bluuebunny/crossref_metadata_2025_split huggingface dataset:
High‐Voltage Supercapacitive Swing Adsorption of Carbon Dioxide
Authors: Bilal Muhammad , Li Jiajie , Guo Hao , Landskron Kai 
Published: March 2023

AbstractSupercapacitive swing adsorption (SSA) with garlic roots‐derived activated carbon achieves a record adsorption capacity of 312 mmol kg−1 at a low energy consumption of 72 kJ mol−1 and high mass loadings (>30 mg cm−2) at 1.0 V for 85%N2/15%CO2 mixtures. The activated carbons are inexpensively prepared in a one‐step process using potassium carbonate, and air as activators. The adsorption capacity further increases with increasing voltage. At a voltage of 1.4 V, a sorption capacity of 524 mmol kg−1 at an energy consumption of 130 kJ mol−1 can be achieved. The volumetric sorption capacity is also enhanced and reaches values of 85.7 mol m−3 at 1.0 V, and 126 mol m−3 at 1.4 V. Cycle stability for at least 130 h is demonstrated.
Probing the Local Electronic Structure in Metal Halide Perovskites through Cobalt Substitution
Authors: Haghighirad Amir A. , Klug Matthew T. , Duffy Liam , Liu Junjie , Ardavan Arzhang , van der Laan Gerrit , Hesjedal Thorsten , Snaith Henry J. 
Published: March 2023

AbstractOwing to the unique chemical and electronic properties arising from 3d‐electrons, substitution with transition metal ions is one of the key routes for engineering new functionalities into materials. While this approach has been used extensively in complex metal oxide perovskites, metal halide perovskites have largely resisted facile isovalent substitution. In this work, it is demonstrated that the substitution of Co2+ into the lattice of methylammonium lead triiodide imparts magnetic behavior to the material while maintaining photovoltaic performance at low concentrations. In addition to comprehensively characterizing its magnetic properties, the Co2+ ions themselves are utilized as probes to sense the local electronic environment of Pb in the perovskite, thereby revealing the nature of their incorporation into the material. A comprehensive understanding of the effect of transition metal incorporation is provided, thereby opening the substitution gateway for developing novel functional perovskite materials and devices for future technologies.
Metal‐Organic Frameworks Nanocarriers for Functional Nucleic Acid Delivery in Biomedical Applications
Authors: He Li , Shang Mengdi , Chen Zhongkai , Yang Zhaoqi 
Published: March 2023

AbstractMetal−organic frameworks (MOFs), a distinctive funtionalmaterials which is constructed by various metal ions and organic molecules, have gradually attracted researchers′ attention from they were founded. In the last decade, MOFs emerge as a biomedical material with potential applications due to their unique properties. However, the MOFs performed as nanocarriers for functional nucleic acid delivery in biomedical applications rarely summarized. In this review, we introduce recent developments of MOFs for nucleic acid delivery in various biologically relevant applications, with special emphasis on cancer therapy (including siRNA, ASO, DNAzyme, miRNA and CpG oligodeoxynucleotides), bioimaging, biosensors and separation of biomolecules. We expect the accomplishment of this review could benefit certain researchers in biomedical field to develop novel sophisticated nanocarriers for functional nucleic acid delivery based on the promising material of MOFs.
Morbidity of insured Swedish cats between 2011 and 2016: Comparing disease risk in domestic crosses and purebreds
Authors: Hadar Barr N. , Bonnett Brenda N. , Poljak Zvonimir , Bernardo Theresa M. 
Published: March 2023

AbstractBackgroundSources of population‐based cat health information are scarce. The objective of this study was to determine disease frequency in cats using pet insurance data to inform health promotion efforts.MethodsA descriptive analysis of cats insured with Agria Pet Insurance in Sweden (2011–2016) was performed. Incidence rates of broad disease categories were calculated based on veterinary care events and an exact denominator consisting of cat‐years‐at‐risk. Rate ratios were calculated, comparing domestic crosses to all purebreds and specific purebreds to all other purebreds combined.ResultsThe study included over 1.6 million cat‐years‐at‐risk (78.5% were domestic crosses), 18 breeds and 24 disease categories. The most common disease categories causing morbidity in purebreds were digestive, whole body, injury, urinary lower, skin and female reproduction. Purebreds had the highest relative risk (compared to domestics crosses) in the female reproduction, heart, operation complication, respiratory lower and immunological disease categories.LimitationsThere are typical limitations of secondary data, but they do not negate the overall value of such a large dataset.ConclusionThis study demonstrates how pet insurance data can be used to find breed‐specific differences in the incidence of various disease categories in cats. This may be of importance for breeders, cat owners, veterinarians and researchers.
A form of hepatogenous copper poisoning in fattening cattle associated with the ingestion of mouldy straw
Authors: Otter Arthur , Schock Alexandra , Payne Jo 
Published: March 2023

AbstractTwo bulls from a group of 85 fattening bulls and heifers were examined postmortem. Both had generalised jaundice, swollen pale brown livers, dark brown kidneys and dark brown urine in the bladders. Biochemical testing of the livers and kidneys was indicative of copper poisoning in the two animals. Histopathology identified necrotising hepatopathy, consistent with an acute haemolytic crisis, superimposed on liver lesions of longer duration, which were suggestive of another toxic aetiology. Analysis of the animals’ concentrate diets did not indicate excess amounts of copper, but they had access to poor quality straw, which was visibly mouldy; the straw was removed and no further clinical disease was observed. This case report is an example of copper poisoning occurring in animals that were not fed excess copper, but had underlying hepatic damage, which reduced their copper tolerance, and resembles hepatogenous copper toxicity associated with the ingestion of hepatotoxic plants.
Vorbeugender Rettungsdienst – präventive Ansätze und Förderung von Gesundheitskompetenz an den Schnittstellen zur Notfallrettung
Authors: Breuer Florian , Beckers Stefan K. , Dahmen Janosch , Gnirke Andre , Pommerenke Christopher , Poloczek Stefan 
Published: March 2023

ZusammenfassungIn den Rettungsdienstgesetzen der Länder beschränken sich die Ausführungen bislang im Wesentlichen auf die Durchführung von Maßnahmen zum Erhalt der Gesundheit von Notfallpatientinnen und Notfallpatienten sowie auf die Beförderung in ein geeignetes Krankenhaus. Der vorbeugende Brandschutz hingegen ist in den Feuerwehrgesetzen bzw. durch Rechtsverordnungen geregelt. Zunehmende Einsatzzahlen im Rettungsdienst und fehlende Einrichtungen der alternativen Versorgung begründen die Notwendigkeit eines vorbeugenden Rettungsdienstes. Hierunter werden alle Maßnahmen verstanden, die vor Eintritt eines Ereignisses stattfinden, um der Entstehung von Notfällen vorzubeugen. Im Ergebnis soll das Risiko eines Notfallereignisses, welches zum Notruf 112 führt, verringert werden oder das Auftreten verzögert werden. Der vorbeugende Rettungsdienst soll auch dazu beitragen, das Outcome der medizinischen Versorgung von Patientinnen und Patienten zu verbessern. Weiterhin soll es ermöglicht werden, Hilfesuchende frühzeitig einer geeigneten Versorgungsform zuzuführen.
Genetic mapping of the powdery mildew resistance gene Pm7 on oat chromosome 5D
Authors: Brodführer Sophie , Mohler Volker , Stadlmeier Melanie , Okoń Sylwia , Beuch Steffen , Mascher Martin , Tinker Nicholas A. , Bekele Wubishet A. , Hackauf Bernd , Herrmann Matthias Heinrich 
Published: March 2023

AbstractKey messageThree independent experiments with different genetic backgrounds mapped the resistance genePm7in the oat genome to the distal part of the long arm of chromosome 5D.AbstractResistance of oat toBlumeria graminisDC. f. sp.avenaeis an important breeding goal in Central and Western Europe. In this study, the position of the effective and widely used resistance genePm7in the oat genome was determined based on three independent experiments with different genetic backgrounds: genome-wide association mapping in a diverse set of inbred oat lines and binary phenotype mapping in two bi-parental populations. Powdery mildew resistance was assessed in the field as well as by detached leaf tests in the laboratory. Genotyping-by-sequencing was conducted to establish comprehensive genetic fingerprints for subsequent genetic mapping experiments. All three mapping approaches located the gene to the distal part of the long arm of chromosome 5D in the hexaploid oat genome sequences of OT3098 and ‘Sang.’ Markers from this region were homologous to a region of chromosome 2Ce of the C-genome species,Avena eriantha, the donor ofPm7, which appears to be the ancestral source of a translocated region on the hexaploid chromosome 5D.
An international wheat diversity panel reveals novel sources of genetic resistance to tan spot in Australia
Authors: Taylor Julian , Jorgensen Dorthe , Moffat Caroline S. , Chalmers Ken J. , Fox Rebecca , Hollaway Grant J. , Cook Melissa J. , Neate Stephen M. , See Pao Theen , Shankar Manisha 
Published: March 2023

AbstractKey messageNovel sources of genetic resistance to tan spot in Australia have been discovered using one-step GWAS and genomic prediction models that accounts for additive and non-additive genetic variation.AbstractTan spot is a foliar disease in wheat caused by the fungal pathogenPyrenophora tritici-repentis(Ptr) and has been reported to generate up to 50% yield losses under favourable disease conditions. Although farming management practices are available to reduce disease, the most economically sustainable approach is establishing genetic resistance through plant breeding. To further understand the genetic basis for disease resistance, we conducted a phenotypic and genetic analysis study using an international diversity panel of 192 wheat lines from the Maize and Wheat Improvement Centre (CIMMYT), the International Centre for Agriculture in the Dry Areas (ICARDA) and Australian (AUS) wheat research programmes. The panel was evaluated using Australian Ptr isolates in 12 experiments conducted in three Australian locations over two years, with assessment for tan spot symptoms at various plant development stages. Phenotypic modelling indicated high heritability for nearly all tan spot traits with ICARDA lines displaying the greatest average resistance. We then conducted a one-step whole-genome analysis of each trait using a high-density SNP array, revealing a large number of highly significant QTL exhibiting a distinct lack of repeatability across the traits. To better summarise the genetic resistance of the lines, a one-step genomic prediction of each tan spot trait was conducted by combining the additive and non-additive predicted genetic effects of the lines. This revealed multiple CIMMYT lines with broad genetic resistance across the developmental stages of the plant which can be utilised in Australian wheat breeding programmes to improve tan spot disease resistance.
Conceptualising the social in mental health and work capability: implications of medicalised framing in the UK welfare system
Authors: Irvine Annie , Haggar Tianne 
Published: March 2023

Abstract
Purpose
This paper asks whether the separation of mental health from its wider social context during the UK benefits assessment processes is a contributing factor to widely recognised systemic difficulties, including intrinsically damaging effects and relatively ineffective welfare-to-work outcomes.

Methods
Drawing on multiple sources of evidence, we ask whether placing mental health—specifically a biomedical conceptualisation of mental illness or condition as a discrete agent—at the core of the benefits eligibility assessment process presents obstacles to (i) accurately understanding a claimant’s lived experience of distress (ii) meaningfully establishing the specific ways it affects their capacity for work, and (iii) identifying the multifaceted range of barriers (and related support needs) that a person may have in relation to moving into employment.

Results
We suggest that a more holistic assessment of work capacity, a different kind of conversation that considers not only the (fluctuating) effects of psychological distress but also the range of personal, social and economic circumstances that affect a person’s capacity to gain and sustain employment, would offer a less distressing and ultimately more productive approach to understanding work capability.

Conclusion
Such a shift would reduce the need to focus on a state of medicalised incapacity and open up space in encounters for more a more empowering focus on capacity, capabilities, aspirations, and what types of work are (or might be) possible, given the right kinds of contextualised and personalised support.
Demographic change and the rate of return in pay-as-you-go pension systems
Authors: Schön Matthias 
Published: March 2023

AbstractThe ongoing demographic change in most developed countries consists of two coinciding independent developments that differ in structure and persistence: A slow, monotonic and (presumably) permanent longevity effect caused by an increasing life expectancy; and a more rapidly changing, non-monotonic and less permanent cohort effect caused by fluctuations in the size of cohorts. This paper shows the longevity effect has a positive impact on the rates of return households generate within a pay-as-you-go (PAYG) pension system. The cohort effect, by contrast, results in winners and losers in PAYG systems. The paper additionally shows that the type of PAYG pension system alters the results significantly. Taking the remarkable demographic change in Germany as an example, a large-scale overlapping generation model quantifies rates of return within the PAYG pension system for every cohort. The results show that the two effects combined cause return differentials of almost 1.3 percentage points between generations.
Impact of the 12-gene recurrence score in influencing adjuvant chemotherapy prescription in mismatch repair proficient stage II/III colonic carcinoma—a systematic review and meta-analysis
Authors: Davey Matthew G. , O’Neill Maeve , Regan Mark , Meshkat Babak , Nugent Emmeline , Joyce Myles , Hogan Aisling M. 
Published: March 2023

Abstract
Introduction
The 12-gene recurrence score (RS) is a clinically validated assay which predicts recurrence risk in patients with stage II/III colon cancer. Decisions regarding adjuvant chemotherapy may be guided using this assay or based on the judgement of tumour board.

Aims
To assess the concordance between the RS and MDT decisions regarding adjuvant chemotherapy in colon cancer.

Methods
A systematic review was performed in accordance with PRISMA guidelines. Meta-analyses were performed using the Mantel–Haenszel method using the Review Manager version 5.4 software.

Results
Four studies including 855 patients with a mean age of 68 years (range: 25–90 years) met inclusion criteria. Overall, 79.2% had stage II disease (677/855) and 20.8% had stage III disease (178/855). For the entire cohort, concordant results between the 12-gene assay and MDT were more likely than discordant (odds ratio (OR): 0.38, 95% confidence interval (CI): 0.25–0.56, P < 0.001). Patients were more likely to have chemotherapy omitted than escalated when using the RS (OR: 9.76, 95% CI: 6.72–14.18, P < 0.001). For those with stage II disease, concordant results between the 12-gene assay and MDT were more likely than discordant (OR: 0.30, 95% CI: 0.17–0.53, P < 0.001). In stage II disease, patients were more likely to have chemotherapy omitted than escalated when using the RS (OR: 7.39, 95% CI: 4.85–11.26, P < 0.001).

Conclusions
The use of the 12-gene signature refutes the decision of tumour board in 25% of cases, with 75% of discordant decisions resulting in omission of adjuvant chemotherapy. Therefore, it is possible that a proportion of such patients are being overtreated when relying on tumour board decisions alone.
Forgotten forest relics: Apple trees (Malus spp.) in eastern U.S. forests
Authors: Woodall Christopher , Liknes G. C. , Bunker J. P. , Peace C. P. , Frank J. M. 
Published: March 2023

AbstractOne potential legacy of the widespread deforestation of the 1700-1800s and subsequent agricultural abandonment and reforestation across the eastern United States (U.S.) during the 1900s is the establishment of introduced apple trees (Malus domestica) exclusive of naturally occurring native crab apple species. As these apple trees might provide ecological services and a genetic reserve of long-forgotten apple cultivars, a region-wide forest inventory was used to estimate the current extent, condition, and changes in the population of apple trees across eastern forests of the U.S. It was found that hundreds of millions of apple trees currently exist in the forests of the northern U.S. with indications of population senescence as the abundance of seedlings and saplings decline while the abundance of the largest-sized trees and standing dead trees increase. The distribution of forest apple trees is only aligned with native crab apple distributions in limited areas, suggesting distinct feral apple populations derived from agricultural abandonment decades ago. As these extant apple trees are likely relics of former orchards and/or their naturally dispersed progeny, these populations may serve as an in-situ gene bank representing hundreds, if not thousands, of apple cultivars forgotten long ago but adapted to local conditions and perhaps of importance to ensuring the future resilience of domestic apple production in the context of global change.
Petro-physical Characterization of the Shallow Sediments in a Coastal Area in NE Italy from the Integration of Active Seismic and Resistivity Data
Authors: Accaino F. , Da Col F. , Böhm G. , Picotti S. , Giorgi M. , Meneghini F. , Schleifer A. 
Published: March 2023

AbstractIntegrated geophysical analysis using different methods along with a priori information from wells, is a proven approach to investigate the geology and the petro-physical characteristics of subsoil. We collected seismic and geoelectric data in an area located on the Adriatic coast in North-Eastern Italy, aimed at characterizing the quaternary sediments and the shallow geological structures. Compressional and shear-wave data provided information about geometry and velocity of the quaternary sedimentary succession, while geoelectric data provided information about the resistivity in the shallower formation, which strongly depends on the presence of groundwater (brine) and on its salinity. Clustering analysis allowed us to subdivide the study area into subdomains showing similar values of resistivity and compressional- and shear-wave velocity, enabling for a better interpretation of the processed seismic sections. Then, we calculated the petro-physical properties of the investigated sediments, i.e., brine saturation and resistivity, porosity, and clay content, for each cluster. This inverse problem involves rock-physics theories and an optimization algorithm based on the simulated annealing global-search method. The results, validated using borehole stratigraphy, provided information about the salty water wedge intrusion.
Annealing-induced phase conversion on spray pyrolyzed cubic-SnS thin films
Authors: Kishore Bhat T. R. , Jeganath K. , George Sajan D. , Raviprakash Y. 
Published: March 2023

AbstractThe cubic-tin sulfide (SnS) compound material is optimal for the absorber layer in photovoltaic technology. In this study, the role of annealing temperature on the physical properties of cubic-SnS thin film has been determined. The spray pyrolyzed SnS thin films were post-annealed, using the chemical vapor deposition system, at the temperature range between 350 and 500 °C The annealed films have been analyzed using a comprehensive range of characterization techniques i.e., X-ray diffraction (XRD), Raman spectroscopy, UV–Vis spectroscopy, Photoluminescence spectroscopy (PL), Field-emission scanning electron microscopy (FESEM), Energy dispersive spectroscopy (EDS) and Hall measurements. The XRD results discovered the phase deterioration of cubic-SnS at higher annealing temperatures i.e., > 350 °C. Further, the Raman analysis confirmed the cubic-SnS phase deterioration, along with the formation of SnS2 and Sn2S3 secondary phases, at higher annealing temperatures. Besides that, a band gap in the range of 1.63–1.68 eV has been obtained for the SnS thin films. The films exhibit the near-band edge emission peak in the PL spectra. Moreover, the SEM micrographs show the needle-shaped grains, and their size and distribution were increased with respect to the enhancement in annealing temperature. A considerable amount of sulfur inclusion was observed in EDS analysis and the films annealed at 450° exhibit the near stoichiometric composition ratio of Sn/S = 1.01. The hall measurement studies showed resistivity, carrier concentration, and mobility of 29.4–376.5 Ω cm, 4.2 × 1014–3.0 × 1016 cm−3 and 13.1–66.1 cm2/Vs, respectively.
Energy transfer mechanisms in binary tree-structured oscillator with nonlinear energy sinks
Authors: Bak Bendegúz Dezső , Rochlitz Róbert , Kalmár-Nagy Tamás 
Published: March 2023

AbstractWe study a binary tree-structured multi-degree-of-freedom nonlinear oscillator with impulsive and continuous excitations. The response of this model is studied for excitations that are applied to the largest masses. It is shown how choosing the mass of the smallest blocks influences the response of the system regarding the dissipation and how efficient targeted energy transfer is realized in the system. The simplified frequency energy plot is introduced as a means of analyzing the response of multi-degree-of-freedom systems for impulsive excitations. For continuous excitations, it is shown that the smallest masses (nonlinear energy sinks) are active only inside specific nonlinear frequency bands when the excitation amplitude is sufficiently high.
Translanguaging as bona fide practice in a multilingual South African science classroom
Authors: Charamba Erasmos 
Published: March 2023

AbstractThe call for improving students’ academic achievement in science education has increased in urgency in recent years. It has also increased in complexity in the face of the growing cultural and linguistic diversity of present-day classrooms following inter- and intra-state migration. Although translanguaging pedagogy, where languages of input and output are deliberately interchanged, remains a relatively young field of research, it has grown substantially in the past decade. The study presented in this article sought to explore the role language plays in the academic performance of multilingual students at a primary school in South Africa. Adopting an ethnographic research design, the author collected qualitative data through lesson observations video-recorded in a fifth-grade science class, supplemented with several interviews with the teacher. Data analysis involved a combination of both inductive and deductive methods, and the results affirm that translanguaging pedagogy is indispensable for effective learning in multilingual classrooms. The author’s findings confirm insights from previous research that the ability and encouragement to use multiple languages in science class allows multilingual students to engage in a practice of generating and creating scientific explanations in their own voice, resulting in better academic performance.