cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.17188/1281841
title: Materials Data on PC2S2N3 by Materials Project

description: C2PN3S2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two C2PN3S2 clusters. there are six inequivalent C4+ sites. In the first C4+ site, C4+ is bonded in a distorted linear geometry to one N3- and one S2- atom. The C–N bond length is 1.21 Å. The C–S bond length is 1.56 Å. In the second C4+ site, C4+ is bonded in a distorted linear geometry to one N3- and one S2- atom. The C–N bond length is 1.21 Å. The C–S bond length is 1.56 Å. In the third C4+ site, C4+ is bonded in a distorted linear geometry to one N3- and one S2- atom. The C–N bond length is 1.21 Å. The C–S bond length is 1.56 Å. In the fourth C4+ site, C4+ is bonded in a distorted linear geometry to one N3- and one S2- atom. The C–N bond length is 1.22 Å. The C–S bond length is 1.55 Å. In the fifth C4+ site, C4+ is bonded in a distorted linear geometry to one N3- and one S2- atom. The C–N bond length is 1.21 Å. The C–S bond length is 1.56 Å. In the sixth C4+ site, C4+ is bonded in a distorted linear geometry to one N3- and one S2- atom. The C–N bond length is 1.21 Å. The C–S bond length is 1.56 Å. There are three inequivalent P5+ sites. In the first P5+ site, P5+ is bonded to four N3- atoms to form corner-sharing PN4 tetrahedra. There are a spread of P–N bond distances ranging from 1.59–1.67 Å. In the second P5+ site, P5+ is bonded to four N3- atoms to form corner-sharing PN4 tetrahedra. There are a spread of P–N bond distances ranging from 1.59–1.66 Å. In the third P5+ site, P5+ is bonded to four N3- atoms to form corner-sharing PN4 tetrahedra. There are a spread of P–N bond distances ranging from 1.60–1.66 Å. There are nine inequivalent N3- sites. In the first N3- site, N3- is bonded in a distorted linear geometry to one C4+ and one P5+ atom. In the second N3- site, N3- is bonded in a bent 120 degrees geometry to two P5+ atoms. In the third N3- site, N3- is bonded in a bent 120 degrees geometry to two P5+ atoms. In the fourth N3- site, N3- is bonded in a bent 150 degrees geometry to one C4+ and one P5+ atom. In the fifth N3- site, N3- is bonded in a bent 120 degrees geometry to two P5+ atoms. In the sixth N3- site, N3- is bonded in a bent 150 degrees geometry to one C4+ and one P5+ atom. In the seventh N3- site, N3- is bonded in a distorted bent 150 degrees geometry to one C4+ and one P5+ atom. In the eighth N3- site, N3- is bonded in a bent 150 degrees geometry to one C4+ and one P5+ atom. In the ninth N3- site, N3- is bonded in a bent 150 degrees geometry to one C4+ and one P5+ atom. There are six inequivalent S2- sites. In the first S2- site, S2- is bonded in a single-bond geometry to one C4+ atom. In the second S2- site, S2- is bonded in a distorted single-bond geometry to one C4+ atom. In the third S2- site, S2- is bonded in a single-bond geometry to one C4+ atom. In the fourth S2- site, S2- is bonded in a distorted single-bond geometry to one C4+ atom. In the fifth S2- site, S2- is bonded in a single-bond geometry to one C4+ atom. In the sixth S2- site, S2- is bonded in a single-bond geometry to one C4+ atom.
DOI: 10.17188/1281842
title: Materials Data on Eu3(B3Rh4)2 by Materials Project

description: Eu3(Rh4B3)2 crystallizes in the orthorhombic Fmmm space group. The structure is three-dimensional. there are three inequivalent Eu sites. In the first Eu site, Eu is bonded in a 6-coordinate geometry to one Eu, ten Rh, and six equivalent B atoms. The Eu–Eu bond length is 3.15 Å. There are a spread of Eu–Rh bond distances ranging from 3.05–3.30 Å. There are two shorter (2.97 Å) and four longer (3.21 Å) Eu–B bond lengths. In the second Eu site, Eu is bonded in a 12-coordinate geometry to two Eu, twelve Rh, and six equivalent B atoms. The Eu–Eu bond length is 3.15 Å. There are four shorter (3.16 Å) and eight longer (3.18 Å) Eu–Rh bond lengths. There are four shorter (3.22 Å) and two longer (3.30 Å) Eu–B bond lengths. In the third Eu site, Eu is bonded in a 6-coordinate geometry to one Eu, ten Rh, and six equivalent B atoms. There are a spread of Eu–Rh bond distances ranging from 3.05–3.30 Å. There are two shorter (2.97 Å) and four longer (3.21 Å) Eu–B bond lengths. There are three inequivalent Rh sites. In the first Rh site, Rh is bonded in a distorted square co-planar geometry to four Eu and four B atoms. There are two shorter (2.18 Å) and two longer (2.21 Å) Rh–B bond lengths. In the second Rh site, Rh is bonded in a 4-coordinate geometry to four equivalent Eu and four equivalent B atoms. All Rh–B bond lengths are 2.13 Å. In the third Rh site, Rh is bonded in a distorted square co-planar geometry to four Eu and four B atoms. There are two shorter (2.14 Å) and two longer (2.21 Å) Rh–B bond lengths. There are four inequivalent B sites. In the first B site, B is bonded in a 6-coordinate geometry to three equivalent Eu and six Rh atoms. Both B–Rh bond lengths are 2.21 Å. In the second B site, B is bonded in a 5-coordinate geometry to three equivalent Eu and five Rh atoms. In the third B site, B is bonded in a 6-coordinate geometry to three equivalent Eu and six Rh atoms. There are two shorter (3.22 Å) and one longer (3.30 Å) B–Eu bond lengths. All B–Rh bond lengths are 2.18 Å. In the fourth B site, B is bonded in a 6-coordinate geometry to three equivalent Eu and six Rh atoms. There are two shorter (3.22 Å) and one longer (3.30 Å) B–Eu bond lengths. All B–Rh bond lengths are 2.18 Å.
DOI: 10.17188/1281843
title: Materials Data on TbIn2Ni by Materials Project

description: TbNiIn2 crystallizes in the triclinic P1 space group. The structure is three-dimensional. there are two inequivalent Tb sites. In the first Tb site, Tb is bonded in a 1-coordinate geometry to three equivalent Ni and ten In atoms. There are a spread of Tb–Ni bond distances ranging from 2.96–3.15 Å. There are a spread of Tb–In bond distances ranging from 3.20–3.45 Å. In the second Tb site, Tb is bonded in a 1-coordinate geometry to three equivalent Ni and ten In atoms. There are a spread of Tb–Ni bond distances ranging from 2.97–3.14 Å. There are a spread of Tb–In bond distances ranging from 3.20–3.45 Å. There are two inequivalent Ni sites. In the first Ni site, Ni is bonded in a 9-coordinate geometry to three equivalent Tb and six In atoms. There are a spread of Ni–In bond distances ranging from 2.68–2.74 Å. In the second Ni site, Ni is bonded in a 9-coordinate geometry to three equivalent Tb and six In atoms. There are a spread of Ni–In bond distances ranging from 2.68–2.74 Å. There are four inequivalent In sites. In the first In site, In is bonded in a 12-coordinate geometry to five Tb, three Ni, and four In atoms. There are a spread of In–In bond distances ranging from 2.97–3.22 Å. In the second In site, In is bonded in a 12-coordinate geometry to five Tb, three Ni, and four In atoms. There are a spread of In–In bond distances ranging from 3.09–3.21 Å. In the third In site, In is bonded in a 12-coordinate geometry to five Tb, three Ni, and four In atoms. The In–In bond length is 2.97 Å. In the fourth In site, In is bonded in a 12-coordinate geometry to five Tb, three Ni, and four In atoms.
DOI: 10.17188/1281844
title: Materials Data on In3Ru by Materials Project

description: RuIn3 crystallizes in the tetragonal P-4n2 space group. The structure is three-dimensional. Ru is bonded in a 8-coordinate geometry to eight In atoms. There are a spread of Ru–In bond distances ranging from 2.69–2.83 Å. There are two inequivalent In sites. In the first In site, In is bonded in a linear geometry to two equivalent Ru atoms. In the second In site, In is bonded in a 1-coordinate geometry to three equivalent Ru atoms.
DOI: 10.17188/1281845
title: Materials Data on PbCSNCl by Materials Project

description: PbCNSCl crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Pb2+ is bonded in a 5-coordinate geometry to two equivalent N3-, three equivalent S2-, and three equivalent Cl1- atoms. Both Pb–N bond lengths are 2.87 Å. There are two shorter (3.17 Å) and one longer (3.20 Å) Pb–S bond lengths. There are one shorter (2.96 Å) and two longer (2.98 Å) Pb–Cl bond lengths. C4+ is bonded in a distorted linear geometry to one N3- and one S2- atom. The C–N bond length is 1.19 Å. The C–S bond length is 1.64 Å. N3- is bonded in a distorted single-bond geometry to two equivalent Pb2+ and one C4+ atom. S2- is bonded in a distorted single-bond geometry to three equivalent Pb2+ and one C4+ atom. Cl1- is bonded in a distorted trigonal non-coplanar geometry to three equivalent Pb2+ atoms.
DOI: 10.17188/1281846
title: Materials Data on Sr4GaCN5 by Materials Project

description: Sr4GaCN5 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. there are four inequivalent Sr2+ sites. In the first Sr2+ site, Sr2+ is bonded in a 6-coordinate geometry to six N3- atoms. There are a spread of Sr–N bond distances ranging from 2.60–3.23 Å. In the second Sr2+ site, Sr2+ is bonded in a 7-coordinate geometry to five N3- atoms. There are a spread of Sr–N bond distances ranging from 2.49–2.81 Å. In the third Sr2+ site, Sr2+ is bonded in a 6-coordinate geometry to six N3- atoms. There are a spread of Sr–N bond distances ranging from 2.49–3.13 Å. In the fourth Sr2+ site, Sr2+ is bonded in a 7-coordinate geometry to seven N3- atoms. There are a spread of Sr–N bond distances ranging from 2.51–3.13 Å. Ga3+ is bonded in a trigonal planar geometry to three N3- atoms. There are a spread of Ga–N bond distances ranging from 1.91–1.93 Å. C4+ is bonded in a linear geometry to two N3- atoms. There is one shorter (1.23 Å) and one longer (1.24 Å) C–N bond length. There are five inequivalent N3- sites. In the first N3- site, N3- is bonded in a 7-coordinate geometry to six Sr2+ and one Ga3+ atom. In the second N3- site, N3- is bonded in a 7-coordinate geometry to six Sr2+ and one Ga3+ atom. In the third N3- site, N3- is bonded in a distorted single-bond geometry to four Sr2+ and one C4+ atom. In the fourth N3- site, N3- is bonded in a 1-coordinate geometry to three Sr2+ and one C4+ atom. In the fifth N3- site, N3- is bonded to five Sr2+ and one Ga3+ atom to form a mixture of edge and corner-sharing NSr5Ga octahedra. The corner-sharing octahedra tilt angles range from 7–10°.
DOI: 10.17188/1281847
title: Materials Data on YIn2Ni9 by Materials Project

description: YNi9In2 crystallizes in the tetragonal P4/mbm space group. The structure is three-dimensional. Y is bonded in a 12-coordinate geometry to sixteen Ni and four equivalent In atoms. There are eight shorter (3.00 Å) and eight longer (3.26 Å) Y–Ni bond lengths. All Y–In bond lengths are 3.25 Å. There are three inequivalent Ni sites. In the first Ni site, Ni is bonded to two equivalent Y, seven Ni, and three equivalent In atoms to form distorted NiY2In3Ni7 cuboctahedra that share corners with eighteen NiY2In3Ni7 cuboctahedra, edges with nine NiY2In2Ni8 cuboctahedra, and faces with twenty NiY2In3Ni7 cuboctahedra. There are a spread of Ni–Ni bond distances ranging from 2.38–2.52 Å. There are one shorter (2.61 Å) and two longer (2.78 Å) Ni–In bond lengths. In the second Ni site, Ni is bonded to two equivalent Y, eight Ni, and two equivalent In atoms to form a mixture of distorted edge, corner, and face-sharing NiY2In2Ni8 cuboctahedra. There are a spread of Ni–Ni bond distances ranging from 2.48–2.66 Å. Both Ni–In bond lengths are 2.82 Å. In the third Ni site, Ni is bonded to eight Ni and four equivalent In atoms to form NiIn4Ni8 cuboctahedra that share corners with sixteen NiY2In2Ni8 cuboctahedra, edges with two equivalent NiIn4Ni8 cuboctahedra, and faces with twenty NiY2In3Ni7 cuboctahedra. All Ni–In bond lengths are 2.82 Å. In is bonded in a 12-coordinate geometry to two equivalent Y, twelve Ni, and one In atom. The In–In bond length is 2.92 Å.
DOI: 10.17188/1281848
title: Materials Data on Li5Ca7Sn11 by Materials Project

description: Li5Ca7Sn11 crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. there are three inequivalent Li sites. In the first Li site, Li is bonded to four Sn atoms to form LiSn4 tetrahedra that share corners with two equivalent LiSn4 tetrahedra, a cornercorner with one CaSn7 trigonal bipyramid, edges with two equivalent LiSn4 tetrahedra, and edges with two equivalent CaSn7 trigonal bipyramids. There are a spread of Li–Sn bond distances ranging from 2.81–2.88 Å. In the second Li site, Li is bonded in a 1-coordinate geometry to five Sn atoms. There are one shorter (2.87 Å) and four longer (2.99 Å) Li–Sn bond lengths. In the third Li site, Li is bonded in a 3-coordinate geometry to five Sn atoms. There are a spread of Li–Sn bond distances ranging from 2.87–3.35 Å. There are four inequivalent Ca sites. In the first Ca site, Ca is bonded to seven Sn atoms to form distorted CaSn7 trigonal bipyramids that share a cornercorner with one LiSn4 tetrahedra, edges with two equivalent LiSn4 tetrahedra, and faces with two equivalent CaSn7 trigonal bipyramids. There are a spread of Ca–Sn bond distances ranging from 3.22–3.83 Å. In the second Ca site, Ca is bonded in a 7-coordinate geometry to seven Sn atoms. There are a spread of Ca–Sn bond distances ranging from 3.25–3.52 Å. In the third Ca site, Ca is bonded in a 8-coordinate geometry to eight Sn atoms. There are a spread of Ca–Sn bond distances ranging from 3.30–3.43 Å. In the fourth Ca site, Ca is bonded in a 10-coordinate geometry to ten Sn atoms. There are two shorter (3.32 Å) and eight longer (3.41 Å) Ca–Sn bond lengths. There are six inequivalent Sn sites. In the first Sn site, Sn is bonded in a 8-coordinate geometry to three Li, three Ca, and two Sn atoms. There are one shorter (2.85 Å) and one longer (2.93 Å) Sn–Sn bond lengths. In the second Sn site, Sn is bonded in a 8-coordinate geometry to six Ca and two Sn atoms. The Sn–Sn bond length is 2.95 Å. In the third Sn site, Sn is bonded in a 10-coordinate geometry to two equivalent Li, six Ca, and two Sn atoms. There are one shorter (2.95 Å) and one longer (2.99 Å) Sn–Sn bond lengths. In the fourth Sn site, Sn is bonded in a 9-coordinate geometry to five Li, three Ca, and one Sn atom. In the fifth Sn site, Sn is bonded in a 1-coordinate geometry to one Li, six Ca, and two Sn atoms. The Sn–Sn bond length is 2.91 Å. In the sixth Sn site, Sn is bonded in a 1-coordinate geometry to one Li, six Ca, and two equivalent Sn atoms.
DOI: 10.17188/1281849
title: Materials Data on VGe3 by Materials Project

description: VGe3 crystallizes in the cubic Pm-3n space group. The structure is three-dimensional. V is bonded to twelve equivalent Ge atoms to form a mixture of face and edge-sharing VGe12 cuboctahedra. All V–Ge bond lengths are 2.85 Å. Ge is bonded in a 6-coordinate geometry to four equivalent V and two equivalent Ge atoms. Both Ge–Ge bond lengths are 2.55 Å.
DOI: 10.17188/1281851
title: Materials Data on Ag2Hg7(P4I3)2 by Materials Project

description: Ag2Hg7(P4I3)2 crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. Ag1+ is bonded to two equivalent P1- and four I1- atoms to form AgP2I4 octahedra that share corners with two equivalent AgP2I4 octahedra, corners with two equivalent HgP2I4 octahedra, and corners with four PAgHgP2 trigonal pyramids. The corner-sharing octahedral tilt angles are 52°. Both Ag–P bond lengths are 2.74 Å. There are two shorter (3.03 Å) and two longer (3.12 Å) Ag–I bond lengths. There are three inequivalent Hg+1.71+ sites. In the first Hg+1.71+ site, Hg+1.71+ is bonded in a 7-coordinate geometry to two P1- and five I1- atoms. There are one shorter (2.49 Å) and one longer (2.50 Å) Hg–P bond lengths. There are a spread of Hg–I bond distances ranging from 3.32–3.83 Å. In the second Hg+1.71+ site, Hg+1.71+ is bonded in a 7-coordinate geometry to two P1- and five I1- atoms. There are one shorter (2.49 Å) and one longer (2.50 Å) Hg–P bond lengths. There are a spread of Hg–I bond distances ranging from 3.26–3.81 Å. In the third Hg+1.71+ site, Hg+1.71+ is bonded to two equivalent P1- and four equivalent I1- atoms to form HgP2I4 octahedra that share corners with four equivalent AgP2I4 octahedra and corners with four equivalent PAgHgP2 trigonal pyramids. The corner-sharing octahedral tilt angles are 52°. Both Hg–P bond lengths are 2.69 Å. All Hg–I bond lengths are 3.17 Å. There are three inequivalent P1- sites. In the first P1- site, P1- is bonded to one Ag1+, one Hg+1.71+, and two P1- atoms to form PAgHgP2 trigonal pyramids that share a cornercorner with one AgP2I4 octahedra, a cornercorner with one HgP2I4 octahedra, a cornercorner with one PHg3P tetrahedra, and corners with three PAgHgP2 trigonal pyramids. The corner-sharing octahedra tilt angles range from 54–57°. There are one shorter (2.24 Å) and one longer (2.25 Å) P–P bond lengths. In the second P1- site, P1- is bonded to three Hg+1.71+ and one P1- atom to form corner-sharing PHg3P tetrahedra. The P–P bond length is 2.19 Å. In the third P1- site, P1- is bonded to two Hg+1.71+ and two equivalent P1- atoms to form distorted PHg2P2 trigonal pyramids that share corners with two equivalent AgP2I4 octahedra, a cornercorner with one PHg3P tetrahedra, and corners with three PAgHgP2 trigonal pyramids. The corner-sharing octahedral tilt angles are 58°. There are two inequivalent I1- sites. In the first I1- site, I1- is bonded in a 7-coordinate geometry to one Ag1+ and six Hg+1.71+ atoms. In the second I1- site, I1- is bonded in a 7-coordinate geometry to two equivalent Ag1+ and five Hg+1.71+ atoms.
DOI: 10.17188/1281852
title: Materials Data on LiIn2Ru by Materials Project

description: LiRuIn2 is Heusler structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Li is bonded in a distorted body-centered cubic geometry to six equivalent Ru and eight equivalent In atoms. All Li–Ru bond lengths are 3.26 Å. All Li–In bond lengths are 2.83 Å. Ru is bonded in a distorted body-centered cubic geometry to six equivalent Li and eight equivalent In atoms. All Ru–In bond lengths are 2.83 Å. In is bonded in a body-centered cubic geometry to four equivalent Li and four equivalent Ru atoms.
DOI: 10.17188/1281853
title: Materials Data on UF6 by Materials Project

description: UF6 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four uranium hexafluoride molecules. U6+ is bonded in an octahedral geometry to six F1- atoms. There are five shorter (2.02 Å) and one longer (2.03 Å) U–F bond lengths. There are six inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one U6+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one U6+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one U6+ atom. In the fourth F1- site, F1- is bonded in a single-bond geometry to one U6+ atom. In the fifth F1- site, F1- is bonded in a single-bond geometry to one U6+ atom. In the sixth F1- site, F1- is bonded in a single-bond geometry to one U6+ atom.
DOI: 10.17188/1281854
title: Materials Data on AsXe2O4F9 by Materials Project

description: Xe2O4F3AsF6 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four AsF6 clusters and four Xe2O4F3 clusters. In each AsF6 cluster, As is bonded in an octahedral geometry to six F atoms. There are a spread of As–F bond distances ranging from 1.74–1.80 Å. There are six inequivalent F sites. In the first F site, F is bonded in a single-bond geometry to one As atom. In the second F site, F is bonded in a single-bond geometry to one As atom. In the third F site, F is bonded in a single-bond geometry to one As atom. In the fourth F site, F is bonded in a single-bond geometry to one As atom. In the fifth F site, F is bonded in a single-bond geometry to one As atom. In the sixth F site, F is bonded in a single-bond geometry to one As atom. In each Xe2O4F3 cluster, there are two inequivalent Xe sites. In the first Xe site, Xe is bonded in a distorted see-saw-like geometry to two O and two F atoms. Both Xe–O bond lengths are 1.85 Å. There are one shorter (2.03 Å) and one longer (2.31 Å) Xe–F bond lengths. In the second Xe site, Xe is bonded in a distorted see-saw-like geometry to two O and two F atoms. Both Xe–O bond lengths are 1.85 Å. There are one shorter (2.04 Å) and one longer (2.28 Å) Xe–F bond lengths. There are four inequivalent O sites. In the first O site, O is bonded in a single-bond geometry to one Xe atom. In the second O site, O is bonded in a single-bond geometry to one Xe atom. In the third O site, O is bonded in a single-bond geometry to one Xe atom. In the fourth O site, O is bonded in a single-bond geometry to one Xe atom. There are three inequivalent F sites. In the first F site, F is bonded in a single-bond geometry to one Xe atom. In the second F site, F is bonded in a single-bond geometry to one Xe atom. In the third F site, F is bonded in a linear geometry to two Xe atoms.
DOI: 10.17188/1281855
title: Materials Data on CeAl5Pt3 by Materials Project

description: CePt3Al5 crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Ce is bonded in a 11-coordinate geometry to six Pt and eleven Al atoms. There are a spread of Ce–Pt bond distances ranging from 3.23–3.26 Å. There are a spread of Ce–Al bond distances ranging from 3.23–3.59 Å. There are three inequivalent Pt sites. In the first Pt site, Pt is bonded in a 9-coordinate geometry to two equivalent Ce and seven Al atoms. There are a spread of Pt–Al bond distances ranging from 2.52–2.64 Å. In the second Pt site, Pt is bonded in a 9-coordinate geometry to two equivalent Ce and seven Al atoms. There are a spread of Pt–Al bond distances ranging from 2.50–2.68 Å. In the third Pt site, Pt is bonded in a 9-coordinate geometry to two equivalent Ce and seven Al atoms. There are a spread of Pt–Al bond distances ranging from 2.52–2.73 Å. There are five inequivalent Al sites. In the first Al site, Al is bonded in a 5-coordinate geometry to one Ce and five Pt atoms. In the second Al site, Al is bonded in a 4-coordinate geometry to one Ce and four Pt atoms. In the third Al site, Al is bonded to three equivalent Ce and four Pt atoms to form a mixture of distorted face, edge, and corner-sharing AlCe3Pt4 tetrahedra. In the fourth Al site, Al is bonded to three equivalent Ce and four Pt atoms to form a mixture of distorted face, edge, and corner-sharing AlCe3Pt4 tetrahedra. In the fifth Al site, Al is bonded to three equivalent Ce and four Pt atoms to form a mixture of distorted face, edge, and corner-sharing AlCe3Pt4 tetrahedra.
DOI: 10.17188/1281856
title: Materials Data on Cu4W(SCl)4 by Materials Project

description: Cu2WS4(CuCl2)2 crystallizes in the tetragonal I4/mmm space group. The structure is one-dimensional and consists of two Cu2WS4 ribbons oriented in the (0, 0, 1) direction and two CuCl2 ribbons oriented in the (0, 0, 1) direction. In each Cu2WS4 ribbon, there are two inequivalent W6+ sites. In the first W6+ site, W6+ is bonded in a body-centered cubic geometry to eight equivalent S2- atoms. All W–S bond lengths are 2.56 Å. In the second W6+ site, W6+ is bonded in a body-centered cubic geometry to eight equivalent S2- atoms. All W–S bond lengths are 2.56 Å. Cu+1.50+ is bonded in a 4-coordinate geometry to four equivalent S2- atoms. All Cu–S bond lengths are 2.40 Å. S2- is bonded in a 2-coordinate geometry to two W6+ and two equivalent Cu+1.50+ atoms. In each CuCl2 ribbon, Cu+1.50+ is bonded in a square co-planar geometry to four equivalent Cl1- atoms. All Cu–Cl bond lengths are 2.31 Å. Cl1- is bonded in a bent 120 degrees geometry to two equivalent Cu+1.50+ atoms.