bluuebunny/crossref_metadata_2025_split huggingface dataset:
Iron‐based catalysts bearing bis(imido)–pyridine ligands for the polymerization of tert‐butyl acrylate
Authors: Castro Pascal M. , Lappalainen Kristian , Ahlgrén Markku , Leskelä Markku , Repo Timo 
Published: March 2003

AbstractIron(II) dichloride complexes bearing a tridentate nitrogen donor ligand were investigated for the homopolymerization of tert‐butyl acrylate after activation with methylaluminoxane. Two new complexes were synthesized, 2,6‐bis[1‐(cyclohexylimido)ethyl]pyridine iron chloride (FeCl2) and 2,6‐bis[1‐(isopropylimido)ethyl]pyridine FeCl2, and the single‐crystal X‐ray structure of the latter one was determined. Turnover frequencies of the catalysts during polymerization ranged from 36 to 241 cycles/mol/h. The obtained polymers exhibited weight‐average molecular weights ranging from 24,000 to 438,500 g/mol, and the molar mass distribution varied between 1.8 and 4.3. Activity of the catalytic system and the molar mass of the polymer are influenced by the ligand structure of the complexes as well as other polymerization conditions such as monomer concentration and temperature. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1380–1389, 2003
Synthesis of poly(β‐pinene)‐g‐poly(meth)acrylate by the combination of living cationic polymerization and atom transfer radical polymerization
Authors: Lu Jiang , Liang Hui , Zhang Wei , Cheng Qing 
Published: March 2003

AbstractNew graft copolymers of β‐pinene with methyl methacrylate (MMA) or butyl acrylate (BA) were synthesized by the combination of living cationic polymerization and atom transfer radical polymerization (ATRP). β‐Pinene polymers with predetermined molecular weights and narrow molecular weight distributions (MWDs) were prepared by living cationic polymerization with the 1‐phenylethyl chloride/TiCl4/Ti(OiPr)4/nBu4NCl initiating system, and the resultant polymers were brominated quantitatively by N‐bromosuccinamide in the presence of azobisisobutyronitrile, yielding poly(β‐pinene) macroinitiators with different bromine contents (Br/β‐pinene unit molar ratio = 1.0 and 0.5 for macroinitiators a and b, respectively). The macroinitiators, in conjunction with CuBr and 2,2′‐bipyridine, were used to initiate ATRP of BA or MMA. With macroinitiator a or b, the bulk polymerization of BA induced a linear first‐order kinetic plot and gave graft copolymers with controlled molecular weights and MWDs; this indicated the living nature of these polymerizations. The bulk polymerization of MMA initiated with macroinitiator a was completed instantaneously and induced insoluble gel products. However, the controlled polymerization of MMA was achieved with macroinitiator b in toluene and resulted in the desired graft copolymers with controlled molecular weights and MWDs. The structures of the obtained graft copolymers of β‐pinene with (methyl)methacrylate were confirmed by 1H NMR spectra. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1237–1242, 2003
Charge‐mosaic membrane prepared from microspheres
Authors: Takizawa Minoru , Sugito Yoshifumi , Oguma Naomi , Nakamura Michiei , Horiguchi Shojiro , Fukutomi Takashi 
Published: March 2003

AbstractA new type of charge‐mosaic membrane was prepared from poly(4‐vinyl pyridine) microspheres 250–350 nm in diameter as an anion‐exchange element and from linear poly(sodium styrene sulfonic acid) as a cation‐exchange element. The mosaic structure on the surface of the membrane and the continuous connection of the microspheres in the membrane were confirmed by scanning electron microscopy observations and the electrical conductivity of the membrane. The microspheres were continuously connected from one side to the other side of the membrane surface when the weight fraction of the microspheres increased more than 20–25 wt % in the membrane. The flux of KCl, the permeability coefficient of KCl, the volume flux, and the selectivity dialysis separation of the electrolyte (KCl) and nonelectrolyte (glucose and saccharose) of the membrane indicated that it had the characteristic properties of a charge‐mosaic membrane. Ion‐exchange membranes composed of each raw material of the charge‐mosaic membrane did not show these properties. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1251–1261, 2003
Main‐chain, thermotropic, liquid‐crystalline, hydrogen‐bonded polymers of 4,4′‐bipyridyl with aliphatic dicarboxylic acids
Authors: Bhowmik Pradip K. , Wang Xiaobin , Han Haesook 
Published: March 2003

AbstractA series of main‐chain, thermotropic, liquid‐crystalline (LC), hydrogen‐bonded polymers or self‐assembled structures based on 4,4′‐bipyridyl as a hydrogen‐bond acceptor and aliphatic dicarboxylic acids, such as adipic and sebacic acids, as hydrogen‐bond donors were prepared by a slow evaporation technique from a pyridine solution and were characterized for their thermotropic, LC properties with a number of experimental techniques. The homopolymer of 4,4′‐bipyridyl with adipic acid exhibited high‐order and low‐order smectic phases, and that with sebacic acid exhibited only a high‐order smectic phase. Like the homopolymer with adipic acid, the two copolymers of 4,4′‐bipyridyl with adipic and sebacic acids (75/25 and 25/75) also exhibited two types of smectic phases. In contrast, the copolymer of 4,4′‐bipyridyl with adipic and sebacic acids (50/50), like the homopolymer with sebacic acid, exhibited only one high‐order smectic phase. Each of them, including the copolymers, had a broad temperature range of LC phases (36–51 °C). The effect of copolymerization for these hydrogen‐bonded polymers on the thermotropic properties was examined. Generally, copolymerization increased the temperature range of LC phases for these polymers, as expected, with a larger decrease in the crystal‐to‐LC transition than in the LC‐to‐isotropic transition. Additionally, it neither suppressed the formation of smectic phases nor promoted the formation of a nematic phase in these hydrogen‐bonded polymers, as usually observed in many thermotropic LC polymers. The thermal transitions for all of them, measured by differential scanning calorimetry, were well below their decomposition temperatures, as measured by thermogravimetric analysis, which were in the temperature range of 193–210 °C. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1282–1295, 2003
Polyester hydrogels with swelling properties controlled by the polymer architecture, molecular weight, and crosslinking agent
Authors: Finne Anna , Albertsson Ann‐Christine 
Published: March 2003

AbstractHydrogels of poly(1,5‐dioxepan‐2‐one) and hydrogels of block copolymers of poly(1,5‐dioxepan‐2‐one) and poly(L‐lactide) were synthesized. Both star‐shaped polymers and linear polymers were polymerized with ring‐opening polymerization and crosslinked in situ with a tetrafunctional acid chloride (1,2,3,4‐cyclopentane tetracarboxylic acid chloride) or a difunctional acid chloride (succinyl chloride). Different network architectures were synthesized in this way. The initial monomer concentrations and the molecular weights of the macromonomers were also altered. The networks were characterized with 1H NMR and differential scanning calorimetry, and the swelling abilities of the different hydrogels were investigated in water and dichloromethane. The ratio of the monomer to the crosslinking agent was assessed by the quantification of the signal intensities in the 1H NMR spectra of the swelled network and agreed with the theoretical crosslinking density. Both the homopolymers of 1,5‐dioxepan‐2‐one and the copolymers of 1,5‐dioxepan‐2‐one and L‐lactide swelled to a high degree in water. The swelling properties of the materials could be varied over a broad range by changes in the architecture, molecular weight, and content of the precursor in the network. Star‐shaped poly(1,5‐dioxepan‐2‐one) crosslinked with a difunctional acid chloride had the highest degree of swelling among the different homopolymer hydrogels. This network also had the lowest glass‐transition temperature because of the flexible units in the structure. The same trends found for the homopolymer hydrogels were also seen in the hydrogels with block copolymers. The hydrogels swelled enormously in dichloromethane, and as in water, the star‐shaped copolymer crosslinked with a difunctional acid chloride had the highest degree of swelling. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1296–1305, 2003
Modified polysulfones. VI. Preparation of polymer membrane materials containing benzimine and benzylamine groups as precursors for molecularly imprinted sensor devices
Authors: Robertson Gilles P. , Guiver Michael D. , Bilodeau François , Yoshikawa Masakazu 
Published: March 2003

AbstractA modified polysulfone containing benzylamine groups was synthesized as a reactive membrane material. Polysulfone was activated at the ortho‐sulfone site by direct lithiation with n‐butyllithium, and the resulting lithiated polysulfone was then reacted with benzonitrile; this yielded a polymer with pendant benzimine groups. The structure was confirmed by NMR and IR spectroscopy and by the transformation of imine to ketone by acid hydrolysis. The polymeric benzimine was also reduced to benzylamine with sodium cyanoborohydride in an acidic medium. The structure and degree of substitution of both benzylamine derivatives were determined by NMR and IR spectroscopy. The modified polysulfone containing benzylamine groups initiated the polymerization of N‐carboxyanhydride of γ‐benzyl‐L‐glutamate [Glu(OBzl)–NCA]. The side‐chain oligopeptide of Glu(OBzl)–NCA attached to polysulfone was converted into molecular recognition sites. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1316–1329, 2003
Synthesis, characterization, and properties of novel ladderlike phosphorus‐containing polysilsesquioxanes
Authors: Chiang Chin‐Lung , Ma Chen‐Chi M. 
Published: March 2003

AbstractNovel ladderlike polysilsesquioxanes that contain phosphorus were successfully synthesized by the sol–gel method. The polysilsesquioxanes were characterized by Fourier transform infrared spectroscopy, 29Si NMR, and X‐ray diffraction. The characterizations demonstrated that the polymer possesses a typical ladderlike structure. The thermogravimetric and differential scanning calorimetric data revealed that the polysilsesquioxanes possess excellent thermal stability. A kinetic analysis of thermal degradation showed that the activation energy of thermal degradation is 187 kJ/mol, according to Kissinger's method. The activation energy of thermal degradation normally increases with conversion (from 171 to 309 kJ/mol) according to Ozawa's method. The average activation energy, calculated by Ozawa's method, was 209 kJ/mol. The scanning electron microscopic photograph and Si and P mappings of ladderlike polysilsesquioxanes showed that the particles were uniformly dispersed at the molecular level and that the sizes of the polysilsesquioxane particles were less than 100 nm. The ultraviolet–visible spectra of the ladderlike polysilsesquioxanes revealed no absorbance in the range of 400–800 nm. Ladderlike polysilsesquioxanes possess excellent optical transparency and excellent flame retardance. This transmittance may be used as a criterion for identifying the formation of a homogeneous phase. These polymers have great potential in waveguide applications. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1371–1379, 2003
Synthesis of 1,3‐bis(2‐trimethylsilyloxyhexafluoro‐2‐propyl)‐5‐allylbenzene and its introduction into polysiloxane chains
Authors: Boutevin B. , Gaboyard M. , Guida‐Pietrasanta F. , Hairault L. , Lebret B. , Pasquinet E. 
Published: March 2003

AbstractThe synthesis of 1,3‐bis(2‐trimethylsilyloxyhexafluoro‐2‐propyl)‐5‐allylbenzene (IV) is described, starting from commercially available 1,3‐bis(2‐hydroxyhexafluoro‐2‐propyl)benzene. After the first step of iodination was optimized, a series of metallating agents were tested, before allylation, so that the best reagent could be selected. The allyl compound IV was then added to two different copoly(dimethyl‐methylhydro)siloxanes, PS 122.5 and PS 123 from Gelest/ABCR, via platinum‐catalyzed hydrosilylation, for the preparation of new polysiloxanes bearing specifically designed pendant aryl moieties. The different synthesized products were characterized by spectroscopic methods (IR and 1H, 13C, 19F, and 29Si NMR), and the glass‐transition temperatures of copolymers VI‐2, VI‐3, and VI‐4 were measured. It was shown that the higher the amount was of grafted fluoroaryl groups, the higher the glass‐transition temperature was. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1400–1410, 2003
Tao Zhang, Soo‐Young Park, B. L. Farmer, Leonard V. Interrante, Synthesis of comb‐type polycarbosilanes via nucleophilic substitution reactions on the main‐chain silicon atoms, Journal of Polymer Science Part A: Polymer Chemistry (2003) 41(7) 984–997
Authors: Zhang Tao , Park Soo‐Young , Farmer B. L. , Interrante Leonard V. 
Published: March 2003

AbstractThe original article to which this erratum refers was published in Journal of Polymer Science Part A: Polymer Chemistry (2003) 41(7) 984–997No abstract.
Choice of the Focal Point Position Using Lasentec FBRM
Authors: Worlitschek Jörg , Mazzotti Marco 
Published: March 2003

AbstractThe Focused Beam Reflectance Measurement (FBRM) technique provides on‐line and in situ information about the chord length distribution (CLD) of a population of particles in dispersion. The effect of changing the focal point position on the measured CLD is experimentally analyzed by carrying out single particle FBRM determinations in both pure water and a dispersion of fines. The results allow some general conclusions to be drawn about optimal focal point positions.
Automated Digital Image Based Measurement of Boundary Fractal Dimension for Complex Nanoparticles
Authors: Wettimuny Ramitha , Penumadu Dayakar 
Published: March 2003

AbstractThere is a growing realization that complex nanoparticles produced by combustion reaction, precipitation, and spray technology using supercritical fluids, are fractally structured. The boundary fractal dimension is linked to the flow, packing and consolidation dynamics of nanopowders. It also contains information on the formation dynamics of the nanoparticles produced by various methods. Extraction of the fractal dimension information embodied in the nanoparticle's fractal structure is hampered by the lack of automated characterization algorithms for processing images of particles. This paper describes an efficient algorithm for analyzing digitized images of fractally structured nanoparticles and presents a computer program that automates the procedure using digital image processing techniques. The program functionality is demonstrated and discussed using digital images of typical pigment, ceramic and pharmaceutical powders.
Selection of Descriptors for Particle Shape Characterization
Authors: Hentschel Mark L. , Page Neil W. 
Published: March 2003

AbstractConventional shape descriptors, formed from a ratio of two particle size measurements, are among the simplest of the many methods used for quantitative particle shape characterization. However, a significant limitation of using one of these shape descriptors is that its value is often not unique to a specific shape. Use of several different shape descriptors may circumvent this problem but, as particle size can be defined in a large number of ways, a similarly large number of shape descriptors can be defined. While some differ substantially, others are only subtly different, conveying similar information. Thus, it is not obvious which of the many possible descriptors should be utilized. In this paper, two‐dimensional particle shape descriptors obtained by image analysis of six different commercially sourced powders were considered. Techniques of cluster and correlation analysis were applied to assist in identifying redundant descriptors for shape characterization of these powder particles, allowing for efficient description of shape using a reduced set. It was found that at least two descriptors are required: aspect ratio and the square root of form factor. Significantly, each descriptor is most sensitive to a different attribute of shape: elongation and ruggedness, respectively.
An Experimental Study of Liquid Jets Interacting with Cross Airflows
Authors: Birouk Madjid , Stäbler Thomas , Azzopardi Barry J. 
Published: March 2003

AbstractThe primary break‐up of liquid jets in cross flows has been studied experimentally. An open‐circuit wind tunnel was employed in which the airflow was generated by a centrifugal fan. The test section, positioned 3 m downstream of the fan, was made of clear acrylic resin to allow optical access and visualization. The working liquid used in the present experiment was an aero‐engine lubrication oil, which was injected perpendicularly into the air flow, via a nozzle placed in the top wall of the test‐section. The study of the primary break‐up mechanisms of the jet involved three parameters, the oil viscosity, and the jet and air cross flow velocities, which were varied independently. Two different break‐up regimes were observed and identified; arcade break‐up and bag break‐up. These were separated by a transition zone. Transverse and longitudinal (or streamwise) penetrations of the jet before the liquid breakup were also measured. The correlation proposed by Wu et al. to predict the jet transverse penetration before the break‐up of the liquid, as a function of the liquid/airflow momentum‐flux ratio, was found to be applicable only to liquids with low viscosity. An empirical extension to this equation has been produced.
Viscous Interaction Between a Vortex Tube and a Rotating Spherical Particle
Authors: Niazmand Hamid , Renksizbulut Metin 
Published: March 2003

AbstractThe transient advection of a cylindrical vortex tube in a viscous incompressible flow field and its interaction with a rotating/spinning spherical particle has been investigated numerically at Reynolds numbers in the range of 20≤ Re≤200 for angular velocities of 0≤Ω≤0.5. The effects of vortex parameters such as size, circulation strength and initial position relative to the particle, on the temporal behavior of the lift and drag forces are studied. Vortex‐sphere interactions bring about major changes in the flow field particularly when coupled with particle rotation. It is observed that the forces acting on the particle are significantly influenced during the time that the vortex core is in the vicinity of the particle. The extent of these local changes are about ±30% in the drag coefficient and about ±200% in the lift coefficient as compared to flow over a rotating solid sphere with no vortex interaction. It is also found that a vortex with core radius between one and two particle diameters creates the strongest temporal variations in the lift and drag coefficients. Furthermore, maximum lift variations occur for the vortex‐particle head on collision, while a vortex with an offset distance of about one diameter from the principal flow axis generates the maximum drag variations.
Self Similarity of Cross‐Stream Droplet Momentum Displacement in Dispersed Multiphase Flow
Authors: Milanez Marko , Naterer Greg F. , Venn Geoff , Richardson Giles 
Published: March 2003

AbstractAnalytical methods are developed and applied to droplet motion, as it relates to aircraft icing. Impinging droplets largely affect the heat balance at an iced aircraft surface, as well as the final ice shape. In this study, a similarity solution of the Eulerian droplet momentum equation is developed. Droplet motion near a flat plate is investigated with a similarity solution. By using scaling, sensitivity, order of magnitude and similarity methods, a momentum displacement of droplets (or particles) due to the presence of the solid surface is predicted. Self similarity of the droplet profiles is established, such that downstream propagation can be expressed in terms of a single independent coordinate. Limiting trends of momentum/drag induced and Blasius‐diffusion profiles are found to identify the spatial range encompassing the droplet motion. The predicted results are successfully compared against the scaling requirements.
Inverse Velocity and Singularity Analysis of Low‐DOF Serial Manipulators
Authors: Fang Yuefa , Tsai Lung‐Wen 
Published: March 2003

AbstractThis paper presents a method for exact inverse velocity analysis of low‐DOF (degrees of freedom n<6) serial manipulators. For a low‐DOF serial manipulator, the number of independently controllable variables in the Cartesian space is equal to the number of joint variables in the joint space, and the remaining 6−n variables are linearly dependent on these independent variables. This paper employs the theory of reciprocal screws to determine a mapping between the independent velocity components in the Cartesian space and the joint rates in the joint space. It is shown that singular conditions of a low‐DOF manipulator depend on choice of independent variables. A 5‐DOF and a 4‐DOF manipulator are analyzed, and a numerical example in which the end effector of a 4‐DOF manipulator is commanded to follow a straight line is used to demonstrate the methodology. © 2003 Wiley Periodicals, Inc.
Comparing the resource‐based and market‐based views of the firm: empirical evidence from Czech privatization
Authors: Makhija Mona 
Published: March 2003

AbstractThe recent privatization of state‐owned enterprises in the Czech Republic forms a natural experiment to test and compare the predictive ability of the resource‐based view (RBV) against the market‐based view (MBV) under conditions of great change. It has been recognized in the literature that, under normal stable circumstances, a firm's internal resources and its external market power are fundamentally intertwined. Consequently, it is difficult to identify the relative roles of these two theories in explaining expected firm performance and firm value. However, when market conditions are in a state of flux, as in the case of the Czech Republic in 1992, we expect the firm's resources to be the primary determinants of firm value. In order to test this notion, an RBV model was developed, based on a set of firm features reflecting the rare and valuable ability to compete in the emerging capitalistic economy (as opposed to the currently prevailing bureaucratically planned economy). A contrasting MBV model was also developed, highlighting the role of market power in this regard. These models were assessed in a cross‐sectional sample of 988 Czech firms undergoing privatization. The empirical findings show that the RBV‐driven variables are remarkably better at explaining share values of Czech firms in the period of privatization than MBV‐driven variables. These results underscore the role of firm resources as a primary determinant of firm value in rapidly changing environments. Copyright © 2003 John Wiley & Sons, Ltd.
The capital structure implications of pursuing a strategy of innovation
Authors: O'Brien Jonathan P. 
Published: March 2003

AbstractIn this paper, we argue that consideration of firm strategy can help illuminate the choices managers make between debt and equity financing. Within an industry, the form of competition that each firm chooses will determine the strategic value to the firm of maintaining financial slack. Our empirical analysis yields strong support for the proposition that financial slack should be a particularly critical strategic imperative for firms pursuing a competitive strategy premised on innovation. We also demonstrate that firms pursuing such a strategy that fail to recognize the value of financial slack are likely to perform poorly. Copyright © 2003 John Wiley & Sons, Ltd.