cometadata/datacite-rtg-text-other-reclassification-records huggingface dataset:
In vitro Studies on Proliferation and Production of Cytokine and IgG by Human PBMCs Stimulated with Polysaccharide Extract from Plants Endemic to Gabon
Creators: name: Mengome, Line Edwige
name: Voxeur, Aline
name: Akue, Jean Paul
name: Lerouge, Patrice
Publisher: name: Zenodo
Year: 2021
Subjects: Pectins
hemicelluloses
cytokines
IgG
human PBMCs
endemic plants
Gabon

description: Polysaccharides were extracted from seven plants endemic to Gabon to study their potential immunological activities. Peripheral blood mononuclear cell (PBMC) (5 × 105 cells/mL) proliferation, cytokine and immunoglobulin G (IgG) assays were performed after stimulation with different concentrations of polysaccharide fractions compared with lipopolysaccharides (LPS) and concanavalin A (ConA) from healthy volunteers. The culture supernatants were used for cytokine and IgG detection by enzyme-linked immunosorbent assay (ELISA). The results show that pectin and hemicellulose extracts from Uvaria klainei, Petersianthus macrocarpus, Trichoscypha addonii, Aphanocalyx microphyllus, Librevillea klaineana, Neochevalierodendron stephanii and Scorodophloeus zenkeri induced production levels that were variable from one individual to another for IL-12 (3–40 pg/mL), IL-10 (6–443 pg/mL), IL-6 (7–370 pg/mL), GM-CSF (3–170 pg/mL) and IFN-γ (5–80 pg/mL). Only hemicelluloses from Aphanocalyx microphyllus produce a small amount of IgG (OD = 0.034), while the proliferation of cells stimulated with these polysaccharides increased up to 318% above the proliferation of unstimulated cells. However, this proliferation of PBMCs was abolished when the pectin of some of these plants was treated with endopolygalacturonase (p < 0.05), but the trend of cytokine synthesis remained the same, both before and after enzymatic treatment or saponification. This study suggests that these polysaccharides stimulate cells in a structure-dependent manner. The rhamnogalacturonan-I (RGI) fragment alone was not able to induce the proliferation of PBMC. This study confirms the immunostimulatory properties of polysaccharides.
Density functional perturbation theory within non-collinear magnetism
Creators: name: Ricci, Fabio
name: Prokhorenko, Sergei
name: Torrent, Marc
name: Verstraete, Matthieu J.
name: Bousquet, Eric
Publisher: name: arXiv
Year: 2019
Subjects: subject: Computational Physics (physics.comp-ph)
subject: Strongly Correlated Electrons (cond-mat.str-el)
subject: FOS: Physical sciences

description: We extend the density functional perturbation theory formalism to the case of non-collinear magnetism. The main problem comes with the exchange-correlation (XC) potential derivatives, which are the only ones that are affected by the non-collinearity of the system. Most of the present XC functionals are constructed at the collinear level, such that the off-diagonal (containing magnetization densities along $x$ and $y$ directions) derivatives cannot be calculated simply in the non-collinear framework. To solve this problem, we consider here possibilities to transform the non-collinear XC derivatives to a local collinear basis, where the $z$ axis is aligned with the local magnetization at each point. The two methods we explore are i) expanding the spin rotation matrix as a Taylor series, ii) evaluating explicitly the XC for the local density approximation through an analytical expression of the expansion terms. We compare the two methods and describe their practical implementation. We show their application for atomic displacement and electric field perturbations at the second order, within the norm-conserving pseudopotential methods.
ENERGETIK MUAMMOLAR YECHIMINING NAZARIY VA AMALIY JIHATLARI
Creators: name: Xidirov, Bobir Baxirovich
Publisher: name: Zenodo
Year: 2025

description: Energetik muammolar zamonaviy dunyodagi muhim masalalardan biridir. Ushbu maqola energetik muammolarni tahlil qilishda matematik yondoshuvlarning rolini o‘rganishga qaratilgan. Asosiy diqqat matematik modellash, optimallashtirish usullari va stoxastik yondoshuvlarning qo‘llanilishiga qaratiladi. Maqolada matematik yondoshuvlarning energetik samaradorlikni oshirish va resurslardan samarali foydalanishdagi ahamiyati muhokama qilinadi.
Havelockia oraneae Martins & Souto 2019
Creators: name: Martins, Luciana
name: Marques, Alexandre Oliveira
name: Fukuda, Marcelo Veronesi
name: Tavares, Marcos
Publisher: name: Zenodo
Year: 2022
Subjects: Biodiversity
Taxonomy
Animalia
Echinodermata
Holothuroidea
Dendrochirotida
Sclerodactylidae
Havelockia
Havelockia oraneae

description: Havelockia oraneae Martins & Souto, 2019 Fig. 2G
 Havelockia oraneae Martins & Souto, 2019: 1128-1130, figs. 1-2, Table 1.
 Type locality: Todos os Santos Bay (13°02′S, 38°37′W), Salvador, Bahia, Brazil.
 Type material: Holotype – MZUSP 1636: 12 mm long, Todos os Santos Bay (13°02′S, 38°37′W), Salvador, Bahia, Brazil, 16 m, 05.iv.1997. Paratype – MZUSP 1637: 1 specimen, 70 mm long, same collection data as holotype. UFBA 1641: 1 specimen, 10 mm long, Guarajuba beach (12°45′S, 38°05′W), CamaÇari, Bahia, Brazil, 26 m, 20.vii.2005.
 Distribution: Todos os Santos Bay, Salvador, Bahia, Brazil.
description: Published as part of Martins, Luciana, Marques, Alexandre Oliveira, Fukuda, Marcelo Veronesi & Tavares, Marcos, 2022, An annotated catalogue of Echinodermata types in the Museu de Zoologia, Universidade de São Paulo, Brazil, pp. 1-11 in Papéis Avulsos de Zoologia 62 on page 6, DOI: 10.11606/1807-0205/2022.62.015, http://zenodo.org/record/7177498
Screened and Unscreened Phases in Sedimenting Suspensions
Creators: name: Levine, Alex
name: Ramaswamy, Sriram
name: Frey, Erwin
name: Bruinsma, Robijn
Publisher: name: arXiv
Year: 1998
Subjects: subject: Soft Condensed Matter (cond-mat.soft)
subject: Statistical Mechanics (cond-mat.stat-mech)
subject: FOS: Physical sciences

description: A coarse-grained stochastic hydrodynamical description of velocity and concentration fluctuations in steadily sedimenting suspensions is constructed, and analyzed using self-consistent and renormalization group methods. We find that there exists a dynamical, non-equilibrium phase transition from an "unscreened" phase in which we recover the Caflisch-Luke (R.E. Caflisch and J.H.C. Luke, Phys. Fluids 28, 759 (1985)) divergence of the velocity variance to a "screened" phase where the velocity fluctuations have a finite correlation length growing as $ϕ^{-1/3}$ where $ϕ$ is the particle volume fraction, in agreement with Segrè et. al. (Phys. Rev. Lett. 79, 2574 (1997)) and the velocity variance is independent of system size. Detailed predictions are made for the correlation function in both phases and at the transition.
description: 4 pages, revtex 1 figure
Gravitational Waves from Compact Dark Objects in Neutron Stars
Creators: name: Horowitz, C. J.
name: Reddy, Sanjay
Publisher: name: arXiv
Year: 2019
Subjects: subject: High Energy Astrophysical Phenomena (astro-ph.HE)
subject: General Relativity and Quantum Cosmology (gr-qc)
subject: High Energy Physics - Phenomenology (hep-ph)
subject: Nuclear Theory (nucl-th)
subject: FOS: Physical sciences

description: Dark matter could be composed of compact dark objects (CDOs). We find that the oscillation of CDOs inside neutron stars can be a detectable source of gravitational waves (GWs). The GW strain amplitude depends on the mass of the CDO, and its frequency is typically in the range 3-5 kHz as determined by the central density of the star. In the best cases, LIGO may be sensitive to CDO masses greater than or of order $10^{-8}$ solar masses.
description: 5 pages, 1 figure, Phys. Rev. Lett. in press
Zamarada ignicosta subsp. ignicosta Prout L. B. 1912
Creators: name: Mbata, Keith J.
name: Prins, Jurate De
Publisher: name: Zenodo
Year: 2023
Subjects: Biodiversity
Taxonomy
Animalia
Arthropoda
Insecta
Lepidoptera
Geometridae
Zamarada
Zamarada ignicosta
Zamarada ignicosta ignicosta prout l. b., 1912a

description: Zamarada ignicosta ignicosta Prout L. B., 1912a
COMMON NAME(S): Geometer moth.
SYNONYM(S): Zamarada hemimeres Prout L. B., 1915; Zamarada pyrocinctoides Strand, 1917b.
IUCN STATUS: Not Evaluated (NE).
DISTRIBUTION: Zambia, Zimbabwe.
LOCALITY IN ZAMBIA: Lusaka and Chirundu, in Lusaka Province.
LARVAL HOSTPLANT(S): Unknown.
SOURCES: African Moths 2019; De Prins & De Prins 2022; Fletcher 1974.
description: Published as part of Mbata, Keith J. & Prins, Jurate De, 2023, Annotated checklist of moths of Zambia (Insecta: Lepidoptera), pp. 1-503 in Zootaxa 5354 (1) on page 234, DOI: 10.11646/zootaxa.5354.1.1, http://zenodo.org/record/10130434
Breakage mechanics for cemented granular materials in surface-reactive environments
Creators: name: biot-bazant, figshare admin
name: Shen, Xianda
name: Buscarnera, Giuseppe
Publisher: name: The Biot-Bazant Conference
Year: 2021
Subjects: subject: Mechanics
subject: 91402 Geomechanics and Resources Geotechnical Engineering
subject: FOS: Environmental engineering

description: This publication is part of the proceedings of the Biot-Bažant Conference on Engineering Mechanics and Physics of Porous Materials, which took place virtually on June 1-3, 2021. It contains a one-page abstract and the video of the talk that was given at the conference.
Additional file 1: of The association of county-level socioeconomic factors with individual tobacco and alcohol use: a longitudinal study of U.S. adults
Creators: name: Hamad, Rita
name: Brown, Daniel
name: Basu, Sanjay
Publisher: name: figshare
Year: 2019
Subjects: subject: Medicine
subject: Biotechnology
subject: Evolutionary Biology
subject: FOS: Biological sciences
subject: Sociology
subject: FOS: Sociology
subject: 69999 Biological Sciences not elsewhere classified
subject: Developmental Biology
subject: Cancer
subject: Science Policy
subject: 111714 Mental Health
subject: FOS: Health sciences

description: Table S1. Ordinary Least Squares Analysis of the Association between Lagged County-Level Characteristics and Individual Health Behaviors, U.S. National Longitudinal Study of Youth, 1992â 2012. (DOCX 23 kb)
Psolidium lonchostinum Martins & Tavares 2020
Creators: name: Martins, Luciana
name: Marques, Alexandre Oliveira
name: Fukuda, Marcelo Veronesi
name: Tavares, Marcos
Publisher: name: Zenodo
Year: 2022
Subjects: Biodiversity
Taxonomy
Animalia
Echinodermata
Holothuroidea
Dendrochirotida
Psolidae
Psolidium
Psolidium lonchostinum

description: Psolidium lonchostinum Martins & Tavares, 2020 Fig. 3E
 Psolidium lonchostinum Martins & Tavares, 2020: 2-5, figs. 1-3.
 Type locality: Rio Grande do Sul, Brazil.
 Type material: Holotype – MZUSP 744: 8.3 mm long, Rio GrandedoSul (33°41′S, 51°32′W), Brazil, 200 m, 02.iv.1998. Paratypes – MZUSP 743: 7 specimens, 7-7.5 mm long, São Paulo (24°20′S, 44°09′W), Brazil, 258 m, 10.i.1998; MZUSP 591: 8 specimens, 6-8.2 mm long, São Paulo (24°20′S, 44°09′W), Brazil, 258 m, 10.i.1998.
 Distribution: Southeastern coast of Brazil (São Paulo and Rio Grande do Sul).
description: Published as part of Martins, Luciana, Marques, Alexandre Oliveira, Fukuda, Marcelo Veronesi & Tavares, Marcos, 2022, An annotated catalogue of Echinodermata types in the Museu de Zoologia, Universidade de São Paulo, Brazil, pp. 1-11 in Papéis Avulsos de Zoologia 62 on page 8, DOI: 10.11606/1807-0205/2022.62.015, http://zenodo.org/record/7177498
The long-wavelength behaviour of the exchange-correlation kernel in the Kohn-Sham theory of periodic systems
Creators: name: Ghosez, Ph.
name: Gonze, X.
name: Godby, R. W.
Publisher: name: arXiv
Year: 1997
Subjects: subject: Materials Science (cond-mat.mtrl-sci)
subject: FOS: Physical sciences

description: The polarization-dependence of the exchange-correlation (XC) energy functional of periodic insulators within Kohn-Sham (KS) density-functional theory requires a ${\cal O} (1/q^2)$ divergence in the XC kernel for small vectors q. This behaviour, exemplified for a one-dimensional model semiconductor, is also observed when an insulator happens to be described as a KS metal, or vice-versa. Although it can occur in the exchange-only kernel, it is not found in the usual local, semi-local or even non-local approximations to KS theory. We also show that the test-charge and electronic definitions of the macroscopic dielectric constant differ from one another in exact KS theory, but are equivalent in the above-mentioned approximations.
description: 7 pages, 1 figure
RAQAMLI IQTISODIYOT SHAROITIDA YOSHLAR TADBIRKORLIGINI RIVOJLANTIRISH
Creators: name: Tolipov, Umidjon
Publisher: name: Zenodo
Year: 2024

description: Ushbu maqolada tez rivojlanayotgan raqamli iqtisodiyot sharoitida yoshlar tadbirkorligini rivojlantirish bilan bog'liq muammolar va imkoniyatlar ko'rib chiqiladi. Adabiyotlarni keng qamrovli tahlil qilish orqali maqola yoshlar tadbirkorligining hozirgi holatini o'rganadi, uning o'sishiga to'sqinlik qiladigan asosiy masalalarni aniqlaydi va ushbu muammolarni hal qilish usullarini taklif qiladi. Natijalar bo'limida muvaffaqiyatli tashabbuslar va ularning yoshlar tadbirkorligini rivojlantirishga ta'siri ta'kidlangan bo'lsa, munozara bo'limida siyosat va ta'limga ta'siri tanqidiy ko'rib chiqilgan. Maqola raqamli asrda yoshlar tadbirkorligi uchun qulay muhit yaratish bo'yicha tushuncha va takliflar bilan yakunlanadi.
Additional file 4: of CaLRR-RLK1, a novel RD receptor-like kinase from Capsicum annuum and transcriptionally activated by CaHDZ27, act as positive regulator in Ralstonia solanacearum resistance
Creators: name: Mou, Shaoliang
name: Gao, Feng
name: Shen, Lei
name: Yang, Sheng
name: He, Weihong
name: Cheng, Wei
name: Wu, Yang
name: He, Shuilin
Publisher: name: figshare
Year: 2019
Subjects: subject: Biochemistry
subject: Microbiology
subject: FOS: Biological sciences
subject: Evolutionary Biology
subject: Environmental Sciences not elsewhere classified
subject: Ecology
subject: Sociology
subject: FOS: Sociology
subject: Immunology
subject: FOS: Clinical medicine
subject: Biological Sciences not elsewhere classified
subject: Developmental Biology
subject: Inorganic Chemistry
subject: FOS: Chemical sciences
subject: Mental Health
subject: Hematology
subject: Plant Biology

description: Table S1. Pepper primers used for qPCR in this study. Table S2. Tobacco primers used for qPCR in this study. Table S3. Primers used in these experiments. (DOCX 21 kb)
Psolus thandari Martins & Tavares 2019
Creators: name: Martins, Luciana
name: Marques, Alexandre Oliveira
name: Fukuda, Marcelo Veronesi
name: Tavares, Marcos
Publisher: name: Zenodo
Year: 2022
Subjects: Biodiversity
Taxonomy
Animalia
Echinodermata
Holothuroidea
Dendrochirotida
Psolidae
Psolus
Psolus thandari

description: Psolus thandari Martins & Tavares, 2019 Fig. 3C
 Psolus thandari Martins & Tavares, 2019a: 538-542, figs. 5-6, Table 1.
 Type locality: Campos Basin, Rio de Janeiro, Brazil.
 Type material: Holotype – MZUSP 593: 5.7 mm long. Campos Basin (21°41′S, 40°20′W), Rio de Janeiro, Brazil, 44 m, xii.1991 to i.1992. Paratypes – MZUSP 1634: 3 specimens, 4.5-5 mm long, same collection data as holotype.
 Distribution: Campos Basin, Rio de Janeiro, Brazil.
description: Published as part of Martins, Luciana, Marques, Alexandre Oliveira, Fukuda, Marcelo Veronesi & Tavares, Marcos, 2022, An annotated catalogue of Echinodermata types in the Museu de Zoologia, Universidade de São Paulo, Brazil, pp. 1-11 in Papéis Avulsos de Zoologia 62 on page 8, DOI: 10.11606/1807-0205/2022.62.015, http://zenodo.org/record/7177498
Untitled Item
Creators: name: biot-bazant, figshare admin
name: Shen, Xianda
name: Buscarnera, Giuseppe
Publisher: name: The Biot-Bazant Conference
Year: 2021
Subjects: subject: Mechanics
subject: 91402 Geomechanics and Resources Geotechnical Engineering
subject: FOS: Environmental engineering

description: This publication is part of the proceedings of the Biot-Bažant Conference on Engineering Mechanics and Physics of Porous Materials, which took place virtually on June 1-3, 2021. It contains a one-page abstract and the video of the talk that was given at the conference.
Additional file 2: of The association of county-level socioeconomic factors with individual tobacco and alcohol use: a longitudinal study of U.S. adults
Creators: name: Hamad, Rita
name: Brown, Daniel
name: Basu, Sanjay
Publisher: name: figshare
Year: 2019
Subjects: subject: Medicine
subject: Biotechnology
subject: Evolutionary Biology
subject: FOS: Biological sciences
subject: Sociology
subject: FOS: Sociology
subject: 69999 Biological Sciences not elsewhere classified
subject: Developmental Biology
subject: Science Policy
subject: 111714 Mental Health
subject: FOS: Health sciences

description: Table S2. Fixed Effects Analysis of the Association between Lagged County-Level Characteristics and Individual Health Behaviors, U.S. National Longitudinal Study of Youth, 1992â 2012. (DOCX 23 kb)
Effect of sintering temperature under high pressure in the uperconductivity for MgB2
Creators: name: Jung, C. U.
name: Park, Min-Seok
name: Kang, W. N.
name: Kim, Mun-Seog
name: Kim, Kijoon H. P.
name: Lee, S. Y.
name: Lee, Sung-Ik
Publisher: name: arXiv
Year: 2001
Subjects: subject: Superconductivity (cond-mat.supr-con)
subject: FOS: Physical sciences

description: We report the effect of the sintering temperature on the superconductivity of MgB2 pellets prepared under a high pressure of 3 GPa. The superconducting properties of the non-heated MgB2 in this high pressure were poor. However, as the sintering temperature increased, the superconducting properties were vastly enhanced, which was shown by the narrow transition width for the resistivity and the low-field magnetizations. This shows that heat treatment under high pressure is essential to improve superconducting properties. These changes were found to be closely related to changes in the surface morphology observed using scanning electron microscopy.
description: 3 Pages including 3 figures
CEN-CENELEC Project Team 1, Mandate BC-IT-226, Final Results of Phase 1, Planning Tasks
Creators: name: Level-7 Ltd, Centennial Court, Bracknell, Berkshire, UK
name: Rayner, Dave
name: Tenckhoff, Jürgen T
name: Martin, Neil
name: Dittmar, Lars
name: European Commission DG XIII
Publisher: name: Zenodo
Year: 1992

description: Dieser Bericht dokumentiert die Ergebnisse der ersten Phase des CEN-CENELEC Project Team 1 (Mandate BC-IT-226), das sich mit der Anerkennung von Testberichten und Zertifikaten für IT&T im Europäischen Binnenmarkt befasst. Die Untersuchung konzentriert sich auf die Harmonisierung von Test- und Konformitätsbewertungsverfahren, um technische Handelshemmnisse abzubauen.

Jürgen Tenckhoff wirkte als Teilnehmer an den Tasks B/4 & B/5 mit, die sich speziell mit der gegenseitigen Anerkennung von Testberichten und Zertifikaten für IT&T-Produkte beschäftigten. Die Arbeit umfasste eine Analyse bestehender Verfahren, die Identifikation regulatorischer Herausforderungen und die Entwicklung eines Rahmens zur Verbesserung der Marktzugänglichkeit in der EU.

🔹 Englisch:"This report contains the introduction to the full study and the introduction to the specific tasks B/4 & B/5, in which I participated. The complete study is available in paper form in my personal archive."

🔹 Deutsch (optional als Zusatz):"Dieser Bericht enthält die Einführung der vollständigen Studie sowie die Einführung zu den spezifischen Aufgaben B/4 & B/5, an denen ich mitgewirkt habe. Die komplette Studie befindet sich als gedruckte Version in meinem persönlichen Archiv."

 
description: For related work, see also: Jürgen Tenckhoff (1988). Establishment of Conformance Test Services in Europe, Computer Standards & Interfaces, DOI: 10.1016/0920-5489(88)90043-8
Additional file 3: of Extensive nuclear reprogramming and endoreduplication in mature leaf during floral induction
Creators: name: Prete, Stefania
name: Molitor, Anne
name: Charif, Delphine
name: Bessoltane, Nadia
name: Soubigou-Taconnat, Ludivine
name: CĂŠcile Guichard
name: VĂŠronique Brunaud
name: Granier, Fabienne
name: Fransz, Paul
name: ValĂŠrie Gaudin
Publisher: name: figshare
Year: 2019
Subjects: subject: Cell Biology
subject: Genetics
subject: FOS: Biological sciences
subject: Molecular Biology
subject: 69999 Biological Sciences not elsewhere classified
subject: Developmental Biology
subject: Plant Biology

description: Figure S3. RNA-Seq experiments and expressed gene distributions. (a) Library sizes of the biological replicates. (b) Read mapping for the different time points and biological replicates. (c) Distribution of the expressed genes in the genomes. (d) Differentially expressed genes (DEGs) and Venn diagram with the three main comparisons. (e) Distribution of the expressed genes in the main gene classes. (PDF 194 kb)
Additional file 4: of Extensive nuclear reprogramming and endoreduplication in mature leaf during floral induction
Creators: name: Prete, Stefania
name: Molitor, Anne
name: Charif, Delphine
name: Bessoltane, Nadia
name: Soubigou-Taconnat, Ludivine
name: CĂŠcile Guichard
name: VĂŠronique Brunaud
name: Granier, Fabienne
name: Fransz, Paul
name: ValĂŠrie Gaudin
Publisher: name: figshare
Year: 2019
Subjects: subject: Cell Biology
subject: Molecular Biology
subject: Ecology
subject: FOS: Biological sciences
subject: 69999 Biological Sciences not elsewhere classified
subject: Developmental Biology

description: Figure S4. Analysis of lncRNAs. (a) Resources used to construct the lncTU dataset. (b) lncTUs differentially expressed for each comparison using the Benjamini-Hochberg (BH) test. (PDF 51 kb)
Psolus tommasi Martins & Tavares 2019
Creators: name: Martins, Luciana
name: Marques, Alexandre Oliveira
name: Fukuda, Marcelo Veronesi
name: Tavares, Marcos
Publisher: name: Zenodo
Year: 2022
Subjects: Biodiversity
Taxonomy
Animalia
Echinodermata
Holothuroidea
Dendrochirotida
Psolidae
Psolus
Psolus tommasi

description: Psolus tommasi Martins & Tavares, 2019 Fig. 3D
 Psolus tommasi Martins & Tavares, 2019a: 536-538, figs. 3-4, Table 1.
 Type locality: São Paulo, Brazil.
 Type material: Holotype – MZUSP 583: 12 mm long, São Paulo (24°20′S, 44°09′W), Brazil, 258 m.
 Distribution: São Paulo, Brazil.
description: Published as part of Martins, Luciana, Marques, Alexandre Oliveira, Fukuda, Marcelo Veronesi & Tavares, Marcos, 2022, An annotated catalogue of Echinodermata types in the Museu de Zoologia, Universidade de São Paulo, Brazil, pp. 1-11 in Papéis Avulsos de Zoologia 62 on page 8, DOI: 10.11606/1807-0205/2022.62.015, http://zenodo.org/record/7177498
Cyclotron resonance in a two-dimensional electron gas with long-range randomness
Creators: name: Fogler, M. M.
name: Shklovskii, B. I.
Publisher: name: arXiv
Year: 1998
Subjects: subject: Mesoscale and Nanoscale Physics (cond-mat.mes-hall)
subject: FOS: Physical sciences

description: We show that the the cyclotron resonance in a two-dimensional electron gas has non-trivial properties if the correlation length of the disorder is larger than the de Broglie wavelength: (a) the lineshape assumes three different forms in strong, intermediate, and weak magnetic fields (b) at the transition from the intermediate to the weak fields the linewidth suddenly collapses due to an explosive growth in the fraction of electrons with a diffusive-type dynamics.
description: A few typos corrected
Monte Carlo phonon transport simulations in hierarchically disordered silicon nanostructures
Creators: name: Chakraborty, Dhritiman
name: Foster, Samuel
name: Neophytou, Neophytos
Publisher: name: arXiv
Year: 2018
Subjects: subject: Mesoscale and Nanoscale Physics (cond-mat.mes-hall)
subject: FOS: Physical sciences

description: Hierarchical material nanostructuring is considered to be a very promising direction for high performance thermoelectric materials. In this work we investigate thermal transport in hierarchically nanostructured silicon. We consider the combined presence of nanocrystallinity and nanopores, arranged under both ordered and randomized positions and sizes, by solving the Boltzmann transport equation using the Monte Carlo method. We show that nanocrystalline boundaries degrade the thermal conductivity more drastically when the average grain size becomes smaller than the average phonon mean free path. The introduction of pores degrades the thermal conductivity even further. Its effect, however, is significantly more severe when the pore sizes and positions are randomized, as randomization results in regions of higher porosity along the phonon transport direction, which introduce significant thermal resistance. We show that randomization acts as a large increase in the overall effective porosity. Using our simulations, we show that existing compact nanocrystalline and nanoporous theoretical models describe thermal conductivity accurately under uniform nanostructured conditions, but overestimate it in randomized geometries. We propose extensions to these models that accurately predict the thermal conductivity of randomized nanoporous materials based solely on a few geometrical features. Finally, we show that the new compact models introduced can be used within Matthiessens rule to combine scattering from different geometrical features within approximately 10 per cent accuracy.
description: 47 pages, 16 figures
Additional file 1: of Temporary transvenous diaphragm pacing vs. standard of care for weaning from mechanical ventilation: study protocol for a randomized trial
Creators: name: Evans, Douglas
name: Shure, Deborah
name: Clark, Linda
name: Criner, Gerard
name: Dres, Martin
name: Abreu, Marcelo
name: Laghi, Franco
name: McDonagh, David
name: Petrof, Basil
name: Nelson, Teresa
name: Similowski, Thomas
Publisher: name: figshare
Year: 2019
Subjects: Medicine
Science Policy

description: SPIRIT 2013 checklist: recommended items to address in a clinical trial protocol and related documents. (DOC 124 kb)
A lower bound on the tree-width of graphs with irrelevant vertices
Creators: name: Adler, Isolde
name: Krause, Philipp Klaus
Publisher: name: arXiv
Year: 2019
Subjects: subject: Discrete Mathematics (cs.DM)
subject: Combinatorics (math.CO)
subject: FOS: Computer and information sciences
subject: FOS: Mathematics

description: For their famous algorithm for the disjoint paths problem, Robertson and Seymour proved that there is a function $f$ such that if the tree-width of a graph $G$ with $k$ pairs of terminals is at least $f(k)$, then $G$ contains a solution-irrelevant vertex (Graph Minors. XXII., JCTB 2012). We give a single-exponential lower bound on $f$. This bound even holds for planar graphs.
Thermal analysis and crystal growth of doped Nb$_2$O$_5$
Creators: name: Hidde, Julia
name: Guguschev, Christo
name: Klimm, Detlef
Publisher: name: arXiv
Year: 2018
Subjects: subject: Materials Science (cond-mat.mtrl-sci)
subject: FOS: Physical sciences

description: The systems Nb$_2$O$_5$-Ta$_2$O$_5$ and Nb$_2$O$_5$-V$_2$O$_5$ were investigated using thermal analysis, X-ray powder diffraction and thermodynamic simulations. Solid solution formation is possible for both systems; furthermore, both contain one intermediate compound, VNb$_9$O$_{25}$ or Ta$_2$Nb$_4$O$_{15}$, respectively. Phase relationships for pure niobium(V)-oxide and tantalum(V)-oxide were studied under ambient pressure. It was found that both compounds can occur in two stable solid modifications. For niobium(V)-oxide this are the monoclinic high-temperature modification (H-Nb$_2$O$_5$) and an orthorhombic low-temperature modification (T-Nb$_2$O$_5$) and for tantalum(V)-oxide a tetragonal high-temperature form ($α$-Ta$_2$O$_5$) and an orthorhombic low-temperature form ($β$-Ta$_2$O$_5$). Based on these results, crystal growth experiments with various compositions from both systems were carried out using the optical floating zone (OFZ) technique.
description: 15 pages, 10 figures, 6 tables, submitted to J. Crystal Growth
Gravitational Wave Experiments and Early Universe Cosmology
Creators: name: Maggiore, Michele
Publisher: name: arXiv
Year: 1999
Subjects: subject: General Relativity and Quantum Cosmology (gr-qc)
subject: Astrophysics (astro-ph)
subject: High Energy Physics - Phenomenology (hep-ph)
subject: High Energy Physics - Theory (hep-th)
subject: FOS: Physical sciences

description: Gravitational-wave experiments with interferometers and with resonant masses can search for stochastic backgrounds of gravitational waves of cosmological origin. We review both experimental and theoretical aspects of the search for these backgrounds. We give a pedagogical derivation of the various relations that characterize the response of a detector to a stochastic background. We discuss the sensitivities of the large interferometers under constructions (LIGO, VIRGO, GEO600, TAMA300, AIGO) or planned (Avdanced LIGO, LISA) and of the presently operating resonant bars, and we give the sensitivities for various two-detectors correlations. We examine the existing limits on the energy density in gravitational waves from nucleosynthesis, COBE and pulsars, and their effects on theoretical predictions. We discuss general theoretical principles for order-of-magnitude estimates of cosmological production mechanisms, and then we turn to specific theoretical predictions from inflation, string cosmology, phase transitions, cosmic strings and other mechanisms. We finally compare with the stochastic backgrounds of astrophysical origin.
description: 99 pages, Latex, 17 figures. To appear in Physics Report. v4: conceptual changes in sect. 7.4
Experimental Wireless Communication Using Chaotic Baseband Waveform
Creators: name: Yao, Jun-Liang
name: Sun, Yu-Zhe
name: Ren, Hai-Peng
name: Grebogi, Celso
Publisher: name: arXiv
Year: 2019
Subjects: subject: Signal Processing (eess.SP)
subject: Chaotic Dynamics (nlin.CD)
subject: FOS: Electrical engineering, electronic engineering, information engineering
subject: FOS: Physical sciences

description: Some new properties of the chaotic signal have been implemented in communication system applications recently. However, due to the broadband property of the chaotic signal, it is very difficult for a practical transducer or antenna to convert such a broadband signal into a signal that would be suitable for practical band-limited wireless channel. Thus, the use of chaos property to improve the performance of conventional communication system without changing the system configuration becomes a critical issue in communication with chaos. In this paper, chaotic baseband waveform generated by a chaotic shaping filter is used to show that this difficulty can be overcome. The generated continuous-time chaotic waveform is proven to be topologically conjugate to a symbolic sequence, allowing the encoding of arbitrary information sequence into the chaotic waveform. A finite impulse response filter is used to replace the impulse control in order to encode information into the chaotic signal, simplifying the algorithm for high speed communication. A wireless communication system is being proposed using the chaotic signal as the baseband waveform, which is compatible with the general wireless communication platform. The matched filter and decoding method, using chaos properties, enhance the communication system performance. The Bit Error Rate (BER) and computational complexity performances of the proposed wireless communication system are analyzed and compared with the conventional wireless systems. The results show that the proposed chaotic baseband waveform of our wireless communication method has better BER performance in both the static and time-varying wireless channels. The experimental results, based on the commonly-used wireless open-access research platform, show that the BER of the proposed method is superior to the conventional method under a practical wireless multipath channel.
description: 15 pages, 17 figures
Additional file 2: of Extensive nuclear reprogramming and endoreduplication in mature leaf during floral induction
Creators: name: Prete, Stefania
name: Molitor, Anne
name: Charif, Delphine
name: Bessoltane, Nadia
name: Soubigou-Taconnat, Ludivine
name: Guichard, Cécile
name: Brunaud, Véronique
name: Granier, Fabienne
name: Fransz, Paul
name: Gaudin, Valérie
Publisher: name: figshare
Year: 2019
Subjects: subject: Cell Biology
subject: Pharmacology
subject: Ecology
subject: FOS: Biological sciences
subject: Plant Biology

description: Figure S2. Growth of rosette leaves in response to SD or a SD-LD switch. (a) Measurements of the total rosette leaf areas. (b) Area measurement of the first six leaves. Col-0 plants were grown in SD for 4 weeks, then kept in SD (continuous line) or transferred in LD (dash line). Two biological replicates were performed with 10 plants, each. Experimental values are mean ± SEM. (PDF 70 kb)
Additional file 1: of Extensive nuclear reprogramming and endoreduplication in mature leaf during floral induction
Creators: name: Prete, Stefania
name: Molitor, Anne
name: Charif, Delphine
name: Bessoltane, Nadia
name: Soubigou-Taconnat, Ludivine
name: Guichard, Cécile
name: Brunaud, Véronique
name: Granier, Fabienne
name: Fransz, Paul
name: Gaudin, Valérie
Publisher: name: figshare
Year: 2019
Subjects: subject: Medicine
subject: Cell Biology
subject: Ecology
subject: FOS: Biological sciences
subject: Developmental Biology
subject: Plant Biology

description: Figure S1. Characterization of the SD-LD switch. (a) Flowering time according to the number of weeks in SD. Rosette and cauline leaves were recorded on plants when the first flowers appeared. The bolting time was quantified when the stem was 0.5 cm high from sowing. Three biological replicates were performed with 12 plants, each. (b) Expression of the AP1::GUS reporter gene in the apical shoots of plants grown 4 weeks in SD, and then transferred to LD. Day after transfer (dat). (PDF 772 kb)
Additional file 20: of Extensive nuclear reprogramming and endoreduplication in mature leaf during floral induction
Creators: name: Prete, Stefania
name: Molitor, Anne
name: Charif, Delphine
name: Bessoltane, Nadia
name: Soubigou-Taconnat, Ludivine
name: Guichard, Cécile
name: Brunaud, Véronique
name: Granier, Fabienne
name: Fransz, Paul
name: Gaudin, Valérie
Publisher: name: figshare
Year: 2019
Subjects: subject: Biochemistry
subject: Cell Biology
subject: Genetics
subject: FOS: Biological sciences
subject: Molecular Biology
subject: Developmental Biology
subject: Cancer

description: Figure S8. Expression of MAF5 and its antisense lncTU located in the 3′ end of MAF5 region at T0, T2 and T3. (a) Fold changes. (b) Browser snapshot showing the expression profiles. BR1: biological replicate number 1. (PDF 77 kb)
Additional file 3: of Intratumoral 18F-FLT infusion in metabolic targeted radiotherapy
Creators: name: Thititip Tippayamontri
name: GuĂŠrin, Brigitte
name: RenĂŠ Ouellet
name: Otman Sarrhini
name: Rousseau, Jacques
name: Lecomte, Roger
name: Benoit Paquette
name: LĂŠon Sanche
Publisher: name: figshare
Year: 2019
Subjects: subject: Space Science
subject: Pharmacology
subject: 39999 Chemical Sciences not elsewhere classified
subject: FOS: Chemical sciences
subject: Sociology
subject: FOS: Sociology
subject: 69999 Biological Sciences not elsewhere classified
subject: FOS: Biological sciences
subject: 110309 Infectious Diseases
subject: FOS: Health sciences

description: Supplementary information. (DOCX 13 kb)
ENERGETIKA: MUAMMOLAR, YECHIMLAR VA ISTIQBOLLAR
Creators: name: Saipova, Dilnoza Shuxratovna
name: Usmonova, Dilnoza Hadjimuratovna
Publisher: name: Zenodo
Year: 2025

description: Mazkur maqolada energetika sohasidagi muammolar, yechimlar va istiqbollar ko‘rib chiqiladi. O‘zbekiston energetika ishlab chiqarish va uzatilish jarayonlarida ko‘plab ekologik, iqtisodiy va texnologik muammolarga duch kelmoqda. Muammolar sifatida cheklangan tabiiy resurslar, ekologik ifloslanish, uzatilishdagi energiya yo‘qotishlari va eski texnologiyalar ko‘rib chiqiladi. Maqolada samaradorlikni ko‘tarish va ekologik masalalarni hal qilish yo‘llari sifatida qayta tiklanadigan energiya manbalarini joriy qilish, modern texnologiyalarni ko‘paytirish va xalqaro hamkorlik ko‘rsatiladi. Shuningdek, kelajak istiqbollarida "Smart grid" texnologiyasi, ekologik energetika tashabbuslari va ta'lim dasturlari orqali yoshlarni energetika sohasiga tayyorlash zarurligi ta'kidlanadi.
Recent Comparative Analysis of the Phytochemicals, Proximate and Mineral Compositions of Scent Leaf (Ocimum gratissimum) and Bitter Leaf (Vernonia amygdalina) Leaves
Creators: name: Nkoli M. Mgbemena
name: Ngozi F. Amako
Publisher: name: Zenodo
Year: 2021
Subjects: Plant
food
bitter leaf
scent leaf
nutrients

description: Medicinal- plant -based drugs have the advantage of being simple, effective and have broad spectrum activity. An ethno-botanical and ubiquitous plant serves as rich resources of natural drugs for research development. Ocimum gratissimum (fam. Lamiaceae) ‘Scent leaf’ and Vernonia amygdalina (fam. Asteraceae) ‘Bitter leaf’ are commonly consumed vegetables in Southern Nigeria. O. gratissimum is used by the ‘Igbos’ of South East Nigeria to flavor soups and stews while it is popular with the ‘Yorubas’ of South West Nigeria for treatment of stomach disorders. V. amygdalina is a well known vegetable in West Africa used as both food and for its pharmaceutical properties. The enormous use of these vegetables in the diet motivated the present study whereby the food compositions, mineral constituents and the phytochemicals of the two vegetables were determined. Qualitative analysis, of the aqueous extracts, revealed the presence of saponins, terpenoids, tannins, flavonoids, steroids, alkaloids, phenolics and anthraquinones in both vegetables. Generally V. amygdalina contained higher quantities of secondary metabolites, saponin which was reported as the highest amount was 5.71±0.12 mg/g and 3.52±0.01 mg/g followed by terpenoids 5.64±0.11 mg/g and 3.40±0.11 mg/g in V. amygdalina and O. gratissimum respectively. There is however a minute amount of anthraquinone in the two vegetables. Proximate analysis and macro elements were determined using their various standard methods. The results of proximate analysis revealed the presence of moisture (12.28 ± 0.02% and 10.01± 0.01%) protein (35.37±0.11% and 22.20±0.02%) and total ash (6.00±0.20% and 5.75±0.10%) each in V. amygdalina and O. gratisimum respectively. The following minerals were present calcium, magnesium, potassium, sodium, iron, copper and zinc, with zinc being in the highest concentration (46.80± 0.03 mg/kg and 58.00±0.12 mg/kg) followed by copper (9.45±0.11 mg/kg and 16.60 ± 0.03 mg/kg) each in V. amygdalina and O. gratissimum respectively. There are higher values of phytochemicals and food components in V. amygdalina while O. gratissimum had higher mineral contents. These two vegetables are potential sources of components for complementary medicine.
Direct measurement of the Seebeck coefficient in a Kondo-correlated single-quantum-dot transistor
Creators: name: Dutta, B.
name: Majidi, D.
name: Corral, A. Garcia
name: Erdman, P.
name: Florens, S.
name: Costi, T.
name: Courtois, H.
name: Winkelmann, C. B.
Publisher: name: arXiv
Year: 2018
Subjects: subject: Mesoscale and Nanoscale Physics (cond-mat.mes-hall)
subject: FOS: Physical sciences

description: We report on the first measurement of the Seebeck coefficient in a tunnel-contacted and gate-tunable individual single-quantum dot junction in the Kondo regime, fabricated using the electromigration technique. This fundamental thermoelectric parameter is obtained by directly monitoring the magnitude of the voltage induced in response to a temperature difference across the junction, while keeping a zero net tunneling current through the device. In contrast to bulk materials and single molecules probed in a scanning tunneling microscopy (STM) configuration, investigating the thermopower in nanoscale electronic transistors benefits from the electric tunability to showcase prominent quantum effects. Here, striking sign changes of the Seebeck coefficient are induced by varying the temperature, depending on the spin configuration in the quantum dot. The comparison with Numerical Renormalization Group (NRG) calculations demonstrate that the tunneling density of states is generically asymmetric around the Fermi level in the leads, both in the cotunneling and Kondo regimes.
Psolidium nanoplax Martins & Tavares 2020
Creators: name: Martins, Luciana
name: Marques, Alexandre Oliveira
name: Fukuda, Marcelo Veronesi
name: Tavares, Marcos
Publisher: name: Zenodo
Year: 2022
Subjects: Biodiversity
Taxonomy
Animalia
Echinodermata
Holothuroidea
Dendrochirotida
Psolidae
Psolidium
Psolidium nanoplax

description: Psolidium nanoplax Martins & Tavares, 2020 Fig. 3F
 Psolidium nanoplax Martins & Tavares, 2020: 6, figs. 4-5.
 Type locality: Campos Basin, Rio de Janeiro, Brazil.
 Type material: Holotype – MZUSP 589: 11 mm long, Campos Basin (21°41′S, 40°20′W), Rio de Janeiro, Brazil, 44 m, xii.1991 to i.1992. Paratypes – MZUSP 592: 1 specimen, 8.5 mm long. Same collection data as holotype.
 Distribution: Campos Basin, Rio de Janeiro, Brazil.
description: Published as part of Martins, Luciana, Marques, Alexandre Oliveira, Fukuda, Marcelo Veronesi & Tavares, Marcos, 2022, An annotated catalogue of Echinodermata types in the Museu de Zoologia, Universidade de São Paulo, Brazil, pp. 1-11 in Papéis Avulsos de Zoologia 62 on page 8, DOI: 10.11606/1807-0205/2022.62.015, http://zenodo.org/record/7177498
Bilayer Splitting in the Electronic Structure of Heavily Overdoped Bi2Sr2CaCu2O8+d
Creators: name: Feng, D. L.
name: Armitage, N. P.
name: Lu, D. H.
name: Damascelli, A.
name: Hu, J. P.
name: Bogdanov, P.
name: Lanzara, A.
name: Ronning, F.
name: Shen, K. M.
name: Eisaki, H.
name: Kim, C.
name: Shen, Z. -X.
name: Shimoyama, J. -i.
name: Kishio, K.
Publisher: name: arXiv
Year: 2001
Subjects: subject: Superconductivity (cond-mat.supr-con)
subject: Strongly Correlated Electrons (cond-mat.str-el)
subject: FOS: Physical sciences

description: The electronic structure of heavily overdoped Bi$_2$Sr$_2$CaCu$_2$O$_{8+δ}$ is investigated by angle-resolved photoemission spectroscopy. The long-sought bilayer band splitting in this two-plane system is observed in both normal and superconducting states, which qualitatively agrees with the bilayer Hubbard model calculations. The maximum bilayer energy splitting is about 88 meV for the normal state feature, while it is only about 20 meV for the superconducting peak. This anomalous behavior cannot be reconciled with the quasiparticle picture.
description: 4 pages, 4 figures, submitted to Phys. Rev. Lett
Additional file 2: of Assessment of mGluR5 KO mice under conditions of low stress using a rodent touchscreen apparatus reveals impaired behavioural flexibility driven by perseverative responses
Creators: name: Jisoo Lim
name: Eosu Kim
name: Noh, Hyun
name: Shinwon Kang
name: Phillips, Benjamin
name: Kim, Dong
name: Bussey, Timothy
name: Saksida, Lisa
name: Heath, Christopher
name: Kim, Chul
Publisher: name: figshare
Year: 2019
Subjects: subject: 69999 Biological Sciences not elsewhere classified
subject: FOS: Biological sciences
subject: Science Policy

description: Figure S2. mGluR5 KO mice perform better than WT littermates in the PR4 schedule task evaluated after undergoing the touchscreen EXT task. a Breakpoint in PR4. b Target touches in PR4. c Blank touches in PR4. WT group n = 10 and mGluR5 KO group n = 10, unpaired t test; ***p
CARMENES input catalogue of M dwarfs IV. New rotation periods from photometric time series
Creators: name: Alonso, E. Diez
name: Caballero, J. A.
name: Montes, D.
name: Juez, F. J. de Cos
name: Dreizler, S.
name: Dubois, F.
name: Jeffers, S. V.
name: Lalitha, S.
name: Naves, R.
name: Reiners, A.
name: Ribas, I.
name: Vanaverbeke, S.
name: Amado, P. J.
name: Bejar, V. J. S.
name: Cortes-Contreras, M.
name: Herrero, E.
name: Hidalgo, D.
name: Kurster, M.
name: Logie, L.
name: Quirrenbach, A.
name: Rau, S.
name: Seifert, W.
name: Schofer, P.
name: Tal-Or, L.
Publisher: name: arXiv
Year: 2018
Subjects: subject: Solar and Stellar Astrophysics (astro-ph.SR)
subject: FOS: Physical sciences

description: Aims. The main goal of this work is to measure rotation periods of the M-type dwarf stars being observed by the CARMENES exoplanet survey to help distinguish radial-velocity signals produced by magnetic activity from those produced by exoplanets. Rotation periods are also fundamental for a detailed study of the relation between activity and rotation in late-type stars. Methods. We look for significant periodic signals in 622 photometric time series of 337 bright, nearby M dwarfs obtained by long-time baseline, automated surveys (MEarth, ASAS, SuperWASP, NSVS, Catalina, ASAS-SN, K2, and HATNet) and for 20 stars which we obtained with four 0.2-0.8 m telescopes at high geographical latitudes. Results. We present 142 rotation periods (73 new) from 0.12 d to 133 d and ten long-term activity cycles (six new) from 3.0 a to 11.5 a. We compare our determinations with those in the existing literature; we investigate the distribution of P rot in the CARMENES input catalogue,the amplitude of photometric variability, and their relation to vsin i and pEW(Halfa); and we identify three very active stars with new rotation periods between 0.34 d and 23.6 d.
description: 34 pages, 43 figures, 2 appendix tables
Low-lying Quasiparticle Excitations around a Vortex Core in Quantum Limit
Creators: name: Hayashi, N.
name: Isoshima, T.
name: Ichioka, M.
name: Machida, K.
Publisher: name: arXiv
Year: 1998
Subjects: subject: Superconductivity (cond-mat.supr-con)
subject: FOS: Physical sciences

description: Focusing on a quantum-limit behavior, we study a single vortex in a clean s-wave type-II superconductor by self-consistently solving the Bogoliubov-de Gennes equation. The discrete energy levels of the vortex bound states in the quantum limit is discussed. The vortex core radius shrinks monotonically up to an atomic-scale length on lowering the temperature T, and the shrinkage stops to saturate at a lower T. The pair potential, supercurrent, and local density of states around the vortex exhibit Friedel-like oscillations. The local density of states has particle-hole asymmetry induced by the vortex. These are potentially observed directly by STM.
description: 4 pages, 6 figures
On-the-fly ab initio semiclassical evaluation of absorption spectra of polyatomic molecules beyond the Condon approximation
Creators: name: Patoz, Aurélien
name: Begušić, Tomislav
name: Vaníček, Jiří
Publisher: name: arXiv
Year: 2018
Subjects: subject: Chemical Physics (physics.chem-ph)
subject: Computational Physics (physics.comp-ph)
subject: FOS: Physical sciences

description: To evaluate vibronic spectra beyond the Condon approximation, we extend the on-the-fly ab initio thawed Gaussian approximation by considering the Herzberg-Teller contribution due to the dependence of the electronic transition dipole moment on nuclear coordinates. The extended thawed Gaussian approximation is tested on electronic absorption spectra of phenyl radical and benzene: Calculated spectra reproduce experimental data and are much more accurate than standard global harmonic approaches, confirming the significance of anharmonicity. Moreover, the extended method provides a tool to quantify the Herzberg-Teller contribution: we show that in phenyl radical, anharmonicity outweighs the Herzberg-Teller contribution, whereas in benzene, the Herzberg-Teller contribution is essential, since the transition is electronically forbidden and Condon approximation yields a zero spectrum. Surprisingly, both adiabatic harmonic spectra outperform those of the vertical harmonic model, which describes the Franck-Condon region better. Finally, we provide a simple recipe for orientationally averaging spectra, valid beyond Condon approximation, and a relation among the transition dipole, its gradient, and nonadiabatic coupling vectors.
description: Final form available via open access in J. Phys. Chem. Lett.: https://pubs.acs.org/doi/10.1021/acs.jpclett.8b00827. Last 11 pages contain the Supporting Information