bluuebunny/crossref_metadata_2025_split huggingface dataset:
Exploring an Adequate DFT Functional to Accurately Describe the Singlet Excited State Properties in HLCT Materials: A Benchmark Study
Authors: Jeon Sang Ho , Kang Sunwoo , Kim Taekyung 
Published: October 2023

AbstractThe popularly used global, meta‐GGA, and range‐separated hybrid DFT functionals are examined to compare the predictive qualities of singlet excited state (S1) properties in HLCT materials. Among these hybrid DFT functionals, it is clarified that both M06 and LC‐ω*HPBE functionals show quantitatively and qualitatively excellent predictions of absorption energies, compared to experiments. However, a discrepant behavior in predicting the emission energy is found that LC‐ω*HPBE functional obviously predicts more accurate emission energy than M06 functional. Also, the calculated τs values by means of M06 and LC‐ω∗HPBE functionals show that LC‐ω∗HPBE functional gives quantitatively and qualitatively superior prediction. Consequently, it is suggested that LC‐ω*HPBE functional should be used to conduct the essential photo‐physical properties of HLCT materials in S1 state.
Tuning the Coherent Propagation of Organic Exciton‐Polaritons through the Cavity Q‐factor
Authors: Tichauer Ruth H. , Sokolovskii Ilia , Groenhof Gerrit 
Published: October 2023

AbstractTransport of excitons in organic materials can be enhanced through polariton formation when the interaction strength between these excitons and the confined light modes of an optical resonator exceeds their decay rates. While the polariton lifetime is determined by the Q(uality)‐factor of the optical resonator, the polariton group velocity is not. Instead, the latter is solely determined by the polariton dispersion. Yet, experiments suggest that the Q‐factor also controls the polariton propagation velocity. To understand this observation, the authors perform molecular dynamics simulations of Rhodamine chromophores strongly coupled to Fabry–Pérot cavities with various Q‐factors. The results suggest that propagation in the aforementioned experiments is initially dominated by ballistic motion of upper polariton states at their group velocities, which leads to a rapid expansion of the wavepacket. Cavity decay in combination with non‐adiabatic population transfer into dark states, rapidly depletes these bright states, causing the wavepacket to contract. However, because population transfer is reversible, propagation continues, but as a diffusion process, at lower velocity. By controlling the lifetime of bright states, the Q‐factor determines the duration of the ballistic phase and the diffusion coefficient in the diffusive regime. Thus, polariton propagation in organic microcavities can be effectively tuned through the Q‐factor.
Bio‐Inspired Fractal Robust Hydrogel Catheter for Intra‐Abdominal Sepsis Management
Authors: Wang Lichun , Li Wenzhao , Li Min , Lai Puxiang , Yang Chunhua , Wang Hui , Ma Bo , Huang Rongkang , Zu Yan 
Published: October 2023

AbstractTo deal with intra‐abdominal sepsis, one of the major global causes of death in hospitalized patients, efficient abscess drainage is crucial. Despite decades of advances, traditional catheters have demonstrated poor drainage and absorption properties due to their simple tubular structures and their dense nonporous surface. Herein, inspired by porous sponges and fractal roots, a multifaceted hydrogel catheter with effective drainage, absorptive, and robust properties, is presented. Its unique fractal structures provide extensive internal branching and a high specific surface area for effective drainage, while the hierarchical porous structures provide a wide range of absorption capabilities. Additionally, its distinctive multi‐interpenetration network maintains robust and appropriate mechanical properties, even after absorption multiple times of liquid and mechanical disturbance, allowing for intact removal from the abdominal cavity without harm to the animal in vivo. Besides, the loaded antimicrobial peptides are capable of being released in situ to inhibit the potential for infections. In vivo experiments have demonstrated that this hydrogel catheter efficiently removes lethal abscesses and improves survival. It is believed that this innovative and practical catheter will create a future precedent for hydrogel drainage devices for more effective management of intra‐abdominal sepsis.
Micromotor‐Enabled Active Hydrogen and Tobramycin Delivery for Synergistic Sepsis Therapy
Authors: Song Yanzhen , Zhang Ruotian , Qin Hanfeng , Xu Wenxin , Sun Jia , Jiang Jiamiao , Ye Yicheng , Gao Junbin , Li Huaan , Huang Weichang , Liu Kun , Hu Yunrui , Peng Fei , Tu Yingfeng 
Published: October 2023

AbstractSepsis is a highly heterogeneous syndrome normally characterized by bacterial infection and dysregulated systemic inflammatory response that leads to multiple organ failure and death. Single anti‐inflammation or anti‐infection treatment exhibits limited survival benefit for severe cases. Here a biodegradable tobramycin‐loaded magnesium micromotor (Mg‐Tob motor) is successfully developed as a potential hydrogen generator and active antibiotic deliverer for synergistic therapy of sepsis. The peritoneal fluid of septic mouse provides an applicable space for Mg‐water reaction. Hydrogen generated sustainably and controllably from the motor interface propels the motion to achieve active drug delivery along with attenuating hyperinflammation. The developed Mg‐Tob motor demonstrates efficient protection from anti‐inflammatory and antibacterial activity both in vitro and in vivo. Importantly, it prevents multiple organ failure and significantly improves the survival rate up to 87.5% in a high‐grade sepsis model with no survival, whereas only about half of mice survive with the individual therapies. This micromotor displays the superior therapeutic effect of synergistic hydrogen‐chemical therapy against sepsis, thus holding great promise to be an innovative and translational drug delivery system to treat sepsis or other inflammation‐related diseases in the near future.
Cell Surface Engineering Tools for Programming Living Assemblies
Authors: Almeida‐Pinto José , Lagarto Matilde R. , Lavrador Pedro , Mano João F. , Gaspar Vítor M. 
Published: October 2023

AbstractBreakthroughs in precision cell surface engineering tools are supporting the rapid development of programmable living assemblies with valuable features for tackling complex biological problems. Herein, the authors overview the most recent technological advances in chemically‐ and biologically‐driven toolboxes for engineering mammalian cell surfaces and triggering their assembly into living architectures. A particular focus is given to surface engineering technologies for enabling biomimetic cell–cell social interactions and multicellular cell‐sorting events. Further advancements in cell surface modification technologies may expand the currently available bioengineering toolset and unlock a new generation of personalized cell therapeutics with clinically relevant biofunctionalities. The combination of state‐of‐the‐art cell surface modifications with advanced biofabrication technologies is envisioned to contribute toward generating living materials with increasing tissue/organ‐mimetic bioactivities and therapeutic potential.
A Roadmap for Solid‐State Batteries
Authors: Schmaltz Thomas , Hartmann Felix , Wicke Tim , Weymann Lukas , Neef Christoph , Janek Jürgen 
Published: October 2023

AbstractSolid‐state batteries are considered as a reasonable further development of lithium‐ion batteries with liquid electrolytes. While expectations are high, there are still open questions concerning the choice of materials, and the resulting concepts for components and full cells. On the basis of an analysis of all materials and concept options, a roadmap for solid‐state batteries is presented, relying on both literature survey and experts' opinions. Diverse cell concepts with different solid electrolytes may be developed up to the commercial level, yet there are still major uncertainties concerning production routes, safety as well as cost. As one of the key developments, it appears that hybrid material and cell concepts may be particularly successful on the way to commercialization.
Soil profile health in the Palouse soil series: Carbon, nitrogen, nutrients, and aggregates
Authors: Naasko Katherine , Pan William , Reganold John , Huggins David , Madsen Isaac , Sullivan Tarah , Wills Skye , Tao Haiying 
Published: October 2023

AbstractDeep soil health (>30 cm) supports deep roots in dryland wheat cropping systems. However, few studies examine how tillage and climate impact soil health indicators deeper than 30 cm in dryland wheat systems. We evaluated how select soil chemical (i.e., nutrients and pH), biological (i.e., carbon [C] and nitrogen [N] fractions and ratios), and physical (i.e., mean weight diameter [MWD] of soil aggregates) health indicators were impacted by depth, tillage, and climate. We sampled soil profiles of the Palouse soil series from 0‐ to 85 cm in depth at three no‐till (NT) and three conventional till (CT) sites across a mean annual precipitation (MAP) gradient (460–660 mm) in the Palouse River watershed. NT sites, compared to CT sites, had higher total C (TC) and N (TN), permanganate oxidizable C, hot‐water extractable C and N, and cold‐water extractable N (0–5 cm); greater soil moisture (0–29 cm); larger MWD (0–5 cm; 10–85 cm); but lower soil pH (0–10 cm; 59–85 cm); less TC, TN, and NO3−(29–85 cm); less NH4+and mineralizable soil C (MINC) (29–59 cm); and lower autoclaved‐citrate extractable (ACE) protein (0–5 cm; 29–85 cm). Sites with higher MAP had greater soil moisture (0–29 cm), higher MINC (0–85 cm), lower CWC (5–10 cm; 29–59 cm), and lower TC and ACE protein (29–85 cm). The variable effects of tillage and climate on these soil health indicators with soil depth show the importance of evaluating soil health in both surface and subsurface soil depths in dryland wheat cropping systems.
Soybean yield and profitability are affected by the spatial distribution of seeds in rows and seeding rate
Authors: Coelho Antonio Eduardo , Sangoi Luis , Sapucay Moryb Jorge Lima da Costa , Bratti Felipe , Balbinot Junior Alvadi Antonio 
Published: October 2023

AbstractSoybean [Glycine max (L.) Merr.] yield and profitability can be affected by plant‐to‐plant spatial uniformity and sowing rate. This study aimed to evaluate the agronomic and economic performance of soybean in relation to the spatial distribution of seeds in rows and seeding rates. A field experiment was conducted during the 2018–2019 and 2019–2020 growing seasons in Londrina, Paraná state, Brazil. We evaluated three coefficients of variation of seed distribution in rows (coefficient of variation of seeds distribution (VDS): 0%, 50%, and 100%) and four seeding rates (350,000, 262,500, 175,000, and 87,500 seeds ha−1), which corresponded to 100%, 75%, 50%, and 25% of the recommended seeding rate of the cultivar BRS 1003 IPRO, respectively. Sowing was performed manually to ensure that seed distribution accurately adhered to the experimental setup. Soybean yield components, yield, and profitability were then evaluated. The lower VDS improved the yield by 374 kg ha−1 compared to the higher VDS and increased the profitability by $334.7 ha−1 in 2019–2020. A seeding rate of 262,500 seeds ha−1 yielded the highest grain yield. The highest soybean profitability was achieved at a seeding rate 6.5% lower than that which produced the highest yield. Branching is essential in compensating for lower seeding rates and plants with uneven spatial distributions. The present study shows that equidistant distribution of seeds in rows optimizes grain yield.
Aggregation‐induced suppression of quantum tunneling by manipulating intermolecular arrangements of magnetic dipoles
Authors: Deng Wei , Du Shan‐Nan , Ruan Ze‐Yu , Zhao Xiao‐Jun , Chen Yan‐Cong , Liu Jun‐Liang , Tong Ming‐Liang 
Published: October 2023

AbstractThe relaxation time under zero field reflects the memory retention capabilities of single‐molecule magnets (SMMs) when used as storage devices. Intermolecular magnetic dipole interaction is ubiquitous in aggregates of magnetic molecules and can greatly influence relaxation times. However, such interaction is often considered harmful and challenging to manipulate in molecular solids, especially for high‐performance lanthanide single‐ion magnets (SIMs). By an elaborately designed combination of ion pairing and hydrogen bonding, we have synthesized two pseudo‐D5h SIMs with supramolecular arrangements of magnetic dipoles in staggered and side‐by‐side patterns, the latter of which exhibits a 104‐fold slower zero‐field relaxation time at 2 K. Intriguingly, the side‐by‐side complex exhibits a significantly accelerated magnetic relaxation upon diamagnetic dilution, contrary to the general trend observed in the staggered complex. This strongly reveals the presence of aggregation‐induced suppression of quantum tunneling in a side‐by‐side arrangement, which has not been observed in mononuclear SMMs. By leveraging ion‐pairing aggregation and converting to a side‐by‐side pattern, this study successfully demonstrates an approach to transform a harmful intermolecular dipole interaction into a beneficial one, achieving a τQTM of 980 s ranking among the best‐performance SMMs.
Replicated radiations in the South American marsh pitcher plants (Heliamphora) lead to convergent carnivorous trap morphologies
Authors: Liu Sukuan , Smith Stacey D. 
Published: October 2023

AbstractPremiseThe evolution of carnivorous pitcher traps across multiple angiosperm lineages represents a classic example of morphological convergence. Nevertheless, no comparative study to‐date has examined pitcher evolution from a quantitative morphometric perspective.MethodsIn the present study, we used comparative morphometric approaches to quantify the shape space occupied byHeliamphorapitchers and to trace evolutionary trajectories through this space to examine patterns of divergence and convergence within the genus. We also investigated pitcher development, and, how the packing of pitchers is affected by crowding, a common condition in their natural environments.ResultsOur results showed thatHeliamphorapitchers have diverged along three main axes in morphospace: (1) pitcher curvature; (2) nectar spoon elaboration; and (3) pitcher stoutness. Both curvature and stoutness are correlated with pitcher size, suggesting structural constraints in pitcher morphological evolution. Among the four traits (curvature, spoon elaboration, stoutness, and size), all but curvature lacked phylogenetic signal and showed marked convergence across the phylogeny. We also observed tighter packing of pitchers in crowded conditions, and this effect was most pronounced in curved, slender pitchers.ConclusionsOverall, our study demonstrates that diversification and convergent evolution of carnivory‐related traits extends to finer evolutionary timescales, reinforcing the notion that ecological specialization may not necessarily be an evolutionary dead end.
Indication of mixed glucose and fatty acid use by inferred brown adipose tissue activity in Samoans
Authors: Niclou Alexandra , Vesi Lupesina , Arorae Maria , Naseri New Caledonia , Savusa Kima Faasalele , Naseri Take , Young Jessica , Rivara Anna C. , Ocobock Cara 
Published: October 2023

AbstractObjectivesDespite the growing rates of global obesity and the known positive associations between brown adipose tissue (BAT) and cardiovascular health, little is known about the metabolic effects of BAT activity in Samoans, a population at high risk of obesity and type II diabetes. Here we assessed the potential effects of inferred BAT activity on metabolic health markers in Samoan adults exposed to mild cold.MethodsUsing point‐of‐care finger prick technology we measured fasting glucose, total cholesterol, high‐density lipoprotein (HDL), and low‐density lipoprotein (LDL) levels before and after 30 min of cold exposure among 61 individuals (38 females, 23 males, ages 31–54) from ‘Upolu Island, Samoa. Respiratory quotient was measured by indirect calorimetry to determine substrate metabolism at room temperature and cold exposure.ResultsFasting glucose levels decreased significantly (p < .001) after cold exposure while neither total cholesterol (p = .88), HDL (p = .312), nor LDL (p = .089) changed. Respiratory quotient decreased significantly (p = .009) between exposures, suggesting an increased preference for lipid metabolism as a response to cold.ConclusionsThe observed effects of inferred BAT activity on biomarkers suggest BAT activity utilizes both glucose and lipid‐derived fatty acids as fuel for thermogenesis. Our work provides evidence for the beneficial metabolic effects of BAT and emphasizes the need for the population‐specific development of metabolic treatments involving BAT to ensure the successful and equitable minimization of extreme consequences of obesity and metabolic health.
Association among 25‐hydroxyvitamin D levels, hypertriglyceridemic‐waist phenotype, and cardiometabolic markers in individuals with type 2 diabetes mellitus from regions with high solar incidence
Authors: Oliveira Juliana de Souza , Santos Beatriz da Cruz , Santos Ramara Kadija Fonseca , Santos Cynthia Batista , Reis Aline Rocha , Santos Cinthia Fontes da Silva , de Carvalho Gabrielli Barbosa , Brandão‐Lima Paula Nascimento , Rocha Vivianne de Sousa , Pires Liliane Viana 
Published: October 2023

AbstractObjectiveTo evaluate the relationship between vitamin D status and hypertriglyceridemic‐waist (HTW) phenotype and cardiometabolic markers in individuals with type 2 diabetes mellitus (T2DM) living in regions with high solar incidence (10° south).MethodsAn observational, cross‐sectional study, with 122 individuals with T2DM, of both sexes, aged between 19 and 59 years, residing in Sergipe/Brazil. Measurements included serum 25‐hydroxyvitamin D (25[OH]D), glucose, insulin, total cholesterol, LDL‐c, HDL‐c, triacylglycerols, blood pressure, body mass index, %body fat, and waist circumference. Participants were classified by the presence or absence of the HTW phenotype, according to increased waist circumference and triacylglycerols concentrations. Logistic and linear regression models were applied to verify the association among the concentration of 25(OH)D, HTW phenotype, and lipid profile variables.ResultsTriacylglycerols concentrations (p = .013) and %body fat (p = .011) were higher in women with serum 25(OH)D insufficient/deficient than in those with adequate 25(OH)D levels. Individuals with serum 25(OH)D insufficiency/deficiency were 2.595 times more likely to present the HTW phenotype than those with adequate 25(OH)D levels (p = .021). Additionally, a negative association was observed between the concentration of 25(OH)D and total cholesterol (Beta = −0.204, p = .049).ConclusionInsufficiency/deficiency of serum 25(OH)D in individuals with T2DM increases the chances of developing the HTW phenotype.
Growth reference charts for children with hypochondroplasia
Authors: Cheung Moira S. , Cole Tim J. , Arundel Paul , Bridges Nicola , Burren Christine P. , Cole Trevor , Davies Justin Huw , Hagenäs Lars , Högler Wolfgang , Hulse Anthony , Mason Avril , McDonnell Ciara , Merker Andrea , Mohnike Klaus , Sabir Ataf , Skae Mars , Rothenbuhler Anya , Warner Justin , Irving Melita 
Published: October 2023

AbstractHypochondroplasia (HCH) is a rare skeletal dysplasia causing mild short stature. There is a paucity of growth reference charts for this population. Anthropometric data were collected to generate height, weight, and head circumference (HC) growth reference charts for children with a diagnosis of HCH. Mixed longitudinal anthropometric data and genetic analysis results were collected from 14 European specialized skeletal dysplasia centers. Growth charts were generated using Generalized Additive Models for Location, Scale, and Shape. Measurements for height (983), weight (896), and HC (389) were collected from 188 (79 female) children with a diagnosis of HCH aged 0–18 years. Of the 84 children who underwent genetic testing, a pathogenic variant in FGFR3 was identified in 92% (77). The data were used to generate growth references for height, weight, and HC, plotted as charts with seven centiles from 2nd to 98th, for ages 0–4 and 0–16 years. HCH‐specific growth charts are important in the clinical care of these children. They help to identify if other comorbidities are present that affect growth and development and serve as an important benchmark for any prospective interventional research studies and trials.
The impact of COVID‐19 on the well‐being of Australian visual artists and arts workers
Authors: Lye Jenny , Hirschberg Joe , McQuilten Grace , Powell Chloë , MacNeill Kate , Badham Marnie 
Published: October 2023

AbstractIn this paper, we assess the impact of the COVID‐19 pandemic on the Australian visual arts sector. We base our analysis on the responses of over 1500 visual artists and arts workers to a survey conducted by the National Association for the Visual Arts (NAVA), the national peak body for the visual and media arts, craft and design sector in September 2021. NAVA employed this online survey to study the relationship between the pandemic and both the incomes and mental health of artists and arts workers. Using regression analysis, we find that there has been a significant impact for both artists and arts workers, with the severity of the impacts varying by gender, age and the availability of state‐based and Australian Government support programmes. Reduced hours and loss of contracted work and commissions due to the pandemic were both related to declines in income and mental health outcomes for artists and for arts workers. Housing stress was associated with a higher likelihood of a significant or extreme mental health impact for artists and arts workers. In addition, artists' incomes and mental health outcomes were impacted when faced with a reduced ability to sell, although some artists were able to increase their online profiles.
Rapid rewarming rate associated with favorable neurological outcomes in patients with post–cardiac arrest syndrome patients treated with targeted temperature management
Authors: Shin Masaru , Fujita Motoki , Hifumi Toru , Koga Yasutaka , Yagi Takeshi , Nakahara Takashi , Todani Masaki , Kaneda Kotaro , Tsuruta Ryosuke 
Published: October 2023

AbstractAimTo determine whether the rewarming rate is associated with neurological outcomes in patients with post–cardiac arrest syndrome treated with targeted temperature management (TTM) at 34°C.MethodsWe conducted a retrospective analysis of a nationwide cohort study of out‐of‐hospital cardiac arrest in Japan. Adult patients who experienced a return of spontaneous circulation and completed TTM at 34°C between June 2014 and December 2019 were divided equally into three groups (slow, moderate, and rapid) according to their rewarming rates from 34°C to 36°C. The rates of favorable neurological outcomes (Cerebral Performance Category of 1–2 after 30 days) were compared among the groups, and the adjusted odds ratios for a favorable neurological outcome were calculated for the groups.ResultsWe analyzed 348, 357, and 358 patients in the slow, moderate, and rapid groups, respectively. The periods of rewarming from 34°C to 36°C were 41.9 ± 10.5, 22.4 ± 1.8, and 12.2 ± 3.6 h, respectively. The number of favorable neurological outcomes after 30 days was 121 (34.8%), 125 (35.0%), and 147 (41.1%), respectively, with no significant differences among the three groups (p = 0.145). Rapid rewarming was independently associated with a favorable neurological outcome compared with slow rewarming (adjusted odds ratio 1.57 [95% confidence interval 1.04–2.37]; p = 0.031).ConclusionsRapid rewarming after TTM at 34°C was associated with a more favorable neurological outcome than slow rewarming.