bluuebunny/crossref_metadata_2025_split huggingface dataset:
Assessment of the plasma desorption time‐of‐flight mass spectrometry technique for pesticide adsorption and degradation on ‘as‐received’ treated soil samples
Authors: Thomas J. P. , Nsouli B. , Darwish T. , Fallavier M. , Khoury R. , Wehbé N. 
Published: July 2005

AbstractThe assessment of the plasma desorption time‐of‐flight mass spectrometry (PD‐TOFMS) technique as a tool for direct characterization of pesticides adsorbed on agricultural soil is made for the first time in this study. Pellets of soils impregnated by solutions of three pesticides, namely norflurazon, malathion and oxyfluorfen, as well as deposits of these solutions onto aluminum surfaces, were investigated to this end. The yield values of the most characteristic peaks of the negative ion mass spectra were used to determine both the lowest concentrations detected on soils and limits of detection from thin films. The lowest values on soils are for malathion (1000 ppm range), and the largest for norflurazon (20 000 ppm), which is close to the limit of detection (LOD) found for the pesticide on the aluminum substrate (∼0.2 µg · cm−2). Different behaviors were observed as a function of time of storage in the ambient atmosphere or under vacuum; norflurazon adsorbed on soil exhibited high stability for a long period of time, and a rapid degradation of malathion with the elapsed time was clearly observed. The behavior of oxyfluorfen was also investigated but segregation processes seem to occur after several days. Although by far less sensitive than conventional methods based on extraction processes and used for real‐world analytical applications, this technique is well suited to the study of the transformations occurring at the sample surface. A discussion is presented of the future prospects of such experiments in degradation studies. Copyright © 2005 John Wiley & Sons, Ltd.
The ability of ‘family friendly’ organizational resources to predict work–family conflict and job and family satisfaction
Authors: Brough Paula , O'Driscoll Michael P. , Kalliath Thomas J. 
Published: July 2005

AbstractThe effectiveness of organizational interventions in reducing the adverse consequences of work–family conflict has produced mixed findings. This paper examines the relationship between the use of organizational ‘family friendly’ resources (such as crèche facilities, flexible working hours, and job sharing), with levels of work–family conflict, and job and family satisfaction over time. Using structural equation modelling, these associations were tested in 398 employed men and women who each completed a self‐report questionnaire administered on two occasions. The use of organizational interventions directly predicted increased levels of concurrent (Time 1) work–family interference and increased levels of subsequent (Time 2) job satisfaction. Both organizational interventions and family interventions (i.e. support) positively predicted subsequent family satisfaction. The research demonstrates that the provision of organizational ‘family‐friendly’ practices will produce improved psychological outcomes for employees. Copyright © 2005 John Wiley & Sons, Ltd.
Synthesis and Characterization of a Two‐Dimensional Zinc Phosphite, Zn3(tren)(HPO3)3·xH2O (x ≈ 0.5; tren = tris(2‐aminoethyl)amine)
Authors: Zhong You‐Ju , Chen Yong‐Mei , Sun Yan‐Qiong , Yang Guo‐Yu 
Published: July 2005

AbstractA new zinc phosphite with the formula Zn3(tren)(HPO3)3·xH2O (x≈0.5) has been synthesized under hydrothermal conditions and characterized by FTIR, elemental analysis, powder X‐ray diffraction, single‐crystal X‐ray diffraction, thermogravimetric analysis and its fluorescent spectrum. The compound crystallizes in the triclinic system, space group ${\rm P}{\bar 1}$ (No.2), a = 10.1188(9) Å, b = 10.4194(9) Å, c = 10.5176(9) Å, α = 60.763(2)°, β = 70.6150(10)°, γ = 80.725(2)°, V = 912.77(14) Å3, Z = 2. The structure consists of double crankshaft chains, which are linked by Zn‐O‐P bonds to form 8‐ and 12‐membered channels along the [100] direction. The claw‐like Zn‐centered complexes of Zn(N4C6H18) as the supported templates, hang into the 12‐MR channels through Zn‐O‐P linkages with framework.
Structural Aspect of CuCN Catalytic Cyclodimerization of N‐Allylquinolinium Halides
Authors: Pavlyuk Oleksii , Lis Tadeusz , Mys'kiv Marian G. 
Published: July 2005

AbstractBy a reaction between the corresponding [N‐allylquinolinium]X (X = Cl, Br, I) and CuCN in a methanolic medium crystals of [C24H21N2][CuCl1.35Br0.65] (1), [C24H21N2][CuBr2] (2) and [C24H21N2]I (3) have been obtained and characterized structurally by X‐ray (at 100 K). Isostructural complexes 1 and 2 crystallize in monoclinic space group P21/n, Z = 4: 1 a = 13.193(4), b = 19.185(5), c = 8.429(3), β = 104.85(3)°, V = 2062(1) Å3, R = 0.051 for 3359 reflections; 2 a = 13.373(4), b = 19.104(6), c = 8.544(3) Å, β = 104.58(3)°, V = 2112(1) Å3, R = 0.057 for 3297 reflections. Compound 3 crystallizes in monoclinic system, space group P21/n, Z = 4, a = 8.889(2), b = 16.842(3), c = 13.294(3) Å, β = 104.71(3)° V = 1925(1) Å3, R = 0.034 for 4042 reflections. The same cation [C24H21N2]+ in the compound 1–3 appeared as a product of N‐allylquinolinium catalytic cyclodimerization. Neither N‐allyl nor C‐vinyl groups participate in CuI π‐coordination in the structures of 1 and 2, therefore [CuX2]− anions can possess a linear form.
Recent Advances in the Chemistry of “Clusters” and Coordination Polymers of Alkali, Alkaline Earth Metal and Group 11 Compounds
Authors: Fromm Katharina M. , Gueneau Estelle D. , Robin Adeline Y. , Maudez William , Sague Jorge , Bergougnant Rémi 
Published: July 2005

AbstractThis contribution gives an overview on the different subjects treated in our group. One of our fundamental interests lies in the synthesis and study of low‐dimensional polymer and molecular solid state structures. We have chosen several synthetic approaches in order to obtain such compounds.Firstly, the concept of cutting out structural fragments from a solid state structure of a binary compound will be explained on behalf of BaI2. Oxygen donor ligands, used as chemical scissors on BaI2, allow obtaining three‐, two‐, one‐ and zero‐dimensional derived compounds depending on their size and concentration. Thus, a structural genealogy tree for BaI2 can be established. This method, transferred to alkali halides using crown ethers and calix[n]arenes as delimiting ligands, leads us to the subject of one‐dimensional ionic channels.A second chapter deals with the supramolecular approach for the synthesis of different dimensional polymer structures derived from alkaline earth metal iodides, and based on the combination of metal ion coordination with hydrogen bonding between the cationic complexes and their anions. Under certain circumstances, rules can be established for the prediction of the dimensionality of a given compound, thus contributing to the fundamental problem of structure prediction in crystal engineering.A third part describes a fundamentally new synthetic pathway for generating pure alkaline earth metal cage compounds as well as alkali and alkaline earth mixed metal clusters. In a first step, different molecular precursors, such as solvated alkaline earth metal halides are investigated as a function of the ligand size and reactivity. They are then reacted with some alkali metal compound in order to partially eliminate alkali halide and to form the clusters. The so obtained unique structures of ligand stabilized metal halide, hydroxide and/or alkoxide and aryloxide aggregates are of interest as potential precursors for oxide materials. Approaches to two synthetic methods of the latter, sol‐gel and (MO)‐CVD, are investigated with our compounds.In order to generate single source precursors for oxide materials, we started to investigate transition metal ions, especially Cu and Ag, using multitopic ligands. This has led us into the fundamental problematic of “crystal engineering” and solid state structure prediction and we found ourselves confronted to numerous interesting cases of polymorphism and pseudo‐polymorphism. Weak interactions, such as π‐stacking, H‐bonding and metal‐metal interactions, and solvent, counter ion and concentration effects seem to play important roles in the construction of such low‐dimensional structures.Finally, the physical properties of some of our compounds are described qualitatively in order to show the wide spectrum of possibilities and potential applications for the chemistry in this field.
$^{1}_{\infty}\rm [Li_{3}(NbSe_{4})\cdot4MeCN]$ – ein neues lösliches Tetrachalkogenoniobat
Authors: Feuerhake Robert , Sahin Hülya , Fenske Dieter 
Published: July 2005

Abstract$^{1}_{\infty}\rm [Li_{3}(NbSe_{4})\cdot4MeCN]$ – a Novel Soluble TetrachalcogenoniobateIn Acetonitrile, Nb(OEt)5 reacts with LiOMe and Se(SiMe3)2 to form the novel tetraselenoniobate $^{1}_{\infty}\rm [Li_{3}(NbSe_{4})\cdot4MeCN]$. The molecular structure was determined by single crystal X‐ray diffraction. The new compound is soluble in polar organic solvents and seems to be a suitable starting material for the synthesis of new heterobimetallic complexes, as some reactivity towards copper phosphine complexes could be observed.
(Sr2N)H: Untersuchungen zur Redox‐Intercalation von Wasserstoff in Sr2N
Authors: Chemnitzer René , Auffermann Gudrun , Többens Daniel M. , Kniep Rüdiger 
Published: July 2005

Abstract(Sr2N)H: On the Redox‐Intercalation of Hydrogen into Sr2NStrontium‐nitride‐hydride is obtained as brown‐yellow single phase powder by reaction of strontium‐subnitride (Sr2N) with hydrogen (200 bar, 620 K) and subsequent treatment under vacuum (10−6 bar, 870 K). The structure determination was carried out by a combination of X‐ray and neutron diffraction experiments on a deuterated sample. The elemental composition of the ternary compound was confirmed by means of chemical analyses. (Sr2N)D crystallizes in the space group $R{\bar 3}m$ with a = 381.91(2) pm and c = 1887.61(2) pm. Strontium (Sr2+) in the crystal structure of (Sr2N)D is arranged with an only slightly distorted ccp‐motif. Nitrogen (N3−) and deuterium (D−) occupy the octahedral voids of the Sr2+‐matrix in an ordered manner resulting in an alternating sequence of layers (anti‐α‐NaFeO2‐type structure).
Metathetical Reactions in the System Na(K)PF6 – LiBF4 – Aprotic Media
Authors: Plakhotnyk Andriy V. , Tarasova Lidiya D. , Ernst Ludger , Schmutzler Reinhard 
Published: July 2005

Abstract19F NMR spectroscopy, X‐ray powder diffraction, elemental analysis, and ab initio quantum chemical calculations were used to study metathetical reactions between potassium or sodium hexafluorophosphate and lithium tetrafluoroborate in a mixture of propylene carbonate (PC) – dimethyl carbonate (DMC). It was shown that the increase in size of the cations in the second coordination sphere from Na+ to K+ results in an increase of the equilibrium conversion. This is in agreement with the influence of the cation size on the solubility of tetrafluoroborates in the media investigated.
Versuche zur Darstellung von t‐BuCN5S3 und die unerwartete Isolierung einer kovalenten Modifikation von Tetraschwefelpentastickstoff‐chlorid S4N5Cl
Authors: Knapp Carsten , Lork Enno , Borrmann Tobias , Stohrer Wolf‐Dieter , Mews Rüdiger 
Published: July 2005

AbstractAttempts to prepare t‐BuCN5S3 and the unexpected Isolation of a covalent Modification of Tetrasulfur‐pentanitrogen Chloride S4N5ClAttempts to prepare the bicyclic sulfur‐nitrogen heterocycle t‐BuCN5S3 via (NSCl)3 and the corresponding silylated amidinates and amidines failed because of the inaccessibility of the silylated intermediates. Reactions of MN(SiMe3)2 (M = Li, Na) with t‐BuCN did not yield the expected amidinates t‐BuC(NSiMe3)2M, instead the adducts [t‐BuCN·MN(SiMe3)2]2 were isolated. The attempted synthesis of t‐BuCN5S3 from t‐BuCN(SiMe3)2M, prepared in situ from t‐BuLi and Me3SiNCNSiMe3, and (NSCl)3 unexpectedly resulted a mixture of S4N5Cl and S5N6. The crystal structure determination for S4N5Cl showed a new covalent modification of S4N5Cl (monoclinic, P21/c, a = 1005.0(4) pm, b = 1193.5(8) pm, c = 1152.5(6) pm, β = 93.67(3)°), different from the known ionic S4N5Cl (orthorhombic, Pnma, a = 1738.90(10) pm, b = 781.50(10) pm, c = 483.03(5)). The unsuccessful attempts to prepare t‐BuCN5S3, the unexpected formation of S4N5Cl and S5N6, and the bonding properties of the new covalent modification of S4N5Cl are discussed.
Spectroscopic and Electrochemical Behavior of the Methyl and Ethyl Derivatives of Bis(acetylacetonato) oxovanadium(IV)
Authors: dos Santos Claro Paula C. , González‐Baró Ana C. , Parajón‐Costa Beatriz S. , Baran Enrique J. 
Published: July 2005

AbstractThe infrared, Raman and electronic spectra of the oxovanadium (IV) complexes of the 3‐methyl and 3‐ethyl substituted acetylacetone were recorded and discussed in detail, in comparison with that of the bis(acetylacetonato) complex and on the basis of the known structural data of these compounds. The electrochemical behavior of the three complexes was investigated by cyclic voltammetry in DMSO solutions, and the mechanism of the involved processes is briefly discussed.
The Structure of the Tricosahydrotetracosaborate Anion B24H233−
Authors: Volkov Oleg , Hu Chunhua , Kölle Ulrich , Paetzold Peter 
Published: July 2005

AbstractFollowing a modified prescription of 1969, the anion B24H233− was formed from B12H122− by electrolysis at 1.5 V. The crystal structure of M3(B24H23)(MeCN)1.5 (M = [CpFe{C5H4(CH2NMe3)}]) revealed the anion to consist of two icosahedral B12H11 units, connected by a bent B–H–B bridge. From the reaction of B12H122− with CF3COOH, reported in the literature as a source of B24H233−, the substitution product B12H11(CF3COO)2− was isolated.
The Crystal Structures of R3CuSnS7 (R = La–Nd, Sm, Gd–Ho)
Authors: Gulay L. D. , Olekseyuk I. D. , Wołcyrz Marek , Stępień‐Damm J. 
Published: July 2005

AbstractCrystal structures of R3CuSnS7 (R = La–Nd, Sm, Gd–Ho) (La3CuSiS7 structure type, space group P63, Pearson symbol hP24) were determined by means of X‐ray single crystal diffraction (a = 1.0317(1) nm, c = 0.60274(7) nm, R1 = 0.0202 for La3CuSnS7; a = 1.0209(1) nm, c = 0.60150(7) nm, R1 = 0.0273 for Ce3CuSnS7; a = 1.0075(1) nm, c = 0.60212(6) nm, R1 = 0.0224 for Nd3CuSnS7) and X‐ray powder diffraction (a = 1.01417(2) nm, c = 0.60210(2) nm, RBragg = 0.0824 for Pr3CuSnS7; a = 0.99288(2) nm, c = 0.60800(2) nm, RBragg = 0.0926 for Sm3CuSnS7; a = 0.98087(3) nm, c = 0.61511(3) nm, RBragg = 0.0885 for Gd3CuSnS7; a = 0.97512(2) nm, c = 0.61573(2) nm, RBragg = 0.0904 for Tb3CuSnS7; a = 0.97024(2) nm, c = 0.61694(2) nm, RBragg = 0.0918 for Dy3CuSnS7; a = 0.96527(2) nm, c = 0.61731(2) nm, RBragg = 0.0864 for Ho3CuSnS7). The structures are built up from columns of distorted face‐sharing sulfur anticuboctahedra arranged along the c‐axis. The columns are connected with each other via common edges. The remaining atoms are located in the intercolumnar channels.
π–π Stacking‐Interlinked Molecular Squares with Hepta‐Coordinated Cadmium(II) Corners, [Cd(DMAP)3(NO2)2]·0.5H2O
Authors: Marandi Farzin , Soudi Ali Akbar , Morsali Ali , Kempe Rhett 
Published: July 2005

AbstractThe single crystal X‐ray analysis data of the new hepta‐coordinate cadmium(II) complex of N,N‐dimethyl‐N‐(4‐pyridyl)amine (DMPA), [Cd(DMPA)3(NO2)2]·0.5H2O, shows that the coordination environment around the CdII is pentagonal bipyramidal. Furthermore, self‐assembly of this complex as molecular squares that interlink via π–π stacking interactions is observed. This network contains voids that are filled by water molecules.
Synthesis, Characterization and X‐ray Crystal Structure of a Chromium(III) Complex Obtained from a Proton‐Transfer Compound Containing 1,10‐Phenanthroline‐2,9‐dicarboxylic Acid and 2,6‐Pyridinediamine
Authors: Moghimi Abolghasem , Alizadeh Robabeh , Aragoni M. Carla , Lippolis Vito , Aghabozorg Hossein , Norouzi Parviz , Isaia Francesco , Sheshmani Shabnam 
Published: July 2005

AbstractThe novel 1,10‐phenanthroline‐2,9‐dicarboxylate containing Chromium(III) complex, (pydaH)[Cr(phendc)2] · 5H2O, was synthesized using proton‐transfer compound LH2, (pydaH2)2+(phendc)2−, (pyda: 2,6‐pyridinediamine; phendcH2: 1,10‐phenanthroline‐2,9‐dicarboxylic acid) and thoroughly characterized by elemental analysis, IR spectroscopy, X‐ray crystallography and cyclic voltammetry. The complex crystallizes in the monoclinic space group P21/n with four formula units in the unit cell. The unit cell dimensions are: a = 13.962(3) Å, b = 14.529(3) Å, c = 16.381(3) Å and β = 106.691(4)°. In this complex, 1,10‐phenanthroline‐2,9‐dicarboxylate acts as a tridentate ligand and the lattice is composed of anionic hexacoordinated complex, [Cr(phendc)2]−, 2,6‐pyridiniumdiamine counter ion, (pydaH)+, and five lattice water molecules.Crystallographic characterization revealed that the resulting supramolecular structure is strongly stabilized by complicated network of hydrogen bonds between the crystallization water molecules, counter ion and both coordinated and uncoordinated carboxylate groups. There is no relevant π‐π interaction for this anionic complex between pyda or phendc moieties. The electrochemical studies indicated over potential for both the cathodic and anodic peaks of the complex with respect to the free Cr3+ ion, as a consequence of the energy requirement for rearrangement of the ligand at electrode surface.
Synthesis and Structure of Bis(para‐methoxyphenyl)selenoxide and its Monohydrate. Theoretical Considerations of the Hydration of Diorganoselenium Oxides
Authors: Beckmann Jens , Duthie Andrew 
Published: July 2005

AbstractThe title compound was prepared by base hydrolysis of (p‐MeOC6H4)2SeCl2 in water and isolated as the crystalline monohydrate, (p‐MeOC6H4)2SeO·H2O, in which the water molecule is associated via hydrogen‐bonding. Water‐free (p‐MeOC6H4)2SeO was obtained crystalline after drying and recrystallisation from toluene. Both crystal phases were investigated by single crystal X‐ray diffraction. Preliminary DFT calculations at the B3LYP/LANL2DZdp level of theory suggest that the hydrogen bonded complexes R2SeO·H2O (R = H, Me, Ph) are by 2.79, 3.36 and 11.10 kcal mol−1 more stable than the corresponding elusive diorganoselenium dihydroxides R2Se(OH)2. The hydrogen bond energies of R2SeO·H2O (R = H, Me, Ph) are 5.98, 7.18 and 5.89 kcal mol−1.
Synthesis of Lanthanide Bromide Complexes from Oxides. The Crystal Structures of [LnBr2(diglyme)2][LnBr4(diglyme)] (Ln = Sm, Eu) and [LnBr2(HMPA)4]Br·0.5H2O (Ln = La, Sm)
Authors: Petriček Saša 
Published: July 2005

AbstractThe reaction of the lanthanide oxides, bromotrimethylsilane and water in THF resulted in [LnBr3(THF)x]. If digylme (diglyme = diethylen glicol dimethyl ether) was added to these reaction mixtures in the mole ratio n(Ln): n(diglyme) ∼ 1: 2.2 – 3, the ionic complexes [LnBr2(diglyme)2][LnBr4(diglyme)] (Ln = La (1), Sm (2), Eu (3)) were isolated. Crystal structures of the two new complexes, 2 and 3, which were recrystallized from dichloromethane, were determined. The immediate reaction of the complexes 1 and 2 with HMPA (HMPA = hexamethylphosphoramide) in toluene resulted in [LnBr2(HMPA)4]Br·0.5H2O (Ln = La(4), Sm (5)).
Synthese, Schwingungsspektren und Kristallstrukturen der Nitratoargentate (Ph4P)[Ag(NO3)2(CH3CN)]·CH3CN und (Ph4P)[Ag2(NO3)3]
Authors: Neumüller Bernhard , Weller Frank , Schmock Fritjof , Dehnicke Kurt 
Published: July 2005

AbstractSynthesis, Vibrational Spectra, and Crystal Structures of the Nitrato Argentates (Ph4P)[Ag(NO3)2(CH3CN)]·CH3CN and (Ph4P)[Ag2(NO3)3]Tetraphenylphosphonium bromide reacts in acetonitril suspension with excess silver nitrate to give (Ph4P)[Ag(NO3)2(CH3CN)]·CH3CN (1), whereas (Ph4P)[Ag2(NO3)3] (2) is obtained in a long‐time reaction from (Ph4P)Br and excess AgNO3 in dichloromethane suspension. Both complexes were characterized by vibrational spectroscopy (IR, Raman) and by single crystal structure determinations.1: Space group P21/c, Z = 4, lattice dimensions at 193 K: a = 1781.5(3), b = 724.8(1), c = 2224.2(3) pm, β = 96.83(1)°, R1 = 0.0348. 1 contains isolated complex units [Ag(NO3)2(CH3CN)]−, in which the silver atom is coordinated by the chelating nitrate groups and by the nitrogen atom of the solvated CH3CN molecule with a short Ag—N distance of 220.7(4) pm.2: Space group I2, Z = 4, lattice dimensions at 193 K: a = 1753.4(4), b = 701.7(1), c = 2105.5(4) pm, R1 = 0.072. In the polymeric anions [Ag2(NO3)3]− each silver atom is coordinated in a chelating manner by one nitrate group and by two oxygen atoms of two bridging nitrate ions. In addition, each silver atom forms a weak π‐bonding contact with a phenyl group of the (Ph4P)+ ions with shortest Ag···C separations of 266 and 299 pm, respectively, indicating a (4+1) coordination of silver atoms.
The Coordination Chemistry of the Ylide Adduct O2CC(PPh3)2; Preparation, Crystal Structures, and Spectroscopic Properties of [Cl3In{O2CC(PPh3)2}], [Cl2Sn{O2CC(PPh3)2}], and [I2In{O2CC(PPh3)2}2]I
Authors: Petz Wolfgang , Köhler Karen , Mörschel Philipp , Neumüller Bernhard 
Published: July 2005

AbstractThe betain like carbodiphosphorane CO2 adduct O2CC(PPh3)2 (1a) can serve as a ligand versus hard Lewis acids from main group compounds. Thus, reaction of 1a with InCl3, InI3 and SnCl2 in polar solvents leads to the addition compounds [Cl3In{O2CC(PPh3)2}] (2), [Cl2SnO2CC(PPh3)2}] (3) and the salt like compound [I2In{O2CC(PPh3)2}2]I (4) in good yields. Whereas in the indium compounds 1a acts as a chelating ligand, in the tin compound the molecule coordinates with one oxygen atom only as a monodentate ligand. 4 has a pyramidal structure with a stereochemical active pair of electrons. All compounds could be characterized by X‐ray analyses and the usual spectroscopic methods.
Synthesis and Crystal Structure Determination by X‐Ray Powder Diffraction of Nickel Tetrametaphosphimate Octahydrate Ni2(PO2NH)4 · 8 H2O
Authors: Römer S. Rebecca , Schnick Wolfgang 
Published: July 2005

AbstractNi2(PO2NH)4 · 8 H2O is isotypic with M2(PO2NH)4 · 8 H2O (M = Mg, Mn, Co, Zn) and crystallizes in the space group P21/c, Z = 2, with a = 641.25(1), b = 1041.42(1), c = 1278.18(2) pm and β = 104.243(1)°. The structure is composed of Ni2+ and (PO2NH)44− ions as well as crystal water molecules. The P4N4 rings of the (PO2NH)44− ions exhibit a slightly distorted chair–2 conformation, which has been described by torsion angles, displacement asymmetry parameters and puckering parameters. The tetrametaphosphimate anions are connected forming layers. These layers are linked solely by hydrogen bonds, forming a three‐dimensional network.
Synthese und Kristallstruktur von 2‐Azido‐4,6‐dichloro‐s‐triazin
Authors: Gibson Katharina , Tragl Sonja , Meyer H.‐Jürgen 
Published: July 2005

AbstractSynthesis and Crystal Structure of 2‐Azido‐4,6‐dichloro‐s‐triazineSingle crystals of 2‐azido‐4,6‐dichloro‐s‐triazine were obtained from a reaction between cyanuric chloride and sodium azide. The structure of this compound was determined by single crystal X‐ray diffraction. 2‐Azido‐4,6‐dichloro‐s‐triazine crystallizes in the orthorhombic space group Pbca (no. 61), Z = 8, a = 746.48(8) pm, b = 952.6(1) pm, c = 2001.6(2) pm. The crystal structure contains (C3N3)(N3)Cl2 molecules being arranged in a tape‐like fashion, with tapes running along a‐axis direction. The tapes are combined with each other by interlocking azide‐ligands including an angle of approximately 90°. This arrangement leads to the formation of corrugated layers in the crystal structure.