bluuebunny/crossref_metadata_2025_split huggingface dataset:
Benzothiazole Clubbed Imidazolone Derivatives: Synthesis, Molecular
Docking, DFT Studies, and Antimicrobial Studies
Authors: Desai Nisheeth , Maheta Abhay , Jethawa Aratiba , Ahmad Iqrar , Patel Harun , Dave Bharti 
Published: November 2022

Aim:
This study aims to synthesize antimicrobial agents and their molecular docking,
and DFT studies of benzothiazole-imidazolone scaffolds.

Background:
Benzothiazole and imidazolone analogues are of interest due to their potential
activity against microbial infections. In search of suitable antimicrobial compounds, we report
here the synthesis, characterization, and biological activities of benzothiazole and imidazolone
analogues (4a-l).

Objective:
The benzothiazole clubbed imidazolone motifs were synthesized, characterized, and
screened for their antimicrobial activity. Molecular docking was carried out for the development
of antimicrobial agents based on the results of biological activity obtained.

Methods:
We have synthesized a new series of benzothiazole-clubbed imidazolone hybrids by
using multi-step reactions in the search for antimicrobial agents (4a-l). The structures were
determined by 1H NMR, 13C NMR, IR, and mass spectroscopy techniques. Moreover, synthesized
compounds were evaluated for their antimicrobial activity by using a Serial Broth Dilution
method. In addition, molecular electrostatic potential, geometric optimization, and molecular
reactivity analyses (HOMO-LUMO) of 4c, which is one of the compounds with the highest
antibacterial activity, were performed.

Results:
The in vitro antimicrobial activity was evaluated against pathogenic strains. Among
them, compounds 4c showed the most potent biological activity against Gram-negative bacteria,
E. coli with MIC values of 50 μg/mL, and compound 4c active against A. clavatus with MIC
values of 100 μg/mL. Active compound 4c HUMO-LUMO energies, molecular electrostatic potential
analysis, and geometric optimization parameters were calculated with a 6-31G ** base set
using DFT/B3LYP theory, and the results were displayed. Molecular docking studies were
performed on E. coli DNA Gyrase B to understand the binding interaction of compound 4c, and it
was observed that compound 4c interacted with Arg76 amino acid of the active site through
hydrophobic interaction.

Conclusion:
Benzothiazole-clubbed imidazolone hybrids (4a-l) indicated promising antimicrobial
activity. Among them, compounds 4b (MIC=50 μg/mL C. albicans), 4c (MIC=50 μg/mL, E. coli),
4e (MIC= 100 μg/mL, A. niger), and 4g (MIC= 50 μg/mL, S. pyogenes) with electronwithdrawing
bromo, chloro, and fluoro group at the para position of the phenyl ring
on benzothiazole-imidazolone hybrids indicated remarkable potency compared to the standard
drug. The geometric optimization, molecular reactivity, and MESP analyses of 4c were calculated
with the B3LYP/6-31G ** base set and ΔE = ELUMO-EHOMO, which was found to be -
0.12096 eV. In addition, the binding affinity scores correlated well with the in vitro antimicrobial
activity (4c), while their binding modes proposed the involvement of steric, electrostatic, and hydrogen-
bonding interactions with the active site.
Evaluation of Evidence-based Presentations in a Postgraduate Program at a U.S. Dental Institution: A Retrospective Study
Authors: Bhadila Ghalia , Hamza Tahir , Dhar Vineet , Dragan Irina F. 
Published: November 2022

Objective:
The objective of this retrospective study was to appraise the level of evidence of presentations gathered from an electronic repository of an advanced postgraduate program in pediatric dentistry at a single U.S.-based dental institute.

Methods:
After the ethical approval was obtained, the presentations were assessed, and themes were identified. Using the cited references, the respective level of evidence was collected based on: the year of publication, reference source, choice of journal, journal impact factor, study design, altmetric score of the articles, and h-index of the authors. STATA version 15.1 (College Station, TX, USA) and Microsoft Excel software were used for statistical analysis.

Results and Discussion:
A sum of 690 references between the years 2015 to 2020 have been used in a total of 74 presentations. Presentations related to special health care needs accounted for 29.7% (n= 22) of the total presentations; followed by oral diagnosis/pathology/medicine (n= 17; 23%). The median number of references used in each presentation was eight, and the most common study design was unfiltered. The median number of the first author’s h-index was 25, and the median number of the altmetric score was four.

Conclusion:
This study appraised the level of evidence used in resident presentations in a postgraduate program in pediatric dentistry at a U.S. dental institute. The findings of this study could provide useful data to postgraduate program directors who wish to address the level of evidence used in their programs. Additionally, by using the altmetric scores and h-indexes presented in this study, future studies can compare the level of evidence between similar academic institutions or programs.
Synthesis, Crystal Structure, Vibrational Study, Optical Properties and
Hirshfeld Surface Analysis of a New Centrosymmetric Hybrid Material,
Bis(3-Aminoquinolium) Tetrachloridocobaltate (II)
Authors: Boughzala Habib , Said Maha 
Published: November 2022

Abstract:
The title organic-inorganic hybrid compound (C9H9N2)2[CoCl4] crystallizes at room temperature in the monoclinic C2/c space group. Its atomic arrangement can be described as an alternation of organic-inorganic layers along the c-axis. Crystal cohesion of the compound is achieved through N-H…Cl hydrogen bonds between the anions and cations and through cycle stacking interactions between organic cations. The vibrational properties were studied by Fourier Transform Infrared (FTIR) spectroscopy. The three-dimensional Hirshfeld surface (3D-HS) analysis and the two-dimensional fingerprint plots (2D-FP) were generated to quantify the weak intermolecular interactions present in the crystal. The optical properties were investigated by optical absorption and photoluminescence measurements. The band gap energy indicates that the compound behaves as an insulator material. Photoluminescence results suggest that the title compound can have a potential application as a non-linear optical material.
Peningkatan Pengetahuan Pelaku UMKM Mengenai Urgensi NIB di Desa Bareng, Kecamatan Bareng, Kabupaten Jombang
Authors: Wibisono Claressia Sirikiet , Oktadifa Rani Melati , Mas’udah Kusuma Wardhani 
Published: November 2022

Kemudahan untuk memperoleh legalitas usaha sudah mencapai titik baik. Bersamaan dengan diterbitkannya Online Single Submission (OSS), pemerintah Indonesia memberikan sarana bagi para pelaku usaha di Indonesia untuk dapat mendaftarkan usaha mereka. Proses pendaftaran dan pendataan usaha ini akan menghasilkan Nomor Induk Berusaha (NIB) yang berguna untuk memberikan legalitas di dalam menjalankan usaha sekaligus sebagai sarana agar pemerintah dapat mendata kepemilikan usaha masyarakat Indonesia. Urgensi mengenai kepemilikan NIB dicantumkan kembali dalam Undang-Undang Cipta Kerja Nomor 11 Tahun 2022. Terbentuknya Undang-Undang yang terhitung masih baru, sangat mungkin banyak pelaku usaha yang belum memahami urgensi serta belum mengerti bagaimana cara untuk mendapatkan NIB. Maka dari itu kegiatan pengabdian kepada masyarakat ini dilakukan untuk memberikan wawasan mengenai mengenai urgensi NIB dan langkah yang perlu dilakukan untuk mendapatkan NIB melalui OSS. Kegiatan pengabdian dilaksanakan dilaksanakan pada bulan Mei menggunakan metode diseminasi yang dilanjutkan dengan pendampingan pembuatan NIB secara langsung atau door-to-door ke rumah pelaku UMKM yang berlokasi di Desa Bareng, Kecamatan Bareng, Kabupaten Jombang.

Increase The Knowledge of UMKM Actors about The urgency of NIB in The Bareng Village, Jombang Regency
The ease of obtaining business legality has reached a good point. Along with the Online Single Submission (OSS) issuance, the Indonesian government provides a platform for business actors in Indonesia to register their businesses. This business registration and data collection process will produce a Business Identification Number (NIB) which is useful for providing legality in running a business and a means for the government to record business ownership of the Indonesian people. The urgency of NIB ownership is reiterated in the Government Regulation Law Number 11 of 2021 concerning Job Creation. Since the regulation is still relatively categorized as the new law, it is very possible that many business actors do not understand the urgency and do not understand how to get a NIB. Therefore, this community service activity is carried out to provide insight into the urgency of NIB and the steps that need to be taken to obtain NIB through OSS. The service activity was held in May 2022 and carried out using the dissemination method followed by assistance in making NIB directly or door-to-door to the homes of business owners located in Bareng Village, Bareng District, Jombang Regency.
Aligning Performance Measurement Systems across the Supply Chain: Evidence from Electronic Components Suppliers
Authors: O’Connor Neale G. , Schloetzer Jason D. 
Published: November 2022

ABSTRACT
Successful interorganizational governance requires practices that reduce information asymmetry between supply chain partners and foster collaborative activities. We study one potential practice—suppliers aligning their performance measurement systems with their largest customer’s performance priorities. Using survey data collected from face-to-face interviews with executives from over 1,000 electronic components suppliers, we find that suppliers with greater customer-supplier information asymmetry and higher partner interdependence have performance measurement systems that align more with their largest customer’s performance priorities. These results are particularly apparent when the exchange involves complex components and when the largest customer represents a greater proportion of supplier sales, suggesting that performance measurement system alignment is of greater value in such situations. We conclude that the performance priorities of large customers play a role in shaping suppliers’ management control systems.
Social Entrepreneurship Training for Beneficiary Families in Sundajaya Hilir Village: Pejuang Muda Best Project
Authors: Halimah Halimah , Pamungkas Raja Ibnu , Kristi Yanuar 
Published: November 2022

Pejuang Muda is a program initiated by the Ministry of Social Affairs in collaboration with the Ministry of Education, Culture, Research, and Technology and the Ministry of Religion of the Republic of Indonesia as a welcome form of the Merdeka Learning Campus Merdeka (MBKM) program. The purpose of Pejuang Muda is to carry out learning outside the campus to produce students who have problem solver cycle skills, identify problems, plan programs, and implement programs. The learning was carried out in two parts, namely learning General Materials through online/online and Team Based Projects. Pejuang Muda program was focused on several categories, namely 1) Development of social assistance programs, 2) Empowerment of the poor and the elderly, 3) Healthy lifestyle and environmental hygiene and 4) Facilities for public use. This article intends to report the results of the implementation of social entrepreneurship training activities for members of Beneficiary Families (KPM) Sundajaya Hilir Village, Baros District, Sukabumi City. This activity was one of the learning outcomes in Project Based activities. The training was carried out using the problem solver cycle method which consisted of 3 steps; identify problems, plan programs, and implement programs. Based on the evaluation results, it is known that through the training activities the people of Sundajaya Hilir village feel motivated to make an effort to raise the family economy.
Participatory Urban Improvement and Gender. Lessons from Jordan Refugee Camps
Authors: Al-Nammari Fatima , Malhis Shatha 
Published: November 2022

Abstract
The objective of this paper is to investigate the successes and challenges of participatory planning of three urban improvement projects. The paper uses a case study approach with mixed methods of interviews and documents to investigate how women were included and whether the strategies used succeeded in overcoming gender inequalities in the preparation of the master plans and action plans, thus achieving benefits for both men and women in the camps. The results indicate that using of mixed gender inclusion strategies support gender equity, but significant changes cannot take place depending on context. Such projects should focus on the sustainability of the change even if incremental.
Pengembangan Motif Batik Tiga Negeri Khas Surakarta dengan Teknik Cap untuk Pasar Industri Kreatif
Authors: Amboro Joko Lulut , Widiastuti Theresia , Setyawan Setyawan , Sulistyati Apika Nurani 
Published: November 2022

Ketika dunia sedang dilanda pandemi, semua sektor ekonomi mengalami kemacetan dan berdampak pada penurunan yang cukup signifikan. Namun, yang menarik adalah produk hasil dari kreativitas semacam batik justru masih mempunyai kesempatan yang cukup baik untuk tetap bertahan. Apalagi dengan kemudahan melalui media online. Bisnis online sebagai sektor perekonomian baru di Indonesia berdampak pada pola pikir masyarakat termasuk masyarakat tradisional, termasuk masyarakat perajin batik. Kesempatan ini memberi peluang besar bagi dunia perbatikan khususnya para kriyawan dan perajin batik untuk melakukan pengembangan tanpa batas demi tercapainya kebaruan corak yang sesuai dengan selera pasar saat ini. Salah satu dari sekian banyak varian batik pesisir yang memiliki sejarah cukup panjang adalah batik Tiga Negeri Surakarta, yang pernah diproduksi di Surakarta dan saat ini berhenti karena satu-satunya perusahaan yang memproduksi batik jenis ini sudah tutup pada tahun 2014; padahal corak ini masih mungkin untuk dikembangkan. Batik dengan motif utama burung berekor panjang dan bunga berkelopak banyak ini terkait dengan filosofi Cina dan dipadukan dengan isen ciri khas batik pedalaman khususnya Surakarta. Target untuk memberikan nuansa baru, yang sesuai dengan konsumen masa kini, memerlukan teknik khusus agar tepat sasaran. Penelitian kualitatif ini memanfaatkan pendekatan analisis tren mode untuk mendapatkan masukan ke arah mana pengembangan motif harus dimulai. Melalui analisis tren dapat diukur tren yang sedang terjadi di pasar beberapa tahun ke depan, sesuai dengan kondisi dan perubahan masyarakat yang sedang terjadi.
Effectiveness of Near-Peer Versus Faculty Point-of-Care Ultrasound Instruction to Third-Year Medical Students
Authors: Rong Katie , Lee Grace , Herbst Meghan 
Published: November 2022

Background: Incorporation of point-of-care ultrasound (POCUS) in undergraduate medical education (UME) is expanding; however, its effective implementation is impeded by a lack of trained faculty. Recruitment of near-peer (NP) instructors is a potential solution, but there are concerns surrounding NP teaching effectiveness compared to faculty instruction. While some institutions have assessed supplemental NP instruction, or NP-taught sessions with strict faculty supervision, few if any have compared effectiveness of NP POCUS instruction alone to faculty instruction through a multi-dimensional assessment. The aim of this study was to compare the effectiveness of near-peer (NP) instruction to faculty instruction at an undergraduate medical education clinical POCUS session for third-year medical students. Methods: This was a randomized controlled trial where third-year medical students were assigned to one of two groups for a 90-minute POCUS session: NP instruction or faculty instruction. A pre- and post-session multiple-choice test and a post-session objective structured clinical examination (OSCE) were administered to assess conceptual and hands-on clinical POCUS knowledge gained. Students’ perceptions of the instructors and session were evaluated using a Likert scale. Results: Seventy-three students (66% of the class) participated; 36 taught by faculty and 37 by NP instructors. Both groups showed a significant score increase from pre-test to post-test (p =0.002); however, there was no significant difference between groups in post-test (p=0.27) nor OSCE scores (p=0.20). Student perceptions of instructor competency were not statistically significant. Conclusions: NP instructors were as effective at teaching clinical POCUS to third-year medical students as faculty instructors at our institution.
Establishing an Experiential Liaison Position to Increase IPPE and APPE Capacity and Preceptor Satisfaction in the Health System Environment
Authors: Patel Toral , Nuffer Wesley , Gilliam Eric , Thompson Megan 
Published: November 2022

Description of the problem: Providing experiential experiences for student pharmacists within health systems can be challenging for schools of pharmacy. Establishing clinical faculty practices within health systems enables schools to increase student placements, however the clinical faculty typically prioritize experiential education within their individual clinical practice and may not be positioned to develop experiential education opportunities across the site.
Description of the innovation: A novel clinical faculty position, the experiential liaison (EL), established at the school’s largest health system partner to focus on improving the quality and quantity of experiential education across an academic medical center (AMC).
Critical analysis: University of Colorado Skaggs School of Pharmacy and Pharmaceutical Science (SSPPS) identified interested preceptors, recognized and coordinated preceptor development, and facilitated development of quality experiential activities within the site through the establishment of the EL position. Since the establishment of the EL position, student placement at the site increased to 34% of SSPPS’s experiential placements in 2020. A high number of preceptors answered “strongly agree or agree” to understanding SSPPS’s curriculum, expectations from the school, how to utilize assessment tools to measure student performance on rotation, and how to provide feedback to the school. Preceptor development opportunities are routine and effective, and the relationship between the school and hospital is collaborative.
Implications: Establishing an experiential liaison clinical faculty position within a health system is a feasible strategy for schools to further increase experiential education placements in health systems.
Determining the Level of Attachment to their Babies of Mothers Who Breastfeed Effectively and Think They Are Sufficient in Breastfeeding: A Cross-Sectional Study
Authors: GÜLER Nazan , AKKÖZ ÇEVİK Semra 
Published: November 2022

Objective: This study aims to determine the relationship between breastfeeding success and breastfeeding self-efficacy and maternal infant attachment.
Methods: The study was conducted in xxx Family Health Center between March -June 2017. The questionnaire form, the LATCH Breastfeeding Identification and Assessment Scale, the Breastfeeding Self-Efficacy Scale, and the Maternal Attachment Inventory were used to collect data in the study. The Kruskall Wallis Analysis Mann, Whitney-U Analysis, Spearman Correlation and Kurtosis and skewness coefficients, Internal consistency Cronbach α coefficient were used in data analysis.
Results: The women who participated in the study had an average score of 9.87±0.42 in the LATCH Breastfeeding Identification and Assessment Scale, 63.51±10.71 in the Breastfeeding Self-Efficacy Scale and 101.58±2.28 in the Maternal Attachment Inventory. The difference between the average Breastfeeding Self-Efficacy Scores according to the level of education and time when breastfeeding started was statistically significant (p
Le numérique au service de la valorisation des compétences des jeunes adultes
Authors: COVILLE Marion , RAMPNOUX Olivier , VÉTEL Bruno 
Published: November 2022

Cette contribution questionne les modalités d’apprentissage des jeunes utilisateurs d’interfaces numériques. À la suite d'Auray (2016), nous analysons les aptitudes à maîtriser les environnements numériques, en discutant la typologie en 4 compétences qu’il propose. Parmi elles, nous nous focalisions surtout sur la compétence dite géographique. Elle regroupe 2 sous-compétences : topologique, une position d’action tactique réorientée de proche en proche et cartographique, une position d’action stratégique et surplombante envisagée en présence de connaissances exhaustives sur une situation. Pour mener ce travail comparatif, nous croisons les apprentissages inscrits dans deux domaines institutionnalisés : l’université et la santé. Des données empiriques issues de deux enquêtes menées dans ces contextes permettent de compléter l’analyse des inégalités sociales face au numérique par celle des handicaps cognitifs liés à l’autisme et physiques liés à des douleurs chroniques.
KOMPAS.COM DECONSTRUCTION ON RESHUFFLE STATEMENTS AS A POLITICAL POLICY DURING THE COVID-19 PANDEMIC
Authors: Fernando Joshua , Sarwoprasodjo Sarwititi , Hapsari Dwi Retno , Irandiputri Matahari , Hidayati Ratih Kurnia 
Published: November 2022

<p><em>The COVID-19 pandemic seems to be a challenge for every country in determining its political-strategic direction. The political policies taken are determining the sustainability of the lives of hundreds of millions of Indonesians. During the COVID-19 pandemic, the reshuffle issue continued to surface and made media coverage very important. Kompas.com is present as a major media that continues to record the development of the reshuffle issue amid the pandemic. This study aims to look at the framing of three reports of kompas.com in different time frames, regarding the reshuffle issue during the C</em><em>OVID</em><em>-19 pandemic. This study used a qualitative research method with theory of deconstruction of perspective</em> <em>Jacques Derrida and was sorted using Robert N. Entman's framing analysis. The results of this study found that kompas.com tried to construct public thinking by making opinion articles as an emphasis on news discourse reshuffles which made a shift of people's views to the possibility that resulted in a reshuffle that became a reality.<strong></strong></em></p>
Visible and Invisible Ethnicity: Native Language and Religiosity Among the Kalmyks during the Years of Deportation, 1943–1956
Authors: Guchinova Elza 
Published: November 2022

Abstract
This article is devoted to an important period, as yet insufficiently studied by anthropologists and sociologists, in the history of Kalmykia – the deportation of the Kalmyks to Siberia (1943–1956) and its cultural implications. Its aim is to show how the stigmatization of the exiled Kalmyks in an unfavorable social and political environment influenced their linguistic and religious behavior. These issues are part of the process of creating a Soviet Kalmyk ethnicity, which began after the establishment of Soviet power on the Kalmyk steppe in 1920 and was a continuation in the realm of politics of the forced modernization of the people. Kalmyks in Siberia tried to hide ethnically marked forms of culture, abstaining from speaking Kalmyk in public and hiding their religiosity. The article uses field materials collected by the author in the form of interviews conducted between 2004 and 2019 and published memoirs about exile.