bluuebunny/crossref_metadata_2025_split huggingface dataset:
Du niveau textuel au niveau énonciatif dans la grammaticalisation : le rôle du contexte
Authors: Combettes Bernard 
Published: January 2023

Bernard Combettes : From textual level to enundative level in the grammaticalization process : the function of context.
This paper analyses the function of linguistic contexts in the grammaticalization process. Within the theoretical framework of the "evolution in three levels" (propositional level, textual level, pragmatic level), we underline the importance and the specificity of thematic constructions from a diachronic point of view. Certain expressions evolve first from linked adverbial to a thematic function, then to a topic function. This is exemplified by the study of two samples : the evolution of topic markers like quant a, en ce qui concerne, and the evolution ofthe su bord inator dans la mesure ou.
Comme et ses valeurs : le point de vue historique (XIVe-XVIe siècles)
Authors: Kuyumcuyan Annie 
Published: January 2023

Annie Kuyumcuyan : The meanings of comme : a historical perspective (14th-16th centuries).
Among function words which can have many meanings depending on the context, comme is one ofthe most polysemie in Modem French, even when it is only studied in its subordinate role in complex sentences. Imbs considered that it was unequalled in the variety of its different uses. The study of comme from a diachronic point of view has been facilitated by the computerization of huge corpuses, which allow a better understanding of its polysemy. It is thus possible to discover the stages by which the word has passed and to identify apparently heterogeneous meanings, which are actually coherent, when taking their progressive construction into consideration.
One-Pot Protolignin Extraction by Targeted Unlocking Lignin–Carbohydrate Esters via Nucleophilic Addition–Elimination Strategy
Authors: Lou Yuhan , Sun Xinyue , Yu Yanyan , Zeng Suqing , Li Yilin , Liu Yongzhuang , Yu Haipeng 
Published: January 2023

Protolignin extraction can facilitate structure elucidation and valorization of lignin in biorefinery, but is rather challenging due to the complex chemical bonds present. Here, we developed the in situ generated NH
3
-reline (IGNR) system to realize one-pot protolignin extraction from lignocellulose. In the IGNR system, reline consisting of choline chloride and urea acted as both a solvent and a nucleophile generator, and the nucleophilic addition–elimination mechanism was verified by model compound studies. The in situ generated NH
3
could precisely cleave the lignin–carbohydrate esters in lignocellulose with a near-quantitative retention of carbohydrates. The extracted IGNR–Protolignin exhibited native lignin substructure with high molecular weight and high β-O-4′ content (41.5 per 100 aromatic units). In addition, the up-scaled kilogram reaction demonstrated the feasibility of the IGNR system for potential industrial application in a green and sustainable pathway. This work represents a breakthrough toward protolignin extraction in practice with the future goal of achieving total biorefinery.
Evaluation of Complex Treatment of Patients with Traumatic Optical Neuropathy Based on Functional and Hemodynamic Indicators of the Eye
Authors: С.С. Агзамова, 
Published: January 2023

Цель. Определение эффективности комплексного лечения пациентов с сочетанными травмами орбиты, осложненными травматической оптической нейропатией. Материалы и методы. С 2019 по 2020 год в отделение челюстно-лицевой хирургии госпитализировано 1152 пациента с черепно-мозговой травмой, из них у 784 диагностированы различные переломы костей средней зоны лица, среди которых у 35 пациентов (35 глаз) была выявлена ТОН. Пациенты были разделены на две группы в зависимости от проводимой терапии. Результаты. Анализ результатов сочетанного хирургического и совместного офтальмологического консервативного лечения пациентов основной группы показал достоверное улучшение гемодинамических показателей, которые указывают на стабилизацию ишемического процесса в 95% случаев, а также анализ показал, что уже на ранних стадиях патологии макулярная зона сетчатки участвует в процессе. Эти отклонения в раннем посттравматическом периоде говорят об изначальном функциональном угнетении колбочко-палочковой системы. Эти параметры у пациентов основной группы достоверно коррелировали с показателями остроты зрения.
Purpose. To determine the effectiveness of complex treatment of patients with concomitant orbital injuries complicated by traumatic optic neuropathy. Materials and methods. From 2019 to 2020, 1152 patients with craniocerebral trauma were hospitalized in the Department of Maxillofacial Surgery, of which 784 were diagnosed with various fractures of the bones of the middle zone of the face, among which 35 patients (35 eyes) were diagnosed with TON. Patients were divided into two groups, depending on the therapy. Results. Analysis of the results of combined surgical and joint ophthalmic conservative treatment of patients in the main group showed a significant improvement in hemodynamic parameters, which indicate stabilization of the ischemic process in 95% of cases, and the analysis showed that already in the early stages of the pathology, the macular area of the retina is involved in the process. These deviations in the early post- traumatic period indicate the initial functional inhibition of the cone-rod system. These parameters in patients of the main group significantly correlated with visual acuity.
Femtosecond Laser-Assisted Surgical Management of Postkeratoplasty Astigmatism: Indications and Results
Authors: Г.В. Ситник, 
Published: January 2023

Посткератопластический астигматизм – одна из ведущих причин низкого зрения после пересадки роговицы. Цель исследования. Изучить эффективность хирургического лечения посткератопластического астигматизма высокой степени после пересадки роговицы по поводу кератоконуса. Материалы и методы. В исследование включены 24 пациента (24 глаза) с посткератопластическим астигматизмом. В 1-ю группу вошли 15 пациентов с правильным астигматизмом, которым выполняли фемтоассистированную дугообразную кератотомию (ФАДК); 2-ю составили 9 пациентов, у 6 из которых астигматизм был неправильным. Во 2-й группе выполняли фемтоассистированную циркулярную клиновидную резекцию роговицы (ФЦКР). Результаты. У пациентов обеих групп получено достоверное улучшение кератотопографических индексов, а также улучшение НКОЗ и КОЗ после операций. В 1-й группе КОЗисх составляла 0,2 (0,10–0,3), КОЗитог – 0,6 (0,5–0,7) (T=0, Z=3,408, p<0,001). Во 2-й группе КОЗисх составляла 0,1 (0,09–0,2), КОЗитог – 0,6 (0,55–0,7) (T=0, Z=2,521, p=0,012). Выводы. Выполнение ФАДК при правильном посткератопластическом астигматизме позволяет уменьшить величину кератометрического цилиндра на 61%, значимо повысить как НКОЗ, так и КОЗ. ФЦКР эффективна при неправильном астигматизме и может являться альтернативой повторной пересадке роговицы.
Post-keratoplasty astigmatism is one of the leading causes of low vision after corneal transplantation. Purpose. To study the effectiveness of surgical management of high post-keratoplasty astigmatism after corneal transplantation for keratoconus. Materials and methods. The study included 24 patients (24 eyes) with post-keratoplasty astigmatism. Group 1 included 15 patients with regular astigmatism who underwent femtosecond laser-assisted arcuate keratotomy (FLAK); the 2nd consisted of 9 patients, 6 of whom had irregular astigmatism. In group 2, femtosecond laser-assisted circular wedge resection of the cornea (FCWR) was performed. Results. In patients of both groups, a significant improvement in keratotopography indices was obtained, as well as an improvement in UCVA and BCVA after surgery. In group 1, initial BCVA was 0.2 (0.10–0.3), final BCVA was 0.6 (0.5–0.7) (T=0, Z=3.408, p<0.001). In group 2, initial BCVA was 0.1 (0.09–0.2), final BCVA – 0.6 (0.55–0.7) (T=0, Z=2.521, p=0.012). Conclusions. FLAK in patients with regular high post-keratoplasty astigmatism helps reduce the keratometric cylinder by 61%, significantly increase both UCVA and BCVA. FCWR is effective for irregular astigmatism and may be an alternative to corneal retransplantation.
Highly sensitive photodetector based on two-dimensional ferroelectric semiconducting β-InSe/graphene heterostructure
Authors: Li Jialin , Chen Yuzhong , Li Yujie , Zhu Haiming , Li Linjun 
Published: January 2023

Abstract
A 2D ferroelectric β-InSe/graphene heterostructure was fabricated by mechanical exfoliation, and the carrier dynamics crossing the heterostructure interface has been systematically investigated by Raman, photoluminescence, and transient absorption measurements. Due to the efficient interfacial photo excited electron transfer and photogating effect from trapped holes, the heterostructure devices demonstrate superior performance with a maximum responsivity of 2.12 × 104 A W−1, detectivity of 1.73 × 1014 Jones, and fast response time (241 μs) under λ = 532 nm laser illumination. Furthermore, the photo responses influenced by the ferroelectric polarization field are investigated. Our work confirms a ferroelectric β-InSe/graphene heterostructure as an outstanding material platform for sensitive optoelectronic applications.
Pendidikan Tahfidz Al-Qur’an Di SMPN 2 Amuntai Selatan Kabupaten Hulu Sungai Utara
Authors: Hamli Haji 
Published: January 2023

<p align="center"><strong>Abstrak</strong><strong> </strong></p><p>Pendidikan tahfidz Al-qur’an di SMPN 2 Amuntai Selatan Kabupaten Hulu Sungai Utara yang baik sangat diharapkan. Hal ini dimaksudkan untuk mensukseskan para siswa yang berilmu dengan didasari oleh al-Qur’an. Berdasarkan pernyataan ini, maka dilakukan penelitian dengan fokus penelitian yang menitik beratkan pada pendidikan tahfidz al-Qur’an di SMPN 2 Amuntai Selatan Kabupaten Hulu Sungai Utara. Adapun tujuan penelitian ini adalah untuk mengetahui pendidikan tahfidz al-Qur’an di SMPN 2 Amuntai Selatan Kabupaten Hulu Sungai Utara. Guru pendidikan tahfidz dan beberapan orang siswa yang sedang menghafala Al-Qur’an di SMPN 2 Amuntai Selatan Kabupaten Hulu Sungai Utara. Adapun teknik yang digunakan dalam pengumpulan data adalah wawancara, observasi, dan dokumentasi. Kemudian diolah melalui proses reduksi data, display data, dan verifikasi data. Sedangkan untuk menganalisiskan data penulis menggunakan analisis deskriptif dan kualitatif. Akhirnya dapat diambil kesimpulan bahwa pendidikan tahfidz al-Qur’an di SMPN 2 Amuntai Selatan Kabupaten Hulu Sungai Utara tergambar pada; <em>Pertama</em>, telah memanajemen waktu, tempat, dan materi yang dihafal. <em>Kedua</em>, telah mengaktifkan dan memperkuat peran instruktur tahfidz dalam membimbing dan memotivasi siswa penghafal al-Qur’an. <em>Ketiga</em>, telah menyempurnakan mekanisme dan metode yang diterapkan oleh guru tahfiz. <em>Keempat</em>, telah memperkuat dukungan orangtua. <em>Kelima</em>, telah memperkuat kontrol dan motivasi atasan. Adapun beberapa faktor penting yang diperhatikan, antara lain; <em>Pertama</em>, faktor bakat dan minat. <em>Kedua</em>, faktor usia: <em>Ketiga</em>, faktor kecerdasan. <em>Keempat</em>, faktor hati yang bersih dan khusyu</p>
Synthesis and Characterization of New Oxazepines Compounds Derived From D- Galactose
Authors: Rasmia M. Rumez  
Published: January 2023

New Schiff bases derived from D-galactose were synthesized by condensation of aldehyde (1,2:3,4-Di-O-isopropylidene-6-carboxaldehyde-α-D-galactopyranose) with different aromatic amines such as (4-bromo, 3-hydroxy, 4-iodo, 4-methoxy) aniline in dry benzene using glacial acetic acid as a catalyst. These compounds were converted to oxazepine derivatives by addition
reaction with maleic anhydride in dry benzene as a solvent. The structures of the synthesized compounds have been characterized by elemental analysis, FTIR spectra, some of them by using 1HNMR spectra and measurement of its physical properties.
(E)-2-((1,7,7-Trimethylbicyclo [2.2.1]Heptan-2-Ylidene) Amino) Acetic Acid Compound and their Metal Complexes: Synthesis and Characterization
Authors: Nuha H. Al-Saadawy  , Ziad S. Fadhel  
Published: January 2023

The reaction of camphor with glycine under the showing conditions yielded (E)-2-((1,7,7-trimethylbicyclo[2.2.1]heptan-2-ylidene)amino)acetic acid ligand . The complexes of Cu(II), Ni(II), Co(II), Zn(II) and Fe(II) with ligand have been obtained by the reaction between copper bromide, hydrate nickel chloride, hydrate cobalt chloride, zinc chloride, and iron bromide with ligand in 1:2 mole ratio. The free ligands and their metal complexes have been separated in the solid state. The spectroscopic data of the complexes recommend their 1:2 structures which are researched by elemental analysis (CHN) 1H NMR and FT-IR spectroscopy. From the spectroscopic data proposed the octahedral structure for the all complexes.
THE DESCRIPTION OF IRON LEVELS OF WATER AT INDUSTRIAL HOUSING IN BATURAJA, OGAN KOMERING ULU
Authors: Khoiriah Nasihatul , Mutholib Abdul 
Published: January 2023

Background: In everyday life, humans are very dependent on water and the quality of health is also very much determined by the quality of water used for daily needs. The presence of chemicals substances or contaminants in water (for examples Fe) that exceed the acceptable levels of standard can risk human health. It can cause failure in metabolism (hemochromatosis). Based on the Ministry of Health dictire No.32 year 2017 maximum level of iron allowed in water is 1.0 mg/l. The aim of this descriptive research was to determine the level of Iron in industrial housing water in Baturaja, Ogan Komering Ulu. Methode: The total samples were 15 home water taken by sistematic random sampling. The iron content was measured by Atomic Absorption Spectrophotometry (AAS) method. The results: showed all the samples were qualified with mean level 0.105227 mg/l, median 0,106000 mg/l, standar deviation 0,0175790 mg/l, the lowest level was 0.0789 mg /l and the highest level was 0.1345 mg/l. all watern samples (100%) met the requirements <1 mg/l and no samples did not meet the requirements >1 mg/l. 14 samples (93.3%) of iron levels in water based on acidity were not qualified <6.5 or> 9 and 1 sample (6.3%) of iron levels in water were qualified = 6.5-9. 15 samples (100%) of water content through distances that meet the requirements. The minimum level of iron is 0.0830 mg /l at a distance of 1- 50 meters and The maximum level of iron 0.1345 mg / l at a distance of 1-50 meters and 1-50 meters. Conclusion: The average level of Fe in Industrial Residential Water in Baturaja, Ogan Komering Ulu Regency, meets the quality requirements of environmental health quality standards for water media for sanitation hygiene purposes.
SERA POOLED STABILITY AS A SGPT CONTROL MATERIAL WITH STORAGE TIME AND TEMPERATURE VARIATION
Authors: Lestari Wuni Sri , Karwiti Witi , Latifah Aminahtun , Listiani Yenni , Harianja Sri Hartini 
Published: January 2023

To improve the quality of laboratory examination results, it is absolutely necessary to carry out quality assurance and these activities usually require control materials. The price of expensive commercial control materials is an obstacle to carrying out laboratory quality control. Efforts to maintain quality control are using pooled sera as control material. One of the examinations that is often done is the examination of SGPT (Serum Glutamic Pyruvate Transaminase) blood. The choice of SGPT parameter is expected to represent the type of enzyme assay. The purpose of this study was to determine the stability of pooled sera used as control material for SGPT examination with time and temperature variations. Methods: This research is an experimental study, which was carried out using a collection of serum found in the TLM Clinical Chemistry Laboratory of the Health Ministry of Health, Jambi. By using 2 treatments, the samples were stored at a temperature of 20-25oC and -5oC. Data analysis using ANOVA and coefficient of variation value. Results: The results showed a significant value (p-value) of SGPT of p = 0.008. A significant value (p-value) which is greater than the value of = 0.05, indicates that there is an effect of storage time and temperature variations. Conclusion : There is a significant effect of storage time and temperature variation of pooled sera control material on the stability of SGPT examination.
HUBUNGAN KEJADIAN KECACINGAN STH DENGAN PERSONAL HYGIENE PADA PENAMBANG PASIR DI CEMPAKA KOTA BANJARBARU
Authors: - Zahratannujhah , Rifqoh Rifqoh , Muhlisin Ahmad , Roebiakto Erfan 
Published: January 2023

Latar Belakang: Infeksi kecacingan merupakan salah satu infeksi yang masih menjadi masalah kesehatan di indonesia, salah satunya infeksi kecacingan Soil Transmitted Helminths. Pekerja yang beresiko terinfeksi adalah pekerja yang sehari-hari kontak langsung dengan tanah seperti penambang pasir dengan faktor Sanitasi lingkungan dan personal hygiene yang buruk. Penelitian ini bertujuan untuk mengetahui adanya hubungan kejadian kecacingan STH dengan personal hygiene pada penambang pasir di Cempaka kota Banjarbaru. Metode: metode penelitian ini adalah survey analitik dengan rancangan cross sectional, jumlah populasi dan sampel sebanyak 21 orang menggunakan teknik total sampling. Dengan memberikan kuesioner dan pemeriksaan telur cacing menggunakan metode kato katz. Hasil: Ditemukan sebanyak 14 orang (66,7%) negatif kecacingan STH dan 7 orang (33,3%) positif kecacingan STH, dengan EPG spesies cacing tambang sebanyak (96-192/gr feses) dan EPG Ascaris lumbricoides (24-48/gr feses). Responden dengan personal hygiene kurang baik sebanyak 13 orang (61,9%) dan baik sebanyak 8 orang (38,1%). Responden yang memiliki personal hygiene kurang baik sebanyak 7 orang (33,3%) positif kecacingan STH. Kesimpulan: ada hubungan antara personal hygiene dengan kecacingan STH berdasarkan analisa uji Fisher’s Exact dengan nilai p-value<α (0,018<0,05).
Educação para a Competência em Informação e a Formação de Multiplicadores no contexto da Educação Profissional e Tecnológica
Authors: Silva Carlos Robson Souza da , Cavalcante Luciane de Fátima Beckman , Alcará Adriana Rosecler 
Published: January 2023

Tem como objetivos discutir o conceito de Competência em Informação na Educação Profissional e Tecnológica, refletir sobre o papel educativo dos multiplicadores de Competência em Informação e apontar para a possibilidade de uma formação de multiplicadores pensada a partir de um modelo de Competência em Informação na Educação Profissional e Tecnológica. Trata-se de revisão de literatura, da qual foram selecionados autores que oferecessem argumentos teóricos para alcançar os objetivos propostos. Conceitua Competência em Informação na Educação Profissional e Tecnológica e Multiplicadores de Competência em Informação. Apresenta o Modelo de Competência em Informação na Educação Profissional e Tecnológica de Silva (2021) e discute a possibilidade de seu uso na formação de multiplicadores. Encerra apontando para o fato de que o processo de formação continuada facilita aos profissionais da informação a implementação de ações de Competência em Informação ao mesmo tempo em que compreendem e apreendem a história, a filosofia e as dinâmicas próprias da Educação Profissional.
Tem como objetivos discutir o conceito de Competência em Informação na Educação Profissional e Tecnológica, refletir sobre o papel educativo dos multiplicadores de Competência em Informação e apontar para a possibilidade de uma formação de multiplicadores pensada a partir de um modelo de Competência em Informação na Educação Profissional e Tecnológica. Trata-se de revisão de literatura, da qual foram selecionados autores que oferecessem argumentos teóricos para alcançar os objetivos propostos. Conceitua Competência em Informação na Educação Profissional e Tecnológica e Multiplicadores de Competência em Informação. Apresenta o Modelo de Competência em Informação na Educação Profissional e Tecnológica de Silva (2021) e discute a possibilidade de seu uso na formação de multiplicadores. Encerra apontando para o fato de que o processo de formação continuada facilita aos profissionais da informação a implementação de ações de Competência em Informação ao mesmo tempo em que compreendem e apreendem a história, a filosofia e as dinâmicas próprias da Educação Profissional.
Upaya Meningkatkan Aktivitas dan Hasil Belajar Matematika Siswa Melalui Penerapan Penilaian Portofolio pada Kelas VII SMPN 2 Simpang Jernih Tahun Pelajaran 2019/2020
Authors: Suliani  
Published: January 2023

Penelitian Tindakan Kelas ini bertujuan untuk mengetahui peningkatkan aktivitas dan hasil belajar matematika siswa kelas VII SMPN 2 Simpang Jernih melalui penenerapan penilaian portofolio. Penelitian ini terdiri dari dua siklus. Setiap siklus terdiri dari empat tahap yaitu perencanaan, pelaksanaan tindakan, observasi, dan refleksi. Subyek dalam penelitian ini adalah siswa kelas VII SMPN 2 Simpang Jernih yang berjumlah 20 siswa. Teknik pengumpulan data menggunakan observasi, portofolio, dan tes. Data dianalisis secara deskriptif kuantitatif dan kualitatif. Hasil penelitian menunjukkan adanya peningkatan persentase aktivitas dan hasil belajar siswa, hal ini dapat dilihat dari ketuntasan KKM siswa dari kegiatan pratindakan dan setiap siklus, yaitu pada pratindakan aktivitas siswa sebesar 50%, pada siklus I sebesar 78%, sedangkan pada siklus II sebesar 87%. Hal tersebut diiringi dengan peningkatan rata-rata hasil belajar siswa dari pratindakan sebesar 44,83%, siklus I sebesar 60%, sedangkan pada siklus II sebesar 80%. Dengan demikian dapat disimpulkan bahwa penerapan penilaian Portofolio dapat meningkatkan hasil belajar siswa kelas VII SMPN 2 Simpang Jernih.
Peningkatan Aktivitas Siswa Melalui Model Pembelajaran Type Numbered Heads Together Pada Materi Pokok Lingkaran Di Kelas Xi-Mia-1 SMA Negeri 1 Sei Kanan
Authors: Pulungan Nora Esteriah 
Published: January 2023

Penelitian ini bertujuan untuk melihat hasil belajar siswa antara lain hasil belajar siswa, keterampilan, psikomotorik siswa, dan aktivitas siswa saat bekerja dalam kelompok dikelas ada pada mata pelajaran matematika dengan model pembelajaran kooperatif type numbered heads together dikelas XI-MIA 1 SMA Negeri 1 Sei Kanan.Subjek penelitian ini diambil dikelas dengan jumlah siswa 32 orang. Awal kegiatan belajar mengajar dilakukan test hasil belajar atau pretest, dengan data rata-rata 42,7 hal tersebut menunjukkan bahwa rata-rata siswa jarang membaca buku sebelum pembelajaran disekolah. Kemudian dilanjutkan kegiatan belajar mengajar, akhir kegiatan belajar mengajar kedua dan kegiatan belajar mengajar IV dilakukan test hasil belajar post test 1 dan post test 2 hasil dari masing-masing menunjukkan 74,2 dan 86,3. Data aktivitas siswa menurut pengamatan pada siklus 1 antara lain membaca 42% bekerja 26%, pertanyaan sesame teman 12%, pertanyaan kepada guru 11% dan yang tidak relevan dalam kegiatan belajar mengajar 9%. Data aktivitas siswa menurut pengamatan pada siklus 2 antara lain membaca 20%, bekerja 40%, bertanya sesama teman 18%, pertanyaan kepada guru 18%, dan yang tidak relevan dengan kegiatan belajar mengajar 4%. Sikap konstruktif siswa setelah menerapkan model pembelajaran kooperatif type NHT: sikap senang terhadap pelajaran matematika 89,4 : sikap ingin tahu siswa terhadap pelajaran matematika 87,4: sikap ingin membantu yang kesulitan belajar matematika 91,5. Ini merupakan efek dari model pembelajaran kooperatif type numbered head together yang cukup menumbuhkan sikap ingin tahu dan minat terhadap pelajaran.
Assessement of nuvan toxicity to lipids in snake headed fresh water fish Channa punctatus
Authors: Rani Rekha , Gautam R.K. 
Published: January 2023

The healthy functioning of the biosphere in our planet, the life depends entirely on the water flow and steady state phenomenon. Lethal concentration of Nuvan calculated for the fresh water snake headed fish Channa punctatus 0.27ml/L after 24, 48, 72 and 96 hours. For the chronic study 1/10th Nuvan concentration (0.027ml/L) provided to observe fish. Blood serum cholesterol (Chol.) and triglycerides (TG) estimated after chronic toxic stress of Nuvan to fish Channa punctatus. Fish serum TG revealed significant decrease level while Cholesterol showed significant elevated level after 7, 14, 21, and 28days at different level p > 0.05, p <0.01 and p <0.001 in fresh water fish Channa punctatus.