bluuebunny/crossref_metadata_2025_split huggingface dataset:
Polypyrrole/reduced graphene oxide composites coated zinc anode with dendrite suppression feature for boosting performances of zinc ion battery
Authors: Khamsanga Sonti , Uyama Hiroshi , Nuanwat Weerapong , Pattananuwat Prasit 
Published: May 2022

AbstractMetallic zinc (Zn) anode has been received a great promise for aqueous rechargeable zinc-ion batteries (ZIBs) due to its intrinsic safety, low cost, and high volumetric capacity. However, the dendrite formation regarding the surface corrosion is the critical problems to achieve the high performance and the long lifespans of ZIBs. Here, we purpose the facile cyclic voltammetry deposition of polypyrrole/reduced graphene oxide (PPy/rGO) composites coated onto Zn 3D surface as Zn anode for ZIBs. As results, the deposited PPy/rGO layer demonstrates the homogeneous distribution covering onto Zn surface, effectively suppressing the formation of dendrite. Additionally, a symmetric cell of the PPy/rGO coated Zn remarkably enhances an electrochemical cycling with a low voltage hysteresis for zinc plating/stripping, which is superior to the pristine Zn cell. In addition, the deposited layer of PPy/rGO on Zn effectively improves the reactivity of electrochemically active surface area and the intrinsic electronic configurations, participating in extraction/intercalation of Zn2+ ions and leading to enhance ZIBs performance. The coin cell battery of Zn-PPy/rGO//MnO2 can deliver a high initial discharge capacity of 325 mAh/g at 0.5A/g with a good cycling stability up to 50% capacity retention after 300 cycles. Thus, these achieved results of Zn-PPy/rGO//MnO2 battery with dendrite-free feature effectively enhance the life-performance of ZIBs and open the way of the designed coating composite materials to suppress dendrite issues.
Theoretical analysis of the deformation for steel gas pipes taking into account shear effects under surface explosion loads
Authors: Wu Tingyao , Yu Hongan , Jiang Nan , Zhou Chuanbo , Luo Xuedong 
Published: May 2022

AbstractGround blast loads are of great importance to the safe operation of steel and gas pipelines, and the results obtained from traditional theoretical formulas for pipeline safety prediction are in error with the actual measured data. In this paper, full-size field tests and corresponding numerical simulations are carried out using Timoshenko beam theory and explosion stress wave theory, which consider shear effects. At the same time, combined with the theory of foundation stiffness and pipeline stiffness flexibility ratio, a modified theoretical model is obtained in line with the actual conditions of the site, which can accurately calculate the deformation and displacement of pipeline underground explosion load, and greatly reduce the error of theoretical prediction results. The innovation of the research results in this paper is that the theoretical stress in the Timoshenko beam can be replaced by the circumferential strain. On the other hand, the modified theoretical solution can obtain the critical weight of explosives to prevent pipeline damage at different buried depths. It provides a theoretical basis for the protection of pipelines’ underground blast loads and provides research ideas for the safe protection and design of pipelines.
Analysis of oat seed transcriptome with regards to proteins involved in celiac disease
Authors: Leišová-Svobodová Leona , Sovová Tereza , Dvořáček Václav 
Published: May 2022

AbstractOat (Avena sativa L.) is considered to be a healthy food. In contrast to other grain crops, oat is high in protein, lipids, dietary fiber, antioxidants, and uniquely in avenanthramides. The question of whether it can also be consumed by people suffering from celiac disease is still unresolved. The main aim of this study was to extract and sequence genes for potentially harmful avenins, globulins, and α-amylase/trypsin inhibitors in six oat varieties and to establish their variability using PacBio sequencing technology of enriched libraries. The results were compared with sequences of the genes already present in databases. In total, 21 avenin, 75 globulin, and 25 α-amylase/trypsin inhibitor genes were identified and mapped in the hexaploid oat chromosomes. In all of the three gene families, only marginal sequence differences were found between the oat varieties within the individual genes. Avenin epitopes were found in all four types of avenin genes occurring in all oat varieties tested within this study. However, the number of avenin genes was nearly four times lower than of globulin genes and, on the protein level, formed only 10% of storage proteins. Therefore, the question of whether oat is safe to celiac disease people is a question of boundary values.
Effects of acute administration of trimethylamine N-oxide on endothelial function: a translational study
Authors: Jomard Anne , Liberale Luca , Doytcheva Petia , Reiner Martin F. , Müller Daniel , Visentin Michele , Bueter Marco , Lüscher Thomas F. , Vettor Roberto , Lutz Thomas A. , Camici Giovanni G. , Osto Elena 
Published: May 2022

AbstractElevated circulating levels of nutrient-derived trimethylamine N-oxide (TMAO) have been associated with the onset and progression of cardiovascular disease by promoting athero-thrombosis. However, in conditions like bariatric surgery (Roux-en-Y gastric bypass, RYGB), stable increases of plasma TMAO are associated with improved endothelial function and reduced cardiovascular morbidity and mortality, thus questioning whether a mechanistic relationship between TMAO and endothelial dysfunction exists. Herein, we translationally assessed the effects of acute TMAO exposure on endothelial dysfunction, thrombosis and stroke. After RYGB, fasting circulating levels of TMAO increased in patients and obese rats, in parallel with an improved gluco-lipid profile and higher circulating bile acids. The latter enhanced FXR-dependent signalling in rat livers, which may lead to higher TMAO synthesis post RYGB. In lean rats, acute TMAO injection (7 mg kg−1) 1.5-h before sacrifice and ex-vivo 30-min incubation of thoracic aortas with 10−6 M TMAO did not impair vasodilation in response to acetylcholine (Ach), glucagon-like peptide 1, or insulin. Similarly, in lean WT mice (n = 5–6), TMAO injection prior to subjecting mice to ischemic stroke or arterial thrombosis did not increase its severity compared to vehicle treated mice. Endothelial nitric oxide synthase (eNOS) activity and intracellular stress-activated pathways remained unaltered in aorta of TMAO-injected rats, as assessed by Western Blot. Pre-incubation of human aortic endothelial cells with TMAO (10−6 M) did not alter NO release in response to Ach. Our results indicate that increased plasmatic TMAO in the near-physiological range seems to be a neutral bystander to vascular function as translationally seen in patients after bariatric surgery or in healthy lean rodent models and in endothelial cells exposed acutely to TMAO.
Impact of the presence of partially erupted third molars on the local radiographic bone condition
Authors: Fernandes Ighor Andrade , Galvão Endi Lanza , Gonçalves Patricia Furtado , Falci Saulo Gabriel Moreira 
Published: May 2022

AbstractThe decision on retaining or prophylactically removing asymptomatic lower third molars is still discussed in the literature. This study aimed to verify the association between asymptomatic lower third molars and local bone conditions through periapical radiographs. Based on sample size calculations, 288 radiographs were required. Dependent variables were alveolar bone crest status and radiolucency between the distal aspect of the third molar crown and the ascending mandibular ramus. Independent variables were sex, age, Pell and Gregory and Winter’s classification, angulation and distance between second and third molars, third molar side. Advanced ages (OR 1.15; CI 1.08–1.24; p < 0.001) and greater third molar angulations (OR 1.03; CI 1.01–1.04; p < 0.001) significantly increased the chance of radiographic alterations in the bone crest between second and third molars. Radiolucency distal to third molars was solely impacted by patient’s age (OR 1.05; CI 1.01–1.11; p = 0.036). Older patients and lower third molars with greater angulations about adjacent second molar should be evaluated for third molar removal because of the increased chance of alveolar bone crest alterations. Older patients should also be monitored for wider radiolucent pericoronal spaces distal to lower third molars and its consequences.
Online recognition and yield estimation of tomato in plant factory based on YOLOv3
Authors: Wang Xinfa , Vladislav Zubko , Viktor Onychko , Wu Zhenwei , Zhao Mingfu 
Published: May 2022

AbstractIn order to realize the intelligent online yield estimation of tomato in the plant factory with artificial lighting (PFAL), a recognition method of tomato red fruit and green fruit based on improved yolov3 deep learning model was proposed to count and estimate tomato fruit yield under natural growth state. According to the planting environment and facility conditions of tomato plants, a computer vision system for fruit counting and yield estimation was designed and the new position loss function was based on the generalized intersection over union (GIoU), which improved the traditional YOLO algorithm loss function. Meanwhile, the scale invariant feature could promote the description precision of the different shapes of fruits. Based on the construction and labeling of the sample image data, the K-means clustering algorithm was used to obtain nine prior boxes of different specifications which were assigned according to the hierarchical level of the feature map. The experimental results of model training and evaluation showed that the mean average precision (mAP) of the improved detection model reached 99.3%, which was 2.7% higher than that of the traditional YOLOv3 model, and the processing time for a single image declined to 15 ms. Moreover, the improved YOLOv3 model had better identification effects for dense and shaded fruits. The research results can provide yield estimation methods and technical support for the research and development of intelligent control system for planting fruits and vegetables in plant factories, greenhouses and fields.
Boosting SARS-CoV-2 detection combining pooling and multiplex strategies
Authors: Correa Isadora Alonso , de Souza Rodrigues Tamires , Queiroz Alex , de França Nascimento Leon , Wolff Thiago , Akamine Rubens Nobumoto , Kuriyama Sergio Noboru , da Costa Luciana Jesus , Fidalgo-Neto Antonio Augusto 
Published: May 2022

AbstractRT-qPCR is the gold standard technique available for SARS-CoV-2 detection. However, the long test run time and costs associated with this type of molecular testing are a challenge in a pandemic scenario. Due to high testing demand, especially for monitoring highly vaccinated populations facing the emergence of new SARS-CoV-2 variants, strategies that allow the increase in testing capacity and cost savings are needed. We evaluated a RT-qPCR pooling strategy either as a simplex and multiplex assay, as well as performed in-silico statistical modeling analysis validated with specimen samples obtained from a mass testing program of Industry Federation of the State of Rio de Janeiro (Brazil). Although the sensitivity reduction in samples pooled with 32 individuals in a simplex assay was observed, the high-test sensitivity was maintained even when 16 and 8 samples were pooled. This data was validated with the results obtained in our mass testing program with a cost saving of 51.5% already considering the expenditures with pool sampling that were analyzed individually. We also demonstrated that the pooling approach using 4 or 8 samples tested with a triplex combination in RT-qPCR is feasible to be applied without sensitivity loss, mainly combining Nucleocapsid (N) and Envelope (E) gene targets. Our data shows that the combination of pooling in a RT-qPCR multiplex assay could strongly contribute to mass testing programs with high-cost savings and low-reagent consumption while maintaining test sensitivity. In addition, the test capacity is predicted to be considerably increased which is fundamental for the control of the virus spread in the actual pandemic scenario.
Insecticide resistant Anopheles gambiae have enhanced longevity but reduced reproductive fitness and a longer first gonotrophic cycle
Authors: Osoro Joyce K. , Machani Maxwell G. , Ochomo Eric , Wanjala Christine , Omukunda Elizabeth , Githeko Andrew K. , Yan Guiyun , Afrane Yaw A. 
Published: May 2022

AbstractWidespread insecticide resistance in African malaria vectors raises concerns over the potential to compromise malaria vector control interventions. Understanding the evolution of resistance mechanisms, and whether the selective disadvantages are large enough to be useful in resistance management or designing suitable control strategies is crucial. This study assessed whether insecticide resistance to pyrethroids has an effect on the gonotrophic cycle and reproductive potential of malaria vector Anopheles gambiae. Comparative tests were performed with pyrethroid-resistant and susceptible colonies of Anopheles gambiae colonized from the same geographical area, and the reference Kisumu strain was used as a control. Adult females aged 3 days old were given a blood meal and kept separately for individual egg-laying. The number of days taken to lay eggs post-blood-feeding was recorded to determine the length of the gonotrophic cycle. To measure adult longevity and reproduction potential, newly emerged males and females of equal numbers were aspirated into a cage and females allowed to blood feed daily. The number of eggs laid and the surviving mosquitoes were recorded daily to determine fecundity, net reproduction rate, intrinsic growth rate and adult longevity. Overall, the resistant females had a significantly longer (1.8 days) gonotrophic cycle than susceptible females (F2, 13 = 9. 836, P < 0.01). The proportion of resistant females that laid eggs was lower 31.30% (94/300) compared to 54% (162/300) in the susceptible colony and 65.7% (197/300) in the Kisumu strain. The mean number of eggs laid per female was significantly lower in the resistant colony (88.02 ± 20) compared to the susceptible colony (104.9 ± .28.8) and the Kisumu strain (97.6 ± 34.8). The adult longevity was significantly higher for resistant (39.7 ± 1.6 days) compared to susceptible (29.9 ± 1.7 days) and the Kisumu strain was (29.6 ± 1.1 days) (F2,8 = 45.05, P < 0.0001). Resistant colony exhibited a lower fecundity (4.3 eggs/females/day) and net reproductive rate (2.6 offsprings/female/generation) compared to the susceptible colony (8.6 eggs/female/day; 4.7 offsprings/female/generation respectively) and Kisumu strain (9.7 eggs/female/day; 4.1 offsprings/female/generation respectively). The study suggests high fitness cost on reproductive parameters of pyrethroid-resistant mosquitoes particularly on the duration of gonotrophic cycle, fecundity and net reproductive rate. These fitness costs are likely associated with maintaining both target site and metabolic mechanisms of resistance to pyrethroids. Despite these costs, resistant mosquitoes had longer longevity. These results give insights to understanding the fitness cost of insecticide resistance and thus are critical when predicting the epidemiological impact of insecticide resistance.
Detection of Mimivirus from respiratory samples in tuberculosis-suspected patients
Authors: Sakhaee Fatemeh , Mosayebi Amroabadi Jalal , Razi Sara , Vaziri Farzam , Abdolrahimi Farid , Moghaddam Sina , Rahimi Jamnani Fatemeh , Siadat Seyed Davar , Fateh Abolfazl 
Published: May 2022

AbstractAcanthamoeba polyphaga mimivirus (APMV), a species of amoeba-infecting giant viruses, has recently emerged as human respiratory pathogens. This study aimed to evaluate the presence of Mimivirus in respiratory samples, collected from tuberculosis (TB)-suspected patients. The study was performed on 10,166 clinical respiratory samples from April 2013 to December 2017. Mimivirus was detected using a suicide nested-polymerase chain reaction (PCR) and real-time PCR methods. Of 10,166 TB-suspected patients, 4 (0.04%) were positive for Mimivirus, including Mimivirus-53, Mimivirus-186, Mimivirus-1291, and Mimivirus-1922. Three out of four patients, hospitalized in the intensive care unit (ICU), were mechanically ventilated. All patients had an underlying disease, and the virus was detected in both sputum and bronchoalveolar lavage samples. In conclusion, Mimivirus was isolated from TB-suspected patients in a comprehensive study. The present results, similar to previous reports, showed that Mimiviruses could be related to pneumonia. Further studies in different parts of the world are needed to additional investigate the clinical importance of Mimivirus infection.
Real- and momentum-space description of the excitons in bulk and monolayer chromium tri-halides
Authors: Acharya Swagata , Pashov Dimitar , Rudenko Alexander N. , Rösner Malte , Schilfgaarde Mark van , Katsnelson Mikhail I. 
Published: May 2022

AbstractExcitons with large binding energies ~2–3 eV in CrX3have been characterized as being localized (Frenkel) excitons that emerge from the atomicd − dtransitions between the Cr-3d-t2gandegorbitals. The argument has gathered strength in recent years as the excitons in recently made monolayers are found at almost the same energies as the bulk. The Laporte rule, which restricts such parity forbidden atomic transitions, can relax if a symmetry-breaking mechanism is present. While what can be classified as a purely Frenkel exciton is a matter of definition, we show using an advanced first principles parameter-free approach that these excitons in CrX3, in both its bulk and monolayer variants, have band origin and it is thedphybridization between Cr and X that primarily acts as the symmetry-breaking mechanism that relaxes the Laporte rule. We show that the character of these excitons is mostly determined by the Cr-dorbital manifold, nevertheless, the fractions of the spectral weight shared with the ligand halogen states increases as thedphybridization enhances. The hybridization enhances as the halogen atom becomes heavier, bringing the X-pstates closer to the Cr-dstates in the sequence Cl → Br → I, with an attendant increase in exciton intensity and a decrease in binding energy. By applying a range of different kinds of perturbations that qualitatively mimics the effects originating from the missing vertex in self-energy, we show that moderate changes to the two-particle Hamiltonian that essentially modifies the Cr-d-X-phybridization, can alter both the intensities and positions of the exciton peaks. A detailed analysis of several deep-lying excitons, with and without strain, elucidates the fact that the exciton is most Frenkel-like in CrCl3and CrBr3and acquires mixed Frenkel–Wannier character in CrI3, making the excitons in CrI3most susceptible to environmental screening and spin–orbit coupling.
Hypothalamic remodeling of thyroid hormone signaling during hibernation in the arctic ground squirrel
Authors: Chmura Helen E. , Duncan Cassandra , Saer Ben , Moore Jeanette T. , Barnes Brian M. , Loren Buck C. , Christian Helen C. , Loudon Andrew S. I. , Williams Cory T. 
Published: May 2022

AbstractHibernation involves prolonged intervals of profound metabolic suppression periodically interrupted by brief arousals to euthermy, the function of which is unknown. Annual cycles in mammals are timed by a photoperiodically-regulated thyroid-hormone-dependent mechanism in hypothalamic tanycytes, driven by thyrotropin (TSH) in the pars tuberalis (PT), which regulates local TH-converting deiodinases and triggers remodeling of neuroendocrine pathways. We demonstrate that over the course of hibernation in continuous darkness, arctic ground squirrels (Urocitellus parryii) up-regulate the retrograde TSH/Deiodinase/TH pathway, remodel hypothalamic tanycytes, and activate the reproductive axis. Forcing the premature termination of hibernation by warming animals induced hypothalamic deiodinase expression and the accumulation of secretory granules in PT thyrotrophs and pituitary gonadotrophs, but did not further activate the reproductive axis. We suggest that periodic arousals may allow for the transient activation of hypothalamic thyroid hormone signaling, cellular remodeling, and re-programming of brain circuits in preparation for the short Arctic summer.
Single thermodynamic transition at 2 K in superconducting UTe2 single crystals
Authors: Rosa Priscila F. S. , Weiland Ashley , Fender Shannon S. , Scott Brian L. , Ronning Filip , Thompson Joe D. , Bauer Eric D. , Thomas Sean M. 
Published: May 2022

AbstractUTe2 is a newly-discovered unconventional superconductor wherein multicomponent topological superconductivity is anticipated based on the presence of two superconducting transitions and time-reversal symmetry breaking in the superconducting state. The observation of two superconducting transitions, however, remains controversial. Here we demonstrate that UTe2 single crystals displaying an optimal superconducting transition temperature at 2 K exhibit a single transition and remarkably high quality supported by their large residual resistance ratio and small residual heat capacity in the superconducting state. Our results shed light on the intrinsic superconducting properties of UTe2 and bring into question whether UTe2 is a multicomponent superconductor at ambient pressure.
Juglophen: a tetradentate non-innocent electron sponge naphthoquinone-imine ligand and its reduced and oxidized nickel complexes [Ni(jp)]−,0,+
Authors: Schumann Henrik , Klein Marius , Prinzisky Christian , Burghaus Olaf , Sundermeyer Jörg 
Published: May 2022

The synthesis of new tetradentate dianionic N2O2 ligand juglophen (H2jp, 1), its nickel(ii) complex [Ni(jp)] (2) as well as oxidized [Ni(jp)]+ (3) and reduced [Ni(jp)]− (4) ionic species are reported.
Cu3N/Cu2O core–shell nanowires: growth and properties
Authors: Mavridou Kalliopi , Katsikini Maria , Othonos Andreas , Florini Nikoletta , Komninou Philomela , Zervos Matthew 
Published: May 2022

CuO nanowires were grown on Cu foils at 600 °C, coated with Cu and converted into Cu3N/Cu2O core–shell nanowires under NH3:H2 at 400 °C. The structural and optical properties are described in detail as well as its potential for energy applications.