请解答下面的单项选择题，并简要分析 A、B、C、D 四个选项。
题目：室温下，向 {100 mL 0.1 mol/L NH_{4}Cl} 溶液中加入下列物质。有关结论正确的是
| | | |
| --- | --- | --- |
| 加入的物质 结论 | | |
| {A} {100 mL 0.1 mol/L} 盐酸 溶液中 {2c} {(NH_{4}^{+})= c(Cl^{-})} | | |
| {B} {0.01 mol Na_{2}O_{2}} 固体 反应完全后，溶液 {pH} 增大， {c(Na^{+}) =} {2c} {(Cl^{-})} | | |
| {C} {100 mL H_{2}O} 由水电离出的 {c(H^{+})⋅c(OH^{-})} 不变 | | |
| {D} {100 mL 0.1 mol/L NH_{3}⋅H_{2}O} 溶液中 { {c(O{H}^{-})}{c({H}^{+})} } 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| | |
A. {A}
B. {B}
C. {C}
D. {D}

A. {100mL0.1mol/L} 盐酸，由于铵根离子部分水解，则 {2c(NH_{4}^{+}) < c(Cl^{−})}，故A错误；
B.钠离子和氯离子不发生水解， {0.01molNa_{2}O_{2}} 固体反应后生成 {0.02mol} 钠离子，原溶液中含有氯离子的物质的量为： {0.1mol/L×0.1L=0.01mol}，则 {c(Na^{+})=2c(Cl^{−})}；且反应后氢氧化钠过量，溶液呈碱性，溶液的 {pH} 增大，故B正确；
C.加入 {100mLH_{2}O} 后，溶液浓度减小，铵根离子的水解程度增大，则水的电离程度最大，故水电离出的 {c(H^{+})⋅c(OH^{−})} 的乘积会增大，故C错误；
D.加入 {100mL0.1mol/LNH_{3} H_{2}O}，溶液碱性最强，则氢氧根离子浓度增大、氢离子浓度减小，溶液中 {c(OH^{−})/c(H^{+})} 增大，故D错误。
最终答案：B