bluuebunny/crossref_metadata_2025_split huggingface dataset:
PENGEMBANGAN DIGITAL MARKETING PADA BIBIT TANAMAN BERBASIS WEB MOBILE DI DESA PEKALONGAN LAMPUNG TIMUR
Authors: Nizamiyati Nizamiyati , Adriani Weni Yunisa , Marliana Iin 
Published: January 2025

Abstract : Kecamatan Pekalongan, Kabupaten Lampung Timur merupakan sentra bibit buah-buahan dan tanaman hias di Lampung. Banyak masyarakat di Pekalongan berprofesi sebagai petani bibit buah-buahan, tak sedikit pula dari masyrarakat juga menanam tanaman hias, beragam jenis bibit buah-buahan tersedia di Pekalongan, pembelinya sendiri datang dari berbagai wilayah, diantaranya luar Lampung. Selama ini pemasaran bibit tersebut dilakukan secara konvensonal, sehingga hasil penjualannya belum maksimal. Dengan tujuan untuk meningkatkan akses pasar yang lebih luas, maka penulis melakukan pengembangan digital marketing untuk membantu memasarkan bibit-bibit hasil dari Pekalongan Lampung Timur. Tujuan dari kegiatan ini adalah untuk melakukan pengembangan digital marketing sabagai sarana pemasaran bibit dari hasil masyarakat Pekalongan Lampung Timur yang diharapkan dapat membantu meningkatkan akses pasar yang lebih luas melalui strategi multi chanel marketing.
Midline Compared With Peripheral Intravenous Catheters for Therapy of 4 Days or Longer in Pediatric Patients
Authors: Kleidon Tricia M. , Gibson Victoria , Cattanach Paula , Schults Jessica , Royle Ruth H. , Ware Robert S. , Marsh Nicole , Pitt Colleen , Dean Anna , Byrnes Joshua , Rickard Claire M. , Ullman Amanda J. 
Published: September 2023

ImportancePeripheral intravenous catheters (PIVCs) frequently fail during treatment causing therapy interruption, pain, recatheterization, and additional health care costs. Midline catheters (MCs) may improve functional dwell time and reduce failure compared with traditional PIVCs.ObjectiveTo compare device failure of MCs with PIVCsDesign, Setting, and ParticipantsThis was a pragmatic, randomized clinical superiority trial with an embedded internal pilot study conducted from July 2020 to May 2022. The study took place in a quaternary pediatric hospital in Brisbane, Queensland, Australia. Inclusion criteria were patients aged 1 to 18 years requiring peripherally compatible intravenous therapy for 4 days or longer.InterventionsPatients were randomly assigned 1:1 to receive a PIVC or MC, stratified by age (≤5 years, &amp;gt;5 years). One catheter was studied per patient.Main Outcomes and MeasuresThe primary outcome was all-cause device failure, defined as premature cessation of device function. Secondary outcomes included number of insertion attempts, insertion failure, pain (on insertion), procedural time, patient/parent satisfaction (with insertion), device dwell time, device complications during dwell time, additional vascular access devices required to complete treatment, clinician satisfaction (at removal), and health care costs.ResultsOf the 128 patients randomly assigned to study groups, 127 patients (median [IQR] age, 7 [2-13] years; 71 male [56%]) had a device inserted, with 65 (51.2%) in the PIVC group and 62 (48.8%) in the MC group. All patients were included in the intention-to-treat analysis. Device failure was lower in patients in the MC group (10 [16.1%]) compared with those in the PIVC group (30 [46.2%]; odds ratio [OR], 0.22; 95% CI, 0.10-0.52; P &amp;lt;.001). MCs were associated with fewer insertion attempts (mean difference [MD], −0.3; 95% CI, −0.5 to 0; P = .04), increased dwell time (MD, 66.9 hours; 95% CI, 36.2-97.5 hours; P &amp;lt;.001), and fewer patients required additional vascular access devices to complete treatment in the MC group (4 [6.5%]) and PIVC group (19 [29.2%]; OR, 0.17; 95% CI, 0.05-0.52; P = .002). Compared with PIVCs, use of MCs was associated with greater patient (9.0 vs 7.1 of 10; P = .002) and parent (9.1 vs 8.2 of 10; P = .02) satisfaction and lower health care costs (AUS −$151.67 [US −$101.13] per person; 95% credible interval, AUS −$171.45 to −$131.90 [US −$114.20 to −$87.95]).Conclusions and RelevanceFindings suggest that MC insertion for patients requiring peripherally compatible intravenous therapy for 4 days or longer should be prioritized to reduce the resource intensive, expensive, and burdensome sequelae of device failure.Trial RegistrationAustralia New Zealand Clinical Trials Registry, ACTRN12620000724976
Prevalence and Characteristics of Patients With Systemic Sclerosis Fulfilling the 2019 EULAR/American College of Rheumatology Classification Criteria for Systemic Lupus Erythematosus
Authors: Bass Ronald D. , Moore Duncan F. , Steen Virginia D. 
Published: September 2023

ObjectiveThere is limited literature describing the overlap of systemic sclerosis (SSc) and systemic lupus erythematosus (SLE), and the studies have employed a range of case definitions. Our study used the new EULAR/American College of Rheumatology (ACR) SLE classification criteria to define SSc‐SLE cases among our center's SSc cohort.MethodsThis is a single‐center, retrospective study of a previously described cohort of patients with SSc. Patient data were re‐abstracted to evaluate for fulfillment of the 2019 EULAR/ACR classification criteria for SLE. Demographic, laboratory, clinical features, and mortality were compared among patients with SSc‐SLE and patients with SSc alone.ResultsAmong the 402 patients with SSc that were analyzed, 40 (10%) fulfilled the 2019 EULAR/ACR SLE classification criteria. Neuropsychiatric and renal involvement were rare. An initial SLE diagnosis was purported in 43% of the patients with SSc‐SLE and 7% of patients with SSc alone (P < 0.001). Patients with SSc‐SLE were more likely to be female, African American, and with limited cutaneous SSc. Anti–U1‐RNP antibody positivity prevalence was 30% among patients with SSc‐SLE and 6.6% among patients with SSc alone (P < 0.001). Death during follow‐up occurred in 12 patients (30%) with SSc‐SLE and in 81 patients (22%) with SSc alone, but there was no difference in survival among the groups per log rank test (P = 0.404).ConclusionTen percent of patients with SSc fulfill the 2019 EULAR/ACR classification criteria for SLE. These patients comprise a distinct demographic, serologic, and clinical phenotype but have similar severe SSc‐specific end‐organ damage and mortality as patients with SSc alone. Patients with SLE with Raynaud phenomenon should be evaluated for SSc‐specific autoantibodies and scleroderma organ involvement.
Realizing High Efficiency and High Color Quality for All‐Fluorescence White Organic Light‐Emitting Diodes by Interlayer‐Sensitizing Configuration with Electron‐Capturing Agent
Authors: Liu Hao , Fu Yan , Tang Ben Zhong , Zhao Zujin 
Published: September 2023

AbstractAs a promising next‐generation lighting technology, all‐fluorescence white organic light‐emitting diodes (WOLEDs) have advanced rapidly but still face the formidable challenge of achieving high efficiencies and high color quality simultaneously. Herein, an interlayer sensitization strategy assisted by electron‐capturing agent with thermally activated delayed fluorescence (TADF) is proposed for the fabrication of high‐performance all‐fluorescence WOLEDs. The proof‐of‐concept three‐color devices with an interlayer‐sensitizing configuration are designed, and a low concentration of TADF electron‐capturing agent is codoped with a red conventional fluorescence (CF) emitter to reduce exciton loss. The major energy transfer from TADF sensitizing layer to red CF emitter combined with the supplementary energy transfer from TADF electron‐capturing agent to CF emitter can successfully increase exciton utilization. The synergistic effect endows the three‐color all‐fluorescence WOLEDs with high efficiencies, high color quality, and improved efficiency stability and operational stability, simultaneously. The resultant WOLEDs successfully attain remarkable external quantum efficiency of 31.0%, outstanding color rendering index of 93 and long operational lifetime. The record‐beating comprehensive performances of these WOLEDs strongly demonstrate the great potential of the proposed strategy for the exploration of high‐performance all‐fluorescence WOLEDs.
Chiral Van Der Waals Superlattices for Enhanced Spin‐Selective Transport and Spin‐Dependent Electrocatalytic Performance
Authors: Bian Zhiyun , Nakano Yuki , Miyata Keisuke , Oya Ichiro , Nobuoka Masaki , Tsutsui Yusuke , Seki Shu , Suda Masayuki 
Published: September 2023

AbstractThe emergence of the chiral‐induced spin‐selectivity (CISS) effect offers a new avenue for chiral organic molecules to autonomously manipulate spin configurations, thereby opening up possibilities in spintronics and spin‐dependent electrochemical applications. Despite extensive exploration of various chiral systems as spin filters, one often encounters challenges in achieving simultaneously high conductivity and high spin polarization (SP). In this study, a promising chiral van der Waals superlattice, specifically the chiral TiS2 crystal, is synthesized via electrochemical intercalation of chiral molecules into a metallic TiS2 single crystal. Multiple tunneling processes within the highly ordered chiral layered structure of chiral TiS2 superlattices result in an exceptionally high SP exceeding 90%. This remarkable observation of significantly high SP within the linear transport regime is unprecedented. Furthermore, the chiral TiS2 electrode exhibits enhanced catalytic activity for oxygen evolution reaction (OER) due to its remarkable spin‐selectivity for triplet oxygen evolution. The OER performance of chiral TiS2 superlattice crystals presented here exhibits superior characteristics to previously reported chiral MoS2 catalysts, with an approximately tenfold increase in current density. The combination of metallic conductivity and high SP sets the stage for the development of a new generation of CISS materials, enabling a wide range of electron spin‐based applications.
Regulating Lithium Transfer Pathway to Avoid Capacity Fading of Nano Si Through Sub‐Nano Scale Interfused SiOx/C Coating
Authors: Yu Ruohan , Pan Yexin , Jiang Yuqian , Zhou Liang , Zhao Dongyuan , Van Tendeloo Gustaaf , Wu Jinsong , Mai Liqiang 
Published: September 2023

AbstractSi nanoparticles (NPs) are considered as a promising high‐capacity anode material owing to their ability to prevent mechanical failure from drastic volume change during (de)lithiation. However, upon cycling, a quick capacity fading is still observed for Si NPs, and the underlying mechanism remains elusive. In this contribution, it is demonstrated that the quick capacity fading is mainly caused by the generation of dead (electrochemically inert) Si with blocked electron conductivity in a densely composited Si/SEI (solid electrolyte interface) hybrid. This is due to the combined influence of electrolyte‐related side reactions and the accompanied agglomeration of Si NPs. A compact, sub‐nano scale interfused SiOx/C composite coating onto the Si NPs is constructed, and a highly stabilized electrochemistry is achieved upon long cycling. The SiOx/C coating with electron/ion dual transport paths and robust mechanical flexibility enables a fast and stable lithium ion/electron dual diffusion pathway towards the encapsulated Si. With fast reaction kinetics, stable SEI, and an antiagglomeration feature, the obtained Si@SiOx/C composite demonstrates a stable high capacity. This work unravels new perspectives on the capacity fading of Si NPs and provides an effective encapsulating method to remedy the structure degradation and capacity fading of nano Si.
Photoluminescence Mechanism of Dual‐State Emission Materials Based on the Sulfone Bridged Distyrylbenzene Derivative
Authors: Li Yexi , Dai Jianan , Yang Song , Sui Ning , Wang Chenguang , Meng Xiangdong , Wang Kai , Zhang Hanzhuang , Liu Xiaomin , Lu Geyu , Wang Yinghui 
Published: September 2023

AbstractHerein, a novel molecular SO2‐Bri‐DSB based on the sulfone‐bridged distyrylbenzene derivative is synthesized, and its organic crystal is fabricated. It has a very high photoluminescence (PL) quantum efficiency in the solution and crystalline state, i.e., dual‐state emission (DSE), and the corresponding PL mechanism is clarified in detail using the transient absorption and transient PL test. The PL behaviors in the monomolecular state and organic crystal are compared. In addition, the optical anisotropy of the SO2‐Bri‐DSB crystal is thoroughly investigated using various polarization‐dependent spectroscopy techniques. The time evolution of anisotropy is composed of a step behavior caused by the anisotropy of the electronic transition and a slow enhancing process with a lifetime of 4.86 ns, which is governed by the change in emission lifetime due to the anisotropy. The space‐resolved evolution of the optical anisotropy is investigated using the polarization‐dependent light wave‐guiding test and exhibits that the emission anisotropy gradually decreases with length, and it has a longer effective propagation length than the polarization emission signal. The findings provide insight into the intrinsic optical anisotropy of single‐molecular crystals and indicate that these materials have enormous potential in the domains of polarization lighting and display.
Cross‐Correlated Quantum Thermometry Using Diamond Containing Dual‐Defect Centers
Authors: Gupta Madhav , Zhang Tongtong , Yeung Lambert , Zhang Jiahua , Tan Yayin , Yiu Yau Chuen , Zhang Shuxiang , Wang Qi , Wang Zhongqiang , Chu Zhiqin 
Published: September 2023

AbstractThe contactless temperature measurement at micro/nanoscale is vital to a broad range of fields in modern science and technology. The nitrogen‐vacancy (NV) center, a kind of diamond defect with unique spin‐dependent photoluminescence, is recognized as one of the most promising nanothermometers. However, this quantum thermometry technique is prone to a number of possible perturbations, which will unavoidably degrade its actual temperature sensitivity. Here, for the first time, a cross‐validated optical thermometry method is developed using a bulk diamond sample containing both NV centers and silicon‐vacancy (SiV) centers, achieving a sensitivity of 22 and 86 mK (√Hz)−1 respectively. Particularly, the latter has been intrinsically immune to those influencing perturbations for the NV‐based quantum thermometry, hence serving as a real‐time cross‐validation system. As a proof‐of‐concept demonstration, a trustworthy temperature measurement is shown under the influence of varying magnetic fields, which is a common artefact present in practical systems. This multi‐modality approach allows synchronized cross‐validation of the measured temperature, which is required for micro/nanoscale quantum thermometry in complicated environments such as a living cell.
Multilayer C and BN δ‐Graphyne Sheets: An Exploration of Electronic and Optical Characteristics
Authors: Majidi Roya 
Published: September 2023

AbstractThe structural, electronic, and optical characteristics of multilayer C δ‐graphyne and δ‐graphyne‐like BN sheets are discussed by first‐principles study. The calculations approved that the sheets are energetically favorable and thermally stable. The layers are held together by van der Waals forces. The mono‐ and tri‐layer C δ‐graphyne exhibit semimetallic behavior, while bi‐ and tetra‐layer C δ‐graphyne are semiconductors with negligible bandgap. All multilayer BN δ‐graphyne sheets are insulators with indirect bandgap. The bandgap increases with increasing number of layers. The optical behavior of the structures is anisotropic under electric fields polarized parallel and perpendicular to the sheets. The sheets exhibit high static dielectric constants, optical absorption, and optical conductivity. The electronic and optical characteristics of C and BN δ‐graphyne sheets promise their progress and application in the world of optoelectronics.
Full‐Control and Switching of Optical Fano Resonance by Continuum State Engineering
Authors: Ko Joo Hwan , Park Jin‐Hwi , Yoo Young Jin , Chang Sehui , Kang Jiwon , Wu Aiguo , Yang Fang , Kim Sejeong , Jeon Hae‐Gon , Song Young Min 
Published: September 2023

AbstractFano resonance, known for its unique asymmetric line shape, has gained significant attention in photonics, particularly in sensing applications. However, it remains difficult to achieve controllable Fano parameters with a simple geometric structure. Here, a novel approach of using a thin‐film optical Fano resonator with a porous layer to generate entire spectral shapes from quasi‐Lorentzian to Lorentzian to Fano is proposed and experimentally demonstrated. The glancing angle deposition technique is utilized to create a polarization‐dependent Fano resonator. By altering the linear polarization between s‐ and p‐polarization, a switchable Fano device between quasi‐Lorentz state and negative Fano state is demonstrated. This change in spectral shape is advantageous for detecting materials with a low‐refractive index. A bio‐particle sensing experiment is conducted that demonstrates an enhanced signal‐to‐noise ratio and prediction accuracy. Finally, the challenge of optimizing the film‐based Fano resonator due to intricate interplay among numerous parameters, including layer thicknesses, porosity, and materials selection, is addressed. The inverse design tool is developed based on a multilayer perceptron model that allows fast computation for all ranges of Fano parameters. The method provides improved accuracy of the mean validation factor (MVF = 0.07, q‐q') compared to the conventional exhaustive enumeration method (MVF = 0.37).
Second Harmonic Generation Studies of Interfacial Strain Engineering in BaZr0.2Ti0.8O3
Authors: Ren Yuhang , Maity Piyali , Ascienzo David , Kurt Onur , Cheng H. , Ouyang Jun 
Published: September 2023

AbstractFilm ferroelectrics demonstrate large breakdown strength, high energy density, and many unique phenomena not found in bulk materials. In this investigation, a rhombohedral BaZr0.2Ti0.8O3 (BZT) solid solution and various film‐substrate misfit strains are utilized to optimize the energy storage performance of ferroelectric thick films. Optical second harmonic generation is applied in both reflection and transmission geometries to reveal the renovation of entangled rhombohedral and tetragonal phases in the BZT films under compressive misfit strains. It is shown that the interfacial strain between the BZT film and substrate introduces the tetragonal domains. The competition between the tetragonal and rhombohedral phases creates the self‐assembled, anisotropically strained morphotropic structures to effectively accommodate the elastic and electrical stress fields through inside the thick BZT film. The BZT films demonstrate exceptional energy storage performance because of the adaptable nano‐domain structure within the bulk of the BZT films and may be engineered to optimize the superior performance of BZT films in energy storage.
Bright dual‐color electrochemiluminescence of a structurally determined Pt1Ag18 nanocluster
Authors: Yin Bing , Jiang Lirong , Wang Xiaojian , Liu Ying , Kuang Kaiyang , Jing Mengmeng , Fang Chunmin , Zhou Chuanjun , Chen Shuang , Zhu Manzhou 
Published: September 2023

AbstractMetal nanoclusters possess excellent electrochemical, optical, and catalytic properties, but correlating these properties remains challenging, which is the foundation to generate electrochemiluminescence (ECL). Herein, we report for the first time that a structurally determined Pt1Ag18 nanocluster generates intense ECL and simultaneously enhances the ECL of carbon dots (CDs) via an electrocatalytic effect. Pt1Ag18 nanocluster show aggregation‐induced emission enhancement and aggregation‐induced ECL enhancement under light and electrochemical stimulation, respectively. In the presence of tripropylamine (TPrA) as a coreactant, solid Pt1Ag18 shows unprecedented ECL efficiency, which is more than nine times higher than that of 1 mM Ru(bpy)32+ with the same TPrA concentration. Potential‐resolved ECL spectra reveal two ECL emission bands in the presence of TPrA. The ECL emission centered at 650 nm is assigned to the solid Pt1Ag18 nanocluster, consistent with the peak wavelength in self‐annihilation ECL and photoluminescence of the solid state. The ECL emission centered at 820 nm is assigned to the CDs on the glassy carbon electrode. The electrocatalytic effect of the nanoclusters enhanced the ECL of the CDs by a factor of more than 180 in comparison to that without nanoclusters. Based on the combined optical and electrochemical results, the ECL generation pathways and mechanisms of Pt1Ag18 and CDs are proposed. These findings are extremely promising for designing multifunctional nanocluster luminophores with strong emissions and developing ratiometric sensing devices.
Recent progress in polymerization‐induced self‐assembly: From the perspective of driving forces
Authors: Zhao Zizhuo , Lei Shujing , Zeng Min , Huo Meng 
Published: September 2023

AbstractPolymerization‐induced self‐assembly (PISA) enables the simultaneous growth and self‐assembly of block copolymers in one pot and therefore has developed into a high‐efficiency platform for the preparation of polymer assemblies with high concentration and excellent reproducibility. During the past decade, the driving force of PISA has extended from hydrophobic interactions to other supramolecular interactions, which has greatly innovated the design of PISA, enlarged the monomer/solvent toolkit, and endowed the polymer assemblies with intrinsic dynamicity and responsiveness. To unravel the important role of driving forces in the formation of polymeric assemblies, this review summarized the recent development of PISA from the perspective of driving forces. Motivated by this goal, here we give a brief overview of the basic principles of PISA and systematically discuss the various driving forces in the PISA system, including hydrophobic interactions, hydrogen bonding, electrostatic interactions, and π‐π interactions. Furthermore, PISA systems that are driven and regulated by crystallization or liquid crystalline ordering were also highlighted.
The normal relationship between fat and lean mass for mature (21–30 year old) physically fit men and women
Authors: Potter Adam W. , Tharion William J. , Nindl Lyndsey J. , McEttrick David M. , Looney David P. , Friedl Karl E. 
Published: September 2023

AbstractObjectiveDetermine if relative body fat (%BF) remains a biological norm in physically active, non‐obese American men and women and determine reference values for other components of body composition.MethodsParticipants (n = 174 men, 70 women) were physically fit U.S. Marine 2nd Lieutenants, in their third decade of physical maturity (age 21–30). Body composition was assessed by dual‐energy x‐ray absorptiometry (DXA) and bioelectrical impedance analysis (BIA); and body images were obtained by 3D body scans.ResultsFor men and women, respectively, %BF averaged 16.2 ± 4.1 (median 15.3), 24.3 ± 4.5 (median 23.8); fat‐free mass (FFM): 67.7 ± 7.2, 49.4 ± 5.3 kg; FFM index: 21.5 ± 1.8, 18.3 ± 1.6 kg/m2; and body mass index (BMI): 25.5 ± 1.9, 24.1 ± 2.2 kg/m2. Bone mineral content (BMC) was 5% of FFM; total body water (TBW) was 70%–72% of FFM. Physique remained similar between median and higher percentiles of %BF. Only small changes in key measures were noted across the six‐month training program.ConclusionsMean %BF of healthy active men and women in 2021 remains very similar to the 15% and 25% posited in 1980, suggesting that relative body fat has a normal fat‐lean relationship in physically mature humans. These data may bring new attention to sex‐appropriate %BF.
Hypervalent Iodine‐Mediated Alkyne Functionalization: Facile Access to Trifluoromethyl‐ and Pentafluoroethyl‐Substituted Thiazoles
Authors: Kwak Yoonna , Choi Ye Rin , Yu Jaeni , Choi Sungwook , Hong Ki Bum 
Published: September 2023

AbstractThe use of hypervalent iodine with Lewis acid provided alkyne trifluoromethylation and pentafluoroethylation to access trifluoro‐and pentafluoro‐substituted thiazoles. This simple and efficient method is compatible with a broad range of aryl‐ and alkyl‐substituted thiourea starting materials. Additionally, a gram‐scale reaction proves the practicality of this transformation.