bluuebunny/crossref_metadata_2025_split huggingface dataset:
Tofukasu-derived biochar with interconnected and hierarchical pores for high efficient removal of Cr (VI)
Authors: Fang Liang , Yang Wei , Hou Jianhua , Zheng kewang , Hussain Asif , Zhang Yongcai , Hou Zhenhua , Wang Xiaozhi 
Published: October 2023

AbstractHerein, we report the synthesis of interconnected hierarchical pore biochar (HTB) via an ice-templating strategy using bio-waste (tofukasu). The abundance of N- and O-containing functional groups in tofukasu makes it easy to form hydrogen bonds with water molecules and water clusters, resulting in nano-micro structures like ice clusters and snow crystals during freezing process. More importantly, tofukasu will be squeezed by micron-scale snow crystals to form coiled sheet-like structures, and its surface and interior will be affected by needle-like ice nanocrystals from several nanometers to tens of nanometers to form transverse groove needles and mesopores. The ice crystals are then removed by sublimation with tofukasu, leaving the interconnected pore structure intact. Therefore, the ice template synthesis strategy endowed the interconnected hierarchical pore structure of HTB with a large specific surface area (SBET, 733 m2⋅g−1) and hierarchical porosity (30.30% for mesopores/total pore volume ratio), which is significantly higher than the normal dry treated tofukasu biochar (TB), which had a SBET of 436 m2⋅g−1 and contained 1.53% mesopores. In addition, the sheet-like structure with interconnected pores of HTB favors high exposure of active sites (N- and O-containing functional groups), and a fast electron transport rate. As a result, HTB had an excellent adsorption capacity of 159.65 mg⋅g−1, which is 4.7 times that of typical block biochar of TB (33.89 mg⋅g−1) according to Langmuir model. Electrochemical characterization, FTIR and XPS analysis showed that the mechanism of Cr(VI) removal by HTB included electrostatic attraction, pore filling, reduction and surface complexation.
Graphical Abstract
Physical Fitness of Thoroughbred Horse Racing Jockeys
Authors: Legg Kylie A. , Cochrane Darryl J. , Gee Erica K. , Chin Yin Y. , Rogers Chris W. 
Published: October 2023

Abstract
Purpose
Thoroughbred racing jockeys compete at maximum physiological capacity in a sport with a high risk of falls and injury. A greater understanding of the physical capacities determining jockey performance may lead to minimum physical performance parameters and corrective interventions to improve jockey fitness and performance and reduce jockey and horse injury. The aim of this study was to develop appropriate physical testing procedures for jockeys and a physical fitness profile for different licence levels.

Methods
Fifty-eight jockeys (n = 24 females, n = 34 males), representing all apprentice jockeys licenced in New Zealand in 2021 (100%, n = 8 probationers and n = 39 apprentices) and eleven professional jockeys (14%) were assessed to determine baseline physiological and fitness data. Descriptive statistics and boxplots were used to compare aerobic fitness, abdominal (core), upper and lower body strength, muscular power, reaction time, flexibility and a novel ‘saddle’ test targeting lower body strength, balance, and endurance between licencing levels. Effect Size (ES) was used to determine magnitude of differences between groups.

Results
More experienced jockeys had greater relative lower body strength (ES = 0.2–0.7) and better balance (ES = 0.5–0.9) compared to the less experienced groups. Jockeys who were in the top 20 of the premiership table (jockey rankings) had faster reaction times (ES = 0.7) and greater core extensor strength (ES = 0.7) than other cohorts. Most tests showed little differentiation between jockey licence levels, however the ‘saddle test’ showed greater variability in the less experienced race riders. This test may be an effective measure of jockey baseline performance.

Conclusions
These data could be used to inform minimum jockey licencing requirements and future physical fitness training programmes to increase jockey physiological fitness, thereby minimising risk of falls or injury due to physiological deficits and performance.
Flexible Institution Building in the International Anti-corruption Regime: Proposing a Transnational Asset Recovery Mechanism
Authors: Helfer Laurence R. , Rose Cecily , Brewster Rachel 
Published: October 2023

AbstractAsset recovery is a fundamental principle of anti-corruption law, without which the financial damage from corruption cannot be repaired. Yet recovering assets is notoriously difficult and time-consuming, and the United Nations Convention Against Corruption provides little technical or institutional support to facilitate such returns. To remedy this, we propose the creation of a transnational asset recovery mechanism that could provide myriad services to states upon request, including gathering and publishing information, providing technical assistance and capacity building, helping to conclude agreements on asset return, and monitoring returned funds. Theoretically, we introduce the concepts of customizability and selectability to explain why a flexible transnational asset recovery mechanism has advantages over more formal international institutions, such as an international anti-corruption court. These benefits include lower financial and political costs, enhanced adaptability, and a greater likelihood of enhancing interstate cooperation regarding asset returns.
Prefix monoids of groups and right units of special inverse monoids
Authors: Dolinka Igor , Gray Robert D. 
Published: October 2023

AbstractA prefix monoid is a finitely generated submonoid of a finitely presented group generated by the prefixes of its defining relators. Important results of Guba (1997), and of Ivanov, Margolis and Meakin (2001), show how the word problem for certain one-relator monoids, and inverse monoids, can be reduced to solving the membership problem in prefix monoids of certain one-relator groups. Motivated by this, in this paper, we study the class of prefix monoids of finitely presented groups. We obtain a complete description of this class of monoids. All monoids in this family are finitely generated, recursively presented and group-embeddable. Our results show that not every finitely generated recursively presented group-embeddable monoid is a prefix monoid, but for every such monoid, if we take a free product with a suitably chosen free monoid of finite rank, then we do obtain a prefix monoid. Conversely, we prove that every prefix monoid arises in this way. Also, we show that the groups that arise as groups of units of prefix monoids are precisely the finitely generated recursively presented groups, whereas the groups that arise as Schützenberger groups of prefix monoids are exactly the recursively enumerable subgroups of finitely presented groups. We obtain an analogous result classifying the Schützenberger groups of monoids of right units of special inverse monoids. We also give some examples of right cancellative monoids arising as monoids of right units of finitely presented special inverse monoids, and we show that not all right cancellative recursively presented monoids belong to this class.
Modeling Denitrification: Can We Report What We Don't Know?
Authors: Grosz B. , Matson A. , Butterbach‐Bahl K. , Clough T. , Davidson E. A. , Dechow R. , DelGrosso S. , Diamantopoulos E. , Dörsch P. , Haas E. , He H. , Henri C. V. , Hui D. , Kleineidam K. , Kraus D. , Kuhnert M. , Léonard J. , Müller C. , Petersen S. O. , Sihi D. , Vogeler I. , Well R. , Yeluripati J. , Zhang J. , Scheer C. 
Published: October 2023

AbstractBiogeochemical models simulate soil nitrogen (N) turnover and are often used to assess N losses through denitrification. Though models simulate a complete N budget, often only a subset of N pools/fluxes (i.e., N2O, , NH3, NOx) are published since the full budget cannot be validated with measured data. Field studies rarely include full N balances, especially N2 fluxes, which are difficult to quantify. Limiting publication of modeling results based on available field data represents a missed opportunity to improve the understanding of modeled processes. We propose that the modeler community support publication of all simulated N pools and processes in future studies.
Kinetic Modeling of Radiation Belt Electrons With Geant4 to Study Energetic Particle Precipitation in Earth's Atmosphere
Authors: Berland G. D. , Marshall R. A. , Capannolo L. , McCarthy M. P. , Zheng L. 
Published: October 2023

AbstractWe present a new model designed to simulate the process of energetic particle precipitation, a vital coupling mechanism from Earth's magnetosphere to its atmosphere. The atmospheric response, namely excess ionization in the upper and middle atmosphere, together with bremsstrahlung X‐ray production, is calculated with kinetic particle simulations using the Geant4 Monte Carlo framework. Mono‐energy and mono‐pitch angle electron beams are simulated and combined using a Green's function approach to represent realistic electron spectra and pitch angle distributions. Results from this model include more accurate ionization profiles than previous analytical models, deeper photon penetration into the atmosphere than previous Monte Carlo model predictions, and predictions of backscatter fractions of loss cone electrons up to 40%. The model results are verified by comparison with previous precipitation modeling results, and validated using balloon X‐ray measurements from the Balloon Array for RBSP Relativistic Electron Losses mission and backscattered electron energy and pitch angle measurements from the Electron Loss and Fields Investigation with a Spatio‐Temporal Ambiguity‐Resolving CubeSat mission. The model results and solution techniques are developed into a Python package for public use.
Decadal Variability in Subsurface Nutrient Availability on the Scotian Shelf Reflects Changes in the Northwest Atlantic Ocean
Authors: Lehmann N. , Reed D. C. , Buchwald C. , Lavoie D. , Yeats P. A. , Mei Z.‐P. , Wang Z. , Johnson C. L. 
Published: October 2023

AbstractSubsurface nutrients on the Scotian Shelf, an ocean region at the convergence of the subpolar and subtropical western boundary currents (i.e., Labrador Current (LC) and Gulf Stream (GS)), are chiefly modulated by upstream shelf and slope waters. Yet little is known about long‐term fluctuations in the advective transport of nutrients to the shelf. Here, we synthesized nutrient and hydrographic data from 1975 to 2020 to characterize decadal changes in upper (60–150 m) and lower (150–200 m) subsurface nutrient availability across the shelf. Hydrographic and nutrient anomalies highlight a transition from a warm, saline, high‐nutrient GS‐dominated system in the 1980 to colder, fresher, lower‐nutrient LC‐dominated conditions in the late 1980 and early 1990. In the mid‐1990, an increase in excess silicate and phosphate (relative to nitrate) marks a shift in the LC contribution toward a strengthening of the inner shelf component relative to the outer shelf‐edge branch. Since 2010, rapid increases in subsurface temperature and salinity indicate the transition back to a GS‐dominated system, albeit with a distinct decline in dissolved nutrients relative to the previous warm period, which diverges from the nutrient increase generally associated with GS water. Declines in lower subsurface nutrient concentrations since 2010 are likely driven by a density‐related shift in the GS source water toward a less dense, lower‐nutrient GS contribution. This shift is evidenced by a decrease in excess phosphate amidst minor declines in excess silicate, reflecting the characteristic density‐related patterns of excess nutrients in GS waters.
Design and Assessment of a Novel Approach for Ecosystem Warming Experiments in High‐Energy Tidal Wetlands
Authors: Rich Roy L. , Mueller Peter , Fuß Miriam , Gonçalves Salomé , Ostertag Eva , Reents Svenja , Tang Hao , Tashjian Allegra , Thomsen Simon , Kutzbach Lars , Jensen Kai , Nolte Stefanie 
Published: October 2023

AbstractCoastal salt marshes have an important role in climate change adaptation and mitigation. Direct and indirect responses to warming are expected to vary along the marsh elevation gradient, making ecosystem responses to warming at this marine‐terrestrial ecotone uncertain. The Marsh Ecosystem Response to Increased Temperatures (MERIT) experiment was established in 2018 on the North Sea coast of Germany. Experimental plots are evenly distributed over three elevational marsh zones (pioneer, low marsh, and high marsh) and include three temperature treatments (ambient, +1.5°C, +3.0°C). MERIT's novel design combines active warming (horizontal surface warming cables and vertical soil warming pins) with passive, partially covered domes. For performance assessment, temperature deltas between ambient and warmed plots were calculated and evaluated at seasonal, daily, and diurnal timescales. We used Linear Mixed Models with Residual Maximum Likelihood for evaluating warming treatment effects and constraining environmental factors. MERIT was effective at ecosystem warming in this high‐energy environment both above‐ and belowground. Mixed models show that warming treatment dominates temperature differences belowground and at the soil surface, along with factors such as wind speed, flooding duration, and solar radiation. Aboveground warming was lower than belowground warming, but the dome design minimized issues seen in other open‐top chamber experiments. The combination of passive aboveground warming with feedback‐controlled active surface and belowground heating provides a setup for understanding warming effects on tidal ecosystems without altering the natural impacts of wind, radiation, and tidal inundations at high‐energy coastlines. Our design creates opportunities to expand future warming experiments to remote locations and technically challenging environments.
Small Reservoirs as Nitrogen Transformers: Accounting for Seasonal Variability in Inorganic and Organic Nitrogen Processing
Authors: Whitney Christopher T. , Wollheim Wilfred M. , Gold Arthur J. , Buonpane Joshua M. 
Published: October 2023

AbstractAnthropogenic nitrogen (N) inputs to the landscape have serious consequences for inland and coastal waters. Reservoirs are effective at mitigating downstream N fluxes but measurements have generally focused on large reservoirs and have not considered seasonal variability or all N forms. In this study, we conducted an N mass balance in eight small reservoirs (surface area <0.55 km2) in coastal New England over annual time periods, including both inorganic and organic forms of N. We found that small reservoirs have high capacity for dissolved inorganic N (DIN) retention during low and moderate discharge, but are roughly in balance for DIN at higher discharge. Because proportional DIN retention occurred when N inputs were at their lowest, their effect on downstream N fluxes is small over annual time frames. Further, dissolved organic N (DON) was also evident during low flow late in the warm season. Accounting for DON production, the net effect of reservoirs on total dissolved N (TDN) fluxes was limited. These transformations between inorganic and organic N should be considered when evaluating the effect of small reservoirs on TDN fluxes over seasonal and annual timescales. With dam removal becoming a common solution to aging, unsafe dams, their ability to retain or produce N must be scrutinized at longer time scales while accounting for the complete N pool to better comprehend the effect their reservoirs have on downstream waters.
Diachronous Quaternary Development of the Jiayuguan Fault and Implications for Strain Compartmentalization and Modern Earthquake Hazards in the NW Hexi Corridor, China
Authors: Yang Haibo , Li An , Cunningham Dickson , Zhan Yan , Luo Jiahong , Yang Xiaoping , Chen Zhidan , Zuo Yuqi , Hu Zongkai , Tang Ruoni 
Published: October 2023

AbstractThe NNW‐trending Jiayuguan Fault (JYGF) is an actively developing thrust fault that delimits the SW margin of Jiayuguan, a major industrial city in the northwestern Hexi Corridor, China. In this study, we document the geometry, kinematics, and slip rates of the JYGF based on analysis of satellite imagery, low‐altitude photogrammetry, field observations, paleo‐seismic trenching, and Quaternary dating. The JYGF hanging‐wall contains a NE‐vergent asymmetric anticline of Cretaceous redbeds unconformably overlain by faulted, tilted and folded alluvial fan and fluvial terrace surfaces. Subsidiary fault scarps are associated with anticlinal flexure and contractional strain. The vertical uplift and crustal shortening rates are both ∼0.1 mm/a since ∼420 ka and geomorphic markers and dated landforms indicate southeastward fault propagation and hanging‐wall uplift from the Heishan toward the modern Beida River channel. The NW end of the fault appears to connect with the Altyn‐Tagh‐Heishan‐Jinta'Nanshan sinistral strike‐slip fault array suggesting that the JYGF is one of several parallel, splay faults that transfer strike‐slip motion to active folding and thrusting in the region. We relocate the 1992 Ms 5.4 earthquake epicenter using the NonLinLoc method and suggest that the JYGF may link southeastward with Quaternary‐active faults and folds in the Wenshushan. A seismic rupture along the total fault length of 25–40 km for the JYGF‐Wenshushan deforming belt corresponds to a potential earthquake magnitude in the 6.6–7.0 range. Compartmentalized faulting and folding in the NW–most Hexi Corridor defines a triangular block of active deformation where NE‐directed contractional deformation of the Qilian Shan foreland interacts with E‐W left‐lateral displacement along the Altyn‐Tagh‐Heishan‐Jinta'Nanshan sinistral strike‐slip system.
Concentrations and Yields of Mercury, Methylmercury, and Dissolved Organic Carbon From Contrasting Catchments in the Discontinuous Permafrost Region, Western Canada
Authors: Thompson L. M. , Low M. , Shewan R. , Schulze C. , Simba M. , Sonnentag O. , Tank S. E. , Olefeldt D. 
Published: October 2023

AbstractClimate change and permafrost thaw may impact the mobilization of terrestrial dissolved organic carbon (DOC), mercury (Hg), and neurotoxic methylmercury (MeHg) into aquatic ecosystems; thus, understanding processes that control analyte export in northern catchments is needed. We monitored water chemistry for 3 years (2019–2021) at a peatland catchment (Scotty Creek) and a mixed catchment (Smith Creek) in the Dehcho (Northwest Territories), within the discontinuous permafrost zone of boreal western Canada. The peatland catchment had higher DOC and dissolved MeHg, but lower total Hg concentrations (mean ± standard deviation; 19 ± 2.6 mg DOC L−1; 0.08 ± 0.04 ng DMeHg L−1; 1.1 ± 0.3 ng THg L−1) than the mixed catchment (12 ± 4.4 mg DOC L−1; 0.05 ± 0.01 ng DMeHg L−1; 3.1 ± 2.2 ng THg L−1). Analyte concentrations increased with discharge at the mixed catchment, suggesting transport limitation and the flushing of near‐surface, organic‐rich flow paths during wet periods. In contrast, analyte concentrations in the peatland catchment were not primarily associated with discharge. MeHg concentrations, MeHg:THg, and MeHg:DOC increased with water temperature, suggesting enhanced Hg methylation during warmer periods. Mean open water season DOC and total MeHg yields were greater and more variable from the peatland than the mixed catchment (1.1–6.6 vs. 1.4–2.4 g DOC m−2; 5.2–36 vs. 6.1–10 ng MeHg m−2). Crucial storage thresholds controlling runoff generation likely drove greater inter‐annual variability in analyte yields from the peatland catchment. Our results suggest climate change may influence the production and transport of MeHg from boreal‐Arctic catchments as temperatures increase, peatlands thaw, and runoff generation is altered.
Automatic Time Step Control to Resolve Hydromechanically Driven Fault Reactivation, Spontaneous Nucleation, and Seismic Arrest
Authors: Han Zheng , Ren Guotong , Younis Rami M. 
Published: October 2023

AbstractA physical understanding of the progression from flow‐driven (quasi‐static) poromechanical deformation to dynamic fault rupture is critical to the resilient operations of several engineering systems. These processes are bridged by a progression from fault reactivation to the spontaneous nucleation of unstable sliding. Toward addressing this challenge, novel automatic time step size control methods are developed to enable accurate and efficient simulation of these dynamics and transitions from the first principles. The controllers combine local models for discretization error and Coulomb failure conditions to automatically adjust the time step size across several orders of magnitude. The methods do not require additional empirical or theoretical input and can resolve the pre‐rupture, interseismic, and seismic periods to the allowed accuracy. The computational results reveal that the proposed methods automatically capture the onset of reactivation and nucleation for homogeneous and heterogeneous fields. Hydrodynamic and structural heterogeneity lead to disparate critical nucleation sizes compared to those predicted by theory. The results highlight its potential in predicting induced seismicity in realistic subsurface engineering systems and at practical scales.
Dimensionless Thermal Efficiency Analysis for Aquifer Thermal Energy Storage
Authors: Tang Darrell W. S. , Rijnaarts Huub H. M. 
Published: October 2023

AbstractSeasonal warm and cold water storage in groundwater aquifers is a cost‐effective renewable energy technology for indoor heating and cooling. Simple dimensionless analytical solutions for the thermal recovery efficiency of Aquifer Thermal Energy Storage (ATES) systems are derived, subject to heat losses caused by thermal diffusion and mechanical dispersion. The analytical solutions pertain to transient pumping rates and storage durations, and multiple cycles of operation, and are applicable to various well configurations and thermal plume geometries. Heat losses to confining layers, its implications for optimizing plume geometries and aspect ratios, and heat spreading due to free convection are also discussed. This provides a general tool for broad and rapid assessment of aquifers and ATES systems. We show that if heat exchange with the confining layers is negligible, the thermal recovery efficiency of thermal plumes with cylindrical geometry is independent of the aquifer porosity and heat capacity C0. Therefore, if mechanical dispersion is negligible as is often the case, the only aquifer property that affects the recovery efficiency is the aquifer thermal conductivity. The field‐scale aquifer thermal conductivity λ can therefore be inferred from the recovery efficiency of a push‐pull heat recovery test. Remarkably, an increase in C0 could either increase, decrease, or not affect the recovery efficiency, depending on the thermal plume geometry. Hence, the analytical solutions reveal that the recovery efficiency is affected by complex interactions between the thermal plume geometry and aquifer properties. Approximate analytical solutions for subsurface temperature profiles over an entire ATES cycle are also derived.