bluuebunny/crossref_metadata_2025_split huggingface dataset:
2D Conjugated Metal–Organic Frameworks Embedded with Iodine for High‐Performance Ammonium‐Ion Hybrid Supercapacitors
Authors: Gao Mingming , Wang Zhiyong , Liu Zaichun , Huang Ying , Wang Faxing , Wang Mingchao , Yang Sheng , Li Junke , Liu Jinxin , Qi Haoyuan , Zhang Panpan , Lu Xing , Feng Xinliang 
Published: August 2023

AbstractAmmonium ions (NH4+) are emerging non‐metallic charge carriers for advanced electrochemical energy storage devices, due to their low cost, elemental abundance, and environmental benignity. However, finding suitable electrode materials to achieve rapid diffusion kinetics for NH4+ storage remains a great challenge. Herein, a 2D conjugated metal–organic framework (2D c‐MOF) for immobilizing iodine, as a high‐performance cathode material for NH4+ hybrid supercapacitors, is reported. Cu‐HHB (HHB = hexahydroxybenzene) MOF embedded with iodine (Cu‐HHB/I2) features excellent electrical conductivity, highly porous structure, and rich accessible active sites of copper‐bis(dihydroxy) (Cu─O4) and iodide species, resulting in a remarkable areal capacitance of 111.7 mF cm−2 at 0.4 mA cm−2. Experimental results and theoretical calculations indicate that the Cu─O4 species in Cu‐HHB play a critical role in binding polyiodide and suppressing its dissolution, as well as contributing to a large pseudocapacitance with adsorbed iodide. In combination with a porous MXene anode, the full NH4+ hybrid supercapacitors deliver an excellent energy density of 31.5 mWh cm−2 and long‐term cycling stability with 89.5% capacitance retention after 10 000 cycles, superior to those of the state‐of‐the‐art NH4+ hybrid supercapacitors. This study sheds light on the material design for NH4+ storage, enabling the development of novel high‐performance energy storage devices.
Anode‐Less All‐Solid‐State Batteries Operating at Room Temperature and Low Pressure
Authors: Oh Jihoon , Choi Seung Ho , Kim Ji Young , Lee Jieun , Lee Taegeun , Lee Nohjoon , Lee Taeyong , Sohn Yeeun , Chung Woo Jun , Bae Ki Yoon , Son Samick , Choi Jang Wook 
Published: August 2023

AbstractAnode‐less all‐solid‐state batteries (ASSBs) are being targeted for next‐generation electric mobility owing to their superior energy density and safety as well as the affordability of their materials. However, because of the anode‐less configuration, it is nontrivial to simultaneously operate the cell at room temperature and low pressure as a result of the sluggish reaction kinetics of lithium (de)plating and the formation of interfacial voids. This study overcomes these intrinsic challenges of anode‐less ASSBs by introducing a dual thin film consisting of a magnesium upper layer with a Ti3C2Tx MXene buffer layer underneath. The Mg layer enables reversible Li plating and stripping at room temperature by reacting with Li via a (de)alloying reaction with a low reaction barrier. The MXene buffer layer maintains the electrolyte‐electrode interface by inhibiting the formation of voids even at low pressure of 2 MPa owing to the high ductility of MXene. This study highlights the importance of a combined chemical and mechanical approach when designing anode‐less electrodes for practical adaptation for anode‐less ASSBs.
Carbonate Hydrogenated to Formate in the Aqueous Phase over Nickel/TiO2 Catalysts
Authors: Zhang Xiaochen , Li Aowen , Tang Haoyi , Xu Yao , Qin Xuetao , Jiang Zheng , Yu Qiaolin , Zhou Wu , Chen Liwei , Wang Meng , Liu Xi , Ma Ding 
Published: August 2023

AbstractCarbonate hydrogenation to formate is a promising route to convert captured carbon dioxide into valuable chemicals, thus reducing carbon emissions and creating a revenue return. Developing inexpensive catalysts with high activity, selectivity, and stability remains challenging. We report a supported non‐noble metal catalyst, Ni/TiO2, with great selectivity over 96 % and excellent stability in catalyzing the conversion of carbonate into formate in aqueous solution. Ni0 and Ni2+ species are both observed in Ni/TiO2 catalysts, and the synergistic effect of these two Ni components leads to high activity and high selectivity of carbonate hydrogenation to formate.
Annulation‐Induced Hidden Reactivity of the 1,2,4‐Triazole Backbone
Authors: Karak Pirudhan , Sreelakshmi P. A. , Chakraborty Barsha , Pal Manisha , Khatua Bitasik , Lal Koner Apurba , Choudhury Joyanta 
Published: August 2023

AbstractTriazoles are an important class of compounds with widespread applications. Functionalization of the triazole backbone is thus of significant interest. In comparison to 1,2,3‐triazoles, C−H activation‐functionalization of the congeners 1,2,4‐triazoles is surprisingly underdeveloped. Indeed, no such C−H activation‐functionalization has been reported for 4‐substituted 1,2,4‐triazole cores. Furthermore, although denitrogenative ring‐opening of 1,2,3‐triazoles is well‐explored, 1,2,4‐triazole/triazolium substrates have not been known to exhibit N−N bond‐cleaving ring‐opening reactivity so far. In this work, we unveiled an unusual hidden reactivity of the 1,2,4‐triazole backbone involving the elusive N−N bond‐cleaving ring‐opening reaction. This new reactivity was induced by a Satoh‐Miura‐type C−H activation‐annulation at the 1,2,4‐triazole motif appended with a pyridine directing group. This unique reaction allowed ready access to a novel class of unsymmetrically substituted 2,2′‐dipyridylamines, with one pyridine ring fully‐substituted with alkyl groups. The unsymmetrical 2,2′‐dipyridylamines were utilized to access unsymmetrical boron‐aza‐dipyridylmethene fluorescent dyes. Empowered with desirable optical/physical properties such as large Stokes shifts and suitable hydrophobicity arising from optimal alkyl chain length at the fully‐substituted pyridine‐ring, these dyes were used for intracellular lipid droplet‐selective imaging studies, which provided useful information toward designing suitable lipid droplet‐selective imaging probes for biomedical applications.
The Future of (Radio)‐Labeled Compounds in Research and Development within the Life Science Industry
Authors: Derdau Volker , Elmore Charles S. , Hartung Thomas , McKillican Bruce , Mejuch Tom , Rosenbaum Claudia , Wiebe Christine 
Published: August 2023

AbstractIn this review the applications of isotopically labeled compounds are discussed and put into the context of their future impact in the life sciences. Especially discussing their use in the pharma and crop science industries to follow their fate in the environment, in vivo or in complex matrices to understand the potential harm of new chemical structures and to increase the safety of human society.
Glycerol dehydration catalyzed by solid acid in nonthermal plasma and simulation analysis of plasma electric field
Authors: Liu Lu , Ye Xiaofei Philip , Datta Ashim 
Published: August 2023

AbstractNonthermal plasma (NTP), for the first time, was integrated in glycerol dehydration reaction catalyzed by silicotungstic acid supported on mesoporous silica with argon as the carrier and discharge gas. A range of reaction temperatures (220–320°C) and NTP discharge field strengths (2.06–6.87 kV/cm) were studied for the individual and interactive effects regarding the glycerol conversion and product selectivity. Results showed that the presence of NTP always improved the glycerol conversion, and NTP increased acrolein selectivity if properly conditioned. An optimal condition of 275°C and 4.58 kV/cm NTP field strength achieved a glycerol conversion of 94.4 mol%, acrolein selectivity of 88.0 mol%, with an acrolein yield of 83.1 mol%, representing a 10% improvement in acrolein production over that conducted at the same temperature but without NTP. Results of this study will also have significant implication for other heterogeneously catalyzed dehydration reactions. Simulation of the high‐voltage electric field distribution as function of NTP electrical conductivity and relative permittivity of catalyst materials also offers insight for the future design of reactors and catalysts.
Synthesis of a network‐structured polymer with low viscosity effect and its use as filtrate reducer for water‐based drilling fluids
Authors: Lin Zhengwen , Li Fang , Liu Xinyu , Su Junlin 
Published: August 2023

AbstractWith the development of deep formations, high temperature and high salinity seriously affect the rheology and filtration performance of water‐based drilling fluids. Therefore, in this study, a network‐structured polymer (DSD‐β‐CD) with low viscosity effect was synthesized using β‐cyclodextrin (β‐CD) as the backbone and N,N‐dimethylacrylamide (DMAA), sodium p‐styrene sulfonate (SSS), and dimethyl diallyl ammonium chloride (DMDAAC) as monomers. The polymer was analyzed by transmission electron microscope, Fourier transform infrared spectrum, nuclear magnetic resonance, and thermogravimetric analysis. The filtrate reducer in this study showed excellent temperature and salt resistance, the filtration loss of the water‐based drilling fluid containing 3.5% DSD‐β‐CD and 18% NaCl was 5.1 mL after hot rolling at 220°C for 16 h. Additionally, its viscosity was 0.2 mPa s higher than that of the water‐based drilling fluid with 18% NaCl, showing an excellent low viscosity effect. The filtration loss reduction mechanism of DSD‐β‐CD was investigated by viscosity analysis, mud cake analysis, particle size distribution, hydration swelling of bentonite, and Zeta potential. The results showed that DSD‐β‐CD could be adsorbed on the surface of bentonite particles through hydrogen bonds and ionic bonds, which increased the dispersion of bentonite particle and the compactness of the mud cake, thus reducing the filtration loss.
Anti–Citrullinated Protein Antibodies With Multiple Specificities Ameliorate Collagen Antibody–Induced Arthritis in a Time‐Dependent Manner
Authors: Gomez Alejandro M. , Brewer R. Camille , Moon Jae‐Seung , Acharya Suman , Kongpachith Sarah , Wang Qian , Jahanbani Shaghayegh , Wong Heidi H. , Lanz Tobias V. , Love Zelda Z. , Min‐Oo Gundula , Niedziela‐Majka Anita , Robinson William H. 
Published: August 2023

ObjectiveAnti–citrullinated protein antibodies (ACPAs) are highly specific for rheumatoid arthritis (RA) and have long been regarded as pathogenic. Despite substantial in vitro evidence supporting this claim, reports investigating the proinflammatory effects of ACPAs in animal models of arthritis are rare and include mixed results. Here, we sequenced the plasmablast antibody repertoire of a patient with RA and functionally characterized the encoded ACPAs.MethodsWe expressed ACPAs from the antibody repertoire of a patient with RA and characterized their autoantigen specificities on antigen arrays and enzyme‐linked immunosorbent assays. Binding affinities were estimated by bio‐layer interferometry. Select ACPAs (n = 9) were tested in the collagen antibody–induced arthritis (CAIA) mouse model to evaluate their effects on joint inflammation.ResultsRecombinant ACPAs bound preferentially and with high affinity (nanomolar range) to citrullinated (cit) autoantigens (primarily histones and fibrinogen) and to auto‐cit peptidylarginine deiminase 4 (PAD4). ACPAs were grouped for in vivo testing based on their predominant cit‐antigen specificities. Unexpectedly, injections of recombinant ACPAs significantly reduced paw thickness and arthritis severity in CAIA mice as compared with isotype‐matched control antibodies (P ≤ 0.001). Bone erosion, synovitis, and cartilage damage were also significantly reduced (P ≤ 0.01). This amelioration of CAIA was observed for all the ACPAs tested and was independent of cit‐PAD4 and cit‐fibrinogen specificities. Furthermore, disease amelioration was more prominent when ACPAs were injected at earlier stages of CAIA than at later phases of the model.ConclusionRecombinant patient‐derived ACPAs ameliorated CAIA. Their antiinflammatory effects were more preventive than therapeutic. This study highlights a potential protective role for ACPAs in arthritis.image
Elevation of IL‐17 Cytokines Distinguishes Kawasaki Disease From Other Pediatric Inflammatory Disorders
Authors: Brodeur Kailey E. , Liu Meng , Ibanez Daniel , de Groot Mareike J. , Chen Liang , Du Yan , Seyal Eman , Laza‐Briviesca Raquel , Baker Annette , Chang Joyce C. , Chang Margaret H. , Day‐Lewis Megan , Dedeoglu Fatma , Dionne Audrey , de Ferranti Sarah D. , Friedman Kevin G. , Halyabar Olha , Lo Mindy S. , Meidan Esra , Sundel Robert P. , Henderson Lauren A. , Nigrovic Peter A. , Newburger Jane W. , Son Mary Beth , Lee Pui Y. 
Published: August 2023

ObjectiveKawasaki disease (KD) is a systemic vasculitis of young children that can lead to development of coronary artery aneurysms. We aimed to identify diagnostic markers to distinguish KD from other pediatric inflammatory diseases.MethodsWe used the proximity extension assay to profile proinflammatory mediators in plasma samples from healthy pediatric controls (n = 30), febrile controls (n = 26), and patients with KD (n = 23), multisystem inflammatory syndrome in children (MIS‐C; n = 25), macrophage activation syndrome (n = 13), systemic and nonsystemic juvenile idiopathic arthritis (n = 14 and n = 10, respectively), and juvenile dermatomyositis (n = 9). We validated the key findings using serum samples from additional patients with KD (n = 37) and febrile controls (n = 28).ResultsHigh‐fidelity proteomic profiling revealed distinct patterns of cytokine and chemokine expression across pediatric inflammatory diseases. Although KD and MIS‐C exhibited many similarities, KD differed from MIS‐C and other febrile diseases in that most patients exhibited elevation in one or more members of the interleukin‐17 (IL‐17) cytokine family, IL‐17A, IL‐17C, and IL‐17F. IL‐17A was particularly sensitive and specific, discriminating KD from febrile controls with an area under the receiver operator characteristic curve of 0.95 (95% confidence interval 0.89–1.00) in the derivation set and 0.91 (0.85–0.98) in the validation set. Elevation of all three IL‐17‐family cytokines was observed in over 50% of KD patients, including 19 of 20 with coronary artery aneurysms, but was rare in all other comparator groups.ConclusionElevation of IL‐17 family cytokines is a hallmark of KD and may help distinguish KD from its clinical mimics.image
Alloying and Nanotechnology for Sn‐based Anode Materials: Paving the Way to the Future of Lithium‐Ion Batteries
Authors: Ding Shukai , Zhang Le , Su Qingmei , Du Gaohui 
Published: August 2023

AbstractThe development of lithium‐ion batteries (LIBs) with high energy density is of utmost importance to meet the growing demand for 3 C devices and electric automobiles worldwide. Over the past three decades, there has been significant interest in Sn‐based anode materials for LIBs, owing to their high specific capacity and low charge/discharge plateau. Two primary strategies, namely alloying and nanotechnology, have been extensively investigated to enhance the electrochemical performance of Sn‐based anodes. However, the complete understanding and recognition of the full potential of these strategies, both in the past and future, remains incomplete. This review aims to provide a comprehensive discussion on the development of Sn‐based anodes prepared using the aforementioned strategies. Furthermore, it emphasizes the practical potential of Sn‐based anodes and the associated preparation technologies for large‐scale production. Establishing a strong connection between these technologies and high‐performance Sn‐based composites is crucial, and this objective will be achieved through an extensive comparison and detailed introduction of relevant concepts. By addressing these aspects, this review will contribute to the advancement of Sn‐based anodes research and its application in high‐performance LIBs, ultimately driving progress in the field of energy storage.
Information search processing affects social decisions
Authors: Wei Zi‐Han , Liang Yan , Liang Ci‐Juan , Liu Hong‐Zhi 
Published: August 2023

AbstractSocial decisions often require individuals to balance conflicts between their own selfish interests and the need for equality. The way information about available options is presented can have an impact on how people process information and make social decisions. In this study, we examined the effect of information presentation on social decisions in a mini‐dictator game, where participants must make binary choices about how to allocate money between themselves and another participant. We conducted two tasks with different presentation styles: the attribute‐based task, where attributes such as own payoffs or others' payoffs were displayed sequentially, and the alternative‐based task, where alternatives were displayed sequentially. We found that participants in the attribute‐based task made more selfish choices and were less sensitive to equality than those in the alternative‐based task. The direction of information search and the complexity level of information processing played a mediating role in the effect of task on social decisions. Our findings highlight the relationship between information search and social decisions, shedding light on the mechanisms and processes that underlie social decision‐making.
Bioengineered chimeric tRNA/pre‐miRNAs as prodrugs in cancer therapy
Authors: Rafieenia Fatemeh , Ebrahimi Seyed Omar , Emadi Ensieh sadat , Taheri Forough , Reiisi Somayeh 
Published: August 2023

AbstractToday, biologic prodrugs have led to targeting specific tumor markers and have increased specificity and selectivity in cancer therapy. Various studies have shown the role of ncRNAs in cancer pathology and tumorigenesis and have suggested that ncRNAs, especially miRNAs, are valuable molecules in understanding cancer biology and therapeutic processes. Most miRNAs‐based research and treatment are limited to chemically synthesized miRNAs. Synthetic alterations in these miRNA mimics may affect their folding, safety profile, and even biological activity. However, despite synthetic miRNA mimics produced by automated systems, various carriers could be used to achieve efficient production of bioengineered miRNAs through economical microbial fermentation. These bioengineered miRNAs as biological prodrugs could provide a new approach for safe therapeutic methods and drug production. In this regard, bioengineered chimeric miRNAs could be selectively processed to mature miRNAs in different types of cancer cells by targeting the desired gene and regulating cancer progression. In this article, we aim to review bioengineered miRNAs and their use in cancer therapy, as well as offering advances in this area, including the use of chimeric tRNA/pre‐miRNAs.
Staying in my lane: An exploration of counsellors' and psychotherapists' understanding and use of nutrition in the therapy room
Authors: Leonard Jayne 
Published: August 2023

AbstractIntroduction and AimsA significant body of research has found a positive association between a healthy diet and good mental health, and between an unhealthy diet and poorer mental health. Despite this, nutritional education and methods of intervention remain largely absent from psychotherapy training and practice, and mental health professionals worldwide report poor nutritional literacy. This study aims to explore how therapists understand and view diet and nutrition in the context of mental health, and whether, and how, they use this knowledge with clients.Methodology and MethodsThis qualitative study used an interpretative phenomenological analysis approach when collecting and analysing the data. Participants were from throughout Ireland, with recruitment taking place via an email call for participants. A brief pre‐interview conversation ensured respondents fulfilled the inclusion criteria. Six integrative/pluralistic psychotherapists were interviewed about their views and understanding of nutrition in relation to mental health and psychotherapy, as well as about their training, supervision and their use of diet‐related interventions with clients.FindingsFour master themes were identified: “therapist experiences and beliefs,” which relates to how participants experienced and viewed nutrition on personal and professional levels; “meanings associated with food and nutrition” by therapists, and their perception of the meanings their clients placed upon food; “boundaries and barriers” that therapists experienced or perceived when it came to discussing nutrition with clients; and “the silence around nutrition in psychotherapy,” in terms of its absence from training, supervision and peer discussions.Discussion and ConclusionsThe study highlights the importance and meaning that individuals place on nutrition for mental well‐being, while also highlighting its absence from training programmes, supervision sessions and discussions with peers and within the wider profession. The study further indicates potential boundary issues and ethical concerns as a result of the disparity between training/supervision and client needs/therapist practice.
Artificial intelligence consumer behavior: A hybrid review and research agenda
Authors: Jain Varsha , Wadhwani Ketan , Eastman Jacqueline K. 
Published: August 2023

AbstractThe advancement of artificial intelligence (AI) technology and its applications has drastically transformed consumer behavior (CB). As consumers interact with these applications on multiple platforms and touchpoints, it becomes crucial to understand how these interactions affect consumer behavior and its components, including personality, attitude, engagement, decision‐making, and trust. The research on the relationship between artificial intelligence and consumer behavior (hereafter referred to as AI CB) revolves around these topics and has grown exponentially in recent years. A rigorous review is required to provide directions for future studies by comprehending the extensive literature, understanding research gaps, and identifying the future directions for scholarly work. This article aims to address this research gap by analyzing 107 AI CB articles using the bibliometric and framework‐based methodology to provide insights into publication trends, dominant theories, methods, antecedents, decisions, and outcomes in the AI CB literature. Most importantly, the review identifies clusters of research fronts and provides a thematic framework for current research. These clusters or themes relate to AI interaction with consumer behavior dimensions, including consumer acceptance and trust, consumer interaction and engagement, attitude and personality, decision‐making, and adoption. This thematic framework and TCM‐ADO analysis offer future research directions to advance theory development and have implications for industry and society.