bluuebunny/crossref_metadata_2025_split huggingface dataset:
Studi Tentang Penerapan Character Building Di Sekolah Dan Madrasah
Authors: Shofwan Arif 
Published: June 2023

Penelitian kualitatif ini membahas pembentukan karakter di sekolah dan madrasah. Tulisan dengan studi kepustakaan ini fokus pada tiga hal, yaitu penerapan pembentukan karakter; peran guru, serta pendukung dan penghambat pembentukan karakter. Penelitian ini menghasilkan beberapa hal berikut. Pertama, penerapan pembentukan karakter dapat dilakukan dengan menggunakan delapanbelas nilai budaya dan karakter bangsa yang dirumuskan pendidikan nasional Indonesia dan lainnya. Kedua, peran guru dalam pembentukan karakter, antara lain: evaluator, motivator, konselor, pembimbing, dan mediator demi terbentuknya karakter peserta didik secara maksimal. Ketiga, faktor pendukung pembentukan karakter, antara lain: pengalaman pra sekolah, tingkat kecerdasan, kreativitas, motivasi belajar, sikap dan kebiasaan belajar, serta lingkungan sekolah yang positif. Keempat, faktor penghambat pembentukan karakter, antara lain: kukuhnya pengaruh paham behaviorisme dalam sistem pendidikan, kapasitas SDM pendidik yang masih rendah, tuntutan zaman yang semakin pragmatis, sikap dan pendirian yang kurang menguntungkan bagi tegaknya demokratisasi pendidikan, dan beberapa hal lainnya.
Upaya Kelompok Wanita Tani Dalam Peningkatan Pendapatan Keluarga Melalui Pemanfaatan Lahan Pekarangan
Authors: Fardhilah Lulu , Darusman Yus , Danial Adang 
Published: June 2023

ABSTRAK
Penelitian ini dilatar belakangi oleh permasalahan kemiskinan yang masih banyak di kalangan masyarakat serta kurangnya optimalisasi lahan pekarangan dimana masih banyak orang yang kurang sadar akan manfaat tentang lahan pekarangan selain agar lahan pekarangan menjadi indah juga memiliki potensi dalam penyediaan bahan pangan, serta mengurangi pengeluaran rumah tangga. Tujuan dari penelitian ini yaitu untuk dapat membantu peningkatan pendapatan yang ada didalam keluarga. Permasalahan yang ada di masyarakat terkait tentang kemiskinan dan lahan pekarangan yang kurang berfungsi maka diperlukannya pembentukan kelompok wanita tani Kenanga yang ada di Desa Nyanggahurip Kecamatan Cibereum Kota Tasikmalaya untuk membantu peningkatan pendapatan keluarga melalui pemanfaatan lahan pekarangan. Metode yang digunakan dalam penelitian ini adalah menggunakan metode penelitian dengan jenis penelitian kualitatif yang bersifat deskriptif. Peneliti menggunakana sumber data, teknik pengumpulan data melalui wawancara, observasi, dan dokumentasi.Dari hasil yang diperoleh dalam penelitian ini terbentuknya suatu kelompok tidak terlepas dari kedekatan, interaksi, keseimbangan, kesinambungan dan pertukaran. Dengan mengikuti kelompok wanita tani kenanga wanita menjadi lebih bisa mengembangkan potensi yang ada di dalam dirinya melalui pemanfaatan lahan pekarangan. Adanya dukungan dari Dinas Ketahanan Pangan dan Perikanan Kota Tasikmalaya menjadikan kelompok wanita tani kenanga berjalan dengan baik. Keberhasilan kelompok wanita tani kenanga juga dilihat dari hasil yang diperoleh anggota kelompok wanita tani kenanga.
Upaya Pengembangan Minat Literasi dan Kemampuan Menghafal Pada Anak Melalui Video Animasi di Teras Baca Sumberpasir Kabupaten Malang
Authors: Puji Rahayu Riris Dwi , Mawarni Sutrisna Lala , Ahmad Ahmad 
Published: June 2023

Minat literasi dan kemampuan menghafal anak merupakan sebuah potensi yang sangat dibutuhkan dan digali dengan lebih efektif. Upaya yang perlu dilakukan adalah dengan dapat mengkolaborasikan situasi dan kondisi di tengah revolusi 4.0. Seperti di Desa Sumberpasir, Kecamatan Pakis, Kabupaten Malang yang memiliki Teras Baca sebagai sarana tambahan untuk anak-anak Desa Sumberpasir. Di teras baca Sumberpasir, memiliki program bimbingan belajar dengan peserta didik usia sekolah dasar berjumlah 30 peserta didik. Permasalahan utama ialah minat literasi pada anak-anak dirasa masih kurang cukup sehingga menjadi penghambat dalam kemampuan menghafal mereka. Adapun metode yang digunakan dalam penelitian ini adalah penelitian kualitatif deskriptif melalui pendekatan studi kasus. Terkait permasalahan di atas, solusi yang ditawarkan oleh penulis adalah video pembelajaran berbasis animasi yang dapat membantu upaya pengembangan minat literasi dan kemampuan menghafal anak-anak bimbingan belajar di teras baca sumberpasir. Hasil yang diperoleh yaitu (1) implikasi pemanfaatan media video animasi sebagai strategi pengembangan minat literasi dan kemampuan menghafal pada anak; (2) peran animasi dalam pembelajaran; dan (3) tingkat efektifitas pemanfaatan video animasi untuk mengembangkan minat literasi dan kemampuan menghafal pada anak desa sumberpasir. Video animasi ini memiliki beberapa konten yang mendukung upaya meningkatkan minat literasi dan kemampuan menghafal anak di Teras Baca Sumberpasir.
Kata Kunci: Literasi, Menghafal, Video Animasi
The use of wireless sensors in the neonatal intensive care unit: a study protocol
Authors: Senechal Eva , Radeschi Daniel , Tao Lydia , Lv Shasha , Jeanne Emily , Kearney Robert , Shalish Wissam , Sant Anna Guilherme 
Published: June 2023

Background
Continuous monitoring of vital signs and other biological signals in the Neonatal Intensive Care Unit (NICU) requires sensors connected to the bedside monitors by wires and cables. This monitoring system presents challenges such as risks for skin damage or infection, possibility of tangling around the patient body, or damage of the wires, which may complicate routine care. Furthermore, the presence of cables and wires can act as a barrier for parent-infant interactions and skin to skin contact. This study will investigate the use of a new wireless sensor for routine vital monitoring in the NICU.

Methods
Forty-eight neonates will be recruited from the Montreal Children’s Hospital NICU. The primary outcome is to evaluate the feasibility, safety, and accuracy of a wireless monitoring technology called ANNE® One (Sibel Health, Niles, MI, USA). The study will be conducted in 2 phases where physiological signals will be acquired from the standard monitoring system and the new wireless monitoring system simultaneously. In phase 1, participants will be monitored for 8 h, on four consecutive days, and the following signals will be obtained: heart rate, respiratory rate, oxygen saturation and skin temperature. In phase 2, the same signals will be recorded, but for a period of 96 consecutive hours. Safety and feasibility of the wireless devices will be assessed. Analyses of device accuracy and performance will be accomplished offline by the biomedical engineering team.

Conclusion
This study will evaluate feasibility, safety, and accuracy of a new wireless monitoring technology in neonates treated in the NICU.
Clinical Outcomes of Surgery for Age-related Cataract with Intraocular Lens Implantation in Two Hospitals in North-Central Nigeria
Authors: Jeneral Alfin Ruth 
Published: June 2023

Aims: The study aimed to assess the post-operative presenting visual acuity (PVA) and best-corrected visual acuity (BCVA) from six weeks and above post-surgery, of patients operated for age-related cataract with biometry-calculated IOL power and available IOL power implantation, in two hospitals in Jos, Nigeria.
Study Design: Retrospective cross-sectional survey.
Place and Duration of Study: Eye units of two mission Hospitals in Jos namely; Bingham University Teaching Hospital and the Faith Alive foundation Hospital, between June and August 2021.
Methodology: Patients aged 40 years and above, who had undergone surgery for age-related cataract in the preceding 18 months in two hospitals in Jos and were six weeks or more post-surgery were consecutively enrolled into the study, after obtaining informed consent. Socio-demographic data and surgical history were obtained from patients and their surgical records. The PVA and BCVA were assessed and categorized based on World Health Organization guidelines.
Results: A total of 87 patients were examined within the study period. Post-operative PVA was good (≥6/18) in 32 (36.8%), borderline (<6/18-6/60) in 41 (47.1%) and poor (<6/60) in 14 (16.1%) participants. After refraction, the proportion of good outcomes increased to 78.2% with only 8.1% of outcomes remaining poor. Biometry-calculated IOL power and available IOL power use did not significantly influence visual outcome (P=.645 and P=.146 for PVA and BCVA respectively).
Conclusion: Majority of participants had post-operative PVA in the borderline category with residual uncorrected refractive error as the principal cause. Regardless of the IOL power implanted, surgery for age-related cataract enhanced patients’ vision. This study has shown that the presence of biometry is a guarantee of refractive success. Hence, refractive outcome audits are essential.
A Unifying Perspective of Common Motifs That Occur across Disparate Classes of Materials Harboring Displacive Phase Transitions
Authors: Grünebohm Anna , Hütten Andreas , Böhmer Anna E. , Frenzel Jan , Eremin Ilya , Drautz Ralf , Ennen Inga , Caron Luana , Kuschel Timo , Lechermann Frank , Anselmetti Dario , Dahm Thomas , Weber Frank , Rossnagel Kai , Schierning Gabi 
Published: June 2023

AbstractSeveral classes of materials manifest displacive phase transitions, including shape memory alloys, many electronically correlated materials, superconductors, and ferroelectrics. Each of these classes of materials displays a wide range of fascinating properties and functionalities that are studied in disparate communities. However, these materials’ classes share similar electronic and phononic instabilities in conjunction with microstructural features. Specifically, the common motifs include twinned microstructures, anomalies in the transport behavior, softening of specific phonons, and frequently also (giant) Kohn anomalies, soft phonons, and/or nesting of the Fermi surface. These effects, phenomena, and their applications have until now been discussed in separate communities, which is a missed opportunity. In this perspective a unified framework is presented to understand these materials, by identifying similarities, defining a unified phenomenological description of displacive phase transitions and the associated order parameters, and introducing the main symmetry‐breaking mechanisms. This unified framework aims to bring together experimental and theoretical know‐how and methodologies across disciplines to enable unraveling hitherto missing important mechanistic understanding about the phase transitions in (magnetic) shape memory alloys, superconductors and correlated materials, and ferroelectrics. Connecting structural and electronic phenomena and microstructure to functional properties may offer so‐far unknown pathways to innovate applications based on these materials.
Photoactivated DNA Assembly and Disassembly for On‐Demand Activation and Termination of cGAS‐STING Signaling
Authors: Yu Fangzhi , Li Xiangfei , Zhao Jian , Zhao Yuliang , Li Lele 
Published: June 2023

AbstractDespite significant progress in DNA self‐assembly for interfacing with biology, spatiotemporally controlled regulation of biological process via in situ dynamic DNA assembly remains an outstanding challenge. Here, we report an optically triggered DNA assembly and disassembly strategy that enables on‐demand activation and termination of the cyclic GMP‐AMP synthase (cGAS)‐stimulator of interferon genes (STING) signaling pathway. In the design, an activatable DNA hairpin is engineered with a photocleavable group at defined site to modulate its self‐assembly activity. Light activation induces the configurational switching and consequent self‐assembly of the DNA hairpins to form long linear double‐stranded structures, allowing to stimulate cGAS protein to synthesize 2′,3′‐cyclic‐GMP‐AMP (cGAMP) for STING stimulation. Furthermore, by endowing the pre‐assembled DNA scaffold with a built‐in photolysis feature, we demonstrate that the cGAS‐STING stimulation can be efficiently terminated through remote photo‐triggering, providing for the first time a route to control the temporal “dose” on‐demand for such a stimulation. We envision that this regulation strategy will benefit and inspire both fundamental research and therapeutic applications regarding the cGAS‐STING pathway.
The role of community college leaders in developing a transfer sending culture for Latinx students
Authors: Viramontes José Del Real 
Published: June 2023

AbstractThis chapter provides community college leaders with recommendations to develop a transfer sending culture for Latinx students who want to pursue a pathway to a 4‐year college/university. Community college leaders can create a transfer sending culture for Latinx students by standardizing a transfer process so that all Latinx students who aim to transfer can do it efficiently and in a timely manner.
Visible‐Light Photoredox Catalyzed Regioselective 1,4‐Hydroalkylation of 1,3‐Enyne
Authors: Hou Hong , Pan Yingjie , Sun Yuejie , Han Ying , Yan Chaoguo , Shi Yaocheng , Zhu Shaoqun 
Published: June 2023

AbstractDescribed herein is a visible‐light photoredox‐catalyzed regioselective 1,4‐hydroalkylation of 1,3‐enynes. Various of di‐ and tri‐substituent allenes were really accessible under the present reaction conditions. The visible‐light photoredox activation of the carbon nucleophile to generate its radical species, allowing the addition with un‐activated enynes. The synthetic utility for the present protocol was demonstrated by a large‐scale reaction, as well as the derivatization of the allene product.
Dimetal‐Binding Scaffold 2‐(Pyridin‐2‐yl)imidazo [1,5‐b]pyridazine‐7‐ylidene: Synthesis of Trinuclear Heterobimetallic Complexes Involving Gold‐Metal Interactions
Authors: Kitabayashi Akito , Ono Yuriko , Taketsugu Tetsuya , Sawamura Masaya , Higashida Kosuke 
Published: June 2023

AbstractAs a dimetal‐binding rigid scaffold, 2‐(pyridin‐2‐yl)imidazo[1,5‐b]pyridazine‐7‐ylidene was introduced. The scaffold was first converted into a meridional Au,N,N‐tridentate ligand through binding of a Au(I)Cl moiety at the carbene center. The Au(I) center and the N,N‐chelating moiety were expected to function as metallophilic and 4e‐σ‐donative interaction sites, respectively, in the binding of the second metal center. In this manner, various trinuclear heterobimetallic complexes were synthesized with different 3d‐metal sources, such as cationic CuI, CuII, NiII, and CoII salts. SC‐XRD analysis showed that the mono‐3d‐metal di‐gold(I) trinuclear heterobimetallic complexes were constructed through gold(I)‐metal interactions. Metallophilic interactions were also investigated by quantum chemical calculations including the AIM and IGMH methods.
Assessment of drought tolerance of sesame germplasm with agronomic and quality traits
Authors: Qureshi Moin , Arslan Mehmet , Golukcu Muharrem , Bera Sandip K. , Uzun Bulent , Yol Engin 
Published: June 2023

AbstractSesame (Sesamum indicum L.) is a summer crop and its production is threatened by drought stress (WS) due to increased aridity and higher temperature worldwide. Breeding sesame accessions that are more tolerant to WS is therefore highly important for sustainable seed production. Here, 21 accessions representing 12 sesame‐growing countries were evaluated with yield and quality traits under two different water‐regime treatments as non‐stressed (NS) and WS. The combined analysis of variance revealed that there was a significant variation among the accessions for all agronomic traits. We also found that the effects of treatment and genotype were significant for the quality traits of oil content, stearic acid, oleic acid, linoleic acid, and linolenic acid. The t‐test of significance for mean values indicated that there were significant differences between the treatments for plant height, number of branches, number of capsules, and seed yield. The highest yield was found in PI 170735 with the value of 25.6 g/plant in the treatment of WS. The higher values were observed for oil content in NS treatment, the highest amount of oil content was recorded as 53.9% for PI 207664. In addition, higher grand mean was observed for oleic acid under WS treatment. Principal component analysis using the five agronomic traits indicated that 76.60% and 71.18% variability accounted for the first two principal components (PCs) with eigen values ≥ 1 in WS and NS treatments, respectively. The diverse accessions characterized with agro‐quality traits can be used in further improvement programs to develop new drought‐tolerant cultivars.
Primary small‐cell carcinoma in the lung was found after the cold snare polypectomy of the small metastatic lesion in the cecum: A case report
Authors: Suto Daisuke , Yoshida Masashi , Yamada Hidehiko , Akita Takayuki , Osawa Yosuke , Sato Kiichi , Otake Takaaki , Nakazato Yoshimasa , Arakawa Nobuhito , Ohdaira Hironori , Suzuki Yutaka , Kohgo Yutaka 
Published: June 2023

AbstractMetastasis from small‐cell lung cancer to the colon is very rare. A 74‐year‐old man without respiratory or abdominal symptoms underwent a follow‐up lower gastrointestinal endoscopy after a polypectomy. He was diagnosed with a 5 mm IIa non‐hyperplastic polyp in the cecum and underwent a cold snare polypectomy. The histopathological findings confirmed the diagnosis of small cell carcinoma. The tumor was positive in the deep margins of the submucosal layer. Subsequent systemic examination revealed a mass in the lower lobe of the left lung. Thus, the tumor in the cecum was determined to be a colorectal metastasis from primary small‐cell carcinoma of the lung. Metastasis to the colon was diagnosed as small‐cell lung cancer based on local positivity for thyroid transcription factor‐1 and morphologic and immunochemical features. To our best knowledge, this is the first report of colon metastasis from small cell carcinoma identified by endoscopic treatment.
Remote patient management of heart failure across the ejection fraction spectrum: A pre‐specified analysis of the TIM‐HF2 trial
Authors: Kerwagen Fabian , Koehler Kerstin , Vettorazzi Eik , Stangl Verena , Koehler Magdalena , Halle Martin , Koehler Friedrich , Störk Stefan 
Published: June 2023

AbstractAimsThe benefit of non‐invasive remote patient management (RPM) for patients with heart failure (HF) has been demonstrated. We evaluated the effect of left ventricular ejection fraction (LVEF) on treatment outcomes in the TIM‐HF2 (Telemedical Interventional Management in Heart Failure II; NCT01878630) randomized trial.Methods and resultsTIM‐HF2 was a prospective, randomized, multicentre trial investigating the effect of a structured RPM intervention versus usual care in patients who had been hospitalized for HF within 12 months before randomization. The primary endpoint was the percentage of days lost due to all‐cause death or unplanned cardiovascular hospitalization. Key secondary endpoints were all‐cause and cardiovascular mortality. Outcomes were assessed by LVEF in guideline‐defined subgroups of ≤40% (HF with reduced EF [HFrEF]), 41–49% (HF with mildly reduced EF [HFmrEF]), and ≥50% (HF with preserved EF [HFpEF]). Out of 1538 participants, 818 (53%) had HFrEF, 224 (15%) had HFmrEF, and 496 (32%) had HFpEF. Within each LVEF subgroup, the primary endpoint was lower in the treatment group, i.e. the incidence rate ratio [IRR] remained below 1.0. Comparing intervention and control group, the percentage of days lost was 5.4% versus 7.6% for HFrEF (IRR 0.72, 95% confidence interval [CI] 0.54–0.97), 3.3% versus 5.9% for HFmrEF (IRR 0.85, 95% CI 0.48–1.50) and 4.7% versus 5.4% for HFpEF (IRR 0.93, 95% CI 0.64–1.36). No interaction between LVEF and the randomized group became apparent. All‐cause and cardiovascular mortality were also reduced by RPM in each subgroup with hazard ratios <1.0 across the LVEF spectrum for both endpoints.ConclusionIn the clinical set‐up deployed in the TIM‐HF2 trial, RPM appeared effective irrespective of the LVEF‐based HF phenotype.
Mannich‐Type Reactions of Alkylzinc Reagents
Authors: Pinaud Marine , Plantiveau Emilie , Huet Eric , Le Gall Erwan , Presset Marc 
Published: June 2023

AbstractMannich‐type reactions involving alkylzinc reagents have been developed using different strategies. We show that the addition of these organometallic species to sulfonyl imines occurs upon simple heating and affords Mannich products in moderate to excellent yields (14 examples, 30–99 %). Interestingly, N‐alkyl imines were also found to be suitable partners after activation as an acyliminium by acetyl chloride (12 examples, 49–86 %) or, more originally, by TMSCl (14 examples, 26–87 %). These methods proved complementary, leading to the preparation of both N‐protected secondary or tertiary amines and N‐unprotected secondary amines in good yields, with an increased eco‐compatibility, and under simple conditions.
2,2′‐Bis(arylamino)‐1,1′‐biaryls as Building Blocks for the Synthesis of Dibenzo[d,f][1,3]diazepines, Dibenzo[d,f][1,3]diazepinones, and Dibenzo[c,e][1,2,7]thiadiazepine 6‐Oxides
Authors: Thoran Robert , Schuh Tristan , Holling Philipp , Puls Florian , Kataeva Olga , Knölker Hans‐Joachim 
Published: June 2023

AbstractThe iron‐catalyzed oxidative C−C homocoupling of diarylamines affords 2,2′‐bis(arylamino)‐1,1′‐biaryls which represent crucial synthetic building blocks for an access to a range of seven‐membered heterocyclic ring systems. Reaction with paraformaldehyde, diphenyl carbonate, and diphenyl sulfite as efficient 1,1‐dielectrophiles led to dibenzo[d,f][1,3]diazepines, dibenzo[d,f][1,3]diazepinones, and dibenzo[c,e][1,2,7]thiadiazepine 6‐oxides. The synthetic procedures enable short and practical routes to these 1,3‐diazepine derivatives under mild reaction conditions and with a high tolerance of various functional groups.
Chronic pain is associated with less grey matter volume in the anterior cingulum, anterior and posterior insula and hippocampus across three different chronic pain conditions
Authors: Neumann Nicola , Domin Martin , Schmidt Carsten‐Oliver , Lotze Martin 
Published: June 2023

AbstractBackgroundChronic pain of different aetiologies and localization has been associated with less grey matter volume (GMV) in several cortical and subcortical brain areas. Recent meta‐analyses reported low reproducibility of GMV alterations between studies and pain syndromes.MethodsTo investigate GMV in common chronic pain conditions defined by body location (chronic back pain, n = 174; migraine, n = 92; craniomandibular disorder, n = 39) compared to controls (n = 296), we conducted voxel‐based morphometry and determined GMV from high‐resolution cranial MRIs obtained in an epidemiologic survey. Mediation analyses were performed between the presence of chronic pain and GMV testing the mediators stress and mild depression. The predictability of chronic pain was investigated with binomial logistic regression.ResultsWhole‐brain analyses yielded reduced GMV within the left anterior insula and the anterior cingulate cortex, for a ROI approach additionally the left posterior insula and left hippocampus showing less GMV across all patients with chronic pain. The relationship of pain with GMV in the left hippocampus was mediated by self‐reported stressors in the last 12 months. Binomial logistic regression revealed a predictive effect for GMV in the left hippocampus and left anterior insula/temporal pole for the presence of chronic pain.ConclusionsChronic pain across three different pain conditions was characterized by less GMV in brain regions consistently described for different chronic pain conditions before. Less GMV in the left hippocampus mediated by experienced stress during the last year might be related to altered pain learning mechanisms in chronic pain patients.SignificanceGrey matter reorganization could serve as a diagnostic biomarker for chronic pain. In a large cohort, we here replicated findings of less grey matter volume across three pain conditions in the left anterior and posterior insula, anterior cingulate and left hippocampus. Less hippocampal grey matter was mediated by experienced stress.