bluuebunny/crossref_metadata_2025_split huggingface dataset:
Identification and Characterization of Arbuscular Mycorrhizal Strains from the Roots and Rhizospheres of Tomato, Brinjal, Chilli and Onion
Authors: Banu Most. Bilkis , Mian Musharraf Hossain , Rahman M. Mazibur , Moslehuddin Abu Zofar Md. , Matin Mohammad Quamrul Islam 
Published: January 2023

Rhizosphere soils and roots of two vegetables (tomato and brinjal) and two spices (chilli and onion) crops were collected from each of four Agro-Ecological Zones (AEZs) of Bangladesh viz. AEZ-9 (RARS, Jamalpur), AEZ-11 (RARS, Jashore), AEZ-25 (ARS, Bogura) and AEZ-28 (BARI, Joydebpur) in 2014-2015. Characterization and identification of arbuscular mycorrhizal strains were studied in the microbiology laboratory of the Bangladesh Agricultural Research Institute (BARI). Different crops showed positive responses in percent root colonization such as 74.11-83.78%, 22.11-24.33%, 7.33-8.89%, and 6.67-9.33% in onion, tomato, chilli, and brinjal, respectively. Rhizosphere soil of individual crops had also variations in the number of spore populations such as 120.11-200.33, 33.44-50.78, 36.11-39.22, and 28.56-41.89 per 100g soil in onion, tomato, chilli, and brinjal, respectively. Eleven AM strains were identified in tomatoes: Glomus geosporum, G. mosseae, G. fasciculatum, G. spp., Acaulospora dilatata, A. bireticulata, A. mellea, A. morrowiae, Entrophospora infrequens, Sclerocystis coremioides and Gigaspora margarita. Nine each were identified from other three crops. G. spp. and Acaulospora bireticulata were absent in brinjal and chilli. Acaulospora dilatata and A. mellea were absent in onion. The formation of AM structures was found inconsistent and fluctuating from site to site in the present study. Both oval and spherical-shaped vesicles were found among the AM structures.
Determinants of Audit Delay in Companies Listed on the Indonesia Stock Exchange during the Covid-19 Pandemic
Authors: Manaf Sodikin , Sulastri Putu , Pitoyo Agus , Sujarwo Anton 
Published: January 2023

Aims: This study about audit delay aims to test the influence size company, solvability, profitability, switching auditors and internal control system (ICS) on audit delay in companies listed on the Indonesia Stock Exchange.
Study Design: The design of this research study is correlational.
Place and Duration of Study: Indonesia Stock Exchange (IDX) in 2020.
Methodology: The population study was companies listed on the Indonesia Stock Exchange (IDX) in 2020. Samples 84 are determined based on the formula Slovin, with the simple random sampling technique. The analytical technique used multiple linear regression with SPSS 24 program assistance.
Results: Research results show that during the COVID-19 pandemic, profitability and ICS decrease audit delay and solvability upgrade audit delay; meanwhile, size companies and switching auditors are not influential in auditing delays.
Conclusion: Research results in this support theory signalling, providing proof of empirical influence profitability and ICS lower audit delays.
Effect of atorvastatin on lipoxygenase pathway‐related gene expression in an in vitro model of lipid accumulation in hepatocytes
Authors: Golfetto Miskiewicz Ivanna Carolina , Cho Hyen Chung , Lee Ji In , Lee Jihye , Lee Yenna , Lee Yun Kyung , Choi Sung Hee 
Published: January 2023

Lipid accumulation in hepatocytes can result from an imbalance between lipid acquisition and lipid catabolism. In recent years, it has been discovered that eicosanoids derived from arachidonic acid (AA) have the potential to create specialized pro‐resolving lipid mediators to actively resolve inflammation, but it is not clear whether AA and lipoxygenases exert effects on hepatic inflammation. Here, the effects of atorvastatin on the expression of cytoplasmic phospholipase A2 (cPLA2) and lipoxygenase pathway genes (ALOX5, ALOX12, ALOX15, and ALOX15B) were evaluated in an in vitro model of palmitic acid (PA)‐induced hepatocyte lipid accumulation in McA‐RH7777 (McA) cells. Palmitic acid increased cPLA2 expression, intracellular AA levels, and ALOX12 expression (P < 0.05). Atorvastatin at various concentrations had no significant effects on AA levels or on cPLA2, ALOX15, and ALOX15B expressions. ALOX5 was not detected, despite multiple measurements. Pro‐inflammatory IL‐1β expression levels were upregulated by PA (P < 0.01) and attenuated by atorvastatin (P < 0.001). TNFα did not differ among groups. The expression levels of anti‐inflammatory IL‐10 decreased in response to PA (P < 0.05), but were not affected by atorvastatin. In conclusion, in an in vitro model of lipid accumulation in McA cells, atorvastatin reduced IL‐1β; however, its effect was not mediated by AA and the lipoxygenase pathway at the established doses and treatment duration. Further research is required to investigate time‐response data, as well as other drugs and integrated cell systems that could influence the lipoxygenase pathway and modulate inflammation in liver diseases.
3D Micropatterned Functional Surface Inspired by Salvinia Molesta via Direct Laser Lithography for Air Retention and Drag Reduction
Authors: Tricinci Omar , Pignatelli Francesca , Mattoli Virgilio 
Published: January 2023

AbstractBioinspired functional surfaces are attracting increasing interest in surface engineering, mostly in the field of wettability. The Salvinia‐effect is a remarkable example of superficial air retention and drag force reduction caused by selective chemical coating (super‐hydrophobic wax and hydrophilic dead cells) and peculiar 3D hierarchical morphological structures. The replication of Salvinia‐like patterns at the microscale has always been prevented by limitations in microfabrication techniques, thus hindering relevant technological applications at this dimensional scale. Integrating 3D laser lithography and traditional microfabrication techniques, dimensionally downscaled, 3D micropatterned surfaces inspired for the first time by both morphology and chemical coating of the hairs present on the Salvinia Molesta leaves are reproduced. The effect of design and different surface energies (bare hydrophilic, hydrophobic, selective hydrophilic/hydrophobic coating) on the wettability are modeled and investigated. Bioinspired surfaces demonstrated to be super‐hydrophobic in terms of apparent static contact angle (up to 170°) and provide tunable adhesion with roll‐off angle from less than 10° to 90°. They successfully proved remarkable underwater air retention capability, sustained by stable Cassie‐Baxter state under external hydrostatic pressure up to 4 atm. The proposed surfaces are tested in hydrodynamic conditions: drag force reduction is successfully demonstrated with up to 40% of energy saved.
Multivalent Lactobionic Acid and N‐Acetylgalactosamine‐Conjugated Peptide Nucleic Acids for Efficient In Vivo Targeting of Hepatocytes
Authors: Kumar Vikas , Wahane Aniket , Gupta Anisha , Manautou José E. , Bahal Raman 
Published: January 2023

AbstractPeptide nucleic acids (PNAs) are used/applied in various studies to target genomic DNA and RNA to modulate gene expression. Non‐specific targeting and rapid elimination always remain a challenge for PNA‐based applications. Here, the synthesis, characterization, in vitro and in vivo study of di lactobionic acid (diLBA) and tris N‐acetyl galactosamine (tGalNAc) conjugated PNAs for liver‐targeted delivery are reported. For proof of concept, diLBA, and tGalNAc conjugated PNAs (anti‐miR‐122 PNAs) were synthesized to target microRNA‐122 (miR‐122) which is over‐expressed in the hepatic tissue. Different lengths of anti‐miR‐122 PNAs conjugated with diLBA and tGalNAc are tested. Cell culture and in vivo analyses to determine biodistribution, efficacy, and toxicity profile are performed. This work indicates that diLBA conjugates show significant retention in hepatocytes in addition to tGalNAc conjugates after in vivo delivery. Full‐length PNA conjugates show significant downregulation of miR‐122 levels and subsequent de‐repression of its downstream targets with no evidence of toxicity. The results provide a robust framework for ligand‐conjugated delivery systems for PNAs that can be explored for broader biomedical applications.
Morphology Tuning via Linker Modulation: Metal‐Free Covalent Organic Nanostructures with Exceptional Chemical Stability for Electrocatalytic Water Splitting
Authors: Karak Shayan , Koner Kalipada , Karmakar Arun , Mohata Shibani , Nishiyama Yusuke , Duong Nghia Tuan , Thomas Neethu , Ajithkumar Thalasseril Govindankuttykaimal , Hossain Munshi Sahid , Bandyopadhyay Subhajit , Kundu Subrata , Banerjee Rahul 
Published: January 2023

AbstractThe development of synthetic routes for the formation of robust porous organic polymers (POPs) with well‐defined nanoscale morphology is fundamentally significant for their practical applications. The thermodynamic characteristics that arise from reversible covalent bonding impart intrinsic chemical instability in the polymers, thereby impeding their overall potential. Herein, a unique strategy is reported to overcome the stability issue by designing robust imidazole‐linked POPs via tandem reversible/irreversible bond formation. Incorporating inherent rigidity into the secondary building units leads to robust microporous polymeric nanostructures with hollow‐spherical morphologies. An in‐depth analysis by extensive solid‐state NMR (1D and 2D) study on 1H, 13C, and 14N nuclei elucidates the bonding and reveals the high purity of the newly designed imidazole‐based POPs. The nitrogen‐rich polymeric nanostructures are further used as metal‐free electrocatalysts for water splitting. In particular, the rigid POPs show excellent catalytic activity toward the oxygen evolution reaction (OER) with long‐term durability. Among them, the most efficient OER electrocatalyst (TAT‐TFBE) requires 314 mV of overpotential to drive 10 mA cm−2 current density, demonstrating its superiority over state‐of‐the‐art catalysts (RuO2 and IrO2).
Dual‐Mode Integrated Janus Films with Highly Efficient NaH2PO2‐Enhanced Infrared Radiative Cooling and Solar Heating for Year‐Round Thermal Management
Authors: Yang Peng , He Jiajun , Ju Yanshan , Zhang Qingyuan , Wu Yipeng , Xia Zhengcai , Chen Liang , Tang Shaochun 
Published: January 2023

AbstractThe currently available materials cannot meet the requirements of human thermal comfort against the hot and cold seasonal temperature fluctuations. In this study, a dual‐mode Janus film with a bonded interface to gain dual‐mode functions of both highly efficient radiative cooling and solar heating for year‐round thermal management is designed and prepared. The cooling side is achieved by embedding NaH2PO2 particles with high infrared radiation (IR) emittance into a porous polymethyl methacrylate (PMMA) film during pore formation process, which is reported for the first time to the knowledge. A synergistic enhancement of NaH2PO2 and 3D porous structure leads to efficient radiant cooling with high solar reflectance (R̅solar ≈ 92.6%) and high IR emittance (ε̅IR ≈ 97.2%), especially the ε̅IR value is much greater than that of the reported best porous polymer films. In outdoor environments under 750 mW cm−2 solar radiation, the dual‐mode Janus film shows subambient cooling temperature of ≈8.8 °C and heating temperature reaching ≈39.3 °C, indicating excellent thermal management capacity. A wide temperature range is obtained only by flipping the dual‐mode Janus film for thermal management. This work provides an advanced zero‐energy‐consumption human thermal management technique based on the high‐performance dual‐mode integrated Janus film material.
Direct‐Ink‐Write 3D Printing of Programmable Micro‐Supercapacitors from MXene‐Regulating Conducting Polymer Inks
Authors: Li Le , Meng Jian , Bao Xuran , Huang Yunpeng , Yan Xiu‐Ping , Qian Hai‐Long , Zhang Chao , Liu Tianxi 
Published: January 2023

Abstract3D printing is gaining prospects thanks to the ease of manufacturing energy storage devices with programmable geometry at the macro‐ and microscales. Herein, a direct ink writing 3D printing approach for preparing all‐printed flexible micro‐supercapacitors is demonstrated using rationally designed poly(3,4‐ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS)/MXene composite gels as inks without the tedious processes and toxic organic additives. Among the printable inks, the homogeneously distributed MXene nanosheets can boost the printability of PEDOT:PSS solution and also regulate the interconnected electronic structures of the PEDOT:PSS undergoing a micellar to linear structure transition. The resulting 3D printed micro‐supercapacitors and integrated devices can deliver exceptionally large areal capacitances, remarkable rate performance, and high cycling stability with thickness‐independent capacitances even under exceptional deformations and low temperatures. This study thus provides a simple yet environmental‐friendly approach for preparing the conducting‐polymer‐based inks for 3D printing of customized, multiscale, and integrated energy devices.
African apes and the evolutionary history of orthogrady and bipedalism
Authors: Williams Scott A. , Prang Thomas Cody , Russo Gabrielle A. , Young Nathan M. , Gebo Daniel L. 
Published: January 2023

AbstractSince the first discovery of human fossils in the mid‐19th century, two subjects—our phylogenetic relationship to living and fossil apes and the ancestral locomotor behaviors preceding bipedalism—have driven the majority of discourse in the study of human origins. With few fossils and thus limited comparative evidence available to inform or constrain them, morphologists of the 19th and early mid‐20th centuries posited a range of scenarios for the evolution of bipedalism. In contrast, there exists a rich hominin fossil record and the acceptance ofPan(chimpanzees and bonobos) as our closest living relatives is nearly universal, yet consensus about the ancestral condition from which hominins evolved remains elusive. Notably, while the earliest known hominins are generally congruent with parsimonious inferences of an African ape‐like last common ancestor, our more distantly related Miocene ape cousins are frequently invoked as evidence in favor of more complex scenarios that require substantial homoplasy. Debate over these alternatives suggests that how we infer ancestral nodes and weigh evidence to test their relative likelihoods remains a stumbling block. Here we argue that a key contributor to this impasse includes the history of terminology associated with positional behavior, which has become confused over the last century. We aim to clarify positional behavior concepts and contextualize knuckle‐walking and other forms of posture and locomotion chimpanzees and gorillas engage in, while arguing that the presence of homoplasy in ape evolution does not alter the weight of evidence in favor of an African ape‐like evolutionary history of hominins.
Dual cognitive and mobility impairments and future dementia ‐ Setting a research agenda
Authors: Tian Qu , Montero‐Odasso Manuel , Buchman Aron S. , Mielke Michelle M. , Espinoza Sara , DeCarli Charles S. , Newman Anne B. , Kritchevsky Stephen B. , Rebok George W. , Resnick Susan M. , Thambisetty Madhav , Verghese Joe , Ferrucci Luigi 
Published: January 2023

AbstractDual cognitive and mobility impairments are associated with an increased risk of dementia. Recent studies examining temporal trajectories of mobility and cognitive function in aging found that dual decline is associated with higher dementia risk than memory decline or gait decline only. Although initial data show that individuals with dual decline or impairment have excessive cardiovascular and metabolic risk factors, the causes of dual decline or what underlies dual decline with a high risk of dementia remain largely unknown. In December 2021, the National Institute on Aging Intramural and Extramural Programs jointly organized a workshop on Biology Underlying Moving and Thinking to explore the hypothesis that older persons with dual decline may develop dementia through a specific pathophysiological pathway. The working group discussed assessment methods for dual decline and possible mechanisms connecting dual decline with dementia risk and pinpointed the most critical questions to be addressed from a translational perspective.
Economic Evaluation of a Mobile Stroke Unit Service in Germany
Authors: Oliveira Gonçalves Ana Sofia , Rohmann Jessica L. , Piccininni Marco , Kurth Tobias , Ebinger Martin , Endres Matthias , Freitag Erik , Harmel Peter , Lorenz‐Meyer Irina , Rohrpasser‐Napierkowski Ira , Busse Reinhard , Audebert Heinrich J. 
Published: January 2023

BackgroundLower global disability and higher quality of life among ischemic stroke patients was found to be associated with the dispatch of mobile stroke units (MSUs) among patients eligible for recanalizing treatments in the Berlin_Prehospital Or Usual Delivery of stroke care (B_PROUD) study. The current study assessed the cost‐utility and cost‐effectiveness of additional MSU dispatch using data from this prospective, controlled, intervention study.MethodsOutcomes considered in the economic evaluation included quality‐adjusted life years (QALYs) derived from the 3‐level version of EQ‐5D (EQ‐5D‐3L) and modified Rankin Scale (mRS) scores for functional outcomes 3‐months after stroke. Costs were prospectively collected during the study by the MSU provider (Berlin Fire Brigade) and the B_PROUD research team. We focus our results on the societal perspective. As we aimed to determine the economic consequences of the intervention beyond the study's follow‐up period, both care costs and QALYs were extrapolated over 5 years.ResultsThe additional MSU dispatch resulted in an incremental €40,984 per QALY. The best‐case scenario and the worst‐case scenario yielded additional costs of, respectively, €24,470.76 and €61,690.88 per QALY. In the cost‐effectiveness analysis, MSU dispatch resulted in incremental costs of €81,491 per survival without disability. The best‐case scenario and the worst‐case scenario yielded additional costs of, respectively, €44,455.30 and €116,491.15 per survival without disability.InterpretationAmong patients eligible for recanalizing treatments in ischemic stroke, MSU dispatch was associated with both higher QALYs and higher costs and is cost‐effective when considering internationally accepted thresholds ranging from an additional €40,000 to €80,000 per QALY. ANN NEUROL 2023;93:942–951
Virtual Excitations and Entanglement Dynamics and Polygamy in Three Ultra‐Strongly Coupled Systems
Authors: Hab‐arrih Radouan , Jellal Ahmed 
Published: January 2023

AbstractThe Milburn dynamics of three non resonant ultra‐strongly coupled oscillators are resolved by using symplectic geometry. The Milburn dynamics of virtual excitations and how they affect the pairwise entanglement are looked at. It is found that the dynamics of excitations and entanglement experience similar profiles against time, physical parameters, and decoherence rate. Furthermore, it is shown that the extinction of excitations entails separability, which demonstrates the hierarchy between entanglement and virtual excitations. Additionally, the effects of physical parameters on the redistribution of virtual excitations among the three bi‐partitions are analyzed. As a result, the violation of the monogamy of excitations is shown as in quantum discord. This implies that excitations can be considered as signatures of quantum correlations beyond entanglement. Besides, it is emphasized that the treatment can be used to model coupled quantum circuits in real situations (with decoherence).
Development of a General and Selective Nanostructured Cobalt Catalyst for the Hydrogenation of Benzofurans, Indoles and Benzothiophenes
Authors: Zhou Bei , Chandrashekhar Vishwas G. , Ma Zhuang , Kreyenschulte Carsten , Bartling Stephan , Lund Henrik , Beller Matthias , Jagadeesh Rajenahally V. 
Published: January 2023

AbstractThe selective hydrogenation of benzofurans in the presence of a heterogeneous non‐noble metal catalyst is reported. The developed optimal catalytic material consists of cobalt‐cobalt oxide core–shell nanoparticles supported on silica, which has been prepared by the immobilization and pyrolysis of cobalt‐DABCO‐citric acid complex on silica under argon at 800 °C. This novel catalyst allows for the selective hydrogenation of simple and functionalized benzofurans to 2,3‐dihydrobenzofurans as well as related heterocycles. The versatility of the reported protocol is showcased by the reduction of selected drugs and deuteration of heterocycles. Further, the stability, recycling, and reusability of the Co‐nanocatalyst are demonstrated.
Beyond Microporosity in Porous Organic Molecular Materials (POMMs)
Authors: Halliwell Chris , Soria Jesus Ferrando , Fernandez Antonio 
Published: January 2023

AbstractPorous organic molecular materials (POMMs) are a novel class of porous materials that cover a wide range of organic‐based molecular building blocks connected through weak supramolecular interactions, such as hydrogen bonds, π‐π stacking, van der Waals and electrostatic interactions. Despite of their diverse chemical and structural nature, common features to POMMs include solution processability, crystallinity and microporosity. Herein, we focus, for the first time, on the advance of the field of POMMs beyond the archetypical microporosity. In particular, we highlight relevant examples of meso‐ and macroporous POMMs, as well as hierchachical ones (micro‐/meso‐, micro‐/macro‐ and meso‐/macroporous). We also remark some of their unique properties, and how they can be key in many applications.
Silver‐Mediated Cascade Synthesis of Functionalized 1,4‐Dihydro‐2H‐benzo‐1,3‐oxazin‐2‐ones from Carbon Dioxide
Authors: Li Xuetong , Benet‐Buchholz Jordi , Escudero‐Adán Eduardo C. , Kleij Arjan W. 
Published: January 2023

AbstractA conceptually novel catalytic domino approach is presented for the synthesis of highly functional 1,4‐dihydro‐2H‐1,3‐benzoxazine‐2‐one derivatives. Key to the chemoselectivity is a proper design of the precursor to override thermodynamically favored parasitic cyclization processes and empower the formation of the desired product through Thorpe–Ingold effects. The synthetic diversity of these CO2‐based heterocycles is further demonstrated, and the isolation of a reaction intermediate supports an unusual ring‐expansion sequence from an α‐alkylidene, five‐membered cyclic carbonate to a six‐membered cyclic carbamate by N‐induced isomerization.
Environmental DNA survey to detect an endemic cryptic fish, Anablepsoides cryptocallus, in tropical freshwater streams
Authors: Baudry Thomas , Mauvisseau Quentin , Arqué Alexandre , Goût Jean‐Pierre , Delaunay Carine , de Boer Hugo J. , Grandjean Frédéric 
Published: January 2023

Abstract

Martinique island is a biodiversity hotspot in the Lesser Antilles that harbours many endemic species. One of these, Anablepsoides cryptocallus, also known as ‘Poisson gale’, is the only endemic freshwater fish of Martinique and a species with a poorly understood distribution range.
In this study, an environmental DNA (eDNA) detection protocol was developed, validated, and optimized, targeting a short fragment (125 bp) of the A. cryptocallus COI mitochondrial gene, to investigate the presence of this species in Martinique. Fifty‐seven sites spread over 43 permanent rivers and two wetlands were sampled using both eDNA and conventional fishing (dip net capture).
Presence was confirmed in 27 sites using eDNA detection, and in nine sites by dip net fishing. eDNA‐based detection of A. cryptocallus was effective and less time‐consuming than conventional fishing, making it a relevant tool for future studies throughout the island. Even though A. cryptocallus was found to be present in a significant number of sites, many sites previously known for this species were found to be negative, highlighting the need for continuous monitoring.
There is now an urgent need to propose protection status for this endemic species to preserve its preferential habitats, as these are being increasingly threatened by human activities that are leading to habitat loss and fragmentation.