bluuebunny/crossref_metadata_2025_split huggingface dataset:
Work Life Balance: Studi Empiris Keterlibatan Anggota, Iklim Organisasi, Kepuasan Kerja Anggota Organisasi di Polda Metro Jaya
Authors: Balqis Sasya Aisha , Setyabudi Chairul Muriman , Dharma Surya 
Published: July 2023

Tulisan ini mengkaji mengenai pengaruh keterlibatan anggota, iklim organisasi dan kepuasan kerja terhadap keseimbangan kehidupan kerja (work life balance) anggota organisasi di Polda Metro Jaya. Dalam perspektif manajemen sumber daya manusia, fenomena keseimbangan kehidupan kerja (work life balance) merupakan faktor penting karena dapat mempengaruhi kinerja dan produktivitas individu dan organisasi. Work life balance merupakan kondisi dimana individu dapat menyeimbangkan tanggungjawab pekerjaan dengan keluarga yang dipengaruhi oleh sejumlah faktor. Dengan demikian, dalam tulisan ini penekanan keseimbangan terletak pada kemampuan individu untuk memenuhi tuntutan peran yang dikarenakan oleh kehidupan kerja dan kehidupan keluarga. Tulisan ini dianalisis dengan menggunakan Teori Keseimbangan Kehidupan Kerja dengan melihat variabel keterlibatan anggota, iklim organisasi, dan kepuasan kerja. Tulisan ini memfokuskan kepada fenomena work life balance anggota polisi yang bekerja pada fungsi-fungsi operasional di Polda Metro Jaya seperti Ditreskrim, Direktorat Inteligen, Direktorat Lalu lintas, Direktorat Binmas Dan Direktorat Shabara. Tulisan ini menemukan bahwa keseimbangan kehidupan kerja telah terbukti mempengaruhi individu dan organisasi. Tulisan ini menyimpulkan bahwa keterlibatan anggota, iklim organisasi dan kepuasan kerja di Polda Metro Jaya berpengaruh terhadap keseimbangan kehidupan kerja para anggotanya.

Kata kunci: Keseimbangan Kehidupan Kerja, Polda Metro Jaya, Iklim Organisasi, Kepuasan Kerja
Taksir Istikhdam al Toriqoh al Istiqroiyah 'Ala Qudroh al Tollibat Fi Ta'lim Qowa'id An Nahw
Authors: Anisya Abdillah Nada , Ramadona Syahri 
Published: July 2023

الهدف من هذا البحث هو معرفة تأثير استخدام الطريقة الاستقرائية على قدرة الطالبات في تعليم قواعد النحو في الصف الثامن بمدرسة عثمان بن عفان المتوسطة الإسلامية والمنهج المستخدم هو المنهج الكمي بالنوع التجريبي (One Group Pretest Posttest Design) ولجمع البيانات المستخدمة الملاحظة والمقابلة والاختبار. أما تحليل البيانات بالتحليل الإحصائي بالرمز (Test-t). ونتيجة البحث وجود تأثير الطريقة الاستقرائية تؤثر على قدرة الطالبات في تعليم قواعد النحو في الصف الثامن بمدرسة عثمان بن عفان المتوسطة الإسلامية بالدليل نتيجة الاختبار-ت 3,07 - أكبر من نتيجة tt.. فالفرضية التبادلية (Ha) مقبولة والفرضية العدمية (H0) مردودة. والخلاصة وجود تأثير على قدرة الطالبات في تعليم قواعد النحو. هذه الطريقة المناسبة لمرحلة متوسطة.
АВТОКӨЛІК КӘСІПОРЫНДАРЫНЫҢ КӨЛІКТІК-ЛОГИСТИКАЛЫҚ ҚЫЗМЕТ КӨРСЕТУ ЖҰМЫСТАРЫН САПАЛЫҚ ТҰРҒЫДА БАСҚАРУ КӨРСЕТКІШТЕРІН АНЫҚТАУ
Authors: Тойлыбаев Асылбек , Пернебеков Сакен , Әділбек Аяжан , Кумек Камшат , Аскер Бакдаулет 
Published: July 2023

Мақалада көліктік-логистиқалық қызмет көрсету саласындағы негізгі проблемалар мен мәселелер жеткізілім тізбегіндегі барлық іс-әрекеттерді сапалы түрде басқару тұрғысынан қарастырылған. Заманауи талаптарға жауап бере алатын көліктік-логистиқалық қызмет көрсету саласындағы оң өзгерістер, бірінші кезекте, көліктік қызметті тұтынушылармен қатар компаниялардың да пайда алу мүмкіндігіне бағытталған арнайы көрсеткіштер жүйесін қалыптастыруға тікелей байланысты екендігі анықталды. Басты назар әртүрлі тұтынушыларға көліктік-логистиқалық қызмет көрсетуші көліктік компаниялардың қызметтерін сапалы басқарудың көрсеткіштері мен мәнбірлеріне аударылған. Көліктік-логистиқалық қызмет көрсету жұмыстарын сапалы басқарудың негізгі мәнбірлері мен көрсеткіштерінің арнайы жіктемесі келтірілген. Аталған жіктеменің маңызды ерекшеліктерінің бірі ретінде серіктес көліктік-логистиқалық кәсіпорындар мен бәсекелес кәсіпорындармен арадағы ынтымақтастық дәрежесі қабылданған. Ұсынылып отырған ұсыныстарды тәжірибелік тұрғыда пайдалану көліктік-логистиқалық қызметті тұтынушылардың сұраныстарын толық және сапалы қанағаттандыруға бағытталған басқару шешімдерінің тиімділік деңгейін арттыруға мүмкіндік береді.
ASSESSMENT OF THE LIFE CONDITION OF TREES BEFORE LOGGING FROM SAMPLES OF WOOD FROM STUMPS AND/OR LOGS IN FORENSIC BOTANICAL EXAMINATION USING DENDROCHRONOLOGICAL METHODS
Authors: Жаворонков Ю.М. , Унжакова С.В. , Цветков В.А. 
Published: July 2023

Статья посвящена оценке жизненного состояния деревьев по пням (образцам древесины с пней) и сортиментам древесины (образцам с сортиментов древесины) при производстве судебно-ботанической экспертизы с применением методов дендрохронологического анализа в комплексе с уже существующей практикой установления жизненного состояния деревьев по пням с использованием внешних (морфологических) диагностических признаков. В статье сформированы рекомендации для специалистов и экспертов в области судебной ботаники (исследование объектов растительного происхождения), а также для лиц, занимающихся расследованием преступлений, связанных с незаконной рубкой лесных насаждений, специалистов, осуществляющих санитарные обследования лесных участков, городских насаждений.
The article deals with the assessment of the vital state of trees on stumps (wood samples from stumps) and wood assortments (wood samples from wood assortments) in the course of forensic botanical examination using dendrochronological analysis methods in combination with the already existing practice of establishing the vital state of trees on stumps using external (morphological) diagnostic signs. The article forms recommendations for specialists and experts in the field of fo-rensic botany (examination of objects of plant origin), as well as for persons involved in the investigation of crimes related to illegal logging, specialists who carry out sanitary inspections of forest areas, urban plantations.
Efektifitas Pemberian Massage Counter Pressure dan Aromaterapi Lavender terhadap Tingkat Nyeri pada Kala I Fase Aktif Persalinan Normal di PMB Filda Fairuza, S.ST., M.Kes Tahun 2023
Authors: Azkiya Fadhila , Fairuza Filda 
Published: July 2023

The purpose of this study was to determine the effect of giving counter pressure massage and lavender aromatherapy on pain levels during the first stage of the active phase of normal labor at PMB Filda Fairuza, S.ST., M.Kes in 2023. This type of quantitative research was a comparative research design with 2 sample pairs , where there are two groups that will be compared and will be given a pretest before being given treatment, and given a posttest after being given treatment. The results of this study revealed that in the intervention group, before being given counterpressure massage and lavender aromatherapy, the majority of severe pain intensity was found, namely 25 people (75.8%), and after being given counterpressure massage and lavender aromatherapy, the majority of severe pain intensity categories were obtained, namely 18 people (54 ,4%). Whereas in the control group, before the intervention period, the majority of severe pain intensity was found, namely 22 people (66.7%), and after the intervention period, the majority of severe pain intensity categories were 25 people (75.8%).

Tujuan penelitian ini adalah untuk mengetahui efek pemberian massage counter pressure dan aromaterapi lavender terhadap tingkat nyeri pada kala I fase aktif persalinan normal di PMB Filda Fairuza, S.ST., M.Kes Tahun 2023. Jenis penelitian kuantitatif dengan desain penelitian komparatif 2 sampel berpasangan, dimana terdapat dua kelompok yang akan dibandingkan dan akan diberikan pretest sebelum diberikan perlakuan, dan diberikan posttest setelah diberikan perlakuan. Hasil penelitian ini adalah diketahui bahwa pada kelompok intervensi, sebelum diberikan massage counterpressure dan aromaterapi lavender didapatkan mayoritas intensitas nyeri berat yaitu 25 orang (75,8%), dan setelah diberikan massage counterpressure dan aromaterapi lavender didapatkan mayoritas kategori intensitas nyeri berat yaitu 18 orang (54,4%). Sedangkan pada kelompok kontrol, sebelum periode intervensi didapatkan mayoritas intensitas nyeri berat yaitu 22 orang (66,7%), dan setelah periode intervensi didapatkan mayoritas kategori intensitas nyeri berat 25 orang (75,8%).
Surface Engineering of Perovskite Films via Sequential Moisture Cooling and Passivation for Efficient Solar Cells
Authors: Wang Can , Ou Zeping , Pan Yi , Ouedraogo Nabonswende Aida Nadege , Chen Peidong , Gao Qin , Yang Ke , Lei Hongliang , Ouyang Yunfei , Wan Wei , Gao Mingyang , Wu Zhiwei , Peng Deyong , Jiang Tingming , Sun Kuan 
Published: January 2025

AbstractDefect density on the perovskite film surface significantly exceeds that found in the bulk, primarily due to the presence of dangling bonds and excessive strain. Herein, a synergistic surface engineering is reported aimed at reducing surface defects of perovskite films. This method involves subjecting the thermally‐annealed perovskite films to a controlled cooling condition involving an ambient environment with regulated humidity, as opposed to a nitrogen environment, followed by phenethylammonium iodide (PEAI) passivation. The perovskite films treated with moisture cooling (MC) exhibit enhanced radiative recombination, prolonged charge carrier lifetime, and improved hole transport and extraction when in contact with the hole transport layer (HTL), alongside a significant reduction in strain. Notably, the passivation effect of PEAI on the MC‐treated perovskite films is significantly amplified compared with the films subjected to nitrogen cooling (NC) treatment, as evidenced by a more uniform surface potential mapping and a markedly extended charge carrier lifetime. This enhanced passivation effect may arise from the higher ratio of newly‐formed 2D perovskite phase PEA2FAPb2I7 to PEA2PbI4 in the MC‐treated film. Consequently, the MC‐based perovskite solar cell (PSC) achieves a champion power conversion efficiency (PCE) of 25.28%, surpassing that of the NC‐treated device, which exhibits a PCE of only 24.01%.
Switching From Acceptor to FRET Donor: How the Organic Solar Cell Architecture Can Change the Role of a Chromophore
Authors: Jin Hui , Mallo Neil , Zhang Guanran , Lindsay Oliver , Chu Ronan , Gao Mile , McAnally Shaun , Etchells Isaac M. , Burn Paul L. , Gentle Ian R. , Shaw Paul E. 
Published: January 2025

AbstractThe third component in a ternary organic solar cell (OSC) is generally selected to maximize absorption of the solar spectrum. The fused ring non‐fullerene acceptor 2,2′‐[({4,4,9,9‐tetra‐n‐octyl‐4,9‐dihydro‐s‐indaceno[1,2‐b:5,6‐b']dithiophene‐2,7‐diyl}bis{benzo[c][1,2,5]thiadiazole‐7,4‐diyl})bis(methaneylylidene)]dimalononitrile (o‐IDT‐BT‐DCV) was investigated for use in binary and ternary OSCs. The optimized binary device with o‐IDT‐BT‐DCV as the acceptor and PM6 as the donor had a maximum power conversion efficiency (PCE) of 10.8%. Incorporation of o‐IDT‐BT‐DCV into a donor:acceptor PM6:Y6 blend delivered a ternary OSC with a maximum PCE of 16.2%. Femtosecond transient absorption spectroscopy (fs‐TAS), transient photovoltage (TPV), and transient photocurrent (TPC) measurements in combination showed that o‐IDT‐BT‐DCV in the ternary blend did not behave as an acceptor. Instead, it contributed to charge carrier generation through a sub‐picosecond energy transfer process to Y6, followed by a photoinduced hole transfer mechanism with PM6 and/or spontaneous exciton dissociation within the Y6 phase. Encapsulated ternary blend devices were found to be more stable than the binary blend solar cells. Under 1‐sun illumination and maximum power point (MPP) tracking, excluding the initial burn‐in loss, the ternary device retained ≈80% of its MPP over 1200 h compared to the 40% retained by the PM6:Y6 devices.
Development of Functional and Hydrolytically Stable Vinyl Monomers as Methacrylate Dental Resin Restorative Alternatives
Authors: Gouveia Zach , Finer Yoav , Santerre J. Paul 
Published: January 2025

AbstractDental resin‐based restorative (RBR) materials represent the most ubiquitous biomaterials utilized globally. Methacrylate (MA)‐ester based monomers – present in RBRs since the 1960s – experience significantly elevated rates of failure compared to previously used silver/amalgam fillings attributed to their hydrolysis reported in both simulated and in vivo environments. There is currently no alternative RBR chemistry that matches the functional and clinical workflow considerations of MA‐RBRs while addressing their limited‐service lives. The objective of this work is to utilize a systematic framework to develop alternative hydrolytically‐stable monomers (HSMs), assessing key physical properties, biostability, and cytocompatibility towards eliminating or reducing the biodegradation of RBRs. This process yielded HSMs (referreed to as 3BE, 3TE) that matched the physical properties of MA‐control materials, including viscosity, polymerization conversion, hydrophilicity, water uptake, and surface hardness (p > 0.05), while outperforming MA‐based materials in all simulated oral environments, showing improved biostability in reconstituted human saliva, simulated human salivary esterase (SHSE), bacterial culture, and acidic media (p < 0.05). Additionally, HSMs were found to be less cytotoxic than commercial MA‐monomers (p < 0.05) and unlikely to be genotoxic. Therefore, the HSMs and associated resins developed in this study have the potential to significantly improve the clinical service life of RBRs, without compromising their fundamental features.
Self‐Assembled 3D Blue Phase Liquid Crystals for Intelligent Photonic Crystals and Functional Devices
Authors: Wang Meng , Yang Hui , Li Xiaosong , Zhang Xia , Yang Huai 
Published: January 2025

AbstractLiquid crystal (LC) materials, with their supramolecular self‐assembly nanostructures and stimulus‐responsive properties, offer inherent advantages in the development of advanced intelligent functional materials. Among various LC phase, blue phase liquid crystals (BPs) are regarded as promising candidates for intelligent photonic crystals due to their unique 3D periodic nanostructures and the capability to selectively reflect circularly polarized light within the visible spectrum. Over the past decades, various methodologies are developed to synthesize BP materials with superior thermal stability, high‐quality optical properties and excellent stimulus‐responsibility, yielding significant research outcomes in the design and application of visual functional devices. Herein, this review summarizes the recent advancements in BPLCs. It comprehensively covers the structural characteristics and preparation methods of BP photonic crystals, detailing significant research findings in their optical, electrical, mechanical, and humidity‐responsive properties, as well as their pivotal applications in sensors, optical devices, stimulus response, and anti‐counterfeiting devices. Finally, the challenges and prospective development directions of this novel soft matter intelligent material are discussed. It is anticipated that this review will provide valuable insights for scientists and engineers in interdisciplinary fields, including materials science, photonics, chemistry, and physics, facilitating the fabrication of advanced functional soft materials.
Enhancing the Infrared Emission from Silver Chalcogenide Quantum Dots Through Microcavity Coupling
Authors: Makke Lina , Bossavit Erwan , Mastrippolito Dario , Shcherbakov Andrei , Cavallo Mariarosa , Zhang Huichen , Gemo Tommaso , Colle Albin , Khalili Adrien , Hua Muchuan , Lafosse Xavier , Xu Xiang Zhen , Silly Mathieu G. , Pierucci Debora , Lhuillier Emmanuel , Diroll Benjamin T. , Degiron Aloyse , Ithurria Sandrine 
Published: January 2025

AbstractNanocrystals (NCs) appear as a promising platform for cost effective infrared optoelectronics, while offering a simplified coupling to the CMOS platform. However, this perspective is slowed down by toxicity concerns, the most effective materials being based on Pb and Hg. There is currently a large effort to bring forth new platforms that are active in the infrared with a reduced heavy metal content. Here, the focus is on silver chalcogenides, which, thanks to a combination of inter‐ and intraband transitions, is suited to cover both short and mid wave infrared ranges. However, this material being less mature, the achieved photoluminescence (PL) appears quite broad, which is problematic for device integration. Here, it is demonstrated that a strong control over the PL spectrum can be obtained through integration into a dielectric cavity that magnifies the electric field by a factor 20 and narrows the PL full width at half maximum down to 15 nm for an emission at telecom wavelength. The PL is also highly directional to avoid most waveguiding effects which is of utmost interest for enhancing the efficiency of NC‐based light emitting diodes.
High‐Performance Red OLEDs Enabled by an Organoboron‐Nitrogen‐Carbonyl‐Hybridized Multiresonant Emitter
Authors: Cheng Ying‐Chun , Walia Rajat , Zhang Tong‐Yuan , Wang Hui , Xiong Xin , Yu Jia , Fan Xiao‐Chun , Chen Xian‐Kai , Wang Kai , Zhang Xiao‐Hong 
Published: January 2025

AbstractOrganoboron‐nitrogen‐carbonyl‐hybridized (h‐BNCO) frameworks are emerging templates for developing high‐performance multiresonant (MR) emitters, but their potentials have not been fully explored. In this study, a novel red MR emitter, namely, h‐BNCO‐3, is developed by decorating two diphenylamine moieties onto a h‐BNCO MR skeleton (h‐BNCO‐2). Compared with the green backbone, h‐BNCO‐3 achieves a substantial emission redshift of 76 nm while retaining a narrow full width at half maximum (FWHM) of 45 nm (0.16 eV) in toluene. Moreover, the common advantages of integrating a carbonyl group in B/N‐based systems, e.g., significant nπ* contribution in the triplet manifolds, are obvious in h‐BNCO‐3. Thus, h‐BNCO‐3 obtained a fast reverse intersystem crossing rate (kRISC) of over 105 s−1. The optimized non‐sensitized organic light‐emitting diode (OLED) based on h‐BNCO‐3 achieved red emission with an external quantum efficiency (EQE) of 26.4%. Moreover, by further employing a phosphor as a sensitizer, the h‐BNCO‐3‐based OLED can reach an impressive EQE of 38.0%, which is among the best results of red MR‐OLEDs. This work demonstrates the effectiveness of integrating carbonyl into organoboron‐nitrogen‐based frameworks with peripheral decorations for enhancing kRISC, offering new insights for developing high‐performance MR emitters based on h‐BNCO systems.
Tuning 1D Plasmonic Gap at Nanometer Scale for Advanced SERS Detection
Authors: Moghaddam Mahsa Haddadi , Sharma Sobhagyam , Park Daehwan , Kim Dai Sik 
Published: January 2025

AbstractThe “hotspots”, which are typically found in nanogaps between metal structures, are critical for the enhancement of the electromagnetic field. Surface‐enhanced Raman scattering (SERS), a technique known for its exceptional sensitivity and molecular detection capability, relies on the creation of these hotspots within nanostructures, where localized surface plasmon resonance (LSPR) amplifies Raman signals. However, creating adjustable nanogaps on a large scale remains challenging, particularly for applications involving biomacromolecules of various sizes. The development of tunable plasmonic nanostructures on flexible substrates represents a significant advance in the creation and precise control of these hotspots. This work introduces tunable nanogaps on flexible substrates, utilizing thermally responsive materials to allow real‐time control of gap width for different molecule sizes. Through advanced nanofabrication techniques, uniform, tunable nanogaps are achieved over large areas of wafer scale, enabling dynamic modulation of SERS signals. This approach results in an enhancement factor of over ≈10⁷, sufficient for single‐molecule detection, with a detection limit as low as 10⁻¹2 m. The thermally tunable nanogaps provide a powerful tool for the precise detection of molecules and offer significant advantages for a wide range of sensing and analytical applications.
Organic Photoredox Catalytic Sulfonylation of Enaminones to Access 3‐Sulfonyl Chromones
Authors: Sun Jun , Wei Yu , Wang Wenjian , Lin Wen , Wang Chaodong , Zhou Jiadi , Wang Guan , Li Jianjun 
Published: January 2025

AbstractHerein, we disclose a readily available phenothiazine derivative as an oxidizing organic photocatalyst, that serves to induce radical cascade sulfonylation/cyclization reaction of enaminones. A variety of 3‐sulfonyl chromones have been obtained with moderate to excellent yields. This catalytic platform proceeds under metal‐free conditions with a wide substrate scope and broad functional group compatibility, which unlocks the new reactivity of phenothiazine derivatives and adds significant synthetic values to O‐heterocycles.
Squamocin Suppresses Tumor Growth through Triggering an Endoplasmic Reticulum Stress‐Associated Degradation of EZH2/MYC Axis
Authors: Zhu Yin , Liu Yurui , Wang Xiangtao , Chen Zhifeng , Chen Baojian , Hu Bingxin , Tang Tiane , Cheng Haoran , Liu Xinglong , Ning Yunshan 
Published: January 2025

AbstractDespite substantial advances in the antitumor effects of annonaceous acetogenins (ACGs), the absence of a defined biological action mechanism remains a major barrier to their clinical application. Here, it is found that squamocin effectively depletes both EZH2 and MYC in multiple cancer cell lines, including head and neck squamous cell carcinoma, and gastric and colorectal cancer, demonstrating potent efficacy in suppressing these in vivo tumor models. Through the combination of surface plasmon resonance (SPR), differential scanning fluorimetry (DSF), and cellular thermal shift assay (CETSA), heat shock protein 90α (HSP90α) is identified as the direct binding target of squamocin. Mechanistically, squamocin disrupts mitochondrial respiratory Complex I function, reduces ATP production, and impairs HSP90α function, provoking endoplasmic reticulum (ER) stress and the unfolded protein response (UPR). These intrinsic events within tumor cells enhance ER stress‐associated ubiquitylation and degradation by triggering ubiquitin via the E1 activase UBA6, facilitating ubiquitin transferring to E2 conjugate UBE2Z and increasing the activities of E3 ligase FBXW7 to degrade both EZH2 and MYC. The findings elucidate the role of squamocin in the degradation of oncoproteins EZH2 and MYC by triggering an ER stress‐associated UBA6‐UBE2Z‐FBXW7 ubiquitin cascade, providing insights that may accelerate therapeutic development targeting tumors driven by the EZH2/MYC axis.
Ultrathin High‐Efficiency Zener Diode Fabricated Using Organized ZnS Nanoparticles in Surface‐Grafted Poly(methacrylic acid) Matrix
Authors: Wieczorek Wojciech , Mazur Tomasz , Górka‐Kumik Weronika , Dąbczyński Paweł , Podborska Agnieszka , Bernasik Andrzej , Szuwarzyński Michał 
Published: January 2025

AbstractHere, the fabrication method of ultrathin Zener diodes is presented utilizing a novel hybrid system of zinc sulfide (ZnS) nanoparticles embedded within a poly(methacrylic acid) (PMAA) matrix, surface‐grafted via ARGET‐ATRP polymerization. The controlled polymerization method facilitates precise control over layer thickness, while the in situ synthesis of ZnS nanoparticles ensures uniform coverage throughout the polymer matrix. The obtained hybrid systems with nanometric thickness (<40 nm) are characterized by diode conductivity with a clear breakdown characteristic of the Zener system. The obtained ultra‐thin layers on p‐doped silicon, in addition to their electrical characteristics, are studied using an atomic force microscope (AFM) and secondary ion mass spectrometry (SIMS) to examine the structure and composition of a hybrid polymer‐nanoparticle system.