bluuebunny/crossref_metadata_2025_split huggingface dataset:
One Pot Synthesis of Oximes from Carbonyl Compounds Catalysed by Vanadium(
V) Complex
Authors: Kurbah Sunshine Dominic 
Published: January 2023

Background:
An eco-friendly catalyst was synthesized in good yield and characterized by various physicochemical techniques. The catalytic performance of the environmentally benign complex was investigated via slurry synthesis of oximes. The catalytic studies were successfully carried out using a simple protocol. The fascinating advantage of this protocol is cost effectiveness, simple work up, good yield, short reactions time, and milder reaction conditions.

Methods:
The complex was prepared by reaction of vanadium pentoxide with hydrazone ligand in 1:1 molar ratios, and to this reaction mixture, potassium carbonate (0.14 g, 1 mmol) was added and ground till fine yellow colour powder appeared. Oximations were carried out by reacting the substrates, 15 % H2O2, ammonia and vanadium(V) complex. The reaction was taken in a mortar and ground till a fine powder appeared. After completion of the reaction, the crude product was extracted using dichloromethane/water in 1:2, v/v, evaporated and dried under vacuum.

Results:
We synthesized different varieties of oximes using our newly synthesized complex as a catalyst. The products were characterized by 1H NMR and 13C NMR spectroscopy. The completion of the reaction was monitored by checking the complete disappearance of the aldehyde proton and the appearance of oxime protons. We also grew some single crystals of the products to provide further supporting evidences about the formation of products.

Conclusion:
Oximation of various carbonyl compounds was prepared quantitatively under the slurry condition, using {[K(H¬2O)3][V(O)2L]}2 as a catalyst. The catalytic reactions can be carried out under mild conditions, with ease of scalability, and straightforward work-up procedure, which makes the present protocols greener and better alternative methods for the synthesis of oximes.
Performasi Metode Algoritma First Maximum Expansion pada Penjadwalan Kanal Uplink untuk Long Term Evolution
Authors: Purnomo Muhammad Fauzan Edy , Purnomowati Endah Budi , Iswara Wanaputri 
Published: January 2023

LTE adalah salah satu jaringan telekomunikasi yang memiliki keunggulan utama berupa data rate yang tinggi, karena keunggulan tersebut membuat jaringan ini menjadi salah satu jaringan yang paling banyak digunakan. ini menimbulkan permasalahan baru dimana sumber daya radio harus digunakan seefektifÂ dan seefisien mungkin untuk memberikan pelayanan yang terbaik. Pelayanan yang dimaksud adalah alokasi sumber daya radio berupa resource block kepada user aktif. Proses alokasi ini disebut dengan penjadwalan/scheduling, dan dibutuhkan sebuah algoritma untuk menjalankan penjadwalan tersebut. Penjadwalan yang digunakan pada penelitian kali ini yaitu First Maximum Expansion (FME) untuk parameter uji BER, throughput, dan fairness.Â Penelitian ini dilakukaan dengan proses simulasi pada skenario single cell pada dua kondisi yaitu LOS dan NLOS, dan juga menggunakan 4 skenario dengan pengaruh variasi jarak dan jumlah user. Saat menggunakan algoritma FME didapatkan hasil fairness yang sangat bagus di tiap skenarionya pada variasi jumlah user dan jarak user terhadap eNodeB, hasil yang didapatkan sekitar 0,96-0,99 yang sangat mendekati angka 1 yang mengartikan bahwa nilai fairness index pada algoritma ini sangat baik. Sedangkan untuk hasil BER dan throughput cukup bervariatif untuk variasi jumlah user dan jarak user terhadap eNodeB. Variasi jumlah user menyebabkan nilai BER dan throughput cenderung tetap seiring bertambahnya jumlah user. Variasi jarak user mempunyai pengaruh secara langsung terhadap nilai BER dan berpengaruh secara tidak langsung terhadap nilai throughput.
Perancangan Awal Dual Axis Solar Tracking System dengan Penambahan Reflektor dan Water Treatment
Authors: Halim Levin , Wiharja Alvin Rinaldi 
Published: January 2023

Energi terbarukan didapat dengan memanfaatkan sumber energi dari alam yang tidak akan habis jika digunakan terus-menerus. Salah satu energi terbarukan adalah energi matahari, dan salah satu cara untuk memanfaatkannya dibutuhkan sebuah alat yang dapat mengubah energi matahari menjadi energi listrik, yaitu panel surya. Pada penelitian ini, dibuat rancangan awal dual axis solar tracking system atau sistem penjejak matahari dengan metode fuzzy logic dan penambahan reflektor serta water treatment. Rancangan yang dibuat pada penelitian kali ini berupa desain CAD menggunakan software SolidWorks. Semua rancangan yang dibuat, diambil dari beberapa referensi yang digabungkan, sedangkan parameter yang digunakan hanya besar sudut atara reflektor dan panel surya.
Refusal of Retreatment With Topical 5-Fluorouracil Among Patients With Actinic Keratosis: Qualitative Analysis
Authors: Singh Rohan , McCain Sarah , Feldman Steven R 
Published: January 2023

Background
Actinic keratosis (AK) is a common premalignant skin lesion, and topical 5-fluorouracil (5-FU) is commonly used in field-directed therapy. However, 5-FU is associated with frequent local skin reactions.

Objective
This study aimed to qualitatively assess experiences among patients with AK who refuse retreatment with 5-FU.

Methods
Semistructured interviews were conducted with 10 adult participants who had received treatment with 5-FU for AK between January 1, 2017, and January 1, 2020, and refused future treatment with 5-FU. Results were analyzed using qualitative research methods.

Results
Although most participants had low concern upon having received a diagnosis of AK, most felt that treatment is very important. When initiating treatment with 5-FU, most cited recommendation by their health care professionals as the primary motivator and initially had low concern regarding treatment. The side effects associated with treatment were physically and psychosocially burdensome for most participants and led to temporary lifestyle adjustments. After treatment, most did not believe that their health care provider prepared them for treatment or were unsure. While half of the participants felt that 5-FU helped treat AKs, half were either unsure, due to premature discontinuation, or did not think that 5-FU treated their AKs.

Conclusions
5-FU is one of the most commonly prescribed treatments for AKs, yet most patients experienced both a physical and psychosocial burden with the treatment. Inability to assess efficacy due to premature discontinuation secondary to 5-FU–related reactions is common, and shared decision-making, navigating treatment options, and taking into account patient preferences may be critical to help assure better adherence and outcomes. Although our study was limited by input from participants who refused future treatment with 5-FU, most stated that they would still continue to seek treatment for AKs in the future and would consider other topical treatments, especially if associated with a milder tolerability profile.
Conservation Environmental Sustainability in The Perspective of Islamic Legal Philosophy
Authors: Munib Munib , Patrajaya Rafik , Ihsan Reza Noor , Amin Muhammad 
Published: January 2023

This paper is motivated by the existence of central issues regarding environmental damage that are increasingly concerning, both those reported through the mass media and those circulating on national and international television broadcasts. Therefore, it is necessary to have a solution for handling and to bridge environmental issues studied across various disciplines of knowledge, in this case, using an Islamic legal philosophy approach. This research method is a normative legal study using the perspective of Islamic legal philosophy. This study indicates that religion has tended to focus more on matters of ritual aspects without looking further at the meanings of the symbols of religious teachings themselves, particularly if they are associated with awareness to conserve the environment adequately because it involves the benefit of many people. This paper aims to reveal the sides of religious teachings, especially Islamic teachings that raise awareness of the environment. Because in Islamic doctrine, it is taught about how to behave by values or norms concerning human relations with the universe (hablu minal 'alam). The philosophical view of Islamic law is that humans are essentially entrusted with managing the planet and its contents as caliphs on earth, particularly in maintaining and managing the natural resources in a trustworthy manner to avoid mafsadah (damage) that threatens all human life. The findings of this study indicate that the Islamic legal philosophy provides a living guide for how to treat the environment in both peaceful and emergency situations. This can be accomplished by not destroying plants (trees), not throwing dirt anywhere, managing the land to be productive, removing obstacles in the flow of people's movement, and sharing responsibility for sustainably managing forests, water, and energy.
Substitute Heirs in the Compilation of Islamic Law: An Overview from Gender Equality Perspective Case Study of the Religious Courts in Banjarmasin
Authors: Ideham Wahidah 
Published: January 2023

The enactment of Article 185 of the Kompilasi Hukum Islam, solely translated as Compilation of Islamic Law) in Indonesia has brought some “winds of change” for the grandchildren whose parents (male or female) have died before the heirs. However, in the case of its application in the Banjar Muslim community of South Kalimantan, it seems that it still requires various efforts, such as subpoenas, lawsuits, requests through authorized institutions, and the assistance of advocates. This Article on Inheritance is indeed very brief, thus allowing for a juridical interpretation and opening opportunities for legal discretion against it. Therefore, different responses to it are necessary, and many perspectives can be considered to convey a conclusion and verify that the resolution of this case is by the principles of maqâshid al-syarîah—which are gender equitable—and benefit the family lineage. The Banjarmasin Religious Court, one of the institutions holding the authority to examine and adjudicate this inheritance issue, has issued its legal products in court decisions and verdicts. This research aimed to determine (1) how the case of substitute heirs in the Banjar community of South Kalimantan is resolved and (2) the application of Article 185 KHI in the Banjarmasin Religious Court. On this basis, a case study of several copies of the letter was the approach employed in this normative legal research. The study found that there were four decisions and two verdicts—which were all aligned with Article 185 of KHI and were gender-responsive.
Passampo Siri' in the Bugis Marriage Practies in East Kolaka, Indonesia: A Sociological Perspective of Islamic Law
Authors: Ipandang Ipandang , Darlis Syamsul 
Published: January 2023

This research aims to illustrate the problematics of Passampo Siri’ marriage practice in the Bugis community, East Kolaka Regency, using a descriptive qualitative method based on the sociology of Islamic law. Data collection techniques involve interviews with informants deemed necessary and observing or directly paying attention to the implementation of the marriage tradition through siri'. The findings indicate that the Bugis society practices this type of marriage because of social pressure to conceal shame, adherence to ancestral customs, a lack of public understanding of relevant marriage law norms, and low levels of public education. However, the custom is no longer practiced since it cannot provide justice and order in society. This marriage also has implications for acts against the law of society, as stipulated in Article 53 of the KHI that a pregnant woman out of wedlock can only be married to a man who impregnates her. In contrast, for the practice of Passampo Siri’ marriages, the pregnant woman out of wedlock is married to another man. Therefore, this research contributes directly to the development of the study of Islamic law in Indonesia and the world in finding the best solution to achieving legal expectations among the public, especially regarding marriages of pregnant women out of wedlock with men who do not impregnate them.
Muslims Resistance to Health Protocols in COVID-19 Funeral: A Study of Islamic Law
Authors: Zainuddin Zainuddin , Qudsy Saifuddin Zuhri , Cahyani Novita , Zulkifli Zulkifli , Warman Arifki Budia 
Published: January 2023

Some Muslims have stood up against health protocols for burying COVID-19 corpses. This research aimed to investigate the initial occurrence of this resistance in society, the contributing factors to the resistance, and the implications of the resistance. To date, most studies on resistance focused on social perspectives, but this research probed into the discourse of resistance during COVID-19 from the perspective of legal transformation, especially in Islamic law or fiqh. This study employed a qualitative approach supported by data obtained from printed and electronic media, and informants. The analysis revealed that public resistance to the burial which complied to health protocols was not only embodied in rhetorics or values but made apparent in their attitude. This study concludes that public resistance sucessfully reformed the law by bringing about the new fiqh regarding the burial practice. Since the community might not readily understand and accept this neq fiqh, we advised the government and related institutions to take intensive approaches to introduce this transformation to public.
The Approach of Local Wisdom and Islamic Law to the Establishment of Regional Regulations on Alcoholic Drinks
Authors: HL Rahmatiah , Arbani Tri Suhendra , Damopolii Muljono , M. Nur Abdullah , Hanafiah Muktar 
Published: January 2023

In several regions in Indonesia, there are many criminal cases of abuse of alcoholic beverages, but on the other hand, in many regions, they provide legalization for alcoholic beverages themselves. The phenomenon of alcoholic beverages is faced with cultural connotations and local wisdom. From this view, this study will look at the influence of local wisdom and Islamic legal views so that they can influence local regulatory policies. Furthermore, the other hand, it will also discuss law enforcement from alcoholic beverages that have a terrible impact on the community. The research method used is a normative legal research method. The study uses a statutory approach and the analysis of legislation theory. The study results indicate that the traditions strongly influence the North Toraja area's formation of regional regulations in its community. One view can be drawn that the link between the traditions of a region will follow the existing regulations in that area. This is in line with the basis for the formation of regional regulations. There are three principal foundations: the philosophical, the juridical, and the sociological. The majority of the population in every Indonesian region is Muslim, which also affects the norm value of local government regulation. This can be seen in the Province of Aceh, which strongly opposes the existence of alcoholic beverages in the area. For the Province of South-Sulawesi alone in Takalar Regency, the same thing applies by strictly prohibiting the drinking, producing, and trading of alcoholic beverages, even though these include traditional drinks. Therefore, this research shows that strong Islamic values greatly influence the local community. Law enforcement is closely related to the implementation of sanctions from existing regulations. Penalty application is so religious in every area. Some impose sanctions regarding production and trade permits, and some apply criminal sanctions, and so on.
Analisis Sistem Pengolahan Limbah Medis Padat Puskesmas Di Kecamatan Bayung Lencir, Musi Banyuasin
Authors: Andrayani Desi , Syarifuddin Hutwan , Guspianto Guspianto 
Published: January 2023

Operasional Puskesmas akan menimbulkan limbah, yang berpotensi menimbulkan dampak terhadap masyarakat dan lingkungan hidup. Tujuan penelitian ini menganalisis sistem pengolahan limbah medis padat (pemilahan, pewadahan, pengangkutan, penyimpanan, dan pengolahan) sesuai dengan Permen LHK No. 56/Menlhk/2015 pada puskesmas yang ada di Kecamatan Bayung Lencir, Kabupaten Musi Banyuasin.
Metode penelitian kualitatif dengan pendekatan deskriptif, pelaksanaan penelitian pada bulan desember 2021 sampai Mei 2022. Sumber informasi dalam penelitian ini yaitu Kepala puskesmas sebagai informasi kunci (key informan) dokter, perawat, bidan, apoteker, analis, sanitarian, dan Cleaning service.
Kecamatan Bayung Lencir memiliki dua puskesmas yaitu puskesmas Bayung Lencir dan puskesmas Suka Jaya, puskesmas memiliki proses pengolahan limbah medis padat dengan tahap yang sama yaitu pemilahan, pewadahan, pengangkutan, penyimpanan dan pengolahan. Berdasarkan permen LHK Nomor P.56/menLHK-setjen/2015 dan Permen LHK no.P12 tahun 2020 belum terpenuhi dan belum dilaksanakan dengan baik. Pemilahan belum dilakukan secara optimal masih terjadinya pencampuran antara limbah medis padat dengan limbah non medis dan limbah benda tajam, sanitarian melakukan pemilahan kembali yang akan berisiko keselamatan dan kesehatan kerja. Telah tersedia tempat sampah medis dan non medis tetapi masih ditemukan sampah bercampur. Pengangkutan tidak memiliki jalur khusus dan pengangkutan masih manual langsung diambil dari tempat penampungan limbah medis padat sehingga berisiko menjadi penularan, kapasitas tempat penyimpanan sampah sementara (TPS) tidak mencukupi serta belum memiliki izin. Pengolahan limbah medis padat
Kajian Sanitasi Lingkungan Terhadap Kejadian Stunting di Wilayah Kerja Puskesmas Simpang Tuan Kabupaten Tanjung Jabung Timur
Authors: Soraya Soraya , Ilham Ilham , Hariyanto Hariyanti 
Published: January 2023

Stunting
merupakan suatu kondisi gangguan pertumbuhan linier akibat kekurangan asupan yang bersifat kronik dan banyak muncul di wilayah negara berkembang termasuk Indonesia. Kejadian stunting di Kecamatan Mendahara Ulu sebesar 20,56%. Presentase stunting tersebut termasuk dalam masalah kesehatan masyarakat dalam kategori masalah ringan karena lebih dari 20%. Sanitasi lingkungan merupakan penyebab tidak langsung terjadinya stunting.
Keadaan lingkungan yang tidak saniter menyebabkan lebih mudah terjangkit penyakit seperti diare dan penyakit infeksi
yang berdampak terjadinya stunting
.
Penelitian ini menggunakan desain cross sectional. Sampel penelitian adalah ibu yang memiliki balita di wilayah kerja Puskesmas Simpang Tuan sebesar 228 orang. Instrumen penelitian adalah kuesioner. Data dianalisis menggunakan uji chi square. Sebesar 30,3% responden memiliki balita stunting, 45,2% sarana jamban kurang baik, 37,3% sarana air bersih kurang baik, 46,5% SPAL kurang baik dan 38,2% pengelolaan sampah. Hasi
l
uji statistik diketahui ada hubungan antara sanitasi jamban (p=0,000; PR=15,534), sarana air bersih (p=0,000; PR=4,427), SPAL (p=0,000; PR=6,791) dan pengelolaan sampah (p=0,000; PR=10,805) dengan stunting. Kejadian stunting di wilayah kerja Puskesmas Simpang Tuan berhubungan dengan sarana jamban, sarana air bersih, SPAL dan pengelolaan sampah. Diharapkan kepada Puskesmas Simpang Tuan untuk melakukan pemberdayaan kepada masyarakat mengenai sanitasi lingkungan melalui program Sanitasi Total Berbasis Masyarakat (STBM)
ANALISIS TERHADAP NETRALITAS APARATUR SIPIL NEGARA DALAM PEMILIHAN KEPALA DAERAH BERDASARKAN PERATURAN PERUNDANG-UNDANGAN
Authors: Rahmansyah Arif , Irwandi Irwandi 
Published: January 2023

Abstract
The purpose of this study is to analyze how the neutrality of the state civil apparatus in the implementation of the Regional Head Election in Indonesia. The reason is, there are still neutrality violation cases of the state civil apparatus in regional head elections. Where the author reviews from the point of view of the position and role of the State Civil Apparatus Commission (KASN) in maintaining the neutrality of ASN. As mandated in Law Number 5 of 2014 concerning State Civil Apparatus, article 29 states that KASN is domiciled in the state capital. The formulation of the problem in this study is how the role of KASN in overseeing the neutrality of ASN in the election of regional heads according to Law Number 5 of 2014 and how good regulation is in monitoring the neutrality of the State Civil Apparatus in the election of regional heads. The type of research used is normative juridical, namely legal research methods carried out by examining library materials or secondary materials. The result of this research is the weak regulation on the position of the State Civil Apparatus Commission.

Keyword : Neutrality, State Civil Apparatus, Regional Head Election

Abstrak

Tujuan penelitian ini adalah untuk menganalisis bagaimana netralitas aparatur sipil Negara dalam pelaksanaan Pemilihan Umum Kepala Daerah di Indonesia. Karena masih sering terjadi kasus pelanggaran netralitas aparatur sipil Negara dalam pemilihan kepala daerah. Dimana penulis meninjau dari sudut pandang kedudukan serta peran Komisi Aparatur Sipil Negara (KASN) dalam menjaga netralitas ASN. Sebgaimana diamantkan dalam Undang-Undang Nomor 5 Tahun 2014 Tentang Aparatur Sipil Negara pasal 29 mengatakan KASN berkedudukan di ibukota Negara. Adapun rumusan masalah dalam penelitian ini adalah bagaimana peran KASN dalam mengawasi netralitas ASN dalam pemilihan kepala daerah menurut Undang-Undang Nomor 5 Tahun 2014 dan bagimana pengaturan yang baik dalam hal mengawasi netralitas Aparatur Sipil Negara dalam pemilihan kepala daerah. Tipe penelitiann yang digunakan ini adalah yuridis normatif yaitu metode penelitian hukum yang dilakukan dengan cara meneliti bahan pustaka atau bahan sekunder. Hasil dari penelitian ini adalah lemah nya pengaturan tentang kedudukan Komisi Aparatur Sipil Negara.

Kata Kunci: Netralitas, Aparatur Sipil Negara, Pemilihan Kepala Daerah.
Studi Komparatif Kewenangan Presiden Dalam Pengangkatan Kepala Kepolisian Republik Indonesia Sebelum Dan Sesudah Amandemen Undang Undang Dasar Negara Republik Indonesia Tahun 1945
Authors: Anugerah Prasetya Gemmy , Yarni Meri , Eriton Muhammad 
Published: January 2023

penelitian ini bertujuan untuk mengetahui bagaimana pengaturan mengenai kewenangan Presiden dalam mengangkat Kepala Kepolisian Republik Indonesia dan untuk mengetahui bagaimana tahapan mekanisme pengangkatan Kepala Kepolisian Republik Indonesia. Tipe penelitian yang digunakan termasuk jenis penelitian yuridis normatif, yang mengacu pada norma-norma hukum, asas-asas hukum, sistematika hukum, perbandingan hukum, dan sejarah hukum yang berhubungan dengan permasalahan pengaturan kewenangan Presiden dalam pengangkatan Kepala Kepolisian Republik Indonesia menurut Undang-Undang Dasar Negara Republik Indonesia Tahun 1945 dan aturan mengenai mekanisme pengankatan Kepala kepolisian Republik Indonesia menurut Undang-Undang Nomor 2 Tahun 2002 Tentang Kepolisian Republik Indonesia. Pendekatan yang digunakan yaitu pendekatan perundang-undangan, pendekatan konseptual dan pendekatan perbandingan. Bedasarkan hasil pembahasan, bahwa setelah bergulirnya masa order baru dan menurut Undang-Undang Nomor 2 Tahun 2002, bahwa dalam pengangkatan Kepala Kepolisian Republik Indonesia, Presiden harus meminta persetujuan Dewan Perwakilan Rakyat (DPR) terlebih dahulu sebagai cerminan dari sistem pemerintahan Indonesia yaitu sistem pemerintahan Presidensil dengan prinsip check and balances. Dalam Undang-Undang Nomor 2 Tahun 2002 tidak terdapat aturan mengenai bagaimana calon Kepala Kepolisian Republik Indonesia yang telah mendapat persetujuan DPR tetapi tidak ditetapkan oleh Presiden. Adapun mekanisme yang seharusnya, bahwa calon Kepala Kepolisian Republik Indonesia yang telah melakukan fit and poper test dan telah mendapat persetujuan dari DPR haruslah dilantik/ditetapkan oleh Presiden.