bluuebunny/crossref_metadata_2025_split huggingface dataset:
Hearing as adaptive cascaded envelope interpolation
Authors: Thoret Etienne , Ystad Sølvi , Kronland-Martinet Richard 
Published: June 2023

AbstractThe human auditory system is designed to capture and encode sounds from our surroundings and conspecifics. However, the precise mechanisms by which it adaptively extracts the most important spectro-temporal information from sounds are still not fully understood. Previous auditory models have explained sound encoding at the cochlear level using static filter banks, but this vision is incompatible with the nonlinear and adaptive properties of the auditory system. Here we propose an approach that considers the cochlear processes as envelope interpolations inspired by cochlear physiology. It unifies linear and nonlinear adaptive behaviors into a single comprehensive framework that provides a data-driven understanding of auditory coding. It allows simulating a broad range of psychophysical phenomena from virtual pitches and combination tones to consonance and dissonance of harmonic sounds. It further predicts the properties of the cochlear filters such as frequency selectivity. Here we propose a possible link between the parameters of the model and the density of hair cells on the basilar membrane. Cascaded Envelope Interpolation may lead to improvements in sound processing for hearing aids by providing a non-linear, data-driven, way to preprocessing of acoustic signals consistent with peripheral processes.
Electrochemical water oxidation using a stable water-soluble mononuclear manganese clathrochelate
Authors: Zheng Shenke , Liang Xiangming , Dai Chang , Yang Xueli , Li Ziyang , Lai Yilong , Hong Li , Lin Junqi 
Published: June 2023

A mononuclear manganese clathrochelate complex [MnIV(L-6H)]2− is found to be an efficient homogeneous water oxidation catalyst under near neutral conditions. Oxygen evolution occurs at a low onset overpotential of only 540 mV.
A high‐capacity and nonvolatile spintronic associative memory hardware accelerator
Authors: Rezaei Mahan , Amirany Abdolah , Moaiyeri Mohammad Hossein , Jafari Kian 
Published: June 2023

AbstractSignificant progress has been made in manufacturing emerging technologies in recent years. This progress implemented in‐memory‐computing and neural networks, one of today's hottest research topics. Over time, the need to process complex tasks has increased. This need causes the emergence of intelligent processors. A nonvolatile associative memory based on spintronic synapses utilising magnetic tunnel junction (MTJ) and carbon nanotube field‐effect transistors (CNTFET)‐based neurons is proposed. The proposed design uses the MTJ device because of its fascinating features, such as reliable reconfiguration and nonvolatility. At the same time, CNTFET has overcome conventional complementary metal‐oxide‐semiconductor shortcomings like the short channel effect, drain‐induced barrier lowering, and poor hole mobility. The proposed design is simulated in the presence of process variations. The proposed design aims to increase the number of weights generated in the synapse for higher memory capacity and accuracy. The effect of different tunnel magnetoresistance (TMR) values (100%, 200%, and 300%) on the performance and accuracy of the proposed design has also been investigated. This investigation shows that the proposed design performs well even with a low TMR value, which is very important and remarkable from the fabrication point of view.
Geographic information system‐based prediction of solar power plant production using deep neural networks
Authors: Mokarram Marzieh , Aghaei Jamshid , Mokarram Mohammad Jafar , Mendes Gonçalo Pinto , Mohammadi‐Ivatloo Behnam 
Published: June 2023

AbstractThe study aims to predict solar energy generation to ensure the successful operation of solar power plants. This objective is crucial in light of the increasing energy demand, global warming concerns, and greenhouse gas emissions. To achieve this, the study employs multiple linear regression and feature selection techniques to calculate energy generation. Additionally, long short‐term memory (LSTM) is used to predict energy generation levels based on climate conditions. Furthermore, the spatial distribution of energy generation is analyzed using inverse distance weighting. The results of the study reveal that temperature, solar radiation, relative humidity, wind speed, wind direction, and vapor pressure deficit are the most significant parameters for predicting energy generation. The LSTM method proves to be highly accurate in predicting fluctuating energy generation patterns. Notably, the southern regions of the study area exhibit a greater potential for energy generation compared to the northern regions. Approximately 30% of the region generates over 1400 kWh, with the southern areas, characterized by hot and dry climates, producing around 1500 kWh, while the northern regions, with cold and humid climates, generate approximately 1100 kWh.
Ionized gas kinematics and chemical abundances of low-mass star-forming galaxies at z  ∼  3
Authors: Llerena M. , Amorín R. , Pentericci L. , Calabrò A. , Shapley A. E. , Boutsia K. , Pérez-Montero E. , Vílchez J. M. , Nakajima K. 
Published: June 2023

Context. Feedback from massive stars plays a crucial role in regulating the growth of young star-forming galaxies (SFGs) and in shaping their interstellar medium (ISM). This feedback contributes to the removal and mixing of metals via galactic outflows and to the clearance of neutral gas, which facilitates the escape of ionizing photons.
Aims. Our goal is to study the impact of stellar feedback on the chemical abundances of the ISM in a sample of SFGs with strong emission lines at z ∼ 3.
Methods. We selected 35 low-mass SFGs (7.9 < log(M⋆/M⊙) < 10.3) from deep spectroscopic surveys based on their CIII]λ1908 emission. We used new follow-up near-infrared (NIR) observations to examine their rest-optical emission lines and to identify ionized outflow signatures through broad emission line wings detected after Gaussian modeling of [OIII]λλ4959,5007 profiles. We characterized the gas-phase metallicity and carbon-to-oxygen (C/O) abundance of the galaxies using a Te-based method via the OIII]λ1666/[OIII]λ5007 ratio and photoionization models.
Results. We find line ratios and rest-frame equivalent widths (EWs) characteristic of high-ionization conditions powered by massive stars. Our sample displays a mean rest-frame EW([OIII]λ5007) of ∼560 Å, while about 15% of the SFGs show EW([OIII]λλ4959,5007)  >  1000 Å and EW(CIII])  >  5 Å, closely resembling those now seen in epoch of reionization (EoR) galaxies with the James Webb Space Telescope. We find high Te values, which imply low gas-phase metallicities 12+log(O/H) ∼ 7.5–8.5 (mean of 17% solar) and C/O abundances from 23% to 128% solar, with no apparent increasing trend with metallicity. Our sample follows the mass-metallicity relation at z ∼ 3, with some galaxies showing lower gas-phase metallicities. This results in significant deviations from the fundamental metallicity relation. From our [OIII]λλ4959,5007 line profile modeling, we find that 65% of our sample shows an outflow component, which is found both blue- or redshifted relative to the ionized gas systemic velocity, and the mean maximum velocities are vmax ∼ 280 km s−1. We find a weak correlation between vmax and the star formation rate surface density (ΣSFR) of vmax = (2.41 ± 0.03) × ΣSFR(0.06 ± 0.03). Moreover, we find that the mass-loading factor μ of our galaxy sample is typically lower than in more massive galaxies from the literature, but it is higher than in typical local dwarf galaxies. In the stellar mass range covered by our sample, we find that μ increases with ΣSFR. This suggests that for a given stellar mass, denser starbursts in low-mass galaxies produce stronger outflows. Our results complement the picture drawn by similar studies at lower redshift, suggesting that the removal of ionized gas in low-mass SFGs driven by stellar feedback is regulated by their stellar mass and by the strength and concentration of their star formation, that is, ΣSFR.
Role of Gene Mutations in Acute Myeloid Leukemia: A Review Article
Authors: Singh Himanshu , Kumar Magesh , Kanungo Himanshu 
Published: June 2023

AbstractAcute myeloid leukemia (AML) is an immensely heterogeneous disease characterized by the clonal growth of promyelocytes or myeloblasts in bone marrow as well as in peripheral blood or tissue.Enhancement in the knowledge of the molecular biology of cancer and recognition of intermittent mutations in AML contribute to favorable circumstances to establish targeted therapies and enhance the clinical outcome. There is high interest in the development of therapies that target definitive abnormalities in AML while eradicating leukemia-initiating cells. In recent years, there has been a better knowledge of the molecular abnormalities that lead to the progression of AML, and the application of new methods in molecular biology techniques has increased that facilitating the advancement of investigational drugs.In this review, literature or information on various gene mutations for AML is discussed. English language articles were scrutinized in plentiful directories or databases like PubMed, Science Direct, Web of Sciences, Google Scholar, and Scopus. The important keywords used for searching databases is “Acute myeloid leukemia”, “Gene mutation in Acute myeloid leukemia”, “Genetic alteration in Acute myeloid leukemia,” and “Genetic abnormalities in Acute myeloid leukemia.”
Improved semi-experimental equilibrium structure and high-level theoretical structures of ketene
Authors: Smith Houston H. , Esselman Brian J. , Wood Samuel A. , Stanton John F. , Woods R. Claude , McMahon Robert J. 
Published: June 2023

The millimeter-wave rotational spectrum of ketene (H2C=C=O) has been collected and analyzed from 130 to 750 GHz, providing highly precise spectroscopic constants from a sextic, S-reduced Hamiltonian in the Ir representation. The chemical synthesis of deuteriated samples allowed spectroscopic measurements of five previously unstudied ketene isotopologues. Combined with previous work, these data provide a new, highly precise, and accurate semi-experimental (reSE) structure for ketene from 32 independent moments of inertia. This reSE structure was determined with the experimental rotational constants of each available isotopologue, together with computed vibration–rotation interaction and electron-mass distribution corrections from coupled-cluster calculations with single, double, and perturbative triple excitations [CCSD(T)/cc-pCVTZ]. The 2σ uncertainties of the reSE parameters are ≤0.0007 Å and 0.014° for the bond distances and angle, respectively. Only S-reduced spectroscopic constants were used in the structure determination due to a breakdown in the A-reduction of the Hamiltonian for the highly prolate ketene species. All four reSE structural parameters agree with the “best theoretical estimate” (BTE) values, which are derived from a high-level computed re structure [CCSD(T)/cc-pCV6Z] with corrections for the use of a finite basis set, the incomplete treatment of electron correlation, relativistic effects, and the diagonal Born–Oppenheimer breakdown. In each case, the computed value of the geometric parameter lies within the statistical experimental uncertainty (2σ) of the corresponding semi-experimental coordinate. The discrepancies between the BTE structure and the reSE structure are 0.0003, 0.0000, and 0.0004 Å for rC–C, rC–H, and rC–O, respectively, and 0.009° for θC–C–H.
General form of axially symmetric stationary metric: exact solutions and conservation laws in vacuum fields
Authors: Jyoti Divya , Kumar Sachin 
Published: June 2023

Abstract
The invariant non-static solutions of Einstein’s vacuum field equations, corresponding to the most general form of axially symmetric stationary line element that represents a non conformally flat semi-Riemannian spacetime in cylindrical coordinates, are investigated. Lie symmetry method is used for symmetry reduction as well as for obtaining exact solutions in terms of arbitrary functions. The conservation laws are obtained for vacuum equations in axially symmetric gravitational fields. The solutions of Lewis metric and Chandrasekhar metric, are derived from the obtained solutions. By considering the possibilities of arbitrary functions, the graphical behaviour of the solutions is also shown.
A generic instability in clustering dark energy?
Authors: Hassani Farbod , Adamek Julian , Kunz Martin , Shi Pan , Wittwer Peter 
Published: June 2023

Abstract
In this paper, we study the effective field theory (EFT) of dark energy (DE) for the k-essence model beyond linear order. Using particle-mesh N-body simulations that consistently solve the DE evolution on a grid, we find that the next-to-leading order in the EFT expansion, which comprises the terms of the equations of motion that are quadratic in the field variables, gives rise to a generic instability in the regime of low speed of sound (high Mach number). We rule out the possibility of a numerical artefact by considering simplified cases in spherically and plane symmetric situations analytically. If the speed of sound vanishes exactly, the non-linear instability makes the evolution singular in finite time, signalling a breakdown of the EFT framework. The case of finite (but small) speed of sound is subtle, and the local singularity could be replaced by some other type of behaviour with strong non-linearities. While an ultraviolet completion may cure the problem in principle, there is no reason why this should be the case in general. As a result, for a large range of the effective speed of sound cs
, a linear treatment is not adequate.
Observables for cyclic causal set cosmologies
Authors: Dowker Fay , Zalel Stav 
Published: June 2023

Abstract
In causal set theory, cycles of cosmic expansion and collapse are modelled by causal sets with ‘breaks’ and ‘posts’ and a special role is played by cyclic dynamics in which the universe goes through perpetual cycles. We identify and characterise two algebras of observables for cyclic dynamics in which the causal set universe has infinitely many breaks. The first algebra is constructed from the cylinder sets associated with finite causal sets that have a single maximal element and offers a new framework for defining cyclic dynamics as random walks on a novel tree. The second algebra is generated by a collection of stem-sets and offers a physical interpretation of the observables in these models as statements about unlabelled stems with a single maximal element. There are analogous theorems for cyclic dynamics in which the causal set universe has infinitely many posts.
Triple interference, non-linear Talbot effect and gravitization of the quantum
Authors: Berglund Per , Geraci Andrew , Hübsch Tristan , Mattingly David , Minic Djordje 
Published: June 2023

Abstract
Recently we have discussed a new approach to the problem of quantum gravity in which the quantum mechanical structures that are traditionally fixed, such as the Fubini–Study metric in the Hilbert space of states, become dynamical and so implement the idea of gravitizing the quantum. In this paper we elaborate on a specific test of this new approach to quantum gravity using triple interference in a varying gravitational field. Our discussion is driven by a profound analogy with recent triple-path interference experiments performed in the context of non-linear optics. We emphasize that the triple interference experiment in a varying gravitational field would deeply influence the present understanding of the kinematics of quantum gravity and quantum gravity phenomenology. We also discuss the non-linear Talbot effect as another striking phenomenological probe of gravitization of the geometry of quantum theory.
Plasma-enhanced atomic layer deposition of nickel and nickel oxide on silicon for photoelectrochemical applications
Authors: O’Donnell S , O’Neill D , Shiel K , Snelgrove M , Jose F , McFeely C , O’Connor R 
Published: June 2023

Abstract
The production of hydrogen fuel through sunlight-driven water splitting has the potential to harness and store large quantities of solar energy in a clean and scalable chemical state, suitable for later use in a range of energy applications. Silicon (Si) possesses many of the required properties to be used effectively as a photoelectrochemical (PEC) water-splitting photoanode. However, its sensitivity to corrosion during the oxygen evolution reaction limits its performance in photoanode applications, thus requiring additional overlayer materials to protect the underlying Si substrate. Nickel oxide (NiO) is one material that acts as an effective protective layer, being transparent, suitably conductive and stable. In this work, we present NiO deposition via state-of-the-art atomic layer deposition and photoemission studies to grow and characterize NiO and Ni–metal protective films. Early-stage nucleation of deposited thin films is illustrated along with the effects of post-deposition annealing and argon milling on depth profile information. Previous reports on the effects of slow argon milling are explored and counter arguments are proposed. Protective films are subjected to PEC testing, which shows enhancement of stability and photocurrent output as a result of the deposited films and plasma annealing on these thin films.
DFT investigation of structural and optoelectronic properties of glassy chalcogenide CuXY2 (X = Sb, Bi; Y = S, Se, Te) molecules
Authors: Ranjan Prabhat , Balasubramanian Krishnan , Chakraborty Tanmoy 
Published: June 2023

Abstract
The structural, electronic, spectral and optical properties of the ternary semiconducting material CuXY2 (X = Sb, Bi; Y = S, Se, Te) are computed using the density functional theory (DFT) technique. The ground-state configurations show that these systems have distorted rhomboidal structures in singlet states. It is found that CuSbY2 possesses higher highest occupied molecular orbital (HOMO) – lowest unoccupied molecular orbital (LUMO) energy gap than CuBiY2. We have employed three different levels of theory (B3LYP/LANL2DZ, relativistic effective—core potentials—CRENBL++, LANL08+) to study the electronic states. The energy gaps of these materials vary from 1.926–2.183 eV and 1.862–2.340 eV, respectively, at different levels of theory, suggesting their suitability as solar cell absorbents. DFT-based global structural descriptors are computed and analyzed with the help of vertical ionization energy and vertical electron affinity. The optical properties, such as optical electronegativity, refractive index, dielectric constant and IR and Raman activity, are studied. Our results show that the optical electronegativity of CuSbY2 is higher than that of CuBiY2 whereas the refractive index of CuSbY2 is smaller than that of CuBiY2. The computed harmonic frequencies and maximum intensities of IR and Raman spectra decline from S to Se to Te for systems CuSbY2 and CuBiY2. Our computed electrostatic potentials and other electronic properties show that CuBiY2 systems differ substantially from CuSbY2 due to relativistic effects on Bi.
Characteristic excitonic absorption of MoSi2N4 and WSi2N4 monolayers
Authors: Liu Hongling , Huang Baibiao , Dai Ying , Wei Wei 
Published: June 2023

Abstract
As new members of the two-dimensional materials family, MoSi2N4 and WSi2N4 exhibit unique physical properties. However, their optical properties in consideration of spin–orbit coupling (SOC) have not been discussed. In this work, the excited-state properties of MoSi2N4 and WSi2N4 monolayers are studied by means of many-body perturbation theory in combination with first-principles calculations. We find that the quasiparticle correction leads to a large band gap renormalization of more than 1 eV for MoSi2N4 and WSi2N4 monolayers. Because of the SOC, characteristic A and B excitons form with large binding energies of about 1 eV. The excitation energy difference of A and B excitons can be used to well address the spin–valley splitting. MoSi2N4 shows more abundant excitons (A′, B′ and C excitons), turning out to be a promising candidate to explore intra- and inter-exciton transitions. The exciton wave function indicates that the low-energy excitons in MoSi2N4 and WSi2N4 monolayers are confined in the middle MoN2/WN2 layer, which is unfavorable for excitonic photocatalysis. On the other hand, the valley states based on excitons can be protected by SiN layers from both sides.
Structure and magnetism of the triangular lattice material YbBO3
Authors: Sala G , Stone Matthew B , Do Seung-Hwan , Taddei Keith M , Zhang Qiang , Halász Gábor B , Lumsden M D , May Andrew F , Christianson Andrew D 
Published: June 2023

Abstract
YbBO3 is a member of the orthoborate family of materials which contains a triangular arrangement of Yb3+ ions. Here we study the physical properties of YbBO3 with neutron diffraction, inelastic neutron scattering, specific heat, and ac susceptibility measurements. The neutron diffraction measurements confirm that our samples of YbBO3 crystallize in the monoclinic space group

C
2

/

c

(#15) which contains two crystallographically distinct Yb3+ sites decorating a slightly distorted triangular lattice. Heat capacity and ac susceptibility measurements indicate a potential transition to magnetic order at 0.4 K. In agreement with these observations, neutron diffraction measurements at 0.044 K observe magnetic Bragg peaks which can be indexed by a propagation vector of (0 0 1). Although determining a unique spin configuration corresponding to the observed magnetic Bragg peaks is not possible, model refinements indicate that the ordered moments are likely in the range of 0.4–0.9

μ
B

and, notably, require moments on both Yb sites. In addition to the magnetic Bragg peaks, diffuse scattering at low Q is observed indicating that the transition does not correspond to complete long range magnetic order. The two-site picture for YbBO3 is further evidenced by the number of crystal field excitations observed by inelastic neutron scattering measurements. Together these results show that YbBO3 is a two-site triangular lattice material with signatures of long-range order as well as shorter ranged spin correlations.
Electrochemical testosterone biosensor based on pencil graphite electrode electrodeposited with copper oxide nanoparticles
Authors: Bozdoğan Betül 
Published: June 2023

Abstract
Accurately monitoring the blood levels of testosterone (TST) in a sensitive, simple, and rapid manner is of paramount importance for the diagnosis and treatment of various medical conditions, as well as for controlling pharmaceutical quality and facilitating doping detection. TST, the primary male sex hormone, plays a crucial role in facilitating human physical performance, protein synthesis, and the development of muscle mass. Consequently, TST and its analogues are frequently abused by athletes as performance-enhancing steroid in order to increase muscle mass and enhance their performance. The use of such steroids is strictly prohibited to guarantee fair play. In this study, we employed a pencil graphite electrode that was electrochemically modified with CuO nanoparticles (CuONPs) for determination of TST. The electrode response was significantly enhanced by approximately fourfold compared to the unmodified pencil graphite electrode (PGE) when electrodeposition CuONPs onto PGE surface was performed at a potential of −0.6 V for 200 s. The success of modification was confirmed through morphological analysis using scanning electron microscopy and energy-dispersive x-ray spectroscopy. Using square wave adsorptive stripping voltammetry analysis in Britton–Robinson buffer at pH 6.0, we demonstrated that the proposed sensor exhibited sensitivity to detect TST within a linear range of 5–200 nM. The detection limit of sensor was calculated 4.6 nM (1.32 ng ml−1). The sensor platform developed for the accurate, sensitive, and specific determination of TST holds tremendous potential for the development of point-of-care devices and their integration into lab-on-a-chip research.