bluuebunny/crossref_metadata_2025_split huggingface dataset:
Family, nurse, and physician beliefs on family‐centered rounds: A 21‐site study
Authors: Patel Shilpa J. , Khan Alisa , Bass Ellen J. , Graham Dionne , Baird Jennifer , Anderson Michele , Calaman Sharon , Cray Sharon , Destino Lauren , Fegley April , Goldstein Jenna , Johnson Tyler , Kocolas Irene , Lewis Kheyandra D. , Liss Isabella , Markle Peggy , O'Toole Jennifer K. , Rosenbluth Glenn , Srivastava Raj , Vara Tiffany , Landrigan Christopher P. , Spector Nancy D. , Knighton Andrew J. 
Published: September 2022

AbstractBackgroundVariation exists in family‐centered rounds (FCR).ObjectiveWe sought to understand patient/family and clinician FCR beliefs/attitudes and practices to support implementation efforts.Designs, Settings and ParticipantsPatients/families and clinicians at 21 geographically diverse US community/academic pediatric teaching hospitals participated in a prospective cohort dissemination and implementation study.InterventionWe inquired about rounding beliefs/attitudes, practices, and demographics using a 26‐question survey coproduced with family/nurse/attending‐physician collaborators, informed by prior research and the Consolidated Framework for Implementation Research.Main Outcome and MeasuresOut of 2578 individuals, 1647 (64%) responded to the survey; of these, 1313 respondents participated in FCR and were included in analyses (616 patients/families, 243 nurses, 285 resident physicians, and 169 attending physicians). Beliefs/attitudes regarding the importance of FCR elements varied by role, with resident physicians rating the importance of several FCR elements lower than others. For example, on adjusted multivariable analysis, attending physicians (odds ratio [OR] 3.0, 95% confidence interval [95% CI] 1.2–7.8) and nurses (OR 3.1, 95% CI 1.3–7.4) were much more likely than resident physicians to report family participation on rounds as very/extremely important. Clinician support for key FCR elements was higher than self‐reported practice (e.g., 88% believed family participation was important on rounds; 68% reported it often/always occurred). In practice, key elements of FCR were reported to often/always occur only 23%–70% of the time.ResultSupport for nurse and family participation in FCR is high among clinicians but varies by role. Physicians, particularly resident physicians, endorse several FCR elements as less important than nurses and patients/families. The gap between attitudes and practice and between clinician types suggests that attitudinal, structural, and cultural barriers impede FCR.
Do private translation mechanisms encourage food safety in dairy production? Evidence from the Brazilian Conseleites
Authors: de Oliveira Gustavo Magalhães , Schnaider Paula Sarita Bigio , Saes Maria Sylvia Macchione , Martino Gaetano 
Published: September 2022

AbstractThis study investigates how and why the translation role of private meso‐institutions can help in the implementation of food safety norms in Brazilian dairy supply chains. Relying on a unique dataset containing producer‐level data, we combine a difference‐in‐differences approach with matching to investigate the experience of the Brazilian Conseleites. Our results indicate that milk quality levels tend to be higher in the states where Conseleites operate, suggesting a reduction in the cost of obtaining and disseminating information, and potentially, of transaction costs in a more general way.
Coding metasurface for diffusion‐like scattering in multiple directions based on Pancharatnam–Berry phase
Authors: Feng Maochang , Li Xuejian , Chen Xiaoli , Liu Zhewei , Li Yongfeng , Zhang Jieqiu , Zheng Qiqi , Wang Jiafu , Ma Hua , Qu Shaobo 
Published: September 2022

AbstractDiffusion‐like scattering along multiple directions based on coding metasurface (CM) is proposed for both mono‐static and bi‐static radar cross section (RCS) reduction in this work. Different from the previous CMs achieving diffusion‐like scattering only in one direction, the proposed CMs can realize diffusion‐like scattering along multiple directions via designing the phase spatial distributions of the consisted coding elements. The multiple diffusion‐like scattering CMs were designed by using the co‐polarization reflection resonators under circularly polarized wave incidence based on Pancharatnam–Berry (PB) phase. By elaborately arranging the phase spatial distribution of coding elements, two, three, and four beams of diffusion‐like scattering were realized. The bi‐static RCS reduction was improved with increasing number of the backward diffusion‐like scattering beams. The measured results agree well with the simulations, and both demonstrated the excellent performance on mono‐static and bi‐static RCS reduction. Our strategy can help realize stealth applications under bi‐static detections.
Development of novel reversible thermometer from N‐isopropylacrylamide and dicyanodihydrofuran hydrazone probe
Authors: Snari Razan M. , Al‐Qahtani Salhah D. , Aldawsari Afrah M. , Alnoman Rua B. , Ibarhiam Saham F. , Alaysuy Omaymah , Shaaban Fathy , El‐Metwaly Nashwa M. 
Published: September 2022

AbstractA simple‐structured polymeric colorimetric thermometer with selective colorimetric changes over a specific temperature range was developed. Thermo‐responsive poly(N‐isopropylacrylamide‐co‐Dicyanodihydrofuran hydrazone) [Poly(NIPAM‐co‐DCDHFH)] organogel imprinted with DCDHFH chromophoric probe was prepared via free radical polymerization. The DCDHFH chromophore bearing a vinyl group was prepared by azo‐coupling of DCDHF with a diazonium salt of 2‐amino‐5‐nitrophenol bearing a vinyl substituent. The poly(NIPAM‐co‐DCDHFH) consists of DCDHFH chromophore and N‐isopropylacrylamide (NIPAM) monomers. The chemical structure of DCDHFH probe was verified by 1H NMR and FT‐IR. The thermochromic property can be attributed to a heat‐stimulated polymer self‐assembly process controlling the inner hydrophobicity leading to charge delocalization on the molecular system of the DCDHFH chromophore. Poly(NIPAM‐co‐DCDHFH) functioned as a thermochromic detector displaying colorful shifts between yellow (422 nm) and blue (580 nm) with raising the temperature of the aqueous poly(NIPAM‐co‐DCDHFH). These color shifts were correlated to the temperature increment from 28 to 46°C owing to the phase changes of the poly(NIPAM‐co‐DCDHFH) copolymer in aqueous media. The morphological features of the organogel nanofibers were studied by transmission electron microscope (TEM) and scanning electron microscopy (SEM). The working mechanism accounting for the thermochromic performance of poly(NIPAM‐co‐DCDHFH) was explored. The cytotoxicity of the poly(NIPAM‐co‐DCDHFH) hydrogel was also evaluated. This is a significant study for a variety of potential applications, such as functional apparel and medicinal applications.
The shape of aroma: Measuring and modeling citrus oil gland distribution
Authors: Amézquita Erik J. , Quigley Michelle Y. , Ophelders Tim , Seymour Danelle , Munch Elizabeth , Chitwood Daniel H. 
Published: September 2022

Societal Impact StatementCitrus are intrinsically connected to human health and culture, preventing human diseases like scurvy and inspiring sacred rituals. Citrus fruits come in a stunning number of different sizes and shapes, ranging from small clementines to oversized pummelos, and fruits display a vast diversity of flavors and aromas. These qualities are key in both traditional and modern medicine and in the production of cleaning and perfume products. By quantifying and modeling overall fruit shape and oil gland distribution, we can gain further insight into citrus development and the impacts of domestication and improvement on multiple characteristics of the fruit.Summary

Citrus come in diverse sizes and shapes, and play a key role in world culture and economy. Citrus oil glands in particular contain essential oils which include plant secondary metabolites associated with flavor and aroma. Capturing and analyzing nuanced information behind the citrus fruit shape and its oil gland distribution provide a morphology‐driven path to further our insight into phenotype–genotype interactions.
We investigated the shape of citrus fruit of 51 accessions based on 3D X‐ray computed tomography (CT) scan reconstructions. Accessions include members of the three ancestral citrus species as well as related genera, and several interspecific hybrids. We digitally separate and compare the size of fruit endocarp, mesocarp, exocarp, and oil gland tissue. Based on the centers of the oil glands, overall fruit shape is approximated with an ellipsoid. Possible oil gland distributions on this ellipsoid surface are explored using directional statistics.
There is a strong allometry along fruit tissues; that is, we observe a strong linear relationship between the logarithmic volume of any pair of major tissues. This suggests that the relative growth of fruit tissues with respect to each other follows a power law. We also observe that on average, glands distance themselves from their nearest neighbor following a square root relationship, which suggests normal diffusion dynamics at play.
The observed allometry and square root models point to the existence of biophysical developmental constraints that govern novel relationships between fruit dimensions from both evolutionary and breeding perspectives. Understanding these biophysical interactions prompts an exciting research path on fruit development and breeding.
Year in review 2021: Neuromuscular diseases
Authors: Kelchtermans Jelte , Mayer Oscar H. 
Published: September 2022

AbstractIn this years' review of neuromuscular respiratory medicine, there were a series of articles on home mechanical ventilation, real‐world studies assessing the impact of nusinersen, and studies describing upper airway dysfunction. Beyond this, we highlight two excellent reviews regarding cardiac dysfunction in neuromuscular diseases.
Achieving the objectives of the 2030 sustainable development goals agenda: Causalities between economic growth, environmental sustainability, financial development, and renewable energy consumption
Authors: Guang‐Wen Zheng , Murshed Muntasir , Siddik Abu Bakkar , Alam Md Shabbir , Balsalobre‐Lorente Daniel , Mahmood Haider 
Published: September 2022

AbstractAs the global concerns regarding climate change and the related environmental adversities continue to persist alongside rapid development of the world economies, the United Nations declared a set of compressive sustainable development goals (SDG) that are to be realized by the end of 2030. These goals are specifically conceptualized to collectively facilitate the attainment of sustainable socioeconomic development while concurrently improving the quality of the global environment. Hence, this study assesses the interlinkages between economic growth, environmental pollution, financial development, and renewable energy use in light of the objectives of SDG8, SDG13, SDG10, and SDG7 by considering the BRICS nations as a case study. Although the previous studies, in this regard, have predominantly focused on specifically scrutinizing the determinants of these four macroeconomic variables of concern, not much importance was shown to map the interrelationships among these variables. The econometric analysis conducted in this study utilizes quarterly frequency data covering the period from 1990‐Q1 to 2020‐Q4. Overall, the findings from causality and variance decomposition analyses reveal that in the long run these variables are influenced by each other which, in turn, also verifies the cross‐linkages between the four SDG of concern. Besides, the causality‐related findings appear to be robust when alternate causality estimators are employed. Therefore, based on these critically important causal relationships, a set of interactive SDG‐related policies is recommended.
A Parchment‐Like Supercapacitor Made with Sustainable Graphene Electrodes and its Enhanced Capacitance by Incorporation of the LaSrCoO3 Perovskite
Authors: Garces Luis , Lopez‐Medina Margarita , Padmasree Karinjilottu Padmadas , Mtz‐Enriquez Arturo Isaias , Medina‐Velazquez Dulce Yolotzin , Flores‐Zuñiga Horacio , Oliva Jorge 
Published: September 2022

AbstractThis work reports the electrochemical properties of rollable supercapacitors (SCs) assembled with electrodes made of recycled soda label as supporting substrate, graphene (conductive material), TiNi alloy (negative collector) and copper foil (positive collector). The electrochemical properties of the SCs improved by adding the La0.5Sr0.5CoO3 (LSC) nanoparticles on their electrodes. Those nanoparticles have irregular morphology and sizes of 220–1800 nm. The SCs fabricated without LSC exhibited a gravimetric capacitance and energy density of 406.3 F g−1 and 56.5 Wh kg−1, respectively. When the LSC is added on the SC electrodes, the above values increase to 920.9 F g−1 and 127.1 Wh kg−1, that is, the capacitance was enhanced by ≈84 %. Another SC was fabricated using copper foil as negative collector instead of the TiNi alloy, but the capacitance and energy density were lowered to 135 F g−1 and 18.7 Wh kg−1, respectively. This result indicates that using the TiNi alloy as negative collector was important to produce higher capacitance. Surprisingly, the capacitance retention of the SC made with LSC increased to 133 % after 300 rolling cycles but it diminished to 78 % after 500 rolling cycles. The devices made with and without LSC exhibited output voltages of 1.25 V and 0.4 V, respectively. UV‐Vis absorbance, Raman and XPS spectra revealed the existence of oxygen vacancy defects and Co2+/Co3+ species on the SC electrodes, which worked as redox centers for the charge storage.
DNA‐Binding Studies of Ofloxacin Using a Series of Spectroscopic, Electrochemical Techniques and in Silico Approaches
Authors: Çeşme Mustafa , Özaltay Ayşe 
Published: September 2022

AbstractOfloxacin (OFL), a quinolone antibiotic, shows a bactericidal effect by inhibiting the DNA gyrase enzyme in bacteria. In addition to its use in various infections has a wide range of benefits from urinary system disorders to pneumonia and bronchitis. DNA is the main molecular target for many small molecules of therapeutic importance. In this article, the interaction between OFL and fsDNA (fish sperm DNA) is reported using a combination of biophysical (spectroscopic and electrochemical) and in silico techniques (molecular docking and molecular dynamics). The interaction and complex formation were studied using UV‐visible and steady‐state fluorescence spectroscopy. Ethidium bromide (EtBr), Rhodamine B (RB) competitive displacement, potassium iodide quenching, and ionic strength assays confirmed the binding mode between OFL and DNA via minor groove binding. Thermodynamic parameters at various temperatures supported the enthalpically driven, exothermic, and spontaneous reaction between OFL and fsDNA. It was found that hydrogen bond interaction and van der Waals forces play a dominant role in forming the complex form. DNA melting experiments corroborated these findings. In‐silico molecular docking and molecular dynamics simulation studies revealed the interaction mode, major stabilizing forces, and the nucleotide sequences OFL binds and dock into the GC‐rich region of the DNA minor groove, confirming the in vitro experiment results.
A Simple Environmentally Friendly Method for the Synthesis of Hydroxyisoxazolidine Derivatives
Authors: Drosik Olga Kinga , Korytkowska‐Wałach Anna , Szczepankiewicz Wojciech , Suwiński Jerzy Wiktor 
Published: September 2022

AbstractA series of 5‐hydroxyisoxazolidines has been successfully synthesized through tris(hydroxymethyl)aminomethane (TRIS) buffered hydroxylamine hydrochloride and α, β‐ unsaturated ketones reaction. This synthetic approach can be considered as environmentally friendly because of the use of non‐toxic and non‐hazardous reagents at room temperature. The reaction is also metal‐free and generates minimum non‐toxic waste. The structure of 5‐hydroxyisoxazolidines was confirmed not only by extended NMR analysis but by a series of elimination and acetylation reactions. Hydroisoxazolidines are obtained as a mixture of diastereomers (cis‐, trans‐ and N‐invertomers). Usually, three sets of 1HNMR signals are observed for that class of compound (especially for protons H3 and both H4). The analysis of cis‐ and trans‐isomerization of the product 2 b has been conducted.
Regulation of Structure and Magnetic Properties for Nickel(II)/Cobalt(II) Coordination Polymers with 1,4‐Bis(imidazole‐1‐ylmethyl)benzene Ligand
Authors: Wang Yanhong , Gong Duming , Lu Hongcheng 
Published: September 2022

AbstractTwo new coordination polymers Ni(bix)3 ⋅ 2(NO3) ⋅ (H2O) 1 and Co(bix)2 ⋅ 2(NO3) 2 (bix=1,4‐bis(imidazole‐1‐ylmethyl)benzene) have successfully been synthesized via hydrothermal reactions. These two compounds have similar local coordination environments but different topological networks due to the flexibility of the bix ligand. Additionally, magnetic studies reveal that 1 and 2 also exhibit different magnetic behaviors. Although magnetic exchange pathways are same as MII‐bix‐MII (M=Ni 1, Co 2), 1 shows purely paramagnetic state almost down to 2 K with weak antiferromagnetic interaction; while stronger antiferromagnetic interaction in 2 is suggested. Meanwhile, an anomaly around 38 K in zero‐field‐cooled mode is observed but suppressed in field‐cooled mode, which may be suggesting the spin canting for 2. The field dependent magnetizations show magnetization of 2.17 μB and 2.44 μB at 7 T for 1 and 2, respectively. Also, the magnetic interaction J/kB of −3.3 K is estimated for 2.
Synthesis of Fluoroalkyl Cyclopentenes: Highly Diastereoselective Phosphine‐Catalyzed [3+2] Annulation of β‐Fluoroalkylvinyl Arylsulfones with Morita‐Baylis‐Hillman Carbonates
Authors: Xu Jiaqing , Hu Yimin , Liao Jianning , Du Juan , Wang Lei , Wang Wei , Wu Yongjun , Guo Hongchao 
Published: September 2022

AbstractA phosphine‐catalyzed [3+2] annulation of β‐fluoroalkylvinyl arylsulfones and Morita‐Baylis‐Hillman carbonates was achieved to generate tetrasubstituted cyclopentene carboxylates with a fluoroalkylated stereogenic center at C4. The substrates with various substituents provided the expected [3+2] products in generally excellent yields and diastereoselectivities. This transformation provides a simple and efficient method for the synthesis of fluoroalkyl‐substituted cyclopentene compounds.
Controlled Core/Crown Growth Enables Blue‐Emitting Colloidal Nanoplatelets with Efficient and Pure Photoluminescence
Authors: Hu An , Bai Peng , Zhu Yunke , Tang Zhenyu , Xiao Lixin , Gao Yunan 
Published: September 2022

AbstractColloidal semiconductor CdSe nanoplatelets (NPLs) feature ultranarrow and anisotropic emissions. However, the optical performance of blue‐emitting NPLs is deteriorated by trap states, currently exhibiting tainted emissions and inferior photoluminescence quantum yields (PLQYs). Here, near trap‐free blue‐emitting NPLs are achieved by the controlled growth of the core/crown. Deep trap states in NPLs can be partially suppressed with the asymmetrical crown growth and are further suppressed with the growth of the small core and the alloyed symmetrical crown, yielding NPLs with pure blue emissions and near‐unity PLQYs. Exciton dynamic research based on these NPLs indicates that the trap emission stems from surface traps. Besides, light‐emitting diodes exhibiting ultranarrow emission centered around 461 nm with full‐width‐at‐half‐maximums down to 11 nm are fabricated using these NPLs.
Recent Development of Moisture‐Enabled‐Electric Nanogenerators
Authors: Guan Peiyuan , Zhu Renbo , Hu Guangyu , Patterson Robert , Chen Fandi , Liu Chao , Zhang Shuo , Feng Ziheng , Jiang Yue , Wan Tao , Hu Long , Li Mengyao , Xu Zhemi , Xu Haolan , Han Zhaojun , Chu Dewei 
Published: September 2022

AbstractPower generation by converting energy from the ambient environment has been considered a promising strategy for developing decentralized electrification systems to complement the electricity supply for daily use. Wet gases, such as water evaporation or moisture in the atmosphere, can be utilized as a tremendous source of electricity by emerging power generation devices, that is, moisture‐enabled‐electric nanogenerators (MEENGs). As a promising technology, MEENGs provided a novel manner to generate electricity by harvesting energy from moisture, originating from the interactions between water molecules and hydrophilic functional groups. Though the remarkable progress of MEENGs has been achieved, a systematic review in this specific area is urgently needed to summarize previous works and provide sharp points to further develop low‐cost and high‐performing MEENGs through overcoming current limitations. Herein, the working mechanisms of MEENGs reported so far are comprehensively compared. Subsequently, a systematic summary of the materials selection and fabrication methods for currently reported MEENG construction is presented. Then, the improvement strategies and development directions of MEENG are provided. At last, the demonstrations of the applications assembled with MEENGs are extracted. This work aims to pave the way for the further MEENGs to break through the performance limitations and promote the popularization of future micron electronic self‐powered equipment.
Abstract Monitors for Quantitative Specifications
Authors: Henzinger Thomas A. , Mazzocchi Nicolas , Saraç N. Ege 
Published: September 2022

AbstractQuantitative monitoring can be universal and approximate: For every finite sequence of observations, the specification provides a value and the monitor outputs a best-effort approximation of it. The quality of the approximation may depend on the resources that are available to the monitor. By taking to the limit the sequences of specification values and monitor outputs, we obtain precision-resource trade-offs also for limit monitoring. This paper provides a formal framework for studying such trade-offs using an abstract interpretation for monitors: For each natural number n, the aggregate semantics of a monitor at time n is an equivalence relation over all sequences of at most n observations so that two equivalent sequences are indistinguishable to the monitor and thus mapped to the same output. This abstract interpretation of quantitative monitors allows us to measure the number of equivalence classes (or “resource use”) that is necessary for a certain precision up to a certain time, or at any time. Our framework offers several insights. For example, we identify a family of specifications for which any resource-optimal exact limit monitor is independent of any error permitted over finite traces. Moreover, we present a specification for which any resource-optimal approximate limit monitor does not minimize its resource use at any time.
Einleitung
Authors: Muth Lydia 
Published: September 2022

Zusammenfassung„Alkohol ist die am weitesten verbreitete Droge in unserer Gesellschaft“ (Körkel 2018). Besonders schwer betroffen unter Menschen mit Alkoholabhängigkeitsstörungen ist der Anteil der sogenannten Chronisch Mehrfachgeschädigt/Mehrfachbeeinträchtigt Abhängigkeitskranken (CMA) Menschen. Um die Bedarfserfassung und die anschließenden Hilfen personenzentriert, teilhabefördernd und krankheitsbildspezifisch ausrichten zu können, sowie um den volkswirtschaftlichen und gesellschaftlichen Schaden, welcher durch diese Klientel ohne sachgerechte Hilfe verursacht wird, so gering wie möglich zu halten, ist ein Instrument notwendig, welches eindeutig, praxisnah, zielgruppenspezifisch und transparent die Hilfebedarfe aufzeigt und daraus klar erkennbar Leistungen und den monetären Finanzierungsaufwand ableitet. Ziel der vorliegenden Arbeit ist die Erstellung und Evaluierung eines solchen Instrumentes.Im ersten Kapitel erfolgt eine überblicksartige Einführung in das Thema sowie dessen gesellschaftliche Relevanz sowie die Festlegung und Begründung des Arbeitszieles.