bluuebunny/crossref_metadata_2025_split huggingface dataset:
BIOFILIA LA NATURALEZA COMO FACTOR DE TENDENCIA EN EL DISEÑO DE UNA VIVIENDA
Authors: Gareca Apaza Mireya Lauren 
Published: November 2023

Antecedentes: Los estudios en este tema señalan que la biofilia es un elemento importante para mejorar la calidad del hábitat de los seres humanos. Por consiguiente, la pandemia ocasionada por el COVID-19 ha generado una mayor valoración de los espacios que habitamos, principalmente de los espacios conectados con la naturaleza.
Objetivo: Proponer estrategias de diseño biofílico que contribuyan al mejoramiento de las condiciones ambientales y espaciales de las viviendas, en correspondencia con los factores de diseño arquitectónicos más relevantes identificados por sus ocupantes.
Material y métodos: Esta investigación utilizó un enfoque cuali-cuantitativo, desde el paradigma interpretativo, se aplicó el método análisis documental y el comparativo. Entre las técnicas se utilizó la encuesta y entrevista, la población encuestada fue de 100 personas y 60 arquitectos, se realizó un muestreo no probabilístico para el primer caso y por conveniencia en el segundo caso.
Resultados y discusión: Los resultados de las encuestas realizadas a los ocupantes nos muestran que sólo un 13% de viviendas unifamiliares de la ciudad de Sucre presentan espacios con vegetación, un 24% carece de iluminación natural y 8% de ventilación natural. Así mismo, el reglamento local de edificación no contribuye con la presencia de elementos naturales en los espacios libres destinados para este fin, debido a su falta de claridad sobre el tipo de ocupación.
Conclusiones: Un diseño arquitectónico que no contemple aspectos como: espacios abiertos ajardinados, iluminación natural y ventilación, afectará la calidad del hábitat en términos ambientales y sensoriales, así como en la salud de los ocupantes.
The Influence of Work Motivation, Compensation and Organizational Culture On Organizational Commitment Through Job Satisfaction As A Mediating Variable
Authors: Nurwisda Delaga , Suciningtyas Santi , Susidin Susidin 
Published: November 2023

Background: Public perception of public services is still influenced by the lack of organizational commitment of government officials.
Aim: this research is to analyze the mediating relationship between Work Motivation, Compensation and Organizational Culture through Job Satisfaction and Organizational Commitment Performance: a study of employees in public service agencies.
The objective of this research subject is Civil Servant at Disperindagkop Pemalang Regency. The population in this study is 96 employees.
Method: This study uses explanatory research for causal relationships between variables through hypothesis testing.sampling techniques with purposive sampling, The data analysis methods used are path analysis and Sobel tests to test indirect influences (mediation effects).
Findings: Based on the results of data analysis, several things were concluded, including: there is a significant direct effect of Work Motivation, Compensation and Organizational Culture on Organizational Commitment through Job Satisfaction as a mediating variable. In addition, Job Satisfaction also has a significant effect on employee Organizational Commitment.
ly acsept and use application technology to develop their business.
Effects of Steam Pretreated Rice Biomass Condensate Containing Soluble Solid Inhibitors on Disruption of Pomacea Canaliculata Egg
Authors: Khamis Nor Azahanim , Shamsudin Saleha , Zabidi Muhammad Hafiz , Kasim Khairul Farihan , Bahrin Ezyana Kamal 
Published: November 2023

Pomacea canaliculata is an invasive freshwater snail species that has become a serious pest of rice in irrigation and paddy fields and is popularly known as the golden apple snail. They are species that are capable of surviving and spreading rapidly, causing significant changes in the ecosystem. The application of natural by-products of a physicochemical method of biomass steam pre-treated condensate is one option for disrupting Pomacea Canaliculata egg. This experiment was conducted to investigate the feasibility of steam pre-treated rice biomass condensate which contained soluble solid inhibitors as a biopesticide to eradicate Pomacea canaliculata. Rice straw, rice husk, and a combination of rice straw and rice husk (1:1) were pre-treated by the saturated steam pre-treatment in a batch reactor at high temperatures (190°C and 210°C) for 10 min. The steam condensate produced from this system was analysed for major degraded products or inhibitors such as furfural, hydroxymethylfurfural (HMF), and phenol. The steam condensate which contained soluble solid inhibitors was then analysed for solubility test on P. canaliculata eggs. The effect of soluble solid inhibitors on the eggs was structurally examined by using a scanning electron microscope (SEM). The results revealed that rice husk which was pre-treated at 210°C reflected the highest contents of furfural (0.300 g/L), HMF (1.670 g/L), and phenol (0.087 g/L). However, the combination of rice biomass sample (1:1) condensate at 210°C demonstrated the greatest solubility percentage (11.51%) when treated to the eggs P. canaliculata eggs. The image of the egg structure examined by SEM clearly displayed the fractures forming on the cuticle layer of the eggs. SEM results demonstrated that the condensate from saturated steam pre-treated rice biomass has the possibility to be used as a biopesticide to disrupt the eggs and eventually could prevent the snails’ invasion.
A comparison of three‐film analysis software for stereotactic radiotherapy patient‐specific quality assurance
Authors: Buddhavarapu Athreya 
Published: November 2023

AbstractAimThe aim of this study was to investigate the suitability of three radiochromic film analysis software for stereotactic radiotherapy patient‐specific quality assurance (PSQA): FilmQA Pro v5.0, SNC Patient v6.2, and eFilmQA v5.0.MethodsFilm calibration was conducted for each software followed by three sets of measurements. The first set assessed calibration accuracy by comparing measured and delivered doses at increments different from those used for calibration. The second set used each software to conduct PSQA through gamma analysis on 10 stereotactic radiosurgery (SRS) and stereotactic body radiation therapy (SBRT) patients. The third set utilized SNC Patient and eFilmQA to carry out gamma analysis on a collection of four digital test images, eliminating delivery and scanning uncertainties from impacting the analysis. Key supporting features within each software for conducting gamma analysis were identified.ResultsOverall, FilmQA Pro and eFilmQA were deemed comparable and favoured over SNC Patient due to the presence of key features such as triple‐channel dosimetry, auto‐optimization, and dose scaling. FilmQA Pro has a substantial user base and established reputation. eFilmQA, having been introduced more recently, serves as a viable alternative to FilmQA Pro, having been further refined for stereotactic radiotherapy PSQA.ConclusionThis study investigated the suitability of three film analysis software (FilmQA Pro, eFilmQA, and SNC Patient) for stereotactic radiotherapy PSQA. Results from the investigation indicated that both FilmQA Pro and eFilmQA are comparably suitable and are preferred over SNC Patient. Both FilmQA Pro and eFilmQA are recommended for radiotherapy clinics.
In Vitro Mechanical Stimulation to Reproduce the Pathological Hallmarks of Human Cardiac Fibrosis on a Beating Chip and Predict The Efficacy of Drugs and Advanced Therapies
Authors: Visone Roberta , Paoletti Camilla , Cordiale Alessandro , Nicoletti Letizia , Divieto Carla , Rasponi Marco , Chiono Valeria , Occhetta Paola 
Published: November 2023

AbstractCardiac fibrosis is one of the main causes of heart failure, significantly contributing to mortality. The discovery and development of effective therapies able to heal fibrotic pathological symptoms thus remain of paramount importance. Micro‐physiological systems (MPS) are recently introduced as promising platforms able to accelerate this finding. Here a 3D in vitro model of human cardiac fibrosis, named uScar, is developed by imposing a cyclic mechanical stimulation to human atrial cardiac fibroblasts (AHCFs) cultured in a 3D beating heart‐on‐chip and exploited to screen drugs and advanced therapeutics. The sole provision of a cyclic 10% uniaxial strain at 1 Hz to the microtissues is sufficient to trigger fibrotic traits, inducing a consistent fibroblast‐to‐myofibroblast transition and an enhanced expression and production of extracellular matrix (ECM) proteins. Standard of care anti‐fibrotic drugs (i.e., Pirfenidone and Tranilast) are confirmed to be efficient in preventing the onset of fibrotic traits in uScar. Conversely, the mechanical stimulation applied to the microtissues limit the ability of a miRNA therapy to directly reprogram fibroblasts into cardiomyocytes (CMs), despite its proved efficacy in 2D models. Such results demonstrate the importance of incorporating in vivo‐like stimulations to generate more representative 3D in vitro models able to predict the efficacy of therapies in patients.
Hyaluronic Acid‐Based Reactive Oxygen Species‐Responsive Multifunctional Injectable Hydrogel Platform Accelerating Diabetic Wound Healing
Authors: Shi Chen , Zhang Ying , Wu Guanfu , Zhu Zhangyu , Zheng Haiping , Sun Ximeng , Heng Yongyuan , Pan Shaowei , Xiu Haonan , Zhang Jing , Yin Zhaowei , Yu Ziyi , Liang Bin 
Published: November 2023

AbstractDiabetic wounds are more likely to develop into complex and severe chronic wounds. The objective of this study is to develop and assess a reactive oxygen species (ROS)‐responsive multifunctional injectable hydrogel for the purpose of diabetic wound healing. A multifunctional hydrogel (HA@Cur@Ag) is successfully synthesized with dual antioxidant, antibacterial, and anti‐inflammatory properties by crosslinking thiol hyaluronic acid (SH‐HA) and disulfide‐bonded hyperbranched polyethylene glycol (HB‐PBHE) through Michael addition; while, incorporating curcumin liposomes and silver nanoparticles (AgNPs). The HA@Cur@Ag hydrogel exhibits favorable biocompatibility, degradability, and injectivity. The outcomes of in vitro and in vivo experiments demonstrate that the hydrogel can effectively be loaded with and release curcumin liposomes, as well as silver ions, thereby facilitating diabetic wound healing through multiple mechanisms, including ROS scavenging, bactericidal activity, anti‐inflammatory effects, and the promotion of angiogenesis. Transcriptome sequencing reveals that the HA@Cur@Ag hydrogel effectively suppresses the activation of the tumour necrosis factor (TNF)/nuclear factor κB (NF‐κB) pathway to ameliorate oxidative stress and inflammation in diabetic wounds. These findings suggest that this ROS‐responsive multifunctional injectable hydrogel, which possesses the ability to precisely coordinate and integrate intricate biological and molecular processes involved in wound healing, exhibits notable potential for expediting diabetic wound healing.
Chiral Plasmonic Hybrid Nanostructures: A Gateway to Advanced Chiroptical Materials
Authors: Tan Lili , Fu Wenlong , Gao Qi , Wang Peng‐peng 
Published: November 2023

AbstractChirality introduces a new dimension of functionality to materials, unlocking new possibilities across various fields. When integrated with plasmonic hybrid nanostructures, this attribute synergizes with plasmonic and other functionalities, resulting in unprecedented chiroptical materials that push the boundaries of the system's capabilities. Recent advancements have illuminated the remarkable chiral light–matter interactions within chiral plasmonic hybrid nanomaterials, allowing for the harnessing of their tunable optical activity and hybrid components. These advancements have led to applications in areas such as chiral sensing, catalysis, and spin optics. Despite these promising developments, there remains a need for a comprehensive synthesis of the current state‐of‐the‐art knowledge, as well as a thorough understanding of the construction techniques and practical applications in this field. This review begins with an exploration of the origins of plasmonic chirality and an overview of the latest advancements in the synthesis of chiral plasmonic hybrid nanostructures. Furthermore, representative emerging categories of hybrid nanomaterials are classified and summarized, elucidating their versatile applications. Finally, the review engages with the fundamental challenges associated with chiral plasmonic hybrid nanostructures and offer insights into the future prospects of this advanced field.
Multienzymatic Cascades and Nanomaterial Scaffolding—A Potential Way Forward for the Efficient Biosynthesis of Novel Chemical Products
Authors: Hooe Shelby L. , Smith Aaron D. , Dean Scott N. , Breger Joyce C. , Ellis Gregory A. , Medintz Igor L. 
Published: November 2023

AbstractSynthetic biology is touted as the next industrial revolution as it promises access to greener biocatalytic syntheses to replace many industrial organic chemistries. Here, it is shown to what synthetic biology can offer in the form of multienzyme cascades for the synthesis of the most basic of new materials—chemicals, including especially designer chemical products and their analogs. Since achieving this is predicated on dramatically expanding the chemical space that enzymes access, such chemistry will probably be undertaken in cell‐free or minimalist formats to overcome the inherent toxicity of non‐natural substrates to living cells. Laying out relevant aspects that need to be considered in the design of multi‐enzymatic cascades for these purposes is begun. Representative multienzymatic cascades are critically reviewed, which have been specifically developed for the synthesis of compounds that have either been made only by traditional organic synthesis along with those cascades utilized for novel compound syntheses. Lastly, an overview of strategies that look toward exploiting bio/nanomaterials for accessing channeling and other nanoscale materials phenomena in vitro to direct novel enzymatic biosynthesis and improve catalytic efficiency is provided. Finally, a perspective on what is needed for this field to develop in the short and long term is presented.
Plasmon‐Coupled GaN Microcavity for WGM Lasing and Label‐Free SERS Sensing of Biofluids
Authors: Sun Jianli , Mao Wangqi , Xia Chuansheng , Wang Weian , Cui Qiannan , Shi Zengliang , Zhu Gangyi , Wang Mingliang , Xu Chunxiang 
Published: November 2023

AbstractA signal amplification strategy is always required to improve sensing performance, especially for mass‐prepared, miniature and highly sensitive testing equipment. Herein, an on‐chip integrated biosensor combining microcavity lasing and surface enhanced Raman scattering (SERS) for label‐free biochemical analysis is developed. The gallium nitride (GaN) microrings array is fabricated as a whispering gallery mode microlaser based on totally internal wall reflection, and gold nanoparticles (AuNPs) are further assembled on the cavity surface to confine the optical field synergistically. The improvement of lasing capability indicates the strong light‐matter interaction that is conducive to superior response of biomolecules. As a functional example, a GaN/AuNPs substrate is employed in a urine assay, which avoids the shortcomings of requiring specific reactive reagents on different display modules. Ultimately, the chip not only realizes a wide range of pH (3.6–7.8) identification depending on the ultra‐sensitivity feedback of lasing to the refractive index of liquids, but also significantly enhances SERS signals to enable real‐time determination of the biomolecules in human urine. Even the lowest levels of creatinine (0.02%) can be quantitatively detected in less than a minute; thus this work with dual‐mode spectral analyses realizes rapid diagnosis for urinary systems, as well as provides a more accurate reference for the screening of other diseases.
The Impact of Microstructure on Filament Growth at the Sodium Metal Anode in All‐Solid‐State Sodium Batteries
Authors: Ding Ziming , Tang Yushu , Ortmann Till , Eckhardt Janis Kevin , Dai Yuting , Rohnke Marcus , Melinte Georgian , Heiliger Christian , Janek Jürgen , Kübel Christian 
Published: November 2023

AbstractIn recent years, all‐solid‐state batteries (ASSBs) with metal anodes have witnessed significant developments due to their high energy and power density as well as their excellent safety record. While intergranular dendritic lithium growth in inorganic solid electrolytes (SEs) has been extensively studied for lithium ASSBs, comparable knowledge is missing for sodium‐based ASSBs. Therefore, polycrystalline Na‐β″‐alumina is employed as a SE model material to investigate the microstructural influence on sodium filament growth during deposition of sodium metal at the anode. The research focuses on the relationship between the microstructure, in particular grain boundary (GB) type and orientation, sodium filament growth, and sodium ion transport, utilizing in situ transmission electron microscopy (TEM) measurements in combination with crystal orientation analysis. The effect of the anisotropic sodium ion transport at/across GBs depending on the orientation of the sodium ion transport planes and the applied electric field on the current distribution and the position of sodium filament growth is explored. The in situ TEM analysis is validated by large field of view post‐mortem secondary ion mass spectrometer (SIMS) analysis, in which sodium filament growth within voids and along grain boundaries is observed, contributing to the sodium network formation potentially leading to failure of batteries.
Ferroelectric Layer‐Assisted Asymmetric Heterojunction Boosts Power Output in Silicon Hydrovoltaic Device
Authors: Song Yuhang , Song Zheheng , Jiang Conghui , Xing Chunfang , Zeng Xuelian , Zhang Zekun , Chen Zhewei , Song Tao , Shao Beibei , Wang Yusheng , Sun Baoquan 
Published: November 2023

AbstractHydrovoltaic devices (HDs) that convert ubiquitous environmental energy via water evaporation serves as a prospective technology for renewable power schemes. However, it remains a grand challenge to perform controllable and stable modulation of hydrovoltaic power generation for multi‐scenario practical applications. Here, a ferroelectric‐field assisted silicon HD is proposed, which sandwiches an ultrathin polarizable polymer between nanostructured silicon and the top electrode, constituting an asymmetric heterojunction designed to clinch well‐regulated and robust electrical signal output. Tunable modulation of the internal electric field at the silicon/top electrode interface can be realized by facilely aligning the polarization orientation of the ferroelectric domains, thus dominating the silicon energy band bending and controlling the ultimate electrical signal. Upon effective forward polarization, the interfacial dipoles can build a stronger asymmetric electric field, which allows an efficient sweep of the charges out of the heterojunction. Accordingly, the resulting device clinches to yield a considerably modulated voltage of 1.04 V, nearly three‐fold modulation over the reverse polarization one. As prospective applications, multifunctional sensing platforms including the self‐sufficient environmental temperature detector, intelligent water‐level alarm system, and automatic‐manual dual‐mode irrigation control system are demonstrated. This work exhibits the unique characteristics of ferroelectric HDs with tunable electrical performance.
Achieving pH‐universal electrosynthesis of formate under industrial‐grade current density by enriched selenium vacancies
Authors: Zhao Zilin , Hu Xiangzhao , Liu Yingnan , Wang Dashuai , Yang Bin , Li Zhongjian , Gao Xiang , Hu Xiaobing , Lei Lecheng , Hou Yang 
Published: November 2023

AbstractElectrosynthesis of formate via CO2 reduction (CO2ER) is of great significance for completing carbon cycle, however, low CO2 utilization efficiency caused by slow reaction kinetics greatly hinder its large‐scale application. Herein, we reported a ~50 nm‐thick SnSe2 nanosheets with enriched Se vacancies, which exhibits an excellent catalytic activity for pH‐universal formate electrosynthesis. In alkaline, neutral, and acidic electrolytes, this catalyst reached up to the maximum formate Faradaic efficiencies of 94.1%, 81.7%, and 78.1%, respectively. Under corresponding pH conditions, the maximum formate partial current densities achieved 800, 568, and 495 mA cm−2, respectively. Kinetic experiments combined with in situ electrochemical spectroscopy unveiled that the abundant Se vacancies promoted the dissociation of water to produce more protons, thereby accelerating the formation rate of key *OOCH intermediate. Theoretical calculations validated that the formation of enriched Sn active sites lowered the energy barrier for the *OOCH formation, eventually facilitating the formate electrosynthesis process.
Plant protein and animal protein‐based Pickering emulsion: A review of preparation and modification methods
Authors: Wen Jiayu , Jiang Lianzhou , Sui Xiaonan 
Published: November 2023

AbstractProtein‐based Pickering emulsions are gaining popularity due to their biocompatibility and alignment with people's pursuit of health. This review focuses on recent advances in the preparation of Pickering emulsions using various plant and animal proteins from different sources. For sustainability and cost reasons, plant proteins are preferred, while animal proteins provide better nutritional quality. According to the type of plant or animal protein, the suitable modification and preparation methods of stable Pickering emulsion are summarized, including heating, enzyme induction, anti‐solvent precipitation, pH‐cycling, glycosylation, microwave heating, spray drying, and high hydrostatic pressure. Different methods were employed to modify the properties of Pickering emulsion particles at the oil–water interface. To overcome the amphiphilicity limitations of some proteins, substances such as polysaccharides or polyphenols were combined to improve the physical and chemical properties of the particles. Additionally, this review analyzes the effect of different protein particle sources on the properties of Pickering emulsions.
Structural elements and spheres of expertise: Creating a healthy ecosystem for cultural data initiatives
Authors: Given Lisa M. , Polkinghorne Sarah , Cattlin Joann 
Published: November 2023

AbstractWhile technology affords creation of digital collections, and promises access to all, the reality is that many cultural data collections exist in a precarious ecosystem, where erratic funding, fragmented support, and disconnected expertise threaten their continued existence. As a significant branch of the broader information ecosystem, cultural data collections range in size and scope, from national institutions to bespoke local collections supported by individuals. This exploratory, qualitative study engaged cultural data experts in Australia, Canada, and the United Kingdom to map the broad cultural data ecosystem and to identify opportunities for healthier growth. The development and maintenance of cultural data collections requires integration across the spheres of expertise of creators, curators, subject matter experts, information science, and computing and technology. The foundational structural elements of the ecosystem include funding, policies, access to existing data, community context, and technological infrastructure. The key elements of a healthy data ecosystem are clarity of purpose, user‐focused design, sustainability, allied coproduction, and reciprocal interconnection. A healthier cultural data ecosystem means more collections and initiatives will have positive impacts for research, knowledge, and diverse communities, contributing positively to the broader information ecosystem and to society, at large.