bluuebunny/crossref_metadata_2025_split huggingface dataset:
Consequências do isolamento social para a Educação de Jovens e Adultos (EJA) em Itacoatiara – Amazonas
Authors: Da Silva Kelly Cristina Lopes , Da Silva Fabrício Valentim , Silva Flávia Fernanda Santos 
Published: September 2023

O presente trabalho visa destacar as consequências do isolamento social para educação de jovens e adultos (EJA) durante o decorrer da pandemia. Propôs-se a compreender como se desenvolveram as aulas remotas nas turmas da EJA do Ensino Fundamental da Secretaria Municipal de Itacoatiara (SEMED) no período pandêmico. O estudo tem abordagem qualitativa com uso de questionário. Os sujeitos da pesquisa foram constituídos por 4 professoras e um professor da EJA da rede municipal de educação de Itacoatiara/AM. A entrevista com os sujeitos da pesquisa procedeu-se de maneira presencial, por meio de um formulário. Para o tratamento dos dados, utilizou-se a análise qualitativa de conteúdo. Assim, identificou-se a necessidade de documentos orientadores para o desenvolvimento das aulas remotas e curso de formação continuada aos docentes para utilização de ferramentas tecnológicas como o classroom. Constatou-se a preocupação com a ausência de estrutura tecnológica para desenvolvimento das aulas e material didático adequado.
CONDROMALÁCIA PATELAR E DESEQUILÍBRIOS MUSCULARES: PAPEL DA REABILITAÇÃO MUSCULAR NA MELHORIA DOS SISTEMAS E PREVENÇÃO DE RECORRÊNCIA
Authors: Da Costa Leandro José , Lima Ronaldo Nunes 
Published: September 2023

Introdução: E uma terminação dada a lesão da cartilagem abrangendo uma ou mais partes da patela pode-se dizer que sua incidência na população é bem grande, majorando de acordo com a idade, sendo bastante comum em pessoas do gênero feminino e acima do peso. Durante o desenvolvimento da pesquisa notar-se-á que a prática de exercício físicos aumenta as condições de produção do líquido lubrificante, abrandando e melhorando os principais sintomas da síndrome. Objetivo: O objetivo do estudo é demonstrar a importância como é feito a prevenção das lesões e as orientações necessárias e adequadas para a população. Materiais e Métodos: No presente trabalho a metodologia utilizada foi a revisão de literatura, feita na relação, com livros indexados em bases de dados na Public/Publisher, Medline (Pubmed), Literatura Latino-americana e do Caribe em ciências da saúde (Lilacs), Scientific Eletronic Library online (Scielo), Google acadêmico e biblioteca virtual em saúde (BVS) publicados entre 2012 a 2023. Resultado: Na maioria dos artigos foi apresentado uma abordagem qualitativa, após a seleção dos artigos para a organização para que possa ter uma melhor compreensão dos resultados Conclusão: A condromalácia pode ser causada por diversas etiologias, dentre elas as principais que são fatores que são associados com os traumas diretas na patela, atividade física em excesso, obesidade e sobrepeso, variações anatômicas ósseas, instabilidade femoropatelar por luxações ou subluxações no joelho em valgo e exposição ocupacional.
Crescimento inicial e aspectos ecofisiológicos de leguminosas florestais inoculadas com fungos micorrízicos em áreas degradadas por mineração
Authors: Fernandes Milton Marques , Silva Ademilson Jesus , Oliveira Cassandra Mendonça , Oliveira Dêniver Dehuel Souza , Santos Cilene , Araújo Filho Renisson Neponuceno , Gomes Filho Raimundo Rodrigues , Fernandes Marcia Rodrigues de Moura 
Published: September 2023

O objetivo deste estudo foi avaliar o crescimento em altura, diâmetro, a taxa de sobrevivência e a ecofisiologia de Acacia mangium e Mimosa caesalpiniifolia inoculadas com fungos micorrízicos arbusculares (Rhizophagus clarus) e sem inoculação em área degradada de mineração no município de Itaporanga D’Ajuda, SE. O experimento foi implantado no espaçamento de 3x3 m em uma área degradada por mineração de areia e cascalhos no município de Itaporanga D’Ajuda, SE com as espécies Acacia mangium (Acacia) e Mimosa caesalpiniifolia (Sabiá). Foram definidos quatro tratamentos: Acacia mangium sem FMA; Mimosa caesalpiniifolia sem FMA; Acacia mangium com FMA; Mimosa caesalpiniifolia com FMA. As plantas de cada tratamento foram avaliadas quanto à altura da planta, diâmetro da base do caule, taxa de sobrevivência e parâmetros ecofisiológicos aos 12 meses após o plantio, utilizando 5 plantas selecionadas ao acaso por tratamento. Doze meses após o plantio conclui-se: a leguminosa florestal Mimosa caesalpiniifolia inoculada com fungos micorrízicos Rhizophagus clarus apresentou os melhores resultados em altura, taxa de sobrevivência e eficiência fotossintética. A Acacia mangium sem inoculação com fungos micorrízicos Rhizophagus clarus teve o maior diâmetro e a segunda maior altura. Porém a menor taxa de sobrevivência pode ter superestimado os resultados de diâmetro e altura.
Blasts from the past. A personal Web presence: 1993-1996.
Authors: Rzepa Henry 
Published: September 2023

Egon Willighagen recently gave a presentation at the RSC entitled “The Web – what is the issue” where he laments how little uptake of web technologies as a “*channel for communication of scientific knowledge and data” *there is in chemistry after twenty years or more. It caused me to ponder what we were doing with the web twenty years ago.
A wider look at chlorine trifluoride: crystal structures and data mining.
Authors: Rzepa Henry 
Published: September 2023

A while ago, I explored how the 3-coordinate halogen compound ClF
<sub>
3
</sub>
is conventionally analyzed using VSEPR (valence shell electron pair repulsion theory). Here I (belatedly) look at other such tri-coordinate halogen compounds using known structures gleaned from the crystal structure database (CSD). The search query specifies 7A as the central atom, defined with just three bonded (non-metallic) atoms.
Examples please of FAIR (data); good and bad.
Authors: Rzepa Henry 
Published: September 2023

The site fairsharing.org is a repository of information about FAIR (Findable, Accessible, Interoperable and Reusable) objects such as research data. A project to inject chemical components, rather sparse at the moment at the above site, is being promoted by workshops under the auspices of e.g. IUPAC and CODATA and the GO-FAIR initiative.
First, hexacoordinate carbon – now pentacoordinate nitrogen?
Authors: Rzepa Henry 
Published: September 2023

A few years back I followed a train of thought here which ended with hexacoordinate carbon, then a hypothesis rather than a demonstrated reality. That reality was recently confirmed
<em>
via
</em>
a crystal structure, DOI:10.5517/CCDC.CSD.CC1M71QM[cite]10.1002/anie.201608795[/cite]. Here is a similar proposal for penta-coordinate nitrogen. First, a search of the CSD (Cambridge structure database) for such nitrogen.
Elongating an N-B single bond is much easier than stretching a C-C single bond.
Authors: Rzepa Henry 
Published: September 2023

An N-B single bond is iso-electronic to a C-C single bond, as per below. So here is a simple question: what form does the distribution of the lengths of these two bonds take, as obtained from crystal structures? The Conquest search query is very simple (no disorder, no errors). When applied to the Cambridge structure database (CSD) the following two distributions are obtained.
VSEPR Theory: A closer look at bromine trifluoride, BrF3.
Authors: Rzepa Henry 
Published: September 2023

I analysed the bonding in chlorine trifluoride a few years back in terms of VSEPR theory. I noticed that several searches on this topic which led people to this post also included a query about the differences between it and the bromine analogue. For those who posed this question, here is an equivalent analysis.
Managing (open) NMR data: a working example using Mpublish.
Authors: Rzepa Henry 
Published: September 2023

In March, I posted from the ACS meeting in San Diego on the topic of Research data: Managing spectroscopy-NMR, and noted a talk by MestreLab Research on how a tool called
<strong>
Mpublish
</strong>
in the forthcoming release of their NMR analysis software
<strong>
Mestrenova
</strong>
could help. With that release now out, the opportunity arose to test the system.
Tautomeric polymorphism.
Authors: Rzepa Henry 
Published: September 2023

Conformational polymorphism occurs when a compound crystallises in two polymorphs differing only in the relative orientations of flexible groups (
<strong>
e.g.
</strong>
Ritonavir).[cite]10.1039/D1SC06074K[/cite] At the Beilstein conference, Ian Bruno mentioned another type; ** tautomeric polymorphism**, where a compound can crystallise in two forms differing in the position of acidic protons. Here I explore three such examples.
MOLinsight: A web portal for the processing of molecular structures by blind students.
Authors: Rzepa Henry 
Published: September 2023

Occasionally one comes across a web site that manages to combine being unusual, interesting and also useful. Thus www.molinsight.net is I think a unique chemistry resource for blind and visually impaired students. If you think perhaps that it might be a little too specialised to be useful for you, go visit it first.
Chemistry preprint servers (revisited).
Authors: Rzepa Henry 
Published: September 2023

This week the ACS announced its intention to establish a “
<em>
ChemRxiv preprint server to promote early research sharing
</em>
”. This was first tried quite a few years ago, following the example of especially the physicists. As I recollect the experiment lasted about a year, attracted few submissions and even fewer of high quality.
London: set to become a National Park City in 2019.
Authors: Rzepa Henry 
Published: September 2023

Last year, I showed photos of wildflower meadows in west London close to where we live, evolving as the seasons changed. Today we hear the announcement that London itself is set be declared the world’s first National Park City in 2019. What is a park city you may ask? It draws on the principles of National Parks such as the Peak District, the New Forest, or the South Downs in the UK, but in a city setting.
Twenty one years of chemistry-related Java apps: RIP Java?
Authors: Rzepa Henry 
Published: September 2023

In an earlier post, I lamented the modern difficulties in running old instances of Jmol, an example of an application program written in the Java programming language. When I wrote that, I had quite forgotten a treasure trove of links to old Java that I had collected in 1996-7 and then abandoned. Here I browse through a few of the things I found. The collection is at DOI: 10.14469/hpc/2657.
Is (hν)3 an allotrope of light?
Authors: Rzepa Henry 
Published: September 2023

A little while ago I pondered allotropic bromine, or Br(Br)
<sub>
3
</sub>
. But this is a far wackier report[cite]10.1126/science.aao7293[/cite] of
<em>
a molecule of light.
</em>
The preparation and detection of dimer and trimer bound photon states is pure physics; probably considered by the physicists themselves as NOT chemistry. It is certainly true, as a chemist, that I understood only a little of the article.
(another) WATOC 2017 report.
Authors: Rzepa Henry 
Published: September 2023

Another selection (based on my interests, I have to repeat) from WATOC 2017 in Munich. Odile Eisenstein gave a talk about predicted^ 13^C chemical shifts in transition metal (and often transient) complexes, with the focus on metallacyclobutanes. These calculations include full spin-orbit/relativistic corrections, essential when the carbon is attached to an even slightly relativistic element.
What’s in a name? Carbenes: a reality check.
Authors: Rzepa Henry 
Published: September 2023

To quote from Wikipedia:
<em>
in chemistry, a carbene is a molecule containing a neutral carbon atom with a valence of two and two unshared valence electrons
</em>
. The most ubiquitous type of carbene of recent times is the one shown below as
<strong>
1
</strong>
, often referred to as a resonance stabilised or
<em>
persistent carbene
</em>
. This type is of interest because of its ability to act as a ligand to an astonishingly wide variety of
Can a novel opioid-free protocol following total knee arthroplasty prevent chronic opioid addiction? A follow-up study of 386 patients.
Authors: Wickline Andrew , Corrado Kayleigh 
Published: September 2023

Background: Studies have shown that there is an approximately 8.2% risk of chronic addiction after total knee arthroplasty (TKA) using conventional methods to recover from surgery in patients who are opioid-naive (1). A previous study by the authors found that a novel multimodal protocol significantly reduced the use of postoperative TKA opioids in the first 90 days post-op (2). The present study sought to ascertain whether the protocol had persistent effects which led to a lower risk of chronic addiction than that which is currently published. Methods: All 386 patients from the previous study who underwent TKA were identified through a HIPPA-compliant portal and searched on the New York State Internet System for Tracking Over-Prescribing (NYS I-STOP) database. Patients who had received one or more opioid prescriptions in the 12 months preceding the I-STOP search were noted and then individually contacted to ascertain the reason for the prescription. Results: Overall, 88 patients received an opioid prescription within 12 months of searching I-STOP, 73 of which were opioid-naive. Of the opioid-naive patients, 10 were defined as chronic opioid users post-TKA, but only one patient named the TKA as the reason for using opioids. This study found that there was a 0.28% (1/356) chance for opioid-naive patients to become chronically addicted to opioids as a direct result of the TKA. The overall risk of becoming a chronic opioid user for any reason (including TKA) was 2.81% (10/356). The overall risk of an opioid-naive patient receiving at least one or more opioid prescriptions outside of the 90 day window after TKA for any reason was 20.5% (73/356). Conclusions: Following the previously published novel multimodal protocol led to a significant reduction in post-operative risk for converting to chronic opioid use in patients who were opioid-naive prior to surgery as directly related to the TKA. This study suggests that querying large databases for opioid use after TKA may not capture the actual reason for post-surgical opioid prescriptions and further study is warranted to determine the actual frequency with which TKA is responsible for chronic opioid use.
Pengaruh Kepemimpinan Transformational Terhadap Organizational Citizenship Behavior Karyawan Pada Perusahaan Tekstil di Jakarta Timur
Authors: Aziza Pretty Failasufa 
Published: September 2023

Penelitian ini menggunakan pendekatan kuantitatif. Data dikumpulkan melalui kuesioner dan wawancara mendalam. Responden dalam penelitian ini adalah karyawan swasta pada perusahaan tekstil di Jakarta. Penelitian ini menggunakan Transformational Leadership Behaviour Inventory (TLI) untuk mengukur kepemimpinan transformational dan OCB scale dengan 5 dimensi utama dari Podsakoff untuk mengukur OCB. Jumlah responden dalam penelitian ini adalah 221 dari beberapa jumlah karyawan pada perusahaan tekstil di Jakarta. Hasil dari penelitian ini menunjukkan bahwa kepemimpinan transformational berpengaruh signifikan terhadap organizational citizenship behavior. Namun kepemimpinan transformational secara parsial tidak berpengaruh signifikan terhadap organizational citizenship behavior. Hal ini disebabkan oleh: (1) terdapat faktor lain yang lebih mempengaruhi organizational citizenship behavior salah satunya adalah kepemimpinan transaksional karena kepemimpinan transaksional mempertimbangkan perilaku extra role maupun in role para bawahannya, hal tersebut menyebabkan bawahan akan menunjukkan kinerja OCB-nya, (2) perlu mempertimbangkan supaya kecerdasan emosional menjadi variabel mediasi antara kepemimpinan transformational dengan organizational citizenship behavior sehingga pengaruh kepemimpinan transformational terhadap OCB dapat dirasakan secara tidak langsung melalui kecerdasan emosional.
Le rôle des tribunaux ontariens dans la reconnaissance des traits socioreligieux amish
Authors: Legault-Laberge Raphaël Mathieu 
Published: September 2023

Les amish sont présents dans le sud ontarien depuis 1822. Ce groupe religieux minoritaire manifeste certains traits socioreligieux uniques qui font partie de leur normativité (Ordnung), tels que l’utilisation des chevaux pour leurs déplacements et leurs travaux agricoles et la communalisation intergénérationnelle des espaces de vie familiaux. Ces mêmes caractéristiques ont surgi comme éléments centraux de certaines décisions des tribunaux ontariens. Ces tribunaux ont-ils contribué à la reconnaissance des spécificités socioreligieuses et normatives des amish ? Si oui, à quel niveau et dans quelle mesure ? L’hypothèse avancée dans le cadre de cette étude postule que les tribunaux ont influencé positivement la reconnaissance des traits socioreligieux amish, et ce, à l’échelle locale. Les deux cas considérés afin d’étayer cette hypothèse (Mornington (Township) v. Kuepfer et Stoll v. Kawartha Lakes (City) Committee of Adjustment) concernent le droit municipal. Dans le premier cas, les amish ont obtenu le droit de garder des chevaux dans une municipalité où un règlement l’interdisait formellement. Dans le second cas, les amish ont obtenu le droit de construire une seconde résidence sur un terrain agricole où cela n’était pas permis. Dans les deux cas considérés, les tribunaux ontariens ont reconnu la liberté de religion des amish, jouant un rôle dans la reconnaissance de leurs traits socioreligieux.
Rencontrer la mer : l’expérience vécue d’une expédition en voilier sur le Saint-Laurent en contexte d’intervention sociale
Authors: Gendreau Robert Henri-Bastien , Genest-Dufault Sacha 
Published: September 2023

Bien qu’un nombre grandissant d’études soulignent les bienfaits de l’interaction avec la nature (Institut de cardiologie de Montréal, 2021), rares sont celles qui se penchent spécifiquement sur le rôle des environnements marins dans le cadre des pratiques centrées sur la nature et l’aventure. Or, ces espaces qu’il convient d’appeler les « environnements bleus » possèdent des caractéristiques qui leur sont propres et sont reconnus notamment pour leurs effets bénéfiques sur la santé physiologique et psychologique (White et al., 2020). Il existe à travers le monde différents programmes qui, par l’entremise d’un séjour en mer à bord d’un voilier, ont pour but de soutenir des personnes et des groupes vivant diverses difficultés (Schijf et al., 2017). Les pratiques d’intervention misant sur la navigation à voile offrent ainsi une singulière occasion d’immersion dans un environnement marin. Cet article présente des résultats de recherche et une réflexion quant à ce phénomène à ce jour peu étudié sous l’angle du travail social. L’article s’appuie sur les résultats préliminaires d’un mémoire de maitrise en travail social en cours de réalisation à l’Université du Québec à Rimouski qui vise, par une approche phénoménologique, à mieux comprendre l’expérience vécue par les personnes intervenantes et participantes lors d’une expédition en voilier sur le Saint-Laurent en contexte d’intervention sociale.
escuta como método e os pobres/oprimidos como sujeitos
Authors: Andrade Martins Alexandre 
Published: September 2023

Considerando desafios em saúde global, este texto busca compreender o impacto do global no local a partir de uma proposta de bioética global não universal, mas plural. As ações em saúde global são dominadas por uma perspectiva ocidentalizada de assistência à saúde em realidades locais que parte de um modelo de cima para baixo. Este artigo analisa essa perspectiva por meio de aspectos essenciais das iniciativas em saúde global – métodos, atores principais, financiamento e mentalidade – que levam a perceber a sua limitação aos fundamentar modos de operar em saúde global e, ao mesmo tempo, contraditoriamente contribuem para os mesmos problemas que afirma enfrentar ao responder necessidades imediatas em saúde de populações empobrecidas. Seguindo a identificação dessa limitação, o artigo argumenta por uma perspectiva que parta do local, das experiências sentidas na realidade concreta das pessoas, para, então, avançar para o global, que será um global plural e inclusivo em vista de construir colaboração. Assim, não há um global epistemológico e normativo da prática como é a perspectiva ocidental dominante, mas um global plural que é universal no proceder – do local para o global – mas plural no compreender e no enfrentar os desafios em saúde global, sem uma epistemologia dominante. Dessa forma, um ethos de colaboração é desenvolvido a partir da escuta e do aprendizado mútuo que ocorrem onde o desafio é experienciado. Por fim, o autor apresenta a escuta como primeiro movimento em saúde global fundamentado em uma bioética global plural e inclusiva, em um constante desenvolvimento epistemológico com impacto ético.
Atrium on the university campus
Authors: Baklyskaia Larisa Evgen'evna , Chukmareva Elizaveta Andreevna , Fisheva Natal'ya Olegovna 
Published: September 2023

The article discusses atrium spaces in the university environment. The subject of the study is the architectural and design organization of informal learning spaces (open atriums). The relevance of the research is determined by the importance of the practical implementation of the ideas and principles of using atrium spaces in the design of the learning environment, including when developing a detailed plan for the creation of an intercollegiate campus on the basis of the Pacific National University (PNU) in the city of Khabarovsk. Campus concepts involve a large number of open educational spaces and transformable classrooms. Particular attention is paid to the study of students' preferences in determining the key characteristics of spaces for informal learning that determine their use. The novelty of the research may be the identification of design features of informal learning spaces (open atriums) and consideration of techniques for shaping environmental objects of this type from general design principles to the development of subject content. The case study was conducted at the Department of Architectural Environment Design of Pacific National University. Mixed research methods were used, including observation, visual analysis, questionnaires and interviews, as well as testing of theoretical conclusions in diploma and course projects of students of PNU. The main results of the work are the basis for further research and can be used to develop future strategies for designing informal learning spaces.
Introduction
Authors: Panieri Giuliana , Stiller-Reeve Mathew , Bertolotto Bianc Giuliano 
Published: September 2023

An introduction to the 5 interdisciplinary lesson plans about the ocean and connecting with it via the senses that make up this booklet. The booklet was developed as part of the Advancing Knowledge about Methane in the Arctic (AKMA) Project, which is also briefly presented here.
生活从难闻
Authors: Stiller-Reeve Mathew , Rosnes Erling , Eiliertsen Mari , Ramalho Sofia , Poddevin Victor , Panieri Giuliana , Bertolotto Bianc Giuliano 
Published: September 2023

重点：
要了解硫化氢表明在深海底部有生命。
学习目标：
通过这个活动，我们创造了一种类似于有机物腐烂产生的硫化氢的讨厌的气味。我们以这种
气味为基 础，讨论/讲授来自深海海底的有趣的生命、动物和食物网。
键词：
深海，硫化氢，化能合成，线虫动物门，管虫，食物网。
冷泉之行
Authors: Mohadjer Solmaz , Aune Vibeke , Oddone Davide , Panieri Giuliana , Bertolotto Bianc Giuliano 
Published: September 2023

重点：
冷泉在哪里, 在冷泉会发生什么，以及科学家如何研究它们。
学习目标：本课结束后，学生应该能够：

通过观察和描述科学地图，将不同的数据集联系起来

区分二氧化碳和甲烷气体
澄清对温室气体的错误认识
解释什么是冷泉，为什么大多数气体/甲烷水合物发生在大陆边缘
描述科学家用来定位和研究甲烷/天然气水合物的一些方法

前提
在本课之前，学生应该熟悉了解地图、分子结构和结合，以及温室效应和气体。
键词：
北冰洋, 甲烷, 二氧化碳, 气体水合物, 冷泉, 温室气体