title: Ð­ÐºÑÐ¿ÐµÑÐ¸Ð¼ÐµÐ½ÑÐ°Ð»ÑÐ½Ð¾Ðµ Ð¸ÑÑÐ»ÐµÐ´Ð¾Ð²Ð°Ð½Ð¸Ðµ Ð¸ ÑÐ¸ÑÐ»ÐµÐ½Ð½Ð¾Ðµ Ð¼Ð¾Ð´ÐµÐ»Ð¸ÑÐ¾Ð²Ð°Ð½Ð¸Ðµ ÑÐµÑÐ¼Ð¸ÑÐµÑÐºÐ¾Ð³Ð¾ ÑÐ°Ð·Ð»Ð¾Ð¶ÐµÐ½Ð¸Ñ Ð²ÑÑÐ¾ÐºÐ¾ÑÐ½ÐµÑÐ³ÐµÑÐ¸ÑÐµÑÐºÐ¾Ð³Ð¾ Ð¼Ð°ÑÐµÑÐ¸Ð°Ð»Ð°
title: Ð²ÑÐ¿ÑÑÐºÐ½Ð°Ñ ÐºÐ²Ð°Ð»Ð¸ÑÐ¸ÐºÐ°ÑÐ¸Ð¾Ð½Ð½Ð°Ñ ÑÐ°Ð±Ð¾ÑÐ° Ð¼Ð°Ð³Ð¸ÑÑÑÐ°
titleType: Subtitle
title: Experimental study and numerical simulation of thermal decomposition of high-energy material
Creators: name: Ð¡ÑÐ²Ð¾ÑÐ¾Ð², ÐÐ»ÐµÐºÑÐ°Ð½Ð´Ñ
Publisher: name: Ð¡Ð°Ð½ÐºÑ-ÐÐµÑÐµÑÐ±ÑÑÐ³ÑÐºÐ¸Ð¹ Ð¿Ð¾Ð»Ð¸ÑÐµÑÐ½Ð¸ÑÐµÑÐºÐ¸Ð¹ ÑÐ½Ð¸Ð²ÐµÑÑÐ¸ÑÐµÑ ÐÐµÑÑÐ° ÐÐµÐ»Ð¸ÐºÐ¾Ð³Ð¾
Year: 2019
Subjects: ÐÐ°Ð»Ð¾ÑÐ¸Ð¼ÐµÑÑÐ¸Ñ
ÐÐ·ÑÑÐ²ÑÐ°ÑÑÐµ Ð²ÐµÑÐµÑÑÐ²Ð°
Ð§Ð¸ÑÐ»ÐµÐ½Ð½ÑÐµ Ð¼ÐµÑÐ¾Ð´Ñ
Ð²ÑÑÐ¾ÐºÐ¾ÑÐ½ÐµÑÐ³ÐµÑÐ¸ÑÐµÑÐºÐ¸Ðµ Ð¼Ð°ÑÐµÑÐ¸Ð°Ð»Ñ
ÑÐµÑÐ¼Ð¸ÑÐµÑÐºÐ¾Ðµ ÑÐ°Ð·Ð»Ð¾Ð¶ÐµÐ½Ð¸Ðµ
ÑÐ¾ÑÐ¼Ð°Ð»ÑÐ½Ð¾-ÐºÐ¸Ð½ÐµÑÐ¸ÑÐµÑÐºÐ°Ñ Ð¼Ð¾Ð´ÐµÐ»Ñ
ÑÐµÑÐ¼Ð¸ÑÐµÑÐºÐ°Ñ ÑÑÐ°Ð±Ð¸Ð»ÑÐ½Ð¾ÑÑÑ

description: Ð¡Ð´ÐµÐ»Ð°Ð½ Ð¾Ð±Ð·Ð¾Ñ Ð»Ð¸ÑÐµÑÐ°ÑÑÑÑ Ð¿Ð¾ ÑÐµÐ¾ÑÐµÑÐ¸ÑÐµÑÐºÐ¸Ð¼ Ð¾ÑÐ½Ð¾Ð²Ð°Ð¼ ÑÐºÑÐ¿ÐµÑÐ¸Ð¼ÐµÐ½ÑÐ°Ð»ÑÐ½Ð¾Ð¹ ÐºÐ°Ð»Ð¾ÑÐ¸Ð¼ÐµÑÑÐ¸Ð¸ Ð¸ ÐºÐ¸Ð½ÐµÑÐ¸ÑÐµÑÐºÐ¾Ð³Ð¾ Ð°Ð½Ð°Ð»Ð¸Ð·Ð° Ð¸ Ð¼ÐµÑÐ¾Ð´Ð°Ð¼ Ð¿Ð¾ÑÑÑÐ¾ÐµÐ½Ð¸Ñ ÑÐ¾ÑÐ¼Ð°Ð»ÑÐ½Ð¾-ÐºÐ¸Ð½ÐµÑÐ¸ÑÐµÑÐºÐ¸Ñ Ð¼Ð¾Ð´ÐµÐ»ÐµÐ¹ ÑÐµÑÐ¼Ð¸ÑÐµÑÐºÐ¾Ð³Ð¾ ÑÐ°Ð·Ð»Ð¾Ð¶ÐµÐ½Ð¸Ñ ÐºÐ¾Ð½Ð´ÐµÐ½ÑÐ¸ÑÐ¾Ð²Ð°Ð½Ð½ÑÑ Ð²ÐµÑÐµÑÑÐ². ÐÑÐ¾Ð±Ð¾Ðµ Ð²Ð½Ð¸Ð¼Ð°Ð½Ð¸Ðµ ÑÐ´ÐµÐ»ÐµÐ½Ð¾ Ð²Ð»Ð¸ÑÐ½Ð¸Ñ Ð¾ÑÐ´ÐµÐ»ÑÐ½ÑÑ Ð¿ÑÐ¾ÑÐµÐ´ÑÑ Ð¿ÐµÑÐ²Ð¸ÑÐ½Ð¾Ð¹ Ð¾Ð±ÑÐ°Ð±Ð¾ÑÐºÐ¸ ÑÐºÑÐ¿ÐµÑÐ¸Ð¼ÐµÐ½ÑÐ°Ð»ÑÐ½ÑÑ Ð´Ð°Ð½Ð½ÑÑ (Ð´ÐµÐºÐ¾Ð½Ð²Ð¾Ð»ÑÑÐ¸Ñ, Ð²ÑÑÐ¸ÑÐ°Ð½Ð¸Ðµ Ð±Ð°Ð·Ð¾Ð²Ð¾Ð¹ Ð»Ð¸Ð½Ð¸Ð¸) Ð½Ð° ÐºÐ¸Ð½ÐµÑÐ¸ÑÐµÑÐºÑÑ Ð¼Ð¾Ð´ÐµÐ»Ñ ÑÐµÑÐ¼Ð¸ÑÐµÑÐºÐ¾Ð³Ð¾ ÑÐ°Ð·Ð»Ð¾Ð¶ÐµÐ½Ð¸Ñ. ÐÐ·ÑÑÐµÐ½ Ð¿ÑÐ¸Ð½ÑÐ¸Ð¿ Ð¼ÐµÑÐ¾Ð´Ð° Ð´Ð¸ÑÑÐµÑÐµÐ½ÑÐ¸Ð°Ð»ÑÐ½Ð¾Ð¹ ÑÐºÐ°Ð½Ð¸ÑÑÑÑÐµÐ¹ ÐºÐ°Ð»Ð¾ÑÐ¸Ð¼ÐµÑÑÐ¸Ð¸ Ð¸ ÑÑÑÑÐ¾Ð¹ÑÑÐ²Ð¾ ÑÐµÐ°Ð»Ð¸Ð·ÑÑÑÐµÐ¹ ÐµÐ³Ð¾ ÑÑÑÐ°Ð½Ð¾Ð²ÐºÐ¸ (ÐºÐ°Ð»Ð¾ÑÐ¸Ð¼ÐµÑÑ TG-DSC-111 Setaram). ÐÑÐ¾Ð²ÐµÐ´ÐµÐ½Ð¾ Ð¸ÑÑÐ»ÐµÐ´Ð¾Ð²Ð°Ð½Ð¸Ðµ ÑÐµÑÐ¼Ð¸ÑÐµÑÐºÐ¾Ð³Ð¾ ÑÐ°Ð·Ð»Ð¾Ð¶ÐµÐ½Ð¸Ñ Ð¾Ð±ÑÐ°Ð·ÑÐ¾Ð² Ð²ÑÑÐ¾ÐºÐ¾-ÑÐ½ÐµÑÐ³ÐµÑÐ¸ÑÐµÑÐºÐ¾Ð³Ð¾ Ð¼Ð°ÑÐµÑÐ¸Ð°Ð»Ð° Â«ÐÑÐ¾Ð½Ð¸ÑÂ» (ÑÐ¼ÐµÑÑ Ð¾ÑÐ³Ð°Ð½Ð¸ÑÐµÑÐºÐ¸Ñ Ð²ÐµÑÐµÑÑÐ² Ð½Ð° Ð¾ÑÐ½Ð¾Ð²Ðµ Ð´Ð¸Ð½Ð¸ÑÑÐ°ÑÐ° Ð¿ÑÐ¾Ð¿Ð¸Ð»ÐµÐ½Ð³Ð»Ð¸ÐºÐ¾Ð»Ñ) Ð¿ÑÐ¸ 3-Ñ ÑÐºÐ¾ÑÐ¾ÑÑÑÑ Ð½Ð°Ð³ÑÐµÐ²Ð°. ÐÑÐ±Ð¾Ñ Ð´Ð°Ð½Ð½Ð¾Ð³Ð¾ Ð¼Ð°ÑÐµÑÐ¸Ð°Ð»Ð° Ð¾Ð±ÑÑÐ»Ð¾Ð²Ð»ÐµÐ½ Ð¾Ð¿Ð°ÑÐ½Ð¾ÑÑÑÑ ÑÐ°Ð·Ð²Ð¸ÑÐ¸Ñ ÑÐµÐ¿Ð»Ð¾Ð²Ð¾Ð³Ð¾ Ð²Ð·ÑÑÐ²Ð° Ð² ÑÐµÐ·ÑÐ»ÑÑÐ°ÑÐµ Ð±ÑÑÑÑÐ¾Ð³Ð¾ ÑÐºÐ·Ð¾ÑÐµÑÐ¼Ð¸ÑÐµÑÐºÐ¾Ð³Ð¾ ÑÐ°Ð·Ð»Ð¾Ð¶ÐµÐ½Ð¸Ñ. Ð Ð´Ð°Ð½Ð½Ð¾Ð¹ ÑÐ°Ð±Ð¾ÑÐµ Ð²Ð¿ÐµÑÐ²ÑÐµ Ð²ÑÐ¿Ð¾Ð»Ð½ÐµÐ½ ÐºÐ¾Ð¼Ð¿Ð»ÐµÐºÑÐ½ÑÐ¹ Ð°Ð½Ð°Ð»Ð¸Ð· Ð²Ð»Ð¸ÑÐ½Ð¸Ñ ÑÐ°Ð·Ð»Ð¸ÑÐ½ÑÑ Ð¿ÑÐ¾ÑÐµÐ´ÑÑ Ð¿ÐµÑÐ²Ð¸ÑÐ½Ð¾Ð¹ Ð¾Ð±ÑÐ°Ð±Ð¾ÑÐºÐ¸ ÐºÐ°Ð»Ð¾ÑÐ¸Ð¼ÐµÑÑÐ¸ÑÐµÑÐºÐ¸Ñ Ð´Ð°Ð½Ð½ÑÑ (Ñ. Ðµ. Ð°Ð½Ð°Ð»Ð¸Ð· Ð¾Ð´Ð½Ð¾Ð²ÑÐµÐ¼ÐµÐ½Ð½Ð¾Ð³Ð¾ ÑÑÐµÑÐ° Ð¿ÑÐ¾ÑÐµÐ´ÑÑ Ð²Ð¾ÑÑÑÐ°Ð½Ð¾Ð²Ð»ÐµÐ½Ð¸Ñ ÑÐµÐ¼Ð¿ÐµÑÐ°ÑÑÑÐ½Ð¾Ð³Ð¾ Ð¾ÑÐºÐ»Ð¸ÐºÐ° Ð¸ Ð´ÐµÐºÐ¾Ð½Ð²Ð¾Ð»ÑÑÐ¸Ð¸) Ð½Ð° ÐºÐ¸Ð½ÐµÑÐ¸ÑÐµÑÐºÑÑ Ð¼Ð¾Ð´ÐµÐ»Ñ ÑÐ°Ð·Ð»Ð¾Ð¶ÐµÐ½Ð¸Ñ Ð¼Ð°ÑÐµÑÐ¸Ð°Ð»Ð° Â«ÐÑÐ¾Ð½Ð¸ÑÂ» Ð¸ Ð½Ð° Ð¿ÑÐ¾Ð³Ð½Ð¾Ð· ÑÐµÑÐ¼Ð¸ÑÐµÑÐºÐ¾Ð¹ Ð¾Ð¿Ð°ÑÐ½Ð¾ÑÑÐ¸ Ð´Ð°Ð½Ð½Ð¾Ð³Ð¾ Ð¼Ð°ÑÐµÑÐ¸Ð°Ð»Ð°.
description: A review of the literature on the theoretical foundations of experimental calorimetry and kinetic analysis and methods for constructing formal-kinetic models of thermal decomposition of condensed substances has been made. Particular attention is paid to the effect of individual procedures for the initial processing of experimental data (deconvolution, subtraction of the baseline) on the kinetic model of thermal decomposition. The principle of the method of differential scanning calorimetry and the device for realizing its installation (calorimeter TG-DSC-111 Setaram) have been studied. The study of thermal decomposition of samples of the high-energy material âPronitâ (a mixture of organic substances based on propylene glycol dinitrate) was carried out at 3 heating rates. The choice of this material due to the risk of thermal explosion as a result of rapid exothermic decomposition. In this paper, for the first time, a comprehensive analysis of the effect of various procedures for the primary processing of calorimetric data (ie, an analysis of simultaneous consideration of the procedures for recovering temperature response and deconvolution) on the kinetic model of decomposition of the material âPronitâ and on the prediction of the thermal hazard of this material was performed.