bluuebunny/crossref_metadata_2025_split huggingface dataset:
Research status and advantages analysis of plant transfer printing and dyeing under the background of sustainable development
Authors: Ren Borui , Wang Jiaoqing 
Published: May 2022

With the acceleration of social process, handicraft is gradually replaced by industrial production. The excessive use of chemical dyes has caused serious waste of resources, environmental pollution and physical harm, which is contrary to the five development concepts of innovation, coordination, green, openness and sharing proposed at the Fifth Plenary Session of the 18th CPC Central Committee. In November 2012, the 18th National Congress of the Communist Party of China incorporated the Five-sphere Integrated Plan for the cause of socialism with Chinese characteristics, making the CPC the first ruling party in the world to incorporate ecological civilization into its program of action. Ecological civilization construction under the leadership of the communist party of China has achieved a major breakthrough, at the same time also achieve rapid economic development, people's living standards generally improved, is given priority to with functional and practical products can not meet the growing spiritual and cultural demand, consumers desire in products demand more emotional resonance for nature. Based on the green development plan goal and the mainstream background of sustainable development proposed in the 13th Five-Year Plan, this paper sorts out the research status of plant printing and dyeing, and expounds the advantages of plant printing and dyeing combined with consumer willingness and market demand, which has reference value for further exploring the green development of plant printing and dyeing.
Platonic Science in the Vernacular: Sebastiano Erizzo’s Italian Translation of Plato’s Timaeus (1557)
Authors: De Robertis Tommaso 
Published: May 2022

This article provides a textual and contextual investigation of the earliest Italian translation of Plato’s Timaeus, produced by Sebastiano Erizzo (1525-1585) and printed in Venice by Comin da Trino in 1557. While the work perfectly reflects Erizzo’s interests in Platonic philosophy, there is evidence that a key motivation behind this venture was the encouragement of his editor and literary agent, Girolamo Ruscelli (1518-1566), who sought to incorporate Erizzo’s translation into the first complete program of vernacularisation of Plato’s works ever attempted in Italy. This project was meant not only to rival Aristotle’s corpus in the vernacular, which by that time was available almost in its entirety, but also to contribute to the problem of the best method for teaching philosophy, an issue hotly debated in Padua and Venice in these years. Both the philological accuracy and the rich interpretive apparatus of Erizzo’s edition testify to a radical change in the way sixteenth-century intellectuals approached Platonic philosophy. By dismissing the most evident theologically-oriented elements of Marsilio Ficino’s translation (1484), Erizzo seems to be far more concerned with the philological aspects of the translator’s work. In this sense, Erizzo’s translation may be considered as the result of, and also a significant step towards, a new interpretation of Plato’s natural philosophy.
Does who I am and what I feel determine what I see (or say)? A meta-analytic systematic review exploring the influence of real and perceived bodily state on spatial perception of the external environment
Authors: MacIntyre Erin , Braithwaite Felicity A. , Mouatt Brendan , Wilson Dianne , Stanton Tasha R. 
Published: May 2022

Background
Bodily state is theorised to play a role in perceptual scaling of the environment, whereby low bodily capacity shifts visuospatial perception, with distances appearing farther and hills steeper, and the opposite seen for high bodily capacity. This may play a protective role, where perceptual scaling discourages engaging with the environment when capacity is low.

Methodology
Our protocol was pre-registered via Open Science Framework (https://osf.io/6zya5/) with all amendments to the protocol tracked. We performed a systematic review and meta-analysis examining the role of bodily state/capacity on spatial perception measures of the environment. Databases (Medline, PsychINFO, Scopus, Embase, and Emcare) and grey literature were searched systematically, inclusive to 26/8/21. All studies were assessed using a customised Risk of Bias form. Standard mean differences and 95% CIs were calculated via meta-analysis using a random-effects model.

Results
A total of 8,034 studies were identified from the systematic search. Of these, 68 experiments (3,195 participants) met eligibility and were included in the review. These were grouped into the following categories: fatigue; pain; age; embodiment; body size/body paty size; glucose levels; fitness; and interoception, and interoceptive accuracy. We found low level evidence (limited studies, high risk of bias) for the effect of bodily state on spatial perception. There was consistent evidence that both glucose manipulations and age influence spatial perception of distances and hills in a hypothesised direction (lower capacity associated with increased distance and hill steepness). Mixed evidence exists for the influence of external loads, embodiment, body/body-part size manipulations, pain, and interoceptive accuracy. Evidence for fitness and/or fatigue influencing spatial perception was conflicting; notably, methodological flaws with fitness and fatigue paradigms and heterogenous spatial perception measures may underlie null/conflicting results.

Conclusion
We found limited evidence for bodily state influencing spatial perception of the environment. That all studies had high risk of bias makes conclusions about reported effects reflecting actual perceptual shifts (vs merely reflecting experimental demands or error due to inadequate study design) pre-emptive. Rigorous evaluation is needed to determine whether reported effects reflect more than bias (e.g., experimental demands, inadequate blinding). Future work using reliable measures of spatial perception, comprehensive evaluation of relevant confounders, and methodologically robust (and experimentally confirmed) bodily state experimental paradigms is warranted.
Molecular Identification of Xa4 Resistance Gene to Xanthomonas oryzae pv. oryzae in Cultivated Rice in Northwest Benin
Authors: Djedatin G. , Nanoukon C. , Missihoun A. , Lomou M. , Sedah P. , Agbangla C. 
Published: May 2022

Aims: The aim of this study was to identify the cultivated rice varieties that were resistant to Xanthomonas oryzae pv. oryzae (Xoo) by molecular screening. Xanthomonas oryzae pv. oryzae (Xoo) was the causal agent of bacterial blight, in the department of Atacora in Benin.
Place and Duration of Study: Laboratory of Molecular Biology and Bioinformatics Applied to Genomics, between July 2021 and November 2021.
Methodology: Thirty-two rice accessions were collected in the department of Atacora and the IRBB4 isogenic line carrying Xa4 resistance gene, as a positive control, were screened using SSR marker. Genomic DNA was extracted from plants leaves. PCR using a pair of MP12 primers linked to the Xa4 gene were performed and amplified products were analyzed by electrophoresis in a 2% agarose gel.
Results: Our results showed that a significant number of rice varieties grown in northern Benin were resistant to Xoo. 62.5% were resistant of which 70% were local varieties. Some of these resistant varieties (35%) were heterozygous (Xa4/xa4) and others were homozygous (Xa4/Xa4). 10% had specific genotypes other than those expected, which showed the probability of existence new resistance alleles that need to be characterized.
Conclusion: This is the first time that a bacterial blight resistance gene has been identified in Beninese rice cultivation. This result will be very useful to rice breeders for developing elites resistant varieties through markers assisted selection programs.
Effect of Nitrogen Levels and Planting Methods on Growth and Yield of Black Rice (Oryza sativa L.)
Authors: Jesiya Khwairakpam , Umesha C. , Meshram M. R. , Akash Khwairakpam 
Published: May 2022

Background: Compared to other types of rice, black rice has the highest protein content vitamins and minerals. Black rice contains essential amino acids like lysine, tryptophan; vitamins such as vitamin B1, vitamin B2, folic acid; and it is a good source of minerals including iron, zinc, calcium, phosphorus and selenium.
Objectives: Impact of nitrogen levels and planting methods on black rice growth and production.
Methods: A field experiment was conducted during kharif season of 2021, at crop research farm of Department of Agronomy at Sam Higginbottom University of Agriculture, Technology and Sciences, Prayagraj in North Eastern plains of Eastern Uttar Pradesh. under randomized block design comprising of 9 treatments of which treatments (T1-T9) with different combination of nitrogen along with different planting meathods which are replicated thrice.
Conclusion: The treatment Nitrogen at 75 kg/ha nitrogen + SRI method recorded maximum. Plant height (118.13 cm), number of tillers/hill (11.00), plant dry weight (31.62 g/plant), number of panicles per hill (10.83), number of grains per panicle (196.70), number of filled grains per panicle (116.33), grain yield (4.61 t/ha) and straw yield (11.38 t/ha). Because the findings are based on research conducted during a single season, they may be repeated for further confirmation.
Potassium Forms in Brown Sarson Growing Soils in District Kupwara, Kashmir
Authors: Chesti M. H. , Mir Shakeel A. , Khan Inayat Mustafa , Baligah Hujjat Ul , Mir Aamir H. , Qadri Tabasum N. , Bhat M. Auyoub 
Published: May 2022

Distribution of different forms of potassium and their correlation with soil physico-chemical properties was studied in Brown Sarson growing soils of district Kupwara. The study was carried out to pave a way for drafting proper fertilization plan keeping in view the importance of potassium for crops and reluctance of farmers in applying the same. The study area was divided into two regions i: e upper belt and lower belt and surface soil samples (0-25 cm), ten from each belt were collected for analysis. The soil samples collected were studied for potassium forms and physico- chemical properties. The soils analyzed were clay loam to loamy in texture and acidic to neutral in reaction. The organic carbon content was higher in lower belts as compared to upper belts. The potassium fractions followed an order total-K > lattice-K > acid soluble-K > non exchangeable- K> available-K> exchangeable-K> water soluble-K. All forms of K were positively correlated to organic carbon, cation exchange capacity and clay content and negatively correlated with pH and calcium carbonate.
2D Transition Metal Dichalcogenide with Increased Entropy for Piezoelectric Electronics
Authors: Chen Yulong , Tian Ziao , Wang Xiang , Ran Nian , Wang Chen , Cui Anyang , Lu Huihui , Zhang Miao , Xue Zhongying , Mei Yongfeng , Chu Paul K. , Liu Jianjun , Hu Zhigao , Di Zengfeng 
Published: May 2022

AbstractPiezoelectricity in 2D transition metal dichalcogenides (TMDs) has attracted considerable interest because of their excellent flexibility and high piezoelectric coefficient compared to conventional piezoelectric bulk materials. However, the ability to regulate the piezoelectric properties is limited because the entropy is constant for certain binary TMDs other than multielement ones. Herein, in order to increase the entropy, a ternary TMDs alloy, Mo1−xWxS2, with different W concentrations, is synthesized. The W concentration in the Mo1−xWxS2 alloy can be controlled precisely in the low‐supersaturation synthesis and the entropy can be tuned accordingly. The Mo0.46W0.54S2 alloy (x = 0.54) has the highest configurational entropy and best piezoelectric properties, such as a piezoelectric coefficient of 4.22 pm V−1 and a piezoelectric output current of 150 pA at 0.24% strain. More importantly, it can be combined into a larger package to increase the output current to 600 pA to cater to self‐powered applications. Combining with excellent mechanical durability, a mechanical sensor based on the Mo0.46W0.54S2 alloy is demonstrated for real‐time health monitoring.
Intraparticle Macromolecular Migration Alters the Structure and Function of Proteins Reversibly Immobilized on Porous Microbeads
Authors: Diamanti Eleftheria , Arana‐Peña Sara , Ramos‐Cabrer Pedro , Comino Natalia , Carballares Diego , Fernandez‐Lafuente Roberto , López‐Gallego Fernando 
Published: May 2022

AbstractWhile migration of reversibly immobilized proteins across the volume of supports is investigated in conditions where an external force is applied or under fluid flow conditions, their passive migration upon sample storage and its effect on the protein functionality remain unexplored. Understanding such intraparticle macromolecular migration is essential to develop protein functionalized biomaterials with a longer life span. This work investigates the spatiotemporal migration of His‐tagged immobilized fluorescent proteins inside porous agarose microbeads under different storage conditions. A tool that assesses the intraparticle protein migration across the surface of the porous supports is developed. Differences in migration patterns between different proteins suggest that binding dynamics between proteins and their supports play a key role in their migration. The effect of macromolecular migration on the functional and structural properties of bound proteins and enzymes is also explored. Therefore, single‐particle measurements to understand how the migration process affects the functionality of immobilized enzymes are performed. Evaluating protein migration and understanding the reason behind such phenomena allows gaining control over immobilization processes and design immobilization chemistries that either prevent or promote intraparticle macromolecular diffusion upon storage, depending on the desired final application.
Electrophoretic‐Driven In Situ Polymerization Depositing High‐Quality Perovskite Films for Photodetectors
Authors: Yan Wei , Shen Jianhua , Wang Yu , Wen Zhen , Chen Cheng , Zhu Yihua , Li Chunzhong 
Published: May 2022

AbstractPerovskite quantum dots (PQDs) have wide applications in optoelectronic devices due to their excellent stability and processability. However, PQD films are still seeking to overcome the problems of disorder and porosity. This seriously hinders the carrier transport and the application of PQDs in photodetectors (PDs). In this work, the electrophoretic deposition (EPD) method is employed to fabricate PQDs with conjugated linoleic acid (CLA) as the ligands, and the highly oriented and dense films are obtained. In addition, CLA molecules can polymerize during electrophoresis, which shortens the quantum dot spacing. It facilitates carrier transport while improving the stability of the film. PDs prepared by electrophoresis have a high detectivity (D*) up to 5.1 × 1012 Jones, which is 3.9 times higher than PDs prepared by spin coating (1.3 × 1012 Jones) and reaches the highest record under the same conditions. In addition, the device exhibits a remarkable stability, maintaining 95% of the initial performance when left in the air for 3 months. This work provides a new perspective on the assembly of PQDs in the application of optoelectronic devices.
Self‐Straining Nanocrystals Strategy: Temperature and Pressure Co‐Induced Phase Transitions of CsPbBr3 in Amorphous Matrices
Authors: Zheng Ruilin , Ueda Jumpei , Li Jiyao , Shinozaki Kenji , Fan Zeyu , Horike Satoshi , Tanabe Setsuhisa 
Published: May 2022

AbstractUnderstanding temperature and pressure co‐induced structural evolution of nanocrystals (NCs) is important for the design and application of heterostructure devices. However, the phase transition and band structure change are difficult to be analyzed under temperature and negative pressure co‐induced conditions. Here, an adjustable self‐straining strategy to control the temperature and pressure co‐induced phase transitions of NCs in amorphous matrices is reported. The synchronous pressure regulation, based on the thermal expansion mismatch between the NCs and the amorphous matrix, can be achieved by changing a single temperature variable. Two new phase transition processes of CsPbBr3 NCs, including monoclinic‐orthorhombic and reversible amorphization, are clarified for the first time using the proposed self‐straining strategy. Besides, all the phase transition temperatures of the self‐straining NCs show a high sensitivity response to the pressure regulation. Most importantly, the encapsulation of CsPbBr3 NCs in an amorphous matrix excludes the effect of external environments allowing the elucidation of the widely existing “self‐straining effect” in the NCs with heterogeneous structures. This work provides a better fundamental understanding of the phase transitions of NCs and paves the way toward the development of an in situ method to predict the multiphysics co‐induced structural evolution of NCs in optoelectronic devices.
Nanostructured Intermetallic Nickel Silicide (Pre)Catalyst for Anodic Oxygen Evolution Reaction and Selective Dehydrogenation of Primary Amines
Authors: Mondal Indranil , Hausmann J. Niklas , Vijaykumar Gonela , Mebs Stefan , Dau Holger , Driess Matthias , Menezes Prashanth W. 
Published: May 2022

AbstractThe development of novel earth‐abundant metal‐based catalysts to accelerate the sluggish oxygen evolution reaction (OER) is crucial for the process of large‐scale production of green hydrogen. To solve this bottleneck, herein, a simple one‐pot colloidal approach is reported to yield crystalline intermetallic nickel silicide (Ni2Si), which results in a promising precatalyst for anodic OER. Subsequently, an anodic‐coupled electrosynthesis for the selective oxidation of organic amines (as sacrificial proton donating agents) to value‐added organocyanides is established to boost the cathodic reaction. A partial transformation of the Ni2Si intermetallic precatalyst generates a porous nickel(oxy)hydroxide phase modified with oxidic silicon species as unequivocally demonstrated by a combination of quasi in situ Raman and X‐ray absorption spectroscopy as well as ex situ methods. The activated form of the catalyst generates a geometric current density of 100 mA cm−2at an overpotential (η100) of 348 mV displaying long‐term durability over a week and high efficiency in paired electrolysis.
A Multifaceted Ferrocene Interlayer for Highly Stable and Efficient Lithium Doped Spiro‐OMeTAD‐based Perovskite Solar Cells
Authors: Webb Thomas , Liu Xueping , Westbrook Robert J.E. , Kern Stefanie , Sajjad Muhammad T. , Jenatsch Sandra , Jayawardena K. D. G. Imalka , Perera W. Hashini K. , Marko Igor P. , Sathasivam Sanjayan , Li Bowei , Yavari Mozhgan , Scurr David J. , Alexander Morgan R. , Macdonald Thomas J. , Haque Saif A. , Sweeney Stephen J. , Zhang Wei 
Published: May 2022

AbstractOver the last decade, 2,2″,7,7″‐Tetrakis[N,N‐di(4‐methoxyphenyl)amino]‐9,9′‐spirobifluorene (spiro‐OMeTAD) has remained the hole transporting layer (HTL) of choice for producing high efficiency perovskite solar cells (PSCs). However, PSCs incorporating spiro‐OMeTAD suffer significantly from dopant induced instability and non‐ideal band alignments. Herein, a new approach is presented for tackling these issues using the functionality of organometallocenes to bind to Li+ dopant ions, rendering them immobile and reducing their impact on the degradation of PSCs. Consequently, significant improvements are observed in device stability under elevated temperature and humidity, conditions in which ion migration occurs most readily. Remarkably, PSCs prepared with ferrocene retain 70% of the initial power conversion efficiency (PCE) after a period of 1250 h as compared to only 8% in the control. Synergistically, it is also identified that ferrocene improves the hole extraction yield at the HTL interface and reduces interfacial recombination enabling PCEs to reach 23.45%. This work offers a pathway for producing highly efficient spiro‐OMeTAD devices with conventional dopants via addressing the key challenge of dopant induced instability in leading PSCs.
Design Rationale and Device Configuration of Lithium‐Ion Capacitors
Authors: Liang Jiaxing , Wang Da‐Wei 
Published: May 2022

AbstractLithium‐ion capacitors (LICs) are a game‐changer for high‐performance electrochemical energy storage technologies. Despite the many recent reviews on the materials development for LICs, the design principles for the LICs configuration, the possible development roadmap from academy to industry has not been adequately discussed. Systematic understanding of device development is the foundation to more efficient utilization of advanced LICs materials. This review focuses on the principle of the recent configurations of LICs, the device design rationales, and new prelithiation techniques that are an integral part in LIC design. The authors also comment on the new generation multifunctional LICs that are capable of meeting the emerging applications in flexible electronics and other modern technologies. Finally, the status of LICs is presented and several key take‐home messages about minimizing the gaps between academic and industry requirements are proposed.
“Sandwich” Diimine‐Copper Catalysts for C−H Functionalization by Carbene Insertion
Authors: Klimovica Kristine , Heidlas Julius X. , Romero Irvin , Le Thanh V. , Daugulis Olafs 
Published: May 2022

AbstractWe report here “sandwich” diimine‐copper(I) catalysts for C(sp3)−H bond functionalization. Reactions of alkanes and ethers with trimethylsilyldiazomethane, ethyl diazoacetate, and trifluoromethyl‐diazomethane have been demonstrated. We also report C(sp3)−H bond methylation, benzylation, and diphenylmethylation by diazomethane, aryldiazomethanes, and diphenyldiazomethane. These reactions are rare examples of base‐metal catalyzed, intermolecular C(sp3)−H functionalizations by employing unactivated diazo compounds. Electrophilicity and unique steric environment of “sandwich”‐copper catalysts are likely reasons for their catalytic efficiency.
Concise Synthesis of Tunicamycin V and Discovery of a Cytostatic DPAGT1 Inhibitor
Authors: Mitachi Katsuhiko , Mingle David , Effah Wendy , Sánchez‐Ruiz Antonio , Hevener Kirk E. , Narayanan Ramesh , Clemons William M. , Sarabia Francisco , Kurosu Michio 
Published: May 2022

AbstractA short total synthesis of tunicamycin V (1), a non‐selective phosphotransferase inhibitor, is achieved via a Büchner–Curtius–Schlotterbeck type reaction. Tunicamycin V can be synthesized in 15 chemical steps from D‐galactal with 21 % overall yield. The established synthetic scheme is operationally very simple and flexible to introduce building blocks of interest. The inhibitory activity of one of the designed analogues 28 against human dolichyl‐phosphate N‐acetylglucosaminephosphotransferase 1 (DPAGT1) is 12.5 times greater than 1. While tunicamycins are cytotoxic molecules with a low selectivity, the novel analogue 28 displays selective cytostatic activity against breast cancer cell lines including a triple‐negative breast cancer.