cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.15468/dl.z4xmuc
title: Occurrence Download

description: A dataset containing 178146 species occurrences available in GBIF matching the query:
{
 "TaxonKey" : [
 "is Populus nigra"
 ]
}

 The dataset includes 178146 records from 1993 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0047594-250827131500795/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.pr8gtk
title: Occurrence Download

description: A dataset containing 5087 species occurrences available in GBIF matching the query:
{
 "and" : [
 "Country is United States of America",
 {
 "or" : [
 "TaxonKey is Eumorpha pandorus Hübner",
 "TaxonKey is Eumorpha achemon Drury, 1773",
 "TaxonKey is Sphinx eremitus Hübner, 1824"
 ]
 }
 ]
}

 The dataset includes 5087 records from 45 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0364760-210914110416597/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.dqry5f
title: Occurrence Download

description: A dataset containing 298 species occurrences available in GBIF matching the query:
{
 "TaxonKey" : [
 "is Selaginella decomposita Spring"
 ]
}

 The dataset includes 298 records from 39 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0004680-200127171203522/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.kqxcz4
title: Occurrence Download

description: A dataset containing 720 species occurrences available in GBIF matching the query:
{
 "and" : [
 "TaxonKey is one of (Agonimia allobata (Stizenb.) P.James)",
 "Geometry POLYGON((-9.36035 44.71551,-10.59082 42.81152,-11.82129 36.80928,-7.69043 36.17336,-3.38379 35.88905,3.12012 38.13456,9.18457 38.20366,11.7334 37.16032,12.78809 34.74161,17.09473 33.79741, 23.15918 34.23451,30.10254 32.62087,33.2666 32.99024,35.72754 35.03,33.00293 35.53223,28.69629 35.17381,28.34473 36.31513,25.7959 37.50973,24.91699 39.90974,28.78418 40.6473,30.71777 41.17865,36.87012 45.213,38.18848 46.98025,38.71582 47.7541,39.94629 47.93107,40.20996 49.61071,37.0459 50.34546,35.72754 50.40152,33.79395 52.26816,31.68457 51.94426,31.4209 53.27835,32.56348 53.43572,30.98145 54.77535,30.89355 55.52863,28.43262 56.02295,27.20215 57.65716,27.37793 58.30949,27.90527 59.17593,29.66309 59.88894,27.6416 60.58697,31.50879 62.75473,28.78418 69.83962,30.89355 70.28912,29.22363 71.55274,21.75293 71.30079,14.28223 70.14036,11.38184 67.47492,4.87793 63.66576,-5.53711 71.52491,-10.63477 71.69129,-21.5332 67.74276,-28.56445 65.36684,-24.3457 61.35461,-9.36035 44.71551))",
 "HasCoordinate is true",
 "HasGeospatialIssue is false",
 "Year is greater than or equal to 1980",
 "Year is less than or equal to 2021"
 ]
}

 The dataset includes 720 records from 41 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0228933-210914110416597/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.e95m3s
title: Occurrence Download

description: A dataset containing 4607 species occurrences available in GBIF matching the query:
{
 "and" : [
 "TaxonKey is Aloe arborescens Mill.",
 "HasCoordinate is true",
 "HasGeospatialIssue is false"
 ]
}

 The dataset includes 4607 records from 86 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0001918-230828120925497/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.e6zp7y
title: Occurrence Download

description: A dataset containing 38629 species occurrences available in GBIF matching the query:
{
 "and" : [
 "BasisOfRecord is Fossil",
 "Geometry POLYGON((-175.13992 51.19053,-129.51027 50.53394,-130.49835 55.66829,-142.2187 64.41207,-155.13519 65.43315,-167.56828 63.59165,-175.13992 51.19053))",
 "HasGeospatialIssue is false"
 ]
}

 The dataset includes 38629 records from 41 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0013462-200127171203522/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.wj9myf
title: Occurrence Download

description: A dataset containing 7832 species occurrences available in GBIF matching the query:
{
 "and" : [
 "TaxonKey is Carex ericetorum Pollich",
 "HasGeospatialIssue is false",
 "HasCoordinate is true",
 "Year is greater than or equal to 1990",
 "OccurrenceStatus is Present",
 {
 "not" : {
 "BasisOfRecord" : [
 "is one of (Fossil, Living Specimen)"
 ]
 }
 }
 ]
}

 The dataset includes 7832 records from 162 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0163065-220831081235567/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.2s9hc4
title: Occurrence Download

description: A dataset containing 1071 species occurrences available in GBIF matching the query:
{
 "TaxonKey" : [
 "is one of (Aspidosperma desmanthum Benth., Aspidosperma desmanthum Benth. ex Müll.Arg.)"
 ]
}

 The dataset includes 1071 records from 122 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0001919-230828120925497/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.15468/dl.6kzidi
title: Occurrence Download

description: A dataset containing 9121449 species occurrences available in GBIF matching the query:
{
 "Geometry" : [
 "POLYGON((-118.94678 32.82275,-120.95581 32.70605,-120.43652 25.74316,-120.50684 19.30957,-118.74334 9.52323,-93.00586 12.67383,-92.62793 15.19629,-90.4834 16.63769,-91.53809 17.65723,-94.4209 17.48144,-97.15429 17.38476,-102.92871 21.55957,-104.2998 24.09082,-105.17871 25.32129,-105.56543 25.84863,-107.14746 27.99316,-108.63412 30.56623,-108.97559 31.15723,-111.26074 31.22754,-112.38574 31.96582,-114.77637 32.91504,-117.20215 32.3877,-118.94678 32.82275))"
 ]
}

 The dataset includes 9121449 records from 1517 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0038546-191105090559680/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.3535/a50-97n-blj
title: Diarsia dahlii Hübner, 1813

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/j98-pmq-3f6
title: Orthosia (Orthosia) incerta Hufnagel, 1766

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/7xv-dwr-wyz
title: Lygephila (Lygephila) craccae [Denis & Schiffermüller], 1775

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/bfs-7qn-5gr
title: Nyctegretis lineana Scopoli, 1786

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/evr-jck-zb4
title: Autographa jota (Linnaeus, 1758)

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/dva-0kh-qeb
title: Agriades aquilo Aurivillius

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/sq9-602-hhd
title: Eupsilia transversa Hufnagel, 1766

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/ahy-15k-b35
title: Autographa gamma (Linnaeus, 1758)

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/t12-345-rhe
title: Borkhausenia luridicomella (Herrich-Schäffer, 1855)

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/ncm-kj3-xxm
title: Autographa gamma (Linnaeus, 1758)

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/yxa-mgn-h3a
title: Schrankia costaestrigalis (Stephens, 1834)

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/60v-4tw-7yg
title: Lithophane (Lithophane) consocia Borkhausen, 1792

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/p22-p9t-m4n
title: Brachylomia viminalis Fabricius, 1777

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/dna-mvf-e7f
title: Anaplectoides prasina [Denis & Schiffermüller], 1775

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/dx1-hyx-fqy
title: Celastrina argiolus (Linnaeus, 1758)

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/ynf-k5v-wsj
title: Lygephila (Lygephila) craccae [Denis & Schiffermüller], 1775

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/xlz-6p6-6f8
title: Oeneis jutta Hübner, 1806

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/yjh-450-wzz
title: Agriphila inquinatella [Denis & Schiffermüller], 1775

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/f2j-r79-247
title: Conistra (Dasycampa) erythrocephala ([Denis & Schiffermüller], 1775)

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/hef-br2-aes
title: Aphantopus hyperantus (Linnaeus, 1758)

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/hzd-fn5-1ga
title: Autographa jota (Linnaeus, 1758)

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/015-9mx-kb7
title: Eudonia truncicolella (Stainton, 1849)

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/2ps-j4a-59y
title: Diarsia rubi (Vieweg, 1790)

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/l70-n0b-wdr
title: Aglais urticae (Linnaeus, 1758)

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/wv5-r6f-r3j
title: Anaplectoides prasina [Denis & Schiffermüller], 1775

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/75v-gfq-rxc
title: Boloria Moore, 1900

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/xne-6ct-563
title: Anaplectoides prasina [Denis & Schiffermüller], 1775

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/a8f-rdv-whj
title: Eudonia truncicolella (Stainton, 1849)

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/e51-8ym-bjt
title: Autographa gamma (Linnaeus, 1758)

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/cz7-ga1-d2v
title: Conistra (Dasycampa) erythrocephala ([Denis & Schiffermüller], 1775)

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/llv-aqk-fwc
title: Autographa jota (Linnaeus, 1758)

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/2j6-vqc-phh
title: Scoparia ambigualis Treitschke, 1829

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/qe2-d30-bkm
title: Macdunnoughia (Macdunnoughia) confusa (Stephens, 1850)

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/nnz-327-4kh
title: Agriphila straminella [Denis & Schiffermüller], 1775

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/tyz-jkv-8hw
title: Anaplectoides prasina [Denis & Schiffermüller], 1775

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/xng-ns5-zr5
title: Autographa jota (Linnaeus, 1758)

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/b4t-szx-6tb
title: Oeneis jutta Hübner, 1806

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/l4j-km7-ng6
title: Aglais urticae (Linnaeus, 1758)

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/wlw-4al-a13
title: Lygephila (Lygephila) craccae [Denis & Schiffermüller], 1775

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/yef-5jz-3sx
title: Lygephila (Lygephila) craccae [Denis & Schiffermüller], 1775

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/htz-4dv-1hf
title: Diarsia dahlii Hübner, 1813

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/l6b-nmd-qwx
title: Lithophane (Lithophane) consocia Borkhausen, 1792

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.15468/dl.tdv4xt
title: Occurrence Download

description: A dataset containing 0 species occurrences available in GBIF matching the query:
{
 "and" : [
 "TaxonKey is one of ()",
 "Year is greater than or equal to 2021",
 "Year is less than 2025"
 ]
}

 The dataset includes 0 records from 0 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0035561-251120083545085/datasets/export for details.
DOI: 10.3535/51y-p6h-mc8
title: Eupsilia transversa Hufnagel, 1766

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/mjx-9d7-fwt
title: Lasionycta staudingeri Aurivillius, 1891

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/2pt-pds-bjt
title: Drepana curvatula (Borkhausen, 1790)

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/qm6-ce3-1b6
title: Platytes alpinella Hübner

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.15468/dl.akrpf9
title: Occurrence Download

description: A dataset containing 14 species occurrences available in GBIF matching the query:
{
 "and" : [
 "TaxonKey is Gyptis mackiei",
 "HasCoordinate is true",
 "HasGeospatialIssue is false"
 ]
}

 The dataset includes 14 records from 7 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0035560-251120083545085/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.3535/vn5-msj-9p2
title: Tetheella fluctuosa (Hübner, 1803)

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/b1s-qmz-3e7
title: Xestia (Pachnobia) alpicola Zetterstedt, 1840

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/zvf-ka9-bm2
title: Lasionycta staudingeri Aurivillius, 1891

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/7ss-nk9-qvx
title: Autographa jota (Linnaeus, 1758)

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/jpe-m4a-fkh
title: Oeneis jutta Hübner, 1806

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/6l9-4fj-4ez
title: Gortyna flavago [Denis & Schiffermüller], 1775

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/wmn-ghj-5xc
title: Aglais urticae (Linnaeus, 1758)

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.15468/dl.3h3dv3
title: Occurrence Download

description: A dataset containing 173 species occurrences available in GBIF matching the query:
{
 "and" : [
 "BasisOfRecord is one of (Observation, Machine Observation, Human Observation, Material sample, Material citation, Specimen, Fossil, Living Specimen, Occurrence evidence)",
 "DatasetKey is one of (EOD – eBird Observation Dataset, iNaturalist Research-grade Observations, MVZ Bird Collection (Arctos), Xeno-canto - Bird sounds from around the world, Anymals+plants - Citizen Science Data, Birda - Global Observation Dataset, Observation.org, Nature data from around the World)",
 "Geometry POLYGON((-43.14359 -23.27766,-43.11206 -23.27766,-43.11206 -22.9423,-43.14359 -22.9423,-43.16308 -22.96753,-43.1906 -22.99504,-43.21467 -22.99046,-43.26397 -23.00995,-43.31499 -23.02428,-43.33219 -23.01511,-43.35225 -23.01511,-43.37174 -23.0174,-43.40614 -23.01855,-43.452 -23.03001,-43.47952 -23.02829,-43.49442 -23.03116,-43.52136 -23.04033,-43.52767 -23.04262,-43.54601 -23.05237,-43.57009 -23.07702,-43.58843 -23.23294,-43.14359 -23.27766))",
 "Issue is Coordinate rounded",
 "IucnRedListCategory is one of (EN, VU, NT, LC, DD, NE)",
 "License is one of (CC0 1.0, CC-BY 4.0, CC-BY-NC 4.0, Pending, Incompatible)",
 "Month is one of (January, February, March, April, May, June, July, August, September, October, November, December)",
 "TaxonKey is Aves"
 ]
}

 The dataset includes 173 records from 4 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0035562-251120083545085/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.3535/flx-16t-nph
title: Celastrina argiolus (Linnaeus, 1758)

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/p14-670-zfc
title: Eudonia truncicolella (Stainton, 1849)

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/5dk-whs-za2
title: Macdunnoughia (Macdunnoughia) confusa (Stephens, 1850)

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/7cg-k8s-xsr
title: Arenostola phragmitidis Hübner, 1803

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/226-3s8-q6p
title: Macdunnoughia (Macdunnoughia) confusa (Stephens, 1850)

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/sjw-gly-bga
title: Platytes alpinella Hübner

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/9fx-kwh-rfl
title: Anaplectoides prasina [Denis & Schiffermüller], 1775

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/mza-yak-pc1
title: Boloria Moore, 1900

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/z5a-5g2-s1n
title: Lasionycta staudingeri Aurivillius, 1891

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/84e-6hn-0an
title: Enargia paleacea (Esper, 1788)

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/x8c-jpn-nnk
title: Xestia (Pachnobia) alpicola Zetterstedt, 1840

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/6dr-ymn-qmp
title: Sympistis heliophila Paykull, 1793

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/nym-2y6-1c8
title: Sympistis heliophila Paykull, 1793

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/yr0-axj-nh5
title: Oeneis bore Esper, 1790

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/hay-qqs-m30
title: Oeneis jutta Hübner, 1806

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/mez-wdd-06n
title: Xanthia (Cirrhia) Hübner, 1816

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/4at-gv6-srh
title: Leucania (Leucania) comma Linnaeus, 1761

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/wml-xv8-32a
title: Macdunnoughia (Macdunnoughia) confusa (Stephens, 1850)

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/eng-4bn-m8k
title: Conistra (Conistra) vaccinii (Linnaeus, 1761)

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/qr8-5yp-16c
title: Coscinia cribraria (Linnaeus, 1758)

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.15151/esrf-dc-2303883875
title: EXAFS Data for "Modulator Control of Cation Distribution in Mixed-Metal UiO-66(Zr,Ce) Metal-Organic Frameworks"

description: The cation distribution and the redox activity of the [(CexZr6-x)(OH)4O4]12+ clusters in bimetallic UiO-66(Ce/Zr) MOFs were modified by varying the choice of modulator during synthesis. Extended X-ray absorption spectroscopy (EXAFS) at the Ce and Zr K-edges, in-situ Fourier-transform infra-red (FTIR) spectroscopy, along with density functional theory (DFT) calculations reveal that using benzoic acid as a modulator leads to the preferential formation of the [(cis-Ce2Zr4)(OH)4O4]12+ cluster in UiO-66 (Ce/Zr) with higher Ce incorporation (33% Ce) than formic acid-modulated synthesis, which predominantly contains a [(CeZr5)(OH)4O4]12+ cluster (17% Ce). Analysis of the reaction solution using Ce K-edge EXAFS and Ce LIII-edge X-ray absorption near edge structure (XANES) shows how the formation of isolated Ce(III) in the synthesis solution limits the uptake of Ce(IV) into the UiO-66 structure for both modulators, but the effect is less for the benzoic acid modulator, explaining the enhanced overall incorporation of Ce. The local metal distribution of Ce and Zr in the M6 clusters is found to significantly impact the catalytic activity in the benzyl alcohol oxidation reaction using microwave-assisted heating, with the cis-Ce2Zr4 clusters exhibiting higher redox activity than CeZr5; this is rationalised by the greater possibility of removing oxide ions that bridge a pair of Ce(IV) in the cluster to mediate the catalytic transformation. The results show how the choice of modulator during MOF synthesis can influence local distribution of metal cations, providing a subtle way to fine tune properties beyond the average crystal structure.
DOI: 10.3535/jh3-1j0-vlj
title: Catoptria fulgidella Hübner

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/eng-as6-nyz
title: Apamea (Apamea) sublustris (Esper)

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/f8a-m8b-h7b
title: Evergestis pallidata Hufnagel, 1767

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.
DOI: 10.3535/dm7-hgp-n70
title: Evergestis pallidata Hufnagel, 1767

description: Digital Specimen for the physical specimen hosted at Finnish Museum of Natural History.