bluuebunny/crossref_metadata_2025_split huggingface dataset:
Optical Supercontinuum Generation via Rotational and Vibrational Molecular Cavity Optomechanics
Authors: Lu Qijing , Liao Lingqin , Chen Longxiang , Guo Junqiang , Hu Ya , Zhang Yan‐Lei , Zou Chang‐Ling , Wu Xiang , Xie Shusen 
Published: November 2022

AbstractThe solid high quality (Q) factor whispering gallery mode microcavities are demonstrated as an excellent experimental platform for enhanced light–matter interactions, and are applied in the studies of nonlinear optics, quantum optics, and sensing. However, the interaction between the microcavity and liquid anisotropic molecule, which is unique for abundant vibrational and rotational degrees of freedom, is rarely studied. Here, the gap is bridged by filling an optofluidic microbubble resonator with carbon disulfide, and the related anisotropic molecular cavity optomechanics effects are investigated. Due to the enhanced coupling between the optical mode and the rotation/vibration of molecules, stimulated Rayleigh–Kerr/Raman–Kerr scattering effects are observed. Molecular cavity optomechanics provides a broadband gain for generating Stokes photons in high‐Q optical modes, and eventually allows quasi‐supercontinuum generation with a bandwidth of 436 nm under a low continuous laser pump power of about 10 mW. This work opens a new avenue for strong light–matter interactions by exploring rotational and vibrational molecular cavity optomechanics, which provides a promising platform for nonlinear optics, cavity‐enhanced molecular reorientation dynamics, and novel optical sources.
Consequences of Teenage Childbearing on Child Outcomes in the United States
Authors: Gorry Devon 
Published: November 2022

AbstractChildren of teen mothers have worse academic, labor market, and behavioral outcomes in the United States, but it is not clear whether these poor outcomes are caused by having a young mother or driven by selection into teen motherhood. Understanding the reasoning behind poor child outcomes is important for designing effective policies to improve child trajectories. Simple correlations using data from the National Longitudinal Survey of Youth 1979 (NLSY79) and the NLSY79 Children and Young Adults (NLSY79CY) confirm that outcomes for children of teenage mothers are worse relative to children of older mothers. These negative relationships persist after controlling for background variables or including family fixed effects, though the magnitudes are attenuated. However, these approaches fail to fully account for selection into teen motherhood. To overcome selection, I employ an empirical strategy that relies on miscarriages to put bounds on the causal effects of teen childbearing. These bounds show that teen childbearing among mothers who choose to give birth does not cause adverse outcomes for children.
Optimizing the mechanical properties of TiO2/PA12 nano‐composites fabricated by SLS 3D printing
Authors: Afshari Mahmoud , Bakhshi Soroush , Samadi Mohammad Reza , Afshari Hossein 
Published: November 2022

AbstractIn this paper, the selective laser sintering process was used to fabricate the TiO2/PA12 nano‐composite parts by considering the parameters of laser power, scanning speed, and TiO2 content. The response surface methodology was used to improve the mechanical properties of TiO2/PA12 nano‐composite parts. The fracture surface characteristics of the specimens were examined using the scanning and transmission electron microscopy. The results indicated that the increase in laser power from 10 to 15 W improved the tensile strength, modulus, and impact strength of the nano‐composite parts because of the fine dispersion of TiO2 nano‐particles. An increase in the scanning speed from 2000 to 3000 mm/s resulted in the reduction of tensile strength and modulus due to lower heat input and consequently incomplete densification of polyamide‐12. In addition, the increase of TiO2 content up to 5 wt% can improve the tensile strength, modulus, and impact strength, but requires increasing the laser power. However, the mechanical properties of the nano‐composite parts were enhanced simultaneously at laser power of 12.4 W, scanning speed of 2000 mm/s and TiO2 content of 1.9 wt%. Moreover, the addition of TiO2 up to 5 wt% showed a slight influence on thermal stability and crystallinity of the sintered specimens.
The effect of postoperative ventilation strategies on postoperative complications and outcomes in patients with esophageal atresia: Results from the Turkish Esophageal Atresia Registry
Authors: Cömert Hatice Sonay Yalçın , Güney Doğuş , Durakbaşa Çiğdem Ulukaya , Dökümcü Zafer , Soyer Tutku , Fırıncı Binali , Çiftçi İlhan , Öztan Mustafa Onur , Demirel Berat Dilek , Parlak Ayşe , Göllü Gülnur , Karaman Ayşe , Akkoyun İbrahim , Gül Cengiz , İlhan Hüseyin , Oral Akgün , Özcan Rahşan , Özen Önder , Kıyan Gürsu , Erdem Ali Onur , Özaydın Seyithan , Uzunlu Osman , Yıldız Abdullah , Erginel Başak , Ertürk Nazile , Bilici Salim , Samsum Hakan , Özen Mehmet Ali , Özçakır Esra , Aydın Emrah , Mert Mehmet , Topbaş Murat 
Published: November 2022

AbstractObjectivesPostoperative ventilatory strategies in patients with esophageal atresia (EA) and tracheoesophageal fistula (TEF) may have an impact on early postoperative complications. Our national Esophageal Atresia Registry was evaluated to define a possible relationship between the type and duration of respiratory support on postoperative complications and outcome.Study DesignAmong the data registered by 31 centers between 2015 and 2021, patients with esophago‐esophageal anastomosis (EEA)/tracheoesophageal fistula (TEF) were divided into two groups; invasive ventilatory support (IV) and noninvasive ventilatory support and/or oxygen support (NIV‐OS). The demographic findings, gestational age, type of atresia, associated anomalies, and genetic malformations were evaluated. We compared the type of repair, gap length, chest tube insertion, follow‐up times, tensioned anastomosis, postoperative complications, esophageal dilatations, respiratory problems requiring treatment after the operation, and mortality rates.ResultsAmong 650 registered patients, 502 patients with EEA/TEF repair included the study. Four hundred and seventy of patients require IV and 32 of them had NIV‐OS treatment. The IV group had lower mean birth weights and higher incidence of respiratory problems when compared to NIV‐OS group. Also, NIV‐OS group had significantly higher incidence of associated anomalies than IV groups. The rates of postoperative complications and mortality were not different between the IV and NIV‐OS groups.ConclusionWe demonstrated that patients who required invasive ventilation had a higher incidence of low birth weight and respiratory morbidity. We found no relation between mode of postoperative ventilation and surgical complications. Randomized controlled trials and clinical guidelines are needed to define the best type of ventilation strategy in children with EA/TEF.
Bayesian method application: Integrating mathematical modeling into clinical pharmacy through vancomycin therapeutic monitoring
Authors: Chen Ashley , Gupta Anjum , Do Dylan Huy , Nazer Lama H. 
Published: November 2022

AbstractThe most recent consensus guidelines for dosing and monitoring vancomycin recommended the use of area‐under‐the‐curve with Bayesian estimation for therapeutic monitoring. As this is a modern concept in the practice of clinical pharmacy, the main objective of this review is to introduce the fundamentals of Bayesian estimation and its mathematical application as it relates to vancomycin therapeutic drug monitoring. In addition, we aim to identify pharmacokinetic (PK) software programs that incorporate Bayesian estimation for vancomycin dosing and to describe the PK models utilized in those software programs for the adult population. Twelve software programs that utilize Bayesian estimation were identified, which included: Adult and Pediatric Kinetics, Best Dose, ClinCalc, DoseMeRx, ID‐ODS, InsightRx, MwPharm++, NextDose, PrecisePK, TDMx, Tucuxi, and VancoCalc. The software programs varied in the population PK models used as the Bayesian a priori. With the presence of various vancomycin Bayesian software programs, it is important to choose those that utilize PK models reflective of the specific patient population.
Efficacy of novel water‐absorbing polymer amended soil for improving drought resilience of Solanum lycopersicum
Authors: Rattan Bharat , Saha Abhisekh , Bordoloi Sanandam , Garg Ankit , Sahoo Lingaraj , Sekharran S. 
Published: November 2022

AbstractClimate change has exacerbated the frequency and duration of droughts. To sustain food production in such conditions, water storage and retention capacity of soil must be enhanced. Development of water‐absorbing polymer (WAP) from coal carbon residue (fly ash) can provide an economical and environmentally friendly alternative to commercial WAP for enhancing water retention and crop yield. The main objective of this study is to evaluate the growth performance of tomato species (Solanum lycopersicum L.) under continued drought conditions in the presence of in‐house developed fly ash‐based WAP (FA‐WAP) against that of commercially available WAP (Com‐WAP). Quantification of the soil–water retention curve (SWRC) revealed an increase in plant wilting time and plant‐available water content (PAWC) in the order: control soil (no amendment) < Com‐WAP‐amended soil < FA‐WAP‐amended soil. Both the WAPs positively influenced the transpiration factors of crops in terms of stomatal conductance (SC) and photosynthetic yield under continued drought conditions. The yield parameters (i.e., the number of fruits, total weight, and shoot fresh biomass) increased by 82, 106, and 115%, respectively, in the case of FA‐WAP‐amended soil as compared with that of the control. Nevertheless, FA‐WAP provided 20% higher yield of tomato species during continued drought conditions than commercial WAP. The application of FA‐WAP can be an effective strategy to impart beneficial usage of FA waste by significantly reducing the irrigation frequency and irrigation water requirement without compromising the crop yield. It also ensures sustainable water stress management for a major food crop (tomato), thereby contributing towards United Nation's Sustainable Development Goals 2, 13, and 15.
Efficient Lithium/Sodium‐Ion Storage by Core–Shell Carbon Nanospheres@TiO2 Decorate by Epitaxial WSe2 Nanosheets Derived from Bimetallic Polydopamine Composites
Authors: Qin Yifan , Zhao Zejun , Wang Teng , Li Sijia , Yan Meng , Hao Chentao , Bao Xiaobing , He Shengnan , Zhang Mingchang , Yang Yong 
Published: November 2022

AbstractMetal‐polydopamine coordination chemistry attracts great attention owing to the synergistic effect of adjustable components and advantageous structures. However, few efforts have been devoted to exploring bimetal‐polydopamine composites, especially for multistructural composites with high‐capacity components and high stability. In this regard, the TiO2@C‐WSe2 core–shell nanospheres are designed and fabricated based on Ti‐W‐polydopamine composites after selenization, in which the TiO2 nanoparticles are encapsulated or embedded in the carbon nanospheres and the external WSe2 nanosheets are grown epitaxially on the carbon surfaces, featuring multiple channels for ion diffusion and abundant active edges for electrochemical reactions. The introduction of WSe2 not only greatly improves the capacity but also results in exponential growth of the active edge. As a result, the as‐prepared TiO2@C‐WSe2 displayed long‐term cycling performance in lithium‐ion batteries. Furthermore, the anode is assembled into sodium‐ion batteries, manifesting a stable capacity of 352 mA h g−1 at 1.0 A g−1 even after 2000 cycles, one of the best performances for polydopamine‐based composites. Enhanced performance can be attributed to the synergies of high‐capacity components and different dimensional materials. This work highlights that the rational design of functional structures provides a novel inspiration for electrodes with effective nanoarchitectures.
Controlled Supramolecular Self‐Assembly Pathways by Intramolecular Rotation of D–A Molecular System toward the Signal Differentiation Detection of Toxic Vapors
Authors: Guo Yongxian , Gong Yanjun , Zhao Mei , Ping Jiantao , Yoon Juyoung , Hu Qiongzheng 
Published: November 2022

AbstractRevealing the structural evolution mechanisms of supramolecular self‐assembly can facilitate the exploitation of new self‐assembly pathways and various functional materials. Here, this work reports a unique intramolecular rotation‐induced structural evolution of supramolecular assemblies from a metastable state to a thermodynamically stable state using a twisting D–A molecule. These self‐assemblies are applied to the signal differentiation detection of toxic dimethylsulfide (DMS) vapors. The F161BT monomer of the inactive state is trapped in off‐pathway metastable nanospheres, which can disassemble and induce the transformation of the F161BT monomer into an active state by crossing the energy barrier. Subsequently, the active monomer goes through the processes of nucleation and elongation, forming thermodynamically stable on‐pathway microribbons. Adding seeds can accelerate the molecular conformational transformation, generating microribbons with controlled lengths. Opposite fluorescent responses are obtained when exposing the two aggregates to the DMS vapors, allowing the sensitive detection of DMS with enhanced selectivity, which offers tremendous potential in practical applications.
P‐Orbital Bismuth Single‐Atom Catalyst for Highly Effective Oxygen Electroreduction in Quasi‐Solid Zinc‐Air Batteries
Authors: Deng Daijie , Wu Suqin , Li Henan , Li Huaming , Xu Li 
Published: November 2022

AbstractP‐block metals have gradually been utilized to synthesize non‐noble‐metal catalysts for oxygen reduction reaction (ORR) due to the easily tunable localizedp‐orbitals and resulted versatile electronic structures. The high‐density single‐atom bismuth sites (Bi−NC) anchored onto nitrogen‐doped three‐dimensional porous carbon are proved to possess significant electrocatalytic ORR performance. Theoretical calculations unveil positively charged bismuth centers prominently improved the adsorption capacity of N‐doped carbon to O2. Theporbitals of Bi sites within Bi−NC easily generate hybrid states withporbitals of O2, thus promoting charge transfer and ultimately reducing the energy barrier of ORR. Benefiting fromp‐orbital electrons regulation of bismuth atoms, Bi−NC exhibit ORR half‐wave potential of 0.86 V (vs RHE). Additionally, both liquid and quasi‐solid zinc‐air batteries with Bi−NC as air‐cathodes achieve higher power density and specific capacity than 20 wt% Pt/C, and comparable stability and round‐trip efficiency with 20 wt% Pt/C. The discovery sheds light on the theoretical and practical guidance forp‐block metallic single‐atom catalysts.
Horn rule discovery with batched caching and rule identifier for proficient compressor of knowledge data
Authors: Wang Ruoyu , Sun Daniel , Wong Raymond , Ranjan Rajiv 
Published: November 2022

AbstractKnowledge data has been widely applied to artificial intelligence applications for interpretable and complex reasoning. Modern knowledge bases are constructed via automatic knowledge extraction from open‐accessible sources. Thus the sizes of KBs are continuously growing, heavily burdening the maintenance and application of the knowledge data. Besides the grammatical redundancies, semantically repeated information also frequently appears in knowledge bases but is still under‐explored. Existing semantic compressors fail to efficiently discover expressive patterns and thus perform unsatisfyingly on knowledge data. This article proposes SInC, a semantic inductive compressor, to efficiently induce first‐order Horn rules and semantically compress knowledge bases. SInC improves the scalability of top‐down rule mining by batching correlated records in the cache and further optimizes the pruning of duplication and specialization via an identifier structure of Horn rules. SInC was evaluated on real‐world and synthetic datasets and compared against the state‐of‐the‐art. The results show that the batched caching speed up the rule mining procedure by more than two orders while consuming fewer than three times memory space. The identifier technique speeds up the duplication and specialization pruning by orders of magnitude with less than 5‰ and 15% error rates, respectively. SInC outperforms the state‐of‐the‐art from the perspective of overall compression on both scalability and compression effect.
Noble gases in aquitard provide insight into underlying subsurface stratigraphy and free gas formation
Authors: Lightfoot Alexandra Kathryn , Stopelli Emiliano , Berg Michael , Brennwald Matthias , Kipfer Rolf 
Published: November 2022

AbstractBiogeochemical gas production resulting in free gas phase formation can severely affect groundwater and solute transport in aquifers. Such gas–water interactions are important in aquifers affected by geogenic As, which are commonly associated with biogeochemical CH4 production. Additionally, the influence of aquitards on As concentrations in contaminated aquifers has recently been challenged. These observations prompted the analysis through a heterogeneous aquitard overlying a high CH4−gas‐producing zone of an As‐contaminated aquifer. A sediment core taken through the aquitard was analyzed for noble gases to assess how the aquitard physically contributes to the underlying gas production. Results reveal that the aquitard pore space is unsaturated in two separate layers resulting in hanging pore water constrained by an air‐like gas phase. This interlayering of unsaturated and saturated zones identifies the aquitard's stratigraphy as key in determining hydrostatic pressure—a main control of free gas formation (i.e., CH4) in the underlying aquifer. The partly unsaturated conditions reduce the hydrostatic pressure by 30% compared with fully saturated conditions. To our knowledge, this is the first study applying noble gases to examine the influence of an aquitards physical state on gas production in an underlying aquifer. Further, such partly unsaturated sediment layers of low conductivity might provide preferential pathways for periodic water flow, fostering aquitard–aquifer solute transport. Groundwater samples additionally collected throughout the study site confirm more widespread degassing than previously reported. Up to 90% of the expected atmospheric noble gas concentrations is lost from groundwater immediately below the investigated sediment core.
Citizenship, Care and Choice: LGBTQ+ Intimacies in Southern Europe—An Introduction
Authors: Santos Ana Cristina 
Published: November 2022

AbstractThe Introduction offers an overview of the main issues guiding the INTIMATE research project from which the book emerged. Three main themes constitute umbrella terms structuring the book: citizenship, care and choice. Each of these themes is discussed theoretically and in relation to LGBTQ+ intimacies. The last part of the Introduction outlines and summarizes each chapter.
Italian Queer Transfeminism Towards a Gender Strike
Authors: Arfini Elia A. G. 
Published: November 2022

AbstractIn this chapter, I review a number of projects stemming from the transfeminist movement, with particular attention to Italy and a focus on the iconic practice of the gender strike. After an introduction to the field and its genealogy, I analyse examples of activism related to academic labour and gender labour that adopt a materialist analysis of the construction of gendered and sexual subjectivity. I argue that, ultimately, queer transfeminist critiques coalesce around the call for a gender strike as a way to interrupt both the extraction of value resulting from the production of genders and the violence of the social obligation to reproduce binary genders. As such, this strategy of mobilization, I argue, highlights the collective potentials and individual limits of the capacity to choose.
Uprisings: A Meditation on Feminist Strategies for Enacting the Common
Authors: de Oliveira João Manuel 
Published: November 2022

AbstractThis chapter discusses queer and feminist uprisings as way of creating a politics of the common in the scenario of the bleak perspectives of Capitalocene, neoliberal rationalities governing the economies, with hard-right conservative parties in power in several countries. Starting with the global level, the text first takes a look at feminist organizing against hard right specifically in Brazil, with the #elenao movement. Focusing on regional southern European contexts, the text analyses the Critical Pride movement in Madrid and in Left Bloc political party in Portugal. Tackling recent political and social contexts, the text looks at these two possibilities as way of counteracting (neo)liberal perspectives on identities and politics by creating a common ground with other social movements. This is a project of alliances, an enactment of the common.
The Sexual Politics of Healthy Families and the Making of Class Relations
Authors: Bertone Chiara 
Published: November 2022

AbstractThe chapter explores how healthist framings as strategies of legitimation of same-sex parenting, in which knowledge on children’s health and psychological adjustment has become a key battleground, can work at concealing class relations while reproducing them. The case of Italy, where economic inequalities are particularly dramatic for families with children, with widespread and growing child poverty, is particularly telling about the implications of invisibilizing class relations in debates and research on same-sex parenting. Connecting different strands of literature, the chapter argues that the processes of recognition of same-sex parenting needs instead to be understood as related to how current class dynamics are at play in the re-familization of care responsibilities, the therapeutic surveillance of parents and the lines of exclusion drawn by models of good parenting.
Female Migrants’ Experiences of Labour Market ‘Integration’ in Denmark
Authors: Pace Michelle , Bennetzen Katrine Sofie Bruun 
Published: November 2022

AbstractThis chapter explores the role of gender in migrants’ efforts at integrating into the labour market in Denmark. Numerous academic works argue that the experience of integration (and migration) is qualitatively different for men and women. They conclude that gender plays a critical role in the pre-migration stage, in how men and women transition across state boundaries and, most significantly, in determining the way integration bureaucracies are experienced in host societies. Such studies demonstrate that the experience of integration is gendered and often to the detriment of women. But can the experience of women also be generalisable and reveal the foundational nature and logics of a host country’s integration regime? To answer this question, the chapter empirically focuses on the biographical accounts of female migrants in Denmark and their experiences of labour market integration (LMI). Since most holders of family reunification visas in Denmark are women, their experiences confirm the extant literature’s claim that migration is a gendered process. In addition, we argue that the nature of their experiences of LMI in Denmark also reflects the foundational character of the Danish integration regime. The biographical accounts of our female narrators are analysed through the scope of turning points – as path-altering events – in their integration narratives and associated epiphanies, that is, revelations or apprehensions triggered by turning points.