bluuebunny/crossref_metadata_2025_split huggingface dataset:
Landslide susceptibility assessment in the rocky coast subsystem of Essaouira, Morocco
Authors: Khouz Abdellah , Trindade Jorge , Oliveira Sérgio C. , El Bchari Fatima , Bougadir Blaid , Garcia Ricardo A. C. , Jadoud Mourad 
Published: November 2022

Abstract. In recent decades, multiple researchers have produced landslide susceptibility maps using different techniques and models, including the
information value method, which is a statistical model that is widely
applied to various coastal environments. This study aimed to evaluate
susceptibility to landslides in the Essaouira coastal area using bivariate
statistical methods. In this study, 588 distinct landslides were identified, inventoried, and mapped. Landslides are performed by
means of observation and interpretation of different data sources, namely high-resolution satellite images, aerial photographs, topographic maps, and extensive field surveys. The rocky coastal system of Essaouira is located in the middle of the Atlantic coast of Morocco. The study area was split into 1534 cliff terrain units that were 50 m in width. For training and validation purposes, the landslide inventory was divided into two independent groups: 70 % for training and 30 % for validation. Twenty-two layers of landslide conditioning factors were prepared – namely, elevation, slope angle, slope aspect, plan curvature, profile curvature, cliff height, topographic wetness index, topographic position index, slope over area ratio, solar radiation, presence of faulting, lithological units, toe lithology, presence and type of cliff toe protection, layer tilt, rainfall, streams, land-use patterns, normalised difference vegetation index, lithological material grain size, and presence of springs. The statistical relationship between the conditioning factors and the different landslide types was calculated using the bivariate information value method in a pixel-based model and in the elementary terrain units-based model. Coastal landside susceptibility maps were validated using landslide training group partitions. The receiver operating characteristic curve and area under the curve were used to assess the accuracy and prediction capacity of the different coastal landslide susceptibility models. Two methodologies, considering a pixel-based approach and using coastal terrain units, were adopted to evaluate coastal landslide susceptibility. The results allowed for the classification of 38 % of the rocky coast subsystem as having high susceptibility to landslides, which were mostly located in the southern part of the Essaouira coastal area. These susceptibility maps will be useful for future planned development activities as well as for environmental protection.
Pengaruh Pengetahuan Pajak dan Sanksi Pajak terhadap Kepatuhan Wajib Pajak Orang Pribadi Dengan Preferensi Resiko sebagai Variabel Moderasi (Studi pada Kantor Pelayanan Pajak Pratama Jayapura)
Authors: Hutadjulu Linda Yuliani , Larasati Rudiawie 
Published: November 2022

Penelitian ini bertujuan untuk menguji pengaruh pemahaman dan sanksi perpajakan terhadap kepatuhan wajib pajak dengan preferensi risiko sebagai variabel moderasi (studi pada KPP Jayapura). Penelitian ini merupakan penelitian kuantitatif dengan pendekatan deskriptif. populasi dalam penelitian ini adalah seluruh wajib pajak KPP Pratama Jayapura. Teknik pengambilan sampel menggunakan metode purposive sampling. Sampel di dalam penelitian ini adalah wajib pajak yang telah melaporkan SPT tahunan pada KPP Pratama Jayapura tersebut, adapun sampel dalam penelitian ini berjumlah 95 wajib pajak.Metode pengumpulan data yaitu menggunakan kuesioner online yang dibagikan secara Online dengan Teknik snowball sampling. Data yang digunakan dalam penelitian merupakan data primer yang dikumpulkan melalui survei kuesioner.Alat Analisis data dalam penelitian ini menggunakan pendekatan Structural Equation Model (SEM) dengan metode Partial Least Square (PLS) dengan menggunakan software WarpPLS 7.0. PLS – SEM digunakan untuk menguji secara simultan hubungan antar konstruk laten dalam hubungan linear ataupun nonlinear dengan banyak indicator baik berbentuk reflektif dan formatif.Hasil analisis moderasi dengan melihat nilai P-value menunjukkan bahwa preferensi risiko tidak memoderasi hubungan pemahaman perpajakan terhadap kepatuhan wajib. Hal ini berarti bahwa wajib pajak belum memahami khususnya pemahaman dasar mengenai pajak agar wajib pajak dapat mempertimbangkan segala sesuatu sebelum melakukan pembayaran pajak karena pemahaman pajak menjadi faktor yang sangat penting dalam membantu wajib pajak melaksanakan tingkat kepatuhan wajib pajak. Sedangkan Hasil analisis rmoderasi dengan pendekatan nilai p-value menunjukkan bahwa preferensi risiko memoderasi hubungan sanksi perpajakan terhadap kepatuhan wajib. Hal ini berarti bahwa masyarakat pada umumnya akan patuh pada peraturan apabila ada sanksi yang mengikat, Selain itu hal yang harus diperhatikan wajib pajak dalam melakukan pembayaran pajak adalah risiko. Karena Semakin tinggi sanksi yang diberikan maka akan menghasilkan kepatuhan yang tinggi pula.
UMA PERSPECTIVA DECOLONIAL PARA A EDUCAÇÃO MUSICAL BRASILEIRA NO ENSINO BÁSICO
Authors: Nogueira Ricardo Emílio Ferreira Quevedo 
Published: November 2022

O ensino de música, componente obrigatório do currículo das escolas brasileiras, via de regra, se baseia em modelos e obras europeias, apresentadas como padrão de excelência a ser perseguido. Tais obras, a despeito de sua elaborada concepção e aceitação universal, estão muito longe da realidade dos nossos estudantes. A imposição desse tipo de ensino, onde a música europeia é apresentada como “superior”, perpetua um sistema racista de submissão aos valores da “metrópole”, no qual a nossa música é considerada como “inferior”, inculta ou de pior qualidade. O ensino de música baseado exclusivamente em obras de origem europeia, além disso, pode desestimular o aprendizado ou o gosto dos estudantes que, muitas vezes, não se identificam com os seus estilos, formas e ritmos. A proposta deste trabalho foi pesquisar a bibliografia sobre alternativas de Educação Musical numa perspectiva não-eurocêntrica (decolonial), analisar algumas abordagens recentes que enfatizam a cultura nacional e discutir a viabilidade de uma Educação Musical brasileira, que valorizasse a nossa música e permitisse uma aprendizagem mais prazerosa dos fundamentos da linguagem musical. A partir das observações e conclusões dos estudiosos do tema, verificou-se que uma Educação Musical que inclua nossas músicas e manifestações populares é viável e capaz de propiciar um maior envolvimento e o desenvolvimento musical dos estudantes brasileiros, de modo eficaz e atraente. Este trabalho sugere, portanto, a adoção de uma abordagem para a Educação Musical na educação básica, que seja fortemente baseada na nossa cultura popular e na diversidade da música brasileira.
Predictors of sexual aggression among gay men and lesbian women: An application of Malamuth's confluence model
Authors: Waldis Lea , Herzberg Philipp Yorck , Herold Julia , Nothhelfer Konstanze , Krebs Joline , Troche Stefan 
Published: November 2022

AbstractThe present study investigated whether the core constructs of Malamuth's confluence model (i.e., hostility against individuals of the same sex and sexual orientation [HASSO], impersonal sexuality [IS], and high dominance/low nurturance [HDLN]) could predict sexual aggressive behavior (SA) of gay men against other gay men and of lesbian women against other lesbian women. For both gay men (N = 226) and lesbian women (N = 190) regression analysis showed that IS, HDLN, and especially HASSO proved to be important predictors for sexual aggression. The confluence of all three risk factors in terms of a three‐way interaction added to the prediction of SA in lesbian women but not in gay men. Overall, the three predictors explained 30% of the variance in SA among men and 62% of the variance in SA among women.
Automatic measurement of beam‐positioning accuracy at off‐isocenter positions
Authors: Ono Tomohiro , Kido Takahisa , Nakamura Mitsuhiro , Iramina Hiraku , Kakino Ryo , Mizowaki Takashi 
Published: November 2022

AbstractPurposeThis study performed an automatic measurement of the off‐axis beam‐positioning accuracy at a single isocenter via the TrueBeam Developer mode and evaluated the beam‐positioning accuracy considering the effect of couch rotational errors.MethodsTrueBeam STx and the Winston–Lutz test‐dedicated phantom, with a 3 mm diameter steel ball, were used in this study. The phantom was placed on the treatment couch, and the Winston–Lutz test was performed at the isocenter for four gantry angles (0°, 90°, 180°, and 270°) using an electronic portal imaging device. The phantom offset positions were at distances of 0, 25, 50, 75, and 100 mm from the isocenter along the superior–inferior, anterior–posterior, and left–right directions. Seventeen patterns of multileaf collimator‐shaped square fields of 10 × 10 mm2 were created at the isocenter and off‐axis positions for each gantry angle. The beam‐positioning accuracy was evaluated with couch rotation along the yaw‐axis (0°, ± 0.5°, and ± 1.0°).ResultsThe mean beam‐positioning errors at the isocenter and off‐isocenter distances (from the isocenter to ±100 mm) were 0.46–0.60, 0.44–0.91, and 0.42–1.11 mm for the couch angles of 0°, ±0.5°, and ±1°, respectively. The beam‐positioning errors increased as the distance from the isocenter and couch rotation increased.ConclusionThese findings suggest that the beam‐positioning accuracy at the isocenter and off‐isocenter positions can be evaluated quickly and automatically using the TrueBeam Developer mode. The proposed procedure is expected to contribute to an efficient evaluation of the beam‐positioning accuracy at off‐isocenter positions.
Multi‐Stage Phase‐Segregation of Mixed Halide Perovskites under Illumination: A Quantitative Comparison of Experimental Observations and Thermodynamic Models
Authors: Suchan Klara , Just Justus , Beblo Pascal , Rehermann Carolin , Merdasa Aboma , Mainz Roland , Scheblykin Ivan G. , Unger Eva 
Published: November 2022

AbstractPhoto‐ and charge‐carrier‐induced ion migration is a major challenge when utilizing metal halide perovskite semiconductors for optoelectronic applications. For mixed iodide/bromide perovskites, the compositional instability due to light‐ or electrical bias induced phase‐segregation restricts the exploitation of the entire bandgap range. Previous experimental and theoretical work suggests that excited states or charge carriers trigger the process, but the exact mechanism is still under debate. To identify the mechanism and cause of light‐induced phase‐segregation phenomena, the full compositional range of methylammonium lead bromide/iodide samples are investigated, MAPb(BrxI1‐x)3 with x = 0…1, by simultaneous in situ X‐ray diffraction (XRD) and photoluminescence (PL) spectroscopy during illumination. The quantitative comparison of composition‐dependent in situ XRD and PL shows that at excitation densities of 1 sun, only the initial stage of photo‐segregation is rationalized with the previously established thermodynamic models. However, a progression of the phase segregation is observed that is rationalized by considering long‐lived accumulative photo‐induced material alterations. It is suggested that (additional) photo‐induced defects, possibly halide vacancies and interstitials, need to be considered to fully rationalize light‐induced phase segregation and anticipate the findings to provide crucial insight for the development of more sophisticated models.
2D Oxides Realized via Confinement Heteroepitaxy
Authors: Turker Furkan , Dong Chengye , Wetherington Maxwell T. , El‐Sherif Hesham , Holoviak Stephen , Trdinich Zachary J. , Lawson Eric T. , Krishnan Gopi , Whittier Caleb , Sinnott Susan B. , Bassim Nabil , Robinson Joshua A. 
Published: November 2022

AbstractNovel confinement techniques facilitate the formation of non‐layered 2D materials. Here it is demonstrated that the formation and properties of 2D oxides (GaOx, InOx, SnOx) at the epitaxial graphene (EG)/silicon carbide (SiC) interface is dependent on the EG buffer layer properties prior to element intercalation. Using 2D Ga, it is demonstrated that defects in the EG buffer layer lead to Ga transforming to GaOx with non‐periodic oxygen in a crystalline Ga matrix via air oxidation at room temperature. However, crystalline monolayer GaO2 and bilayer Ga2O3 with ferroelectric wurtzite structure(FE‐WZ') can then be formed via subsequent high‐temperature O2 annealing. Furthermore, the graphene/X/SiC (X = 2D Ga or Ga2O3) junction is tunable from Ohmic to a Schottky or tunnel barrier depending on the interface species. Finally, using vertical transport measurements and electron energy loss spectroscopy analysis, the bandgap of 2D gallium oxide is identified as 6.6 ± 0.6 eV, significantly larger than that of bulk β‐Ga2O3 (≈4.8 eV), suggesting strong quantum confinement effects at the 2D limit. The study presented here is foundational for development of atomic‐scale, vertical 2D/3D heterostructure for applications requiring short transit times, such as GHz and THz devices.
Tissue‐Targeted Drug Delivery Strategies to Promote Antigen‐Specific Immune Tolerance
Authors: Rui Yuan , Eppler Haleigh B. , Yanes Alexis A. , Jewell Christopher M. 
Published: November 2022

AbstractDuring autoimmunity or organ transplant rejection, the immune system attacks host or transplanted tissue, causing debilitating inflammation for millions of patients. There is no cure for most of these diseases. Further, available therapies modulate inflammation through nonspecific pathways, reducing symptoms but also compromising patients’ ability to mount healthy immune responses. Recent preclinical advances to regulate immune dysfunction with vaccine‐like antigen specificity reveal exciting opportunities to address the root cause of autoimmune diseases and transplant rejection. Several of these therapies are currently undergoing clinical trials, underscoring the promise of antigen‐specific tolerance. Achieving antigen‐specific tolerance requires precision and often combinatorial delivery of antigen, cytokines, small molecule drugs, and other immunomodulators. This can be facilitated by biomaterial technologies, which can be engineered to orient and display immunological cues, protect against degradation, and selectively deliver signals to specific tissues or cell populations. In this review, some key immune cell populations involved in autoimmunity and healthy immune tolerance are described. Opportunities for drug delivery to immunological organs are discussed, where specialized tissue‐resident immune cells can be programmed to respond in unique ways toward antigens. Finally, cell‐ and biomaterial‐based therapies to induce antigen‐specific immune tolerance that are currently undergoing clinical trials are highlighted.
Microneedle‐Assisted Transdermal Delivery of 2D Bimetallic Metal–Organic Framework Nanosheet‐Based Cascade Biocatalysts for Enhanced Catalytic Therapy of Melanoma
Authors: Chen Jiajie , Niu Huicong , Guan Lei , Yang Zhibo , He Yuzhao , Zhao Jinjin , Wu Chengtie , Wang Yitong , Lin Kaili , Zhu Yufang 
Published: November 2022

AbstractCurrent conventional treatments for malignant melanoma still face limitations, especially low therapeutic efficacy and serious side effects, and more effective strategies are urgently needed to develop them. Delivering biocatalysts into tumors to efficiently trigger in situ cascade reactions has shown huge potential in producing more therapeutic species or generating stronger tumoricidal effects for augmented tumor therapy. Recently, ultrathin 2D metal–organic framework (MOF) nanosheets have acquired great interest in biocatalysis owing to their large surface areas and abundant accessible active catalytic sites. Herein, an enhanced catalytic therapeutic strategy against melanoma is developed by biocompatible microneedle (MN)‐assisted transdermal delivery of a 2D bimetallic MOF nanosheet‐based cascade biocatalyst (Cu‐TCPP(Fe)@GOD). Profiting from the constructed dissolving MN system, the loaded Cu‐TCPP(Fe)@GOD hybrid nanosheets can be accurately delivered into the melanoma sites through skin barriers, and subsequently, trigger the specific cascade catalytic reactions in response to the acidic tumor microenvironment to effectively generate highly toxic hydroxyl radical (•OH) and deplete glucose nutrient for inducing the death of melanoma cells. The ultimate results prove the high melanoma inhibition effect and biosafety of such therapeutic modality, exhibiting a new and promising strategy to conquer malignant melanoma.
Fibrillization of Non‐Fullerene Acceptors Enables 19% Efficiency Pseudo‐Bulk Heterojunction Organic Solar Cells
Authors: Li Donghui , Deng Nan , Fu Yiwei , Guo Chuanhang , Zhou Bojun , Wang Liang , Zhou Jing , Liu Dan , Li Wei , Wang Kai , Sun Yanming , Wang Tao 
Published: November 2022

AbstractThe structural order and aggregation of non‐fullerene acceptors (NFA) are critical toward light absorption, phase separation, and charge transport properties of their photovoltaic blends with electron donors, and determine the power conversion efficiency (PCE) of the corresponding organic solar cells (OSCs). In this work, the fibrillization of small molecular NFA L8‐BO with the assistance of fused‐ring solvent additive 1‐fluoronaphthalene (FN) to substantially improve device PCE is demonstrated. Molecular dynamics simulations show that FN attaches to the backbone of L8‐BO as the molecular bridge to enhance the intermolecular packing , inducing 1D self‐assembly of L8‐BO into fine fibrils with a compact polycrystal structure. The L8‐BO fibrils are incorporated into a pseudo‐bulk heterojunction (P‐BHJ) active layer with D18 as a donor, and show enhanced light absorption, charge transport, and collection properties, leading to enhanced PCE from 16.0% to an unprecedented 19.0% in the D18/L8‐BO binary P‐BHJ OSC, featuring a high fill factor of 80%. This work demonstrates a strategy for fibrillating NFAs toward the enhanced performance of OSCs.
Nanoengineered Carbon‐Based Interfaces for Advanced Energy and Photonics Applications: A Recent Progress and Innovations
Authors: Levchenko Igor , Baranov Oleg , Riccardi Claudia , Roman H. Eduardo , Cvelbar Uroš , Ivanova Elena P. , Mohandas Mandhakini , Ščajev Patrik , Malinauskas Tadas , Xu Shuyan , Bazaka Kateryna 
Published: November 2022

AbstractAs famed quantum physicist W. Pauli once said, “The surface was invented by the devil”. The nonequilibrium state of particles forming the surface, and the presence of dangling bonds transform the surfaces into a 2D reactor with high physical and chemical reactivity. When two such active surfaces are matched, their interface becomes even more reactive, giving rise to novel properties or enhanced performance. For this reason, much effort is applied to design nanoengineered interfacial systems for applications spanning all facets of human life. This review article discusses recent, mostly within two years, progress in the design of complex, sophisticated carbon‐based interfacial material systems for energy and photonics applications, with the aim to emphasize some of the most interesting and important examples of such systems. Differences in the processes that take place on flat and 3D (curved) surfaces are discussed, with the view of guiding the design and construction of complex functional interfaces, focusing on several points that are of particular importance to the ongoing development of advanced interfacial material systems.
Manganese‐CpG Nanocomposite Integrates ROS‐Induced Cell Apoptosis and STING‐Activated and Adjuvant‐Augmented Immune Responses for Tumor Elimination and Prevention
Authors: Chen Jie , Lu Jianxiu , Shan Yunyi , Wang Yanqiu , Xu Zhilong , Xi Juqun , Fan Lei , Gao Lizeng 
Published: November 2022

AbstractChemodynamic therapy (CDT) based on Fenton‐like reaction possesses great potential for anticancer therapy with high efficiency and specificity. However, CDT still suffers low therapeutic efficiency due to intratumoral insufficient H2O2 or unfavorable tumor microenvironment. To enhance tumor treatment and in particular prevent tumor recurrence, the combined strategies with CDT are essentially needed. Herein, a nanocomposite based on Mn2+ and cytosine‐phosphate‐guanine oligonucleotides (CpG ODNs) (MnCpGPNCs) is constructed to combine CDT with immunostimulating responses by exploiting Mn2+‐induced CDT and Mn2+/CpG ODNs‐coinduced immunotherapy against mouse colon tumor cells. Specifically, MnCpGPNCs efficiently deliver and sensitively release Mn2+ in tumor cells to trigger Fenton‐like reaction, causing cell apoptosis. Importantly, Mn2+ also promotes the stimulator of interferon genes pathway to increase the production of type I interferons, thus increasing cytotoxic T lymphocyte infiltration, dendritic cell maturation, and proinflammatory cytokine secretion. Furthermore, CpG ODNs serve as immune adjuvant enhanced the antigen presentation and immune‐eliciting potency. The combination of Mn2+‐based CDT with augmented immunotherapy efficiently inhibits the primary/distance tumors and prevents tumorigenesis. Overall, this newly developed metal‐CpG system demonstrates a paradigm to expand chemodynamic agents as immunotherapy boosters to complement current treatments for tumor elimination and prevention.
Bulk Oxygen Stabilization via Electrode‐Electrolyte Interphase Tailored Surface Activities of Li‐Rich Cathodes
Authors: Zhang Xu , Zhao Jingteng , Lee Gi‐Hyeok , Liang Yuan , Wang Boya , Liu Shiqi , Wang Errui , Yang Wanli , Yu Haijun 
Published: November 2022

AbstractThe O3‐type Li‐rich layered oxides (LLOs) are approaching industrial applications as high‐energy cathode materials for Li‐ion batteries (LIBs), however, they suffer from rapid performance decay associated with oxygen activities. The interplay between surface and bulk transformations in LLOs, especially the electrochemical behaviors of oxygen anions, remains elusive. Here, by regulating the surface of an O3‐type LLO (Li1.13Mn0.517Ni0.256Co0.097O2) using an all‐fluorinated electrolyte, an enhanced capacity retention from 57.4% to 85.3% and a suppressed voltage decay from 1.34 mV cycle−1 to 0.58 mV cycle−1 within 300 cycles are realized. The performance enhancement is attributed to the thin, uniform, robust, and compact F‐rich cathode‐electrolyte interphase (CEI), which suppresses various types of oxygen‐related surface degradation and, more importantly, stabilizes the bulk oxygen reactions. Through the combined experimental and theoretical studies, this work directly reveals the intriguing association between the surface and bulk oxygen activities and demonstrates that optimizing the interphase is an effective approach for improving the stability of high‐energy battery cathodes involving oxygen redox reactions.