bluuebunny/crossref_metadata_2025_split huggingface dataset:
The relationship between parents’ sleep quality and sleep hygiene and preschool children’ sleep habits
Authors: Chehri Azita , Taheri Paraveh , Khazaie Habibolah , Jalali Amir , Ahmadi Alireza , Mohammadi Reza 
Published: September 2022

Objective The relationship between parents’ sleep quality and sleep hygiene and preschool children’s sleep habits was examined.
Material and Methods The study population consisted of the parents of all preschool children at daycare centers located in Kermanshah Province. Through cluster sampling, 153 parents from 26 daycare centers were selected. In order to assess the quality of sleep and sleep health of parents, Pittsburg sleep quality index (PSQI) and sleep hygiene index (SHI) were used. As to the status of childrens sleep habits (CSH), the parents also completed child sleep habit questionnaire (CSHQ). Data analysis was performed in SPSS version 25. The non-parametric tests like U Mann-Whitney test, Kruskal-Wallis’s test, Spearman’s rho, and regression test were used.
Results The mean score of CSHQ from the parents’ viewpoint was 56.34±7.96, which meant a relatively improper sleep habits in the children. The CSH was significantly and directly related to parents’ sleep quality and all of its subscales except two sub-scales (SSQ and HSE). In addition, CSH was directly and significantly related to the parents’ sleep hygiene and its three subscales. The results of multiple linear regression showed that the impact coeffcient of parents’ sleep quality (B=1.02), given the t-value, predicted changes in CSH with 0.99 confidence.
Conclusion In general, the results showed that CSH was in a relatively bad state, while it had a direct relationship with parents’ sleep quality and hygiene. To improve CSH, it is possible to improve parents’ sleep quality through implementing proper programs and motivating parents to observe sleep hygiene.
The nexus between sleep disturbances and mental health outcomes in military staff: a systematic review
Authors: Farhadian Negin , Moradi Alireza , Nami Mohammad , Kazemi Kamran , Ghadami Mohammad Rasoul , Ahmadi Alireza , Mohammadi Reza , Talebi Mohammad Naseh , Chakrabarti Prasun , Kateb Babak , Khazaie Habibolah 
Published: September 2022

Objectives Military personnel are unique occupational groups who happen to frequently experience sleep insuffciencies. Since sleep disorders are known to be linked to many psychiatric symptoms, sleep disturbance is a salient concern among active duty service members and veterans. Existing evidence indicates that although sleep disturbances co-occur with mental illnesses, there is a tendency to particularly label them as consequences of certain mental health issues.
Material and Methods This review focuses on the emerging evidence which identifies sleep disturbances as a precursor for mental illnesses. In this regard, the impact of sleep disturbance on the development of mental health outcomes including post-traumatic stress disorder (PTSD), depression, and anxiety has been thoroughly scrutinized. A systematic search was conducted using PubMed, Scopus, and Web of Science academic databases using appropriate keywords.
Results Reviewed evidence substantiates the predicting role of sleep complaints and disorders to herald PTSD, depression, and anxiety among military staff.
Conclusion Early diagnosis of sleep disturbances and properly addressing them in active-duty service members and veterans should be then sought to prevent the development and progression of consequent mental health- related comorbidities in this study group.
Correlation and agreement of regional cerebral oxygen saturation measured from sensor sites at frontal and temporal areas in adult patients undergoing cardiovascular anesthesia
Authors: Tribuddharat Sirirat , Ngamsaengsirisup Kriangsak , Mahothorn Phatcharakamon , Sathitkarnmanee Thepakorn 
Published: September 2022

Background
The function and viability of the brain depend on adequate oxygen supply. A decrease in cerebral blood supply causing cerebral desaturation may lead to many neurological complications. Direct measurement of regional cerebral oxygen saturation (rScO2) assists in early detection and management. Near-infrared spectroscopy (NIRS) has been introduced for measuring rScO2. A pair of sensors are attached to the right and left forehead. However, there are some situations where the forehead of the patient is not accessible for sensor attachment (e.g., neurosurgery involving the frontal area; a bispectral index (BIS) sensor already attached, or a wound to the forehead); therefore, alternate sites for sensor attachment are required. The temporal area was proposed as an alternate site. The objective of this study was to assess the correlation and agreement of rScO2 measured at the forehead vs. the temporal area.

Methods
Adult patients undergoing cardiothoracic or vascular surgery were monitored for rScO2 using two pairs of ForeSight sensors. The first pair (A1 and A2) were attached to the right and left forehead, while the second pair (B1 and B2) were attached to the right and left temporal area. The rScO2 values measured from A1 vs. B1 and A2 vs. B2 were assessed for correlation and agreement using the Bland-Altman analysis.

Results
Data from 19 patients with 14,364 sets of data were analyzed. The data from A1 vs. B1 and A2 vs. B2 showed moderate positive correlation (r = 0.627; P < 0.0001 and r = 0.548; P < 0.0001). The biases of A1 vs. B1 and A2 vs. B2 were −2.3% (95% CI [−2.5 to −2.2]; P < 0.0001) and 0.7% (95% CI [0.6–0.8]; P < 0.0001). The lower and upper limits of agreement of A1 vs. B1 were −17.5% (95% CI [−17.7 to −17.3]) and 12.8% (95% CI [12.6–13.0]). The lower and upper limits of agreement of A2 vs. B2 were −14.6% (95% CI [−14.8 to −14.4]) and 16.0% (95% [CI 15.8–16.3]).

Conclusions
The rScO2 values measured from sensors at the frontal and temporal areas show a moderate correlation with sufficiently good agreement. The temporal area may be an alternative to the frontal area for cerebral oximetry monitoring.
Cancer, platelet distribution width, and total protein levels as predictors of rebleeding in upper gastrointestinal bleeding
Authors: Tatlıparmak Ali Cankut , Dikme Özlem , Dikme Özgür , Topaçoğlu Hakan 
Published: September 2022

Background
Rebleeding is associated with poor outcomes in upper gastrointestinal bleeding (UGIB). Identifying predictors of rebleeding can assist in risk assessment. The aim of the study is to investigate the factors affecting rebleeding in patients with UGIB admitted to the emergency department.

Methods
This retrospective, observational, cross-sectional study was conducted on patients with UGIB presented to the emergency department. Patients who did not arrest in the first 24 h, who were not diagnosed with GI malignancy, and who were clinically diagnosed with UGIB were included in the study. Patient demographic characteristics, hemodynamic parameters, patient parameters, and bleeding that may affect rebleeding were evaluated. The primary endpoint was rebleeding within 7 days.

Results
The study included 371 patients. A total of 55 patients (14.8%) had rebleeding within 7 days, and 62 patients (16.7%) presented without bleeding manifestations. Rebleeding rates were higher in those who presented with bloody or coffee-ground vomitus, had a diagnosis of cancer, had blood in their nasogastric tube, and had peptic ulcers due to endoscopy. Mean cell hemoglobin concentration, lymphocyte, albumin, and total protein values of patients with rebleeding were low; red blood cell distribution width, neutrophil count, platelet distribution width (PDW), and neutrophil lymphocyte ratio were high. In-hospital mortality and 30-day mortality values of patients with rebleeding were significantly increased. In the multivariate analysis, cancer, PDW, and total protein levels were statistically significant.

Conclusion
The presence of cancer, low total protein level, and high PDW are effective parameters in predicting 7-day rebleeding in patients with UGIB admitted to the emergency department.
Cost‐Effectiveness of Telehealth‐Delivered Exercise and Dietary Weight Loss Programs for Knee Osteoarthritis Within a Twelve‐Month Randomized Trial
Authors: Harris Anthony , Hinman Rana S. , Lawford Belinda J. , Egerton Thorlene , Keating Catherine , Brown Courtney , Metcalf Ben , Spiers Libby , Sumithran Priya , Quicke Jonathan G. , Bennell Kim L. 
Published: September 2022

ObjectiveTo evaluate the cost‐effectiveness of telehealth‐delivered exercise and diet‐plus‐exercise programs within 12 months.MethodsAn economic evaluation within a 12‐month, 3‐arm, parallel randomized trial of two 6‐month telehealth‐delivered exercise programs, with and without a dietary component. A total of 415 people with knee osteoarthritis ages 45–80 years and body mass index of 28–40 kg/m2 were assigned to 1 of 2 telehealth‐delivered exercise programs, 1 without (n = 172) and 1 with (n = 175) a dietary component (ketogenic very low calorie diet), or to an education control (n = 67), for 6 months, with 6 months follow‐up. The primary economic outcomes were quality‐adjusted life years (QALYs) and health system costs. Measured costs were the direct intervention (consultations, equipment/resources, and meal replacements) and health care use in 2020 Australian dollars ($AU1.5 = $US1). Secondary analysis included weight loss and work productivity gains.ResultsThe clinical trial demonstrated greater improvements in pain and function compared to information only for individuals with knee osteoarthritis and overweight/obesity. We can be 88% confident that diet plus exercise is cost effective ($45,500 per QALY), 53% confident that exercise is cost‐effective ($67,600 per QALY) compared to the control, and 86% confident that augmenting exercise with the diet program is cost effective ($21,100 per QALY).ConclusionTelehealth‐delivered programs targeting exercise with dietary intervention for people with knee osteoarthritis who have overweight/obesity are likely to be cost‐effective, particularly if potential long‐term gains from weight loss and work productivity are realized.
Programmable Synthesis of Biobased Materials Using Cell‐Free Systems
Authors: Choi Yun‐Nam , Cho Namjin , Lee Kanghun , Gwon Da‐ae , Lee Jeong Wook , Lee Joongoo 
Published: September 2022

AbstractMotivated by the intricate mechanisms underlying biomolecule syntheses in cells that chemistry is currently unable to mimic, researchers have harnessed biological systems for manufacturing novel materials. Cell‐free systems (CFSs) utilizing the bioactivity of transcriptional and translational machineries in vitro are excellent tools that allow supplementation of exogenous materials for production of innovative materials beyond the capability of natural biological systems. Herein, recent studies that have advanced the ability to expand the scope of biobased materials using CFS are summarized and approaches enabling the production of high‐value materials, prototyping of genetic parts and modules, and biofunctionalization are discussed. By extending the reach of chemical and enzymatic reactions complementary to cellular materials, CFSs provide new opportunities at the interface of materials science and synthetic biology.
Investigating Adsorption of Cellulose Nanocrystals at Air–Liquid and Solid–Liquid Interfaces in the Presence of Hydrotropes
Authors: Turpin Geosmin A. , Nelson Andrew , Holt Stephen A. , Giles Luke W. , Milogrodzka Izabela , Teo Boon M. , Raghuwanshi Vikram S. , Horn Roger G. , van 't Hag Leonie , Tabor Rico F. 
Published: September 2022

AbstractCoating a substrate with anisotropic nanoparticles such as cellulose nanocrystals (CNCs) confers some of their desirable physicochemical properties, such as strength, wettability, and barrier properties. The formation of monolayer coatings of CNCs via dip coating is affected by the enrichment of CNCs at both air–liquid and substrate–liquid interfaces. In this work, a surfactant‐free method for dip coating CNCs is presented through use of the hydrotrope tetraethylammonium chloride. Hydrotropes demonstrate a different mechanism for facilitating interfacial enrichment, adsorbing to CNCs and rendering them weakly hydrophobic, causing them to adsorb to both solid–liquid and air–liquid interfaces without affecting the surface tension of the system. This new coating mechanism may be more robust as adsorption onto the substrate from the bulk dispersion is less sensitive to the air–liquid interface. Adsorption at the solid–liquid interface showed two distinct CNC layers, with a tightly bound, close‐packed CNC layer at the interface, and a loosely associated outer layer. Adsorption of both layers is shown to be fully reversible after washing with ultra pure water, highlighting the potential of hydrotropes for facilitating new coating mechanisms.
Advances in Processing Kinetics for All‐Inorganic Halide Perovskite: Towards Efficient and Thermodynamic Stable Solar Cells
Authors: Singh Anupriya , Satapathi Soumitra 
Published: September 2022

AbstractThe all‐inorganic CsPbX3 (X—Cl, Br, I) perovskite has the potential to solve the practical issues of environmental instability due to the presence of hygroscopic organic cations in the hybrid organic–inorganic perovskites. The promising CsPbX3 perovskite exists in different crystallographic phases depending upon the composition and processing conditions which potentially impact the film morphology, device efficiency, and stability. Stabilizing the black metastable phase at room temperature has substantially solved the problem of high crystallization temperature, which is the main roadblock in managing the control over morphology and also the choice of the underlying charge transporting layers. Despite this progress, most of the works have not mentioned all the signatures of the metastable lower temperature black phase. In this focused review, the difference between the processing conditions to achieve different phases of not only the CsPbI3 but also the other halogen counterparts is analyzed. Additionally, progress done for each combination of halides is presented and the best processing conditions for each combination of halides are summarized. Finally, their photophysical properties are analyzed and the current state of inorganic perovskites in solar cell applications is presented, and a roadmap is put forward for all inorganic CsPbX3 perovskite‐based commercial photovoltaics devices.
Tailoring intrinsic hydrophobicity and surface energy on rough surface via low‐T Cassie–Wenzel wetting transition method
Authors: Huang Fei , Motealleh Behrooz , Wang Donghui , Cornelius Chris J. 
Published: September 2022

AbstractWettability is an important parameter of micro/nanostructured composites. The measurement of apparent contact angle is strongly affected by surface roughness, which induces some challenges to study the intrinsic hydrophobicity correlating to the nature of chemistry. Carbon‐Nafion composites exhibited about 30° decrease in apparent contact angle from 30 to 10°C due to the condensation of water vapor into cavities, suggesting a significant Cassie–Wenzel wetting transition phenomenon. The focus of this work has been on the first‐time use of a low‐T Cassie–Wenzel wetting transition method to evaluate Young's (ideal) contact angle and surface free energy. A maximum Young's contact angle (113°) and minimum total surface energy (12 mJ/m2) were determined at Nafion content of 70 wt%, indicating the orientation effect that sulfonate groups in Nafion preferentially pointed toward polar carbon. This approach provided the reasonable prediction of intrinsic hydrophobicity, especially when a rough solid surface is not easily wetted by liquids.
Base‐catalyzed Sulfurative Condensation of 2‐Oxoindoles to Isoindigos Using Elemental Sulfur
Authors: Chen Wei , Lu Xiao‐Bing , Zhou Hui 
Published: September 2022

AbstractHerein, the base‐catalyzed formation of isoindigos is described through the cascade reaction of 2‐oxoindoles with elemental sulfur (S8) serving as an environmentally friendly and cheap sulfurating reagent. Readily available organic amines, especially 1,4‐diazabicyclo[2.2.2]octane (DABCO), exhibit excellent activity for this protocol, thus simply and efficiently providing structurally diverse isoindigos in moderate to high yields with a broad substrate scope. A plausible mechanism involving the	generation of 3‐thioisatin intermediates and the subsequent self‐condensation, was proposed on the basis of mechanistic studies. The practicality of the methodology was further demonstrated by the synthesis of gram‐scalable drug molecules and value‐added spirothiopyrans.
Inorganic Bases Enhanced Organocatalysis for Aerobic α‐Hydroxylation of Aliphatic Cycloketones
Authors: Wang Yongtao , Sun Wenjing , Lu Rui , Wen Zeyu , Yao Jia , Li Haoran 
Published: September 2022

AbstractDue to the lack of approach for aerobic α‐hydroxylation of the inert α‐C(sp3)‐H in aliphatic cycloketones, here we attempt to activate it by the combination of 1,5,7‐triazabicyclo [4.4.0] dec‐5‐ene with inorganic bases at controlled basicity. Via kinetic experiments, the role of weak inorganic bases was unveiled to protect TBD from the keto acid byproducts. Furthermore, by the investigation of substrate scope and DFT calculations, we revealed that the alkyl‐substitution induced ring strain release in cycloketones dominated both the reactivity and selectivity. We assume these findings could benefit the synthesis route designs and method developments for inert C−H oxidations.
A multiplicity of identities: The intersections of cranial vault modification, paleodiet, and sex in San Pedro de Atacama, Chile
Authors: Torres Christina M. , Knudson Kelly J. , Pestle William J. 
Published: September 2022

AbstractObjectivesIntentional cranial modification and diet serve as markers of identity. Here, we explore the intersection between the body and social persona in the San Pedro oases through the complex relationship(s) between these markers and other aspects of society and the individual.MethodsSkeletal remains of 1190 individuals were analyzed for evidence of intentional head shaping and classed as unmodified, tabular, or annular. Stable carbon and nitrogen isotope analyses of bone (n = 203) focused on the contribution of C3plants, C4/CAM plants, beans, and terrestrial animal meat per the Bayesian model, FRUITS. Strontium isotope data from dental enamel was considered for more detailed analyses.ResultsCranial modification was present in 520 individuals (43.7%;N = 1190). Modification was significantly more common among females (χ2 = 7.403,p = 0.007). There was no significant difference in presence or type between periods. Average values for the four modeled food groupings differ significantly. There is a significant difference in consumption of C4/CAM plants by those individuals with modified heads consuming more (26.5 ± 9.9% vs. 23.6 ± 9.4%, Wilcoxon signed‐rank test,p < 0.05). In the Middle Period sample, males consume significantly more C4/CAM plants (p < 0.05) and females more C3plants (p < 0.01). Four of those with outlier C4values were analyzed for strontium, yielding values outside the “local” range.ConclusionsAs head shaping is permanently imposed in infancy while dietary patterns are the consequence of ongoing choices and constraints in the social and ecological environment, these markers of identity are not parallel. The numerous points of intersection between these markers and other aspects of identity are highlighted.
Wide‐ranging migration and destination of early olfactory placode‐derived neurons in chick embryos
Authors: Miyakawa Momoko , Murakmai Shizuko , Uchiyama Yasuo 
Published: September 2022

AbstractCell migration from the olfactory placode (OP) is a well‐known phenomenon wherein various cell types, such as gonadotropin‐releasing hormone (GnRH)‐producing neurons, migrate toward the telencephalon (TEL) during early embryonic development. However, the spatial relationship between early migratory cells and the forebrain is unclear. We examined the early development of whole‐mount chick embryos to observe the three‐dimensional spatial relationship among OP‐derived migratory neurons, olfactory nerve (ON), and TEL. Migratory neurons that express highly polysialylated neural cell adhesion molecule (PSA‐NCAM) emerge from the OP and spread over a relatively wide TEL area at the Hamburger and Hamilton (HH) stage 17. Most migratory neurons form a cellular cord between the olfactory pit and rostral TEL within HH18–20. The earliest axons from the olfactory epithelium (OE) were detected along this neuronal cord using DiI‐labeling at HH21. Furthermore, a few PSA‐NCAM‐positive neurons were dispersed around the cellular cord and over the lateral TEL at HH18. A long cellular cord branch extending to the lateral TEL was transiently observed within HH18–24. These results suggest a novel migratory route of OP‐derived neurons during the early developmental stages. Following GFP vector introduction into the OP of HH13–15 embryos, labeled neurons were detected around and within the lateral TEL at HH23 and HH27. At HH36, labeled cells were observed in the rostral‐lateral TEL, including the olfactory bulb (OB) region. GFP‐labeled and calretinin‐positive neurons were detected in the OB, suggesting that early OP‐derived neurons enter the forebrain and function as interneurons in the OB.
Untangling business model outcomes, impacts and value
Authors: Dembek Krzysztof , Lüdeke‐Freund Florian , Rosati Francesco , Froese Tobias 
Published: September 2022

AbstractValue is a key concept in the business model literature. Yet business models are not only about value and how it is created. They are also key to understanding how organisations create outcomes for stakeholders and impact the natural environment and society. So far, however, business model studies have paid little attention to the conceptual differences and particularities of outcomes, impacts and value. This prevailing vagueness is critical. Lacking an understanding of how organisations create outcomes and impacts while aiming to create value with and for their stakeholders can harm both communities and the organisations involved, despite their best intentions. Hence, this article clarifies the differences between business model outcomes, impacts and value and offers an activity system theory‐based framework to map and analyse business models. Using the example of TOMS, this article shows how changes in a business model's activity system influence the outcomes, impacts and value it creates. Finally, we argue that a stakeholder perspective is necessary but insufficient to understand the system‐level impacts of business models and that it needs to be complemented with a systems theory lens.