cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.15151/esrf-es-779303812
title: Structure and self-organization of conducting polymers in ultrathin films

description: The proposed experiment aims to study Langmuir monolayers based on three poly(3-alkyl thiophene) bearing different end-groups on the lateral chains. The objective is to investigate the out of plane structure of these films spread at the air-water interface by means of XRR. In parallel, the surface concentration of monomers will be assessed using X-ray fluorescence. Correlation between chemical structure and organization at the air-water interface could thus be achieved in ultrathin films of conducting polymers.
DOI: 10.15151/esrf-es-778014448
title: Growth and structure of Fe Doped tetragonal CuO/STO(001)

description: Magnetic semiconducting thin films with high coercive field and remanence at room temperature are of primary importance for spintronic applications. We plan to realize such films by doping with iron a tetragonal CuO layer grown in epitaxy on SrTiO3(001). A key feature to obtain the desired properties is the Fe substitution of Cu in the CuO tetragonal structure. This configuration should result in a large magnetic superexchange interaction. We will use in situ non-resonant and resonant x-ray diffraction (RXD) to study the films structure. RXD, measured at the Fe K edge, allows to quantify the occupancy rate of the two cations on a same crystallographic site. At the same time GIXRD will allow to exclude the presence of spurious phases.
DOI: 10.15151/esrf-es-778016223
title: Scanning and In-situ MLL Development for X-ray Nanodiffraction on Thin Film, Space and Additively Manufactured Applications
DOI: 10.15151/esrf-es-779304727
title: Pressure evolution of superconducting kagome metals AV3Sb5 (A = K, Rb, Cs)

description: The material realization of kagome metals attracted a lot of attention in recent years. The peculiar kagome geometry along with the itinerant carriers cause linearly dispersing bands of Dirac fermions and flat bands. Contrary to the magnetic counterparts dominated by flat-band ferromagnetsm, the AV3Sb5 compounds (A=K, Rb, Cs) were shown to display a charge-density-wave instability as well as superconductivity at ambient pressure. These simple ternary compounds are the first practical candidates for correlated kagome metals where unconventional superconductivity has been predicted theoretically nearly a decade ago. Here, we propose a systematic high-pressure XRD study of AV3Sb5 in order to trace the structural changes and establish their links to the observed properties. We aim to reveal the important structural parameters that stabilize the different CDW and SC states in a non-magnetic kagome metal.
DOI: 10.15151/esrf-es-778020129
title: Valence-to-core XES studies on Cu-SSZ-13 for NOx removal by selective catalytic reduction with NH3 in the presence of HCHO

description: The objectives of this study are: (i) investigate the local environment of Cu atoms in Cu-SSZ-13 during SCR of NOx with NH3 in the presence of HCHO and (ii) find out the structural peculiarities of Cu species contributing to lower HCN emissions.
DOI: 10.15151/esrf-es-778020396
title: lattice dynamics in P-doped BaNi2As2

description: Signatures of nematic fluctuations have now been observed in various families of superconductors (SC) and have triggered intense investigations on the role of nematicity in the pairing mechanism. Recently, superconducting BaNi2(As,P)2 has received significant attention as a candidate system for charge-driven electronic nematicity. In this tetragonal system, a unidirectional charge density wave (CDW) order sets in before a structural transition to a triclinic phase occurs. We have recently performed a combined diffuse scattering (DS) and inelastic x-ray scattering (IXS) study in BaNi2(As,P)2, in which we have identified the soft phonon responsible for the formation of the IC-CDW. Here we propose to complete our study by extending our measurements to higher P-doping levels, for which the triclinic transition is fully supressed, and the superconducting Tc is strongly increased.
DOI: 10.15151/esrf-es-778027846
title: Polarimetric Resonant Inelastic X-ray Scattering of a newly discovered mode in a cuprate high-temeprature superconductor.

description: Resonant Inelastic X-ray Scattering (RIXS) has been a premier tool in the study of cuprate high-temperature superconductors. Spectrometers with increasing energy resolution near the Cu-L3 edge have been able to detect and study several states and excitations below 1eV energy-loss, including magnon, and paramagnon excitations, and static charge order and its dynamic excitations. With the advent of energy resolution better than 35 meV at the Cu L3-edge, it has been possible to study the bond stretching phonon mode at ~70meV and its coupling to the electronic charge order. We recently performed Cu L3 RIXS on a cuprate superconductor and discovered a never before reported mode with sub 1eV energy. There are many possibilities for its origin, including charge, magnetic or lattice excitations. We propose to investigate the physical origin of this mode by leveraging the unique capability of ERIXS to resolve the polarization of the scattered photon.
DOI: 10.15151/esrf-es-776857239
title: Next-generation DFXM
DOI: 10.14278/rodare.1643
title: Three-dimensional, km-scale hyperspectral data of a well-exposed Zn-Pb mineral exploration target at Black Angel Mountain, Greenland

description: Hyperspectral imaging is a most promising innovative technology for non-invasive material mapping and is starting to be adapted in a wide range of applications, including geosciences, ag-riculture, and food quality control. Novel processing workflows have revolutionized the way we can correct, interpret, and integrate hyperspectral data in the past decade. The reprojection of planar hyperspectral scans to real 3D point cloud representations (“hyperclouds”) has opened up new possibilities for the mapping of large and topographically complex targets. So far, only a few tools have been developed to process and visualize this kind of data. In this contribution we pre-sent an open-source hypercloud dataset capturing complex but spectacularly well exposed geolo-gy from the Black Angel Mountain in Maarmorilik, West Greenland, alongside a detailed and interactive tutorial documenting the workflow that was used to create it.
DOI: 10.6084/m9.figshare.19368918.v1
title: Synthesis of spiro chromanone sandwiched 15,16,18 membered <i>(Z)</i>-dioxo cycloalkenes by ring closing metathesis and homodimers of 8-allyl-7-((6-bromoalkyl) oxy) spirochroman-4-ones by cross metathesis

description: Novel spiro chromanone sandwiched 15,16,18 membered (<i>Z</i>)-1,7-dioxo cycloalkenes by Ring Closing Metathesis (RCM) and homodimers of 8-allyl-7-((6-bromo alkyl)oxy) spirochroman-4-ones by Cross Metathesis (CM) were synthesized from simple starting materials 2,4 dihydroxy acetophenone, allyl bromide, and dibromo alkanes. Spiro chromanone is chosen as the core moiety to be incorporated owing to its medicinal and pharmacophoric properties. The concept of molecular hybridization was adopted for the synthesis of compounds <b>18–26</b> using Ring Closing Metathesis as a key step. Intermediates <b>6,7,8</b> were alkylated with dibromo alkanes to obtain the substrates for RCM and CM, respectively. The dimer dienes <b>9–17</b> were made to undergo RCM and the bromo alkyl intermediates <b>27–34</b> were made to undergo CM to get homodimers <b>35–42</b>.
DOI: 10.6084/m9.figshare.19368918
title: Synthesis of spiro chromanone sandwiched 15,16,18 membered <i>(Z)</i>-dioxo cycloalkenes by ring closing metathesis and homodimers of 8-allyl-7-((6-bromoalkyl) oxy) spirochroman-4-ones by cross metathesis

description: Novel spiro chromanone sandwiched 15,16,18 membered (<i>Z</i>)-1,7-dioxo cycloalkenes by Ring Closing Metathesis (RCM) and homodimers of 8-allyl-7-((6-bromo alkyl)oxy) spirochroman-4-ones by Cross Metathesis (CM) were synthesized from simple starting materials 2,4 dihydroxy acetophenone, allyl bromide, and dibromo alkanes. Spiro chromanone is chosen as the core moiety to be incorporated owing to its medicinal and pharmacophoric properties. The concept of molecular hybridization was adopted for the synthesis of compounds <b>18–26</b> using Ring Closing Metathesis as a key step. Intermediates <b>6,7,8</b> were alkylated with dibromo alkanes to obtain the substrates for RCM and CM, respectively. The dimer dienes <b>9–17</b> were made to undergo RCM and the bromo alkyl intermediates <b>27–34</b> were made to undergo CM to get homodimers <b>35–42</b>.
DOI: 10.6084/m9.figshare.19346169
title: Synthesis of 5-arylidene-3-(pyridin-4-yl)-2-thio-imidazolidinone derivatives with the end of flexible chain modified with aryl groups under microwave

description: A series of 2-thio-imidazolidinone derivatives with aryl group modifications at the end of the five-carbon side chain were synthesized. Compared with conventional heating, the target compounds were obtained in higher yield (77–95%) and shorter reaction time under the assistance of microwave heating 100 °C over 2 h.
DOI: 10.6084/m9.figshare.19346169.v1
title: Synthesis of 5-arylidene-3-(pyridin-4-yl)-2-thio-imidazolidinone derivatives with the end of flexible chain modified with aryl groups under microwave

description: A series of 2-thio-imidazolidinone derivatives with aryl group modifications at the end of the five-carbon side chain were synthesized. Compared with conventional heating, the target compounds were obtained in higher yield (77–95%) and shorter reaction time under the assistance of microwave heating 100 °C over 2 h.
DOI: 10.6084/m9.figshare.19346166.v1
title: Diyne mediated formal synthesis of (−)-A26771B

description: A formal asymmetric synthesis of (−)-A26771B (1) has been achieved where optically active glycidol and Noyori asymmetric hydrogenation are applied to introduce asymmetric centers. Commercially available 1,7-octadiyne, (<i>R</i>)-glycidol and acetaldehyde are used as the starting materials. The outlined synthetic strategy involves fewer number of synthetic steps, applying simple chemical transformations.
DOI: 10.6084/m9.figshare.19346166
title: Diyne mediated formal synthesis of (−)-A26771B

description: A formal asymmetric synthesis of (−)-A26771B (1) has been achieved where optically active glycidol and Noyori asymmetric hydrogenation are applied to introduce asymmetric centers. Commercially available 1,7-octadiyne, (<i>R</i>)-glycidol and acetaldehyde are used as the starting materials. The outlined synthetic strategy involves fewer number of synthetic steps, applying simple chemical transformations.
DOI: 10.5281/zenodo.6587463
title: Florian Fischer Master thesis data

description: Raw data for all presented evaluations in Florian Fischer's Master thesis: Elevating System Requests to First-Class Citizens of<br> Work-Stealing Concurrency Platforms
DOI: 10.5281/zenodo.6587462
title: Florian Fischer Master thesis data

description: Raw data for all presented evaluations in Florian Fischer's Master thesis: Elevating System Requests to First-Class Citizens of<br> Work-Stealing Concurrency Platforms
DOI: 10.25909/6294629e7fb99
title: Untitled Item

description: doi mint
DOI: 10.6084/m9.figshare.19531561
title: Targeted therapy for adrenocortical carcinoma: a genomic-based search for available and emerging options.

description: Supplementary to the publication mentioned above<br>
DOI: 10.6084/m9.figshare.19531561.v3
title: Targeted therapy for adrenocortical carcinoma: a genomic-based search for available and emerging options.

description: Supplementary to the publication mentioned above<br>
DOI: 10.6084/m9.figshare.19531561.v2
title: Targeted therapy for adrenocortical carcinoma: a genomic-based search for available and emerging options.

description: Supplementary to the publication mentioned above<br>
DOI: 10.5445/ir/1000146637
title: Ancillary files for "Meson width differences and asymmetries - Calculations of higher order contributions to neutral B-meson mixing"
DOI: 10.6084/m9.figshare.16767220
title: Supplementary Materials: High-frequency Fluctuation Intensity as a Predictor of Post-Stenotic Dilatation in Swine

description: Supplementary Materials: High-frequency Fluctuation Intensity as a Predictor of Post-Stenotic Dilatation in Swine
DOI: 10.6084/m9.figshare.16767220.v8
title: Supplementary Materials: High-frequency Fluctuation Intensity as a Predictor of Post-Stenotic Dilatation in Swine

description: Supplementary Materials: High-frequency Fluctuation Intensity as a Predictor of Post-Stenotic Dilatation in Swine
DOI: 10.6084/m9.figshare.16767220.v7
title: Supplementary Materials: High-frequency Fluctuation Intensity as a Predictor of Post-Stenotic Dilatation in Swine

description: Supplementary Materials: High-frequency Fluctuation Intensity as a Predictor of Post-Stenotic Dilatation in Swine
DOI: 10.14278/rodare.1641
title: Data publication: Contactless Inductive Flow Tomography for real-time control of electromagnetic actuators in metal casting

description: Dataset containing the raw and post-processed data used for in the associated publication. Dataset contains the measurements of the flow-induced magnetic field for identification of the compensation parameters and the test data used to validate the model. It also contains the down-sampled velocity profile generated from the numerical simulations, and the reconstructions of the same velocity profile.
DOI: 10.14278/rodare.1640
title: Data publication: Contactless Inductive Flow Tomography for real-time control of electromagnetic actuators in metal casting

description: Dataset containing the raw and post-processed data used for in the associated publication. Dataset contains the measurements of the flow-induced magnetic field for identification of the compensation parameters and the test data used to validate the model. It also contains the down-sampled velocity profile generated from the numerical simulations, and the reconstructions of the same velocity profile.
DOI: 10.5281/zenodo.6592207
title: Aphid conservation biological control in arable crops via flower strips: the predominant role of plant resources over diversity effects

description: Dataset and R code
DOI: 10.5281/zenodo.6592206
title: Aphid conservation biological control in arable crops via flower strips: the predominant role of plant resources over diversity effects

description: Dataset and R code
DOI: 10.5281/zenodo.6592071
title: TACO dataset YOLO Split

description: TACO dataset converted to YOLO txt with different splits
DOI: 10.6084/m9.figshare.19920437
title: Gradual and Transformative Institutional Change: the influence of stakeholders and advocacy coalitions at the Belo Monte Hydroelectric power plant

description: Abstract This work analyzes the performance of stakeholders and advocacy coalitions in processes of gradual institutional change based on the case study of the Belo Monte hydroelectric power plant. The methodology adopts content analysis, using shorthand notes of hearings held in the National Congress, and other publicly available documents. In-depth semi-structured interviews were also conducted, collecting data from individuals involved in the history of the power plant. The study allowed to characterize stakeholders pro or against the enterprise, observing their degree of influence and the role played. In addition, the work used the Advocacy Coalition Framework to verify how stakeholders formed three advocacy coalitions and exerted the strategies of institutional change ‘displacement,’ ‘conversion,’ and ‘layering’ following the gradual and transformative institutional change model. Empirical evidence indicates that the composition of coalition members may determine the type of institutional change and that institutional changes can also result from learning among coalitions, as the incorporation of socio-environmental considerations that have altered the original design of the hydroelectric power plant.
DOI: 10.6084/m9.figshare.19920437.v1
title: Gradual and Transformative Institutional Change: the influence of stakeholders and advocacy coalitions at the Belo Monte Hydroelectric power plant

description: Abstract This work analyzes the performance of stakeholders and advocacy coalitions in processes of gradual institutional change based on the case study of the Belo Monte hydroelectric power plant. The methodology adopts content analysis, using shorthand notes of hearings held in the National Congress, and other publicly available documents. In-depth semi-structured interviews were also conducted, collecting data from individuals involved in the history of the power plant. The study allowed to characterize stakeholders pro or against the enterprise, observing their degree of influence and the role played. In addition, the work used the Advocacy Coalition Framework to verify how stakeholders formed three advocacy coalitions and exerted the strategies of institutional change ‘displacement,’ ‘conversion,’ and ‘layering’ following the gradual and transformative institutional change model. Empirical evidence indicates that the composition of coalition members may determine the type of institutional change and that institutional changes can also result from learning among coalitions, as the incorporation of socio-environmental considerations that have altered the original design of the hydroelectric power plant.
DOI: 10.6084/m9.figshare.19920439
title: Aquatic physiotherapy in the functional capacity of elderly with knee osteoarthritis

description: Abstract Introduction: Physicaltherapy in patients with osteoarthritis (OA) acts to decrease pain, increase joint functionality and to promote improvement in quality of life. Objective: To analyze the effect of a structured program of aquatic physiotherapy (AP) on functional capacity (FC) and mobility of elderly people with OA. Methods: Prospective, quantitative and analytical, randomized control study. The sample consisted of 29 patients, aged 60 years or over, diagnosed with OA, randomly allocated to the intervention group (IG), composed of 17 participants who underwent BP for two months, and to the control group (CG) of 12 participants. The primary outcome was measured by the WOMAC instruments and six-minute walk test. As a secondary endpoint, the Timed Up and Go Test measured mobility. Descriptive statistical analysis was used to present the data, with mean and standard deviation values. The comparison between groups for potential confounding factors and in relation to evolution was performed using the non-parametric chi-square test, Fisher's exact test and the Kruskal-Wallis test, and Dunn's test for multiple comparisons. The differences were considered statistically significant when p &lt; 0.05. Results: There was a significant difference in physical and functional parameters related to pain (p &lt; 0.001), stiffness (p &lt; 0.001) physical activity (p &lt; 0.001), distance covered in six minutes (p = 0.001), and mobility (p &lt; 0.001) when comparing IG to CG. Conclusion: The structured AP program effectively contributed to the improvement of FC and mobility of elderly people with knee OA.
DOI: 10.6084/m9.figshare.19920439.v1
title: Aquatic physiotherapy in the functional capacity of elderly with knee osteoarthritis

description: Abstract Introduction: Physicaltherapy in patients with osteoarthritis (OA) acts to decrease pain, increase joint functionality and to promote improvement in quality of life. Objective: To analyze the effect of a structured program of aquatic physiotherapy (AP) on functional capacity (FC) and mobility of elderly people with OA. Methods: Prospective, quantitative and analytical, randomized control study. The sample consisted of 29 patients, aged 60 years or over, diagnosed with OA, randomly allocated to the intervention group (IG), composed of 17 participants who underwent BP for two months, and to the control group (CG) of 12 participants. The primary outcome was measured by the WOMAC instruments and six-minute walk test. As a secondary endpoint, the Timed Up and Go Test measured mobility. Descriptive statistical analysis was used to present the data, with mean and standard deviation values. The comparison between groups for potential confounding factors and in relation to evolution was performed using the non-parametric chi-square test, Fisher's exact test and the Kruskal-Wallis test, and Dunn's test for multiple comparisons. The differences were considered statistically significant when p &lt; 0.05. Results: There was a significant difference in physical and functional parameters related to pain (p &lt; 0.001), stiffness (p &lt; 0.001) physical activity (p &lt; 0.001), distance covered in six minutes (p = 0.001), and mobility (p &lt; 0.001) when comparing IG to CG. Conclusion: The structured AP program effectively contributed to the improvement of FC and mobility of elderly people with knee OA.
DOI: 10.6084/m9.figshare.19920445
title: MULTIVARIATE ANALYSIS APPLIED TO SPRAY DEPOSITION IN GROUND APPLICATION OF PHYTOSANITARY PRODUCTS IN COFFEE PLANTS

description: ABSTRACT An adequate combination of factors involved in the technology used for phytosanitary product application contributes to an efficient spray deposition on the target. The objective of this study was to use multivariate analysis to characterize the magnitude of effects and the order of influence of three factors that interfere with the quality of phytosanitary product application in coffee plants. An entirely randomized design was adopted, with four repetitions, using a 2 × 2 × 3 factorial scheme, with two classes of droplets quality (fine and coarse), two application rates (250 and 400 L ha-1), and the use of adjuvants (with no adjuvant or with Fighter®and Aureo® adjuvants). The quality of the application was determined by jointly analyzing the spray deposition on three thirds of leaves, in their internal and external layers, the runoff to soil, coverage, droplet density, relative amplitude, and the volumetric median diameter. The results underwent analysis of variance (ANOVA) to measure the effect sizes (η2). After testing the assumptions of multivariate analysis, clustering and principal component analyses were performed. The class of droplets was found to be the most influential factor in the quality of the phytosanitary product application (spray deposition and runoff to soil). When focusing on spray deposition on leaves, the second-most influential factor was the application rate and the relation between the application rate and the adjuvants. For the other variables, the second-most influential factor was the application rate.