bluuebunny/crossref_metadata_2025_split huggingface dataset:
Evaluation of Sn0.9Fe0.1O2‐δ as Potential Anode Material for Sodium‐Ion Batteries
Authors: Lenzer Anja , Birrozzi Adele , Wirsching Anna‐Lena , Li Yueliang , Geiger Dorin , Kaiser Ute , Asenbauer Jakob , Bresser Dominic 
Published: August 2023

AbstractThe introduction of transition metals such as iron in oxides of alloying elements as, for instance, SnO2 has been proven to enable higher capacities and superior charge storage performance when used as lithium‐ion electrode materials. Herein, we report the evaluation of such electrode materials, precisely (carbon‐coated) Sn0.9Fe0.1O2−δ(−C), for sodium‐ion battery applications. The comparison with SnO2 as reference material reveals the beneficial impact of the presence of iron in the tin oxide lattice, enabling higher specific capacities and a greater reversibility of the de‐/sodiation process – just like for lithium‐ion battery applications. The overall achievable capacity, however, remains relatively low with about 300 mAh g−1 and up to more than 400 mAh g−1 for Sn0.9Fe0.1O2‐δ and Sn0.9Fe0.1O2−δ‐C, respectively, compared to the theoretical specific capacity of more than 1,300 mAh g−1 when assuming a completely reversible alloying and conversion reaction. The subsequently performed ex situ/operando XRD and ex situ TEM/EDX analysis unveils that this limited capacity results from an incomplete de‐/sodiation reaction, thus, providing valuable insights towards an enhanced understanding of alternative reaction mechanisms for sodium‐ion anode material candidates.
Functional partnerships between GPI‐anchored proteins and adhesion GPCRs
Authors: Lin Hsi‐Hsien 
Published: August 2023

AbstractSpecific extracellular interaction between glycophosphatidylinositol (GPI)‐anchored proteins and adhesion G protein‐coupled receptors (aGPCRs) plays an important role in unique biological functions. GPI‐anchored proteins are derived from a novel post‐translational modification of single‐span membrane molecules, while aGPCRs are bona fide seven‐span transmembrane proteins with a long extracellular domain. Although various members of the two structurally‐distinct protein families are known to be involved in a wide range of biological processes, many remain as orphans. Interestingly, accumulating evidence has pointed to a complex interaction and functional synergy between these two protein families. I discuss herein current understanding of specific functional partnerships between GPI‐anchored proteins and aGPCRs.
A path towards enterprise environmental performance improvement: How does CEO green experience matter?
Authors: Li Xin , Guo Fei , Wang Jiaqi 
Published: August 2023

AbstractNudging the amelioration of enterprise environmental performance is the micro‐foundation for effectively enhancing resource utilization and realizing sustainable development. Based on the upper echelons theory, the characteristics and previous experiences of managers determine their strategic choices and then affect the behavior of enterprises at the whole social layer. Nevertheless, the literature concerning the effect of CEO green experience on enterprise environmental performance is void. To bridge this gap, this paper uses the data of China's A‐share listed enterprises from 2010 to 2021 to empirically investigate the direct impact, influence mechanisms, and heterogeneities of CEO green experience on enterprise environmental performance. The study finds that CEO green experience can significantly promote the improvement of enterprise environmental performance. Based on the main effect, to exploring potential mechanisms behind the conclusion, we figure that environmental ethics commitment, environmental protection investment, and green technology innovation are the core mechanism approaches during the process of CEO green experience affects environmental performance. Heterogeneity analysis of CEO characteristics demonstrates that the green experience of female CEOs, older CEOs, and high educated CEOs both have a pronounced effect on ameliorating enterprise environmental performance. Furthermore, the positive effect of CEO green experience on environmental performance is more prominent in non‐state‐owned enterprises, heavily polluting industries, and regions with high environmental protection pressure. Besides providing an effective supplement for the research on managers and environmental performance, this paper also generates micro‐empirical support for government departments to formulate and optimize environmental policies.
Time‐trends and age and stage differences in 5‐year relative survival for common cancer types by sex in the canton of Zurich, Switzerland
Authors: Wanner Miriam , Syleouni Maria‐Eleni , Karavasiloglou Nena , Limam Manuela , Bastiaannet Esther , Korol Dimitri , Rohrmann Sabine 
Published: August 2023

AbstractBackgroundSurvival trends help to evaluate the progress made to reduce the burden of cancer. The aim was to estimate the trends in 5‐year relative survival of patients diagnosed with breast, prostate, lung, colorectal cancer and skin melanoma in the time periods 1980–1989, 1990–1999, 2000–2009 and 2010–2015 in the Canton of Zurich, Switzerland. Furthermore, we investigated relative survival differences by TNM stage and age group.MethodsData from the Cancer Registry of Zurich was used from 1980 to and including 2015, including incident cases of breast (N = 26,060), prostate (N= 23,858), colorectal (N= 19,305), lung cancer (N= 16,858) and skin melanoma (N= 9780) with follow‐up until 31 December 2020. The cohort approach was used to estimate 5‐year relative survival.ResultsThe 5‐year relative survival increased significantly between 1980 and 1989, and 2010 and2015: from 0.70 to 0.89 for breast, from 0.60 to 0.92 for prostate, from 0.09 to 0.23 (men) and from 0.10 to 0.27 (women) for lung, from 0.46 to 0.66 (men) and from 0.48 to 0.68 (women) for colorectal cancer, and from 0.74 to 0.94 (men) and from 0.86 to 0.96 (women) for skin melanoma. Survival for stage IV tumors was considerably lower compared to lower‐staged tumors for all cancer types. Furthermore, relative survival was similar for the age groups <80 years but lower for patients aged 80 years and older.ConclusionThe observed increasing trends in survival are encouraging and likely reflect raised awareness around cancer, improved diagnostic methods, and improved treatments. The fact that stage I tumor patients have generally high relative survival reflects the efforts made regarding early detection.
Real‐time reconstruction of pipes using RGB‐D cameras
Authors: Kim Dong‐Min , Ahn JeongHyeon , Kim Seung‐wook , Lee Jongmin , Kim Myungho , Han JungHyun 
Published: August 2023

AbstractThis paper presents a novel method that automatically reconstructs pipes in real time using an RGB‐D camera. The input image is decomposed into superpixels, and a pipe element, which is a 3D circle lying on the pipe surface, is generated for each superpixel. Over frames, the pipe elements are grouped into sequences and are finally modeled in parametric equations. The method is tested in daily settings, where the pipes may be curved and their radii may vary along the axes. The test results show that the method is able to reconstruct pipes efficiently, precisely and robustly.
Hand‐painted yuzen‐dyeing simulation for online handcraft experience
Authors: Torii Takuma 
Published: August 2023

AbstractOn‐site workshops provide an opportunity to learn the craftsmanship, but the first hurdle is often high. Online handcraft experiences can be a solution to this first hurdle by providing preliminary craft experience from anywhere on the internet. In collaboration with a traditional craftsman, this motivated us to develop an online simulator for a thin‐brush dyeing, called yuzen, one of the Japanese traditional handcrafts innovated in the 17th century. The goal of this simulator is providing easy‐going experience, that is, it can be materially unrealistic but mimicking visual appearance. The simulator incorporates various characteristics of yuzen, by which the developed 2D fluid simulation algorithm reduces its computational burden. The yuzen dyeing algorithm is similar to an existing ink‐wash painting algorithm, but the present work provides (1) theoretical justification for the algorithm and parameter choices, (2) implementing yuzen dyeing‐specific characteristics, and (3a) a physical experiment to examine qualitative resemblance, and (3b) to identify unknown physical parameters for further reality in future development.
Towards Ruthenium(II)‐Rhenium(I) Binuclear Complexes as Photosensitizers for Photodynamic Therapy
Authors: Wang Youchao , Felder Patrick S. , Mesdom Pierre , Blacque Olivier , Mindt Thomas L. , Cariou Kevin , Gasser Gilles 
Published: August 2023

AbstractThe search for new metal‐based photosensitizers (PSs) for anticancer photodynamic therapy (PDT) is a fast‐developing field of research. Knowing that polymetallic complexes bear a high potential as PDT PSs, in this study, we aimed at combining the known photophysical properties of a rhenium(I) tricarbonyl complex and a ruthenium(II) polypyridyl complex to prepare a ruthenium‐rhenium binuclear complex that could act as a PS for anticancer PDT. Herein, we present the synthesis and characterization of such a system and discuss its stability in aqueous solution. In addition, one of our complexes prepared, which localized in mitochondria, was found to have some degree of selectivity towards two types of cancerous cells: human lung carcinoma A549 and human colon colorectal adenocarcinoma HT29, with interesting photo‐index (PI) values of 135.1 and 256.4, respectively, compared to noncancerous retinal pigment epithelium RPE1 cells (22.4).
A hunting arrow traumatism to the head: A case report from Niger
Authors: Ibrahim Assoumane Issa , Murhega Roméo Bujiriri , Samuila Sanoussi 
Published: August 2023

Key Clinical MessageArrow injuries have not disappeared in our environment despite the advances in the development of warfare tools in the world. All regions of the body can be the target of these arrows and in particular the cephalic region whose gravity will depend on the structures reached.AbstractWith the development of modern weapons of war, arrow wounds have become rare in developed countries, but they are still common in developing countries, including Niger. These injuries are often serious and life‐threatening when they are in the head and neck region, due to the presence of major vessels and vital organs in these areas of the body. Extraction of these arrows is usually difficult due to the proximity of major vital structures. Unskilled extraction can aggravate the injury or result in unintentional damage to vital structures with imminent risk of death. We present the case of a patient with a homemade arrow to the head in the left periorbital region that we successfully extracted at the National Hospital in Niamey. Our objective is to highlight the experience with this patient and review some reports in the literature.
Freeze‐Thawed Nafion‐Poly(vinyl alcohol) Self‐healing Membranes for Direct Methanol Fuel Cells
Authors: Ng Wei Wuen , Thiam Hui San , Pang Yean Ling , Lim Yun Seng , Wong Jianhui , Lai Soon Onn 
Published: August 2023

AbstractSelf‐healing proton‐exchange membranes (PEMs) made of poly(vinyl alcohol) (PVA) and Nafion were synthesized using the freeze‐thaw method. Since PVA is more selective towards water than methanol, the blend membrane successfully reduced methanol permeability and improved selectivity compared to the recast Nafion membrane. The addition of PVA also helped the membrane self‐heal by promoting the formation of hydrogen bonds. In contrast to the pristine Nafion, which exhibited even more severe methanol crossover after being damaged than before, the Nafion‐PVA membrane underwent a self‐healing process and regained much of its methanol barrier function. These advantageous characteristics of the Nafion‐PVA membrane suggest its potential use in direct methanol fuel cells (DMFCs).
Interaction Between the Transferrin Protein and Plutonium (and Thorium), What's New?
Authors: Zurita Cyril , Tsushima Satoru , Solari Pier Lorenzo , Menut Denis , Dourdain Sandrine , Jeanson Aurélie , Creff Gaëlle , Den Auwer Christophe 
Published: August 2023

AbstractTransferrin (Tf) is a glycoprotein that transports iron from the serum to the various organs. Several studies have highlighted that Tf can interact with metals other than Fe(III), including actinides that are chemical and radiological toxics. We propose here to report on the behavior of Th(IV) and Pu(IV) in comparison with Fe(III) upon Tf complexation. We considered UV‐Vis and IR data of the M2Tf complex (M=Fe, Th, Pu) and combined experimental EXAFS data with MD models. EXAFS data of the first M−O coordination sphere are consistent with the MD model considering 1 synergistic carbonate. Further EXAFS data analysis strongly suggests that contamination by Th/Pu colloids seems to occur upon Tf complexation, but it seems limited. SAXS data have also been recorded for all complexes and also after the addition of Deferoxamine‐B (DFOB) in the medium. The Rg values are very close for apoTf, ThTf and PuTf, but slightly larger than for holoTf. Data suggest that the structure of the protein is more ellipsoidal than spherical, with a flattened oblate form. From this data, the following order of conformation size might be considered:holoTf<M2Tf (M=Th, Pu)<apoTf<M2Tf‐DFOB (M=Fe, Th, Pu).
Low‐Pressure Sensitive Piezochromic Fluorescence Switching of Tetraphenylethylene‐Anthraquinone
Authors: Wei Yude , Yang Runqing , Cui Guangzhen , Dai Shuting , Pan Guocui , Wang Jing , Ren Haoxuan , Ma Wenyue , Gu Zijian , Zhang Chenchen , Li Guangming , Liu Zhaoyang , Xu Bin , Tian Wenjing 
Published: August 2023

AbstractInvited for the cover of this issue are Prof. Wenjing Tian and co‐workers at Jilin University. The image depicts the highly sensitive piezochromic fluorescence switching of tetraphenylethylene‐anthraquinone under low‐pressure regimes (∼60 kPa). Read the full text of the article at 10.1002/chem.202301070.
Global optimization of the design of intensified shell and tube heat exchanger using tube inserts
Authors: Chang Chenglin , Shen Weifeng 
Published: August 2023

AbstractThis paper investigates global optimization of the detailed design of intensified shell and tube heat exchangers using two tube inserts: twisted tape and coiled wire. Three objectives, including heat exchanger area, total annualized cost, and environmental impact, are respectively minimized. All the design variables are considered as the ones that have discrete values based on their physical nature or manufacturing standards. We present, for the first time, a tailored global optimization approach for the design of intensified shell and tube heat exchanger: Set trimming procedure. We compare the computational performance of our set trimming procedure, exhaustive enumeration, and commercial solvers. The proposed three objectives have certain competitive relationships and multi‐objective optimization is performed to analyze the conflicts among them. Two literature examples are tested for illustration purposes. The solution results indicate that the intensified heat exchanger designed using tube inserts compares well to the regular heat exchanger using plain tube. Compared with commercial solvers, set trimming procedure runs fast and can converge to global optimum without initial value. The pareto‐optimal solutions of multi‐objective optimization provide holistic trade‐offs between different objectives, hence helping the process designer make proper decisions for the design of intensified shell and tube heat exchangers.
Fe‐Doped CoS2 Nanoarrays: Efficient Electrocatalytic Nitrate Reduction to Ammonia under Ambient Conditions
Authors: Lu Xiaoliang , Zhou Jinzhi , Zhao Jinxiu , Wu Dan , Liu Xuejing , Ren Xiang , Wei Qin , Ju Huangxian 
Published: August 2023

AbstractThe electrocatalytic nitrate reduction reaction (NO3−RR) enables the reduction of nitrate to ammonium ions under ambient conditions. It was considered as an alternative reaction for the production of ammonia (NH3) in recent years. In this paper, we report that the Fe doping CoS2 nanoarrays can effectively catalyze the formation of NH3 from nitrate (NO3−) under ambient conditions. This is mainly due to the increase of the NO3− reaction active site by Fe doping and the porous nanostructure of the catalyst, which greatly improves the catalytic activity. Specifically, at −0.9 V vs. RHE, the NH3 yield rate (RNH3) of Fe−CoS2/CC is 17.8×10−2 mmol h−1 cm−2 with Faraday Efficiency (FE) of 88.93 %. Besides, such catalyst shows good durability and catalytic stability, which provides the possibility for the future application of electrocatalytic NH3 production.
Investigations into Annona fruit consumption as a potential source of dietary higenamine intake in the context of sports drug testing
Authors: Rubio Ana , Thomas Andreas , Euler Luisa , Geyer Hans , Krug Oliver , Reis Gabriel , Padilha Monica Costa , Pereira Henrique Marcelo Gualberto , Muniz‐Santos Renan , Cameron Luiz Claudio , Stojanovic Biljana , Kuehne Dirk , Lagojda Andreas , McLeod Malcolm Donald , Thevis Mario 
Published: August 2023

AbstractHigenamine is prohibited in sports as a β2‐agonist by the World Anti‐Doping Agency. As a key component of a great variety of plants, including the Annonaceae family, one aim of this research project was to evaluate whether the ingestion of Annona fruit could lead to higenamine adverse analytical findings. Single‐dose administration studies including three Annona species (i.e., Annona muricata, Annona cherimola, and Annona squamosa) were conducted, leading to higenamine findings below the established minimum reporting level (MRL) of 10 ng/mL in urine. In consideration of cmax values (7.8 ng/mL) observed for higenamine up to 24 h, a multidose administration study was also conducted, indicating cumulative effects, which can increase the risk of exceeding the applicable MRL doping after Annona fruit ingestion. In this study, however, the MRL was not exceeded at any time point. Further, the major urinary excretion of higenamine in its sulfo‐conjugated form was corroborated, its stability in urine was assessed, and in the absence of reference material, higenamine sulfo‐conjugates were synthesized and comprehensively characterized, suggesting the predominant presence of higenamine 7‐sulfate. In addition, the option to include complementary biomarkers of diet‐related higenamine intake into routine doping controls was investigated. A characteristic urinary pattern attributed to isococlaurine, reticuline, and a yet not fully characterized bismethylated higenamine glucuronide was observed after Annona ingestion but not after supplement use, providing a promising dataset of urinary biomarkers, which supports the discrimination between different sources of urinary higenamine detected in sports drug testing programs.
Potential electrolytes for solid state batteries and its electrochemical analysis—A review
Authors: Zulfiqar Zunaira , Zulfiqar Sadaf , Abbas Qaisar , Mirzaeian M. , Raza Rizwan 
Published: August 2023

AbstractThe main purpose of this review is to present comprehensive research on all solid‐state electrolytes in a single frame. In next‐generation rechargeable solid‐state batteries, the solid‐state electrolytes are well known for their thermal stability, ionic conduction, and electrochemical stability. Therefore, in scientific societies, the development of potential solid‐state electrolytes become a trending debate to enhance their cycling stability and electrochemical properties. Here, the recent development of all solid electrolytes (such as ceramic and structure‐based electrolytes) to enhance their electrochemical properties is summarized. From previous studies, the installation of solid electrolytes is hindered by the following factors electrode‐electrolyte interface, dendrite growth, and discharge capacity as well as its solutions are discussed. Additionally, advanced electrochemical characterization techniques such as electrochemical impedance spectroscopy, cyclic voltammetry, and galvanostatic charging and discharging used to evaluate the electrochemical behavior of electrolytes in the solid frame are summarized for the first time. Moreover, an up‐to‐date article on battery performance with potential electrolytes and some future perspectives also give a vivid image of the pragmatic applications of these batteries at the commercial level.
Improving older adults' autobiographical memory through video‐conferencing intervention during COVID‐19
Authors: Jung Dawoon , Choi Juhee , Park Soohyun , Choi Kee‐Hong 
Published: August 2023

AbstractBackgroundAutobiographical memory (AM) is valuable not only as an indicator of mental health and cognitive function, but also as a target of therapeutic intervention for older adults. In the context of the COVID‐19 pandemic, the demand for online psychosocial interventions and assessment services has sharply increased. Thus, the present study examined the effectiveness of videoconferencing AM (vAM) intervention using the Ecological Momentary Assessment (EMA) method in addition to the traditional paper‐and‐pencil assessment among samples of community dwelling older adults.MethodsTwenty‐seven older adults (aged 66–86 years) participated in a vAM intervention composed of 4 weekly 90‐min sessions. The primary outcome was AM specificity, with secondary outcomes as depressive symptom and cognitive function, measured before and after the intervention. In addition, daily emotions were measured through EMA over 4 weeks of intervention. The EMA data were analyzed using a multilevel analysis.ResultsThe results showed low dropout rates (7%) and high EMA response rates (85%). Autobiographical memory specificity increased (Cohen's d = 0.678), and the level of depression declined significantly (Cohen's d = 0.375) after the program. Additionally, measures assessing cognitive function, such as Seoul Verbal Learning Test and DSC (Digit Symbol Coding), showed significant improvements. The EMA results indicated a decrease in the intensity and proportion of negative emotions experienced during the program.ConclusionsThis study is the first to utilize videoconferencing and EMA to deliver an AM intervention targeting older adults. The intervention was effective in improving mental health and cognitive function, including AM in older adults. Additionally, EMA was found to be a feasible tool for use in older adults.
The health, economic and social burden of smoking in Argentina, and the impact of increasing tobacco taxes in a context of illicit trade
Authors: Palacios Alfredo , Alcaraz Andrea , Casarini Agustín , Rodriguez Cairoli Federico , Espinola Natalia , Balan Dario , Perelli Lucas , Augustovski Federico , Bardach Ariel , Pichon‐Riviere Andrés 
Published: August 2023

AbstractTobacco tax increases, the most cost‐effective measure in reducing consumption, remain underutilized in low and middle‐income countries. This study estimates the health and economic burden of smoking in Argentina and forecasts the benefits of tobacco tax hikes, accounting for the potential effects of illicit trade. Using a probabilistic Markov microsimulation model, this study quantifies smoking‐related deaths, health events, and societal costs. The model also estimates the health and economic benefits of different increases in the price of cigarettes through taxes. Annually, smoking causes 45,000 deaths and 221,000 health events in Argentina, costing USD 2782 million in direct medical expenses, USD 1470 million in labor productivity loss costs, and USD 1069 million in informal care costs—totaling 1.2% of the national gross domestic product. Even in a scenario that considers illicit trade of tobacco products, a 50% cigarette price increase through taxes could yield USD 8292 million in total economic benefits accumulated over a decade. Consequently, raising tobacco taxes could significantly reduce the health and economic burdens of smoking in Argentina while increasing fiscal revenue.