cometadata/datacite-rtg-text-other-reclassification-records huggingface dataset:
Random matrix theory: Dyson Brownian motion
Creators: name: Finocchio, Gianluca
Publisher: name: Mathematisches Forschungsinstitut Oberwolfach
Year: 2020

description: The theory of random matrices was introduced by John Wishart (1898–1956) in 1928. The theory was then developed within the field of nuclear physics from 1955 by Eugene Paul Wigner (1902–1995) and later by Freeman John Dyson, who were both concerned with the statistical description of heavy atoms and their electromagnetic properties. In this snapshot, we show how mathematical properties can have unexpected links to physical phenomenena. In particular, we show that the eigenvalues of some particular random matrices can mimic the electrostatic repulsion of the particles in a gas.
description: Snapshots of modern mathematics from Oberwolfach;2020,02
A REVIEW OF AN ALTERNATIVE STUDIO PEDAGOGY FOR ALTERNATIVE SPACES: CASE STUDIES FROM A STUDENT'S DESIGN COMPETITION
Creators: name: Saquib, Mohammad
Publisher: name: TuEngr Group
Year: 2020
Subjects: Design competition
Public Interest Design
Learning outcomes
User satisfaction
Design studio pedagogy
Live projects.

description: International Transaction Journal of Engineering, Management, & Applied Sciences & Technologies, 11, 5, 11A05I: 1-14
Mesochorus (Mesochorus) scandinavicus SCHWENKE 1999
Creators: name: Riedel
name: Pénigot
name: Schwarz
name: Diller
name: Johansson
name: Japoshvili, G.
Publisher: name: Zenodo
Year: 2023
Subjects: Biodiversity
Taxonomy
Animalia
Arthropoda
Insecta
Hymenoptera
Ichneumonidae
Mesochorus
Mesochorus scandinavicus

description: Mesochorus (Mesochorus) scandinavicus SCHWENKE, 1999
M a t e r i a l e x a m i n e d: Trap4:1♁29.vi.-13.vii.
D i s t r i b u t i o n: Western Palaearctic, new record for Georgia and the Caucasus region.
description: Published as part of Riedel, Pénigot, Schwarz, Diller, Johansson & Japoshvili, G., 2023, Darwin wasps (Hymenoptera, Ichneumonidae) of the Kintrishi National Park, Sakartvelo (Georgia), with descriptions of six new species, pp. 61-153 in Linzer biologische Beiträge 55 (1) on page 111, DOI: 10.5281/zenodo.10788481
Mesochorus (Mesochorus) semirufus HOLMGREN 1860
Creators: name: Riedel
name: Pénigot
name: Schwarz
name: Diller
name: Johansson
name: Japoshvili, G.
Publisher: name: Zenodo
Year: 2023
Subjects: Biodiversity
Taxonomy
Animalia
Arthropoda
Insecta
Hymenoptera
Ichneumonidae
Mesochorus
Mesochorus semirufus

description: Mesochorus (Mesochorus) semirufus HOLMGREN, 1860
M a t e r i a l e x a m i n e d: Trap 7: 1♁ 1-13.vi., 1♀ 13-27.vii., 1♀ 7-21.ix.
D i s t r i b u t i o n: Transpalaearctic and Oriental, known from Georgia (RIEDEL et al. 2018).
description: Published as part of Riedel, Pénigot, Schwarz, Diller, Johansson & Japoshvili, G., 2023, Darwin wasps (Hymenoptera, Ichneumonidae) of the Kintrishi National Park, Sakartvelo (Georgia), with descriptions of six new species, pp. 61-153 in Linzer biologische Beiträge 55 (1) on page 111, DOI: 10.5281/zenodo.10788481
Unraveling Motion in Proteins by Combining NMR Relaxometry and Molecular Dynamics Simulations: A Case Study on Ubiquitin
Creators: name: Champion, Candide
name: Lehner, Marc
name: Smith, Albert A.
name: Ferrage, Fabien
name: Riniker, Sereina
Publisher: name: ETH Zurich
Year: 2023

description: Nuclear magnetic resonance (NMR) relaxation experiments shine light onto the dynamics of molecular systems in the picosecond to nanosecond timescales. As these methods cannot provide an atomically resolved view of the motion of atoms, functional groups, or domains giving rise to such signals, relaxation techniques have been combined with molecular dynamics (MD) simulations to obtain mechanistic descriptions and gain insights into the functional role of side chain or domain motion. In this work, we present a comparison of five computational methods which permit the joint analysis of MD simulations and NMR relaxation experiments. We discuss their relative strengths and areas of applicability, and demonstrate how they may be utilized to interpret the dynamics in MD simulations with the small protein ubiquitin as test system. We focus on the aliphatic side chains given the rigidity of the backbone of this protein. We find encouraging agreement between experiment, Markov state models built in the χ1/χ2 rotamer space of isoleucine residues, explicit rotamer jump models, and a decomposition of the motion using ROMANCE. These methods allow us to ascribe the dynamics to specific rotamer jumps. Simulations with eight different force fields and three different water models highlight how the different metrics may be employed to pinpoint force field deficiencies. Furthermore, the presented comparison offers a perspective on the utility of NMR relaxation to serve as validation data for the prediction of kinetics by state-of-the-art biomolecular force fields.
description: ChemRxiv
description: ISSN:2573-2293
Mutation order in acute myeloid leukemia identifies uncommon patterns of evolution and illuminates phenotypic heterogeneity
Creators: name: Schwede, Matthew
name: Jahn, Katharina
name: Kuipers, Jack
name: Miles, Linde A.
name: Bowman, Robert L.
name: Robinson, Troy
name: Furudate, Ken
name: Uryu, Hidetaka
name: Tanaka, Tomoyuki
name: Sasaki, Yuya
name: Ediriwickrema, Asiri
name: Benard, Brooks
name: Gentles, Andrew J.
name: Levine, Ross
name: Beerenwinkel, Niko
name: Takahashi, Koichi
name: Majeti, Ravindra
Publisher: name: ETH Zurich
Year: 2023

description: Acute myeloid leukemia (AML) has a poor prognosis and a heterogeneous mutation landscape. Although common mutations are well-studied, little research has characterized how the sequence of mutations relates to clinical features. Using published, single-cell DNA sequencing data from three institutions, we compared clonal evolution patterns in AML to patient characteristics, disease phenotype, and outcomes. Mutation trees, which represent the order of select mutations, were created for 207 patients from targeted panel sequencing data using 1 639 162 cells, 823 mutations, and 275 samples. In 224 distinct orderings of mutated genes, mutations related to DNA methylation typically preceded those related to cell signaling, but signaling-first cases did occur, and had higher peripheral cell counts, increased signaling mutation homozygosity, and younger patient age. Serial sample analysis suggested that NPM1 and DNA methylation mutations provide an advantage to signaling mutations in AML. Interestingly, WT1 mutation evolution shared features with signaling mutations, such as WT1-early being proliferative and occurring in younger individuals, trends that remained in multivariable regression. Some mutation orderings had a worse prognosis, but this was mediated by unfavorable mutations, not mutation order. These findings add a dimension to the mutation landscape of AML, identifying uncommon patterns of leukemogenesis and shedding light on heterogenous phenotypes.
description: Research Square
description: ISSN:2693-5015
Mesochorus (Mesochorus) tenuiscapus THOMSON 1886
Creators: name: Riedel
name: Pénigot
name: Schwarz
name: Diller
name: Johansson
name: Japoshvili, G.
Publisher: name: Zenodo
Year: 2023
Subjects: Biodiversity
Taxonomy
Animalia
Arthropoda
Insecta
Hymenoptera
Ichneumonidae
Mesochorus
Mesochorus tenuiscapus

description: Mesochorus (Mesochorus) tenuiscapus THOMSON, 1886
M a t e r i a l e x a m i n e d: Trap4: 1♀ 10-24.viii.
D i s t r i b u t i o n: Western Palaearctic, known from Georgia (RIEDEL et al. 2018).
description: Published as part of Riedel, Pénigot, Schwarz, Diller, Johansson & Japoshvili, G., 2023, Darwin wasps (Hymenoptera, Ichneumonidae) of the Kintrishi National Park, Sakartvelo (Georgia), with descriptions of six new species, pp. 61-153 in Linzer biologische Beiträge 55 (1) on page 111, DOI: 10.5281/zenodo.10788481
Mesochorus (Mesochorus) testaceus GRAVENHORST 1829
Creators: name: Riedel
name: Pénigot
name: Schwarz
name: Diller
name: Johansson
name: Japoshvili, G.
Publisher: name: Zenodo
Year: 2023
Subjects: Biodiversity
Taxonomy
Animalia
Arthropoda
Insecta
Hymenoptera
Ichneumonidae
Mesochorus
Mesochorus testaceus

description: Mesochorus (Mesochorus) testaceus GRAVENHORST, 1829
M a t e r i a l e x a m i n e d: Trap4: 1♀ 15-29.vi.
D i s t r i b u t i o n: Transpalaearctic, known from Georgia (RIEDEL et al. 2018).
description: Published as part of Riedel, Pénigot, Schwarz, Diller, Johansson & Japoshvili, G., 2023, Darwin wasps (Hymenoptera, Ichneumonidae) of the Kintrishi National Park, Sakartvelo (Georgia), with descriptions of six new species, pp. 61-153 in Linzer biologische Beiträge 55 (1) on page 111, DOI: 10.5281/zenodo.10788481
ROLES OF REMUNERATION ON CONSUMER RESPONSES TOWARDS SOCIAL MEDIA ADVERTISING: A PAKISTANI PERSPECTIVE
Creators: name: Qazi Mohammed Ahmed, Osman Sadiq Paracha
Publisher: name: TuEngr Group
Year: 2020
Subjects: Remuneration Motivation
Consumers' attitudes
Purchase intentions
Behavioral Intention
Electronic word of mouth
Young segment consumers
Perceived social media advertising value (PSMAV).

description: International Transaction Journal of Engineering, Management, & Applied Sciences & Technologies, 11, 5, 11A05J: 1-14
Mesochorus (Mesochorus) tipularius GRAVENHORST 1829
Creators: name: Riedel
name: Pénigot
name: Schwarz
name: Diller
name: Johansson
name: Japoshvili, G.
Publisher: name: Zenodo
Year: 2023
Subjects: Biodiversity
Taxonomy
Animalia
Arthropoda
Insecta
Hymenoptera
Ichneumonidae
Mesochorus
Mesochorus tipularius

description: Mesochorus (Mesochorus) tipularius GRAVENHORST, 1829
M a t e r i a l e x a m i n e d: Trap4: 1♀ 29.vi.-13.vii.
D i s t r i b u t i o n: Holarctic, new record for Georgia and the Caucasus region.
description: Published as part of Riedel, Pénigot, Schwarz, Diller, Johansson & Japoshvili, G., 2023, Darwin wasps (Hymenoptera, Ichneumonidae) of the Kintrishi National Park, Sakartvelo (Georgia), with descriptions of six new species, pp. 61-153 in Linzer biologische Beiträge 55 (1) on page 111, DOI: 10.5281/zenodo.10788481
Mesochorus (Mesochorus) triangulus SCHWENKE 1999
Creators: name: Riedel
name: Pénigot
name: Schwarz
name: Diller
name: Johansson
name: Japoshvili, G.
Publisher: name: Zenodo
Year: 2023
Subjects: Biodiversity
Taxonomy
Animalia
Arthropoda
Insecta
Hymenoptera
Ichneumonidae
Mesochorus
Mesochorus triangulus

description: Mesochorus (Mesochorus) triangulus SCHWENKE, 1999
M a t e r i a l e x a m i n e d: Trap7: 1♀ 27.vii.-20.viii.
D i s t r i b u t i o n: Western Palaearctic, new record for Georgia and the Caucasus region.
description: Published as part of Riedel, Pénigot, Schwarz, Diller, Johansson & Japoshvili, G., 2023, Darwin wasps (Hymenoptera, Ichneumonidae) of the Kintrishi National Park, Sakartvelo (Georgia), with descriptions of six new species, pp. 61-153 in Linzer biologische Beiträge 55 (1) on page 111, DOI: 10.5281/zenodo.10788481
MPEC 2024-K102 : 2024 KK
Creators: name: Minor Planet Center Staff
Publisher: name: The Minor Planet Center
Year: 2024
Subjects: subject: Small Solar System bodies
valueUri: http://astrothesaurus.org/uat/1469
subject: 2024 KK

description: The Minor Planet Electronic Circulars contain information on unusual minor planets, routine data on comets and natural satellites, and occasional editorial announcements.  They are published on behalf of Division F of the International Astronomical Union by the Minor Planet Center, Smithsonian Astrophysical Observatory, Cambridge, MA 02138, U.S.A.
A radical queer utopian future: A reciprocal relation beyond sexual difference
Creators: name: Nicholas, Lucy
Publisher: name: Swinburne
Year: 2024

description: Removing, transcending, or otherwise rendering void or absent sex/gender as a central element of selfhood is an aim rarely pursued in theory or in activism concerned with deconstructing sex/gender. Even in queer and transgender theory that imagines alternative models or landscapes of identity or the self, sex/gender is usually merely adjusted, varied, and multiplied rather than rejected or transcended. The few visions of future landscapes of identity and sexuality in Western contexts that dare to imagine a selfhood without sex /gender, or at least without sexual difference, appear to be limited to a strain of 1970s utopian feminist science fiction and more recently among the theory and prefigurative practices of contemporary anarchist-queer communities. This article views the current relationship between self and other as one that, in departing from the assumption of sex/gender, does not allow subjects to define themselves and others outside of it. In its place I propose an alternative way of being (ethics) derived from a social and intersubjective ontological basis that values reciprocal relations between subjects that are not reducible to antagonism or difference.
Mesochorus (Mesochorus) tuberculiger THOMSON 1886
Creators: name: Riedel
name: Pénigot
name: Schwarz
name: Diller
name: Johansson
name: Japoshvili, G.
Publisher: name: Zenodo
Year: 2023
Subjects: Biodiversity
Taxonomy
Animalia
Arthropoda
Insecta
Hymenoptera
Ichneumonidae
Mesochorus
Mesochorus tuberculiger

description: Mesochorus (Mesochorus) tuberculiger THOMSON, 1886
M a t e r i a l e x a m i n e d: Trap12: 1♀ 13-27.vii.
D i s t r i b u t i o n: Transpalaearctic, new record for Georgia and the Caucasus region.
description: Published as part of Riedel, Pénigot, Schwarz, Diller, Johansson & Japoshvili, G., 2023, Darwin wasps (Hymenoptera, Ichneumonidae) of the Kintrishi National Park, Sakartvelo (Georgia), with descriptions of six new species, pp. 61-153 in Linzer biologische Beiträge 55 (1) on page 111, DOI: 10.5281/zenodo.10788481
A Hierarchical transport architecture for wireless sensor networks
Creators: name: Jin, Jiong
name: Law, Yee Wei
name: Wang, Wei Hua
name: Palaniswami, Marimuthu
Publisher: name: Swinburne
Year: 2024

description: For practical applications, wireless sensor networks (WSNs) with diverse sensor types and that run heterogenous applications are becoming increasingly important. Our motivation in this work is to, for this sort of heterogenous WSNs, devise a flow control and resource allocation algorithm (with respect to both wireless channel usage and sensor node energy), that allow data to be gathered in the fairest manner, while still respecting the needs of different sensing tasks. A two-layer hierarchical transport architecture is designed to guarantee a certain measure of optimality in rate allocation, addressing the balance between fairness and performance. In essence, utility max-min fairness is achieved among upper-layer cluster heads, whereas utility proportional fairness is achieved within each lower-layer cluster. The proposed architecture is to be applied to a real marine sensor network on the Great Barrier Reef.
Gas-Wall Partitioning of Oxygenated Organic Compounds: Measurements, Structure–Activity Relationships, and Correlation with Gas Chromatographic Retention Factor
Creators: name: Yeh, Geoffrey K.
name: Ziemann, Paul J.
Publisher: name: Taylor & Francis
Year: 2015
Subjects: subject: 110309 Infectious Diseases
subject: FOS: Health sciences
subject: Inorganic Chemistry
subject: FOS: Chemical sciences
subject: Chemistry
subject: Earth and Environmental Sciences
subject: Engineering
subject: Biochemistry

description: Gas-wall partitioning of 50 oxygenated organic compounds was investigated by using gas chromatography to monitor time-dependent gas-phase concentrations of authentic standards added to a large Teflon environmental chamber. Compounds included C8–C14 monofunctional ketones and alcohols, C5–C9 monoacids, and C4–C10 diols with linear and cyclic structures. Measured time constants for reaching gas-wall partitioning equilibrium ranged from ∼10 to 100 min with an average value of ∼30 min and exhibited no obvious trend with compound structure, whereas the extent of equilibrium partitioning to the walls ranged from ∼0 to 100% and increased with increasing carbon number and with functional group composition in the order ketones < alcohols < monoacids < diols. When results were modeled using an approach analogous to one commonly used to describe absorptive gas-particle partitioning in terms of compound vapor pressure and aerosol mass loading it was determined that the absorptive properties of the Teflon film walls were equivalent to 2–36 mg m−3 of liquid organic aerosol particles. These results, when combined with those obtained in previous studies, indicate that most multifunctional products formed from the oxidation of atmospherically important hydrocarbons including isoprene, monoterpenes, aromatics, and alkanes have the potential to undergo significant partitioning to the walls of Teflon chambers and thus be lost from further chemical reaction and secondary organic aerosol formation as well as from gas and particle analyses. Two approaches for estimating equilibrium gas-wall partitioning in such studies are presented: one is a structure–activity relationship based on the absorptive gas-wall partitioning model and the other involves the use of observed correlations between gas-wall partitioning and compound retention on a gas chromatographic column.Copyright 2015 American Association for Aerosol Research
A simple framework of utility max-min flow control using sliding mode approach
Creators: name: Jin, Jiong
name: Wang, Wei Hua
name: Palaniswami, Marimuthu
Publisher: name: Swinburne
Year: 2024

description: Motivated by the limitations of current optimal flow control approach, we develop a new utility max-min flow control framework using classic sliding mode control. It consists of a source algorithm and a binary congestion feedback mechanism, in which only the sources with the highest utility at each congested link are required to reduce their transmission rates. It can be directly applied to a multi-service network with heterogeneous applications that have different QoS characteristics. The proposed framework achieves the utility max-min fairness among applications efficiently in the sense of low overhead and rapid convergence. Rigorously, the system is proven to be asymptotically stable by means of Lyapunov's theorem.
Temporal changes in cranial size in South African vlei rats (Otomys): evidence for the ‘third universal response to warming’
Creators: name: Aluwani Nengovhela
name: Baxter, Roderick M
name: Taylor, Peter J
Publisher: name: Taylor & Francis
Year: 2015
Subjects: subject: 110309 Infectious Diseases
subject: FOS: Health sciences
subject: Biological Sciences
subject: Ecology
subject: FOS: Biological sciences
subject: Earth and Environmental Sciences
subject: Evolutionary Biology

description: Using museum collections and recently collected specimens we studied geographical and temporal (from 1906 to 2013) changes in skull size of two sibling species of rodents, Otomys auratus and O. angoniensis, in northern South Africa occupying distinct temperate grassland (O. auratus) and subtropical savanna (O. angoniensis) biomes. We hypothesised that cranial size should vary in space and time within species according to Bergmann's Rule, which predicts an inverse relationship between body size and temperature. We used the greatest length of the skull (GLS) as a robust indicator of body size. Cranial size of both O. auratus and O. angoniensis decreased significantly over the past 100 years, as expected given historical evidence of warming across northern South Africa since the 1950s. In terms of geographical patterns, GLS was inversely correlated with both latitude and longitude in O. auratus but these trends were correlated with annual rainfall rather than mean annual temperature. Conversely, cranial size of O. angoniensis was weakly positively correlated with longitude but with no climatic variables. Our results demonstrate rapid morphological changes in two herbivorous South African rodents over the past 100 years. Whilst the general decline in size with time in relation to increased temperature is consistent with Bergmann's Rule, multiple drivers may underlie geographical trends in the two species.
Mesochorus (Mesochorus) viator SCHWENKE 2004
Creators: name: Riedel
name: Pénigot
name: Schwarz
name: Diller
name: Johansson
name: Japoshvili, G.
Publisher: name: Zenodo
Year: 2023
Subjects: Biodiversity
Taxonomy
Animalia
Arthropoda
Insecta
Hymenoptera
Ichneumonidae
Mesochorus
Mesochorus viator

description: Mesochorus (Mesochorus) viator SCHWENKE, 2004
M a t e r i a l e x a m i n e d: Trap 7: 1♀ 5-20.v., 1♀ 27.vii.-10.viii.
D i s t r i b u t i o n: Western Palaearctic, new record for Georgia and the Caucasus region.
description: Published as part of Riedel, Pénigot, Schwarz, Diller, Johansson & Japoshvili, G., 2023, Darwin wasps (Hymenoptera, Ichneumonidae) of the Kintrishi National Park, Sakartvelo (Georgia), with descriptions of six new species, pp. 61-153 in Linzer biologische Beiträge 55 (1) on page 111, DOI: 10.5281/zenodo.10788481
Mesochorus (Mesochorus) vittator
Creators: name: Riedel
name: Pénigot
name: Schwarz
name: Diller
name: Johansson
name: Japoshvili, G.
Publisher: name: Zenodo
Year: 2023
Subjects: Biodiversity
Taxonomy
Animalia
Arthropoda
Insecta
Hymenoptera
Ichneumonidae
Mesochorus
Mesochorus vittator

description: Mesochorus (Mesochorus) vittator (ZETTERSTEDT, 1838)
M a t e r i a l e x a m i n e d: Trap 2: 1♀ 5-20.v., 2♀♀ 7-21.ix.; trap 4: 2♀♀ 15-29.vi., 2♀♀ 29.vi.-13.vii., 1♀ 13-27.vii., 1♀ 27.vii.-10.viii., 1♀ 7-21.ix.; trap 7: 1♀ 19.x.-3.xi.
D i s t r i b u t i o n: Holarctic and Neotropical, known from Georgia (RIEDEL et al. 2018).
description: Published as part of Riedel, Pénigot, Schwarz, Diller, Johansson & Japoshvili, G., 2023, Darwin wasps (Hymenoptera, Ichneumonidae) of the Kintrishi National Park, Sakartvelo (Georgia), with descriptions of six new species, pp. 61-153 in Linzer biologische Beiträge 55 (1) on page 111, DOI: 10.5281/zenodo.10788481
Chorinaeus brevicalcar THOMSON 1887
Creators: name: Riedel
name: Pénigot
name: Schwarz
name: Diller
name: Johansson
name: Japoshvili, G.
Publisher: name: Zenodo
Year: 2023
Subjects: Biodiversity
Taxonomy
Animalia
Arthropoda
Insecta
Hymenoptera
Ichneumonidae
Chorinaeus
Chorinaeus brevicalcar

description: Chorinaeus brevicalcar THOMSON, 1887
M a t e r i a l e x a m i n e d: Trap4:1♁15-29.vi.
D i s t r i b u t i o n: Transpalaearctic, new record for Georgia and the Caucasus region.
description: Published as part of Riedel, Pénigot, Schwarz, Diller, Johansson & Japoshvili, G., 2023, Darwin wasps (Hymenoptera, Ichneumonidae) of the Kintrishi National Park, Sakartvelo (Georgia), with descriptions of six new species, pp. 61-153 in Linzer biologische Beiträge 55 (1) on page 112, DOI: 10.5281/zenodo.10788481
The HNO donor ability of hydroxamic acids upon oxidation with cyanoferrates(III)
Creators: name: Gutiérrez, María M.
name: Almaraz, Alejandra E.
name: Bari, Sara E.
name: Olabe, José A.
name: Amorebieta, Valentín T.
Publisher: name: Taylor & Francis
Year: 2015
Subjects: subject: Inorganic Chemistry
subject: FOS: Chemical sciences
subject: Marine Biology
subject: Ecology
subject: FOS: Biological sciences
subject: Chemistry
subject: Earth and Environmental Sciences
subject: Physiology
subject: Microbiology
subject: Biochemistry
subject: Biophysics

description: The hydroxamic acids (RC(O)NHOH, HA) exhibit diverse biological activity, including hypotensive properties associated with formation of nitroxyl (HNO) or nitric oxide (NO). Oxidation of two HAs, benzohydroxamic and acetohydroxamic acids (BHA, AHA) by [Fe(CN)5NH3]2− or [Fe(CN)6]3− was analyzed by spectroscopic, mass spectrometric techniques, and flow EPR measurements. Mixing BHA with both Fe(III) reactants at pH 11 allowed detecting the hydroxamate radical, (C6H5)C(O)NO˙−, as a one-electron oxidation product, as well as N2O as a final product. Successive UV–vis spectra of mixtures containing [Fe(CN)5NH3]2− (though not [Fe(CN)6]3−) at pH 11 and 7 revealed an intermediate acylnitroso-complex, [Fe(CN)5NOC(O)(C6H5)]3− (λmax, 465 nm, very stable at pH 7), formed through ligand interchange in the initially formed reduction product, [Fe(CN)5NH3]3−, and characterized by FTIR spectra through the stretching vibrations ν(CN), ν(CO), and ν(NO). Free acylnitroso derivatives, formed by alternative reaction paths of the hydroxamate radicals, hydrolyze forming RC(O)OH and HNO, postulated as precursor of N2O. Minor quantities of NO are formed only with an excess of oxidant. The intermediacy of HNO was confirmed through its identification as [Fe(CN)5(HNO)]3− (λmax, 445 nm) as a result of hydrolysis of [Fe(CN)5(NOC(O)(C6H5)]3− at pH 11. The results demonstrate that hydroxamic acids behave predominantly as HNO donors.
Synthesis and stability of 2+1 complexes of N,N-diethylbenzoylthiourea with [MI(CO)3]+ (M = Re, 99mTc)
Creators: name: Hayes, Thomas R.
name: Powell, Ashton S.
name: Barnes, Charles L.
name: Benny, Paul D.
Publisher: name: Taylor & Francis
Year: 2015
Subjects: Biological Sciences
Chemistry
Biotechnology
Molecular Biology
Cell Biology
Biochemistry
Biophysics

description: In the last two decades, the fac-[MI(OH2)3(CO)3]+ (M = Re, 99mTc) core has been an important synthon in the development of new radiopharmaceuticals and methodologies. A bidentate N,N-diethylbenzoylthiourea (HEt2btu, H1) ligand was reacted with fac-[MI(OH2)3(CO)3]+ as part of a 2+1 strategy consisting of a bidentate and a monodentate ligands to saturate the coordination sphere. When excess H1 was used in the reaction, an unusual 2+1 complex of fac-[ReI(CO)3(1)(H1)], 2, was isolated that contained two H1 ligands, OS bidentate and S monodentate in different protonation states. Equimolar concentrations of HEt2btu and fac-[ReI(CO)3]+ generated the single addition of the ligand; however, isolation of the solid revealed a μ-sulfur-bridged dimer of fac-[ReI(CO)31)]2, 3. Reaction of H1 with fac-[MI(OH2)3(CO)3]+ followed by the addition of a monodentate ligand (i.e. pyridine, methyl imidazole, cyclohexyl isocyanide, triphenylphosphine) yielded the corresponding 2+1 fac-[MI(CO)3(1)(L)] complexes. Single-crystal X-ray structural analysis of the Re complexes revealed conformational differences of the ligand on the metal depending on the protonation state of the central amine in the protonated H1versus1 ligand. Comparison of these complexes with previous complexes and free H1 revealed significant shifts in the bond angles, bond lengths, and ligand planarity that are discussed further. The corresponding 2+1 fac-[99mTcI(CO)3(1)(L)] complexes were also prepared in moderate to good yields and their stability examined by amino acid challenge studies.
Utility max-min fair resource allocation for communication networks with multipath routing
Creators: name: Jin, Jiong
name: Wang, Wei Hua
name: Palaniswami, Marimuthu
Publisher: name: Swinburne
Year: 2024

description: This paper considers the flow control and resource allocation problem as applied to the generic multipath communication networks with heterogeneous applications. We propose a novel distributed algorithm, show and prove that among all the sources with positive increasing and bounded utilities (no need to be concave) in steady state, the utility max-min fairness is achieved, which is essential for balancing Quality of Service (QoS) for different applications. By combining the first order Lagrangian method and filtering mechanism, the adopted approach eliminates typical oscillation behavior in multipath networks and possesses a rapid convergence property. In addition, the algorithm is capable of deciding the optimal routing strategy and distributing the total traffic evenly out of the available paths. The performance of our utility max-min fair flow control algorithm is evaluated through simulations under two representative case studies, as well as the real implementation issues are addressed deliberately for the practical purpose.
The Impact of Green Areas on Mitigating Urban Heat Island Effect: A Review
Creators: name: Shishegar, Nastaran
Publisher: name: figshare
Year: 2015
Subjects: Design
Climate Science

description: Urban Heat Island (UHI) is considered as one of the major problems in the 21st century as a consequence of urbanisation and industrialisation of human civilisation. The main source of UHI is the large amount of heat produced from urban structures, as they absorb and re-radiate solar radiations. Therefore, Urban Heat Islands develop in areas with a high percentage of non-reflective, water-resistant surfaces and a low percentage of vegetation. Specifically, a lack of vegetation reduces heat lost due to evapotranspiration. Vegetation, particularly in the presence of high moisture levels, plays a vital role in the regulation of surface temperatures, even more than may non- reflective or low-albedo surfaces. There are different ways of reducing the effects of UHI. However, a common measure to mitigate Urban Heat Island is to increase urban green spaces such as parks, street trees and green roofs. This paper discusses the current literature and knowledge about the impacts of green spaces on mitigating UHI. Studies conducted on the influence of greenery on mitigating UHI have indicated that all green spaces help urban areas adapt to the impact of UHI regardless of whether they are parks, street trees or green roofs.
Catalytic oxygenation of various monophenols by copper(I) complexes with bis(pyrazolyl)methane ligands: differences in reactivity
Creators: name: Hamann, Jessica Nadine
name: Schneider, Rebecca
name: Tuczek, Felix
Publisher: name: Taylor & Francis
Year: 2015
Subjects: Biological Sciences
Chemistry
Earth and Environmental Sciences
Molecular Biology
Biochemistry

description: Three new mononuclear copper(I) complexes supported by the symmetric ligands 1,1′-methylenebis-1H-pyrazole (BPM), 1,1′-methylenebis(3-methyl-1H-pyrazole) (mBPM), and 1,1′-methylenebis(3,5-di-methyl-1H-pyrazole) (dmBPM) were synthesized as catalytic model systems of tyrosinase. The influence of various functional groups on the catalytic conversion of monophenols is investigated and the formation of the corresponding ortho-quinones is monitored using UV/vis and NMR spectroscopy. Comparison of various monophenols reveals the differences in reactivity which are analyzed and interpreted based on key intermediates of the mechanistic cycle.
Interventions to reduce self-stigma among people living with HIV: A Systematic review
Creators: name: France, Nadine Ferris
name: Lyons, Sophie
name: Cioringa, Ana
name: Webster Mavhu
name: Miramontes, Iria Manas
name: Byrne, Elaine
Publisher: name: University of Limerick
Year: 2025
Subjects: classificationCode: 42
subject: Health sciences
subject: FOS: Health sciences

description: Over 4 decades into the global HIV pandemic, HIV-related self-stigma—a mindset of negative beliefs, thoughts, and behaviors a person holds about themselves—remains a major barrier to HIV treatment, management, and care. HIV-related self-stigma is a persistent public health threat and leads to depression and other mental health problems, lowers adherence to antiretroviral medication, and acts as a barrier to health services. Not enough is known about what interventions work and how they work to reduce self-stigma. We conducted a systematic review of existing interventions that address self-stigma among people living with HIV to address this gap. We searched PubMed, Embase, and Web of Science; used Covidence review software; dual-screened the results; extracted data from each included study; analyzed the data using Cochrane guidelines and the Template for Intervention Description and Replication Framework; and categorized the content based on emerging themes around the intervention/program. We included 35 studies in the review, with the majority (32/35, 91%) showing promise to reduce HIV self-stigma or components of self-stigma. Intervention approaches included working on thoughts, feelings, and beliefs through a range of cognitive-based, inquiry-based, and mindful-based techniques, often with a forward-looking goal-setting focus. However, comparison of studies was difficult with different definitions and understandings of self-stigma and different measurement scales. Many studies were small-scale and lacked sufficient in-depth descriptions. This study makes an important contribution to the field of HIV more broadly and HIV-related stigma, specifically, in proposing a common definition of self-stigma and providing in-depth descriptions of interventions in terms of content, type, level, and effectiveness.
Colpotrochia cincta
Creators: name: Riedel
name: Pénigot
name: Schwarz
name: Diller
name: Johansson
name: Japoshvili, G.
Publisher: name: Zenodo
Year: 2023
Subjects: Biodiversity
Taxonomy
Animalia
Arthropoda
Insecta
Hymenoptera
Ichneumonidae
Colpotrochia
Colpotrochia cincta

description: Colpotrochia cincta (SCOPOLI, 1763)
M a t e r i a l e x a m i n e d: Trap 7: 1♁ 23.iv.-5.v., 1♁ 5-20.v., 1♀ 1♁ 1-25.vi., 1♁ 27.vii.- 10.viii., 1♁ 10-24.viii., 2♁♁ 7-21.ix., 1♀ 21.ix.-5.x., 1♁ 19.x.-3.xi.; trap 12: 1♁ 10-24.viii.
D i s t r i b u t i o n: Transpalaearctic, known from Georgia (DJANELIDZE 1967, RIEDEL & JAPOSHVILI 2021).
description: Published as part of Riedel, Pénigot, Schwarz, Diller, Johansson & Japoshvili, G., 2023, Darwin wasps (Hymenoptera, Ichneumonidae) of the Kintrishi National Park, Sakartvelo (Georgia), with descriptions of six new species, pp. 61-153 in Linzer biologische Beiträge 55 (1) on page 112, DOI: 10.5281/zenodo.10788481
Getting in front of homelessness: Housing single older women now
Creators: name: Sharam, Andrea
Publisher: name: Swinburne
Year: 2024

description: Single older women in Australia have emerged as a growing population group vulnerable to housing insecurity and at risk of homelessness in their old age. Their vulnerability arises from the gendered nature of labour and child rearing in Australia which compromises women's lifetime capacity to earn, acquire and retain housing equity. This is exacerbated by inflated housing purchase prices, increasing rental costs, low rental vacancies, and an age pension system that assumes full home ownership at retirement. The Salvation Army Southern Territory commissioned research in response to the growing number of women entering the welfare system in old age due to insufficient capital resources and income to provide for their retirement. A survey was undertaken, aimed at single women over the age of 40 with or without children who did not believe they would own their housing outright when they retired. The research sought to find out more about their current housing situation and needs and their aspirations and capacity for meeting their longer-term housing needs. It also tested women's attitudes to an alternative affordable housing model based on a land trust where land would be donated and in which they would be required to contribute equity but would have restrictions, for instance, on capture of capital gains. The research wanted to understand whether an affordable housing model based on a land trust would be viable in terms of consumer capacity to pay and preferences.
The HNO donor ability of hydroxamic acids upon oxidation with cyanoferrates(III)
Creators: name: Gutiérrez, María M.
name: Almaraz, Alejandra E.
name: Bari, Sara E.
name: Olabe, José A.
name: Amorebieta, Valentín T.
Publisher: name: Taylor & Francis
Year: 2015
Subjects: subject: Inorganic Chemistry
subject: FOS: Chemical sciences
subject: Marine Biology
subject: Ecology
subject: FOS: Biological sciences
subject: Chemistry
subject: Earth and Environmental Sciences
subject: Physiology
subject: Microbiology
subject: Biochemistry
subject: Biophysics

description: The hydroxamic acids (RC(O)NHOH, HA) exhibit diverse biological activity, including hypotensive properties associated with formation of nitroxyl (HNO) or nitric oxide (NO). Oxidation of two HA’s, benzohydroxamic and acetohydroxamic acids (BHA, AHA) by [Fe(CN)5NH3]2− or [Fe(CN)6]3− was analyzed by spectroscopic, mass spectrometric techniques, and flow EPR measurements. Mixing BHA with both Fe(III) reactants at pH 11 allowed detecting the hydroxamate radical, (C6H5)C(O)NO• −, as a 1-electron oxidation product, as well as N2O as a final product. Successive UV-vis spectra of mixtures containing [Fe(CN)5NH3]2− (though not [Fe(CN)6]3−) at pH 11 and 7 revealed an intermediate acylnitroso-complex, [Fe(CN)5(NOC(O)(C6H5)]3− (λmax, 465 nm, very stable at pH 7), formed through ligand-interchange in the initially formed reduction product, [Fe(CN)5NH3]3−, and characterized by FTIR spectra through the stretching vibrations ν(CN−), ν(CO) and ν(NO). Free acylnitroso derivatives, formed by alternative reaction paths of the hydroxamate radicals, hydrolyze forming RC(O)OH and HNO, postulated as precursor of N2O. Minor quantities of NO are formed only with an excess of oxidant. The intermediacy of HNO was confirmed through its identification as [Fe(CN)5(HNO)]3− (λmax, 445 nm) as a result of hydrolysis of [Fe(CN)5(NOC(O)(C6H5)]3− at pH 11. The results demonstrate that hydroxamic acids behave predominantly as HNO-donors.
Exochus erythronotus
Creators: name: Riedel
name: Pénigot
name: Schwarz
name: Diller
name: Johansson
name: Japoshvili, G.
Publisher: name: Zenodo
Year: 2023
Subjects: Biodiversity
Taxonomy
Animalia
Arthropoda
Insecta
Hymenoptera
Ichneumonidae
Exochus
Exochus erythronotus

description: Exochus erythronotus (GRAVENHORST, 1820)
M a t e r i a l e x a m i n e d: Trap 2: 1♀ 21.ix.-5.x.
D i s t r i b u t i o n: Western Palaearctic, known from Georgia (RIEDEL et al. 2018).
description: Published as part of Riedel, Pénigot, Schwarz, Diller, Johansson & Japoshvili, G., 2023, Darwin wasps (Hymenoptera, Ichneumonidae) of the Kintrishi National Park, Sakartvelo (Georgia), with descriptions of six new species, pp. 61-153 in Linzer biologische Beiträge 55 (1) on page 112, DOI: 10.5281/zenodo.10788481
Deliverable-D-JIP2-D4.5-Report-of-available-tools-and-algorithms-and-ranking-of-most-valuable-features (COHESIVE)
Creators: name: COHESIVE
Publisher: name: Zenodo
Year: 2020

description: Deliverable-D-JIP2-D4.5-Report-of-available-tools-and-algorithms-and-ranking-of-most-valuable-features (COHESIVE) COHESIVE OHEJP Project deliverable
FACTORES ASOCIADOS A DEFECTOS CONGÉNITOS
Creators: name: Vasco-Toapanta, Cristhian Santiago
name: Salas Escobar, Pablo Andrés
name: Espinoza Serrano, Alisson Estefany
name: Guanoluisa Vasco, Alisson Mayerly
Publisher: name: Zenodo-HGOIA
Year: 2024
Subjects: Anomalías congénitas
recién nacido
factor de riesgo perinatal

description: El riesgo de anomalías congénitas es universal y tienen un impacto en la mortalidad y morbilidad de los individuos afectados. Los estudios epidemiológicos son esenciales para mejorar el  entendimiento de los factores de riesgo asociados.

OBJETIVO: Determinar los factores de riesgo asociados a anomalías congénitas en recién nacidos ingresados en el Hospital Gineco-Obstétrico Isidro Ayora de Quito.
Synthesis and stability of 2+1 complexes of N,N-diethylbenzoylthiourea with [MI(CO)3]+ (M = Re, 99mTc)
Creators: name: Hayes, Thomas R.
name: Powell, Ashton S.
name: Barnes, Charles L.
name: Benny, Paul D.
Publisher: name: Taylor & Francis
Year: 2015
Subjects: Biological Sciences
Chemistry
Biotechnology
Molecular Biology
Cell Biology
Biochemistry
Biophysics

description: In the last two decades, the fac-[MI(OH2)3(CO)3]+ (M = Re, 99mTc) core has been an important synthon in the development of new radiopharmaceuticals and methodologies. A bidentate N,N-diethylbenzoylthiourea (HEt2btu, H1) ligand was reacted with fac-[MI(OH2)3(CO)3]+ as part of a 2+1 strategy consisting of a bidentate and a monodentate ligands to saturate the coordination sphere. When excess H1 was used in the reaction, an unusual 2+1 complex of fac-[ReI(CO)3(1)(H1)], 2, was isolated that contained two H1 ligands, OS bidentate and S monodentate in different protonation states. Equimolar concentrations of HEt2btu and fac-[ReI(CO)3]+ generated the single addition of the ligand, however, isolation of the solid revealed a μ-sulfur bridged dimer of fac-[ReI(CO)31)]2, 3. Reaction of H1 with fac-[MI(OH2)3(CO)3]+ followed by addition of a monodentate ligand (i.e., pyridine, methyl imidazole, cyclohexyl isocyanide, triphenylphosphine) yielded the corresponding 2+1 fac-[MI(CO)3(1)(L)] complexes. Single crystal X-ray structural analysis of the Re complexes revealed conformational differences of the ligand on the metal depending on the protonation state of the central amine in the protonated H1 vs. 1 ligand. Comparison of these complexes with previous complexes and free H1 revealed significant shifts in the bond angles, bond lengths, and ligand planarity that are discussed further. The corresponding 2+1 fac-[99mTcI(CO)3(OS-1)(L)] complexes were also prepared in moderate to good yields and their stability examined by amino acid challenge studies.
Exploring predictors of job satisfaction in call centres -the case of Australia
Creators: name: Annakis, John
name: Lobo, Tony
name: Pillay, Soma
Publisher: name: Swinburne
Year: 2024

description: In this paper we examine predictors of job satisfaction within the call centre industry. Using a qualitative methodology, we investigate the nature and extent of job satisfaction of customer service representatives in two large Australian call centres. The findings from the study confirm that monitoring, personal privacy and flexibility correlate to workers' wellbeing and job satisfaction.
Subordinate external employment opportunities and corporate decision-making
Creators: name: Cai, Yue
Publisher: name: The Australian National University
Year: 2022

description: I examine the impact of the external labour market on subordinate executives' incentives and behaviour associated with firms' financial reporting quality and investment choices. Specifically, I test how the strength of the external employment opportunities facing subordinates influences focal firms' earnings management choices, overall investment level, the level of excess cash holdings and the likelihood of cutting committed resources following sales drops. I find that firms whose subordinates face greater external employment opportunities, measured by the compensation difference between focal firms' subordinates and their peers, tend to engage more aggressively in income-increasing real and accrual-based earnings management. This result is robust to alternative methods of peer identification schemes, alternative measures of subordinate external pay gaps, suspect firm sample analyses and propensity score matched sample analyses. Further, the association between the subordinate external employment opportunities and focal firms' income-increasing real and accrual-based earnings management is stronger in years in which the likelihood of firms' engaging in earnings management is higher. I also show that on classifying subordinates according to their predominant functional roles (financial or operating), operating subordinates' incentives can significantly influence both accruals-based and real earnings management whereas financial subordinates do not seem to have independent effects on accruals management. One possible interpretation is that financial subordinates are held more responsible for focal firms' financial statements and may incur higher financial or reputational costs, such as legal punishments or fines, if financial misconduct is revealed. With regard to the impact of the value of subordinates' external employment opportunities on focal firms' decisions regarding investment behaviour, I find that although the strength of such opportunities has a positive impact on focal firms' tendency to underinvest, it does not significantly affect firms' excess cash holdings. Further, firms with larger subordinate external pay gaps tend to cut less of resources they have committed following a decrease in sales. However, these findings are highly sensitive to peer identification schemes.
Temperature- and pressure-dependent kinetico-mechanistic studies on the formation of mixed-valence {(tetraamine)CoIIINCFeII(CN)5}− units
Creators: name: Alcázar, Laura
name: Bogdándi, Virág
name: Lente, Gábor
name: Martínez, Manuel
name: Vázquez, Marta
Publisher: name: Taylor & Francis
Year: 2015
Subjects: Biological Sciences
Chemistry
Earth and Environmental Sciences
Cell Biology
Biochemistry
Biophysics

description: The reduction of CoIII in the tetraamine-encapsulating ligand complex [CoIII{(μ-ET)(Me2)cyclen}(H2O)2]3+ by [FeII(CN)6]4− has been studied kinetico-mechanistically at different pH, temperatures, and pressures. The process agrees with the expected outer-sphere redox mechanism, with the value of the encounter-complex equilibrium constant large enough to allow for kinetic determination of the first-order electron transfer reaction rate constant. The value of the encounter-complex equilibrium constant, Kpre-eq, is not only dependent on the charge of the redox partners, but also on the establishment of an important network of hydrogen bonds. These can also explain the differences obtained in the activation volumes determined for the diaqua and bis-hydroxo complexes. Neither the leaching of CoII nor the presence of [FeIII(CN)6]3− is observed in the final reaction medium, which indicates that a fast sequence involving substitution on the transient CoII complex followed by a fast inner-sphere electron transfer takes place. This sort of mechanism has already been established for encapsulating pentaamine ligand complexes, but this is the first example of such a sequential reaction occurring on a tetradentate ligand complex. Preliminary UV–Vis and electrochemical characterization experiments have been conducted on the final reaction mixtures, suggesting the formation of a stable cyanide-bridged CoIII/FeII mixed-valence complex of the same type reported in the literature for encapsulating {CoIII(N)5} skeletons.
Exochus ferus TOLKANITZ 1993
Creators: name: Riedel
name: Pénigot
name: Schwarz
name: Diller
name: Johansson
name: Japoshvili, G.
Publisher: name: Zenodo
Year: 2023
Subjects: Biodiversity
Taxonomy
Animalia
Arthropoda
Insecta
Hymenoptera
Ichneumonidae
Exochus
Exochus ferus

description: Exochus ferus TOLKANITZ, 1993
M a t e r i a l e x a m i n e d: Trap 7: 1♁ 10-24.viii., 1♀ 24.viii.-7.ix.
D i s t r i b u t i o n: Transpalaearctic, known from Armenia (TOLKANITZ 2007), new record for Georgia.
description: Published as part of Riedel, Pénigot, Schwarz, Diller, Johansson & Japoshvili, G., 2023, Darwin wasps (Hymenoptera, Ichneumonidae) of the Kintrishi National Park, Sakartvelo (Georgia), with descriptions of six new species, pp. 61-153 in Linzer biologische Beiträge 55 (1) on page 112, DOI: 10.5281/zenodo.10788481
Catalytic oxygenation of various monophenols by copper(I) complexes with bis(pyrazolyl)methane ligands: Differences in reactivity
Creators: name: Hamann, Jessica Nadine
name: Schneider, Rebecca
name: Tuczek, Felix
Publisher: name: Taylor & Francis
Year: 2015
Subjects: Biological Sciences
Chemistry
Earth and Environmental Sciences
Molecular Biology
Biochemistry

description: Three new mononuclear copper(I) complexes supported by the symmetric ligands 1,1'–methylenebis-1H-pyrazole (BPM), 1,1'-methylenebis(3-methyl-1H-pyrazole) (mBPM) and 1,1'-methylenebis(3,5-di-methyl-1H-pyrazole) (dmBPM) were synthesized as catalytic model systems of tyrosinase. The influence of various functional groups on the catalytic conversion of monophenols is investigated and the formation of the corresponding ortho-quinones is monitored using UV/Vis and NMR spectroscopy. Comparison of various monophenols reveals differences in reactivity which are analyzed and interpreted based on key intermediates of the mechanistic cycle.
Identifying business value from the use of social media: An SME perspective
Creators: name: Stockdale, Rosemary
name: Ahmed, Ashir
name: Scheepers, Helana
Publisher: name: Swinburne
Year: 2024

description: This research examines how smaller businesses can derive business value from the use of social media. Conducted from the SME perspective, the study first examines the relevant literature to identify the key issues involved in the use of social media. It then examines five established case studies and the case firms' websites. The extracted data is used to draw insights into the business problems and objectives that influence SMEs to use social media. Business value is found to lie primarily in the domain of customer engagement and the realisation of benefits is strongly influenced by the ability of the SME to identify with their customer base. It is anticipated that the findings of this research will foster an understanding of the business value that can be derived from social media by small and medium enterprises.