bluuebunny/crossref_metadata_2025_split huggingface dataset:
Biotinylated Fluorescent Polymeric Nanoparticles for Enhanced Immunostaining
Authors: Yudhistira Tesla , Da Silva Elisabete Cruz , Combes Antoine , Lehmann Maxime , Reisch Andreas , Klymchenko Andrey S. 
Published: February 2023

AbstractThe performance of fluorescence immunostaining is physically limited by the brightness of organic dyes, whereas fluorescence labeling with multiple dyes per antibody can lead to dye self‐quenching. The present work reports a methodology of antibody labeling by biotinylated zwitterionic dye‐loaded polymeric nanoparticles (NPs). A rationally designed hydrophobic polymer, poly(ethyl methacrylate) bearing charged, zwitterionic and biotin groups (PEMA‐ZI‐biotin), enables preparation of small (14 nm) and bright fluorescent biotinylated NPs loaded with large quantities of cationic rhodamine dye with bulky hydrophobic counterion (fluorinated tetraphenylborate). The biotin exposure at the particle surface is confirmed by Förster resonance energy transfer with dye‐streptavidin conjugate. Single‐particle microscopy validates specific binding to biotinylated surfaces, with particle brightness 21‐fold higher than quantum dot‐585 (QD‐585) at 550 nm excitation. The nanoimmunostaining method, which couples biotinylated antibody (cetuximab) with bright biotinylated zwitterionic NPs through streptavidin, significantly improves fluorescence imaging of target epidermal growth factor receptors (EGFR) on the cell surface compared to a dye‐based labeling. Importantly, cetuximab labeled with PEMA‐ZI‐biotin NPs can differentiate cells with distinct expression levels of EGFR cancer marker. The developed nanoprobes can greatly amplify the signal from labeled antibodies, and thus become a useful tool in the high‐sensitivity detection of disease biomarkers.
Applications of X‐Ray‐Based Characterization in MXene Research
Authors: Zhang Jizhen , Usman Ken Aldren S. , Judicpa Mia Angela N. , Hegh Dylan , Lynch Peter A. , Razal Joselito M. 
Published: February 2023

AbstractX‐rays are a penetrating form of high‐energy electromagnetic radiation with wavelengths ranging from 10 pm to 10 nm. Similar to visible light, X‐rays provide a powerful tool to study the atoms and elemental information of objects. Different characterization methods based on X‐rays are established, such as X‐ray diffraction, small‐ and wide‐angle X‐ray scattering, and X‐ray‐based spectroscopies, to explore the structural and elemental information of varied materials including low‐dimensional nanomaterials. This review summarizes the recent progress of using X‐ray related characterization methods in MXenes, a new family of 2D nanomaterials. These methods provide key information on the nanomaterials, covering synthesis, elemental composition, and the assembly of MXene sheets and their composites. Additionally, new characterization methods are proposed as future research directions in the outlook section to enhance understanding of MXene surface and chemical properties. This review is expected to provide a guideline for characterization method selection and aid in precise interpretation of the experimental data in MXene research.
Enhancing the Chemical Stability of MXene Through Synergy of Hydrogen Bond and Coordination Bond in Aqueous Solution
Authors: Wang Xiao‐Yun , Liao Si‐Yuan , Huang Hai‐Peng , Wang Qiao‐Feng , Shi Yu‐Ying , Zhu Peng‐Li , Hu You‐Gen , Sun Rong , Wan Yan‐Jun 
Published: February 2023

AbstractMXenes with unique physicochemical properties have shown substantial potential in electromagnetic interference (EMI) shielding. However, the chemical instability and mechanical fragility of MXenes has become a major hurdle for their application. Abundant strategies have been dedicated to improving the oxidation stability of colloidal solution or mechanical properties of films, which always come at the expense of electrical conductivity and chemical compatibility. Here, hydrogen bond (H‐bond) and coordination bond are employed to achieve chemical and colloidal stability of MXenes (0.1 mg mL−1) by occupying the reaction sites of Ti3C2Tx attacking of water and oxygen molecules. Compared to the Ti3C2Tx, the Ti3C2Tx modified with alanine via H‐bond shows significantly improved oxidation stability (at room temperature over 35 days), while the Ti3C2Tx modified with cysteine by synergy of H‐bond and coordination bond can be maintained even after 120 days. Simulation and experimental results verify the formation of H‐bond and Ti‐S bond by a Lewis acid‐base interaction between Ti3C2Tx and cysteine. Furthermore, the synergy strategy significantly improves the mechanical strength of the assembled film (up to 78.1 ± 7.9 MPa), corresponding the increment of 203% compared to untreated one, almost without compromising the electrical conductivity and EMI shielding performance.
Unraveling the Steric Link to Copper Precursor Decomposition: A Multi‐Faceted Study for the Printing of Flexible Electronics
Authors: Mrig Shreya , Bhide Malavika A. , Zhou Ye , Stanton Nils , Wang Jingyan , Douglas Samuel P. , Tinker Henry R. , Mears Kristian L. , Bakewell Clare M. , Knapp Caroline E. 
Published: February 2023

AbstractThe field of printed electronics strives for lower processing temperatures to move toward flexible substrates that have vast potential: from wearable medical devices to animal tagging. Typically, ink formulations are optimized using mass screening and elimination of failures; as such, there are no comprehensive studies on the fundamental chemistry at play. Herein, findings which describe the steric link to decomposition profile: combining density functional theory, crystallography, thermal decomposition, mass spectrometry, and inkjet printing, are reported. Through the reaction of copper(II) formate with excess alkanolamines of varying steric bulk, tris‐co‐ordinated copper precursor ions: “[CuL3],” each with a formate counter‐ion (1–3) are isolated and their thermal decomposition mass spectrometry profiles are collected to assess their suitability for use in inks (I1–3). Spin coating and inkjet printing of I1,2 provides an easily up‐scalable method toward the deposition of highly conductive copper device interconnects (ρ = 4.7–5.3 × 10−7 Ω m; ≈30% bulk) onto paper and polyimide substrates and forms functioning circuits that can power light‐emitting diodes. The connection among ligand bulk, coordination number, and improved decomposition profile supports fundamental understanding which will direct future design.
Patterns of endocardial fibroelastosis without atrioventricular block in fetuses exposed to anti‐Ro/SSA antibodies
Authors: Keller S. B. , Cohen J. , Moon‐Grady A. , Cuneo B. , Paul E. , Coll A. C. , Campbell M. , Srivastava S. 
Published: February 2023

ABSTRACTAnti‐Ro/SSA‐antibody‐mediated endocardial fibroelastosis (EFE) without atrioventricular (AV) block at presentation is a rare cardiac phenotype. We report on 11 fetuses with this rare type of anti‐Ro/SSA‐antibody‐mediated cardiac involvement, presenting with a distinctive echocardiographic pattern of EFE. Eleven fetuses with isolated EFE at presentation were included from four cardiac centers, and experienced fetal cardiologists reached a consensus regarding EFE location on echocardiography at presentation. Interval changes to subsequent fetal and postnatal echocardiograms were assessed to evaluate response to therapy. Echocardiographic markers of cardiac performance, including diastolic function and AV conduction, were reviewed. Ten fetuses were found to have EFE of the aortic root, proximal aorta and/or left ventricular outflow tract. In the same 10 cases, EFE of the pulmonary root, pulmonary artery and/or right ventricular outflow tract was identified. Six cases had atrial EFE and six had EFE of the crux. Four cases were known to be positive for anti‐Ro/SSA antibodies prior to diagnosis, whereas, in the remaining seven, echocardiographic findings prompted testing, which was positive in all cases. The AV interval at presentation was normal in all cases, but one fetus subsequently developed AV block. Nine patients were treated with transplacental dexamethasone, five of which also received intravenous immunoglobulin (IVIG), and one received IVIG only. Of the 10 treated cases, six had improvement in EFE as shown by serial imaging and, in four cases, the severity was unchanged. All patients were liveborn. In our cohort, EFE of the aortic and pulmonary arteries and outflow tracts was nearly universal, and involvement of the atria and the crux of the heart was also common. The high survival rate and low burden of AV block are also suggestive of a distinct phenotype of anti‐Ro/SSA‐antibody‐mediated cardiac disease with a favorable prognosis. © 2023 International Society of Ultrasound in Obstetrics and Gynecology.
Management control systems and innovation: a case study grounded in institutional theory
Authors: Barros Rúben Silva , Ferreira Ana Maria Dias Simões da Costa 
Published: February 2023

AbstractDrawing on the growing literature that has addressed the role of Management Control Systems in innovation and the literature on institutional theory, this study explores the case of Amorim Cork Composites to analyse how the situated rationalities within the company get reflected in the management control practices in use, and then how these practices are used to communicate and provide guidance when innovation is part of the strategy. The study uses a single case study approach at an innovative company, collecting data from 32 interviews, direct observations, and documentation of the company. Based on that data, this study is able to perceive the existence of a rationality that is constructed around the importance of innovation, which becomes a paramount part of the defined strategy and leaves signs on to the internal control practices of the company. After that, through a mix of strategic objectives, well-defined cascaded process of these objectives, values, mottos, objectives related to that situated rationality within the company, and with the commitment created within the “signing” of objectives contracts, managers are able to communicate strategically and provide guidance to the collaborators, driving them to action that makes them more aware.
Food and social media: a research stream analysis
Authors: García-León Ruth Areli , Teichert Thorsten 
Published: February 2023

AbstractInterest in food and online communication is growing fast among marketing and business scholars. Nevertheless, this interest has been not exclusive to these areas. Researchers from different disciplines have focused their research on different concepts, target populations, approaches, methodologies, and theoretical backgrounds, making this growing body of knowledge richer, but at the same time difficult to analyze. In order to have a broader overview of this topic, this study analyzes the existent literature regarding food and social media in social sciences in order to identify the main research streams and themes explored. With this purpose, the present paper uses bibliometric methods to analyze 1356 journal articles by means of factor and social network analysis. The study contributes by revealing 4 clusters containing 11 dominant research streams within the social sciences, determining the linkages among the main research discourses, and recommending new future topics of research.
Creating a consumer-driven global community of practice to support action within environmental design with people living with dementia: assistive technology challenges and opportunities
Authors: Ong Emily , Frost Dennis , Kuliga Saskia , Layton Natasha , Liddle Jacki 
Published: February 2023

AbstractThe environment, and assistive technologies as part of this, can play an important role in supporting the participation and wellbeing of people living with dementia. If not considered, environments can be overwhelming and disempowering. Disability approaches including environmental considerations and assistive technology were often not offered routinely with people living with dementia. Concerned by this, dementia advocates aimed to create change in this area. The Environmental Design-Special Interest Group (ED-SiG) of Dementia Alliance International was developed as an international consumer-driven community of practice bringing together people with different relevant expertise including living experience (people living with dementia, care partners), architecture and design, occupational therapy, rehabilitation and care provision. This practice opinion piece provides an overview of dementia, the need for collaborative practices within practice with people living with dementia, and the considerations of assistive technology, environmental design and the global context. The reflection provides insights into this international community of practice, with personal reflections of members with living experience of dementia, and benefits and opportunities in considering environmental design and assistive technology from the perspectives of members. This work demonstrates and advocates collaborations that centre the perspectives and expertise of people living with dementia.
Multibeam laser–plasma interaction at the Gekko XII laser facility in conditions relevant for direct-drive inertial confinement fusion
Authors: Cristoforetti G. , Koester P. , Atzeni S. , Batani D. , Fujioka S. , Hironaka Y. , Hüller S. , Idesaka T. , Katagiri K. , Kawasaki K. , Kodama R. , Mancelli D. , Nicolai Ph. , Ozaki N. , Schiavi A. , Shigemori K. , Takizawa R. , Tamagawa T. , Tanaka D. , Tentori A. , Umeda Y. , Yogo A. , Gizzi L. A. 
Published: February 2023

Abstract
Laser–plasma interaction and hot electrons have been characterized in detail in laser irradiation conditions relevant for direct-drive inertial confinement fusion. The experiment was carried out at the Gekko XII laser facility in multibeam planar target geometry at an intensity of approximately

$3\times {10}^{15}$

W/cm2. Experimental data suggest that high-energy electrons, with temperatures of 20–50 keV and conversion efficiencies of

$\eta <1\%$

, were mainly produced by the damping of electron plasma waves driven by two-plasmon decay (TPD). Stimulated Raman scattering (SRS) is observed in a near-threshold growth regime, producing a reflectivity of approximately

$0.01\%$

, and is well described by an analytical model accounting for the convective growth in independent speckles. The experiment reveals that both TPD and SRS are collectively driven by multiple beams, resulting in a more vigorous growth than that driven by single-beam laser intensity.
Prevalence of vitamin D deficiency in patients with spinal cord injury at admission: a single-centred study in the UK
Authors: Wong Samford , Dong Honglin , Hirani Shashivadan P. , Gainullina Irina , Ussef Ibrahim , Graham Allison 
Published: February 2023

Abstract
Vitamin D deficiency is prevalent in patients with chronic spinal cord injury (SCI) and has been implicated as an aetiologic factor of osteoporosis and various skeletal and extra-skeletal issues in SCI patients. Few data were available regarding vitamin D status in patients with acute SCI or immediately assessed at hospital admission. This retrospective cross-sectional study evaluated vitamin D status in SCI patients at admission to a UK SCI centre in January–December 2017. A total of 196 eligible patients with serum 25(OH)D concentration records at admission were recruited. The results found that 24 % were vitamin D deficient (serum 25(OH)D < 25 nmol/l), 57 % of the patients had serum 25(OH)D < 50 nmol/l. The male patients, patients admitted in the winter–spring time (December–May), and patients with serum sodium < 135 mmol/l or with non-traumatic causes had a significant higher prevalence of vitamin D deficiency than their counterparts (28 % males v. 11⋅8 % females, P = 0⋅02; 30⋅2 % in winter–spring v. 12⋅9 % in summer–autumn, P = 0⋅007; 32⋅1 % non-traumatic v. 17⋅6 % traumatic SCI, P = 0⋅03; 38⋅9 % low serum sodium v. 18⋅8 % normal serum sodium, P = 0⋅010). There was a significant inverse association of serum 25(OH)D concentration with body mass index (BMI) (r = −0⋅311, P = 0⋅002), serum total cholesterol (r = −0⋅168, P = 0⋅04) and creatinine concentrations (r = −0⋅162, P = 0⋅02) that were also significant predictors of serum 25(OH)D concentration. Strategies for systematic screening and efficacy of vitamin D supplementation in SCI patients need to be implemented and further investigated to prevent the vitamin D deficiency-related chronic complications.
INTUITIONISTIC SAHLQVIST THEORY FOR DEDUCTIVE SYSTEMS
Authors: FORNASIERE DAMIANO , MORASCHINI TOMMASO 
Published: February 2023

AbstractSahlqvist theory is extended to the fragments of the intuitionistic propositional calculus that include the conjunction connective. This allows us to introduce a Sahlqvist theory of intuitionistic character amenable to arbitrary protoalgebraic deductive systems. As an application, we obtain a Sahlqvist theorem for the fragments of the intuitionistic propositional calculus that include the implication connective and for the extensions of the intuitionistic linear logic.
The Many Faces of Slavery
Authors: Marquez John C. 
Published: February 2023

This essay reviews the following works:The Trade in the Living: The Formation of Brazil in the South Atlantic, Sixteenth to Seventeenth Centuries. By Luiz Felipe de Alencastro. Translated by Gavin Adams and Luiz Felipe de Alencastro; revised by Michael Wolfers and Dale Tomich. Albany: SUNY Press, 2018. Pp. xx + 606. $95.00 hardcover. ISBN: 9781438469294.Freedom’s Captives: Slavery and Gradual Emancipation on the Colombian Black Pacific. By Yesenia Barragan. Cambridge: Cambridge University Press, 2021. Pp. xviii + 326. $99.99 hardcover. ISBN: 9781108832328.From the Galleons to the Highlands: Slave Trade Routes in the Spanish Americas. Edited by Alex Borucki, David Eltis, and David Wheat. Albuquerque: University of New Mexico Press, 2020. Pp. x + 350. $34.95 paperback. ISBN: 9780826361165.Una historia de la emancipación negra: Esclavitud y abolición en la Argentina. By Magdalena Candioti. Buenos Aires: Siglo Veintiuno Editores, 2021. Pp. 272. Arg$3,892.00 paperback. ISBN: 9789878011134.Hiding in Plain Sight: Black Women, the Law, and the Making of a White Argentine Republic. By Erika Denise Edwards. Tuscaloosa: University Alabama Press, 2020. Pp. xvi + 168. $29.95 paperback. ISBN: 9780817360313.Afro-Catholic Festivals in the Americas: Performance, Representation, and the Making of Black Atlantic Tradition. Edited by Cécile Fromont. University Park: Pennsylvania State University Press, 2019. Pp. 224. $29.95 paperback. ISBN: 9780271083308.Constructing the Spanish Empire in Havana: State Slavery in Defense and Development, 1762–1835. By Evelyn P. Jennings. Baton Rouge: Louisiana State University Press, 2020. Pp. xiv + 283. $45.00 hardcover. ISBN: 9780807173947.Africanos livres: A abolição do tráfico de escravos para o Brasil. By Beatriz G. Mamigonian. São Paulo: Companhia das Letras, 2017. Pp. 625. R$74.90 paperback. ISBN: 9788535929331.The Story of Rufino: Slavery, Freedom, and Islam in the Black Atlantic. By João José Reis, Flávio dos Santos Gomes, and Marcus J. M. de Carvalho. Translated by H. Sabrina Gledhill. New York: Oxford University Press, 2020. Pp. ix + 307. ISBN: 9780190224363.Captives of Conquest: Slavery in the Early Modern Spanish Caribbean. By Erin Woodruff Stone. Philadelphia: University of Pennsylvania Press, 2021. Pp. 235. $49.95 hardcover. ISBN: 9780812253108.
Association between legume consumption and the intake of other foods and nutrients in the Finnish adult population
Authors: Gholami Karim Abad Atiyeh , Kinnunen Tarja I. , Maukonen Mirkka , Koivisto Anna-Maija , Männistö Satu , Kaartinen Niina E. 
Published: February 2023

AbstractThe role of legumes in healthy and sustainable diets is increasingly of interest. Few studies have investigated the association between legume consumption and the consumption of other food groups and the intake of nutrients. This study examined how legume consumption is associated with the consumption of other foods and the intake of nutrients among Finnish adults. Our study used cross-sectional data from the population-based FinHealth 2017 Study consisting of 2250 men and 2875 women aged ≥18 years. The associations between legume consumption (quartile classification), food groups and nutrients were analysed using multivariable linear regression. The models were initially adjusted for energy intake and additionally for age, educational level, smoking status, leisure-time physical activity and BMI. Legume consumption had a positive association with age, education level and leisure-time physical activity. The consumption of legumes was positively associated with the consumption of fruits and berries, vegetables, nuts and seeds and fish and fish products and inversely associated with the consumption of red and processed meat, cereals and butter and butter-based fat spreads. Furthermore, legume consumption was positively associated with the intake of protein, fibre, folate, thiamine and salt in both sexes and inversely associated with the intake of saturated fatty acids and sucrose (sucrose, women only). Thus, legume consumption appears to reflect overall healthier food choices. An increase in legume consumption could accelerate the transition to more sustainable diets. The confounding role of other foods and nutrients should be considered when studying associations between legume consumption and health outcomes.
Oceanic resurge deposits at the Rochechouart impact structure (France) suggest a marine target environment
Authors: Ormö Jens , Sturkell Erik , Lambert Philippe , Bourquin Sylvie , Cherfils Jean-Baptiste 
Published: February 2023

AbstractThe Rochechouart impact structure, located in the western part of the Massif Central in France, has been suggested to be one of the largest impact structures in western Europe. Various age datings have placed the event in a span from the Late Triassic to the Early Jurassic, but the most recent works favour a Late Triassic age. Very little is known about the target environment at the time and location of the impact event. Seemingly coeval, potential tsunamites along palaeoshorelines of the sea that covered parts of continental Europe at the time have been suggested to be related to the impact event and may indicate a marine target setting. Here we apply the method of visual line-logging of the graded suevite in the Chassenon SC2 drill core. This method has previously been used to investigate the depositional environment of similar deposits in several marine target impact craters. It allowed us to compare the deposits at these craters with those at Rochechouart, and in this way not only confirm the marine target setting, but also estimate the target water depth to be ∼200 m. Altogether, our results indicate a palaeogeographic target setting in a newly opened seaway connecting the Paris Basin with the Aquitaine Basin, which may indicate an age of impact at the younger end of the hitherto suggested age-span, i.e. in the late Rhaetian – Early Jurassic.
Double Machine Learning: Explaining the Post-Earnings Announcement Drift
Authors: Hansen Jacob H. , Siggaard Mathias V. 
Published: February 2023

AbstractWe demonstrate the benefits of merging traditional hypothesis-driven research with new methods from machine learning that enable high-dimensional inference. Because the literature on post-earnings announcement drift (PEAD) is characterized by a “zoo” of explanations, limited academic consensus on model design, and reliance on massive data, it will serve as a leading example to demonstrate the challenges of high-dimensional analysis. We identify a small set of variables associated with momentum, liquidity, and limited arbitrage that explain PEAD directly and consistently, and the framework can be applied broadly in finance.