bluuebunny/crossref_metadata_2025_split huggingface dataset:
Combined recovery of valuable metals from LiFePO4–LiCoO2 system without adding oxidant and reductant
Authors: Ren Zhongqi , Zheng Shuai , Li Ruiqi , Li Yongjian , Dong Liping , Wu Xi , Tian Shichao , Zhou Zhiyong 
Published: April 2023

AbstractBased on the oxidation of ferrous ions in lithium iron phosphate and reduction of trivalent cobalt ions in lithium cobaltate, an innovative combined recovery process of lithium iron phosphate and lithium cobaltate powders is proposed. The effects of leaching conditions on leaching performance are studied and the optimal leaching conditions are obtained. Under these conditions, the leaching efficiencies of lithium and cobalt ions reach up to 99.92% and 81.11%, respectively. After removing ferric ions from leachate, the cobalt and lithium ions are separately recovered from the leaching solution. The final precipitation rate of cobalt ions is up to 97.71% with the purity of cobalt oxalate as 99.94%. In addition, the precipitation rate of lithium ions is 78.54% and the purity of lithium carbonate reaches up to 99.94%. Finally, the reaction path and mechanism for the combined recovery of lithium iron phosphate–lithium cobaltate system are preliminary investigated.
Global burden of female breast cancer and its association with socioeconomic development status, 1990–2044
Authors: Zhang Jingya , Lu Yongbo , Zhang Ning , Yu Zeru , Li Haorao , He Rongxin , Mao Ying , Zhu Bin 
Published: April 2023

AbstractBackgroundBreast cancer is a widespread disease in women worldwide.AimWe aimed to explore the global epidemiological trends of female breast cancer (FBC) between 1990 and 2044.Methods and ResultsDisease burden, population, and socio‐demographic index (SDI) data were obtained from the Global Health Data Exchange (GHDx) database. We analyzed temporal trends, age differences, risk factors, and geographic patterns of FBC disease burden globally and explored the association between age‐standardized incidence rate (ASIR) of FBC and SDI. Bayesian age‐period‐cohort model was also performed to predict the changes in FBC incidence worldwide from 2020 to 2044. First, the global ASIR of FBC increased by 14.31% from 1990 to 2019 (95% Uncertainty Interval 4.75% to 23.98%). The death rate presented a falling trend. Second, alcohol use is the most‐highlighted risk factor for FBC in some high‐income regions such as Europe. A high fasting plasma glucose levels is the most prominent risk factor for FBC in Latin America and Africa. Third, the ASIR of the FBC increases with the SDI. Fourth, the incidence is expected to increase faster among women aged 35–60 years and fastest for those aged 50–54 years from 2020 to 2044. Countries with a high incidence of FBC that is expected to increase significantly include Barbados, Burkina Faso, Senegal, Monaco, Lebanon, Togo, and Uganda.ConclusionThe disease burden of FBC varies worldwide; the findings suggest attaching importance to the control of middle and low‐middle SDI regions. Public health as well as cancer prevention experts should pay more attention to regions and populations at an increased risk of developing FBC, focusing on their prevention and rehabilitation while conducting further epidemiological studies to investigate the risk factors of their increase.
Multi‐strategy‐based leader election mechanism for the Raft algorithm
Authors: Du Zhiqiang , Qu Zhi , Fu Yanfang , Huang Muhong , Liu Liangxin 
Published: April 2023

SummaryRaft is a consensus algorithm that implements highly available replicas. As raft requires a leader to drive the protocol execution, it usually employs a round‐robin leader election mechanism to select a random leader among all nodes. However, when the elected leader suffers from performance issues, the protocol will temporarily lose aliveness. To address this issue, we propose a multi‐strategy leader election mechanism that allows nodes to proactively trigger a new round of election when they believe the leader suffers from performance issues, and replace this leader with a new one in a designated priority queue. The formal analysis and experimental results show that the mechanism can improve the system's throughput/latency without additional election time overhead.
Red‐Emitting Fluorophores Featuring Combined Hybridized Local and Charge‐Transfer Excited State and Aggregation‐Induced Emission as Efficient Emitters for Electroluminescent Devices
Authors: Chaiwai Chaiyon , Kitisriworaphan Wipaporn , Petdee Sujinda , Chawanpunyawat Thanyarat , Chasing Pongsakorn , Nalaoh Phattananawee , Manyum Thanaporn , Sudyodsuk Taweesak , Promarak Vinich 
Published: April 2023

AbstractHerein, donor (D)‐acceptor (A) type fluorophores (TTBz and TTNz) were designed and synthesized with different acceptor units. The two acceptor units benzo[c][1,2,5]thiadiazole (Bz) and naphtho[2,3‐c][1,2,5]thiadiazole (Nz) are asymmetrically functionalized with triphenylamine (TPA) as a strong donor and tetraphenylethylene (TPE) as an aggregation‐induced emission (AIE)‐luminogen to realize combined AIE and hybridized local and charge transfer (HCLT) excited state features as well as long‐wavelength emission. Their HCLT and AIE properties are verified by theoretical calculations, solvatochromic effects, and transient photoluminescence decay experiments. They exhibit strong orange‐red and deep‐red fluorescence emission with good thermal stability and hole mobility, leading to effective utilization as emitters in organic light‐emitting diodes (OLEDs). The resulting devices show decent electroluminescent (EL) performance (current efficiency of 12.04–12.58 cd A−1, maximum brightness of 11206–20160 cd m−2, and external quantum efficiency of 5.11–5.47 %). Particularly, the TTNz‐based OLED demonstrates steady deep‐red emission with a peak at 661 nm and CIE coordinates of (0.67, 0.33).
The relationship between perceived corporate environmental responsibility and employees' pro‐environmental behavior: A moderated serial mediation model
Authors: Wang Dawei , Wang Li , Sun Chongyu , Wu Dan , Mao Wenxu , Hu Yixin 
Published: April 2023

AbstractIn order to achieve corporate sustainable development, it is an effective way to emphasize the development of employees' pro‐environmental behavior at the microlevel. This study examined the relationship between perceived corporate environmental responsibility (CER) and employees' PEB and its mechanisms based on the cognitive‐affective processing system (CAPS) theory. Data were collected from 300 employees in the manufacturing and logistics industries in two stages in this study, with a whole‐group sampling method. The results showed that (1) perceived CER is positively correlated with employees' PEB; (2) environmental internal motivation and harmonious environmental passion play a serial mediating role between perceived CER and employees' PEB; (3) person–organization fit moderates the serial mediating path through which perceived CER influences employees' PEB via environmental internal motivation and harmonious environmental passion, by enhancing the positive influence of perceived CER on environmental internal motivation, such that the higher the level of person–organization fit, the stronger the positive serial mediating effect. This study provides a valuable interpretation for understanding the relationship between perceived CER and employees' PEB from both cognitive and affective perspectives, and provides new ideas for intervening in employees' PEB to achieve corporate sustainable development.
Cooperative communication for safety message dissemination in unsaturated networks with varying contention windows
Authors: Septa Neha , Wagh Sushama 
Published: April 2023

SummarySafety message dissemination is crucial in vehicular ad hoc networks (VANETs) for road safety applications. Vehicles regularly transmit safety messages to surrounding vehicles to prevent road accidents. However, changing vehicle mobility and density can cause unstable network conditions in VANETs, making it inappropriate to use a fixed contention window (CW) for different network densities. It has been proposed a 1‐D Markov model under unsaturation conditions to analyze the performance of the system with varying CWs under changing vehicle densities. Additionally, it introduces the use of cooperative communication (CoC) to relay failed safety messages. In CoC, two control packets, namely, negative acknowledge (NACK) and enable to cooperate (ETC), are utilized. The proposed analytical model named cooperative communication for safety message dissemination (CoC‐SMD) is used to calculate throughput and average packet delay for varying CW and different packet size. The simulation confirms the validity of the analytical results and show significant improvement in the metrics through the use of varying CW sizes and CoC compared with existing techniques.
TRPS1 outperforms GATA3 in pleural effusions with metastatic breast carcinoma versus mesothelioma
Authors: Baban Farah , Koepplin Justin W. , Ahmad Muhammad , Clarke‐Brodber Anna‐Lee , Bois Melanie C. , Hartley Christopher P. , Sturgis Charles D. 
Published: April 2023

AbstractIntroductionIn evaluating malignant pleural fluid cytology, metastatic adenocarcinomas and mesotheliomas are often differential diagnoses. GATA binding protein 3 (GATA3) has historically been used to confirm metastatic breast carcinomas; however, GATA3 has low specificity if mesothelioma is included in differential diagnoses. Trichorhinophalangeal syndrome type 1 (TRPS1) protein is expressed in all types of breast carcinomas, with reported high specificity and sensitivity. We investigated the performance of TRPS1 immunohistochemistry (IHC) and compared it to GATA3 in pleural fluids diagnosed with metastatic breast carcinoma and mesothelioma.MethodsThirty‐six consecutive ThinPrep pleural fluids and 4 pleural fine needle aspirations (FNAs) with diagnoses of metastatic breast carcinoma (21) and mesothelioma (19) were retrieved, and IHC with TRPS1 and GATA3 was performed on all. Immunoreactivity scores for TRPS1 were calculated by multiplying percentage of immunoreactive cells by staining intensity. Immunoreactivity scores were negative if 0 or 1, low positive if 2, intermediate positive if 3 or 4, or high positive if 6 or 9. Nuclear immunoreactivity of ≥10% with at least moderate intensity was judged GATA3 positive.ResultsGATA3 showed immunoreactivity in all metastatic breast carcinomas and 84% of mesotheliomas. TRPS1 was immunoreactive in all breast carcinoma cases (18 with a score of 9 and 3 with a score of 6). TRPS1 showed low positivity in 5% of mesothelioma cases with all other cases being negative.ConclusionWhen cytomorphologic differential diagnoses of mesothelioma exist, TRPS1 is a more specific marker than GATA3 for confirmation of metastatic breast carcinoma in pleural fluid cytology.
Browning of boreal lakes: Do public perceptions and governance align with the biological foundations?
Authors: Albrecht Eerika , Hannonen Olga , Palacín‐Lizarbe Carlos , Suni Jarno , Härkönen Laura H. , Soininen Niko , Kukkonen Jussi , Vainikka Anssi 
Published: April 2023

AbstractBrowning of surface waters, also known as brownification, is a process of decreasing water transparency, particularly in boreal lakes surrounded by intensively managed forests and wetlands. In this paper, we review the ecological consequences and ecosystem‐based management (EBM) of browning through a systematic review approach and adopt an interdisciplinary approach to formulating new governance of this complex phenomenon. To understand the effects of browning on the recreational value of freshwaters, we present primary survey data on public perceptions of recreational fishing tourists on water quality in Finland. We identify a need to develop EBM beyond the EU's Water Framework Directive (WFD) to fully account for the extensive implications of browning. We also highlight the need for a better understanding of the within‐lake microbial processes to estimate the browning‐associated changes in the greenhouse gas balance of lakes. Tourist perceptions of the quality of waterbodies in Finland were largely in agreement with the general proportion of waterbodies classified in a good or excellent ecological status class, but these perceptions may be detached from biological quality assessment criteria. Consequently, we suggest that the EBM of inland waters should improve the utilization of information on not only biogeochemical processes but also users' perspectives on aquatic ecosystems beyond the EU WFD.
HSE National Clinical Programme for Eating Disorders in Ireland: COVID‐19 pandemic and eating disorder care in a new national eating disorder service
Authors: JO Driscoll David , Jennings Rhona , Clifford Michelle , Maher Caroline , Corbett Marie , Wade Sarah , Dunne Deirdre , Collins Ciara , McDevitt Sara 
Published: April 2023

AbstractBackgroundThe COVID‐19 pandemic experience was different in each country (e.g., prevalence, societal restrictions). There is limited data on eating disorder (ED) diagnosis and service activity trends within Ireland. The aim of this study is to describe the ED referral and hospitalization trends during COVID‐19 in Ireland.MethodMonthly data (2019–2021) from three regional community ED services (two‐child and one‐adult) were collected. National psychiatric and medical hospitalization data were analyzed. A descriptive and trend analysis was performed.ResultsThere was a trend of referrals to community ED services during the COVID‐19 pandemic for children (p < .0001) and adults (p = .0019). Albeit the increase in child referrals was evident at an earlier point before adult referrals. There was a trend of a diagnosis for children and adults of anorexia nervosa (p < .0001; p = .0257) and other‐specified‐feeding‐or‐eating‐disorder (OSFED) respectively (p = .0037; p = .0458). There was no trend in psychiatric co‐morbidity. There was a trend of child (p = .0003) not adult (n = 0.1669) psychiatric hospitalization. There was a trend of medical hospitalization for child and adult combined (p < .0001).ConclusionThis study adds to the growing literature on the association of the COVID‐19 pandemic on ED trends and the need for future public health and service provision funding to be allocated for mental health services during periods of international crisis.Public SignificanceThis study illustrates the referral and hospitalization trend in young persons and adults with an ED in Ireland during the COVID‐19 pandemic. This study highlights that there was a trend of Anorexia Nervosa and OSFED presentations during the COVID‐19 pandemic.
Treatment of avoidant‐restrictive food intake disorder in an older adult: A proof‐of‐concept case study
Authors: Grunewald William , Smith April R. , Brown Tiffany A. 
Published: April 2023

AbstractObjectiveCognitive behavioral therapy for Avoidant Restrictive Food Intake Disorder (ARFID; CBT‐AR) is an emerging treatment for ARFID. However, this treatment modality has yet to be examined among older adults (e.g., older than 50 years) or with adults presenting with feeding tubes. To inform future versions of CBT‐AR, we present the results of a singular case study (G) of an older male with the sensory sensitivity phenotype of ARFID who presented for treatment with a gastrostomy tube.MethodsG was a 71‐year‐old male who completed eight sessions of CBT‐AR in a doctoral training clinic. ARFID symptom severity and comorbid eating pathology changes were examined pre‐ and post‐treatment.ResultsPosttreatment, G reported significant decreases in ARFID symptom severity and no longer met diagnostic criteria for ARFID. Furthermore, throughout treatment, G reported significant increases in his oral food consumption (vs. calories being pushed through the feeding tube), solid food consumption, and the feeding tube was ultimately removed.DiscussionThis study provides proof of concept that CBT‐AR is potentially effective for older adults and/or those presenting for treatment with feeding tubes. Validation of patient efforts and severity of ARFID symptoms emerged as core to treatment success and should be emphasized when training clinicians in CBT‐AR.Public SignificanceCognitive behavior therapy for ARFID (CBT‐AR) is the leading treatment for this disorder; however, it has yet to be tested among older adults or those with feeding tubes. This single‐patient case study demonstrates that CBT‐AR may be efficacious in reducing ARFID symptom severity among older adults with a feeding tube.
Theoretical Investigations on the Agostic Interactions of the Molybdenum and Manganese Complexes
Authors: Zhang Min , Zhang Wanjing , Liang Guangchao 
Published: April 2023

AbstractThe essential participation of agostic interactions in C−H bond activation, cyclometallation and other catalytic processes has been widely observed. To quantitatively evaluate the Mo−H−C agostic interaction in the Mo β/γ‐ agostomers [CpMo(CO)2(PiPr3)]+(Mo,1andMo,2) and the Mn−H−C agostic interaction in the Mn α/ϵ‐agostomers [(C6H9]Mo(CO)3] (Mn,1andMn,2), the comprehensive density functional theory (DFT) theoretical investigations were performed. Results indicated that the Mo β‐agostomer1is only favorable by 0.5 kcal mol−1than Mo γ‐agostomer2, and the Gibbs barrier for their interconversion was 9.1 kcal mol−1. A slightly higher Gibbs barrier of 12.7 kcal mol−1for the isomerization between the Mn α/ϵ‐agostomers was also obtained. The relatively strong agostic interactions in Mo β‐agostomer1and Mn α‐agostomer1were further verified by the AIM (Atoms‐In‐Molecules) analyses and the NAdOs (natural adaptive orbitals) analyses. The findings on the agostic interaction presented in this study are believed to benefit the understandings of the agostic interaction involved catalytic processes and to promote the development of new organometallic complexes.
Personalized medicine: Somatosensory phenotyping in musculoskeletal pain conditions
Authors: Curatolo Michele 
Published: April 2023

AbstractBackgroundCurrent clinical phenotyping of musculoskeletal pain provides very limited evidence‐ based support to personalized medicine. This paper discusses the potential of somatosensory phenotyping to contribute to personalized medicine for prognosis and prediction of treatment effects.MethodsHighlight of definitions and regulatory requirements for phenotypes and biomarkers. Appraisal of the literature on somatosensory phenotyping in musculoskeletal pain.ResultsSomatosensory phenotyping can identify clinical conditions and manifestations that may affect treatment decisions. However, studies have shown inconsistent associations of phenotyping measures with clinical outcomes, and the strength of association is mostly weak. Most somatosensory measures have been developed for research, are too demanding to find large acceptance in clinical settings, and have uncertain clinical usefulness.ConclusionsCurrent somatosensory measures will unlikely be validated as strong prognostic or predictive biomarkers. However, they still have the potential to support personalized medicine. Including somatosensory measures in biomarker signatures, that is, a set of measures that are collectively associated with outcomes, is potentially more useful than aiming to the identification of single biomarkers. Furthermore, somatosensory phenotyping may be introduced as part of patient's evaluation to contribute to better‐informed and personalized treatment decisions. To this purpose, a change in the way research currently approaches somatosensory phenotyping is warranted. A pathway is proposed that involves: (1) the identification of clinically applicable measures that are specific to clinical conditions; (2) the association of somatosensory phenotypes with outcomes; (3) multi‐site replication; and (4) the determination of clinical benefits in randomized controlled trials.SignificanceSomatosensory phenotyping has the potential to support personalized medicine. However, current measures do not seem to meet the criteria for being strong prognostic or predictive biomarkers, most of them are too demanding to find large acceptance in clinical settings, and their clinical usefulness has not been proven. The value of somatosensory phenotyping can be more realistically determined by re‐orienting research to the development of simplified testing protocols, applicable to large‐scale clinical practice, and tested for clinical usefulness in randomized controlled trials.
How do we cope when we believe we can? A systematic review and meta‐analysis of studies on coping and negative mood regulation expectancies
Authors: Mazur‐Socha Zofia , Przepiórka Aneta , Sobol Małgorzata 
Published: April 2023

AbstractNegative mood regulation expectancies (NMRE) are individuals’ beliefs about their ability to alleviate a negative mood. The literature on the relations between NMRE and coping often reports ambiguous results. The current review aims to integrate and summarize evidence on the associations between NMRE and coping. We searched the Cumulative Index to Nursing and Allied Health Literature (CINAHL), Education Resources Information Center (ERIC), PsycInfo, PsycArticles, Scopus and Web of Science databases and found 19 articles for a systematic review and 17 articles for a meta‐analysis. There was a medium significant effect size for active coping (r = .31, 95% confidence interval [CI] [.26; .36]), and a small significant effect for avoidant coping (r = −.14, 95% CI [−.22; −.06]). Moderate to high levels of significant heterogeneity were observed, indicating differences in relationships between NMRE and coping across studies. Method of measuring coping was a significant moderator of its relationship to NMRE. Given the solid evidence of the positive relationship between NMRE and active coping, both variables should be considered in research and in psychological interventions. Further directions for the development of theory and for future research are suggested.
Electrochemical urea biosensor based onProteus mirabilisurease immobilized over polyaniline PANi‐Glassy carbon electrode
Authors: Atailia Sara , Baraket Abdoullatif , Rabai Selma , Benounis Messaoud , Jaffrezic Nicole , Araar Hala , Naït‐Bouda Abdelyamine , Boumaza Abdecharif , Errachid Abdelhamid , Houhamdi Moussa 
Published: April 2023

AbstractIn this study, a novel, sensitive electrochemical enzyme‐based biosensor for urea detection was presented. This biosensor combines a three‐electrode system consisting of a classic Glassy Carbon Electrode (GCE) as the working electrode, a platinum counter electrode, and Ag/AgCl as the reference electrode. To construct this urea platform, a GCE was modified with a polyaniline (PANi) film. Then, bacterial urease fromProteus mirabiliswas immobilized on the modified GCE (Pm‐Urease‐PANi‐GCE). For the characterization of surface modification, Cyclic Voltammetry (CV) and Scanning Electron Microscope (SEM) were applied, while the Square Wave Voltammetry (SWV) technique was performed for urea detection. The main analytical characteristics of the Pm‐Urease‐PANi‐GCE biosensor showed a good linear range from 0.1 to 10 mM of urea, a limit of detection (LOD) of 0.1 mM, a Michaelis‐Menten Kmof 0.23 mM, and a sensitivity value 46 μA/mM/cm2. This biosensor allows the detection of urea in solutions, and it could be improved for further medical, environmental, or engineering applications.