bluuebunny/crossref_metadata_2025_split huggingface dataset:
ПЕДАГОГІЧНА НАУКА ДЛЯ РОЗБУДОВИ НОВОЇ КРАЇНИ
Authors: Кремень Василь Григорович 
Published: August 2022

У виступі розкрито ключові напрями дослідницької підтримки освітян та практичних дій Міністерства освіти і науки України заради успішного функціонування і подальшої модернізації освіти України в умовах війни. Представлено найбільш вагомі здобутки вчених НАПН України у: дошкільній освіті, зокрема Центру раннього розвитку дитини та дошкільної освіти Інституту проблем виховання; модернізації змісту загальної середньої освіти, що втілюється на основі створених вченими Інституту педагогіки підручників з усіх предметів для 5-го класу; цифровізації освіти, у сфері якої суспільного резонансу набули розробки про застосування хмарних технологій у закладах освіти, використання електронних освітніх цифрових ресурсів, SMART-комплекси для закладів професійної (професійно-технічної) освіти; національно-патріотичному вихованні — за розробленими технологіями, програмами та методичними рекомендаціями дослідників Інституту проблем виховання; психологічних дослідженнях, які є особливо актуальними для українського суспільства в умовах повномасштабного військового вторгнення; освіті українських дітей за кордоном, що реалізується, для прикладу, в межах відкритого за ініціативи Інституту цифровізації освіти Центру дистанційної освіти для українських школярів у м. Варшава; підвищенні кваліфікації учителів, що здійснюється за відповідними інноваційними освітніми програмами.
Crystal-Chemical Observations and the Relation Between Sodium and H2O in Different Beryl Varieties
Authors: Henry Rhiana E. , Groat Lee A. , Evans R. James , Cempírek Jan , Škoda Radek 
Published: August 2022

ABSTRACTBeryl (Be3Al2Si6O18) is a well-known mineral, most famously in its vivid green form of emerald, but also as a range of other colors. Prominent varieties of beryl aside from emerald include aquamarine, red beryl, heliodor, goshenite, and morganite. There has not been a significant amount of research dedicated to comparing the crystal-chemical differences among the varieties of beryl except in determining chromophoric cations. While the H2O content within structural channels of emerald has been explored, and the H2O content of individual beryl specimens has been studied, there has not yet been a study comparing the H2O content systematically across beryl varieties. In this study we consider single-crystal X-ray diffraction data and electron probe microanalyses of 80 beryl specimens of six primary varieties, to compare and contrast their crystal chemistry. Beryl cation substitutions are dominantly coupled substitutions that require Na to enter a structural channel site. The results indicate that with increasing Na content beryl varieties diverge into two groups, characterized by substitutions at octahedral or tetrahedral sites, and that the dominant overall cation substitutions in each beryl variety tend to be different in more than just their chromophores. We find that the relation between Na and H2O content in beryl is consistent for beryl with significant Na content, but not among beryl with low Na content. Natural red beryl is found to be anhydrous, and heliodor has Na content too low to reliably determine H2O content from measured Na. We determined equations and recommendations to relate the Na and H2O content in emerald, aquamarine, goshenite, and morganite from a crystallographic perspective that is applicable to beryl chemistry measured by other means. This research will help guide future beryl studies in classifying beryl variety by chemistry and structure and allow the calculation of H2O content in a range of beryl varieties from easily measured Na content instead of requiring the use of expensive or destructive methods.
Bortolanite, Ca2(Ca1.5Zr0.5)Na(NaCa)Ti(Si2O7)2(FO)F2, a New Rinkite-Group (Seidozerite Supergroup) TS-Block Mineral from the Bortolan Quarry, Poços de Caldas Massif, Minas Gerais, Brazil
Authors: Day Maxwell C. , Sokolova Elena , Hawthorne Frank C. , Horváth László , Pfenninger-Horváth Elsa 
Published: August 2022

ABSTRACT
Bortolanite (IMA 2021–040a), ideally Ca2(Ca1.5Zr0.5)Na(NaCa)Ti(Si2O7)2(FO)F2, is a rinkite-group (seidozerite supergroup) TS-block mineral from Poços de Caldas massif, Minas Gerais, Brazil. Associated minerals are götzenite, nepheline, alkali feldspar, aegirine, natrolite, analcime, and manganoan pectolite. Bortolanite shows complex compositional zoning with götzenite and is visually indistinguishable from götzenite. Bortolanite is pale-yellow to brown and has a vitreous luster. Cleavage is perfect parallel to {100}. Mohs hardness is 5. Bortolanite fluoresces weak yellow under ultraviolet light (100–280 nm). Dcalc. = 3.195 g/cm3. Bortolanite is biaxial (+) with refractive indices (λ = 589.3 nm) α = 1.673(2), β = 1.677(2), γ = 1.690(2); 2Vmeas. = 56(2)°, 2Vcalc. = 58.4°. Chemical analysis by electron microprobe gave Nb2O5 1.07, HfO2 0.20, ZrO2 6.70, TiO2 9.94, SiO2 32.49, Gd2O3 0.12, Nd2O3 0.37, Ce2O3 1.25, La2O3 0.65, Y2O3 0.31, FeO 0.59, MnO 1.46, CaO 31.15, Na2O 8.36, F 6.95, O=F –2.93, sum 98.68 wt.%. The empirical formula based on 18 (O + F) apfu is (Ca1.88La0.03Ce0.06Nd0.02Gd0.01)Σ2[Ca1.56(Zr0.41Hf0.01Y0.02)Σ0.44]Σ2(Na0.85Ca0.15)Σ1(Na1.18Ca0.60Mn0.16Fe2+0.06)Σ2(Ti0.94Nb0.06)Σ1(Si4.07O14)(O1.24F0.76)Σ2F2, Z = 1. The simplified formula is Ca2(Ca,Zr)2Na(Na,Ca)2Ti(Si2O7)2(O,F)2F2. Bortolanite is triclinic, space group P, a 9.615(3), b 5.725(2), c 7.316(2) Å, α 89.91(1), β 101.14(1), γ 100.91(1)°, V 387.7(3) Å3. The crystal structure was refined to R1 = 3.19% on the basis of 2194 unique reflections [F &gt; 4σ(F)] measured using a Bruker APEX II ULTRA three-circle diffractometer with a rotating-anode generator (MoKα), multilayer optics, and an APEX II 4K CCD detector. The crystal structure of bortolanite is a framework of TS (Titanium-Silicate) blocks [structure type B3(RG)], where the TS block consists of HOH sheets (H-heteropolyhedral, O-octahedral). The TS block exhibits linkage and stereochemistry typical for the rinkite group where Ti (+ Nb + Zr) = 1 apfu. The O sheet is composed of Ti-dominant MO(1) octahedra, [8]Na-dominant MO(2) polyhedra and (Na,Ca) MO(3) octahedra. In the H sheet in bortolanite, Si2O7 groups link to (Ca1.5Zr0.5) MH and Ca-dominant AP octahedra. Along a, TS blocks link directly through common edges of MH and AP polyhedra and common vertices of MH, AP, and Si polyhedra of the H sheets belonging to two TS blocks. The name bortolanite is after the locality: the Bortolan quarry in the Poços de Caldas massif, Brazil. Bortolanite is isostructural with three rinkite-group minerals: fogoite-(Y), hainite-(Y), and götzenite.
FEATURES OF THE PROSECUTOR'S SUPERVISION OVER THE STATE OF LEGALITY IN THE FIELD OF MATERIAL, HOUSEHOLD AND HEALTH CARE PROVISION IN THE CUSTODY OF WOMEN AND MINORS IN REMAND PRISONS
Authors: Расторопова Ольга Владимировна 
Published: August 2022

Надзор за состоянием законности в сфере материально-бытового и медико-санитарного обеспечения содержания под стражей в следственных изоляторах женщин и несовершеннолетних является весьма актуальной темой, учитывая предусмотренные законодательством определенные особенности содержания под стражей лиц рассматриваемых категорий. Систематически и повсеместно выявляемые нарушения должностными лицами уголовно-исполнительной системы, допущение фактов неисполнения требований уголовно-исполнительного законодательства влекут нарушение прав и законных интересов женщин и несовершеннолетних, отбывающих наказание в СИЗО. В статье отмечается, что прокурорские проверки содержания в СИЗО женщин и несовершеннолетних осужденных необходимо осуществлять на регулярной основе, то есть вне зависимости от наличия информации о фактах нарушения законности. Кроме того, необходимо принять меры по усилению взаимодействия между работниками, осуществляющими надзор за соблюдением законов при содержании под стражей и за уголовно-процессуальной деятельностью органов следствия. Выработка единого подхода к осуществлению прокурорской деятельности, владение методикой проведения проверок позволят не допустить нарушения состояния законности содержания в СИЗО женщин и несовершеннолетних.
Supervision of the state of legality in the field of material, household and health care provision of custody in remand prisonsfor women and minors is a very relevant topic, taking into account certain features of the detention of persons of the categories under consideration provided for by legislation. Systematically and universally detected violations by officials of the penal enforcement system, the admission of facts of non-compliance with the requirements of the penal enforcement legislation entails violation of the rights and legitimate interests of women and minors serving sentences in pre-trial detention. The article notes that the prosecutor's checks of the detention of women and under-age convicts in the pre-trial detention center should be carried out on a regular basis, that is, regardless of the availability of information about the facts of violation of the rule of law. In addition, it is necessary to take measures to strengthen the interaction between employees supervising compliance with the laws during detention and the criminal procedural activities of investigative bodies. The development of a unified approach to the implementation of prosecutorial activities, knowledge of the methodology for conducting inspections will prevent violations of the legality of the detention of women and minors in the pre-trial detention center.
THE UNIQUENESS OF THE SPORTS AND RECREATION SPACE SPECIFICS OF A MODERN UNIVERSITY
Authors: Битшева Ирина Геннадьевна 
Published: August 2022

В статье приводится попытка выяснить смыслосодержащую уникальность специфики физкультурно-оздоровительного пространства современного вуза. Данное пространство определяется совокупностью субъектов, между которыми установлены системные отношения, направленные на достижение цели сохранения и укрепления здоровья. Физкультурно-оздоровительное пространство вуза помогает решению как специфических задач развития двигательной активности, борьбы с гиподинамией, распространенной в современной студенческой среде, так и задач, связанных с формированием физически и психологически здоровой личности современного молодого человека. В статье рассматриваются факторы и основания, позволяющие считать физкультурно-оздоровительное пространство вуза уникальной образовательно-воспитательной средой.
The article presents an attempt to clarify the semantic uniqueness of the specifics of the physical culture and wellness space of a modern university. This space is determined by a set of subjects between whom systemic relations have been established aimed at achieving the goal of preserving and strengthening health. The physical culture and wellness space of the university helps to solve both specific tasks of developing motor activity, combating physical inactivity, common in the modern student environment, and tasks related to the formation of a physically and psychologically healthy personality of a modern young person. The article examines the factors and grounds that make it possible to consider the physical culture and recreation space of the university as a unique educational environment.
HUMANITARIAN EDUCATION AS AN ELEMENT OF STATE BUILDING
Authors: Каликанов Сергей Викторови 
Published: August 2022

В статье раскрывается сущность гуманитарного образования, его особенности и характерные черты. Показывается значение и важность гуманитарного образования как для общества, так и для государства. Гуманитарное образование говорит о смыслах, ценностях и идеалах, тем самым формирует нравственность человека, являясь важнейшей частью образования. Также в статье анализируется современная ситуация в гуманитарных науках, которые представляют собой поле идейной борьбы противоположных мировоззренческих конструкций. Автор прослеживает логические взаимосвязи между различными картинами мира, имеющимися в области гуманитарных наук, и показывает последствия для общества и государства принятия той или иной картины мира. Обосновывается тезис о принципиальной ангажированности гуманитарного образования и необходимости поставить его на служение обществу. Навязываемое обществу представление о том, что образование является всего лишь услугой, лишает образование связи с государством, с государственными интересами, превращает его в автономную и самодостаточную область коммерции, что не способствует повышению качества выпускаемых кадров. Качество образования определяет качество жизни государства, и во многом - его силу. Только исконное для России мировоззрение будет работать на сохранение и развитие государства, восстановление демографического потенциала, сохранение культуры, возвращение позиций страны в глобальном масштабе.
The article reveals the essence of humanitarian education, its features and characteristics. The significance and importance of humanitarian education is shown, both for society and for the State. Humanitarian education speaks about meanings, values and ideals, thus forming human morality and being the most important part of education. The article also analyses the current situation in the humanities, which is a field of ideological battles of opposing worldview constructions. The author traces the logical relationships between various pictures of the world that exist in the humanities, and shows the consequences for society and the state of accepting one or another picture of the world. The thesis about the principled engagement of humanitarian education and the necessity to put it at the service of the society is justified. The idea that education is just a service, imposed on the society, deprives education of its connection with the state and with the state interests, turning it into an autonomous and self-sufficient field of commerce, which does not contribute to the quality of the graduates. The quality of education determines the quality of life of the state and in many ways, its strength. Only a historically native Russian worldview will work for the preservation and development of the state, the restoration of demographic potential, the preservation of culture, and the return of the country's position on a global scale.
On Icy Ocean Worlds, Size Controls Ice Shell Geometry
Authors: Kang Wanying , Jansen Malte 
Published: August 2022

AbstractThe ice shell and subsurface ocean on icy worlds are strongly coupled together—heat and salinity flux from the ice shell induced by the ice thickness gradient drives circulation in the ocean, and in turn, the heat transport by ocean circulation shapes the ice shell. Since measurements in the near future are likely to remain constrained to above the ice shell, understanding this ocean−ice interaction is crucial. Using an ocean box model and a series of experiments simulating the 2D ocean circulation, we find that large icy moons with strong gravity tend to have stronger ocean heat transport under the same ice shell topography. As a result, the equilibrium ice shell geometry is expected to be flatter on moons with larger size, and vice versa. This finding is broadly consistent with the observed ice shell geometry for Enceladus and Europa.
Gas and Cosmic-Ray Properties in the MBM 53, 54, and 55 Molecular Clouds and the Pegasus Loops Revealed by H i Line Profiles, Dust, and Gamma-Ray Data
Authors: Mizuno T. , Hayashi K. , Metzger J. , Moskalenko I. V. , Orlando E. , Strong A. W. , Yamamoto H. 
Published: August 2022

Abstract
In studying the interstellar medium (ISM) and Galactic cosmic rays (CRs), uncertainty of the interstellar gas density has always been an issue. To overcome this difficulty, we used a component decomposition of the 21 cm H i emission line and used the resulting gas maps in an analysis of γ-ray data obtained by the Fermi Large Area Telescope (LAT) for the MBM 53, 54, and 55 molecular clouds and the Pegasus loop. We decomposed the ISM gas into intermediate-velocity clouds, narrow-line and optically thick H i, broad-line and optically thin H i, CO-bright H2, and CO-dark H2 using detailed correlations with the H i line profiles from the HI4PI survey, the Planck dust-emission model, and the Fermi-LAT γ-ray data. We found the fractions of the optical depth correction to the H i column density and CO-dark H2 to be nearly equal. We fitted the CR spectra directly measured at/near the Earth and the measured γ-ray emissivity spectrum simultaneously. We obtained a spectral break in the interstellar proton spectrum at ∼7 GeV, and found that the γ-ray emissivity normalization agrees with the AMS-02 proton spectrum within 10%, relaxing the tension with the CR spectra previously claimed.
High Equivalent Width of Hα+[N ii] Emission in z ∼ 8 Lyman-break Galaxies from IRAC 5.8 μm Observations: Evidence for Efficient Lyman-continuum Photon Production in the Epoch of Reionization
Authors: Stefanon Mauro , Bouwens Rychard J. , Illingworth Garth D. , Labbé Ivo , Oesch Pascal A. , Gonzalez Valentino 
Published: August 2022

Abstract
We measure, for the first time, the median equivalent width (EW) of Hα+[N ii] in star-forming galaxies at z ∼ 8. Our estimate leverages the unique photometric depth of the Spitzer/IRAC 5.8 μm band mosaics (probing ≈5500–7100 Å at z ∼ 8) of the GOODS Reionization Era Wide Area Treasury from Spitzer (GREATS) program. We median-stacked the stamps of 102 Lyman-break galaxies in the 3.6, 4.5, 5.8, and 8.0 μm bands, after carefully removing potential contamination from neighboring sources. We infer an extreme rest-frame EW0(Hα+[N ii]) =

2328

−
1127

+
1326

Å from the measured red [3.6] − [5.8] = 0.82 ± 0.27 mag, consistent with young (≲107 yr) average stellar population ages at z ∼ 8. This implies an ionizing photon production efficiency of

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o

g

(

ξ

i

o

n

,
0

/

e

r

g

H

z

−
1

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=

25.97

−
0.28

+
0.18

. Such a high value for photoproduction, similar to the highest values found at z ≲ 4, indicates that only modest escape fractions f
esc ≲ 0.3 (at 2σ) are sufficient for galaxies brighter than M
UV < −18 mag to reionize the neutral hydrogen at z ∼ 8. This requirement is relaxed even more to f
esc ≤ 0.1 when considering galaxies brighter than M
UV ≈ −13 mag, consistent with recent luminosity functions and as typically assumed in studies addressing reionization. These exceptional results clearly indicate that galaxies can be the dominant source of reionizing photons, and provide us with an exciting glimpse into what we might soon learn about the early universe, and particularly about the reionization epoch, from forthcoming JWST/MIRI and NIRCam programs.
Convolutional Neural Networks for Searching Superflares from Pixel-level Data of the Transiting Exoplanet Survey Satellite
Authors: Tu Zuo-Lin , Wu Qin , Wang Wenbo , Zhang G. Q. , Liu Zi-Ke , Wang F. Y. 
Published: August 2022

Abstract
In this work, six convolutional neural networks (CNNs) have been trained based on 15,638 superflare candidates on solar-type stars, which are collected from the three years of Transiting Exoplanet Survey Satellite (TESS) observations. These networks are used to replace the manually visual inspection, which was a direct way of searching for superflares, and exclude false-positive events in recent years. Unlike other methods, which only used stellar light curves to search for superflare signals, we try to identify superflares through TESS pixel-level data with lower risk of mixing false-positive events and give more reliable identification results for statistical analysis. The evaluated accuracy of each network is around 95.57%. After applying ensemble learning to these networks, the stacking method promotes accuracy to 97.62% with a 100% classification rate, and the voting method promotes accuracy to 99.42% with a relatively lower classification rate at 92.19%. We find that superflare candidates with short duration and low peak amplitude have lower identification precision, as their superflare features are hard to be identified. The database includes 71,732 solar-type stars and 15,638 superflare candidates from TESS with corresponding feature images and arrays, and the trained CNNs in this work are public available.
Interstellar Complex Organic Molecules in SiO-traced Massive Outflows
Authors: Rojas-García O. S. , Gómez-Ruiz A. I. , Palau A. , Orozco-Aguilera M. T. , Dagostino M. Chavez , Kurtz S. E. 
Published: August 2022

Abstract
The interstellar medium contains dust and gas, in which molecules can proliferate at high densities and in cold conditions. Interstellar complex organic molecules (iCOMs) are C-bearing species that contain at least six atoms. As they are detected in young stellar objects, iCOMs are expected to inhabit early stages of star formation evolution. In this study, we try to determine which iCOMs are present in the outflow component of massive protostars. To do this, we analyzed the morphological extension of blue- and redshifted iCOM emission in a sample of 11 massive protostars employing mapping observations at 1 mm within a ∼1 GHz bandwidth for both the IRAM-30 m and APEX telescopes. We modeled the iCOM emission of the central pointing spectra of our objects using the XCLASS local thermal equilibrium radiative transfer code. We detected the presence of several iCOMs such as CH3OH, 13CH3OH, CH3OCHO, C2H5C15N, and (c-C3H2)CH2. In G034.41+0.24, G327.29-0.58, G328.81+0.63, G333.13-0.43, G340.97-1.02, G351.45+0.66, and G351.77-0.54, the iCOM lines show a faint broad-line profile. Due to the offset peak positions of the blue- and redshifted emission, covering from ∼0.1 to 0.5 pc, these wings are possibly related to movements external to the compact core, such as large-scale low-velocity outflows. We have also established a correlation between the parent iCOM molecule CH3OH and the shock tracer SiO, reinforcing the hypothesis that shock environments provide the conditions to boost the formation of iCOMs via gas-phase reactions.
Comparative Evaluation of Intrathecal Dexmedetomidine and Fentanyl as an Adjuvant for Combined Spinal–Epidural Analgesia for Labor
Authors: Jain Anshul , Mittal Ashok , Sharma Sanjya , Deep Akash 
Published: August 2022

Background:
Combined spinal–epidural technique is a widely accepted and popular modality for labor analgesia. Opioids are being used as adjuvants since long time. Dexmedetomidine is a new drug that is being used as an intrathecal adjuvant.

Aim:
The study aims to compare the safety and efficacy of fentanyl and dexmedetomidine as intrathecal adjuvants in labor analgesia.

Settings and Design:
This was a continuous, prospective, randomized controlled trial with 120 parturients.

Materials and Methods:
After ethical approval and written consent, participants were divided randomly into two groups: Group A – bupivacaine 2.5 mg (0.5 mL diluted to 2 mL) + 20 μg of dexmedetomidine in 1 mL saline intrathecally (total volume: 3 mL) and Group B – bupivacaine 2.5 mg (0.5 mL diluted to 2 mL) + 15 μg of fentanyl in 1 mL saline intrathecally (total volume: 3 mL). Primary outcomes were satisfactory analgesia, mode of delivery, and neonatal outcome. Participants were monitored for the onset and duration of analgesia, degree of motor block, and maternal and fetal side effects.

Results:
A total of 108 parturients reported sufficient analgesia (Group A: 57; Group B: 51), and 74 patients delivered vaginally (Group A: 41; Group B: 44). The rates of normal vaginal delivery were higher in Group B. Group A reported earlier onset of analgesia (61.26 ± 18.23 s) that lasted for longer duration (124.16 ± 26.23 min) than in Group B. There were no serious side effects in any of the groups. Fetal ultrasound revealed attenuation of fetal heart rate variability. The heart rate of newborns was also found to be low in Group A.

Conclusion:
Chances of vaginal delivery are higher with intrathecal fentanyl as an adjuvant. Intensity and duration of analgesia are better with intrathecal dexmedetomidine.