bluuebunny/crossref_metadata_2025_split huggingface dataset:
Noise‐Reduced WSe2 Phototransistors for Enhanced Photodetection Performance via Suppression of Metal‐Induced Gap States
Authors: Ryoo Sunggyu , Sim Jinwoo , Jeong Seungjun , Jang Juntae , Woo Jaeyong , Park Jaehyoung , Ko Seongmin , Kim Yeeun , Song Youngmin , Yoo Jongeun , Ahn Heebeom , Kang Keehoon , Cho Daeheum , Cho Kyungjune , Lee Takhee 
Published: January 2025

AbstractPhototransistors are critical components in optoelectronics, and 2D transition metal dichalcogenides (TMDC), such as tungsten diselenide (WSe2), show promise for phototransistor applications due to their strong light‐matter interaction, unique excitonic properties, and high surface‐to‐volume ratio. In 2D TMDC‐based phototransistors, 1/f noise, caused by complex defect states, acts as a dominant low‐frequency noise (LFN) and is crucial for obtaining accurate photodetection characteristics. However, many studies still overlook LFN and focus on enhancing photocurrent or response time. In this study, the importance of LFN analysis is highlighted in WSe2 phototransistors and demonstrate reduced noises and enhanced photodetection performance through the suppression of metal‐induced gap states (MIGS) that act as noise sources by utilizing semimetal bismuth (Bi) contact. The WSe2 phototransistors demonstrated ≈1000 times lower noise, 100 times higher responsivity, and 10 times higher specific detectivity than devices with conventional metal contacts. The results of this study suggest that reducing LFN in photodetection devices, such as by suppressing MIGS, can be an efficient way to enhance device performance.
Tumor Microenvironment‐Driven Structural Transformation of Vanadium‐Based MXenzymes to Amplify Oxidative Stress for Multimodal Tumor Therapy
Authors: Zhu Hai , Li Tinghua , Peng Xinhao , Zhang Xiaoxian , Zhang Xuequan , Wang Qiusheng , Lei Lei , Zhang Jun , He Bin , Cao Jun 
Published: January 2025

AbstractMXenzymes, a promising class of catalytic therapeutic material, offer great potential for tumor treatment, but they encounter significant obstacles due to suboptimal catalytic efficiency and kinetics in the tumor microenvironment (TME). Herein, this study draws inspiration from the electronic structure of transition metal vanadium, proposing the leverage of TME specific‐features to induce structural transformations in sheet‐like vanadium carbide MXenzymes (TVMz). These transformations trigger cascading catalytic reactions that amplify oxidative stress, thereby significantly enhancing multimodal tumor therapy. Specifically, the engineered HTVMz, coated with hyaluronic acid, exhibits good stability and generates a thermal effect under NIR‐II laser irradiation. The thermal effect, combined with TME characteristics, facilities a structural transformation into ultra‐small vanadium oxide nanozymes (VOx). The enlarged surface area of VOx substantially enhances ROS regeneration and amplifies oxidative stress, which promotes lysosomal permeability and induces endoplasmic reticulum stress. The high‐valent vanadium in VOx interacts with intracellular glutathione, disrupting redox homeostasis and intensifying oxidative stress further. These amplifications accelerate tumor apoptosis, induce ferroptosis, and suppress HSP90 expression. Consequently, the heightened thermal sensitivity of HTVMz synergistically promotes tumor cell death via multimodal therapeutic pathways. This study presents an innovative strategy for tumor catalytic therapy by manipulating MXenzymes structures, advancing the field of catalytic therapy.
Advances in Symbiotic Bioabsorbable Devices
Authors: Zhu Chang , Wang Engui , Li Zhou , Ouyang Han 
Published: January 2025

AbstractSymbiotic bioabsorbable devices are ideal for temporary treatment. This eliminates the boundaries between the device and organism and develops a symbiotic relationship by degrading nutrients that directly enter the cells, tissues, and body to avoid the hazards of device retention. Symbiotic bioresorbable electronics show great promise for sensing, diagnostics, therapy, and rehabilitation, as underpinned by innovations in materials, devices, and systems. This review focuses on recent advances in bioabsorbable devices. Innovation is focused on the material, device, and system levels. Significant advances in biomedical applications are reviewed, including integrated diagnostics, tissue repair, cardiac pacing, and neurostimulation. In addition to the material, device, and system issues, the challenges and trends in symbiotic bioresorbable electronics are discussed.
Self‐Adaptive Quantum Kernel Principal Component Analysis for Compact Readout of Chemiresistive Sensor Arrays
Authors: Wang Zeheng , van der Laan Timothy , Usman Muhammad 
Published: January 2025

AbstractThe rapid growth of Internet of Things (IoT) devices necessitates efficient data compression techniques to manage the vast amounts of data they generate. Chemiresistive sensor arrays (CSAs), a simple yet essential component in IoT systems, produce large datasets due to their simultaneous multi‐sensor operations. Classical principal component analysis (cPCA), a widely used solution for dimensionality reduction, often struggles to preserve critical information in complex datasets. In this study, the self‐adaptive quantum kernel (SAQK) PCA is introduced as a complementary approach to enhance information retention. The results show that SAQK PCA outperforms cPCA in various back end machine‐learning tasks, particularly in low‐dimensional scenarios where quantum bit resources are constrained. Although the overall improvement is modest in some cases, SAQK PCA proves especially effective in preserving group structures within low‐dimensional data. These findings underscore the potential of noisy intermediate‐scale quantum (NISQ) computers to transform data processing in real‐world IoT applications by improving the efficiency and reliability of CSA data compression and readout, despite current qubit limitations.
Impact of Leadership Styles and Organisational Citizenship Behaviours on Organisational Green Innovation Performance: The Moderating Role of Organisational Legitimacy
Authors: Zhao Shuliang , Renxi Wu , Giglio Carlo , Appolloni Andrea 
Published: January 2025

ABSTRACTFirms' green innovation performance is influenced by several factors, including external legitimacy pressures and internal leader–member exchange relationships. Existing studies make little distinction between types of sustainable innovation and neglect leader, employee and organisational factors in the same strategic management framework. Based on institutional and social exchange theories, data from 537 Chinese enterprises are analysed through a hierarchical regression to explore how different leadership styles, organisational citizenship behaviours and legitimacy outside organisations affect green innovation performance. Research findings suggest that both transactional and transformational leadership contribute to organisational citizenship behaviours and green innovation performance. Organisational citizenship behaviours partially mediate between leadership styles and green innovation. Organisational legitimacy only positively moderates between leadership styles and organisational citizenship for green product innovation. This implies that organisations should pay attention to fostering high‐quality leader–member exchange relationships, formulating sustainable innovation management strategies and seeking a balance between obtaining organisational legitimacy and promoting organisational citizenship.
Process intensification of the baculovirus expression vector system using a perfusion process with a low multiplicity of infection at high cell concentrations
Authors: Altenburg Jort J. , Juarez‐Garza Brenda E. , van Keimpema Jelle , van Oosten Linda , Pijlman Gorben P. , van Oers Monique M. , Wijffels René H. , Martens Dirk E. 
Published: January 2025

AbstractThe emergence of new viruses and the spread of existing pathogens necessitate efficient vaccine production methods. The baculovirus expression vector system (BEVS) is an efficient and scalable system for subunit and virus‐like particle vaccine production and gene therapy vectors. However, current production processes are often limited to low cell concentrations (1–4 × 106 cells/mL) in fed‐batch mode. To improve the volumetric productivity of the BEVS, a medium exchange strategy was investigated. Screening experiments were performed to test baculovirus (expressing green fluorescent protein; GFP) infection and productivity of insect cell cultures infected at high cell concentration (1–2 × 107 cells/mL), showing that infection at high cell concentrations was possible with medium exchange. Next, duplicate perfusion runs with baculovirus infection were performed using a cell concentration upon infection (CCI) of 1.2 × 107 cells/mL and a multiplicity of infection (MOI) of 0.01, reaching a maximum viable cell concentration of 2.8 × 107 cells/mL and a maximum GFP production of 263 mg/L. The volumetric productivity of these perfusion runs was 4.8 times higher than for reference batch processes with a CCI of 3 × 106 cells/mL and an MOI of 1. These results demonstrate that process intensification can be achieved for the BEVS by implementing perfusion, resulting in a higher volumetric productivity.
Construction of 1,3‐Diboryl Allenes from gem‐Iododiboron Compounds via Intermolecular Boryl Group Transfer†
Authors: Li Ming , Wei Yi , Chen Du , Ning Peng‐Fei , Yang Yi‐Fei , Xie Xiao‐Yu , Liu Chao , Hong Kai 
Published: January 2025

Comprehensive SummaryAllenylboronates are valuable synthetic building blocks and have garnered significant interest. However, their 1,3‐diboyl substituted analogs have not been reported. Herein, we disclosed a novel method for creating 1,3‐diboyl allenes from gem‐iododiboron compounds and alkynyl Grignard reagents. The starting materials are initially converted into the corresponding propargylic gem‐bis(boronates), which then undergo an intermolecular boryl group transfer to afford 1,3‐diboyl allenes, as confirmed by mechanistic studies. This method features good tolerance to steric hindrance and is compatible with a wide variety of functional groups.
Evaluation of the Effect of Momelotinib on Cardiac Repolarization: A Thorough QT Study
Authors: Vlasakakis Georgios , Alvarez Yolanda , Hart Timothy , Ho Yu Liu , Ellis Catherine 
Published: January 2025

AbstractA randomized, partially blinded, placebo‐controlled, crossover study in 48 healthy adults assessed the effect of momelotinib on the heart rate‐corrected QT interval (QTc) using the Fridericia formula (QTcF). QTc was evaluated for momelotinib 200 mg (therapeutic dose), momelotinib 800 mg (supratherapeutic dose), moxifloxacin 400 mg (positive control), and placebo. Pharmacokinetic profiles of momelotinib and its active metabolite M21 were evaluated. Momelotinib did not prolong QTcF, as the upper bounds of the 2‐sided 90% confidence intervals (CIs) for the mean difference between doses of momelotinib and placebo were <10 milliseconds at all time points. The lower limit of the 2‐sided 98% CI for the mean difference in QTcF between moxifloxacin versus placebo was >5 milliseconds at 2, 3, and 4 hours after dosing, demonstrating assay sensitivity. There was no positive relationship between momelotinib plasma concentrations and QTcF. Adverse events (AEs) were more frequent with the supratherapeutic dose of momelotinib, but none were considered severe. There were no deaths, serious AEs, or AEs leading to study discontinuation. Neither therapeutic nor supratherapeutic doses of momelotinib led to clinically significant effects on the QTc interval, supporting a negative finding for QTc prolongation from this thorough QT study.
A Cross‐Sectional Network Analysis of Intimate Partner Violence and Suicidal Ideation Among Arab Women
Authors: Tayim Natalie , Ayasrah Mohammad Nayef , Ahmed Marei , Abdelrahman Rasha Mohamed 
Published: January 2025

ABSTRACTIntroductionThe current study aimed to evaluate the relationship between intimate partner violence (IPV) and suicidal ideation among women using a network analysis approach.MethodSecondary data including 440 women (mean age ± SD = 32.78 ± 8.09) who experienced IPV in the last 6 months were used. The Revised Composite Abuse Scale‐Short Form, Columbia‐Suicide Severity Rating Scale and Revised Scale of Economic Abuse were used to assess IPV and suicidal ideation. Network analysis, centrality measures and bridge centrality were applied to understand the interplay between IPV and suicide risk factors.ResultsThe strongest association in the network analysis was found between ‘Wish to be Dead’ (S.1) and ‘Non‐Specific Active Suicidal Thoughts’ (S.2) with a weight of 0.523, indicating a substantial correlation between general suicidal thoughts and particular desires to die. IPV symptoms, particularly economic exploitation and psychological abuse, showed strong links to suicidal ideation. ‘Active Suicidal Ideation with Specific Plan and Intent’ (S.5) was significantly related to ‘Make you take out a loan or buy something on credit when you didn't want to’ (EA.11) with a weight of 0.276. Additionally, centrality analysis showed that ‘Wish to be Dead’ (S.1) was the most central node in the network of suicidal ideation, with the highest centrality score (betweenness = 2.625).ConclusionThese findings suggest that IPV, mainly psychological abuse, plays a pivotal role in suicidal ideation among women. Mental health interventions should focus on addressing IPV‐related psychological abuse. Suicide prevention efforts must integrate IPV screening into clinical practice.
Evolutions of Both Temperature Field and Convection Field During GaInSb THM and VB Crystal Growths and Influences of Temperature Gradient
Authors: Wang Pei , Wang Bowen , Zhao Leran , Liu Ming , Liu Jian , Zhang Xinhu , Liu Juncheng 
Published: January 2025

AbstractIII‐V semiconductor compound crystals are widely used in the advanced infrared detectors and lasers etc. The traveling heater method (THM) and the vertical Bridgman method (VB) are two important methods to grow high‐quality, especially low dislocation density bulk single crystals, in which the furnace temperature gradient GTH, usually plays a key role determining the dislocation density. This work simulates numerically GaInSb crystal growths with both THM and VB, displaying the evolutions of both the temperature field inside the crucible domain and the flow field in the melt in detail, investigating the influences of GTH on the temperature and the flow fields, especially on the temperature gradient at the front of crystal growth interface and its shape. The results show that both of them are more dependent on GTH during THM crystal growth than during VB one. Furthermore, this work focuses on the impact of the mushy zone in the front of growth interface during the ternary compounds’ crystal growth, which has been almost always ignored in the previous numerical simulation works.
Transparent Banking: Unveiling the Drivers of Online Circular Economy Disclosure in European Banks
Authors: Fraccalvieri Ilenia , L'Abate Vitiana , Raimo Nicola , Vitolla Filippo , Bussoli Candida 
Published: January 2025

ABSTRACTIn response to global efforts to address climate change, biodiversity loss, and ecosystem degradation, the transition to a circular economy (CE) has emerged as a key strategy for achieving sustainable development. Financial institutions, particularly banks, play a pivotal role in this transition by supporting companies through financial and legal frameworks, network development services, and advisory support, while also adopting internal sustainable practices. Given their central role in the CE, banks are also expected to enhance transparency by clearly communicating their CE initiatives and raising awareness. Despite this, CE disclosure (CED) practices among banks have received limited attention in academic literature. This study, through the lens of legitimacy theory, aims to address this gap by examining the level of CED in European banks and the impact of certain bank characteristics—such as size, age, Internet visibility, and internationalization—on the amount of CE information disseminated through their official websites. The econometric analysis, conducted on a sample of 107 European banks, reveals that size, Internet visibility, and internationalization positively influence the amount of CE information disclosed, while age has no significant effect. The findings enhance the knowledge of how banks manage and communicate their CE efforts, providing valuable insights for banks, policymakers, and standard setters.
Recovery of Rare Earths from End‐of‐Life NdFeB Permanent Magnets from Wind Turbines
Authors: Alcaraz Lorena , Rodríguez‐Largo Olga , Barquero‐Carmona Gorka , Berja Alba , Quesada Adrián , López Félix A. 
Published: January 2025

AbstractThis work aims to recover rare earths from wind turbines NdFeB magnets through pyrometallurgical and hydrometallurgical techniques. First, a NdFeB hydride powder is obtained by decrepitation with hydrogen. Subsequently, this powder was subjected to a chlorination roasting process and successive leaching with water to bring the metals into solution. This was followed by a liquid‐liquid extraction to remove the iron and purify the rare earth solution. For this purpose, Aliquat 336 diluted in Solvesso was selected as the iron selective extraction agent. As a single extraction was not enough for complete iron removal, a second Fe extraction step was carried out. This second extraction step was performed using the restored organic phase. This restoration was achieved by treating the organic phase with Na2SO3 and then washing it with a 3 M HCl solution. In this way, the process was achieved more sustainably. Finally, the rare earths contained in the final solution were precipitated using oxalic acid to obtain mixed rare earth oxalates.
The Eurasian Magpie Preys on the Nests of Vinous‐throated Parrotbills in Invasive Smooth Cordgrass
Authors: Chen Yanhong , Xu Youle , Wang Junjie , Chen Taiyu , Liu Bin , Chen Pan , Lu Changhu 
Published: January 2025

ABSTRACTNative animals worldwide are experiencing long‐term coexistence with invasive plants, leading to diverse behavioral changes. Invasive plants may create new habitat structures that affect the distribution or behavior of prey, which in turn might attract predators to these novel habitats, thereby altering predator–prey dynamics within the ecosystem. However, this phenomenon is rarely reported. Our previous research found that in the Yellow Sea wetlands of China, the native bird species, the vinous‐throated parrotbill (Sinosuthora webbiana), has adapted to breeding in the invasive smooth cordgrass (Spartina alterniflora) by increasing its nesting height. Here, our observations indicate that in cordgrass habitats, the main nest predator of parrotbills was the Eurasian magpie (Pica pica), accounting for 75% of predation events. In contrast, in native habitats, the primary predators were mammals and snakes, accounting for 83% of predation events, with no nests being predated by magpies. We believe that changes in the breeding and nesting behavior of parrotbills may have attracted magpie predation in cordgrass habitats. Our findings may provide an empirical case of how behavioral changes induced by invasive plants can lead to dynamic shifts in predation relationships. We advocate for further research into this intriguing phenomenon, as it could enhance our understanding of changes in interspecific relationships and their ecological consequences within the context of biological invasions.
The power and pitfalls of amino acid carbon stable isotopes for tracing origin and use of basal resources in food webs
Authors: Vane Kim , Cobain Matthew R. D. , Larsen Thomas 
Published: January 2025

AbstractNatural and anthropogenic stressors alter the composition, biomass, and nutritional quality of primary producers and microorganisms, the basal organisms that synthesize the biomolecules essential for metazoan growth and survival (i.e., basal resources). Traditional biomarkers have provided valuable insight into the spatiotemporal dynamics of basal resource use, but lack specificity in identifying multiple basal organisms, can be confounded by environmental and physiological processes, and do not always preserve in tissues over long timescales. Carbon stable isotope ratios of essential amino acids (δ13C‐EAA) show remarkable promise in identifying and distinguishing clades of basal organisms with unique δ13C‐EAA fingerprints that are independent of trophic processing and environmental variability, providing unparalleled potential in their application. Understanding the biochemical processes that underpin δ13C‐AA data is crucial, however, for holistic and robust inferences in ecological applications. This comprehensive methodological review, for the first time, conceptualizes these mechanistic underpinnings that drive δ13C‐EAA fingerprints among basal organisms and incorporates δ13C values of non‐essential amino acids that are generally overlooked in ecological studies, despite the gain of metabolic information. We conduct meta‐analyses of published data to test hypothesized AA‐specific isotope fractionations among basal organism clades, demonstrating that phenylalanine separates vascular plant δ13C‐EAA fingerprints, which strongly covaries with their phylogeny. We further explore the utility of non‐essential AAs in separating dietary protein sources of archaeological humans, showing the differences in metabolic information contained within different NEAAs. By scrutinizing the many methodologies that are applied in the field, we highlight the absence of standardized analytical protocols, particularly in sample pretreatments leading to biases, inappropriate use of statistical methods, and reliance on unsuitable training data. To unlock the full potential of δ13C‐EAA fingerprints, we provide in‐depth explanations on knowledge gaps, pitfalls, and optimal practices in this complex but powerful approach for assessing ecosystem change across spatiotemporal scales.