bluuebunny/crossref_metadata_2025_split huggingface dataset:
Combination of bifunctional aldehydes and poly(vinyl alcohol) as the crosslinking systems to improve paper wet strength
Authors: Xu Gordon G. , Yang Charles Q. , Deng Yulin 
Published: May 2004

AbstractTwo bifunctional aldehydes (i.e., glyoxal and glutaraldehyde) are used as the crosslinking agents to improve paper wet strength in the presence of fully hydrolyzed poly(vinyl alcohol) (PVA) as a co‐reactant. These bifunctional aldehydes alone improve paper wet strength but diminish its folding endurance. The use of PVA as a co‐reactant not only improves paper wet strength but also increases its dry strength and folding endurance. Glutaraldehyde is able to impart much higher levels of wet strength to the treated paper than glyoxal when a catalyst is present. The wet strength of the treated paper increases as the amount of PVA added is increased, and it also increases as the molecular weight (Mw) of the PVA increases. The data suggest that the reaction between glutaraldehyde and PVA promotes the formation of interfiber crosslinking, thus improving the wet strength without diminishing the flexibility of the treated paper. The use of a catalyst is critical to achieve high levels of durable wet strength of the treated paper. We studied the effects of different Lewis acids as the catalysts for crosslinking of pulp cellulose by glutaraldehyde and found that Zn(NO3)2 is the most effective one. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 1673–1680, 2004
MoO2(acac)2 immobilized on polymers as catalysts for cyclohexene epoxidation: Effect of the degree of crosslinking
Authors: Reyes Patricio , Borda Gloria , Gnecco Juan , Rivas Bernabé L. 
Published: May 2004

AbstractCrosslinked poly(4‐vinylpyridine‐co‐styrene) used as support for a immobilized oxomolybdenum complex was synthesized by radical polymerization. As crosslinking agent, 1,4‐divinylbenzene (DVB) was incorporated at 2, 4, and 6 mol %. Catalysts having similar MoO2(acac)2 loading on different resins were obtained by refluxing a solution of the complex with the polymeric supports at 70°C. FTIR, specific surface area, and XPS techniques were used for characterization. It was found that a significant increase in the surface area occurs as the degree of crosslinking increases, presumably due to the development of branched polymers having higher porosity. XPS showed that the complex is anchored to the pyridinic nitrogen on the resin and that that Mo was present essentially as Mo(VI) species. The Mo/C atomic surface ratio exhibits a maximum for the catalyst with medium crosslinking degree. The epoxidation of cyclohexene was studied in the temperature range 40–60°C by using tert‐butyl hydroperoxide as oxidant agent. The catalysts were active and selective to the corresponding epoxide and almost no leaching of the active phase was observed. The highest catalytic activity of the studied solids was displayed by the one supported on the resin with intermedium degree of crosslinking. The results are explained in terms of the access to the active sites and surface composition. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 1602–1608, 2004
Thermally stable conducting composites based on a carbon black‐filled polyoxadiazole matrix
Authors: Souza Fernando G. , Sena Maria E. , Soares Bluma G. 
Published: May 2004

AbstractNew thermally stable conducting materials can be obtained by dispersing conducting carbon black into poly(4,4′‐diphenylether‐1,3,4‐oxadiazole) (POD–DPE) solution in NMP. The blend preparation process resulted in quite good dispersed composite and a relatively low percolation threshold (around 5 wt % of CB). The effect of the compressive stress on the resistivity of composite has been evaluated. The resistivity decreases continuously as the applied pressure is increased. In addition to the electrical conductivity, the presence of carbon black resulted in higher thermally stable materials. The thermal stability, electrical conductivity, and pressure‐sensible characteristics make this conducting material a good candidate for application in manufacture of pressure sensors for high temperature ambient. This material shows a typical semiconductor behavior, characterized by an increase of conductivity with the temperature. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 1631–1637, 2004
Role of molecular weight of atactic poly(vinyl alcohol) (PVA) in the structure and properties of PVA nanofabric prepared by electrospinning
Authors: Lee Joon Seok , Choi Kyu Ha , Ghim Han Do , Kim Sam Soo , Chun Du Hwan , Kim Hak Yong , Lyoo Won Seok 
Published: May 2004

AbstractAtactic poly(vinyl alcohols) (a‐PVAs) having number‐average degrees of polymerization [(Pn)s] of 1700 and 4000 were prepared by the solution polymerization of vinyl acetate, which was followed by the saponification of poly(vinyl acetate) to investigate the effects of molecular weights of a‐PVA on the characteristics of electrospun a‐PVA nanofabrics. A‐PVA nanofabrics were prepared by electrospinning with controlling the process parameters including the electrical field, conductivity, tip‐to‐collector distance, and solution concentration. Through a series of characterization experiments, we identified that the molecular weight of a‐PVA had a marked influence on the structure and properties of nanofabrics produced. That is, the higher the molecular weight of PVA, the superior the physical properties of PVA nanofabric. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 1638–1646, 2004
Microwave‐assisted and classical heating polycondensation reaction of bis(p‐amido benzoic acid)‐N‐trimellitylimido‐L‐leucine with diisocyanates as a new method for preparation of optically active poly(amide imide)s
Authors: Mallakpour Shadpour , Rafiemanzelat Fatemeh 
Published: May 2004

AbstractA new class of optically active poly(amide imide)s were synthesized via direct polycondensation reaction of diisocyanates with a chiral diacid monomer. The step‐growth polymerization reactions of monomer bis(p‐amido benzoic acid)‐N‐trimellitylimido‐L‐leucine (BPABTL) (5) as a diacid monomer with 4,4′‐methylene bis(4‐phenylisocyanate) (MDI) (6) was performed under microwave irradiation, solution polymerization under gradual heating and reflux condition in the presence of pyridine (Py), dibuthyltin dilurate (DBTDL), and triethylamine (TEA) as a catalyst and without a catalyst, respectively. The optimized polymerization conditions according to solvent and catalyst for each method were performed with tolylene‐2,4‐diisocyanate (TDI) (7), hexamethylene diisocyanate (HDI) (8), and isophorone diisocyanate (IPDI) (9) to produce optically active poly(amide imide)s by the diisocyanate route. The resulting polymers have inherent viscosities in the range of 0.09–1.10 dL/g. These polymers are optically active, thermally stable, and soluble in amide type solvents. All of the above polymers were fully characterized by IR spectroscopy, 1H NMR spectroscopy, elemental analyses, specific rotation, and thermal analyses methods. Some structural characterization and physical properties of this new optically active poly(amide imide)s are reported. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 1647–1659, 2004
Miscibility study of polymer blends composed of semirigid thermotropic liquid crystalline polycarbonate, poly(vinyl alcohol), and chitosan
Authors: Sato Moriyuki , Koshino Tomohiro , Kajitani Yasuko , Inamura Isamu , Kubo Yasuo 
Published: May 2004

AbstractMiscibility of binary and ternary polymer blends composed of thermotropic liquid crystalline polycarbonate (LCPC), poly(vinyl alcohol) (PVA), and chitosan was investigated by viscosity method, FTIR spectrum, and scanning electron microscope techniques. Effect of addition of chitosan as a compatibilizer on miscibility and morphology of binary LCPC/chitosan and PVA/chitosan and ternary LCPC/PVA/chitosan polymer blends was discussed. These measurements indicated that addition of chitosan into the blends of LCPC with PVA leads to an increase of miscibility and a formation of clear fibril structures on fractured surfaces, which are due to intermolecular hydrogen‐bonding interaction between LCPC, PVA, and chitosan chains. It was suggested that side‐chain hydroxy group of PVA and amino and hydroxy groups of chitosan play an important role in the formation of miscible phase and improvement of morphology in binary and ternary blends composed of LCPC, PVA, and chitosan. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 1616–1622, 2004
Rheological quantification of molecular parameters: Application to a hydrogen bond forming blend
Authors: Cai Haijun , Ait‐Kadi Abdellatif , Brisson Josée 
Published: May 2004

AbstractThe component dynamics and molecular parameters were investigated for miscible poly(4‐vinyl phenol)/poly(ethylene oxide) (PVPh/PEO) blends. Global values of molecular weight between entanglements (Me) were first estimated for the blends and were compared with existing athermal model predictions. Global interchain friction coefficients (ξ) of the blends were deduced from the zero‐shear viscosity. A maximum was observed at a composition of 20–30 wt % of PEO. Chain dimensions of this phase are estimated by using a relationship between the plateau modulus and a packing length (i.e., number of individual chains present in a given small volume of the melt). A slight increase in Me is observed at low PEO weight fraction (before 0.20), followed by a sharp decrease in Me values after this concentration. Values of ξ in PVPh/PEO blends show a maximum value at 20–30 wt % of PEO. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 1623–1630, 2004
Cationized milled pine bark as an adsorbent for orthophosphate anions
Authors: Tshabalala Mandla A. , Karthikeyan K. G. , Wang D. 
Published: May 2004

AbstractMore efficient adsorption media are needed for removing dissolved phosphorus in surface water runoff. We studied the use of cationized pine bark as a sorbent for dissolved phosphorus in water. Cationized pine bark was prepared by treating extracted milled pine bark with polyallylamine hydrochloride (PAA HCl) and epichlorohydrin (ECH) in aqueous medium. Attachment of PAA HCl to the bark was monitored by percentage of weight gain and nitrogen content. Changes in bark surface chemistry were characterized by zeta potential and inverse gas chromatography measurements. Energy dispersive x‐ray analysis and scanning electron microscopy were used to determine changes in chemical composition and morphology of the cationized bark. The cationized bark showed a decrease in the dispersive component of the surface energy and a barely measurable change in the surface acid–base properties. In the pH range 2.5 to 7.9, the cationized bark showed a positive zeta potential, which changed to negative at pH 7.9 or higher. By comparison, the zeta potential of control extracted bark remained negative throughout the pH range of 2.5 to 9. We propose that the reaction of bark with PAA HCl results in a surface network of fixed cationic sites of quaternary ammonium that have mobile chloride ions as counter anions. Preliminary results from batch adsorption experiments indicate that cationized milled bark has an estimated maximum adsorption capacity of approximately 12.65 mg phosphate/g, which compares favorably with that of other well‐known phosphorus sorbents. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 1577–1583, 2004
Biaxially self‐reinforced high‐density polyethylene prepared by dynamic packing injection molding. I. Processing parameters and mechanical properties
Authors: Lei Jun , Jiang Chaodong , Shen Kaizhi 
Published: May 2004

AbstractUniaxial oscillating stress field by dynamic packing injection molding (DPIM) is well established as a means of producing uniaxially self‐reinforced polyethylene and polypropylene. Here, the effects on the mechanical properties of high‐density polyethylene (HDPE) in both flow direction (MD) and transverse direction (TD) of packing modules and processing parameters in DPIM are described. Both biaxially and uniaxially self‐reinforced HDPE samples are obtained by uniaxial shear injection molding. The most remarkable biaxially self‐reinforced HDPE specimens show a 42% increase of the tensile strength in both MD and TD. The difference of stress–strain behavior and impact strength between MD and TD for the DPIM moldings indicates the asymmetry of microstructure in the two directions. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 1584–1590, 2004
Combining melody processing and information retrieval techniques: Methodology, evaluation, and system implementation
Authors: Melucci Massimo , Orio Nicola 
Published: May 2004

AbstractThe article describes the project on music information retrieval that has been carried out at the University of Padova, Italy. The research work has been characterized by the synergy of the modular integration of sound techniques of melody processing and of statistical information retrieval. After illustrating the background from which the project has originated, we describe the complete process, from methodology design through evaluation and system implementation. Conclusions, impacts on research in music information retrieval, and future directions are also described.
BV photometry of five shell galaxies
Authors: Pierfederici F. , Rampazzo R. 
Published: May 2004

AbstractCurrent views consider shell structures as bona fide signatures of a recent minor/major merging event though also weak interaction models (WIM) could produce long lasting shells on host galaxies possessing a stellar thick disc.We present a B V band photometric study of a sample of 5 shell galaxies belonging to the Malin & Carter (1983) compilation. The structural properties and colors of the galaxies, as well as the colors of their shells are examined in detail.We did not find signatures of the presence of double nuclei. NGC 7585 is the only E galaxy in the sample and has a moderately boxy structure. The other galaxies have either a discy structure or are mixed E/S0 type galaxies. NGC 474 is a true lenticular. NGC 6776 shows a diffuse asymmetric outer structure and a system of tails of the the same color of the galaxy body; but not clear shells. In general, the color of the shells in our sample is similar or slightly redder than that of the host galaxy, whose color, in turn, is typical of the early‐type morphological class. One of the outer shells of NGC 474 is significantly bluer than the body of the galaxy. Since NGC 474 appears to be interacting with NGC 470, the color of this one shell could be explained as result of a recent acquisition of material through tidal interaction.The WIM hypothesis could explain both the red and the blue shells of NGC 474, this latter acquired from the fly‐by of the nearby companion NGC 470, but the lack of the constancy of shell surface brightness as a ratio of the underlying galaxy brightness argues against WIM. We speculate about evidence, which also comes from different observations, that suggests a merging/accretion origin of the shells. (© 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
H II emission line region in LEDA 212995, a small neighboring galaxy of Mrk 1040
Authors: Popović L. Č. , Mediavilla E. G. , Bon E. , Ilić D. , Richter G. 
Published: May 2004

AbstractWe present here new spectroscopic observations of Mrk 1040 and LEDA 212995 (Mrk 1040 companion) obtained with the Isaac Newton Telescope (INT). The intensity ratios and widths for the narrow emission lines found in LEDA 212995 are typical of H II regions. The red‐shift (0.0169 ± 0.00015) of the object derived from these emission lines is very close to the red‐shift of Mrk 1040 (z = 0.01665). The weak narrow and broad absorption lines were detected in the Hα wavelength band of LEDA 212995 spectra. These absorptions indicate that the companion might be at least partly obscured by Mrk 1040. Using this and previous observations we discuss the possible physical relationship between these two galaxies. (© 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
The close binary system SU Ind
Authors: Budding E. , Rhodes M. , Priestley J. , Zeilik M. 
Published: May 2004

AbstractPhotometric data on the southern mid‐F type close eclipsing binary system SU Ind from the Carter Observatory (NZ) were examined, together with a light curve obtained from the Hipparcos Epoch Photometry (HEP) database. The system appears detached, although appreciably evolved from the Zero Age Main Sequence. The HEP period must be accurate for its own epoch, but it is significantly different from the reference (Hoffmeister 1956) value. This is difficult to explain, given the uncomplicated nature of the light curve. The apparent discrepancy can be reconciled with a period that has remained almost constant over the 40 year interval between the epochs by assuming some confusion between the almost equal depth minima. The near‐equality of components raises issues of determinacy in light curve analysis, which are reviewed against the presentation of relevant numerical curve‐fitting details. The system is of physical interest, in that it is close to the start of the ‘active’ range of spectral types. Its stars have relatively rapid rotation speeds and probably shallow convective subphotospheric layers. (© 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
Impact of astronomical research from different countries
Authors: Sánchez S. F. , Benn C. R. 
Published: May 2004

AbstractThe impact of astronomical research carried out by different countries has been compared by analysing the 1000 most‐cited astronomy papers published 1991‐8 (125 from each year). 61% of the citations are to papers with first authors at institutions in the USA, 11% in the UK, 5% in Germany, 4% in Canada, 3% in Italy and 3% in France. 17% are to papers with first authors in ESO countries. The number of citations is approximately proportional to the number of IAU members in a given country. The number of citations per IAU astronomer is highest in the USA, Switzerland and the UK. Within continental Europe, the number of citations per IAU astronomer varies little from country to country, but is slightly higher in the north than in the south. The sample of 1000 papers maps regional subject preferences. 62% of the extragalactic papers in the sample were published from the USA, 15% from the UK, 23% from other countries (mainly in continental Europe). 62% of the papers on stars were also published from the USA, but the fractions from the UK and from other countries are 2% and 36% respectively. (© 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
Magnetic activity and dynamics of close binaries
Authors: Lanza A.F. , Rodonò M. 
Published: May 2004

AbstractThe connection between orbital period modulation and magnetic activity in close binaries is reviewed with an emphasis on the comparison between observational data for RS CVn systems and recently proposed theoretical models. The orbital period changes occurring on timescales of the order of a few decades can be accounted for by means of a standing torsional Alfven wave in the convection zone of the magnetically active components of such systems. Two resonant excitation mechanisms based on the coupling between the wave and an αΩ dynamo are discussed from a qualitative point of view. (© 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
Spots on FK Com: active longitudes and “flip‐flops”
Authors: Korhonen H. , Berdyugina S.V. , Tuominen I. 
Published: May 2004

AbstractWe have earlier investigated the surface structures of a late‐type, single, giant FK Com for the years 1994–1998 using Doppler imaging. These surface temperature maps revealed long‐lived active regions at high latitudes. Long‐term photometric observations also show that these active regions tend to occur at two permanent active longitudes which are 180 degrees apart from each other, and that the activity switches the longitude with an average period of about 3 years (the “flip‐flop” phenomenon). In this work we present new Doppler maps of FK Com obtained 1998‐2003 and light‐curve maps obtained 2002–2003. These new maps are investigated together with the earlier temperature maps and light‐curve maps, with an aim of further studying the active longitudes, “flip‐flop” phenomenon and surface differential rotation on FK Com. (© 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
Stellar activity on the lower main sequence in Praesepe
Authors: Kafka S. , Honeycutt R.K. 
Published: May 2004

AbstractAn αΩ dynamo is considered responsible for magnetic activity in late K/early M main sequence stars, which is expected to be enhanced in later types as the surface convection zone deepens. At about spectral type M3, where the star presumably becomes fully convective, the magnetic field is theorized to change in character, switching to a more uniform, turbulence‐generated surface field. As a consequence, the nature of activity is expected to change at later spectral types. In field stars, age, mass, rotation and perhaps metallicity play a role in determining the activity level, but the effects are difficult to disentangle. Therefore, open clusters with a more homogeneous sample can provide valuable information on the dynamo operation and magnetic activity of lower main sequence stars. We present preliminary results of our spectroscopic study for activity indicators among the lower main sequence stars of the intermediate age (700 My) open cluster Praesepe. Chromospheric activity as manifested by the presence/absence of Hα in late K/M stars is presented, and other activity indicators are discussed. (© 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
Thin flux tube models for star spots
Authors: Granzer T. 
Published: May 2004

AbstractThe possibility of understanding stellar activity as an up‐scaled version of the activity of our Sun is investigated. A theoretical model to explain properties of sunspots is used for explaining observed latitudes of star spots. The model is based on thin‐flux‐tube simulations that study the path of magnetic flux tubes from their origin in a stellar overshoot layer to photospheric layers. A direct comparison of the simulation results with individual stars is given. (© 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
The eclipsing active star SV Camelopardalis
Authors: Patkós L. , Csizmadia Sz. 
Published: May 2004

AbstractWe present analysis and spot solutions based on yet unpublished B and V photoelectric observations on the active binary system SV Cam, carried out at Piszkéstető Mountain Station of Konkoly Observatory Budapest. The present spot solutions are based on the observed light curves in September 1993 and July 1994. Comparison of recent and older spot solutions – taken from the literature – suggests long term differences, but these divergences might be caused by some differences of the applied computational methods. (© 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)