bluuebunny/crossref_metadata_2025_split huggingface dataset:
Network Representation of fMRI Data Using Visibility Graphs: The Impact of Motion and Test-Retest Reliability
Authors: Poudel Govinda R. , Sharma Prabin , Lorenzetti Valentina , Parsons Nicholas , Cerin Ester 
Published: February 2024

AbstractVisibility graphs provide a novel approach for analysing time-series data. Graph theoretical analysis of visibility graphs can provide new features for data mining applications in fMRI. However, visibility graphs features have not been used widely in the field of neuroscience. This is likely due to a lack of understanding of their robustness in the presence of noise (e.g., motion) and their test-retest reliability. In this study, we investigated visibility graph properties of fMRI data in the human connectome project (N = 1010) and tested their sensitivity to motion and test-retest reliability. We also characterised the strength of connectivity obtained using degree synchrony of visibility graphs. We found that strong correlation (r > 0.5) between visibility graph properties, such as the number of communities and average degrees, and motion in the fMRI data. The test-retest reliability (Intraclass correlation coefficient (ICC)) of graph theoretical features was high for the average degrees (0.74, 95% CI = [0.73, 0.75]), and moderate for clustering coefficient (0.43, 95% CI = [0.41, 0.44]) and average path length (0.41, 95% CI = [0.38, 0.44]). Functional connectivity between brain regions was measured by correlating the visibility graph degrees. However, the strength of correlation was found to be moderate to low (r < 0.35). These findings suggest that even small movement in fMRI data can strongly influence robustness and reliability of visibility graph features, thus, requiring robust motion correction strategies prior to data analysis. Further studies are necessary for better understanding of the potential application of visibility graph features in fMRI.
Strategies and Barriers to Reconcile Pest Management with Insect Conservation in Temperate and Boreal Forests
Authors: Gazzea Elena , Battisti Andrea , Marini Lorenzo 
Published: February 2024

Abstract
Purpose of Review
To describe how general prescriptions to protect temperate and boreal forests against pests have been affecting the conservation of insect diversity, (2) to identify potential conflicts between biodiversity conservation actions and pest control, and (3) to provide future directions to reconcile forest pest management with insect conservation.

Recent Findings
Despite dealing with the same habitats and organisms, forest pest management and insect conservation have been separate disciplines, often pursuing conflicting goals. However, there is a large intersection between the two, as interventions to control pests can have repercussions on biodiversity and vice versa. In several regions, forest pest management is shifting from reactive measures to contain on-going outbreaks to proactive strategies to create forest landscapes that are more resistant and resilient against pests in the long-term. These developments suggest a possible convergence between pest management and insect conservation objectives.

Summary
Several reactive measures adopted to control pests can cause negative impacts on non-target insects, although effects are sometimes localized and often context-dependent. Following ecological, economic, and social considerations, pest management has been evolving towards diversifying forests across multiple spatial scales to reduce the severity of outbreaks and the risk of damage. Such strategies concur with multiple conservation goals to increase insect diversity across intensive forest landscapes. Insect conservation has traditionally targeted saproxylic organisms, neglecting the conservation of other insect guilds and seldom assessing side effects on pests. Despite some important knowledge gaps, we propose complementary approaches to combine multiple diversification strategies at the landscape scale to reconcile pest management with insect conservation.
Laser-Induced and MOF-Derived Metal Oxide/Carbon Composite for Synergistically Improved Ethanol Sensing at Room temperature
Authors: Lim Hyeongtae , Kwon Hyeokjin , Kang Hongki , Jang Jae Eun , Kwon Hyuk-Jun 
Published: February 2024

AbstractAdvancements in sensor technology have significantly enhanced atmospheric monitoring. Notably, metal oxide and carbon (MOx/C) hybrids have gained attention for their exceptional sensitivity and room-temperature sensing performance. However, previous methods of synthesizing MOx/C composites suffer from problems, including inhomogeneity, aggregation, and challenges in micropatterning. Herein, we introduce a refined method that employs a metal–organic framework (MOF) as a precursor combined with direct laser writing. The inherent structure of MOFs ensures a uniform distribution of metal ions and organic linkers, yielding homogeneous MOx/C structures. The laser processing facilitates precise micropatterning (< 2 μm, comparable to typical photolithography) of the MOx/C crystals. The optimized MOF-derived MOx/C sensor rapidly detected ethanol gas even at room temperature (105 and 18 s for response and recovery, respectively), with a broad range of sensing performance from 170 to 3,400 ppm and a high response value of up to 3,500%. Additionally, this sensor exhibited enhanced stability and thermal resilience compared to previous MOF-based counterparts. This research opens up promising avenues for practical applications in MOF-derived sensing devices.
The Influence of Filling System Design on Quality Performance in Gray Iron
Authors: Heyworth Robert 
Published: February 2024

AbstractSignificant evidence now supports the quality improvement seen in castings that employ naturally pressurized filling systems in their production. However, despite the documented evidence for improvement, these systems have not become ubiquitous. Gray iron, the industry’s most prominent alloy, has been particularly slow to accept the shift in system design. The suggested tolerability of gray iron to turbulence, the market’s price sensitivity, and the perceived economics of naturally pressurized systems are potential factors that have hindered adoption. However, if, through improved quality, the economic justification for these systems can be made in this adverse setting, there is a merit in their application to all alloys and processes. A sample gray iron part, currently being produced in a foundry environment with known porosity issues, was selected, to which a new system and several basin designs were applied. A mixed method analysis of casting simulations, production trials, and economic and environmental modeling was used to evaluate system performance. The results show a strong association between filling system design and sub-surface porosity. However, no association was found between basin design and porosity occurrence at lower porosity levels. Nevertheless, the economic and environmental modeling highlights that quality-orientated systems yield significant financial and environmental savings for the organization due to reduced scrap levels. These findings imply that quality-orientated system designs should be employed even when cost is the most critical measure.
Regional decline and structural changes in Northeast China: an exploratory space–time approach
Authors: Chen Yilin 
Published: February 2024

AbstractLiterature on New Economic Geography (NEG) highlights the importance of spatial concentration and spillover effects in economic growth or decline. Northeast China, as an old industrial base, is experiencing a regional decline since its transition to the post-industrial stage. Therefore, what is the main sectoral composition in Northeast China and how does this influence regional decline? To what extent do spatial spillovers play a role before and during the regional decline of Northeast China? Based on these questions, we investigated the spatial connections between regional decline and structural changes in Northeast China over three development periods: Rust Belt (1995–2002), revival (2002–2015), and decline (2015–2019). The recent exploratory space–time data analysis was employed on prefecture-level income and its structural change components (sectoral output and employment ratio). We found that the possible reason for the regional decline in Northeast China is premature deindustrialisation. Spatial co-decline in the employment of industry and construction, the primary source of regional decline, facilitates most of the space–time patterns of the regional income. Agglomeration of the agricultural sector has shifted to the north, while industry and construction have gravitated towards the middle and south, with no clear spatial patterns in the service sector. Dependence on natural resources has a "lock-in effect" that inhibits the transition from industry to services, so industry and construction remain the most efficient in Northeast China. Strengthening spatial connections is essential for local governments to develop service sectors and overcome declining conditions.
Characterization and pathogenicity of fungal species associated with hazelnut trunk diseases in North-western Italy
Authors: Martino Ilaria , Monchiero Matteo , Gullino M. Lodovica , Guarnaccia Vladimiro 
Published: February 2024

Abstract
Italy is the second largest hazelnut producer worldwide and Piedmont is one of the most productive regions in the country. The changing climatic condition and fungal trunk diseases (FTD) can have a severe impact on this crop. Particularly, the considerable spread of Cytospora cankers (‘Mal dello stacco’) and dieback represent a serious concern for producers. Thus, considering the limited studies on the causal agents, different surveys were conducted in seven hazelnut orchards during 2021 and 2022. Eight fungal species were identified: Anthostoma decipiens, Botryosphaeria dothidea, Diaporthe eres, Dia. rudis, Diplodia seriata, Dip. subglobosa, Dothiorella parva and Nothophoma brennandiae. Species identification was achieved through multilocus phylogeny and morphology assessment. All the fungal species were pathogenic on healthy hazelnut plants (cultivar Tonda Gentile) and A. decipiens and Dia. eres were the most aggressive. The present study is the first report of B. dothidea and Dia. eres as causal agents of FTD on hazelnut in Italy and of Dia. rudis, Dip. subglobosa and N. brennandiae worldwide. Moreover, the study provides clarification of the fungal pathogens associated with FTD on this crop in Piedmont, thus laying the base for further studies on epidemiology, ecology and management strategies.
Oral intake of bucillamine, carvedilol, metformin, or phenformin does not protect against UVR-induced squamous cell carcinomas in hairless mice
Authors: Pihl Celina , Bjerring Peter , Andersen Flemming , Haedersdal Merete , Lerche Catharina M. 
Published: February 2024

AbstractSquamous cell carcinoma represents the second most common type of keratinocyte carcinoma with ultraviolet radiation (UVR) making up the primary risk factor. Oral photoprotection aims to reduce incidence rates through oral intake of photoprotective compounds. Recently, drug repurposing has gained traction as an interesting source of chemoprevention. Because of their reported photoprotective properties, we investigated the potential of bucillamine, carvedilol, metformin, and phenformin as photoprotective compounds following oral intake in UVR-exposed hairless mice. Tumour development was observed in all groups in response to UVR, with only the positive control (Nicotinamide) demonstrating a reduction in tumour incidence (23.8%). No change in tumour development was observed in the four repurposed drug groups compared to the UV control group, whereas nicotinamide significantly reduced carcinogenesis (P = 0.00012). Metformin treatment significantly reduced UVR-induced erythema (P = 0.012), bucillamine and phenformin increased dorsal pigmentation (P = 0.0013, and P = 0.0005), but no other photoprotective effect was observed across the repurposed groups. This study demonstrates that oral supplementation with bucillamine, carvedilol, metformin, or phenformin does not affect UVR-induced carcinogenesis in hairless mice.
Graphical Abstract
The pope, a knight and a bishop on the edge of Christendom: the politics of exclusion in thirteenth-century Ireland
Authors: Marshall John 
Published: February 2024

AbstractThis article provides a re-appraisal of the land dispute between the lord of Leinster, William Marshal, and the bishop of Ferns, Ailbe Ó Máelmuaid, in the 1210s. In 1215, Ailbe petitioned the pope to solve the dispute, leading to the pronouncement of an interdict and excommunication against the Marshal. It is argued that after King John of England died and the Marshal became regent of England in 1216, the papal stance towards the land dispute changed and the Marshal enjoyed favour in Rome, thus shutting the roads to redress for the bishop of Ferns. Now the most powerful man in the Plantagenet dominions, William Marshal used his position as regent to begin the policy of English discrimination against Gaelic-born bishops for episcopal sees in Ireland. This article uses this dispute as a means of exploring Ireland's position within wider Latin Christendom against the background of the papacy's crusading agenda.
Colonialist intervention in a metropolitan revolution: reconsidering A remonstrance of divers remarkeable passages
Authors: Kelsey Sean 
Published: February 2024

AbstractThis article presents findings from a fresh examination of a familiar source, shedding new light on the creation of one of the best-known contemporary accounts of the 1641 Irish uprising. It is argued that a text usually regarded as the work of Henry Jones, dean of Kilmore, ought to be understood as the intellectual property of both a team of authors and their sponsors, a New English faction at Dublin Castle with long-standing ambitions to crush popery and entrench planter hegemony in Ireland. It is argued that this group's objective was to strengthen the hand of the populist ‘junto’ at Westminster, led by John Pym, that was wrestling with Charles I for political and constitutional supremacy in English affairs in the winter and spring of 1641–2. The colonialists contributed to this metropolitan revolution by rendering safe to handle the Irish rebels’ politically-explosive seditious slander that their uprising had been raised by royal command. The notorious falsehood of the rebels’ claims has obscured the demonstrably underhand and fundamentally deceitful calculation with which the colonialists helped introduce it into mainstream English political culture, in order to isolate the king further and weaken his personal authority on both sides of the Irish Sea.
The Weaver Street bombing in Belfast 1922: violence, politics and memory
Authors: Dobrianska Nadia 
Published: February 2024

AbstractOn 13 February 1922, an unidentified person threw a bomb into Weaver Street, which was full of Catholic children at play, killing four children and two women. The bombing became a locus of political controversy between the British government, the Provisional Government of the Irish Free State and the government of Northern Ireland, and became the archetypal story of innocent Catholic lives taken by the intercommunal conflict in the six counties which became Northern Ireland in 1920‒22. This article seeks to contribute to the understanding of the role of this intercommunal conflict in Irish and British politics, using the Weaver Street bombing as a case study. This article analyses nationalist representation of the conflict as an orchestrated campaign against Catholics, ‘a pogrom’; unionist representation of the conflict as loyalist self-defence against the I.R.A.; and the British government's effort to publicly maintain neutrality in the conflict.
British Army intelligence in provincial Ireland, 1919‒1921: organisation, outcomes and the 6th Division blacklist
Authors: Bielenberg Andy , Borgonovo John 
Published: February 2024

AbstractIntelligence played a critical role in the Irish War of Independence, though debate remains about the effectiveness of British information-gathering. Historians have focused largely on the intelligence war in Dublin. This article examines British Army intelligence in the 6th Division area (roughly the southern third of the island). It will contextualise British military intelligence before the conflict and traces the slow development of an intelligence organisation in the 6th Division. It then considers the sources and nature of British information gathering, particularly interrogation of prisoners and the collection and analysis of captured documents. Military intelligence summaries and a ‘Blacklist’ of I.R.A. suspects across the 6th Division are used to ascertain the quality of military intelligence products during the final stages of the conflict. The ‘Blacklist’ can be contrasted with I.R.A. unit arrest data and leadership lists, to assess the effectiveness of British military intelligence at a county level. This comparison provides a new measure of British performance, clearly revealing the limitations of British military intelligence in the 6th Division, particularly when compared to relatively more successful results achieved by crown forces in the Dublin District.
Response of the Central Pacific Intertropical Convergence Zone to Northern Hemisphere Cooling During the Last Glacial Maximum and Heinrich Stadial 1
Authors: Kim Mun Gi , Seo Inah , Hyeong Kiseong 
Published: February 2024

AbstractThe latitudinal position of the Intertropical Convergence Zone (ITCZ) reflects the energy imbalance between the hemispheres. Southward displacements of the ITCZ during the Last Glacial Maximum (LGM; 19–26.5 ka) and Heinrich Stadial 1 (HS1; 14.6–17.5 ka), are widely accepted, but their magnitude is controversial. Geochemistry of detrital fractions in down‐core sediments collected from 6°N to equator along the 131.5°W transect reveal a distinct shift in εNd, La/Yb, and La–Sc–Th composition from predominantly northern hemisphere‐sourced to mixed northern and southern hemisphere‐sourced signal at 3°N–4°N during the LGM and 3°N–6°N during HS1. These contrasting provenance signals point to the past ITCZ functioning as a dust barrier. Given that a comparable geochemical demarcation currently occurs at 6°N–7°N, our data suggest that the ITCZ migrated southward by ∼3° during the LGM and ∼1°–3° during HS1 relative to its modern position in the central Pacific.
Analysis of Beach Cusp Formation and Evolution Using High‐Frequency 3D Lidar Scans
Authors: O’Dea Annika , Brodie Katherine 
Published: February 2024

AbstractIn this study, beach cusp characteristics were explored using 15 months of 3D lidar scans collected hourly at the Field Research Facility in Duck, NC. Fourier analyses were performed on lidar‐derived beach elevation contours to generate spatial cusp spectra. Active cusp events were identified on the basis of the location and magnitude of each spectrum's peak and used to evaluate conditions during cusp formation and evolution. Cusps primarily developed during times with normally‐incident, long period, low energy wave conditions with low frequency spread, and reflective beach conditions. The upper and lower beaches often exhibited different behavior and morphologies, with persistent upper‐beach cusps lasting days to months and dynamic lower‐beach cusps evolving over individual tidal cycles. At times, beaches exhibiting multiple cusp systems reverted to a single cusp system extending over the entire beach when the high‐tide waterline reached the upper‐beach cusps, with the location and spacing of the resulting lower‐beach cusps controlled by the upper‐beach cusps. These observations are consistent with a “morphological coupling” hypothesis proposing that hydrodynamic‐morphodynamic feedbacks between the swash and upper‐beach cusps can result in the formation of lower‐beach cusps with a related wavelength as the tide falls. However, there were also times when the high‐tide waterline reached the upper‐beach cusps that did not result in a unified beach state. These results suggest that while morphological coupling is often an important factor in controlling the development of new lower‐beach cusps, this coupling cannot initiate cusp formation in hydrodynamic conditions outside those favorable for cusp activity.
Wearable respiratory sensors for health monitoring
Authors: Yin Zhifu , Yang Yang , Hu Cong , Li Jinzhe , Qin Boyu , Yang Xue 
Published: February 2024

Abstract
Real-time monitoring and early warning of human health conditions is an important function of wearable devices. Along with the development of the Internet of Things and the medical drive for early detection and treatment, wearable devices will become increasingly important in the future. Compared with traditional sensors, wearable sensors with mechanical softness and deformability are able to adapt to geometric nonlinearities and deformations caused by motion that occurs in application scenarios, thus ensuring stable and effective signal output under various complex working conditions. Various novel sensing materials have been developed for the detection of various biomarkers of respiration over the past few years. Here, we summarize the latest innovations in wearable respiratory sensors, highlighting the dominant sensing materials, designs, sensing mechanisms, and clinical implications. Finally, the future challenges and directions of wearable respiratory sensors are outlined toward promoting advancement in the field of wearable respiratory monitoring.
Grid-like entorhinal representation of an abstract value space during prospective decision making
Authors: Nitsch Alexander , Garvert Mona M. , Bellmund Jacob L. S. , Schuck Nicolas W. , Doeller Christian F. 
Published: February 2024

AbstractHow valuable a choice option is often changes over time, making the prediction of value changes an important challenge for decision making. Prior studies identified a cognitive map in the hippocampal-entorhinal system that encodes relationships between states and enables prediction of future states, but does not inherently convey value during prospective decision making. In this fMRI study, participants predicted changing values of choice options in a sequence, forming a trajectory through an abstract two-dimensional value space. During this task, the entorhinal cortex exhibited a grid-like representation with an orientation aligned to the axis through the value space most informative for choices. A network of brain regions, including ventromedial prefrontal cortex, tracked the prospective value difference between options. These findings suggest that the entorhinal grid system supports the prediction of future values by representing a cognitive map, which might be used to generate lower-dimensional value signals to guide prospective decision making.
An integrated self-optimizing programmable chemical synthesis and reaction engine
Authors: Leonov Artem I. , Hammer Alexander J. S. , Lach Slawomir , Mehr S. Hessam M. , Caramelli Dario , Angelone Davide , Khan Aamir , O’Sullivan Steven , Craven Matthew , Wilbraham Liam , Cronin Leroy 
Published: February 2024

AbstractRobotic platforms for chemistry are developing rapidly but most systems are not currently able to adapt to changing circumstances in real-time. We present a dynamically programmable system capable of making, optimizing, and discovering new molecules which utilizes seven sensors that continuously monitor the reaction. By developing a dynamic programming language, we demonstrate the 10-fold scale-up of a highly exothermic oxidation reaction, end point detection, as well as detecting critical hardware failures. We also show how the use of in-line spectroscopy such as HPLC, Raman, and NMR can be used for closed-loop optimization of reactions, exemplified using Van Leusen oxazole synthesis, a four-component Ugi condensation and manganese-catalysed epoxidation reactions, as well as two previously unreported reactions, discovered from a selected chemical space, providing up to 50% yield improvement over 25–50 iterations. Finally, we demonstrate an experimental pipeline to explore a trifluoromethylations reaction space, that discovers new molecules.