cometadata/datacite-titles-descriptions-related-identifiers huggingface dataset:
DOI: 10.6084/m9.figshare.6318077.v1
title: Alkalinity, inorganic carbon and CO2 flux variability during extreme rainfall years (2010-2011) in two polluted tropical estuaries NE Brazil

description: Abstract The susceptibility of coastal environments to shifts in the biogeochemical cycles of carbon and nutrients driven by anthropogenic pressure and climate change is a real challenge for the scientific community. This paper evaluated the effects of an extreme rainfall event over the nutrients and carbonate parameters in two polluted tropical estuaries. Surface water samples were taken seasonally along a salinity gradient in the Capibaribe and Barra de Jangadas estuaries in order to investigate the spatial and seasonal variability of dissolved nutrients, chlorophyll-a, dissolved oxygen, total alkalinity, inorganic carbon, partial pressure of CO2 (pCO2) and CO2 fluxes. The increased riverine influence caused by the fluvial flooding during the extremely rainy season augmented the nitrogen concentrations in the plumes, which also presented reduced salinity, alkalinity and dissolved oxygen values. In the Capibaribe plume it has also shifted the mean CO2 flux value of - 4.01 mmolC m-2 d-1 during the dry season, to a positive mean flux of + 5.7 mmolC m-2 d-1 during the rainy season. Within the estuaries the BOD5,20 and dissolved phosphorus values were higher during the dry season (p&lt;0.0001), they showed positive correlation with the phytoplanktonic blooms that reached a chl-a value of 85 mg m-3 in the Capibaribe. The high alkalinity found in both estuaries, with mean values between dry and wet seasons respectively from 1808 to 1373 µmol kg-1 in the Capibaribe estuary and 1616 to 1058 µmol kg-1 in Barra de Jangadas estuary, may act as a buffer to the process of coastal acidification due to eutrophication. The increased rivers discharge lead to a greater transport of organic matter and nutrients to the coast, decreasing the oxygen availability and shifting the metabolic status of the estuarine plume to heterotrophic, whereas increased the water quality within the estuaries due the flushing promoted by the extreme rainfall event.
DOI: 10.6084/m9.figshare.6318404.v1
title: Spatial sedimentary distribution, seasonality and the characteristics of organic matter on Fernando de Noronha insular shelf

description: Abstract The present study was conducted in the Fernando de Noronha archipelago (4°S/32°W). The objective is the evaluation of the spatial distribution and seasonal variations in the sediments and sedimentary organic matter in the northern insular shelf of Fernando de Noronha ("Mar de Dentro"). Nineteen surface sediment samples were collected between December 2013, July 2014 and November 2014. The studied methods included analysis of the grain size, coarse fraction, morphoscopy, total organic matter content, calcium carbonate, organic carbon, total nitrogen, sedimentary phosphorus (organic, inorganic and total), elemental ratios (C/N, C/P) and stable isotopic ratios (δ13C-δ15N). The results allowed to infer that there is no seasonal variation in sediment distribution. Whereas, the shelf sediments present a calcareous sandy sedimentary cover (CaCO3≈ 88.3%), predominantly of well-sorted fine sands, with low organic matter content (TOM&lt;2.87%, TOC&lt;4.29%, TP&lt;0.44µmol/g) and are mainly of marine origin (δ13C ≈ -22.17%PDB). As conclusions was observed a spatial variation, where the southwestern part is dominated by gravelly and northeast part is composed for fine sand, conditioned by the bottom morphology, sediments sources and, wave action. The geochemistry showed some stations with relative enrichment in organic matter content (TOC&gt;3.0%; TN&gt;0.4%) of mixed origin (δ13C= -24.5 to -23.0%PDB), which were related to anthropogenic impacts and the biotic and abiotic local processes.
DOI: 10.6084/m9.figshare.6318404
title: Spatial sedimentary distribution, seasonality and the characteristics of organic matter on Fernando de Noronha insular shelf

description: Abstract The present study was conducted in the Fernando de Noronha archipelago (4°S/32°W). The objective is the evaluation of the spatial distribution and seasonal variations in the sediments and sedimentary organic matter in the northern insular shelf of Fernando de Noronha ("Mar de Dentro"). Nineteen surface sediment samples were collected between December 2013, July 2014 and November 2014. The studied methods included analysis of the grain size, coarse fraction, morphoscopy, total organic matter content, calcium carbonate, organic carbon, total nitrogen, sedimentary phosphorus (organic, inorganic and total), elemental ratios (C/N, C/P) and stable isotopic ratios (δ13C-δ15N). The results allowed to infer that there is no seasonal variation in sediment distribution. Whereas, the shelf sediments present a calcareous sandy sedimentary cover (CaCO3≈ 88.3%), predominantly of well-sorted fine sands, with low organic matter content (TOM&lt;2.87%, TOC&lt;4.29%, TP&lt;0.44µmol/g) and are mainly of marine origin (δ13C ≈ -22.17%PDB). As conclusions was observed a spatial variation, where the southwestern part is dominated by gravelly and northeast part is composed for fine sand, conditioned by the bottom morphology, sediments sources and, wave action. The geochemistry showed some stations with relative enrichment in organic matter content (TOC&gt;3.0%; TN&gt;0.4%) of mixed origin (δ13C= -24.5 to -23.0%PDB), which were related to anthropogenic impacts and the biotic and abiotic local processes.
DOI: 10.6084/m9.figshare.14325735.v1
title: Prokaryotic picoplankton distribution within the oxygen minimum zone of the central Mexican Paciﬁc across environmental gradients

description: Abstract Marine picophytoplankton has become an important issue to understand the global ecology of phototrophic forms, due to its wide distribution and contribution to biomass and productivity. We studied the abundance, distribution and signature pigments of the prokaryote picophytoplankters Prochlorococcus and Synechococcus during an oceanographic cruise (26 April to 7 May, 2011) in the central Mexican Paciﬁc, a relatively poorly-known oxygen minimum zone (OMZ), and the eﬀect of three environmental gradients. Prochlorococcus and Synechococcus abundances were comparable with those found in other tropical areas (0.17 to 30.37 X 104 cells mL-1, and 0.9 to 30.97 X 104 cells mL-1, respectively). Prochlorococcus abundances reached highest numbers in deeper waters, often coinciding with the second deep in situ ﬂuorescence (and chlorophyll α) maxima, at oceanic stations, below the nitratecline, whereas Synechococcus abundances were higher at subsurface waters and its concentration maxima usually coincided with the subsurface in situ ﬂuorescence maxima, with slightly higher abundances in coastal stations. Statistical analyses support signiﬁcantly these results. Distribution of divinyl-chlorophyll α was erratic along the water column and occasionally coincided with the deep in situ ﬂuorescence maxima, whereas the distribution of zeaxanthin usually followed that of chlorophyll α and the abundances of Synechococcus, and peaked together. These results are similar to those previously found in the study area and in more temperate zones, and also to the general trend in OMZ, but conﬁrm that the second deep chlorophyll α maxima are attributed to high Prochlorococcus densities. We additionally found the abundance and distribution of Prochlorococcus and Synechococcus strongly driven by the environmental gradients observed.
DOI: 10.6084/m9.figshare.14325735
title: Prokaryotic picoplankton distribution within the oxygen minimum zone of the central Mexican Paciﬁc across environmental gradients

description: Abstract Marine picophytoplankton has become an important issue to understand the global ecology of phototrophic forms, due to its wide distribution and contribution to biomass and productivity. We studied the abundance, distribution and signature pigments of the prokaryote picophytoplankters Prochlorococcus and Synechococcus during an oceanographic cruise (26 April to 7 May, 2011) in the central Mexican Paciﬁc, a relatively poorly-known oxygen minimum zone (OMZ), and the eﬀect of three environmental gradients. Prochlorococcus and Synechococcus abundances were comparable with those found in other tropical areas (0.17 to 30.37 X 104 cells mL-1, and 0.9 to 30.97 X 104 cells mL-1, respectively). Prochlorococcus abundances reached highest numbers in deeper waters, often coinciding with the second deep in situ ﬂuorescence (and chlorophyll α) maxima, at oceanic stations, below the nitratecline, whereas Synechococcus abundances were higher at subsurface waters and its concentration maxima usually coincided with the subsurface in situ ﬂuorescence maxima, with slightly higher abundances in coastal stations. Statistical analyses support signiﬁcantly these results. Distribution of divinyl-chlorophyll α was erratic along the water column and occasionally coincided with the deep in situ ﬂuorescence maxima, whereas the distribution of zeaxanthin usually followed that of chlorophyll α and the abundances of Synechococcus, and peaked together. These results are similar to those previously found in the study area and in more temperate zones, and also to the general trend in OMZ, but conﬁrm that the second deep chlorophyll α maxima are attributed to high Prochlorococcus densities. We additionally found the abundance and distribution of Prochlorococcus and Synechococcus strongly driven by the environmental gradients observed.
DOI: 10.6084/m9.figshare.14325738
title: Citogenotoxic response of juvenile cobia Rachycentron canadum (Linnaeus, 1766) reared in two different systems

description: Abstract Aquaculture production is continuously growing worldwide, and marine fish farming in Brazil is still in its infancy. Intensive farming conditions may cause physiological stress to the cultured organism, which can be evaluated by citogenotoxic biomarkers. The aim of this study was to assess the genotoxic effect of the rearing conditions in red blood cells of juvenile cobia Rachycentron canadum by using comet assay and micronucleus and other nuclear abnormalities assay. Juvenile cobia were reared for 13 weeks in indoor tank with open water circulation and in near shore cage. The comet assay and the nuclear abnormalities assay detected higher DNA damage and higher nuclear abnormalities frequency in erythrocytes of fish reared in the indoor tank. Results showed that two methods are complementary. Additionally, cobia were injected with ß-naphthoflavone (BNF) at concentrations of 2mgkg-1 and 10mgkg-1 in laboratory controlled conditions, and maintained for 7 days in separate tanks to better understand the response mechanisms of this species to a toxic substance. The comet assay did not detect any significant differences between BNF injected and control fish, whereas nuclear abnormalities assay showed significant differences between BNF injected and the control groups. The damages identified by the comet assay are repairable breaks in the DNA strands, whereas nuclear abnormalities may be permanent. Possibly the period of maintenance after injection was enough to clean BNF from the organisms and to repair the breaks in the DNA strands. As cobia seems to respond very well to genotoxic elements, comet assay and nuclear abnormalities assay would be useful tools to monitor farming conditions.
DOI: 10.6084/m9.figshare.14325738.v1
title: Citogenotoxic response of juvenile cobia Rachycentron canadum (Linnaeus, 1766) reared in two different systems

description: Abstract Aquaculture production is continuously growing worldwide, and marine fish farming in Brazil is still in its infancy. Intensive farming conditions may cause physiological stress to the cultured organism, which can be evaluated by citogenotoxic biomarkers. The aim of this study was to assess the genotoxic effect of the rearing conditions in red blood cells of juvenile cobia Rachycentron canadum by using comet assay and micronucleus and other nuclear abnormalities assay. Juvenile cobia were reared for 13 weeks in indoor tank with open water circulation and in near shore cage. The comet assay and the nuclear abnormalities assay detected higher DNA damage and higher nuclear abnormalities frequency in erythrocytes of fish reared in the indoor tank. Results showed that two methods are complementary. Additionally, cobia were injected with ß-naphthoflavone (BNF) at concentrations of 2mgkg-1 and 10mgkg-1 in laboratory controlled conditions, and maintained for 7 days in separate tanks to better understand the response mechanisms of this species to a toxic substance. The comet assay did not detect any significant differences between BNF injected and control fish, whereas nuclear abnormalities assay showed significant differences between BNF injected and the control groups. The damages identified by the comet assay are repairable breaks in the DNA strands, whereas nuclear abnormalities may be permanent. Possibly the period of maintenance after injection was enough to clean BNF from the organisms and to repair the breaks in the DNA strands. As cobia seems to respond very well to genotoxic elements, comet assay and nuclear abnormalities assay would be useful tools to monitor farming conditions.
DOI: 10.6084/m9.figshare.14325740.v1
title: Morphodynamics of a wave dominated embayed beach on an irregular rocky coastline

description: Abstract Wave-dominated embayed beaches on irregular rocky coastlines are highly appreciated for their landscapes and tourism potential. Yet our understanding about the interaction of the oceanographic processes with the geological inheritance in this type of beaches still needs further investigation to better understand their natural balance. In this study, we apply the classical approach of morphodynamics to describe for the first time the variations in the Boiçucanga beach morphology, an embayed beach located in São Sebastião City on an irregular rocky coastline that is well known for its beautiful beaches embedded in the valleys of Serra do Mar. Field surveys were performed over 15 months, between April 2008 and September 2009, seeking to evaluate the interactions among the morphology, sediments and hydrodynamic characteristics at Boiçucanga. All data generated during the field surveys have supported the application of the following morphodynamic models: Classification of morphological beach stages [O]; Number of nearshore sandbars [B*]; Relative tide range [RTR]; Beach exposure on embayed coasts [Ro/a and ß]; and Embayment beach scaling parameter [d] to determine the geomorphological behavior of the beach on monthly and annual time scales. From these models, Boiçucanga is classified as a deep embayed beach exposed to high-energy waves, with a predominant reflective profile, which favors the development of beach cusps and topographically controlled rip currents. The combined results of the field observations and applied models allowed us to better understand the role of geological heritage in the two morphodynamic signatures found at the same beach arch. For future studies, we will focus on numerical models to increase the understanding of the hydrodynamic processes that govern the sediment transport in Boiçucanga.
DOI: 10.6084/m9.figshare.14325740
title: Morphodynamics of a wave dominated embayed beach on an irregular rocky coastline

description: Abstract Wave-dominated embayed beaches on irregular rocky coastlines are highly appreciated for their landscapes and tourism potential. Yet our understanding about the interaction of the oceanographic processes with the geological inheritance in this type of beaches still needs further investigation to better understand their natural balance. In this study, we apply the classical approach of morphodynamics to describe for the first time the variations in the Boiçucanga beach morphology, an embayed beach located in São Sebastião City on an irregular rocky coastline that is well known for its beautiful beaches embedded in the valleys of Serra do Mar. Field surveys were performed over 15 months, between April 2008 and September 2009, seeking to evaluate the interactions among the morphology, sediments and hydrodynamic characteristics at Boiçucanga. All data generated during the field surveys have supported the application of the following morphodynamic models: Classification of morphological beach stages [O]; Number of nearshore sandbars [B*]; Relative tide range [RTR]; Beach exposure on embayed coasts [Ro/a and ß]; and Embayment beach scaling parameter [d] to determine the geomorphological behavior of the beach on monthly and annual time scales. From these models, Boiçucanga is classified as a deep embayed beach exposed to high-energy waves, with a predominant reflective profile, which favors the development of beach cusps and topographically controlled rip currents. The combined results of the field observations and applied models allowed us to better understand the role of geological heritage in the two morphodynamic signatures found at the same beach arch. For future studies, we will focus on numerical models to increase the understanding of the hydrodynamic processes that govern the sediment transport in Boiçucanga.
DOI: 10.6084/m9.figshare.14325741.v1
title: Modelling the effects of sea-level rise and sediment budget in coastal retreat at Hermenegildo Beach, Southern Brazil

description: Abstract Climate change effects such as accelerated sea-level rise, wave climate alteration and disturbances on sediment-budgets are anticipated to lead to a range of adverse impacts in coastal regions around the world. A rise in sea-level is expected to cause shoreline recession, and a sediment deficit can have a similar effect. Since large uncertainties exist in relation to sea-level rise rates and sediment budgets, it is relevant to determine how sensitive the coast is to each of these disturbances. In this context, this paper provides a quantitative evaluation of each of these parameters in terms of modeled coastal recession through risk-based assessments using an aggregated coastal model, the DRanSTM (Dilating Random Shoreface Translation Model). In each separate computer simulation, a sediment budget and a sea-level scenario were set for an erosional coastal stretch: Hermenegildo Beach, Rio Grande do Sul state in southern Brazil. Effects of changes in wave climate were not directly considered in this study. However, indirect measures of such changes should be reflected on coastal sediment budgets. Simulation results demonstrate that under present-day sea-level rise rates, sediment deficit exerts control over coastal recession. Conversely, under the higher forecasted sea-level rise for the year 2100, mean shoreline recession will be dictated by sea-level rise, considering historical sediment deficit will be sustained.
DOI: 10.6084/m9.figshare.14325741
title: Modelling the effects of sea-level rise and sediment budget in coastal retreat at Hermenegildo Beach, Southern Brazil

description: Abstract Climate change effects such as accelerated sea-level rise, wave climate alteration and disturbances on sediment-budgets are anticipated to lead to a range of adverse impacts in coastal regions around the world. A rise in sea-level is expected to cause shoreline recession, and a sediment deficit can have a similar effect. Since large uncertainties exist in relation to sea-level rise rates and sediment budgets, it is relevant to determine how sensitive the coast is to each of these disturbances. In this context, this paper provides a quantitative evaluation of each of these parameters in terms of modeled coastal recession through risk-based assessments using an aggregated coastal model, the DRanSTM (Dilating Random Shoreface Translation Model). In each separate computer simulation, a sediment budget and a sea-level scenario were set for an erosional coastal stretch: Hermenegildo Beach, Rio Grande do Sul state in southern Brazil. Effects of changes in wave climate were not directly considered in this study. However, indirect measures of such changes should be reflected on coastal sediment budgets. Simulation results demonstrate that under present-day sea-level rise rates, sediment deficit exerts control over coastal recession. Conversely, under the higher forecasted sea-level rise for the year 2100, mean shoreline recession will be dictated by sea-level rise, considering historical sediment deficit will be sustained.
DOI: 10.6084/m9.figshare.14325743
title: Investigation of persistent coherent structures along the Southern Brazilian Shelf

description: Abstract The freshwater-influenced region of the Patos Lagoon discharge to the Southern Brazilian Shelf (SBS) is a region of complex fluid dynamics. Seasoning and synoptic variable winds and coastal current conditions create an alternating flow pattern. The aim of this paper was to investigate the occurrence of persistent coherent structures in this environment. A numerical approach was chosen to describe the main hydrodynamic features of the region during a climatological year. The open-source finite-element code Telemac-Mascaret was applied to the three-dimensional domain. In addition the two-equation k-epsilon model described the turbulence mechanisms. The presence of persistent high-turbulent structures was identified within the study area. These occur as a strong curvilinear disturbance characterized by higher turbulent production and dissipation rates, which increase local mixture. As a result, upward circulation flow was observed, which may be due to irregularities in bottom topography associated with wind-induced stress forces. These results increase the information about the circulation structures of the study area by means of numerical modelling analysis.
DOI: 10.6084/m9.figshare.14325743.v1
title: Investigation of persistent coherent structures along the Southern Brazilian Shelf

description: Abstract The freshwater-influenced region of the Patos Lagoon discharge to the Southern Brazilian Shelf (SBS) is a region of complex fluid dynamics. Seasoning and synoptic variable winds and coastal current conditions create an alternating flow pattern. The aim of this paper was to investigate the occurrence of persistent coherent structures in this environment. A numerical approach was chosen to describe the main hydrodynamic features of the region during a climatological year. The open-source finite-element code Telemac-Mascaret was applied to the three-dimensional domain. In addition the two-equation k-epsilon model described the turbulence mechanisms. The presence of persistent high-turbulent structures was identified within the study area. These occur as a strong curvilinear disturbance characterized by higher turbulent production and dissipation rates, which increase local mixture. As a result, upward circulation flow was observed, which may be due to irregularities in bottom topography associated with wind-induced stress forces. These results increase the information about the circulation structures of the study area by means of numerical modelling analysis.