bluuebunny/crossref_metadata_2025_split huggingface dataset:
Periprosthetic distal femoral fractures after total knee replacement treated by ORIF. Mid to long-term follow-up study in 12 patients
Authors: Caterini Alessandro , Luciano Claudia , Rovere Giuseppe , Ziranu Antonio , Farsetti Pasquale , De Maio Fernando 
Published: September 2023

Periprosthetic fractures following total knee arthroplasty are a quite uncommon traumatic lesion that often are present in elderly patients with osteoporosis and comorbidities. The most common periprosthetic fracture affects the distal femur. The main internal fixation techniques are ORIF with a locking plate and retrograde intramedullary nailing. In the present study, we report the medium-long term results in 12 patients with a distal femoral periprosthetic fracture stabilized with a locking plate. We reviewed 12 patients affected by a periprosthetic distal femur fracture surgically treated between 2010 and 2016 by ORIF using a locking compression plate after an average follow-up of 5.75 years. The average age of the patients at diagnosis was 78 years. The mean interval time between knee arthroplasty and distal femoral fracture was 8.25 years. Clinical results were assessed using the WOMAC score, while radiographic results according to Beals and Tower’s criteria. All fractures of our series were type II according to the Rorabeck and Taylor classification. At follow-up, the WOMAC score ranged from 40.5 to 76.5 points (average 53.92). Radiographic results, according to Beals and Tower’s criteria, were excellent in 5 patients and good in 7. All patients returned to their previous daily activities. We believe that reduction and internal fixation with a locking plate is a surgical option of treatment that provides satisfactory clinical and radiological results in Rorabeck type II periprosthetic distal femoral fractures.
Tinjauan Konseling Pastoral Terhadap Pelatihan Pelayan Tuhan: Menghadapi Konflik KDRT Jemaat
Authors: Ria Natal 
Published: September 2023

Abstract The church should conduct pastoral counseling training for ministers, especially with regard to strategies to help congregants face conflict. The research aims to answer the church's challenge on how to train ministers of God to deal with congregational domestic violence conflicts through clinical pastoral education methods. The qualitative research is in the form of literature review, learning by doing theory and experience to answer the formulation of the problem. The results of the discussion explain that the steps that the church must take in training ministers of God are interviews, commitment, congregational visits and counseling guidance. The truth confrontation method and problem focused and emotion focused coping stress strategies are ways to help congregations deal with domestic violence conflicts. From the discussion, it is concluded that the church needs to take steps to produce the needs of competent counseling personnel, especially in helping congregations face conflicts. Abstrak Gereja sebaiknya melakukan pelatihan konseling pastoral bagi pelayan khususnya berkaitan dengan strategi untuk menolong jemaat menghadapi konflik. Penelitian bertujuan untuk menjawab tantangan gereja bagaimana pelatihan pelayan Tuhan menghadapi konflik KDRT jemaat melalui metode pendidikan pastoral klinis. Adapun penelitian kualitatif berupa kajian pustaka, teori learning by doing dan experience untuk menjawab rumusan masalah tersebut. Hasil pembahasan menjelaskan bahwa langkah-langkah yang harus dilakukan gereja dalam pelatihan pelayan Tuhan adalah wawancara, komitmen, kunjungan jemaat dan bimbingan konseling. Metode truth confrontation dan strategi problem focused dan emotion focused coping stress merupakan cara untuk membantu jemaat menghadapi konflik KDRT. Dari pembahasan maka diperoleh kesimpulan bahwa gereja perlu melakukan langkah-langkah untuk menghasilkan kebutuhan tenaga konseling yang kompeten, khususnya dalam menolong jemaat menghadapi konflik.
Janji Berkat Ismael: Kontra Argumen Terhadap Islamofobia dan Implikasi Bagi Misi Gereja
Authors: Theofany Shekinah , Justine Normando 
Published: September 2023

AbstractIslamophobia is an attitude that is widespread, especially among Christians. This attitude is one of the obstacles to evangelism and the mission of the church. Using a qualitative descriptive and literary study method, this research aims to make the church aware of the importance of Ishmaelites and Muslims as targets of God's mission of love to fight Islamophobia. The results of the discussion put forward Islamophobia in a Christian environment, the relationship between Ishmael and Islam, the meaning and content of Ishmael's Blessing Promise, and its implications for the church and mission. The conclusion from this discussion is that Islam has a correlation with Ismail and Christians have a duty as a means of mission, namely to preach the Gospel and show love for Muslims. AbstrakSikap Islamofobia merupakan sikap yang marak terutama di kalangan Kristen. Sikap ini merupakan salah satu hambatan penginjilan dan misi gereja. Dengan metode Deskriptif Kualitatif dan Studi Pustaka, penelitian ini bertujuan supaya gereja menyadari pentingnya keturunan Ismael dan umat Islam sebagai sasaran misi kasih Allah guna melawan sikap islamofobia. Hasil pembahasan mengemukakan islamofobia dalam lingkungan Kristen, hubungan antara Ismael dan Islam, Makna dan isi Janji Berkat Ismael, serta implikasinya terhadap gereja dan misi. Kesimpulan dari pembahasan ini adalah bahwa Islam memiliki korelasi dengan Ismail dan umat Kristen memiliki tugas sebagai sarana misi ialah untuk mengabarkan Injil dan menunjukkan kasih terhadap umat Islam.
Keluarga Spiritual Yang Melampaui Fisik: Doktrin Adopsi Dan Implikasinya Bagi Gereja Di Indonesia
Authors: Anugerah Bima 
Published: September 2023

AbstractIndonesia is a pronatalist country that gives high priority to marriage and the presence of children in the family. However, it must be acknowledged that there are families who cannot have children (barren). In addition, there are also people who are not married. In the church, these people have a place because they are children in God's family. The concept of God's family providing this kind of acceptance is based on the doctrine of adoption. The doctrine of adoption states that a person who believes in Christ is a person who is justified and regenerated so that he is adopted as a child in God's family. Through the church, those who are barren and unmarried get a new family that is not bound by physical relationships. This truth offers an alternative narrative compared to the pronatalist narrative that exists in Indonesian society. Through the concept of the church as God's family, which is based on the doctrine of adoption, those who are barren and unmarried gain a place in the church as members of God's family. AbstrakIndonesia adalah negara pronatalis yang memberi prioritas tinggi terhadap pernikahan dan kehadiran anak di dalam keluarga. Namun, perlu diakui bahwa ada keluarga yang tidak memiliki keturunan. Selain itu, ada juga orang-orang yang tidak menikah. Di dalam gereja, orang-orang ini mendapatkan tempat merupakan anak di dalam keluarga Allah. Konsep keluarga Allah yang memberikan penerimaan seperti ini didasarkan pada doktrin adopsi. Doktrin adopsi menyatakan bahwa orang yang beriman kepada Kristus adalah orang yang dibenarkan dan dilahirbarukan sehingga diangkat menjadi anak di dalam keluarga Allah. Melalui gereja, yang tidak memiliki keturunan dan selibat mendapatkan keluarga baru yang tidak terikat oleh hubungan lahiriah. Kebenaran ini menawarkan sebuah narasi alternatif dibandingkan narasi pronatalis yang ada di masyarakat Indonesia. Melalui konsep gereja sebagai keluarga Allah, yang didasarkan pada doktrin adopsi, yang tidak memiliki keturunan dan selibat mendapatkan tempat di dalam gereja sebagai anggota keluarga Allah.
Improving the quality of clinical practice guidelines in China: A call to action for editors of medical journals
Authors: Li Na , Li Yule , Li Jie 
Published: September 2023

High-quality clinical practice guidelines (CPGs) have the potential to standardize medical practice and improve patient outcomes. However, in China, the quality of CPGs is generally lower than the global average, particularly in terms of methodological and reporting quality. This hinders the dissemination and implementation of CPGs in healthcare practice. To enhance the scientific rigor and authority of CPGs, their development should adhere to reporting guidelines. As medical journals serve as the platform for CPG publication, editors of medical journals have a significant responsibility for the quality control of publishing CPGs. We call on editors of medical journals to be equipped with the CPG reporting guidelines, implement them in their journal practice, and actively participate in the development of CPGs. Additionally, editors of medical journals can also promote CPG quality awareness among medical professionals and journal editors. These efforts will contribute to the high-quality development of CPGs in China.
ANALISIS WACANA KOHESI GRAMATIKAL REFERENSI ENDOFORA DALAM SEBUAH CERPEN “AKU CINTA UMMI KARENA ALLAH” KARYA JENNY ERVINA
Authors: Ita Rosita  , Dara Syahadah  , Nuryeni Nuryeni  , Hajjah Muawanah  , Yustina Sari  
Published: September 2023

Dalam wacana memerlukan adanya unsur komunikasi yang berupa sumber meliputi pembicara/penulis/pendengar; penerima meliputi pendengar/pembaca/pembicara; saluran komunikasi; pesan; dan pokok masalah. Dalam wacana memiliki ciri utama yaitu harus adanya kepaduan yang terbentuk oleh adanya kesatuan dan pertautan. Kesatuan ini berkenaan dengan pokok masalah, sedangkan pertautan itu berkenaan dengan hubungan antara bagian yang satu dan bagian yang lain, yang berupa kalimat, paragraf, dan pasal.Dalam membentuk wacana diperlukan adanya hubungan antara kata, frasa, klausa dan kalimat sehingga menjadi satu kesatuan dalam wacana yang dapat disebut dengan kohesi gramatikal; tuturan yang membentuk wacana tersebut saling berhubungan dan menghasilkan suatu makna atau arti yang saling terpadu atau membentuk satu kesatuan di dalam wacana yang dapat disebut koherensi. Dari uraian yang dikemukakan diatas, bahwa apabila urutan dalam suatu wacana tidak jelas atau penempatan kata yang tidak sesuai atau salah maka akan menyebabkan keambiguan atau ketidakjelasan arti atau makna dan tidak koherensinya suatu wacana. Oleh karena itu, kohesi dalam suatu wacana sangat penting dalam mendukung koherensi. dipilihnya karya sastra berupa cerpen sebagai objek dalam menganalisis adalah karena cerpen termasuk ke dalam bagian dari wacana yang dikemas secara ringkas tanpa meningggalkan faktor-faktor yang membentuknya yaitu menggunakan kohesi dan koherensi supaya membentuk satu kesatuan wacana yang utuh dan padu. Sedangkan alasan peneliti secara khusus memilih cerpen berjudul “Aku Cinta Ummi Karena Allah” karya Jenny Ervina karena cerpen ini merupakan salah satu karya yang pertama kali dibuat oleh TKW yang berasal dari Petir, Serang-Banten. Selanjutnya, penelitian analisis wacana ini dapat memberikan pengetahuan mengenai permasalahan kohesi dalam unsur-unsur wacana, khususnya dalam kohesi gramatikal referensi berupa endofora yang bersifat anafora dan katafora.
Acciones implementadas por el sector empresarial privado de Costa Rica y su efecto en el alcance de los Objetivos de Desarrollo Sostenible en 2022
Authors: González Marín María Luisa , Rojo Gutiérrez Marco Antonio 
Published: September 2023

La presente investigación se basa en cuáles acciones orientadas a la atención de la diversidad, equidad e inclusión realizan empresas del sector empresarial privado de Costa Rica en el 2022 y el efecto de estas en el alcance de los siguientes Objetivos de Desarrollo Sostenible: 4 -Educación de Calidad, 5 -Igualdad de Género, 8 -Trabajo Decente y Crecimiento Económico, 10 -Reducción de las Desigualdades y 16 -Paz, Justicia e Instituciones Sólidas, planteados en la Agenda 2030 de las Naciones Unidas. Muestra los resultados de un estudio basado en la aplicación de una metodología mixta. Consta de un análisis cuantitativo y cualitativo con el apoyo de instrumentos de recolección de datos. El instrumento utilizado para la recolección de los datos cuantitativos es un cuestionario. Los resultados obtenidos a partir del instrumento de recolección de datos sugieren que las empresas del sector empresarial privado de Costa Rica que gestionan el eje temático de diversidad, equidad e inclusión, tienen relación directa con algunos de los Objetivos de Desarrollo Sostenible definidos por la Organización de las Naciones Unidas en la Agenda 2030. Es recomendable que las empresas del sector empresarial privado, de Costa Rica realicen un minucioso trabajo que evidencie la relación que tienen sus acciones en la dimensión relacional de diversidad, equidad e inclusión, con algunos de los Objetivos de Desarrollo Sostenible. Esta investigación ofrece un insumo para estas empresas con el fin de que evidencien la existencia de esta relación y su contribución hacia Costa Rica con el alcance de algunos Objetivos de Desarrollo Sostenible.
The Radical SAM [FeFe]‐Hydrogenase Maturase HydE
Authors: Nicolet Yvain 
Published: September 2023

Abstract

The enzyme HydE is involved in the assembly of the [2Fe]
H
‐subcluster of the [FeFe]‐hydrogenase active site (also termed H‐cluster). The protein belongs to the radical SAM enzyme superfamily and uses a (κ
3
‐cysteinate‐Fe
II
(CN)(CO)
2
organometallic complex as substrate. Upon SAM cleavage, the 5′‐deoxyadenosyl radical attacks the cysteinate sulfur atom and produces two successive EPR active intermediates. Yet, the final product of the reaction remains unknown. In addition to the radical SAM [4Fe–4S]‐cluster, HydE from
Thermotoga maritima
exhibits an auxiliary [4Fe–4S]‐cluster located at the surface of the protein. This peculiarity allowed structural characterizations of FeS‐cluster assembly and degradation intermediate structures.
Sustainable Routes for the Depolymerization of Lignocellulosic Biomass
Authors: Lindenbeck Lucie , Liu Yanbing , Beele Björn B. , Slabon Adam , Rodrigues Bruno V. Manzolli 
Published: September 2023

Abstract
Lignocellulosic biomass is the world largest renewable resource used as a raw material to produce high‐value‐added chemicals, such as biofuels and other biomaterials. However, the complex chemical structures of its main constituents, named cellulose, hemicelluloses, and lignin, pose a challenge to the breakdown of these biopolymers into smaller units. In this scenario, sustainable methods for the depolymerization of lignocellulosic biomass aim to chemically break these macromolecules into simple monomers and dimers, while minimizing the use of hazardous chemicals and energy‐intensive processes. Different depolymerization strategies have been proposed, including enzymatic, electrochemical, acid‐catalyzed, and solvent‐based methods. Nevertheless, the development and improvement of sustainable approaches toward depolymerization technologies is still ongoing, and there is still room for further research to optimize the efficiency, cost‐effectiveness, and scalability of the processes. While the successful depolymerization of biomass may significantly contribute to the transition to a more sustainable and environmentally friendly economy, this article outlines the most recent developments focusing on the particularities of these processes, including biological, electrochemical, thermal, and chemical methods.
Soft, Long‐Lived, Bioresorbable Electronic Surgical Mesh with Wireless Pressure Monitor and On‐Demand Drug Delivery
Authors: Kaveti Rajaram , Lee Joong Hoon , Youn Joong Kee , Jang Tae‐Min , Han Won Bae , Yang Seung Min , Shin Jeong‐Woong , Ko Gwan‐Jin , Kim Dong‐Je , Han Sungkeun , Kang Heeseok , Bandodkar Amay J. , Kim Hyun‐Young , Hwang Suk‐Won 
Published: September 2023

AbstractCurrent research in the area of surgical mesh implants is somewhat limited to traditional designs and synthesis of various mesh materials, whereas meshes with multiple functions may be an effective approach to address long‐standing challenges including postoperative complications. Herein, a bioresorbable electronic surgical mesh is presented that offers high mechanical strength over extended timeframes, wireless post‐operative pressure monitoring, and on‐demand drug delivery for the restoration of tissue structure and function. The study of materials and mesh layouts provides a wide range of tunability of mechanical and biochemical properties. Dissolvable dielectric composite with porous structure in a pyramidal shape enhances sensitivity of a wireless capacitive pressure sensor, and resistive microheaters integrated with inductive coils provide thermo‐responsive drug delivery system for an antibacterial agent. In vivo evaluations demonstrate reliable, long‐lived operation, and effective treatment for abdominal hernia defects, by clear evidence of suppressed complications such as adhesion formation and infections.
Molecular Cooperativity in the Intense Raman Scattering on the Surface of an Organic Molecular Microcrystal
Authors: Bhakat Arin , Chattopadhyay Arun 
Published: September 2023

AbstractMetal free substrates as promising surface enhanced Raman spectroscopy (SERS) platforms have recently gained significant attention owing to their high spectral stability, ease of synthesis, environmental stability, biocompatibility, and target molecule specificity. In this context, molecular crystals of π‐conjugated small molecules can represent a class of prominent candidates, the SERS properties – especially analyte specificity – of which can be tuned based on molecular bonding and interaction. Herein it is suggested and demonstrated that microcrystals of a small organic molecule such as those of π‐conjugated terephthalic acid (TA) can be used as novel platforms for SERS. TA microcrystals show unprecedented Raman signal enhancements up to 1.50 × 106 for the analyte molecule rhodamine‐6G (R6G), 3.23 × 104 for rhodamine B (RhB), and 7.17 × 104 for the eosin yellowish (EY) at 785 nm laser stimulation. Experimental results also show that molecular cooperativity in the Raman signal enhancement or reduction of binary mixtures over TA microcrystals can be analyte‐specific. The density functional theory (DFT) based electronic structure of the crystals, photo‐induced charge transfer transitions, and the concept of hybrid orbitals through noncovalent interactions in the combined system provide insights into the cooperative, molecule‐specific intense SERS performance. These findings represent a substantial exploratory breakthrough in the relatively nascent domain of organic SERS.
Acid‐Promoted Electron Transfer with Inverse Kinetic Isotope Effect for Disproportionation of Nitroxyl Radicals in CH3CN
Authors: Wang Xinyu , Wang Yongtao , Li Haoran 
Published: September 2023

AbstractThough electron transfer (ET) and proton transfer (PT) are extensively involved in organic reactions, they remain unclear in acid‐enabled disproportionation of nitroxyl radicals, especially in organic solvents. Here we unveil the acid‐promoted electron transfer (APET) mechanism with inverse kinetic isotope effect (KIE) for the disproportionation of 2,2,6,6‐tetramethylpiperidine‐1‐oxyl (TEMPO) in CH3CN. Kinetic experiments relying on on‐line detection of electron paramagnetic resonance (EPR) was conducted together with theoretical calculations, giving consistent insights on the mechanisms. Moreover, the significant effect of water as cosolvent was revealed. The findings here will encourage further mechanistic understandings and method developments for nitroxyl‐participated organic reactions.
The Alzheimer's Disease Neuroimaging Initiative and the role and contributions of the Private Partners Scientific Board (PPSB)
Authors: Albala Bruce , Appelmans Eline , Burress Ramona , De Santi Susan , Devins Theresa , Klein Gregory , Logovinsky Veronika , Novak Gerald P. , Ribeiro Kim , Schmidt Mark E. , Schwarz Adam J. , Scott David , Shcherbinin Sergey , Siemers Eric , Travaglia Alessio , Weber Christopher J. , White Leah , Wolf‐Rodda Julie , Vasanthakumar Aparna 
Published: September 2023

AbstractThe Alzheimer's Disease Neuroimaging Initiative (ADNI) Private Partners Scientific Board (PPSB) encompasses members from industry, biotechnology, diagnostic, and non‐profit organizations that have until recently been managed by the Foundation for the National Institutes of Health (FNIH) and provided financial and scientific support to ADNI programs. In this article, we review some of the major activities undertaken by the PPSB, focusing on those supporting the most recently completed National Institute on Aging grant, ADNI3, and the impact it has had on streamlining biomarker discovery and validation in Alzheimer's disease. We also provide a perspective on the gaps that may be filled with future PPSB activities as part of ADNI4 and beyond.Highlights
The Private Partners Scientific board (PPSB) continues to play a key role in enabling several Alzheimer's Disease Neuroimaging Initiative (ADNI) activities.
PPSB working groups have led landscape assessments to provide valuable feedback on new technologies, platforms, and methods that may be taken up by ADNI in current or future iterations.
Experimental and Computational Studies on Cobalt(I)‐Catalyzed Regioselective Allylic Alkylation Reactions
Authors: Andreetta Philip , Martin Robert T. , Souilah Charafa , Rentería‐Gómez Ángel , Song Zhihui , Khorramshahi Bayat Yas , Ivlev Sergei , Gutierrez Osvaldo , Casitas Alicia 
Published: September 2023

AbstractHere, we report the development of cobalt(I)‐catalyzed regioselective allylic alkylation reactions of tertiary allyl carbonates with 1,3‐dicarbonyl compounds. A family of well‐defined tetrahedral cobalt(I) complexes bearing commercially available bidentate bis(phosphine) ligands [(P,P)Co(PPh3)Cl] are synthesized and explored as catalysts in allylic alkylation reactions. The catalyst [(dppp)Co(PPh3)Cl] (dppp=1,3‐Bis(diphenylphosphino)propane) enables the alkylation of a large variety of tertiary allyl carbonates with high yields and excellent regioselectivity for the branched product. Remarkably, this methodology is selective for the activation of tertiary allyl carbonates even in the presence of secondary allyl carbonates. This contrasts with the selectivity observed in cobalt‐catalyzed allylic alkylations enabled by visible light photocatalysis. Mechanistic insights by means of experimental and computational investigations support a Co(I)/Co(III) catalytic cycle.
Tetraphenylporphyrin‐based Chelating Ligand Additive as a Molecular Sieving Interfacial Barrier toward Durable Aqueous Zinc Metal Batteries
Authors: Zhao Xin , Wang Yao , Huang Cong , Gao Yifu , Huang Miaofei , Ding Yichen , Wang Xia , Si Zhichun , Zhou Dong , Kang Feiyu 
Published: September 2023

AbstractThe sustained water consumption and uncontrollable dendrite growth strongly hamper the practical applications of rechargeable zinc (Zn) metal batteries (ZMBs). Herein, for the first time, we demonstrate that trace amount of chelate ligand additive can serve as a “molecular sieve‐like” interfacial barrier and achieve highly efficient Zn plating/stripping. As verified by theoretical modeling and experimental investigations, the benzenesulfonic acid groups on the additive molecular not only facilitates its water solubility and selective adsorption on the Zn anode, but also effectively accelerates the de‐solvation kinetics of Zn2+. Meanwhile, the central porphyrin ring on the chelate ligand effectively expels free water molecules from Zn2+ via chemical binding against hydrogen evolution, and reversibly releases the captured Zn2+ to endow a dendrite‐free Zn deposition. By virtue of this non‐consumable additive, high average Zn plating/stripping efficiency of 99.7 % over 2100 cycles together with extended lifespan and suppressed water decomposition in the Zn||MnO2 full battery were achieved, thus opening a new avenue for developing highly durable ZMBs.