bluuebunny/crossref_metadata_2025_split huggingface dataset:
Harmony in flux: Unraveling the green innovation with organizational forgetting, absorptive capacity, and the jazz of organizational improvisation
Authors: Shahzad Mohsin , Zafar Abaid Ullah , Ye Maoran , Ding Xiangan 
Published: January 2024

AbstractOrganizations are advised to consistently seek and assimilate novel information from external sources to enhance their adsorptive capacity and better understand and address environmental challenges. Despite the evident influence of external knowledge on absorptive capacity and green innovation performance (GIP), there is a notable dearth of discussion on the internal mechanisms facilitating this transformation, potentially leading to adverse consequences for GIP. In response to this gap, our research intends to explore the direct impact of organizational forgetting (OF) on GIP, both independently and through potential absorptive capacity (PAC) and realized absorptive capacity (RAC). Further, this investigation incorporates the moderating role of organizational improvisation (OI) to provide a comprehensive understanding of an encompassing model. Utilizing structural equation modeling (SEM) on data from 321 respondents from Chinese manufacturing firms, our findings reveal that OF significantly contributes to GIP, PAC, and RAC. Moreover, this association is partially mediated by both PAC and RAC. Further, OI expressively moderated the targeted relationships in confounding ways. Importance–performance map analysis also highlights the pivotal role of PAC with a notable performance value (68.812), while OF takes precedence in importance with a substantial value (0.572) compared to all exogenous variables. These insights contribute to an enriched understanding of the vital role OF plays in enhancing PAC, RAC, OI, and GIP—an aspect that has yielded inconsistent results in prior studies. Consequently, our findings advocate for increased investment by managers and policymakers in cultivating the capacity to absorb new knowledge as a strategic imperative for fostering innovation and GIP within industries.
A multifamily group for adolescents with emotion regulation difficulties: Adolescent, parent and clinician experiences
Authors: Cleary Ruth , Houghton Sharon , O’Driscoll Lawrie Claire , Dowling Clodagh , O'Hanrahan Kevin , Devoy Susan 
Published: January 2024

AbstractBackgroundDialectical behaviour therapy (DBT) has been successfully adapted for use with adolescents experiencing difficulties associated with the maladaptive undercontrol of emotion. However, clinical observation and research findings suggest that adolescents may exhibit traits of both undercontrol and overcontrol—where over‐regulation of emotion predominates. In the adult population, distinct groups of individuals with under‐ and overcontrolled regulation styles can be identified, and treatments such as Group Radical Openness (GRO) have shown promise in treating difficulties associated with the latter. However, there are difficulties identifying distinct groups of under‐ and overcontrolled adolescents.AimsThe present study therefore sought to qualitatively explore the experiences of participants (adolescents and parents) and facilitators of an intervention integrating DBT for adolescents’ skills training with GRO.MethodSix adolescents, seven parents and six clinicians completed semi‐structured interviews. Data were analysed using thematic analysis. Nine themes and six subthemes were generated.FindingsFindings suggested that an intervention of this type may have particular utility for adolescents with emotion regulation difficulties in the context of both overcontrol and undercontrol. Participants described improvements in symptoms and relational functioning, which they attributed to the development of a shared language for communicating about emotion and the multifamily group context within which the intervention was delivered. Findings also emphasised the utility of rolling groups.DiscussionFurther research investigating the efficacy of this intervention is warranted. Strengths, limitations, future directions and implications for practice are discussed.
miR‐142‐3p/5p role in cancer: From epigenetic regulation to immunomodulation
Authors: Zareifar Parisa , Ahmed Hani Moslem , Ghaderi Pouya , Farahmand Yalda , Rahnama Negin , Esbati Romina , Moradi Ali , Yazdani Omid , Sadeghipour Yasin 
Published: January 2024

AbstractMicroRNAs (miRNAs) play critical roles in cancer pathobiology, acting as regulators of gene expression and pivotal drivers of tumorigenesis. It is believed that miRNAs act through canonical mechanisms, involving the binding of mature miRNAs to target messenger RNAs (mRNAs) and subsequent repression of protein translation or degradation of target mRNAs. miR‐142‐3p/5p has been extensively studied and established as a key regulator in various malignancies. Recent discoveries have revealed miR‐142‐3p/5p serve as either oncogene or tumor suppressor in cancer. By targeting epigenetic factor and cancer‐related signaling pathway, miR‐142‐3p/5p can regulate wide range of downstream genes. The immune modulatory role of miR‐142‐3p/5p has been shown in various cancers, which provides significant insight into immunosuppression and tumor escape from the immune response. Exosomes with miR‐142‐3p/5p facilitate cell communication and can affect cancer cell behavior, offering potential therapeutic, and diagnosis applications in cancer therapy. In this review, for the first time, we comprehensively summarize the current knowledge regarding mentioned functions of miR‐142‐3p/5p in cancer pathobiology.
The connection between epigenetics and gut microbiota‐current perspective
Authors: Yuan Xingxing , Tan Yurong , Bajinka Ousman , Jammeh Modou L. , Dukureh Abubakarr , Obiegbusi Chidera N. , Abdelhalim Khalid A. , Mohanad Mahmoud 
Published: January 2024

AbstractBoth the epigenetic changes and gut microbiota (GM) have attracted a growing interest in establishing effective diagnostics and potential therapeutic strategies for a number of diseases. These disorders include metabolic, central nervous system‐related diseases, autoimmune, and gastrointestinal infections (GI). Despite the number of studies, there is no extensive review that connects the epigenetics modifications and GM as biomarkers that could confer effective diagnostics and confer treatment options. To this end, this review hopes to give detailed information on connecting the modifications in epigenetic and GM. An updated and detailed information on the connection between the epigenetics factors and GM that influence diseases are given. In addition, the review showed some associations between the epigenetics to the maternal GM and offspring health. Finally, the limitations of the concept and prospects into this new emerging discipline were also looked into. Although this review elucidated on the maternal diet and response to offspring health with respect to GM and epigenetic modifications, there still exist various limitations to this newly emerging discipline. In addition to integrating complementary multi‐omics data, longitudinal sampling will aid with the identification of functional mechanisms that may serve as therapeutic targets. To this end, this review gave a detailed perspective into harnessing disease diagnostics, prevention and treatment options through epigenetics and GM.
Aminic Organoselenium Compounds as Glutathione Peroxidase Mimics and Inhibitors of Ferroptosis
Authors: Chhillar Babli , Kadian Rajni , Kumar Manish , Yadav Manisha , Sodhi Nikhil , Xavier da Silva Thamara Nishida , Friedmann Angeli Jose Pedro , Singh Vijay P. 
Published: January 2024

AbstractThe synthesis of diarylamine‐based organoselenium compounds via the nucleophilic substitution reactions has been described. Symmetrical monoselenides and diselenides were conveniently synthesized by the reduction of their corresponding selenocyanates using sodium borohydride. Selenocyanates were obtained from 2‐chloro acetamides by the nucleophilic displacement with potassium selenocyanate. Selenides were synthesized by treating the 2‐chloro acetamides with in situ generated sodium butyl selenolate as nucleophile. Further, the newly synthesized organoselenium compounds were evaluated for their glutathione peroxidase (GPx)‐like activity in thiophenol assay. This study revealed that the methoxy‐substituted organoselenium compounds showed significant effect on the GPx‐like activity. The catalytic parameters for the most efficient catalysts were also determined. The anti‐ferroptotic activity for all GPx‐mimics evaluated in a 4−OH‐tamoxifen (TAM) inducible GPx4 knockout cell line using liproxstatin as standard.
Numerical Performance Investigation of a Side‐outlet Cyclone for Particulate Matter and Polymer Powder Separation
Authors: Duran Jeffrey Z. , Gabon Rommel Thompson G. , Licdan Maurice O. , Caldona Eugene B. 
Published: January 2024

AbstractThe side‐outlet cyclone, featuring a novel geometric design with a lateral gas outlet, proves advantageous in space‐constrained environments compared to traditional cyclones with top gas outlets. Herein, a cyclone separator with a side‐outlet configuration was numerically investigated using the renormalization group k‐ε model and pressure drop and separation efficiency as the performance parameters. Simulation results revealed that the side‐outlet cyclone operates at a low to moderate pressure drop of 80.8412 Pa, with a removal efficiency of 45.48 %. The operating pressure drop was found to be only one‐third of the computed pressure drop from mathematical modeling, with a removal efficiency 15 % lower than the experimental value. With varying cyclone design modifications, suitable experimental procedures and measuring approaches are desirable to further accurately corroborate these results.
Regulating solid electrolyte interphase film on fluorine‐doped hard carbon anode for sodium‐ion battery
Authors: Yang Cuiyun , Zhong Wentao , Liu Yuqiao , Deng Qiang , Cheng Qian , Liu Xiaozhao , Yang Chenghao 
Published: January 2024

AbstractFor the performance optimization strategies of hard carbon, heteroatom doping is an effective way to enhance the intrinsic transfer properties of sodium ions and electrons for accelerating the reaction kinetics. However, the previous work focuses mainly on the intrinsic physicochemical property changes of the material, but little attention has been paid to the resulting interfacial regulation of the electrode surface, namely the formation of solid electrolyte interphase (SEI) film. In this work, element F, which has the highest electronegativity, was chosen as the doping source to, more effectively, tune the electronic structure of the hard carbon. The effect of F‐doping on the physicochemical properties of hard carbon was not only systematically analyzed but also investigated with spectroscopy, optics, and in situ characterization techniques to further verify that appropriate F‐doping plays a positive role in constructing a homogenous and inorganic‐rich SEI film. The experimentally demonstrated link between the electronic structure of the electrode and the SEI film properties can reframe the doping optimization strategy as well as provide a new idea for the design of electrode materials with low reduction kinetics to the electrolyte. As a result, the optimized sample with the appropriate F‐doping content exhibits the best electrochemical performance with high capacity (434.53 mA h g−1 at 20 mA g−1) and excellent rate capability (141 mA h g−1 at 400 mA g−1).
Light Triggered Reversible Aggregation/Dispersion of Hydroxy Azo‐benzenes During Photo Switching: Solvent, Ions Assisted Dispersion, and Induced Quenching Emission
Authors: Patel Samridhi , Das Binayak , Mishra Puneet , Chandra Girish 
Published: January 2024

AbstractHydroxy azo‐benzenes are very well known for their rapid trans⇆cis photoisomerization under polar solvents. In contrast, we synthesized two hydroxymethylated‐ hydroxyazobenzene derivatives and investigated their light‐triggered photoisomerization and stability under polar solvents. The result showed just opposite behavior and very slow trans⇆cis isomerization was observed (minutes‐days). Thus, the UV‐vis spectrum revealed a very low decrease in the absorbance of π–π* transition. Surprisingly, the isomerization process became faster with the addition of ionic species. Here, we attempted to understand the underlying cause of the unusual photo‐switching behavior. The presence of hydroxymethyl and fluorine substituents was found to have a significant effect on the stability of the trans and photo‐isomerized cis products. Here, it was confirmed with NMR and DLS studies that the unusual photostability of trans compounds was caused by polar solvent‐assisted aggregation (hydrodynamic radius, RH 5660–1720 nm) which underwent dispersion (RH, 220–68 nm) and formed a significant stable solvated photoproduct under photoirradiation. Furthermore, this aggregation‐dispersion was found to be very slowly reversible. Further, the fluorescence emission demonstrated a characteristic dispersion‐induced quenching. Regular photoswitching was observed under non‐polar conditions in benzene where an expected blue shift of π–π* transition and an increase in the intensity of n–π* transitions.
Comparative study on the effects of different polishing methods on tooth surface microstructure and roughness following initial periodontal treatment
Authors: Gong Jingjue , Huang Xin , Yuan Shuang 
Published: January 2024

AbstractObjectiveTo investigate the effects of different polishing methods on the surface microstructure and roughness of teeth following initial periodontal treatment.MethodsTeeth were divided into three groups (silica onegloss, polishing disc, and polishing strip) in vitro. Tooth surface microstructure was characterized via scanning electron microscopy. Roughness was measured by profilometry and laser scanning confocal microscopy (LSCM). According to the in vitro results, one group was chosen for further clinical trials. Effects of the chosen polishing method on patient plaque control and satisfaction were assessed via plaque staining and visual analog scale (VAS).ResultsElectron microscopy results revealed that the polishing disc group had smoother roots and crowns than did the other two groups. Roughness analysis revealed that the crown roughness with the polishing disc and silica onegloss was lower, and the root roughness with the polishing disc was the lowest (p < .05) The LSCM results showed that the pigment deposition depth with the polishing disc and silicon onegloss in the crowns and roots were significantly lower than those with the other two methods (p = .000). The polishing effect of the polishing disc was best among the three groups. Clinical trials were performed to verify the polishing disc effects. Plaque staining results showed that the decrease in plaque in the polishing disc group was greater than that of the rubber cup group (p = .020), which was similar to the results of LSCM. The VAS results showed that the polishing disc made teeth feel smoother, similar to the results of the roughness detection, and the procedure was more comfortable (p < .05). However, there was no significant difference between the two groups regarding foreign body sensation during pronunciation (p = .178).ConclusionCombining in vitro and in vivo evaluations, the use of a polishing disc following periodontal treatment yielded superior polishing effects on teeth and was better accepted by patients.
An improved resource scheduling strategy through concatenated deep learning model for edge computing IoT networks
Authors: Vijayasekaran Gunasekaran , Duraipandian Mariappan 
Published: January 2024

SummaryWith increasing challenges and research in edge‐assisted IoT models, an improved resource scheduling approach exploiting deep learning concepts is proposed in this research work. Improvement in performance in the proposed work is achieved primarily by addressing the response time and waiting time. This could be achieved if the optimal resources are scheduled without any delay. The presented concatenated deep learning technique considers the time series IoT network source requirements and allocates optimal resources from the resource pool, considering resource availability, workload, and computation time. Two deep learning techniques, namely, CNN and GRU, are utilized for the concatenation process, while resource characteristics are considered as features that are extracted and classified to schedule optimal resources. Novelty in the proposed work is exhibited in the form of the concatenation process proposed. The proposed resource scheduling performance metrics are compared with the performance of the existing scheduling model through simulation analysis for better validation. The proposed model selects the optimal resources from the resource pool using concatenated features and schedules for respective requests with minimum delay and waiting time, which increases the overall efficiency of the edge computing IoT networks.
Does restoring apex predators to food webs restore ecosystems? Large carnivores in Yellowstone as a model system
Authors: Hobbs N. Thompson , Johnston Danielle B. , Marshall Kristin N. , Wolf Evan C. , Cooper David J. 
Published: January 2024

AbstractModification of food webs is a frequent cause of shifts in ecosystem states that resist reversal when the food web is restored to its original condition. We used the restoration of the large carnivore guild including gray wolves (Canis lupis), cougars (Felis concolor), and grizzly bears (Ursus arctos horribilis) to the northern range of Yellowstone National Park as a model system to understand how ecosystems might resist reconfiguration after the restoration of apex predators to the food web. The absence of wolves, cougars, and grizzly bears for nearly a century from the northern range was the primary cause of dramatic changes in riparian plant communities. Willows (Salix spp.) were suppressed in height by intense browsing by the dominant herbivore, elk (Cervus canadensis). The loss of activity by beavers (Castor canadensis) coincided with the loss of tall willows. We hypothesized that intense elk browsing interrupted the mutualism between willow and beavers: ecosystem engineering by beavers was a critical component of willow habitat and tall willows were a critical component of habitat for beavers. This interruption made riparian communities resilient to the disturbance caused by the restoration of apex predators. We hypothesized further that reductions in elk browsing attributable to reductions in elk population size were not sufficient to prevent the suppression of willow growth. To test these hypotheses, we conducted a 20‐year, factorial experiment that crossed simulated beaver dams with the exclusion of browsing. We found that willows grew to heights expected for restored communities only in the presence of dams and reduced browsing. Willows experiencing ambient conditions remained well below this expectation. We found no difference in heights or growth rates of willows in experimental controls and willows in 21 randomly chosen sites, confirming that the results of the experiment were representative of range‐wide conditions. A reorganized community of large herbivores was implicated in the suppression of willow growth. We conclude that the restoration of large carnivores to the food web failed to restore riparian plant communities on Yellowstone's northern range, supporting the hypothesis that this ecosystem is in an alternative stable state caused primarily by the extirpation of apex predators during the early 20th century.
Mo Doping and Electrochemical Activation Co‐Induced Vanadium Composite as High‐Rate and Long‐Life Anode for Ca‐Ion Batteries
Authors: Pan Hongchen , Wang Chunfang , Qiu Minling , Wang Yaxin , Han Cuiping , Nan Ding 
Published: January 2024

Calcium‐ion batteries have been considered attractive candidates for large‐scale energy storage applications due to their natural abundance and low redox potential of Ca2+/Ca. However, current calcium ion technology is still hampered by the lack of high‐capacity and long‐life electrode materials to accommodate the large Ca2+ (1.00 Å). Herein, an amorphous vanadium structure induced by Mo doping and in‐situ electrochemical activation is reported as a high‐rate anode material for calcium ion batteries. The doping of Mo could destroy the lattice stability of VS4 material, enhancing the flexibility of the structure. The following electrochemical activation further converted the material into sulfide and oxides co‐dominated composite (defined as MoVSO), which serves as an active material for the storage of Ca2+ during cycling. Consequently, this amorphous vanadium structure exhibits excellent rate capability, achieving discharge capacities of 306.7 and 149.2 mAh g−1 at 5 and 50 A g−1 and an ultra‐long cycle life of 2000 cycles with 91.2% capacity retention. These values represent the highest level to date reported for calcium ion batteries. The mechanism studies show that the material undergoes a partial phase transition process to derive MoVSO. This work unveiled the calcium storage mechanism of vanadium sulfide in aqueous electrolytes and accelerated the development of high‐performance aqueous calcium ion batteries.
Progress in the Synthesis of Cyclobutenones
Authors: Qian Yi‐Sen , Xu Yun‐He 
Published: January 2024

AbstractIn recent years, significant progress has been made in the synthesis of cyclobutenones. The unique structural features and reactivity of cyclobutenones, making them of great values in organic synthesis. Therefore, the development of new strategies for synthesizing the cyclobutenones has been a major focus of organic chemists. This review summarizes the synthetic methods for the cyclobutenones in the past several decades and provides an overview of the characteristics and advantages of these strategies. The aim of this review is to provide valuable insights for the synthesis of cyclobutenones.