bluuebunny/crossref_metadata_2025_split huggingface dataset:
Phosphosulfide semiconductors for optoelectronics and solar energy conversion
Authors: Mittmann Lena A , Crovetto Andrea 
Published: April 2024

Abstract
Inorganic phosphosulfides—materials containing phosphorus, sulfur, and at least one metal—are a vast and chemically-versatile family of materials. Benefiting from a wide range of possible phosphorus oxidation states, phosphosulfide semiconductors exist as thiophosphate compounds with various types of P–S polyanions, as genuine multi-anion compounds with or without P–P bonds, as solid solutions, and as many intermediate cases. Since metal phosphides and metal sulfides are among the highest-performing optoelectronic semiconductors, it seems reasonable to consider the phosphosulfide family as a potential pool of materials for solar cells, photoelectrochemical cells, and light-emitting diodes. Nevertheless, phosphosulfide semiconductors have very rarely been characterized with these applications in mind. In this perspective article, we reflect on the potential applicability of known and hypothetical phosphosulfides as light absorbers and emitters in optoelectronic devices. First, we distill the existing knowledge accessible through the Materials Project database, finding promising phosphosulfides among the compounds already present in the database and identifying what we see as the general advantages and challenges of phosphosulfides as optoelectronic materials. Then, we propose three concrete research directions aimed at finding novel high-quality phosphosulfide semiconductors with high light absorption coefficients, high carrier mobilities, and long carrier lifetimes. In particular, we argue that the versatility of phosphorus in this class of materials could potentially be exploited to engineer defect tolerance. Finally, we describe and explain the advantages of a custom synthesis setup dedicated to high-throughput exploration of thin-film phosphosulfides.
Unveiling the non-innocence of vanadium dopant in TiO2 nanocrystals for advanced energy storage and smart windows
Authors: García-Tecedor Miguel , Villar-García Ignacio J , Gorni Giulio , Liras Marta , de la Peña O´Shea Víctor , Barawi Mariam 
Published: April 2024

Abstract
Vanadium doped TiO2 NCs stand out as a promising candidate for energy storage applications due to its high electrical conductivity and redox properties. However, the thermodynamical behavior of the material under working conditions has not been explored and the reasons for its superior performance remain unlocked. This study explores the use of a combination of advanced in situ spectroscopy techniques, including x-ray absorption spectroscopy (XAS), spectro-electrochemistry (SEC), and electrochemical impedance spectroscopy (EIS) to provide unprecedented insights into the intricate electrochemical reaction mechanisms within these nanocrystals. Density functional theory calculations and EIS reveal the active role of substitutional V ions in the TiO2 anatase network as electron donors, enhancing surface charge and carrier density and improving pseudocapacitive properties. Cyclic voltammetry and in situ SEC reveal that V-doped TiO2 NCs exhibit significantly improved charge storage capacities, particularly in the pseudo-capacitance storage mechanism. In situ SEC and XAS analyses indicate that a more effective reduction of Ti4+ ions occurs during the electrochemical process in doped NCs, leading to higher charge capacitance and faster processes. Furthermore, in situ XAS measurements of the V K-edge revealed that the vanadium ions, beyond improving the redox behavior of the host, also actively participate in the reduction process. The significant changes in the V K-edge XANES and extended x-ray absorption fine structure spectra observed under reduction conditions can be ascribed to a change in the structure and oxidation state of the vanadium ions during the electrochemical reaction.
Exploring the impact of AlGaN barrier thickness and temperature on normally-on GaN HEMT performance
Authors: Hidayat Wagma , Usman Muhammad 
Published: April 2024

Abstract
We study varying barrier thicknesses in GaN/AlGaN HEMTs as well as the effect of temperature fluctuation on device functionality theoretically. Structures A, B, C, D, and E are designed each with barrier thickness 16 nm, 19 nm, 22 nm, 25 nm, and 28 nm respectively. The impact of barrier thickness on the surface barrier height, strain relaxation and 2DEG concentration is explained including GaN HEMT’s drain and transfer properties. At elevated temperatures, the polar-optical phonon dispersion is the predominant process. Yet, at lower temperatures, the interface-roughness (IFR) and alloy disorder dispersion both satisfactorily account for the calculated mobilities.
Characterization of Bauhinia Variegata natural fiber treated with bleaching, benzoylation, and alkalization
Authors: Varma Vinod Kumar , Sarangi Saroj Kumar 
Published: April 2024

Abstract
This study describes the physical, chemical, mechanical as well as morphological characterization of surface modified novel Bauhinia Variegata (BVR) stem fibers. Surface modifications for the fiber are accomplished with bleaching, benzoylation, and alkalization treatments. Using standard test methods, the chemical constituents of BVR fiber are evaluated like α- cellulose 62.5%, hemicellulose 10.8%, lignin18.2% and wax 0.8%. Scanning electron microscopy (SEM) was used to see how different the chemical reactions affect the fiber and SEM images confirmed the enhanced rough surface and existence of voids, along with the subtraction of unusual substances from the fiber surface. In both treated as well as untreated BVR, a Fourier-transform infrared spectroscopy (FTIR) analysis established the presence of cellulose, hemicelluloses, and lignin components. X-ray diffraction test evaluated the crystalline index for treated and raw fiber. The thermogravimetric test provides proof of enhanced thermal sustainability in the BVR upon treating chemically. The increased tensile strength and Young’s modulus upon chemical treatment confirm the improvement in the mechanical properties of the BVR fiber. The moisture absorption test revealed that the hydrophilic nature of BVR was reduced after the chemical treatment, promoting greater fiber-matrix adhesion. Presently studied BVR fiber seems to be a good substitute to the harmful man-made fibers for making of bio composites.
Enabling low-power analog and RFIC design through advanced semiconductor FDSOI MOSFETs
Authors: Singh Abhay Pratap , Mishra Vimal Kumar , Akhter Shamim 
Published: April 2024

Abstract
This study investigates the electrical performance of advanced semiconductor Ge-pocket-doped fully depleted silicon-on-insulator MOSFETs in comparison to conventional fully depleted silicon-on-insulator (FDSOI) MOSFETs. In this study vital electrical parameters such as the drain current, band diagram, lateral electric field, surface potential, and work function of the gate material were investigated. The advanced Ge pocket-doped FDSOI MOSFET structure demonstrates superior characteristics, such as a higher Ion/Ioff ratio, smaller subthreshold slope, lower capacitance, and higher cut-off frequency, when compared to conventional FDSOI MOSFETs. The structure of the Ge pocket-doped FDSOI MOSFET in the source and drain regions is designed to overcome the scaling effects of the transistor. In addition, this paper delves into the fabrication of the proposed device structure, outlining the key steps and intricacies involved. This study shows that the proposed device can be used for both digital and analog applications because it has good switching performance and a low cut-off frequency. In addition, the fabrication steps of the proposed structure were compatible with the existing fabrication process steps for conventional FDSOI MOSFETs. The simulation and analysis of the advanced semiconductor structure were performed using the Sentaurus TCAD simulator.
Experimental investigation of hydraulic jump characteristics in sloping rough surfaces for sustainable development
Authors: Gupta Sanjeev Kumar , Dwivedi Vijay Kumar 
Published: April 2024

Abstract
Understanding the intricate dynamics of hydraulic jumps in sloped channels holds pivotal importance in various engineering applications. This research explores the intricate relationship between the size of the bed material and the basic properties of hydraulic jumps, providing insight into the relative jump length, height, and energy efficiency. The goal of the research is to get important knowledge that will be useful for optimizing hydraulic systems and enhancing their overall efficiency in diverse engineering domains. This study used an open-channel flow arrangement with four-bed slopes (0° to 6°) and three irregularity heights (10 to 30 mm). During the investigation, the Froude number differed from 2.30 to 8.85 and the Reynolds number differed from 5450 to 25500. A novel instinctive technique was used to create correlations for different hydraulic jump characteristics in roughen-bed inclined channels. The study examines the combined effects of roughness and slope of the bed, and it was discovered that the relative jump height and efficiency of hydraulic jump increase by 19.37% and 8.44% respectively while the relative jump length decreases by 23.05% with an increase in bed slope from 0° to 6°. The relative jump height and efficiency of the hydraulic jump increase by 14.20% and 21.06% respectively while the relative jump length decreases by 29.09% with a rise in bed roughness from 0 to 30 mm.
Survival analysis of freezing stress in the North American native perennial flax, Linum lewisii
Authors: Gossweiler André Dunedin , Smart Brian C , Hulke Brent S 
Published: April 2024

Abstract
Abstract. The expansive range of Lewis flax (Linum lewisii), an herbaceous perennial, exposes the species to a diversity of climatic conditions. As interest in the domestication and adoption of perennial crop alternatives grows and interest in this species for natural area restoration continues, the assurance of a commercial plant variety’s ability to endure the full range of possible climatic extremes is paramount. This study examines the freezing tolerance of a geographically representative sampling of 44 Lewis flax accessions at winter temperature extremes experienced in the northern Great Plains of the USA. Survival analysis models were adapted to include temperature exposure, in replacement of ordinal time typically used in such models, to produce statistics evaluating reactions to extreme temperatures that Lewis flax would encounter in our field environments. Our results revealed Lewis flax is more freezing tolerant than previously reported, and revealed four accessions with significantly superior genetic freezing tolerance than the released ‘Maple Grove’ cultivar. Furthermore, regrowth analyses indicate variation among accessions not associated with survival, which could lead to improving regrowth rate and survival simultaneously. These findings and their methodology expand the understanding of Lewis flax adaptation for winter hardiness and offer an efficient, new model that can be used to evaluate freezing tolerance at ordinal temperatures without requiring extensive prior physiological knowledge for a species.
Anti-cancer effects of plant-derived Micromonospora sp. M2 against A549 and MCF-7 cell lines
Authors: Jeong Gyeong Han , Bak Dong-Ho , Lee Hanui , Cho Ja Young , Kang Seong Hee , Chung Byung Yeoup , Park Sanghwa , Bai Hyoung-Woo 
Published: April 2024

Abstract
The huge diversity of secondary bioactive metabolites, such as antibiotic and anticancer compounds produced by Micromonospora sp., makes it an attractive target for study. Here, we explored the anti-proliferative activities of Micromonospora sp. M2 extract (MBE) in relation to its pro-oxidative activities in A549 and MCF7 cell lines. Anti-proliferative effects were assessed by treating cells with MBE. We found that treatment with MBE decreased cell proliferation and increased intracellular reactive oxygen species, and that these observations were facilitated by the suppression of the PI3K-AKT pathway, alterations to the Bcl/Bad ratio, and increased caspase activity. These observations also demonstrated that MBE induced apoptotic cell death in cell lines. In addition, the phosphorylation of P38 and c-Jun N-terminal kinase (JNK) were upregulated following MBE treatment in both cell lines. Collectively, these results indicate that MBE acts as an anticancer agent via oxidative stress and JNK/mitogen-activated protein kinase pathway activation, enhancing apoptotic cell death in cell lines.
ViNe-Seg: deep-learning-assisted segmentation of visible neurons and subsequent analysis embedded in a graphical user interface
Authors: Ruffini Nicolas , Altahini Saleh , Weißbach Stephan , Weber Nico , Milkovits Jonas , Wierczeiko Anna , Backhaus Hendrik , Stroh Albrecht 
Published: April 2024

Abstract

Summary
Segmentation of neural somata is a crucial and usually the most time-consuming step in the analysis of optical functional imaging of neuronal microcircuits. In recent years, multiple auto-segmentation tools have been developed to improve the speed and consistency of the segmentation process, mostly, using deep learning approaches. Current segmentation tools, while advanced, still encounter challenges in producing accurate segmentation results, especially in datasets with a low signal-to-noise ratio. This has led to a reliance on manual segmentation techniques. However, manual methods, while customized to specific laboratory protocols, can introduce variability due to individual differences in interpretation, potentially affecting dataset consistency across studies. In response to this challenge, we present ViNe-Seg: a deep-learning-based semi-automatic segmentation tool that offers (i) detection of visible neurons, irrespective of their activity status; (ii) the ability to perform segmentation during an ongoing experiment; (iii) a user-friendly graphical interface that facilitates expert supervision, ensuring precise identification of Regions of Interest; (iv) an array of segmentation models with the option of training custom models and sharing them with the community; and (v) seamless integration of subsequent analysis steps.

Availability and implementation
ViNe-Seg code and documentation are publicly available at https://github.com/NiRuff/ViNe-Seg and can be installed from https://pypi.org/project/ViNeSeg/.
Interaction between risk factors, coronary calcium, and CCTA plaque characteristics in patients aged 18–45 years
Authors: Lorenzatti Daniel , Piña Pamela , Huang Dou , Apple Samuel J , Fernandez-Hazim Carol , Ippolito Paul , Abdullah Aftab , Rodriguez-Guerra Miguel , Skendelas John P , Scotti Andrea , Kuno Toshiki , Latib Azeem , Schenone Aldo L , Nasir Khurram , Blankstein Ron , Blaha Michael J , Berman Daniel S , Dey Damini , Virani Salim S , Garcia Mario J , Slipczuk Leandro 
Published: April 2024

Abstract

Aims
The atherosclerotic profile and advanced plaque subtype burden in symptomatic patients ≤45 years old have not been established. This study aimed to assess the prevalence and predictors of coronary artery calcium (CAC), plaque subtypes, and plaque burden by coronary computed tomography angiography (CCTA) in symptomatic young patients.

Methods and results
We included 907 symptomatic young patients (18–45 years) from Montefiore undergoing CCTA for chest pain evaluation. Prevalence and predictors of CAC, plaque subtypes, and burden were evaluated using semi-automated software. In the overall population (55% female and 44% Hispanic), 89% had CAC = 0. The likelihood of CAC or any plaque by CCTA increased with &gt;3 risk factors {RFs, odds ratio [OR] 7.13 (2.14–23.7) and OR 10.26 (3.36–31.2), respectively}. Any plaque by CCTA was present in 137 (15%); the strongest independent predictors were age ≥35 years [OR 3.62 (2.05–6.41)] and family history of premature coronary artery disease (FHx) [OR 2.76 (1.67–4.58)]. Stenosis ≥50% was rare (1.8%), with 31% of those having CAC = 0. Significant non-calcified plaque (NCP, 37.2%) and low-attenuation plaque (LAP, 4.24%) burdens were seen, even in those with non-obstructive stenosis. Among patients with CAC = 0, 5% had plaque, and the only predictor of exclusively NCP was FHx [OR 2.29 (1.08–4.86)].

Conclusion
In symptomatic young patients undergoing CCTA, the prevalence of CAC or any coronary atherosclerosis was not negligible, and the likelihood increased with RF burden. The presence of coronary stenosis ≥50% was rare and most often accompanied by CAC &gt;0, but there was a significant burden of NCP and LAP even within the non-obstructive group.
Addressing chronic diseases: a comparative study of policies towards type-2 diabetes and hypertension in selected European countries
Authors: Seghieri Chiara , Ferré Francesca , Tortù Costanza , Bertarelli Gaia , Mavrogianni Christina , Usheva Natalya , Toti Florian , Moreno Luis , Agapidaki Eirini , Manios Yannis 
Published: April 2024

Abstract

Background
Type-2 diabetes (T2D) and hypertension (HTN) are two of the most prevalent non-communicable diseases (NCDs): they both cause a relevant number of premature deaths worldwide and heavily impact the national health systems. This study illustrates the impact of HTN and T2D in four European countries (Albania, Bulgaria, Greece and Spain) and compares their policies towards the monitoring and management of HTN and T2D and the prevention of NCDs as a whole. This analysis is conducted throughout the DigiCare4You Project (H2020)—which implements an innovative solution involving digital tools for the prevention and management of T2D and HTN.

Methods
The analysis is implemented through desk research, and it is enriched with additional information directly provided by the local coordinators in the four countries, by filling specific semi-structured forms.

Results
The countries exhibit significant differences in the prevalence of HTN and T2D and available policies and programs targeted to these two chronic conditions. Each country has implemented strategies for HTN and T2D, including prevention initiatives, therapeutic guidelines, educational programs and children's growth monitoring programs. However, patient education on proper disease management needs improvement in all countries, registries about patients affected by HTN and T2D are not always available, and not all countries promoted acts to contain the increasing rates of risk factors related to NCDs.

Conclusions
While political awareness of the risks associated with HTN, T2D and NCDs in general is growing, there is a collective need for countries to strengthen their policies for preventing and managing these chronic diseases.
A Longitudinal Investigation of the Association Between Stroke and Loneliness
Authors: Willroth Emily C , Rule Payton D , Graham Eileen K , Nicholas Marjorie L , Hattori Robin , Thompson Tess , Connor Lisa Tabor 
Published: April 2024

Abstract

Objectives
The present research examined associations between stroke and long-term trajectories of loneliness.

Methods
We conducted secondary analyses in 3 large representative panel studies of adults 50 years and older in the United States, Europe, and Israel: the English Longitudinal Study of Aging (ELSA; analytic N = 14,992); the Survey of Health, Aging, and Retirement in Europe (SHARE; analytic N = 103,782); and the Health and Retirement Study (HRS; analytic N = 22,179). Within each sample, we used discontinuous growth curve modeling to estimate loneliness trajectories across adulthood and the impact of stroke on loneliness trajectories.

Results
Across all 3 samples, participants who experienced stroke reported higher levels of loneliness relative to participants who did not experience stroke. In ELSA and HRS (but not SHARE), loneliness levels were higher after stroke onset relative to before stroke onset.

Discussion
This research adds to a growing body of evidence demonstrating elevated loneliness among stroke survivors and highlights the need for interventions to increase social connectedness after stroke.
Correlates of SuperAging in Two Population-Based Samples of Hispanic Older Adults
Authors: Doyle Cassidy , Andel Ross , Saenz Joseph , Crowe Michael 
Published: April 2024

Abstract

Objectives
“SuperAgers” are generally defined as people 80+ years old with episodic memory performance comparable to those 20 years younger. Limited knowledge exists to describe characteristics of SuperAgers, with even less known about Hispanic SuperAgers.

Methods
We examined indicators of cognitive, physical, and psychological resilience in relation to the likelihood of being a SuperAger using data from 2 population-based studies of Hispanic older adults (Puerto Rican Elderly: Health Conditions [PREHCO] Study; Health and Retirement Study [HRS]). SuperAgers were defined as (1) ≥80 years old, (2) recall scores ≥ the median for Hispanic respondents aged 55–64, and (3) no cognitive impairment during the observation period. Overall, 640 PREHCO participants and 180 HRS participants were eligible, of whom 45 (7%) and 31 (17%) met SuperAging criteria.

Results
Logistic regressions controlling for age and sex demonstrated that higher education (PREHCO: odds ratio [OR] = 1.20, p &lt; .001; HRS: OR = 1.14, p = .044) and fewer instrumental activities of daily living limitations (PREHCO: OR = 0.79, p = .019; HRS: OR = 0.58, p = .077; cognitive resilience), fewer activities of daily living limitations (PREHCO: OR = 0.72, p = .031; HRS: OR = 0.67, p = .068; physical resilience), and fewer depressive symptoms (PREHCO: OR = 0.84, p = .015; HRS: OR = 0.69, p = .007; psychological resilience) were associated with SuperAging, although not all results reached threshold for statistical significance, presumably due to low statistical power. Additionally, known indicators of physical health (e.g., chronic conditions and self-rated health) did not relate to SuperAging.

Discussion
Increasing access to education and recognizing/treating depressive symptoms represent potential pathways to preserve episodic memory among older Hispanic adults.