bluuebunny/crossref_metadata_2025_split huggingface dataset:
Realizing Quantum Technologies in Nanomaterials and Nanoscience
Authors: Iyengar Sathvik Ajay , Puthirath Anand B. , Swaminathan Venkataraman 
Published: February 2022

AbstractA brief overview of quantum materials and their prospects for applications, in the near, mid, and far‐term in the areas of quantum information science, spintronics, valleytronics, and twistronics and those involving topology are covered in this perspective. The material and processing challenges that will modulate the realism of the applications will be discussed as well.
Recent Advances of Aqueous Rechargeable Zinc‐Iodine Batteries: Challenges, Solutions, and Prospects
Authors: Lin Dun , Li Yat 
Published: February 2022

AbstractAqueous rechargeable zinc‐iodine batteries (ZIBs), including zinc‐iodine redox flow batteries and static ZIBs, are promising candidates for future grid‐scale electrochemical energy storage. They are safe with great theoretical capacity, high energy, and power density. Nevertheless, to make aqueous rechargeable ZIBs practically feasible, there are quite a few hurdles that need to be overcome, including self‐discharge, sluggish kinetics, low energy density, and instability of Zn metal anodes. This article first reviews the electrochemistry in aqueous rechargeable ZIBs, including the flow and static battery configurations and their electrode reactions. Then the authors discuss the fundamental questions of ZIBs and highlight the key strategies and recent accomplishments in tackling the challenges. Last, they share their thoughts on the future research development in aqueous rechargeable ZIBs.
Melamine Foam with pH‐Responsive Wettability for Fast Oil Absorption and Desorption
Authors: Ma Junjun , Xie Yangchun , Yang Tao , He Xiaohua 
Published: February 2022

AbstractInnovative 3D materials with the switchable wetting surface attract significant attention due to their application in oil/water separation. Herein, a fast pH‐responsive and highly effective melamine foam (MF) grafted with poly (2‐dimethylaminoethyl methacrylate) is prepared by surface‐initiated chain transfer radical polymerization. The as‐prepared MF displays superhydrophilic and superoleophobic surface in strong acid solution while it becomes superhydrophobic in neutral or basic solution. Therefore, it can be rapid to selectively absorb different types of oils from the oil–water mixture with a great absorption capacity of 54–117 g g−1 and automatically desorb oil in less than 60 s with a desorption efficiency of 99% (dichloromethane) in acid solution. Moreover, the as‐prepared MF possesses excellent recyclability, and the absorption capacity and the desorption efficiency are almost unchanged after 15 cycles. The pH‐sensitive MF with switchable wetting surfaces has great potential for the oily water separation.
Electrochemical Thin Film Deposition of Copper(I) Halides in Aqueous Solution: Substrate Extension and Structure Transformation
Authors: Xu Si‐Yu , Wu Ya‐Nan , Chen Bi‐Cui , Huang Pei‐Wen , Zhang Zhi‐Zhuan , Zhong Yu , Zhao Yi , Huang Xiao‐Ying , Du Ke‐Zhao 
Published: February 2022

AbstractIn this paper, a green and simple electrochemical method is developed that can directly deposit thin films of [CuX(pyz)]n and [Cu2X2(pyz)]n (X = Cl, Br, I; pyz = pyrazine) in aqueous solution. This method can overcome the thermodynamical instability of Cu(I) and the poor solubility of hybrid organic–copper(I) halides. By heating in different atmospheres, the single‐crystal transformation between [CuX(pyz)]n and [Cu2X2(pyz)]n can be realized with luminescent switching, which is used for information encryption and encoding. More importantly, the corresponding thin film can be deposited on various substrates leading to flexible light‐emitting and photoelectric devices.
Cdyl Deficiency Brakes Neuronal Excitability and Nociception through Promoting Kcnb1 Transcription in Peripheral Sensory Neurons
Authors: Sun Zhao‐Wei , Waybright Jarod M. , Beldar Serap , Chen Lu , Foley Caroline A. , Norris‐Drouin Jacqueline L. , Lyu Tian‐Jie , Dong Aiping , Min Jinrong , Wang Yu‐Pu , James Lindsey I. , Wang Yun 
Published: February 2022

AbstractEpigenetic modifications are involved in the onset, development, and maintenance of pain; however, the precise epigenetic mechanism underlying pain regulation remains elusive. Here it is reported that the epigenetic factor chromodomain Y‐like (CDYL) is crucial for pain processing. Selective knockout of CDYL in sensory neurons results in decreased neuronal excitability and nociception. Moreover, CDYL facilitates histone 3 lysine 27 trimethylation (H3K27me3) deposition at the Kcnb1 intron region thus silencing voltage‐gated potassium channel (Kv) subfamily member Kv2.1 transcription. Loss function of CDYL enhances total Kv and Kv2.1 current density in dorsal root ganglia and knockdown of Kv2.1 reverses the pain‐related phenotypes of Cdyl deficiency mice. Furthermore, focal administration of a novel potent CDYL antagonist blunts nociception and attenuates neuropathic pain. These findings reveal that CDYL is a critical regulator of pain sensation and shed light on the development of novel analgesics targeting epigenetic mechanisms.
Metal–Organic Polyhedra as Building Blocks for Porous Extended Networks
Authors: Khobotov‐Bakishev Akim , Hernández‐López Laura , von Baeckmann Cornelia , Albalad Jorge , Carné‐Sánchez Arnau , Maspoch Daniel 
Published: February 2022

AbstractMetal–organic polyhedra (MOPs) are a subclass of coordination cages that can adsorb and host species in solution and are permanently porous in solid‐state. These characteristics, together with the recent development of their orthogonal surface chemistry and the assembly of more stable cages, have awakened the latent potential of MOPs to be used as building blocks for the synthesis of extended porous networks. This review article focuses on exploring the key developments that make the extension of MOPs possible, highlighting the most remarkable examples of MOP‐based soft materials and crystalline extended frameworks. Finally, the article ventures to offer future perspectives on the exploitation of MOPs in fields that still remain ripe toward the use of such unorthodox molecular porous platforms.
Looking beyond history: tracing the dispersal of the Malaysian complex of crops to Africa
Authors: Grimaldi Ilaria M. , Van Andel Tinde R. , Denham Tim P. 
Published: February 2022

AbstractIn his 1959 book, Africa: Its Peoples and Their Culture History, George P. Murdock suggested that a Malaysian complex of crops dispersed to Africa in ancient times across the Indian Ocean along the Sabaean Lane. The Malaysian complex comprised bananas, sugarcane, taro, three yam species, rice, Polynesian arrowroot, breadfruit, coconut, areca palm, and betel leaf. Except for rice, arrowroot, and potentially taro, most of these crops were domesticated in the Island Southeast Asia‐New Guinea region, from where they dispersed to Africa. Our reassessment of agronomic, archaeological, classical, genetic, and historical sources shows that we need to go beneath standard historical narratives to recover a much more ancient and complex history of crop introductions to Africa. Despite considerable uncertainty and fragmented research, we were able to conclude that the Malaysian complex of crops did not arrive in Africa as a complete assemblage at one time or along one route. Multiple lines of evidence suggest that these crops arrived in Africa at different times and followed different pathways of introduction to the continent.
Phosphorogenic Iridium(III) bis‐Tetrazine Complexes for Bioorthogonal Peptide Stapling, Bioimaging, Photocytotoxic Applications, and the Construction of Nanosized Hydrogels
Authors: Yip Alex Man‐Hei , Lai Calvin Kin‐Ho , Yiu Ken Shek‐Man , Lo Kenneth Kam‐Wing 
Published: February 2022

AbstractThe dual functionality of 1,2,4,5‐tetrazine as a bioorthogonal reactive unit and a luminescence quencher has shaped tetrazine‐based probes as attractive candidates for luminogenic labeling of biomolecules in living systems. In this work, three cyclometalated iridium(III) complexes featuring two tetrazine units were synthesized and characterized. Upon photoexcitation, the complexes were non‐emissive but displayed up to 3900‐fold emission enhancement upon the inverse electron‐demand Diels–Alder (IEDDA) [4+2] cycloaddition with (1R,8S,9s)‐bicyclo[6.1.0]non‐4‐yne (BCN) substrates. The rapid reaction kinetics (k2 up to 1.47×104 M−1 s−1) of the complexes toward BCN substrates allowed effective peptide labeling. The complexes were also applied as live cell bioimaging reagents and photocytotoxic agents. One of the complexes was utilized in the preparation of luminescent nanosized hydrogels that exhibited interesting cargo delivery properties.
Tuning the High‐Pressure Phase Behaviour of Highly Compressible Zeolitic Imidazolate Frameworks: From Discontinuous to Continuous Pore Closure by Linker Substitution
Authors: Song Jianbo , Pallach Roman , Frentzel‐Beyme Louis , Kolodzeiski Pascal , Kieslich Gregor , Vervoorts Pia , Hobday Claire L. , Henke Sebastian 
Published: February 2022

AbstractThe high‐pressure behaviour of flexible zeolitic imidazolate frameworks (ZIFs) of the ZIF‐62 family with the chemical composition M(im)2−x(bim)xis presented (M2+=Zn2+, Co2+; im−=imidazolate; bim−=benzimidazolate, 0.02≤x≤0.37). High‐pressure powder X‐ray diffraction shows that the materials contract reversibly from an open pore (op) to a closed pore (cp) phase under a hydrostatic pressure of up to 4000 bar. Sequentially increasing the bim−fraction (x) reinforces the framework, leading to an increased threshold pressure for theop‐to‐cpphase transition, while the total volume contraction across the transition decreases. Most importantly, the typical discontinuousop‐to‐cptransition (first order) changes to an unusual continuous transition (second order) forx≥0.35. This allows finetuning of the void volume and the pore size of the material continuously by adjusting the pressure, thus opening new possibilities for MOFs in pressure‐switchable devices, membranes, and actuators.
Advancing the circular economy through dynamic capabilities and extended customer engagement: Insights from small sustainable fashion enterprises in the UK
Authors: Elf Patrick , Werner Andrea , Black Sandy 
Published: February 2022

AbstractThe circular economy holds the potential to significantly reduce resource use. However, attempts to fully utilize its potential have fallen short so far. Based on a longitudinal interview‐based study, we examine how micro, small and medium enterprises (MSMEs) in the UK fashion industry advance the circular economy (CE). Whereas the dynamic capabilities framework is mostly used for medium and large businesses, our findings advance the current literature, demonstrating how the distinctive development and use of dynamic capabilities enable MSMEs to act in agile ways, allowing them to introduce, test and advance CE solutions, while providing them with more resilience during times of crises. Our study further shows that fashion MSMEs adopt circular economy business models (CEBMs) by going beyond conventional, technology‐focused approaches currently dominating business thinking. The research highlights MSMEs' ability to engage in circular practices through an extension of existing business models in the form of close interactions with their customers demonstrating the importance and potential of extended business‐customer engagement in businesses' attempts to adopt CE practices.
Hemodynamic variation is a dominant contributing factor of Graves' hyperthyroidism complication: Heart failure and fatal liver dysfunction, a case report and analysis
Authors: Li Zhiyuan , Wang Jinjing , Zeng Jing , Xue Jian , Li Xinyu , Su Jianbing , Fang Yi 
Published: February 2022

AbstractTachycardia and atrial fibrillation, early symptoms of hyperthyroidism indicate significant hemodynamic variation in cardiovascular system, if left untreated and further deterioration in hemodynamics can result in chronic heart failure and liver dysfunction even a fatal event. We describe a female patient of Graves' hyperthyroidism to present the continuum of the pathophysiology development of the disease, to highlight the hemodynamic variation is a dominant contributing factor of Graves' hyperthyroidism complication, we wish to emphasize cardiac manifestations in the setting of thyrotoxicosis should be treated promptly and aggressively.
Multivesicular hepatic human hydatid cyst from Iran: First genotyping‐based confirmation
Authors: Soleymani Eissa , Sayyadi Sohrab , Pazoki Hossein , Fakhar Mahdi , Banimostafavi Elham Sadat , Kolivand Mohsen , Davoodi Lotfollah , Soleymani Mostafa 
Published: February 2022

AbstractCystic echinococcosis is one of the most important zoonotic parasitic diseases caused by the tapeworm Echinococcus granulosus. To date, the genotype of multivesicular CE has not been identified. In this regard, the genotyping of multivesicular types of CE could help clinicians understand and manage the disease effectively.
Beating pulmonary vein sign during catheter ablation
Authors: Ishida Shinichi , Takemoto Yoshio , Yamase Yuichiro , Yagami Kei 
Published: February 2022

AbstractThe beating of a pulmonary vein during cardiac catheterization is a rare phenomenon caused by the heart beating through the pericardial effusion when a cardiac tamponade occurs. This “beating pulmonary vein” sign is useful for early detection of a tamponade before circulatory collapse occurs.
Carcinoma en cuirasse associated with zosteriform metastasis in breast adenocarcinoma
Authors: Ghannem Azza , Frioui Refka , Tabka Mariam , Sriha Badreddine , Belajouza Colandane , Denguezli Mohamed 
Published: February 2022

AbstractBreast cancer is the first cancer associated with cutaneous metastasis (CM). The clinical presentation of these metastases is comprehensive. We report an original case of carcinoma en cuirasse associated with zosteriform metastasis that indicates the development of contralateral breast cancer.
Engineering of Cation Occupancy of CoFe2O4 Oxidation Catalysts by Nanosecond, Single‐Pulse Laser Excitation in Water
Authors: Zerebecki Swen , Salamon Soma , Landers Joachim , Yang Yuke , Tong Yujin , Budiyanto Eko , Waffel Daniel , Dreyer Maik , Saddeler Sascha , Kox Tim , Kenmoe Stephane , Spohr Eckhard , Schulz Stephan , Behrens Malte , Muhler Martin , Tüysüz Harun , Kramer Campen R. , Wende Heiko , Reichenberger Sven , Barcikowski Stephan 
Published: February 2022

AbstractDue to the variability of the cation occupancy of octahedral and tetrahedral sites, spinel ferrites and cobaltites are particularly interesting to investigate activity trends in oxidation catalysis. Yet, the preparation of the respective catalyst series remains challenging. We employed pulsed laser defect engineering of CoFe2O4 nanoparticles in water to gradually alter the cation occupancy of octahedral and tetrahedral sites by single laser pulses and study its effect on cinnamyl alcohol oxidation. Three CoFe2O4 catalysts from different synthesis methods resembling different initial site occupancy were chosen as starting materials. The laser‐induced randomization of the cation occupancy was verified by Mössbauer spectroscopy and linearly correlated with the conversion of cinnamyl alcohol while the size and Co : Fe ratio was maintained during laser processing. The study solidifies the importance of octahedral Co3+‐sites and the feasibility of pulsed laser processing for altering the cation occupancy and related crystallographic defect density in oxidation catalysis.
MOF Encapsulated AuPt Bimetallic Nanoparticles for Improved Plasmonic‐induced Photothermal Catalysis of CO2 Hydrogenation
Authors: Wang Yaqin , Zhang Xibo , Chang Kuan , Zhao Zhiying , Huang Jiayu , Kuang Qin 
Published: February 2022

AbstractExploring new catalytic strategies for achieving efficient CO2 hydrogenation under mild conditions is of great significance for environmental remediation. Herein, a composite photocatalyst Zr‐based MOF encapsulated plasmonic AuPt alloy nanoparticles (AuPt@UiO‐66‐NH2) was successfully constructed for the efficient photothermal catalysis of CO2 hydrogenation. Under light irradiation at 150 °C, AuPt@UiO‐66‐NH2 achieved a CO production rate of 1451 μmol gmetal−1 h−1 with 91 % selectivity, which far exceeded those obtained by Au@Pt@UiO‐66‐NH2 with Pt shell on Au (599 μmol gmetal−1 h−1) and Au@UiO‐66‐NH2 (218 μmol gmetal−1 h−1). The outstanding performances of AuPt@UiO‐66‐NH2 were attributed to the synergetic effect originating from the plasmonic metal Au, doped active metal Pt, and encapsulation structure of UiO‐66‐NH2 shell. This work provides a new way for photothermal catalysis of CO2 and a reference for the design of high‐performance plasmonic catalysts.
Improving diagnosis and risk stratification across the ejection fraction spectrum: the Maastricht Cardiomyopathy registry
Authors: Henkens Michiel T.H.M. , Weerts Jerremy , Verdonschot Job A.J. , Raafs Anne G. , Stroeks Sophia , Sikking Maurits A. , Amin Hesam , Mourmans Sanne G.J. , Geraeds Chrit B.G. , Sanders‐van Wijk Sandra , Barandiarán Aizpurua Arantxa , Uszko‐Lencer Nicole H.M.K. , Krapels Ingrid P.C. , Wolffs Petra F.G. , Brunner Han G. , van Leeuwen Rick E.W. , Verhesen Wouter , Schalla Simon M. , van Stipdonk Antonius W.M. , Knackstedt Christian , Li Xiaofei , Abdul Hamid Myrurgia A. , van Paassen Pieter , Hazebroek Mark R. , Vernooy Kevin , Brunner‐La Rocca Hans‐Peter , van Empel Vanessa P.M. , Heymans Stephane R.B. 
Published: February 2022

AbstractAimsHeart failure (HF) represents a clinical syndrome resulting from different aetiologies and degrees of heart diseases. Among these, a key role is played by primary heart muscle disease (cardiomyopathies), which are the combination of multifactorial environmental insults in the presence or absence of a known genetic predisposition. The aim of the Maastricht Cardiomyopathy registry (mCMP‐registry; NCT04976348) is to improve (early) diagnosis, risk stratification, and management of cardiomyopathy phenotypes beyond the limits of left ventricular ejection fraction (LVEF).Methods and resultsThe mCMP‐registry is an investigator‐initiated prospective registry including patient characteristics, diagnostic measurements performed as part of routine clinical care, treatment information, sequential biobanking, quality of life and economic impact assessment, and regular follow‐up. All subjects aged ≥16 years referred to the cardiology department of the Maastricht University Medical Center (MUMC+) for HF‐like symptoms or cardiac screening for cardiomyopathies are eligible for inclusion, irrespective of phenotype or underlying causes. Informed consented subjects will be followed up for 15 years. Two central approaches will be used to answer the research questions related to the aims of this registry: (i) a data‐driven approach to predict clinical outcome and response to therapy and to identify clusters of patients who share underlying pathophysiological processes; and (ii) a hypothesis‐driven approach in which clinical parameters are tested for their (incremental) diagnostic, prognostic, or therapeutic value. The study allows other centres to easily join this initiative, which will further boost research within this field.ConclusionsThe broad inclusion criteria, systematic routine clinical care data‐collection, extensive study‐related data‐collection, sequential biobanking, and multi‐disciplinary approach gives the mCMP‐registry a unique opportunity to improve diagnosis, risk stratification, and management of HF and (early) cardiomyopathy phenotypes beyond the LVEF limits.
Early risk stratification in patients with cardiogenic shock irrespective of the underlying cause – the Cardiogenic Shock Score
Authors: Beer Benedikt N. , Jentzer Jacob C. , Weimann Jessica , Dabboura Salim , Yan Isabell , Sundermeyer Jonas , Kirchhof Paulus , Blankenberg Stefan , Schrage Benedikt , Westermann Dirk 
Published: February 2022

AimsEarly risk stratification is essential to guide treatment in cardiogenic shock (CS). Existing CS risk scores were derived in selected cohorts, without accounting for the heterogeneity of CS. The aim of this study was to develop a universal risk score (the Cardiogenic Shock Score, CSS) for all CS patients, irrespective of the underlying cause.Methods and resultsWithin a registry of 1308 CS unselected patients admitted to a tertiary care hospital between 2009 and 2019, a Cox regression model was fitted to derive the CSS, with 30‐day mortality as main outcome. The CSS's predictive ability was compared to the IABP‐SHOCK II score, the CardShock score and SCAI classification by C‐indices and validated in an external cohort of 934 CS patients. Based on the Cox regression, nine predictors were included in the CSS: age, sex, acute myocardial infarction (AMI‐CS), systolic blood pressure, heart rate, pH, lactate, glucose and cardiac arrest. The CSS had the highest C‐index in the overall cohort (0.740 vs. 0.677/0.683 for IABP‐SHOCK II score/CardShock score), in patients with AMI‐CS (0.738 vs. 0.675/0.689 for IABP‐SHOCK II score/CardShock score) and in patients with non‐AMI‐CS (0.734 vs. 0.677/0.669 for IABP‐SHOCK II score/CardShock score). In the external validation cohort, the CSS had a C‐index of 0.73, which was higher than all other tested scores.ConclusionThe CSS provides improved information on the risk of death in unselected patients with CS compared to existing scores, irrespective of its cause. Because it is based on point‐of‐care variables which can be obtained even in critical situations, the CSS has the potential to guide treatment decisions in CS.
Different domains of identity predict different exit strategies
Authors: Wagoner Joseph A. , Rinnela Mark J. , Barreto Nicolas B. , Turjacanin Vladimir , Blaylock Danielle L. 
Published: February 2022

AbstractGroup schisms are ubiquitous, but little is known about what predicts how people will break away from a group. We hypothesized that different domains of identification (national, regional, ethnonational) would predict support for different types of exit. Study 1 focused on Serbs in the Republic of Srpska within Bosnia‐and‐Herzegovina (N = 188), while Studies 2 (N = 115) and 3 (N = 318) focused on people who identify as Irish in Northern Ireland within the United Kingdom. Across all three studies, weaker national identification predicted support for subgroup exit. Stronger ethnonational identification consistently predicted support for the subgroup joining an existing group, while regional identification had differing relationships with support for the subgroup becoming an independent entity across the samples. Individual exit intentions were predicted by different domains of identification across the three samples. These findings suggest that various domains of identification can predict how people will leave a group.