cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.6084/m9.figshare.12027717.v1
title: Structural and Functional Stabilization of Sericin from Bombyx mori Cocoons in a Biopolysaccharide Film: Bioorigami for Skin Regeneration

description: Development and optimization of a bioorigami film with silk sericin was pursued for skin regeneration. Several formulations were produced, with varying integrated sericin contents, viz. 0, 1, 2, 5, 10, 20 and 50 mgsericin mLfilm-1. The physico-chemical characteristics of the bioorigami films produced were evaluated via infrared spectrophotometry, X-ray diffraction, X-ray transmission, X-ray fluorescence, thermogravimetry, differential scanning calorimetry, transdermal protein permeation, kinetics of protein release from the bioorigami films and free radical scavenging activities. The mechanical resistance was also evaluated. The results by 2,2-diphenyl-1-picryl-hydrazil (DPPH) assay suggest that the bioorigami films integrating crude sericin extract had capacity to sequester free radicals, exhibited prolonged release of the bioactive protein, good physico-chemical characteristics and adequate mechanical resistance. Specifically, the bioorigami film with 10 mgsericin mLfilm-1 proved to be able to release all the bioactive protein in a 12 h timeframe. The results suggest potential for use in biopharmaceutical application, specifically, as material for use in hydrogels.
DOI: 10.6084/m9.figshare.12027705
title: Sporepolinic morphology of fluvial terrace sediments in the Western Amazon

description: ABSTRACT Morphological descriptions were made for pollen grains and spores extracted from samples from three sedimentary sections - Chandless 1, Purus 10 and Purus 30 - from fluvial terraces on the Chandless and Purus rivers, Acre State, Brazil. Level CH1-12 at Chandless 1 was C14-dated to 4861 - 5050 cal yr BP, P10-3 of Purus 10 was dated through the OSL method at 8200 +/- 65 yr BP, while P30-6 at Purus 30 was C14 dated to 7845 - 7998 cal yr BP. For pollen analysis, 2 cm3 of each sample was removed, treated with potassium hydroxide (KOH) and acetolysed, followed by palymorph separation with bromoform/alcohol density 2.0 solution. A total of 49 palynomorphs were morphologically described (39 pollen types and 10 Pteridophyte spores). The most frequent pollen types belonged to Anacardiaceae, Arecaceae, Euphorbiaceae, Fabaceae, Rutaceae and Amaranthaceae, while the most frequent spores belonged to Polypodiaceae and Pteridaceae. The pollen richness found in the studied samples reflects the current vegetation occupying the banks of the rivers.
DOI: 10.6084/m9.figshare.12027708
title: Using distribution models to estimate blooms of phytosanitary cyanobacteria in Brazil

description: Abstract: The multiple uses of aquatic ecosystems by humankind and the continuous interference of their activities have contributed to the emergence of potentially toxic cyanobacteria blooms. Here, we firstly created a database of occurrences of cyanobacteria blooms in Brazil through a systematic review of the scientific literature available in online platforms (e.g. Web of Science, Capes Thesis Catalogue). Secondly, we carried out ecological niche models with occurrence data obtained from these studies to predict climatically suitable areas for blooms. We select 21 bioclimatic variables input environmental data. We used five modeling methods for the current climate scenario: (1) Maxent; (2) Support Vector Machines; (3) Random Forest; (4) Maximum Likelihood e (5) Gaussian. We found that the number of publications about bloom events was higher in 2009 with a decline in the years 2012, 2013 and 2017. Furthermore, the years with the higher records of blooms in freshwater environments were 2005, 2011 e 2014. These events occurring mainly in public supply reservoirs and are mostly of the genera Microcystis Lemmermann, 1907, Dolichospermum (Ralfs ex Bornet & Flahault) P.Wacklin, L.Hoffmann & J.Komárek, 2009 and Raphidiopsis F.E.Fritsch & F.Rich, 1929. Modeling the potential distribution of blooms, we found sampling gaps that should be targeting for future researches, especially in the Amazon biome. Overall, the models did not predict highly suitable areas in the /north of Brazil, while other regions were relatively well distributed with a higher number of occurrence records in the Southeast region.
DOI: 10.6084/m9.figshare.12027705.v1
title: Sporepolinic morphology of fluvial terrace sediments in the Western Amazon

description: ABSTRACT Morphological descriptions were made for pollen grains and spores extracted from samples from three sedimentary sections - Chandless 1, Purus 10 and Purus 30 - from fluvial terraces on the Chandless and Purus rivers, Acre State, Brazil. Level CH1-12 at Chandless 1 was C14-dated to 4861 - 5050 cal yr BP, P10-3 of Purus 10 was dated through the OSL method at 8200 +/- 65 yr BP, while P30-6 at Purus 30 was C14 dated to 7845 - 7998 cal yr BP. For pollen analysis, 2 cm3 of each sample was removed, treated with potassium hydroxide (KOH) and acetolysed, followed by palymorph separation with bromoform/alcohol density 2.0 solution. A total of 49 palynomorphs were morphologically described (39 pollen types and 10 Pteridophyte spores). The most frequent pollen types belonged to Anacardiaceae, Arecaceae, Euphorbiaceae, Fabaceae, Rutaceae and Amaranthaceae, while the most frequent spores belonged to Polypodiaceae and Pteridaceae. The pollen richness found in the studied samples reflects the current vegetation occupying the banks of the rivers.
DOI: 10.6084/m9.figshare.12027708.v1
title: Using distribution models to estimate blooms of phytosanitary cyanobacteria in Brazil

description: Abstract: The multiple uses of aquatic ecosystems by humankind and the continuous interference of their activities have contributed to the emergence of potentially toxic cyanobacteria blooms. Here, we firstly created a database of occurrences of cyanobacteria blooms in Brazil through a systematic review of the scientific literature available in online platforms (e.g. Web of Science, Capes Thesis Catalogue). Secondly, we carried out ecological niche models with occurrence data obtained from these studies to predict climatically suitable areas for blooms. We select 21 bioclimatic variables input environmental data. We used five modeling methods for the current climate scenario: (1) Maxent; (2) Support Vector Machines; (3) Random Forest; (4) Maximum Likelihood e (5) Gaussian. We found that the number of publications about bloom events was higher in 2009 with a decline in the years 2012, 2013 and 2017. Furthermore, the years with the higher records of blooms in freshwater environments were 2005, 2011 e 2014. These events occurring mainly in public supply reservoirs and are mostly of the genera Microcystis Lemmermann, 1907, Dolichospermum (Ralfs ex Bornet & Flahault) P.Wacklin, L.Hoffmann & J.Komárek, 2009 and Raphidiopsis F.E.Fritsch & F.Rich, 1929. Modeling the potential distribution of blooms, we found sampling gaps that should be targeting for future researches, especially in the Amazon biome. Overall, the models did not predict highly suitable areas in the /north of Brazil, while other regions were relatively well distributed with a higher number of occurrence records in the Southeast region.
DOI: 10.6084/m9.figshare.12027696
title: Approach to An Unusual Cardiac Mass: Mitral Annulus Caseoma

description: Abstract Caseous calcification of the mitral annulus (CCMA) is known to be a rare variant of mitral annulus calcification, a chronic and degenerative process of the mitral valve fibrous ring. It usually carries a benign prognosis. The following case demonstrates a huge mitral annulus caseoma that complicated with severe mitral regurgitation and was treated with a successful surgery. The common consensus on the optimal management of CCMA is conservative medical management and avoiding unnecessary surgery. Therewithal, the current indications for surgical intervention include mitral valve dysfunction, strokes and uncertain diagnosis. Aggressive debridement, risk of left ventricular perforation and exposure of caseous debris to the systemic blood flow may increase the risk of a standard mitral valve surgery. Mitral valve replacement should be preferred compared with mitral valve repair.
DOI: 10.6084/m9.figshare.12027699
title: Comparison of Femoral and Axillary Artery Cannulation in Acute Type A Aortic Dissection Surgery

description: Abstract Introduction: One of the most important points of the acute type A aortic dissection surgery is how to perform cannulation regarding cerebral protection concerns and the conditions of arterial structures as a pathophysiological consequence of the disease. Objective: In this study, femoral and axillary cannulation methods were compared in acute type A aortic dissection operations. Methods: The study retrospectively evaluated 52 patients who underwent emergency surgery for acute type A aortic dissection. Patients without malperfusion according to Penn Aa classification were chosen for preoperative standardization of the study groups. The femoral arterial cannulation group was group 1 (n=22) and the axillary arterial cannulation group was group 2 (n=30). The groups were compared in terms of perioperative and postoperative results. Results: There was no statistically significant difference in terms of preoperative data. In terms of postoperative parameters, especially early mortality and new-onset cerebrovascular event, there was no statistically significant difference. Mortality rates in group 1 and group 2 were 13.6% (n=3) and 10% (n=3), respectively (P=0.685). Postoperative new-onset cerebral events ratio was found in 5 (22.7%) in the femoral cannulation group and 6 (20%) in the axillary cannulation group (P=0.812). Conclusion: Both femoral and axillary arterial cannulation methods can be safely performed in patients with acute type A aortic dissection, provided that cerebral protection strategies should be considered in the first place. The method to be performed may vary depending on the patient’s current medical condition or the surgeon's preference.
DOI: 10.6084/m9.figshare.12027696.v1
title: Approach to An Unusual Cardiac Mass: Mitral Annulus Caseoma

description: Abstract Caseous calcification of the mitral annulus (CCMA) is known to be a rare variant of mitral annulus calcification, a chronic and degenerative process of the mitral valve fibrous ring. It usually carries a benign prognosis. The following case demonstrates a huge mitral annulus caseoma that complicated with severe mitral regurgitation and was treated with a successful surgery. The common consensus on the optimal management of CCMA is conservative medical management and avoiding unnecessary surgery. Therewithal, the current indications for surgical intervention include mitral valve dysfunction, strokes and uncertain diagnosis. Aggressive debridement, risk of left ventricular perforation and exposure of caseous debris to the systemic blood flow may increase the risk of a standard mitral valve surgery. Mitral valve replacement should be preferred compared with mitral valve repair.
DOI: 10.6084/m9.figshare.12027699.v1
title: Comparison of Femoral and Axillary Artery Cannulation in Acute Type A Aortic Dissection Surgery

description: Abstract Introduction: One of the most important points of the acute type A aortic dissection surgery is how to perform cannulation regarding cerebral protection concerns and the conditions of arterial structures as a pathophysiological consequence of the disease. Objective: In this study, femoral and axillary cannulation methods were compared in acute type A aortic dissection operations. Methods: The study retrospectively evaluated 52 patients who underwent emergency surgery for acute type A aortic dissection. Patients without malperfusion according to Penn Aa classification were chosen for preoperative standardization of the study groups. The femoral arterial cannulation group was group 1 (n=22) and the axillary arterial cannulation group was group 2 (n=30). The groups were compared in terms of perioperative and postoperative results. Results: There was no statistically significant difference in terms of preoperative data. In terms of postoperative parameters, especially early mortality and new-onset cerebrovascular event, there was no statistically significant difference. Mortality rates in group 1 and group 2 were 13.6% (n=3) and 10% (n=3), respectively (P=0.685). Postoperative new-onset cerebral events ratio was found in 5 (22.7%) in the femoral cannulation group and 6 (20%) in the axillary cannulation group (P=0.812). Conclusion: Both femoral and axillary arterial cannulation methods can be safely performed in patients with acute type A aortic dissection, provided that cerebral protection strategies should be considered in the first place. The method to be performed may vary depending on the patient’s current medical condition or the surgeon's preference.
DOI: 10.6084/m9.figshare.12027681
title: Near-Infrared Luminescence from Visible-Light-Sensitized Ruthenium(II)-Neodymium(III) Heterobimetallic Bridged Complexes Containing Alkoxy(silyl) Functional Groups

description: New infrared emitting d-f (ruthenium(II)-neodymium(III)) heterobimetallic complexes with alkoxy(silyl) functional groups have been prepared. Visible excitation evidenced energy transfer processes from the ruthenium(II) donor to neodymium(III) acceptors leading to infrared emission. Energy transfer rates (kEnT) and efficiency of energy transfer (ηEnT) are, respectively, 0.61 × 107s-1 and 44% for RuL1-NdL3 complex. Larger values of kEnT (3.04 × 107 s-1) and ηEnT (84%) were detected for RuL2-NdL4 complex. RuL1-NdL3 and RuL2-NdL4 complexes were fully characterized by elementary analysis (EA), mass spectrometry (MS), Fourier transform infrared spectroscopy (FTIR) and Fourier transform Raman spectroscopy (FT-Raman). Total correlation spectroscopy (TOCSY1D), 1H{13C} heteronuclear single quantum correlation (HSQC) and 1H{13C} heteronuclear multiple bond correlation (HMBC) nuclear magnetic resonance (NMR) analyses were also carried out to characterize NdL3 and RuL1-NdL3 complexes. The presence of trialkoxysilyl-substituted ligands would allow further grafting onto any silica or silicated surface aiming at applications as new luminescent near infrared (NIR)-emitting biosensors or biomarkers.
DOI: 10.6084/m9.figshare.12027678
title: Antibacterial activity of polyvinyl alcohol (PVA)/ε-polylysine packaging films and the effect on longan fruit

description: Abstract Biodegradable and antimicrobial films via combing ε-polylysine (ε-PL) and polyvinyl alcohol (PVA) is a promising material for food packaging. We prepared the ε-PL/ PVA films with the ε-PL content of 0%, 1%, 3%, 5% and 7% (wt., relative to PVA) by casting method and their physical and chemical properties were characterized. SEM indicated the surface of ε-PL/PVA films was smooth with well compatibility between ε-PL and PVA at the ε-PL addition content of 1%. The tensile strength and barrier properties for water vapor and oxygen of the ε-PL/PVA films initially elevated and then decreased when ε-PL content exceeded 1%. The ε-PL doped endows antibacterial activity of PVA and the antibacterial property of ε-PL/PVA films was increasing with increase of ε-PL content. Compared with the control, the ε-PL/PVA packaging films could inhibit effectively the pericarp browning and pulp breakdown for longan, consequently the rate of commercially acceptable fruit packaged by ε-PL/PVA films was improved dramatically. However, the effect of ε-PL/PVA on weight loss rate for longan was worse than the control.
DOI: 10.6084/m9.figshare.12027681.v1
title: Near-Infrared Luminescence from Visible-Light-Sensitized Ruthenium(II)-Neodymium(III) Heterobimetallic Bridged Complexes Containing Alkoxy(silyl) Functional Groups

description: New infrared emitting d-f (ruthenium(II)-neodymium(III)) heterobimetallic complexes with alkoxy(silyl) functional groups have been prepared. Visible excitation evidenced energy transfer processes from the ruthenium(II) donor to neodymium(III) acceptors leading to infrared emission. Energy transfer rates (kEnT) and efficiency of energy transfer (ηEnT) are, respectively, 0.61 × 107s-1 and 44% for RuL1-NdL3 complex. Larger values of kEnT (3.04 × 107 s-1) and ηEnT (84%) were detected for RuL2-NdL4 complex. RuL1-NdL3 and RuL2-NdL4 complexes were fully characterized by elementary analysis (EA), mass spectrometry (MS), Fourier transform infrared spectroscopy (FTIR) and Fourier transform Raman spectroscopy (FT-Raman). Total correlation spectroscopy (TOCSY1D), 1H{13C} heteronuclear single quantum correlation (HSQC) and 1H{13C} heteronuclear multiple bond correlation (HMBC) nuclear magnetic resonance (NMR) analyses were also carried out to characterize NdL3 and RuL1-NdL3 complexes. The presence of trialkoxysilyl-substituted ligands would allow further grafting onto any silica or silicated surface aiming at applications as new luminescent near infrared (NIR)-emitting biosensors or biomarkers.
DOI: 10.6084/m9.figshare.12027672
title: The combined effect of exposure time to sodium chlorite (NaClO2) solution and packaging on postharvest quality of white button mushroom (Agaricus bisporus) stored at 4 °C

description: Abstract Agaricus bisporus was washed with 1 g/L sodium chlorite (NaClO2) (SC) solution for 30, 60 and 120 s, packed with a non-perforated polyvinyl chloride (PVC) film and stored at 4 °C for 12 days. Washing the mushrooms with the SC solution and packaging with the PVC film slowed down the change in colour and firmness of the mushrooms, but treating the mushrooms with the SC solution longer than 60 s adversely affected the mushroom texture. After 12 days of storage, the weight loss of the mushrooms packed with the PVC film was less than 10% compared to the control. Headspace O2 concentration decreased while CO2 concentration increased throughout 12 days of storage and reached about 15% and 4%, respectively. Pseudomonas spp. counts for unwashed and unpacked mushrooms reached 10.30 log10 CFU/g after 12 days of storage while the mushrooms washed with the SC solution and packaged with the PVC film had Pseudomonas spp. counts as low as 6.62 log10 CFU/g. Treating the mushrooms with the SC solution for 60 s and packaging with the PVC film were found to be the most appropriate treatment to minimize the change on the postharvest quality of white button mushroom.
DOI: 10.6084/m9.figshare.12027675
title: Protective effect of Echinochrome against intrahepatic cholestasis induced by alpha-naphthylisothiocyanate in rats

description: Abstract The present study was designed to evaluate the protective effects of echinochrome (Ech) on intrahepatic cholestasis in rats induced by a single (i.p.) injection of alpha-naphthylisothiocyanate (ANIT) (75 mg/kg body weight). The rats were pre-treated orally for 48hr (one dose / 24hr) with Ech (1, 5 and 10 mg/kg body weight) or ursodeoxycholic acid (UDCA) 80 mg/kg body weight drug then, injected with ANIT. ANIT markedly increased serum activities of alanine amino transaminase (ALT), aspartate amino transaminase (AST) and alkaline phosphatase (ALP), which was accompanied by a massive inflammation of epithelial cells on bile duct at 24h after ANIT injection. ANIT also increased the levels of total protein (TP), total bilirubin (TB), direct bilirubin (DB), indirect bilirubin (IB), however decrease albumin content (ALB). In addition ANIT increased hepatic MDA and NO level and decreased GSH level and GST activity. The Ech exerted hepatoprotective and anticholestatic effects as assessed by a significant decrease in the activities of serum AST, ALT and ALP, and the levels of TP, TB, DB and IB as well as liver MDA level and NO level. In conclusion, Ech was found to possess hepatoprotective effect against intrahepatic cholestasis induced by hepatotoxin such as ANIT.
DOI: 10.6084/m9.figshare.12027669
title: Calcium oxalate content from two Amazonian amilaceous roots and the functional properties of their isolated starches

description: Abstract The calcium oxalate content from two Amazonian amilaceous roots, Xanthosoma sagittifolium and Pachyrhizus tuberosus, before and after cooking were studied in the present work. Calcium oxalate raphides were observed by light microscopy in longitudinal sections from fresh tubers. The functional properties and physicochemical characteristics of isolated starches from both species were also investigated. Starches granules were observed with scanning electronic microscopy and presented a typical oval-circular shape, smooth surfaces and size ranging from 3.6 μm to 14 μm. Lower gel clarity, slightly high water-binding capacity, A-type starch structure and low values of crystallinity degree were determined in the isolated starches. High intensity bands related to vibrations of glucosidic bonds of polysaccharides were observed by infrared spectroscopy in both starches. Thermal degradation behavior data of the isolated starches reveled high initial decomposition temperatures. Thus, the studied cooked tubers presented low levels of calcium oxalates and are safe to be consumed as a boiled vegetable. Their isolated starches possess good functional characteristics to be applied as an ingredient to products in food industry.
DOI: 10.6084/m9.figshare.12027672.v1
title: The combined effect of exposure time to sodium chlorite (NaClO2) solution and packaging on postharvest quality of white button mushroom (Agaricus bisporus) stored at 4 °C

description: Abstract Agaricus bisporus was washed with 1 g/L sodium chlorite (NaClO2) (SC) solution for 30, 60 and 120 s, packed with a non-perforated polyvinyl chloride (PVC) film and stored at 4 °C for 12 days. Washing the mushrooms with the SC solution and packaging with the PVC film slowed down the change in colour and firmness of the mushrooms, but treating the mushrooms with the SC solution longer than 60 s adversely affected the mushroom texture. After 12 days of storage, the weight loss of the mushrooms packed with the PVC film was less than 10% compared to the control. Headspace O2 concentration decreased while CO2 concentration increased throughout 12 days of storage and reached about 15% and 4%, respectively. Pseudomonas spp. counts for unwashed and unpacked mushrooms reached 10.30 log10 CFU/g after 12 days of storage while the mushrooms washed with the SC solution and packaged with the PVC film had Pseudomonas spp. counts as low as 6.62 log10 CFU/g. Treating the mushrooms with the SC solution for 60 s and packaging with the PVC film were found to be the most appropriate treatment to minimize the change on the postharvest quality of white button mushroom.
DOI: 10.6084/m9.figshare.12027675.v1
title: Protective effect of Echinochrome against intrahepatic cholestasis induced by alpha-naphthylisothiocyanate in rats

description: Abstract The present study was designed to evaluate the protective effects of echinochrome (Ech) on intrahepatic cholestasis in rats induced by a single (i.p.) injection of alpha-naphthylisothiocyanate (ANIT) (75 mg/kg body weight). The rats were pre-treated orally for 48hr (one dose / 24hr) with Ech (1, 5 and 10 mg/kg body weight) or ursodeoxycholic acid (UDCA) 80 mg/kg body weight drug then, injected with ANIT. ANIT markedly increased serum activities of alanine amino transaminase (ALT), aspartate amino transaminase (AST) and alkaline phosphatase (ALP), which was accompanied by a massive inflammation of epithelial cells on bile duct at 24h after ANIT injection. ANIT also increased the levels of total protein (TP), total bilirubin (TB), direct bilirubin (DB), indirect bilirubin (IB), however decrease albumin content (ALB). In addition ANIT increased hepatic MDA and NO level and decreased GSH level and GST activity. The Ech exerted hepatoprotective and anticholestatic effects as assessed by a significant decrease in the activities of serum AST, ALT and ALP, and the levels of TP, TB, DB and IB as well as liver MDA level and NO level. In conclusion, Ech was found to possess hepatoprotective effect against intrahepatic cholestasis induced by hepatotoxin such as ANIT.