bluuebunny/crossref_metadata_2025_split huggingface dataset:
Entrainment Rates and Their Synoptic Dependence on Wind Speed Aloft in California's Central Valley
Authors: Caputi Dani J. , Trousdell Justin , Mehrotra Shobhit , Conley Stephen , Alexander G. Aaron , Oldroyd Holly J. , Faloona Ian 
Published: December 2022

AbstractDaytime atmospheric boundary layer (ABL) dynamics—including potential temperature budgets, water vapour budgets, and entrainment rates—are presented from in situ flight data taken on six afternoons near Fresno in the San Joaquin Valley (SJV) of California during July/August 2016. The flights took place as a part of the California Baseline Ozone Transport Study aimed at investigating transport pathways of air entering the Central Valley from offshore and mixing down to the surface. Midday entrainment velocity estimates ranged from 0.8 to 5.4 cm s−1 and were derived from a combination of continuously determined ABL heights during each flight and model-derived subsidence rates, which averaged -2.0 cm s−1 in the flight region. A strong correlation was found between entrainment velocity (normalized by the convective velocity scale) and an inverse bulk ABL Richardson number, suggesting that wind shear at the ABL top plays a significant role in driving entrainment. Similarly, we found a strong correlation between the entrainment efficiency (the ratio of entrainment to surface heat fluxes with an average of 0.23 ± 0.15) and the wind speed at the ABL top. We explore the synoptic conditions that generate higher winds near the ABL top and propose that warm anomalies in the southern Sierra Nevada mountains promote increased entrainment. Additionally, a method is outlined to estimate turbulence kinetic energy, convective velocity scale (w*), and the surface sensible heat flux in the ABL from a slow, airborne wind measurement system using mixed-layer similarity theory.
Identifying Genes that Affect Differentiation of Human Neural Stem Cells and Myelination of Mature Oligodendrocytes
Authors: Ye Dou , Wang Qian , Yang Yinxiang , Chen Bingyu , Zhang Fan , Wang Zhaoyan , Luan Zuo 
Published: December 2022

AbstractHuman neural stem cells (NSCs) are self-renewing, multipotent cells of the central nervous system (CNS). They are characterized by their ability to differentiate into a range of cells, including oligodendrocytes (OLs), neurons, and astrocytes, depending on exogenous stimuli. An efficient and easy directional differentiation method was developed for obtaining large quantities of high-quality of human OL progenitor cells (OPCs) and OLs from NSCs. RNA sequencing, immunofluorescence staining, flow cytometry, western blot, label-free proteomic sequencing, and qPCR were performed in OL lines differentiated from NSC lines. The changes in the positive rate of typical proteins were analyzed expressed by NSCs, neurons, astrocytes, OPCs, and OLs. We assessed Gene Ontology (GO) enrichment and Kyoto Encyclopedia of Genes and Genomes (KEGG) pathways of differentially expressed (DE) messenger RNAs (mRNAs) related to the differentiation of NSCs and the maturation of OLs. The percentage of NSCs differentiated into neurons, astrocytes, and OLs was 82.13%, 80.19%, and 90.15%, respectively. We found that nestin, PAX6, Musashi, and vimentin were highly expressed in NSCs; PDGFR-α, A2B5, NG2, OLIG2, SOX10, and NKX2-2 were highly expressed in OPCs; and CNP, GALC, PLP1, and MBP were highly expressed in OLs. RNA sequencing, western blot and qPCR revealed that ERBB4 and SORL1 gradually increased during NSC–OL differentiation. In conclusion, NSCs can differentiate into neurons, astrocytes, and OLs efficiently. PDGFR-α, APC, ID4, PLLP, and other markers were related to NSC differentiation and OL maturation. Moreover, we refined a screening method for ERBB4 and SORL1, which may underlie NSC differentiation and OL maturation.
Graphical Abstract
Potential unreported genes and proteins may regulate differentiation of human neural stem cells into oligodendrocyte lineage. Neural stem cells (NSCs) can differentiate into neurons, astrocytes, and oligodendrocyte (OLs) efficiently. By analyzing the DE mRNAs and proteins of NSCs and OLs lineage, we could identify reported markers and unreported markers of ERBB4 and SORL1 that may underlie regulate NSC differentiation and OL maturation.
Interplay between Safety Climate and Emotional Exhaustion: Effects on First Responders’ Safety Behavior and Wellbeing Over Time
Authors: Lee Jin , Resick Christian J. , Allen Joseph A. , Davis Andrea L. , Taylor Jennifer A. 
Published: December 2022

AbstractVarious job demands continuously threaten Emergency Medical Service (EMS) first responders’ safety and wellbeing. Drawing on Job Demands–Resources Theory, the present study examines the effects of the organizational context—safety climate—and the psychological context—emotional exhaustion—on safety behaviors and wellbeing over time. We tested our hypotheses in a longitudinal study of 208 EMS first responders nested within 45 stations from three fire departments in US metropolitan areas over 6 months during the beginning of the COVID-19 pandemic. Multilevel modeling showed that the relationship between safety climate and safety compliance behaviors can be attenuated when EMS first responders experience high emotional exhaustion. Emotional exhaustion was also negatively associated with morale while safety climate was positively associated with morale. Additionally, EMS first responders experienced increased depression when their emotional exhaustion levels were high. Higher safety climate was associated with decreased depression when emotional exhaustion was within a low-to-medium range. Higher safety climate was also associated with lower absolute levels of depression across the entire range of emotional exhaustion. These findings suggest that promoting safety climate and mitigating emotional exhaustion can augment EMS first responders’ safety behaviors and wellbeing.]
High-energy two-electron transfer in ion-atom collisions
Authors: Belkić Dževad 
Published: December 2022

AbstractTwo-electron transfer by fast heavy nuclei from heliumlike targets is studied. A detailed sequence of comprehensive computations is carried out in a large keV–MeV range of the projectile energies. This set is illustrated with total cross sections for double capture by alpha particles from helium atoms using several frequently applied four-body quantum-mechanical distorted wave models with the correct boundary conditions. The sensitivity of the obtained total cross sections is examined for different choices of the bound and continuum states. Especially at high energies, the influence of the compactness of the bound states is investigated by reference to the mechanism of the velocity matching kinematic double electron capture. Also considered is the dependence of these cross sections on the electronic screening of the projectile and the target nuclear charges in the bound and continuum states. The impact of this electronic shielding on total cross sections is assessed by reference to the corresponding bare nuclear charges in the bound and continuum states. Relative to all the available experimental data (100–6000 keV), the found striking model-dependence implies that two-electron transfer is sharply different from the associated one-electron transfer involving the same colliding particles.
Towards a typology of risk preference: Four risk profiles describe two-thirds of individuals in a large sample of the U.S. population
Authors: Frey Renato , Duncan Shannon M. , Weber Elke U. 
Published: December 2022

AbstractIt has been a longstanding goal of the behavioral sciences to measure and model people’s risk preferences. In this article, we adopt a novel theoretical perspective of doing so and test to what extent specific types of individuals share similar risk profiles (i.e., configurations of multidimensional risk preferences). To this end, we analyzed data of a U.S. sample (N = 3,123) in a comprehensive and rigorous way, resulting in a twofold contribution. First, based on data from the Domain-Specific Risk-Taking scale (DOSPERT) and using a cross-validation procedure, we established a multidimensional trait space including general and domain-specific dimensions of risk preference. Second, we employed model-based cluster analyses in this multidimensional trait space, finding that 66% of participants can be described well with four basic risk profiles. In sum, the typological perspective proposed in this article has important implications for current theories of risk preference and the measurement of individual differences therein.
Parametric Analysis and Optimization of Vanillin Hydrodeoxygenation Over a Sulfided Ni-Mo/δ-Al2O3 Catalyst Under Continuous-Flow Conditions
Authors: Kristensen Tove , Hulteberg Christian , Blomberg Sara , Tunå Per , Abdelaziz Omar 
Published: December 2022

AbstractA fundamental understanding of the process parameters affecting the catalytic hydrodeoxygenation (HDO) of bio-oils is of significance for enabling further progression and improvement of industrial biofuel upgrading methods. Herein, a novel demonstration and evaluation of the effect of temperature, pressure, and weight hourly space velocity in the continuous HDO of vanillin to cresol over a Ni-Mo/δ-Al2O3 catalyst are presented. Response surface methodology was used as a statistical experimental design method, and the application of central composite design enabled the generation of a statistically significant simulation model and a true optimization parametric study. The distribution of Ni and Mo on δ-Al2O3 was confirmed using scanning electron microscopy with energy dispersive X-ray analysis (SEM-EDX). No gradients with EDX mapping could be identified, and the elemental analysis showed well-dispersion of the metals. The mesoporous character of the catalyst-support system was unraveled using N2 physisorption. Experiments were conducted within the parametric range of 250–350 °C, 3–9 bar, and 15–35 h−1. Both temperature and pressure were found to have statistically significant linear and quadratic effects on the selectivity for cresol. The parametric interaction of temperature with pressure and space velocity also had a significant effect on the resulting response. The optimal temperature range becomes more critical at lower space velocities. Optimal selectivity for cresol was established at 314 °C, 5 bar, and 35 h−1. The fitting quality of the generated regression model was statistically confirmed and experimentally validated to describe the specified HDO process within the 95% two-sided confidence interval.
Mapping potential surpluses, deficits, and mismatches of ecosystem services supply and demand for urban areas
Authors: Vargas Leonardo , Ruiz Diana , Gómez-Navarro Carolina , Ramirez Wilson , Hernandez Olga Lucia 
Published: December 2022

AbstractLand-use decision making in densely populated cities is challenged to cover the urban demand for water and food while maintaining the integrity of ecosystems that regulate the supply of these ecosystem services, beyond urban limits. Land-use decision making can be informed using spatial analysis of ecosystem services supply and demand, shedding light on potential mismatches, surpluses, deficits, and unsustainable uses of ecosystems. The integration of such analysis in land-use decision making, however, can be challenged by the complexity of the hierarchical and inflexible planning models used in various countries. We explored how the analysis of potential mismatches, surpluses, and deficits in the supply and demand of water and fertile soil can be spatially assessed for urban areas, and how such information can be used to inform land-use decision making. We used official data and geoprocessing methods to map water -supply, demand, and risk for water scarcity-, and fertile supply –supply, demand, and risk for food insecurity-, for Bogota and Villavicencio. We showed a high risk for water scarcity in Bogota, and an increasing competition for fertile soil between urbanization and agriculture. We recommended a cooperative management strategy of ecosystems and services considering that both cities shared river basins and natural reserves, in addition to their strike differences in population size. Inter-jurisdictional and inter-municipal cooperation, in addition to strong governance, are necessary to handle mismatches of urban ecosystem services supply and demand, and a potential solution to solve conflicts related to access, availability, and jurisdiction of ecosystem services in urban areas..
Understanding Potato Production Practices in North-Western Kenya through Surveys: an Important Key to Improving Production
Authors: Kwambai Thomas K. , Struik Paul C. , Griffin Denis , Stack Laura , Rono Selly , Nyongesa Moses , Brophy Caroline , Gorman Monica 
Published: December 2022

AbstractPotato is the second most important food crop after maize in Kenya. However, most farmers produce potatoes under sub-optimal management, resulting in low yields, despite the introduction of improved varieties. Potato production practices were documented and compared to contribute towards improved potato management and productivity in Kenya. The study was guided by the hypothesis that potato farming and management practices influence potato performance and can depend on the production environment. Focus group discussions and household surveys were conducted in three major potato growing areas in Kaptama, Saboti and Lelan in Bungoma, Trans Nzoia and Elgeyo Marakwet counties in Kenya. Farming was the main occupation of 58.2% of the respondents. Respondents across the study sites indicated that they grew potatoes with their main focus as a cash (83.6%) and food (16.4%) crop. Most respondents had planted potatoes during both the last long (96.4%) and short (92.4%) rainy seasons. The four most important constraints limiting optimal potato production according to respondents were lack of quality seed, diseases (specifically late blight and bacterial wilt), poor marketing and lack of adequate technical knowledge on potato management. Low yields realized by farmers were mainly influenced by poor farmer practices in the use of seed, fertilizers, pesticides and crop rotation. This was compounded by farmers’ perceptions on input quantities applied, frequencies and farmers’ access to agricultural extension information on potatoes, which heavily relied on family members and neighbouring farmers. Provision of quality seeds and training of farmers with the support of demonstrations on fertilizer and pesticide and appropriate crop rotation practices are recommended for improved potato production and yields. Use of irrigation where possible should be enhanced through government and development partners’ support to ensure sustainable potato production and supply. Also, the use of viable extension information channel(s) could enhance potato production for household food security, livelihoods and national goals.
Phantom study on surgical performance in augmented reality laparoscopy
Authors: Heiliger Christian , Heiliger Thomas , Deodati Alessandra , Winkler Alexander , Grimm Matthias , Kalim Faisal , Esteban Javier , Mihatsch Lorenz , Hiendl Lena , Andrade Dorian , Frank Alexander , Jacob Sven , Mohamed Khaled Ahmed , Solyanik Olga , Mandal Subhamoy , Werner Jens , Eck Ulrich , Navab Nassir , Karcz Konrad 
Published: December 2022

AbstractPurposeOnly a few studies have evaluated Augmented Reality (AR) in in vivo simulations compared to traditional laparoscopy; further research is especially needed regarding the most effective AR visualization technique. This pilot study aims to determine, under controlled conditions on a 3D-printed phantom, whether an AR laparoscope improves surgical outcomes over conventional laparoscopy without augmentation.MethodsWe selected six surgical residents at a similar level of training and had them perform a laparoscopic task. The participants repeated the experiment three times, using different 3D phantoms and visualizations:Floating AR,Occlusion AR, and without any AR visualization (Control). Surgical performance was determined using objective measurements. Subjective measures, such as task load and potential application areas, were collected with questionnaires.ResultsDifferences in operative time, total touching time, and SurgTLX scores showed no statistical significance ($$p>0.05$$p>0.05). However, when assessing the invasiveness of the simulated intervention, the comparison revealed a statistically significant difference ($$p=0.009$$p=0.009). Participants felt AR could be useful for various surgeries, especially for liver, sigmoid, and pancreatic resections (100%). Almost all participants agreed that AR could potentially lead to improved surgical parameters, such as operative time (83%), complication rate (83%), and identifying risk structures (83%).ConclusionAccording to our results, AR may have great potential in visceral surgery and based on the objective measures of the study, may improve surgeons' performance in terms of an atraumatic approach. In this pilot study, participants consistently took more time to complete the task, had more contact with the vascular tree, were significantly more invasive, and scored higher on the SurgTLX survey than with AR.
Corrosion Behavior of EN18 Steel and Copper in the Sulfuric Acid Medium for As-Bought and Annealed Materials
Authors: Jomy Jilna , Sharma Sathyashankara , Prabhu P. R. , Prabhu Deepa 
Published: December 2022

AbstractEN18 steel and copper are used as materials for oil and gas industries for chemical storage, which come in contact with the sulfuric acid medium during the pickling process. In such instances cleaning of impurities and oxide layer removal, leads to excessive corrosion. Thus, the improvement in the microstructure through annealing treatment and its effect on the corrosion behavior of EN18 steel and copper are studied by immersing in 0.5 M H2SO4 for as-bought and 0.5, 0.25, 0.1 M H2SO4 medium solutions after annealing treatment. The metal specimens were heated to 900 °C for EN18 steel and 600 °C for copper and then both were furnace cooled and the change in the microstructure of annealed and as-received metal specimens was analyzed using Scanning Electron microscopy (SEM). The Electrochemical Impedance Spectroscopy (EIS) and Potentiodynamic polarization (PDP) measurement showed that there is a decrease in the corrosion rate for both metals after annealing treatment. The effect of corrosion rate at the temperature range of 30-50 °C was analyzed and activation parameters were described using Arrhenius and transition state theories. Suitable corrosion mechanisms for both steel and copper in the H2SO4 medium have been discussed.
Graph-based prediction of missing KPIs through optimization and random forests for KPI systems
Authors: May Marvin Carl , Fang Zeyu , Eitel Michael B. M. , Stricker Nicole , Ghoshdastidar Debarghya , Lanza Gisela 
Published: December 2022

AbstractKey performance indicators (KPIs) are widely used to monitor and control the production in industry. On an aggregated level, often represented as graphs or interrelated KPI systems, a comprehensive overview is given. However, missing or inaccurate sensor data and KPIs, as well inconsistencies in KPI based management are a major hurdle disturbing operations. To counter the impact of such missing KPIs, we propose a value optimization based approach to reconstruct the values of missing KPIs within a KPI system. While the approach shows successful reconstruction in the case study, the value optimization can be sped up through a random forest prediction of the initial optimization set. Thus, the inclusion of previous knowledge about the system behavior proves beneficial and superior to the pure optimization based approach, as validated by both randomized and simulation-based measurement data.
Wood Hemicelluloses as Innovative Wall Materials for Spray-Dried Microencapsulation of Berry Juice: Part 1—Effect of Homogenization Techniques on their Feed Solution Properties
Authors: Halahlah Abedalghani , Piironen Vieno , Mikkonen Kirsi S. , Ho Thao M. 
Published: December 2022

AbstractThe use of wood hemicelluloses, including galactoglucomannans (GGM) and glucuronoxylans (GX), in spray-dried microencapsulation of bioactive compounds has not been reported. Our study aims to investigate the benefits of spray-dried GGM and GX powders (sGGM and sGX) along with the effects of homogenization techniques (magnetic stirring, ultrasonication, and a combination of UltraTurrax homogenization and microfluidization) on the physicochemical properties of feed solutions (10–20%, w/w). Feed solutions of bilberry juice with sGGM, sGX, and mixtures of either sGGM or sGX with methylcellulose (MC) or carboxymethylcellulose (CMC) were examined to produce highly stable feed solutions for spray-dried microencapsulation. The effects of ultrasonication amplitudes (30–80%) on the viscosity and particle size distribution of sGGM feed solutions were more profound than observed in their sGX counterparts. Unlike sGX feed solutions, sGGM feed solutions homogenized by ultrasonication and microfluidization formed a gel-like structure. Microfluidization also caused a loss of total anthocyanin content (TAC) of the feed solutions. Magnetic stirring resulted in no gel formation and in the lowest viscosity of the feed solutions; hence, it is an effective method for preparing hemicellulose feed solutions. sGGM and sGX powders have high heat stability with melting temperatures of 170–180 °C. The sGGM + CMC combination was more stable over 1 week of storage than the sGGM and sGX feed solutions. Storing the feed solutions reduced TAC and increased sGGM viscosity. Our results indicated that GGM and GX have high potential for use as wall materials in the spray-dried microencapsulation of bioactive compounds.
Effect of Temporarily Opening and Closing the Marine Connection of a River Estuary
Authors: Montagna Paul A. , Palmer Terence A. , Pollack Jennifer Beseres 
Published: December 2022

AbstractThe lower Rio Grande is a river-dominated estuary that serves as the border between Texas, USA, and Tamaulipas, Mexico. River estuaries encompass the section of the river influenced by tidal exchange with the Gulf of Mexico, but the connection with the Rio Grande is intermittent and can be temporarily open or closed. During the 4.8-year study period, the river mouth was closed 30% of the time, mostly during average or dry climatic conditions, with the temporary closing of the river mouth being linked to hydrology. When the Rio Grande estuary is closed, salinity is low (1.5 psu compared to 4.8 psu when open), nitrate plus nitrite are low (4.4 μM compared to 31.5 μM when open), and ammonium is high (9.6 μM compared to 4.3 μM when open), but chlorophyll is similar (20 μg/L compared to 21 μg/L when open). Benthic macrofaunal abundance and biomass are higher when the river mouth is closed: 16,700 individuals m−2 and 3.3 g m−2 compared to 8800 individuals m−2 and 2.4 g m−2 when the Rio Grande river mouth is open. Benthic macrofaunal community structure is divided into two groups: chironomid larvae and Oligochaeta dominated when the river mouth was closed, whereas polychaetes Mediomastus ambiseta and Streblospio benedicti dominated when the river mouth was open. The implications of these results for managing freshwater flows are that the open and closed conditions each have a characteristic benthic macrofaunal community that is strongly influenced by system hydrology.