bluuebunny/crossref_metadata_2025_split huggingface dataset:
Nickel Sulfide/Hierarchical Porous Carbon from Spent Residue Hydrocracking Catalyst as Electrocatalyst for the Oxygen Evolution Reaction
Authors: Wang Xinhao , Hou Yunhui , Ge Shaohui , Hou Yuandong , Wu Zhijie , Chen Zhaojun , Gao Ruitong , Du Hui 
Published: September 2023

AbstractSpent residue slurry‐phase hydrocracking catalyst coated with coke have been classified as hazardous solid waste, presenting serious economic and environmental issues to refiners. Herein, the spent catalysts with a nickel sulfide nanoparticle/coke hierarchical structure (NiSX/C) from our previous work were used to prepare nickel sulfide/hierarchical porous carbon (NiSX/HPC) for the oxygen evolution reaction (OER) through the method of carbonization, activation, and sulfurization. The results indicate that the NiSX/C converts into Ni/HPC after carbonization and activation, and then transform into NiSX/HPC by sulfurization. The optimized NiSX/HPC‐8 possesses the crystal phase of NiS2, and the high specific surface area of 1134.9 m2 g−1 with the hierarchical micro‐mesoporous structure. Besides, NiSX/HPC‐8 achieves a low overpotential of 236 mV at 10 mA cm−2, a low Tafel slope of 64.1 mV dec−1, and excellent stability. This work provides a viable method for upcycling spent catalysts to re‐constructed OER catalysts with high catalytic performance and durability.
The intersocietal IWGDF, ESVS, SVS guidelines on peripheral artery disease in people with diabetes and a foot ulcer
Authors: Fitridge Robert , Chuter Vivienne , Mills Joseph , Hinchliffe Robert , Azuma Nobuyoshi , Behrendt Christian‐Alexander , Boyko Edward J. , Conte Michael S. , Humphries Misty , Kirksey Lee , McGinigle Katharine C. , Nikol Sigrid , Nordanstig Joakim , Rowe Vincent , Russell David , van den Berg Jos C. , Venermo Maarit , Schaper Nicolaas 
Published: September 2023

AbstractDiabetes related foot complications have become a major cause of morbidity and are implicated in most major and minor amputations globally. Approximately 50% of people with diabetes and a foot ulcer have peripheral artery disease (PAD) and the presence of PAD significantly increases the risk of adverse limb and cardiovascular events. The International Working Group on the Diabetic Foot (IWGDF) has published evidence based guidelines on the management and prevention of diabetes related foot complications since 1999. This guideline is an update of the 2019 IWGDF guideline on the diagnosis, prognosis and management of peripheral artery disease in people with diabetes mellitus and a foot ulcer. For this guideline the IWGDF, the European Society for Vascular Surgery and the Society for Vascular Surgery decided to collaborate to develop a consistent suite of recommendations relevant to clinicians in all countries. This guideline is based on three new systematic reviews. Using the Grading of Recommendations, Assessment, Development, and Evaluation framework clinically relevant questions were formulated, and the literature was systematically reviewed. After assessing the certainty of the evidence, recommendations were formulated which were weighed against the balance of benefits and harms, patient values, feasibility, acceptability, equity, resources required, and when available, costs. Through this process five recommendations were developed for diagnosing PAD in a person with diabetes, with and without a foot ulcer or gangrene. Five recommendations were developed for prognosis relating to estimating likelihood of healing and amputation outcomes in a person with diabetes and a foot ulcer or gangrene. Fifteen recommendations were developed related to PAD treatment encompassing prioritisation of people for revascularisation, the choice of a procedure and post‐surgical care. In addition, the Writing Committee has highlighted key research questions where current evidence is lacking. The Writing Committee believes that following these recommendations will help healthcare professionals to provide better care and will reduce the burden of diabetes related foot complications.
New extralimital breeding records of saltmarsh sparrows (Ammospiza caudacuta) and Nelson's sparrows (Ammospiza nelsoni) and their implications
Authors: Ruskin Katharine J. , Clark Jonathan D. , Hotopp Alice , Kovach Adrienne I. , Guido Nicole A. , Hernandez Dean L. , Peña Colin , Webb Samantha N. , Shriver W. Gregory 
Published: September 2023

AbstractSaltmarsh (Ammospiza caudacuta) and Nelson's (A. nelsoni) sparrows are sister taxa that breed in tidal marshes along the coast of the Northeastern United States and Canada. The Saltmarsh Sparrow breeds from mid‐coast Maine south to Virginia, while the Acadian Nelson's Sparrow breeds from the Canadian maritime provinces south to northern Massachusetts. Here, we present three extralimital observations of breeding Saltmarsh (n = 2) and Nelson's (n = 1) sparrows. In 2021 and 2022, we observed Saltmarsh Sparrow females attending nests at Mendall Marsh, ME, and Milbridge, ME, respectively, approximately 60 and 110 km beyond the documented northern extent of the Saltmarsh Sparrow breeding range. In 2022, we observed a breeding‐condition male Nelson's sparrow singing in the upriver portion of a marsh on Cape Cod, Massachusetts, approximately 115 km beyond the previously documented southern extent of the Nelson's Sparrow breeding range. We confirmed morphological species identification using a panel of microsatellite DNA loci. Due to both the well‐documented population declines of these species in the region and the intensity of sampling effort undertaken in recent years, we suggest that these observations likely are not indicative of range expansion. However, they do indicate that these 2 taxa have the capacity to use and successfully reproduce in marshes well beyond their established breeding limits. Our findings provide novel insight into the potential for these taxa to occur and successfully breed outside their documented breeding ranges. Given increased interest in their conservation, these results support the idea that management actions aimed at creating or maintaining nesting habitat across both species ranges could benefit both taxa.
UVA‐Light‐Promoted Catalyst‐Free Photochemical Aerobic Oxidation of Boronic Acids
Authors: Gkizis Petros L. , Constantinou Constantinos T. , Kokotos Christoforos G. 
Published: September 2023

AbstractThe hydroxy group, and the phenol moiety in particular, is ubiquitous in several natural products, in organic synthesis and/or pharmaceutical industry. With the uprise of photoredox catalysis, many efforts worldwide focus on developing novel and sustainable protocols, providing an easy access to hydroxy‐containing molecules. Boronic acids and boronic ester derivatives are considered valuable precursors for the synthesis of hydroxy group derivatives. Herein, we report a novel, sustainable, light‐driven protocol, where the impact of wavelength irradiation on boronic acid aerobic photooxidation was examined. In this work, UVA‐light (370 nm) irradiation was found to promote the photocatalyst‐free aerobic oxidation of boronic acids and boronic acid derivatives. Furthermore, a broad scope of substrates was tested, and extensive mechanistic studies were performed in order to probe the reaction mechanism.
Long‐term performance of single‐lap joints: Review, challenges and prospects in civil engineering
Authors: Shu Yue , Qiang Xuhong , Jiang Xu , Xiao Yi , Dong Hao 
Published: September 2023

AbstractCompared with traditional technology, bonding technology is more suitable for civil structure reinforcement because of its cost‐efficiency and superior mechanical properties. However, research on the long‐term performance of single‐lap joints (SLJs) requires better organization and comprehension. This article aims to investigate the long‐term performance and optimization design of SLJs. The main factors influencing the long‐term performance of SLJs from both material and component levels are discussed. The moisture diffusion mechanisms of bulk adhesives and the degradation mechanisms of SLJs are explored. Moreover, the optimization design of SLJs focuses on evaluating the overlap length, adhesive layer thicknesses, and changes in adhesives along the overlap length based on available literature. It is found that the applicability of diffusion models should be validated, and the selection of the models should consider working environments and types of adhesives. Exploring failure mechanisms and design criteria for the mixed SLJs in hygrothermal environments with/without sustained or alternating load is significant for the optimization design. This article indicates the limitations on the shear strength and long‐term performance of SLJs in available studies and provides insights into the challenges and prospects of their optimization design.
Seismic fragility analysis of coupled building‐slope systems
Authors: Raj Dhiraj , Singh Yogendra , Kaynia Amir M. 
Published: September 2023

AbstractBuildings located on hill slopes are subjected to additional effects under seismic action compared with those on flat ground. This article presents Incremental Dynamic Analyses of coupled building‐slope systems incorporating topographic amplification, nonlinear slope movement and irregular structural configuration of hill‐side buildings. Two different stable slopes, supporting single and multiple adjacent ductile moment resisting reinforced concrete frame buildings with step‐back configuration, prevalent in Indian and Chinese hilly regions, are modelled and analyzed using the finite element software ABAQUS. A suite of 21 ground motions is incrementally scaled and used to compute the seismic response of the coupled system. Fragility curves for different damage states, derived as lognormal probability distributions in terms of three different Intensity Measures (IMs) and damage probabilities of the considered buildings, are derived and compared. The spectrum‐based IMs (e.g., spectral acceleration at fundamental period, and average of the spectral acceleration over a period range) result in lower record‐to‐record variability, compared with the peak ground acceleration as the IM. The results reveal that ignoring the effect of slope significantly underestimates the fragility for all the damage states.
Development and Validation of Multiple Linear Regression Models for Predicting Chronic Zinc Toxicity to Freshwater Microalgae
Authors: Price Gwilym A. V. , Stauber Jenny L. , Jolley Dianne F. , Koppel Darren J. , Van Genderen Eric J. , Ryan Adam C. , Holland Aleicia 
Published: September 2023

Abstract
Multiple linear regression (MLR) models were developed for predicting chronic zinc toxicity to a freshwater microalga, Chlorella sp., using three toxicity-modifying factors (TMFs): pH, hardness, and dissolved organic carbon (DOC). The interactive effects between pH and hardness and between pH and DOC were also included. Models were developed at three different effect concentration (EC) levels: EC10, EC20, and EC50. Models were independently validated using six different zinc-spiked Australian natural waters with a range of water chemistries. Stepwise regression found hardness to be an influential TMF in model scenarios and was retained in all final models, while pH, DOC, and interactive terms had variable influence and were only retained in some models. Autovalidation and residual analysis of all models indicated that models generally predicted toxicity and that there was little bias based on individual TMFs. The MLR models, at all effect levels, performed poorly when predicting toxicity in the zinc-spiked natural waters during independent validation, with models consistently overpredicting toxicity. This overprediction may be from another unaccounted for TMF that may be present across all natural waters. Alternatively, this consistent overprediction questions the underlying assumption that models developed from synthetic laboratory test waters can be directly applied to natural water samples. Further research into the suitability of applying synthetic laboratory water–based models to a greater range of natural waters is needed. Environ Toxicol Chem 2023;42:2630–2641. © 2023 The Authors. Environmental Toxicology and Chemistry published by Wiley Periodicals LLC on behalf of SETAC.
Petrogenesis of the Zijinshan alkaline complex in Shanxi Province, western North China Craton: Mixing of melts from multiple sources
Authors: Wang Zhen‐Yu , Fan Hong‐Rui , Liu Shuang‐Liang , Li Xiao‐Chun 
Published: September 2023

The destruction of the North China Craton (NCC) is a well‐known dynamic event in the Mesozoic, but the western NCC, with only few magmatic activities, has lacked studies so far. The Zijinshan alkaline complex, tectonically located at the western part of the NCC and the eastern edge of Ordos Block/Basin, is one of the most typical alkaline intrusions during the NCC destruction, and consists of monzonite, aegirine–augite syenite, nepheline syenite, pseudoleucite phonolite and trachyte porphyry. Geochronological, geochemical and in situ Sr–Nd–Hf isotopic analyses were performed on the various lithologies, in order to reveal the magma sources, petrogenesis and possible geodynamic processes. Zircon and titanite U–Pb dating shows that the Zijinshan complex was emplaced at ~130 Ma. The main rocks are enriched in light rare earth elements (LREEs) and large‐ion lithophile elements (LILEs; such as Rb, Ba, K, Sr), and depleted in heavy rare earth elements (HREEs) and high‐field‐strength elements (HFSEs; such as Th, U, Nb, Ta, Ti), without negative Eu anomaly. In addition, the obviously enriched and inhomogeneous Sr–Nd isotopic components occurred among the various lithologies, implying the primary magma of Zijinshan complex may originate from a deep mixed source. Specifically, the monzonites of Zijinshan complex come from the partial melting of the enriched lithospheric mantle with participation of crustal materials. Meanwhile, the nepheline syenites and alkaline volcanics originated from the enriched lithospheric mantle mixing with the depleted asthenosphere‐derived compositions. During the NCC destruction, continuous asthenospheric upwelling resulted in several times of mixing of melts from asthenospheric mantle, lithospheric mantle and lower crust in different proportions, and then the mixed magma of each episode migrated upward to the shallow part to form the Zijinshan pluton.
Delayed skin grafting protocol following Integra™ application for non‐radiated scalp reconstruction for decreased wound depth and improved contour
Authors: Reece Mac Kenzie , Walker Hannah , Benintendi Isabella , Ward Stacey , Thatcher Ashley , Johnson R. Michael , Kadakia Sameep P. 
Published: September 2023

AbstractThe clinical use of Integra™ has expanded to include scalp reconstruction since its FDA approval in 1996. Integra™, or dermal regeneration template, can be utilized in patients who are elderly with multiple medical comorbidities. Well‐established Integra™ techniques utilize skin grafting 1–2 weeks following evidence of template vascularity. Most studies show the time to graft placement as <30 days, with almost all <52 days. No single article proposes a time frame for applying STSG after neodermis regeneration. Therefore, we aimed to describe our protocol to define a time frame for delaying scalp reconstruction with STSG following dermal regeneration. Over the last several years, the senior author has utilized a delayed reconstruction with skin grafting method where‐in Integra™ is applied to either debrided bone or exposed pericranium in selected patients, and allowed to mature for ~6 weeks before performing skin grafting. The results have been predictable, reproducible, and have yielded high levels of patient and provider satisfaction due to the improved contour cosmesis. In this pictorial essay, the authors' novel protocol is detailed.
Bibliometric analysis of publication trends and topics of influenza‐related encephalopathy from 2000 to 2022
Authors: Zhang Zhengyu , Tan Juntao , Li Ying , Zhou Xiumei , Niu Jianhua , Chen Jun , Sheng Hongfeng , Wu Xiaoxin , Yuan Yuan 
Published: September 2023

AbstractBackgroundInfluenza‐related encephalopathy is a rapidly progressive encephalopathy that usually presents during the early phase of influenza infection and primarily manifests as central nervous system dysfunction. This study aimed to analyze the current research status and hotspots of influenza‐related encephalopathy since 2000 through bibliometrics analysis.MethodsThe Web of Science Core Collection (WOSCC) was used to extract global papers on influenza‐related encephalopathy from 2000 to 2022. Meanwhile, the VOSviewer and CiteSpace software were used for data processing and result visualization.ResultsA total of 561 published articles were included in the study. Japan was the country that published the most articles, with 205 articles, followed by the United States and China. Okayama University and Tokyo Medical University published the most articles, followed by Nagoya University, Tokyo University, and Juntendo University. Based on the analysis of keywords, four clusters with different research directions were identified: “Prevalence of H1N1 virus and the occurrence of neurological complications in different age groups,” “mechanism of brain and central nervous system response after influenza virus infection,” “various acute encephalopathy” and “diagnostic indicators of influenza‐related encephalopathy.”ConclusionsThe research progress, hotspots, and frontiers on influenza‐related encephalopathy after 2000 were described through the visualization of bibliometrics. The findings will lay the groundwork for future studies and provide a reference for influenza‐related encephalopathy. Research on influenza‐related encephalopathy is basically at a stable stage, and the number of research results is related to outbreaks of the influenza virus.
A study on the level of NLRP3 inflammasome in patients with premature rupture of membranes
Authors: Xue Fen , Wang Yan , Tao Xue‐Qiang , Su Wei 
Published: September 2023

AbstractObjectiveIn this study, we investigated the levels of interleukin‐1β (IL‐1β), IL‐18, and the NOD‐like receptor pyrin domain‐containing 3 (NLRP3) inflammasome in patients with premature rupture of membranes (PROMs).MethodsWe selected 60 pregnant women at the Fourth Hospital of Baotou between January 2019 and July 2021. These women were divided into three distinct groups: the preterm PROM group with 20 cases, term PROM (TPROM) group with 20 cases, and a control group with 20 cases consisting of normal full‐term pregnancies without PROM. Peripheral blood was collected from all participants. Using enzyme‐linked immunosorbent assay, the levels of IL‐1 and IL‐18 in the plasma were assessed. Additionally, the proportions of NLRP3, apoptosis‐associated speck‐like protein (ASC), and caspase‐1‐positive macrophages were also evaluated.ResultsThe ratios of NLRP3, ASC, IL‐1β, and IL‐18 concentrations, along with the presence of caspase‐1‐positive macrophages, were notably greater in the PROM groups in comparison with the control group (p < .05). In the TPROM group and control group, the proportions of IL‐1β and IL‐18 levels were found to be lower than NLRP3, ASC, and caspase‐1‐positive macrophages levels (p < .05).ConclusionThe concentrations of IL‐1β and IL‐18, as well as the ratios of NLRP3, ASC, and caspase‐1‐positive macrophages, were elevated in patients with PROM compared to the control group. This suggests a potential correlation between the excessive activation of NLRP3 and the development of PROM.
Diagnostic values of serum BNP, PTX3, and VEGF in acute pulmonary embolism complicated by pulmonary artery hypertension and their correlations with severity of pulmonary artery hypertension
Authors: Zheng Qinghou , Zhang Bin , Lu Na , Li Xinyi , Jin Beibei , Jin Pingkui 
Published: September 2023

AbstractObjectiveThis paper aimed to unveil the diagnostic values of serum brain natriuretic peptide (BNP), pentraxin 3 (PTX3), and vascular endothelial growth factor (VEGF) in acute pulmonary embolism complicated by pulmonary artery hypertension (APE‐PAH) and their correlations with severity of PAH.MethodsA total of 153 patients with APE were selected for our study and divided into the PAH and Non‐PAH groups according to the measurement of pulmonary artery pressure by echocardiography. Serum BNP levels were measured by chemiluminescence immunoassay, and serum PTX3 and VEGF levels were appraised by ELISA. The predictive values of BNP, PTX3, and VEGF for APE‐PAH were evaluated by applying the receiver operating characteristic (ROC) curve. Spearman test was implemented to correlate BNP, PTX3, and VEGF with the severity of PAH.ResultsHigher serum levels of BNP, PTX3, and VEGF were observed in the PAH group versus the Non‐PAH group (p < .05). ROC curve analysis indicated that BNP, PTX3, and VEGF had acceptable diagnostic value for predicting APE‐PAH. Higher serum levels of BNP, PTX3, and VEGF were witnessed in the moderate and severe PAH groups in contrast to the mild PAH group (p < .05), and the levels of these parameters were elevated in the severe PAH group versus the moderate PAH group (p < .05). Spearman correlation analysis signified that serum BNP (r = 0.377), PTX3 (r = 0.488), and VEGF (r = 0.575) levels were positively correlated with the severity of PAH in APE‐PAH patients.ConclusionSerum BNP, PTX3, and VEGF levels are significantly elevated in APE‐PAH patients. Serum BNP, PTX3, and VEGF levels are of clinical value in the diagnosis of APE‐PAH patients, and serum BNP, PTX3, and VEGF levels are positively correlated with the severity of PAH and can be used as predictors of the severity of PAH.
Tumor cell‐expressed lipolysis‐stimulated lipoprotein receptor negatively regulates T‐cell function
Authors: Funauchi Masashi , Serada Satoshi , Hiramatsu Kosuke , Funajima Eiji , Kanda Mizuki , Nagase Yoshikazu , Nakagawa Satoshi , Ohkawara Tomoharu , Fujimoto Minoru , Suzuki Yuji , Ueda Yutaka , Kimura Tadashi , Naka Tetsuji 
Published: September 2023

AbstractLipolysis‐stimulated lipoprotein receptor (LSR) is known as a lipoprotein receptor. LSR is expressed in various solid tumors, including epithelial ovarian, gastric, and colon cancers. High LSR expression is significantly associated with poor prognosis, but its role in cancer has not been fully elucidated. LSR belongs to the Ig protein superfamily, which is conserved in B7 family. Here, we assessed LSR as a novel immune checkpoint molecule. We developed a novel anti‐LSR antibody (#27‐6 mF‐18) that defects antibody‐dependent cellular cytotoxicity and complement‐dependent cytotoxicity activity. The #27‐6 mF‐18 cross‐reacts with both human and mouse LSR. We found that LSR was expressed on 4T1 murine breast cancer cell line. The #27‐6 mF‐18 exhibited antitumor effects against the 4T1 syngeneic tumor model, a poor immunogenic model refractory to treatment with anti‐PD‐1 or anti‐CTLA‐4 antibodies. Compared with control antibody‐treated mice, mice treated with #27‐6 mF‐18 showed significantly increased numbers of CD8+ T cells and a ratio of activated CD8+ T cells infiltrated in the tumor tissue. This antitumor effect was abrogated by CD8+ T‐cell depletion through anti‐CD8 antibody treatment, indicating that LSR negatively regulates tumor immunity by repressing CD8+ T cells. These findings show that LSR negatively regulates T‐cell immune activity. LSR targeting could provide immune checkpoint inhibitors for cancer immunotherapy.