bluuebunny/crossref_metadata_2025_split huggingface dataset:
SOCIO-ECONOMIC DEVELOPMENT IN THE CONTEXT OF USING REASONABLE SPECIALIZATION IN THE ECONOMY OF UKRAINE
Authors: Andrusiv Uliana , Zelinska Halyna , Galtsova Olga , Seleznova Olena , Bahorka Mariia , Yurchenko Nataliia 
Published: May 2022

. The article analyzes the uneven economic growth in the regions of Ukraine and proposes the development of regional policy based on the use of the smart specialization idea. As a tool for analyzing the uneven economic development of regions, we used a method based on the comparison of regions by gross regional product per capita, which formed the basis for determining the funnel of backwardness of the region among others in terms of economic growth. The analysis was conducted for 2010 and 2020. The calculations made it possible to identify areas that differ significantly in development potential. It is proposed to use the ideas of the smart specialization concept as a new model of the Ukraine’s regions economic development in order to equalize interregional disparities. Revealed the essence of this concept implementation on the example of the Carpathian region economy in 2020 is revealed. It is determined that the formation of educational, tourist and construction clusters in the region are the foundations that will form a long-term strategy for its development. The main measures for the introduction of construction and educational clusters are proposed. The components that determine the innovative development of Ukraine on the basis of the Global Indices of Competitiveness and Innovation are analyzed. Proposed the formation of economic policy, which is aimed at solving strategic tasks of the regions socio-economic development - ensuring economic growth and quality of life in Ukraine. It is justified that the application of the smart specialization approach in long-term regional strategies will contribute to a synergistic effect for both human and innovative development, which is the goal of the new regional economic policy.
To solvethe tasks used general and special research methods, namely: theoretical generalization to clarify the essence of smart specialization), statistical, comparative, comparative and strategic analysis (to calculate and build the dynamics of GRP per capita by region of Ukraine), graphical (for a visual representation of the results of the analysis). In addition, the visualization method was used to build the algorithm for forming the regional policy of Ukraine.
Combinations of action observation and motor imagery on golf putting’s performance
Authors: Lin Chi-Hsian , Lu Frank J.H. , Gill Diane L. , Huang Ken Shih-Kuei , Wu Shu-Ching , Chiu Yi-Hsiang 
Published: May 2022

Motor imagery (MI) and action observation (AO) have been found to enhance motor performance, but recent research found that a combination of action observation and motor imagery (AOMI) together is even better. Despite this initial finding, the most effective way to combine them is unknown. The present study examined the effects of synchronized (i e.,concurrently doing AO and MI), asynchronised (i.e., first doing AO then MI), and progressive (first asynchronised approach, then doing synchronized approach) AOMI on golf putting performance and learning. We recruited 45 university students (Mage = 20.18 + 1.32 years; males = 23, females = 22) and randomly assigned them into the following four groups: synchronized group (S-AOMI), asynchronised group (A-AOMI), progressive group (A-S-AOMI), and a control group with a pre-post research design. Participants engaged in a 6-week (three times/per-week) intervention, plus two retention tests. A two-way (group × time) mixed ANOVA statistical analysis found that the three experimental groups performed better than the control group after intervention. However, we found progressive and asynchronised had better golf putting scores than synchronized group and the control group on the retention tests. Our results advance knowledge in AOMI research, but it needs more research to reveal the best way of combining AOMI in the future. Theoretical implications, limitations, applications, and future suggestions are also discussed.
High Mass Loading 3D‐Printed Sodium‐Ion Hybrid Capacitors
Authors: Yuan Jun , Qiu Min , Chen Jun Xiang , Hu Xiang , Liu Yangjie , Yu Biao , Zhong Guobao , Weng Zixiang , Zhan Hongbing , Wen Zhenhai 
Published: May 2022

AbstractSodium‐ion hybrid capacitors (SIHCs) have been regarded as one of the promising energy devices thanks to its low cost and compromise between energy density and power density, yet remain a challenge towards practical levels of mass loading (>10 mg cm−2). Herein, the fabrication of a 1D core–shell structure is reported with N‐doped porous carbon encapsulating ZnV2O4 nanofibers (ZnV2O4NFs@N‐PC), which features an open framework and favorable properties for facilitating ion diffusion, mass transportation, and electron transfer, enabling it to perform impressively for sodium ions storage. A 3D printed SIHC is conceptually proposed by coupling the 3D printed ZnV2O4NFs@N‐PC anode with a 3D printed active carbon cathode, which can deliver a high energy/power density of 145.07 Wh kg−1/3677.1 W kg−1 with a durable cycling lifespan. It is demonstrated that the 3D printed SIHC, even at a high mass loading of up to 16.25 mg cm−2, can release a high areal energy/power density of 1.67 mWh cm−2/38.96 mW cm−2, outperforming most of the SIHCs developed so far. The present work sheds light on the role of the design of electrode materials and verifies the promise of 3D‐printed technology for next‐generation electrochemical energy devices.
Low Surface Accessible Area NanoCoral TiO2 for the Reduction of Foreign Body Reaction During Implantation
Authors: Zhang Fanyu , Qi Haoning , Mo Wenting , Ni Yueqi , Zhao Qin , Wang Yulan , Jiang Shuting , Tang Qinchao , Cheng Yihong , Xiao Xiangheng , Zhang Yufeng 
Published: May 2022

AbstractThe entry of implants triggers the secretion of damage associated molecular patterns (DAMPs) that recruit dendritic cells (DCs) and results in subsequent foreign body reaction (FBR). Though several studies have illustrated that the surface accessible area (SAA) of implants plays a key role in the process of DAMPs release and absorption, the effect of SAA on the immune reaction still remains unknown. Here, a series of TiO2 plates with different SAA is fabricated to investigate the relationship between SAA and FBR. Compared with larger SAA surface, the aggregation of DC is significantly inhibited by lower SAA surface. Total internal reflection microscopy (TIRFM) and molecular dynamic (MD) simulation show that although high mobility group box 1 (HMGB1) is adsorbed more on plates with lower SAA, the exposure ratio of cysteine (CYS) residue in HMGB1 is significantly decreased in lower SAA group. The lower exposure of CYS reduces the activation of Toll‐like receptors 4 (TLR4), which down‐regulates the expression of myeloid differentiation factor (Myd88)‐TNF receptor associated factor 6 (TRAF6) to inhibit nuclear factor kappa B (NF‐κB) signaling. Generally, this study reveals the mechanism of how SAA, a nanoscale property, affects FBR from perspective of DAMPs, and provides a new direction for designing better biocompatible implants.
Photogenerated Azido Radical Mediated Oxidation: Access to Carbonyl Functionality from Alcohols, Alkylarenes, and Olefins via Organophotoredox
Authors: Shee Maniklal , Singh N. D. Pradeep 
Published: May 2022

AbstractAzido radical mediated photocatalytic oxidation method for the selective oxidation of various well‐known feedstocks, such as (hetero)aromatic or aliphatic alcohols, alkylarenes, and terminal alkenes, is successfully accomplished. Herein, the catalytic HAT and reversible addition/elimination strategies of azido radical have been explored to convert the commonly oxidizable functionalities into invaluable carbonyls or tertiary alcohols using an organic photocatalyst 4CzIPN with tetrabutyl ammonium azide (TBAN3) and air/O2 as an oxidant. Indeed, this mild, operationally simple, and productive method offers good to excellent product yields with a wide range of structurally diverse substrates, including pharmaceutical derivatives with good functional group tolerance. Several control experiments have been carried out to investigate the detailed reaction mechanism.magnified image
Broadband Spin‐Locked Metasurface Retroreflector
Authors: Tan Qingze , Zheng Bin , Cai Tong , Qian Chao , Zhu Rongrong , Li Xiaofeng , Chen Hongsheng 
Published: May 2022

AbstractRetroreflectors are ubiquitously used in a multitude of applications, such as cloaking, wireless communication, radar, and antenna, owing to their ability to augment the reflected electromagnetic (EM) waves in the incident direction. However, Current metasurface retroreflector designs have yet to mature into a practical method due to the limitations of low efficiency and narrow band, which actually originate from the difficulty in simultaneously engineering phase profiles of certain metasurface at distinct wavelengths. Here, a broadband spin‐locked retroreflector with high efficiency that relies only on a simple metasurface layer is demonstrated. The metasurface is designed with low‐loss dielectric resonators, introducing both the propagation and geometric phases to enable dispersive phase compensation. The results indicate that the proposed metasurface can achieve retroreflection over a broadband spectrum while keeping the spin state identical. Furthermore, a broadband spin‐locked cloak is presented for validation. The work builds up a major advance for practice‐oriented retroreflector and even envision this approach may open new vistas in the very cutting‐edge research of 6G wireless communication network.
Short‐term impacts of cover crops in maritime potato (Solanum tuberosum) systems
Authors: Una Toby M. , McMoran Don , Seefeldt Steven S. , Maupin Brian , Myhre Elizabeth , Griffin‐LaHue Deirdre 
Published: May 2022

AbstractCover cropping is a soil conservation practice widely investigated in agronomic crops, but less is known about cover crop implications in specialty cropping systems, particularly in a high disturbance system like potato (Solanum tuberosum L.). Brassica cover crops are popular in eastern Washington potato production, but brassica seed crop production in western Washington presents issues with use of brassica cover crops in the region's fresh‐market potato systems. To identify winter cover crops compatible with regional restrictions and climatic challenges in western Washington potato systems, trials including a no‐cover control, eight single species (including brassicas, grasses, and legumes), and a grass–legume mixture were conducted in Mount Vernon, WA, in 2018–2019 and 2019–2020. We examined cover crop and weed biomass production, potato yield and quality, and short‐term soil health impacts by measuring permanganate oxidizable carbon (POXC) and inorganic nitrogen before cover crop incorporation and at midseason. Cover crop biomass and weed suppression varied by year, with annual ryegrass (Lolium multiflorum Lam.) producing the most biomass in both years despite poorer weather conditions and reduced cover crop biomass in other treatments in 2020, making it a good cover crop candidate for western Washington. Both POXC and inorganic nitrogen were greater at midseason but did not vary among cover crop treatments, suggesting that temporal variation influences POXC and inorganic nitrogen more than a single winter of cover crops. Potato yield and tuber wireworm damage varied by year, but not across cover crop treatments, and tuber symptoms resembling black scurf did not vary by year nor treatment.
Topological Quantum Phase Transitions of Anisotropic Antiferromagnetic Kitaev Model Driven by Magnetic Field
Authors: Jia Shi‐Qing , Quan Ya‐Min , Zou Liang‐Jian , Lin Hai‐Qing 
Published: May 2022

AbstractThe evolution of quantum spin liquid states (QSL) of the anisotropic antiferromagnetic (AFM) Kitaev model with the [001] magnetic field by utilizing the finite‐temperature Lanczos method (FTLM) is investigated. In this anisotropic Kitaev model with and (K is the energy unit), due to the competition between anisotropy and magnetic field, the system emerges four exotic quantum phase transitions (QPTs) when and , while only two QPTs when . At these magnetic‐field tuning quantum phase transition points, the low‐energy excitation spectrums appear level crossover, and the specific heat, magnetic susceptibility and Wilson ratio display anomalies; accordingly, the topological Chern number may also change. These results demonstrate that the anisotropic interacting Kitaev model with modulating magnetic field displays more rich phase diagrams, in comparison with the isotropic Kitaev model.
Statefinder Analysis of Symmetric Teleparallel Cosmology
Authors: Solanki Raja , Sahoo Pradyumn K. 
Published: May 2022

AbstractStatefinder diagnostics is a convenient method that can differentiate between the various dark energy models. In this article, the statefinder parameters in symmetric teleparallel cosmology are analyzed. The gravity theory is an alternative theory to general relativity where gravitational interactions attribute to the non‐metricity scalar Q. In the present work, two models are considered which contains a linear and a non‐linear form of non‐metricity scalar, specifically, and , where α and β are free parameters and then statefinder parameters are evaluated. The trajectory of the models in the plane are plotted. In addition, the physical behavior of different cosmological parameters such as density, deceleration, and the EoS parameters are analyzed. Further, Om diagnostic is used to differentiate the behavior of both models. It is found that both models predict that the present universe is accelerating due to the dark energy component evolving due to non‐metricity. Moreover, model I represents phantom type behavior while model II follows quintessence scenario.
The impact of fatty acid profile on the physicochemical properties of commercial margarines in Brazil
Authors: Silva Thaís Jordânia , Barrera‐Arellano Daniel , Badan Ribeiro Ana Paula 
Published: May 2022

AbstractThis study aimed to evaluate how lipid profiles affect the physicochemical properties, fatty acid profiles, and nutritional qualities of Brazilian margarines. We analyzed the texture profiles of 13 margarine samples and characterized their fatty acid composition, solid fat content, crystallization kinetics by NMR and thermal behavior by differential scanning calorimetry. The samples had total fat content ranging from 20% to 82% and low trans fatty acid (TFA) levels, except for two samples (5–7% elaidic acid). The fatty acid compositions of all samples showed a predominance of linoleic (23%–46%), oleic (20%–46%), and palmitic acids (7%–14%), indicating that they were formulated with soybean and palm oils. Saturated fat content ranged from 23% to 31%. Compared to the other evaluated samples, those with higher content of lipid and saturated fatty acids (SFAs) exhibited increased hardness and stickiness but reduced spreadability and adhesiveness. The presence of TFAs resulted in increased plasticity of the samples. Reformulation resulted in products with greater SFA levels, which had a negative impact as it increased the atherogenic index (AI: 0.22–0.48). The HF55 sample contained canola oil‐based fat and presented the best nutritional and physical properties. This study is the first to report a complete evaluation of representative margarines, with essential information in reformulating to achieve lower SFA.
Study on the effect of ionic strength on particle migration and deposition in porous media covered by biofilm based on coupled Lattice Boltzmann method and Discrete element method
Authors: Hong Yiqun , Chen Liping , Gong Yanfeng , Wang Shiling , Zhou Yanjie 
Published: May 2022

AbstractBiofilms covering porous media will interact with particles and affect particle migration. In order to investigate the migration mechanism of particles in porous media covered by biofilms, the migration process of particles with different particle sizes under the condition of the changing ionic strength is analyzed by using the lattice Boltzmann method–discrete element method (LBM‐DEM) coupling method from mesoscopic scale. The variation patterns of ion strength include gradient and mutation, respectively. Also, the agglomeration of particles at the pore throat in porous media is investigated under different conditions. The main results are obtained as follows. First, both the change of ionic strength and its changing mode significantly affect the migration behavior of particles in NaCl solution but have little effect on the behavior of particles in CaCl2 solution. Second, when the pressure difference between the pressure difference between the inlet and outlet of porous media is 0.4 kPa, the residual permeability of 1.5‐μm particles in the NaCl solution with ionic strength mutation is the highest, which has value of 64.92%. Third, at the specific flow rate, the particles in low ionic strength solution are more likely to be settled. The attraction of particles in the CaCl2 solution is one order of magnitude less than that in the NaCl solution, and the accumulated particles are more likely to be dispersed.
On the fractional glitch recoveries and pulsar spin properties
Authors: Eze Christian I. , Iyida Evaristus U. , Eya Innocent O. 
Published: May 2022

AbstractPulsar glitches are sudden jumps in the spin frequency of an otherwise steadily spinning down neutron star. A glitch, in many pulsars, is followed by a recovery phase in which the pulsars return fully or partially to the pre‐glitch state on a wide range of time scales. This paper statistically investigates the behavior of the glitch recovery parameter, Q, and its relationship with the pulsar rotational parameters. The Q for the different sub‐classes of the glitch sizes appear to arise from different distributions, suggesting a possible different path of recovery or interior dynamics for the recovery of glitches of different sizes. While the Q has moderate relation with characteristic age, rotational frequency, fractional moment of inertia, and coupling parameter, it shows a very weak correlation with spin‐down rate. The implications are discussed. Glitch and glitch recovery appear to have different underlying physics, but both point to some dynamical changes within the interior of the neutron star.
Asymmetrical sex reversal: Does the type of heterogamety predict propensity for sex reversal?
Authors: Nemesházi Edina , Bókony Veronika 
Published: May 2022

AbstractSex reversal, a mismatch between phenotypic and genetic sex, can be induced by chemical and thermal insults in ectotherms. Therefore, climate change and environmental pollution may increase sex‐reversal frequency in wild populations, with wide‐ranging implications for sex ratios, population dynamics, and the evolution of sex determination. We propose that reconsidering the half‐century old theory “Witschi's rule” should facilitate understanding the differences between species in sex‐reversal propensity and thereby predicting their vulnerability to anthropogenic environmental change. The idea is that sex reversal should be asymmetrical: more likely to occur in the homogametic sex, assuming that sex‐reversed heterogametic individuals would produce new genotypes with reduced fitness. A review of the existing evidence shows that while sex reversal can be induced in both homogametic and heterogametic individuals, the latter seem to require stronger stimuli in several cases. We provide guidelines for future studies on sex reversal to facilitate data comparability and reliability.
Enhancing cereal productivity by genetic modification of root architecture
Authors: Kořínková Nikola , Fontana Irene M. , Nguyen Thu D. , Pouramini Pouneh , Bergougnoux Véronique , Hensel Goetz 
Published: May 2022

AbstractFood security is one of the main topics of today's agriculture, primarily due to increasingly challenging environmental conditions. As most of humankind has a daily intake of cereal grains, current breeding programs focus on these crop plants. Customized endonucleases have been included in the breeders’ toolbox after successfully demonstrating their use. Due to technological restrictions, the main focus of the new technology was on above‐ground plant organs. In contrast, the essential below ground components were given only limited attention. In the present review, the knowledge of the root system architecture in cereals and the role of phytohormones during their establishment is summarized, and the underlying molecular mechanisms are outlined. The review summarizes how the use of CRISPR‐based genome editing methodology can improve the root system architecture to enhance crop production genetically. Finally, future research directions involving this knowledge and technical advances are suggested.
Biomedical applications of three‐dimensional bioprinted craniofacial tissue engineering
Authors: Charbe Nitin Bharat , Tambuwala Murtaza , Palakurthi Sushesh Srivatsa , Warokar Amol , Hromić‐Jahjefendić Altijana , Bakshi Hamid , Zacconi Flavia , Mishra Vijay , Khadse Saurabh , Aljabali Alaa A. , El‐Tanani Mohamed , Serrano‐Aroca Ãngel , Palakurthi Srinath 
Published: May 2022

AbstractAnatomical complications of the craniofacial regions often present considerable challenges to the surgical repair or replacement of the damaged tissues. Surgical repair has its own set of limitations, including scarcity of the donor tissues, immune rejection, use of immune suppressors followed by the surgery, and restriction in restoring the natural aesthetic appeal. Rapid advancement in the field of biomaterials, cell biology, and engineering has helped scientists to create cellularized skeletal muscle‐like structures. However, the existing method still has limitations in building large, highly vascular tissue with clinical application. With the advance in the three‐dimensional (3D) bioprinting technique, scientists and clinicians now can produce the functional implants of skeletal muscles and bones that are more patient‐specific with the perfect match to the architecture of their craniofacial defects. Craniofacial tissue regeneration using 3D bioprinting can manage and eliminate the restrictions of the surgical transplant from the donor site. The concept of creating the new functional tissue, exactly mimicking the anatomical and physiological function of the damaged tissue, looks highly attractive. This is crucial to reduce the donor site morbidity and retain the esthetics. 3D bioprinting can integrate all three essential components of tissue engineering, that is, rehabilitation, reconstruction, and regeneration of the lost craniofacial tissues. Such integration essentially helps to develop the patient‐specific treatment plans and damage site‐driven creation of the functional implants for the craniofacial defects. This article is the bird's eye view on the latest development and application of 3D bioprinting in the regeneration of the skeletal muscle tissues and their application in restoring the functional abilities of the damaged craniofacial tissue. We also discussed current challenges in craniofacial bone vascularization and gave our view on the future direction, including establishing the interactions between tissue‐engineered skeletal muscle and the peripheral nervous system.