bluuebunny/crossref_metadata_2025_split huggingface dataset:
The identification of sulphide minerals by infra-red spectroscopy
Authors: Soong R. , Farmer V. C. 
Published: December 2006

SynopsesThe value of infra-red spectra in identifying sulphide minerals has been assessed by surveying the spectra of some forty specimens. Spectra of finely ground samples dispersed in polyethylene discs were obtained in the region 420-90 cm−1 with a resolution of 3–4 cm−1, using a Beckman-RIIC Fourier-Transform Interferometer. Except for minerals whose metallic conductivity obliterated vibrational features, the spectra permitted rapid recognition of sulphide minerals either alone or in mixtures.Spectra of the following twenty-five pure, or nearly pure specimens are presented: cinnabar, galena, pyrrhotine, alabandine, sphalerite, wurtzite, realgar, orpiment, stibnite, bismuthinite, arsenopyrite, tetrahedrite, pyrargyrite, proustite, enargite, bournonite, boulangerite, jamesonite, and plagionite. Sulphides whose metallic conductivity led to featureless, almost total, absorption of infra-red radiation included chalcosine, troilite, millerite, covelline, bornite, and pyrrhotine: only the spectrum of the last is illustrated as a typical example.Comparison of the spectra reproduced here with those previously published show a fair measure of agreement, although there are discrepancies. Povarennykh and co-workers, for example, have reported a common sequence of broad absorption bands at 370, 280, and 180 cm−1 for minerals that were found here to exhibit featureless metal-like absorption. The sources of these and other discrepancies are briefly discussed.
The origin of rhythmic layering
Authors: Maaløe Sven 
Published: December 2006

SummaryRhythmic layering in the Skaergaard intrusion shows variation in crystal size and in modal proportions of primocrysts with structural height. These changes are ascribed to variations in nucleation rates of primocrysts. The nucleation theory requires that crystallization occurs under supercooled conditions, and that the crystallization of one primocryst phase may change the composition of the magma in such a manner that the nucleation rates of other primocrysts are influenced. Both these constraints appear to have been fulfilled for the Skaergaard intrusion.
Cryptic variation in the Rhum layered intrusion
Authors: Dunham A. C. , Wadsworth W. J. 
Published: December 2006

SummaryElectron-microprobe analyses of cumulus olivine, chromite, pyroxene, and plagioclase from layered peridotites and allivalites of the Eastern and Western Layered Series of Rhum demonstrate the presence of cryptic variation. Olivine varies from Fo88-78 within individual units, and there are corresponding changes in the Mg/(Mg+Fe2+) ratios in the pyroxenes and chromites. Plagioclase changes are not so dramatic, but the An-content broadly follows the Mg/(Mg+Fe2+) ratio in the other minerals. The most Fe-(and Na-) rich phases do not occur at the top of lithological units, but some way below. The composition trend above them is reversed. The data are interpreted as the result of periodic infilling of a magma chamber, the new magma mixing with the remains of the previous pulse. Each pulse was followed by a period when fractional crystallization produced the layered rocks. New data on Ni in the olivines suggests that the ratio of the volume of initial magma to volume of layered rocks was about four to one, the initial magma being allied to the high-calcium low-alkali tholeiitic basalts of Skye.
The crystal structure of stilpnomelane. Part III: Chemistry and physical properties
Authors: Eggleton R. A. , Chappell B. W. 
Published: December 2006

SummaryFull chemical analysis, cell dimensions, γ refractive index, density, and infra-red absorption spectrum have been determined for fourteen stilpnomelanes. Coupled with data from previously described material and electron probe analyses of three further samples, the new information shows that γ = 1·616+0·0047 Fe3+ −0·0037 Mg; substitution of Mn for Fe appears to have little effect on γ. For ferrostilpnomelane, D = 2·85−0·011 Mg, for ferristilpnomelane, D = 2·89−0·011 Mg. Cell dimensions clearly distinguish ferro-, ferri-, and man-ganstilpnomelanes; for ferri-stilpnomelane a = 22·03−0·00446 Mg−0·00786 Fe3+ (Å). A convenient approximation to the structural formula using a ⅛ subcell, is K0·6(Mg, Fe2+Fe3+)6Si8Al(O,OH)27 2–4 H2O.
Sampleite from Jingemia Cave, Western Australia
Authors: Bridge P. J. , Pryce M. W. , Clarke R. M. , Costello M. B. 
Published: December 2006

SummarySampleite from Jingemia Cave, Watheroo (30° 16′ S. 116° 00° E.), 190 km north of Perth, Western Australia is derived from the alteration of copper sulphides in contact with guano deposits. Associated minerals are atacamite, weddellite, and gypsum on goethite and manganese-oxide-coated friable quartz rock. Birnessite, halite, dolomite, taranakite, todorokite, apatite, and malachite are also present.The sampleite occurs as platy spheroidal aggregates to 0·3 mm with D 3·20±0·01, α 1·625 ∥ [010], β and γ 1·674, all ±0·002, α Turquoise Green 41d to Light Blue-Green 39d, β and γ Benzol Green 41 to Venice Green 41b, absorption α < β = γ, 2Vα 5–10°. Chemical analyses are given.Cu3(PO4)2·3H2O, a corrosion product reported on artifacts, is believed to be sampleite. A further occurrence of sampleite has been recorded from Brookton, 120 km ESE. of Perth. The structurally related mineral lavendulan has been reported from five Western Australian localities.
Glauconite and celadonite: two separate mineral species
Authors: Buckley H. A. , Bevan J. C. , Brown K. M. , Johnson L. R. , Farmer V. C. 
Published: December 2006

SummaryAnalyses of glauconites and celadonites from continental sedimentary rocks and sea-floor basalts using X-ray diffraction, electron probe microanalysis, infra-red spectroscopy, and X-ray fluorescence spectroscopy are reported. The minerals are shown to be distinct species; each an isomorphous replacement series, glauconite having an average half unit cell of K0·85(Fe3+, Al3+)1·34 (Mg2+, Fe2+)0·66(Si3·76Al0·24)O10(OH)2 whereas celadonite approaches the ideal half unit cell of K(Fe3+, Al3+)(Mg2+, Fe2+)Si4O10(OH)2. Considerable Fe3+Alvi interchangeability occurs in the octahedral layer in both minerals and considerable substitution of aluminium in the tetrahedral layer of glauconites results in the more disordered 1Md type of structure compared with the more highly ordered 1M structure of celadonites. Some mixed layer glauconite-smectites and celadonites were also examined and could be distinguished from true glauconites and celadonites by chemical analysis, XRD, and IR techniques. It is proposed that the terms ‘glauconite’ and ‘celadonite’ should be used only for those minerals containing less than 5% interlayering.
Acicular hornblende schists and associated metabasic rocks from North-West Pakistan
Authors: Kempe D. R. C. 
Published: December 2006

SynopsesA suite of unusual acicular hornblende schists is found at Warsak (34° 10′ N. 71°C 23′ E.), some 30 km WNW. of Peshawar, North-West Pakistan. The schists occur in association with sill-like masses of amphibolite facies meta-igneous rocks, possibly a metamorphosed gabbroic and doleritic, dioritic, and granitic calc-alkaline series, and intrusions of alkaline granite and microgranite. These rocks lie within Palaeozoic metasediments and all are folded synclinally. The area was first described by Ahmad et al. (1969).The rocks of the acicular hornblende schist suite (fig. I) consist essentially of large, idioblastic hornblende crystals—comprising some 30–60 % of the rock—in a fine-grained granoblastic matrix of oligoclase feldspar with minor quartz, iron oxide, biotite, and rutile. The boat-shaped, blue-green hornblendes, twinned on {100}, reach 5 mm in length and are often grouped in sprays or clusters; they are sieved with quartz, ilmenite, and patchy calcite. The groundmass also contains patches and veins of calcite, associated with ragged patchy areas of reddish brown, amorphous iron oxide or hydroxide, perhaps introduced hydrothermally. The schists coarsen in grain size outwards through the sill-form, the hornblendes reaching 4 cm, become rich in chlorite and biotite, and grade into the apparently metagabbroic amphibolitic rocks.The acicular hornblende schists have a generally basaltic composition, while the hornblendes are tschermakitic. An analysed amphibole has 16·5% Al2O3, is slightly zoned with alumina increasing from core to rim, and has the formula:Three hypotheses of the origin of the rocks were considered; metamorphism of a suite of basic tufts is the most favoured. Origins involving metamorphism of a lamprophyre-appinite suite or of a gabbroic marginal facies are therefore rejected. Texturally the rocks strongly resemble metatuffs (fig. 2) that occur associated with metagreywackes in the Otago schists of New Zealand (Turner, 1933); like many similar Alpine schists they also contain tschermakitic hornblendes. The Warsak tufts could have formed originally, together with the meta-igneous rocks, possibly as lavas, in an inter-plate tectonic environment; the high A1 content of the hornblende, which is typical of many amphiboles from the surrounding alpine environment in North-West Pakistan, and other mineralogical evidence in the region support a highpressure environment for the metamorphism of the rocks to just within the amphibolite facies, at moderate temperatures of approximately 465 °C.
Crystallization history of sector-zoned microcline megacrysts from the Godani Valley pluton, Nigeria
Authors: Vaniman David 
Published: December 2006

SummarySector-zoning is brought out by mineral inclusions (plagioclase, biotite, hornblende, sphene, and apatite) in 2 to 5 cm microcline megacrysts of the Godani Valley pluton, Nigeria. The inclusions are concentrated in the megacryst rims beneath the faces {110} and {20}; the megacryst cores are not sector-zoned. Comparison with other occurrences (Portugal and Czechoslovakia) shows that this type of sector-zoning is not controlled by growth rate. Chemical sector-zoning does not occur in the Godani megacrysts. Growth from magma is proposed, with preference for inclusions on faces at a high angle to the feldspar a-chain. A superficially similar type of sector-zoning occurs in microcline megacrysts of both pluton and wall rock at Papoose Flat, California, suggesting that this feature can be generated either by growth from magma or by replacement.
Tapiolite, its chemistry and cell dimensions
Authors: Clark A. M. , Fejer E. E. 
Published: December 2006

SummaryElectron-probe analyses and cell dimensions are reported for twenty members of the tapiolite group. The minerals can be placed in ordered and disordered structural groups, the latter with a significantly larger c dimension. The a and c dimensions for both groups are dependent mainly on their titanium contents. The disordered set form part of a discontinuous series through strüverite/ilmenorutile to rutile. The chemical and structural data are incompatible with the existence of ferrotantalite or mossitc as valid species.
Garavellite, FeSbBiS4, a new mineral from the Cu-Fe deposit of Valle del Frigido in the Apuane Alps, northern Tuscany, Italy
Authors: Gregorio F. , Lattanzi P. , Tanelli G. , Vurro F. 
Published: December 2006

SummaryGaravellite occurs in polished sections, as small aggregates, up to 200 µm across, of anhedral crystals, usually in direct contact with tetrahedrite, Sb-rich bismuthinite, chalcopyrite, and siderite. Chemical formula Fe0,80Cu0.02Sb1.13Bi0.78As0.01S4 on the basis of S = 4, or ideally FeSbBiS4.The mineral has an orthorhombic unit cell with a = 11.439, b = 14.093, c = 3.754 Å, Z = 4; calculated density 5.64 gm/cm3. Important diffraction lines are 14.00 (m) 010, 7.08 (m) 020, 3.62 (vs) 230, 3.49 (m) 040, 3.34 (m) 320, 3.20 (vs) 121, 3.10 (m) 201, 2.98 (s) 240, 2.89 (s) 221, 2.63 (vs) 311, 2.51 (vs) 250, 2.16 (m) 421, 1.677 (m) 312. In reflected light it is grey with a brown-olive tint similar to that of tetrahedrite. Bireftectance is distinct and anisotropism is also strong, from yellowish-green to bluish grey. Vickers hardness (50 g load) 212–22 kg/mm2. Reflectance in air: 470 nm R1 = 33.5−34.7%, R2 = 40.5– 42.8%; 546 nm 32.8–34.7%, 40.2–42.0%; 589 nm 32.6– 33.7%, 39.3–41.0%; 650 nm 32.4–34.6%, 38.4–41.0%.The mineral and name have been approved before publication by the Commission on New Minerals and Mineral Names, IMA.Frigidite, the so-called nickel-bearing variety of tetrahedrite found at this locality, is shown to be an intergrowth of tetrahedrite and Ni-bearing minerals.
New data on wittichenite
Authors: Criddle A. J. , Stanley C. J. 
Published: December 2006

SummaryThe wittichenite (BM 1977, 172) discovered in the course of a reflected light study of polished sections from the Seathwaite deposit, Cumbria (described earlier in this journal by Stanley and Criddle), is the first authenticated occurrence of the species in Great Britain; for this reason it was examined in detail and compared with a specimen (BM 1437) from Wittichen, the type locality. Chemical analyses, cell dimensions, visible-spectrum reflectances, quantitative colour values, and VHN's are provided. They are in agreement with previously published data for the species.
The loss of Fe and Na from a basaltic melt during experiments using the wire-loop method
Authors: Corrigan Gay , Gibb Fergus G. F. 
Published: December 2006

SummaryLosses of Fe and Na from a typical basaltic liquid during experiments using the wire-loop method have been determined for both Pt and Ag40Pd60 alloy wire by electron-microprobe analyses of the quenched glasses. The amount of Fe lost is dependent on the duration of the experiment and is particularly sensitive to the ratio of sample to metal in direct contact with it. Fe losses can be minimized by using the thinnest wire possible in conjunction with the largest amount of sample that will adhere to the wire and, if Ag-Pd wire is used, can be kept below the 1% level even in long experiments. Much more serious in terms of changes in the bulk composition are losses of Na, which appear to be in direct linear proportion to the length of the experiment and in inverse proportion to the mass of the sample. Even when samples in excess of 200 mg are used the Na losses are unlikely to be less than 5% except in experiments of less than a few days' duration or on samples with very low initial Na contents.
Nukundamite, a new mineral, and idaite
Authors: Rice C. M. , Atkin D. , Bowles J. F. W. , Criddle A. J. 
Published: December 2006

SummaryA new mineral, nukundamite, from a Fijian kuroko deposit is described. It has been referred to as idaite, Cu5FeS6, or Cu5.5xFexS6.5x. Electron-probe analyses gave Cu 56.51, Fe 9.64, and S 33.51, total with traces of Ag and As is 99.79%. Hexagonal with a 3.782, c 11.187 Å, Z = 1. Empirical formula Cu3.37, Fe0.66, S3.97 on the basis of eight atoms. Copper-coloured, metallic lustre, cleavage {0001} perfect. Density (g cm−3) 4.53 (calc), 4.30 (meas). Strongly pleochroic from reddish orange (Ro) to pale grey (Re). Parallel extinction. Very strong anisotropy with pale green-grey rotation colours. Reflectance values and quantitative colour values in air and oil are given. Similarities with the covelline structure are indicated.An attempt to fully describe idaite from the Ida mine was unsuccessful. The description of the type material therefore remains inadequate.
Chemical mineralogy of the aureole of the Nahant Gabbro at East Point, Nahant, Mass., USA
Authors: Verma P. K. 
Published: December 2006

SummaryThe Lower Cambrian Weymouth Formation at Nahant, Massachusetts, consisting of interbedded pelitic and calcareous rocks, was intruded by the Nahant Gabbro. The predominant metapelitic mineral assemblage of the contact aureole is quartz-muscovite-chlorite-magnetite-ilmenite. The calcareous hornfelses exhibit a varied mineral assemblage, and in some cases the variation can be spatially related to the intrusive. A number of cross-cutting thin mineral veins, many containing prehnite, are characteristically associated with these calcsilicate rocks.The minerals have been analysed by electron microprobe and this work indicates the presence of a possible solvus in the Fe3+-Al epidote solid solution series. At the physicochemical conditions of the formation of the Nahant hornfelses, the ferric mole fractions of coexisting epidotes are 0.49 and 0.98.Comparison with experimental work shows that the conditions of the contact metamorphism were T ≃ 500°C, Ptotal ≃ 2 kb, and XCO2 ≃ 0.2. However, the present assemblages are the result of a later low-grade regional metamorphism, the ultimate product of which was prehnite.
The Moine amphibolite suites of central and northern Sutherland, Scotland
Authors: Moorhouse Steven J. , Moorhouse Valerie E. 
Published: December 2006

SummaryThree groups of amphibolites within the Moine rocks of Sutherland have been analysed for twenty-six elements by XRF analysis. (1) Very rare epidotic hornblende schists within pelite, possibly derived from volcanic ash deposited penecontemporaneously with the pelite (2 analyses). (2) Major and minor bodies of ‘early Moine’ schistose garnetiferous amphibolite intruded early in the deformational sequence (41 analyses). (3) Small bodies of ‘Loch a' Mhòid metadolerite’, intruded later in the deformational sequence (23 analyses). Rare Moine ultrabasites are associated with these metadolerites and probably formed from the same magma as olivine cumulates. These ultrabasites (5 analyses) are chemically distinct from Lewisian ultrabasites (both in the basement sheets within the Moine rocks of Sutherland and in the foreland Lewisian rocks) and from the Glen Urquhart ultrabasic body (3 analyses).Using variation diagrams it is inferred that chemical variation in these amphibolites is due largely to pyroxene and plagioclase crystallization in the early amphibolites and olivine, pyroxene, and plagioclase crystallization in the Loch a' Mhòid metadolerites and ultrabasites, followed in both cases by high-level fractionation. This has led to high values of incompatible elements in many of the early amphibolites. Although geochemical discrimination diagrams tend to give ambiguous results for many of these rocks, the early amphibolites are shown to be tholeiitic in nature with a chemistry transitional between within-plate and island-arc type basaltic magma. The Loch a' Mhòid metadolerites are mildly alkaline within-plate type basaltic magma.
An explanation of anomalous optical properties of topaz
Authors: Akizuki Mizuhiko , Hampar Martin S. , Zussman Jack 
Published: December 2006

SummaryA study has been made of topaz crystals showing a sectoral texture related to the growth of the crystal, and showing anomalous optical properties within the sectors. The growth surfaces responsible for the development of most of the sectors have been identified. The fluorine/hydroxyl sites in topaz are symmetrically equivalent in the solid crystal, but at a growth surface this equivalence may be lost, resulting in a reduction in the crystal symmetry and the ordering of fluorine and hydroxyl, the ordering scheme being retained once the crystal has formed. The reduction in symmetry expected to be produced by this ordering is in general agreement with the actual reduction in symmetry indicated by the optical properties. Heating of the topaz to about 950 °C results in the almost complete disappearance of the optical anomalies due to disordering, which may be related to the loss of hydroxyl from the crystal. Anomalous pyro- and piezoelectric phenomena may also be the result of ordering. Published optical and X-ray determinative curves for fluorine in topaz may give erroneous results for ordered topaz.
The iron-rich blueschist facies minerals: I. Deerite
Authors: Muir Wood R. 
Published: December 2006

SummaryThe mineral deerite is restricted in occurrence to blueschist facies meta-ironstones. From the ideal formula of Si12O40(OH)10 there are a limited range of substitutions: Ti and V for Fe3+ and Mn on the Fe2+ site. In the present survey of deerite compositions from the majority of deerite localities the maximum substitutions have been 2Ti and 3Mn in the above formula. There is an at present unexplained anomaly in the totals of a number of the analyses indicating that there may be variations away from the ideal formula towards increased hydroxyl and decreased cation contents.From differences between the mineral compatibilities of deerites from the higher-grade Franciscan exotic block blueschist localities and those from more conformable Alpine blueschists, in conjunction with previous work on the experimental stabilities of the low-pressure/low-temperature hydrous iron silicate minerals, it has been possible to map the form of the low-pressure deerite stability field involving reactions of greenalite or minnesotaite or grunerite with magnetite and quartz. Within the deerite stability field, further deerite-forming reactions involve the breakdown of riebeckite and the hydrous incompatibility of magnetite with quartz; both are very dependent on the activity of sodium. A low-pressure stability to 4 kb at 200 °C and 6 kb at 300 °C are estimated from these low-temperature breakdown reactions. This fits in well with the high-pressure deerite stability determinations of Langer et al. (1977).
Weathering mineral facies in altered granites: The importance of local small-scale equilibria
Authors: Meunier A. , Velde B. 
Published: December 2006

SummaryClassical clay mineralogy determinations and electron microprobe analyses of weathering minerals developed in altered two-mica granites indicate that the chemical forces that produce new minerals are often constrained to small volumes, frequently on the scale of a mineral grain or contact between two grains in the granite.Chemical potentials such as pH, alkali and alkaline earth and silica activity in the altering aqueous solutions provoke a destabilization of pre-existing minerals, which recrystallize locally to give a new multimineral product. The chemical composition of the new phases is largely governed by the relative concentrations of the elements present in the former minerals.Three mineral facies were observed in the weathered granites: initially a sericite-beidellitic type, then a beidellite-kaolinitic type, and finally a last stage kaolinite-oxide facies assemblage. The position of each facies is not restricted to a given depth in the profile but the relative proportions of each facies found in a thin-section size sample change towards the kaolinite-oxide facies.The global rock chemistry reflects the type facies predominant in each sample. The first two facies are roughly silica conservative while the kaolinite-oxide facies loses silica as well as alkali and alkaline earths.Geochemical and clay mineral studies of rock alteration should consider problems of mineral genesis at very localized sites.