cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.3535/a20-wqk-6gc
title: Marsupina bufo (Bruguière, 1792)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/bv7-xvf-5kp
title: Babelomurex spinosus (Y. Hirase, 1908)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/svv-n5z-6ke
title: Epitonium Röding, 1798

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/xbh-cdh-wam
title: Onoba semicostata (Montagu, 1803)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/75b-dbw-yqb
title: Vanikoro distans (Récluz, 1844)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/naq-qtv-brp
title: Alabina Dall, 1902

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.25666/dataosu-2018-12-03-03
title: New ultracool dwarf candidates in Gaia DR2
title: Nouvelles candidates naines brunes et étoiles de très petite masse dans Gaia DR2

description: Photometric and astrometric parameters of 14915 ultra-cool dwarf candidates found in Gaia DR2.
description: Paramètres photométriques et astrométriques de 14915 candidates naines brunes et étoiles de très petite masse trouvées dans Gaia DR2.
description: Audience: Research
description: UpdatePeriodicity: no update
description: Project: GAIA, CNES - Centre national d'études spatiales (Another national), ESA - European Space Agency (Another international)
description: Observational data: Astrometric Space mission
DOI: 10.3535/kve-a7m-9v8
title: Aporrhais pespelecani (Linnaeus, 1758)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/yd0-fm2-4cc
title: Finella pupoides A. Adams, 1860

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/d3b-1h0-lpk
title: Melanopsis tingitana Morelet, 1864

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/1c8-jc9-r5m
title: Trachypollia didyma (Schwengel, 1943)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/l93-hn9-7vn
title: Buccinum undatum Linnaeus, 1758

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/esk-c7n-xg4
title: Baicaliidae P. Fischer, 1885

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/jqg-vxq-sx1
title: Chicoreus ramosus (Linnaeus, 1758)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.25666/dataosu-2019-07-08-02
title: Pollen analysis - Montrond-le-Château (F-25), Grotte des Cavottes
title: Analyse pollinique - Montrond-le-Château (F-25), Grotte des Cavottes

description: Natural site: stalagmitic floor. 4 palynological samples almost sterile.
description: Site naturel : plancher stalagmitique. 4 échantillons lus quasiment stériles.
description: Audience: Research
description: UpdatePeriodicity: no update
description: Observational data: Echantillons prélevés dans la grotte.
Préparation physico-chimique à la liqueur lourde.
Détermination et comptage des spores et des pollens au microscope.
DOI: 10.3535/lyh-9kz-d75
title: Canarium mutabile (Swainson, 1821)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/s8t-gqf-b4l
title: Calyptraeidae Lamarck, 1809

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/nrv-myh-6km
title: Caecum textile de Folin, 1867

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/pfp-d78-txy
title: Hipponix antiquatus (Linnaeus, 1767)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/fx5-d20-mh6
title: Angulyagra oxytropis (W. H. Benson, 1836)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/11a-771-mbt
title: Hipponix Blainville, 1819

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/xv5-1ew-ywj
title: Ostrea edulis Linnaeus, 1758

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.25666/dataosu-2019-07-08-03
title: Pollen analysis - Orange (F-84), LGV-lot 21
title: Analyse pollinique - Orange (F-84), LGV-lot 21

description: Natural site: drilling in a wet plain. 14 palynological samples.
description: Site naturel : forage dans une plaine humide. 14 échantillons lus.
description: Audience: Research
description: UpdatePeriodicity: no update
description: Observational data: Echantillons prélevés par forage, sonde russe (type GIK).
Préparation physico-chimique, méthode dite NaOH.
Détermination et comptage des spores et des pollens au microscope.
DOI: 10.3535/n56-1n8-e0k
title: Hinea lineata (da Costa, 1778)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/nfh-h9c-xcz
title: Trivia monacha (da Costa, 1778)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/hql-bz3-2zp
title: Pomacea sordida (Swainson, 1823)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/rej-ckc-5xl
title: Nototriphora decorata (C. B. Adams, 1850)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/90j-km7-rxk
title: Cyclotus discoideus (G. B. Sowerby I, 1843)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/wwy-sdf-yws
title: Purpura persica (Linnaeus, 1758)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.25666/dataosu-2019-07-09-05
title: Pollen analysis - Doucier (F-39), Lac du Val 2018
title: Analyse pollinique - Doucier (F-39), Lac du Val 2018

description: Natural site, edge of lake. 8 palynological samples.
description: Site naturel, bord de lac. 8 échantillons lus.
description: Audience: Research
description: UpdatePeriodicity: no update
description: Observational data: Echantillons prélevés par forage, sonde russe (type GIK).
Préparation physico-chimique, méthode dite NaOH.
Détermination et comptage des spores et des pollens au microscope.
DOI: 10.3535/4tq-fre-tcg
title: Nerita albicilla Linnaeus, 1758

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.15468/dl.c864q7
title: Occurrence Download

description: A dataset containing 21 species occurrences available in GBIF matching the query:
{
 "and" : [
 "TaxonKey is one of (Zosterops lacertosus)",
 "HasCoordinate is true",
 "OccurrenceStatus is Present",
 "License is one of (CC-BY 4.0, CC0 1.0)"
 ]
}

 The dataset includes 21 records from 1 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0003246-250811113504898/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.3535/48r-k8e-h1m
title: Elimia semicarinata (Say, 1829)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/vj5-l10-l49
title: Barleeia W. Clark, 1853

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/nq8-f7r-l7m
title: Naticidae Guilding, 1834

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/wpc-zj1-0l0
title: Erronea onyx onyx (Linnaeus, 1758)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.25666/dataosu-2019-07-10
title: Pollen analysis - Caderousse (F-84), Les Négades LGV sondages 1 et 2
title: Analyse pollinique - Caderousse (F-84), Les Négades LGV sondages 1 et 2

description: Natural site, drilling in a wet plain. 18 palynological samples.
description: Site naturel, forage plaine humide. 18 échantillons lus.
description: Audience: Research
description: UpdatePeriodicity: no update
description: Observational data: Echantillons prélevés par forage, sonde russe (type GIK).
Préparation physico-chimique, méthode dite NaOH.
Détermination et comptage des spores et des pollens au microscope.
DOI: 10.3535/9ph-c49-cwv
title: Polinices lacteus (Guilding, 1834)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/l37-7md-ygr
title: Mammilla maura (Lamarck, 1816)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/99e-f8w-l1w
title: Orphanopusia patriarchalis (Gmelin, 1791)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/frw-lh8-08s
title: Tarebia granifera (Lamarck, 1816)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/qk0-q9d-v8y
title: Cittarium pica (Linnaeus, 1758)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/qta-ndf-gl2
title: Cypraeidae Rafinesque, 1815

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/xmq-54v-5en
title: Mastonia rubra (Hinds, 1843)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/bap-6wt-lrf
title: Japonia ciliocincta (E. von Martens, 1865)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/sar-0vg-z4k
title: Cheilea equestris (Linnaeus, 1758)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/6gp-4bg-n7l
title: Crucibulum monticulus S. S. Berry, 1969

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/bf5-pf7-kcm
title: Merdigera obscura (O. F. Müller, 1774)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/w7b-z7a-h9x
title: Crassula aequilatera (Reeve, 1854)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/jp1-9ev-lq8
title: Tonna galea (Linnaeus, 1758)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/kmt-5yt-59x
title: Meioceras nitidum (W. Stimpson, 1851)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/0n7-9zj-pgb
title: Melanoides Olivier, 1804

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/5at-5rz-658
title: Casmaria erinaceus (Linnaeus, 1758)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/xxt-58y-92l
title: Caecum plicatum P. P. Carpenter, 1858

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/1kk-4wc-7k2
title: Pythia pantherina (A. Adams, 1851)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/h3r-bkr-l63
title: Trivia monacha (da Costa, 1778)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/cfb-vhw-jct
title: Neritodryas cornea (Linnaeus, 1758)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/k25-s7r-x7z
title: Hemisinus cubanianus (A. d'Orbigny, 1842)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/wg2-trf-amc
title: Crepidula onyx G. B. Sowerby I, 1824

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/kj5-66a-hdt
title: Gyroscala commutata (Monterosato, 1877)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/t5z-k0t-846
title: Rissoidae Gray, 1847

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/rdw-7qr-lff
title: Rissoa lia (Monterosato, 1884)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/xwb-e6e-a92
title: Rissoina ambigua (A. Gould, 1849)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/3k5-pbb-edd
title: Neverita duplicata (Say, 1822)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/lrq-d3a-qj6
title: Barleeia W. Clark, 1853

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.15468/dl.4q4j4v
title: Occurrence Download

description: A dataset containing 57 species occurrences available in GBIF matching the query:
{
 "and" : [
 "TaxonKey is one of (Zosterops luteirostris)",
 "HasCoordinate is true",
 "OccurrenceStatus is Present",
 "License is one of (CC-BY 4.0, CC0 1.0)"
 ]
}

 The dataset includes 57 records from 5 constituent datasets; see https://api.gbif.org/v1/occurrence/download/0003248-250811113504898/datasets/export for details.
 
Data from some individual datasets included in this download may be licensed under less restrictive terms.
DOI: 10.3535/4lm-0vw-mw2
title: Natica arachnoidea (Gmelin, 1791)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/q2a-ex2-kze
title: Polinices aurantius (Röding, 1798)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/eqn-dbd-gy9
title: Echinolittorina lineolata (A. d'Orbigny, 1841)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/tfb-v27-5s6
title: Pedipes pedipes (Bruguière, 1789)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/hrx-7gp-e8v
title: Crisilla quisquiliarum (R. B. Watson, 1886)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/m9h-jgm-8gd
title: Tonna sulcosa (Born, 1778)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/ndc-ml5-hkk
title: Setia turriculata Monterosato, 1884

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/b2n-4ja-78t
title: Bostrycapulus aculeatus (Gmelin, 1791)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/hr3-ted-a7r
title: Thais Röding, 1798

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/lgw-zr3-k6z
title: Cyclophorus perdix tuba (G. B. Sowerby I, 1842)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/39a-afh-8qq
title: Burnupena pubescens (Küster, 1858)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/7aq-93q-ka9
title: Stenothyra krungtepensis Brandt, 1968

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/h2r-8th-vmp
title: Amphithalamus P. P. Carpenter, 1864

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/tzm-l10-6l5
title: Finella A. Adams, 1860

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/7jm-n7b-3fe
title: Pollia rubiginosa (Reeve, 1846)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/81l-vaa-be9
title: Truncatella scalaris piratica Clench & R. D. Turner, 1948

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/psj-gty-b1n
title: Eulimidae R. A. Philippi, 1853

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/dk8-a5v-7mv
title: Cassidula nucleus (Gmelin, 1791)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/gnb-5cq-tpm
title: Alvania beanii (Hanley, 1844)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/41j-bsp-75z
title: Omphalotropis columellaris Quadras & Möllendorff, 1893

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/xh1-l43-g58
title: Tenagodus cumingii Mörch, 1861

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/7py-xxt-81b
title: Naticidae Guilding, 1834

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/tpq-ym6-dk0
title: Niveria suffusa (J. E. Gray, 1827)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/fv7-zfl-jsg
title: Thylacodes medusae Pilsbry, 1891

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/yrl-sem-qlq
title: Iniforis turristhomae (Holten, 1802)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/6ns-sys-7qz
title: Cosmotriphora melanura (C. B. Adams, 1850)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.25666/dataosu-2019-11-26
title: Continuous regional climate change projection for France
title: Projection régionale continue du changement climatique pour la France

description: This data-set concerns the regionalization at 12km resolution of the two Radiative Pathways Projection RCP4.5 and RCP8.5 simulated by the CCSM4 Earth System Model. This dynamic downscaling experiment uses the ARW/WRF model version 3.8.1 run in climate mode. The simulation were conducted by the CRC team of the Biogéosciences lab within the framework of both the ANR CoSAC and PSDR Prosys projects. The experimental set-up uses two embedded domains with a resolution of 48km and 12km respectively. The selected physical schemes follow the experimental protocol described in Boulard et al. 2016. The data are available for the period 1980-2100 at daily time step. Note that for surface temperature and rainfall a quantile-mapping post-correction has been applied.
description: Cet ensemble de données concerne la régionalisation à une résolution de 12 km des deux projections de trajectoire radiative RCP4.5 et RCP8.5 simulées par le modèle de système terrestre CCSM4. Cette expérience de réduction d'échelle dynamique utilise le modèle ARW / WRF version 3.8.1 exécuté en mode climatique. La simulation a été réalisée par l'équipe CRC du laboratoire Biogéosciences dans le cadre des projets ANR CoSAC et PSDR Prosys. La configuration expérimentale utilise deux domaines intégrés avec une résolution de 48 km et 12 km respectivement. Les schémas physiques sélectionnés suivent le protocole expérimental décrit dans Boulard et al. 2016. Les données sont disponibles pour la période 1980-2100 au pas de temps quotidien. Notez que pour la température de surface et les précipitations, une post-correction de la cartographie quantile a été appliqué
description: Audience: University: master, Research, Informal Education, Stakeholder
description: UpdatePeriodicity: no update
description: AdditionnalInformation: Pour accéder aux données, merci de contacter l'administrateur du serveur (contact informatique) pour obtenir l'ouverture gratuite d'un compte d'accès aux données.

To access the data, please contact the data server manager (computing contact) to create an account to freely access the data.
description: Simulation or computational data: Regional climate simulation using the ARW/WRF model v.3.8.1.
DOI: 10.3535/dlz-n84-pv9
title: Thiara Röding, 1798

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/n8r-nf8-hq9
title: Nototriphora decorata (C. B. Adams, 1850)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/3x9-55b-zmj
title: Stramonita biserialis (Blainville, 1832)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/z3j-s2d-c80
title: Manzonia manzoniana (Rolán, 1987)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/pg9-qtz-sa4
title: Monophorus olivaceus (Dall, 1889)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/y02-vsk-xwj
title: Clypeomorus nympha Houbrick, 1985

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/mfq-e1q-nn2
title: Amphithalamus P. P. Carpenter, 1864

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.25666/dataosu-2019-12-04
title: Heterodinuclear Diphosphane-Bridged Iron–Platinum Diyne Complexes as Metalloligands for the Assembly of Polymetallic Systems (Fe, Pt, Co)

description: Treatment of [(OC)3Fe(μ-C=O)(µ-dppm)Pt(PPh3)] (1a) (dppm=Ph2PCH2PPh2) with 1,7-octadiyne affords the isomeric dimetallacyclopentenones [(OC)2Fe(µ-dppm)(µ-C(=O)C{(CH2)4C≡CH}=CH)Pt(PPh3)] (2a) and [(OC)2Fe(µ-dppm)(µ-C(=O)C(H)=C{(CH2)4C≡CH})Pt(PPh3)] (2a′). In a similar manner, the reaction with 1,3-diethynylbenzene and 1,4-diethynylbenzene yields [(OC)2Fe(μ-C(=O)C{C6H4–C≡CH}=CH)(μ-dppm)Pt(PPh3)] (2b,c); using [(OC)3Fe(μ-C=O)(µ-dppa)Pt(PPh3)] (1b) (dppa=Ph2PNHPPh2) as starting material provides [(OC)2Fe(μ-C(=O)C{p-C6H4–C≡CH}=CH)(μ-dppa)Pt(PPh3)] (2d). The isomeric μ-vinylidene complexes [(OC)3Fe(µ-dppm){(µ-C=CH(C6H4C≡CH)})Pt(PPh3)] (3b,c) result from treatment of [(OC)3Fe{Si(OMe)3}(μ-dppm)Pt(H)(PPh3)] with the two aromatic diynes. Reaction of 2a with a further equivalent of 1a yields the structurally characterized tetranuclear species [(OC)2Fe(µ-dppm)(µ-C(=O)C{(CH2)2}=CH)Pt(PPh3)]2 (4a). A dissymmetric heterotetranuclear dimetallacyclopentenone 4b is produced by reacting 2b with [(OC)3Fe(μ-C=O)(µ-dppa)Pt(PPh3)] (1b). An unusual heterotetranuclear dimetallacyclopentenone-μ-vinylidene compound 4c results from reaction of 3c with 1 equivalent of 1a. The dimetallacyclopentenone-dicobaltatetrahedrane cluster [(OC)2Fe(µ-dppm)(µ-C(=O)C{(CH2)4(η2-HC2Co2(CO)6}=CH)Pt(PPh3)] (5a) is formed by addition of [Co2(CO)8] to 2a. Likewise, [(OC)2Fe(µ-dppm)(µ-C(=O)C{C6H4(η2-HC2Co2(CO)4(µ-dppm)}=CH)Pt(PPh3)] (5b) is produced by mixing [Co2(CO)6(µ2-dppm)] with 2b. When attempting to prepare a heterotetranuclear complex by reacting 2a with [Co2(CO)6{P(OPh)3}2], the targeted compound was not formed. Instead, the substitution product [(OC)2Fe(µ-dppm)(µ-C(=O)C{(CH2)4C≡CH}=CH)Pt{P(OPh)3}] (6a) was isolated. 2b reacts in an analogous manner yielding [(OC)2Fe(μ-C(=O)C{C6H4–C≡CH}=CH)(μ-dppm)Pt{P(OPh)3}] (6b).
description: Audience: University: master, Research
description: UpdatePeriodicity: no update
description: Experimental data: Synthèse, Diffraction des rayons X, Résonance Magnétique Nucléaire
DOI: 10.3535/4rr-kvs-hhm
title: Onoba transenna (R. B. Watson, 1886)

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/a0v-lc2-kj0
title: Cerithidea Swainson, 1840

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.
DOI: 10.3535/d02-vbm-cr1
title: Simulamerelina Ponder, 1985

description: Digital Specimen for the physical specimen hosted at Naturalis Biodiversity Center.