bluuebunny/crossref_metadata_2025_split huggingface dataset:
Mechanism of hopping conduction in Be–Fe–Al–Te–O semiconducting glasses and glass–ceramics
Authors: Wójcik Natalia A. , Tagiara Nagia S. , Möncke Doris , Kamitsos Efstratios I. , Ali Sharafat , Ryl Jacek , Barczyński Ryszard J. 
Published: January 2022

AbstractElectrical properties of beryllium-alumino-tellurite glasses and glass–ceramics doped with iron ions were studied using impedance spectroscopy. The conductivity was measured over a wide frequency range from 10 mHz to 1 MHz and the temperature range from 213 to 473 K. The D.C. conductivity values showed a correlation with the Fe-ion concentration and ratio of iron ions on different valence states in the samples. On the basis of Jonscher universal dielectric response the temperature dependence of conductivity parameters were determined and compared to theoretical models collected by Elliott. In glasses, the conduction process was found to be due to the overlap polaron tunneling while in glass–ceramics the quantum mechanical tunneling between semiconducting crystallites of iron oxides is proposed. The D.C. conductivity was found not to follow Arrhenius relation. The Schnakenberg model was used to analyze the conductivity behavior and the polaron hopping energy and disorder energy were estimated. Additionally, the correlation between alumina dissolution and basicity of the melts was observed.
Social emotional ability development (SEAD): An integrated model of practical emotion-based competencies
Authors: Harris Victor W. , Anderson Jonathan , Visconti Brian 
Published: January 2022

AbstractSocial emotional abilities (i.e., specific skills), defined as the set of cognitive abilities, emotion-based knowledge, and behavioral competencies (i.e., skill levels) that facilitate adaptively employing prosocial processes and behaviors (i.e., “actions”), such as emotional regulation and sympathetic and empathetic response behaviors, is contemporarily modeled and measured as emotional intelligence. This conceptualization can be problematic, however, as the two concepts are not the same and traditional methods of measuring emotional intelligence can have limited practical utility. The social emotional ability development (SEAD) theoretical model introduced in this treatise represents a pragmatic and simplified approach to the development of social emotional ability and competency as abstracted from constructs of emotional intelligence, social intelligence, and sociocultural learning theory. Further, the SEAD model reaches beyond the individual as the unit of analysis to explore, conceptualize, differentiate, investigate, and define the hierarchal, bi-directional, and contextual nature of the dimensions of social emotional ability within close relationships. Implications for how the SEAD model can be used by researchers, practitioners, educators, individuals, families, and couples across a broad spectrum of domains and interventions are discussed.
Taking phenomenology beyond the first-person perspective: conceptual grounding in the collection and analysis of observational evidence
Authors: Klinke Marianne Elisabeth , Fernandez Anthony Vincent 
Published: January 2022

Abstract
Phenomenology has been adapted for use in qualitative health research, where it’s often used as a method for conducting interviews and analyzing interview data. But how can phenomenologists study subjects who cannot accurately reflect upon or report their own experiences, for instance, because of a psychiatric or neurological disorder? For conditions like these, qualitative researchers may gain more insight by conducting observational studies in lieu of, or in conjunction with, interviews. In this article, we introduce a phenomenological approach to conducting this kind of observational research. The approach relies on conceptual grounding to focus a study on specific aspects of the participants’ experiences. Moreover, the approach maintains the openness to novel discoveries that qualitative research requires while also providing a structured framework for data collection and analysis. To illustrate its practical application, we use examples of hemispatial neglect—a neurologic disorder in which patients characteristically lack awareness of their own illness and bodily capacities. However, the approach that we describe can be applied more broadly to the study of complex illness experiences and other experiential alterations.
Towards progressive regulatory approaches for agricultural applications of animal biotechnology
Authors: Hallerman Eric M. , Bredlau Justin P. , Camargo Luiz Sergio A. , Dagli Maria Lucia Zaidan , Karembu Margaret , Ngure Godfrey , Romero-Aldemita Rhodora , Rocha-Salavarrieta Pedro Jesús , Tizard Mark , Walton Mark , Wray-Cahen Diane 
Published: January 2022

AbstractTraditional breeding techniques, applied incrementally over thousands of years, have yielded huge benefits in the characteristics of agricultural animals. This is a result of significant, measurable changes to the genomes of those animal species and breeds. Genome editing techniques may now be applied to achieve targeted DNA sequence alterations, with the potential to affect traits of interest to production of agricultural animals in just one generation. New opportunities arise to improve characteristics difficult to achieve or not amenable to traditional breeding, including disease resistance, and traits that can improve animal welfare, reduce environmental impact, or mitigate impacts of climate change. Countries and supranational institutions are in the process of defining regulatory approaches for genome edited animals and can benefit from sharing approaches and experiences to institute progressive policies in which regulatory oversight is scaled to the particular level of risk involved. To facilitate information sharing and discussion on animal biotechnology, an international community of researchers, developers, breeders, regulators, and communicators recently held a series of seven virtual workshop sessions on applications of biotechnology for animal agriculture, food and environmental safety assessment, regulatory approaches, and market and consumer acceptance. In this report, we summarize the topics presented in the workshop sessions, as well as discussions coming out of the breakout sessions. This is framed within the context of past and recent scientific and regulatory developments. This is a pivotal moment for determination of regulatory approaches and establishment of trust across the innovation through-chain, from researchers, developers, regulators, breeders, farmers through to consumers.
Palladium-catalyzed enantioselective carbonylation reactions
Authors: Peng Jin-Bao , Liu Xin-Lian , Li Lin , Wu Xiao-Feng 
Published: January 2022

AbstractCarbonylation, one of the most powerful approaches to the preparation of carbonylated compounds, has received significant attention from researchers active in various fields. Indeed, impressive progress has been made on this subject over the past few decades. Among the various types of carbonylation reactions, asymmetric carbonylation is a straightforward methodology for constructing chiral compounds. Although rhodium-catalyzed enantioselective hydroformylations have been discussed in several elegant reviews, a general review on palladium-catalyzed asymmetric carbonylations is still missing. In this review, we summarize and discuss recent achievements in palladium-catalyzed asymmetric carbonylation reactions. Notably, this review’s contents are categorized by reaction type.
Protective Factors for Decreasing Nicotine, Alcohol, and Cannabis Use Among Adolescents with a History of Adverse Childhood Experiences (ACEs)
Authors: Afifi Tracie O. , Taillieu Tamara , Salmon Samantha , Stewart-Tufescu Ashley , Struck Shannon , Fortier Janique , MacMillan Harriet L. , Sareen Jitender , Tonmyr Lil , Katz Laurence Y. 
Published: January 2022

AbstractAdolescents who have experienced adversity have an increased likelihood of using substances. This study examined if individual-, family-, school-, and community-level protective factors were associated with a decreased likelihood of substance use. Data from the Well-Being and Experiences Study (the WE Study) collected from 2017 to 2018 were used. The sample was adolescents aged 14 to 17 years (N = 1002) from Manitoba, Canada. Statistical methods included descriptive statistics and logistic regression models. The prevalence of past 30-day substance use was 20.5% among boys and 29.2% among girls. Substance use was greater among adolescent girls compared to boys. Protective factors associated with an increased likelihood of not using substances included knowing culture or language, being excited for the future, picturing the future, sleeping 8 to 10 h per night (unadjusted models only), participating in non-sport activity organized by the school, having a trusted adult in the family, frequent hugs from parent, parent saying “I love you” (unadjusted models only), eating dinner together every day, mother and father understanding adolescent’s worries and problems, being able to confide in mother and father, feeling close to other students at school, having a trusted adult at school, feeling a part of school, having a trusted adult in the community (unadjusted models only), volunteering once a week or more, and feeling motivated to help and improve one’s community. Knowledge of protective factors related to decreased odds of substance use may help inform strategies for preventing substance use and ways to foster resilience among adolescents.
Combining haptics and inertial motion capture to enhance remote control of a dual-arm robot
Authors: Girbés-Juan Vicent , Schettino Vinicius , Gracia Luis , Solanes J. Ernesto , Demiris Yiannis , Tornero Josep 
Published: January 2022

AbstractHigh dexterity is required in tasks in which there is contact between objects, such as surface conditioning (wiping, polishing, scuffing, sanding, etc.), specially when the location of the objects involved is unknown or highly inaccurate because they are moving, like a car body in automotive industry lines. These applications require the human adaptability and the robot accuracy. However, sharing the same workspace is not possible in most cases due to safety issues. Hence, a multi-modal teleoperation system combining haptics and an inertial motion capture system is introduced in this work. The human operator gets the sense of touch thanks to haptic feedback, whereas using the motion capture device allows more naturalistic movements. Visual feedback assistance is also introduced to enhance immersion. A Baxter dual-arm robot is used to offer more flexibility and manoeuvrability, allowing to perform two independent operations simultaneously. Several tests have been carried out to assess the proposed system. As it is shown by the experimental results, the task duration is reduced and the overall performance improves thanks to the proposed teleoperation method.
High-resolution pressure transducer design and associated circuitry to build a network-ready smart sensor for distributed measurement in oil and gas production wells
Authors: Santos Edval J. P. , Silva Leonardo B. M. 
Published: January 2022

AbstractMiniaturized single-mode thickness-shear pressure transducer combined with high-temperature SOI, silicon on insulator, integrated circuit technology is proposed as network-ready high-pressure high-resolution smart sensor for distributed data acquisition in oil and gas production wells. The transducer miniaturization is investigated with a full 3D computer model previously developed by the authors to assess the impact of intrinsic losses and various geometrical features on transducer performance. Over the last decades there has been a trend toward size reduction of high-resolution pressure transducer. The implemented model provides insight into the evolution of high-resolution pressure transducers from Hewlett-Packard™ to Quartzdyne™ and beyond. Distributed measurement in production oil wells in extreme harsh environment, such as found in the pre-salt layer, is an unsolved problem. The industry move toward electrified wells offers an opportunity for application of smart sensor technology and power line communications to achieve distributed high-resolution data acquisition.
Tight oil reservoir production characteristics developed by CO2 huff ‘n’ puff under well pattern conditions
Authors: Xia Zhizeng , Wang Xuewu , Xu Rui , Ren Weiwei 
Published: January 2022

AbstractTight oil reservoirs have poor physical properties, and the problems including rapid oil rate decline and low oil recovery degree are quite common after volume fracturing. To obtain a general understanding of tight oil reservoir production improvement by CO2 huff ‘n’ puff, the high-pressure physical properties of typical tight oil samples are measured. Combining the typical reservoir parameters, the production characteristics of the tight oil reservoir developed by the CO2 huff ‘n’ puff are numerically studied on the basis of highly fitted experimental results. The results show that: (1) during the natural depletion stage, the oil production rate decreases rapidly and the oil recovery degree is low because of the decrease in oil displacement energy and the increase in fluid seepage resistance. (2) CO2 huff ‘n’ puff can improve the development effect of tight oil reservoirs by supplementing reservoir energy and improving oil mobility, but the development effect gradually worsens with increasing cycle number. (3) The earlier the CO2 injection timing is, the better the development effect of the tight reservoir is, but the less sufficient natural energy utilization is. When carrying out CO2 stimulation, full use should be made of the natural energy, and the appropriate injection timing should be determined by comprehensively considering the formation-saturation pressure difference and oil production rate. The research results are helpful for strengthening the understanding of the production characteristics of tight oil reservoirs developed by CO2 huff ‘n’ puff.
The Fourier transform infrared spectroscopy (FTIR) analysis for the clay mineralogy studies in a clastic reservoir
Authors: Jozanikohan Golnaz , Abarghooei Mohsen Nosrati 
Published: January 2022

AbstractThe complete characteristics knowledge of clay minerals is necessary in the evaluation studies of hydrocarbon reservoirs. Ten samples taken from two wells in a heterogeneous clastic gas reservoir formation in NE Iran were selected to conduct the transmission Fourier transform infrared spectroscopy (FTIR) tests for the clay mineralogy studies. The FTIR analysis showed that there were clear signs of clay minerals in all samples. The wavenumber region of the clay minerals in FTIR tests was detected to be 3621, 3432, 1034, and 515 cm−1 for illite, 3567, 3432, 1613, 1088, 990, 687, 651, and 515 cm−1 for magnesium-rich chlorite, 3700, 3621, 3432, 1034, 687, and 463 cm−1 for kaolinite, and 3567, 1088, 990, and 463 cm−1 for glauconite. After screening of samples by the FTIR method, the samples were then analyzed by powder X-ray diffraction (PXRD), wavelength dispersive X-ray fluorescence (WDXRF), and scanning electron microscopy (SEM). The PXRD and SEM result showed illite was by far the most common clay present. Kaolinite, magnesium-rich chlorite, and traces of smectite and the mixed-layer clays of both the illite–smectite and chlorite-smectite types were also recognized. The combination of PXRD and WDXRF results could quantify the clay abundances in the each well too. It was concluded that the FTIR analysis successfully could show the absorption bonds of all constituent clays. However, the infrared absorption spectra of mixed-layer clays overlapped those of the respective constituents of each mixed-layer minerals. This can be considered as the evidence of the usefulness of FTIR technique in the screening of the samples for the clay mineralogy studies.
Representation of positive semidefinite elements as sum of squares in 2-dimensional local rings
Authors: Fernando José F. 
Published: January 2022

AbstractA classical problem in real geometry concerns the representation of positive semidefinite elements of a ring A as sums of squares of elements of A. If A is an excellent ring of dimension $$\ge 3$$

≥
3

, it is already known that it contains positive semidefinite elements that cannot be represented as sums of squares in A. The one dimensional local case has been afforded by Scheiderer (mainly when its residue field is real closed). In this work we focus on the 2-dimensional case and determine (under some mild conditions) which local excellent henselian rings A of embedding dimension 3 have the property that every positive semidefinite element of A is a sum of squares of elements of A.
Cohomology of complements of toric arrangements associated with root systems
Authors: Bergvall Olof 
Published: January 2022

AbstractWe develop an algorithm for computing the cohomology of complements of toric arrangements. In the case a finite group $$\Gamma $$
Γ
is acting on the arrangement, the algorithm determines the cohomology groups as representations of $$\Gamma $$
Γ
. As an important application, we determine the cohomology groups of the complements of the toric arrangements associated with root systems of exceptional type as representations of the corresponding Weyl groups.
Influence of Gd3+ doping concentration on the properties of Na(Y,Gd)F4:Yb3+, Tm3+ upconverting nanoparticles and their long-term aging behavior
Authors: López de Guereñu Anna , Klier Dennis T. , Haubitz Toni , Kumke Michael U. 
Published: January 2022

AbstractWe present a systematic study on the properties of Na(Y,Gd)F4-based upconverting nanoparticles (UCNP) doped with 18% Yb3+, 2% Tm3+, and the influence of Gd3+ (10–50 mol% Gd3+). UCNP were synthesized via the solvothermal method and had a range of diameters within 13 and 50 nm. Structural and photophysical changes were monitored for the UCNP samples after a 24-month incubation period in dry phase and further redispersion. Structural characterization was performed by means of X-ray diffraction (XRD), transmission electron microscopy (TEM) as well as dynamic light scattering (DLS), and the upconversion luminescence (UCL) studies were executed at various temperatures (from 4 to 295 K) using time-resolved and steady-state spectroscopy. An increase in the hexagonal lattice phase with the increase of Gd3+ content was found, although the cubic phase was prevalent in most samples. The Tm3+-luminescence intensity as well as the Tm3+-luminescence decay times peaked at the Gd3+ concentration of 30 mol%. Although the general upconverting luminescence properties of the nanoparticles were preserved, the 24-month incubation period lead to irreversible agglomeration of the UCNP and changes in luminescence band ratios and lifetimes.
Vertically Divergent Responses of SOC Decomposition to Soil Moisture in a Changing Climate
Authors: Pallandt Marleen , Ahrens Bernhard , Koirala Sujan , Lange Holger , Reichstein Markus , Schrumpf Marion , Zaehle Sönke 
Published: January 2022

AbstractThe role of soil moisture for organic matter decomposition rates remains poorly understood and underrepresented in Earth System Models (ESMs). We apply the Dual Arrhenius Michaelis‐Menten (DAMM) model to a selection of ESM soil temperature and moisture outputs to investigate their effects on decomposition rates, at different soil depths, for a historical period and a future climate period. Our key finding is that the inclusion of soil moisture controls has diverging effects on both the speed and direction of projected decomposition rates (up to ±20%), compared to a temperature‐only approach. In the top soil, the majority of these changes is driven by substrate availability. In deeper soil layers, oxygen availability plays a relatively stronger role. Owing to these different moisture controls along the soil depth, our study highlights the need for depth‐resolved inclusion of soil moisture effects on decomposition rates within ESMs. This is particularly important for C‐rich soils in regions which may be subject to strong future warming and vertically opposing moisture changes, such as the peat soils at northern high latitudes.
Relationship between serum 25-hydroxyvitamin D and target organ damage in children with essential hypertension
Authors: Liu Yang , Shi Lin , Lin Yao , Zhang Mingming , Chen Fangfang , Li Aijie , Liu Yanyan 
Published: January 2022

AbstractResearchers have shown that 25-hydroxyvitamin D (25[OH] D), a kind of active vitamin D in the human body, plays a role in cardiovascular disease (CVD). Low serum 25(OH) D levels have been found to be associated with elevated blood pressure (BP) in adults. However, measurement of 25(OH) D in hypertensive children has not been documented. The aim of this study was to investigate the relationship between 25(OH) D and target organ damage (TOD) in children with essential hypertension. We recruited a total of 346 children with essential hypertension and analyzed the correlation between serum 25(OH) D and TOD. Serum 25(OH) D concentration was significantly lower in the TOD than in the no-TOD group (t = 2.416, P = 0.016), as well as significantly lower in the two-organ damage than in the single-organ damage group (t = 3.140, P = 0.002). Pearson’s correlation coefficient (PCC) indicated that serum 25(OH) D levels were negatively correlated with left ventricular mass index (LVMI; r = −0.110, P = 0.041) and albuminuria (r = −0.120, P = 0.026). Linear- regression analysis showed that 25(OH) D was a risk factor for left ventricular hypertrophy (LVH; β ± s.e. =−0.074 ± 0.036; 95% confidence interval [CI], − 0.145 to –0.003; P < 0.001) and renal damage (β ± s.e.= −0.018 ± 0.008; 95% CI, − 0.035 to –0.002; P = 0.004). In total, our data revealed that serum 25(OH) D was independently associated with hypertensive cardiac and renal damage, meaning that it was a risk factor for LVH and albuminuria in childhood hypertension.
Regulation of Src tumor activity by its N-terminal intrinsically disordered region
Authors: Aponte Emilie , Lafitte Marie , Sirvent Audrey , Simon Valérie , Barbery Maud , Fourgous Elise , Boublik Yvan , Maffei Mariano , Armand Florence , Hamelin Romain , Pannequin Julie , Fort Philippe , Pons Miquel , Roche Serge 
Published: January 2022

AbstractThe membrane-anchored Src tyrosine kinase is involved in numerous pathways and its deregulation is involved in human cancer. Our knowledge on Src regulation relies on crystallography, which revealed intramolecular interactions to control active Src conformations. However, Src contains a N-terminal intrinsically disordered unique domain (UD) whose function remains unclear. Using NMR, we reported that UD forms an intramolecular fuzzy complex involving a conserved region with lipid-binding capacity named Unique Lipid-Binding Region (ULBR), which could modulate Src membrane anchoring. Here we show that the ULBR is essential for Src’s oncogenic capacity. ULBR inactive mutations inhibited Src transforming activity in NIH3T3 cells and in human colon cancer cells. It also reduced Src-induced tumor development in nude mice. An intact ULBR was required for MAPK signaling without affecting Src kinase activity nor sub-cellular localization. Phospho-proteomic analyses revealed that, while not impacting on the global tyrosine phospho-proteome in colon cancer cells, this region modulates phosphorylation of specific membrane-localized tyrosine kinases needed for Src oncogenic signaling, including EPHA2 and Fyn. Collectively, this study reveals an important role of this intrinsically disordered region in malignant cell transformation and suggests a novel layer of Src regulation by this unique region via membrane substrate phosphorylation.