bluuebunny/crossref_metadata_2025_split huggingface dataset:
Pendidikan Islam Perspektif Syed Naquib Al Attas
Authors: Edy Edy , Permata Sari Intan 
Published: June 2022

Education is the joint of life, so that humans are able to solve the problems that occur on this earth. According to Al Attas adab is one of the typical terms in the tradition of the development of Islamic education. Adab is the main key in Islamic education. Therefore, Al Attas needs to give a new meaning to the term adab. Al Attas agrees with linguists regarding the meaning of the word adab, Al Attas states that adab is the right action, springs from self-discipline built on knowledge, and comes from wisdom. This research is descriptive qualitative with a library research approach, which focuses more on collecting data from various relevant data sources. This includes books, internet, and research results related to the title of this scientific work. The results showed that according to Syed Muhammad Naquib Al-Attas' view, Islamic education is a process of inculcating knowledge into human beings. In the current Millennial era, the name Al Attas deserves to be equated with the names of world scientists such as Ismail Razi Al Faruqi, Fazlur Rahman as a contemporary Muslim scientist. Al Attas is one of the most influential scientists in this millennial era, Al Attas is not changing the laws or principles of education in Islam, but making new changes in developing the Islamic education system.
Keywords: Adab, Islamic education , Syed Naquib Al Attas
Assessment of a developed pig cadaver model for teaching crown lengthening surgical procedures
Authors: Zhong Jinsheng , Shi Dong , Wang Cui , Zhen Min , Wei Yiping , Han Ziyao , Hu Wenjie , Chung Kwok-Hung 
Published: June 2022

Background
Information regarding using a pig cadaver model for teaching purposes in dentistry is limited, especially for periodontal surgery procedures. The aim of this study was to assess the feasibility and efficacy of teaching crown lengthening surgical procedures using a prepared pig cadaver model.

Methods
Mandibles of slaughtered pigs with subgingival crown fracture defects on two premolars and two molars on each side were prepared as periodontal surgery teaching cases. A resident group (n = 20) and an instructor group (n = 18) participated in assessing the efficacy of the model by completing questionnaires before and after training sessions. Data was either assessed descriptively or analyzed statistically with Wilcoxon signed-rank test with the significance level at α = 0.05.

Results
Results revealed that all the knowledge points showed statistically significant improvements (p < 0.05) except for the procedure to determine the quantity of bone removal during osteotomy procedures. Most residents rated the efficacy of the model obtained with 9.0 out of 10 scale. The data of effectiveness of the pig cadaver model from the instructor group ranged from 7.4 ± 1.4 to 9.0 ± 1.0.

Conclusion
Results of this study support feasibility in using prepared pig cadaver models to teach crown lengthening surgical procedures to postgraduates.
The effect of listening to preferred music after a stressful task on performance and psychophysiological responses in collegiate golfers
Authors: Wang Hung-Tsung , Chen Yung-Sheng , Rekik Ghazi , Yang Chia-Chen , Lai Mao-Sheng , Tai Hsia-Ling 
Published: June 2022

Background
This study explores whether listening to preferred music after a stressful situation affects putting and swinging performance, heart rate (HR), HR variability (HRV), and anxiety among amateur golfers.

Methods
Twenty healthy amateur collegiate golfers voluntarily participated in this study (age 20.1 ± 1.17 yrs., height = 173.8 ± 7.74 cm, body weight = 72.35 ± 12.67 kg). Pre- and post-intervention HR and HRV measurements were taken, along with a self-report of the State-Trait Anxiety Inventory (STAI-S) and Triple Factor Anxiety Inventory (TFAI). Participants were exposed to a stressful situation through the Stroop Colour and Word Test (SCWT) and then instructed to perform three golf-practice sessions in a golf simulator, separated by 48–72 hours of recovery, under different conditions: control, pre-task music, and synchronised music.

Results
No significant difference was identified between the experimental conditions for swinging (in terms of total distance (p = 0.116), carry distance (p = 0.608), speed of the ball (p = 0.819), and launch angle (p = 0.550) and putting performance (the number of successful putts on target (p > 0.05) and distance error between the target and ball (p = 0.122). No main effect for condition and time of intervention, as well as no interaction between these two factors was found for HR, HRV, and STAI-S (p = 0.116). However, the pre and post-intervention percentages of physiological items of the TFAI indicated a large, significant difference in synchronised music trial (p = 0.012, pre-task trial = −1.92% < control trial = 0% < synchronised trial = 4.58%).

Conclusions
The results imply that following a stressful situation, listening to preferred music before and/or during golf has no immediate effect on golf performance, anxiety, and psychophysiological responses in collegiate golfers.
Effect of Reflectance Confocal Microscopy for Suspect Lesions on Diagnostic Accuracy in Melanoma
Authors: Pellacani Giovanni , Farnetani Francesca , Ciardo Silvana , Chester Johanna , Kaleci Shaniko , Mazzoni Laura , Bassoli Sara , Casari Alice , Pampena Riccardo , Mirra Marica , Lai Michela , Magi Serena , Mandel Victor D. , Di Matteo Sergio , Colombo Giorgio Lorenzo , Stanganelli Ignazio , Longo Caterina 
Published: June 2022

ImportancePrevious systematic reviews and meta-analyses have concluded that given data paucity, a comparison of reflectance confocal microscopy (RCM) with dermoscopy is complex. They recommend comparative prospective studies in a real-world setting of suspect lesions.ObjectiveTo test the hypothesis that RCM reduces unnecessary lesion excision by more than 30% and identifies all melanoma lesions thicker than 0.5 mm at baseline.Design, Setting, and ParticipantsThis randomized clinical trial included 3165 patients enrolled from 3 dermatology referral centers in Italy between January 2017 and December 2019, with a mean (SD) follow-up of 9.6 (6.9) months (range, 1.9-37.0 months). The consecutive sample of 3165 suspect lesions determined through dermoscopy were eligible for inclusion (10 patients refused). Diagnostic analysis included 3078 patients (48 lost, 39 refused excision). Data were analyzed between April and September 2021.InterventionsPatients were randomly assigned 1:1 to standard therapeutic care (clinical and dermoscopy evaluation) with or without adjunctive RCM. Information available guided prospective clinical decision-making (excision or follow-up).Main Outcomes and MeasuresHypotheses were defined prior to study initiation. All lesions excised (baseline and follow-up) were registered, including histopathological diagnoses/no change at dermoscopy follow-up (with or without adjunctive RCM). Number needed to excise (total number of excised lesions/number of melanomas) and Breslow thickness of delayed diagnosed melanomas were calculated based on real-life, prospective, clinical decision-making.ResultsAmong the 3165 participants, 1608 (50.8%) were male, and mean (SD) age was 49.3 (14.9) years. When compared with standard therapeutic care only, adjunctive RCM was associated with a higher positive predictive value (18.9 vs 33.3), lower benign to malignant ratio (3.7:1.0 vs 1.8:1.0), and a number needed to excise reduction of 43.4% (5.3 vs 3.0). All lesions (n = 15) with delayed melanoma diagnoses were thinner than 0.5 mm.Conclusions and RelevanceThis randomized clinical trial shows that adjunctive use of RCM for suspect lesions reduces unnecessary excisions and assures the removal of aggressive melanomas at baseline in a real-life, clinical decision-making application for referral centers with RCM.Trial RegistrationClinicalTrials.gov Identifier: NCT04789421
Construction of CoNiFe Trimetallic Carbonate Hydroxide Hierarchical Hollow Microflowers with Oxygen Vacancies for Electrocatalytic Water Oxidation
Authors: Liu Yihao , Chen Guanyu , Ge Riyue , Pei Ke , Song Chenxi , Li Wenxian , Chen Yingying , Zhang Yuan , Feng Lingyan , Che Renchao 
Published: June 2022

AbstractIt is of great challenge to design transition multimetallic carbonate hydroxides with delicate hollow features and defects for efficient electrolytic oxygen evolution reaction (OER). Here, a sequential self‐templating method to synthesize CoNiFe trimetallic carbonate hydroxide hierarchical hollow microflowers (CN‐xFe HMs) with oxygen vacancies (VO) is reported. The synergistic merits of hollow structure, Fe substitution, and VO endow the CN‐xFe HMs with high active‐site exposure density and increased electrical conductivity. Specially, the optimized CN‐xFe HMs validate the excellent OER performance with an overpotential of 258 mV to drive 10 mA cm−2 and a Tafel slope of 48.7 mV dec−1. Theoretical calculations reveal that Fe substitution and VO can synergistically regulate the electronic states to achieve near‐ideal adsorption/desorption capacity for oxygenated intermediates. Moreover, the successful synthesis of other six metals substituted CoNiM (M = Cu, Zn, Cr, Mo, Er and La) carbonate hydroxides provides a universal protocol to construct transition multimetallic electrocatalysts with hollow structures for gaining highly efficient energy conversion reactions.
Graphene Growth across the Twin Boundaries of Copper Substrate
Authors: Huang Deping , Duan Yinwu , Zhang Leining , li Xin , Zhang Yongna , Ding Feng , Guo Jing , Huang Xiaoxu , Li Zhancheng , Shi Haofei 
Published: June 2022

AbstractTwin crystals, the formation energy of which is much smaller than that of ordinary grain boundaries, widely exist in the annealed copper and are hard to eliminate. The study of the effects of twin boundaries on graphene growth is of great significance to the understanding of graphene epitaxy. However, there are few studies on the effects of twin boundaries on the graphene growth process. Here, this article experimentally demonstrates that graphene islands are subjected to different compressive strains from the opposite copper crystal plane after growing across the twin boundary. Further results reveal that graphene can grow across different twin boundaries, such as atom steps, narrow valleys, and even micron‐scale ridges, without forming linear defect. Therefore, strain‐induced graphene doping can be manipulated with the type of twin boundaries and the location on the twin crystals. The transition region where the degree of doping changes monotonically across the twin boundary further confirms the different spatial doping phenomena of graphene islands. This work provides a new perspective for understanding the effect of twin boundaries on the graphene epitaxy, which is expected to have a potential impact on growing high‐quality graphene on twinned copper substrates.
Se‐Containing MOF Coated Dual‐Fe‐Atom Nanozymes With Multi‐Enzyme Cascade Activities Protect Against Cerebral Ischemic Reperfusion Injury
Authors: Tian Ruizhen , Ma Hongyin , Ye Wei , Li Yijia , Wang Shiping , Zhang Zherui , Liu Shengda , Zang Mingsong , Hou Jinxing , Xu Jiayun , Luo Quan , Sun Hongcheng , Bai Fuquan , Yang Yi , Liu Junqiu 
Published: June 2022

AbstractThe atomically monodispersed dual‐atom nanozyme not only possesses the advantages of homogeneous active centers and high atomic utilization efficiency but also exhibits amazing synergistic effect for higher catalytic activities than single‐atom nanozyme. However, how to construct dual‐atom nanozyme with multi‐enzyme cascade capacity for protecting against brain tissue damage is a great challenge. Herein, for coping with the secondary damage to brain tissue caused by the explosive generation of reactive oxygen species(ROS) during cerebral ischemia‐reperfusion, a multi‐enzyme cascade antioxidant system is constructed by encapsulating dual‐Fe‐atom nanozyme (Fe2NC) in a selenium‐containing MOF (Se‐MOF) shell layer. The designed dual‐Fe‐atom nanozyme exhibits higher superoxide dismutase‐like, catalase‐like, and even oxidase‐like activities than single‐atom Fe (Fe1NC) nanozyme, and moreover, the Se‐MOF shell layer not only acts as a glutathione peroxidase mimic, but also improves the stability and biocompatibility of the Fe2NC nanozyme obviously. The synergistic effect of Fe2NC has been demonstrated to be the main reason for the higher activity by density functional theory calculations. In vitro and in vivo results reveal that the multifunctional antioxidant Fe2NC@Se nanoparticles can counteract oxidative damage and inhibit neural apoptosis after cerebral ischemia‐reperfusion injury by effectively eliminating intracellular ROS and potentially inhibiting the ASK1/JNK apoptotic signaling pathway.
Understanding Rapid Intercalation Materials One Parameter at a Time
Authors: van den Bergh Wessel , Stefik Morgan 
Published: June 2022

AbstractDemand for fast, energy‐dense storage drives the research into nanoscale intercalation materials. Nanomaterials accelerate kinetics and can modify reaction path thermodynamics, intercalant solubility, and reversibility. The discovery of intercalation pseudocapacitance has opened questions about their fundamental operating principles. For example, are their capacitor‐like current responses caused by storing energy in special near‐surface regions or rather is this response due to normal intercalation limited by a slower faradaic surface‐reaction? This review highlights emerging methods combining tailored nanomaterials with the process of elimination to disambiguate cause‐and‐effect at the nanoscale. This method is applied to multiple intercalation pseudocapacitive materials showing that the timescales exhibiting surface‐limited kinetics depended on the total intercalation length scale. These trends are inconsistent with the near‐surface perspective. A revised current‐model without assuming special near‐surface storage fits experimental data better across wide timescales. This model, combined with tailored nanomaterials and the process of elimination, can isolate material‐specific effects such as how amorphization/defect‐tailoring modifies both insertion and diffusion kinetics. Avenues for both faster intercalation pseudocapacitance and increased energy density are discussed. A relaxation time argument is suggested to explain the continuum between battery‐like and pseudocapacitive behaviors. Future directions include synthetic methods emphasizing tailored defects and analytical methods that minimize assumptions.
Designing Rewritable Dual‐Mode Patterns using a Stretchable Photoresponsive Polymer via Orthogonal Photopatterning
Authors: Xu Wen‐Cong , Liu Chengwei , Liang Shuofeng , Zhang Dachuan , Liu Yazhi , Wu Si 
Published: June 2022

AbstractThe fabrication of dual‐mode patterns in the same region of a material is a promising approach for high‐density information storage, new anti‐counterfeiting technologies, and highly secure encryption. However, dual‐mode patterns are difficult to achieve because the two patterns in one material may interfere with each other during fabrication and usage. The development of noninterfering dual‐mode patterns requires new materials and patterning techniques. Herein, a novel orthogonal photopatterning technique is reported for the fabrication of noninterfering dual‐mode patterns on an azopolymer P1. P1 is a unique material that exhibits both photoinduced reversible solid‐to‐liquid transitions and good stretchability. In the first step of orthogonal photopatterning, patterned photonic structures are fabricated on a P1 film via masked nanoimprinting controlled by photoinduced reversible solid‐to‐liquid transitions. In the second step, the P1 film is stretched and irradiated with polarized light through a photomask, which generates a chromatic polarization pattern. In particular, the photonic structures and chromatic polarization in the dual‐mode pattern are noninterfering. Another feature of dual‐mode patterns is that they are rewritable via photo‐, thermal, or solution reprocessing, which are useful for recycling and reprogramming. This study opens an avenue for the development of novel materials and techniques for photopatterning.
Single‐Layer‐Particle Electrode Design for Practical Fast‐Charging Lithium‐Ion Batteries
Authors: Tu Shuibin , Lu Ziheng , Zheng Mengting , Chen Zihe , Wang Xiancheng , Cai Zhao , Chen Chaoji , Wang Li , Li Chenhui , Seh Zhi Wei , Zhang Shanqing , Lu Jun , Sun Yongming 
Published: June 2022

AbstractEfforts to enable fast charging and high energy density lithium‐ion batteries (LIBs) are hampered by the trade‐off nature of the traditional electrode design: increasing the areal capacity usually comes with sacrificing the fast charge transfer. Here a single‐layer chunky particle electrode design is reported, where red‐phosphorus active material is embedded in nanochannels of vertically aligned graphene (red‐P/VAG) assemblies. Such an electrode design addresses the sluggish charge transfer stemming from the high tortuosity and inner particle/electrode resistance of traditional electrode architectures consisting of randomly stacked active particles. The vertical ion‐transport nanochannels and electron‐transfer conductive nanowalls of graphene confine the direction of charge transfer to minimize the transfer distance, and the incomplete filling of nanochannels in the red‐P/VAG composite buffers volume change locally, thus avoiding the variation of electrodes thickness during cycling. The single‐layer chunky particle electrode displays a high areal capacity (5.6 mAh cm−2), which is the highest among the reported fast‐charging battery chemistries. Paired with a high‐loading LiNi0.6Co0.2Mn0.2O2 (NCM622) cathode, a pouch cell shows stable cycling with high energy and power densities. Such a single‐layer chunky particle electrode design can be extended to other advanced battery systems and boost the development of LIBs with fast‐charging capability and high energy density.
Visible‐Light‐Mediated C‐2 Functionalization and Deoxygenative Strategies in Heterocyclic N‐Oxides
Authors: Singh Jitender , Patel Roshan I. , Sharma Anuj 
Published: June 2022

AbstractHeterocyclic N‐oxides are prevalent in numerous natural products with broad applications in pharmaceuticals, agrochemicals, material sciences, and asymmetric synthesis. Owing to their profound biological and physiological activity and unique chemical reactivity, the importance of these compounds has stimulated substantial interest among organic synthetic chemists. More importantly, C‐2 functionalization of heterocyclic N‐oxides, including pyridine‐, isoquinoline‐, pyrazine‐, quinoxaline‐, and quinoline N‐oxides, is among the most important strategies for heterocyclic functionalization. Besides, deoxygenation of heterocyclic N‐oxides has also emerged as a reaction of significance in organic chemistry. In the past decade, visible light photoredox catalyzed C‐2 functionalization and deoxygenation of these heterocyclic N‐oxides have drawn substantial attention owing to their mild reaction conditions. This review has been categorized based on visible‐light‐mediated nondeoxygenative C‐2 functionalization (alkylation, fluoroalkylation, arylation, acylation, and amination), deoxygenative C‐2 functionalization (sulfonylation, alkynylation, alkylation, and acylation), and deoxygenation (without C−H functionalization) of heterocyclic N‐oxides. For most part of the work, the substrate scope, limitation, and mechanism of the reactions have been discussed.magnified image
Metal Porphyrins as Single Site Catalyst Models Explored by Electrochemical Scanning Tunneling Microscopy: A New Perspective in Electrocatalysis
Authors: Facchin Alessandro , Durante Christian 
Published: June 2022

AbstractM–N–C materials featuring M–Nx single site catalysts, where for example M = Co, Mg, or Fe coordinating x atoms of nitrogen, have been intensely investigated as promising candidates to replace Pt group metals in a variety of electrocatalytic reactions, for example in the O2 reduction reactions (ORR). However, despite the recent emerging of atomic resolution techniques, there is still a lack of understanding of the precise configuration of the M–Nx single site. For example, metal porphyrins are known to act as catalysts for O2 and they are indeed good model systems for mimicking M–N4 sites. In particular, it would be of interest to gain more information on the precise dynamic of the catalytic process at atomic scale, especially in an electrochemical environment, i.e., at electrode/electrolyte interphase. An approach that is becoming more and more consolidated is to combine the information coming from electrochemistry and scanning tunneling microscopy techniques in electrochemical scanning tunneling microscopy (EC‐STM) and the result is that a precise dynamic of the catalytic site at atomic scale can be investigated. This review aims to emphasize the main results and advances of EC‐STM in investigating small molecule electrocatalysis and specifically O2 reduction at metal porphyrins M–N4 model system.
Clinical significance of postpancreatectomy acute pancreatitis defined by the International Study Group for Pancreatic Surgery
Authors: Ikenaga Naoki , Nakata Kohei , Fujita Nobuhiro , Abe Toshiya , Ideno Noboru , Ishigami Kousei , Nakamura Masafumi 
Published: June 2022

AbstractAimThe International Study Group for Pancreatic Surgery (ISGPS) developed a structured definition of postpancreatectomy acute pancreatitis (PPAP) in 2021. This study aimed to evaluate the clinical significance of PPAP as defined by the ISGPS criteria.MethodsWe evaluated the medical records and postoperative computed tomography (CT) findings of 247 patients who underwent pancreaticoduodenectomy. Postoperative hyperamylasemia (POH) was defined as an elevation in serum amylase levels over the upper baseline limit (≥133 U/L) on postoperative days 1 and 3. PPAP was defined as acute pancreatitis satisfying the following three requirements: POH, clinically relevant deterioration, and radiologic features consistent with acute pancreatitis.ResultsPostoperative hyperamylasemia and PPAP were prevalent in 9.7% (24/247) and 3.6% (9/247) of the patients, respectively. PPAP grade B occurred in eight patients, seven of whom experienced Clavien–Dindo grade IIIA complications, including postoperative pancreatic fistula (POPF) and extended periods of postoperative hospitalization. PPAP grade C occurred in one patient, who died from the exacerbation of underlying interstitial pneumonia following the POPF occurrence. Acute pancreatitis determined by CT was observed in 15.3% (38/247) of the patients who underwent pancreaticoduodenectomy and was strongly associated with severe morbidity (P < .0001) and longer postoperative hospitalization (P < .0001). POH preceded acute pancreatitis on CT in only 23.7% (9/38) of those cases, resulting in a low incidence rate of PPAP.ConclusionPost‐pancreatectomy acute pancreatitis is a major postoperative complication of pancreatic resection; however, based on the current ISGPS criteria, its prevalence is low. Defining PPAP promotes universal evaluation and understanding of this new concept.