bluuebunny/crossref_metadata_2025_split huggingface dataset:
Homogenized Upcycling for Spent LiNi0.5Co0.2Mn0.3O2: Modulating O Vacancies toward Enhanced Structural Stability
Authors: Ge Peng , Wang Bin , Zeng Zihao , Zhu Chao , Lei Hai , Li Jiexiang , Zhou Hanyu , Sun Wei , Yang Yue 
Published: January 2025

AbstractFascinated by the high value and low pollution, the direct recycling of spent LiNi0.5Co0.2Mn0.3O2 (S‐NCM) has triggered plenty of exploring activities. Considering different industry sources, they always display various particle sizes and surface traits. Therefore, the simple recovery of chemical defects hardly meets the market demand. Herein, the homogenized strategy, containing physical crushing and chemical recovering, is introduced to regenerate morphology and components of S‐NCM, where the successfully regenerated samples displayed uniform particle size and stable chemical lattice. Assisted by physical crushing, the precursors show a large contacting area with oxygen during morphology reconstruction, accompanied by the effective repairing of the internal lattice. More significantly, the unique manner induces the repairing of oxygen vacancies (OVs) and the lowering of Li/Ni disorder, bringing about enhanced structural stability. Moreover, the lowering of oxygen redox activity and the improvement of oxygen binding energy are further revealed by theoretical calculations. The as‐optimized regenerated samples display a considerable capacity of 139.6 mAh g−1 with a remarkable capacity retention of 94% at 1.0 C. Even at 5.0 C, its capacity retention could be kept at ≈80.8% after 150 loops. Given this, this work is expected to provide effective guidance for different NCM regenerations, meanwhile offering an in‐depth understanding of morphology/lattice reconstruction.
A Modified Polydopamine Nanoparticle Loaded with Melatonin for Synergistic ROS Scavenging and Anti‐Inflammatory Effects in the Treatment of Dry Eye Disease
Authors: Yang Xue , Wang Bowen , Zeng Hao , Liang Lihong , Zhang Runze , Deng Wenrui , Zhao Xuan , Yuan Jin 
Published: January 2025

AbstractDry eye disease (DED) is a multifaceted ocular surface disorder that significantly impacts patients’ daily lives and imposes a substantial economic burden on society. Oxidative stress, induced by the overproduction of reactive oxygen species (ROS), is a critical factor perpetuating the inflammatory cycle in DED. Effectively scavenging ROS is essential to impede the progression of DED. In this study, boronophenylalanine‐ containing polydopamine (PDA‐PBA) nanoparticles are developed loaded with melatonin (MT), which are blended with poly(vinyl alcohol) (PVA) to create eye drops PVA/ PDA‐PBA@MT (PPP@MT). In vitro and in vivo studies demonstrate that PPP@MT exhibits dual functionalities in reducing ROS production and downregulating inflammatory pathways, thereby preserving mitochondrial integrity and further inhibiting programmed cell death. Following PPP@MT treatment, tear secretion, corneal structure, and the number of goblet cells are markedly restored in a mouse model of dry eye, indicating the therapeutic efficacy of this agent. Collectively, PPP@MT, characterized by minimal side effects and favorable bioavailability, offers promising therapeutic insights for the management of DED and other ROS‐mediated disorders.
Photosynthesis‐Inspired NIR‐Triggered Fe₃O₄@MoS₂ Core–Shell Nanozyme for Promoting MRSA‐Infected Diabetic Wound Healing
Authors: Xiao Jiamu , An Xuping , Tang Fei , Dai Xu , Zhang Song , Zhu Xiaolong , Shen Jian , Yuan Jiang , Gan Donglin , Wang Mingqian 
Published: January 2025

AbstractBacterial infections can lead to severe medical complications, including major medical incidents and even death, posing a significant challenge in clinical trauma repair. Consequently, the development of new, efficient, and non‐resistant antimicrobial agents has become a priority for medical practitioners. In this study, a stepwise hydrothermal reaction strategy is utilized to prepare Fe3O4@MoS2 core–shell nanoparticles (NPs) with photosynthesis‐like activity for the treatment of bacterial infections. The Fe3O4@MoS2 NPs continuously catalyze the production of reactive oxygen species (ROS) from hydrogen peroxide through photosynthesis‐like reactions and convert light energy into heat with a photothermal efficiency of 30.30%. In addition, the photosynthetically generated ROS, combined with the iron‐induced cell death mechanism of the Fe3O4@MoS2 NPs, confer them with exceptional and broad‐spectrum antibacterial properties, achieving antimicrobial activities of up to 98.62% for Staphylococcus aureus, 99.22% for Escherichia coli, and 98.55% for methicillin‐resistant Staphylococcus aureus. The composite exhibits good cell safety and hemocompatibility. Finally, a full‐thickness diabetic wound model validates the significant pro‐healing properties of Fe3O4@MoS2 in chronic diabetic wounds. Overall, the design of photosynthesis‐inspired Fe3O4@MoS2 presents new perspectives for developing efficient photothermal nano‐enzymatic compounds, offering a promising solution to the challenges of antimicrobial drug resistance and antibiotic misuse.
DEyeA: Artificial Muscles for the Restoration of Eye Blinking Following Facial Paralysis
Authors: Konstantinidi Stefania , Koenigsdorff Markus , Martin Pierre‐Jean , Benouhiba Amine , Civet Yoan , Gerlach Gerald , Perriard Yves 
Published: January 2025

AbstractFacial nerve palsy results in the inability to control facial muscles, including the Orbicularis Oculi, which is the main muscle enabling the blinking action. Blinking is not only important for responding socially to other humans, it is also essential for lubricating the cornea. Without lubrication, loss of vision or eye infections may occur. Current procedures for patients are not always adequate, and there is a real need for more appropriate solutions. This study presents a novel design for a prosthesis that enables the restoration of eye‐blinking abilities in patients with paralysis. The prosthesis consists of an artificial muscle, namely a dielectric elastomer actuator (DEA), used in conjunction with a bistable negative‐rate biasing system (NBS). The prosthesis along with a realistic and anatomically precise eyelid are fabricated and characterized. The specifications in terms of stroke, force and frequency, including opening and closing time of the eyelid, are reached and a natural blinking movement is achieved, with a resulting displacement of the artificial eyelid of 2.5 mm, showing that the use of a DEA with a NBS is a promising approach for the restoration of blinking in the treatment of facial paralysis.
A Paper‐Based Robust Hybrid Photodetector Based on the 2D/0D/0D MoS2/N‐GQD/CsPbBr3 Triple Junction
Authors: Patil Kalyanee , Barve Kanchan , Pisal Akshaya , Ogale Satishchandra , Bhave Tejashree 
Published: January 2025

AbstractFlexible photodetectors (FPDs) are emerging as essential components for next‐generation wearable optoelectronic devices, bendable imaging sensors, and implantable optoelectronics. However, the development of high‐performance FPDs hinges on the identification of innovative material systems that combine excellent optoelectronic properties, efficient charge transport, and scalable processing techniques. In this study, these challenges by introducing a novel hybrid paper‐based photodetector featuring a 2D MoS₂/N‐doped Graphene Quantum Dot (N‐GQD)/CsPbBr₃ quantum dot triple junction are addressed. This architecture is fabricated entirely through cost‐effective and easily scalable solution‐based methods, emphasizing the practicality of large‐scale production. The incorporation of N‐GQDs as an intermediate layer between MoS₂ nanoflowers and CsPbBr₃ QDs significantly enhances carrier transport and separation, leading to outstanding device performance. The materials and fabricated device are characterized by X‐ray diffraction, Scanning Electron Microscopy, Transmission Electron Microscopy, UV–vis and Photoluminescence spectroscopy, and Ultra Violet photoelectron spectroscopy. The photodetector exhibits a remarkable responsivity of 0.458 A W−1 and a specific detectivity of 3.28 × 10¹¹ Jones, highlighting its potential for high‐sensitivity applications. These results underscore the originality of the triple‐junction design and its significance as a versatile, economical platform for advancing flexible and large‐area photodetectors, paving the way for their deployment in wearable optoelectronics and expanded photo communication technologies.
Microwave Monitoring by Compact Carbon Nanotube Photo‐Thermoelectric Sensors Beyond the Diffraction Limit Toward Ultrabroadband Non‐Destructive Inspections
Authors: Zhang Qi , Li Honghao , Koshimizu Ryo , Takahashi Norika , Kinoshita Yuya , Sano Asumi , Jin Junyu , Okawa Hiroki , Matsuzaki Yuto , Shikichi Daiki , Kawano Yukio , Li Kou 
Published: January 2025

AbstractElectromagnetic‐wave (EMW) sensing in microwave (MW) frequencies exhibits permeability even to deeper positions of various non‐metallic materials (indispensable for social products) and potentially facilitates non‐destructive inspections. However, conventional MW‐sensor designs generally have faced difficulties in miniaturizations for longer wavelengths and the subsequent diffraction limit. While EMW sensors essentially require pixel miniaturizations for imaging, implementations of typical external antennas concentrating MW‐irradiation into smaller areas than the diffraction limit fatally complicate overall fabrications and operations. Herein, this work demonstrates that carbon nanotube (CNT) film photo‐thermoelectric (PTE) sensors sufficiently handle even MW‐irradiation in compact configurations beyond the diffraction limit by themselves while maintaining inherent operations in shorter‐wavelength millimeter‐wave–infrared bands. The CNT film PTE sensors enhance MW‐detection responses with particular channel dimensions (shorter length and narrower width), demonstrating a signal‐to‐noise ratio of 1497 with a 1‐mm‐square planar structure under 5 GHz irradiation (one‐sixtieth size of the wavelength). In such advantageous behaviors, this work experimentally clarifies that electrically conductive wiring of the CNT film PTE sensor (inherently included within pristine device structures as response signal readout electrodes) plays a key antenna‐like role. Then, the presenting devices demonstrate composition‐identifying non‐destructive testing of complex targets with multiple‐wavelength imaging in ultrabroad MW–near‐infrared bands, while compensating characteristics in respective irradiation regions.
Transforming Agricultural Food Waste Into Bioplastics: Methods, Potential, and Technological Advances
Authors: Asim Zukhruf , Shahzad Hafiz Muhammad Aamir , Ghodake Gajanan , Mahmoud Khaled A. , Almomani Fares , Rasool Kashif 
Published: January 2025

AbstractThe improper disposal of agricultural food waste (AFW) and its associated plastic packaging significantly exacerbates environmental degradation, including pollution, greenhouse gas emissions, and loss of valuable resources, while imposing substantial economic burdens. These pressing challenges have spurred advancements in bioplastics as sustainable and eco‐friendly alternatives to conventional plastics. Here, the potential of AFW, rich in biopolymers such as starch and cellulose, as a renewable feedstock is examined for bioplastics such as polylactic acid, polybutylene succinate, and polyhydroxyalkanoates. It explores the characteristics of these bioplastics, focusing on production techniques such as extraction‐based processes, microbial fermentation, fermentation combined with polymerization, and synthesis from volatile fatty acids. Additionally, the role of AFW pretreatment methods, including physical, chemical, biological, and enzymatic approaches, in enhancing conversion efficiency is analyzed. Here, it is highlighted that recent advancements in bioplastic production have improved efficiency, biodegradability, and scalability, offering a viable substitute for traditional plastics. These findings demonstrate that valorizing AFW not only addresses plastic and food waste challenges but also promotes sustainability and circular economy principles, paving the way for greener industries and reduced ecological impact.
Effect of Wall Slip on the Extrusion Characteristics of 3D Printing of Cementitious Materials
Authors: Wang Yibo , Yan Ming , Yang Kun , Ao Chenyang , Ren Changzai 
Published: January 2025

AbstractThis paper investigates the impact of wall slip on the screw extrusion of cementitious materials. A wall slip extrusion model is developed based on the theory of infinite parallel plates. Then, the extrusion characteristics under different slip conditions of the screw and the cylinder wall are discussed. Finally, the Finite Element Method is used to verify the conclusions drawn from theoretical model analysis. The results show that when −1≤a←1/3 (where a is the ratio of pressure flow to the sum of drag flow and slip flow), slippage on either the screw wall or the cylinder wall can reduce the extrusion flow rate, and the number of flow recirculation planes is one. When −1/3≤a≤1, the number of flow recirculation planes increases to two, and screw wall slip is conducive to expanding the extrusion flow rate. Conversely, cylinder wall slip may reduce the extrusion flow rate. Moreover, the simulation results are consistent with those of the theoretical model, further verifying the rationality of the model.
Conversion–Lithiophilicity Hosts Toward Long‐Term and High‐Energy‐Density Lithium Metal Batteries
Authors: Huang Aoming , Huang Hongjiao , Li Shaoxiong , Pan Xiansong , Wang Ai‐Yin , Chen Han‐Yi , Wang Tao , Li Linlin , Maximov Maxim , Ren Jianwei , Wu Yuping , Peng Shengjie 
Published: January 2025

AbstractLithium metal anode emerges as an ideal candidate for the next generation of high‐energy‐density batteries. However, challenges persist in achieving high lithium utilization rates while maintaining the demands of high energy density and extended cycle life. In this work, a novel conversion–lithiophilicity strategy is proposed to regulate the longevity of high‐energy‐density batteries by injecting lithium ion activity. This strategy is validated through carbon nanofiber decorated with Fe3C and Fe2O3 particles. The uniform metallic lithium deposition induced by lithiophilic Fe3C substrates has been verified through lithium deposition/stripping experiments and density functional theory calculations. The electrochemical active Fe2O3 component supplies additional anodic capacity and suppress battery degradation, as demonstrated in lithium‐ion storage research and three electrode system studies. When paired with LiFePO4 cathodes at an N/P ratio of 2, the full battery showcases outstanding cycling stability over 300 cycles at 1C, with an exceptional energy density of 438 Wh kg−1 (calculated based on the cathode material and lithium content). Furthermore, the full battery delivers rapid kinetics of 124 mAh g−1 at 2C. The conversion–lithiophilicity strategy presented offers a promising avenue for the development of high‐energy density and long‐life lithium metal batteries.
Soil test correlation of Olsen‐P for corn and soybean in a subtropical humid region
Authors: Reussi Calvo N. I. , Cortez D. , Crespo C. , Wyngaard N. , Terrazas J. , Paz C. , Trujillo R. , Correndo A. , Garcia F. O. 
Published: January 2025

AbstractAccurate phosphorus (P) fertilizer recommendations for soybean [Glycine max (L.) Merr.] and corn (Zea mays L.) are crucial for maximizing productivity and economic return while minimizing the environmental impact of fertilizer use. Currently, there are no calibrations for diagnosing P deficiencies in croplands of Bolivia. This study aimed to define and compare the P critical soil test value (CSTV) for corn and soybean using the Olsen method. Twenty fertilization field trials were conducted for corn and 75 for soybean in the Santa Cruz de la Sierra region, including treatments with and without P fertilization. Soil pre‐planting (0–20 cm) organic matter, Olsen P, pH, as well as yield were determined. Relative yield (RY) was estimated as the ratio of grain yield between the control and P‐fertilized treatments. The CSTV was calculated using the arcsine‐logarithm method, with data resampling through bootstrapping. The average yield response to added P was 259 kg ha−1 (+11.0%) for soybean and 545 kg ha−1 (+13.7%) for corn. For soybean, CSTVs were determined as 6.1 and 11.0 mg kg−1 (r = 0.34, p = 0.002) for 90% and 95% of RY, respectively. For corn, the CSTVs were 8.1 and 13.9 mg kg−1 (r = 0.34, p = 0.14) for 90% and 95% of RY, respectively. The confidence intervals suggest no differences between crops. The Olsen‐P is a promising tool for soil fertility recommendations in Bolivia. Yet, the modest goodness of fit obtained suggests the need for further research refining the performance of soil test P diagnosis in the region.
Brownian bridges for contained random walks
Authors: Curtis George , Ramkrishna Doraiswami , Narsimhan Vivek 
Published: January 2025

AbstractUsing linear operator techniques, we demonstrate an efficient method for investigating rare events in stochastic processes. Specifically, we examine contained trajectories, which are continuous random walks that only leave a specified region of phase space after a set period of time . We show that such trajectories can be efficiently generated through the use of a Brownian Bridge, derived via the solution to the Backward Fokker–Planck (BFP) equation. Using linear operator techniques, we place the BFP operator in self‐adjoint form and show that in the asymptotic limit , the set of paths contained in a specified region is equivalent to paths on a modified potential energy landscape that is related to the dominant eigenfunction of the self‐adjoint BFP operator. We demonstrate this idea on several example problems, one of which is the Graetz problem, where one is interested in the survival time of a particle diffusing in tube flow.
The Rapid Rise of Silicosis in Victoria, Australia Associated With Artificial Stone Countertop Industry Work
Authors: Hoy Ryan F. , Tomic Dunya , Gwini StellaMay , Dimitriadis Christina , Abramson Michael , Collie Alex , Barnes Hayley , Glass Deborah C. , Hore‐Lacy Fiona , Kinsman Natasha , Sim Malcolm R. , Walker‐Bone Karen 
Published: January 2025

ABSTRACTBackgroundThe fabrication and installation of artificial (engineered) stone countertops is a relatively new cause of silicosis. Our aim was to investigate silicosis rates in Victoria, Australia, and the association with stone countertop industry work.MethodsWorkers' compensation claims for silicosis from January 1, 1991 to December 31, 2022 were analyzed across 8‐year time periods. Incidence rates per 100,000 persons were calculated by time period, age, and sex. Additionally, incident silicosis cases were reported to a clinical registry by respiratory physicians from May 1, 2019 to December 31, 2022, and analyzed by referral source and occupational history.ResultsOver 32 years, there were 536 workers' compensation claims for silicosis (98.9% male, median age 40 years). In total, 482 (89.9%) were received between 2015 and 2022, a 27‐fold increase from the previous 8‐year period. The incidence rate for silicosis claims in the adult population increased from 0.12 per 100,000 in 1991–1998 to 2.38 per 100,000 in 2015–2022. In the clinical registry there were 210 incident cases between 2019 and 2022; 97% worked in the countertop industry, 95% with artificial stone. Almost all (89%) cases had been referred following participation in a government screening program for stone countertop industry workers.ConclusionThere has been a major rise in compensation claims for silicosis in Victoria. Active screening of stone countertop workers led to the diagnosis of almost all registered incident silicosis cases. This underscores the risk to stone countertop workers and highlights the potential for under‐recognition of silicosis without screening at‐risk workers, especially in countries where artificial stone has become popular.
Transition to Adult Care in Turner Syndrome: Research Gaps and Strategies for Achieving Success
Authors: Nahata Leena , Verlinde Franciska , Stochholm Kirstine , Gutmark‐Little Iris 
Published: January 2025

ABSTRACTHealth care transition is a process by which children with chronic medical conditions gradually and purposefully move from pediatric to adult‐centered health care systems. While transition guidelines have been published by multiple national and international organizations, transition processes have not been optimized for many populations, including youth with Turner syndrome (TS). Numerous barriers exist, at both the system and individual/family level. Mitigating transition‐related barriers requires a multi‐faceted approach, including: conducting research to assess TS specific transition interventions and outcomes; developing educational/training initiatives and quality improvement efforts; engaging in advocacy/policy change; and implementing evidence‐based strategies to optimize transition. The goals of this manuscript are to outline key research gaps that need to be addressed regarding health care transition in TS and to suggest strategies to optimize transition outcomes. Given the importance of a multi‐disciplinary and patient‐centered approach, we specifically outline the roles of pediatric health care teams (including navigators), adult health care teams, patients, caregivers, and institutional resources.
Efficacy of Using Photobiomodulation Therapy in Allergic Rhinitis: A Placebo‐Controlled Randomized Clinical Trial
Authors: Oliveira Patrícia Costa , Correia Luísa Oliveira , Lopes Natália Medeiros Dias , Molossi Julia , Fornazieri Marco Aurélio 
Published: January 2025

ABSTRACTBackgroundRecent studies have extensively explored new non‐invasive and side‐effect‐free therapeutic strategies for the treatment of allergic rhinitis (AR). Photobiomodulation therapy (PBMT) utilizes photons from the red to infrared spectrum to modulate biological processes, exhibiting anti‐inflammatory and regenerative properties. The objective of our study was to evaluate the efficacy of PBMT in patients with AR.MethodsThis study was a randomized, placebo‐controlled, double‐blind clinical trial involving 62 patients with AR. Participants underwent PBMT twice weekly, totaling eight sessions over the course of 1 month. The control group consisted of 29 patients who received treatment with a non‐light‐emitting device, while 33 patients in the laser therapy group received a protocol of 6 J of red and infrared light administered intranasally, along with 1 J of infrared light applied externally to the nose. Objective, psychophysical, and subjective assessments of nasal obstruction and olfactory function were conducted both before and after the treatment.ResultsPBMT contributed to significant improvements in various nasal and respiratory parameters. The peak nasal inspiratory flow demonstrated significant improvement (p < 0.001), and the Nasal Obstruction Symptom Evaluation scale indicated notable enhancement in nasal obstruction (p = 0.048). Additionally, the Rhinitis Control Assessment Test reflected significant symptom improvement over the past week (p = 0.035). However, the University of Pennsylvania Smell Identification Test showed no significant change in olfactory function (p = 0.251).ConclusionOur data suggest that PBMT may serve as a promising therapeutic option for individuals with AR, providing an alternative for those who are unable to tolerate conventional medications. Furthermore, it demonstrates efficacy and safety as a viable treatment alternative.