bluuebunny/crossref_metadata_2025_split huggingface dataset:
Gaseous Synergistic Self‐Assembly and Arraying to Develop Bio‐Organic Photocapacitors for Neural Photostimulation
Authors: Fan Xinyuan , Tang Yiming , Zhang Jiahao , Ma Kang , Xu Zhengyu , Liu Yuying , Xue Bin , Cao Yi , Mei Deqing , Wang Wei , Wei Guanghong , Tao Kai 
Published: January 2025

AbstractBioinspired supramolecular architectonics is attracting increasing interest due to their flexible organization and multifunctionality. However, state‐of‐the‐art bioinspired architectonics generally take place in solvent‐based circumstance, thus leading to achieving precise control over the self‐assembly remains challenging. Moreover, the intrinsic difficulty of ordering the bio‐organic self‐assemblies into stable large‐scale arrays in the liquid environment for engineering devices severely restricts their extensive applications. Herein, a gaseous organization strategy is proposed with the physical vapor deposition (PVD) technology, allowing the bio‐organic monomers not only self‐assemble into architectures well‐established from the solvent‐based approaches but morphologies distinct from those delivered from the liquid cases. Specifically, 9‐fluorenylmethyloxycarbonyl‐phenylalanine‐phenylalanine (Fmoc‐FF) self‐assembles into spheres with tailored dimensions in the gaseous environment rather than conventional nanofibers, due to the distinct organization mechanisms. Arraying of the spherical architectures can integrate their behaviors, thus endorsing the bio‐organic film the ability of programmable optoelectronic properties, which can be employed to design P‐N heterojunction‐based bio‐photocapacitors for non‐invasive and nongenetic neurostimulations. The findings demonstrate that the gaseous strategy may offer an alternative approach to achieve unprecedented bio‐organic superstructures, and allow ordering into large‐scale arrays for behavior integration, potentially paving the avenue of developing supramolecular devices and promoting the practical applications of bio‐organic architectonics.
Predicting Survival Rates in Brain Metastases Patients from Non‐Small Cell Lung Cancer Using Radiomic Signatures Associated with Tumor Immune Heterogeneity
Authors: Deng Fuxing , Xiao Gang , Tanzhu Guilong , Chu Xianjing , Ning Jiaoyang , Lu Ruoyu , Chen Liu , Zhang Zijian , Zhou Rongrong 
Published: January 2025

AbstractNon‐small cell lung cancer (NSCLC) frequently metastasizes to the brain, significantly worsened prognoses. This study aimed to develop an interpretable model for predicting survival in NSCLC patients with brain metastases (BM) integrating radiomic features and RNA sequencing data. 292 samples are collected and analyzed utilizing T1/T2 MRIs. Bidirectional stepwise logistic regression is employed to identify significant variables, facilitating the construction of a prognostic model, which is benchmarked against four machine learning algorithms. BM tissue samples are processed for RNA extraction and sequencing. The optimal model achieved an AUC of 0.96 and a C‐index of 0.89 in the train set and an AUC of 0.84 with a C‐index of 0.78 in the test set, indicating strong predictive performance and generalizability. Patients from Xiangya Hospital are stratified into high‐risk (n = 11) and low‐risk (n = 30) groups. RNA sequencing revealed an enrichment of immune‐related pathways, particularly the interferon (IFN) pathway in the low‐risk group. Immune cell infiltration analysis identified a significant presence of CD8+‐T cells, IFNγ‐6/‐18 in the low‐risk group, suggesting an immunologically favorable tumor microenvironment. These findings highlight the potential of combining radiomic and RNA sequencing data for improved survival predictions and personalized treatment strategies in BM patients from NSCLC.
Characterization of the Micro‐Morphology and Compositional Distribution of Chang'e‐5 Lunar Soil Mineral Surfaces Using TOF‐SIMS
Authors: Song Tinglu , Liu Jie , Zhang Chunlin , Yang Xinyu , Chen Taiyang , Jiang Shunzi , Xu Fan , Li Ning , Zhu Menghua , Li Shaolin , Zou Meishuai 
Published: January 2025

AbstractThe lunar soil samples returned by China's Chang'e‐5 (CE‐5) contain valuable information on geological evolutions on the Moon. Herein, by employing high‐resolution time‐of‐flight secondary ion mass spectrometry (TOF‐SIMS), five rock chip samples from the CE‐5 lunar soil are characterized in‐depth, which reveal micro‐morphological and compositional features. From the elemental/molecular ion distribution images, minerals such as pyroxene, ilmenite, feldspar, K‐rich glass, silica, and silicate minerals are identified, along with their occurrence states and distribution results. More importantly, uncommon vesicle‐like patterns are probed via TOF‐SIMS, which may not be captured by conventional electron microscopy. The possible origins of vesicles are also proposed. Hopefully, these discoveries will provide essential guidance for future investigations on the Moon and accelerate the application of TOF‐SIMS in space exploration.
High‐Efficiency PbS Quantum Dots Infrared Solar Cells via Numerical Simulation and Experimental Optimization
Authors: Ji Taiming , Wu Zhixu , Xiang Pengfei , Lu Yu , Liu Sisi , Tang Rongxin , Wang Yuhao , Xia Yong 
Published: January 2025

AbstractLow‐bandgap lead sulfide quantum dots (PbS QDs) can efficiently harness the infrared (IR) light in the solar spectrum beyond 1100 nm, showing great application potential in the bottom subcells of tandem solar cells. However, achieving further efficiency improvements in PbS QDs IR solar cells still faces many challenges. In this work, the effects of the absorber layer thickness, the carrier mobility in the absorber layer, the defect density in the absorber layer and at the absorber/electron transfer layer (ETL) interface, and the doping density of the ETL and hole transfer layer (HTL) on the performance of PbS QDs (≈0.95 eV) IR solar cells are systematically investigated through SCAPS‐1D simulation. A theoretical efficiency of 16.95% and 2.15% is calculated for PbS QDs IR solar cells under AM 1.5 and 1100 nm‐filtered illumination, respectively. Based on the simulation results, the corresponding PbS QDs IR solar cells are fabricated with an efficiency of 11.53% under AM 1.5 illumination, a remarkable 1100 nm‐filtered efficiency of 1.30%, and a high external quantum efficiency of 70.50% at 1290 nm. Hence, these findings will accelerate the optimization of the performance of PbS QDs IR solar cells approaching their theoretical efficiency limit.
Stable and Efficient Perovskite Photovoltaics via a Three‐In‐One Passivating Approach by Aminoacetonitrile Hydrochloride
Authors: Liu Yinjiang , Kong Tengfei , Zhang Yang , Zhao Zihan , Chen Weiting , Liu Wenli , Gao Peng , Wang Xu‐Dong , Bi Dongqin 
Published: January 2025

AbstractReducing defect density is of significant importance for enhancing the power conversion efficiency (PCE) and stability of perovskite solar cells (PSCs). While most previous outstanding studies have focused on individual layers within the perovskite device structure. Herein, a three‐in‐one strategy using the aminoacetonitrile hydrochloride (AmiHCl) molecule to reduce the defects in the bulk and surface of perovskite. The results of the study found that the AmiHCl bottom modification can decrease the number of buried interface holes, doping into bulk perovskite can modulate crystallization via a strong interaction between AmiHCl and perovskite components, and the upper interface modification can inhibit the formation of vacancies by creating hydrogen bonds with A‐site cations. This approach yields PSCs with an efficiency of 25.90% and a high fill factor (FF) of 88.54%. Additionally, the modified PSCs show significantly enhanced operational stability, with the PCE retaining more than 90.0% of the initial value after 1350 h of maximum power point tracking.
Ambient‐Printed Methylammonium‐Free Perovskite Solar Cells Enabled by Multiple Molecular Interactions
Authors: Lang Lei , Ding Zicheng , Du Yachao , Wu Nan , Liu Pengchi , Qin Ru , Wang Shuang , Wang Zhichao , Tu Yongchao , Liu Xiujie , Zhang Zheng , Gong Yongshuai , Liu Dongxue , Zhao Kui , Liu Shengzhong (Frank) 
Published: January 2025

AbstractThe ambient printing of high‐performance and stable perovskite solar cells (PSCs) is crucial for enabling low‐cost and energy‐efficient industrial fabrication. However, producing high‐quality perovskite films via ambient printing remains challenging due to direct exposure to air, which easily induces additional stacking defects and triggers perovskite degradation compared to films fabricated by traditional spin‐coating under inert conditions. Here, a multiple molecular interaction strategy is introduced to address this challenge by incorporating a 2‐thiazole formamidine hydrochloride (TC) additive, effectively suppressing defect formation during ambient printing. The specific interactions between TC and precursor components, i.e., multiple hydrogen bonds and coordination interactions, could promote the crystallization of α‐phase perovskites and reduce cation and anion vacancies simultaneously when drying in air. These endows high‐quality ambient‐printed perovskite films with large crystalline grains with eliminated nanovoids and low trap‐densities, which improve charge carrier dynamics and prevent perovskite decomposition and hydration under thermal/humidity stress during long‐term annealing/ambient storage. The unencapsulated PSCs show a high efficiency of 23.72% with good stability, i.e., realizing 92% and 95% efficiency retention after 672 h of annealing at 85 °C in a N2 atmosphere and after 2088 h of storage in ambient air.
Adult Children's Urbanization and Family Farmland Transfer: Evidence From China
Authors: Wang Zhihua , Zhang Can , Li Zhongjian , Fan Zengzeng 
Published: January 2025

ABSTRACTThe transfer of agricultural land from families to external entities can enhance land use efficiency, leading to reduced production costs and increased farmer income. However, the decision to transfer family farmland is influenced not only by macroeconomic policies and farmers' actions but also by the decisions of their adult children. This study investigates how the urbanization of adult children impacts household land transfer decisions. Using data from the China Family Panel Studies from 2012 to 2020, the research employs an Extended Regression Model to analyze this relationship. The findings reveal that adult children's urbanization significantly raises the likelihood of family farmland transfer. Further, heterogeneity analysis finds that this effect is more pronounced in households with smaller families, fewer children, no male offspring, and higher incomes. The study identifies three mechanisms through which adult children's urbanization promotes household farmland transfer: the aging effect, the accompanying migration effect, and the wealth effect.
‘I Don't Think I Would've Survived Without Having a Constant Support System’: Independent Living Skills Acquisition During the Transition From Care in Western Australia
Authors: Starr Michael , Chung Donna , Parsons Lauren , Cordier Reinie 
Published: January 2025

ABSTRACTFor care‐experienced young people, the preparation for leaving out‐of‐home care (OOHC) is vital in support of post‐OOHC outcomes. This research explores the acquisition of Independent Living Skills (ILS) amongst young people in Western Australia and is based on interviews with care‐experienced young people at two time points: while in OOHC and after leaving OOHC. Overall, 72% of participants were female, 45% had a disability and 45% identified as Aboriginal and/or Torres Strait Islander. Total years spent in care ranged from 2 to 16 years. This study adopts two research methods; first, using eight different domains to conceptualise the ILS needed in early adulthood, interview transcript data was cross‐referenced to understand the interconnected nature of ILS. Second, a thematic analysis was conducted of the interview transcripts to highlight participants' experiences. Findings highlight three themes relating to System Impacts, Social and Cultural Capital and Practical Identity and Self‐focus upon acquiring ILS. The findings address this Special Issue's sub‐themes, namely in relation to highlighting (1) examples of good policy and practice in transition planning and/or ongoing gaps in transitions from care policy, practice and implementation for 15–18 year olds/assisting care leavers aged 18–21 years and providing (2) lived experience perspectives.
The impact of ketogenic diet on the frequency of psychogenic non‐epileptic seizures (PNES): A feasibility randomized pilot study
Authors: Janssen‐Aguilar Reinhard , la Portilla Juan Galindez‐de , Martínez‐Juárez Iris E. , Mimiaga‐Hernandez Claudia , Alvarado‐Luis Gabriel , Aguilar‐Hernandez Andrea , Garcia‐Esparza Kevin Alan , Hernadez‐Palestina Mariel , Crail‐Meléndez Daniel 
Published: January 2025

AbstractThe potential of dietary interventions, particularly the use of the ketogenic diet in patients with Psychogenic Non‐Epileptic Seizures (PNES), remains underexplored. This study aimed to assess the feasibility of a 6‐week ketogenic diet (Modified Atkins Diet, MAD) intervention in adult patients with PNES and to compare its effects on PNES frequency and other variables against a control healthy diet (CD). A feasibility pilot randomized controlled trial was conducted at a tertiary neurology hospital, enrolling outpatients diagnosed with PNES and assigning them to either MAD or CD. Baseline and follow‐up assessments (at 2, 4, and 6 weeks) included evaluation of mental health, PNES frequency, and metabolic measures. Descriptive and inferential methods, including repeated measures ANOVA, were used for statistical analysis. Seventeen patients (mean age 28.23 ± 7.1) were randomly allocated to receive either MAD (n = 12) or CD (n = 5). The entire sample exhibited a significant decrease in monthly PNES frequency (p = 0.01, Hedges ES = 0.618) without differences between groups. The MAD group showed significant improvement in PNES frequency, depression, and anxiety at week six. Results demonstrate that the implementation of MAD is feasible in patients with PNES and suggest that it may reduce seizure frequency and symptoms of depression and anxiety. These findings warrant further investigation in larger, powered studies to demonstrate efficacy.Plain Language SummaryThis study explored the potential benefits of the Modified Atkins Diet (MAD) in reducing the frequency of psychogenic non‐epileptic seizures (PNES). The results showed that the diet is safe, well‐tolerated, and may decrease the occurrence of PNES, as well as symptoms of depression and anxiety. These findings suggest that dietary modifications could be a helpful complement to PNES treatment, though larger studies are necessary to confirm these outcomes.
Efficacy of integrated cultural practices for dollar spot disease management on creeping bentgrass and bermudagrass
Authors: Shahoveisi Fereshteh , Shah Kabita K. , Koch Paul , Kaminski John E. , Roberson Travis , McCall David , Nangle Edward 
Published: January 2025

AbstractDollar spot, caused by Clarireedia spp., is one of the major challenges in golf course management. While individual cultural practices such as adequate nitrogen fertilization, thatch removal, aeration, and dew removal (DR) can reduce dollar spot severity, there are limited reports across multiple locations on the effectiveness of integrating multiple cultural practices for improved dollar spot suppression. Field studies were conducted in Wisconsin, Ohio, Pennsylvania, and Virginia to evaluate the efficacy of urea fertilizer, DR, and a plant growth regulator (PGR) in dollar spot management on golf course greens and fairways. Each of the three treatments had two levels including applied or not applied. Urea and early DR reduced dollar spot severity across several locations, while PGR did not affect disease suppression. In some locations, the two‐way and three‐way interaction effects were significant, where combining the treatments reduced disease severity compared to non‐treated plots or when only one treatment was applied. Overall, the urea application had the most notable and consistent impact on reducing disease severity, while the effectiveness of DR and PGR varied depending on the location and year. Results from this study provide insights into the development of an effective integrated management program for dollar spot.
Digestive System Development and Posterior Hox/Parahox Gene Expression During Larval Life and Metamorphosis of the Phoronid Phoronopsis harmeri
Authors: Temereva Elena N. , Kostyuchenko Roman P. 
Published: January 2025

ABSTRACTPhoronida is a small group of marine animals, most of which are characterized by a long larval period and complex metamorphosis. As a result of metamorphosis, their body changes so much that their true anterior and posterior ends are very close to each other, and the intestine becomes long and U‐shaped. Using histology and electron microscopy, we have shown that the elongation and change in shape of the digestive tract that occurs during metamorphosis in Phoronopsis harmeri larvae is accompanied by the formation of new parts and changes in ultrastructure. At the same time, our in situ hybridization data suggest that the posterior markers Cdx and Post2 are expressed in posterior tissues at larval stages, during metamorphosis, and in juveniles, and that changes in their expression correlate with remodeling of the posterior parts of the digestive tract. Our data may shed light on the evolution of body patterning in animals undergoing complex metamorphosis.
You, Me, and the AI: The Role of Third‐Party Human Teammates for Trust Formation Toward AI Teammates
Authors: Erengin Türkü , Briker Roman , de Jong Simon B. 
Published: January 2025

ABSTRACTAs artificial intelligence (AI) becomes increasingly integrated in teams, understanding the factors that drive trust formation between human and AI teammates becomes crucial. Yet, the emergent literature has overlooked the impact of third parties on human‐AI teaming. Drawing from social cognitive theory and human‐AI teams research, we suggest that how much a human teammate perceives an AI teammate as trustworthy, and engages in trust behaviors toward the AI, determines a focal employee's trust perceptions and behavior toward this AI teammate. Additionally, we propose these effects hinge on an employee's perceptions of trustworthiness and trust in the human teammate. We test these predictions across two studies: (1) an online experiment comprising individuals with work experience that examines perceptions of disembodied AI trustworthiness, and (2) an incentivized observational study that investigates trust behaviors toward an embodied AI. Both studies reveal that a human teammate's perceived trustworthiness of, and trust in, the AI teammate strongly predict the employee's trustworthiness perceptions and behavioral trust in the AI teammate. Furthermore, this relationship vanishes when employees perceive their human teammates as less trustworthy. These results advance our understanding of third‐party effects in human‐AI trust formation, providing organizations with insights for managing social influences in human‐AI teams.
Improvement of Functional and Technological Properties of Chickpea Aquafaba Through Lactic Fermentation
Authors: Colucci Cante Rosa , Nigro Federica , Lentini Giulia , Passannanti Francesca , Gallo Marianna , Mauriello Francesca , Budelli Andrea Luigi , Nigro Roberto 
Published: January 2025

ABSTRACTBioconversion processes represent sustainable, environmentally friendly, and cost‐effective tools to improve the nutritional quality, bioactivity, and technological properties of agri‐food waste. The chickpea cooking wastewater aquafaba, commonly used as an egg‐replacer ingredient in various food formulations, was investigated as a suitable substrate for Lacticaseibacillus paracasei NPB‐01's growth, which reached a final bacterial load of 9 Log and lactic acid production of 2.16 g/L after 24 h of process. Despite total saponins and polyphenols showing nonsignificant differences before and after fermentation, a significant improvement in the antioxidant power of fermented aquafaba was found. The microbial proteolysis and the simultaneous approach of pH to the chickpea proteins' isoelectric value (approximately 4.5) conferred high surface hydrophobicity and flexibility to the protein units, emphasizing the technological characteristics of aquafaba. In particular, a tenfold‐enhanced emulsifying capacity and a significant improvement in foam and emulsion stability (98% and 100%, respectively) were observed, confirming the potential of fermented aquafaba as an enhanced texture‐modifying ingredient with probiotic and antioxidant properties.
Topologically Integrated Photonic Biosensor Circuits
Authors: Kong Ze‐Lin , Liu Yang , Jiang Jian‐Hua 
Published: January 2025

AbstractIntegrated nanophotonic biosensors offer a promising route toward future biomedical detection applications that may enable inexpensive, portable, and sensitive diagnosis of diseases with a small amount of biological samples for convenient early‐stage screening of fatal diseases. However, the current photonic biosensor designs are not suitable for highly integrated and multiplexing device architectures that can achieve the detection of complex combinations of many biomarkers. Here, a topological scheme is proposed for the integration of miniature biosensors in photonic crystal chips that can meet the above requirement. Using photonic topological edge states as robust 1D waveguides that connect many photonic biosensors, here the topologically integrated photonic biosensor circuits is proposed. It is demonstrated that the performance of the topologically integrated photonic biosensors is much more robust against disorders than that of the photonic biosensors connected by the normal photonic waveguides, due to the robust transport of photons along the edge channel. Since disorders arising from the fabrication imperfection and the random distribution of the biomarkers are inevitable in genuine devices, resilience against disorders is a necessity for on‐chip integration of biosensors. The topological scheme proposed here thus opens a promising path toward reliable integration of photonic biosensors for next‐generation biomedical applications.
Tristate Switching of Terahertz Metasurfaces Enabled by Transferable VO2
Authors: Zhu Fengjie , Yang Kainan , Hao Jianhua , Fan Kebin , Ma He , Wu Jingbo , Zhang Caihong , Zhang Xinping , Wang Huabing , Jin Biaobing , Chen Jian , Wu Peiheng 
Published: January 2025

AbstractAchieving dynamic switching among absorption (A), reflection (R), and transmission (T) states is not only essential for advancing the understanding of light‐metasurface interactions but also holds significant potential for practical applications, such as selective electromagnetic shielding and smart windows. However, at terahertz and higher frequencies, implementing active elements in multilayer configurations presents challenges that are not as straightforward as those encountered in the microwave range. In this work, it is demonstrated that tristate ART tuning can be realized in a single‐layer, free‐standing metasurface by switching between a dual dipolar mode (electric dipole and magnetic dipole) and a single dipole mode (electric dipole). By transferring a flexible vanadium dioxide (VO2) thin film onto the free‐standing dielectric Huygens’ metasurface, ART modulation is achieved, transitioning from a near‐unity transmission state to a near‐perfect absorption state, and finally to a high‐reflection state with the reflection up to 0.65 during the insulator‐to‐metal transition induced by heating onto the phase‐change material. The results may lead to new approaches in designing reconfigurable metasurfaces based on phase‐change materials for wavefront control and electromagnetic shielding applications.