bluuebunny/crossref_metadata_2025_split huggingface dataset:
Synthesis, Structure and Hydrolysis Studies of Dimethyltris(Trimethylsilyl)Methylmetallanes of Aluminium and Gallium
Authors: Schnitter Christoph , Roesky Herbert W. , Albers Thomas , Schmidt Hans‐Georg , Röpken Cord , Parisini Emilio , Sheldrick George M. 
Published: July 2007

AbstractThe reactions of [(Me3Si)3CLi2thf] with Me2MCl (M = Al, Ga) afford the mixed trialkylmetallanes [(Me3Si)3‐CAlMe2·thf] (1) and [(Me3Si)3 CGaMe2·thf] (2) in high yields. The coordinated THF molecule of compound 2 can be removed by sublimation in vacuo to yield the solvent‐free product [(Me3Si)3‐CGaMe2] (3). Hydrolysis of compound 2 with one equivalent of water at 0°C gives the trimeric hydroxide [{(Me3Si)3CGaMe(μ‐OH)}3] (4), while the reaction with two equivalents of water at room temperature yields the unusually stable gallium hydroxide‐water complex [{(Me3Si)3CGaMe(OH)(μ‐OH)MeGaC(SiMe3)3) H2O·2thf] (6). On heating, compound 6 is converted to the hydroxide [{(Me3Si)3C}4Ga4(μ‐O)2(μ ‐OH)4] (5), which has a heteroadamantane‐like core. The hydrolysis of compound 1 with one equivalent of water at − 25°C gives the dimeric hydroxide [{(Me3Si)3CAlMe(μ‐OH)}2·2thf] (7), while the reaction with two equivalents of water results in the formation of the novel hydroxide [{(Me3Si)3C}4Al4(μ‐O)2 (μ‐OH)4] (8), which is isostructural to the gallium compound 6 with the adamantane‐like structure. The molecular structures of compounds 1, 2, 4, 5·3THF, 6, 7 and 8·0.5 THF have been determined by X‐ray structure analysis. Compound 7 is the first structurally characterised aluminium hydroxide containing methyl groups, and 8 is the smallest structurally characterised galloxane hydroxide described in literature.
Asymmetric Addition Reactions with Optimized Selenium Electrophiles
Authors: Wirth Thomas , Fragale Gianfranco 
Published: July 2007

AbstractThe synthesis of various nonracemic diselenides by different methods is described. These diselenides are precursors for optically active selenium electrophiles. Their facial selectivity upon addition to styrene was investigated with respect to the chiral moiety neighboring the selenium. Diselenides 1 i, 1 n, and 1 v yielded addition products 7 with diastereomeric excesses up to 95%. Some diselenides, intermediates, and products of the addition reaction were investigated by 77Se NMR spectroscopy.
The First Examples of Enantiomerically Pure Diphosphane Dioxides—(RP,RP)‐ and (SP,SP)‐1,2‐Di‐ter‐butyl‐1,2‐diphenyldiphosphane 1,2‐Dioxides, and (RP)‐ and (SP)‐1‐tert‐Butyl‐1,2,2‐triphenyldiphosphane 1,2‐Dioxides
Authors: Haynes Richard K. , Lam William Wai‐Lun , Williams Ian D. , Yeung Lam‐Lung 
Published: July 2007

AbstractWhereas oxidative dimerization of each of the lithiated reagents (RP)‐ and (SP)‐tert‐butylphenylphosphane oxides 1 Li and 2 Li by means of oxygen in THF at low temperature led cleanly to meso‐1,2‐di‐tert‐butyl‐1,2‐diphenyldiphosphane dioxide (3), the respective nucleophilic substitution reactions of 1 Li and 2 Li with the (RP)‐ and (SP)‐tert‐butylphenylphosphinic bromides (4 and 6) in THF under argon led to the corresponding (SP,SP)‐ and (RP,RP)‐12‐di‐tert‐butyl‐1,2‐diphenyldiphosphane dioxides (5 and 7) in good yields, together with the meso‐diphosphane dioxide 3. The structures of 3 and 5 were established by X‐ray crystallography. Similarly, the reaction of lithiated (RP)‐phosphane oxide 1 Li with diphenylphosphinic bromide (8) or of achiral lithiated diphenylphosphane oxide 10 Li with (RP)‐tert‐butylphenylphosphinic bromide (4) provided (SP)‐tert‐butyltriphenyldiphosphane dioxide (9).
1H NMR Spectroscopic Studies of the Conformational Isomers of Pyrrolidinofullerenes
Authors: Lukoyanova Olena , Kitaygorodskiy Alex , Cardona Claudia M. , Echegoyen Luis 
Published: July 2007

AbstractMixed bis‐adduct derivatives of C60 containing a pyrrolidine and a malonate methano group were synthesized. Three regioisomers, the e′, the trans‐2, and the trans‐3, were isolated and characterized. In‐depth NMR studies of these methano‐pyrrolidinofullerenes showed that the nitrogen inversion on the pyrrolidine moiety is not a fast event in the 1H NMR time scale as previously regarded. Solvent effects, variable temperature experiments, and protonation of the pyrrolidine nitrogen are addressed.
ChemInform Abstract: Structure of Trithiatriazines
Authors: JAUDAS‐PREZEL E. , MAGGIULLI R. , MEWS R. , OBERHAMMER H. , STOHRER W.‐D. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Structure of Lithium Heptaborate, Li3B7O12.
Authors: JIANG A. , LEI S. , HUANG Q. , CHEN T. , KE D. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Crystal Chemistry of cyclo‐Hexaphosphates. Part 12. Structure of Ammonium Calcium cyclo‐Hexaphosphate Hexahydrate.
Authors: AVERBUCH‐POUCHOT M. T. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Thermochemistry of the Gaseous Thorium Bromides.
Authors: HILDENBRAND D. L. , LAU K. H. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Formation and Stability of Gaseous BSe2.
Authors: BINNEWIES M. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Preparation and Properties of the Novel Monoamidotrihydroxycyclotrinitridosulfodiphosphate Anion.
Authors: ROZANOV I. A. , MEDVEDEVA L. YA. , GOEVA L. V. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Electronic Spectroscopy and Structure of 3‐Amino‐s‐tetrazine in a Supersonic Jet.
Authors: ALFANO J. C. , MARTINEZ S. J. III , YANG D. D. , LEVY D. H. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Pressure‐Induced Enhancement of the Ferromagnetic Intermolecular Interaction of an α‐Nitronyl Nitroxide Organic Radical.
Authors: AWAGA K. , MARUYAMA Y. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Structures of (2R,4S,5R)‐3,4‐Dimethyl‐2,5‐diphenyl‐1,3,2‐ oxazaphospholidine(P‐B)borane (I) and of (2R,5S)‐5‐Methyl‐2,4,4‐ triphenyl‐1,3,2‐dioxaphospholane(P‐B)borane (II).
Authors: JUGE S. , STEPHAN M. , GENET J. P. , HALUT‐DESPORTES S. , JEANNIN S. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: (S)‐N‐(5,6,7,10‐Tetrahydro‐1,2,3‐trimethoxy‐11‐methylthio‐10‐oxobenzo( a)heptalen‐7‐yl)acetamide (Pseudothiocolchicine).
Authors: PILATI T. , BIANCHI R. , CASALONE G. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Structure of 2,3‐Dimethylquinoxaline
Authors: WOZNIAK K. , KRYGOWSKI T. M. , KARIUKI B. , JONES W. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Catalysis of α‐Fe and Fe1‐xS Toward the Hydrogenolysis of trans‐ Stilbene in Hydroaromatic Hydrocarbon Solvents.
Authors: FUTAMURA S. , FUJIMOTO K. , KAMIYA Y. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Formation of Novel Unsaturated Side Chain Penicillins with Isopenicillin N Synthase.
Authors: BALDWIN J. E. , BRADLEY M. , ABBOTT S. D. , ADLINGTON R. M. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Reaction of N‐Unsubstituted Azoles with Diphenylnitrilimine.
Authors: DE LA HOZ A. , PARDO C. , SANCHEZ A. , ELGUERO J. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Condensation of 2‐Acetyl 1,3‐Cycloalkanediones with Dialkyl Acetals of N,N‐Dialkylformamides: A Simple and Convenient Method of Aminomethylenation of 2‐Acetylsubstituted Cyclic β‐Diketones.
Authors: MIKHAL'CHUK A. L. , GULYAKEVICH O. V. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: CO2 Laser Induced Decomposition of Propylene Oxide.
Authors: JAKOUBKOVA M. , POLA J. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Highly Selective Partial Oxidation of Methane to Methyl Trifluoroacetate.
Authors: VARGAFTIK M. N. , STOLAROV I. P. , MOISEEV I. I. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Reduction of Isoxazoloprostanoids by Complex Metal Hydrides.
Authors: LAKHVICH F. A. , KOROLEVA E. V. , ANTONEVICH I. P. , YANKOVA T. V. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Imination of Sulfur Compounds. Part 31. Arylsulfonylimination of 2‐Oxo‐ 1‐carboethoxypropyl Aryl Sulfides.
Authors: KOVAL' I. V. , PANASENKO T. G. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: A New Synthetic Route to 1,1,2,2‐Tetracyanocyclopropanes.
Authors: LEE J.‐Y. , HALL H. K. JUN. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Synthesis and Antiviral Activity of Adamantyloxiranes and Their Derivatives.
Authors: SHIRYAEV A. K. , MOISEEV I. K. , BOREKO E. I. , KOROBCHENKO L. V. , VLADYKO G. V. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Regioselective Ring Opening of Polycyclic Aromatic Hydrocarbon Epoxides by Polymer‐Supported N3‐ Anion.
Authors: LAKSHMAN M. , NADKARNI D. V. , LEHR R. E. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Functionalized Organolithium Reagents. Part 8. Novel (α,β‐ Epoxyalkyl)lithium Reagents via the Lithiation of Organyl‐Substituted Epoxides.
Authors: EISCH J. J. , GALLE J. E. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: β‐Keto Ester Dianions as Regiospecific Enolate Equivalents for N‐ Substituted Pyrrolidine‐3‐ones.
Authors: GILES M. , HADLEY M. S. , GALLAGHER T. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Stereocontrolled Access to all‐trans α,β,γ‐ Substituted Pyrrolidinones and Pyrrolidines of High Optical Purity from D‐Pyroglutamic Acid.
Authors: HANESSIAN S. , RATOVELOMANANA V. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Synthesis and Antimicrobial Activity of 2‐Aryl‐1,4‐dihydroisoquinolin‐ 3‐imines.
Authors: BABICHEV F. S. , PATRATII V. K. , KOVTUNENKO V. A. , PRODANCHUK N. G. , SINCHENKO N. G. , KISEL' V. M. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Synthesis of 5,6‐Diamino‐3,8‐dimethyl‐4,7‐phenanthroline.
Authors: SAVOSIN I. V. , SHABUROV V. V. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: An Efficient and Facile Synthesis of Novel 2‐Arylpyrido(2,3‐d) pyrimidin‐5(8H)‐ones.
Authors: SINGH B. , LASKOWSKI S. C. , LESHER G. Y. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Fluorinated Macrocyclic Ethers as Fluoride Ion Hosts. Novel Structures and Dynamic Properties.
Authors: FARNHAM W. B. , ROE D. C. , DIXON D. A. , CALABRESE J. C. , HARLOW R. L. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Efficient Synthesis of Crown Ester‐Linked Ruthenium Complexes. A New Class of a Supramolecular Sensitizer‐Crown Ester Assembly for Electron Transfer.
Authors: DUERR H. , KILBURG H. , BOSSMANN S. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Unexpected Reactivity of Bifunctional Hexacoordinated Silicon Species.
Authors: BRELIERE C. , CORRIU R. J. P. , ROYO G. , WONG CHI MAN W. W. C. , ZWECKER J. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Benzeneselenenyl p‐Toluenesulfonate: Preparation and Electrophilic Addition to Acetylenes.
Authors: BACK T. G. , MURALIDHARAN K. R. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Cyclotelluratd Derivatives of 2‐(3‐Thienyl)pyridine.
Authors: SINGH H. B. , SUDHA N. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Synthesis and Structure of Di‐2‐benzo(b)thienyl Ditelluride.
Authors: KUMAR S. K. , SINGH H. B. , DAS K. , SINHA U. C. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: A Novel Intramolecular Cyclization of Titanocene Vinylidene Complexes: Formation of Bicyclic Titanacyclobutanes and ‐butenes.
Authors: DENNEHY R. D. , WHITBY R. J. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Synthesis and Structural Characterization of Bimetallic μ‐Malonyl Complexes.
Authors: O'CONNOR J. M. , UHRHAMMER R. , RHEINGOLD A. L. , STALEY D. L. , CHADHA R. K. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Base‐Free Silylene Complexes ((η5‐C5Me5)(PMe3)2Ru=Si(SR)2)BPh4 (R: Et, p‐MeC6H4).
Authors: STRAUS D. A. , GRUMBINE S. D. , TILLEY T. D. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Structure of Ratibinolide, a Sesquiterpene Lactone
Authors: SORIANO‐GARCIA M. , VILLENA IRIBE R. , MATA R. , ROJAS A. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: A Facile and Enantioselective Total Synthesis of (+)‐19‐ Nordeoxycorticosterone.
Authors: NEMOTO H. , SATOH A. , ANDO M. , FUKUMOTO K. 
Published: July 2007

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.