bluuebunny/crossref_metadata_2025_split huggingface dataset:
A review of the photochromic behavior of metal complexes embedded in conjugated (–N=N–C=N–) and non-conjugated azo-imine-based ligands
Authors: Mandal Paritosh , Pratihar Jahar Lal 
Published: April 2023

Abstract
Photochromic compounds are well known and attract tremendous necessity for their versatile applications in various fields of science. When exposed to light, metal complexes containing potentially photoswitchable azo (–N=N–) and imine (–C=N–) based ligands can be switched between trans (E) and cis (Z) two isomers, as well as energy manipulation and energy level modulation. Then the cis (Z) isomers underwent slow thermal isomerization back to the more stable trans (Z) isomers. The quantum efficiency of metal complexes has been tuned by modifying the ligands’ structures and altering metal substrates. Herein our review encompasses the photochromic behavior of a few conjugated azo-imine (–N=N–C=N–), ligands such as arylazoimidazoles, phenylazopyridine, azobispyridine, arylazopyrozoles, as well as a few non-conjugated azo-imine or Schiff base ligands with their metal complexes.
Recitative Voice: Reading Silently and Aloud, with Jean-Luc Nancy
Authors: Puranen Joni P. 
Published: April 2023

AbstractThis text studies the corporeality of attentive reading. It relies and builds upon philosopher Jean-Luc Nancy’s suggestion that there is, each time, arecitative voicewithin the heart of our advancement through a textual body. This text examines the intriguing figure of recitative voice by paying attention to two bodily variations of reading: reading aloud and reading silently. Nancy’s recitative voice, as a sonorous, resonant, oral, buccal and vocal notion, can help us in explicating how our bodies condition our experiences of reading, yet ultimately he remains rather implicit on how we advance through textual bodies. This short text argues that we can explicate the bodily weight implicit to reading, if we interpreted it as a recitative act. When we read aloud, our experience of a text consists of an advancement of our conjoined gaze and voice through the letters, words and sentences making up our text; when we read silently, our closed and silent mouth is still conjoined with our advancing gaze, advancing as desirous for speech and with words already grasped, even when no words are folded in (or with) exhaled warm air.
Synthesizes of graphene oxide grafted with chitosan and copper oxide nanoparticles for the removal of lambda-cyhalothrin and thiamethoxam insecticides from wastewater
Authors: Khawaja Heena , Zahir Erum , Asghar Muhammad Asif , Daniel Asher Benjamin 
Published: April 2023

Abstract
The residue of lambda-cyhalothrin (LCT) and thiamethoxam (TMX) insecticides are toxic systemic pyrethroid and neonicotinoid insecticides and their entrance into water bodies can have a toxic impact on aquatic and terrestrial life. Therefore, producing of economical, sustainable and effective adsorbents is immediately required for the removal of these insecticides from polluted water. In this study, the nanocomposite of graphene oxide (GO) grafted with chitosan (CS) and copper oxide nanoparticles (Cu-NPs) was synthesized, characterized and assessed, for the first time, for LCT and TMX removal from wastewater using sorption and mechanism studies. The removal of LCT and TMX was assessed by varying the adsorbent dose, initial concentrations of insecticides, pH, exposure time and temperature to achieve optimum sorption conditions. The nanocomposite provides more than 80% removal rate for 1400 mg/L of insecticides in an aqueous solution using only 100 mg of nanocomposite at 318 K in 120 min due to large surface area and pore volume. The adsorption equilibrium data best followed the Langmuir model, with an adsorption capacity of 153 and 193 mg/g for the LCT and TMX, respectively. The pseudo-second-order explained the kinetics best, and the thermodynamic study indicated that the process was spontaneous, and endothermic and proceeded with the increase in randomness. The suggested mechanisms of LCT and TMX sorption by GO-CS-Cu nanocomposite are hydrogen bonding and electrostatic attraction. The reusability study of GO-CS-Cu was executed up to five cycles and maintains its efficiency even after the considered cycles. In conclusion, the study proves the promising use of GO-CS-Cu as a stable, reusable and promising adsorbent for LCT and TMX removal from wastewater at the industrial level.
Development of BOLD Response to Motion in Human Infants
Authors: Biagi Laura , Tosetti Michela , Crespi Sofia Allegra , Morrone Maria Concetta 
Published: April 2023

Behavioral studies suggest that motion perception is rudimentary at birth and matures steadily over the first few years. We demonstrated previously that the major cortical associative areas serving motion processing, like middle temporal complex (MT+), visual cortex area 6 (V6), and PIVC in adults, show selective responses to coherent flow in 8-week-old infants. Here, we study the BOLD response to the same motion stimuli in 5-week-old infants (four females and four males) and compare the maturation between these two ages. The results show that MT+ and PIVC areas show a similar motion response at 5 and 8 weeks, whereas response in the V6 shows a reduced BOLD response to motion at 5 weeks, and cuneus associative areas are not identifiable at this young age. In infants and in adults, primary visual cortex (V1) does not show a selectivity for coherent motion but shows very fast development between 5 and 8 weeks of age in response to the appearance of motion stimuli. Resting-state correlations demonstrate adult-like functional connectivity between the motion-selective associative areas but not between primary cortex and temporo-occipital and posterior-insular cortices. The results are consistent with a differential developmental trajectory of motion area respect to other occipital regions, probably reflecting also a different development trajectory of the central and peripheral visual field.SIGNIFICANCE STATEMENTHow the cortical visual areas attain the specialization that we observed in human adults in the first few months of life is unknown. However, this knowledge is crucial to understanding the consequence of perinatal brain damage and its outcome. Here, we show that motion selective areas are already functioning well in 5-week-old infants with greater responses for detecting coherent motion over random motion, suggesting that very little experience is needed to attain motion selectivity.
Suitability of Selat Nasik Water Conditions for Tiger Grouper Cultivation in Floating Net Cage Systems
Authors: Aldera Sabrina Anne , Adibrata Sudirman , Kurniawan Kurniawan 
Published: April 2023

According to the suitability of water conditions for tiger grouper aquaculture, there are several water quality factors such as temperature, pH, salinity, water depth, current speed, water brightness, and dissolved oxygen. The purpose of this study was to analyze the value of the physical-chemical parameters of the waters and the suitability of the water conditions for the cultivation of tiger grouper (Epinephelus fuscoguttatus) in the Nasik Strait waters. This research was conducted in February 2021 with water quality analysis carried out in situ and ex-situ (Environmental Services Laboratory) at 4 different stations. The method used in this research is descriptive qualitative and the purposive sampling method is used to determine the location of the station. Observation of water conditions using physical and chemical parameters consisting of temperature, pH, salinity, water depth, current speed, water brightness, and dissolved oxygen and carried out using matching methods for data analysis. The results of this study indicate that the waters of the Nasik Strait have a sufficient level of suitability for tiger grouper aquaculture according to the results, namely; Station 1 with a suitability value of 87%, which is put in the Very Suitable class (1), Station 2 with a suitability value of 87%, which is put in the Very Suitable class (1), Station 3 with a suitability value of 80% which is put in the class Sufficiently Appropriate (S2), and at Station 4 having a suitability value of 80% is put in the Sufficiently Appropriate (S2) class. The results show that the waters of the Nasik Strait are in the category of Very Suitable and Fairly Suitable for the development of tiger grouper aquaculture and indicate that the waters of the Nasik Strait are suitable as cultivation locations and need to be maintained regarding water quality by managing water quality management.
A Reliable Procedure to Estimate the Rupture Propagation Directions from Source Directivity: The 2016–2018 Central Italy Seismic Sequence
Authors: Calderoni Giovanna , Di Giovambattista Rita , Ventura Guido 
Published: April 2023

AbstractWe present a new approach to estimate the predominant direction of rupture propagation during a seismic sequence. A fast estimation of the rupture propagation direction is essential to know the azimuthal distribution of shaking around the seismic source and the associated risks for the earthquake occurrence. The main advantage of the proposed method is that it is conceptually reliable, simple, and fast (near real time). The approach uses the empirical Green’s function technique and can be applied directly to the waveforms without requiring the deconvolution of the instrumental response and without knowing a priori the attenuation model and the orientation of the activated fault system. We apply the method to the 2016–2017 Amatrice-Visso-Norcia high-energy and long-lasting earthquake series in central Italy, which affected a large area up to 80 km along strike, with more than 130,000 events of small-to-moderate magnitude recorded until the end of August 2022. Most of the selected events analyzed in this study have a magnitude greater than 4.4 and only four seismic events have a magnitude in the range of 3.3–3.7. Our results show that the complex activated normal fault system has a rupture direction mainly controlled by the pre-existing normal faults and by the orientation of the reactivated faults. In addition, the preferred direction of rupture propagation is also controlled by the presence of fluid in the pre-existing structural discontinuities. We discuss the possible role of fluids as a cause of bimaterial interface. Another important finding from our analysis is that the spatial evolution of seismicity is controlled by the directivity.
Deposition of spray droplets by four spray nozzles and two working pressures
Authors: Matos do Nascimento Jackeline , Martins Hidalgo Cerzosimo João Victor , Biazotti Compagnoni Raphael , Viegas Neto Antonio Luiz , Paniagua Mendieta Fernando Mateus 
Published: April 2023

The deposition of spray droplets on the target can be influenced by the type spray nozzle used, as well as the employed working pressure. Thus, with the commercial availability of new spray nozzles, performance studies with the new models become necessary. This study was carried out to evaluate ground deposition of spray droplets by four models of spray nozzles, at two working pressures. The experiment was conducted in Dourados/MS, in September 2020, with strip design and 4x2 factorial scheme, with five repetitions. Four spray nozzles were used (single flat fan, ST-IA 02 model; angle flat fan MUG 02; hollow cone MGA 02; and double flat fan ST-IA/D 02), working at 30 and 50 psi pressures. The distance between each nozzle was 50 cm, 60 cm above the ground. Water-sensitive paper was used and, immediately after application, the paper was scanned using the DropScan® tool. Subsequently, the number of droplets, coverage, amplitude, dispersion, Volume Median Diameter (VMD), Number Median Diameter (NMD), DV09, and DV01 were evaluated. The hollow cone spray nozzle provided a higher number of droplets and greater coverage compared to the other nozzles for the studied weather conditions.
Training of Future Translators through Advertising Slogans Translation
Authors: Sichkar Svitlana , Kaminska Maryna , Bryk Maryna , Melko Khrystyna , Zhurkova Olga , Kharkevych Halyna 
Published: April 2023

The paper focuses on translating advertising texts as an indispensable tool for future translators’ training. It elaborates on a semiotic approach to English advertising slogans translation into Ukrainian. From this perspective, it is possible to capitalize on language to decode the concepts encapsulated in advertising texts and devise ways of affecting mass consciousness. The present research gives a comprehensive account of translation strategies involved in deciphering the subtlety of meanings actualized in the advertising context. A comprehensive translator’s preparation should include training in various translation strategies, as they are essential for producing high-quality translations that meet the needs of both the client and the target audience. By using appropriate translation strategies, translators can ensure that their translations are accurate, efficient, and culturally appropriate while preserving the original text’s style, tone, and impact. Commercial, social, and political advertising slogans have been subjected to a comparative analysis. The study results prove that lexical-semantic, grammatical, and stylistic transformations are used in rendering advertising slogans into Ukrainian. However, the translation process is often complicated due to discrepancies in the syntactic structures of English and Ukrainian languages. The latter affect either separate untranslatable elements or the whole target language text. Therefore, translating advertising texts is a helpful tool for future translators’ training, as it allows them to develop a range of skills and strategies essential for success in the translation industry while also meeting the needs of clients who require high-quality translations of their advertising materials.
The Use of Reference Materials In the Analysis of Medicinal Plant Raw Materials and Herbal Medicinal Products
Authors: Ryazanova T. K. , Kurkin V. A. 
Published: April 2023

The need to improve pharmacopoeial approaches to the standardization of medicinal plant raw materials (MPRMs) and herbal medicinal products (HMPs), and the need to ensure the implementation of the principle of «cross-cutting» standardization in the series «medicinal plant raw material – phyto-substance – herbal medicinal product» determine the relevance of developing new, more rational approaches to the analysis of objects of plant origin.The purpose of the research was the theoretical and experimental substantiation of the use of reference materials in the development of assay procedures on the example of certain types of plant raw materials and products based on it from the standpoint of the chemical composition, stability and physicochemical properties of the biologically active compounds contained in them.Assay of active substances was carried out by high performance liquid chromatography (HPLC) using a Milichrome-6 chromatograph with a spectrophotometric detector in the ultraviolet (UV-) region. The UV spectra were recorded using a Specord 40 spectrophotometer. The measurement results were processed using the WinASPECT and Microsoft Excel 2016 programs.As a result of research, procedures for assay of syringin in the bark of Syringa vulgaris, and in the rhizomes and roots of Eleutherococcus senticosus, rosavin and salidroside in the rhizomes and roots of Rhodiola rosea, arbutin in the leaves of Arctostaphylos uva-ursi and Vaccinium vitis-idaea, isosalipurposide in the flowers of Helichrysum arenarium, the amount of anthracene derivatives in fresh leaves of Aloe arborescens were developed and validated. Spectrophotometric methods for determining the amount of biologically active phenylpropanoids in terms of eleutheroside B (syringin) in MPRMs and HMPs of Eleutherococcus senticosus and the amount of aralosides in the roots of Aralia Manchurian were introduced. Based on the data obtained, the scientific rationale for the use of reference materials of syringin (Syringa vulgaris bark, Eleutherococcus senticosus rhizomes and roots), rosavin and salidroside (Rhodiola rosea rhizomes and roots), the sum of ammonium salts of aralosides (Manchurian aralia root), arbutin (Arctostaphylos uva-ursi and Vaccinium vitis-idaea leaves), mixtures of aloins A and B (Aloe arborescens fresh leaves) in the analysis procedures was provided. The concept of a systematic approach to the analysis of medicinal plant raw materials and products based on it was formulated.
Rancang Bangun Sistem Informasi Lomba Start-Up Berbasis Web
Authors: Yudhanto Yudho 
Published: April 2023

<p>Abstrak</p><p>Rencana proposal bisnis merupakan suatu pernyataan formal atas tujuan berdirinya sebuah bisnis, serta suatu alasan mengapa pendirinya yakin bahwa tujuan tersebut dapat dicapai, serta strategi atau rencana-rencana apa yang akan dijalankan untuk mencapai tujuan tersebut. D3 Teknik Informatika UNS merupakan suatu Lembaga yang bergerak di bidang Pendidikan yang salah satu tujuan dari lembaga ini merupakan memiliki jiwa kewirausahaan dalam bidang rekayasa bisnis teknologi informasi. Dengan adanya tujuan tersebut, maka D3 Teknik Informatika UNS berupaya untuk meningkatkan jiwa kewirausahaan dengan mengadakan perlombaan kompetisi rancangan bisnis sebagai salah satu cara mewujudkan tujuan tersebut. Dengan adanya lomba tersebut, diharapkan akan tercipta dan ditemukan banyak mahasiswa yang berjiwa kewirausahaan dan bisnis untuk mengajukan rancangan bisnis yang akan atau sudah ditekuni dalam kompetisi. Berdasarkan upaya yang akan diadakan oleh D3 Teknik Informatika UNS, maka diusulkanlah suatu sistem yang dapat mempermudah dalam pendataan, pengerjaan, pemantauan, serta pengelolaan proposal bisnis dimana proposal tersebut merupakan suatu syarat utama dalam mengikutin perlombaan yang akan diselenggarakan. Hasil dari penelitian ini merupakan sistem informasi e-proposal rancangan bisnis berbasis <em>website</em> yang memiliki fitur pengelolaan pendaftaran, penginputan proposal oleh peserta lomba, serta penjurian yang dilakukan oleh juri yang terdaftar.<em> </em>Pengujian aplikasi dilakukan dengan metode Blackbox melibatkan mahasiswa, staff dan dosen.</p><p>Abstract</p><p><em>A business proposal plan is a formal statement of the purpose of establishing a business, as well as a reason why the founder believes that these goals can be achieved, as well as what strategies or plans will be implemented to achieve these goals. D3 Informatics Engineering UNS is an institution engaged in the education sector, one of the goals of this institution is to have an entrepreneurial spirit in the field of information technology business engineering. With this goal in mind, D3 Informatics Engineering UNS seeks to increase the entrepreneurial spirit by holding a business design competition as a way to achieve this goal. With this competition, it is hoped that it will create and find many students who have an entrepreneurial and business spirit to submit business designs that will or have been occupied in the competition. Based on the efforts that will be held by D3 Informatics Engineering UNS, a system is proposed that can facilitate data collection, execution, monitoring, and management of business proposals where the proposal is a main requirement in participating in the competition to be held. The result of this research is a website-based business design e-proposal information system that features registration management, input of proposals by contest participants, and judging by registered judges. Application testing is carried out using the Blackbox method involving students, staff and lecturers.</em></p>
Pengaruh Pemanfaatan Media Sosial, Kreativitas, dan Kecerdasan Emosional terhadap Minat Berwirausaha Mahasiswa di Jakarta
Authors: Maharani Anisa , Corry Yohana  , Aditya Pratama  
Published: April 2023

The purpose of this study is to ascertain the effect of social media utilization, creativity, and emotional intelligence on student’s entrepreneurship interest in Jakarta. The type of data used in quantitative. The sampling technique was purposive sampling to 150 respondents who were included in the research criteria. The data was obtained usimg a survey method with Likert Type. The data anlysis technique used is multiple linear regression analysis using SPSS version 25. Based on the test results, it was stated that the utilization of social media had a positive and significant effect on interest in entrepreneurship, creativity had a positive and significant effect on interest in entrepreneurship and emotional intelligence had a positive and significant effect on interest in entrepreneurship. The coefficient of determination in this study was 47,4% which showed the social media utilization, creativity and emtional intelligence on student’s entrepreneurship interest in Jakarta while unstudied additional factors affected the remainder.

Penelitian ini bertujuan untuk mengetahui pengaruh pemanfaatan media sosial, kreativitas, dan kecerdasan emosional terhadap minat berwirausaha mahasiswa di Jakarta. Metode yang digunakan pada penelitian ini adalah metode kuantitatif. Teknik pengambilan sampel secara purposive sampling kepada 150 responden yang termasuk kedalam kriteria penelitian. Data didapatkan menggunaka metode survei dan instrumen kuesioner dengan skala likert. Dengan teknik analisis regresi linear berganda menggunakan bantuan aplikasi SPSS versi 25.0. Berdasarkan hasil pengujian hipotesis dinyatakan bahwa pemanfaatan media sosial berpengaruh secara positif dan signifikan terhadap minat berwirausaha, kreativitas berpengaruh secara positif dan signifikan terhadap minat berwirausaha serta kecerdasan emosional berpengaruh positif dan signifikan terhadap minat berwirausaha. Koefisien determinasi pada penelitian ini adalah 48,5% yang menunjukkan pemanfaatan media sosial, kreativitas dan kecerdasan emosional memengaruhi minat berwirausaha, sedangkan sisanya dipengaruhi faktor lain yang tidak diteliti.
Faktor-faktor yang Mempengaruhi Online Shopping Intention pada Produk Vitamin di DKI Jakarta
Authors: Herdina Ekky Octavianty  , Andi Muhammad Sadat  , Dewi Agustin Pratama Sari  
Published: April 2023

Penelitian ini bertujuan untuk menguji faktor-faktor yang mempengaruhi online shopping intention produk vitamin di DKI Jakarta selama pandemi Covid-19. Ada enam tiga variabel yang digunakan yaitu online shopping anxiety, perceived ease of use, dan perceived benefit. Peneliti menggunakan metode kuantitatif dengan menyebarkan kuesioner melalui Google Form. Peneliti menggunakan sampel sebanyak 250 responden yang pernah melakukan belanja produk vitamin di e-commerce minimal dua kali selama pandemi, berdomisili di DKI Jakarta, dan berusia ≥17 tahun. Data diolah menggunakan IBM SPSS Statistics 22 dan AMOS versi 21. Hasil penelitian menunjukkan bahwa pengaruh online shopping anxiety terhadap online shopping intention adalah signifikan negatif, pengaruh perceived ease of use terhadap online shopping intention adalah signifikan positif, pengaruh perceived benefit terhadap online shopping intention adalah signifikan positif dan pengaruh online shopping anxiety terhadap perceived ease of use adalah signifikan negatif.
Kata Kunci: Online Shopping Anxiety, Perceived Ease of Use, Perceived Benefit, Online Shopping Intention, Produk Vitamin, E-Commerce