bluuebunny/crossref_metadata_2025_split huggingface dataset:
Formation of the All-Russian civil identity in the territories liberated during the SVO: risks and prospects
Authors: Bogachev Aleksei Mikhailovich , Teplykh Galina Ivanovna , Kavchuk Pavel Nikolaevich 
Published: July 2023

The article "Formation of the All-Russian civil identity in the territories liberated during the SVO: risks and prospects" is devoted to the actual problem of socio-psychological integration of residents of the DPR, LPR, Zaporozhye and Kherson regions in the all-Russian space in conjugation of this problem with such factors as post-traumatic stress disorder (PTSD) and social stress disorder (SSR). The authors of the article believe that to solve this and other problems, it is necessary to apply a special theological and psychological approach. This approach is associated with the actualization in psychological reality and with the help of psychological tools of creative attitudes based on traditional values for Russia. This article presents the author's material based on the experience of working in the territories liberated during the SVO and included in Russia (Mariupol), which allows conceptually assessing the risks and prospects for the formation of an all-Russian civil identity in these territories. According to the authors, they should be considered in the context of extrapolation to the entire territory of Russia from the point of view of both eliminating the consequences of social stress disorders and protecting the traditional values of domestic civilization. The unique concept of including citizens of the "new territories" in the general field of Russian identity in the context of overcoming the consequences of PTSD and SSR, as well as extrapolating the experience gained to work on the prevention of extremism throughout the Russian Federation is presented.
Capitalism and Global Mining: Latin American Perspectives 1500-1914
Authors: Torres James V. 
Published: July 2023

Objective/Context: The paper provides a comprehensive overview of Latin American mining history, exploring cross-pollination opportunities between mining historians and scholars of the emerging field of the history of capitalism. The analysis spans from the region’s integration into global markets during the 1500s to the twilight of export-led growth in the early twentieth century. Methodology: The study builds on an overview of both classic and contemporary literature, offering new insights into understanding existing data on mining history within a global context. By incorporating perspectives from geology, ecology, and economics, the article investigates the connections between specific mineral deposits and different paths of capitalistic development across Latin America. Originality: The paper sketches some of the gaps in the analysis of global and local flows of minerals and comments on notable contributions to the broader field of Latin American history. It introduces innovative approaches for the study of output cycles, geological and ecological endowments, technological spillovers, and mining economics. Conclusions: First, the existing literature has predominantly focused on precious metals, with few scholars studying non-precious metals and non-metallic minerals. Second, the narratives surrounding mining history have been primarily centered on silver, overshadowing the significance of bimetallism in understanding the emergence of global capitalism. Thirdly, examining the microeconomic dynamics of mining in the region may present fresh opportunities to explore the impact of mining on sectoral and managerial transformations. Finally, studies of the two-way interaction of capitalism and mining need to include research on the energy and environmental systems that underpinned mineral extraction and production.
Climate-Resilient Adaptation Strategies in Potato Production and Major Factors Influencing It in Karnataka, India
Authors: Kumar H. R. Harish , Pavan V. , Yeshwanth Raghuramreddy 
Published: July 2023

The World is already experiencing climate change and it has profound effects on both agriculture and horticulture. Hence present study attempts to identify climate resilient adaptation strategies in potato production and major factors influencing it in Karnataka, India. For the study Kolar and Hassan districts were selected based on their climate vulnerability status and potato crop was selected for the analysis. Primary data for the study were collected from 160 sample respondents through well structure, pre-tested interview schedule during 2021-22. To achieve the proposed objectives, descriptive statistics such as percentage and binary logistic regression was employed. The study identified six major climate-resilient adaptation strategies adopted by the respondents in potato cultivation such as early sowing, more than the recommended dose of pesticide application, preventive plant protection measures (in advance), improving water captures, drying of seed tubers before sowing and adapting heat/drought resistant varieties. Among six strategies, majority (92.50 % of Kolar and 72.50 % of Hassan) of the respondents adopted improving water captures as a major adaptation strategy. Binary regression revealed that education (0.5893), family size (0.7592), farming experience (1.0938), access to weather alerts (2.0914), and awareness of climate change (1.3409) had positive and significant impact on adaptation behavior of the sample respondents (pooled).
Antiviral Medications for Treatment of Nonsevere Influenza
Authors: Gao Ya , Zhao Yunli , Liu Ming , Luo Shuyue , Chen Yamin , Chen Xiaoyan , Zheng Qingyong , Xu Jianguo , Shen Yanjiao , Zhao Wanyu , Li Zhifan , Huang Sha , Huang Jie , Tian Jinhui , Guyatt Gordon , Hao Qiukui 
Published: January 2025

ImportanceThe optimal antiviral drug for treatment of nonsevere influenza remains unclear.ObjectiveTo compare effects of antiviral drugs for treating nonsevere influenza.Data SourcesMEDLINE, Embase, CENTRAL, CINAHL, Global Health, Epistemonikos, and ClinicalTrials.gov were searched from database inception to September 20, 2023.Study SelectionRandomized clinical trials comparing direct-acting influenza antiviral drugs to placebo, standard care, or another antiviral drug for treating people with nonsevere influenza.Data Extraction and SynthesisPaired reviewers independently performed data extraction and risk of bias assessment. A frequentist network meta-analysis was performed to summarize the evidence and the certainty of evidence was evaluated using the GRADE approach.Main Outcomes and MeasuresMortality, admission to hospital, admission to the intensive care unit, duration of hospitalization, time to alleviation of symptoms, emergence of resistance, and adverse events.ResultsOverall, 73 trials with 34 332 participants proved eligible. Compared with standard care or placebo, all antiviral drugs had little or no effect on mortality for low-risk patients and high-risk patients (all high certainty). All antiviral drugs (no data for peramivir and amantadine) had little or no effect on hospital admission for low-risk patients (high certainty). For hospital admission in high-risk patients, oseltamivir (risk difference [RD], −0.4%; 95% CI, −1.0 to 0.4; high certainty) had little or no effect and baloxavir may have reduced risk (RD, −1.6%; 95% CI, −2.0 to 0.4; low certainty); all other drugs may have had little or uncertain effect. For time to alleviation of symptoms, baloxavir probably reduced symptom duration (mean difference [MD], −1.02 days; 95% CI, −1.41 to −0.63; moderate certainty); umifenovir may have reduced symptom duration (MD, −1.10 days; 95% CI, −1.57 to −0.63; low certainty); oseltamivir probably had no important effect (MD, −0.75 days; 95% CI, −0.93 to −0.57; moderate certainty). For adverse events related to treatment, baloxavir (RD, −3.2%; 95% CI, −5.2 to −0.6; high certainty) had few or no adverse events; oseltamivir (RD, 2.8%; 95% CI, 1.2 to 4.8; moderate certainty) probably increased adverse events.Conclusions and RelevanceThis systematic review and meta-analysis found that baloxavir probably reduced risk of hospital admission for high-risk patients and may reduce time to alleviation of symptoms, without increasing adverse events related to treatment in patients with nonsevere influenza. All other antiviral drugs either probably have little or no effect, or uncertain effects on patient-important outcomes.
Use of Maternal-Fetal Medicine Subspecialist Services by Commercially Insured Pregnant People
Authors: Sullivan Haley K. , Armstrong Joanne C. , Fox Kathe , Cohen Jessica L. , Sinaiko Anna D. 
Published: January 2025

ImportanceImproving access to high-quality maternity care and reducing maternal morbidity and mortality are major policy priorities in the US. Previous research has primarily focused on access to general obstetric care rather than access to high-risk pregnancy care provided by maternal-fetal medicine subspecialists (MFMs).ObjectiveTo measure access to MFM services and determine patient factors associated with MFM service use, including MFM telemedicine.Design, Setting, and ParticipantsThis cohort study identified pregnancies in commercial health insurance claims from the Health Care Cost Institute from 2016 to 2021. More than 2.1 million pregnancies were included, where age at delivery was 18 years or greater and people were continuously enrolled for the duration of their pregnancy. The association of patient and pregnancy covariates with MFM involvement in care was analyzed using logistic regression; and rates of telemedicine for pregnancies in urban and rural areas were reported over time. Data were analyzed from June 2022 to March 2024.Main Outcomes and MeasuresPrimary study outcomes included whether a pregnancy ever had a service from an MFM, the type of MFM services provided, and whether MFM care occurred via telemedicine.ResultsThere were 2 169 026 pregnancies among 1 968 091 unique people (1 325 212 [61.2%] aged 25 to 34 years). Among 1 625 237 pregnancies at risk for conditions that might require MFM involvement, 838 493 (51.6%) had an MFM service. Rates of MFM involvement in care varied considerably by geography, with pregnancies in rural areas having lower use than urban areas. Use of telemedicine-enabled MFM care increased in 2020 and 2021 but remained low: in 2021, 2.7% of urban pregnancies (7535 of 276 599) and 1.7% of rural pregnancies (550 of 32 949) received telemedicine-enabled MFM care.Conclusions and RelevanceIn this cohort study, access to MFM services varied across geography, even among pregnancies at risk for conditions that might require MFM involvement. These results suggested a need to improve access to MFM care for at-risk pregnancies and to further explore expanded access via telemedicine.
Mental Health Utilization Among Transgender Veterans
Authors: Lee Joy L. , Hirsh Adam , Radhakrishnan Archana , Jasuja Guneet K. , Taylor Stanley , Dickinson Stephanie , Mineo Jocelyn , Carnahan Jennifer , Weiner Michael 
Published: January 2025

ImportanceCompared with cisgender (CG) individuals, transgender and gender-diverse (TGD) individuals experience substantial social and economic disparities that can result in adverse mental health consequences. It is critical to understand potential barriers to care and to address the causes of the disparities in the future.ObjectiveTo characterize mental health care utilization among TGD veterans with depression.Design, Setting, and ParticipantsThis cohort study used electronic health record data from the US Department of Veterans Affairs (VA) to create a 1:3 age group–matched and VA facility–matched nationwide cohort of TGD and CG veterans with documentation of depression during 2018 to 2020. Data analysis was performed from January to November 2023.ExposureTGD identity was ascertained by diagnosis of a gender identity disorder.Main Outcomes and MeasuresThe primary outcome was mental health care utilization, including counts of outpatient (in specialty care and primary care settings), telehealth, emergency department, and inpatient visits in this cohort. Descriptive statistics were used to characterize counts of mental health utilization, and statistically significant differences between TGD and CG veterans were tested using χ2 and Fisher exact tests. Wilcoxon rank-sum tests were used to test for differences in utilization between the 2 groups. Adjusted logistic regression, controlling for age group, administrative sex, race, Charlson Comorbidity Index, and number of mental health medications (eg, antidepressant, antipsychotic, and anxiolytic medications), was also used to compare utilization between TGD and CG veterans.ResultsAmong 10 564 veterans with depression (mean [SD] age, 46.4 [15.2] years; 8050 male [76.2%]), 2643 TGD veterans were matched with 7921 CG veterans. TGD veterans had 6 more specialty mental health visits per year than CG veterans (mean [SD], 13.93 [20.08] vs 8.46 [14.96] visits a year; median [range], 7.14 [0.00-246.30] vs 3.76 [0.00-202.38] visits per year). In adjusted models, compared with CG veterans, TGD veterans were 2.6 times more likely to have an outpatient mental-health visit (odds ratio, 2.60; 95% CI, 2.16-3.15).Conclusions and RelevanceIn this cohort study of veterans with depression, TGD veterans had significantly higher utilization of mental health services compared with CG veterans, even after adjusting for several relevant health factors. Different health system resources may be required to meet the needs of this population. Further studies are needed to understand the determinants of these disparities and subsequently how to address them.
NN‐Enriched Nucleoside Analogs
Authors: Wauchope Orrette R. 
Published: January 2025

Abstract
Nitrogen enrichment has played a pivotal role in the discovery of several key bioactive compounds, targeting several disease states. Nucleosides containing NN bonds have been at the forefront of these discoveries. In this chapter, the medicinal properties of NN enriched‐nucleosides such as triazoles, pyrazole, tetrazole, pyridazine, and triazines possessing a variety of substitutions will be discussed. Additionally, the chemistry driving the discovery of these important bioactive compounds will also be addressed. It is without a doubt that NN‐enriched nucleosides are at the forefront in understanding and developing pertinent bioactive probes/compounds. This will in part allow for the development of several more innovative bioactive NN‐enriched nucleoside analogs to increase the development of more medicinally relevant compounds.
Cyclic α‐/β‐Peptoids: Bioinspired Macrocyclic Peptidomimetics
Authors: Izzo Irene , D'amato Assunta , Pierri Giovanni , Riccardis Francesco De 
Published: January 2025

Abstract

Peptoid‐based macrocycles represent precious tools in biomimetic and supramolecular chemistry for their innate propensity to recognize biopolymers, molecules, and ion guests, and also for their impressive ability to adopt stable secondary structures and display remarkable chemical diversity. The ample variety of
N
‐substituted glycine available, the subtle host/guest interplay, and the efficient head‐to‐tail macrocyclization reactions greatly expand their potentials and functional capabilities. In this chapter, we report studies correlating sequence, structures, and functions of α‐/β‐cyclic peptoids reported in the chemical literature till 2021 and describe how crucial intramolecular interactions, cationic hosts, and strategically positioned stereogenic centers forge their morphologic attributes. The advances in the field of cyclic peptoids represent the first steps for the foundations of a rational design of protein mimetics and a possible model on which to base drug design and supramolecular/biomimetic chemistry.
Heterocycles with Fluorinated Explosophoric Functional Groups give Energetic Materials
Authors: Shen Hongjing , Liu Yinle , Gao Haixiang , Shreeve Jean'ne M. 
Published: January 2025

Abstract
The incorporation of explosophoric functional groups containing fluorine has been found to enhance the overall energetic characteristics of heterocycles. Fluorine‐containing compounds have been extensively investigated as potential high‐energy materials. Compared to nitrogen‐rich heterocycles lacking fluorine, those containing fluorine exhibit superior properties owing to their higher density and enhanced stability. By combining heterocycles with explosophoric functional groups that contain fluorine, numerous advanced high energy density materials (HEDMs) have been synthesized. This review is an overview of recent progress in the design of fluorine‐containing energetic compounds, encompassing data on their synthesis methods, physical attributes, and detonation properties wherever possible. Owing to their synthetic potential and exceptional properties, fluorine‐containing energetic materials hold great potential for the development of highly energetic materials for both civilian and military applications.
NN‐Enriched Nucleic Acids and Their Components
Authors: Wauchope Orrette R. 
Published: January 2025

Abstract
Undoubtedly, N–N enriched molecules have been prevalent in the exploration of DNA and RNA structure and function. This prevalence has been expedited by the continued development of Huisgen [3 + 2] cycloaddition, or “click chemistry.” Click chemistry has enabled the syntheses of several varieties of N–N enriched oligonucleotides having a myriad of functionalities from gene silencing, molecular imaging to the understanding DNA polymerase activity. In this chapter, the inclusion of N–N enriched nucleobases and their impact on several scientific fields will be discussed. Emphasis will be placed on oligonucleotides having triazole, pyrazole, pyridazine, and pyrazine nucleobase modifications.
Ocean Currents Compensation‐Based IAILOS‐ROESOs Guidance and Adaptive Sliding Mode Path Following Control for Unmanned Surface Vehicles
Authors: Zhang Huang , He Zhiping , Wang Guofeng , Fan Yunsheng , Song Baojian 
Published: January 2025

ABSTRACTThis article studies the problem of path following for unmanned surface vehicles (USVs) with ocean currents and input saturation and proposes an ocean currents compensation‐based improved adaptive integral line‐of‐sight with reduced‐order expanded state observers (IAILOS‐ROESOs) guidance and adaptive integral sliding mode control (AISMC) compound guidance‐control method. In the guidance module, an IAILOS‐ROESOs guidance law is presented to estimate ocean currents of varying strengths, compensating for the effects of ocean currents at the kinematics level. Then, the AISMC law with the RBF neural network and parameter update law are introduced to approximate the lumped disturbances and estimate their bounds of the estimation error in the control module. Meanwhile, integrating nonlinear differential estimators and improved auxiliary dynamic systems with a smoothly switching function, achieves the differential signal filtering and input saturation, and the hyperbolic tangent saturation function with adjustable parameters is further used to improve the robustness of the system. Theoretical analysis indicates that all errors converge to zero. Finally, the effectiveness of the control strategy is verified through comparative simulations.
Monolayer Interfacial Assembly toward Two‐Dimensional Mesoporous Heterostructure for Boosting Wave Absorption
Authors: Zhang Zelin , Chen Aibing , Li Xiao , Li Ruonan , Zhou Haowei , Liu Zhongming , Zhang Xinyue , Jing Xudong , Lin Zhongxue , Zhou Di , Kong Biao , Xie Lei 
Published: January 2025

AbstractMicrowave absorption materials play a key role in various fields, including military stealth, human safety protection, and so on. Construction of 2D mesoporous heterostructures is an attractive approach to enhance wave‐absorbing ability, while it is still a great challenge. Herein, 2D mesoporous carbon‐MXene‐carbon heterostructures (MCMCH) with channels parallel to surface are successfully prepared via a monolayer interfacial assembly strategy. Through the precise adjustment and polymerization, cylindrical micelles orderly monolayered assemble on both surfaces of 2D MXene nanosheets, resulting in 2D switch‐like polydopamine‐MXene‐polydopamine nanosheets, and 2D MCMCH are finally generated by further calcination. Due to the excellent dielectric polarization relaxation and conductive loss, MCMCH achieves the strongest reflection loss of −54.2 dB at a thickness of only 1.5 mm. The presence of mesochannels not only introduces air with a low permittivity for optimal impedance matching, but also further extends the attenuation path of the incident electromagnetic wave. The maximum radar cross‐section reduction of 26.9 dB m2 is achieved for the MCMCH compared to the perfect electric conductor. This work provides a reference for surface engineering based on 2D mesoporous heterostructures to enhance the microwave absorption performance.
Modulating the Electronic Properties of Single Ni Atom Catalyst via First‐Shell Coordination Engineering to Boost Electrocatalytic Flue Gas CO2 Reduction
Authors: Wang Zhiyuan , Chen Zhen , Du Xin , Zhang Yueteng , Liu Zhongyi , Zang Shuang‐Quan 
Published: January 2025

AbstractElectrochemical converting CO2 to CO via single atom catalyst is an effective strategy for reducing CO2 concentration in the atmosphere and achieving a carbon‐neutral cycle. However, the relatively low CO2 concentration in industrial processes and large energy barriers for activating CO2 severely obstruct the actual application. Reasonably modulating the coordination shell of the active center is an effective strategy to enhance the activity of single atom catalysts. Herein, a well‐designed single‐atom electrocatalyst Ni‐N3S1 is developed via a large‐scale synthesis strategy. The constructed Ni‐N3S‐C exhibits a superior catalytic activity than Ni‐N4‐C for CO2 to CO conversion in H‐type cells, and the industrial‐level current density with excellent durability at a wide pH range can be achieved in gas‐diffusion flow cells. Experimental results and density functional theory (DFT) calculation demonstrate that introducing low electronegative S in an active center can significantly regulate the electronic structure of the active site, promoting the CO2 adsorption capacity and decreasing the energy barrier of *COOH formation, thus the larger size and flexibility of sulfur mitigate the nickel agglomeration and enhance the stability of Ni‐N3S‐C catalyst. This work provides an effective strategy for designing highly active single‐atom catalysts for electrocatalysis via modulating the coordination shell of reactive sites.
Revolutionizing Perovskite Solar Cells with Carbon Electrodes: Innovations and Economic Potential
Authors: Chen Ming , Wang Nan , Bai Dongliang , Li Yixuan , Yang Shaoan , Wang Ziyu , Zhu Xuejie , Yang Dong , Liu Shengzhong (Frank) 
Published: January 2025

AbstractPerovskite solar cells (PSCs) have made remarkable strides, positioning themselves as a leading technology in the pursuit of efficient and affordable renewable energy. A critical bottleneck of their continued advancement is electrode material, which plays an important role in determining both device efficiency and stability. Carbon‐based electrodes have emerged as a promising alternative to traditional metal counterparts, offering several key benefits, including lower production costs, environmental‐friendly, and improved long‐term stability. This review provides a comprehensive analysis of the material compatibility, durability challenges and recent advancements in PSCs with carbon electrodes. By exploring innovative approaches and breakthroughs, we aim to pave a way for the future development of high‐performance, cost‐effective, and sustainable perovskite photovoltaics.