bluuebunny/crossref_metadata_2025_split huggingface dataset:
THE PROBLEMS EXPERIENCED BY THE LAST OTTOMAN PARLIAMENTARIANS WHO WERE ABLE TO JOIN THE GRAND NATIONAL ASSEMBLY IN THE FIRST TERM IN TERMS OF REACHING THE PARLIAMENT
Authors: YILMAZ Yakup 
Published: October 2023

The defeat of the Ottoman Empire in the First World War and the occupation of the country and its institutions, including Istanbul, by the Allied Powers hampered the work of the Parliament. This parliament, which was the last Ottoman Parliament, was an authority that showed the courage to take decisions that would positively affect the fate of the Turkish nation. So much so that it was able to take the "Misak-ı Milli" decisions, which are still actively used even in today's politics, and declare the indivisibility and unity of the homeland even under occupation.
This parliament was seen as a structure that could not be controlled by the British and it was shut down. Subsequently, the members either fled or were sent into exile. Following this event, Mustafa Kemal and his friends deemed it necessary to open a new parliament in Ankara and this new constituent assembly was able to convene on April 23, 1920. As a result of the elections held, along with the new deputies who joined the assembly, the remaining deputies from the last Ottoman parliament were asked to come to Ankara and join the assembly.
Many patriotic former Ottoman MPs who were able to escape from Istanbul, exile or imprisonment came to Ankara and started to work in the constituent assembly. The processes of their participation in the Grand National Assembly and the problems they faced are tried to be revealed in this study. The aforementioned process has been revealed by using both research works and official sources and memoirs of the period.
Keywords: Ottoman Mebusan Assembly, Grand National Assembly, , Deputy.

This parliament was seen as a structure that could not be controlled by the British and it was shut down. Subsequently, the members either fled or were sent into exile. Following this event, Mustafa Kemal and his friends deemed it necessary to open a new parliament in Ankara and this new constituent assembly was able to convene on April 20, 1920. As a result of the elections held, along with the new deputies who joined the assembly, the remaining deputies from the last Ottoman parliament were asked to come to Ankara and join the assembly.
Many patriotic former Ottoman MPs who were able to escape from Istanbul, exile or imprisonment came to Ankara and started to work in the constituent assembly. The processes of their participation in the First Grand National Assembly and the problems they faced are tried to be revealed in this study. The aforementioned process has been revealed by using both research works and official sources and memoirs of the period.
Keywords: Ottoman Mebusan Assembly, Grand National Assembly, , Deputy,
Mapping literature reviews on coral health: A review map, critical appraisal and bibliometric analysis
Authors: Burke Samantha , Pottier Patrice , Macartney Erin L. , Drobniak Szymon M. , Lagisz Malgorzata , Ainsworth Tracy , Nakagawa Shinichi 
Published: October 2023

Abstract

The state of coral reefs has been of great concern, as documented in the growing amount of primary literature. These reports on coral health have accumulated, resulting in reviews of the primary studies (i.e. secondary literature). Recently, such reviews have also accumulated, creating an opportunity to review the secondary literature. Second‐order syntheses (reviews of secondary literature) provide an overview of the field, which can be used to guide future research.

Based on our previously published protocol, we compiled peer‐reviewed secondary literature on coral health from Scopus and Web of Science databases. We synthesised 335 secondary literature papers on coral health, 35 of which underwent critical appraisal and 333 of which also underwent bibliometric analysis.

The secondary literature consisted primarily of qualitative reviews (78%). Over 80% of papers stated informing coral conservation as the review's purpose. Climate change (50%) and coral resilience (42%) were the most studied topics, and bioerosion was the least (3.6%). Critically appraised papers scored poorly on Collaboration for Environmental Evidence Synthesis Assessment Tool criteria (studies did not meet standards 55% of the time). The authors of the secondary literature were highly interconnected (with 30% of the authors having more than 15 coauthors within our dataset) and included authors from countries with coral reefs (predominantly in Australia and USA; 79% of papers). The secondary literature on coral health had a median Altmetric score of 5.27.

We have revealed key gaps in coral health topics for further review (e.g. coral range shifts and microbial biodiversity), particularly when considering conservation policy. Incorporating research in policy could be improved through greater research accessibility and continuing to gather public interest in coral reefs. We further recommend broadening research collaborations to include even more researchers from countries with coral reefs (e.g. Maldives). Finally, the secondary literature on coral health needs better reporting transparency (e.g. publishing code).

Our second‐order synthesis is timely, pushing coral health research in a new direction—one which produces research of higher quality, collaboration, and efficiency. As coral reefs decline, we should also aim to rebuild public trust in research and strengthen the evidence base for conservation.
Hand and finger, ultrasound‐guided, percutaneous core needle biopsies: A safe procedure with high diagnostic accuracy
Authors: Magoon Stephanie , Peters Vanessa , de Souza Felipe Ferreira , Chen David , Owens Patrick , Pretell‐Mazzini Juan , Fullerton Natalia , Jose Jean , Rosenberg Andrew , Subhawong Ty K. 
Published: October 2023

AbstractIntroduction/PurposeTo determine the diagnostic accuracy and complication rates of ultrasound‐guided, percutaneous core needle biopsies of soft tissue masses in the hand and fingers.MethodsReports from all ultrasound‐guided procedures between 21 May 2014 and 17 March 2022 were queried for keywords including “hand”, OR “finger”, AND “biopsy”. Patient demographics, lesion size and location, biopsy needle gauge and the number of cores obtained were recorded. The final pathology of the mass excision was then compared with the core needle biopsy (CNB) for each patient.ResultsSixty‐six records were reviewed, and 37 patients met inclusion criteria. Maximum lesion diameter averaged 1.45 cm with a range between 0.4 and 4.3 cm. The frequency of needle gauges used was 14G (14%), 16G (24%), 18G (38%), 20G (11%) and ‘not reported’ (14%). The mean number of tissue cores obtained was 2.9 (SD 1.2; range 1 to 6), excluding nine cases that reported ‘multiple’. The frequency of CNB diagnoses included tenosynovial giant cell tumour (TGCT) at 30%, ganglion cyst at 11% and epidermal inclusion cyst at 5%. CNB was 100% sensitive in detecting the three (8%) malignancies. Of the 37 tumours biopsied, 16 were surgically excised. One angiomyoma was originally diagnosed as a haemangioma on CNB, but all other histologic results were concordant for a diagnostic accuracy of 97%.DiscussionSmall soft tissue masses in the hands and fingers, even those less than 1 cm, are often amenable to ultrasound‐guided CNB. Performance under image guidance facilitates retrieval of core specimens adquate for histologic diagnosis with relatively few passes using higher gauge needles.ConclusionOverall, ultrasound‐guided CNB of the hand and fingers is safe and highly accurate in diagnosing soft tissue tumours. The accuracy is unrelated to the needle's gauge, the number of passes and the size of the lesions.
Dominant Role of Hole Transport Pathway in Achieving Record High Photoconductivity in Two‐Dimensional Metal–Organic Frameworks
Authors: Wang Denan , Ostresh Sarah , Streater Daniel , He Peilei , Nyakuchena James , Ma Qiushi , Zhang Xiaoyi , Neu Jens , Brudvig Gary W. , Huang Jier 
Published: October 2023

AbstractMetal–organic frameworks (MOFs) with mobile charges have attracted significant attention due to their potential applications in photoelectric devices, chemical resistance sensors, and catalysis. However, fundamental understanding of the charge transport pathway within the framework and the key properties that determine the performance of conductive MOFs in photoelectric devices remain underexplored. Herein, we report the mechanisms of photoinduced charge transport and electron dynamics in the conductive 2D M−HHTP (M=Cu, Zn or Cu/Zn mixed; HHTP=2,3,6,7,10,11‐hexahydroxytriphenylene) MOFs and their correlation with photoconductivity using the combination of time‐resolved terahertz spectroscopy, optical transient absorption spectroscopy, X‐ray transient absorption spectroscopy, and density functional theory (DFT) calculations. We identify the through‐space hole transport mechanism through the interlayer sheet π–π interaction, where photoinduced hole state resides in HHTP ligand and electronic state is localized at the metal center. Moreover, the photoconductivity of the Cu−HHTP MOF is found to be 65.5 S m−1, which represents the record high photoconductivity for porous MOF materials based on catecholate ligands.
Clonazepam‐related sexual dysfunction in male veterans with PTSD
Authors: Fossey Mark D. , Hamner Mark B. 
Published: October 2023

AbstractMedication‐induced sexual dysfunction can significantly interfere with patients' quality of life and lead to poor compliance. This retrospective study examined the records of 100 male veterans with post‐traumatic stress disorder (PTSD) selected in alphabetical order from an active treatment file of 230 patients. Forty‐two patients had received clonazepam (mean maximum dose: 3.4 ±1.6 mg/day) at some point during their treatment. Of these, 18 (42.9%) complained of significant sexual dysfunction (primarily erectile dysfunction). Eighty‐four patients received diazepam (mean maximum dose: 52.1 ± 29.7 mg/day), nine received alprazolam (mean maximum dose: 5.2 ± 2.8 mg/day) and eight received lorazepam (mean maximum dose: 3.8 ± 2.4 mg/day). None of these patients complained of sexual dysfunction during treatment with these three other benzodiazepines. Our findings suggest that benzodiazepines, particularly clonazepam in the current study, can be a cause of sexual dysfunction in many male patients. Prospective studies comparing the overall clinical utility of various benzodiazepines are indicated in this and other clinic populations. Anxiety 1:233–236 (1994/1995). © 1995 Wiky‐Liss, Inc.
Preference for quicker offers: The critical roles of temporal reference points and evaluation mode
Authors: Lei Chao , Zhang Pengcheng , Gregory Lance , Wang Haijiang , Wang Guoxuan , Häubl Gerald 
Published: October 2023

AbstractPeople may use the amount of time it takes someone else to reach a particular decision as input that informs their thoughts and feelings about that decision. Building on prior work suggesting that people are more inclined to accept offers that are extended more rapidly, the current research shows that this preference for quicker offers depends critically on whether offers are considered simultaneously along with other offers or individually (i.e., joint vs. separate evaluation mode), as well as on the presence and nature of explicit temporal reference points in joint evaluation mode. We theorize that the preference for quicker offers is limited to settings where (1) multiple offers are considered simultaneously and (2) the amount of time it took for these offers to be made exceeds a salient temporal reference point. This implies that the effect should not be observed when multiple offers are considered that were not all generated more slowly than an explicit temporal reference point, or when offers are considered one at a time. Evidence from seven studies provides support for this theorizing. The findings advance our understanding of the nuanced ways in which the amount of time taken to extend offers affects how people interpret, draw inferences from, and respond to these offers.
Electrolytic construction of nanosphere‐assembled protective layer toward stable lithium metal anode
Authors: Lu Gongxun , Li Shuai , Yue Ke , Yuan Huadong , Luo Jianmin , Liu Yujing , Wang Yao , Tao Xinyong , Nai Jianwei 
Published: October 2023

AbstractThe uncontrolled dendrite growth and electrolyte consumption in lithium metal batteries result from a heterogeneous and unstable solid electrolyte interphase (SEI). Here, a high‐voltage forced electrolysis strategy is proposed to stabilize the lithium metal via electrodepositing a spherical protective layer. This peculiar SEI is composed of a nanosized Li sphere that is encased with adjustable composition, as proved by cryo‐transmission electron microscopy and multiple surface‐sensitive spectroscopies. Such a three‐dimensional nanosphere‐assembled protective layer has homogeneous components, mechanical strength, and rapid Li‐ion conductivity, enabling it to alleviate the volume expansion and prevent dendrite growth during Li deposition. The symmetric cell can be stably operated for ultralong‐term cycling time of 2000 and 800 h even at high current densities of 1 and 10 mA cm−2, respectively. Using this interface permits stable cycling of full cells paired with LiFePO4 and LiNi0.8Co0.1Mn0.1O2 cathodes with low negative/positive capacity ratio, high current density, and limited Li excess. This tactic also fosters a novel insight into interface design in the battery community and encourages the practical implementation of lithium metal batteries.
Improvement of drug‐induced gingival overgrowth and cerebrovascular related dementia after dental treatments
Authors: Tanoue Naomi , Kawasaki Hanako , Kiriishi Kensuke , Ayuse Takao 
Published: October 2023

Key Clinical MessageDrug‐induced gingival overgrowth can occur as a side effect of specific drugs and lead to poor oral function. Appropriate dental management of the overgrowth may improve oral function and improve cognitive deficits after cerebrovascular accidents.
WO3‐based Materials for Photocatalytic and Photoelectrocatalytic Selective Oxidation Reactions
Authors: Wang Ziru , Einaga Hisahiro 
Published: October 2023

AbstractSelective oxidation reactions are crucial in producing various chemicals in the industry. However, most catalytic processes for these reactions use harsh reaction conditions. Recently, heterogeneous photo(electro)catalysis has been considered promising for selective oxidation reactions under mild conditions. Semiconductor materials are frequently used as heterogeneous photocatalysts because they can produce active species that contribute to the oxidation of organic compounds under light irradiation. Among various semiconductor photocatalysts, tungsten oxide (WO3) is one of the most promising candidates due to its advantages, including high stability, wide light adsorption range, proper band structures, and unique catalytic mechanism. This paper reviews the WO3‐based materials for photocatalytic (PC) and photoelectrocatalytic (PEC) selective oxidations. We summarize the strategies for designing WO3 structures, which include morphology control, crystal facet optimization, and defect engineering. Then, the finely designed WO3 structures for PC and PEC oxidation of several typical organic compounds have been discussed based on catalytic mechanism and performance. Finally, we propose the prospects and challenges of WO3 photocatalysts and photoanodes in selective oxidation reactions.
Tailoring Secondary Coordination Sphere Effects in Single‐metal‐site Catalysts by Surface Immobilization of Supramolecular Cages
Authors: Laan Petrus C. M. , Bobylev Eduard O. , de Zwart Felix J. , Vleer Joppe A. , Troglia Alessandro , Bliem Roland , Rothenberg Gadi , Reek Joost N. H. , Yan Ning 
Published: October 2023

AbstractControlling the coordination sphere of heterogeneous single‐metal‐site catalysts is a powerful strategy for fine‐tuning their catalytic properties but is fairly difficult to achieve. To address this problem, we immobilized supramolecular cages where the primary‐ and secondary coordination sphere are controlled by ligand design. The kinetics of these catalysts were studied in a model reaction, the hydrolysis of ammonia borane, over a temperature range using fast and precise online measurements generating high‐precision Arrhenius plots. The results show how catalytic properties can be enhanced by placing a well‐defined reaction pocket around the active site. Our fine‐tuning yielded a catalyst with such performance that the reaction kinetics are diffusion‐controlled rather than chemically controlled.
Photoisomerization of “Partially Embedded Dihydropyridazine” with a Helical Structure
Authors: Usui Kazuteru , Amano Ami , Murayama Kasumi , Sasaya Miho , Kusumoto Ryota , Umeno Tomohiro , Murase Satsuki , Iizuka Naoko , Matsumoto Shota , Fuchi Yasufumi , Takahashi Kazuyuki , Kawahata Masatoshi , Kobori Yasuhiro , Karasawa Satoru 
Published: October 2023

AbstractInvited for the cover of this issue are the groups of Kazuteru Usui and Satoru Karasawa at Showa Pharmaceutical University and Yasuhiro Kobori of Kobe University. The image depicts chirality control of helical compounds through cycles of photocleavage and recombination under sunlight with a “Jack and the Beanstalk” motif. Read the full text of the article at 10.1002/chem.202302413.
Electronic Effects in Phosphino‐Iminophosphorane PdII Complexes upon Varying the N Substituent
Authors: Popovici Ingrid , Lognon Elise , Casaretto Nicolas , Monari Antonio , Auffrant Audrey 
Published: October 2023

AbstractThree series of palladium(II) complexes supported by a phosphine‐iminophosphorane ligand built upon an ortho‐phenylene core were investigated to study the influence of the iminophosphorane N substituent. Cis‐dichloride palladium(II) complexes 1 in which the N atom bears an isopropyl (iPr, 1 a), a phenyl (Ph, 1 b), a trimethylsilyl (TMS, 1 c) group or an H atom (1 d) were synthesized in high yield. They were characterized by NMR, IR spectroscopy, HR‐mass spectrometry, elemental analysis, and X‐ray diffraction. A substantial bond length difference between the Pd−Cl bonds was observed in 1. Complexes 1 a–d were converted into [Pd(LR)Cl(CNtBu)](OTf)] 2 a–d whose isocyanide is located trans to the iminophosphorane. The corresponding dicationic complexes [Pd(LR)(CNtBu)2](OTf)2 3 a–d were also synthesized, however they exhibited lower stability in solution than 2, the isopropyl derivative 3 a being the most stable of the series. Molecular modeling was performed to rationalize the regioselectivity of the substitution of the single chloride by isocyanide (from 1 to 2) and to study the electronic distribution in the complexes. In particular differences between the TMS and H containing complexes vs. the iPr and Ph ones were found. This suggests that the nature of the N substituent is far from innocent and can help tune the reactivity of iminophosphorane complexes.
Cybersecurity and process safety synergy: An analytical exploration of cyberattack‐induced incidents
Authors: Wen He , Khan Faisal 
Published: October 2023

AbstractIn recent years, cyber‐connected industrial control systems (ICS) for remote operations have increased cyber and process risks. While process safety is widely studied, its connectivity with the cyber threat has not been well explored. It is crucial to study cybersecurity and process safety in an integrated way to ensure safe operations. This study addresses this gap by first analyzing the cyber incidents related to ICS since 1990. Subsequently, it connects cyber incidents with process accidents by Bowtie based on the ATT&CK framework. It further develops a Bayesian network due to the insignificant probabilities by Bowtie. The developed model is explained with case analysis. This study confirms that the process industry is prone to cyberattacks, and the field controllers are the main targets of attacks. The study observes that the safety instrument system (SIS) is critical for both the attackers and neutralizing the attacks (defenders). Moreover, attackers deploy newer approaches to attack the ICS, and therefore, methods of threat assessment and its neutralizing strategies should be dynamic.
(R)‐PFI‐2 Analogues as Substrates and Inhibitors of Histone Lysine Methyltransferase SETD7
Authors: Porzberg Miriam R. B. , Lenstra Danny C. , Damen Eddy , Blaauw Richard H. , Rutjes Floris P. J. T. , Wegert Anita , Mecinović Jasmin 
Published: October 2023

Abstract(R)‐PFI‐2 is a histone substrate‐competitive inhibitor of the human histone lysine monomethyltransferase SETD7. Aimed at developing potent inhibitors of SETD7 that can also act as small molecule substrates, we replaced the pyrrolidine ring of (R)‐PFI‐2 with several side chains bearing nucleophilic functional groups. We explored the inhibitory activity of 20 novel (R)‐PFI‐2 analogues, and found that the most potent analogue has a hydroxyethyl side chain (7). SETD7’s ability to catalyse methylation of (R)‐PFI‐2‐based small molecules was evaluated by mass spectrometric assays, and we observed efficient methylation of analogues bearing lysine mimicking nucleophilic amines. The optimal side chain was found to be an aminoethyl group (1), which was surprisingly also dimethylated by SETD7. The work demonstrates that small molecules can act as both substrates and inhibitors of biomedically important SETD7.
Development and evaluation of the “Toothbrushing Timer with Information on Toothbrushes” application: A prospective cohort pilot study
Authors: Kaneyasu Yoshino , Shigeishi Hideo , Sugiyama Masaru , Ohta Kouji 
Published: October 2023

AbstractObjectivesFor people, it is challenging to be conscious of the appropriate toothbrushing time to maintain good oral health in daily life. The aim of this study was to preliminarily examine the utility of an application (app) that combines a toothbrushing timer and information on toothbrushes.Materials and MethodsWe developed the “Toothbrushing Timer with Information on Toothbrushes” app to help users ensure appropriate toothbrushing time and learn about the beneficial characteristics of toothbrushes. A total of 18 participants were registered for the study. At baseline (T0) and after 1 month (T1) of app usage, study participants answered a digital questionnaire that comprised three questions on oral health practice, self‐efficacy in oral hygiene, and quality of life related to oral health (Oral Health Impact Profile‐14 [OHIP‐14]).ResultsFive participants were excluded from the analysis as they did not answer the digital questionnaire. Finally, 13 participants completed the survey with a follow‐up of 1 month. The 13 participants were grouped into health professionals (n = 8) and non‐health professionals (n = 5). The total scores for oral health practice and self‐efficacy related to oral hygiene increased after a month of app usage in health professional and non‐health professional groups. However, there were no significant differences between T0 and T1 in either group. The total score of OHIP‐14 was lower at T1 than at T0 in both groups. Therefore, participants showed better oral health practice, self‐efficacy in oral hygiene, and quality of life related to oral health at T1 compared with that at T0.ConclusionsOur app showed positive results for the users and is useful in maintaining and promoting oral health awareness and practice. However, our pilot study lacks sufficient power and did not yield significant differences. Therefore, high‐quality clinical trials with larger sample sizes are warranted for further improvement and evaluation.