(Invited) Non-Polymer Organic Solar Cells: Microscopic Phonon Control to Suppress Non-Radiative Voltage Loss Via Charge-Separated State
Authors: Kobori Yasuhiro , Fuki Masaaki , Masuo Sadahiro , Yamada Hiroko 
Published: September 2023

Recent remarkable developments on non-fullerene solar cells have reached photoelectric conversion efficiency (PCE) of 18% by tuning the band energy levels in small molecular acceptors. In this respect, development of the small donor molecule is essential. Although several methods have been applied to elucidate the elementary processes of charge carriers in BHJ-OSCs, mechanistic details of non-radiative voltage loss are poorly understood originating from interfacial heterogeneous electron-hole pairs.A recent time-resolved electron paramagnetic resonance (TREPR) study suggested an impact of the recombination process generating the triplet excitons in non-fullerene acceptor solar cells,[1] while geometries and motions of charge-separated (CS) states were elucidated in details by electron spin polarization (ESP).[2-4] Furthermore, although effects of low-frequency nuclear motions (phonon) on the photocarrier generations have been discussed in several literatures,[2,5,6] microscopic origin of the phonon playing a role on the OPV performance is unclear including impact of the phonon assist on primary recombination processes. Here we systematically investigated mechanisms of solar cell performance with diketopyrrolopyrrole (DPP)–tetrabenzoporphyrin (BP) conjugates of C4-DPP–H2BP and C4-DPP–ZnBP where C4 represents butyl group substituted at the DPP unit as small p-type molecules in non-polymer organic solar cells (OSC) with an acceptor of [6,6]-phenyl-C61-buthylic acid methyl ester. We clarified microscopic origins of the photocarrier caused by phonon-assisted 1D electron-hole dissociations at donor:acceptor interface. Using a time-resolved electron paramagnetic resonance, we have characterized controlled charge-recombination by manipulating disorders in π-π donor stacking, ensuring carrier transport through face-on molecular conformations to suppress non-radiative voltage loss via capturing specific interfacial radical pairs separated by 1.8 nm in bulk-heterojunction solar cells. While disordered lattice motions from the π-π stackings via zinc ligation are essential to enhance the entropy for charge-dissociations at the interface, too much ordered crystallinity causes backscattering phonon to reduce OSC performances.
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