bluuebunny/crossref_metadata_2025_split huggingface dataset:
BUSINESS ANALYSIS – NEW ANALYTICS FOR MANAGEMENT
Authors: Чернышева Ю.Г. 
Published: July 2022

Современный мир изменился практически до неузнаваемости, и сейчас мы живем в VUCA-мире. VUCA-мир – это стрессовый, постоянно изменяющийся мир со множеством вызовов, мир, в котором требуется быстро и адекватно перерабатывать огромные объемы информации. Этот мир требует новых подходов во всех областях, начиная с компетенций специалистов и заканчивая реагированием организации на вызовы, постоянно возникаю-щие перед ней. Бизнес-анализ – новая аналитическая концепция, представляющая собой высший уровень аналитики для бизнеса. Бизнес-анализ позволяет организациям противо-стоять VUCA-миру, разрабатывать решения, основанные на данных, используя подход da-ta driven decision. Этот подход дает возможность гарантировать лучшее решение проблем бизнеса и разработки стратегии его развития.
The modern world has changed almost beyond recognition and now we live in a VUCA world. The VUCA world is a stressful, constantly changing world with many challenges, a world in which huge amounts of information must be processed quickly and adequately. This world re-quires new approaches in all areas, from the competencies of specialists to the organization's re-sponse to the challenges that constantly arise in front of it. Business Intelligence is a new analyti-cal concept that represents the highest level of business intelligence. Business analysis allows or-ganizations to confront the VUCA world, develop data-driven decisions using the data driven de-cision approach. This approach makes it possible to guarantee the best solution to business prob-lems and develop a strategy for its development.
La desafección política en los países del entorno europeo español ¿una actitud estable?
Authors: Megías Adrián , Cristina Moreno  
Published: July 2022

Esta investigación se centra en la desafección política en Europa.
Tras los peores años de crisis económica, los datos muestran un significativo incremento de esta actitud hacia la política. Este aumento contradice la tesis convencional de que la desafección tiene una naturaleza estructural. A partir de la identificación de los factores que explican la desafección en España, y si son de tipo estructural o coyuntural, estos resultados se comparan con los de los países europeos de su entorno. Para ello, se aborda un análisis jerárquico de clasificación cruzada usando datos de encuestas procedentes de la ESS. Los resultados revelan la importancia del contexto en la configuración de la desafección en los países europeos.
Analisis Kemampuan Teknik Dasar Permainan Sepak Takraw Pada Tim Kabupaten Toli-Toli
Authors: Purwanto Didik , Rifandy Arief Aditya , Sardiman Sardiman 
Published: July 2022

Tujuan dari penelitian ini adalah untuk mengetahui kemampuan teknik dasar permainan sepak takraw pada Tim Sepak Takraw Kabupaten Toli-Toli. Desain yang digunakan dalam penelitian ini adalah deskriptif kuantitatif. Instrumen yang digunakan dalam penelitian ini yaitu tes keterampilan bermain sepak takraw buatan M. Husni Thamrin meliputi tes sepak mula, sepak sila, sepak kura, heading dan smash. Populasi penelitian ini berjumlah 18 orang. Teknik pengambilan sampel dalam penelitian ini adalah teknik sampling jenuh dimana semua anggota populasi dijadikan sampel. Hasil penelitian ini menunjukkan bahwa: (1) tidak terdapat nilai kategori sangat tinggi; (2) kategori tinggi sebanyak 5; (3) kategori sedang sebanyak 9; (4) kategori kurang sebanyak 4; (5) tidak terdapat nilai sangat kurang. Hasil nilai uji deskriptif didapatkan skor maksimal sebesar 79,30, dan skor minimal sebesar 36,81 dengan skor rata-rata 50 dan standar deviasi 10. Secara keseluruhan dapat disimpulkan bahwa keterampilan bermain sepak takraw Kabupaten Toli-toli masuk dalam kategori sedang.
Efektifitas Diabetes Self Management Education (DSME) terhadap Kadar Glukosa Darah pada Pasien Diabetes Mellitus Tipe 2 di Wilayah Puskesmas Limboto Barat
Authors: Sudirman Andi Akifa , Modjo Dewi 
Published: July 2022

Diabetes Self Management Education (DSME) merupakan serangkaian intervensi khusus untuk membantu diabetisi dalam merubah gaya hidupnya sehingga menjadi patuh dalam manajemen perawatan diri. DSME diberikan secara berkesinambungan yang mengacuh pada pilar penatalaksanaan DM. Tujuan penelitian adalah diketahuinya efektifitas Diabetes Self Management Education (DSME) terhadap kadar glukosa darah pada pasien diabetes mellitus tipe 2 di Wilayah Kerja Puskesmas Limboto Barat. Metode penelitian pre eksperimen desain dengan jumlah sampel 15 orang, teknik pengambilan sampling dengan probability sampling. Analisis menggunakan uji dependen t-test/uji paired t test. Hasil penelitian didapatkan perbedaan kadar glukosa darah yang bermakna pada pengukuran sesudah pemberian DSME pada responden dimana diperoleh nilai p < 0,05 (p = 0,00), dengan nilai t positif (4,67) yang berarti pengukuran kadar glukosa darah sebelum perlakuan lebih besar dari pengukuran sesudah perlakuan, sehingga dapat disimpulkan bahwa terdapat perbedaan kadar glukosa darah pada pasien diabetes mellitus tipe 2 sebelum dan sesudah intervensi penerapan Diabetes Self Manajement Education (DSME). Saran pada penelitian ini diharapkan penerapan program edukasi (pendidikan kesehatan) untuk diabetisi diberikan dengan lebih sistematis dan berkesinambungan memuat materi-materi terkait dengan menggunakan media dan metode yang menarik.
Consumer Culture and Abundance of Choices: Having More, Feeling Blue
Authors: Roubal Ondřej 
Published: July 2022

The defining feature of contemporary consumer culture is the escalation of consumption opportunities and the expanding space for choice. An unbridled and unrestricted range of products is part of material prosperity, rising living standards, and emancipation of human freedoms. The growing demands for constant consumer decision-making in an increasingly opaque environment of potential targets of choice exposes consumers to the risk of procrastination, passivity, and resignation, as well as psychological discomfort. The goal here is to contribute to theories of consumer behavior in the context of the psychological experience of choice under the conditions of the accelerated quantity of consumption volumes against the backdrop of the COVID-19 pandemic. While conventional offline shopping was drastically curtailed during the coronavirus crisis, freedom of consumer choice was maintained despite many proclamations to the contrary. I seek to provide support to the claim that freedom of consumer choice was maintained and often amplified during the pandemic in the online virtual environment of digital commerce formats. Freedom of consumer choice has merely been transformed into a horizontal level of application by the relatively rapid and fluid conversion of market activities into the cyberspace of a growing number of e-stores and online supermarkets, unconstrained by the physical space of shelves and counters.
Animated Instructional Medium in Structural Foundation
Authors: Daradar Maricel 
Published: July 2022

Complicated concepts in designs are difficult to explain in traditional media, such as still slides. Animation seems to provide an advantage in delivering a better rendition of these concepts. This study aimed to develop an Animated Instructional Medium in Structural Foundation, which could be used by Drafting Technology Students of Carlos Hilado Memorial State College, Talisay, Negros Occidental and will serve as a viable instructional material in teaching drafting technology subjects. Specifically, it sought to design and develop an Animated Instructional Medium in Structural Foundation with the following features: animated, interactive, and quality. It also determined the acceptability of the project in terms of animation, user control, interactivity, and images. Moreover, formulate an instructional guide for using the project. Descriptive and developmental methods were used in this study involving one hundred forty respondents comprising architects, civil engineers, drafting instructors, and students for project evaluation. The findings of the study showed that the Animated Instructional Medium in Structural Foundation was rated highly acceptable in terms of technical features and very acceptable in terms of animation, user control, interactivity, images, and text. An instructional guide was formulated to serve as an instructional medium for teaching basic structural foundations in Architectural Drafting. This study is beneficial to the BSIT Drafting students, construction foremen, construction workers, homeowners, instructors, and researchers.
Prevalence, characteristics, and consequences of verbal and physical violence against healthcare staff in Chinese hospitals during 2010–2020
Authors: Jia Chen , Han Yijing , Lu Wenping , Li Ruofan , Liu Weizheng , Jiang Jianan 
Published: July 2022

Abstract

Objectives
This study investigated the characteristics of workplace violence (WPV) against Chinese healthcare staff and their casualties after severe physical violence (PV).

Methods
We scrutinized medical WPV incidents reported online and analyzed information on timing, location, violence, criminal incentives, and casualties following severe PV in China from 2010 to 2020.

Results
WPVs were mostly committed by young and middle-aged male family members of the patients, especially in the emergency department (49.1%), and mostly associated with dissatisfaction with treatment effect (28.9%) in general. High medical costs (62.5%) were the leading cause of verbal violence (VV), whereas men predominantly committed PV (OR = 4.217, 95% CI: 1.439–12.359) owing to dissatisfaction with the healthcare staff's attitude (P &lt; 0.001). The victims were security personnel in most cases (81.1%). Nurses were generally more likely to experience PV (P &lt; 0.05), while doctors were more likely to experience lethal PV (OR = 4.732, 95% CI: 1.42–15.772), which mostly happened in oncology (P &lt; 0.05) and committed by visitors (P &lt; 0.001). Slight injuries and mortality were more likely to be inflicted by being rejected for unreasonable demands and disappointed with the treatment effect (P &lt; 0.05).

Conclusions
Medical WPV has numerous reasons, locations, and diverse victims and offenders. Some severe WPVs have serious consequences. Therefore, it is recommended for the concerned authorities to adopt effective steps for appropriate legislative, security, and conflict-resolution measures.
Electrochemical Synthesis of Iodohydrins
Authors: Luan Shinan , Castanheiro Thomas , Poisson Thomas 
Published: July 2022

AbstractIodohydrins and corresponding ethers were synthesized by an electrochemical process using inexpensive and non‐toxic ammonium iodide. This transformation was applied to a panel of alkenes, giving products without the need of external hazardous oxidants, reductants or metal catalyst. This protocol showed a general efficiency to synthesize valuable iodinated molecules with yields from 19% to 90%.magnified image
Visible‐Light Photoredox‐Catalyzed Tandem One‐Pot Construction of C4‐Difluoroalkylated Phthalazin‐1(2H)‐Ones
Authors: Yao Zhen , Yang Ji , Luo Zhenli , Ye Jianhan , Han Jiahong , Zhang Xin , Xu Lijin , Wang Peng , Shi Qian 
Published: July 2022

AbstractTandem one‐pot regioselective synthesis of C4‐difluoroalkylated phthalazin‐1(2H)‐ones from readily available hydrazines, 2‐formylbenzoic acids and bromodifluoroacetate derivatives under visible‐light photocatalysis is reported. This mild protocol provides straightforward access to various C4‐difluoroalkylated phthalazin‐1(2H)‐ones, and displays broad substrate scope and wide functional group tolerance. Moreover, this process is also suitable for the synthesis of C4‐trifluoromethylated and perfluorobutylated phthalazin‐1(2H)‐ones. The use of fac‐[Ir(ppy)3] photocatalyst and the introduction of an organic base additive are pivotal to catalysis.magnified image
Anionic Co‐insertion Charge Storage in Dinitrobenzene Cathodes for High‐Performance Aqueous Zinc–Organic Batteries
Authors: Song Ziyang , Miao Ling , Duan Hui , Ruhlmann Laurent , Lv Yaokang , Zhu Dazhang , Li Liangchun , Gan Lihua , Liu Mingxian 
Published: July 2022

AbstractHighly active and stable cathodes are critical for aqueous Zn–organic batteries with high capacity, fast redox kinetics, and long life. We herein reportpara‐,meta‐, andortho‐dinitrobenzene (p‐,m‐, ando‐DB) containing two successive two‐electron processes, as cathode materials to boost the battery performance. Theoretical and experimental studies reveal that nitro constitutional isomerism is key to zincophilic activity and redox kinetics.p‐DB hosted in carbon nanoflower harvests a high capacity of 402 mAh g−1and a superior stability up to 25 000 cycles at 5 A g−1, giving a Zn–organic battery with a high energy density of 230 Wh kg−1. An anionic co‐insertion charge storage mechanism is proposed, entailing a two‐step (de)coordination of Zn(CF3SO3)+with nitro oxygen. Besides, dinitrobenzene can be electrochemically optimized by side group regulation via implanting electron‐withdrawing motifs. This work opens a new window to design multielectron nitroaromatics for Zn–organic batteries.
Simultaneous Detection of Circularly Polarized Luminescence and Raman Optical Activity in an Organic Molecular Lemniscate
Authors: Palomo Luis , Favereau Ludovic , Senthilkumar Kabali , Stępień Marcin , Casado Juan , Ramírez Francisco J. 
Published: July 2022

AbstractCircularly polarized luminescence (CPL) and Raman optical activity (ROA) were observed in a single spectroscopic experiment for a purely organic molecule, an event that had so far been limited to lanthanide‐based complexes. The present observation was achieved for [16]cycloparaphenylene lemniscate, a double macrocycle constrained by a rigid 9,9′‐bicarbazole subunit, which introduces a chirality source and allows the molecule to be resolved into two configurationally stable enantiomers. Distortion of oligophenylene loops in this lemniscular structure produces a large magnetic transition dipole moment while maintaining the π‐conjugation‐induced enhancement of the Raman signal, causing the appearance of the CPL/ROA couple. A two‐photon mechanism is proposed to explain the population of the lowest‐energy excited electronic state prior to the simultaneous emission‐scattering event.
Evaluation of roll dry granulation process on the high‐viscosity melt solidification and heat recovery
Authors: Liu Hu , Yu Pengfei , Xue Jingwen , Zhang Yankang , Che Defu 
Published: July 2022

AbstractHigh‐viscosity melt with temperature above 1600 K has great potential for energy saving. A mathematical model was proposed on the heat transfer between the rotating roll and melt in a roll dry granulation system, aiming at the efficient granulation and heat recovery of high‐viscosity melt. In the model, the relationship between the rotation angle and time was utilized to simplify the three‐dimensional dynamic process to a one‐dimensional static problem. Then, the influences of the roll material, dimension, rotational speed, and the melt shedding angle on the system performance were investigated. Simulation results indicated that increasing the thermal conductivity or decreasing the wall thickness will result in a higher cooling rate but a more nonuniform heat flux distribution. The possible vibration and thermal fatigue due to the nonuniform heat flux distribution will cause a poor working stability. Heat‐resistant steel is a better choice than copper alloy. The optimum wall thickness is about 19 mm, and the rotational speed should be kept below 17 rpm. The overall exergy efficiency increased from 37% to 59%, when the melt shedding angle changed from 120° to 28.8°. This study provides a further feasible method for the efficient granulation and heat recovery of high‐viscosity melt.
What Limits the Rate Capability of Ultrathick Composite Electrodes in Lithium‐Ion Batteries? A Case Study on the Thickness‐Dependent Impedance of LiCoO2 Cathodes
Authors: Cronau Marvin , Paulus Alexander , Pescara Lars Pateras , Kroll Moritz , Renz Diemo , Mekontso Joëlle Aurelie , Marx Anna , Roling Bernhard 
Published: July 2022

AbstractIncreasing the thickness of composite electrodes in lithium‐ion batteries from about 80–100 μm in state‐of‐the‐art commercial cells to several 100 μm would enhance the energy density, however at the expense of the power density. Despite this common knowledge, quantitative studies on the impedance and rate capability of composite electrode in dependence of the electrode thickness are scarce. Therefore, we have carried out a case study on LiCoO2 composite electrodes with thicknesses up to about 250 μm. We first demonstrate that conventional composite electrode preparation leads to ion transport tortuosities in the electrolyte‐filled pores, which are virtually independent of the thickness. The thickness‐dependent impedance of these electrodes decreases with increasing thickness and follows the predictions of a generalized transmission line (GTLM) model. We use the GTLM model for analyzing in what way cycling of ultrathick electrodes (250–300 μm) with a rate of 1 C should be achievable.
Development of a Tethered mRNA Amplifier to increase protein expression
Authors: Torkzaban Bahareh , Kawalerski Ryan , Coller Jeff 
Published: July 2022

AbstractHerein, we present a novel method to specifically increase a messenger RNA's (mRNA) expression at the post‐transcriptional level. This is accomplished using what we term a “Tethered mRNA Amplifier.” The Tethered mRNA Amplifier specifically binds an mRNA's 3′ untranslated region and enhances its stability/translation, often doubling protein output. We test this approach on several transcripts associated with haploinsufficiency disorders and increase their steady‐state expression in cell culture. We suggest this approach may be a tenable therapeutic modality with precise activity and broad‐spectrum application.
Recent advances, challenges and metabolic engineering strategies in the biosynthesis of 3‐hydroxypropionic acid
Authors: Liang Bo , Sun Guannan , Zhang Xinping , Nie Qingjuan , Zhao Yukun , Yang Jianming 
Published: July 2022

AbstractAs an attractive and valuable platform chemical, 3‐hydroxypropionic acid (3‐HP) can be used to produce a variety of industrially important commodity chemicals and biodegradable polymers. Moreover, the biosynthesis of 3‐HP has drawn much attention in recent years due to its sustainability and environmental friendliness. Here, we focus on recent advances, challenges, and metabolic engineering strategies in the biosynthesis of 3‐HP. While glucose and glycerol are major carbon sources for its production of 3‐HP via microbial fermentation, other carbon sources have also been explored. To increase yield and titer, synthetic biology and metabolic engineering strategies have been explored, including modifying pathway enzymes, eliminating flux blockages due to byproduct synthesis, eliminating toxic byproducts, and optimizing via genome‐scale models. This review also provides insights on future directions for 3‐HP biosynthesis.
Use of multikinase inhibitors/lenvatinib concomitant with antiresorptive therapy for bone metastases from radioiodine‐resistant differentiated thyroid cancer
Authors: Navarro‐Gonzalez Elena 
Published: July 2022

AbstractBone is the second most common distant metastasis site in differentiated thyroid cancer (DTC) and is normally associated with the presence of other metastases, which are usually radioiodine‐resistant. The presence of bone metastasis (BM) determines low survival and greater morbidity due to the frequency of skeletal‐related events (SREs), which can be a serious complication of BM. There is evidence that antiresorptive therapy (AT) reduces SREs in other solid tumors, but not yet in DTC BM, for which data are scant. The same is true for systemic therapy with multikinase inhibitors (MKIs). In general, the results for MKI use are well known, although the effect on BM has rarely been evaluated. While MKIs are indicated in current clinical practice guidelines, studies evaluating the benefits and risks of concomitant treatment with MKIs and AT are lacking, and the available data come from small samples in retrospective studies. The objective of this article is to review the latest evidence for concomitant MKIs and AT.
On the singular gamma, Wishart, and beta matrix‐variate density functions
Authors: Mathai Arak M. , Provost Serge B. 
Published: July 2022

AbstractWhen a real positive definite matrix follows a Wishart or, more generally, a matrix‐variate gamma distribution with shape parameter and positive definite scale parameter matrix , one can represent as for some matrix of dimension . When , has a singular distribution whose properties can be studied via the density function of . It will be shown that when follows a matrix‐variate extended Gaussian distribution, the density function of the resulting singular gamma distribution can be obtained by making use of successive transformations and their associated Jacobians. The singular Wishart distribution will then be obtained as a particular case. The marginal and conditional density functions resulting from an arbitrary partitioning of will be considered as well. The same technique will also be applied to the derivation of the density functions of real and complex singular type‐1 and type‐2 beta‐distributed matrices. It so happens that the proposed approach, which is based on manipulations involving the wedge products of certain differential elements, generally proves more efficient than the intricate procedures that have hitherto been employed in the literature.
Ultrafine Palladium Embedded in N‐doped Porous Carbon Material from Carbazole‐covalent Triazine Polymer for Green Suzuki‐Miyaura Coupling Reaction
Authors: Zhang Li , Yu Haitao , Wu Wenjin , Ge Qi , Ni Shujing , Song Chunmei , Huang Kun 
Published: July 2022

AbstractHere, we develop a facile synthesis route to fabricate ultrafine palladium nanoparticles embedded in N‐doped porous carbon material (Pd@N‐PCM), in which carbazole‐covalent triazine polymers obtained by Friedel‐Crafts alkylation at room temperature are used as precursor of N‐doped carbon. The obtained Pd@N‐PCM as a green catalyst shows the high catalytic efficiency (TOF=982 h−1) for Suzuki‐Miyaura coupling reaction of chlorobenzene under the mild reaction condition (room temperature, a non‐toxic solvent and air atmosphere). The brilliant catalytic activity of Pd@N‐PCM gives the credit to the concerted effect from the ultrafine Pd and N‐doped porous carbon.
Photoinduced Intervalence Charge Transfers: Spectroscopic Tools to Study Fundamental Phenomena and Applications
Authors: Ramírez‐Wierzbicki Ivana , Cotic Agustina , Cadranel Alejandro 
Published: July 2022

AbstractThe exploitation of excited state chemistry for solar energy conversion or photocatalysis has been continuously increasing, and the needs of a transition to a sustainable human development indicate this trend will continue. In this scenario, the study of mixed valence systems in the excited state offers a unique opportunity to explore excited state electron transfer reactivity, and, in a broader sense, excited state chemistry. This Concept article analyzes recent contributions in the field of photoinduced mixed valence systems, i. e. those where the mixed valence core is absent in the ground state but created upon light absorption. The focus is on the utilization of photoinduced intervalence charge transfer bands, detected via transient absorption spectroscopy, as key tools to study fundamental phenomena like donor/acceptor inversion, hole delocalization, coexistence of excited states and excited state nature, together with applications in molecular electronics.