title: ÐÑÑÐ»ÐµÐ´Ð¾Ð²Ð°Ð½Ð¸Ðµ ÑÐ¾ÑÑÐ°Ð²Ð° Ð¿ÑÐ¾Ð´ÑÐºÑÐ¾Ð² Ð²Ð·Ð°Ð¸Ð¼Ð¾Ð´ÐµÐ¹ÑÑÐ²Ð¸Ñ Ð°Ð½Ð¸Ð·Ð¾Ð»ÑÑÐ° ÑÑÐ¸ÑÑÐ¾ÑÐ¸Ð´Ð° Ð±Ð¾ÑÐ° Ñ ÐºÐ¸ÑÐ»Ð¾ÑÐ¾Ð´Ð¾Ð¼ Ð² ÑÐµÐ¶Ð¸Ð¼Ðµ Ð³Ð¾ÑÐµÐ½Ð¸Ñ Ð½Ð° Ð¾ÑÐ½Ð¾Ð²Ðµ ÑÐµÑÐ¼Ð¾Ð´Ð¸Ð½Ð°Ð¼Ð¸ÑÐµÑÐºÐ¸Ñ ÑÐ°ÑÑÑÑÐ¾Ð²
title: Ð²ÑÐ¿ÑÑÐºÐ½Ð°Ñ ÐºÐ²Ð°Ð»Ð¸ÑÐ¸ÐºÐ°ÑÐ¸Ð¾Ð½Ð½Ð°Ñ ÑÐ°Ð±Ð¾ÑÐ° Ð¼Ð°Ð³Ð¸ÑÑÑÐ°
titleType: Subtitle
title: Research of the composition of products of interaction of boron trifluoride anisolate with oxygen in the combustion mode on the basis of thermodynamic calculations
Creators: name: ÐÐ»Ð¸ÑÐ¾Ð², ÐÐ¸ÑÐ°Ð¸Ð»
Publisher: name: Ð¡Ð°Ð½ÐºÑ-ÐÐµÑÐµÑÐ±ÑÑÐ³ÑÐºÐ¸Ð¹ Ð¿Ð¾Ð»Ð¸ÑÐµÑÐ½Ð¸ÑÐµÑÐºÐ¸Ð¹ ÑÐ½Ð¸Ð²ÐµÑÑÐ¸ÑÐµÑ ÐÐµÑÑÐ° ÐÐµÐ»Ð¸ÐºÐ¾Ð³Ð¾
Year: 2022
Subjects: ÐÐ¾Ñ, ÑÐ¾ÐµÐ´Ð¸Ð½ÐµÐ½Ð¸Ñ
ÐÐµÑÐ°Ð»Ð»Ñ
Ð°Ð½Ð¸Ð·Ð¾Ð»
ÑÑÐ¸ÑÑÐ¾ÑÐ¸Ð´ Ð±Ð¾ÑÐ°
ÑÐ½ÐµÑÐ³Ð¸Ñ Ð³Ð¸Ð±Ð±ÑÐ°
ÑÐ°Ð²Ð½Ð¾Ð²ÐµÑÐ½ÑÐ¹ ÑÐ¾ÑÑÐ°Ð²
Ð¾ÐºÐ¸ÑÐ»ÐµÐ½Ð¸Ðµ
anisole
boron trifluoride
gibbs energy
equilibrium composition
oxidation

description: Ð¢ÐµÐ¼Ð° Ð²ÑÐ¿ÑÑÐºÐ½Ð¾Ð¹ ÐºÐ²Ð°Ð»Ð¸ÑÐ¸ÐºÐ°ÑÐ¸Ð¾Ð½Ð½Ð¾Ð¹ ÑÐ°Ð±Ð¾ÑÑ: Â«ÐÑÑÐ»ÐµÐ´Ð¾Ð²Ð°Ð½Ð¸Ðµ ÑÐ¾ÑÑÐ°Ð²Ð° Ð¿ÑÐ¾Ð´ÑÐºÑÐ¾Ð² Ð²Ð·Ð°Ð¸Ð¼Ð¾Ð´ÐµÐ¹ÑÑÐ²Ð¸Ñ Ð°Ð½Ð¸Ð·Ð¾Ð»ÑÑÐ° ÑÑÐ¸ÑÑÐ¾ÑÐ¸Ð´Ð° Ð±Ð¾ÑÐ° Ñ ÐºÐ¸ÑÐ»Ð¾ÑÐ¾Ð´Ð¾Ð¼ Ð² ÑÐµÐ¶Ð¸Ð¼Ðµ Ð³Ð¾ÑÐµÐ½Ð¸Ñ Ð½Ð° Ð¾ÑÐ½Ð¾Ð²Ðµ ÑÐµÑÐ¼Ð¾Ð´Ð¸Ð½Ð°Ð¼Ð¸ÑÐµÑÐºÐ¸Ñ ÑÐ°ÑÑÑÑÐ¾Ð²Â». ÐÐ°Ð½Ð½Ð°Ñ ÑÐ°Ð±Ð¾ÑÐ° Ð¿Ð¾ÑÐ²ÑÑÐµÐ½Ð° Ð¸ÑÑÐ»ÐµÐ´Ð¾Ð²Ð°Ð½Ð¸Ñ Ð¾Ð´Ð½Ð¾Ð³Ð¾ Ð¸Ð· ÑÐ¿Ð¾ÑÐ¾Ð±Ð¾Ð² ÑÐ°Ð·Ð´ÐµÐ»ÐµÐ½Ð¸Ñ ÑÐ¸ÑÑÐµÐ¼Ñ Ð°Ð½Ð¸Ð·Ð¾Ð»-ÑÑÐ¸ÑÑÐ¾ÑÐ¸Ð´ Ð±Ð¾ÑÐ°, Ð° ÑÐ°ÐºÐ¶Ðµ Ð¾Ð¿ÑÐµÐ´ÐµÐ»ÐµÐ½Ð¸Ñ ÑÐµÑÐ¼Ð¾Ð´Ð¸Ð½Ð°Ð¼Ð¸ÑÐµÑÐºÐ¸ ÑÐ°Ð²Ð½Ð¾Ð²ÐµÑÐ½Ð¾Ð³Ð¾ ÑÐ¾ÑÑÐ°Ð²Ð° Ð²ÐµÑÐµÑÑÐ² Ð² ÑÐ¸ÑÑÐµÐ¼Ðµ ÑÐ»ÐµÐ¼ÐµÐ½ÑÐ¾Ð², ÑÐ¾Ð¾ÑÐ²ÐµÑÑÑÐ²ÑÑÑÐµÐ¹ Ð¾ÐºÐ¸ÑÐ»ÐµÐ½Ð¸Ñ Ð´Ð°Ð½Ð½Ð¾Ð¹ ÑÐ¸ÑÑÐµÐ¼Ñ. ÐÐ°Ð´Ð°ÑÐ¸, ÐºÐ¾ÑÐ¾ÑÑÐµ ÑÐµÑÐ°Ð»Ð¸ÑÑ Ð² ÑÐ¾Ð´Ðµ Ð¸ÑÑÐ»ÐµÐ´Ð¾Ð²Ð°Ð½Ð¸Ñ: ÐÑÐµÐ½ÐºÐ° Ð·Ð½Ð°ÑÐµÐ½Ð¸Ñ Ð°Ð´Ð¸Ð°Ð±Ð°ÑÐ¸ÑÐµÑÐºÐ¾Ð¹ ÑÐµÐ¼Ð¿ÐµÑÐ°ÑÑÑÑ Ð¿ÑÐ¾Ð´ÑÐºÑÐ¾Ð² Ð¾ÐºÐ¸ÑÐ»ÐµÐ½Ð¸Ñ Ð°Ð½Ð¸Ð·Ð¾Ð»Ð° Ð´Ð»Ñ ÑÐ°Ð·Ð½Ð¾Ð³Ð¾ ÐºÐ¾Ð»Ð¸ÑÐµÑÑÐ²Ð° ÐºÐ¸ÑÐ»Ð¾ÑÐ¾Ð´Ð°/Ð²Ð¾Ð·Ð´ÑÑÐ° Ð±ÐµÐ· ÑÑÑÑÐ° Ð´Ð¸ÑÑÐ¾ÑÐ¸Ð°ÑÐ¸Ð¸. Ð Ð°Ð·ÑÐ°Ð±Ð¾ÑÐºÐ° ÑÐ¾Ð±ÑÑÐ²ÐµÐ½Ð½Ð¾Ð³Ð¾ ÐºÐ¾Ð´Ð°, Ð¾ÑÐ½Ð¾Ð²Ð°Ð½Ð½Ð¾Ð³Ð¾ Ð½Ð° Ð¼Ð¸Ð½Ð¸Ð¼Ð¸Ð·Ð°ÑÐ¸Ð¸ ÑÐ½ÐµÑÐ³Ð¸Ð¸ ÐÐ¸Ð±Ð±ÑÐ° ÑÐ¼ÐµÑÐ¸ Ð²ÐµÑÐµÑÑÐ², ÐºÐ¾Ð³Ð´Ð° Ð¿ÑÐ¾Ð´ÑÐºÑÐ°Ð¼Ð¸ Ð²Ð·Ð°Ð¸Ð¼Ð¾Ð´ÐµÐ¹ÑÑÐ²Ð¸Ñ ÑÑÐ¸ÑÑÐ¾ÑÐ¸Ð´Ð° Ð±Ð¾ÑÐ° Ð¸ Ð²Ð¾Ð´Ñ ÑÐ²Ð»ÑÑÑÑÑ Ð½Ð°Ð¸Ð±Ð¾Ð»ÐµÐµ ÑÐµÑÐ¼Ð¾ÑÑÐ°Ð±Ð¸Ð»ÑÐ½ÑÐµ Ð¾ÐºÑÐ¸Ð´ Ð±Ð¾ÑÐ°, ÑÑÐ¾ÑÐ¸Ð´ Ð±Ð¾ÑÐ°, ÑÑÐ¾ÑÐ¸Ð´ Ð²Ð¾Ð´Ð¾ÑÐ¾Ð´Ð° Ð¸ Ð²Ð¾Ð´Ð°. ÐÐµÑÐ¸ÑÐ¸ÐºÐ°ÑÐ¸Ñ ÑÐ°Ð·ÑÐ°Ð±Ð¾ÑÐ°Ð½Ð½Ð¾Ð³Ð¾ ÐºÐ¾Ð´Ð° Ð¿ÑÑÑÐ¼ ÑÑÐ°Ð²Ð½ÐµÐ½Ð¸Ñ Ð¿Ð¾Ð»ÑÑÐµÐ½Ð½ÑÑ ÑÐµÐ·ÑÐ»ÑÑÐ°ÑÐ¾Ð² Ñ ÑÐµÐ·ÑÐ»ÑÑÐ°ÑÐ°Ð¼Ð¸ ÑÐ°ÑÑÑÑÐ° ÑÐµÑÐ¼Ð¾Ð´Ð¸Ð½Ð°Ð¼Ð¸ÑÐµÑÐºÐ¸ ÑÐ°Ð²Ð½Ð¾Ð²ÐµÑÐ½ÑÑ ÑÐ¾ÑÑÐ°Ð²Ð¾Ð² Ð² ÑÐ¸ÑÑÐµÐ¼Ðµ ÑÐ»ÐµÐ¼ÐµÐ½ÑÐ¾Ð² B-F-O-H, Ð¿Ð¾Ð»ÑÑÐµÐ½Ð½ÑÑ Ñ Ð¿Ð¾Ð¼Ð¾ÑÑÑ ÐºÐ¾Ð¼Ð¼ÐµÑÑÐµÑÐºÐ¸Ñ ÐºÐ¾Ð´Ð¾Ð² ÐÑÑÑÐ°-4 Ð¸ CWB. Ð¡ Ð¿Ð¾Ð¼Ð¾ÑÑÑ Ð²ÑÑÐµÑÐ¿Ð¾Ð¼ÑÐ½ÑÑÑÑ Ð¿ÑÐ¾Ð³ÑÐ°Ð¼Ð¼Ð½ÑÑ Ð¿ÑÐ¾Ð´ÑÐºÑÐ¾Ð² ÑÐ°ÑÑÑÐ¸ÑÐ°ÑÑ ÑÐµÑÐ¼Ð¾Ð´Ð¸Ð½Ð°Ð¼Ð¸ÑÐµÑÐºÐ¸ ÑÐ°Ð²Ð½Ð¾Ð²ÐµÑÐ½ÑÐ¹ ÑÐ¾ÑÑÐ°Ð² Ð´Ð»Ñ ÑÐ¸ÑÑÐµÐ¼Ñ B-F-O-H-Ð¡-N, Ð° ÑÐ°ÐºÐ¶Ðµ Ð¾Ð¿ÑÐµÐ´ÐµÐ»Ð¸ÑÑ Ð½Ð°Ð¸Ð±Ð¾Ð»ÐµÐµ Ð²ÐµÑÐ¾ÑÑÐ½ÑÐµ Ðº Ð¿Ð¾Ð»ÑÑÐµÐ½Ð¸Ñ Ð±Ð¾ÑÐ¾ÑÐ¾Ð´ÐµÑÐ¶Ð°ÑÐ¸Ðµ Ð²ÐµÑÐµÑÑÐ²Ð°. ÐÐ»Ñ ÑÐµÑÐµÐ½Ð¸Ñ Ð¿Ð¾ÑÑÐ°Ð²Ð»ÐµÐ½Ð½ÑÑ Ð·Ð°Ð´Ð°Ñ Ð±ÑÐ» Ð¸ÑÐ¿Ð¾Ð»ÑÐ·Ð¾Ð²Ð°Ð½ Ð¼ÐµÑÐ¾Ð´ ÑÐµÑÐ¼Ð¾Ð´Ð¸Ð½Ð°Ð¼Ð¸Â­ÑÐµÑÐºÐ¾Ð³Ð¾ Ð¸ÑÑÐ»ÐµÐ´Ð¾Ð²Ð°Ð½Ð¸Ñ, Ð¾ÑÐ½Ð¾Ð²Ð°Ð½Ð½ÑÐ¹ Ð½Ð° Ð¼Ð¸Ð½Ð¸Ð¼Ð¸Ð·Ð°ÑÐ¸Ð¸ ÑÐ½ÐµÑÐ³Ð¸Ð¸ ÐÐ¸Ð±Ð±ÑÐ°. Ð ÑÐµÐ·ÑÐ»ÑÑÐ°ÑÐµ Ð±ÑÐ»Ð° Ð½Ð°Ð¿Ð¸ÑÐ°Ð½Ð° Ð¿ÑÐ¾Ð³ÑÐ°Ð¼Ð¼Ð° Ð´Ð»Ñ ÑÐµÐ°Ð»Ð¸Ð·Ð°ÑÐ¸Ð¸ Ð´Ð°Ð½Ð½Ð¾Ð³Ð¾ Ð¼ÐµÑÐ¾Ð´Ð°, ÐºÐ¾ÑÐ¾ÑÐ°Ñ Ð±ÑÐ»Ð° Ð²ÐµÑÐ¸ÑÐ¸ÑÐ¸ÑÐ¾Ð²Ð°Ð½Ð° Ñ Ð¿Ð¾Ð¼Ð¾ÑÑÑ Ð´Ð²ÑÑ ÐºÐ¾Ð¼Ð¼ÐµÑÑÐµÑÐºÐ¸Ñ Ð¿ÑÐ¾Ð³ÑÐ°Ð¼Ð¼Ð½ÑÑ Ð¿Ð°ÐºÐµÑÐ¾Ð² CWB Ð¸ ÐÐ¡Ð¢Ð Ð-4. Ð¢Ð°ÐºÐ¶Ðµ Ñ Ð¿Ð¾Ð¼Ð¾ÑÑÑ ÑÑÐ¸Ñ Ð¿Ð°ÐºÐµÑÐ¾Ð² Ð±ÑÐ» ÑÐ°ÑÑÑÐ¸ÑÐ°Ð½ ÑÐµÑÐ¼Ð¾Ð´Ð¸Ð½Ð°Ð¼Ð¸ÑÐµÑÐºÐ¸ ÑÐ°Ð²Ð½Ð¾Ð²ÐµÑÐ½ÑÐ¹ ÑÐ¾ÑÑÐ°Ð² Ð¿ÑÐ¾Ð´ÑÐºÑÐ¾Ð² Ð¾ÐºÐ¸ÑÐ»ÐµÐ½Ð¸Ñ ÑÐ¸ÑÑÐµÐ¼Ñ. ÐÐ° Ð¾ÑÐ½Ð¾Ð²Ð°Ð½Ð¸Ð¸ Ð¿ÑÐ¾Ð²ÐµÐ´ÐµÐ½Ð½ÑÑ ÑÐ°ÑÑÐµÑÐ¾Ð² Ð±ÑÐ» ÑÐ´ÐµÐ»Ð°Ð½ Ð²ÑÐ²Ð¾Ð´ Ð¾ Ð½ÐµÐ¾Ð±ÑÐ¾Ð´Ð¸Ð¼Ð¾ÑÑÐ¸ Ð¼Ð¾Ð´Ð¸ÑÐ¸ÐºÐ°ÑÐ¸Ð¸ ÑÐ°ÑÑÐ¼Ð°ÑÑÐ¸Ð²Ð°ÐµÐ¼Ð¾Ð¹ ÑÐµÑÐ½Ð¾Ð»Ð¾Ð³Ð¸Ð¸ Ð´Ð»Ñ ÑÐ²ÐµÐ»Ð¸ÑÐµÐ½Ð¸Ñ Ð²ÑÑÐ¾Ð´Ð° Ð¸ÑÐºÐ¾Ð¼ÑÑ Ð¿ÑÐ¾Ð´ÑÐºÑÐ¾Ð².
description: Theme of the final qualification work: "Research of the composition of products of interaction of boron trifluoride anisolate with oxygen in the combustion mode on the basis of thermodynamic calculations". This work is devoted to the study of one of the ways to separate the anisole-boron trifluoride system, as well as to determine the thermodynamically equilibrium composition of substances in the system of elements corresponding to the oxidation of this system. Tasks that were solved in the course of the study: Estimation of the value of the adiabatic temperature of anisole oxidation products for different amounts of oxygen/air without dissociation. Development of own code based on minimizing the Gibbs energy of a mixture of substances, when the products of the interaction of boron trifluoride and water are the most thermally stable boron oxide, boron fluoride, hydrogen fluoride and water.Verification of the developed code by comparing the obtained results with the results of calculating the thermodynamically equilibrium compositions in the system of B-F-O-H elements, obtained using commercial codes Astra-4 and CWB. Using the above software products, calculate the thermodynamically equilibrium composition for the B-F-O-H-C-N system, and also determine the most likely boron-containing substances to be obtained.To solve the tasks set, the method of thermodynamic research based on the minimization of the Gibbs energy was used. As a result, a program was written to implement this method, which was verified using two commercial software packages CWB and ASTRA-4. Also, using these packages, the thermodynamically equilibrium composition of the oxidation products of the system was calculated.Based on the calculations, it was concluded that it is necessary to modify the considered technology in order to increase the yield of the desired products.