bluuebunny/crossref_metadata_2025_split huggingface dataset:
A Student-Centric Analysis of Faculty Competences and Competencies for Effective Educational Experiences
Authors: Lozada Paolo Roberto 
Published: January 2025

Competences represents different characteristics of a holistic approach to personal development and community engagement and Competencies are aspects that plays a crucial role in effective teaching and contributes to creating meaningful learning experiences for students. The objectives of the study are to determine the competences and competencies that provides effective teaching at San Sebastian College – Recoletos de Cavite Inc., to analyze the faculty performance based on student perspectives using the Student Evaluation of Teachers tool, and to develop recommendations for improving faculty competences and competencies from a student-centric perspective. The study used a descriptive quantitative design and evaluation results from the Center of Research and Creative Works of San Sebastian College – Recoletos de Cavite, Inc. are gathered to analyze the data. The evaluation of faculty competencies across three academic years (2020-2021, 2021-2022, and 2022-2023) reveals consistent high performance. In 2020-2021, the majority of faculty received high-level ratings in both competences and competencies, with 146 and 148 faculty members respectively. This trend continued in 2021-2022, with a significant increase to 352 and 356 faculty members receiving high-level ratings. The 2022-2023 data shows a slight decrease, with 183 and 186 faculty members rated at a high level. Across all years, very few faculty members were rated at low or very low levels, indicating overall strong faculty performance. Continuous curriculum adaptation, incorporating online teaching methods, and improving collaboration with the industry while supporting effective work-life routines will help educational institutions to improve their academic performance.
Alkylphenols and Alkylphenol Ethoxylates in Freshwater Fish: Levels and Human Health Risk Estimates from River Benue, Central Nigeria
Authors: Wase Geoffrey Aernyi , Eneji Ishaq Shaibu , Wuana Raymond Ahule , Tongu Sylvester Mbaavaga , Sha’Ato Rufus 
Published: January 2025

Alkylphenols (APs) and Alkylphenols ethoxylates (APEs), are ubiquitous estrogenic chemicals, widely distributed in fish due to their persistence and lipophilicity. This study determined levels of APs and APEs, and the associated human health risk in two fish species, 16 Labeo coubie (African carp) and 16 Hydrocynus vittatus (African Tiger fish) sampled quarterly from River Benue, central Nigeria between September 2019 and June 2020. Compounds were identified and quantified using Gas Chromatography with Mass Spectrometric detection (GC-MS). Levels of twenty APs (∑20APs) in Labeo cubie ranged from ND-16.0 ng g-1 wet wt, with total and maximum values of 94.5 ng g-1 wet wt, and 16.0 ng g-1 wet wt respectively. Residues of four APEs (∑4APEs) ranged from ND-3.1 ng g-1 wet wt, total of 5.0 ng g-1 wet wt, and maximum of 3.1ng g-1 wet wt respectively. In Hydrocynus vitatus, ∑20APs ranged from ND-27.8 ng g-1 wet wt, total and maximum of 205 and 27.8 ng g-1 wet wt, respectively. Estimated risk from ingestion of compounds in Labeo cubie and Hydrocynus vitatus by adult and children indicate no immediate potential harm as the hazard quotient (HQ) value was less than one (HQ < 1). However, children could suffer higher body burdens of these pollutants than adults if they are fed with these fish. This study provides baseline data on levels and estimated human health risk from ingestion of these two species of fish contaminated by APs and APEs to regulatory agents and future researchers.
Studies on Correlation and Path Coefficient Analysis for Yield and Yield Associated Traits in Wheat (Triticum aestivum L.) Genotypes
Authors: Choudhary Shivani , Gaur S. C. , Kumar Sunil 
Published: January 2025

A randomized complete block design with three replications was used to plant twenty bread wheat genotypes inside Mosul B.R.D P.G. College in Deoria (U.P.). The rows were spaced three meters apart, with a split-plot system. The objective was to evaluate the relationship between grain yield and specific traits, including plant height, number of spikes, number of grains per spike, biological yield, 1000-grain weight and harvest index. Additionally, the study aimed to perform genotypic and phenotypic path coefficient analysis to identify key traits influencing grain yield. According to the data, the biological yield, number of spikes and grain yield exhibited the highest means when row spacing was 2.5 cm. Comparing this row space to 2.5 and 0.25 m row spaces, respectively, the grain yield was 0.615% and 0.2373% greater. Grain yield was one of the several qualities certain genotypes substantially exceeded, placing them at the forefront of PBW-343, Black and K-1006 followed by the genotypes HD-3086, PBW-107, DBW14 and Raj-4120. The yield/unit area was found to have phenotypically significant positive correlations with the number of spikes per unit area and to have substantial positive genotypic and phenotypic correlations with plant height, biological yield, number of grains/spike, 1000 grain weight, and harvest index. Path coefficient analysis showed that the number of grains/spike and harvest index had greater direct effects on grain yield from genetic and phenotypic factors as well as indirect effects through some other traits, with biological factors being the most important. This information helps determine the reliability of these three traits as selection criteria for higher yield performance in breeding programs.
Rhetorical Devices Used To Make Emphasis In Brian Tracy’s Talk “How To Build A Business That Works”
Authors: Faith Christopher , Nugroho Aylanda Hidayati Dwi 
Published: January 2025

This research investigates the types of rhetorical devices that Brian Tracy used in his business presentation, three types of rhetorical devices that are mostly used, and how these rhetorical devices are used to make emphasis on his business tips and suggestions. This research used Harris (2018) and Fahnestock (2011) theories on rhetorical devices. The findings showed that Brian Tracy utilized different types of rhetorical devices to aid him in emphasizing his main idea, such as metaphor, simile, sentential adverb, asyndeton, polysyndeton, hyperbole, paralepsis, litotes, and climax. The three most used types of rhetorical devices in his presentation are Metaphor, Sentential Adverb and Simile. Brian Tracy utilized metaphor to create a clearer imagery, sentential adverb to separate the anecdotes and conclusion, and simile to give comparison of two subjects. From the findings, the writer concludes that rhetorical devices can help the presenter in delivering his main points. Rhetorical devices help in emphasizing the main idea and creates a more engaging presentation with the audience, hence creating a more impactful and beneficial presentation.
Evaluation of Assisted Reproductive Technology Health Insurance Coverage for Multiple Pregnancies and Births in Korea
Authors: Cha Wontae , Yun Il , Nam Chung-Mo , Nam Jin Young , Park Eun-Cheol 
Published: June 2023

ImportanceWhile various policies to support couples experiencing infertility have been introduced due to the fertility rate rapidly dropping in developed countries, few large-scale nationwide cohort studies have evaluated the outcomes of assisted reproductive technology (ART) health insurance coverage policies.ObjectiveTo evaluate ART health insurance coverage for multiple pregnancies and births in Korea.Design, Setting, and ParticipantsThis population-based cohort study used delivery cohort data from the Korean National Health Insurance Service database between July 1, 2015, and December 31, 2019. A total of 1 474 484 women were included after exclusion of those who gave birth at nonmedical institutions and those with missing data.ExposureTwo 27-month periods were examined before and after the Korean National Health Insurance Service had begun covering ART treatment (preintervention period, July 1, 2015, to September 30, 2017; postintervention period, October 1, 2017, to December 31, 2019).Main Outcomes and MeasuresMultiple pregnancies and multiple births were identified by International Statistical Classification of Diseases and Related Health Problems, Tenth Revision diagnosis codes. Total births were defined as the total number of babies born to each pregnant woman during the follow-up period. An interrupted time series with segmented regression was conducted to analyze the time trend and its change in outcomes. Data analysis was conducted between December 2, 2022, and February 15, 2023.ResultsOf the 1 474 484 women eligible for the analysis (mean [SD] age, 33.2 [4.6] years), approximately 1.60% had multiple pregnancies and 1.10% had multiple births. After covering ART treatment, the likelihood of multiple pregnancies and multiple births was estimated to increase by 0.7% (estimate, 1.007; 95% CI, 1.004-1.011; P &amp;lt; .001) and 1.2% (estimate, 1.012; 95% CI, 1.007-1.016; P &amp;lt; .001) compared with before coverage. The probability of an increase in the number of total births per pregnant woman after the intervention was estimated to be 0.5% (estimate, 1.005; 95% CI, 1.005-1.005; P &amp;lt; .001). The relatively high-income class above the median income showed a decreasing trend in multiple births and total births before the intervention, but after the intervention, a significant increase was observed.Conclusions and RelevanceThis population-based cohort study found that the possibility of multiple pregnancies and births in Korea significantly increased after the implementation of an ART health insurance coverage policy. These findings suggest that the development and coverage of policies to support couples experiencing infertility may help address low fertility rates.
Cell Electrospinning: a Review of Materials and Methodologies for Biofabrication
Authors: Maurmann Natasha , França Fernanda S. , Girón Juliana , Pranke Patricia 
Published: June 2023

AbstractThe process of electrohydrodynamic living cell microencapsulation inside a scaffold during the electrospinning (ES) process is called cell electrospinning (CE). Several studies demonstrate the feasibility of using cell electrospinning for biomedical applications, allowing for the direct biofabrication of living cells to be encapsulated in fibers for the formation of active biological scaffolds. In this review, a comprehensive overview of the materials and methodologies used in cell electrospinning, as well as their biomedical application in tissue engineering, is provided. Cell ES represents an innovative technique for automated application in regenerative medicine.
Intracellular Liquid‐Liquid Phase Separation Induces Tunable Anisotropic Nanocrystal Growth for Multidimensional Analysis
Authors: Liu Hao , Liu Zhiming , Wang Yihan , Xiao Jiang , Liu Xiaohui , Jiang Hui , Wang Xuemei 
Published: June 2023

AbstractSpatially directed biomineralization of nanocrystals for specific optical purposes in biological systems and elucidation of the mechanism of biomineralized nanocrystals remains a fascinating but extremely challenging task. Herein, the biomineralization of tunable gold nanocrystals with in situ protein coronas by intracellular liquid‐liquid phase separation (LLPS) for in situ molecule surface‐enhanced Raman spectrum (SERS) analysis and tumor fluorescence identification. The anisotropic nanocrystals are realized by regulating LLPS, in which the nucleation of nanocrystals is at the protein secondary structural site (β‐Corner) of the droplet, the different adsorption energies of crystal surfaces further promote the directional growth of nanocrystals. Interestingly, gold nanocrystals with ultra‐narrow fluorescence emission at half‐peak width and ultra‐long Stokes shift and can obtain in situ molecular fingerprint information of protein corona to achieve by SERS. Of note are the anisotropic nanocrystals to differentiate clinical patient tumor tissue samples. Therefore, this study reveals the mechanism of intracellular tunable nanocrystal biomineralization and provides the basis for its biomedical application.
Metallic Particles‐Induced Surface Reconstruction Enabling Highly Durable Zinc Metal Anode
Authors: Liu Wen , Zhao Qiwen , Yu Huaming , Wang Han , Huang Shaozhen , Zhou Liangjun , Wei Weifeng , Zhang Qichun , Ji Xiaobo , Chen Yuejiao , Chen Libao 
Published: June 2023

AbstractAqueous zinc batteries usher in a renaissance due to their intrinsic security and cost effectiveness, bespeaking vast application foreground for large‐scale energy storage system. However, uncontrolled dendrite growth along with hydrogen evolution severely restricts its reversibility and stability for practical application. Herein, the surface of Zn metal is reconstructed with metallic particles (In, Sn, In0.2Sn0.8) to diminish surface defects and regulate Zn deposition behavior. The alloyed In–Sn greatly activates the Zn surface for lower Zn adsorption energy barrier to expedite plating kinetics and confine Zn aggregation. Dense and uniform deposition of Zn on the reconstructed surface significantly prevents the Zn substrate from dendrites growth for catastrophic damage. Meanwhile, alloy layer embodies high hydrogen evolution overpotential, ensuring high plating and stripping efficiency for Zn anode. Consequently, In0.2Sn0.8 reconstructed surface realizes long‐term lifespan up to 1800 h with low polarization (12 mV) at the condition of 1 mA cm−2 and 1 mAh cm−2. When paired with sodium vanadate (NVO) cathode, the full cell steady operates for a high‐capacity retention of 94.0% after 5000 cycles at 5 A g−1. This study provides new insights into the surface‐defects dependent Zn deposition process and offers a guide for constructing stable surface for dendrite‐free Zn growth.
From Aluminum Dissolution in Supercapacitors to Electroplating: A New Way for Al Thin Film Deposition?
Authors: Zaccagnini Pietro , Heß Lars Henning , Baudino Luisa , Laurenti Marco , Serrapede Mara , Lamberti Andrea , Balducci Andrea 
Published: June 2023

AbstractThe present work addresses a new finding observed while performing aluminum dissolution experiments for supercapacitors (SCs) stability investigation. Supercapacitor (SC) electrodes based on carbon‐coated aluminum foils are electrochemically cycled in harsh conditions into bis‐trifluoromethylsulfonyl imide (TFSI)‐based electrolyte and using Acetonitrile (ACN) as solvent. Dissolution of aluminum is observed with subsequent plating on the carbonaceous surface of counter electrodes. Moreover, the same process can be reproduced also on standard SC activated carbon electrodes. This mechanism can open the way to an effective strategy to achieve Al film deposition by electroplating becoming competitive with the most common copper counterpart.
Inverse metabolic engineering for improving protein content in Saccharomyces cerevisiae
Authors: Lee Young‐Oh , Do Sang‐Hun , Won Jae Yoon , Chin Young‐Wook , Chewaka Legesse S. , Park Bo‐Ram , Kim Soo‐Jung , Kim Sun‐Ki 
Published: June 2023

AbstractProduction of Saccharomyces cerevisiae‐based single cell protein (SCP) has recently received great attention due to the steady increase in the world's population and environmental issues. In this study, an inverse metabolic engineering approach was applied to improve the production of yeast SCP. Specifically, an S. cerevisiae mutant library, generated using UV‐random mutagenesis, was screened for three rounds to isolate mutants with improved protein content and/or concentration. The #1021 mutant strain exhibited a respective 31% and 23% higher amino acid content and concentration than the parental S. cerevisiae D452‐2 strain. Notably, the content, concentration, and composition of amino acids produced by the PAN2* strain, with a single nucleotide polymorphism in PAN2 coding for a catalytic subunit of the poly(A)‐nuclease (PAN) deadenylation complex, were virtually identical to those produced by the #1021 mutant strain. In a glucose‐limited fed‐batch fermentation, the PAN2* strain produced 19.5 g L−1 amino acids in 89 h, which was 16% higher than that produced by the parental D452‐2 strain. This study highlights the benefits of inverse metabolic engineering for enhancing the production titer and yield of target molecules without prior knowledge of rate‐limiting steps involved in their biosynthetic pathways.
Structural Optimization, Fungicidal Activities Evaluation, DFT Study and Structure‐Activity Relationship of Dopamine Derivatives with Benzothiazole Fragment from Polyrhachis dives
Authors: Wang Yaxuan , Huang Danling , Cheng Yong‐Xian 
Published: June 2023

AbstractIn our previous work, two dopamine derivatives with benzothiazole fragment were isolated and identified from Polyrhachis dives (P. dives). Based on their characteristic structure, we used them as lead compound to carry out structural optimization and subsequent fungicidal evaluation. Here 20 dopamine derivatives with benzothiazole fragment were designed and synthesized by a facile method, and their structures were characterized by 1H‐NMR, 13CNMR and HMRS. In bioassays, most of the title compounds possess potential fungicidal activities against Altenaia alternala (A. alternala) and Botrytis cinerea (B. cinerea). Especially, (E)‐N‐(2‐(benzo[d]thiazol‐6‐yl)ethyl)‐3‐(p‐tolyl)acrylamide and (E)‐N‐(2‐(benzo[d]thiazol‐6‐yl)ethyl)‐3‐(4‐(trifluoromethyl)phenyl)acrylamide displayed 29.3 mg/L and 10.7 mg/L EC50 value against A. alternala, respectively, which possessed equivalent fungicidal activities level to hymexazol.
Effect of plasmid DNA isoforms on preparative anion exchange chromatography
Authors: Kralj Špela , Kodermac Špela Meta , Bergoč Ines , Kostelec Tomas , Podgornik Aleš , Štrancar Aleš , Černigoj Urh 
Published: June 2023

AbstractIncreased need for plasmid DNA (pDNA) with sizes above 10 kbp (large pDNA) in gene therapy and vaccination brings the need for its large‐scale production with high purity. Chromatographic purification of large pDNA is often challenging due to low process yields and column clogging, especially using anion‐exchanging columns. The goal of our investigation was to evaluate the mass balance and pDNA isoform composition at column outlet for plasmids of different sizes in combination with weak anion exchange (AEX) monolith columns of varying channel size (2, 3 and 6 µm channel size). We have proven that open circular pDNA (OC pDNA) isoform is an important driver of reduced chromatographic performance in AEX chromatography. The main reason for the behaviour is the entrapment of OC pDNA in chromatographic supports with smaller channel sizes. Entrapment of individual isoforms was characterised for porous beads and convective monolithic columns. Convective entrapment of OC pDNA isoform was confirmed on both types of stationary phases. Porous beads in addition showed a reduced recovery of supercoiled pDNA (on an 11.6 kbp plasmid) caused by diffusional entrapment within the porous structure. Use of convective AEX monoliths or membranes with channel diameter >3.5 µm has been shown to increase yields and prevent irreversible pressure build‐up and column clogging during purification of plasmids at least up to 16 kbp in size.
Barriers in quest for cancer care access in two states of northeast India
Authors: Kuru Dindi , Kumar K Anil , Chaturvedi Pankaj 
Published: June 2023

AbstractBackgroundThe cancer burden in northeast India is high, with low survival and low case detection. Despite the availability of cancer institutes in the region, existing literature remarks on the increasing travel outside the region for cancer care. However, research is sparse on identifying impediment factors to the access of state cancer institutes.ObjectiveTo examine the barriers to cancer care in five common cancer sites: oral, lungs, stomach, breast and cervix.MethodFollowing a descriptive multiple‐embedded case study design integrating quantitative and qualitative approaches, 388 participants were selected in phase one by stratified random sampling. In phase two, by purposive sampling, 21 semi‐structured interviews were conducted.ResultThe result suggests that family decision is the central factor in cancer care access. Treatment initiation is delayed because the existing government health insurance scheme does not cover diagnostic tests. Adverse steps are taken to fund cancer treatment. Besides, opting for alternative medicines were due to fear of surgery, chemotherapy and recommendations by relatives. Arranging accommodation, transportation and infrastructure shortage was another hurdle. In contrast, the lack of awareness of the state cancer institutes was a barrier to its access.ConclusionThis paper identifies and describes factors that hinder access to state cancer institutes. The findings could enhance policy interventions for efficient cancer care access in the region. Integration with NGOs working at the state level for cancer services would support ease of access by providing funds for diagnostic tests, accommodation and transportation, especially for those who cannot afford it.
The offshore wind energy potential of Morocco: Optimal locations, cost analysis, and socioenvironmental examination
Authors: Charouif Yassine , Lehnert Matthew R. 
Published: June 2023

Abstract
Morocco, a country without substantial fossil fuels, is emerging as a leader in renewable energy. This article addresses an untapped natural resource in Morocco: offshore wind. Methodologically, we use geographic information systems to assess optimal locations for offshore wind energy plants based on wind speed and power density from the Global Wind Atlas. We incorporate geological, environmental, and economic parameters and calculate capital expenses, operating expenses, development costs, and decommissioning costs to determine if the wind plant will provide a return on investment during its lifetime. The results identify three locations near the cities of Dakhla, Boujdour, and Essaouira that would recoup their investment in 14, 13, and 18 years, respectively, along with supplying 21.8% of Morocco's current energy needs for 2022. We conclude by considering the implications that the new plants would have for Morocco in the social, political, environmental, and economic dimensions. Integr Environ Assess Manag 2024;20:201–210. © 2023 SETAC
The consequences of neglected confounding and interactions in mixed‐effects meta‐regression: An illustrative example
Authors: Knop Eric S. , Pauly Markus , Friede Tim , Welz Thilo 
Published: June 2023

AbstractAnalysts seldom include interaction terms in their meta‐regression model, which can introduce bias if an interaction is present. We illustrate this by reanalysing a meta‐regression study in acute heart failure. Based on a total of 285 studies, the 1‐year mortality rate related to acute heart failure is considered and the connection to the study‐level covariates year of recruitment and average age of study participants are of interest. We show that neglecting a possibly confounding variable and an interaction term might lead to erroneous inference and conclusions. Based on our results and accompanying simulations, we recommend to include possible confounders and interaction terms, whenever they are plausible, in mixed‐effects meta‐regression models.