High performance Carnot Batteries based on hybrid cycles
Creators: name: Farres Antunez, Pau
name: McTigue, Joshua D
name: White, Alexander
Publisher: name: Apollo - University of Cambridge Repository
Year: 2020

description: Pumped thermal energy storage (PTES) has seen a rapid increase in research interest and private investment during the last few years. A range of different concepts has been proposed, based on different thermodynamic cycles, and the most promising ones are already being turned into demonstration projects or small-scale storage plants. These include PTES systems based on the Joule-Brayton cycle, the Rankine cycle and the Liquid Air cycle, among others. This presentation will explore how hybridising some of these concepts can result in systems that are more flexible, cheaper, or have superior performance compared with the original cycles. More specifically, two examples will be shown where the Joule-Brayton cycle can be effectively used to support a Rankine battery and a Liquid Air battery. One general advantage of Brayton-PTES systems is that they can use molten salts as liquid storage media. Molten salts are cheap, safe and abundant, and have been used for concentrated solar power (CSP) applications in a large number of commercial plants. Employing the same storage material at similar temperature levels opens the possibility of hybrid “solar-PTES” systems that would require less capital investment than two separate plants. Such a hybrid system could charge the same hot stores using either solar energy or off-peak electricity, becoming both a power plant and an energy storage plant, therefore increasing the capacity factor while employing a single heat engine during discharge. A numerical model has been implemented to study a solar-PTES system where an existing CSP plant (based on the Rankine cycle) is retrofitted with a Brayton heat pump, and several strategies are explored to boost the overall performance. Similar configurations could be employed to transform other kinds of thermal power plant (such as coal power plants) into Brayton-Rankine batteries. In contrast to most PTES systems, liquid air energy storage (LAES) stores most of the available energy cryogenically, by liquefying atmospheric air and storing it at very low temperatures. This is advantageous because liquid air has a very high energy density - and is free. However, the difficulties in reaching full liquefaction during the charge process have a significant impact on the round-trip efficiency of the cycle. It has been found that these difficulties can be greatly minimised by employing the support of a Brayton cycle. A hybrid system was designed where a Brayton-PTES plant operates as a topping cycle and an LAES plant operates as a bottoming cycle. The cooling provided by the Brayton cycle allows the LAES side to achieve full air liquefaction, which translates into a significant boost in performance. Furthermore, the cold thermal reservoirs that would be required by the two separate cycles are replaced by a single heat exchanger that acts between them, therefore saving significant amounts of storage media per unit of energy stored. Results from a numerical study indicate that the hybrid cycle can increase round-trip efficiency by 5-10 percent points compared with the separate cycles, and achieve an even larger increase in terms of energy density.