bluuebunny/crossref_metadata_2025_split huggingface dataset:
Bio‐Templated Silver Nanopatterns for Photothermal and Antifogging Coatings
Authors: De Swarnalok , Nguyen Hoang M. , Zou Fangxin , Basarir Fevzihan , Mousavi Maryam , Mäkinen Kristiina , Kostiainen Mauri A. , Vapaavuori Jaana 
Published: December 2023

AbstractTransparent photothermal coatings based on plasmonic noble metals often face a trade‐off between achieved temperatures and transmittances. This challenge arises from the fact that plasmonic nanoparticles (NPs), which rely on their size and structures, selectively absorb light of various wavelengths and convert it into heat. In the cases of randomly arranged plasmonic NPs, absorbances are predominantly in the visible range, leading to lowered transmittances. In this work, the self‐assembly behavior of a biotemplate containing flexible potato virus A (PVA) is used to produce network‐like surface patterns with controllable intermittent vacancies. These templates effectively anchor silver nanoparticles (AgNPs), forming dense arrays of plasmonic hotspots interspersed with vacant regions. With this approach, a temperature increase of 21 °C above ambient temperature under 1‐sun radiation is achieved while maintaining a visible light transmittance as high as 78% measured at 550 nm wavelength. The PVA biotemplated AgNPs show excellent potential as antifogging coating, exhibiting 2–3 times faster defogging rates compared to uncoated samples in both indoor and outdoor conditions. Overall, a platform is presented for biotemplating metal NPs, the development of long‐range surface patterns with controlled vacancies, and the demonstration of transparent photothermal activity with an antifogging application.
Tailoring Fe3+‐Activated Broadband NIR Phosphors: Enhancing External Quantum Efficiency and Spectrum Adjustability Through Crystal Field Engineering in Double Perovskite Antimonate Structures
Authors: Zhang Xibao , Wu Xiudi , Xu Yonghui , Yin Shuwen , Zhong Chuansheng , Zhou Liang , You Hongpeng 
Published: December 2023

AbstractFor near‐infrared (NIR) luminescent materials, it is a challenge to develop the next generation materials with high external quantum efficiency (EQE), low toxicity, and adjustable spectrum. The transition metal ion Fe3+ can act as a good activator and emit NIR light in oxide host lattice, but there is limited research on this topic. Herein, authors have developed a series of Fe3+ activated A2BSbO6:yFe3+ (A = Ca, Sr, Ba; B = Sc, Y, Ga) phosphors with a double perovskite structure, which can efficiently convert the exciting light into NIR emission in the range of 750–1200 nm with a full‐width half‐maximum (FWHM) of 1372−1525 cm−1. The NIR luminescence originates from the 4T1 (4G)→6A1 (6S) transition of the Fe3+ ions situated in the octahedral sites. By employing crystal field engineering, the emission spectra peak can be adjusted within the range of 842–944 nm, and the excitation spectra can be tuned from 334 to 374 nm. These spectral adjustments enable a good match between the phosphors and commercially ultraviolet chips. When excited at 334 nm, the Sr2ScSbO6:0.1%Fe3+ phosphor demonstrates a remarkably high EQE of 54.2% and high luminescent thermostability. These characteristics make it suitable for applications in NIR spectral detection.
Synthesis of Furo[2,3‐f]dibenzotropones via Intramolecular Wittig Reaction of Alkylidene Dibenzo‐β‐tropolones
Authors: Chien Po‐Chung , Chen Yi‐Ru , Chen You‐Jie , Chang Ching‐Fen , Marri Gangababu , Lin Wenwei 
Published: December 2023

AbstractA strategy was developed for synthesizing furan‐fused dibenzotropones via intramolecular Wittig reactions of alkylidene dibenzo‐β‐tropolones and acylating reactants in catalytic or stoichiometric conditions. With these protocols, a series of furo[2,3‐f]dibenzotropones were obtained in 49–99% yields within 1–10 hours. Mechanistic studies of the base‐free phenomena revealed that the organophosphane acts both as a mediator and a regenerable Brønsted base under heating.
Exploring Optoelectronic‐Thermal Coupling in Perovskite Solar Cells Utilizing Varied Hole Transport Layers
Authors: Cheng Wan , Liu Ying , Zhou Rui , Yang Yuanlin , Wang Chunxia , Li Ying , Zhou Liwei , Niu Lianbin , Chen Lijia 
Published: December 2023

AbstractPerovskite solar cells (PSCs) have become a research hotspot both domestically and internationally due to their superior optoelectronic performance as a new type of thin‐film solar cell. One of the methods to enhance the performance of PSCs is the optimization of the hole transport layer(HTL). In this study, COMSOL Multiphysics simulation software is employed to model and simulate PSCs, and perform coupled simulations of the optical, electrical, and thermal properties of PSCs with different HTL. The simulations analyze the carrier concentration, Shockley–Read–Hall (SRH) recombination, electric field profile, and temperature distribution in the devices. The simulation results demonstrate that among the different HTL (CuO, Spiro‐OMeTAD, and NiO), NiO exhibited more favorable characteristics as a HTL for improving the photovoltaic conversion efficiency of PSCs. The photovoltaic conversion efficiency reached 17.14% with NiO as the hole transport layer, and the SRH recombination rate in PSCs based on NiO HTL of PSCs is lower than CuO and Spiro‐OMeTAD, facilitating efficient charge transport. Furthermore, the temperature distribution of PSCs is analyzed based on different HTL, and the results indicate that PSCs with NiO as the hole transport layer exhibited higher thermal stability.
Secondary and micronutrient application effects on corn fertilized for different yield goals under highly weathered soil conditions
Authors: Amissah Solomon , Ankomah Godfred , Lee Robert D. , Sohag Md Ariful I. , Harris Glendon H. , Cabrera Miguel , Franklin Dorcas H. , Diaz‐Perez Juan C. , Sintim Henry Y. 
Published: December 2023

AbstractHighly weathered soils have low native fertility; thus, optimum nutrient management is critical, especially for a high‐input crop such as corn (Zea mays). Field studies were established in Plains and Tifton, GA, to assess secondary nutrient (SN; Mg, Ca, and S) and micronutrient (MN; B, Zn, Mn, Fe, Cu, and Mo) application effects on corn fertilized with primary nutrients (PN; N, P, and K) to achieve 12.5 Mg ha−1 (low) and 25.1 Mg ha−1 (high) yields. Both Plains and Tifton have Ultisol soil. However, the Tifton soil has a 30‐cm top sandy layer, and the Plains soil has no top sandy layer. Differences in corn nutrient concentrations were observed at the V5–V7 stage but not in biomass accumulation. The 12.5 Mg ha−1 target grain yield from applying the low PN was exceeded at both locations (by 19.0%–26.6% in Plains and 6.3%–19.7% in Tifton), irrespective of the SN or MN application. However, the 25.1 Mg ha−1 target grain yield from applying the high PN rate was not achieved, with yields of 16.9–17.7 Mg ha−1 in Plains and 15.7–17.1 Mg ha−1 in Tifton obtained. The SN and/or MN application increased corn yield (by 2.3%–13.6%) across all conditions, but the differences were statistically significant under just the low PN rate in Tifton. Overall, the results showed that SN and MN could be yield‐limiting factors of corn in the Ultisol soils tested in the study, and also 12.5 Mg ha−1 corn yield can be achieved with lower PN rates than currently recommended.
A severe neurocognitive phenotype caused by biallelic CHD3 variants in two siblings
Authors: Goldfarb Yaacobi Racheli , Sukenik Halevy Rivka 
Published: December 2023

AbstractCHD3 heterozygous variants are associated with Snijders Blok‐Campeau syndrome (SBCS) which consists of intellectual disability (ID), macrocephaly, and dysmorphic facies. Most reported variants are missense or loss of function clustered within the ATPase/helicase domain of the protein. We report a severe neurocognitive phenotype caused by biallelic CHD3 variants in two siblings, each inherited from a mildly affected parent. Male and female siblings were referred to the Genetics Clinic due to severe ID and profound dysmorphism. The parents are first cousins of Iranian descent with borderline intellectual abilities. Exome sequencing was performed for the affected female and her parents. A single homozygous candidate variant in the CHD3 gene was detected in the proband: c.5384_5389dup. p.Arg1796_Phe1797insTrpArg, resulting in an in‐frame insertion of 2 amino acids located outside the ATPase/helicase domain at the C‐terminal region of CHD3‐encoding residues. This variant is classified as likely pathogenic according to ACMG guidelines. The variant was detected in a heterozygous state in each parent. Both affected siblings were homozygous, while their unaffected brother did not carry the variant. Biallelic CHD3 variants cause a severe neurodevelopmental syndrome that is distinguishable from SBCS. We assume that the variant type (in‐frame insertion) and location may enable CHD3 biallelic variants.
Genetics of 21‐hydroxylase deficiency: Clinical presentation should guide the investigation
Authors: Ilany Jacob 
Published: December 2023

AbstractA young couple applied for preconception counseling because of a case of congenital adrenal hyperplasia in the family. They were concerned about their risk of giving birth to a child with classic congenital adrenal hyperplasia. The case presented here demonstrates the complexity of the genetics of 21‐hydroxylase deficiency and the way the clinical presentation should guide the genetic inquiry.
Weak Solvation Effect Induced Optimal Interfacial Chemistry Enables Highly Durable Zn Anodes for Aqueous Zn‐Ion Batteries
Authors: Cao Xianshuo , Xu Wei , Zheng Dezhou , Wang Fuxin , Wang Yi , Shi Xin , Lu Xihong 
Published: December 2023

AbstractAqueous zinc‐ion batteries (AZIBs) are emerging as one of the most reliable energy storage technologies for scale‐up applications, but still suffer from the instability of Zn anode, which is mainly caused by the undesirable dendrite growth and side reactions. To tackle these issues, we formulate a new aqueous electrolyte with weak solvation effect by introducing low‐dielectric‐constant acetone to achieve H2O‐poor solvation structure of Zn2+. Experimental and theoretical calculation studies concurrently reveal that such solvation structure can: i) relieve the solvated H2O related side reactions, ii) suppress the dendrite growth by boosting the desolvation kinetics of Zn2+ and iii) in situ form solid electrolyte interface (SEI) to synergistically inhibit the side reaction and dendrite growth. The synergy of these three factors prolongs the cycling life of Cu/Zn asymmetric cell from 30 h to more than 800 h at 1 mA cm−2/1 mAh cm−2, and can work at more harsh condition of 5 mA cm−2/5 mAh cm−2. More encouragingly, Zn/V2O5 ⋅ nH2O full cell also shows enhanced cycling stability of 95.9 % capacity retention after 1000 cycles, much better than that with baseline electrolyte (failing at ≈700th cycle).
Perfluoroalkyl‐Decorated Noble‐Metal‐Free MOFs for the Highly Efficient One‐Pot Four‐Component Coupling between Aldehydes, Amines, Alkynes, and Flue Gas CO2
Authors: Yang Fan , Wang Jiajia , Wang You , Yu Benling , Cao Yiwen , Li Jiawei , Wu Linlin , Huang Jianhan , Liu You‐Nian 
Published: December 2023

AbstractThe non‐noble‐metal catalysed‐multicomponent reactions between flue gas CO2 and cheap industrial raw stocks into high value‐added fine chemicals is a promising manner for the ideal CO2 utilization route. To achieve this, the key fundamental challenge is the rational development of highly efficient and facile reaction pathway while establishing compatible catalytic system. Herein, through the stepwise solvent‐assisted linker installation, post‐synthetic fluorination and metalation, we report the construction of a series of perfluoroalkyl‐decorated noble‐metal‐free metal–organic frameworks (MOFs) PCN‐(BPY‐CuI)‐(TPDC‐Fx) [BPY=2,2′‐bipyridine‐5,5′‐dicarboxylate, TPDC‐NH2=2′‐amino‐[1,1′:4′,1′′‐terphenyl]‐4,4′′‐dicarboxylic acid] that can catalyze the one‐pot four‐component reaction between alkyne, aldehyde, amine and flue gas CO2 for the preparation of 2‐oxazolidinones. Such assembly endows the MOFs with superhydrophobic microenvironment, superior water resistance and highly stable catalytic site, leading to 21 times higher turnover numbers than that of homogeneous counterparts. Mechanism investigation implied that the substrates can be efficiently enriched by the MOF wall and then the adsorbed amine species act as an extrinsic binding site towards dilute CO2 through their strong preferential formation to carbamate acid. Moreover, density functional theory calculations suggest the tetrahedral geometry of Cu in MOF offers special resistance towards amine poisoning, thus maintaining its high efficiency during the catalytic process.
Solid state conversion of novel coordinated precursors to visible light active photocatalysts with enhanced photocatalytic activity
Authors: Hasan Mohammad , Ali Mayada S. , Madkour Metwally 
Published: December 2023

The new polydentate N'1,N'3‐bis((E)‐3‐oxopentan‐2‐ylidene)malonohidrazide chelating agent (H2L) and its coordinated complexes of Co2+, Cu2+, and Ni2+ were prepared and characterized by elemental analysis, molar conductance, and spectra (Fourier transform infrared [FT‐IR], ultraviolet–visible spectroscopy [UV–vis], and Fast‐Atom Bombardment Mass Spectrometry (FAB‐MS). Also, thermal and magnetic investigations were conducted. X‐ray single crystal of the H2L ligand revealed a triclinic structure with space group P‐1. In this study, we provide a one‐pot preparation approach for transition metal oxide nanoparticles (NPs) such as CuO, Co3O4, and NiO NPs. The methodology entails the thermal decomposition of coordinated metal precursors in a solid‐state environment, obviating the necessity for agitation and rinsing. The remarkable significance of this method lies in its ability to produce highly pure NPs without the requirement of washing, and it allows for systematic and efficient production. Herein, we propose a large‐scale, environmentally benign and renewable, transition metals oxide NPs such as CuO, Co3O4, and NiO using solid‐state thermal degradation of their coordinated precursors. The NPs are subjected to analysis employing a range of techniques, such as X‐ray powder diffraction (XRD), X‐ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), N2 sorpometry (BET), and UV–vis). The photocatalytic activities of the synthesized NPs were assessed using photodegradation of organic contaminants in wastewater.
Lightweight polyethylene terephthalate bead foams with good interfacial adhesion and thermal insulation performance fabricated by supercritical carbon dioxide secondary foaming strategy
Authors: Yang Senlin , Ma Wenjie , Ren Xiangfeng , Han Dong , Wang Zengzeng , Xu Dawei 
Published: December 2023

AbstractThis paper reported the novel supercritical carbon dioxide (scCO2) secondary foaming and molding strategy to prepare the thermal‐insulation polyethylene terephthalate (PET) bead foam part with good interfacial adhesion and high expansion ratio. The incorporation of porous structure could effectively enhance the blowing agent solubility and fabricate the system viscosity difference, which contributed to the expansion and further welding of the expanded PET beads. Under the optimum foaming conditions, PET bead foam parts with excellent comprehensive performance were successfully prepared by molding method in the confined space via scCO2 secondary foaming, and the corresponding welding mechanism of PET beads was further investigated. The obtained foam parts possessed good tensile and compressive properties, reaching 1.03 and 1.27 MPa (at 20% strain) respectively. Besides, the foam part exhibited the low thermal conductivity of 0.060 Wm−1 K−1, which confirmed the improvement of thermal insulation performance owing to the high expansion ratio.
Listen to this: Why consumer behavior researchers should care about listening
Authors: Itzchakov Guy , Wheeler S. Christian 
Published: December 2023

AbstractConsumers' decisions are intricately interwoven with their conversations. Whether it is an animated discussion with a trusted friend extolling the virtues of a newly acquired car (i.e., Word‐of‐Mouth), an engaging dialogue with a salesperson, or a clarifying call to a help center seeking guidance on a just‐purchased smartwatch, every exchange hinges on a pivotal factor: the quality of listening. Listening quality shapes perceptions, affects social influence, drives behavioral intentions, and, ultimately, determines purchase and post‐purchase outcomes. Yet, despite its importance to these consumer behavior outcomes, listening has received scant attention in consumer psychology. In this paper, we review the effects of listening on consumer behavior‐relevant outcomes and unpack the components of quality listening to reveal their independent mechanisms. We also point to new frontiers in listening research beyond the in‐person, dyadic interactions that have been the primary focus of listening research to date. By doing this, we elucidate how listening and consumer behavior are connected and encourage more research on listening in consumer psychology.
In Situ Spectroscopic Study of CO2 Capture and Methanation over Ni−Ca Based Dual Functional Materials
Authors: Miyazaki Shinta , Chen Duotian , Jiacheng Bao , Toyao Takashi , Kanda Yasuharu , Shimizu Ken‐ichi 
Published: December 2023

AbstractCarbon dioxide capture and reduction (CCR) to CH4 using dual‐functional materials (DFMs) have recently attracted significant attention as a promising strategy for carbon capture and utilization. In this study, we investigate the mechanism of CCR to CH4 over Al2O3‐supported Ni−Ca DFMs (Ni−Ca/Al2O3) under cyclic feeds of model combustion exhaust (2.5 % CO2+0 or 10 % O2/N2) and H2 at 500 °C. Various spectroscopic analyses, including time‐resolved in situ X‐ray diffraction and X‐ray absorption spectroscopy, were conducted during CO2 capture and the subsequent H2‐reduction steps. Based on these analyses, we propose a mechanism of CCR to CH4 over Ni−Ca based DFMs. During the CO2 capture step, the Ni0 species underwent complete oxidation in the presence of O2 to yield NiO. Subsequently, CO2 was captured through the interaction between the CaO surface and CO2, resulting in the formation of CaCO3 layers on the CaO particles. When the gas flow was switched to H2, NiO was partially to provide Ni0 sites, which acted as active sites for H2‐reduction of the adjacent CaCO3 layers to yield CaO and gas‐phase products, CH4 and H2O.
Dipyridyl‐Fused Quinoxalineimide (DPQI): A Strong Electron‐Withdrawing Building Block for n‐Type Polymer Semiconductors
Authors: Li Mingwei , Yang Wanli , Cheng Rong , Liu Xuantong , Zhang Zihan , Tian Xiaowen , Shi Yongqiang 
Published: December 2023

AbstractExploration of new electron‐withdrawing building blocks plays a key role in the development of n‐type organic semiconductors. Herein, a strong electron‐withdrawing building block, dipyridyl‐fused quinoxalineimide (DPQI), was successfully designed and synthesized. Single‐crystal structure reveals that DPQI molecule possesses a completely planar backbone, which is beneficial for charge transport. For comparison, dibenzo‐fused quinoxalineimide (DBQI) was also synthesized. The frontier molecular orbital (FMO) energy levels downshift with the incorporation of nitrogen atoms onto the π‐conjugated backbone of quinoxalineimide. Two acceptor‐acceptor (or all‐acceptor) polymers P(BTI‐DBQI) and P(BTI‐DPQI) based on DBQI and DPQI were synthesized, respectively. Two polymers exhibit deep lowest‐unoccupied molecular orbital (LUMO) levels (~−3.5 eV). Additionally, P(BTI‐DPQI) exhibits unipolar n‐type charge transport with μe of 1.4×10−4 cm2 V−1 s−1 in the organic field‐effect transistors (OFET), which render them highly attractive for developing n‐type semiconductors device. This work demonstrates that DPQI is a promising building block for constructing n‐type polymer semiconductors.
Tuning Chemoenzymatic Pd/Laccase Conformation Toward Optimized Heterogeneous Aerobic Oxidation
Authors: Yang Fangfang , Rousselot Pailley Pierre , Backov Rénal , Courvoisier‐Dezord Elise , Amouric Agnès , Tron Thierry , Mekmouche Yasmina 
Published: December 2023

AbstractHeterogeneous chemoenzymatic catalysts differing in their spatial organization and relative orientation of their enzymatic laccase and Pd units confined into macrocellular silica foams were tested on veratryl alcohol oxidation. When operating under continuous flow, we show that the catalytic efficiency of hybrids is significantly enhanced when the Pd(II) complex is combined with a laccase exhibiting a surface located lysine next to the T1 oxidation site of the enzyme.
A case of pregnant patient with stenotic bicuspid aortic valve
Authors: Lewek Joanna , Maciejewski Marek , Banach Maciej , Bielecka‐Dąbrowa Agata Magdalena 
Published: December 2023

Key Clinical MessageAsymptomatic severe aortic stenosis (AS) during pregnancy remains challenging; however, the postponement of surgery with the possibility of valvuloplasty as a bridge therapy seems reasonable. Our case showed that despite physiological changes during pregnancy, the aortic valve defect did not worsen, which allowed us to avoid dilemmas related to anticoagulation on artificial valve.AbstractA 31‐year‐old woman, with a bicuspid aortic aorta, post‐aortic valvulotomy, was listed for cardiac surgery because of severe aortic stenosis. However, the operation was postponed due to procreation plans. During the pregnancy and delivery, we did not observe neither deterioration of symptoms nor changes of echocardiographic parameters. Subsequent monthly echocardiographic studies did not reveal a significant increase of peak and mean aortic gradient.Presented case reports showed that despite physiological changes associated with pregnancy, the aortic valve defect did not worsen, which allowed to avoid dilemmas related to anticoagulation on artificial valves.
To Be or Not To Be… Cooperative? Trimetallic Catalysts for the Ring‐Opening Polymerisation of Cyclic Esters
Authors: Lowy Phoebe A. , Abdul Rahman Maisarah , Nichol Gary S. , Morrison Carole A. , Garden Jennifer A. 
Published: December 2023

AbstractMultimetallic catalysts have emerged as a promising route to enhance catalyst performance in cyclic ester ring‐opening polymerisation (ROP), as these complexes can outperform the monometallic analogues in terms of reactivity and/or polymerisation control. Such enhancements are often attributed to “multimetallic cooperativity”, yet the origins of this cooperativity often remain unclear. Here, we report the synthesis and characterisation of two trimetallic Al‐salen complexes (L1(AlMe)3 and L1(AlEt)3), containing three Al‐salen subunits in close proximity, and their monometallic analogues (L2(AlMe) and L2(AlEt)). These complexes have been applied as catalysts for cyclic ester ROP under a range of conditions, to probe their potential for cooperative behaviour. Trimetallic L1(AlMe)3 and L1(AlEt)3 both display high activities in rac‐lactide ROP, giving kobs values of up to 11×10−3 min−1. Yet careful benchmarking against the monometallic complexes reveals that whether these systems display multimetallic cooperativity or not depends upon the reaction conditions. Detailed kinetic and spectroscopic studies into the origins of cooperativity revealed that the neighbouring metals play a key role in the initiation step, rather than propagation. Overall, these studies highlight the importance of understanding the reaction conditions in order to accurately define whether a catalyst displays multimetallic cooperativity.