bluuebunny/crossref_metadata_2025_split huggingface dataset:
Consumption of 100% Fruit Juice and Body Weight in Children and Adults
Authors: Nguyen Michelle , Jarvis Sarah E. , Chiavaroli Laura , Mejia Sonia Blanco , Zurbau Andreea , Khan Tauseef A. , Tobias Deirdre K. , Willett Walter C. , Hu Frank B. , Hanley Anthony J. , Birken Catherine S. , Sievenpiper John L. , Malik Vasanti S. 
Published: January 2024

ImportanceConcerns have been raised that frequent consumption of 100% fruit juice may promote weight gain. Current evidence on fruit juice and weight gain has yielded mixed findings from both observational studies and clinical trials.ObjectiveTo synthesize the available evidence on 100% fruit juice consumption and body weight in children and adults.Data SourcesMEDLINE, Embase, and Cochrane databases were searched through May 18, 2023.Study SelectionProspective cohort studies of at least 6 months and randomized clinical trials (RCTs) of at least 2 weeks assessing the association of 100% fruit juice with body weight change in children and adults were included. In the trials, fruit juices were compared with noncaloric controls.Data Extraction and SynthesisData were pooled using random-effects models and presented as β coefficients with 95% CIs for cohort studies and mean differences (MDs) with 95% CIs for RCTs.Main Outcomes and MeasuresChange in body mass index (BMI; calculated as weight in kilograms divided by height in meters squared) was assessed in children and change in body weight in adults.ResultsA total of 42 eligible studies were included in this analysis, including 17 among children (17 cohorts; 0 RCTs; 45 851 children; median [IQR] age, 8 [1-15] years) and 25 among adults (6 cohorts; 19 RCTs; 268 095 adults; median [IQR] age among cohort studies, 48 [41-61] years; median [IQR] age among RCTs, 42 [25-59]). Among cohort studies in children, each additional serving per day of 100% fruit juice was associated with a 0.03 (95% CI, 0.01-0.05) higher BMI change. Among cohort studies in adults, studies that did not adjust for energy showed greater body weight gain (0.21 kg; 95% CI, 0.15-0.27 kg) than studies that did adjust for energy intake (−0.08 kg; 95% CI, −0.11 to −0.05 kg; P for meta-regression &amp;lt;.001). RCTs in adults found no significant association of assignment to 100% fruit juice with body weight but the CI was wide (MD, −0.53 kg; 95% CI, −1.55 to 0.48 kg).Conclusion and RelevanceBased on the available evidence from prospective cohort studies, in this systematic review and meta-analysis, 1 serving per day of 100% fruit juice was associated with BMI gain among children. Findings in adults found a significant association among studies unadjusted for total energy, suggesting potential mediation by calories. Further trials of 100% fruit juice and body weight are desirable. Our findings support guidance to limit consumption of fruit juice to prevent intake of excess calories and weight gain.
Review of fault models for reproducing and predicting strong ground motions and permanent displacements—findings in the 2016 Kumamoto earthquake
Authors: Dan Kazuo 
Published: January 2024

AbstractFor accurate evaluation of the impact of earthquakes to structures in the vicinity of the earthquake faults, it has been required to develop appropriate calculation methods for short‐ and long‐period ground motions and permanent displacements. The 2016 Kumamoto, Japan, earthquake provided these kinds of records, and several research papers have been published to propose methods for reproducing or predicting them. I reviewed these papers and summarized probable methods for evaluating fault parameters for broadband‐period ground motions in areas very close to the faults.
Overcoming biodiversity blindness: Secondary data in primary citizen science observations
Authors: Pernat Nadja , Canavan Susan , Golivets Marina , Hillaert Jasmijn , Itescu Yuval , Jarić Ivan , Mann Hjalte M. R. , Pipek Pavel , Preda Cristina , Richardson David M. , Teixeira Heliana , Vaz Ana Sofia , Groom Quentin 
Published: January 2024

Abstract

In the face of the global biodiversity crisis, collecting comprehensive data and making the best use of existing data are becoming increasingly important to understand patterns and drivers of environmental and biological phenomena at different scales.

Here we address the concept of secondary data, which refers to additional information unintentionally captured in species records, especially in multimedia‐based citizen science reports. We argue that secondary data can provide a wealth of ecologically relevant information, the utilisation of which can enhance our understanding of traits and interactions among individual organisms, populations and biodiversity dynamics in general.

We explore the possibilities offered by secondary data and describe their main types and sources. An overview of research in this field provides a synthesis of the results already achieved using secondary data and different approaches to information extraction.

Finally, we discuss challenges to the widespread use of secondary data, such as biases, licensing issues, use of metadata and lack of awareness of this trove of data due to a missing common terminology, as well as possible solutions to overcome these barriers.

Although the exploration and use of secondary data is only emerging, the many opportunities identified show how these data can enrich biodiversity research and monitoring.
Toward High‐Performance All‐Solid‐State Thin Film FeOxSy/LiPON/Li Microbatteries via Dual‐Interface Modification
Authors: He Yan , Xia Qiuying , Liu Wei , Wu Chuanzhi , Wang Jinshi , Cai Yu , Guo Yifei , Zan Feng , Xu Jing , Xia Hui 
Published: January 2024

AbstractFeaturing high theoretical capacity, low cost, and low preparation temperature, Li‐free cathodes are considered promising for all‐solid‐state thin‐film lithium microbatteries (TFBs). In this work, a Li‐free cathode of amorphous FeOxSy film is prepared, followed by the fabrication and investigation of FeOxSy/LiPON/Li TFBs. It is found that the structural degradation at both the LiPON/Li and FeOxSy/LiPON interfaces results in a rapid capacity loss for the TFB during electrochemical cycling. To achieve both high rate capability and long cycle life for the TFB, a dual‐interface modification approach using amorphous Al2O3 as an interlayer is proposed. During the TFB cycling, the Al2O3 interlayer not only enables robust LiPON/Li contact by preventing the formation of Li voids but also blocks the diffusion of Fe element from FeOxSy to LiPON electrolyte, effectively suppressing the interfacial resistance growth. Consequently, the dual‐interface modified TFB achieves greatly improved rate capability (194.3 mAh g−1 at 5 A g−1) and cycle performance (71% capacity retention after 800 cycles), which are superior to the pristine TFB and single‐interface modified TFB. This work advances the fundamental understanding of the failure mechanisms at the solid‐solid electrode/electrolyte interfaces, offering a feasible interfacial modulation strategy to develop advanced all‐solid‐state lithium batteries.
Photoacoustic‐Imaging‐Guided Photothermal Regulation of Calcium Influx for Enhanced Immunogenic Cell Death
Authors: Wang Mengxin , Xue Fengfeng , An Lu , Wu Dan , Sha Shuang , Huang Gang , Tian Qiwei 
Published: January 2024

AbstractImmunogenic cell death (ICD) induced by calcium ion (Ca2+) overload has attracted significant attention owing to its ability to activate the immune system and generate durable antitumor immune responses. However, the slow release of Ca2+ by commonly used nanomodulators provides tumor cells with the opportunity to efficiently eliminate excess Ca2+ through ion channels, thus diminishing the therapeutic efficacy. Consequently, it is crucial to explore strategies for rapid Ca2+ release. To address this issue, a glutathione‐triggered Ca(IO3)2@starch‐based Ca2+ nanobomb is presented. This nanobomb not only enables accurate and efficient Ca2+ delivery to the tumor site but also exploits glutathione‐triggered photoacoustic (PA) imaging‐guided photothermal precise control of TRPV1 ion channel activation for enhancing the Ca2+ influx. Both in vitro and in vivo results confirm that the photothermally regulated Ca2+ influx based on this Ca2+ nanobomb effectively promotes ICD and stimulates immune infiltration in tumor tissues, ultimately leading to the effective inhibition of tumor growth and metastasis. The developed Ca2+ nanobomb presents a potential strategy to enhance ICD based on Ca2+ overload, thus addressing the challenges associated with precise and timely regulation of Ca2+ influx and offering prospects for improved antitumor immunotherapy.
Synthesis of Metalloborophene Nanoribbons on Cu(110)
Authors: Weng Xiao‐Ji , Zhu Yi , Xu Ying , Bai Jie , Zhang Zhuhua , Xu Bo , Zhou Xiang‐Feng , Tian Yongjun 
Published: January 2024

AbstractMetalloborophene, characterized by the presence of metal‐centered boron wheels denoted as M©Bn, has garnered considerable attention in recent years due to its versatile properties and potential applications in fields such as electronics, spintronics, and catalysis. However, the experimental verification of metalloborophene is challenging, mainly due to the unconventional 2D boron networks. In this study, scanning tunneling microscopy, X‐ray photoelectron spectroscopy, low energy electron diffraction, and first‐principles calculations are employed to unveil Cu©B8 metalloborophene nanoribbons formed via spontaneous alloying after the deposition of boron on a heated Cu(110) substrate under ultrahigh vacuum condition. The thermodynamically preferred precursor, the anchoring of boron network to metal atoms, and anisotropic lattice mismatch are identified as pivotal factors in the formation of these metalloborophene nanoribbons. This discovery expands the repertoire of 2D materials and offers a potential pathway for the synthesis of other metalloborophenes.
Enhanced Al‐Storage Performance by Electronic Properties Optimization and Structural Customization in MOF‐Derived Heterostructure
Authors: Kang Rongkai , Du Yiqun , Zhang Dongmei , Sun Chenyi , Wang Han , Zhang Xingchang , Wan Jiaqi , Chen Guowen , Zhang Jianxin 
Published: January 2024

AbstractChalcogenide cathodes with multi‐electron transfer characteristics are indispensable to aluminum‐ion batteries (AIBs). Nevertheless, their grievous capacity degradation and sluggish reaction kinetics remain fundamental challenges for the practical application. Herein, a Cu2S/Ni3S2 multiphase structure within the metal‐organic frame (MOF) derived carbon decoration layer (CNS@MC) is constructed to elevate the intrinsic electronic properties of chalcogenide cathode and realize high‐performance AIBs. The existence of outer carbon layer and strong orbital interaction at inner heterointerfaces eliminates the bandgap and arises more electrons at Fermi level, efficiently reducing the energy barrier for electron transfer and achieving high reactivity within cathodes. The CNS@MC also presents a strong electronic interaction with active solvent groups, which is beneficial to capture Al3+ and facilitate the three‐electron charge‐storage reactions. Experimental results demonstrate that the tailored CNS@MC cathode possesses superior redox kinetics due to the sufficient surface area and rapid Al‐ion diffusion during cycling. Meanwhile, the robust CNS@MC delivers ultra‐high electrochemical stability (131.1 mAh g−1 over 3500 cycles) with high coulombic efficiency and outstanding rate performance. This work offers new opportunities for optimizing the intrinsic properties of the chalcogenide electrodes based on MOF derivatives and heterostructure, providing novel thoughts for designing high‐performance AIBs.
General Scalable Synthesis of Mesoporous Metal Oxide Nanosheets with High Crystallinity for Ultralong‐Life Li–S Batteries
Authors: Wang Biao , Tang Jiayi , Jia Suyue , Xing Zhanqi , Chen Shaowei , Deng Yu , Meng Xiangkang , Tang Shaochun 
Published: January 2024

AbstractMesoporous metal oxide nanosheets (MMONs) are demonstrated great promise for various catalytic applications such as water splitting, CO2 reduction, and metal–sulfur batteries. However, limited by the conventional high‐temperature synthetic routes, the prepared MMONs expose only a small portion of the effective catalytic sites, which greatly restricts their electrocatalytic activity. Herein, a facile and general glycine‐assisted strategy is developed to synthesize a series of MMONs with high crystallinity and remarkable porosity. Impressively, single‐phase perovskite type MMONs containing up to ten metal cations can be synthesized easily using this method without any further purification step. As a proof of concept, the Li–S cell with mesoporous LaFe0.4Co0.2Ni0.2Cu0.2O3 nanosheets as catalyst achieves superior ultralong cycling life over 1500 cycles at 2 C with only 0.041% capacity decay per cycle and a high areal capacity reaching 6.0 mAh cm−2 at a low electrolyte/sulfur ratio of 5.9 µL mg−1. The improved performance is attributed to abundant active sites and synergistic contribution of multicomponent. This work paves a new avenue for the general synthesis of advanced MMONs and will inspire the practical applications in different fields.
Physically and Chemically Stable Molybdenum‐Based Composite Electrodes for p–i–n Perovskite Solar Cells
Authors: Fan Rundong , Sun Wei , Li Congmeng , Chen Yihua , Xie Haipeng , Gao Yongli , Ma Yue , Peng Zongyang , Huang Zijian , Yin Ruiyang , Pei Fengtao , Zhou Wentao , Wu Yuetong , Liu Huifen , Li Kailin , Song Tinglu , Zou Dechun , Zai Huachao , Li Hui , Chen Qi , Wang Qian , Zhou Huanping 
Published: January 2024

AbstractMetal halide perovskite solar cells (PSCs) have garnered much attention in recent years. Despite the remarkable advancements in PSCs utilizing traditional metal electrodes, challenges such as stability concerns and elevated costs have necessitated the exploration of innovative electrode designs to facilitate industrial commercialization. Herein, a physically and chemically stable molybdenum (Mo) electrode is developed to fundamentally tackle the instability factors introduced by electrodes. The combined spatially resolved element analyses and theoretical study demonstrate the high diffusion barrier of Mo ions within the device. Structural and morphology characterization also reveals the negligible plastic deformation and halide‐metal reaction during aging when Mo is in contact with perovskite (PVSK). The electrode/underlayer junction is further stabilized by a thin seed layer of titanium (Ti) to improve Mo film's uniformity and adhesion. Based on a corresponding p–i–n PSCs (ITO/PTAA/PVSK/C60/SnO2/ITO/Ti/Mo), the champion sample could deliver an efficiency of 22.25%, which is among the highest value for PSCs based on Mo electrodes. Meanwhile, the device shows negligible performance decay after 2000 h operation, and retains 91% of the initial value after 1300 h at 50–60 °C. In summary, the multilayer Mo electrode opens an effective avenue to all‐round stable electrode design in high‐performance PSCs.
Heterojunction‐Induced Rapid Transformation of Ni3+/Ni2+ Sites which Mediates Urea Oxidation for Energy‐Efficient Hydrogen Production
Authors: Guo Peng , Cao Shoufu , Huang Wenjing , Lu Xiaoqing , Chen Weizhe , Zhang Youzi , Wang Yijin , Xin Xu , Zou Ruiqing , Liu Sibi , Li Xuanhua 
Published: January 2024

AbstractWater electrolysis is an environmentally‐friendly strategy for hydrogen production but suffers from significant energy consumption. Substituting urea oxidation reaction (UOR) with lower theoretical voltage for water oxidation reaction adopting nickel‐based electrocatalysts engenders reduced energy consumption for hydrogen production. The main obstacle remains strong interaction between accumulated Ni3+ and *COO in the conventional Ni3+‐catalyzing pathway. Herein, a novel Ni3+/Ni2+ mediated pathway for UOR via constructing a heterojunction of nickel metaphosphate and nickel telluride (Ni2P4O12/NiTe), which efficiently lowers the energy barrier of UOR and avoids the accumulation of Ni3+ and excessive adsorption of *COO on the electrocatalysts, is developed. As a result, Ni2P4O12/NiTe demonstrates an exceptionally low potential of 1.313 V to achieve a current density of 10 mA cm−2 toward efficient urea oxidation reaction while simultaneously showcases an overpotential of merely 24 mV at 10 mA cm−2 for hydrogen evolution reaction. Constructing urea electrolysis electrolyzer using Ni2P4O12/NiTe at both sides attains 100 mA cm−2 at a low cell voltage of 1.475 V along with excellent stability over 500 h accompanied with nearly 100% Faradic efficiency.
Simultaneous Enhancement of Thermal Insulation and Impact Resistance in Transparent Bulk Composites
Authors: Zhang Xiao , Zhou Jianyu , Wu Kaijin , Zhang Shuaishuai , Xie Lili , Gong Xinglong , He Linghui , Ni Yong 
Published: January 2024

AbstractTransparent bulk glass is highly demanded in devices and components of daily life to transmit light and protect against external temperature and mechanical hazards. However, the application of glass is impeded by its poor functional performance, especially in terms of thermal isolation and impact resistance. Here, a glass composite integrating the nacre‐inspired structure and shear stiffening gel (SSG) material is proposed. Benefiting from the combination of these two elements, this nacre‐inspired SSG/glass composite (NSG) exhibits superior thermal insulation and impact resistance while maintaining transparency simultaneously. Specifically, the low thermal conductivity of the SSG combined with the anisotropic heat transfer capability of the nacre‐inspired structure enhances the out‐of‐plane thermal insulation of NSG. The deformations over large volumes in nacre‐inspired facesheets promote the deformation region of the SSG core, synergistic effect of tablet sliding mechanism in nacre‐inspired structure and strain‐rate enhancement in SSG material cause the superior impact resistance of overall panels in a wide range of impact velocities. NSG demonstrates outstanding properties such as transparency, light weight, impact resistance, and thermal insulation, which are major concerns for the application in engineering fields. In conclusion, this bioinspired SSG/glass composite opens new avenues to achieve comprehensive performance improvements for transparent structural materials.
MBene with Redox‐Active Terminal Groups for an Energy‐Dense Cascade Aqueous Battery
Authors: Zhang Zishuai , Li Yi , Mo Funian , Wang Jiaqi , Ling Wei , Yu Miao , Huang Yan 
Published: January 2024

AbstractTwo‐dimensional (2D) transition metal borides (MBenes), new members of the 2D materials family, hold great promise for use in the electrocatalytic and energy storage fields because of their high specific area, high chemical activity, and fast charge carrier mobility. Although various types of MBenes are reported, layered MBenes featuring redox‐active terminal groups for high energy output are not yet produced. A facile and energy‐efficient method for synthesizing MBenes equipped with redox‐active terminal groups for cascade Zn||I2 batteries is presented. Layered MBenes have ordered metal vacancies and ─Br terminal groups, enabling the sequential reactions of I−/I0 and Br−/Br0. The I2‐hosting MBene‐Br cathode results in a specific energy as high as 485.8 Wh kg−1 at 899.7 W kg−1 and a specific power as high as 6007.7 W kg−1 at 180.2 Wh kg−1, far exceeding the best records for Zn||I2 batteries. The results of this study demonstrate that the challenges of MBene synthesis can be overcome and reveal an efficient path for producing high‐performance redox‐active electrode materials for energy‐dense cascade aqueous batteries.
Synthesis of High Refractive Index Polymer Thin Films for Soft, Flexible Optics Through Halomethane Quaternization of Poly(4‐Vinylpyridine)
Authors: Huo Ni , Rivkin Jeremy , Jia Ruobin , Zhao Yineng , Tenhaeff Wyatt E. 
Published: January 2024

AbstractApplications in soft, flexible optical, and optoelectronic applications demand polymer thin film coatings that can accommodate substantial physical deformations. The preparation of high refractive index polymers (HRIPs) through the quaternization of poly(4‐vinylpyridine) (P4VP) thin films with (di)halomethanes is presented. P4VP thin films are prepared by initiated chemical vapor deposition (iCVD) and then quaternized through exposure to saturated vapors of iodomethane (CH3I), dibromomethane (CH2Br2), and diiodomethane (CH2I2), resulting in refractive indices (RI) as high as 1.67, 1.71, and 2.07, respectively (at 632.8 nm). Fourier‐transform infrared (FTIR) spectroscopy and X‐ray photoelectron spectroscopy (XPS) confirmed the quaternization of pyridine pendant groups on the polymer chain to n‐methylpyridinium with primarily an iodide or bromide counterion, though a minor fraction of polyiodides are also detected. Additionally, these films demonstrate superior thermal stability, retaining their refractive index and thickness after thermal excursions to 200 °C. The halogenated P4VP films exhibit superior mechanical flexibility relative to conventional inorganic coatings (Al2O3 and Ta2O5) and do not fracture at uniaxial tensile strains as high as 10%. This new material chemistry and fabrication approach method may enable advanced optical designs and functionality in a wide range of substrates and device architectures.
Silk‐Based Functional Inks with Color‐Tunable Light Upconversion for Printing on Arbitrary Surfaces
Authors: Ahn Junyong , Kim Taehoon , Omenetto Fiorenzo G. , Park Junyong 
Published: January 2024

AbstractA biocompatible and versatile silk‐based functional ink with hydrophilic upconversion nanoparticles (UCNPs) that can be printed or painted on arbitrary substrates, including biological surfaces is demonstrated. Hydrophilic UCNPs, ready to be dispersed in aqueous silk fibroin solution, are synthesized in large quantities via facile hydrothermal synthesis using citric acid. Based on a systematic study of dopant control to achieve robust red emission from citrate‐capped UCNPs, three primary colors are obtained, which serve as the basis for the expansion of the color palette. The synthesized UCNPs are homogeneously dispersed in regenerated silk fibroin solutions derived from Bombyx mori cocoons to produce water‐based functional inks. Cyan, magenta, and yellow (CMY) inks are created by combining red, green, and blue (RGB) inks. Demonstrator devices, where a variety of colorful patterns and codes are revealed only under near‐infrared irradiation, are realized through stencil printing or brush painting on flexible polymer films, fruit, leaves, silkworm cocoons, and pig skin. The patterns and codes are highly heat resistant (≈230 °C) and can be easily washed off with water after use. The printable/paintable inks and functions proposed here will provide new opportunities for applications where sustainability, biocompatibility, and intentional luminescence are simultaneously required.