bluuebunny/crossref_metadata_2025_split huggingface dataset:
Féminisation d’un discours public sur la langue à Moncton entre 1947 et 1965 : les traces archivistiques d’une honte linguistique
Authors: LeBlanc Isabelle 
Published: October 2023

Dans ce texte, je m’intéresserai à l’existence de traces archivistiques attestant de la féminisation d’un discours public sur la langue dans la région de Moncton dans la période précédant l’adoption du bilinguisme officiel par la province du Nouveau-Brunswick. En mobilisant un petit corpus d’archives de presse datant de 1947 à 1965, je propose une réflexion sur la mise en discours par les femmes d’une honte linguistique. En effet, Annette Boudreau (2021) développe amplement la notion de « honte sociale » dans son plus récent ouvrage qui s’intitule Dire le silence : insécurité linguistique en Acadie 1867-1970. Elle conçoit la honte comme participant à l’insécurité linguistique et identitaire d’un groupe, source de silence collectif (apprendre à se taire). Pour ma part, je m’appuierai sur Boudreau afin de mener une réflexion théorique sur la honte à partir de paroles de femmes. L’objectif sera d’examiner comment les archives de femmes permettent de penser la honte linguistique au-delà du silence pour s’intéresser au discours d’émancipation linguistique.
Les mondes enfouis d’Anne Suzanne Richard. Une marge d’autonomisation féminine après la Déportation (1785-1789)
Authors: Vasquez-Parra Adeline 
Published: October 2023

Au lendemain du traité de Paris (1763), une nouvelle génération d’Acadiens et d’Acadiennes voit le jour : celle des enfants de déportés. Nombre d’entre eux se trouvent en France à partir de 1758. Cette génération n’a pas beaucoup connu l’Acadie et a grandi dans des communautés de réfugié·es. Celle-ci se trouve tiraillée entre les sentiments de nostalgie de ses aîné·es et les nouvelles opportunités sociales et professionnelles offertes par la France des années prérévolutionnaires alors en pleine mutation politique et économique. Alors que se découvrent au XIXe siècle certains « destins » de femmes issues de la Déportation, cet article revient sur celui d’Anne Suzanne Richard, tailleuse et lingère acadienne à Morlaix, en Bretagne, pour rendre compte d’une « marge d’autonomisation ». Ce concept renvoie au façonnement d’un réseau de connexions sociales dans la poursuite d’un but propre échappant au contrôle total du pouvoir communautaire et/ou étatique. L’une de ces marges est ici étudiée en lui octroyant une orientation spécifiquement féminine : la relation épistolaire entre Richard et une aristocrate bretonne, la comtesse Marie Jeanne Jégou du Laz. Au cours de leurs échanges entre 1785 et 1789, l’autonomie féminine se dévoile loin de toute conception homogène et réifiée de la catégorie historique de « femme réfugiée ». Des relations sociales se nouent autour d’Anne Suzanne Richard pour la placer dans des interactions avec différents milieux sociaux et professionnels, de la sphère domestique à la sphère publique. En cela, la marge d’autonomisation ouvre sur un nouveau traitement archivistique des femmes acadiennes réfugiées par l’exploration de nouvelles dynamiques de réseaux entreprises entre agentes historiques, communautés marchandes et acteurs indépendants après la Déportation.
Prediction models of macro-nutrient content in plant organs ofCucumis meloin response to soil elements using support vector regression
Authors: Keshtehgar Abbas , Dahmardeh Mahdi , Ghanbari Ahmad , Khammari Issa 
Published: October 2023

BackgroundUndoubtedly, the importance of food and food security as one of the present and future challenges is not invisible to anyone. Nowadays, the development of methods for monitoring the nutrient content in crop products is an essential issue for implementing reasonable and logical soil properties management. The modeling technique can evaluate the soil properties of fields and study the subject of crop yield through soil management. This study aims to predict fruit yield and macro-nutrient content in plant organs ofCucumis meloin response to soil elements using support vector regression (SVR).MethodologyIn the spring of 2020, this study was done as a factorial test in a randomized complete block design with three replications. The first factor was the use of fertilizers in six levels: no fertilizer (control), cow manure (30 t ha−1), sheep manure (30 t ha−1), nanobiomic foliar application (2 l ha−1), silicone foliar application (3 l ha−1), and chemical fertilizer from urea, triple superphosphate, and potassium sulfate sources (200, 100, and 150 kg ha−1). In addition, four levels of vermicompost considering as the second factor: no vermicompost (control), 5, 10, and 15 t ha−1. Input data sets such as fruit yield and nitrogen, phosphorus, and potassium levels in the seeds, fruits, leaves, and roots are used to calibrate the probabilistic model of SP using SVR.ResultsAccording to the results, when the data sets of the nitrogen, phosphorus, and potassium in the fruit uses as input, the accuracy of these models was higher than 80.0% (R2= 0.807 for predicting fruit nitrogen; R2= 0.999 for fruit phosphorus; R2= 0.968 for fruit potassium). Also, the results of the prediction models in response to soil elements showed that the soil nitrogen content ranged from 0.05 to 1.1%, soil phosphorus from 10 to 59 mg kg−1, and soil potassium from 180 to 320 mg kg−1, which offers a suitable macro-nutrient content in the soil. Likewise, the best fruit nitrogen content ranged from 1.27 to 4.33%, fruit phosphorus from 15.74 to 26.19%, fruit potassium from 15.19 to 19.67%, and fruit yield from 2.16 to 5.95 kg per plant obtained under NPK chemical fertilizers and using 15 t ha−1of vermicompost.ConclusionsBecause the fruit values had the highest contribution in prediction than observed values, thus identified as the best plant organs in response to soil elements. Based on our findings, the importance of fruit phosphorus identifies as a determinant that strongly influenced melon prediction models. More significant values of soil elements do not affect increasing fruit yield and macro-nutrient content in plant organs, and excessive application may not be economical. Therefore, our studies provide an efficient approach with potentially high accuracy to estimate fruit yield and macro-nutrient in the fruits ofCucumis meloin response to soil elements and cause a saving in the amount of fertilizer during the growing season.
Different patterns of foreground and background processing contribute to texture segregation in humans: an electrophysiological study
Authors: Zhang Baoqiang , Hu Saisai , Zhang Tingkang , Hai Min , Wang Yongchun , Li Ya , Wang Yonghui 
Published: October 2023

Background
Figure-ground segregation is a necessary process for accurate visual recognition. Previous neurophysiological and human brain imaging studies have suggested that foreground-background segregation relies on both enhanced foreground representation and suppressed background representation. However, in humans, it is not known when and how foreground and background processing play a role in texture segregation.

Methods
To answer this question, it is crucial to extract and dissociate the neural signals elicited by the foreground and background of a figure texture with high temporal resolution. Here, we combined an electroencephalogram (EEG) recording and a temporal response function (TRF) approach to specifically track the neural responses to the foreground and background of a figure texture from the overall EEG recordings in the luminance-tracking TRF. A uniform texture was included as a neutral condition. The texture segregation visual evoked potential (tsVEP) was calculated by subtracting the uniform TRF from the foreground and background TRFs, respectively, to index the specific segregation activity.

Results
We found that the foreground and background of a figure texture were processed differently during texture segregation. In the posterior region of the brain, we found a negative component for the foreground tsVEP in the early stage of foreground-background segregation, and two negative components for the background tsVEP in the early and late stages. In the anterior region, we found a positive component for the foreground tsVEP in the late stage, and two positive components for the background tsVEP in the early and late stages of texture processing.

Discussion
In this study we investigated the temporal profile of foreground and background processing during texture segregation in human participants at a high time resolution. The results demonstrated that the foreground and background jointly contribute to figure-ground segregation in both the early and late phases of texture processing. Our findings provide novel evidence for the neural correlates of foreground-background modulation during figure-ground segregation in humans.
Encounter Appropriateness Score for You Model: Development and Pilot Implementation of a Predictive Model to Identify Visits Appropriate for Telehealth in Rheumatology
Authors: Solomon Mary , Henao Ricardo , Economau‐Zavlanos Nicoleta , Smith Isaac , Adagarla Bhargav , Overton A. J. , Howe Catherine , Doss Jayanth , Clowse Megan , Leverenz David L. 
Published: October 2023

ObjectiveWe aimed to develop a decision‐making tool to predict telehealth appropriateness for future rheumatology visits and expand telehealth care access.MethodsThe model was developed using the Encounter Appropriateness Score for You (EASY) and electronic health record data at a single academic rheumatology practice from January 1, 2021, to December 31, 2021. The EASY model is a logistic regression model that includes encounter characteristics, patient sociodemographic and clinical characteristics, and provider characteristics. The goal of pilot implementation was to determine if model recommendations align with provider preferences and influence telehealth scheduling. Four providers were presented with future encounters that the model identified as candidates for a change in encounter modality (true changes), along with an equal number of artificial (false) recommendations. Providers and patients could accept or reject proposed changes.ResultsThe model performs well, with an area under the curve from 0.831 to 0.855 in 21,679 encounters across multiple validation sets. Covariates that contributed most to model performance were provider preference for and frequency of telehealth encounters. Other significant contributors included encounter characteristics (current scheduled encounter modality) and patient factors (age, Routine Assessment of Patient Index Data 3 scores, diagnoses, and medications). The pilot included 201 encounters. Providers were more likely to agree with true versus artificial recommendations (Cohen's κ = 0.45, P < 0.001), and the model increased the number of appropriate telehealth visits.ConclusionThe EASY model accurately identifies future visits that are appropriate for telehealth. This tool can support shared decision‐making between patients and providers in deciding the most appropriate follow‐up encounter modality.
Transcranial Direct Current Stimulation for Knee Osteoarthritis: A Systematic Review and Meta‐Analysis of Randomized Controlled Trials
Authors: Yang Jia‐Man , Li Cong‐Cong , Wang Yi , Li Jun‐Yi , Xu Jian‐Mei , Liang Man‐Guang , Ou Liang , Shen Zhen , Chen Ze‐Hua 
Published: October 2023

ObjectiveThe effects of transcranial direct current stimulation (tDCS) in the treatment of knee osteoarthritis (KOA) is still unclear. The objective is to evaluate the efficacy and safety of tDCS in improving symptoms in patients with KOA.MethodsThe following electronic databases were searched for eligible randomized controlled trials (RCTs): PubMed, Embase, Web of Science, and the Cochrane Library. The search was performed from the inception dates to April 30, 2023. Data extraction and quality assessment were performed by two independent reviewers. Standard mean differences (SMDs) with 95% confidence intervals (95% CIs) for pooled data were calculated. A random‐effects model was used for the data analyses. The primary outcomes were pain and physical function. Secondary outcomes included stiffness, mobility performance, quality of life, pressure pain tolerance, and plasma levels of brain‐derived neurotrophic factor (BDNF).ResultsThis meta‐analysis included 13 RCTs. tDCS was significantly associated with pain decrease compared with sham tDCS (SMD = −0.62, 95% CI −0.87 to −0.37, P < 0.00001). When comparing tDCS plus other non‐tDCS with sham tDCS plus other non‐tDCS, there was no longer a significant association with pain decrease (SMD = −0.45, 95% CI −1.08 to 0.17, P = 0.16). The changes in physical function were not significantly different between the tDCS and sham tDCS groups (SMD = −0.09, 95% CI −0.56 to 0.38, P = 0.71). When comparing tDCS plus other non‐tDCS with sham tDCS plus other non‐tDCS, there was still no significant association with improvement in physical function (SMD = −0.66, 95% CI −1.63 to 0.30, P = 0.18). There was no significant difference with improvement in stiffness (SMD = −0.21, 95% CI −0.77 to 0.34, P = 0.45), mobility performance (SMD = 4.58, 95% CI −9.21 to 18.37, P = 0.51), quality of life (SMD = −7.01, 95% CI −22.61 to 8.59, P = 0.38), and pressure pain tolerance (SMD = 0.30, 95% CI −0.09 to 0.69, P = 0.13). There was a statistically significant reduction in plasma levels of BDNF (SMD = −13.57, 95% CI −24.23 to −2.92, P = 0.01).ConclusionIn conclusion, tDCS could significantly alleviate pain, but it might have no efficacy in physical function, stiffness, mobility performance, quality of life, and pressure pain tolerance among patients with KOA.
Photo‐Responsive Dynamic Organic Room‐Temperature Phosphorescence Materials Based on a Functional Unit Combination Strategy
Authors: Yang Zhiqiang , Liu Haichao , Zhang Xiangyu , Lv Yingbo , Fu Zhiyuan , Zhao Shuaiqiang , Liu Meng , Zhang Shi‐Tong , Yang Bing 
Published: October 2023

AbstractA rational molecular design strategy facilitates the development of a purely organic room‐temperature phosphorescence (RTP) material system with precisely regulated luminescence properties, which surely promotes its functional integration and intelligent application. Here, a functional unit combination strategy is proposed to design novel RTP molecules combining a folding unit with diverse luminescent cores. The different luminescent cores are mainly responsible for tunable RTP properties, while the folding unit contributes to the spin–orbit coupling (SOC) enhancement, which makes the RTP material design as workable as the building block principle. By this strategy, a series of color/lifetime‐tunable RTP materials is achieved with unique photo‐responsive RTP enhancement when subjected to UV irradiation, which expands their application scenarios in reusable privacy tags, advanced “4D” encryption, and phase separation analysis of blended polymers. This work suggests a simple and effective strategy to design purely organic RTP materials with tunable color and lifetime, and also provides new application options for photo‐responsive dynamic RTP materials.
“The most significant child welfare reform in a generation”: An examination of the strategies used by the Home Stretch campaign
Authors: Mendes Philip 
Published: October 2023

AbstractFor more than three decades, official and independent enquiries have documented the poor outcomes experienced by many young people transitioning from out‐of‐home care (OOHC) in Australia, known as care leavers. Yet, until 2017, most of the state and territory governments cut off financial support to these vulnerable young people at no later than 18 years of age and failed to provide them with the ongoing material and relationship assistance into early adulthood guaranteed to most of their non‐care peers. Australia was regarded internationally as a leaving care laggard. This paper examines the remarkably effective advocacy strategies used by the Home Stretch campaign, formed in 2016, to persuade all Australian jurisdictions to extend OOHC until 21 years. By the end of 2022, every state and territory had agreed to introduce some form of extended care, and Australia was recognised as a global leader in leaving care policy and programmes provision.
Getting more value from Australian Intergenerational Reports
Authors: Podger Andrew 
Published: October 2023

AbstractThis article highlights the lessons learned from a study of the 2021 Intergenerational Report hosted by the Academy of the Social Sciences in Australia. That study, published in a book, More than Fiscal, (Podger et al., 2023, More than Fiscal, ANU Press), also advises how to improve future IGRs. The article includes a brief assessment of the extent to which the recently published 2023 IGR takes up the improvements suggested.
Isomer Effect on Energy Storage of π‐Extended S‐Shaped Double[6]Heterohelicene
Authors: Kumar Viksit , Bharathkumar H. J. , Dongre Sangram D. , Gonnade Rajesh , Krishnamoorthy Kothandam , Babu Sukumaran Santhosh 
Published: October 2023

AbstractRecently, chiral and nonplanar cutouts of graphene have been the favorites due to their unique optical, electronic, and redox properties and high solubility compared with their planar counterparts. Despite the remarkable progress in helicenes, π‐extended heterohelicenes have not been widely explored. As an anode in a lithium‐ion battery, the racemic mixture of π‐extended double heterohelical nanographene containing thienothiophene core exhibited a high lithium storage capability, attaining a specific capacity of 424 mAh g−1 at 0.1 A g−1 with excellent rate capability and superior long‐term cycling performance over 6000 cycles with negligible fade. As a first report, the π‐extended helicene isomer (PP and MM), with the more interlayer distance that helps faster diffusion of ions, has exhibited a high capacity of 300 mAh g−1 at 2 A g−1 with long‐term cycling performance over 1500 cycles compared to the less performing MP and PM isomer and racemic mixture (150 mAh g−1 at 2 A g−1). As supported by single‐crystal X‐ray analysis, a unique molecular design of nanographenes with a fixed (helical) molecular geometry, avoiding restacking of the layers, renders better performance as an anode in lithium‐ion batteries. Interestingly, the recycled nanographene anode material displayed comparable performance.
Pyrazine‐linked Iron‐coordinated Tetrapyrrole Conjugated Organic Polymer Catalyst with Spatially Proximate Donor‐Acceptor Pairs for Oxygen Reduction in Fuel Cells
Authors: Wang Yang , Wang Minghao , Chen Ting , Yu Weisheng , Liu Hongfei , Cheng Han , Bi Wentuan , Zhou Min , Xie Yi , Wu Changzheng 
Published: October 2023

AbstractNitrogen‐coordinated iron (Fe−N4) materials represent the most promising non‐noble electrocatalysts for the cathodic oxygen reduction reaction (ORR) of fuel cells. However, molecular‐level structure design of Fe−N4 electrocatalyst remains a great challenge. In this study, we develop a novel Fe−N4 conjugated organic polymer (COP) electrocatalyst, which allows for precise design of the Fe−N4 structure, leading to unprecedented ORR performance. At the molecular level, we have successfully organized spatially proximate iron‐pyrrole/pyrazine (FePr/Pz) pairs into fully conjugated polymer networks, which in turn endows FePr sites with firmly covalent‐bonded matrix, strong d‐π electron coupling and highly dense distribution. The resulting pyrazine‐linked iron‐coordinated tetrapyrrole (Pz−FeTPr) COP electrocatalyst exhibits superior performance compared to most ORR electrocatalysts, with a half‐wave potential of 0.933 V and negligible activity decay after 40,000 cycles. When used as the cathode electrocatalyst in a hydroxide exchange membrane fuel cell, the Pz−FeTPr COP achieves a peak power density of ≈210 mW cm−2. We anticipate the COP based Fe−N4 catalyst design could be an effective strategy to develop high‐performance catalyst for facilitating the progress of fuel cells.
Photocatalytic Enantioselective Hydrosulfonylation of α,β‐Unsaturated Carbonyls with Sulfonyl Chlorides
Authors: Cao Shi , Kim Doyoung , Lee Wooseok , Hong Sungwoo 
Published: October 2023

AbstractThis research explores the enantioselective hydrosulfonylation of various α,β‐unsaturated carbonyl compounds via the use of visible light and redox‐active chiral Ni‐catalysis, facilitating the synthesis of enantioenriched α‐chiral sulfones with remarkable enantioselectivity (exceeding 99 % ee). A significant challenge entails enhancing the reactivity between chiral metal‐coordinated carbonyl compounds and moderate electrophilic sulfonyl radicals, aiming to minimize the background reactions. The success of our approach stems from two distinctive attributes: 1) the Cl‐atom abstraction employed for sulfonyl radical generation from sulfonyl chlorides, and 2) the single‐electron reduction to produce a key enolate radical Ni‐complex. The latter process appears to enhance the feasibility of the sulfonyl radical's addition to the electron‐rich enolate radical. An in‐depth investigation into the reaction mechanism, supported by both experimental observations and theoretical analysis, offers insight into the intricate reaction process. Moreover, the versatility of our methodology is highlighted through its successful application in the late‐stage functionalization of complex bioactive molecules, demonstrating its practicality as a strategy for producing α‐chiral sulfones.
The impact of green innovation on sustainability and financial performance: Evidence from the Jordanian financial sector
Authors: Srouji Anan F. , Hamdallah Madher E. , Al‐Hamadeen Radhi , Al‐Okaily Manaf , Elamer Ahmed A. 
Published: October 2023

AbstractThe purpose of this study is to examine the relationship between sustainability performance (SP) and financial performance (FP), based on performance disclosures (reporting) of the Jordanian financial sector for the period of 2017–2020. The study employs green innovation (GI) indicators as moderating and mediating variables; by using hierarchical regression; as means of unlocking and examining the relationship between SP and FP; through the lens of the stakeholder theory. The hierarchical regression findings suggest that GI indicators partially mediate the relationship between SP and FP, but do not demonstrate a moderating effect. As a main result, it is indicated that Jordanian financial institutions may use SP transparency indicators as an incentive variable, which could influence their overall FP. The research also contributes to the existing literature by adding insight into the use of GI indicators in a developing country and the potential impact on financial institutions markets. These findings lend empirical credence to the generally held belief that increase disclosure benefits for both internal and external users.