DOI: 10.48420/26556775.v1
title: Data for <b>Investigating Silicatein Selectivity and Specificity in Silicon-Oxygen Bond Condensation and Metathesis</b>

description: Spreadsheets containing the numerical data in Excel and Origin format.<b>Data including variance expressed as standard deviations.</b><b>File 1. Silyl phenoxy and octyloxy</b><b> condensation</b><b>s</b> contain the numerical data for Table 1 and Figure S1 in the paper. It contains the data for the area under the curve for the chromatographic peaks corresponding to triethyloctyloxy silyl ether (TES-OOc), triethylphenoxy silyl ether (TES-OPh) and disiloxane (TES)<sub>2</sub>O respectively where product conversion was plotted against time.<b>File 2. C</b><b>ompetition reaction </b>contains the numerical data for Figure 1 and Table S1 in the paper. It contains the data for the area under the curve for the chromatographic peaks corresponding to triethyloctyloxy silyl ether (TES-OOc) and triethylphenoxy silyl ether (TES-OPh) respectively where product conversion was plotted against time.<b>File 3. Additives and small molecules reactions</b> contain the numerical data for Figure 3 in the paper. It contains the data for the area under the curve for the chromatographic peaks corresponding to triethylphenoxy silyl ether (TES-OPh) and disiloxane respectively where product conversion was plotted against lyophilised additives and small molecule catalysts.<b>File 4. S</b><b>ilyl transfer reaction</b><b>s </b>contain the numerical data for Figure 4 and Table S3 in the paper. It contains the data for the area under the curve for the chromatographic peak corresponding to triethylphenoxy silyl ether (TES-OPh), trimethylphenoxy silyl ether (TMS-OPh) and disiloxane respectively where product conversion was plotted against time.<b>Data including variance expressed as standard error of the mean.</b><b>File 5. </b><b>Silyl phenoxy and octyloxy</b><b> condensation</b><b>s</b> contain the numerical data for Table 1 and Figure S1 in the paper. It contains the data for the area under the curve for the chromatographic peaks corresponding to triethyloctyloxy silyl ether (TES-OOc), triethylphenoxy silyl ether (TES-OPh) and disiloxane (TES)<sub>2</sub>O respectively where product conversion was plotted against time.<b>File 6. C</b><b>ompetition reaction </b>contains the numerical data for Figure 1 and Table S1 in the paper. It contains the data for the area under the curve for the chromatographic peaks corresponding to triethyloctyloxy silyl ether (TES-OOc) and triethylphenoxy silyl ether (TES-OPh) respectively where product conversion was plotted against time.<b>File 7. Temperature p</b><b>rofile reaction</b> contains the numerical data for Figure 3 in the paper. It contains the data for the area under the curve for the chromatographic peaks corresponding to triethylphenoxy silyl ether (TES-OPh) and disiloxane (TES)<sub>2</sub>O respectively where product conversion was plotted against lyophilised additives and small molecule catalysts.<b>File 8</b><b>. Additives and small molecules reactions</b> contain the numerical data for Figure 3 in the paper. It contains the data for the area under the curve for the chromatographic peaks corresponding to triethylphenoxy silyl ether (TES-OPh) and disiloxane respectively where product conversion was plotted against lyophilised additives and small molecule catalysts.<b>File 9</b><b>. S</b><b>ilyl transfer reaction</b><b>s </b>contain the numerical data for Figure 4 and Table S3 in the paper. It contains the data for the area under the curve for the chromatographic peak corresponding to triethylphenoxy silyl ether (TES-OPh), trimethylphenoxy silyl ether (TMS-OPh) and disiloxane respectively where product conversion was plotted against time.