bluuebunny/crossref_metadata_2025_split huggingface dataset:
Better experimental design by hybridizing binary matching with imbalance optimization
Authors: Krieger Abba M. , Azriel David A. , Kapelner Adam 
Published: February 2022

AbstractWe present a new experimental design procedure that divides a set of experimental units into two groups in order to minimize error in estimating a treatment effect. One concern is the elimination of large covariate imbalance between the two groups before the experiment begins. Another concern is robustness of the design to misspecification in response models. We address both concerns in our proposed design: we first place subjects into pairs using optimal nonbipartite matching, making our estimator robust to complicated nonlinear response models. Our innovation is to keep the matched pairs extant, take differences of the covariate values within each matched pair, and then use the greedy switching heuristic of Krieger et al. (2019) or rerandomization on these differences. This latter step greatly reduces covariate imbalance. Furthermore, our resultant designs are shown to be nearly as random as matching, which is robust to unobserved covariates. When compared to previous designs, our approach exhibits significant improvement in the mean squared error of the treatment effect estimator when the response model is nonlinear and performs at least as well when the response model is linear. Our design procedure can be found as a method in the open source R package available on CRAN called GreedyExperimentalDesign.
Efficient Etherification of 2,5‐Bis(hydroxymethyl)furan to 2,5‐Bis(propoxymethyl)furan by an Amorphous Silica‐Alumina Catalyst in a Fixed‐Bed Reactor
Authors: Chen Liangqi , Xue Tingting , Hu Hualei , Chen Chunlin , Wang Dazhi , Cai Weijie , Yang Yong , Zhang Jian 
Published: February 2022

AbstractThe efficient etherification of 2,5‐bis(hydroxymethyl)furan (BHMF) to 2,5‐bis(propoxymethyl)furan (BPMF) was achieved by using low‐cost amorphous silica‐aluminas (ASA) catalysts in a fixed‐bed reactor. A considerable yield of BPMF up to 85.1 % was obtained over ASA‐30 catalyst under the reaction conditions of 140 °C, 2.0 MPa of N2, and 0.015 h−1 of WHSV. The excellent performance of ASA‐30 catalyst could be attributed to the relatively stronger acidity (>375 °C) and larger mesoporous size (6 nm), thereby facilitating the conversion of BHMF to BPMF. In addition, the lower ratio of Brønsted/Lewis acid sites for ASA catalyst was found to efficiently suppress the occurrence of side reactions.
Quantitative In‐Situ NMR Illumination for Excitation and Kinetic Analysis of Molecular Motor Intermediates
Authors: Wilcken Roland , Gerwien Aaron , Huber Ludwig Alexander , Dube Henry , Riedle Eberhard 
Published: February 2022

AbstractThe front cover artwork is provided by the groups of Henry Dube and Eberhard Riedle. The image shows an NMR tube at very low temperatures that is illuminated, leading to photoisomerization back and forth of a molecular motor. Quantum yields (Φ) for this process are measured in situ. Read the full text of the Research Article at 10.1002/cptc.202100232.
The ‘Minibulk’ system for advancing winter cereal breeding populations
Authors: Olson Eric , Brown‐Guedira Gina , Noble Amanda , Smith Jared , Forsberg Lance , Brisco Elizabeth , Brown Linda 
Published: February 2022

AbstractConventional selected‐bulk breeding is a low cost means of advancing populations but requires years of selection in the field to generate fixed lines. Doubled haploid (DH) methods produce fixed lines quickly but without selection and at high cost. The ‘Minibulk’ system was developed to combine the speed of DHs with the population size and crossover opportunities of selected‐bulk breeding. Breeding populations of winter wheat (Triticum aestivum L.) were vernalized and advanced at high density in the greenhouse from the F2 to the F4 generation. F4 populations underwent visual selection in the field, and derived lines were genotyped for variants at photoperiod and vernalization alleles and across the genome using genotyping‐by‐sequencing. The number of crossover events and parental genome contributions were determined for recombinant inbred lines (RILs) within populations and among RILs across populations. During vernalization, seeds in all populations germinated and underwent vegetative growth, forming a dense seed mat that was transplanted directly into greenhouse pots. A 22‐h photoperiod accelerated development, and many populations reached physiological maturity as soon as five weeks after transplanting. Increasing the number of seeds planted from 300 in the F2 to 500 in the F3 increased the number of fertile spikes produced, thereby maintaining a larger population size. The number of crossovers detected differed significantly between populations and chromosomes, while the number of crossovers detected in each population was related to marker density. Adoption of the minibulk system by winter cereal breeding programs can lead to significant cost savings and acceleration of the breeding cycle.
A novel multiport converter switching scheme to integrate multiple renewable energy sources
Authors: Bizhani Hamed , Techato Kuaanan , Noroozian Reza , Muyeen S. M. , Blaabjerg Frede 
Published: February 2022

SummaryIn this paper, an innovative switching scheme named simultaneous space vector modulation (SSVM) is proposed for integrating various AC sources in the energy industry using a unified multiport converter. The proposed SSVM technique is applied to the multileg topology of a multiport converter, which is an encouraging option for the grid integration of renewable energy sources and multimachine drives. Considering the shared leg in the multileg converter, the proposed SSVM can utilize the utmost simultaneous switching states between different ports, resulting in lower switching loss and better DC‐link voltage utilization compared with the conventional sequential space vector modulation approach. A novel decision matrix concept is introduced to identify the simultaneous switching states. For this aim, according to the number of ports of the multileg converter, decision matrices containing valid simultaneous switching states are first calculated. Then, they are defined as look‐up tables in the proposed SSVM to be retrieved and exploited in every sampling period. The effectiveness of the proposed SSVM for a seven‐leg version of the multileg converter is assessed using the simulation analysis and real‐time validation. The capability of the proposed SSVM‐based multiport converter in grid integration of AC renewable energy sources is also verified considering two permanent magnet synchronous generator (PMSG)‐based wind turbines with real wind speed patterns. The simulation results confirm that the proposed SSVM is properly able to manage the power flow between different ports and improve the DC voltage utilization and switching loss compared with the sequential SVM.
Novel PE and APC tandems: Additional near‐infrared fluorochromes for use in spectral flow cytometry
Authors: Seong Yekyung , Nguyen Denny X , Wu Yian , Thakur Archana , Harding Fiona , Nguyen Tuan Andrew 
Published: February 2022

AbstractRecent advances in flow cytometry instrumentation and fluorochrome chemistries have greatly increased fluorescent conjugated antibody combinations that can be used reliably and easily in routine experiments. The Cytek Aurora flow cytometer was first released with three excitation lasers (405, 488, and 640 nm) and incorporated the latest Avalanche Photodiode (APD) technology, demonstrating significant improvement in sensitivity for fluorescent emission signals longer than 800 nm. However, there are limited commercially available fluorochromes capable of excitation with peak emission signals beyond 800 nm. To address this gap, we engineered six new fluorochromes: PE‐750, PE‐800, PE‐830 for the 488 nm laser and APC‐750, APC‐800, APC‐830 for the 640 nm laser. Utilizing the principal of fluorescence resonance energy transfer (FRET), these novel structures were created by covalently linking a protein donor dye with an organic small molecule acceptor dye. Additionally, each of these fluorochrome conjugates were shown to be compatible with fixation/permeabilization buffer reagents, and demonstrated acceptable brightness and stability when conjugated to antigen‐specific monoclonal antibodies. These six novel fluorochrome reagents can increase the numbers of fluorochromes that can be used on a spectral flow cytometer.
Multi‐elemental chemostratigraphy of Triassic mudstones in eastern Svalbard: Implications for source rock formation in front of the World’s largest delta plain
Authors: Wesenlund Fredrik , Grundvåg Sten‐Andreas , Engelschiøn Victoria Sjøholt , Thießen Olaf , Pedersen Jon Halvard 
Published: February 2022

AbstractThe Triassic Boreal Ocean was a shallow epicontinental basin and the sink of the World's largest delta plain known to date. Nutrient and freshwater supply from this delta have been regarded as important causes for high productivity and water mass stratification, forming Middle Triassic oil‐prone source rocks. Recent studies attribute upwelling and a productivity‐induced oxygen minimum zone as important factors. A multi‐elemental chemostratigraphic study of a Spathian–Carnian mudstone succession exposed in eastern Svalbard was performed to investigate their formation. This includes 89 samples from three localities, from which 34 elements were acquired using combustion and X‐ray fluorescence analyses. The goal is to provide a correlation framework and infer the role of productivity, redox and water mass restriction on organic matter accumulation and source rock formation. These processes had major impact on the source potential. The Spathian Vendomdalen Member suggests deposition during intermittent benthic euxinia and low productivity, corresponding with a reported deep thermocline that obstructed upwelling. The lower Anisian lower–middle Muen Member shows negligible enrichment in redox‐sensitive elements but in situ phosphate nodules, consistent with developing upwelling and moderate productivity. The middle Anisian upper Muen Member formed during high productivity and phosphogenesis and is linked with basin‐wide upwelling. Productivity, phosphate and redox proxies are all strongly enriched in the upper Anisian–Ladinian Blanknuten Member. In the south‐western Barents Sea, the pro‐deltaic environment of the emerging Triassic Boreal Ocean delta system had terminated these conditions. The upper Ladinian upper Blanknuten Member formed within intermittent euxinic bottom waters due to the shallowing sea level. The Carnian Tschermakfjellet Formation marks the dominance of the prograding delta system and the end of Triassic oil‐prone source rock formation in Svalbard.
Urban runoff and stream channel incision interact to influence riparian soils and understory vegetation
Authors: Solins Joanna P. , Cadenasso Mary L. 
Published: February 2022

AbstractRiparian soil processes and vegetation are sensitive to water availability. Urbanization can alter riparian water availability by modifying stream flows and stream channel morphology. In cities, runoff from impervious surfaces tends to increase stormflow magnitudes, causing stream channels to incise, or downcut. This change in channel morphology has been linked to lowered water tables and drier conditions in temperate urban riparian zones, leading to shifts in riparian nitrogen (N) cycling and vegetation communities. In Mediterranean climates with distinct wet and dry periods, there is an additional dynamic to consider: runoff from urban water use can cause streams to flow when they would otherwise be dry. This dry‐season stream flow could create increased, rather than decreased, water availability in urban riparian zones. However, channel incision may counteract this effect. We asked whether dry‐season stream flow interacted with channel incision to influence riparian soil characteristics and understory vegetation along streams in Sacramento, California, which has a Mediterranean climate with an intense summer dry season. At 40 stream reaches that varied by severity of downcutting and presence of dry‐season flow, we sampled soils and vegetation on top of stream banks and at the margin of the low‐flow channel, an important location for nutrient cycling in dry climates. We measured soil moisture, organic matter, and ∂15N, as well as total and perennial understory vegetation cover. We found that channel characteristics associated with incision limited the influence of dry‐season stream flow on soil moisture, and this interaction appears to have lasting effects on soil organic matter and perennial vegetation on bank tops. At the stream margin, channel downcutting was associated with reduced soil organic matter and vegetation cover, while dry‐season flow was associated with increased vegetation cover. Values of soil ∂15N pointed to limited hydrologic linkage between stream flows and riparian bank soils along incised streams. Our findings suggest that channel incision could limit the ability of urban riparian ecosystems to mitigate low‐flow water quality. However, where streams are not incised in Mediterranean climates, dry‐season flows from urban runoff may actually increase riparian productivity and N cycling above historical levels.
Rapid ant community reassembly in a Neotropical forest: Recovery dynamics and land‐use legacy
Authors: Hoenle Philipp O. , Donoso David A. , Argoti Adriana , Staab Michael , von Beeren Christoph , Blüthgen Nico 
Published: February 2022

AbstractRegrowing secondary forests dominate tropical regions today, and a mechanistic understanding of their recovery dynamics provides important insights for conservation. In particular, land‐use legacy effects on the fauna have rarely been investigated. One of the most ecologically dominant and functionally important animal groups in tropical forests are the ants. Here, we investigated the recovery of ant communities in a forest–agricultural habitat mosaic in the Ecuadorian Chocó region. We used a replicated chronosequence of previously used cacao plantations and pastures with 1–34 years of regeneration time to study the recovery dynamics of species communities and functional diversity across the two land‐use legacies. We compared two independent components of responses on these community properties: resistance, which is measured as the proportion of an initial property that remains following the disturbance; and resilience, which is the rate of recovery relative to its loss. We found that compositional and trait structure similarity to old‐growth forest communities increased with regeneration age, whereas ant species richness remained always at a high level along the chronosequence. Land‐use legacies influenced species composition, with former cacao plantations showing higher resemblance to old‐growth forests than former pastures along the chronosequence. While resistance was low for species composition and high for species richness and traits, all community properties had similarly high resilience. In essence, our results show that ant communities of the Chocó recovery rapidly, with former cacao reaching predicted old‐growth forest community levels after 21 years and pastures after 29 years. Recovery in this community was faster than reported from other ecosystems and was likely facilitated by the low‐intensity farming in agricultural sites and their proximity to old‐growth forest remnants. Our study indicates the great recovery potential for this otherwise highly threatened biodiversity hotspot.
Emergent trophic interactions following the Chinook salmon invasion of Patagonia
Authors: Muñoz Nicolas J. , Reid Brian , Correa Cristian , Madriz Ruben Isaí , Neff Bryan D. , Reynolds John D. 
Published: February 2022

AbstractIn their native range, Pacific salmon (Oncorhynchus spp.) have strong interactions with a multitude of species due to the annual pulse of marine‐derived nutrients that they deliver to streams and forests when they spawn and die. Over the past few decades, Chinook salmon (Oncorhynchus tshawytscha) has established non‐native populations throughout the Patagonia region of southern South America. Here, we provide the first assessment of the pathways through which salmon‐derived nutrients enter stream and forest food webs in Patagonia by surveying multiple streams in southern Chile to identify invertebrate and vertebrate consumers of salmon carcasses and summarizing all documented trophic interactions of Chinook salmon in Patagonia. Blowflies (Calliphoridae) were the dominant colonizer of carcasses in the riparian zone, and midge flies (Chironomidae) were the most common invertebrate on submerged carcasses. Camera trap monitoring in the riparian zone revealed consumption of carcasses or carcass‐associated invertebrates by the insectivorous passerine bird “chucao” (Scelorchilis rubecula), small rodents (black rat Rattus rattus, house mouse Mus musculus, and/or colilargo Oligoryzomys longicaudatus), the South American fox “culpeo” (Lycalopex culpaeus), and the invasive American mink (Neovison vison). A mink was filmed transferring a carcass from stream to streambank, indicating that vertebrate scavenging likely increases the degree to which marine‐derived nutrients enter terrestrial food webs. The native taxa that consume salmon are closely related to species that benefit from salmon consumption in North America, suggesting that the pathways of salmon nutrient incorporation in North American food webs have functionally re‐emerged in South America. Similarly, non‐native trout (Oncorhynchus mykiss and Salmo trutta) and mink consume salmon in Patagonia, and their eco‐evolutionary history of coexistence with salmon could mean that they are preadapted for salmon consumption and could thus be key beneficiaries of this invasion. Expanded monitoring of the abundance and impacts of salmon will be vital for understanding how these novel inputs of marine‐derived nutrients alter Patagonian food webs.
Feasibility analysis of using novel Sepanta biodiesel fuel as an additive to gas micro‐turbine fuels: An experimental study
Authors: Hajinezhad Ahmad , Ahmadi Sepideh Sadat , Alimoradiyan Hamed 
Published: February 2022

AbstractThe population growth, causing the increasing energy demand, the lack of fossil fuels, and its pollution, has become the most important human challenges in years. One of the main goals in using fossil fuels is electricity generation in the utilities, as they can be used in many different types. Gas power plants are one of the ways of generating electricity in many areas, and they are based on gas turbines. The current study aims to define a novel biodiesel fuel named, Sepanta; to improve the combustion conditions of diesel fuel in a gas turbine by using an Iranian endemic plant: Salvia leriifolia seeds oil. In the present research, Sepanta biodiesel has been added to the diesel Euro 4 in different concentrations (20%, 40%, and 60%). Firstly, to determine the differentiation of Sepanta fuel from pure diesel, experiments were carried out such as determining the thermal value and carbon percentage, hydrogen, nitrogen, and oxygen determination in the fuel mixed with Sepanta, and then, in the lake of Sepanta, using the pure diesel, determination of the optimal points has been carried out. The results showed the use of 60% Sepanta reduced the 27% release of unburned hydrocarbons and the use of 40% Sepanta reduced 33% nitrogen oxides in the way to approve the ideal Sepanta performance as an additive to the defined biodiesel.
Fire dynamics inside a large and open‐plan compartment with exposed timber ceiling and columns: CodeRed #01
Authors: Kotsovinos Panagiotis , Rackauskaite Egle , Christensen Eirik , Glew Adam , O'Loughlin Eoin , Mitchell Harry , Amin Rikesh , Robert Fabienne , Heidari Mohammad , Barber David , Rein Guillermo , Schulz Judith 
Published: February 2022

SummaryThere is an increasing global demand to build from timber as it is a sustainable and attractive material. One of the key challenges associated with timber buildings is their performance in a fire, in particular, for medium‐ and high‐rise buildings and when timber is exposed. Research on this topic to date has been performed in compartments smaller than 84 m2 which does not capture the fire dynamics of large compartments. This paper presents the first in a series of experiments carried out inside a large, purpose‐built, open‐plan compartment with a floor area of 352 m2. The large‐scale compartment had a fully exposed, unloaded, cross‐laminated timber (CLT) ceiling and glued laminated timber (glulam) columns, made with adhesives that have been tested to not exhibit char fall‐off in fire. At 352 m2 floor area, this is currently the largest compartment fire experiment carried out globally. The compartment characteristics and the arrangement of the wood crib mimicked the previous series of experiments in Poland in a non‐combustible compartment by Rackauskaite et al. (2021). The experiment was instrumented with thermocouples measuring the gas temperature in the compartment, and above two of the openings, as well as the temperature within the timber members. Plate thermometers were also included to measure the heat flux to the ceiling and of the external flaming. Additionally, fixed and drone‐mounted cameras captured the fire. A protected steel column was added to calculate the equivalent fire exposure when compared to a standard fire resistance furnace test. The experiment was allowed to burn out without fire‐fighting intervention. Continuous measurements were taken for 48 h. The wood crib was ignited at one end of the compartment. Flames rapidly spread across the timber ceiling to the other end of the compartment with the rest of the wood crib being involved in the fire at 5 min 36 s from ignition. The total duration of the fire was 22 min 30 s, at which time visible flaming ceased. Significant external flaming was observed through the openings in the order of 3 m in height but varied with position as the fire travelled across the compartment. Analysis of the experimental results and camera footage showed that the presence of the timber structure approximately doubled the heat release rate (HRR) compared to the value expected from the wood crib alone. Smouldering combustion of the timber members continued for hours after the cessation of flaming, burning in several hotspots, resulting in holes through the CLT slab. This paper improves the understanding fire dynamics for open‐plan, exposed timber compartments and has shown that issues such as external flaming, smouldering and the increase in HRR need to be considered when deriving practical design solutions.