, Marine Geodesy, 41:1, 1-23, DOI: 10.1080/01490419.2017.1373173"]}
DOI: 10.6084/m9.figshare.17857527
title: Radiation induced mutagenesis, physio-biochemical profiling and field evaluation of mutants in sugarcane cv. CoM 0265

description: Sugarcane is an important cash crop and is affected by soil salinity. CoM 0265, a moderately salt-tolerant variety grown in the Maharashtra region (India), has low sugar content. The present study was aimed to employ gamma ray induced in vitro mutagenesis with repeated and step-wise selection in sugarcane for the isolation and physio-biochemical profiling of the selected salt-tolerant mutants for improved agronomic performance and sugar content. Embryogenic callus culture of CoM 0265 variety was subjected to different doses of gamma radiation (10, 20, 30, 40, 50, and 60 Gy) followed by selection on NaCl containing media (50, 100, 150, 200, and 250 mM NaCl). The regenerated plantlets were hardened and selected based on ground nursery field trial on normal soil and saline field trial, in augmented block design for the selected mutant clones. Different physio-biochemical changes and activity of antioxidant enzymes were analyzed in the salt selected in vitro cultures and field-grown mutant clones. Dose optimization showed 40 Gy as the LD<sub>50</sub> for gamma radiation and 150 mM NaCl as the dose for in vitro selection experiments. The selected mutant clones showed higher tissue water content (TWC), chlorophyll, and lower sodium content indicative of tolerance to salt stress. Catalase and peroxidase enzyme activities in the top visible dewlap (TVD) of the putative mutant clones were significantly higher than the control. The average yield and sucrose percent of the selected mutant clones were significantly higher than control checks in the saline field trial. Mutant clones M8457 and M8721 exhibited improved yield and commercial cane sugar over the parent control check varieties under saline field conditions. Catalase activity was strongly associated with TWC (<i>r</i> = 0.34) and chlorophyll content (<i>r</i> = 0.41) while it was negatively correlated with sodium ion content (<i>r</i> = –0.38). Peroxidase activity in TVD also showed a significant positive correlation with chlorophyll content (<i>r</i> = 0.42) and a negative correlation with sodium ion content (<i>r</i>=–0.39). The improvement in yield and CCS (t/ha) was strongly associated with the lower sodium ion content of the mutant clones (<i>r</i>=–0.54 and −0.53, respectively). Gamma ray induced mutants were isolated for improved sucrose and high yield in sugarcane var. CoM 0265. The results suggest that gamma radiation induced mutations result in physiological and metabolomic alterations for better growth and adaptation under in vitro and field stress conditions in sugarcane. The improved mutants can be further useful for commercial cultivation in saline areas.
DOI: 10.6084/m9.figshare.17857527.v2
title: Radiation induced mutagenesis, physio-biochemical profiling and field evaluation of mutants in sugarcane cv. CoM 0265

description: Sugarcane is an important cash crop and is affected by soil salinity. CoM 0265, a moderately salt-tolerant variety grown in the Maharashtra region (India), has low sugar content. The present study was aimed to employ gamma ray induced in vitro mutagenesis with repeated and step-wise selection in sugarcane for the isolation and physio-biochemical profiling of the selected salt-tolerant mutants for improved agronomic performance and sugar content. Embryogenic callus culture of CoM 0265 variety was subjected to different doses of gamma radiation (10, 20, 30, 40, 50, and 60 Gy) followed by selection on NaCl containing media (50, 100, 150, 200, and 250 mM NaCl). The regenerated plantlets were hardened and selected based on ground nursery field trial on normal soil and saline field trial, in augmented block design for the selected mutant clones. Different physio-biochemical changes and activity of antioxidant enzymes were analyzed in the salt selected in vitro cultures and field-grown mutant clones. Dose optimization showed 40 Gy as the LD<sub>50</sub> for gamma radiation and 150 mM NaCl as the dose for in vitro selection experiments. The selected mutant clones showed higher tissue water content (TWC), chlorophyll, and lower sodium content indicative of tolerance to salt stress. Catalase and peroxidase enzyme activities in the top visible dewlap (TVD) of the putative mutant clones were significantly higher than the control. The average yield and sucrose percent of the selected mutant clones were significantly higher than control checks in the saline field trial. Mutant clones M8457 and M8721 exhibited improved yield and commercial cane sugar over the parent control check varieties under saline field conditions. Catalase activity was strongly associated with TWC (<i>r</i> = 0.34) and chlorophyll content (<i>r</i> = 0.41) while it was negatively correlated with sodium ion content (<i>r</i> = –0.38). Peroxidase activity in TVD also showed a significant positive correlation with chlorophyll content (<i>r</i> = 0.42) and a negative correlation with sodium ion content (<i>r</i>=–0.39). The improvement in yield and CCS (t/ha) was strongly associated with the lower sodium ion content of the mutant clones (<i>r</i>=–0.54 and −0.53, respectively). Gamma ray induced mutants were isolated for improved sucrose and high yield in sugarcane var. CoM 0265. The results suggest that gamma radiation induced mutations result in physiological and metabolomic alterations for better growth and adaptation under in vitro and field stress conditions in sugarcane. The improved mutants can be further useful for commercial cultivation in saline areas.
DOI: 10.5281/zenodo.5785817
title: Front polylines extracted from DWD Maps

description: Weather fronts extracted from surface analysis maps of the German Weather Service (Deutscher Wetterdienst, DWD) for the years 2015 to 2020 Fronts are described by an identifier (warm, cold, occ) followed by several [lat, lon] coordinate pairs in degree [North, East] Stationary-Fronts are extracted as either cold or warm fronts e.g. warm [75.69211706913667, 29.558180185836815] [75.12348547753966, 26.89164117647018] ... No guarantee is given regarding correctness or completeness of extracted fronts
description: {"references": ["Data basis: Deutscher Wetterdienst"]}
DOI: 10.5281/zenodo.5785816
title: Front polylines extracted from DWD Maps

description: Weather fronts extracted from surface analysis maps of the German Weather Service (Deutscher Wetterdienst, DWD) for the years 2015 to 2020 Fronts are described by an identifier (warm, cold, occ) followed by several [lat, lon] coordinate pairs in degree [North, East] Stationary-Fronts are extracted as either cold or warm fronts e.g. warm [75.69211706913667, 29.558180185836815] [75.12348547753966, 26.89164117647018] ... No guarantee is given regarding correctness or completeness of extracted fronts
description: {"references": ["Data basis: Deutscher Wetterdienst"]}
DOI: 10.5255/ukda-sn-855785
title: Prisoner death investigations: improving safety in prisons and societies, 2019-2020

description: This is qualitative data collection of semi-structured interviews conducted between December 2019-October 2020 within a study that examined how the Prisons and Probation Ombudsman (seek to) effect change in prisons following prisoner suicides and how death investigations could have more impact on prison policy and practice. The study ran from 2019-2021. Internationally, prisoner mortality rates are up to 50% above those in the community. Although prisoner deaths are frequent and have significant implications across a broad range of stakeholder groups, these harms are rarely acknowledged. We address this by examining how the PPO (seek to) effect change in prisons following prisoner suicides and how death investigations could have more impact on prison policy and practice from semi-structured interviews with multisectoral stakeholders. Within this project, 46 semi-structured interviews were undertaken with multisectoral stakeholders: 17 PPO staff (who work across England and Wales from a base in London), 8 prison Governing Governors (representing 8 prisons), 11 regional SCGLs (representing all but two regions nationally) and 9 Coroners (who represent 9 of the 92 separate coroners’ jurisdictions in England and Wales) and bereaved family members (n=1). These professional groups have received limited consideration in previous research despite International laws, e.g. Article 2 of the European Convention on Human Rights, requiring that all deaths in state detention are independently investigated. In England and Wales, prisoner deaths are externally investigated by at least the police, PPO and Coroner. These police, ombudsman and coroner investigations can be very disruptive and cause uncertainty and anxiety for all involved. The research demonstrates how the harms of prisoner deaths and investigations are broadly unacknowledged and radiate widely. We sought to stimulate both i) more substantive support for all those caught up in prison suicides and death investigations and ii) reconsideration of how prisoner deaths are investigated. For data storage and analysis purposes, the participants were divided into four categories: 1) Prison and Probation Ombudsman staff (PPO); 2) Governing Governors (Governors); 3) Safer Custody Group Leads (SCGLs); 4) Coroners (coroners); 5) bereaved family members (prisoner family). Because of the sensitivity of this research 3 SCGL transcripts have been omitted due to the participants still being identifiable following transcript anonymisation. Further information about the project and links to publications are available on the University of Nottingham SafeSoc project webpage https://www.safesoc.co.uk
DOI: 10.25921/a604-7a58
title: EK80 Water Column Sonar Data Collected During AT42-03-20181102-235041
DOI: 10.21985/n2-sd06-qn69
title: Structural spine plasticity: learning and forgetting of 1 odor-specific subnetworks in the olfactory bulb
DOI: 10.6084/m9.figshare.20182226
title: The new educational paradigm in COVID era: Can Blackboard replace physical teaching in EFL writing classrooms?

description: This study investigates the effectiveness of Blackboard in promoting EFL students’ writing performance in the Department of English Language and Translation at Qassim University. The data were collected for two periods: before (spring 2019) and after (spring 2020) the spread of COVID-19 virus. The study analyzed the students’ final grades in three different levels of writing courses. The results were collected and analyzed across the two different teaching approaches (face-to-face and Blackboard) to evaluate the two learning experiences and to highlight suggestions for enhancing students’ and teachers’ experience in online learning in the future. This study enlisted two groups of undergraduate male and female Saudi students who had applied for English language courses at Qassim University. Ethical approval was obtained (issued on, Sep. 25, 2020) from the deanship of scientific affairs to the head of the departments and the students. Students were also assured that their information would be only used for the study and that they were not required to disclose their identity in any way. Verbal consent of the participants was obtained because the ethics committee at the Qassim University approves verbal consent. Moreover, it is very difficult to get written consent from 833 participants. Still, as the study did not ask indulge the participants in interview, observation or questionnaire, it is enough to get permission from the University ethics committee. The consent letter states " This research meets the high ethical and scientific standards expected by society, and the participants have informed the Committee that they have no problem with the outcomes of the research work being published". The first group comprised students who took Writing 1, 2, and 3 prior to the pandemic, and the second group were those who took the same courses after the pandemic. The participants were assigned to take these three compulsory writing courses in the first three semesters after joining the program. The study sample thus included a total of 833 participants (287 males and 546 females). The students had prior experience with Blackboard as a learning tool. All freshman students, in traditional and pandemic times, are introduced to the most important features of Blackboard at the beginning of each semester. Additionally, three general courses were taught completely online during the first semester after students’ full enrolment in the program. <br>