bluuebunny/crossref_metadata_2025_split huggingface dataset:
The crystal structure of 18-crown-6 ― tetraaqua-dichlorido-di-μ2-chloridodicopper(II) (2/1), C12H32O10Cu2Cl4
Authors: Liu Zhaolong , Jin Shifeng 
Published: September 2023

Abstract
C12H32O10Cu2Cl4, monoclinic, P21/n (no. 14), a = 9.0202(4) Å, b = 9.5791(4) Å, c = 13.6994(6) Å, β = 92.555(1)°, V = 1182.53(9) Å3, Z = 2, R
gt(F) = 0.0308, wR
ref(F
2) = 0.0800, T = 293(2) K.
Online news platforms still matter: generational news consumption patterns during the 2020 presidential election
Authors: Ray Rik 
Published: September 2023

Abstract

Purpose
Gen Z or younger news audiences are believed to contribute to declining news consumption as a result of decreased news interest and reduced trust, particularly in political news. It can have adverse consequences for democratic processes. This study offers a more nuanced perspective by qualifying the role of context, and generational differences and similarities in online political news consumption patterns before and after the 2020 US presidential election, which witnessed a series of unprecedented events in the country’s history.

Design/methodology/approach
To investigate these patterns, I use US aggregated website visitation data from Comscore in a quasi-experimental interrupted time series design, leveraging the 2020 election as a natural experimental condition.

Findings
While Gen Z are indeed consuming considerably less news, contrary to assumptions, there was significantly increased engagement with news websites following the election. Additionally, media audiences across generations are likely to reduce social media use during such events.

Implications
Major political events can significantly influence media use patterns such as the extent of news consumption in general and political news in particular, something not often considered in media effects-oriented research. There is also an urgent need to review and reassess our definitions of news, news sources, and its audience.

Originality/value
By using observational data in a quasi-experimental design, this study offers a more precise and refined perspective of generational patterns of online political news consumption in the context of a major political event that both corroborates as well as challenges some our existing notions of media use.
Experimental measurements of X-rays emission cross sections induced by photons
Authors: Taïbouni Nabila , Amokrane Arezki , Azli Tarek , Mohammed Larbi Ben Amor , Belouadah Naima , Boukeffoussa Khelifa , Medour Camelia Yasmine , Zouad Hamza , Messaoudi Mohammed 
Published: September 2023

Abstract
The energy-dispersive X-ray fluorescence (ED-XRF) technique has been used for measurements of K

α
, K

β
, and total K X-rays emission cross sections induced by photons, as well as K-shell fluorescence yields for pure elements with 22 ⩽ Z ⩽ 49. These metals have been irradiated at 59.54 KeV excitation energy from an 241Am annular radioactive source. The characteristic K X-rays emitted by the targets have been detected with a Silicon drift detector (SDD); the net areas of the K

α
and K

β
spectral peaks have been determined using the fitting process of PYMCA software. The obtained experimental values of the K X-ray fluorescence cross sections and the K-shell fluorescence yields were compared to the theoretical calculated ones and also to the experimental results obtained from a different experimental setup using a point source. The obtained values were between (6.84 ± 0.55 b/at.) and (891.0 ± 67.5 b/at.) for pure metals form Scandium to Indium. Experimental values were in good agreement with theoretical values within limits of uncertainty, as well as with the data reported in the literature. Moreover, the experimental determination of K X-ray fluorescence cross-section of scandium (Sc) at 59.54 KeV has not been preceded as far as we know. The value obtained is (6.84 ± 0.55 b/at). This new result obtained maybe contribute to the enrichment of the available databases.
Gestational diabetes mellitus is associated with a low serum level of mitochondrial-derived peptide-MOTS-C
Authors: Özer Serdar , Alkan Baylan Filiz , Tok Abdullah 
Published: September 2023

Abstract

Objectives
Although MOTS-C has been reported to have a role in diabetes mellitus, no human studies have evaluated the serum level of MOTS-C in GDM. It was aimed to investigate serum levels of MOTS-C in patients with gestational diabetes mellitus (GDM).

Methods
Comparisons were made of 44 pregnant patients diagnosed with GDM and a control group of 44 healthy pregnant women in respect of serum MOTS-C, insulin, and glucose levels, and serum lipid profile.

Results
A significantly higher level of fasting serum glucose and significantly lower serum levels of MOTS-C and high density lipoprotein were determined in the GDM group compared to the control group (p<0.05 for all). A cut-off value of 173.5 ng/mL for serum MOTS-C level had sensitivity of 81.8 % and specificity of 61.4 % for GDM diagnosis (p<0.001). A significant correlation was determined between the serum MOTS-C and serum glucose levels (r=−0.239, p=0.025).

Conclusions
For the first time in literature, the results of this study showed that patients with GDM had a decreased serum level of MOTS-C and that increasing serum MOTS-C levels were associated with a decrease in serum glucose levels, thereby supporting the view that mitochondrial dysfunction plays a role in GDM pathogenesis. Therefore, MOTS-C could be a promising diagnostic biomarker for GDM cases.
Crystal structures and luminescence properties of Li6
MN4:Ce3+ (M = Mo, W)
Authors: Klotz Martin , Seibald Markus , Baumann Dominik , Wurst Klaus , Heymann Gunter , Huppertz Hubert 
Published: September 2023

Abstract
The compounds Li6MoN4 and Li6WN4 were prepared from the reactants M (M = Mo, W) and Li3N in a radiofrequency furnace at 1000 °C. The lithonitridometallates crystallize in the tetragonal system with the lattice parameters: a = 6.6844(1), c = 4.9294(1) Å for Li6WN4 based on single-crystal X-ray diffraction data and a = 6.6611(3), c = 4.9338(3) Å for Li6MoN4 taken from powder X-ray diffraction data. Colorless to slightly reddish single-crystals of the tungsten compound were isolated and the crystal structure was refined in the space group P42/nmc (no. 137) with Z = 2 and the powder X-ray data of the molybdenum compound were analyzed by a Rietveld refinement. Both structures belong to the Li6[ZnO4] type published by Hoppe et al. in 1987 (Untenecker H., Hoppe R. Z. Anorg. Allg. Chem. 1987, 551, 147–150) and could be doped with Ce3+ for the first time. The investigated compounds show a reddish color impression upon UV to blue irradiation and exhibit a broad emission band with a maximum at λ
max = 693 nm (fwhm 97 nm) for Li6MoN4 and at λ
max = 653 nm (fwhm 133 nm) for Li6WN4.
Antioxidative effects of vitamin D in muscle dysfunction
Authors: Russo Cristina , Valle Maria Stella , Malaguarnera Lucia 
Published: September 2023

Graphical abstract

Abstract
Pathological conditions characterized by systemic inflammation and oxidative stress can often impair the muscle cells efficiency. The gradual decline of muscle mass and tone drastically reduces the motor skills of the patient affecting the simplest daily activities. Muscle dysfunction, resulting in the deterioration of muscle tissue, can lead to a serious situation of muscle wasting that can evolve into sarcopenia. In addition, muscle dysfunction causing metabolic disorders impairs the quality of life. The function of skeletal muscle is deeply conditioned by environmental, nutritional, physical, and genetic factors. Proper nutrition with balanced protein and vitamins intake and an active lifestyle helps to strengthen tissues and counteract pathological conditions and generalized weakness. Vitamin D performs antioxidant actions, indispensable in skeletal muscle. Epidemiological data indicate that vitamin D deficiency is a widespread status in the world. Vitamin D deficiency induces mitochondrial failure, reduced production of adenosine triphosphate, oxidative injury, and compromised muscle function. Among the different types of antioxidants, vitamin D has been identified as the main compound that can improve the effectiveness of the treatment for muscle weakness and improve conditions related to sarcopenia. The purpose of this review is to analyze molecular processes used by vitamin D against oxidative stress and how it can affect muscle function in order to assess whether its use as a supplement in inflammatory pathologies and oxidative stress can be useful to prevent deterioration and improve/maintain muscle function.
Effect of a hospital-based maternal counseling guide on exclusive breastfeeding practices in Anambra State, Nigeria: A protocol for a cluster-randomized controlled trial (HOME Trial)
Authors: Maureen Ugonwa Anetoh , Chisom God’swill Chigbo , Chinazom Cynthia Agujiobi , Benjamin Maduabuchukwu Aniugbo , Rita Oluebubechukwu Atakulu , Amarachi Triumph Nwabanne , Ifeoma Blessing Umeh , Chijioke Maxwell Ofomata , Noreen Ebelechukwu Agbapuonwu Noreen Ebelechukwu , Lydia Ijeoma Eleje , Brian Onyebuchi Ogbonna , Chinyere Ukamaka Onubogu , George Uchenna Eleje , Obinna Ikechukwu Ekwunife , Izuchukwu Loveth Ejie 
Published: September 2023

Background: Optimal breastfeeding is so critical that it could save the lives of over 820,000 children under the age of five years each year. For optimal growth, development, and health, the WHO recommends Exclusive Breastfeeding (EBF) in the first six months. To ensure nursing mothers breastfeed their children exclusively, they should also have access to skilled practical help to build mothers’ confidence and prevent or resolve breastfeeding problems. Interventions promoting optimal Infant and Young Child Feeding practices could prevent 19% of under-five deaths, and such intervention could improve nursing mothers’ understanding and practice of EBF. Objective: This trial is designed to formulate a hospital-based counseling guide on EBF, implement it, and determine its effect on improving EBF practice in Anambra State, Nigeria. Methods: The study is a cluster randomized controlled trial conducted in selected hospitals in Anambra State, Nigeria. Based on inclusion criteria, 12 hospitals that offer comprehensive ante-natal and post-natal clinic services and have a higher population of women assessing care in the ante- and post-natal clinics were selected for the study. Six hospitals each were randomized to either the intervention or the control arm. The intervention hospitals received the formulated hospital-based counseling guide and the hospital’s usual care, while the control hospitals received only the hospital’s usual care. Statistical analysis will be conducted using Statistical Package for Social Science (SPSS version 25). Descriptive statistics will be used to summarize and present demographic and clinical characteristics. Categorical variables will be expressed as frequencies or percentages and quantitative variables as means, standard deviations, median, and interquartile ranges. An intention-to-treat analysis will be conducted.
Displacement Hazard from Distributed Ruptures in Strike-Slip Earthquakes
Authors: Rodriguez Padilla Alba Mar , Oskin Michael E. 
Published: September 2023

ABSTRACTWidespread distributed fracturing during earthquakes threatens infrastructure and lifelines. We combine high-resolution rupture maps from the five major surface-rupturing strike-slip earthquakes in southern California and northern Mexico since 1992 to incorporate the displacements produced by distributed ruptures into a probabilistic displacement hazard analysis framework. Through analysis of the spatial distribution of mapped ruptures and displacements for each of these events, we develop a magnitude-dependent expression for the probability per unit area of finding a distributed rupture that accommodates a displacement that exceeds a displacement threshold at a given distance from the principal fault. Our model is best applied to estimating expected distributed displacements for strike-slip earthquakes, similar to those analyzed, with widespread ruptures across immature fault zones.
New technologies in the financial industry: case of Poland
Authors: Iwanicz-Drozdowska Małgorzata , Cichowicz Ewa , Cicirko Marianna , Kawiński Marcin , Nowak Agnieszka K. 
Published: September 2023

This study evaluates the scope and consequences of the application of new technologies (NTs) within the Polish banking and insurance sectors and thus contributes to the knowledge of CEE financial market development. The goal is to understand the implementation of particular NTs in two different sectors and identify the motivations, strategies, phases of realisation and cost efficiency depending on the institution’s size. The detail of the study requires the use of qualitative research methods. In-depth interviews are employed to figure out the criteria based on which decisions to implement NTs are made. The findings indicate that the primary objective of NT implementation is to respond to customers’ needs, followed by cost-cutting and achieving more efficient internal processes. The application of artificial intelligence (AI) and machine learning (ML) in risk management areas is still a work in progress. In the next five years cloud computing is expected to become the most important NT and thus will have to meet numerous regulatory requirements.
Studying Religion Critically in Universities and Schools: Bridging the Gap?
Authors: Alberts Wanda 
Published: September 2023

The article tries to identify the place of the critical Study of Religion in universities and schools, comparing examples for different recent developments in Germany and Britain. One decisive issue in this respect is the question if the critical Study of Religion as a discipline or as (critical) education about Religion is visible at all and if the differences to other, often much better known (often religious) approaches are acknowledged or played down. The discussed examples (a judgement of the German Federal Constitutional Court on the religious limitation of the academic freedom of professors of theology, the BA report on Theology and Religious Studies Provision in UK Higher Education and the report of the Commission on Religious Education) highlight some subtleties of a complex field where important facts and distinctions remain concealed to non-specialists. With respect to RE, the article argues that these dynamics fit the concept of "small-i-indoctrination". Referring to Katharina Frank’s empirical research on the communication of knowledge about religion (Religionskunde) it spells out the important distinctions that need to be made explicit in order to make the characteristics of a critical (secular) approach better known.
Estimation of Genetic Variability and Character Association Analysis of Underutilized Ornamental Canna Lily (Canna indica L.)
Authors: Baranidharan R. , Lourdusamy D. Keisar , Aruna P. , Rajamani K. , Chandrakumar K. , Karthikeyan S. , Vaganan M. Mayil 
Published: September 2023

Background: Canna lily (Canna indica L.) is an edible herbaceous perennial plant in which flowers and rhizomes were commonly used as a food additive and its potentiality was not fully utilized in India. To stun these hindrances, morphological characterizations are needed to determine the genetic variability to improve flower quality and rhizome yield in canna lily. Methods: In the present research, a field experiment was conducted during 2022-2023 in Botanical Garden, Tamil Nadu Agricultural University, Coimbatore, Tamil Nadu. Twelve accessions were investigated by using a randomized block design with 3 replications. All the observations for 23 quantitative traits were carried out at 0.05 and 0.01 probability. Results: The wide range of genetic variability was observed, a high genetic coefficient of variation ranged from 8.49 to 75.62 % and a phenotypic coefficient of variation ranged from 8.83 to 76.50 % was observed in 20 traits except in time taken for first flowering, rhizome diameter, number of nodes per rhizome. High heritability coupled with high genetic advance as a percent of mean was observed for 21 traits except in time taken for flowering and number of nodes per rhizome. Character association analysis revealed that stem diameter and inflorescence length showed highly significant and positively correlated with flower yield and rhizome yield per plant. Path analysis specified that the number of leaves per clump had a very high and positive direct effect on fresh flower yield per plant.
Al-Takâmul wa al-Tawfîq bayna al-Fiqh wa al-Tasawwuf: Wijhah Nazhar Kiyahî Muhammad Shâlih Darat al-Samarânî fi Taqaddum al-Fikr al-Dinî fî Indûnîsiyâ
Authors: Kasdi Abdurrohman , Umma Farida  , Fauzan Adim  
Published: September 2023

This article aimed to analyze the perspective of Kiyahî Shâlih Darat in integrating fiqh and Sufism which are generally considered different from one another. Fiqh tends to illustrate the outward side in deriving legal rulings from the Qur’an and Sunnah, while Sufism tends to refer to the inner side in applying the teachings. The integration between both is deemed necessary to balance the internal and external dimensions of Muslim life, as they are an inseparable unit. This research is a qualitative library one with the data collected from the books of Kiyahî Shâlih Darat and research on his ideas. It is furthermore a study that attempts to analyze the contents of Kiyahî Shâlih Dârât’s thought objectively and scientifically to find its meanings and values. The results showed that the Kiyahî Shâlih Darat mastered various disciplines ranging from fiqh, Sufism, tafseer to hadith. His thought reflects the manifestation of a perfect religious intellectual spirit. He interpreted the Islamic teaching and its ritual practices in the context of carrying out the integration between fiqh which emphasized the outward aspects and sufism which focused on the inner ones. According to him, Muslims who only rely on one of both and ignore another cannot be considered perfect Muslims because Islam does not only give attention to external things but also internal ones. Likewise, Islam not only regulates the soul but also takes care of physical matters. Fiqh without Sufism, as he mentioned, will be empty, while Sufism without fiqh will be futile so real Islam is a combination between both.
Survei Permasalahan Guru BK Pascapandemi
Authors: Mussilaturrohmi Mussilaturrohmi , Hapsari Novita Tri , Susanti Ana , Kholili Ma'rifatin Indah 
Published: September 2023

<p class="IEEEAuthorEmail"><span lang="EN-GB">The objectives of this study are (1) to identify the conditions for implementing BK in schools and (2) to identify problems faced by counselors after the Covid-19 Pandemic. The research method uses surveys. Data collection techniques used questionnaires about counselors' problems after the Pandemic. The study population was counselors in Indonesia, and the research sample was 323 respondents from the islands of Java, Sumatra, Kalimantan, Sulawesi, Bali-NTT-NTB, and Maluku. Data analysis using descriptive statistics. The results of the study found that there were several obstacles experienced by counselor in the implementation of counselor services after the Pandemic, such as the imbalance in the ratio of counselors to students, the absence of class hours, the absence of instruments for counselors, and changes in the curriculum that caused changes in the design of the counselor program. These problems can be solved through cooperation from various parties. Support from schools, stakeholders and parents is needed so that the implementation of counselor services can be as planned. </span><span class="longtext"><span lang="EN">Suggestions for further research can be done by conducting literature reviews or conducting experimental research related to problems that occur after the pandemic.</span></span></p>
Hubungan antara Dukungan Teman Sebaya dengan Stres Akademik pada Siswa
Authors: Febrianti Nadya Rizki , Surur Naharus , Kholili Ma'rifatin Indah 
Published: September 2023

<p>The objectives of the study are: to describe the level of mutual support, academic stress experienced and analyze the relationship between peer support and academic stress in third class of MIPA SMA Negeri 8 Surakarta. The method used is a quantitative approach with a correlation method. The correlation method was used to determine the relationship between two variables, namely peer support and academic stress. The results of this study show that: (1) The category of collegial support for students in third class of MIPA SMA Negeri 8 Surakarta is at the average level of 44 students (67.7%), (2) category of academic stress in the middle level which is 47 students (72.3%), (3) Pearson Product Moment Correlation test results obtained rcount value of -.302 and rateable value of 0.2441. With these results, it is concluded that the value of rcount is greater than the value of table, so the hypothesis proposed in this study which says "There is a significant negative relationship between peer support and academic stress in third class of MIPA SMA Negeri 8 Surakarta" can be accepted or verify. </p>
Ring-Shaped Meniscus, MRI Features, and Diagnosis
Authors: Mitra Matthias , Lee Yee Han Dave 
Published: September 2023

Case:
A ring-shaped meniscus (RSM) is a rare malformation of debatable origin usually occurring on the lateral meniscus. Here, we present 2 cases of RSM with differing etiologies and discuss the current literature on the topic. These reports may help with the identification of RSMs in the future and assist in understanding the true etiopathogenesis of individual cases.

Conclusion:
These 2 cases exemplify the variation in presentations of ring-shaped menisci and their radiological features on both x-ray and magnetic resonance imaging. This reinforces the idea that there may be both a congenital and an iatrogenic etiology to this rare condition.
Prinsip Kerja Sama pada Siniar Close The Door Deddy Corbuzier Edisi Mei-Juni 2022
Authors: Anjani Winda Catur , Kusuma Emy Rizta 
Published: September 2023

The aims of this article is determine the use of the principle of cooperation in Podcast of Deddy Corbuzier's Close The Door on May-June 2022 Edition. This article used descriptive qualitative method. The data is a direct speech on Deddy Corbuzier's Podcast. Data collection using documentation, listen, record, and transcription techniques. There were two podcast videos analyzed with different numbers of speech participants. Data is presented using data tables. The results showed that: 1) There are 347 adherents to the principle of cooperation. The most dominating maxim is quantity maxim. The least adhered to maxim is the implementation maxim. 2) There were 148 violations of the principle of cooperation. The most dominating maxim is the quantity maxim. The least violated maxim is the quality maxim.