bluuebunny/crossref_metadata_2025_split huggingface dataset:
A Bite of the Forbidden Fruit: The Abject of Food and Affirmative Environmental Ethics
Authors: Sauka Anne 
Published: April 2022

Abstract
This article explores the negative framing of environmental concern in the context of food procurement and consumption, through the lens of the myth of Eden considering the ontological and genealogical aspects of the experienced exile from nature. The article first considers the theoretical context of the negative framing of food ethics. Demonstrating the consequences of the experience of food as abject, the article then goes on to discuss the exile from Eden as an explanatory myth for the perceptual inbetweenness of humankind. The aim of the article is to outline the genealogical markers of the negative framing of food ethics via the discussion of the exile from Eden. In the context of a new materialist understanding of the nature–culture continuum, the article depicts the exile as a perceptual rather than ontological divide that does not reflect a factual human inbetweenness but mirrors the objectification of nature by stripping the flesh of its spirit. Such reenvisioning is thought to be a pivotal aspect for mitigating the affectual abjectivity of food and recapturing the factual entanglement of body–environment to enable affirmative environmental ethics.
Kant on the Status of Ideas and Principles of Reason
Authors: Gava Gabriele 
Published: April 2022

Abstract
In the Transcendental Dialectic of the first Critique, Kant famously claims that even if ideas and principles of reason cannot count as cognitions of objects, they can play a positive role when they are used “regulatively” with the aim of organizing our empirical cognitions. One issue is to understand what assuming “regulatively” means. What kind of attitude does this “assuming” imply? Another issue is to characterize the status of ideas and principles themselves. It is to this second issue that this article is dedicated. Some interpreters have suggested that ideas and principles that can be assumed regulatively consist of propositions that we know are false. Others have suggested that at least some regulative ideas, as for example the idea of the homogeneity of nature, consist of propositions that we know are true but are indeterminate. Still others argue that, in assuming regulative ideas and principles, we assume propositions that cannot be proved true, but are nonetheless possibly true. In this article, I reject the view that regulative ideas consist of true but indeterminate propositions. Moreover, I argue that it is wrong to presuppose that only one of the remaining two options can apply to Kant’s account of regulative ideas and principles. By contrast, I submit that while in some cases assuming regulative ideas and principles does involve assuming some propositions that we know are false, this is not true for all regulative ideas and principles. More specifically, assuming regulative ideas involves assuming false propositions when assuming them means assuming that a “totality of appearances” is given.
IUPAC specification for the FAIR management of spectroscopic data in chemistry (IUPAC FAIRSpec) – guiding principles
Authors: Hanson Robert M. , Jeannerat Damien , Archibald Mark , Bruno Ian J. , Chalk Stuart J. , Davies Antony N. , Lancashire Robert J. , Lang Jeffrey , Rzepa Henry S. 
Published: April 2022

Abstract
A set of guiding principles for the development of a standard for FAIR management of spectroscopic data are outlined and discussed. The principles form the basis for future recommendations of IUPAC Project 2019-031-1-024 specifying a detailed data model and metadata schema for describing the contents of an “IUPAC FAIRData Collection” and the organization of digital objects within that collection. Foremost among the recommendations will be a specification for an “IUPAC FAIRData Finding Aid” that describes the collection in such a way as to optimize the findability, accessibility, interoperability, and reusability of its contents. Results of an analysis of data provided by an American Chemical Society Publications pilot study are discussed in relation to potential workflows that might be used in implementing the “IUPAC FAIRSpec” standard based on these principles.
Reaction SPL – extension of a public document markup standard to chemical reactions
Authors: Schadow Gunther , Borodina Yulia V. , Delannée Victorien , Ihlenfeldt Wolf-Dietrich , Godfrey Alexander G. , Nicklaus Marc C. 
Published: April 2022

Abstract
There are numerous formats and data models for describing reaction-related data. However, each offers only a limited coverage of the multitude of information that can be of interest to a broad user base in the context of chemical reactions. Structured Product Labeling (SPL) is a robust yet fairly light public XML document standard. It uses a highly generic but usefully refinable data schema, which is, like a language, highly expressive. We are therefore presenting an extension of SPL to chemical reactions (“Reaction SPL”). This extension is designed to support chemical manufacturing processes, which include as a minimum the chemical reaction and the procedures and conditions to run it. We provide an overview of the SPL reaction specification structures followed by some examples of documents with reaction data: predicted single-step reactions, a two-step synthesis, an enzymatic reaction, an example how to represent a reaction center, a patent, and a fully annotated reaction with by-products. Special attention is given to a mechanism for atom-atom mapping of reactions as well as to the possibility to integrate Reaction SPL with laboratory automation equipment, in particular automated synthesis devices.
Theoretical insights into the reduction mechanism of neptunyl nitrate by hydrazine derivatives
Authors: Cheng Zhong-Ping , Li Xiao-Bo , Wu Qun-Yan , Chai Zhi-Fang , Shi Wei-Qun 
Published: April 2022

Abstract
In the advanced spent fuel cycle, the control and adjustment of neptunium valence state is greatly important for the highly efficient separation of neptunium. Hydrazine and its derivatives as salt-free reagents can selectively reduce Np(VI) to Np(V), but their reduction mechanisms are still unclear. We explored the reduction of [NpVIO2(H2O)2(NO3)2] by N2H4 and its two derivatives HOC2H4N2H3 and CHON2H3 using scalar relativistic density functional theory. The thermodynamic energy of the reactions [NpVIO2(H2O)2(NO3)2] with three reductants are sensitive to the substitution group, HOC2H4N2H3 enhances thermodynamic ability of the reaction and CHON2H3 shows contrary result. Both HOC2H4N2H3 and CHON2H3 have lower energy barrier compared to N2H4 based on the potential energy profiles (PEPs), which probably attributes to the intramolecular hydrogen bond of hydrazine derivatives. The nature of these redox reactions is that the hydrogen atom of reductants is gradually transferred to the axis oxygen atom of neptunyl, which accompanies the N–H bond dissociation and Oax–H bond formation. The reduction of Np(VI) with HOC2H4N2H3 is the most favorable reaction based on the thermodynamic and kinetic results. This work provides theoretical perspective into the reduction of Np(VI) to Np(V), which is beneficial to the development of more effective free-salt reductants for the separation of neptunium from uranium and plutonium in spent fuel reprocessing.
On the volatility of protactinium in chlorinating and brominating gas media
Authors: Gäggeler Heinz W. , Eichler Bernd , Jost Dieter T. , Eichler Robert 
Published: April 2022

Abstract
A multi-target recoil chamber technique was applied to study online chemical properties of protactinium in chlorinating and brominating gas media using 226Pa (T
1/2 = 1.8 min) decaying by alpha emission (74%) and β+/EC decay (26%). A 58 MeV proton beam passing 15 × 50 μg/cm2 thick 232Th targets enabled production of 226Pa formed in the reaction 232Th(p,7n). Isothermal gas chromatography in quartz columns allowed for the determination of adsorption enthalpies of oxohalides and pure halides of Pa5+ compounds. On the basis of empirical correlations, these adsorption enthalpies (ΔH0
ads) could be converted to sublimation enthalpies (ΔH0
subl). Resulting values for the assumed compounds PaCl5, PaOCl3, PaBr5, and PaOBr3 were 113 ± 15, 329 ± 16, 165 ± 5 and 235 ± 17 kJ/mol, respectively. These values are rather similar to known ΔH0
subl data for group-5 elements Nb, Ta and Db in support of the assumption that Pa is a pseudo-group 5 element.
How accurate are half-life data of long-lived radionuclides?
Authors: Heinitz Stephan , Kajan Ivan , Schumann Dorothea 
Published: April 2022

Abstract
We have consulted existing half-life data available in Nuclear Data Sheets for radionuclides with Z < 89 in the range between 30 and 108 years with emphasis on their uncertainty. Based on this dataset, we have highlighted the lack of reliable data by giving examples for nuclides relevant for astrophysical, environmental and nuclear research. It is shown that half-lives for a substantial number of nuclides require a re-determination since existing data are either based on one single measurement, are contradictory or are associated with uncertainties above 5%.
Selective actinide(III) separation using 2,6-bis[1-(propan-1-ol)-1,2,3-triazol-4-yl]pyridine (PyTri-Diol) in the innovative-SANEX process: laboratory scale counter current centrifugal contactor demonstration
Authors: Wilden Andreas , Schneider Dimitri , Paparigas Zaina , Henkes Maximilian , Kreft Fabian , Geist Andreas , Mossini Eros , Macerata Elena , Mariani Mario , Gullo Maria Chiara , Casnati Alessandro , Modolo Giuseppe 
Published: April 2022

Abstract
An innovative-SANEX process for the selective separation of the trivalent actinides americium and curium from a simulated PUREX raffinate solution was successfully demonstrated on the laboratory scale using a 16-stage 1 cm annular centrifugal contactor setup. The solvent was composed of 0.2 mol L−1
N,N,N′,N′-tetra-n-octyl-diglycolamide (TODGA) and 5% v/v 1-octanol in a kerosene diluent. Zr(IV) and Pd(II) co-extraction was prevented using trans-1,2-diaminocyclohexane-N,N,N′,N′-tetraacetic acid (CDTA) as a masking agent in the feed. The actinide(III) selective back-extraction was achieved using 2,6-bis[1-(propan-1-ol)-1,2,3-triazol-4-yl]pyridine (PyTri-Diol) in 0.45 mol L−1 HNO3 as a CHON alternative to the sulfur-containing stripping agent used in a previous version of the innovative-SANEX process. The new process described in this paper showed excellent performance for the recovery of An(III). An An(III) product with a quasi-quantitative recovery of americium and curium (≥99.9%) and very good separation from fission and activation products was obtained (decontamination factors ≥4000). Only a slight contamination with Zr and Ru was observed. This test demonstrates the successful use of molecules containing only carbon, hydrogen, oxygen, and nitrogen atoms (so-called CHON molecules) for the selective separation of An(III) from a simulated PUREX raffinate solution. By avoiding sulfur- or phosphorous-containing molecules, the generation of secondary radioactive waste during process operation can be reduced drastically.
Optimization of Laboratory Molding Techniques for Nordic Dry Deep Mixing
Authors: Hov Sølve , Falle Fredrik , Paniagua Priscilla 
Published: April 2022

Abstract
The dry deep mixing method is a widely used stabilization method in the Nordic countries to improve the strength and deformation properties of soft clays. In engineering practice, laboratory tests normally precede in situ stabilization; however, previous studies have shown considerable differences between field and laboratory stabilization. The type of laboratory molding technique will determine how representative the specimen is compared with field conditions. A key property is the amount of entrapped air in the stabilized clay, which is shown to be very low in field stabilization. This paper presents a study of two different Norwegian molding techniques, including different optimizations to reduce the amount of entrapped air. The specimens are tested for density and strength, and it is shown that the strength increases with increasing density of the stabilized clay. Consequently, there is an inverse relationship between the amount of entrapped air and the strength, showing the importance of reducing the amount of entrapped air in laboratory specimens as much as possible. It is also shown that the wet mixing method does not necessarily give the same strength development as dry deep mixing given the same water to binder ratio.
Neglected Monteggia fracture: a review
Authors: Zhang Rui , Wang Xiaoyu , Xu Jia , Kang Qinglin , Hamdy Reggie C 
Published: April 2022

Monteggia fracture is characterized by radial head dislocation combined with proximal ulnar fracture.
If not diagnosed at an early stage, these lesions can gradually lead to forearm deformities and dysfunction, finally resulting in neglected Monteggia fracture. When the radial head is not reduced, several deformities develop at the humeroradial joint, including cubitus valgus and osteoarthritis.
Adequate radiographs are crucial when the surgeons deal with forearm injuries.
At present, proximal ulnar osteotomy and open reduction of chronic radial head dislocation provides satisfactory functional outcomes because of anatomic alignment reconstruction.
Supplementary procedures, including transcapitellar pinning and repair or reconstruction of the annular ligament, which are performed in order to enhance stability of the humeroradial joint, should be thoroughly assessed based on joint rotational stability after reduction and on potential complications.
Sugerencias para escribir análisis de resultados, conclusiones y recomendaciones en tesis y trabajos de grado
Authors: Bermúdez Rubio Dagoberto , Cuenca Rivera Pablo Emilio , García Murillo Paulo Germán , Gutiérrez Gómez Gonzalo , Portela Ramírez Albert Johan 
Published: April 2022

Con base en la experiencia de los autores como asesores de trabajos de grado e investigación, se encontraron dificultades en los estudiantes o investigadores para redactar los resultados, conclusiones y recomendaciones en todo tipo de textos de investigación, aspectos importantes a la hora de escribir un informe final. En este escenario, se elaboró este artículo, cuyo objetivo se encuentra en el marco de la investigación cuantitativa. En este, se hacen sugerencias para escribir resultados, conclusiones y recomendaciones del trabajo de grado o investigación, con el fin de contribuir al proceso formativo de investigadores y estudiantes y mejorar la redacción de las secciones en las que se refleja, de forma integral, la totalidad de los componentes de toda investigación.
Ahora bien, con respecto a los resultados, estos se consideran el eje principal del documento final. A partir de estos, se presentan las conclusiones, es decir, los hallazgos, y se responde al problema planteado y a los objetivos. Por último, en las recomendaciones se evidencian los temas que, normalmente, van unidos a las conclusiones; que, en ocasiones, se confunden o se redactan sin determinar las diferencias.
How can the potential harms of loot boxes be minimised?: Proposals for understanding and addressing issues at a national level
Authors: Macey Joseph , Cantell Mikko , Tossavainen Tommi , Karjala Antti , Castrén Sari 
Published: April 2022

Abstract

Background and aims
Loot boxes are in-game items which distribute rewards to players via random-number generation; many games require players to make in-game payments to access their contents. The combination of financial outlay and random rewards has raised concern about similarities to gambling. This debate paper presents a series of themes identified by an inter-institutional working group in Finland, alongside suggested actions, and are presented with the intention of stimulating debate among stakeholders.

Methods
This work uses an exploratory research approach to gather data from a range of sources, including state-of-the-art reports from several fields and qualitative content analysis of invited presentations from a range of stakeholders, including affected individuals, practitioners, and field-specific experts.

Results and Discussion
Several significant themes emerged from the work and are presented alongside a series of proposed action points. Based on this preliminary exploration we propose a series of, non-exhaustive, actions for both primary and secondary prevention. Furthermore, the group identified the potential for responsible gaming practices to be adopted which would help to minimize the harm from overspending in gaming activities. Finally, we identified the need for further research in the field, for example the use of player data and both longitudinal and qualitative studies.

Conclusions
The emergent themes are discussed in relation to both the views of the presenters and existing research in the field and are intended to promote discussion concerning the viability of context-specific approaches to an issue of global reach and significance.
I. Dünya Savaşı’nda Osmanlı ve İngiliz Savaş Dergilerinin Propaganda Bağlamında Karşılaştırılması: “The War Illustrated” ve “Harp Mecmuası” Örneği
Authors: EŞİTTİ Şakir , IŞIK Mehmet 
Published: April 2022

İlk kitlesel savaş olan I. Dünya Savaşı’nda, kitle iletişim araçlarının propaganda amacıyla yoğun şekilde kullanıldığı görülmektedir. Savaş yılları boyunca basın sıkı bir denetim altında tutulmuş, bizzat devlet eliyle çıkarılan gazete ve dergilerle halka ve askerlere verilmek istenilen mesajlar doğrudan iletilmiştir. Bu dönemde çıkarılan “savaş dergileri” (war magazine) ya da “askeri dergiler” (military magazine), mesajların doğrudan hedef kitleye iletilmesi açısından önemli bir yere sahiptir. Mevcut literatürde Osmanlı Devleti’nin I. Dünya Savaşı yıllarında yaptığı propaganda faaliyetleriyle savaştığı ülkelerdeki propaganda faaliyetlerini karşılaştırarak inceleyen çalışmaların sayısının oldukça yetersiz olduğu gözlenmektedir. Bu çalışmanın temel amacı I. Dünya Savaşı yıllarında, dönemin süper gücü konumundaki Büyük Britanya’nın ve Osmanlı Devleti’nin askeri dergilerdeki propaganda faaliyetlerini propaganda teknikleri açısından karşılaştırmalı olarak incelemek, bu yolla dönemin iki karşıt devletinin propagandalarındaki benzerlik ve farklılıkları ortaya koymaktır. Bu doğrultuda çalışmada, I. Dünya Savaşı yılarında Büyük Britanya’da yayınlanan The War Illustrated dergisi ile Osmanlı Devleti’nde çıkarılan Harp Mecmuası dergisinin içerik ve söylemleri propaganda teknikleri açısından karşılaştırmalı olarak incelenmiştir. Yapılan analizler sonucunda The War Illustrated dergisinde Domenach’ın güçlü propagandanın beş temel kuralına uygun bir propaganda kampanyası yürütüldüğü Harp Mecmuası’nda ise bu kurallara yeterince uyulmadığı sonuçlarına ulaşılmıştır.
Financial independence and maternal mental health- A right balance
Authors: Shekhawat Kirti , Sharma Priyanka , Preksha Menaria  
Published: April 2022

The role and position of women in today’s time is changing rapidly. The idea of making career and becoming mother both goes hand in hand as at one side the biological clock is ticking and at the same time growth in career is also to be taken care. Because of financial independence women are capable of making their decisions more effectively and this leads to better Quality of life, Hardiness and Social Support. According to the survey done by Catalyst, Women in the Workforce – India (October 28, 2020), India’s population is rising with 800 million people by 2050. And with this increasing rate economy is also growing with high GDP and working age population. In the total working population men counts to 76% of the labour force whereas women involvement is just 20.3% of the women aged 15 and above.The study involves the analysis of relevant literature and available data to discuss the role of financial independence and Quality of life, Hardiness and Social Support. It focuses on the mentioned variables with regard to maternal mental health on working women.
Scientific concept development in early childhood through the lens of “over-development”
Authors: Hast Michael 
Published: April 2022

Conceptual development in the scientific domain begins early. This typically brings with it an “overthinking” in form of mis- and alternative conceptions. This study aims to examine more closely the emergence of scientific misconceptions by drawing on three other areas of early rule-based learning where overapplication of rules can be observed in early child development, namely overextension, over regularisation, and over imitation. Key similarities across the different domains of development showcase similar U-shaped trajectories but are seen as sophistication in children’s thought processes, evident through the extrapolation of rules. Age-related differences in when these trajectories emerge are considered, exploring how these developments do not necessarily occur in parallel but as a potential result of each other. Implications for educational practice are considered, given the observed interaction between linguistic and non-linguistic forms of overdevelopment. These focus particularly on the role of talk in formal and informal settings.

Keywords: Overconceptualisation; overextension; over regularisation; over imitation.
Popularization of physical activity in rural schools of Kazakhstan's Aktobe region
Authors: Vasic Bibigul , Zhiembaev Asan , Zeybel Viktor 
Published: April 2022

The transition to distance learning for students, remote work of adults, spending a long time at home, restrictions on communication with classmates, including sports, and a ban on traveling to the city, became the reasons for considering the possibilities of promoting physical activity in rural schools of Aktobe region. Against the background of these reasons, positive aspects should also be highlighted. This study aimed to consider the pedagogical possibilities of promoting physical activity in rural schools in the Aktobe region of Kazakhstan. Data were collected through observation from an experiment carried out with 30 schoolchildren and 3 physical education teachers. Data was also collected from previous studies. The research carried out in this area made it possible to determine the purpose of the publication – to consider the scientific and pedagogical possibilities of popularizing physical activity in small rural schools of the Aktobe region, RK.

Keywords: Integration; livelihoods; pandemic; physical activity; popularization.