bluuebunny/crossref_metadata_2025_split huggingface dataset:
Physically Unclonable Functions Based on Self‐Oriented Nanowires
Authors: Zhao Zihao , Wang Xingyu , Zhang Lingyu , Song Jian , Liao Jihui , Wang Hao , Xu Jinyou 
Published: October 2023

AbstractAs scaling down to the nanoscale, the dramatically increased morphological deviation between nanostructures becomes a major challenge in implementing large‐scale nanodevices. On the other side of the coin, the often‐undesirable rich non‐repeatable randomness introduced during nanostructure growth and subsequent device fabrication is of great value in the implementation of physically unclonable functions (PUF), a booming innovative security primitive. Herein, it is shown that the self‐oriented organic nanowires grown on a faceted surface through a vapor transport process are advanced building blocks for the implementation of two novel PUFs. An optical PUF is first demonstrated by exploiting the unclonable morphological randomness of the self‐oriented nanowires (e.g., length, thickness, density, and location), which can provide an entity‐specific primary encryption for nanowire devices. Next, these nanowires are integrated into photodetector arrays directly on their growth substrate and accordingly enable an electrical PUF based on the inherent resistance variation between detector cells. Furthermore, by combining these two PUFs, a secondary encryption with higher security is proposed for information communication. The implementation of nanowire‐based PUFs not only opens a new device direction to exploit the annoying unclonable randomness of bottom‐up nanowires, but also provides innovative label‐free security primitives for emerging nanowire‐based devices and systems.
Solar Thermal Absorber Using Fe2O3‐SnSe2‐Ti‐Layered Structure Based on Graphene Material
Authors: Almawgani Abdulkarem H. M. , Bo Han Bo , Patel Shobhit K. , Armghan Ammar , Alabsi Basim Ahmad , Taya Sofyan A. 
Published: October 2023

AbstractIn solar energy systems, manufacturing solar absorbers also includes an important section. A one‐perfect design is constructed in three layers to develop a good solar absorption rate and a graphene layer is used in this developed structure. Titanium (Ti) is in the base layer, Stannic selenide (SnSe2) is in the substrate layer, and Ferric Oxide (Fe2O3) is a resonator. The absorption rates can be presented between the overall wavelength range of 0.2–3 µm and divided into three segments. The absorption percentage is above 90% for 2800 nm, more than 95% is in the half region of 0.2–2 µm (1800 nm), and the perfect absorption result of 97% is between 0.2 and 1.5 µm (1300 nm), respectively. AM 1.5 section and graphene results can be calculated by using the numerical equations. To indicate the fewer and greater parameters of the present number, parameter variation sections can be presented. According to the symmetrical design of the developed structure, TE and TM results are almost identical and can be configured in color representation. The greater the amount of light intensity, the greater the number of absorption rates. The polarization can be checked between 0° and 50° changes.
A Spin‐Orbit Torque Switch at Ferromagnet/Antiferromagnet Interface Toward Stochastic or Memristive Applications via Tailoring Antiferromagnetic Ordering
Authors: Wang Ssu‐Yuan , Chen Sheng‐Huai , Chang Hao‐Kai , Li Yi‐Ting , Tseng Chih‐Hsiang , Chen Po‐Chuan , Yang Chao‐Yao , Lai Chih‐Huang 
Published: October 2023

AbstractAntiferromagnet (AFM) has currently participated in the spin‐orbit torque (SOT) technology due to its great potential to be applied to the field‐free SOT switching and to promote the thermal stability of MRAM. However, the effect of varying AFM ordering on the SOT switching and the associated properties is still not comprehensively understood. This work reports how an AFM ordering modifies the strength of Dzyaloshinskii–Moriya‐interaction (DMI) in a heavy metal (Pt)/FM (Co)/AFM (IrMn) trilayer and its effects on SOT switching. Increasing the AFM ordering reflects the enhanced exchange bias through increasing IrMn thickness appears to significantly reduce the DMI strength of the trilayer. Controlling the IrMn thickness appears to serve as a unique switch to activate memristivity/stochasticity in the devices via tailoring AFM ordering on exchange bias: The strong AFM ordering via increasing IrMn thickness enables to increase the stability of multi‐levels for SOT switching, which promotes the memristivity for neuromorphic application. On the contrary, the weak AFM ordering via reducing IrMn thickness will lead to significant stochasticity for the physically unclonable functionality. This work demonstrates an intrinsic tuning over the AFM ordering will serve as a switch to turn the SOT device into a stochastic/memristive cell to bridge probabilistic and neuromorphic computing.
Ultrathin Superhydrophobic Coatings for Air‐Stable Inorganic Solid Electrolytes: Toward Dry Room Application for All‐Solid‐State Batteries
Authors: Kim Kyu Tae , Woo Jehoon , Kim Young‐Soo , Sung Sihyeon , Park Changhyun , Lee Chanhee , Park Young Joon , Lee Hyun‐Wook , Park Kyusung , Jung Yoon Seok 
Published: October 2023

AbstractInorganic solid electrolytes (SEs), such as sulfides and halides, are crucial for developing practical all‐solid‐state batteries (ASSBs) owing to their high ionic conductivities and mechanical sinterabilities. However, their sensitivity to humid air necessitates stringent dry‐room conditions during processing, which increases production costs. This study demonstrates that ultrathin (≈5 nm) superhydrophobic polydimethylsiloxane (PDMS) or fluorinated PDMS (F‐PDMS) protective layers can enhance the stability of air‐sensitive sulfide (Li6PS5Cl (LPSCl)) and halide (Li2.5Zr0.5In0.5Cl6) SEs in ASSBs. The (F)‐PDMS coatings are applied using a scalable, straightforward vapor‐phase deposition process, achieving high Li+ conductivity retention (92%, from 2.5 to 2.3 mS cm−1 at 30 °C). The protective layers effectively inhibit LPSCl degradation under practically relevant dry room conditions (dew point of −50 °C or −10 °C): e.g., from 2.3 to 0.97 mS cm−1 for PDMS‐coated LPSCl versus from 2.5 to 0.57 mS cm−1 for bare LPSCl. Surprisingly, the superhydrophobic coatings facilitate the recovery of Li+ conductivity via vacuum heat treatment. This new phenomenon, known as regeneration, is achieved by the facile elimination of adsorbed water. Furthermore, the regenerated (F)‐PDMS‐coated LPSCl demonstrates significant performance in NCM||Li‐In ASSB cells. These findings suggest that superhydrophobic (F)‐PDMS coatings are a promising solution for practical all‐solid‐state technologies.
Overcoming Two Key Challenges in Monolithic Perovskite‐Silicon Tandem Solar Cell Development: Wide Bandgap and Textured Substrate—A Comprehensive Review
Authors: Khan Danish , Qu Geping , Muhammad Imran , Tang Zeguo , Xu Zong‐Xiang 
Published: October 2023

Abstract33.7% of power conversion efficiency (PCE) in monolithic perovskite‐silicon tandem solar cells (PSTSCs) is an eye‐catcher. Still, the issues emerging from their two main requirements, wide band gap (WBG) perovskites and textured substrates, trigger phase segregation, voltage deficit, perovskite strain, high recombination rates, shunt paths, etc. In addition, the ill‐defined relations of most of these issues to the WBG perovskites and silicon texture originating from the conflicting research outcomes have become severe impediments to developing PSTSCs. From this perspective, an overview of the recently developed monolithic PSTSCs discussing the major hurdles in their up‐scaling, stabilities, and commercialization is presented.
Enhancing Oxygen Evolution Reaction by Simultaneously Triggering Metal and Lattice Oxygen Redox Pair in Iridium Loading on Ni‐Doped Co3O4
Authors: Wang Ansheng , Wang Wanying , Xu Jinchao , Zhu Ao , Zhao Chunning , Yu Meng , Shi Guoliang , Yan Jiaguo , Sun Shuhui , Wang Weichao 
Published: October 2023

AbstractSince the active sites in catalytic systems are either metal sites or lattice oxygen, simultaneously triggering metal and lattice oxygen redox pair with low energy barriers is expected to provide diversified and efficient sites to accelerate oxygen evolution reaction (OER) kinetics, but this is a great challenge. Herein, Ir species (Ir clusters and Ir single atoms) loaded on Ni‐doped Co3O4 is designed (Ir/Ni‐Co3O4), where metallic Ir clusters downsize to spread into high‐density Ir single atoms to load on reconstruction‐derived Ni‐doped CoOOH. In situ spectroscopy, isotope‐labeled, and chemical probe experiments demonstrate that metal site and lattice oxygen are simultaneously activated to participate in the OER. Further theoretical studies demonstrate that the Co site is the most favorable site to promote the OER through an adsorbate evolution mechanism with a low energy barrier of 1.69 eV. The Ni cooperating with Ir atoms synergistically upshifts energy positions of the O p band centers. Thus, the lattice O that bridges Ni and Ir atoms is activated to participate in the OER via coupling with adsorbed O on the Ir site to fulfill O─O bond formation. Benefiting from the conjoint participation of the metal and lattice oxygen redox pair, Ir/Ni‐Co3O4 affords extremely low OER overpotentials of 177 and 263 mV at corresponding 10 and 500 mA cm−2.
Skin‐Inspired Conversion Anodes for High‐Capacity and Stable Potassium Ion Batteries
Authors: Yang Xiaoteng , Gao Yang , Fan Ling , Rao Apparao M. , Zhou Jiang , Lu Bingan 
Published: October 2023

AbstractConversion materials are promising anodes for meeting the emerging demand for high‐energy‐density potassium‐ion batteries. However, their application as anodes is challenging due to the irreversible volume expansion and the resulting structural failure during cycling. Inspired by the skin's structure, skin‐inspired carbon‐coated Fe3O4 QDs (SC‐Fe3O4) is synthesized, which exhibits excellent electrochemical performance with a capacity retention of 84.3% and a stable operation for >7 months. The same method is used to synthesize a series of other conversion material anodes with skin‐inspired structures. Notably, the skin‐inspired carbon‐coated Fe1−xS QDs (SC‐Fe1−xS) show a high reversible capacity of 506 mAh g−1 and a long stability of 1200 cycles. The research illustrates the universality and superiority of biomimetic strategies and provides new insights and directions for building high‐performance rechargeable batteries.
Evaluation of two‐pass herbicide programs for broad‐spectrum weed control in conventional tillage non‐transgenic corn production in Wisconsin atrazine prohibition areas
Authors: Mobli Ahmadreza , DeWerff Ryan P. , Arneson Nicholas J. , Werle Rodrigo 
Published: October 2023

AbstractAchieving effective weed control is crucial for Wisconsin conventional corn growers farming in atrazine prohibition areas. Upon request from our extension clientele, a field study was conducted at Arlington and Brooklyn, WI, in 2021 and 2022 (four site‐years). The study aimed to evaluate the weed control efficacy of comprehensive two‐pass (PRE followed by POST) herbicide program treatments containing products with a wide range of active ingredients and sites of action from various manufacturers without atrazine and glyphosate, in conventional tillage non‐transgenic corn production. Nine and eight out of the 11 two‐pass herbicide programs investigated provided >90% giant foxtail (Setaria faberi Herrm), common ragweed (Ambrosia artemisiifolia L.), velvetleaf (Abutilon theophrasti Medik) and waterhemp [Amaranthus tuberculatus (Moq.) J.D. Sauer] control in 2021, respectively. However, only three treatments provided >90% waterhemp control and the greatest giant foxtail control in 2022 was 79%. Greater end‐of‐season broadleaf and grass weed control was observed in 2021 compared to 2022 due to lower weed pressure and timely early‐season rainfall in 2021. The two‐pass programs, acetochlor/mesotrione fb dicamba/tembotrione (94%–100%) and acetochlor/flumetsulan/clopyralid fb nicosulfuron + dicamba/diflufenzopyr (85%–100%), provided the most consistent broadleaf control across all site‐years. These results demonstrate that a well‐designed and timely deployed two‐pass herbicide program can provide effective control of common broadleaf and grass weeds in conventional corn production assuming moderate weed pressure and timely rainfall for soil residual herbicide activation, otherwise effective weed control, particularly of grass weeds, in the absence of atrazine and glyphosate can be challenging. These results are also translatable to support weed management decisions for glyphosate‐resistant corn hybrids in non‐atrazine prohibition areas.
From parts to whole: Embracing systems science in community psychology
Authors: Lawlor Jennifer A. , Metta Kyle R. 
Published: October 2023

AbstractWith our field's strong focus on context for understanding and acting on social problems, community psychologists have frequently elevated the importance of employing systems thinking and methods that help us to understand systems more effectively. As a result, community psychologists have adopted some methods from the interdisciplinary field of systems science. In this virtual special issue, we will compare how several of these approaches have been used in publications in the AJCP in the last 50 years. We identify differences in their popularity, implementation with communities, and how they create generative discussion in the field. We conclude by looking to the future to explore ways community psychology can deepen engagement with methods from systems science.
Bone health in SATB2‐associated syndrome: Results from a large prospective cohort and recommendations for surveillance
Authors: Zarate Yuri A. , Bosanko Katherine , Andres Aline , Fish Jennifer L. 
Published: October 2023

AbstractAlterations in SATB2 result in SATB2‐associated syndrome (SAS; Glass syndrome, OMIM 612313), an autosomal dominant multisystemic disorder predominantly characterized by developmental delay, craniofacial anomalies, and growth retardation. The bone phenotype of SAS has been less explored until recently and includes a variety of skeletal deformities, increased risk of low bone mineral density (BMD) with a propensity to fractures, and other biochemical abnormalities that suggest elevated bone turnover. We present the results of ongoing surveillance of bone health from 32 individuals (47% females, 3–18 years) with molecularly‐confirmed SAS evaluated at a multidisciplinary clinic. Five individuals (5/32, 16%) were documented to have BMD Z‐scores by DXA scans of −2.0 SD or lower and 7 more (7/32, 22%) had Z‐scores between −1 and − 2 SD at the lumbar spine or the total hip. Alkaline phosphatase levels were found to be elevated in 19 individuals (19/30, 63%) and determined to correspond to bone‐specific alkaline phosphatase elevations when measured (11/11, 100%). C‐telopeptide levels were found to be elevated when adjusted by age and gender in 6 individuals (6/14, 43%). Additionally, the two individuals who underwent bone cross‐sectional geometry evaluation by peripheral quantitative computed tomography were documented to have low cortical bone density for age and sex despite concurrent DXA scans that did not have this level of decreased density. While we could not identify particular biochemical abnormalities that predicted low BMD, the frequent elevations in markers of bone formation and resorption further confirmed the increased bone turnover in SAS. Based on our results and other recently published studies, we propose surveillance guidelines for the skeletal phenotype of SAS.
Magnetic Purcell Enhancement in a Nanoantenna‐Spherical Bragg Resonator Coupled System
Authors: García‐Puente Yalina , Kashyap Raman 
Published: October 2023

AbstractIn this work, a novel approach for enhancing magnetic fields in all‐dielectric nanoantennas using Spherical Bragg Resonators (SBR) is proposed, which can boost quantum emitters' magnetic transitions. A matrix method has been used to optimize the magnetic dipole resonance of a SiO2/Si core‐shell spherical nanoantenna. The radiative and non‐radiative decay rate of a Eu3+ emitter with a quantum efficiency of ∼80% is studied. The findings revealed that the magnetic dipole nanoantenna resonance coupling with the SBR mode significantly enhances the modal magnetic field. A 4‐layer SiO2/Si SBR results in a Purcell factor of , the highest it has found in the literature, to the best of the knowledge. The work offers a theoretical demonstration of the potential of SBR to improve the performance of dielectric nanoantennas.
Dielectric‐Based Electromagnetically Induced Transparency Metamaterial in the Microwave Band
Authors: Dong Han‐Qing , Gao Cheng‐Jing , Zhang Hai‐Feng 
Published: October 2023

AbstractAn electromagnetically induced transparency metamaterial (EITM) based on dielectric resonators is presented in this paper, which consists of a cut wire (CW) and ten dielectric columns. Destructive interference between the CW, which is a branch of the microstrip line, and the dielectric resonators causes the EIT phenomenon. The simulation results show that the dielectric‐based EITM designed can obtain a transmission peak of 0.938 at 2.17 GHz, and the two‐oscillator model is utilized to verify the effectiveness of the structure. In addition, samples of the dielectric‐based EITM are also fabricated and the effectiveness of the metamaterial is experimentally verified. The proposed metamaterial has several advantages, including high efficiency, low loss, a simple structure, and ease of manufacture, which has good prospects for application in the fields of electromagnetic switches, sensors, and nonlinear metamaterials.
Atherosclerosis Progression in the APPLE Trial Can Be Predicted in Young People With Juvenile‐Onset Systemic Lupus Erythematosus Using a Novel Lipid Metabolomic Signature
Authors: Peng Junjie , Dönnes Pierre , Ardoin Stacy P. , Schanberg Laura E. , Lewandowski Laura ,   APPLE trial investigators and Childhood Rheumatology Research Alliance (CARRA), Robinson George , Jury Elizabeth C. , Ciurtin Coziana 
Published: October 2023

ObjectivePatients with juvenile‐onset systemic lupus erythematosus (JSLE) have increased atherosclerosis risk. This study investigated novel atherosclerosis progression biomarkers in the Atherosclerosis Prevention in Pediatric Lupus Erythematosus (APPLE) trial, the largest investigator‐led randomized control trial of atorvastatin versus placebo for atherosclerosis progression in JSLE, using carotid intima‐media thickness (CIMT) as the primary outcome.MethodsUnsupervised clustering of baseline CIMT and CIMT progression over 36 months was used to stratify patients with JSLE. Disease characteristics, cardiovascular risk scores, and baseline serum metabolome were investigated in CIMT‐stratified patients. Machine learning techniques were used to identify and validate a serum metabolomic signature of CIMT progression.ResultsBaseline CIMT stratified patients with JSLE (N = 151) into three groups with distinct high, intermediate, and low CIMT trajectories irrespective of treatment allocation, despite most patients having low cardiovascular disease risk based on recommended assessment criteria. In the placebo group (n = 60), patients with high versus low CIMT progression had higher total (P = 0.001) and low‐density lipoprotein (LDL) (P = 0.002) cholesterol levels, although within the reference range. Furthermore, a robust baseline metabolomic signature predictive of high CIMT progression was identified in the placebo arm (area under the curve, 80.7%). Patients treated with atorvastatin (n = 61) had reduced LDL cholesterol levels after 36 months, as expected; however, despite this, 36% still had high atherosclerosis progression, which was not predicted by metabolomic biomarkers, suggesting nonlipid drivers of atherosclerosis in JSLE with management implications for this subset of patients.ConclusionSignificant baseline heterogeneity and distinct subclinical atherosclerosis progression trajectories exist in JSLE. Metabolomic signatures can predict atherosclerosis progression in some patients with JSLE with relevance for clinical trial stratification.image
The influence of therapists’ spirituality on their practice: A grounded theory exploration
Authors: Blair Lewis J. 
Published: October 2023

AbstractBackgroundCounselling and psychotherapy have complex relationships with religion and spirituality. Therapy has not tended to focus a great deal on the spirituality of the client, much less that of the therapist. More recently, there has been an increased interest in the role of spirituality in therapy.Aim/MethodologyThis study used a grounded theory methodology to explore the spirituality of nine therapists and to identify the ways in which their spirituality influences their practice.FindingsOne overarching theme emerged from the data, which was the reflective, dynamic, and developmental process in which participants were engaged, in order to integrate their spiritual and therapeutic identities. Within this, two sub‐themes emerged: the direct influence of therapist spirituality on therapeutic work, and finding harmony between spirituality and broader professional context.ImplicationsProcesses of professional and spiritual development of therapists are discussed along with implications for practice, training, and research.
Comparative exploration of narrative processes for better and poorer outcomes for depression
Authors: Banham James A. , Schweitzer Robert D. 
Published: October 2023

AbstractBackgroundContemporary psychotherapy research demonstrates that whilst most clients respond positively to psychological interventions, a small but significant proportion of clients fail to experience the expected benefits of therapy. Although methodologies exist that enable the identification of successful and unsuccessful therapy, we have a limited understanding of the processes associated with these outcomes.AimThis study sought to examine the relationship between therapeutic outcome and therapeutic language.MethodologyTherapeutic outcomes of 42 trainee–therapists who provided psychotherapy to 173 clients were tracked with the OQ‐45.2 over a five‐year period with the view of identifying the client/trainee–therapist dyads with the best and poorest outcomes. The six best outcome and six poorest outcome client/trainee–therapist dyads were identified to examine characteristics of therapeutic conversations associated with better and poorer therapy outcomes. Therapeutic conversations were analysed with the Narrative Process Coding System.FindingsBest outcome client/trainee–therapist dyads demonstrated significant increases in reflexive conversation over the course of psychotherapy. Implications: Examining the practices of best and poorest outcome client/trainee–therapist dyads with objective measures of therapy outcome provides an important first step in understanding how therapeutic language may contribute to the greatest therapeutic improvement or deterioration.
Catalytic Properties of Nanometric Metal Overlayers with Two‐Dimensional Structures
Authors: Yoshida Hiroshi , Machida Masato 
Published: October 2023

AbstractAlthough most of the currently used solid catalysts possess a three‐dimensional structure of nanoparticles dispersed on a porous support, the nanoparticle structure should not be considered the optimal structure for all catalytic reactions due to some disadvantages such as thermal instability and catalyst poisoning. Herein, we present the unique catalytic performance of a two‐dimensional metal foil‐supported nanometric Rh thin film, referred to as the “Rh overlayer”, for a catalytic CO−NO reaction and a stoichiometric three‐way catalytic reaction under practical conditions. The extremely high turnover frequency for NO reduction using two‐dimensional Rh is a key to understanding this phenomenon, the detailed mechanism of which can be explained by theoretical calculations.