bluuebunny/crossref_metadata_2025_split huggingface dataset:
Factors Related to the Utilization of Health Services in the Outstanding Unit in the Regional General Hospital of Buton North Regency
Authors: Syafruddin Syafruddin , Saafi La Ode , Azizi Jayadipraja Erwin , Supodo Timbul , Sunarsih Sunarsih 
Published: September 2022

Introduction: Service utilization is the use of service facilities provided either in the form of outpatient care, inpatient care, home visits by health workers or other forms of utilization of these services based on the availability and continuity of services, public acceptance and fairness, easily accessible by the community, affordable, and quality.
Method: This research is quantitative research with a cross-sectional study design. The population in this study amounted to 352 respondents. The sample size is 187 respondents.
Result: The average significance of respondents to four variables, the variable of health service availability is 0.000, the variable of access to health services is 0.002, the variable is cost affordability, the value is 0.000, the variable of Service Acceptance is 0.000. Of the four variables have a relationship with the utilization of outpatient health services.
Conclusion: The average the four variables with the level of trust that exists based on the significance number has factors related to the utilization of health services which are quite closely related to the condition and situation of hospital services when patients make visits.
IMPLEMENTASI KESEJAHTERAAN SOSIAL BAGI PENYANDANG MASALAH LANJUT USIA PERSPEKTIF MAQASHID SYARI’AH DI KOTA MALANG
Authors: F.T. Mu’alim  , M. Djakfar  , A.S. Supriyanto  
Published: September 2022

Introduction: Malang City is committed to be an Elderly Friendly City. A number of policy innovations and pro social welfare programs for the elderly have been implemented. But in fact the aid is still in the form of material such as money and basic necessities. The varied conditions of the elderly require the fulfillment of non-material needs such as health, moral support and religious development. To understand the implementation of welfare for people with elderly problems in Malang City, the maqashid shari'ah perspective is used so that the factual needs of the elderly can be understood more comprehensively.
Methods: The research method used is a qualitative paradigm with the type of case study research. The data analysis technique uses data reduction, presentation, conclusion and verification.
Results and Conclusion: The results of the study indicate that the social welfare program is tentative and continuous. The tentative program is material, while the continuous program is non-material. The implementation of the program is carried out by the Social Service in collaboration with TKSK, PSM and local village officials. The stages in program implementation are receiving reports, visitation by providing an analysis of environmental potential and ending with evacuation if needed. Maqashid shari'ah corrects that social welfare programs have implications but have not maximized maintaining religion, soul, mind, lineage and property, especially during the Covid-19 pandemic. The implication for the unproductive elderly comes from non-material assistance such as assistance and love. Meanwhile, material assistance has implications for productive elderly people for business empowerment.
Key words: Implementation of Social Welfare, Elderly Problems, Maqashid Syari'ah.
Tussen dwang en drang
Authors: Cleton Laura 
Published: September 2022

Between coercion and compulsion. How return counsellors realize the ‘voluntary return’ of undocumented migrants
European governments widely celebrate and extensively fund ‘voluntary return’ programmes and assume that return counsellors play a key role for their implementation. At the same time, these programmes rely on the cooperation of illegalized immigrants involved, whereas the latter are often reluctant to do so. In this article, the author therefore questions how much and what kind of agency individual counsellors exercise to overcome this fundamental conflict of interest. Based on research conducted in the Netherlands, Belgium and Austria, the author conceptualizes counsellors’ work as ‘aspirations management’ that mediates the desires, hopes and interest of precarious status migrants with the goals of governments seeking to return them. The author analytically distinguishes three fundamentally different counselling strategies: facilitating migrants’ existing return aspirations, obtaining their compliance without inducing aspirations, and/or inducing aspirations for return. The author ends this article with critical reflections on the legitimacy and ethics of such aspirations management.
Mechanical power measurement during mechanical ventilation of SARS-CoV-2 critically ill patients. A cohort study
Authors: Rivera Palacios Alejandro , España Johana Andrea , Gómez González José Fernando , Salazar Gutierrez Guillermo , Ávila Reyes Diana , Moreno Paula , Lara Martinez Angie Vanessa , Aguirre-Flórez Mateo , Giraldo-Diaconeasa Adrian 
Published: September 2022

Introduction: The ventilator-induced lung injury (VILI) depends on the amount of energy per minute transferred by the ventilator to the lung measured in Joules, which is called mechanical power. Mechanical power is a development variable probably associated with outcomes in ventilated patients.
Objective: To describe the value of mechanical power in patients with SARS-CoV-2 infection and ventilated for other causes and its relationship between days of mechanical ventilation, length of stay in the intensive care unit (ICU), and mortality.
Methods: A multicenter, analytical, observational cohort study was conducted in patients with SARS-CoV-2 infection who required invasive mechanical ventilation and patients ventilated for other causes for more than 24 hours.
Results: The cohort included 91 patients on mechanical ventilation in three tertiary care centers in the city of Pereira, Colombia. The average value of the mechanical power found was 22.7 ± 1 Joules/min. In the subgroup of patients with SARS-CoV-2 infection, the value of mechanical power was higher 26.8 ± 9 than in the subgroup of patients without a diagnosis of SARS-CoV-2 infection 18.2 ± 1 (p <0.001).
Conclusion: Mechanical power is an important variable to consider during the monitoring of mechanical ventilation. This study found an average value of mechanical power of 22.7 ± 1 Joules/min, being higher in patients with SARS-CoV-2 infection related to longer days of mechanical ventilation and a longer stay in the ICU.
On Certain Subclasses of Meromorphic Functions with Positive Coefficients involving Generalized Liu-Srivastava Operator
Authors: Gatti N B , Magesh N , Jothibasu J , Murthy S 
Published: September 2022

In this paper, making use of the generalized Liu-Srivastava operator, we introduce and study a new subclass ΣP (	α;β; ; λ; k) of meromorphically univalent functions. We obtain the coefficient estimates, distortion bounds, extreme points, radii of meromorphically starlikeness and convexity for functions in the class ΣP (α;β;γ; λ, k): Furthermore we obtain the partial sums for the same.
Analisis Rasio Keuangan Pada Perusahaan Daerah Air Minum Kabupaten Polewali Mandar
Authors: Maskur Hasan  , D’Ornay Anastasya , R Rohman 
Published: September 2022

Penelitian ini bertujuan untuk mengetahui kinerja keuangan Perusahaan Daerah Air Minum Wai Tipalayo Kabupaten Polewali Mandar. Teknik pengumpulan data yang dipergunakan adalah wawancara dan dokumentasi. Teknik analisis data dilakukan berdasarkan Keputusan Mendagri No. 47 Tahun 1999 tentang Pedoman Analisis Kinerja Perusahaan Daerah Air Minum (PDAM). Data yang digunakan dalam penelitian ini meliputi data aspek keuangan berupa Laporan Neraca dan Laporan Laba Rugi, dimana aspek keuangan ini memiliki 10 rasio dan 2 rasio perbaikan indikator. Berdasarkan Kepmendagri No. 47 Tahun 1999 tentang Penilaian Kinerja Perusahaan Daerah Air Minum dari aspek keuangan pada tahun 2014 diperoleh nilai 21 dengan kategori cukup baik, pada tahun 2015 diperoleh nilai 24,75 dengan kategri cukup baik, pada tahun 2016 diperoleh nilai 27,75 dengan kategori baik dan pada tahun 2017 diperoleh nilai 21 dengan kategori cukup baik
Diabetes and Daytime Sleeping: Systematic Review
Authors: Alanazi Yasser Wadi 
Published: September 2022

Background: The relationship between sleep disturbance and diabetes is dual-sided. Chronic sleep disturbance increases the chance of developing insulin resistance, while diabetes reduces sleep quality.
Objective: To address the aspects of insufficient sleep, diabetes mellitus, and their mutual interactions and interlinkages. The main objectives is to address the role and effect of diabetes on sleep. Methods: systematic review. A systematic search was done in PubMed, MEDLINE through Clarivate, Web of Science through Clarivate, and EBSCO. Studies retrieved were managed in Rayyan–Intelligent systematic reviews website for duplicate removal and screening.
Results: DM is one of the most widespread illnesses in the world. In addition to directly disrupting sleep due to nocturia, polyuria, diabetic neuropathy, and neuropathy pain, DM has also been linked to a number of chronic illnesses, including obstructive sleep apnea, cardiovascular issues, hypertension, cerebrovascular accidents, and depression, all of which can lower quality of life and negatively affect sleep. The patient may not bring the sleep issues during their visit to healthcare providers, with acute issues taking precedence during their visit.
Conclusion: DM causes night sleep disturbances which eventually lead to daytime sleeping. Sleep education should be considered an essential part in the diabetic management armamentarium.
Notes on a 20‐Year Partnership: Challenging Architecture and Each Other
Authors: Lyall John 
Published: September 2022

AbstractAlsop's first business partner of two decades, John Lyall describes their formative years as students at the Architectural Association in London, the influence of various members of Archigram, and sharing a house in Southeast London's not‐so‐salubrious Ladywell district. He recounts a world of music gigs, designing events and parties, and the offices they worked for as young architects before forming their fledgling practice in the 1970s.
A Second Course in Architecture
Authors: Hardingham Samantha 
Published: September 2022

AbstractThe milieu in which Alsop was educated, mixed and worked was crucial to the original architect he became. Samantha Hardingham describes those heady days, particularly the influence of the Architectural Association in the early 1970s and its rich menagerie of denizens of the period. She focuses on a critical and enigmatic mentor, Cedric Price, for whom Alsop worked and asserted as a profound influence on his design thinking.
Willie Wonky and the Arty‐tecture Factory
Authors: Coates Nigel 
Published: September 2022

AbstractNigel Coates lets us into the creative world of messy play that Alsop favoured as a way to teach architecture – the live‐in, eat‐in, drink‐in workshop. Such practices disrupted assumed modes of operation for architects and provoked new spatial and formal opportunities. His workshops, studios and lectures were a challenging mixture of kindergarten, party and questioning observations, all conducted with critical and colourful exuberance.
Yes, This Is Architecture
Authors: Thomas Neil 
Published: September 2022

AbstractStructural engineer Neil Thomas describes some of the memorable encounters and collaborations with Alsop, particularly the Cardiff Bay Visitor Centre that Alsop maintained was inspired by his disposable cigarette lighter. A creative relationship maintained over a timeline that spanned nearly 30 years, Thomas conveys their way of working together that was fuelled by a deep desire to dare to dream met with breathtaking and credible design solutions.
Building Knowledge: Reflections on Peckham Library
Authors: Aquilina Thomas 
Published: September 2022

AbstractDescribing the making and thinking behind a film shot at Alsop & Störmer's Stirling Prize‐winning Peckham Library, Thomas Aquilina portrays how the building and its public piazza has democratised a previously neglected patch of South London, providing not just reading materials but much needed community functions for a diverse part of the capital. Much of the building's formal dexterity happens above its users’ heads, deploying the familiar Alsop trope of touching the ground lightly.
Mitochondria‐Driven Dye Rearrangement That Enables Spatiotemporally Controlled Photomedicine
Authors: Luo Pei , Zhang Yongkang , Zhang Junqing , Zhang Hao , Yang Chun , Li Changhua 
Published: September 2022

AbstractReversibly controlling the dye arrangements in living systems has great potential to realize spatiotemporally controlled photomedicine. However, tuning or even maintaining a certain arrangement of dyes in a complex living environments is extremely challenging due to the interference of the various biological species. Herein, a conceptual supramolecular strategy to engineer a switchable photosensitizer (PS) via mitochondria‐mediated dynamic interconversion between monomer and J‐aggregation, enabling specific activation of the mitochondria‐targeting photodynamic therapy (PDT) and hibernation after mitochondria damage is presented. The presented mitochondria‐mediated “activate‐then‐hibernate” PS design enables a fascinating spatiotemporally controlled PDT in which spatially controlled mitochondrial‐targeting enhances therapeutic efficacy and temporally controlled activation‐then‐hibernation averts off‐target damage during PDT and tissue damage after clinical treatment, thus offering significant potential for biological research and clinical needs.
Transparent Lead‐Free Ferroelectric (K, Na)NbO3 Single Crystal with Giant Second Harmonic Generation and Wide Mid‐Infrared Transparency Window
Authors: Yin Fangyi , Liu Lei , Zhu Menghua , Lv Junai , Guan Xin , Zhang Jian , Lin Na , Fu Xiuwei , Jia Zhitai , Tao Xutang 
Published: September 2022

AbstractEnvironment‐friendly lead‐free potassium‐sodium niobate (KNN) has become one of the most extensively investigated ferroelectrics in the past decade, while high transparency KNN single crystal has never been realized yet. Here, a transparent KNN single crystal is successfully grown by the top seeded solution growth method. The KNN crystal possesses a very wide transmittance range of 0.37–8 µm, completely covering the important mid‐infrared atmospheric transparent window (3–5 µm). Noticeably, the KNN crystal exhibits the largest second‐harmonic generation efficiency (7.6× that of potassium‐titanyl phosphate (KTP)) with type‐I phase matchability under the fundamental wavelength of 1064 nm among all of the studied mid‐infrared oxide nonlinear optical crystals reported so far. This work demonstrates a novel mid‐infrared nonlinear optical oxide crystal with a giant second‐harmonic generation and wide transparency range, providing a new idea for the exploration of nonlinear oxide crystals.
Cascade Cyclopolymerization of 5‐Ethynyl‐1,8‐Nonadiyne Derivatives to Synthesize Low Band Gap Conjugated Polyacetylenes Containing a Fused Bicyclic Structure
Authors: Ryu Hanseul , Sung Jong‐Chan , Kim Gangme , Xu Yan , Grubbs Robert H. , Choi Tae‐Lim 
Published: September 2022

AbstractCyclopolymerization is a powerful method for synthesizing polyacetylenes containing four‐ to seven‐membered rings. However, the structure of the repeat unit only consists of mono‐cycloalkene due to the single cyclization of diyne monomers. Herein, we demonstrate a novel cascade cyclopolymerization to synthesize polyacetylenes containing fused bicyclic rings from triyne monomers containing bulky dendrons via sequential cascade ring‐closing metathesis. These dendrons provided solubility and stability to the rigid bicyclic polyacetylene backbone. In addition, we controlled the regioselectivity of the catalyst approach by altering its structure and synthesized polymers containing fused bicyclo[4,3,0] or [4,4,0] rings with high molecular weights of up to 120 kg mol−1. Interestingly, the resulting polymers showed narrower band gaps (down to 1.6 eV) than polymers with mono‐cycloalkene repeat units due to the planarization of the conjugated segment resulting from the fused bicyclic structure.
Phase Transitions in Chemically Fueled, Multiphase Complex Coacervate Droplets
Authors: Donau Carsten , Späth Fabian , Stasi Michele , Bergmann Alexander M. , Boekhoven Job 
Published: September 2022

AbstractMembraneless organelles are droplets in the cytosol that are regulated by chemical reactions. Increasing studies suggest that they are internally organized. However, how these subcompartments are regulated remains elusive. Herein, we describe a complex coacervate‐based model composed of two polyanions and a short peptide. With a chemical reaction cycle, we control the affinity of the peptide for the polyelectrolytes leading to distinct regimes inside the phase diagram. We study the transitions from one regime to another and identify new transitions that can only occur under kinetic control. Finally, we show that the chemical reaction cycle controls the liquidity of the droplets offering insights into how active processes inside cells play an important role in tuning the liquid state of membraneless organelles. Our work demonstrates that not only thermodynamic properties but also kinetics should be considered in the organization of multiple phases in droplets.
Ultrastable Anti‐Acid “Shield” in Layered Silver Coordination Polymers
Authors: Sun Peipei , Xie Mo , Zhang Lin‐Mei , Liu Jia‐Xing , Wu Jin , Li Dong‐Sheng , Yuan Shang‐Fu , Wu Tao , Li Dan 
Published: September 2022

AbstractSurface passivation technology provides noble‐metal materials with limited chemical stability, especially under highly acidic condition. To design effective strategy to enhance stability of noble‐metal particles, an understanding of their surface anticorrosion mechanism at the atomic level is desirable by using two‐dimensional (2D) noble‐metal coordination polymer (CP) as an ideal model for their interfacial region. With the protection of 2‐thiobenzimidazole (TBI), we isolated two Ag‐based 2D CPs, {Ag14(TBI)12X2}n (S−X, where S denotes sheet and X=Cl or Br). These compounds exhibited excellent chemical stability upon immersion in various common solvents, boiling water, boiling ethanol, 10 % hydrogen peroxide, concentrated acid (12 M HCl), and concentrated alkali (19 M NaOH). Systematic characterization and DFT analyses demonstrate that the superior stability of S−X was attributed to the hydrophobic organic shell and dynamic proton buffer layer acting as a double protective “shield”.
Molecular Self‐Assembly Regulated Dopant‐Free Hole Transport Materials for Efficient and Stablen‐i‐pPerovskite Solar Cells and Scalable Modules
Authors: Cheng Qinrong , Chen Haiyang , Yang Fu , Chen Ziyuan , Chen Weijie , Yang Heyi , Shen Yunxiu , Ou Xue‐Mei , Wu Yeyong , Li Yaowen , Li Yongfang 
Published: September 2022

AbstractDopant‐free organic hole transport materials (HTMs) remain highly desirable for stable and efficientn‐i‐pperovskite solar cells (pero‐SCs) but rarely succeed. Here, we propose a molecular assembly strategy to overcome the limited optoelectronic properties of organic HTMs by precisely designing a linear organic small molecule BDT‐DPA‐F from the atomic to the molecular levels. BDT‐DPA‐F can assemble into a fibril network, showing an obviously improved hole mobility and decreased energy disorder. The resultant pero‐SCs showed a promising efficiency of 23.12 % (certified 22.48 %), which is the highest certified value of pero‐SCs with dopant‐free HTMs, to date. These devices also showed a weak‐dependence of efficiency on size, enabling a state‐of‐the‐art efficiency of 22.50 % for 1‐cm2device and 20.17 % for 15.64‐cm2module. For the first time, the pero‐SCs based on dopant‐free HTMs realized ultralong stabilities withT80lifetimes over 1200 h under operation or thermal aging at 85 °C.
Diterpene Biosynthesis from Geranylgeranyl Diphosphate Analogues with Changed Reactivities Expands Skeletal Diversity
Authors: Li Heng , Dickschat Jeroen S. 
Published: September 2022

AbstractTwo analogues of the diterpene precursor geranylgeranyl diphosphate with shifted double bonds, named iso‐GGPP I and iso‐GGPP II, were enzymatically converted with twelve diterpene synthases from bacteria, fungi and protists. The changed reactivity in the substrate analogues resulted in the formation of 28 new diterpenes, many of which exhibit novel skeletons.
Synthesis, Structure, and Bonding of a XeIV Transition‐Metal Coordination Complex, F3XeFb‐ ‐ ‐WOF4
Authors: Bortolus Mark R. , Mercier Hélène P. A. , Schrobilgen Gary J. 
Published: September 2022

AbstractThe coordination complex, F3XeFb‐ ‐ ‐WOF4, was synthesized in CFCl3 solvent by reaction of the weak fluoride‐ion donor and strong oxidative fluorinating agent, XeF4, with the moderate‐strength fluoride‐ion acceptor, WOF4. The compound is the only transition‐metal coordination complex of XeIV and was characterized at low temperatures by single‐crystal X‐ray diffraction and Raman spectroscopy. Xenon tetrafluoride and WOF4 coordinate trans to the W=O bond through a W‐ ‐ ‐Fb bond. The XeF3 moiety of F3XeFb‐ ‐ ‐WOF4 acquires a degree of [XeF3]+ character upon coordination that is reflected by its Xe−F stretching frequencies which are intermediate with respect to those of XeF4 and [XeF3]+. Calculations show W‐ ‐ ‐Fb is predominantly an electrostatic, σ‐hole bond with a significant orbital contribution that accounts for the bent Xe−Fb‐ ‐ ‐W angle. The calculations show F3XeFb‐ ‐ ‐MOF4 (M=Cr, Mo) are less stable than their W analogue, consistent with failed attempts to synthesize F3XeFb‐ ‐ ‐MoOF4.
DNA‐Based Biosensors for Imaging of Subcellular Enzymatic Activity
Authors: Zhao Hengzhi , Yu Fangzhi , Yu Mingming , Li Lele 
Published: September 2022

AbstractAs one kind of the most important biomolecules, enzymes participate in nearly all biochemical reactions. Dysregulation of enzymes’ spatial distributions and activities is often associated with many diseases. In situ imaging of enzymatic activity at the subcellular level is extremely challenging due to the lack of spatiotemporal precision of sensor probes. In this concept, we introduce several recent works in which DNA‐based biosensors with controllable localization ability were constructed for imaging of specific enzymatic activities and dynamics in a subcellular compartment of interest. These DNA‐based biosensors are classified into two types, in which DNA molecules serve as a subcellular targeting scaffold and an enzyme responsive sensing unit, respectively. We highlight the working principles of these DNA‐based biosensors and briefly introduce their biological applications. Finally, we discuss current limitations and future opportunities in this emerging field.