bluuebunny/crossref_metadata_2025_split huggingface dataset:
Kant y Aranguren: que el concepto se haga vida
Authors: Aramburu Zudaire Mikel 
Published: June 2023

El artículo pretende ofrecer una nueva lectura sobre lo que significan Kant y el kantismo en el pensamiento del filósofo español José Luis López Aranguren (1909-96). La investigación se apoya en las referencias más destacadas de sus Obras completas y de otras publicaciones menores sobre todo de la última etapa de su vida. Aunque no escribió ninguna monografía específica ni fue especialista en la filosofía clásica alemana, Aranguren dialoga con Kant, principalmente sobre ética, a lo largo de su larga trayectoria intelectual y de ello se siguen obteniendo claves conceptuales y existenciales para el tiempo presente.

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El problema del gran abismo entre naturaleza y libertad. ¿Qué aporta la Crítica del juicio a su solución?
Authors: Dörflinger Bernd 
Published: June 2023

Este artículo trata de la principal preocupación sistemática de la Crítica del Juicio (KU): el así llamado problema del abismo. En la introducción a la tercera Crítica de Kant, el problema se presenta a nivel de los ámbitos de la filosofía teórica y práctica, para los que se supone que esta (la KU) ofrece una solución. Los dos dominios legislativos de la filosofía, la naturaleza y la libertad, requieren de un tránsito para poder cerrar el abismo entre estos ámbitos de validez a priori. El siguiente texto argumenta que en la Crítica del Juicio hay tres tránsitos o tres enfoques para resolver el problema del abismo entre las legislaciones del entendimiento y la razón: el juicio estético de lo bello y los logros culturales de los seres humanos tanto en las bellas artes como en las ciencias.

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Expression, localization, and function of P4HB in the spermatogenesis of Chinese mitten crab (Eriocheir sinensis)
Authors: Tang Yulian , Ni Anni , Li Shu , Sun Lishuang , Li Genliang 
Published: June 2023

Background
The sperm of Chinese mitten crab (Eriocheir sinensis) have special noncondensed nuclei. The formation and stability of the special nuclei are closely related to the correct folding of proteins during spermatogenesis. P4HB plays a key role in protein folding, but its expression and role in the spermatogenesis of E. sinensis are unclear.

Objective
To investigate the expression and distribution characteristics of P4HB in the spermatogenesis of E. sinensis as well as its possible role.

Methods
The testis tissues of adult and juvenile E. sinensis were used as materials. We utilized a variety of techniques, including homology modeling, phylogenetic analysis, RT-qPCR, western blotting, and immunofluorescence staining to predict the protein structure and sequence homology of P4HB, analyze its expression in the testis tissues, and localize and semi-quantitatively assess its expression in different male germ cells.

Results
The sequence of P4HB protein in E. sinensis shared a high similarity of 58.09% with the human protein disulfide isomerase, and the phylogenetic tree analysis indicated that the protein sequence was highly conserved among crustaceans, arthropods, and other animals species. P4HB was found to be expressed in both juvenile and adult E. sinensis testis tissues, with different localization patterns observed all over the developmental stages of male germ cells. It was higher expressed in the spermatogonia, spermatocytes, and stage I spermatids, followed by the mature sperm than in the stage II and III spermatids. The subcellular localization analysis revealed that P4HB was predominantly expressed in the cytoplasm, cell membrane, and extracellular matrix in the spermatogonia, spermatocytes, stage I and stage II spermatids, with some present in specific regions of the nuclei in the spermatogonia. In contrast, P4HB was mainly localized in the nuclei of stage III spermatids and sperm, with little expression observed in the cytoplasm.

Conclusion
P4HB was expressed in the testis tissues of both adult and juvenile E. sinensis, but the expression and localization were different in male germ cells at various developmental stages. The observed differences in the expression and localization of P4HB may be an essential factor in maintaining the cell morphology and structure of diverse male germ cells in E. sinensis. Additionally, P4HB expressed in the nuclei of spermatogonia, late spermatids, and sperm may play an indispensable role in maintaining the stability of the noncondensed spermatozoal nuclei in E. sinensis.
Prevalence of Burnout Syndrome among Working Physicians in Family Health Centres and Units in Port Said Governorate
Authors: Shaltout Amr Essam , Mohamed Mohamed A. , Ibrahim Nadia Mahmoud , Eldahshan Nahed Amen 
Published: June 2023

Background: The classic symptoms of the syndrome of burnout as described by Maslach et al. are emotional exhaustion, depersonalization, and inefficacy. Prolonged exposure to stress is usually the main cause of emotional exhaustion and it manifests through the loss of enthusiasm for work, feeling helpless, trapped, and defeated. Depersonalization occurs when physicians treat patients indifferently, objectify them, and develop a negative attitude toward their colleagues and profession. Inefficiency, or the lack of a sense of personal achievement, is characterized by the individual’s withdrawal from responsibilities and detachment from the job.
Aim: To assess burnout prevalence among physicians of primary health care centers and units in Port Said.
Subjects and Methods: A cross-sectional study was conducted with simple random sampling of physicians of primary care centers and units. Burnout was measured using the Maslach Burnout Inventory (MBI), a validated 22-item questionnaire considered the gold standard tool for measuring burnout.
Results: In the current study on 155 physicians, the prevalence of burnout was 65.8% among the studied sample with 80%, 65.8%, and 80% of the subjects displayed high Emotional Exhaustion, Depersonalization, and low Personal Accomplishment, respectively. Female gender, urban setting of the practice, being married, unsatisfactory salary, sleeping hours 4-8 hours, and working in night shifts were all factors that significantly contributed to physicians’ burnout.
Conclusion: In the current study, a high prevalence of burnout of 65.8% was found among the physicians in PHC centers and units. Gender, setting of the practice, marital status, salary, sleeping hours, and working in night shifts were all factors that significantly contributing to physicians’ burnout.
Awareness of Beneficiaries on the School–On-Air (SOA) Program of the Department of Agriculture on Halal Goat Production in Maguindanao
Authors: Undong Manan E. 
Published: June 2023

The study was conducted to evaluate and assessed the evident of awareness of beneficiaries on the School on Air (SOA) program on Halal Goat Production of the Department of Agriculture – Maguindanao, BARMM. It was conducted in the province of Maguindanao, Bangsamoro Autonomous Region in Muslim Mindanao. Specifically, it covered six (5) municipalities with one hundred eighty (100) goat raisers who also participated in the Halal Small Ruminant School on the Air Program.
Results showed that majority of the respondents/goat raisers have high level of awareness on the Halal Goat program based on their responses to the different survey parameters. Many of them also disclosed that thru Halal goat school on the air program their knowledge, skills and attitudes (KSA) were enhanced and improved.On the other hand, some of the respondents also observed some gaps and issues in the program implementation, however, they also indicated recommendations for the improvement of future programming. Among them were, use of bilingual in the delivery of relevant information, especially to the rural farmers, regular monitoring of DA technical experts/personnel to their farms and careful use of the word “halal” which, according to them, must be supported by corresponding verses from the holy Quran whenever possible.
Optimization Method of Whole Wheat Flour, Soybean Flour, Oyster Meat Powder for Nutrient- Dense Composite Flour
Authors: Orunaboka Wilson Tamunotonye , Kosoko Sulaimon Babatunde , Wabali Victor Chigozi , Olokoshe Abimbola Abisola 
Published: June 2023

Aim: To study the production of Nutrient – Dense Composite Flour from the blends of whole wheat flour, soybean flour (full fat) and oyster meat powder.
Study Design: The study was design using the D-optimal combination design of Response Surface Methodology (RSM).
Place and Duration of Study: The study was carried out at Department of Food, Nutrition and Home Science, University of Port Harcourt (Processing of raw materials) and the Department of Food Technology, Federal Institute of industrial research Oshodi, Lagos (Analysis of raw materials) between October 2021 and August 2022.
Methodology: The raw materials were each processed to have wholesome flours, and then they were combined according to the matrix generated, which had ranges of 70 – 100%, 0 – 22%, and 0 – 8% for whole wheat flour (WWF), soybean flour (SBF) and oyster meat powder (OMP) respectively.
Results: The design was used to assess the significance (5% probability) of the moisture, fat, and protein content, which ranged from 8.09 to 11.37%, 1.80 to 8.52% and 9.70 to 19.07% respectively; the water absorption (72.00 - 79.10BU), dough stability (9.3 - 17.5BU) and mixing tolerance index (25 - 50BU); and lightness and yellowness, which ranged from 65.48 - 83.2 and 13.77 - 23.58 respectively, of the flour blends. Protein content, water absorption dough stability, and mixing tolerance index were prioritized while moisture content, fat content, and yellowness were minimized for the numerical optimization of the responses. This study highlights the possibilities of utilizing non-conventional raw materials in the production of composite flour with balance nutritional and baking qualities.
Conclusion: The best flour combination was 72.51% whole wheat flour, 19.63% soybean flour, and 7.86% oyster meat powder.
Analysing the Scope of Kitchen Gardens in Achieving Dietary Diversity and Food Security in Rural Households for Resilient and Sustainable Food Systems
Authors: Krithika S. , Karthikeyan C. , Balasubramaniam P. , Selvi R. Gangai , Gurumeenakshi G. 
Published: June 2023

Aim: The study aims to identify the scope of kitchen gardens or nutrition gardens in rural households in Tamil Nadu in achieving dietary diversity and food security. Currently, only a few existing studies analyse the link between kitchen gardens and dietary diversity. The study aims to address this gap.
Study Design: Exploratory study.
Place of Study: Tiruvallur and Coimbatore districts, Tamil Nadu, India during December 2022.
Methodology: The study was conducted among 270 rural household heads selected through a stratified random sampling method. An index validated by Food and Agricultural Organisation (FAO) and FANTA was used to measure Household Dietary Diversity.
Results: The results show there was a significant decrease in dietary diversity among the households. It was also identified that promoting kitchen gardens among poor households can improve food security.
Conclusion: The study suggests suitable policy measures tailored to the local agricultural system to scale up kitchen gardening as a viable model for a resilient food system. Future research could be done to assess the impact of nutritive gardens on household food consumption patterns and food security.
Physical Attributes of Bael (Aegle marmelos L.) Fruit and Suitability for Commercialization and Processing
Authors: Kumar Suman , Ram R. B. , Kumar Awadhesh , Kumar Raveender , Kumar Rajeev , Sharma Malay Marut 
Published: June 2023

The present experiment entitled “Studies on physical attributes of bael (Aegle marmelos L.) fruit suitable for commercialization and processing” was conducted at Horticulture laboratory of the Department of Applied Plant Science during 2011-12. Matured fruits procured from well established bael orchard and investigation was carried out Completely Randomized Block Design with three replications. The observations were recorded on fruit shape, skull colour, pulp colour, fruit weight, skull thickness, fruit length, fruit width, pulp content and seed content. Flattened round fruit shape, greenish skull colour and pale yellow in pulp colour was found in NB-7. Minimum skull thickness 3.10 mm, seed content 2.42 per cent, whereas maximum fruit weight 2.00 kg, fruit length 16.20 cm, fruit width 17.20 cm and pulp content 79.20 per cent was found in cv. Narendra Bael-7. Result indicated that on the basis of physical attributes NB-7 varieties was found best for commercialization and processing.
Density Functional Theory Study of the Effect of Mono-Halogen Substitution on Electronic and Non-Linear Optical Properties of Porphyrin
Authors: Bashir Zahrau Hamisu , Nura A. M. , Gidado A. S. , Shariff M. A. , Muhammad Rabiu Nuhu 
Published: June 2023

Porphyrin is an organic macrocycle compound, with a chemical formular (C20H14N4) it act as important components in various technological application like solar cell, due to their flexibility and low production cost. In this work, DFT and TD-DFT were used to investigate the molecular geometry, HOMO-LUMO energy gap, global chemical indices, thermodynamic properties, non-linear optical properties, IR frequencies and IR intensities, open circuit voltage and UV-Vis spectrum of parent and substituted porphyrin molecules were calculated and noted. All the computations were performed by using Gaussian 03 package. Our result for the bond lengths indicates that the strongest bond was found in chloroporphyrin molecule with value of 1.0771(Å) and the highest bond angles was found to be . The calculated value of HOMO-LUMO energy gap shows that porphyrin will be more stable by the substitution of fluoride atom with HOMO-LUMO energy gap of 5.5865eV. The value of energy gap for parent porphyrin molecule (2.8885) eV was found to be very closer to the reported value of (2.920) eV. It was found that the zero point vibrational energy reduces, while the entropy and specific heat capacity of the molecules rises, due to the effect of the substitutions. The non-linear optical properties calculations shows that, the first-order hyperpolarizability values turn out to be ten times than that of the prototype urea ( esu) molecule, which is commonly used for the comparison of NLO properties with other materials. The computed frequencies and intensities result shows that fluoroporphyrin has slightly higher peak values of frequencies with corresponding intensities than the rest of the substituted porphyrin molecules. The open circuit voltage ranges from 2.0206-4.1568eV in the case of high LUMO and 0.9465-3.0828eV in the case of low LUMO, this value can be applied to organic solar cell. The UV-VIS spectrum, shows that due to the solvent effect there was an increase in the excitation energy and then slight increase in oscillator strength. Our finding shows that the hybrid halogenated compound may be utilized as an application in sensor and solar cells.
Estimation of demographic parameters of some plant species accounting for imperfect detection probabilities
Authors: Martínez‐Villegas Jorge A. , Pisanty Irene , Martorell Carlos , Hernández‐Apolinar Mariana , Valverde Teresa , Granados‐Hernández Luisa A. , Rodríguez‐Sánchez Mariana , Zúñiga‐Vega J. Jaime 
Published: June 2023

AbstractDetection probability (p) in plants is imperfect in natural conditions due to several factors. This imperfect detectability is rarely accounted for in the estimation of demographic parameters, such as survival probabilities (S) or transition rates between different life states or size classes (ψ), which may result in inaccurate quantitative information about plant populations. In this study, we used previously collected data of five plant species belonging to different families with contrasting life forms and habitats (Flaveria chlorifolia,Mammillaria hernandezii,Neobuxbaumia macrocephala,Govenia lagenophora, andCastilleja tenuiflora), data simulations, multi‐state models (a demographic tool that explicitly accounts forp), and direct estimation of survival and transition rates (i.e., assuming perfect detection) to identify in which species, states, or demographic parameters the bias caused by ignoring our imperfect detectability is more severe. Detection was imperfect (p < 1) for all our study species. In general, ignoring detection probabilities yielded underestimated survival and transition rates in all five species. Biases caused by assuming perfect detection were also large and significant, mainly in inconspicuous life states and size classes, such as seedlings and dry individuals. In contrast, considering detection probabilities resulted in fewer underestimated survival and transition rates, with smaller and mostly nonsignificant biases. Intriguingly, some transitions were overestimated even when accounting for detection probabilities. Our findings highlight the importance of considering that detection of most plant species is imperfect in the field, even in species that are apparently conspicuous, to avoid incorrect inferences about plant populations.
Better together: Building an engaged conservation paleobiology science for the future
Authors: Dietl Gregory P. , Durham Stephen R. , Clark Cheryl , Prado Rebecca 
Published: June 2023

Abstract

Making decisions about natural resource conservation is often difficult because of a lack of longer‐term data, which are needed to provide a frame of reference for identifying and choosing appropriate responses to threats impacting species, ecosystems, and the benefits they provide to people.

Despite the promise the field of conservation paleobiology holds for using geohistorical data and insights to provide this longer‐term perspective, examples of successful implementation are uncommon.

Over the past decade, many conservation biology researchers and practitioners have turned to knowledge co‐production to overcome this same challenge. Co‐production prioritizes collaboration between academic and non‐academic partners to produce actionable knowledge that better aligns with conservation practitioners' needs and concerns.

We argue that the conservation paleobiology community must similarly build collective competence to engage more effectively in shared “learning spaces” where actionable knowledge is co‐produced. We draw from our experiences with the Historical Oyster Body Size project and lessons learned from other fields to identify key attributes of actionable geohistorical knowledge and the meaningful co‐production processes that produced it.

Familiarity with these concepts will benefit conservation paleobiologists and all researchers who aspire to help develop longer‐lasting, defensible and more equitable solutions to complex conservation problems presented by a changing world.
Biologics Initiation in Rheumatoid Arthritis by Race and Ethnicity: Results From a Randomized Survey Study
Authors: Simard Julia F. , Lu Rong , Falasinnu Titilola O. , Baker Matthew C. , Hawa Saadiya , Deluna Mariani D. , Horomanski Audra , Fairchild Robert M. 
Published: June 2023

ObjectiveTo investigate whether the race and ethnicity of a patient with rheumatoid arthritis (RA) influences rheumatologists’ likelihood of choosing to initiate biologic disease‐modifying antirheumatic drug (bDMARD) treatment.MethodsWe conducted a randomized survey experiment in which identical brief case vignettes of hypothetical patients with RA were sent to US rheumatologists (respondents). Three of the four cases included some level of treatment decision ambiguity whereas the fourth case strongly favored bDMARD initiation. Each respondent was shown the four case vignettes, with the race and ethnicity (Black, Hispanic, White) randomly assigned for each case. Each vignette offered multiple choices for next therapeutic step, which we summarized using frequencies and proportions by race and ethnicity version.ResultsAmong 159 US rheumatologists, we found that for the three cases with some level of treatment decision ambiguity, there was little to no variability in the proportions of respondents who chose to start a biologic for the Black and Hispanic variants (cases 1, 2, and 3). For case 4, respondents generally agreed to start a biologic with some minimal variability across the variants (92.6% for the Black version, 98.1% for the Hispanic version, and 96.2% for the White version).ConclusionThere are conflicting data regarding bDMARD use and initiation in patients with RA based on the sex and race of the patient. This work adds to this conversation by examining how the next therapeutic step chosen by rheumatologists varied by the race and ethnicity of the hypothetical patient.
The Heterointerface between Fe1/NC and Selenides Boosts Reversible Oxygen Electrocatalysis
Authors: Zheng Huanran , Wang Shibin , Liu Shoujie , Wu Jiao , Guan Jianping , Li Qian , Wang Yuchao , Tao Yu , Hu Shouyao , Bai Yu , Wang Jinxian , Xiong Xiang , Xiong Yu , Lei Yongpeng 
Published: June 2023

AbstractThe rational design and construction of efficient and inexpensive bifunctional oxygen electrocatalysts are highly desirable for the development of rechargeable Zn–air batteries (ZABs). Although single‐atom Fe sites anchored on N‐doped carbon catalysts (Fe1/NC) ensure high oxygen reduction reaction activity, their unitary atomically dispersed active center faces difficult condition in catalyzing oxygen evolution reaction simultaneously. Herein, a composite catalyst containing heterointerface between Fe1/NC and selenides ((Fe,Co)Se2) is constructed. The obtained (Fe,Co)Se2@Fe1/NC exhibits extremely narrow potential gap of 0.616 V and remarkable stability in alkaline media, outperforming the benchmark catalysts (Pt/C+RuO2: 0.720 V). Experimental results and density functional theory calculations reveal that heterointerface between Fe1/NC and (Fe,Co)Se2 accelerates the electron transfer and provides more moderate adsorption sites, which endow (Fe,Co)Se2@Fe1/NC with extremely high bifunctional oxygen catalytic activity. This study not only provides a superior bifunctional catalyst for ZABs, but also enriches the application of single‐atom catalysts in multifunctional energy storage and conversion devices.
Enabling Record‐high Deep‐Red/Near‐Infrared Electroluminescence Through Subtly Managing Intermolecular Interactions of a Thermally Activated Delayed Fluorescence Emitter
Authors: Wang Hui , Wang Kai , Chen Jia‐Xiong , Zhang Xi , Zhou Lu , Fan Xiao‐Chun , Cheng Ying‐Chun , Hao Xiao‐Yao , Yu Jia , Zhang Xiao‐Hong 
Published: June 2023

AbstractDeep‐red/near‐infrared (DR/NIR) organic light‐emitting diodes (OLEDs) are promising for applications such as night‐vision readable marking, bioimaging, and photodynamic therapy. To tune emission spectra into the DR/NIR region, red emitters generally require assistance from intermolecular interactions. But such interactions generally lead to sharp efficiency declines resulting from unwanted quenching events. To overcome this challenge, herein, an advanced method via strategically managing the intermolecular interactions of thermally activated delayed fluorescence (TADF) emitters is proposed. The proof‐of‐concept molecule called DCN‐SPTPA exhibits impressive resistance to quenching while delivering controllable aggregation behavior for redshifting the emission by installing an end‐spiro group. Consequently, two emitters demonstrate similar photophysical properties and device performance at very low doping levels; while DCN‐SPTPA‐based OLEDs demonstrate a 1.3–1.4‐fold enhancement of the external quantum efficiencies (EQEs) with respect to the control molecule at 5–20 wt.% doping ratios, affording DR/NIR emission at 656, 688, 696, and 716 nm with record‐breaking EQEs of 36.1%, 29.3%, 28.2%, and 24.0%, respectively. Moreover, DCN‐SPTPA‐based nondoped NIR device also retains a state‐of‐the‐art EQE of 2.61% peaked at 800 nm. This work first demonstrates instructive guidance for accurately manipulating the intermolecular interactions of red TADF emitters, which will spur future developments in high‐performance DR/NIR OLEDs.