bluuebunny/crossref_metadata_2025_split huggingface dataset:
Effect of Concentration on Sorption of Dissolved Organics by PVC, PTFE, and Stainless Steel Well Casings
Authors: Parker Louise V. , Ranney Thomas A. 
Published: February 2007

AbstractThis report examines sorption of low ppb levels of organic solutions by polytetra‐ fluoroethylene (PTFE), rigid polyvinyl chloride (PVC), and stainless steel 304 and 316 well casings. Nineteen organics were selected, including several munitions and chlorinated solvents. Compounds were selected to offer a range of physical properties, such as solubility in water, octanol/water partition coefficient, and molecular structure. When these results were compared with the results from a similar study conducted at ppm levels, the rate and extent of sorption by PTFE and PVC were the same as seen previously for almost all analytes. There were no losses of any compounds associated with stainless steel. At these low levels (ppm and ppb), the rate of diffusion within the polymer (PVC and PTFE) is independent of concentration. Only with PTFE are the rates rapid enough to be of concern when monitoring for some contaminants in ground water. Tetrachloroethylene was the compound PTFE sorbed the most rapidly. The study showed that PVC well casings are suitable for monitoring low levels (ppm and ppb) of organics.
Vertical Distribution and Partitioning of Chromium in a Glaciof luvial Aquifer
Authors: Nikolaidis Nikolaos P. , Robbins Gary A. , Scherer Michelle , McAninch Brian , Binkhorst Gordon , Asikainen Jay , Suib Steven L. 
Published: February 2007

AbstractThe vertical distribution and partitioning (between the solid and aqueous phase) of chromium in a glaciofluvial aquifer in northeastern Connecticut were assessed. Most of the chromium (99 percent of its mass) is bound to the soil. Retardation is primarily the result of binding to organic matter and adsorption to iron oxide coatings. However, other attenuation mechanisms also appear to be significant. If the degree of chromium binding observed here is representative of other chromium contaminated sites, pump‐and‐treat remediation will not remove the vast amount of chromium from the subsurface. However, most of the chromium may be immobile, and removal may not be required following the initial pumping to remove the mobile fraction. Further knowledge of the mechanisms that bind chromium to the soil, their reversibility, and their kinetics is essential to developing effective remediation strategies.
Evaluation of an Ultrafiltration Method for Surfactant Recovery and Reuse During In Situ Washing of Contaminated Sites: Laboratory and Field Studies
Authors: Ang Carolina C. , Abdul Abdul S. 
Published: February 2007

AbstractFeasibility studies were conducted on the use of ultrafillration to recover surfactant from aqueous waste streams generated from the in situ surfactant washing of a site contaminated with poly‐chlorinated biphenyls (PCBs) and oils. A Romicon Model HF‐Lab‐5 ultrafiltration unit and three types of ultrafillration membranes (PM500, XM50, and CM50) were evaluated for their permeability to a nonionic surfactant previously selected for the in situ washing. Results from laboratory studies using the XM50 membrane cartridge showed that 78 percent of the surfactant passed through the membrane surface (permeate) and was recovered.Two field‐pilot tests of the ultrafiltralion system were conducted using leachate containing a mixture of water, oils, PCBs, and surfactant that was collected from an in situ surfactant‐washing demonstration test. Forty‐six percent of the surfactant (mass) was recovered during the first field test using the XM50 membrane. The membrane retained 94 percent of the PCBs and 89 percent of the oils. The second field test showed that the PM500 membrane recovered 67 percent of the surfactant in the permeate and retained more than 90 percent and 83 percent of the PCBs and oils, respectively. This study indicates that a significant volume of a nonionic surfactant can be recovered from leachatc mixture containing PCBs and oils by ultrafillration. The recovered surfactant could be reused to improve the economic viability of in situ surfactant washing of contaminated sites.
A Conceptual Model of Field Behavior of Air Sparging and Its Implications for Application
Authors: Ahlfeld David P. , Dahmani Amine , Ji Wei 
Published: February 2007

AbstractThe basic physics of air flow through saturated porous media are reviewed and implications arc drawn for the practical application of air sparging. A conceptual model of the detailed behavior of an air sparging system is constructed using elements of multiphase flow theory and the results of recent experimental work. Implications of the conceptual model on air sparging topics are discussed. The meaning of radius of influence in the context of air sparging is found to be ambiguous. The hydrodynamic effects of air sparging such as mounding of ground water and flow impedance are explored. Limitations on rates of remediation and operational strategics for improving sparging effectiveness are examined.
The Application of Petroleum Hydrocarbon Fingerprint Characterization in Site Investigation and Remediation
Authors: Zemo Dawn A. , Bruya James E. , Graf Tom E. 
Published: February 2007

AbstractTremendous resources have been and continue to be spent investigating and remediating petroleum hydrocarbon compounds (PHCs) in soil and ground water. Investigating and planning a remedial strategy for sites affected by PHCs is often a challenging task because of the complex chemical nature of the PHCs. the complex regulatory environment related to PHC cleanup, and the use of analytical methods that provide quantitation but not identification of PHCs. From a technical standpoint, the PHC impacting soil and/or ground water is frequently inadequately characterised, both in identification as well as in is general properties (solubility, toxicity). From a regulatory standpoint, promulgated or recommended total petroleum hydrocarbon (TPH) cleanup levels generally relate to assumed properties of specific unweathered products and are inconsistent among different agencies and regions. This produces a prime situation for unwillingly spending more resources on investigation or remediation than may be necessary, especially when the PHC in the subsurface has different properties from unweathered products such as gasoline or diesel.Accurately identifying the PHC and its nature, a process known as fingerprint characterization, is critical to the determination of appropriate regulatory goals and design of cost‐effective remedial approaches. This paper presents several case studies in which fingerprint characterization made a significant difference in the project outcome. In each instance the nature of the organic material was better understood, the regulatory cleanup levels were negotiated based on the nature of the material, and a remedial approach was implemented that differed significantly from and was generally less costly than what would have been required without fingerprint characterization data.
A Model for Determination of the Phase Distribution of Petroleum Hydrocarbons at Release Sites
Authors: Mott Henry V. 
Published: February 2007

AbstractA model and computer‐based numeric approximation for computing the equilibrium distributions of contaminants at petroleum release sites is presented. A database of contaminant‐specific parameters, including solubility and organic‐carbon partitioning coefficient, is assembled. Applications and limitations of the model are discussed.
Micro‐Purge Low‐Flow Sampling of Uranium‐Contaminated Ground Water at the Fernald Environmental Management Project
Authors: Shanklin D.E. , Sidle W.C. , Ferguson M.E. 
Published: February 2007

AbstractEfforts to sample representative, undisturbed distributions of uranium in ground water beneath the Fernald Environmemal Management Project (FEMP) prompted the application of a novel technique that is less invasive in the monitoring well. Recent studies (Kearl et al. 1992; Barcelona et al. 1994) indicate that representative samples can and should be collected without prior well volume exchange purging or borehole evacuation. Field experiments conducted at the FMMP demonstrate that under specific sampling conditions in a welldefined hydrogeologic system, representative ground water samples for a monitoring program can be obtained without removing the conventional three well volumes from the well. The assumption is made that indicator parameter equilibration may not be necessary to determine when to collect representative samples at the P'liMP. Preliminary results obtained from the field experiment suggest that this may be true. The technique employs low purge rates (< 1 L/min) with dedicated bladder pumps with inlets located in the screened interval of the well, while not disturbing the stagnant water column above the screened interval. If adopted, this technique, termed micro‐purge low‐flow sampling, will produce representative ground water samples, significantly reduce sampling costs, and minimize; waste water over the monitoring life cycle at the FEMP. This technique is well suited for sites that have been fully characterized and are undergoing long‐term monitoring.
Developing A National Drinking Water Regulation for Disinfection of Ground Water
Authors: Macler Bruce A. 
Published: February 2007

AbstractThe Safe Drinking Water Act directs EPA to promulgate requirements for disinfection of ground water‐based drinking water systems. The Ground‐ water Disinfection Rule regulatory workgroup, made up of representatives from EPA, the states, and other interested parties, is actively considering the issues for the wide range of elements necessary to ensure a regulation that will protect public health and can be feasibly implemented. This regulation is likely to require disinfection of ground water sources and systems found to be contaminated or vulnerable to contamination.
Tracer Test to Evaluate Dilution of Ground Water from Lost Circulation
Authors: Schilling Keith E. , Hoyle Blythe L. 
Published: February 2007

AbstractLost circulation, the inadvertent injection of drilling fluids into a highly permeable and/or fractured aquifer during rotary drilling, may result in collection of spurious information if the lost drilling fluids are not adequately purged before sampling the ground water. The purpose of this study was to determine whether removal of the volume of water lost during coring of a monitoring well in the carbonate Scotch Grove Formation (Silurian, east central Iowa) necessarily ensures collection of representative ground water samples. To monitor dilution of the ground water due to lost circulation, rhodamine dye was added to the drilling water and dye recovery was measured in samples collected during purging of five separate 5‐ to 10‐foot intervals.Circulation loss occurred in all five intervals, ranging from nearly 200 gallons in the upper permeable portion of the Scotch Grove to 25 gallons in the less permeable Buck Creek Member below. When the volume of water purged from the upper three intervals corresponded to the volume of water lost during coring, the purge water still contained 11 to 20 percent dyed drilling water. As purging continued, the proportion of drilling water in the samples decreased slowly. After purging more than 200 gallons of water, 86 to 98 percent of the dyed drilling water was recovered from the five test intervals. Four traditionally measured water quality parameters‐pH, temperature, specific conductance, and dissolved oxygen — were less useful than the dye recovery for distinguishing drilling water from formation water in those zones in which the ground water quality was similar to the drilling water. These results indicate that the determination of the quantity of water to be purged prior to sampling must be based, at least in part, on aquifer lithology and hydraulic characteristics.
Monitoring Air Sparging Using Resistivity Tomography
Authors: Schima Susan , LaBrecque Douglas J. , Lundegard Paul D. 
Published: February 2007

AbstractAir sparging is a relatively new technique for the remediation of ground water contaminated with petroleum hydrocarbons. In this technique, air is injected below the water table, beneath the contaminated soil. Remediation occurs by a combination of contaminant partitioning into the vapor phase and enhanced biodegradation. The air is usually removed by vacuum extraction in the vadose zone.The efficiency of remediation from air sparging is a function of the air flow pattern, although the distribution of the injected air is still poorly understood. Cross‐borehole resistivity surveys were performed at a former service station in Florence, Oregon, to address this unknown. The resistivity measurements were made using six wells, one of which was the sparge well. Data were collected over a two‐week period during and after several air injections, or sparge events. Resistivity images were calculated between wells using an algorithm that assumes axially symmetric structures. The movement of the injected air through time was defined by regions of large increases in resistivity, greater than 100 percent from the background. During early sparge times, air moved outward and upward from the injection point as it ascended to the unsaturated zone. At later sparge times, the air flow reached a somewhat stable cone‐shaped pattern radiating out and up from the injection point. Two days after sparging was discontinued, a residue of entrained air remained in the saturated zone, as indicated by a zone of 60 to 80 percent water saturation.
Risk‐Based Engineering Design for a Landfill Leachate Collection and Liner System
Authors: Murray Gordon B. , McBean Edward A. , Sykes Jonathan F. 
Published: February 2007

AbstractA methodology is used to identify the tradeoffs between costs and exposure risk associated with landfill leachate collection and low permeable systems. The results are useful in demonstrating the point at which additional levels of sophistication in design of a leachate/liner system do not produce significant reductions of exposure risk. The case study application to the Durham Regional landfill demonstrates that clay liner hydraulic conductivity is the parameter with the largest influence on the risk of exceedance at the point of compliance. When the underlying clay is more permeable, there is a significant merit associated with use of a QA/QC program.
A Sample‐Freezing Drive Shoe for a Wire Line Piston Core Sampler
Authors: Murphy Fred , Herkelrath W. N. 
Published: February 2007

AbstractLoss of fluids and samples during retrieval of cores of saturated, noncohesive sediments results in incorrect measures of fluid distributions and an inaccurate measure of the stratigraphic position of the sample. To reduce these errors, we developed a hollow drive shoe that freezes in place the lowest 3 inches (75 mm) of a 1.88‐inch‐diameter (48 mm), 5‐foot‐long (1.5 m) sediment sample taken using a commercial wire line piston core smapler. The end of the core is frozen by piping liquid carbon dioxide at ambient temperature through a steel tube from a bottle at the land surface to the drive shoe where it evaporates and expands, cooling the interior surface of the shoe to about ‐ 109°F (‐ 78°C). Freezing a core end takes about 10 minutes. The device was used to collect samples for a study of oil‐water‐air distributions, and for studies of water chemistry and microbial activity in unconsolidated sediments at the site of an oil spill near Bemidji, Minnesota. Before freezing was employed, samples of sandy sediments from near the water table sometimes flowed out of the core barrel as the sampler was withdrawn. Freezing the bottom of the core allowed for the retention of all material that entered the core barrel and lessened the redistribution of fluids within the core. The device is useful in the unsaturated and shallow saturated zones, but does not freeze cores well at depths greater than about 20 feet (6 m) below water, possibly because the feed tube plugs with dry ice with increased exhaust back‐pressure, or because sediment enters the annulus between the core barrel and the core barrel liner and blocks the exhaust.
In Situ Remediation of Jet A in Soil and Ground Water by High Vacuum, Dual Phase Extraction
Authors: Kirshner Marvin , Pressly Nicholas C. , Roth Robert J. 
Published: February 2007

AbstractThis report summarizes the initial results of subsurface remediation at Terminal 1, Kenneth International Airport, to remediate soil and ground water contaminated with Jet A fuel. The project was driven and constrained In the const ruction schedule of a major new terminal at the facility. The remediation system used a combination of ground water pumping, air injection, and soil vapor extraction. In the first five months of operation, the combined processes of dewatering, volatilization, and biodegradation removed a total of 36,689 pounds of total volatile and semivolatile organic jet fuel hydrocarbons from subsurface soil and ground water. The. results of this case study have shown that 62 percent of the removal resulted from biodegradation, 21 percent occurred as a result of liquid removal, and 11 percent resulted from the extraction of volatile organic compounds (VOC's).
Effect of Various Materials in Multilevel Samplers on Monitoring Commonly Occurring Agrichemicals in Ground Water
Authors: Papiernik Thomas D. , Widmer Sharon K. , Spalding Roy F. 
Published: February 2007

AbstractStudies have shown that materials, such us polytetra‐fluoroethylene (PTFE), rigid polyvinyl chloride (rigid PVC). flexible polyvinyl chloride (flexible PVC), stainless steel (SS). low‐density polyethylene (LDPE), and high‐density polyethylene (HDPE), have the potential to influence certain analyte concentrations in ground water samples. The effects of HDPE, LDPE, PTFE, rigid PVC, and SS on aqueous concentrations of nitrate‐N, atrazine, deethylatrazine (DEA), and deisopropylatrazine (DIA) were evaluated in a field study A laboratory study was conducted to evaluate sorption of atrazine DEA, DIA, cyanazine, alachlor, metolachlor, and butachlor to PTFE, HDPE, and SS materials. Butachlor is rarely use in the United States, but was included because of its expected high sorptivity. No significant differences between HDPE, LDPE, PTFE, rigid PVC, and SS were determined for any of the analytes tested in the field study. In the laboratory study, sorption of DIA to PTFE and SS was significant at 2.6 × 10−5 and 4.1 × 10−5μg/m2 respectively. Sorption of DIAA to HDPE was not significantly > 0 sorption of all other compounds to HDPE, PTFE, and SS were also not significantly >0. Results of the two studies indicate that for these analytes (relatively polar or ionized compounds), representative ground water samples are not dependent on the materials used for multilevel sampler construction. When considering these compounds, it appears that the least expensive materials (HDPE, rigid PVC, and LDPE) are good choices for the construction of ground water monitoring wells.
Nickel and Chromium in Ground Water Samples as Influenced by Well Construction and Sampling Methods
Authors: Oakley D. , Korte N.E. 
Published: February 2007

AbstractAn investigation of elevated concentrations of nickel and chromium in certain ground water samples collected at Williams Air Force Base (AFB) indicated that type 304 stainless steel well materials are the source. Chloride in the ground water has apparently caused crevice corrosion of the stainless steel well screens installed during site characterization. An evaluation of site geochemistry suggested that chromium released from the well screen would precipitate, while nickel would remain dissolved. Thus, low‐flow purging and sampling significantly reduces the chromium found in the ground water samples because such sampling minimizes the collection of artificially entrained particulates. In contrast to chromium, nickel concentrations did not decrease during low‐flow purging and sampling, indicating that it is dissolved. Nickel and chromium concentrations are both low following high‐volume purging when turbidity levels are stabilized below 10 nephelometric turbidity units prior to sampling. In the latter case, chromium concentration is low because particulate collection is minimized, and nickel concentration is low because of increased dilution. Based on these results, it is recommended that elevated levels of nickel and chromium in ground water samples collected from stainless steel monitoring wells be carefully evaluated, because well materials may be the source. In addition, although low‐volume purging is increasingly becoming the sampling method of choice, high‐volume purging may be a useful means of determining whether the well materials influence nickel and chromium concentrations.
Ground Water Discharge of Agricultural Pesticides and Nutrients to Estuarine Surface Water
Authors: Gallagher Daniel L. , Dietrich Andrea M. , Reay William G. , Hayes Mary C. , Simmons George M. 
Published: February 2007

AbstractThis research investigated the transport of land‐applied nutrients and pesticides from unconfined aquifers to tidal surface waters of Virginia's coastal plain. Ground water, estuarine surface water, ground water discharge, upland soil, and offshore sediment samples were collected from May 1992 until February 1993 from four agricultural sites. Samples were analyzed for inorganic nitrogen and phosphorus and five pesticides: atrazine, cyanazine, alachlor, metolachlor, and carbofuran. Pesticides from aqueous samples were determined by liquid‐solid phase extraction followed by gas chromatography‐electron capture detection (GC‐ECD) and/or by pesticide‐specific immunoassay. Soil and sediment samples were analyzed by extraction and gas chromatography/mass spectrometry (GC/MS). Nutrient measurements indicated that fertilizer nitrogen was moving from the ground water to the surface water, and nitrogen fluxes across the sediment‐water interface were correlated with fresh water discharge rates. Mean nitrate‐N flux was 2.48 mg/m2hr, with a maximum value of 30.98 mg/m2hr. Pesticides were detected in more than half of the upland soil samples, in approximately 40 percent of the ground water samples, and in just under 20 percent of the seepage meter samples. Pesticides were not detected in any of the offshore sediment samples or surface water samples. Alachlor and metolachlor were detected in upland soil samples at concentrations ranging from 10 to almost 500 μg/kg. All five pesticides were found in ground water samples at concentrations generally below 1 μg/L, with alachlor, atrazine, and metolachlor most frequently found. Alachlor, atrazine, cyanazine, and metolachlor were detected in water discharging across the sediment‐water interface and entering estuarine waters at concentrations ranging from 0.05 to 0.5 μg/L. These levels were generally consistent with the amount of dilution due to the mixing of fresh ground water and saline pore waters prior to discharge across the sediment‐water interface. Based on all positive detections of pesticides in ground water discharge, which represented approximately 18 percent of all samples, average flux rates of cyanazine, metolachlor, alachlor, and atrazine were 0.32, 0.37, 0.80, and 1.12 μg/m2hr, respectively. These findings indicate that submarine ground water transport of both nutrients and pesticides does occur, and this transport route should be considered when implementing agricultural management practices. The levels of nitrogen transport to surface water appears significant. The overall levels of pesticide movement through ground water, although generally quite low, represent a transport route that is commonly neglected in watershed management.