DOI: 10.5281/zenodo.7370066
title: Interpolated data on bioavailable strontium in the southern Trans-Urals, version 1 (use updated!)

description: The dataset consists of five KML files which consist of kriging interpolated values (simple kriging, 2500 m x 2500 m grid) of strontium isotopes for the southern Trans-Urals. The data provided can be used to access interpolated background values of bioavailable strontium in the area of interest. Note that a single value is not a good enough predictor and should not be used as a proxy. Always use a mean of 4-6 (or more) nearby values to achieve the best guess. 


Average grid 2500m.kml: this file contains averaged values of all four samples types


Grass grid 2500m.kml: this file contains data interpolated from the grass sample dataset.


Mollusks grid 2500m.kml: this file contains data interpolated from the mollusk dataset.


Soil grid 2500m.kml: this file contains data interpolated from the soil sample dataset.


Water grid 2500m.kml: this file contains data interpolated from the water sample dataset


The interpolated datasets are based upon the actual measured values published as follows:


Epimakhov, Andrey; Kisileva, Daria; Chechushkov, Igor; Ankushev, Maksim; Ankusheva, Polina (2022): Strontium isotope ratios (87Sr/86Sr) analysis from various sources the southern Trans-Urals. PANGAEA, https://doi.pangaea.de/10.1594/PANGAEA.950380


Description of the original dataset of measured strontium isotopic values:


The present dataset contains measurements of bioavailable strontium isotopes (87Sr/86Sr) gathered in the southern Trans-Urals. There are four sample types, such as wormwood (n = 95), leached soil (n = 95), water (n = 93), and freshwater mollusks (n = 74), collected to measure bioavailable strontium isotopes. The analysis of Sr isotopic composition was carried out in the cleanrooms (6 and 7 ISO classes) of the Geoanalitik shared research facilities of the Institute of Geology and Geochemistry, the Ural Branch of the Russian Academy of Sciences (Ekaterinburg). Mollusk shell samples preliminarily cleaned with acetic acid, as well as vegetation samples rinsed with deionized water and ashed, were dissolved by open digestion in concentrated HNO 3 with the addition of H 2 O 2 on a hotplate at 150°C. Water samples were acidified with concentrated nitric acid and filtered. To obtain aqueous leachates, pre-ground soil samples weighing 1 g were taken into polypropylene containers, 10 ml of ultrapure water was added and shaken in for 1 hour, after which they were filtered through membrane cellulose acetate filters with a pore diameter of 0.2 μm. In all samples, the strontium content was determined by ICP-MS (NexION 300S). Then the sample volume corresponding to the Sr content of 600 ng was evaporated on a hotplate at 120°C, and the precipitate was dissolved in 7M HNO 3 . Sample solutions were centrifuged at 6000 rpm, and strontium was chromatographically isolated using SR resin (Triskem). The strontium isotopic composition was measured on a Neptune Plus multicollector mass spectrometer with inductively coupled plasma (MC-ICP-MS). To correct mass bias, a combination of bracketing and internal normalization according to the exponential law 88 Sr/ 86 Sr = 8.375209 was used. The results were additionally bracketed using the NIST SRM 987 strontium carbonate reference material using an average deviation from the reference value of 0.710245 for every two samples bracketed between NIST SRM 987 measurements. The long-term reproducibility of the strontium isotopic analysis was evaluated using repeated measurements of NIST SRM 987 during 2020-2022 and yielded 87 Sr/ 86 Sr = 0.71025, 2SD = 0.00012 (104 measurements in two replicates). The within-laboratory standard uncertainty (2σ) obtained for SRM-987 was ± 0.003 %.