bluuebunny/crossref_metadata_2025_split huggingface dataset:
Standardization of Nutrient Requirement for Enhancing Yield and Quality in Grape (Vitis vinifera L.) Var. Red Globe
Authors: Kavitha C. , Shamini M. 
Published: November 2023

Grape is one of the important fruit crops grown for its refreshing and nutritious berries. Adequate nutrition is very important for grape cultivation as it directly reflects in the yield and quality of the crop. A field experiment was conducted in the College orchard, TNAU, Coimbatore to standardize the nutrient requirement for the grape variety Red Globe. The experiment consisted of thirteen treatments with varying levels of N (100, 150, 200 g/vine) and K (150, 300, 450, 600 g/ vine) without altering P levels and was laid out in randomized block design with three replications. The results revealed that application of 30 kg FYM + 100:150:150 g NPK/vine (T2) improved the yield/vine (17.25 and 15.51 kg) by increasing the number of bunches per vine (23.00 and 20.13) with optimal bunch weight (750.0 and 770.3 g) in summer and winter season crops respectively. However, the application of 30 kg FYM + 150:150:450 g NPK/vine (T9) improved the quality parameters viz., total soluble solids (17.84 and 17.59 °Brix), reducing sugars (15.65% and 15.55%) and total sugars (17.22% and 17.76%) along with a decrease in acidity (0.48 and 0.49%).
The Role of Socioeconomic Position in the Association Between Mental Disorders and Mortality
Authors: Chen Danni , Ejlskov Linda , Laustsen Lisbeth Mølgaard , Weye Nanna , Sørensen Christine Leonhard Birk , Momen Natalie C. , Dreier Julie Werenberg , Zheng Yan , Damgaard Astrid Jensen , McGrath John J. , Sørensen Henrik Toft , Plana-Ripoll Oleguer 
Published: November 2023

ImportanceStudies are lacking summarizing how the association between mental disorders and mortality varies by socioeconomic position (SEP), particularly considering different aspects of SEP, specific types of mental disorders, and causes of death.ObjectiveTo investigate the role of SEP in the association between mental disorders and mortality and the association between SEP and mortality among people with mental disorders.Data SourcesMEDLINE, Embase, PsycINFO, and Web of Science were searched from January 1, 1980, through April 3, 2023, and a snowball search of reference and citation lists was conducted.Study SelectionInclusion criteria were observational studies estimating the associations between different types of mental disorders and mortality, stratified by SEP and between SEP and mortality in people with mental disorders.Data Extraction and SynthesisPairs of reviewers independently extracted data using a predefined data extraction form and assessed the risk of bias using the adapted Newcastle-Ottawa scale. Graphical analyses of the dose-response associations and random-effects meta-analyses were performed. Heterogeneity was explored through meta-regressions and sensitivity analyses.Main Outcomes and MeasuresAll-cause and cause-specific mortality.ResultsOf 28 274 articles screened, 71 including more than 4 million people with mental disorders met the inclusion criteria (most of which were conducted in high-income countries). The relative associations between mental disorders and mortality were similar across SEP levels. Among people with mental disorders, belonging to the highest rather than the lowest SEP group was associated with lower all-cause mortality (pooled relative risk [RR], 0.79; 95% CI, 0.73-0.86) and mortality from natural causes (RR, 0.73; 95% CI, 0.62-0.85) and higher mortality from external causes (RR, 1.18; 95% CI, 0.99-1.41). Heterogeneity was high (I2 = 83% to 99%). Results from subgroup, sensitivity, and meta-regression analyses were consistent with those from the main analyses. Evidence on absolute scales, specific diagnoses, and specific causes of death was scarce.Conclusion and RelevanceThis study did not find a sufficient body of evidence that SEP moderated the relative association between mental disorders and mortality, but the underlying mortality rates may differ by SEP group, despite having scarcely been reported. This information gap, together with our findings related to SEP and a possible differential risk between natural and external causes of death in individuals with specific types of mental disorders, warrants further research.
Diagnosis of piscine francisellosis in Largemouth Bass from a public display exhibit in north-central Florida, USA
Authors: Sheehy Amanda , Shahin Khalid , Camus Alvin , Francis-Floyd Ruth , Yanong Roy , Fogelson Susan , Soto Esteban 
Published: November 2023

Abstract

Objective
The Largemouth Bass Micropterus salmoides is an important freshwater fish that is native to the southeastern United States and is cultured for conservation, food, and for the sports fishing industry. Francisella orientalis is a globally distributed bacterial pathogen of warmwater fish species and is associated with granulomatous inflammation and high mortalities. Outbreaks of piscine francisellosis in the United States have been reported in only a few fish species. This study describes three case presentations of francisellosis in Largemouth Bass from a public display system in north-central Florida. Additionally, laboratory-controlled immersion challenges using an F. orientalis isolate from tilapia Oreochromis spp. evaluate susceptibility of Largemouth Bass fingerlings to F. orientalis infection and mortality through this exposure route.

Methods
Necropsy, histologic examination, immunohistochemistry, bacterial recovery and culture, and quantitative polymerase chain reaction were used as diagnostic tools to evaluate both the affected display fish and the immersion-challenged fingerlings.

Result
Although the display fish and immersion-challenged fingerlings presented with nonspecific clinical signs, gross and histological changes were indicative of granulomatous disease. Immunohistochemical and molecular testing methods confirmed F. orientalis infection in affected fish.

Conclusion
The three case presentations described here mark the first reporting of naturally occurring piscine francisellosis in Largemouth Bass that were held in a public display exhibit. Additionally, causality was proven in the Largemouth Bass fingerlings through the immersion challenges. These findings demonstrate susceptibility through immersion-based exposure and assert that francisellosis should be considered among the list of differential diagnoses for Largemouth Bass with granulomatous disease.
Lattice‐Matched Interfacial Modulation Based on Olivine Enamel‐Like Front‐Face Fabrication for High‐Voltage LiCoO2
Authors: Yan Yawen , Zhou Shiyuan , Zheng Yichun , Zhang Haitang , Chen Jianken , Zeng Guifan , Zhang Baodan , Tang Yonglin , Zheng Qizheng , Wang Changhao , Wang Chuan‐Wei , Liao Hong‐Gang , Manke Ingo , Kuai Xiaoxiao , Dong Kang , Sun Yang , Qiao Yu , Sun Shi‐Gang 
Published: November 2023

AbstractThe high‐voltage induced undesirable surface passivation bilayer (cathode/electrolyte interface and cation‐densified surface phase) of LiCoO2 inevitably leads to battery degradation. Herein, a continual/uniform enamel‐like olivine layer on LiCoO2 surface is fabricated by employing a high‐speed mechanical fusion method . The enamel‐like layer suppresses interfacial side reactions by tuning EC dehydrogenation, contributing to an ultrathin and stable cathode/electrolyte interface. The strong bonding affinity between LiCoO2 and enamel‐like layer restrains both lattice oxygen loss and associated layered‐to‐spinel structural distortion. Moreover, the thermal stability of highly delithiated LiCoO2 is improved, as both the onset temperatures of layered‐to‐spinel transition and O2 evolution are simultaneously postponed. Stable operation of LiCoO2 at 4.6 V high‐voltage and 55 °C elevated temperature (both >85% capacity retention after 200 cycles) is achieved. This facile and scalable high‐speed solid‐phase coating strategy establishes a technical paradigm to enhance surface/interface stability of high‐energy‐density cathode candidates by constructing an ideal enamel‐like surface layer.
Building a Better Silver Bullet: Current Status and Perspectives of Non‐Viral Vectors for mRNA Vaccines
Authors: Gu Jiayu , Xu Zhourui , Liu Qiqi , Tang Shiqi , Zhang Wenguang , Xie Shouxia , Chen Xiaoyan , Chen Jiajie , Yong Ken‐Tye , Yang Chengbin , Xu Gaixia 
Published: November 2023

AbstractIn recent years, messenger RNA (mRNA) vaccines have exhibited great potential to replace conventional vaccines owing to their low risk of insertional mutagenesis, safety and efficacy, rapid and scalable production, and low‐cost manufacturing. With the great achievements of chemical modification and sequence optimization methods of mRNA, the key to the success of mRNA vaccines is strictly dependent on safe and efficient gene vectors. Among various delivery platforms, non‐viral mRNA vectors could represent perfect choices for future clinical translation regarding their safety, sufficient packaging capability, low immunogenicity, and versatility. In this review, the recent progress in the development of non‐viral mRNA vectors is focused on. Various organic vectors including lipid nanoparticles (LNPs), polymers, peptides, and exosomes for efficient mRNA delivery are presented and summarized. Furthermore, the latest advances in clinical trials of mRNA vaccines are described. Finally, the current challenges and future possibilities for the clinical translation of these promising mRNA vectors are also discussed.
Hole Transport Layer‐Free Low‐Bandgap Perovskite Solar Cells for Efficient All‐Perovskite Tandems
Authors: Ma Tianshu , Wang Huayang , Wu Zhanghao , Zhao Yue , Chen Cong , Yin Xinxing , Hu Lin , Yao Fang , Lin Qianqian , Wang Shaojun , Zhao Dewei , Li Xiaofeng , Wang Changlei 
Published: November 2023

AbstractLow‐bandgap (LBG, Eg ≈1.25 eV) tin‐lead (Sn‐Pb) perovskite solar cells (PSCs) play critical roles in constructing efficient all‐perovskite tandem solar cells (TSCs) that can surpass the efficiency limit of single‐junction solar cells. However, the traditional poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) hole transport layer (HTL) in LBG PSCs usually restricts device efficiency and stability. Here, a strategy of employing 2‐aminoethanesulfonic acid (i.e., taurine) as the interface bridge to fabricate efficient HTL‐free LBG PSCs with improved optoelectronic properties of the perovskite absorbers at the buried contacts is reported. Taurine‐modified ITO substrate has lower optical losses, better energy level alignment, and higher charge transfer capability than PEDOT:PSS HTL, leading to significantly improved open‐circuit voltage (VOC) and short‐circuit current density of corresponding devices. The best‐performing LBG PSC with a power conversion efficiency (PCE) of 22.50% and an impressive VOC of 0.911 V is realized, enabling all‐perovskite TSCs with an efficiency of 26.03%. The taurine‐based HTL‐free TSCs have highly increased stability, retaining more than 90% and 80% of their initial PCEs after constant operation under 1‐sun illumination for 600 h and under 55 °C thermal stress for 950 h, respectively. This work provides a facile strategy for fabricating efficient and stable perovskite devices with a simplified HTL‐free architecture.
Wide‐Range Angle‐Sensitive Plasmonic Color Printing on Lossy‐Resonator Substrates
Authors: Chowdhury Sarah N. , Simon Jeffrey , Nowak Michał P. , Pagadala Karthik , Nyga Piotr , Fruhling Colton , Bravo Esteban Garcia , Maćkowski Sebastian , Shalaev Vladimir M. , Kildishev Alexander V. , Boltasseva Alexandra 
Published: November 2023

AbstractA sustainable, lithography‐free process is demonstrated for generating non fading plasmonic colors with a prototype device that produces a wide range of vivid colors in red, green, and blue (RGB) ([0‐1], [0‐1], [0‐1]) color space from violet (0.7, 0.72, 1) to blue (0.31, 0.80, 1) and from green (0.84, 1, 0.58) to orange (1, 0.58, 0.46). The proposed color‐printing device architecture integrates a semi‐transparent random metal film (RMF) with a metal back mirror to create a lossy asymmetric Fabry‐Pérot resonator. This device geometry allows for advanced control of the observed color through the five‐degree multiplexing (Red‐Green‐Blue (RGB) color space, angle, and polarization sensitivity). An extended color palette is then obtained through photomodification process and localized heating of the RMF layer under various femtosecond laser illumination conditions at the wavelengths of 400 nm and 800 nm. Colorful design samples with total areas up to 10 mm2and 100 µm resolution are printed on 300‐nm‐thick films to demonstrate macroscopic personalized high‐resolution color generation. The proposed printing approach can be extended to other applications including laser marking, anti‐counterfeiting, and chromo‐encryption.
Exploring the Elusive Mind: A Multimodal Wearable Sensor Solution for Measuring Mind Wandering in University Students
Authors: Khosravi Sara , Li Haobo , Khan Ahsan Raza , Zoha Ahmad , Ghannam Rami 
Published: November 2023

AbstractMind‐wandering is a typical daily phenomenon during which attention shifts from external stimuli to internal trains of thought. It affect students' learning by impairing comprehension, diminishing academic achievement, impeding critical thinking, and encouraging a lack of attention and engagement in classroom activities. This study aims to introduce a new method of detecting and tracking mind wandering in university students. This approach involves using wearable sensors, including galvanic skin response (GSR), photoplethysmography (PPG), and eye‐trackers, along with machine learning techniques. The study provides a proof of concept for this multisensory approach. The association between longer fixation duration and mind wandering, and the influence of an instructor's presence on fixation allocation, and, consequently, the frequency and occurrence of mind wandering is investigated. Furthermore, the feasibility of using eye‐trackers in conjunction with GSR and PPG sensors for detecting mind wandering through a wearable multisensory data collection system is assessed. The wearable multisensory device is evaluated by ten participants (university students, males/females aged between 21‐30). Two distinct machine learning methods, support vector machine (SVM) and gated recurrent unit (GRU), are used as classification models. With sensor fusion, the SVM and GRU models yielded maximum accuracies of 86.53% and 89.86%, respectively. Moreover, participants are observed to fixate on instructors more often, just before instances of mind wandering.
Hematopoietic Transcription Factor RUNX1 is Essential for Promoting Macrophage–Myofibroblast Transition in Non‐Small‐Cell Lung Carcinoma
Authors: Tang Philip Chiu‐Tsun , Chan Max Kam‐Kwan , Chung Jeff Yat‐Fai , Chan Alex Siu‐Wing , Zhang Dongmei , Li Chunjie , Leung Kam‐Tong , Ng Calvin Sze‐Hang , Wu Yi , To Ka‐Fai , Lan Hui‐Yao , Tang Patrick Ming‐Kuen 
Published: November 2023

AbstractMacrophage‐myofibroblast transition (MMT) is a newly discovered pathway for mass production of pro‐tumoral cancer‐associated fibroblasts (CAFs) in non‐small cell lung carcinoma (NSCLC) in a TGF‐β1/Smad3 dependent manner. Better understanding its regulatory signaling in tumor microenvironment (TME) may identify druggable target for the development of precision medicine. Here, by dissecting the transcriptome dynamics of tumor‐associated macrophage at single‐cell resolution, a crucial role of a hematopoietic transcription factor Runx1 in MMT formation is revealed. Surprisingly, integrative bioinformatic analysis uncovers Runx1 as a key regulator in the downstream of MMT‐specific TGF‐β1/Smad3 signaling. Stromal Runx1 level positively correlates with the MMT‐derived CAF abundance and mortality in NSCLC patients. Mechanistically, macrophage‐specific Runx1 promotes the transcription of genes related to CAF signatures in MMT cells at genomic level. Importantly, macrophage‐specific genetic deletion and systemic pharmacological inhibition of TGF‐β1/Smad3/Runx1 signaling effectively prevent MMT‐driven CAF and tumor formation in vitro and in vivo, representing a potential therapeutic target for clinical NSCLC.
Progress, Challenge, and Prospect of LiMnO2: An Adventure toward High‐Energy and Low‐Cost Li‐Ion Batteries
Authors: Ma Jin , Liu Tingting , Ma Jie , Zhang Chi , Yang Jinhu 
Published: November 2023

AbstractLithium manganese oxides are considered as promising cathodes for lithium‐ion batteries due to their low cost and available resources. Layered LiMnO2 with orthorhombic or monoclinic structure has attracted tremendous interest thanks to its ultrahigh theoretical capacity (285 mAh g−1) that almost doubles that of commercialized spinel LiMn2O4 (148 mAh g−1). However, LiMnO2 undergoes phase transition to spinel upon cycling cause by the Jahn‐Teller effect of the high‐spin Mn3+. In addition, soluble Mn2+ generates from the disproportionation of Mn3+ and oxygen release during electrochemical processes may cause poor cycle performance. To address the critical issues, tremendous efforts have been made. This paper provides a general review of layered LiMnO2 materials including their crystal structures, synthesis methods, structural/elemental modifications, and electrochemical performance. In brief, first the crystal structures of LiMnO2 and synthetic methods have been summarized. Subsequently, modification strategies for improving electrochemical performance are comprehensively reviewed, including element doping to suppress its phase transition, surface coating to resist manganese dissolution into the electrolyte and impede surface reactions, designing LiMnO2 composites to improve electronic conductivity and Li+ diffusion, and finding compatible electrolytes to enhance safety. At last, future efforts on the research frontier and practical application of LiMnO2 have been discussed.
MXene‐Integrated Perylene Anode with Ultra‐Stable and Fast Ammonium‐Ion Storage for Aqueous Micro Batteries
Authors: Niu Ke , Shi Junjie , Zhang Long , Yue Yang , Mo Shuyi , Li Shaofei , Li Wenbiao , Wen Li , Hou Yixin , Sun Li , Yan Shuwen , Long Fei , Gao Yihua 
Published: November 2023

AbstractThe aqueous micro batteries (AMBs) are expected to be one of the most promising micro energy storage devices for its safe operation and cost‐effectiveness. However, the performance of the AMBs is not satisfactory, which is attributed to strong interaction between metal ions and the electrode materials. Here, the first AMBs are developed with NH4+ as charge carrier. More importantly, to solve the low conductivity and the dissolution during the NH4+ intercalation/extraction problem of perylene material represented by perylene‐3,4,9,10‐tetracarboxylic dianhydride (PTCDA), the Ti3C2Tx MXene with high conductivity and polar surface terminals is introduced as a conductive skeleton (PTCDA/Ti3C2Tx MXene). Benefitting from this, the PTCDA/Ti3C2Tx MXene electrodes exhibit ultra‐high cycle life and rate capability (74.31% after 10 000 galvanostatic chargedischarge (GCD) cycles, and 91.67 mAh g−1 at 15.0 A g−1, i.e., capacity retention of 45.2% for a 30‐fold increase in current density). More significantly, the AMBs with NH4+ as charge carrier and PTCDA/Ti3C2Tx MXene anode provide excellent energy density and power density, cycle life, and flexibility. This work will provide strategy for the development of NH4+ storage materials and the design of AMBs.
Analysis of a Cu‐Doped Metal–Organic Framework, MFM‐520(Zn1‐xCux), for NO2 Adsorption
Authors: Wang Zi , Sheveleva Alena M. , Li Jiangnan , Zhou Zhengyang , Sapchenko Sergei , Whitehead George , Warren Mark R. , Collison David , Sun Junliang , Schröder Martin , McInnes Eric J. L. , Yang Sihai , Tuna Floriana 
Published: November 2023

AbstractMFM‐520(Zn) confines dimers of NO2 with a high adsorption of 4.52 mmol g−1 at 1 bar at 298 K. The synthesis and the incommensurate structure of Cu‐doped MFM‐520(Zn) are reported. The introduction of paramagnetic Cu2+ sites allows investigation of the electronic and geometric structure of metal site by in situ electron paramagnetic resonance (EPR) spectroscopy upon adsorption of NO2. By combining continuous wave and electron‐nuclear double resonance spectroscopy, an unusual reverse Berry distorted coordination geometry of the Cu2+ centers is observed. Interestingly, Cu‐doped MFM‐520(Zn0.95Cu0.05) shows enhanced adsorption of NO2 of 5.02 mmol g−1 at 1 bar at 298 K. Whereas MFM‐520(Zn) confines adsorbed NO2 as N2O4, the presence of monomeric NO2 at low temperature suggests that doping with Cu2+ centers into the framework plays an important role in tuning the dimerization of NO2 molecules in the pore via the formation of specific host‐guest interactions.
Advances in Heterogeneous Catalysts for Lignin Hydrogenolysis
Authors: Shen Zhensheng , Shi Chengxiang , Liu Fan , Wang Wei , Ai Minhua , Huang Zhenfeng , Zhang Xiangwen , Pan Lun , Zou Ji‐Jun 
Published: November 2023

AbstractLignin is the main component of lignocellulose and the largest source of aromatic substances on the earth. Biofuel and bio‐chemicals derived from lignin can reduce the use of petroleum products. Current advances in lignin catalysis conversion have facilitated many of progress, but understanding the principles of catalyst design is critical to moving the field forward. In this review, the factors affecting the catalysts (including the type of active metal, metal particle size, acidity, pore size, the nature of the oxide supports, and the synergistic effect of the metals) are systematically reviewed based on the three most commonly used supports (carbon, oxides, and zeolites) in lignin hydrogenolysis. The catalytic performance (selectivity and yield of products) is evaluated, and the emerging catalytic mechanisms are introduced to better understand the catalyst design guidelines. Finally, based on the progress of existing studies, future directions for catalyst design in the field of lignin depolymerization are proposed.