cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.6084/m9.figshare.14290517
title: An Artemia franciscana bioassay for the monitoring of lipophilic phycotoxins in marine bivalve mollusc cultures: An alternative to screening testing?

description: Abstract In Brazil, malacoculture is developed mainly in the state of Santa Catarina, followed by São Paulo and Rio de Janeiro. In the course of the development of Brazilian mariculture, legislation has addressed the sanitary requirements necessary for bivalve commercialization. However, monitoring phycotoxins is a challenge, due to often costly reference methods. In this context, this study evaluated the use of alternative ecotoxicological and bioanalytical methods using Artemia franciscana (brine shrimp) lethality assessments. The results confirm that, although correlations between the reference mouse assay and the brine shrimp assays were not high, the alternative brine shrimp assay may be incorporated into phycotoxin monitoring programs, as hepatopancreas methanolic extracts of mussel (Perna perna) containing DSP resulted in high lethality rates. Therefore, further methodological adjustment studies and the inclusion of other enzymatic and toxicological models are required to further assess these differences, and associations between ecotoxicological methods as early-alarm methods are encouraged.
DOI: 10.6084/m9.figshare.14290517.v1
title: An Artemia franciscana bioassay for the monitoring of lipophilic phycotoxins in marine bivalve mollusc cultures: An alternative to screening testing?

description: Abstract In Brazil, malacoculture is developed mainly in the state of Santa Catarina, followed by São Paulo and Rio de Janeiro. In the course of the development of Brazilian mariculture, legislation has addressed the sanitary requirements necessary for bivalve commercialization. However, monitoring phycotoxins is a challenge, due to often costly reference methods. In this context, this study evaluated the use of alternative ecotoxicological and bioanalytical methods using Artemia franciscana (brine shrimp) lethality assessments. The results confirm that, although correlations between the reference mouse assay and the brine shrimp assays were not high, the alternative brine shrimp assay may be incorporated into phycotoxin monitoring programs, as hepatopancreas methanolic extracts of mussel (Perna perna) containing DSP resulted in high lethality rates. Therefore, further methodological adjustment studies and the inclusion of other enzymatic and toxicological models are required to further assess these differences, and associations between ecotoxicological methods as early-alarm methods are encouraged.
DOI: 10.6084/m9.figshare.14290519
title: Metal phytosorption potential of Hydrocotyle ranunculoides for mitigation of water pollution in high Andean wetlands of Peru

description: Abstract The phytosorption potential of metals of Hydrocotyle ranunculoides was evaluated for the mitigation of water pollution in the high Andean wetlands of Peru. The plants were selected from 10 wetland sites in the community of Pomachaca- Tarma and were washed with potable water, dried, ground, weighed, chemically digested and read with Varian AA 240 atomic absorption equipment. The plant showed copper concentrations in the root (12.08 ± 1.67 mg/kg) greater than the stem (7.37 ± 1.00 mg/kg), followed by the leaves (7.37 ± 1.56 mg/kg). Lead concentration in the root was 0.228 ± 0.711 mg/kg, but was not found in the stem or leaves. The highest zinc concentration was in the root (67.52 ± 12.57 mg/kg) to the stem (53.30 ± 0.61 mg/kg), followed by the leaves (43.99 ± 8.49 mg/kg). Finally, iron was higher in the root (5571.28 ± 693.94 mg/kg) than in the leaves (342.76 ±122.09 mg/kg), followed by the stem (291.94 ± 54.84 mg/kg). Surrounding water had pH between 7.2 and 7.6; no copper and lead were found, zinc was 0.005 ± 0.012 mg/L and iron was 0.009± 0.007 mg/L. In the sediment, copper was 26.12 ± 0.65 mg/kg, lead 28.25 ± 2.41 mg/kg, zinc 85.98 ± 11.38 mg/kg and iron 26111.89 ± 614.37 mg/kg. These results indicate that this plant absorbs metals in the order of Fe&gt;Zn&gt;Cu&gt;Pb and is an alternative for the development of phytotechnology, oriented to the treatment of effluents with metals that contaminate water in wetlands.
DOI: 10.6084/m9.figshare.14290522.v1
title: Brazilian offshore oil exploration areas: an overview of hydrocarbon pollution

description: Abstract The basins of Campos and Santos, the most important offshore oil reserves in Brazil, hold potential for being the largest offshore oil exploration fields in the next decades, mainly due to the oil located in the pre-salt layer. This region presents real conditions for the occurrence of intense atmospheric events added to the high velocity of the meanders of the Brazilian current. However, the increasing risk of accidents and damage in the region has been the subject of concern and discussion. The risks in the basins of Campos (2011) and Santos (2012) may not exhibit the the same potential for disastrous events as do those in the oil fields of Alaska and of the Gulf of Mexico, but accidents in these areas are not unlikely, as already evidenced by previous accidents under similar operating conditions (e.g. Chevron Platform accident in Campos Basin, RJ, Brazil, 2011). This paper highlights discussion of the multidisciplinary and substantial environmental features in oil exploration fields along the Brazilian coast based on Semi-Systematic Review methodology. The aspects evaluated cover not only geological traits, oceanic and meteorological circulation, but also current oil production, the most significant oil spill accidents recorded up to 2019 and the discussion about some current levels of seawater contamination.
DOI: 10.6084/m9.figshare.14290516.v1
title: Sub-daily hydrological-hydrodynamic simulation in flash flood basins: Una river (Pernambuco/Brazil)

description: Abstract Flash floods are observed in the Una River Basin, Pernambuco/Brazil. This particular type of flood is a short-duration hydrological event with occurrence of the peak flow within minutes to few hours after the onset of the rainfall, taking place typically in mountainous regions. The objective of the paper was to assess the sub-daily hydrological and hydrodynamic modeling of flood events in 2011 and 2017. Sub-daily precipitation and streamflow were applied to the models Hydrologic Engineering Center-Hydrologic Modeling System (HEC-HMS) and River Analysis System (HEC-RAS). Model evaluation methods such as Nash-Sutcliffe efficiency (NSE), percent bias, and the ratio of the root mean squared error to the standard deviation of measured data (RSR) were used in the calibration process. The maximum infiltration rate and the Snyder peak coefficient estimation were the most sensitive parameters in the hydrological model. The calibration of the HEC-HMS showed good performances (Catende station NSE=0.78 and RSR=0.46; Palmares station NSE=0.68 and RSR=0.57). During HEC-RAS 1D flow simulations, steep regions in the Una River caused numerical instabilities. The 2D solution was needed to overcome this problem, allowing us to represent the water level in the city of Palmares satisfactorily.
DOI: 10.6084/m9.figshare.14290519.v1
title: Metal phytosorption potential of Hydrocotyle ranunculoides for mitigation of water pollution in high Andean wetlands of Peru

description: Abstract The phytosorption potential of metals of Hydrocotyle ranunculoides was evaluated for the mitigation of water pollution in the high Andean wetlands of Peru. The plants were selected from 10 wetland sites in the community of Pomachaca- Tarma and were washed with potable water, dried, ground, weighed, chemically digested and read with Varian AA 240 atomic absorption equipment. The plant showed copper concentrations in the root (12.08 ± 1.67 mg/kg) greater than the stem (7.37 ± 1.00 mg/kg), followed by the leaves (7.37 ± 1.56 mg/kg). Lead concentration in the root was 0.228 ± 0.711 mg/kg, but was not found in the stem or leaves. The highest zinc concentration was in the root (67.52 ± 12.57 mg/kg) to the stem (53.30 ± 0.61 mg/kg), followed by the leaves (43.99 ± 8.49 mg/kg). Finally, iron was higher in the root (5571.28 ± 693.94 mg/kg) than in the leaves (342.76 ±122.09 mg/kg), followed by the stem (291.94 ± 54.84 mg/kg). Surrounding water had pH between 7.2 and 7.6; no copper and lead were found, zinc was 0.005 ± 0.012 mg/L and iron was 0.009± 0.007 mg/L. In the sediment, copper was 26.12 ± 0.65 mg/kg, lead 28.25 ± 2.41 mg/kg, zinc 85.98 ± 11.38 mg/kg and iron 26111.89 ± 614.37 mg/kg. These results indicate that this plant absorbs metals in the order of Fe&gt;Zn&gt;Cu&gt;Pb and is an alternative for the development of phytotechnology, oriented to the treatment of effluents with metals that contaminate water in wetlands.
DOI: 10.6084/m9.figshare.14290523
title: Multivariate statistical analysis applied to assess the dispersion of contaminants in a mining tailings basin in the semiarid region of Bahia - Brazil

description: Abstract This study employed multivariate analysis techniques to identify and evaluate the chemical variables responsible for the contamination of the urban area of Boquira, Bahia, due to the abandonment of the tailings basin of Pb-Zn mining, in order to assist in the environmental management of the area. Factor analysis was performed on main and grouping components. The factor analysis allowed grouping the variables into two main factors for street sediment samples, adding up to 72% of the total accumulated variance, and three factors for house dust samples, which explained 77% of the total variance. The variables have a strong correlation with the composition of the tailings basin. Cluster analysis classified the samples according to the concentration of metals in the area, where the influence of the tailings basin and the natural background of the region's rocks in the contamination distribution can be identified.
DOI: 10.6084/m9.figshare.14290522
title: Brazilian offshore oil exploration areas: an overview of hydrocarbon pollution

description: Abstract The basins of Campos and Santos, the most important offshore oil reserves in Brazil, hold potential for being the largest offshore oil exploration fields in the next decades, mainly due to the oil located in the pre-salt layer. This region presents real conditions for the occurrence of intense atmospheric events added to the high velocity of the meanders of the Brazilian current. However, the increasing risk of accidents and damage in the region has been the subject of concern and discussion. The risks in the basins of Campos (2011) and Santos (2012) may not exhibit the the same potential for disastrous events as do those in the oil fields of Alaska and of the Gulf of Mexico, but accidents in these areas are not unlikely, as already evidenced by previous accidents under similar operating conditions (e.g. Chevron Platform accident in Campos Basin, RJ, Brazil, 2011). This paper highlights discussion of the multidisciplinary and substantial environmental features in oil exploration fields along the Brazilian coast based on Semi-Systematic Review methodology. The aspects evaluated cover not only geological traits, oceanic and meteorological circulation, but also current oil production, the most significant oil spill accidents recorded up to 2019 and the discussion about some current levels of seawater contamination.
DOI: 10.6084/m9.figshare.14290525
title: Evaluation of physicochemical water parameters in watersheds of southern Brazil

description: Abstract Water-quality monitoring is one of the main instruments for water-resource management. This work therefore evaluated the water quality of the contribution basin of the Sinnott water treatment plant as well as the relationship between physicochemical water parameters, and analyzed the seasonal variation of water quality parameters as a function of rainfall. The study area encompassed the contribution basin of the Sinnott water treatment plant, formed mainly by the drainage areas of the Pelotas stream and its tributary, the Quilombo Stream, located in the city of Pelotas - Rio Grande do Sul, Brazil. A set of 118,368 data points for each stream was analyzed between 2007 and 2012. The following water quality parameters were evaluated: turbidity, temperature, color, pH, hardness, dissolved oxygen, organic matter, and alkalinity. Results showed that dissolved oxygen and water pH values conformed with Brazilian legislation in the 6 years evaluated. However, water color was the parameter that remained the greatest number of days above the set limits, mainly in the Pelotas Stream. Result indicates the need for conservation actions in the catchment, especially considering the importance of color for the assessment of water quality for public supply, in terms of both treatment costs and of public health. Highest values for water color, turbidity, and organic matter coincided with the occurrence of the highest rainfall values. Agricultural activities may potentiate sedimentation in the contribution basin of the Sinnott water treatment plant.
DOI: 10.6084/m9.figshare.14290523.v1
title: Multivariate statistical analysis applied to assess the dispersion of contaminants in a mining tailings basin in the semiarid region of Bahia - Brazil

description: Abstract This study employed multivariate analysis techniques to identify and evaluate the chemical variables responsible for the contamination of the urban area of Boquira, Bahia, due to the abandonment of the tailings basin of Pb-Zn mining, in order to assist in the environmental management of the area. Factor analysis was performed on main and grouping components. The factor analysis allowed grouping the variables into two main factors for street sediment samples, adding up to 72% of the total accumulated variance, and three factors for house dust samples, which explained 77% of the total variance. The variables have a strong correlation with the composition of the tailings basin. Cluster analysis classified the samples according to the concentration of metals in the area, where the influence of the tailings basin and the natural background of the region's rocks in the contamination distribution can be identified.
DOI: 10.6084/m9.figshare.14290525.v1
title: Evaluation of physicochemical water parameters in watersheds of southern Brazil

description: Abstract Water-quality monitoring is one of the main instruments for water-resource management. This work therefore evaluated the water quality of the contribution basin of the Sinnott water treatment plant as well as the relationship between physicochemical water parameters, and analyzed the seasonal variation of water quality parameters as a function of rainfall. The study area encompassed the contribution basin of the Sinnott water treatment plant, formed mainly by the drainage areas of the Pelotas stream and its tributary, the Quilombo Stream, located in the city of Pelotas - Rio Grande do Sul, Brazil. A set of 118,368 data points for each stream was analyzed between 2007 and 2012. The following water quality parameters were evaluated: turbidity, temperature, color, pH, hardness, dissolved oxygen, organic matter, and alkalinity. Results showed that dissolved oxygen and water pH values conformed with Brazilian legislation in the 6 years evaluated. However, water color was the parameter that remained the greatest number of days above the set limits, mainly in the Pelotas Stream. Result indicates the need for conservation actions in the catchment, especially considering the importance of color for the assessment of water quality for public supply, in terms of both treatment costs and of public health. Highest values for water color, turbidity, and organic matter coincided with the occurrence of the highest rainfall values. Agricultural activities may potentiate sedimentation in the contribution basin of the Sinnott water treatment plant.
DOI: 10.6084/m9.figshare.14290528.v1
title: Extreme rainfall and IDF equations for Alagoas State, Brazil

description: Abstract Intensity-duration-frequency (IDF) equations have important applications in several engineering areas such as urban drainage designs, hydrological modeling, and soil conservation projects. This study analyzes the annual maximum series and fits IDF equations for 44 rainfall stations in Alagoas State, Brazil. We adjusted parameters of the Gumbel distribution (GD) and the Generalized Extreme Value (GEV) distribution. The fitting of the observed data to the probability distributions, as well as the selection of the best distribution, were based on the Kolmogorov-Smirnov and Anderson-Darling tests at a 5% significance level. The GEV distribution with parameters obtained by the L-moments method was considered the best in 73% of rainfall stations. The estimated IDF equations showed a good fit, with determination coefficients above 0.991. The maximum rainfall intensities have spatial variation following the climatic zones of the state. The fitted equations allow estimating rainfall intensities from 5 minutes to 24 hours with a return period of 2 to 100 years, and standard error of less than 6.83 mm h-1.
DOI: 10.6084/m9.figshare.14290529
title: Biodegradation of nitroaromatic compounds in Red Water by white rot fungi Pleurotus ostreatus and floridae

description: Abstract Pleurotus fungi are basidiomycetes that stand out in the degradation of recalcitrant organic compounds such as lignin derivatives and phenolic compounds. The aim of this study was to make a comparative evaluation of the capacity of the Pleurotus ostreatus POS 560 and Pleurotus floridae PSP1 fungi in the degradation of 2,4 and 2,6-dinitrotoluene (DNTs) in effluent from an explosive factory. The characterization of the effluent indicated 318 mg L-1 of DNTs, 246 mg L-1 of COD and toxicity factor for Daphnia magna corresponding to 8. The conduct of a multivariate study estimated the influence of the variables pH (5.0 and 6.0), co-substrate concentration (10 and 20 g L-1 of glucose) and species of the fungus Pleurotus (ostreatus and floridae) on the degradation of DNTs, indicating that the variables Fungus and [Glucose] were significant (p &lt;0.05) presenting effects in the order of + 4.45 ± 0.26 and -1.14 ± 0.26, respectively. The reproduction of the best efficiency conditions (P. floridae; pH 6.0 and 10 g L-1 of glucose) in agitated flasks (100 rpm, 26oC) was able to carry out, within 14 days of treatment, the removal of organic matter and toxicity factor in levels on the order of 55 and 50%, respectively, in addition to the complete degradation of DNTs which occurred in the first 120 hours of treatment. In this period, the maximum activity of the peroxidase and Mn-peroxidase enzymes was also characterized, suggesting high potential of the bioprocess under study for remediation of effluents contaminated with nitroaromatic compounds.
DOI: 10.6084/m9.figshare.14290524
title: Variations in soil water replacement levels promote changes in forage cactus mineral composition and biomass productivity

description: Abstract Population growth and the need to exploit natural resources to produce food and guarantee food sovereignty reduce water availability, which can influence nutrient absorption capacity and production of plants. This study evaluated whether variations in soil water replacement levels promote changes in the mineral composition and biomass productivity of forage cactus varieties. A field experiment was conducted in a randomized block design with five levels of reference evapotranspiration replacement (25, 50, 75, 100 and 125% ETo) and three replicates. Contents of the macronutrients N, P, K, Ca, Mg and S; micronutrients Cu, Fe, Mn, Zn, Cl, Na and B; and biomass productivity were quantified in two varieties of forage cactus (‘Orelha de Elefante Mexicana’ and ‘Miúda’). The data were subjected to principal component and multivariate variance analysis. The mineral composition of the forage cactus varieties ‘Miúda’ and ‘Orelha de Elefante Mexicana’ can be optimized from soil water management, so as to obtain adequate nutritional balance for higher yield. The replacement level of 75% ETo promoted greater balance between nutrients in the cladodes of the forage cactus variety ‘Miúda’, while ‘Orelha de Elefante Mexicana’ had better nutritional balance with the replacement levels of 100 and 125% ETo. Soil water replacement levels of 100 and 125% ETo promote high accumulation of Na+ and Cl- ions in the cladodes of the forage cactus varieties studied. Highest biomass productivity of the varieties ‘Orelha de Elefante Mexicana’ and ‘Miúda’ was obtained with 75 and 100% ETo replacement levels, respectively. Among the varieties, ‘Orelha de Elefante Mexicana’ had a higher capacity for nutrient accumulation and biomass productivity, followed by ‘Miúda’, under the edaphoclimatic conditions of the Brazilian semiarid region.
DOI: 10.6084/m9.figshare.14290528
title: Extreme rainfall and IDF equations for Alagoas State, Brazil

description: Abstract Intensity-duration-frequency (IDF) equations have important applications in several engineering areas such as urban drainage designs, hydrological modeling, and soil conservation projects. This study analyzes the annual maximum series and fits IDF equations for 44 rainfall stations in Alagoas State, Brazil. We adjusted parameters of the Gumbel distribution (GD) and the Generalized Extreme Value (GEV) distribution. The fitting of the observed data to the probability distributions, as well as the selection of the best distribution, were based on the Kolmogorov-Smirnov and Anderson-Darling tests at a 5% significance level. The GEV distribution with parameters obtained by the L-moments method was considered the best in 73% of rainfall stations. The estimated IDF equations showed a good fit, with determination coefficients above 0.991. The maximum rainfall intensities have spatial variation following the climatic zones of the state. The fitted equations allow estimating rainfall intensities from 5 minutes to 24 hours with a return period of 2 to 100 years, and standard error of less than 6.83 mm h-1.
DOI: 10.6084/m9.figshare.14290529.v1
title: Biodegradation of nitroaromatic compounds in Red Water by white rot fungi Pleurotus ostreatus and floridae

description: Abstract Pleurotus fungi are basidiomycetes that stand out in the degradation of recalcitrant organic compounds such as lignin derivatives and phenolic compounds. The aim of this study was to make a comparative evaluation of the capacity of the Pleurotus ostreatus POS 560 and Pleurotus floridae PSP1 fungi in the degradation of 2,4 and 2,6-dinitrotoluene (DNTs) in effluent from an explosive factory. The characterization of the effluent indicated 318 mg L-1 of DNTs, 246 mg L-1 of COD and toxicity factor for Daphnia magna corresponding to 8. The conduct of a multivariate study estimated the influence of the variables pH (5.0 and 6.0), co-substrate concentration (10 and 20 g L-1 of glucose) and species of the fungus Pleurotus (ostreatus and floridae) on the degradation of DNTs, indicating that the variables Fungus and [Glucose] were significant (p &lt;0.05) presenting effects in the order of + 4.45 ± 0.26 and -1.14 ± 0.26, respectively. The reproduction of the best efficiency conditions (P. floridae; pH 6.0 and 10 g L-1 of glucose) in agitated flasks (100 rpm, 26oC) was able to carry out, within 14 days of treatment, the removal of organic matter and toxicity factor in levels on the order of 55 and 50%, respectively, in addition to the complete degradation of DNTs which occurred in the first 120 hours of treatment. In this period, the maximum activity of the peroxidase and Mn-peroxidase enzymes was also characterized, suggesting high potential of the bioprocess under study for remediation of effluents contaminated with nitroaromatic compounds.