bluuebunny/crossref_metadata_2025_split huggingface dataset:
Achieving sustainable development by reducing income inequality: The differential impact of industrial land expansion in urban agglomerations
Authors: Li Qiao , Chen Wei , Zhang Sun , Shi Haimeng 
Published: March 2023

AbstractReducing inequality is essential to achieving sustainable development goals (SDGs). This study aims to clarify the relationship between industrial land expansion, which is closely related to global urban expansion, and inequality reductions and propose strategies to reduce inequality from the perspective of resource utilization. A geographically and temporally weighted regression (GTWR) model is to analyze the impact of industrial land expansion on the urban–rural income gap using data from 215 cities in 19 urban agglomerations in China from 2007 to 2018. The estimation results show that the scale and structure of industrial land expansion differently impact the urban–rural income gap: the expansion scale and structure mainly have a shrinking and expanding effect, respectively. The stage differences of impacts are obvious, with 2013 as the turning point. Finally, there are significant differences between urban agglomerations. The shrinking effect of the expansion scale is smaller in the mature stage than in the development and cultivation stage, while the expanding effect of the expansion structure is more apparent in the cultivation stage. Thus, the differential characteristics and laws of urban agglomeration development can provide useful insights for policymakers as they help to understand the characteristics of industrial land use in urban agglomeration at different stages of development and to reasonably allocate industrial land resources, giving full play to their important role in achieving SDGs.
Studying the Effect of different Temperatures Synthesis of Fe3O4/MnO2 Microrobots on Water Remediation
Authors: Wang Wei long , Lu Hao , Wang Tao bin , Wang Ying 
Published: March 2023

AbstractIndustrial emissions of organic pollutants pose a serious threat to the water environment on which people depend. The effective combination of MnO2‐based microrobots with Fe3O4 nanoparticles offers a promising solution to this challenge. In this work, Fe3O4/MnO2 microrobots were synthesised using a low‐cost and efficient one‐step hydrothermal method. It was found that the kinematic speed of the microrobots increased significantly with increasing synthesis temperature. In addition, the higher the synthesis temperature of Fe3O4/MnO2 microrobots, the more effective they were in removing organic pollutants. The results showed that different structures of MnO2 were produced at different temperatures and the effect of the synthesised microrobots at 80 °C, 100 °C and 130 °C on the catalytic performance and degradation effect was investigated. The Fe3O4/MnO2 microrobots synthesised at 130° showed the most favourable effect on the catalytic performance and degradation. This finding provides a new strategy for future microrobots for water remediation.
Carbon Nanotube Supported CdM(S, Se)/CdTe Anode Catalysts for Electrooxidation of Glucose in Alkaline Media
Authors: Caglar Aykut , Kivrak Hilal , Aktas Nahit 
Published: March 2023

AbstractThe sequential sodium borohydride (SBH, NaBH4) reduction method was utilized to prepare the 0.1 % CdSe/CNT, 0.1 % CdS/CNT, 0.1 % (CdS−CNT)/CdTe, and 0.1 % (CdSe−CNT)/CdTe catalysts. The XRD, SEM‐EDS, TEM, and XPS analyses were used to characterize the catalysts. The electrochemical measurements were examined by cyclic voltammetry (CV), chronoamperometry (CA), and electrochemical impedance spectroscopy (EIS) analyses for glucose electrooxidation. The characterization analyses revealed that the desired structure was formed on the support material. The electrochemical analysis results indicated that the 0.1 % (CdSe−CNT)/CdTe catalyst has higher catalytic activity, stability, and resistance compared to other catalysts with a specific activity of 2.4 mA cm−2.
Synthesis and Characterization of Some Azole Derivatives as Potential Biological and Anticancer Agents
Authors: Uygun Cebeci Yıldız , Ceylan Şule , Altun Muhammed , Alpay Karaoğlu Şengül 
Published: March 2023

AbstractThe treatment of 4‐{[(1E)‐(2,4‐dichlorophenyl)methylene]amino}‐5‐methyl‐2,4‐dihydro‐3H‐1,2,4‐triazol‐3‐one (2) was synthesized from 4‐amino‐5‐methyl‐2,4‐dihydro‐3H‐1,2,4‐triazol‐3‐one (1). Then ethyl (4‐{[(1E)‐(2,4‐dichlorophenyl)methylene]amino}‐3‐methyl‐5‐oxo‐4,5‐dihydro‐1H‐1,2,4‐triazol‐1‐yl)acetate (3) were synthesized by the condensation of compounds 2 with ethyl bromoaetate in basic media. The reaction compound 3 with hydrazine hydrate led to the formation of acid hidrazides (4). The carbohydrazide derivative (5) were afforded by the reaction corresponding 4 with arylisocyanate. Then, this compounds were converted to the corresponding 1,2,4‐triazole derivatives (6) in basic media. The reaction of compounds 6 with several heterocyclic amines in the presence of formaldehyde afforded the corresponding Mannich bases containing various pharmacophore groups (7 a–b). The structures of recently obtained molecules were elucidated on the foundation of 1H NMR, 13C NMR, FT IR, EI MS methods and elemental analysis. All novel synthesized molecules were investigated for their antimicrobial activity. Most of the acquired structures were observed to have excellent antimicrobial property against to most of the test microorganisms. And these compounds have activity better than the standard drug ampicillin and streptomycin In addition, it has been reported that several of the products have potent antiproliferative activities against HeLa cervical cancer cells, while at the same time demonstrating cytotoxic effects toward normal cells.
A Facile Deep Eutectic Solvent (DES) Mediated Green Approach for the Synthesis of Fluorescein and Phenolphthalein Dyes
Authors: Rather Ishfaq Ahmad , Ali Rashid 
Published: March 2023

AbstractOwing to the giant significance of organic dyes in both analytical as well as supramolecular chemistry, here, we report an efficient and green methodology for the preparation of indicator dyes, namely fluorescein and phenolphthalein. This particular method involves an inexpensive, reusable, and biodegradable deep eutectic solvent (DES) of choline chloride (ChCl) and zinc chloride (ZnCl2) in a ratio of 1 : 2, to furnish the corresponding dyes with an appropriate stoichiometry of the easily accessible starting materials. Strikingly, in this procedure, DES played a two‐fold role both as a catalyst as well as solvent and was efficiently recycled for four successive runs with no substantial cascading in the yields of the anticipated products. This simple yet efficient environmentally realistic protocol, to our best knowledge, is the first method, whereby DES has been employed in the successful preparation of any dye molecule to date. Hopefully, this novel procedure for dye(s) synthesis will be of much importance not only from the researchers perspective, but it will also provide a new way for both undergraduate and postgraduate level experiments.
An Inorganic‐Rich SEI Layer by the Catalyzed Reduction of LiNO3 Enabled by Surface‐Abundant Hydrogen Bonding for Stable Lithium Metal Batteries
Authors: Kim Subin , Cho Ki‐Yeop , Kwon JunHwa , Sim Kiyeon , Seok Dain , Tak Hyunjong , Jo Jinhyeon , Eom KwangSup 
Published: March 2023

AbstractLithium (Li) metal anodes (LMAs) are promising anode candidates for realizing high‐energy‐density batteries. However, the formation of unstable solid electrolyte interphase (SEI) layers on Li metal is harmful for stable Li cycling; hence, enhancing the physical/chemical properties of SEI layers is important for stabilizing LMAs. Herein, thiourea (TU, CH4N2S) is introduced as a new catalyzing agent for LiNO3 reduction to form robust inorganic‐rich SEI layers containing abundant Li3N. Due to the unique molecular structure of TU, the TU molecules adsorb on the Cu electrode by forming CuS bond and simultaneously form hydrogen bonding with other hydrogen bonds accepting species such as NO3− and TFSI− through its NH bonds, leading to their catalyzed reduction and hence the formation of inorganic‐rich SEI layer with abundant Li3N, LiF, and Li2S/Li2S2. Particularly, this TU‐modified SEI layer shows a lower film resistance and better uniformity compared to the electrochemically and naturally formed SEI layers, enabling planar Li growth without any other material treatments and hence improving the cyclic stability in Li/Cu half‐cells and Li@Cu/LiFePO4 full‐cells.
Promoting CO2Dynamic Activation via Micro‐Engineering Technology for Enhancing Electrochemical CO2Reduction
Authors: Gong Shanhe , Yang Shaokang , Wang Wenbo , Lu Runqing , Wang Haotan , Han Xu , Wang Guilong , Xie Jimin , Rao Dewei , Wu Chundu , Liu Jun , Shao Shouyan , Lv Xiaomeng 
Published: March 2023

AbstractOptimizing the coordination structure and microscopic reaction environment of isolated metal sites is promising for boosting catalytic activity for electrocatalytic CO2reduction reaction (CO2RR) but is still challenging to achieve. Herein, a newly electrostatic induced self‐assembly strategy for encapsulating isolated Ni‐C3N1moiety into hollow nano‐reactor as I‐Ni SA/NHCRs is developed, which achieves FECO of 94.91% at −0.80 V, the CO partial current density of ≈−15.35 mA cm−2, superior to that with outer Ni‐C2N2moiety (94.47%, ≈−12.06 mA cm−2), or without hollow structure (92.30%, ≈−5.39 mA cm−2), and high FECOof ≈98.41% at 100 mA cm−2in flow cell. COMSOL multiphysics finite‐element method and density functional theory (DFT) calculation illustrate that the excellent activity for I‐Ni SA/NHCRs should be attributed to the structure‐enhanced kinetics process caused by its hollow nano‐reactor structure and unique Ni‐C3N1moiety, which can enrich electron on Ni sites and positively shift d‐band center to the Fermi level to accelerate the adsorption and activation of CO2molecule and *COOH formation. Meanwhile, this strategy also successfully steers the design of encapsulating isolated iron and cobalt sites into nano‐reactor, while I‐Ni SA/NHCRs‐based zinc‐CO2battery assembled with a peak power density of 2.54 mW cm−−2is achieved.
Ligand‐Assistant Iced Photocatalytic Reduction to Synthesize Atomically Dispersed Cu Implanted Metal‐Organic Frameworks for Photo‐Enhanced Uranium Extraction from Seawater
Authors: Liu Tao , Gu Anping , Wei Tao , Chen Mengwei , Guo Xi , Tang Shuai , Yuan Yihui , Wang Ning 
Published: March 2023

AbstractUranium extraction from natural seawater is one of the most promising routes to address the shortage of uranium resources. By combination of ligand complexation and photocatalytic reduction, porous framework‐based photocatalysts have been widely applied to uranium enrichment. However, their practical applicability is limited by poor photocatalytic activity and low adsorption capacity. Herein, atomically dispersed Cu implanted UiO‐66‐NH2 (Cu SA@UiO‐66‐NH2) photocatalysts are prepared via ligand‐assistant iced photocatalytic reduction route. N—Cu–N moiety acts as an effective electron acceptor to potentially facilitate charge transfer kinetics. By contrast, there exist Cu sub‐nanometer clusters by the typical liquid phase photoreduction, resulting in a relatively low photocatalytic activity. Cu SA@UiO‐66‐NH2 adsorbents exhibit superior antibacterial ability and improved photoreduction conversion of the adsorbed U(VI) to insoluble U(IV), leading to a high uranium sorption capacity of 9.16 mg‐U/g‐Ads from natural seawater. This study provides new insight for enhancing uranium uptake by designing SA‐mediated MOF photocatalysts.
Introduction
Authors: Winter Alfred , Ammenwerth Elske , Haux Reinhold , Marschollek Michael , Steiner Bianca , Jahn Franziska 
Published: March 2023

AbstractHealth is one of the key components of our lives. Information systems play a role in many life situations. Life situations comprise normal living, where prevention and wellness are related to health, to emergencies, acute diseases, chronic diseases, care, and rehabilitation. Different stakeholders may have specific requirements regarding health information systems. Such stakeholders comprise patients, healthcare professionals, informal caregivers, biomedical researchers, and management staff in healthcare facilities, insurance companies, governmental bodies, and sponsors. Their requirements of health information systems are sometimes similar and therefore coincide. Other times, however, they tend to conflict and may even become contradictory. To appropriately manage health information systems in the current era of digitization, it is important to be aware of these life situations and stakeholder requirements.
Management Perspective: Scopes and Tasks of Managing Health Information Systems
Authors: Winter Alfred , Ammenwerth Elske , Haux Reinhold , Marschollek Michael , Steiner Bianca , Jahn Franziska 
Published: March 2023

AbstractManagement of information systems can be divided into strategic, tactical, and operational management.Strategic management of information systems deals with the information processing of a healthcare facility as a whole. It comprises the planning of the information system’s architecture and of the organization of information management. The tasks of strategic management are planning an information system and its architecture, directing its establishment and its operation, and monitoring its development and operation with respect to the planned objectives. The strategic information management plan represents the long-term planning of the information system of a healthcare facility.Tactical management of information systems deals with particular functions, application components, or physical data processing systems that are introduced, removed, or changed. Usually, these activities are done in the form of projects.Operational management of information systems is responsible for operating the components of the information system. It ensures the smooth operation of the systems in accordance with the strategic information management plan of the healthcare facility.IT governance deals with the organizational structures for decision-making in the management of information systems. Typical organizational structures include the role of a chief information officer who focuses on the strategic management of information systems, an information management board, and a department of information management in charge of the strategic, tactical, and operational management.Management of information systems must find a balance between often conflicting goals, for example, between homogeneity and heterogeneity of the information system architecture or between functional leanness and functional redundancy.
Information Systems for Specific Health Care and Research Settings
Authors: Winter Alfred , Ammenwerth Elske , Haux Reinhold , Marschollek Michael , Steiner Bianca , Jahn Franziska 
Published: March 2023

AbstractHealth care in different life situations is provided in various health care settings. Consequently, the information systems of different health care settings show specific characteristics both from a technological and a management perspective.Information systems in hospitals have to address the information needs of many clinical and administrative areas and groups of persons. Hospital information systems must therefore support a large number of functions and integrate a comparably large number of application components. Integrity and integration are thus especially crucial topics. Overall, systematic information management is essential in hospitals, being the most complex institutional health care setting.Information systems in nursing homes are typically less complex, as the number of areas and persons is smaller. Consequently, the number of application components is lower than in hospitals. Information systems in ambulatory nursing organizations and medical offices are even less complex and may comprise an even smaller number of application systems. Nevertheless, systematic management of the specific information systems is still needed at least to some extent in order to respond to specific requirements in these health care settings.Information systems in medical research facilities support dedicated functions such as research management or the planning and executing of studies. They typically comprise numerous application components and also have to respond to the requirement of cross-institutional or interprofessional research collaboration.Information systems in personal environments may typically support wellness, prevention, treatment, or rehabilitation and may be either part of institutional health information systems or be realized as a separate information system in a personal environment.
Electron Polarization
Authors: Lin Fanglei 
Published: March 2023

AbstractThis chapter focuses on the introduction and discussion of electron polarization. In addition to the gyromagnetic ratio, the most different character of electrons compared to protons is that electrons radiate electromagnetic energy in a circular accelerator. A very small correction has to be applied to the electron spin flip to account for the synchrotron radiation. The different instantaneous spin flip probabilities, up to down and down to up, can build up the electron beam polarization state. However, mostly synchrotron radiation tends to disturb the electron orbital motion that is eventually balanced by the radiation damping along an equilibrium orbit. The electron spin motion is described by the modified Thomas-BMT equation with the radiative spin transition term included. Detail of the electron (de)polarization phenomena is described in this chapter. The lecture is extracted from various early theoretical papers, lectures, thesis and presentations (Lee, Accelerator Physics. World Scientific Publishing, 1999; Buon and Koutchouk, Polarization of Electron and Proton Beams. CERN-SL-94-80-AP, 1994; Montague, Phys. Rep. 113(1):1–96, 1984; Lee, Spin Dynamics and Snakes in Synchrotrons. World Scientific Publishing, 1997; Barber and Ripken, Handbook of Accelerator Physics and Engineering, 1st edn. World Scientific Publishing, 2006; Barber, An Introduction to Spin Polarisation in Accelerators and Storage Rings. Cockcroft Institute Academic Training Winter Term, 2014; Mane, Nucl. Instr. Methods Phys. Res. A 292:52–74, 1990; Berglund, Spin-Orbit Maps and Electron Spin Dynamics for the Luminosity Upgrade Project at HERA. DESY-THESIS-2001-044, 2001; Electron-Ion Collider Conceptual Design Report, 2020).
Grundbegriffe
Authors: Fischer-Kongtso Satu 
Published: March 2023

ZusammenfassungNachdem ﻿in Kapitel 1 Forschungsinteresse und Ansatz der vorliegenden Arbeit abgesteckt wurden, folgt in Kapitel 2 nun die Erörterung ihrer zentralen theoretischen Grundbegriffe. Die Unterkapitel orientieren sich an den in Kapitel 1 etablierten Konzepten: 2.1 Nation und Nationalismus, 2.2 Identität und Integration, 2.3 Kultur und Emotion, 2.4 Diskurs, Wissen und Macht sowie 2.5 Staatsangehörigkeit und Einbürgerung. Das übergeordnete Ziel ist dabei die Entwicklung eines soliden theoretischen Rahmens für einen allgemeinen Ansatz der Diskursethnologie sowie dessen spezifische Anpassung auf das Themenfeld Nationalismus und Einbürgerung.
Bausteine einer Diskursethnologie
Authors: Fischer-Kongtso Satu 
Published: March 2023

ZusammenfassungAuf ﻿Basis der in Kapitel 2 erarbeiteten Grundbegriffe und der sich daraus ergebenden Vision einer ethnologisch fokussierten Diskurstheorie folgt im vorliegenden 3. Kapitel dieser Arbeit deren methodisch-operationale Ausgestaltung. Anhand einzelner Ausschnitte des zu untersuchenden Diskursfeldes – 3.1 Einbürgerungsinitiative; 3.2 öffentliche Debatte; 3.3 TGH-Lotsenprojekt; 3.4 Grenzgänger_innen im Diskursfeld 3.5 Einbürgerungsfeiern – werden Bausteine eines diskursethnologischen Ansatzes identifiziert, begründet und im Detail ausformuliert. Die mit Hilfe dieses Ansatzes im Feld gewonnenen Daten werden sortiert und für die weitere Auswertung transparent gemacht.
Die dominanten Diskursströmungen
Authors: Fischer-Kongtso Satu 
Published: March 2023

ZusammenfassungIm ﻿Anschluss an den theoretischen Entwurf eines diskursethnologischen Ansatzes (Kapitel 2) und dessen methodische Operationalisierung (Kapitel 3) werden nachfolgend die Ergebnisse der in dieser Arbeit darzustellenden Untersuchung erörtert. Die Analyse beginnt in Kapitel 4 mit der Vorstellung der beiden dominanten Diskursströmungen im Diskursfeld – der staatsnationalen Strömung (Abschnitt 4.1) sowie der ethnonationalen Strömung (Abschnitt 4.2) – und stellt diese einander in einer abschließenden Konfrontation gegenüber (Abschnitt 4.3).
Prävention von Pflegebedürftigkeit
Authors: Blüher Stefan , Schilling Ralph , Stein Thomas , Gellert Paul 
Published: March 2023

Zusammenfassung
Hintergrund
Die Bedeutung der Prävention von Pflegebedürftigkeit wächst mit der Zunahme von pflegebedürftigen Menschen. Für Deutschland gibt es bislang nur unzureichende Daten darüber, welche Faktoren mit der Entstehung einer Pflegebedürftigkeit assoziiert sind. Die vorliegende Studie untersucht die Wechselwirkungen zwischen soziodemografischen und gesundheitsbezogenen Determinanten von Pflegebedürftigkeit, um daraus präventive Anknüpfungspunkte abzuleiten.

Methoden
Analysiert wurden die Begutachtungsdaten des Medizinischen Dienstes (MD) Berlin-Brandenburg zur Feststellung einer Pflegebedürftigkeit nach SGB XI für die Zeiträume 2017 und 2018/2019 mit Fokus auf die Antragstellenden, die über den betrachteten Zeitraum hinweg ohne Pflegegradeinstufung blieben (6037 von insg. 72.680 Antragstellenden des Jahres 2017). Soziale Faktoren wie Haushaltszusammensetzungen, Unterstützungspotenziale und Partnerschaftsstatus wurden über Text-Mining-Verfahren extrahiert und die Daten mittels deskriptiver und multivariabler statistischer Verfahren ausgewertet.

Ergebnisse
Eine erhöhte Chance, ohne Pflegegradeinstufung zu bleiben, hatten jüngere Antragstellende sowie Personen ohne Partnerschaft. Im Zeitraum 2018/2019 ebenfalls assoziiert mit einer erhöhten Chance, ohne Pflegegrad zu bleiben, waren eine Verbesserung der Gesundheit, seit 2017 ohne soziale Unterstützung zu sein, muskuloskelettale Erkrankungen sowie chronisch ischämische Herzkrankheiten. Geringere Chancen, ohne Pflegegradeinstufung zu bleiben, hatten hingegen Antragstellende mit demenziellen und sonstigen psychischen Erkrankungen.

Diskussion
Die erstmalige Untersuchung der MD-Begutachtungsdaten unter einer präventiven Perspektive zeigt, dass soziodemografische und gesundheitsbezogene Determinanten in Wechselwirkung betrachtet werden müssen, um zusätzliche Präventionspotenziale auszumachen
Homozygous loss-of-function variants in FILIP1 cause autosomal recessive arthrogryposis multiplex congenita with microcephaly
Authors: Schnabel Franziska , Schuler Elisabeth , Al-Maawali Almundher , Chaurasia Ankur , Syrbe Steffen , Al-Kindi Adila , Bhavani Gandham SriLakshmi , Shukla Anju , Altmüller Janine , Nürnberg Peter , Banka Siddharth , Girisha Katta M. , Li Yun , Wollnik Bernd , Yigit Gökhan 
Published: March 2023

AbstractArthrogryposis multiplex congenita forms a broad group of clinically and etiologically heterogeneous disorders characterized by congenital joint contractures that involve at least two different parts of the body. Neurological and muscular disorders are commonly underlying arthrogryposis. Here, we report five affected individuals from three independent families sharing an overlapping phenotype with congenital contractures affecting shoulder, elbow, hand, hip, knee and foot as well as scoliosis, reduced palmar and plantar skin folds, microcephaly and facial dysmorphism. Using exome sequencing, we identified homozygous truncating variants in FILIP1 in all patients. FILIP1 is a regulator of filamin homeostasis required for the initiation of cortical cell migration in the developing neocortex and essential for the differentiation process of cross-striated muscle cells during myogenesis. In summary, our data indicate that bi-allelic truncating variants in FILIP1 are causative of a novel autosomal recessive disorder and expand the spectrum of genetic factors causative of arthrogryposis multiplex congenita.