cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.17188/1199556
title: Materials Data on Sr2InI5 by Materials Project

description: Sr2I5In crystallizes in the tetragonal I4/mcm space group. The structure is two-dimensional and consists of four indium molecules and two Sr2I5 sheets oriented in the (0, 0, 1) direction. In each Sr2I5 sheet, Sr2+ is bonded in a 8-coordinate geometry to eight I1- atoms. There are a spread of Sr–I bond distances ranging from 3.29–3.53 Å. There are two inequivalent I1- sites. In the first I1- site, I1- is bonded in a square co-planar geometry to four equivalent Sr2+ atoms. In the second I1- site, I1- is bonded in a 3-coordinate geometry to three equivalent Sr2+ atoms.
DOI: 10.17188/1199557
title: Materials Data on K2TeBr6 by Materials Project

description: K2TeBr6 crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. K1+ is bonded to twelve equivalent Br1- atoms to form KBr12 cuboctahedra that share corners with twelve equivalent KBr12 cuboctahedra, faces with six equivalent KBr12 cuboctahedra, and faces with four equivalent TeBr6 octahedra. All K–Br bond lengths are 3.87 Å. Te4+ is bonded to six equivalent Br1- atoms to form TeBr6 octahedra that share faces with eight equivalent KBr12 cuboctahedra. All Te–Br bond lengths are 2.73 Å. Br1- is bonded in a distorted single-bond geometry to four equivalent K1+ and one Te4+ atom.
DOI: 10.17188/1199558
title: Materials Data on InSn2Br5 by Materials Project

description: InSn2Br5 crystallizes in the tetragonal I4/mcm space group. The structure is two-dimensional and consists of four indium molecules and two Sn2Br5 sheets oriented in the (0, 0, 1) direction. In each Sn2Br5 sheet, Sn2+ is bonded in a 4-coordinate geometry to four Br1- atoms. There are two shorter (2.80 Å) and two longer (3.11 Å) Sn–Br bond lengths. There are two inequivalent Br1- sites. In the first Br1- site, Br1- is bonded in a square co-planar geometry to four equivalent Sn2+ atoms. In the second Br1- site, Br1- is bonded in a single-bond geometry to one Sn2+ atom.
DOI: 10.17188/1199559
title: Materials Data on Rb2CuCl4 by Materials Project

description: Rb2CuCl4 is (La,Ba)CuO4-like structured and crystallizes in the orthorhombic Cmce space group. The structure is three-dimensional. Rb1+ is bonded in a 9-coordinate geometry to nine Cl1- atoms. There are a spread of Rb–Cl bond distances ranging from 3.34–3.60 Å. Cu2+ is bonded to six Cl1- atoms to form corner-sharing CuCl6 octahedra. The corner-sharing octahedral tilt angles are 0°. There are a spread of Cu–Cl bond distances ranging from 2.30–2.79 Å. There are two inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded to five equivalent Rb1+ and one Cu2+ atom to form distorted ClRb5Cu octahedra that share corners with seventeen ClRb5Cu octahedra, edges with eight equivalent ClRb5Cu octahedra, and faces with four equivalent ClRb4Cu2 octahedra. The corner-sharing octahedra tilt angles range from 0–59°. In the second Cl1- site, Cl1- is bonded to four equivalent Rb1+ and two equivalent Cu2+ atoms to form distorted ClRb4Cu2 octahedra that share corners with fourteen ClRb5Cu octahedra, edges with two equivalent ClRb4Cu2 octahedra, and faces with eight ClRb5Cu octahedra. The corner-sharing octahedra tilt angles range from 0–59°.
DOI: 10.17188/1199560
title: Materials Data on TmPt3 by Materials Project

description: TmPt3 is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Tm is bonded to twelve equivalent Pt atoms to form a mixture of corner and face-sharing TmPt12 cuboctahedra. All Tm–Pt bond lengths are 2.89 Å. Pt is bonded in a distorted square co-planar geometry to four equivalent Tm atoms.
DOI: 10.17188/1199561
title: Materials Data on K2PtCl6 by Materials Project

description: K2PtCl6 crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. K1+ is bonded to twelve equivalent Cl1- atoms to form KCl12 cuboctahedra that share corners with twelve equivalent KCl12 cuboctahedra, faces with six equivalent KCl12 cuboctahedra, and faces with four equivalent PtCl6 octahedra. All K–Cl bond lengths are 3.54 Å. Pt4+ is bonded to six equivalent Cl1- atoms to form PtCl6 octahedra that share faces with eight equivalent KCl12 cuboctahedra. All Pt–Cl bond lengths are 2.35 Å. Cl1- is bonded in a distorted single-bond geometry to four equivalent K1+ and one Pt4+ atom.
DOI: 10.17188/1199562
title: Materials Data on BiSI by Materials Project

description: BiSI crystallizes in the orthorhombic Pnma space group. The structure is one-dimensional and consists of two BiSI ribbons oriented in the (1, 0, 0) direction. Bi3+ is bonded to three equivalent S2- and two equivalent I1- atoms to form distorted edge-sharing BiS3I2 square pyramids. There are one shorter (2.61 Å) and two longer (2.78 Å) Bi–S bond lengths. Both Bi–I bond lengths are 3.22 Å. S2- is bonded in a 3-coordinate geometry to three equivalent Bi3+ atoms. I1- is bonded in a distorted L-shaped geometry to two equivalent Bi3+ atoms.
DOI: 10.17188/1199564
title: Materials Data on Cu2Cl2O by Materials Project

description: Cu2OCl2 crystallizes in the orthorhombic Fddd space group. The structure is three-dimensional. Cu2+ is bonded in a square co-planar geometry to two equivalent O2- and two equivalent Cl1- atoms. Both Cu–O bond lengths are 1.99 Å. Both Cu–Cl bond lengths are 2.24 Å. O2- is bonded to four equivalent Cu2+ atoms to form corner-sharing OCu4 tetrahedra. Cl1- is bonded in an L-shaped geometry to two equivalent Cu2+ atoms.
DOI: 10.17188/1199565
title: Materials Data on RbPbI3 by Materials Project

description: RbPbI3 crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Rb1+ is bonded in a 9-coordinate geometry to nine I1- atoms. There are a spread of Rb–I bond distances ranging from 3.90–4.30 Å. Pb2+ is bonded to six I1- atoms to form edge-sharing PbI6 octahedra. There are a spread of Pb–I bond distances ranging from 3.12–3.41 Å. There are three inequivalent I1- sites. In the first I1- site, I1- is bonded in a 5-coordinate geometry to two equivalent Rb1+ and three equivalent Pb2+ atoms. In the second I1- site, I1- is bonded to four equivalent Rb1+ and one Pb2+ atom to form a mixture of distorted edge and corner-sharing IRb4Pb square pyramids. In the third I1- site, I1- is bonded in a 5-coordinate geometry to three equivalent Rb1+ and two equivalent Pb2+ atoms.
DOI: 10.17188/1199566
title: Materials Data on Ga4Bi2O9 by Materials Project

description: Bi2Ga4O9 crystallizes in the orthorhombic Pbam space group. The structure is three-dimensional. there are two inequivalent Ga3+ sites. In the first Ga3+ site, Ga3+ is bonded to four O2- atoms to form GaO4 tetrahedra that share corners with four equivalent GaO6 octahedra and a cornercorner with one GaO4 tetrahedra. The corner-sharing octahedra tilt angles range from 50–60°. There are a spread of Ga–O bond distances ranging from 1.82–1.89 Å. In the second Ga3+ site, Ga3+ is bonded to six O2- atoms to form GaO6 octahedra that share corners with four equivalent GaO4 tetrahedra and edges with two equivalent GaO6 octahedra. There are two shorter (1.96 Å) and four longer (2.04 Å) Ga–O bond lengths. Bi3+ is bonded in a 4-coordinate geometry to six O2- atoms. There are a spread of Bi–O bond distances ranging from 2.17–3.01 Å. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a linear geometry to two equivalent Ga3+ atoms. In the second O2- site, O2- is bonded in a 3-coordinate geometry to two Ga3+ and two equivalent Bi3+ atoms. In the third O2- site, O2- is bonded in a distorted trigonal planar geometry to three Ga3+ atoms. In the fourth O2- site, O2- is bonded in a 4-coordinate geometry to two equivalent Ga3+ and two equivalent Bi3+ atoms.
DOI: 10.17188/1199567
title: Materials Data on Na2O by Materials Project

description: Na2O is Fluorite structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Na1+ is bonded to four equivalent O2- atoms to form a mixture of edge and corner-sharing NaO4 tetrahedra. All Na–O bond lengths are 2.42 Å. O2- is bonded in a body-centered cubic geometry to eight equivalent Na1+ atoms.
DOI: 10.17188/1199568
title: Materials Data on InPb2I5 by Materials Project

description: InPb2I5 crystallizes in the tetragonal I4/mcm space group. The structure is two-dimensional and consists of four indium molecules and two Pb2I5 sheets oriented in the (0, 0, 1) direction. In each Pb2I5 sheet, Pb2+ is bonded in a 8-coordinate geometry to eight I1- atoms. There are a spread of Pb–I bond distances ranging from 3.16–3.61 Å. There are two inequivalent I1- sites. In the first I1- site, I1- is bonded in a square co-planar geometry to four equivalent Pb2+ atoms. In the second I1- site, I1- is bonded in a 3-coordinate geometry to three equivalent Pb2+ atoms.
DOI: 10.17188/1199569
title: Materials Data on Rb2CrCl4 by Materials Project

description: Rb2CrCl4 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Rb1+ is bonded in a distorted body-centered cubic geometry to eight equivalent Cl1- atoms. There are four shorter (3.14 Å) and four longer (3.50 Å) Rb–Cl bond lengths. Cr2+ is bonded in a body-centered cubic geometry to eight equivalent Cl1- atoms. All Cr–Cl bond lengths are 2.95 Å. Cl1- is bonded in a 4-coordinate geometry to four equivalent Rb1+ and two equivalent Cr2+ atoms.
DOI: 10.17188/1199570
title: Materials Data on BaZnCl4 by Materials Project

description: BaZnCl4 is Zircon-like structured and crystallizes in the orthorhombic Pbcn space group. The structure is three-dimensional. Ba2+ is bonded in a 8-coordinate geometry to eight Cl1- atoms. There are a spread of Ba–Cl bond distances ranging from 3.21–3.25 Å. Zn2+ is bonded in a tetrahedral geometry to four Cl1- atoms. There are two shorter (2.29 Å) and two longer (2.31 Å) Zn–Cl bond lengths. There are two inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a 1-coordinate geometry to two equivalent Ba2+ and one Zn2+ atom. In the second Cl1- site, Cl1- is bonded in a distorted trigonal planar geometry to two equivalent Ba2+ and one Zn2+ atom.
DOI: 10.17188/1199571
title: Materials Data on KClO4 by Materials Project

description: KClO4 crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. K is bonded in a 10-coordinate geometry to ten O atoms. There are a spread of K–O bond distances ranging from 2.92–3.21 Å. There are three inequivalent O sites. In the first O site, O is bonded in a distorted single-bond geometry to one K and one Cl atom. The O–Cl bond length is 1.45 Å. In the second O site, O is bonded to three equivalent K and one Cl atom to form a mixture of distorted edge and corner-sharing OK3Cl tetrahedra. The O–Cl bond length is 1.47 Å. In the third O site, O is bonded in a distorted single-bond geometry to three equivalent K and one Cl atom. The O–Cl bond length is 1.46 Å. Cl is bonded in a tetrahedral geometry to four O atoms.
DOI: 10.17188/1199572
title: Materials Data on K2OsCl6 by Materials Project

description: K2OsCl6 crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. K1+ is bonded to twelve equivalent Cl1- atoms to form KCl12 cuboctahedra that share corners with twelve equivalent KCl12 cuboctahedra, faces with six equivalent KCl12 cuboctahedra, and faces with four equivalent OsCl6 octahedra. All K–Cl bond lengths are 3.53 Å. Os4+ is bonded to six equivalent Cl1- atoms to form OsCl6 octahedra that share faces with eight equivalent KCl12 cuboctahedra. All Os–Cl bond lengths are 2.35 Å. Cl1- is bonded in a distorted single-bond geometry to four equivalent K1+ and one Os4+ atom.
DOI: 10.17188/1199573
title: Materials Data on KSn2I5 by Materials Project

description: KSn2I5 crystallizes in the tetragonal I4/mcm space group. The structure is three-dimensional. K1+ is bonded in a 10-coordinate geometry to ten I1- atoms. There are eight shorter (3.86 Å) and two longer (4.01 Å) K–I bond lengths. Sn2+ is bonded in a 4-coordinate geometry to four I1- atoms. There are two shorter (3.01 Å) and two longer (3.32 Å) Sn–I bond lengths. There are two inequivalent I1- sites. In the first I1- site, I1- is bonded to two equivalent K1+ and four equivalent Sn2+ atoms to form corner-sharing IK2Sn4 octahedra. The corner-sharing octahedra tilt angles range from 0–32°. In the second I1- site, I1- is bonded in a distorted trigonal non-coplanar geometry to two equivalent K1+ and one Sn2+ atom.
DOI: 10.17188/1199574
title: Materials Data on K2ZnBr4 by Materials Project

description: K2ZnBr4 crystallizes in the monoclinic P2_1 space group. The structure is three-dimensional. there are two inequivalent K1+ sites. In the first K1+ site, K1+ is bonded in a 7-coordinate geometry to seven Br1- atoms. There are a spread of K–Br bond distances ranging from 3.41–3.80 Å. In the second K1+ site, K1+ is bonded in a 7-coordinate geometry to seven Br1- atoms. There are a spread of K–Br bond distances ranging from 3.32–3.86 Å. Zn2+ is bonded in a tetrahedral geometry to four Br1- atoms. There are a spread of Zn–Br bond distances ranging from 2.43–2.45 Å. There are four inequivalent Br1- sites. In the first Br1- site, Br1- is bonded in a 4-coordinate geometry to three K1+ and one Zn2+ atom. In the second Br1- site, Br1- is bonded in a 4-coordinate geometry to three K1+ and one Zn2+ atom. In the third Br1- site, Br1- is bonded in a 5-coordinate geometry to four K1+ and one Zn2+ atom. In the fourth Br1- site, Br1- is bonded to four K1+ and one Zn2+ atom to form distorted corner-sharing BrK4Zn square pyramids.
DOI: 10.17188/1199575
title: Materials Data on SbI3Cl8 by Materials Project

description: Sb(ICl4)2I is alpha Niobium phosphide-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one hydriodic acid molecule and one Sb(ICl4)2 cluster. In the Sb(ICl4)2 cluster, Sb5+ is bonded in an octahedral geometry to six Cl1- atoms. There are a spread of Sb–Cl bond distances ranging from 2.38–2.51 Å. I1+ is bonded in a linear geometry to two Cl1- atoms. There are one shorter (2.39 Å) and one longer (2.82 Å) I–Cl bond lengths. There are four inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one Sb5+ atom. In the second Cl1- site, Cl1- is bonded in a single-bond geometry to one I1+ atom. In the third Cl1- site, Cl1- is bonded in a distorted bent 120 degrees geometry to one Sb5+ and one I1+ atom. In the fourth Cl1- site, Cl1- is bonded in a single-bond geometry to one Sb5+ atom.
DOI: 10.17188/1199576
title: Materials Data on KFeCl3 by Materials Project

description: KFeCl3 crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. K1+ is bonded in a 8-coordinate geometry to eight Cl1- atoms. There are a spread of K–Cl bond distances ranging from 3.23–3.38 Å. Fe2+ is bonded to six Cl1- atoms to form edge-sharing FeCl6 octahedra. There are a spread of Fe–Cl bond distances ranging from 2.35–2.61 Å. There are three inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a 4-coordinate geometry to one K1+ and three equivalent Fe2+ atoms. In the second Cl1- site, Cl1- is bonded in a 5-coordinate geometry to three equivalent K1+ and two equivalent Fe2+ atoms. In the third Cl1- site, Cl1- is bonded in a 1-coordinate geometry to four equivalent K1+ and one Fe2+ atom.
DOI: 10.17188/1199577
title: Materials Data on KSn2Cl5 by Materials Project

description: KSn2Cl5 crystallizes in the tetragonal I4/mcm space group. The structure is three-dimensional. K1+ is bonded in a 10-coordinate geometry to ten Cl1- atoms. There are eight shorter (3.45 Å) and two longer (3.60 Å) K–Cl bond lengths. Sn2+ is bonded in a 4-coordinate geometry to four Cl1- atoms. There are two shorter (2.61 Å) and two longer (2.99 Å) Sn–Cl bond lengths. There are two inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded to two equivalent K1+ and four equivalent Sn2+ atoms to form distorted corner-sharing ClK2Sn4 octahedra. The corner-sharing octahedra tilt angles range from 0–34°. In the second Cl1- site, Cl1- is bonded in a distorted trigonal non-coplanar geometry to two equivalent K1+ and one Sn2+ atom.
DOI: 10.17188/1199578
title: Materials Data on Ti3Hg by Materials Project

description: HgTi3 crystallizes in the cubic Pm-3n space group. The structure is three-dimensional. Ti is bonded in a 6-coordinate geometry to two equivalent Ti and four equivalent Hg atoms. Both Ti–Ti bond lengths are 2.60 Å. All Ti–Hg bond lengths are 2.91 Å. Hg is bonded to twelve equivalent Ti atoms to form a mixture of face and edge-sharing HgTi12 cuboctahedra.
DOI: 10.17188/1199579
title: Materials Data on KSn2Br5 by Materials Project

description: KSn2Br5 crystallizes in the tetragonal I4/mcm space group. The structure is three-dimensional. K1+ is bonded in a 10-coordinate geometry to ten Br1- atoms. There are eight shorter (3.62 Å) and two longer (3.76 Å) K–Br bond lengths. Sn2+ is bonded in a 4-coordinate geometry to four Br1- atoms. There are two shorter (2.78 Å) and two longer (3.12 Å) Sn–Br bond lengths. There are two inequivalent Br1- sites. In the first Br1- site, Br1- is bonded to two equivalent K1+ and four equivalent Sn2+ atoms to form corner-sharing BrK2Sn4 octahedra. The corner-sharing octahedra tilt angles range from 0–33°. In the second Br1- site, Br1- is bonded in a distorted trigonal non-coplanar geometry to two equivalent K1+ and one Sn2+ atom.
DOI: 10.17188/1199580
title: Materials Data on Hg5(BrO2)2 by Materials Project

description: Hg5(O2Br)2 crystallizes in the orthorhombic Ibam space group. The structure is three-dimensional. there are three inequivalent Hg2+ sites. In the first Hg2+ site, Hg2+ is bonded in a distorted linear geometry to two equivalent O2- and four equivalent Br1- atoms. Both Hg–O bond lengths are 2.13 Å. There are a spread of Hg–Br bond distances ranging from 3.06–3.25 Å. In the second Hg2+ site, Hg2+ is bonded in a 2-coordinate geometry to four equivalent O2- and two equivalent Br1- atoms. There are two shorter (2.09 Å) and two longer (2.82 Å) Hg–O bond lengths. Both Hg–Br bond lengths are 3.39 Å. In the third Hg2+ site, Hg2+ is bonded in a 4-coordinate geometry to four equivalent O2- atoms. All Hg–O bond lengths are 2.34 Å. O2- is bonded to four Hg2+ atoms to form a mixture of distorted edge and corner-sharing OHg4 tetrahedra. Br1- is bonded in a 6-coordinate geometry to six Hg2+ atoms.
DOI: 10.17188/1199582
title: Materials Data on Na2UI6 by Materials Project

description: Na2UI6 is trigonal omega-derived structured and crystallizes in the trigonal R-3 space group. The structure is two-dimensional and consists of three Na2UI6 sheets oriented in the (0, 0, 1) direction. Na1+ is bonded to six equivalent I1- atoms to form NaI6 octahedra that share edges with three equivalent NaI6 octahedra and edges with three equivalent UI6 octahedra. There are three shorter (3.26 Å) and three longer (3.27 Å) Na–I bond lengths. U4+ is bonded to six equivalent I1- atoms to form UI6 octahedra that share edges with six equivalent NaI6 octahedra. All U–I bond lengths are 3.03 Å. I1- is bonded in a distorted T-shaped geometry to two equivalent Na1+ and one U4+ atom.
DOI: 10.17188/1199583
title: Materials Data on Ba7(ClF6)2 by Materials Project

description: Ba7F12Cl2 crystallizes in the hexagonal P-6 space group. The structure is three-dimensional. there are three inequivalent Ba2+ sites. In the first Ba2+ site, Ba2+ is bonded in a 9-coordinate geometry to two equivalent Cl1- and seven F1- atoms. Both Ba–Cl bond lengths are 3.41 Å. There are a spread of Ba–F bond distances ranging from 2.66–2.80 Å. In the second Ba2+ site, Ba2+ is bonded in a 9-coordinate geometry to two equivalent Cl1- and seven F1- atoms. Both Ba–Cl bond lengths are 3.36 Å. There are a spread of Ba–F bond distances ranging from 2.63–3.04 Å. In the third Ba2+ site, Ba2+ is bonded in a 9-coordinate geometry to nine F1- atoms. There are three shorter (2.59 Å) and six longer (2.92 Å) Ba–F bond lengths. There are two inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded to six equivalent Ba2+ and six equivalent F1- atoms to form distorted ClBa6F6 cuboctahedra that share corners with six equivalent FBa5 square pyramids, corners with twelve FBa4 tetrahedra, edges with three equivalent FBa5 square pyramids, edges with nine FBa4 tetrahedra, and faces with two equivalent ClBa6F6 cuboctahedra. All Cl–F bond lengths are 3.47 Å. In the second Cl1- site, Cl1- is bonded in a 12-coordinate geometry to six equivalent Ba2+ atoms. There are four inequivalent F1- sites. In the first F1- site, F1- is bonded to four Ba2+ atoms to form FBa4 tetrahedra that share corners with two equivalent ClBa6F6 cuboctahedra, corners with four equivalent FBa5 square pyramids, corners with ten FBa4 tetrahedra, an edgeedge with one ClBa6F6 cuboctahedra, an edgeedge with one FBa5 square pyramid, and edges with four FBa4Cl2 tetrahedra. In the second F1- site, F1- is bonded to five Ba2+ atoms to form distorted FBa5 square pyramids that share corners with two equivalent ClBa6F6 cuboctahedra, corners with four equivalent FBa5 square pyramids, corners with eight FBa4 tetrahedra, an edgeedge with one ClBa6F6 cuboctahedra, edges with four equivalent FBa5 square pyramids, and edges with seven FBa4 tetrahedra. In the third F1- site, F1- is bonded to four Ba2+ and two equivalent Cl1- atoms to form FBa4Cl2 tetrahedra that share corners with two equivalent FBa5 square pyramids, corners with twelve FBa4 tetrahedra, edges with two equivalent ClBa6F6 cuboctahedra, edges with two equivalent FBa5 square pyramids, edges with five FBa4 tetrahedra, and faces with two equivalent FBa4Cl2 tetrahedra. In the fourth F1- site, F1- is bonded to four Ba2+ atoms to form FBa4 tetrahedra that share corners with two equivalent ClBa6F6 cuboctahedra, corners with two equivalent FBa5 square pyramids, corners with ten FBa4 tetrahedra, edges with four equivalent FBa5 square pyramids, and edges with three FBa4 tetrahedra.
DOI: 10.17188/1199584
title: Materials Data on AgBiO3 by Materials Project

description: AgBiO3 is Ilmenite structured and crystallizes in the trigonal R-3 space group. The structure is three-dimensional. Ag1+ is bonded in a 6-coordinate geometry to six equivalent O2- atoms. There are three shorter (2.35 Å) and three longer (2.68 Å) Ag–O bond lengths. Bi5+ is bonded to six equivalent O2- atoms to form edge-sharing BiO6 octahedra. There are three shorter (2.17 Å) and three longer (2.21 Å) Bi–O bond lengths. O2- is bonded in a distorted see-saw-like geometry to two equivalent Ag1+ and two equivalent Bi5+ atoms.