bluuebunny/crossref_metadata_2025_split huggingface dataset:
Recent Advances in Hierarchical Porous Engineering of MOFs and Their Derived Materials for Catalytic and Battery: Methods and Application
Authors: Li Qian , Li Qun , Wang Zhewei , Zheng Xiaobo , Cai Shichang , Wu Jiabin 
Published: October 2023

AbstractHierarchical porous materials have attracted the attention of researchers due to their enormous specific surface area, maximized active site utilization efficiency, and unique structure and properties. In this context, metal–organic frameworks (MOFs) offer a unique mix of properties that make them particularly appealing as tunable porous substrates containing highly active sites. This review focuses on recent advances in the types and synthetic strategies of hierarchical porous MOFs and their derived materials. Furthermore, it highlights the relationship between the mass diffusion and transport of hierarchical porous structures and the pore size with examples and simulations, while identifying their potential and limitations. On this basis, how the synthesis conditions affect the structure and electrochemical properties of MOFs based hierarchical porous materials with different structures is discussed, highlighting the prospects and challenges for the synthetization, as well as further scientific research and practical applications. Finally, some insights into current research and future design ideas for advanced MOFs based hierarchical porous materials are presented.
Targeted Delivery of Sucrose‐Coated Nanocarriers with Chemical Cargoes to the Plant Vasculature Enhances Long‐Distance Translocation
Authors: Jeon Su‐Ji , Zhang Yilin , Castillo Christopher , Nava Valeria , Ristroph Kurt , Therrien Benjamin , Meza Leticia , Lowry Gregory V. , Giraldo Juan Pablo 
Published: October 2023

AbstractCurrent practices for delivering agrochemicals are inefficient, with only a fraction reaching the intended targets in plants. The surfaces of nanocarriers are functionalized with sucrose, enabling rapid and efficient foliar delivery into the plant phloem, a vascular tissue that transports sugars, signaling molecules, and agrochemicals through the whole plant. The chemical affinity of sucrose molecules to sugar membrane transporters on the phloem cells enhances the uptake of sucrose‐coated quantum dots (sucQD) and biocompatible carbon dots with β‐cyclodextrin molecular baskets (suc‐β‐CD) that can carry a wide range of agrochemicals. The QD and CD fluorescence emission properties allowed detection and monitoring of rapid translocation (<40 min) in the vasculature of wheat leaves by confocal and epifluorescence microscopy. The suc‐β‐CDs more than doubled the delivery of chemical cargoes into the leaf vascular tissue. Inductively coupled plasma mass spectrometry (ICP‐MS) analysis showed that the fraction of sucQDs loaded into the phloem and transported to roots is over 6.8 times higher than unmodified QDs. The sucrose coating of nanoparticles approach enables unprecedented targeted delivery to roots with ≈70% of phloem‐loaded nanoparticles delivered to roots. The use of plant biorecognition molecules mediated delivery provides an efficient approach for guiding nanocarriers containing agrochemicals to the plant vasculature and whole plants.
Ultra‐Low Loading of Ultra‐Small Fe3O4 Nanoparticles on Nonmodified CNTs to Improve Green EMI Shielding Capability of Rubber Composites
Authors: Wei Zijian , Cai Yifan , Zhan Yanhu , Meng Yanyan , Pan Na , Jiang Xiancai , Xia Hesheng 
Published: October 2023

AbstractFrom a material design perspective, the incorporation of Fe3O4@carbon nanotube (Fe3O4@CNT) hybrids is an effective approach for reconciling the contradictions of high shielding and low reflection coefficients, enabling the fabrication of green shielding materials and reducing the secondary electromagnetic wave pollution. However, the installation of Fe3O4 nanoparticles on nonmodified and nondestructive CNT walls remains a formidable challenge. Herein, a novel strategy for fabricating the above‐mentioned Fe3O4@CNTs and subsequently assembling segregated Fe3O4@CNT networks in natural rubber (NR) matrices is proposed. The advanced and unique structure, magnetism, and lossless conductivity endow the as‐obtained Fe3O4@CNT/NR with a shielding effectiveness (SE) of 63.8 dB and a low reflection coefficient of 0.24, which indicates a prominent green‐shielding capability that surpasses those of previously reported green‐shielding materials. Moreover, the specific SE reaches 531 dB cm−1, exceeding that of those of previously reported carbon/polymer composites. Meanwhile, the outstanding conductivity enables the composite to reach a saturation temperature of ≈95 °C at a driving voltage of 1.5 V with long‐term stability. Therefore, the as‐fabricated Fe3O4@CNT/rubber composites represent an important development in green‐shielding materials that are applied in cold environment.
Effect of Electrochemical Pre‐Lithiation on Layered Oxide Cathodes for Anode‐Free Lithium‐metal Batteries
Authors: Vanaphuti Panawan , Su Laisuo , Manthiram Arumugam 
Published: October 2023

AbstractDue to high energy density and lower manufacturing cost, anode‐free lithium‐metal batteries (AFLMBs) are attracting increasing attention. The challenges for developing them lie in inferior Coulombic efficiency and short cycle life due to the highly reactive lithium metal. Herein, an electrochemical pre‐lithiation strategy is applied to layered oxide cathodes, specifically LiNiO2 and LiCoO2, aiming to provide an additional lithium source and understand the effect on the cathode structure for AFLMBs. The mechanism for accommodating the excess Li depends on the structural stability of the cathodes where LiNiO2 forms lithiated Li2NiO2 with the excess lithium in the crystalline lattice while the excess lithium in LiCoO2 forms a Li2O phase. More importantly, an optimal amount of Li excess is necessary to maintain decent cycle stability and specific capacity in AFLMB, with 40% excess Li for LiNiO2 and 150% for LiCoO2. While the pre‐lithiation process causes particle pulverization depending on the amount of Li excess, LiCoO2 offers a much better cycle performance than LiNiO2 with a promising capacity retention of 80% after 300 cycles in AFLMB (vs 76% after 100 cycles for 40% Li excess in LiNiO2). This study provides a promising avenue for developing tailor‐made layered oxide cathodes for AFLMBs.
Microfluidics Coupled Mass Spectrometry for Single Cell Multi‐Omics
Authors: Zhang Dongxue , Qiao Liang 
Published: October 2023

AbstractPopulation‐level analysis masks significant heterogeneity between individual cells, making it difficult to accurately reflect the true intricacies of life activities. Microfluidics is a technique that can manipulate individual cells effectively and is commonly coupled with a variety of analytical methods for single‐cell analysis. Single‐cell omics provides abundant molecular information at the single‐cell level, fundamentally revealing differences in cell types and biological states among cell individuals, leading to a deeper understanding of cellular phenotypes and life activities. Herein, this work summarizes the microfluidic chips designed for single‐cell isolation, manipulation, trapping, screening, and sorting, including droplet microfluidic chips, microwell arrays, hydrodynamic microfluidic chips, and microchips with microvalves. This work further reviews the studies on single‐cell proteomics, metabolomics, lipidomics, and multi‐omics based on microfluidics and mass spectrometry. Finally, the challenges and future application of single‐cell multi‐omics are discussed.
DOMICO: Checking conformance between domain models and implementations
Authors: Zhong Chenxing , Zhang He , Huang Huang , Chen Zhikun , Li Chao , Liu Xiaodong , Li Shanshan 
Published: October 2023

AbstractAs a predominant design method for microsservices architecture (MSA), domain‐driven design (DDD) utilizes a series of standard patterns in both models and implementations to effectively support the design of architectural elements. However, an implementation may deviate from its original domain model that uses certain patterns. The deviation between a domain model and its implementation is a type of architectural drift, which needs to be detected promptly. This paper proposes an approach, namely DOMICO, to check the conformance between the domain model and its implementation, by which the conformance is formalized by defining eight common structural patterns of domain modeling and their representations in both models and the corresponding source code. Based on the formalization, our approach can not only identify the discrepancies (e.g., divergence, absence, and modification) with respect to pattern elements, but also detect possible violations of 24 compliance rules imposed by the patterns. To validate DOMICO, we performed a case study to investigate its use in a supply chain project and its performance. The results show that DOMICO can accurately identify 100% inconsistency issues in the cases examined. As the first conformance checking approach for DDD, DOMICO can be integrated into the regular domain modeling process and help ensure the conformity of microservice implementations to models.
Fetal Medicine Foundation charts for fetal growth in twins
Authors: Wright A. , Wright D. , Chaveeva P. , Molina F. S. , Akolekar R. , Syngelaki A. , Petersen O. B. , Kristensen S. E. , Nicolaides K. H. 
Published: October 2023

ABSTRACTObjectiveTo derive reference distributions of estimated fetal weight (EFW) in twins relative to singletons.MethodsGestational‐age‐ and chorionicity‐specific reference distributions for singleton percentiles and EFW were fitted to data on 4391 twin pregnancies with two liveborn fetuses from four European centers, including 3323 dichorionic (DC) and 1068 monochorionic diamniotic (MCDA) twin pregnancies. Gestational age was derived using the larger of the two crown–rump length measurements obtained during the first trimester of pregnancy. EFW was obtained from ultrasound measurements of head circumference, abdominal circumference and femur length using the Hadlock formula. Singleton percentiles were obtained using the Fetal Medicine Foundation population weight charts for singleton pregnancies. Hierarchical models were fitted to singleton Z‐scores with autoregressive terms for serial correlations within the same fetus and between twins from the same pregnancy. Separate models were fitted for DC and MCDA twins.ResultsFetuses from twin pregnancies tended to be smaller than singletons at the earliest gestational ages (16 weeks for MCDA and 20 weeks for DC twins). This was followed by a period of catch‐up growth until around 24 weeks. After that, both DC and MCDA twins showed reduced growth. In DC twins, the EFW corresponding to the 50th percentile was at the 50th percentile of singleton pregnancies at 23 weeks, the 43rd percentile at 28 weeks, the 32nd percentile at 32 weeks and the 22nd percentile at 36 weeks. In MCDA twins, the EFW corresponding to the 50th percentile was at the 36th percentile of singleton pregnancies at 24 weeks, the 29th percentile at 28 weeks, the 19th percentile at 32 weeks and the 12th percentile at 36 weeks.ConclusionsIn DC and, to a greater extent, MCDA twin pregnancies, fetal growth is reduced compared with that observed in singleton pregnancies. Furthermore, after 24 weeks, the divergence in growth trajectories between twin and singleton pregnancies becomes more pronounced as gestational age increases. © 2023 International Society of Ultrasound in Obstetrics and Gynecology.
Introduction: Integration in and Through Education and Employment
Authors: Teräs Marianne , Osman Ali , Eliasson Eva 
Published: October 2023

AbstractIn this book, our focus is on different aspects of education, employment, and integration of migrants in Norway, Sweden, and Switzerland, and what could be perceived as the relative success of integration processes from different theoretical vantage points, perspectives, and aspects. One intention of the book is to start a debate about what ‘successful integration’ entails. Research about migrants tends to focus on integration failures, such as structural hindrances, discrimination, lack of skills, and difficulties with recognition of prior learning. Our focus is on achievements rather than deficits, particularly how migrants transcend obstacles and mobilise cultural resources.The chapters in the book examine, for example, the significance of labour market initiatives, recognition of prior learning, recognition processes in career counselling, the importance of encounters, historical aspects of integration, the concept of integration, the importance of adult education, bridging programmes, and multicultural perspectives in education.
Potential, Actuality or Vulnerability? The Importance of Recognition in Career Counselling for Newly Arrived Migrants
Authors: Hertzberg Fredrik 
Published: October 2023

AbstractThis article studies the importance of recognition in career guidance counselling for newly arrived migrants. The term “recognition” is used as a sensitising concept, in line with Herbert Blumer’s sociology. The article draws attention to many different meanings of the concept of recognition, such as the recognition of previously established knowledge, skills and experiences; study and career aspirations; norms and values; opportunities for development; and the recognition of particularly difficult and therefore noteworthy life circumstances. The study is based on the analysis of qualitative data, drawn from semi-structured interviews with 14 study and career counsellors, who in their work meet (or have met) newly arrived migrants. The analysis draws attention to the fact that opportunities for development, as well as the recognition of particularly difficult and thus noteworthy life circumstances, are usually acknowledged without more extensive objections, but that the recognition of previously established knowledge, skills and experiences, study and career aspirations as well as norms and values can, according to the interviewees, lead to goal conflicts in study and career counselling work (although the relevance of a recognizing approach is generally emphasised).
Spezifische Teilhaberisiken und -chancen
Authors: Wacker Elisabeth , Beck Iris , Brandt Martina , Köbsell Swantje , Lippke Sonia , Niehaus Mathilde 
Published: October 2023

Zusammenfassung
Dieses Kapitel bezieht sich auf die Teilhabe und Gesundheit von Menschen mit Beeinträchtigungen, wobei das Augenmerk auch auf den besonderen und akuten Belastungen durch die Risiken von

Einsamkeit

und durch

Teilhabeeinschränkung

en in Zeiten der

COVID-19-Pandemie

liegt. Es wird deutlich, dass Menschen mit Beeinträchtigungen ein erhöhtes Einsamkeitsrisiko haben,
was sich negativ auf ihre Gesundheit auswirkt. Als Gegenpole können soziale Beziehungen und Netzwerke
wirken, doch auch diese sind weniger tragfähig als in der Mehrheitsgesellschaft. Dadurch fehlen wichtige
Ressourcen, die Resilienz für den Fall schwieriger Lebenssituationen fördern könnten. Deshalb sollte
der Prävention von Einsamkeit mehr Aufmerksamkeit gewidmet werden. Als besonderes Exklusions- und damit
Einsamkeitsrisiko für Menschen mit Beeinträchtigungen erwiesen sich die Maßnahmen zur Bekämpfung der
COVID-19-Pandemie. Dieser Problematik wird differenziert und auf breiter Datenbasis den exkludierenden
und isolierenden Wirkungen vieler Maßnahmen für Menschen mit Beeinträchtigungen nachgegangen. Ein Exkurs zur

Verfassungsbeschwerde

zur Schutzpflicht des Staates gegenüber Menschen mit Beeinträchtigungen im Hinblick auf

Triage

-Entscheidungen zeigt, welche lebensbedrohlichen Wirkungen der Verzicht auf

Disability Mainstreaming

bei Maßnahmen im Gesundheitswesen haben kann. Daraus folgt, dass

Pandemiebekämpfung

ohne gesundheitsbedrohliche Ausgrenzungen für Menschen mit Beeinträchtigungen entwickelt und durchgeführt werden muss. Welche Rolle ihre Selbstvertretung dabei spielen kann und muss, wird abschließend diskutiert. Entsprechendes gilt für die

Digitalisierung

im Gesundheitswesen. Sie hat im Kontext der COVID-19-Pandemie erheblich an Bedeutung gewonnen, dennoch sind dabei sehr viele Menschen mit Beeinträchtigungen nach wie vor ausgeschlossen.
Inklusive Gesundheitssorge – in All Policies
Authors: Wacker Elisabeth , Beck Iris , Brandt Martina , Köbsell Swantje , Lippke Sonia , Niehaus Mathilde 
Published: October 2023

Zusammenfassung
Die vorangegangenen Kapitel haben verdeutlicht, dass das Leben von Menschen mit Beeinträchtigungen
von vielfachen Benachteiligungen – und damit Risiken – durchzogen ist. Dies betrifft auch ihre Gesundheit
und ihre Gesundheitsversorgung. Folgerichtig legt dieses letzte Kapitel den Fokus auf Gesundheitschancen
bei Beeinträchtigungen und Behinderung und darauf, wie sie verbessert werden können. Im Kontext der Corona-Pandemie
sind Ungleichbehandlungen und deren Konsequenzen deutlich zutage getreten. Dies kann nun im Sinne von
Art. 25 UN-BRK auch jenseits von Krisenzeiten als Chance für eine engagierte Neuausrichtung der gesundheitlichen
Versorgung von Menschen mit Beeinträchtigungen genutzt werden. Die wichtigsten Botschaften dieses Buches
sind hier in zehn wegweisenden „Merkposten“ komprimiert. Um eine bessere gesundheitliche Versorgung von
Menschen mit Beeinträchtigungen sicherzustellen ist ihre aktive und partizipative Beteiligung, als Expertinnen
und Experten in eigener Sache nach dem Motto „nothing about us without us“, von zentraler Bedeutung.
Diesem Ziel dient letztlich auch das zukunftsweisende und partizipativ ausgelegte Konzept „

Health in All Policies

“ (HiaP), mit dem die gesundheitliche Versorgung von Menschen mit Beeinträchtigungen durch den Abbau von Barrieren und Diskriminierung weiterentwickelt werden soll.
Quantum Walk on FRET Networks
Authors: Takeuchi Michihisa 
Published: October 2023

AbstractIn this section, we introduce the basics of quantum walk algorithm and its applications. Quantum walk is a natural extension of the concept of random walk in quantum way; therefore, the results obtained from the discussion are considered as the results by Quantum Computation. In principle, we can expect a certain type of the computation would be boosted. There are a variety of phenomena in Quantum walks, and much broader outcomes are often obtained than those from classical random walk. Such famous examples include quantum search algorithms and quantum simulations. In this article, we introduce a quantum simulation of QCD parton shower algorithm appearing in particle physics.
Spatial Photonic Ising Machine with Time/Space Division Multiplexing
Authors: Ogura Yusuke 
Published: October 2023

AbstractThe spatial photonic Ising machine (SPIM) is an unconventional computing architecture based on parallel propagation/processing with spatial light modulation. SPIM enables the handling of an Ising model using light as a pseudospin. This chapter presents SPIMs with multiplexing to enhance their functionality. Handling a fully connected Ising model with a rank-2 or higher spin-interaction matrix becomes possible with multiplexing, drastically improving its applicability in practical applications. We constructed and examined systems based on time- and space-division multiplexing to handle Ising models with ranks of no less than one while maintaining high scalability owing to the features of spatial light modulation. Experimental results with knapsack problems demonstrate that these methods can compute the Hamiltonian consisting of objective and constraint terms, which require multiplexing, and can determine the ground-state spin configuration. In particular, in space-division multiplexing SPIM, the characteristics of the solution search vary based on the physical parameters of the optical system. A numerical study also suggested the effectiveness of the dynamic parameter settings in improving the Ising machine performance. These results demonstrate the high capability of SPIMs with multiplexing.
Neugeborenen-Hörscreening in Deutschland – Ergebnisse der Evaluationen 2011/2012 und 2017/2018
Authors: Brockow Inken , Söhl Kristina , Hanauer Marianne , Heißenhuber Annette , Marzi Carola , am Zehnhoff-Dinnesen Antoinette , Matulat Peter , Mansmann Ulrich , Nennstiel Uta 
Published: October 2023

Zusammenfassung
Hintergrund
Das Neugeborenen-Hörscreening (NHS) wurde 2009 durch den Gemeinsamen Bundesausschuss (G-BA) mit Aufnahme in die Kinder-Richtlinie bundesweit eingeführt. Dabei wurden in der Kinder-Richtlinie auch Qualitätsziele festgelegt. Um die Qualität des NHS in Deutschland zu überprüfen, hat der G‑BA eine Bietergemeinschaft mit einer ersten Evaluation für die Jahre 2011/2012 und einer Folge-Evaluation für 2017/2018 beauftragt.

Methoden
Grundlage der Evaluationen waren Sammelstatistiken, die von allen geburtshilflichen und neonatologischen Abteilungen, als Leistungserbringer des NHS, geführt werden müssen und ggf. in Kooperation mit Hörscreening-Zentralen (HSZ) erstellt werden. Zusätzliche Daten wurden durch Fragebögen und Interviews erhoben und durch Routinedaten ergänzt, um den vollständigen Screeningprozess zu evaluieren.

Ergebnisse
In 13 Bundesländern sind insgesamt 15 HSZ in den Screeningprozess eingebunden. Deutschlandweit wurde 2018 eine Screeningrate von 86,1 % (2012: 82,4 %) dokumentiert, die sich deutlich zwischen den Bundesländern unterschied. Die vorgegebenen Qualitätsziele konnten noch nicht überall umgesetzt werden. So erreichten nur knapp die Hälfte der Geburtsabteilungen die angestrebte Screeningrate von über 95 %. Beim Vergleich der Folge-Evaluation mit den Daten der ersten Evaluation konnte gezeigt werden, dass sich die Strukturqualität des NHS verbessert hatte, während die Prozessqualität eher gleich blieb oder schlechter geworden war, verdeutlicht insbesondere durch einen Anstieg der Refer-Rate (Kinder, die mit einem auffälligen Befund entlassen wurden) von 5,3 % auf 6,0 %.

Diskussion
Zur Verbesserung der Qualität des NHS sollten flächendeckend HSZ etabliert und – wie in der Richtlinie vorgesehen – bei auffälligem Erstscreening ein zweites Screening noch vor Entlassung konsequenter durchgeführt werden.
Evaluation of antibody-based single cell type imaging techniques coupled to multiplexed imaging of N-glycans and collagen peptides by matrix-assisted laser desorption/ionization mass spectrometry imaging
Authors: Dunne Jaclyn , Griner Jake , Romeo Martin , Macdonald Jade , Krieg Carsten , Lim Mark , Yagnik Gargey , Rothschild Kenneth J. , Drake Richard R. , Mehta Anand S. , Angel Peggi M. 
Published: October 2023

AbstractThe integration of matrix-assisted laser desorption/ionization mass spectrometry imaging (MALDI-MSI) with single cell spatial omics methods allows for a comprehensive investigation of single cell spatial information and matrisomal N-glycan and extracellular matrix protein imaging. Here, the performance of the antibody-directed single cell workflows coupled with MALDI-MSI are evaluated. Miralys™ photocleavable mass-tagged antibody probes (MALDI-IHC, AmberGen, Inc.), GeoMx DSP® (NanoString, Inc.), and Imaging Mass Cytometry (IMC, Standard BioTools Inc.) were used in series with MALDI-MSI of N-glycans and extracellular matrix peptides on formalin-fixed paraffin-embedded tissues. Single cell omics protocols were performed before and after MALDI-MSI. The data suggests that for each modality combination, there is an optimal order for performing both techniques on the same tissue section. An overall conclusion is that MALDI-MSI studies may be completed on the same tissue section as used for antibody-directed single cell modalities. This work increases access to combined cellular and extracellular information within the tissue microenvironment to enhance research on the pathological origins of disease.
Graphical Abstract