bluuebunny/crossref_metadata_2025_split huggingface dataset:
A transition from diagenesis to greenschist facies within a major Variscan fold/thrust complex in SW England
Authors: Primmer T. J. 
Published: December 2006

AbstractThe north coast of Cornwall, from Bude to Newquay, provides a continuous section through a major Variscan fold/thrust complex. Illite crystallinity studies have revealed a transition from diagenesis in the north to greenschist facies metamorphism in the south in the Upper Palaeozoic succession. More detailed studies of mineral assemblages in both metabasites and pelitic rocks support the regional pattern of metamorphism indicated by illite crystallinity, and show that locally in the Tintagel district, the grade of metamorphism may have reached middle to upper greenschist facies. An attempt to correlate the above data with temperatures (108–985°C) derived from O-isotope geothermometers is made. Interpretation of the metamorphic data presented helps to emphasize the tectonic importance of the major structures seen in the fold/thrust complex.
Compositional variation within some sedimentary chlorites and some comments on their origin
Authors: Curtis C. D. , Hughes C. R. , Whiteman J. A. , Whittle C. K. 
Published: December 2006

AbstractA range of authigenic sedimentary chlorites from sandstones has been studied by analytical transmission electron microscopy. Selected area (single crystal) electron diffraction patterns are of the Ib (β = 90°) polytype confirming the earlier observations of Hayes (1970).TEM analyses show all samples to be relatively rich in both Al and Fe. In the general formula (Mg,Fe,Al)n [Si8−xAlxO20](OH)16, x varies between 1.5 and 2.6; Fe/(Fe + Mg) between 0.47 and 0.83 and n between 10.80 and 11.54. Octahedral Al is close to 3 in this formulation and Fe2+ predominates over Fe3+. Swelling chlorites have significantly different compositions which are consistent with smectite/chlorite interstratifications.The Ib (β = 90°) polytype appears to be stable under conditions of moderate to deep burial. It replaces berthierine and swelling chlorites formed at lower temperatures. As commonly seen in grain coatings, however, it precipitates from porewater; solutes probably being contributed from several mineral decomposition reactions.
Possible chemical controls of illite/smectite composition during diagenesis
Authors: Velde B. 
Published: December 2006

AbstractRe-interpretation of the significance of phase assemblages present in two sequences of rocks having experienced similar burial diagenesis allows one to establish that the change of oxidation state of iron in sediments could have the effect of changing the smectite content of the mixed layer mineral. This is used to explain an almost isothermal change in the composition of a sequence while others do not show such a rapid change. An indicator of the reaction is seen in the composition of the chlorite present in the rocks which is iron-rich and alumina-poor compared to chlorites in rocks showing a slower rate of change in the smectite content of the mixed-layered mineral. In order to reveal such a relation, one must make an analysis of the clay mineral assemblage, especially in the number of phases present during the course of diagenesis.
Electron-optical studies of phyllosilicate intergrowths in sedimentary and metamorphic rocks
Authors: White S. H. , Huggett J. M. , Shaw H. F. 
Published: December 2006

AbstractThe results of a microstructural study by backscattered scanning electron microscopy and a microchemical study using X-ray microprobe analysis of phyllosilicate intergrowths from sandstones, shales, metagreywackes, and low-grade schists are presented. The microstructural study revealed that the intergrowths thicken and become more coherent with metamorphic grade; the intergrowths change from incoherent to coherent in the anchizone. The increasing coherency is mirrored by an increase in the crystallinity indices of the illites/phengites. Chemical analysis of the individual intergrowth phases was difficult in the sediments and no systematic compositional variations were recorded. However, clear compositional trends with increasing metamorphic grade emerged in the phengites from the metagreywackes and schists, but in the chlorites only slight compositional changes were recorded.
Carbonate alteration minerals in the Salton Sea geothermal system California, USA
Authors: Douglas McDowell S. , Paces James B. 
Published: December 2006

AbstractActive geothermal systems in fluvial-deltaic sediment of the Salton Trough typically develop a thick, carbonate-cemented sandstone caprock which shows a regular progression of carbonate minerals, mineral reactions, rock-fluid mass transfer, and physical properties on increasing temperature. The Sinclair 3 well contains calcian ankerite at < 175 °C, ankerite from 175 to 195 °C, calcite+minor dolomite from 195 to about 250°C, and calcite at higher temperatures. The carbonate content of sandstone decreases on increasing temperature from > 45% at < 140 °C to about 10% at > 250 °C, The most abrupt decrease occurs in the 140 to 170°C range where significant compaction of sandstone occurs as carbonate is reduced to < 25%, and kaolinite reacts to form chlorite. The overall result is the loss of significant Ca, Fe, Mg, and CO2 from sandstone to the fluid phase on increasing temperature. Reaction ofcalcian ankerite to ankerite near 175 °C, and of ankerite to calcite and minor dolomite in the 195 to 245°C range, takes place on a constant carbonate-volume basis by direct replacement of one carbonate by another. The latter reaction produces significant chlorite, with Al derived from solution of detrital feldspar and from the smectite-to-illite transformation. The equilibrium coexistence of calcite with dolomite and ankerite near 200 °C has allowed construction of an isothermal section in the Ca-Mg-(Fe+Mn) carbonate phase diagram and provided a low-temperature constraint on the calcite limb of the calcite-dolomite solvus.
Structural and phase equilibria studies in the system Pt-Fe-Cu and the occurrence of tulameenite (Pt2FeCu)
Authors: Shahmiri M. , Murphy S. , Vaughan D. J. 
Published: December 2006

AbstractThe crystal structure and compositional limits of the ternary compound Pt2FeCu (tulameenite), formed either by quenching from above the critical temperature of 1178°C or by slow cooling, have been investigated using X-ray diffraction, transmission electron microscopy, differential thermal analysis and electron probe microanalysis.The crystal structure of Pt2FeCu, established using electron density maps constructed from the measured and calculated intensities of X-ray diffraction patterns of powdered specimens, has the (000) and (½½0) lattice sites occupied by Pt atoms and the (½0½) and (0½½) sites occupied by either Cu or Fe atoms in a random manner. The resulting face-centred tetragonal structure undergoes a disordering transformation at the critical temperature to a postulated non-quenchable face-centred cubic structure. Stresses on quenching, arising from the ordering reaction, are relieved by twinning along {101} planes or by recrystallization along with deformation twinning; always involving grain boundary fracturing.Phase relations in the system Pt-Fe-Cu have been investigated through the construction of isothermal sections at 1000 and 600°C. At 1000°C there is an extensive single phase region of solid solution around Pt2FeCu and extending to the binary composition PtFe. At 600°C the composition Pt2FeCu lies just outside this now reduced area of solid solution in a two-phase field. Comparison of the experimental results with data for tulameenite suggests that some observed compositions may be metastably preserved. The occurrence of fine veinlets of silicate or other gangue minerals in tulameenite is suggested to result from grain boundary fracturing on cooling below the critical temperature of 1178°C and to be evidence of a magmatic origin.
Zincian staurolite in Glen Doll, Scotland
Authors: Schumacher Renate 
Published: December 2006

AbstractTextures and relict mineralogy in the Dalradian gneisses from the southern contact aureole of the Glen Doll diorite trace the development of three stages of metamorphism through regional and contact metamorphic phases. Regional metamorphic stage I is characterized by the stability of sillimanite+muscovite; recognition of a subsequent regional metamorphic stage II of lower grade is based on textural criteria, the stability of kyanite and staurolite + quartz, and geothermometry/geobarometry. The breakdown of zincian staurolite occurred under the conditions of contact metamorphism (stage III). Textural evidence from the outer part of the contact aureole suggests that zincian staurolite broke down by the following oxidation reaction:zincian staurolite + muscovite + quartz + O2 → andalusite + Zn-rich spinel + magnetite + biotite + H2O.Various stages of completion of this reaction have been observed in different parts of a sample. Predominance of magnetite over Zn-rich spinel (⩽ 14 wt. % ZnO) as a breakdown product can be explained by the initial breakdown of Fe-staurolite component + muscovite + quartz+O2 to form andalusite+biotite+magnetite. These product phases were joined by the Zn-rich spinel when sufficient Zn-staurolite component had concentrated in the unreacted staurolite. Rare local examples where Zn-rich spinel is dominant over magnetite may reflect lower O2 fugacity and/or higher initial Zn contents of the staurolite.
Zn-rich staurolite from the Uvete area, central Kenya
Authors: Miyake Akira 
Published: December 2006

AbstractZn-rich staurolite occurs in a pelitic gneiss from the Uvete area, central Kenya. The rock was metamorphosed to staurolite-kyanite grade during the Mozambique metamorphism. Microprobe analyses of the staurolite gave the following values (in wt. %): SiO2 26.2–27.3, Al2O3 52.4–53.5, FeO 8.3–9.2, MgO 2.2–2.6, and ZnO 6.0–7.5. Cell dimensions are a = 7.874(± 0.003), b = 16.620(±0.006), c = 5.656(±0.002) Å and β = 90.00 (± 0.002)°. Optical properties are 2Vz = 82–85°, α = 1.742 (±0.002), β = 1.747(±0.002) and γ = 1.753(±0.002). The optical dispersion is moderate and r > v. Density is 3.83(±0.01) g/cm3. Infra-red absorption spectra were also recorded. The cation correlation suggests that the principal substitutions in the staurolite are Zn ⇆ Fe in the tetrahedral sites in the hydroxide sheet and Al ⇆ Mg in the octahedral sites.
Significance of clinopyroxene compositions from the Cudgegong Volcanics and Toolamanang Volcanics: Cudgegong-Mudgee district, NSW, Australia
Authors: Pemberton J. W. , Offler R. 
Published: December 2006

SynopisClinopyroxene phenocrysts and groundmass crystals are relict phases in altered basalt and basaltic andesite lavas, and arenites of the Cudgegong Volcanics and Toolamanang Volcanics, Cudgegong-Mudgee district, New South Wales. Petrography, field relationships and clinopyroxene compositions indicate that basaltic blocks in the latter unit are reworked from the Cudgegong Volcanics. Clinopyroxene phenocrysts show a restricted compositional range and minor Feenrichment from core to rim, features considered indicative of a calc-alkaline parent magma. It is proposed that the Cudgegong Volcanics crystallized under hydrous conditions, at least in the later stages, with risingfO2resulting in a Fe-Ti oxide crystallizing as a primary phase. The clinopyroxenes are considered to have crystallized at moderate (5–6 kbar) and falling pressures and at minimum temperatures in the range 900 to 1000°C. Coupled substitutions affecting the “other” components in the clinopyroxene structural formula indicate that theivAl-viFe3+,ivAl-viAl andivAl-viTi4+couples are important. The Sofala Volcanics, south of the study area, and the Cudgegong Volcanics are similar in age, petrography and stratigraphic position, and contain relict clinopyroxenes which are chemically similar. This suggests that the units are laterally equivalent and adds further evidence to the proposal that an oceanic island arc system was active in central western New South Wales during the Late Ordovician.
Compositional variation in högbomites from north Connemara, Ireland
Authors: Angus N. S. , Middleton R. 
Published: December 2006

AbstractHögbomite occurs in two contrasting mineral assemblages within the Currywongaun-Dough-ruagh intrusion of north Connemara: a cordierite-rich pelitic xenolith and an orthopyroxenite. In the latter, högbomite and green spinel form blebs within magnetite-ilmenite grains. The högbomite displays significant compositional variation from grain to grain: TiO2(3.0–6.3%), FeO (21.6–21.3%), MgO (10.0–7.5%), ZnO (3.6–2.4%). This chemical heterogeneity appears to represent variable degrees of partial substitution of Mg and Zn by Ti, in the replacement of spinel by högbomite. By contrast, in the cordierite-hornfels, the högbomite compositions are more notably enriched in iron: TiO2(4.7–7.0%), FeO (29.6–24.3%), MgO (4.2–6.2%), ZnO (2.7–2.1%). This iron-rich högbomite appears to have formed primarily by interaction between opaque ore and adjacent cordierite, rather than by replacement of spinel.Two high-grade metamorphic episodes appear to be necessary for högbomite growth, one determining chemical composition and the other appropriate physical parameters. In the Connemara occurrences thermal metamorphism and partial melting, coupled with contamination of the surrounding magma, controlled the formation of mineral assemblages rich in Fe, Mg, Al, Ti, and Zn. Emplacement of the intrusion was accompanied by amphibolite facies regional metamorphism and it is to this metamorphic event that the growth of högbomite may be attributed.
The partial melting of basalt and its enclosed mineral-filled cavities at Scawt Hill, Co. Antrim
Authors: Kitchen D. E. 
Published: December 2006

AbstractPartially melted basalts enclosing amygdales which have been completely melted formed at Scawt Hill adjacent to a Tertiary dolerite plug. Melting of the basalts commenced in a clay-rich mesostasis to produce a feldspathic liquid which then crystallized to an assemblage of dendritic olivine, skeletal hypersthene, opaque oxide and Mg-hercynite in a microcrystalline plagioclase matrix. An original mineral assemblage of zeolite, calcite, and saponite-nontronite in the amygdales melted and quenched to a brown glass now containing complexly zoned pyroxenes with plagioclase and opaque oxide. Melting commenced between 700–800°C, reaching a maximum temperature of 1168°C, and was followed by rapid cooling. The assimilation of remelted basalt may alter the course of crystallization of contaminated magmas.
Dynamic biaxial absorption spectra of Ti3+ and Fe2+ in a natural rose quartz crystal
Authors: Cohen A. J. , Makar L. N. 
Published: December 2006

AbstractThe absorption spectrum of Ti3+ in quartz is typical for that element in an octahedral site, except for the high oscillator strength of the band which indicates intensive charge transfer, most likely between a substitutional Ti4+ and an interstitial Ti3+. The biaxial anisotropy of the band is similar to that of octahedral Fe2+ in the same crystal, suggesting the same site for the Ti3+, an interstitial site at the intersection of the threefold axis with two twofold axes. The dynamic nature of the Ti and Fe ions is indicated when the crystal is subjected to X-irradiation and then to bleaching treatment with UV-light or heat. Ti(IV) ions are acceptors of electrons donated by Fe2+ during X-irradiation. This is indicated by increase of the 2.4 eV band intensity with decrease in the Fe2+ band intensities and appearance of Fe3+ charge transfer bands in the UV-region. Heat and UV-light treatment decrease the Fe3+ CT bands and increase the Fe2+ crystal-field bands along with decrease in the 2.4 eV band related to titanium.
Uranoan thorite in lithophysal rhyolite–Topaz Mountain, Utah, USA
Authors: Foord Eugene E. , Cobban Robert R. , Brownfield Isabelle K. 
Published: December 2006

AbstractUranoan thorite crystals have been found occurring as a sparse constituent in lithophysae in 6.1 to 6.8 Ma alkali rhyolite flows at Thomas Mountain, Utah, USA. The crystals are associated with sandidine, quartz, topaz, hematite, magnetite, and calcite; they are leek to dark grass green, transparent, well-formed, euhedral prisms, showing development of forms {100}, {101}, and {111}. The mineral is both optically isotropic, with a refractive index of 1.86(1), and X-ray amorphous, indicating its metamict state. Electron microprobe analysis yields: SiO2 17.3, ThO2 56.8, UO2 25.4, total 99.5%, and a structural formula of (Th0.72U0.31)Σ1.03Si0.97O4.This appears to be the first reported occurrence of thorite in volcanic rocks of rhyolitic composition, and may account for part or all of the Th reported in alkali rhyolites and so-called ‘topaz-rhyolites’ of the western USA.
Genesis of chrysoberyl in the pegmatites of southern Kerala, India
Authors: Soman K. , Nair N. G. K. 
Published: December 2006

AbstractIn southern Kerala, India, chrysoberyl occurs in granitic pegmatites in association with quartz in alkali feldspar and is thought to crystallize earlier than beryl and sillimanite. The pegmatites are thought to have derived from the residual melts of granitic liquids formed by partial melting of the khondalites. In the absence of pyrometasomatic, desilication or aluminium-contamination processes, the genesis of chrysoberyl is explained by the CO2activity in residual melts. This model is at variance with the known concepts and may also explain the genesis of chrysoberyl in Sri Lanka where it is still controversial.
Ion microprobe determination of rare earth elements in accessory minerals
Authors: Reed S. J. B. 
Published: December 2006

AbstractThe application of ion microprobe analysis to REE determination is discussed, with special reference to REE-bearing accessory minerals (e.g. allanite, monazite, apatite, xenotime, sphene). The main analytical problems are shown to be (a) interferences in the mass spectrum caused by molecular ions, and (b) matrix effects, i.e. variations in ion yield with sample composition. Interference suppression using either high mass resolution or secondary-ion energy discrimination is fairly effective, but entails a significant sacrifice in peak intensity. In the absence of a viable model for predicting matrix effects, it is proposed that empirical standardization should be used. Often better absolute accuracy can be obtained by combining ion microprobe and electron microprobe data for REE present in sufficiently high concentrations. Detection limits for REE are in the part per million region at present, with spatial resolution typically around 10 μm, but there is considerable scope for improvement. Better standards and improved understanding of matrix effects should also lead to greater accuracy in quantitative analysis.
Stability constants and formation of Cu(II) and Zn(II) phosphate minerals in the oxidized zone of base metal orebodies
Authors: Clara M. , Magalhães F. , de Jesus Julio Pedrosa , Williams Peter A. 
Published: December 2006

AbstractThe free energies of formation of the minerals libethenite, Cu2PO4OH, pseudomalachite, Cu5(PO4)2(OH)4, cornetite, Cu3PO4(OH)3, tarbuttite, Zn2PO4OH, spencerite, Zn2PO4OH · 1.5H2O, and scholzite, CaZn2(PO4)2 · 2H2O, have been determined at 298.2 K using solution techniques. The values of ΔfG° (298.2 K) for the above minerals are, respectively, −1228.8±3.0, −2840.3±4.2, −1600.9±5.9, −1632.1±4.0, −1982.4±3.1, and −3556.7±7.6 kJ mol−1. These results, together with others from the literature concerning hopeite, Zn3(PO4)2·4H2O, hydroxyapatite, Ca5(PO4)3(OH), and the synthetic salt Cu3(PO4)2 · 2H2O have been used to construct a model for the formation of suites of Zn(II) and Cu(II) phosphate minerals found in the oxidation zone of base metal orebodies. The distributions and modes of occurrence of many natural assemblages of these minerals are readily explained by the model. Particular attention has been focused on deposits at Broken Hill, Zambia, and Saginaw Hill, Arizona, USA.
Ferrierite from Tapu, Coromandel Peninsula, New Zealand, and a crystal chemical study of known occurrences
Authors: Sameshima T. 
Published: December 2006

AbstractFerrierite has been found at Tapu, Coromandel Peninsula, New Zealand, as a mineral vein with calcite in altered hornblende andesite lava of the Miocene Beeson's Island Volcanics. The ferrierite is low in SiO2 (63.67%) and high in Al2O3 (13.75%), MgO (3.48%), and BaO(2.35%). The large a axis and cell volume (a 19.236(4), b 14.162(6), c 7.527(3) Å, V 2050 Å3) are consistent with the low SiO2, high Al2O3, high MgO chemistry. Optical orientation and optical sign (a = Z, b = X, c = Y, 2V(-)55°) of the mineral are different from those of the Lake Kamloops ferrierite reported by Graham (1918). Refractive indices α 1.487, γ 1.489, and density 2.136 were measured. Cleavage observed on (100) is perfect and on (001) is imperfect. Using data from eighteen occurrences so far reported including the Tapu mineral, the crystal chemistry of ferrierite has been studied.
Detrital and authigenic minerals in sediments from the western part of the Indian Ocean
Authors: Tsirambides A. E. 
Published: December 2006

AbstractMineralogical and oxygen isotope analyses have been performed on nine western Indian Ocean core samples in order to distinguish the detrital from authigenic minerals in the sediments. Following the removal of carbonates, organic constituents and Fe and Mn oxides, the residue was separated into five size fractions, the principal minerals present being feldspar, quartz, clinoptilolite, and clay minerals.Oxygen isotope compositions for two samples reflect an authigenic origin for clinoptilolite by the submarine alteration of volcanic material. Oxygen isotope compositions of two separates (free from feldspar and clays) suggest a detrital origin for the quartz in this area. The same mode of origin is apparent for the other components too, except possibly for some smectite which may have formed authigenically.
A new barium uranyl oxide hydrate mineral, protasite
Authors: Pagoaga M. K. , Appleman D. E. , Stewart J. M. 
Published: December 2006

AbstractProtasite, a new barium-containing member of the uranyl oxide hydrate group, occurs as bright orange pseudo-hexagonal platelets associated with uraninite and uranophane on unidentified rock matrix from Shinkolobwe mine, Zaïre. Protasite is monoclinic, Pn with a 12.295(2), b 7.221(1), c 6.9558(8) Å, β 90.40(2)°, and V 617.50(11) Å3. The tabular pseudo-hexagonal crystals are flattened on {010}, 0.1 mm to 0.5 mm wide and up to 0.1 mm thick. They are biaxial negative, 2 V = 60–65°, β and γ 1.79–1.83, and X = b. Sector twinning is common. Microprobe analysis shows BaO 15.0, UO3 78.0, H2O(diff.) 7.0%. The structural formula is Ba[(UO2)3O3(OH)2]. 3H2O, Z = 2, and density(calc.) = 5.827(3) g cm−3. Complete crystal-structure analysis shows protasite to be the simplest model structure of the uranyl oxide hydrate group.
The crystal chemistry of rhodizite: a re-examination
Authors: Pring A. , Din V. K. , Jefferson D. A. , Thomas J. M. 
Published: December 2006

AbstractThe crystal chemistry of rhodizite was re-examined using data from high-resolution electron microscopy (HREM), magic angle spinning nuclear magnetic resonance (MASNMR), a single crystal X-ray structure refinement, and a new chemical analysis. The analysis calculates to the formula: (K0.46Cs0.36Rb0.06 Na0.02)Σ0.90Al3.99Be4(B11·35Be0.55Li0.02)O28· The distribution of alkali cations was shown to be truly random by HREM images and computer image simulations. The distribution of boron and beryllium was monitored by MASNMR, the spectra for both elements gave only single resonances indicating that all beryllium and boron atoms are located in chemically equivalent sites. The structure of rhodizite was refined by single crystal X-ray diffraction techniques. The mineral is cubic a = 7.318(1) Å, space group P3. A full matrix least-squares refinement using 152 unique observed reflections [F > 3σ(F)] converged to R = 0.0344. The refinement confirmed the basic structure as determined by Taxer and Buerger (1967), 4 beryllium atoms of the unit cell were found to occupy a 4e special position, the remaining 0.5 being randomly distributed with the 11.35 boron atoms over the 12h sites.