bluuebunny/crossref_metadata_2025_split huggingface dataset:
Multi-resonant tessellated anchor-based metasurfaces
Authors: Gallagher Cameron P. , Hamilton Joshua K. , Hooper Ian R. , Sambles J. Roy , Hibbins Alastair P. , Lawrence Christopher R. , Bows John 
Published: March 2023

AbstractIn this work, a multi-resonant metasurface that can be tailored to absorb microwaves at one or more frequencies is explored. Surface shapes based on an ‘anchor’ motif, incorporating hexagonal, square and triangular-shaped resonant elements, are shown to be readily tailorable to provide a targeted range of microwave responses. A metasurface consisting of an etched copper layer, spaced above a ground plane by a thin (< 1/10th of a wavelength) low-loss dielectric is experimentally characterised. The fundamental resonances of each shaped element are exhibited at 4.1 GHz (triangular), 6.1 GHz (square) and 10.1 GHz (hexagonal), providing the potential for single- and multi-frequency absorption across a range that is of interest to the food industry. Reflectivity measurements of the metasurface demonstrate that the three fundamental absorption modes are largely independent of incident polarization as well as both azimuthal and elevation angles.
Assessment of surface and electrical properties of the TiO2@zeolite hybrid materials
Authors: Supelano G. I. , Mesa F. , Vargas C. A. Parra , Gómez J. A. Mejía , Dussan A. 
Published: March 2023

AbstractDegradation of pollutants in aqueous medium is of high interest due to the impact on environment and human health, therefore, design and study of the physico-chemical properties of photocatalysts for water remediation are of major significance. Among properties of photocatalyst, those related to the surface and electrical mechanism are crucial to the photocatalyst´s performance. Here we report the chemical and morphological characteristics of TiO2@zeolite photocatalyst by X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM) respectively, and a coherent electrical conduction mechanism was proposed based on data obtained from assisted laser impedance spectroscopy (ALIS), in which the zeolite was synthesized from recycled coal fly ash. The results obtained by SEM and XPS verified the presence of spherical particles of TiO2 anatase with presence of Ti3+ state. ALIS results showed that impedance of the entire system increases when the amount of TiO2 increases and the samples with lower capacitive performance allowed a larger transfer of the charges between the solid–liquid interface. All results showed that higher photocatalytic performance of TiO2 growth over hydroxysodalite with 8.7 wt% and 25 wt% of TiO2 can be explained in terms of the morphology of TiO2 and the interactions between substrate-TiO2 mainly.
Optomechanically induced gain using a trapped interacting Bose-Einstein condensate
Authors: Mikaeili H. , Dalafi A. , Ghanaatshoar M. , Askari B. 
Published: March 2023

AbstractWe investigate the realization of the phenomenon of optomechanically induced gain in a hybrid optomechanical system consisting of an interacting Bose-Einstein condensate trapped inside the optical lattice of a cavity which is generated by an external coupling laser tuned to the red sideband of the cavity. It is shown that the system behaves as an optical transistor while the cavity is exposed to a weak input optical signal which can be amplified considerably in the cavity output if the system is in the unresolved sideband regime. Interestingly, the system has the capability to switch from the resolved to unresolved sideband regime by controlling the s-wave scattering frequency of atomic collisions. We show that the system gain can be enhanced considerably by controlling the s-wave scattering frequency as well as the coupling laser intensity while the system remains in the stable regime. Based on our obtained results, the input signal can be amplified more than 100 million percent in the system output which is much larger than those already reported in the previously proposed similar schemes.
Valorification of Egyptian volcanic tuff as eco-sustainable blended cementitious materials
Authors: Eldahroty Khaled E. H. , Farghali A. A. , Shehata Nabila , Mohamed O. A. 
Published: March 2023

AbstractRhyolite rocks extend from southern Egypt to northern Egypt in the Eastern Desert, and no effective economic exploitation of them has been discovered so far. The pozzolanic activities of different volcanic tuffs (VT) supplied from the Eastern Desert located in Egypt have been investigated as natural volcanic pozzolan materials to develop new green cementitious materials for achieving sustainability goals in the construction field. Experimentally in this paper, the pozzolanic activities of seven diverse specimens of Egyptian tuffs taken with standardized proportions of 75:25% (Cement: volcanic tuffs) were investigated. Pozzolanic features of such tuffs are examined comparatively via strength activity index (SAI), TGA, DTA, and the Frattini’s test. Chemical composition, petrographic, and XRD analysis were also performed for tuffs samples. The pozzolanic reaction degrees were determined according to the compressive strengths at 7, 28, 60 and 90 days with different replacement ratios (20, 25, 30 and 40%) of tuffs samples. Additionally, the micro-filler effects in mortar and concrete were determined by measuring the heat of hydration in mortar samples and the compressive strength of concrete with different additive ratios for tuffs samples besides, the concrete slump test. The results show that TF6 gives a lower cement heat of hydration value which is less than 270 J/g at 7 days. Also, its performance in concrete is better than silica fume at late strength (28 days) since the concrete index value is 106.2% by compared to the concrete index of silica fume 103.9 and therefore it can be used as an alternative to high price and quality variable silica fume (SF) for producing high-performance green concrete. Due to the good pozzolanic behavior proved by nearly most volcanic tuffs, along with their low cost, this study will be profitable for very auspicious the use of Egyptian volcanic tuffs for developing sustainable and eco‑friendly blended cement.
Urban economic fitness and complexity from patent data
Authors: Straccamore Matteo , Bruno Matteo , Monechi Bernardo , Loreto Vittorio 
Published: March 2023

AbstractOver the years, the growing availability of extensive datasets about registered patents allowed researchers to get a deeper insight into the drivers of technological innovation. In this work, we investigate how patents’ technological contents characterise metropolitan areas’ development and how innovation is related to GDP per capita. Exploiting worldwide data from 1980 to 2014, and through network-based techniques that only use information about patents, we identify coherent distinguished groups of metropolitan areas, either clustered in the same geographical area or similar in terms of their economic features. Moreover, we extend the notion of coherent diversification to patent production and show how it is linked to the economic growth of metropolitan areas. Our findings draw a picture in which technological innovation can play a key role in the economic development of urban areas. We contend that the tools introduced in this paper can be used to further explore the interplay between urban growth and technological innovation.
Biomimetic cultivation of atrial tissue slices as novel platform for in-vitro atrial arrhythmia studies
Authors: Amesz Jorik H. , de Groot Natasja M. S. , Langmuur Sanne J. J. , Azzouzi Hamid el , Tiggeloven Vera P. C. , van Rooij Manuela M. M. M. , Knops P. , Bogers Ad J. J. C. , Taverne Yannick J. H. J. 
Published: March 2023

AbstractLiving myocardial slices (LMS) are beating sections of intact human myocardium that maintain 3D microarchitecture and multicellularity, thereby overcoming most limitations of conventional myocardial cell cultures. We introduce a novel method to produce LMS from human atria and apply pacing modalities to bridge the gap between in-vitro and in-vivo atrial arrhythmia studies. Human atrial biopsies from 15 patients undergoing cardiac surgery were dissected to tissue blocks of ~ 1 cm2 and cut to 300 µm thin LMS with a precision-cutting vibratome. LMS were placed in a biomimetic cultivation chamber, filled with standard cell culture medium, under diastolic preload (1 mN) and continuous electrical stimulation (1000 ms cycle length (CL)), resulting in 68 beating LMS. Atrial LMS refractory period was determined at 192 ± 26 ms. Fixed rate pacing with a CL of 333 ms was applied as atrial tachyarrhythmia (AT) model. This novel state-of-the-art platform for AT research can be used to investigate arrhythmia mechanisms and test novel therapies.
Building social capital with elders’ leadership through a community hub “Ibasho” in the Philippines and Nepal
Authors: Aida Takeshi , Kiyota Emi , Tanaka Yasuhiro , Sawada Yasuyuki 
Published: March 2023

AbstractWe quantitatively study the Ibasho project—a unique, innovative community-based project that involves co-creating a building as a social hub. Ibasho’s decision-making undertakes a bottom-up approach, differentiating itself from the conventional top-down decision-making process. Using sui generis data, we find that Ibasho projects in the Philippines and Nepal contributed to enhancing social capital among elders in both cases. Yet there are differences between the two communities. In the Philippines, participation in Ibasho increased the number of a participant’s friends, or “strong ties,” indicating that it is on the intensive margin of human relationships. In contrast, joining Nepal’s Ibasho broadened weak ties rather than strong ones. This contrast may stem from the difference in pre-existing social and built infrastructures in the two communities, which were strengthened through the building-human interactions.
Strong temporal variation of consumer δ13C value in an oligotrophic reservoir is related to water level fluctuation
Authors: Veselý Lukáš , Ercoli Fabio , Ruokonen Timo J. , Bláha Martin , Duras Jindřich , Haubrock Phillip J. , Kainz Martin , Hämäläinen Heikki , Buřič Miloš , Kouba Antonín 
Published: March 2023

AbstractUsing stable carbon and nitrogen isotope analysis (δ13C and δ15N) to assess trophic interactions in freshwater ecosystems is a well established method, providing insight into ecosystem functioning. However, the spatial and temporal variability of isotope values, driven by environmental fluctuation is poorly understood and can complicate interpretations. We investigated how the temporal variation of stable isotopes in consumers (fish, crayfish and macrozoobenthos) of a canyon-shaped oligotrophic reservoir is associated with environmental factors such as water temperature, transparency, flooded area, and water quality measures. Consumers and their putative food sources were sampled and analyzed for carbon and nitrogen stable isotopes annually, and environmental parameters were measured monthly from 2014 to 2016. Results revealed significant differences in δ13C and δ15N values in each consumer among studied years. Over the years, fish and crayfish expressed differences in δ13C between 3 and 5‰, whereas in zoobenthos differences were 12‰. Variability in δ15N was similar across all consumers (2–4‰). Moreover, results suggest that the flooded area of the reservoir was a major driver of δ13C stable isotope values variation in consumers, while variation in δ15N was not linked to any of the studied environmental factors. Bayesian mixing models further showed significant changes in the origin of detritivorous zoobenthos carbon sources (reversal shift from terrestrial detritus to algae origin) between years with low water level to years with the standard water level. Other species showed only slight differences in food source utilization among years. Our study highlights the importance of environmental factors as sources of variation in consumer’s stable isotope values which should be considered especially when studied ecosystem strongly fluctuate in some environmental factor.
Recycling micro polypropylene in modified hot asphalt mixture
Authors: Buruiana Daniela Laura , Georgescu Puiu Lucian , Carp Gabriel Bogdan , Ghisman Viorica 
Published: March 2023

AbstractOne of the objectives of the circular economy is solving the world’s plastic pollution crisis and recycling of materials by ensuring less waste. The motivation of this study was to demonstrate the possibility of recycling two types of wastes with a high risk of pollution, such as plastic based polypropylene and abrasive blasting grit wastes in asphalt roads. The effects of adding together polypropylene based microplastics and grit waste in asphalt mixture for wear layer performance have been shown in this study. The morphology and elemental composition of the hot asphalt mixture samples before and after freeze–thaw cycle were examined by SEM–EDX and the performance of the modified asphalt mixture was determined with laboratory tests including Marshall stability, flow rate, solid–liquid report, apparent density, and water absorption. A hot asphalt mixture suitable for making wear layer in road construction, containing aggregates, filler, bitumen, abrasive blasting grit waste and polypropylene based microplastics is also disclosed. In the recipe of modified hot asphalt mixtures were added 3 proportions of polypropylene-based microplastics such as 0.1%, 0.3% and 0.6%. An improvement of the mixture performance is shown at the asphalt mixture sample with 0.3% of polypropylene. In addition, polypropylene-based microplastics are bond with aggregates from mixture well, so the polypropylene-modified hot asphalt mixture can effectively decrease the appearance of cracks during sudden temperature changes.
The deep origin of ground fissures in the Kenya Rift Valley
Authors: Jia Zhijie , Wu Hongjie , Peng Jianbing , Lu Quanzhong , Huang Weiliang , Liu Chuntao , Wang Feiyong , Liu Yang , He Ming 
Published: March 2023

AbstractIntense volcanic and geothermal activities characterize the Great Rift Valley of East Africa. Ground fissure disasters of the Great Rift Valley have garnered increasing attention in recent years. Through field investigations, trenching, geophysical exploration, gas sampling and analysis, we determined the distribution and origin of 22 ground fissures within the Kedong Basin of the Central Kenya Rift. These ground fissures caused varying degrees of damage to roads, culverts, railways, and communities. Trenching and geophysical exploration have shown that ground fissures in sediments are connected to rock fractures with gas escaping. The gases expelled from the rock fractures contained methane and SO2, which were absent in the normal atmosphere, and 3He/4He ratios in gases measured further indicated that the volatiles were derived from the mantle, suggesting that these rock fractures extended deep into the underlying bedrock. Spatial correlations with rock fractures demonstrate the deep origin of these ground fissures, which are associated with active rifting, plate separation, and volcanism. The ground fissures are formed due to movement on the deeper rock fractures, and then the gas escapes through the fissures. Determining the unusual origin of these ground fissures can not only guide infrastructure development and urban planning but also contribute to the safety of local communities.
Comparison between three types of needles for endoscopic ultrasound-guided tissue acquisition of pancreatic solid masses: a multicenter observational study
Authors: Yang Min Jae , Kim Jaihwan , Park Se Woo , Cho Jae Hee , Kim Eui Joo , Lee Yun Nah , Lee Dong Wook , Park Chan Hyuk , Lee Sang Soo 
Published: March 2023

AbstractIt is debatable which needle has clear superiority of diagnostic performance in endoscopic ultrasound (EUS)-guided fine needle biopsy (FNB) of solid pancreatic masses. This study aimed to compare the performance of three needles and determine the variables that affect diagnostic accuracy. From March 2014 to May 2020, 746 patients with solid pancreatic masses who underwent EUS-FNB using three types of needles (Franseen needle, Menghini-tip needle, and Reverse-bevel needle) were retrospectively reviewed. Multivariate analysis using a logistic regression model was used to identify factors related to diagnostic accuracy. There were significant differences between the groups regarding the procurement rate of the histologic and optimal quality cores (Franseen vs. Menghini-tip vs. Reverse-bevel: 98.0% [192/196] vs. 85.8% [97/113] vs. 91.9% [331/360], P < 0.001 and 95.4% [187/196] vs. 65.5% [74/113] vs. 88.3% [318/360], P < 0.001, respectively). The sensitivity and accuracy using histologic samples were 95.03% and 95.92% for Franseen, 82.67% and 88.50% for Menghini-tip, and 82.61% and 85.56% for Reverse-bevel needles, respectively. In direct comparison between the needles using histologic samples, the Franseen needle showed significantly superior accuracy than the Menghini-tip (P = 0.018) and Reverse-bevel needles (P < 0.001). Multivariate analysis indicated that tumor size ≥ 2 cm (odds ratio [OR] 5.36, 95% confidence interval [CI] 3.40–8.47, P < 0.001) and fanning technique (OR 1.70, 95% CI 1.00–2.86, P = 0.047) were significantly associated with an accurate diagnosis. EUS-FNB using the Franseen needle enables the acquisition of a larger and more adequate histologic core tissue and achieves an accurate histological diagnosis when using the fanning technique.
Smartphone videos of the sit-to-stand test predict osteoarthritis and health outcomes in a nationwide study
Authors: Boswell Melissa A. , Kidziński Łukasz , Hicks Jennifer L. , Uhlrich Scott D. , Falisse Antoine , Delp Scott L. 
Published: March 2023

AbstractPhysical function decline due to aging or disease can be assessed with quantitative motion analysis, but this currently requires expensive laboratory equipment. We introduce a self-guided quantitative motion analysis of the widely used five-repetition sit-to-stand test using a smartphone. Across 35 US states, 405 participants recorded a video performing the test in their homes. We found that the quantitative movement parameters extracted from the smartphone videos were related to a diagnosis of osteoarthritis, physical and mental health, body mass index, age, and ethnicity and race. Our findings demonstrate that at-home movement analysis goes beyond established clinical metrics to provide objective and inexpensive digital outcome metrics for nationwide studies.
C. elegans is not a robust model organism for the magnetic sense
Authors: Malkemper Erich Pascal , Pikulik Patrycja , Krause Tim Luca , Liu Jun , Zhang Li , Hamauei Brittany , Scholz Monika 
Published: March 2023

AbstractMagnetoreception is defined as the ability to sense and use the Earth’s magnetic field, for example to orient and direct movements. The receptors and sensory mechanisms underlying behavioral responses to magnetic fields remain unclear. A previous study described magnetoreception in the nematode Caenorhabditis elegans, which requires the activity of a single pair of sensory neurons. These results suggest C. elegans as a tractable model organism for facilitating the search for magnetoreceptors and signaling pathways. The finding is controversial, however, as an attempt to replicate the experiment in a different laboratory was unsuccessful. We here independently test the magnetic sense of C. elegans, closely replicating the assays developed in the original publication. We find that C. elegans show no directional preference in magnetic fields of both natural and higher intensity, suggesting that magnetotactic behavior in the worm is not robustly evoked in a laboratory setting. Given the lack of a robust magnetic response under controlled conditions, we conclude that C. elegans is not a suitable model organism to study the mechanism of the magnetic sense.
Verification of preparations of (1H-indol-3-yl)methyl electrophiles and development of their microflow rapid generation and substitution
Authors: Masui Hisashi , Kanda Sena , Fuse Shinichiro 
Published: March 2023

AbstractAlthough highly reactive (1H-indol-3-yl)methyl electrophiles such as (1H-indol-3-yl)methyl halides are potential precursors for the synthesis of various indole derivatives, some researchers have reported difficulties in their preparation due to concomitant undesired dimerization/oligomerization. Nevertheless, there have been some reports on the preparation of (1H-indol-3-yl)methyl halides. To resolve this contradiction, all the previously reported preparations of (1H-indol-3-yl)methyl halides were examined. However, we could not reproduce any of these preparations, and we revised several structures of indole derivatives. Here we show the rapid (0.02 s) and mild (25 °C) generation of an (1H-indol-3-yl)methyl electrophile that enables the rapid (0.1 s) and mild (25 °C) nucleophilic substitution in a microflow reactor. Eighteen unprotected indole analogues can be successfully synthesized using the developed microflow nucleophilic substitution with various nucleophiles.
Self-cyclisation as a general and efficient platform for peptide and protein macrocyclisation
Authors: Jia Xinying , Chin Yanni K.-Y. , Zhang Alan H. , Crawford Theo , Zhu Yifei , Fletcher Nicholas L. , Zhou Zihan , Hamilton Brett R. , Stroet Martin , Thurecht Kristofer J. , Mobli Mehdi 
Published: March 2023

AbstractMacrocyclisation of proteins and peptides results in a remarkable increase in structural stability, making cyclic peptides and proteins of great interest in drug discovery—either directly as drug leads or as in the case of cyclised nanodiscs (cNDs), as tools for studies of trans-membrane receptors and membrane-active peptides. Various biological methods have been developed that are capable of yielding head-to-tail macrocyclised products. Recent advances in enzyme-catalysed macrocyclisation include discovery of new enzymes or design of new engineered enzymes. Here, we describe the engineering of a self-cyclising “autocyclase” protein, capable of performing a controllable unimolecular reaction for generation of cyclic biomolecules in high yield. We characterise the self-cyclisation reaction mechanism, and demonstrate how the unimolecular reaction path provides alternative avenues for addressing existing challenges in enzymatic cyclisation. We use the method to produce several notable cyclic peptides and proteins, demonstrating how autocyclases offer a simple, alternative way to access a vast diversity of macrocyclic biomolecules.
Preclassic environmental degradation of Lake Petén Itzá, Guatemala, by the early Maya of Nixtun-Ch’ich’
Authors: Birkett Brooke A. , Obrist-Farner Jonathan , Rice Prudence M. , Parker Wesley G. , Douglas Peter M. J. , Berke Melissa A. , Taylor Audrey K. , Curtis Jason H. , Keenan Benjamin 
Published: March 2023

AbstractPaleolimnological evidence indicates the ancient Maya transformed terrestrial ecosystems by felling forest vegetation to construct large civic-ceremonial centers and to expand agriculture. Human settlements influenced lacustrine environments but the effects of Maya activities on aquatic ecosystems remain poorly studied. Here we analyzed a sediment core from Lake Petén Itzá, Guatemala, to infer paleoenvironmental changes resulting from Maya occupation of the archaeological site of Nixtun-Ch’ich’. Increases in charcoal and fecal stanol concentrations indicate Maya occupation of the Candelaria Peninsula by the late Early Preclassic period. Geochemical proxies reveal a period of lake ecosystem alteration during construction and expansion of the city’s urban grid in the Middle and Late Preclassic periods. Depopulation of the city in the Terminal Preclassic resulted in a decline in lake trophic state. Whereas previous studies of Petén waterbodies have indicated depressed lacustrine primary production, the core collected near Nixtun-Ch’ich’ shows evidence of ancient Maya lake ecosystem deterioration.