bluuebunny/crossref_metadata_2025_split huggingface dataset:
High‐Rate Organic Cathode Constructed by Iron‐Hexaazatrinaphthalene Tricarboxylic Acid Coordination Polymer for Li‐Ion Batteries
Authors: Wang Yifan , Qiao Zelong , Liu Kexin , Yu Le , Lv Yingying , Shi Liyi , Zhao Yin , Cao Dapeng , Wang Zhuyi , Wang Shitao , Yuan Shuai 
Published: November 2022

AbstractThe sluggish ion‐transport in electrodes and low utilization of active materials are critical limitations of organic cathodes, which lead to the slow reaction dynamics and low specific capacity. In this study, the hierarchical tube is constructed by iron‐hexaazatrinaphthalene tricarboxylic acid coordination polymer (Fe‐HATNTA), using HATNTA as the self‐engaged template to coordinate with Fe2+ ions. This Fe‐HATNTA tube with hierarchical porous structure ensures the sufficient contact between electrolyte and active materials, shortens the diffusion distance, and provides more favorable transport pathways for ions. When employed as the cathode for rechargeable Li‐ion batteries, Fe‐HATNTA delivers a high specific capacity (244 mAh g−1 at 50 mA g−1, 91% of theoretical capacity), excellent rate capability (128 mAh g−1 at 9 A g−1), and a long‐term cycle life (73.9% retention over 3000 cycles at 5 A g−1). Moreover, the Li+ ions storage and conduction mechanisms are further disclosed by the ex situ and in situ characterizations, kinetic analyses, and theoretical calculations. This work is expected to boost further enthusiasm for developing the hierarchical structured metal‐organic coordination polymers with superb ionic storage and transport as high‐performance organic cathodes.
One‐year Medicare costs associated with delirium in older hospitalized patients with and without Alzheimer's disease dementia and related disorders
Authors: Hshieh Tammy T. , Gou Ray Yun , Jones Richard N. , Leslie Douglas L. , Marcantonio Edward R. , Xu Guoquan , Travison Thomas G. , Fong Tamara G. , Schmitt Eva M. , Inouye Sharon K. ,   for the BASIL I Study Group
Published: November 2022

AbstractIntroductionOne‐year health‐care costs associated with delirium in older hospitalized patients with and without Alzheimer's disease and related dementias (ADRD) have not been examined previously.MethodsMedicare costs were determined prospectively at discharge, and at 30, 90, and 365 days in a cohort (n = 311) of older adults after hospital admission.ResultsSeventy‐six (24%) patients had ADRD and were more likely to develop delirium (51% vs. 24%, P < 0.001) and die within 1 year (38% vs. 21%, P = 0.002). In ADRD patients with versus without delirium, adjusted mean difference in costs associated with delirium were $34,828; most of the excess costs were incurred between 90 and 365 days (P = 0.03). In non‐ADRD patients, delirium was associated with increased costs at all timepoints. Excess costs associated with delirium in ADRD patients increased progressively over 1 year, whereas in non‐ADRD patients the increase was consistent across time periods.DiscussionOur findings highlight the complexity of health‐care costs for ADRD patients who develop delirium, a potentially preventable source of expenditures.Highlights
Novel examination of health‐care costs of delirium in persons with and without Alzheimer's disease and related dementias (ADRD).
Increased 1‐year costs of $34,828 in ADRD patients with delirium (vs. without).
Increased costs for delirium in ADRD occur later during the 365‐day study period.
For ADRD patients, cost differences between those with and without delirium increased over 1 year.
For non‐ADRD patients, the parallel cost differences were consistent over time.
Ammonium removal by alkaline‐activated coconut coir from synthetic and ground waters
Authors: Van Do Thi Cam , Pham Thi Thanh Yen , Pham Thi Mai Huong 
Published: November 2022

AbstractHigh ammonium concentration in groundwater in Viet Nam is a threaten consequence to Vietnamese people in suburban and rural areas. Coconut coir is an economic waste of Viet Nam's agriculture with million tons generated every year. In this work, NaOH treatment of raw coconut coir (RCC) was implemented to obtain activated biomaterial (NaACC) for evaluation of ammonium adsorption from synthetic and ground waters. First, the effects of adsorbent dosage, initial ammonium concentration, reaction time, temperature on adsorption performance, adsorption isotherm, and kinetics for ammonium‐contained synthetic water were investigated. Second, the ammonium adsorption performance of NaACC from a natural groundwater was also evaluated. The removal efficiencies of ammonium were 49.5, 60.6, and 66.7% with maximum adsorption capacities of 0.51, 0.67, and 0.74 mg/g at temperatures of 30, 40, and 50°C, respectively, at pH 7.0, NaACC dose 40 g/L, initial ammonium concentration 40 mg/L, and reaction time 144 h. The NaACC displayed the best ammonium adsorption following Langmuir isotherm (R2 = 0.9990) and pseudo‐second‐order kinetic model (R2 = 0.9989). The NaACC also exhibited a good ammonium adsorption in natural groundwater with removal efficiency and adsorption capacity of 82.6% and 0.77 mg/g, respectively. Particularly, NaACC can be regenerated up to three cycles for consecutive adsorption of ammonium in groundwater without loss of its adsorptive performance. Therefore, NaACC derived from agricultural wastes was a potential biomaterial for cleaning ammonium from contaminated groundwater.
Electron Storage Performance of Hybrid Materials Comprising Polyoxometalates and Carbon Nanohorns as Cathode‐Active Materials
Authors: Wakamatsu Katsuhiro , Sekihara Akinori , Yamaguchi Yoshihiko , Matsushima Ryo , Matsumura Daiju , Kuila Tapas , Yoshikawa Hirofumi 
Published: November 2022

AbstractNanohybrid materials comprising polyoxometalates (POMs) and nanocarbons have attracted considerable attention as electrode‐active materials for rechargeable lithium‐ion batteries (LIBs). These materials exhibit multi‐electron redox reactions, resulting in an improved battery capacity. This study focuses on carbon nanohorns (CNHs) as a nanocarbon material and evaluates the battery performance using POM/CNH hybrids as cathode‐active materials. X‐ray absorption fine structural analysis was performed to investigate the reaction mechanism of these hybrids. POM/oxidized CNH (CNHox) hybrid materials maintain high capacities at high current densities as the high surface area availability of CNHox leads to high electrical double‐layer capacitances. These findings show an improved performance of the as‐developed material when compared with those reported in previous papers and can contribute toward an improved design of cathode‐active materials for high‐performance supercapacitors.
Potentialities of fluorescent carbon nanomaterials as sensor for food analysis
Authors: Sabui Piyali , Mallick Sadhucharan , Singh Kshitij RB , Natarajan Arunadevi , Verma Ranjana , Singh Jay , Singh Ravindra Pratap 
Published: November 2022

AbstractFood safety and quality are among the most significant and prevalent research areas worldwide. The fabrication of appropriate technical procedures or devices for the recognition of hazardous features in foods is essential to safeguard food materials. In the recent era, developing high‐performance sensors based on carbon nanomaterial for food safety investigation has made noteworthy progress. Hence this review briefly highlights the different detection approaches (colorimetric sensor, fluorescence sensor, surface‐enhanced Raman scattering, surface plasmon resonance, chemiluminescence, and electroluminescence), functional carbon nanomaterials with various dimensions (quantum dots, graphene quantum dots) and detection mechanisms. Further, this review emphasizes the assimilation of carbon nanomaterials with optical sensors to identify multiple contaminants in food products. The insights of carbon‐based nanomaterials optical sensors for pesticides and insecticides, toxic metals, antibiotics, microorganisms, and mycotoxins detection are described in detail. Finally, the opportunities and future perspectives of nanomaterials‐based optical analytical approaches for detecting various food contaminants are discussed.
Prognostic significance of three‐tiered pathological classification for microvascular invasion in patients with combined hepatocellular‐cholangiocarcinoma following hepatic resection
Authors: Wu Yijun , Liu Hongzhi , Chen Yifan , Zeng Jianxing , Huang Qizhen , Zhang Jinyu , Zeng Yongyi , Liu Jingfeng 
Published: November 2022

AbstractBackground and ObjectivesPrevious studies have reported that the microvascular invasion three‐tiered grading (MiVI‐TTG) scheme is a better prognostic predictor than the two‐tiered microvascular invasion (MiVI) grading scheme in hepatocellular carcinoma. This study aims to explore the prognostic significance of MiVI‐TTG in patients undergoing liver resection for combined hepatocellular‐cholangiocarcinoma (cHCC) and to explore the risk factors for MiVI in cHCC.MethodsThis research included 208 patients graded as M0, M1, or M2 using the MiVI‐TTG scheme. Predictive performance was assessed by Cox regression analysis, Kaplan–Meier curve with Log rank test, Harrell's c‐index, and time‐dependent areas under the receiver operating characteristic curve (tdAUC). The clinical utility of the two schemes was evaluated by decision cure analysis (DCA). The risk factors for MiVI were evaluated using logistic regression analysis.ResultsAmong 208 cHCC patients, the proportions of M0, M1 and M2 were 38.9%, 36.5%, and 24.5%, respectively. Patients with severe MiVI status had worse recurrence‐free survival and overall survival (OS) based on Kaplan–Meier analysis. M1, M2, and MiVI‐positive were independent risk factors for early recurrence, while M2 and MiVI‐positive were associated with overall survival (OS). MiVI‐TTG had a larger c‐index, tdAUC, and net benefit rate than the two‐tiered MiVI grading scheme for predicting recurrence free survival and OS. AFP≥400 ng/ml was the independent risk factor for MiVI, and satellite nodules were independent risk factors for M2.ConclusionsMiVI‐TTG has a greater prognostic value than the two‐tiered MiVI grading scheme in patients undergoing hepatic resection for cHCC.
Non‐compromise extreme effect: Attribute discriminability and preference for an extreme alternative
Authors: Banerjee Pronobesh , Masters Tamara , Chatterjee Promothesh 
Published: November 2022

AbstractIn this research, we show that despite a choice set configuration that promotes the compromise effect, consumers do not always prefer the middle alternative but rather choose the extreme option when one of the attributes has higher discriminability than the other. We use findings from the numerical cognition literature to demonstrate why this happens and, more importantly, provide a novel theoretical framework for what we call the “non‐compromise extreme effect.” The findings are unique to the compromise effect literature, which has consistently shown the effect to be robust. More importantly, the findings show that a brand can successfully compete with a well‐established competitor when it performs better on the low performing attribute, which gives a leeway to managers to take share away from the competitor.
Effect of the B4C particles on the brazed joints of SiC ceramics and 2219 aluminum alloy
Authors: Li Xianfen , Cai Kai , Teng Peng , Hua Peng , Cheng Huimin , Zhou Wei 
Published: November 2022

AbstractA two‐step process, including the premetallization of the SiC ceramic by Ag‐26.7Cu‐4Ti+B4C and the followed brazing with the Al‐based filler alloy, was developed to join 2219 aluminum alloy and the metallized SiC. The influence of metallization temperature and the B4C addition on the microstructure and mechanical properties of the joint was analyzed. The reaction products of Ti and B4C were detected in the brazing seam, such as Ti2B, TiC and graphite. With increasing of metallization temperature and B4C addition content, the shear strength of joint first increased and then decreased. The joint shear strength reached 14.0 MPa when SiC metallized with Ag‐26.7Cu‐4Ti+1%B4C at 930°C for 10 min, which showed that appropriate addition of B4C in Ag‐26.7Cu‐4Ti metallization layer could regulate the coefficient of thermal expansion difference between 2219 aluminum alloy and SiC to relieve the residual stress and improve the shear strength of their brazed joint.
Trends in Single‐Use Mixing for Biomanufacturing with an Insight Into Lonza Ibex® Solutions
Authors: de Boulard Arnaud , Kienle Klaus 
Published: November 2022

AbstractBiologics manufacturing has seen many new developments in recent years. The industry is moving away from processing systems based on stainless steel (with cleaning and validation requirements) to single‐use systems (sterilized, disposable plastics). This communication presents an overview of the current single‐use mixing technology landscape, requirements and challenges driven by the need for versatile biomanufacturing platforms with increased productivity. A case study is presented with an insight into Lonza Ibex® Solutions.
Early‐life stress and current stress predict BMI and height growth trajectories in puberty
Authors: Zhong Danruo , Reid Brie M. , Donzella Bonny , Miller Bradley S. , Gunnar Megan R. 
Published: November 2022

AbstractIn cross‐sectional analyses, early institutional care is associated with shorter stature but not obesity during puberty in children adopted into US families. We examined whether shorter stature and leaner body composition in youth adopted internationally from institutions would continue as puberty progressed. We also examined whether current psychosocial stress would moderate the association between early institutional deprivation and growth during adolescence. Using an accelerated longitudinal design and linear mixed‐effects models, we examined the height and body mass index (BMI) of 132 previously institutionalized (PI) and 176 nonadopted (NA) youth. We examined youth aged 7–15 at the beginning of the study three times across 2 years. Nurses assessed anthropometrics and pubertal status. Current psychosocial stress was measured using the Youth Life Stress Interview. Our results indicated that PI youth remained shorter and leaner across three assessments than NA youth. However, age‐and‐sex‐adjusted BMI increased faster in PI youth. Psychosocial stress during puberty predicted greater age‐and‐sex‐adjusted BMI, but this effect did not differ by group. The gap in BMI but not height appears to close between PI and NA youth. Higher psychosocial stress was associated with higher BMI during puberty.
Adolescent nicotine administration impacts working memory and reversal learning but not cognitive flexibility
Authors: Rodefer Joshua S. , Maitland Sarah C. 
Published: November 2022

AbstractThere has been increased interest in early exposure to nicotine through tobacco products and vaping specifically as it relates to addiction, yet fewer studies have focused on whether behavioral effects resulting from early nicotine exposure may persist into adulthood. Our experiments tested the hypothesis that exposure to nicotine during adolescence would impair selective aspects of behavioral cognition in rodents in adulthood. Male and female adolescent rats received either nicotine (0.4 mg/kg) or vehicle injections (intraperitoneal) once daily for 10 days (PND 29–38) followed by a washout period before behavioral testing. Animals were followed in a longitudinal design and evaluated on a battery of both behavioral and cognitive tasks during adulthood (PND 90+) that included locomotor activity, working memory (novel object recognition), cognitive flexibility (attentional set‐shifting task, ASST), and anxiety‐like behaviors. Data suggested that subchronic exposure to nicotine during adolescence produced significant changes in working memory, in two reversal problems in the ASST, and in anxiety‐related behaviors. Taken together these data may suggest that limited early exposure to nicotine may produce selective longer term impairments in cognitive and behavioral processes related to working memory and reversal learning.
Enhancement on parallel wall distance calculation methodology for partitioned unstructured grid
Authors: Zhi Haolin , Deng Shuanghou , Xiao Tianhang , Chen Zhaolin 
Published: November 2022

AbstractMinimum distance to a solid wall is a primary parameter in turbulence models and overset grid assembly for computational fluid dynamics. In present work, a parallel advancing front method is proposed based on partitioned unstructured grids for the sake of further efficient wall distance computation. In order to overcome the inherent problem of conventional advancing front method in parallel environment, a novel “advancing twice and rippling once” strategy is developed to compute wall distance efficiently and further recover the accuracy. Significantly, the established framework is of modular nature to be easily extended to overset grid system for complex multi‐body configurations. The performance of the developed techniques is evidenced by comparison with the existing alternative ways in terms of computing efficiency and accuracy. Subsequently, further case studies are performed to examine its capability to deal with complex engineering applications such as a full transportation, a wing‐store configuration, a helicopter and a F‐16 fighter with onboard payloads. Results show that the proposed advancing front methodology is in practice able to solve extremely complex geometries with both convex and concave shapes with high efficiency and robustness.
Applying the Safe Operating Space (SOS) Approach to Sustainable Commercial Fishing under Varying Lake Levels and Littoral Zone Conditions
Authors: Ofir Eyal , Silver Tal , Steenbeek Jeroen G , Shachar Noam , Gal Gideon 
Published: November 2022

Abstract
Successful management of lake ecosystems and the ecosystem services they provide necessitates ecosystem-based management. The application of ecosystem-based management can assist in achieving sustainable management of the ecosystem to ensure continued and sustainable supply of ecosystem services such as fisheries. One concept for defining sustainable fishing is the Safe Operating Space (SOS). In our study, we apply the Ecopath with Ecosim suite of models to predict the SOS required for the management of a commercial fishery. We use the Lake Kinneret (Israel) ecosystem as a case study to illustrate the approach by developing an Ecospace model of the lake and incorporating the spatio-temporal framework and varying environmental conditions. We test, and demonstrate, the methodology for developing a SOS for a commercial fish population that can be implemented by lake managers elsewhere and illustrate it's use by defining example target values of biomass (e.g., 200 and 250 tons) and catch (e.g., 125 tons/year). Our results show that the SOS for a given target can be defined by a range of fishing efforts and vegetation cover in the lake as a function of lake level. The complexity in defining the actual values highlight the benefit of the approach we present here.
Translating Genetic Discovery into a Mechanistic Understanding of Pediatric Movement Disorders: Lessons from Genetic Dystonias and Related Disorders
Authors: Lin Wei‐Sheng 
Published: November 2022

AbstractThe era of next‐generation sequencing has increased the pace of gene discovery in the field of pediatric movement disorders. Following the identification of novel disease‐causing genes, several studies have aimed to link the molecular and clinical aspects of these disorders. This perspective presents the developing stories of several childhood‐onset movement disorders, including paroxysmal kinesigenic dyskinesia, myoclonus‐dystonia syndrome, and other monogenic dystonias. These stories illustrate how gene discovery helps focus the research efforts of scientists trying to understand the mechanisms of disease. The genetic diagnosis of these clinical syndromes also helps clarify the associated phenotypic spectra and aids the search for additional disease‐causing genes. Collectively, the findings of previous studies have led to increased recognition of the role of the cerebellum in the physiology and pathophysiology of motor control—a common theme in many pediatric movement disorders. To fully exploit the genetic information garnered in the clinical and research arenas, it is crucial that corresponding multi‐omics analyses and functional studies also be performed at scale. Hopefully, these integrated efforts will provide us with a more comprehensive understanding of the genetic and neurobiological bases of movement disorders in childhood.
Pregnant individuals' information needs and intention to vaccinate their children with routine and COVID‐19 vaccines: Findings from a cross‐sectional survey
Authors: Vasudevan Lavanya , Stinnett Sandra S. , Hart Lauren , Gomez Altamirano Pedro , Gonzalez Angel , Weaver Kristin , Gray Beverly , Bartlett John 
Published: November 2022

AbstractObjectiveThe current study assessed pregnant individuals' intention to accept routine and COVID‐19 vaccines for their baby after birth, and to identify key demographic (e.g., age) and nondemographic characteristics (e.g., prior birth) associated with vaccination intention.MethodsThe authors conducted a cross‐sectional survey with pregnant individuals attending prenatal practices affiliated with a large academic medical center and two rural county health departments in the southeastern United States. The survey included 11 questions and was self‐administered by pregnant individuals in clinic settings. The final analysis included responses from 443 pregnant individuals.ResultsOnly 67% of pregnant individuals planned to vaccinate their baby with all recommended routine vaccines; an additional 22% reported having questions about recommendations. Only 35% of pregnant individuals said they would vaccinate their baby as soon as possible with a COVID‐19 vaccine. Younger pregnant individuals and those identifying as Black or African American had lower routine and COVID‐19 vaccination intention. Routine vaccination, but not COVID‐19 vaccination intention, was associated with familiarity with routine vaccination schedule, trimester of pregnancy, Hispanic ethnicity, history of prior birth, and having access to a computer.ConclusionStudy findings support differential tailoring of future interventions targeting pregnant individuals to promote routine and COVID‐19 vaccines for children.
Vaccination in pregnancy: Healthcare provider attitudes and practices
Authors: Rodriguez Gabriella F. , Vilariño Valerie , Agasse Eva , St. Onge Joan E. , Shafazand Shirin , Potter JoNell 
Published: November 2022

AbstractObjectiveTo assess provider attitudes and practices regarding vaccination in pregnancy to discern strategies to increase vaccination rates in pregnancy, given that in the USA, various healthcare organizations recommend that pregnant individuals be vaccinated against influenza, pertussis, and SARS‐CoV‐2, but vaccination rates among gravidas remain suboptimal across these vaccines.MethodsAn Institutional Review Board‐approved survey was disseminated to obstetric healthcare providers by email from June through October 2021. Questions assessed provider demographics, attitudes, and practices surrounding vaccination in pregnancy. A total of 192 providers consented, 179 initiated the survey, and 153 completed it entirely. Statistical software (SAS) was used to perform descriptive statistics.ResultsAll providers strongly agreed/agreed that all pregnant individuals should receive vaccines in pregnancy. Following patient vaccination consent, 13% reported needing to refer patients to alternative sites for vaccine administration. Following patient vaccination decline, 13% did not determine reasons for refusal, 30% did not re‐counsel at subsequent visits, and 92% did not ask another staff member to counsel the patient.ConclusionDespite provider support for maternal immunization, uptake of vaccines in gravidas remains suboptimal, demonstrating a gap between provider recommendations and patient uptake. These data highlight opportunities for intervention regarding counseling and vaccine availability to increase vaccine uptake in pregnancy.