bluuebunny/crossref_metadata_2025_split huggingface dataset:
Convenient synthesis of Co-base metal-organic frameworks to effectively adsorb and remove Cr(VI) from aqueous
Authors: Xie Xiong , Li Xu , Dong Lichun 
Published: August 2023

Abstract
Herein, we reported the synthesis of a series of well-defined regular cobalt-based metal-organic frameworks (MOFs) from 3D to 2D phases through a facile synthesis method and confirm their effective adsorption behavior for Cr(VI) in aqueous. The equilibrium adsorptive capacities of ZIF-67, ZIF-L-Co-H, ZIF-L-Co-L, and ZIF-L-Co were 27.7, 28, 28.2, and 32 mg/g, respectively. ZIF-L-Co nanosheet morphology exhibited excellent adsorption performance for Cr(VI) in water for the first time, and sharp adsorption speed was also presented at the relevant initial concentrations. The Cr(VI) adsorption process demonstrated that the result well fitted the Langmuir isotherm model of 32.5 mg g-1 with uniform monolayer adsorption. The findings provided a broader understanding of Co-MOFs application as the Cr(VI) removal of wastewater.
Preparation of FeCoM Ternary Layered Double Hydroxides
Authors: Wu Yanling , Hou Mingqian , Ma Liping , Li Fangzhou , Chen Zhijie , Xu Kexin 
Published: August 2023

Abstract
LDHs have unique laminar structures, large interlaminar spacing ions, and highly adjustable components, which have been widely used in the field of electrochemistry. However, it is still a considerable challenge to regulate the microstructure and electronic structure of LDHs through reasonable design to obtain electrode materials with high activity. In this paper, three novel ternary-layered dihydroxide nano-compounds have been synthesized. Firstly, three LDHs materials (named as FeCoNi-LDHs, FeCoCu-LDHs, and FeCoZn-LDHs, respectively) were prepared by using the ZIF-67 framework material as a precursor by cation exchange strategy. Finally, the applications of these materials as electrode materials in oxygen evolution reactions (OER) and supercapacitors are explored based on current energy problems.
Development of the internal structure of an alkali-activated paste related to the length of curing
Authors: Kocáb D , Bílek V , Nápravník N , Kucharczyková B 
Published: August 2023

Abstract
This paper deals with the influence of the length of the moist curing period on the development of the internal structure of a paste based on alkali-activated slag. Waterglass was used as the activator. For the purpose of experiment, the test specimens subjected to the experiment were divided into five sets with different curing regimes combining moist and air curing. The reference set was kept in an environment with relative air humidity ≥ 95% during the entire maturing period. The development of the internal structure of the alkali-activated paste was mainly monitored using the resonance method. The obtained results show that the curing regime applied to the test specimens significantly influences the development of the internal structure of the material. The development of the observed dynamic properties (dynamic moduli and Poisson’s ratio) shows the formation of damage to the internal structure of the paste after its exposure to the air. Interestingly, a massive decrease in dynamic modulus of elasticity immediately after exposure to air drying was not prevented, even by intensive moist curing of the paste for 28 days.
The influence of steel fibre amount on the consistency, volume changes and compressive strength of concrete
Authors: Vymazal T , Misák P , Hrabová K , Kocáb D 
Published: August 2023

Abstract
The paper focuses on the consistency of fresh steel fibre reinforced concrete in relation to the amount of steel fibre used. Consistency was determined by the slump test and the flow table test. Furthermore, the paper deals with monitoring the compressive strength and volume changes during the maturing process of steel fibre reinforced concrete. Volume changes were monitored using a shrinkage drain. The results of the steel fibre reinforced concrete properties are compared with the values of the reference concrete without fibres and with each other. The result is an evaluation of how the amount of fibre affects the properties of fresh and hardened concrete. The dependence between consistency, compressive strength and shrinkage of steel fibre reinforced concrete is also established.
Abrupt drought termination in the British–Irish Isles driven by high atmospheric vapour transport
Authors: Parry Simon , Lavers David , Wilby Robert , Prudhomme Christel , Wood Paul , Murphy Conor , O’Connor Paul 
Published: August 2023

Abstract
During protracted dry spells, there is considerable interest from water managers, media and the public in when and how drought termination (DT) will occur. Robust answers to these questions require better understanding of the hydroclimatic drivers of DT than currently available. Integrated vapour transport (IVT) has been found to drive DT in Western North America, but evidence elsewhere is lacking. To evaluate this association for the British–Irish Isles, event coincidence analysis is applied to 354 catchments in the UK and Ireland over the period 1900–2010 using ERA-20C reanalysis IVT data and 7589 DT events extracted from reconstructed river flow series. Linkages are identified for 53% of all DT events across all catchments. Associations are particularly strong for catchments in western and southern regions and in autumn and winter. In Western Scotland, 80% of autumn DTs are preceded by high IVT, whilst in Southern England more than two thirds of winter DTs follow high IVT episodes. High IVT and DT are most strongly associated in less permeable, wetter upland catchments of Western Britain, reflecting their maritime setting and orographic enhancement of prevailing south-westerly high IVT episodes. Although high IVT remains an important drought-terminating mechanism further east, it less frequently results in DT. Furthermore, the highest rates of DT occur with increasing IVT intensity, and the vast majority of the most abrupt DTs only occur following top decile IVT and under strongly positive North Atlantic Oscillation (NAO) conditions. Since IVT and NAO forecasts may be more skilful than those for rainfall which underpin current forecasting systems, incorporating these findings into such systems has potential to underpin enhanced forecasting of DTs. This could help to mitigate impacts of abrupt recoveries from drought including water quality issues and managing compound drought–flood hazards concurrently.
Deep decarbonization and U.S. biofuels production: a coordinated analysis with a detailed structural model and an integrated multisectoral model
Authors: Vimmerstedt Laura , Atnoorkar Swaroop , Bergero Candelaria , Wise Marshall , Peterson Steve , Newes Emily , Inman Daniel 
Published: August 2023

Abstract
Scenarios for deep decarbonization involve biomass for biofuels, biopower, and bioproducts, and they often include negative emissions via carbon capture and storage or utilization. However, critical questions remain about the feasibility of rapid growth to high levels of biomass utilization, given biomass and land availability as well as historical growth rates of the biofuel industry. We address these questions through a unique coordinated analysis and comparison of carbon pricing effects on biomass utilization growth in the United States using a multisectoral integrated assessment model, the Global Change Analysis Model (GCAM), and a biomass-to-biofuels system dynamics model, the Bioenergy Scenario Model (BSM). We harmonized and varied key factors—such as carbon prices, vehicle electrification, and arable land availability—in the two models. We varied the rate of biorefinery construction, the fungibility of feedstock types across conversion processes, and policy incentives in BSM. The rate of growth in biomass deployment under a carbon price in both models is within the range of current literature. However, the reallocation of land to biomass feedstocks would need to overcome bottlenecks to achieve growth consistent with deep decarbonization scenarios. Investments as a result of near-term policy incentives can develop technology and expand capacity—reducing costs, enabling flexibility in feedstock use, and improving stability—but if biomass demand is high, these investments might not overcome land reallocation bottlenecks. Biomass utilization for deep decarbonization relies on extraordinary growth in biomass availability and industrial capacity. In this paper, we quantify and describe the potential challenges of this rapid change.
Changes in groundwater irrigation withdrawals due to climate change in Kansas
Authors: Obembe Oladipo S , Hendricks Nathan P , Krishna Jagadish S V 
Published: August 2023

Abstract
Warming temperatures increase the evapotranspiration demand of crops, leading to an increase in irrigation and exacerbating water scarcity. Previous research relies on models of irrigation water requirements to understand the potential impacts of climate change, but these models have significant uncertainty and ignore the risk-averse behavior of irrigators. Here we develop regression models to estimate how changes in vapor pressure deficit and precipitation affect groundwater withdrawals for corn, soybeans, and wheat using well-level data from the Kansas portion of the High Plains Aquifer. Withdrawals are expected to increase for all three crops, with the largest increase for soybeans. Even after accounting for the CO2 improvements in transpiration efficiency, we find that total withdrawals are expected to increase by 5.9% (7.6%) by mid-century under RCP 4.5 (8.5). The increase in withdrawals is expected to accelerate the decline in aquifer water levels and is therefore important to consider when projecting future aquifer conditions.
Third quantization for bosons: symplectic diagonalization, non-Hermitian Hamiltonian, and symmetries
Authors: Kim Steven , Hassler Fabian 
Published: August 2023

Abstract
Open quantum systems that interact with a Markovian environment can be described by a Lindblad master equation. The generator of time-translation is given by a Liouvillian superoperator

acting on the density matrix of the system. As the Fock space for a single bosonic mode is already infinite-dimensional, the diagonalization of the Liouvillian has to be done on the creation- and annihilation-superoperators, a process called ‘third quantization’. We propose a method to solve the Liouvillian for quadratic systems using a single symplectic transformation. We show that the non-Hermitian effective Hamiltonian of the system, next to incorporating the dynamics of the system, is a tool to analyze its symmetries. As an example, we use the effective Hamiltonian to formulate a

-‘symmetry’ of an open system. We describe how the inclusion of source terms allows us to obtain the cumulant generating function for observables such as the photon current.
In-situ SEM and EBSD investigation of the deformation behavior of extruded Mg-6Al-1Zn-1.1Sc alloy
Authors: Zhang Lei , Zhang Honggang , Wang Jinhui , Chen Lijia , Yuan Shuai , Jin Peipeng 
Published: August 2023

Abstract
The present study subjects the extruded Mg-6Al-1Zn-1.1Sc (wt%) alloy to reveal the deformation during in-situ tensile testing at room temperature by scanning electron microscopy (SEM) and electron backscatter diffraction (EBSD). The results demonstrate that the parallel slip traces are increasingly observed on the surfaces of grains with increasing strains owing to the movement of dislocations inside the grains toward the sample surface, while microcracks are frequently observed at grain boundaries. The slip trace analysis indicate that many basal slips are activated during the deformation. The twinning behaviors of the extruded alloy during tensile testing are dominated by extension twinning. The orientation of grains is demonstrated to have a profound effect on their deformation, where grains with orientations deviating greatest from 〈0001〉//TD exhibit the highest dislocation density after deformation. This can be attributed to the fact that these oriented grains are prone to activate basal slip due to the large Schmid factor (SF). Similarly, the deformation of grains is also found to be highly dependent on their size, where the dislocation density of coarser grains increases more significantly than that of finer grains during deformation because coarser grains have greater space available for accommodating dislocations than finer grains.
Configurable calorimeter simulation for AI applications
Authors: Charkin-Gorbulin Anton , Cranmer Kyle , Di Bello Francesco Armando , Dreyer Etienne , Ganguly Sanmay , Gross Eilam , Heinrich Lukas , Kado Marumi , Kakati Nilotpal , Rieck Patrick , Santi Lorenzo , Tusoni Matteo 
Published: August 2023

Abstract
A configurable calorimeter simulation for AI (CoCoA) applications is presented, based on the Geant4 toolkit and interfaced with the Pythia event generator. This open-source project is aimed to support the development of machine learning algorithms in high energy physics that rely on realistic particle shower descriptions, such as reconstruction, fast simulation, and low-level analysis. Specifications such as the granularity and material of its nearly hermetic geometry are user-configurable. The tool is supplemented with simple event processing including topological clustering, jet algorithms, and a nearest-neighbors graph construction. Formatting is also provided to visualise events using the Phoenix event display software.
Alpaca single B cell interrogation and heavy-chain-only antibody discovery on an optofluidic platform
Authors: Shapiro Mariya B , Boucher Jacqueline , Brousseau Anna , Dehkharghani Amin , Gabriel Justin , Kamat Vishal , Patil Ketan , Gao Feng , Walker Jennifer , Kelly Ryan , Souders Colby A 
Published: August 2023

Abstract
In vivo VHH discovery approaches have been limited by the lack of methodologies for camelid B cell interrogation. Here, we report a novel application of the Beacon® optofluidic platform to the discovery of heavy-chain-only antibodies by screening alpaca B cells. Methods for alpaca B cell enrichment, culture, IgG2/3 detection, and sequencing were developed and used to discover target-specific VHH from an alpaca immunized with prostate-specific membrane antigen (PSMA) or a second target. PSMA-specific hits were expressed as VHH-Fc and characterized using label-free techniques. Anti-PSMA IgG2/3 titer plateaued on day 153, when on-Beacon IgG2/3 secretion and target binding rates peaked. Of 13 recombinantly expressed VHH-Fc, all but one bound with nanomolar affinity, and five were successfully humanized. Repertoire sequencing uncovered additional variants within the clonal lineages of the validated hits. The establishment of this workflow extends the powerful Beacon technology to enable rapid VHH discovery directly from natural camelid immune repertoires.
Application of the International Consensus Classification and World Health Organization 5th edition classification to a series of myeloid neoplasms
Authors: Chopra Saurav , Bailey Nathanael G 
Published: August 2023

Abstract

Objectives
Two new classifications of myeloid neoplasms have recently been published: the International Consensus Classification (ICC) and the 5th edition of the World Health Organization classification (WHO5). We sought to examine the real-world impact of dueling classifications on patient diagnoses.

Methods
Our institutional pathology database was searched, and 237 specimens with a diagnosis of myeloid neoplasia were randomly selected. For each case, a classification based on the WHO5 and the ICC was assigned. The WHO5 and ICC diagnoses were compared to determine their degree of concordance.

Results
After applying the WHO5 and ICC diagnostic criteria, 134 (56.5%) cases were classified as concordant, 63 (26.6%) cases had terminological differences, 37 (15.6%) cases had minor diagnostic discrepancies, and 3 (1.3%) cases had major diagnostic discrepancies. Cases with minor diagnostic discrepancies included 25 cases of myelodysplastic syndrome (MDS), 10 cases of acute myeloid leukemia (AML), and 2 cases of myeloid precursor lesions. Cases with major diagnostic discrepancies included 2 cases that were diagnosed as MDS, not otherwise specified (NOS), according to the ICC but classified as AML with NPM1 alteration and AML with RBM15::MRTFA according to the WHO5 and 1 case that was characterized as chronic myelomonocytic leukemia according to the ICC and as AML with NPM1 alteration according to the WHO5.

Conclusions
This study confirms that a majority of cases are classified similarly using the 2 systems. Given the overall similarity of the systems, future harmonization of the classifications should be pursued to avoid confusion and multiple diagnoses.
The Association of Personal Neglect with Motor, Activities of Daily Living, and Participation Outcomes after Stroke: A Systematic Review
Authors: Embrechts Elissa , Loureiro-Chaves Renata , Nijboer Tanja C W , Lafosse Christophe , Truijen Steven , Saeys Wim 
Published: August 2023

Abstract
Despite its potential clinical impact, the association of personal neglect (PN) with motor, activities of daily living (ADL), and participation outcomes after stroke is not well-understood. This first-ever systematic review on the topic therefore evaluates this association, taking into account suggested subtypes of PN, including body representation neglect, somatosensory neglect, motor neglect, and premotor neglect. A systematic literature search was conducted on February 17, 2023 in PubMed, Web of Science, Scopus, PubPsych, and PsycArticles databases. The study adheres to the guidelines of Preferred Reporting Items for Systematic Reviews and Meta-Analyses, and its protocol was registered on PROSPERO (CRD42020187460). Eleven observational studies were included, gathering 1,400 individuals after stroke (429 showed PN). Results show that individuals with body representation neglect after stroke have significantly decreased movement control and motor strength, lower functional mobility, and ADL independency compared with those without body representation neglect after stroke. Individuals with motor neglect after stroke showed worse motor function and spasticity than to those without motor neglect after stroke. Nonspecified PN (i.e., PN evaluated with an outcome measure that does not allow subcategorization) was related to worse lateropulsion with pushing, longer length of stay and greater odds of being discharged to somewhere other than home. No study evaluated somatosensory and premotor neglect. This review highlights the limited research in this area and emphasizes the need for a more comprehensive PN assessment. However, currently available assessment tools show limited ability to accurately diagnose PN subtypes and future research should prioritize the development of comprehensive diagnostic test batteries.
Using Therapeutic Photography in Social Work—An Interpretive Phenomenological Analysis of the Dynamics within a Group Programme
Authors: Gibson Neil 
Published: August 2023

Abstract
Therapeutic photography is the practice of using photography in order to explore issues and reach defined outcomes with people who use services. It has been deemed to be an accessible tool which can have a positive impact on self-esteem, self-efficacy and empowerment. Using interpretive phenomenological analysis, this research analyses observations and focus group feedback from a group of participants receiving support from a third-sector organisation for mental health issues. Specifically, the data were analysed to look at how a therapeutic photography programme contributed to group dynamics, exploration and outcomes. Three inter-related super-ordinate themes were identified, these being (1) exposing the self; (2) searching; and (3) developing the self. These themes centred around the identity of the participants as they explored their photographs and associated narratives. The results suggest that the medium of photography contributes to enhanced self-disclosure and social bonding through the familiarity of engaging with photographs. The photographs also enable participants to feel in control of the information shared, facilitating the level of exploration and personal learning around identity and roles and could be beneficial in social work with groups where these outcomes are sought.
Intersectional hybrids of Carex remota with C. otrubae and C. vulpina (Cyperaceae) in Europe
Authors: Koopman Jacob , Więcław Helena , Cembrowska-Lech Danuta 
Published: August 2023

Abstract
Carex vulpina and C. otrubae are closely related and morphologically similar species that hybridize with C. remota. The spontaneous appearance of hybrids can cause difficulties in the taxonomic treatment of this group. Morphological separation of the examined species and hybrids had been tested using discriminant function analysis (DFA). We have also analysed the effect of DNA barcoding on hybrid identification from the perspective of machine learning approach (MLA). Hybrids were investigated in terms of three barcodes sequence (ITS, matK, rbcL) by means of the BLOG and WEKA (MLA). Our results provide the first insights into the morphological and genetic relationships between the studied species and their hybrids. Morphological analysis showed traits useful in the identification of hybrids, i.e. dark brown usually fibrous basal sheaths and a dorsally split beak in Carex remota × C. vulpina (inherited from C. vulpina), distinctly separated spikes, and a long bract in C. otrubae × C. remota (inherited from C. remota). Phylogenetic analysis also indicated a close relationship of Carex remota × C. vulpina with C. vulpina and C. otrubae × C. remota with C. remota. Moreover, we have presented here nomenclatural notes on the hybrids and typified the names Carex × crepinii [C. otrubae × C. remota] and Carex × kernii [Carex remota × C. vulpina].
On Their Sovereign’s Secret Service: Special Envoys Detained while in Transit
Authors: Martha Rutsel Silvestre J , De Vriese Kit 
Published: August 2023

Abstract
The case of Mr. Saab, a Venezuelan ad hoc diplomat, raises numerous issues beyond codified international law. The issues discussed in this article are a vivid reminder of the importance of customary international law, and that its principles should not be held to have been tacitly dispensed with by any treaty in the absence of any words making clear an intention to do so. Indeed, whilst important portions of the law of diplomatic relations, including ad hoc diplomacy through special missions, are codified in the Vienna Convention on Diplomatic Relations (VCDR) and the Convention on Special Missions (Special Missions Convention), important aspects of ad hoc diplomacy remains governed by customary international law—as confirmed by the preambles of these treaties. The VCDR and the Special Missions Convention, whether collectively or separately, do not cover all issues relating to diplomacy. In this article, an attempt is made to how these issues should have been addressed in Mr. Saab’s case if the executive and judicial branches of the Government of Cabo Verde had kept this in mind.