bluuebunny/crossref_metadata_2025_split huggingface dataset:
REGIOSELECTIVITY OF THE TELLURIUM-INDUCED CYCLISATION OF TERMINALLY SUBSTITUTED ALLYL, BUTENYL AND PROPARGYL THIOETHERS OF THIENOPYRIMIDINE
Authors: Kut M. , Kut D. , Onysko M. 
Published: May 2023

The method of electrophilic intramolecular cyclization is widely used for the synthesis of condensed thienopyrimidine derivatives. In this work, the regioselectivity of the process of electrophilic intramolecular cyclization of terminally substituted allylic derivatives, but-1-enyl and propargyl thioethers of thienopyrimidine with p-methoxyphenyltellurttrichloride was investigated.
It was established that as a result of the tellurium-induced cyclization of butenyl thioethers of 5,6-dimethyl-3-phenylthieno[2,3-d]pyrimidin-4(3H)-one with p-methoxyphenyltellurium trichloride, angular tricyclic chlorides ― 8-(dichloro(4-methoxyphenyl)-tellanyl)-2,3,9-trimethyl-4-oxo-5-phenyl-5,7,8,9-tetrahydro-4H-thieno[3',2':5,6]pyrimido[2,1-b][1,3]thiazine-10-ium and 9-((dichloro(4-methoxyphenyl)-tellanyl)methyl)-2,3-dimethyl-4-oxo-5-phenyl-5,7,8,9-tetrahydro-4H-thieno­[3',2':5,6]pyrimido[2,1-b][1,3]thiazine-10-ium with an annealed six-membered ring in the form of complexes with p-methoxyphenyltellurium trichloride. It was proved that the electrophilic intramolecular cyclization of 5,6-dimethyl-2-(prop-2-yn-1-ylthio)-3-phenylthieno[2,3-d]pyrimidin-4(3H)-one with aryltellurium trichloride occurs with the formation of an aryltellurium trichloride complex with angular chloride 8-((dichloro(4-methoxyphenyl)-tallanyl)methylidene)-2,3-dimethyl-4-oxo-5-phenyl-4,5,7,8-tetrahydrothiazolo[3,2-a]thieno [3,2-e]pyrimidin-9-ium in the form of one geometric isomer.
Keywords: electrophilic heterocyclization; p-methoxyphenyltellurium trichloride; organotellurium compounds; chloride 4H-thieno[3',2':5,6]pyrimido[2,1-b][1,3]thiazine-10-ium; chloride 4H-thieno[3',2':5,6]pyrimido[2,1-b][1,3]thiazine-10-ium; chloride thiazolo[3,2-a]thieno[3,2-e]pyrimidin-9-ium.
Simulator for personnel of Yumaguzinskaya HPP
Authors: Arkhipova Ye. N. , Arkhipova T. N. , Malikov S. I. , Komlev A. A. 
Published: May 2023

During the operation of hydroelectric power plants, issues arise of improving the skills of hydroelectric power plant personnel, which can be ensured by the introduction of simulators for targeted training of personnel to work both in normal operating conditions and in pre-emergency and emergency situations as close as possible to real ones. It should be noted that the developers of simulators in the Russian energy sector peviously focused on the creation of simulators for thermal power plants, leaving hydroelectric power plants overshadowed. To date, TEST JSC has developed and implemented simulators for Irkutskaya, Bratskaya, Ust-Ilimskaya, Krasnoyarskaya, Ondskaya, Pavlovskaya and Yumaguzinskaya HPPs. This paper discusses the development for the Yumaguzinskaya HPP: a simulator with dynamic computer-aided mnemonic circuits of hydraulic units and electrical circuits of one of the Russian hydroelectric power plants, which will arouse interest among readers of the journal and potential customers. The article describes the prototype facility, the composition of the simulator, which includes a model of the facility and operating modes, a model of the control system, a model of the protection system, a model of locks, a model of emergency and warning alarms, describes in detail the educational and methodological support of the simulator complex, including models of training scenarios, an introductory model, a monitoring program, protocols and instructions. The organization of effective simulator training of operational and maintenance personnel on the simulator for operational switching of the Yumaguzinskaya HPP is achieved through the implementation in the simulator of the following main simulated subsystems: trainee's workplace model, instructor's workplace model, control object model, control system model, training system model. The hydroelectric power plant simulator presented in the paper is versatile and can find practical application both as a tool for training and examination of knowledge of operational personnel, and as a means for conducting occupational skills contests.
Narasi Term Zholim Dalam Tafsir al-Wasith Karya Wahbah al-Zuhaili
Authors: Enghariano Desri Ari 
Published: May 2023

Islam is a mercy for the universe. But in reality, many people don’t want to make Islam the compas of life. This makes them be oppressor. The scholars, especially Wahbah al-Zuhaili have warned in one of his book, namely Tafsir al-Wasith not do oppression. Therefore, this research aims to describe the narration of the term oppression in Tafsir al-Wasith; in the form of the definition of oppression, the history of oppression, various kinds of oppression, triggering factor for doing of oppression, and punishment for oppressor. The method used in this research is thematic method. The results of this research is to explain that the meaning of oppression is attitudes and actions that goes beyond the corridor. Oppression acts in history began with the prophet Adam. There are three kinds of oppression; namaely oppression to Allah, oppression to one’s own person, and oppression to other people. There are three triggering factors for doing oppression; namely fear of the creatures more than fear of the Creator, weak faith in the Day of Judgment, and raises doubt about the justice of Allah. Oppressor will be punished for his oppression; both the punishment of this world and the punishment of the hereafter.
Analysis of the Meaning of the Word Sayyid In the Qur'an and al-Hadis
Authors: Siregar Dame , Pahutar Agus Anwar 
Published: May 2023

There should be a valid argument for worship before it can be practiced. If it is not obligatory to leave it, it is enough and complete the Qur'an and hadith, why are you still looking for a rational argument that contradicts the naql argument. There are 3 meanings of sayyid in the Qur'an, namely follower, husband and leader. Sayyid ah is termed in Indonesia as (siti) is the wife, there is a queen in heaven, if a man is called the king (the term local adat title, meaning it is permissible to call kiyai, Buyya, ustad, Baleo and others, it means that academic degrees such as Dr, Ph.D, may hold positions such as president, may title abri such as generals. The meaning of sayid is lower than the name given by Allah, namely Muhammad, Ahmad, 'Abdun Rosul Nabi and ummi. The use of the word sayyid or sayyid ah in worship has not found the evidence. If it is better, add the word Of course the monotheism sentence becomes: لااله الا الله سيدنا محمد رسول الله, it is also possible to pronounce the shahada to Muhammad as: وأشهد أن سيدنا محمدا عبده ورسوله, and the reading in the adhan iqamah and others, may also be the name of the surah سيدنا محمد and every word added with the word Muhammad سيدنا
Electronic Public Summon In Civil Procedure; In Effort To Quit The Colonial Heritage
Authors: Sujatmiko Bagus 
Published: May 2023

The court summon is the first spearhead of the entire trial process, especially for the civil cases. Court summon has an essential role, even the summon process may decide the legitimation of a trial that conducted by the judge. The court summon is conducted in order to inform the parties when they should appear before the judge. It becomes important due to its impact to the parties’ life fate, either its right over goods or its legal status on a family. Therefore, the laws shall ensure that every person shall know whenever their rights being challenged before the court. In civil cases the court summon is regulated under Article 390 HIR (718 RBg), which is one of its kind is known as public summon. The legal basis to conduct the public summon in last 170 years has not been changed, only public summon in certain case that amended, such as in divorce case. Even then, the change does not really change the summoning process, the summoning still conducted by using a announcing paper that put in the government building and announcing through conventional media mass such as newspaper, radio or television. However nowadays, this kind of media has been left by the people, their popularity has been stolen by the internet like youtube, facebook, Instagram and etc. The Supreme Court (Mahkamah Agung, hereafter as “MA”) shall adapt to this era, MA shall re-innovate the way public summon conducted in last 170 years, by using the innovation of the 21th century which is the “internet”, by using the “Electronic Public Summon”
PARADIGMA FIKIH PRIORITAS DALAM FATWA EKONOMI SYARIAH DI INDONESIA
Authors: Dedi Dedi , Islamy Athoillah , Harahap Abdul Aziz 
Published: May 2023

Upaya membumikan sistem ekonomi syariah di Indonesia tidak selamanya mendapat respons positif, melainkan seringkali menuai pandangan negatif dari masyarakat. Fenomena demikian di antaranya dipicu oleh paradigma yang keliru dalam merespons pelbgai fatwa ekonomi syariah yang ada. Penelitian normatif-filosofis ini bermaksud untuk mengidentifikasi paradigma fikih dalam landasan perumusan fatwa ekonomi syariah oleh Dewan Syariah Nasional (DSN)-Majelis Ulama Indonesia (MUI). Teori analisis dalam penelitian ini, yakni paradigma fikih prioritas (fiqh al-awlawiyat) yang dicetuskan oleh Yusuf al-Qaradawi. Hasil penelitian menunjukan terdapat corak paradigma fikih prioritas dalam landasan perumusan fatwa ekonomi syariah oleh DSN-MUI. Pertama, paradigma fiqh al-muwazanat (fikih keseimbangan) dan fiqh al-wâqi‘ (fiqh realitas) dalam landasan al-Taysîr al-Manhaji dan al-Tafriq baina al-Halal wal Haram. Kecenderungan paradigma fiqh al-muwazanat dan fiqh al-waqi’ terlihat pada penekanan landasan al-Taysîr al-Manhaji yang membandingkan mempertimbangkan kadar kemaslahatan terbaik dan adaptable dengan kondisi empiris ekonomi yang ada. Begitu juga dapat dilihat dalam penekanan landasan at-Tafriq baina al-Halal wal Haram yang memisahkan (harta yang halal dan yang haram, karena relaitas praktik sistem ekonomi syariah di Indonesia masih belum lepas secara totalitas dari sistem ekonomi konvensional. Kedua, paradigma fiqh al-maqasid (fikih tujuan) dalam landasan I‘adah al-Nazhar dan Tahqiq al-Manath. Hal tersebut dapat dilihat dari penekakanan kedua landasan tersebut yang menekankan peninjauan ulang terhadap implikasi fatwa maupun dasar penetapan fatwa untuk mengetahui sejauh mana implikasi maupun dasar penetapan sebuah hukum paralel atau justru berlawanan dengan wujud kemaslahatan yang menjadi tujuan inti dari perumusan fatwa. Implikasi teoritik penelitian ini menunjukan bahwa keberadaaan dimensi corak paradigma fikih prioritas dalam landasan perumusan fatwa ekonomi syariah oleh DSN-MUI dapat senantiasa adaptif dan kontekstual terhadap perkembangan sistem ekonomi modern. Keterbatasan penelitian ini, yakni belum membahas tentang bagaimana bentuk intervensi politik (pemerintah) dalam strategi perumusan pelbagai fatwa DSN-MUI terkait ekonomi syariah.
MEMBANGUN PEMILU YANG DEMOKRATIS MELALUI OPTIMALISASI PARTAI POLITIK
Authors: Damanik Agustina 
Published: May 2023

Partai politik sangat berkaitan dengan pemilihan umum. Dukungan dari partai politik sangat penting dalam sebuah pemilihan umum karena dapat mempengaruhi hasil dari pemilihan umum. Baik hasil sebelum pemilu dan hasil setelah pemilu dilaksanakan partai politik sangat memiliki peran yang culup penting. Keoptimalan partai politik untuk memberikan pendidikan politik bagi masyarakat dapat menurunkan tingkat golput dikalangan masyarakat dan meningkatkan partisipasi pemilih ketika pemilihan umum berlangsung. Ada beberapa faktor yang mempengaruhi pemilu tahun 2019 diantaranya adalah kinerja dari partai politik dalam menjalankan fungsinya secara optimal dan teratur. hal itu dapat meningkatkan atau menurunkan partisispasi dari masyarakat, tergantung bagaimana peran dari partai politik dalam mengoptimalkan perannya.
Legal Formal Cadar Sebagai Ide
Authors: Siregar Khoiruddin Manahan 
Published: May 2023

This study discusses the political participation of veiled students of the Padangsidimpuan State Islamic Institute in the 2019 Presidential Election in Padangsidimpuan City. This research is motivated by the fact that many female students at the Padangsidimpuan State Islamic Institute who wear the veil did not participate in the main election in the presidential election in 2019. The formulation of the problem in this study is how the political participation of students at the Islamic State Institute of Religion who are veiled women in the presidential election in 2019 in Padangsidimpuan City, how are the perceptions and what are the consequences of the perceptions of Padangsidimpuan State Islamic Institute students who are veiled in the presidential election for the state in Padangsidimpuan City, and how the rights of a Muslim woman in exercising their political rights are reviewed from the fiqh siyasah. The type of research is field research (field research), namely research conducted in the field aimed at obtaining information and describing events, events that have occurred in the field in accordance with the facts found. Data sources consist of primary and secondary, namely primary data is data obtained by researchers directly from the first hand by means of interviews and direct observations in the field. This secondary data consists of literature which is reading material, the work of experts from their respective fields which serves to explain primary legal materials. The results of the study stated that the veiled political participation of Padangsidimpuan State Islamic Institute students in the 2019 Presidential Election in Padangsidimpuan City was still very minimal, it could be seen from the level of participation of Padangsidimpuan Islamic Institute students who were veiled in the presidential election in Padangsidimpuan city which had an impact on the level of democracy that was high. exist in this country.Key word: Partisipation, Cadar, presidential election
Maqashid Ash-Sharia Principles In Child Protection
Authors: Harahap Riska Harnysah , Harahap Risalan Basri 
Published: May 2023

Maqashid Asy- Sharia aims to realize the benefit of man in the world and the hereafter. The principle of Maqashid Asy- Sharia consists of maintaining religion (hifzh al-din), nurturing the soul (hifzh al- nafs), Protection of reason (hifzh al-aql), nurturing offspring (Hifzh al-nasl) and maintaining property (hifz al-mal). The formulation of the problem from this study is how the concept of child protection in Law No. 35 of 2014 concerning Child Protection and How the principle of Maqashid Asy-Sharia in Law No. 35 of 2014 concerning Child Protection. The purpose of this study is to find out how the concept of protection of children in Law No. 35 of 2014 concerning Child Protection andTo find out how the principle of Maqashid Asy-Sharia in Law No. 35 of 2014 concerning Child Protection. The theory used in this study is a theory related to the principle of Maqashid Asy- Sharia in law no. 35 of 2014 concerning. Furthermore, the type of research used is library research, using a normative juridical approach. The results of the research obtained, namely, freedom to practice religion, are contained in article 6 of Law No. 35 of 2014, namely that every child has the right to worship according to their religion, thinking, and expression in accordance with their level of intelligence and age under the guidance of parents or guardians.It is found in (hifzh al-din maintains Religion. Children are a generation that needs to be given religious education so that they have a basic foundation in everyday life. Childcare is contained in article 7 of Law No. 35 of 2014, namely parents and families are responsible for nurturing, maintaining, educating, and protecting children. It is called (hifzh al- nafs). The protection of education is contained in article 9 of Law No. 35 of 2014 concerning child protection, namely that every child has the right to obtain education and teaching in order to develop his personality and his level of intelligence with his interests and talents is hifzh al -aql.
Edukasi Pembuatan Pestisida Nabati dari Kulit Bawang Merah di Desa Bagorejo Kabupaten Banyuwangi
Authors: Sekaringgalih Ratri , Rachmah Alif Nur Laili , Susanti Yuni , A’yun Ayu Qurota , Ansori Ansori 
Published: May 2023

Pengabdian masyarakat di Desa Bagorejo bertujuan untuk mengoptimalkan potensi kulit bawang merah sebagai bahan baku pestisida nabati. Hal ini berkaitan dengan masyarakat Bagorejo yang mata pencaharian utamanya adalah petani. Namun, petani cenderung masih menggunakan pestisida kimia untuk membasmi hama. Sehingga pembuatan pestisida nabati merupakan jawaban untuk meminimalisir penggunaan pestisida kimia mengingat dampak penggunaan pestisida kimia yang cukup berbahaya bagi kesehatan manusia dan lingkungan. Harga pestisida kimia yang meningkat setiap tahunnya juga menjadi alasan untuk mendukung penggunaan pestisida nabati. Perkembangan pemanfaatan kulit bawang merah masih sangat minim, hal ini terjadi karena kurangnya kesadaran dan pengetahuan masyarakat akan potensinya. Berdasarkan permasalahan tersebut, kami berinisiatif untuk memberikan solusi melalui sosialisasi dan praktek. Kegiatan diawali dengan sosialisasi potensi kulit bawang merah, pelatihan pembuatan pestisida nabati dari kulit bawang merah, serta evaluasi kegiatan. Hasil dari pengabdian ini yaitu masyarakat dapat memperoleh pengetahuan tambahan tentang potensi kulit bawang merah, dan manfaatnya selain sebagai limbah serta dapat mengolah kulit bawang merah sebagai pestisida nabati.

Community service in Bagorejo Village aims to optimize the potential of red onion skin as a raw material for botanical pesticides. It relates to the Bagorejo community, where the main livelihood is farmers. However, farmers tend to still use chemical pesticides to eradicate pests. So that the manufacture of botanical pesticides is the answer to minimize the use of chemical pesticides, considering the impact of the use of chemical pesticides which are quite dangerous for human health and the environment. The price of chemical pesticides which has increased every year is also a reason to support the use of botanical pesticides. The development of red onion skin utilization is still very minimal, it occurs due to a lack of public awareness and knowledge about its potential. Based on these problems, we took the initiative to provide a solution through outreach and practice. The activity began with socializing the potential of red onion skin, training on processing red onion skin into botanical pesticides and evaluating the activities. The result of this service is the community gained a significant increase in knowledge related the knowledge of the potential of red onion skin, and apart from being a waste, it can also process red onion skin as a botanical pesticide.
Peningkatan Keselamatan Kerja Melalui Pencegahan Penyakit Akibat Kerja Pada Perawat di Rumah Sakit
Authors: Rohmani Ngatoiatu , Nirmalasari Novita , Lestari Ratna 
Published: May 2023

Penyakit akibat kerja dapat terjadi pada pekerja, termasuk perawat. Perawat sering melaporkan berbagai keluhan seperti sakit kepala, nyeri pinggang, tertusuk jarum dan penularan penyakit akibat kerja. Oleh karena itu, perawat perlu meningkatkan kewaspadaan dalam menerapkan budaya keselamatan dan kesehatan kerja agar dapat memberikan asuhan keperawatan secara optimal. Identifikasi risiko bahaya dan pemeriksaan kesehatan juga perlu dilakukan untuk mencegah terjadinya kecelakaan kerja yang dapat menurunkan produktivitas kerja. Sosialisasi dan pemberian edukasi terkait praktik K3 kepada perawat merupakan salah satu upaya yang dapat dilakukan untuk mencegah angka kecelakaan kerja. Kegiatan pengabdian ini bertujuan untuk meningkatkan pengetahuan dan kepatuhan perawat dalam melaksanakan pencegahan penyakit akibat kerja dengan menerapkan protokol yang sesuai dan mengenalkan latihan peregangan di tempat kerja untuk mencegah cedera akibat kerja. Metode pelaksanaan pengabdian kepada masyarakat meliputi: pengkajian kesehatan dan bahaya, analisis masalah, dan implementasi program melalui sosialisasi dan pendidikan kesehatan. Hasil menunjukkan bahwa sebagian besar peserta telah menerapkan pengurangan risiko infeksi dengan mencuci tangan sebelum dan sesudah prosedur dengan teknik yang benar.

Occupational diseases may occur in workers, including nurses. Nurses often report various complaints such as headaches, low back pain, needle pricks and occupational disease transmission. Therefore, nurses need to increase vigilance in implementing a culture of occupational health and safety in order to provide nursing care optimally. Identification of hazard risks and health checks also need to be carried out to prevent work accidents that may reduce the work productivity. Socializing and providing education related to OSH practices to nurses is one of the efforts that can be pursued to prevent the number of work accidents. This service activity aims to increase the knowledge and compliance of nurses in implementing occupational disease prevention by implementing appropriate protocols and introducing stretching exercises in the workplace to prevent work-related injuries. The methods of conducting community service includes: health and hazard screening, problem analysis, and implementation of program through socialization and education. The results showed that majority of participants have implemented infection risk reduction by washing hands before and after the procedure with the correct technique
Pelatihan Penggunaan Dyscalculia Detection Card (DDC) untuk Deteksi Awal Diskalkulia pada Anak
Authors: Abidin Zainal , Sari Okta Pita Dian , Fuady Anies 
Published: May 2023

Tujuan pengabdian ini adalah untuk meningkatkan keterampilan mengajar para guru di SD Al Irsyad Al Islamiyyah, khususnya dalam mendiagnosa kesulitan belajar siswa dalam pembelajaran matematika. Metode pelaksanaan pelatihan ini terdiri dari tiga tahap yang diikuti oleh dua belas wali kelas dari kelas 1 sampai dengan kelas 6. Tahap pertama adalah pra kegiatan yang dilakukan melalui survei awal, sosialisasi kepada guru dan rapat koordinasi dengan tim pengabdi. Tahap kedua pelaksanaan kegiatan dengan penyampaian materi dan praktek menggunakan Dyscalculia Detection Card (DDC) dan penugasan. Ada enam edisi dengan lima seri pada setiap tes. Kegiatan diawali dengan pengisian angket pertama kepada guru terkait pengertian diskalkulia. Tahap ketiga adalah monitoring dan evaluasi dengan memberikan kuesioner dengan indikator yang sama, namun dengan pertanyaan yang berbeda. Melalui pelatihan ini, guru mendapatkan wawasan mengenai diskalkulia dan dapat mendeteksi gejala diskalkulia sedini mungkin. Persentase rata-rata peningkatan guru sebesar 28,75% dari skor rata-rata prapelatihan 44,58 menjadi 72,91. Selain itu, dengan adanya pelatihan ini guru secara langsung meningkatkan kompetensi pedagogiknya terutama dalam mendiagnosis siswa dengan diskalkulia secara mandiri.

The purpose of this dedication is to improve the teaching skills of teachers at SD Al Irsyad Al Islamiyyah, especially in diagnosing students' learning difficulties in learning mathematics. The implementation method for this training consisted of three stages followed by twelve homeroom teachers from grades 1 to grade 6. The first stage was pre-activity which was carried out through an initial survey, outreach to teachers and coordination meetings with the service team. The second stage is the implementation of activities by presenting material and practice using the Dyscalculia Detection Card (DDC) and assignments. There are six editions with five series on each test. The activity begins with filling out the first questionnaire to the teacher regarding understanding dyscalculia. The third stage is monitoring and evaluation by providing a questionnaire with the same indicators, but with different questions. Through this training, teachers gain insight into dyscalculia and can detect symptoms of dyscalculia as early as possible. The average percentage of teacher improvement is 28,75% from the average pre-training score of 44,58 to 72,91. In addition, with this training teachers directly improve their pedagogical competence, especially in diagnosing students with dyscalculia independently.