bluuebunny/crossref_metadata_2025_split huggingface dataset:
Observation of a New Co-F Compound Detected by Very-High-Energy X-ray Diffraction During Thermal Decomposition of CoF3
Authors: Rau J V , Albertini V Rossi , Chilingarov N S , Colonna S , Michiel M di 
Published: September 2002

Abstract
In situ diffraction studies of structural transformations occurring during thermal decomposition of a cobalt fluoride-CoF3-were performed using a very-high-energy (89 keV) synchrotron radiation. The real-time evolution of the crystal lattice was followed as a function of temperature. A new compound appearing as intermediate in the course of the decomposition from CoF3 to CoF2 was discovered.
Spin-Lattice Relaxation Times of Aliphatic Spin Probes in a Unique Triglyceride Membrane
Authors: Nakagawa Kouichi 
Published: September 2002

Abstract
Spin-lattice relaxation times of the spin probe moiety in the HCO membrane were obtained for the first time. The Tle becomes shorter with the probe site going toward the inner chain as well as with a rise in temperature. The spin dynamics were consistent with EPR lineshape observed.
Structural Study on Amorphous AlPO4 by 17O MQMAS and Mutual (31P↔17O) CP/MAS NMR
Authors: Kanehashi Koji , Saito Koji 
Published: September 2002

Abstract
The 17O multiple quantum magic angle spinning (MQMAS) and the mutual (31P↔17O) CP/MAS (MCP) NMR was applied to clarify the detailed chemical structure in amorphous AlPO4. An application of the mutual CP/MAS method being capable of mapping out the connectivity with the 17O MQMAS for characterization of oxygen sites provided precious structural information in amorphous AlPO4.
Synthesis and Magnetic Properties of Mesoporous Vanadium Oxide Sulphate
Authors: Kohiki Shigemi , Shimooka Hirokazu , Takada Syozo , Shimizu Akihiko , Hirakawa Tomohiro , Takahashi Seiji , Deguchi Hiroyuki , Oku Masaoki 
Published: September 2002

Abstract
Preparation and magnetic properties of mesostructured VOSO4 based materials, which were synthesized using liquid-crystal templating technique, have been investigated. Low temperature magnetic properties of the samples exhibited Langevin paramagnetism with an effective magnetic moment μeff=1.4 μB and a paramagnetic Curie point θ=0 K without any magnetic transition, which were considerably different from magnetic properties of α- or β-VOSO4 crystals.
Catalytic Application of Zeolites in the Methanol Conversion to Hydrocarbons
Authors: Aramendía María A , Borau Victoriano , Jiménez César , Marinas José M , Roldán Rafael , Romero Francisco J , Urbano Francisco J 
Published: September 2002

Abstract
The product compositions in the methanol conversion to hydrocarbons over several zeolites are compared and discussed. Although a great number of different compounds are present, small alkanes, such as isobutane and isopentane, and polymethylbenzenes are the major compounds over zeolites beta, mordenite and faujasite. However, zeolite ferrierite is quite selective for alkenes. Also, zeolite beta can transform acetone into hydrocarbons.
Engineering a Hydrophilic Heme Catalytic Pocket into Microsomal Cytochrome b5: Construction of Novel Metalloproteins with High Peroxidase-like Activity
Authors: Wang Wen-Hu , Wang Yun-Hua , Lu Jun-Xia , Wang Jian-Hua , Xie Yi , Huang Zhong-Xian 
Published: September 2002

Abstract
We have engineered novel hemoproteins with high catalytic activity by introducing several hydrophilic residues in the axial ligand of microsomal cytochrome b5, an electron transfer protein. Some (H39S and H39Q) of these mutants possess quite high peroxidase-like reactivity as designed. One (H39C) of them shows very low catalytic reactivity, and this may be attributed to the unique hexa-coordination (His-Fe3+-Cys) for this mutant.
Control of Pore Structure of Mesoporous Smectite-type Materials Containing Cobalt Cations in Octahedral Sheets
Authors: Shirai Masayuki , Aoki Kuriko , Torii Kazuo , Arai Masahiko 
Published: September 2002

Abstract
Mesoporous materials with a smectite-type structure containing cobalt divalent cations in octahedral sheets (MST(Co)) are synthesized by the calcination of the mixture of dimethydistearyl ammonium chloride and silicate fragments synthesized with a hydrothermal method, their pore properties of the MST(Co) samples being able to control with hydrothermal conditions.
Enantioselective Binding of Amino Acid Derivatives onto Imprinted TiO2 Ultrathin Films
Authors: Lee Seung-Woo , Ichinose Izumi , Kunitake Toyoki 
Published: September 2002

Abstract
Ultrathin films of titanium oxide gel that are imprinted with carbobenzyloxy-L (and D)-amino acids (Cbz-Ala, Cbz-Leu, and Cbz-Phe) were prepared on gold-coated QCM electrodes. The imprinted films showed much better binding for template stereoisomers than the corresponding enantiomers. The chiral separation factor increased with increasing sizes of the amino acid side chain.
Infrared Electroabsorption Spectroscopic Study of Association Structures of 5CB in the Solution, Isotropic Liquid and Nematic Liquid Crystal States
Authors: Min Young-Kun , Hiramatsu Hirotsugu , Hamaguchi Hiro-o 
Published: September 2002

Abstract
The association structures of 4-n-pentyl-4’-cyanobiphenyl (5CB) in the solution, isotropic liquid, and nematic liquid crystal states have been studied by infrared electroabsorption spectroscopy. In a 0.5 mol dm-3 carbon tetrachloride solution, the determined value of dipole moment of 5CB (4.9D) agrees excellently with a literature value (4.85D) for monomer, indicating that the 5CB molecule exist as a monomer. Monomeric response of the 5CB molecule to the external field has also been found for the isotropic liquid state. For the nematic phase, marked deviation from the monomeric response has been found, showing the domain formation of the 5CB molecules. The size dependence of the domain response to the applied electric field has also been elucidated.
Synthesis of a New Layered Manganese Oxide Nanocomposite through a Delamination/Reassembling Process
Authors: Liu Zong-huai , Yang Xiaojing , Makita Yoji , Ooi Kenta 
Published: September 2002

Abstract
A new layered nanocomposite with propylamine-containing silica between the manganese oxide sheets was synthesized for the first time through a delamination/reassembling process. It had a higher ordered stacked structure than the silica-pillared manganese oxide obtained by the conventional intercalation reaction.
A Chemical Modification of a Mn12 Single-Molecule Magnet by Replacing Carboxylate Anions with Diphenylphosphate Anions
Authors: Kuroda-Sowa Takayoshi , Fukuda Satoshi , Miyoshi Shinsuke , Maekawa Masahiko , Munakata Megumu , Miyasaka Hitoshi , Yamashita Masahiro 
Published: September 2002

Abstract
Diphenylphosphate anions can replace with benzoate anions of [Mn12O12(O2CPh)16(H2O)4] to afford a novel Mn12 single-molecule magnet (SMM) with mixed bridging ligands.
Characterization of Photochemical Reaction in Photosensitive Printing Plates by 13C NMR in the Bulk State and ATR FTIR Spectroscopy
Authors: Sakaguchi Yoshimitsu , Yamada Takatoshi , Okazaki Yasuyuki , Imahashi Satoshi , Kawahara Keizo 
Published: September 2002

Abstract
Photochemical reaction in a flexographic printing plate was characterized. The distribution of photochemical reaction in the direction of thickness was successfully understood by the combination of overall reactivity obtained by 13C NMR measurement and reactivity near the surface obtained by ATR FTIR spectroscopy.
Mg2+-Selective Fluorescence Enhancement of Benzo-15-crown-5 Derivative Bearing Vinylanthracene Fluorophore
Authors: Shin Eun Ju 
Published: September 2002

Abstract
A fluoroionophore, 1-(anthryl)-2-(benzo-15-crown-5)ethene, was synthesized. This crown ether derivative showed remarkably high cation-induced fluorescence enhancement for magnesium ion.
Three-Component Condensation of Meldrum’s Acid with Aldehyde and Thiol Catalyzed by Polymer-Supported Reagent
Authors: Yadav J S , Syamala M 
Published: September 2002

Abstract
Piperazinomethyl polystyrene serves as an efficient and reusable catalyst in acetic acid (piperazinomethyl polystyrene acetate) for the three component condensation reaction of Meldrum’s acid, aldehyde and a thiol which affords the corresponding spirocyclic derivatives in good yields and purity.
Isolation of Single-wall Carbon Nanotube Bundles Through Gelatin Wrapping and Unwrapping Processes
Authors: Takahashi Teruo , Tsunoda Katsunori , Yajima Hirofumi , Ishii Tadahiro 
Published: September 2002

Abstract
The isolation of single-wall carbon nanotube (SWNT) bundles and purification of these SWNTs were investigated by dispersing the SWNTs in an aqueous gelatin solution. TEM images of the SWNTs dispersed in the gelatin solution showed that the interaction between the gelatin molecules and the SWNTs produces a transformation of the SWNT bundles into thin bundles. Raman spectra measurements revealed that dispersing the SWNTs in the gelatin solution is a good purification procedure for the SWNTs.
Novel Linear and Hyperbranched Aromatic Polyamide with Phenylazometine Units for Chemical Recycling
Authors: Yamamoto Kimihisa , Higuchi Masayoshi , Kanazawa Hirohiko 
Published: September 2002

Abstract
Novel linear and hyper-branched aromatic polyamides having phenylazomethine units were synthesized by the polycondensation of di- or triamine monomers containing azomethine bonds with dicarboxylic acids. The polymers obtained have a high solubility in DMF unlike polyphenylazomethines, a high thermal stability (Td10%&gt;500 °C), and is susceptible to a simple and selective acid catalyzed decomposition for chemical recycling.
Enhanced Third-order Optical Nonlinearities of Au-CdS Core-Shell Nanoparticles Embedded in BaTiO3 Thin Films
Authors: Yang Yong , Shi Jianlin , Chen Hangrong , Dai Shugang , Liu Ye 
Published: September 2002

Abstract
Au-CdS core-shell nanoparticles (CSNs) are synthesized by a simple method based on directly self-assembling process and successfully integrated into BaTiO3 films. The significant enhancement of third-order nonlinear optical nonlinearities of Au-CdS CSNs were reported for the first time.
STM Observation of Single Molecular Chains of π-Conjugated Polymers
Authors: Kasai Hitoshi , Tanaka Hiroyuki , Okada Shuji , Oikawa Hidetoshi , Kawai Tomoji , Nakanishi Hachiro 
Published: September 2002

Abstract
Single molecular chains of π-conjugated polymers such as polythiophene and polydiacetylene were clearly observed by STM, and their molecular structures and/or conformation were discussed in relation to bonding characteristics. It should be noted that even molecular weight could be determined using well-resolved STM images.
Stereoselective Crossed Aldol Reaction via Boron Enolate Generated from α-Iodoketones and 9-BBN-H
Authors: Mukaiyama Teruaki , Imachi Shouhei , Yamane Keiko , Mizuta Masahiro 
Published: September 2002

Abstract
Boron enolates were in situ generated smoothly by treating α-iodo ketones with 9-BBN-H, and aldols were produced in highly diastereoselective manner by successive reaction with various aldehydes at low temperature.
Catalytic Decomposition of Phenyl Acetate by Halide Clusters of Nb, Mo, Ta, and W Possessing Octahedral Metal Core
Authors: Chihara Teiji , Kamiguchi Satoshi 
Published: September 2002

Abstract
The application of hexanuclear halide clusters as catalysts was made. Molecular halide clusters of Nb, Mo, Ta, and W possessing an octahedral metal core were treated in a helium stream at 250 °C for 1 h before introduction of phenyl acetate. These clusters served as catalysts for decomposition of the ester to phenol and ketene. Raman and X-ray analyses showed that the development of the catalytic activity was attributable to the partial loss of the inner halogen ligands.
First-Principles Energy Band Calculation for SrAl2O4 with Monoclinic Structure
Authors: Matsushima Shigenori , Nakamura Hiroyuki , Arai Masao , Xu Chao-Nan 
Published: September 2002

Abstract
The electronic structure of strontium aluminate, SrAl2O4, is calculated by using the scalar-relativistic full potential linearized augmented plane wave (FLAPW) method. SrAl2O4 is predicted to be an indirect-gap material, since the valence band maximum locates near Z point and the conduction band minimum at Γ point. The valence band with the width ca. 5.3 eV is mainly constructed from O 2p orbitals, where Al 3s3p and Sr 5s5p slightly hybridize with O 2p, and the lower conduction band from Sr 5s orbitals.
Bone-Like Apatite Formation On Collagen Fibrils By Biomimetic Method
Authors: Girija E K , Yokogawa Y , Nagata F 
Published: September 2002

Abstract
Formation of collagen-apatite composite by biomimetic methods without any previous treatment of the collagen fibrils has been investigated. Reconstituted collagen fibrils obtained from Type I collagen solution were incubated in conventional and revised simulated body fluid (C and R-SBF) solutions to form calcium phosphate. Spherical deposits of B-type carbonate apatite started precipitating along the fibrils from day 1 of incubation in both C and R-SBF. But the large number of carbonate ions in R-SBF has changed the microstructure of the apatite precipitates. The calcium rich apatite deposits are more in R-SBF than in C-SBF. Percentage of Cl- ions in the precipitates of R-SBF were less than in C-SBF.
Low-Molecular-Weight Hydrogelators Based on L-Lysine with Various Pyridinium Cations
Authors: Suzuki Masahiro , Yumoto Mariko , Kimura Mutsumi , Shirai Hirofusa , Hanabusa Kenji 
Published: September 2002

Abstract
L-Lysine derivatives act as low-molecular-weight hydrogelators that can gel water below 1 wt%.
Assembling Behavior of BINAP Derivative
Authors: Wu Peng , Deng Guojun , Fan Qinghua , Zeng Qingdao , Wang Chen , Wan Lijun , Bai Chunli 
Published: September 2002

Abstract
Ordered assembly of dendritic BINAP ligand has been studied by using scanning tunneling microscopy (STM). It is proposed that the molecules are arranged in a dimeric manner in the assembly.
Copper-mediated Coupling Reaction of Kinetically Stabilized 1-Methyl-2-phosphaethenyllithiums Involving an Isomerization to a 3-Phospha-2-propenyllithium Derivative
Authors: Ito Shigekazu , Kimura Shigeo , Yoshifuji Masaaki 
Published: September 2002

Abstract
Copper-mediated coupling reaction of 1-methyl-2-(2,4,6-tri-t-butylphenyl)-2-phosphaethenyllithiums afforded 1,4-diphosphabuta-1,3-diene or 1,6-diphosphahexa-1,5-diene derivatives, depending upon non-coordinated or coordinated to W(CO)5, which facilitates an isomerization to a 3-phospha-2-propenyllithium.
Diastereoselective Synthesis of 4-Substituted L-Prolines by Intramolecular Radical Cyclization of N-Aryl sulphonyl-N-allyl 3-bromoalanines: Interesting Dependence of Selectivity on the Nature of Sulphonamido Groups
Authors: Basak Amit , Bag Subhendu Sekhar , Rudra Kakali Rani , Barman Jharna , Dutta Sumana 
Published: September 2002

Abstract
Enantiopure 4-substituted L-proline derivatives have been prepared via intramolecular radical cyclization of N-aryl sulphonyl-N-allyl-3-bromo-L-alanines in high yields. Surprisingly, the extent of selectivity was found to be primarily dependent on the nature of sulphonamido aryl group and could be as high as 33:1 using naphthyl sulphonamide.
Reduction of Oxygen at an Electrode Modified by Cobaltporphyrin Liquid Membrane
Authors: Shentu Baoqing , Oyaizu Kenichi , Nishide Hiroyuki 
Published: September 2002

Abstract
The picket-fence cobaltporphyrin (CoP) having rapid and reversible oxygen-binding properties was employed to accumulate oxygen from a bulk solution to a diffusion layer at an electrode surface. Modification of a carbon electrode with a thin CoP liquid membrane resulted in a significant increase in the reduction current of oxygen, which proved to be a new type of modified electrode to reduce the diffusion resistance of oxygen from the bulk solution onto the electrode surface.
Biomimetic Approach for Exact Control of TiO2 Periodic Microstructures
Authors: Yamabi Satoshi , Imai Hiroaki , Awazu Koichi 
Published: September 2002

Abstract
Periodic array of titanium dioxide (TiO2) microprojections was fabricated in aqueous solutions using poly(methylmethacrylate) (PMMA) films with ordered microcavities as a mold. The periodic microprojections consisting of crystalline TiO2 exquisitely transcribed the architecture of the mold without deformation or shrinkage. This biomimetic route including preferable nucleation on the specific organic surface and subsequent growth of the crystalline phase at a low temperature is applicable to construct three-dimensional periodic architectures for photonic structures of various metal oxides.
Hydrolytic Activity of A FeIIIZnII Complex toward Di(p-nitrophenyl) Phosphate: A Functional Model of Heterobimetallic Phosphodiestelase
Authors: Machinaga Hironobu , Matsufuji Kanako , Ohba Masaaki , Kodera Masahito , Okawa Hisashi 
Published: September 2002

Abstract
A FeIIIZnIII complex, [FeZn(L)(AcO)3]BPh4·H2O, of 2-{N-[2-(dimethylamino)ethyl]iminomethyl}-6-[N,N-di(2-pyridyl-methyl)aminomethyl]-4-methylphenolate (L-) hydrolyses tri(p-nitrophenyl) phosphate (TNP) into di(p-nitrophenyl) phosphate (DNP-) and DNP- into mono(p-nitrophenyl) phosphate (MNP2-) in aqueous DMF.
Oxidative Decarboxylation of 4-Arylmethylidene-5(4H)-oxazolones Using Cerium(IV) Ammonium Nitrate
Authors: Ram S Raja , Devi A Rama , Iyengar D S 
Published: September 2002

Abstract
Oxidative decarboxylation of azlactones by cerium(IV) ammonium nitrate yields 2-arylglyoxylamide in very good yields.
Synthesis and Reactions of Water-soluble Diorganoplatinum(II) Complexes
Authors: Komiya Sanshiro , Ikuine Miho , Komine Nobuyuki , Hirano Masafumi 
Published: September 2002

Abstract
Ligand displacement reactions of PtR2(cod) with water soluble tertiary phosphines such as 1,2-bis{di(hydroxymethyl)-phosphino}ethane (DHMPE) or tris(hydroxymethyl)phosphine (THMP) gave new water-soluble diorganoplatinum(II) complexes PtR2L2 [L2=(HOCH2)2PCH2CH2P(CH2OH)2: R=Me (1a); Et (1b); Ph (1c), L=P(CH2OH)3: R=Me (2a); Et (2b); Ph (2c)] at room temperature. They were considerably stable in water and the thermolyses of 1b and 2b at 80 °C liberate ethylene and ethane via β-hydrogen elimination and hydrolysis.
Monolayer Formation and In-Plane Anisotropy of an Amphiphilic Block Molecule
Authors: Qin Lidong , Wu Lixin , Li Hongbo , Hou Xueliang , Qiu Dengli , Shen Jiacong 
Published: September 2002

Abstract
Coverage controlled monolayer nano-sheets with homogeneous height were fabricated by casting aqueous solution of amphiphilic rod-coil diblock molecule 1 on mica surface. The monolayer sheet was anisotropic, due to the asymmetric arrangement of the diblock molecule on surface, confirmed by polarization-dependent fluorescence spectra.
Switching of Terbium(III)-sensitized Luminescence by Ligand Exchange Reaction: Determination of Catecholamines
Authors: Takahashi Yukiko , Tanaka David A Pacheco , Matsunaga Hideyuki , Suzuki Toshishige M 
Published: September 2002

Abstract
Ligand exchange reaction between catecholamines and sulfosalicylic acid (SSA) in the ternary complex, [Tb(SSA)EDTA]4- leads to switch the luminescence signal, providing a simple detection system of catecholamines available in an aqueous solution.
A Benzene-Thermal Synthesis of Cubic Boron Phosphide (BP) Ultrafine Powders
Authors: Gu Yunle , Zheng Huagui , Guo Fan , Qian Yitai , Yang Ziping 
Published: September 2002

Abstract
Ultrafine boron phosphide (BP) with cubic cell was synthesized via a benzene-thermal reaction of boron powder and phosphorus trichloride (PCl3) with metallic lithium or sodium at 350 °C in an autoclave; initiating a new route and developing a facile technique for preparing BP.
DTBB-Catalyzed Lithiation of 4-Hetero-substituted Dibenzothiins
Authors: Yus Miguel , Foubelo Francisco , Ferrández José V 
Published: September 2002

Abstract
The DTBB-catalyzed lithiation of 4-hetero-substituted dibenzothiins (phenoxathiin, phenothiazine, and thianthrene) gives the corresponding functionalized organolithium intermediates, which by reaction with different electrophiles afford the expected functionalized thiols. The cyclization of some alcohol compound derivatives gives the corresponding homologous seven-membered dibenzo heterocycles.
Regio- and Stereoselective Synthesis of a trans-4-[60]Fullerenobisacetic Acid Derivative by a Tether-Directed Biscyclopropanation: A Diacid Component Applicable for the Synthesis of Regio- and Stereo-regular [60]Fullerene Pearl-Necklace Polyamides
Authors: Hino Tetsuo , Hamada Masahiro , Kinbara Kazushi , Saigo Kazuhiko 
Published: September 2002

Abstract
A trans-4-[60]fullerenobisacetic acid derivative was easily obtained from its diethyl ester, which was regio- and stereoselectively prepared by the biscyclopropanation of [60]fullerene with a tethered bis(α-bromophenylacetate) derivative. The polycondensation of the resultant fullerenobisacetic acid with aromatic diamines proceeded smoothly to give the corresponding regio- and stereo-regular [60]fullerene pearl-necklace polyamides in excellent yields.
Convergent and Convenient Total Synthesis of Phytoalexin-Elicitor Active Heptasaccharide by One-Pot Sequential Glycosylation
Authors: Mukaiyama Teruaki , Ikegai Kazuhiro , Hashihayata Takashi , Kiyota Koichi , Jona Hideki 
Published: September 2002

Abstract
Convergent and convenient total synthesis of branched hepta-β-glucoside 1 having phytoalexin-elicitor activity was efficiently accomplished by way of two one-pot sequential glycosylation reactions. Trisaccharide 8 was synthesized in high yield by TfOH-catalyzed one-pot glycosylation using three component monosaccharides and subsequent selective deprotection of a 6′-O-TBDPS group. The second one-pot glycosylation of trisaccharide 8 with the three monosaccharides smoothly proceeded to afford heptaglucoside 11 stereoselectively in 48% total yield based on monosaccharide 3. The targeted compound 1 was obtained in high yield after the removal of the protecting groups.
Ligand-assisted Solvothermal Growth of CdS Nanowires
Authors: Gao Feng , Lu Qingyi , Zhao Dongyuan 
Published: September 2002

Abstract
A simple ligand-assisted solvothermal process has been proposed to synthesize CdS nanowires with aspect ratio (average length/average diameter) up to 100. The simultaneous employment of two types of templates, coordinating solvent ethylenediamine (En) and ligand 8-hydroxyquinoline, has been found to be the key factor for the synthesis of one dimensional nanomaterials with high aspect ratio. By adjusting the concentration of the ligand, the produced one-dimensional nanomaterials can be elongated from 300 nm to 3.0 micrometers with unchanged diameter.
[Pt(CN)2·2Me3SnCN·2Me3SnOH·bpe]n (bpe=trans-1,2-bis(4-pyridyl)ethylene), the First Double-Sinusoidal Platinum-Tin Coordination Polymer
Authors: Chen Wanzhi , Fenghui Liu , You Xiaozeng 
Published: September 2002

Abstract
The coordination polymer [Pt(CN)2·2Me3SnCN·2Me3SnOH·bpe]n was prepared and structurally characterized by X-ray diffraction analysis which consists of one-dimensional double-sinusoidal chains.
Ta3N5 as a Novel Visible Light-Driven Photocatalyst (λ&lt;600 nm)
Authors: Hitoki Go , Ishikawa Akio , Takata Tsuyoshi , Kondo Junko N , Hara Michikazu , Domen Kazunari 
Published: September 2002

Abstract
A transition metal nitride, Ta3N5, is a novel photocatalyst responding to visible light. Ta3N5 evolves H2 and O2 by visible light (λ&lt;600 nm) irradiation in the presence of sacrificial electron donor and acceptor, respectively without any noticeable photo-anodic or cathodic corrosion, representing a candidate for overall water splitting by visible light.
Shift of the Iron Corrosion Potential and Acceleration of the Mass Transport of Dissolved Oxygen by the Micro-MHD Effect
Authors: Shinohara Kenji , Hashimoto Kazuhito , Aogaki Ryoichi 
Published: September 2002

Abstract
Change in the corrosion rate of iron under a high magnetic field was examined by determining corrosion potential shifts and polarization curve measurements. With increasing magnetic flux density, the electrode potential shifted to the anodic side. This was induced by a cathodic diffusion current increment via a microscopic stirring effect in the local magnetohydrodynamic flow, which arose from interaction between the electrochemical corrosion current and the applied magnetic field.