bluuebunny/crossref_metadata_2025_split huggingface dataset:
Dans les interstices et les plis du tissu urbain, une « microruine »
Authors: Jauréguiberry Anne , Tremblin Mathieu 
Published: July 2023

En mai 2021, l’association Va Jouer Dehors rassemble à Marseille des équipes de praticien·ne·s, enseignant·e·s et étudiant·e·s ambassadrices de six villes pour constituer « la plus grande agence internationale d’architecture du monde ». Au sein d’une ruine industrielle, soixante-dix participant·e·s formulent des hypothèses sur les possibilités de « réparer la ville » avec le contexte de crise sanitaire et climatique en arrière-plan. Poursuivant les pistes de réflexion ébauchées au milieu des gravas, un arpentage du Vieux Port devient le point de départ d’une conversation entre l’architecte et urbaniste Anne Jauréguiberry et l’artiste-chercheur Mathieu Tremblin. À partir d’une lecture inframince de l’espace, iels interprètent l’attachement des artistes urbains aux traces d’usage et d’usure dans la ville. Une sorte de « micro-ruine » se déploie au sein de la ville rénovée à une échelle moindre. Elle se niche dans les interstices et les plis du tissu urbain pour déployer son lent processus de transformation de l’environnement urbain.
Multi‐Material Aerosol Jet Printing of Al/Cuo Nanothermites for Versatile Fabrication of Energetic Antennas
Authors: Gamba Livio , Lajoie Justin A. , Sippel Travis R. , Secor Ethan B. 
Published: July 2023

AbstractIn the present study, a nanoscale Al/CuO thermite system is patterned using a multi‐material aerosol jet printing technology. Morphological analysis of samples manufactured with different printing configurations reveal a strong effect of the printhead design on microstructure and degree of mixing between the constituent materials, providing insight on fundamental mechanisms of inline aerosol‐phase mixing during printing. The high‐resolution patterning capability of aerosol jet printing is leveraged to fabricate both blended nanoscale Al/CuO thermites and antennas containing the nanothermite, which exhibit rapid and low‐energy ignition upon exposure to a 2.45 GHz free space electromagnetic field, characterized by an ignition delay of ≈130 ms and ignition energy of ≈216 J. Moreover, the versatility of this approach is demonstrated by manufacturing compositionally graded samples, establishing multi‐material aerosol jet printing as a compelling and versatile platform for microscale energetic device fabrication with broader utility for graded materials. This work shows promise for use of the technique for in situ manufacturing of standalone and integrated energetics and electromagnetic devices.
Overcoming Obstacles in Zn‐Ion Batteries Development: Application of Conductive Redox‐Active Polypyrrole/Tiron Anolyte Interphase
Authors: Luo Mingwu , Gan Xiongri , Zhang Chenran , Yang Yabin , Yue Wan , Zhitomirsky Igor , Shi Kaiyuan 
Published: July 2023

AbstractThis study is focused on overcoming obstacles in the implementation of metallic Zn for zinc‐ion batteries. The major limiting factors of Zn anodes include dendrite growth, hydrogen evolution, and by‐product formation. Herein, the challenges are addressed by the application of a redox‐active electrode‐electrolyte interphase. Cationic polypyrrole(PPy)/anionic Tiron anolyte is formulated as the mixed conducting interphase to push the limits of zinc‐based energy storage. The doping/de‐doping behavior of PPy stimulates the surface adsorption/desorption of Tiron attributed to the ion‐induced nucleation. Testing results show that PPy as a passivating corrosive‐resistant layer improves the interfacial stability of Zn metal; while releasing the redox‐active anolyte boosts the charge transfer of cells by the phenol‐quinone transformations. The Zn//Zn cells demonstrate an improved life from 50 to 2500 cycles with a reduced overpotential at 2 mA cm−2 and 1 mAh cm−2. In situ UV–vis spectroscopic measurements, combined with density functional theory calculations, address the redox mechanisms of PPy/Tiron anolyte. The testing of α‐MnO2//Zn cells shows that the PPy/Tiron anolyte exhibits enhanced capacity and rate performance due to the pseudocapacitive effects. This study unveils a conceptually new approach based on the modification of conducting polymer with redox‐active dopants toward the fabrication of high‐performance Zn‐anolyte batteries.
Translational mRNA Profiling Analysis of Pseudopalisading Cells in Bevacizumab Resistance of GBM
Authors: Kim Yejin , Kim Tae Hoon , Sreynet Srun , Oh Yong Seok , Nam Do‐Hyun , Park Jong Bae , Kim Sung Soo 
Published: July 2023

AbstractGlioblastoma (GBM) is a malignant brain tumor with a poor prognosis that easily recurs. The antiangiogenic agent bevacizumab is used to treat recurrent GBM. However, GBM treated with bevacizumab easily rebounds due to evasive mechanisms that induce resistance to treatment, such as hypoxia‐inducible factor (HIF) associated pathways. The transcription factor HIFs are oxygen‐dependent and are degraded via the ubiquitin‐dependent proteasomal pathway. Therefore, it is necessary to study bevacizumab resistance with HIF‐associated pathways through translational mRNA profiling. This work applies a hypoxia response element (HRE) promoter to the ribosome affinity purification (TRAP) system for hypoxia‐specific translational mRNA profiling analysis. Here, this work analyzes the translatome of pseudopalisading cells in the brain samples of orthotopic mouse models using hypoxia‐responsive 5× HRE‐TRAP system to investigate the molecular mechanism of drug resistance on pseudopalisading cells around the necrotic area induced by bevacizumab resistance. The translatomic analysis result shows that pseudopalisading cells exhibit notable enrichment of gene sets associated with neurodegenerative diseases, such as Alzheimer's disease. The outcomes of this study enhance clinical relevance, meaning that the translatomic analysis result of pseudopalisading cells during bevacizumab treatment‐induced resistance provides new insight into a promising approach for developing targeted therapeutics.
Impacts of vegetation and topsoil removal on soil erosion, soil moisture, and infiltration
Authors: DeVilleneuve Stephanie , Kelly Austin , Miyanaka Noriki , Shanmuhasundaram Thiruvikram , Murphree Parker , Wyatt Briana M. 
Published: July 2023

AbstractSoil erosion by water is a critical environmental problem that affects a large land area globally and is expected to increase substantially as a result of climate change‐induced rainfall intensification. This study sought to determine the impacts of soil mechanical disturbance and topsoil removal on soil erosion and deposition, soil moisture, soil water infiltration, and vegetation type in a central Texas subtropical grassland setting. The removal of topsoil increased soil erosion and caused changes in soil texture, soil moisture, infiltration rate, and the vegetation community within the disturbed area. Soil texture shifted from clay to sand dominated as sand particles were eroded from an upland area. This shift in soil texture led to decreased volumetric soil moisture (−14.6%) as compared to an adjacent undisturbed location. The removal of topsoil also led to an invasion of non‐native grasses that now dominate the vegetated portions of the disturbed area. Erosion and deposition measurements indicated an uneven gain and loss of soil across the disturbed area, but on average 0.85 cm of sand was deposited during the 1‐month study period. Our results show that high levels of erosion are occurring and degrading the immediate landscape, which is likely contributing a large amount of sediment to a nearby waterway, posing a potential water quality threat to an important surface water body.
Functional traits and water‐transport strategies of woody species in an insular environment in a tropical forest
Authors: Castelar João Victor S. , Da Cunha Maura , Simioni Priscila F. , Castilhori Marcelo F. , Lira‐Martins Demetrius , Giles André L. , Costa Warlen S. , Alexandrino Camilla R. , Callado Cátia H. 
Published: July 2023

AbstractPremisePlants survive in habitats with limited resource availability and contrasting environments by responding to variation in environmental factors through morphophysiological traits related to species performance in different ecosystems. However, how different plant strategies influence the megadiversity of tropical species has remained a knowledge gap.MethodsWe analyzed variations in 27 morphophysiological traits of leaves and secondary xylem inErythroxylum pulchrumandTapirira guianensis, which have the highest absolute dominance in these physiognomies and occur together in areas of restinga and dense ombrophilous forest to infer water‐transport strategies of Atlantic Forest woody plants.ResultsThe two species presented different sets of morphophysiological traits, strategies to avoid embolism and ensure water transport, in different phytophysiognomies.Tapirira guianensisshowed possible adaptations influenced by phytophysiognomy, whileE. pulchrumshowed less variation in the set of characteristics between different phytophysiognomies.ConclusionsOur results provide essential tools to understand how the environment can modulate morphofunctional traits and how each species adjusts differently to adapt to different phytophysiognomies. In this sense, the results for these species reveal new species‐specific responses in the tropical forest. Such knowledge is a prerequisite to predict future development of the most vulnerable forests as climate changes.
Surface functionalized Fe3O4‐polyacrylamide dispersion for improved oil recovery at harsh conditions
Authors: Haruna Maje Alhaji , Wen Dong‐sheng 
Published: July 2023

AbstractWith the growing demand for energy supply and the natural decline of oil reservoirs, the development of new enhanced oil recovery (EOR) techniques become more and more critical. Polymer flooding EOR is one of the most successful chemical EOR methods but suffers many drawbacks at high temperatures and high salinity (HT‐HS) conditions. Superparamagnetic nanoparticles (NPs) have been recently investigated for subsurface applications, including in EOR, due to their unique physicochemical properties. Their applicability under harsh reservoir conditions, however, is yet to be examined. In this work, a novel approach is developed to synthesize superparamagnetic Fe3O4 (NPs) with unique surface functionalization (SMag‐NPs) and to form stable polyacrylamide (PAM) dispersions (SMag‐NPs‐PAM). Both stability and core flooding experiment results demonstrate the promising future of the new dispersion. The SMag‐NPs‐PAM dispersion is not only stable at HT‐HS conditions, but also show excellent EOR capability at HT‐HS by recovering, 61.72% of the initial oil quantity, which is significantly higher than those from conventinal NPs‐PAM disperison and pure PAM fluid. These findings show the promising application potential of SMag‐NPs‐PAM for improving oil recovery in challenging HT‐HS reservoir conditions.
Children with autism spectrum disorder who demonstrate normal language scores use a bottom‐up semantic processing strategy: Evidence from N400 recordings
Authors: Phan Lee , Tariq Alina , Lam Garbo , Mirza Maaz , Paiva Dylan , Lazic Milan , Emami Zahra , Anagnostou Evdokia , Gordon Karen A. , Pang Elizabeth W. 
Published: July 2023

AbstractIntroductionThe N400 is an electrophysiological component that reflects lexical access and integration of words with mental representations.MethodsThirty‐five young children with a range of language capabilities (n = 21 neurotypical controls, 10 males, mean age = 6.3 ± 0.9 years; n = 14 children with autism, 12 males, mean age = 6.4 ± 1.1 years) completed an auditory semantic categorization paradigm to evoke the N400. Electroencephalograph (EEG) data were acquired with a 64‐channel electrode cap as children listened via ear inserts to binaurally presented single syllable words and decided whether the words were congruent (in) or incongruent (out) with a pre‐specified category. EEG data were filtered, epoched, and averaged referenced, and global field power (GFP) was computed. The amplitude of the N400 peak in the GFP was submitted to a multiple linear regression analysis.ResultsN400 amplitude was found to predict language scores only for the children with ASD who have language scores in the normal range (r2 = 0.72).ConclusionsThis finding that N400 amplitude only predicted language scores in children with ASD and normal language scores suggests that these children may rely more on basic semantic processing (as reflected by the N400) and less on anticipating and predicting upcoming words. This suggests preferential utilization of a bottom‐up strategy to access higher order language.
Design, in Silico Studies and Biological Evaluation of New Chiral Thiourea and 1,3‐Thiazolidine‐4,5‐dione Derivatives
Authors: Evyapan Samet , Oruç‐Emre Emine Elçin , Sıcak Yusuf , Karaküçük‐İyidoğan Ayşegül , Yılmaz Gizem Tatar , Öztürk Mehmet 
Published: July 2023

AbstractIn this study, new chiral thiourea and 1,3‐thiazolidine‐4,5‐dione derivatives were synthesized, it was aimed to evaluate the various biological activities and molecular docking of these compounds. Firstly, the new thioureas (1–16) were obtained by reacting 1‐naphthylisothiocyanate with different chiral amines. Then, the chiral thioureas were cyclized with oxalyl chloride to obtain 1,3‐thiazolidine‐4,5‐dione derivatives (17–32). All compounds were evaluated with several in vitro antioxidant and enzyme inhibition activities. Compound 30 was the most active compound against AChE, with a value of IC50=8.09±0.58 μM. On the other hand, all compounds were tested in silico absorption, distribution, metabolism, and excretion (ADME) assays to better understand their bioavailability. These physicochemical properties, pharmacokinetics, and drug‐likeness of all compounds were calculated using SwissADME. Furthermore, according to molecular docking analyses compound 30 exhibited significant binding affinities for all enzymes. Based on our overall observations, compound 30 could be recommended as a potential lead for the therapuetic of Alzheimer's.
First‐principles Assessment of the Role of Water in the Reduction Half Cycle of Low‐Temperature NH3‐SCR over Cu‐CHA
Authors: Contaldo Gabriele , Ferri Matteo , Negri Chiara , Nova Isabella , Maestri Matteo , Tronconi Enrico 
Published: July 2023

AbstractDispersion corrected density functional theory calculations show that the presence of H2O in the Reduction Half‐Cycle (RHC) of NH3‐SCR affects the free energy of the kinetically‐relevant transition state (TS) leading to a reduction in the rate and activation energy with respect to dry conditions. In particular, H2O enthalpically stabilizes the kinetically‐relevant TS by 20 kJ mol−1 with respect to the dry counterpart. Such enthalpic stabilization vanishes when van der Waals (vdW) interactions are excluded from the calculations, thus showing the preeminent role of non‐specific dispersion forces in the reduction of the activation enthalpy. At the same time, the enthalpic stabilization is more than compensated by the additional entropy losses of the TS brought forth by the presence of H2O in the CHA cage. Calculated enthalpy and entropy changes with respect to the dry case agree quantitatively with the experimental measurements and reflect the modified reacting environment in the presence of H2O. As a result, this study provides theoretical underpinnings on the mechanistic role of H2O in the RHC and, on a more general basis, highlights the importance of the molecular scale description of the reaction environment in voids of molecular dimensions.
Electrochemical Aldehyde Oxidation at Gold Electrodes: gem‐Diol, non‐Hydrated Aldehyde, and Diolate as Electroactive Species
Authors: Bondue Christoph J. , Spallek Marius , Sobota Lennart , Tschulik Kristina 
Published: July 2023

AbstractTo date the electroactive species of selective aldehyde oxidation to carboxylates at gold electrodes is usually assumed to be the diolate. It forms with high concentration only in very alkaline electrolytes, when OH− binds to the carbonyl carbon atom. Accordingly, the electrochemical upgrading of biomass‐derived aldehydes to carboxylates is believed to be limited to very alkaline electrolytes at many electrode materials. However, OH−‐induced aldehyde decomposition in these electrolytes prevents application of electrochemical aldehyde oxidation for the sustainable upgrading of biomass to value‐added chemicals at industrial scale. Here, we demonstrate the successful oxidation of aliphatic aldehydes at a rotating gold electrode at pH 12, where only 1 % of the aldehyde resides as the diolate species. This concentration is too small to account for the observed current, which shows that also other aldehyde species (i. e., the geminal diol and the non‐hydrated aldehyde) are electroactive. This insight allows developing strategies to omit aldehyde decomposition while achieving high current densities for the selective aldehyde oxidation, making its future industrial application viable.
Green Turtle (Chelonia mydas) Blood and Scute Trace Element Concentrations in the Northern Great Barrier Reef
Authors: Wilkinson Adam , Ariel Ellen , van de Merwe Jason , Brodie Jon 
Published: July 2023

Abstract
Marine turtles face numerous anthropogenic threats, including that of chemical contaminant exposure. The ecotoxicological impact of toxic metals is a global issue facing Chelonia mydas in coastal sites. Local investigation of C. mydas short-term blood metal profiles is an emerging field, while little research has been conducted on scute metal loads as potential indicators of long-term exposure. The aim of the present study was to investigate and describe C. mydas blood and scute metal profiles in coastal and offshore populations of the Great Barrier Reef. This was achieved by analyzing blood and scute material sampled from local C. mydas populations in five field sites, for a suite of ecologically relevant metals. By applying principal component analysis and comparing coastal sample data with those of reference intervals derived from the control site, insight was gleaned on local metal profiles of each population. Blood metal concentrations in turtles from coastal sites were typically elevated when compared with levels recorded in the offshore control population (Howick Island Group). Scute metal profiles were similar in Cockle Bay, Upstart Bay, and Edgecumbe Bay, all of which were distinct from that of Toolakea. Some elements were reported at similar concentrations in blood and scutes, but most were higher in scute samples, indicative of temporal accumulation. Coastal C. mydas populations may be at risk of toxic effects from metals such as Co, which was consistently found to be at concentrations magnitudes above region-specific reference intervals. Environ Toxicol Chem 2023;42:2375–2388. © 2023 The Authors. Environmental Toxicology and Chemistry published by Wiley Periodicals LLC on behalf of SETAC.
Applicability of Chronic Multiple Linear Regression Models for Predicting Zinc Toxicity in Australian and New Zealand Freshwaters
Authors: Stauber Jennifer L. , Gadd Jennifer , Price Gwilym A. V. , Evans Anthony , Holland Aleicia , Albert Anathea , Batley Graeme E. , Binet Monique T. , Golding Lisa A. , Hickey Chris , Harford Andrew , Jolley Dianne , Koppel Darren , McKnight Kitty S. , Morais Lucas G. , Ryan Adam , Thompson Karen , Van Genderen Eric , Van Dam Rick A. , Warne Michael St. J. 
Published: July 2023

Abstract
Bioavailability models, for example, multiple linear regressions (MLRs) of water quality parameters, are increasingly being used to develop bioavailability-based water quality criteria for metals. However, models developed for the Northern Hemisphere cannot be adopted for Australia and New Zealand without first validating them against local species and local water chemistry characteristics. We investigated the applicability of zinc chronic bioavailability models to predict toxicity in a range of uncontaminated natural waters in Australia and New Zealand. Water chemistry data were compiled to guide a selection of waters with different zinc toxicity-modifying factors. Predicted toxicities using several bioavailability models were compared with observed chronic toxicities for the green alga Raphidocelis subcapitata and the native cladocerans Ceriodaphnia cf. dubia and Daphnia thomsoni. The most sensitive species to zinc in five New Zealand freshwaters was R. subcapitata (72-h growth rate), with toxicity ameliorated by high dissolved organic carbon (DOC) or low pH, and hardness having a minimal influence. Zinc toxicity to D. thomsoni (reproduction) was ameliorated by both high DOC and hardness in these same waters. No single trophic level–specific effect concentration, 10% (EC10) MLR was the best predictor of chronic toxicity to the cladocerans, and MLRs based on EC10 values both over- and under-predicted zinc toxicity. The EC50 MLRs better predicted toxicities to both the Australian and New Zealand cladocerans to within a factor of 2 of the observed toxicities in most waters. These findings suggest that existing MLRs may be useful for normalizing local ecotoxicity data to derive water quality criteria for Australia and New Zealand. The final choice of models will depend on their predictive ability, level of protection, and ease of use. Environ Toxicol Chem 2023;42:2614–2629. © 2023 The Authors. Environmental Toxicology and Chemistry published by Wiley Periodicals LLC on behalf of SETAC.