bluuebunny/crossref_metadata_2025_split huggingface dataset:
RELATO DE EXPERIÊNCIA DE UM CURSO DE FORMAÇÃO CONTINUADA DE PROFESSORES EM LIBRAS: “MÃOS QUE FALAM E OLHOS QUE OUVEM”
Authors: Jacaúna Neto Antonio Francisco , Justino Raquel Dark Conceição , Do Carmo Taisa Fidelis 
Published: December 2023

Este trabalho tem como objetivo o propósito de explicitar como ocorreu, que resultados e desafios foram percebidos na formação continuada em Libras para professores em uma rede pública. Trata-se de um relato de experiência tendo como referencial a formação continuada prevista na LDB/1996 como um dever do Estado e, um direito e dever dos docentes, a qual pode ocorrer em diversos e diferentes formatos. Um desses, foi propiciado por um projeto de extensão oferecido pelo Instituto Federal de Goiás que fez parceria com a regional de ensino da cidade de Luziânia-Go, para atender demanda local e interesse de alguns docentes na formação em Libras. A relevância foi a junção entre conhecimentos teóricos e práticos, contatos com a cultura e comunidade surda durante dois semestres. Os resultados são vistos a partir dos dados apresentados pelas cursistas, que apontam conquistas e lacunas no processo dessa formação continuada, o que permitiu aos organizadores do curso, levantar algumas propostas para aperfeiçoar outras formações continuadas.
Upaya Pembudayaan Kesadaran Hukum di Masyarakat
Authors: Putri Novita Amelia 
Published: December 2023

Ketentraman suatu negara dapat dilihat dari banyaknya tingkat kesadaran dan ketaatan hukum dalam bermasyarakatnya. Tujuan penelitian untuk menyelidiki pembudayaan kesadaran hukum dimasyarakat. Metode penelitian ini menggunakan jenis deskriptif Kualitatif, Wawancara merupakan teknik pengumpulan data dengan cara tanya jawab secara sepihak yang dilakukan secara sistematis atau tersusun dan berdasarkankan kepada tujuan penelitian. Hasil penelitian Seberapa besar pengetahuan masyarakat mengenai Hukum, Bentuk kesadaran hukum masyarakat, Pendapat masyarakat mengenai hukum di Indonesia, Harapan masyarakat kepada hukum di Indonesia. Kesimpulan adalah Kesadaran hukum di Indonesia saat belum maksimal masih banyak pelanggaran yang dilakukan oleh masyarakat. Hukum sendiri merupakan aturan yang di buat secara tertulis maupun tidak tertulis untuk mengatur masyarakat, hukum sangat diperlukan dalam masyarakat guna mengatur serta menjaga masyarakat agar tidak timbul kekacauan dalam bermasyarakat itu sendiri. Hukum di Indonesia sendiri masih jauh harapannya dari keiinginan masyarakatnya. Maka, pengupayaan pembudayaan hukum di masyarakat yang dilandasi pada nilai kemanusiaan dan keadilan berdasarkan Ketuhanan yang Maha Esa agar terciptanya kesadaran hukum.
Sosialisasi Level Kewarganegaraan Lingkungan Sebagai Upaya Meningkatkan Kepedulian Lingkungan Bagi Mahasiswa Prodi PPKn FKIP ULM.
Authors: Fatimah Fatimah , Sarbaini Sarbaini , Fahlevi Reja 
Published: December 2023

Tujuan kegiatan pengabdian kepada masyarakat ini adalah untuk memberikan informasi tentang level kewargengaraan mahasiswa Prodi PPKn FKIP ULM, memberikan bimbingan cara mengidentifikasi masalah-masalah lingkungan yang ada disekitarnya, memberikan bimbingan mengimplementasikan kegiatan-kegiatan yang dapat memperbaiki alitas lingkungan disekitarnya. Metode yang digunakan adalah Pemberian informasi dalam bentuk sosialisasi melalui zoom meeting atau penyuluhan tentang konsep level kewarganegaraan kepada mahasiswa prodi PPKn FKIP ULM. Pada saat pelatihan, mayoritas mahasiswa dan masyarakat menerima dengan positif materi yang diberikan narasumber. Sebagian besar dari peserta begitu antusias mengikuti pelatihan, mereka banyak yang menyatakan jika masih banyak yang belum mengerti tentang konsep ataupun pelaksanaannya. Bahkan dari mereka tidak mengerti untuk apa konsep level kewarganegaraan ekologis ini. Hal ini tentunya membuka wawasan dan kesadaranm masyarakat bahwa pentingnya mereka memiliki pengetahuan. Berdasarkan simpulan yang dikemukan diatas, pelatih menyarankan kepada masyarkat agar selalu mulai peduli terhadap lingkungan sungai, agar lingkungan sungai kita tidak tercemar dan mengalami pendangkalan
Green Synthesis of Silver Nanoparticles from Medicinal Plants and Their Biological Applications: A Review
Authors: Saha Suchismita Chatterjee 
Published: December 2023

The manufacture of metal nanoparticles using plant extracts is one of the simplest, most useful, economical and environmentally advantageous approaches to decrease the usage of hazardous substances. Since the earliest days of human history, silver and silver salts have been employed, but silver nanoparticles (Ag NPs) have just recently reached light. Particularly in agriculture and medicine, these have been used as antibacterial, antifungal, and antioxidants. The current research on the environmentally friendly manufacture of silver nanoparticles (AgNPs) utilising various plant extracts and their potential use as antibacterial agents is summarised and explained in this review. The main objective is to provide a comprehensive and systematic review of how various factors affect the synthesis of green Ag NPs with antimicrobial properties. These factors include the type and concentration of plant extracts and phytochemicals, the solvent and temperature of extraction, and the temperature, pH, time, and concentration of the reaction. Recent advances in using different plants to yield Ag NPs with different sizes, shapes, and stabilities have been presented. It is currently demonstrated that Ag NPs prevent many bacteria and fungi from growing and multiplying by combining Ag/Ag+ with the biomolecules found inside the microbial cells. Antioxidants and reactive oxygen species that might be produced by Ag NPs, which, by preventing cell replication, cause apoptosis and cell death. SEM and TEM images of the nanoparticle-pathogen solution show that Ag NPs may enter cells and break through the cell wall since they are smaller than microorganisms. It has similarly been established that lesser Nps present additional risks than superior ones. Additionally, Ag NPs are used in packaging to prevent microbial contamination of food products. Ag NPs' toxicity is influenced by the size, concentration, pH of the media, and length of pathogen exposure. Comprehensive details have also been provided on the biogenic AgNPs' shape- and size-dependent antibacterial properties as well as the improved antimicrobial activities caused by the synergistic interaction of AgNPs with well-known commercial antibiotic medicines.
Programa Residência Pedagógica e suas contribuições ao processo de formação inicial de licenciandos em Matemática
Authors: Lima Francisco José de , Limeira Lucas Lavor , Araujo Neto João Nunes de 
Published: December 2023

Este trabalho tem o propósito de relatar experiências vividas durante o primeiro módulo do Programa Residência Pedagógica (PRP) e contribuições que o programa agrega à formação inicial do futuro professor de Matemática. O PRP é uma ação do Plano Nacional de Formação de Professores que possibilita ao discente adquirir experiência tanto em sala de aula como também no desenvolvimento da escrita acadêmica. Nesse sentido, o programa tem por finalidade agregar experiências teórico-práticas ao processo de formação docente, estabelecendo corresponsabilidade entre as instituições de Ensino Superior e as redes de Educação Básica, na perspectiva de valorizar o ensino. O primeiro módulo do programa consistiu em 138 horas distribuídas em ambientação, formação, observação, regência, planejamento e avaliação. Quanto à metodologia, trata-se de um relato de experiência de abordagem qualitativa, escrito a partir de registros de Diários de Bordo, desenvolvido no Núcleo Matemática, do IFCE campus Cedro. As atividades em sala de aula aconteceram no IFCE campus Cedro, em turmas de 1° e 2º ano do curso técnico em Mecânica Industrial. A experiência aponta que o PRP se constitui em um espaço onde o estudante de licenciatura tem a oportunidade de vivenciar diversas experiências que podem ajudar na melhoria do seu processo de formação. Dentre as vivências, destacam-se os encontros formativos, os planejamentos de aula, a preparação de materiais, as regências de sala de aula e os diálogos com docentes orientadores, professores preceptores e residentes, bem como a escrita dos diários de bordos, refletindo sobre suas contribuições. Conclui-se que as atividades desenvolvidas no programa muito contribuem com a formação inicial docente, uma vez que o licenciando necessita, ao longo de sua graduação familiarizar-se com a sala de aula.
Bi-amalgamations subject to j-clean and weakly j-clean properties
Authors: Adarbeh Khalid , Adarbeh Mohammad 
Published: December 2023

This paper establishes the necessary and sufficient conditions for a bi-amalgamation to inherit the J-clean and weakly J-clean properties in the commutative setting. The new results recover previous works carried on these rings in amalgamations and trivial extensions, also, they are used to provide new examples and counterexamples of J-clean and weakly J-clean rings arise as bi-amalgamations.
Углеводы - описание, польза, влияние на организм и лучшие источники
Authors: Елисеева Татьяна  , Ткачева Наталья  , Шелестун Анна  
Published: December 2023

В статье рассмотрены основные свойства углеводов и их воздействие на организм человека. Проведен систематический обзор современной специализированной литературы и актуальных научных данных. Указаны лучшие натуральные источники углеводов. Рассмотрено использование углеводов в различных видах медицины и эффективность их применения при различных заболеваниях. Отдельно проанализированы потенциально неблагоприятные эффекты углеводов на организм человека при определенных медицинских состояниях и заболеваниях.
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Expanded perlite additive for modification of properties of cement composites
Authors: Харитонов А.М. , Сидорова А.С. , Андреев Д.М. 
Published: December 2023

В статье рассмотрен опыт применения вспученного перлита в составах цементных композитов, степень его влияния на свойства бетонной смеси и затвердевшего бетона при введении его в эту смесь различными способами и в разных пропорциях. Сформулирована гипотеза о возможности применения мелкой фракции вспученного перлита в качестве агента внутреннего ухода в цементных системах с целью снизить усадку при твердении составов в условиях пониженной влажности среды. Получены экспериментальные зависимости усадки и проч­ности на сжатие и при изгибе от количества перлита в смеси, коэффициенты трещиностойкости, а также определено оптимальное содержание (в процентах массы сухой смеси) перлитового песка марки М‑75 группы ВПМ при введении его в качестве добавки.
The article discusses the experience of using expanded perlite in cement composites, the degree of its influence on the properties of the concrete mix and hardened concrete when added in various ways and at different concentrations. A hypothesis has been formulated about the possibility of using a fine fraction of expanded perlite as an internal cure agent in cement systems in order to reduce shrinkage during hardening of compositions under conditions of low environmental humidity. Experimental dependences of the shrinkage value, compressive and bending strength, crack resistance coefficients are obtained, and the optimal concentration of perlite sand grade M-75 of the EPF group is determined when it is introduced as an additive by weight of the dry mixture.
The Duties and Liability of Notary as Public Official in Criminal Law Perspective
Authors: Kesuma Jaya 
Published: December 2023

A notary always leads to criminal relations in their daily profession. The Notary has to the extent their precautionary principle to prevent the malpractice practice. Mant regulations and the ethics code of the profession must have appropriate attention to protect their profession. Duties and Responsibilities of the Notary as a General Officer of the Criminal Law Perspective, which constitutes the scope of the parameters of the Notary's actions in his authority. With the hope that the Notary profession must maintain the integrity and nobleness in the future, the Notary will be a partner of law enforcement officers in providing the best legal services for the community.
L’outil Ultrad de La Presse Canadienne : la traduction automatique dans un contexte journalistique
Authors: Poirier Éric André , Roy Jean-Hugues 
Published: December 2023

En 2018, La Presse Canadienne a mis au point Ultrad, un système de traduction automatique (TA). Ultrad est un des rares systèmes de TA à être utilisé quotidiennement par des journalistes au Canada. Toutes les traductions d’Ultrad sont révisées avant d’être publiées dans la langue cible. Notre article porte sur l’évaluation des traductions fournies par l’outil et sur les révisions apportées par les journalistes de l’agence de presse. Pour mener à bien ce travail, nous avons dépouillé un échantillon de 148 articles en anglais comportant une version traduite automatiquement en français et une version révisée par un rédacteur ou une rédactrice de La Presse Canadienne. L’évaluation des traductions, d’une part, et, d’autre part, la comparaison entre les textes traduits automatiquement et les textes révisés en post-édition (PE) ont reposé sur différentes méthodes d’analyse outillées : la comparaison des fréquences de mots, de l’alignement des paragraphes et de leur sous-segmentation en phrases graphiques pour chacun des deux groupes de bitextes (anglais avec la traduction brute, puis anglais avec la version révisée en PE) et des volumes informationnels des paires de segments; la distance euclidienne (DE) à trois dimensions entre segments source et cible et la correction linguistique fournie par le logiciel de correction linguistiqueAntidotesur la totalité des articles révisés. Notre étude est l’une des rares à s’être penchée sur l’utilisation de la TA par des journalistes. Elle met en évidence les lacunes de la TA et le caractère incontournable des interventions humaines en PE, même si ces interventions ne sont pas infaillibles.
Emergency Department Care for Children During the 2022 Viral Respiratory Illness Surge
Authors: Janke Alexander T. , Mangus Courtney W. , Fung Christopher M. , Kamdar Neil , Macy Michelle L. , Nypaver Michele M. , Kocher Keith E. 
Published: December 2023

ImportancePediatric readiness is essential for all emergency departments (EDs). Children’s experience of care may differ according to operational challenges in children’s hospitals, community hospitals, and rural EDs caused by recurring and sometimes unpredictable viral illness surges.ObjectiveTo describe wait times, lengths of stay (LOS), and ED revisits across diverse EDs participating in a statewide quality collaborative during a surge in visits in 2022.Design, Setting, and ParticipantsThis retrospective cohort study included 25 EDs from the Michigan Emergency Department Improvement Collaborative data registry from January 1, 2021, through December 31, 2022. Pediatric (patient age &amp;lt;18 years) encounters for viral and respiratory conditions were analyzed, comparing wait times, LOS, and ED revisit rates for children’s hospital, urban pediatric high-volume (≥10% of overall visits), urban pediatric low-volume (&amp;lt;10% of overall visits), and rural EDs.ExposuresSurge in ED visit volumes for children with viral and respiratory illnesses from September 1 through December 31, 2022.Main Outcomes and MeasuresProlonged ED visit wait times (arrival to clinician assigned, &amp;gt;4 hours), prolonged LOS (arrival to departure, &amp;gt;12 hours), and ED revisit rate (ED discharge and return within 72 hours).ResultsA total of 2 761 361 ED visits across 25 EDs in 2021 and 2022 were included. From September 1 to December 31, 2022, there were 301 688 pediatric visits for viral and respiratory illness, an increase of 71.8% over the 4 preceding months and 15.7% over the same period in 2021. At children’s hospitals during the surge, 8.0% of visits had prolonged wait times longer than 4 hours, 8.6% had prolonged LOS longer than 12 hours, and 42 revisits occurred per 1000 ED visits. Prolonged wait times were rare among other sites. However, prolonged LOS affected 425 visits (2.2%) in urban high-pediatric volume EDs, 133 (2.6%) in urban pediatric low-volume EDs, and 176 (3.1%) in rural EDs. High visit volumes were associated with increased ED revisits across sites.Conclusions and RelevanceIn this cohort study of more than 2.7 million ED visits, a pediatric viral illness surge was associated with different pediatric acute care across EDs in the state. Clinical management pathways and quality improvement efforts may more effectively mitigate dangerous clinical conditions with strong collaborative relationships across EDs and setting of care.
Mesoscale Clusters in the Crystallisation of Organic Molecules
Authors: Barua Harsh , Svärd Michael , Rasmuson Åke C. , Hudson Sarah P. , Cookman Jennifer 
Published: December 2023

AbstractThe early stages of the molecular self‐assembly pathway leading to crystal nucleation have a significant influence on the properties and purity of organic materials. This mini review collates the work on organic mesoscale clusters and discusses their importance in nucleation processes, with a particular focus on their critical properties and susceptibility to sample treatment parameters. This is accomplished by a review of detection methods, including dynamic light scattering, nanoparticle tracking analysis, small angle X‐ray scattering, and transmission electron microscopy. Considering the challenges associated with crystallisation of flexible and large‐molecule active pharmaceutical ingredients, the dynamic nature of mesoscale clusters has the potential to expand the discovery of novel crystal forms. By collating literature on mesoscale clusters for organic molecules, a more comprehensive understanding of their role in nucleation will evolve and can guide further research efforts.
Simple and Efficient Synthesis of Novel Tetramers with Enhanced Glass Transition Temperature for High‐Performance and Stable Organic Solar Cells
Authors: Zhang Chen , Song Jiali , Ye Linglong , Li Xiaoming , Jee Min Hun , Woo Han Young , Sun Yanming 
Published: December 2023

AbstractOligomer acceptors in organic solar cells (OSCs) have garnered substantial attention owing to their impressive power conversion efficiency (PCE) and long‐term stability. However, the simple and efficient synthesis of oligomer acceptors with higher glass transition temperatures (Tg) remains a formidable challenge. In this study, we propose an innovative strategy for the synthesis of tetramers, denoted as Tet‐n, with elevated Tgs, achieved through only two consecutive Stille coupling reactions. Importantly, our strategy significantly reduces the redundancy in reaction steps compared to conventional methods for linear tetramer synthesis, thereby improving both reaction efficiency and yield. Furthermore, the OSC based on PM6:Tet‐1 attains a high PCE of 17.32 %, and the PM6:L8‐BO:Tet‐1 ternary device achieves an even more higher PCE of 19.31 %. Remarkably, the binary device based on the Tet‐1 tetramer demonstrates outstanding operational stability, retaining 80 % of the initial efficiency (T80) even after 1706 h of continuous illumination, which is primarily attributed to the enhanced Tg (247 °C) and lower diffusion coefficient (1.56×10−27 cm2 s−1). This work demonstrates the effectiveness of our proposed approach in the straightforward and efficient synthesis of tetramers materials with higher Tgs, thus offering a viable pathway for developing high‐efficiency and stable OSCs.
Dynamic Exchange in 3D Cell Culture Hydrogels Based on Crosslinking of Cyclic Thiosulfinates
Authors: Janssen Merel L. , Liu Tingxian , Özel Mertcan , Bril Maaike , Prasad Thelu Hari Veera , E. Kieltyka Roxanne 
Published: December 2023

AbstractDynamic polymer materials are highly valued substrates for 3D cell culture due to their viscoelasticity, a time‐dependent mechanical property that can be tuned to resemble the energy dissipation of native tissues. Herein, we report the coupling of a cyclic thiosulfinate, mono‐S‐oxo‐4‐methyl asparagusic acid, to a 4‐arm PEG‐OH to prepare a disulfide‐based dynamic covalent hydrogel with the addition of 4‐arm PEG‐thiol. Ring opening of the cyclic thiosulfinate by nucleophilic substitution results in the rapid formation of a network showing a viscoelastic fluid‐like behaviour and relaxation rates modulated by thiol content through thiol‐disulfide exchange, whereas its viscoelastic behaviour upon application as a small molecule linear crosslinker is solid‐like. Further introduction of 4‐arm PEG‐vinylsulfone in the network yields a hydrogel with weeks‐long cell culture stability, permitting 3D culture of cell types that lack robust proliferation, such as human pluripotent stem cell‐derived cardiomyocytes (hPSC‐CMs). These cells display native behaviours such as cell elongation and spontaneous beating as a function of the hydrogel's mechanical properties. We demonstrate that the mode of dynamic cyclic thiosulfinate crosslinker presentation within the network can result in different stress relaxation profiles, opening the door to model tissues with disparate mechanics in 3D cell culture.
Single‐Atom Manganese‐Catalyzed Oxygen Evolution Drives the Electrochemical Oxidation of Silane to Silanol
Authors: Tang Hai‐Tao , Zhou He‐Yang , Pan Ying‐Ming , Zhang Jia‐Lan , Cui Fei‐Hu , Li Wen‐Hao , Wang Dingsheng 
Published: December 2023

AbstractThe oxygen evolution reaction (OER), characterized by a four‐electron transfer kinetic process, represents a significant bottleneck in improving the efficiency of hydrogen production from water electrolysis. Consequently, extensive research efforts have been directed towards identifying single‐atom electrocatalysts with exceptional OER performance. Despite the comprehensive understanding of the OER mechanism, its application to other valuable synthetic reactions has been limited. Herein, we leverage the MOOH intermediate, a key species in the Mn−N−C single‐atom catalyst (Mn‐SA@NC), which can be cyclically delivered in the OER. We exploit this intermediate’ s capability to facilitate electrophilic transfer with silane, enabling efficient silane oxidation under electrochemical conditions. The SAC electrocatalytic system exhibits remarkable performance with catalyst loadings as low as 600 ppm and an exceptional turnover number of 9132. Furthermore, the catalytic method demonstrates stability under a 10 mmol flow chemistry setup. By serving as an OER electrocatalyst, the Mn‐SA@NC drives the entire reaction, establishing a practical Mn SAC‐catalyzed organic electrosynthesis system. This synthesis approach not only presents a promising avenue for the utilization of electrocatalytic OER but also highlights the potential of SACs as an attractive platform for organic electrosynthesis investigations.