bluuebunny/crossref_metadata_2025_split huggingface dataset:
The industrial waste land of Mortagne-du-Nord (59) – II – Oxidizing alteration of the slags, hydrochemistry, geochemical modelling and remediation proposal
Authors: Schmitt Jean-Michel , Huet-Taillanter Sabine , Thiry Médard 
Published: June 2005

Abstract
The slag backfills of the former sulfuric acid factory of Mortagne-du-Nord (59) are sulfide- and metal-rich (Zn, Pb, Cd). Sulfide oxidation leads to acidification of surficial groundwater and the dispersal of the metals into the environment, by flow towards the rivers which run along the site. The surficial groundwater pHs fall between 2.5 and 6.8 and the metal content is very high, reaching in places 6 000 mg/L of Zn, 2.5 mg/L of Pb and 600 mg/L of Cd. To conceive a remediation scenario, we tried beforehand to understand the phenomena that govern the oxidation of the sulfides. For this purpose, water levels and water compositions have been surveyed every 2 months during 4 years, a geochemical simulation of the alteration/oxidation has been proposed and leaching tests have been performed.
The survey of the water table level and periodical chemical analyses of the groundwater have shown that the slag alteration is reactivated when the water table drops until the sulfide-bearing ≪ fresh ≫ slags are unsaturated. The analysed waters always show an unbalanced negative ionic charge. Geochemical calculations allow to propose several equilibrium models of the waters and to conclude that the presence of thiosulfates (S2O23−) in the original waters most likely explains the observed ionic disequilibrium. The geochemical modelling of the slag alteration, first by percolation in unsaturated conditions (allowing O2 supply) and then under saturated conditions (without O2 renewal), reproduces satisfactorily the chemistry of sampled groundwaters. Leaching tests of the slags have been performed in the laboratory both by percolation (unsatured environment) and by cirulation (saturated and closed environment). These tests allowed to obtain alteration solutions comparable to the waters sampled on site, with progressive ≪ aging ≫ of the material, in agreement with the decrease of the dissolved metals observed on site during the 4-year survey. Moreover, the tests confirm the importance of the oxygen supply in the reactivation of the alteration.
The evolution of the groundwater chemistry, the thermodynamic modelling, as well as the leaching experiments allow to determine with some details the alteration/oxidation mechanism and show that: (1) alteration is actived or reactived after a drop of the water table within the sulfide-bearing facies, (2) the oxygen supply by diffusion in the poral air is the driving force of slag oxidation, and (3) maintaining the backfills in saturated conditions practically stops alteration.
The geochemical evolution of the site is directly related to its history, with successive re-profiling of the channels which have lead to a lowering of the water table of about 2 m. The remediation should be focused on in-situ processing (water treatment aimed to lower acidity, active barriers, …) rather than on ex-situ (excavation) solutions.
Ordovician acritarchs of China and their utility for global palaeobiogeography
Authors: Li Jun , Servais Thomas 
Published: June 2005

Abstract
Since the 1970s, acritarch workers have recognized two distinct geographic acritarch assemblages in the Ordovician. The first assemblage occurs in the late Tremadoc in low latitude areas. This assemblage, recently redefined by Volkova [1997], has been attributed to warm-water environments. A second “Mediterranean” or “peri-Gondwanan” province, attributed to high latitudes in the southern hemisphere, can easily be recognized in late Tremadoc to Arenig acritarch assemblages. This second palaeogeographic “province”, defined by Li [1989] is distributed around the border of Gondwana in a zone reaching from Argentina through northern Africa and peri-Gondwana up to Iran, Pakistan and southern China. In the present work we propose an initial simplified, tentative model of the latitudinal distribution of selected early to middle Ordovician acritarchs. Both “provinces” are plotted on the recent palaeogeographical reconstruction of the early Ordovician of Li and Powell [2001]. It appears that the first “province” is limited to low and intermediate latitudes, i.e., to warmer water environments. However, the generally adopted interpretation that the so called “Mediterranean” or “peri-Gondwanan” geographical assemblage is principally controlled by palaeolatitudes and is considered to be typically “cold-water” has to be revised, because the distribution of this “province” appears related more to the continental arrangement along the Gondwana border than to latitudes. This distribution shows some similarities with recent investigations in Silurian acritarch palaeogeography [Le Hérissé and Gourvennec, 1995] that provides evidence that the global distribution of Silurian acritarchs is under the interdependence of continental arrangement, latitudinal position, environmental conditions and oceanic currents, and that it is not simply latitudinally controlled as previous interpretations have suggested. The Yangtze Plaform of southern China presents elements of both early to middle Ordovician “provinces”, i.e., from both the “warm-water” and the “peri-Gondwanan” geographic assemblages. The South China Plate is therefore one of the areas that shows typically mixed assemblages. Although it remains difficult to define clearly a “Baltic” province, it is important to note that between the latest Tremadoc and the early Llanvirn a clear distinction of the acritarch assemblages between peri-Gondwana and Baltica is possible.
A new specimen of Spinosaurus (Dinosauria, Theropoda) from the Lower Cretaceous of Tunisia, with remarks on the evolutionary history of the Spinosauridae
Authors: Buffetaut Eric , Ouaja Mohamed 
Published: June 2005

Abstract
A newly discovered incomplete dinosaur dentary from the Chenini Sandstones (early Albian) of Jebel Miteur (Tataouine Governorate, southern Tunisia) is extremely similar to the corresponding part of the type of Spinosaurus aegyptiacus STROMER, 1915, and is identified as Spinosaurus cf. aegyptiacus. A review of African spinosaurids shows that baryonychines were present in the Aptian, and apparently became replaced by spinosaurines in the Albian and Cenomanian, perhaps as part of a more general faunal change between the Aptian and Albian. Spinosaurines may have been derived from the less advanced baryonychines. Several alternative hypotheses about the biogeographical history of the Spinosauridae are discussed.
Early record of tectonic magnetic fabric during inversion of a sedimentary basin Short review and examples from the Corbières transfer zone (France)
Authors: De Lamotte Dominique Frizon , Souque Christine , Grelaud Sylvain , Robion Philippe 
Published: June 2005

Abstract
An integrated study combining anisotropy of magnetic susceptibility (magnetic fabric) and analysis of meso-scale structures is presented. The studied sites, which belong to the Corbières transfer zone (France), suffered a clear polyphase deformation. The magnetic fabric is of tectonic origin and records an early layer parallel shortening. In general, this primary fabric is not altered by later deformations including folding. However, secondary fabrics have been observed in the vicinity of major faults. They are probably related to tectonically driven fluids migrating along these planes. Consequences on interpretation and use of magnetic fabrics in inverted sedimentary basins are discussed.
Cartography of the Ronda peridotite (Spain) by hyperspectral remote sensing
Authors: Launeau Patrick , Sotin Christophe , Girardeau Jacques 
Published: June 2005

Abstract
The Ronda Peridotite, south of Andalusia (Spain), was imaged by AVIRIS in 1991 and partially sampled by us in the field with a GER 3700 spectrometer in 1997 in order to get experience in processing hyperpectral images of planetary surfaces with probes such as ISM Phobos (1989), OMEGA Mars Express (2003) and VIMS Cassini (2004). The high spectral resolution of the images (224 channels from 400 to 2455 nm) is necessary to conduct geological analysis with remote petrological determinations of rock types. On Earth, it is also necessary to determine species of vegetation because of their strong influence in mapping lithology, even in dry areas like the Ronda peridotite.
The Ronda AVIRIS image was first processed to infer geological features using photo-interpretation of colour composite images extracted from 150 useful channels compared to geological maps and checked on the field during the campaign of July 97. This allows us to distinguish easily the peridotite massif from its surrounding rocks and its own serpentine zoning.
Since this work followed the work of Chabrillat et al. [2000] we chose to explore the AVIRIS data with other techniques. We chose to remove the contribution of the atmosphere with spectra collected in the field on a white target at various altitudes and to remove the main vegetation with spectra of the most characteristic vegetation of the peridotite. In both cases we first estimated the amount of atmosphere and vegetation with band ratios and remove them with two similar empiric corrections of the reflectance.
From the spectroscopy data, after removal of the atmosphere and some vegetation signal, we were able to clearly distinguish the crustal rocks from the mantle ones, as well as compositional variations due to pyroxene and mostly serpentine abundance within the peridotites. Hyperspectral infrared spectrometry will provide good geological mapping of the main rocks on planetary surfaces, if images can also be calibrated with in situ field measurements which will not miss any unexpected component. However, some ambiguities remain between certain types of rock which have close mineralogical composition (e.g. harzburgite compared to lherzolite) or which have resulting spectra very similar to each other (plagioclase and lizardite in peridotites). Some other ambiguities between spectra are also introduced by techniques of analysis based on relative reflectance. By not taking into account absolute intensity of the reflectance, because of roughness and topographic shading effects, small mineral variations are not always visible.
The syn-rift sedimentary cover of the North Biscay Margin (bay of Biscay): from new reflection seismic data
Authors: Thinon Isabelle , Réhault Jean-Pierre , Fidalgo-González Luis 
Published: June 2005

Abstract
The Armorican Basin is a deep sedimentary basin lying at the footside of the North Bay of Biscay. From previous scattered inadequate data, the age and nature of this basin, oceanic domain or deep part of the Armorican margin itself were largely speculated. From this new seismo-stratigraphic study based on a dense seismic cover, the sedimentation within the Armorican Basin is beginning in the Aptian times, during the last tectonic rifting episode of the margin. The first sediments formation identified as the « 3B layer » is characterised on the profiles by a chaotic and transparent seismic facies and was emplaced by slumping process when the margin collapsed, at the final rifting phase, just before the oceanic accretion.
The new seismic reflection data give also some informations on the polyphased evolution of the North Biscay Margin during the rifting period. Two main events occurred during the Lower Cretaceous times (the first one is pre-Berriasian, the second is Aptian), separated by a quiet tectonic period including the Upper Berriasian and Lower Aptian times. The first event is responsible of the margin tectonic structuration in some blocks, the second of collapsing and the emplacement of the allochthonous sediments (3B layer) in the Armorican Basin.
Early Ordovician acritarchs of the Lierneux Member (Stavelot Inlier, Belgium): stratigraphy and palaeobiogeography
Authors: Vanguestaine Michel , Servais Thomas 
Published: June 2005

Abstract
The messaoudensis-trifidum acritarch microflora is currently considered to be characteristic of latest Tremadocian-earliest Arenigian cold-water environments on the periphery of Gondwana, at high latitudes in the southern hemisphere. Integrated biostratigraphical studies on both acritarchs and graptolites are available from two areas of peri-Gondwana, the Lake District (northwestern England) and the Sierra Morena (southwestern Spain). The assemblage was also recorded from other areas on the northern border of the Gondwana continent where macrofossils are generally not available: from southern Ireland, the Isle of Man, southern Wales, the island of Rügen in northern Germany, the Prague Basin in the Czech Republic, and southern Turkey. While it appears that the messaoudensis-trifidum acritarch assemblage is limited to cold-water environments in localities on the periphery of Gondwana, some of its elements can be found in other areas. Some taxa, but not the complete assemblage, have been identified in the eastern Cordillera of Argentina, and some species of the assemblage are cited from continents which were situated at intermediate latitudes in warmer waters: some elements of the assemblage are described from localities of Baltica (from Norway, Estonia and the St. Petersburg area in northwestern Russia) and from the Yangzte Platform in southern China. In these regions, typical representatives of the messaoudensis-trifidum assemblage co-occur with taxa typical of temperate and warm-water areas.
The present paper reports the discovery of the messaoudensis-trifidum acritarch assemblage in the Lierneux Member (Stavelot Inlier, Belgium). The Lierneux Member, which constitutes the uppermost part of the Jalhay Formation (formerly Salmian 1c) in the Stavelot Inlier, was first dated as late Tremadocian by Vanguestaine [1992a]. Following recent stratigraphical conclusions based on the detailed investigations of the messaoudensis-trifidum assemblage from different sequences of peri-Gondwana, the age of the Lierneux Member recovered from the Chevron borehole in the Stavelot Massif can now be confirmed as being probably latest Tremadocian. The discovery of the messaoudensis-trifidum assemblage in the Stavelot Inlier provides further evidence for the palaeogeographical distribution of the assemblage on the northern border of Gondwana and allows tentative correlations between eastern Belgium and northern Germany.
Ashgillian graptolite fauna of the Yangtze region and the biogeographical distribution of diversity in the latest Ordovician
Authors: Chen Xu , Melchin Michael J. , Fan Jun-xuan , Mitchell Charles E. 
Published: June 2005

Abstract
Ashgillian graptolites have been described and recorded globally from 15 different paleoplates. The most diverse graptolite faunas are from the Yangtze region, South China, including 28 genera and 96 species. Among them, 25 genera and 73 species belong to the DDO fauna (Dicranograptidae – Diplograptidae – Orthograptidae fauna), and only three genera but 23 species belong to the N fauna (Normalograptidae fauna). Among the Yangtze graptolite fauna there are six endemic genera and 51 endemic species, which represent 21% and 52%, respectively, of the Ashgillian fauna in the region. This is an unusually high level of endemism. Endemic species are present in both the endemic and the cosmopolitan genera.
A late Ashgillian stepwise extinction event has recently been recognized, based on graptolite diversity changes and graphic correlation. This begins with a major extinction from the Diceratograptus mirus Subzone to the middle Normalograptus extraordinarius-N. ojsuensis Zone, and ends with a minor extinction prior to the end of the Normalograptus persculptus Zone. Graptolite faunal replacement of the DDO fauna by the N fauna occurred throughout this interval.
A comparison of Ashgillian graptolite diversity between the Yangtze region and other regions indicates that two different biogeographical realms existed in mid-Ashgillian time. A moderate-diversity graptolite fauna is present in the low-middle latitude realm, which includes South Scotland, Kazakhstan, Kolyma, Nevada, Yukon, Canadian Arctic, SE Australia. The Yangtze region was located in this realm, but was characterized by a very high-diversity fauna. Some other localities, including eastern Avalonia (Wales and England), the Argentina Precordillera, and Bohemia, which mainly represent the mid- to high-latitude realm, contain the lower-diversity mid-Ashgillian assemblages. This biogeographical distribution suggests a latitudinal diversity gradient, which may be controlled mainly by water temperature. This climate gradient becomes much less evident by late Hirnantian time in which most parts of the world have a relatively low diversity fauna totally dominated by normalograptid species, many of which appear to have been eurytopic. Throughout the Ashgillian, however, the Yangtze platform shows a high diversity and long persistence of DDO taxa the mass extinction interval. This may be a consequence of the semi-restricted nature of the basin in which conditions relatively favorable to graptolite survival and speciation existed throughout all or most of the Hirnantian.
Some Cretaceous long-looped terebratulide brachiopods analysed in the light of the diversity observed in the ontogeny of Recent representatives
Authors: Gaspard Danièle 
Published: June 2005

Abstract
The shape of the loop is of prime importance in brachiopod terebratulide classification and has been widely discussed and revised [Williams et al., 1996]. In the Rhynchonelliforma, we have focused our attention on the Terebratellidina, long-looped brachiopods with a wide-range diversity. The observation of its internal structure in recent representatives, investigated from the early growth stages, using the Scanning Electron Microscope (S.E.M.), demonstrates the complexity of its growth. Two main growth types of the descending branches are expressed during early ontogeny [Gaspard, 2002], followed in both cases by forward growth in opposite directions, with a brachial ribbon attached or unattached to the median septum. The purpose of such observations is to find in the fossil records similar growth types. An approach from the recent representatives allows a better knowledge of the Cretaceous taxa considered, even if the only way to recognise the loop is by means of transverse serial sections. The study of the recent terebratellidine loop facilitates the establishment of links between species from different geological periods. It helps to determine superfamilial distinctions and to find possible ancestors of recent terebratellidines.
3-D modelling of salt and heat transport during the 248 m.y. evolution of the Paris basin : diagenetic implications
Authors: Gonçalvès Julio , Violette Sophie , Robin Cécile , Pagel Maurice , Guillocheau François , de Marsily Ghislain , Bruel Dominique , Ledoux Emmanuel 
Published: June 2005

Abstract
A 3-D model of the Paris basin was constructed to reconstitute its 248 m.y. geologic history from the Trias to the present. The model is based on detailed stratigraphic and lithographic data from about 1,100 petroleum drillings. Its scale is regional and it covers a surface area of 700,000 km2, which exceeds the present extent of the basin in order to allow the paleogeographic evolution of the European plate to be taken into account. The geological history is simulated with the numerical model NEWBAS from the Ecole des Mines de Paris.
The model simulates sedimentation, erosion, compaction, fluid flow and processes of solute and heat transport. The objective of this article is to demonstrate the value of this type of modelling for estimating and quantifying the role of fluid circulation in geological processes. Studies of diagenetic cements in the Dogger and Keuper aquifers in the Paris basin have often led their authors to consider the involvement of regional fluid circulation. These studies provide estimates of paleotemperature and paleosalinity which impose constraints on the modelling but the latter may, in turn, contribute to date the events and estimate the relevant processes. By reconstructing heat and salt transport, as proposed in this article, it is therefore possible to define the influence of hydrodynamics on these processes. The history of heat and salt in the basin is shown at various stages on a representative NW-SE cross-section of a present-day flow line which is also valid for Tertiary times. We demonstrate that the role of hydrodynamics may be predominant for salt transport by gravity-driven flow, which explains the salinity increase in the Keuper aquifer and the role of the Bray fault in the salinisation of the Dogger. Although the heat transport is dominated by the conductive component, it is also influenced by the hydrodynamics with a possible convective cooling effect when the head in the aquifers increased at the end of the Tertiary erosion period. This may partly explain the higher temperatures, deduced from fluid inclusions in the Keuper, at the end of the chalk deposition as compared to present ones. According to our simulations, the early Tertiary is the period most compatible with the diagenetic observations for thermal (maximum burial and convective cooling effect) and chemical reasons (topography allowing migration of brines in the Keuper and the Dogger).
A generalization of Cope’s rule
Authors: Guex Jean 
Published: June 2005

Abstract
For numerous shelly invertebrates, Cope’s rule is shown in this paper to merely describe the particular case where volume increase is strictly coupled with diameter or length. Allometries, which are frequently observed in the evolution of the shells’ geometry, mean that their size, volume and surface can vary independently. The consequences of this can be summarized as follows : 1) volume increase not coupled with an increase of diameter or length of the organisms generates increasing involution and/or lateral width in the shell of cephalopods, foraminifera and radiolarians ; 2) an increase of the biomineralizing surface, not coupled with volume increase, generates increasing apparent complexity in the sutures and growth lines in ammonites, and an increase in the complexity and number of chambers in foraminifera.
Control of Permian and Triassic faults on Alpine basement deformation in the Argentera massif (external southern French Alps)
Authors: Delteil Jean , Stephan Jean-François , Attal Mikaël 
Published: June 2005

Abstract
Structural investigations reveal intense and heterogeneous deformation of the sedimentary cover attached to the basement complex of the southern Argentera and Barrot massifs (southernmost External Basement Massifs of the French Alps). Permian and early Triassic syn-depositional extensional tectonics imparted a tilted block pattern to the massifs. An early Miocene first stage of Alpine compression caused pervasive cleavage. This cleavage was controlled by the former pre-existing faults but is nevertheless consistent with NNE contraction. Where regional shortening is orthogonal to the trend of pre-existing faults the pervasive deformation produced either irrotational compressional strain (where no fault inversion occurred), or rotational compressional strain involving syn-cleavage shearing (where faults with favorable paleo-dip were inverted). Where the shortening direction is oblique to the paleo-fault trends, a component of strike-slip movement may locally prevail. A 22 %, N020o directed horizontal shortening, of 11 km, has been calculated based on deformed sedimentary markers in the Permian series and parallel folds in Lower Triassic quartzite. A shallower deformation as brittle reverse faults postdates the cleavage at the southwestern tip of the Argentera Massif and accounts for 4 km of extra shortening. Both types of deformation are connected at depth to a crustal blind thrust system and the Argentera Massif is over-thrust to the south-southwest. The observed strain indicates the Argentera Massif area underwent, from earliest Miocene to Present, a NNE to N rotating compression at distance from the left-lateral southwestern boundary of the Adria block.