bluuebunny/crossref_metadata_2025_split huggingface dataset:
Trace element immobilization by uranyl minerals in granite-hosted uranium ores: Evidences from the Xiazhuang ore field of Guangdong province, China
Authors: Lu Long , Chen Fanrong , Ewing Rodney C. , Wang Rucheng 
Published: January 2007

The oxidative alteration of uraninite and the fate of trace elements (Y, LREE, Zr, and Th) in a granite-hosted uranium ore deposit in north Guangdong province, China, were investigated to understand the geochemical behavior of spent UO2fuel and associated fission products and transuranium elements under oxidizing conditions. In light of the paragenetic relationship of the alteration products, two alteration series of uraninite were identified: one is the silicate series with a mineral paragenesis of uraninite → uranyl oxide hydrates → Si-rich uranyl phase → uranophane (Ca[(UO2)(SiO3OH)]2(H2O)5), and the other is the phosphate series with a mineral paragenesis of uraninite → uranyl oxide hydrates → autunite (Ca[(UO2)(PO4)]2(H2O)6) → yingjiangite ((K2,Ca)(UO2)7(PO4)4(OH)6(H2O)6). In contrast to the wide distribution and abundance of uranophane and the uranyl phosphate minerals, uranyl oxides were only occasionally found in the ore samples, suggesting that the uranyl silicates and phosphates should be the predominant alteration products of UO2under oxidizing conditions, although uranyl oxide hydrates would be the solubility-limiting phase of uranium in the very early stage of alteration. Furthermore, the interlayer cation of the uranyl phases in the Xiazhuang uranium ore field is dominated by Ca2+, indicating that the release of uranium and other radionuclides will be limited mainly by uranophane and autunite during the oxidative alteration of spent UO2fuel in underground repositories where enhanced calcium concentration is expected due to cement/water reactions.Compositionally, the cation atomic ratios in uranyl phases often deviate considerably from their respective stoichiometric values as indicated by the nominal formulae, but the compositional variation does not result in significant structural change as indicated by X-ray diffraction patterns. This observation indicates that the structure of U6+minerals may easily be adjusted to accommodate impurity elements including crystallographically compatible radionuclides. Compared with the primary uraninites, the secondary minerals are slightly enriched in light REE, but significantly depleted in Y3+probably due to its cation-radius mismatch with interlayer Ca2+. The apparent enrichment of Zr4+in uranophane and uranyl phosphates relative to uraninite may result from the coupled substitutions: Zr4+↔ U6+and REE3+↔ Ca2+(K+). Because an adequate charge-balance mechanism and significant distortion of the coordination polyhedra are required for the substitution An4+↔ U6+, this type of substitution may not be common.
A hydrochemical and isotopic case study around a near surface radioactive waste disposal
Authors: Szántó Zs. , Svingor É. , Futó I. , Palcsu L. , Molnár M. , Rinyu L. 
Published: January 2007

As part of the site characterisation program for the near surface radioactive waste treatment and disposal facility (RWTDF) at Püspökszilágy, Hungary, water quality and environmental isotope investigations have been carried out. Water samples for major ion chemistry, tritium, 14C and stable isotope ratio measurements (δ18O, δD, δ34S, δ13C) were taken quarterly from the observation wells, the streams and the precipitation during the period 1999–2001.
The chemical composition of groundwaters presented a continuous transition from waters situated on one side to waters on the top and on the other slope of the disposal suggesting the mixing of the three hydrochemical “endmembers”.
Most of δD and δ 18O data were situated between GMWL and LMWL (δD = 7.2 × δ 18O − 1‰) with Oligocene aquifer presenting recharge of Pleistocene origin and water on the top and the gentle slope of the hill presenting recharge of Holocene origin. δ 34S values of dissolved sulphates varied in a wide range (-14.2‰ to + 5.4‰). The tritium in precipitation varied between 4.4 and 18.1 TU with an annual weighted average of 10 ± 0.3 TU. The streams showed larger fluctuations than the wells, but the changes of δ 18O, δD and T were small compared to those in precipitation (showing seasonal variation). Stable isotope, tritium and radiocarbon data proved that the replenishment of groundwater is slow on the steeper side and the direction of water movement is toward the gentle slope of the hill. It was judged that this path is the one that is most likely to give rise to high doses and, therefore, was used in the hydrological modelling of the safety assessment that followed the present work. The possibility that there may also be transport through the unsaturated zone and systems of perched water tables in layers 1 and 2 to both the Szilágyi and Némedi streams cannot be excluded; the transport along these pathways is likely to be intermittent.
Parametric and semiparametric inference for shape: the role of the scale functional
Authors: Hallin Marc , Paindaveine Davy 
Published: January 2007

We are considering the problem of efficient inference on the shape matrix of an elliptic distribution with unspecified location and either (a) fully specified radial density, (b) radial density specified up to a scale parameter, or (c) completely unspecified radial density. Bickel in [1] has shown that efficiencies under (b) and (c), while being strictly less than under (a), coincide: the efficiency loss caused by an unspecified radial density thus is entirely due to the non-specification of its scale (scale here is not necessarily measured by standard error, as second-order moments may be infinite). Defining scale however requires the choice of a particular scale functional, a choice which has an impact on efficiency bounds. We provide a closed form expression for this efficiency loss, both in hypothesis testing and in point estimation, as a function of the standardized radial density and the scale functional. We show that this loss is maximum at arbitrarily light tails whereas, under arbitrarily heavy tails, it is arbitrarily close to zero: hence, under very heavy tails, ignoring the scale (ignoring the exact density) asymptotically does not harm inference on shape. However, the same loss is nil, irrespective of the standardized radial density, when the scale functional (in dimension k) is the k-th root of the scatter determinant.
The cross-validated adaptive epsilon-net estimator
Authors: Laan Mark J. van der , Dudoit Sandrine , Vaart Aad W. van der 
Published: January 2007

Suppose that we observe a sample of independent and identically distributed realizations of a random variable, and a parameter of interest can be defined as the minimizer, over a suitably defined parameter set, of the expectation of a (loss) function of a candidate parameter value and the random variable. For example, squared error loss in regression or the negative log-density loss in density estimation. Minimizing the empirical risk (i.e., the empirical mean of the loss function) over the entire parameter set may result in ill-defined or too variable estimators of the parameter of interest. In this article, we propose a cross-validated ε-net estimation method, which uses a collection of submodels and a collection of ε-nets over each submodel. For each submodel sand each resolution level ε, the minimizer of the empirical risk over the corresponding ε-net is a candidate estimator. Next we select from these estimators (i.e. select the pair (s,ε)) by multi-fold cross-validation. We derive a finite sample inequality that shows that the resulting estimator is as good as an oracle estimator that uses the best submodel and resolution level for the unknown true parameter. We also address the implementation of the estimation procedure, and in the context of a linear regression model we present results of a preliminary simulation study comparing the cross-validated ε-net estimator to the cross-validatedL1-penalized least squares estimator (LASSO) and the least angle regression estimator (LARS).
Influence of the addition of Pd and Cu to cobalt catalysts prepared by SMAI for F-T synthesis
Authors: Yu Li-hua , Zhang Shou-min , Guo Xianzhi , Wang Da , Wang Shu-rong , Wu Shi-hua 
Published: January 2007

AbstractThe Co-Pd/SiO2 and Co-Cu/SiO2 catalysts were prepared via solvated metal atom impregnation (SMAI) method and investigated for the Fischer-Tropsch (F-T) synthesis. The catalysts contained 5wt.% Co and a weight ratio of Pd (or Cu) to Co of 1/30. XPS indicated that Co, Pd and Cu were in metallic state. The results of XPS and magnetic measurements showed that Co and Pd (Cu) were alloyed. The Co particles on the catalysts were very highly dispersed and they displayed superparamagnetic behavior. FT-IR indicated that the electrons shifted from Cu and Pd to Co. Catalytic tests showed that CO hydrogenation rates followed the order Pd-Co &gt; Cu-Co &gt; Co.
Interaction of fibrinogen with nanosilica
Authors: Rugal Anna , Gun’ko Vladimir , Barvinchenko Valentina , Turov Vladimir , Semeshkina Tatyana , Zarko Vladimir 
Published: January 2007

AbstractInteraction of human plasma fibrinogen (HPF) with fumed nanosilica A-300 in a phosphate buffer solution (PBS) was studied using 1H NMR spectroscopy with layer-by-layer freezing-out of bulk and interfacial water in the temperature range of 210–273 K, TSDC (90 T FTIR, and UV spectroscopy methods. An increase in concentration of HPF in the PBS leads to a decrease in amounts of structured water (frozen at T FTIR and UV spectra show that the HPF adsorption on silica leads to structural changes of the protein molecules. These changes and formation of hybrid HPF/A-300 aggregates can increase the rate of clotting that is of importance on nanosilica application as a component of tourniquet preparations.
Characterization of superparamagnetic MgxZn1−x Fe2O4 powders
Authors: Kassabova-Zhetcheva Violeta , Pavlova Lilyana , Samuneva Bisserka , Cherkezova-Zheleva Zara , Mitov Ivan , Mikhov Mikhail 
Published: January 2007

AbstractStructural and magnetic properties of Mgx Zn1−x Fe2O4 powders have been studied with respect to the application for thermal cancer therapy (magnetic hyperthermia). Mgx Zn1−x Fe2O4 (x=0.1–0.5) powders with particle sizes between 5 and 8 nm were produced by citrate method. The X-ray diffraction patterns of the samples correspond to a spinel phase. The lattice constant and the volume of the elementary cell increase when x changes from 0.1 to 0.5. The FTIR-spectra ascertain the spinel phase formation. The Mossbauer studies reveal the presence of extremely small particles, which undergo superparamagnetic relaxation at room temperature. The core-shell model has been applied to explain quadruple doublets. The quadruple splitting at “shells” is bigger than those at “cores” whereas the isomer shifts remain close. Magnetic studies confirm the presence of extremely small particles that behave as superparamagnetic ones.
Removal of chlorinated solvents from carbonate-buffered water by zero-valent iron
Authors: Jiricek Marek , Sracek Ondra , Janda Vaclav 
Published: January 2007

AbstractThe performance of a ground level reactive cell, filled with Fe0, designed for the treatment of water contaminated by chlorinated solvents, having a total input concentration of approximately 2 mg 1−1 of the principal contaminants trichloroethene and perchloroethene, was tested at the Milovice site in the Czech Republic. A residence time of 1.62 days in the box was sufficient to reduce concentrations to a fraction less than 0.015 of the initial concentration. However, incomplete degradation of cis-1,2-DCE was observed. Reactions approximated first-order kinetics. The principal changes of concentrations of inorganic dissolved species in the reactive cell occurred for Ca2+, HCO 3−, NO 3− (decreased) and for Fe (initially increased, then decreased). Changes for Ca2+ and HCO 3− were caused by the precipitation of secondary carbonate mineral phases such as aragonite and siderite with the minor presence of green rust-CO3. Concentration changes were gradual, along the complete length of the cell with a maximum at the inlet zone. The observations were attributed to minor increases of pH and slow kinetics of precipitation in the carbonate-buffered system. The average porosity loss was estimated to be approximately 2.7 % of the initial porosity per year, suggesting the long-term function of the permeable reactive barrier.
Synthesis and aqueous solution properties of homologous gemini surfactants with different head groups
Authors: Sun Yuhai , Feng Yujun , Dong Hongwei , Chen Zhi , Han Likun 
Published: January 2007

Abstract
A series of homologous gemini surfactants possessing identical hydrophobic chains but different ionic head groups (cationic, anionic, zwitterionic) were synthesized, and their aqueous solution properties were examined. The results showed that the surface activities of gemini surfactants are superior to those of corresponding conventional monomeric surfactants, and molecular arrangements of gemini surfactants at the air-water interface are tighter than those of corresponding conventional surfactants. It was also found that zwitterionic gemini surfactant possesses the highest surface activity among the three surfactants. The behavior at the air-water interface is closely related to the molecular structural features of surfactants, which provide an indication for synthesizing highly-efficient surfactants.
Matrix isolation FTIR spectroscopical study of ethene secondary ozonide
Authors: Bariseviciute Ruta , Ceponkus Justinas , Sablinskas Valdas 
Published: January 2007

AbstractA new method is used for the separation of ethene secondary ozonide (SOZ) from the other products of ethene ozonization reaction. The reaction was performed in the neat films of the reactants at 77 K. Ethene SOZ was separated from other products of the reaction by vacuum distillation at 190–210 K and analyzed by means of the matrix isolation IR absorption spectroscopy. Spectroscopic data from photolysis of the matrix isolated ozonide was used as an argument for assignment of the infrared spectral bands either to ethene SOZ or to other products of the reaction. The spectra of ethene SOZ isolated in the Ar matrix were analyzed by combining experimental results with the theoretical calculations performed at the MP2 6-311+G (3df, 3pd) level. A new assignment of some experimental fundamental bands is proposed taking in to account the Fermi resonance between CH stretch and the five membered ring vibrations. For the first time more than 30 weak infrared absorption bands were observed and assigned to various combination vibrations and overtones. By using new spectral information concerning the overtones and the combination bands it is concluded that the dissociation of unstable ethene SOZ involving breaking of any of the four CO bonds of the five membered ring of ethene SOZ has low probability. Dissociation of the ring starts from breaking of the OO bond.
Addition of TiO2 nanowires in different polymorphs for dye-sensitized solar cells
Authors: Asagoe Keisuke , Ngamsinlapasathian Supachai , Suzuki Yoshikazu , Yoshikawa Susumu 
Published: January 2007

Abstract
TiO2 (B) and TiO2 anatase nanowires were prepared at 150 °C for 120 h by a hydrothermal method followed by calcination in air at 400 °C for 2 h and at 700 °C for 2 h for TiO2 (B) and TiO2 anatase, respectively. Although dye-sensitized solar cells (DSC) with fully nanowire electrodes showed a rather low light-to-electricity conversion efficiency of 1.33 % for TiO2 (B) and 2.42% for TiO2 anatase, 10 wt % nanowire-dispersed electrodes in a P-25 TiO2-nanoparticle matrix demonstrated improved efficiency of 6.17 % for TiO2 (B) and 6.53% for TiO2 anatase, these exceeding that of pure P-25 electrodes in this work (η=5.59%). The dominant mechanisms of the improvement at 10 wt% for the two different polymorphs are thought to be different, i.e., a light-scattering and film-thickness increment for the TiO2 (B) system, whereas there is an improved conduction path through the matrix for the TiO2 anatase system.
Uncertainty of nitrate and sulphate measured by ion chromatography in wastewater samples
Authors: Tepuš Brigita , Simonič Marjana 
Published: January 2007

Abstract
This paper presents an evaluation of measurement uncertainty regarding the results of anion (nitrate and sulphate) concentrations in wastewater. Anions were determined by ion chromatography (EN ISO 10304-2, 1996). The major sources of uncertainty regarding the measurements’ results were identified as contributions to linear least — square or weighted regression lines, precision, trueness, storage conditions, and sampling. Determination of anions in wastewater is very important for the purification procedure, especially the amount of nitrate in waste and potable waters. The determined expanded uncertainty was 6.1 % for nitrate anions and 8.3 % for sulphate anions. The difference between measurement uncertainties determined by the two methods, the weighted and linear least — square methods, is negligible.
Sub-millivolt amplitude potential oscillations observed in the noise of hydrogen evolution on Ag and Cu microelectrodes
Authors: Szenes Ildikó , Mészáros Gábor , Lengyel Béla 
Published: January 2007

Abstract
A strange effect was observed while using the method of quasi-simultaneous determination of electrochemical voltage noise and impedance to obtain information on the kinetics of the hydrogen evolution reaction on Ag and Cu microelectrodes. Beyond a certain polarizing current density we found microvolt-amplitude potential oscillations on both electrodes with a frequency in the 5 Hz–5 kHz range. The oscillations were observed in every single experiment with Ag and Cu, while no oscillatory behavior was observed during the control experiments with the Pt microelectrode. The presence of the oscillations indicates that the mechanism of hydrogen evolution is more complex compared to the original assumption.
Synthesis and magnetic properties of octahedral ferrite NiχCo1−χ
Fe2O4 nanocrystals
Authors: Kasapoglu Nermin , Birsöz Bahar , Baykal Abdülhadi , Köseoglu Yüksel , Toprak Muhammet 
Published: January 2007

Abstract
A series of Ni doped cobalt ferrite compounds with the formula Niχ Co1−χ Fe2O4 where x=0, 0.2, 0.4, 0.6, 0.8, and 1.0 were prepared using a hydrothermal method and subsequently sintered/annealed at 600 °C for 3 h. The influence of the Ni content on the lattice parameter, a, stretching vibration and the magnetization of specimens were subsequently studied. XRD and FTIR were used to investigate structure and composition variations. All samples were found to have a cubic spinel structure. SEM was used to study morphological variations. The results indicate that the average particle sizes are between 30–35 nm with a narrow size distribution along with nanocrystals forming of regular octahedrons. A decrease in the peak to peak line width and increase in resonance field with increasing Ni content were observed from ESR measurements. Based on ESR results, a core-shell type of formation was proposed where the core is made up of undoped CoFe2O4 and the shell is Ni2+ doped CoFe2O4.
Synthesis, characterization and magnetic investigation of (NH4)0.5Mn1.25(H2O)2[BP2O8]·0.5H2O
Authors: Birsöz B. , Baykal A. , Toprak M. , Köseoglu Y. 
Published: January 2007

Abstract
A new borophosphate compound with the composition (NH4)χ Mn((3−χ)/2)(H2O)2 [BP2O8]·(1−x)H2O was prepared under mild hydrothermal conditions and characterized by X-ray powder diffraction (XRD) and Fourier Transform Infrared Spectroscopy (FTIR) methods. The title compound was synthesized from MnCl2·2H2O, H3BO3, and (NH4)2HPO4 with variable molar ratios by heating at 180 °C for 7 days in an autoclave. The X-ray diffraction data of the water insoluble polycrystalline powder was indexed using the TREOR program in hexagonal system with the unit cell parameters of a = 9.5104, c = 15.7108 Å, Z = 6 and the space group P65 (No.176). (NH4)χ Mn((3−χ)/2)(H2O)2 [BP2O8]·(1−x)H2O is isostructural with (NH4)χ M ((3−χ)2)/II (H2O)2 [BP2O8]·(1−x)H2O (MII = Co, Cd, Mg; x = 0.5–1). Its unit cell parameters and hkl values were in good agreement with the other isostructural compounds. This is the first report presenting both the synthetic details and the indexed X-ray powder diffraction pattern of this compound along with the characterization by FTIR, thermal gravimetric analysis, scanning electron microscopy and EPR.
Syringoplutarchusia nordmanni, a new genus and species of the feather mite family Syringobiidae (Acari, Astigmata, Pterolichoidea) from the Black-winged Pratincole Glareola nordmanni (Charadriiformes, Glareolidae)
Authors: Dabert Jacek , Skoracki Maciej 
Published: January 2007

AbstractSyringoplutarchusia, a new genus of the syringicolous feather mite family Syringobiidae (Pterolichoidea), is described based on a single new species, S. nordmanni sp. nov., collected from the feather quills of a museum specimen of the Black-winged Pratincole Glareola nordmanni Fischer, 1842 (Glareolidae). Absence of adanal discs and complete reduction of setae d and e on tarsi IV in males of the new genus is unique in this family. The highly elongated body shape of both sexes is most similar to the genera Plutarchusia Oudemans, 1904 and Paidoplutarchusia Dabert, 2003 but strong sclerotization of coxal fields and hypertrophied posterior legs with variously shaped apophyses resemble more advanced syringobiid mites, e.g. Syringobia Trouessart et Neumann, 1888. Syringoplutarchusia represents the first syringobiid from this host family. The taxonomic status of the new taxon is discussed.
Conductive Mesocellular Silica–Carbon Nanocomposite Foams for Immobilization, Direct Electrochemistry, and Biosensing of Proteins
Authors: Wu S. , Ju H. X. , Liu Y. 
Published: January 2007

AbstractA mesocellular silica–carbon nanocomposite foam (MSCF) is designed for the immobilization and biosensing of proteins. The as‐prepared MSCF has a highly ordered mesostructure, good biocompatibility, favorable conductivity and hydrophilicity, large surface area, and a narrow pore‐size distribution, as verified by transmission electron microscopy (TEM), IR spectroscopy, electrochemical impedance spectroscopy (EIS), nitrogen adsorption–desorption isotherms, pore size distribution plots, and water contact angle measurements. Using glucose oxidase (GOD) as a model, the MSCF is tested for immobilization of redox proteins and the design of electrochemical biosensors. GOD molecules immobilized in the mesopores of the MSCF show direct electrochemistry with a fast electron transfer rate (14.0 ± 1.7 s–1) and good electrochemical performance. Based on a decrease of the electrocatalytic response of the reduced form of GOD to dissolved oxygen, the proposed biosensor exhibits a linear response to glucose concentrations ranging from 50 μM to 5.0 mM with a detection limit of 34 μM at an applied potential of –0.4 V. The biosensor shows good stability and selectivity and is able to exclude interference from ascorbic acid (AA) and uric acid (UA) species that always coexist with glucose in real samples. The nanocomposite foam provides a good matrix for protein immobilization and biosensor preparation.