title: ÐÐ°ÑÑ-ÑÐ¿ÐµÐºÑÑÐ¾Ð¼ÐµÑÑÐ¸ÑÐµÑÐºÐ¸Ð¹ Ð¸ ÑÐµÑÐ¼Ð¾Ð´Ð¸Ð½Ð°Ð¼Ð¸ÑÐµÑÐºÐ¸Ð¹ Ð°Ð½Ð°Ð»Ð¸Ð· Ð²Ð·Ð°Ð¸Ð¼Ð¾Ð´ÐµÐ¹ÑÑÐ²Ð¸Ñ Ð¸Ð¾Ð½Ð¾Ð² ÐºÐ¸Ð»Ð¾ÑÐ»ÐµÐºÑÑÐ¾Ð½Ð²Ð¾Ð»ÑÑÐ½ÑÑ ÑÐ½ÐµÑÐ³Ð¸Ð¹ Ñ Ð¾Ð»Ð¸Ð³Ð¾Ð¿ÐµÐ¿ÑÐ¸Ð´Ð°Ð¼Ð¸
title: Ð²ÑÐ¿ÑÑÐºÐ½Ð°Ñ ÐºÐ²Ð°Ð»Ð¸ÑÐ¸ÐºÐ°ÑÐ¸Ð¾Ð½Ð½Ð°Ñ ÑÐ°Ð±Ð¾ÑÐ° Ð±Ð°ÐºÐ°Ð»Ð°Ð²ÑÐ°
titleType: Subtitle
title: Time-of-flight analysis of the charge and mass composition and thermodynamic analysis of the interaction between oligopeptides and kev-energy ions
Creators: name: ÐÑÐ·ÑÐºÐ¸Ð½, ÐÐ½Ð´ÑÐµÐ¹
Publisher: name: Ð¡Ð°Ð½ÐºÑ-ÐÐµÑÐµÑÐ±ÑÑÐ³ÑÐºÐ¸Ð¹ Ð¿Ð¾Ð»Ð¸ÑÐµÑÐ½Ð¸ÑÐµÑÐºÐ¸Ð¹ ÑÐ½Ð¸Ð²ÐµÑÑÐ¸ÑÐµÑ ÐÐµÑÑÐ° ÐÐµÐ»Ð¸ÐºÐ¾Ð³Ð¾
Year: 2024
Subjects: Ð·Ð°Ñ Ð²Ð°Ñ ÑÐ»ÐµÐºÑÑÐ¾Ð½Ð¾Ð²
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ÑÑÐ°Ð³Ð¼ÐµÐ½ÑÐ°ÑÐ¸Ñ
Ð²ÑÐµÐ¼ÑÐ¿ÑÐ¾Ð»ÐµÑÐ½Ð°Ñ Ð¼Ð°ÑÑ-ÑÐ¿ÐµÐºÑÑÐ¾Ð¼ÐµÑÑÐ¸Ñ
Ð¸Ð·Ð¾Ð»Ð¸ÑÐ¾Ð²Ð°Ð½Ð½ÑÐµ Ð¼Ð¾Ð»ÐµÐºÑÐ»Ñ
time-of-flight mass-spectrometry
peptides
isolated molecules
fragmentation
electron capture

description: ÐÐ°Ð½Ð½Ð°Ñ ÑÐ°Ð±Ð¾ÑÐ° ÑÑÐ°Ð²Ð¸Ñ ÑÐ²Ð¾ÐµÐ¹ ÑÐµÐ»ÑÑ Ð¸ÑÑÐ»ÐµÐ´Ð¾Ð²Ð°Ð½Ð¸Ðµ ÑÐ°ÑÐ°ÐºÑÐµÑÐ° Ð²Ð·Ð°Ð¸Ð¼Ð¾Ð´ÐµÐ¹ÑÑÐ²Ð¸Ñ Ð³Ð»Ð¸ÑÐ¸Ð»-Ð»ÐµÐ¹ÑÐ¸Ð½Ð°, ÑÐ¸ÐºÐ»Ð¾Ð´Ð¸Ð³Ð»Ð¸ÑÐ¸Ð½Ð° Ð¸ Ð³Ð»Ð¸ÑÐ¸Ð»-Ð³Ð»Ð¸ÑÐ¸Ð½Ð° Ñ ÑÐ°Ð´Ð¸Ð°ÑÐ¸ÐµÐ¹ Ð½Ð°Ð»ÐµÑÐ°ÑÑÐµÐ³Ð¾ Ð¿Ð¾ÑÐ¾ÐºÐ° Ð°Ð»ÑÑÐ°-ÑÐ°ÑÑÐ¸Ñ, Ð¿Ð¾Ð»ÑÑÐµÐ½Ð¸Ðµ Ð¸ Ð¸Ð½ÑÐµÑÐ¿ÑÐµÑÐ°ÑÐ¸Ñ ÐºÐ°ÑÐµÑÑÐ²ÐµÐ½Ð½ÑÑ Ð¸ ÐºÐ¾Ð»Ð¸ÑÐµÑÑÐ²ÐµÐ½Ð½ÑÑ ÑÐ°ÑÐ°ÐºÑÐµÑÐ¸ÑÑÐ¸Ðº ÑÐ°ÑÐ¿Ð°Ð´Ð°, ÑÐµÑÐ¼Ð¾Ð´Ð¸Ð½Ð°Ð¼Ð¸ÑÐµÑÐºÐ¸Ñ ÑÐ°ÑÐ°ÐºÑÐµÑÐ¸ÑÑÐ¸Ðº. Ð ÑÐ°ÑÑÐ½Ð¾ÑÑÐ¸, Ð¿ÐµÑÐ²Ð°Ñ ÑÐ°ÑÑÑ ÑÐ°Ð±Ð¾ÑÑ ÑÐ°ÑÑÐ¼Ð°ÑÑÐ¸Ð²Ð°ÐµÑ Ð¾Ð¿ÑÑ Ð¸ÑÑÐ»ÐµÐ´Ð¾Ð²Ð°Ð½Ð¸Ð¹, Ð¿ÑÐ¾Ð²ÐµÐ´ÑÐ½Ð½ÑÑ Ð½Ð°Ð´ ÑÐºÐ°Ð·Ð°Ð½Ð½Ð¾Ð¹ Ð³ÑÑÐ¿Ð¿Ð¾Ð¹ Ð²ÐµÑÐµÑÑÐ², ÑÑÐ°Ð²Ñ ÑÐ²Ð¾ÐµÐ¹ Ð·Ð°Ð´Ð°ÑÐµÐ¹ Ð¾Ð±Ð·Ð¾Ñ Ð¿Ð¾ ÑÐµÐ¼Ðµ Ð¸ÑÑÐ»ÐµÐ´Ð¾Ð²Ð°Ð½Ð¸Ñ. ÐÐ¾ Ð²ÑÐ¾ÑÐ¾Ð¹ ÑÐ°ÑÑÐ¸ Ð¾Ð¿Ð¸ÑÑÐ²Ð°ÐµÑÑÑ ÑÐºÑÐ¿ÐµÑÐ¸Ð¼ÐµÐ½ÑÐ°Ð»ÑÐ½Ð°Ñ ÑÐµÑÐ½Ð¸ÐºÐ°, Ð¾Ð±ÑÑÐ¶Ð´Ð°ÐµÑÑÑ Ð¿ÑÐ¸Ð¼ÐµÐ½ÐµÐ½Ð¸Ðµ ÑÐ°ÐºÐ¾Ð²Ð¾Ð¹ Ðº ÑÐºÐ°Ð·Ð°Ð½Ð½Ð¾Ð¹ Ð³ÑÑÐ¿Ð¿Ðµ Ð²ÐµÑÐµÑÑÐ². Ð¢ÑÐµÑÑÑ ÑÐ°ÑÑÑ ÑÐ°Ð±Ð¾ÑÑ ÑÐµÑÐ°ÐµÑ Ð·Ð°Ð´Ð°ÑÐ¸ Ð¿Ð¾Ð»ÑÑÐµÐ½Ð¸Ñ Ð¸ Ð¸Ð½ÑÐµÑÐ¿ÑÐµÑÐ°ÑÐ¸Ð¸ ÐºÐ°ÑÐµÑÑÐ²ÐµÐ½Ð½ÑÑ Ð¸ ÐºÐ¾Ð»Ð¸ÑÐµÑÑÐ²ÐµÐ½Ð½ÑÑ ÑÐ°ÑÐ°ÐºÑÐµÑÐ¸ÑÑÐ¸Ðº Ð¼Ð°ÑÑ-ÑÐ¿ÐµÐºÑÑÐ¾Ð¼ÐµÑÑÐ¸ÑÐµÑÐºÐ¾Ð³Ð¾ Ð¸ÑÑÐ»ÐµÐ´Ð¾Ð²Ð°Ð½Ð¸Ñ Ð³ÑÑÐ¿Ð¿Ñ Ð²ÐµÑÐµÑÑÐ², Ð² ÑÐ°ÑÑÐ½Ð¾ÑÑÐ¸, ÑÐµÑÐ¼Ð¾Ð´Ð¸Ð½Ð°Ð¼Ð¸ÑÐµÑÐºÐ¸Ñ â ÑÐµÐ¼Ð¿ÐµÑÐ°ÑÑÑÑ Ð¸ ÑÐ½ÑÐ°Ð»ÑÐ¿Ð¸Ð¸ ÑÑÐ±Ð»Ð¸Ð¼Ð°ÑÐ¸Ð¸, Ð¸ Ð½ÐµÐ¿Ð¾ÑÑÐµÐ´ÑÑÐ²ÐµÐ½Ð½Ð¾ ÑÐ²ÑÐ·Ð°Ð½Ð½ÑÑ Ñ ÑÐ°ÑÐ°ÐºÑÐµÑÐ¾Ð¼ ÑÐ°Ð´Ð¸Ð°ÑÐ¸Ð¾Ð½Ð½ÑÑ Ð¿Ð¾Ð²ÑÐµÐ¶Ð´ÐµÐ½Ð¸Ð¹ Ð¼Ð°ÑÑ-ÑÐ¿ÐµÐºÑÑÐ°Ð¼Ð¸ Ð¸ ÑÐµÑÐµÐ½Ð¸ÑÐ¼Ð¸ Ð¿ÑÐ¾ÑÐµÑÑÐ°, Ð¾Ð¿Ð¸ÑÑÐ²Ð°ÑÑÐ¸Ð¼Ð¸ ÑÑÐ°Ð³Ð¼ÐµÐ½ÑÐ°ÑÐ¸Ñ Ð¼Ð¾Ð»ÐµÐºÑÐ». Ð ÐµÐ·ÑÐ»ÑÑÐ°ÑÐ¾Ð¼ ÑÐ°Ð±Ð¾ÑÑ ÑÐ²Ð»ÑÐµÑÑÑ Ð½Ð°Ð±Ð¾Ñ ÑÐºÑÐ¿ÐµÑÐ¸Ð¼ÐµÐ½ÑÐ°Ð»ÑÐ½Ð¾ Ð¿Ð¾Ð»ÑÑÐµÐ½Ð½ÑÑ Ð´Ð°Ð½Ð½ÑÑ Ð¸ ÑÑÐ´ Ð·Ð½Ð°ÑÐµÐ½Ð¸Ð¹, Ð¸Ð¼ÐµÑÑÐ¸Ð¹ Ð²ÑÑÐ¾ÐºÐ¸Ð¹ Ð¿Ð¾ÑÐµÐ½ÑÐ¸Ð°Ð» Ð´Ð»Ñ Ð´Ð°Ð»ÑÐ½ÐµÐ¹ÑÐµÐ³Ð¾ ÑÐ°Ð·Ð²Ð¸ÑÐ¸Ñ ÑÐºÑÐ¿ÐµÑÐ¸Ð¼ÐµÐ½ÑÐ°Ð»ÑÐ½ÑÑ ÑÐµÑÐ½Ð¸Ðº Ð¸ ÐºÐ²Ð°Ð½ÑÐ¾Ð²Ð¾-ÑÐ¸Ð¼Ð¸ÑÐµÑÐºÐ¾Ð³Ð¾ Ð°Ð½Ð°Ð»Ð¸Ð·Ð°.
description: This thesis aims to investigate the nature of the interaction between glycyl-leucine, cyclodiglycine, and glycyl-glycine with the radiation from an incoming beam of alpha particles, as well as to obtain and interpret qualitative and quantitative characteristics of their decomposition and thermodynamic properties. Specifically, the first part of the work reviews previous studies conducted on the specified group of substances, providing an overview of the research topic. The second part describes the experimental techniques used and discusses their application to the mentioned molecules. The third part addresses the tasks of obtaining and interpreting qualitative and quantitative characteristics from mass-spectrometra analysis of the substances and the thermodynamic properties such as sublimation temperature and enthalpy. It also examines the mass spectra and cross-sections associated with radiation damage and molecular fragmentation. The main goals of this work include a set of experimentally obtained data and a series of values that have significant potential for further development of experimental techniques and quantum chemical analysis.