bluuebunny/crossref_metadata_2025_split huggingface dataset:
Accessibility of care plan information from previous treatment setting in palliative care unit: A qualitative study
Authors: Kuusisto Anne , Saranto Kaija , Korhonen Päivi , Haavisto Elina 
Published: August 2022

AbstractAimTo describe accessibility of care plan information from patients' previous treatment setting in palliative care.DesignA qualitative descriptive study.MethodsA total of 33 nurses, social workers and physicians were interviewed. Data were analysed by deductive and inductive content analysis. The Fit between Individuals, Task and Technology (FITT) framework was used as a deductive analysis framework.ResultsIndividual‐task Fit was described in relation to professional‐specific care plan information in palliative care and use of time to obtain care plan information. Individual‐technology Fit was described in relation to health informatics competencies and HIS usability. Task‐technology Fit was described in relation to interoperability between care settings and healthcare providers and lack of interoperability between care settings and healthcare providers.Relevance to clinical practiceThe study confirms the need to review the HIS as a whole from a holistic and patient‐oriented perspective to ensure the continuity of palliative care.
Analysis of hope level and its influencing factors in patients with decompensated cirrhosis
Authors: Zhang Yuanyuan , Xie Ling , Li Fen , Huo Chunyan , Miao Yanling , Wang Lining , Ding Caiyan 
Published: August 2022

AbstractAimThe aim of this study was to examine hope level and its influencing factors in patients with decompensated liver cirrhosis.DesignA prospective observational study.MethodsWe selected 93 patients with decompensated liver cirrhosis from a Chinese university hospital based on the inclusion and exclusion criteria. A general information questionnaire and Herth Hope Index were used, and multiple linear regression identified factors associated with the patients' hope level.ResultsThe participants' average hope level was 32.01 ± 6.14 (moderate). The hope score's highest and lowest dimensions were “interconnectedness” (11.29 ± 2.17) and “temporality and future” (10.12 ± 2.28), respectively. Multiple linear regression showed that education level and monthly per capita income were independent influencing factors (p < .05). These variables explained 38.3% of the variation in hope.ConclusionThe participants' hope level was not optimal. Thus, medical staff should pay special attention to patients with low education level and poor economic status, and guide them to adopt a positive attitude.
Pre‐ and post‐stroke oral antithrombotics and mortality in patients with ischaemic stroke
Authors: García Rodríguez Luis A. , Gaist David , Balabanova Yanina , Brobert Gunnar , Sharma Mike , Cea Soriano Lucía 
Published: August 2022

AbstractBackgroundReducing stroke occurrence requires the effective management of cardiovascular and other stroke risk factors.PurposeTo describe pre‐ and post‐stroke medication use, focusing on antithrombotic therapy and mortality risk, in individuals hospitalised for ischaemic stroke (IS) in the United Kingdom.MethodUsing primary care electronic health records from the United Kingdom, we identified patients hospitalised for IS (July 2016–September 2019) and classed them into three groups: atrial fibrillation (AF) diagnosed pre‐stroke, AF diagnosed post‐stroke, and non‐AF stroke (no AF diagnosed pre‐/post‐stroke). We determined use of cardiovascular medications in the 90 days pre‐ and post‐stroke and calculated mortality rates.ResultsThere were 3201 hospitalised IS cases: 76.2% non‐AF stroke, 15.7% AF pre‐stroke, and 8.1% AF post‐stroke. Oral anticoagulant (OAC) use increased between the pre‐ and post‐stroke periods as follows: 54.3%–78.7% (AF pre‐stroke group), 2.3%–84.8% (AF post‐stroke group), and 3.4%–7.3% (non‐AF stroke group). Corresponding increases in antiplatelet use were 30.8%–35.4% (AF pre‐stroke group) 38.5%–47.5% (AF post‐stroke group), and 37.5%–87.3% (non‐AF stroke group). Among all IS cases, antihypertensive use increased from 66.8% pre‐stroke to 78.8% post‐stroke; statin use increased from 49.6%–85.2%. Mortality rates per 100 person‐years (95% CI) were 17.30 (14.70–20.35) in the AF pre‐stroke group and 9.65 (8.81–10.56) among all other stroke cases.ConclusionOur findings identify areas for improvement in clinical practice, including optimising the level of OAC prescribing to patients with known AF, which could potentially help reduce the future burden of stroke.
Ancient plastid genomes solve the tree species mystery of the imperial wood “Nanmu” in the Forbidden City, the largest existing wooden palace complex in the world
Authors: Jiao Lichao , Lu Yang , Zhang Ming , Chen Yongping , Wang Zhaoshan , Guo Yu , Xu Chao , Guo Juan , He Tuo , Ma Lingyu , Gao Wenqiang , Wang Jie , Zhou Shiliang , Zhang Yonggang , Jiang Xiaomei , Baas Pieter , Yin Yafang 
Published: August 2022

Societal Impact StatementCombining natural and social science approaches to conduct archeological research on wooden cultural relics is important for exploring major aspects of ancient civilizations. The Forbidden City in Beijing, China, is the largest existing wooden palace complex in the world. We examined ancient DNA of imperial wood “Nanmu” specimens taken from representative structural components of the Forbidden City, in order to provide a new perspective on the long‐standing dispute about its species. This allowed us to accurately identify and properly restore these wooden artifacts and improved our understanding of the past interactions between plant distribution, forest resources, and human activities.Summary

Exploring the life styles and production methods of past generations using plant resources can help us to improve our understanding of human civilization. Nanmu, known for its high wood quality, was exclusively used for imperial palace construction in the 15th–19th centuries in China, yet its species has been a subject of long‐standing debate.
Here, we revisit this unresolved problem, using morphology and ancient DNA (aDNA) to analyze 21 centuries‐old Nanmu specimens sampled from representative palaces of the Forbidden City.
Cytochemical staining demonstrated that endogenous aDNA sporadically occurs in the wood ray parenchyma cells of Nanmu specimens. High‐quality plastid genomes were retrieved from archeological woods for the first time via an aDNA capture method, with 90%–100% coverage (137,663–152,805 bp) and sequence depths of 27.05‐ to 1409.94‐fold. Utilizing these ancient genomes, our results demonstrate that Phoebe zhennan and Phoebe hui are most likely the main species of Nanmu in the Forbidden City.
This finding diverges from the prevailing view that Nanmu encompasses woods from the whole genus Phoebe and even its close relative Machilus. It also shows that stringent criteria were used when selecting construction materials for the Forbidden City. By combining morphological traits with aDNA analyses, we provide a new solution for identifying the species of timber used for ancient architecture, and we increase our understanding of the way in which forest resources were recognized and utilized by our ancestors despite the lack of a plant taxonomic framework in ancient times.
Computational Modelling and Optimization of a Methylammonium‐free Perovskite and Ga‐free Chalcogenide Tandem Solar Cell with an Efficiency above 25 %
Authors: Kumar Anjan , Singh Sangeeta , Pandey Rahul 
Published: August 2022

AbstractMulti‐junction solar cells connecting two or more cells with significantly different bandgaps have a lot of promise for exceeding the Shockley Queisser (S‐Q) efficiency limit of single‐junction‐based photovoltaic devices. In this article, a new class of tandem devices has been proposed and investigated for improved efficiencies. The proposed tandem cell is connected in monolithic two‐terminal tandem configurations with wide bandgap formamidinium (FA) based perovskite absorber (FA0.85 Cs0.15 Pb (I0.85 Br0.15)3) (1.6 eV) (Cs15/Br15)) on the top cell and low bandgap gallium free chalcogenide (CuInSe2) absorber on the bottom cell. Doped FA‐based perovskite material is preferred over commonly used FAPbI3 as it is a proven fact that adding modest quantities of cesium and bromine stabilizes the optically active black phase of FAPbI3 Perovskite and increases overall device performance. In contrast, bottom CuInSe2 (CIS) absorber material is selected considering its good thermal stability and excellent light‐absorbing capabilities in a broad‐spectrum range. The feasibility of the suggested tandem configuration is assessed in two steps. First, a 1.6 eV perovskite top cell is simulated and calibrated to suit the state‐of‐the‐art power conversion efficiency of 17.5 %, followed by a 1.04 eV CuInSe2‐based bottom cell with a calibrated efficiency of 16.2 %. Both devices are tested for tandem configuration once the standalone (top and bottom) subcells have been calibrated. At varied absorber thicknesses in both the top and bottom subcells, the current matching conditions are achieved. At optimal thicknesses of 700 nm and 590 nm for the bottom and top absorbers, respectively, the overall tandem structure obtained an excellent power conversion efficiency of 25.13 %. Results reported in this study may pave the way for the development of high‐efficiency perovskite/CIS based tandem solar cells in the future.
Magnetic Biochar Composites Modified with Branched Polyethyleneimine for Highly Efficient Cr(VI) Removal from Water
Authors: Niu Jiaojiao , Cui Can , Zhang Yu , Zhang Li , Li Hongxiong , Zhang Ying , Hu Hailiang , Zhang Jianhui , Xie Yadian 
Published: August 2022

AbstractIn this study, a set of branched polyethyleneimine (BPEI) modified magnetic biochar composites (BPEI500‐MBC, BPEI1800‐MBC and BPEI20000‐MBC) were successfully prepared for capturing Cr(VI) from water solution. The results of the adsorption experiment showed that the adsorption capacity obeyed the sequence of BPEI500‐MBC<BPEI1800‐MBC<BPEI20000‐MBC. The theoretical maximum adsorption capacity of BPEI20000‐MBC calculated by Langmuir model reached 202.71 mg g−1 at 298 K. The adsorption kinetics followed the pseudo‐second‐order kinetics and the intra‐particle diffusion models, and the adsorption isotherm was fitted with the Freundlich adsorption isotherm model. Furthermore, the adsorption thermodynamics calculations proved that the adsorption was a spontaneous endothermic process. The electrostatic attraction between Cr(VI) and the protonated imidazole N+ of BPEI‐MBC played a key role in Cr(VI) adsorption process, accompanied by complexation and partly Cr(VI) was reduced to Cr(III). The adsorption capacity of BPEI20000‐MBC was still remained above 86.87 % after five adsorption‐desorption cycles. Hence, BPEI20000‐MBC is predicted to be an effective adsorbent for removing Cr(VI) and other heavy metal ions from water solution.
Dicationic Imizadolium‐Based Tetrafluoroborate Ionic Liquids: Synthesis and Hydrothermal Stability Study
Authors: Xu Chenqian , Cheng Zhenmin 
Published: August 2022

AbstractSix novel dicationic imizadolium‐based tetrafluoroborate ionic liquids were synthesized, with four of which contained hydroxyl groups. Their chemical structures were identified by FTIR and 1H NMR, and their onset decomposition temperatures (Tonset) were measured by thermogravimetric analysis (TGA). For investigating the hydrothermal stability, all DILs were mixed with water and heated for 1, 5, and 9 hours to 240 °C in an airtight kettle.The results show that DILs with hydroxyls have a higher Tonset but they exhibit evident changes in chemical structures after heating with water for 9 hours. The conflicts between Tonset and long‐term stability tests is ascribed to the reason that water forms new hydrogen bonds with hydroxyls and therefore weakens the intramolecular interaction between the cation and anion.
Blue Luminescent Glutathione‐protected Copper Nanoclusters for Selective Detection of Barbaloin
Authors: Zhang Shen , Cui Rumiao , Zhao Qingkai , Guo Yuyu 
Published: August 2022

AbstractBased on the importance of barbaloin (Bar), development of efficient sensing methods in barbaloin detection has remarkable function and practical significance. In this work, copper nanoclusters (Cu NCs) with good water‐soluble character were prepared by one‐pot way and successfully used for selective detection of barbaloin. The stable probe with uniform size was protected by glutathione (GSH) and reduced by ascorbic acid (AA). Intriguingly, fluorescence of GSH−Cu NCs was quenched by barbaloin. The static quenching and inner filter effect (IFE) was supposed to main quenching mechanism. Furthermore, GSH−Cu NCs could well distinguish barbaloin from possible interferes and exhibited linear relationship of barbaloin concentrations from 3 to 100 μM. Significantly, satisfactory recovery experiments were successfully operated in bovine serum samples for barbaloin sensing. This probe with superior fluorescence properties provided better choice for barbaloin detection.
Giant g‐factor in Self‐Intercalated 2D TaS2
Authors: Wang Ziying , Wang Zishen , Zhou Xin , Fu Wei , Li Haohan , Liu Chaofei , Qiao Jingsi , Quek Su Ying , Su Chenliang , Feng Yuanping , Loh Kian Ping 
Published: August 2022

AbstractCentral to the application of spintronic devices is the ability to manipulate spins by electric and magnetic fields, which relies on a large Landé g‐factor. The self‐intercalation of layered transitional metal dichalcogenides with native metal atoms can serve as a new strategy to enhance the g‐factor by inducing ferromagnetic instability in the system via interlayer charge transfer. Here, scanning tunneling microscopy (STM) and scanning tunneling spectroscopy (STS) are performed to extract the g‐factor and characterize the electronic structure of the self‐intercalated phase of 2H‐TaS2. In Ta7S12, a sharp density of states (DOS) peak due to the Ta intercalant appears at the Fermi level, which satisfies the Stoner criteria for spontaneous ferromagnetism, leading to spin split states. The DOS peak shows sensitivity to magnetic field up to 1.85 mV T−1, equivalent to an effective g‐factor of ≈77. This work establishes self‐intercalation as an approach for tuning the g‐factor.
Covalent Functionalization of Antimonene and Bismuthene Nanosheets
Authors: Ayyub Mohd Monis , Barua Manaswee , Acharya Shashidhara , Rao Chintamani Nagesa Ramachandra 
Published: August 2022

AbstractAntimonene and bismuthene are promising members of the 2D pnictogen family with their tunable band gaps, high electronic conductivity, and ambient stability, making them suitable for electronic and optoelectronic applications. However, semi‐metal to semiconductor transition occurs only in the mono/bilayer regime, limiting their applications. Covalent functionalization is a versatile method for tuning materials’ chemical, electronic, and optical properties and can be explored for tuning the properties of pnictogens. In this work, emissions in liquid exfoliated antimonene and bismuthene are observed at ≈2.23 and ≈2.33 eV, respectively. Covalent functionalization of antimonene and bismuthene with p‐nitrobenzene diazonium salt proceeds with the transfer of lone pairs from Sb/Bi to the diazonium salt, introducing organic moieties on the surface attached predominantly via Sb/BiC bonds. Consequently, Sb/Bi signatures in Raman and X‐ray photoelectron spectra are blue‐shifted, implying lattice distortion and charge transfer. Interestingly, emission can be tailored upon functionalization to 2.18 and 2.27 eV for antimonene and bismuthene respectively, and this opens the possibility of tuning the properties of pnictogens and related materials. This is the first report on covalent functionalization of antimonene and bismuthene. It sheds light on the reaction mechanism on pnictogen surfaces and demonstrates tunability of optical property and surface passivation.
Protein supplement potential of Dodonaea angustifolia leaves by replacing atella on nutrient utilization and performance of Farta sheep fed natural pasture hay basal diet
Authors: Teshager Defaru , Mekuriaw Yeshambel , Beyero Netsanet 
Published: August 2022

AbstractBackgroundProtein feed resources for ruminant animal productions are deficit in Ethiopia.ObjectivesTo evaluate the supplementation effects of dried Dodonaea angustifolia leaves (DDL), dried traditional brewery by‐product locally called atella and their mixtures on nutrient utilization and growth performance of Farta sheep fed natural pasture hay (NPH) as basal diet.MethodsTwenty‐five yearling intact male Farta sheep with average initial body weight of 14.53 ± 1.35 kg (mean ± SD) were used for the study. The experimental sheep were allocated into five blocks of five animals based on their initial body weight. The experiment lasted for 90 days of feeding trial followed by 7 days of digestibility trial. The experimental feeds were NPH ad libitum + 100% DDL + 100 g wheat bran (WB; T1), NPH ad libitum + 75% DDL + 25% dried atella + 100 g WB(T2), NPH ad libitum + 50% DDL + 50% deried atella + 100 g WB (T3), NPH ad libitum + 25% DDL +75% dried atella +100 g WB (T4) and NPH ad libitum + 100% dried atella + 100 g WB (T5).ResultsNPH, DDL and dried atella contained 7.42, 15.39, 21.13% crude protein (CP) and 66, 36, 34% neutral detergent fiber, respectively. Sheep supplemented with increasing level of atella had more dry matter intake (DMI) and crude protein intake (CPI) and the highest of these DMI and CPI were in T5 (868 g/d for dry matter and 113 g/d for CP). This progressive increased CPI from T1 up to T5 was reflected in a significant (p < 0.001) fibers and estimated metabolizable energy intake in the order of T5 > T4 > T3 > T2 > T1. Significant difference (p < 0.001) was recorded on nutrient utilization and the highest was for T5 and lowest for T1. Average daily gain (ADG) and feed conversion efficiency (FCE) were significantly (p < 0.001) increased as the atella inclusion level increased. Sheep in T4 and T5 had the highest ADG and FCE with the order of T5 = T4 > T3 > T2 > T1. ADG was correlated positively and highly significant with nutrients intake and digestibility.ConclusionAtella supplementation better than DDL and then their mixture (T2–T4) supplementation could be recommended in sheep fattening in the study area.
Removal of malignant melanophoroma with intramuscular invasion in a bowfin fish (Amia calva)
Authors: Heniff Ashlyn C. , Lewbart Gregory A. , Applegate Jeffrey R. 
Published: August 2022

AbstractA mature male bowfin fish (Amia calva) presented with a left‐sided lateral caudoventral coelomic swelling. Diagnostic imaging (computed tomography and ultrasound) revealed a focal, expansile muscular mass measuring 6.4 × 3.8 cm in diameter and contiguous with the musculature of the left body wall at the level of the pelvic fin. The mass was surgically excised. Histopathology categorized the mass as a malignant melanophoroma. The patient made a full recovery and lived 4 additional years. The patient died from unrelated causes, and necropsy revealed no evidence of recurrence of neoplasia. This is the first documentation of surgical treatment of a melanophoroma inA calva.
Tumor microenvironment‐regulating nanomedicine design to fight multi‐drug resistant tumors
Authors: Xu Qinqin , Lan Xinyue , Lin Huimin , Xi Qiye , Wang Manchun , Quan Xiaolong , Yao Guangyu , Yu Zhiqiang , Wang Yongxia , Yu Meng 
Published: August 2022

AbstractThe tumor microenvironment (TME) is a very cunning system that enables tumor cells to escape death post‐traditional antitumor treatments through the comprehensive effect of different factors, thereby leading to drug resistance. Deep insights into TME characteristics and tumor resistance encourage the construction of nanomedicines that can remodel the TME against drug resistance. Tremendous interest in combining TME‐regulation measurement with traditional tumor treatment to fight multidrug‐resistant tumors has been inspired by the increasing understanding of the role of TME reconstruction in improving the antitumor efficiency of drug‐resistant tumor therapy. This review focuses on the underlying relationships between specific TME characteristics (such as hypoxia, acidity, immunity, microorganisms, and metabolism) and drug resistance in tumor treatments. The exciting antitumor activities strengthened by TME regulation are also discussed in‐depth, providing solutions from the perspective of nanomedicine design.This article is categorized under:
Therapeutic Approaches and Drug Discovery > Emerging Technologies
Therapeutic Approaches and Drug Discovery > Nanomedicine for Oncologic Disease
Nanotechnology Approaches to Biology > Nanoscale Systems in Biology
Pilot testing of an adaptive, individualized inhibitory control training for binge drinking: first evidence on feasibility, acceptance, and efficacy
Authors: Reichl Daniela , Enewoldsen Niklas , Müller Astrid , Steins-Loeber Sabine 
Published: August 2022

Abstract
Background
Deficits in inhibitory control seem to promote habit behavior and therefore play an important role in the development and maintenance of addictive diseases. Although several training approaches have been suggested, there is a considerable lack of knowledge about the best way to improve inhibitory control. Based on a literature review regarding shortcomings of existing trainings, an individualized, adaptive inhibitory control training was developed. We aimed to assess feasibility and acceptance of this training and to provide preliminary results on its efficacy regarding inhibitory control and binge drinking.

Methods
Sixty-one individuals (30 female) with binge drinking behavior were randomly allocated to either an experimental group receiving three sessions of the inhibitory control training or a waitlist control group receiving no training. Before and after the training, the participants performed a Go/NoGo task to assess inhibitory control (commission errors and false reaction time), completed a questionnaire on drinking-related self-control, and reported drinking behavior.

Results
Although the training was feasible and accepted by participants, it did not affect self-control over drinking, inhibitory control or drinking behavior. The relationship between session number and false reaction time was linear for alcohol stimuli, but squared for neutral stimuli.

Conclusion
Although our findings have to be interpreted in the light of some shortcomings, they demonstrate that further research is needed to enhance our understanding of how to improve inhibitory control and which factors might moderate this process.
Kann die Psychoanalyse noch aus ihren Krisen lernen?
Authors: Buchholz Michael B. 
Published: August 2022

ZusammenfassungMit dem neuen Psychotherapeutengesetz ist eine ernste Lage für die Psychoanalyse entstanden. Auf die eine Gefahr, die technologische Medizinalisierung (Buchholz 2017b, c; Buchholz und Kächele 2019), wurde häufig verwiesen. Eine wachsende Abhängigkeit von der klinischen Psychologie (Slunecko 2021) ist noch wenig gesehen. Wie kann sich die Psychoanalyse behaupten? Vorgeschlagen wird, sich verstärkt Fragen nach a) Ausbildung therapeutischer Persönlichkeiten, b) stärkerer lebensweltlicher Kontextualisierung und c) weit größerer Aufmerksamkeit der originalen Stimme der Patienten in Theorie und Kasuistik zu widmen. Loyalität gegenüber Theorie-Traditionen löst keine Probleme. Sie blockiert Umweltsensitivität und erzeugt Rückzug in Selbstbeschäftigung und beunruhigenden Mangel an Irritierbarkeit. Die viel zu loyale Bindung an Theorietraditionen, an lehranalytische Aus- und Vorbilder, supervisorische Praktiken und an fragliche Behandlungsregeln wehrt die Irritation ab, deren Bewältigung zentrale Aufgabe wäre, und entmutigt die nächste Generation. Dazu am Schluss Vorschläge.