bluuebunny/crossref_metadata_2025_split huggingface dataset:
Replicating a Therapeutic Art Group Protocol for Parents of Youth With Chronic Pain
Authors: Wallace Dustin P. , Curtin Linda , Pielech Melissa , Hoffart Cara M. 
Published: August 2022

Objective: Interventions for parents are important during intensive interdisciplinary pain treatment (IIPT) for youth. Therapeutic art reinforces parent strengths and promotes healthy coping during their child’s treatment. This study measured the feasibility of implementing a published, parent-only group-based therapeutic art intervention in an IIPT program, delivered by a Certified Child Life Specialist (CCLS) with training in therapeutic art. Method: While their child participated in IIPT, forty-two parents participated in at least one therapeutic art group. Content rotated through four modules designed to promote reflection on interpersonal relationships, cultivate support, identify values, acknowledge personal struggles and barriers, and increase artistic self-expression (Pielech et. al., 2013). Following each group, parents completed measures of perceived satisfaction and helpfulness as well as open-ended questions for qualitative analysis. The mixed method design was used to provide depth to the understanding of these parents’ experiences. Results: Supporting feasibility, the full intervention was replicated in a different setting with different providers. Parents attended 69% of sessions, reported little difficulty attending, and reported a high degree of satisfaction, helpfulness, and support. Following each group, parents completed measures of perceived satisfaction and helpfulness as well as open-ended questions. Conclusion: A mixed method design was used to provide depth to the understanding of these parents’ experiences. Disclosure Statement: No potential conflict of interest was reported by the author(s). Funding Statement: No funding sources were provided by the author(s).
Evaluasi Keberhasilan Penerapan Project Information Management System (PIMS) Pada PT. Rifansi Dwi Putra Dengan Menggunakan Model Hot-Fit
Authors: Sinaga Mutiara , Simbolon Verdy , Yunis Roni , Tan Hita 
Published: August 2022

PIMS (Project Information Management System) adalah salah satu aplikasi terintegrasi berbasis web yang digunakan oleh tim proyek untuk menyelesaikan kegiatan - kegiatan manajemen proyek dalam proses bisnisnya secara online menggunakan web browser. Penelitian ini dilakukan dengan mengadopsi model HOT-Fit, dengan mengambil variabel kualitas sistem, kualitas informasi, kualitas layanan, penggunaan sistem, kepuasan pengguna, struktur organisasi, lingkungan organisasi dan manfaat bersih. Tujuan dari penelitian ini adalah untuk mengukur tingkat kesuksesan penerapan sistem informasi PIMS pada PT. Rifansi Dwi Putra dengan karyawan pengguna PIMS sebagai sampel. Teknik pengambilan sampel yang digunakan adalah nonprobability sampling dan menggunakan metode sampling jenuh. .Data dalam penelitian ini didapatkan dari 163 kuesioner yang kembali serta layak untuk diolah melalui penyebaran kuesioner kepada ??? 180 responden. Data diolah dengan menggunakan tools SPSS19 sebagai alat pengujian. Dari 25 hipotesis yang diajukan terdapat 18 hipotesis yang diterima, 12 diantaranya berpengaruh positif dan signifikan, 6 diantaranya uji mediasi yang terbukti memediasi hubungan antara variabel independen dengan dependen, serta ditolaknya 7 hipotesis yang terbukti tidak berpengaruh positif dan signifikan dan 4 hipotesis uji mediasi yang terbukti tidak memediasi hubungan antara variabel independen dengan dependen.
Optimalisasi Pemberdayaan Masyarakat di Tengah Pandemi Covid-19 melalui Kegiatan Pengenalan Go-Digital bagi UMKM di Kelurahan Ujung Sabbang Kecamatan Ujung Kota Parepare
Authors: Fatimah Fatimah , Arfianty Arfianty , Nurwani Nurwani , Tarawiru Yasri , Harun Hernianti 
Published: August 2022

Kegiatan Pengabdian Pada Masyarakat dilakukan untuk memberi bimbingan dalam mengatasi dampak tersebut melalui penggunaan dan pengelolaan media digital yang sesuai. Dengan menggunakan dan mengelola media digital, diharapkan para pelaku usaha dapat menentukan jenis media digital yang tepat untuk produk yang dipasarkan, meningkatkan awareness serta ketertarikan masyarakat mengenai produk. Metode yang digunakan adalah pelatihan secara langsung dengan pemilik usaha UMKM. Materi kegiatan berupa ini adalah strategi penggunaan dan pengelolaan media digital, optimalisasi digital untuk meningkatkan kemampuan pembuatan konten yang menarik, promosi serta sebagai media alternatif bagi pelaku usaha bidang Perdagangan. Media digital yang digunakan antara lain Instagram, Facebook WhatsApp, dan platform lainnya. Hasil kegiatan menunjukkan bahwa pelatihan dan bimbingan yang diberikan memberikan dampak positif bagi para pelaku usaha dengan adanya peningkatan pengetahuan tentang media digital, peningkatan pengetahuan berbagai media yang dapat digunakan dan adanya peningkatan keterampilan dalam penggunaan dan pengelolaan media digital. Rekomendasi yang dapat disampaikan adalah adanya keberlanjutan program pembinaan bagi para pelaku usaha sehingga dapat menerapkan dan mengelola media digital secara optimal.
América Latina: regímenes de bienestar en transición durante los años noventa
Authors: Barba Solano Carlos 
Published: August 2022

Este artigo analisa o andamento do processo de ajuste e de reforma social impulsionado pelas instituições financeiras internacionais e por numerosos governos na América Latina, especialmente nos anos 90. Apresenta as características do paradigma de bem-estar que chegou a ser hegemônico em escala regional e discute as conseqüências de aplicarem-se as mesmas receitas a realidades nacionais muito diversas. Para analisar a heterogeneidade regional, recorre ao conceito de “regime de bem-estar” e emprega uma tipologia que permite mostrar os efeitos diferenciais dos processos aqui abordados. O artigo aponta a necessidade do uso de um paradigma de bem-estar distinto para enfrentar os profundos desafios sociais postos aos países da região, ou seja, assinala a urgência de uma reforma da reforma. PALAVRAS-CHAVE: regimes de bem-estar, pobreza, políticas sociais, transição social, América Latina. LATIN AMERICA: welfare system in transition during the nineties Carlos Barba Solano This paper analyzes the course of the adjustment and social reform processes impelled by international financial institutions and numerous governments in Latin America, especially in the nineties. It presents the characteristics of the welfare paradigm that achieved hegemony in a regional scale and discusses the consequences of applying the same recipes to very diverse national realities. To analyze the regional heterogeneity, it falls back upon the concept of “welfare system” and uses a typology that shows the differential effects of the processes approached here. The paper points the need of the use of a different welfare paradigm to face the deep social challenges put to the countries of the area, in other words, it marks the urgency of a reform of the reform. KEYWORDS: welfare system, poverty, social policies, social transition, Latin America. AMÉRIQUE LATINE: les régimes de bienêtre en phase de transition au cours des années quatre-vingt-dix Carlos Barba Solano Cet article analyse la progression du processus d’ajustement et de réforme sociale provoquée par les institutions financières internationales et par de nombreux gouvernements en Amérique Latine, tout spécialement au cours des années 90. Les caractéristiques du paradigme de bien-être dont le caractère hégémonique a atteint une échelle régionale y sont présentées et les conséquences dues au fait d’appliquer les mêmes formules à des réalités nationales très diverses y sont discutées. Afin d’analyser l’hétérogénéité régionale, on a recours au concept de “régime de bien-être” et on utilise une typologie qui permet de montrer les effets différentiels des processus qui ont été abordés. Dans cet article le besoin d’utiliser un paradigme de bien-être différent pour affronter les profonds défis sociaux auxquels sont confrontés les pays de la région est mis en évidence, c’est-à-dire qu’on y montre l’urgence d’une réforme de la réforme. MOTS-CLÉS: régimes de bien-être, pauvreté, politiques sociales, transition sociale, Amérique Latine. Publicação Online do Caderno CRH: http://www.cadernocrh.ufba.br
A QUESTÃO DA REPRESENTAÇÃO POLÍTICA NA PRIMEIRA REPÚBLICA
Authors: Buarque de Hollanda Cristina 
Published: August 2022

O artigo trata o tema da representação política na Primeira República brasileira (1889-1930) a partir de três importantes matrizes de reflexão sobre a questão: o liberalismo, o positivismo e o realismo. Busca-se rejeitar a narrativa usual das primeiras décadas republicanas, baseada unicamente no diagnóstico de corrupção política, e iluminar outras faces importantes do cenário político da época. A despeito das diferenças significativas entre os modelos interpretativos em evidência, que constituem o cerne do artigo, eles convergem na expectativa de protagonismo do Estado na tarefa de unificação e criação do povo. THE QUESTION OF POLITICAL REPRESENTATION IN THE FIRST BRAZILIAN REPUBLIC Cristina Buarque de Hollanda The paper treats the theme of political representation in the First Brazilian Republic (1889-1930) starting from three important reflection matrixes on the subject: the liberalism, the positivism and the realism. One aims to reject the usual narrative of the first republican decades, based only on the diagnosis of political corruption, and to illuminate other important faces of the political scenery at the time. In spite of significant differences among the interpretative models in evidence, that constitute the core of this paper, they converge in the expectation of protagonism of the State in the creation of the people and unification task. KEYWORDS: First Republic, political representation, liberalism, positivism, realism. LA REPRÉSENTATION POLITIQUE PENDANT LA PREMIÈRE RÉPUBLIQUE BRÉSILIENNE Cristina Buarque de Hollanda Cet article aborde le thème de la représentation politique, au cours de la Première République brésilienne (1889-1930), à partir de trois perspectives importantes de réflexion : le libéralisme, le positivisme et le réalisme. On essaie de ne pas prendre en considération la narrative habituelle des premières décennies républicaines, basée uniquement sur le diagnostic de la corruption politique, et de montrer d’autres aspects importants du scénario politique de l’époque. En dépit des différences significatives entre les modèles interprétatifs mis en évidence, qui constituent le noyau de cet article, il existe une convergence qui va dans le sens d’une attente, celle de voir l’État devenir le protagoniste de l’unification et de la formation du peuple. MOTS-CLÉS: Première République, représentation politique, libéralisme, positivisme, réalisme. Publicação Online do Caderno CRH: http://www.cadernocrh.ufba.br
Discordance Between Oncology Clinician–Perceived and Radiologist-Intended Meaning of the Postradiotherapy Positron Emission Tomography/Computed Tomography Freeform Report for Head and Neck Cancer
Authors: Patel Zachary , Schroeder Jennifer A. , Bunch Paul M. , Evans Joni K. , Steber Cole R. , Johnson Adam G. , Farris Joshua C. , Hughes Ryan T. 
Published: August 2022

ImportanceAssessment of response after radiotherapy (RT) using 18F–fluorodeoxyglucose positron emission tomography (PET) with computed tomography (CT) is routine in managing head and neck squamous cell carcinoma (HNSCC). Freeform reporting may contribute to a clinician’s misunderstanding of the nuclear medicine (NM) physician’s image interpretation, with important clinical implications.ObjectiveTo assess clinician-perceived freeform report meaning and discordance with NM interpretation using the modified Deauville score (MDS).Design, Setting, and ParticipantsIn this retrospective cohort study that was conducted at an academic referral center and National Cancer Institute–designated Comprehensive Cancer Center and included patients with HNSCC treated with RT between January 2014 and December 2019 with a posttreatment PET/CT and 1 year or longer of follow-up, 4 masked clinicians independently reviewed freeform PET/CT reports and assigned perceived MDS responses. Interrater reliability was determined. Clinician consensus–perceived MDS was then compared with the criterion standard NM MDS response derived from image review. Data analysis was conducted between December 2021 and February 2022.ExposuresPatients were treated with RT in either the definitive or adjuvant setting, with or without concurrent chemotherapy. They then underwent posttreatment PET/CT response assessment.Main Outcomes and MeasuresClinician-perceived (based on the freeform PET/CT report) and NM-defined response categories were assigned according to MDS. Clinical outcomes included locoregional control, progression-free survival, and overall survival.ResultsA total of 171 patients were included (45 women [26.3%]; median [IQR] age, 61 [54-65] years), with 149 (87%) with stage III to IV disease. Of these patients, 52 (30%) received postoperative RT and 153 (89%) received concurrent chemotherapy. Interrater reliability was moderate (κ = 0.68) among oncology clinicians and minimal (κ = 0.36) between clinician consensus and NM. Exact agreement between clinician consensus and the NM was 64%. The NM-rated MDS was significantly associated with locoregional control, progression-free survival, and overall survival.Conclusions and RelevanceThe results of this cohort study suggest that considerable variation in perceived meaning exists among oncology clinicians reading freeform HNSCC post-RT PET/CT reports, with only minimal agreement between MDS derived from clinician perception and NM image interpretation. The NM use of a standardized reporting system, such as MDS, may improve clinician-NM communication and increase the value of HNSCC post-RT PET/CT reports.
Effect of employers' concerns about cancer countermeasures on the implementation of cancer screening and support for balancing cancer treatment and work in small and medium-sized Japanese enterprises
Authors: Minamitani Masanari , Tatemichi Masayuki , Mukai Tomoya , Katano Atsuto , Nakagawa Keiichi 
Published: August 2022

Abstract

Objective
Japan has recently implemented screening and support to balance cancer treatment and work. The present study evaluated whether the interest of employers in small and medium-sized enterprises (SMEs) affects cancer control in the workplace.

Methods
Cancer preparedness at work was examined by a Japanese life insurance company contracting 370 000 SMEs. The analysis targeted SMEs hiring ≤50 employees whose employer was aged ≥40 years. The endpoints were performing one or more screening for stomach, colon, or lung cancer recommended for both sexes in Japan and implementing three or more supportive measures from the nine systems listed in a questionnaire. Logistic regression analysis was performed to predict these endpoints using other factors.

Results
The survey was completed from January 5 to 28, 2022 and included 5268 eligible companies. Around half were small enterprises with up to five employees. Screenings were performed for stomach (32%), colorectal (27%), and lung (26%) cancers. Sick leave (36%) was the most common support for balancing cancer treatment and work. Logistic regression analysis revealed that employer's concern was a significant predictor of screening (odds ratio [OR] = 3.59, P &lt; .001) and support (OR = 2.55, P &lt; .01) compared with “not concerned at all,” along with industry type, annual sales, experience of employees with cancer, and employer's participation in screening.

Conclusion
Our findings suggested that employers' interest was a powerful predictor of implementing cancer control in SMEs. Educational intervention targeted toward the employer could play a critical role in improving SMEs.
Effective Hydrogenation Strategies to Boost Efficiency over 20% for Crystalline Silicon Solar Cell with Al2O3/Cu2O Passivating Contact
Authors: Li Le , Ying Lei , Lin Yinyue , Li Xiaodong , Zhou Xi , Du Guanlin , Gao Yi , Liu Wenzhu , Lu Linfeng , Wang Jilei , Yang Liyou , Zhang Shan‐Ting , Li Dongdong 
Published: August 2022

AbstractPassivation interlayers such as Al2O3 are required to improve the hole selectivity of dopant‐free passivating contact based on transition metal oxides. For the interlayer to provide low surface recombination as in conventional silicon heterojunctions (SHJs) or tunnel oxide passivated contact (TOPCon) technologies, “hydrogenation” strategies to effectively introduce hydrogen in passivation interlayers while being compatible with transition metal oxides (TMOs) are urgently sought after. In this work, an easy‐to‐implement strategy to successfully incorporate extra hydrogen in the Al2O3 passivation layer is developed. The chemical and field‐effect passivation mechanisms of the extra hydrogen are revealed via comprehensive experimental analyses and density functional theory calculations. By implementing H‐Al2O3 with Cu2O as the hole‐selective rear contact in p‐type crystalline silicon (c‐Si) solar cells, a remarkable efficiency of 20.35% is achieved (fill factor of 84.76%). The study highlights a promising approach to improve the passivation quality of dielectric interlayers and boost the performance of dopant‐free c‐Si solar cells to compete against mainstream c‐Si photovoltaics technologies.
Rhodium‐Catalyzed Asymmetric Hydrohydrazonemethylation of Styrenes: Access to Chiral Hydrazones, Hydrazides, Hydrazines and Amines
Authors: Kliemann Max N. , Teeuwen Simon , Weike Christopher , Franciò Giancarlo , Leitner Walter 
Published: August 2022

AbstractThe catalytic asymmetric hydroformylation of styrenes was combined with condensation of the resulting aldehydes with acetohydrazide as nucleophile leading to γ‐chiral N’‐substituted aceto‐hydrazones. This cascade reaction is called hydrohydrazonemethylation (HHM) in analogy to similar hydroformylation/condensation sequences. The catalyst was formed in situ from the commercially available chiral phosphine‐ligand (R,R)‐Ph‐BPE and [Rh(acac)(CO)2] and used at a loading of 0.2 mol%. The stable condensation products are not prone to tautomerization providing versatile chiral intermediates. Their one‐pot reduction with DMAB/TsOH resulted in the corresponding γ‐chiral N’‐substituted acetohydrazides (14 examples) with yields ranging from 73% to 91% and enantioselectivities from 77% to 97% ee. Deprotection of the acetohydrazides led to the corresponding β‐chiral hydrazines. Reduction and hydrogenolysis of the hydrazones over Raney‐Ni yielded the corresponding β‐chiral primary amines with 95% ee. Diastereoselective functionalization of the C=N bond of the hydrazones is a further synthetic option, as demonstrated by allylation with (allyl)SiCl3.magnified image
γ‐Pyronecarbaldehyde‐Based Practical Asymmetric Catalytic Synthesis of Chiral 2,4‐Dihydroxycarboxylic Acids andα‐Hydroxy‐γ‐lactones
Authors: Smirnov Maxim V. , Kucherenko Alexander S. , Gridnev Ilya D. , Korlyukov Alexander A. , Zlotin Sergei G. 
Published: August 2022

AbstractBiomass derivedγ‐pyrone‐2‐carbaldehydes were proposed as robust heterocyclic platform for carrying out organocatalytic asymmetric cross‐aldol reactions with various aldehydes and ketones in high yield with excellent diastereoselectivity and enantioselectivity. Origins of efficient stereoinduction were revealed by quantum‐chemical calculations of four possible transition states. The products were converted to synthetically useful chiral 2,4‐dihydroxy carboxylic acid derivativesviaprotection/deprotection and RuIII‐catalyzed oxidative fragmentation steps without racemization of stereogenic centers. The developed approach was applied for asymmetric synthesis of chiral pantolactones, valuable precursors of biologically active substances and natural products, and for synthesis of Dexpanthenol, a medication used for treating defects in the barrier function of skin.magnified image
Potentiation of Drug Toxicity through Virus Latency Reversal Promotes Preferential Elimination of HIV Infected Cells
Authors: Truong Thanh Tung , Hayn Manuel , Frich Camilla Kaas , Olari Lia‐Raluca , Ladefoged Lucy Kate , Olesen Morten T. Jarlstad , Jakobsen Josefine H. , Lunabjerg‐Vestergaard Cherie K. , Schiøtt Birgit , Münch Jan , Zelikin Alexander N. 
Published: August 2022

AbstractEliminating latently infected cells is a highly challenging, indispensable step toward the cure for HIV/AIDS. Hypothesis put forward herein is that the unique HIV protease cut site (Phe‐Pro) can be reconstructed using a potent inhibitor of tubulin polymerization, monomethyl auristatin F (MMAF), which features Phe at its C‐terminus. This presents opportunities to design prodrugs that are specifically activated by the HIV protease. To this end, a series of MMAF derivatives is synthesized and evaluated in cell culture using latently HIV‐infected cells. The cytotoxicity of compounds is indeed enhanced upon latency reversal by up to 11‐fold. As a result, in a mixed cell population, nanomolar concentrations of the lead compounds depletes predominantly the HIV‐infected cells and in doing so markedly enriches the pool of the uninfected cells. Affinity of the lead compounds to the viral protease is validated computationally and experimentally but despite expectations, the mechanism of action of the synthesized toxins is shown to be independent from the enzymatic activity of the HIV protease.
One Hundred‐Nanometer‐Sized CsPbBr3/m‐SiO2 Composites Prepared via Molten‐Salts Synthesis are Optimal Green Phosphors for LCD Display Devices
Authors: Liu Zheming , Sinatra Lutfan , Lutfullin Marat , Ivanov Yurii P. , Divitini Giorgio , De Trizio Luca , Manna Liberato 
Published: August 2022

AbstractThe exploitation of the optimal optical properties of lead halide perovskite nanocrystals in optoelectronic devices is mainly hindered by the low stability of such materials. Here, a molten‐salts approach is developed to encapsulate CsPbBr3 nanocrystals (together with KNO3, NaNO3, and KBr inorganic salts) inside different nanoscale mesoporous SiO2 host matrices, having sizes between 100 and 300 nm. The comparison between optical properties and stability of the products, including the previously reported ≥600‐nm‐sized CsPbBr3/m‐SiO2 composite, indicates that 100‐nm‐sized CsPbBr3/m‐SiO2 particles feature the best stability against humidity, light irradiation and heat, and exhibit a green (peaked at 517 nm) narrow photoluminescence (full width at half maximum of 18 nm) with high quantum yield (77%). Such properties make these composite particles optimal green phosphors for down conversion liquid crystal displays (LCDs). Indeed, the authors demonstrate that a proof‐of‐concept 7‐in. LCD in which the green color conversion layer is a polymer film loaded with 100‐nm‐sized CsPbBr3/m‐SiO2 particles, features an optimal white emission (with correlated color temperature of 6861 K), that is close to the reference white point of NTSC, and covers 92% of NTSC standard color gamut area of CIE1931, higher than that of a reference commercial LCD (Dell XPS 15 7590 laptop).
Design and experimental analysis of a novel slant‐plate photoreactor
Authors: Zhao Jianyong , Ren Guangmin , Li Zizhen , Meng Xiangchao 
Published: August 2022

AbstractA novel slant‐plate photoreactor (SPR) immobilized with titanium dioxide (P25) was developed to address the disadvantage that the effluent on the backlight side of the corrugated plate photoreactor could not be treated. The SPR was tested and analyzed regarding the degradation of phenol under UV light. For comparison, a flat‐plate photoreactor, a slurry photoreactor, and a corrugated plate photoreactor were also examined. The performance of SPR in phenol degradation was higher than either corrugated plate photoreactor with the same angle or flat‐plate. Furthermore, SPR exhibited highest energy utilization efficiency compared to the corrugated plate photoreactor with the same angle and flat‐plate photoreactor in phenol oxidation. The superior performance of SPR was due primarily to the highly exposed catalyst surface area, high mass transfer coefficient, and multiple reuses of reflected light. In addition, the SPR was tested under natural solar light for its possible implementation in practice.