bluuebunny/crossref_metadata_2025_split huggingface dataset:
Synthesis and Characterization of Mononuclear Ruthenium(III) Pyridylamine Complexes and Mechanistic Insights into Their Catalytic Alkane Functionalization with m‐Chloroperbenzoic Acid
Authors: Kojima Takahiko , Hayashi Ken‐ichi , Iizuka Shin‐ya , Tani Fumito , Naruta Yoshinori , Kawano Masaki , Ohashi Yuji , Hirai Yuichirou , Ohkubo Kei , Matsuda Yoshihisa , Fukuzumi Shunichi 
Published: July 2007

AbstractA series of mononuclear RuIII complexes [RuCl2(L)]+, where L is tris(2‐pyridylmethyl)amine (TPA) or one of four TPA derivatives as tetradentate ligand, were prepared and characterized by spectroscopic methods, X‐ray crystallography, and electrochemical measurements. The geometry of a RuIII complex having a non‐threefold‐symmetric TPA ligand bearing one dimethylnicotinamide moiety was determined to show that the nicotine moiety resides trans to a pyridine group, but not to the chlorido ligand. The substituents of the TPA ligands were shown to regulate the redox potential of the ruthenium center, as indicated by a linear Hammett plot in the range of 200 mV for RuIII/RuIV couples with a relatively large ρ value (+0.150). These complexes act as effective catalysts for alkane functionalization in acetonitrile with m‐chloroperbenzoic acid (mCPBA) as terminal oxidant at room temperature. They exhibited fairly good reactivity for oxidation of cyclohexane (CH bond energy 94 kcal mol−1), and the reactivity can be altered significantly by the electronic effects of substituents on TPA ligands in terms of initial rates and turnover numbers. Catalytic oxygenation of cyclohexane by a RuIII complex with 16O‐mCPBA in the presence of H218O gave 18O‐labeled cyclohexanol with 100 % inclusion of the 18O atom from the water molecule. Resonance Raman spectra under catalytic conditions without the substrate indicate formation of a RuIVO intermediate with lower bonding energy. Kinetic isotope effects (KIEs) in the oxidation of cyclohexane suggest that hydrogen abstraction is the rate‐determining step and the KIE values depend on the substituents of the TPA ligands. Thus, the reaction mechanism of catalytic cyclohexane oxygenation depends on the electronic effects of the ligands.
ChemInform Abstract: Preparation of New Nitrogen‐Bridged Heterocycles. Part 24. Syntheses and Reactions of Pyrazolo(1,5‐a)pyridine‐2‐thiols. Part 2.
Authors: KAKEHI A. , ITO S. , SAKURAI T. , URUSHIDO K. , ISAWA H. , TAKASHIMA T. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Trimethylsilylation of Propargyl Chloride and Propargyl Bromide.
Authors: VERKRUIJSSE H. D. , BRANDSMA L. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Photochemical Reactions of p‐Mentha‐1,3,8‐triene and Structural Related p‐Menthadienes.
Authors: SPRAUL M. H. , NITZ S. , DRAWERT F. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Effect of Hydroxyoxime Structure Upon Metal‐Complexing Properties
Authors: BOROWIAK‐RESTERNA A. , SZYMANOWSKI J. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Chemical and Photochemical Reactions Proceeding in the Atmosphere
Authors: PROUSEK J. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Photochemical Reactions of 1,1‐Diphenylpolycyanocyclopropanes in the Presence of Amines. Formal Extrusion of Dicyanomethylene.
Authors: TOMIOKA H. , KANDA M. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Fragmentation of Substituted Acetophenone and Halobenzophenone Ketyls. Calibration of a Mechanistic Probe.
Authors: TANNER D. D. , CHEN J. J. , CHEN L. , LUELO C. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: N‐Iodosuccinimide‐Mediated Oxidative Cleavage of Vicinal, Monoprotected Diols.
Authors: MCDONALD C. E. , HOLCOMB H. , LEATHERS T. , AMPADU‐NYARKO F. , FROMMER J. JUN. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Fused Heterocycles. Part 6. Reactions of 3‐Arylidenechromanones and ‐1‐ thiochromanones with Thiourea.
Authors: LEVAI A. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Ab initio Theoretical Study of Small GaAs Clusters
Authors: GRAVES R. M. , SCUSERIA G. E. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Cadmium Chloride Mediated Regiocontrol of Dienolates and Ketene Thioacetals: γ Condensation with Aldehydes.
Authors: LEI B. , FALLIS A. G. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Radical Cyclization of Some 1,2,6‐Trideoxy‐3,4‐di‐O‐benzyl‐6‐halogeno‐ L‐arabino‐hex‐1‐ynitol Derivatives.
Authors: ROCHIGNEUX I. , FONTANEL M.‐L. , MALANDA J.‐C. , DOUTHEAU A. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Silaamidide Salts: Synthesis, Structure, and Reactions.
Authors: UNDERINER G. E. , TAN R. P. , POWELL D. R. , WEST R. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Transition Metal Complexes. A New Class of Catalysts for the Asymmetric Synthesis of α‐Amino Acids by Phase‐Transfer Alkylation.
Authors: BELOKON' YU. N. , MALEEV V. I. , VIDENSKAYA S. O. , SAPOROVSKAYA M. B. , TSYRYAPKIN V. A. , BELIKOV V. M. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Triterpenoid Glycosides from the Northeastern Pacific Marine Sponge Xestospongia vanilla.
Authors: MORRIS S. A. , NORTHCOTE P. T. , ANDERSEN R. J. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Synthesis of Pheromones. Part 8. Improved Synthesis of 2,4‐Hexadienoic Acid.
Authors: VINCZER P. , NOVAK L. , SZANTAY C. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: 1,2,3‐Triborolanes from Norbornene Derivatives, Allylbenzene and Dehalogenation Products of Dichloro(diisopropylamino)borane; 2,4,5‐ Tris(diisopropylamino)‐2,4,5‐triborabicyclo(1.1.1)pentane ‐ Bicyclus or Carborane?
Authors: BROMM D. , SEEBOLD U. , NOLTEMEYER M. , MELLER A. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: A New and Convenient Process for Separation of Carbon Monoxide.
Authors: SONODA N. , MIYOSHI N. , TSUNOI S. , OGAWA A. , KAMBE N. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Synthesis of Nickel Cobaltite Spinel from Coprecipitated Nickel‐Cobalt Hydroxide Carbonate.
Authors: KLISSURSKI D. G. , UZUNOVA E. L. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Free Radical Cyclizations Leading to Four‐Membered Rings. Part 1. . beta.‐Lactam Production Using Tributyltin Hydride.
Authors: FREMONT S. L. , BELLETIRE J. L. , HO D. M. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Reductive Cleavage of the Carbon‐Phosphorus Bond with Alkali Metals. Part 1. Cleavage of Functionalized Triphenylphosphines: Formation of Secondary and Primary Phosphines.
Authors: BUDZELAAR P. H. M. , VAN DOORN J. A. , MEIJBOOM N. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Preparation of Oligonucleotides Containing dAICA Using an Unexpected Side‐Reaction Observed on a Protected Derivative of 2‐Aza‐2′‐ deoxyinosine.
Authors: FERNANDEZ‐FORNER D. , ERITJA R. , BARDELLA F. , RUIZ‐PEREZ C. , SOLANS X. , GIRALT E. , PEDROSO E. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: NMR Spectroscopy
Authors: MANN B. E. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Repassivation of Rapidly Solidified Magnesium‐Aluminum Alloys.
Authors: MAKAR G. L. , KRUGER J. , SIERADZKI K. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: A New Synthesis of (S)‐β‐Methyl‐γ‐butyrolactone and (S)‐4‐ Benzyloxy‐3‐methylbutanoic Acid.
Authors: BERENS U. , SCHARF H.‐D. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Enzyme‐Catalyzed Hydrolyses of Some Meso‐Diesters.
Authors: COTTERILL I. C. , COX P. B. , DRAKE A. F. , LE GRAND D. M. , HUTCHINSON E. J. , LATOUCHE R. , PETTMAN R. B. , PRYCE R. J. , ROBERTS S. M. , RYBACK G. , SIK V. , WILLIAMS J. O. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Reaction of Thioketones with Carbonyl Oxides and 3,3‐Dimethyl‐1,2‐ dioxirane. (3 + 2) Cycloaddition vs. Oxygen Atom Transfer.
Authors: TABUCHI T. , NOJIMA M. , KUSABAYASHI S. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: A Metal Catalyzed Route to Benzimidazoles Containing a Fused Alicyclic Ring.
Authors: ANASTASIOU D. , CHAOUK H. , JACKSON W. R. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: An Efficient Procedure for the 1‐Alkylation of 2‐Nitroimidazoles and the Synthesis of a Probe for Hypoxia in Solid Tumors.
Authors: LONG A. , PARRICK J. , HODGKISS R. J. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: New π‐Electron Donors for Organic Metals: Synthesis of Substituted Tetrathiafulvalenes with Eight‐ and Nine‐Membered Dithiaheterocycles: Crystal Structure of 5,6,7,8‐Tetrahydro‐1,3‐dithiolo(4,5‐b)(1,4) dithiocine‐2‐thione.
Authors: KUMAR S. K. , SINGH H. B. , JASINSKI J. P. , PAIGHT E. S. , BUTCHER R. J. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: C‐Phosphorylation of Enolates: An Alternate Route to Complex Carbonylactivated Phosphonates.
Authors: BOECKMAN JUN R. , KAMENECKA T. , NELSON S. G. , PRUITT J. R. , BARTA T. E. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: A Moessbauer Study of Microcrystalline YFe10V2.
Authors: CADOGAN J. M. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Preparation and Properties of 1‐Thia‐6‐azacyclodeca‐3,8‐diynes.
Authors: GLEITER R. , RITTER J. , IRNGARTINGER H. , LICHTENTHAELER J. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Regioselective Alkylation of 1‐Silyl‐2‐methylallyl Carbanions.
Authors: LI T. H. , WANG D. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Reactions on Transition Metal Surfaces
Authors: FRIEND C. M. , XU X. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Influence of Hydrogen on the Structure of Amorphous Sputtered Fe‐Co‐Tb Films by Means of Wide‐ and Small Angle Neutron Scattering.
Authors: HECKELE M. , BELLISSENT R. , BRUNSCH A. , LAMPARTER P. , STEEB S. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Metal Dopants in Bi‐Pb‐Ca‐Sr‐Cu‐O High‐Tc Superconductor Thick Films Prepared by Melt Solidification.
Authors: TATSUMISAGO M. , CHIGUSA H. , TOHGE N. , MINAMI T. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Phosphorescence and ESR Spectra of Substituted Triplet Benzonitriles
Authors: WAGNER P. J. , MAY M. L. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Bis(2,6‐difluorophenyl)benzoylmethyl Cation: α‐Ketocarbenium Ion as a Single‐Electron Acceptor.
Authors: KITAGAWA T. , NISHIMURA M. , TAKEUCHI K. , OKAMOTO K. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Allylic Oxidation of Unsaturated Spiroketals.
Authors: BRIMBLE M. A. , EDMONDS M. K. , WILLIAMS G. M. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Synthesis of 1‐Phenyl‐3,3‐dimethyltriazene 2‐Oxide (III) and the Corresponding Triazene (VI) from Nitro Compounds (II), (V) and N‐ Magnesium Bromides (I), (IV).
Authors: APASOV E. T. , DZHETIGENOV B. A. , KALININ A. B. , TARTAKOVSKII V. A. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Bond‐Switch Rearrangement of 3‐Oxo‐δ4‐1,2,4‐thiadiazolin‐5‐yl Ureas.
Authors: L'ABBE G. , ALBRECHT E. , TOPPET S. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.