cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.17188/1298689
title: Materials Data on Ca3Ta2O8 by Materials Project

description: Ca3Ta2O8 crystallizes in the tetragonal I4_1/a space group. The structure is three-dimensional. there are three inequivalent Ca2+ sites. In the first Ca2+ site, Ca2+ is bonded to seven O2- atoms to form distorted CaO7 pentagonal bipyramids that share corners with two equivalent TaO6 octahedra, a cornercorner with one CaO4 tetrahedra, edges with four equivalent TaO6 octahedra, and edges with three equivalent CaO7 pentagonal bipyramids. The corner-sharing octahedra tilt angles range from 33–39°. There are a spread of Ca–O bond distances ranging from 2.22–2.63 Å. In the second Ca2+ site, Ca2+ is bonded in a 8-coordinate geometry to eight O2- atoms. There are four shorter (2.51 Å) and four longer (2.60 Å) Ca–O bond lengths. In the third Ca2+ site, Ca2+ is bonded to four equivalent O2- atoms to form CaO4 tetrahedra that share corners with eight equivalent TaO6 octahedra and corners with four equivalent CaO7 pentagonal bipyramids. The corner-sharing octahedra tilt angles range from 64–65°. All Ca–O bond lengths are 2.18 Å. Ta5+ is bonded to six O2- atoms to form TaO6 octahedra that share corners with two equivalent TaO6 octahedra, corners with two equivalent CaO7 pentagonal bipyramids, corners with two equivalent CaO4 tetrahedra, an edgeedge with one TaO6 octahedra, and edges with four equivalent CaO7 pentagonal bipyramids. The corner-sharing octahedral tilt angles are 37°. There are a spread of Ta–O bond distances ranging from 1.91–2.20 Å. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a 4-coordinate geometry to three Ca2+ and one Ta5+ atom. In the second O2- site, O2- is bonded to two Ca2+ and two equivalent Ta5+ atoms to form a mixture of distorted corner and edge-sharing OCa2Ta2 tetrahedra. In the third O2- site, O2- is bonded in a 4-coordinate geometry to three Ca2+ and one Ta5+ atom. In the fourth O2- site, O2- is bonded in a 4-coordinate geometry to two equivalent Ca2+ and two equivalent Ta5+ atoms.
DOI: 10.17188/1298690
title: Materials Data on Sr4Ta2O9 by Materials Project

description: Sr4Ta2O9 is Ilmenite-like structured and crystallizes in the trigonal P-3c1 space group. The structure is three-dimensional. there are two inequivalent Sr2+ sites. In the first Sr2+ site, Sr2+ is bonded to six equivalent O2- atoms to form distorted SrO6 octahedra that share corners with six equivalent TaO6 octahedra, corners with three equivalent SrO6 pentagonal pyramids, edges with three equivalent SrO6 octahedra, and a faceface with one SrO6 pentagonal pyramid. The corner-sharing octahedra tilt angles range from 39–57°. There are three shorter (2.50 Å) and three longer (2.70 Å) Sr–O bond lengths. In the second Sr2+ site, Sr2+ is bonded to six O2- atoms to form distorted SrO6 pentagonal pyramids that share corners with three equivalent SrO6 octahedra, corners with three equivalent TaO6 octahedra, corners with three equivalent SrO6 pentagonal pyramids, edges with three equivalent TaO6 octahedra, and a faceface with one SrO6 octahedra. The corner-sharing octahedra tilt angles range from 48–62°. There are three shorter (2.41 Å) and three longer (2.55 Å) Sr–O bond lengths. Ta5+ is bonded to six O2- atoms to form distorted TaO6 octahedra that share corners with six equivalent SrO6 octahedra, corners with three equivalent SrO6 pentagonal pyramids, edges with three equivalent SrO6 pentagonal pyramids, and a faceface with one TaO6 octahedra. The corner-sharing octahedra tilt angles range from 39–57°. There are three shorter (1.94 Å) and three longer (2.14 Å) Ta–O bond lengths. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded to two equivalent Sr2+ and two equivalent Ta5+ atoms to form a mixture of distorted corner and edge-sharing OSr2Ta2 trigonal pyramids. In the second O2- site, O2- is bonded in a 4-coordinate geometry to three Sr2+ and one Ta5+ atom.
DOI: 10.17188/1298692
title: Materials Data on LiCuPO4 by Materials Project

description: LiCuPO4 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. Li1+ is bonded in a 3-coordinate geometry to three O2- atoms. There are a spread of Li–O bond distances ranging from 1.89–2.02 Å. Cu2+ is bonded in a square co-planar geometry to four O2- atoms. There are a spread of Cu–O bond distances ranging from 1.94–2.00 Å. P5+ is bonded in a tetrahedral geometry to four O2- atoms. There are a spread of P–O bond distances ranging from 1.51–1.61 Å. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a 3-coordinate geometry to two equivalent Cu2+ and one P5+ atom. In the second O2- site, O2- is bonded in a bent 120 degrees geometry to one Cu2+ and one P5+ atom. In the third O2- site, O2- is bonded in a trigonal planar geometry to one Li1+, one Cu2+, and one P5+ atom. In the fourth O2- site, O2- is bonded in a distorted T-shaped geometry to two equivalent Li1+ and one P5+ atom.
DOI: 10.17188/1298693
title: Materials Data on LiCuPO4 by Materials Project

description: LiCuPO4 crystallizes in the orthorhombic Pbca space group. The structure is three-dimensional. Li1+ is bonded to six O2- atoms to form distorted LiO6 pentagonal pyramids that share corners with four equivalent LiO6 pentagonal pyramids, corners with two equivalent PO4 tetrahedra, corners with two equivalent CuO5 trigonal bipyramids, edges with two equivalent LiO6 pentagonal pyramids, edges with two equivalent PO4 tetrahedra, and an edgeedge with one CuO5 trigonal bipyramid. There are a spread of Li–O bond distances ranging from 2.07–2.45 Å. Cu2+ is bonded to five O2- atoms to form distorted CuO5 trigonal bipyramids that share corners with two equivalent LiO6 pentagonal pyramids, corners with five equivalent PO4 tetrahedra, corners with two equivalent CuO5 trigonal bipyramids, an edgeedge with one LiO6 pentagonal pyramid, and an edgeedge with one CuO5 trigonal bipyramid. There are a spread of Cu–O bond distances ranging from 1.95–2.25 Å. P5+ is bonded to four O2- atoms to form PO4 tetrahedra that share corners with two equivalent LiO6 pentagonal pyramids, corners with five equivalent CuO5 trigonal bipyramids, and edges with two equivalent LiO6 pentagonal pyramids. There are a spread of P–O bond distances ranging from 1.52–1.59 Å. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a 3-coordinate geometry to two equivalent Cu2+ and one P5+ atom. In the second O2- site, O2- is bonded in a 4-coordinate geometry to three equivalent Li1+ and one P5+ atom. In the third O2- site, O2- is bonded in a 4-coordinate geometry to two equivalent Li1+, one Cu2+, and one P5+ atom. In the fourth O2- site, O2- is bonded to one Li1+, two equivalent Cu2+, and one P5+ atom to form distorted corner-sharing OLiCu2P tetrahedra.
DOI: 10.17188/1298694
title: Materials Data on Yb2TeO2 by Materials Project

description: Yb2TeO2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Yb3+ is bonded in a 4-coordinate geometry to four equivalent Te2- and four equivalent O2- atoms. All Yb–Te bond lengths are 3.69 Å. All Yb–O bond lengths are 2.21 Å. Te2- is bonded in a 8-coordinate geometry to eight equivalent Yb3+ atoms. O2- is bonded to four equivalent Yb3+ atoms to form a mixture of edge and corner-sharing OYb4 tetrahedra.
DOI: 10.17188/1298695
title: Materials Data on LiCuPO4 by Materials Project

description: LiCuPO4 crystallizes in the monoclinic P2_1 space group. The structure is three-dimensional. there are two inequivalent Li1+ sites. In the first Li1+ site, Li1+ is bonded in a distorted T-shaped geometry to three O2- atoms. There are one shorter (1.99 Å) and two longer (2.01 Å) Li–O bond lengths. In the second Li1+ site, Li1+ is bonded in a 3-coordinate geometry to four O2- atoms. There are a spread of Li–O bond distances ranging from 1.88–2.64 Å. There are two inequivalent Cu2+ sites. In the first Cu2+ site, Cu2+ is bonded to five O2- atoms to form distorted CuO5 trigonal bipyramids that share corners with three PO4 tetrahedra and an edgeedge with one PO4 tetrahedra. There are a spread of Cu–O bond distances ranging from 1.93–2.64 Å. In the second Cu2+ site, Cu2+ is bonded in a see-saw-like geometry to four O2- atoms. There are a spread of Cu–O bond distances ranging from 1.93–2.01 Å. There are two inequivalent P5+ sites. In the first P5+ site, P5+ is bonded to four O2- atoms to form PO4 tetrahedra that share corners with two equivalent CuO5 trigonal bipyramids and an edgeedge with one CuO5 trigonal bipyramid. There are a spread of P–O bond distances ranging from 1.53–1.60 Å. In the second P5+ site, P5+ is bonded to four O2- atoms to form PO4 tetrahedra that share a cornercorner with one CuO5 trigonal bipyramid. There are a spread of P–O bond distances ranging from 1.55–1.57 Å. There are eight inequivalent O2- sites. In the first O2- site, O2- is bonded in a trigonal non-coplanar geometry to one Li1+, one Cu2+, and one P5+ atom. In the second O2- site, O2- is bonded in a 3-coordinate geometry to two Li1+, one Cu2+, and one P5+ atom. In the third O2- site, O2- is bonded in an L-shaped geometry to one Cu2+ and one P5+ atom. In the fourth O2- site, O2- is bonded in a 3-coordinate geometry to two Cu2+ and one P5+ atom. In the fifth O2- site, O2- is bonded in a trigonal planar geometry to one Li1+, one Cu2+, and one P5+ atom. In the sixth O2- site, O2- is bonded in a 3-coordinate geometry to one Li1+, one Cu2+, and one P5+ atom. In the seventh O2- site, O2- is bonded in a distorted T-shaped geometry to one Li1+, one Cu2+, and one P5+ atom. In the eighth O2- site, O2- is bonded in a 2-coordinate geometry to one Li1+, one Cu2+, and one P5+ atom.
DOI: 10.17188/1298696
title: Materials Data on Ca5Ta4O15 by Materials Project

description: Ca5Ta4O15 crystallizes in the trigonal P-3m1 space group. The structure is three-dimensional. there are three inequivalent Ca2+ sites. In the first Ca2+ site, Ca2+ is bonded in a 9-coordinate geometry to nine equivalent O2- atoms. There are three shorter (2.32 Å) and six longer (2.92 Å) Ca–O bond lengths. In the second Ca2+ site, Ca2+ is bonded in a 9-coordinate geometry to nine O2- atoms. There are three shorter (2.37 Å) and six longer (2.87 Å) Ca–O bond lengths. In the third Ca2+ site, Ca2+ is bonded to twelve O2- atoms to form CaO12 cuboctahedra that share corners with six equivalent CaO12 cuboctahedra and faces with eight TaO6 octahedra. There are six shorter (2.72 Å) and six longer (2.82 Å) Ca–O bond lengths. There are two inequivalent Ta5+ sites. In the first Ta5+ site, Ta5+ is bonded to six O2- atoms to form TaO6 octahedra that share corners with six TaO6 octahedra and faces with three equivalent CaO12 cuboctahedra. The corner-sharing octahedra tilt angles range from 0–10°. There is three shorter (1.96 Å) and three longer (2.02 Å) Ta–O bond length. In the second Ta5+ site, Ta5+ is bonded to six O2- atoms to form TaO6 octahedra that share corners with three equivalent TaO6 octahedra and a faceface with one CaO12 cuboctahedra. The corner-sharing octahedral tilt angles are 10°. There are three shorter (1.90 Å) and three longer (2.12 Å) Ta–O bond lengths. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a 3-coordinate geometry to four Ca2+ and one Ta5+ atom. In the second O2- site, O2- is bonded in a distorted linear geometry to two equivalent Ca2+ and two equivalent Ta5+ atoms. In the third O2- site, O2- is bonded in a 2-coordinate geometry to three Ca2+ and two Ta5+ atoms.
DOI: 10.17188/1298697
title: Materials Data on Sr4Ta2O9 by Materials Project

description: Sr4Ta2O9 crystallizes in the orthorhombic Pbcn space group. The structure is three-dimensional. there are two inequivalent Sr2+ sites. In the first Sr2+ site, Sr2+ is bonded to six O2- atoms to form distorted SrO6 pentagonal pyramids that share corners with three equivalent SrO6 octahedra, corners with three equivalent TaO6 octahedra, a cornercorner with one SrO6 pentagonal pyramid, edges with three equivalent TaO6 octahedra, edges with two equivalent SrO6 pentagonal pyramids, and a faceface with one SrO6 octahedra. The corner-sharing octahedra tilt angles range from 49–57°. There are a spread of Sr–O bond distances ranging from 2.37–2.69 Å. In the second Sr2+ site, Sr2+ is bonded to six O2- atoms to form distorted SrO6 octahedra that share corners with six equivalent TaO6 octahedra, corners with three equivalent SrO6 pentagonal pyramids, edges with three equivalent SrO6 octahedra, and a faceface with one SrO6 pentagonal pyramid. The corner-sharing octahedra tilt angles range from 40–55°. There are a spread of Sr–O bond distances ranging from 2.45–2.80 Å. Ta5+ is bonded to six O2- atoms to form distorted TaO6 octahedra that share corners with six equivalent SrO6 octahedra, corners with three equivalent SrO6 pentagonal pyramids, edges with three equivalent SrO6 pentagonal pyramids, and a faceface with one TaO6 octahedra. The corner-sharing octahedra tilt angles range from 40–55°. There are a spread of Ta–O bond distances ranging from 1.91–2.18 Å. There are five inequivalent O2- sites. In the first O2- site, O2- is bonded to two equivalent Sr2+ and two equivalent Ta5+ atoms to form a mixture of distorted edge and corner-sharing OSr2Ta2 tetrahedra. In the second O2- site, O2- is bonded to two equivalent Sr2+ and two equivalent Ta5+ atoms to form a mixture of distorted edge and corner-sharing OSr2Ta2 trigonal pyramids. In the third O2- site, O2- is bonded in a 3-coordinate geometry to two equivalent Sr2+ and one Ta5+ atom. In the fourth O2- site, O2- is bonded in a 4-coordinate geometry to three Sr2+ and one Ta5+ atom. In the fifth O2- site, O2- is bonded in a 1-coordinate geometry to four Sr2+ and one Ta5+ atom.
DOI: 10.17188/1298698
title: Materials Data on Dy2SeO2 by Materials Project

description: Dy2O2Se crystallizes in the trigonal P-3m1 space group. The structure is three-dimensional. Dy3+ is bonded in a 4-coordinate geometry to three equivalent Se2- and four equivalent O2- atoms. All Dy–Se bond lengths are 2.98 Å. All Dy–O bond lengths are 2.29 Å. Se2- is bonded to six equivalent Dy3+ atoms to form distorted SeDy6 octahedra that share corners with twelve equivalent ODy4 tetrahedra, edges with six equivalent SeDy6 octahedra, and edges with six equivalent ODy4 tetrahedra. O2- is bonded to four equivalent Dy3+ atoms to form ODy4 tetrahedra that share corners with six equivalent SeDy6 octahedra, corners with six equivalent ODy4 tetrahedra, edges with three equivalent SeDy6 octahedra, and edges with three equivalent ODy4 tetrahedra. The corner-sharing octahedra tilt angles range from 27–48°.
DOI: 10.17188/1298699
title: Materials Data on Ho3ReO8 by Materials Project

description: Ho3ReO8 crystallizes in the monoclinic P2_1/m space group. The structure is three-dimensional. there are three inequivalent Ho3+ sites. In the first Ho3+ site, Ho3+ is bonded to seven O2- atoms to form distorted HoO7 pentagonal bipyramids that share corners with three equivalent ReO6 octahedra, corners with three equivalent HoO7 pentagonal bipyramids, an edgeedge with one ReO6 octahedra, and a faceface with one HoO7 pentagonal bipyramid. The corner-sharing octahedra tilt angles range from 49–60°. There are a spread of Ho–O bond distances ranging from 2.24–2.41 Å. In the second Ho3+ site, Ho3+ is bonded in a 6-coordinate geometry to six O2- atoms. There are a spread of Ho–O bond distances ranging from 2.36–2.44 Å. In the third Ho3+ site, Ho3+ is bonded to seven O2- atoms to form distorted HoO7 pentagonal bipyramids that share corners with three equivalent ReO6 octahedra, corners with three equivalent HoO7 pentagonal bipyramids, an edgeedge with one ReO6 octahedra, and a faceface with one HoO7 pentagonal bipyramid. The corner-sharing octahedra tilt angles range from 46–58°. There are a spread of Ho–O bond distances ranging from 2.24–2.42 Å. Re7+ is bonded to six O2- atoms to form ReO6 octahedra that share corners with six HoO7 pentagonal bipyramids and edges with two HoO7 pentagonal bipyramids. There are a spread of Re–O bond distances ranging from 1.84–1.95 Å. There are six inequivalent O2- sites. In the first O2- site, O2- is bonded in a 3-coordinate geometry to two Ho3+ and one Re7+ atom. In the second O2- site, O2- is bonded in a 3-coordinate geometry to two Ho3+ and one Re7+ atom. In the third O2- site, O2- is bonded in a 1-coordinate geometry to two Ho3+ and one Re7+ atom. In the fourth O2- site, O2- is bonded in a 3-coordinate geometry to two Ho3+ and one Re7+ atom. In the fifth O2- site, O2- is bonded to four Ho3+ atoms to form a mixture of distorted corner and edge-sharing OHo4 tetrahedra. In the sixth O2- site, O2- is bonded in a 3-coordinate geometry to two Ho3+ and one Re7+ atom.
DOI: 10.17188/1298700
title: Materials Data on Li2TiS2O by Materials Project

description: Li2TiS2O crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. there are two inequivalent Li1+ sites. In the first Li1+ site, Li1+ is bonded in a 6-coordinate geometry to five S2- and one O2- atom. There are a spread of Li–S bond distances ranging from 2.60–2.95 Å. The Li–O bond length is 2.07 Å. In the second Li1+ site, Li1+ is bonded to five S2- and one O2- atom to form LiS5O octahedra that share corners with two equivalent LiS5O octahedra, corners with three equivalent TiS2O2 tetrahedra, edges with three equivalent LiS5O octahedra, and edges with two equivalent TiS2O2 tetrahedra. The corner-sharing octahedral tilt angles are 6°. There are a spread of Li–S bond distances ranging from 2.55–2.82 Å. The Li–O bond length is 2.69 Å. Ti4+ is bonded to two S2- and two equivalent O2- atoms to form TiS2O2 tetrahedra that share corners with three equivalent LiS5O octahedra, corners with two equivalent TiS2O2 tetrahedra, and edges with two equivalent LiS5O octahedra. The corner-sharing octahedra tilt angles range from 23–78°. Both Ti–S bond lengths are 2.23 Å. There is one shorter (1.86 Å) and one longer (1.87 Å) Ti–O bond length. There are two inequivalent S2- sites. In the first S2- site, S2- is bonded to five Li1+ and one Ti4+ atom to form distorted SLi5Ti octahedra that share corners with five SLi5Ti octahedra, corners with three equivalent OLi2Ti2 trigonal pyramids, edges with eight SLi5Ti octahedra, and edges with two equivalent OLi2Ti2 trigonal pyramids. The corner-sharing octahedra tilt angles range from 4–61°. In the second S2- site, S2- is bonded to five Li1+ and one Ti4+ atom to form distorted SLi5Ti octahedra that share corners with five SLi5Ti octahedra, corners with three equivalent OLi2Ti2 trigonal pyramids, edges with eight SLi5Ti octahedra, and edges with two equivalent OLi2Ti2 trigonal pyramids. The corner-sharing octahedra tilt angles range from 5–61°. O2- is bonded to two Li1+ and two equivalent Ti4+ atoms to form distorted OLi2Ti2 trigonal pyramids that share corners with six SLi5Ti octahedra, corners with two equivalent OLi2Ti2 trigonal pyramids, and edges with four SLi5Ti octahedra. The corner-sharing octahedra tilt angles range from 15–83°.
DOI: 10.17188/1298702
title: Materials Data on LiCuPO4 by Materials Project

description: LiCuPO4 crystallizes in the orthorhombic Pna2_1 space group. The structure is three-dimensional. Li1+ is bonded in a 4-coordinate geometry to four O2- atoms. There are a spread of Li–O bond distances ranging from 1.92–2.44 Å. Cu2+ is bonded to five O2- atoms to form CuO5 trigonal bipyramids that share corners with three equivalent PO4 tetrahedra, corners with two equivalent CuO5 trigonal bipyramids, and an edgeedge with one PO4 tetrahedra. There are a spread of Cu–O bond distances ranging from 1.97–2.17 Å. P5+ is bonded to four O2- atoms to form PO4 tetrahedra that share corners with three equivalent CuO5 trigonal bipyramids and an edgeedge with one CuO5 trigonal bipyramid. There are a spread of P–O bond distances ranging from 1.52–1.61 Å. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a 3-coordinate geometry to one Li1+, one Cu2+, and one P5+ atom. In the second O2- site, O2- is bonded in a distorted trigonal non-coplanar geometry to one Li1+, one Cu2+, and one P5+ atom. In the third O2- site, O2- is bonded to one Li1+, two equivalent Cu2+, and one P5+ atom to form distorted corner-sharing OLiCu2P trigonal pyramids. In the fourth O2- site, O2- is bonded in a distorted trigonal planar geometry to one Li1+, one Cu2+, and one P5+ atom.
DOI: 10.17188/1298703
title: Materials Data on Rb8SnO6 by Materials Project

description: Rb8SnO6 crystallizes in the hexagonal P6_3cm space group. The structure is three-dimensional. there are three inequivalent Rb1+ sites. In the first Rb1+ site, Rb1+ is bonded to four O2- atoms to form distorted RbO4 tetrahedra that share corners with two equivalent SnO4 tetrahedra, corners with ten RbO4 tetrahedra, and edges with five RbO4 tetrahedra. There are a spread of Rb–O bond distances ranging from 2.81–3.17 Å. In the second Rb1+ site, Rb1+ is bonded to four O2- atoms to form distorted RbO4 tetrahedra that share corners with fourteen RbO4 tetrahedra, an edgeedge with one SnO4 tetrahedra, and edges with three equivalent RbO4 tetrahedra. There are a spread of Rb–O bond distances ranging from 2.85–2.99 Å. In the third Rb1+ site, Rb1+ is bonded to four O2- atoms to form RbO4 tetrahedra that share corners with three equivalent SnO4 tetrahedra, corners with nine RbO4 tetrahedra, and edges with three equivalent RbO4 tetrahedra. There are three shorter (2.92 Å) and one longer (2.95 Å) Rb–O bond lengths. Sn4+ is bonded to four O2- atoms to form SnO4 tetrahedra that share corners with twelve RbO4 tetrahedra and edges with three equivalent RbO4 tetrahedra. There are three shorter (2.01 Å) and one longer (2.04 Å) Sn–O bond lengths. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded to four Rb1+ and one Sn4+ atom to form distorted ORb4Sn trigonal bipyramids that share corners with two equivalent ORb7 pentagonal bipyramids, corners with six equivalent ORb4Sn trigonal bipyramids, and edges with two equivalent ORb7 pentagonal bipyramids. In the second O2- site, O2- is bonded to seven Rb1+ atoms to form distorted ORb7 pentagonal bipyramids that share corners with three equivalent ORb4Sn trigonal bipyramids, edges with three equivalent ORb7 pentagonal bipyramids, and edges with three equivalent ORb4Sn trigonal bipyramids. In the third O2- site, O2- is bonded in a 1-coordinate geometry to six Rb1+ and one Sn4+ atom.
DOI: 10.17188/1298704
title: Materials Data on AgH8O5 by Materials Project

description: Ag(H3O2)2H2O crystallizes in the orthorhombic P2_12_12_1 space group. The structure is one-dimensional and consists of four water molecules and two Ag(H3O2)2 ribbons oriented in the (1, 0, 0) direction. In each Ag(H3O2)2 ribbon, Ag2+ is bonded to six O2- atoms to form distorted face-sharing AgO6 octahedra. There are a spread of Ag–O bond distances ranging from 2.21–2.72 Å. There are six inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. In the second H1+ site, H1+ is bonded in a distorted single-bond geometry to two O2- atoms. There is one shorter (1.02 Å) and one longer (1.62 Å) H–O bond length. In the third H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. In the fourth H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.99 Å. In the fifth H1+ site, H1+ is bonded in a distorted single-bond geometry to one O2- atom. The H–O bond length is 1.02 Å. In the sixth H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.99 Å. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a water-like geometry to two H1+ atoms. In the second O2- site, O2- is bonded in a water-like geometry to two equivalent Ag2+ and two H1+ atoms. In the third O2- site, O2- is bonded in a distorted single-bond geometry to two equivalent Ag2+ and two H1+ atoms. In the fourth O2- site, O2- is bonded in a distorted single-bond geometry to two equivalent Ag2+ and one H1+ atom.