bluuebunny/crossref_metadata_2025_split huggingface dataset:
Decoration of viscose fibers with silver nanoparticle-based titanium-organic framework for use in environmental applications
Authors: Rehan Mohamed , Montaser Ahmed S. , El-Shahat Mahmoud , Abdelhameed Reda M. 
Published: January 2024

AbstractTo effectively remove pharmaceuticals, nitroaromatic compounds, and dyes from wastewater, an efficient multifunctional material was created based on silver nanoparticles (Ag) and MIL-125-NH2 (MOF) immobilized on viscose fibers (VF) as a support substrate. Firstly, silver nanoparticles (Ag) were immobilized on the surface of viscose fibers (VF) via in situ synthesis using trisodium citrate (TSC) as a reducing agent to create (VF-Ag). Then, VF and VF-Ag were decorated with the titanium metal–organic framework MIL-125-NH2 (MOF) to create VF-MOF and VF-Ag-MOF. The influence of VF-Ag, VF-MOF, and VF-Ag-MOF on the sonocatalytic or sonophotocatalytic degradation of sulfa drugs was investigated. The results show that VF-Ag-MOF showed excellent sonocatalytic and sonophotocatalytic activity towards the degradation of sulfa drugs compared to VF-Ag and VF-MOF. Furthermore, sonophotodegradation showed a dramatic enhancement in the efficiency of degradation of sulfa drugs compared to sonodegradation. The sonophotodegradation degradation percentage of sulfanilamide, sulfadiazine, and sulfamethazine drugs in the presence of VF-Ag-MOF was 65, 90, and 95 after 45 min of ultrasonic and visible light irradiation. The catalytic activity of VF-Ag, VF-MOF, and VF-Ag-MOF was evaluated through the conversion of p-nitrophenol (4-NP) to p-aminophenol (4-AP). The results demonstrate that VF-Ag-MOF had the highest catalytic activity, followed by VF-Ag and VF-MOF. The conversion percentage of 4-NP to 4-AP was 69%. The catalytic or photocatalytic effects of VF-Ag, VF-MOF, and VF-Ag-MOF on the elimination of methylene blue (MB) dye were investigated. The results demonstrate that VF-Ag-MOF showed high efficiency in removing the MB dye through the reduction (65%) or photodegradation (71%) after 60 min. VF-Ag-MOF composites structure–activity relationships represent that doping within silver NPs enhanced the photocatalytic activity of MIL-125-NH2, which could be explained as follows: (i) Due to the formation of a Schottky barrier at the junction between MIL-125-NH2 and Ag NPs, the photogenerated electrons in the conduction band of MIL-125-NH2 were supposed to be quickly transferred to the valence band of the Ag NPs, and subsequently, the electrons were transferred to the conduction band of Ag NPs. This considerable electron transferring process, which is reported as Z scheme heterojunction, can efficiently suppress the recombination of electron/hole pairs in VF-Ag-MIL-125-NH2 composites. (ii) Sufficient separation between the photogenerated charge carriers (holes and electrons) and avoiding their recombination enhanced the photocatalytic activity of composites.
Copper toxicity on Eisenia fetida in a vineyard soil: a combined study with standard tests, genotoxicity assessment and gut metagenomic analysis
Authors: Marini Enrica , De Bernardi Arianna , Tagliabue Francesca , Casucci Cristiano , Tiano Luca , Marcheggiani Fabio , Vaccari Filippo , Taskin Eren , Puglisi Edoardo , Brunetti Gianluca , Vischetti Costantino 
Published: January 2024

AbstractCopper (Cu) toxicity is a pressing concern for several soils, especially in organic viticulture. The objective of this work was to assess Cu toxicity on the non-target organism Eisenia fetida, employing both traditional and novel tools for early identification of Cu-induced damages. In addition to traditional tests like avoidance and reproductive toxicity experiments, other tests such as the single cell gel electrophoresis (SCGE) and gut microbiome analysis were evaluated to identify early and more sensitive pollution biomarkers. Four sub-lethal Cu concentrations were studied, and the results showed strong dose-dependent responses by the earthworm avoidance test and the exceeding of habitat threshold limit at the higher Cu doses. An inverse proportionality was observed between reproductive output and soil Cu concentration. Bioaccumulation was not detected in earthworms; soil concentrations of potentially bioavailable Cu were not affected by E. fetida presence or by time. On the contrary, the SCGE test revealed dose-dependent genotoxicity for the ‘tail length’ parameter already at the second day of Cu exposition. Gut microbiome analysis a modulation of microbial composition, with the most aboundant families being Pectobateriaceae, Comamonadaceae and Microscillaceae. Bacillaceae increased over time and showed adaptability to copper up to 165 mg/kg, while at the highest dose even the sensitive Acetobacteriaceae family was affected. The research provided new insights into the ecotoxicity of Cu sub-lethal doses highlighting both alterations at earthworms’ cellular level and changes in their gut microbiota.
Mental Health of Hong Kong University Students Under COVID-19: Protective Ecological Factors and Underlying Mechanism
Authors: Chai Wenyu , Shek Daniel T. L. 
Published: January 2024

AbstractWhile the COVID-19 has brought severe challenges to university students’ mental health, there is inadequate research on the related protective factors from different ecological systems and the underlying mechanisms. Guided by the ecological systems theory and the positive youth development approach, this study investigated the associations between two protective factors in the ecological systems (i.e., positive family functioning in the microsystem and Chinese cultural beliefs of adversity in the macrosystem) and students’ mental health in Hong Kong higher education during the period of the pandemic, with resilience (i.e., an important positive youth development quality) proposed as a mediating factor. This study was based on data collected in a large-scale survey of 978 Hong Kong Chinese undergraduate students (mean age = 20.69 with 62.9% being female) in the summer of 2022. Validated measures were used to assess students’ mental health problems (anxiety and depression), the ecological protective factors (positive family functioning and Chinese cultural beliefs of adversity), and resilience. Structural equation modelling was conducted to examine the associations between ecological protective factors and mental health problems, as well as the mediating effects of resilience in the associations. Structural equation modelling revealed that both positive family functioning and Chinese cultural beliefs of adversity negatively predicted anxiety and depression, with resilience partially mediating all paths. The study contributes significantly to the understanding of different ecological protective factors in higher education students’ mental health and the mediating role of resilience. It also provides practical implications for intervention and prevention.
Traces of collisional and transtensional processes between the Carpathia and the European platform in the geoelectric image (NE Slovakia and SE Poland)
Authors: Bezák Vladimír , Ondrášová Lenka , Vozár Ján , Oryński Szymon , Madzin Jozef , Majcin Dušan , Klanica Radek , Bilčík Dušan 
Published: January 2024

AbstractWe present the latest magnetotelluric models on profiles in the northeastern part of Slovakia and the southeastern part of Poland. These models are focused on deciphering the tectonic structures at the contact of the Inner Carpathians with the European Platform in this area. For the Inner Carpathian block, we propose the term Carpathia. Profile SA-01 shows shallower structures and the parallel MT-05 profile shows deeper structures. These models are also correlated with the seismic profile CEL-05. All results are compatible and show an original subduction-collisional structure, which was later replaced by a transpressive-transtensional one. The most striking structures are thick highly conductive subhorizontal zones in the middle crust and a tectonically controlled deep vertical conductive structure—the Carpathian conductive zone. Other significant structures, which also appear in the seismic section, are back thrusting of Flysch Belt and the Klippen Belt basement (Penninic crust) uplift.
Subsurface conditioning in BTA deep hole drilling for improved component performance
Authors: Strodick Simon , Schmidt Robert , Donnerbauer Kai , Rozo Vasquez Julian , Zabel Andreas , Macias Barrientos Marina , Biermann Dirk , Walther Frank 
Published: January 2024

Abstract
When bores with high length-to-diameter ratios (l/D > 10) and large diameters (D > 40 mm) are required, usually, the Boring and Trepanning Association (BTA) deep hole drilling process is used. Common industrial applications of this process are aerospace engineering and petrol exploration, where drilled components range from landing gears and engine shafts to drill collars. Since such parts tend to be particularly costly and highly safety–critical, ensuring favorable surface integrity during drilling is crucial to guarantee their reliability and performance. This study aims to identify correlations between the BTA deep hole drilling process and the resulting surface integrity using experimental and simulative approaches. The impact of feed and cutting speed on the thermomechanical loads and the resulting surface integrity are analyzed, also taking into account the occurrence of dynamic process disturbances. Particularly, the formation of white etching layers (WEL) is investigated using well-established, conventional techniques such as optical microscopy and microhardness testing. Additionally, innovative micromagnetic methods are employed. Magnetic Barkhausen noise (MBN) analysis is qualified as a well-applicable approach for rapid, non-destructive detection of WEL. To enhance understanding of MBN analysis and increase its robustness, the underlying mechanisms, governing the magnetic behavior of the subsurface are elucidated in detail by X-ray diffraction (XRD), electron backscatter diffraction (EBSD), magnetic force microscopy (MFM) and magneto-optical Kerr effect (MOKE) microscopy. The methodology will serve as a basis for controlled subsurface conditioning in BTA deep hole drilling.
Vernalization affects the germination performance of the wetland endangered species Eleocharis carniolica
Authors: Trotta Giacomo , Ceriani Roberta M. , Casolo Valentino , Bellingardi Jessica , Boscutti Francesco , Vuerich Marco , Petrussa Elisa 
Published: January 2024

AbstractEleocharis carniolica W.D.J. Koch (Cyperaceae) is an endangered wetland spike rush mainly threatened by habitat loss and fragmentation. Understanding the germination ecology of this species is essential to perform successful conservation and restoration actions. In this study, we investigated the effect of vernalization (i.e. cold stratification), gibberellic acid (GA3) and chemical scarification on seed germination of E. carniolica from wild populations in northern Italy. The results showed that vernalization (i.e. 8-weeks at 4 °C) significantly improved germination probability, speed, and uniformity compared to non-stratified seeds. Gibberellic acid treatment alone or in combination with vernalization did not show a significant improvement in germination. Chemical scarification using sodium hypochlorite increased germination probability, with 8 h of scarification showing the highest success rate. However, 24-h scarification had a negative impact on germination. Overall, vernalization was found to be the most effective method to enhance germination in E. carniolica. These findings provide valuable insights into the seed germination ecology of this endangered species, aiding in its exsitu conservation, propagation, and in-situ restoration efforts. Moreover, they have important implications on future germination dynamics of this endangered species, especially with predicted climate change scenarios.
Following up with Forest Inheritors: A Survival Analysis of Recently Inherited and Recently Sold Non-Industrial Forest Land in the State of Washington, USA
Authors: Danley Brian , Rabotyagov Sergey , Cooke Andrew 
Published: January 2024

AbstractA growing body of literature shows that the transfer of forest land from one owner to another in the US is associated with events such as parcelization of forest land and/or the subsequent conversion of the land away from forestry land use. For individuals and families who own forest land, a key driver of ownership transfer is the eventual or actual mortality of forest owners themselves. In the State of Washington as well as the US nationally, studies on forest legacy planning reveal that most forest owners want their children or grandchildren to own their forest properties after they no longer own the forest. In contrast, the same surveys also show that a majority of US forest owners acquired their forest land by purchasing the land from a non-relative. We utilize the Washington State Forestland Database to conduct a non-parametric survival analysis of how long recently inherited forest properties remain fully owned by the new owners (i.e. there is no subsequent sale associated with the property) compared to forest land that was sold. Results show that inherited parcels have a significantly lower survival probability as measured by remaining solely within the ownership of the new owner relative to parcels that were sold within an 8-year period. This study quantifies how the mode of forest transfer influences the duration of the following ownership lifecycle and indicates that stewardship efforts should be tailored for owners who have recently inherited forest lands.
Durability of photocatalytic ZnO-based surface coatings and preservation of their antibacterial effect after simulated wear
Authors: Kook Mati , Kaur Harleen , Danilian Dmytro , Rosenberg Merilin , Kisand Vambola , Ivask Angela 
Published: January 2024

AbstractThis study focused on antibacterial durability testing of surface coatings based on acrylic matrix-embedded UVA-activated ZnO. Such coatings on stainless steel were treated by dry rubbing, wet rubbing, and abrasive treatment to simulate wearing during everyday touching, cleaning, and aggressive scrubbing. Abrasive treatment caused clear topological changes to the surfaces, flattened the surface at the micrometer scale, and released a significant amount of surface material, which was partly acrylic matrix and partly the embedded ZnO. The highest release of Zn, the most prominent photocatalytic activity under UVA and the greatest antibacterial effect, was observed for abrasively treated surfaces. Although a small amount of surface material was released from surfaces after dry and wet rubbing, no significant increase in Zn release or photocatalytic activity was detected. On the contrary, antibacterial activity after those treatments decreased in comparison with untreated surfaces, likely due to partial surface masking by the released acrylic matrix. In summary, our results indicate that antimicrobial ZnO material immobilized in acrylic matrix creates stable surface coatings that may lose some of their efficacy during daily use and cleaning procedures, but activity of which will be retained during a more aggressive abrasion procedure.
A retrospective review of methylamphetamine detected in child deaths reported to the Victorian Coroner, Australia
Authors: Mantinieks Dylan , Parsons Sarah , Schumann Jennifer , Drummer Olaf H. , Crump Kerryn , Baber Yeliena , Archer Melanie , Gerostamoulos Dimitri 
Published: January 2024

Abstract
This study investigated methylamphetamine (MA) exposures in the deaths of children (≤ 12 years old) reported to the Coroner in the state of Victoria, Australia, between 2011 and 2020. Demographics, autopsy findings including the cause of death, self-reported prenatal or caregiver drug use, child protection services information, and toxicological findings were summarized by descriptive statistics. Validated methods of liquid chromatography-tandem mass spectrometry were used in the analysis of drugs. There were 50 child deaths with MA detected in blood, urine, and/or hair with 64% (n = 32) identified in 2018–2020. Most children were 1–365 days old (66%, n = 33) and the cause of death was unascertained in 62% (n = 31) of cases. MA was toxicologically confirmed in hair (94%, n = 47) significantly more than blood (18%, n = 9). Prenatal or caregiver drug use was self-reported in 44% (n = 22) and 42% (n = 21) of cases, respectively. Moreover, only 54% (n = 27) of deceased children were a child protection client at their time of death. These findings suggest the number of deceased children exposed to MA has increased over the past 10 years, which is consistent with the greater supply of crystal MA in the Australian community. Hair analysis provided additional means to identify cases that were unknown to child protection services and may have implications for other children in the same drug exposure environment.
Burden of illness in Japanese patients with paroxysmal nocturnal hemoglobinuria receiving C5 inhibitors
Authors: Obara Naoshi , Usuki Kensuke , Hayashi Takeshi , Fujii Masato , Ikezoe Takayuki 
Published: January 2024

AbstractParoxysmal nocturnal hemoglobinuria (PNH) is a rare, acquired, life-threatening blood disorder characterized by hemolysis and resulting in anemia and fatigue. Current therapies for PNH in Japan rely on complement inhibitors targeting the C5 component of the complement. However, the disease burden of Japanese patients with PNH treated with C5 inhibitors (C5i) remains unclear. To investigate this topic, we conducted a cross-sectional survey study that included 59 Japanese patients with PNH treated with C5i. Although many participants received C5i for 1 year or longer, the mean hemoglobin (Hb) level was 10.2 g/dL. Fatigue and shortness of breath were the most common symptoms at the time of diagnosis and survey. In addition, patients with Hb levels ≥ 10.5 g/dL also reported fatigue, depression and reduced quality of life, albeit to a lesser extent. These results suggest that a substantial burden of illness remains in patients with C5i-treated PNH, likely resulting in low quality of life and effects of symptoms on daily life. This study contributes to understanding the unmet needs of the current therapies for PNH, highlighting the need for novel therapeutics.
The Minimal Spherical Dispersion
Authors: Prochno Joscha , Rudolf Daniel 
Published: January 2024

AbstractWe prove upper and lower bounds on the minimal spherical dispersion, improving upon previous estimates obtained by Rote and Tichy in (Anz Österreich Akad Wiss Math Nat Kl 132:3–10, 1995). In particular, we see that the inverse $$N(\varepsilon ,d)$$

N
(
ε
,
d
)

of the minimal spherical dispersion is, for fixed $$\varepsilon >0$$

ε
>
0

, linear in the dimension d of the ambient space. We also derive upper and lower bounds on the expected dispersion for points chosen independently and uniformly at random from the Euclidean unit sphere. In terms of the corresponding inverse $$\widetilde{N}(\varepsilon ,d)$$

N
~

(
ε
,
d
)

, our bounds are optimal with respect to the dependence on $$\varepsilon $$
ε
.
Existence of Positive Solutions for a Singular Hessian Equation with a Negative Augmented Term
Authors: Zhang Xinguang , Chen Peng , Wu Yonghong , Wiwatanapataphee Benchawan 
Published: January 2024

AbstractIn this paper, we focus on the existence of positive solutions for a singular Hessian equation with a negative augmented term. By finding more appropriate upper and lower solutions, we not only overcome the difficulty due to the negative augmented term but also remove a critical condition required in the existing work and establish new results for the existence of positive solutions of the equations under study. Our results improve and complement many existing works.
Unraveling the Phidiana paradox: Phidiana lynceus can retain algal symbionts but its nocturnal tendencies prevent benefits from photosynthesis
Authors: Borgstein Natascha M. , Burgués Palau Laia , Parodi Bianca A. , Laetz Elise M. J. 
Published: January 2024

AbstractNumerous marine invertebrates form symbiotic relationships with single-celled algae, termed “photosymbioses”, and the diversity of these interactions is likely underestimated. We examined Phidiana lynceus, a cladobranch sea slug that feeds on photosymbiotic hydrozoans. We assessed its ability to acquire/retain algal symbionts by examining specimens in starvation, finding that P. lynceus is able to incorporate and retain symbionts for up to 20 days. Examining body size during starvation revealed that P. lynceus does not receive enough energy from hosting symbionts to maintain its body mass let alone grow. Intact symbionts were still present in deceased specimens, indicating that P. lynceus does not digest all of its symbionts, even when starving to death. We also examined slug behavior in the field and lab to determine if it seeks light to facilitate photosynthesis, which could provide energetic and oxygenic benefits. In the field, slugs were always observed hiding under stones during the day and they displayed light avoidance in the lab, suggesting this species actively prevents photosynthesis and the benefits it could receive. Lastly, we measured their metabolic rates during the day and night and when treated with and without a photosynthetic inhibitor. Higher metabolic rates at night indicate that this species displays nocturnal tendencies, expending more energy when it emerges at night to forage. Paradoxically, P. lynceus has evolved all of the requisite adaptations to profit from photosymbiosis but it chooses to live in the dark instead, calling into question the nature of this symbiosis and what each partner might receive from their interaction.
The effect of social network structure on group anchoring bias
Authors: Palombi Giulia , Nonino Fabio , Borgatti Stephen P. 
Published: January 2024

AbstractDecisions—whether made by individuals or groups—often involve estimating quantities, a process that is subject to anchoring bias (Tversky and Kahneman in Science 185: 1124–1131, 1974). Differences in susceptibility to anchoring bias between individuals and groups have been recently explored with the result that groups appear less biased than individuals (Meub and Proeger in Theor Decis 85:117–150, 2018). However, existing studies treat groups monolithically without taking into account their network structure—the pattern of relationships among members. The present paper investigates the effects of group social network structure on anchoring bias. Using a structured survey instrument, we gathered data on competence-based trust relationships among 264 students enrolled in a university degree program. An anchoring experiment was conducted in which some of the students made estimates as individuals, while others did so in groups of different structures. The findings provide initial evidence of differences in bias levels across variously structured groups as well as relative to individuals. Groups with highly centralized trust networks (where a single person owned everyone’s trust) showed more anchoring bias than dense groups (where everyone trusted everyone else) and sparse groups (where no one trusted any other member of the group) showed more bias than dense groups. In addition, despite previous research demonstrating groups are less susceptible than individuals to anchoring bias, this study shows a higher presence of bias in both our centralized groups and sparse groups when compared to individuals, suggesting that group structure might moderate the mitigating effect of groups on anchoring bias. The research has implications for organizational behavior and social network literature. Specifically, this study contributes to the debate on anchoring bias for group decisions by highlighting the significant role of social network structure. At the same time, it contributes to the literature on network structure and performance by providing initial evidence of how network structure affects anchoring bias susceptibility. Moreover, our study contributes to management practice by alerting managers to the dangers of centralized networks, suggesting that competence-based trust plays a vital role in the resistance to anchoring bias.