bluuebunny/crossref_metadata_2025_split huggingface dataset:
Implementation of Integrated Reporting <IR> Framework In Non-Profit Organization
Authors: Nurhaliva Nurhaliva , Handajani Lilik , Sokarina Ayudia 
Published: June 2023

This study aims to implement the 2021 revision of IIRF in X non-profit organization. This research is qualitative research with an action research approach. The results of this study indicate that X non-profit organization is able to present <IR> based on the eight content elements of IIRF, although the information presented in <IR> is not fully presented in full because the adoption of directed <IR> in IIRF is still at an early stage. However, if the organization is consistent with presenting <IR>, there will be a gradual increase in the following years. This research is expected to provide additional guidance on how to apply IIRF as a guide for presenting <IR> for organization X and other non-profit organizations interested in implementing IIRF.
Produção científica sobre compliance no Brasil: estudo bibliométrico na base Spell ®
Authors: Tisott Sirlei Tonello , Ribeiro Sílvio Paula , Santos Cléston Alexandre dos , Munaretto Lianice 
Published: June 2023

Objetivo: Este estudo analisou como se configuram as pesquisas brasileiras sobre compliance na base Spell®. Método: Estudo bibliométrico utilizando, para a coleta de dados, o termo “compliance” no título dos artigos, considerando todos os anos da base até o ano de 2021. Resultados: Os resultados retornaram 19 artigos sobre o tema, sendo 80% deles publicados nos últimos três anos – de 2018 a 2020. Os autores das publicações são provenientes de diferentes universidades e a qualidade dos artigos científicos é alta, tendo em vista que aproximadamente 70% deles estão classificados nos estratos A3 e A4 do Qualis/Capes. Foram observados benefícios da implementação de um programa de compliance nas empresas, como combate e prevenção à lavagem de dinheiro, boa reputação no mercado, mitigação de riscos com fraudes, corrupção e prejuízos financeiros, transparência e credibilidade de entidades públicas e privadas. Contribuições: Esta pesquisa contribui sob a forma de estímulo aos pesquisadores para um aprofundamento teórico - empírico sobre compliance e aos demais leitores (gestores, empresários e executivos) fornece um panorama conceitual, regulatório e apresenta os benefícios do compliance para as empresas. Conclui-se que o tema ainda é pouco explorado teórica e empiricamente no meio acadêmico, o que permite inferir que ainda há um vasto campo de pesquisas empíricas a serem exploradas em estudos futuros.
First recorded stranding of a short-finned pilot whale, Globicephala macrorhynchus, in Britain.
Authors: Kitchener Andrew , Hantke Georg , Penrose Rod , Perkins Matthew , Deaville Rob 
Published: June 2023

A male pilot whale, Globicephala sp., was reported as a live stranding on 1st March 2012 at Hazelbeach, near Neyland, Pembrokeshire. It was euthanased and its skull was recovered during an onsite necropsy. Examination of the skull and contemporary photographs of the stranded animal confirm that this is the first record of short-finned pilot whale, Globicephala macrorhynchus, in Britain.
A Review: Design and Build Damage Detection Equipment on Sensors and Power Supply Automatic Rain Gauge (ARG) With Long Short Term Memory Integrated
Authors: Sinambela Marzuki 
Published: June 2023

The Meteorology, Climatology, and Geophysics Agency (BMKG) technicians have successfully developed automatic rain measuring devices. This tool is called Automatic Rain Gauge - BMKG (ARG-BMKG). The existence of this instrument can replace conventional rain measuring observation systems or public rain stations in Indonesia. ARG – BMKG consists of a tipping bucket sensor, solar panels, GPRS modem, dry battery, and data logger. This repeated operation causes sensor measurement errors due to damage to the sensor due to the sensor voltage supply not meeting specifications, resulting in inaccurate data sent. Predicting sensor damage can be done with predictive maintenance. The results of field tests in previous studies showed that the system could operate properly where the device could measure the voltage of each sensor and send data to the database A sensor damage prediction model was designed and implemented using long-sort term memory (LSTM) by generating root mean square error (rmse). The system can provide damage prediction information on the sensor, and the power supply is displayed through the website properly
Interspecific variation and phylogenetic relationship between mangrove and non-mangrove species of a same family (Meliaceae)—insights from comparative analysis of complete chloroplast genome
Authors: Tan Fengxiao , Li Weixi , Feng Hui , Huang Yelin , Banerjee Achyut Kumar 
Published: June 2023

The mahogany family, Meliaceae, contains 58 genera with only one mangrove genus: Xylocarpus. Two of the three species of the genus Xylocarpus are true mangroves (X. granatum and X. moluccensis), and one is a non-mangrove (X. rumphii). In order to resolve the phylogenetic relationship between the mangrove and non-mangrove species, we sequenced chloroplast genomes of these Xylocarpus species along with two non-mangrove species of the Meliaceae family (Carapa guianensis and Swietenia macrophylla) and compared the genome features and variations across the five species.
The five Meliaceae species shared 130 genes (85 protein-coding genes, 37 tRNA, and eight rRNA) with identical direction and order, with a few variations in genes and intergenic spacers. The repetitive sequences identified in the rpl22 gene region only occurred in Xylocarpus, while the repetitive sequences in accD were found in X. moluccensis and X. rumphii. The TrnH-GUG and rpl32 gene regions and four non-coding gene regions showed high variabilities between X. granatum and the two non-mangrove species (S. macrophylla and C. guianensis). In addition, among the Xylocarpus species, only two genes (accD and clpP) showed positive selection. Carapa guianensis and S. macrophylla owned unique RNA editing sites. The above genes played an important role in acclimation to different stress factors like heat, low temperature, high UV light, and high salinity. Phylogenetic analysis with 22 species in the order Sapindales supported previous studies, which revealed that the non-mangrove species X. rumphii is closer to X. moluccensis than X. granatum. Overall, our results provided important insights into the variation of genetic structure and adaptation mechanism at interspecific (three Xylocarpus species) and intergeneric (mangrove and non-mangrove genera) levels.
Saccharibacteria (TM7), but not other bacterial taxa, are associated with childhood caries regardless of age in a South China population
Authors: You Yang , Yin Meixiang , Zheng Xiao , Liang Qiuying , Zhang Hui , Wu Bu-Ling , Xu Wenan 
Published: June 2023

Background
Human microbiome dysbiosis is related to various human diseases, and identifying robust and consistent biomarkers that apply in different populations is a key challenge. This challenge arises when identifying key microbial markers of childhood caries.

Methods
We analyzed unstimulated saliva and supragingival plaque samples from children of different ages and sexes, performed 16S rRNA gene sequencing, and sought to identify whether consistent markers exist among subpopulations by using a multivariate linear regression model.

Results
We found that Acinetobacter and Clostridiales bacterial taxa were associated with caries in plaque and saliva, respectively, while Firmicutes and Clostridia were found in plaque isolated from children of different ages in preschool and school. These identified bacterial markers largely differ between different populations, leaving only Saccharibacteria as a significant caries-associated phylum in children. Saccharibacteria is a newly identified phylum, and our taxonomic assignment database could not be used to identify its specific genus.

Conclusion
Our data indicated that, in a South China population, oral microbial signatures for dental caries show age and sex differences, but Saccharibacteria might be a consistent signal and worth further investigation, considering the lack of research on this microbe.
The Semont-Plus Maneuver or the Epley Maneuver in Posterior Canal Benign Paroxysmal Positional Vertigo
Authors: Strupp Michael , Mandala Marco , Vinck Anne-Sophie , Van Breda Laure , Salerni Lorenzo , Gerb Johannes , Bayer Otmar , Mavrodiev Vergil , Goldschagg Nicolina 
Published: June 2023

ImportanceQuestions remain concerning treatment efficacy for the common condition of benign paroxysmal positional vertigo (BPPV).ObjectiveTo compare the effectiveness of the Semont-plus maneuver (SM-plus) and the Epley maneuver (EM) for treatment of posterior canal benign paroxysmal positional vertigo (pcBPPV) canalolithiasis.Design, Setting, and ParticipantsThis prospective randomized clinical trial was performed at 3 national referral centers (in Munich, Germany; Siena, Italy; and Bruges, Belgium) over 2 years, with a follow-up to 4 weeks after the initial examination. Recruitment took place from June 1, 2020, until March 10, 2022. Patients were selected randomly during routine outpatient care after being referred to 1 of the 3 centers. Two hundred fifty-three patients were assessed for eligibility. After consideration of the exclusion criteria as well as informed consent, 56 patients were excluded and 2 declined to participate, with 195 participants included in the final analysis. The analysis was prespecified and per-protocol.InterventionsAfter being randomized to the SM-plus or the EM group, patients received 1 initial maneuver from a physician, then subsequently performed self-maneuvers at home 3 times in the morning, 3 times at noon, and 3 times in the evening.Main Outcome and MeasuresPatients had to document whether they could provoke positional vertigo every morning. The primary end point was the number of days until no positional vertigo could be induced on 3 consecutive mornings. The secondary end point was the effect of the single maneuver performed by the physician.ResultsOf the 195 participants included in the analysis, the mean (SD) age was 62.6 (13.9) years, and 125 (64.1%) were women. The mean (SD) time until no positional vertigo attacks could be induced in the SM-plus group was 2.0 (1.6) days (median, 1 [range, 1-8] day; 95% CI, 1.64-2.28 days); in the EM group, 3.3 (3.6) days (median, 2 [range, 1-20] days; 95% CI, 2.62-4.06 days) (P = .01; α = .05, 2-tailed Mann-Whitney test). For the secondary end point (effect of a single maneuver), no significant difference was detected (67 of 98 [68.4%] vs 61 of 97 [62.9%]; P = .42; α = .05). No serious adverse event was detected with both maneuvers. Nineteen patients (19.6%) in the EM group and 24 (24.5%) in the SM-plus group experienced relevant nausea.Conclusions and RelevanceThe SM-plus self-maneuver is superior to the EM self-maneuver in terms of the number of days until recovery in pcBPPV.Trial RegistrationClinicalTrials.gov Identifier: NCT05853328
Modern Prehospital Screening Technology for Emergent Neurovascular Disorders
Authors: Guo Xiaofan , Dye Justin 
Published: June 2023

AbstractStroke is a serious neurological disease and a significant contributor to disability worldwide. Traditional in‐hospital imaging techniques such as computed tomography (CT) and magnetic resonance imaging (MRI) remain the standard modalities for diagnosing stroke. The development of prehospital stroke detection devices may facilitate earlier diagnosis, initiation of stroke care, and ultimately better patient outcomes. In this review, the authors summarize the features of eight stroke detection devices using noninvasive brain scanning technology. The review summarizes the features of stroke detection devices including portable CT, MRI, transcranial Doppler ultrasound , microwave tomographic imaging, electroencephalography, near‐infrared spectroscopy, volumetric impedance phaseshift spectroscopy, and cranial accelerometry. The technologies utilized, the indications for application, the environments indicated for application, the physical features of the eight stroke detection devices, and current commercial products are discussed. As technology advances, multiple portable stroke detection instruments exhibit the promising potential to expedite the diagnosis of stroke and enhance the time taken for treatment, ultimately aiding in prehospital stroke triage.
Research on intelligent dispatching of micro‐grid according to optimized particle swarm algorithm
Authors: Nie Zhen , Zhang Rui 
Published: June 2023

AbstractIn the process of grid connection of irregular output micro‐grid systems, it is of great research significance to make micro‐grid scheduling operate more effectively and economically. To minimize the environmental and total operating costs of the micro‐grid intelligent scheduling system during grid connection, this study proposes a micro‐grid intelligent scheduling model based on an optimized particle swarm optimization algorithm. The optimized particle swarm algorithm mainly improves the problem of the particle swarm algorithm being prone to local optima, making it reduce the possibility of local convergence. Comparative tests were conducted on the improved IPSO algorithm, and the results showed that the non‐dominated solution concentration pollution emissions obtained by the improved IPSO algorithm were at least 18326 Ib, which was lower than the comparison algorithm. In the empirical analysis of the intelligent scheduling model based on the improved IPSO algorithm, the convergence and satisfaction of the model were 0.0054 and 0.922, respectively, which were superior to the comparison algorithm. The above results indicate that the intelligent scheduling model for micro‐grid based on the improved IPSO algorithm has good economy and stability. Compared with traditional energy dispatch methods, this energy dispatch mode has higher economic benefits and is of great significance for promoting the development of micro‐grid.
Van der Waals Ferroelectrics: Theories, Materials, and Device Applications
Authors: Li Shuhui , Wang Feng , Wang Yanrong , Yang Jia , Wang Xinyuan , Zhan Xueying , He Jun , Wang Zhenxing 
Published: June 2023

AbstractIn recent years, an increasing number of 2D van der Waals (vdW) materials are theory‐predicted or laboratory‐validated to possess in‐plane (IP) and/or out‐of‐plane (OOP) spontaneous ferroelectric polarization. Due to their dangling‐bond‐free surfaces, interlayer charge coupling, robust polarization, tunable energy band structures, and compatibility with silicon‐based technologies, vdW ferroelectric materials exhibit great promise in ferroelectric memories, neuromorphic computing, nanogenerators, photovoltaic devices, spintronic devices, and so on. Here, the very recent advances in the field of vdW ferroelectrics (FEs) are reviewed. First, theories of ferroelectricity are briefly discussed. Then, a comprehensive summary of the non‐stacking vdW ferroelectric materials is provided based on their crystal structures and the emerging sliding ferroelectrics. In addition, their potential applications in various branches/frontier fields are enumerated, with a focus on artificial intelligence. Finally, the challenges and development prospects of vdW ferroelectrics are discussed.
Strong and Multicolor‐Tunable Pure Organic Circularly Polarized Room‐Temperature Phosphorescence from Cholesteric Liquid Crystal
Authors: Gong Wei , Huang Guiyan , Yuan Yongjie , Zhang Hailiang 
Published: June 2023

AbstractPure organic circularly polarized room‐temperature phosphorescence (CPRTP) materials show significant promise for applications in advanced anti‐counterfeiting, biological imaging, and so on. However, it remains challenging to prepare CPRTP materials with a high phosphorescence luminescence dissymmetry factor (glum). This article provides a simple and efficient method to prepare pure organic CPRTP materials with high phosphorescence glum from cholesteric liquid crystals by incorporation of achiral phosphorescent chromophore dibenzofuran into chiral cholesterol mesogen via a flexible spacer. The findings show that the synthetic compound Chol‐C6‐DF can form cholesteric liquid crystals and can effectively amplify the glum value through selective reflection. The Chol‐C6‐DF film can produce yellow CPRTP when excited by a dibenzofuran chromophore. The glum value, the lifetime, and the quantum yield of the yellow CPRTP produced by dibenzofuran under the excitation of 380 nm light are −0.19, 567.7 ms, and 3.2%, respectively. Even more interesting is that the chiral cholesterol also exhibits RTP and clustering‐triggered emission characteristics. The glum value and the lifetime of red CPRTP produced by cholesterol under the excitation of 420 nm light are ‐0.11 and 1.11 s. Under excitation of 410, 430, and 470 nm light, the phosphorescent quantum yields are 19.0%, 20.2%, and 19.1%, respectively.
Nanozyme‐Catalyzed Metasurface Plasmon Sensor‐Based Portable Ultrasensitive Optical Quantification Platform for Cancer Biomarker Screening
Authors: Li Rui , Fan Hongli , Zhou Hanlin , Chen Youqian , Yu Qingcai , Hu Wenjun , Liu Gang L. , Huang Liping 
Published: June 2023

AbstractDeveloping plasmonic biosensors that are low‐cost, portable, and relatively simple to operate remains challenging. Herein, a novel metasurface plasmon‐etch immunosensor is described, namely a nanozyme‐linked immunosorbent surface plasmon resonance biosensor, for the ultrasensitive and specific detection of cancer biomarkers. Gold‐silver composite nano cup array metasurface plasmon resonance chip and artificial nanozyme‐labeled antibody are used in two‐way sandwich analyte detection. Changes in the biosensor's absorption spectrum are measured before and after chip surface etching, which can be applied to immunoassays without requiring separation or amplification. The device achieved a limit of alpha‐fetoprotein (AFP) detection < 21.74 fM, three orders of magnitude lower than that of commercial enzyme‐linked immunosorbent assay kits. Additionally, carcinoembryonic antigen (CEA) and carbohydrate antigen 125 (CA125) are used for quantitative detection to verify the universality of the platform. More importantly, the accuracy of the platform is verified using 60 clinical samples; compared with the hospital results, the three biomarkers achieve high sensitivity (CEA: 95.7%; CA125: 90.9%; AFP: 86.7%) and specificity (CEA: 97.3%; CA125: 93.9%; AFP: 97.8%). Due to its rapidity, ease of use, and high throughput, the platform has the potential for high‐throughput rapid detection to facilitate cancer screening or early diagnostic testing in biosensing.
Axial Oxygen Ligands Regulating Electronic and Geometric Structure of Zn‐N‐C Sites to Boost Oxygen Reduction Reaction
Authors: Jin Qiuyan , Wang Chenhui , Guo Yingying , Xiao Yuhang , Tan Xiaohong , Chen Jianpo , He Weidong , Li Yan , Cui Hao , Wang Chengxin 
Published: June 2023

AbstractZn‐N‐C possesses the intrinsic inertia for Fenton‐like reaction and can retain robust durability in harsh circumstance, but it is often neglected in oxygen reduction reaction (ORR) because of its poor catalytic activity. Zn is of fully filled 3d104s2 configuration and is prone to evaporation, making it difficult to regulate the electronic and geometric structure of Zn center. Here, guided by theoretical calculations, five‐fold coordinated single‐atom Zn sites with four in‐plane N ligands is constructed and one axial O ligand (Zn‐N4‐O) by ionic liquid‐assisted molten salt template method. Additional axial O not only triggers a geometry transformation from the planar structure of Zn‐N4 to the non‐planar structure of Zn‐N4‐O, but also induces the electron transfer from Zn center to neighboring atoms and lower the d‐band center of Zn atom, which weakens the adsorption strength of *OH and decreases the energy barrier of rate determining step of ORR. Consequently, the Zn‐N4‐O sites exhibit improved ORR activity and excellent methanol tolerance with long‐term durability. The Zn‐air battery assembled by Zn‐N4‐O presents a maximum power density of 182 mW cm−2 and can operate continuously for over 160 h. This work provides new insights into the design of Zn‐based single atom catalysts through axial coordination engineering.
Trifluoromethyl‐Substituted Conjugated Random Terpolymers Enable High‐Performance Small and Large‐Area Organic Solar Cells Using Halogen‐Free Solvent
Authors: Rehman Zia Ur , Haris Muhammad , Ryu Seung Un , Jahankhan Muhammad , Song Chang Eun , Lee Hang Ken , Lee Sang Kyu , Shin Won Suk , Park Taiho , Lee Jong‐Cheol 
Published: June 2023

AbstractThe advancement of non‐fullerene acceptors with crescent‐shaped geometry has led to the need for polymer donor improvements. Additionally, there is potential to enhance the photovoltaic parameters in high‐efficiency organic solar cells (OSCs). The random copolymerization method is a straightforward and effective strategy to further optimize photoactive morphology and enhance device performance. However, finding a suitable third component in terpolymers remains a crucial challenge. In this study, a series of terpolymer donors (PTF3, PTF5, PTF10, PTF20, and PTF50) is synthesized by introducing varying amounts of the trifluoromethyl‐substituted unit (CF3) into the PM6 polymer backbone. Even subtle changes in the CF3 content can significantly enhance all the photovoltaic parameters due to the optimized energy levels, molecular aggregation/miscibility, and bulk‐heterojunction morphology of the photoactive materials. Thus, the best binary OSC based on the PTF5:Y6‐BO achieves an outstanding power conversion efficiency (PCE) of 18.2% in the unit cell and a PCE of 11.6% in the sub‐module device (aperture size: 54.45 cm2), when using halogen‐free solvent o‐xylene. This work showcases the remarkable potential of the easily accessible CF3 unit as a key constituent in the construction of terpolymer donors in high‐performance OSCs.
A Comprehensive and Versatile Multimodal Deep‐Learning Approach for Predicting Diverse Properties of Advanced Materials
Authors: Muroga Shun , Miki Yasuaki , Hata Kenji 
Published: June 2023

AbstractA multimodal deep‐learning (MDL) framework is presented for predicting physical properties of a ten‐dimensional acrylic polymer composite material by merging physical attributes and chemical data. The MDL model comprises four modules, including three generative deep‐learning models for material structure characterization and a fourth model for property prediction. The approach handles an 18‐dimensional complexity, with ten compositional inputs and eight property outputs, successfully predicting 913 680 property data points across 114 210 composition conditions. This level of complexity is unprecedented in computational materials science, particularly for materials with undefined structures. A framework is proposed to analyze the high‐dimensional information space for inverse material design, demonstrating flexibility and adaptability to various materials and scales, provided sufficient data are available. This study advances future research on different materials and the development of more sophisticated models, drawing the authors closer to the ultimate goal of predicting all properties of all materials.