bluuebunny/crossref_metadata_2025_split huggingface dataset:
One-pot synthesis of naphtho[1,2-e][1,3]oxazines in the presence of FNAOSiPAMP*/CuII as an almond shell based nanocatalyst
Authors: Keihanfar Mina , Mirjalili Bi Bi Fatemeh 
Published: October 2022

AbstractIn the present research work, a novel catalyst based on natural material, namely, Fe3O4@nano-almondshell@OSi(CH2)3/NHCH2pyridine/CuII abbreviated (FNAOSiPAMP/CuII) was designed and prepared. The properties of the catalyst was identified by Fourier-transform infrared spectroscopy (FT-IR), Thermogravimetry ananlysis (TG), X-ray diffraction (XRD), Energy-dispersive X-ray spectroscopy (EDS), Field emission scanning electron microscopy (FESEM), Transmission electron microscopy (TEM), and Mapping. Furthermore, the evaluation of catalytic activity was done in the course of naphtho-1,3-oxazines synthesis. Solvent-free conditions, simplicity of operation, easy work-up and use of an eco-friendly catalyst are some of advantages of this protocol.
Comparison of ART outcome in patients with poor ovarian response according to POSEIDON criteria
Authors: Lee Hyun Joo , Noh Hye Kyung , Joo Jong Kil 
Published: October 2022

AbstractThe aim of this study is to evaluate whether the patient-oriented strategies encompassing individualized oocyte number (POSEIDON) criteria can reflect the prognosis of controlled ovarian stimulation (COS) by comparing the results of assisted reproductive technologies (ART) between four POSEIDON and normal responder (NR) groups. In total, 225 patients were included in this retrospective observational study. The patients underwent various COS protocols and in vitro fertilization or intracytoplasmic sperm injection, followed by fresh or frozen embryo transfer. Based on their clinical and demographic data, patients were divided into four groups according to the POSEIDON classification, and their ART outcomes were evaluated. Statistical analyses were performed using R version 4.0.5, and a p-value of < 0.05 was considered significant. The NR group had the highest number of total oocytes retrieved and total embryos obtained, as well as the best ART outcome in terms of clinical pregnancy rate ([CPR], 47.6%). The POSEIDON groups 1 and 2 had better COS and ART outcomes than groups 3 and 4 (CPR, 22.6%, 22.1%, 16.7%, and 4.8% in groups 1–4, respectively); the patients in group 3 were younger than those in group 2 by definition, but their CPR was lower than that of patients in group 2. When comparing young and old women with low anti-Müllerian hormone (AMH) levels, the younger group (POSEIDON group 2) had better COS and ART outcomes than their older counterparts, especially POSEIDON group 4. A binary logistic regression adjusted for body mass index (BMI) comparing the ART outcomes of patients that did not get pregnant in the POSEIDON groups compared to the NR group showed odds ratios (ORs) (95% confidence interval) of 2.938 (1.496–5.768), 3.376 (1.848–6.167), 6.801 (2.740–16.881), and 20.497 (8.284–50.713) for groups 1, 2, 3, and 4, respectively. Ovarian reserve still seems to outweigh patients’ age when predicting the ART outcomes of low-responder infertile women, as suggested by the results of POSEIDON groups 2 and 3. However, when there are no differences in ovarian reserve, as in POSEIDON groups 2 and 4, younger women with low AMH have a higher probability of pregnancy than their AMH-matched older counterparts.
Audiovisual Mandarin Lexical Tone Perception in Quiet and Noisy Contexts: The Influence of Visual Cues and Speech Rate
Authors: Li Manhong , Chen Xiaoxiang , Zhu Jiaqiang , Chen Fei 
Published: October 2022

Purpose:
Armed with the theory of embodied cognition proposing tight interactions between perception, motor, and cognition, this study aimed to test the hypothesis that speech rate–altered Mandarin lexical tone perception in quiet and noisy environments could be affected by the bodily dynamic cross-modal information.

Method:
Fifty-three adult listeners completed a Mandarin tone perception task with 720 tone stimuli in auditory-only (AO), auditory–facial (AF), and auditory-facial-plus-gestural (AFG) modalities, at fast, normal, and slow speech rates under quiet and noisy conditions. In AF and AFG modalities, both congruent and incongruent audiovisual information were designed and presented. Generalized linear mixed-effects models were constructed to analyze the accuracy of tone perception across different conditions.

Results:
In Mandarin tone perception, the magnitude of enhancement of AF and AFG cues across three speech rates was significantly higher than that of the AO cue in the adverse context of noise, yet additional metaphoric gestures did not show significant differences from the facial information. Furthermore, the performance of auditory tone perception at the fast speech rate was significantly better than that at the normal speech rate when the inputs were incongruent between auditory and visual channels in quiet.

Conclusions:
This study provided compelling evidence showing that integrated audiovisual information plays a vital role not only in improving lexical tone perception in noise but also in modulating the effects of speech rate on Mandarin tone perception in quiet for native listeners. Our findings, supporting the theory of embodied cognition, are implicational for speech and hearing rehabilitation among both young and old clinical populations.
Preparation and characterisation of tough and porous polyvinyl alcohol/POC membrane for biomedical applications
Authors: Niu Zuoliang , You Ziying , Lu William W. , Wang Zhenming , Wang Chenglin 
Published: October 2022

AbstractPolyvinyl alcohol (PVA) is a synthetic polymer that has been extensively studied for fabricating porous membranes via electrospinning for diverse biomedical applications. However, the poor mechanical properties of electrostatically spun PVA nanofiber membranes severely limit their application in the biomedical field. Therefore, porous, tough hybrid PVA‐based fibrous membranes were prepared by introducing poly (1,8‐octanediol citrate) (POC) into PVA fibrous membranes followed by sodium citrate treatment. The tensile modulus, fracture strength, and fracture toughness of the sodium citrate‐treated PVA/POC (CPP) membranes achieve 119.81 ± 5.32 MPa, 10.34 ± 1.57 MPa and 401.51 ± 11.67 MJ m−2, respectively, which were ∼60, ∼10, and ∼4 times higher than those achieved by the pristine PVA membrane. Moreover, the novel CPP membranes exhibited suitable biodegradation ratios and high cell/issue affinities, suggesting their potential biomedical applications in soft or hard tissue repair. This strategy, which provides porous structures, high mechanical properties and excellent biocompatibility, demonstrates a facile but effective approach for the development of advanced biomaterials.
A hybrid method for day‐ahead photovoltaic power forecasting based on generative adversarial network combined with convolutional autoencoder
Authors: Pan Xueping , Zhou Jieyang , Sun Xiaorong , Cao Yang , Cheng Xiaomei , Farahmand Hossein 
Published: October 2022

AbstractPhotovoltaic (PV) generation has high impact on the decarbonization pathways of power systems. Accuracy of day‐ahead PV power forecasting has become crucial in the operation and control of power system with high PV penetration. This paper develops a hybrid approach based on generative adversarial network (GAN) combined with convolutional autoencoder (CAE) to improve PV power forecasting accuracy. Self‐organizing map method is first utilized as data pre‐processing to classify target days into different weather types based on solar irradiance. With the ability of GAN to reduce the burden of loss and the advantages of CAE to extract multi‐scale effective features from the weather and PV power, PV power forecasting model consisting of GAN and CAE is proposed. The developed method has been tested on a real dataset in a Chinese PV station and compared with base reference PV forecasting methods. Numerical testing results demonstrate the effectiveness of our method with high accuracy.
Modeling the CO outflow in DG Tauri B: Swept-up shells versus perturbed MHD disk wind
Authors: de Valon A. , Dougados C. , Cabrit S. , Louvet F. , Zapata L. A. , Mardones D. 
Published: October 2022

Context. The origin of outflows and their exact impact on disk evolution and planet formation remain crucial open questions. DG Tau B is a Class I protostar associated with a rotating conical CO outflow and a structured disk. Hence it is an ideal target to study these questions.
Aims. We aim to characterize the morphology and kinematics of the DG Tau B outflow in order to elucidate its origin and potential impact on the disk.
Methods. Our analysis is based on Atacama Large Millimeter Array (ALMA) 12CO(2–1) observations of DG Tau B at 0.15″ (20 au) angular resolution. We developed a tomographic method to recover 2D (R,Z) maps of vertical velocity VZ and specific angular momentum j = R × Vϕ. We created synthetic data cubes for parametric models of wind-driven shells and disk winds, which we fit to the observed channel maps.
Results. Tomographic analysis of the bright inner conical outflow shows that both VZ and j remain roughly constant along conical surfaces, defining a shear-like structure. We characterize three different types of substructures in this outflow (arches, fingers, and cusps) with apparent acceleration. Wind-driven shell models with a Hubble law fail to explain these substructures. In contrast, both the morphology and kinematics of the conical flow can be explained by a steady conical magnetohydrodynamic (MHD) disk wind with foot-point radii r0 ≃ 0.7–3.4 au, a small magnetic level arm parameter (λ ≤ 1.6), and quasi periodic brightness enhancements. These might be caused by the impact of jet bow shocks, source orbital motion caused by a 25 MJ companion at 50 au, or disk density perturbations accreting through the wind launching region. The large CO wind mass flux (four times the accretion rate onto the central star) can also be explained if the MHD disk wind removes most of the angular momentum required for steady disk accretion.
Conclusions. Our results provide the strongest evidence so far for the presence of massive MHD disk winds in Class I sources with residual infall, and they suggest that the initial stages of planet formation take place in a highly dynamic environment.
Zahnmedizinische Diagnoseprävalenzen bei Kindern,
Jugendlichen und jungen Erwachsenen mit psychischen Störungen im
Vergleich zu Gesunden-Analyse und Abschätzung kassenärztlicher
Abrechnungsdaten (2019)
Authors: Schmidt Peter , Reis Daniela , Schulte Andreas Gerhard , Fricke Oliver 
Published: October 2022

Zusammenfassung
Ziel Analyse mundgesundheitsbezogener Diagnoseprävalenzen bei
Kindern, Jugendlichen (KiJu), jungen Erwachsenen mit psychischen
Erkrankungen/Verhaltensstörungen (PEVS) und jenen der
Allgemeinbevölkerung in Deutschland anhand von kassenärztlichen
Abrechnungsdaten
Methode Anonym vom ZI (Zentralinstitut) bereitgestellte bundesweite
Abrechnungsdaten (2019) von GKV-Versicherten (0–44 Jahre) wurden
u. a. nach Geschlecht, Altersgruppen sowie ICD-K00-K14-Diagnose
stratifiziert.
Ergebnis Über diese Datenbank wurden keine verlässlichen
mund- bzw. zahngesundheitsbezogenen Aussagen generiert. Laut Datensatz wiesen
unabhängig von einer F-Diagnose 1,8% aller 11.854.384
KiJu-GKV-Versicherten sowie 0,2% der 18–44-Jährigen
(23.348.399 GKV-Versicherte) eine zahn-hartsubstanzbezogene Diagnose
(ICD-10-K02/K03.2) auf. Anhand verfügbarer Literatur zur
Kariesprävalenz von KiJu mit PEVS kann von einer mittleren ungewichteten
Prävalenz von 51% ausgegangen werden. Daran und der
F-Diagnoseprävalenz bei KiJu im Jahr 2017 orientierend, müssten
geschätzt 957.952 (Abb. 1) KiJu
mit einer PEVS auch eine Zahnkaries aufweisen.
Schlussfolgerung Die Kennzahlen mundgesundheitsbezogener,
ärztlicher Diagnoseprävalenzen bei Personen der
Allgemeinbevölkerung und Altersgenossen mit PEVS sind sehr gering.
Offensichtlich werden zahnbezogene Diagnosen von u. a. Haus- und
Kinderärzten nur äußerst selten vergeben. Die vorhandene
Literatur sowie klinische Erfahrung zeigen, dass diese kassenärztlichen
Abrechnungsdaten nicht geeignet sind die Zahngesundheit der Personengruppen
realistisch abzubilden. Somit ist für die Vernetzung, die Verbesserung
der Versorgungsforschung und Versorgung, z. B. von Subgruppen der
Gesellschaft, eine interprofessionelle zahn-/ärztliche,
datenschutzkonforme Zentraldatenbank anzustreben.
The Lateral Malleolus Is a Simple and Reliable Landmark that Can Be Used to Reliably Perform Restricted Kinematically Aligned Total Knee Arthroplasty—Anatomical and Clinical Studies in Japanese Population
Authors: Hiranaka Takafumi , Jackson William F. M. , Fujishiro Takaaki , Suda Yoshihito , Araki Shotaro , Kamenaga Tomoyuki , Koide Motoki , Okamoto Koji 
Published: October 2022

AbstractIn restricted kinematic alignment total knee arthroplasty (TKA), bone resection is performed within a safe range to help protect against failure from extreme alignments. Patient-specific instrumentation, navigations, and robotics are often required for restricting bone cuts within a specified safe zone. We hypothesized that the lateral malleolus could be used as a landmark for restricting the tibial osteotomy using a mechanical jig. Here, we examine its feasibility in anatomical and clinical settings. We studied long-leg standing radiographs of 114 consecutive patients (228 knees) who underwent knee arthroplasty in our institution. We measured the lateral malleolus angle (LMA), the angle between the tibial axis and the line between the center of the knee and the lateral surface of the lateral malleolus. The medial proximal tibial angle was also measured before and after restricted kinematic alignment TKA under restriction with reference to the lateral malleolus. Mean LMA was 5.5 ± 0.5 degrees. This was relatively consistent and independent of patient's height, weight, and body mass index. The lateral malleolus is a reliable bone landmark that can be used to recognize approximately 5.5 degrees of varus intraoperatively. A surgeon can use this as a restriction of the tibial varus cut up to 6 degrees without the requirement for expensive assistive technologies.
Use of Grafts on an Open Gap Is Advantageous for Preventing Correction Loss in 1-Week Staged Bilateral Open-Wedge High Tibial Osteotomies
Authors: Yoon Kyoung Ho , Song Sang Jun , Hwang Sung Hyun , Jung Cheol Hyun , Park Cheol Hee 
Published: October 2022

AbstractOne-week staged bilateral open-wedge high tibial osteotomies (OWHTOs) can be a safe procedure, with the added advantage of fast functional recovery, cost saving, and reduced hospital stay. However, there can be concerns about correction loss after 1-week staged OWHTOs because high loading is inevitably applied to osteotomy sites during postoperative weight bearing. Although leaving the osteotomy site with no grafts is possible in OWHTOs, the use of grafts can provide additional stability to the osteotomy site and prevent correction loss. We compared the amount and incidence of correction loss between 1-week staged bilateral OWHTOs with and without allogenic bone grafts. Seventy-five patients who underwent 1-week staged bilateral OWHTOs with a locking spacer plate (Nowmedipia, Seoul, Korea) by a single surgeon were retrospectively reviewed. Allogenic cancellous bone grafts were applied in 53 patients (group G; 106 knees, operated consecutively between 2012 and 2017) but not in 22 patients (group N; 44 knees, operated consecutively between 2017 and 2019). Demographics were similar between the groups. Radiographically, the mechanical axis (MA), medial proximal tibial angle (MPTA), and posterior tibial slope (PTS) were evaluated preoperatively and within 1 year postoperatively. Unstable hinge fracture was investigated using computed tomography in all cases. The incidence of correction loss (MPTA loss ≥ 3 degrees) was determined. There were no significant differences in the MA, MPTA, and PTS between the groups preoperatively and 2 weeks postoperatively. The incidence of unstable hinge fractures did not differ. The losses in MA, MPTA, and PTS during the first postoperative year were significantly greater in group N than in group G (MA, −5.5 vs. −2.3 degrees; MPTA, −3.0 vs. 0 degrees; PTS, −2.0 vs. −0.7 degrees; p < 0.05 on all parameters). The correction loss incidence was 6.6% (7/106) and 31.8% (14/44) in groups G and N, respectively (p < 0.001). Appropriate treatment is necessary to prevent correction loss in 1-week staged bilateral OWHTOs. Grafting, which provides additional stability to the osteotomy site, is a recommended method. Level of evidence is IV.
Perinatal Testicular Torsion in Northern Ireland: A Nationwide 10-Year Review
Authors: Alchoikani Nasib , MacCormack Brian , Marshall David 
Published: October 2022

Abstract
Introduction Perinatal or neonatal testicular torsion (PTT) is defined as testicular torsion within the first 30 days of life. PTT is a rare event, and bilateral PTT is even rarer. However, recent articles have advocated emergency bilateral exploration to exclude the catastrophic possibility of asymptomatic contralateral testicular torsion leading to anorchia. The aim of this study is to evaluate PTT in Northern Ireland (NI) using a nationwide population-based retrospective observational study.
Methods All boys in NI who underwent emergency scrotal exploration within their first 30 days of life for possible testicular torsion over a 10-year period (January 2010–December 2019 inclusive) were included. Intraoperative findings primarily evaluated included diagnosis and presence of synchronous or asynchronous (metachronous) contralateral testicular torsion. Secondary outcomes included correlation between intraoperative findings and any preoperative ultrasound scan (USS), and scrotal examination findings during postoperative outpatient follow-up.
Results A total of 19 patients who underwent emergency scrotal exploration in the study period were included. An intraoperative finding confirming the diagnosis of PTT was reported in 14 (73.7%) patients. The incidence of PTT was calculated as 11.3 per 100,000 per male live births in NI, with bilateral PTT accounting for two patients (14.2% of all PTTs), divided equally between synchronous and asynchronous PTTs. Of two affected testes where preservation was felt appropriate intraoperatively, only one was still palpable at follow-up, producing a testicular salvage rate after PTT of only 7.1%. Testicular findings on preoperative USS were confirmed intraoperatively in five out of six patients, producing a concordance rate of 83.3%.
Conclusion This is the first nationwide population-based study to calculate more accurately the incidence of PTT, and bilateral synchronous and asynchronous bilateral PTTs, all of which seem to be significantly higher than previously estimated. However, in keeping with previous reports, this study confirms the poor salvage rate of testes undergoing perinatal torsion, and suboptimal concordance between preoperative USS findings and intraoperative diagnosis.
High-resolution fiber imaging for pulsed power experiments
Authors: Fulford K. W. , Yager-Elorriaga D. A. , Patel S. , Montoya M. M. , Chandler K. , Gilmore M. A. 
Published: October 2022

This work presents a novel approach for imaging the visible emissions from plasmas in pulsed power experiments using high-resolution plastic optical fibers. The diagnostic consists of a 2 mm diameter core commercial cable constructed of 13 000 individual acrylic fibers. The fibers are fused together to create a single high-resolution bundle. Different designs were investigated to cover a wide range of resolutions and fields of view (3–700 µm and 0.05–45 mm, respectively). The system was tested on the 1-MA Mykonos accelerator at Sandia National Laboratories and successfully imaged visible emission from a hybrid x-pinch target. Diagnostic development and preliminary results are presented.
From adverb to intensifier
Authors: Pastuch Magdalena , Mitrenga Barbara , Wąsińska Kinga 
Published: October 2022

Abstract
This paper aims is to analyse the status of selected Polish words: okrutnie (‘cruelly’), strasznie (‘terribly’) and szalenie (‘madly’). These units are traditionally considered to be adverbs, and their formal structure and original meaning indicate derivation from proper adjectives. We presume that adverbs might develop into intensifiers, which are semantically close to bardzo (‘very’). By analysing the linguistic material extracted from chronologically differentiated corpora of Polish (korba, kf19 and nkjp), we want to show how this linguistic process has been evolving over the centuries. Our research examines quantitative and qualitative collocational data of okrutnie, strasznie and szalenie with their categorical value and semantic evaluation (positive, neutral and negative). Our research reveals that the changing of words’ meaning, and their syntactic function, switched from the object language to the metalanguage level, is a feature associated with grammaticalization. We used a statistical chi-square test to verify the probability of word co-occurrence.
Employing retrospective process tracing in an international exploratory study
Authors: Gumul Ewa , Herring Rachel E. 
Published: October 2022

Abstract
This paper reports on a RPT study which employed an adapted version of the three-stage method used by Herring (2018). The same stimulus and method were employed with two distinct populations
(experienced medical interpreters in the USA and student interpreters in Poland), with the aim of refining RPT methods and
exploring the feasibility of their use in multi-researcher, multi-site studies. The authors discuss the process of developing and
carrying out a study design and procedure for use by two researchers across two sites and with two populations, critically address
the effectiveness of the use of the method & procedure by two researchers, and discuss recommendations for future studies
employing similar designs and methods. The paper also presents preliminary analysis of the RPT data gathered as part of the study
and suggests avenues for further research.
Observation of oscillatory Raman gain associated with two-photon Rabi oscillations of nanofiber-coupled atoms
Authors: Liedl Christian , Pucher Sebastian , Schneeweiss Philipp , Yatsenko Leonid P , Rauschenbeutel Arno 
Published: October 2022

Abstract
Quantum emitters with a Λ-type level structure enable numerous protocols and applications in quantum science and technology. Understanding and controlling their dynamics is, therefore, one of the central research topics in quantum optics. Here, we drive two-photon Rabi oscillations between the two ground states of cesium atoms and observe the associated oscillatory Raman gain and absorption that stems from the atom-mediated coherent photon exchange between the two drive fields. The atoms are efficiently and homogeneously coupled with the probe field by means of a nanofiber-based optical interface. We study the dependence of the two-photon Rabi frequency on the system parameters and observe Autler–Townes splitting in the probe transmission spectrum. Beyond shedding light on the fundamental processes underlying two-photon Rabi oscillations, our method could also be used to investigate (quantum) correlations between the two drive fields as well as the dynamical establishment of electromagnetically induced transparency.