cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.6084/m9.figshare.7865516.v1
title: Sulfonated poly(ether ether ketone)/hydroxyapatite membrane as biomaterials: process evaluation

description: Abstract Poly(ether ether ketone) (PEEK) has excellent properties, such as high biocompatibility and an elastic modulus similar to bone, which makes it a suitable biomaterial. When modified with sulfuric acid (H2SO4) and hydroxyapatite (HA), its workability and bioactivity is enhanced, and this makes it of great importance in medicine. This study investigates a better combination of process parameters to manufacture sulfonated PEEK/HA (SPEEK/HA) membranes for biomaterials. Chemical, thermal, and biological analyses were carried out on all samples. The sulfonated structure was observed to enhance wettability, adhesion, and cell viability. Furthermore, an increase in the degree of sulfonation facilitated their workability as required for biomaterials; making them suitable for osseointegration. Besides, the SPEEK/HA membranes presented cell adhesion, confirming the viability to use as biomaterial. This study presents a cheap alternative method to easily process biomaterials of improved workability.
DOI: 10.6084/m9.figshare.7865504
title: Owlet moths (Lepidoptera: Noctuoidea) associated with Bt and non- Bt soybean in the brazilian savanna

description: Abstract The use of GMO expressing Bt toxin in soybean production has increased significantly in the last years in Brazil in order to manage the damage caused by lepidopteran pests. In this study, we compared the richness and abundance of owlet moths (Noctuoidea) associated with Bt and non-Bt soybean. We determined the temporal variations as a function of phenology, and correlated the population variations of the most common species with meteorological variables. The research was conducted at the experimental area of Embrapa Cerrados. The collection method used was differentiated being suppressive and absolute. A total of 13 species were collected, of which eight occurred on Bt soybeans. The most representative taxa were Chrysodeixis includens (72.87%), Anticarsia gemmatalis (18.17%) and Spodoptera spp (5.22%). The number of larvae belonging to species targeted by the Bt technology was 10 times lower on Bt than on non-Bt soybeans. Utetheisa ornatrix and Elaphria deltoides were recorded on soybean for the first time, observing larvae of both species in non-Bt soybean and those of U. ornatrix also in Bt soybean. Only A. gemmatalis larvae correlated (p &lt;0.05) negatively with precipitation. This study provided field information on the abundance and species richness of owlet moths on non-Bt soybeans, associated with the effects of Bt soybean. When considering the different levels of infestation between cultivars as a criterion, larvae monitoring is of substantial importance in order to develop the lost control program.
DOI: 10.6084/m9.figshare.7865507
title: Integrative Analysis Based on HPLC-DAD-MS/MS and NMR of Bertholletia excelsa Bark Biomass Residues:Determination of Ellagic Acid Derivatives

description: Bertholletia excelsa Bonpl. (Lecythidaceae) is a South American tree worldwide known for providing the Brazil nuts. In the Amazon Region, B. excelsa is found in monocultures, integrating agroforestries and providing raw materials for food and timber industries. Through the application of an integrative analysis based on high-performance liquid chromatography coupled with diode array detector and tandem mass spectrometry (HPLC-DAD-MS/MS) and nuclear magnetic resonance (NMR) techniques, the present study showed that B. excelsa bark biomass residues contain large quantities of ellagic acid (EA) and its derivatives. Qualitatively, five compounds were characterized for the ﬁrst time in this species. Quantitations were carried out to determine the total amount of these compounds in outer and inner bark tissues. A total of 4.96 and 44.09 g of EA derivatives per kg of dry residues was determined for the outer and inner barks, respectively. Among the EA derivatives, eschweilenol C, ellagic acid and valoneic acid dilactone were the main compounds. These results pointed B. excelsa barks as a valuable biomass residue with potential to be source of health-promoting compounds. Therefore, a potential raw material as source of valuable bioactive phenolic compounds is described herein.
DOI: 10.6084/m9.figshare.7865498
title: Toxicity bioassay and sub-lethal effects of diazinon on blood profile and histology of liver, gills and kidney of catfish, Clarias gariepinus

description: Abstract The catfish, Clarias gariepinus, was exposed to different acute concentrations (5-10 mg/l) of diazinon and the Lc50 value was recorded as high as 7.3 mg/l for 96 hours. The fishes exposed to three sub-lethal levels of diazinon (0.73, 1.095 and 1.46 mg/l) for 30 days showed that the pesticide induces changes in different blood parameters. Number of red blood cells (RBC), haemoglobin level and haematocrit values were elevated whereas white blood cells (WBC) count was reduced. Various blood indices like mean corpuscular volume (MCV), mean corpuscular haemoglobine (MCH) and mean corpuscular haemoglobine concentration (MCHC) vary insignificantly in the fish treated with diazinon. Glucose level and activity level of aspartate aminotransferase (AST) and alanine aminotransferase (ALT) was increased in Clarias gariepinus exposed to diazinon. Protein level in plasma of fish treated with pesticide was changed but the change was insignificant. Histological changes in the liver, gills and kidney of fishes exposed to diazinon were apparent when compared to control. Hepatocytes necrosis and bleeding were more distinct in the fishes exposed to pesticide. Glomerulus hypertrophy and bleeding in kidneys; and fusion and degeneration of secondary lamellae and epithelial hyperplasia in gills were also observed in the exposed fish.
DOI: 10.6084/m9.figshare.7865501
title: Effect of intracanal diode laser application and low-level laser therapy on CGRP change

description: Abstract: The aim of this study was to investigate the effect of a placebo, intracanal diode laser application, and low-level laser therapy (LLLT) on the change of the total amount of calcitonin gene-related peptide (CGRP) in the gingival crevicular fluid (GCF) (split-mouth study design). GCF sampling was performed on a contralateral tooth and experimental tooth (root canal-treated tooth) of thirty-nine patients. The patients were divided into three groups (n = 13), as follows: placebo (mock laser application), intracanal laser application, and LLLT. GCF sampling was repeated at the same sites (experimental and control teeth) one week after root canal treatment. The data were analyzed using the Pearson's correlation analysis and the independent-samples t-tests (p=0.05). In the placebo group, the total CGRP level changes in the GCF before and after treatment was significantly higher for experimental teeth than for control teeth (p&lt;0.05). However, there was no significant difference between experimental and control teeth in the intracanal laser application and LLLT groups (p &gt; 0.05). Intracanal laser application and low-level laser therapy have immunomodulation effects linked to the modulation of the total amount of CGRP in the GCF.
DOI: 10.6084/m9.figshare.7865501.v1
title: Effect of intracanal diode laser application and low-level laser therapy on CGRP change

description: Abstract: The aim of this study was to investigate the effect of a placebo, intracanal diode laser application, and low-level laser therapy (LLLT) on the change of the total amount of calcitonin gene-related peptide (CGRP) in the gingival crevicular fluid (GCF) (split-mouth study design). GCF sampling was performed on a contralateral tooth and experimental tooth (root canal-treated tooth) of thirty-nine patients. The patients were divided into three groups (n = 13), as follows: placebo (mock laser application), intracanal laser application, and LLLT. GCF sampling was repeated at the same sites (experimental and control teeth) one week after root canal treatment. The data were analyzed using the Pearson's correlation analysis and the independent-samples t-tests (p=0.05). In the placebo group, the total CGRP level changes in the GCF before and after treatment was significantly higher for experimental teeth than for control teeth (p&lt;0.05). However, there was no significant difference between experimental and control teeth in the intracanal laser application and LLLT groups (p &gt; 0.05). Intracanal laser application and low-level laser therapy have immunomodulation effects linked to the modulation of the total amount of CGRP in the GCF.
DOI: 10.6084/m9.figshare.7865504.v1
title: Owlet moths (Lepidoptera: Noctuoidea) associated with Bt and non- Bt soybean in the brazilian savanna

description: Abstract The use of GMO expressing Bt toxin in soybean production has increased significantly in the last years in Brazil in order to manage the damage caused by lepidopteran pests. In this study, we compared the richness and abundance of owlet moths (Noctuoidea) associated with Bt and non-Bt soybean. We determined the temporal variations as a function of phenology, and correlated the population variations of the most common species with meteorological variables. The research was conducted at the experimental area of Embrapa Cerrados. The collection method used was differentiated being suppressive and absolute. A total of 13 species were collected, of which eight occurred on Bt soybeans. The most representative taxa were Chrysodeixis includens (72.87%), Anticarsia gemmatalis (18.17%) and Spodoptera spp (5.22%). The number of larvae belonging to species targeted by the Bt technology was 10 times lower on Bt than on non-Bt soybeans. Utetheisa ornatrix and Elaphria deltoides were recorded on soybean for the first time, observing larvae of both species in non-Bt soybean and those of U. ornatrix also in Bt soybean. Only A. gemmatalis larvae correlated (p &lt;0.05) negatively with precipitation. This study provided field information on the abundance and species richness of owlet moths on non-Bt soybeans, associated with the effects of Bt soybean. When considering the different levels of infestation between cultivars as a criterion, larvae monitoring is of substantial importance in order to develop the lost control program.
DOI: 10.6084/m9.figshare.7865507.v1
title: Integrative Analysis Based on HPLC-DAD-MS/MS and NMR of Bertholletia excelsa Bark Biomass Residues:Determination of Ellagic Acid Derivatives

description: Bertholletia excelsa Bonpl. (Lecythidaceae) is a South American tree worldwide known for providing the Brazil nuts. In the Amazon Region, B. excelsa is found in monocultures, integrating agroforestries and providing raw materials for food and timber industries. Through the application of an integrative analysis based on high-performance liquid chromatography coupled with diode array detector and tandem mass spectrometry (HPLC-DAD-MS/MS) and nuclear magnetic resonance (NMR) techniques, the present study showed that B. excelsa bark biomass residues contain large quantities of ellagic acid (EA) and its derivatives. Qualitatively, five compounds were characterized for the ﬁrst time in this species. Quantitations were carried out to determine the total amount of these compounds in outer and inner bark tissues. A total of 4.96 and 44.09 g of EA derivatives per kg of dry residues was determined for the outer and inner barks, respectively. Among the EA derivatives, eschweilenol C, ellagic acid and valoneic acid dilactone were the main compounds. These results pointed B. excelsa barks as a valuable biomass residue with potential to be source of health-promoting compounds. Therefore, a potential raw material as source of valuable bioactive phenolic compounds is described herein.
DOI: 10.6084/m9.figshare.7865492
title: Behavior of expanded polystyrene as lightweight filler in retaining walls with intermediate slabs

description: Abstract The present study explores a retaining wall with an intermediate slab. To reduce the lateral earth pressure on the wall, the substitution of part of the soil by blocks of expanded polystyrene (EPS) with high density is proposed, which could result in significant economic savings. Also, the possibility of building the wall elevation with smaller thickness (preexisting wall reinforcement) will be analyzed. To do this, the situation and optimum geometry of the EPS blocks will be studied in detail, besides a study of two scaled models, one without EPS and another with blocks with rectangular distribution. The obtained results allow us to affirm that the reduction in pressure is very significant if the blocks are arranged with the proper geometry and situation over the sliding plane but without eliminating the beneficial effect of the weight of the ground located over the slab.
DOI: 10.6084/m9.figshare.7865483
title: Seismic Evaluation of Horizontally Curved Bridges Subjected to Near-Field Ground Motions

description: Abstract Horizontally curved bridges have more complex seismic behavior than straight bridges and have been more vulnerable to earthquakes. The present study aimed to evaluate the seismic response of concrete bridges with straight and arched box girder decks in isolated and non-isolated states. The results indicated that increasing the curvature of the non-isolated bridge could increase the irregularity. In addition, increasing the curvature of the deck leads to an increase in shear force, bending moment, and displacement in the piers in the radial direction of the arc, and causes vulnerability of the piers in this direction. Further, in the deck of the bridge, the reduction of the arc radius, especially in the non-isolated bridges, considerably increases the radial shear force, torsion and minor bending moment of the deck. In both isolated and non-isolated cases, the demand in the piers and deck of the bridge under the influence of near-fault ground motions is greater than that of the far-field earthquakes. Seismic isolation results in reducing the force demand in the pier, and the deck of the bridge, leading to a reduction in the force demand rate caused by increasing the central arc angle on the bridge deck.
DOI: 10.6084/m9.figshare.7865489
title: Dynamic structural response characteristics of new concept blast walls under hydrocarbon explosions

description: Abstract Offshore installations activities entail the hazard of explosion accidents with potentially severe consequences to safety of workers, integrity of system, pollution of the environment, and economic losses. Blast walls are generally used for the purpose of reducing the explosion consequences. This study introduce a new concept of blast wall (perforated blast wall) which can disrupt loaindg pressure during the explosion. A dynamic finite element analysis was performed to investigate the effects of the geometric characteristics on the performance of perforated blast walls. A series of computations were performed varying with opening size, plate thickness and opening layout associated with Blockage Ratio. A proposal formula was derived as a function of those design parameters for easily expecting the dynamic structural response characteristics.
DOI: 10.6084/m9.figshare.7865492.v1
title: Behavior of expanded polystyrene as lightweight filler in retaining walls with intermediate slabs

description: Abstract The present study explores a retaining wall with an intermediate slab. To reduce the lateral earth pressure on the wall, the substitution of part of the soil by blocks of expanded polystyrene (EPS) with high density is proposed, which could result in significant economic savings. Also, the possibility of building the wall elevation with smaller thickness (preexisting wall reinforcement) will be analyzed. To do this, the situation and optimum geometry of the EPS blocks will be studied in detail, besides a study of two scaled models, one without EPS and another with blocks with rectangular distribution. The obtained results allow us to affirm that the reduction in pressure is very significant if the blocks are arranged with the proper geometry and situation over the sliding plane but without eliminating the beneficial effect of the weight of the ground located over the slab.
DOI: 10.6084/m9.figshare.7865495
title: Zinc Ferrite Nanoparticles via Coprecipitation Modified Method: Glycerol as Structure Directing and Stabilizing Agent

description: Coprecipitation is one of the most practical methods used to synthesize ferrite nanoparticles. Fine characteristics of these materials can be improved by means of a series of modifications in the synthesis method. In this paper we present a study of influence of glycerol as structure directing and stabilizing agent in the synthesis of zinc ferrite nanoparticle, exploring its chelating capacity and oxidation. The studied materials include two series of zinc ferrite samples and its precursors obtained with or without glycerol throughout different stages during the synthesis process. The structural and morphological characteristics were evaluated by means of different techniques such as X-ray diffraction, Fourier transformed infrared spectroscopy, scanning and transmission electron microscopy and thermal analysis. The oxidation of glycerol was determined by high-performance liquid chromatograph. The obtained results demonstrate that zinc ferrite crystals synthesized in the presence of glycerol are initially bigger than those synthesized in absence of it, but according to the oxidation process they tend to decrease giving rise to intermediate phases. Interestingly, these samples grow back during more advanced stages and become structurally better organized, compared to the series of samples produced in absence of glycerol. These results indicate that glycerol is capable to modify the synthesis route of zinc ferrite nanoparticles via coprecipitation, acting directly over the size and morphology of the crystals.
DOI: 10.6084/m9.figshare.7865498.v1
title: Toxicity bioassay and sub-lethal effects of diazinon on blood profile and histology of liver, gills and kidney of catfish, Clarias gariepinus

description: Abstract The catfish, Clarias gariepinus, was exposed to different acute concentrations (5-10 mg/l) of diazinon and the Lc50 value was recorded as high as 7.3 mg/l for 96 hours. The fishes exposed to three sub-lethal levels of diazinon (0.73, 1.095 and 1.46 mg/l) for 30 days showed that the pesticide induces changes in different blood parameters. Number of red blood cells (RBC), haemoglobin level and haematocrit values were elevated whereas white blood cells (WBC) count was reduced. Various blood indices like mean corpuscular volume (MCV), mean corpuscular haemoglobine (MCH) and mean corpuscular haemoglobine concentration (MCHC) vary insignificantly in the fish treated with diazinon. Glucose level and activity level of aspartate aminotransferase (AST) and alanine aminotransferase (ALT) was increased in Clarias gariepinus exposed to diazinon. Protein level in plasma of fish treated with pesticide was changed but the change was insignificant. Histological changes in the liver, gills and kidney of fishes exposed to diazinon were apparent when compared to control. Hepatocytes necrosis and bleeding were more distinct in the fishes exposed to pesticide. Glomerulus hypertrophy and bleeding in kidneys; and fusion and degeneration of secondary lamellae and epithelial hyperplasia in gills were also observed in the exposed fish.
DOI: 10.6084/m9.figshare.7865480
title: Fatigue degradation strategies to simulate crack propagation using peridynamic based computational methods

description: Abstract The aim of this paper is to develop new computational tools to study fatigue crack propagation in structural materials. In particular we compare the performance of different degradation strategies to study fatigue crack propagation phenomena adopting peridynamic based computational methods. Three fatigue degradation laws are proposed. Two of them are original. Initially a cylinder model is used to compare the computational performance of the three fatigue laws and to study their robustness with respect to variations of discretization parameters. Then the fatigue degradation strategies are implemented in a peridynamic framework for fatigue crack propagation analyses. Both cylinder model and peridynamic simulations show that the third proposed degradation law is unique in its combination of high accuracy, high stability and low computational cost.
DOI: 10.6084/m9.figshare.7865483.v1
title: Seismic Evaluation of Horizontally Curved Bridges Subjected to Near-Field Ground Motions

description: Abstract Horizontally curved bridges have more complex seismic behavior than straight bridges and have been more vulnerable to earthquakes. The present study aimed to evaluate the seismic response of concrete bridges with straight and arched box girder decks in isolated and non-isolated states. The results indicated that increasing the curvature of the non-isolated bridge could increase the irregularity. In addition, increasing the curvature of the deck leads to an increase in shear force, bending moment, and displacement in the piers in the radial direction of the arc, and causes vulnerability of the piers in this direction. Further, in the deck of the bridge, the reduction of the arc radius, especially in the non-isolated bridges, considerably increases the radial shear force, torsion and minor bending moment of the deck. In both isolated and non-isolated cases, the demand in the piers and deck of the bridge under the influence of near-fault ground motions is greater than that of the far-field earthquakes. Seismic isolation results in reducing the force demand in the pier, and the deck of the bridge, leading to a reduction in the force demand rate caused by increasing the central arc angle on the bridge deck.
DOI: 10.6084/m9.figshare.7865489.v1
title: Dynamic structural response characteristics of new concept blast walls under hydrocarbon explosions

description: Abstract Offshore installations activities entail the hazard of explosion accidents with potentially severe consequences to safety of workers, integrity of system, pollution of the environment, and economic losses. Blast walls are generally used for the purpose of reducing the explosion consequences. This study introduce a new concept of blast wall (perforated blast wall) which can disrupt loaindg pressure during the explosion. A dynamic finite element analysis was performed to investigate the effects of the geometric characteristics on the performance of perforated blast walls. A series of computations were performed varying with opening size, plate thickness and opening layout associated with Blockage Ratio. A proposal formula was derived as a function of those design parameters for easily expecting the dynamic structural response characteristics.