bluuebunny/crossref_metadata_2025_split huggingface dataset:
The Green Stock Market Bubble
Authors: Lehnert Thorsten 
Published: November 2022

AbstractOne may contend that there are some clear similarities between the market for sustainable assets now and the situation of tech stocks right before the collapse of the dot-com bubble. In fact, before 2000, the risk of the new technology was primarily idiosyncratic because of the limited scale of production and the low likelihood of a widespread adoption. Subsequently, with an increasing probability of adoption, also, the old economy was affected by the new technology and, hence, the wealth of the representative agent. As a result, systematic risk increased, which depressed stock prices, because it pushed up the discount rates in the new and old economies. Similarly, given the high probability of a large-scale adoption of the new “green technology,” it is likely that there is not only a bubble forming in green energy stocks, but the boom is affecting the stock market as a whole. I apply a recently developed recursive testing procedure and dating algorithm that is useful in detecting multiple bubble events. Using S&P 500 stock market data, price-dividend ratios, I identify the well-known historical speculative bubbles and find an explosive movement in today’s market starting in June 2021, which can be associated with the new “green technology.” I find that an explosive movement in green stocks started roughly a year before it was migrating to the whole stock market. I argue that this is a good bubble because it will enable businesses to invest cheaply in green energy, hastening the transition away from fossil fuels and assisting in the fight against climate change.
Application of Fe(III)–EDDS complexes and soybean peroxidase in photo-Fenton processes for organic pollutant removal: insights into possible synergistic effects
Authors: Bertolotti Silvia , Minella Marco , Laurenti Enzo , Brigante Marcello , Mailhot Gilles , Bianco Prevot Alessandra 
Published: November 2022

AbstractPhoto-Fenton processes activated by biodegradable Fe(III)–EDDS complexes have attracted huge attention from the scientific community, but the operative mechanism of the photo-activation of H2O2 in the presence of Fe(III)–EDDS has not been fully clarified yet. The application of the Fe(III)–EDDS complex in Fenton and photo-Fenton (mainly under UV-B light) processes, using 4-chlorophenol (4-CP) as a model pollutant was explored to give insights into the operative mechanism. Furthermore, the potential synergistic contribution of soybean peroxidase (SBP) was investigated, since it has been reported that upon irradiation of Fe(III)–EDDS the production of H2O2 can occur. SBP did not boost the 4-CP degradation, suggesting that the possibly produced H2O2 reacts immediately with the Fe(II) ion with a quick kinetics that does not allow the diffusion of H2O2 into the bulk of the solution (i.e., outside the solvent cage of the complex). So, a concerted mechanism in which the photochemically produced H2O2 and Fe(II) react inside the hydration sphere of the Fe(III)–EDDS complex is proposed.
Graphical abstract
Gender is dynamic for all people
Authors: Brady B. , Rosenberg S. , Newman C. E. , Kaladelfos A. , Kenning G. , Duck-Chong E. , Bennett J. 
Published: November 2022

AbstractGender is dynamic across the life-course for all people. This is true for you, me and the collective ‘us’. In this perspective paper, we invite you to reflect on how changes in the experience and expression of gender can be most appropriately viewed as a normal part of human development, diversity, and growth. We can find gender’s dynamism in at least three areas: that the meaning of gender has changed over time; that there are significant cultural differences in the meaning of gender; and that one’s own gender and relationship to it can change, evolve, weaken, and galvanise across a lifetime. From our position as interdisciplinary scientists, artists, and community advocates, each of us informed by distinctive and dynamic lived experiences of gender, we examine how the foundations of psychology may be limiting the capacity for the discipline to accurately reflect dynamic experiences of gender in the real world. We encourage you to ponder how we can address points of resistance to change in thought and practice and embed a more deliberately dynamic understanding of gender within our knowledge systems and structures. Ultimately, we seek to empower you, the reader, to take up the challenge of new ways of thinking and behaving in relation to gender.
Impacts of tourism on coastal areas
Authors: Smith Timothy F. , Elrick-Barr Carmen E. , Thomsen Dana C. , Celliers Louis , Le Tissier Martin 
Published: November 2022

Abstract
The socioeconomics of the Anthropocene is exposing coastal regions to multiple pressures, including climate change hazards, resource degradation, urban development and inequality. Tourism is often raised as either a panacea to, or exacerbator of, such threats to ecosystems and sustainable livelihoods. To better understand the impacts of tourism on coastal areas, Scopus and Web of Science databases were searched for the top 100 cited papers on coastal tourism. Web of Science suggested ‘highly cited’ papers were also included to allow for more recent high-impact papers. Of the papers retrieved, 44 focused on the impacts of tourism. Social/cultural and environmental impacts were viewed as mostly negative, while economic impacts were viewed as mostly positive but only of actual benefit to a few. In addition, when compared with recent whole-of-sector reviews and reports it was evident that coastal tourism is increasingly a global enterprise dominated by large corporations that leverage various interests across local to transnational scales. Through this global enterprise, even the positive economic benefits identified were overshadowed by a broader system of land and property development fuelling local wealth inequity and furthering the interests of offshore beneficiaries. Only two highly cited papers discussed tourism within a broader context of integrated coastal zone management, suggesting that tourism is mostly assessed as a discrete sector within the coastal zone and peripheral to other coastal management considerations or the global tourism sector as a whole. The findings have relevance to the holistic management of coasts, coastal tourism and the achievement of sustainable development goals in a way that considers the increasing threats from coastal hazards, resource extraction and urbanisation, as well as the pervasive impacts of international business systems from local to global scales.
Epilepsy Surgery in Adult Stroke Survivors with New-Onset Drug-Resistant Epilepsy
Authors: Antaya Tresah C. , Le Britney N. , Richard Lucie , Qureshi Amna , Shariff Salimah Z. , Sposato Luciano A. , Burneo Jorge G. 
Published: November 2022

ABSTRACT:Background:Despite its effectiveness, surgery for drug-resistant epilepsy is underutilized. However, whether epilepsy surgery is also underutilized among patients with stroke-related drug-resistant epilepsy is unclear. Therefore, our objectives were to estimate the rates of epilepsy surgery assessment and receipt among patients with stroke-related drug-resistant epilepsy and to identify factors associated with these outcomes.Methods:We used linked health administrative databases to conduct a population-based retrospective cohort study of adult Ontario, Canada residents discharged from an Ontario acute care institution following the treatment of a stroke between January 1, 1997, and December 31, 2020, without prior evidence of seizures. We excluded patients who did not subsequently develop drug-resistant epilepsy and those with other epilepsy risk factors. We estimated the rates of epilepsy surgery assessment and receipt by March 31, 2021. We planned to use Fine-Gray subdistribution hazard models to identify covariates independently associated with our outcomes, controlling for the competing risk of death.Results:We identified 265,081 patients who survived until discharge following inpatient stroke treatment, 1,902 (0.7%) of whom subsequently developed drug-resistant epilepsy (805 women; mean age: 67.0 ± 13.1 years). Fewer than six (≤0.3%) of these patients were assessed for or received epilepsy surgery before the end of follow-up (≤55.5 per 100,000 person-years). Given that few outcomes were identified, we could not proceed with the multivariable analyses.Conclusions:Patients with stroke-related drug-resistant epilepsy are infrequently considered for epilepsy surgery that could reduce morbidity and mortality.
Educational initiative in an NCATS TL1 training program to address the impact of systemic racism on human health, biomedical research, and the translational scientist
Authors: Gay Martha D. , Bell Kimberly A. , Bujold Emily A. , Geraci Marilla , Lee Dexter L. , Sandberg Kathryn , Speth Robert C. 
Published: November 2022

Abstract

Introduction:
The goal of clinical and translational science (CTS) is to fill gaps in medical knowledge toward improving human health. However, one of our most pressing challenges does not reside within the biological map we navigate to find sustainable cures but rather the moral compass to recognize and overcome racial and ethnic injustices that continue to influence our society and hinder diverse research rigor. The Georgetown-Howard Universities Center for Clinical and Translational Science includes an inter-institutional TL1-funded training program for predoctoral/postdoctoral trainees in Translational Biomedical Science (TBS).

Methods:
In the fall of 2020, the TBS program responded to the national social justice crisis by incorporating a curriculum focused on structural racism in biomedical research. Educational platforms, including movie reviews, Journal Clubs, and other workshops, were threaded throughout the curriculum by ensuring safe spaces to discuss racial and ethnic injustices and providing trainees with practical steps to recognize, approach, and respond to these harmful biases in the CTS. Workshops also focused on why individuals underrepresented in science are vital for addressing and closing gaps in CTS.

Results:
Paring analysis using REDCap software de-identified participants after invitations were sent and collected in the system to maintain anonymity for pre- and post-analysis. The Likert scale evaluated respondents’ understanding of diverse scientific circumstances. The pre/Fall and post/Spring surveys suggested this curriculum was successful at raising institutional awareness of racial and ethnic biases. Evaluating the effectiveness of our program with other training Clinical and Translational Science Awards (CTSA) consortiums will strengthen both the academic and professional TBS programs.
The triple-deficit hypothesis in Arabic: Evidence from children with and without dyslexia
Authors: Layes Smail , Cohen Marjolaine , van Viersen Sietske 
Published: November 2022

AbstractThis study investigated the triple-deficit hypothesis in Arabic, a Semitic transparent orthography, among 258 native Arabic children from Grade 3, divided into a typical readers group (n = 204) and a dyslexia group (n = 54). Children were tested on word- and pseudoword-reading accuracy, word-reading fluency, phonological awareness (PA), naming speed (NS), orthographic processing (OP), and nonverbal reasoning ability. The results indicated that all children with dyslexia had either double or triple deficits, and none of them had a single deficit. Children with triple deficits showed lower performance than children with single and no deficits on all the reading measures. They have also lower performance to children with double deficits on word-reading accuracy but comparable scores in word- and pseudoword-reading fluency. In addition, OP was confirmed as an additional independent predictor of word-level reading skills besides PA and NS, while controlling for age and nonverbal intelligence. The classification findings showed that the presence of a triple deficit maximizes the risk of reading failure. These findings support the additive nature of combined deficits in PA, NS, and OP. Moreover, they establish the benefit of including OP as a third deficit, in addition to PA and NS, underlying dyslexia in Arabic.
Successful device closure by Amplatzer vascular plug II of a rare celiacomesenteric trunk-to-right atrium fistula in a repaired giant omphalocele
Authors: Chen Yu-Hsuan , Cheng Kun-Shan , Hung Wei-Li 
Published: November 2022

AbstractAorto-right-atrial fistula is an uncommon condition with an unclear pathogenesis. We present the case of a 3-year-old girl with a giant omphalocele repaired days after birth and incidentally discovered with a celiacomesenteric trunk-to-right atrium fistula. Three-dimensional reconstruction CT unveiled its anatomical pattern, and the fistula was successfully closed using a Amplatzer vascular plug II percutaneously.
Importance of Background Vorticity Effect and Doppler Shift in Defining Near‐Inertial Internal Waves
Authors: Rama Jemima , Shakespeare Callum J. , Hogg Andrew McC. 
Published: November 2022

AbstractNear‐inertial waves contain a significant fraction of the ocean's internal wave energy and can propagate long distances from their source before dissipating. However, a varying background flow velocity can alter the wave propagation in two ways. The background vorticity modifies the lower bound of the wave frequency bandwidth while Doppler shifts alter the wave intrinsic frequency. Both effects complicate the identification of the waves and the quantification of their energy content. This study analyses the output of a realistic simulation of the North Pacific using adaptive frequency filters to isolate the effects of vorticity and Doppler shift on the apparent wave energy. Spectral filters neglecting background vorticity effects results in apparent near‐inertial energy being underestimated by 40% in anticyclonic structures and overestimated by 100% in cyclonic structures. The asymmetry in energy bias is reinforced when both background vorticity and Doppler shift effects are omitted from the frequency filters.
The Existence and Origin of Multiple Equilibria in Sand‐Mud Sediment Beds
Authors: Colina Alonso A. , van Maren D. S. , Herman P. M. J. , van Weerdenburg R. J. A. , Huismans Y. , Holthuijsen S. J. , Govers L. L. , Bijleveld A. I. , Wang Z. B. 
Published: November 2022

AbstractThe sediment composition of the seabed governs its mobility, hence determining sediment transport and morphological evolution of estuaries and tidal basins. Bed sediments often consist of mixtures of sand and mud, with spatial gradients in the sand/mud content. This study aims at increasing the understanding of processes driving the sediment composition in tidal basins, focusing on depositional processes. We show that bed sediments in the Wadden Sea tend to be either mud‐dominated or sand‐dominated, resulting in a bimodal distribution of the mud content where the two modes represent equilibrium conditions. The equilibria depend primarily on the sediment deposition fluxes, with bimodality originating from the dependence of suspended sand/mud concentrations on the local bed composition. Our analysis shows that bimodality is a phenomenon that is not only specific for the Wadden Sea; it can be expected for a wide range of suspended sediment concentrations and thus also in other systems worldwide.
Vesicular Olivines and Pyroxenes in Shocked Kamargaon L6 Chondrite: Implications for Primary Volatiles and Its Multiple Impacts History
Authors: Tiwari Kishan , Ghosh Sujoy , Miyahara Masaaki , Ray Dwijesh 
Published: November 2022

AbstractAbundant vesicles are found in terrestrial rocks, basaltic meteorites, and carbonaceous chondrites which testify to the presence of significant quantities of volatiles and favorable conditions for vesiculation. Furthermore, vesicular olivine has been reported in terrestrial rocks and carbonaceous chondrites. However, vesicles in the ordinary chondrites are rare due to their low volatile content and obliteration by the late impact events. Here, we report the first evidence of vesicular olivine (Fo76) and pyroxene (En73–81Fs17–26Wo01–02) in an ordinary chondrite. The vesicular texture in the shocked Kamargaon L6 chondrite possibly formed due to localized melting during a shock event and subsequent degassing of volatiles after decompression. We propose three possible mechanisms for vesicle formation in the Kamargaon meteorite: (a) liberation of S2 vapor, (b) evaporation of moderately volatile elements (MVEs) like Na and Mn, and (c) vaporization of olivine and pyroxene, by constraining the primary abundance of volatiles based on the observed volume of vesicles. We suggest that all three or any combination of these mechanisms could be responsible for vesicle formation. Segmented texture in olivine is also observed in the shock vein (SV) of the Kamargaon chondrite. The segmentation has developed due to the formation of sub‐grain boundaries during the recovery process when grains were subjected to localized shear stress. Average shock pressure and temperature conditions in the SV are ∼24–25 GPa and ∼2310–2633K, respectively. The thermal model of the SV cooling gives the crystallization time of ∼50 ms and shock pulse duration of ∼2s.
High-resolution European daily soil moisture derived with machine learning (2003–2020)
Authors: O Sungmin , Orth Rene , Weber Ulrich , Park Seon Ki 
Published: November 2022

AbstractMachine learning (ML) has emerged as a novel tool for generating large-scale land surface data in recent years. ML can learn the relationship between input and target, e.g. meteorological variables and in-situ soil moisture, and then estimate soil moisture across space and time, independently of prior physics-based knowledge. Here we develop a high-resolution (0.1°) daily soil moisture dataset in Europe (SoMo.ml-EU) using Long Short-Term Memory trained with in-situ measurements. The resulting dataset covers three vertical layers and the period 2003–2020. Compared to its previous version with a lower spatial resolution (0.25°), it shows a closer agreement with independent in-situ data in terms of temporal variation, demonstrating the enhanced usefulness of in-situ observations when processed jointly with high-resolution meteorological data. Regional comparison with other gridded datasets also demonstrates the ability of SoMo.ml-EU in describing the variability of soil moisture, including drought conditions. As a result, our new dataset will benefit regional studies requiring high-resolution observation-based soil moisture, such as hydrological and agricultural analyses.
Multi-omics HeCaToS dataset of repeated dose toxicity for cardiotoxic & hepatotoxic compounds
Authors: Verheijen Marcha , Sarkans Ugis , Wolski Witold , Jennen Danyel , Caiment Florian , Kleinjans Jos ,   HeCaToS Consortium, Agarkova Irina , Atkinson Francis L. , Bachmann Ivo , Baier Vanessa , Barel Gal , Bauer Chris , van den Beucken Twan , Boerno Stefan , Bosc Nicolas , Carey Conn , Castell José V. , Clayton Olivia , Cordes Henrik , Deeb Sally , Gmuender Hans , Gotta Stefano , Guye Patrick , Hersey Anne , Herwig Ralf , Heymans Stephane , Hunt Peter , Hunter Fiona M. I. , Hynes James , Keun Hector , Kouloura Eirini , Kuepfer Lars , Kunz Laura , Lewalle Alex , Lienhard Matthias , Martínez-Sena Teresa , Merken Jort , Minguet Jasmine , Nguyen Nhan , Niederer Steven , Nudischer Ramona , Asensio Juan Ochoteco , Oliveira Bernardo , Panse Christian , Pluess Carla , Roth Adrian B. , Schlapbach Ralph , Schrooders Yannick , Schuchhardt Johannes , Segall Matthew , Selevsek Nathalie , Sepulveda Pilar , Smit Ines , Thiel Christoph , Timmermann Bernd , Wittenberger Timo , Zerck Alexandra 
Published: November 2022

AbstractThe data currently described was generated within the EU/FP7 HeCaToS project (Hepatic andCardiacToxicitySystems modeling). The project aimed to develop anin silicoprediction system to contribute to drug safety assessment for humans. For this purpose, multi-omics data of repeated dose toxicity were obtained for 10 hepatotoxic and 10 cardiotoxic compounds. Most data were gained fromin vitroexperiments in which 3D microtissues (either hepatic or cardiac) were exposed to a therapeutic (physiologically relevant concentrations calculated through PBPK-modeling) or a toxic dosing profile (IC20 after 7 days). Exposures lasted for 14 days and samples were obtained at 7 time points (therapeutic doses: 2-8-24-72-168-240-336 h; toxic doses 0-2-8-24-72-168-240 h). Transcriptomics (RNA sequencing & microRNA sequencing), proteomics (LC-MS), epigenomics (MeDIP sequencing) and metabolomics (LC-MS & NMR) data were obtained from these samples. Furthermore, functional endpoints (ATP content, Caspase3/7 and O2 consumption) were measured in exposed microtissues. Additionally, multi-omics data from human biopsies from patients are available. This data is now being released to the scientific community through the BioStudies data repository (https://www.ebi.ac.uk/biostudies/).
Evaluation of geometric tortuosity for 3D digitally generated porous media considering the pore size distribution and the A-star algorithm
Authors: Ávila Joseph , Pagalo Javier , Espinoza-Andaluz Mayken 
Published: November 2022

AbstractPorous materials are of great interest in multiple applications due to their usefulness in energy conversion devices and their ability to modify structural and diffusive properties. Geometric tortuosity plays an important role in characterizing the complexity of a porous medium. The literature on several occasions has related it as a parameter dependent on porosity only. However, due to its direct relationship with the morphology of the medium, a deeper analysis is necessary. For this reason, in the present study, the analysis of the geometric tortuosity is proposed considering the porosity and the pore size distribution. Geometric tortuosity in artificially generated digital porous media is estimated using the A-star algorithm and the Pore Centroid method. By performing changes in the size of the medium and the distribution of the pore size, results are obtained that indicate that the geometric tortuosity does not only depend on the porosity. By maintaining the same porosity, the geometric tortuosity increases if the pore size is reduced. Similarly, these pore size effects are greater if the size of the medium is reduced. The A-star algorithm was found to be more suitable to characterize the majority of paths within the half-pore. On the other hand, to increase the size, the Pore Centroid method is the most appropriate. Finally, three types of correlations were generated relating tortuosity with porosity and pore size. All the correlations were determined with 95% of interval confidence.
Synthesis of pyrimidine-6-carbonitriles, pyrimidin-5-ones, and tetrahydroquinoline-3-carbonitriles by new superb oxovanadium(V)-[5,10,15,20-tetrakis(pyridinium)-porphyrinato]-tetra(tricyanomethanide) catalyst via anomeric based oxidation
Authors: Dashteh Mohammad , Makhdoomi Sajjad , Baghery Saeed , Zolfigol Mohammad Ali , Khazaei Ardeshir , Gu Yanlong 
Published: November 2022

AbstractOxovanadium(V)-[5,10,15,20-tetrakis(pyridinium)-porphyrinato]-tetra(tricyanomethanide) [(VO)TPP][(TCM)4] was designed, synthesized and characterized by various techniques such as FT-IR, EDX, SEM equipped with EDX mappings, CHN elemental analysis, ICP-OES, XRD, SEM, TEM, TGA, DTA, DRS, Kubelka–Munk function (Tauc’s plot), and UV–Vis analyses. Then, [(VO)TPP][(TCM)4] was used as a benign and expedient catalyst for the synthesis of numerous heterocyclic compounds such as 5-amino-7-(aryl)-4,7-dihydro-[1,2,4]triazolo[1,5-a]pyrimidine-6-carbonitriles, 5-amino-7-(aryl)-[1,2,4]triazolo[1,5-a]pyrimidine-6-carbonitriles, 7-(aryl)-7,12-dihydro-5H-isochromeno[4,3-d][1,2,4]triazolo[1,5-a]pyrimidin-5-ones, and 4-(aryl)-2-(1H-indol-3-yl)-5,6,7,8-tetrahydroquinoline-3-carbonitriles under solvent-free conditions at 100 °C via a cooperative geminal-vinylogous anomeric based oxidation.