cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.48436/4ps6f-c4d29
title: Palladium-catalyzed ortho alkoxylation of oxazoline derivatives: An avenue to reach meta-substituted electron-rich arenes via employing a traceless directing group

description: Analytical Data and Compound Numbering (in paper numbering vs. ELN entries) for the Publication entitled:"Palladium-catalyzed ortho alkoxylation of oxazoline derivatives: An avenue to reach meta-substituted electron-rich arenes via employing a traceless directing group"

The paper was published on 2024-10-25 in ACS Omega

DOI: 10.1021/acsomega.4c04389

Authors: Raheleh Pourkaveh, Dennis Svatunek, Michael Schnürch

Funded by the Austrian Science Fund (FWF, project number P33064-N) 

Context and methodology

An efficient and highly regioselective palladium-catalyzed oxazoline-directed alkoxylation is reported. The reaction proceeds under air and mild temperatures (60 °C). A series of alcohols can be used as alkoxylating agents and concomitantly act as reaction solvents, whereas primary and secondary alcohols are tolerated. Furthermore, fluorinated alcohols can be applied as well, introducing pharmaceutically relevant fluorine-containing groups. 1,3-Dialkoxylated products can be further subjected to hydrolysis transforming the oxazoline-directing group to a carboxylic acid, which can be removed by decarboxylation if desired. This approach demonstrates the capability to reverse the conventional site selectivity of electrophilic aromatic substitution reactions, since it allows the synthesis of arenes with two electron-donating groups in a 1,3-relationship.

The publication and its Supporting Information can be found as open-access files on the publisher's website (see DOI above).

All detailed files containing the analytical raw data, for all compounds given in the Supporting Information of the manuscript are uploaded. An additional pdf file named File code for compounds.pdf is uploaded, that should clearly link the compound number given in the paper to the respective entry in the ELN and the respective analytical data files. 

Technical details

The files uploaded contain the FIDs of NMR spectra recorded by an in-house Bruker Spectrometer. A software to display NMR-spectra is needed, such as MestreNova or Topspin).

HRMS data is uploaded too and has to be processed via MassHunter software.
DOI: 10.15468/dl.39kq8b
title: Occurrence Download

description: A dataset containing 310 species occurrences available in GBIF matching the query:
{
 "TaxonKey" : [
 "is Hedysarum polybotrys Hand.-Mazz."
 ]
}

 The dataset includes 310 records from 29 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0002692-250121130708018/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.vu3fqd
title: Occurrence Download

description: A dataset containing 15 species occurrences available in GBIF matching the query:
{
 "TaxonKey" : [
 "is Anathallis amazonica E.M.Pessoa & M.Alves"
 ]
}

 The dataset includes 15 records from 3 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0002693-250121130708018/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.at24th
title: Occurrence Download

description: A dataset containing 1993 species occurrences available in GBIF matching the query:
{
 "DatasetKey" : [
 "is Distribución, estructura poblacional y utilización del saguaro (Carnegiea gigantea (Engelm.) Britt. & Rose) en México"
 ]
}

 The dataset includes 1993 records from 1 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0002694-250121130708018/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.r98kgp
title: Occurrence Download

description: A dataset containing 1796 species occurrences available in GBIF matching the query:
{
 "TaxonKey" : [
 "is Gempylus serpens Cuvier, 1829"
 ]
}

 The dataset includes 1796 records from 101 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0002690-250121130708018/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.cv32j7
title: Occurrence Download

description: A dataset containing 58 species occurrences available in GBIF matching the query:
{
 "and" : [
 "DatasetKey is one of (International Barcode of Life project (iBOL), iNaturalist Research-grade Observations, Observation.org, Nature data from around the World)",
 "GadmGid is DEU.15_1",
 "TaxonKey is Eriocheir sinensis H.Milne Edwards, 1853",
 "Year 2019-2024"
 ]
}

 The dataset includes 58 records from 3 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0002696-250121130708018/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.6084/m9.figshare.28210808
title: Smooth muscle cell Piezo1 depletion results in impaired contractile properties in murine small bowel: Supp Figure Data

description: Title: Smooth muscle cell Piezo1 depletion results in impaired contractile properties in murine small bowelLoss of Piezo1 in smooth muscle cells (SMCs) of the small bowel disrupts gut motility by impairing contractility, Ca²⁺ flux, and stretch-induced responses. Specifically, Piezo1-deficient SMCs lead to weight loss, delayed transit, muscularis thinning, altered cellular profiles, and expression of ion channels critical for motility, while also resulting in dysrhythmic Ca2+ signaling in vitro. Supplementary data: Figure graph data values
DOI: 10.15468/dl.8z7zya
title: Occurrence Download

description: A dataset containing 3 species occurrences available in GBIF matching the query:
{
 "TaxonKey" : [
 "is Anathallis caroli (Schltr.) F.Barros & Barberena"
 ]
}

 The dataset includes 3 records from 3 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0002697-250121130708018/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.17043/li-2025-wikimpacts-1.0
title: Wikimpacts — A global climate impact database based on automated information extraction from Wikipedia
DOI: 10.15468/dl.ycx4v9
title: Occurrence Download

description: A dataset containing 18151 species occurrences available in GBIF matching the query:
{
 "DatasetKey" : [
 "is Atlas de la nature de Bordeaux Métropole \"Espèces de Métropole\" - Inventaire de la flore de Bordeaux Métropole 2013"
 ]
}

 The dataset includes 18151 records from 1 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0232182-200613084148143/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.agzj4n
title: Occurrence Download

description: A dataset containing 14972 species occurrences available in GBIF matching the query:
{
 "and" : [
 "DatasetKey is MVZ Egg and Nest Collection (Arctos)"
 ]
}

 The dataset includes 14972 records from 1 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0015617-190813142620410/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.nbs2qm
title: Occurrence Download

description: A dataset containing 876 species occurrences available in GBIF matching the query:
{
 "and" : [
 "Country is Germany",
 "DatasetKey is EOD – eBird Observation Dataset",
 "TaxonKey is Turdus torquatus Linnaeus, 1758",
 "Year 2015-2024"
 ]
}

 The dataset includes 876 records from 1 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0014454-240229165702484/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.tud85f
title: Occurrence Download

description: A dataset containing 6608 species occurrences available in GBIF matching the query:
{
 "and" : [
 "Geometry POLYGON((-141.24023 59.80063,-122.7832 59.80063,-122.7832 69.77895,-141.24023 69.77895,-141.24023 59.80063))",
 "HasGeospatialIssue is false",
 "TaxonKey is Bombus Latreille, 1802"
 ]
}

 The dataset includes 6608 records from 16 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0246108-200613084148143/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.ikxq1m
title: Occurrence Download

description: A dataset containing 9150 species occurrences available in GBIF matching the query:
{
 "and" : [
 "DatasetKey is The Collection of Lichenicolous Fungi at the Botanische Staatssammlung München"
 ]
}

 The dataset includes 9150 records from 1 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0015606-190813142620410/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.wlfs1d
title: Occurrence Download

description: A dataset containing 49 species occurrences available in GBIF matching the query:
{
 "and" : [
 {
 "or" : [
 "BasisOfRecord is Observation",
 "BasisOfRecord is Human Observation",
 "BasisOfRecord is Specimen"
 ]
 },
 "Country is Peru",
 "Year 1904-2019",
 "TaxonKey is Panthera onca (Linnaeus, 1758)"
 ]
}

 The dataset includes 49 records from 7 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0015601-190813142620410/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.p3gyqm
title: Occurrence Download

description: A dataset containing 4736 species occurrences available in GBIF matching the query:
{
 "and" : [
 "DatasetKey is iNaturalist Research-grade Observations",
 "TaxonKey is Oxalis montana Raf."
 ]
}

 The dataset includes 4736 records from 1 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0010242-240321170329656/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.amj5pb
title: Occurrence Download

description: A dataset containing 667 species occurrences available in GBIF matching the query:
{
 "and" : [
 "DatasetKey is Antarctic Krill occurrence data from Discovery expeditions"
 ]
}

 The dataset includes 667 records from 1 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0015607-190813142620410/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.unuk99
title: Occurrence Download

description: A dataset containing 60695 species occurrences available in GBIF matching the query:
{
 "TaxonKey" : [
 "is Pungitius pungitius (Linnaeus, 1758)"
 ]
}

 The dataset includes 60695 records from 230 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0248993-200613084148143/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.7cs3ct
title: Occurrence Download

description: A dataset containing 1469 species occurrences available in GBIF matching the query:
{
 "and" : [
 "BasisOfRecord is Specimen",
 "HasCoordinate is true",
 "HasGeospatialIssue is false",
 "OccurrenceStatus is Present",
 "TaxonKey is Eumetopias Gill, 1866"
 ]
}

 The dataset includes 1469 records from 28 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0016243-210819072339941/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.844n6g
title: Occurrence Download

description: A dataset containing 143 species occurrences available in GBIF matching the query:
{
 "TaxonKey" : [
 "is Berberis prattii C.K.Schneid."
 ]
}

 The dataset includes 143 records from 26 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0056017-240229165702484/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.7rftor
title: Occurrence Download

description: A dataset containing 344743 species occurrences available in GBIF matching the query:
{
 "TaxonKey" : [
 "is Scrophularia L."
 ]
}

 The dataset includes 344743 records from 823 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0015610-190813142620410/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.96hesv
title: Occurrence Download

description: A dataset containing 491 species occurrences available in GBIF matching the query:
{
 "TaxonKey" : [
 "is Rasbora borapetensis Smith, 1934"
 ]
}

 The dataset includes 491 records from 25 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0249019-200613084148143/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.u5xnr3
title: Occurrence Download

description: A dataset containing 1922 species occurrences available in GBIF matching the query:
{
 "and" : [
 "TaxonKey is Plantae",
 "HasGeospatialIssue is false",
 "HasCoordinate is true",
 "OccurrenceStatus is Present",
 "Country is Germany",
 "DecimalLongitude is greater than or equal to 13.0256844514838",
 "DecimalLongitude is less than 13.0287440046682",
 "DecimalLatitude is greater than or equal to 47.27011",
 "DecimalLatitude is less than or equal to 55.05864"
 ]
}

 The dataset includes 1922 records from 22 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0014429-240229165702484/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.kdiy7v
title: Occurrence Download

description: A dataset listing the 588 species recorded in GBIF matching the query:
{
 "TaxonKey" : [
 "is Scrophularia L."
 ]
}

 The dataset's 588 records were derived from 823 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0015613-190813142620410/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.4mv3xz
title: Occurrence Download

description: A dataset containing 39310 species occurrences available in GBIF matching the query:
{
 "and" : [
 "TaxonKey is Micranthes stellaris (L.) Galasso, Banfi & Soldano",
 "HasCoordinate is true",
 "HasGeospatialIssue is false"
 ]
}

 The dataset includes 39310 records from 359 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0002426-240202131308920/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.krwnio
title: Occurrence Download

description: A dataset containing 330 species occurrences available in GBIF matching the query:
{
 "TaxonKey" : [
 "is Dermatemys mawii Gray, 1847"
 ]
}

 The dataset includes 330 records from 38 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0023386-190621201848488/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.4nxd9f
title: Occurrence Download

description: A dataset containing 2769 species occurrences available in GBIF matching the query:
{
 "and" : [
 "Country is India",
 "TaxonKey is Lantana camara L."
 ]
}

 The dataset includes 2769 records from 21 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0008399-210819072339941/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.fzm6tl
title: Occurrence Download

description: A dataset containing 45 species occurrences available in GBIF matching the query:
{
 "TaxonKey" : [
 "is Plagiantha tenella Renvoize"
 ]
}

 The dataset includes 45 records from 19 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0023387-190621201848488/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.jmca2q
title: Occurrence Download

description: A dataset containing 123 species occurrences available in GBIF matching the query:
{
 "TaxonKey" : [
 "is Crepis purpurea (Willd.) M.Bieb."
 ]
}

 The dataset includes 123 records from 21 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0014007-240314170635999/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.cbkxs7
title: Occurrence Download

description: A dataset containing 131 species occurrences available in GBIF matching the query:
{
 "and" : [
 {
 "or" : [
 "Continent is North America",
 "Continent is South America"
 ]
 },
 "OccurrenceStatus is Present",
 "TaxonKey is Phaseolus microcarpus Mart."
 ]
}

 The dataset includes 131 records from 8 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0238994-200613084148143/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.rn33m5
title: Occurrence Download

description: A dataset containing 15 species occurrences available in GBIF matching the query:
{
 "TaxonKey" : [
 "is Crotalaria vialis Milne-Redh."
 ]
}

 The dataset includes 15 records from 7 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0014020-240314170635999/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.qs14p6
title: Occurrence Download

description: A dataset containing 140 species occurrences available in GBIF matching the query:
{
 "and" : [
 "BasisOfRecord is Human Observation",
 "DatasetKey is Fundación Miguel Lillo - Colección Criptogámica"
 ]
}

 The dataset includes 140 records from 1 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0005735-190813142620410/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.ck5b8e
title: Occurrence Download

description: A dataset containing 419 species occurrences available in GBIF matching the query:
{
 "TaxonKey" : [
 "is Porthidium dunni (Hartweg & Oliver, 1938)"
 ]
}

 The dataset includes 419 records from 29 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0229488-200613084148143/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.mhdhff
title: Occurrence Download

description: A dataset containing 5721 species occurrences available in GBIF matching the query:
{
 "and" : [
 "Country is Peru",
 "TaxonKey is Myrtis fanny (R.Lesson, 1838)"
 ]
}

 The dataset includes 5721 records from 25 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0003671-240202131308920/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.nfrmah
title: Occurrence Download

description: A dataset containing 4724666 species occurrences available in GBIF matching the query:
{
 "and" : [
 "Country is Colombia",
 "TaxonKey is Aves"
 ]
}

 The dataset includes 4724666 records from 351 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0023397-190621201848488/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.gj27w2
title: Occurrence Download

description: A dataset containing 23 species occurrences available in GBIF matching the query:
{
 "TaxonKey" : [
 "is Anemia ×ulbrichtii Rosenst."
 ]
}

 The dataset includes 23 records from 11 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0229500-200613084148143/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.bkshev
title: Occurrence Download

description: A dataset containing 1001 species occurrences available in GBIF matching the query:
{
 "and" : [
 "Country is Peru",
 "TaxonKey is Chaetocercus bombus Gould, 1871"
 ]
}

 The dataset includes 1001 records from 13 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0003674-240202131308920/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.bxvsud
title: Occurrence Download

description: A dataset containing 10725 species occurrences available in GBIF matching the query:
{
 "TaxonKey" : [
 "is Cannabis sativa L."
 ]
}

 The dataset includes 10725 records from 363 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0008338-190813142620410/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.zdshxj
title: Occurrence Download

description: A dataset containing 20 species occurrences available in GBIF matching the query:
{
 "and" : [
 "DatasetKey is Geographically tagged INSDC sequences",
 "TaxonKey is Proctoporus chasqui (Chávez, Siu-Ting, Duran & Venegas, 2011)"
 ]
}

 The dataset includes 20 records from 1 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0259267-200613084148143/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.hzwyip
title: Occurrence Download

description: A dataset containing 47 species occurrences available in GBIF matching the query:
{
 "and" : [
 "Year 2010-2019",
 "Geometry POLYGON((-74.70703 -54.77535,-66.26953 -56.55948,-64.86328 -54.57206,-66.97266 -51.61802,-65.21484 -46.55886,-59.23828 -40.71396,-54.66797 -38.54817,-56.77734 -33.13755,-54.31641 -27.9944,-59.58984 -19.97335,-63.45703 -13.23995,-64.86328 -9.79568,-68.02734 -4.91583,-67.67578 0,-82.08984 2.1089,-83.14453 -4.21494,-78.57422 -15.62304,-72.24609 -18.97903,-72.59766 -25.48295,-74.35547 -34.59704,-74.70703 -43.83453,-76.81641 -50.51343,-74.70703 -54.77535))",
 "HasCoordinate is true",
 "TaxonKey is Liolaemus nitidus (Wiegmann, 1834)",
 "HasGeospatialIssue is false"
 ]
}

 The dataset includes 47 records from 2 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0013618-190621201848488/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.ygebud
title: Occurrence Download

description: A dataset containing 13 species occurrences available in GBIF matching the query:
{
 "TaxonKey" : [
 "is Culcasia brevipetiolata Bogner"
 ]
}

 The dataset includes 13 records from 4 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0014003-240314170635999/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.t9tzk7
title: Occurrence Download

description: A dataset containing 18 species occurrences available in GBIF matching the query:
{
 "TaxonKey" : [
 "is Condea cubensis (Urb.) Harley & J.F.B.Pastore"
 ]
}

 The dataset includes 18 records from 12 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0153859-240321170329656/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.