bluuebunny/crossref_metadata_2025_split huggingface dataset:
Kornerupine breakdown reactions in paragneisses from southern Madagascar
Authors: Ackermand Dietrich , Windley Brian F. , Razafiniparany Andriantefison H. 
Published: December 2006

AbstractKornerupine-rich layers up to several centimetres thick with minor sillimanite, spinel, Fe oxide and ilmenite occur in a diopsidite in sillimanite-cordierite gneiss south of Beraketa (24°27′S, 46°48′E), southern Madagascar. Kornerupine, sillimanite, spinel and hematite grains up to 1 mm across have mutual polygonal boundaries indicating textural equilibrium at their crystallisation. Kornerupine has XMg 0.67–0.80 and 0.9 to 2.6 wt.% B2O3. Sillimanite contains up to 2.0 wt.% Fe2O3. Spinel is essentially (Mg,Fe2+) Al2O4 with an XMg range of 0.29–0.40 and exsolution lamellae of Fe oxide. Textural relations demonstrate two limited reactions, each confined to areas less than 500 µm across: (1) Kornerupine and spinel reacted along grain contacts to form very fine-grained tourmaline, corundum and chlorite. The replacing phases are symmetrically zoned with a central tourmaline and hematite, bordered by an aggregate of chlorite, tourmaline and corundum, followed outwards by a rim of chlorite against the kornerupine and spinel. (2) Within kornerupine grains, zoned, round aggregates consist of very fine-grained chlorite, tourmaline and corundum of different composition than in (1). They define the terminal reaction of kornerupine breakdown.Geothermobarometry indicates that the early kornerupine-bearing assemblage was stable at 7.0 kbar and 700 °C. This P-T point lies close to the retrograde, nearly isothermal trajectory defined independently by nearby sapphirine-bearing assemblages. The fine-grained aggregates formed most likely during further cooling, or by increasing water fugacity.
Barstowite, 3PbCl2.PbCO3.H2O, a new mineral from Bounds Cliff, St Endellion, Cornwall
Authors: Stanley C. J. , Jones G. C. , Hart A. D. , Keller P. , Lloyd D. 
Published: December 2006

AbstractBarstowite, ideally 3PbCl2.PbCO3.H2O is a new mineral from a lead-antimony vein at the south-western end of Bounds Cliff, St Endellion, Cornwall. It occurs as very small (0.2–0.5 mm) subparallel elongate intergrown crystals which form aggregates (up to 3 mm) containing minor inclusions of galena and jamesonite. Other associated minerals are quartz, dolomite, phosgenite, cerussite, sphalerite, pyrite and chalcopyrite. Barstowite is colourless to white and is transparent with an adamantine lustre and white streak. It is brittle, has an imperfect prismatic cleavage, and an uneven fracture. Low reflecting, barstowite has a moderate bireflectance from grey to dark grey in hue and weak to moderate anisotropy. Internal reflections (colourless) are abundant. Measured reflectance values in air and oil are tabulated. Colour values relative to the CIE illuminant C for R1 and R2 in air respectively are: Y% 12.9, 13.3; λd 477, 476; Pe% 3.5, 3.7. VHN100 111 (range 108–117); calculated Mohs hardness is 3. Infrared spectra of barstowite, phosgenite and cerussite are compared.X-ray studies show that barstowite is monoclinic with space group P21/m and a 4.218(2), b 9.180(2), c 16.673(4) Å, β 91.49(3)°. It has a cell volume of 645.38 Å3 with Z = 2. Dcalc. is 5.76 g/cm3, Dmeas. is 5.71 g/cm3. The strongest six lines of the X-ray powder pattern are [d in Å (I) (hkl)] 4.02 (10) (022); 2.296(8) (040; ; 106); 2.377(6) (007; 026); 4.16(5) (004); 2.108(4) (200); 3.79(3) (014). The name is for the late Richard William Barstow, the Cornish mineral dealer.
Coexisting glasses occurring as inclusions in leucite from lamproites: examples of silicate liquid immiscibility in ultrapotassic magmas
Authors: Mitchell Roger H. 
Published: December 2006

AbstractInclusions occurring in leucites from the Oscar and Zirkel Mesa leucite lamproites consist of high (>10 wt.%) and low (<4 wt.%) K2O discrete glass phases which are interpreted to have resulted from silicate liquid immiscibility. Both glasses are quartz-normative and rich in Ti, Fe, Mg, Ca and Ba and poor in Al. The high-K glass is strongly peralkaline. Neither of the glasses have compositions representative of any known lamproites. These inclusions represent the first described examples of silicate-silicate immiscibility shown by glass in alkaline rocks.
The geochemistry and tectonic setting of the Demirköy pluton of the Srednogorie–Istranca granitoid chain, NW Turkey
Authors: Aykol A. , Tokel S. 
Published: December 2006

AbstractThe chain of Late Subhercynian granitoids can be traced along the Srednogorie-Istranca-Pontid belt. The Demirköy pluton outcrops in the Istranca segment. The rocks of the pluton range from diorite through grandiorite to perthite granite with granodiorite predominating. On the basis of 25 chemical analyses, the intrusive setting of the granitoid has been investigated. Calcic to calc-alkaline and peraluminous to metaluminous character indicate a subduction-related origin. Low to moderate concentrations of the large-ion lithophiles (LIL), high field strength elements (HFS), light rare earth elements (La, Ce) and low HFS/LIL ratios indicate a mantle-derived magma with subduction-related enrichment. Trace element discrimination diagrams such as Rb/Zr-Nb, Rb/Zr-Y, Rb-SiO2 and Rb-(Nb + Y), are particularly indicative of normal arc-setting for the samples.The Demirköy granitoid is chemically indistinguishable from the Upper Cretaceous granitoids of Strednogorie to the west and the Pontids to the east. This extensive maximum of plutonism can be considered as a time marker in the northern Tethys subduction system.
Oscillatory zoning in metamorphic minerals: an indicator of infiltration metasomatism
Authors: Yardley B. W. D. , Rochelle C. A. , Barnicoat A. C. , Lloyd G. E. 
Published: December 2006

AbstractExamples of oscillatory zoning in metamorphic minerals, imaged using a Back-Scattered Electron Detector on the SEM, are described from a series of contrasting environments. These are a prehnite vein sampled by drilling in the Mirvalles geothermal field, Costa Rica, a pyroxene vein developed in a regional metamorphic shear zone in the Yilgarn block, Western Australia, and a bedded metasomatic diopside rock from regionally metamorphosed metasediments in Connemara, Ireland. In each case the formation of oscillatory zoning can be ascribed to mineral growth under supersaturated conditions due to fluid infiltration. Oscillations can be related in the first example to periodic episodes of pressure release and boiling in the geothermal field, but in the regional metamorphic examples actualistic models are harder to define. The development of oscillatory zoning is likely to be a characteristic feature of infiltration metasomatism and can be used as a criterion in the recognition of metasomatic mineral growth in metamorphic rocks outside the vein environment.
Porphyroblast textural sector-zoning and matrix displacement
Authors: Rice A. H. N. , Mitchell J. I. 
Published: December 2006

AbstractThere is an association between the development of cleavage domes, a texture reflecting the displacement of insoluble matrix grains by porphyroblasts growing under a bulk hydrostatic stress, and textural sector-zoning. This has been found in garnet, staurolite, chiastolite, pyrite and possibly emerald porphyroblasts. Sector-zoned porphyroblasts form by lineage growth normal to the crystal faces. This causes several distinctive textures (type 1 inclusions and type 2 intergrowths, inclusion bands, growth prongs), all of which are directly or indirectly related to displacement growth. Graphite or other carbonaceous material is ubiquitous in samples showing textural sector-zoning.
Modification of antiphase domain sizes in omphacite by dislocation glide and creep mechanisms and its petrological consequences
Authors: van Roermund H. L. M. , Lardeaux J. M. 
Published: December 2006

AbstractA T.E.M. study of omphacites from the western Italian Alps (Sesia Lanzo Zone and Monviso eclogites) has revealed a bimodal size distribution of antiphase domains: (a) 250–350 Å, (b) ≥ 2500 Å. In addition observed dislocation substructures and ‘large-scale’ antiphase domains are intimately interconnected.A model is presented that can explain modification of the antiphase domain sizes by the interplay of cooling/growth and dislocation glide and/or creep mechanisms. Subsequent coarsening of the modified antiphase domains is inferred to be the result of surface free-energy processes. The model clearly illustrates that only the ‘relatively undeformed’ areas containing the small-scale antiphase domains can be used for thermometric methods.
Banded sphalerite from the North Pennine Orefield
Authors: More A. P. , Vaughan D. J. , Ashworth J. R. 
Published: December 2006

AbstractOptical microscopy of doubly polished thin sections of North Pennine sphalerite has revealed a range of previously unrecognised textures for the Alston Block mineralisation. Delicate growth zoning, interrupted by numerous solution disconformities, was seen in transmitted light. Two principal varieties of growth-banded sphalerite are recognised; the earlier (Type 1) is characterised by the development of thin opaque bands. Type 2 has colour bands between yellow and brown, correlated with iron content. In Type 1, iron levels (up to 3 wt.%) are not sufficient to account for the observed opacity. Ultra-violet and infra-red techniques failed to detect any organic inclusions. Electron microscopy revealed locally high concentrations of sub-micrometre inclusions, both beam-stable and beam-unstable, and a variety of growth-related crystal defects.Fluid inclusion thermometry in both sphalerite varieties and the accompanying quartz gangue implies a saline mineralising fluid (20–25 wt.% equiv. NaCl) at a relatively low temperature (100° to 140°C). Tubular inclusions are conspicuous. A deformation-induced lamelliform optical anisotropy is superimposed on a growth-related grid-iron anisotropy. Growth band offset is apparent where the deformation fabric cross-cuts the growth banding. Deformation on {111} twin and slip planes was indicated by electron microscopy.
The ore textures of the Neves-Corvo volcanogenic massive sulphides and their implications for ore beneficiation
Authors: Gaspar O. , Pinto A. 
Published: December 2006

AbstractThe Neves-Corvo mine opened officially in December 1988 and it is already the biggest producer of copper in the Iberian Pyrite Belt (IPB). Tin production started in 1990. The ore deposits of the IPB are related to felsic submarine volcanism which developed during the lower Tournaisian to the middle Visean. At the end of the first phase of Hercynian deformation in the middle Westphalian, the ore deposits were affected by low-pressure metamorphism producing schistosity and prehenite-pumpellyite greenschist facies assemblages in the volcanogenic sediments of the IPB.The unique nature of the mineralogy of the Neves-Corvo deposit compared with other IPB deposits is mainly a result of the introduction of later Cu-rich hydrothermal solutions to the primitive ore pile and the presence of tin mineralisation. The cupriferous ores are rich in tetrahedrite-tennantite, stannite, kesterite, stannoidite and mawsonite.Cassiterite occurs in Neves-Corvo: (a) as thin layers of euhedral crystals in cupriferous ores, partially replaced by chalcopyrite; (b) in the schistosity of a banded black shale chalcopyrite hanging wall formation; (c) as metre-sized lenses of massive cassiterite overlying the cupriferous ores.The ore textures at Neves-Corvo are complex, due to intergrowths of fine colloform pyrite with the base metal minerals. Because of the low grade of metamorphism, colloform, geopetal and soft-sediment diagenetic features are preserved in the ‘complex ores’. These ‘complex ores’ have contents of 0.5% Cu, 1% Pb and 5.5% Zn. In copper-rich ores (7.9% Cu and 1.4% Zn), replacement of the primary ore by chalcopyrite has obliterated most of these textures and produced fine chalcopyrite-tetrahedrite-pyrite intergrowths. The textures clearly indicate the genesis of these ores but they impose a practical problem in recovery of the metals. There is no clear correlation between these textures and the ore classification used at the mine, but an understanding of the textures is vital since the ‘complex ores’ require fine grinding to achieve liberation and the fine grinding adversely affects the froth flotation processing of the ore.The implications of the complex sulphide textures for ore beneficiation have been studied using reflected light microscopy, with determination of modal analyses and grain-size distributions of free particles and middlings from concentrates and tailings.The outcome of a one-year intensive study is that the ore microscopy laboratory at the mine now produces daily information about the textures of the feed ores so that metallurgical engineers can optimise the performance of the ore dressing plant.
Mineralogical and textural evolution of the economic manganese mineralisation in western Rhodope massif, N. Greece
Authors: Nimfopoulos M. K. , Pattrick R. A. D. 
Published: December 2006

AbstractThe western Rhodope massif contains a significant number of ‘battery grade’ Mn-oxide deposits which are best developed in the area near Kato Nevrokopi, Drama district, N. Greece. Economic Mn-oxide ore concentrations are confined to fault zones and related karsts in marbles. The mineralisation has formed by weathering of hydrothermal veins that were genetically related to Oligocene magmatism.At Kato Nevrokopi, progressive and continuous weathering of primary, hydrothermal veins of rhodochrosite, mixed sulphide, quartz and ‘black calcite’ (calcite and todorokite) has resulted in the formation of the assemblage MnO-gel-(amorphous Mn-oxide)-todorokite-azurite-goethite-cerussite in the veins and the assemblage MnO-gel-nsutite-chalcophanite-birnessite-cryptomelane-pyrolusite and malachite and amorphous Fe-oxides in karstic cavities.The fs2 and fO2 of the hydrothermal fluids increased with time. The breakdown of the hypogene Mn-carbonate was aided by the production of an acidic fluid due to the oxidation of sulphides. Precipitation of the supergene ores was caused by neutralisation of the fluids due to reaction with the host marble and to mixing of relatively reduced fluids with oxygenated surface water in a fluctuation water table regime. Zinc was also mobile during weathering and became concentrated in the intermediate Mn-oxides, effectively stabilising their structures. The mineral paragenesis records the progressive oxidation of the ore and the appearance of less hydrated Mn-oxides, low in alkalis and alkaline earths.
Textural evolution of W-Cu-Sn-bearing hydrothermal veins at Minas da Panasqueira, Portugal
Authors: Foxford K. A. , Nicholson R. , Polya D. A. 
Published: December 2006

AbstractCombined structural and textural studies of the quartz veins of the Panasqueira W-Cu-Sn deposit of central Portugal have revealed the presence of coeval forms of crack-seal and cavity-fill mineral textures. The textures result from the dilational and infilling histories of brittle fractures produced within the host rock by the intrusion of pressurised fluids. Crack-seal textures were produced wherever or whenever crystal growth rates matched or were greater than fracture dilation rates, whereas cavity-fill textures developed wherever or whenever dilation rates were quicker than those of crystal growth. Rates of dilation within the blade-like fissures were naturally lowest at the edges, where types of crack-seal textures were produced, and highest in the cores, where cavity-fill texture formed. During propagation the linkage of adjacent echelon blades, by the rupture of the host-rock straps (bridges) between them, enhanced dilation rates and led to the widespread development of cavity-fill textures. Within the composite fissures so produced, environments in which types of crack-seal textures could form were restricted to the fissure margins and to areas where the tensile strain was sympathetically shared between closely spaced fissures. Textures and minerals characteristic of each fracture environment were able to form simultaneously within the fracture system.
Cathodoluminescence and growth of cassiterite in the composite lodes at South Crofty Mine, Cornwall, England
Authors: Farmer C. B. , Searl A. , Halls C. 
Published: December 2006

AbstractThe cathodoluminescence (CL) of cassiterite (SnO2) from the paragenetic sequence in the lodes at South Crofty Mines has been used in the interpretation of the processes which govern mineral deposition. Luminescence is controlled by the substitution of Ti, Fe and W for Sn in the cassiterite lattice. Ti and W behave as luminescence activators whereas Fe quenches luminescence. The observed colours and intensity of the luminescence are believed to result from the interplay between these effects. Successive generations of cassiterite formed during the separate stages of paragenetic evolution show different luminescence colours. These are believed to reflect changes in bulk composition of the fluid, which is indicated by the systematic variation in the composition of tourmaline in the associated gangue.CL also reveals details of growth and deformation in individual crystals. Growth textures observed in CL are broad concentric growth banding, oscillatory zoning and sector zoning. Sector boundaries often show a zig-zag form which is indicative of competitive growth of adjacent crystal faces. Interpretation of CL textures is used to support the hypothesis that cassiterite growth took place under two main regimes. These are, firstly, conditions in which fluid pressure decreased abruptly when tectonic reactivation caused dilation of parts of the lode fracture system and secondly, conditions of sustained hydraulic pressure within fractured vein fill. In tectonically induced fractures the crystals are stubby, have non-equivalent growth faces and are commonly tetragonal bipyramidal forms in which sector zoning is invariably present. In hydraulic fractures crystals take a predominantly tetragonal prismatic form. Thus, it is believed that growth under these contrasting conditions leads to distinctive morphology and zoning in cassiterite, providing a basis for typomorphic characterisation.
Conversion of nepheline to sodalite during subsolidus processes in alkaline rocks
Authors: Finch Adrian A. 
Published: December 2006

AbstractCathodoluminescence (CL) petrography of nepheline syenites of the Igaliko complex, Gardar province, South Greenland shows that sodalites possess embayed contacts against nepheline, and have formed by a process of metasomatic replacement. This texture is demonstrated clearly by CL, since sodalite luminesces bright orange and nepheline is poorly luminescent. The transformation from nepheline to sodalite results in a volume change which leads to a network of fractures in which deep-blue luminescent fluorite is precipitated. Fluorite is formed since the chlorination process involved in the transformation causes localised reductions of the salinity of the fluid and therefore a decrease in the solubility of fluorite. Sodalite-fluorite textures observed using CL allow sodalites of secondary origin in alkaline igneous rocks to be identified.Nephelines and sodalites, when observed using scanning electron microscopy, possess small micropores. By analogy with recent work on alkali feldspars, pervasive alteration of nephelines may occur by fluid flow assisted by a permeable micropore network.
Vanadian allanite-(La) and Vanadian allanite-(Ce) from the Hemlo gold deposit, Ontario, Canada
Authors: Pan Yuanming , Fleet Michael E. 
Published: December 2006

AbstractAllanite-(La) (containing up to 7.80 wt.% V2O3 and with La/ΣREE and La/Ce atomic ratios up to 0.54 and 1.45, respectively) and allanite-(Ce) (up to 8.46 wt.% V2O3) occur in close association with vanadian muscovite, barian tomichite and vanadian titanite in the main ore zone of the Hemlo gold deposit, Ontario, Canada. Allanite-(Ce) generally occurs as a minor constituent in cross-cutting veins or along foliation planes, whereas allanite-(La) invariably occurs in direct contact with titanite. The high V concentrations in the allanites from Hemlo are readily attributable to an adequate local source of this element, and are most likely controlled mainly by a simple substitution of V for Al in octahedral coordination. Vanadian allanite-(La) and vanadian allanite-(Ce), without any systematic differences in other constituents, are clearly distinct in REE composition, in respect to both the relative concentrations of La and Ce and abundances of other REE. The formation of both allanites (Ce- and La-rich) indicates very localised remobilisation and concentration of REE during a late hydrothermal alteration. The unusual REE composition of vanadian allanite-(La) directly reflects partitioning of REE with coexisting titanite, and the formation of this unusual phase may be attributable to replacement of earlier titanite with redistribution of REE in the solid state.
On the poikilitic nature of Jabal Al Hasawinah eudialyte
Authors: Oun Khaled M. 
Published: December 2006

AbstractPoikilitic eudialyte outcrops in a strongly peralkaline phonolithic cumulo-dome in Jabal Al Hasawinah, Libya. Textural relationships reveal that the eudialyte has formed at a very late stage of the rock petrogenesis. Electron microprobe analyses confirm its volatile (hydrous) nature and low REE content.
Mg-rich dumortierite in cordierite-orthoamphibole-bearing rocks from the high-grade Bamble Sector, south Norway
Authors: Visser Diederik , Senior Antony 
Published: December 2006

AbstractDumortierite is described from several occurrences of cordierite-orthoamphibole-bearing rocks in the upper-amphibolite facies area of the Bamble Sector, south Norway. Dumortierite occurs with chlorite, muscovite and quartz in late M4 alteration zones or aggregates after M3, peak-metamorphic cordierite and garnet and early M4 vein-cordierite, and intergrown with or replacing orthoamphibole. Late M4P-T conditions, which are interpreted as conditions of dumortierite formation, are estimated from the associated late M4 kyanite-andalusite-chlorite-quartz assemblage and Mg-Fe exchange geothermometry to be 500 ± 50 °C and 3–4 kbar. Retrogression of M3 mineral assemblages is initiated by influx of fluids with XCO2 of 0.3–0.4 during early M4 followed by more water-rich fluids during late M4. Late M4 fluids may show local variations in alkalis and boron. The dumortierites are the most Mg-rich (2.23–3.42 wt. % MgO) ever reported, and contain 0.00–2.05 wt.% TiO2, 0.00–1.08 wt.% Fe2O3, 29.62–32.42 wt.% SiO2 and 55.20–59.71 wt.% Al2O3. Al is the most likely substituent for Si, which shows a minor deficiency at the tetrahedral sites in most dumortierites. The major variations in the mineral chemistry can be described by the coupled substitutions Mg + Ti = 2AlVI, 3Mg = 2AlVI and possibly Mg + H = AlVI. Favoured by low ƒO2 prevailing conditions a significant part of total iron in dumortierites at one locality is present as Fe2+ giving evidence for the Fe2+ + SiIV = AlIV + AlVI tschermakite substitution. FeMg−1 substitution is considered to be limited. Ti-rich dumortierites coexist with rutile, ilmenite or titaniferous magnetite. The development of dumortierite from orthoamphibole correlates with an observed decrease of Al, Mg and Na and increase of Si and Fe in orthoamphibole towards dumortierite.
A new method for measuring the crystallinity index of quartz by infrared spectroscopy
Authors: Shoval S. , Ginott Y. , Nathan Y. 
Published: December 2006

AbstractA new method for measuring the crystallinity index of quartz is presented. It is based on the measurement of the intensity of the first derivative of the infrared absorption spectrum at the shoulder at c. 1145 cm−1. The results correlate well with X-ray and D.T.A. crystallinity measurements.