bluuebunny/crossref_metadata_2025_split huggingface dataset:
PENGARUH KEPUASAN KERJA DAN KOMITMEN ORGANISASIONAL TERHADAP TURNOVER INTENTION (Studi Kasus pada de Vins Sky Hotel Seminyak)
Authors: Narti Ni Ketut , Lasmini Ni Ketut , Marheni Lily , Sawitri Made Yani 
Published: December 2023

Turnover intention is a thought possessed by every employee to stop working. The purpose of this study is to determine the effect of job satisfaction partially on turnover intention, the effect of organizational commitment partially on turnover intention and the effect of job satisfaction and organizational commitment simultaneously on turnover intention. The population used in this study were all de Vins Sky Hotel, Seminyak employees, totaling to 91 employees. Data collection is done through interviews and questionnaires. The analysis technique used is the classical assumption test, multiple linear regression analysis, correlation coefficient analysis, coefficient of determination analysis, t-test and f test. The result of analysis shows that job satisfaction has a negative and significant effect on turnover intention. Organizational commitment has a negative and significant effect on turnover intention. While simultaneously job satisfaction and organizational commitment significantly influence turnover intention.
ANALISIS PENDAPATAN PETANI TERHADAP PEREKONOMIAN MASYARAKAT DI DESA ADAT ASAK
Authors: Ari Sudiartini Ni Wayan , Santika Dewi Ni Putu 
Published: December 2023

The purpose of the study, among others, is to analyze the income of farmers producing rice for the communityâ€™s economy. The study was conducted on 6 sample farmers in the Asak Adat Village in the Karangasem District, Karangasem Regency, Bali. Data collection is done by interview and documentation techniques. The analytical tool used is income analysis. The results showed that the results calculated by the method of analysis of farm income according to Soekarwati (2006: 58). Shows that the income of rice farmers in terms of the average yield per acre is Rp. 186,160 and the average income per 3 months is only Rp. 3,210,000 which is far below the minimum wage, so the results of this study show that farmers who earn below the minimum wage are not sufficient for their daily needs and cannot even guarantee long-term or future life. The factors of area of arable land, the amount of effective labor, the amount of fertilizer, the amount of pesticides, the experience of farmers in trying to farm, the distance of the farmerâ€™s house to arable land, and the irrigation system have a very significant effect on increasing the production of lowland rice, whereas, the experience of farmers has no effect ( non significant) to increase paddy rice production.
PERHITUNGAN HARGA JUAL MASSA COR CN-17A SEBAGAI DASAR USULAN TARIF BAHAN BAKU KERAMIK PADA BTIKK
Authors: Normal I Nyoman , Siagian Arifin 
Published: December 2023

The aims of this research are: (1) calculating and evaluating the basic tariff for the latest raw material technology services on the bulk selling price of CN-17A castings; (2) determine the effect of raw material technology service rates on the cost of production; (3) determine the effect of raw material technology service rates on profitability; and (4) proposing tariffs for new raw material technology services. The results showed that: (1) The theoretical raw material technology service tariff for CN-17A pouring mass was IDR 8,648.60 per liter, but the last tariff was IDR 4,500 per kg; (2) The tariff for raw material technology services affects the cost of goods manufactured. Raw material technology service rates are in accordance with PP. 51 of 2018 resulted in the cost of production of Rp 4,090.91 per kg, while the cost of goods manufactured should be Rp 8,862.36 per liter; (3) Tariffs for raw material technology affect profitability. The tariff for raw material technology services according to PP. 51 of 2018 is lower than it should be IDR 75.80 per kg (liter); and (4) the latest tariffs for ceramic raw material technology services need to be revised to reflect more realistic conditions.
PERAN CITRA MEREK MEMEDIASI PENGARUH SOCIAL MEDIA MARKETING TERHADAP BOOKING INTENTION PADA CHAIN HOTEL DI BALI
Authors: Dewi Rahmayanti Putu Laksmita , Suartina I Wayan , Sumerta I Komang 
Published: December 2023

The economy in Bali relies on tourism sector, but due to the Covid-19 outbreak, regional income in Bali decreased in 2020. The tourism accommodation sector is one sort of business involved in the affected tourism industry. Bali has a large number of hotels, particularly chain hotels such as Aston, Ibis, Harris, Fave, and Horizon Hotels. When compared to local hotels, the hotel chain has the strength of a strong brand because it is more well-known. However, hotel chains in Bali were also affected by the Covid-19 outbreak, as seen by the decreased occupancy rate. As a result, the researcher investigated the role of brand image in mediating the effect of social media marketing on chain hotel booking intentions in Bali. Data was gathered by having 70 domestic tourists fill out google form questionnaire. Purposive sampling was utilized as the sample technique. SMART-PLS 3.0 was used to analyze the data. The findings of this study show that social media marketing has a positive and significant effect on brand image, that social media marketing has a positive and significant effect on booking intention, that social media marketing has a positive and significant effect on booking intention, and that the brand image variable can mediate the influence of social media marketing on booking intention.
Assessment of the effects of transforming growth factor beta1 (TGF-β1)-Smad2/3 on fibrosis in rat myofascial trigger points using point shear wave elastography
Authors: Fang Xin , Yin Yalong , Lun Haimei , Su Shitao , Zhu Shangyong 
Published: December 2023

Background & Aims
Myofascial trigger points (MTrPs) are highly sensitive irritated points within a tense belt of skeletal muscle, and are the main cause of muscle pain and dysfunction. MTrPs can also cause paraesthesia and autonomic nervous dysfunction. Furthermore, long-term and chronic MTrPs can cause muscle atrophy and even disability, seriously affecting the quality of life and mental health of patients, and increasing the social and economic burden. However, to date, there have been few studies on fibrogenesis and changes in MTrPs. Therefore, this study investigated whether transforming growth factor beta1 (TGF-β1)-Smad2/3 participates in the formation of MTrPs and how it affects fibrosis using point shear wave elastography.

Methods
Forty Sprague‒Dawley rats were randomly divided into the MTrPs group and the control group. Blunt injury combined with eccentric exercise was used to establish an MTrPs model. Electromyography (EMG), haematoxylin and eosin (H&E) staining and transmission electron microscopy (TEM) were used to verify the model. The collagen volume fraction was measured by Masson staining, the protein expression of TGF-β1 and p-Smad2/3 was measured by Western blotting (WB) and immunohistochemistry (IHC), and the shear wave velocity (SWV) was measured by point shear wave elastography.

Results
EMG, H&E and TEM examination indicated that the modelling was successful. The collagen volume fraction and the protein expression of TGF-β1 and p-Smad2/3 were higher in the MTrPs group than in the control group. The SWV of the MTrPs group was also higher than that of the control group. These differences suggest that MTrPs may exhibit fibrosis. The correlations between the collagen volume fraction and SWV and between the collagen volume fraction and TGF-β1 were positive.

Conclusion
Fibrotic conditions may be involved in the formation of MTrPs. Ultrasound point shear wave elastography and assessment of TGF-β1 and p-Smad2/3 expression can reflect the degree of MTrPs fibrosis to some extent. Further exploration of the important role of TGF-β1 and Smad2/3 in the pathogenesis of MTrPs will be of great significance for clinical treatment.
Economic Burden of Health Conditions Associated With Adverse Childhood Experiences Among US Adults
Authors: Peterson Cora , Aslam Maria V. , Niolon Phyllis H. , Bacon Sarah , Bellis Mark A. , Mercy James A. , Florence Curtis 
Published: December 2023

ImportanceAdverse childhood experiences (ACEs) are preventable, potentially traumatic events in childhood, such as experiencing abuse or neglect, witnessing violence, or living in a household with substance use disorder, mental health problems, or instability from parental separation or incarceration. Adults who had ACEs have more harmful risk behaviors and worse health outcomes; the economic burden associated with these issues is uncertain.ObjectiveTo estimate the economic burden of ACE-associated health conditions among US adults.Design, Setting, and ParticipantsIn this economic evaluation, regression models of cross-sectional survey data from the 2019-2020 Behavioral Risk Factor Surveillance System (BRFSS) and previous studies were used to estimate ACE population-attributable fractions (PAFs) (ie, the fraction of total cases associated with a specific exposure) for selected health outcomes (anxiety, arthritis, asthma, cancer, chronic obstructive pulmonary disease, depression, diabetes, heart disease, kidney disease, stroke, and violence) and risk factors (heavy drinking, illicit drug use, overweight and obesity, and smoking) among the 2019 US adult population. Adverse childhood experience PAFs were used to calculate the proportion of total condition-specific medical spending and lost healthy life-years related to ACEs using Global Burden of Disease Study data. Data analysis was performed from September 10, 2021, to November 29, 2022.ExposureAdverse childhood experiences (age &amp;lt;18 years).Main Outcomes and MeasuresMonetary valuation of ACE-associated morbidity and mortality using standard US value of statistical life methods and presented in terms of annual and lifetime per affected person and total population estimates at the national and state levels.ResultsA total of 820 673 adults, representing 255 million individuals, participated in the BRFSS in 2019 and 2020. An estimated 160 million of the total 255 million US adult population (63%) had 1 or more ACE, associated with an annual economic burden of $14.1 trillion ($183 billion in direct medical spending and $13.9 trillion in lost healthy life-years). This was $88 000 per affected adult annually and $2.4 million over their lifetimes. The lifetime economic burden per affected adult was lowest in North Dakota ($1.3 million) and highest in Arkansas ($4.3 million). Twenty-two percent of adults had 4 or more ACEs and comprised 58% of the total economic burden—the estimated per person lifetime economic burden for those adults was $4.0 million.Conclusions and RelevanceIn this cross-sectional analysis of the US adult population, the economic burden of ACE-related health conditions was substantial. The findings suggest that measuring the economic burden of ACEs can support decision-making about investing in strategies to improve population health.
Regulating Graphitic Microcrystalline and Single‐Atom Chemistry in Hard Carbon Enables High‐Performance Potassium Storage
Authors: Xu Wenbin , Li Huaidong , Zhang Xinyue , Chen Tsung‐Yi , Yang Hao , Min Huihua , Shen Xiaodong , Chen Han‐Yi , Wang Jin 
Published: December 2023

AbstractHard carbon (HC) has attracted considerable research interest as the most promising anode for potassium‐ion batteries (PIBs) due to its tunable interlayer spacing and abundant voids to accommodate K+. However, the practical application of hard carbon is severely hampered by low initial Coulombic efficiency (ICE) and high plateau potential. Herein, a manganese ion‐catalyzed pyrolysis strategy is explored to regulate the graphitic microcrystalline structure and localized electron distribution in hard carbon that greatly improve K+ plateau storage and ICE. Systematic experimental measurements, in situ/ex situ observations, dynamic analysis, and density functional theory calculations elucidate that the introduction of Mn2+ ions could catalyze the formation of short‐ordered graphitic nanodomains in hard carbon to provide abundant insertions of K+, and meanwhile induce localized electron distribution through the Mn─N3─C coordination structure to enable dynamic K+ diffusion and electron transfer kinetics. Consequently, the modulated hard carbon exhibits a high low‐potential–plateau capacity, excellent rate capability, and high initial Coulombic efficiency in potassium half‐cell configurations. More importantly, the charge storage mechanism of “adsorption–intercalation” is proposed based on the correlation between carbon structures and discharge/charge plateau. This work provides an in‐depth insight into the fundamentals of microstructure regulation of hard carbon anode for high‐performance PIBs.
Boosting MRSA Infectious Osteoporosis Treatment: Mg‐Doped Nanofilm on Vacancy‐Enriched TiO2 Coating for Providing In Situ Sonodynamic Bacteria‐Killing and Osteogenic Alkaline Microenvironment
Authors: Chen Shimeng , Liu Fuwei , Xin He , Wen Dan , Zhang Yingang , Li Bo , Han Yong 
Published: December 2023

AbstractTo effectively combat infectious osteoporosis, Ti‐based implants with enhanced antibacterial and osseointegrative properties are urgently required. Herein, a one‐step method involving Mg thermal‐reduction is employed to modify a hydroxyapatite (HA) array on Ti, which comprises an inner TiO2 layer and an outer nanorod‐like HA layer. This process introduces oxygen vacancies (OVs) into the TiO2 layer and deposits a Mg─O‐contained amorphous nanolayer on each HA nanorod. The introduced OVs enhance reactive oxygen species (ROS) yield by the array during ultrasound treatment via narrowing TiO2 bandgap and improving H2O molecules absorption. The produced ROS, combined with a weak alkaline microenvironment created by the degraded Mg─O nanolayer, endows the array with potent bacterial‐killing and biofilm‐eradicating efficacies within a 5 min ultrasound treatment via the combination of proton‐consumption and cell envelop‐detriment effects. Moreover, due to the alkaline microenvironment and the released Mg2+, the array hinders osteoclastogenesis by activating the inflammation‐related FAK‐PI3K‐AKT signaling pathway in macrophages, as revealed by transcriptomic analysis, resulting in robust osseointegration in rat femoral shaft with concurrent bacterial‐infection and osteoporosis. This work paves a new way for simultaneously endowing a sonosensitive coating on Ti with sonodynamic treatment‐derived high antibacterial ability and alkaline microenvironment‐mediated strong osseointegration for infectious osteoporosis treatment.
Recrystallization‐Induced Laser Lift‐Off Strategy for Flexible Thermal Sensors with Near‐Limit Sensitivity
Authors: Guo Dongliang , Ling Jinghui , Huang Yizhuo , Xiong Wennan , Xu Yixuan , Bai Yunzhao , Li Kan , Zhang Fan , Huang YongAn 
Published: December 2023

AbstractFlexible thermal sensors have attracted immense interest as an alternative to conventional rigid sensors in personal healthcare monitoring, biomedical applications, and human‐machine interaction. However, most metal‐based flexible thermal sensors exhibit low sensitivity, primarily resulting from electron scattering due to manufacturing defects. The heat‐intolerant polymer substrate hinders the pathway to improve the sensitivity of metal thin films through high‐temperature annealing. Herein, a recrystallization‐induced laser lift‐off strategy is proposed to overcome the contradiction between the flexible substrate and high‐temperature annealing. Systematically theoretical and experimental studies reveal the mechanism of thermal‐induced recrystallization in increasing the temperature coefficient of resistance (TCR) and the separation of sensors from rigid substrates. Valuable insights are acquired in the modulation of interface adhesion by altering the surface roughness of nickel. A critical temperature is provided to guide the detachment of the sensor. The fabricated thin‐film flexible thermal sensor achieves a TCR of 6.2‰°C−1, approaching the TCR limit of bulk material. This strategy opens a new general route for fabricating high‐temperature annealed sensors on flexible substrates.
Iron‐Catalyzed Direct C3−H Trifluoromethylthiolation of Quinoxalin‐2(1H)‐ones
Authors: Chen Xiaoyu , Geng Yang , Zhu Yu , Zou Dapeng , Wu Yangjie , Wu Yusheng 
Published: December 2023

AbstractAn iron‐catalyzed direct C3−H radical trifluoromethylthiolation of quinoxalin‐2(1H)‐ones has been developed. This protocol uses earth‐abundant FeSO4 ⋅ 7H2O as the catalyst, and AgSCF3 as the trifluoromethylthiolating reagent to provide various SCF3‐containing quinoxalin‐2(1H)‐one derivatives in 26–88% yields. Preliminary mechanistic investigations indicate that the reaction proceeds through a radical pathway.
Learning from Polymeric π‐Backbone to Film Sequences Unravels that a Coexistence of Bilayered and Mixed Morphologies Optimally Strengthens Thermoelectrics
Authors: Tang Junhui , Wu Zhiyuan , Li Wenhao , Zuo Guangzheng , Zhao Yan , Liang Ziqi 
Published: December 2023

Abstractπ‐Conjugated polymers can be manipulated at the molecular and thin‐film levels to strengthen thermoelectric performance. Herein, two distinctive polymers—PBDP‐T and PBDB‐T with respective outstanding Seebeck coefficient (S) and electrical conductivity (σ) are selected and their functional units are integrated to synthesize random terpolymers via the ′backbone sequence′ strategy. The resulting disordered π‐backbones of terpolymers however lead to an unsuccessful acquisition of high power factor (PF). Alternately, the ′film sequence′ strategy is utilized and representative high‐σ P2F and high‐S PTB7‐Th polymers are blended. Note that 3D conductive paths are generated in the blend films when the PTB7‐Th content falls between 35–80 wt%, which favors charge transportation and yields high σ. At an optimal 65 wt% PTB7‐Th, a maximum PF of 145.5 µW m−1 K−2 is obtained, far surpassing that of each parent polymer, which marks a breakthrough of the ′two‐phase combination′ rule. The peak PF achieved in medium PTB7‐Th content is attributed to the coexistence of bilayered and mixed morphologies, the former of which delivers slowly declining σ while the latter results in greatly elevated S with increasing PTB7‐Th. Given the notably lower thermal conductivity acquired in blend than neat polymers, the room‐temperature thermoelectric figure‐of‐merit as high as 0.15 is achieved.
Visible Light‐Induced Imide Alkylation of Azauracils with Aryl Diazoesters
Authors: Hota Sudhir Kumar , Murarka Sandip 
Published: December 2023

AbstractA visible light‐induced green and sustainable N−H functionalization of (aza)uracils with α‐diazo esters leading to imide alkylation is described. The reaction does not require any catalyst or additive and proceeds under mild conditions. Moreover, an intriguing three component coupling was observed when (aza)uracils were allowed to react with α‐diazo esters in cyclic ethers (e. g. 1,4‐dioxane, THF) as a solvent. Both the insertion and three‐component coupling features broad scope with good to excellent yields and appreciable functional group tolerance. Notably, the divergent method enables modification of natural products and pharmaceuticals, thereby facilitates access to potentially biologically active compounds.
Predictive Modeling in Service Line Inventory Development
Authors: Deheer Katie , Epstein Kristin , Cummings Joanna 
Published: December 2023

Key TakeawaysAcceptance of predictive modeling as a verification method in inventories complying with the Lead and Copper Rule Revisions is determined by individual states, many of which accept this approach.Predictive modeling is an accurate, time‐saving, economical way to reduce unknowns in the inventory and streamline lead service line replacement.For the best outcomes, the performance and reliability of predictive models must be evaluated carefully and from multiple perspectives.
To Fend Off Cyberattacks, Build a Castle
Authors: Sumner Michael 
Published: December 2023

Key TakeawaysWith the number and sophistication of cyberattacks increasing dramatically around the world, defensive and robust cybersecurity practices are a must.Using a Defense in Depth strategy offers water and wastewater utilities a multilayered system to guard against cyberattacks.Important cybersecurity barriers include risk assessments, access control, network segmentation, multifactor authentication, and security assessments.
An incarcerated epigastric hernia with unusual contents
Authors: Kulkarni Shrirang Vasant 
Published: December 2023

Key Clinical MessageAn epigastric hernia usually contains preperitoneal fat, but rarely may contain colon. This fact needs to be kept in mind by the operating surgeons.AbstractAn epigastric hernia usually contains preperitoneal fat, but rarely may contain colon. Experience with such a singular case is presented and discussed. This fact needs to be kept in mind by the operating surgeons.
1,2,3,4‐Tetrafluorobiphenylene: A Prototype Janus‐Headed Scaffold for Ambipolar Materials
Authors: Nikulshin Pavel V. , Makarov Alexander Yu. , Koskin Igor P. , Becker Christina S. , Kazantsev Maxim S. , Beckmann Jens , Balmohammadi Yaser , Grabowsky Simon , Mebs Stefan , Naumova Olga V. , Protasov Dmitry Yu. , Svit Kirill A. , Irtegova Irina G. , Radiush Ekaterina A. , Bagryanskaya Irina Yu. , Shundrin Leonid A. , Zibarev Andrey V. 
Published: December 2023

AbstractThe title compound was synthesized by Ullmann cross‐coupling in low yield as the first representative of [n]phenylene containing hydrocarbon and fluorocarbon rings. Stille/Suzuki‐Miyaura cross‐coupling reactions, as well as substitution of fluorine in suitable starting compounds, failed to give the same product. The geometric and electronic structures of the title compound were studied by X‐ray diffraction, cyclic voltammetry and density functional theory calculations, together with Hirshfeld surface and reduced density gradient analyses. The crystal structure features head‐to‐tail π‐stacking and other fluorine‐related secondary bonding interactions. From the nucleus‐independent chemical shifts descriptor, the four‐membered ring of the title compound is antiaromatic, and the six‐membered rings are aromatic. The Janus molecule is highly polarized; and the six‐membered fluoro‐ and hydrocarbon rings are Lewis π‐acidic and π‐basic, respectively. The electrochemically‐generated radical cation of the title compound is long‐lived as characterized by electron paramagnetic resonance, whereas the radical anion is unstable in solution. The title compound reveals electrical properties of an insulator. On expanding its molecular scaffold towards partially fluorinated [n]phenylenes (n≥2), the properties presumably can be transformed into those of semiconductors. In this context, the title compound is suggested as a prototype scaffold for ambipolar materials for organic electronics and spintronics.