bluuebunny/crossref_metadata_2025_split huggingface dataset:
Planar Spin Glass with Topologically Protected Mazes in the Liquid Crystal Targeting for Reconfigurable Micro Security Media
Authors: Park Geonhyeong , Choi Yun‐Seok , Kwon S. Joon , Yoon Dong Ki 
Published: May 2023

AbstractThe planar spin glass pattern is widely known for its inherent randomness, resulting from the geometrical frustration. As such, developing physical unclonable functions (PUFs)—which operate with device randomness—with planar spin glass patterns is a promising candidate for an advanced security systems in the upcoming digitalized society. Despite their inherent randomness, traditional magnetic spin glass patterns pose considerable obstacles in detection, making it challenging to achieve authentication in security systems. This necessitates the development of facilely observable mimetic patterns with similar randomness to overcome these challenges. Here, a straightforward approach is introduced using a topologically protected maze pattern in the chiral liquid crystals (LCs). This maze exhibits a comparable level of randomness to magnetic spin glass and can be reliably identified through the combination of optical microscopy with machine learning‐based object detection techniques. The “information” embedded in the maze can be reconstructed through thermal phase transitions of the LCs in tens of seconds. Furthermore, incorporating various elements can enhance the optical PUF, resulting in a multi‐factor security medium. It is expected that this security medium, based on microscopically controlled and macroscopically uncontrolled topologically protected structures, may be utilized as a next‐generation security system.
A Minimalistic, Synthetic Cell‐Inspired Metamaterial for Enabling Reversible Strain‐Stiffening
Authors: Taale Mohammadreza , Schmidt Målin , Taheri Fereydoon , Timmermann Michael , Selhuber‐Unkel Christine 
Published: May 2023

AbstractStrain‐stiffening, i.e. the nonlinear stiffening of a material in response to a strain, is an intrinsic feature of many biological systems, including skin, blood vessels, and single cells. To avoid a mismatch in mechanical properties, synthetic materials in contact with such biological systems should also be strain‐stiffening. Conventional strain‐stiffening materials are either highly dependent on the applied strain‐rate, or only available for a limited stiffness regime. Both aspects limit the applicability of these materials. In contrast, living cells employ a dynamic strain‐stiffening mechanism that is based on the cross‐linking of cytoskeletal fibers in response to external stress. This strain‐stiffening of the cytoskeleton is mimicked in a mechanical metamaterial by a minimalistic structure consisting of parallel slats connected to backbones. Herein, it is demonstrated experimentally that the structures can be adapted such that the strain required for stiffening, the final stiffness, as well as the degree of stiffening can be tuned, particularly by combining several strain‐stiffening elements. These properties make the structure promising for the development of devices that should resemble the mechanical properties of human soft tissues, e.g., skin‐integrated flexible electronics and blood vessel grafts.
Wireless Human Motion Detection with a Highly Sensitive Wearable Pressure Sensing Technology
Authors: Yan Jinli , Liu Jie , Qu Qing , Chen Xinjian , Liu Jian , Nie Baoqing 
Published: May 2023

AbstractWireless flexible sensing devices using inductive‐capacitive (LC) resonator‐enabled transmission technologies are attractive in the areas of human motion detection, health inspection, and implantable medical devices. However, challenges remain in LC‐based wireless sensing devices, including low device sensitivity/resolution and slow signal readout speed based on sweeping excitation frequencies. Herein, an LC resonator‐based wireless pressure sensing technology (LC‐WPS) is proposed for flexible contact pressure measurements in a real‐time manner. It includes a fully flexible passive LC pressure sensor and a signal‐reading circuit for wireless communication with the sensor and real‐time data processing. The passive sensor detects external pressure by the changes in resonant frequency. Importantly, by optimizing the design of the LC resonator in the sensor, the LC‐WPS converts the pressure‐dependent resonant frequency into circuit output voltage to a great extent, achieving a high sensitivity (1.23 × 10−2 kPa−1) and resolution (54 Pa) within a pressure range of 0–15 kPa. In addition, the LC‐WPS utilizes a single operating frequency (i.e., 13.56 MHz) instead of sweeping the operating frequencies to identify the sensor resonant frequency, featuring fast and real‐time data analysis and processing. Real‐time monitoring of human motions, such as laryngeal movement, neck bending and wrist rotation, is demonstrated, verifying the applicability of the LC‐WPS in the fields of wearable medical care and sports biomechanics.
Flash Reforming Pyrogenic Carbon to Graphene for Boosting Advanced Oxidation Reaction
Authors: Teng Tao , Wu Xuan , Lu Yilin , Yu Fengbo , Jia Chao , Sun Liming , Lin Litao , He Zhelin , Gao Jie , Zhang Shicheng , Zhu Xiangdong 
Published: May 2023

AbstractBiomass‐derived pyrogenic carbon is attractive for advanced oxidation processes (AOPs); however, its amorphous structure limits its activation efficiency. Graphene with highly conjugated π structure possesses superior electron transport ability and thus high usefulness. However, bygone strategies are scarcely effective for reforming pyrogenic carbon to graphene. Herein, for the first time, a state‐of‐the‐art flash Joule heating (FJH) technique is showcased for reforming pyrogenic carbon to 2–5‐layer graphene. FJH current‐induced ultrahigh temperature and stress field realize instantaneous (≈10 s) regeneration of pyrogenic carbon via synchronization actions of carbonization, graphitization, and exfoliation. Meanwhile, volatilization of doped N atoms accelerates graphitization but has less of an effect on graphene configuration. Accordingly, tuned oxygen groups at the graphene edge boost peroxydisulfate (PDS) adsorption for finer initiating activation. Subsequently, 2D graphene with excellent electron utilization rate strengthens hydroxyl radical and direct electron transfer pathways in activating PDS for sulfamethoxazole (SMX) degradation. Impressively, the SMX degradation efficiency by fabricated graphene raises ≈8.9‐fold as compared with pristine pyrogenic carbon. Additionally, fabricated graphene is more efficient in PDS activation than commercial metal catalysts. Undoubtedly, this study realizes effective transformation of pyrogenic carbon to graphene for highly efficient metal‐free carbocatalyst.
Atomic Layer Deposition of Ultrathin Al2O3 Layer on Carbon Nanotube Anodes for Potassium Ion Batteries with High Initial Coulombic Efficiency and Electrochemical Performance
Authors: Wang Yun , Wang Ruishuai , Zhu Hongzheng , Jiang Wenfeng , Guo Jia , Yang Dong , Liu Liang , Liu Jian 
Published: May 2023

AbstractPotassium ion batteries (PIBs) have emerged as one of the most attractive alternatives to lithium‐ion batteries (LIBs) to satisfy the burgeoning energy demand. The continuous growth of solid electrolyte interphase (SEI) and consumption of potassium resources cause poor initial Coulombic efficiency (ICE), unstable cycling performance, and even safety issues. Herein, the fabrication of an artificial SEI of an ultrathin Al2O3 layer by atomic layer deposition (ALD) on a multi‐walled carbon nanotubes (MWCNTs) anode for high‐performance PIBs is reported. The SEI resistance and the charge transfer resistance in the MWCNTs electrode are significantly reduced according to electrochemical impedance spectroscopy (EIS) and galvanostatic intermittent titration (GITT) measurements. The MWCNT electrode with a 2‐nm Al2O3 layer exhibits a much higher ICE of up to 85.9% than that of the uncoated one (20.8 %). It also maintains a remarkably high reversible capacity of 284 mA h g−1 at 100 mA g−1 after 100 cycles. In particular, the anode delivers superior rate capability of 558, 303, 251, 203, and 154 mAh g−1 at a current density of 50, 100, 200, 400, and 800 mA g−1, respectively. This work offers an effective approach for fabricating PIBs with high ICE and electrochemical performance.
Microsphere‐Aided Super‐Resolution Scanning Spectral and Photocurrent Microscopy for Optoelectronic Devices
Authors: Li Yingjian , Qiu Caiyu , Ji Huajian , Duan Siyu , Qin Feng , Li Zeya , Chen Peng , Huang Junwei , Yu Geliang , Yuan Hongtao 
Published: May 2023

AbstractDielectric microspheres naturally possess unique optical properties by which the light's focus and confinement can be manipulated on a microscale. Combining microspheres and optical or Raman microscopy, super‐resolution imaging beyond the diffraction limit and enhancement of Raman signals are demonstrated to provide abundant spectroscopic information on materials. However, microsphere‐aided super‐resolution scanning photocurrent imaging remains challenging to date. Here, based on the photonic nanojet mechanism, a super‐resolution photocurrent and spectral microscopy equipped with a scanning tip with silica dielectric microspheres are presented. With such microsphere‐aided microscopy, order of magnitude enhancements for single‐point Raman and photoluminescence signals can be achieved, and the spatial resolutions for photocurrent and spectral mapping surpass the best resolution of the original confocal system restricted by the diffraction limit. This versatile system enables correlative super‐resolution spectral and photocurrent imaging, serving as a reliable tool for comprehensively understanding and uncovering the optoelectronic properties of materials.
Achieving Highly Sensitive Near‐Infrared Organic Photodetectors using Asymmetric Non‐Fullerene Acceptor
Authors: Lee Un‐Hak , Park Byoungwook , Rhee Seunghyun , Ha Jong‐Woon , Whang Dong Ryeol , Eun Hyeong Ju , Kim Jong H. , Shim Yeongseok , Heo Junseok , Lee Changjin , Kim Bumjoon J. , Yoon Sung Cheol , Lee Jaewon , Ko Seo‐Jin 
Published: May 2023

AbstractOrganic photodetectors (OPDs) based on non‐fullerene acceptors (NFAs) have received considerable attention because of their potential for use in various commercial applications as near‐infrared (NIR) light sensing platforms. However, recent OPDs suffer from low NIR photoresponse and large dark/noise currents with narrow bandgap organic photoactive materials. Herein, a π‐bridge molecular engineering strategy replacing alkoxythienyl with benzothiadiazole for ultra‐narrow bandgap (ultra‐NBG) NFAs is designed to achieve simultaneously high photoresponse at NIR region and low noise current density, thereby leading to excellent NIR (≈1050 nm) detectivity (D*). The newly synthesized ultra‐NBG NFAs, namely COB and CBT with optical bandgaps below 1.14 eV, present high responsivity (R) with 0.369 and 0.080 A W−1, respectively, at a wavelength of 1050 nm. Especially, with effectively suppressed noise current density, COB‐based OPD exhibits a high NIR (≈1050 nm) D* value of 2.18 × 1011 cm Hz1/2 W−1 at −0.5 V bias. The obtained R and D* values for these NFAs exceed or are comparable to those of a commercial Si photodetector at 1050 nm. This work provides important insight into the π‐bridge molecular engineering strategy for ultra‐NBG NFAs, which facilitate achieving highly sensitive NIR OPDs with high NIR photoresponse and low dark/noise current.
Bridging Chloride Anions Enables Efficient and Stable InP Green Quantum‐Dot Light‐Emitting Diodes
Authors: Wu Qianqian , Wang Lin , Cao Fan , Wang Sheng , Li Lufa , Jia Guohua , Yang Xuyong 
Published: May 2023

AbstractZnMgO nanoparticles (NPs) are commonly used as the electron transport layer (ETL) in indium phosphide (InP) based quantum dots light‐emitting diodes (QLEDs). It has been experimentally found that the inherent oxygen vacancy defects in ZnMgO can be passivated by halogen additives. However, an in‐depth understanding of how the halogen additives in ZnMgO affect the quantum dots (QDs) films is currently missing. Here, the study reports on efficient and stable indium phosphide (InP) green QLEDs by effectively bridging QDs and ETL using chloride (Cl) ions. As bi‐functional anchoring additives, Cl ions not only passivate the oxygen vacancy defects of ZnMgO NPs for suppressing the exciton quenching at the QDs/ZnMgO interfaces, but also facilitate the hole transport of QDs due to part replacement of insulated oleic acid ligands on the surfaces of InP QDs with Cl anions for more balanced charge injection in the devices. Consequently, the optimized green InP QLED achieves a peak external quantum efficiency (EQE) of 13.8% and an operational lifetime of 5944 h, which, to the best of current knowledge, represents the best overall performance among the reported green InP QLEDs.
A Lewis Base Hydrogen Bond Donor (LB/HBD) Organocatalytic Approach to Dithiabridged Triarylamine Hetero[4]helicenes
Authors: Lupi Michela , Salmi Omar , Viglianisi Caterina , Menichetti Stefano 
Published: May 2023

AbstractN‐thiophthalimido‐ arylphenothiazines 2 and triarylamines 3 can be converted to dithiabridged triarylamine hetero[4]helicenes 1 using catalytic amounts of chalcogen substituted Lewis Bases and hexafluoro isopropanol as hydrogen bond donor. The procedure occurs under mild reaction conditions and gives good yields avoiding the use of excesses of Lewis Acids as previously reported. A preliminary study about the possibility to control the M and P absolute stereochemistry of helicenes 1 using enantiopure sulfur containing LBs from the natural chiral pool is also reported.magnified image
Divergent Hydroxysulfenylation and Chlorosulfonylation of Styrenes with Sulfinyl Chlorides Steered by Controlled Disproportionation of Sulfoxide‐Onium Ions
Authors: Liang Qingjin , Jia Tiezheng 
Published: May 2023

AbstractHerein, sulfinyl chlorides and styrenes have been exploited to afford either β‐hydroxy‐phenylethyl sulfides catalyzed by homogenous ZnCl2, or β‐chloro‐phenylethyl sulfones mediated by heterogeneous CuO nanoparticles (NPs). The key to achieve such a divergent synthetic strategy is the controlled disproportionation process of sulfoxide‐onium ions, induced by different metal complexes. Owing to the mild conditions, a wide range of functional groups and heterocycles could be tolerated by both of the protocols. The mechanistic studies reveal the key role of sulfoxide‐onium ions in both of the reaction pathways, and suggest that metal‐steered disproportionation defines the oxidation state of sulfur in products.
Photothermal Controlled‐Release Immunomodulatory Nanoplatform for Restoring Nerve Structure and Mechanical Nociception in Infectious Diabetic Ulcers
Authors: Jiang Le , Wu Xiangyi , Wang Yifan , Liu Chunlin , Wu Yixian , Wang Jingyun , Xu Nan , He Zhijun , Wang Shuqin , Zhang Hao , Wang Xiumei , Lu Xiong , Tan Qian , Sun Xiaodan 
Published: May 2023

AbstractInfectious diabetic ulcers (IDU) require anti‐infection, angiogenesis, and nerve regeneration therapy; however, the latter has received comparatively less research attention than the former two. In particular, there have been few reports on the recovery of mechanical nociception. In this study, a photothermal controlled‐release immunomodulatory hydrogel nanoplatform is tailored for the treatment of IDU. Due to a thermal‐sensitive interaction between polydopamine‐reduced graphene oxide (pGO) and the antibiotic mupirocin, excellent antibacterial efficacy is achieved through customized release kinetics. In addition, Trem2+ macrophages recruited by pGO regulate collagen remodeling and restore skin adnexal structures to alter the fate of scar formation, promote angiogenesis, accompanied by the regeneration of neural networks, which ensures the recovery of mechanical nociception and may prevent the recurrence of IDU at the source. In all, a full‐stage strategy from antibacterial, immune regulation, angiogenesis, and neurogenesis to the recovery of mechanical nociception, an indispensable neural function of skin, is introduced to IDU treatment, which opens up an effective and comprehensive therapy for refractory IDU.
X‐yne click polymerization
Authors: Fu Xinyao , Qin Anjun , Tang Ben Zhong 
Published: May 2023

AbstractAlkyne‐based click polymerizations have been nurtured into a powerful synthetic technique for the preparation of new polymers with advanced structures and versatile properties. Among them, the emerging thiol‐yne, hydroxyl‐yne, and amino‐yne click polymerizations have made remarkable progress from reactions to applications. These polymerizations avoid the usage of inherently dangerous monomers and are safer to operate than the classical azide‐alkyne click polymerization (AACP), making them more prospective for diverse applications. To greatly promote the new alkyne‐based click polymerizations beyond AACP, a new concept of “X‐yne click polymerization” is proposed to unify them, where “X” denotes the monomers that can react with alkynes under mild reaction conditions, including thiols, alcohols, amines, and other promising ones. In this review, we mainly present a brief account of the progress of X‐yne click polymerization and discuss in detail the challenges and opportunities in this field.
Supramolecularly Engineered Reporters with Superoxide Anion‐Triggered Chemiluminescence for Early Diagnosis and Efficient Amelioration of Acute Kidney Injury
Authors: Wu Menglin , Cui Mingyue , Jiang Airui , Sun Rong , Liu Mingzhu , Pang Xueke , Wang Houyu , Song Bin , He Yao 
Published: May 2023

AbstractWe report the “water‐in‐oil‐in‐water” preparation of kidney injury molecule‐1‐targeting supramolecular chemiluminescence (CL) reporters (PCCS), consisting of L‐serine‐modified poly(lactic‐co‐glycolic) acid (PLGA)‐encapsulated peroxyoxalate (CPPO), chlorin e6 (Ce6) and superoxide dismutase (SOD), for early diagnosis and amelioration of acute kidney injury (AKI). In this system, O2⋅−, a biomarker of AKI, triggers the oxidation of CPPO to 1,2‐dioxetanedione and subsequent CL emission via CL resonance energy transfer to Ce6. The L‐serine‐modified PLGA stabilizes CPPO and Ce6 via noncovalent interactions, promoting long‐lived CL (half‐lives: ≈1000 s). Transcriptomics analysis shows that PCCS reporters reduce the inflammatory response through glutathione metabolism and inhibition of the tumor necrosis factor signaling pathway. The reporters are able to non‐invasively detect AKI at least 12 h earlier than current assays, and their antioxidant properties allow simultaneous treatment of AKI.
Graphene nanosheet stabilized Pickering emulsion and its polystyrene nanocomposites
Authors: Li Yanke , Yu Weiwei , Li Yue , Ding Yanjun , Liu Huilin , Zhang Yichuan , Guo Mingming 
Published: May 2023

AbstractHigh thermal conductivity and electrical insulation materials are necessary for packaging materials of miniaturized electronic equipment at present. Graphene nanosheets (GNs) have great potential in polymer composites due to its excellent thermal conductivity. However, the ultra‐high conductivity of GNs will reduce the insulation of polymer composites, so that the GN composites have good thermal conductivity and electrical insulation has become the focus of research. Herein, the closed cell polystyrene nanocomposites are polymerized by using a Pickering emulsion route. Based on the exfoliating effect of pristine graphite at the oil–water interface and the amphiphilic properties of GNs during the preparation of emulsion, the resulting graphite can achieve good dispersion in the polystyrene resin. Furthermore, the high heat transfer rate of the resulting graphite makes the temperature of polystyrene resin increase by 60.2°C at room temperature within 1 min. Meanwhile, the high volume electrical resistivity (3.63 × 109 Ω·m) and breakdown strength (33.8 kV·mm−1) confirms the PNGL0.610%/PS composite keep excellent electrical insulation at 10.0 wt% filler loading.
Experimental studies on the preparation and properties of starch‐graft‐poly(hexyl acrylate) copolymers
Authors: Worzakowska Marta 
Published: May 2023

AbstractThe preparation and the properties such as the chemical stability, solution properties, moisture absorption, ability to gelation, glass transition temperatures, thermal stabilities and the decomposition course of starch‐graft‐poly(hexyl acrylate) copolymers have been studied. In general, it can be said that as the grafting percent increases the chemical resistance in alkaline, inert, acidic and buffer environments, and the solubility in non‐polar solvents of the copolymers increases. In turn, the solubility in polar solvents decreases compared to the solubility of starch. The Tg of starch‐g‐poly(hexyl acrylate) copolymers is in the range 102–133°C and is much higher than Tg of poly(hexyl acrylate) homopolymer. The thermal stability of all tested copolymers is higher than 274°C (inert conditions) and 230°C (oxidative conditions). In inert conditions, all tested copolymers decompose in two main stages related to pyrolysis combined with the emissions of the following volatiles: CO, CO2, H2O, aldehydes, alcohols, acids, ester, furanes, aliphatic and alkene fragments. In turn, the copolymers decompose in main three stages in oxidative conditions. The emission of CO, CO2, H2O, aldehydes, alcohols, acids, aliphatic, furanes and alcohols as a result of pyrolysis, oxidation, decarboxylation, dehydration, and combustion processes was confirmed.
Liquefied petroleum gas sensing activity of betel nut fiber‐polyaniline conducting composites synthesized by time‐controlled in situ polymerization
Authors: Chutia Sudipta , Phukan Kandarpa 
Published: May 2023

AbstractIn this paper, we report the liquefied petroleum gas (LPG) sensing behavior of polyaniline‐betel nut fiber (PANI/BNF) composite synthesized through a one‐step in situ oxidative polymerization method using HCl, H2SO4 and H3PO4 as doping acids. The deposition of emeraldine salt (ES) form of PANI on betel nut filament surface is explained by Fourier‐transform infrared spectroscopy (FT‐IR) and Ultraviolet–Visible (UV–vis) spectroscopy. Scanning electron microscopy (SEM) revealed that PANI particle size decreased and the thickness of the coated PANI layer increased with reaction time. Optical band gap of Polyaniline‐Betel nut fiber composites (PB) PB‐2, PB‐4 and PB‐6 were found be 3.68, 3.37, and 2.75 eV using the Tauc plot. X‐ray diffraction (XRD) analysis and thermogravimetric (TG) analysis showed that HCl‐doped PANI/BNF composites have high crystallinity and thermal stability as compared to the composites formed using H2SO4 and H3PO4. The electrical conductivity of the composites was determined by using a multimeter (Keithley Model 2000). The conducting filaments showed good resistive sensing activity toward LPG with minimum (100 ppm) 26% and maximum (1300 ppm) 44% of response sensitivity with decreasing response time and increasing recovery time. The plausible response mechanism of PANI/cellulose sensor toward LPG operating at room temperature is also discussed.