bluuebunny/crossref_metadata_2025_split huggingface dataset:
Improving the system of legal regulation of service in the penal system
Authors: Брыков Д.А. , Моторова Н.В. 
Published: June 2022

В статье рассматриваются основные изменения в нормативно-правовой регламентации прохождения службы в уголовно-исполнительной системе, связанные с принятием Федерального закона от 19.07.2018 № 197-ФЗ «О службе в уголовно-исполнительной системе Российской Федерации и о внесении изменений в Закон Российской Федерации “Об учреждениях и органах, исполняющих уголовные наказания в виде лишения свободы”». В настоящее время требуется существенная нормотворческая работа по регламентации системы управления персоналом уголовно-исполнительной системы Российской Федерации, направленная на повышение эффективности кадровой деятельности. Значительная часть данной работы была проведена в 2018–2021 гг., однако остаются отдельные направления совершенствования, которые структурированно изложены в статье. Кроме того, предложен ряд мероприятий по изменению действующего законодательства в сфере управления персоналом уголовно-исполнительной системы. Данные изменения позволят унифицировать правовое положение сотрудников уголовно-исполнительной системы с другими категориями государственных служащих
The article discusses key changes in the normative-legal regulation of service in the penal enforcement system related to the adoption of Federal Law No. 197-FZ of July 19, 2018 “On service in the penal enforcement system of the Russian Federation and on amendments to the law of the Russian Federation ‘On institutions and bodies executing criminal penalties in the form of imprisonment’”. Currently, it is necessary to conduct significant regulatory work to regulate the personnel management system of the administrative and executive system of the Russian Federation, aimed at improving the efficiency of personnel activities. A significant part of this work was carried out in 2018–2021; however, there are still separate areas requiring improvement and presented in the article. In addition, the authors propose a number of measures to change the current legislation in the field of personnel management of the penal system. These changes will make it possible to unify the legal status of employees of the penal enforcement system with other categories of civil servants
Sources of the administrative law and process: issues of classification and correlation
Authors: Нагорных Р.В. 
Published: June 2022

В статье обосновываются выводы о том, что необходимость теоретического и практического разрешения проблем источников административного права и процесса напрямую связана с общими проблемами административно-правового регулирования и приобретает сегодня принципиальное значение. Отличительной особенностью источников норм административного права и процесса является фактическое многообразие публичных управленческих общественных отношений, образующих предмет административного права и административного процесса. В статье анализируются основные правовые формы, содержащие нормы административного права и иные административно-правовые средства, входящие в структуру административно-правового механизма регулирования публичных общественных отношений. Наряду с основной и общепризнанной формой источников современного административного права и административного процесса, которой являются нормативные правовые акты, в статье анализируются и иные менее изученные формы их источников: правовой обычай, правовая доктрина, принципы права, судебный прецедент и судебная практика, религиозные нормы
The necessity of theoretical and practical solution of the problems of administrative law sources and the process is directly related to general problems of administrative and legal regulation and is gaining fundamental importance today. A distinctive feature of the sources of administrative law and process norms is the actual diversity of public managerial relations that form the subject of administrative law and administrative process. The article analyzes key legal forms containing the norms of administrative law and other administrative and legal means included in the structure of the administrative and legal mechanism for regulating public relations. Along with the main and generally recognized form of sources of modern administrative law and administrative process, which are normative legal acts, the article describes legal custom, legal doctrine, principles of law, judicial precedent and judicial practice, religious norms
Unexpected efficient reactions of nitrogen nucleophiles with α,β-unsaturated nitriles / esters
Authors: Suryasaraswathi K  , Saravanan S  , Muthusubramanian S  
Published: June 2022

α,β-Unsaturated compounds containing aldehyde, ketone, nitrile and ester functional groups are versatile precursor for the synthesis of novel organic molecules. All these compounds undergo Michael addition of carbon and other nucleophiles at b-carbon atom of the a,b-unsaturated system. Different carbo- and hetero-cyclic compounds can be synthesized by varying the conditions of cyclisation of the Michael adducts. In this context, it is planned to synthesize pyrazole derivatives and diazepine derivatives by reacting a,b-unsaturated compounds with different Nitrogen nucleophiles such as, o-phenylenediamine etc. The present investigation reports the unexpected hydrogenation of C=C in a,b-unsaturated nitriles and the unexpected synthesis of azine derivatives from a,b-unsaturated nitrileand hydrazinium sulphate.
Synthesis, Characterization, and Biological Evaluation of Some 3d-Metal Complexes of Schiff Base Derived from Sulfonamide Drug
Authors: Latha R  , Umadevi M  
Published: June 2022

A sulfonamide based novel acyclic bidentate compartmental ligand E-4-(((1H-indol-3-yl)methylene)amino)-N-(pyridine-2-yl) benzenesulfonamide was prepared by condensation of Indole-3-carbaldehyde with sulphapyridine in equimolar ratio in ethanol. The reaction of metal chlorides (Mn(II), Co(II), and Cu(II) with the newly synthesised ligand in methanol results the formation of deep colored metal complexes with the formula [ML2]Cl2 (M=Mn, Co, and Cu). The free ligand and its metal complexes were characterized by elemental analyses, conductometric measurements, IR, UV-Vis,1H and 13CNMR and EI Mass spectrometric techniques. The physical measurements and FTIR spectral data showed that most of the complexes contain octahedrally coordinated to the central ion (II). The antibacterial activity of the ligand and its complexes was done by well diffusion method using DMSO as inert solvent and the test solution was diffused into the plate and affected the growth of the incubated microorganisms such as staphylococcus aureus, E.coli, Bacillus, Aspergillus niger. The values of zone ofinhibition were found out at 37 ºC for a period of 24 h. It has beenfound that all the complexes have higher activity than the free ligandand the standard.
Adsorption of crystal violet onto hibiscus Rosa Sinensis
Authors: Porselvi V. M  , Kumaresan S  
Published: June 2022

The removal of the textile dye, crystal violet (CV), from aqueous solutions was studied by adsorptionon Hibiscus rosa sinensis. Batch adsorption studies were conducted by varying the initial concentration of the adsorbate, adsorbent dosage, contact time, and pH. The effect of pH on adsorption of crystal violet ontoHibiscus rosa sinensis was studied at pH 4. The percentage removal of dye was measured as a function of both the concentration of the dye (10 - 30 ppm) and the temperature (303 – 323 K). The experimental data were fitted into the Freundlich and Langmuir adsorption isotherm equations. The values of their corresponding constants were determined. Thermodynamic parameters like free energy, enthalpy and entropy of the systems were calculated using Freundlich constant. The present study shows that nearly80% removal of crystal violet was observed and hence Hibiscus rosa sinensiswas found to be an efficient adsorbent for the removal of the basic dye crystal violet from aqueous solutions.
Presentación inusual de infección por SARS-CoV-2 simulando púrpura de Schönlein Henoch (vasculitis por inmunoglobulina A)
Authors: Sancilio Andrea , Graziano Ana , García Munitis Pablo , Bresso Paula , Bugalter Mariela , Delgado Paula 
Published: June 2022

La vasculitis por inmunoglobulina A, anteriormente llamada púrpura Schönlein Henoch (VIgA/PSH), es la vasculitis sistémica más frecuente en la infancia. El desencadenante más común es una infección previa del tracto respiratorio superior. Se caracteriza por púrpura palpable no trombocitopénica con artralgias y/o artritis, afectación gastrointestinal y compromiso renal.
SARS-CoV-2 es un virus ARN que causa la enfermedad COVID-19. Afecta frecuentemente el sistema respiratorio con presentaciones que varían desde una rinitis hasta condiciones severas como síndrome de distress respiratorio, shock séptico o síndrome de in amación multisistémica (multi-system in ammation syndrome, MIS).
Se describe el caso de un niño de 5 años de edad con clínica de VIgA/PSH como forma inicial de presentación y diagnóstico posterior de infección por SARS-CoV-2, derivado al hospital de mayor complejidad, con encefalopatía hipertensiva que presentó evolución favorable y restitución completa del cuadro clínico.
Frecuencia de infección por SARS-CoV-2 en asistentes a un congreso médico en la Ciudad Autónoma de Buenos Aires
Authors: Quintana Rosana , Isnardi Carolina , Brigante Alejandro , Pons-Estel Guillermo , Soriano Enrique R. , Citera Gustavo , Mysler Eduardo , Rosa Javier , Berbotto Guillermo , Bellomio Verónica , De la Vega María Celina 
Published: June 2022

Introducción: en el contexto de la pandemia por SARS-CoV-2, la Sociedad Argentina de Reumatología (SAR) organizó su congreso “híbrido” (presencial y virtual), en diciembre de 2021, en concordancia con la condición epidemiológica. El objetivo principal de este trabajo fue describir la frecuencia de nuevos casos de infección luego de asistir al Congreso y la opinión de los médicos sobre los aspectos de bioseguridad del evento, y como objetivo secundario, analizar las características de los asistentes durante la pandemia por SARS-CoV-2.
Materiales y métodos: estudio transversal a través de una encuesta online, autoadministrada y anónima. Se encuestaron a los concurrentes (médicos y no médicos) al Congreso (presencial o virtual). La primera encuesta fue al momento de la inscripción y la segunda luego de 14 días de culminado, solo para los médicos. Se realizó un análisis descriptivo de los resultados.
Resultados: 1.322 individuos se inscribieron al Congreso; 1.039 (98,9%) eran médicos. 1.051 (79,5%) completaron la primera encuesta y 501 (48,2%) contestaron la segunda. Mientras 428 (85,4%) asistieron presencialmente, la virtualidad la eligieron aquellos con más años de ejercicio (p=0,023), con comorbilidades (p=0,03) y quienes tuvieron una internación previa por SARS-CoV-2 (p=0,05). Del total, 1.028 (97,8%) estaban vacunados. El 84,6% tuvo una opinión favorable sobre la modalidad “híbrida”. Cinco (1,2%) presentaron síntomas de infección por SARS-CoV-2 y tres (0,7%) tuvieron confirmación diagnóstica.
Conclusiones: cinco personas registraron la infección sintomática después del evento. Las medidas de bioseguridad tomadas fueron las aconsejadas por el Ministerio de Salud de la Nación y la opinión de los médicos sobre las mismas fueron favorables.
Heterologous high dose SARS-CoV-2 mRNA vaccine booster may improve immune response in seronegative kidney transplant recipients
Authors: Tylicki Leszek , Biedunkiewicz Bogdan , Ślizień Zuzanna , Muchlado Marta , Dębska-Ślizień Alicja 
Published: June 2022

IntroductionThree-dose mRNA vaccination against COVID-19 is unable to elicit a sufficient immune response in immunocompromised subjects.Material and methodsThe aim of the study was to conduct a retrospective evaluation of the efficacy of a heterologous mRNA booster with mRNA-1273 in constantly seronegative kidney transplant recipients (KTRs) after three doses of the BNT162b2 mRNA vaccine. Twelve seronegative KTRs received a mRNA-1273 booster 5 months after the third dose of BNT162b2.ResultsA total of 5 out of 12 patients (41.7%) seroconverted, with a mean titer of 353 BAU/ml.ConclusionsThe administration of a heterologous mRNA vaccine as a booster may be an effective alternative for achieving post-vaccination immunity in seronegative KTRs.
The overall benefits of empagliflozin treatment in adult siblings with glycogen storage disease type Ib: one year experience
Authors: Bidiuk Joanna , Gaciong Zbigniew , Sobieraj Piotr 
Published: June 2022

IntroductionRecently published case reports suggest the benefit of empagliflozin use in subjects with glycogen storage disease Ib (GSD Ib).Material and methodsWe present the clinical and laboratory data of 2 adult brothers with GSD Ib treated with empagliflozin for 12 months.ResultsThere was no severe infection during administration of empagliflozin. The improvement of clinical symptoms of inflammatory bowel disease and arthritis along with reduction in serum CRP levels and urinary albumin excretion were noted. Neutrophil count increased allowing for reduction or temporary withdrawal of G-CSF treatment.ConclusionsEmpagliflozin may be new safe treatment in GSD Ib patients with advanced stage of the disease.
Quelques conséquences de la pandémie de Covid-19 sur la relation école-famille en contexte d’éducation prioritaire : le point de vue des enseignant-es du canton de Genève
Authors: Napoli Julia 
Published: June 2022

La crise de la Covid-19 a conduit à des mesures exceptionnelles pour freiner la pandémie, dont la fermeture des écoles. Cette période inédite a donné lieu à de nombreuses recherches pour en analyser l’impact et les enjeux. Nos propos s’inscrivent dans la continuité de ces études. Les résultats que nous présentons sont issus d’une recherche axée sur la mise en œuvre des politiques du réseau d’enseignement prioritaire (REP). Cette recherche, menée dans le canton de Genève de janvier à mars 2021, a consisté en 35 entretiens semi-directifs effectués auprès d’acteurs/trices impliqué-es dans la mise en œuvre de la politique au niveau de sept établissements scolaires : directeurs/trices, enseignant-es, éducateurs/trices, coordinateurs/trices pédagogiques. Nous avons choisi de mettre en avant la perception des enseignant-es sur l’impact de la fermeture des écoles pendant la pandémie en termes d’acquis des élèves et de la relation qu’ils ont entretenue avec les familles. Les résultats présentés dans cet article rejoignent les principales conclusions de la littérature : si une meilleure compréhension réciproque et des modes de communication innovants ont pu être observés entre l’école et les familles pendant la pandémie, la relation demeure asymétrique et la cause de l’échec est toujours imputée aux familles.
Les relations école-familles au défi de la Covid-19 à Genève : quelles pratiques pour quels effets sur les inégalités ?
Authors: Rienzo Stefanie 
Published: June 2022

Au sein de l’enseignement primaire genevois, les relations école-familles représentent aujourd’hui un des enjeux majeurs de la scolarité des enfants, étant considérées comme un moyen essentiel pour lutter contre l’échec et les inégalités scolaires. Cet article cherche à mieux comprendre comment les relations entre les enseignant-es et les parents se sont concrètement déroulées suite à l’annonce du premier confinement dû à la crise sanitaire de la Covid-19 et quels sont les effets de ces nouvelles pratiques collaboratives sur les inégalités scolaires. Pour cela, il s’appuie sur différentes données récoltées dans le cadre de notre recherche doctorale : des observations participantes en tant qu’enseignante d’août 2018 à juin 2020, des entretiens semi-directifs menés avec les enseignant-es, les différent-es intervenant-es scolaires, les parents et les enfants, et divers documents institutionnels. L’analyse des données met en évidence de nombreuses tensions et ambivalences au sein des pratiques enseignantes et du système scolaire lui-même, ayant pour effets la persistance et l’aggravation des inégalités scolaires. La crise de la Covid-19 montre ainsi la nécessité de repenser le rôle de la collaboration entre les enseignant-es et les parents, tout comme celui de l’école dans son entièreté.
Resiliensi Akademik Siswa Sekolah Menengah Pertama dalam Mengikuti Pembelajaran Tatap Muka Terbatas (TMT) di Daerah Khusus Ibukota (DKI) Jakarta
Authors: Faturrohmah Afi , Sagita Dony Darma 
Published: June 2022

This study aims to identify the level of academic resilience of junior high school students (First Secondary School) during the period of Pembelajaran Tatap Muka Terbatas (Limited Face-to-Face Learning) during the Covid-19 pandemic. The type of research using quantitative descriptive design with the population used is Muhammadiyah Junior High School 2 Jakarta (n=379). The sampling technique uses Convention sampling. This study used a questionnaire adapted from the Indonesian version of The Academic Resilience Scale-30 (ARS-30) with a lycert scale. The data obtained will be analyzed using categorization tests through the IBM SPSS Statistics 26 and Microsoft Excel applications. The results of the study showed that 311 students (82.1%) had a high academic resilience rate and 68 students (17.9%) had a moderate resilience rate determined through measuring academic resilience dimensions (1) Perseverance or persistence, (2) Reflecting and Adaptive Help Seeking, (c) Negatif Affect and Emotional Response. Therefore it can be inferred that the academic resilience rate of junior high school students in the Pembelajaran Tatap Muka Terbatas period has a relatively high category.
Pendampingan Kegiatan Belajar Siswa dengan Memanfaatkan Barang Bekas untuk Meningkatkan Minat dan Kreativitas Belajar Siswa pada Era Covid-19
Authors: Jannah Nur Roikhatul , Pratiwi Wiwied 
Published: June 2022

The article gave learning assistance by students’ utilizing waste to increase students' interest and creativity. This research used ABCD (Asset Based Community Development) method. Five steeps to conduct this research; discovery, dream, design, define, and destiny. As for this research method including: preparation stage consisting of observation, interview to parents of students, delivery of strategies, and material extension, implementation stage consisting of socialist implementation of activities initiated by approach and mentoring students, evaluation stage of assessment of activities that have been carried out. The results activities showed that the students learning assistance against corona virus and utilizing used goods as a place to wash hands, mentoring students in utilizing waste to make product handicrafts, and mentoring students in utilizing waste as a learning medium.
Keywords: Utilizing Waste, Assistance Learning Activity, Creativity in Covid-19 Era
Community Service of Strengthening Financial Management of Micro Small Medium Enterprises (UMKM) in Pandemic Covid-19
Authors: Effendi Bahtiar , Kurniawan Kurniawan , Setiawati Lulu 
Published: June 2022

The article provides financial management learning assistance to improve the financial management capabilities of Small and Medium Enterprises. This research uses Asset Based Community (ABCD) that utilize the potential asset of community, either social or infrastructure. Three activities in analyzing the research; introduction, mentoring and evaluation. As for this research method includes: the preparation stage which consists of observation, interviews with village heads, delivery of materials, and material counseling, implementation stage consists of the implementation of seminar activities initiated by the approach and assistance to business actors, the evaluation stage of the evaluation of activities that have been carried out have been done. The results of the activity showed that the ability of the learning mentoring participants increased after this community service activity.
Keywords: Community Service Management, Micro Small Medium Enterprises, Financial Management
Strengthening Chemistry Teachers' Technological Pedagogical Content Knowledge through the Introduction of Augmented Reality and Learning Management Systems
Authors: Imaduddin Muhamad , Astuti Andari Puji 
Published: June 2022

Strengthening of Technological Pedagogical Content Knowledge (TPACK) needs to be done as an effort to present chemistry learning that is following the times. The purpose of this activity is to identify the TPACK conditions of chemistry teachers, as well as to seek initial activities to strengthen teachers’ TPACK through the introduction of augmented reality technology according to chemical content, as well as classroom management based on a learning management system platform. The implementation method included Focus Group Discussion (FGD) activities, lectures, and implementation practices. Participants in this activity consisted of chemistry teachers who were active members of the Chemistry Teacher Groups of Kudus Regency, as many as 17 teachers. This community service activity is in the form of a series of activities that include (1) identification of difficult chemistry materials, most of which show microscopic concepts as one of the difficult materials, (2) identification of the condition of the teacher's level of mastery of technology which is generally still at a moderate level, (3) introduce the potential use of technology in the chemistry learning process in the form of Augmented Reality, namely RAppChemistry, and (4) the use of a learning management system in the form of the Google Classroom platform that can be used in electronic-based teaching and learning processes. Further partnerships need to be implemented to implement the technology on a classroom scale. Activities that may be carried out are lesson study activities to optimize the integration of technology in chemistry learning.
Keywords: Pedagogical Content Knowledge, Augmented Reality, Learning Management System