bluuebunny/crossref_metadata_2025_split huggingface dataset:
Business plan development in an international project aimed at creating a fictitious hotel
Authors: Pellešová Pavlína , Heinz Krystyna 
Published: December 2022

The article describes the process of developing a business plan for a fictitious hotel as part of a simulation exercise involving five partners participating in an international project. It describes the project goals, its structure, tasks, and the achievements of the project participants. The starting point for the development of a business plan by each team were theoretical aspects that need to be considered in the process. Based on them, the participants designed their hotels under the guidance and mentorship of the project’s researchers. The project outputs in the form of proposals to create specific hotels in selected countries contribute to the project goals regarding entrepreneurship education through experiential learning provided to students of tourism. It can be argued that students participating in such simulations will be better prepared for the competitive labour market and will have the skills necessary to set up their own businesses in the hotel industry.
Ensembling Scale Invariant and Multiresolution Gabor Scores for Palm Vein Identification
Authors: Ananthi G. , Raja Sekar J. , Arivazhagan S. 
Published: December 2022

Biometric recognition based on palm vein trait has the advantages of liveness detection and high level of security. An improved human palm vein identification system based on ensembling the scores computed from scale invariant features and multiresolution adaptive Gabor features is proposed. In the training phase, from the input palm vein images, the interested palm regions are segmented using 3-valley point maximal palm extraction strategy, an improved method that extracts the maximal region of interest (ROI) easily and properly. Extracted ROI is enhanced using contrast limited adaptive histogram equalization method. From the enhanced image, local invariant features are extracted by applying scale invariant feature transform (SIFT). The texture and multiresolution features are extracted by employing adaptive Gabor filter over the enhanced image. These two features, scale invariant and multiresolution Gabor features act as the templates. In the testing phase, for the test images, ROI extraction, image enhancement, and two different feature extractions are performed. Using cosine similarity and match count-based classification, the score, Ss is computed for the SIFT features. Another score, Sg is computed using the normalized Hamming distance measure for the Gabor features. Both these scores are ensembled using the weighted sum rule to produce the final score, SF for identifying the person. Experiments conducted with CASIA multispectral palmprint image database version 1.0 and VERA palm vein database show that, the proposed method achieves equal error rate of 0.026% and 0.0205% respectively. For these databases, recognition rate of 99.73% and 99.89% respectively are obtained which is superior to the state-of-the-art methods in authentication and identification. The proposed work is suitable for applications wherein the authenticated person should not be considered as imposter.
Internalisasi Nilai-Nilai Cinta Tanah Air pada Ekstrakurikuler Irmas Al Fikri di SMKN 1 Lemahabang
Authors: Luthfiah Luthfiah 
Published: December 2022

Skripsi ini dilatarbelakangi oleh problematika kebangsaan yakni intoleransi. Sikap intoleransi kerap berakhir pada konflik dan kekerasan di lingkungan sekolah sehingga memiliki ancaman serius bagi masa depan generasi muda dan kualitas pendidikan di Indonesia maka sekolah harus menentukan startegi khsusus untuk mengatasi ini.
Tujuan penelitian ini adalah untuk mengetahui nilai-nilai cinta tanah air yang diinternalisasikan Irmas Al Fikri, mengetahui strategi internalisasi nilai-nilai cinta tanah air pada Irmas Al Fikri, mengetahui persepsi kognitif anggota Irmas Al Fikri.
Penelitian ini menggunakan pendekatan kualitatif dengan jenis penelitian deskriptif. Penelitian ini menggunakan sumber data primer dan sumber data sekunder dari kegiatan ekstrakurikuler Irmas Al Fikri SMKN 1 Lemahabang. Data dikumpulkan dengan teknik studi lapangan. Analisis data dilakukan dengan tahapan reduksi data melalui analisis kode, penyajian data, verifikasi dan kesimpulan.
Hasil penelitian ini menunjukkan bahwa bentuk internalisasi nilai-nilai cinta tanah air yang telah terealisasikan pada Irmas Al Fikri diantaranya yaitu kajian keindonesiaan yang dilaksanakan setiap satu bulan dua kali, rihlah ke tempat ibadah agama lain, bakti sosial terhadap masyarakat sekitar, dan latihan dasar kepemimpinan. Kegiatan tersebut tentunya berlandaskan nilai-nilai kebangsaan meliputi mencintai keberagamana atau perbedaan, mengembangkan rasa kekeluargaan dengan semangat gotong royong, toleransi, peduli lingkungan, peduli sosial, dan tanggung jawab.
Kesimpulan pada proses internalisasi nilai cinta tanah air masih belum merata keseluruh anggota, karena masih ada anggota belum memahami betul makna dasar negara (pancasila) sehingga perlu adanya evaluasi lebih lanjut untuk memaksimalkan proses internalisasi ini. Berkenaan dengan hal tersebut pengurus dan pembina berkomitmen untuk terus memaksimalkan dan merata keseluruh lapisan anggota Irmas Al Fikri.
ADVERBIA DALAM BAHASA JEPANG DAN PADANANNYA DALAM BAHASA INDONESIA
Authors: Wouthuyzen Mariana 
Published: December 2022

Paparan ini bertujuan untuk mendeskripsikan fukushi (adverbia) dalam bahasa Jepang, khususnya tentang kata yang berhubungan dengan fukushi (adverbia), pembentukan, perbedaan pemakaian fukushi (adverbia), dan makna fukushi (adverbia). Penulis menunjukkan bahwa pemakaian fukushi (adverbia) taihen, taisō, sōtō ni, makoto ni, totemo, zuibun, dan hijō ni mempunyai makna yang sama atau hampir sama tetapi dalam penggunaannya terdapat perbedaan satu dengan yang lainnya. Di samping itu, fukushi adalah kata yang dapat digunakan untuk menerangkan dōshi (verba), keiyōshi (adjektiva-i), dan keiyōdoshi (adjektiva-na) tetapi tidak bisa menjadi subjek, predikat dan pelengkap, dan tidak mengalami konjugasi. Fukushi dapat pula menjadi yogen atau fukushi lain, sehingga penggunannya dalam bahasa Indonesia adalah seperti kata keterangan.
Seljuk Code in the Cultural Landscape of Crimea
Authors: Kotliar Elena Romanovna , Khlevnoi Vladimir Aleksandrovich 
Published: December 2022

The subject of the study is the Seljuk cultural code in the cultural landscape of the Crimea. The object of the study is the Seljuk style in the decorative and applied arts and architecture of the Crimea. The article uses the following methods: culturological (ontological and semiotic) analysis in deciphering the meanings of Seljuk elements, the method of historicism in the ontology of Seljuks in the Crimea, the method of analysis of previous studies, the method of synthesis in the identification of ethnic signs. The article discusses the following aspects of the topic: The semantics of the Seljuk code in the cultural landscape of the Crimea is revealed, examples and ways of applying Seljuk stylistics in decorative and applied art and architectural decor of modern and postmodern are considered. 1. The multinational cultural landscape of Crimea consists of the cultures of ethnic groups that inhabited the Crimea in different periods. The leading marker of the definition and self-determination of ethnic groups is religion and folk mythology, embodied in national traditions. A clear example demonstrating ethnic identity and its continuity is folk art. 2.	The appearance of the Seljuks in Crimea and the wide spread of the Seljuk style, which has become one of the main components of the "Crimean style" in modern and postmodern architecture, is not accidental and is due to centuries-old ethnic migrations and the mutual influence of cultures. The Seljuk style, therefore, ceases to be purely ethnic, and becomes part of the cultural landscape of the Crimea, used in the decor regardless of the ethnic origin of the author / owner. 3.	A special contribution of the authors to the study is the identification and justification of the Seljuk code as one of the main ones in the Crimean stylistics. The scientific novelty of the research consists in the semiotic and stylistic analysis of the Seljuk code in the cultural landscape of the Crimea.
Analysis of the Annealing Budget of Metal Oxide Thin‐Film Transistors Prepared by an Aqueous Blade‐Coating Process
Authors: Tang Tianyu , Dacha Preetam , Haase Katherina , Kreß Joshua , Hänisch Christian , Perez Jonathan , Krupskaya Yulia , Tahn Alexander , Pohl Darius , Schneider Sebastian , Talnack Felix , Hambsch Mike , Reineke Sebastian , Vaynzof Yana , Mannsfeld Stefan C. B. 
Published: December 2022

AbstractMetal oxide (MO) semiconductors are widely used in electronic devices due to their high optical transmittance and promising electrical performance. This work describes the advancement toward an eco‐friendly, streamlined method for preparing thin‐film transistors (TFTs) via a pure water‐solution blade‐coating process with focus on a low thermal budget. Low temperature and rapid annealing of triple‐coated indium oxide thin‐film transistors (3C‐TFTs) and indium oxide/zinc oxide/indium oxide thin‐film transistors (IZI‐TFTs) on a 300 nm SiO2 gate dielectric at 300 °C for only 60 s yields devices with an average field effect mobility of 10.7 and 13.8 cm2 V−1 s−1, respectively. The devices show an excellent on/off ratio (>106), and a threshold voltage close to 0 V when measured in air. Flexible MO‐TFTs on polyimide substrates with AlOx dielectrics fabricated by rapid annealing treatment can achieve a remarkable mobility of over 10 cm2 V−1 s−1 at low operating voltage. When using a longer post‐coating annealing period of 20 min, high‐performance 3C‐TFTs (over 18 cm2 V−1 s−1) and IZI‐TFTs (over 38 cm2 V−1 s−1) using MO semiconductor layers annealed at 300 °C are achieved.
Biomolecules‐Incorporated Metal‐Organic Frameworks Gated Light‐Sensitive Organic Photoelectrochemical Transistor for Biodetection
Authors: Li Cheng‐Jie , Hu Jin , Gao Ge , Chen Jia‐Hao , Wang Cheng‐Shuang , Zhou Hong , Chen Guangxu , Qu Peng , Lin Peng , Zhao Wei‐Wei 
Published: December 2022

AbstractIncorporating biomolecules into metal‐organic frameworks (MOFs) as exoskeletons to form biomolecules‐MOFs biohybrids has attracted great attention as an emerging class of advanced materials. Organic devices have been shown as powerful platforms for next‐generation bioelectronics, such as wearable biosensors, tissue engineering constructs, and neural interfaces. Herein, biomolecules‐incorporated MOFs as innovative gating module is realized for the first time, which is exemplified by biocatalytic precipitation (BCP)‐oriented horseradish peroxidase (HRP)‐embedded zeolitic imidazolate framework‐90 (HRP@ZIF‐90)/CdIn2S4 gated organic photoelectrochemical transistor under light illumination. In connection to a sandwich immunocomplexing targeting the model analyte human IgG, the IgG‐dependent generation of H2O2 and the tandem HRP‐triggered BCP reaction can cause the in situ blocking of the pore network of ZIF‐90, leading to variant gating effect with corresponding responses of the device. This representative biodetection achieved good analytical performance with a wide linear range and a low detection limit of 100 fg mL−1. In the view of the plentiful biomolecule‐MOF complexes and their potential interactions with organic systems, this study provides a proof‐of‐concept study for the generic development of biomolecules‐MOFs‐gated electronics and beyond.
Naphthalimide‐Based 3D Organic Semiconductors: Synthesis and Application as Photo‐Electrocatalysts for Organic Dyes Degradation and Water Splitting
Authors: Suárez‐Blas Fátima , Li Junyi , Alonso‐Navarro Matías J. , Harbuzaru Alexandra , Ponce Ortiz Rocío , Ramos María Mar , Shalom Menny , Barrio Jesús , Segura José L. 
Published: December 2022

Abstract1,2‐diketone‐based naphthalimide has emerged as an important electron‐withdrawing building block in the synthesis of organic semiconductor assemblies for a wide range of applications. The reaction with different diamine derivatives enables the formation of pyrazine linkers which promotes planarity and rigidity of the naphthalimide‐based semiconductors, therefore tunning their electronic structure and processability. Despite the significant use of this versatile building block to generate flat and rigid assemblies, the correlation between rigidity and dimensionality in these systems and their photocatalytic activity remains unexplored so far. Herein, with the aim to modulate the photocatalytic activity of these materials, a new family of assemblies with different dimensionality end‐capped with naphthalimide moieties are developed in which one (NIPB), three (3NIPT), and four (4NIPTM) units have been selectively introduced. The good processability of these novel semiconductors combined with their suitable energy levels allows their application as photo‐electrocatalysts for the degradation of organic dyes and for water splitting. The derivative with the highest dimensionality, 4NIPTM, shows higher photo‐electrocatalytic activity and lower charge transfer resistance than that of conventional semiconductors (such as TiO2 and C3N4), reaching photocurrents up to 20 µA cm−2.
A Stable Solid Polymer Electrolyte for Lithium Metal Battery with Electronically Conductive Fillers
Authors: Guo Xuelin , Ju Zhengyu , Qian Xitang , Liu Yijie , Xu Xiao , Yu Guihua 
Published: December 2022

AbstractElectronic conduction in solid‐polymer electrolytes is generally not desired, which causes leakage of electrons or energy loss, and the electronically conductive domains at electrode‐electrolyte interfaces can lead to continuous decomposition of electrolytes and shorting issues. However, it is noticed in this work that in an insulating matrix, the conductive domains at certain aspects could also have positive effects on the electrolyte performance with proper control. This work evaluates the limitation and benefits of electronically conductive domains in a solid‐polymer electrolyte system and discusses the approach to improve the electrolyte physicochemical properties with densified local electric field distribution, enhanced bulk dielectric property, and charge transfer. By deliberately introducing the conductive domains in a regular solid‐polymer electrolyte, stable cycle life, low overpotential, and promising full cell performance could be achieved.
The Ketosynthase Domain Controls Chain Length in Mushroom Oligocyclic Polyketide Synthases
Authors: Löhr Nikolai A. , Urban Maximilian C. , Eisen Frederic , Platz Lukas , Hüttel Wolfgang , Gressler Markus , Müller Michael , Hoffmeister Dirk 
Published: December 2022

AbstractThe nonreducing iterative type I polyketide synthases (NR‐PKSs) CoPKS1 and CoPKS4 of the webcap mushroom Cortinarius odorifer share 88 % identical amino acids. CoPKS1 almost exclusively produces a tricyclic octaketide product, atrochrysone carboxylic acid, whereas CoPKS4 shows simultaneous hepta‐ and octaketide synthase activity and also produces the bicyclic heptaketide 6‐hydroxymusizin. To identify the region(s) controlling chain length, four chimeric enzyme variants were constructed and assayed for activity in Aspergillus niger as heterologous expression platform. We provide evidence that the β‐ketoacyl synthase (KS) domain determines chain length in these mushroom NR‐PKSs, even though their KS domains differ in only ten amino acids. A unique proline‐rich linker connecting the acyl carrier protein with the thioesterase domain varies most between these two enzymes but is not involved in chain length control.
Blocking Methanation during Reverse Water Gas Shift Reaction on Ni/SiO2 Catalysts by Surface Ag
Authors: Zhang Chu , Zhang Ruoyu , Liu Yuxin , Wu Xiaoxia , Wang Hua , Ge Qingfeng , Zhu Xinli 
Published: December 2022

AbstractReverse water gas shift (RWGS) reaction is an attractive approach to convert CO2 with renewable H2 to produce CO. However, this reaction is always accompanied by undesirable methanation reaction lowering the CO selectivity, particularly, at low reaction temperature and on Ni catalysts. Herein, a strategy of deposition of inert Ag on the surface of Ni to block methanation reaction during RWGS for selective conversion of CO2 toward CO was reported. Characterizations showed that in contrast to formation of bulk Ni−Ag alloy, both Ag particle and highly dispersed Ag are direct contacting with Ni particle. Surface Ag modifies the property of Ni geometrically and electronically, resulting in reduced accessible surface Ni sites and Ni ensemble size, as well as electron transfer from Ni to Ag. Consequently, both the amount and strength of CO adsorption are reduced, which facilitates CO desorption and reduces CO methanation activity. The Ag modification tunes Ni/SiO2 from selective methanation to selective RWGS, with 100 % CO selectivity on Ni‐0.3 Ag/SiO2 (Ag/Ni=0.3) at 400 °C with gas hourly space velocity (GHSV) >300 L g−1 h−1 and CO selectivity is >80.7 % even at a low GHSV of 15 L g−1 h−1. Moreover, the Ni‐0.3 Ag/SiO2 appears to be very stable for RWGS reaction.
Covalent Triazine Frameworks (CTFs): Synthesis, Crystallization, and Photocatalytic Water Splitting
Authors: Sun Ruixue , Tan Bien 
Published: December 2022

AbstractCovalent Triazine Frameworks (CTFs) have received great attention from academia owing to their unique structure characteristics such as nitrogen‐rich structure, chemical stability, fully conjugated skeleton and high surface area; all these unique properties make CTFs attractive for widespread applications, especially for photocatalytic applications. In this review, we aim to provide recent advances in the CTFs preparation, and mainly focus on their photocatalytic applications. This review provides a comprehensive and systematic overview of the CTFs’ synthetic methods, crystallinity lifting strategies, and their applications for photocatalytic water splitting. Firstly, a brief background including the photocatalytic water splitting and crystallinity are provided. Then, synthetic methods related to CTFs and the strategies for enhancing the crystallinity are summarized and compared. After that, the general photocatalytic mechanism and the strategies to improve the photocatalytic performance of CTFs are discussed. Finally, the perspectives and challenges of fabricating high crystalline CTFs and designing CTFs with excellent photocatalytic performance are discussed, inspiring the development of CTF materials in photocatalytic applications.
Confinement of Assemblies of Peptides by Chemical Reactions in Living Cells
Authors: Yang Xuejiao , Lu Honglei , Kong Nan , Wang Huaimin 
Published: December 2022

AbstractThe self‐assembly of peptides plays an important role in optics, catalysis, medicine, and disease treatment. In recent years, peptide‐based materials have exhibited great potential for cancer therapy and disease imaging due to their excellent biocompatibility, structural tenability, and ease of functionality. Peptides could self‐assemble into diverse nanostructures in vivo triggered by endogenous stimuli, which initiated chemical reactions and self‐assembled to achieve desired biological functions in the tumor microenvironment. This concept introduces the utilization of endogenous triggers to construct functional nanostructures in vivo and their corresponding biological applications. After briefly discussing the representative example of chemical reactions induced self‐assembly of peptides in the living system, we describe the several stimuli triggered self‐assembly for constructing therapeutic assemblies and serving as an imaging probe. Finally, we give a brief outlook to discuss the future direction of this exciting new field.
Molecular Design of A−D−A Electron Acceptors Towards Low Energy Loss for Organic Solar Cells
Authors: Guo Yuan , Zhu Lingyun , Duan Ruihong , Han Guangchao , Yi Yuanping 
Published: December 2022

AbstractLow energy loss is a prerequisite for organic solar cells to achieve high photovoltaic efficiency. Electron‐vibration coupling (i. e., intramolecular reorganization energy) plays a crucial role in the photoelectrical conversion and energy loss processes. In this Concept article, we summarize our recent theoretical advances on revealing the energy loss mechanisms at the molecular level of A−D−A electron acceptors. We underline the importance of electron‐vibration couplings on reducing the energy loss and describe the effective molecular design strategies towards low energy loss through decreasing the electron‐vibration couplings.
Adaptive fuzzy‐region growing fusion and improved CNN‐ANFIS‐based automated segmentation and classification of cervical cancer
Authors: J. Jeyshri , M. Kowsigan 
Published: December 2022

SummaryThe cervical cancer screening mechanisms help to classify cervical lesions into cancerous, precancerous, and normal. But, some of the classification approaches provide optimal outcomes based on the precise spotting and segmenting of cervical cancer. Moreover, still, challenges persist in the precise spotting of cervical cancer. The conventional screening methods for cervical cancer require more experienced pathologists, but it may also lead to poor efficiency and low accuracy. To overcome these issues, medical image processing introduces both machine learning and deep learning methods into cervical cell classification. The major scope of this task is to plan a new cervical cancer diagnosis method using intelligent approaches. Here, the segmentation of abnormality is done by the novel adaptive fuzzy‐region growing fusion model, which is improved by the hybridized optimization algorithm named gray wolf‐tunicate swarm algorithm (GW‐TSA). Then, the new ensemble classification termed Improved convolutional neural network with artificial neural network fuzzy inference system, which depends on the proposed GW‐TSA for performance enhancement through optimizing the hyperparameters. Finally, the simulation findings show that the designed approach is achievable and provides the highest accuracy rate in diagnosing cervical cancer.
Hydrogen Bonding versus Halogen Bonding: Spectroscopic Investigation of Gas‐Phase Complexes Involving Bromide and Chloromethanes
Authors: Robinson Hayden T. , Haakansson Christian T. , Corkish Timothy R. , Watson Peter D. , McKinley Allan J. , Wild Duncan A. 
Published: December 2022

AbstractHydrogen bonding and halogen bonding are important non‐covalent interactions that are known to occur in large molecular systems, such as in proteins and crystal structures. Although these interactions are important on a large scale, studying hydrogen and halogen bonding in small, gas‐phase chemical species allows for the binding strengths to be determined and compared at a fundamental level. In this study, anion photoelectron spectra are presented for the gas‐phase complexes involving bromide and the four chloromethanes, CH3Cl, CH2Cl2, CHCl3, and CCl4. The stabilisation energy and electron binding energy associated with each complex are determined experimentally, and the spectra are rationalised by high‐level CCSD(T) calculations to determine the non‐covalent interactions binding the complexes. These calculations involve nucleophilic bromide and electrophilic bromine interactions with chloromethanes, where the binding motifs, dissociation energies and vertical detachment energies are compared in terms of hydrogen bonding and halogen bonding.