bluuebunny/crossref_metadata_2025_split huggingface dataset:
Q‐switched mode‐locked Nd:GGG laser with MoS2–SnSe2 heterojunction nanosheets
Authors: Li Mingxin , Zhou Yu , Li Shuai , Tang Shuo , Yu Shuangyuan , Zhang Wei , Yang Hang , Zhao Ling 
Published: December 2023

AbstractIn this paper, we used the liquid phase stripping method to manufacture MoS2–SnSe2 heterojunction saturable absorber (SA). The scanning electron microscope, the atomic force microscope, and the Raman spectrometer were used to characterize the MoS2–SnSe2 heterojunction SA. The Q‐switched mode‐locked (QSML) Nd:GGG laser with MoS2–SnSe2 heterojunction SA was presented. The maximum output power of the QSML Nd:GGG laser was 236.4 mW with a repetition rate of 83.3 MHz and pulse width of 447 ps. In short, the MoS2–SnSe2 heterojunction nanosheets present excellent saturable absorption characteristics.
Conservation and contrast in cell states of echinoderm ovaries
Authors: Oulhen Nathalie , Morita Shumpei , Pieplow Cosmo , Onorato Thomas M. , Foster Stephany , Wessel Gary 
Published: December 2023

AbstractEchinoderms produce functional gametes throughout their lifespan, in some cases exceeding 200 years. The histology and ultrastructure of echinoderm ovaries has been described but how these ovaries function and maintain the production of high‐quality gametes remains a mystery. Here, we present the first single cell RNA sequencing data sets of mature ovaries from two sea urchin species (Strongylocentrotus purpuratus [Sp] and Lytechinus variegatus [Lv]), and one sea star species (Patiria miniata [Pm]). We find 14 cell states in the Sp ovary, 16 cell states in the Lv ovary and 13 cell states in the ovary of the sea star. This resource is essential to understand the structure and functional biology of the ovary in echinoderms, and better informs decisions in the utilization of in situ RNA hybridization probes selective for various cell types. We link key genes with cell clusters in validation of this approach. This resource also aids in the identification of the stem cells for prolonged and continuous gamete production, is a foundation for testing changes in the annual reproductive cycle, and is essential for understanding the evolution of reproduction of this important phylum.
How young adults with sickle cell disease define “being a good patient” in the adult healthcare system
Authors: Nwora Christle , Prince Elizabeth J. , Pugh Laura , Weaver Meaghann S. , Pecker Lydia H. 
Published: December 2023

AbstractBackgroundYoung adulthood brings new challenges for managing sickle cell disease. There are fewer adult specialists, sickle cell disease morbidities accumulate, and mortality increases. Developmental changes in roles and responsibilities also affect management. This study explores how young adults with sickle cell disease experience their role as a patient.MethodsIn this mixed‐methods study at a sickle cell center, young adult participants completed the Sickle Cell Self Efficacy Survey, the Measures of Sickle Cell Stigma, and the Adult Sickle Cell Quality of Life Measurement Short‐Forms. Semi‐structured interviews on the patient role were conducted, transcribed, and then analyzed using thematic analysis.ResultsTwenty‐four participants aged 19–25 years defined expectations of being a “good patient.” Five definitional themes emerged: health maintenance, emotion regulation, self‐advocacy, honest communication, and empathy for clinicians. Participants identified support from families and clinicians are important facilitators of role fulfillment.DiscussionHow young adult patients with sickle cell disease define being a “good patient” has implications for the transition of care for both pediatric and adult medicine practices. This understanding can inform healthcare system designs and programs aimed at supporting patients and families.
Implications of a local flora survey for pre‐human grass flora in north‐western Madagascar
Authors: Ramiandrisoa Botovao Auguste , Lucien Jean Jaossin , Razafitsara Rosinètte Luchat , Maharombaka Cyrille , Ranarijaona Hery Lisy Tiana , Vorontsova Maria S. 
Published: December 2023

Societal Impact StatementMadagascar's children are taught that their ancestors destroyed the vast ancient forest, giving rise to modern grasslands, a misleading myth that continues to undermine people's relationship with nature. Replacing this myth with a more nuanced and accurate narrative around grassy ecosystems is fundamental to building a more positive relationship between Madagascar's people and ecosystems, a process that is necessary to build modern conservation practice and environmental governance. The data we present are consistent with a pre‐human grass flora in the region, suggesting the local grassy ecosystems should not be written off as fully anthropogenic and undesirable but are instead in need of recognition and further research attention.Summary

Grassy ecosystems cover over a quarter of dry land, with mosaics of old‐growth and recently formed anthropogenic systems appearing superficially similar to an uninformed observer. Grasses are part of a deep web of historic relationships between grassy ecosystems and local people.
We collect and compile the first list of grass species (Poaceae) in north‐west Madagascar in order to make an initial evidence assessment for a pre‐human grass flora. Field surveys and voucher specimen collections were carried out. Specimen identification was performed using morphological character comparison with reference specimens, literature and personal knowledge of grasses from other parts of Madagascar.
Seventy species are recorded and assigned to 44 genera. The species list is compared with regional grass checklists from central and south‐central Madagascar. Thirty‐five grasses are unique to Mahajanga, comprising 19% of the multi‐region species pool analysed; the regional species richness is comparable to that of the highlands.
The main subfamilies represented are the Panicoideae (64%) and Chloridoideae (29%). Seven species are endemic to Madagascar, reflecting their evolutionary origins on the island. Many of the species are found in multiple types of habitat and substrate, while others are restricted to limited areas and habitats, and local species richness varies significantly with habitat and soil. The main disturbance regimes driving species occurrence include fire and grazing, possibly partly reflecting similar disturbances prior to human arrival. The patterns observed in the grass flora of north‐western Madagascar are overall congruent with a pre‐human grass flora.
Decision authority and the returns to algorithms
Authors: Kim Hyunjin , Glaeser Edward L. , Hillis Andrew , Kominers Scott Duke , Luca Michael 
Published: December 2023

AbstractResearch SummaryWe evaluate a pilot in an Inspections Department to explore the returns to a pair of algorithms that varied in their sophistication. We find that both algorithms provided substantial prediction gains, suggesting that even simple data may be helpful. However, these gains did not result in improved decisions. Inspectors often used their decision authority to override algorithmic recommendations, partly to consider other organizational objectives without improving outcomes. Interviews with 55 departments find that while some ran pilots seeking to prioritize inspections using data, all provided considerable decision authority to inspectors. These findings suggest that for algorithms to improve managerial decisions, organizations must consider both the returns to algorithms in the context and how decision authority is managed.Managerial SummaryWe evaluate a pilot in an Inspections Department to explore the returns to algorithms on decisions. We find that the greatest gains in this context come from integrating data into the decision process in the form of simple heuristics, rather than from increasing algorithmic sophistication or additional data. We also find that these improvements in prediction do not fully translate into improved decisions. Decision‐makers were less likely to follow data‐driven recommendations, partly in consideration of other organizational objectives, but without substantially improving on them overall. These findings suggest that organizations should consider the returns to technical sophistication in each context, and that the design and management of decision authority can be a key choice that impacts the value organizations can capture from using predictive analytics.
Tailoring Ionic Liquid Chemical Structure for Enhanced Interfacial Engineering in Two‐Step Perovskite Photovoltaics
Authors: Wang Fei , Ma Jing , Duan Dawei , Liang Xiao , Zhou Kang , Sun Yonggui , Wang Taomiao , Yang Guo , Pei Guoxian , Lin Haoran , Shi Yumeng , Zhu Quanyao , Li Gang , Hu Hanlin 
Published: December 2023

AbstractIonic liquids (ILs) have emerged as versatile tools for interfacial engineering in perovskite photovoltaics. Their multifaceted application targets defect mitigation at SnO2‐perovskite interfaces, finely tuning energy level alignment, and enhancing charge transport, meanwhile suppressing non‐radiative recombination. However, the diverse chemical structures of ILs present challenges in selecting suitable candidates for effective interfacial modification. This study adopted a systematic approach, manipulating IL chemical structures. Three ILs with distinct anions are introduced to modify perovskite/SnO2 interfaces to elevate the photovoltaic capabilities of perovskite devices. Specifically, ILs with different anions exhibited varied chemical interactions, leading to notable passivation effects, as confirmed by Density Functional Theory (DFT) calculation. A detailed analysis is also conducted on the relationship between the ILs' structure and regulation of energy level arrangement, work function, perovskite crystallization, interface stress, charge transfer, and device performance. By optimizing IL chemical structures and exploiting their multifunctional interface modification properties, the champion device achieved a PCE of 24.52% with attentional long‐term stability. The study establishes a holistic link between IL structures and device performance, thereby promoting wider application of ILs in perovskite‐based technologies.
Mo2C‐Based Ceramic Electrode with High Stability and Catalytic Activity for Hydrogen Evolution Reaction at High Current Density
Authors: Huang Anding , Huang Haisen , Wang Feihong , Ke Nianwang , Tan Chuntian , Hao Luyuan , Xu Xin , Xian Yuxi , Agathopoulos Simeon 
Published: December 2023

AbstractDeveloping robust electrodes with high catalytic performance is a key step for expanding practical HER (hydrogen evolution reaction) applications. This paper reports on novel porous Mo2C‐based ceramics with oriented finger‐like holes directly used as self‐supported HER electrodes. Due to the suitable MoO3 sintering additive, high‐strength (55 ± 6 MPa) ceramic substrates and a highly active catalytic layer are produced in one step. The in situ reaction between MoO3 and Mo2C enabled the introduction of O in the Mo2C crystal lattice and the formation of Mo2C(O)/MoO2 heterostructures. The optimal Mo2C‐based electrode displayed an overpotential of 333 and 212 mV at 70 °C under a high current intensity of 1500 mA cm−2 in 0.5 m H2SO4 and 1.0 m KOH, respectively, which are markedly better than the performance of Pt wire electrode; furthermore, its price is three orders of magnitude lower than Pt. The chronopotentiometric curves recorded in the 50 – 1500 mA cm−2 range, confirmed its excellent long‐term stability in acidic and alkaline media for more than 260 h. Density functional theory (DFT) calculations showed that the Mo2C(O)/MoO2 heterostructures has an optimum electronic structure with appropriate *H adsorption‐free energy in an acidic medium and minimum water dissociation energy barrier in an alkaline medium.
Polymerization Based on Modified β‐Cyclodextrin Achieves Efficient Phosphorescence Energy Transfer for Anti‐Counterfeiting
Authors: Cheng Qingwen , Ma Xin‐Kun , Zhou Xiaolu , Zhang Ying‐Ming , Liu Yu 
Published: December 2023

AbstractSupramolecular polymerization can not only activate guest phosphorescence, but also promote phosphorescence Förster resonance energy transfer and induce effective delayed fluorescence. Herein, the solid supramolecular assemblies of ternary copolymers based on acrylamide, modified β‐cyclodextrin (CD), and carbazole (CZ) are reported. After doping with polyvinyl alcohol (PVA) and dyes, a NIR luminescence supramolecular composite with a lifetime of 1.07 s, an energy transfer efficiency of up to 97.4% is achieved through tandem phosphorescence energy transfer. The ternary copolymers can realize macrocyclic enrichment of dyes in comparison to CZ and acrylamide copolymers without CD, which can facilitate energy transfer between triplet and singlet with a high donor–acceptor ratio. Additionally, the flexible polymeric films exhibit regulable lifetime, tunable luminescence color, and repeatable switchable afterglow by adjusting the excitation wavelength, donor–acceptor ratio, and wet/dry stimuli. The luminescence materials are successfully applied to information encryption and anti‐counterfeiting.
An Overview of Metal‐Organic Framework Based Electrocatalysts: Design and Synthesis for Electrochemical Hydrogen Evolution, Oxygen Evolution, and Carbon Dioxide Reduction Reactions
Authors: Iniyan S. , Ren Juanna , Deshmukh Swapnil , Rajeswaran K. , Jegan G. , Hou Hua , Suryanarayanan Vembu , Murugadoss Vignesh , Kathiresan Murugavel , Xu Ben Bin , Guo Zhanhu 
Published: December 2023

AbstractDue to the increasing global energy demands, scarce fossil fuel supplies, and environmental issues, the pursued goals of energy technologies are being sustainable, more efficient, accessible, and produce near zero greenhouse gas emissions. Electrochemical water splitting is considered as a highly viable and eco‐friendly energy technology. Further, electrochemical carbon dioxide (CO2) reduction reaction (CO2RR) is a cleaner strategy for CO2 utilization and conversion to stable energy (fuels). One of the critical issues in these cleaner technologies is the development of efficient and economical electrocatalyst. Among various materials, metal‐organic frameworks (MOFs) are becoming increasingly popular because of their structural tunability, such as pre‐ and post‐ synthetic modifications, flexibility in ligand design and its functional groups, and incorporation of different metal nodes, that allows for the design of suitable MOFs with desired quality required for each process. In this review, the design of MOF was discussed for specific process together with different synthetic methods and their effects on the MOF properties. The MOFs as electrocatalysts were highlighted with their performances from the aspects of hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and electrochemical CO2RR. Finally, the challenges and opportunities in this field are discussed.
Differentially methylated genes involved in reproduction and ploidy levels in recent diploidized and tetraploidized Eragrostis curvula genotypes
Authors: Carballo J. , Achilli A. , Hernández F. , Bocchini M. , Pasten M. C. , Marconi G. , Albertini E. , Zappacosta D. , Echenique V. 
Published: December 2023

AbstractEpigenetics studies changes in gene activity without changes in the DNA sequence. Methylation is an epigenetic mechanism important in many pathways, such as biotic and abiotic stresses, cell division, and reproduction. Eragrostis curvula is a grass species reproducing by apomixis, a clonal reproduction by seeds. This work employed the MCSeEd technique to identify deferentially methylated positions, regions, and genes in the CG, CHG, and CHH contexts in E. curvula genotypes with similar genomic backgrounds but with different reproductive modes and ploidy levels. In this way, we focused the analysis on the cvs. Tanganyika INTA (4x, apomictic), Victoria (2x, sexual), and Bahiense (4x, apomictic). Victoria was obtained from the diploidization of Tanganyika INTA, while Bahiense was produced from the tetraploidization of Victoria. This study showed that polyploid/apomictic genotypes had more differentially methylated positions and regions than the diploid sexual ones. Interestingly, it was possible to observe fewer differentially methylated positions and regions in CG than in the other contexts, meaning CG methylation is conserved across the genotypes regardless of the ploidy level and reproductive mode. In the comparisons between sexual and apomictic genotypes, we identified differentially methylated genes involved in the reproductive pathways, specifically in meiosis, cell division, and fertilization. Another interesting observation was that several differentially methylated genes between the diploid and the original tetraploid genotype recovered their methylation status after tetraploidization, suggesting that methylation is an important mechanism involved in reproduction and ploidy changes.
eHealth interventions to support colorectal cancer patients’ self-management after discharge from surgery—an integrative literature review
Authors: Husebø Anne Lunde Marie , Søreide Jon Arne , Kørner Hartwig , Storm Marianne , Wathne Hege Bjøkne , Richardson Alison , Morken Ingvild Margreta , Urstad Kristin Hjorthaug , Nordfonn Oda Karin , Karlsen Bjørg 
Published: December 2023

Abstract
Introduction
Colorectal cancer (CRC) creates elevated self-management demands and unmet support needs post-discharge. Follow-up care through eHealth post-primary surgery may be an effective means of supporting patients’ needs. This integrative review describes the evidence regarding eHealth interventions post-hospital discharge focusing on delivery mode, user-interface and content, patient intervention adherence, impact on patient-reported outcomes and experiences of eHealth.

Methods
A university librarian performed literature searches in 2021 using four databases. After screening 1149 records, the authors read 30 full-text papers and included and extracted data from 26 papers. Two authors analysed the extracted data using the ‘framework synthesis approach’.

Results
The 26 papers were published between 2012 and 2022. The eHealth interventions were mainly delivered by telephone with the assistance of healthcare professionals, combined with text messages or video conferencing. The user interfaces included websites, applications and physical activity (PA) trackers. The interventions comprised the monitoring of symptoms or health behaviours, patient information, education and counselling. Evidence showed a better psychological state and improved PA. Patients reported high satisfaction with eHealth. However, patient adherence was inadequately reported.

Conclusions
eHealth interventions may positively impact CRC patients’ anxiety and PA regardless of the user interface. Patients prefer technology combined with a human element.
Re-imagining metastatic breast cancer care delivery: a patient-partnered qualitative study
Authors: Roberson Mya L. , Henricks Anna , Woods Joshua , Glenn Lesley , Maues Julia , James Deltra , Reid Sonya 
Published: December 2023

Abstract
Purpose
While significant progress in metastatic breast cancer (MBC) treatment has prolonged survival and improved prognosis, there remain substantial gaps in providing patient-centered supportive care. The specific care delivery needs for metastatic cancer differ from that of early-stage cancer due to the incurable nature and lifelong duration of the condition. The objective of this study was to assess how patients living with MBC would re-imagine cancer care delivery.

Methods
This qualitative study was conducted in partnership with patient-led organizations Guiding Researchers and Advocates to Scientific Partnerships (GRASP) and Project Life, a nonprofit, online wellness community founded by patients with MBC for patients living with MBC. Virtual semi-structured interviews (n = 36) were conducted with Project Life members purposively sampled from the groups’ overall membership. The interview guide contained items surrounding patients’ lived experiences of MBC, greatest unmet needs related to care, and perspectives on virtual wellness community involvement. Interviews were coded using two-stage deductive and inductive analysis.

Results
Three major themes for re-imagining cancer care delivery were identified, including holistic care, information needs, and conceptual shifts. Within these several subthemes emerged with patients re-imagining referrals to non-oncological services, caregiver support, acceptance of integrative medicine, streamlined clinical trial enrollment, curated quality patient resources, MBC-specific terminology and approaches, long-term life and goal-of-care planning, and patient-centered voice throughout.

Conclusion
People living with metastatic cancers have specific supportive care needs. These findings highlight patient-driven areas for re-imagination that are most salient for individuals with MBC.
Exploratory and seasonal movements of adult common shelducks in the eastern Wadden Sea
Authors: Cimiotti Dagmar S. , Hötker Hermann , Garthe Stefan 
Published: December 2023

AbstractHabitat conditions surrounding individual birds are key components determining their fitness, notably by influencing effective foraging, escape from predators, and adaptation to changing environmental conditions. Birds living in dynamic habitats are particularly likely to have a high need to explore; however, spatial and temporal patterns of exploratory movements are poorly understood. We investigated the exploratory movements of adult common shelducks (hereafter Shelducks, Tadorna tadorna) in the Wadden Sea, which provides a dynamic habitat for birds. We captured nine shelducks in adjacent breeding areas and attached GPS satellite telemetry devices for 5–18 months, mostly covering the post-breeding period. We analyzed bird-movement patterns based on mean daily locations and behavioral change point analysis. All individuals explored on a median of 22% of tracking days (range = 6–39%). Individuals usually explored new areas for a short time before switching to stay in these areas for longer periods. Exploratory movements were particularly frequent before the start of the flightless period during molting. During this time, shelducks explored the traditional molting area in the Elbe estuary intensively. However, birds did not explore places within the area subsequently used for molting for longer or more often than other places. The molting area was used for a median of 59 days, i.e., about twice as long as required for the flightless period, suggesting that this area was explored not only to select a suitable molting place, but also for other purposes. Only two shelducks performed longer-distance exploration movements, i.e., > 45 km from their sedentary areas. We therefore concluded that exploratory movements by adult shelducks may enable the birds to adapt to small-scale changes in habitat conditions.