bluuebunny/crossref_metadata_2025_split huggingface dataset:
Elucidating Mesostructural Effects on Thermal Conductivity for Enhanced Insulation Applications
Authors: Ren Tingting , Chen Zhenxiang , Chen Jiahao , Huang Xirui , Li Xingjin , Zhang Jie , Lu Qianqian , Hung Chin‐Te , Zhao Tiancong , Wang Min , Zhao Dongyuan 
Published: January 2025

AbstractThermal management is a key link in improving energy utilization and preparing insulation materials with excellent performance is the core technological issue. Complex and irregular pore structures of insulation materials hinder the exploration of structure‐property relationships and the further promotion of material performance. Ordered mesoporous silica (OMS) is a kind of porous material with ordered frameworks. This work elucidates the effects of ordered porous architecture on the thermal conductivity of mesoporous silica. Herein, two typical OMS, SBA‐15 and SBA‐16, characterized by well‐defined porous structures with distinct spatial orientations are synthesized to study the relevance between structure and thermal conductivity. Compared to the 3D cubic mesoporous structure of SBA‐16, the 2D hexagonal structure of SBA‐15 exhibits anisotropic effects that restrict both solid and gaseous conduction, thereby providing better thermal insulating. Due to the influence of porosity, the thermal conductivity is found to decrease strongly with increasing pore size and decreasing wall thickness. Moreover, OMS composite aerogels with outstanding thermal insulation, mechanical performance, and hydrophobicity are fabricated through incorporating OMS into cellulose nanofibers (CNF). Consequently, this work contributes to a deeper understanding of heat transfer in OMS and provides an idea for designing OMS‐based composite materials, thereby advancing their potential applications.
Deep‐Learning‐Enabled Fast Raman Identification of the Twist Angle of Bi‐Layer Graphene
Authors: Chen Yangbo , Li Cheng , Liu Shan , Gao Shikun , Huang Chenyi , Yu Xin , Xu Xiangrui , Ke Haibo , Xue Dezhen , Yu Gui , Liu Zhe , Dai Mengyan , Zhang Xueao 
Published: January 2025

AbstractTwisted bilayer graphene (TBG) has drawn considerable attention due to its angle‐dependent electrical, optical, and mechanical properties, yet preparing and identifying samples at specific angles on a large scale remains challenging and labor‐intensive. Here, a data‐driven strategy that leverages Raman spectroscopy is proposed in combination with deep learning to rapidly and non‐destructively decode and predict the twist angle of TBG across the full angular range. By processing high‐dimensional Raman data, the deep learning model extracts hidden information to achieve precise twist angle identification. This approach is further extended to a 2D plane, enabling accurate orientational mapping within individual samples. Through interpretability analysis, the model is validated in conjunction with first‐principles theoretical calculations, ensuring robust and explainable results. This data‐driven methodology not only facilitates efficient TBG characterization but also introduces a broadly applicable framework for studying other angle‐dependent 2D materials, thereby advancing the field of material spectroscopy and analysis.
Ensuring Confidentiality in Supply Chains With an Application to Life‐Cycle Assessment
Authors: Brucker Achim D. , Yalman Sakine 
Published: January 2025

ABSTRACTModern supply chains of goods and services rely heavily on close collaborations between the partners within these supply chains. Consequently, there is a demand for IT systems that support collaborations between business partners, for instance, allowing for joint computations for global optimizations (in contrast to local optimizations that each partner can do on their own). Still, businesses are very reluctant to share data or connect their enterprise systems to allow for such joint computation. The topmost factor that businesses name as reason for not collaborating, is their security concern in general and, in particular, the confidentiality of business critical data. While there are techniques (e.g., homomorphic encryption or secure multiparty computation) that allow joint computations and, at the same time, that are protecting the confidentiality of the data that flows into such a joint computation, they are not widely used. One of the main problems that prevent their adoption is their perceived performance overhead. In this paper, we address this problem by an approach that utilized the structure of supply chains by decomposing global computations into local groups, and applying secure multiparty computation within each group. This results in a scalable (resulting in a significant smaller runtime overhead than traditional approaches) and secure (i.e., protecting the confidentiality of data provided by supply chain partners) approach for joint computations within supply chains. We evaluate our approach using life‐cycle assessment (LCA) as a case study. Our experiments show that, for instance, secure LCA computations even in supply chains with 15 partners are possible within less than two minutes, while traditional approaches using secure multiparty computation need more than a day.
Human Dermal Microvascular Arterial and Venous Blood Endothelial Cells and Their Use in Bioengineered Dermo‐Epidermal Skin Substitutes
Authors: Rütsche Dominic , Nanni Monica , Cheng Phil , Caflisch Nicolà , Tastanova Aizhan , Jenni Céline , Levesque Mitchell P. , Moehrlen Ueli , Klar Agnes S. , Biedermann Thomas 
Published: January 2025

AbstractThe bioengineering of vascular networks is pivotal to create complex tissues and organs for regenerative medicine applications. However, bioengineered tissues comprising an arterial and venous plexus alongside a lymphatic capillary network have not been explored yet. Here, scRNA‐seq is first employed to investigate the arterio‐venous endothelial cell marker patterning in human fetal and juvenile skin. Transcriptomic analysis reveals that arterial and venous endothelial cell markers NRP1 (neuropilin 1) and NR2F2 (nuclear receptor subfamily 2 group F member 2) are broadly expressed in fetal and juvenile skin. In contrast, expression of NRP1 and NR2F2 on the protein level is cell‐type specific and is retained in 2D (2‐dimensional) cultures in vitro. Finally, distinct arterial and venous capillaries are bioengineered in 3D (3‐dimensional) hydrogels and rapid anastomosis is demonstrated with the host vasculature in vivo. In summary, the bioengineering of human arterial, venous, and lymphatic capillaries is established, hence paving the way for these cells to be used in regenerative medicine and future clinical applications
Mitigating PM2.5 Induced Myocardial Metal Deposition Through Sodium Thiosulfate Resulted in Reduction of Cardiotoxicity and Physiological Recovery From Ischemia–Reperfusion via Mitochondrial Preservation
Authors: Sivakumar Bhavana , Kurian Gino A. 
Published: January 2025

ABSTRACTThe cardiovascular risks linked to PM2.5 include calcification in both vasculature and myocardial tissues, leading to structural changes and functional decline. Through the selection of a clinically proven endogenous agent, sodium thiosulfate (STS), capable of addressing PM2.5 related cardiac abnormalities, we not only address the absence of effective solutions to mitigate PM2.5 toxicity, but also provide evidence for the repurposing potential of STS in ameliorating PM2.5 induced cardiac damage. Female Wistar rats were exposed to PM2.5 (250 μg/m3) for 3 h daily for 21 days. STS was administered thrice weekly for 3 weeks during exposure after which the hearts were excised and mounted on a Langendorff apparatus for induction of ischemia–reperfusion injury (IR). STS administration improved cardiac function in PM2.5 exposed rat hearts, accompanied by increased expression of the master regulator gene PGC1‐α and increased mitochondrial mass. Moreover, STS restored bioenergetic function and balanced mitochondrial fission–fusion dynamics. The beneficial effects of STS were further evidenced by its ability to scavenge metals, thereby reducing heavy metal deposition in mitochondria and alleviating oxidative stress and inflammation. Furthermore, STS facilitated the clearance of damaged mitochondria through mitophagy. Additionally, STS activated the PI3K/AKT/GSK3ß signaling pathway, providing cardio protection against IR injury in PM2.5‐exposed hearts by preserving mitochondrial function. These results underscore the potential therapeutic benefits of STS in mitigating the adverse cardiac effects induced by PM2.5 exposure. The translation of these findings to clinical practice holds promise for the development of targeted interventions aimed at reducing the cardiovascular toxicity associated with PM2.5 exposure.
The Carbon Border Adjustment Mechanism: Opportunities and Challenges for Non‐EU Countries
Authors: Erdogdu Erkan 
Published: January 2025

ABSTRACTThe European Union's Carbon Border Adjustment Mechanism (CBAM) represents a groundbreaking policy to address global climate change by mitigating carbon leakage and aligning international trade with environmental objectives. As the first initiative of its kind, CBAM imposes carbon pricing on imported goods, encouraging non‐EU producers to meet stringent environmental standards. This mechanism not only supports the EU's ambitious Green Deal targets but also drives innovation, fostering a global transition to low‐carbon technologies. This paper offers an analysis of CBAM's design, phased implementation, and possible impacts. While CBAM drives technological advancements and strengthens climate governance, it also poses challenges, including compliance burdens for developing nations and potential geopolitical tensions. CBAM also promotes sustainable economic transformation by encouraging exporters in carbon‐intensive sectors to adopt green technologies, enhancing competitiveness and resilience. However, without financial and technical assistance, compliance costs risk deepening global inequalities. This study underscores CBAM's dual role as an environmental policy and a catalyst for equitable sustainability, linking economic, environmental, and technological dimensions. The findings highlight how trade policies can address global challenges, drive innovation, and reshape international climate governance, offering insights for policymakers navigating the complexities of sustainable development.
Configure to Conquer: Implementing Configurators to Improve Competitiveness
Authors: Netz Johan , Padhi Pritam , Magnusson Peter , Odhe JanErik , Skrinning Mattias , Windfäll Åsa 
Published: January 2025

Abstract
Recent advancements in technology have created new possibilities for customizing product design without significantly changing the costs of production. By using so-called configurators, which are a form of platform-based technology, firms now have the means to customize products more efficiently. Previous research has mainly focused on the technical side of configurators, whereas the business and organizational issues involved during their introduction are much less understood. The purpose of this chapter is to explore the challenges of adopting configurators in an organization. We combine a literature review from 1980 to the present with findings from an empirical study of a newly developed sales configurator for maritime components.
Enhancing the Phygital Customer Experience in the Digital World
Authors: Gustafsson Amie , Öberg Christina , Shams Poja 
Published: January 2025

Abstract
This chapter explores the concepts of customer experience (CX), phygital customer experience, and digital customer experience. We begin by examining the evolution of the concept of experience in the economy, including the challenges of effectively understanding and measuring experiences. We then delve into the challenges of understanding CX in the context of digitalization and automation, specifically through the lens of self-service technology. This chapter provides an in-depth examination of the conceptualization of CX in unmanned stores and offers insights into how researchers and practitioners can navigate this evolving landscape.
New insights into the biology of the commercial holothurian Parastichopus regalis (Cuvier, 1817) and their ecological implications
Authors: Ramón Montserrat , Baeta Marc , Pérez-Ruzafa Angel , Galimany Eve 
Published: January 2025

Abstract
Holothurians provide important ecosystem services by enhancing sediment health through bioturbation. The sea cucumber Parastichopus regalis has a wide distribution in the Mediterranean Sea. Even though it is a commercially exploited species, little is known about its ecological traits and there is no information on the bioturbation potential resulting from its feeding activity. To address these knowledge gaps, the population density, demographic structure, musculature and evisceration of P. regalis were investigated on Arenys de Mar, NW Mediterranean. Food assimilation efficiency, and feeding and bioturbation rates were assessed through field and laboratory experiments. The exploited population exhibited a healthy distribution of sizes/ages, and the density values were similar to or greater than those described in other Mediterranean areas. This species did not show seasonal evisceration, and seasonal patterns in muscle weight depended on year and body size. The field results indicated that P. regalis selected organic matter from the sediment as food. The average individual feeding rate was 8.6 g wet sediment d−1. The bioturbation role of the P. regalis population in the studied area was especially important at depths between 81 m and 124 m, where it consumed between 7.6 and 13.8 t of wet sediment y−1 km−2. These results highlight the important role that this species play in deep habitats as sediment bioturbator, controlling the accumulation of dead organic matter.
Trophic ecology of squids in the Benguela Upwelling System elucidated by combining stomach content, stable isotope and fatty acid analyses
Authors: Kremer Kira Izabela , Hagen Wilhelm , Oesterwind Daniel , Duncan Sabrina , Bode-Dalby Maya , Dorschner Sabrina , Dudeck Tim , Sell Anne F. 
Published: January 2025

Abstract
Squids occur worldwide in marine ecosystems and play a major role in pelagic food webs by connecting lower and higher trophic levels. Their high feeding intensities and pronounced diel vertical migrations make squids important components of nutrient cycles in marine ecosystems. This study assessed the trophic position and nutritional ecology of a squid species assemblage in the Benguela Upwelling System (BUS) by combining stomach content, stable isotope and fatty acid trophic marker analyses. Samples were collected in the northern (nBUS) and southern (sBUS) BUS in austral spring 2021. A total of 20 squid species from eleven families were identified. Stomach content analyses showed that squid species preyed on a variety of organisms ranging from crustaceans to lanternfishes (Myctophidae) and flying squids (Ommastrephidae). Stable isotope analyses revealed significant differences in δ15N values of small squids (dorsal mantle length < 10 cm) between the two subsystems, but none in those of large squids (dorsal mantle length > 10 cm). Trophic levels ranged from 2.2 to 5.0. Isotopic niche width was widest in the families Ommastrephidae and Cranchiidae. Principal component analyses of fatty acid compositions displayed distinct clusters separating squid families and different prey taxa. This study shows that nBUS and sBUS squids exploit a large variety of pelagic prey organisms and that trophic differences are primarily dependent on squid species and size. The results emphasize the squids’ importance as interlinking element in pelagic food webs and their key function in energy transfer between epi- and mesopelagic layers.
Differentiating Kawasaki Disease and Multisystem Inflammatory Syndrome in Children Using Blood Composite Scores: Insights into Clinical Outcomes and Predictive Indices
Authors: Ulu Kadir , Çağlayan Şengül , Coşkuner Taner , Vazgeçer Ebru Oğultekin , Öner Taliha , Sözeri Betül 
Published: January 2025

Abstract
The study sought to assess the clinical utility of complete blood count-derived composite scores, suggesting their potential as markers of inflammation and disease severity in Kawasaki disease (KD) and multisystem inflammatory syndrome in children (MIS-C) with Kawasaki-like features. This retrospective study analyzed data from 71 KD and 73 MIS-C patients and 70 healthy controls. The KD group showed a higher rate of coronary involvement (26.7% vs. 10.9%), while the MIS-C group had a higher intensive care unit (ICU) admission rate (34.2% vs. 2.8%). Platelet counts, lymphocyte counts, mean platelet volume (MPV), MPV/Lymphocyte (MPVLR), and MPV/Platelet (MPVPR) ratios demonstrated the highest specificities in distinguishing MIS-C than KD (84.5%, 83.1%, 91.1%, 88.7%, and 88.7%, respectively). Monocyte counts, MPV, and MPVPR demonstrated the highest specificities to predictive ICU admission in the MIS-C group (83.3%, 89.6%, and 89.6%, respectively). Lymphocyte counts, platelet/lymphocyte ratio (PLR), neutrophil/lymphocyte ratio (NLR), MPVLR, and Systemic Immune-Inflammation Index (SII) parameters were found to have high negative predictive values for predicting KD patients without coronary artery lesions (CALs) (85.7%, 86.1%, 87.1%, 87.1%, and 85.7%, respectively)., Systemic Inflammation Response Index (SIRI), MPVPR, and CRP were independently predictive of ICU admission in the MIS-C group, and lymphocyte count and IVIG resistance were also identified as significant predictors of CALs in the KD group. NLR, MPVLR, MPVPR, and NPR indices effectively differentiate MIS-C from KD and predict ICU admission in MIS-C. NLR, PLR, MPVLR, and SII are valuable in excluding CALs in KD with high negative predictive values. In addition, SIRI and MPVLR were independent predictors of ICU admission in MIS-C, and lymphocyte count was identified as an independent predictor of CALs in KD.
Morphometric analysis of the greater palatine foramen: a CBCT study in Portugal
Authors: Martins Tomás , Guedes Vanessa , Martins Eugénio , Mesquita Pedro 
Published: January 2025

Abstract

Purpose
The greater palatine foramen (GPF) represents the inferior opening of the greater palatine canal and is located posterolaterally on both sides of the hard palate. The aim of this study is to morphometrically characterise the GPF and to determine its anatomical relationships in a Portuguese population.

Methods
A retrospective study was performed based on the clinical records which included all permanent teeth erupted and a cone beam computed tomography (CBCT) of the entire maxilla. The diameters of the GPF and its distances to posterior nasal spine (PNS), posterior border of the hard palate (PBHP), anterior nasal spine (ANS), midline maxillary suture (MMS) and incisive foramen (IF) were measured. Its position in relation to molars and the shape and direction of opening towards the oral cavity were classified. Global descriptive and comparative analysis were conducted.

Results

N = 100. Metric analysis (mean in millimetres): anteroposterior diameter 5.35, lateromedial diameter 2.24, GPF-PNS 16.26, GPF-PBHP 4.83, GPF-ANS 49.94, GPF-MMS 14.74, GPF-IF 35.18. Position in relation to molars (%): 0% anterior to 2nd molar, 3% opposite 2nd molar, 15% between 2nd and 3rd molars, 77% opposite 3rd molar, 5% distal to 3rd molar. Shape (%): oval 71%, slit 26%, round 1%, other 2%. Metric variables were higher in males than in females (95% CI). There were no differences between genders for categorical variables or between sides for any variable (95% CI).

Conclusion
The most common shape of the GPF is oval and its most common position is opposite the 3rd molar.
Advancing eco-friendly adsorption: a sustainable approach for rapid and efficient methylene blue removal
Authors: Erdem Yayayürük Aslı , Çankaya Nevin , Yayayürük Onur 
Published: January 2025

Abstract
Synthetic dyes, particularly methylene blue (MB), pose significant environmental challenges due to their persistent presence in water bodies. This study introduces a sustainable polymer adsorbent, poly(LIM-co-DVB-co-AcM), synthesized using d-limonene and 4-acryloylmorpholine. Comprehensive characterization using FTIR, SEM, TGA, and BET analysis revealed its thermal stability, surface morphology, and adsorption properties. Adsorption experiments demonstrated optimal MB removal at pH 7.0 with a 20 mg dosage and a 60-min contact time. The Langmuir isotherm model showed monolayer adsorption with a capacity of 54.2 mg g−1, while kinetic studies confirmed the suitability of the pseudo-second-order model. Thermodynamic analysis indicated a spontaneous and exothermic process. The polymer achieved over 99% MB removal efficiency across diverse water matrices, highlighting its potential as a scalable and eco-friendly solution for water purification.
Natural variability masks climate change sea surface temperature signals: a comparison between the Baltic Sea, North Sea and North Atlantic Ocean
Authors: Poul H. Mashayekh , Gröger M. , Karsten S. , Mayer B. , Pohlmann T. , Meier H. E. M. 
Published: January 2025

Abstract
Climate variability in marine environments, particularly sea surface temperature (SST), is influenced by natural fluctuations occurring at various temporal and spatial scales. Distinguishing between anthropogenic climate change trends and natural variability is crucial for understanding the complex dynamics of ocean temperatures. This study applies the concept of Time of Emergence (ToE) to estimate when the signal of long-term climate change becomes distinguishable from natural variability in SST for different seasons. The study focuses on the North Sea, Baltic Sea, and North Atlantic Ocean, utilizing 30 ensemble members of simulation from a regional climate model system, MPIOM-REMO, with slightly different initial conditions. The results reveal that winter ToEs emerge earlier than summer ToEs in all study areas, mainly driven by larger winter SST changes and show that shallow coastal seas like the North and Baltic Seas experience earlier ToEs than the deep central North Atlantic. These findings emphasize the influence of regional processes, such as sea ice dynamics and changes in stratification, on the spatial and temporal variability of ToE patterns.
Current practice and barriers for transition of care (TOC) in pediatric surgery: perspectives of adult surgeons from different subspecialties
Authors: Sia Woon Teen , Tay Jia Chyi , Lee Tiong Chan , Nah Shireen Anne , A. Nallusamy Mohan Arunasalam , Mahendran Hans Alexander 
Published: January 2025

Abstract

Introduction
The advancements in neonatal resuscitation and surgical care have enabled children with congenital abnormalities to receive corrective surgeries and achieve lifespans well into adulthood. These patients may require long-term follow-up as they continue to have risks of developing sequelae from their original diseases or surgical interventions.

Purpose
This study aimed to investigate the current practice and barriers to the transition of care (TOC) from the perspectives of adult surgeons.

Methods
A cross-sectional study was conducted with purposive sampling of adult surgeons from different subspecialties. An online self-administered questionnaire was distributed.

Results
There were 60 respondents. 62% of the respondents had experience managing referrals for continuation of care or complications in patients with congenital abnormalities. 38% of the respondents believed that TOC should be implemented when patients reached ages 17–18 years. 93% of the respondents agreed that a proper TOC model would greatly benefit patient care, and 97% asserted the need to develop TOC pathways in Malaysia. The absence of a proper guideline was the greatest barrier to a smooth TOC.

Conclusion
This study offered insights into the obstacles to TOC based on the perspectives and experiences of adult surgeons who participated. While not exhaustive, our study provided a better understanding of the challenges in developing the appropriate referral pathways for the continued care of these patients.