bluuebunny/crossref_metadata_2025_split huggingface dataset:
Release of UPR‐Mp‐37 and UPR‐Mp‐48 white common bean germplasm with improved resistance to ashy stem blight
Authors: Viteri Diego M. , Linares‐Ramírez Angela M. , Vázquez Roberto 
Published: October 2023

AbstractWhite common bean (Phaseolus vulgarisL.) breeding lines (BL) UPR‐Mp‐37 (Reg. no. GP‐315, PI 703030), and UPR‐Mp‐48 (Reg. no. GP‐316, PI 703031) with improved resistance to ashy stem blight [caused byMacrophomina phaseolina(Tassi) Goidanich] were developed at the University of Puerto Rico. Both these BL had lower severity (mean scores of 4.1–4.7) to PRI21M. phaseolinaisolate compared with white common bean genotypes ‘Bella’, ‘Beníquez’, NY6020‐4, and ‘Verano’ that had a susceptible response (scores >7.0). UPR‐Mp‐37 was selected from the cross NY6020‐4/A 195//SEA 5 while UPR‐Mp‐48 was derived from the common bean population BAT 477/NY6020‐4//PRA154. UPR‐Mp‐37 has an indeterminate growth habit type III, initiates flowering at 30 days after planting, reaches harvesting maturity at 89 days, and has an average weight of 27.4 g per 100 seed. UPR‐Mp‐48 has a determinate growth habit type I, initiates flowering and matures at 33 and 85 days after planting, respectively, and has an average weight of 29.6 g per 100 seed. Both BL had over 800 kg ha−1seed yields in Isabela, Puerto Rico. The resistance of UPR‐Mp‐37 and UPR‐Mp‐48 BL can be introgressed into susceptible white beans to reduce the disease severity.
Recent advances in microfluidic fiber‐spinning chemistry
Authors: Song Yan , Yu Xiao‐Qing , Chen Su 
Published: October 2023

AbstractFiber‐spinning chemistry (FSC) has emerged as a promising micro‐reaction platform due to its high‐specific surface area, efficient heat and mass transfer, and enhanced reaction rate. The FSC strategy employs spinning fibers as microreactors, lessening the emissions of volatile organic compounds (VOCs), and realizing the design of micro/nanoscale fibers and the synthesis of nanomaterials. In this review, we highlight the latest advancements in FSC in respect of preparation mechanisms and technical advantages. Various FSC strategies, including microfluidic spinning, electro‐microfluidic spinning (EMS), and microfluidic blow spinning (MBS) are emphasized. In particular, the regulation of microfluidic chips in the FSC process is introduced. Additionally, the application of the FSC strategy is summarized in the synthesis of fluorescent nanomaterials, nonweaving for multidimensional fibers, and all‐weather smart textiles. Finally, the advanced progress and future perspectives are discussed. Overall, this review will provide theoretical guidance for the design of well‐defined micro/nanoscale fibers based on the FSC platforms.
Twisted Bilayer Graphene: A Journey Through Recent Advances and Future Perspectives
Authors: Rakkesh R. Ajay , Rebecca P. N. Blessy , Naveen T. B. , Durgalakshmi D. , Balakumar S. 
Published: October 2023

AbstractTwisted bilayer graphene (TBG) has emerged as a fascinating research frontier in condensed matter physics and materials science. This review article comprehensively overviews recent advances and future perspectives in studying TBG. The challenges associated with fabricating and characterizing TBG structures, including precise control of the twist angle and accurate determination of electronic properties, are discussed. Furthermore, the intriguing phenomena observed in TBG, such as superconductivity, insulating phases, and correlated electron states, shedding light on their underlying mechanisms, are explored. Scalability and device integration of TBG are explored, along with potential engineering strategies to tailor its properties for specific applications. By synthesizing and analyzing the latest scientific reports, a roadmap for further research is provided and the promising prospects for TBG are highlighted.
Association between fractional exhaled nitric oxide and therapeutic adherence to controller management in pediatric asthma patients
Authors: Cleves Daniela , Vargas Pedro , Acuña‐Cordero Ranniery , Aguilera‐Otalvaro Paula , Camargo Bethy , Aristizábal‐Duque Ricardo , Rodríguez‐Martínez Carlos E. 
Published: October 2023

AbstractObjectivesGuidelines for asthma management recommend, before establishing additional therapeutic behaviors, to confirm correct use and adequate therapeutic adherence to treatment. Evidence exists on the use of fractional exhaled nitric oxide (FeNO) values for monitoring therapeutic adherence in adults. It is important to establish whether there is a correlation between FeNO and therapeutic adherence in children. This study aims to provide new knowledge about the relationship between FeNO and therapeutic adherence in asthmatic children.Materials and MethodsAnalytical cross‐sectional study including asthma patients 5–18 years of age, attending follow‐up at Hospital Militar Central (HMC) between May and November 2022 in Colombia. A sociodemographic survey was carried out, followed by the Pediatric Inhaler Adherence Questionnaire (PIAQ), and asthma control test (ACT) or childhood asthma control test (cACT). We defined adequate therapeutic adherence as not missing a single application of inhaled steroids in the last 15 days according to PIAQ. A poisson regression model was carried out including relevant predictors for therapeutic adherence such as FeNO values, age, tobacco exposure at home, atopy, and time since initiation of use of inhaled controller.ResultsEighty‐two children with a median age of 10 years (interquartile range: 7–12 years) were included. Adequate therapeutic adherence was reported by 68.3%. After adjusting for age, sex, exposure to cigarette smoke, duration of controller therapy, and atopy, FeNO < 20 ppb was independently associated with adequate therapeutic adherence (RR = 1.5, p = .04, 95% confidence interval: 1.03–2.19).ConclusionsFeNO values seem to be useful to identify pediatric patients with asthma who have adequate adherence to inhaled steroids in a MIC.
Relevant Advances in the Synthesis and Applications of N‐Glycopyranosides
Authors: Guimarães Bruna Martins , de Oliveira Silva Rayane , de Sales Barbosa Maria Verônica , de Freitas Jucleiton José Rufino , Freitas Juliano Carlo Rufino , de Oliveira Ronaldo Nascimento , de Freitas Filho João Rufino 
Published: October 2023

AbstractN‐glycosides are produced when an aglycone is connected, for example, using a glycosylation reaction, to the sugar moiety via linkage of C−N bond at anomeric carbon. N‐glycosides are obtained from different precursors, including glucals, 1‐azido glycosides, glycosyl azide, glycosyl isothiocyanate, 2‐deoxy‐2‐iodo‐N‐glycoside, glycosyl‐1H‐1,2,3‐triazol, and 2‐nitroglucal. The biological relevance of N‐glycopyranosides has drowned attracted the attention of several researchers. The scope of this review covers the literature from 2010 to 2022. Recent advances focused on the natural occurrence, synthesis, mechanism, and pharmacological applications of N‐glycopyranosides are discussed.
Synthesis of Novel Polycyclic Alkylated Tetralin Base Oils Catalyzed by Ionic Liquids and Its Lubricating Properties
Authors: Fu Jiajia , Chen Chen , Tang Qiong , Xu Hong , Liu Lei , Dong Jinxiang 
Published: October 2023

AbstractA novel polycyclic alkylated tetralin (PAT) similar to the naphthenic oil was successfully synthesized through Friedel‐Crafts alkylation. This was accomplished by reacting coal‐based chemical tetralin with 1,7‐octadiene, using Et3NHCl−AlCl3 ionic liquid as a catalyst. To enhance the selectivity towards dialkylated products (C28−2THN), the reaction conditions were systematically studied. Interestingly, the reaction could proceed well even at a low temperature of 0 °C and the selectivity for C28−2THN products could reach 54.0 %. The primary physicochemical properties of PAT were investigated in detail, it was found that the existence of polycyclic structures contributes to high viscosity, better thermal‐oxidative stability and good polarity. Compared with octyltetralins‐ and commercial alkylnaphthalene‐based oil (AN30), the PAT exhibited superior friction‐reducing and anti‐wear properties under the load of 100 N at 50 °C due to its rigid cycle structures and flexible chain.
Reproducible and High‐Performance WOLEDs Based on Independent High‐Efficiency Triplet Harvesting of Yellow Hot‐Exciton ESIPT and Blue TADF Emitters
Authors: Yang Ningjing , Yue Guochang , Zhang Yong , Qin Xiaoyu , Gao Zhiqiang , Mi Baoxiu , Fan Quli , Qian Yan 
Published: October 2023

AbstractHot exciton organic light‐emitting diode (OLED) emitters can balance the high performance of a device and reduce efficiency roll‐off by fast reverse intersystem crossing from high‐lying triplets (hRISC). In this study, an excited‐state intramolecular proton transfer (ESIPT) fluorophore of 2‐(benzo[d]thiazol‐2‐yl)‐4‐(pyren‐1‐yl)phenol (PyHBT) with the typical characteristic properties of a hot exciton is developed. With high efficiency of utilization of the exciton (91%), its yellow OLED exhibited high external quantum efficiency (EQE) of 5.6%, current efficiency (CE) of 16.8 cd A−1, and power efficiency (PE) of 17.3 lm W−1. The performance of the yellow emissive “hot exciton” ESIPT fluorophores is among the highest recorded. Due to the large Stokes shift of the ESIPT emitter, non‐energy‐transferred high‐performance white OLEDs (WOLEDs) are developed, which are reproducible and highly efficient. This is possible because of the independent harvesting of most of the triplets in both complementary‐color emitters without the interference of energy transfer. The PyHBT‐based WOLEDs exhibit a maximum EQE of 14.3% and CE of 41.1 cd A−1, which facilitates the high‐yield mass production of inexpensive WOLEDs.
An Ultra‐Flexible Sodium‐Ion Full Cell with High Energy/Power Density and Unprecedented Structural Stability
Authors: Jena Sambedan , Tran Duy Thanh , Park Sehwi , Islam Muhaiminul , Kim Nam Hoon , Lee Joong Hee 
Published: October 2023

AbstractFuturistic wearable electronics desperately need power sources with similar flexibility and durability. In this regard, the authors, therefore, propose a scalable PAN‒PMMA blend‐derived electrospinning protocol to fabricate free‐standing electrodes comprised of cobalt hexacyanoferrate nanocube cathode and tin metal organic framework‐derived nanosphere anode, respectively, for flexible sodium‐ion batteries. The resulting unique inter‐networked nanofiber mesh offers several advantages such as robust structural stability towards repeated bending and twisting stresses along with appreciable electronic/ionic conductivity retention without any additional post‐synthesis processing. The fabricated flexible sodium ion full cells deliver a high working voltage of 3.0 V, an energy density of 273 Wh·kg−1, and a power density of 2.36 kW·kg−1. The full cells retain up to 86.73% of the initial capacity after 1000 cycles at a 1.0 C rate. After intensive flexibility tests, the full cells also retain 78.26% and 90.78% of the initial capacity after 1000 bending and twisting cycles (5 mm radius bending and 40o axial twisting), respectively. This work proves that the proposed approach can also be employed to construct similar robust, free‐standing nanofiber mesh‐based electrodes for mass‐producible, ultra‐flexible, and durable sodium ion full cells with commercial viability.
Electronic and Geometric Effects Endow PtRh Jagged Nanowires with Superior Ethanol Oxidation Catalysis
Authors: Yu Renqin , Shao Ruiwen , Ning Fanghua , Yu Yaodong , Zhang Jing , Ma Xian‐Yin , Zhu Rongying , Li Menggang , Lai Jianping , Zhao Yufeng , Zeng Lingyou , Zhang Jiujun , Xia Zhonghong 
Published: October 2023

AbstractComplete ethanol oxidation reaction (EOR) in C1 pathway with 12 transferred electrons is highly desirable yet challenging in direct ethanol fuel cells. Herein, PtRh jagged nanowires synthesized via a simple wet‐chemical approach exhibit exceptional EOR mass activity of 1.63 A mgPt−1 and specific activity of 4.07 mA cm−2, 3.62‐fold and 4.28‐folds increments relative to Pt/C, respectively. High proportions of 69.33% and 73.42% of initial activity are also retained after chronoamperometric test (80 000 s) and 1500 consecutive potential cycles, respectively. More importantly, it is found that PtRh jagged nanowires possess superb anti‐CO poisoning capability. Combining X‐ray absorption spectroscopy, X‐ray photoelectron spectroscopy as well as density functional theory calculations unveil that the remarkable catalytic activity and CO tolerance stem from both the Rh‐induced electronic effect and geometric effect (manifested by shortened Pt─Pt bond length and shrinkage of lattice constants), which facilitates EOR catalysis in C1 pathway and improves reaction kinetics by reducing energy barriers of rate‐determining steps (such as *CO → *COOH). The C1 pathway efficiency of PtRh jagged nanowires is further verified by the high intensity of CO2 relative to CH3COOH/CH3CHO in infrared reflection absorption spectroscopy.
Broad‐Range‐Response Battery‐Type All‐in‐one Self‐Powered Stretchable Pressure‐Sensitive Electronic Skin
Authors: Liang Xing , Zhang Xiaoyu , Hu Zhenyu , Sun Qi , Liu Muxiang , Gu Puzhong , Yang Xiao , Huang Jia , Zu Guoqing 
Published: October 2023

AbstractHighly sensitive self‐powered stretchable electronic skins with the capability of detecting broad‐range dynamic and static pressures are urgently needed with the increasing demands for miniaturized wearable electronics, robots, artificial intelligence, etc. However, it remains a great challenge to achieve this kind of electronic skins. Here, unprecedented battery‐type all‐in‐one self‐powered stretchable electronic skins with a novel structure composed of pressure‐sensitive elastic vanadium pentoxide (V2O5) nanowire‐based porous cathode, elastic porous polyurethane /carbon nanotube/polypyrrole anode, and polyacrylamide ionic gel electrolyte are reported. A new battery‐type self‐powered pressure sensing mechanism involving the output current variation caused by the resistance variation of the electrodes and electrolytes under external pressure is revealed. The battery‐type self‐powered electronic skins combining high sensitivity, broad response range (1.8 Pa–1.5 MPa), high fatigue resistance, and excellent stability against stretching (50% tensile strain) are achieved for the first time. This work provides a new and versatile battery‐type sensing strategy for the design of next‐generation all‐in‐one self‐powered miniaturized sensors and electronic skins.
Advances of Zn Metal‐Free “Rocking‐Chair”‐Type Zinc Ion Batteries: Recent Developments and Future Perspectives
Authors: Bai Youcun , Zhang Heng , Liang Wenhao , Zhu Chong , Yan Lijin , Li Changming 
Published: October 2023

AbstractAqueous zinc ion battery (AZIBs) has attracted the attention of many researchers because of its safety, economy, environmental protection, and high ionic conductivity of electrolytes. However, the battery greatly suffers from zinc dendrite produced by zinc metal anode leading to poor cycle life and even unsafe problems, which limit its further development for various important applications. It is known that the success of the commercialization of lithium‐ion batteries (LIBs) is mainly due to replacement of lithium metal anode with graphite, which avoids the formation of Li dendrite. Therefore, it is an important step to develop aqueous zinc ion anode to replace conventional zinc metal one with zinc‐metal free anode material. In this review, the working principle and development prospect of “rocking‐chair” AZIBs are introduced. The research progress of different types of zinc metal‐free anode materials and cathode materials in “rocking‐chair” AZIBs is reviewed. Finally, the limitations and challenges of the Zn metal‐free “rocking‐chair” AZIBs as well as solutions are deeply discussed, aiming to provide new strategies for the development of advanced zinc‐ion batteries.
Tunable Contacts of Bi2O2Se Nanosheets MSM Photodetectors by Metal‐Assisted Transfer Approach for Self‐Powered Near‐Infrared Photodetection
Authors: Wang Guangcan , Liu Fengjing , Chen Ruichang , Wang Mingxu , Yin Yanxue , Zhang Jie , Sa Zixu , Li Pengsheng , Wan Junchen , Sun Li , Lv Zengtao , Tan Yang , Chen Feng , Yang Zai‐xing 
Published: October 2023

AbstractOwing to the Fermi pinning effect arose in the metal electrodes deposition process, metal–semiconductor contact is always independent on the work function, which challenges the next‐generation optoelectronic devices. In this work, a metal‐assisted transfer approach is developed to transfer Bi2O2Se nanosheets onto the pre‐deposited metal electrodes, benefiting to the tunable metal–semiconductor contact. The success in Bi2O2Se nanosheets transfer is contributed to the stronger van der Waals adhesion of metal electrodes than that of growth substrates. With the pre‐deposited asymmetric electrodes, the self‐powered near‐infrared photodetectors are realized, demonstrating low dark current of 0.04 pA, high Ilight/Idark ratio of 380, fast rise and decay times of 4 and 6 ms, respectively, under the illumination of 1310 nm laser. By pre‐depositing the metal electrodes on polyimide and glass, high‐performance flexible and omnidirectional self‐powered near‐infrared photodetectors are achieved successfully. This study opens up new opportunities for low‐dimensional semiconductors in next‐generation high‐performance optoelectronic devices.
Network of Inorganic Nanocrystals Can Swell: Study of Swelling‐Induced Surface Instability
Authors: Park Se Young , Lee Seongjae , Lee Seunghan , Kim Jungwook , Char Kookheon , Kang Moon Sung 
Published: October 2023

AbstractA unique organic–inorganic hybrid network composed of inorganic nanocores (ranging from semiconductors to metallic ones) interconnected through organic molecules can be produced by crosslinking the organic ligands of colloidal inorganic nanocrystals in assemblies. This work reports that this network, which is conventionally considered an inorganic film, can swell when exposed to a solvent because of the interaction between the solvent and the organic linkage within the network. Intriguingly, this work discovers that drying the solvent of the swollen organic–inorganic hybrid network can significantly affect the morphology owing to the swelling‐induced compress stress, which is widely observed in various organic network systems. This work studies the surface instability of crosslinked organic–inorganic hybrid networks swollen by various organic solvents, which led to buckling delamination. Specifically, this work investigates the effects of the i) solvent–network interaction, ii) crosslinking density of the network, and iii) thickness of the film on the delamination behavior of the crosslinked network.
Cancer Cell Membrane‐Based Materials for Biomedical Applications
Authors: Lu Yongping , Fan Linming , Wang Jun , Hu Mingxiang , Wei Baogang , Shi Ping , Li Jianshu , Feng Jinyan , Zheng Yu 
Published: October 2023

AbstractThe nanodelivery system provides a novel direction for disease diagnosis and treatment; however, its delivery effectiveness is restricted by the short biological half‐life and inadequate tumor targeting. The immune evasion properties and homologous targeting capabilities of natural cell membranes, particularly those of cancer cell membranes (CCM), have gained significant interest. The integration of CCM and nanoparticles has resulted in the emergence of CCM‐based nanoplatforms (CCM‐NPs), which have gained significant attention due to their unique properties. CCM‐NPs not only prolong the blood circulation time of core nanoparticles, but also direct them for homologous tumor targeting. Herein, the history and development of CCM‐NPs as well as how these platforms have been used for biomedical applications are discussed. The application of CCM‐NPs for cancer therapy will be described in detail. Translational efforts are currently under way and further research to address key areas of need will ultimately be required to facilitate the successful clinical adoption of CCM‐NPs.
Transient Zwitterions Dynamics Empowered Adaptive Interface for Ultra‐Stable Zn Plating/Stripping
Authors: Wu Xingxing , Xia Yufan , Chen Shuang , Luo Zhen , Zhang Xuan , Lu Yingying , Pan Hongge , Xu Ben Bin , Yan Mi , Jiang Yinzhu 
Published: October 2023

AbstractA highly reversible zinc anode is crucial for the commercialization of zinc‐ion batteries. However, the change in the microstructure of the electric double layer originated from the dynamic change in charge density on the electrode greatly impacts anode reversibility during charge/discharge, which is rarely considered in previous research. Herein, the zwitterion additive is employed to create an adaptive interface by coupling the transient zwitterion dynamics upon the change of interfacial charge density. Ab initio molecular dynamics simulations suggest the molecular orientation and adsorption groups of zwitterions will be determined by the charging state of the electrode. ZnSO4 electrolyte with zwitterion fulfills a highly reversible Zn anode with an average Coulombic efficiency of up to 99.85%. Zn/Zn symmetric cells achieve greatly enhanced cycling stability for 700 h with extremely small voltage hysteresis of 29 mV under 5 mA cm−2 with 5 mAh cm−2. This study validates the adaptive interface based on transient dynamics of zwitterions, which sheds new light on developing highly reversible metal anodes with a high utilization rate.
A Universal Additive Design Strategy to Modulate Solvation Structure and Hydrogen Bond Network toward Highly Reversible Fe Anode for Low‐Temperature All‐Iron Flow Batteries
Authors: Yang Jing , Yan Hui , Zhang Qi‐an , Song Yuanfang , Li Ying , Tang Ao 
Published: October 2023

AbstractAqueous all‐iron redox flow batteries (RFBs) are promising competitors for next‐generation grid‐scale energy storage applications. However, the high‐performance operation of all‐iron RFBs in a wider temperature range is greatly hindered by inferior iron plating/stripping reaction and low solid–liquid transition temperature at Fe anode. Herein, a universal electrolyte additive design strategy for all‐iron RFBs is reported, which realizes a highly reversible and dendrite‐free Fe anode at low temperatures. Quantum chemistry calculations first screen several organic molecules with oxygen‐containing functional groups and identify N,N‐Dimethylacetmide (DMAc) as a potential candidate with low cost, high solubility, and strong interactions with Fe2+ and H2O. Combined experimental characterizations and theoretical calculations subsequently demonstrate that adding DMAc into the FeCl2 solution effectively reshapes the primary solvation shell of Fe2+ via the Fe2+‐O (DMAc) bond and breaks hydrogen‐bonding network of water through intensified H‐bond interaction between DMAc and H2O, thereby affording the Fe anode with enhanced Fe/Fe2+ reversibility and lower freezing point. Consequently, the assembled all‐iron RFB achieves an excellent combination of high power density (25 mW cm−2), long charge‐discharge cycling stability (95.59% capacity retention in 103 h), and preeminent battery efficiency at −20 °C (95% coulombic efficiency), which promise a future for wider temperature range operation of all‐iron RFBs.