bluuebunny/crossref_metadata_2025_split huggingface dataset:
Conceptual Metaphor of Different Conventionality Levels from the Perspectives of Translatability Assessment and Translation Strategies
Authors: Nguyen Thong Vi , Hien Nguyen Thi Thao 
Published: December 2022

This study examines the Conceptual Metaphor Theory from an innovative perspective: translatability and translation strategy. The experiment recruited 239 undergraduate students of different translation training to evaluate the translatability of twelve sentences of different metaphor types before translating them into Vietnamese. Additionally, this study examines how students deal with metaphorical mapping images as well as grammatical and lexical refining attempts. The factorial ANOVA results (p=.02) indicate that the effect of metaphor types on translatability levels is conditional on translation training levels, despite the fact that the main effect is on metaphor types, not translation skill. Besides, twelve in-depth strategies to deal with the source sentences are identified, establishing a new model for metaphorical translation strategy. Chi-square analysis reveals associations between translation training levels and strategies (p<.01); and between metaphor types and strategies (p<.01). This study argues for the possibility that translation could be considered among conceptual metaphor's cognitive mechanisms.
Airborne Instrumentation for Aerosol Measurements
Authors: Stefanutti Leopoldo , Donfrancesco Guido Di , Guzzi Rodolfo 
Published: December 2022

Abstract
The airborne, satellite, and balloon‐borne instrumentation is a powerful tool for the measurement of microphysical properties and the chemical composition of aerosol and cloud particles. Such instruments can be subdivided into two broad categories: remote sensing instrumentation and in situ instrumentation. In the first category, there are dynamic instrumentation like cloud RADARs (radio detection and ranging), LIDARs (light detection and ranging), and backscattersondes. In contrast, in the second category, there are passive instruments like multispectral and hyperspectral instruments for zenith measurements or limb/occultation detections. Both categories can determine the microphysical properties of the aerosols while the second category can, although only with complex a priori assumptions, also determine their chemical composition. This article is an updated discussion on different types of such airborne aerosol instruments, considering their detection limits and ranges, reliability, and applications. The paper also briefly describes the different platforms available for airborne aerosol/satellite instrumentation along with different payload configurations.
Quantitative Analysis, Infrared
Authors: Cadet Frédéric , Pérez‐Guaita David , Garrigues Salvador , de la Guardia Miguel 
Published: December 2022

AbstractIn this article, after reviewing the different mathematical methods used in quantification by IR, the main advantages and drawbacks and applications with or without previous sample treatment are presented. The bases of the use of quantitative IR in food analysis such as lipids (measurement of unsaturation degrees and lipids determination), carbohydrates, and proteins (secondary structures and quantitative analysis); original examples of the use of IR spectroscopy combined with enzymes; and modern applications in the clinical field are presented in detail, followed by examples of Fourier transform infrared (FTIR) analysis coupled with other analytical methods in different fields such as pharmaceuticals, petroleum, paints, and other industrial products and in the fields of health, environment, and trace compounds analysis in order to think about the limitations and perspectives of IR spectroscopy for quantitative analysis. It appears that the most significant developments in the field of quantitative analysis will probably come through the progress in chemometrics and instrumentation. More recently, approaches combining infrared spectroscopy and deep learning (DL) have shown great potential.
Local Indicators of Spatial Association (LISA)
Authors: Scharf Henry 
Published: December 2022

AbstractLocal indicators of spatial association (LISAs) are a family of statistics with useful mathematical properties that can help researchers identify areas where an observed process is structurally distinct from broader patterns of variation. Some important ways that observed values in an area can differ from the broader pattern are: (i) values tend to be much higher (hot spots) or lower (cold spots) than average and (ii) values tend to be more/less similar across neighboring locations (positive/negative autocorrelation) than in other parts of the study area. This article introduces LISAs, discusses common uses and potential pitfalls, and provides an application of two commonly used LISAs and a related visualization tool, the Moran scatterplot, to rates of cyclist injury in San Diego County, California.
Xenodocheion
Authors: Miller Timothy S. 
Published: December 2022

Abstract

Xenodocheion
was a Greek term for new Christian philanthropic institutions that appeared during the fourth century
ce
in the Eastern Roman Empire. Although
xenodocheion
occasionally served as a synonym for
pandocheion
(commercial inn), after 300
ce
it referred exclusively to hospices offering free lodging to travelers and homeless poor (Kislinger 1984: 171–5).
Petra papyri
Authors: Frösén Jaakko 
Published: December 2022

Abstract

The discovery of the remnants of ca. 140 charred papyrus rolls during the excavations of the Petra church in 1993 substantially expanded our knowledge of the Byzantine city. At the end of the sixth or beginning of the seventh century
ce
, a fire destroyed the church, also affecting the room where the papyri were kept.
Homosexuality (homoeroticism), female
Authors: Brooten Bernadette J. 
Published: December 2022

Abstract
“Homosexuality” is a modern medical category that is unsuited for the ancient Mediterranean world, whereas “homoeroticism,” while also contemporary, is more neutral. Sources from Archaic Greece through to Late Antique Egypt in Greek, Latin, Hebrew, Coptic, and Arabic attest to female homoerotic desire and to erotic contact between women and possibly between women and persons with ambiguous genitalia. Whereas such desire and contact were celebrated in Archaic Greece, by the time of the Roman Empire and into Late Antiquity, they were largely vilified, frequently defined as “contrary to nature.”
Flexible Skin Patch Enabled Tumor Hybrid Thermophysical Therapy and Adaptive Antitumor Immune Response
Authors: Sun Xuyang , Wu Tao , Duan Minghui , Yuan Bo , Zhu Xiyu , Wang Hongzhang , Liu Jing 
Published: December 2022

AbstractInnovations on materials and technologies have greatly promoted the rapid development of wearable electronics from disease diagnosis to therapeutics. For superficial skin tumors, skin‐attachable patches possess the advantages of minimally invasive property, alleviative side effects, and high efficiency. The development of noninvasive techniques and devices is still in urgent demands. Here, a flexible skin patch fabricated through a facile preparation method is reported for noninvasive hybrid thermophysical therapy and adaptative immune function enhancement. The liquid metal enabled skin patch is demonstrated with high conductivity, certain stability, biocompatibility, and an enhanced adhesive merit on skin surfaces for cryoablation therapy and magnetic hyperthermia therapy. The skin patch exhibits remarkably conformable heating and cooling performance toward the treatment of 4T1 breast tumors. The magnetic resonance images also indicate the significant tumor ablation effect. Interestingly, a relatively stable proportion of both CD8+ T and CD4+ T cells in the peripheral blood is identified after tumor therapy in comparison with the decreased trend in the untreated group, representing an efficient antitumor immune response induced by the skin patch. The developed skin patch would provide a promising noninvasive approach for tumor therapies by direct tumor destruction and maintenance of the antitumor immune response.
3D Cold‐Trap Environment Printing for Long‐Cycle Aqueous Zn‐Ion Batteries
Authors: Lu Hongyu , Hu Jisong , Zhang Yan , Zhang Kaiqi , Yan Xiaoying , Li Heqi , Li Jianzhu , Li Yujie , Zhao Jingxin , Xu Bingang 
Published: December 2022

AbstractZn powder (Zn‐P)‐based anodes are always regarded as ideal anode candidates for zinc ion batteries owing to their low cost and ease of processing. However, the intrinsic negative properties of Zn‐P‐based anodes such as easy corrosion and uncontrolled dendrite growth have limited their further applications. Herein, a novel 3D cold‐trap environment printing (3DCEP) technology is proposed to achieve the MXene and Zn‐P (3DCEP‐MXene/Zn‐P) anode with highly ordered arrangement. Benefitting from the unique inhibition mechanism of high lattice matching and physical confinement effects within the 3DCEP‐MXene/Zn‐P anode, it can effectively homogenize the Zn2+ flux and alleviate the Zn deposition rate of the 3DCEP‐MXene/Zn‐P anode during Zn plating–stripping. Consequently, the 3DCEP‐MXene/Zn‐P anode exhibits a superior cycling lifespan of 1400 h with high coulombic efficiency of ≈9.2% in symmetric batteries. More encouragingly, paired with MXene and Co doped MnHCF cathode via 3D cold‐trap environment printing (3 DCEP‐MXene/Co‐MnHCF), the 3DCEP‐MXene/Zn‐P//3DCEP‐MXene/Co‐MnHCF full battery delivers high cyclic durability with the capacity retention of 95.7% after 1600 cycles. This study brings an inspired universal pathway to rapidly fabricate a reversible Zn anode with highly ordered arrangement in a cold environment for micro‐zinc storage systems.
Three‐Dimensional Reconstruction of Conductive Filaments in HfOx‐Based Memristor
Authors: Wei Tiantian , Lu Yuyao , Zhang Fan , Tang Jianshi , Gao Bin , Yu Pu , Qian He , Wu Huaqiang 
Published: December 2022

AbstractHfOx‐based memristor has been studied extensively as one of the most promising memories for the excellent nonvolatile data storage and computing‐in‐memory capabilities. However, the resistive switching mechanism, relying on the formation and rupture of conductive filaments (CFs) during device operations, is still under debate. In this work, the CFs with different morphologies after different operations—forming, set, and reset—are clearly revealed for the first time by 3D reconstruction of conductive atomic force microscopy (c‐AFM) images. Intriguingly, multiple CFs are successfully observed in HfOx‐based memristor devices with three different resistive states. CFs after forming, set, and reset exhibit the typical morphologies of hourglass, inverted‐cone, and short‐cone, respectively. The rupture location of CFs after the reset operation is also observed clearly. These findings reveal the microscopic behaviors underlying the resistive switching, which could pave the road to design and optimize oxide‐based memristors for both memory and computing applications.
High‐Radiance Near‐Infrared Perovskite Light‐Emitting Diodes with Improved Roll‐Off Degradation
Authors: Yu Maotao , Ji Yongqiang , Yan Haoming , Hu Jinhao , Li Shunde , Xu Hongyu , Chen Peng , Zhao Lichen , Guan Shuzhen , Bi Xiaoyin , Yang Xiaoyu , Jia Shuang , Yi Chang , Luo Deying , Wang Jianpu , Lu Zheng‐Hong , Gong Qihuang , Zhu Rui 
Published: December 2022

AbstractThe external quantum efficiency (EQE) of state‐of‐the‐art near‐infrared perovskite light‐emitting diodes (PeLEDs) is now approaching the limit set by the out‐coupling efficiency. However, there is plenty of room for enhancing these devices’ radiance and the EQE roll‐off. This work reports how conductive and passivating additives construct efficient high‐radiance near‐infrared PeLEDs with improved EQE roll‐off. Specifically, the synergistic effect of 1,4‐phenylenediacetic acid (PDA) and 5‐aminovaleric acid (5‐AVA) is used to regulate the quality of the perovskite emissive layer, thereby enhancing the roll‐off threshold of injection currents (a value at which the device EQE or radiance starts degrading). According to in situ structural evolution analyses from the perovskite precursor to the perovskite crystal, the presence of PDA within the perovskite precursor solution can produce an intermediate phase with 5‐AVA and formanmidinium cation, which can retard the perovskite nucleation and crystal growth, leading to improved perovskite film quality. The resulting champion PeLED delivers among the highest radiance of 505 W sr−1 m−2 and a peak EQE of 17.56%. More importantly, the improved PeLED shows a well‐retained radiance of 80% at a current injection density of up to ≈1800 mA cm−1, opening a new avenue for high‐radiance PeLEDs with improved roll‐off degradation.
Tailored p‐Orbital Delocalization by Diatomic Pt‐Ce Induced Interlayer Spacing Engineering for Highly‐Efficient Ammonia Electrosynthesis
Authors: Chen Dong , Zhang Shaoce , Yin Di , Li Wanpeng , Bu Xiuming , Quan Quan , Lai Zhengxun , Wang Wei , Meng You , Liu Chuntai , Yip SenPo , Chen Fu‐Rong , Zhi Chunyi , Ho Johnny C. 
Published: December 2022

AbstractElectrochemical nitrate reduction to ammonia (eNO3RR) is a green and appealing method for ammonia synthesis, but is hindered by the multistep chemical reaction and competitive hydrogen generation. Herein, the synthesis of 2D SnS nanosheets with tailored interlayer spacing is reported, including both expansion and compression, through the active diatomic Pt‐Ce pairs. Taking together the experimental results, in situ Raman spectra, and DFT calculations, it is found that the compressed interlayer spacing can tune the electron density of localized p‐orbital in Sn into its delocalized states, thus enhancing the chemical affinity towards NO3− and NO2− but inhibiting hydrogen generation simultaneously. This phenomenon significantly facilitates the rate‐determining step (*NO3→*NO2) in eNO3RR, and realizes an excellent Faradaic efficiency (94.12%) and yield rate (0.3056 mmol cm−2 h−1) for NH3 at −0.5 V versus RHE. This work provides a powerful strategy for tailoring flexible interlayer spacing of 2D materials and opens a new avenue for constructing high‐performance catalysts for ammonia synthesis.
Agrifood system participation and production efficiency among smallholder vegetable farmers in Northern Ghana
Authors: Abdul‐Rahaman Awal , Issahaku Gazali , Ma Wanglin 
Published: December 2022

AbstractFormalized marketing arrangements between smallholder farmers and produce buyers are gradually replacing spot market transactions in developing countries due to the rapid structural transformation of agrifood systems. This study examines the impact of agrifood system participation on the total value of vegetable production and technical efficiency (TE), using a sample of 423 vegetable farmers from Northern Ghana. We employ propensity score matching and W. Greene's selection bias‐corrected stochastic production frontier methods to correct for observable and unobservable selection bias issues, respectively. We further use a metafrontier model to derive technology gap ratios (TGRs) and meta‐TE for agrifood system participants and nonparticipants. The results reveal that agrifood system participants are about 50% more productive than nonparticipants. In addition, participants have higher meta‐TE (58% vs. 55%) and TGR (98% vs. 94%) than nonparticipants. Variables such as farmer group membership, extension visits, mobile phone ownership, irrigation and road access are the notable correlates of smallholder farmers' participation in agrifood systems. The total value of vegetable production is significantly influenced by fertilizer, agrochemicals, seeds, irrigation, soil fertility, and location‐fixed effects. [EconLit Citations: D24, Q12, Q18]
A diagnosis of Birt–Hogg–Dubé syndrome in individuals with Smith–Magenis syndrome: Recommendation for cancer screening
Authors: Vocke Cathy D. , Fleming Leah R. , Piskorski Anna M. , Amin Ali , Phornphutkul Chanika , de la Monte Suzanne , Vilboux Thierry , Duncan Folami , Pellegrino Joan , Braddock Bonnie , Middelton Lindsay A. , Schmidt Laura S. , Merino Maria J. , Cowen Edward W. , Introne Wendy J. , Linehan W. Marston , Smith Ann C. M. 
Published: December 2022

AbstractWe report a series of four unrelated adults with Smith–Magenis syndrome (SMS) and concomitant features of Birt–Hogg–Dubé (BHD) syndrome based upon haploinsufficiency for FLCN and characteristic renal cell carcinomas and/or evidence of cutaneous fibrofolliculomas. Three of the cases constitute the first known association of histopathologically verified characteristic BHD‐associated renal tumors in adults with SMS; the fourth was identified to have histologically confirmed skin fibrofolliculomas. Molecular analysis documented second‐hit FLCN mutations in two of the three cases with confirmed BHD renal pathology. These cases suggest the need to expand management recommendations for SMS to include kidney cancer surveillance starting at 20 years of age, as per the screening recommendations for BHD syndrome.
Self‐Adaptive Re‐Organization Enables Polythiophene as an Extraordinary Cathode Material for Aluminum‐Ion Batteries with a Cycle Life of 100 000 Cycles
Authors: Zhang Junfei , Wu Yunling , Liu Miao , Huang Lu , Li Yanguang , Wu Yingpeng 
Published: December 2022

AbstractAluminum‐ion batteries (AIBs) have attracted great attentions in recent years. Organic materials such as polythiophene (PT) are promising cathode for AIBs. However, the capacity and cyclic stability of conventional organic cathode such as PT are limited by the inadequate degree of reaction and the unstable nature of organic materials. To obtain high‐performance organic cathode, a new PT with the ability of self‐adaptive re‐organization was prepared. During cycling, its molecular chain can be re‐organized, and the polymerization mode will change from Cα−Cα(α‐PT) to Cβ−Cβ(β‐PT). This change leads to smaller steric hindrance and faster kinetics during ion insertion which can lower the reaction energy barrier and stabilize the molecular structure. Benefited by this, AIBs with this cathode can deliver a specific capacity of 180 mAh g−1(@2 A g−1) and a superb stability of 100 000 cycles at 10 A g−1. High energy density and power density can also be achieved with this cathode.
Twisting of Porphyrin by Assembly in a Metal‐Organic Framework yielding Chiral Photoconducting Films for Circularly‐Polarized‐Light Detection
Authors: Li Chun , Schopmans Henrik , Langer Lukas , Marschner Stefan , Chandresh Abhinav , Bürck Jochen , Tsuchiya Youichi , Chihaya Adachi , Wenzel Wolfgang , Bräse Stefan , Kozlowska Mariana , Heinke Lars 
Published: December 2022

AbstractWhile materials based on organic molecules usually have either superior optoelectronic or superior chiral properties, the combination of both is scarce. Here, a crystalline chiroptical film based on porphyrin with homochiral side groups is presented. While the dissolved molecule has a planar, thus, achiral porphyrin core, upon assembly in a metal–organic framework (MOF) film, the porphyrin core is twisted and chiral. The close packing and the crystalline order of the porphyrin cores in the MOF film also results in excellent optoelectronic properties. By exciting the Soret band of porphyrin, efficient photoconduction with a high On‐Off‐ratio is realized. More important, handedness‐dependent circularly‐polarized‐light photoconduction with a dissymmetry factor g of 4.3×10−4 is obtained. We foresee the combination of such assembly‐induced chirality with the rich porphyrin chemistry will enable a plethora of organic materials with exceptional chiral and optoelectronic properties.
Selective hydroxyalkoxylation of epoxidized methyl oleate by an amphiphilic ionic liquid catalyst
Authors: Winfield DeMichael D. , Moser Bryan R. 
Published: December 2022

AbstractOleic acid is an attractive biobased platform chemical. Precursors for biobased materials can be accessed by epoxidation and subsequent hydroxyalkoxylation of oleic acid. The hydroxyalkoxylation step is conventionally performed with sulfuric acid or a metal catalyst. Due to their high polarity, many ionic liquid catalysts are ineffective for hydroxyalkoxylation of fatty acid derivatives with non‐polar alcohols. In this work, we utilized an amphiphilic ionic liquid catalyst to perform hydroxyalkoxylations of epoxidized methyl oleate. An ionic liquid catalyst based on dimethyl lauryl amine was synthesized and evaluated for this reaction due to its long alkyl group. The amphiphilic nature of the ionic liquid allowed for better miscibility and reactivity compared to other ionic liquids. Several alcohols were used with high yields (≥80%) and selectivity (≥92%), including nonpolar alcohols with longer alkyl chains such as octanol and dodecanol. The high selectivity of these conditions could be advantageous for applications in lubricants, biofuels, or polyol preparation. This work demonstrates a greener alternative to conventional hydroxyalkoxylation catalysts.
Edge Site Catalyzed Vanadyl Oxidation Elucidated byOperandoRaman Spectroscopy
Authors: Radinger Hannes , Bauer Felix , Scheiba Frieder 
Published: December 2022

AbstractThe kinetic processes responsible for the efficient oxidation of dissolved vanadyl oxide species in the positive half‐cell of a vanadium flow battery are far from being understood. Despite recent evidence that the reaction is most strongly favored at hydrogen‐terminated graphite edge sites, a mechanism involving oxygen‐containing surface groups has still been frequently reproduced to date. In this work,operandoRaman spectroscopy follows the reaction at the interface between graphite‐based model electrodes and vanadium‐containing sulfuric acid as the electrolyte. The potential‐dependent growth of different vibrational modes is related to the electrocatalytic activity of the sample and allows to track the oxidation of the electrolyte species. Moreover, the results express vanadium reaction intermediates of dimeric origin only on the edge‐exposed surface of graphite, which exhibits significantly higher electrochemical activity. No interaction with surface oxygen postulated before could be observed for the active electrodes at potentials relevant to the reaction. Instead, a new growing graphite‐related feature shows direct electronic interactions between vanadium ions and carbon atoms during charge transfer.
Self‐control is negatively linked to prosociality in young children
Authors: Barragan‐Jason Gladys , Hopfensitz Astrid 
Published: December 2022

AbstractHuman prosociality is a valuable but also deeply puzzling trait. While several studies suggest that prosociality is an impulsive behavior, others argue that self‐control is necessary to develop prosocial behaviors. Yet, prosociality and self‐control in children have rarely been studied jointly. Here, we measured self‐control (i.e., delay‐of‐gratification) and prosociality (i.e., giving in a dictator game) in 250 4‐ to 6‐year‐old French schoolchildren. Contrary to previous studies, we found a negative relationship between waiting in the delay‐of‐gratification task and giving in the dictator game. The effect was especially pronounced when the partner in the dictator game was unknown compared with giving in a dictator game where the partner was a friend. Our results suggest that self‐control is not always necessary to act prosocially. Future studies investigating whether and how such pattern develops across the lifespan and across cultures are warranted.