cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.17188/1683245
title: Materials Data on Li3V3SbO8 by Materials Project

description: Li3V3SbO8 crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. there are two inequivalent Li1+ sites. In the first Li1+ site, Li1+ is bonded to six O2- atoms to form LiO6 octahedra that share corners with six equivalent VO6 octahedra, edges with two equivalent SbO6 octahedra, edges with four LiO6 octahedra, and edges with four VO6 octahedra. The corner-sharing octahedra tilt angles range from 7–8°. There are a spread of Li–O bond distances ranging from 2.19–2.30 Å. In the second Li1+ site, Li1+ is bonded to six O2- atoms to form LiO6 octahedra that share corners with six equivalent VO6 octahedra, edges with two equivalent SbO6 octahedra, edges with four equivalent LiO6 octahedra, and edges with four equivalent VO6 octahedra. The corner-sharing octahedral tilt angles are 9°. There are two shorter (2.16 Å) and four longer (2.18 Å) Li–O bond lengths. There are two inequivalent V5+ sites. In the first V5+ site, V5+ is bonded to six O2- atoms to form VO6 octahedra that share corners with six equivalent LiO6 octahedra, edges with two equivalent SbO6 octahedra, edges with four LiO6 octahedra, and edges with four VO6 octahedra. The corner-sharing octahedra tilt angles range from 7–8°. There are a spread of V–O bond distances ranging from 2.05–2.16 Å. In the second V5+ site, V5+ is bonded to six O2- atoms to form VO6 octahedra that share corners with six equivalent LiO6 octahedra, edges with two equivalent SbO6 octahedra, edges with four equivalent LiO6 octahedra, and edges with four equivalent VO6 octahedra. The corner-sharing octahedral tilt angles are 9°. There are two shorter (2.15 Å) and four longer (2.17 Å) V–O bond lengths. Sb2- is bonded to six O2- atoms to form SbO6 octahedra that share edges with six LiO6 octahedra and edges with six VO6 octahedra. All Sb–O bond lengths are 2.01 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded to three Li1+ and three V5+ atoms to form OLi3V3 octahedra that share corners with six equivalent OLi3V3 octahedra and edges with twelve OLi2V2Sb square pyramids. The corner-sharing octahedral tilt angles are 0°. In the second O2- site, O2- is bonded to two Li1+, two V5+, and one Sb2- atom to form OLi2V2Sb square pyramids that share corners with nine OLi2V2Sb square pyramids, edges with four equivalent OLi3V3 octahedra, and edges with four OLi2V2Sb square pyramids. In the third O2- site, O2- is bonded to two equivalent Li1+, two equivalent V5+, and one Sb2- atom to form OLi2V2Sb square pyramids that share corners with nine OLi2V2Sb square pyramids, edges with four equivalent OLi3V3 octahedra, and edges with four equivalent OLi2V2Sb square pyramids.
DOI: 10.17188/1683247
title: Materials Data on Li2La2Si3 by Materials Project

description: La2Li2Si3 crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. Li is bonded to three equivalent La and four Si atoms to form a mixture of distorted edge, face, and corner-sharing LiLa3Si4 tetrahedra. All Li–La bond lengths are 3.16 Å. There are a spread of Li–Si bond distances ranging from 2.63–2.77 Å. There are two inequivalent La sites. In the first La site, La is bonded in a 9-coordinate geometry to nine Si atoms. There are a spread of La–Si bond distances ranging from 3.15–3.28 Å. In the second La site, La is bonded in a 12-coordinate geometry to six equivalent Li and six Si atoms. All La–Si bond lengths are 3.20 Å. There are two inequivalent Si sites. In the first Si site, Si is bonded in a 1-coordinate geometry to one Li, six La, and two equivalent Si atoms. There are one shorter (2.39 Å) and one longer (2.40 Å) Si–Si bond lengths. In the second Si site, Si is bonded in a 6-coordinate geometry to six equivalent Li and three La atoms.
DOI: 10.17188/1683248
title: Materials Data on La3Yb2(GaO4)3 by Materials Project

description: Yb2La3(GaO4)3 crystallizes in the cubic Ia-3d space group. The structure is three-dimensional. Yb3+ is bonded to six equivalent O2- atoms to form YbO6 octahedra that share corners with six equivalent GaO4 tetrahedra. All Yb–O bond lengths are 2.29 Å. La3+ is bonded in a body-centered cubic geometry to eight equivalent O2- atoms. There are four shorter (2.51 Å) and four longer (2.58 Å) La–O bond lengths. Ga3+ is bonded to four equivalent O2- atoms to form GaO4 tetrahedra that share corners with four equivalent YbO6 octahedra. The corner-sharing octahedral tilt angles are 56°. All Ga–O bond lengths are 1.89 Å. O2- is bonded in a 4-coordinate geometry to one Yb3+, two equivalent La3+, and one Ga3+ atom.
DOI: 10.17188/1683250
title: Materials Data on YbZr3F15 by Materials Project

description: YbZr3F15 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. Yb3+ is bonded in a 8-coordinate geometry to eight F1- atoms. There are a spread of Yb–F bond distances ranging from 2.29–2.31 Å. There are two inequivalent Zr4+ sites. In the first Zr4+ site, Zr4+ is bonded in an octahedral geometry to six F1- atoms. There are a spread of Zr–F bond distances ranging from 2.01–2.09 Å. In the second Zr4+ site, Zr4+ is bonded in a 8-coordinate geometry to eight F1- atoms. There are a spread of Zr–F bond distances ranging from 2.04–2.31 Å. There are eight inequivalent F1- sites. In the first F1- site, F1- is bonded in a bent 150 degrees geometry to two equivalent Zr4+ atoms. In the second F1- site, F1- is bonded in a bent 150 degrees geometry to one Yb3+ and one Zr4+ atom. In the third F1- site, F1- is bonded in a bent 150 degrees geometry to one Yb3+ and one Zr4+ atom. In the fourth F1- site, F1- is bonded in a linear geometry to two equivalent Zr4+ atoms. In the fifth F1- site, F1- is bonded in a linear geometry to one Yb3+ and one Zr4+ atom. In the sixth F1- site, F1- is bonded in a bent 150 degrees geometry to one Yb3+ and one Zr4+ atom. In the seventh F1- site, F1- is bonded in a distorted bent 150 degrees geometry to two Zr4+ atoms. In the eighth F1- site, F1- is bonded in a bent 150 degrees geometry to two Zr4+ atoms.
DOI: 10.17188/1683252
title: Materials Data on Zr3FeF6 by Materials Project

description: Zr2FeF4ZrF2 crystallizes in the triclinic P-1 space group. The structure is two-dimensional and consists of one 13842-94-9 molecule and one Zr2FeF4 sheet oriented in the (0, 0, 1) direction. In the Zr2FeF4 sheet, there are two inequivalent Zr sites. In the first Zr site, Zr is bonded in a linear geometry to two equivalent F atoms. Both Zr–F bond lengths are 2.03 Å. In the second Zr site, Zr is bonded in a linear geometry to two equivalent F atoms. Both Zr–F bond lengths are 2.03 Å. Fe is bonded in a distorted rectangular see-saw-like geometry to four F atoms. There are two shorter (2.15 Å) and two longer (2.19 Å) Fe–F bond lengths. There are two inequivalent F sites. In the first F site, F is bonded in a water-like geometry to one Zr and one Fe atom. In the second F site, F is bonded in a water-like geometry to one Zr and one Fe atom.
DOI: 10.17188/1683253
title: Materials Data on Li2MnF5 by Materials Project

description: Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations
DOI: 10.17188/1683254
title: Materials Data on Na3VSO3 by Materials Project

description: Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations
DOI: 10.17188/1683256
title: Materials Data on La2TiCo16 by Materials Project

description: La2TiCo16 crystallizes in the trigonal R3m space group. The structure is three-dimensional. there are two inequivalent La sites. In the first La site, La is bonded in a 10-coordinate geometry to nineteen Co atoms. There are a spread of La–Co bond distances ranging from 3.03–3.27 Å. In the second La site, La is bonded in a 9-coordinate geometry to one Ti and eighteen Co atoms. The La–Ti bond length is 3.18 Å. There are a spread of La–Co bond distances ranging from 3.02–3.36 Å. Ti is bonded in a 1-coordinate geometry to one La and thirteen Co atoms. There are a spread of Ti–Co bond distances ranging from 2.35–2.70 Å. There are five inequivalent Co sites. In the first Co site, Co is bonded to two La, one Ti, and nine Co atoms to form a mixture of distorted edge, corner, and face-sharing CoLa2TiCo9 cuboctahedra. There are a spread of Co–Co bond distances ranging from 2.40–2.72 Å. In the second Co site, Co is bonded to two La, one Ti, and nine Co atoms to form a mixture of distorted edge, corner, and face-sharing CoLa2TiCo9 cuboctahedra. There are a spread of Co–Co bond distances ranging from 2.40–2.56 Å. In the third Co site, Co is bonded to three La, one Ti, and eight Co atoms to form a mixture of distorted edge, corner, and face-sharing CoLa3TiCo8 cuboctahedra. Both Co–Co bond lengths are 2.52 Å. In the fourth Co site, Co is bonded to three La and nine Co atoms to form a mixture of edge, corner, and face-sharing CoLa3Co9 cuboctahedra. The Co–Co bond length is 2.58 Å. In the fifth Co site, Co is bonded in a distorted single-bond geometry to one La, one Ti, and twelve Co atoms.
DOI: 10.17188/1683257
title: Materials Data on MnCoO4 by Materials Project

description: Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations
DOI: 10.17188/1683258
title: Materials Data on Sb2S3 by Materials Project

description: Sb2S3 is Stibnite structured and crystallizes in the orthorhombic Pmn2_1 space group. The structure is two-dimensional and consists of two Sb2S3 sheets oriented in the (0, 0, 1) direction. there are four inequivalent Sb3+ sites. In the first Sb3+ site, Sb3+ is bonded in a 6-coordinate geometry to six S2- atoms. There are a spread of Sb–S bond distances ranging from 2.55–3.26 Å. In the second Sb3+ site, Sb3+ is bonded to five S2- atoms to form SbS5 square pyramids that share corners with two equivalent SbS6 octahedra, an edgeedge with one SbS6 octahedra, and edges with four SbS5 square pyramids. The corner-sharing octahedral tilt angles are 9°. There are a spread of Sb–S bond distances ranging from 2.49–2.86 Å. In the third Sb3+ site, Sb3+ is bonded to six S2- atoms to form distorted SbS6 octahedra that share corners with two equivalent SbS5 square pyramids, edges with two equivalent SbS6 octahedra, and edges with three SbS5 square pyramids. There are a spread of Sb–S bond distances ranging from 2.57–3.19 Å. In the fourth Sb3+ site, Sb3+ is bonded to five S2- atoms to form SbS5 square pyramids that share edges with two equivalent SbS6 octahedra and edges with four SbS5 square pyramids. There are a spread of Sb–S bond distances ranging from 2.48–2.88 Å. There are six inequivalent S2- sites. In the first S2- site, S2- is bonded in a 3-coordinate geometry to three Sb3+ atoms. In the second S2- site, S2- is bonded in a 3-coordinate geometry to three Sb3+ atoms. In the third S2- site, S2- is bonded to five Sb3+ atoms to form distorted edge-sharing SSb5 square pyramids. In the fourth S2- site, S2- is bonded in a distorted water-like geometry to three Sb3+ atoms. In the fifth S2- site, S2- is bonded in a distorted trigonal non-coplanar geometry to three Sb3+ atoms. In the sixth S2- site, S2- is bonded to five Sb3+ atoms to form distorted edge-sharing SSb5 square pyramids.
DOI: 10.17188/1683259
title: Materials Data on Sr2CrN2 by Materials Project

description: Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations
DOI: 10.17188/1683260
title: Materials Data on LaCoO3 by Materials Project

description: Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations
DOI: 10.17188/1683261
title: Materials Data on Li2Mn3(P2O7)2 by Materials Project

description: Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations
DOI: 10.17188/1683262
title: Materials Data on Ni(ClO3)2 by Materials Project

description: NiO4O2Cl2 is Heusler structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four hydrochloric acid molecules, two oxygen molecules, and two NiO4 clusters. In each NiO4 cluster, Ni is bonded in a square co-planar geometry to four equivalent O atoms. All Ni–O bond lengths are 1.76 Å. O is bonded in a single-bond geometry to one Ni atom.
DOI: 10.17188/1683263
title: Materials Data on Cs3BN2 by Materials Project

description: Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations
DOI: 10.17188/1683264
title: Materials Data on BaCr2AsO10 by Materials Project

description: BaCr2AsO10 crystallizes in the triclinic P-1 space group. The structure is three-dimensional. Ba is bonded in a 10-coordinate geometry to ten O atoms. There are a spread of Ba–O bond distances ranging from 2.75–3.16 Å. There are two inequivalent Cr sites. In the first Cr site, Cr is bonded to four O atoms to form CrO4 tetrahedra that share a cornercorner with one AsO4 tetrahedra. There are a spread of Cr–O bond distances ranging from 1.62–1.81 Å. In the second Cr site, Cr is bonded to four O atoms to form CrO4 tetrahedra that share a cornercorner with one AsO4 tetrahedra. There are a spread of Cr–O bond distances ranging from 1.62–1.83 Å. As is bonded to four O atoms to form AsO4 tetrahedra that share corners with two CrO4 tetrahedra. There are a spread of As–O bond distances ranging from 1.67–1.77 Å. There are ten inequivalent O sites. In the first O site, O is bonded in a distorted single-bond geometry to two equivalent Ba and one As atom. In the second O site, O is bonded in a distorted single-bond geometry to one Ba and one As atom. In the third O site, O is bonded in a distorted bent 150 degrees geometry to one Cr and one As atom. In the fourth O site, O is bonded in a bent 120 degrees geometry to one Cr and one As atom. In the fifth O site, O is bonded in a distorted single-bond geometry to one Ba and one Cr atom. In the sixth O site, O is bonded in a single-bond geometry to one Ba and one Cr atom. In the seventh O site, O is bonded in a distorted single-bond geometry to one Ba and one Cr atom. In the eighth O site, O is bonded in a single-bond geometry to two equivalent Ba and one Cr atom. In the ninth O site, O is bonded in a single-bond geometry to one Ba and one Cr atom. In the tenth O site, O is bonded in a single-bond geometry to one Ba and one Cr atom.
DOI: 10.17188/1683265
title: Materials Data on CeSi2OsRu by Materials Project

description: CeOsRuSi2 crystallizes in the tetragonal I-4m2 space group. The structure is three-dimensional. Ce3+ is bonded in a 8-coordinate geometry to eight equivalent Si4- atoms. All Ce–Si bond lengths are 3.24 Å. Os1+ is bonded to four equivalent Si4- atoms to form OsSi4 tetrahedra that share corners with four equivalent OsSi4 tetrahedra and edges with four equivalent RuSi4 tetrahedra. All Os–Si bond lengths are 2.40 Å. Ru4+ is bonded to four equivalent Si4- atoms to form RuSi4 tetrahedra that share corners with four equivalent RuSi4 tetrahedra and edges with four equivalent OsSi4 tetrahedra. All Ru–Si bond lengths are 2.40 Å. Si4- is bonded in a 9-coordinate geometry to four equivalent Ce3+, two equivalent Os1+, and two equivalent Ru4+ atoms.
DOI: 10.17188/1683266
title: Materials Data on LiCoP2O7 by Materials Project

description: Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations
DOI: 10.17188/1683267
title: Materials Data on Mg2Ti by Materials Project

description: Mg2Ti is beta-derived structured and crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. there are two inequivalent Mg sites. In the first Mg site, Mg is bonded to six Mg and six equivalent Ti atoms to form MgMg6Ti6 cuboctahedra that share corners with six equivalent TiMg10Ti2 cuboctahedra, corners with twelve MgMg6Ti6 cuboctahedra, edges with seven equivalent TiMg10Ti2 cuboctahedra, edges with eleven equivalent MgMg8Ti4 cuboctahedra, faces with six equivalent TiMg10Ti2 cuboctahedra, and faces with fourteen MgMg8Ti4 cuboctahedra. There are a spread of Mg–Mg bond distances ranging from 3.00–3.11 Å. There are two shorter (3.03 Å) and four longer (3.07 Å) Mg–Ti bond lengths. In the second Mg site, Mg is bonded to eight Mg and four equivalent Ti atoms to form MgMg8Ti4 cuboctahedra that share corners with six equivalent TiMg10Ti2 cuboctahedra, corners with twelve MgMg8Ti4 cuboctahedra, edges with three equivalent TiMg10Ti2 cuboctahedra, edges with fifteen MgMg6Ti6 cuboctahedra, faces with eight equivalent TiMg10Ti2 cuboctahedra, and faces with twelve MgMg6Ti6 cuboctahedra. There are two shorter (3.00 Å) and four longer (3.08 Å) Mg–Mg bond lengths. There are two shorter (3.12 Å) and two longer (3.14 Å) Mg–Ti bond lengths. Ti is bonded to ten Mg and two equivalent Ti atoms to form TiMg10Ti2 cuboctahedra that share corners with six equivalent TiMg10Ti2 cuboctahedra, corners with twelve MgMg8Ti4 cuboctahedra, edges with eight equivalent TiMg10Ti2 cuboctahedra, edges with ten MgMg6Ti6 cuboctahedra, faces with six equivalent TiMg10Ti2 cuboctahedra, and faces with fourteen MgMg6Ti6 cuboctahedra. Both Ti–Ti bond lengths are 3.00 Å.
DOI: 10.17188/1683268
title: Materials Data on AgI3O8 by Materials Project

description: AgO8I3 crystallizes in the orthorhombic Pnc2 space group. The structure is three-dimensional. there are two inequivalent Ag1+ sites. In the first Ag1+ site, Ag1+ is bonded in a 8-coordinate geometry to eight O2- atoms. There are a spread of Ag–O bond distances ranging from 2.52–2.90 Å. In the second Ag1+ site, Ag1+ is bonded in a 4-coordinate geometry to six O2- atoms. There are a spread of Ag–O bond distances ranging from 2.46–2.88 Å. There are eight inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted trigonal non-coplanar geometry to two Ag1+ and one I5+ atom. The O–I bond length is 1.83 Å. In the second O2- site, O2- is bonded in a distorted single-bond geometry to one Ag1+ and two I5+ atoms. There are one shorter (1.81 Å) and one longer (2.75 Å) O–I bond lengths. In the third O2- site, O2- is bonded in a distorted bent 120 degrees geometry to two I5+ atoms. There are one shorter (1.98 Å) and one longer (2.07 Å) O–I bond lengths. In the fourth O2- site, O2- is bonded in a distorted single-bond geometry to three I5+ atoms. There are a spread of O–I bond distances ranging from 1.84–2.82 Å. In the fifth O2- site, O2- is bonded in a 2-coordinate geometry to one Ag1+ and one I5+ atom. The O–I bond length is 1.82 Å. In the sixth O2- site, O2- is bonded in a distorted single-bond geometry to two Ag1+ and two I5+ atoms. There are one shorter (1.81 Å) and one longer (2.75 Å) O–I bond lengths. In the seventh O2- site, O2- is bonded in a distorted trigonal planar geometry to one Ag1+ and two I5+ atoms. There are one shorter (1.97 Å) and one longer (2.09 Å) O–I bond lengths. In the eighth O2- site, O2- is bonded in a distorted single-bond geometry to three I5+ atoms. There are a spread of O–I bond distances ranging from 1.84–2.80 Å. There are four inequivalent I5+ sites. In the first I5+ site, I5+ is bonded in a 6-coordinate geometry to six O2- atoms. In the second I5+ site, I5+ is bonded in a distorted see-saw-like geometry to four O2- atoms. In the third I5+ site, I5+ is bonded in a 6-coordinate geometry to six O2- atoms. In the fourth I5+ site, I5+ is bonded in a 4-coordinate geometry to four O2- atoms.
DOI: 10.17188/1683269
title: Materials Data on BaFeF5 by Materials Project

description: Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations
DOI: 10.17188/1683270
title: Materials Data on Na5Br4Cl by Materials Project

description: Na5Br4Cl is Caswellsilverite-like structured and crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. there are four inequivalent Na1+ sites. In the first Na1+ site, Na1+ is bonded to six Br1- atoms to form a mixture of edge and corner-sharing NaBr6 octahedra. The corner-sharing octahedral tilt angles are 0°. All Na–Br bond lengths are 2.99 Å. In the second Na1+ site, Na1+ is bonded to five Br1- and one Cl1- atom to form a mixture of edge and corner-sharing NaBr5Cl octahedra. The corner-sharing octahedra tilt angles range from 0–1°. There are four shorter (2.99 Å) and one longer (3.01 Å) Na–Br bond lengths. The Na–Cl bond length is 2.96 Å. In the third Na1+ site, Na1+ is bonded to two equivalent Br1- and four equivalent Cl1- atoms to form NaBr2Cl4 octahedra that share corners with six NaBr6 octahedra and edges with twelve NaBr5Cl octahedra. The corner-sharing octahedral tilt angles are 0°. Both Na–Br bond lengths are 2.98 Å. All Na–Cl bond lengths are 2.99 Å. In the fourth Na1+ site, Na1+ is bonded to six Br1- atoms to form a mixture of edge and corner-sharing NaBr6 octahedra. The corner-sharing octahedral tilt angles are 0°. All Na–Br bond lengths are 2.99 Å. There are two inequivalent Br1- sites. In the first Br1- site, Br1- is bonded to six Na1+ atoms to form BrNa6 octahedra that share corners with six BrNa6 octahedra, edges with four equivalent ClNa6 octahedra, and edges with eight BrNa6 octahedra. The corner-sharing octahedra tilt angles range from 0–1°. In the second Br1- site, Br1- is bonded to six Na1+ atoms to form BrNa6 octahedra that share a cornercorner with one ClNa6 octahedra, corners with five BrNa6 octahedra, and edges with twelve BrNa6 octahedra. The corner-sharing octahedral tilt angles are 0°. Cl1- is bonded to six Na1+ atoms to form ClNa6 octahedra that share corners with two equivalent BrNa6 octahedra, corners with four equivalent ClNa6 octahedra, edges with four equivalent ClNa6 octahedra, and edges with eight equivalent BrNa6 octahedra. The corner-sharing octahedral tilt angles are 0°.
DOI: 10.17188/1683272
title: Materials Data on Cs2PtCl4 by Materials Project

description: Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations
DOI: 10.17188/1683273
title: Materials Data on EuBi2 by Materials Project

description: EuBi2 is Zirconium Disilicide structured and crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. Eu is bonded in a 10-coordinate geometry to ten Bi atoms. There are a spread of Eu–Bi bond distances ranging from 3.40–3.74 Å. There are two inequivalent Bi sites. In the first Bi site, Bi is bonded in a 4-coordinate geometry to six equivalent Eu and two equivalent Bi atoms. Both Bi–Bi bond lengths are 3.18 Å. In the second Bi site, Bi is bonded in a 8-coordinate geometry to four equivalent Eu and four equivalent Bi atoms. All Bi–Bi bond lengths are 3.34 Å.