bluuebunny/crossref_metadata_2025_split huggingface dataset:
KUTADGU BİLİG’DE İKİNCİL EDATLAR
Authors: CAN Meltem 
Published: July 2023

Dil, insanlık tarihinin en eski olgularından biridir. Dilin ne olduğu ve nasıl çalıştığı insanlık tarihi
boyunca merak konusu olmuş, buna yönelik çalışmalar gerek dolaylı gerek doğrudan günümüze kadar devam
etmiştir. Bu çalışmalar süreç boyunca aynı zamanda birtakım problemlerle karşılaşmıştır. Problemlerin kimi
çözüme ulaşmışken, kimi hâlâ çözüm beklemektedir. Bu bağlamda Türk diliyle ilgili çalışmalara bakıldığında,
çalışmaların problemlerinden birinin edat gibi kullanıldığı hâlde aslında edat olmayan, hangi sözcük kategorisi
adı altında değerlendirilmesi gerektiğiyle ilgili çokça soru işareti barındıran, üzerinde oldukça sık tartışılan,
farklı ifadelerle açıklamaya çalışılan, ancak şimdiye kadar kabul edilebilir bir kavram alanı ve terimle
karşılanamayan ikincil edat kategorisidir. Bu çalışma üç bölümden oluşmuştur. İlk bölümde dilbilim tarihi
çalışmalarının genel problemleri üzerinde durulmuştur. İkinci bölümde edat ve ikincil edat kategorileri
dilbilgiselleşme çerçevesinde değerlendirilmiştir. Üçüncü bölümde ise ikincil edat kullanımları Türk dili
tarihinin en önemli eserlerinden olan Kutadgu Bilig’de incelenmiş, buna göre adın, basa, naru, oza, okşaġ, öŋ,
teg, utru birimlerinin ikincil edat kullanımları belirlenmiştir.
Deep graph neural network with fish-inspired task allocation algorithm for heart disease diagnosis
Authors: Krishna Lava Kumar Gopu  , Suthendran Kannan  
Published: July 2023

Heart disease is a very hazardous disease and many people suffered from this disease globally. The major aim is “to diagnose the heart disease with higher accuracy through decreasing error rate including computational complexity”. The existing techniques did not proffer adequate accuracy and also increased the error rate. Therefore, a Deep Graph Neural Network with Fish-Inspired Task Allocation Algorithm is proposed in this manuscript for categorizing heart disease diagnosis (DGNN-FITA-HDD). Synthetic Minority Oversampling and standard scalar strategies are utilized for pre-processing process. The pre-processed output is given to feature selection process. Two-Stage Feature Selection method selects the most important features from pre-processing output. Extracted features are transferred to Deep Graph Neural Network (DGNN) for categorizing presence and absence of heart disease. DGNN does not expose any adoption of optimization strategies for calculating the optimum parameters to assure accurate prediction. Fish-Inspired Task Allocation approach is proposed for optimizing the weight parameters of DGNN. The proposed approach is executed at MATLAB. The performance of algorithm is analyzed with/without feature selection method. By this, the proposed DGNN-FITA-HDD method attains higher accuracy with feature selection of 13.41%, 18.53%, 10.38% and 9.31% and without feature selection attains 6.5%, 8.64%, 4.39%, and 10.28% compared with existing methods, like EDGA-AHHO-HDD, XGB-MAPO-HDD, AGAFL-HDD and RFBM-HDD respectively.
A Dual‐Functional Electrolyte Additive for High‐Performance Potassium Metal Batteries
Authors: Park Jimin , Jeong Yeseul , Kang Hyokyeong , Yu Tae‐Yeon , Xu Xieyu , Liu Yangyang , Xiong Shizao , Lee Seon Hwa , Sun Yang‐Kook , Hwang Jang‐Yeon 
Published: July 2023

AbstractPotassium metal batteries (KMBs) coupled with layered transition metal oxides as cathode materials are a promising energy−storage technology owing to low cost and high capacity. However, uncontrollable dendritic growth in the K−metal anode and chemical reactivity of the layered transition metal oxide cathode against the electrolyte solution cause KMBs to suffer from low Coulombic efficiency, rapid capacity fading, and critical safety issues. In this study, an electrolyte engineering strategy is introduced by introducing adiponitrile (ADN) as a dual−functional electrolyte additive containing an electron−rich nitrile group (C≡N) in its molecule structure. Thus, the addition of 1 wt.% ADN can alter the chemical properties of the electrolyte solution, thereby improving the anode−electrolyte and cathode−electrolyte interfacial stabilities in KMBs. The formation of a potassiophilic compound with C≡N in the solid electrolyte interphase layer can guide the uniform electrodeposition of K and suppress the dendritic growth in the K−metal. Moreover, C≡N forms a strong coordination bond with the oxidized transition metal, leading the reversible redox reactions by mitigating the undesirable disproportionation reaction and improving the thermal stability of the layered transition metal oxide cathode. Computational calculations and experimental characterizations are used to verify the role of ADN additive in enhancing the electrochemical properties of KMBs.
Novel bisphosphonates via castor oil
Authors: Fayer Effrat L. , Rosen Emily , Cermak Diana M. , Cermak Steven C. 
Published: July 2023

AbstractHydroxy fatty acids (HFAs) have long been a staple component of feedstock oils with uses ranging from motor oils to food to pharmaceuticals. Castor oil, which contains the HFA ricinoleic acid as its principal component, is the most widely used source of HFA in the world. In addition, bisphosphonates are a functional moiety that has been shown to display a variety of industrial applications, ranging from use in water softeners to osteoporosis drugs, primarily due to their affinity for the calcium ion. We have long been interested in the modification of ricinoleic acid from castor oil to phosphorus derivatives, including α‐hydroxy phosphonates and phosphonic acids, and have now accomplished the synthesis of a family of ricinoleic‐derived bisphosphonates: one that retains the cis alkene found in ricinoleic acid and one where the alkene has undergone hydrogenation. These compounds have been produced in high yields and high purity and the synthesis of these compounds is reported.
Fabrication of polycaprolactone scaffolds filled with cell‐compatible porous matrix for enhanced cell growth for biomedical applications
Authors: Hsu Chih‐Chin , Hsu Chen‐Chih , Lin Che‐Min , Wang Da‐Ming , Hsieh Hsyue‐Jen 
Published: July 2023

AbstractIn this study, polycaprolactone (P) scaffolds are fabricated by 3D‐printing method, and subsequently a mixed solution of natural‐biocompatible chitosan (C), gelatin (G), and hydroxyapatite (H) is filled into the pores of P scaffolds. Freeze‐gelation method is then carried out to successfully form a cell‐compatible porous CGH matrix within P scaffold pores, obtaining a newly fabricated scaffold called CGH/P composite scaffold which has large specific surface area favorable for cell attachment and growth. The effects of slow cooling (sc) and fast cooling (fc) modes utilized in freeze process on pore structures of CGH matrix are observed via SEM. The use of fc mode creates a CGH matrix with a laminar structure which benefits nutrient permeation and cell migration. Mechanical properties tests indicate that the maximum compressive strength and Young's modulus of CGH/P‐fc scaffolds are 2–7 and 15–35 MPa, respectively. Cell compatibility tests show that on day 7, the cell numbers in the CGH/P‐fc scaffolds are about twofold of those in the P scaffolds, and the cell activities in the CGH/P‐fc scaffolds are even higher, indicating that the presence of laminar porous CGH matrix within P scaffold pores substantially enhances the migration, attachment, and growth of cells in the scaffolds. The results suggest that the fabricated CGH/P‐fc composite scaffold is highly promising for biomedical applications such as bone repair in the future.
Evaluation of psychometric properties of the Dental Anxiety Inventory (DAI‐36) questionnaire using iterative hybrid ordinal logistic: Differential item functioning (DIF)
Authors: Roustaei Narges , Allahyari Elahe 
Published: July 2023

AbstractObjectivesDental Anxiety Inventory (DAI‐36) questionnaire is an instrument for assessing dental anxiety. The different perceptions of the questionnaire items in the individual at the same level of underlying dental anxiety may lead to different reported dental anxieties. This study aims to determine the differential item functioning (DIF) of the DAI‐36 measure items.MethodsThe DAI‐36 was completed by 950 participants. An iterative hybrid ordinal logistic regression model was used to detect DIF across gender, education, and age groups. DIF analysis was done by lordif package in R3.1.3 software.ResultsThe chi‐square statistics declared 7, 7, and 4 nonuniform DIF items, and 2, 5, and 4 uniform DIF items across gender, education, and age groups, respectively. ΔR2 was always lower than 0.07 in all uniform and nonuniform DIF items. However, Δβ1 revealed significant uniform DIF in items 1 and 8 across gender (Δβ1(item 1) = 0.0137, Δβ1(item 8) = 0.0124) and items 22 and 27 across age categories (Δβ1(item 22) = 0.0110, Δβ1(item 27) = 0.0136).ConclusionsDIF items had no large magnitude or cancel out each other, so statements phrased in the DAI‐36 questionnaire have equivalent meaning across participants, regardless of their gender, education, and age groups.
Seborrheic keratosis in an adolescent: A rare presentation
Authors: Zare Pooria , Ramezani Mazaher 
Published: July 2023

Key Clinical MessageSeborrheic keratosis is a common benign epidermal lesion that typically occurs in the elderly population. Its occurrence in childhood and adolescence is rare and can pose a diagnostic challenge for clinicians and dermatopathologists. We report a case of a 16‐year‐old boy with multiple brown, black oval‐shaped stuck‐on lesions on his face, which were diagnosed as seborrheic keratosis based on histological findings. The patient had no significant medical history or family history of seborrheic keratosis. In this report, we discuss the differential diagnoses of seborrheic keratosis‐like lesions in childhood and adolescence and explain why they were not compatible with our case. We also review the available treatment options. Our case emphasizes the need for dermatologists to consider seborrheic keratosis in the differential diagnosis of cutaneous lesions in young patients.
Recent Advances in Nickel‐Catalyzed Synthesis of Allenes: New Insights and Perspectives
Authors: Liu Xiaopan , Jiao Chenchen , Cui Shilin , Liu Qingfeng , Zhang Xingjie , Zhang Guisheng 
Published: July 2023

AbstractAllenes are one of the most important functional groups in organic chemistry, featuring unique physical and chemical properties. They are not only the key scaffolds present in natural products, pharmaceutical molecules, and advanced functional materials, but also the valuable and versatile building blocks for the construction of various complex and bioactive molecules in organic synthesis. Accordingly, benefiting from the rapid development of transition metal catalysis, numerous remarkable and efficient approaches for the synthesis of allenes from readily available chemicals have been established in the past decades. In this brief review, we focus on the recent advancements in nickel‐catalyzed synthesis of allenes. These transformations are divided into two categories according to the types of reactions and sorted further by starting materials. Moreover, a concise discussion of the limitations and potential areas of improvement in this field is also provided, which would give an inspiration for future study on allene synthesis.
The study of color as a component of urban cultural construction: A theoretical reflection and methodological proposal
Authors: Odetti Jimena Vanina 
Published: July 2023

AbstractThis article presents a theoretical reflection and a methodological proposal for the study of urban color as an element of experience and urban cultural construction. The purpose is to propose a methodology based on the analysis of the relationships between the objective and subjective aspects of color in the city. To this end, we aim to understand the objective visual perceptions and relate them to the subjective associations that the inhabitants identify from the urban experience. Additionally, a methodological crossover is carried out that considers the study of urban color from the perceptual and objective analysis of color with the methodologies of imaginaries and urban anthropology. Thus, the proposed chromatic approach links the objective and subjective aspects of color with the tangible and intangible elements of the city. By so doing, this article underlines how the results are not limited to the objective terms of the study of urban color but are enriched by the identification of subjective aspects, such as the analysis of the historical and social contexts in which the colors were chosen, as well as the perceptions that their inhabitants have about them. This research aims to deepen and broaden the view of a city from a chromatic study's perspective. The conclusions invite us to make a reading of the representations and perceptions of the inhabitants of a city who, through the questioning of color, can express their needs, desires and emotions for the place they inhabit and thus transmit a particular cultural construction of the city.
Human activities modulate reciprocal effects of a subterranean ecological engineer rodent, Tachyoryctes macrocephalus, on Afroalpine vegetation cover
Authors: Asefa Addisu , Reuber Victoria , Miehe Georg , Wraase Luise , Wube Tilaye , Schabo Dana G. , Farwig Nina 
Published: July 2023

AbstractHuman activities, directly and indirectly, impact ecological engineering activities of subterranean rodents. As engineering activities of burrowing rodents are affected by, and reciprocally affect vegetation cover via feeding, burrowing and mound building, human influence such as settlements and livestock grazing, could have cascading effects on biodiversity and ecosystem processes such as bioturbation. However, there is limited understanding of the relationship between human activities and burrowing rodents. The aim of this study was therefore to understand how human activities influence the ecological engineering activity of the giant root‐rat (Tachyoryctes macrocephalus), a subterranean rodent species endemic to the Afroalpine ecosystem of the Bale Mountains of Ethiopia. We collected data on human impact, burrowing activity and vegetation during February and March of 2021. Using path analysis, we tested (1) direct effects of human settlement on the patterns of livestock grazing intensity, (2) direct and indirect impacts of humans and livestock grazing intensity on the root‐rat burrow density and (3) whether human settlement and livestock grazing influence the effects of giant root‐rat burrow density on vegetation and vice versa. We found lower levels of livestock grazing intensity further from human settlement than in its proximity. We also found a significantly increased giant root‐rat burrow density with increasing livestock grazing intensity. Seasonal settlement and livestock grazing intensity had an indirect negative and positive effect on giant root‐rat burrow density, respectively, both via vegetation cover. Analysing the reciprocal effects of giant root‐rat on vegetation, we found a significantly decreased vegetation cover with increasing density of giant root‐rat burrows, and indirectly with increasing livestock grazing intensity via giant root‐rat burrow density. Our results demonstrate that giant root‐rats play a synanthropic engineering role that affects vegetation structure and ecosystem processes.
Building better solid‐state batteries with silicon‐based anodes
Authors: Sun Zhefei , Yin Quanzhi , Chen Haoyu , Li Miao , Zhou Shenghui , Wen Sifan , Pan Jianhai , Zheng Qizheng , Jiang Bing , Liu Haodong , Kim Kangwoon , Li Jie , Han Xiang , He Yan‐Bing , Zhang Li , Li Meicheng , Zhang Qiaobao 
Published: July 2023

AbstractSilicon (Si)‐based solid‐state batteries (Si‐SSBs) are attracting tremendous attention because of their high energy density and unprecedented safety, making them become promising candidates for next‐generation energy storage systems. Nevertheless, the commercialization of Si‐SSBs is significantly impeded by enormous challenges including large volume variation, severe interfacial problems, elusive fundamental mechanisms, and unsatisfied electrochemical performance. Besides, some unknown electrochemical processes in Si‐based anode, solid‐state electrolytes (SSEs), and Si‐based anode/SSE interfaces are still needed to be explored, while an in‐depth understanding of solid–solid interfacial chemistry is insufficient in Si‐SSBs. This review aims to summarize the current scientific and technological advances and insights into tackling challenges to promote the deployment of Si‐SSBs. First, the differences between various conventional liquid electrolyte‐dominated Si‐based lithium‐ion batteries (LIBs) with Si‐SSBs are discussed. Subsequently, the interfacial mechanical contact model, chemical reaction properties, and charge transfer kinetics (mechanical–chemical kinetics) between Si‐based anode and three different SSEs (inorganic (oxides) SSEs, organic–inorganic composite SSEs, and inorganic (sulfides) SSEs) are systemically reviewed, respectively. Moreover, the progress for promising inorganic (sulfides) SSE‐based Si‐SSBs on the aspects of electrode constitution, three‐dimensional structured electrodes, and external stack pressure is highlighted, respectively. Finally, future research directions and prospects in the development of Si‐SSBs are proposed.
Incidence of client‐initiated workplace violence among counselors: A national study
Authors: Kempf Janet Kathleen , Laux John M. , Dari Tahani , Fox Christine M. 
Published: July 2023

AbstractWorkplace violence (WPV) is a global concern and consists of psychological and physical threats or acts. To date, limited data exist to document client‐initiated WPV experienced by professional counselors. Survey results from 2616 counselors in 12 states indicate that most counselors have no memory of WPV training from their counselor education programs. Over 75% of the sample experienced WPV. Counselors experience psychological forms of WPV at greater rates than physical forms. Over half of WPV experiences occurred during participants’ graduate training and in the first 4 years of their professional practice. WPV occurs in all locations where counselors work. WPV's consequences differ, ranging from none to career ending disruptions. Counselors’ responses varied, including no action or responses, seeking support from supervisors, professional peers, and family members, and engaging in medical and/or mental health services. Suggestions for practice, training, and future research are offered.
Surgical Outcomes by Early Airway Endoscopy Findings after Pediatric Staged Laryngotracheoplasty
Authors: Dabbous Helene , Chorney Stephen R. , Johnson Romaine F. , Kou Yann‐Fuu 
Published: July 2023

ObjectivesTo determine how initial postoperative airway endoscopy findings after stent removal predict successful decannulation in children undergoing double‐staged laryngotracheoplasty (dsLTP). Secondary objectives assessed timing of decannulation and number of endoscopic interventions needed after dsLTP.MethodsA case series with chart review included children who underwent dsLTP at a tertiary children's hospital between 2008 and 2021. Rates of decannulation, time to decannulation, and number of interventions after dsLTP were recorded for children with high‐ or low‐grade stenosis at the first bronchoscopy after stent removal.ResultsOf the 65 children who were included, 88% had high‐grade stenosis and 98% had a preoperative tracheostomy. Successful decannulation happened in 74% of the children, and 44% of the children were decannulated within 12 months of surgery. For children with low‐grade stenosis at the first endoscopy after stent removal, 84% were successfully decannulated compared with 36% of the children with high‐grade stenosis (p = 0.001). After dsLTP, children with high‐grade stenosis required 7.5 interventions (SD: 3.3) compared with 4.0 interventions (SD: 3.0) for children with low‐grade stenosis (p < 0.001). Decannulated children with high‐grade stenosis necessitated more endoscopic procedures (7.0 vs. 3.7, p = 0.02). Time to decannulation was similar between children with high‐ and low‐grade early postoperative stenosis (21.9 vs. 17.8 months, p = 0.63).ConclusionsHigher grade stenosis identified on the first airway endoscopy after suprastomal stent removal is correlated with lower decannulation rates and more postoperative endoscopic interventions. Although time to decannulation was not impacted by early stenosis grade, surgeons might utilize these early airway findings to counsel families and prognosticate possible surgical success.Level of Evidence4 Laryngoscope, 134:963–967, 2024
Children's Oncology Group's 2023 blueprint for research: Neuroblastoma
Authors: Bagatell Rochelle , DuBois Steven G. , Naranjo Arlene , Belle Jen , Goldsmith Kelly C. , Park Julie R. , Irwin Meredith S. ,   the COG Neuroblastoma Committee
Published: July 2023

AbstractNeuroblastoma is the most common extra‐cranial solid tumor in children and is known for its clinical heterogeneity. A greater understanding of the biology of this disease has led to both improved risk stratification and new approaches to therapy. Outcomes for children with low and intermediate risk disease are excellent overall, and efforts to decrease therapy for such patients have been largely successful. Although survival has improved over time for patients with high‐risk disease and treatments evaluated in the relapse setting are now being moved into earlier phases of treatment, much work remains to improve survival and decrease therapy‐related toxicities. Studies of highly annotated biobanked samples continue to lead to important insights regarding neuroblastoma biology. Such studies, along with correlative biology studies incorporated into therapeutic trials, are expected to continue to provide insights that lead to new and more effective therapies. A focus on translational science is accompanied by an emphasis on new agent development, optimized risk stratification, and international collaboration to address questions relevant to molecularly defined subsets of patients. In addition, the COG Neuroblastoma Committee is committed to addressing the patient/family experience, mitigating late effects of therapy, and studying social determinants of health in patients with neuroblastoma.
Application of a structural monitoring on segmental tunnel linings
Authors: Rauch Fabian , Fischer Oliver 
Published: July 2023

AbstractThe prediction of the structural behavior and the internal forces acting in segmental tunnel linings is a difficult task and contains uncertainties. In situ measurements within structural monitoring are the only possibility to assess the results under realistic boundary conditions. However, no standardized structural monitoring method for segmented lining exists and consequentially setting up a new monitoring project requires an increased effort. Therefore, in this paper, first, an analysis of experiences in reported monitoring projects is done. Then, a report on a current monitoring project carried out by the authors and the experiences made are presented. Based on these, suggestions are given to facilitate future applications of structural monitoring on segmental tunnel linings regarding conceptualization, instrumentation, installation, operation, and data evaluation.