cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.6084/m9.figshare.20097469.v1
title: Sustainable and Reusable Sulfonic Acid-Functionalized Task-Specific Ionic Liquid Catalysts for Multicomponent Reactions. A Review

description: Improvements in Sustainable Organic Synthesis are usually related to the investigation of less hazardous, non-corrosive and renewable materials, as well as waste prevention, energy efficiency, solvent-free reactions, and the development of efficient reusable catalysts. In this context, multicomponent reactions emerged as important strategies for the rapid and more sustainable synthesis of organic molecules. In addition, the use of task-specific ionic liquids as non-conventional solvents and/or catalysts in multicomponent reactions has recently received great attention, contributing to the development of greener synthetic methodologies. This review describes the studies on the use of structurally diverse homogeneous and heterogeneous sulfonic acid-functionalized task-specific ionic liquids as acidic catalysts for multicomponent reactions applied to the synthesis of nitrogen- and oxygen-based heterocycles, as well as related compounds. The combination of the green credentials of multicomponent reactions and acidic ionic liquids are able to improve process sustainability and green metrics, contributing to sustainable chemical development and, ultimately, to economic growth and cleaner industrial production.
DOI: 10.6084/m9.figshare.20097469
title: Sustainable and Reusable Sulfonic Acid-Functionalized Task-Specific Ionic Liquid Catalysts for Multicomponent Reactions. A Review

description: Improvements in Sustainable Organic Synthesis are usually related to the investigation of less hazardous, non-corrosive and renewable materials, as well as waste prevention, energy efficiency, solvent-free reactions, and the development of efficient reusable catalysts. In this context, multicomponent reactions emerged as important strategies for the rapid and more sustainable synthesis of organic molecules. In addition, the use of task-specific ionic liquids as non-conventional solvents and/or catalysts in multicomponent reactions has recently received great attention, contributing to the development of greener synthetic methodologies. This review describes the studies on the use of structurally diverse homogeneous and heterogeneous sulfonic acid-functionalized task-specific ionic liquids as acidic catalysts for multicomponent reactions applied to the synthesis of nitrogen- and oxygen-based heterocycles, as well as related compounds. The combination of the green credentials of multicomponent reactions and acidic ionic liquids are able to improve process sustainability and green metrics, contributing to sustainable chemical development and, ultimately, to economic growth and cleaner industrial production.
DOI: 10.6084/m9.figshare.20097472
title: Educational practices and students’ ability to differentiate between native and exotic species in schools in Southern Brazil

description: Abstract Rising urbanisation and destruction of biomes have alienated humans from native species in their regions, demanding consideration of local ecosystems. The present study aimed to analyse the knowledge of students from public schools located in southern Brazil about native and exotic species, biomes, and biodiversity, and the difficulties that they attributed to these definitions. Research activities included lecture-discussion, fieldwork, and questionnaires, and data were analysed with Chi-Square, Fisher’s Exact Test, Binomial Test, Spearman’s Correlation and Content Analysis, employing a Mixed Method Research design. Middle School students showed lack of conceptual knowledge and attributed greater levels of difficulty to the concepts in comparison with High School students, while native species and the concept of biodiversity were better defined than exotic species and biomes. Moreover, students associated the concepts of ‘native’ and ‘exotic’ to ‘known/common’ and 'unknown/rare/strange', respectively.
DOI: 10.6084/m9.figshare.20097472.v1
title: Educational practices and students’ ability to differentiate between native and exotic species in schools in Southern Brazil

description: Abstract Rising urbanisation and destruction of biomes have alienated humans from native species in their regions, demanding consideration of local ecosystems. The present study aimed to analyse the knowledge of students from public schools located in southern Brazil about native and exotic species, biomes, and biodiversity, and the difficulties that they attributed to these definitions. Research activities included lecture-discussion, fieldwork, and questionnaires, and data were analysed with Chi-Square, Fisher’s Exact Test, Binomial Test, Spearman’s Correlation and Content Analysis, employing a Mixed Method Research design. Middle School students showed lack of conceptual knowledge and attributed greater levels of difficulty to the concepts in comparison with High School students, while native species and the concept of biodiversity were better defined than exotic species and biomes. Moreover, students associated the concepts of ‘native’ and ‘exotic’ to ‘known/common’ and 'unknown/rare/strange', respectively.
DOI: 10.6084/m9.figshare.20097473
title: Simultaneous ocular and osseous syphilis: a case report

description: ABSTRACT Syphilis is a reemerging and potentially serious disease. Owing to its ubiquity and pleomorphism, it is called “the great imitator”. We report the case of a young woman with secondary syphilis who presented with bilateral acute syphilitic posterior placoid chorioretinopathy along with a syphilitic skull periostitis. A pachymeningeal enhancement was observed on magnetic resonance imaging, but we believe it was an extension of the bone process rather than a meningitis itself on the basis of the normal cerebrospinal fluid analysis results. Treatment with intravenous crystalline penicillin resulted in complete resolution of the signs, symptoms, and imaging findings. Secondary syphilis is the stage with the highest bacteremia and the highest transmissibility, presenting mainly with mucocutaneous disorders and, less frequently, with involvement of other organs. High suspicion and a pragmatic approach are essential to the diagnosis because this disease can affect several organs, as in the present case, in which the eyes, bones, and skin were affected.
DOI: 10.6084/m9.figshare.20097473.v1
title: Simultaneous ocular and osseous syphilis: a case report

description: ABSTRACT Syphilis is a reemerging and potentially serious disease. Owing to its ubiquity and pleomorphism, it is called “the great imitator”. We report the case of a young woman with secondary syphilis who presented with bilateral acute syphilitic posterior placoid chorioretinopathy along with a syphilitic skull periostitis. A pachymeningeal enhancement was observed on magnetic resonance imaging, but we believe it was an extension of the bone process rather than a meningitis itself on the basis of the normal cerebrospinal fluid analysis results. Treatment with intravenous crystalline penicillin resulted in complete resolution of the signs, symptoms, and imaging findings. Secondary syphilis is the stage with the highest bacteremia and the highest transmissibility, presenting mainly with mucocutaneous disorders and, less frequently, with involvement of other organs. High suspicion and a pragmatic approach are essential to the diagnosis because this disease can affect several organs, as in the present case, in which the eyes, bones, and skin were affected.
DOI: 10.6084/m9.figshare.20097476
title: Screening Questionnaire for Early Signs of Autism Spectrum Disorder: evidence of validity and internal consistency

description: ABSTRACT Objective Assess the evidence of validity and the internal consistency of the Questionnaire for Screening Early Signs of Autism Spectrum Disorder (QR-TEA). Methods Four healthcare professionals with more than five years of clinical experience in treating children diagnosed with ASD analyzed the content. A sample of 133 parents/guardians of children aged 24-36 months from all over Brazil participated in the internal structure and internal consistency study. Participants answered the questionnaire through interviews with healthcare professionals. An exploratory factor analysis technique verified the factor structure. Additionally, to assess the instrument’s internal consistency, the composite reliability was calculated. Results i-IVC = 1.00 was found for most items; Kappa between 0.51 and 0.94; p &lt; 0.05; CCI = 0.90; p &lt; 0.05. Exploratory factor analysis pointed to a two-factor solution for QR-TEA. Composite reliability was adequate (above 0.70) for both factors. The factor structure replicability measure suggested that the two factors are replicable in future studies (H &gt; 0.80). Conclusions The data indicate initial evidence of validity and adequate internal consistency. The findings also support the psychometric adequacy of the QR-TEA in line with the DSM-5 two-factor model. It is recommended to conduct further studies to assess other evidence of validity and to verify the sensibility and specificity.
DOI: 10.6084/m9.figshare.20097476.v1
title: Screening Questionnaire for Early Signs of Autism Spectrum Disorder: evidence of validity and internal consistency

description: ABSTRACT Objective Assess the evidence of validity and the internal consistency of the Questionnaire for Screening Early Signs of Autism Spectrum Disorder (QR-TEA). Methods Four healthcare professionals with more than five years of clinical experience in treating children diagnosed with ASD analyzed the content. A sample of 133 parents/guardians of children aged 24-36 months from all over Brazil participated in the internal structure and internal consistency study. Participants answered the questionnaire through interviews with healthcare professionals. An exploratory factor analysis technique verified the factor structure. Additionally, to assess the instrument’s internal consistency, the composite reliability was calculated. Results i-IVC = 1.00 was found for most items; Kappa between 0.51 and 0.94; p &lt; 0.05; CCI = 0.90; p &lt; 0.05. Exploratory factor analysis pointed to a two-factor solution for QR-TEA. Composite reliability was adequate (above 0.70) for both factors. The factor structure replicability measure suggested that the two factors are replicable in future studies (H &gt; 0.80). Conclusions The data indicate initial evidence of validity and adequate internal consistency. The findings also support the psychometric adequacy of the QR-TEA in line with the DSM-5 two-factor model. It is recommended to conduct further studies to assess other evidence of validity and to verify the sensibility and specificity.
DOI: 10.6084/m9.figshare.20097478
title: Estimation of cropland prices in Rio Grande do Sul by multiple linear regression and principal component analysis

description: ABSTRACT: This study aimed to price croplands in Rio Grande do Sul State (southern Brazil) and point which variables had the most significant impact on prices. The main purpose was achieved using multiple linear regression and principal component analysis. The variables used in this study were planted area, production, price, and yield of the commodities soybean, wheat, and corn. The period under analysis was from January 1994 to December 2017 (biannual observations). Multiple linear regression showed that five variables contributed to land pricing, being three related to soybean and two to wheat. Multivariate analysis grouped the investigated variables into clusters and indicated their influence, in addition to providing information on land prices and reducing variable dimensionality from fourteen original variables to three principal components to be analyzed. The two analyses complemented each other so that the croplands’ price was explained by three variables, in which two corroborated in constructing the pricing model for croplands.
DOI: 10.6084/m9.figshare.20097478.v1
title: Estimation of cropland prices in Rio Grande do Sul by multiple linear regression and principal component analysis

description: ABSTRACT: This study aimed to price croplands in Rio Grande do Sul State (southern Brazil) and point which variables had the most significant impact on prices. The main purpose was achieved using multiple linear regression and principal component analysis. The variables used in this study were planted area, production, price, and yield of the commodities soybean, wheat, and corn. The period under analysis was from January 1994 to December 2017 (biannual observations). Multiple linear regression showed that five variables contributed to land pricing, being three related to soybean and two to wheat. Multivariate analysis grouped the investigated variables into clusters and indicated their influence, in addition to providing information on land prices and reducing variable dimensionality from fourteen original variables to three principal components to be analyzed. The two analyses complemented each other so that the croplands’ price was explained by three variables, in which two corroborated in constructing the pricing model for croplands.
DOI: 10.6084/m9.figshare.20097479
title: Continuity of care from the hospital: interdisciplinarity and devices for integrality in health care networks

description: ABSTRACT The aim of this study is to analyze the scientific production on the continuity and comprehensiveness of care, identifying devices used for this construction starting from the hospital. This research is an integrative review carried out in June and July 2021. Thus, PubMed/Medline, Lilacs, BDENF, and Lis databases were used for the selection of articles. Thirty-six articles were analyzed. Three categories emerged from the analysis: Health care and comprehensiveness within the hospital; The linkage and connections in the continuity of care; Health care networks in the Unified Health System and continuity of care. The analysis allowed identifying strategies/tools on the organization of work in the micropolitical dimension of health care production. The main devices found were: safe discharge, bed races, clinic management, case discussion, care lines, liaison nurses, regulatory complexes, continuing education, and multidisciplinarity. It was concluded that, although some studies are related to a practice in the still fragmented health care network, the mentioned devices constitute advances towards a model of care based on lines of care within and outside the hospital seeking articulation with the health care network.
DOI: 10.6084/m9.figshare.20097479.v1
title: Continuity of care from the hospital: interdisciplinarity and devices for integrality in health care networks

description: ABSTRACT The aim of this study is to analyze the scientific production on the continuity and comprehensiveness of care, identifying devices used for this construction starting from the hospital. This research is an integrative review carried out in June and July 2021. Thus, PubMed/Medline, Lilacs, BDENF, and Lis databases were used for the selection of articles. Thirty-six articles were analyzed. Three categories emerged from the analysis: Health care and comprehensiveness within the hospital; The linkage and connections in the continuity of care; Health care networks in the Unified Health System and continuity of care. The analysis allowed identifying strategies/tools on the organization of work in the micropolitical dimension of health care production. The main devices found were: safe discharge, bed races, clinic management, case discussion, care lines, liaison nurses, regulatory complexes, continuing education, and multidisciplinarity. It was concluded that, although some studies are related to a practice in the still fragmented health care network, the mentioned devices constitute advances towards a model of care based on lines of care within and outside the hospital seeking articulation with the health care network.
DOI: 10.6084/m9.figshare.20097481
title: Cross-cultural adaptation and validity of the Questionnaire on Sexual Quality of Life – Female (SQoL-F) in Brazil

description: ABSTRACT Objective The quality of sexual life encompasses sexual satisfaction and with partnership, the expression of sexual desires and values, good body image, in addition to physical, behavioral, psychological and emotional issues that affect sexuality. There are no reliable and valid instruments to assess the quality of sexual life of Brazilian women, so this study sought to translate the Questionnaire on Sexual Quality of Life – Female (SQoL-F) and present evidence of validity of the instrument in the Brazilian context. Methods The translation, content validity evaluation, pre-final version test and exploratory factor analysis were performed. Results The presence of a single factor was identified that explained 49% of the variance, consistent with what was proposed in the original questionnaire. This one-factor model presented adequate factor loadings (between 0.36 and 0.85). Conclusion The questionnaire had good internal consistency and presented satisfactory evidence of validity for use with Brazilian women.
DOI: 10.6084/m9.figshare.20097481.v1
title: Cross-cultural adaptation and validity of the Questionnaire on Sexual Quality of Life – Female (SQoL-F) in Brazil

description: ABSTRACT Objective The quality of sexual life encompasses sexual satisfaction and with partnership, the expression of sexual desires and values, good body image, in addition to physical, behavioral, psychological and emotional issues that affect sexuality. There are no reliable and valid instruments to assess the quality of sexual life of Brazilian women, so this study sought to translate the Questionnaire on Sexual Quality of Life – Female (SQoL-F) and present evidence of validity of the instrument in the Brazilian context. Methods The translation, content validity evaluation, pre-final version test and exploratory factor analysis were performed. Results The presence of a single factor was identified that explained 49% of the variance, consistent with what was proposed in the original questionnaire. This one-factor model presented adequate factor loadings (between 0.36 and 0.85). Conclusion The questionnaire had good internal consistency and presented satisfactory evidence of validity for use with Brazilian women.
DOI: 10.6084/m9.figshare.20097485.v1
title: Spatial mapping of annual rainfall in the São Francisco River Basin

description: Abstract Precipitation is an important object of study and plays an important role in the dynamics of rainfall distribution in a region. This study investigated the spatial and temporal variation of precipitation in the São Francisco River Basin (SFRB). A historical series of data from 1989 to 2018 was analyzed, and a random function was decomposed into trend and residual components for analysis of precipitation. Interpolation techniques were used to analyze precipitation spatial behavior over time, using high-resolution precipitation maps. Our results showed that the exponential model prevailed in four periods. The findings also showed a high precipitation variability in the SFRB and enabled us to monitor precipitation behavior over the years, as well as in the different sub-regions in SFRB. Finally, important information was obtained, enabling, for instance, the identification of vulnerable areas suffering from lack of rainfall.
DOI: 10.6084/m9.figshare.20097485
title: Spatial mapping of annual rainfall in the São Francisco River Basin

description: Abstract Precipitation is an important object of study and plays an important role in the dynamics of rainfall distribution in a region. This study investigated the spatial and temporal variation of precipitation in the São Francisco River Basin (SFRB). A historical series of data from 1989 to 2018 was analyzed, and a random function was decomposed into trend and residual components for analysis of precipitation. Interpolation techniques were used to analyze precipitation spatial behavior over time, using high-resolution precipitation maps. Our results showed that the exponential model prevailed in four periods. The findings also showed a high precipitation variability in the SFRB and enabled us to monitor precipitation behavior over the years, as well as in the different sub-regions in SFRB. Finally, important information was obtained, enabling, for instance, the identification of vulnerable areas suffering from lack of rainfall.
DOI: 10.6084/m9.figshare.19899677
title: Concordance between regenerating plants, ants and other arthropods in the Atlantic Forest: the importance of tree identity in the canopy

description: ABSTRACT Monitoring restoration practices is an expensive process, but essential to verifying their success. One way to reduce sampling costs is using biodiversity indicators, a term used for a functional or taxonomic group that is in agreement with another group. The objective of this work was to evaluate the agreement between the richness and composition of regenerating plants, ants and other arthropods under the canopy of four tree species in a restoration area in the Atlantic Forest, Brazil, as well as to determine the relationship of biological communities with parameters environmental and spatial. It was found that environmental variables, often linked to the tree's identity, are preponderant in determining the relationship between ants, other arthropods and regenerating plants. In addition, ants proved to be weak indicators of regenerating plants and other arthropods diversity and composition and this relationship was not guided by environmental and spatial variables. Thus, the results found here recommend caution when using ants as indicators of plant biodiversity and other arthropods in monitoring programs in the Atlantic Forest.
DOI: 10.6084/m9.figshare.19899677.v1
title: Concordance between regenerating plants, ants and other arthropods in the Atlantic Forest: the importance of tree identity in the canopy

description: ABSTRACT Monitoring restoration practices is an expensive process, but essential to verifying their success. One way to reduce sampling costs is using biodiversity indicators, a term used for a functional or taxonomic group that is in agreement with another group. The objective of this work was to evaluate the agreement between the richness and composition of regenerating plants, ants and other arthropods under the canopy of four tree species in a restoration area in the Atlantic Forest, Brazil, as well as to determine the relationship of biological communities with parameters environmental and spatial. It was found that environmental variables, often linked to the tree's identity, are preponderant in determining the relationship between ants, other arthropods and regenerating plants. In addition, ants proved to be weak indicators of regenerating plants and other arthropods diversity and composition and this relationship was not guided by environmental and spatial variables. Thus, the results found here recommend caution when using ants as indicators of plant biodiversity and other arthropods in monitoring programs in the Atlantic Forest.