bluuebunny/crossref_metadata_2025_split huggingface dataset:
FEATURES OF FORMATION OF BASIC PARAMETERS OF THE SPECIALIZED MARINE TRANSPORT FLEET
Authors: Golubkova Iryna , Frasyniuk Tatyana , Babachenko Maryna , Yavorska Anastasiia , Levinska Tetyana 
Published: July 2022

The article discusses the basic principles of optimizing the status of subsystems of the marine transport industry. Since the positioning of stability management in any segment of transport activities reflects a system of principles, a system of the interdependence of structural elements of merchant shipping was identified. Taking into account the most important provisions for managing the economic stability of shipping and the principles of repayable financing, urgent problems of improving the assessment of business decisions by criteria and indicators reflecting the functioning of shipping companies and trading ports are considered in the article. The structure of the problems and advantages of the formation of an active marine transport strategy is presented. Some factors of the development of specialized segments of the global maritime trade market are disclosed. The regularity and conditions for the formation of the parameters of the marine transport cluster are formulated. The article discusses measures to balance the economic interests of maritime transport and the consumers of its products. On this basis, the economic stimulation of optimal economic results is intensified. The necessity of using a wider range of economic regulation in comparison with the concentration of efforts on one model in optimizing the basic state of the regional complex of maritime transport is considered. The article also takes into account the analysis of factors that contribute to the optimization of the final indicators with the parameters of the maritime trade market. Features of innovative approaches that are of fundamental importance in the transport business and reflect the intellectual property of the company's management or its consultants are highlighted. It is on the life cycle ideas of the fleet that functional and financial stability of positioning can be achieved, despite the fact that new competitors appear at regular intervals. It is recommended to systematize the conditions for achieving the parameters of transport independence in the development of international transport integration, special attention is paid to the choice of mission based on the formation of a merchant shipping system that provides standardized efficiency. This, in turn, should be achieved through the benefits of innovative freight technologies.
СТАЛЕ БАНКІВНИЦТВО: КОНЦЕПЦІЯ ЕКОЛОГІЧНОЇ ПОЛІТИКИ БАНКУ У СФЕРІ РОЗПОДІЛУ РЕСУРСІВ ДЛЯ СТИМУЛЮВАННЯ СТАЛОГО ЕКОНОМІЧНОГО РОЗВИТКУ
Authors: Алєксєєв Ігор , Мазур Андріана 
Published: July 2022

У статті досліджено важливість участі фінансових інституцій у процесі становлення сталих перетворень. Зокрема проаналізовано праці стосовно визначення стану виконання банками своїх зобов’язань, визначених основними принципами сталого банківництва, ідентифікування вкладу банків та інших фінансових установ у процес стимулювання сталих змін в економіці та забезпечення досягнення Цілей Сталого Розвитку до 2030 року. Здійснено дослідження стану енергетичного споживання в Україні, тенденцій розвитку ринку відновлюваних джерел енергії, провадження проєктів із виробництва енергії з біомаси. Ідентифіковано ключові бар’єри провадження таких проєктів, серед яких необхідність налагодження ефективних механізмів фінансової підтримки, зокрема політики банківського кредитування. Досліджено вклад банківського сектора на ринках, що розвиваються, у промоцію сталих перетворень і досягнення Цілей Сталого Розвитку.Сформовано концепцію екологічної політики банку у сфері розподілу ресурсів для сприяння сталому економічному розвитку, яка базується на двох ключових структурних компонентах. Перший передбачає управління екологічними ризиками у сфері кредитування, які зокрема регламентували б участь банків у впровадженні системи заходів безпеки навколишнього середовища шляхом оцінювання свого кредитного портфеля, аналізування всіх проєктів, що підлягають кредитуванню, на предмет відповідності стандартам екологічної безпеки та охорони навколишнього середовища, а також відмови в розгляді заявок на отримання кредиту проєктам, які становлять потенційну загрозу для навколишнього середовища, та підприємствам, які займаються екологічно небезпечними видами діяльності. Другий обумовлює розвиток програм «зеленого фінансування» як структурного компоненту системи екологічного менеджменту банків, зокрема щодо кредитування різного роду прибуткових екологічних проєктів із метою підвищення ефективності участі банків у їх фінансуванні, а також можливості участі банків у інвестуванні неприбуткових соціально-екологічних ініціатив об’єднаних територіальних громад, міст із метою підвищення екологічної відповідальності банків і їхньої участі в налагодженні процесів сталого розвитку регіону зокрема та країни загалом.
CONCENTRATION OF ENTREPRENEURIAL ACTIVITY IN THE REGIONS OF UKRAINE IN THE CONTEXT OF SUSTAINABLE DEVELOPMENT
Authors: Simkiv Liliia , Andrusiv Uliana , Kupalova Galyna , Goncharenko Nataliia , Dzoba Oleh , Yushkevych Olena 
Published: July 2022

The state and features of small business development in Ukraine are studied in the context of ensuring the postulates of sustainable development. Positive and negative trends and changes are revealed, prospects of the development of business structures are defined in terms of sustainable development. Assessing the concentration of entrepreneurial activity in the regions of Ukraine, we note the presence of certain fluctuations in the dynamics and interregional differences in the density of economic entities per 10 thousand population. Based on the analysis of the entrepreneurial activity in the regions of Ukraine, it is established that despite the insufficient level of small business development, its influence on the economic development of the regions is growing. This is confirmed by the calculated coefficient of the impact of revenues from small businesses to the local budget on GRP, the importance of which is growing in all regions. The calculation of the ratio of personnel costs in the field of small business to personnel costs in all enterprises shows its tendency to decrease in most regions, which is explained by an increase in business shadowing rather than lower wages and a reduced number of employees in these enterprises. It is proved that the development of entrepreneurship solves not only economic but also social issues. It is an effective means of restructuring, enhancing innovation, overcoming imbalances in certain market segments, creating new jobs and reducing unemployment. Stimulating the development of an entrepreneurial activity, supporting small business and creating conditions for economic management are among the primary tasks of the state's economic policy.
Tindak Tutur Asertif Dalam Novel Goodbye You Karya Heri Putra Dan Hendra Putra
Authors: Aisyah Siti , Ningsih Asih Ria 
Published: July 2022

Artikel ini ditulis untuk mengetahui penggunaan bentuk dan strategi tindak tutur asertif. Tujuan pada penelitian ini untuk mendeskripsikan bentuk dan strategi tindak tutur asertif yang terdapat dalam novel Good bye you karya Heri Putra dan Hendra Putra. Jenis penelitian ini adalah deskriptif kualitatif. Sumber data dalam penelitian ini adalah novel. Data penelitian ini berupa kalimat dalam tuturan Naya kepada Zafrel Teknik pengumpulan data menggunakan teknik dokumentasi dan teknik catat. Instrumen penelitian adalah peneliti sendiri selaku instrumen utama dan dibantu dengan instrumen pendukung berupa tabel pengumpul data. Data dalam penelitian dianalisis melalui tiga tahapan, yaitu (1) pengelompokan data, (2) mengkode data, dan (3) menganalisis data. Hasil analisis data menunjukkan adanya penggunaan tindak tutur asertif dalam novel Good Bye You meliputi (1) bentuk tindak tutur asertif yang terbagi menjadi empat yakni bentuk menyatakan, bentuk menyarankan, bentuk membual, dan bentuk mengeluh, (2) strategi tindak tutur asertif yang terbagi menjadi dua yakni strategi tindak tutur asertif langsung dan strategi tindak tutur asertif tidak langsung.
Autorretrato y marca personal: Cómo se ven y cómo ven su futuro los estudiantes de Periodismo.
Authors: Conde Mariola 
Published: July 2022

Casi la totalidad (93%) de los estudiantes que han participado en este proyecto manifiestan que nunca habían realizado con anterioridad un ejercicio de introspección. A pesar de la importancia del autoconocimiento para el desarrollo de las habilidades para la vida, según la Organización Mundial de la Salud (Who, 1994), el 87% de los alumnos demostraba un conocimiento escaso y confuso sobre sí mismos, sus aptitudes, capacidades y expectativas de futuro. Una vez realizado el ejercicio, calificado de “muy positivo” y “útil” por el 100% de los participantes, los alumnos y alumnas muestran sus preferencias laborales, estando muy cerca el porcentaje de los que quieren dedicarse al periodismo en medios de comunicación, de los que se decantan por trabajar en otras áreas más vinculadas a la comunicación corporativa o el entorno digital. El estudiantado se muestra consciente de las altas barreras de entrada al mercado laboral y de la creciente competencia, pero señalan las posibilidades que pueden encontrarse ante una profesión en pleno cambio. La totalidad del alumnado declara que seguirá su formación para especializarse y poder ser más competitivos. En general, los participantes se muestran ilusionados y con expectativas ante el futuro, más del 75% de ellos quieren desarrollar su vida profesional en el territorio en el que viven y las personas que más admiran, para el 82%, son sus padres y madres.

Con este estudio se abren nuevas líneas de investigación para determinar si es necesario, o no, realizar ejercicios de introspección y autoconocimiento de forma pautada, incluso antes de que el alumnado comience sus estudios universitarios.
Aloneliness predicts relational anger and aggression toward romantic partners
Authors: Swets Julie A. , Cox Cathy R. 
Published: July 2022

AbstractAloneliness is the negative psychological state characterized by dissatisfaction with one's lack of solitude, which is connected to well‐being deficits (e.g., depression, stress). From an I3 theory perspective, we expected that aloneliness could predict anger and partner‐directed aggression among persons in romantic relationships, who must, by nature of their partnership, dedicate time to their romantic partners. In Studies 1a and 1b (N = 554), trait aloneliness positively correlated with trait anger, aggression, and violence, but more strongly among persons in relationships (vs. single persons). In Study 2, aloneliness was experimentally primed among 93 undergraduates in relationships. When aloneliness was salient (vs. a control), participants reported higher anger and used more pins in a partner‐representative voodoo doll. These results suggest that solitude is an inhibiting factor against anger and, potentially, the perpetration of partner‐directed aggression. Although subsequent work in this area is needed, we add evidence showing the importance of individual differences in the need for solitude.
Event‐based optimal filter for a networked system with multiplicative and auto/cross‐correlated process and measurement noise
Authors: Roy Avinash Kumar , Kannan Srinivasan 
Published: July 2022

SummaryThis article presents an event triggered based optimal filter for a networked system with multiplicative noise in state and measurement matrices. The process and measurement noise are auto/cross‐correlated, which is described as a moving average process. The network in both sensor to estimator (S‐E) and controller to actuator (C‐A) channel is affected by random sensor delay and packet dropouts. These effects are modeled using two random variables for both the S‐E and C‐A channels. Sensor data are transmitted to the estimator through the S‐E channel using an event‐based mechanism. It depends on a time varying threshold to improve trade‐off between tracking performance and utilization of network bandwidth. The process and measurement noise are two‐step auto/cross‐correlated. A comprehensive augmented stochastic model is developed for the networked system by combining the effects of event triggering, network constraints and noise correlation. The filter is designed using an innovation analysis approach based on orthogonal projection. The solution of the filter is given in terms of a Lyapunov and a Riccati equation. An algorithm is presented for the implementation of developed filter. The stability properties of the proposed optimal filter are analyzed. The effectiveness of the proposed filter is shown in the simulation platform and accumulated mean square error performance is evaluated based on Monte Carlo simulation.
Multifunctional Fiber‐Enabled Intelligent Health Agents
Authors: Chen Min , Li Pan , Wang Rui , Xiang Yuanzhuo , Huang Zhiheng , Yu Qiao , He Muyao , Liu Jia , Wang Jiaxi , Su Minyu , Zhang Manni , Jian Aijia , Ouyang Jingyu , Zhang Chenxi , Li Jing , Dong Mengxue , Zeng Shaoning , Wu Jiawei , Hong Ping , Hou Chong , Zhou Ning , Zhang Dingyu , Zhou Huamin , Tao Guangming 
Published: July 2022

AbstractThe application of wearable devices is promoting the development toward digitization and intelligence in the field of health. However, the current smart devices centered on human health have disadvantages such as weak perception, high interference degree, and unfriendly interaction. Here, an intelligent health agent based on multifunctional fibers, with the characteristics of autonomy, activeness, intelligence, and perceptibility enabling health services, is proposed. According to the requirements for healthcare in the medical field and daily life, four major aspects driven by intelligent agents, including health monitoring, therapy, protection, and minimally invasive surgery, are summarized from the perspectives of materials science, medicine, and computer science. The function of intelligent health agents is realized through multifunctional fibers as sensing units and artificial intelligence technology as a cognitive engine. The structure, characteristics, and performance of fibers and analysis systems and algorithms are reviewed, while discussing future challenges and opportunities in healthcare and medicine. Finally, based on the above four aspects, future scenarios related to health protection of a person's life are presented. Intelligent health agents will have the potential to accelerate the realization of precision medicine and active health.
The Third Dimension of Ferroelectric Domain Walls
Authors: Roede Erik D. , Shapovalov Konstantin , Moran Thomas J. , Mosberg Aleksander B. , Yan Zewu , Bourret Edith , Cano Andres , Huey Bryan D. , van Helvoort Antonius T. J. , Meier Dennis 
Published: July 2022

AbstractFerroelectric domain walls are quasi‐2D systems that show great promise for the development of nonvolatile memory, memristor technology, and electronic components with ultrasmall feature size. Electric fields, for example, can change the domain wall orientation relative to the spontaneous polarization and switch between resistive and conductive states, controlling the electrical current. Being embedded in a 3D material, however, the domain walls are not perfectly flat and can form networks, which leads to complex physical structures. In this work, the importance of the nanoscale structure for the emergent transport properties is demonstrated, studying electronic conduction in the 3D network of neutral and charged domain walls in ErMnO3. By combining tomographic microscopy techniques and finite element modeling, the contribution of domain walls within the bulk is clarified and the significance of curvature effects for the local conduction is shown down to the nanoscale. The findings provide insights into the propagation of electrical currents in domain wall networks, reveal additional degrees of freedom for their control, and provide quantitative guidelines for the design of domain‐wall‐based technology.
LSPR‐Enhanced Pyro‐Phototronic Effect for UV Detection with an Ag–ZnO Schottky Junction Device
Authors: Huang Jing , Li Qi , Lu Xianmao , Meng Jianping , Li Zhou 
Published: July 2022

AbstractSensitive and rapid detection of low‐power density ultraviolet (UV) light is of great significance for various applications such as space exploration, biological analysis, environmental sensors, communications, and imaging. However, the persistent photoconductivity (PPC) of photodetectors, which are based on ZnO, will cause a long decay time and make it difficult to capture weak light signals. In this work, the pyro‐phototronic effect of ZnO is integrated with the localized surface plasmon resonance (LSPR) of Ag nanoparticles (NPs) to enhance the performance of ZnO‐based photodetectors. The self‐powered photodetector is consisted of the ZnO nanowires (ZnO NWs) and Ag NPs, which can detect 325 nm UV light with a power density of 340 nW cm−2 quickly and sensitively. Compared with the photodetector without Ag NPs, the performance is significantly improved. Under the 325 nm UV light with the same power density, the best responsivity, and detectivity are 8.82 × 10−5 A W−1 and 4.9 × 1010 Jones, respectively. And the fast response time is remarkably reduced to 8.72 ms. These results help to understand the performance of LSPR enhanced photodetectors deeply and expand the methods for preparing high‐performance photodetectors.
Flexible Neural Interfaces Based on 3D PEDOT:PSS Micropillar Arrays
Authors: Lunghi Alice , Mariano Anna , Bianchi Michele , Dinger Nikita Bhupesh , Murgia Mauro , Rondanina Eliana , Toma Andrea , Greco Pierpaolo , Di Lauro Michele , Santoro Francesca , Fadiga Luciano , Biscarini Fabio 
Published: July 2022

AbstractMulti‐electrode arrays with 3D micropillars allow the recording of electrophysiological signals in vitro with higher precision and signal‐to‐noise ratio than planar arrays. This is the result of the tight interaction between the 3D electrode and the cell membrane. Most 3D electrodes are manufactured on rigid substrates and their integration on flexible substrates is largely unexplored. Here, a straightforward approach is presented for fabricating soft interfaces featuring 3D poly(3,4‐ethylenedioxythiophene)‐poly(styrenesulfonate) (PEDOT:PSS) micropillars on a soft flexible substrate made of polydimethylsiloxane (PDMS). Large‐area isotropic arrays of PEDOT:PSS micropillars with tailored geometric area, surface properties, and electrochemical characteristics are fabricated via a combination of soft‐lithography and electrodeposition. A 60% increase in capacitance is achieved for high density micropillars compared to planar electrodes and this is found to be correlated with the increased electroactive surface area. Furthermore, 3D PEDOT:PSS micropillars support adhesion, growth and differentiation of SH‐SY5Y cells, and influence the direction of neurite outgrowth. Finally, by virtue of their elasticity, soft micropillars act as excellent anchoring loci for elongating neurites, facilitating their bending and twisting around the micropillar, increasing the number of contact points between the cells and the electrode, a key requirement to obtain high performance neural interfaces.
Quasi‐1D ZrS3 as an Anisotropic Nano‐Reflector for Manipulating Light–Matter Interactions
Authors: Guo Junqing , Xiao Zhenyang , Wu Ziyu , Liao Xiaxia , Wan Siyuan , Fu Xuewen , Zhou Yangbo 
Published: July 2022

Abstract2D layered materials with low crystal symmetries exhibit unique anisotropic physical properties. Here the systematic studies on the optical modulation effects of such anisotropic 2D materials to isotropic 2D materials in their stacked van der Waals (vdW) heterostructures are reported. By applying angle‐resolved polarization spectroscopic characterizations on the MoS2/ZrS3 vdW heterostructure, periodic intensity variations of the Raman scattering and photoluminescence (PL) emission modes of monolayer MoS2 are observed, which are closely correlated to the anisotropic optical properties of the underlying ZrS3 layers. Such anisotropic optical modulation effects can be identified with the thickness of ZrS3 reduced to few layers (≈6 nm), and are attributed to the strong birefringence and dichroism effects in ZrS3 that cause reflection difference between its crystal axis, thus modulating the Raman/PL intensities of MoS2 via Fabry–Pérot interference effect. Furthermore, the polarized photocurrent response of the heterostructure is also demonstrated, where its major contribution originates from MoS2. This work develops a new methodology to tune the light–matter interactions and properties of isotropic 2D materials by the combination with anisotropic 2D materials, which substantially broadens the application of low symmetry layered materials in polarization sensitive optoelectronic devices.
Solid‐Supported Tetrahydropyran‐Based Hybrid Dipeptide Catalysts for Michael Addition of Aldehydes to Nitrostyrenes
Authors: García‐Monzón Irma , Borges‐González Jorge , Martín Tomás 
Published: July 2022

AbstractThe heterogenization of homogeneous catalysts onto a solid support is a step towards a more sustainable chemistry. The recovery and reuse of catalysts is extremely important from a practical, economic and environmental point of view. In this regards, we report a series of polymer‐supported tetrahydropyran‐based hybrid dipeptides that serve as active catalysts for the enantioselective Michael addition of aldehydes to β‐nitrostyrenes. These supported catalysts have been designed considering the optimal anchor position and orientation between the catalyst and the solid support. Additionally, the influence of the linker length on the catalytic efficiency was studied. The catalysts allowed the transformation of a variety of substrates in 76–98% yield and with 94–97% enantiomeric excess. Detailed deactivation studies have provided important information, which allows to increase the useful life of these immobilized catalysts.magnified image
Divergent Synthesis of β‐Hydroxy Amides (Esters) and γ‐Amino Alcohols via Ir/f‐Diaphos Catalyzed Asymmetric Hydrogenation
Authors: Zhao Xianghua , Yang Zehui , Cheng Yuqi , Huang An , Hu Fangyuan , Ling Fei , Zhong Weihui 
Published: July 2022

AbstractThe iridium/f‐diaphos L2 or L9 catalyzed asymmetric hydrogenation of β‐aryl β‐keto amides (esters), and β‐amino ketones to afford two enantiomers of the desired chiral alcohols was realized with 90%‐99% yield and 73%‐99% ee. This protocol could be easily conducted on gram scale in the presence of low catalyst loading (up to 9900 TON). Moreover, the hydrogenated products are versatile building blocks for a variety of biologically active molecules and drugs, such as Fluoxetine, Dapoxetine and so on.magnified image