bluuebunny/crossref_metadata_2025_split huggingface dataset:
Structures and Electronic Properties of Titanium Oxo Clusters with Tartrate Ligand: A Density Functional Theory Study
Authors: HUANG Jing , YANG Lei , ZENG Shasha 
Published: July 2023

Titanium oxo clusters are considered a model for nanotitanium dioxide and have gradually become a new field of functional materials in solar cells. In this work, the precise structural information of two types of tartrate-based titanium-oxo clusters was investigated by quantum chemical approaches. Density functional theory (DFT) and time-dependent density functional theory (TDDFT) calculations provided the precise structural parameters of Ti4(C4H2O6)(AS)2(OiPr)10 and Ti4(C4H2O6)(ATS)2(OiPr)10. Our work provided reliable results in agreement with the experimental results. In both molecules, the Ti-O bonds were mainly divided into three categories: the bonds in the first category were the coordination bonds between the central skeleton Ti atom and the tartaric acid group, whose bond lengths were 2.000 – 2.080 Å; the bonds in the second category were the coordination bond formed by the Ti atom and the oxygen on the AS ligand sulphonic acid group, whose bond lengths were 2.148 – 2.310 Å; the bonds in the third category were the Ti-O bonds with shorter bond lengths, which were the coordination bond formed by the Ti atom and the oxygen on the isopropylalkoxy group with their bond lengths in the value range from 1.777 Å to 1.795 Å. These kinds of Ti-O bonds also can be found in other Ti4 titanium-oxo clusters. Molecular orbitals showed that electron transfer from the AS/ATS ligand to the {Ti4} central skeleton was induced by sunlight with maximum UV-Vis absorption of 605/629 nm. Our calculation results provide strong guidance for the discovery of new efficient titanium oxo in solar cells.
Dizziness Handicap Inventory: autopercepción de los síntomas al inicio de la rehabilitación en sujetos con déficits vestibulares
Authors: Caldara Betina , Sanchez Correa Cecilia Mariel , Heberling Tamara , Canale Delfina 
Published: July 2023

Objetivo: Clasificar los síntomas autopercibidos en leves, moderados o graves y describir el dominio más afectado del Dizziness Handicap Inventory (DHI) según sexo, tipo de desorden vestibular y edad al inicio de un programa de rehabilitación vestibular (RV).
Materiales y método: Estudio observacional, descriptivo, transversal y retrospectivo. Se incluyeron sujetos mayores de 18 años con déficits vestibulares que concurrieron a la entrevista inicial de un programa de RV en un consultorio de kinesiología de la Ciudad Autónoma de Buenos Aires entre 2011 y 2021. Las variables se agruparon en primarias (autopercepción de discapacidad) y secundarias (sexo, tipo de desorden vestibular y edad).
Resultados: Se incluyeron 527 sujetos. El 45% de los sujetos presentaron sintomatología leve; el 38%, moderada y el 16%, grave. Los sujetos más jóvenes refirieron sintomatología moderada, mientras que en el resto de los grupos refirieron sintomatología leve. Las mujeres presentaron mayor autopercepción de síntomas. Los sujetos con síndromes vestibulares periféricos obtuvieron puntajes menores en el DHI.
Conclusión: Los síntomas autopercibidos fueron de moderados a graves en el 54% de los sujetos, y los dominios más afectados fueron el físico y funcional. Esta información resulta relevante, ya que nos permite plantear objetivos claros tendientes a disminuir los síntomas y la discapacidad consecuente, y así mejorar la calidad de vida en sujetos con déficits vestibulares.
Paresias y parálisis de grupos musculares de miembro superior y miembro inferior en sujetos post infección por SARS-CoV-2 ingresados a kinesiología motora en un centro de rehabilitación en la Ciudad Autónoma de Buenos Aires
Authors: Sanchez Correa Cecilia Mariel , Simes Natalia , Fernández Esteban , Aon María José , Díaz Tabares Milagros , Errani Fabiana Magdalena , Fernández Quintero Jemina , Gomezcoello Gilbert Johanna , Gonzalez Cecilia del Valle , Pérez Harguindeguy Soledad , Turano María Laura 
Published: July 2023

Objetivo: Describir la incidencia de parálisis o paresias focalizadas de grupos musculares de miembro superior (MS) y de miembro inferior (MI) en sujetos post infección por SARS-CoV-2 al ingreso a kinesiología motora en un centro de rehabilitación en CABA, y describir las características clínico-demográficas de los sujetos.
Materiales y método: Estudio descriptivo, observacional y retrospectivo. Los datos se obtuvieron de las historias clínicas de los sujetos internados. Las variables que se registraron fueron la presencia de paresias o parálisis de los grupos musculares de MS y de MI, el tiempo de evolución de la COVID-19, los antecedentes, la medicación, la duración en decúbito prono, la edad y el sexo.
Resultados: Se incluyeron 84 sujetos. El 85% (n=71) fueron hombres, con una mediana de edad de 62 años. La incidencia total de paresias o parálisis focalizadas de los grupos musculares de MS y de MI fue del 57% (n=84). El 49% (n=41) de los sujetos presentaron hipertensión arterial (HTA); el 30% (n=25), diabetes y el 29% (n=24), obesidad. El 89% (n=75) de los sujetos tomaban 3 o más medicamentos y el 56% (n=47) estuvieron en decúbito prono.
Conclusión: La incidencia total de paresias o parálisis de los grupos musculares de MS y de MI fue del 57% (n=84) en sujetos post infección por SARS-CoV-2 al ingreso a kinesiología motora en un centro de rehabilitación de CABA. El 56% (n=47) estuvieron en decúbito prono. La mayoría fueron hombres de 62 años, con 55 días de evolución de la COVID-19, HTA y polifarmacia.
Uji Kualitas Fisik Dan Kimiawi Dedak Padi Penggilingan Di Kecamatan Nggadungala, Kabupaten Sumba Timur
Authors: Nggiku Andronikus Kahumbu , Sudarma I Made Adi 
Published: July 2023

Penelitian ini dilakukan di Kecamatan Ngadungala, Kabupaten Sumba Timur. Tujuan penelitian ini untuk mengetahui uji kualitas fisik dan kimiawi dedak padi penggilingan, sebanyak 7 pemilik usaha penggilingan padi. Metode penelitian yang di gunakan yaitu metode wawancara langsung kepada pemilik penggilingan yang ada di Kecamatan Ngadungala, Kabupaten Sumba Timur sebanyak 7 penggilingan. Uji kualitas fisik yang dilakukan uji kerapatan tumpukan dedak padi yang mengeluarkan sekam dan tidak mengeluarkan sekam, uji kimiawi yang lihat yaitu uji proksimat. Analisis data menggunakan uji T untuk kualitas fisik, sedangkan pengujian kualitas uji kimiawi menggunakan analisis deskriptif. Hasil penelitian dedak padi di setiap penggilingan Kecamatan Ngadungala memiliki rata-rata kerapatan tumpukan dan nilai kerapatan pemadatan tumpukan dedak padi pada T1 memiliki nilai tidak berbeda dibandingkan dengan dedak padi yang tidak mengeluarkan sekam (T2). Demikian juga pada uji kimiawi dedak padi yang hanya sedikit menunjukkan adanya kualitas yang lebih baik pada T1 dibandingkan T2. Nilai kualitas kimiawi dedak di Kecamatan Ngadungala memiliki rata-rata BK 86.748%, PK 15.241%, dan SK 14.322%. Disimpulkan bahwa kualitas dedak padi di Kecamatan Ngandungala cukup baik dan dapat dijadikan sebagai salah satu bahan pakan ternak yang baik.
Trichorhinophalangeal Syndrome Type 1 Is a Highly Sensitive and Specific Marker for Diagnosing Triple-Negative Breast Carcinomas on Cytologic Samples
Authors: Lynn Terrance J. , Shi Jianhui , Liu Haiyan , Monaco Sara E. , Prichard Jeffrey W. , Lin Fan 
Published: July 2023

Context.—
Definitive diagnosis of metastatic triple-negative breast carcinoma (TNBC) is challenging on cytologic samples. Recent studies demonstrated that trichorhinophalangeal syndrome type 1 (TRPS1) is a highly sensitive and specific marker for diagnosing breast carcinomas, including TNBC, on surgical specimens.

Objective.—
To evaluate TRPS1 expression in TNBCs on cytologic samples and a large series of nonbreast tumors on tissue microarray sections.

Design.—
Immunohistochemical (IHC) analysis of TRPS1 and GATA-binding protein 3 (GATA3) was performed on 35 TNBC cases on surgical specimens, and 29 consecutive TNBC cases on cytologic specimens. IHC analysis of TRPS1 expression was also performed on 1079 nonbreast tumors on tissue microarray sections.

Results.—
Of the surgical specimens, 35 of 35 TNBC cases (100%) were positive for TRPS1, all with diffuse positivity, whereas 27 of 35 (77%) were positive for GATA3, with diffuse positivity in 7 cases (26%). Of the cytologic samples, 27 of 29 TNBC cases (93%) were positive for TRPS1, with diffuse positivity in 20 cases (74%), whereas 12 of 29 (41%) were positive for GATA3, with diffuse positivity in 2 cases (17%). Of the nonbreast malignant tumors, TRPS1 expression was seen in 9.4% (3 of 32) of melanomas, 10.7% (3 of 28) of small cell carcinomas of the bladder, and 9.7% (4 of 41) of ovarian serous carcinomas.

Conclusions.—
Our data confirm that TRPS1 is a highly sensitive and specific marker for diagnosing TNBC cases on surgical specimens as reported in the literature. In addition, these data demonstrate that TRPS1 is a much more sensitive marker than GATA3 in detecting metastatic TNBC cases on cytologic samples. Therefore, inclusion of TRPS1 in the diagnostic IHC panel is recommended when a metastatic TNBC is suspected.
Middle to late Tertiary geology of the Cedar Hills-Selden Hills area, Dona Ana County, New Mexico
Authors: Seager William R. , Clemons Russell E. 
Published: July 2023

Rocks in the Cedar Hills and Selden Hills provide an excellent record of 1) Oligocene volcanism in the Cedar Hills vent zone, 2) the timing of initial rifting in the Rio Grande rift, and 3) the Miocene-Pliocene evolution of the rift. Volcanic activity in the Cedar Hills vent zone about 35 m.y. ago was concentrated along a northtrending zone at least 20 miles long and as much as 4 miles wide. Initial rhyolitic tephra eruptions were closely followed by emplacement of an ash-flow tuff sheet from fissures within the vent zone, and by the formation of tuff cones, diatremes, and collapsed areas. Volcanic activity in the zone was climaxed by the intrusion of at least 21 flow-banded rhyolite intrusions. The vent zone, together with other north-trending Oligocene faults and basins, all generally parallel to the Rio Grande rift, suggest that these features may be precursors of the rift. The transition into active faulting within the Rio Grande rift is marked by outpouring of Uvas Basaltic Andesite (26 m.y.). Initial rifting is indicated by eruption of basaltic andesite from a cinder cone constructed across the Cedar Hills fault, one of the large, throughgoing rift faults of the region. The interfingering of basaltic andesite flows with fanglomerate derived from the uplifted block suggests rifting was in progress at least 26 m.y. ago.Late Tertiary evolution of the rift is characterized by the development of deep, broad downwarps in Miocene time that were filled with bolson deposits, and then segmented into smaller intrabasin uplifts and grabens in Pliocene time. Many of the uplifts of the region appear to have formed initially in Pliocene time, while others originated as early as earliest Miocene or latest Oligocene.
Sedimentology of braided alluvial interval of Dakota Sandstone, northeastern New Mexico
Authors: Gilbert J. L. , Asquith G. B. 
Published: July 2023

The Dakota Sandstone in northeastern New Mexico is subdivided into three intervals. The Lower interval is a braided alluvial sheet composed of fine- to medium-grained, cross-stratified sandstone with conglomerate lenses. The middle interval represents a meander-belt environment and contains fine- to very fine grained, lenticular sandstone with interbedded carbonaceous shale and coal. The upper interval represents a transgressive marine succession containing fine- to very fine grained, horizontally stratified sandstone with burrow casts of Ophiomorpha.Paleocurrent analysis of the braided alluvial interval indicates a dominant southeasterly transport direction. This conclusion is supported by a decrease in mean grain size and thickness to the east and southeast. Analysis of the stratification ratio indicates that proximal braided-stream facies are predominant in the west and northwest parts of the study area, and that distal braided-stream facies are predominant to the east and southeast. The sediment dispersal pattern and the presence of proximal braided stream facies indicate that the source areas were the San Luis and Apishapa uplifts of Colorado and New Mexico.
Psycoeducation of Responsible Scouts Care for Others in Disaster Response
Authors: Noviekayati I.G.A.A. , Samudra Eric Arizona , Valerie Carissa , Ariyanto Rizky , Barata Mahardi Setia 
Published: July 2023

The attitude of disaster response to disaster-affected communities in general is an urgent priority to be given so that the community becomes resilient. So far, people are accustomed to relying on government assistance and are not able to provide an appropriate first response. This is because the community does not understand how to act appropriately when a disaster occurs in the area where they live. Law No. 24 of 2007 on Disaster Management. The subjects in this study were 110 Advanced Coaches, the Surabaya Kwarcab Helping Brigade, the Surabaya Kwarcab Care Scouts, the Surabaya Kwartir Branch Work Council using a knowledge scale on disaster response and psychoeducation related to Psychological First Aids. The results of the calculation of the t test (Paired Sample Test) obtained the results of t = 6.473 at p = 0.000. This means that between the pre-test and post-test of there is a very significant difference the experimental group in the knowledge of disaster response. The pre-test of the experimental group (Mean = 96.2553) was higher than the post-test of the experimental group (Mean = 88.5745), this indicates that PFA psychoeducation can increase knowledge about disaster response, thus indicating a significant relationship between psychoeducational independent variables. PFA with the dependent variable is knowledge about disaster response. The implication of this research is that it is expected to become an extension program so that it can increase knowledge related to disaster mitigation so that in the future members of the Rescue Brigadier can become the vanguard of disaster mitigation.
Reaching IMO 2050 GHG Targets Exclusively Through Energy Efficiency Measures
Authors: Lindstad Elizabeth , Polic Dražen , Rialland Agathe , Sandaas Inge , Stokke Tor 
Published: July 2023

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Maritime transport accounts for around 3% of global anthropogenic greenhouse gas (GHG) emissions (Well-to-Wake). These GHG emissions must be reduced by at least 50% in absolute values by 2050 to contribute to the ambitions of the Paris Agreement signed in 2015. Switching to zero-carbon fuels made from renewable sources (hydro, wind, or solar) is seen by many as the most promising option to deliver the desired GHG reductions. However, renewable energy is a scarce resource that gives a much larger GHG reduction spent within other sectors. This study explores how to reach the IMO 2050 GHG targets exclusively through energy efficiency measures. The results indicate that by combining wind-assisted ship propulsion (WASP) with a slender hull form, fuel consumption and GHG emissions can be reduced by 30–35%, at a negative abatement cost for speeds exceeding 8 knots. Where the cost saving increases with the speed because at higher speeds, the fuel accounts for a higher share of the total cost, which implies that the cost saving goes from zero at 8 knots, to 5% reduction at 11 knots average speed to 14% reduction of total cost with 15 knots average speed. In comparison, GHG reductions through zero-carbon fuels will increase transport costs by 50–200%.

Introduction
From the first days of our civilization, sea transport has enabled regional and global trades. Today, sea transport accounts for 80% of the global trade measured in ton-miles (UNCTAD 2021) and 3% of greenhouse gas (GHG) emissions measured Well-to-Wake (Lindstad et al. 2021). More than 40% of this sea trade is performed by dry bulkers, making them the real workhorses of the sea. Even though sea transport is energy efficient compared to other transport modes, all sectors need to reduce their GHG emissions by at least 50% in absolute values by 2050 to contribute to the Paris Agreement (UNFCCC 2015). According to Bouman et al. (2017), the desired energy and GHG reductions can be achieved through: Design and other technical improvements of ships; Operational improvements; Fuels with zero or low GHG footprints; or a combination of these.
Music Composition Magringsing | Komposisi Tabuh “Magringsing”
Authors: Rama Rama Widana , - Wardizal 
Published: July 2023

Magringsing adalah sebuah garapan tabuh kreasi yang terinspirasi dari proses pembuatan kain tenun gringsing di Desa Tenganan Pegringsingan. Pada tahap pembuatan kain gringsing, terdapat teknik yang cukup unik dan jarang digunakan pada jenis kain tenun lainnya yaitu menggunakan teknik double ikat dengan jalinan benang pakan dan lungsin yang dijalin antara satu sama lain dengan cara vertikal dan horizontal sehingga menghasilkan kesatuan motif-motif yang utuh, menarik serta memiliki nilai estetika. Garapan Magringsing dilandasi pemikiran yang berpijak kepada pola-pola tradisi yang telah ada pada karya-karya yang telah diciptakan sebelumnya dengan adanya pengembangan unsur-unsur musikal yang dituangkan ke dalam media ungkap gamelan Semar Pegulingan Saih Pitu. Metode penciptaan yang digunakan dalam garapan Magringsing adalah metode penciptaan Panca Sthiti Ngawi Sani yang meliputi tahap inspirasi (ngawirasa), tahap eksplorasi (ngawacak), tahap konsepsi (ngarencana), tahap eksekusi (ngawangun) dan tahap produksi (ngebah). Garapan Magringsing terdiri dari empat bagian, dan durasi keseluruhan garapan yaitu 11 menit. Melalui garapan Magringsing diharapkan dapat meningkatkan minat masyarakat untuk lebih mencintai dan mengapresiasi produk lokal Bali yang sarat akan filosofi, dan tentunya memiliki nilai keindahan dan keistimewaan seperti kain gringsing.

Kata Kunci: Magringsing, double ikat, Panca Sthiti Ngawi Sani
Musical Creation: Aku dan Kamu Bukan Kita | Kreasi musik: Aku dan Kamu Bukan Kita
Authors: Junaedi I Putu Agus , - Saptono , Ruastiti Ni Made 
Published: July 2023

Karya seni karawitan baru berjudul “Aku dan Kamu bukan Kita”, ini bermakna pada penunjukan aku (penata), masyarakat penonton (kamu), (bukan kita) merupakan perbedaan interpretasi, apresiasi, dan pemahaman masing-masing individu yang menikmati karya ini. Artinya bahwa dalam kehidupan ini kita harus menyadari adanya perbedaan prinsip, persepsi, cara pandang, perlakuan dalam kehidupan. Perbedaan itu indah dan tidak mesti diseragamkan. Kita harus saling menerima dan saling menghargai perbedaan, karena perbedaan adalah pengayaan yang dapat digunakan untuk saling melengkapi dan saling mengisi kekurangan satu sama lainnya. Penciptaan karya ini bertujuan untuk menampilkan warna baru dalam seni karawitan Bali yang selama ini selalu dimainkan secara berkelompok, dan masing-masing orang memainkan satu instrumen. Berbeda halnya dibandingkan dengan garapan baru ini, yang dalam penyajiannya menggunakan satu instrumen, dimainkan oleh satu orang pemain. Sajian musik solois ini dikembangkan dari instrumen tingklik dengan mengadopsi teknik permainan berbagai alat pukul instrumen tradisional Bali. Penciptaan karya seni karawitan baru “Aku dan Kamu bukan Kita”, ini dilakukan dengan menggunakan metode penciptaan yang dikemukakan oleh I Wayan Senen yaitu melalui proses rangsangan awal, kemudian dilanjutkan dengan proses implementasi gagasan dengan menggunakan proses penciptaan yang dikemukakan oleh Halma Hawkins, melalui tahapan eksplorasi, improvisasi, dan pembentukan. Inovasi karya seni karawitan baru yang dimainkan secara solois ini mengembangkan teknik permainan instrumen yang diadopsi dari berbagai macam teknik instrumen pukul di Bali.
The Transformation of Wargasari’s Kidung into Composition “Wehyang” | Transformasi Kidung Wargasari ke dalam Komposisi Karawitan “Wehyang”
Authors: Purna Yasa I Made Rai , Santosa Hendra 
Published: July 2023

Karya seni karawitan yang berjudul “WeHyang” merupakan karya seni yang terinspirasi dari tradisi Mesucian yang terdapat di Desa Kapal. Karya seni karawitan “WeHyang” terinspirasi dari kidung wargasari yang digunakan sebagai nyanyian suci dalam prosesi tradisi berlangsung. Alunan bait-bait kidung yang dinyanyikan dengan padalingsa yang berbeda setiap baitnya ditransformasikan ke dalam pola – pola gamelan. Gamelan yang digunakan sebagai media ungkap dalam karya seni karawitan “WeHyang” yaitu gamelan selonding. Gamelan selonding terdiri dari nyongnyong ageng, nyongnyong alit, peenem, petuduh, gong dan kempul. Dalam karya ini dibagi menjadi 3 bagian yaitu bagian 1 dengan transformasi 4 baris kidung, bagian kedua transformasi 4 baris kidung dan bagian ketiga gabungan dari semua transformasi yang dituangkan dalam pola-pola gamelan selonding. Adanya pengembangan pola-pola melodi, teknik-teknik permainan yang sudah ada terkandung dalam karya seni karawitan “WeHyang”.
Kata kunci: WeHyang, Selonding, Kidung.
Design principles for higher education teacher development
Authors: Pischetola Magda , Kilberg Møller Jeppe 
Published: July 2023

This study moves from the research question: how to design a professional course/concept for the development of higher education teachers’ digital competences? It presents Teknosofikum, a project funded by the Danish Ministry of Higher Education and Science between 2020 and 2023. The outcome of the project is a course for higher education teachers with a focus on digital competence. Grounded in sociomaterial theories, digital competence refers here to the capacity to develop agency towards professional changes driven by technology. It comprises teachers’ abilities to evaluate why, when, how and with what effects to include digital technologies in teaching. The study draws on qualitative and quantitative data gathered through design-based research along the first three course iterations,with a total of 64 participants. The findings show the emergence of three design principles: (i) relational approach to technology; (ii) praxis; and (iii)organized non-linearity. These principles will guide the final format of Teknosofikum course/concept.
PROBLÉMATIQUE D’ACCUMULATION CHEZ LES PERSONNES ÂGÉES : UNE ÉTUDE QUALITATIVE DES INTERACTIONS ENTRE LES PERSONNES ACCUMULATRICES, LES PERSONNES PROCHES AIDANTES ET LES AUTRES ACTEURS IMPLIQUÉS
Authors: Moreau Annik , Dallaire Bernadette 
Published: July 2023

Les données épidémiologiques citées dans leDiagnostic and Statistical Manual of Mental Disorders(American Psychiatric Association [APA], 2013) estiment la prévalence de la syllogomanie dans une fourchette de 2 % à 6 % des populations générales des pays occidentaux, la proportion étant plus importante chez les personnes âgées de 55 ans et plus. La réponse aux besoins des personnes âgées aux prises avec cette problématique repose généralement sur le soutien des familles et des proches, qui doivent composer avec les difficultés de la personne âgée concernée à se départir de ses biens et à son refus de recevoir du soutien. Notre étude vise à mieux comprendre comment les personnes proches aidantes (PPA) se coordonnent avec les personnes accumulatrices et avec les autres acteurs impliqués, et comment cela affecte leurs interactions. Nous avons réalisé des entretiens semi-dirigés avec onze PPA et huit intervenantes sociales de la région de Québec; le matériel recueilli a été soumis à une analyse thématique des contenus. Nos résultats suggèrent que la problématique d’accumulation fait l’objet de négociations au sein de la dyade aidant(e)-aidé(e), ainsi que dans les interactions avec les autres intervenant(e)s impliqués. On y constate aussi que les professionnel(le)s en travail social ont parfois à jouer le rôle de médiateurs ou de médiatrices et à assurer le respect des droits des différents acteurs en permettant des ajustements dans les interactions.