Scalable Pore Engineering Strategy for Promoting Ion Transport and Rate Capability in Thick Li-Ion Battery Electrodes
Authors: Kim Doyoub , Yushin Gleb , Magasinski Alexandre , Sun Yueyi , Wang Baolin , Narla Aashray , Lee Seung-Hun , Yoo Hana , Jhulki Samik , Song Ah-Young , Hah Jinho , Zhu Ting , Alexeev Alexander 
Published: November 2022

Since the first commercialization of lithium-ion batteries (LIBs) in the early 1990s, previous research has been extensive on electrode material development. Due to its high volumetric energy and power densities and its low cost, the LIBs have aided in the widespread adoption of advanced mobile electronic devices, slowly spurred the market penetration of electric vehicles (EVs) globally and been incorporated in household energy storage systems to promote efficient use of renewable energy1,2. Unfortunately, after rapid improvements in LIB technology, the present progress in increasing energy density and reducing the costs of LIBs has been slow. To overcome the performance limitations on the material side, increasing the nickel (Ni) content of layered lithium nickel cobalt aluminum oxide (NCA) and lithium nickel cobalt manganese oxide (NCM) cathode materials and blending silicon with graphite anode materials have shown promise3,4,5. On the manufacturing side, there is a push to use thicker and denser electrodes and increase areal capacity loadings from 3-4 mAh/cm2 to 5-7 mAh/cm2 to reduce the mass and volume fraction of inactive materials and thus reduce costs and improve the energy density and specific energy of LIB cells beyond about 700 Wh/L and 250 Wh/kg, respectively6.-8
. Unfortunately, the characteristic Li+ ion diffusion time is proportional to the square of the average diffusion path through the electrode, which depends on both the electrode thickness and the tortuosity. As a result, the charging time and power performance characteristics in high-loading, dense electrodes may become undesirably poor. Herein, we report on several manufacturing pathways to create straight channel pores within electrodes to accelerate electrolyte wetting and facilitate rapid ion transport to overcome these rate limitations.
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