bluuebunny/crossref_metadata_2025_split huggingface dataset:
Ceria Boosting on In Situ Nitrogen-Doped Graphene Oxide for Efficient Bifunctional ORR/OER Activity
Authors: Kashinath L. , Byrappa K. 
Published: June 2022

In the present work, a highly efficient and excellent electrocatalyst material for bifunctional oxygen reduction/evolution reaction (ORR/OER) was synthesized using the microwave-assisted hydrothermal method. In brief, ultrafine hexagonal cerium oxide (CeO2) nanoparticles were tailored on the layered surface of in situ nitrogen-doped graphene oxide (NGO) sheets. The nanocomposites exhibited a high anodic onset potential of 0.925 V vs. RHE for ORR activity and 1.2 V for OER activity with a very high current density in 0.5 M KOH. The influence of oxygen cluster on Ce3+/Ce4+ ion decoration on outward/inward in situ nitrogen-coupled GO enhanced the physicochemical properties of composites and in turn increased electron transferability. The microwave-assisted hydrothermal coupling technique provides a higher density, active sites on CeO2@NGO composites, and oxygen deficiency structures in ultrafine Ce-O particles and boosts higher charge transferability in the composites. It is believed that the physical states of Ce-N- C, Ce-C=O, and a higher amount of oxygen participation with ceria increase the density of composites that in turn increases the efficiency. N-doped graphene oxide promotes high current conduction and rapid electron transferability while reducing the external transport resistance in oxygen electrocatalysis by sufficient mass transfer through in-built channels. This study may provide insights into the knowledge of Ce-enabled bifunctional activity to guide the design of a robust catalyst for electrochemical performance.
Persistent Coronary Vasomotor Tone During Myocardial Ischemia Occurs at the Capillary Level and May Involve Pericytes
Authors: Le D. Elizabeth , Zhao Yan , Kaul Sanjiv 
Published: June 2022

BackgroundThere is persistent coronary vasomotor tone during myocardial ischemia, despite ongoing coronary arteriolar dilatation. The mechanism underlying this vasodilatory tone, which can be unmasked by coronary vasodilators, is unclear. We hypothesized that persistent microvascular resistance during myocardial ischemia occurs at the level of capillaries and may be caused by pericytes.MethodsWe studied nine instrumented dogs where coronary blood flow and coronary driving pressure were reduced to half by placement of stenoses. Myocardial blood flow and myocardial blood volume were measured with myocardial contrast echocardiography before and during adenosine administration. In three animals, the heart was perfusion-fixed under these conditions for electron microscopic assessment of capillary and pericyte size.ResultsDuring ischemia, myocardial blood volume decreased and myocardial vascular resistance remained unchanged. Adenosine administration reversed the decline in myocardial blood volume and decreased myocardial vascular resistance. Electron microscopy showed larger capillaries in ischemic beds receiving adenosine than ischemic beds not receiving adenosine. Pericytes in beds receiving adenosine also tended to be larger.ConclusionCapillaries are the site of persistent vasomotor tone during myocardial ischemia; any other site of vascular regulation (arterioles or venules) cannot explain these myocardial contrast echocardiography findings, which are confirmed on post-mortem electron microscopic examination. The decrease in capillary size is likely caused by pericyte contraction in an attempt to maintain a constant capillary hydrostatic pressure. Adenosine relaxes pericytes, restores myocardial blood volume, reduces myocardial vascular resistance, and improves regional function during ischemia. These findings could have important therapeutic implications.
Geochemical Analogy Viscosity of Mid-Ocean Ridge Basalt as an Indicator for Determining the Location of Seafloor Hydrothermal Fields?
Authors: Li Chuanshun , Wang Guohuai , Yan Shijuan , Du Dewen 
Published: June 2022

Many achievements have been made in the exploration of seafloor polymetallic hydrothermal vents, however, it needs to further study how to discovery more potential new hydrothermal or massive sulfide fields. In this study, we collected 9818 major-element geochemical data sets of basalt samples from the Mid-Atlantic Ridge (MAR, 78°N–53°S) and the seafloor topographic data for eleven known hydrothermal vents (e.g., TAG, Snake Pit, MAR 22°30′N, Lilliput). Based on the different spatial distances between basalts and hydrothermal vents, we classified all the basalts into three categories: 1) basalt near known vent (focal objects of the research, 29 samples), 2) basalt around known vent (observed objects, 155 samples), and 3) other basalt of the MAR (as background basalt). Meanwhile, we used major element components of basalts to calculate the analogy viscosity and analyzed the possible correlation between analogy viscosity and the spatial distribution of seafloor hydrothermal vents. We found that the analogy viscosity of basalt near known vent fall into a narrow medium value range (∼46.8–68.5 Pa s) contrasted with the range of background basalt values range (∼4.0–356.0 Pa·s). It infers that these basalts on the Mid-Atlantic Ridge with the medium values of analogy viscosity favor the formation of hydrothermal vents. However, due to the complexities of magmatic activity and fault structure, as well as the multi-stage water-rock reaction, whether the analogy viscosity of basalts can be used as an indicator for determining the location of seafloor hydrothermal field or not needs further verification. Hence, this paper provides a possible rule (the variation of analogy viscosity estimated by major element components in the basalts) for exploration the location of hydrothermal vents rather than a fully developed method.
Effect of Hyperthyroidism Control During Pregnancy on Maternal and Fetal Outcome: A Systematic Review and Meta-Analysis
Authors: Alves Junior Jose Mario , Bernardo Wanderley Marques , Ward Laura Sterian , Villagelin Danilo 
Published: June 2022

ContextAlthough the overt hyperthyroidism treatment during pregnancy is mandatory, unfortunately, few studies have evaluated the impact of treatment on reducing maternal and fetal outcomes.ObjectiveThis study aimed to demonstrate whether treatment to control hyperthyroidism manifested during pregnancy can potentially reduce maternal-fetal effects compared with euthyroid pregnancies through a systematic review with meta-analysis.Data SourceMEDLINE (PubMed), Embase, Cochrane Library Central, LILACS/BIREME until May 2021.Study SelectionStudies that compared, during the gestational period, treated women with hyperthyroidism versus euthyroid women. The following outcomes of this comparison were: pre-eclampsia, abruptio placentae, fetal growth retardation, gestational diabetes, postpartum hemorrhage, low birth weight, stillbirth, spontaneous abortions, premature birth.Data ExtractionTwo independent reviewers extracted data and performed quality assessments. Dichotomous data were analyzed by calculating risk differences (DR) with fixed and random effect models according to the level of heterogeneity.Data SynthesisSeven cohort studies were included. The results of the meta-analysis indicated that there was a lower incidence of preeclampsia (p=0.01), low birth weight (p=0.03), spontaneous abortion (p&lt;0.00001) and preterm birth (p=0.001) favouring the euthyroid pregnant group when compared to those who treated hyperthyroidism during pregnancy. However, no statistically significant differences were observed in the outcomes: abruptio placentae, fetal growth retardation, gestational diabetes mellitus, postpartum hemorrhage, and stillbirth.ConclusionsOur findings demonstrated that treating overt hyperthyroidism in pregnancy is mandatory and appears to reduce some potential maternal-fetal complications, despite there still being a residual risk of negative outcomes.
The Flexible and Transparent Film Heaters Based on Regenerated Cellulose and Carbon Nanotubes
Authors: Cui Jiedong , Lu Pengbo , Li Yinghui , Xu Ke , Li Yang , Shen Haoyu , Liu Chaocheng , Zhang Tianyi , Liu Detao 
Published: June 2022

The flexible and transparent film heaters (FTFHs) with the advantages of mechanical flexibility, portability, and excellent electrothermal performance, are key to the next generation portable, wearable heaters and thermal protection systems. However, the present flexible and transparent substrates of FTFHs are fabricated by typical plastic PET films, which suffer from poor interfacial adhesion with the thermally conductive materials. In this work, the transparent regenerated cellulose fibers made of completely dissolved in NMMO solution followed by regeneration process is presented to disperse and support carbon nanotubes (CNTs) by a vacuum-dewatering process. In the presence of cellulose fibers, these CNTs have strong hydrogen bonding properties in the dehydration-deposition process and thus respond to tight intertwining structures in fibrous composites. The resulting regenerated cellulose fibers exhibit high optical transparency of 88% (@550 nm) and good mechanical properties (30 MPa). Interestingly, the FTFHs show a rapid heating response, high generation temperature, and resistance stability for up to 2 h. The FTFHs made with earth-abundant, cost-effective, and recyclable materials, have excellent potential in the areas of green flexible and transparent film heaters.
Mudstone Baffles and Barriers in Lower Cretaceous Strata at a Proposed CO2 Storage Hub in Kemper County, Mississippi, United States
Authors: Wethington Conn , Pashin Jack , Wethington Jamar , Esposito Richard , Riestenberg David 
Published: June 2022

The Cretaceous and Tertiary deposits in Mississippi, Alabama, and the adjacent continental shelf constitute a widespread succession of sandstone, mudstone, and carbonate that has proven to be an important target for geologic CO2storage in the onshore Gulf of Mexico basin. Integrated analysis of stratigraphy, sedimentology, and reservoir properties based on cores and geophysical well logs indicates that the Paluxy Formation and Washita- Fredericksburg interval present gigatonne-class storage opportunities. The distribution, geometry, and composition of the area is a direct reflection of the original depositional environments, and understanding these factors is essential for understanding the geologic storage potential of the Paluxy Formation and Washita-Fredericksburg interval at the Kemper County energy facility in Mississippi. Geologic characterization of the Mississippi Embayment at the energy facility focused primarily on characterizing the confinement potential of the storage complex. Integration of core analyses and geophysical well logs has yielded a high-resolution stratigraphic analysis of storage reservoirs, baffles, barriers, and seals. Scanning electron microscopy (SEM) coupled with energy dispersive X-ray spectroscopy (EDS), and quantitative X-ray diffraction (XRD) was used to characterize microfabric, pore types, and mineralogy within mudstone of the east-central Mississippi Embayment at the Kemper County energy facility. Mudstone beds in the Paluxy Formation and Washita-Fredericksburg interval have variable thickness and continuity. High water saturation in the Cretaceous mudstone units influences swelling smectite clay and mudrock permeability based on pulse decay analysis is 1–96 nD. These low permeability values indicate that the mudstone units are effective baffles, barriers, and confining intervals that make significant migration of injected CO2out of the storage complex unlikely. The numerous baffles and barriers within the target reservoir intervals, moreover, favor the retention of multiple CO2in plumes within the abundant stacked sandstone bodies.
Underwater Macroplastic Detection Using Imaging Sonars
Authors: Flores Natasha Y. , Oswald Stephanie B. , Leuven Rob S. E. W. , Collas Frank P. L. 
Published: June 2022

Plastic pollution in the ocean occurs mainly via riverine transport. In rivers, plastic is pervasive in sediments and in the water column. Monitoring of floating plastics in rivers is time consuming as it is usually collected using nets and classified by hand, or counted and classified visually. To make plastic detection in the water column more time- and cost-efficient, there is a need to explore remote sensing options. Here we present the results of two semi-controlled pilot tests in standing water using two imaging sonar technologies: an Adaptive Resolution Imaging Sonar (ARIS) sonar and a low-cost side-scan sonar (SSS). Additionally, the ARIS sonar was tested in flowing water at a sheltered shore channel behind a longitudinal training dam in the river Waal, Netherlands. Both technologies were able to detect 100% of the macroplastics tested in standing water. The ARIS sonar provided higher resolution images of the targets tested due to its high operation frequency detecting macroplastics down to a size of 1 cm2. The ARIS sonar detected macroplastics in the field, however, the detection decreased to 67% in flowing water. This sonar was limited to the 2D horizontal position of targets. The SSS is a low-cost option for monitoring of plastics and is integrated with CHIRP sonar technology that combines side and down imaging providing the 3D position of targets. For future monitoring, an ARIS sonar in motion or two ARIS sonars used simultaneously may provide the necessary 3D spatial information of plastic targets.
Very-Short-Term Variations of Sea Surface and Atmospheric Parameters Before the Ms 6.2 Zhangbei (China) Earthquake in 1998
Authors: Liu Yingjia , Wu Lixin , Qi Yuan , Ding Yifan 
Published: June 2022

The Ms 6.2 Zhangbei earthquake occurred at 3:53 (UTC) on 10 January 1998, with its epicenter located at about 150 km northwest of Beijing, China. Over the past 2 decades, many studies have reported that there was a positive thermal infrared (TIR) anomaly appearing along the direction from the Bohai Sea to Zhangbei within 2–3 days preceding the earthquake, which was considered to be caused by the activity of the great Zhangbei-Bohai fault (ZBF) extending across the Bohai Sea to the southeast, while neither the TIR anomaly is convinced nor the mechanism is clear. A collaborative analysis of the atmospheric disturbances several days before, during, and after the earthquake was conducted by using satellite observations and reanalysis datasets with multiple parameters, including sea surface roughness, evaporation rate, atmospheric CO concentration, atmospheric sea salt concentration, and cloud base height above the sea surface, as well as satellite infrared cloud images. Through individual analysis of the change of each parameter and synergic analysis of multiple parameters, particular atmospheric disturbances, including the formation of strip-shaped clouds on January 7 and 9, were revealed over the ZBF and another great fault named Tancheng-Lujiang fault (TLF), which extends across the Bohai Sea to the northeast. After careful investigation and attribution analysis of the spatio-temporal evolutions of the atmospheric disturbances every hour above and around the Bohai Sea from January 7 to 12, we came to the conclusion that the particular strip-shaped clouds were low-level clouds caused by the seismic activity and submarine gas release from TLF but not ZBF and was forced by particular wind field and lowering boundary layer. As an aftereffect of the gas release from TLF and the formation of the localized low-level clouds of higher brightness temperature than that of the land surface, a positive TIR anomaly, thus, appeared above TLF and by chance along ZBF, preceding the Zhangbei earthquake.
What Is the Impact of the Establishment of Natural Reserves on Rural Residential Land? An Empirical Study From Hunan Province, China
Authors: Wu Yuanlai , Tang Houtian , Jiang Ping , Chen Jinxiu 
Published: June 2022

The rural residential land (RRL) in natural reserves has been deeply transformed due to the disturbance constrained by ecological protection policies. Exploring the distribution characteristics and driving factors of RRL in natural reserves and non-natural reserves will help to promote the governance of land space and alleviate the contradiction of land use. Therefore, taking 122 county-level administrative regions in Hunan Province as an example, this article analyzes and compares the spatiotemporal distribution characteristics of RRL in natural reserves and non-natural reserves by using land use change dynamics, nuclear density analysis, the transfer matrix model, and the ordinary least-squares model and explores how the establishment of natural reserves affects the RRL area change. The results show that (1) the overall RRL area in Hunan changed from 171,162.27 hm2 in 2000 to 169,914.6 hm2 in 2020, with a total reduction of 1,247.67 hm2 and a decrease of 0.73%, and the distribution of the RRL area change presented a hot trend in the northeast and a cold trend in the southwest. (2) The occupation of urban construction land is the main reason for the reduction in RRL area, and the transformation of cultivated land and forestland into RRL is the main source of the increase in RRL area. (3) During 2000–2020, the overall RRL in natural reserves increased by 1,538.37 hm2, with an increase of 0.11%, while the overall RRL in non-natural reserves decreased by 2,786.04 hm2, with a decrease of 0.14%. (4) The establishment of natural reserves has a significant negative correlation with the area of RRL in 2000, 2010, and 2020, indicating that the establishment of natural reserves can limit the growth speed of the RRL area to a certain extent, but is affected by factors such as economic development and rural population growth; it cannot directly promote the overall reduction of RRL area. The results of this study can provide a reference for decision-making related to the spatial structure optimization of natural reserves and non-natural protected RRL and the coordinated development of urban and rural areas.
Biophysical and Biocultural Upheavals in Mesoamerica, a Conservation Perspective: Mountains, Maize-Milpa, and Globalization
Authors: del Castillo Rafael F. , Rivera-García Raúl 
Published: June 2022

Three upheavals shaped southern Mexico to Panama (SMP) biodiversity:   1. The Great American Interchange that allowed migrations between the Neotropical and the Nearctic biogeographic realms;   2. human colonization with the generation of Mesoamerican cultures; and   3. the Spaniards’ arrival and globalization.Tectonic events generated a narrow piece of land with steep topography and high environmental heterogeneity, demanding high levels of local adaptation. Habitat size is usually restricted and reduced by frequent disturbances. Topography imposes few options for individuals forced to displace. Thus, extinction risks should be unusually high. Humans initiated an ongoing defaunation process and introduced the maize and the milpa, an itinerant maize-based slash-and-burn polyculture, which depends on revegetation to re-establish soil fertility. Also, the milpa is a most important pre-Hispanic legacy, a biocultural and landrace reservoir actively affecting landscape configuration, succession, soil development, and the genetic architecture of the species. Unprecedented human epidemics and soil, biodiversity, and culture erosion followed behind the Spanish aftermath and the subsequent globalization. &gt; 63 million people and ≈100 ethnic groups inhabit SMP in 2020, which, with the biota, share the same problems of climate change, disturbance, and acculturation. SMP has been the scenario of severe climate change, fastest and deadliest extinction events (amphibians), a most spectacular exotic-species invasion (Africanized honeybees), and accelerated deforestation, defaunation, and acculturation. Biocultural conflicts between native and non-native people are globalization byproducts and sources of habitat destruction and species decline. Bottom-up initiatives are likely the best option for conservation in indigenous areas, whereas honest (i.e., with truly conservation intentions) top-down initiatives are helpful if the affected people are considered subjects (no objects) of conservation plans. We suggest some unique areas requiring conservation attention and analyzed current conservation initiatives. Not a single initiative is best suited for all conservation needs in SMP. Protection of all successional stages is critical for resilience and revegetation. Conservation of the milpa system (crop fields and subsequent fallows) is an optimal option for minimizing tradeoffs between conservation and people needs and safeguarding traditional culture and local landraces but is limited to areas with indigenous people and may not work for species with large home ranges.
DNA N6-Methyladenine Modification in Eukaryotic Genome
Authors: Li Hao , Zhang Ning , Wang Yuechen , Xia Siyuan , Zhu Yating , Xing Chen , Tian Xuefeng , Du Yinan 
Published: June 2022

DNA methylation is treated as an important epigenetic mark in various biological activities. In the past, a large number of articles focused on 5 mC while lacking attention to N6-methyladenine (6 mA). The presence of 6 mA modification was previously discovered only in prokaryotes. Recently, with the development of detection technologies, 6 mA has been found in several eukaryotes, including protozoans, metazoans, plants, and fungi. The importance of 6 mA in prokaryotes and single-celled eukaryotes has been widely accepted. However, due to the incredibly low density of 6 mA and restrictions on detection technologies, the prevalence of 6 mA and its role in biological processes in eukaryotic organisms are highly debated. In this review, we first summarize the advantages and disadvantages of 6 mA detection methods. Then, we conclude existing reports on the prevalence of 6 mA in eukaryotic organisms. Next, we highlight possible methyltransferases, demethylases, and the recognition proteins of 6 mA. In addition, we summarize the functions of 6 mA in eukaryotes. Last but not least, we summarize our point of view and put forward the problems that need further research.