DOI: 10.17188/1283459
title: Materials Data on Ag8Ge3O10 by Materials Project

description: Ag8Ge3O10 crystallizes in the monoclinic Pc space group. The structure is three-dimensional. there are thirty-two inequivalent Ag1+ sites. In the first Ag1+ site, Ag1+ is bonded in a 4-coordinate geometry to four O2- atoms. There are a spread of Ag–O bond distances ranging from 2.22–2.72 Å. In the second Ag1+ site, Ag1+ is bonded in a distorted trigonal planar geometry to three O2- atoms. There are a spread of Ag–O bond distances ranging from 2.32–2.57 Å. In the third Ag1+ site, Ag1+ is bonded in a 4-coordinate geometry to four O2- atoms. There are a spread of Ag–O bond distances ranging from 2.29–2.55 Å. In the fourth Ag1+ site, Ag1+ is bonded in a 4-coordinate geometry to four O2- atoms. There are a spread of Ag–O bond distances ranging from 2.34–2.69 Å. In the fifth Ag1+ site, Ag1+ is bonded in a 4-coordinate geometry to four O2- atoms. There are a spread of Ag–O bond distances ranging from 2.24–2.83 Å. In the sixth Ag1+ site, Ag1+ is bonded in a 4-coordinate geometry to four O2- atoms. There are a spread of Ag–O bond distances ranging from 2.32–2.43 Å. In the seventh Ag1+ site, Ag1+ is bonded in a 4-coordinate geometry to four O2- atoms. There are a spread of Ag–O bond distances ranging from 2.28–2.64 Å. In the eighth Ag1+ site, Ag1+ is bonded in a 4-coordinate geometry to four O2- atoms. There are a spread of Ag–O bond distances ranging from 2.30–2.78 Å. In the ninth Ag1+ site, Ag1+ is bonded in a 3-coordinate geometry to three O2- atoms. There are two shorter (2.21 Å) and one longer (2.59 Å) Ag–O bond lengths. In the tenth Ag1+ site, Ag1+ is bonded in a 4-coordinate geometry to four O2- atoms. There are a spread of Ag–O bond distances ranging from 2.30–2.78 Å. In the eleventh Ag1+ site, Ag1+ is bonded in a 4-coordinate geometry to four O2- atoms. There are a spread of Ag–O bond distances ranging from 2.21–2.79 Å. In the twelfth Ag1+ site, Ag1+ is bonded to five O2- atoms to form distorted AgO5 trigonal bipyramids that share corners with five GeO4 tetrahedra. There are a spread of Ag–O bond distances ranging from 2.35–2.72 Å. In the thirteenth Ag1+ site, Ag1+ is bonded in a 5-coordinate geometry to five O2- atoms. There are a spread of Ag–O bond distances ranging from 2.26–2.88 Å. In the fourteenth Ag1+ site, Ag1+ is bonded in a 4-coordinate geometry to four O2- atoms. There are three shorter (2.35 Å) and one longer (2.66 Å) Ag–O bond lengths. In the fifteenth Ag1+ site, Ag1+ is bonded in a 3-coordinate geometry to three O2- atoms. There are a spread of Ag–O bond distances ranging from 2.32–2.36 Å. In the sixteenth Ag1+ site, Ag1+ is bonded in a 3-coordinate geometry to three O2- atoms. There are a spread of Ag–O bond distances ranging from 2.27–2.43 Å. In the seventeenth Ag1+ site, Ag1+ is bonded in a 3-coordinate geometry to three O2- atoms. There are a spread of Ag–O bond distances ranging from 2.26–2.54 Å. In the eighteenth Ag1+ site, Ag1+ is bonded in a distorted trigonal planar geometry to three O2- atoms. There are a spread of Ag–O bond distances ranging from 2.31–2.39 Å. In the nineteenth Ag1+ site, Ag1+ is bonded in a 3-coordinate geometry to three O2- atoms. There are a spread of Ag–O bond distances ranging from 2.25–2.42 Å. In the twentieth Ag1+ site, Ag1+ is bonded in a distorted see-saw-like geometry to four O2- atoms. There are a spread of Ag–O bond distances ranging from 2.29–2.63 Å. In the twenty-first Ag1+ site, Ag1+ is bonded in a 3-coordinate geometry to four O2- atoms. There are a spread of Ag–O bond distances ranging from 2.28–2.92 Å. In the twenty-second Ag1+ site, Ag1+ is bonded in a 4-coordinate geometry to four O2- atoms. There are a spread of Ag–O bond distances ranging from 2.28–2.85 Å. In the twenty-third Ag1+ site, Ag1+ is bonded in a 4-coordinate geometry to four O2- atoms. There are a spread of Ag–O bond distances ranging from 2.20–2.80 Å. In the twenty-fourth Ag1+ site, Ag1+ is bonded in a distorted trigonal planar geometry to three O2- atoms. There are a spread of Ag–O bond distances ranging from 2.32–2.53 Å. In the twenty-fifth Ag1+ site, Ag1+ is bonded in a distorted see-saw-like geometry to four O2- atoms. There are a spread of Ag–O bond distances ranging from 2.27–2.65 Å. In the twenty-sixth Ag1+ site, Ag1+ is bonded in a 2-coordinate geometry to three O2- atoms. There are a spread of Ag–O bond distances ranging from 2.18–2.91 Å. In the twenty-seventh Ag1+ site, Ag1+ is bonded in a 4-coordinate geometry to four O2- atoms. There are a spread of Ag–O bond distances ranging from 2.21–2.88 Å. In the twenty-eighth Ag1+ site, Ag1+ is bonded in a 4-coordinate geometry to four O2- atoms. There are a spread of Ag–O bond distances ranging from 2.17–2.75 Å. In the twenty-ninth Ag1+ site, Ag1+ is bonded in a 3-coordinate geometry to three O2- atoms. There are a spread of Ag–O bond distances ranging from 2.14–2.68 Å. In the thirtieth Ag1+ site, Ag1+ is bonded in a 4-coordinate geometry to four O2- atoms. There are a spread of Ag–O bond distances ranging from 2.26–2.69 Å. In the thirty-first Ag1+ site, Ag1+ is bonded in a 4-coordinate geometry to four O2- atoms. There are a spread of Ag–O bond distances ranging from 2.22–2.66 Å. In the thirty-second Ag1+ site, Ag1+ is bonded in a 4-coordinate geometry to four O2- atoms. There are a spread of Ag–O bond distances ranging from 2.21–2.66 Å. There are twelve inequivalent Ge4+ sites. In the first Ge4+ site, Ge4+ is bonded to four O2- atoms to form GeO4 tetrahedra that share a cornercorner with one GeO4 tetrahedra and a cornercorner with one AgO5 trigonal bipyramid. There are a spread of Ge–O bond distances ranging from 1.76–1.82 Å. In the second Ge4+ site, Ge4+ is bonded to four O2- atoms to form corner-sharing GeO4 tetrahedra. There are a spread of Ge–O bond distances ranging from 1.77–1.83 Å. In the third Ge4+ site, Ge4+ is bonded to four O2- atoms to form GeO4 tetrahedra that share a cornercorner with one GeO4 tetrahedra and a cornercorner with one AgO5 trigonal bipyramid. There are a spread of Ge–O bond distances ranging from 1.77–1.83 Å. In the fourth Ge4+ site, Ge4+ is bonded to four O2- atoms to form corner-sharing GeO4 tetrahedra. There are a spread of Ge–O bond distances ranging from 1.74–1.82 Å. In the fifth Ge4+ site, Ge4+ is bonded to four O2- atoms to form corner-sharing GeO4 tetrahedra. There are a spread of Ge–O bond distances ranging from 1.74–1.83 Å. In the sixth Ge4+ site, Ge4+ is bonded to four O2- atoms to form GeO4 tetrahedra that share corners with two GeO4 tetrahedra and a cornercorner with one AgO5 trigonal bipyramid. There are a spread of Ge–O bond distances ranging from 1.76–1.81 Å. In the seventh Ge4+ site, Ge4+ is bonded to four O2- atoms to form corner-sharing GeO4 tetrahedra. There are a spread of Ge–O bond distances ranging from 1.76–1.81 Å. In the eighth Ge4+ site, Ge4+ is bonded to four O2- atoms to form corner-sharing GeO4 tetrahedra. There are a spread of Ge–O bond distances ranging from 1.77–1.83 Å. In the ninth Ge4+ site, Ge4+ is bonded to four O2- atoms to form corner-sharing GeO4 tetrahedra. There are a spread of Ge–O bond distances ranging from 1.76–1.83 Å. In the tenth Ge4+ site, Ge4+ is bonded to four O2- atoms to form corner-sharing GeO4 tetrahedra. There are a spread of Ge–O bond distances ranging from 1.77–1.81 Å. In the eleventh Ge4+ site, Ge4+ is bonded to four O2- atoms to form GeO4 tetrahedra that share a cornercorner with one GeO4 tetrahedra and a cornercorner with one AgO5 trigonal bipyramid. There are a spread of Ge–O bond distances ranging from 1.76–1.83 Å. In the twelfth Ge4+ site, Ge4+ is bonded to four O2- atoms to form GeO4 tetrahedra that share corners with two GeO4 tetrahedra and a cornercorner with one AgO5 trigonal bipyramid. There are a spread of Ge–O bond distances ranging from 1.76–1.82 Å. There are forty inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted tetrahedral geometry to three Ag1+ and one Ge4+ atom. In the second O2- site, O2- is bonded in a 4-coordinate geometry to three Ag1+ and one Ge4+ atom. In the third O2- site, O2- is bonded in a 2-coordinate geometry to two Ge4+ atoms. In the fourth O2- site, O2- is bonded in a 1-coordinate geometry to four Ag1+ and one Ge4+ atom. In the fifth O2- site, O2- is bonded in a 5-coordinate geometry to four Ag1+ and one Ge4+ atom. In the sixth O2- site, O2- is bonded in a distorted tetrahedral geometry to three Ag1+ and one Ge4+ atom. In the seventh O2- site, O2- is bonded in a 4-coordinate geometry to three Ag1+ and one Ge4+ atom. In the eighth O2- site, O2- is bonded in a distorted bent 120 degrees geometry to two Ag1+ and two Ge4+ atoms. In the ninth O2- site, O2- is bonded in a 1-coordinate geometry to four Ag1+ and one Ge4+ atom. In the tenth O2- site, O2- is bonded in a 4-coordinate geometry to three Ag1+ and one Ge4+ atom. In the eleventh O2- site, O2- is bonded in a 4-coordinate geometry to three Ag1+ and one Ge4+ atom. In the twelfth O2- site, O2- is bonded in a 1-coordinate geometry to three Ag1+ and one Ge4+ atom. In the thirteenth O2- site, O2- is bonded in a 3-coordinate geometry to four Ag1+ and one Ge4+ atom. In the fourteenth O2- site, O2- is bonded in a distorted tetrahedral geometry to three Ag1+ and one Ge4+ atom. In the fifteenth O2- site, O2- is bonded in a distorted tetrahedral geometry to three Ag1+ and one Ge4+ atom. In the sixteenth O2- site, O2- is bonded in a distorted bent 120 degrees geometry to two Ag1+ and two Ge4+ atoms. In the seventeenth O2- site, O2- is bonded in a 2-coordinate geometry to two Ag1+ and two Ge4+ atoms. In the eighteenth O2- site, O2- is bonded in a 3-coordinate geometry to four Ag1+ and one Ge4+ atom. In the nineteenth O2- site, O2- is bonded in a 4-coordinate geometry to three Ag1+ and one Ge4+ atom. In the twentieth O2- site, O2- is bonded in a 1-coordinate geometry to three Ag1+ and one Ge4+ atom. In the twenty-first O2- site, O2- is bonded in a 1-coordinate geometry to four Ag1+ and one Ge4+ atom. In the twenty-second O2- site, O2- is bonded in a 2-coordinate geometry to one Ag1+ and two Ge4+ atoms. In the twenty-third O2- site, O2- is bonded in a 5-coordinate geometry to four Ag1+ and one Ge4+ atom. In the twenty-fourth O2- site, O2- is bonded in a 1-coordinate geometry to three Ag1+ and one Ge4+ atom. In the twenty-fifth O2- site, O2- is bonded in a distorted bent 120 degrees geometry to two Ag1+ and two Ge4+ atoms. In the twenty-sixth O2- site, O2- is bonded in a 2-coordinate geometry to two Ag1+ and two Ge4+ atoms. In the twenty-seventh O2- site, O2- is bonded in a 4-coordinate geometry to three Ag1+ and one Ge4+ atom. In the twenty-eighth O2- site, O2- is bonded in a 4-coordinate geometry to three Ag1+ and one Ge4+ atom. In the twenty-ninth O2- site, O2- is bonded in a 5-coordinate geometry to four Ag1+ and one Ge4+ atom. In the thirtieth O2- site, O2- is bonded in a 5-coordinate geometry to four Ag1+ and one Ge4+ atom. In the thirty-first O2- site, O2- is bonded in a 4-coordinate geometry to three Ag1+ and one Ge4+ atom. In the thirty-second O2- site, O2- is bonded in a distorted bent 120 degrees geometry to two Ag1+ and two Ge4+ atoms. In the thirty-third O2- site, O2- is bonded in a 4-coordinate geometry to three Ag1+ and one Ge4+ atom. In the thirty-fourth O2- site, O2- is bonded in a 4-coordinate geometry to three Ag1+ and one Ge4+ atom. In the thirty-fifth O2- site, O2- is bonded in a 5-coordinate geometry to four Ag1+ and one Ge4+ atom. In the thirty-sixth O2- site, O2- is bonded in a 4-coordinate geometry to three Ag1+ and one Ge4+ atom. In the thirty-seventh O2- site, O2- is bonded in a 4-coordinate geometry to three Ag1+ and one Ge4+ atom. In the thirty-eighth O2- site, O2- is bonded in a 5-coordinate geometry to four Ag1+ and one Ge4+ atom. In the thirty-ninth O2- site, O2- is bonded in a 4-coordinate geometry to three Ag1+ and one Ge4+ atom. In the fortieth O2- site, O2- is bonded in a 4-coordinate geometry to three Ag1+ and one Ge4+ atom.