cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.6084/m9.figshare.6007838.v1
title: Finite element simulation of fracture in a restored premolar tooth using high aspect ratio elements

description: Abstract Introduction The term cracked tooth syndrome refers to an incomplete fracture of a vital posterior tooth that involves the dentin and occasionally extends into the pulp. There is a very limited number of publications trying to model dentin crack growth using numerical techniques. Therefore, it is essential to numerically model this phenomenon in order to improve the clinical procedures. Methods A 2D finite element model is proposed to simulate crack initiation and propagation in a restored premolar tooth. The geometric model was based on computed tomography data. A special finite element technique, named mesh fragmentation technique, is used to model and analyze the behavior of the tooth. This technique was used to model cracks in quasi-brittle materials based on the use of interface solid finite elements with high aspects ratio. A tension damage constitutive relation between stresses and strains consistent with the continuous strong discontinuity approach is used to describe crack formation and propagation. Results The main aspects of modeling technique and procedures are explained in detail as well as the whole results, including both elastic and fracture analyses of the restored tooth. Conclusion The results of the current fracture analysis show that, under various loading conditions, there is no crack initiation in the restored tooth under typical loading magnitude. However, in the case of tooth with a pre-existing crack, which can be aroused during the restoration process, a crack propagation was observed, while they did not reach a critical fracture state.
DOI: 10.6084/m9.figshare.6007835
title: Development of a Novel and Simple Electroanalytical Procedure for the Determination of Copper in Biofuel Employing a Sensor Based on Vulcan Functionalized with Carbazone

description: A novel and simple electroanalytical method for the determination of Cu2+ in biodiesel samples by stripping voltammetric analysis was developed. The method employs a carbon paste electrode (CPE) modified with Vulcan carbon, previouly functionalized with carbazone (CBZ). The CPE/Vulcan-CBZ sensor promoted a significant increase in the analytical signal obtained from copper as compared to unmodified CPE, and the CPE modified with Vulcan carbon (CPE/ Vulcan). Vulcan-CBZ, Vulcan and CBZ materials were characterized by Fourier transform infrared spectroscopy (FTIR) technique. The electrochemical behavior of the sensor was evaluated using cyclic voltammetry (CV) and square-wave anodic stripping voltammetric (SWASV) techniques. The CPE/Vulcan-CBZ modified electrode showed excellent response and was able to detect Cu2+ at nanomolar levels. The electrochemical method is based on preconcentration of Cu2+ ions on the CPE/Vulcan-CBZ at 0.35 V vs. Ag/AgCl(sat) in 0.2 mol L-1 ammonium sulfate solution ((NH4)2SO4), pH 3.5, during 120 s, followed by subsequent chemical stripping. The analytical signal showed a linear response for Cu2+ concentrations in the range from 6 to 190 nmol L-1 (r = 0.998), with a detection limit of 1.2 nmol L-1. The sensor was successfully applied for the determination of Cu2+ in biodiesel and the average recovery varied between 97.0 and 102.8% for the soybean biodiesel samples and between 109.6 and 111.0% for the babassu biodiesel samples showing a good accuracy for the proposed method.
DOI: 10.6084/m9.figshare.6007835.v1
title: Development of a Novel and Simple Electroanalytical Procedure for the Determination of Copper in Biofuel Employing a Sensor Based on Vulcan Functionalized with Carbazone

description: A novel and simple electroanalytical method for the determination of Cu2+ in biodiesel samples by stripping voltammetric analysis was developed. The method employs a carbon paste electrode (CPE) modified with Vulcan carbon, previouly functionalized with carbazone (CBZ). The CPE/Vulcan-CBZ sensor promoted a significant increase in the analytical signal obtained from copper as compared to unmodified CPE, and the CPE modified with Vulcan carbon (CPE/ Vulcan). Vulcan-CBZ, Vulcan and CBZ materials were characterized by Fourier transform infrared spectroscopy (FTIR) technique. The electrochemical behavior of the sensor was evaluated using cyclic voltammetry (CV) and square-wave anodic stripping voltammetric (SWASV) techniques. The CPE/Vulcan-CBZ modified electrode showed excellent response and was able to detect Cu2+ at nanomolar levels. The electrochemical method is based on preconcentration of Cu2+ ions on the CPE/Vulcan-CBZ at 0.35 V vs. Ag/AgCl(sat) in 0.2 mol L-1 ammonium sulfate solution ((NH4)2SO4), pH 3.5, during 120 s, followed by subsequent chemical stripping. The analytical signal showed a linear response for Cu2+ concentrations in the range from 6 to 190 nmol L-1 (r = 0.998), with a detection limit of 1.2 nmol L-1. The sensor was successfully applied for the determination of Cu2+ in biodiesel and the average recovery varied between 97.0 and 102.8% for the soybean biodiesel samples and between 109.6 and 111.0% for the babassu biodiesel samples showing a good accuracy for the proposed method.
DOI: 10.6084/m9.figshare.6007832
title: Can intra-radicular cleaning protocols increase the retention of fiberglass posts? A systematic review

description: Abstract The presence of residues within the root canal after post-space preparation can influence the bond strength between resin cement and root dentin when using fiberglass posts (FGPs). Currently, there is no consensus in the literature regarding what is the best solution for the removal of debris after post-space preparation. This systematic review involved “in vitro” studies to investigate if cleaning methods of the root canal after post-space preparation can increase the retention of FGPs evaluated by the push-out test. Searches were carried out in PubMed (MEDLINE) and Scopus databases up to July2017. English language studies published from 2007 to July 2017 were selected. 475 studies were found, and 9 were included in this review. Information from the 9 studies were collected regarding the number of samples, storage method after extraction, root canal preparation, method of post-space preparation, endodontic sealer, resin cement, cleaning methods after post-space and presence of irrigant activation. Five studies presented the best results for the association of sodium hypochlorite (NaOCl) and ethylenediamine tetra-acetic acid (EDTA), while in the other 4 studies, the solutions that showed improved retention of FGPs were photon-induced photoacoustic streaming (PIPS), Qmix, Sikko and EDTA. The results showed heterogeneity in all comparisons due to a high variety of information about cleaning methods, different concentrations, application time, type of adhesive system and resin cements used. In conclusion, this review suggests that the use of NaOCl/EDTA results in the retention of FGPs and may thus be recommended as a post-space cleaning method influencing the luting procedure.
DOI: 10.6084/m9.figshare.6007832.v1
title: Can intra-radicular cleaning protocols increase the retention of fiberglass posts? A systematic review

description: Abstract The presence of residues within the root canal after post-space preparation can influence the bond strength between resin cement and root dentin when using fiberglass posts (FGPs). Currently, there is no consensus in the literature regarding what is the best solution for the removal of debris after post-space preparation. This systematic review involved “in vitro” studies to investigate if cleaning methods of the root canal after post-space preparation can increase the retention of FGPs evaluated by the push-out test. Searches were carried out in PubMed (MEDLINE) and Scopus databases up to July2017. English language studies published from 2007 to July 2017 were selected. 475 studies were found, and 9 were included in this review. Information from the 9 studies were collected regarding the number of samples, storage method after extraction, root canal preparation, method of post-space preparation, endodontic sealer, resin cement, cleaning methods after post-space and presence of irrigant activation. Five studies presented the best results for the association of sodium hypochlorite (NaOCl) and ethylenediamine tetra-acetic acid (EDTA), while in the other 4 studies, the solutions that showed improved retention of FGPs were photon-induced photoacoustic streaming (PIPS), Qmix, Sikko and EDTA. The results showed heterogeneity in all comparisons due to a high variety of information about cleaning methods, different concentrations, application time, type of adhesive system and resin cements used. In conclusion, this review suggests that the use of NaOCl/EDTA results in the retention of FGPs and may thus be recommended as a post-space cleaning method influencing the luting procedure.
DOI: 10.6084/m9.figshare.6007826
title: Coping strategies for domestic violence against pregnant female adolescents: integrative review

description: ABSTRACT Objective: To investigate and analyze in the scientific literature coping strategies for domestic violence against pregnant female adolescents. Method: This is an integrative literature review, conducted from July to August 2017 on LILACS, SciELO and PubMed, using the descriptors and the MeSH terms: confrontation, violence, adolescent, pregnant women, prenatal care. Result: The sample comprised 9 articles that were organized and characterized according to year, country of study and coping strategy used. The main forms of coping involved the active search for cases and the primary care approach with all family members. Conclusion: Individualized prenatal care, the change in professional training and networking activities were pointed out as important components of the strategies for coping with violence against pregnant adolescents.
DOI: 10.6084/m9.figshare.6007826.v1
title: Coping strategies for domestic violence against pregnant female adolescents: integrative review

description: ABSTRACT Objective: To investigate and analyze in the scientific literature coping strategies for domestic violence against pregnant female adolescents. Method: This is an integrative literature review, conducted from July to August 2017 on LILACS, SciELO and PubMed, using the descriptors and the MeSH terms: confrontation, violence, adolescent, pregnant women, prenatal care. Result: The sample comprised 9 articles that were organized and characterized according to year, country of study and coping strategy used. The main forms of coping involved the active search for cases and the primary care approach with all family members. Conclusion: Individualized prenatal care, the change in professional training and networking activities were pointed out as important components of the strategies for coping with violence against pregnant adolescents.
DOI: 10.6084/m9.figshare.6007820
title: Assessment of the implementation of a Warehouse Management System in a multinational company of industrial gears and drives

description: Abstract The companies may gain competitive advantage when they have an efficient logistics. In this aspect, the use of tools for the management and control of material handling and storage are essential for a fast and efficient logistics. The Warehouse Management System (WMS) is one available alternative for the automation of the logistic operations. In this context, this study has the central objective of analyzing the results of the implementation of a WMS system in a manufacturer of mechanical parts, in terms of operational efficiency and quality. The results of this study are focused on the satisfaction of the workers involved with the logistic operations, evaluated by means of interviews, and on the operational results, evaluated by means of a comparative analysis of the logistic performance indicators at two different times, the time before and the time after the implementation of the WMS. The analysis of the performance indicators demonstrated that the logistic operations have become more agile, what has reflected on financial gains. In addition, the workers involved with the change have reported a decrease in the functional conflicts and an increase in the reliability and credibility of information available to internal and external customers.
DOI: 10.6084/m9.figshare.6007820.v1
title: Assessment of the implementation of a Warehouse Management System in a multinational company of industrial gears and drives

description: Abstract The companies may gain competitive advantage when they have an efficient logistics. In this aspect, the use of tools for the management and control of material handling and storage are essential for a fast and efficient logistics. The Warehouse Management System (WMS) is one available alternative for the automation of the logistic operations. In this context, this study has the central objective of analyzing the results of the implementation of a WMS system in a manufacturer of mechanical parts, in terms of operational efficiency and quality. The results of this study are focused on the satisfaction of the workers involved with the logistic operations, evaluated by means of interviews, and on the operational results, evaluated by means of a comparative analysis of the logistic performance indicators at two different times, the time before and the time after the implementation of the WMS. The analysis of the performance indicators demonstrated that the logistic operations have become more agile, what has reflected on financial gains. In addition, the workers involved with the change have reported a decrease in the functional conflicts and an increase in the reliability and credibility of information available to internal and external customers.
DOI: 10.6084/m9.figshare.6007817
title: Qualitative and Quantitative Chemical Investigation of Orthopedic Alloys by Combining Wet Digestion, Spectroanalytical Methods and Direct Solid Analysis

description: In this study, two laser-based techniques, laser-induced breakdown spectroscopy (LIBS) and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) were used for analytical signal evaluation of Ti, Al, and V and investigation of possible harmful elements eventually present as minor elements in Ti alloys. Due to the lack of certified reference materials, samples were also analyzed by wavelength dispersive X-ray fluorescence (WDXRF) and inductively coupled plasma optical emission spectrometry (ICP OES) after microwave-assisted digestion. To maximize the efficiency of LIBS and LA-ICP-MS, operational conditions were adjusted aiming to find optimal analytical performance. LIBS showed several Ti emission lines and few signals for Al and V. LA-ICP-MS was able to detect all three major constituents. For quantitative analysis, the correlation of intensity signals from LIBS analysis with reference values obtained by ICP OES was not successful, showing that there are still difficulties for quantification using solid samples. Measurements using ICP OES showed that additionally to major constituents, only Fe was present in concentrations around 0.2%. Analysis by WDXRF confirmed the presence of Fe. Results using both methods, i.e., ICP OES and WDXRF, were in good agreement.
DOI: 10.6084/m9.figshare.6007817.v1
title: Qualitative and Quantitative Chemical Investigation of Orthopedic Alloys by Combining Wet Digestion, Spectroanalytical Methods and Direct Solid Analysis

description: In this study, two laser-based techniques, laser-induced breakdown spectroscopy (LIBS) and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) were used for analytical signal evaluation of Ti, Al, and V and investigation of possible harmful elements eventually present as minor elements in Ti alloys. Due to the lack of certified reference materials, samples were also analyzed by wavelength dispersive X-ray fluorescence (WDXRF) and inductively coupled plasma optical emission spectrometry (ICP OES) after microwave-assisted digestion. To maximize the efficiency of LIBS and LA-ICP-MS, operational conditions were adjusted aiming to find optimal analytical performance. LIBS showed several Ti emission lines and few signals for Al and V. LA-ICP-MS was able to detect all three major constituents. For quantitative analysis, the correlation of intensity signals from LIBS analysis with reference values obtained by ICP OES was not successful, showing that there are still difficulties for quantification using solid samples. Measurements using ICP OES showed that additionally to major constituents, only Fe was present in concentrations around 0.2%. Analysis by WDXRF confirmed the presence of Fe. Results using both methods, i.e., ICP OES and WDXRF, were in good agreement.
DOI: 10.6084/m9.figshare.6007811
title: Remembering the past – studies on evolution done by the genetics group at Universidade Federal do Rio Grande do Sul (UFRGS)

description: Abstract After a brief introduction about the factors that are involved in science development, and world and Brazilian evolutionary genetics, the studies developed in Porto Alegre in this area were reviewed. Four periods in the development of this group were distinguished: (a) Origins and first expansion (1949-1961); (b) Second expansion (1962-1988); (c) Third expansion (1989-2001); and (d) The last 15 years (2002-present). The international Porto Alegre Biological Evolution Workshops (PABEWs), with five biannual events from 2007 o 2015, were also mentioned. The final message stressed the importance of the maintenance of this and other Brazilian groups of research through adequate finance and recognition.
DOI: 10.6084/m9.figshare.6007811.v1
title: Remembering the past – studies on evolution done by the genetics group at Universidade Federal do Rio Grande do Sul (UFRGS)

description: Abstract After a brief introduction about the factors that are involved in science development, and world and Brazilian evolutionary genetics, the studies developed in Porto Alegre in this area were reviewed. Four periods in the development of this group were distinguished: (a) Origins and first expansion (1949-1961); (b) Second expansion (1962-1988); (c) Third expansion (1989-2001); and (d) The last 15 years (2002-present). The international Porto Alegre Biological Evolution Workshops (PABEWs), with five biannual events from 2007 o 2015, were also mentioned. The final message stressed the importance of the maintenance of this and other Brazilian groups of research through adequate finance and recognition.
DOI: 10.6084/m9.figshare.6007808
title: DNA fingerprinting based on SSR amplification profiles for Piper species identification (Piperaceae)

description: ABSTRACT DNA fingerprinting based on SSR amplification profiles was applied to native species of Piper from the Atlantic Forest to compare the utility of this type of molecular marker with the morphological characters traditionally applied in Piper taxonomy and identification. Fifty-one SSR markers developed for four species of Piper native to Asia and Mesoamerica were applied to 16 species, together with 63 morphological characters, for species characterization. Molecular and morphological data were analysed by cluster analysis, followed by a cluster sharpness test and the construction of a heat map to visualize the association of characters with species groups. A multivariate regression tree determined the number of loci needed for species identification. Forty-five primers were transferable to at least four species. Molecular data were more efficient in detecting sharp groups than morphological data. Species groups delimited by a set of shared morphological characters were differentiated based on molecular data. The sixteen studied species could be separated by nine primers, demonstrating the cross-species transferability of SSR markers and the usefulness of DNA fingerprinting for both the delimitation and the identification of species of Piper.
DOI: 10.6084/m9.figshare.6007808.v1
title: DNA fingerprinting based on SSR amplification profiles for Piper species identification (Piperaceae)

description: ABSTRACT DNA fingerprinting based on SSR amplification profiles was applied to native species of Piper from the Atlantic Forest to compare the utility of this type of molecular marker with the morphological characters traditionally applied in Piper taxonomy and identification. Fifty-one SSR markers developed for four species of Piper native to Asia and Mesoamerica were applied to 16 species, together with 63 morphological characters, for species characterization. Molecular and morphological data were analysed by cluster analysis, followed by a cluster sharpness test and the construction of a heat map to visualize the association of characters with species groups. A multivariate regression tree determined the number of loci needed for species identification. Forty-five primers were transferable to at least four species. Molecular data were more efficient in detecting sharp groups than morphological data. Species groups delimited by a set of shared morphological characters were differentiated based on molecular data. The sixteen studied species could be separated by nine primers, demonstrating the cross-species transferability of SSR markers and the usefulness of DNA fingerprinting for both the delimitation and the identification of species of Piper.
DOI: 10.6084/m9.figshare.6007805
title: Genetic diversity and population structure of Vriesea reitzii (Bromeliaceae), a species from the Southern Brazilian Highlands

description: Abstract The Southern Brazilian Highlands are composed by a mosaic of Mixed Ombrophilous Forest (MOF) and grassland formations, an interesting landscape for the study of population structure. We analyzed the genetic diversity within and among populations of the MOF-endemic bromeliad Vriesea reitzii by genotyping seven nuclear microsatellite loci in 187 individuals from six populations. We characterized levels of genetic diversity and assessed the genetic structure among populations. Vriesea reitzii populations showed high levels of genetic variation (number of alleles 28 - 43, allelic richness 3.589 - 5.531) and moderate levels of genetic differentiation (FST = 0.123, RST = 0.096). The high levels of genetic diversity may be explained by species life-history traits, such as habit and mating system. The moderate structure may be a product of the combination of ancient and contemporary gene flow, resulting from the expansion of the forest in the Holocene, and/or due to facilitated dispersal mediated by the MOF’s mosaic landscape. The genetic results indicated no imminent threat to this bromeliad. However, the species is highly associated with the MOF, putting landscape conservation at the center of conservation efforts for the species’ maintenance.