bluuebunny/crossref_metadata_2025_split huggingface dataset:
Optimal material control in an assembly system with component commonality
Authors: Agrawal Narendra , Cohen Morris A. 
Published: October 2004

AbstractAllocation of scarce common components to finished product orders is central to the performance of assembly systems. Analysis of these systems is complex, however, when the product master schedule is subject to uncertainty. In this paper, we analyze the cost—service performance of a component inventory system with correlated finished product demands, where component allocation is based on a fair shares method. Such issuing policies are used commonly in practice. We quantify the impact of component stocking policies on finished product delays due to component shortages and on product order completion rates. These results are used to determine optimal base stock levels for components, subject to constraints on finished product service (order completion rates). Our methodology can help managers of assembly systems to (1) understand the impact of their inventory management decisions on customer service, (2) achieve cost reductions by optimizing their inventory investments, and (3) evaluate supplier performance and negotiate contracts by quantifying the effect of delivery lead times on costs and customer service. © 2001 John Wiley & Sons, Inc. Naval Research Logistics 48:409–429, 2001
Bayesian inference based on partial monitoring of components with applications to preventive system maintenance
Authors: Gåsemyr Jørund , Natvig Bent 
Published: October 2004

AbstractConsider a binary, monotone system ofncomponents. The assessment of the parameter vector, θ, of the joint distribution of the lifetimes of the components and hence of the reliability of the system is often difficult due to scarcity of data. It is therefore important to make use of all information in an efficient way. For instance, prior knowledge is often of importance and can indeed conveniently be incorporated by the Bayesian approach. It may also be important to continuously extract information from a system currently in operation. This may be useful both for decisions concerning the system in operation as well as for decisions improving the components or changing the design of similar new systems. As in Meilijson [12], life‐monitoring of some components and conditional life‐monitoring of some others is considered. In addition to data arising from this monitoring scheme, so‐called autopsy data are observed, if not censored. The probabilistic structure underlying this kind of data is described, and basic likelihood formulae are arrived at. A thorough discussion of an important aspect of this probabilistic structure, the inspection strategy, is given. Based on a version of this strategy a procedure for preventive system maintenance is developed and a detailed application to a network system presented. All the way a Bayesian approach to estimation of θ is applied. For the special case where components are conditionally independent given θ with exponentially distributed lifetimes it is shown that the weighted sum of products of generalized gamma distributions, as introduced in Gåsemyr and Natvig [7], is the conjugate prior for θ. © 2001 John Wiley & Sons, Inc. Naval Research Logistics 48: 551–577, 2001.
Reliability of a 2‐dimensional k‐within‐consecutive‐r × s‐out‐of‐m × n:F system
Authors: Akiba Tomoaki , Yamamoto Hisashi 
Published: October 2004

AbstractA 2‐dimensional rectangular (cylindrical) k‐within‐consecutive‐r × s‐out‐of‐m × n:F system is the rectangular (cylindrical) m × n‐system if the system fails whenever k components in a r × s‐submatrix fail. This paper proposes a recursive algorithm for the reliability of the 2‐dimensional k‐within‐consecutive‐r × s‐out‐m × n:F system, in the rectangular case and the cylindrical case. This algorithm requires min (O(mkr(n−s)), O(nks(m−r))), and O(mkrn) computing time in the rectangular case and the cylindrical case, respectively. The proposed algorithm will be demonstrated and some numerical examples will be shown. © 2001 John Wiley & Sons, Inc. Naval Research Logistics 48: 625–637, 2001.
Applying Lanchester's linear law to model the Ardennes campaign
Authors: Chen Patrick S. , Chu Peter 
Published: October 2004

AbstractIn modern warfare, many believe the decisive factor in winning a battle is seizing the right moment to shift from defense to attack, or vice versa. This paper attempts to bring that perspective to Lanchester's differential equations of warfare, and continues the application of Lanchester's linear law to the analysis of the World War II battle of Ardennes, as reported in earlier issues of Naval Research Logistics by Bracken and by Fricker. A new variable, shift time, accounting for the timing of the shift between defense and attack is explicitly included in our version of the model, and it helps obtain improved goodness of fit to historical data. © 2001 John Wiley & Sons, Inc. Naval Research Logistics 48:653–661, 2001
Mini‐Review: Morphological changes in the human epileptogenic hippocampus
Authors: Proper E.A. , Hoogland G. , van Veelen C.W.M. , de Graan P.N.E. 
Published: October 2004

AbstractThe availability of surgical tissue from epilepsy patients and the development of different animal models have increased our knowledge about the morphological changes in the epileptogenic brain. In this review we focus on the main morphopathological changes in the hippocampus from patients with temporal lobe epilepsy.The pathological substrate most frequently found in patients, suffering from temporal lobe epilepsy is hippocampal sclerosis. The sclerotic hippocampus is characterized by neuronal degeneration, astrogliosis, and granule cell dispersion. Even temporal lobe epilepsy patients with a non‐sclerotic hippocampus suffer from neuronal cell loss. Another important hallmark of the sclerotic hippocampus is the presence of mossy fibre sprouts in the supragranular region of the dentate gyrus. This so called “mossy fibre” sprouting was only observed in the sclerotic hippocampus, and corresponded to the degree of hippocampal sclerosis. Moreover, the demonstration of actively sprouting mossy fibres in the sclerotic hippocampus, indicates that the process of mossy fibre sprouting is still an active, on‐going process in the sclerotic hippocampus, even though these patients have suffered from seizures for many years. This active mossy fibre sprouting could potentially further aggravate the process of neuronal degeneration and astrogliosis. Therefore, it seems important to surgically remove the sclerotic hippocampal tissue in patients with temporal lobe epilepsy as early as possible.
Alkoxyamine‐mediated “living” radical polymerization: MS investigation of the early stages of styrene polymerization initiated by cumyl‐TEISO
Authors: Cresidio Salvacion P. , Aldabbagh Fawaz , Busfield W. Ken , Jenkins Ian D. , Thang San H. , Zayas‐Holdsworth Clovia , Zetterlund Per B. 
Published: October 2004

AbstractA new series of 1,1,3,3‐tetraethylisoindoline‐2‐oxyl (TEISO)‐based alkoxyamines was prepared. The half‐lives for thermal dissociation indicated that the most sterically congested cumyl‐TEISO alkoxymine had the greatest potential as an initiator for the polymerization of monomers at lower temperatures. The polymerization of styrene at 110 °C gave a linear evolution of Mn with conversion in the early stages. Further evidence for the “living” nature was given by the polydispersities of the polymers that remained low (Mw/Mn = 1.13–1.27) throughout the polymerization (up to 80% conversion). No polymer was formed for the styrene system in a reasonable time below 100 °C. High‐performance liquid chromatographic/mass spectrometric investigations of the distribution of trapped oligomers containing one to nine monomer units formed at 60 °C revealed that the trapping of oligomeric cumyl–styryl radicals by TEISO is irreversible at this temperature. Methyl methacrylate polymerized with cumyl‐TEISO at 60–70 °C, although the initial high rates of polymerization soon decreased to zero at low conversions (10–15%), and the high polydispersities (Mw/Mn = 1.42–1.73) indicated significant side reactions. © 2001 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 39: 1232–1241, 2001
Light harvesting and energy transfer within coumarin‐labeled polymers
Authors: Adronov Alex , Robello Douglas R. , Fréchet Jean M. J. 
Published: October 2004

AbstractLinear copolymers that have pendant coumarin‐2 and coumarin‐343 chromophores were prepared as analogues to previously synthesized light‐harvesting dendrimers. The chromophore ratios within these polymers were maintained similar to those of the various generation dendrimers to investigate the effect of polymer architecture on the energy‐transfer efficiency between the coumarin‐2 donors and coumarin‐343 acceptors. Both physical and photophysical properties of these polymers were analyzed and compared to those of the analogous dendrimers. Energy‐transfer efficiencies were relatively high in the polymers; however, deleterious excimer formation between the coumarin‐343 chromophores diminished the quantum yield of fluorescence of the polymers when compared to the analogous dendrimers. Overall, it was found that the ultimate performance of the dendritic light‐harvesting antennae was superior to that of the polymeric analogues, but the polymers were more practical in terms of synthetic accessibility. © 2001 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 39: 1366–1373, 2001
Block copolymerization of tert‐butyl methacrylate with α,ω‐difunctionalized polystyrene macroiniferter and hydrolysis to amphiphilic block copolymer
Authors: Qin Shu‐Hui , Qiu Kun‐Yuan 
Published: October 2004

AbstractThe block copolymerization of tert‐butyl methacrylate (tBMA) with a difunctionalized polystyrene (PS) macroinitiator was investigated. The polymerizations were performed under UV light irradiation using PS bearing α‐ and ω‐functionalized end groups containing diethyldithiocarbamyl groups as a macroiniferter. Kinetic studies indicate the molecular weights of triblock copolymers increased linearly with the conversion. Block copolymers with different lengths of PtBMA segments were easily prepared by varying the ratio of tBMA and PS macroiniferter or by controlling the monomer conversion. The formations of block copolymers were characterized by gel permeation chromatographic, 1H NMR, and DSC analyses. PtBMA segments of the triblock copolymer were subsequently hydrolyzed quantitatively to poly(methacrylic acid) segments using concentrated HCl as a catalyst in a refluxing solution of dioxane, and then an amphiphilic ABA triblock copolymer was produced. © 2001 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 39: 1450–1455, 2001
Synthesis and polymerization mechanism of bisacetoacetamides
Authors: Chang Ji Young , Kim Bum Jin , Park Chong Rae , Han Man Jung , Kim Tae Ja , Yun Hoseop 
Published: October 2004

AbstractBisacetoacetamides were prepared, and their polymerization was investigated. The acetoacetyl groups were introduced to diamines by the reaction with diketene to give bisacetoacetamides. They were polymerized under high pressure (34.5 MPa) at 200 °C for 30 min to create the crosslinked films. The polymerization mechanism was studied by a model reaction of acetoacetanilide. The model‐reaction results indicated that the polymerization of bisacetoacetamides proceeded by addition reactions of the isocyanates formed as intermediates and in part by condensation reactions between the acetoacetamido groups. The isocyanates also reacted with the urea groups on the polymer chains to form biurets, which would cause crosslinking. In the presence of a diamine, the reaction produced a soluble oligourea. © 2001 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 39: 1456–1462, 2001
Main kinetic features of ethylene polymerization reactions with heterogeneous Ziegler–Natta catalysts in the light of a multicenter reaction mechanism
Authors: Kissin Yury V. 
Published: October 2004

AbstractA previously developed kinetic scheme for ethylene polymerization reactions with heterogeneous Ziegler–Natta catalysts (see Y. V. Kissin, R. I. Mink, & T. E. Nowlin, J Polym Sci Part A: Polym Chem 1999, 37, 4255 and Y. V. Kissin, R. I. Mink, T. E. Nowlin, & A. J. Brandolini, J Polym Sci Part A: Polym Chem 1999, 37, 4273, 4281) states that the catalysts have several types of active centers that have different activities and different stabilities, produce different types of polymer materials, and respond differently to reaction conditions. Each type of center produces a single polymer component (Flory component), a material with a uniform structure (copolymer composition, isotacticity, etc.) and a narrow molecular weight distribution (weight‐average molecular weight/number‐average molecular weight = 2.0). This article examines several previously known features of ethylene polymerization and copolymerization reactions on the basis of this mechanism. The discussed subjects include temperature and cocatalyst effects on the polymerization kinetics and molecular weight distribution of polymers and reaction parameter effects (temperature, ethylene and hydrogen partial pressures, and α‐olefin and cocatalyst concentrations) on the molecular weights of Flory components. The results show that the formulation of the multicenter kinetic scheme and the development of kinetic tools necessary for the application of this scheme significantly expand our understanding of the working of heterogeneous polymerization catalysts and provide additional means for their control. © 2001 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 39: 1681–1695, 2001
Photoinitiated polymerization of methacrylic monomers in a polystyrene matrix: Kinetic, mechanistic, and structural aspects
Authors: Mateo J. L. , Calvo M. , Bosch P. 
Published: October 2004

AbstractThe kinetics and mechanism of the photoinitiated polymerization of tetrafunctional and difunctional methacrylic monomers [1,6‐hexanediol dimethacrylate (HDDMA) and 2‐ethylhexyl methacrylate (EHMA)] in a polystyrene (PS) matrix were studied. The aggregation state, vitreous or rubbery, of the monomer/matrix system and the intermolecular strength of attraction in the monomer/matrix and growing macroradical/matrix systems are the principal factors influencing the kinetics and mechanism. For the PS/HDDMA system, where a relatively high intermolecular force of attraction between monomer and matrix and between growing macroradical and matrix occurs, a reaction‐diffusion mechanism takes place at low monomer concentrations (<30–40%) from the beginning of the polymerization. For the PS/EHMA system, which presents low intermolecular attraction between monomer and matrix and between growing macroradical and matrix, the reaction‐diffusion termination is not clear, and a combination of reaction‐diffusion and diffusion‐controlled mechanisms explains better the polymerization for monomer concentrations below 30–40%. For both systems, for which a change from a vitreous state to a rubbery state occurs when the monomer concentration changes from 10 to 20%, the intrinsic reactivity and kp/kt1/2 ratio (where kp is the propagation kinetic constant and kt is the termination kinetic constant) increase as a result of a greater mobility of the monomer in the matrix (a greater kp value). The PS matrix participates in the polymerization process through the formation of benzylic radical, which is bonded to some extent by radical–radical coupling with the growing methacrylic radica, producing grafting on the PS matrix. © 2001 John Wiley & Sons, Inc. J Polym Sci Part A: Polym Chem 39: 2049–2057, 2001
“Charge transfer” polymerization—and the absence thereof!
Authors: Hall, H. K. , Padias Anne Buyle 
Published: October 2004

AbstractMechanisms for “charge‐transfer” spontaneous polymerizations and cycloadditions between electron‐rich olefins and electron‐poor olefins were reviewed. As for propagation, literature proposals involving charge‐transfer complexes were rejected. Instead, alternating copolymerization is ascribed to polar effects in free‐radical reactions. As for spontaneous initiation, literature proposals involving charge‐transfer complexes, with or without proton transfer, were rejected. Instead, the initiating species is postulated to be a tetramethylene zwitterion biradical, which may initiate either ionic homopolymerization or free‐radical copolymerization. A new hypothesis proposes that any interaction that brings vinyl monomers close together may facilitate tetramethylene formation and spontaneous polymerization. These interactions include Coulombic, acid–base, hydrophobic–hydrophilic and templating–tethering interactions. © 2001 John Wiley & Sons, Inc. J Polym Sci Part A: Polym Chem 39: 2069–2077, 2001
Modified polysulfones. IV. Synthesis and characterization of polymers with silicon substituents for a comparative study of gas‐transport properties
Authors: Guiver Michael D. , Robertson Gilles P. , Rowe Sheri , Foley Stephen , Kang Yong Soo , Park Hyun Chae , Won Jongok , Thi Hoai Nam Le 
Published: October 2004

AbstractWe previously conducted a detailed study of gas‐transport and other properties of a series of silicon derivatives of Udel polysulfone (PSf) and Radel polyphenylsulfone; we now report the details of their preparation by the reaction of lithiated polymer intermediates with chlorosilylalkylaryl electrophiles. Ortho‐sulfone‐substituted polymers with pendant trimethylsilyl, dimethylphenylsilyl, and diphenylmethylsilyl and other groups were obtained by direct metalation followed by the reaction of the dilithiated intermediate with the appropriate silyl electrophile. In addition, the structural regularity and geometry of the dilithiated site was also exploited to introduce silicon into the main chain by the reaction of dichlorosilyl electrophiles, leading to the formation of a new tricyclic heteroatom ring. Ortho‐ether PSf derivatives were obtained from a dibrominated polymer via the lithiation of brominated polymer and reaction with a silyl electrophile. The degree of substitution of the silyl groups was 2.0 or less from dilithiated polymers and was dependent on the electrophile reactivity and reaction conditions. A detailed structural characterization of the polymers by NMR and IR spectroscopy is reported in addition to glass‐transition temperatures and thermal stabilities. © 2001 John Wiley & Sons, Inc. J Polym Sci Part A: Polym Chem 39: 2103–2124, 2001
Block and star block copolymers by mechanism transformation. VI. Synthesis and characterization of A4B4 miktoarm star copolymers consisting of polystyrene and polytetrahydrofuran prepared by cationic ring‐opening polymerization and atom transfer radical polymerization
Authors: Guo Yan‐Ming , Pan Cai‐Yuan , Wang Jian 
Published: October 2004

AbstractThe synthesis of A4B4 miktoarm star copolymers, where A is polytetrahydrofuran (PTHF) and B is polystyrene (PSt), was accomplished with orthogonal initiators and consecutive cationic ring‐opening polymerization (CROP) and atom transfer radical polymerization (ATRP). The compound formed in situ from the reaction of 3‐{2,2‐bis[2‐bromo‐2‐(chlorocarbonyl) ethoxy] methyl‐3‐(2‐chlorocarbonyl) ethoxy} propoxyl‐2‐bromopropanoyl chloride [C(CH2OCH2CHBrCOCl)4] with silver perchlorate was used to initiate the CROP of tetrahydrofuran. The obtained polymer contained four secondary bromine groups at the α position to the original initiator sites and was used to initiate the ATRP of styrene with a CuBr/2,2′‐bipyridine catalyst to form a C(PTHF)4(PSt)4 miktoarm star copolymer. The miktoarm copolymer was characterized by gel permeation chromatography and 1H NMR. The macroinitiator C(PTHF)4Br4 was hydrolyzed to afford PTHF arms. © 2001 John Wiley & Sons, Inc. J Polym Sci Part A: Polym Chem 39: 2134–2142, 2001
Low‐oxidation‐potential conducting polymers derived from 3,4‐ethylenedioxythiophene and dialkoxybenzenes
Authors: Irvin Jennifer A. , Schwendeman Irina , Lee Youngkwan , Abboud Khalil A. , Reynolds John R. 
Published: October 2004

AbstractMonomers derived from 3,4‐ethylenedioxythiophene and phenylenes with branched or oligomeric ether dialkoxy substituents were prepared with the Negishi coupling technique. Electrooxidative polymerization led to the corresponding dialkoxy‐substituted 3,4‐ethylenedioxythiophene–phenylene polymers, with extremely low oxidation potentials (E1/2,p = −0.16 to −0.50 V vs Ag/Ag+) due to the highly electron‐rich nature of these materials. The polymers were electrochromic, reversibly switching from red to blue upon oxidation, with bandgaps at about 2 eV. The electrochemical behavior of the oligomeric ether‐substituted polymer was investigated in the presence of different metal ions. Films of the polymer exhibited electrochemical recognition for several alkali and alkaline‐earth cations with selectivity in the order Li+ > Ba2+ > Na+ > Mg2+. Cyclic voltammetry showed a decrease in the oxidation potential and an improvement in the definition of the voltammetric response, as well as an increase in the overall electroactivity of the polymer films when the concentration of the cations in the medium was increased. These results are discussed in terms of the electrostatic interactions between the complexed cation and the redox center, as well as the diffusion of the ionic species into the polymer matrix. © 2001 John Wiley & Sons, Inc. J Polym Sci Part A: Polym Chem 39: 2164–2178, 2001
Synthesis of well‐defined cyclodextrin‐core star polymers
Authors: Ohno Kohji , Wong Benjamin , Haddleton David M. 
Published: October 2004

AbstractThe synthesis of 21‐arm methyl methacrylate (MMA) and styrene star polymers is reported. The copper (I)‐mediated living radical polymerization of MMA was carried out with a cyclodextrin‐core‐based initiator with 21 independent discrete initiation sites: heptakis[2,3,6‐tri‐O‐(2‐bromo‐2‐methylpropionyl]‐β‐cyclodextrin. Living polymerization occurred, providing well‐defined 21‐arm star polymers with predicted molecular weights calculated from the initiator concentration and the consumed monomer as well as low polydispersities [e.g., poly(methyl methacrylate) (PMMA), number‐average molecular weight (Mn) = 55,700, polydispersity index (PDI) = 1.07; Mn = 118,000, PDI = 1.06; polystyrene, Mn = 37,100, PDI = 1.15]. Functional methacrylate monomers containing poly(ethylene glycol), a glucose residue, and a tert‐amine group in the side chain were also polymerized in a similar fashion, leading to hydrophilic star polymers, again with good control over the molecular weight and polydispersity (Mn = 15,000, PDI = 1.03; Mn = 36,500, PDI = 1.14; and Mn = 139,000, PDI = 1.09, respectively). When styrene was used as the monomer, it was difficult to obtain well‐defined polystyrene stars at high molecular weights. This was due to the increased occurrence of side reactions such as star–star coupling and thermal (spontaneous) polymerization; however, low‐polydispersity polymers were achieved at relatively low conversions. Furthermore, a star block copolymer consisting of PMMA and poly(butyl methacrylate) was successfully synthesized with a star PMMA as a macroinitiator (Mn = 104,000, PDI = 1.05). © 2001 John Wiley & Sons, Inc. J Polym Sci Part A: Polym Chem 39: 2206–2214, 2001