bluuebunny/crossref_metadata_2025_split huggingface dataset:
Impoliteness Strategies Used by Sylvie Grateau Toward Emily Cooper in Emily in Paris Season One
Authors: Santoso Tania Silvia , Tedjaatmadja Herwindy Maria 
Published: October 2022

This descriptive-quantitative study is aimed at finding out the types of impoliteness super-strategies used by Sylvie toward her employee, Emily, in Emily in Paris season one, as well as the most and least frequently used types. The main theory used is Culpeper's (1996, 2005) impoliteness strategy. The findings reveal that Sylvie has implemented all five types of impoliteness super-strategies. The most common is negative impoliteness which most likely occurs because Sylvie always opposes Emily on purposes despite knowing how much Emily wants to be professionally acknowledged at Savoir. The least frequently used is withhold politeness, which might happen because although Sylvie is a generally nice person, she uses clearer impolite strategies to Emily on purpose. The writers conclude that Sylvie purposefully uses impoliteness strategies and adds impolite gestures, to bring Emily down and to emphasize her power to get rid of Emily from Savoir. Keywords: impoliteness, impoliteness strategy, status, utterance
An Annotated Translation of a Book Entitled Experiencing God in The Ordinary
Authors: Evelyn Marcella , Rini Julia Eka 
Published: October 2022

An annotated translation is based on notes and observations which the translator writes down in the process of translation, concentrating mainly on problematic passages or passages with interesting features relating to the topic of the project. In this project, the author translated a 215-page book entitled Experiencing God in The Ordinary from English as the source language (SL )to Bahasa Indonesia as the target language (TL) using the annotated translation method. Based on the translation result, she classified and explained the difficulties encountered by using Newmark’s four levels in translation: the textual, the referential, the cohesive, and the naturalness.
Triggering ZT to 0.40 by Engineering Orientation in One Polymeric Semiconductor
Authors: Wang Dongyang , Ding Jiamin , Dai Xiaojuan , Xiang Lanyi , Ye Dekai , He Zihan , Zhang Fengjiao , Jung Seok‐Heon , Lee Jin‐Kyun , Di Chong‐an , Zhu Daoben 
Published: October 2022

AbstractBreaking the thermoelectric (TE) trade‐off relationship is an important task for maximizing the TE performance of polymeric semiconductors. Existing efforts have focused on designing high‐mobility semiconductors and achieving ordered molecular doping, ignoring the critical role of the molecular orientation during TE conversion. Herein, the achievement of ZT to 0.40 is reported by fine‐tuning the molecular orientation of one diketopyrrolopyrrole (DPP)‐based polymer (DPP‐BTz). Films with bimodal molecular orientation yield superior doping efficiency by increasing the lamellar spacing and achieve increased splitting between the Fermi energy and the transport energy to enhance the thermopower. These factors contribute to the simultaneous improvement in the Seebeck coefficient and electrical conductivity in an unexpected manner. Importantly, the bimodal film exhibits a maximum power factor of up to 346 µW m−1 K−2, >400% higher than that of unimodal films. These results demonstrate the great potential of molecular orientation engineering in polymeric semiconductors for developing state‐of‐the‐art organic TE (OTE) materials.
Carbene Catalyzed Asymmetric Synthesis of Selenylated δ‐Lactones via [4+2] Annulation of Selenyl Vinyl Ketones and Enals
Authors: Verma Ram Subhawan , Talukdar Ranadeep , Azaz Tazeen , Tiwari Bhoopendra 
Published: October 2022

AbstractA direct (organo)catalytic method for the synthesis of chiral selenylated δ‐lactones via [4+2] annulation of selenyl vinyl ketones with enals has been achieved. The C5‐selenylated dihydropyranones were obtained in 54–88% yield with 90–99% enantioselectivity.magnified image
An activatable NIR‐II fluorescent probe for tracking heavy‐metal ion and high‐level salt‐induced oxidative stress in plant sprouts
Authors: Long Yi , Chen Junjie , Zeng Fang , Wu Shuizhu 
Published: October 2022

AbstractHumans and plants have become enfolded and inseparable. Abiotic stresses in particular oxidative stress caused by heavy‐metal ions or high‐level salt contamination deleteriously impact plants’ growth process and have become a major threat to sustaining food security. Sprouting is the first step in plants’ growth process. When plant sprouts endure oxidative stress induced by toxic heavy‐metal ions or high‐level salt, accelerated generation of reactive oxygen species (e.g., H2O2) occurs inside plant sprouts; hence in‐situ H2O2 in plant sprouts could serve as the in‐vivo biomarker for tracking the oxidative stress in plant sprouts. Herein, we design an activatable probe CT‐XA‐H2O2 to track the oxidative stress in plant sprouts via in vivo NIR‐II fluorescent imaging. In CT‐XA‐H2O2, cyano‐thiazole acts as the electron‐accepting moiety and xanthane‐aminodiphenyl as the electron‐donating moiety, and dioxaborolane as the biomarker‐responsive unit and fluorescence quencher. The probe CT‐XA‐H2O2 shows weak fluorescent emission. When H2O2 is present, the dioxaborolane in the probe is cleaved, consequently, the dye CT‐XA‐OH is generated and brings about significant fluorescent signals for detecting and imaging the in‐situ biomarker. Moreover, the aminodiphenyl group endues the chromophore (the activated probe) with aggregation‐induced emission characteristics, which ensures stronger fluorescence in the aggregated state in the aqueous milieu. The probe CT‐XA‐H2O2 has been employed in the Cd2+‐ion or high‐level salt (NaCl) induced oxidative stress models of soybean sprouts and peanut sprouts, and the experimental results evidently reveal the probe's ability for in‐situ biomarker‐activatable in‐vivo detection and imaging in the plants' sprouts.
Fast‐current‐driven synthesis of ultrathin ZIF‐8 membrane on ceramic tube for propene/propane separation
Authors: Zhao Yali , Yang Xiayi , Luo Jiayu , Wei Yanying , Wang Haihui 
Published: October 2022

AbstractMOF membranes are very promising in molecular separation, but it is still a challenge for industrial applications due to the complex and time‐consuming synthesis. We use the fast current‐driven synthesis (FCDS) method to achieve controlled growth of ZIF‐8 membranes on porous graphite‐coated ceramic tubes by controlling the growth time and current density. Grown for 30 min at a current density of 0.74 mA/cm2, the ZIF‐8 membrane exhibits selectivity for C3H6/C3H8 up to 63 with C3H6 permeance of 6 × 10−9 mol/(m2 s Pa). Furthermore, the ZIF‐8 membrane exhibits a pressure resistance of up to 3 bar and good stability of ~96 h. This work realizes the breakthrough of the MOF membrane synthesis via FCDS method from the frequently‐used expensive and fragile anodic aluminum oxide (AAO) disc substrate to the tough ceramic tubular substrate, which broadens the road for the industrialization of MOF membranes in gas separation fields.
Secondary Phosphine Sulfide‐Enabled Iridium‐Catalyzed Asymmetric Allylic Substitution
Authors: Wu Zeng‐Hua , Wang Huai‐Yu , Yang Huai‐Lan , Wei Li‐Hua , Hayashi Tamio , Duan Wei‐Liang 
Published: October 2022

AbstractAn iridium‐catalyzed asymmetric synthesis of branched allylic phosphine compounds under mild conditions is reported. Products bearing various functional groups can be synthesized with excellent stereoselectivity (up to 99.9 % ee) and regioselectivity. The employment of phosphine sulfides with relatively low deactivation capacity against metal catalysts is crucial for the success of this reaction.
Quorum sensing unveils the sludge floccule‐assisted stabilization of aerobic granules in granule‐dominated sequencing batch reactors
Authors: Li Yu‐Sheng , Li Bing‐Bing , Tian Tian , Yu Han‐Qing 
Published: October 2022

AbstractFloccules are another major form of microbial aggregates in aerobic granular sludge systems. Previous studies mainly attributed the persistence of floccules to their relatively faster nutrient uptake and higher growth rate over aerobic granules; however, they failed to unravel the underlying mechanism of the long‐term coexistence of these two aggregates. In this work, the existence and function of the floccules in an aerobic granule‐dominated sequencing batch reactor were investigated from the view of quorum sensing (QS) and quorum quenching (QQ). The results showed that though the floccules were closely associated with the granules in terms of similar community structures (including the QS‐ and QQ‐related ones), they exhibited a relatively higher QQ‐related activity but a lower QS‐related activity. A compatible proportion of floccules might be helpful to maintain the QS‐related activity and keep the granules stable. In addition, the structure difference was demonstrated to diversify the QS‐ and QQ‐related activities of the floccules and the aerobic granules. These findings could broaden our understanding of the interactions between the coexistent floccules and granules in aerobic granule‐dominated systems and would be instructive for the development of the aerobic granular sludge process.
The relationship between dietary patterns and aggressive behavior in adolescent girls: A cross‐sectional study
Authors: Malekahmadi Mahsa , Khayyatzadeh Sayyed Saeid , Heshmati Javad , Alshahrani Shadia Hamoud , Oraee Nikzad , Ferns Gordon A. , Firouzi Safieh , Pahlavani Naseh , Ghayour‐Mobarhan Majid 
Published: October 2022

AbstractBackgroundThere are few studies about the relationship between dietary patterns and aggression. The aim of this study was to assess the relationship between the main dietary patterns and aggression scores among adolescent girls in Iran.MethodsThis cross‐sectional study was conducted on 670 adolescent girls. The 168‐item self‐administered Semi‐quantitative Food Frequency Questionnaire was used to evaluate dietary intake and to identify major dietary patterns, while factor analysis was applied. Aggression was evaluated by the validated Persian version of the Buss‐Perry questionnaire. Statistical analysis was performed by crude and adjusted models.ResultsThree main dietary patterns including healthy, fast food, and Western were identified. A significant positive association was found between more adherence to Western dietary pattern and the presence of a high aggression score (OR: 2.00; 95% CI: 1.32–3.05, p‐trend = .001); even after adjustment for potential confounders, these findings were significant.ConclusionAlthough Western dietary patterns were associated with increased aggression risk, there was no significant relationship between healthy and fast food dietary patterns and the prevalence of a high aggression score. Further studies, particularly longitudinal intervention studies, are required to clarify this relationship.
Bimetallic CuSbSe2: A Potential Anode Material for Sodium and Lithium‐Ion Batteries with High‐Rate Capability and Long‐Term Stability
Authors: Hui Da , Chen Xi , Bian Xiaofei , He Chunfeng , Yao Shiyu , Chen Gang , Du Fei 
Published: October 2022

AbstractBimetallic transition metal chalcogenides (TMCs) materials have emerged as attractive anodes for lithium‐ion batteries (LIBs) and sodium‐ion batteries (SIBs) because of the high intrinsic electronic conductivity, rich redox sites and unique reaction mechanism. In this work, we report the synthesis and electrochemical properties of a novel bimetallic TMCs material CuSbSe2. The as‐prepared anode delivers a high reversible capacity of 545.6  mA h g−1 for SIBs and 592.6  mA h g−1 for LIBs at a current density of 0.2 A g−1, and an excellent rate capability of 425.9  mA h g−1 at 20 A g−1 for SIBs and 226.0  mA h g−1 at 10 A g−1 for LIBs without any common‐used surface modification or carbonaceous compositing. In addition, ex situ X‐ray diffraction (XRD) and High‐resolution transmission electron microscopy (HRTEM) reveal a combined conversion‐alloying reaction mechanism of LIBs and NIBs. Our findings suggest bimetallic CuSbSe2 could be a potential anode material for both SIBs and LIBs.
Complete tumor necrosis after neoadjuvant chemotherapy defines good responders in patients with Ewing sarcoma
Authors: Lozano‐Calderón Santiago A. , Albergo Jose Ignacio , Groot Olivier Q. , Merchan Nelson A. , El Abiad Jad M. , Salinas Vanessa , Gomez Mier Luis Carlos , Montoya Camilo Soto , Ferrone Marco L. , Ready John E. , Linares Francisco J. , Levin Adam S. , Peleteiro Pensado Manuel , Pozo Kreilinger José Juan , Ruiz Irene Barrientos , Ortiz‐Cruz Eduardo J. , Gebhardt Mark C. , Cote Gregory M. , Choy Edwin , Spentzos Dimitrios , Hung Yin P. , Deshpande Vikram , Chebib Ivan A. , McCulloch Robert Allan , Farfalli Germán , Aponte Tinao Luis , Morris Carol D. , Petur Nielsen Gunnlaugur , Anderson Megan E. , Jeys Lee M. 
Published: October 2022

AbstractBackgroundSurvival in patients who have Ewing sarcoma is correlated with postchemotherapy response (tumor necrosis). This treatment response has been categorized as the response rate, similar to what has been used in osteosarcoma. There is controversy regarding whether this is appropriate or whether it should be a dichotomy of complete versus incomplete response, given how important a complete response is for in overall survival of patients with Ewing sarcoma. The purpose of this study was to evaluate the impact that the amount of chemotherapy‐induced necrosis has on (1) overall survival, (2) local recurrence‐free survival, (3) metastasis‐free survival, and (4) event‐free survival in patients with Ewing sarcoma.MethodsIn total, 427 patients who had Ewing sarcoma or tumors in the Ewing sarcoma family and received treatment with preoperative chemotherapy and surgery at 10 international institutions were included. Multivariate Cox proportional‐hazards analyses were used to assess the associations between tumor necrosis and all four outcomes while controlling for clinical factors identified in bivariate analysis, including age, tumor volume, location, surgical margins, metastatic disease at presentation, and preoperative radiotherapy.ResultsPatients who had a complete (100%) tumor response to chemotherapy had increased overall survival (hazard ratio [HR], 0.26; 95% CI, 0.14–0.48; p < .01), recurrence‐free survival (HR, 0.40; 95% CI, 0.20–0.82; p = .01), metastasis‐free survival (HR, 0.27; 95% CI, 0.15–0.46; p ≤ .01), and event‐free survival (HR, 0.26; 95% CI, 0.16–0.41; p ≤ .01) compared with patients who had a partial (0%–99%) response.ConclusionsComplete tumor necrosis should be the index parameter to grade response to treatment as satisfactory in patients with Ewing sarcoma. Any viable tumor in these patients after neoadjuvant treatment should be of oncologic concern. These findings can affect the design of new clinical trials and the risk‐stratified application of conventional or novel treatments.
N,S‐co‐doped FeCo Nanoparticles Supported on Porous Carbon Nanofibers as Efficient and Durable Oxygen Reduction Catalysts
Authors: Son Dong‐kyu , Bae Sooan , Nithya Jeghan Shrine Maria , Lee Gibaek 
Published: October 2022

AbstractFinding high‐performance, low‐cost, efficient catalysts for oxygen reduction reactions (ORR) is essential for sustainable energy conversion systems. Herein, highly efficient and durable iron (Fe) and cobalt (Co)‐supported nitrogen (N) and sulfur (S) co‐doped three‐dimensional carbon nanofibers (FeCo−N, S@CNFs) were synthesized via electrospinning followed by carbonization. The as‐prepared FeCo−N,S@CNFs served as efficient ORR catalysts in alkaline 0.1 m KOH solutions that were N2 and O2‐saturated. The experimental results revealed that FeCo−N,S@CNFs were highly active ORR catalysts with defect‐rich active pyridinic N and pyrrolic N and metal bonds to N and S atom sites, which enhanced the ORR activity. FeCo−N,S@CNFs exhibited a high onset potential (Eonset=0.89 V) and half‐wave potential (E1/2=0.85 V), similar to the electrocatalytic activity of commercial Pt/C. Additionally, the durability of the as‐prepared FeCo−N,S@CNFs catalysts was maintained for 14 h with long‐term stability and high tolerance to methanol stability, accounting for their excellent catalytic ability. Furthermore, Co−N@CNFs, Fe−N@CNFs, and varying Fe and Co ratios were compared with those of FeCo−N,S@CNFs. Synergistic interactions between metals and heteroatoms were believed to play a significant role in enhancing the ORR activity. Owing to their excellent catalytic reduction ability, the as‐prepared FeCo−N,S@CNFs can be widely used in battery‐based systems and replace commercial Pt/C in fuel cell applications.
Electrochemical and spectral studies of rhodanine in view of heavy metals determination
Authors: Matica Ovidiu Teodor , Brotea Alina Giorgiana , Ungureanu Eleonora‐Mihaela , Mandoc Luisa Roxana , Birzan Liviu 
Published: October 2022

AbstractThe electrochemical study of 2‐Sulfanylidene‐1,3‐thiazolidin‐4‐one (rhodanine, R) was performed on a glassy carbon working electrode by using three methods: differential pulse voltammetry (DPV), cyclic voltammetry (CV), and linear sweep voltammetry (LSV) at rotating disk electrode voltammetry (RDE). The CV, DPV, and LSV at RDE curves for R were recorded at different concentrations in 0.1 M TBAP/CH3CN. Polymeric films were formed by successive cycling at different potentials and by controlled potential electrolysis. The film formation was proved by recording the CV curves of the chemically modified electrodes (CMEs) in transfer solutions containing ferrocene in 0.1 M TBAP/CH3CN. The obtained CMEs were used for the detection of heavy metal ions. Synthetic samples of heavy metal ions (Cd (II), Pb (II), Cu (II), Hg (II)) of concentrations between 10−7 and 10−5 M were analyzed using CMEs prepared in different conditions. The most intense signal was obtained for Pb(II) ion (estimated detection limit = 10−7 M), which shows that these CMEs can be used for Pb(II) ion detection. The ability of R to form complexes with Pb(II) ion was also tested by UV‐Vis spectrometry. The obtained results showed the formation of Pb(II)R2 as the most stable complex.
Feasibility, safety, and tolerability of two modalities of plasma exchange with albumin replacement to treat elderly patients with Alzheimer's disease in the AMBAR study
Authors: Boada Mercè , Kiprov Dobri , Anaya Fernando , López Oscar L. , Núñez Laura , Olazarán Javier , Lima José , Grifols Carlota , Barceló Miquel , Rohe Regina , Prieto‐Fernández Cristina , Szczepiorkowski Zbigniew M. , Páez Antonio 
Published: October 2022

AbstractBackgroundIn the Alzheimer Management by Albumin Replacement (AMBAR) study, mild‐to‐moderate Alzheimer's disease (AD) patients were treated with a plasma exchange (PE) program. Feasibility and safety of PE in this specific population are poorly understood and were analyzed in detail in this study.MethodsQualified patients were treated with 6 weeks of weekly conventional therapeutic plasma exchange (TPE) with albumin replacement followed by monthly low‐volume plasma exchange (LVPE) for 12 months. The patients were divided into four groups: placebo (sham PE treatment), low‐albumin (20 g), low‐albumin + intravenous immunoglobulin (IVIG) (10 g), and high‐albumin (40 g) + IVIG (20 g). Adverse events (AEs) were recorded and analyzed for all PE treatment groups and PE modalities.ResultsPE procedure‐related AEs were more common in the active treatment groups (16.9% out of 1283 TPE and 12.5% out of 2203 LVPE were associated with at least one AE, a similar rate than in other PE indications) than in the placebo group (0.7% out of 1223 sham PE). Percentage of procedures with at least one AEs was higher with central venous access compared to peripheral venous access in all three active treatment groups (20.1% vs 13.1%, respectively).ConclusionThe TPE and LVPE procedures used in the AMBAR study on mild‐to‐moderate AD population were as safe and feasible as in other therapeutic applications of PE or routine plasmapheresis.
Parents' willingness to vaccinate themselves and their children with the booster vaccine against SARS‐CoV‐2: A cross‐sectional study in Puyang city, China
Authors: Zhou Yiguo , Li Guo‐Xing , Zhao Tian‐Shuo , Du Juan , Zhang Wan‐Xue , Xie Ming‐Zhu , Chen Lin‐Yi , Zeng Jing , Wang Chao , Liu Bei , Liu Ya‐Qiong , Cui Fuqiang , Lu Qing‐Bin 
Published: October 2022

AbstractWe aimed to investigate the hesitancy and willingness of parents to vaccinate themselves and their children with a booster dose against severe acute respiratory syndrome coronavirus 2 and related factors. We conducted a cross‐sectional study in Puyang city, China. The information was collected, including demographic characteristics, willingness to receive a booster dose of coronavirus disease 2019 (COVID‐19) vaccine, and attitudes and concerns toward COVID‐19 and vaccines. Vaccine hesitancy was assessed in individuals completing the first two doses and booster eligible, while vaccine willingness was assessed in those completing the first two doses and not yet booster eligible. Among the participants completing two primary doses while not meeting the booster criteria, 95.4% (1465/1536) and 95.0% (1385/1458) had a willingness to a booster dose of COVID‐19 vaccine for themselves and their children, respectively. Among the participants who met the booster criteria, 40.3% had vaccine hesitancy. Vaccine hesitancy and unwillingness tended to occur in people who were younger, less educated, less healthy, and with unsureness of vaccines' efficacy and adverse events (AE). The younger age of children, children in poorer health, and concern about the efficacy and AE of vaccines contributed to the participants' unwillingness to vaccinate their children. We observed a high willingness to the booster dose of COVID‐19 vaccine both for the parents and their children, regardless of the eligibility to a booster dose. However, 40% of people had delayed vaccination behaviors. The promotion of scientific knowledge of vaccines' effectiveness and safety is needed, especially for people in poor health and parents with young children. Timely disclosure of AE caused by COVID‐19 vaccines and proper aiding offered to people encountering AE are suggested.
Critical appraisal in ecology: What tools are available, and what is being used in systematic reviews?
Authors: Stanhope Jessica , Weinstein Philip 
Published: October 2022

AbstractMany reviews referred to as ‘systematic reviews’ in ecology are not consistent with best practice in that they generally lack appropriate critical appraisal of included studies. This limitation is particularly important in applied ecology, where there have been increasing calls for more systematic reviews to guide decision making. To identify the available critical appraisal tools (CATs) and hierarchies of evidence available for ecology studies, we systematically searched for: studies that described the development and/or examination of tools to assess the potential methodological bias in studies of ecology; and the tools used to assess potential methodological bias of included studies in ecological systematic reviews. We identified 680 reviews labelled as ‘systematic reviews’ in ecology, however only 4.0% performed critical appraisal of the included studies. Three hierarchies of evidence and 23 CATs were identified, and assessed as lacking independent development, validity and reliability testing, and/or completeness. The authors of the reviews that included critical appraisal have appropriately identified the need to move reviews in ecology in the direction of this higher level of evidence, and have taken applied ecology further in the direction of evidence‐based practice. However, we identified shortcomings in these approaches when compared with best practice, and conclude that new tools are needed that reflect a range of questions posed in ecology. Through increasing the availability of such tools, the strength of evidence provided by systematic reviews in ecology would improve.