title: ÐÐ¸ÑÐ»ÐµÐºÑÑÐ¸ÑÐµÑÐºÐ¸Ðµ ÑÐ²Ð¾Ð¹ÑÑÐ²Ð° Ð¿Ð¾Ð»Ð¸ÑÑÐµÑÐ°Ð½Ð¾Ð²ÑÑ Ð¸Ð¾Ð½Ð¾Ð¼ÐµÑÐ¾Ð² Ð½Ð° Ð¾ÑÐ½Ð¾Ð²Ðµ ÑÐ°Ð·Ð²ÐµÑÐ²Ð»ÐµÐ½Ð½ÑÑ ÑÑÐ¸ÑÐ¾Ð² Ð¸ Ð°Ð¼Ð¸Ð½Ð¾ÑÑÐ¸ÑÐ¾Ð² Ð¾ÑÑÐ¾ÑÐ¾ÑÑÐ¾ÑÐ½Ð¾Ð¹ ÐºÐ¸ÑÐ»Ð¾ÑÑ
title: Ð²ÑÐ¿ÑÑÐºÐ½Ð°Ñ ÐºÐ²Ð°Ð»Ð¸ÑÐ¸ÐºÐ°ÑÐ¸Ð¾Ð½Ð½Ð°Ñ ÑÐ°Ð±Ð¾ÑÐ° Ð¼Ð°Ð³Ð¸ÑÑÑÐ°
titleType: Subtitle
title: Dielectric properties of polyurethane ionomers based on branched esters and ami-noesters of orthophosphoric acid
Creators: name: ÐÐ¸ÐºÐ¸ÑÐ¸Ð½Ð°, ÐÐ»Ð¸Ð·Ð°Ð²ÐµÑÐ°
Publisher: name: Ð¡Ð°Ð½ÐºÑ-ÐÐµÑÐµÑÐ±ÑÑÐ³ÑÐºÐ¸Ð¹ Ð¿Ð¾Ð»Ð¸ÑÐµÑÐ½Ð¸ÑÐµÑÐºÐ¸Ð¹ ÑÐ½Ð¸Ð²ÐµÑÑÐ¸ÑÐµÑ ÐÐµÑÑÐ° ÐÐµÐ»Ð¸ÐºÐ¾Ð³Ð¾
Year: 2021
Subjects: ÐÐ¾Ð»Ð¸ÑÑÐµÑÐ°Ð½Ñ
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description: This work is devoted to the study of the features of the processes of dielectric relaxation and charge transfer in polyurethane ionomers based on esters and aminoesters of orthophosphoric acid, as well as with the presence of phthalic anhy-dride in the reaction system. Tasks that were solved in the course of the study: 1. To make a literary review on the topic of the work 2. To experimentally investigate the frequency dependences of the dielectric and electrically conductive parameters of samples based on esters and aminoesters of orthophosphoric acid, as well as aminoesters of orthophosphoric acid with the ad-dition of phthalic anhydride to the reaction system. 3. To study the effect of the amount of ether, aminoester, and phthalic anhydride in the reaction system on the dielectric and electrical characteristics 4. To develop model concepts of the processes of dielectric relaxation and charge transfer in polymer materials based on EPA and AEPA 5. To develop model ideas about the supramolecular structure of polydimensional materials based on EPA and AEPA It was found that the change in the amount of orthophosphoric acid, the presence of an amine component and phthalic anhydride in the synthesis of OPA-based PUIS has a noticeable effect on the number of ionic groups in the resulting films, and, consequently, on their properties. The revealed high dielectric characteristics in combination with the high adhesive and mechanical properties of AEPA-6-PU are of interest for their use as coatings for printed circuit boards and similar applications.