bluuebunny/crossref_metadata_2025_split huggingface dataset:
Competencias relevantes en contabilidad. La perspectiva de estudiantes y empleadores
Authors: Blasco Burriel María Pilar , Costa Toda Alicia , Labrador Barrafón Margarita 
Published: January 2023

University education is focused on the acquisition of skills by students, regardless of the technical nature of the subjects and syllabus. In the field of accounting, previous literature has confirmed the existence of a gap in expectations between the skills of students and what would be desirable from a professional perspective. The main contribution of this paper is the analysis of desirable and acquired competences from two perspectives: students and employers, with the aim of analyzing to what extent the competences acquired by future accounting professionals are adapted to those required. The study includes both generic and accounting-specific competences. The results confirm that both groups (students and employers) agree on the skills required of accountants and confirm that these relevant skills are not being adequately acquired, showing that there is an expectation gap with regard to the skills acquired.
La formación universitaria está orientada a la adquisición de competencias por parte de los estudiantes, con independencia del carácter más o menos técnico de las materias. En el ámbito de la contabilidad, la literatura previa ha constatado la existencia de un gap de expectativas entre la formación de los estudiantes y la que sería deseable desde una perspectiva profesional. La principal contribución de este trabajo es el estudio de las competencias desde dos perspectivas: estudiantes y empleadores, con el objetivo de analizar en qué medida las competencias adquiridas por los futuros profesionales de la contabilidad se adaptan a las demandadas. Además, se incluyen en el estudio tanto las denominadas competencias genéricas como las específicas de las materias de contabilidad. Los resultados constatan que ambos colectivos (estudiantes y empleadores) se muestran coincidentes en las competencias que debería poseer un profesional de la contabilidad actual y corroboran que esas competencias relevantes no se están adquiriendo en el grado necesario, evidenciando que existe gap de expectativas en la formación.
Acute physiological outcomes of high-intensity functional training: a scoping review
Authors: McDougle Jacob M. , Mangine Gerald T. , Townsend Jeremy R. , Jajtner Adam R. , Feito Yuri 
Published: January 2023

BackgroundSystematic reviews and meta-analyses related to high-intensity functional training (HIFT) have been conducted. However, due to a restricted pool of available research, these investigations are often limited in scope. As such, a scoping review investigating the present literature surrounding the acute physiological response to HIFT-based exercise was chosen as a more appropriate structured review.MethodologyA scoping review was conducted following Arksey and O’Malley’s framework. Three large scale databases were searched to reveal any article pertaining to HIFT and related exercise terminology.ResultsA total of 2,241 articles were found during the initial search. Following this, titles, then abstracts, and full-texts were reviewed to determine inclusion eligibility. A total of 60 articles which investigated a combined total of 35 unique HIFT workouts were included within this review.ConclusionsA variety of physiological parameters and HIFT workouts have been examined. Markers of intensity (e.g., blood lactate concentrations, heart rate) have been most consistently assessed across all studies, and these support the idea that HIFT workouts are typically performed at high-intensity. In contrast, the inclusion of most other measures (e.g., hormonal, markers of inflammation and damage, energy expenditure, performance) has been inconsistent and has thus, limited the possibility for making generalized conclusions. Differences in study methodologies have further impacted conclusions, as different studies have varied in sample population characteristics, workouts assessed, and time points. Though it may be impossible to comprehensively research all possible HIFT workouts, consistent adoption of population definitions and workload quantification may overcome this challenge and assist with future comparisons.
Insular holobionts: persistence and seasonal plasticity of the Balearic wall lizard (Podarcis lilfordi) gut microbiota
Authors: Baldo Laura , Tavecchia Giacomo , Rotger Andreu , Igual José Manuel , Riera Joan Lluís 
Published: January 2023

Background
Integrative studies of animals and associated microbial assemblages (i.e., the holobiont) are rapidly changing our perspectives on organismal ecology and evolution. Insular vertebrates provide ideal natural systems to understand patterns of host-gut microbiota coevolution, the resilience and plasticity these microbial communities over temporal and spatial scales, and ultimately their role in the host ecological adaptation.

Methods
Here we used the endemic Balearic wall lizard Podarcis lilfordi to dissect the drivers of the microbial diversity within and across host allopatric populations/islets. By focusing on three extensively studied populations/islets of Mallorca (Spain) and fecal sampling from individually identified lizards along two years (both in spring and autumn), we sorted out the effect of islet, sex, life stage, year and season on the microbiota composition. We further related microbiota diversity to host genetics, trophic ecology and expected annual metabolic changes.

Results
All the three populations showed a remarkable conservation of the major microbial taxonomic profile, while carrying their unique microbial signature at finer level of taxonomic resolution (Amplicon Sequence Variants (ASVs)). Microbiota distances across populations were compatible with both host genetics (based on microsatellites) and trophic niche distances (based on stable isotopes and fecal content). Within populations, a large proportion of ASVs (30–50%) were recurrently found along the four sampling dates. The microbial diversity was strongly marked by seasonality, with no sex effect and a marginal life stage and annual effect. The microbiota showed seasonal fluctuations along the two sampled years, primarily due to changes in the relative abundances of fermentative bacteria (mostly families Lachnospiraceae and Ruminococcaceae), without any major compositional turnover.

Conclusions
These results support a large resilience of the major compositional aspects of the P. lilfordi gut microbiota over the short-term evolutionary divergence of their host allopatric populations (<10,000 years), but also indicate an undergoing process of parallel diversification of the both host and associated gut microbes. Predictable seasonal dynamics in microbiota diversity suggests a role of microbiota plasticity in the lizards’ metabolic adaptation to their resource-constrained insular environments. Overall, our study supports the need for longitudinal and integrative studies of host and associated microbes in natural systems.
Influence of Irrigation Schedules on Yield and Nutrient Uptake of Groundnut Varieties
Authors: Chandini Shaik , Lakshmi N. Venkata , Rekha M. Sree , Babu M. Ravi 
Published: January 2023

Aim: Evaluation of different irrigation schedules on yield and nutrient uptake of groundnut varieties.
Study Design: The experiment was laid out in split plot design with different irrigation schedules in main plot and different groundnut varieties in sub plots and was replicated thrice.
Place and Duration of Study: The field experiment was conducted during rabi season of 2021 and 2022 at the Agricultural College Farm, Bapatla, ANGRAU, Lam, Guntur, Andhra Pradesh.
Methodology: The experiment was performed with twelve treatments in split plot design. The main plot comprised three different irrigation schedules (IW/CPE ratio of 1.0, 0.8 and 0.6) and sub plot with four different groundnut varieties (TAG-24, Dheeraj, Kadiri Lepakshi and Kadiri Chitravati). Observations of the crop and soil during the experimentation were recorded at regular intervals. The significance of the treatment impact was examined by the test.
Results: The experimental results indicated that among different irrigation schedules, IW/CPE ratio of 1.0 recorded highest pod yield (3175 kg ha-1) and haulm yield (4291 kg ha-1) which was significantly superior over IW/CPE ratio of 0.6 (pod yield-2579 kg ha-1 and haulm yield-3681 kg ha-1) but found on a par with IW/CPE ratio of 0.8 (pod yield-2916 kg ha-1 and haulm yield-4034 kg ha-1). Among the varieties, Kadiri Lepakshi recorded highest pod yield (3607 kg ha-1) and haulm yield (4647 kg ha-1) which was significantly superior over Kadiri Chitravati, Dheeraj and TAG-24 and lowest pod (2074 kg ha-1) and haulm yield (3424 kg ha-1) was recorded with TAG-24. Highest N, P and K uptake of plant (104.2, 11.8 and 54.3, respectively) was recorded with irrigation scheduled at IW/CPE ratio of 1.0 along with Kadiri Lepakshi compared to the other treatments.
BHRF1-1 MicroRNA of Epstein Barr Virus in Chronic B-Lymphocytic Leukemia Patients
Authors: El-Gohary Ahmed Mostafa , Orfao José Alberto , Gad Omnia Abd El-Fatah , El-Zamarany Enas Arafa , Zahra Mohammed Kamal 
Published: January 2023

Background: Epstein–Barr Virus (EBV) is one of the human gamma herpes viruses that promotes subclinical and latent infections in healthy B lymphocytes. This research objects to find out the value of expression of BHRF1-1 microRNA of EBV in chronic B- lymphocytic leukemia (B-CLL) patients.
Methods: This retrospective research involved 40 subjects diagnosed with B-CLL and positive for Epstein Barr Virus Nuclear Antigen-1 IgG (EBNA-1 IgG) and 40 healthy volunteers serving as the control group. Subjects were allocated equally into two groups: group I: 40 patients with B-CLL and group II: 40 healthy volunteers matched for age and sex with patients serving as a control group.
Results: There was a significant increase in BHRF1-1 expression in CLL cases than control group (P value <0.001). Overall survival was significantly higher in patients with low BHRF1-1 expression (<3.63) than the patients with overexpression of BHRF1-1 in B-cells that was related to shorter OS BHRF1-1 expression (>3.63) (p value 0.004). Lymphocyte count (≥50 x109/L), CD38 Expression, Rai Staging (III/ IV), FISH (17p deletion vs del 13q14, trisomy 12 and del 11q23) and relative expression of BHRF1-1(high) were the significant indicators.
Conclusions: EBV-encoded miRNAs are highly found in EBV-associated tumors as BHRF1-1 MicroRNA marker of EBV.
Spatial Analysis of Access to Psychiatrists for US Military Personnel and Their Families
Authors: Bacolod Marigee , Heissel Jennifer , Shen Yu-Chu 
Published: January 2023

ImportanceMilitary service members and their families have greater mental health care needs compared with their civilian counterparts. Some communities have inadequate access to psychiatrists for this population.ObjectivesTo identify geographic variations in the availability of military and civilian psychiatrists within a 30-minute driving time of TRICARE (the US military’s health care program) beneficiaries’ communities and compare the likelihood of living in areas with inadequate access to psychiatrists for historically underserved and other communities.Design, Setting, and ParticipantsThis retrospective cohort study of all zip code communities in the continental US, Hawaii, and Alaska with at least one TRICARE beneficiary between January 1, 2016, and September 30, 2020, combines data from the Defense Health Agency, the National Plan and Provider Enumeration System, and the US Census to estimate a logistic regression to compare differences between communities with and without a psychiatrist shortage. Data were analyzed from September 2021 to November 2022.Main Outcomes and MeasuresA community’s likelihood of having a shortage of military and civilian psychiatrists within a 30-minute driving time and a community’s likelihood of having no psychiatrists. Odds ratios were calculated to estimate likelihood of the outcomes.ResultsThis study includes 39 487 unique communities where 13% of the population is Black and 14% of the population is Hispanic. During the study period, 35% of TRICARE beneficiaries lived in communities with a shortage of both military and civilian psychiatrists, and 6% lived in communities with no access to military or civilian psychiatrists. Low-income communities with high income inequality were 1.64 (95% CI, 1.30-2.07) times more likely to have inadequate access to psychiatrists and 2.59 (95% CI, 1.82-3.69) times more likely to have no access to psychiatrists, compared with reference communities (average income without high income inequality); low-income communities without high income inequality were 1.37 (95% CI, 1.05-1.78) times more likely to have inadequate access to psychiatrists and 1.93 (95% CI, 1.28-2.89) times more likely to have no access to psychiatrists. Rural communities were 6.65 (95% CI, 5.09-8.69) times more likely to have inadequate access to psychiatrists than urban communities.Conclusions and RelevanceIn this cohort study of US communities, 35% of TRICARE beneficiaries lived in communities with inadequate access to psychiatrists. Psychiatric capacity was structurally inequitable along 2 separate dimensions: the income gradient and rurality. Developing targeted strategies for these shortage areas could alleviate disparities.
Changes in Tophus Composition During Urate‐Lowering Therapy: A Dual‐Energy Computed Tomography Study
Authors: Chen Leanne , Gamble Gregory D. , Horne Anne , Drake Jill , Doyle Anthony J. , Uhlig Till , Stamp Lisa K. , Dalbeth Nicola 
Published: January 2023

ObjectiveThe gouty tophus is an organized structure composed of monosodium urate (MSU) crystals and chronic inflammatory soft tissue. This dual‐energy computed tomography (DECT) study aimed to determine whether the composition of the tophus changes during urate‐lowering therapy.MethodsSerial DECT scans from 32 people with gout were obtained over 2 years of allopurinol therapy, dose‐escalated to serum urate of <0.36 mmoles/liter. Up to 5 index tophi were selected for each patient, with 103 separate tophi included in the analysis. Using manual outlining methods of conventional CT and DECT scans, the same index tophi were serially measured for total tophus volume and urate volume. For each tophus, the soft tissue volume was then calculated by subtracting the urate volume from the total tophus volume.ResultsThe mean ± SD serum urate reduced from 0.43 ± 0.03 mmoles/liter at baseline to 0.31 ± 0.02 mmoles/liter at year 2. The mean ± SD total tophus volume reduced over the 2‐year period from 5.17 ± 5.55 cm3 to 2.61 ± 2.73 cm3 (P < 0.0001). Greater reductions in tophus urate volumes than tophus soft tissue volumes were observed; the tophus urate volume decreased by 70.6%, and tophus soft tissue volume decreased by 37.8% (P < 0.0001). The mean tophus urate:soft tissue ratio reduced from 0.15 at baseline to 0.05 at year 2 (P < 0.001).ConclusionThe composition of the tophus is dynamic and changes during urate‐lowering therapy for gout management. The soft tissue component of the tophus is slower to respond and may persist without measurable MSU crystal deposition.
Pregnancy outcomes in women with sickle cell disease in California
Authors: Adesina Oyebimpe O. , Brunson Ann , Fisch Samantha C. , Yu Bo , Mahajan Anjlee , Willen Shaina M. , Keegan Theresa H. M. , Wun Ted 
Published: January 2023

AbstractAdverse pregnancy outcomes occur frequently in women with sickle cell disease (SCD) across the globe. In the United States, Black women experience disproportionately worse maternal health outcomes than all other racial groups. To better understand how social determinants of health impact SCD maternal morbidity, we used California's Department of Health Care Access and Information data (1991–2019) to estimate the cumulative incidence of pregnancy outcomes in Black women with and without SCD—adjusted for age, insurance status, and Distressed Community Index (DCI) scores. Black pregnant women with SCD were more likely to deliver at a younger age, use government insurance, and live in at‐risk or distressed neighborhoods, compared to those without SCD. They also experienced higher stillbirths (26.8, 95% confidence interval [CI]: 17.5–36.1 vs. 12.4 [CI: 12.1–12.7], per 1000 births) and inpatient maternal mortality (344.5 [CI: 337.6–682.2] vs. 6.1 [CI: 2.3–8.4], per 100 000 live births). Multivariate logistic regression models showed Black pregnant women with SCD had significantly higher odds ratios (OR) for sepsis (OR 14.89, CI: 10.81, 20.52), venous thromboembolism (OR 13.60, CI: 9.16, 20.20), and postpartum hemorrhage (OR 2.25, CI 1.79–2.82), with peak onset in the second trimester, third trimester, and six weeks postpartum, respectively. Despite adjusting for sociodemographic factors, Black women with SCD still experienced significantly worse pregnancy outcomes than those without SCD. We need additional studies to determine if early introduction to reproductive health education, continuation of SCD‐modifying therapies during pregnancy, and increasing access to multidisciplinary perinatal care can reduce morbidity in pregnant women with SCD.
Paroxysmal nocturnal hemoglobinuria: Where we stand
Authors: Panse Jens 
Published: January 2023

AbstractFor the last 20 years, therapy of paroxysmal nocturnal hemoglobinuria (PNH) relied—up until recently—on antibody based terminal complement inhibitionon. PNH pathophysiology—a mutational defect leading to partial or complete absence of complement‐regulatory proteins on blood cells—leads to intravascular hemolysis and consequences such as thrombosis and other sequelae. A plethora of new drugs interfering with the proximal and terminal complement cascade are under recent development and the first “proof‐of‐pinciple” proximal complement inhibitor targeting C3 has been approved in 2021. “PNH: where we stand” will try to give a brief account on where we came from and where we stand focusing on approved therapeutic options. The associated improvements as well as potential consequences of actual and future treatments as well as their impact on the disease will continue to necessitate academic and scientific focus on improving treatment options as well as on side effects and outcomes relevant to individual patient lives and circumstances in order to develop effective, safe, and available treatment for all hemolytic PNH patients globally.
Intramolecular Cyclization: A Convenient Strategy to Realize Efficient BT.2020 Blue Multi‐Resonance Emitter for Organic Light‐Emitting Diodes
Authors: Cao Chen , Tan Ji‐Hua , Zhu Ze‐Lin , Lin Jiu‐Dong , Tan Hong‐Ji , Chen Huan , Yuan Yi , Tse Man‐Kit , Chen Wen‐Cheng , Lee Chun‐Sing 
Published: January 2023

AbstractRationally tuning the emission position and narrowing the full width at half‐maximum (FWHM) of an emitter is of great importance for many applications. By synergistically improving rigidity, strengthening the resonant strength, inhibiting molecular bending and rocking, and destabilizing the HOMO energy level, a deep‐blue emitter (CZ2CO) with a peak wavelength of 440 nm and an ultranarrow spectral FWHM of 16 nm (0.10 eV) was developed via intramolecular cyclization in a carbonyl/N resonant core (QAO). The dominant υ0‐0transition character of CZ2CO gives a Commission Internationale de I’Éclairage coordinates (CIE) of (0.144, 0.042), nicely complying with the BT.2020 standard. Moreover, a hyper‐fluorescent device based on CZ2CO shows a high maximum external quantum efficiency (EQEmax) of 25.6 % and maintains an EQE of 22.4 % at a practical brightness of 1000 cd m−2.
Ligand Hybridization for Electro‐reforming Waste Glycerol into Isolable Oxalate and Hydrogen
Authors: Wu Jianxiang , Liu Xiang , Hao Yaming , Wang Shaoyan , Wang Ran , Du Wei , Cha Shuangshuang , Ma Xian‐Yin , Yang Xuejing , Gong Ming 
Published: January 2023

AbstractThe electro‐reforming of glycerol is an emerging technology of simultaneous hydrogen production and biomass valorization. However, its complex reaction network and limited catalyst tunability restrict the precise steering toward high selectivity. Herein, we incorporated the chelating phenanthrolines into the bulk nickel hydroxide and tuned the electronic properties by installing functional groups, yielding tunable selectivity toward formate (max 92.7 %) and oxalate (max 45.3 %) with almost linear correlation with the Hammett parameters. Further combinatory study of intermediate analysis and various spectroscopic techniques revealed the electronic effect of tailoring the valence band that balances between C−C cleavage and oxidation through the key glycolaldehyde intermediate. A two‐electrode electro‐reforming setup using the 5‐nitro‐1,10‐phenanthroline‐nickel hydroxide catalyst was further established to convert crude glycerol into pure H2 and isolable sodium oxalate with high efficiency.
Stabilization of liquid water‐in‐oil emulsions by modifying the interfacial interaction of glycerol monooleate with aqueous phase ingredients
Authors: Romero‐Peña Maria , Ghosh Supratim 
Published: January 2023

AbstractGlycerol monooleate (GMO)‐stabilized liquid water‐in‐vegetable oil emulsions are difficult to stabilize due to the desorption of GMO from the water‐vegetable oil interface toward the oil phase. This work improved the stability of GMO‐stabilized liquid 20 wt% water‐in‐canola oil (W/CO) emulsion by modifying the dispersed aqueous phase composition with hydrogen bond‐forming agents. As a control, 20 wt% water‐in‐mineral oil (W/MO) emulsion was also utilized. Different concentrations of hydrogen bond‐forming agents (citric acid (CA), ascorbic acid (AA), low methoxyl pectin (LMP)) with and without salts (sodium chloride (S) or calcium chloride (Ca)) were added to the aqueous phase before emulsification, which enhanced emulsifier binding to the water–oil interface. W/CO emulsion without any aqueous phase additive destabilized instantly, whereas W/MO emulsion stayed stable during the week‐long observation. The addition of hydrogen bond‐forming agents and salts significantly improved emulsion stability. LMP, with many hydrogen bond‐forming groups, was able to provide the highest emulsion stability after 7 days in both oils compared to AA, CA and their mixtures with S. Emulsions with both oils formed weak gels due to the formation of an extensive network of water droplet aggregates. Overall, the hydrogen bond‐forming agents interacted with GMO at the interface, thereby favoring their presence at the water droplet surface and significantly improving the stability of liquid W/CO emulsions. The knowledge developed in this research can be useful in utilizing GMO to stabilize liquid water‐in‐oil emulsions without using any fat crystal network.