bluuebunny/crossref_metadata_2025_split huggingface dataset:
Spondyloenchondrodysplasia: Clinical variability in three cases
Authors: Tüysüz Beyhan , Arapoglu Müjde , Üngür Savaş 
Published: April 2004

AbstractSpondyloenchondrodysplasia is a very rare skeletal dysplasia in which multiple enchondromata exist in the metaphyses of the long bones with platyspondyly. We present three patients (two of them are sibs) with spondyloenchondrodysplasia. The first patient was a 10‐year‐old boy, who had short stature and enchondromatous‐like lesions in the metaphyses of the long bones and platyspondyly on radiography. His older sister (21‐years old) had received growth hormone therapy 12 years earlier due to short stature, and her radiological findings were similar but milder than her brother. Both the sibs had normal intelligence and no calcification of the basal ganglia. The third patient was a 6‐year‐old boy who had short stature, mental retardation, enchondromatous‐like lesions in the metaphyses of the long bones and platyspondyly. His cranial BT showed calcification of basal ganglia. The findings of the two sibs in the first family were compatible with spondyloenchondrodysplasia. The difference in clinical severity between the siblings shows the variability within the family. The third case with mental retardation and the presence of intracranial calcifications is compatible with spondyloenchondrodysplasia with basal ganglia calcification. In conclusion, we suggest that family screening and cranial imaging for the presence of intracranial calcifications should be considered in every patient with the diagnosis of spondyloenchondrodysplasia. © 2004 Wiley‐Liss, Inc.
The effect of short, high intensity magnetic field pulses on the healing of skin wounds in rats
Authors: Milgram Joshua , Shahar Ron , Levin‐Harrus Tal , Kass Philip 
Published: April 2004

AbstractThe object of this study was to examine the effect of high intensity, short duration pulsed electromagnetic fields (PEMF) on the healing of full thickness skin wounds in rats. Full thickness skin wounds were surgically created in two groups of Sprague–Dawley male rats. The rats were randomly divided into two groups, each containing 20 rats. Animals in the treatment group received treatments with the PEMF device on day 0, 3, 7, 9, 12, 14, 17, and 22, while the rats in the control group were subjected to the same procedure, but with the PEMF device not activated. Photographs of the surgically created wounds were obtained on day 0, 3, 7, 9, 12, 14, 17, and 22. Wound contraction (WC), wound epithelialization (WE), non‐healed wound, and contraction–epithelialization (CE) ratio were calculated for each wound. No significant difference was found between the two groups for the parameters of WC, WE, non‐healed wound, and CE ratio. A significant group × time interaction was found for WE and CE ratio. This type of PEMF did not have a significantly beneficial effect on wound healing. Wounds in the PEMF treated group were relatively less contracted and showed a compensatory increase in epithelialization in the early stages of wound repair. Bioelectromagnetics 25:271–277, 2004. © 2004 Wiley‐Liss, Inc.
Antibody‐Catalyzed Benzoin Oxidation as a Mechanistic Probe for Nucleophilic Catalysis by an Active Site Lysine
Authors: Sklute Genia , Oizerowich Rachel , Shulman Hagit , Keinan Ehud 
Published: April 2004

AbstractAldolase antibody 24H6, which was obtained by reactive immunization against a 1,3‐diketone hapten, is shown to catalyze additional reactions, including H/D exchange and oxidation reactions. Comparison of the H/D exchange reaction at the α‐position of a wide range of aldehydes and ketones by 24H6 and by other aldolase antibodies, such as 38C2, pointed at the significantly larger size of the 24H6 active site. This property allowed for the catalysis of the oxidation of substituted benzoins to benzils by potassium ferricyanide. This reaction was used as a mechanistic probe to learn about the initial steps of the 24H6‐catalyzed aldol condensation reaction. The Hammett correlation (ρ=4.7) of log(kcat) versus the substituent constant, σ, revealed that the reaction involves rapid formation of a Schiff base intermediate from the ketone and an active site lysine residue. The rate‐limiting step in this oxidation reaction is the conversion of the Schiff base to an enamine intermediate. In addition, linear correlation (ρ=3.13) was found between log(KM) and σ, indicating that electronic rather than steric factors are dominant in the antibody–substrate binding phenomenon and confirming that the reversible formation of a Schiff base intermediate comprises part of the substrate‐binding mechanism.
N,N′‐Ethylenebis(pyridoxylideneiminato) and N,N′‐Ethylenebis(pyridoxylaminato): Synthesis, Characterization, Potentiometric, Spectroscopic, and DFT Studies of Their Vanadium(IV) and Vanadium(V) Complexes
Authors: Correia Isabel , Costa Pessoa Joāo , Duarte M. Teresa , Henriques Rui T. , Piedade M. Fátima M. , Veiros Luís F. , Jakusch Tamás , Kiss Tamás , Dörnyei Ágnes , Castro M. Margarida C. A. , Geraldes Carlos F. G. C. , Avecilla Fernando 
Published: April 2004

AbstractThe Schiff base N,N′‐ethylenebis(pyridoxylideneiminato) (H2pyr2en, 1) was synthesized by reaction of pyridoxal with ethylenediamine; reduction of H2pyr2en with NaBH4 yielded the reduced Schiff base N,N′‐ethylenebis(pyridoxylaminato) (H2Rpyr2en, 2); their crystal structures were determined by X‐ray diffraction. The totally protonated forms of 1 and 2 correspond to H6L4+, and all protonation constants were determined by pH‐potentiometric and 1H NMR titrations. Several vanadium(IV) and vanadium(V) complexes of these and other related ligands were prepared and characterized in solution and in the solid state. The X‐ray crystal structure of [VVO2(HRpyr2en)] shows the metal in a distorted octahedral geometry, with the ligand coordinated through the N‐amine and O‐phenolato moieties, with one of the pyridine‐N atoms protonated. Crystals of [(VVO2)2(pyren)2]⋅2 H2O were obtained from solutions containing H2pyr2en and oxovanadium(IV), where Hpyren is the “half” Schiff base of pyridoxal and ethylenediamine. The complexation of VIVO2+ and VVO2+ with H2pyr2en, H2Rpyr2en and pyridoxamine in aqueous solution were studied by pH‐potentiometry, UV/Vis absorption spectrophotometry, as well as by EPR spectroscopy for the VIVO systems and 1H and 51V NMR spectroscopy for the VVO2 systems. Very significant differences in the metal‐binding abilities of the ligands were found. Both 1 and 2 act as tetradentate ligands. H2Rpyr2en is stable to hydrolysis and several isomers form in solution, namely cis–trans type complexes with VIVO, and α‐cis‐ and β‐cis‐type complexes with VVO2. The pyridinium‐N atoms of the pyridoxal rings do not take part in the coordination but are involved in acid–base reactions that affect the number, type, and relative amount of the isomers of the VIVO–H2Rpyr2en and VVO2–H2Rpyr2en complexes present in solution. DFT calculations were carried out and support the formation and identification of the isomers detected by EPR or NMR spectroscopy, and the strong equatorial and axial binding of the O‐phenolato in VIVO and VVO2 complexes. Moreover, the DFT calculations done for the [VIVO(H2Rpyr2en)] system indicate that for almost all complexes the presence of a sixth equatorial or axial H2O ligand leads to much more stable compounds.
Selective Complexation and Transport of Europium Ions at the Interface of Vesicles
Authors: Marchi‐Artzner Valérie , Brienne Marie‐Josephe , Gulik‐Krzywicki Thaddée , Dedieu Jean‐Claude , Lehn Jean‐Marie 
Published: April 2004

AbstractThe aim of the present work was to design functionalized lipidic membranes that can selectively interact with lanthanide ions at the interface and to exploit the interaction between membranes induced by this molecular‐recognition process with a view to building up self‐assembled vesicles or controlling the permeability of the membrane to lanthanide ions. Amphiphilic molecules bearing a β‐diketone unit as head group were synthesized and incorporated into phospholipidic vesicles. Binding of EuIII ions to the amphiphilic ligand can lead to formation of a complex involving ligands of the same vesicle membrane (intravesicular complex) or of two different vesicles (intervesicular complex). The effect of EuIII ions on vesicle behavior was studied by complementary techniques such as fluorimetry, light scattering, and electron microscopy. The formation of an intravesicular luminescent Eu/β‐diketone ligand (1/2) complex was demonstrated. The linear increase in the binding constant with increasing concentration of ligands in the membrane revealed a cooperative effect of the ligands distributed in the vesicle membrane. The luminescence of this complex can be exploited to monitor the kinetics of complexation at the interface of the vesicles, as well as ion transport across the membrane. By encapsulation of 2,6‐dipicolinic acid (DPA) as a competing ligand which forms a luminescent Eu/DPA complex, the kinetics of ion transport across the membrane could be followed. These functional vesicles were shown to be an efficient system for the selective transport of EuIII ions across a membrane with assistance by β‐diketone ligands.
Catalytic Asymmetric Bromination and Chlorination of β‐Ketoesters
Authors: Marigo Mauro , Kumaragurubaran Nagaswami , Jørgensen Karl Anker 
Published: April 2004

AbstractThe first general catalytic asymmetric bromination and chlorination of β‐ketoesters has been developed. The reactions proceed for both acyclic and cyclic β‐ketoesters catalyzed by chiral bisoxazolinecopper(II) complexes giving the corresponding optically active α‐bromo‐ and α‐chloro‐β‐ketoesters in high yields and moderate to good enantioselectivities. For the optically active chlorinated products the isolated yields are in the range of 88–99 % and the enantiomeric excesses up to 77 % ee, while the optically active brominated adducts are formed in 70–99 % isolated yield and up to 82 % ee. Based on the absolute configuration of the optically active products, the face selectivity for the catalytic enantioselective halogenation is discussed based on a bidentate coordination of the β‐ketoester to the chiral catalyst and a X‐ray structure of chiral α,γ‐diketoesterenolatebisoxazolinecopper(II) complex.
On Triazoles. Part 49. Synthesis of 5,6‐Dihydrothiazolo[3,2‐b][1,2,4]triazol‐2‐yl‐, 6,7‐Dihydro‐5H‐[1,2,4]triazolo[5,1‐b][1,3]thiazin‐2‐yl‐, and 5,6,7,8‐Tetrahydro[1,2,4]triazolo[5,1‐b] [1,3]thiazepin‐2‐yl‐isoquinolinium Salts
Authors: Prauda Ibolya , Reiter Jozsef 
Published: April 2004

AbstractFor Abstract see ChemInform Abstract in Full Text.
Synthesis of Spiro[4.5]decane and Bicyclo[4.3.0]nonane Ring Systems by Self‐Cyclization of (Z)‐ and (E)‐2‐(Trimethylsilylmethyl)pentadienal Derivative.
Authors: Kuroda Chiaki , Honda Shigenobu , Nagura Yuki , Koshio Hiroyuki , Shibue Taku , Takeshita Tokio 
Published: April 2004

AbstractFor Abstract see ChemInform Abstract in Full Text.
New Chiral Ruthenium(II) Catalysts Containing 2,6‐Bis(4′‐(R)‐phenyloxazolin‐2′‐yl)pyridine (Ph‐Pybox) Ligands for Highly Enantioselective Transfer Hydrogenation of Ketones.
Authors: Cuervo Dario , Gamasa M. Pilar , Gimeno Jose 
Published: April 2004

AbstractFor Abstract see ChemInform Abstract in Full Text.
Efficient Aqueous‐Phase Heck and Suzuki Couplings of Aryl Bromides Using Tri(4,6‐dimethyl‐3‐sulfonatophenyl)phosphine Trisodium Salt (TXPTS).
Authors: Moore Lucas R. , Shaughnessy Kevin H. 
Published: April 2004

AbstractFor Abstract see ChemInform Abstract in Full Text.
Unexpected Reaction of 2,3‐Epoxy Sulfonates: Novel Formation of Two Enones with Reversed Substituents at α‐ and β‐Positions from the Single Isomer.
Authors: Fujioka Hiromichi , Ohba Yusuke , Futamura Junko , Kita Yasuyuki 
Published: April 2004

AbstractFor Abstract see ChemInform Abstract in Full Text.
Interaction of Hydrazides of 2‐Aryl‐4‐methyl‐4‐cyclohexene‐1,1‐dicarboxylic Acids with Certain Heterocyclic Aldehydes.
Authors: Tetere Z. , Zicane D. , Ravina I. , Petrova M. , Gudriniece E. 
Published: April 2004

AbstractFor Abstract see ChemInform Abstract in Full Text.
Diastereoselective Michael Addition of (S)‐Mandelic Acid Enolate to Nitroalkenes. Enantioselective Synthesis of α‐Hydroxy‐α,β‐diaryl‐γ‐lactams.
Authors: Blay Gonzalo , Fernandez Isabel , Monje Belen , Pedro Jose R. 
Published: April 2004

AbstractFor Abstract see ChemInform Abstract in Full Text.
Synthesis of 2‐(1‐Alkoxyvinyl)oxazolidines by Condensation of 2‐Alkoxypropenals with 2‐Aminoalkanols and Ring—Chain Tautomerism of the Products.
Authors: Keiko N. A. , Funtikova E. A. , Stepanova L. G. , Chuvashev Yu. A. , Larina L. I. 
Published: April 2004

AbstractFor Abstract see ChemInform Abstract in Full Text.
New Rearrangement of Azofuroxans in an Oxidizing Medium.
Authors: Ovchinnikov Igor V. , Epishina Margarita A. , Molotov Sergey I. , Strelenko Yuri A. , Lyssenko Konstantin A. , Makhova Nina N. 
Published: April 2004

AbstractFor Abstract see ChemInform Abstract in Full Text.
4,4‐Dialkyl‐Substituted N‐Methylmorpholinium 3,5‐Dicyano‐6‐oxo‐1,4,5,6‐tetrahydropyridine‐2‐thiolates and Some of Their Properties.
Authors: Dyachenko V. D. , Nikishin A. A. , Chernega A. N. 
Published: April 2004

AbstractFor Abstract see ChemInform Abstract in Full Text.
Synthesis of New 4‐Nitrosophenyl‐1,4‐dihydropyridines of Pharmacological Interest.
Authors: Santander‐G. I. P. , Nunez‐Vergara Luis J. , Squella J. A. , Navarrete‐Encina P. A. 
Published: April 2004

AbstractFor Abstract see ChemInform Abstract in Full Text.
Multicomponent One‐Pot Synthesis of Pyrido[3′,2′:4,5]thieno[3,2‐b]pyridines as a Novel Approach to Condensed Pyridines.
Authors: Dotsenko Victor V. , Krivokolysko Sergey G. , Litvinov Victor P. 
Published: April 2004

AbstractFor Abstract see ChemInform Abstract in Full Text.
Nitriles in Organic Synthesis: Synthesis of Pyrido[2,1‐b]benzothiazole Derivatives and Polyfunctionally‐Substituted Pyridines.
Authors: Zaki M. E. A. , Fadda A. A. , Samir K. , Amer F. A. 
Published: April 2004

AbstractFor Abstract see ChemInform Abstract in Full Text.
Reactions of 4,7‐Dihydro‐1,2,4‐triazolo[1,5‐a]pyrimidines with α,β‐Unsaturated Carbonyl Compounds.
Authors: Lipson Victoria V. , Ignatenko Irina V. , Desenko Sergey M. , Shishkina Svetlana V. , Shishkin Oleg V. , Komykhov Sergey A. , Logvinenko Natalya V. , Orlov Valery D. , Meier Herbert 
Published: April 2004

AbstractFor Abstract see ChemInform Abstract in Full Text.
Synthesis of Pyrimido[1,2‐a]benzimidazol‐4(10H)‐one Derivatives and Evaluation of Their Interactions with DNA.
Authors: Da Settimo A. , Primofiore G. , Da Settimo F. , Marini A. M. , Taliani S. , Salerno S. , Dalla Via L. 
Published: April 2004

AbstractFor Abstract see ChemInform Abstract in Full Text.
Synthesis of 9‐Aryl‐6,6‐dimethyl‐5,6,7,9‐tetrahydro‐1,2,4‐triazolo [5,1‐b]quinazolin‐8(4H)ones.
Authors: Lipson V. V. , Desenko S. M. , Shirobokova M. G. , Borodina V. V. 
Published: April 2004

AbstractFor Abstract see ChemInform Abstract in Full Text.
Synthesis of 4H‐Tetrazolo[1,5‐a][1]benzazepines from the Baylis—Hillman Adducts of 2‐Azidobenzaldehyde.
Authors: Lee Chang Hoon , Song Young Seok , Cho Hyun In , Yang Je Woo , Lee Kee‐Jung 
Published: April 2004

AbstractFor Abstract see ChemInform Abstract in Full Text.
Synthesis of 3‐Acetyl‐N‐aryl‐4‐diethylaminoselenet‐2(2H)‐imines from 4‐Diethylamino‐3‐butyn‐2‐one and Aryl Isoselenocyanates.
Authors: Atanassov Plamen K. , Linden Anthony , Heimgartner Heinz 
Published: April 2004

AbstractFor Abstract see ChemInform Abstract in Full Text.
Heterocycle‐Fused Cyclohexylglycine Derivatives as Novel Dipeptidyl Peptidase‐IV Inhibitors.
Authors: Mastracchio Anthony , Parmee Emma R. , Leiting Barbara , Marsilio Frank , Patel Reshma , Thornberry Nancy A. , Weber Ann E. , Edmondson Scott D. 
Published: April 2004

AbstractFor Abstract see ChemInform Abstract in Full Text.
Diastereoselective Synthesis of 5‐(Alditol‐1‐C‐yl)‐hydantoins and Their Use as Precursors of Polyhydroxylated‐α‐amino Acids.
Authors: Ulgheri Fausta , Orru Gianmauro , Crisma Marco , Spanu Pietro 
Published: April 2004

AbstractFor Abstract see ChemInform Abstract in Full Text.
Stereospecific Access to β‐Mannosides from Glucose‐Derived 1,2‐Orthoesters as Glycosyl Donors.
Authors: Kaji Eisuke , Hosokawa Yugo , Watanabe Yusuke , Kobayashi Mina , Yamakawa Mayumi 
Published: April 2004

AbstractFor Abstract see ChemInform Abstract in Full Text.
9‐(2‐Aryloxyethyl) Derivatives of Adenine — A New Class of Non‐Nucleosidic Antiviral Agents.
Authors: Petrov V. I. , Ozerov A. A. , Novikov M. S. , Pannecouque C. , Balzarini J. , De Clercq E. 
Published: April 2004

AbstractFor Abstract see ChemInform Abstract in Full Text.
Endoscopic ultrasound‐guided fine‐needle aspiration of lymph nodes: The Hennepin County Medical Center experience
Authors: Stelow Edward B. , Lai Rebecca , Bardales Ricardo H. , Mallery Shawn , Linzie Bradley M. , Crary Gretchen , Stanley Michael W. 
Published: April 2004

AbstractEndoscopic ultrasound (EUS)‐guided fine‐needle aspiration (FNA) allows for the sampling and diagnosis of lesions of the gastrointestinal system and adjacent tissues. It has also proved helpful with the sampling of lymphadenopathy both for the staging of malignancy and for the diagnosis of lymphadenopathy of other causes. We review our experience with EUS‐guided FNA of lymph nodes. The cytology files were searched at Hennepin County Medical Center (HCMC) for all cases of lymph nodes sampled by EUS. Clinical history, biopsy site, diagnosis, and follow‐up information (including ancillary testing) were reviewed. Between January 1, 2000 and December 5, 2002, 217 lymph nodes from 185 different patients were sampled by EUS at HCMC. Biopsy sites included 62 mediastinal, 9 paraesophageal, and 146 intra‐abdominal lymph nodes. Diagnoses were as follows: metastatic non‐small cell carcinoma (n = 69); benign, reactive lymph node (n = 76); granulomatous lymphadenopathy (n = 18); malignant lymphoma (n = 7); atypical–suspicious for malignancy (n = 5); metastatic small cell carcinoma (n = 2); necrotic debris (n = 4), and foreign material (n = 1); 35 cases were nondiagnostic (16.1%) in 22 of 185 patients (11.9%). Ancillary tests including flow cytometry, cytogenetics, and cultures were performed. EUS‐guided FNA of mediastinal and intra‐abdominal lymph nodes provides diagnostic material from which ancillary testing may be performed. Diagn. Cytopathol. 2004;30:301–306. © 2004 Wiley‐Liss, Inc.
ThinPrep evaluation of fluid samples aspirated from cystic ovarian masses
Authors: Lu Dongsi , Davila Rosa M. , Pinto Karen R. , Lu Danielle W. 
Published: April 2004

AbstractThe cytological evaluation of ovarian cystic fluid using ThinPrep has not been reported. To determine the diagnostic accuracy of ThinPrep cytology in distinguishing between benign and nonbenign ovarian cystic lesions, we examined 65 fluid samples aspirated during intraoperative consultation with subsequent histologic correlation. One ThinPrep slide was prepared from each sample aspirated from surgically removed ovarian cystic masses and reviewed blindly by a panel of three cytopathologists. The parameters used in cytological evaluation were cellularity, cell types, cellular arrangement, and background. Four samples were acellular and excluded from the study. The consensus cytologic diagnoses were compiled for 61 cases which were assigned to one of the following diagnostic categories: negative for malignant cells (40 cases), atypical cytology (13 cases), and suspicious or positive for malignancy (8 cases). Histologic correlation of the cytological benign/negative cases showed that 26/40 (65%) were histologically benign and 14/40 were false‐negative (35%, 5 carcinomas and 9 borderline tumors) with 10 of these cases being mucinous tumors. Most false‐negative cytologic samples (11/14 or 79%) did not have an epithelial component. Of the 21 cytological nonbenign diagnoses (atypical/suspicious/positive), 15 (71%) were confirmed on histology (10 carcinomas and 5 borderline tumors). However, a nonbenign cytologic diagnosis was rendered in 6 histologically benign cases, including 2 serous cystadenomas, 1 mucinous cystadenoma, 1 serous cystadenofibroma, 1 endometriosis, and 1 corpus luteal cyst. The diagnostic sensitivity by ThinPrep evaluation of ovarian cystic masses is 81% (26/32) for benign and 52% (15/29) for nonbenign lesions. Our results concluded that ThinPrep examination of ovarian cystic fluid is not accurate in distinguishing benign from malignant cysts, given the significant number of false‐negative diagnoses. Major contributing factors include sparse cellularity of the fluid samples and mucinous differentiation of the tumors. Diagn. Cytopathol. 2004;30:320–324. © 2004 Wiley‐Liss, Inc.
The effects of an audio‐visual training program in dyslexic children
Authors: Magnan Annie , Ecalle Jean , Veuillet Evelyne , Collet Lionel 
Published: April 2004

AbstractA research project was conducted in order to investigate the usefulness of intensive audio–visual training administered to children with dyslexia involving daily voicing exercises. In this study, the children received such voicing training (experimental group). for 30 min a day, 4 days a week, over 5 weeks. They were assessed on a reading task before and after the training. A significant benefit to the experimental group was found after training. These preliminary results underline the role of the phonological components of dyslexia. Copyright © 2004 John Wiley & Sons, Ltd.
An internal information optimum algorithm for a multilayer perceptron and its generalization analysis
Authors: Tomomura Masanobu , Nakayama Kenji 
Published: April 2004

AbstractThe backpropagation (BP) algorithm is a learning algorithm for the multilayer perceptron. However, when this algorithm is applied to the pattern classification problem the generalization ability may not be maximized, even if the learning converges. This paper proposes an algorithm to improve the generalization ability by shifting the hyperplane constructed by the BP algorithm on the basis of internal information. The basic properties of the algorithm are analyzed. Then, the algorithm is extended to the multilayer perceptron and its generalization ability is examined by computer simulation. The proposed method is shown to be useful when the training data are sparse. © 2004 Wiley Periodicals, Inc. Electron Comm Jpn Pt 2, 87(5): 67–80, 2004; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/ecjb.20077
Lipase‐catalysed production and chemical composition of diacylglycerols from soybean oil deodoriser distillate
Authors: Lo Seong Koon , Baharin Badlishah Sham , Tan Chin Ping , Lai Oi Ming 
Published: April 2004

AbstractDiacylglycerols (DAG) were enzymatically produced by lipase‐catalysed esterification of glycerol with fatty acids from soybean oil deodoriser distillate (SODD). Effects of reaction parameters such as reaction time, temperature, enzyme type, enzyme load, substrate molar ratio and water content, as well as the effect of molecular sieves as water adsorbent were studied. Lipozyme RM IM was determined to be the most effective among the lipases screened. The following conditions yielded 69.9% DAG (all percentages are wt/wt): 4 h reaction time, 65 °C reaction temperature, 10% Lipozyme RM IM, 2.5:1 fatty acid to glycerol molar ratio, and 30% molecular sieves. DAG synthesis of 11.9% was still observed at 10% water content. After purification, the product oil contained 86.3% DAG. This oil consisted predominantly of 1,3‐diolein (19.1%), 1‐oleoyl‐3‐linoleoyl‐glycerol (18.2%) and 1‐oleoyl‐2‐linoleoyl‐glycerol (16.6%). The fatty acid profile of the oil was similar to that of refined, bleached and deodorised (RBD) soybean oil. The % ratio of 1,3‐ to 1,2‐positional isomers of DAG was at 56:44.