Ozone pollution during the COVID-19 lockdown in the spring of 2020 over Europe, analysed from satellite observations, in situ measurements, and models
Authors: Cuesta Juan , Costantino Lorenzo , Beekmann Matthias , Siour Guillaume , Menut Laurent , Bessagnet Bertrand , Landi Tony C. , Dufour Gaëlle , Eremenko Maxim 
Published: April 2022

Abstract. We present a comprehensive study integrating satellite observations of ozone pollution, in situ measurements, and chemistry-transport model
simulations for quantifying the role of anthropogenic emission reductions during the COVID-19 lockdown in spring 2020 over Europe. Satellite
observations are derived from the IASI+GOME2 (Infrared Atmospheric Sounding Interferometer + Global Ozone Monitoring Experiment 2) multispectral synergism, which provides better sensitivity to near-surface ozone pollution. These observations are mainly analysed in terms of differences between the average on 1–15 April 2020, when the strictest lockdown restrictions took place, and the same period in 2019. They show clear enhancements of near-surface ozone in central Europe and northern Italy, as well as some other hotspots, which are typically characterized by volatile organic compound (VOC)-limited chemical regimes. An overall reduction of ozone is observed elsewhere, where ozone chemistry is limited by the abundance of NOx. The spatial distribution of positive and negative ozone concentration anomalies observed from space is in relatively good quantitative agreement with surface in situ measurements over the continent (a correlation coefficient of 0.55, a root-mean-squared difference of 11 ppb, and the same standard deviation and range of variability). An average difference of ∼ 8 ppb between the two observational datasets is observed, which can partly be explained by the fact the satellite approach retrieves partial columns of ozone with a peak sensitivity above the surface (near 2 km of altitude over land and averaging kernels reaching the middle troposphere over ocean). For assessing the impact of the reduction of anthropogenic emissions during the lockdown, we adjust the satellite and in situ surface observations
for subtracting the influence of meteorological conditions in 2020 and 2019. This adjustment is derived from the chemistry-transport model
simulations using the meteorological fields of each year and identical emission inventories. Using adjustments adapted for the altitude and
sensitivity of each observation, both datasets show consistent estimates of the influence of lockdown emission reduction. They both show lockdown-associated ozone enhancements in hotspots over central Europe and northern Italy, with a reduced amplitude with respect to the total
changes observed between the 2 years and an overall reduction elsewhere over Europe and the ocean. Satellite observations additionally provide
the ozone anomalies in the regions remote from in situ sensors, an enhancement over the Mediterranean likely associated with maritime traffic
emissions, and a marked large-scale reduction of ozone elsewhere over ocean (particularly over the North Sea), in consistency with previous
assessments done with ozone sonde measurements in the free troposphere. These observational assessments are compared with model-only estimations, using the CHIMERE chemistry-transport model. Whereas a general qualitative
consistency of positive and negative ozone anomalies is observed with respect to observational estimates, significant changes are seen in their
amplitudes. Models underestimate the range of variability of the ozone changes by at least a factor 2 with respect to the two observational datasets, both for enhancements and decreases of ozone. Moreover, a significant ozone decrease observed at a large hemispheric scale is not simulated since the modelling domain is the European continent. As simulations only consider the troposphere, the influence from stratospheric ozone is also missing. Sensitivity analyses also show an important role of vertical mixing of atmospheric constituents, which depends on the meteorological fields used in the simulation and significantly modify the amplitude of the changes of ozone pollution during the lockdown.