bluuebunny/crossref_metadata_2025_split huggingface dataset:
Limibacter
Authors: Yokota Akira 
Published: March 2023

Abstract

Li.mi.bac'ter. L. masc. n.
limus
, mud; N.L. masc. n.
bacter
(equivalent of Gr. neut. n.
baktron
) rod or staff; N.L masc. n.
Limibacter
, rod from mud, referring to the isolation source of the first strain.

Bacteroidota / Flavobacteria / Flavobacteriales / Flammeovirgaceae / Limibacter

The genus
Limibacter
accommodates strictly aerobic, Gram‐negative, gliding, apricot‐ to pale‐orange‐pigmented, rod‐shaped bacteria, which were isolated from marine sediments. Members of this genus are mesophilic heterotrophs, which require NaCl for growth. The major menaquinone is MK‐7. The major fatty acids are iso‐C
15:0
and C
16:1
ω7
c
. The genus includes one species,
Limibacter armeniacum
. Known habitats are marine sediments.

DNA G + C content (mol%)
: 27.8–27.9 (HPLC).

Type species
:
Limibacter armeniacum
Yoon et al. 2008
VP
.
Thiohalospirales ord. nov.
Authors: Sorokin Dimitry Y. , Merkel Alexander Y. 
Published: March 2023

Abstract

Thi.o.ha.lo.spir.al'es N.L. fem. n.
Thiohalospira
, the type genus of the order; L. fem. pl. n. suff. ‐
ales,
ending to denote an order; N.L. fem. pl. n.
Thiohalospirales,
the order of the genus
Thiohalospira
.

Proteobacteria / Gammaproteobacteria / Thiohalospirales ord. nov.

The order
Thiohalospirales
accommodates aerobic, chemolithoautotrophic, sulfur‐oxidizing halophilic bacteria from hypersaline habitats which assimilate CO
2
via the Calvin–Benson‐Bassham cycle. The order is a deeply branching lineage of the
Gammaproteobacteria
and consists of a single family
Thiohalospiraceae
and genus
Thiohalospira
. The order‐level status was established by phylogenomic analysis based on the Genome Taxonomy DataBase classification.

Type genus
:
Thiohalospira
Sorokin et al. 2008
VP
.
Using mixed models to examine the factors associated with intimate partner violence among married women in Pakistan
Authors: Raza Hassan , Baron Cortes Linda M. , van Eeden‐Moorefield Brad , Khaw Lyndal 
Published: March 2023

AbstractCurrently, the rate of intimate partner violence (IPV) in Pakistan is 29%, which is likely an underestimate. This study used mixed models to examine the effects of women empowerment, women and husband's education, number of adult women in a household, number of children 5 or under in a household, and place of residence on physical violence and controlling behavior, controlling for women's current age and wealth status. Nationally representative data collected from 3,545 currently married women in the Pakistan Demographic and Health Survey (2012–2013) was used for the current study. Mixed models were estimated separately for physical violence and controlling behavior. Logistic regression was also used to conduct additional analyses. Results indicated that women and their husband's education, and number of adult women in a household were associated with a decrease in physical violence, whereas women's empowerment, and women and their husband's education were associated with a decrease in controlling behavior. The implications and limitations of the study are discussed.
Bioinspired Nanofibrous Aerogel with Vertically Aligned Channels for Efficient Water Purification and Salt‐Rejecting Solar Desalination
Authors: Ma Wenjing , Lu Tao , Cao Wenxuan , Xiong Ranhua , Huang Chaobo 
Published: March 2023

AbstractSolar steam generation has become one of the most promising strategies to relieve the freshwater crisis. Whereas, the construction of a solar‐thermal water evaporation structure that can operate continuously under sunlight to generate clean water with high efficiency, good stability, and high salt‐rejecting capability is quite crucial but challengeable. Enlightened by the water transport and transpiration process in trees, an advanced nanofibrous aerogel evaporator is fabricated with multifunctional capabilities through decoration of functional component onto an aerogel skeleton. The rational integration of hierarchical structure and functional constituents, results in outstanding solar‐vapor conversion efficiency of 96.1% and a fast evaporation rate about 2.33 kg m−2 h−1 under 1 sun. Additionally, the evaporator exhibits remarkably outdoor evaporation and highly effective salt‐resistant performances. Significantly, the evaporator can monitor salt precipitation in its inner pores in real time. This study demonstrates an eco‐friendly and economic solution for sustainable clean water production using nanofiber aerogel‐based evaporators.
One‐Component Artificial Gustatory System Based on Hydrogen‐Bond Organic Framework for Discrimination of Versatile Analytes
Authors: Jiang Minhao , Yan Xiangyu , Wang Yibo , Pu Fang , Liu Huiling , Li Yumei , Yang Chunfeng , Zhu Jiawei , Liu Xuemeng , Ren Jinsong , Qu Xiaogang 
Published: March 2023

AbstractHydrogen‐bond organic frameworks (HOFs) with excellent structural and luminescent properties have emerged as a promising material for the construction of fluorescence sensors. However, designing a facile, universal and high throughput sensor with multiplex detection capacity still remains challenging. Herein, a one‐component sensor array is constructed that mimics natural gustatory system for accurate and high‐throughput discrimination and identification of versatile analytes. HOF as a single sensing element greatly simplifies the probe preparation in sensor array and detection procedure. Metal ions, proteins and bacteria as the model targets are rapid and accurately discriminated, presenting the universality of the system. Particularly, the system is successfully used for the classification of antibiotic mechanisms. The study expands the application scope of HOFs and provides a facile and universal system for sensing applications.
A Bionic‐Gill 3D Hydrogel Evaporator with Multidirectional Crossflow Salt Mitigation and Aquaculture Applications
Authors: Zhang Lidian , Zhang Yu , Zou Miaomiao , Yu Cunlong , Li Chuxin , Gao Can , Dong Zhichao , Wu Lei , Song Yanlin 
Published: March 2023

AbstractIn recent years, interfacial solar‐driven steam generation has gained huge attention as a sustainable and energy‐efficient technology. However, salt scaling on and inside the evaporator structure induced by insufficient ion distribution control will lower the evaporation performance and hinder the stability and durability of evaporators. Herein, inspired by the highly efficient salt‐expelling property of the gill filaments of large yellow croaker, a bionic‐gill 3D hydrogel evaporator is proposed with fabulous multidirectional ion migration controllability. A 3D structure composed of arrayed beaded hollow columns with beaded hollow holes inspired by gill filaments ensuring longitudinal ion backflow and the peristome‐mimetic arrayed grooves of microcavities ensuring lateral ion advection is designed and constructed to achieve fabulous multidirectional crossflow salt ion migration, which ensures high evaporation performance for pure water (an evaporation rate of 2.53 kg m−2 h−1with an energy efficiency of 99.3%) as well as for high salinity brine (2.11 kg m−2 h−1for 25.0 wt.% NaCl solution), with no salt crystallizing after long‐term use. Furthermore, the 3D hydrogel evaporator has excellent chemical stability, mechanical properties, folding‐irrelevant evaporation performance, and portability so that it can be used for the preliminary desalination of breeding wastewater through the proposed self‐circulation koi aquaculture system.
“One Stone Five Birds” Plasma Activation Strategy Synergistic with Ru Single Atoms Doping Boosting the Hydrogen Evolution Performance of Metal Hydroxide
Authors: Yan Ping , Yang Tao , Lin Minxi , Guo Yanan , Qi Zipeng , Luo Qiquan , Yu Xin‐Yao 
Published: March 2023

AbstractLayered metal hydroxides (LMHs) are promising catalysts for oxygen evolution reaction. However, the hydrogen evolution reaction (HER) activity of LMHs is unsatisfactory due to their poor conductivity and limited active sites. Herein, taking Ni(OH)2 as demonstration, a novel “one stone five birds” plasma activation strategy synergistic with Ru single atoms (Ru SAs) doping is developed to boost the HER activity of Ni(OH)2 by constructing heterostructured β‐Ni(OH)2/Ni‐Ru SAs nanosheet arrays (NSAs). Benefiting from the structural/compositional features and optimized electronic state, the as‐obtained β‐Ni(OH)2/Ni‐Ru SAs NSAs exhibit splendid HER activity with a low overpotential of 16 mV at 10 mA cm−2 and a small Tafel slope of 21 mV dec−1 in alkaline solution. Excellent HER performance in alkaline seawater and neutral solutions are also demonstrated by the β‐Ni(OH)2/Ni‐Ru SAs NSAs. The plasma activation and Ru SAs doping play important roles in enhancing water adsorption and accelerating the kinetics of water dissociation. Density functional theory (DFT) calculations reveal that the introduction of Ru SAs in the system facilitates the generation of surface OH vacancies for providing more active sites as well as decreases the antibonding state density of the generated mid‐gap state for enhancing H adsorption strength toward the optimal range.
Anion‐Incorporated Mg‐Ion Solvation Modulation Enables Fast Magnesium Storage Kinetics of Conversion‐Type Cathode Materials
Authors: Shen Yinlin , Wang Yujia , Miao Yingchun , Li Qiang , Zhao Xiangyu , Shen Xiaodong 
Published: March 2023

AbstractRechargeable magnesium batteries (RMB) have emerged as one of the most promising alternatives to lithium‐ion batteries due to the prominent advantages of magnesium metal anodes. Nevertheless, their application is hindered by sluggish Mg‐ion storage kinetics in cathodes, although various structural modifications of cathode materials have been performed. Herein, an electrolyte design using an anion‐incorporated Mg‐ion solvation structure is developed to promote the Mg‐ion storage reactions of conversion‐type cathode materials. The addition of the trifluoromethanesulfonate anion (OTf−) in the ether‐based Mg‐ion electrolyte modulates the solvation structure of Mg2+ from [Mg(DME)3]2+ to [Mg(DME)2.5OTf]+ (DME = dimethoxy ethane), which facilitates Mg‐ion desolvation and thus significantly expedites the charge transfer of the cathode material. As a result, the as‐prepared CuSe cathode material on copper current collector exhibits a considerable increase in magnesium storage capacity from 61% (228 mAh g‐1) to 95% (357 mAh g‐1) of the theoretical capacity at 0.1 A g‐1 and a more than twofold capacity increase at a high current density of 1.0 A g‐1. This work provides an efficient strategy via electrolyte modulation to achieve high‐rate conversion‐type cathode materials for RMBs.
Ultrathin Nitride Ferroic Memory with Large ON/OFF Ratios for Analog In‐Memory Computing
Authors: Wang Ding , Wang Ping , Mondal Shubham , Hu Mingtao , Wu Yuanpeng , Ma Tao , Mi Zetian 
Published: March 2023

AbstractComputing in the analog regime using nonlinear ferroelectric resistive memory arrays can potentially alleviate the energy constraints and complexity/footprint challenges imposed by digital von Neumann systems. Yet the current ferroelectric resistive memories suffer from either low ON/OFF ratios/imprint or limited compatibility with mainstream semiconductors. Here, for the first time, ferroelectric and analog resistive switching in an epitaxial nitride heterojunction comprising ultrathin (≈5 nm) nitride ferroelectrics, i.e., ScAlN, with potentiality to bridge the gap between performance and compatibility is demonstrated. High ON/OFF ratios (up to 105), high uniformity, good retention, (<20% variation after > 105 s) and cycling endurance (>104) are simultaneously demonstrated in a metal/oxide/nitride ferroelectric junction. It is further demonstrated that the memristor can provide programmability to enable multistate operation and linear analogue computing as well as image processing with high accuracy. Neural network simulations based on the weight update characteristics of the nitride memory yielded an image recognition accuracy of 92.9% (baseline 96.2%) on the images from Modified National Institute of Standards and Technology. The non‐volatile multi‐level programmability and analog computing capability provide first‐hand and landmark evidence for constructing advanced memory/computing architectures based on emerging nitride ferroelectrics, and promote homo and hybrid integrated functional edge devices beyond silicon.
Biomimetic Gradient Bouligand Structure Enhances Impact Resistance of Ceramic‐Polymer Composites
Authors: Wen Shao‐Meng , Chen Si‐Ming , Gao Weitao , Zheng Zhijun , Bao Jia‐Zheng , Cui Chen , Liu Shuai , Gao Huai‐Ling , Yu Shu‐Hong 
Published: March 2023

AbstractBiological materials relied on multiple synergistic structural design elements typically exhibit excellent comprehensive mechanical properties. Hierarchical incorporation of different biostructural elements into a single artificial material is a promising approach to enhance mechanical properties, but remains challenging. Herein, a biomimetic structural design strategy is proposed by coupling gradient structure with twisted plywood Bouligand structure, attempting to improve the impact resistance of ceramic‐polymer composites. Via robocasting and sintering, kaolin ceramic filaments reinforced by coaxially aligned alumina nanoplatelets are arranged into Bouligand structure with a gradual transition in filament spacing along the thickness direction. After the following polymer infiltration, biomimetic ceramic‐polymer composites with a gradient Bouligand (GB) structure are eventually fabricated. Experimental investigations reveal that the incorporation of gradient structure into Bouligand structure improves both the peak force and total energy absorption of the obtained ceramic‐polymer composites. Computational modeling further suggests the substantial improvement in impact resistance by adopting GB structure, and clarifies the underlying deformation behavior of the biomimetic GB structured composites under impact. This biomimetic design strategy may provide valuable insights for developing lightweight and impact‐resistant structural materials in the future.
Thermally Enhanced and Long Lifetime Red TADF Carbon Dots via Multi‐Confinement and Phosphorescence Assisted Energy Transfer
Authors: Lou Qing , Chen Niu , Zhu Jinyang , Liu Kaikai , Li Chao , Zhu Yongsheng , Xu Wen , Chen Xu , Song Zhijiang , Liang Changhao , Shan Chong‐Xin , Hu Junhua 
Published: March 2023

AbstractThermally activated delayed fluorescence (TADF) materials, which can harvest both singlet and triplet excitons for high‐efficiency emission, have attracted widespread concern for their enormous applications. Nevertheless, luminescence thermal quenching severely limits the efficiency and operating stability in TADF materials and devices at high temperature. Herein, a surface engineering strategy is adopted to obtain unique carbon dots (CDs)‐based thermally enhanced TADF materials with ≈250% enhancement from 273 to 343 K via incorporating seed CDs into ionic crystal network. The rigid crystal network can simultaneously boost reverse intersystem crossing process via enhancing spin‐orbit coupling between singlet and triplet states and suppressing non‐radiative transition rate, contributing to the thermally enhanced TADF character. Benefiting from efficient energy transfer from triplet states of phosphorescence center to singlet states of CDs, TADF emission at ≈600 nm in CDs displays a long lifetime up to 109.6 ms, outperforming other red organic TADF materials. Thanks to variable decay rates of the delayed emission centers, time and temperature‐dependent delayed emission color has been first realized in CDs‐based delayed emission materials. The CDs with thermally enhanced and time‐/temperature‐dependent emission in one material system can offer new opportunities in information protection and processing.
Covalent Organic Frameworks for Atmospheric Water Harvesting
Authors: Nguyen Ha L. 
Published: March 2023

AbstractAtmospheric water harvesting using reticular materials is an innovation that has the potential to change the world. Using covalent organic frameworks (COFs) for capturing water holds great promise because COFs are metal‐free, stable under working conditions, and their structure can be intentionally designed to meet the requirements for this application. To promote the chemistry and use of COFs for atmospheric water harvesting, important features for synthesizing suitable water‐harvesting COFs are discussed. The achievements of using COFs as water harvesters are then highlighted, showing how the water harvesting properties are related to the structural design. Finally, perspectives and research directions for further studies in COF chemistry are provided.
Photo‐Stimuli‐Responsive Dual‐Emitting Luminescence of a Spiropyran‐Encapsulating Metal–Organic Framework for Dynamic Information Encryption
Authors: Zheng He‐Qi , Yang Yu , Wang Zhiyu , Yang Deren , Qian Guodong , Cui Yuanjing 
Published: March 2023

AbstractThe development of photo‐stimuli‐responsive luminescent materials is essential to address emerging demands in encryption security. Here, a novel photo‐stimuli‐responsive dual‐emitting luminescent material ZJU‐128⊃SP (SP = spiropyran) is reported, which is obtained by encapsulating spiropyran molecules into a cadmium‐based metal–organic framework (MOF), [Cd3(TCPP)2]·4DMF·4H2O (ZJU‐128, H4TCPP = 2,3,5,6‐tetrakis (4‐carboxyphenyl)pyrazine). This MOF/dye composite ZJU‐128⊃SP exhibits a blue emission from the ligand of ZJU‐128 at 447 nm and a red emission around 650 nm from spiropyran. Utilizing the photoisomerization of spiropyran from ring‐closed to ring‐open form under UV‐light irradiation, significant fluorescence resonance energy transfer (FRET) process between ZJU‐128 and spiropyran is achieved. As a result, the blue emission of ZJU‐128 is gradually decreased while the red emission of spiropyran increases. This dynamic fluorescent behavior can fully recover to the original state following exposure to visible light (>405 nm). By taking advantage of the time‐dependent fluorescence, dynamical anti‐counterfeiting patterns and multiplexed coding are successfully developed based on ZJU‐128⊃SP film. This work provides an inspiring point for the design of information encryption materials with higher security requirements.
Emerging Iontronic Neural Devices for Neuromorphic Sensory Computing
Authors: Dai Shilei , Liu Xu , Liu Youdi , Xu Yutong , Zhang Junyao , Wu Yue , Cheng Ping , Xiong Lize , Huang Jia 
Published: March 2023

AbstractLiving organisms have a very mysterious and powerful sensory computing system based on ion activity. Interestingly, studies on iontronic devices in the past few years have proposed a promising platform for simulating the sensing and computing functions of living organisms, because: 1) iontronic devices can generate, store, and transmit a variety of signals by adjusting the concentration and spatiotemporal distribution of ions, which analogs to how the brain performs intelligent functions by alternating ion flux and polarization; 2) through ionic‐electronic coupling, iontronic devices can bridge the biosystem with electronics and offer profound implications for soft electronics; 3) with the diversity of ions, iontronic devices can be designed to recognize specific ions or molecules by customizing the charge selectivity, and the ionic conductivity and capacitance can be adjusted to respond to external stimuli for a variety of sensing schemes, which can be more difficult for electron‐based devices. This review provides a comprehensive overview of emerging neuromorphic sensory computing by iontronic devices, highlighting representative concepts of both low‐level and high‐level sensory computing and introducing important material and device breakthroughs. Moreover, iontronic devices as a means of neuromorphic sensing and computing are discussed regarding the pending challenges and future directions.
Advances in Metaphotonics Empowered Single Photon Emission
Authors: Kan Yinhui , Bozhevolnyi Sergey I. 
Published: March 2023

AbstractSpontaneous photon emission can be drastically modified by placing quantum emitters (QEs) in nanostructured environment, resulting in dramatically enhanced emission rates due to the Purcell effect along with generation of collimated single‐photon beams propagating in design directions and featuring well‐defined polarization states. Recent advances in single‐photon generation engineering demonstrate fascinating possibilities for the directional emission of photons with designed spin and orbital angular momenta, a development that is crucial for exploiting the full potential of QEs within quantum information technologies. Although many different nanostructured configurations are considered for hosting QEs to mold single‐photon beams, collimating of the latter requires relatively large interaction areas to be involved, thus making the use of metasurfaces preferential. Furthermore, optical metasurfaces consisting of planar arrays of resonant nanoscale elements offer complete control over optical fields and thereby design freedom in shaping single‐photon emission. Here, recent advances in exploiting quantum optical metasurfaces for achieving enhanced and directional emission of single photons with specified polarization properties are overviewed. Special attention is paid to hybrid plasmon–QE coupled metasurfaces based on efficient QE coupling to surface plasmon modes that are subsequently outcoupled by designed dielectric nanoarrays into free propagating photon emission. Perspectives for future developments of metasurface empowered QEs are also discussed.
Visualizing Circularly Polarized Long Afterglow for Information Security
Authors: Zhao Shanshan , Li Guangen , Guo Qi , Wang Yaxin , Zhang Mingjiang , Zhou Yajie , Jin Shan , Zhu Manzhou , Zhuang Taotao 
Published: March 2023

AbstractCreating security materials that carry distinct information with numerous optical characteristics enables enhanced anticounterfeiting levels to deter forgery ranging from currencies to pharmaceuticals. Circularly polarized long afterglow (CPLA) has attracted extensive attention in anticounterfeiting owing to its multiple and unusual optical properties (i.e., long afterglow and circular polarization), introducing intensity variation into the time dimension. However, constructing a visualized CPLA—meeting the requirements toward practical applications—is still a challenge. Here, a cementation‐coupling strategy is designed to combine chiral photonic membranes with phosphor films for building full‐colored CPLA architectures. The CPLA systems achieve desired performance with a largest afterglow dissymmetry value (gCPLA) of −0.67 and a longest visualization time (tvis) of 40 min simultaneously, satisfying practical demands for information security. As‐prepared CPLA materials are further patterned to work as optical labels in security fields. The resulting multidimensional variations in both time and intensity increase the complexity of information encryption, offering potentials for advanced security technologies.