bluuebunny/crossref_metadata_2025_split huggingface dataset:
Inferring population connectivity in eastern massasauga rattlesnakes (Sistruruscatenatus) using landscape genetics
Authors: Martin Scott A. , Peterman William E. , Lipps Gregory J. , Gibbs H. Lisle 
Published: December 2022

AbstractAssessing the environmental factors that influence the ability of a threatened species to move through a landscape can be used to identify conservation actions that connect isolated populations. However, direct observations of species' movement are often limited, making the development of alternate approaches necessary. Here we use landscape genetic analyses to assess the impact of landscape features on the movement of individuals between local populations of a threatened snake, the eastern massasauga rattlesnake (Sistrurus catenatus). We linked connectivity data with habitat information from two landscapes of similar size: a large region of unfragmented habitat and a previously studied fragmented landscape consisting of isolated patches of habitat. We used this analysis to identify features of the landscape where modification or acquisition would enhance population connectivity in the fragmented region. We found evidence that current connectivity was impacted by both contemporary land‐cover features, especially roads, and inherent landscape features such as elevation. Next, we derived estimates of expected movement ability using a recently developed pedigree‐based approach and least‐cost paths through the unfragmented landscape. We then used our pedigree and resistance map to estimate resistance polygons of the potential extent for S. catenatus movement in the fragmented landscape. These polygons identify possible sites for future corridors connecting currently isolated populations in this landscape by linking the impact of future habitat modification or land acquisition to dispersal ability in this species. Overall, our study shows how modeling landscape resistance across differently fragmented landscapes can identify habitat features that affect contemporary movement in threatened species in fragmented landscapes and how this information can be used to guide mitigation actions whose goal is to connect isolated populations.
The ontogenetic dietary shift from non‐dangerous to dangerous prey in predator‐eating predators under capture risk
Authors: Suzuki Yuya , Ikemoto Mito , Yokoi Tomoyuki 
Published: December 2022

AbstractEvaluating the patterns and generality of ontogenetic dietary shifts (ODSs) contributes to understanding prey–predator interactions and food web dynamics. Numerous studies have focused on predators that target distinctively lower trophic‐level organisms. However, the ODS of predators that routinely prey on organisms at similar trophic levels (i.e., predator‐eating predators) have been neglected in ODS research. The ODS patterns of predator eaters may not fit into conventional frameworks owing to constraints of potential capture risk (e.g., deadly counterattack from prey) and body size. We aimed to reveal the ODS patterns of predator eaters and determine whether the patterns were affected by body size and capture risk. Assuming that capture risk is a significant factor in ODS patterns, we expected: (1) juvenile araneophagic spiders to forage on non‐dangerous prey (insects) and capture larger non‐dangerous prey more frequently than dangerous prey (spiders); and (2) as they grow, their prey types will shift from non‐dangerous to dangerous prey because larger predators will be able to capture dangerous prey as the optimal food. As a result of field observations, we revealed that the major ODS pattern in these spiders changed from a mixed (both insect and spider) to a spider‐dominant diet. The model selection approach showed that this diet shift was partly due to predator size, and the relative importance of predator size was higher than the life stage per se and almost equal to species identity. In these spiders, the body size of spider prey tended to be smaller than that of insects when the predators were small, suggesting that capture risk may be a critical factor in determining the ODS patterns of these predators. Therefore, our study adds to the evidence that the capture risk is crucial in comprehensively understanding the mechanisms determining ODS patterns in natural systems.
The influence of weevil herbivory on leaf litter chemistry in dioecious willows
Authors: Ramstack Hobbs Joy M. , Garthwaite Iris J. , Lancaster Logan , Moffett‐Dobbs Jordan A. , Johnson Kelly , Criss Nichole , McConathy Victoria , James C. Andrew , Gipe Alex , Claeson Shannon M. , LeRoy Carri J. 
Published: December 2022

AbstractLeaf litter inputs can influence the structure and function of both terrestrial and adjacent aquatic ecosystems. Dioecy and herbivory are two factors that together have received little attention, yet have the potential to affect the quantity, quality, and timing of riparian litterfall, litter chemistry, and litter decomposition processes. Here, we explore litter chemistry differences for the dioecious Sitka willow (Salix sitchensis Sanson ex. Bong), which is establishing on primary successional habitats at Mount St. Helens (WA, USA) and is heavily infested with a stem‐boring weevil (Cryptorhynchus lapathi). Weevil‐attacked branches produced summer senesced litter that had significantly higher %N, lower C:N ratios, and lower condensed tannins than litter from branches that were unattacked by the weevil and senesced naturally in the autumn. Weevils more often attack female willows; however, these common litter chemicals did not significantly differ between males and females within the weevil‐attacked and ‐unattacked groups. High‐resolution mass spectrometry was used to isolate compounds in litter from 10 Sitka willow individuals with approximately 1500–1600 individual compounds isolated from each sample. There were differences between weevil‐attacked litter and green leaf samples, but at this level, there was no clustering of male and female samples. However, further exploration of the isolated compounds determined a suite of compounds present only in either males or females. These findings suggest some variation in more complex litter chemistry between the sexes, and that significant differences in weevil‐attacked litter chemistry, coupled with the shift in seasonality of litter inputs to streams, could significantly affect in‐stream ecological processes, such as decomposition and detritivore activity.
Highly‐Selective Construction of Aza‐Fused Pyrrolo Isoquinoline Derivatives
Authors: Zheng Jing , He Yuan , Dong Lin 
Published: December 2022

AbstractA novel Rh(III)‐catalyzed cascade C−H activation/annulation/nucleophilic attack/Michael addition of 2‐phenyloxazoles with maleimides for highly‐selective construction of pyrroloisoquinoline derivatives through conditions control is reported. In this reaction, oxazoles were used both as the directing group and potential functionalized reagents, H2O was the nucleophile. The notable features of this protocol include atom economy and highly regioselectivity.
Incorporation of awareness programs into a model of the spread of HIV/AIDS among people who inject drugs
Authors: Alsharari Maha , Greenhalgh David 
Published: December 2022

AbstractMathematical modeling techniques have been used extensively during the human immunodeficiency virus (HIV) epidemic. Drug injection causes increased HIV spread in most countries globally. The media is crucial in spreading health awareness by changing mixing behavior. The published studies show some of the ways that differential equation models can be employed to explain how media awareness programs influence the spread and containment of disease (Greenhalgh et al. Appl Math Comput. 2015;251:539–563). Here we build a differential equation model which shows how disease awareness programs can alter the HIV prevalence in a group of people who inject drugs (PWIDs). This builds on previous work by Greenhalgh and Hay (1997) and Liang et al. (2016). We have constructed a mathematical model to describe the improved model that reduces the spread of the diseases through the effect of awareness of disease on sharing needles and syringes among the PWID population. The model supposes that PWIDs clean their needles before use rather than after. We carry out a steady state analysis and examine local stability. Our discussion has been focused on two ways of studying the influence of awareness of infection levels in epidemic modeling. The key biological parameter of our model is the basic reproductive number . is a crucial number which determines the behavior of the infection. We find that if is less than one then the disease‐free steady state is the unique steady state and moreover whatever the initial fraction of infected individuals then the disease will die out as time becomes large. If exceeds one there is the disease‐free steady state and a unique steady state with disease present. We also showed that the disease‐free steady state is locally asymptotically stable if is less than one, neutrally stable if is equal to one and unstable if exceeds one. In the last case, when is greater than one the endemic steady state was locally asymptotically stable. Our analytical results are confirmed by using simulation with realistic parameter values. In nontechnical terms, the number is a critical value describing how the disease will spread. If is less than or equal to one then the disease will always die out but if exceeds one and disease is present the disease will sustain itself and moreover the numbers of PWIDs with disease will tend to a unique nonzero value.
Influence of Geochemical Fractionation of Fulvic Acid on its Spectral Characteristics and its Protection Against Copper Toxicity to Daphnia magna
Authors: Dee Kato T. , Meyer Joseph S. , Smith Kathleen S. , Ranville James F. 
Published: December 2022

Abstract
Dissolved copper (Cu) can contribute to toxicity in aquatic systems impacted by acid mine drainage (AMD), and its bioavailability is influenced by aqueous complexation with organic ligands that predominantly include fulvic acids (FAs). Because the geochemical fractionation of FAs that accompanies sorption to hydrous aluminum oxides (HAOs) and hydrous iron oxides (HFOs) can alter Cu complexation with FA, we investigated FAs isolated from three categories of water (pristine, AMD, and in situ-fractionated mixtures of pristine and AMD collected at stream confluences) in three mining-impacted alpine watersheds in central Colorado, USA. We also conducted geochemical fractionation of field-collected FAs and Suwannee River FAs by precipitating HAOs and HFOs in the laboratory. Spectral properties of the FAs (e.g., UV-VIS absorbance) were altered by geochemical fractionation, and in acute toxicity tests with an aquatic invertebrate (Daphnia magna) Cu was more toxic in the presence of in situ- and laboratory-fractionated FAs (median effect concentration [EC50] 19–50 µg Cu L−1) than in the presence of nonfractionated FAs (EC50 48–146 µg Cu L−1). After adjusting for the strain-specific sensitivity of our D. magna, we improved the accuracy of Biotic Ligand Model predictions of Cu EC50 values for AMD-related FAs by using an “effective dissolved organic carbon” based on spectral properties that account for among-FA differences in protectiveness against Cu toxicity. However, some differences remained between predicted and measured EC50 values, especially for FAs from AMD-related waters that might contain important metal-binding moieties not accounted for by our measured spectral indices. Environ Toxicol Chem 2023;42:449–462. © 2022 SETAC
Tunnel Drammen (Norway) – Solution for excavating a tunnel in loose soil with the presence of groundwater
Authors: Gallego Francisco , Matt Kajetan , Helgason Einar 
Published: December 2022

AbstractThe soil tunnel in Drammen (Norway), part of Bane NOR's ‘New Double Track Drammen–Kobbervikdalen' project, has a length of 290 m; however, the different unfavourable boundary conditions combined with a large excavation cross section (156 m2) make this section the most technically challenging part of the project. The soil tunnel is driven mostly in saturated glaciofluvial sediments, which consist primarily of sand and gravel with a low content of fines, resulting in a low cohesion to cohesionless soil. The groundwater level, always within or above the tunnel section, cannot be lowered during the construction due to project requirements. These geological/hydrogeological conditions together with the large cross section present a high‐risk scenario for any tunnelling project and, in the case of Norway, an unprecedented challenge. Moreover, the tunnel is located in an urban area and has a low overburden of just 8 to 9 m during the first 80 m. For the client it was critical that the design solution was safe, robust, and able to respond to the existing level of uncertainty and potential unexpected occurrences. ILF's design is able to answer these technical challenges while removing many of the typical risks associated to saturated soil tunnelling with a solution that relies mainly on extensive pre‐excavation ground improvement works in the form of jet grouting executed from the surface.
Contribution of modern blasting technology to achieve accurate contour profiles in tunneling
Authors: Ganster Mark 
Published: December 2022

AbstractThe profile accuracy during tunnel excavation will be influenced by several factors. Basically the design of the blasting pattern, the confinement conditions, the peak particle velocity generated, the escape of the gas volume and the geology are shown here, which are decisive criteria for successfully avoiding damage induced by blasting operations. Smooth blasting methods have been used successfully for years to minimize rock damage. By using electronic initiation systems in combination with software programs for modeling the energy conditions and the peak particle velocities generated, subsidence damage caused by blasting can be largely avoided.
Västlänken – The West Link Project, Korsvägen construction section in Gothenburg, Sweden
Authors: Stephan Sara , Renz Florian , Hoffmann Björn 
Published: December 2022

AbstractWest Link (Swedish: Västlänken) is one of the biggest infrastructure projects in Sweden building an in total 8 km double‐track railway tunnel in Gothenburg, which is currently under construction. “E05 Korsvägen” is a construction lot which is part of the West Link project with the Swedish transport authority Trafikverket as the client. The works were awarded to the Joint Venture (JV) West Link Contractors consisting of Wayss & Freytag Ingenieurbau AG and NCC. A special contract model with a design and build part combined with a regular bill of quantities comprises building an underground double‐track railway tunnel with a length of 3.2 km and the new Korsvägen station. This sub‐project includes three drill and blast sections and three open excavation sections. All three construction pits will be executed in challenging soft ground conditions. The JV is confronted with high environmental demands and special requirements for the blasting works in the urban area of Gothenburg.
Early Yanshanian metallogenesis of the Banjing tungsten deposit in Ganxian, Jiangxi province, China: Constraints from geochemistry, Sr–Nd isotopes, zircon U–Pb, molybdenite Re–Os, and mica 40Ar–39Ar dating
Authors: Li Jianfeng , Fu Jianming , Lu Youyue , Cheng Shunbo , Ma Liyan , Chen Xiqing , Quan Hongyan , Ma Kemeng 
Published: December 2022

The Banjing tungsten deposit, which has been discovered recently, is located in the northernmost part of the Dabu pluton, southern Jiangxi Province, China. In this study, zircon LA‐ICP‐MS U–Pb dating of the fine‐grained porphyritic biotite granite indicate that it was formed in the early Yanshanian (159.4 ± 2.5 Ma–161.6 ± 0.8 Ma). Whole‐rock geochemical studies have shown the fine‐grained porphyritic biotite granite has SiO2 of 75.82%–76.84%, Al2O3 12.50%–12.87%, MgO 0.07%–0.20%, and CaO 0.64%–1.09%, with A/CNK of 1.017–1.038. It has a total rare earth elements content of 93.9–118.9 ppm with strong negative Eu anomalies (δEu = 0.021–0.081). The biotite granite is enriched in Rb, Th, U, Nd and depleted in Ba, Sr, Nb, Ti. These data suggest the Dabu pluton belongs to S‐type granite. This pluton has ISr of 0.71212–0.72929 and εNd(t) from −9.60 to −10.62 with Nd model ages concentrated in 1732–1838 Ma. These isotopic data in combination with zircon Hf isotopes suggest the biotite granite originated from partial melting of the Middle Proterozoic metamorphic supracrustal rocks in South China, with a minor contribution from juvenile crust. Meanwhile, this study has obtained Re–Os isochron ages of the intrusion‐related and quartz vein‐type molybdenum mineralization are 156.3 ± 2.7 Ma and 157.0 ± 1.1 Ma in the Banjing tungsten deposit, respectively. Sericite from the greisen‐type tungsten‐molybdenum ore has an 40Ar–39Ar plateau age of 156.4 ± 1.0 Ma, interpreted as the formation age of this deposit. Collectively, the Banjing tungsten deposit is considered as a product of the early Yanshanian large‐scale peak mineralization in South China, which was formed in an extensional intracontinental environment caused by the subduction of the Palaeo‐Pacific Plate.
Clarifying the Ethics and Oversight of Chimeric Research
Authors: Johnston Josephine , Hyun Insoo , Neuhaus Carolyn P. , Maschke Karen J. , Marshall Patricia , Craig Kaitlynn P. , Matthews Margaret M. , Drolet Kara , Greely Henry T. , Hill Lori R. , Hinterberger Amy , Hurley Elisa A. , Kesterson Robert , Kimmelman Jonathan , King Nancy M. P. , Lopes Melissa J. , O'Rourke P. Pearl , Parent Brendan , Peckman Steven , Piotrowska Monika , Schwarz May , Sebo Jeff , Stodgell Chris , Streiffer Robert , Wilkerson Amy 
Published: December 2022

AbstractThis article is the lead piece in a special report that presents the results of a bioethical investigation into chimeric research, which involves the insertion of human cells into nonhuman animals and nonhuman animal embryos, including into their brains. Rapid scientific developments in this field may advance knowledge and could lead to new therapies for humans. They also reveal the conceptual, ethical, and procedural limitations of existing ethics guidance for human‐nonhuman chimeric research.Led by bioethics researchers working closely with an interdisciplinary work group, the investigation focused on generating conceptual clarity and identifying improvements to governance approaches, with the goal of helping scholars, funders, scientists, institutional leaders, and oversight bodies (embryonic stem cell research oversight [ESCRO] committees and institutional animal care and use committees [IACUCs]) deliver principled and trustworthy oversight of this area of science. The article, which focuses on human‐nonhuman animal chimeric research that is stem cell based, identifies key ethical issues in and offers ten recommendations regarding the ethics and oversight of this research. Turning from bioethics’ previous focus on human‐centered questions about the ethics of “humanization” and this research's potential impact on concepts like human dignity, this article emphasizes the importance of nonhuman animal welfare concerns in chimeric research and argues for less‐siloed governance and oversight and more‐comprehensive public communication.
Metallic foam with cross flow heat exchanger: A review of parameters, performance, and challenges
Authors: Hassan Ahmed M. , Alwan Adil Abbas , Hamzah Hameed Kadhem 
Published: December 2022

AbstractThe cross‐flow heat exchanger involves a tractor moving between two fluids that flow in a direction perpendicular to each other, and one of the fluids is often a liquid and the other is a gas. This type of heat exchanger has been studied in many previous studies for its importance in air conditioning applications and many industrial applications. In this type of heat exchanger, the surface area for heat transfer is very large. Therefore, many techniques have been used to improve the thermal and dynamic performance of this type of heat exchanger. In this study, previous studies that used metallic foam as one of the ways to improve the performance of heat exchangers were reviewed. The most important techniques that were used in previous studies during the process of evaluating the thermal performance of a cross‐flow heat exchanger in the presence of different types of metal foam were clarified. The use of metal foam depends on important factors, including (1) the type of material, where copper and aluminum were used in most of the previous studies, due to their availability and ease of foam formation using these materials, in addition to the good thermal properties, (2) porosity, where the porosity value of metal foam ranged between 0.85 and 0.98 in the previous studies, (3) the density of pores, most of the studies ranged between 10 and 40 PPI.
Vancomycin functionalization of gold nanostars for sensitive detection of foodborne pathogens through surface‐enhanced Raman scattering
Authors: Dayalan Sandhiya , Gedda Gangaraju , Li Ruei–Nian , Zulfajri Muhammad , Huang Genin Gary 
Published: December 2022

AbstractIn this paper, we report a sensitive surface‐enhanced Raman scattering (SERS) biosensor for the detection of food‐borne pathogens on the basis of recognition of bacterial cells through the specific targeting agent vancomycin. Vancomycin‐functionalized gold nanostars (GNSs–4–MBA–van) were synthesized as SERS tags for specific and sensitive quantification of food pathogens. The Raman reporter molecule 4–mercaptobenzoic acid (4–MBA) was also a linker molecule to attach vancomycin to gold nanostars. The proposed vancomycin‐based SERS technique achieved a detection limit of 5.7 and 8.2 CFU/ml forStaphylococcus aureusandEscherichia coli, respectively. The logarithm of the bacterial concentration ranged from 101to 107 CFU/ml and demonstrated a linear relationship with the SERS intensity of the characteristic 4–MBA Raman peak at 1,081 cm−1. Principle component analysis was used to discriminate the two pathogens simultaneously by using reproducible and specific intrinsic fingerprints and intracellular components obtained through SERS. Moreover, the spiking tests revealed that GNSs–4–MBA–van is effective as a potential biosensor for detecting pathogens in the fresh meat and food‐processing industries.