bluuebunny/crossref_metadata_2025_split huggingface dataset:
Catalytic Decomposition Mechanism of PH3 on 3DCuO/C and High Value Utilization of Deactivated Catalysts
Authors: Feng Jiayu , Ma Lixuan , Wang Chi , Ma Yixing , Sun Xin , Jia Lijuan , Ning Ping , Zhang Riguang , Wang Fei , Li Kai 
Published: April 2023

AbstractWith the widespread application of lithium iron phosphate batteries, the production capacity of the yellow phosphorus industry has increased sharply, and the treatment of the highly toxic by‐product PH3 is facing severe challenges. In this study, a 3D copper‐based catalyst (3DCuO/C) that can efficiently decompose PH3 at low temperatures and low oxygen concentrations is synthesized. The PH3 capacity is up to 181.41 mg g−1, which is superior to that previously reported in the literature. Further studies indicated that the special 3D structure of 3DCuO/C induces oxygen vacancies on the surface of CuO, which is beneficial to the activation of O2, and then promotes the adsorption and dissociation of PH3. The doping of P after dissociation determines the formation of Cu‐P, and the eventual conversion to Cu3P leads to the deactivation of CuO active sites. More strikingly, due to the appearance of Cu3P, the deactivated De‐3DCuO/C (Cu3P/C) exhibited significant activity in the photocatalytic degradation of rhodamine B and photocatalytic oxidation of Hg0 (gas) and can also be a candidate as an anode material for Li batteries after modification, which will provide a more thorough and economical treatment scheme for deactivated catalysts.
Application of high‐performance fibre reinforced concrete to precast girders for road bridges: Conceptual considerations and numerical analyses
Authors: Ruiz Rafael , Todisco Leonardo , Corres Hugo 
Published: April 2023

AbstractHigh‐performance fiber‐reinforced concrete (HPFRC) can be considered a promising material for the construction of precast concrete girders for road bridges. This paper presents conceptual considerations and numerical analysis to support this statement. The HPFRC is a compromised alternative between FRC and UHPFRC mixes. Specifically, a tailor‐made mix design of HPFRC jointly developed by ACCIONA and the authors is presented, and then compared with the other types of fiber‐reinforced concretes collected from the technical literature. In addition, some trends observed in the database are described. This material characterization is followed by a conceptual analysis of the advantages of the application of HPFRC to road bridges. Specifically, a proposed bridge for the case of a 60 m‐span box girder is analyzed. A comparison between alternatives based on the use of HPFRC and conventional reinforced concrete is discussed. The results shed light on the viability of this material for bridge application. Specifically, the main finding show potential significant material savings in structural elements of the superstructure. Finally, ongoing and future research for a wide application to the construction sector are briefly discussed.
A feature selection for video quality of experience modeling: A systematic literature review
Authors: Skaka ‐ Čekić Fatima , Baraković Husić Jasmina 
Published: April 2023

AbstractQuality of Experience (QoE) multidimensional concept is the key for successful delivery of multimedia services. Higher user requirements for new experiences such as augmented reality, virtual reality, and future 6G services set higher requirements for QoE. A more complex QoE space requires the use of data mining methods in order to process the data for better QoE prediction. The increased dimensionality of the QoE space becomes a limiting factor for achieving the desired QoE prediction accuracy. Existing studies considering the QoE multidimensional concept with approaches that overcome the challenge of increased QoE space dimensionality are of great importance for future research. Accordingly, this article aims to review the applications of Feature Selection (FS) methods in video QoE modeling. It provides a comprehensive overview of the existing studies with the categorization and review of applied FS methods with reference to the data collection and data modeling steps. The analysis included 71 studies which provides overview of the FS methods applications in video QoE modeling depending on the input Influence Factor (IF) dimension sizes, type of IFs, QoE prediction methods used and QoE evaluation type. Our review revealed the advantages of using FS methods in video QoE modeling, frequency of application of FS methods with potential of applying more FS methods in a series or a parallel, gives an overview of the achieved dimensionality reduction degree for different methods, and provides insights in opportunities for researchers for applying FS methods on complex multidimensional QoE space.This article is categorized under:
Technologies > Data Preprocessing
Algorithmic Development > Multimedia
Swiss Taxes on Investment and Financing
Authors: Meier Henri B. , Marthinsen John E. , Gantenbein Pascal A. , Weber Samuel S. 
Published: April 2023

AbstractSwitzerland's federal government got the right to impose indirect taxes in 1848, and only under the pressure of war expenditures, in 1940, was it authorized to levy direct taxes. Government spending and tax revenues have grown since then. Unlike stories of a tax paradise, Switzerland's total tax burden is only slightly below the OECD's European average and often not in the best interest of future economic development. The country's tax laws favor debt over equity financing. Its Tax and Social Security systems support the retired generation. Stamp and withholding taxes hamper the development of Swiss capital markets, and not allowing tax credits from losses for more than seven years heavily burdens innovative start-ups, constituting an intergenerational transfer of assets and opportunities.
Swiss Institutional Investors
Authors: Meier Henri B. , Marthinsen John E. , Gantenbein Pascal A. , Weber Samuel S. 
Published: April 2023

AbstractInstitutional Investors, such as insurance companies, pension funds, real estate funds, and mutual funds, have become critically important players in the Swiss financial market. They channel capital from a multitude of investors, such as households, businesses, and the government, into asset classes like equities, debt, commodities, and real estate. The social security system plays a key role in this, together with the state-run basic benefit plan, the mandatory occupational pension scheme, and private savings. Insurance companies, comprising life insurance, non-life insurance, and reinsurance business activities, along with the growing class of collective investment schemes, have become enormous sources of investment capital, deciding about their allocation—unfortunately not in the best interest of their contributors’ future, also because of increasingly comprehensive regulations.
Swiss Debt Markets
Authors: Meier Henri B. , Marthinsen John E. , Gantenbein Pascal A. , Weber Samuel S. 
Published: April 2023

AbstractThe stable Swiss franc currency, low-interest rates, high market liquidity, and long-term funding opportunities have made Swiss debt markets an attractive source of capital for borrowers, such as businesses, governments, and supranational organizations. The exceptionally well-developed long-term debt market has reduced the need for short-term financing and has proven highly resilient during times of turmoil. Today, Switzerland has a non-public borrowers’ market that is larger than the public borrowers’ segment, partly due to the federal debt brake. A distinctive feature is the Pfandbrief market which has remained loss-free during its 90-year history. While the share of foreign bonds has decreased over time, Sustainable Bonds, comprising Green Bonds, Social Bonds, and bonds linked to sustainability have emerged as a new important bond type.
Percolate: An Exponential Family JIVE Model to Design DNA-Based Predictors of Drug Response
Authors: Mourragui Soufiane M. C. , Loog Marco , van Nee Mirrelijn , de Wiel Mark A van , Reinders Marcel J. T. , Wessels Lodewyk F. A. 
Published: April 2023

AbstractMotivation: Anti-cancer drugs may elicit resistance or sensitivity through mechanisms which involve several genomic layers. Nevertheless, we have demonstrated that gene expression contains most of the predictive capacity compared to the remaining omic data types. Unfortunately, this comes at a price: gene expression biomarkers are often hard to interpret and show poor robustness.Results: To capture the best of both worlds, i.e. the accuracy of gene expression and the robustness of other genomic levels, such as mutations, copy-number or methylation, we developed Percolate, a computational approach which extracts the joint signal between gene expression and the other omic data types. We developed an out-of-sample extension of Percolate which allows predictions on unseen samples without the necessity to recompute the joint signal on all data. We employed Percolate to extract the joint signal between gene expression and either mutations, copy-number or methylation, and used the out-of sample extension to perform response prediction on unseen samples. We showed that the joint signal recapitulates, and sometimes exceeds, the predictive performance achieved with each data type individually. Importantly, molecular signatures created by Percolate do not require gene expression to be evaluated, rendering them suitable to clinical applications where only one data type is available.Availability: Percolate is available as a Python 3.7 package and the scripts to reproduce the results are available here.
Aspects of N-partite information in conformal field theories
Authors: Agón César A. , Bueno Pablo , Andino Oscar Lasso , López Alejandro Vilar 
Published: April 2023

Abstract
We present several new results for the N-partite information, IN, of spatial regions in the ground state of d-dimensional conformal field theories. First, we show that IN can be written in terms of a single N-point function of twist operators. Using this, we argue that in the limit in which all mutual separations are much greater than the regions sizes, the N-partite information scales as IN ~ r−2N∆, where r is the typical distance between pairs of regions and ∆ is the lowest primary scaling dimension. In the case of spherical entangling surfaces, we obtain a completely explicit formula for the I4 in terms of 2-, 3- and 4-point functions of the lowest-dimensional primary. Then, we consider a three- dimensional scalar field in the lattice. We verify the predicted long-distance scaling and provide strong evidence that IN is always positive for general regions and arbitrary N for that theory. For the I4, we find excellent numerical agreement between our general formula and the lattice result for disk regions. We also perform lattice calculations of the mutual information for more general regions and general separations both for a free scalar and a free fermion, and conjecture that, normalized by the corresponding disk entanglement entropy coefficients, the scalar result is always greater than the fermion one. Finally, we verify explicitly the equality between the N-partite information of bulk and boundary fields in holographic theories for spherical entangling surfaces in general dimensions.
Trends and Variations in Drain Use Following Pancreatoduodenectomy: Is Early Drain Removal Becoming More Common?
Authors: Sahara Kota , Ruff Samantha M. , Miyake Kentaro , Toyoda Junya , Yabushita Yasuhiro , Homma Yuki , Kumamoto Takafumi , Matsuyama Ryusei , Endo Itaru , Pawlik Timothy M. 
Published: April 2023

AbstractBackgroundAlthough previous studies have noted the potential benefit of early drain removal (EDR) after pancreatoduodenectomy (PD), there is a paucity of data on the timing of drain removal utilizing a national database that reflect the “real world” setting. Given the ongoing controversy related to PD drain use and management, we sought to define trends in drain use among a large national cohort, as well as identify factors associated with EDR following PD.MethodsThe ACS NSQIP targeted pancreatectomy database was used to identify patients who underwent PD between 2014 and 2020. The trend in proportion of patients with EDR (removal ≤ POD3) as well as predictors of EDR were assessed. Risk‐adjusted postoperative outcomes were evaluated by multivariable regression analysis.ResultsAmong 14,356 patients, 16.2% of patients (N = 2324) experienced EDR, and the proportion of patients with EDR increased by 68% over the study period (2014: 10.9% vs. 2020: 18.3%, p < 0.001). Higher drain fluid amylase on POD1‐3 [LogWorth (LW) = 44.3], operative time (LW = 33.2), and use of minimally invasive surgery (LW = 14.0) were associated with EDR. Additionally, EDR was associated with decreased risk of overall and serious morbidity, PD‐related morbidity (e.g., pancreatic fistula), reoperation, prolonged length of stay and readmission (all p < 0.05).ConclusionsRoutine drain placement remains a common practice among most surgeons. EDR following PD increased over time was associated with lower post‐operative complications and shorter LOS. Despite evidence that EDR was safe and may even be associated with lower complications, only 1 in 6 patients were managed with EDR.
Effect of intraperitoneal infusion of ropivacaine combined with dexmedetomidine in patients undergoing total laparoscopic hysterectomy: a single-center randomized double-blinded controlled trial
Authors: Miao Liyan , Chen Qiuchun , Wang Yuping , Wang Denggui , Zhou Min 
Published: April 2023

Abstract
Purpose
To investigate the effect of intraperitoneal infusion of ropivacaine combined with dexmedetomidine and ropivacaine alone on the quality of postoperative recovery of patients undergoing total laparoscopic hysterectomy (TLH).

Methods
Female patients scheduled to undergo a TLH under general anesthesia at Fujian Maternity and Child Health Hospital were included. Before the end of pneumoperitoneum, patients were laparoscopically administered an intraperitoneal infusion of 0.25% ropivacaine 40 ml (R group) or 0.25% ropivacaine combined with 1 µg/kg dexmedetomidine 40 ml (RD group). The primary outcome was QoR-40, which was assessed before surgery and 24 h after surgery. Secondary outcomes included postoperative NRS scores, postoperative anesthetic dosage, the time to ambulation, urinary catheter removal, and anal exhaust. The incidence of dizziness, nausea, and vomiting was also analyzed.

Results
A total of 109 women were recruited. The RD group had higher QoR scores than the R group at 24 h after surgery (p < 0.05). Compared with the R group, NRS scores in the RD group decreased at 2, 6, 12, and 24 h after surgery (all p < 0.05). In the RD group, the time to the first dosage of postoperative opioid was longer and the cumulative and effective times of PCA compression were less than those in the R group (all p < 0.05). Simultaneously, the time to ambulation (p = 0.033), anal exhaust (p = 0.002), and urethral catheter removal (p = 0.018) was shortened in the RD group. The RD group had a lower incidence of dizziness, nausea, and vomiting (p < 0.05).

Conclusion
Intraperitoneal infusion of ropivacaine combined with dexmedetomidine improved the quality of recovery in patients undergoing TLH.

Trial registration
ChiCTR2000033209, Registration Date: May 24, 2020.
Long-term outcome after decompressive hemicraniectomy for malignant middle cerebral artery infarction
Authors: Berger Natalie , Brunner Anna , Wünsch Gerit , Nistl Oliver , Pinter Daniela , Fandler-Höfler Simon , Haidegger Melanie , Pichler Alexander , Hatab Isra , Mokry Michael , Wolfsberger Stefan , Enzinger Christian , Gattringer Thomas , Kneihsl Markus 
Published: April 2023

Abstract
Background
Although decompressive hemicraniectomy (DHC) is a lifesaving treatment strategy for patients with malignant middle cerebral artery infarction (mMCAi), only one in four patients achieves low to moderate post-stroke disability according to previous studies. However, the short follow-up periods in prior studies could have overestimated the poor clinical prognosis. This study therefore examined the long-term outcome after DHC for mMCAi.

Methods
We retrospectively included all patients who had undergone DHC after mMCAi at the University Hospital Graz between 2006 and 2019. Demographics, clinical data and complications were collected from electronic clinical patient records. To investigate long-term prognosis, all patients were followed up to 14 years after stroke including quality of life (QOL) assessment. Post-stroke disability was rated according to the modified Rankin Scale (mRS).

Results
Of 47 patients that had undergone DHC for mMCAi, follow-up data were available in 40 patients (mean age: 48 years; 40% female). Six months after the mMCAi, 14 patients had died (35%) and nine (23%) had a low to moderate post-stroke disability (mRS 0–3). Of 26 stroke survivors, half (50%) showed further mRS improvement (≥ 1 point) during the long-term follow-up period (mean follow-up time: 8 years). At last follow-up, 17 patients had achieved an mRS score of ≤ 3 (65% versus 35% after 6 months; p = 0.008) and 55% had no signs of depression and anxiety, and 50% no signs of pain or discomfort in QOL assessment.

Conclusion
This study shows substantial long-term improvement of functional disability and reasonable QOL in mMCAi patients after DHC.
Impact of antigen retrieval protocols on the immunohistochemical detection of epigenetic DNA modifications
Authors: Moshi Jobran M. , Ummelen Monique , Broers Jos L. V. , Ramaekers Frans C. S. , Hopman Anton H. N. 
Published: April 2023

AbstractThis study compares three different pretreatment protocols for the immunohistochemical detection of 5-methylcytosine (5-mC) and 5-hydroxymethylcytosine (5-hmC) in nuclear DNA. The human biological samples analyzed included formalin-fixed and paraffin-embedded (FFPE) normal squamous epithelium, ethanol-fixed cultured cells, and metaphase chromosomes. The antigen retrieval methods included low pH Citrate and high pH Tris–ethylenediaminetetraacetic acid (EDTA) protocols, as well as a method using Pepsin pretreatment combined with HCl for DNA denaturation. A gradual increase in the detection levels of 5-mC and 5-hmC was observed when going from Citrate via Tris/EDTA to Pepsin/HCl retrieval. While the Citrate retrieval protocol was the least efficient for the detection of 5-mC and 5-hmC, it did preserve nuclear morphology and enabled visualization of differences in intra- and internuclear distribution patterns in tissue and cell culture samples by single- and double-fluorescence detection. Quantification of (hydroxy)methylation levels in FFPE material demonstrated a significant heterogeneity and differences in 5-mC and 5-hmC levels within and between nuclei in the different compartments of normal squamous epithelium. It was concluded that immunohistochemical detection of 5-mC and 5-hmC enables the correlation of these DNA modifications with histomorphological features in heterogeneous tissues, but this is influenced by different pretreatment protocols that must be carefully chosen to allow an appropriate interpretation of these epigenetic switches.
Data-based localisation methods using simulated data with application to small-scale structures
Authors: Scholl Manuel , Passek Matthias , Lainer Mirjam , Taddei Francesca , Schneider Felix , Müller Gerhard 
Published: April 2023

AbstractSeveral methods to localise sources of vibrations have been established in the literature. A great amount of those methods are based on databases with features of known impact positions. Great effort needs to be put into highly expensive experiments that deliver those databases. In this paper, we propose several simulation techniques that may replace the expensive experiments for source localisation. The paper compares the localisation accuracy of simulated and experimental data for two different localisation approaches, the reference database method and neural networks. Both methods process signal arrival time differences from several positions on the structure. The methods are exemplarily applied to a complex small-scale structure from the automotive industry: The small dimensions of the brake disk hat and the inclusion of holes is a challenging task for the accuracy of the applied localisation techniques. Results show that simulated data can replace experimentally gained data well in case of the reference database method, whereas the neuronal networks approach should stick to experimentally gained data. The evaluations show that, despite the small dimension, the relative localisation accuracy is within accepted ranges of literature.
Oculocutaneous albinism: the neurological, behavioral, and neuro-ophthalmological perspective
Authors: Galli Jessica , Loi Erika , Dusi Laura , Pasini Nadia , Rossi Andrea , Scaglioni Vera , Mauri Lucia , Fazzi Elisa 
Published: April 2023

AbstractOculocutaneous albinism (OCA) is a group of rare, genetic disorders caused by absent/reduced melanin biosynthesis. The aim of this study was to explore the neurovisual, cognitive, adaptive, and behavioral profile of children affected by OCA, also evaluating any possible effect of the visual acuity deficit on the clinical profile and genotype–phenotype correlations. Eighteen children (9 males, mean age 84 months ± 41; range 18–181 months) with a molecular confirmed diagnosis of OCA were enrolled in the study. We collected data on clinical history, neurodevelopmental profile, neurological and neurovisual examination, and cognitive, adaptive, and emotional/behavioral functioning. A global neurodevelopmental impairment was detected in 56% of the children, without evolving into an intellectual disability. All the patients showed signs and symptoms of visual impairment. Low adaptive functioning was observed in 3 cases (17%). A risk for internalizing behavioral problems was documented in 6 cases (33%), for externalizing problems in 2 (11%), and for both in 5 (28%). Twelve children (67%) showed one or more autistic-like features. Correlation analyses revealed significant associations between the visual acuity level and performance intelligence quotient (p = 0.001), processing speed index (p = 0.021), Vineland total score (p = 0.020), Vineland communication (p = 0.020), and socialization (p = 0.037) domains. No significant correlations were found between genotype and phenotype.Conclusion: Children with OCA may present a global neurodevelopmental delay that seems to improve with age and emotional/behavioral difficulties, along with the well-known visual impairment. An early neuropsychiatric evaluation and habilitative training are recommended to improve vision-related performance, neurodevelopment, and any psychological difficulties.

What is Known:• Children with oculocutaneous albinism show dermatological and ophthalmological problems.• An early visual impairment may have negative implications on motor, emotional, and cognitive processes that would allow the child to organize his or her experiences.

What is New:• In addition to a variable combination of ocular signs and symptoms, children with oculocutaneous albinism may present an early neurodevelopmental delay and emotional/behavioral difficulties.• An early visual treatment is recommended to improve vision-related performance,
neurodevelopment, and any psychological difficulties.