bluuebunny/crossref_metadata_2025_split huggingface dataset:
Non arrendersi all’ovvio. Considerazioni sugli stereotipi di genere in margine alla sentenza della Corte costituzionale n. 131 del 2022 sull’attribuzione del cognome
Authors: Borello Maria 
Published: September 2022

SOMMARIO: 1. Considerazioni introduttive - 2. Stereotipi e luoghi comuni - 3. Stereotipi e linguaggio di genere - 4. Contro un automatismo discriminante: la sentenza della Corte costituzionale n. 131 del 2022 - 5. Non arrendersi all’ovvio.
Resist the obvious. Some considerations on gender stereotypes following the sentence of the Italian Constitutional Court, n. 131 of 2022, on the attribution of the surname
ABSTRACT: The aim of this contribution is to examine the gender inequalities issues, particularly those of women, within the linguistic perspective. In particular, it highlights the discriminating capacity of stereotypes and discusses their performative dimension. Nowadays, despite several recommendations to reduce the gender gap, women continue to be marginalised in a still strong masculine culture, also through discursive practices. So, commonplaces, thanks to their simplicity and immediacy, reinforce an order of power relations between genders that place women in a position of subordination. In order to subvert this situation and reach an equal condition, the law also appears useful. The last sentence issued by the Italian Constitutional Court, on the attribution of surname to children, offers a good example in this sense. The path still appears long and uncertain, but highlighting stereotypes distortions can contribute to achieving an equal democracy which finds in inclusiveness an indispensable basis for an authentically democratic condition of life, that encourages the emergence and spread of a way of being more open, and also more ethical, a way of being of the future and for the future.
Over procesafspraken en de zoektocht naar het gedeelde belang
Authors: van den Hazel C.J.D. (Rinske) , van de Stouwe A.S. (Anouk) , Tiebosch M. (Maartje) 
Published: September 2022

Over procesafspraken en de zoektocht naar het gedeelde belang
Procesafspraken zijn een eerste stap naar een nieuwe vorm van rechtspraak waarbij samenwerking en onderhandeling centraal staan. In dit artikel staan de auteurs stil bij de stand van zaken in ‘procesafsprakenland’ aan de hand van jurisprudentie. Zij bespreken het nut van procesafspraken voor de verschillende partijen en schetsen de praktijk in de tweede lijn. Daarbij staan zij onder andere stil bij de kwestie hoe het probleem van een mogelijk negatieve uitkomst wordt getackeld. Dilemma’s worden niet onbesproken gelaten en de bijdrage wordt afgesloten met een blik op de toekomst van procesafspraken.
De rafelranden van procesafspraken
Authors: van der Meij P.P.J. (Patrick) 
Published: September 2022

De rafelranden van procesafspraken
De strafzaken waarin eind 2021 procesafspraken zijn gemaakt, zijn vanuit de overbelaste strafrechtspleging tot voor kort instemmend ontvangen. Het streven naar het maken van dergelijke procesafspraken kreeg daardoor ook opvolging in andere strafzaken. De strafzaken waarin procesafspraken een rol spelen lopen enorm uiteen, zowel wat betreft aard en omvang, als bijvoorbeeld fase van het strafproces en feitelijke en juridische complexiteit van de zaak. Een analyse van de jurisprudentie legt de zwakke plekken bloot van de praktijk van procesafspraken en onderstreept waarom bij een voortschrijdende toepassing een meer structurele en met waarborgen omgeven procedure noodzakelijk is. Er zijn gewoonweg te veel rafelranden.
Menumbuhkan Perilaku dan Nilai Kewirausahaan Dalam Meningkatkan Kemandirian Bisnis di Kota Medan
Authors: Siregar Ahmad Rajin , M. Nawawi Zuhrinal 
Published: September 2022

Perspectives and ways of behaving are the solidarity of an individual's personality which is framed by propensity ordinary. Pioneering conduct is impacted by inward and outer variables. These variables are possession freedoms (property right, PR), capacities/capabilities (skill/capacity,), and motivating forces while outside factors incorporate the climate in this way Attitudes and conduct can be changed without anyone else and/or there are natural tensions/impacts. there is an impact from inside themselves and from outside the climate to relate then develop indi mentalities and explicit ways of behaving. It is important to expect independent ventures' hardships by leading an exact concentrate on the enterprising soul, innovative qualities, and appraisal of pioneering conduct that might influence the acknowledgment of freedom endeavors. This study intends to investigate the impact of pioneering soul and enterprising qualities on innovative way of behaving to make business autonomy. The discoveries show that the pioneering soul impacts innovative way of behaving and positive roundabout impact on the business freedom.
Keywords : Attitude, behaviour, entepreneurial spirit, to create business independence
Pengaruh Profitabilitas, Resiko Bisnis Dan Pertumbuhan Penjualan Terhadap Struktur Modal pada Perusahaan Property dan Real Estate di BEI Periode 2016 - 2020
Authors: Brona Areza Marta , Rinofah Risal , Prima Sari Pristin , Prima Sari Pristin 
Published: September 2022

Capital structure is a comparison between foreign capital and own capital. In principle, the company needs funding both from outside which is debt and from within which is joint capital, therefore the company must determine and compile how much capital the company must need. This study aims to analyze the effect of profitability, business risk and sales growth on the capital structure of property and real estate companies listed on the Indonesia Stock Exchange for the period 2016-2020 partially and simultaneously. This study uses quantitative data types obtained from secondary data with sample data collection techniques through purposive sampling method. This research method uses descriptive method with data analysis tool using multiple linear regression method. The results of this study indicate that profitability as proxied by ROE has an insignificant negative effect on capital structure, business risk has a significant negative effect on capital structure and sales growth has an insignificant negative effect on capital structure. Meanwhile, simultaneously (together) profitability, business risk and sales growth affect the capital structure of property and real estate companies listed on the Indonesia Stock Exchange for the period 2016-2020.
Keywords: Profitability, Business Risk, Sales Growth, Capital Structure.
Constructing Science
Authors: Weisberg Deena Skolnick , Sobel David M. 
Published: September 2022

An examination of children's causal reasoning capacities and how those capacities serve as the foundation of their scientific thinking.
Young children have remarkable capacities for causal reasoning, which are part of the foundation of their scientific thinking abilities. In Constructing Science, Deena Weisberg and David Sobel trace the ways that young children's sophisticated causal reasoning abilities combine with other cognitive, metacognitive, and social factors to develop into a more mature set of scientific thinking abilities. Conceptualizing scientific thinking as the suite of skills that allows people to generate hypotheses, solve problems, and explain aspects of the world, Weisberg and Sobel argue that understanding how this capacity develops can offer insights into how we can become a more scientifically literate society.
Investigating the development of causal reasoning and how it sets the stage for scientific thinking in the elementary school years and beyond, Weisberg and Sobel outline a framework for understanding how children represent and learn causal knowledge and identify key variables that differ between causal reasoning and scientific thinking. They present empirical studies suggesting ways to bridge the gap between causal reasoning and scientific thinking, focusing on two factors: contextualization and metacognitive thinking abilities. Finally, they examine children's explicit understanding of such concepts as science, learning, play, and teaching.
Evaluation of Textbook Outcome as a Composite Quality Measure of Elective Laparoscopic Cholecystectomy
Authors: Lucocq James , Scollay John , Patil Pradeep 
Published: September 2022

ImportanceA textbook outcome (TO) is a composite quality measure that incorporates multiple perioperative events to reflect the most desirable outcome. The use of TO increases the event rate, captures more outcomes to reflect patient experience, and can be used as a benchmark for quality improvement.ObjectivesTo introduce the concept of TO to elective laparoscopic cholecystectomy (LC), propose the TO criteria, and identify characteristics associated with TO failure.Design, Setting, and ParticipantsThis retrospective cohort study was performed at 3 surgical units in a single health board in the United Kingdom. Participants included all patients undergoing elective LC between January 1, 2015, and January 1, 2020. Data were analyzed from January 1, 2015, to January 1, 2020.Main Outcomes and MeasuresThe TO criteria were defined based on review of existing TO metrics in the literature for other surgical procedures. A TO was defined as an unremarkable elective LC without conversion to open cholecystectomy, subtotal cholecystectomy, intraoperative complication, postoperative complications (Clavien-Dindo classification ≥2), postoperative imaging, postoperative intervention, prolonged length of stay (&gt;2 days), readmission within 100 days, or mortality. The rate of TOs was reported. Reasons for TO failure were reported, and preoperative characteristics were compared between TO and TO failure groups using both univariate analysis and multivariable logistic regressions.ResultsA total of 2166 patients underwent elective LC (median age, 54 [range, 13-92] years; 1579 [72.9%] female). One thousand eight hundred fifty-one patients (85.5%) achieved a TO with an unremarkable perioperative course. Reasons for TO failure (315 patients [14.5%]) included conversion to open procedure (25 [7.9%]), subtotal cholecystectomy (59 [18.7%]), intraoperative complications (40 [12.7%]), postoperative complications (Clavien-Dindo classification ≥2; 92 [29.2%]), postoperative imaging (182 [57.8%]), postoperative intervention (57 [18.1%]), prolonged length of stay (&gt;2 days; 142 [45.1%]), readmission (130 [41.3%]), and mortality (1 [0.3%]). Variables associated with TO failure included increasing American Society of Anesthesiologists score (odds ratio [OR], 2.55 [95 CI, 1.69-3.85]; P &lt; .001), increasing number of prior biliary-related admissions (OR, 2.68 [95% CI, 1.36-5.27]; P = .004), acute cholecystitis (OR, 1.42 [95% CI, 1.08-1.85]; P = .01), preoperative endoscopic retrograde cholangiopancreatography (OR, 2.07 [95% CI, 1.46-2.92]; P &lt; .001), and preoperative cholecystostomy (OR, 3.22 [95% CI, 1.54-6.76]; P = .002).Conclusions and RelevanceThese findings suggest that applying the concept of TO to elective LC provides a benchmark to identify suboptimal patterns of care and enables institutions to identify strategies for quality improvement.
Network‐Nanostructured ZIF‐8 to Enable Percolation for Enhanced Gas Transport
Authors: Lee Hyunhee , Chi Won Seok , Lee Moon Joo , Zhang Ke , Edhaim Fatima , Mizrahi Rodriguez Katherine , DeWitt Stephen J. A. , Smith Zachary P. 
Published: September 2022

AbstractMembrane‐based separations offer energy‐efficient solutions for various applications, but commercial polymer membranes show limited performance and stability. Mixed‐matrix membranes (MMMs), incorporating nanoporous inorganic materials in polymer matrices, have been of great interest to circumvent these polymer‐specific issues. However, reaching the percolation threshold is crucial to leverage high‐performing inorganic phases fully, yet the traditional sphere‐like nanofillers require high loadings that easily result in agglomerations and non‐selective defects. Here, a branch‐shaped zeolitic imidazole framework‐8 (ZIF‐8) nanoparticle is synthesized where its unique morphology automatically interconnects, readily forming percolated networks within the polymer matrix at loadings as low as 20 wt.%. Because of the high surface‐area‐to‐volume ratios of branched ZIF‐8 (BZ), strong polymer–particle interactions suppress polymer chain dynamics and the rotation of the ZIF‐8 ligand. This interphase confinement results in enhanced membrane stability and a smaller diffusion cut‐off than traditional ZIF‐8. With pre‐connected diffusion pathways and confined ZIF pores, BZ MMMs significantly outperformed MMMs with sphere‐like ZIF‐8 for H2‐based separations. Overall, the findings provide a novel approach to enhance filler effects in MMMs even at low loadings without any alignment, which can enable the development of advanced membranes in fields where percolation is desired, including separations, sensors, conductors, and batteries.
Unique Role of GeO2 as a Noninvasive Promoter of Nano‐Sized Zeolite Crystals
Authors: Parmar Deependra , Mallette Adam J. , Yang Taimin , Zou Xiaodong , Rimer Jeffrey D. 
Published: September 2022

AbstractThe synthesis of zeolites with nano‐sized dimensions is often limited to a narrow design space that conventionally relies upon the design of organics to direct hierarchical materials. Here, it is demonstrated that the addition of an inorganic modifier, germanium oxide (GeO2), to a zeolite growth mixture directs the formation of crystals with ultrasmall dimensions. This effect is observed for zeolites ZSM‐11 and ZSM‐5 over a range of synthesis conditions wherein the role of GeO2 in zeolite crystallization deviates from its typical function as a heteroatom. Notably, the final products contain trace amounts of Ge, which indicates the inorganic modifier does not compete for sites in the zeolite framework based on its formation of a discrete phase that enables GeO2 recovery. Catalytic tests using the methanol‐to‐hydrocarbons reaction reveal significant enhancement in the performance of zeolite catalysts prepared with GeO2 compared to reported examples of nano‐sized zeolites. These findings highlight a potentially generalizable and commercially viable synthesis method to reduce mass‐transport limitations in zeolites for diverse applications.
Adverse heat‐health outcomes and critical environmental limits (Pennsylvania State University Human Environmental Age Thresholds project)
Authors: Wolf S. Tony , Vecellio Daniel J. , Kenney W. Larry 
Published: September 2022

AbstractBackgroundThe earth's climate is warming and the frequency, duration, and severity of heat waves are increasing. Meanwhile, the world's population is rapidly aging. Epidemiological data demonstrate exponentially greater increases in morbidity and mortality during heat waves in adults ≥65 years. Laboratory data substantiate the mechanistic underpinnings of age‐associated differences in thermoregulatory function. However, the specific combinations of environmental conditions (i.e., ambient temperature and absolute/relative humidity) above which older adults are at increased risk of heat‐related morbidity and mortality are less clear.MethodsThis review was conducted to (1) examine the recent (past 3 years) literature regarding heat‐related morbidity and mortality in the elderly and discuss projections of future heat‐related morbidity and mortality based on climate model data, and (2) detail the background and unique methodology of our ongoing laboratory‐based projects aimed toward identifying the specific environmental conditions that result in elevated risk of heat illness in older adults, and the implications of using the data toward the development of evidence‐based safety interventions in a continually‐warming climate (PSU HEAT; Human Environmental Age Thresholds).ResultsThe recent literature demonstrates that extreme heat continues to be increasingly detrimental to the health of the elderly and that this is apparent across the world, although the specific environmental conditions above which older adults are at increased risk of heat‐related morbidity and mortality remain unclear.ConclusionCharacterizing the environmental conditions above which risk of heat‐related illnesses increase remains critical to enact policy decisions and mitigation efforts to protect vulnerable people during extreme heat events.
Identifying factors for poorer educational outcomes that may be exacerbated by COVID‐19: A systematic review focussing on at‐risk school children and adolescents
Authors: Coles Laetitia , Johnstone Melissa , Pattinson Cassandra , Thorpe Karen , Van Halen Olivia , Zheng Zhaoxi , Bayliss Olivia , Lakeman Nicole , Western Mark , Povey Jenny , Staton Sally 
Published: September 2022

AbstractSchool closures across Australia in response to COVID‐19 have persisted since 2020, with rising mental health problems in children and adolescents, alongside rising negative family health and socioeconomic outcomes. Further, some children and young people who were already experiencing disadvantage pre‐pandemic may be at heightened risk of poorer educational outcomes. Therefore, the aim of this study was to conduct a systematic review of the literature to identify the factors for poorer educational outcomes that may be exacerbated by COVID‐19 amongst disadvantaged school students. Key development stages of disadvantage were identified: young children who started school behind, older students already at risk of disengagement from school and children and young people who have had contact with the child protection system. Five databases were systematically searched, across two search periods. A total of 69 Australian, peer‐reviewed articles, published in 2005–2021, examining risk factors for poor educational outcomes for children attending school met the inclusion criteria and were included in final analyses. Our findings provide evidence of key risk factors that make these populations susceptible to worsening outcomes resulting from the COVID‐19 pandemic, and of the critical importance of ongoing research to guide policy and practice support for these at‐risk groups.
Cysteine‐Assisted Click‐Chemistry for Proximity‐Driven, Site‐Specific Acetylation of Histones
Authors: Afonso Cláudia F. , Marques Marta C. , António João P. M. , Cordeiro Carlos , Gois Pedro M. P. , Cal Pedro M. S. D. , Bernardes Gonçalo J. L. 
Published: September 2022

AbstractPost‐translational modifications of histones are essential in the regulation of chromatin structure and function. Among these modifications, lysine acetylation is one of the most established. Earlier studies relied on the use of chromatin containing heterogeneous mixtures of histones acetylated at multiple sites. Differentiating the individual contribution of single acetylation events towards chromatin regulation is thus of great relevance. However, it is difficult to access homogeneous samples of histones, with a single acetylation, in sufficient quantities for such studies. By engineering histone H3 with a cysteine in proximity of the lysine of interest, we demonstrate that conjugation with maleimide‐DBCO followed by a strain‐promoted alkyne‐azide cycloaddition reaction results in the acetylation of a single lysine in a controlled, site‐specific manner. The chemical precision offered by our click‐to‐acetylate approach will facilitate access to and the study of acetylated histones.
Perfekt Isotaktisches Polypropylen nach In Situ Aktivierung von Ultrarigiden meso Hafnocenen
Authors: Stieglitz Lucas , Lenz Tim M. , Saurwein Andreas , Rieger Bernhard 
Published: September 2022

AbstractFür über 40 Jahre basierte die Synthese von racemischen C2‐symmetrischen indenyl‐Metallocenen für die isospezifische Polymerisation von Propylen auf einer sehr aufwändigen Trennung der beiden hergestellten rac und meso Isomere. Bis heute gelten letztere als unerwünscht, da sie ataktisches Polypropylen (aPP) anstatt isotaktischem Polypropylen (iPP) produzieren, wenn sie mit Methylaluminoxan (MAO) aktiviert werden. Überraschenderweise lieferte die in situ Aktivierung des meso Hafnocens I perfekt isotaktisches Polypropylen. Über Kernspinresonanzspektroskopie (NMR) konnten wir eine Isomerisierung der meso Verbindung zur entsprechenden rac Verbindung nach Zugabe von Triisobutylaluminum (TIBA) nachweisen und ein praktisches Polymerisationsprotokoll etablieren, welches vergleichbare Produktivitäten für reines meso‐I und Isomerengemische verglichen mit reinem rac‐I lieferte. Durch dieses Isomerisierungsprotokoll wurde die potentielle Ausbeute an iPP um mehr als 400 % gesteigert. Es wurde gezeigt, dass dieses Protokoll auf weitere meso Verbindungen anwendbar ist und erste mechanistische Einblicke wurden erhalten.
The synergy between nucleotide biosynthesis inhibitors and antiviral nucleosides: New opportunities against viral infections?
Authors: de Mariz e Miranda Leandro S. 
Published: September 2022

Abstract5ʹ‐Phosphorylated nucleoside derivatives are molecules that can be found in all living organisms and viruses. Over the last century, the development of structural analogs that could disrupt the transcription and translation of genetic information culminated in the development of clinically relevant anticancer and antiviral drugs. However, clinically effective broad‐spectrum antiviral compounds or treatments are lacking. This viewpoint proposes that molecules that inhibit nucleotide biosynthesis may sensitize virus‐infected cells toward direct‐acting antiviral nucleosides. Such potentially synergistic combinations might allow the repurposing of drugs, leading to the development of new combination therapies.