cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.17632/h83w68yr7g.1
title: Data for: Discovering Gene-Disease Associations with Biomedical Word Embeddings

description: This is the dataset supporting the publication Discovering Gene-Disease Associations with Biomedical Word Embeddings. Finding the right target for a disease is critical in the drug development process. This paper presents a machine learning approach for predicting gene-disease associations that (i) employs biomedical word embeddings as features for a classifier trained on Open Targets Platform (OTP) data that (ii) generalises beyond a specific disease or gene class. We train, evaluate and compare different word embedding models and classifiers for the task at hand. In addition, we validate the approach by training on a past OTP release and show that it can assist in identifying probable positive associations among current low evidence associations, confirmed by a recent OTP release. Furthermore, we train word embedding models on different time slices of biomedical articles from ScienceDirect and demonstrate that the trained classifier predicts associations that have not explicitly been mentioned in the training corpus, 5 years into the future. Please send a message to Elsevier describing briefly your request on how you would like to use the assets with a short justification. Elsevier will connect directly with you for the elaboration of a personalized license. The contact information can be found in the license information.
DOI: 10.21258/1519536
title: Inventaire forestier national suisse - Tableau no 902203
DOI: 10.21258/1488000
title: Inventaire forestier national suisse - Tableau no 891722
DOI: 10.21258/1514233
title: Inventaire forestier national suisse - Tableau no 891971
DOI: 10.5517/ccdc.csd.cc22lk7h
title: CCDC 1924456: Experimental Crystal Structure Determination

description: Related Article: Gabriel Brunet, Elizaveta A. Suturina, Guillaume P. C. George, Jeffrey S. Ovens, Paul Richardson, Christophe Bucher, Muralee Murugesu|2020|Chem.-Eur.J.|26|16455|doi:10.1002/chem.202003073
DOI: 10.5517/ccdc.csd.cc22lk8j
title: CCDC 1924457: Experimental Crystal Structure Determination

description: Related Article: Gabriel Brunet, Elizaveta A. Suturina, Guillaume P. C. George, Jeffrey S. Ovens, Paul Richardson, Christophe Bucher, Muralee Murugesu|2020|Chem.-Eur.J.|26|16455|doi:10.1002/chem.202003073
DOI: 10.5517/ccdc.csd.cc22lk9k
title: CCDC 1924458: Experimental Crystal Structure Determination

description: Related Article: Gabriel Brunet, Elizaveta A. Suturina, Guillaume P. C. George, Jeffrey S. Ovens, Paul Richardson, Christophe Bucher, Muralee Murugesu|2020|Chem.-Eur.J.|26|16455|doi:10.1002/chem.202003073
DOI: 10.5517/ccdc.csd.cc254qxz
title: CCDC 2000551: Experimental Crystal Structure Determination

description: Related Article: Jan Nekvinda, Michael Kugler, Josef Holub, Suzan El Anwar, Jiří Brynda, Klára Pospíšilová, Zdeňka Růžičková, Pavlína Řezáčová, Bohumír Grüner|2020|Chem.-Eur.J.|26|16541|doi:10.1002/chem.202002809
DOI: 10.5517/ccdc.csd.cc25kxd2
title: CCDC 2013214: Experimental Crystal Structure Determination

description: Related Article: Sonia Bajo, María M. Alcaide, Joaquín López-Serrano, Jesús Campos|2020|Chem.-Eur.J.|26|15519|doi:10.1002/chem.202004566
DOI: 10.5517/ccdc.csd.cc25kxf3
title: CCDC 2013215: Experimental Crystal Structure Determination

description: Related Article: Sonia Bajo, María M. Alcaide, Joaquín López-Serrano, Jesús Campos|2020|Chem.-Eur.J.|26|15519|doi:10.1002/chem.202004566
DOI: 10.5517/ccdc.csd.cc25kxg4
title: CCDC 2013216: Experimental Crystal Structure Determination

description: Related Article: Sonia Bajo, María M. Alcaide, Joaquín López-Serrano, Jesús Campos|2020|Chem.-Eur.J.|26|15519|doi:10.1002/chem.202004566
DOI: 10.5517/ccdc.csd.cc25kxh5
title: CCDC 2013217: Experimental Crystal Structure Determination

description: Related Article: Sonia Bajo, María M. Alcaide, Joaquín López-Serrano, Jesús Campos|2020|Chem.-Eur.J.|26|15519|doi:10.1002/chem.202004566
DOI: 10.5517/ccdc.csd.cc25kxj6
title: CCDC 2013218: Experimental Crystal Structure Determination

description: Related Article: Sonia Bajo, María M. Alcaide, Joaquín López-Serrano, Jesús Campos|2020|Chem.-Eur.J.|26|15519|doi:10.1002/chem.202004566
DOI: 10.5517/ccdc.csd.cc25kxk7
title: CCDC 2013219: Experimental Crystal Structure Determination

description: Related Article: Sonia Bajo, María M. Alcaide, Joaquín López-Serrano, Jesús Campos|2020|Chem.-Eur.J.|26|15519|doi:10.1002/chem.202004566
DOI: 10.5517/ccdc.csd.cc2606p4
title: CCDC 2025995: Experimental Crystal Structure Determination

description: Related Article: Jipan Yu, Chongyang Zhao, Rong Zhou, Wenchao Gao, Shuai Wang, Kang Liu, Siyu Chen, Kongqiu Hu, Lei Mei, Liyong Yuan, Zhifang Chai, Hanshi Hu, Weiqun Shi|2020|Chem.-Eur.J.|26|16521|doi:10.1002/chem.202003431
DOI: 10.21258/1482900
title: Inventaire forestier national suisse - Tableau no 893068
DOI: 10.5281/zenodo.4312953
title: Complete set of raw and processed datasets, as well as associated Jupyter notebooks for analysis, associated with manuscript entitled: "The MOUSE project: a practical approach for obtaining traceable, wide-range X-ray scattering information"

description: This dataset is a complete set of raw, processed and analyzed data, complete with Jupiter notebooks, associated with the manuscript mentioned in the title. In the manuscript, we provide a ``systems architecture''-like overview and detailed discussions of the methodological and instrumental components that, together, comprise the "MOUSE" project (<strong>M</strong>ethodology <strong>O</strong>ptimization for <strong>U</strong>ltrafine <strong>S</strong>tructure <strong>E</strong>xploration). Through this project, we aim to provide a comprehensive methodology for obtaining the highest quality X-ray scattering information (at small and wide angles) from measurements on materials science samples.
DOI: 10.5281/zenodo.4312952
title: Complete set of raw and processed datasets, as well as associated Jupyter notebooks for analysis, associated with manuscript entitled: "The MOUSE project: a practical approach for obtaining traceable, wide-range X-ray scattering information"

description: This dataset is a complete set of raw, processed and analyzed data, complete with Jupiter notebooks, associated with the manuscript mentioned in the title. In the manuscript, we provide a ``systems architecture''-like overview and detailed discussions of the methodological and instrumental components that, together, comprise the "MOUSE" project (<strong>M</strong>ethodology <strong>O</strong>ptimization for <strong>U</strong>ltrafine <strong>S</strong>tructure <strong>E</strong>xploration). Through this project, we aim to provide a comprehensive methodology for obtaining the highest quality X-ray scattering information (at small and wide angles) from measurements on materials science samples.
DOI: 10.21258/1524868
title: Inventaire forestier national suisse - Tableau no 898701
DOI: 10.21258/1512204
title: Inventaire forestier national suisse - Tableau no 897794
DOI: 10.5281/zenodo.4079515
title: Dynamics of soliton self-injection locking in optical microresonators

description: <pre>The code and data used to produce the plots within the paper entitled "Dynamics of soliton self-injection locking in optical microresonators." </pre>
DOI: 10.5281/zenodo.4079514
title: Dynamics of soliton self-injection locking in optical microresonators

description: <pre>The code and data used to produce the plots within the paper entitled "Dynamics of soliton self-injection locking in optical microresonators." </pre>
DOI: 10.5066/p9yoqfqk
title: 365149109492300 - Laguna Creek below Dennehotso near Kayenta, AZ - 2020/06/02 Terrestrial Lidar Data

description: This is a terrestrial LiDAR laser scanner dataset of an intermittent waterway named Laguna Creek near the community of Dennehotso, AZ collected on June 2, 2020. The reach scanned for this study is located at the bridge where State Route 160 crosses the waterway. The river channel on the upstream side of the bridge has experienced bank erosion over recent years. A bank stabilization project was implemented by the Arizona Department of Transportation in 2018. This scan is intended to capture the condition of the bank in 2020 and be used to measure any changes to the bank protection that has occurred since the installation.. A Leica MS-60 Multistation was used for the laser scanner data collection. Multiple scans were combined by setting up the scanner using resection techniques coupled with Leica RTK - GPS equipment. All scan data are corrected using measurements of a reference mark with a known location that has been used for prior surveying projects.
DOI: 10.21258/1513787
title: Inventaire forestier national suisse - Tableau no 891876
DOI: 10.17632/2rprjfnvk4.1
title: Nucleoredoxin-like 2 LTP
DOI: 10.17632/p6hhwk8yt8.1
title: Espectrophotometer EKO 711F SN:S16601.10 2019 data of FOTOVOLTAICA UFSC @ SAPIENS Park Florianópolis SC Brazil

description: Espectrophotometer EKO 711F SN: S16601.10. 2019 Data taken every minute during daylight at Photovoltaics Lab. Universidade Federal de Santa Catarina at Sapiens Park, Florianópolis SC Brazil. Lat.: 27.430891 S ; Long. 48.441406 W ; Alt. 6m . Local time = GMT-3. Data use GMT time stamp on file names synchronized by internet. Data from 20171017 a few are missing. WSD, CSV and log files are available.
DOI: 10.17632/s64cc8mskr.1
title: Espectrophotometer EKO 711F SN:S16601.10 Oct, 17th 2017-2018 data of FOTOVOLTAICA UFSC @ SAPIENS Park Florianópolis SC Brazil

description: Espectrophotometer EKO 711F SN: S16601.10. Oct, 17th 2017-2018 Data taken every minute during daylight at Photovoltaics Lab. Universidade Federal de Santa Catarina at Sapiens Park, Florianópolis SC Brazil. Lat.: 27.430891 S ; Long. 48.441406 W ; Alt. 6m . Local time = GMT-3. Data use GMT time stamp on file names synchronized by internet. Data since 20171017 a few are missing. WSD, CSV and log files generated by sensors are available.
DOI: 10.21258/1524371
title: Inventaire forestier national suisse - Tableau no 902090
DOI: 10.17632/gspc9r73r5.1
title: FRET-MC: a fluorescence melting competition assay for studying G4 structures in vitro

description: Raw FRET-melting, UV-melting and biophysical characterizations (CD/TDS/IDS). Note: Raw FRET-melting curves of test set are belong to another work and were mixed with FRET-MC results of other sequences what were not discussed in this paper, for this part we only showed the data for drawing. Note files provided experiment date and the meaning of batch.
DOI: 10.17632/6y3hwsz2zz.1
title: Patient outcome non-immobilized spinal fractures

description: 1. The purpose of this set is to answer the question what are the differences in patient outcomes for non-immobilized spinal fractures after a trauma and delivered by an Emergency Medical Service (EMS) on the Emergency Department (ED) between the pre-period (rigid preventive spinal immobilisation protocol) and the post-period (a Dutch selective preventive spinal immobilisation protocol). 2. One row is one unique patient. 3. Data exists mainly categorical variables, age is a continu variable. Language is Dutch. 4. #N/B means 'data is not available'. 5. The data comes from 2 databases: 1) the digital record of the EMS and 2) the electronisch patient record of the ED. These data were merged before analysis 6. The periods 2013-2014 and 2017-2018 means: the data of the years 2013 and 2014 were merged and together they form a unit that represents the pre-period. The same usage for de post-period 2017-2018. 7. The main finding: 1) 125 of 1,147 trauma patients had a fracture, of which 54 fractures were not immobilized. However, between the pre- and post-period in percentages there were no statistical significant differences.
DOI: 10.17632/8gx48tmvjr.2
title: nGVS_MAP_HR_ELD2020

description: Dataset; nGVS_MAP_HR_ELD2020
DOI: 10.17632/m2y5nzmdbv.1
title: Data of jornal of sustainable forestry

description: The study hypothesized that, the conversion of natural forests to forest farm interface and farmlands affect the woody species diversity, biomass and soil organic carbon stocks.
DOI: 10.21258/1502771
title: Inventaire forestier national suisse - Tableau no 899120
DOI: 10.17632/c9bjyxbk2r.1
title: PERFORMANCE OF SALAMANCA’S REFINEMENT OF THE T3-AJCC8 VERSUS THE BRIGHAM AND WOMEN’S HOSPITAL AND TÜBINGEN ALTERNATIVE STAGING SYSTEMS FOR HIGH-RISK CUTANEOUS SQUAMOUS CELL CARCINOMA

description: Supplementary Material: "PERFORMANCE OF SALAMANCA’S REFINEMENT OF THE T3-AJCC8 VERSUS THE BRIGHAM AND WOMEN’S HOSPITAL AND TÜBINGEN ALTERNATIVE STAGING SYSTEMS FOR HIGH-RISK CUTANEOUS SQUAMOUS CELL CARCINOMA". Puebla-Tornero L, Corchete-Sánchez LA, Conde-Ferreirós A, García-Sancha N, Corchado-Cobos R, Román-Curto C & Cañueto J.
DOI: 10.21258/1498284
title: Inventaire forestier national suisse - Tableau no 893052
DOI: 10.5281/zenodo.4313069
title: Data Repository Aaricia Ponnet

description: This dataset contains oral production collected with foreign language learners of Hindi.
DOI: 10.5281/zenodo.4313068
title: Data Repository Aaricia Ponnet

description: This dataset contains oral production collected with foreign language learners of Hindi.
DOI: 10.21258/1521199
title: Inventaire forestier national suisse - Tableau no 891825
DOI: 10.17632/zcm6rnv9bb.1
title: “Nothing is difficult to the man who will give up”: Relative deprivation leads to the endorsement of “anti-chicken soup” in China

description: This research contains two data. Data-Study 1 is the data of study 1 and Data-Study 2 is the data of study 2.
DOI: 10.17632/d3ykf83tyv.1
title: Transcriptomic analysis of Human gastric cancer

description: Gastric cancer is the fifth common malignancy and the third leading cause of cancer-associated mortality worldwide. Therapeutic options for the treatment of GC remains inadequate, therefore understanding the underlying molecular mechanisms of the gastric carcinogenesis and identify sensitive biomarkers could be helpful for the prevention and treatment of the disease. Currently, the high-throughput sequencing techniques, in particular the RNA-seq method represents an advanced approach to evaluate the transcriptional changes between tumor and healthy samples. We performed an AmpliSeq Transcriptome analysis (RNA-seq) of 24 gastric tumors (and their matched normal tissues), according to the Lauren classification using the Ion S5 Sequencer with Torrent Suite Software v10.
DOI: 10.21258/1498965
title: Inventaire forestier national suisse - Tableau no 897293
DOI: 10.17632/sb8h3hw84k.1
title: CTSC-NETs

description: Tumor-derived CTSC promotes breast-to-lung metastasis by regulating neutrophil recruitment and Neutrophil Extracellular Trap (NET) Formation in metastasis niches
DOI: 10.17632/r3vwyr2w5x.1
title: Direct detection of SARS-CoV-2 using CRISPR-Cas13a and a mobile phone-based device. Fozouni. et al.

description: We report the development of an amplification-free CRISPR-Cas13a assay for direct detection of SARS-CoV-2 from nasal swab RNA that can be read with a mobile phone microscope. The assay achieved ~100 copies/uL sensitivity in under 30 minutes of measurement time and accurately detected pre-extracted RNA from a set of positive clinical samples in under 5 minutes. We combined crRNAs targeting SARS-CoV-2 RNA to improve sensitivity and specificity, and directly quantified viral load using enzyme kinetics. Integrated with a reader device based on a mobile phone, this assay has the potential to enable rapid, low-cost, point-of-care screening for SARS-CoV-2.
DOI: 10.17632/8wxxmr8cyb.1
title: Dr.
DOI: 10.17632/97nrhjtts9.1
title: Results of experiments on modelling the ecological niche and potential distribution of Megacopta cribraria (Fabricius, 1798) (Heteroptera, Plataspidae)

description: The dataset includes the results of experiments to modelling the ecological niche and potential distribution of Megacopta cribraria (Fabricius, 1798) (Heteroptera, Plataspidae). The experiments were based on data on species occurrences (GBIF, 2020; Kudzu bug (EDDMaps), 2020) and raster layers with bioclimatic variables in 2.5 minutes resolution. (Fick, Hijmans, 2017; https://www.worldclim.org/) 1. Fick S. E., Hijmans R. J. WorldClim 2: new 1km spatial resolution climate surfaces for global land areas // International Journal of Climatology. 2017. Vol. 37, iss. 12. P. 4302 – 4315. 2. GBIF.org. GBIF Occurrence Download. 2020. Available at: https://doi.org/10.15468/dl.9vrgkj (accessed: 02 September 2020). 3. Kudzu bug, Megacopta cribraria Hemiptera: Plataspidae – EDDMapS. 2020. Available at: https://www.eddmaps.org/species/subject.cfm?sub=56834 (accessed: 02 September 2020).
DOI: 10.21258/1529094
title: Inventaire forestier national suisse - Tableau no 898214
DOI: 10.17632/5tgk53r4v5.1
title: HRV sepsis dataset

description: Derivation and Validation of Heart Rate Variability Based Scoring Models for Continuous Risk Stratification in Patients with Suspected Sepsis in the Emergency Department by Machine Learning Algorithms.
DOI: 10.21258/1515707
title: Inventaire forestier national suisse - Tableau no 897691
DOI: 10.21258/1520520
title: Inventaire forestier national suisse - Tableau no 898005
DOI: 10.17632/ww2vzsnf9b.1
title: Finite element models of human lens at ages 16, 35 and 48

description: Four lens models were created for each of 16, 35, and 48-year groups, giving 12 simulations. The difference between the four models was in the capsule material properties and thickness.
DOI: 10.17632/86hgtcws9d.1
title: Database of sediment transport calculation

description: The results of sediment transport calculation by tsunami and storm wave on ideal topography condition.
DOI: 10.6084/m9.figshare.12090783
title: A new Co(II) coordination polymer: crystal structure and treatment activity on viral myocarditis by reducing CVB3 virus burdens

description: This work presents the synthesis and characterization of a thiocyanato linked Co(II) coordination polymer [Co<sub>2</sub>L<sub>1</sub>(μ1,3-SCN)(η1SCN)]<sub>n</sub> (<b>1</b>) using potential multisite compartmental N,O donor Schiff base blocker ligand [N, N′-bis(3-methoxysalicylidenimino)-1,3-daminopropane] (H<sub>2</sub>L<sub>1</sub>) in presence of Co(OAc)<sub>2</sub> and KSCN. The structural determination shows that complex <b>1</b> shows a 1D chain-like structure composed of binuclear {Co2} cluster-based unit. Furthermore, the nanoparticles of complex <b>1</b> were prepared by a green grinding approach, which has good water dispersibility. In addition, for nano <b>1</b>, the treatment on the myocarditis induced by CVB3 virus was evaluated, and the mechanism was also discussed. Finally, the potential binding mode of the compound binding to VP1 indicated a potential binding site and regulation mechanism.
DOI: 10.6084/m9.figshare.12073929.v1
title: Solvent-directed synthesis of two Cu(II)-based coordination polymers: structural diversity and protective effect on viral myocarditis by reducing inflammatory response in myocardial cells

description: Two Cu(II)-based coordination polymers with the chemical formula of [Cu(bibb)(1,4-NDC)](DMF) (<b>1</b>, bibb = 1,4-bis(benzimidazol-1-yl)−2-butylene, 1,4-H<sub>2</sub>NDC = 1,4-naphthalenedicarboxylic acid, DMF = N,N-dimethylformamide) and [Cu(bibb)(1,4-NDC)](DMA) (<b>2</b>, N,N-dimethylacetamide) have been prepared. The structural solution and refinement results based on the crystal data show that complex <b>1</b> exhibits a rarely 2-fold interpenetrating 3D (4,5)-connected <b>xah</b> framework, and complex <b>2</b> possesses an unusual 3D (3,4)-connected <b>dmc</b> topology. Furthermore, the protective activity of compounds <b>1</b> and <b>2</b> on Viral myocarditis (VMC) was detected on CVB3-induced mouse viral myocarditis model. The relative expression of the inflammatory factors <i>nf-κb</i> and <i>p38</i> in myocardial cells after compounds <b>1</b> and <b>2</b> treatment was measured with reverse transcription-polymerase chain reaction (RT-PCR). The release level of the inflammatory cytokines IL-1 and MCP-1 by myocardial cells was determined with enzyme linked immunosorbent assay (ELISA) detection kit.
DOI: 10.6084/m9.figshare.12074088
title: A porous Sr(II)-organic framework for 5-fluorouracil delivery and anti-cancer activity against human melanoma cells

description: A new Sr(II)-based metal organic framework (MOF) formulated as [Sr(HTATB)(H<sub>2</sub>O)<sub>2</sub>](DMF)<sub>4</sub> (<b>1</b>) has been prepared by reaction of Sr(NO<sub>3</sub>)<sub>2</sub> with the rigid tricarboxylic acid linker 4,4′,4″-s-triazine-2, 4, 6-triyltribenzoic acid (H<sub>3</sub>TATB) in a mixed solvent of N,N-dimethylformamide (DMF) and water. Complex <b>1</b> has been characterized by powder X-ray diffraction (PXRD), elemental analysis (EA) and single crystal X-ray diffraction (SCXRD). In light of its large inner spaces as well as widely distributed open metal sites, the guest-free <b>1</b> (<b>1a</b>) has been used as a crystalline vessel for delivering small-molecule chemotherapeutics such as 5-fluorouracil (5-Fu), which exhibits an outstanding loading capacity around 36.48 wt%. Furthermore, the cumulative release value of 5-Fu at 48 h was about 96.5% in phosphate buffer saline (PBS). In addition, the 3-(4,5-dimethyl-2-thiazolyl)−2,5-diphenyl-2-H-tetrazolium bromide (MTT) assay was employed to evaluate the <i>in vitro</i> cytotoxicity of the carrier 5-Fu loaded <b>1a</b> against the human melanoma cell lines.
DOI: 10.6084/m9.figshare.12074088.v1
title: A porous Sr(II)-organic framework for 5-fluorouracil delivery and anti-cancer activity against human melanoma cells

description: A new Sr(II)-based metal organic framework (MOF) formulated as [Sr(HTATB)(H<sub>2</sub>O)<sub>2</sub>](DMF)<sub>4</sub> (<b>1</b>) has been prepared by reaction of Sr(NO<sub>3</sub>)<sub>2</sub> with the rigid tricarboxylic acid linker 4,4′,4″-s-triazine-2, 4, 6-triyltribenzoic acid (H<sub>3</sub>TATB) in a mixed solvent of N,N-dimethylformamide (DMF) and water. Complex <b>1</b> has been characterized by powder X-ray diffraction (PXRD), elemental analysis (EA) and single crystal X-ray diffraction (SCXRD). In light of its large inner spaces as well as widely distributed open metal sites, the guest-free <b>1</b> (<b>1a</b>) has been used as a crystalline vessel for delivering small-molecule chemotherapeutics such as 5-fluorouracil (5-Fu), which exhibits an outstanding loading capacity around 36.48 wt%. Furthermore, the cumulative release value of 5-Fu at 48 h was about 96.5% in phosphate buffer saline (PBS). In addition, the 3-(4,5-dimethyl-2-thiazolyl)−2,5-diphenyl-2-H-tetrazolium bromide (MTT) assay was employed to evaluate the <i>in vitro</i> cytotoxicity of the carrier 5-Fu loaded <b>1a</b> against the human melanoma cell lines.
DOI: 10.6084/m9.figshare.12102804
title: Syntheses and structures of thiophosphorylatocavitands and their reactivity towards first-row transition metal halides

description: Two-step reactions of resorcin[4]arene (<b>1</b>) or methylresorcin[4]arene (<b>2</b>) with PPhCl<sub>2</sub> and subsequent <i>in situ</i> oxidation with sulfur powder afforded a series of new thiophosphorylatocavitands <b>1a–1d</b> or <b>2a–2d</b>, respectively. Molecular structures of <b>1a</b>⋅C<sub>3</sub>H<sub>6</sub>O, <b>1d</b>⋅C<sub>3</sub>H<sub>6</sub>O⋅CH<sub>4</sub>O, <b>2a</b>⋅2C<sub>2</sub>H<sub>6</sub>O⋅2H<sub>2</sub>O, and <b>2b</b>⋅2C<sub>4</sub>H<sub>8</sub>O have been determined by X-ray diffraction analysis, which showed the <i>C</i><sub>4v</sub> stereoisomer with the four P = S bonds oriented towards the molecular cavity. The binding ability of thiophosphorylatocavitands <b>1a</b> and <b>2b</b> towards Cu(I), Mn(II), Co(II), Cu(II), and Zn(II) halides was studied by UV/vis absorption.