bluuebunny/crossref_metadata_2025_split huggingface dataset:
Recent Advancement in Metal‐Organic Framework for Water Electrolysis: A Review
Authors: Khan Sadia , Noor Tayyaba , Iqbal Naseem , Pervaiz Erum 
Published: May 2022

AbstractAn alternative to fossil fuel is essential to overcome energy shortages and resolve the environmental problem. Hydrogen production via earth‐abundant water resources is a clean, sustainable, and energy‐rich fuel source. For the water splitting process, the catalyst is an essential need to enhance the kinetics of the overall reaction. Therefore, noble metals are used as the state‐of‐the‐art catalyst for the OER and HER process due to their remarkable efficiency and stability. But, their high cost and inadequacy are the main obstructs to their commercialization. To commercialize the process, researchers are trying to replace the expensive noble catalyst with a non‐noble stable, conductive, and more productive catalyst. In recent decades, transition metal based metal organic framework (MOF) has been extensively used as an electro‐catalyst to enhance the kinetics of the OER and HER process. MOF as an electro‐catalyst is a promising candidate to improve the rate of water splitting reaction due to their inherent properties such as high surface area, tunable morphology, and high porosity. In this review, the significant data of recent years are assembled for the water splitting process by using the MOFs as an electro‐catalyst. This review not only captures the advancement in MOF materials with the effective approach of designing but also indicates the catalyst evaluation parameters and detailed mechanism of the HER and the OER process. Meanwhile, challenges and future prospectus of the MOF based catalyst for the water splitting process are also described here. Hopefully, this review article will help to develop a more productive MOF for the generation of green and sustainable hydrogen.
Partial afforestation has uncertain effect on flood frequency and peak discharge at large catchment scales (100–1000 km2), south‐central Chile
Authors: Bathurst James C. , Hagon Hannah , Hambly Barton Frederick , Iroumé Andrés , Kilbride Aidan , Kilsby Chris 
Published: May 2022

AbstractAn extensive programme of commercial afforestation in south‐central Chile provides a unique opportunity to extend the field‐based understanding of forest impact on floods to the large catchment scale (100–1000 km2). Until now, much of that understanding has been limited to small catchments (<10 km2). Data for an approximately 50‐year period are analysed systematically for four catchments (434–1545 km2) with 18%–54% increases in forest cover. For each catchment, the forest impact is quantified by pairing annual maximum flood frequency curves and peak discharge/storm rainfall relationships for the pre‐ and post‐afforestation periods. These periods are themselves defined using land use surveys and cumulative double mass curves for runoff and rainfall. Scaling the frequency curves with a discharge corresponding to mean annual rainfall normalizes for rainfall differences and thus isolates the effect of forest cover. Partial afforestation rates of up to 50%, while markedly affecting annual evapotranspiration and runoff, have less certain effects on peak discharges. Downward shifts in the flood frequency curves occur following afforestation but appear more readily explained by changes in rainfall regime. These changes include a small decline in annual rainfall and a downward shift in some of the frequency curves for the storm rainfall totals corresponding to the annual maximum discharges. Nevertheless, some forest impact cannot be ruled out and the effect of a 100% change in forest cover on flood response remains unknown. The results suggest complexity in large catchment flood response and provide only weak support for afforestation with the sole purpose of reducing flood peaks at the large catchment scale. This is a significant conclusion, given that it challenges the largely uncritical view among the public, governments and development agencies worldwide that forests prevent floods.
Supporting early infant relationships and reducing maternal distress with the Newborn Behavioral Observations: A randomized controlled effectiveness trial
Authors: Nicolson Susan , Carron Sarah‐Pia , Paul Campbell 
Published: May 2022

AbstractResearch points to the significant impact of maternal distress on the parent‐infant relationship and infant development. The Newborn Behavioral Observations (NBO) is a brief intervention supporting the infant, the parent and their relationship. This randomized controlled trial examined the effectiveness of the NBO in a population with antenatal distress and risk of postnatal depression (PND). Pregnant, first‐time mothers with current anxiety or depression symptoms or past mental illness were recruited from two Australian hospitals. Participants received three NBO sessions in the first month of life plus treatment as usual (TAU), or, TAU‐only. Outcomes assessed at infant age 4 months included mother‐infant interaction quality; maternal anxiety and depression symptoms; and depression diagnosis. Of 111 pregnant individuals randomized, 90 remained eligible and 74 completed the trial (82.2% retention). There were intervention effects on emotional availability F(6, 67) = 2.52, p = .049, Cohen's d = .90, with higher sensitivity and non‐intrusiveness in the intervention group (n = 40) than the comparison group (n = 34). There was an intervention effect approaching significance for anxiety symptoms at 4 months (p = .06), and a significant effect over time (p = .014), but not for depression symptoms. Anxiety and depression symptoms significantly reduced to sub‐clinical levels within the intervention group only. There were fewer depression diagnoses (n = 6) than expected across groups, with no observed intervention effect. No adverse intervention effects were seen. Exploratory analysis of sensory processing sensitivity suggested differential susceptibility to distress and intervention benefits. The NBO was accepted and exerted meaningful effects on relationship quality and distress; and may enhance the infant's interaction experience and maternal emotional adjustment in at‐risk populations.
Pharmacist strategies for addressing medication cost barriers to equitable health in primary care
Authors: Westerhof Lindsey , Misher Anne , Fulbright April 
Published: May 2022

AbstractCost can be a barrier to achieving health equity for guideline‐directed medical therapy; however, ambulatory care pharmacists who provide services in primary care settings can assist in reducing these barriers. Strategies to reduce drug cost should be tailored to patient‐specific factors including insurance type, drugs being prescribed, and availability of local and national assistance programs. Pharmacists can use a team‐based approach, when possible, to promote health equity in drug access due to cost. The authors provide recommendations that can be incorporated into clinical practice and improve health equity.
Residential mobility or mobile residentiality? Exploring the effects of place stability and variety in consumer psychology
Authors: Wang Yajin 
Published: May 2022

AbstractEstablishing a new residence is a life‐changing event with a significant impact on people's psychology and behavior. However, digitalization, the sharing economy, and flexible working conditions have made it easier for people to move, and some people have even abandoned the concept of a permanent residence and adopted a new lifestyle—“mobile residentiality”—in which they seek residence only rarely and temporarily. This article explores the effects of place stability and variety on the consumer's self and identity, social relationships and networks, and personal and societal well‐being.
Advanced Bionics HiRes Ultra and Ultra 3D Series Cochlear Implant Recall: Time Course of Anomalies
Authors: Gärtner Lutz , Lenarz Thomas 
Published: May 2022

ObjectivesTo estimate median survival time until the appearance of anomalies indicating a potential implant failure associated with fluid ingress in implanted cochlear implant (CI) devices of the initial version of Advanced Bionics HiRes Ultra and HiRes Ultra 3D series.Study DesignRetrospective review.MethodsCochlear implantation was performed in a standard fashion. Implant integrity was tested at follow‐up visits by measuring impedance and electrically evoked compound action potential (ECAP). Additional tests such as electrical field imaging (EFI) were conducted by the manufacturer. Based on these tests, the presence or absence of an anomaly was classified.ResultsOf the 349 devices implanted at this institution, 181 showed anomalies in accordance with the special failure mode and for this reason, 120 implants were already explanted. The median survival time without anomalies was 1062 days. So far, the suspicion of device failures has been confirmed in all cases in which a post‐implantation analysis was already available.ConclusionsRegular tests at the follow‐up visits are necessary to monitor the integrity of CIs.Level of Evidence3 Laryngoscope, 132:2484–2490, 2022
3D Engineering of Orbital Angular Momentum Beams via Liquid‐Crystal Geometric Phase
Authors: Liu Si‐Jia , Chen Peng , Ge Shi‐Jun , Zhu Lin , Zhang Yi‐Heng , Lu Yan‐Qing 
Published: May 2022

AbstractOrbital angular momentum (OAM) provides a novel degree of freedom for light, deeply inspiring versatile light‐matter interactions and large‐density multiplexing computing. Recently, multimode and multichannel control of OAM beams have aroused extensive curiosity, whereas their flexible engineering in 3D space still remains challenging. Here, a new type of liquid‐crystal geometric phase optical elements is demonstrated to achieve on‐demand 3D tailoring of OAM beams. Via integrating binary and continuous phase patterns into photo‐aligned liquid crystals, customized 3D lattices of identical or propagation‐variant OAM beams are generated in an electrically tunable broadband manner. By altering the incident spin, these volumetric OAM beams can be switched among different states on the higher‐order Poincaré sphere. This work demonstrates a practical approach toward efficient OAM harnessing with large channel capacity and high spatial mode diversity, holding great potential for 3D optical manipulation, recording, and microscopy.
THE HIDDEN POWERS OF VULNERABILITY AND HUMILITY
Authors: Mohan Shantha 
Published: May 2022

AbstractThe author adapts lessons from her new book Leadership Lessons with The Beatles, drawing on what she’s learned from that iconic band, and how it can be applied by organizations and individual leaders. She writes from the perspective of an engineer who became a global software leader. The two Beatles song titles she writes about here are “Help!” for vulnerability, and “Within You and Without You,” for humility. She also writes about her own leadership journey, and discusses principles of mentorship and collaboration. She uses the example of a product manager, and how that person’s work fits into an organization. She writes that the “role of a product manager in a technical organization provides a great example of a vulnerable leader.” For humility, she writes about a leader she knows who embodies that term: Anand Deshpande, founder, chair, and managing director of the software firm Persistent Systems in India, a publicly traded global technology service provider. The characteristics of humility that she further describes are self‐awareness, gratitude, integrity, learning, and listening. Within learning, she writes: “Read voraciously. Reflect on what you read and then write. Your thoughts are clarified, and you can make sense of what you read when you do. Influential leaders are lifelong learners.”
Design and implementation of static 2:1 frequency divider based on GaAs pHEMT
Authors: Zhao Ranran , Zhang Yuming , Lu Hongliang , Wu Yue 
Published: May 2022

AbstractThis study presents a low phase noise static 2:1 frequency divider in a 0.15 µm gallium arsenide pseudomorphic high electron mobility transisitor process. The proposed divider is based on an improved source coupled logic structure. The maximum bandwidth utilization of the frequency divider is improved up to 100% through theoretical analysis. This frequency divider with low phase noise achieves an operating frequency of direct current ~4.8 GHz for 0 dBm input, and the phase noise is −131.06 dBc/Hz@10 MHz. The chip area is 0.624 × 0.923 mm.
Convergence analysis of vector extended locally optimal block preconditioned extended conjugate gradient method for computing extreme eigenvalues
Authors: Benner Peter , Liang Xin 
Published: May 2022

AbstractThis article is concerned with the convergence analysis of an extension of the locally optimal preconditioned conjugate gradient method for the extreme eigenvalue of a Hermitian matrix polynomial that possesses some extended form of Rayleigh quotient. This work is a generalization of the analysis by Ovtchinnikov (SIAM J Numer Anal. 2008;46(5):2567–92.). As instances, the algorithms for definite matrix pairs and hyperbolic quadratic matrix polynomials are shown to be globally convergent and to have an asymptotically local convergence rate. Also, numerical examples are given to illustrate the convergence behavior.
Compassion satisfaction and compassion fatigue in haematology cancer nurses: A cross‐sectional survey
Authors: Chen Fengjiao , Leng Yamei , Li Jiping , Zheng Yuhuan 
Published: May 2022

AbstractAimThis study aimed to investigate compassion satisfaction (CS) and compassion fatigue (CF) in haematology nurses and their associated factors.DesignA cross‐sectional survey.MethodsThe survey was conducted on 336 haematology nurses from 21 hospitals in Sichuan, China. The CS and CF were assessed by the Professional Quality of Life Scale version 5. The CF was determined by burnout and secondary traumatic stress.ResultsHaematology nurses in China had moderate levels of CS and moderate‐to‐low CF. Better nursing competence of teaching/consultation and communication/coordination and the percentage of critically ill patients >60% predicted higher CS. The permanent nurse, better nursing competence of communication/coordination and specialized clinical practice predicted less burnout, while working >40 hr per week or more nurse‐patient conflict events predicted more burnout. In addition, working >40 hr per week, more nurse‐patient conflict events and having the need of psychological support predicted higher secondary traumatic stress.
Structures of becoming: The who, what, and how of holistic science advising
Authors: Dodo Seriki Vanessa , McDonald Scott 
Published: May 2022

AbstractAddressing equity issues in science education requires a reorientation to how science students are advised and how science, technology, engineering, and mathematics (STEM) education, particularly science, is viewed. STEM education is often figuratively described as a pipeline containing students who leak out before reaching the nexus of their STEM education/career journey. The authors of this paper argue that STEM education must be viewed from an ecosystems perspective, where students interact with one another, their physical environment and cultural contexts, and other humans who can support them in becoming STEM professionals. Within this STEM ecosystem, many individuals have a pivotal role in supporting students as they learn and develop within the science field. These individuals, particularly advisors, must possess knowledge, beliefs, skills, and dispositions that help students cultivate a sense of belonging, engage them in critical thinking about their academic and career choices, and aid their identity development in learning as becoming in STEM professions. The authors describe who these individuals are, the roles they play, and also provide practical examples, using vignettes, of how advisors can support students of color pursuing science degrees and careers. Finally, recognizing that students' STEM advising ecosystem operates at any grade level or stage of life, the authors have organized the descriptive portion of this study according to the following levels elementary, secondary, undergraduate, graduate, and career.
Element‐Doped Mxenes: Mechanism, Synthesis, and Applications
Authors: Wang Ronghao , Li Muhan , Sun Kaiwen , Zhang Yuhao , Li Jingfa , Bao Weizhai 
Published: May 2022

AbstractHeteroatom doping can endow MXenes with various new or improved electromagnetic, physicochemical, optical, and structural properties. This greatly extends the arsenal of MXenes materials and their potential for a spectrum of applications. This article comprehensively and critically discusses the syntheses, properties, and emerging applications of the growing family of heteroatom‐doped MXenes materials. First, the doping strategies, synthesis methods, and theoretical simulations of high‐performance MXenes materials are summarized. In order to achieve high‐performance MXenes materials, the mechanism of atomic element doping from three aspects of lattice optimization, functional substitution, and interface modification is analyzed and summarized, aiming to provide clues for developing new and controllable synthetic routes. The mechanisms underlying their advantageous uses for energy storage, catalysis, sensors, environmental purification and biomedicine are highlighted. Finally, future opportunities and challenges for the study and application of multifunctional high‐performance MXenes are presented. This work could open up new prospects for the development of high‐performance MXenes.
Inositol hexakisphosphate primes syndapin I/PACSIN 1 activation in endocytosis
Authors: Shi Yue , Zhao Kaixuan , Yang Guang , Yu Jia , Li Yuxin , Kessels Michael M. , Yu Lina , Qualmann Britta , Berggren Per-Olof , Yang Shao-Nian 
Published: May 2022

AbstractEndocytosis is controlled by a well-orchestrated molecular machinery, where the individual players as well as their precise interactions are not fully understood. We now show that syndapin I/PACSIN 1 is expressed in pancreatic β cells and that its knockdown abrogates β cell endocytosis leading to disturbed plasma membrane protein homeostasis, as exemplified by an elevated density of L-type Ca2+ channels. Intriguingly, inositol hexakisphosphate (InsP6) activates casein kinase 2 (CK2) that phosphorylates syndapin I/PACSIN 1, thereby promoting interactions between syndapin I/PACSIN 1 and neural Wiskott–Aldrich syndrome protein (N-WASP) and driving β cell endocytosis. Dominant-negative interference with endogenous syndapin I/PACSIN 1 protein complexes, by overexpression of the syndapin I/PACSIN 1 SH3 domain, decreases InsP6-stimulated endocytosis. InsP6 thus promotes syndapin I/PACSIN 1 priming by CK2-dependent phosphorylation, which endows the syndapin I/PACSIN 1 SH3 domain with the capability to interact with the endocytic machinery and thereby initiate endocytosis, as exemplified in β cells.
Predictive Value of Plasma Copeptin Level in Children with Acute Heart Failure
Authors: El Amrousy Doaa , Abdelhai Dina , Nassar Mohammed 
Published: May 2022

AbstractWe investigated the ability of copeptin level to predict adverse outcome in pediatric heart failure (HF) and correlated copeptin level with various clinical and echocardiographic data. This cohort study was carried out on forty children with clinical picture of acute HF as the patient group and forty healthy children of matched age and sex as the control group. Echocardiographic examination and plasma copeptin level were performed for all included children at admission. Patients were followed up for 6 months for mortality or readmission. Plasma copeptin level was significantly higher in the patient group (16.2 ± 5) pmol/L compared to the control group (4.1 ± 2.3) pmol/L, P ˂0.001. Moreover, copeptin level was positively correlated with Ross classification, being the highest in patients with class IV (19.6 ± 3.9) pmol/L compared to those with class III (15.2 ± 4) pmol/L and class II (10.4 ± 1.5) pmol/L. Copeptin levels were significantly higher in patients with bad prognosis (21.2 ± 4.1) pmol/L compared to those with good prognosis (14.5 ± 4.1) pmol/L, P ˂0.001. Copeptin level had a significant positive correlation with age, heart rate, respiratory rate, and ROSS classification. On the contrary, copeptin level had a significant negative correlation with left ventricular fraction shortening and diastolic function. Copeptin at cut-off value of ≥ 19.5 pmol/L yielded a sensitivity of 75% and a specificity of 93% to predict adverse outcome in children with HF. Plasma copeptin level has a good prognostic value to predict adverse outcome in pediatric heart failure. Moreover, copeptin correlate well with the severity of pediatric HF.
Posterior pharyngeal wall augmentation in post-adenoidectomy velopharyngeal insufficiency
Authors: Amer Ayman , Saqr Anas Magdy , Zayed Ahmed Mohamed , El-Kotb Mohamed , Elsobki Ahmed 
Published: May 2022

Abstract
Purpose
To assess the efficacy of posterior pharyngeal wall augmentation using septal or conchal cartilages with other bulks—according to the persistent gap and the individual anatomy of each patient—in improving velopharyngeal function in patients who acquired persistent velopharyngeal insufficiency (VPI) post-adenoidectomy.

Methods
Observational descriptive prospective case series of 24 patients (their ages ranged between 3 and 26 years) who developed persistent VPI post-adenoidectomy (more than 3 months) although they had normal speech resonance before adenoidectomy.

Results
The present study demonstrated that statistically significant improvement in auditory perceptual assessment (APA) was found regarding all obligatory speech disorders and unintelligibility of speech. Significant improvement was observed in the degree of velar mobility, size of the persistent gap, and the gap distance between velum and posterior pharyngeal wall at rest and during phonation in post-operative evaluation versus pre-operative. A significant change was observed in the closure pattern of the velopharyngeal port (VPP) as all patients turned to coronal closure.

Conclusions
Posterior pharyngeal wall augmentation could be used in VPI post-adenoidectomy up to 7 mm and lead to better speech outcomes. Also, it revealed that using conchal and/or septal cartilage as a graft regardless of the patient’s age is a safe procedure.