bluuebunny/crossref_metadata_2025_split huggingface dataset:
Predicting child aggression: The role of parent and child endorsement of reactive aggression across 13 cultural groups in 9 nations
Authors: Rothenberg William A. , Sorbring Emma , Lansford Jennifer E. , Peña Alampay Liane , Al‐Hassan Suha M. , Bacchini Dario , Bornstein Marc H. , Chang Lei , Deater‐Deckard Kirby , Giunta Laura Di , Dodge Kenneth A. , Gurdal Sevtap , Liu Qin , Long Qian , Oburu Paul , Pastorelli Concetta , Skinner Ann T. , Tapanya Sombat , Steinberg Laurence , Maria Uribe Tirado Liliana , Yotanyamaneewong Saengduean 
Published: December 2022

AbstractParent and child endorsement of reactive aggression both predict the emergence of child aggression, but they are rarely studied together and in longitudinal contexts. The present study does so by examining the unique predictive effects of parent and child endorsement of reactive aggression at age 8 on child aggression at age 9 in 1456 children from 13 cultural groups in 9 nations. Multiple group structural equation models explored whether age 8 child and parent endorsement of reactive aggression predicted subsequent age 9 child endorsement of reactive aggression and child aggression, after accounting for prior child aggression and parent education. Results revealed that greater parent endorsement of reactive aggression at age 8 predicted greater child endorsement of aggression at age 9, that greater parent endorsement of reactive aggression at age 8 uniquely predicted greater aggression at age 9 in girls, and that greater child endorsement of reactive aggression at age 8 uniquely predicted greater aggression at age 9 in boys. All three of these associations emerged across cultures. Implications of, and explanations for, study findings are discussed.
Thinking through situations: The mediating role of rumination in the relationship between need for cognition and aggression
Authors: Barlett Christopher P. 
Published: December 2022

AbstractNeed for cognition (NFC)—a stable personality trait associated with the enjoyment of thinking—has been shown to influence myriad social situations; however, no research has tested the direct and indirect effects of NFC on aggression. We predicted that NFC would negatively correlate with aggression, which would be mediated by rumination. Participants (N = 216 US adults) completed measures assessing NFC, aggression, and rumination. In line with our hypotheses, results showed that NFC was negatively correlated with aggression, and both anger rumination and more general rumination mediated this relationship. Future research and conclusions are discussed.
Quantifying intrafractional gastric motion using auto‐segmentation on MRI: Deformation and respiratory‐induced displacement compared
Authors: Driever Theo , Hulshof Maarten C.C.M. , Bel Arjan , Sonke Jan‐Jakob , van der Horst Astrid 
Published: December 2022

AbstractBackground and purposeFor accurate pre‐operative gastric radiotherapy, intrafractional changes must be taken into account. The aim of this study is to quantify local gastric deformations and compare these deformations with respiratory‐induced displacement.Materials and methodsCoronal 2D MRI scans (15–16 min; 120 repetitions of 25–27 interleaved slices) were obtained for 18 healthy volunteers. A deep‐learning network was used to auto‐segment the stomach. To separate out respiratory‐induced displacements, auto‐segmentations were rigidly shifted in superior‐inferior (SI) direction to align the centre of mass (CoM) within every slice. From these shifted auto‐segmentations, 3D iso‐probability surfaces (isosurfaces) were established: a reference surface for POcc = 0.50 and 50 other isosurfaces (from POcc = 0.01 to 0.99), with POcc indicating the probability of occupation by the stomach. For each point on the reference surface, distances to all isosurfaces were determined and a cumulative Gaussian was fitted to this probability‐distance dataset to obtain a standard deviation (SDdeform) expressing local deformation. For each volunteer, we determined median and 98th percentile of SDdeform over the reference surface and compared these with the respiratory‐induced displacement SDresp, that is, the SD of all CoM shifts (paired Wilcoxon signed‐rank, α = 0.05).ResultsLarger deformations were mostly seen in the antrum and pyloric region. Median SDdeform (range, 2.0–2.9 mm) was smaller than SDresp (2.7–8.8 mm) for each volunteer (p < 0.00001); 98th percentile of SDdeform (3.2–7.3 mm) did not significantly differ from SDresp (p = 0.13).ConclusionLocally, gastric deformations can be large. Overall, however, these deformations are limited compared to respiratory‐induced displacement. Therefore, unless respiratory motion is considerably reduced, the need to separately include these deformation uncertainties in the treatment margins may be limited.
Regulating Na‐ion Solvation in Quasi‐Solid Electrolyte to Stabilize Na Metal Anode
Authors: Zhou Xiaoyan , Li Zhuo , Li Wanming , Li Xiaogang , Fu Jialong , Wei Lu , Yang Hui , Guo Xin 
Published: December 2022

AbstractSodium metal batteries are promising for cost‐effective energy storage, however, the sluggish ion transport in electrolytes and detrimental sodium‐dendrite growth stall their practical applications. Herein, a cross‐linking quasi‐solid electrolyte with a high ionic conductivity of 1.4 mS cm−1 at 25 °C is developed by in‐situ polymerizing poly (ethylene glycol) diacrylate‐based monomer. Benefiting from the refined solvation structure of Na+ with a much lower desolvation barrier, random Na+ diffusion on the Na surface is restrained, so that the Na dendrite formation is suppressed. Consequently, symmetrical Na||Na cells employing the electrolyte can be cycled >2000 h at 0.1 mA cm−2. Na3V2(PO4)3||Na batteries reveal a high discharge specific capacity of 66.1 mAh g−1 at 15 C and demonstrate stable cycling over 1000 cycles with a capacity retention of 83% at a fast rate of 5 C.
A Polymer Canvas with the Stiffness of the Bone Matrix to Study and Control Mesenchymal Stem Cell Response
Authors: Zanut Alessandra , Li Rui , Deng Ru , Liu Xiangyu , Rejhon Martin , Chen Weiqiang , Weck Marcus , de Peppo Giuseppe Maria , Riedo Elisa 
Published: December 2022

AbstractReproducing in vitro the complex multiscale physical features of human tissues creates novel biomedical opportunities and fundamental understanding of cell−environment interfaces and interactions. While stiffness has been recognized as a key driver of cell behavior, systematic studies on the role of stiffness have been limited to values in the KPa−MPa range, significantly below the stiffness of bone. Here, a platform enabling the tuning of the stiffness of a biocompatible polymeric interface up to values characteristic of human bone is reported, which are in the GPa range, by using extremely thin polymer films on glass and cross‐linking the films using ultraviolet (UV) light irradiation. It is shown that a higher stiffness is related to better adhesion, proliferation, and osteogenic differentiation, and that it is possible to switch on/off cell attachment and growth by solely tuning the stiffness of the interface, without any surface chemistry or topography modification. Since the stiffness is tuned directly by UV irradiation, this platform is ideal for rapid and simple fabrication of stiffness patterns and gradients, thus representing an innovative tool for combinatorial studies of the synergistic effect of tissue environmental cues on cell behavior, and creates new opportunities for next‐generation biosensors, single‐cell patterning, and lab‐on‐a‐chip devices.
Dressing Bacteria With a Hybrid Immunoactive Nanosurface to Elicit Dual Anticancer and Antiviral Immunity
Authors: Liu Ying , Zhang Mengmeng , Wang Xinyue , Yang Fengmin , Cao Zhenping , Wang Lu , Liu Jinyao 
Published: December 2022

AbstractApproaches capable of simultaneously treating cancer and protecting susceptible patients from lethal infections such as coronavirus disease 2019, are highly desirable but prove to be difficult. Here, dressing bacteria with a hybrid immunoactive nanosurface is reported to elicit dual anticancer and antiviral immunity. A combination of a checkpoint blocking antibody and a virus‐specific antigen is covalently conjugated to polydopamine nanoparticles, which can be anchored onto bacterial surface, by a one‐step in situ polymerization of dopamine under a cell‐friendly condition. By virtue of the ability to colonize and penetrate deep tumor tissue, dressed bacteria enable sustained release and expanded exposure of carried immunoactivators to stimulate immune cells. In addition to a carrier role, bacteria are able to further provoke innate immunity due to the native immunogenicity of the pathogen‐associated molecular patterns. Immunization with dressed bacteria promotes the maturation, and activation of antigen‐presenting cells, which induces robust humoral and cellular immune responses in tumor‐bearing mice. As evidenced by efficient production of viral‐antigen‐specific immunoglobulin G antibody in serum and significantly suppressed tumor growth in different models, dressing bacteria with a hybrid immunoactive nanosurface paves an avenue to prepare next‐generation therapeutics for synergistic treatment and prevention.
PbWO4 Synergistically Modified with Styrene Maleic Anhydride and Bis(dioctyl pyrophosphate) Ethylene Titanate in Highly Filled Polymer Fibers for Enhanced γ‐Ray Shielding Safety and Wear Comfort of Articles
Authors: Mai Fu‐Han , Zhang Quan‐Ping , Wang Rui , Meng Ling‐Cheng , Liu Peng‐Qing , Zhang Yuan , Li Jia‐Le , Jiang Yong , Liang Qian‐Qian , Guo Lei , Liu Ji‐Zhen , Li Yin‐Tao , Zhou Yuan‐Lin 
Published: December 2022

AbstractRadiation protection safety and wear comfort of personal protective equipment (PPE) are of vital importance to nuclear personnel involved. Unfortunately, it is difficult for current PEE to meet the increasing requirements, which causes tremendous threats to health and reduced working efficiency. Here, a highly filled polymer fiber for textile‐based PPE to deal with the dilemma is put forward. PbWO4 (PWO) particles are superficially modified with styrene maleic anhydride (SMA) and then titanate coupling agent (bis(dioctyl pyrophosphate) ethylene titanate (BPET)) to form PWO@SMA‐BPET. After that, as high as 70 wt% PWO@SMA‐BPET/polyvinyl alcohol (PVA) fibers are obtained by solution blending and wet spinning in succession. Synergistic effects of surface modification with SMA and BPET lead to uniform dispersion PWO particles and good compatibility of interfaces in highly filled fibers. Importantly 36.6% γ‐ray (105 keV) shielding has been detected at three‐layer fabrics with 70 wt% PWO@SMA‐BPET/PVA fiber. Besides, the fabrics also display 116 mm s−1 of air permeability and 5388 g m−2 24 h of water vapor permeability, respectively. This work discloses synergistic effects on surface modification of high loading inorganic particles in polymer fibers, which give a further boost to γ‐ray shielding safety and wear comfort of PPE.
Highly Efficient Narrow‐Band Green Emission in LaZn1‐xMnxAl11O19 Magnetoplumbite Phosphors toward White LED Application and Optical Thermometer
Authors: Dang Peipei , Lian Hongzhou , Lin Jun 
Published: December 2022

AbstractMn2+‐doped phosphors with narrow‐band green emission are promising for white light‐emitting diodes (WLEDs) to achieve high color rendering index and efficacy. Here, a series of narrow‐band green‐emitting LaZn1−xMnxAl11O19 (0.01 ≤ x ≤ 0.30) magnetoplumbite phosphors (λem = 515 nm) with full width at half maximum (FWHM) of ≈26 nm are designed based on highly symmetrical crystallographic structure. These green phosphors exhibit good photoluminescence quantum yield (PLQY) and small thermal quenching (TQ) performance (86%@423 K) under 450 nm blue light excitation. By further heavy doping Mn2+ into LaZnAl11O19, a broadband red emission peaking at ≈672–697 nm appears upon blue light excitation due to the Mn2+–Mn2+ super‐exchange interactions. A dual‐wavelength emission in LaZn1−xMnxAl11O19 (0.5 ≤ x ≤ 1.0) phosphors provides thermal‐sensitive emission for ratiometric temperature sensing with good relative sensitivity. Benefitting from the Eu2+ → Mn2+ energy transfer, the green emission from Mn2+ is increased by 26 times, and the internal QY of La0.97Zn1−xMnxAl11O19:0.03Eu2+ reaches as high as 88% upon 350 nm light excitation. The efficient blue‐to‐green phosphors are obtained and used as candidates for violet‐excited WLEDs. This study has a guiding role in the development of Mn2+‐doped phosphors in mineral structure with photoluminescence control based on high symmetry and Mn2+–Mn2+ dimers.
Natural Peach Gum as Porous Carbon Precursor and Gel Electrolyte for High‐Performance Zinc‐Ion Hybrid Supercapacitors
Authors: Shi Fangfang , Liu Qifan , Yang Chao , Qiu Jianhui , Zang Limin 
Published: December 2022

AbstractEnabling green manufacturing processes for energy storage devices is a significant aspect of achieving sustainable development. Herein, peach gum (PG) which is a kind of natural, renewable, and abundant biomass, is chosen to fabricate zinc‐ion hybrid supercapacitors (ZHSCs). PG is used as the carbon source to prepare porous carbon materials by simultaneous carbonization and activation process. The effects of potassium hydroxide concentration and carbonization temperature on the as‐prepared carbon materials are investigated. The porous carbon prepared under the optimal conditions has a large specific surface area of 1587 m2 g−1, and the ZHSC constructed by this porous carbon and Zn foil exhibits a high specific capacity of 338.3 mAh g−1 at 0.2 A g−1 in 2 m ZnSO4. Furthermore, PG is used to prepare PG/ZnSO4 gel electrolyte to assemble the quasisolid‐state ZHSC, and the maximum specific capacity, energy density, and power density of the device can reach 169.2 mAh g−1, 152.3 Wh kg−1, and 9000 W kg−1, respectively. Besides, the device also exhibits good cycling stability with a capacity retention of 90.1% after 15 000 cycles. This strategy provides a simple and effective way for the application of PG to fabricate green energy storage devices with high performance.
A Calcium Alginate Hydrogel Microsphere‐Based Transcatheter Arterial Viroembolization Strategy for Hepatocellular Carcinoma
Authors: Lv Peng , Chen Hu , Cheng Hongwei , Liu Xuan , Liu Chao , Zeng Yun , Jiang Lai , Wang Xiaoyong , Mao Jingsong , Liu Gang 
Published: December 2022

AbstractOncolytic adenoviruses (OAs)‐based virotherapy can regulate the tumor microenvironment, providing a rational strategy for combination treatment with other tumor therapy techniques, such as transcatheter arterial embolization (TAE). Here, a novel, validated transcatheter arterial viroembolization (TAVE) strategy—a calcium alginate hydrogel microsphere with OA encapsulated (OA@Alg beads) to achieve a combination of TAE with oncolytic virotherapy to enhance and prolong antitumor efficacy of OA in hepatocellular carcinoma treatment—is described. The OA@Alg beads show excellent vascular embolization in a rabbit hepatic VX2 carcinoma model, resulting in successful occlusion of hepatic arteries. Importantly, OA@Alg beads enable sustained release of OA and maintain their bioactivity for extended periods while preventing OA shedding from the tumor site to healthy tissues. Moreover, the system preserves the OA's ability to induce an antitumor immune response, resulting in higher intratumoral infiltration by CD4+/CD8+ T cells. The OA@Alg beads have the potential as an effective embolic system for TAVE in the clinical treatment of hepatocellular carcinoma.
Amorphous 2D‐Nanoplatelets of Red Phosphorus Obtained by Liquid‐Phase Exfoliation Yield High Areal Capacity Na‐Ion Battery Anodes
Authors: Kaur Harneet , Konkena Bharathi , Gabbett Cian , Smith Ross , McCrystall Mark , Tian Ruiyuan , Roy Ahin , Carey Tian , Vega‐Mayoral Victor , Nicolosi Valeria , Coleman Jonathan N. 
Published: December 2022

AbstractThe development of sodium ion batteries will require high‐performance electrodes with very large areal capacity and reasonable rate performance. Although red phosphorus is a very promising electrode material, it has not yet fulfilled these requirements. Here, liquid phase exfoliation is used to convert solid red phosphorus into amorphous, quasi‐2D nanoplatelets. These nanoplatelets have lateral sizes of hundreds of nanometers, thickness of 10s of nanometers and are quite stable in ambient conditions, displaying only low levels of oxidation on the nanosheet surface. By solution mixing with carbon nanotubes, these nanoplatelets can be fabricated into nanocomposite battery anodes. After employing an extended activation process, good cycling stability over 1000 cycles and low‐rate capacitances >2000 mAh gP−1 is achieved. Because of the high conductivity and mechanical robustness provided by the nanotube network, it is possible to fabricate very thick electrodes. These electrodes display extremely high areal capacities approaching 10 mAh cm−2 at currents of ≈1 mA cm−2. Detailed analysis shows these electrodes to be limited by solid‐state diffusion such that the thickest electrodes have state‐of‐the‐art rate performance and a near‐optimized combination of capacity and rate performance.
Immobilizing Low‐Cost Metal Nitrides in Electrochemically Reconstructed Platinum Group Metal (PGM)‐Free Oxy‐(Hydroxides) Surface for Exceptional OER Kinetics in Anion Exchange Membrane Water Electrolysis
Authors: Thangavel Pandiarajan , Lee Hojeong , Kong Tae‐Hoon , Kwon Seontaek , Tayyebi Ahmad , Lee Ji‐hoon , Choi Sung Mook , Kwon Youngkook 
Published: December 2022

AbstractA highly efficient and platinum group metal (PGM)‐free oxygen evolution reaction (OER) electrode is developed by immobilizing Ni3N particles on the electrochemically reconstructed amorphous oxy‐hydroxides surface, resulting in a twofold higher industrial relevance current density of 1 A cmgeo−2 at an ultra‐small overpotential η(O2) of 271 mV, with a high turnover frequency of 2.53 s−1, high Faradic efficiency of 99.6 % and exceptional OER stability of 1000 h in continuous electrolysis. Such a unique amorphous‐crystalline interface with enriched active sites greatly facilitates electron transport and OER kinetics at the electrode‐electrolyte interface. Further, combined with an efficient PGM‐free cathode (MoNi4/MoO2@Ni), this electrode demonstrates a current density of 685 mA cmgeo−2 at 1.85 Vcell at 70 °C in an anion exchange membrane water electrolyzer (AEMWE) operated with ultra‐pure water‐electrolyte. These findings highlight the design of highly‐efficient oxygen‐evolving catalysts and significant advancement in the practical implementation of AEMWEs for grid‐scale hydrogen production.
BHLHA9 homozygous duplication in a consanguineous family: A challenge for genetic counseling
Authors: Chouery Eliane , Tahan Elio , Karam Rim , Pharoun Jana , Mehawej Cybel , Megarbane Andre 
Published: December 2022

AbstractSplit‐hand/foot malformation (SHFM) with long‐bone deficiency (SHFLD) is a rare condition characterized by SHFM associated with long‐bone malformation usually involving the tibia. It includes three different types; SHFLD1 (MIM % 119,100), SHFLD2 (MIM % 610,685) and SHFLD3 (MIM # 612576). The latter was shown to be the most commonly reported with a duplication in the 17p13.1p13.3 locus that was narrowed down to the BHLHA9 gene. Here, we report a consanguineous Lebanese family with three members presenting with limb abnormalities including tibial hemimelia. One of these patients presented with additional bowing fibula and another with bilateral split hand. CGH array analysis followed by RQ‐PCR allowed us to detect the first homozygous duplication on the short arm of chromosome 17p13.3 including the BHLHA9 gene and involved in SHFLD3. Interestingly, one patient with the homozygous duplicated region, carrying thus four BHLHA9 copies presented with long bone deficiency but no SHFM. The incomplete penetrance and the variable expressivity of the disease in this family as well as the presence of the BHLHA9 homozygous duplication rendered genetic counseling extremely challenging and preimplantation genetic diagnosis almost impossible.
ZDHHC15 as a candidate gene for autism spectrum disorder
Authors: Casellas‐Vidal Dolors , Mademont‐Soler Irene , Sánchez Joana , Plaja Alberto , Castells Neus , Camós Maria , Nieto‐Moragas Javier , del Mar García Maria , Rodriguez‐Solera Celia , Rivera Helena , Brunet Joan , Álvarez Sara , Perapoch Josep , Queralt Xavier , Obón María 
Published: December 2022

AbstractThe phenotypic repercussion of ZDHHC15 haploinsufficiency is not well‐known. This gene was initially suggested as a candidate for X‐linked mental retardation, but such an association was later questioned. We studied a multiplex family with three members with autism spectrum disorder (ASD) by array CGH, karyotype, exome sequencing and X‐chromosome inactivation patterns. Medical history interviews, cognitive and physical examinations, and sensory profiling were also assessed. The three family members with ASD (with normal cognitive abilities and an abnormal sensory profile) were the only carriers of a 1.7 Mb deletion in the long arm of chromosome X, involving: ZDHHC15, MAGEE2, PBDC1, MAGEE1, MIR384 and MIR325. The normal chromosome X was preferentially inactivated in female carriers, and the whole exome sequencing of an affected family member did not reveal any additional genetic variant that could explain the phenotype. Thus, in the present family, ASD segregates with a deletion on chromosome X that includes ZDHHC15. Considering our results together with gene data (regarding function, expression, conservation and animal/cellular models), ZDHHC15 is a candidate gene for ASD. Emerging evidence also suggests that this gene could be associated with other neurodevelopmental disorders, with incomplete penetrance and variable expressivity.
Unraveling the Structure Transition and Peroxidase Mimic Activity of Copper Sites over Atomically Dispersed Copper‐Doped Carbonized Polymer Dots
Authors: Gao Fucheng , Huang Jian , Ruan Ying , Li Hui , Gong Pengyu , Wang Fenglong , Tang Qunwei , Jiang Yanyan 
Published: December 2022

AbstractThe lack of systematic structural resolution makes it difficult to build specific transition‐metal‐atom‐doped carbonized polymer dots (TMA‐doped CPDs). Herein, the structure‐activity relationship between Cu atoms and CPDs was evaluated by studying the peroxidase‐like properties of Glu−Cu−CPDs prepared by using copper glutamate (Glu) with a Cu−N2O2 initial structure. The results showed that the Cu atoms bound to Glu−Cu−CPDs in the form of Cu−N2C2, indicating that Cu−O bonds changed into Cu−C bonds under hydrothermal conditions. This phenomenon was also observed in other copper‐doped CPDs. Moreover, the carboxyl and amino groups content decreased after copper‐atom doping. Theoretical calculations revealed a dual‐site catalytic mechanism for catalyzing H2O2. The detection of intracellular H2O2 suggested their application prospects. Our study provides an in‐depth understanding of the formation and catalytic mechanism of TMA‐doped‐CPDs, allowing for the generation specific TMA‐doped‐CPDs.
Selective Electrochemical Hydrogenation of Phenol with Earth‐abundant Ni−MoO2 Heterostructured Catalysts: Effect of Oxygen Vacancy on Product Selectivity
Authors: Zhou Peng , Guo Si‐Xuan , Li Linbo , Ueda Tadaharu , Nishiwaki Yoshinori , Huang Liang , Zhang Zehui , Zhang Jie 
Published: December 2022

AbstractHerein, we report highly efficient carbon supported Ni−MoO2 heterostructured catalysts for the electrochemical hydrogenation (ECH) of phenol in 0.10 M aqueous sulfuric acid (pH 0.7) at 60 °C. Highest yields for cyclohexanol and cyclohexanone of 95 % and 86 % with faradaic efficiencies of ∼50 % are obtained with catalysts bearing high and low densities of oxygen vacancy (Ov) sites, respectively. In situ diffuse reflectance infrared spectroscopy and density functional theory calculations reveal that the enhanced phenol adsorption strength is responsible for the superior catalytic efficiency. Furthermore, 1‐cyclohexene‐1‐ol is an important intermediate. Its hydrogenation route and hence the final product are affected by the Ov density. This work opens a promising avenue to the rational design of advanced electrocatalysts for the upgrading of phenolic compounds.