bluuebunny/crossref_metadata_2025_split huggingface dataset:
Molecular evolution in star-forming cores: From prestellar cores to protostellar cores
Authors: Aikawa Yuri , Wakelam Valentine , Sakai Nami , Garrod R. T. , Herbst E. , Yamamoto Satoshi 
Published: October 2008

AbstractWe investigate the molecular abundances in protostellar cores by solving the gas-grain chemical reaction network. As a physical model of the core, we adopt a result of one-dimensional radiation-hydrodynamics calculation, which follows the contraction of an initially hydrostatic prestellar core to form a protostellar core. Temporal variation of molecular abundances is solved in multiple infalling shells, which enable us to investigate the spatial distribution of molecules in the evolving core. The shells pass through the warm region of T ~ 20–100 K in several 104 yr and falls onto the central star in ~100 yr after they enter the region of T > 100 K. We found that the complex organic species such as HCOOCH3 are formed mainly via grain-surface reactions at T ~ 20–40 K, and then sublimated to the gas phase when the shell temperature reaches their sublimation temperatures (T ≥ 100 K). Carbon-chain species can be re-generated from sublimated CH4 via gas-phase and grain-surface reactions. HCO2+, which is recently detected towards L1527, are abundant at r = 100–2,000 AU, and its column density reaches ~1011 cm−2 in our model. If a core is isolated and irradiated directly by interstellar UV radiation, photo-dissociation of water ice produces OH, which reacts with CO to form CO2 efficiently. Complex species then become less abundant compared with the case of embedded core in ambient clouds. Although a circumstellar (protoplanetary) disk is not included in our core model, we can expect similar chemical reactions (i.e., production of large organic species, carbon-chains and HCO2+) to proceed in disk regions with T ~ 20–100 K.
Organic chemistry in circumstellar envelopes: Setting the stage for prebiotic synthesis
Authors: Ziurys Lucy M. 
Published: October 2008

AbstractOne of the few carbon-rich environments found in interstellar space is the ejecta of asymptotic giant branch (AGB) stars. Such material, which forms a circumstellar envelope, becomes enriched in carbon due to “dredge-up” phenomena associated with nucleosynthesis. A unique organic synthesis flourishes in the gas phase in these envelopes, and radio and millimeter observations have identified a wide range of C-bearing compounds, including long acetylenic chains such as HC5N, HC7N, C4H, C6H, C8H, C6H−, C8H−, and C3O. Oxygen-rich envelopes also have a non-negligible carbon chemistry, fostering species such as HCN and HCO+. Phosphorus chemistry appears to be active as well in circumstellar shells, as evidenced by the recent detections of HCP, CCP, and PO. Radio observations also indicate that some fraction of the circumstellar molecular material survives into the planetary nebula stage, and then becomes incorporated into diffuse, and eventually, dense clouds. The complex organic molecules found in dense clouds such as Sgr B2(N) may be the products of “seed” material that can be traced back to the carbon-enriched circumstellar gas.
Organic molecular anions in interstellar and circumstellar environments
Authors: Cordiner M. A. , Millar T. J. , Walsh C. , Herbst E. , Lis D. C. , Bell T. A. , Roueff E. 
Published: October 2008

AbstractThe synthesis of organic molecular anions in TMC-1 and IRC+10216 is investigated. Modelled C2H−, CN−, C3N−, C5N− and C7N− column densities are sufficiently great that these species might be observable in IRC+10216. Density-enhanced shells in the outer envelope of IRC+10216 are found to enhance the C2H− and CN− column densities by shielding these anions from destruction by UV radiation. From a newly-derived upper column density limit of 6.6 × 1010 cm−2 for C2H− in IRC+10216 we deduce the primary production mechanism for this anion to be C2H2 + H− ⇒ C2H− + H2. In TMC-1, due to the low radiative electron attachment rates calculated for C2H−, CN− and CH2CN−, these species have modelled column densities below the detection threshold. They could, however, be produced in reactions we have not yet considered.
Circumstellar H2O in M-type AGB stars
Authors: Maercker Matthias , Schöier Fredrik L. , Olofsson Hans 
Published: October 2008

AbstractSurprisingly high amounts of H2O have recently been reported in the circumstellar envelope around the M-type AGB star W Hya. However, substantial uncertainties remain, as the required radiative transfer modelling is difficult due to high optical depths, sub-thermal excitation and the sensitivity to the combined radiation field from the central star and dust grains.
Unidentified infrared bands and the formation of PAHs around carbon stars
Authors: Speck Angela , Barlow Mike , Wesson Roger , Clayton Geoff , Volk Kevin 
Published: October 2008

AbstractAlthough unidentified infrared bands (UIBs) have been observed in many astrophysical environments, there is one notable exception: carbon (C) stars. Only a handful of C stars have been shown to emit UIBs and most have hot companions. This makes C stars with hot companions an ideal location to investigate the emitters of the UIBs. PAHs are excited by absorption of single photons whose energy is then distributed over the whole molecule. These molecules then emit the energy at the characteristic wavelengths, but the precise wavelengths and strength ratios depend on the size, composition and charge state of the individual PAHs. Furthermore, the wavelength of photons needed to excite PAHs depends on their size and charge state. While small PAHs undoubtedly need higher energy (UV) photons, it has been suggested that large or ionized PAHS (>100 C atoms) can be excited by visible or even near-IR photons. The lack of PAH emission from single carbon stars suggests that either PAHs do not form around C stars or that only small neutral grains form, which cannot be excited by a C star's radiation field.There are two competing formation mechanisms for PAHs around C stars: (1) “bottom-up” where acetylene molecules react to form aromatic rings, building up to PAHs; or (2) “top-down”, where small carbon grains react with H atoms and desorb PAHsUsing spatially resolved spectroscopic observations from Gemini/Michelle, of five carbon stars with hot companions, we investigate the circumstance under which PAH emission occurs and try to discriminate between formation mechanisms.
Probing chemical processes in AGB stars
Authors: Schöier Fredrik L. , Olofsson Hans 
Published: October 2008

AbstractWe are conducting multi-transition observations of circumstellar line emission from common molecules such as HCN, SiO, CS, SiS and CN for a large sample of AGB stars with varying photospheric C/O-ratios and mass-loss charachteristics. Our recently published results for SiO and SiS clearly show that major constraints on the relative roles of non-equilibrium chemistry, dust condensation, and photodissociation can be obtained from the study of circumstellar molecular line emission. Presented here are also preliminary results based on detailed radiative transfer modelling of HCN line emission.
Aromatic, aliphatic, and the unidentified 21 micron emission features in proto-planetary nebulae
Authors: Hrivnak Bruce J. , Volk Kevin , Geballe T. R. , Kwok Sun 
Published: October 2008

AbstractAromatic features at 3.3, 6.2, 7.7, 8.6, 11.3 μm are observed in proto-planetary nebulae (PPNe) as well as in PNe and H ii regions. Aliphatic features at 3.4 and 6.9 μm are also observed; however, these features are often stronger in PPNe than in PNe. These observations suggest an evolution in the features from simple molecules (C2H2) in AGB stars to aliphatics in PPNe to aromatics in PNe. In the same carbon-rich PPNe, a strong, broad, unidentified 21 μm emission feature has been found. We will present recent observations of the aromatic, aliphatic, and 21 μm emission features, along with C2H2 (13.7 μm) and a new feature at 15.8 μm, and discuss correlations among them and other properties of these PPNe.
Mapping the PAHs and H2 in ρ Oph A
Authors: Justtanont Kay , Liseau René , Larsson Bengt 
Published: October 2008

AbstractWe present an ISOCAM-CVF map of the ρ Oph A region, covering 3′ × 3′. For each 6 arcsec2 pixel, we extract the spectrum from 5–15 μm. We determine the fluxes of the main PAH features by fitting Lorentzian profiles to the spectrum. The peaks of the various PAH components correspond well with the known positions of the PDRs in this vicinity. The spectrum in several pixels exhibits strong rotational lines of molecular hydrogen which can be used to derive the physical properties of the cloud. The H2 emission traces the hot gas of the bipolar CO outflow from VLA1623.
Properties of polycyclic aromatic hydrocarbons in the star forming environment in nearby galaxies
Authors: Sakon Itsuki , Onaka Takashi , Kato Daisuke , Kaneda Hidehiro , Kataza Hirokazu , Okada Yoko , Kawamura Akiko , Onishi Toshikazu , Fukui Yasuo 
Published: October 2008

AbstractWe have carried out the mid-infrared slit spectroscopic observations of sources in the LMC and in NGC 6946 with AKARI/IRC. We investigate the properties of the UIR bands in terms of the star forming activities. We find systematically larger ratios of UIR bands in 6–9 μm to 11.2 μm band in active star forming regions than in the quiet regions. This behavior is consistent with the photo-ionization model of PAHs. Our results suggest that the ratios of UIR bands in 6–9 μm to 11.2 μm band can be used as more efficient and vigorous tools to measure the extent of on-going star formation in remote galaxies rather than just the presence or absence of the features themselves.
Detection of the unidentified infrared bands in a filament of the dwarf galaxy NGC1569
Authors: Matsumoto H. , Onaka T. , Sakon I. , Kaneda H. 
Published: October 2008

AbstractWe made near- to mid-infrared imaging and spectroscopic observations of the dwarf galaxy NGC 1569 with the Infrared Camera (IRC) on board AKARI. The unidentified infrared (UIR) band features at 6.2, 7.7, and 11.2 μm, which are generally attributed to polycyclic aromatic hydrocarbons (PAHs), are clearly detected in a structure associated with an Hα filament. The filament is filled with X-ray emission and is thought to be formed by outflow from the galaxy. Since PAHs are destroyed rapidly in hot plasma, it is most likely that PAHs in the filament are produced from fragmentation of large carbonaceous grains in the shock. We also detect excess emission in 2–5 μm in the filament, which may come from very small grains.
Spectra of nearby galaxies measured with a new very broadband receiver
Authors: Narayanan Gopal , Snell Ronald L. , Erickson Neal R. , Chung Aeree , Heyer Mark H. , Yun Min , Irvine William M. 
Published: October 2008

AbstractThree-millimeter-wavelength spectra of a number of nearby galaxies have been obtained at the Five College Radio Astronomy Observatory (FCRAO) using a new, very broadband receiver. This instrument, which we call the Redshift Search Receiver, has an instantaneous bandwidth of 36 GHz and operates from 74 to 110.5 GHz. The receiver has been built at UMass/FCRAO to be part of the initial instrumentation for the Large Millimeter Telescope (LMT) and is intended primarily for determination of the redshift of distant, dust-obscured galaxies. It is being tested on the FCRAO 14 m by measuring the 3 mm spectra of a number of nearby galaxies. There are interesting differences in the chemistry of these galaxies.
Organic matter in interplanetary dust particles
Authors: Flynn G. J. , Keller L. P. , Wirick S. , Jacobsen C. 
Published: October 2008

AbstractAnhydrous interplanetary dust particles (IDPs), which are the most mineralogically primitive extraterrestrial materials available for laboratory analysis, contain several percent organic matter. The high O:C and N:C ratios suggest the organic matter in the anhydrous IDPs is significantly less altered by thermal processing than the organic matter in meteorites. X-ray Absorption Near-Edge Structure (XANES) spectroscopy and infrared spectroscopy demonstrate the presence of C=C, most likely as C-rings, C=O, and aliphatic C-H2and C-H3in all the IDPs examined. A D-rich spot, containing material that is believed to have formed in a cold molecular cloud, has C-XANES and infrared spectra very similar to the organic matter in the anhydrous IDPs, possibly indicating a common formation mechanism. However the primitive organic matter in the IDPs differs from the interstellar/circumstellar organic matter characterized by astronomical infrared spectroscopy in the relative strengths of the asymmetric aliphatic C-H2and C-H3absorptions, with the IDP organic having a longer mean chain length. If both types of organic matter originated by the same process, this may indicate the interstellar organic matter has experienced more severe radiation processing than the organic matter in the primitive IDPs.
Unraveling the chemical history of the Solar System as recorded in extraterrestrial organic matter
Authors: Cody George D. , Alexander Conel M. O'D. , Kilcoyne A. L. David , Yabuta Hikaru 
Published: October 2008

AbstractWe have initiated an extensive program of molecular analysis of extraterrestrial organic matter isolated from a broad range of meteorites (spanning multiple classes, groups, and petrologic types), including recent molecular spectroscopic analyses of the organic matter in the Comet 81P/Wild 2 samples. The results of these analyses clearly reveal the signature of multiple reaction pathways that transformed extraterrestrial organic matter away from its primitive roots. The most significant molecular transformation occurred in the post-accretionary phase of the parent body. However, each of the various chemical transformation trajectories point unambiguously back to a common primitive origin. Applying a wide range of spectroscopic techniques we find that the primitive organic precursor is striking in its chemical complexity exhibiting a broad array of oxygen- and nitrogen-bearing functional groups. The π-bonded carbon exists as predominately highly substituted single ring aromatics, there exists no evidence for abundant, large, polycyclic aromatic hydrocarbons (PAHs). We find that the molecular structure of primitive extraterrestrial organics is consistent with synthesis from small reactive molecules, e. g. formaldehyde, whose random condensation and subsequent rearrangement chemistry at low temperatures leads to a highly cross-linked macromolecule.
Organics in meteorites - Solar or interstellar?
Authors: Alexander Conel M. O'D. , Cody George D. , Fogel Marilyn , Yabuta Hikaru 
Published: October 2008

AbstractThe insoluble organic material (IOM) in primitive meteorites is related to the organic material in interplanetary dust particles and comets, and is probably related to the refractory organic material in the diffuse interstellar medium. If the IOM is representative of refractory ISM organics, models for how and from what it formed will have to be revised.
Laboratory experiments as support to the built up of Titan's theoretical models and interpretation of Cassini-Huygens data
Authors: Gazeau Marie-Claire , Benilan Yves , Es-sebbar Et Touhami , Ferradaz Thomas , Hébrard Eric , Jolly Antoine , Raulin François , Romanzin Claire , Guillemin Jean-Claude , Berteloite Coralie , Canosa André , Le Picard Sébastien D. , Sims Ian R. 
Published: October 2008

AbstractTo interpret the concentrations of the products measured in Titan's atmosphere and to better understand the associated chemistry, many theoretical models have been developed so far. Unfortunately, large discrepancies are still found between theoretical and observational data. A critical examination of the chemical scheme included in these models points out some problems regarding the reliability of the description of critical reaction pathways as well as the accuracy of kinetic parameters. Laboratory experiments can be used to reduce these two sources of uncertainty. It can be:i) experimental simulations: in our laboratory (LISA), representative Titan's simulation experiments are planned to be carried out in a reactor where the initial gas mixture will be exposed, for the first time, to both electrons and photons. Thus, the chemistry between N atoms and CH3, CH2, CH fragments, issued from electron dissociation of N2 and photo-dissociation of CH4 respectively, will be initiated. Thank to a time resolved technique, we will be able to analyse “in situ”, qualitatively and quantitatively, the stable species as well as the short life intermediates. Then, the implied chemistry will be determined precisely, and consequently, its description will be refined in theoretical models. The current status of this program will be given.ii) specific experiments: they are devoted, for example, to determine kinetic rate constants and low temperature VUV spectra that will be used to feed models and to interpret observational data. Such experiments performed in LISA and in Rennes' laboratory concern polyynes and cyanopolyynes as these compounds could link the gaseous and the solid phase in planetary atmosphere. Results concerning C4H+ hydrocarbons kinetic rate constants and VUV cross section of HC3N and HC5N will be detailed.
The source of heavy organics and aerosols in Titan's atmosphere
Authors: Waite J. H. , Young D. T. , Coates A. J. , Crary F. J. , Magee B. A. , Mandt K. E. , Westlake J. H. 
Published: October 2008

AbstractIon-neutral chemistry in Titan's upper atmosphere (~ 1000 km altitude) is an unexpectedly prodigious source of hydrocarbon-nitrile compounds. We report observations from the Cassini Ion Neutral Mass Spectrometer (INMS; Waite et al. 2004) and Cassini Plasma Spectrometer (CAPS; Young et al. 2004) that allow us to follow the formation of the organic material from the initial ionization and dissociation of nitrogen and methane driven by several free energy sources (extreme ultraviolet radiation and energetic ions and electrons) to the formation of negative ions with masses exceeding 10,000 amu.
Possibilities of lightning-induced processes in gas-dusty atmosphere of water-containing bodies of Solar System
Authors: Serozhkin Yuriy 
Published: October 2008

AbstractLightning is considered as one of energy sources for synthesis of biochemical compounds. Numerous theoretical and experimental researches of gas-grain chemistry show that chemical reactions on the gas - ice boundary play a considerable role in such synthesis. In this connection the greatest interest represents studying lightning in gas-dusty atmospheres of water-containing bodies (comets, ice satellites of Jupiter and Saturn).
Micro-Raman study of nanodiamonds from Allende meteorite
Authors: Gucsik Arnold , Ott Ulrich , Marosits Edit , Karczemska Anna , Kozanecki Marcin , Szurgot Marian 
Published: October 2008

AbstractWe have studied the Raman spectroscopic signatures of nanodiamonds from the Allende meteorite in which some portions must be of presolar origin as indicated by the isotopic compositions of various trace elements. The spectra of the meteoritic nanodiamond show a narrow peak at 1326 cm−1 and a broad band at 1590 cm−1. Compared to the intensities of these peaks, the background fluorescence is relatively high. A significant frequency shift from 1332 to 1326 cm−1, peak broadening, and appearance of a new peak at 1590 cm−1 might be due to shock effects during formation of the diamond grains. Such changes may have several origins: an increase in bond length, a change in the electron density function or charge transfer, or a combination of these factors. However, Raman spectroscopy alone does not allow distinguishing between a shock origin of the nanodiamonds and formation by a CVD process as is favored by most workers.
Stardust in meteorites: A link between stars and the Solar System
Authors: Zinner Ernst 
Published: October 2008

AbstractUltimately, all of the solids in the Solar System, including ourselves, consist of elements that were made in stars by stellar nucelosynthesis. However, most of the material from many different stellar sources that went into the making of the Solar System was thoroughly mixed, obliterating any information about its origin. An exception are tiny grains of preserved stardust found in primitive meteorites, micrometeorites, and interplanetary dust particles. These μm- and sub-μm-sized presolar grains are recognized as stardust by their isotopic compositions, which are completely different from those of the Solar System. They condensed in outflows from late-type stars and in SN ejecta and were included in meteorites, from which they can be isolated and studied for their isotopic compositions in the laboratory. Thus these grains constitute a link between us and our stellar ancestors. They provide new information on stellar evolution, nucleosynthesis, mixing processes in asymptotic giant branch (AGB) stars and supernovae, and galactic chemical evolution. Red giants, AGB stars, Type II supernovae, and possibly novae have been identified as stellar sources of the grains. Stardust phases identified so far include silicates, oxides such as corundum, spinel, and hibonite, graphite, silicon carbide, silicon nitride, titanium carbide, and Fe-Ni metal.
The flux of interstellar particles detected in the Solar System
Authors: Hajduková Mária 
Published: October 2008

AbstractThe present work shows the proportion of interstellar meteors from different mass ranges (exceeding 20 orders of mass scale) detected by various observational techniques. Having analysed the IAU Meteor Data Center, we find that the mass index of interstellar particles continuously increases towards higher masses, but there is a significant change between 10−10 − 10−11 kg. This break is possibly caused by different physical processes leading to different populations of interstellar particles and might be connected with their origin.
The occurence of interstellar meteoroids in the vicinity of the Earth
Authors: Hajduková Mária 
Published: October 2008

AbstractIf interstellar meteors are present among the registered meteor orbits, the distribution of the excesses of their heliocentric velocities should correspond to the distribution of radial velocities of close stars. Hence, for the velocity vi = 20 kms−1 of an interstellar meteor (with respect to the Sun) we obtain a heliocentric velocity vH = 46.6 kms−1 of an interstellar meteor arriving at the Earth. Moreover, a concentration of radiants to the Sun's apex should be observed. An analysis of the hyperbolic meteors among the 4581 photographic orbits of the IAU Meteor Data Center showed that the identification of the vast majority of the hyperbolic orbits in these catalogues has been caused by an erroneous determination of their heliocentric velocity and/or other parameters. Any error in the determination of vH, especially near the parabolic limit, can create an artificial hyperbolic orbit that does not really exist. On the basis of photographic meteors from the IAU MDC, the proportion of possible interstellar meteors decreased significantly (greater than 1 order of magnitude) after error analysis and does not exceed the value 2.5 × 10−4. Neither any concentration of radiants to the Sun's apex, nor any distribution following the motion of interstellar material has been found.