cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.17188/1262830
title: Materials Data on Ho2Ti3Si4 by Materials Project

description: Ho2Ti3Si4 crystallizes in the tetragonal P4_12_12 space group. The structure is three-dimensional. Ho3+ is bonded to seven Si4- atoms to form distorted HoSi7 pentagonal bipyramids that share corners with four equivalent TiSi6 octahedra, corners with six equivalent HoSi7 pentagonal bipyramids, corners with five equivalent TiSi6 pentagonal pyramids, edges with three equivalent HoSi7 pentagonal bipyramids, edges with two equivalent TiSi6 pentagonal pyramids, faces with two equivalent TiSi6 octahedra, faces with two equivalent HoSi7 pentagonal bipyramids, and faces with four equivalent TiSi6 pentagonal pyramids. The corner-sharing octahedra tilt angles range from 45–53°. There are a spread of Ho–Si bond distances ranging from 2.82–3.12 Å. There are two inequivalent Ti+3.33+ sites. In the first Ti+3.33+ site, Ti+3.33+ is bonded to six Si4- atoms to form TiSi6 octahedra that share corners with four equivalent TiSi6 octahedra, corners with eight equivalent HoSi7 pentagonal bipyramids, corners with six equivalent TiSi6 pentagonal pyramids, faces with four equivalent HoSi7 pentagonal bipyramids, and faces with four equivalent TiSi6 pentagonal pyramids. The corner-sharing octahedral tilt angles are 52°. There are a spread of Ti–Si bond distances ranging from 2.69–2.79 Å. In the second Ti+3.33+ site, Ti+3.33+ is bonded to six Si4- atoms to form distorted TiSi6 pentagonal pyramids that share corners with three equivalent TiSi6 octahedra, corners with five equivalent HoSi7 pentagonal bipyramids, corners with four equivalent TiSi6 pentagonal pyramids, edges with two equivalent HoSi7 pentagonal bipyramids, edges with four equivalent TiSi6 pentagonal pyramids, faces with two equivalent TiSi6 octahedra, and faces with four equivalent HoSi7 pentagonal bipyramids. The corner-sharing octahedra tilt angles range from 38–41°. There are a spread of Ti–Si bond distances ranging from 2.56–2.73 Å. There are two inequivalent Si4- sites. In the first Si4- site, Si4- is bonded in a 9-coordinate geometry to four equivalent Ho3+, four Ti+3.33+, and one Si4- atom. The Si–Si bond length is 2.50 Å. In the second Si4- site, Si4- is bonded in a 9-coordinate geometry to three equivalent Ho3+, five Ti+3.33+, and one Si4- atom.
DOI: 10.17188/1262831
title: Materials Data on Er2Ti3Si4 by Materials Project

description: Er2Ti3Si4 crystallizes in the tetragonal P4_12_12 space group. The structure is three-dimensional. Er3+ is bonded to seven Si4- atoms to form distorted ErSi7 pentagonal bipyramids that share corners with four equivalent TiSi6 octahedra, corners with six equivalent ErSi7 pentagonal bipyramids, corners with five equivalent TiSi6 pentagonal pyramids, edges with three equivalent ErSi7 pentagonal bipyramids, edges with two equivalent TiSi6 pentagonal pyramids, faces with two equivalent TiSi6 octahedra, faces with two equivalent ErSi7 pentagonal bipyramids, and faces with four equivalent TiSi6 pentagonal pyramids. The corner-sharing octahedra tilt angles range from 45–53°. There are a spread of Er–Si bond distances ranging from 2.81–3.10 Å. There are two inequivalent Ti+3.33+ sites. In the first Ti+3.33+ site, Ti+3.33+ is bonded to six Si4- atoms to form TiSi6 octahedra that share corners with four equivalent TiSi6 octahedra, corners with eight equivalent ErSi7 pentagonal bipyramids, corners with six equivalent TiSi6 pentagonal pyramids, faces with four equivalent ErSi7 pentagonal bipyramids, and faces with four equivalent TiSi6 pentagonal pyramids. The corner-sharing octahedral tilt angles are 52°. There are a spread of Ti–Si bond distances ranging from 2.68–2.79 Å. In the second Ti+3.33+ site, Ti+3.33+ is bonded to six Si4- atoms to form distorted TiSi6 pentagonal pyramids that share corners with three equivalent TiSi6 octahedra, corners with five equivalent ErSi7 pentagonal bipyramids, corners with four equivalent TiSi6 pentagonal pyramids, edges with two equivalent ErSi7 pentagonal bipyramids, edges with four equivalent TiSi6 pentagonal pyramids, faces with two equivalent TiSi6 octahedra, and faces with four equivalent ErSi7 pentagonal bipyramids. The corner-sharing octahedra tilt angles range from 38–41°. There are a spread of Ti–Si bond distances ranging from 2.55–2.72 Å. There are two inequivalent Si4- sites. In the first Si4- site, Si4- is bonded in a 9-coordinate geometry to four equivalent Er3+, four Ti+3.33+, and one Si4- atom. The Si–Si bond length is 2.50 Å. In the second Si4- site, Si4- is bonded in a 9-coordinate geometry to three equivalent Er3+, five Ti+3.33+, and one Si4- atom.
DOI: 10.17188/1262832
title: Materials Data on Ca2InN by Materials Project

description: Ca2InN crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. there are two inequivalent Ca sites. In the first Ca site, Ca is bonded in a distorted rectangular see-saw-like geometry to one In and four equivalent N atoms. The Ca–In bond length is 3.67 Å. There are two shorter (2.42 Å) and two longer (2.53 Å) Ca–N bond lengths. In the second Ca site, Ca is bonded in an L-shaped geometry to six equivalent In and two equivalent N atoms. There are four shorter (3.49 Å) and two longer (3.70 Å) Ca–In bond lengths. Both Ca–N bond lengths are 2.37 Å. In is bonded in a 11-coordinate geometry to seven Ca and four equivalent In atoms. There are two shorter (2.96 Å) and two longer (3.51 Å) In–In bond lengths. N is bonded to six Ca atoms to form a mixture of edge and corner-sharing NCa6 octahedra. The corner-sharing octahedral tilt angles are 18°.
DOI: 10.17188/1262833
title: Materials Data on Pd2N by Materials Project

description: Pd2N is zeta iron carbide structured and crystallizes in the orthorhombic Pnnm space group. The structure is three-dimensional. Pd is bonded in a 3-coordinate geometry to three equivalent N atoms. There are one shorter (2.04 Å) and two longer (2.22 Å) Pd–N bond lengths. N is bonded to six equivalent Pd atoms to form a mixture of edge and corner-sharing NPd6 octahedra. The corner-sharing octahedral tilt angles are 45°.
DOI: 10.17188/1262834
title: Materials Data on EuAu5 by Materials Project

description: EuAu5 crystallizes in the hexagonal P6/mmm space group. The structure is three-dimensional. Eu3+ is bonded in a distorted hexagonal planar geometry to eighteen Au+0.60- atoms. There are six shorter (3.29 Å) and twelve longer (3.70 Å) Eu–Au bond lengths. There are two inequivalent Au+0.60- sites. In the first Au+0.60- site, Au+0.60- is bonded to four equivalent Eu3+ and eight Au+0.60- atoms to form a mixture of edge, corner, and face-sharing AuEu4Au8 cuboctahedra. There are four shorter (2.85 Å) and four longer (2.88 Å) Au–Au bond lengths. In the second Au+0.60- site, Au+0.60- is bonded in a 3-coordinate geometry to three equivalent Eu3+ and six equivalent Au+0.60- atoms.
DOI: 10.17188/1262836
title: Materials Data on Mn5(NiBi2)2 by Materials Project

description: Ni2Mn5Bi4 crystallizes in the cubic F-43m space group. The structure is three-dimensional. there are two inequivalent Mn sites. In the first Mn site, Mn is bonded in a 6-coordinate geometry to three equivalent Mn, three equivalent Ni, and three equivalent Bi atoms. All Mn–Mn bond lengths are 2.99 Å. All Mn–Ni bond lengths are 2.56 Å. All Mn–Bi bond lengths are 2.85 Å. In the second Mn site, Mn is bonded in a 10-coordinate geometry to two equivalent Mn, two equivalent Ni, and six Bi atoms. Both Mn–Ni bond lengths are 2.66 Å. There are a spread of Mn–Bi bond distances ranging from 2.94–3.07 Å. Ni is bonded in a 10-coordinate geometry to six Mn and four Bi atoms. There are one shorter (2.66 Å) and three longer (2.89 Å) Ni–Bi bond lengths. There are three inequivalent Bi sites. In the first Bi site, Bi is bonded in an octahedral geometry to six equivalent Mn atoms. In the second Bi site, Bi is bonded in a 10-coordinate geometry to six equivalent Mn and four equivalent Ni atoms. In the third Bi site, Bi is bonded in a 8-coordinate geometry to six Mn and two equivalent Ni atoms.
DOI: 10.17188/1262837
title: Materials Data on CePu4Co3 by Materials Project

description: Pu4CeCo3 crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. there are two inequivalent Pu sites. In the first Pu site, Pu is bonded in a 2-coordinate geometry to one Pu and four equivalent Co atoms. The Pu–Pu bond length is 2.82 Å. There are a spread of Pu–Co bond distances ranging from 2.45–3.17 Å. In the second Pu site, Pu is bonded in a 4-coordinate geometry to one Pu, two equivalent Ce, and six Co atoms. There are one shorter (3.17 Å) and one longer (3.19 Å) Pu–Ce bond lengths. There are a spread of Pu–Co bond distances ranging from 2.64–3.27 Å. Ce is bonded in a 4-coordinate geometry to four equivalent Pu and four equivalent Co atoms. There are two shorter (2.80 Å) and two longer (2.81 Å) Ce–Co bond lengths. There are two inequivalent Co sites. In the first Co site, Co is bonded in a 10-coordinate geometry to four equivalent Pu atoms. In the second Co site, Co is bonded in a 10-coordinate geometry to eight Pu and two equivalent Ce atoms.
DOI: 10.17188/1262838
title: Materials Data on Ce(Ni2Sn)2 by Materials Project

description: Ce(Ni2Sn)2 crystallizes in the tetragonal I-4c2 space group. The structure is three-dimensional. Ce is bonded in a 8-coordinate geometry to eight equivalent Ni and eight equivalent Sn atoms. There are four shorter (3.00 Å) and four longer (3.04 Å) Ce–Ni bond lengths. All Ce–Sn bond lengths are 3.50 Å. Ni is bonded in a 10-coordinate geometry to two equivalent Ce, four equivalent Ni, and four equivalent Sn atoms. There are a spread of Ni–Ni bond distances ranging from 2.53–2.73 Å. There are a spread of Ni–Sn bond distances ranging from 2.54–2.68 Å. Sn is bonded in a 12-coordinate geometry to four equivalent Ce and eight equivalent Ni atoms.
DOI: 10.17188/1262839
title: Materials Data on Ce3Ni2Sn7 by Materials Project

description: Ce3Ni2Sn7 crystallizes in the orthorhombic Cmmm space group. The structure is three-dimensional. there are two inequivalent Ce sites. In the first Ce site, Ce is bonded in a 12-coordinate geometry to two equivalent Ni and twelve Sn atoms. Both Ce–Ni bond lengths are 3.48 Å. There are a spread of Ce–Sn bond distances ranging from 3.26–3.35 Å. In the second Ce site, Ce is bonded in a 10-coordinate geometry to four equivalent Ni and ten Sn atoms. All Ce–Ni bond lengths are 3.62 Å. There are a spread of Ce–Sn bond distances ranging from 3.38–3.51 Å. Ni is bonded in a 5-coordinate geometry to five Ce and five Sn atoms. There are a spread of Ni–Sn bond distances ranging from 2.48–2.54 Å. There are four inequivalent Sn sites. In the first Sn site, Sn is bonded in a distorted square co-planar geometry to four equivalent Ce atoms. In the second Sn site, Sn is bonded in a 12-coordinate geometry to four Ce and two equivalent Ni atoms. In the third Sn site, Sn is bonded in a 12-coordinate geometry to four Ce and two equivalent Ni atoms. In the fourth Sn site, Sn is bonded in a 9-coordinate geometry to six equivalent Ce, one Ni, and two equivalent Sn atoms. Both Sn–Sn bond lengths are 2.88 Å.
DOI: 10.17188/1262841
title: Materials Data on U(HO2)2 by Materials Project

description: UO2(OH)2 crystallizes in the orthorhombic Pbca space group. The structure is two-dimensional and consists of two UO2(OH)2 sheets oriented in the (0, 0, 1) direction. U6+ is bonded to six O2- atoms to form corner-sharing UO6 octahedra. The corner-sharing octahedral tilt angles are 45°. There are a spread of U–O bond distances ranging from 1.83–2.34 Å. H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 1.00 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted single-bond geometry to two equivalent U6+ and one H1+ atom. In the second O2- site, O2- is bonded in a single-bond geometry to one U6+ atom.
DOI: 10.17188/1262843
title: Materials Data on Sc(Fe2P)2 by Materials Project

description: Sc(Fe2P)2 crystallizes in the tetragonal P4_2/mnm space group. The structure is three-dimensional. Sc is bonded to six equivalent P atoms to form a mixture of distorted edge and corner-sharing ScP6 octahedra. The corner-sharing octahedral tilt angles are 40°. There are two shorter (2.73 Å) and four longer (2.78 Å) Sc–P bond lengths. Fe is bonded in a 3-coordinate geometry to three equivalent P atoms. There are one shorter (2.24 Å) and two longer (2.29 Å) Fe–P bond lengths. P is bonded in a 9-coordinate geometry to three equivalent Sc and six equivalent Fe atoms.
DOI: 10.17188/1262844
title: Materials Data on Pu3Co by Materials Project

description: Pu3Co crystallizes in the orthorhombic Cmcm space group. The structure is two-dimensional and consists of two Pu3Co sheets oriented in the (0, 1, 0) direction. there are two inequivalent Pu sites. In the first Pu site, Pu is bonded in a 3-coordinate geometry to three equivalent Co atoms. There are two shorter (2.84 Å) and one longer (3.09 Å) Pu–Co bond lengths. In the second Pu site, Pu is bonded in a 2-coordinate geometry to two equivalent Co atoms. Both Pu–Co bond lengths are 2.52 Å. Co is bonded in a 10-coordinate geometry to eight Pu atoms.
DOI: 10.17188/1262845
title: Materials Data on UCu5 by Materials Project

description: UCu5 crystallizes in the cubic F-43m space group. The structure is three-dimensional. U is bonded in a 12-coordinate geometry to sixteen Cu atoms. There are twelve shorter (2.92 Å) and four longer (3.05 Å) U–Cu bond lengths. There are two inequivalent Cu sites. In the first Cu site, Cu is bonded in a 4-coordinate geometry to four equivalent U and twelve equivalent Cu atoms. All Cu–Cu bond lengths are 2.92 Å. In the second Cu site, Cu is bonded to three equivalent U and nine Cu atoms to form a mixture of distorted corner, edge, and face-sharing CuU3Cu9 cuboctahedra. There are three shorter (2.46 Å) and three longer (2.52 Å) Cu–Cu bond lengths.
DOI: 10.17188/1262846
title: Materials Data on DyNiSn by Materials Project

description: DyNiSn crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Dy is bonded in a 12-coordinate geometry to six equivalent Ni and six equivalent Sn atoms. There are a spread of Dy–Ni bond distances ranging from 3.01–3.31 Å. There are a spread of Dy–Sn bond distances ranging from 3.12–3.21 Å. Ni is bonded in a 10-coordinate geometry to six equivalent Dy and four equivalent Sn atoms. There are a spread of Ni–Sn bond distances ranging from 2.60–2.79 Å. Sn is bonded in a 10-coordinate geometry to six equivalent Dy and four equivalent Ni atoms.
DOI: 10.17188/1262847
title: Materials Data on Fe2Sn by Materials Project

description: Fe2Sn crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. there are two inequivalent Fe sites. In the first Fe site, Fe is bonded in a 8-coordinate geometry to eight Fe and six equivalent Sn atoms. There are two shorter (2.63 Å) and six longer (2.87 Å) Fe–Fe bond lengths. All Fe–Sn bond lengths are 2.87 Å. In the second Fe site, Fe is bonded to six equivalent Fe and five equivalent Sn atoms to form a mixture of distorted corner and face-sharing FeFe6Sn5 trigonal bipyramids. There are three shorter (2.55 Å) and two longer (2.63 Å) Fe–Sn bond lengths. Sn is bonded in a 5-coordinate geometry to eleven Fe atoms.
DOI: 10.17188/1262848
title: Materials Data on PuGa4 by Materials Project

description: PuGa4 crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. Pu is bonded in a 11-coordinate geometry to thirteen Ga atoms. There are a spread of Pu–Ga bond distances ranging from 2.97–3.13 Å. There are three inequivalent Ga sites. In the first Ga site, Ga is bonded in a 9-coordinate geometry to three equivalent Pu and six Ga atoms. There are a spread of Ga–Ga bond distances ranging from 2.58–2.91 Å. In the second Ga site, Ga is bonded to four equivalent Pu and eight Ga atoms to form a mixture of distorted edge, face, and corner-sharing GaPu4Ga8 cuboctahedra. There are four shorter (3.02 Å) and two longer (3.06 Å) Ga–Ga bond lengths. In the third Ga site, Ga is bonded in a 3-coordinate geometry to three equivalent Pu and eight Ga atoms.
DOI: 10.17188/1262849
title: Materials Data on GdOs2 by Materials Project

description: GdOs2 is Hexagonal Laves structured and crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. Gd3+ is bonded in a 12-coordinate geometry to twelve Os+1.50- atoms. There are a spread of Gd–Os bond distances ranging from 3.13–3.19 Å. There are three inequivalent Os+1.50- sites. In the first Os+1.50- site, Os+1.50- is bonded to six equivalent Gd3+ and six Os+1.50- atoms to form a mixture of corner, edge, and face-sharing OsGd6Os6 cuboctahedra. There are four shorter (2.73 Å) and two longer (2.74 Å) Os–Os bond lengths. In the second Os+1.50- site, Os+1.50- is bonded to six equivalent Gd3+ and six Os+1.50- atoms to form a mixture of corner, edge, and face-sharing OsGd6Os6 cuboctahedra. There are a spread of Os–Os bond distances ranging from 2.59–2.76 Å. In the third Os+1.50- site, Os+1.50- is bonded to six equivalent Gd3+ and six Os+1.50- atoms to form a mixture of corner, edge, and face-sharing OsGd6Os6 cuboctahedra.
DOI: 10.17188/1262850
title: Materials Data on HfGa by Materials Project

description: HfGa crystallizes in the orthorhombic Pbcm space group. The structure is three-dimensional. there are three inequivalent Hf sites. In the first Hf site, Hf is bonded in a 6-coordinate geometry to six Ga atoms. There are a spread of Hf–Ga bond distances ranging from 2.80–2.93 Å. In the second Hf site, Hf is bonded in a 9-coordinate geometry to nine Ga atoms. There are a spread of Hf–Ga bond distances ranging from 2.80–2.99 Å. In the third Hf site, Hf is bonded to seven Ga atoms to form a mixture of distorted face, edge, and corner-sharing HfGa7 pentagonal bipyramids. There are a spread of Hf–Ga bond distances ranging from 2.71–3.10 Å. There are three inequivalent Ga sites. In the first Ga site, Ga is bonded in a 10-coordinate geometry to six Hf and four Ga atoms. There are two shorter (2.65 Å) and two longer (2.84 Å) Ga–Ga bond lengths. In the second Ga site, Ga is bonded in a 9-coordinate geometry to nine Hf atoms. In the third Ga site, Ga is bonded in a 9-coordinate geometry to seven Hf and two equivalent Ga atoms.
DOI: 10.17188/1262851
title: Materials Data on IrPb by Materials Project

description: IrPb crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. Ir is bonded in a 8-coordinate geometry to two equivalent Ir and six equivalent Pb atoms. Both Ir–Ir bond lengths are 2.84 Å. All Ir–Pb bond lengths are 2.81 Å. Pb is bonded in a 6-coordinate geometry to six equivalent Ir atoms.
DOI: 10.17188/1262852
title: Materials Data on Sc5Pb3 by Materials Project

description: Sc5Pb3 crystallizes in the hexagonal P6_3/mcm space group. The structure is three-dimensional. there are two inequivalent Sc sites. In the first Sc site, Sc is bonded in a 6-coordinate geometry to six equivalent Pb atoms. All Sc–Pb bond lengths are 3.06 Å. In the second Sc site, Sc is bonded in a 5-coordinate geometry to five equivalent Pb atoms. There are a spread of Sc–Pb bond distances ranging from 2.94–3.38 Å. Pb is bonded in a 9-coordinate geometry to nine Sc atoms.
DOI: 10.17188/1262853
title: Materials Data on Sn2Ru by Materials Project

description: RuSn2 is Khatyrkite-like structured and crystallizes in the tetragonal I4/mcm space group. The structure is three-dimensional. Ru is bonded in a 10-coordinate geometry to eight equivalent Sn atoms. All Ru–Sn bond lengths are 2.82 Å. Sn is bonded in a 4-coordinate geometry to four equivalent Ru and one Sn atom. The Sn–Sn bond length is 2.97 Å.
DOI: 10.17188/1262857
title: Materials Data on Nd12Co6Sn by Materials Project

description: Nd12Co6Sn crystallizes in the cubic Im-3 space group. The structure is three-dimensional. Nd is bonded in a 3-coordinate geometry to three equivalent Co and one Sn atom. There are one shorter (2.77 Å) and two longer (2.96 Å) Nd–Co bond lengths. The Nd–Sn bond length is 3.62 Å. Co is bonded in a 2-coordinate geometry to six equivalent Nd and one Co atom. The Co–Co bond length is 2.22 Å. Sn is bonded in a cuboctahedral geometry to twelve equivalent Nd atoms.
DOI: 10.17188/1262858
title: Materials Data on Rb2Ag4S3 by Materials Project

description: Rb2Ag4S3 crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. there are two inequivalent Rb1+ sites. In the first Rb1+ site, Rb1+ is bonded to six S2- atoms to form a mixture of distorted corner, edge, and face-sharing RbS6 octahedra. The corner-sharing octahedra tilt angles range from 39–67°. There are a spread of Rb–S bond distances ranging from 3.44–3.52 Å. In the second Rb1+ site, Rb1+ is bonded to six S2- atoms to form a mixture of distorted corner, edge, and face-sharing RbS6 octahedra. The corner-sharing octahedra tilt angles range from 39–67°. There are a spread of Rb–S bond distances ranging from 3.37–3.50 Å. There are four inequivalent Ag1+ sites. In the first Ag1+ site, Ag1+ is bonded in a distorted trigonal planar geometry to three S2- atoms. There are two shorter (2.56 Å) and one longer (2.66 Å) Ag–S bond lengths. In the second Ag1+ site, Ag1+ is bonded in a 3-coordinate geometry to four S2- atoms. There are a spread of Ag–S bond distances ranging from 2.53–3.19 Å. In the third Ag1+ site, Ag1+ is bonded in a distorted trigonal planar geometry to three S2- atoms. There are one shorter (2.55 Å) and two longer (2.75 Å) Ag–S bond lengths. In the fourth Ag1+ site, Ag1+ is bonded in a distorted trigonal planar geometry to three S2- atoms. There are two shorter (2.49 Å) and one longer (2.73 Å) Ag–S bond lengths. There are three inequivalent S2- sites. In the first S2- site, S2- is bonded in a 9-coordinate geometry to three Rb1+ and six Ag1+ atoms. In the second S2- site, S2- is bonded in a 8-coordinate geometry to four Rb1+ and four Ag1+ atoms. In the third S2- site, S2- is bonded in a 3-coordinate geometry to five Rb1+ and three Ag1+ atoms.
DOI: 10.17188/1262859
title: Materials Data on Eu(BS2)2 by Materials Project

description: Eu(BS2)2 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. Eu2+ is bonded in a 9-coordinate geometry to nine S2- atoms. There are a spread of Eu–S bond distances ranging from 2.94–3.55 Å. There are two inequivalent B3+ sites. In the first B3+ site, B3+ is bonded to four S2- atoms to form corner-sharing BS4 tetrahedra. There are a spread of B–S bond distances ranging from 1.92–1.95 Å. In the second B3+ site, B3+ is bonded to four S2- atoms to form a mixture of corner and edge-sharing BS4 tetrahedra. There are a spread of B–S bond distances ranging from 1.88–1.97 Å. There are four inequivalent S2- sites. In the first S2- site, S2- is bonded in a 2-coordinate geometry to two equivalent Eu2+ and two B3+ atoms. In the second S2- site, S2- is bonded in a distorted water-like geometry to two equivalent Eu2+ and two equivalent B3+ atoms. In the third S2- site, S2- is bonded in a 2-coordinate geometry to three equivalent Eu2+ and two equivalent B3+ atoms. In the fourth S2- site, S2- is bonded in a 2-coordinate geometry to two equivalent Eu2+ and two B3+ atoms.