Anne Njemanze ta kasan ce yar fim din wasan kwaikwayo ce a Najeriya. Ita ce mshaharaaa fannin rar rawcikiniwar fim rawa na ɗin Domitila, Tinsel, Ìrètí da Launi. Ta auri wani dan fim din Nollywood Segun Arinze, wanda daga baya ya zama auren gajeruwa.Ma'auratan suna da 'ya ɗaya, Renny Morenike, wanda aka haifa a ranar 10 Mayu. A watan Nuwamba 2013, ta sake yin aure da Silver Ojieson. Koyaya, shima bai wuce watanni takwas ba har zuwa Yulin 2014 saboda fama da tashe tashen hankula na cikin gida, zagi da batir. Jim kadan bayan rabuwa da auren farko, ta hadu da wani hadari a Calabar, Jihar Kuros Riba. Sakamakon hatsarin, 'yar asalin jihar Imo Owerri ta lalace matuka yayin da Njemanze ta kasance cikin kangi na tsawon shekaru 2. A cikin 1995 ta fara wasan kwaikwayo tare da fim din gida Rattle Snake . Daga baya ta zama shahararriyar 'yar fim tare da shahararrun fina-finan gida Domitilla da Domitilla II tare da matsakaicin matsayi. Daga baya ta yi fim a cikin Furucin Gaskiya inda tare da Liz Benson.