bluuebunny/crossref_metadata_2025_split huggingface dataset:
(Digital Presentation) In-Depth Analysis of Interfacial Processes between Lithium Metal and Polymer Electrolyte Using Electrochemical Impedance Spectroscopy and Distribution of Relaxation Times
Authors: Lennartz Peter , Chiou Min-Huei , Thienenkamp Johannes H. , Winter Martin , Brunklaus Gunther 
Published: November 2022

Rechargeable solid-state lithium metal batteries are highly promising systems beyond lithium-ion technology, potentially affording high gravimetric and volumetric energy densities. Despite substantial progress in this field, significant challenges remain, including interfacial changes upon cell operation and achievement of reversible lithium inventory. Here, polymer electrolytes may offer flexible solutions and operational safety, providing compromises among conflicting demands of mechanical robustness and sufficient ionic conductivity, though advancements and tailored design of future polymer materials of functional layers and cell designs require input from insights into interfacial processes, characteristic charge transfer rates and associated resistances at electrode|electrolyte interfaces, respectively.
In this work, electrochemical impedance spectroscopy (EIS) is therefore carefully exploited for the analysis of relevant charge transfer processes in case of introduced polymer electrolytes[1], invoking a distribution of relaxation times (DRT) approach. The obtained complex permittivity and conductivity of the materials upon variation of temperature as well as explicit modification of the thin lithium metal electrodes with artificial polymer layers yield characteristic data of the evolution of interfacial resistances and the corresponding charge transfer reactions, in this way demonstrating the significant diagnostic strength of EIS/DRT analysis for future developments. In addition, operando EIS/DRT analysis is done upon plating of lithium metal, complemented by 7Li solid-state NMR spectra acquired at various states during lithium deposition, thereby revealing occurring species and their microstructures based on the 7Li NMR chemical shifts.
In summary, EIS/DRT analysis is utilized as powerful diagnostic technique, highlighting how to exploit observable trends of characteristic parameters at electrode|electrolyte interfaces for future design of polymer-based materials as well as high performance cell concepts.

[1]Chiou et al., Journal of Power Sources 538 (2022) 231528

Figure 1
Incorporating Heteroatom-Doped Graphene in Electrolyte for High-Performance Lithium-Sulfur Batteries
Authors: Shah Vaidik , Joo Yong Lak 
Published: November 2022

Despite dominating the current commercial energy storage landscape, Li-ion batteries are fast approaching their theoretical limit. Meanwhile, Lithium Sulphur (Li-S) batteries, owing to their ultrahigh theoretical energy density of about 2600 Whkg-1, low-cost, Earth-abundant, and environmentally friendly sulfur (S) cathode, are seen as promising replacements to realize energy densities beyond 500 Whkg-1. Despite these advantages, the large-scale implementation of Li-S technology has been stymied due to several issues, one of the most deleterious of them is the dissolution and shuttling of polysulfide intermediates during cycling resulting in severe self-discharge, lowered S utilization and coulombic efficiency. Over the past decades, substantial amount of research towards mitigating ‘polysulfide shuttling’ shuttling has been focused on cathodic modification strategies such as infiltration of S in porous carbon, metal oxide or conducting polymer scaffold matrix which retard the mobility and loss of active material. However, such simple confinement strategies have been shown to be lacking over long cycling due to the relatively weak intermolecular interactions between the host and polysulfide molecules. An effective solution comes in the form of engineering ‘sulfiphilic’ materials that adsorb polysulfide species. For example, surface modification of cathodes with rGO and functionalized carbon species have shown success in reducing the redox shuttling. However, these approaches require elaborate preparation and hence, are limited in their practical usage.
To overcome this, we propose a facile approach to improve cell performance via incorporation of functionalized graphenic species in the Li-S electrolyte. In this work, we have probed the impact of using tailored single-layer, heteroatom-doped graphene as electrolyte additives. We have studied the impact of their morphology and functionalization on the electrochemical performance of the cell. Results show a marked improvement in the discharge capacity and a high capacity retention of 84% over 105 cycles at 0.2 C cycling rate. The GCD cycle analysis showed an improvement in first cycle discharge plateau suggesting improved S utilization which was further substantiated by extensive postmortem analysis and polysulfide adsorption testing. Further, the electrolyte-modified cells showed an impressive three-fold and two-fold improvement in capacity at 1C and 2C cycling rates, respectively.
These results demonstrated that tailored heteroatom-doped graphene in the form of electrolyte additive is an effective strategy to improve electrochemical performance via enhanced polysulfide encapsulation, cell conductivity and anode stabilization. Finally, we will present the effect of heteroatom-doped graphenic species on mitigation of polysulfide shuttling and cell performance when they are incorporated in the gel electrolyte system.
Heterostructured Carbon Mesonetworks By Electrospinning
Authors: Texter John , Li Qi , Yan Feng 
Published: November 2022

Thermodynamically stable dispersions of carbon nanotubes and graphene in water are prepared at high concentrations (6-17 % by weight) by scalable liquid phase exfoliation processing using polymerized ionic liquid (PIL) stabilizers (nanolatexes, nanoparticles). This stability emanates from stabilizers that are based on imidazolium moieties that provide strong binding to the sp2 surfaces of nanocarbons while exhibiting high solvation by water. These dispersions provide means to make advanced materials and coatings exhibiting ultra-high thermal conductivity, shear switchable rheo-optical fluids, and heterostructured and high specific surface area coatings. Such advanced coatings provide a platform for catalytic membranes and electrocatalytic electrodes derived by electrospinning and further extend the utility and potential of 2D materials. We demonstrate how nonwoven mats made by electrospinning can dimensionally grow beyond the inherent 1D fibers, intrinsic to electrospinning, to provide 2D- heterostructured networks. These networks are obtained by operating close to an instability boundary, the Rayleigh instability, where fluid (electrospinning) streams decompose into droplets. Two classes of such networks are demonstrated and discussed, wherein the carrier fluid is an aqueous solution of poly(vinyl alcohol), PVA:
(i) The first is derived from aqueous graphene (2D) dispersions stabilized by 0D PIL nanolatexes (NLs) 20-30 nm in diameter. As the Plateau-Rayleigh instability is approached, the usual 1D fiber morphology transforms to (preserve) reveal the intrinsic 2D morphology of individual nanoplatelets that are connected by nanofibers.
(ii) The second is derived from aqueous MWCNT (1D) dispersions stabilized by 0D NLs. As the Plateau-Rayleigh instability is approached, on drying a heterostructured 2D network is formed, where 0D (NL) + 1D (MWCNT) yields 2D networks. These 2D “microfilms” form from collapse of multiphase fluid menisci comprising aqueous PVA solution and NLs shed from MWCNT surfaces and are supported by mini-networks of MWCNTs.
Morphology tuning, modulation of ionic and electrical conductivities, and directions for future applications are discussed. These examples provide bases for increasing network dimensionality using colloidal re-equilibration, rather than by diffusion-limited aggregation.
Análise da atratividade turística do litoral piauiense: atualização da avaliação dos atrativos turísticos, entre 2010 e 2020
Authors: Braga Solano de Souza , Guzzi Anderson , Perinotto André Riani Costa , Malta Guilherme Augusto Pereira 
Published: November 2022

O diálogo proposto sobre o potencial dos atrativos turísticos e as políticas públicas adotadas no estado do Piauí aborda algumas das questões para o turismo não se refletir em desenvolvimento nos quatro municípios do litoral piauiense, sendo eles de Ilha Grande, Luís Correia, Parnaíba e Cajueiro da Praia. A inadequação ou desconhecimento dos atrativos turísticos e do tipo de turismo planejado e pretendido pelos governos e empresários foram considerados os fatores de destaque. Para a compreensão deste cenário, optou-se pela reavaliação do potencial dos atrativos turísticos naturais e culturais com base no Inventário da Oferta Turística conduzido nos anos de 2019 e 2020. O objetivo foi comparar com o diagnóstico semelhante realizado em 2010 no Plano de Desenvolvimento Integrado do Turismo Sustentável Costa do Delta financiado pela Secretaria de Estado de Turismo do Piauí para direcionar as políticas públicas do setor. Após a análise dos dados notou-se que a espacialização da infraestrutura turística está concentrada em alguns pontos da costa e a maioria dos atrativos turísticos localizados fora desta faixa territorial foram ignorados pelos empresários e pelo poder público. Observou-se, ainda, a existência da aposta no Turismo de Sol e Praia como a única forma de atrair turistas para os municípios do litoral piauiense. Espera-se que este estudo possa ser considerado para a elaboração dos planos municipais de turismo e para o Plano de Turismo do Polo Costa do Delta, pois o Piauí tem grande e diversificado potencial para o Ecoturismo.
Peripheral Eosinophil Count Is Associated With the Prognosis of Patients With Type B Aortic Dissection Undergoing Endovascular Aortic Repair: A Retrospective Cohort Study
Authors: Zhao Kaiwen , Zhu Hongqiao , Ma Jiqing , Zhao Zhiqing , Zhang Lei , Zeng Zan , Du Pengcheng , Sun Yudong , Yang Qin , Zhou Jian , Jing Zaiping 
Published: November 2022

Background
Eosinophil count (EOS) has been proposed to provide prognostic information in multiple cardiovascular disorders. However, few researchers have investigated the predictive value of EOS for patients with type B aortic dissection who had thoracic endovascular repair.

Methods and Results

The authors reviewed the records of 912 patients with type B aortic dissection who were treated with thoracic endovascular repair in Changhai Hospital, Shanghai. By using receiver operating characteristic curve analysis, patients were divided into 2 groups based on the admission EOS cutoff value (<7.4×10
6
/L [n=505] and ≥7.4×10
6
/L [n=407]). To reduce selection bias, propensity score matching was applied. Multivariable regression analysis and Kaplan–Meier curves were performed to assess the association between EOS and long‐term outcomes. Furthermore, we investigated nonlinear correlations between EOS and outcomes using general additive models with restricted cubic splines. In the matched population, lower EOS was associated with significantly higher 30‐day mortality (4.1% vs 0%,
P
=0.007). There was no statistically difference in 30‐day adverse events between the 2 groups (all
P
>0.05). Kaplan–Meier analysis revealed that patients with an EOS <7.4×10
6
/L had a higher incidence of 1‐year all‐cause death (7.95% vs. 2.34%,
P
=0.008) and aortic‐related death (5.98% vs 1.81%,
P
=0.023) than those with higher EOS. Multivariable Cox analysis showed that continuous EOS was independently associated with 1‐year mortality (hazard ratio, 3.23 [95% CI, 1.20–8.33],
P
=0.019). In addition, we discovered a nonlinear association between EOS and 1‐year outcomes.

Conclusions
Lower admission EOS values predict higher short‐ and long‐term mortality after thoracic endovascular repair.
Public Leaderboard Feedback in Sampling Competition: An Experimental Investigation
Authors: Hudja Stanton , Roberson Brian , Rosokha Yaroslav 
Published: November 2022

Abstract
We investigate the role of performance feedback, in the form of a public leaderboard, in a sequential-sampling contest with costly observations. We show theoretically that for contests with a fixed ending date (i.e., finite horizon), providing public performance feedback may result in fewer expected observations and a lower expected value of the winning observation. We conduct a controlled laboratory experiment to test the theoretical predictions and find that the experimental results largely support the theory. In addition, we investigate how individual characteristics affect competitive sequential-sampling activity.
Peer Advice on Financial Decisions: A Case of the Blind Leading the Blind?
Authors: Ambuehl Sandro , Bernheim B. Douglas , Ersoy Fulya , Harris Donna 
Published: November 2022

Abstract
We investigate the impact of peer interaction on the quality of financial decision making in a laboratory experiment. Face-to-face communication with a randomly assigned peer significantly improves the quality of subsequent private decisions even though simple mimicry would have the opposite effect. We present evidence that the mechanism involves general conceptual learning (because the benefits of communication extend to previously unseen tasks), and that the most effective learning relationships are horizontal rather than vertical (because people with weak skills benefit most when their partners also have weak skills). The benefits of demonstrably effective financial education do not propagate to peers.
Worker Earnings, Service Quality, and Firm Profitability: Evidence from Nursing Homes and Minimum Wage Reforms
Authors: Ruffini Krista 
Published: November 2022

Abstract
This paper examines whether higher earnings for frontline workers affects the quality of employees’ output. I leverage increases in the statutory minimum wage, combined with worker, consumer, and firm outcomes in the nursing home sector. I find that higher minimum wages increase income and retention among low-wage employees and improve consumer outcomes, measured by fewer inspection violations; lower rates of adverse, preventable health conditions; and lower resident mortality. Firms maintain profitability by attracting consumers with a greater ability to pay and increasing prices for these individuals.
Decontextualized Instruction or Disembodied Reading?
Authors: Currier Elizabeth 
Published: November 2022

Abstract
Scholars agree that the book of Proverbs cannot be related to an actual performance context. Many identify literarily staged performance contexts and, therefore, speech performances in the book. The idea of an actual performance context is dismissed on the ground that no oral-performance setting can be reconstructed for any part of Proverbs. In this article, I suggest that cognitive research into how humans process language fills theoretical lacunae in approaches that limit performance context and speech performance to ancient oral settings. I propose conceptual models of performance context and speech performance that account for interpretations common among scholars that Proverbs was produced to influence readers, in spite of our inability to reconstruct ancient oral performance settings. In sum, I suggest that the communicative (if asynchronous) interaction between producers and readers (ancient to modern) can be seen as the actual (if composite and entirely cognitive) performance context of the book.
The Beatitude אַשְׁרֵי and the Confession of Sins in Psalms 32–41
Authors: van der Lugt Pieter 
Published: November 2022

Abstract
Different from the general opinion that Pss 25–34 and 35–41 represent individual cycles of poems, this article argues that the concluding cycle of Book I of the Psalter starts with Ps 32. The cycle Pss 32–41 is determined by the beatitude אַשְׁרֵי, which opens Pss 32 and 41. The cycle as a whole consists of eleven poems and represents a poetic tryptich: with its 42 poetic lines the alphabetic acrostic Ps 37 takes a central position and is framed by panels of five poems on both sides.
Phylogenetic position of Ptychaphelenchus eucalypticola Hodda, 2009 within the Aphelenchoidoidea Skarbilovich, 1947 (Siddiqi, 1980) inferred from partial 18S and 28S rDNA gene sequences
Authors: Huston Daniel C. , Khudhir Manda , Hodda Mike 
Published: November 2022

Summary
At the time of description, the morphology of Ptychaphelenchus eucalypticola Hodda, 2009 indicated it could be assigned to either the Aphelenchoididae Skarbilovich, 1947 (Paramonov, 1953) or the Parasitaphelenchidae Ruehm, 1956 (Siddiqi, 1980) within the Aphelenchoidoidea Skarbilovich, 1947 (Siddiqi, 1980). Although P. eucalypticola was, tentatively, and remains assigned to the Aphelenchoididae, its relationships with other aphelenchoids have not been reassessed, and no molecular data were previously available for this species. We re-collected P. eucalypticola from its type host and locality, Eucalyptus macrorhyncha F. Muell. ex Benth., from Mount Ainslie, ACT, Australia. We performed Bayesian inference and maximum likelihood analyses of a concatenated 18S + 28S rDNA gene sequence dataset to determine the position of P. eucalypticola within the Aphelenchoidoidea, followed by 18S and 28S single-gene analyses to further assess relationships between this species and an expanded set of close relatives. All analyses indicated P. eucalypticola is correctly assigned to the Aphelenchoididae, in a clade comprising all species of Ficophagus Davies & Bartholomaeus, 2015 and some species presently assigned to Aphelenchoides Fisher, 1894, sister to Martininema Davies & Bartholomaeus, 2015 and additional species of Aphelenchoides. Our 18S single-gene analyses did not resolve the position of P. eucalypticola relative to Aphelenchoides and Ficophagus; however, our 28S single-gene analyses indicated a sister relationship between P. eucalypticola and Ficophagus. This sister relationship is plausible as the former species shares many characteristics with species of the latter genus; however, there are sufficient morphological differences to consider P. eucalypticola as representative of a distinct lineage within the Aphelenchoidoidea.
Human Rights During the Pandemic and the National Human Rights Commission of Bangladesh
Authors: Rafid Raihan Rahman 
Published: November 2022

Abstract
The covid-19 outbreak has brought forth the existing cracks and crevices in the governance of Bangladesh. At such a time, the National Human Rights Commission of Bangladesh (nhrcb), as the only State institution mandated to protect and promote human rights exclusively and impartially, is tasked with a crucial role to ensure respect for human rights. This article assesses the activities undertaken by the nhrcb during the pandemic and finds that the nhrcb evinced only a limited role in monitoring the violation of rights and provided formulaic recommendations to the government. It did not observe the implementation of their recommendations and has performed rather formalistically. While the country has experienced a deteriorating human rights situation, the nhrcb has failed to flex its muscles when compared to other national human rights institutions in South Asia. This article argues that the national human rights institutions (nhri s) in India, Nepal and Sri Lanka, embedded in a similar context and armed with almost identical mandates, have demonstrated a novel and strenuous effort intending to adapt to and fulfil their functions during the unprecedented crisis. The nhrcb may benefit by learning from these nhri s as well as taking lessons from its own past activities. Previously, it did not eschew politically sensitive issues and earmarked a strong leadership even with limited institutional capacities. The nhrcb has however responded to the changing dynamics and challenges posed by the covid-19 pandemic with silence. It needs to become more vibrant to enhance, regionally and internationally, the country’s image in upholding human rights norms and standards.
The Political Economy of Hegemonic Masculinity: Race, Income, and Housework in the United States
Authors: Small Sarah F. 
Published: November 2022

Macrocultural dynamics of hegemonic masculinity complicate microeconomic negotiations. In this article, I examine hegemonic masculinity as an explanatory framework to understand how gendered work in households differs along income and race dimensions. I use Panel Study of Income Dynamics data to demonstrate how men of different race and income groups respond to their female partner out-earning them, an economic threat to masculinity. Results indicate that upper-income couples with White men have a strong aversion to the situation in which a woman out-earns her male partner. Middle-income White men follow suit, but lower-income White men, and Black men in most income groups, do not. I discuss how these findings relate directly to power, patriarchy, and the hegemonic nature of hegemonic masculinity. JEL Classification: B54, J15, J16
Psychiatrist and trainee moral injury during the organisational long COVID of Australian acute psychiatric inpatient services
Authors: Looi Jeffrey CL , Maguire Paul A , Kisely Stephen R , Allison Stephen 
Published: November 2022

Objective This paper provides a commentary on the risk of moral injury amongst psychiatrists and trainees working in the acute psychiatric hospital sector, during the third winter of the COVID-19 pandemic. Conclusions Moral injuries arise from observing, causing or failing to prevent adverse outcomes that transgress core ethical and moral values. Potentially, morally injurious events (PMIEs) are more prevalent and potent while demand on acute hospitals is heightened with the emergence of highly infectious SARS-CoV-2-Omicron subvariants (BA.4 and BA.5). Acute hospital inpatient services were already facing extraordinary stresses in the context of increasingly depleted infrastructure and staffing related to the pandemic. These stresses have a high potential to be morally injurious. It is essential to immediately fund additional staff and resources and address workplace health and safety, to seek to arrest a spiral of moral injury and burnout amongst psychiatrists and trainees. We discuss recommended support strategies.
A review of the novel tissue factor antibody–drug conjugate: Tisotumab vedotin
Authors: Luu Kevin , Chu Angelyne , Chang Brandon 
Published: November 2022

Objective To review and compare the pharmacology, efficacy, and safety of the novel tissue factor antibody–drug conjugate, tisotumab vedotin Data sources Literature search was performed through PubMed MEDLINE, Google Scholar, ClinicalTrials.gov, and the Food and Drug Administration. Data summary Tisotumab vedotin, a novel tissue factor antibody–drug conjugate, was granted accelerated approval by the US FDA on 20 September 2021 for adult patients with recurrent or metastatic cervical cancer with disease progression on or after chemotherapy. Tisotumab vedotin demonstrated clinical efficacy in a number of solid tumors in innovaTV 201 and more specifically in cervical cancer in the pivotal phase 2 innovaTV 204. In the single-arm innovaTV 204 study, 101 patients with recurrent or metastatic cervical cancer received intravenous tisotumab vedotin at the recommended dose of 2 mg/kg every 3 weeks until disease progression or unacceptable toxicity. The independent review committee confirmed an objective response rate of 24% with 7% complete responses and 17% partial responses. Tisotumab vedotin is associated with several notable adverse events with data from innovaTV 204 including ocular toxicity, hemorrhage, and peripheral neuropathy. Ninety-two percent of patients experienced treatment-related adverse events with 28% experiencing an adverse event of grade 3 or higher. Conclusions Metastatic cervical cancer has a high risk of relapse with few effective second-line therapeutic options. Current guidelines recommend single agent tisotumab vedotin as a possible option. Ongoing trials will further define its place in therapy.