bluuebunny/crossref_metadata_2025_split huggingface dataset:
Purpurin‐Promoted Photo‐Redox Reduction of Benzyl Selenocyanates as Masked Selenols, Preparative, Electrochemical, Computational, and Mechanistic Study
Authors: Castro‐Godoy Willber D. , Bouchet Lydia M. , Puiatti Marcelo , Schmidt Luciana C. , Argüello Juan E. 
Published: November 2022

AbstractThe reduction of substituted benzyl selenocyanates to give the corresponding diselenides was performed by means of photo‐redox catalysis using Eosin Y, Rhodamine 6G, Fluorescein, and Purpurin (PP) under LED irradiation. In all cases, diselenides were obtained as the only photoproducts; affording excellent yields when PP was used as photocatalyst under irradiation and air atmosphere in the presence of triethylamine (TEA). Our experimental findings indicate that despite TEA displays an acid‐base equilibrium between PP and PP2−, only the former is photoactive. In addition, electrochemical properties of the selenocyanates under study were measured, finding that Se‐CN moiety is relatively easy to reduce, around −1 V vs SCE. As a result, RC6H4CH2SeCN can act as masked selenols under photoinduced electron transfer conditions, making this methodology compatible with substituents (R) susceptible to hydrolysis or reduction. DFT calculations lead to a better insight into the reductive process.
Living the Good Life: An Islamic Perspective on Positive Psychology
Authors: Saritoprak Seyma N. , Abu-Raiya Hisham 
Published: November 2022

AbstractThis chapter aims to explore Muslims’ religion/spirituality and discuss the factors that are important to consider in scientific research and clinical practice at the intersections of positive psychology, religion, and spirituality. The discussion is based on the theological teachings of the Islamic religion, theoretical speculations regarding the links between Islam and positive psychology, and the relevant findings of empirical studies conducted with Muslim samples. The chapter is composed of five sections. The first is an overview of the geographic distribution, demographic composition, and intrafaith diversity of Muslims around the world. The second section reviews key Muslim religious/spiritual beliefs, teachings, practices, and texts. The third section discusses common Muslim understandings of virtues, health, and well-being. The fourth section reviews potential implications for science and practice at the intersections of positive psychology, religion, and spirituality. The final section offers recommendations for guiding research and practice when working with Muslims at these intersections.
Positive Psychology and Religion/Spirituality Across Cultures in Europe, Non-US North America, and South America
Authors: Rossy Clàudia , Gámiz María , Recoder Silvia , Crespo Iris , Fernández-Capo Maria , Davis Edward B. , Lacey Ethan K. 
Published: November 2022

AbstractThe purpose of this chapter is to synthesize and critique the research on positive psychology and psychology of religion/spirituality (R/S) that has been conducted in Europe, non-US North America (Canada and Central America), and South America. In light of the importance of considering cultural differences and similarities across religions and continents, this chapter synthesizes how cultural factors may affect research and practice on positive psychology and the psychology of R/S in these regions of the world. We start with a brief overview of the sociocultural and religious backdrop of these regions. Then we turn to review the main findings in each area, specifying how and what topics have been emphasized in the research on positive psychology and R/S. Finally, we consider practical implications for research and clinical practice, as well as some gaps in the current literature and future directions for research.
Positive Psychology and the Psychology of Religion and Spirituality in Historical Perspective
Authors: Nelson James M. , Canty Noelle 
Published: November 2022

AbstractThe fields of positive psychology (PP) and the psychology of religion/spirituality (PRS) have much in common, both in terms of their areas of interest and the presuppositions they bring to their work. For example, PP and PRS are both rooted in the philosophies of positivism (which assumes all knowledge must be empirically verified using the scientific method) and naturalism (which assumes there are no realities beyond the natural, material world). Both PP and PRS have much to offer society and the scientific community, but their historic roots in positivistic naturalism currently limit this potential, both in terms of concepts and methods. In this chapter, we argue that for PP and the PRS to coevolve and flourish, they must transcend their perhaps often unaware—but staunch—commitment to positivistic naturalism. In particular, the fields of PP and PRS need to draw inclusively and meaningfully from the methodological, conceptual, and experiential insights of philosophical and religious traditions. Doing so will help PP and PRS broaden the scope of what they each consider meaningful, possible, desirable, and transformative. Ironically, a greater appreciation of the past will enable both fields to have greater scientific, societal, and practical impact in the future.
Religion/Spirituality and the Twin Virtues of Humility and Gratitude
Authors: Cauble Madalyn R. , Said Iman Abdulkadir , McLaughlin Aaron T. , Gazaway Sarah , Van Tongeren Daryl R. , Hook Joshua N. , Lacey Ethan K. , Davis Edward B. , Davis Don E. 
Published: November 2022

AbstractIn this chapter, we review the literature on religion/spirituality (R/S) and the twin virtues of humility and gratitude. We focused on articles that were published in peer-reviewed journals and included both a measure of religion/spirituality and humility or gratitude. We focus our review by exploring two questions: (1) how is R/S associated with humility and gratitude, and (2) how might humility and gratitude work in tandem (consistent with the social oil hypothesis of humility)? We found cross-sectional evidence linking R/S and humility and gratitude. Additional work is needed to test the recent theory on how humility and gratitude may work together to promote and protect strong relationships, especially at the collective level. We suggest ways to catalyze research in this area, including the potential for future work aligning humility and gratitude. We also identify implications for practice both in clinical settings and religious communities.
Theological Virtues, Health, and Well-Being: Theory, Research, and Public Health
Authors: Long Katelyn N. G. , VanderWeele Tyler J. 
Published: November 2022

AbstractThis chapter uses a population health perspective to examine the role of the theological virtues of faith, hope, and love in promoting human health and well-being. We begin with an overview of public health’s traditional focus on health-related exposures and outcomes and then summarize growing evidence that religion and spirituality play a vital role in health and well-being. Next, we review empirical evidence suggesting associations between faith, hope, and love and subsequent health and well-being, focusing on findings from the public health literature. We reflect on what aspects of these virtues are and are not captured by current measures, as well as what might be needed to improve measurement going forward. We describe the role of religious communities in fostering these virtues in the modern context—faith in an era of an increasing sense of meaninglessness, hope in an era of increasing despair and deaths of despair, and love in an era of increasing division. We close by discussing potential implications for public health and human flourishing.
Positive Psychology and Religiousness/Spirituality in the Context of Couples and Families
Authors: Mahoney Annette , Chinn Jay R. , McGraw James S. 
Published: November 2022

AbstractIn this chapter, we examine the intersections of positive psychology (PP) and religiousness/spirituality (R/S) in close relationships. Specifically, within Mahoney’s (J Marriage Fam 72:805–827, 2010) relational spirituality framework, we focus on the maintenance stage of healthy relationships and explore helpful roles that R/S can play for diverse types of couples and families. We briefly summarize extensive evidence that global markers of R/S (e.g., religious service attendance) are associated with relational well-being. We also highlight that global markers of R/S confound relatively commonplace positive religious/spiritual processes with less common but potentially toxic manifestations of R/S. We then delve into four specific religious/spiritual strengths that are empirically tied to better relational functioning: sanctification, spiritual intimacy, prayer for partner, and positive religious/spiritual coping. Next, we offer guidelines consistent with available scientific research that religious leaders, chaplains, couple and family educators, and psychotherapists might consider when working in community or clinical settings. Finally, we suggest ways to advance science and practice on the roles of R/S, for better and worse, within intimate and family relationships.
Cultural Considerations in Positive Psychology and the Psychology of Religion and Spirituality
Authors: Mattis Jacqueline S. 
Published: November 2022

AbstractResearch in positive psychology and the psychology of religion and spirituality has been largely acultural, acontextual, and apolitical. However, social scientists interested in positive human development have long recognized that culture plays a central and indelible role in shaping human behavior. In this chapter, I highlight clarifying definitions of culture. I explore the link between culture, religiosity, spirituality, and positive psychological development. I argue that extant approaches to the study of culture, religiosity/spirituality, and positive development are limited in that they do not sufficiently account for structural and sociopolitical contributors to these relationships. I also posit that existing models do not typically account for the power dynamics that shape positive psychological and prosocial outcomes. Drawing on the Socioecological, Transactional model of Religiosity and Spirituality (SET-RS Urban; Mattis et al., 2019), I propose a new conceptual frame that addresses these gaps. This new framework, the integrative model of Culture, Religiosity, and Spirituality in Positive Development (CRSPD), can guide future research on the relations between culture, religiosity, spirituality, and prosocial development.
Strengthening Social Cohesion
Authors: Jennissen Roel , Bovens Mark , Engbersen Godfried , Bokhorst Meike 
Published: November 2022

AbstractThe increasing diversity of the Dutch population is making conviviality more complicated. Not only in the big cities and their suburbs, but also in medium-sized cities, expat and horticultural municipalities (see Chap. 3). Moreover, modern migrants do not stay in the Netherlands as long as they used to; half have left again after 5 years. This places considerable demands upon schools, for example, which have to deal with pupils arriving and leaving throughout the course of the year. For voluntary associations, too, a high turnover of members is not conducive to cohesion. And the same applies to neighbourhoods where much of the population is just ‘passing through’.
Towards Migration Policy with an Eye for Social Cohesion
Authors: Jennissen Roel , Bovens Mark , Engbersen Godfried , Bokhorst Meike 
Published: November 2022

AbstractIn Chap.3we established that increasing ethnic diversity puts pressure on social cohesion. In Chap.4we noted the lack of coherence between policies addressing migration and aspects of conviviality. These observations raise the question as to what extent the government could take more account of the issue of social cohesion in the design of Dutch migration policy.
Freeze-out forbidden dark matter in the hidden sector in the mass range from sub-GeV to TeV
Authors: Yang Kwei-Chou 
Published: November 2022

Abstract
Kinematically forbidden channels can set the freeze-out dark matter (DM) relic abundance. These channels are described by DM annihilations into heavier states, which vanish at zero temperature limit, but occur at finite temperatures in the early Universe. For the case that the final state of the forbidden channel is scalar mediators that couple to Standard Model (SM) matter through mixing with the SM Higgs, the signals from DM-nucleon interactions and from mediator-related missing energy or displaced vertices could be detected by direct detections and particle physics experiments, respectively. We thus present a study on the simplest secluded vector dark matter model that can exhibit this scenario in the mass range from sub-GeV to TeV. The dark matter resides in the hidden sector, which is in thermal equilibrium with the SM before freeze-out. During freeze-out, the depletion of its density results from its annihilation into two heavier but metastable scalars, where the coupling can be determined by having the correct relic density and constrained by the perturbative unitarity bound. However, much of the allowed parameter space is insensitive to the mixing angle between the hidden scalar and SM Higgs. We find that a more significant mass splitting between DM and the mediator can be allowed only in the sub-GeV region. Moreover, the mass splitting in the TeV region is required to be within the percent level. This model of the forbidden DM interacting with SM particles through the scalar portal is testable in experiments.
Four-loop QCD cusp anomalous dimension at small angle
Authors: Grozin Andrey G. , Lee Roman N. , Pikelner Andrey F. 
Published: November 2022

Abstract
We calculate the small angle expansion of the four-loop QCD cusp anomalous dimension. As a byproduct of our calculation, we also obtain the four-loop anomalous dimension of the heavy-quark field in HQET. The validity of the calculational setup is cross-checked by the independent calculation of the four-loop QCD beta-function from heavy-quark-gluon vertex renormalization in HQET. We check the obtained results for the cusp anomalous dimension and heavy-quark field anomalous dimension against available analytical and numerical results. Finally, we find that the maximal transcendentality contribution to the QCD Bremsstrahlung function coincides, up to a factor 3/2, with the Bremsstrahlung function in $$ \mathcal{N} $$
N
= 4 supersymmetric Yang-Mills theory, at least, through 4 loops.
Complexity for superconformal primaries from BCH techniques
Authors: Rabambi Phumudzo , van Zyl Hendrik J. R. 
Published: November 2022

Abstract
We extend existing results for the Nielsen complexity of scalar primaries and spinning primaries in four dimensions by including supersymmetry. Specifically, we study the Nielsen complexity of circuits that transform a superconformal primary with definite scaling dimension, spin and R-charge by means of continuous unitary gates from the $$ \mathfrak{su} $$
su
(2, 2|$$ \mathcal{N} $$
N
) group. Our analysis makes profitable use of Baker-Campbell-Hausdorff formulas including a special class of BCH formulas we conjecture and motivate. With this approach we are able to determine the super-Kähler potential characterizing the circuit complexity geometry and obtain explicit expressions in the case of $$ \mathcal{N} $$
N
= 1 and $$ \mathcal{N} $$
N
= 2 supersymmetry.
Equivariant multiplicities via representations of quantum affine algebras
Authors: Casbi Elie , Li Jian-Rong 
Published: November 2022

AbstractFor any simply-laced type simple Lie algebra$$\mathfrak {g}$$gand any height function$$\xi $$ξadapted to an orientationQof the Dynkin diagram of$$\mathfrak {g}$$g, Hernandez–Leclerc introduced a certain category$$\mathcal {C}^{\le \xi }$$C≤ξof representations of the quantum affine algebra$$U_q(\widehat{\mathfrak {g}})$$Uq(g^), as well as a subcategory$$\mathcal {C}_Q$$CQof$$\mathcal {C}^{\le \xi }$$C≤ξwhose complexified Grothendieck ring is isomorphic to the coordinate ring$$\mathbb {C}[\textbf{N}]$$C[N]of a maximal unipotent subgroup. In this paper, we define an algebraic morphism$${\widetilde{D}}_{\xi }$$D~ξon a torus$$\mathcal {Y}^{\le \xi }$$Y≤ξcontaining the image of$$K_0(\mathcal {C}^{\le \xi })$$K0(C≤ξ)under the truncatedq-character morphism. We prove that the restriction of$${\widetilde{D}}_{\xi }$$D~ξto$$K_0(\mathcal {C}_Q)$$K0(CQ)coincides with the morphism$$\overline{D}$$D¯recently introduced by Baumann–Kamnitzer–Knutson in their study of equivariant multiplicities of Mirković–Vilonen cycles. This is achieved using the T-systems satisfied by the characters of Kirillov–Reshetikhin modules in$$\mathcal {C}_Q$$CQ, as well as certain results by Brundan–Kleshchev–McNamara on the representation theory of quiver Hecke algebras. This alternative description of$$\overline{D}$$D¯allows us to prove a conjecture by the first author on the distinguished values of$$\overline{D}$$D¯on the flag minors of$$\mathbb {C}[\textbf{N}]$$C[N]. We also provide applications of our results from the perspective of Kang–Kashiwara–Kim–Oh’s generalized Schur–Weyl duality. Finally, we use Kashiwara–Kim–Oh–Park’s recent constructions to define a cluster algebra$$\overline{\mathcal {A}}_Q$$A¯Qas a subquotient of$$K_0(\mathcal {C}^{\le \xi })$$K0(C≤ξ)naturally containing$$\mathbb {C}[\textbf{N}]$$C[N], and suggest the existence of an analogue of the Mirković–Vilonen basis in$$\overline{\mathcal {A}}_Q$$A¯Qon which the values of$${\widetilde{D}}_{\xi }$$D~ξmay be interpreted as certain equivariant multiplicities.
Weld bead geometry real-time control in gas metal arc welding processes using intelligent systems
Authors: Girón-Cruz Jorge Andrés , Pinto-Lopera Jesús Emilio , Alfaro Sadek C. A. 
Published: November 2022

AbstractGas metal arc welding (GMAW) process is one of the most important in the industry, so different efforts have been made to anticipate the parameters to convert this process into a stable one capable of joining parts with minimum human interference. In this sense, controlling is essential for automated applications because properties such as the weld mechanical strength are defined by the metal composition, the microstructure, and the weld bead geometry. Nevertheless, performing this automatic control to guarantee quality characteristics similar to a human expert’s in mechanized welding systems is still tricky. Nowadays, although various sensors have been used in the monitoring for control, it is still hard to detect effective options to real-time identify geometry characteristics in the formation process of the welds. Furthermore, even today, a process much more complex is to control more than one parameter simultaneously or control the weld penetration using a single sensor. Then, this research describes two intelligence systems for real-time control of the weld bead geometry in the GMAW process. The first is a passive vision system with sensor fusion that controls the width and height; the second is an active vision system that controls the penetration. Results indicate that the proposed methodology can be applied to simultaneously control external geometrical parameters without a predefined model of the welding process. In the case of penetration, a fuzzy controller and a neural network-based model help the system adapt to input parameter variations throughout the welding process, thus correcting instabilities under changing operating conditions.
Distinct redox state regulation in the seedling performance of Norway maple and sycamore
Authors: Alipour Shirin , Wojciechowska Natalia , Bujarska-Borkowska Barbara , Kalemba Ewa Marzena 
Published: November 2022

AbstractNorway maple and sycamore, two Acer genus species, have an important ecological value and different sensitivity to stressing factors being currently aggravated by climate change. Seedling growth is postulated to be the main barrier for successful plant establishment under the climate change scenarios. Therefore, the differences in redox regulation during the seedling performance of Norway maple and sycamore were investigated. Seeds of the two Acer species exhibited an identical high germination capacity, whereas seedling emergence was higher in sycamores. PCA analyses revealed that there is more diversification in the leaf characteristics than roots. Norway maple displayed a higher chlorophyll content index (CCI) with a similar leaf mass whereas sycamore seedlings exhibited a higher normalized difference vegetation index (NDVI), higher water content, higher root biomass and higher shoot height. Based on NDVI, sycamore seedlings appeared as very healthy plants, whereas Norway maple seedlings displayed a moderate healthy phenotype. Therefore, redox basis of seedling performance was investigated. The total pool of glutathione was four times higher in sycamore leaves than in Norway maple leaves and was reflected in highly reduced half-cell reduction potential of glutathione. Sycamore leaves contained more ascorbate because the content of its reduced form (AsA) was twice as high as in Norway maple. Therefore, the AsA/DHA ratio was balanced in sycamore leaves, reaching 1, and was halved in Norway maple leaves. Nicotinamide adenine dinucleotide phosphate content was twice as high in sycamore leaves than in Norway maples; however, its reduced form (NADPH) was predominant in Norway maple seedlings. Norway maple leaves exhibited the highest anabolic and catabolic redox charge. The higher reduction capacity and the activity of NADPH-dependent reductases in Norway maple leaves possibly resulted in higher CCI, whereas the larger root system contributed to higher NDVI in sycamore. The different methods of controlling redox parameters in Acer seedlings grown at controlled conditions provided here can be useful in understanding how tree species can cope with a changing environment in the future.
SVM ensemble training for imbalanced data classification using multi-objective optimization techniques
Authors: Grzyb Joanna , Woźniak Michał 
Published: November 2022

AbstractOne of the main problems with classifier training for imbalanced data is defining the correct learning criterion. On the one hand, we want the minority class to be correctly recognized, and on the other hand, we do not want to make too many mistakes in the majority class. Commonly used metrics focus either on the predictive quality of the distinguished class or propose an aggregation of simple metrics. The aggregate metrics, such asGmeanorAUC, are primarily ambiguous, i.e., they do not indicate the specific values of errors made on the minority or majority class. Additionally, improper use of aggregate metrics results in solutions selected with their help that may favor the majority class. The authors realize that a solution to this problem is using overall risk. However, this requires knowledge of the costs associated with errors made between classes, which is often unavailable. Hence, this paper will propose thesemoosalgorithm - an approach based on multi-objective optimization that optimizes criteria related to the prediction quality of both minority and majority classes.semoosreturns a pool of non-dominated solutions from which the user can choose the model that best suits him. Automatic solution selection formulas with a so-called Pareto front have also been proposed to comparestate-of-the-artmethods. The proposed approach will train asvmclassifier ensemble dedicated to the imbalanced data classification task. The experimental evaluations carried out on a large number of benchmark datasets confirm its usefulness.