bluuebunny/crossref_metadata_2025_split huggingface dataset:
Atomically Dispersed Indium‐Copper Dual‐Metal Active Sites Promoting C−C Coupling for CO2 Photoreduction to Ethanol
Authors: Shi Hainan , Wang Haozhi , Zhou Yichen , Li Jiahui , Zhai Panlong , Li Xiangyang , Gurzadyan Gagik G. , Hou Jungang , Yang Hong , Guo Xinwen 
Published: August 2022

AbstractPhotoreduction of CO2 to C2+ solar fuel is a promising carbon‐neutral technology for renewable energy. This strategy is challenged by its low productivity due to low efficiency in multielectron utilization and slow C−C coupling kinetics. This work reports a dual‐metal photocatalyst consisting of atomically dispersed indium and copper anchored on polymeric carbon nitride (InCu/PCN), on which the photoreduction of CO2 delivered an excellent ethanol production rate of 28.5 μmol g−1 h−1 with a high selectivity of 92 %. Coupled experimental investigation and DFT calculations reveal the following mechanisms underpinning the high performance of this catalyst. Essentially, the In−Cu interaction enhances the charge separation by accelerating charge transfer from PCN to the metal sites. Indium also transfers electrons to neighboring copper via Cu−N−In bridges, increasing the electron density of copper active sites. Furthermore, In−Cu dual‐metal sites promote the adsorption of *CO intermediates and lower the energy barrier of C−C coupling.
The Origin of High‐Voltage Stability in Single‐Crystal Layered Ni‐Rich Cathode Materials
Authors: Sun Jianming , Cao Xin , Yang Huijun , He Ping , Dato Michael A. , Cabana Jordi , Zhou Haoshen 
Published: August 2022

AbstractCompared with the polycrystal (PC) Ni‐rich cathode materials, the single‐crystal (SC) counterpart displayed excellent structural stability, high reversible capacity and limited voltage decay during cycling, which received great attention from academics and industry. However, the origin of fascinating high‐voltage stability within SC is poorly understood yet. Herein, we tracked the evolution of phase transitions, in which the destructive volume change and H3 phase formation presented in PC, are effectively suppressed in SC when cycling at a high cut‐off voltage of 4.6 V, further clarifying the origin of high‐voltage stability in SC cathode. Moreover, SC electrode displayed crack‐free morphology, and excellent electrochemical stability during long‐term cycling, whereas PC suffered severe capacity and voltage fade because of the spinel‐like phase, decoding the failure mechanisms of PC and SC during cycling at high cut‐off voltages. This finding provides universal insights into high‐voltage stability and failure mechanisms of layered Ni‐rich cathode materials.
Polyurethane (PU) based multifunctional materials: Emerging paradigm for functional textiles, smart, and biomedical applications
Authors: Sikdar Partha , Dip Tanvir Mahady , Dhar Avik K. , Bhattacharjee Maitry , Hoque Md. Saiful , Ali Solaiman Bin 
Published: August 2022

AbstractThe advances in polymer chemistry research have revolutionized the field of smart materials and biomedical. Polyurethanes (PUs) are a versatile polymer class with diverse structure, morphology, and behavior under various conditions deemed suitable for many functional and intelligent responses. Owing to their biocompatibility, biodegradability, excellent mechanical strength, tailorable chemical, and physical forms, PU has drawn significant research attention in recent times for a wide range of applications. Herein, this review paper outlines PU's recent advances in specific applications encompassing functional textiles, intelligent functionality and medical usage. This article contains a comprehensive review of recent developments and research works concerning PU's direct involvement as coatings, 3D objects, or composite parts to add novel purpose to the textile substrates, smart objects, or medical applications. Commencing with PU's application for the waterproof breathable textiles, the review further explores recent research where PU was incorporated as a phase change material and protective clothing. This review further delves innovative functionalities and responsiveness of the polymer triggered by various stimuli. It ends with an inclusive review of PU's different forms of application concerning medical devices and activities. Finally, perspectives on future challenges and new research opportunities are also presented and discussed.
Wet continuous mixing technique based on full formula of carbon black
Authors: Sui Yanjun , Lai Qingxiang , Nie Wanfu , Tang Shaoshu , Wang Chuasheng , Bian Huiguang 
Published: August 2022

AbstractMixing is the most important production process in rubber production and processing. Essentially, mixing is the technique of uniformly dispersing fillers and small materials in raw rubber, which directly determines the performance and durability of rubber products. This study focuses on overcoming the limitations of the batch mixing technique by combining the wet mixing and continuous mixing techniques, such that their advantages complement each other. In addition, this paper proposes a full formula wet mixing technique, wherein wet continuous mixing used full formula of carbon black to resolve the issue of carbon black flying, which occurs due to the small size of carbon black particles and causes pollution in the air and harmful effects in humans. Based on experimental datasets, it can be inferred that there is desirable mutual synergy between the full formula wet process and the continuous mixing technique, which can simplify the process of adding small materials during the mixing process and improve the quality of mixed rubber as well as promote continuous rubber production. Furthermore, the basic physical properties such as tensile and tear and dynamic mechanical properties of the produced rubber are significantly improved compared with those of the rubber produced by conventional mixing.
Twenty years on: The rationale and use of the clinical cross‐sectional orientation in neuroanatomy
Authors: Champney Thomas H. 
Published: August 2022

AbstractTwenty years ago, it was noted that with the advent of computed tomography (CT), the orientation of neuroanatomy should change. Radiologists had standardized the clinical cross‐sectional view to indicate an inferior view with posterior at the bottom of the field. This is in contrast with the neuroanatomical cross‐sectional view with posterior at the top of the field. For the past 10 years, the author has taught all of the anatomical disciplines including neuroanatomy to more than 2000 students using only the clinical view. This makes learning easier for the students by keeping all of their cross‐sectional views in the same orientation including clinical, radiological, anatomical, embryological, and neuroanatomical. There have been no adverse effects associated with the use of the clinical orientation and there appears to be no valid reason for maintaining the older, nonclinical orientation in contemporary health‐care education.
Association between dietary intake of n‐3 polyunsaturated fatty acids and risk of colorectal cancer in the Japanese population: The Japan Collaborative Cohort Study
Authors: Kato Ayako , Okada Chika , Eshak Ehab S. , Iso Hiroyasu , Tamakoshi Akiko ,   the JACC Study Group
Published: August 2022

AbstractBackgroundEpidemiological studies of the dietary intake of specific n‐3 polyunsaturated fatty acids (PUFA) and anatomical subsite‐specific colorectal cancer (CRC) are limited. We examined the prospective associations of total n‐3 PUFA, marine‐derived n‐3 PUFA [combined eicosapentaenoic acid (EPA), docosapentaenoic acid (DPA), and docosahexaenoic acid (DHA)], and alpha‐linolenic acid (ALA) as plant‐derived n‐3 PUFA with the risk of CRC by subsite in the Japan Collaborative Cohort Study.MethodsThe participants completed a self‐administered food frequency questionnaire and had no prior history of CRC. Cox proportional hazards model was used to determine the associations between n‐3 PUFAs intake and CRC risk overall and by anatomical subsite.ResultsDuring the median 13.8‐year follow‐up period, 699 of the 42,536 participants aged 40–79 years developed incident CRC. An inverse association was found between dietary ALA intake and the risk of distal colon cancer; the multivariable hazard ratios and 95% confidence intervals for the highest quartiles (Q4) were 0.41 (0.21–0.81; p trend = 0.01) compared with the lowest quartiles (Q1). Marine n‐3 PUFA intake was not associated with CRC risk in the overall or anatomical subsite‐specific analyses.ConclusionOur findings suggest that higher ALA intake may be beneficial for lowering the risk of distal colon cancer.
Nitrogen Forms Modify Growth Response and Accumulation of Potentially Toxic Elements by Wheat Genotypes in Nickel‐Contaminated Soil
Authors: Sabir Muhammad , Usman Sumia , Saifullah  , Bibi Sadia , Ahmad Hamaad Raza , Nazar Saima , Farooqi Zia Ur Rahman 
Published: August 2022

AbstractThe effect of nitrogen (N) forms on growth and accumulation of nickel (Ni), zinc (Zn), copper (Cu), and manganese (Mn) by wheat genotypes viz. Lasani‐2008 and Sahar‐2006 is investigated. Genotypes are grown in Ni‐contaminated soil with different N forms viz. urea, NH4–N, mixed N (NH4–NO3), and NO3–N. Lasani‐2008 produces maximum shoot dry weight (SDW) with NO3–N while Sahar‐2006 produces maximum SDW with NH4–N. Lasani‐2008 has higher SDW (24%), greenness index (7%), photosynthetic rate (18%), and transpiration rate (29%) compared to Sahar‐2006. This genotype accumulates more N with mixed N (NH4–NO3) and NH4–N and has 47% higher remediation factor. Lasani‐2008 contains 43% more Ni and maximum Zn in roots with NH4–N while minimum with NO3–N. Lasani‐2008 accumulates Ni and Zn more in shoots while Sahar‐2006 retains more Ni in roots. Sahar‐2006 contains 16% higher Mn in shoot compared to Lasani‐2008. Manganese is maximum with NO3–N followed by urea in roots. It is concluded that genotypes differ for Ni accumulation in response to N forms. Lasani‐2008 proves effective for remediation of Ni‐contaminated soils while Sahar‐2006 can be a good choice for restricting the entry of potentially toxic elements into food chain.
F‐SWIR: Rumor Fick‐spreading model considering fusion information decay in social networks
Authors: Li Weimin , Wei Dingmei , Zhou Xiaokang , Li Shaohua , Jin Qun 
Published: August 2022

SummaryThe spread of rumors has a major negative impact on social stability. Traditional rumor spreading models are mostly based on infectious disease models and do not consider the influence of individual differences and the network structure on rumor spreading. In this paper, we propose a rumor Fick‐spreading model that integrates information decay in social networks. The dissemination of rumors in social networks is random and uncertain and is affected by the dissemination capabilities of individuals and the network environment. The rumor Fick‐transition coefficient and Fick‐transition gradient are defined to determine the influence of the individual transition capacity and the network environment on rumor propagation, respectively. The Fick‐state transition probability is used to describe the probability of change of an individual's state. Moreover, an information decay function is defined to characterize the self‐healing probability of individuals. According to the different roles and reactions of users during rumor dissemination, the user state and the rumor dissemination rules among users are refined, and the influence of the network structure on the rumor dissemination is ascertained. The experimental results demonstrate that the proposed model outperforms other rumor spread models.
Biocompatible Porphyrin‐Peptide Conjugates as Theranostic Agents Targeting the Epstein‐Barr Virus
Authors: Li Xiong , Xie Chen , Zha Shuai , Tam Wing Sze , Jiang Mingjun , Wong Ka‐Leung 
Published: August 2022

AbstractEpstein‐Barr virus (EBV) is a common human‐infected virus related to many diseases and cancers. Recently, some peptides have been found to serve targeting and therapeutic roles by inhibiting EBNA1, an oncoprotein of the EBV. We herein report the conjugation of the EBNA1‐targeting peptides and porphyrins which can bring synergistic effects by both introducing more specific treatments (photodynamic therapy) and improving the biocompatibility of the photosensitizer and the peptides. One of our compounds exhibited significant photo‐cytotoxicity where the Lethal Concentration 50 (LC50)=6.1 μM in EBV‐positive cells. Besides, in vitro cell imaging and co‐staining can also be achieved simultaneously and suggested the binding inside nucleus.
A macro‐model for describing the in‐plane seismic response of masonry‐infilled frames with sliding/flexible joints
Authors: Dhir Prateek Kumar , Tubaldi Enrico , Pantò Bartolomeo , Caliò Ivo 
Published: August 2022

AbstractMasonry infill walls are among the most vulnerable components of reinforced concrete (RC) frame structures. Recently, some techniques for enhancing the performance of the infills have been proposed, aiming at improving both the global and the local behaviour of the infilled frame structure. Among the most promising ones, there are those that aim to decouple or reduce the infill‐frame interaction by means of flexible or sliding joints, relying respectively on rubber or low‐friction materials at the interface between horizontal subpanels or between the panels and the frame. Numerous models have been developed in the last decades for describing the seismic response of masonry‐infilled RC frames, but these have focused mainly on the case of traditional infills. This study aims to fill this gap by proposing a two‐dimensional macro‐element model for describing the in‐plane behaviour of RC infilled frames with flexible or sliding joints. The proposed modelling approach, implemented in OpenSees, is an extension of a discrete macro‐element previously developed for the case of traditional infill panels. It is calibrated and validated in this study against quasi‐static tests from the literature, carried out on masonry‐infilled RC frames with sliding and rubber joints. The study results show the capabilities of the proposed modelling approach to evaluate the benefits of using flexible joints in terms of minimising the negative effects of the interaction between infill and RC frame and limiting the increase of global stiffness of the system with respect to the bare frame condition.
Influence of the design objectives on the seismic performance of steel moment resisting frames retrofitted with buckling restrained braces
Authors: Gutiérrez‐Urzúa Fernando , Freddi Fabio 
Published: August 2022

AbstractBuckling restrained braces (BRBs) represent an effective strategy for the seismic retrofit of existing steel moment resisting frames (MRFs), as they contribute to increasing the strength and ductility capacity of the structure. However, current design strategies do not provide recommendations on how the performance increase is achieved. Prioritising either the increase of strength or ductility capacity has an impact on the damage evolution and affects the overall performance of the structure. A low increase of strength typically requires larger exploitation of the ductility capacity (i.e., damage) of the existing structure, while a high increase of strength produces a significant increase of stiffness, which is often accompanied by an increase of the seismic demands that may limit the effectiveness of the retrofitting solution. The present study assesses the impact of these decisions on the overall performance of steel MRFs retrofitted with BRBs. For this purpose, two MRFs with several BRB retrofitting configurations are used as case study structures. Finite Element Models are built in OpenSees and assessed through Incremental Dynamic Analyses to account for the record‐to‐record variability. Fragility relationships are derived based on local Engineering Demand Parameters (EDPs) to describe structural and non‐structural damage, as well as path‐dependent damage indicators (i.e., residual drifts and cumulative ductility in BRBs). A comparison of the overall performance of the structures is carried out in terms of risk estimates for a high seismicity location.
Novel infrared puffing: Effect on physicochemical attributes of puffed rice (Oryza sativa L.)
Authors: Shavandi Mahdi , Javanmard Majid , Basiri Alireza 
Published: August 2022

AbstractThe effect of novel infrared (IR) puffing and various IR powers (350, 450, and 550 Watts [W]) at various distances (10, 20, and 30 cm) on physicochemical characteristics of puffed rice (puffing properties, color, total phenolic content [TPC], antioxidant activity, peroxide value, and morphology) was investigated. By reducing the distance and increasing the IR power, the volume puffing was significantly increased (p < .05), and bulk density was significantly decreased (p < .05) but there was no significant difference in the length/breadth ratio. The IR puffing effect on color, the TPC, antioxidant activity, and food compounds' analysis through Fourier transform infrared (FTIR) spectra were significant (p < .05) during IR puffing. The scanning electron microscopy (SEM) images showed that by increasing the IR power and decreasing the sample distance from the IR source, the size of protrusions was increased (the volume of the protrusions). The maximum increase in the protrusions size was observed in 10 cm distance and 550 W power of IR. This is the first report on the IR puffing of rice and according to the results, the IR puffing technology has a high efficiency at the rice puffing.
Does expanding access to cannabis affect traffic crashes? County‐level evidence from recreational marijuana dispensary sales in Colorado
Authors: Gunadi Christian 
Published: August 2022

AbstractThis article examines the effect of recreational cannabis dispensary sales on traffic crashes by employing difference‐in‐differences model that exploits the variation in the timing of recreational marijuana dispensary entry across counties within Colorado. Using marijuana‐related hospital discharge as a measure of marijuana abuse/misuse, the results indicate a sizable rise in marijuana‐related hospital discharges after the entry of retail cannabis stores. However, there is a lack of evidence that traffic crash incidents are affected by the entry. The preferred estimate suggests that, at 90% confidence level, a large increase in traffic crashes by more than 5% can be ruled out.
Evaluation of a novel SARS‐CoV‐2 rapid antigenic test diagnostic value in respiratory samples; is the reported test accuracy similar to values in the real‐world? A cross‐sectional study
Authors: Hatami Hossein , Rezaeian AhmadReza 
Published: August 2022

AbstractBackground and AimsAlthough reverse transcription‐polymerase chain reaction (RT‐PCR) assay was introduced as the gold standard to detect SARS‐CoV‐2, the method was known to be time‐consuming besides the requirement for an equipped laboratory. This survey aims to investigate a novel SARS‐CoV‐2 antigen test as a diagnostic tool in COVID‐19 patients to overcome these limitations in addition to evaluating COVID‐19 population characteristics.MethodsA retrospective cross‐sectional study was carried out during the first semester of 2021, and about 1070 nasopharyngeal samples were collected to compare the E‐Health Barakat Company SARS‐CoV‐2 antigen rapid test results with RT‐PCR reports as the reference method.ResultsTotally 537 participants were included in this study for employing RT‐PCR and the antigen test sequentially. The novel antigen rapid test sensitivity is considered 21.09% in the real world, though 81% in the manufacturer's instruction has been mentioned. Moreover, the most revealed manifestations were found respiratory symptoms and fatigue sensations.ConclusionThis study is the first one on evaluating the SARS‐CoV‐2 antigen test in our country. Although the novel antigen assay was found quick and easy to perform, the test performance was very disappointing. The extensive false‐negative results made it an inappropriate candidate for mass screening.
Interventions to increase participation of NGOs in preventive care: A scoping review
Authors: Sajadi Haniye Sadat , Ghadirian Laleh , Rajabi Fatemeh , Sayarifard Azadeh , Rostamigooran Narges , Majdzadeh Reza 
Published: August 2022

AbstractBackground and AimsNongovernmental organizations (NGOs) have enormous potential to effectively prevent and manage diseases; however, little research is available on interventions used to improve NGOs' participation in this area. A scoping review was conducted to identify options proposed or implemented to improve the participation of the NGOs in preventive care.MethodsPubmed, Web of Science, and ProQuest were extensively searched. Google Scholar was also searched to find potential studies related to the subject. Relevant keywords were used in the English language. The reference list of relevant studies was also scanned. Studies were screened with defined inclusion and exclusion criteria. Relevant data were then extracted. Two individuals independently screened and extracted studies. The interventions implemented or proposed to promote the participation of the NGOs in the implementation of preventive interventions were deductively identified and classified.ResultsEighteen articles were included in our review. We identified 31 interventions and categorized them into 11 strategies, including (1) building strong collaboration among NGOs and with governments; (2) expanding networks and sustained relations among NGOs; (3) evaluating the NGOs' performance; (4) increasing intersectoral collaboration; (5) advocating for the role of NGOs; (6) supporting NGOs from the side of government; (7) empowering the abilities and capabilities of NGOs; (8) defining the precise roles and responsibilities of the parties; (9) strengthening the health system governance; (10) increasing the health literacy of the community; and (11) developing required regulations, rules, and policies. None of the interventions identified had evidence of its effectiveness.ConclusionThe current evidence on effective interventions to strengthen NGOs' participation in implementing health care is scanty. It means there is an information gap in the effect of interventions to improve NGOs' participation in health.
Slip and temperature jump effects of MHD stagnation point flow towards a translating plate considering nonlinear radiations
Authors: Sarkar Suman , Makinde Oluwole D. 
Published: August 2022

AbstractThis article investigates the combined effects of nonlinear radiation and magnetic parameter under the velocity slip and temperature jump conditions on the boundary layer flow, arising in magnetohydrodynamics stagnation point flow toward a horizontal moving plate with constant velocity, . The governing mass, momentum, and energy equations are reduced into nonlinear ordinary differential equations with boundary conditions using the relevant similarity variables. The reduced boundary value problem is regulated by the magnetic parameter, slip parameter, temperature jump parameter, Prandtl number, radiation parameter, and temperature ratio parameter. In the absence of an analytic solution, the reduced equations are then demonstrated numerically using the shooting technique. The effects of parameters on the flow domain are analyzed using tables and figures. Moreover, two‐dimensional streamlines are plotted for visualizing fluid flow. It is found that the temperature decreases as the magnetic parameter, slip parameter, temperature jump parameter, and Prandtl number increase, but the opposite scenario is observed when the radiation parameter and temperature ratio parameter increase.