bluuebunny/crossref_metadata_2025_split huggingface dataset:
Large ensemble of downscaled historical daily snowfall from an earth system model to 5.5 km resolution over Dronning Maud Land, Antarctica
Authors: Ghilain Nicolas , Vannitsem Stéphane , Dalaiden Quentin , Goosse Hugues , De Cruz Lesley , Wei Wenguang 
Published: April 2022

Abstract. We explore a methodology to statistically downscale snowfall – the primary driver of surface mass
balance in Antarctica – from an ensemble of historical (1850–present day) simulations performed
with an earth system model over the coastal region of Dronning Maud Land (East Antarctica).
This approach consists of associating daily snowfall simulations from a polar-oriented regional
atmospheric climate model at 5.5 km spatial resolution with specific weather patterns observed
over 1979–2010 CE with the atmospheric reanalyses ERA-Interim and ERA5. This association is
then used to generate the spatial distribution of snowfall for the period from 1850 to present day for
an ensemble of 10 members from the Community Earth System Model (CESM2). The new dataset of daily and
yearly snowfall accumulation based on this methodology is presented in this paper (MASS2ANT
dataset; https://doi.org/10.5281/zenodo.4287517; Ghilain et al., 2021). Based on a comparison
with available ice cores and spatial reconstructions, our results show that the spatio-temporal
distribution of snowfall is improved in the downscaled dataset compared with the CESM2
simulations. This dataset thus provides information that may be useful in identifying the large-scale
patterns associated with the local precipitation conditions and their changes over the past century.
COUNTERING TERRORISM AND REDUCING STRATEGIC UNCERTAINTY: ANALYSING ‘SHAPING’ MULTINATIONAL MILITARY EXERCISES
Authors: Bashir Sadaf , Gul Sumara 
Published: April 2022

The post-Cold War period has witnessed a significant increase in ‘shaping’ multinational military exercises, which are considered a valuable instrument of defence diplomacy. Shaping multinational military exercises aim to encourage the partner military's role and adapt relationship to reduce strategic uncertainty. Since 2014, Pakistan’s conduct and participation in multinational military exercises have increased significantly. Pakistan conducts four such exercises to reduce strategic uncertainty: recruitment, capacity-building, role-forming, and trust-developing. This article, therefore, argues that Pakistan pursues shaping multinational military exercises to mould the strategic thinking of both friends and potential adversaries to achieve foreign policy goals in a complex security environment.

Bibliography Entry
Bashir, Sadaf, Sumara Gul. 2021. "Countering Terrorism and Reducing Strategic Uncertainty: Analysing ‘Shaping’ Multinational Military Exercises." Margalla Papers 25 (2): 71-83.
Productive Tensions
Authors: Bingham Christopher B. , McDonald Rory M. 
Published: April 2022

How leaders can recast innovation's toughest trade-offs—efficiency vs. flexibility, consistency vs. change, product vs purpose—as productive tensions.
Why is leading innovation in today's dynamic business environment so distressingly hit-or-miss? More than 90 percent of high-potential ventures don't reach their projected targets. Surveys show that 80 percent of executives consider innovation crucial to their growth strategy, but only 6 percent are satisfied with their innovation performance. Should leaders aim for Steve Jobs-level genius, shower their projects with resources, or lean in to luck and embrace uncertainty? None of the above, say Christopher Bingham and Rory McDonald.
Drawing on cutting-edge research and probing interviews with hundreds of leaders across three continents, Bingham and McDonald find in Productive Tensions that the most effective leaders and successful innovators embrace the tensions that arise from competing aims: efficiency or flexibility? consistency or change? product or purpose? Bingham and McDonald spotlight eight critical tensions that every innovator must master, and they spell out, with dozens of detailed examples of both success and failure, how to navigate them. How do you excite customers about a product they've never imagined? When is it wise to accept what the data is telling you, and when should you ignore the data and plow forward anyway? How can you maintain stakeholders' trust and support during radical unforeseen course corrections? Bingham and McDonald guide readers through innovation's thorniest tensions, using examples drawn from the experience of organizations as varied as P&G, Instagram, the US military, Honda, In-N-Out Burger, Slack, Under Armour, and the snowboarding company Burton.
Doping‐Induced Electronic/Ionic Engineering to Optimize the Redox Kinetics for Potassium Storage: A Case Study of Ni‐Doped CoSe2
Authors: Shan Hui , Qin Jian , Wang Jingjing , Sari Hirbod Maleki Kheimeh , Lei Li , Xiao Wei , Li Wenbin , Xie Chong , Yang Huijuan , Luo Yangyang , Zhang Gaini , Li Xifei 
Published: April 2022

AbstractHeteroatom doping effectively tunes the electronic conductivity of transition metal selenides (TMSs) with rapid K+ accessibility in potassium ion batteries (PIBs). Although considerable efforts are dedicated to investigating the relationship between the doping strategy and the resulting electrochemistry, the doping mechanisms, especially in view of the ion and electronic diffusion kinetics upon cycling, are seldom elucidated systematically. Herein, the crystal structure stability, charge/ion state, and bandgap of the active materials are found to be precisely modulated by favorable heteroatom doping, resulting in intrinsically fast kinetics of the electrode materials. Based on the combined mechanisms of intercalation and conversion reactions, electron and K+ ion transfer in Ni‐doped CoSe2 embedded in carbon nanocomposites (Ni‐CoSe2@NC) can be significantly enhanced via electronic engineering. Benefiting from the synthetic controlled Ni grains, the heterointerface formed by the intermediate products of electrochemical reactions in Ni‐CoSe2@NC strengthens the conversion kinetics and interdiffusion process, developing a low‐barrier mesophase with optimized potassium storage. Overall, an electronic tuning strategy can offer deeper atomic insights into the conversion reaction of TMSs in PIBs.
Synthesis of Defective Nanographenes Containing Joined Pentagons and Heptagons
Authors: Fei Yiyang , Liu Junzhi 
Published: April 2022

AbstractDefective nanographenes containing joined pentagons and heptagons exhibit striking physicochemical properties from both experimental and theoretical perspectives compared with their pure hexagonal counterparts. Thus, the synthesis and characterization of these unique polyarenes with well‐defined defective topologies have attracted increasing attention. Despite extensive research on nonalternant molecules since the last century, most studies focused on the corresponding mutagenic and carcinogenic activities. Recently, researchers have realized that the defective domain induces geometric bending and causes electronic perturbation, thus leading to significant alteration of the photophysical properties. This review discusses the synthesis and characterization of small nonalternant polycyclic hydrocarbons in the early stage and recent developments in embedding pentagon–heptagon (5–7) pairs into large carbon skeletons through in‐solution chemistry.
Temperature and Rainfall Patterns Constrain the Multidimensional Rewilding of Global Forests
Authors: Zhou Guiyao , Zhou Xuhui , Eldridge David J. , Han Ximei , Song Yanjun , Liu Ruiqiang , Zhou Lingyan , He Yanghui , Du Zhenggang , Delgado‐Baquerizo Manuel 
Published: April 2022

AbstractThe long‐term contribution of global forest restoration to support multiple dimensions of biodiversity and ecosystem function remains largely illusive across contrasting climates and forest types. This hampers the capacity to predict the future of forest rewilding under changing global climates. Here, 120 studies are synthesized across five continents, and it is found that forest restoration promotes multiple dimensions of biodiversity and ecosystem function such as soil fertility, plant biomass, microbial habitat, and carbon sequestration across contrasting climates and forest types. Based on global relationship between stand age and soil organic carbon stock, planting 350 million hectares of forest under the UN Bonn Challenge can sequester >30 Gt soil C in the surface 20 cm over the next century. However, these findings also indicate that predicted increases in temperature and reductions in precipitation can constrain the positive effects of forest rewilding on biodiversity and ecosystem function. Further, important tradeoffs are found in very old forests, with considerable disconnection between biodiversity and ecosystem function. Together, these findings provide evidence of the importance of the multidimensional rewilding of forests, suggesting that on‐going climatic changes may dampen the expectations of the positive effects of forest restoration on biodiversity and ecosystem function.
Concise access to perimidines by palladium (II) complexes via acceptorless dehydrogenative coupling of alcohols
Authors: Clinton Savarimuthu Selvan , Ramesh Rengan , Małecki Jan Grzegorz 
Published: April 2022

A facile protocol for the one‐pot synthesis of 2,3‐dihydro‐1H‐perimidines via dehydrogenative coupling of easily exploitable benzyl alcohols supported by new Pd(II) complexes has been reported. To accomplish the construction of perimidines, a new set of palladium(II) complexes [Pd(L)Cl (PPh3)] (1–3) encompassing biphenyl benzhydrazone ligands (L=L1–L3) has been reported as catalysts. Structural characterization by elemental analysis, FT‐IR, NMR (1H and13C), and mass spectral analyses confirmed the composition of synthesized complexes. The molecular structures complex1and complex2were unequivocally resolved using single‐crystal X‐ray diffraction. It reveals that the complex espoused distorted square‐planar geometry around Pd(II) ion chelated by azomethine nitrogen and imidolate oxygen of biphenyl benzhydrazone ligands with labile chloride and a triphenylphosphine. Further, the selective synthesis of a broad range of functionalized perimidines has been accomplished via ADC of a variety of alcohols with 1,8‐diamino naphthalene. The palladium complexes mediated catalytic synthesis offered good yields of perimidines up to 86% using only 0.5 mol% catalyst loading. A probable mechanism to the formation of perimidines was postulated from the results of control experimental investigations. The environmentally compassionate, greener ADC protocol progresses via the generation of aldehyde intermediate and releases only water and hydrogen gas.
Efficient Oxidation of Paracetamol Triggered by Molecular‐Oxygen Activation at β‐Cyclodextrin‐Modified Titanate Nanotubes
Authors: Zhou Yi , Liu Qiming , Li Xia , Ling Liangxiong , Zhou Yanbo 
Published: April 2022

AbstractTitanate nanotubes (TNTs) were coated with a cyclic oligosaccharide (carboxymethyl‐β‐cyclodextrin, CM‐β‐CD) to obtain a photocatalyst (CM‐β‐CD‐TNT) for efficiently activating molecular oxygen and removing the target contaminant. The hydrophobic cavity and the large specific surface area of the photocatalyst provide abundant active sites for activating molecular oxygen. The free radical capture experiment and quenching experiment showed that cyclodextrin could facilitate adsorption and activation of molecular oxygen to produce O2.−. Therefore, compared with the pristine TNT, CM‐β‐CD‐TNT accelerated the oxidation efficiency of paracetamol (APAP) by 3.4 times. Moreover, the ring cleavage reaction induced by CM‐β‐CD‐TNT effectively reduced the acute toxicity of wastewater containing APAP. Furthermore, 100% of bisphenol A (BPA), bisphenol S (BPS), phenol, 2,4‐dichlorophen (2,4‐DCP), and carbamazepine (CBZ) were degraded by CM‐β‐CD‐TNT after 2.5 h ultraviolet (UV) light irradiation. This strategy provides a new dimension for the advanced treatment of organic wastewater by organic macrocyclic molecule‐modified materials.
Non‐fragile reliable control of nonlinear positive semi‐Markovian jump systems with nonlinear actuator faults
Authors: Liu Jinjin , Song Chunyue , Li Zhiqiang , Zhang Ting 
Published: April 2022

AbstractThis paper investigates the non‐fragile reliable control of nonlinear positive semi‐Markovian jump systems with nonlinear actuator faults. First, a novel fault model consisting of linear and nonlinear terms is established for the systems. By constructing a stochastic co‐positive Lyapunov function, the non‐fragile reliable controller is designed for the systems with additive gain perturbations using matrix decomposition technique. Then, the proposed design is extended for dealing with multiplicative gain perturbations and variable gain perturbations. Under the designed controllers, the resulting closed‐loop systems are positive and stochastically stable. All presented conditions are solvable in terms of linear programming. Finally, two illustrative examples are provided to verify the effectiveness of the theoretical results.
How bricolage influences green management in high‐polluting manufacturing firms: The role of stakeholder engagement
Authors: Wu Liang , Liu Heng 
Published: April 2022

AbstractAs green management (GM) matters not only for firms' competitiveness but also has social and health benefits, both the public and government often expect firms to apply it. However, the current literature fails to provide a detailed explanation of how emerging market firms in high‐polluting manufacturing (HPM) industries deal with challenges when applying GM activities, even though these firms may be a key source of environmental problems. To address this research gap, we draw upon a subjectivist view of resource construction to investigate how and when HPM firms in emerging economies can rely on the tactic of bricolage to boost GM. We tested our research model on a sample of 180 chemical engineering manufacturing firms in China. Our results showed that HPM firms can rely on bricolage to positively implement GM, but its effects depend on the participation of different stakeholders. That is, firms can benefit more from bricolage in implementing GM when their suppliers can provide strong technical support and the moral requirements of the public are high. This study highlights the role of subjective resource construction activities in GM with the help of different stakeholder's participation in emerging economies and provides novel explanations and policy implications for this emerging phenomenon.
Treatment patterns, effectiveness, and patient‐reported outcomes of palbociclib therapy in Chinese patients with advanced breast cancer: A multicenter ambispective real‐world study
Authors: Shen Lesang , Zhou Jun , Chen Yiding , Ding Jinhua , Wei Haiyan , Liu Jian , Xia Wenjie , Xie Bojian , Xie Xiaohong , Li Xujun , Dai Yuechu , Zhang Guobing , Qiu Xia , Li Chao , Sun Shanshan , Chen Wuzhen , Gong Dihe , Li Hengyu , Huang Jian , Jiang Xia , Ni Chao 
Published: April 2022

AbstractBackgroundPalbociclib was the only available cyclin‐dependent kinase 4/6 inhibitor in China until very recently, and its effect has not been systemically evaluated among Chinese patients. This study aims to assess the efficacy, safety and patient‐reported outcomes (PROs) of palbociclib plus endocrine therapy (ET) in real‐world China.MethodsAn ambispective cohort study was conducted on patients with advanced HR+HER2− breast cancer who received palbociclib between July 2018, and November 2020 and were enrolled from 12 hospitals. Treatment patterns, survival outcomes, and safety events were documented, and PROs (European Organization for Research and Treatment of Cancer Quality of Life Questionnaire‐Core 30 items [EORTC QLQ‐C30] and EuroQoL 5 dimensions [EQ‐5D]) were analyzed. The Kaplan–Meier method was used to visualize and estimate the median progression‐free survival (mPFS). Log‐rank tests, Cox regressions, t tests, and chi‐square tests were performed for comparison.ResultsA total of 190 patients (median follow‐up of 18.0 months) were enrolled. Palbociclib was mostly combined with aromatase inhibitors (66.3%), fulvestrant (32.6%), and tamoxifen (1.1%). The mPFS values were 21.0, 14.0, and 7.0 months with palbociclib administered in first‐ (n = 83), second‐ (n = 41) and subsequent‐line settings (n = 66), respectively. Endocrine sensitivity was significantly associated with patient prognosis (mPFS: 23.0, 12.0, and 6.0 months for endocrine naïve, acquired, and primary resistant patients, respectively, p < 0.01). The outcome was worse for patients who failed to meet the inclusion criteria of PALOMA‐3 than for those who met the criteria (later‐line: 6.0 months vs. 9.0 months). The most common adverse events (AEs) were neutropenia (74.2%; grade 3/4: 30.0%), fatigue (48.4%), anemia (32.6%), and thrombocytopenia (22.1%). PRO data suggested that palbociclib plus ET significantly improved cognitive and emotional function, pain symptoms, and overall quality of life.ConclusionsPalbociclib is effective for front‐line use and for treating endocrine‐sensitive patients in real‐world China and is generally well tolerated. The prevalence of AEs in the Chinese population is different from that reported in the PALOMA‐2/3 trials.
Cultural congruity and extensions of corporate heritage brands: An empirical analysis of time‐honored brands in China
Authors: Zhou Luyang , Hui Michael K. , Zhou Lianxi , Li Shengxiao 
Published: April 2022

AbstractThis article furthers the understanding of cultural congruity in relation to extension evaluations of corporate heritage brands. The extension of corporate heritage brands remains challenging, due to their unique identities around heritage—typically fostering a narrow spectrum of product‐cultural domain. Drawing on the concept of cultural congruity, this paper puts forward the notion that one effective way to break the deadlock of a brand's heritage is to expand into product categories that share the unique cultural heritage in ways that are meaningful, not merely symbolic. Based on data from a large survey on time‐honored brands in China, this paper demonstrates that cultural congruity does not only influence extension evaluations directly, but also indirectly through perceived fit. The findings further indicate that brand cultural heritage positively moderates both direct and indirect effects. This study enhances the concept of product fit from the lens of cultural congruity and opens up a new avenue for managing corporate heritage brands in the marketplace.
COVID‐19 and COVID‐19 vaccine‐related dermatological reactions: An interesting case series with a narrative review of the potential critical and non‐critical mucocutaneous adverse effects related to virus, therapy, and the vaccination
Authors: Pour Mohammad Arash , Mashayekhi Farzaneh , Seirafianpour Farnoosh , Gholizadeh Mesgarha Milad , Goodarzi Azadeh 
Published: April 2022

AbstractThis narrative review article was conducted to lay out a summarized but exhaustive review of current literature over mucocutaneous manifestations in 4 dimensions of SARS‐CoV‐2 pandemic: virus itself, treatment‐related, vaccine‐induced, and alteration of chronic dermatologic diseases following infection. Virus and vaccine‐related were mainly self‐limited and non‐severe. Treatment‐related reactions could be life‐threatening.
Determining the Scope 3 Emissions of Companies
Authors: Schmidt Mario , Nill Moritz , Scholz Johannes 
Published: April 2022

AbstractThe use of materials, goods, and services is associated with greenhouse gas emissions. These so‐called scope 3 emissions make a considerable contribution to the climate footprints of companies. Calculating these emissions is difficult because they occur in the supply chain, which can usually only be traced to the first supplier. Economic input‐output analysis methods can be used to estimate emissions in supply chains. They provide indications of the origin of emissions by country and industry sector or product group. With recursive methods in the supply chain, these calculations can be continuously improved.
Study on molecular structure and association behaviour of heavy subfractions of vacuum residue by an improved separation method
Authors: Tian Feng , Han Wei , Zhu Yonghong , Wang Yijie , Fan Xiaoyong , Du Chongpeng , Wang Feili , Zheng Huaan , Teng Haipeng , Li Dong 
Published: April 2022

AbstractVacuum residue (VR) is the most complex component of crude oil. Due to the special structure of heavy subfractions, physical aggregation and chemical coking reactions easily occur through molecular force, which affects the normal processing. Therefore, in‐depth study and analysis of their composition, structure and association behaviours are particularly important. In view of the shortcomings of the traditional separation method in terms of separation accuracy, mainly including the purification of asphaltenes and the poor separation of resins. In this paper, a reasonably improved separation method is adopted, and the multi‐stage asphaltene extraction and the multi‐stage silica gel coupling separation are carried out innovatively, which achieves a high yield of 99% while ensuring the separation accuracy. The samples were characterized by elemental analysis (EA), gel permeation chromatography (GPC), Fourier‐transform infrared spectroscopy (FT‐IR), hydrogen nuclear magnetic resonance spectroscopy (1H‐NMR), X‐ray photoelectron spectroscopy (XPS), X‐ray diffraction (XRD), and scanning electron microscope (SEM) to study their structural characteristics and association behaviours. The results show that the main forms of heteroatoms in asphaltene and resin surface are C‐O‐C, C‐OH, pyridine, pyrrole, and thiophene, and the content of these substances is higher in asphaltene. Compared with resins, asphaltenes contain a more peri‐condensed aromatic structure and shorter alkyl substituent side chains. By studying the hydrogen bond and acid–base interaction, it is found that asphaltene and resin mainly contain OH‐OH, OH‐π, and OH‐ether O, of which the content of OH‐OH is the highest. Asphaltene and resin have more neutral and basic substances. These hydrogen bonds and acid–base interactions caused by heteroatoms are the main forces for the association of the heavy subfractions of the VR.
Developmental neuroanatomy of the rosy bitterling Rhodeus ocellatus (Teleostei: Cypriniformes)—A microCT study
Authors: Yi Wenjing , Mueller Thomas , Rücklin Martin , Richardson Michael K. 
Published: April 2022

AbstractBitterlings are carp‐like teleost fish (Cypriniformes: Acheilanathidae) known for their specialized brood parasitic lifestyle. Bitterling embryos, in fact, develop inside the gill chamber of their freshwater mussel hosts. However, little is known about how their parasitic lifestyle affects brain development in comparison to nonparasitic species. Here, we document the development of the brain of the rosy bitterling, Rhodeus ocellatus, at four embryonic stages of 165, 185, 210, 235 hours postfertilization (hpf) using micro‐computed tomography (microCT). Focusing on developmental regionalization and brain ventricular organization, we relate the development of the brain divisions to those described for zebrafish using the prosomeric model as a reference paradigm. Segmentation and three‐dimensional visualization of the ventricular system allowed us to identify changes in the longitudinal brain axis as a result of cephalic flexure during development. The results show that during early embryonic and larval development, histological differentiation, tissue boundaries, periventricular proliferation zones, and ventricular spaces are all detectable by microCT. The results of this study visualized with differential CT profiles are broadly consistent with comparable histological studies, and with the genoarchitecture of teleosts like the zebrafish. Compared to the zebrafish, our study identifies distinct developmental heterochronies in the rosy bitterling, such as a precocious development of the inferior lobe.