bluuebunny/crossref_metadata_2025_split huggingface dataset:
Pelatihan Aplikasi Komputer Teknik Bangunan Bagi Mahasiswa Tingkat Akhir
Authors: Hasrul M Reza , Asnur Moeh. Kay Muddin , Yusuf Furqan Ali 
Published: November 2023

Perkembangan teknologi informasi yang semakin pesat di era globalisasi saat ini tidak bisa dihindari lagi pengaruhnya terhadap dunia pendidikan. Tuntutan global menuntut dunia pendidikan untuk selalu dan senantiasa menyesuaikan perkembangan teknologi terhadap usaha dalam peningkatan mutu pendidikan, terutama penyesuaian penggunaan teknologi informasi dan komunikasi bagi dunia Pendidikan dalam penelitian ini penggunaan Software Plaxis dalam bidang ilmu Geoteknik untuk mengatasi Untuk mengatasi permasalahan geoteknik, salah satunya dapat dilakukan dengan bantuan metode perhitungan elektronik atau komputasi yaitu berupa program aplikasi komputer Software Plaxis, Masalahnya adalah kurangnya pengetahuan tentang penggunaan Software Plaxis. Sasaran eksternal adalah pemahaman mahasiswa tentang Software Plaxis dan penerapan pada mahasiswa tingkat akhir. Metode yang digunakan adalah: ceramah, diskusi,pelatihan dan tanya jawab. Hasil yang dicapai meningkatkan pengetahuan tentang Software Plaxis mahasiswa dan untuk mengatasi permasalahan geoteknik. Peserta pelatihan merupakan mahasiswa tingkat akhir
Implementasi Program Layanan Aspirasi dan Pengaduan Masyarakat (SIDUMAS) Dalam Pengaduan Masyarakat di Dinas Komunikasi dan Informatika Kabupaten Badung
Authors: Widyaningtyas Arista , Prabawati Ni Putu Anik , Wismayanti Kadek Wiwin Dwi 
Published: November 2023

The aim of this research is to find out how the Community Aspiration and Complaints Service (SIDUMAS) program is implemented in public complaints at the Badung Regency Communication and Information Service. This research uses a qualitative research method with a descriptive approach that collects data through observation, interviews and documentation. This research uses public policy theory with indicators of program implementation by Charles O. Jones with three (3) types of indicators, namely, organization, interpretation or understanding, and application or application. For the three indicators of program implementation, the results showed that all of these indicators were running, but there were several indicators that were not running optimally, namely organizational indicators and application or implementation.

Abstrak
Tujuan penelitian ini untuk mengetahui bagaimana implementasi program Layanan Aspirasi dan Pengaduan Masyarakat (SIDUMAS) dalam pengaduan masyarakat di Dinas Komunikasi dan Informatika Kabupaten Badung. Penelitian ini menggunakan metode penelitian kualitatif dengan pendekatan deskriptif yang mengumpulkan data melalui observasi, wawancara serta dokumentasi. Penelitian ini menggunakan teori kebijakan publik dengan indikator implementasi program oleh Charles O. Jones dengan tiga (3) jenis indikator yaitu, organisasi, interpretasi atau pemahaman, serta aplikasi atau penerapan. Dengan menggunakan ketiga indikator implementasi program tersebut, didapatkan hasil yang menjelaskan bahwa seluruh indikator tersebut telah berjalan, namun terdapat beberapa indikator yang belum berjalan secara optimal yaitu indicator organisasi dan aplikasi atau penerapan.
Kata Kunci: Implementasi Program, Layanan Aspirasi dan Pengaduan Masyarakat (SIDUMAS), Dinas Komunikasi dan Informatika.
Evaluation of a Method to Estimate Foot Eversion Moments During the Support Phase of Running
Authors: Tsujimoto Norio 
Published: November 2023

Background: Excessive external eversion moments acting on the ankle derived from the ground reaction force (GRF) during the support phase of running are considered a risk factor for overuse lower-limb injuries. The external eversion moment is considered to be dominated by the moment derived from the vertical GRF. However, no studies have directly evaluated the accuracy with which external eversion moment can be estimated with this information. Thus, the objective of this study was to evaluate the extent to which external eversion moment can be estimated from external eversion moment derived from vertical GRF.
Methods: From three-dimensional foot coordinates and GRF data of 28 healthy participants, we computed external eversion moment (EMrun), center of the ankle coordinates (ANKrun), center of pressure coordinates (COPrun), and vertical GRF (VGRFrun) during the support phase of running. Moreover, we computed center of the ankle joint coordinates (ANKstand) and vertical GRF (VGRFstand) in the resting standing position.
Results: A highly significant correlation was observed between EMrun and external eversion moment derived from vertical GRF ([COPrun – ANKrun] × VGRFrun), with a contribution of 84.7%. Moreover, a highly significant correlation was observed between EMrun and (COPrun – ANKstand) × VGRFstand, with a contribution of 81.5%.
Conclusions: These results indicate that external eversion moment can be estimated from the external eversion moment derived from vertical GRF with high accuracy. Moreover, it was found that the accuracy did not decrease even if the data of center of ankle and vertical GRF were replaced with the data during standing.
Comparison of Supination-Adduction Type 2 and Supination–External Rotation Type 4 in Bimalleolar Ankle Fractures: Does Partial Pylon Variant of Supination-Adduction Type Fracture Affect Functional Outcomes?
Authors: Yüce Ali , Bayraktar Tahsin Olgun , Yerli Mustafa , Karslıoğlu Bülent , Dedeoğlu Süleyman Semih , İmren Yunus , Kır Mustafa Çağlar , Gürbüz Hakan 
Published: November 2023

Background: Supination-adduction (SAD) type injuries are pylon variant injuries and lie between partial intra-articular pylon fractures and rotational ankle fractures. We aimed to evaluate functional outcomes of SAD type 2 bimalleolar fractures in comparison to supination–external rotation (SER) type 4 fractures.
Methods: We retrospectively reviewed data of 42 cases with SER type 4 and 20 cases with SAD type 2 injuries. Patients with a history of rheumatic disease, open fractures, pathologic fractures, nonbimalleolar fractures, neuropathic disease, and talus osteochondral lesion, and those operated on after greater than 72 hours because of skin lesion or managed with a two-stage surgical protocol after external fixation, were not included in the study. We compared these two groups in terms of the mean age, follow-up time, visual analog scale pain and American Orthopedic Foot and Ankle Society scores, Kellgren-Lawrence arthrosis classification, union time, and complications.
Results: The groups did not differ in terms of mean age (P = .115) and sex (P = .573). There was no significant difference in terms of union time between the groups (P = .686). American Orthopedic Foot and Ankle Society score was significantly higher in the SER group (91.2 ± 9.9) than in the SAD group (86.1 ± 13.2; P = .034). Visual analog scale pain scores were similar in the SAD (0.3 ± 0.92) and the SER (0.26 ± 0.7) groups (P = .897).
Conclusions: Supination-adduction bimalleolar fractures may have worse functional outcomes in the intermediate term than do SER bimalleolar fractures, implying pylon variant fractures as a mechanism of injury. Supination-adduction bimalleolar fractures might be associated with a high rate of intra-articular cartilage impaction, resulting in varus deformity after surgery.
Distal Tibiofibular Malreduction in Ankle Fractures Received Fibula Plate and Syndesmotic Screw Fixation
Authors: Yüce Ali , Yerli Mustafa , Imren Yunus , Dedeoglu Suleyman Semih , Cabuk Haluk , Gurbuz Hakan 
Published: November 2023

Background: The aim of the study was to examine the effect of the position of the plate and syndesmotic screw on postoperative tibiofibular joint malreductions in cases where the syndesmotic screw is inserted through the hole of the anatomically locked lateral distal fibula plate.
Methods: Thirty patients (13 female and 17 male patients) with postoperative computed tomographic scans were examined retrospectively. Patient information (eg, tibiofibular congruence measured from postoperative computed tomographic scans, the anterior and posterior tibiofibular distance at axial sections, the presence and orientation of fibular rotation, the presence of tibiofibular intraarticular piece, the angle between the syndesmotic screw and incisural line, the placement of the plate, and the localization of the screw on the fibula in axial images) was recorded.
Results: Those with fibular internal rotation had a lower syndesmotic screw–incisural line angle (SIA) (P = .001).There was a very strong negative significant correlation between the tibiofibular angle and SIA (rho, −0.780; P = .001). The median tibiofibular angle was found to be higher in cases with the fibula plate placed anteriorly (P = .009).The median SIA was found to be lower in cases with the fibula plate placed anteriorly (P = .004).The rate of placement of syndesmotic screw in the anterior third of the fibula was found to be high in cases with the fibula plate placed anteriorly (P = .049).
Conclusions: In ankle fractures treated with insertion of a syndesmotic screw through the plate, the orientation of the syndesmotic screw in the axial plane and the position of the plate may be associated with the incidence of postoperative syndesmosis malreduction.
Response of Foliar Feeding of NAA, Urea, Nano-urea and Biofertisol on Fruit Quality of Mango (Mangifera indica L.) cv. Langra
Authors: Kumar Raushan , Sharma Rajnee , Sharma T. R. , Pandey C. S. , Singh Deepak , Thakur Shikha , Singh Surya Pratap 
Published: November 2023

A study was conducted during the season of 2022-23 at the fruit research station in Imalia, which is affiliated with the Department of Horticulture at the JNKVV in Jabalpur. The objective of the study was to evaluate the positive effect of foliar sprays containing NAA, Urea, Nano-urea, and Biofertisol on the fruit quality of mango (Mangifera indica L.) cv. Langra. The experiment was laid out in Randomized Block design in three replications and all the treatments were replicated thrice by using the single tree as a unit. Each treatment was carried out with one tree for each replication. At the full bloom and pea stage, the spraying of three different concentrations of NAA (20 ppm, 30 ppm, and 40 ppm), Urea (2%, 3%, and 4%), Nano-urea (0.2%, 0.3%, and 0.4%) and Biofertisol (5 ml/l, 10 ml/l, and 15 ml/l) was compared with the control, which consisted of no spraying. According to the findings of the experiment, applying a foliar spray containing 40 ppm of NAA resulted in a significant improvement in the quality parameter, as measured by a maximum TSS value of 22.22 oBrix, a maximum TSS: acid ratio of 117.13, maximum ascorbic acid content of 26.70 mg/100g, a minimum acidity content of 0.19%, and reducing sugars of 6.74% and total sugars of 17. During the evaluation, it performed at the same level as T3 (NAA 30 ppm), T2 (NAA 20 ppm), and T7 (Urea 4%).
Scalable Terahertz Room Temperature Photoreceivers Based on Large‐Area Hexagonal Boron Nitride and Graphene Heterostructures
Authors: Viti Leonardo , Balci Osman , Zhang Jincan , Meersha Adil , Ferrari Andrea C. , Vitiello Miriam S. 
Published: January 2025

AbstractThe development of scalable techniques for large‐area growth of layered materials unlocks technological opportunities for the implementation of devices and components suitable for on‐chip integration on photonic integrated platforms. Here, terahertz (THz) photoreceivers based on large‐area hexagonal boron nitride/single‐layer graphene (SLG)/hexagonal boron nitride heterostructures, prepared by chemical vapor deposition and realized by means of an industrially scalable method, are reported. The photo‐thermoelectric sensors are integrated on‐chip with planar antennas, on‐chip radio frequency circuitry, a low‐pass hammer‐head filter and coplanar strip lines, combining nanosecond response time and large sensitivity. Room temperature responsivities of ≈4 V W−1, with noise equivalent power ≈4 nWHz−1/2 at high (2.86 THz) frequencies are reached, in a fully frequency‐scalable architecture. This paves the way for multiplexed hyperspectral THz cameras and optical communication systems.
From Hard Crystal to Soft Fiber: Thermochromic Color‐Tunable and “On‐Off”‐Switchable Afterglow of Single‐Component Ultralong RTP Organogel
Authors: Lin Huamiao , Shi Yi , Geng Peng , Chen Shuzhan , Luo Dan , Xiao Shuzhang 
Published: January 2025

AbstractPure organic stimuli‐responsive phosphorescent materials with multi‐color afterglows, good reversibility, and ease manipulation are highly appealing for dynamic anti‐counterfeiting applications, but remain challenging to achieve. In this work, a phosphorescent soft organogel is rationally designed by introducing functional carbonyl (benzoyl or acetyl) units into dibenzofuran skeleton to promote the intersystem crossing (ISC), and screening potential organogelators through predicting the self‐assembly process with the aid of all‐atom molecular dynamic simulation (AMDS). AMDS indicates that the designed gelator candidates (DBF‐Me and DBF‐Ph) can self‐assemble in the mixture of DMSO/H2O through balanced π‐π intermolecular interactions between neighboring molecules, thus promoting the gelation. Notably, the DBF‐Ph fiber gel exhibits a yellow afterglow at room temperature (298 K) with a lifetime of 235.1 ms, which can be switched off at 358 K but restored after cooling to room temperature. Furthermore, the yellow afterglow (298 K) can turn to green at 208 K and blue at 77 K, due to the slight change of conformation and molecular packing as revealed by analysis of temperature‐dependent single crystal structures. This single‐component DBF‐Ph fiber gel, capable of achieving color‐tunable and “on‐off”‐switchable afterglow through a single temperature response, offers significant potential in developing soft ultralong RTP materials for multi‐level anti‐counterfeiting features.
A Liquid Crystal Polymer With Thermally‐Induced Deformation and Reversible Fluorescence Switching
Authors: Zhao Xin , Yang Ziyue , Zhang Xiaoyu , Liu Xiaojun , Pu Yu , Qin Lang , Wei Jia , Yu Yanlei 
Published: January 2025

AbstractStimuli‐responsive liquid crystal polymers (LCPs) hold significant promises as materials for designing multifunctional soft actuators. Recently, this group explored a novel strategy to develop a multi‐responsive LCP by combining ring‐opening metathesis polymerization (ROMP) with post‐polymerization modification (PPM). The current study aims to advance the approach to design an LCP capable of thermally‐induced deformation and fluorescence switching. ROMP is first employed to synthesize a reactive linear LCP precursor containing aggregation‐induced emission luminogens (AIEgens) with excellent processability, enabling the preparation of arbitrary shapes through various processing techniques. Subsequently, PPM is responsible for anchoring the mesogen alignment of the as‐prepared film and fiber geometries. The obtained cross‐linked LCP films and fibers undergo contraction, bending, unfolding and rolling with increasing temperature. Furthermore, the disruption of mesogen at high temperature weakens the restriction of AIEgen motions, facilitating the switching of the fluorescence property of LCPs. This material design combines the diverse fabrication opportunities, advanced actuation capabilities, and the tunable emission properties of AIEgens, while also enabling the visualization of the actuator's state.
Synthesis and Structures of 9,9’‐Bianthryl‐Based Cyclic Dimer and Dinaphtho[c,g]Carbazole via Oxidative Coupling
Authors: Shimizu Atsuki , Toyota Shinji , Iwanaga Tetsuo 
Published: January 2025

Abstract9,9′‐Bianthryl‐based cyclic dimer and dinaphtho[c,g]carbazole derivatives were synthesized from a di(2‐anthracenyl)amine derivative via Scholl reactions. The selectivity of annulation sites was regulated by the choice of oxidants. By optimizing reaction conditions with 2,3‐dichloro‐5,6‐dicyano‐p‐benzoquinone (DDQ) and MeSO3H, a cyclic dimer of 9,9′‐bianthryl units featuring a chiral structure was obtained. Enantiomers of the cyclic dimer were successfully resolved by chiral high‐performance liquid chromatography (HPLC). Circular dichroism (CD) spectra of the M,M‐isomer were analyzed using theoretical calculations based on the time‐dependent density functional theory (TD‐DFT) method. The calculations reasonably reproduced the observed CD bands and determined the absolute stereochemistry. Oxidation with FeCl3 gave a dinaphtho[c,g]carbazole derivative, where the 1‐positions of the anthracene units were fused intramolecularly. DFT calculations were further employed to predict the preferential bonding sites of the two 2‐anthryl units leading to the dinaphtho[c,g]carbazole derivative.
Traumatic internal carotid artery aneurysm distant from facial bone fractures treated with a flow diverter stent: A case report
Authors: Watanabe Tatsuya , Nakao Junzo , Boku Keishun , Hirata Koji , Totoki Yasukazu , Tasaki Kuniharu , Miura Takeshi , Hoshino Tetsuya , Matsumoto Yukei , Enomoto Yuki , Marushima Aiki , Matsumaru Yuji , Inoue Yoshiaki 
Published: January 2025

AbstractBackgroundTraumatic intracranial aneurysms (TICAs) can be fatal if ruptured. We report a case of a TICA, distant from facial bone fractures, successfully treated with flow diverter (FD) before rupture.Case PresentationA 20‐year‐old woman was admitted following a car accident. Initial contrast‐enhanced computed tomography revealed traumatic subarachnoid hemorrhage, a 5‐mm internal carotid artery aneurysm, LeFort type I + II, and mandibular fracture. On Day 8, she developed oculomotor palsy, and digital subtraction angiography revealed the aneurysm had increased to 12 mm. She started dual antiplatelet therapy (DAPT) following facial fracture repair. On Day 17, FD was placed, resulting in contrast agent stagnation within the aneurysm. Three months postinjury, her neurological symptoms improved.ConclusionScreening for cerebrovascular injury is crucial several days following severe head trauma, even without skull base fractures. Unruptured TICA can be safely treated with FD following DAPT administration.
All‐in‐One Photoacid Generators with Green/Red‐light Responsiveness and Cooperative Functionality
Authors: Guo Huichao , Zhang Zhiwei , Chen Yuhao , Yang Haochen , Deng Long , Dai Jinghong , Cong Muyu , Wang Bangsen , Qu Da‐Hui , Zhu Wei‐Hong , Zhang Junji , Tian He 
Published: January 2025

AbstractPhotoacid generators (PAGs) are invaluable molecular tools that exhibited tremendous potential in emerging interdisciplinary researches of life‐science, nanotechnology and smart materials. However, current PAGs are primarily mono‐functional in terms of acid generation and rely on UV/deep‐blue light excitation, posing a fundamental hurdle to their broader adoption. Developing cooperatively functioned PAGs with long‐wavelength light responsiveness presents a formidable challenge due to the absence of suitable molecular scaffolds. Here, we introduce a newly‐developed perylene bisimides PAG motif (PBI‐PAG) that integrates desired multi‐functionality and visible‐light photo‐reactivity. Taking advantages of characteristic opto‐electronic properties of PBI scaffold, PBI‐PAGs are capable of quantitative releasing (>99 %) a palette of acids upon green/red light (560–605 nm) excitation. Concurrently, a photo‐generated counterpart is functioned as a photo‐sensitizer that could perform cooperatively with acid as an anti‐metastasis cancer therapy agent. These two processes constitute the first example of a cooperatively functioned PAG operated at substrate‐adaptive wavelengths.
Organic‐Free Synthesis of High‐Silica Zeolite Y with Aluminophosphate as the Aluminum Carrier
Authors: Zhao Qingdi , Ling Jiejie , Wang Jilong , Gao Yan , Liu Hailang , Zhang Zhenghan , Jiang Jingang , Nakayama Akira , Li Jian , Muraoka Koki , Wu Peng , Xu Le 
Published: January 2025

AbstractThe wide application of zeolite Y in petrochemical industry is well‐known as one of the milestones in zeolite chemistry and heterogeneous catalysis. However, the traditional organic‐free synthesis typically produces (hydro)thermally unstable zeolite Y with Si/Al atomic ratio (SAR) less than 2.5. Inspired by drug delivery process in which active components are kinetically controlled released, we develop a unique approach based on the pre‐synthesized aluminum carrier to prepare one of the most siliceous zeolite Y with SAR up to 3.44 without using organics. The crystalline or amorphous aluminophosphates serve as the ideal carrier for the controlled incorporation of Al into zeolite framework during zeolite Y crystallization. Experimental and theoretical results reveal that the partial introduction of aluminophosphate as Al source would rationally regulate the crystallization kinetics, facilitating the formation of high‐silica zeolite Y with random Al distribution. This approach enhances the hydrothermal stability and catalytic performance of zeolite Y in benchmark reaction.
Boosting CO2 Hydrogenation by Synergistic Incorporation of Pure Silica Silicalite‐1 Zeolite and CeO2 into Cu Catalysts
Authors: Xu Jing , Wang Ke , Zhao Meng , Zhang Rui , Cui Wenjie , Liu Li , Wang Xiao , Wang Jing , Song Shuyan , Zhang Hongjie 
Published: January 2025

AbstractChemical conversion of CO2 is providing an opportunity to mitigate the global warming induced by the overconsumption of fossil fuel. Cu has been regarded as one of the most powerful contenders in catalyzing CO2 conversion, yet the precise manipulation of its surface state and the nearby chemical environment continues to pose a formidable challenge. In this work, we report a high‐efficiency catalyst by utilizing CeO2 and pure silicon zeolite (S1) to co‐activate Cu species. In CO2‐to‐methanol (CTM) conversion, the space‐time yield of methanol (STYMeOH) of the obtained CuCe/S1 catalysts reaches 87.23 g kgCu−1 h−1, which represents a fivefold increase compared to that of the Cu/CeO2 catalysts. The following mechanistic investigations reveal that S1 serves as a pivotal stabilizer for the small‐sized CeO2 particles, thereby significantly enhancing the synergistic interaction between Cu species and CeO2. The crafted interaface possesses abundant oxygen vacancies and a high content of Cu+, significantly enhancing the adsorption of CO2 and inhibiting the formation of CO. Our discovery presents a promising new direction for catalyst upgrading and performance enhancement for CTM processes in the foreseeable future.
FDA‐approved drugs featuring macrocycles or medium‐sized rings
Authors: Du Youlong , Semghouli Anas , Wang Qian , Mei Haibo , Kiss Loránd , Baecker Daniel , Soloshonok Vadim A. , Han Jianlin 
Published: January 2025

AbstractMacrocycles or medium‐sized rings offer diverse functionality and stereochemical complexity in a well‐organized ring structure, allowing them to fulfill various biochemical functions, resulting in high affinity and selectivity for protein targets, while preserving sufficient bioavailability to reach intracellular compartments. These features have made macrocycles attractive candidates in organic synthesis and drug discovery. Since the 20th century, more than three‐score macrocyclic drugs, including radiopharmaceuticals, have been approved by the US Food and Drug Administration (FDA) for treating bacterial and viral infections, cancer, obesity, immunosuppression, inflammatory, and neurological disorders, managing cardiovascular diseases, diabetes, and more. This review presents 17 FDA‐approved macrocyclic drugs during the past 5 years, highlighting their importance and critical role in modern therapeutics, and the innovative synthetic approaches for the construction of these macrocycles.