Age and Petrogenesis of Ultramafic Lamprophyres of the Arbarastakh Alkaline-Carbonatite Complex, Aldan-Stanovoy Shield, South of Siberian Craton (Russia): Evidence for Ultramafic Lamprophyre-Carbonatite Link
Authors: Doroshkevich Anna , Prokopyev Ilya , Kruk Mikhail , Sharygin Viktor , Izbrodin Ivan , Starikova Anastasiya , Ponomarchuk Anton , Izokh Andrey , Nugumanova Yazgul 
Published: July 2022

Abstract
In this study, we discuss mineral chemistry data, melt inclusion study results, and report Ar–Ar phlogopite age for the aillikite dikes of the Arbarastakh alkaline-carbonatite complex on the Aldan-Stanovoy shield, Russia. Aillikite was crystallized at 631 ± 8.5 Ma, coeval with the intrusion age of the Arbarastakh rocks. The Arbarastakh complex was formed during the late Neoproterozoic epoch of rare earth element-Nb ore-bearing alkaline-carbonatite magmatic activity that was widespread on the southwestern and southern margins of the Siberian craton, related to rifting processes during the breakup of the supercontinent Rodinia. The aillikites show mineralogical characteristics of primitive magmas such as highly forsteritic olivine, Mg-ilmenite, and Cr-rich spinel. The variance in olivine zonation, morphologies, and chemical element distribution indicate that olivine in the aillikites is represented by several genetic types: xenogenic olivines (Fe-poor cores) from the sheared peridotite, olivine antecrysts (Fe-rich cores) related to mantle metasomatism by preceding proto-aillikite melt, and olivine phenocrysts formed during crystallization of aillikite melt. The latter shows decreasing Ni and Cr due to fractional crystallization of olivine, ilmenite, and chromite, along with increasing Mn and Ca concentrations that are consistent with enrichment of these elements in the residual melt. The olivine phenocrysts chemistry shows variations that are characteristic of the presence of phlogopite and carbonate in the mantle source (low 100*Ca/Fe (0.4–1.2) and 100*Mn/Fe (1–2), moderate 100*Ni/Mg (1.4–0.4)). Spinel shows a wide compositional variation with two compositional zoning trends, one of which follows the titanomagnetite trend, while the other follows the qandilite-rich magnesio-ulvöspinel-magnetite one. The latter trend indicates an increase in fO2 and attendant Fe oxidation to Fe3+ during crystallization. Ilmenite composition evolution (from Mg-rich to Mn-rich) also reflects the carbonate-rich nature of aillikite melt. We identify primary melt inclusions hosted in phlogopite and secondary melt inclusions in olivine; both melt inclusions types have daughter minerals dominated by dolomite, calcite, Na-Ca carbonates, phosphates, and phlogopite, consistent with the carbonate-rich nature of aillikite melt. The calculated temperatures reflect the early stage of aillikite crystallization, with values ranging from 1169 to 1296°C and fO2 values (olivine-spinel pair) varying from +0.40 to +1.03 ΔFMQ and from ΔNNO −0.9 to ΔNNO −2.0 (perovskite oxygen barometer); in contrast, the homogenization temperature of the secondary melt inclusions in olivine (700–720°C) characterizes late-stage aillikite melt evolution. The carbonate-rich nature of the Arbarastakh aillikite and its similar age to the carbonatites are consistent with a genetic relationship between them.