bluuebunny/crossref_metadata_2025_split huggingface dataset:
Distinct photochemistry in glycine particles mixed with different atmospheric nitrate salts
Authors: Liang Zhancong , Cheng Zhihao , Zhang Ruifeng , Qin Yiming , Chan Chak K. 
Published: August 2023

Abstract. Particulate free amino acids (FAAs) are essential components of organonitrogen that have critical climate impacts, and they are usually considered stable end-products from protein degradation. In this work, we investigated the decay of glycine (GC) as a model FAA under the photolysis of different particulate nitrate salts using an in situ Micro-Raman system. Upon cycling the relative humidity (RH) between 3 % and 80 % RH, ammonium nitrate (AN) and GC mixed particles did not exhibit any phase change, whereas sodium nitrate (SN) and GC mixed particles crystallized at 60 % and deliquesced at 82 % RH. Under light illumination at 80 % RH, AN + GC particles showed almost no spectral changes, while rapid decays of glycine and nitrate were observed in SN + GC particles. The interactions between nitrate and glycine in AN + GC particles suppressed crystallization but also hindered nitrate photolysis and glycine decay. On the other hand, glycine may form a complex with Na+ in deliquescent SN + GC particles and allow unbonded nitrate to undergo photolysis and trigger glycine decay, though nitrate photolysis was greatly hindered upon particle crystallization. Our work provides insights into how FAAs may interact with different nitrate salts under irradiation and lead to distinct decay rates, which facilitates their atmospheric lifetime estimation.
Predicting soil hydraulic properties for binary mixtures – concept and application for constructed Technosols
Authors: Willaredt Moreen , Nehls Thomas , Peters Andre 
Published: August 2023

Abstract. Constructed Technosols are an important means of substituting natural soil material, such as peat and geogenic material, for use in urban green infrastructure. One characteristic of Technosols important to their role in urban green infrastructure, specifically with respect to urban water management, is their soil hydraulic properties (SHPs). The SHPs depend on the composition of the constructed Technosols (e.g. their components and their mixing ratio). The diversity of possible components and the infinite number of mixing ratios practically prohibit the experimental identification of the composition needed to achieve suitable soil hydrological functions. In this study, we propose a compositional model for predicting the water retention curves (WRCs) of any binary mixture based on the measured WRCs of its two pure components only (basic scheme) or with one additional mixture (extended scheme). The unsaturated hydraulic conductivity curves (HCCs) are predicted based on the modelled WRCs.
The compositional model is developed from existing methods for estimating the porosity of binary mixtures. The model was tested on four data sets of measured WRCs of different binary mixtures. The distribution of water and air in 50 cm high soil columns filled with these mixtures was predicted under hydrostatic conditions in order to assess their suitability for typical urban applications. The difference between the maxima of the pore size distributions ΔPSDmax (m) of the components indicates the applicability of the compositional approach. For binary mixtures with small ΔPSDmax, the water content deviations between the predicted and the measured WRCs range from 0.004 to 0.039 cm3 cm−3. For mixtures with a large ΔPSDmax, the compositional model is not applicable. The prediction of the soil hydraulic properties of any mixing ratio facilitates the simulation of flow and transport processes in constructed Technosols before they are produced (e.g. for specific urban water management purposes).
Brief communication: The Glacier Loss Day as an indicator of a record-breaking negative glacier mass balance in 2022
Authors: Voordendag Annelies , Prinz Rainer , Schuster Lilian , Kaser Georg 
Published: August 2023

Abstract. In the hydrological year 2021/2022, Alpine glaciers showed unprecedented mass loss. On Hintereisferner (Ötztal Alps, Austria), the glacier-wide mass balance was −3319 kg m−2. Near-daily observations of the surface elevation changes from a permanent terrestrial laser scanning set-up allowed the determination of the day when the mass balance of Hintereisferner started to become negative. This Glacier Loss Day (GLD) was already reached on 23 June in 2022 and gave way to a long ice ablation period. In 2021/2022, this and the high cumulative positive degree days explain the record-breaking mass loss. By comparing the GLDs of 2019/2020–2021/2022, we found a gross yet expressive indicator of the glacier's imbalance with the persistently warming climate.
Multiple-peak traveling waves of the Gray-Scott model
Authors: Chen Xinfu , Lai Xin , Qin Cong , Qi Yuanwei , Zhang Yajing 
Published: August 2023

We study a reaction-diffusion system which models the pre-mixed isothermal autocatalytic chemical reaction of order m (m > 1) between two chemical species, a reactant A and an auto-catalyst B, A + m B --> (m+1) B, and a linear decay B -->C, where C is an inert product. The special case of m = 2 is the much studied Gray-Scott model, but without feeding. We prove existence of multiple traveling waves which have distinctive number of local maximaor peaks. It shows a new and very distinctive feature of Gray-Scott type of models in generating rich and structurally different traveling pulses than related models in literature such as isothermal autocatalysis without decay, or a bio-reactor model with isothermal autocatalysis of order m + 1 with m-th order of decay.
Effectiveness of 'motivational interviewing' on sick leave: a randomized controlled trial in a social insurance setting
Authors: Aasdahl Lene , Standal Martin Inge , Hagen Roger , Solbjør Marit , Bagøien Gunnhild , Fossen Heidi , Foldal Vegard Stolsmo , Bjørngaard Johan Håkon , Rysstad Tarjei , Grotle Margreth , Johnsen Roar , Fors Egil A 
Published: August 2023

OBJECTIVE: This study aimed to evaluate the effectiveness of motivational interviewing (MI) – a counselling approach offered by caseworkers at the Norwegian Labor and Welfare Administration (NAV) – on return to work (RTW) for individuals sick-listed for ≥8 weeks due to any diagnoses. MI was compared to usual case management and an active control during 12 months of follow-up.
METHODS: In a randomized clinical trial with three parallel arms, participants were randomized to MI (N=257), usual case management (N=266), or an active control group (N=252). MI consisted of two MI sessions while the active control involved two sessions without MI, both were offered in addition to usual case management. The primary outcome was number of sickness absence days based on registry data. Secondary outcomes included time to sustainable RTW, defined as four consecutive weeks without medical benefits.
RESULTS: The median number of sickness absence days for the MI group was 73 days [interquartile range (IQR) 31–147], 76 days (35–134) for usual care, and 75 days (34–155) for active control. In total 89%, 88% and 86% of the participants, respectively, achieved sustainable RTW. The adjusted hazard ratio (HR) for time to sustainable RTW was 1.12 (95% CI 0.90–1.40) for MI compared to usual case management and HR 1.16 (95% CI 0.93–1.44) compared to the active control.
CONCLUSIONS: This study did not provide evidence that MI offered by NAV caseworkers to sick-listed individuals was more effective on RTW than usual case management or an active control. Providing MI in this context could be challenging as only half of the MI group received the intervention.
EFEKTIVITAS MEDIA KARTU BERGAMBAR DALAM MENULIS HURUF HIRAGANA SISWA DI SMA NEGERI 1 TONDANO
Authors: Kuhuwael Wenanda 
Published: August 2023

Efektivitas Media Kartu Bergambar Terhadap Kemampuan Menulis Huruf Hiragana Siswa Di SMA Negeri 1 Tondano“. Media kartu bergambar ini merupakan salah satu media pembelajaran bagi tingkat pemula khususnya pelajar, kartu ini memuat masing-masing huruf Hiragana, cara baca dan urutan penulisannya untuk meningkatkan aktivitas berfikir, mempermudah daya ingat siswa dan meningkatkan penguasaan huruf Hiragana. Tujuan penelitian ini untuk mendeskripsikan kemampuan siswa dalam menulis huruf Hiragana sebelum dan sesudah menggunakan media kartu bergambar. Penelitian ini dilaksanakan di SMA Negeri 1 Tondano, dengan populasi siswa kelas X Bahasa sebanyak 40 orang siswa. Sampel yang digunakan adalah 20 orang siswa. Metode penelitian yang digunakan adalah metode true experimental design dengan menggunakan desain Pretest-Posttest Control Group Design. Teknik analisis data yang digunakan adalah teknik statistic uji-t. Hasil penelitian ini menunjukkan bahwa terdapat pengaruh yang signifikan dengan menggunakan media kartu bergambar dalam penguasaan menulis huruf Hiragana bahasa Jepang. Hal ini dibuktikan dari rata-rata hasil belajar siswa pada kelas eksperiment 68 dan pada kelas kontrol 55,9, dan dari hasil hipotesis dengan menggunakan statistic uji-t diperoleh hasil dimana = 4,78 dari pada = 1,68 sehingga nilai rata-rata hasil belajar siswa yang diajarkan dengan menggunakan media kartu bergambar lebih baik dari rata-rata hasil belajar siswa yang tidak menggunakan media kartu bergambar.
MORAL VALUES IN LADY GAGA’S SELECTED SONGS LYRIC
Authors: Alouw Yuni E. , Oroh Elizabeth Z. , Olii Sanerita T. 
Published: August 2023

The purpose of this study is to reveal the moral values found in Lady Gaga’s selected songs. This research is a qualitative research since the data gathered are in the form of words rather than numbers. In analyze the data; the writer used objective approach because the data were taken only from the work itself, the study only focused on moral values found only in Lady Gaga’s selected song lyrics. The result show that There are four songs that full contain moral values. Born This Way morally tells about originality that needs to be sustained by human. Til It Hapens To You is a song to express the pain of women who become the victims of violation and sexual assault, Grigio Girls is composed to describe the mental strenth of female friends who got cancer and how they keep sustaining their life and Angel Down is about abuse of teenager, comes from the experience when a teenager was shot by neighbour, implying there is no care and protection to teens in their period of growth to future maturity, Til It Hapens To You is mainly about social moral that women needs to appreciated and respected, Grigio Girls delivers individual moral that tells that each individual needs to be strong and brave to face even hardest phase in life in this case cancer as acute disease, and Angel Down conveys social moral value with its concern to teenangers that needs to be given special attention in family and society.
Keywords : Dynamic, Sisterhood Relationship, Moral Values, Literature.
The Pattern and Outcome of Management of Acquired Anorectal fistulas in Children at a semi-urban Teaching Hospital
Authors: Olori Samson , Osagie Olabisi O 
Published: August 2023

Background: Acquired anorectal fistulas are a severe cause for parental concerns, and they pose considerable challenges in their management.
Aim: The aim of this study is to document the pattern of presentation and the management outcome for the cases of acquired anorectal fistula in children seen in our centre.
Method: A retrospective review of the thirteen (13) case notes of the patients with acquired anorectal fistulas managed from 2008-2011 was done. The information retrieved included; the age at presentation, sex, aetiology of the fistula, site of the fistula, the duration of the fistula to the presentation, weight loss, and other associated medical conditions, history of a developmental milestone,type of intervention, the outcome of management, HIVstatus of patients and parents.
Results: There were two males and eleven females; eight of whom were HIV positive. Five fistulas were due to each to faecal impaction, birth trauma, trauma from rectal enema procedure, iatrogenic following posterior sagittal ano-rectoplasty (PSARP) andsexual abuse respectively.
Conclusion: The fistula healing outcome for acquired anorectal fistula in HIV positive cases was weak compared to the trauma-related groups.
Severe Conjunctival Papilloma in a Six year old female - Case report
Authors: Chipeta George N. , Muma Kangwa I. M. 
Published: August 2023

Conjunctival papilloma is a benign growth arising from the stratified squamous epithelium of the conjunctiva. It is mostly a self-limiting growth. Conjunctival papilloma occurs commonly in male adults especially in their third and fourth decades of life. It rarely occurs in children. This is a case report of a six (6) year-old female patient who was seen at the Solwezi General Hospital Eye Clinic (SGHEC) with complaints of difficulties in seeing, sandy sensation and tearing of the right eye. The patient had a twelve-month history of multiple fleshy growths on the conjunctival surface of the right eye, referred from a rural health centre in the District. A clinical diagnosis of conjunctival papilloma was made at SGHEC and the child was referred to Kitwe Teaching Eye Hospitals (KTEH) for furthermanagement. At Kitwe Teaching Eye Hospital, a successful excisional biopsy of the conjunctival papilloma lesions on the right eye was conducted with adjunctive therapy of Mitomycin-C intraoperatively, and topical chemotherapy of 5- fluorouracil (5-FU) after surgery. A definitive diagnosis of Benign Conjunctival Papilloma was confirmed for the patient's condition, based on the results from the histopathology samples that were sent to the Cancer Disease Hospital in Lusaka.
Evaluation of Serum Calcium Levels in a Cohort of Head Injured Patients: A Prospective Observational Study
Authors: Oyemolade Toyin Ayofe , Adeolu Augustine , Baogun James , Badejo Oluwakemi , Oluremi Omolola 
Published: August 2023

Objectives:Serum calcium abnormalities in head injurycanresultinanumberofclinicalmanifestations which may worsen outcome. The serum level of calcium is not routinely measured in head injured patients in our country. This study aims to determine the incidence of deranged serum calcium level in a cohort of head injured patients in Nigerian and relate this to injury severity and management outcomeMaterials and

Methods:This was a prospective observational study of head injured patient who presented at our center within 24 hours of trauma during the study period. Clinical and demographic characteristics as well as admission serum calcium levels were analysed using the Statistical Package for the Social Sciences (SPSS). The outcome measureswereserumcalciumlevelsandmanagement outcome. Ap-value less than 0.05 was considered as statistically significant.Results:There were 114 patients in the study, 89 males and 25 females (M:F- 3.7:1). The mean age was 31.2±15.8 years. Head injury was severe in 18.42% of the patients, moderate in 22.81% and mild in 58.77% (Table 1). The serum calcium ranged from6.60-10.42mg/dlwithameanof8.62±0.83mg/dl. Serum calcium level was normal in 55.26% of the cases, and low in 44.74% (Fig. 2). There was no correlation between serum calcium level and severity of injury (p=0.667) or outcome of head injury (p=0.973) in this study.

Conclusion:Derangement in admission serum calcium was common in our patients with almost half of our patients presenting with hypocalcaemia. However, there was no correlation between serum calcium level and severity of injury or outcome of head injury in this study.
Analysis Of Factors Influencing Souvenir Buying Decisions (Study On Gmmtv Fans In Jabodetabek)
Authors: Syahidah Hanna Asma , Nurmahdi Adi 
Published: August 2023

The purpose of this study is to determine and assess the impact of fan loyalty and price perceptions on the decision to purchase GMMTV souvenirs, with product placement serving as a moderating variable. The subjects of this study were Jabodetabek fans who had purchased souvenirs. The sample size in this study was determined using Hair's formula, resulting in a sample size of 120 participants. This study was carried out by delivering questionnaires to 141 respondents. The research hypothesis was tested using SmartPLS 4.0 software and a Partial Least Square (PLS) based Structural Equation Model (SEM). The variables that are examined in this study are fan loyalty, price perceptions, product placement, and purchasing decisions. In this study, data were tested using the Measurement Model Test (Outer Model) and the Structural Model Test (Inner Model). According to the findings, customer purchasing decisions for GMMTV souvenirs are influenced by the variables of fan loyalty, price perception, and product placement individually. The results for each fan loyalty and price perception variable, however, varied when the relationship between fan loyalty and price perception was tested using the mediating variable of product placement. Price perception has a considerable influence on purchase decisions when mediated by the product placement variable, as evidenced by a t-statistic value of 2.006 and a p-value of 0.045. Price perception has a considerable influence on purchase decisions when mediated by the product placement variable, as evidenced by a t-statistic value of 2.006 and a p-value of 0.045. Meanwhile, with a t-statistic of 1.410 and a p-value of 0.159, the fan loyalty variable mediated by product placement on purchase decisions has no effect, and the hypothesis is rejected.
Internationale sancties: leuker kunnen we het niet maken, wel makkelijker
Authors: van der Aa N.M.D. 
Published: August 2023

Internationale sancties: leuker kunnen we het niet maken, wel makkelijker
De EU-sancties tegen Rusland zijn op onderdelen onduidelijk. In dit redactioneel analyseert de auteur waar die onduidelijkheid vandaan komt, doet hij enkele voorstellen om die onduidelijkheid weg te nemen en bespreekt hij hoe in het strafrecht moet worden omgegaan met deze onduidelijkheid, in het bijzonder in het kader van het leerstuk van kleurloos opzet.
De asset freeze: vaker ingezet, ruimer uitgelegd?
Authors: van den Oord I.M. , Strijder J.J. 
Published: August 2023

De asset freeze: vaker ingezet, ruimer uitgelegd?
De afgelopen 16 maanden heeft de bekendheid van het concept ‘bevriezingsmaatregelen’ een vlucht genomen. Sinds de Russische inval in Oekraïne in februari 2022 heeft de EU aan honderden personen en entiteiten een bevriezingsmaatregel opgelegd. Door zo’n maatregel worden hun tegoeden en economische middelen in de EU geblokkeerd. De grotere economische verwevenheid tussen de EU en Rusland zorgt ervoor dat meer Europese bedrijven deze bevriezingsmaatregel tegenkomen. Mede daarom zijn er meerdere ontwikkelingen geweest waarbij de toepassing van deze bevriezingsmaatregelen nader is uitgewerkt. In deze bijdrage staan de auteurs stil bij een aantal van deze ontwikkelingen.
Plaatsing op de sanctielijst: voldoende onderbouwd?
Authors: Buruma T.M.D. 
Published: August 2023

Plaatsing op de sanctielijst: voldoende onderbouwd?
De beslissing om een entiteit op een sanctielijst te plaatsen vereist weinig onderbouwing. Desondanks blijken er geregeld problemen te zijn met het gebruikte bewijs of is het tijdsverloop onvoldoende meegewogen. Het loont dan ook op te komen tegen plaatsingsbeslissingen. Op dit moment echter leunt de kwaliteit van beslissingen te veel op de mate waarin tegen de plaatsingsbeslissing wordt opgekomen. Daardoor bestaat de vrees dat veel entiteiten op onvoldoende onderbouwde gronden op sanctielijsten zijn beland.
Modernisering van de Sanctiewet 1977: de (nieuwe) rol van het bestuursrecht
Authors: Strijder J.J. 
Published: August 2023

Modernisering van de Sanctiewet 1977: de (nieuwe) rol van het bestuursrecht
De Russische inval in Oekraïne heeft Nederland in vele opzichten wakker geschud. Ook in Den Haag is de Sanctiewet op de politieke agenda komen te staan. De Nationaal Coördinator Sanctienaleving en Handhaving deed vorig voorjaar aanbevelingen om de uitvoering van sanctiemaatregelen te verbeteren. Daarop heeft de minister van Buitenlandse Zaken aangekondigd dat de Sanctiewet wordt ‘gemoderniseerd’. In dit artikel staat de auteur stil bij de aangekondigde grotere rol voor het bestuursrecht binnen de Sanctiewet.
Kleurloos opzet op het financieren van terroristische organisaties
Authors: Haselager I.M.A. , de Jong F. 
Published: August 2023

Kleurloos opzet op het financieren van terroristische organisaties. Noot bij HR 10 januari 2023, ECLI:NL:HR:2023:2, NJ 2023/46
Reikwijdte van het opzetbegrip in artikel 2 lid 1 Wet op de Economische Delicten.
Instrumentalisering van burgerlijk procesrecht
Authors: van Schaick Bert 
Published: August 2023

Instrumentalisering van burgerlijk procesrecht. Over de inzet van het burgerlijk procesrecht om buiten het burgerlijk procesrecht gelegen doelen te realiseren
Hoewel het HvJ EU vrij consequent de procesrechtelijke autonomie van de lidstaten benadrukt, grijpt het openlijk in dat procesrecht in, vooral om materieelrechtelijke consumentenbescherming tot stand te brengen. Het HvJ EU lijkt een trendsetter. De instrumentalisering van het procesrecht raakt aan fundamentele procesrechtelijke beginselen.
Límites Hermenéuticos Al Principio de Complementariedad en La Jurisprudencia de La Corte Penal Internacional: Una Aparente Aporía Sobre Los Alcances Materiales de Las Jurisdicciones Nacionales
Authors: Villarreal Julio Francisco , Díaz Verónica Marrache , Melgarejo Patricia Nieto , Requejo Gilmer Alarcón 
Published: August 2023

Objetivo: Contrastar los alcances del principio de complementariedad en función de la dimensión de soberanía jurisdiccional nacional a partir de la jurisprudencia más relevante, en el punto, de la Corte Penal Internacional. Metodología: se apeló a un método hermenéutico crítico, analizando la interrelación entre el principio de complementariedad y la soberanía jurisdiccional de cada Estado en función de un análisis socio-histórico de las instituciones y la jurisprudencia de la Corte Penal Internacional. Conclusión: se arriba a la conclusión de que entre el respeto irrestricto al principio de complementariedad y la soberanía jurisdiccional de cada Estado no existe inconsistencia alguna. Eventuales contradicciones entre ambos esquemas deben ser entendidas en función de circunstancias socio-históricas de excepcionalidad, como la figura del debellatio o las propias implicancias de la relación entre poderes al interior de cada Estad. El presente trabajo reivindica la necesidad de un ejercicio heurístico contestatario a las tesituras que hacen de presupuestos normativos como el principio de complementariedad y la soberanía jurisdiccional de cada Estado categorías analíticas cerradas y solipsistas, desde que tal tesitura no solo no permitiría contrastar diversos paradigmas jurídicos, sino, para peor, obstaría a toda posibilidad de sancionar crímenes graves.