bluuebunny/crossref_metadata_2025_split huggingface dataset:
3‐Bromo‐4‐Aminotoluene
Authors: Johnson J. R. , Sandborn L. T. 
Published: November 2003

Abstract

3‐Bromo‐4‐aminotoluene

intermediate: 3‐bromo‐4‐acetaminotoluene

intermediate: hydrochloride of 3‐bromo‐4‐aminotoluene

product: 3‐bromo‐4‐aminotoluene
3‐Methylpentanoic Acid
Authors: Vliet E. B. , Marvel C. S. , Hsueh C. M. 
Published: November 2003

Abstract

3‐Methylpentanoic acid

reactant: 200 g. (0.92 mole) of ethyl
sec.
‐butylmalonate

product: 3‐methylpentanoic acid

product:
n
‐caproic acid
Methyl Isopropyl Carbinol
Authors: Drake Nathan L. , Cooke Giles B. 
Published: November 2003

AbstractMethyl isopropyl carbinolreactant: 600 g. (4.9 moles) of isopropyl bromidereactant: 200 g. (4.5 moles) of acetaldehydeproduct: methyl isopropyl carbinol
Isobutyl Bromide
Authors: Noller C. R. , Dinsmore R. 
Published: November 2003

Abstract

Isobutyl bromide

reactant: 518 g. (643 cc., 7 moles) of dry isobutyl alcohol

reactant: 695 g. (244 cc., 2.56 moles) of phosphorus tribromide

product: isobutyl bromide

product:
sec.
‐butyl

product:
n
‐propyl

product: isopropyl
2,6‐Dimethylpyridine
Authors: Singer Alvin , McElvain S. M. 
Published: November 2003

Abstract2,6‐Dimethylpyridineintermediate: 1,4‐dihydro‐3,5‐dicarbethoxy‐2,6‐dimethylpyridineintermediate: 3,5‐dicarbethoxy‐2,6‐dimethylpyridineproduct: 2,6‐Dimethylpyridine
2‐Hydroxy‐3,5‐diiodobenzoic Acid
Authors: Woollett G. H. , Johnson W. W. 
Published: November 2003

Abstract2‐Hydroxy‐3,5‐diiodobenzoic acidreactant: Twenty‐five grams (0.18 mole) of salicylic acidreactant: 62 g. (0.38 mole) of iodine monochlorideproduct: diiodosalicylic acidproduct: 4‐hydroxy‐3,5‐diiodobenzoic acid
p‐Nitrobenzyl Bromide
Authors: Coleman G. H. , Honeywell G. E. 
Published: November 2003

Abstractp‐Nitrobenzyl bromidereactant: 300 g. (2.2 moles) of technicalp‐nitrotoluenesolvent: 4 l. of hot ligroinproduct:p‐Nitrobenzyl bromide
p
‐Nitrobenzaldehyde
Authors: Lieberman S. V. , Connor Ralph 
Published: November 2003

Abstract

p
‐Nitrobenzaldehyde

reactant: 50 g. (0.36 mole) of
p
‐nitrotoluene

intermediate:
p
‐nitrobenzaldiacetate

product:
p
‐nitrobenzoic acid

product:
p
‐bromobenzaldehyde

intermediate:
p
‐bromobenzaldiacetate

product:
p
‐nitrobenzaldehyde
9‐Anthraldehyde; 2‐Ethoxy‐1‐Naphthaldehyde
Authors: Fieser (A) L. F. , Hartwell J. L. , Jones J. E. , Wood (B) J. H. , Bost R. W. 
Published: November 2003

Abstract

9‐anthraldehyde; 2‐ethoxy‐1‐naphthaldehyde

product: 9‐Anthraldehyde

reactant: 22.5 g. (0.13 mole) of anthracene

product: 2‐Ethoxy‐1‐naphthaldehyde
1,1‐Cyclobutanedicarboxylic Acid and Cyclobutanecarboxylic Acid
Authors: Heisig G. B. , Stodola F. H. 
Published: November 2003

Abstract

1,1‐Cyclobutanedicarboxylic acid and cyclobutanecarboxylic acid

product: 1,1‐cyclobutanedicarboxylic acid

product: cyclobutanecarboxylic acid

reactant: ethyl pentane‐1,1,5,5‐tetracarboxylate
β‐Phenylethylamine
Authors: Robinson John C. , Snyder H. R. 
Published: November 2003

Abstractβ‐Phenylethylamineproduct: β‐phenylethylaminebyproduct: Di‐(β‐phenylethyl)‐amineproduct:n‐hexylamineproduct: 3,4‐dimethoxyphenylethylamineproduct:o‐methylphenylethylamineproduct:m‐methylphenylethylamineproduct:p‐methylphenylethylamineproduct: 3,4‐methylenedioxyphenylethylamine
Tetrahydrofurfuryl Bromide
Authors: Smith L. H. 
Published: November 2003

Abstract

Tetrahydrofurfuryl bromide

reactant: 96 g. (56.5 ml., 0.36 mole) of redistilled phosphorus tribromide

reactant: 102 g. (1 mole) of redistilled tetrahydrofurfuryl alcohol

product: tetrahydrofurfuryl bromide
4‐Amino‐4H‐1,2,4‐Triazole
Authors: Allen C. F. H. , Bell Alan 
Published: November 2003

Abstract4‐Amino‐4H‐1,2,4‐triazolereactant: 148 g. (2 moles) of ethyl formateproduct: 4‐amino‐1,2,4‐triazole hydrochlorideproduct: 4‐Amino‐1,2,4‐triazole
3,12‐Diacetoxy‐
bisnor
‐Cholanyldiphenylethylene
Authors: Riegel Byron , Moffett R. B. , McIntosh A. V. 
Published: November 2003

Abstract

3,12‐Diacetoxy‐
bisnor
‐cholanyldiphenylethylene

intermediate: 102 g. (0.25 mole) of methyl desoxycholate in 700 ml. of dry benzene

product: 3,12‐diacetoxy‐
bisnor
‐cholanyldiphenylethylene
2,6‐Dichloroaniline and 2,6‐Dibromoaniline
Authors: Seikel Margaret K. 
Published: November 2003

Abstract2,6‐Dichloroaniline and 2,6‐dibromoanilineintermediate: 3,5‐dichlorosulfanilamideproduct: 2,6‐dichloroanilineintermediate: 3,5‐dibromosulfanilamideproduct: 2,6‐dibromoaniline
β‐
d
‐Glucose‐2,3,4,6‐Tetraacetate
Authors: McCloskey Chester M. , Coleman George H. 
Published: November 2003

Abstract

β‐
d
‐Glucose‐2,3,4,6‐tetraacetate

reactant: 82.2 g. (0.2 mole) of acetobromoglucose

product: β‐
d
‐Glucose‐2,3,4,6‐tetraacetate (2,3,4,6‐tetraacetyl‐β‐
d
‐glucose)
2‐Nitro‐4‐Methoxyaniline
Authors: Fanta Paul E. , Tarbell D. S. 
Published: November 2003

Abstract

2‐Nitro‐4‐methoxyaniline

intermediate: 2‐nitro‐4‐methoxyacetanilide

product: 2‐Nitro‐4‐methoxyaniline
Di‐(
p
‐Chlorophenyl)Acetic Acid
Authors: Grummitt Oliver , Buck Allen , Egan Richard 
Published: November 2003

Abstract

Di‐(
p
‐chlorophenyl)acetic acid

solvent: 400 ml. of diethylene glycol

reactant: 49.5 g. (0.14 mole) of 1,1‐di‐(
p
‐chlorophenyl)‐2,2,2‐trichloroethane

product: di‐(
p
‐chlorophenyl) acetic acid

byproduct: di‐(
p
‐chlorophenyl) methane
Lepidine
Authors: Neumann Fred W. , Sommer Nolan B. , Kaslow C. E. , Shriner R. L. 
Published: November 2003

Abstract

Lepidine

reactant: 20 g. (0.11 mole) of pure 2‐chlorolepidine

catalyst: 3 g. of palladium on carbon

product: 6‐Methyllepidine

product: 8‐Methyllepidine

product: 5,8‐Dimethyllepidine

product: 6,8‐Dimethyllepidine

product: 6‐Methoxylepidine monohydrate

product: 5,8‐Dimethoxylepidine

product: 2‐Methyl‐6‐methoxyquinoline

product: Lepidine
3,5‐Dimethyl‐4‐Carbethoxy‐2‐Cyclohexen‐1‐One and 3,5‐Dimethyl‐2‐Cyclohexen‐1‐One
Authors: Horning E. C. , Denekas M. O. , Field R. E. 
Published: November 2003

Abstract

3,5‐Dimethyl‐4‐carbethoxy‐2‐cyclohexen‐1‐One and 3,5‐Dimethyl‐2‐Cyclohexen‐1‐One

product: 3,5‐dimethyl‐4‐carbethoxy‐2‐cyclohexen‐1‐one

product: 3,5‐dimethyl‐2‐cyclohexen‐1‐one
2,3‐Diphenylindone (2,3‐Diphenyl‐1‐Indenone)
Authors: Allen C. F. H. , Gates J. W. , VanAllan J. A. 
Published: November 2003

Abstract

2,3‐Diphenylindone (2,3‐diphenyl‐1‐indenone)

product: 2,3‐diphenylindone
2‐Hydroxycinchoninic Acid
Authors: Jacobs Thomas L. , Winstein S. , Linden Gustave B. , Robson Jean H. , Levy Edward F. , Seymour Dexter 
Published: November 2003

Abstract

2‐Hydroxycinchoninic acid

reactant: 600 g. (4.1 moles) of isatin

intermediate: N‐acetylisatin

product: 2‐Hydroxycinchoninic acid
m
‐Nitrobenzaldehyde Dimethylacetal
Authors: Icke Roland N. , Redemann C. Ernst , Wisegarver Burnett B. , Alles Gordon A. 
Published: November 2003

Abstract

m
‐Nitrobenzaldehyde dimethylacetal

product:
m
‐
Nitrobenzaldehyde dimethylacetal
.
1,2,5‐Trihydroxypentane
Authors: Grummitt Oliver , Stearns James A. , Arters A. A. 
Published: November 2003

Abstract

1,2,5‐Trihydroxypentane

reactant: 680 ml. (714 g., 7 moles) of redistilled tetrahydrofurfuryl alcohol

intermediate: 1,2,5‐triacetoxypentane

product: 1,2,5‐trihydroxypentane
n
‐Butylacetylene
Authors: Campbell Kenneth N. , Campbell Barbara K. 
Published: November 2003

Abstract

n
‐butylacetylene

product:
n
‐butylacetylene

product:
n
‐propylacetylene

product:
n
‐Amylacetylene

product: isoamylacetylene

product:
n
‐Hexylacetylene
N‐Methyl‐2,3‐Dimethoxybenzylamine
Authors: Balcom Don M. , Noller C. R. 
Published: November 2003

Abstract

N‐methyl‐2,3‐dimethoxybenzylamine

product: N‐methyl‐2,3‐dimethoxybenzylamine

reactant: 2,3‐dimethoxybenzaldehyde employed was a darkcolored product supplied by the Monsanto Chemical Company or Eastman Kodak Company
Arylureas:
p
‐Bromophenylurea
Authors: Kurzer Frederick 
Published: November 2003

Abstract

Arylureas:
p
‐bromophenylurea

product:
p
‐bromophenylurea

:
p
‐Tolylurea

:
m
‐Tolylurea

:
o
‐Tolylurea

: 1‐(4‐Biphenylyl)urea

: 1‐(2‐Biphenylyl)urea

:
p
‐Methoxyphenylurea

:
p
‐Ethoxyphenylurea

:
m
‐Ethoxyphenylurea

:
o
‐Ethoxyphenylurea

:
m
‐Bromophenylurea

:
o
‐Bromophenylurea

:
o
‐Chlorophenylurea
2‐Aminobenzophenone
Authors: Scheifele H. J. , DeTar D. F. 
Published: November 2003

Abstract

2‐Aminobenzophenone

intermediate:
p
‐toluenesulfonylanthranilic acid

product: 2‐aminobenzophenone

byproduct: Phenyl
p
‐tolyl sulfone

product: 4′‐Methyl‐2‐aminobenzophenone
o
‐Methylbenzyl Alcohol
Authors: Brasen W. R. , Hauser C. R. 
Published: November 2003

Abstract

o
‐Methylbenzyl alcohol

intermediate:
o‐Methylbenzyl acetate

intermediate: 2‐methylbenzylethyldimethylammonium bromide

product:
o‐Methylbenzyl alcohol

intermediate: 2,3‐dimethylbenzyl acetate

product: 2,3‐dimethylbenzyl alcohol
2‐Methylbenzyldimethylamine
Authors: Brasen W. R. , Hauser C. R. 
Published: November 2003

Abstract

2‐Methylbenzyldimethylamine

intermediate: benzyltrimethylammonium iodide

product:
2‐Methylbenzyldimethylamine

product: 2,3‐dimethylbenzyldimethylamine
Sodium β‐Styrenesulfonate and β‐Styrenesulfonyl Chloride
Authors: Rondestvedt Christian S. , Bordwell F. G. 
Published: November 2003

Abstract

Sodium β‐Styrenesulfonate and β‐Styrenesulfonyl Chloride

solvent: 800 ml. of ethylene chloride

reactant: dioxane

product: 95 + % pure sodium β‐styrenesulfonate

product: β‐styrenesulfonyl chloride

byproduct: 2,4‐diphenylbutane‐1,4‐sultone

byproduct: sodium 2‐phenyl‐2‐hydroxyethane‐1‐sulfonate
2‐Phenylcycloheptanone
Authors: Gutsche C. David , Johnson Herbert E. 
Published: November 2003

Abstract

2‐Phenylcycloheptanone

intermediate: 360 g. (2.0 moles) of ethyl N‐benzylcarbamate

intermediate: 415 g. (2.0 moles) of ethyl N‐nitroso‐N‐benzylcarbamate

product: 2‐phenylcycloheptanone

solvent: petroleum ether

byproduct: methyl benzyl ether

product: 2‐(
o
‐Methylphenyl)cycloheptanone

product: 2‐(
p
‐Methylphenyl)cycloheptanone

product: 2‐(
o
‐Methoxyphenyl)cycloheptanone

product: 2‐(
m
‐Methoxyphenyl)cycloheptanone

product: 2‐(
p
‐Methoxyphenyl)cycloheptanone
Diethyl Benzoylmalonate
Authors: Price John A. , Tarbell D. S. 
Published: November 2003

Abstract

Diethyl benzoylmalonate

reactant: 20.2 g. (0.2 mole) of triethylamine

reactant: 21.7 g. (0.2 mole) of ethyl chlorocarbonate

product: Diethyl benzoylmalonate
3,4‐Dinitro‐3‐Hexene
Authors: Bisgrove D. E. , Brown J. F. , Clapp L. B. 
Published: November 2003

Abstract

3,4‐Dinitro‐3‐hexene

reactant: 247 g. (205 ml., 2.0 moles) of 1‐chloro‐1‐nitropropane

product: 3,4‐dinitro‐3‐hexene

byproduct: potassium 1‐nitropropylnitronate

product: 2,3‐Dinitro‐2‐butene
3‐
n
‐Heptyl‐5‐cyanocytosine
Authors: Kehm Barbara B. , Whitehead Calvert W. 
Published: November 2003

Abstract

3‐
n
‐Heptyl‐5‐cyanocytosine

intermediate: N‐
n
‐heptylurea

intermediate: 3‐
n
‐heptylureidomethylenemalononitrile

product: 3‐
n
‐heptyl‐5‐cyanocytosine
6‐Ketohendecanedioic Acid
Authors: Durham Lois J. , McLeod Donald J. , Cason James 
Published: November 2003

Abstract

6‐Ketohendecanedioic acid

reactant: 89.3 g. (0.5 mole) of δ‐carbomethoxyvaleryl chloride

product: 6‐ketohendecanedioic acid

reactant: 100 g. (0.63 mole) of redistilled commercial methyl hydrogen adipate
trans
‐2‐Methyl‐2‐Dodecenoic Acid
Authors: Allen C. Freeman , Kalm Max J. 
Published: November 2003

Abstract

trans
‐2‐Methyl‐2‐dodecenoic acid

product: 2‐methyl‐2‐dodecenoic acid

solvent: Commercial hexane

product: 2‐methyl‐2‐eicosenoic acid

product: 2‐methyl‐2‐hexacosenoic acid

product: 2,4‐dimethyl‐2‐pentacosenoic acid
Indole‐3‐Aldehyde
Authors: James Philip N. , Snyder H. R. 
Published: November 2003

Abstract

Indole‐3‐aldehyde

reactant: 288 ml. (274 g., 3.74 moles) of freshly distilled dimethylformamide

catalyst: 86 ml. (144 g., 0.94 mole) of freshly distilled phosphorus oxychloride

reactant: 100 g. (0.85 mole) of indole

product: indole‐3‐aldehyde
Methylenecyclohexane and N,N‐Dimethylhydroxylamine Hydrochloride
Authors: Cope Arthur C. , Ciganek Engelbert 
Published: November 2003

Abstract

Methylenecyclohexane and N,N‐dimethylhydroxylamine hydrochloride

reactant: 49.4 g. (0.35 mole) of N,N‐dimethylcyclohexylmethylamine

product: methylenecyclohexane

product: N,N‐dimethylhydroxylamine hydrochloride
N,N‐Dimethylaminomethylferrocene Methiodide
Authors: Lednicer Daniel , Hauser Charles R. 
Published: November 2003

Abstract

N,N‐Dimethylaminomethylferrocene methiodide

reactant: 43.2 g. (0.422 mole) of bis(dimethylamino)‐methane

intermediate: dimethylaminomethylferrocene

product: N,N‐dimethylaminomethylferrocene methiodide
α,β‐Diphenylpropionic Acid
Authors: Hauser Charles R. , Dunnavant W. R. 
Published: November 2003

Abstract

α,β‐Diphenylpropionic acid

reactant: 14.2 g. (0.104 mole) of phenylacetic acid

reactant: 13.2 g. (0.104 mole) of benzyl chloride

product: α,β‐diphenylpropionic acid

solvent: 60 ml. of petroleum ether
N,N‐Diethyl‐1,2,2‐trichlorovinylamine
Authors: Speziale A. J. , Freeman R. C. 
Published: November 2003

Abstract

N,N‐diethyl‐1,2,2‐trichlorovinylamine

intermediate: N,N‐Diethyl‐2,2,2‐trichloroacetamide

product: N,N‐diethyl‐1,2,2‐trichlorovinylamine

byproduct: tri‐
n
‐butylphosphine oxide

byproduct: phosphine oxide
Phenacylamine Hydrochloride
Authors: Baumgarten Henry E. , Petersen James M. 
Published: November 2003

AbstractPhenacylamine Hydrochloridebyproduct: sodium chlorideproduct: phenacylamine hydrochlorideproduct: 2‐Aminocyclopentanoneproduct: 2‐Aminocyclohexanoneproduct: 3‐Amino‐2‐heptanoneproduct:p‐Bromophenacylamineproduct:p‐Chlorophenacylamineproduct:p‐Methoxyphenacylamineproduct:p‐Nitrophenacylamineproduct:p‐Methylphenacylamineproduct:p‐Phenylphenacylamineproduct: α‐Aminovalerophenoneproduct: 2‐Amino‐1‐tetraloneproduct: 2‐Amino‐4,4‐dimethyl‐1‐tetraloneproduct: Desylamine (2‐amino‐2‐phenylacetophenone)product: Phenacylamine
Adamantane
Authors: Schleyer Paul von R. , Donaldson M. M. , Nicholas R. D. , Cupas C. 
Published: November 2003

Abstract

Adamantane

reactant: 200 g. (1.51 moles) of purified dicyclopentadiene

intermediate:
endo
‐tetrahydrodicyclopentadiene

product: adamantane

solvent: 250 ml. of petroleum ether
2‐Cyano‐6‐Methylpyridine
Authors: Feely Wayne E. , Evanega George , Beavers Ellington M. 
Published: November 2003

Abstract

2‐Cyano‐6‐methylpyridine

intermediate:
1‐Methoxy‐2‐methylpyridinium methyl sulfate
.

reactant: 109 g. (1.0 mole) of dry powdered 2‐picoline‐1‐oxide

product: 2‐cyano‐6‐methylpyridine

byproduct: 4‐cyano‐2‐methylpyridine

product: 2‐cyano‐4,6‐dimethylpyridine

product: 2‐cyanoquinoline

product: 1‐cyanoisoquinoline
Hexahydrogallic Acid and Hexahydrogallic Acid Triacetate
Authors: Burgstahler Albert W. , Bithos Zoe J. 
Published: November 2003

Abstract

Hexahydrogallic acid and hexahydrogallic acid triacetate

solvent: 100 ml. of 30–40° petroleum ether

product: hexahydrogallic acid

product:
Hexahydrogallic acid triacetate
1‐Aminopyridinium Iodide
Authors: Gösl R. , Meuwsen A. 
Published: November 2003

Abstract

1‐Aminopyridinium iodide

product: 1‐aminopyridinium iodide

product: methylhydrazinium hydrogen sulfate

product: ethylhydrazinium hydrogen oxalate

product: butylhydrazinium hydrogen sulfate

product: 1‐aminopiperidinium hydrogen oxalate

product: 1,1‐dibutylhydrazinium hydrogen oxalate

product: 1,1,1‐trimethylhydrazinium hydrogen oxalate

product: 1‐amino‐2‐methylpyridinium iodide

product: 1‐amino‐2,4‐dimethylpyridinium iodide

product: 1‐amino‐2,6‐dimethylpyridinium iodide

product: 1‐amino‐2,4,6‐trimethylpyridinium iodide

product: 1‐aminoquinolinium iodide
2‐Mercaptopyrimidine
Authors: Crosby Donald G. , Berthold Robert V. , Johnson Herbert E. 
Published: November 2003

Abstract

2‐Mercaptopyrimidine

reactant: 176 g. (0.80 mole) of commercial‐grade 1,1,3,3‐tetraethyoxypropane

intermediate: 2‐mercaptopyrimidine hydrochloride

product: 2‐mercaptopyrimidine

product: 2‐mercaptopyrimidine bisulfate
3‐Bromothiophene
Authors: Gronowitz S. , Raznikiewicz T. 
Published: November 2003

Abstract

3‐Bromothiophene

reactant: 1283 g. (4.00 moles) of 2,3,5‐tribromothiophene

product: 3‐bromothiophene

byproduct: 2‐bromothiophene
1,3‐Dihydro‐3,5,7‐Trimethyl‐2H‐Azepin‐2‐One
Authors: Paquette Leo A. 
Published: November 2003

Abstract

1,3‐Dihydro‐3,5,7‐trimethyl‐2H‐azepin‐2‐one

byproduct: phenol

product: 1,3‐dihydro‐3,5,7‐trimethyl‐2H‐azepin‐2‐one
α,α‐Dimethyl‐β‐Phenethylamine
Authors: Ritter John J. , Kalish Joseph 
Published: November 2003

Abstract

α,α‐Dimethyl‐β‐phenethylamine

intermediate:
N‐Formyl‐α,α‐dimethyl‐β‐phenethylamine
.

product: α,α‐dimethyl‐β‐phenethylamine
α‐Ethyl‐α‐Methylsuccinic Acid
Authors: Prout F. S. , Aguilar V. N. , Girard F. H. , Lee D. D. , Shoffner J. P. 
Published: November 2003

Abstract

α‐Ethyl‐α‐methylsuccinic acid

product: α‐ethyl‐α‐methylsuccinic acid

product: ethyl 2,3‐dicyano‐3‐methylpentanoate
p
‐Chlorophenyl Isothiocyanate
Authors: van der Kerk G. J. M. , Pluygers C. W. , de Vries G. 
Published: November 2003

Abstract

p
‐Chlorophenyl isothiocyanate

solvent: 200 ml. of petroleum ether

product:
p
‐chlorophenyl isothiocyanate

product: phenyl isothiocyanate

product:
p
‐phenylene diisothiocyanate

product:
p
‐acetylaminophenyl isothiocyanate

product:
p
‐ethoxyphenyl isothiocyanate

product:
p
‐bromophenyl isothiocyanate
N‐Mono‐ and N,N‐Disubstituted Ureas and Thioureas: Cyclohexylurea and 2,6‐Dimethylphenylthiourea
Authors: Neville Roy G. , McGee John J. 
Published: November 2003

AbstractN‐mono‐ and N,N‐disubstituted ureas and thioureas: Cyclohexylurea and 2,6‐Dimethylphenylthioureaproduct: cyclohexylureaproduct: 2,6‐dimethylphenylthioureaproduct: benzylureaproduct: phenylureaproduct:t‐butylureaproduct: N‐(2‐benzothiazolyl)ureaproduct: dibenzylthioureaproduct:t‐butylthiourea
2‐Acetamido‐3,4,6‐tri‐
O
‐acetyl‐2‐deoxy‐α‐
D
‐Glucopyranosyl Chloride
Authors: Horton Derek 
Published: November 2003

Abstract

2‐Acetamido‐3,4,6‐tri‐
O
‐acetyl‐2‐deoxy‐α‐
D
‐glucopyranosyl chloride

product: 2‐acetamido‐3,4,6‐tri‐
O
‐acetyl‐2‐deoxy‐α‐
D
‐glucopyranosyl chloride
2,2′‐Dichloro‐α,α′‐Epoxybibenzyl
Authors: Mark V. 
Published: November 2003

Abstract

2,2′‐Dichloro‐α,α′‐epoxybibenzyl

product: 2,2′‐Dichloro‐α,α′‐epoxybibenzyl

product: o‐Bromophenyl

product: m‐Bromophenyl

product: o‐Fluorophenyl

product: 3,4‐Dichlorophenyl

product: m‐Nitrophenyl

product: p‐Cyanophenyl

product: p‐Formylphenyl

product: 1‐Naphthyl

product: 2‐Thienyl

product: 2‐Pyridyl
3,4‐Dichloro‐1,2,3,4‐tetramethylcyclobutene
Authors: Criegee R. 
Published: November 2003

Abstract

3,4‐Dichloro‐1,2,3,4‐tetramethylcyclobutene

product: 3,4‐Dichloro‐1,2,3,4‐tetramethylcyclobutene
Hexaphenylbenzene
Authors: Fieser Louis F. 
Published: November 2003

Abstract

Hexaphenylbenzene

reactant: 8.0 g. of tetraphenylcyclopentadienone (0.021 mole)

reactant: 8.0 g. of diphenylacetylene (0.043 mole)

intermediate:
meso
‐Stilbene dibromide

product: Hexaphenylbenzene
3‐Hydroxyglutaronitrile
Authors: Johnson F. , Panella J. P. 
Published: November 2003

Abstract3‐Hydroxyglutaronitrilebyproduct: 4‐chloro‐3‐hydroxybutyronitrile and 4‐hydroxycrotononitrileproduct: 3‐Hydroxyglutaronitrileproduct: 2‐amino‐6‐bromopyridine
o
‐Nitrobenzaldehyde
Authors: Kalir A. 
Published: November 2003

Abstract

o
‐Nitrobenzaldehyde

intermediate:
o
‐nitrobenzylpyridinium bromide

intermediate: N‐(
p
‐dimethylaminophenyl)‐α‐(
o
‐nitrophenyl)nitrone

product:
o
‐nitrobenzaldehyde

product: fluoro‐o‐nitrobenzaldehydes

reactant: Fluoro‐2‐nitrobenzylpyridinium Bromide

intermediate: N‐(p‐dimethylaminophenyl)‐ α‐(fluoro‐o‐nitrophenyl)nitrone
Perchlorofulvalene
Authors: Mark V. 
Published: November 2003

AbstractPerchlorofulvalenereactant: 47.5 g. (0.100 mole) of decachlorobi‐2,4‐cyclopentadienylsolvent: 200 ml. of petroleum etherreactant: 25.2 g. (0.121 mole) of triisopropyl phosphite in 25 ml. of petroleum etherproduct: perchlorofulvalenereactant: diisopropyl hydrogen phosphitereactant: triisopropyl phosphate
exo
‐
cis
‐Bicyclo[3.3.0]Octane‐2‐Carboxylic Acid
Authors: Dowbenko R. 
Published: November 2003

Abstract

exo
‐
cis
‐Bicyclo[3.3.0]octane‐2‐carboxylic acid

reactant: 325 g. (3.0 moles) of
cis,cis
‐1,5‐cyclooctadiene

solvent: 3 l. of chloroform

intermediate: 2‐(trichloromethyl)bicyclo[3.3.0]octane

product:
exo
‐
cis
‐bicyclo[3.3.0]octane‐2‐carboxylic acid
Unsolvated
n
‐Butylmagnesium Chloride
Authors: Bryce‐Smith D. , Blues E. T. 
Published: November 2003

Abstract

Unsolvated
n
‐butylmagnesium chloride

solvent: 60 ml. of methylcyclohexane

product:
n
‐butylmagnesium chloride

product:
n
‐butane

solvent: light petroleum
p
‐Bromodiphenylmethane
Authors: Galun A. B. , Kalir A. 
Published: November 2003

Abstract

p
‐Bromodiphenylmethane

intermediate: 1‐phenyl‐2,2,2‐trichloroethanol

intermediate: 146 g. (0.40 mole) of 1‐
p
‐bromophenyl‐1‐phenyl‐2,2,2‐trichloroethane

product:
p
‐Bromodiphenylmethane
2,2,4‐Trimethyl‐3‐Oxovaleryl Chloride
Authors: Elam Edward U. , Gott P. Glenn , Hasek Robert H. 
Published: November 2003

Abstract

2,2,4‐Trimethyl‐3‐oxovaleryl chloride

product: 2,2,4‐trimethyl‐3‐oxovaleryl chloride
7‐Cyanoheptanal
Authors: Ohno Masaji , Naruse Norio , Terasawa Isao 
Published: November 2003

Abstract

7‐Cyanoheptanal

intermediate: 2‐chlorocyclooctanone oxime hydrochloride

intermediate: 2‐methoxycyclooctanone oxime

product: 7‐cyanoheptanal

byproduct: 2,4‐dinitrophenylhydrazone

solvent: methanol‐triethylamine
1,2‐Cyclononadiene
Authors: Skattebøl L. , Solomon S. 
Published: November 2003

Abstract

1,2‐Cyclononadiene

reactant:
cis
‐cyclooctene, 178 g. (214 ml., 1.62 moles)

intermediate: 9,9‐dibromobicyclo[6.1.0]nonane

product: 1,2‐cyclononadiene
trans
‐Cyclooctene
Authors: Cope Arthur C. , Bach Robert D. 
Published: November 2003

Abstract

trans
‐Cyclooctene

reactant: 155.3 g. (1 mole) of N,N‐dimethylcyclooctylamine

intermediate: 100 g. (0.34 mole) of N,N,N‐trimethylcyclooctylammonium iodide

byproduct:
cis
‐cyclooctene

product:
trans
‐cyclooctene
Arylbenzenes: 3,4‐Dichlorobiphenyl
Authors: Hey D. H. , Perkins M. J. 
Published: November 2003

AbstractArylbenzenes: 3,4‐dichlorobiphenylreactant: Thirty‐eight grams (0.1 mole) of bis‐3,4‐dichlorobenzoyl peroxidebyproduct: 3,4‐dichlorobenzoic acidsolvent: 100 ml. of petroleum etherproduct: 3,4‐dichlorobiphenylbyproduct: biphenyl
trans
‐4,4′‐Dimethoxystilbene
Authors: Findlay J. W. A. , Turner A. B. 
Published: November 2003

Abstract

trans
‐4,4′‐Dimethoxystilbene

byproduct: 2,3‐dichloro‐5,6‐dicyanohydroquinone

product:
trans
‐4,4′‐dimethoxystilbene
Phenols: 6‐Methoxy‐2‐Naphthol
Authors: Kidwell R. L. , Murphy M. , Darling S. D. 
Published: November 2003

Abstract

Phenols: 6‐Methoxy‐2‐naphthol

reactant: 95 g., of 6‐bromo‐2‐methoxynaphthalene

product: 6‐methoxy‐2‐naphthol
R(+)‐ and S(−)‐α‐Phenylethylamine
Authors: Ault Addison 
Published: November 2003

Abstract

R(+)‐ and S(−)‐α‐phenylethylamine

product:
(S)‐(−)‐α‐Phenylethylamine

intermediate: (−)‐amine (+)‐hydrogen tartrate salt

product:
(R)‐
(+)‐α‐
Phenylethylamine

intermediate: (+)‐amine sulfate
Tetramethyl‐
p
‐phenylenediamine
Authors: Hünig S. , Quast H. , Brenninger W. , Frankenfield E. 
Published: November 2003

Abstract

Tetramethyl‐
p
‐phenylenediamine

reactant: 54 g. (0.5 mole) of powdered
p
‐phenylenediamine

reactant: 320 ml. (3.4 mole) of dimethyl sulfate

reactant: 100 ml. of ethanolamine

product: Tetramethyl‐
p
‐phenylenediamine
2,4,6‐Triphenylphenoxyl
Authors: Dimroth K. , Berndt A. , Perst H. , Reichardt C. 
Published: November 2003

Abstract2,4,6‐Triphenylphenoxylintermediate: 2,4,6‐triphenylanilineintermediate: 2,4,6‐triphenylphenolproduct: 2,4,6‐triphenylphenoxyl
2,4,6‐Triphenylpyrylium Tetrafluoroborate
Authors: Dimroth K. , Reichardt C. , Vogel K. 
Published: November 2003

Abstract2,4,6‐Triphenylpyrylium tetrafluoroborateproduct: 2,4,6‐triphenylpyrylium tetrafluoroboratereactant: 19 ml. (19 g., 0.95 mole) of anhydrous hydrofluoric acidreactant: 126 ml. (142 g., 1.00 mole) of distilled boron trifluoride etherate
Bis(trifluoromethyl)diazomethane
Authors: Middleton W. J. , Gale D. M. 
Published: November 2003

Abstract

Bis(trifluoromethyl)diazomethane

reactant: 82.5 g. (0.500 mole) of hexafluoroacetone imine

intermediate: hexafluoroacetone hydrazone

product: bis(trifluoromethyl)diazomethane