bluuebunny/crossref_metadata_2025_split huggingface dataset:
Molecular lines in the envelopes of evolved stars
Authors: Zhang Yong , Kwok Sun , Trung Dinh-V- 
Published: October 2008

AbstractWe report a spectral line survey of the circumstellar envelopes of evolved stars at millimeter wavelengths. The data allow us to investigate the chemical processes in different physical environments and evolutionary stages. A total of more than 500 emission features (mostly rotational transitions of molecules) are detected in the survey. Our observations show that the sources in different evolutionary stages have remarkably different chemical composition. As a star evolves from AGB stage to proto-planetary nebula, the abundances of Si-bearing molecules (SiO, SiCC, and SiS) decrease, while the abundances of some long-chain molecules, such as CH3CN, C4H, and HC3N, increase. After further evolution to planetary nebula, the abundances of neutral molecules dramatically decrease, and the emission from molecular ions becomes more intense. These differences can be attributed to the changes of the role that dust, stellar winds, shock waves, and UV/X-rays from the central star play in different evolutionary stages. These results will provide significant constraints on models of circumstellar chemistry.
The 1 mm spectrum of VY Canis Majoris: Chemistry in an O-rich envelope
Authors: Tenenbaum Emily D. , Milam Stefanie N. , Apponi Aldo J. , Woolf Neville J. , Ziurys Lucy M. , Schöier Fredrik L. 
Published: October 2008

AbstractWe present preliminary results of an unbiased spectral survey at 1 mm of the oxygen-rich supergiant, VY CMa. A number of exotic molecules have been detected, including NaCl and PO, and a relatively rich organic chemistry is observed. Results of the survey will be compared with carbon-rich stars.
HCO+ emission possibly related with a shielding mechanism that protects water molecules in the young PN K 3-35
Authors: Gómez Y. , Tafoya D. , Anglada G. , Loinard L. , Torrelles J. M. , Miranda L. F. , Osorio M. , Franco-Hernández R. , Nyman L. , Nakashima J. , Deguchi S. 
Published: October 2008

AbstractWater maser emission has been detected only toward three planetary nebulae (PNe). In particular, in K3-35, the first PN where water vapor maser emission was detected, the components are located in a torus-like structure with a radius of 85 AU and also at the surprisingly large distance of 5000 AU from the star, in the tips of the bipolar lobes. The existence of these water molecules in PNe is puzzling, probably related to some unknown mechanism shielding them against the ionizing radiation. We report the detection of HCO+ (J = 1 − 0) emission toward K 3-35, that not only suggests that dense molecular gas (~105 cm−3) is present in this PN, but also that this kind of PN can enrich their surroundings with organic molecules.
Synthesis of organic compounds in the circumstellar environment
Authors: Kwok Sun 
Published: October 2008

AbstractThrough the techniques of millimeter-wave and infrared spectroscopy, over 60 species of gas-phase molecules and a variety of inorganic and organic solids have been detected in the short phase of stellar evolution between the asymptotic giant branch and planetary nebulae. The chemical pathways that lead to the synthesis of complex organic compounds in such low-density environments are therefore important topics of astrochemistry. In this review, we summarize the observational evidence for the existence of complex aliphatic and aromatic compounds in these circumstellar environments, and discuss the nature of their possible carriers. Also discussed are a number of unidentified emission features which may also have an organic origin. The possible relations between these circumstellar organic matter with Solar System organic matter are explored.
A Spitzer Space Telescope study of dust features in planetary nebula and Hii regions
Authors: Bernard-Salas Jeronimo , Peeters Els , Lebouteiller Vianney , Sloan Gregory C. , Brandl Bernhard R. , Houck James R. 
Published: October 2008

AbstractOne of the key questions of infrared astronomy is how the characteristics of dust depend on the physical properties of the surrounding medium. To address this question, we present results from the Spitzer Space Telescope on two projects designed to study the dust properties of a sample of 25 Planetary Nebulae (PNe) in the Magellanic Clouds, and three well-known Giant Hii regions (NGC 3603, 30 Doradus and N 66/NGC 346). Most PNe show emission from polycyclic aromatic hydrocarbons (PAHs) and only two of them show amorphous silicates. Eleven PNe display a strong broad feature around 11 μm which is attributed to silicon carbide and 8 of them show magnesium sulfide. One PNe, SMP LMC 11, shows spectacular absorption bands due to molecules which are the precursors from which more complex hydrocarbons are formed. The Spitzer spectra of the Hii regions, NGC 3603, 30 Doradus, and NGC 346 are very rich, displaying a wealth of spectral features within each region. This not only allows us to compare the dust at different metallicities but also to study the spatial variations of many features across a given region and correlate it with the distance to the ionizing cluster(s) and other parameters.
Spitzer spectroscopy of unusual hydrocarbons in cool radiative environments
Authors: Sloan G. C. 
Published: October 2008

AbstractThe Spitzer Space Telescope has discovered several objects with unusual spectra, where the emission features from polycyclic aromatic hydrocarbons (PAHs) are shifted to longer wavelengths than normally observed. Previously, only two of these class C PAH spectra had been identified. The new and larger sample reveals that PAHs emit at longer wavelengths when processed by cooler radiation fields. Limited laboratory data show that samples with mixtures of aromatic and aliphatic hydrocarbons produce emission features at longer wavelengths than purely aromatic samples. The aliphatic bonds are more fragile and would only survive in cooler radiation fields. In harsher radiation fields, the aliphatics attached to the aromatic hydrocarbons are destroyed.
Carbon-rich AGB stars in our Galaxy and nearby galaxies as possible sources of PAHs
Authors: Matsuura M. , Sloan G. C. , Bernard-Salas J. , Zijlstra A. A. , Wood P. R. , Whitelock P. A. , Menzies J. W. , Feast M. , Lagadec E. , Groenewegen M. A. T. , Cioni M. R. , van Loon J. Th. , Harris G. 
Published: October 2008

AbstractWe have obtained infrared spectra of carbon-rich AGB stars in three nearby galaxies – the Large and Small Magellanic Clouds, and the Fornax dwarf spheroidal galaxy. Our primary aim is to investigate gas compositions and mass-loss rate of these stars as a function of metallicity, by comparing AGB stars in several galaxies with different metallicities. C2H2are detectable from AGB stars, and possibly PAHs are subsequently formed from C2H2. Thus, it is worth investigating chemical processes at low metallicity. These stars were observed using the Infrared Spectrometer (irs) onboard theSpitzer Space Telescopewhich covers 5–35 μm region, and the Infrared Spectrometer And Array Camera (isaac) on the Very Large Telescope which covers the 2.9–4.1 μm region. HCN, CH and C2H2molecular bands, as well as SiC and MgS dust features are identified in the spectra. The equivalent width of C2H2molecular bands is larger at lower metallicity, thus PAHs might be abundant in AGB stars at low metallicity. We find no evidence that mass-loss rates depend on metallicity. Chemistry of carbon stars is affected by carbon production during the AGB phase rather than the metallicities. We argue that lower detection rate of PAHs from the interstellar medium of lower metal galaxies is caused by destruction of PAHs in the ISM by stronger UV radiation field.
PAH anions as carriers of the mid-IR emission bands in planetary nebulae
Authors: Szczerba Ryszard , Joblin Christine , Berné Olivier , Szyszka Cezary 
Published: October 2008

AbstractWe present results of the mid-IR spectra decomposition for planetary nebulae and compact H ii regions in our Galaxy and Magellanic Clouds. The striking correlation between the required PAH component with “7.7” μm band shifted to about 7.8 μm and electron densities of the modeled sources allows us to argue that this PAH component may be in fact PAH anions (PAH−).
On the inorganic carriers of the 21 micron emission feature in post-AGB stars
Authors: Zhang Ke , Jiang Biwei , Li Aigen 
Published: October 2008

AbstractThe mysterious 21 μm emission feature seen in only 12 C-rich proto-planetary nebulae (PPNe) remains unidentified since its discovery in 1989. Over a dozen materials have been suggested as the carrier candidates while none of them has received general acceptance. We investigate the inorganic carrier candidates by applying the observational constraints of the feature strength and associated features. It is found that: (1) three candidates, TiC clusters, fullerenes with Ti impurity atoms, and SiS2, are not abundant enough to account for the emission power of the 21 μm band, (2) five candidates, doped-SiC, SiO2-mantled SiC dust, carbon and silicon mixtures, Fe2O3, and Fe3O4, all show associated features which are either not detected in the 21 μm sources or detected but with a much lower strength, and (3) FeO, which satisfies the abundance constraints, does not display any associated features which are not seen in the 21 μm sources. Moreover, FeO is more likely to survive in the C-rich environment than Fe2O3and Fe3O4. Thus FeO seems to be the most plausible one among the inorganic carrier candidates.
Dust properties in the circumstellar shells of evolved stars: Observational constraints from ISO and Spitzer infrared spectroscopy
Authors: García-Lario P. , Calderón J. V. Perea , García-Hernández D. A. , Stanghellini L. , Engels D. , Manchado A. , Davies J. E. , Villaver E. , Shaw R. A. , Bobrowsky M. 
Published: October 2008

AbstractWe present the results of a systematic analysis of the solid state features identified in the circumstellar environments of a large sample of evolved stars with ISO/SWS and Spitzer/IRS spectroscopy. The sample includes several hundred stars with a wide variety of progenitor masses evolving from the early AGB phase to the PN stage. Our observations are used to propose an evolutionary scheme in which the results obtained can be interpreted as a consequence of the nucleosynthesis processes that take place in this short phase of the stellar evolution, in particular the third dredge-up and hot bottom burning, which in turn are also strongly modulated by the stellar metallicity.
A survey of 3.3 micron PAH emission in planetary nebulae using FLITECAM
Authors: Smith Erin C. , McLean Ian S. 
Published: October 2008

AbstractWe have performed a study of 3.3 micron PAH emission in planetary nebulae using ground-based observations with FLITECAM, one of a suite of instruments designed for airborne astronomy aboard SOFIA, NASA's Stratospheric Observatory for Infrared Astronomy. The survey was performed on the Shane 3 meter telescope at Lick Observatory as part of the ground-based commissioning of the FLITECAM grism spectroscopy mode. Spectral resolution of R ~ 1700 was obtained with direct-ruled KRS-5 grisms. Targets included AGB stars and sources showing PAH emission in KAO, ISO or IRAS observations. Additionally, several oxygen-rich nebulae were observed in order to test methodology. Twenty objects were surveyed, of which 11 showed PAH emission. In objects exhibiting PAH emission, the relationship between the nebular C/O ratio and PAH equivalent width was found, showing a detectable PAH emission cutoff at a nebular C/O ratio of 0.65 ± 0.28. Selected objects with detected PAH emission were further investigated to trace PAH emission spectral variation within individual nebulae.
Molecules in nearby and primordial supernovae
Authors: Cherchneff Isabelle , Lilly Simon 
Published: October 2008

AbstractWe present new chemical models of supernova (SN) ejecta based on a chemical kinetic approach. We focus on the formation of inorganic and organic molecules including gas phase dust precursors, and consider zero-metallicity progenitor, massive supernovae and nearby core-collapse supernovae such as SN1987A. We find that both types are forming large amounts of molecules in their ejecta at times as early as 200 days after explosion. Upper limits on the dust formation budget are derived. Our results on dust precursors do not agree with existing studies on dust condensation in SN ejecta. We conclude that PMSNe could be the first non-primodial molecule providers in the early universe, ejecting up to 34% of their progenitor mass under molecular form to the pristine, local gas.
Organic compounds in galaxies
Authors: Onaka Takashi , Matsumoto Hiroko , Sakon Itsuki , Kaneda Hidehiro 
Published: October 2008

AbstractThe unidentified infrared (UIR) emission bands in the near- to mid-infrared are thought to originate from organic compounds in the interstellar medium. Recent space observations with Spitzer and AKARI have clearly revealed that the UIR bands are commonly seen in external galaxies, including elliptical galaxies, except for very metal-poor dwarf galaxies. They are also detected in extended structures of galaxies, such as extra-planar components and filaments produced by outflows, suggesting that the band carriers are ubiquitous organic compounds in galaxies. Since the UIR bands are prominent features in the infrared spectrum of galaxies and are linked to the star-formation activity, it is highly important to understand the nature, formation, processing, and destruction of the UIR band carriers in galaxies. While there is no systematic variation detected in the UIR spectrum in normal galaxies, significantly low values are derived for the ratio of the 7.7 μm to 11.2 μm bands in elliptical galaxies as well as in galaxies with low-luminosity AGNs compared to normal star-forming galaxies. Relatively low band ratios are also seen in the UIR band spectrum of extended structures in galaxies. If the same mechanism leads to the low band ratio, it would provide important information on the band carrier properties. It should also be noted that the band carriers are believed to be destroyed in a short time scale in environments where low band ratios are detected. The survival and supply processes in these environments are a key to understand the nature of the band carriers.
Diffuse interstellar bands in the Local Group: From the Milky Way, the Magellanic Clouds to the Andromeda galaxy
Authors: Cox N. L. J. , Cordiner M. A. 
Published: October 2008

AbstractWe report on recent developments in the study of diffuse interstellar bands in the Local Group galaxies. We present preliminary results on the detection of the 5780 Å DIB toward 17 targets in the vicinity of NGC 206 in M31.
Polycyclic aromatic hydrocarbons in elliptical galaxies
Authors: Kaneda Hidehiro , Onaka Takashi , Sakon Itsuki , Matsumoto Hiroko , Suzuki Toyoaki 
Published: October 2008

AbstractWe have observed 18 nearby dusty elliptical galaxies in the near- to far-infrared with Spitzer and AKARI. We have found that polycyclic aromatic hydrocarbons are present in 14 out of the 18 elliptical galaxies.
A 3-mm molecular line study of the Central Molecular Zone of the Galaxy
Authors: Jones Paul A. , Burton Michael G. , Lowe Vicki 
Published: October 2008

AbstractWe are studying the Central Molecular Zone (CMZ) in the inner few degrees around the Galactic Centre, by mapping multiple 3-mm molecular lines, with the 22-m Mopra telescope. During 2006, we covered a 5 × 5 arcmin2 area of the Sagittarius B2 molecular cloud complex (Jones et al. 2008). We find substantial differences in chemical and physical conditions within the complex. We show some results here of Principal Component Analysis (PCA) of line features in this Sgr B2 area. During 2007 we covered the larger region of longitude −0.2 to 0.9 deg. and latitude -0.20 to 0.12 deg., including Sgr A and Sgr B2, in the frequency range 85.3 to 91.3 GHz. This includes lines of C3H2, CH3CCH, HOCO+, SO, H13CN, H13CO+, SO, H13NC, C2H, HNCO, HCN, HCO+, HNC, HC3N, 13CS and N2H+.
ISM spectrum by cosmic dust?
Authors: Prevenslik Thomas V. 
Published: October 2008

AbstractThe interstellar medium (ISM) spectrum is usually explained by the response of dust particles (DPs) to the absorption of ultraviolet (UV) and visible (VIS) photons from nearby stars. With regard to the unidentified infrared (UIR) bands, the DPs are thought heated by UV and VIS photons to about 100 K thereby exciting the polycyclic aromatic hydrocarbons (PAHs). However, the UIR bands may be explained with the DPs at 2.7 K. To wit, the UIR bands form by the direct excitation of PAHs by infrared (IR) radiation induced from the absorption of cosmic microwave background (CMB) radiation in DPs by quantum electrodynamics (QED).
Organic matter in the Solar System: From colors to spectral bands
Authors: Cruikshank Dale P. 
Published: October 2008

AbstractThe reflected spectral energy distribution of low-albedo, red-colored, airless bodies in the outer Solar System (planetary satellites, Centaur objects, Kuiper Belt objects, bare comet nuclei) can be modeled with spectral models that incorporate the optical properties of refractory complex organic materials synthesized in the laboratory and called tholins. These materials are strongly colored and impart their color properties to the models. The colors of the bodies cannot be matched with plausible minerals, ices, or metals. Iapetus, a satellite of Saturn, is one such red-colored body that is well matched with tholin-rich models. Detection of aromatic and aliphatic hydrocarbons on Iapetus by the Cassini spacecraft, and the presence of these hydrocarbons in the tholins, is taken as evidence for the widespread presence of solid organic complexes aromatic and aliphatic units on many bodies in the outer Solar System. These organic complexes may be compositionally similar to the insoluble organic matter in some classes of the carbonaceous meteorites, and thus may ultimately derive from the organic matter in the interstellar medium.
Organics in the samples returned from comet 81P/Wild 2 by the Stardust Spacecraft
Authors: Sandford Scott A. 
Published: October 2008

AbstractThe Stardust Mission collected samples from Comet 81P/Wild 2 on 2 Jan 2004 and returned these samples to Earth on 15 Jan 2006. After recovery, a six month preliminary examination was done on a portion of the samples. Studies of the organics in the samples were made by the Organics Preliminary Examination Team (PET) - a worldwide group of over 55 scientists. This paper provides a brief overview of the findings of the Organics PET. Organics in the samples were studied using a multitude of analytical techniques including spatial determination of C and heteroatom elemental abundances (STXM), functional group identification (micro-FTIR/Raman, C,N,O-XANES), and specific molecular identification of certain classes of organics (HPLC-LIF, L2MS, TOF-SIMS). Analyses were also made of spacecraft components and environmental samples collected near the recovered returned capsule to assess contamination issues. The distribution of organics (abundance, functionality, and relative elemental abundances of C,N,O) is heterogeneous both within and between particles. They are an unequilibrated reservoir that experienced little parent body processing after incorporation into the comet. Some organics look like those seen in IDPs (and to a lesser extent, meteorites), while new aromatic-poor and highly labile organics, not seen in meteoritic materials, are also present. The organics are O,N-rich compared to meteoritic organics. Some of the organics have an interstellar heritage, as evidenced by D and15N enrichments.
Chemical diversity of organic volatiles among comets: An emerging taxonomy and implications for processes in the proto-planetary disk
Authors: Mumma Michael J. 
Published: October 2008

AbstractAs messengers from the early Solar System, comets contain key information from the time of planet formation and even earlier – some may contain material formed in our natal interstellar cloud. Along with water, the cometary nucleus contains ices of natural gases (CH4, C2H6), alcohols (CH3OH), acids (HCOOH), embalming fluid (H2CO), and even anti-freeze (ethylene glycol). Comets today contain some ices that vaporize at temperatures near absolute zero (CO, CH4), demonstrating that their compositions remain largely unchanged after 4.5 billion years. By comparing their chemical diversity, several distinct cometary classes have been identified but their specific relation to chemical gradients in the proto-planetary disk remains murky. How does the compositional diversity of comets relate to nebular processes such as chemical processing, radial migration, and dynamical scattering? No current reservoir holds a unique class, but their fractional abundance can test emerging dynamical models for origins of the scattered Kuiper disk, the Oort cloud, and the (proposed) main-belt comets. I will provide a simplified overview emphasizing what we are learning, current issues, and their relevance to the subject of this Symposium.
Predominantly left-handed circular polarization in comets: Does it indicate L-enantiomeric excess in cometary organics?
Authors: Rosenbush V. , Kiselev N. , Kolokolova L. 
Published: October 2008

AbstractPolarimetric observations demonstrated that all comets with significant values of circular polarization show predominantly left–handed circularly polarized light. We discuss the presence of homochiral organics in cometary materials as a source of the observed circular polarization. We have studied the effect of chirality on light–scattering properties of cometary dust considering particles that possess optical activity. Our investigations show that the cometary dust may include optically active materials which can be prebiological homochiral organics.
Solid organics in cometary comae
Authors: Tozzi Gian Paolo , Kolokolova Ludmilla 
Published: October 2008

AbstractIt is known since long ago that in comets a large quantity of organic matter exists in form of grains or is embedded in silicate grains. This was detected in situ by cometary space missions as well as inferred as a distributed source of some molecules observed in comets. Since organic matter is rather volatile, finding slow sublimating grains in comets can be good evidence of organics as a constituent of such grains. Here we describe a method to detect sublimating grains in comets. It consists of specific observations, specific data analysis, and some light-scattering modeling. We detect sublimating grains by measuring the quantity of grains as a function of the nucleocentric distance. Once detected, it is possible to get their photometric characteristics and compare them with the results of light-scattering modeling. The method has been applied to several comets. Sublimating grains were reliably identified for two of them.