cometadata/datacite-rtg-text-other-reclassification-records huggingface dataset:
Iridoid glycosides from Alonsoa meridionalis
Creators: name: Tomassini, Lamberto
name: Serafini, Mauro
name: Foddai, Sebastiano
name: Ventrone, Antonio
name: Nicoletti, Marcello
Publisher: name: Taylor & Francis
Year: 2014
Subjects: Uncategorised

description: A new iridoid glucoside has been isolated from the Chilean native Alonsoa meridionalis (L.f.) Kuntze. Its structure has been assigned as 6′-O-β-d-glucopyranosyl-8-O-acetylharpagide (1) by using spectroscopic methods. Harpagoside (2), laterioside (3) and verbascoside (4) were also identified.
title: Prior Informed Consent – the Case of Peru: The Wrong Kind of Right? Prior Consultation between Contestation and Meaninglessness in the Peruvian Amazon
Creators: name: Flemmer, Riccarda
Publisher: name: Fachinformationsdienst für internationale und interdisziplinäre Rechtsforschung
Year: 2016
Subjects: subject: 341

description: Völkerrechtsblog
title: Völkerrecht verstehen: Wie gewinnen wir die anderen 99%?
Creators: name: Beham, Markus
name: Fink, Melanie
name: Janik, Ralph
Publisher: name: Fachinformationsdienst für internationale und interdisziplinäre Rechtsforschung
Year: 2016
Subjects: subject: 341

description: Völkerrechtsblog
title: Wind of Change in New York?: Die diesjährigen Richterwahlen zum IGH und die Implikationen für das Machtgefüge der Vereinten Nationen
Creators: name: Dören, Richard
Publisher: name: Fachinformationsdienst für internationale und interdisziplinäre Rechtsforschung
Year: 2017
Subjects: subject: 341

description: Völkerrechtsblog
MAKTABGACHA TA'LIMDA ART TERAPIYA
Creators: name: Sharipova, Hanifa
Publisher: name: Zenodo
Year: 2024

description: Quyidagi tezisda maktabgacha ta’lim hamda boshlang’ich  ta’lim tashkilotlarida Art terapiyadan foydalanish, shu bilan birgalikda uning maqsadi, ahamiyti va vazifalarini tushuntirishdan iborat.
Intramolecular Cyclization of 1-(ω-Phenylalkyl)-2-(nitromethylene)pyrrolidines in Triflic Acid
Creators: name: Bamba Fanté
name: Yaya Soro
name: Sorho Siaka
name: Marrot, Jérôme
name: Coustard, Jean-Marie
Publisher: name: Taylor & Francis
Year: 2014
Subjects: Uncategorized

description: 1-(ω-Phenylalkyl)-2-(nitromethylene)pyrrolidines in triflic acid undergo a C,O-diprotonation, followed by loss of water, to form conjugated iminium–hydroxynitrilium dications, which react with the tethered phenyl ring by electrophilic aromatic substitution to afford tricyclic iminium compounds as triflate salts. The scope and mechanism of this reaction are discussed.
Het onderwijsachterstandenbeleid loopt achter.
Creators: name: Diessen, Geert
Publisher: name: De Cascade
Year: 2016
Subjects: onderwijsachterstandenbeleid

description: BeleidsontwikkelingenIn Nederland wordt al ruim veertig jaar landelijkbeleid gevoerd dat gericht is op de bestrijding vanonderwijsachterstanden die het gevolg zijn van sociale,economische en culturele factoren gelegen in dethuissituatie van kinderen. Aanvankelijk was er apartbeleid voor autochtone arbeiderskinderen en kinderen vanbuitenlandse werknemers. Halverwege de jaren tachtigwerden deze twee beleidsstromen samengevoegd vanuitde gedachte dat de problemen van beide doelgroepenvergelijkbaar waren en dat daarom ook met één aanpakvolstaan kon worden. Dit neemt niet weg dat er toch ookaparte maatregelen werden genomen voor allochtonekinderen. Tien jaar geleden verdween die etnischecomponent helemaal uit het beleid.
Report for policymakers with strategies for sustainable craft ecosystem management and heritage preservation
Creators: name: Gasparin, Marta
name: Macció, Enrico
name: Beye, Andrea
name: Bustamante, Margot
name: Jacobsen, Lea
Publisher: name: Zenodo
Year: 2024

description: This report illustrates the methodology developed within the Hephaestus project to research and promote craft ecosystem management and heritage preservation in Europe through policymaking. It does so by outlining the complex historical evolution of craft, as both a concept and a practice, and discussing the implications on the relationship between craft and other sectors. It then describes the state-of-the-art research on craft policy and addresses existing policy gaps, by considering current European policies on craft. Additionally, it presents the emerging insights from the fieldwork activities conducted within the Hephaestus project, including relevant themes for policy interventions. Finally, it presents the methodological guidelines that will inform historical analysis and participatory activities for the development of policy interventions.
Intramolecular Cyclization of 1-(ω-Phenylalkyl)-2-(nitromethylene)pyrrolidines in Triflic Acid
Creators: name: Bamba Fanté
name: Yaya Soro
name: Sorho Siaka
name: Marrot, Jérôme
name: Coustard, Jean-Marie
Publisher: name: Taylor & Francis
Year: 2014
Subjects: Uncategorised

description: 1-(ω-phenylalkyl)-2-(nitromethylene)pyrrolidines in triflic acid undergo a C,O-diprotonation, followed by loss of water, to form conjugated iminium-hydroxynitrilium dications, which react with the tethered phenyl ring by electrophilic aromatic substitution to afford tricyclic iminium compounds as triflate salts. The scope and mechanism of this reaction are discussed.
Koloniale Spuren in Ahrensburg: Joseph | Heinrich Carl Ambach und weitere Schwarze Menschen im Umkreis der Familie Schimmelmann
Creators: name: Bärwald, Annika
Publisher: name: Zenodo
Year: 2024
Subjects: slavery
colonialism
Black Europe

description: Blogpost für den Lern- und Gedenkort im Alten Speicher (Runder Tisch Ahrensburg), Oktover 2024, https://gedenkort-speicher.de/2024/10/17/koloniale-spuren-in-ahrensburg/
Intramolecular Cyclization of 1-(ω-Phenylalkyl)-2-(nitromethylene)pyrrolidines in Triflic Acid
Creators: name: Bamba Fanté
name: Yaya Soro
name: Sorho Siaka
name: Marrot, Jérôme
name: Coustard, Jean-Marie
Publisher: name: Taylor & Francis
Year: 2014
Subjects: Uncategorised

description: 1-(ω-Phenylalkyl)-2-(nitromethylene)pyrrolidines in triflic acid undergo a C,O-diprotonation, followed by loss of water, to form conjugated iminium–hydroxynitrilium dications, which react with the tethered phenyl ring by electrophilic aromatic substitution to afford tricyclic iminium compounds as triflate salts. The scope and mechanism of this reaction are discussed.
Data Management in Herbal Medicinal Products Manufacturing Processes: Documentation
Batch Processing Record and Electronic Data Management
Creators: name: Somphop Thammarungsri
Publisher: name: Faculty of Pharmaceutical Sciences KKU MSU UBU
Year: 2016
Subjects: Documentation, Herbal medicinal products manufacturing, Electronic Data Management, Batch Processing Record

description: Isan Journal of Pharmaceutical Sciences, 12, 2, 44-56
Development of a bimodal structure in ocean wave spectra
Creators: name: Toffoli, Alessandro
name: Onorato, M.
name: Bitner-Gregersen, E. M.
name: Monbaliu, J.
Publisher: name: Swinburne
Year: 2024

description: Traditionally, the directional distribution of ocean waves has been regarded as unimodal, with energy concentrated mainly on the wind direction. However, numerical experiments and field measurements have already demonstrated that the energy of short waves tends to be accumulated along two off-wind directions, generating a bimodal directional distribution. Here, numerical simulations of the potential Euler equations are used to investigate the temporal evolution of initially unimodal directional wave spectra. Because this approach does not include external forcing such as wind and breaking dissipation, spectral changes are only driven by nonlinear interactions. The simulations show that the wave energy spreads outward from the spectral peak, following two characteristic directions. As a result, the directional distribution develops a bimodal form as the wavefield evolves. Although bimodal properties are more pronounced in the high wave number part of the spectrum, in agreement with previous field measurements, the simulations also show that directional bimodality characterizes the spectral peak.
Combining a Click–Multicomponent Reaction: One-Pot Synthesis of 1,2,3-Triazol-4-ylmethyl 3-Amino-5,10-dihydro-5,10-dioxo-1H-pyrazolo[1,2-b]phthalazine-2-carboxylate Derivatives
Creators: name: Dabiri, Minoo
name: MaGee, David
name: Salehi, Peyman
name: Torkian, Laleh
name: Fakharian, Mahsa
name: Donahue, Jordan
Publisher: name: Taylor & Francis
Year: 2014
Subjects: Uncategorized

description: (1,2,3-Triazol-4-yl)methyl-3-amino-5,10-dihydro-5,10-dioxo-1H-pyrazolo[1,2-b]phthalazine-2-carboxylate derivatives were synthesized by a four-component, one-pot condensation reaction of benzaldehyde derivatives, an active methylene compound (prop-2-ynyl-2-cyanoacetate), azides, and phthalhydrazide in the presence of Cu(OAc)2/sodium ascorbate as catalysts and 1-methyl-1H-imidazolium trifluoroacetate ([Hmim]TFA) as an ionic liquid medium in good to excellent yields.
Maximum steepness of oceanic waves: Field and laboratory
Creators: name: Toffoli, Alessandro
name: Babanin, Alexander
name: Onorato, M.
name: Waseda, T.
Publisher: name: Swinburne
Year: 2024

description: The breaking of waves is an important mechanism for a number of physical, chemical and biological processes in the ocean. Intuitively, waves break when they become too steep. Unfortunately, a general consensus on the ultimate shape of waves has not been achieved yet due to the complexity of the breaking mechanism which still remains the least understood of all processes affecting waves. To estimate the limiting shape of ocean waves, here we present a statistical analysis of a large sample of individual wave steepness. Data were collected from measurements of the surface elevation in laboratory facilities and the open sea under a variety of sea state conditions. Observations reveal that waves are able to reach steeper profiles than the Stokes' limit for stationary waves. Due to the large number of records this finding is statistically robust.
Synthesis and Characterization of 2-Carboxyethyltriphenyl Phosphonium Tribromide and Its Application as Catalyst in Silylation of Alcohols and Thiols Under Solvent-Free Condition
Creators: name: Dey, Rupa Rani
name: Siddhartha Sankar Dhar
Publisher: name: Taylor & Francis
Year: 2014
Subjects: Uncategorized

description: A phosphonium-based catalyst, 2-carboxyethyltriphenyl phosphonium tribromide (CTPTB), has been synthesized by reacting triphenyl phosphine with acrylic acid and potassium bromide under solvent-free condition followed by oxidation of Br− to with KMnO4. This hitherto unknown tribromide reagent is characterized by ultraviolet–visible, Fourier transform–infrared, 1H NMR, and 31P NMR spectroscopy. Its efficacy as catalyst is established by investigating its catalytic activity in silylation of alcohols and thiols by hexamethyl disilazane (HMDS). It is found to be a very good catalyst and selectively and efficiently catalyzes the silylation reactions.
Freak waves in crossing seas
Creators: name: Onorato, M.
name: Proment, D.
name: Toffoli, Alessandro
Publisher: name: Swinburne
Year: 2024

description: We consider the modulational instability in crossing seas as a potential mechanism for the formation of freak waves. The problem is discussed in terms of a system of two coupled Nonlinear Schröedinger equations. The asymptotic validity of such system is discussed. For some specific angles between the two wave trains, the equations reduce to an integrable system. A stability analysis of these equations is discussed. Furthermore, we present an analytical study of the maximum amplification factor for an unstable plane wave solution. Results indicate that angles between 10° and 30° are the most probable for establishing a freak wave sea. We show that the theoretical expectations are consistent with numerical simulations of the Euler equations.
IOT TEXNOLOGIYALARI VA KIBERXAVFSIZLIK
Creators: name: Xojanova, Alfiya
Publisher: name: Zenodo
Year: 2024

description: Ushbu maqolada IoT (Internet of Things) texnologiyalarining rivojlanishi va bu texnologiyalarning kiberxavfsizlikka ta'siri ko'rib chiqiladi. IoT qurilmalari kundalik hayotimizning ajralmas qismiga aylanib bormoqda, ular uy-ro'zg'or buyumlaridan tortib sanoat uskunalarigacha bo'lgan ko'plab sohalarda qo'llanilmoqda. Shu bilan birga, IoT qurilmalarining keng tarqalishi kiberxavfsizlikka oid yangi muammolarni yuzaga keltiradi. Maqolada IoT qurilmalarining xavfsizlikka oid asosiy tahdidlari, shu jumladan, ma'lumotlarning maxfiyligi, butunligi va mavjudligiga tahdid soluvchi omillar batafsil tahlil qilinadi.
Evolution of weakly nonlinear random directional waves: laboratory experiments and numerical simulations
Creators: name: Toffoli, Alessandro
name: Gramstad, O.
name: Trulsen, K.
name: Monbaliu, J.
name: Bitner-Gregersen, E.
name: Onorato, M.
Publisher: name: Swinburne
Year: 2024

description: Nonlinear modulational instability of wavepackets is one of the mechanisms responsible for the formation of large-amplitude water waves. Here, mechanically generated waves in a three-dimensional basin and numerical simulations of nonlinear waves have been compared in order to assess the ability of numerical models to describe the evolution of weakly nonlinear waves and predict the probability of occurrence of extreme waves within a variety of random directional wave fields. Numerical simulations have been performed following two different approaches: numerical integration of a modified nonlinear Schrodinger equation and numerical integration of the potential Euler equations based on a higher-order spectral method. Whereas the first makes a narrow-banded approximation (both in frequency and direction), the latter is free from bandwidth constraints. Both models assume weakly nonlinear waves. On the whole, it has been found that the statistical properties of numerically simulated wave fields are in good quantitative agreement with laboratory observations. Moreover, this study shows that the modified nonlinear Schrodinger equation can also provide consistent results outside its narrow-banded domain of validity.
Efficient Microwave-Assisted Synthesis of N-(2-Alkyl/aryl-4-phenyl-1H-imidazol-1-yl)-2-phenylacetamides
Creators: name: Menteşe, Emre
name: Yılmaz, Fatih
Publisher: name: Taylor & Francis
Year: 2014
Subjects: Uncategorized

description: An easy, efficient, and environmentally friendly method for the synthesis of N-(2-alkyl/aryl-4-phenyl-1H-imidazol-1-yl)-2-phenylacetamides from the reaction of phenyl acylbromides and phenylacetohydrazide derivatives has been presented. Shorter reaction times, simple workup procedure, no catalyst requirement, and use of small quantities of organic solvent are the most obvious advantages of this protocol.
Synergistic effect of hexane extract of Kaempferia parviflora on antibiotics against methicillinresistant Staphylococcus aureus
Creators: name: Bunliang Suphim
Publisher: name: Faculty of Pharmaceutical Sciences KKU MSU UBU
Year: 2016
Subjects: hexane extract, Kaempferia parviflora, methicillin-resistant S. aureus, antibiotic agents

description: Isan Journal of Pharmaceutical Sciences, 12, 2, 57-67
Combining a Click–Multicomponent Reaction: One-Pot Synthesis of 1,2,3-Triazol-4-ylmethyl 3-Amino-5,10-dihydro-5,10-dioxo-1H-pyrazolo[1,2-b]phthalazine-2-carboxylate Derivatives
Creators: name: Dabiri, Minoo
name: MaGee, David
name: Salehi, Peyman
name: Torkian, Laleh
name: Fakharian, Mahsa
name: Donahue, Jordan
Publisher: name: Taylor & Francis
Year: 2014
Subjects: Uncategorised

description: (1,2,3-Triazol-4-yl)methyl-3-amino-5,10-dihydro-5,10-dioxo-1H-pyrazolo[1,2-b]phthalazine-2-carboxylate derivatives were synthesized by a four-component, one-pot condensation reaction of benzaldehyde derivatives, an active methylene compound (prop-2-ynyl-2-cyanoacetate), azides, and phthalhydrazide in the presence of Cu(OAc)2/sodium ascorbate as catalysts and 1-methyl-1H-imidazolium trifluoroacetate ([Hmim]TFA) as an ionic liquid medium in good to excellent yields.
Wave breaking in directional fields
Creators: name: Babanin, Alexander
name: Waseda, T.
name: Kinoshita, T.
name: Toffoli, Alessandro
Publisher: name: Swinburne
Year: 2024

description: Wave breaking is observed in a laboratory experiment with waves of realistic average steepness and directional spread. It is shown that modulational-instability mechanism is active in such circumstances, and can lead to the breaking. Experiments were conducted in the directional wave tank of the University of Tokyo, and the mechanically-generated wave fields consisted of a primary wave with sidebands in the frequency domain, with continuous directional distribution in the angular domain. Initial steepness of the primary wave and sidebands, as well as the width of directional distributions varied in a broad range, in order to determine the combination of steepness/directional-spread properties which separate modulational-instability breaking from the linear-focusing breaking.
The EU Argentinean Trade Dispute on Biodiesel: An Economic Assessment
Creators: name: Gohin, Alexandre
name: Levert, Fabrice
name: Forslund, Agneta
name: Gohin, Alexandre
name: Levert, Fabrice
name: Forslund, Agneta
Publisher: name: Unknown
Year: 2017
Subjects: subject: Agricultural and Food Policy
subject: International Relations/Trade
subject: export taxes
subject: biodiesel
subject: world trade organization
subject: Argentina

description: Argentina has a long record of taxing agricultural exports. In 2013, the European Commission started to impose antidumping duties on exports of Argentinean biodiesel. They were considered being dumped due to reduced export taxes compared to those applied to soybean oil exports. The objective of this paper is to analyze the economic consequences of these Argentinean differential taxes on the European biodiesel and related sectors. Thanks to an original model simulating the world markets of main arable crops, we first analyze the results of an increase of the export tax on biodiesel only. We then simulate the consequences of a reduction of export taxes on soybean products. Finally, we assess the impacts of the overall Argentinean policy of differentiated taxation of agricultural exports. One main conclusion is that European biodiesel producers are relatively more penalized than biodiesel producers in other countries by the current Argentinean policy, due to a relatively greater production of rapeseed. US and Brazilian producers suffer from welfare losses in all scenarios due to the indirect effects on soybean markets. The welfare impacts on consumers and taxpayers are often opposite to the welfare impacts on producers, leading to small global welfare effects.
title: Les gagnants à la loterie
title: Les gagnants à la loterie
titleType: AlternativeTitle
Creators: name: Dubuis, Claudia
Publisher: name: Groupement romand d'études des addictions
Year: 2015

description: Cette notice a été réalisée dans le cadre d’une revue de la littérature sur les jeux d’argent dans le domaine des sciences humaines.
title: Jeu d’argent
title: interdits, tabous, critiques
titleType: Subtitle
title: Jeu d’argent
titleType: AlternativeTitle
Creators: name: Dubuis, Claudia
Publisher: name: Groupement romand d'études des addictions
Year: 2015

description: Cette notice a été réalisée dans le cadre d’une revue de la littérature sur les jeux d’argent dans le domaine des sciences humaines.
Occurrence of extreme waves in three-dimensional mechanically generated wave fields propagating over an oblique current
Creators: name: Toffoli, Alessandro
name: Cavaleri, L.
name: Babanin, Alexander
name: Benoit, M.
name: Bitner-Gregersen, E. M.
name: Monbaliu, J.
name: Onorato, M.
name: Osborne, A. R.
name: Stansberg, C. T.
Publisher: name: Swinburne
Year: 2024

description: Laboratory experiments were performed to study the dynamics of three-dimensional mechanically generated waves propagating over an oblique current in partial opposition. The flow velocity varied along the mean wave direction of propagation with an increasing trend between the wave-maker and the centre of the tank. Tests with regular wave packets traversing the area of positive current gradient showed that the concurrent increase of wave steepness triggered modulational instability on otherwise stable wave trains and hence induced the development of very large amplitude waves. In random directional wave fields, the presence of the oblique current resulted in a weak reinforcement of wave instability with a subsequent increase of the probability of occurrence of extreme events. This seems to partially compensate the suppression of strongly non-Gaussian properties due to directional energy distribution.
title: Quo Vadis PMSC?: The way forward in dealing with Private Military and Security Companies: A response to Prof. Sossai’s assessment of the legal side effects of privatized war
Creators: name: Renz, Frauke
Publisher: name: Fachinformationsdienst für internationale und interdisziplinäre Rechtsforschung
Year: 2017
Subjects: subject: 341

description: Völkerrechtsblog
title: L’encadrement étatique
title: législation et morale
titleType: Subtitle
title: L’encadrement étatique
titleType: AlternativeTitle
Creators: name: Cusin, David
Publisher: name: Groupement romand d'études des addictions
Year: 2013

description: Cette notice a été réalisée dans le cadre d’une revue de la littérature sur les jeux d’argent dans le domaine des sciences humaines
An Efficient Microwave Assisted Synthesis of N-(2-Alkyl/Aryl-4-Phenyl-1H-imidazol-1-yl)-2-phenylacetamides
Creators: name: Menteşe, Emre
name: Yılmaz, Fatih
Publisher: name: Taylor & Francis
Year: 2014
Subjects: Uncategorised

description: An easy, efficient and environmentally friendly method for the synthesis of N-(2-alkyl/aryl-4-phenyl-1H-imidazol-1-yl)-2-phenylacetamides from the reaction of phenyl acylbromides and phenylacetohydrazide derivatives has been presented. Shorter reaction times, simple work-up procedure, no catalyst requirement and using of low quantity of organic solvent are the most obvious advantages of this protocol.
Generating service models by trace subsequence substitution
Creators: name: Du, Miao
name: Schneider, Jean-Guy
name: Hine, Cameron
name: Grundy, John
name: Versteeg, Steve
Publisher: name: Swinburne
Year: 2024

description: Software service emulation is an emerging technique for creating realistic executable models of server-side behaviour and is particularly useful in quality assurance: replicating production-like conditions for large-scale enterprise software systems. This allows performance engineers to mimic very large numbers of servers and/or provide a means of controlling dependencies on diverse third-party systems. Previous approaches to service emulation rely on manual definition of interaction behaviour requiring significant human effort. They also rely on either a system expert or documentation of system protocol and behaviour, neither of which are necessarily available. We present a novel method of automatically building client-server and server-server interaction models of complex software systems directly from interaction trace data, utilising longest common subsequence matching and field substitution algorithms. We evaluate our method against two common application-layer protocols: LDAP and SOAP. The results show that without explicit knowledge of the protocol specifications, our generated service models can produce well-formed responses for interactions. These responses can then be used within an emulation framework for large-scale enterprise system quality assurance purposes.
title: Verstoß von Deutschland gegen EMRK wegen mangelnder Untersuchung von Polizeigewalt: Die Entscheidung des EGMR vom 9. November 2017 in der Sache Hentschel and Stark v. Germany, 47274/15
Creators: name: Frowein, Jochen
Publisher: name: Fachinformationsdienst für internationale und interdisziplinäre Rechtsforschung
Year: 2017
Subjects: subject: 341

description: Völkerrechtsblog
title: Last but not least: Lebenslang für den "Schlächter des Balkans": Das Urteil des Jugoslawienstrafgerichtshofes vom 22. November 2017 gegen Ratko Mladić
Creators: name: Hartig, Annegret
Publisher: name: Fachinformationsdienst für internationale und interdisziplinäre Rechtsforschung
Year: 2017
Subjects: subject: 341

description: Völkerrechtsblog
title: La régulation des jeux de hasard et d’argent en Suisse
title: La régulation des jeux de hasard et d’argent en Suisse
titleType: AlternativeTitle
Creators: name: Villeneuve, Jean-Patrick
Publisher: name: Groupement romand d'études des addictions
Year: 2015

description: Cette notice a été réalisée dans le cadre d’une revue de la littérature sur les jeux d’argent dans le domaine des sciences humaines.
INSC: An Iterative Negotiation Approach for Service Compositions
Creators: name: He, Qiang
name: Yang, Yun
name: Yan, Jun
name: Jin, Hai
Publisher: name: Swinburne
Year: 2024

description: The service-oriented paradigm offers support for engineering service-based systems (SBSs) based on service compositions. The selection of services with the aim to fulfil the quality constraints for SBSs and to achieve the optimisation goals is a critical and challenging issue. In particular, when the quality-of-service (QoS) constraints for a SBS are severe, it is often difficult to find an optimal solution for the SBS. Exploiting the competition among service providers can help SBS developers obtain favourable QoS offers for the component services of SBSs and increase the possibility of finding optimal solutions for the SBSs. In this paper, we present a novel joint optimisation and negotiation approach named Iterative Negotiation for Service Composition (INSC) that supports effective and efficient QoS-aware service selection for SBSs. We evaluate INSC experimentally using example SBSs that are synthetically generated based on a real-world Web service dataset. The experimental results show that INSC can significantly and efficiently increase the possibility of finding optimal solutions in severe service composition scenarios.
Combining a Click-Multicomponent Reaction: One-Pot Synthesis of 1,2,3-Triazol-4-ylmethyl 3-Amino-5,10-dihydro-5,10-dioxo-1H-pyrazolo[1,2-b]phthalazine-2-carboxylate Derivatives
Creators: name: Dabiri, Minoo
name: MaGee, David
name: Salehi, Peyman
name: Torkian, Laleh
name: Fakharian, Mahsa
name: Donahue, Jordan
Publisher: name: Taylor & Francis
Year: 2014
Subjects: Uncategorised

description: (1,2,3-Triazol-4-yl)methyl-3-amino-5,10-dihydro-5,10-dioxo-1H-pyrazolo[1,2-b]phthalazine-2-carboxylate derivatives were synthesized by a four-component, one-pot condensation reaction of benzaldehyde derivatives, an active methylene compound (prop-2-ynyl-2-cyanoacetate), azides and phthalhydrazide in the presence of Cu(OAc)2/sodium ascorbate as catalysts and 1-methyl-1H-imidazolium trifluoroacetate ([Hmim]TFA) as an ionic liquid medium in good to excellent yields.
Efficient Microwave-Assisted Synthesis of N-(2-Alkyl/aryl-4-phenyl-1H-imidazol-1-yl)-2-phenylacetamides
Creators: name: Menteşe, Emre
name: Yılmaz, Fatih
Publisher: name: Taylor & Francis
Year: 2014
Subjects: Uncategorised

description: An easy, efficient, and environmentally friendly method for the synthesis of N-(2-alkyl/aryl-4-phenyl-1H-imidazol-1-yl)-2-phenylacetamides from the reaction of phenyl acylbromides and phenylacetohydrazide derivatives has been presented. Shorter reaction times, simple workup procedure, no catalyst requirement, and use of small quantities of organic solvent are the most obvious advantages of this protocol.
One-Pot Tandem Synthesis of Tetrasubstituted Pyrazoles via 1,3-Dipolar Cycloaddition Between Aryl Hydrazones and Ethyl But-2-ynoate
Creators: name: Srikantamurthy Ningaiah
name: Shridevi D. Doddaramappa
name: , Chandra
name: Madegowda, Mahendra
name: Shubakara Keshavamurthy
name: Umesha K. Bhadraiah
Publisher: name: Taylor & Francis
Year: 2014
Subjects: Uncategorized

description: 1,3,4,5-Tetrasubstituted pyrazoles are rapidly and regioselectively synthesized in a one-pot, three-step sequence consisting of condensation, nitrilimine generation, and cycloaddition using mercuric acetate. Newly synthesized compounds were characterized by spectral studies. Regiochemistry of compounds 6a and 8a was determined as 1,4- and 1,5-regioisomers respectively by X-ray crystallography.
Synthesis and Characterization of 2-Carboxyethyltriphenyl Phosphonium Tribromide and its Application as Catalyst in Silylation of Alcohols and Thiols under Solvent Free Condition
Creators: name: Dey, Rupa Rani
name: Siddhartha Sankar Dhar
Publisher: name: Taylor & Francis
Year: 2014
Subjects: Uncategorised

description: A phosphonium based catalyst, 2-Carboxyethyltriphenyl phosphonium tribromide (CTPTB) has been synthesized by reacting triphenyl phosphine with acrylic acid and potassium bromide under solvent-free condition followed by oxidation of Br- to with KMnO4. This hitherto unknown tribromide reagent is characterized by UV-Visible, FT-IR, 1H NMR and 31P NMR spectroscopy. Its efficacy as catalyst is established by investigating its catalytic activity in silylation of alcohols and thiols by hexamethyl disilazane (HMDS). Indeed it is found to be a very good catalyst which selectively and efficiently catalyzes the silylation reactions.
Synthesis and Characterization of 2-Carboxyethyltriphenyl Phosphonium Tribromide and Its Application as Catalyst in Silylation of Alcohols and Thiols Under Solvent-Free Condition
Creators: name: Dey, Rupa Rani
name: Siddhartha Sankar Dhar
Publisher: name: Taylor & Francis
Year: 2014
Subjects: Uncategorised

description: A phosphonium-based catalyst, 2-carboxyethyltriphenyl phosphonium tribromide (CTPTB), has been synthesized by reacting triphenyl phosphine with acrylic acid and potassium bromide under solvent-free condition followed by oxidation of Br− to with KMnO4. This hitherto unknown tribromide reagent is characterized by ultraviolet–visible, Fourier transform–infrared, 1H NMR, and 31P NMR spectroscopy. Its efficacy as catalyst is established by investigating its catalytic activity in silylation of alcohols and thiols by hexamethyl disilazane (HMDS). It is found to be a very good catalyst and selectively and efficiently catalyzes the silylation reactions.
A silicon-containing polyazomethine and derived metal complexes: synthesis, characterization, and evaluation of the properties
Creators: name: Mirela-Fernanda Zaltariov
name: Cazacu, Maria
name: Shova, Sergiu
name: Cristian-Dragos Varganici
name: Vacareanu, Loredana
name: Musteata, Valentina
name: Airinei, Anton
Publisher: name: Taylor & Francis
Year: 2014
Subjects: Uncategorized

description: A new dialdehyde-containing silicon was prepared by a reaction of Williamson-type and structurally characterized. By its subsequent condensation with 2,5-bis(p-aminophenyl)-1,3,4-oxadiazole, a multifunctional polyazomethine-containing imine, phenylene, oxadiazole, ether, and carbosilane groups within the chain was prepared. The complexes of this polymer with Co(II), Cu(II), and Zn(II) ions formed on the basis of electron-donor ability of the oxadiazole and azomethine groups were prepared in a one-step approach by mixing the two precursors of polyazomethine (dialdehyde and diamine) with corresponding metal salt. The ligand and metal complexes were characterized by spectral (Fourier transform infrared (FTIR), 1H, and 13C NMR) methods. The thermal, optical, electrochemical, and dielectric properties were studied and the effects of the metal insertion in dependence on its nature over these properties were evaluated. All compounds are soluble in common organic solvents and show low glass transitions due to the flexible ether and Si–C bonds, are fluorescent, mainly due to the oxadiazole ring, are redox active and have high dielectric constant due to the presence of oxadiazole, azomethine metal units.
title: Ukraine v. Russia: Passage through Kerch Strait and the Sea of Azov: Part II: Ukraine’s Rights of Passage through Kerch Strait
Creators: name: Schatz, Valentin
name: Koval, Dmytro
Publisher: name: Fachinformationsdienst für internationale und interdisziplinäre Rechtsforschung
Year: 2018
Subjects: subject: 341

description: Völkerrechtsblog
title: Ukraine v. Russia: Passage through Kerch Strait and the Sea of Azov: Part III: The Jurisdiction of the Arbitral Tribunal
Creators: name: Schatz, Valentin
name: Koval, Dmytro
Publisher: name: Fachinformationsdienst für internationale und interdisziplinäre Rechtsforschung
Year: 2018
Subjects: subject: 341

description: Völkerrechtsblog
De werking van het onderwijsachterstandenbeleid
Creators: name: Driessen, Geert
Publisher: name: 4W Weten Wat Werkt en Waarom
Year: 2024
Subjects: onderwijsachterstandenbeleid

description: De plaats waar je wieg staat, bepaalt je kansen in hetleven. Dat is in een notendop het uitgangspunt van hetNederlandse onderwijsachterstandenbeleid. Scholen krijgenextra geld om te compenseren voor een minder stimulerendethuisomgeving. Maar hoe houdbaar is dit uitgangspunteigenlijk nog? En wat heeft het voor zin om geld uit te trekkenvoor achterstandsleerlingen als scholen het niet rechtstreeksaan hen (hoeven te) besteden?
Synthesis of a novel water-soluble conjugated polyelectrolyte based on polycyclopentadithiophene backbone and its application for heparin detection
Creators: name: Xiangwei Zhu
name: Wenjuan Guo
name: Huizhi Li
name: Guangyou Zhang
name: Meishan Pei
name: Luyan Wang
name: Jijun Feng
Publisher: name: Taylor & Francis
Year: 2014
Subjects: Uncategorized

description: The novel water-soluble conjugated polyelectrolyte containing a new kind of backbone poly[(4,4-bis(3ʹ-N,N,N-trimethylammonium) propyl) cyclopentadithiophene dichloride] (PBTPC-Cl) is synthesized and characterized. The PBTPC-Cl is readily soluble in polar solvents and is applied as a sensitive and selective fluorescent probe for heparin detection in aqueous solution. Upon adding heparin into the aqueous solution of polymer, PBTPC-Cl could bind heparin via electrostatic interactions and results in the quenching of emission peaks. Quantitative analysis of heparin shows high selectivity and good linear relationship with a detection limit to 0.05 μM in HEPES aqueous buffer.
One-Pot Tandem Synthesis of Tetrasubstituted Pyrazoles via 1,3-dipolar Cycloaddition Between Aryl Hydrazones and Ethyl But-2-ynoate
Creators: name: Srikantamurthy Ningaiah
name: Shridevi D. Doddaramappa
name: , Chandra
name: Madegowda, Mahendra
name: Shubakara Keshavamurthy
name: Umesha K. Bhadraiah
Publisher: name: Taylor & Francis
Year: 2014
Subjects: Uncategorised

description: 1,3,4,5-Tetrasubstituted pyrazoles are rapidly and regioselectively synthesized in a one-pot, 3 step sequence consisting of condensation, nitrilimine generation and cycloaddition using mercuric acetate. Newly synthesized compounds were characterized by spectral studies. Regiochemistry of compounds (6a) and (8a) was determined as 1,4- and 1,5-regioisomers respectively by X-ray crystallography.
One-Pot Tandem Synthesis of Tetrasubstituted Pyrazoles via 1,3-Dipolar Cycloaddition Between Aryl Hydrazones and Ethyl But-2-ynoate
Creators: name: Srikantamurthy Ningaiah
name: Shridevi D. Doddaramappa
name: , Chandra
name: Madegowda, Mahendra
name: Shubakara Keshavamurthy
name: Umesha K. Bhadraiah
Publisher: name: Taylor & Francis
Year: 2014
Subjects: Uncategorised

description: 1,3,4,5-Tetrasubstituted pyrazoles are rapidly and regioselectively synthesized in a one-pot, three-step sequence consisting of condensation, nitrilimine generation, and cycloaddition using mercuric acetate. Newly synthesized compounds were characterized by spectral studies. Regiochemistry of compounds 6a and 8a was determined as 1,4- and 1,5-regioisomers respectively by X-ray crystallography.
A silicon-containing polyazomethine and derived metal complexes: synthesis, characterization, and evaluation of the properties
Creators: name: Mirela-Fernanda Zaltariov
name: Cazacu, Maria
name: Shova, Sergiu
name: Cristian-Dragos Varganici
name: Vacareanu, Loredana
name: Musteata, Valentina
name: Airinei, Anton
Publisher: name: Taylor & Francis
Year: 2014
Subjects: Uncategorised

description: A new dialdehyde-containing silicon was prepared by a reaction of Williamson-type and structurally characterized. By its subsequent condensation with 2,5-bis(p-aminophenyl)-1,3,4-oxadiazole, a multifunctional polyazomethine-containing imine, phenylene, oxadiazole, ether, and carbosilane groups within the chain was prepared. The complexes of this polymer with Co(II), Cu(II), and Zn(II) ions formed on the basis of electron-donor ability of the oxadiazole and azomethine groups were prepared in a one-step approach by mixing the two precursors of polyazomethine (dialdehyde and diamine) with corresponding metal salt. The ligand and metal complexes were characterized by spectral (Fourier transform infrared (FTIR), 1H, and 13C NMR) methods. The thermal, optical, electrochemical, and dielectric properties were studied and the effects of the metal insertion in dependence on its nature over these properties were evaluated. All compounds are soluble in common organic solvents and show low glass transitions due to the flexible ether and Si–C bonds, are fluorescent, mainly due to the oxadiazole ring, are redox active and have high dielectric constant due to the presence of oxadiazole, azomethine metal units.
Synthesis of a novel water-soluble conjugated polyelectrolyte based on polycyclopentadithiophene backbone and its application for heparin detection
Creators: name: Xiangwei Zhu
name: Wenjuan Guo
name: Huizhi Li
name: Guangyou Zhang
name: Meishan Pei
name: Luyan Wang
name: Jijun Feng
Publisher: name: Taylor & Francis
Year: 2014
Subjects: Uncategorised

description: The novel water-soluble conjugated polyelectrolyte containing a new kind of backbone poly[(4,4-bis(3ʹ-N,N,N-trimethylammonium) propyl) cyclopentadithiophene dichloride] (PBTPC-Cl) is synthesized and characterized. The PBTPC-Cl is readily soluble in polar solvents and is applied as a sensitive and selective fluorescent probe for heparin detection in aqueous solution. Upon adding heparin into the aqueous solution of polymer, PBTPC-Cl could bind heparin via electrostatic interactions and results in the quenching of emission peaks. Quantitative analysis of heparin shows high selectivity and good linear relationship with a detection limit to 0.05 μM in HEPES aqueous buffer.
A GFP promoter fusion library for the study of Salmonella biofilm formation and the mode of action of biofilm inhibitors
Creators: name: S.C.A. Robijns
name: S. Roberfroid
name: S. Van Puyvelde
name: B. De Pauw
name: E. Uceda Santamaría
name: A. De Weerdt
name: D. De Coster
name: K. Hermans
name: S.C.J. De Keersmaecker
name: J. Vanderleyden
name: H.P.L. Steenackers
Publisher: name: Taylor & Francis
Year: 2014
Subjects: Marine Biology

description: Salmonella, an important foodborne pathogen, forms biofilms in many different environments. The composition of these biofilms differs depending on the growth conditions, and their development is highly coordinated in time. To develop efficient treatments, it is therefore essential that biofilm formation and its inhibition be understood in different environments and in a time-dependent manner. Many currently used techniques, such as transcriptomics or proteomics, are still expensive and thus limited in their application. Therefore, a GFP-promoter fusion library with 79 important Salmonella biofilm genes was developed (covering among other things matrix production, fimbriae and flagella synthesis, and c-di-GMP regulation). This library is a fast, inexpensive, and easy-to-use tool, and can therefore be conducted in different experimental setups in a time-dependent manner. In this paper, four possible applications are highlighted to illustrate and validate the use of this reporter fusion library.
Impact of ruthenium on microstructure and corrosion behavior of β-type Ti–Nb–Ru alloys for biomedical applications
Creators: name: Biesiekierski, Arne
name: Ping, D. H.
name: Yamabe-Mitarai, Y.
name: Wen, Cuie
Publisher: name: Swinburne
Year: 2024

description: Corrosion behavior and microstructure of as-cast metastable b-type Ti-20Nb-xRu (x = 0, 0.5, 1.0, 1.5 at.%) have been investigated using linear polarization and transmission electron microscopy (TEM), respectively. Ruthenium (Ru) was confirmed to be a b-phase stabilizer as a titanium (Ti) alloying element which served to suppress both x precipitation and elemental segregation; the prominence and degree of elemental segregation between the Nb-rich primary dendrites and the interdendritic areas rapidly decreased with minor Ru addition, yielding a more homogenous microstructure overall. Additionally, even minimal Ru additions significantly altered the corrosion potential (Ecorr), yielding a 0.3 V shift in the noble direction over the Ru-free controls, along with a comparable shift in the potential at which the initial passive region begins to fail (Einc). The present result suggests Ru addition can confer a greater resistance to corrosion in b-Ti alloys.
Children’s digital competence in early childhood education: A comparative analysis of curricula
Creators: name: Kontkanen, Sini
name: Pöntinen, Susanna
name: Kewalramani, Sarika
name: Veresov, Nikolai
name: Havu-Nuutinen, Sari
Publisher: name: Swinburne
Year: 2024

description: Children’s digital competence (DC) is often poorly supported in early childhood education (ECE). Furthermore, common definition of DC is difficult to find. Therefore, the aim of this comparative curriculum study was to better understand how objectives and content of DC are defined in ECE. Australia and Finland curricula were analyzed applying theory-driven content analysis. The results indicated that in both countries theoretical basis of DC was present: objectives and content of DC referred to (1) technical skills and practices, (2) applying digital technologies, (3) evaluate digital technologies critically, and (4) motivation to participate in a digital culture. However, aims, content, and practical guidelines on the curricula were unclear. This study recommends that ECE curricula should better emphasis and make explicit the key elements of DC and how to holistically foster children’s DC in practice. Further studies to clarify the important elements of DC in ECE curricula frameworks is required
Soliton-induced Majorana fermions in a one-dimensional atomic topological superfluid
Creators: name: Liu, Xiaji
Publisher: name: Swinburne
Year: 2024

description: We theoretically investigate the behavior of dark solitons in a one-dimensional spin-orbit coupled atomic Fermi gas in harmonic traps by solving self-consistently the Bogoliubov-de Gennes equations. The dark soliton -to be created by phase imprinting in future experiments -is characterized by a real order parameter, which changes sign at a point node and hosts localized Andreev bound states near the node. By considering both cases of a single soliton and multiple solitons, we find that the energy of these bound states decreases to zero when the system is tuned to enter the topological superfluid phase by increasing an external Zeeman field. As a result, two Majorana fermions emerge in the vicinity of each soliton, in addition to the well-known Majorana fermions at the trap edges associated with the nontrivial topology of the superfluid. We propose that the soliton-induced Majorana fermions can be directly observed by using spatially resolved radio-frequency spectroscopy or indirectly probed by measuring the density profile at the point node. For the latter, the deep minimum in the density profile will disappear due to the occupation of the soliton-induced zero-energy Majorana fermion modes. Our prediction could be tested in a resonantly interacting spin-orbit coupled 40K Fermi gas confined in a two-dimensional optical lattice.
Briefs for business transformation and policymaking
Creators: name: De Bernard, Manfredi
name: Cacciatore, Silvia
name: Lusiani, Maria
name: Panozzo, Fabrizio
Publisher: name: Zenodo
Year: 2024

description: Despite the documented cultural and economic value of craft, current categorizations of data regarding crafting organizations are far from adequate. Classifications that prove effective in identifying conventional economic activities often fail when applied to craft. The focus of the present document is on NACE and national equivalents – ATECO, SNI, and Dansk Branchekode DB07 - for Italy, Sweden, and Denmark, respectively. Given its nature, craft ends up being formally considered part of industrial and mass-produced manufacturing sectors. Hard to be confined within exclusive definitions, largely conducted by micro-enterprises operating informally, and more defined by the process rather than the final product, craft falls within the crevices of current classification systems. 

Problematically, inadequate identification of craft activities results in underperforming policies that are incapable of understanding the extent of the phenomenon of interest and precisely target craft organizations and their needs. Moreover, from the crafters' perspective, policies and regulations without adequate classification end up misfitting and hampering their activities. 

The deliverable’s purpose is twofold: on the one hand, to underscore flaws in official classifications and databases and outline guidelines for the project's partners to constitute a robust database despite the limitations of official data sources; on the other hand, to propose a series of policy recommendations precisely addressing the flaws underscored during the data collection process. The document is thus so structured: 

Section 2 presents an overview of the main mapping exercises conducted on a European level. The review is undertaken to gain a broader understanding of the data architecture regarding craft activities, comprehend their limits, and explore how policymakers have addressed them so far. 

Section 3 follows, presenting the guidelines we elaborated to navigate the available data and compensate for their gaps, including a working definition of craft to be adopted by Hephaestus partners. In addition to the reviewed documents and fieldwork, an indispensable element the guidelines lean on is found in the relationship with key members of the ecosystem to adapt structural deficiencies to local opportunities. The section concludes with some structural solutions to minimize the necessity of a dedicated explorative and mapping effort when seeking reliable data on craft in a given ecosystem. 

Section 4 indicates the expected deadlines for each ecosystem to collect and share craft organisations and occupational data. 

Section 5 anticipates the policy recommendations that will follow the completion of the current deliverable course of action.
Network architecture and QoS issues in the internet of things for a smart city
Creators: name: Jin, Jiong
name: Gubbi, Jayavardhana
name: Luo, Tie
name: Palaniswami, Marimuthu
Publisher: name: Swinburne
Year: 2024

description: The emerging Internet of Things (IoT) that effectively integrates cyber-physical space to create smart environments will undoubtedly have a plethora of applications in the near future. Meanwhile, it is also the key technological enabler to create smart cities, which will provide great benefits to our society. In this paper, four different IoT network architectures spanning various smart city applications are presented and their corresponding network Quality of Service (QoS) requirements are defined. Furthermore, as the beneficiary of smart city, we have the responsibility to actively participate in its development as well. A new network paradigm, participatory sensing, is thus discussed as a special case to highlight the way people may be involved in the information acquisition-transmission-interpretation-action loop.
SOXTA KASHTAN URUG'LARI TARKIBIDAGI RADIONUKLIDLAR TAHLILI
Creators: name: Yoqubova, Nilufar
Publisher: name: Zenodo
Year: 2024

description: Ushbu maqolada radionuklidlar va ularning soxta kashtan urug’lari tarkibidagi miqdori tahlil qilish hamda SanPiN (№0193-06) talablariga mosligini tekshirishga oid ma’lumotlar keltirilgan