bluuebunny/crossref_metadata_2025_split huggingface dataset:
(Invited) High Throughput Solvent-Free Manufacturing of Battery Electrodes
Authors: Steinhoff Bryan Dennis , Dong James , Mashtalir Olha , Amin-Sanayei Ramin , Hong Kunlun , Li Jianlin 
Published: November 2022

Research into the manufacturing of LIB electrodes is constantly evolving with new active materials, improved binders, and improved drying techniques to more efficiently produce high-quality electrodes. However, the one constant in all these endeavors is that electrode research and manufacture still generally rely on a slurry-coating process, where large amounts of potentially toxic solvents are necessary for slurry production. As such, solvent-free, also known as dry-process (DP), electrode processing has been proposed to solve the conventional lithium-ion battery electrodes fabrication disadvantages, such as high equipment costs for solvent reclamation, currently seen in industry.
Currently, the solvent-free, state-of-the-art electrodes use polytetrafluoroethylene (PTFE) as a binder and the PTFE is fibrillized and dispersed in the dry powder mixture using a jet mill. One key solvent-free electrode shortcoming is that PTFE is not electrochemically stable for the anode, traditionally resulting in initial capacity losses of greater than 30% and poor mechanical strength, effectively limiting solvent-free processing to cathodes. A second shortcoming is that solvent-free electrodes generally require the addition of fibrillization promoters or processing steps that add cost and detract from performance by limiting active material content in the final electrodes.
In a recent development, Navitas and its internal partners of Cabot, Arkema, the University of Tennessee, Knoxville, and Oak Ridge National Laboratory have shown the capability to produce both solvent-free anodes and cathodes utilizing an advanced dry-electrode process (ADEP) that also enables high-throughput production of next generation battery electrodes. These electrodes have improved mechanical strength, sufficient to withstand roll-to-roll manufacturing, and the anodes demonstrate an initial capacity loss of less than 15%. The group has demonstrated roll-to-roll production of solvent-free electrodes at quasi-industry standard active material compositions (90-92%) without the reliance of previously used fibrillization promoters, even at reduced PTFE concentrations in the formulation. Navitas has recently demonstrated the large format lamination of the initially formed, or “free-standing,” electrodes after they have been produced in roll-to-roll manufacturing and the integration of solvent-free electrodes in dual-layer and multi-layer pouch cells using typical industry tooling and cell production techniques.
Key words: solvent-free, dry-process, fibrillization, next generation lithium-ion batteries (NGLB), advanced dry-electrode process (ADEP), initial capacity loss, free-standing, roll-to-roll, pouch cell
Assembling an All-Solid-State Ceramic Battery: Assessment of Chemical and Thermal Compatibility of Solid Ceramic Electrolytes and Active Material Using High Temperature X-Ray Diffraction
Authors: Bertrand Marc , Rousselot Steeve , Aymé-Perrot David , Dollé Mickaël 
Published: November 2022

Lithium ion batteries (LIBs) are the most known and used batteries for portable energy storage because of their high energy densities, long cycle life and relatively low price. However, they still fall short for the development of long range electric vehicles and stationary applications due to organic liquid electrolytes that are currently electrochemically limited and present safety issues (fire or explosion in case of short-cut or overcharging). Solid oxide electrolytes appear to be one of the solutions because of their non-flammability and wide potential window. Inorganic oxide electrolytes have reasonable ionic conductivities (10-5-10-3 S/cm at ambient temperature), high mechanical strength, and high chemical stability.
Assembling an all ceramic solid-state battery with inorganic oxide electrolyte is challenging as it requires a deep knowledge of the thermal, chemical and electrochemical behavior of each component of the cell. The battery must be a continuous monolithic block with a thin dense electrolyte separator, in order to minimize the polarization. In addition, optimized interfaces between active material and electrolytes must be ensured in the composite electrodes. This is often achieved with oxide-based materials by using high temperature processing.
Thermal expansion occurring during this step can lead to cracks, which will affect the performance and cyclability of the device. The primary driving force of a crack during the fabrication of hybrid ceramic is the stress due to mismatch in the coefficient of thermal expansion (TEC) of the various layers/materials. Moreover, it must be certain that no reaction occurs between active material and electrolytes in the sintering temperature range. These are then two key parameters to address for the development of all ceramic solid-state batteries.
In this work, in situ-XRD has been used to determine the TEC and the thermal stability of various well-known oxide active materials and solid electrolytes. The aim of this presentation is to discuss about the best selection of compatible oxide-based materials to avoid unwanted cracks or reaction during the sintering processing of ceramic solid-state batteries.
Enhancing Cycle Performance for Li-Rich Layered Oxides By the Stabilization of Crystal Structure
Authors: Choi Woo-Seok , Sung Nak Kyun , Kim Jeom-Soo 
Published: November 2022

Li-rich layered oxides (LLO) have been studied as a next generation low-cost and high-capacity positive electrode materials. In LLO, the structural stability must be ensured to reversible Li intercalation. Blocking the tetrahedral site, the path of ions moving from transition metal sites to the lithium layer, may reduce the cation mxing which casuses the structural instability. In addition, introducing electrochemically inactive metal ions in the transition metal layer would stabilize the O-Me-O stacking by binding energy with oxygen which is higher than the transition metals.
In this study, LLOs were obtained with and without doping at varous conditions. Doping elements are B and Ge of x mol% with repect of transition metals (Mn, Ni, Co). The effect of doping of is evaluated through the evaluation of the physical and electrochemical characteristics of the synthesized LLOs. Especially, the elelctrochemical cycle stability is throughly studied at various charge cuf-off voltages. The details of evaluation and analysis results will be presented.
Using Organosulfur Materials to Solve Critical Challenges Facing Lithium-Sulfur Batteries
Authors: Bhargav Amruth , Manthiram Arumugam 
Published: November 2022

The high abundance and environmental benignity of sulfur coupled with its high energy density of nearly 2,500 Wh kg-1 render the lithium-sulfur (Li-S) battery technology a sustainable energy storage solution for the future. Unfortunately, in Li-S batteries, the sulfur cathode suffers from poor electronic and ionic conductivity and the notorious polysulfide shuttle effect. Meanwhile, the anode suffers from continuous degradation owing to the high reactivity of Li metal. Organosulfur materials may present a way to overcome these limitations. Organic functional groups bound to sulfur could enhance electronic and ionic conductivity. Limiting the polysulfide order in an organosulfur material can minimize the shuttle effect. Furthermore, organic groups could stabilize the electrolyte-anode interface.
Two studies on using organosulfur materials to overcome the challenges of Li-S will be presented. The first study shows a method to rationally design organosulfide polymers that can provide inherent Li-ion conductivity. The enhancement in ionic conductivity results in an improvement in performance under high-rate and high-loading conditions. The application of such materials in flexible Li-S batteries will be showcased. In the second study, a mechanistic understanding of how organosulfide-rich interphase at the Li-metal anode improves the stripping/plating efficiency will be elucidated. By understanding the effect of different functional groups on the efficiency of the anode, a set of design rules for developing organosulfide molecules that generate a stable interface will be proposed.
Comparative Study on the Electrochemical Properties of Cylindrical and Pouch-Type Lithium Ion Battery
Authors: Kim Min-Sung , Shim Jae-Hyun , Kim Bom , Kim Woo-Jin , Kim Jae-Hoon 
Published: November 2022

As the field expands from portable electronic devices to large energy storage devices such as electric vehicles, more reliable and innovative battery technologies are more important than ever.
Currently, there are three types of lithium battery packaging: cylindrical, prismatic and pouch. Cylindrical batteries with a cylindrical shape and structure were one of the first mass-produced battery types and are still mass-produced and dominate in some applications. On the other hand, prismatic batteries are gaining popularity due to their high capacity, thin form, and efficient use of space. Due to the angular shape, multiple cells can be easily connected to form larger packs. Finally, pouch batteries are known for their lighter construction, using a sealed flexible foil as the packaging material.
Each of these battery types offers a set of advantages and disadvantages. There is no clear winner, but the battery you choose can influence your product design in many ways. For example, each of these battery form factors can have a different temperature distribution and heat transfer model.
In this study, a cylindrical battery and a pouch-type battery of the same capacity were manufactured using the same four major materials (positive electrode, negative electrode, separator, and electrolyte), respectively, to study the cell chemical characteristics of Li-ion secondary batteries. In particular, it is intended to provide a field to which each type of lithium ion secondary battery can be applied by understanding the characteristics of thermal and deterioration.
(Digital Presentation) A Battery Interface Ontology for Data Interoperability and Semantic Knowledge Representation
Authors: Clark Simon , Andersen Casper Welzel , Flores Eibar , Bleken Francesca Lønstad , Friis Jesper 
Published: November 2022

Data drives battery development. Despite the unprecedented volume of data being generated across both industry and research today, the battery data landscape remains a patchwork of heterogeneous sources with inconsistent metadata needed to correctly interpret its meaning. A new approach is needed to ensure that reported battery data is interoperable, reusable, and machine-readable. Furthermore, there is a growing need to share knowledge about batteries among groups from different backgrounds and organizations (e.g., experimentalists, modellers, engineers, technicians, etc.).
The Battery Interface Ontology (BattINFO) is designed to meet these needs [1]. An ontology is a data model that represents domain knowledge as a map of concepts and the relations between them. This allows data to be mapped to common vocabulary terms, such that any two pieces of data mapped to the same term are also mapped to each other. Additionally, the network of concepts and relations allow expert knowledge to be expressed as graphs in a machine-readable form, which can then be queried to identify links between individual pieces of data and quickly share knowledge across organizations.
BattINFO is a free, open-source domain ontology for electrochemistry and batteries that facilitates battery data interoperability and enables machine-readable semantic knowledge representation. A conceptual overview is shown in Figure 1. BattINFO was developed within the scope of the EU H2020 project BIG-MAP to facilitate data interoperability between more than 30 battery research institutes and companies in Europe. This contribution introduces BattINFO, demonstrates specific use cases for how it can be applied to accelerate battery data handling and development, and presents plans for future development and integration into the global battery data landscape.
[1] S. Clark et al., “Toward a Unified Description of Battery Data,” Adv. Energy Mater., vol. 2102702, 2021.

Figure 1
Stabilization of Dual Interfaces for High-Capacity Sulfurized Polyacrylonitrile through Electrolyte Selection
Authors: Yu Kunpeng , Li Mingqian , Holoubek John , Cai Guorui , Chen Zheng 
Published: November 2022

Sulfurized polyacrylonitrile (SPAN) is considered as a promising cathode for the increasing need of high energy density and low-cost lithium-ion batteries. By chemically attaching sulfur to the conductive polymer backbone, SPAN system can promote a solid-solid conversion during the lithiation/delithiation process of sulfur, which avoids the polysulfide “shuttle effect”, and thus renders a better cycling stability compared to Li-sulfur system. However, due to the dissolving nature of long-chain polysulfide in ether-based electrolyte, SPAN annealed at high temperature is preferred in many Li-SPAN systems, which sacrifices the specific capacity in exchange for a higher cycling stability.
Here, a new design strategy for Li-SPAN batteries is reported. We manipulate a multistage approach by selecting SPAN and compatible electrolyte to achieve high specific capacity and outstanding cycling stability. In this work, optimally annealed SPAN is selected to increase the capacity, and localized high-concentration electrolyte (LHCE) is chosen in consideration of stabilizing the interfaces on both cathode and anode. Compared with commonly used carbonated-based electrolyte, LHCE shows a great advantage on capacity and cycling stability. Moreover, the long cycling performance of the high-mass-loading full cells under room (23°C) and high (60°C) temperature is demonstrated with a great potential for high-energy and low-cost batteries.
High-Quality Electrochemically Exfoliated Graphene Protective Layer for Metal Batteries
Authors: Lee Hoyoung , Lee Seung Woo , Lee Kyungbin 
Published: November 2022

Graphene has attracted substantial attention due to its exceptional mechanical, thermal, electrical, and chemical properties. There has been active research for the scalable production of high-quality graphene. Among various techniques, electrochemical exfoliation is facile, fast, and cost-effective for graphene production. Our previous finding on anodic exfoliation suggested that the binding energy between the intercalator and graphene sheet plays an important role in exfoliation efficiency.1 We further extended the hypothesis to the cathodic exfoliation process to produce high-quality graphene. The characteristics and morphologies of electrochemically exfoliated graphene using alkali metals (e.g. Na, K, and Cs) are compared. Then, we will employ the exfoliated graphene on lithium metal anodes as carbon support for efficient lithium deposition in lithium metal batteries.
References

Lee, H.; Choi, J. I.; Park, J.; Jang, S. S.; Lee, S. W. Role of anions on electrochemical exfoliation of graphite into graphene in aqueous acids. Carbon 2020, 167, 816-825.
Hypoperfusion Intensity Ratio Is Correlated With the Risk of Parenchymal Hematoma After Endovascular Stroke Treatment
Authors: Winkelmeier Laurens , Heit Jeremy J. , Adusumilli Gautam , Geest Vincent , Christensen Soren , Kniep Helge , van Horn Noel , Steffen Paul , Bechstein Matthias , Sporns Peter , Lansberg Maarten G. , Albers Gregory W. , Wintermark Max , Fiehler Jens , Faizy Tobias D. 
Published: November 2022

Background:
Parenchymal hematoma (PH) is a major complication after endovascular treatment (EVT) for ischemic stroke. The hypoperfusion intensity ratio (HIR) represents a perfusion parameter reflecting arterial collateralization and cerebral microperfusion in ischemic brain tissue. We hypothesized that HIR correlates with the risk of PH after EVT.

Methods:
Retrospective multicenter cohort study of patients with large vessel occlusion who underwent EVT between 2013 and 2021 at one of the 2 comprehensive stroke centers (University Medical Center Hamburg-Eppendorf, Germany and Stanford University School of Medicine, CA). HIR was automatically calculated on computed tomography perfusion studies as the ratio of brain volume with time-to-max (Tmax) delay >10 s over volume with Tmax >6 s. Reperfusion hemorrhages were assessed according to the Heidelberg Bleeding Classification. Primary outcome was PH occurrence (PH+) or absence (PH−) on follow-up imaging. Secondary outcome was good clinical outcome defined as a 90-day modified Rankin Scale score of 0 to 2.

Results:

A total of 624 patients met the inclusion criteria. We observed PH in 91 (14.6%) patients after EVT. PH+ patients had higher HIR on admission compared with PH− patients (median, 0.6 versus 0.4;
P
<0.001). In multivariable regression, higher admission blood glucose (adjusted odds ratio [aOR], 1.08 [95% CI, 1.04–1.13];
P
<0.001), extensive baseline infarct defined as Alberta Stroke Program Early CT Score ≤5 (aOR, 2.48 [1.37–4.42];
P
=0.002), and higher HIR (aOR, 1.22 [1.09–1.38];
P
<0.001) were independent determinants of PH after EVT. Both higher HIR (aOR, 0.83 [0.75–0.92];
P
<0.001) and PH on follow-up imaging (aOR, 0.39 [0.18–0.80];
P
=0.013) were independently associated with lower odds of achieving good clinical outcome.

Conclusions:
Poorer (higher) HIR on admission perfusion imaging was strongly associated with PH occurrence after EVT. HIR as a surrogate for cerebral microperfusion might reflect tissue vulnerability for reperfusion hemorrhages. This automated and quickly available perfusion parameter might help to assess the need for intensive medical care after EVT.
Levites, Priests, and Temple: Was the Chronicler Influenced by Ezekiel 40–48?
Authors: Amar Itzhak 
Published: November 2022

Abstract
This article examines whether Chronicles was influenced by Ezek 40–48—i.e., whether the book contains material not found in P or developed therefrom. To this end, it investigates the basis on which the Chronicler distinguishes priests from Levites, identifies those he deems responsible for guarding the Temple, elucidates his view of the Temple’s sanctity, and discusses whether he draws on one or several sources.
Luxuriant and Well-Fatted: The Meaning of מעדנת in 1 Sam 15:32
Authors: Millar Suzanna R. 
Published: November 2022

Abstract
The meaning of מעדנת in 1 Sam 15:32 is disputed, variously being translated “trembling,” “in chains,” or “cheerfully.” Based on linguistic and contextual evidence, I argue that it is best translated “luxuriantly” or “well-fatted,” and depicts Agag like a fattened animal going to slaughter.
Death on display
Authors: Casteels Isabel 
Published: November 2022

Abstract
Isabel Casteels examines the response of contemporary viewers – both intended and actual – to Frans Hogenberg’s execution prints dating from the first decades of the Dutch Revolt. Hogenberg characterised these executions, like those of the counts of Egmond and Horn in Brussels in 1566, as religious ceremonies, thus implicitly criticising them. The prints highlight the public, ritual, and indeed purely theatrical elements of these events, which, from the perspective of the Catholic Church and the secular authorities, may have legitimised them, but for Protestants and supporters of the Revolt generally did exactly the opposite – that is, de-legitimised them, exposed them for what they really were: cruel bloodshed. Eyewitness accounts confirm this, as did the prosecution of printers who issued copies of the prints. The depiction of the audience in many of the prints made their viewers aware of their role in these judicial rituals.
Materia mortis
Authors: Lipińska Aleksandra 
Published: November 2022

Abstract
This essay offers a revaluation of the materiality of early modern Netherlandish tombs, a field that has only recently attracted serious scholarly attention. Her contribution focuses on the role played by materiality as a crucial yet often overlooked aspect of these monuments. Tomb sculpture generally relied on a combination of material properties: the potential of realistic representation, durability, intrinsic value, and material splendour. Most suitable for a convincing representation of a dead body in this period was translucent alabaster with its warm flesh tone, while Italian white marble and bronze referenced antiquity and classical notions of durability. The use of specific sets of local and imported materials resulted in a unique ‘material image’ of Netherlandish tomb sculpture, which effectively contributed to the preservation of the deceased’s memoria, social status, and dynastic and personal magnificence.
Facilitating Civic Awareness and Social Participation as a Product: A Case Study of Formosa Salon
Authors: Lee Bo-Yi 
Published: November 2022

Abstract
Social marketing aims to improve social welfare by changing individuals’ behaviours, and deepening democracy should not be an exception. We can use social marketing to enhance civic awareness and public engagement by turning citizens who do not care about these issues into active participants in our society. However, current research has not explored how we can apply social marketing to achieve this goal. This research examines Formosa Salon from the perspectives of exchange theory, the theory of hierarchy of effects, and the framework of the social marketing mix. By gathering and analysing data from archival data, semi-structured interviews, and researchers’ engagement, this study views increasing civic awareness and promoting public engagement in social issues as a product sold by Formosa Salon. The price of this product is the knowledge barrier. The organisers of Formosa Salon have marketed their product on the internet and through higher education institutions in London. The contributions of this study and key recommendations are also identified.
The efficacy and safety of telitacicept for the treatment of systemic lupus erythematosus: a real life observational study
Authors: Chen Ruilin , Fu Rong , Lin Zeying , Huang Chenghui , Huang Wenhui 
Published: November 2022

Objective To investigate the efficacy and safety of telitacicept treatment in a Chinese SLE cohort, with real-life settings. Methods All patients with SLE who were receiving telitacicept treatment at least 4 weeks were included, and were followed up. Patients received subcutaneous injection of telitacicept weekly based on the standard treatment. SLE responder index-4 (SRI-4) was assessed before the first administration and at least 4 weeks after the first administration. Disease flares during the follow-up period were defined as an increase in disease activity and the number or dose of immunosuppressive drugs. Results After 4–45 weeks’ administration of telitacicept, 80% ( n = 16) reached SRI-4 response. The prednisolone dosage declined from a mean of 30.25 mg/d (95% CI 21.99–38.51) before treatment to 13.25 mg/d (95% CI 9.92–16.58) after treatment. The proportion of patients without receiving an immunosuppressive drug increased from 15% to 43% at the endpoint. 19 cases showed various reduction of IgM after treatment ( p < 0.05) and C3 and C4 showed either stable or an upward trend. The 24 h urinary protein median value of the 14 cases (baseline 24 h urinary protein >0.5 g/d) showed significant reduction, and 7 of them turned negative. Adverse events were mild to moderate and controllable. Conclusion Telitacicept is a potential treatment option for patients with SLE, especially in lupus nephritis, with significantly increased SRI-4 response rate and reduced the glucocorticoid and immunosuppressive drugs.