bluuebunny/crossref_metadata_2025_split huggingface dataset:
Intergrowths of hexagonal and monoclinic pyrrhotites in some sulphide ores from norway
Authors: Lianxing Gu , Vokes Frank M. 
Published: December 2006

AbstractPyrrhotites in polished sections from more than twenty stratabound massive sulphide and magmatic nickel-copper deposits in Norway were studied under the microscope using the magnetic colloid method. In both types of deposits, two distinct styles of intergrowths between monoclinic and hexagonal pyrrhotites were found: crystallographically-controlled lamellar intergrowths and fissure-controlled irregular intergrowths.Lamellar intergrowths consist of crystallographically oriented monoclinic lamellae occurring in a hexagonal matrix and were produced originally by exsolution from hexagonal pyrrhotite on cooling. Irregular intergrowths comprise blades and patches of monoclinic pyrrhotite occurring along fissures and grain boundaries of hexagonal pyrrhotite, and were formed by interactions between hexagonal grains and sulphur-rich hydrothermal solutions.Increase in lamella thickness and spacing, development of lamella zonations, wedge-shaped composite ends, boxworks and composite lamellae were caused by progressive lamellae coarsening and maturation during natural annealing, which could have been promoted by anisotropic stress. Metamorphic recrystallization and annealing tend to homogenize pyrrhotite and erase preexisting exsolution lamellae.
Temperature gradients in large cold-seal pressure vessels
Authors: Dalton J. A. , Gibb F. G. F. 
Published: December 2006

AbstractRadial and longitudinal temperature gradients within cold-seal pressure vessels can contribute significantly to the total temperature unccrtainty in any one experiment and it is important to calibrate such gradients before experiments are undertaken. We have measured temperature gradients in vertically mounted large cold-seal vessels at 1 atm and 1 kbar and in the temperature range 500–800°C Radial gradients were measured with the vessel at various positions within the furnace by recording the temperature difference between a thermocouple in the internal bore of the vessel and one in a well in the top of the vessel. We find that when the vessel is at a certain position in the furnace, the temperatures read by these two thermocouples are equivalent to within 1°C. The contribution of radial gradients to temperature uncertainty can be thus be substantially minimized if experiments are undertaken with the vessel in this position. Longitudinal gradients of 2.8°C/cm at 500°C and 3°C/cm at 800°C were recorded at 1 kbar. These profiles are significantly steeper than those recorded at 1 atm. Not to calibrate temperature gradients at the experimental conditions or failure to calibrate vessels at all could lead to large temperature uncertainties.
Minor and trace element chemistry of carbonates, apatites and magnetites in some African carbonatites
Authors: Dawson J. B. , Steele I. M. , Smith J. V. , Rivers M. L. 
Published: December 2006

AbstractIn calcites and dolomites in seven African carbonatites, SrO, FeO and MnO occur in concentrations from 1 to 2 wt.%, whereas Ce, Y, Cu and Zn occur only at the ppm level. Sr, Ce and Y partition preferentially into calcite relative to co-existing dolomite, whereas Fe and Mn favour dolomite. Sr partitions preferentially into calcite relative to co-exisiting apatite, but the light rare-earth elements partition into apatite. Magnetite from Kerimasi contains up to 13 wt.% MgO and 6 wt.% MnO, extending the known ranges in composition of magnetites from carbonatites.
The stabilities of secondary tin minerals. Part 2: The hydrolysis of tin(II) sulphate and the stability of Sn3O(OH)2SO4
Authors: Edwards R. , Gillard R. D. , Williams P. A. 
Published: December 2006

AbstractTritin(II)dihydroxyoxosulphate, Sn3O(OH)2SO4, is a rare corrosion product found on the surfaces of certain tin alloys. A new synthesis based on the hydrolysis of SnSO4 is described. The stability constant determination of Sn3O(OH)2SO4,s, at 298.2K and 105Pa is determined using direct measurements via electrodes, of the activities of tin(II) and sulphate ions. ΔfG0(298.2K) is equal to −1563.1 ± 0.9 KJ mol−1.
Nb-rich baotite in carbonatites and fenites at Haast River, New Zealand
Authors: Cooper Alan F. 
Published: December 2006

AbstractBaotite occurs as an accessory mineral in carbonatites, fenites, and carbothermal veins associated with a lamprophyre dyke swarm in the Haast River area of south Westland, New Zealand. Carbonatites are petrogenetically evolved, with assemblages dominated by ankerite, siderite and Ba-Sr-REE carbonates. Microprobe analysis indicates baotite compositions more Nb-rich than previously recorded, with compositions close to Ba4[Ti3(Nb,Fe)5]Si4O28Cl. Ti must be partially replaced in both crystallographically-independent octahedral sites. Compositional zoning, and stoichiometric considerations suggest that the dominant octahedral substitution is the same as that described in rutile, namely 3Ti4+ ⇌ 2Nb5+ + Fe2+. Contrary to previous suggestions, Fe in the octahedral site should, therefore, be dominated by Fe2+.The presence of baotite further documents the involvement of halogens in carbonatite magmas. In the New Zealand occurrences it is suggested that the chlorine originates from associated phonolitic magmas and is partitioned into carbonatite during liquid immiscibility.
Prismatine: revalidation for boron-rich compositions in the kornerupine group
Authors: Grew Edward S. , Cooper Mark A. , Hawthorne Frank C. 
Published: December 2006

AbstractKornerupine and prismatine were introduced independently by Lorenzen in 1884 (but published in 1886 and 1893) and by Sauer in 1886, respectively. Ussing (1889) showed that the two minerals were sufficiently close crystallographically and chemically to be regarded as one species. However, recent analyses of boron using the ion microprobe and crystal structure refinement, indicate that the boron content of one tetrahedral site in kornerupine ranges from 0 to 1. Kornerupine and prismatine, from their respective type localities of Fiskenæsset, Greenland and Waldheim, Germany, are distinct minerals, members of an isomorphic series differing in boron content. For this reason, we re-introduce Sauer’s name prismatine for kornerupines with B > 0.5 atoms per formula unit (p.f.u.) of 22(O,OH,F), and restrict the name kornerupinesensu strictoto kornerupines with B < 0.5 p.f.u. Kornerupinesensu latois an appropriate group name for kornerupine of unknown boron content. Kornerupinesensu strictoand prismatine from the type localities differ also in Fe2+/Mg ratio, Si − (Mg + Fe2++ Mn) content, Al content, F content, colour, density, cell parameters, and paragenesis. Both minerals formed under granulite-facies conditions with sapphirine and phlogopite, but kornerupinesensu strictois associated with anorthite and hornblende or gedrite, whereas prismatine is found with oligoclase (An9–13), sillimanite, garnet, and/or tourmaline. Occurrences at other localities suggest that increasing boron content extends the stability range of prismatine relative to that of kornerupinesensu stricto.
Petrographic relationships between mineral phases and bitumen in the Oklo Proterozoic natural fission reactors, Gabon
Authors: Parnell John 
Published: December 2006

AbstractSeveral of the Proterozoic natural fission reactors at Oklo, Gabon contain abundant organic matter (bitumen), with which much of the reactor uranium is associated. An understanding of the petrography of the bitumen is important in assessing its role in element retention following fissiogenic reactions. The bitumen is replacive and includes vestiges of detrital grains and clays of the host sandstones. It also contains several generations of mineral phases related to the migration of uranium and daughter lead, and other elements mobilized by hydrothermal activity in the reactor zones. The minerals include (primary) uraninite precipitated after reduction of uranium by organic matter, silicates concentrated in radiation halos around the uraninite, and native lead, galena and further uraninite which migrated from the primary uraninite. The silicates are illitic clays in the immediate vicinity of the reactors, and chloritic more distant from the reactors. Authigenic clays in radiation halos are compositionally distinct from earlier host rock clays. Local migration of uranium and lead is evident as dispersion of the elements through the radiation halos; cross-cutting veinlets of uraninite, native lead and galena, including veinlets extending directly from the primary uraninite crystals; and concentrations of the elements at the margins of bitumen masses. The limit of observed uranium dispersion is within clay immediately beyond the bitumen margins.
Twinning in an orthorhombic aluminate sodalite, Ca8[Al12O24] (CrO4)2
Authors: Hassan Ishmael 
Published: December 2006

AbstractTransmission electron microscopy (TEM) was used to study the aluminate sodalite, Ca8[Al12O24](CrO4)2. This aluminate sodalite has four polymorphs: one cubic, one modulated, one tetragonal, and an orthorhombic cell that arise from ordering of [Ca4·CrO4]6+ clusters that occur in the cages of the structure. The transition temperatures are 432, 453, and 610 K. The cell parameters for the orthorhombic phase, with the cubic cell parameter of a = b = c = 9.222 Å, are 3a × 2b × c. Transformation twins are formed at 432 K during the transition from the tetragonal to the orthorhombic phase. The twin plane is {110} in the cubic cell, and {320} in the orthorhombic cell.
An unusual ruby-sapphire-sapphirine-spinel assemblage from the Tertiary Barrington volcanic province, New South Wales, Australia
Authors: Lin Sutherland F. , Coenraads Robert R. 
Published: December 2006

AbstractRuby-sapphire-sapphirine-spinel forms small, corroded, crystalline aggregates in corundum bearing alluvials shed from the Tertiary Barrington basalt shield volcano. Sapphirine is near a 7:9:3 (MgO-Al2O3-SiO2) composition and, together with the corundum, shows reaction rims of pleonaste spinel. Spinel in the aggregates has a compositional range Sp 68–73 Hc 27–29 Cm 0–3. The aggregates give new insights into the ruby-sapphire source rocks. Potential origins include metamorphic recrystallization of aluminous material (below 1460°C) or high temperature-high pressure crystallization reactions related to lamprophyric or basaltic magmas (up to 1300°C and 20 kbar). Sapphirine-spinel thermometry suggests final crystallization temperatures for the aggregates around 780 to 940°C and reaction with host magmas at over 1000°C.The Barrington gemfield includes two distinct corundum suites. One, typical in eastern Australia, is dominated by blue-green, well-crystallized, growth-zoned sapphire, commonly containing rutile silk and Ferich spinel inclusions (Hc 51–73, Mt 18–35, Mf 6–8, Usp 2–6). The other, an unusual suite, is dominated by ruby and pastel coloured sapphires, with little crystal shape or growth zonation and restricted mineral inclusions, mostly chromian pleonaste and pleonaste. The ruby-sapphire-sapphirine-spinel aggregates provoke new thoughts on the origin of rubies and sapphires and their indicator minerals in eastern Australian and southeastern Asian volcanic gemfields.
Mineral chemistry and geochronology of the potassic alkaline ultramafic Inagli complex, Aldan Shield, eastern Siberia
Authors: Mues-Schumacher U. , Keller J. , Kononova V. A. , Suddaby P. J. 
Published: December 2006

AbstractThe Inagli complex, one of several Mesozoic intrusive complexes of the Aldan Shield (Siberian Platform), exhibits a concentric structure comprising several alkaline ultramafic rock-types. A central dunite body is surrounded by olivine- and phlogopite-clinopyroxenites forming an inner rim. The outer rim consists of different shonkinitic and malignitic rocks. The K-Ar ages obtained for the whole complex vary around 132 Ma.The dunites and clinopyroxenites are characterized by cumulate textures. With increasing modal abundances of clinopyroxene and subordinate phlogopite, the rocks develop to olivine-clinopyroxenite, shonkinite, and malignite with intercumulus potassium feldspar. Mineralogical characterization of the rocks suggests they evolved by fractional crystallization. The highly forsteritic olivines (Fo up to 95) require a melt as magnesian as mg# 87.1, representing ±26 wt.% MgO. The parental melt is likely to be an olivine-, H2O- and K2O-rich picritic liquid of shoshonitic character. Major and trace element systematics show highLILE/LREEandLREE/HFSEratios indicating the involvement of a subduction zone component in the genesis of these rocks.
Solubility and spectrochemical characteristics of synthetic chernikovite and meta-ankoleite
Authors: Van Haverbeke Laurent , Vochten Renaud , Van Springel Karel 
Published: December 2006

AbstractChernikovite and meta-ankoleite were synthesized with a relatively high crystallinity and the compounds were identified by means of chemical analysis and X-ray diffraction. The infrared spectra were recorded and the bands assigned. From the luminescence spectra, the band-gap energy for both compounds was calculated as 2.35 eV, indicating that they must be considered as insulators. The dependence of the solubilities of these compounds on the acidity of the solution was studied, and the dominant ionic species were determined. The pKsp values of chernikovite and meta-ankoleite were found to be 22.73±0.24 and 24.30±0.81 respectively.
Wesselsite, SrCu[Si4O10], a further new gillespite-group mineral from the Kalahari Manganese Field, South Africa
Authors: Giester G. , Rieck B. 
Published: December 2006

AbstractWesselsite, SrCu[Si4O10], is a new mineral species from the Wessels mine, Kalahari Manganese Field, South Africa, and it belongs to the gillespite group. Wesselsite is tetragonal, space group P4/ncc; the unit cell parameters, refined from Gandolfi film data, are a = 7.366(1), c = 15.574(3) Å V = 845.01 Å3. The strongest lines are (dobs/lobs/hkl) (7.79/35/002), (4.33/20/112), (3.89/20/004), (3.44/40/104), (3.33/100/202), (3.12/55/114), (3.03/50/212), (2.68/25/204), (2.61/30/220) and (2.32/30/116). Wesselsite is associated with hennomartinite, embedded in a matrix of sugilite, xonotlite, quartz and pectolite. Microprobe analyses of 111 samples show that it is the end-member of a solid solution series with effenbergerite, BaCu[Si4O10], with substitutions of Sr by Ba up to 50 mol.%. Wesselsite forms tiny subhedral plates in sizes not exceeding 50 × 50 × 5 µm, arranged in clusters of up to 200 µm. It shows a perfect cleavage parallel to {001}, has blue colour, white to light blue streak, and is uniaxial negative with ω = 1.630(2), ε = 1.590(5), strongly pleochroic from blue (ω) to pale blue (ε). The calculated density is 3.32 g cm−3, the measured density is 3.2(1) g cm−3.
MgSiO3 perovskite: a HRTEM study
Authors: Hassan Ishmael , Kudoh Yasuhiro , Buseck Peter R. , Ito Eui 
Published: December 2006

AbstractSelected-area electron diffraction patterns for the [110] zone of MgSiO3 perovskite are consistent with the orthorhombic unit cell obtained by X-ray diffraction (a = 4.775, b = 4.929, c = 6.897 Å). Various areas of a crystal fragment show diffuse streaking along c*, and well-developed satellite reflections that give a 3-fold repeat along [10]*. Another fragment shows doubled cell dimensions when viewed down [30]. The variable occurrence of the satellite reflectioncs and diffuse streaking indicate subtle variations in ordering, chemistry, or both. Images obtained by high-resolution transmission electron microscopy contain perfectly ordered regions, out-of-phase boundaries, and intergrowths of the two orthorhombic forms of perovskite.
Microwave techniques for the synthesis and deuteration of minerals, with particular reference to scorodite, FeAsO4.2H2O
Authors: Baghurst David R. , Barrett Jack , Coleyshaw Esther E. , Griffith William P. , Mingos D. Michael P. 
Published: December 2006

AbstractMicrowave dielectric heating methods for the preparation of a number of arsenate, phosphate, vanadate, molybdate and carbonate minerals and their deuterated analogues are reported; rapid and efficient syntheses of these have been achieved. The application of this to the study of vibrational spectroscopy of minerals is discussed, with particular reference to scorodite.
Cellular precipitates of iron oxide in olivine in a stratospheric interplanetary dust particle
Authors: Rietmeijer Frans J. M. 
Published: December 2006

AbstractThe petrology of a massive olivine-sulphide interplanetary dust particle shows melting of Fe,Ni-sulphide plus complete loss of sulphur and subsequent quenching to a mixture of iron-oxides and Fe,Ni-metal. Oxidation of the fayalite component in olivine produced maghemite discs and cellular intergrowths with olivine and rare andradite-rich garnet. Cellular reactions require no long-range solid-state diffusion and are kinetically favourable during pyrometamorphic oxidation. Local melting of the cellular intergrowths resulted in three dimensional symplectic textures. Dynamic pyrometamorphism of this asteroidal particle occurred at ∼1100°C during atmospheric entry flash (5–15 s) heating.
Iridescent anthophyllite-gedrite from Simiuttat, Nuuk district, southern West Greenland composition, exsolution, age
Authors: Rodgers K. A. , Kinny P. D. , McGregor V. R. , Clark G. R. , Henderson G. S. 
Published: December 2006

AbstractGolden iridescent, <1–100 mm crystals of alternating lamellae of anthophyllite and gedrite constitute the bulk of orthoamphibolite pods within quartz-cordierite gneisses of the Akulleq terrane at Simiuttat, SW Greenland. X-ray powder diffraction powder gavea= 18.526(7),b= 17.979(15),c= 5.285(23) Å; a single crystal hasa= 18.546(7),b= 17.950(16),c= 5.280(1) Å, space groupPnmawith some reflections being notably broader than others. Spot EMPA yielded composite analyses: AlIV= 0.89–1.3, Mg/(Mg+Fe2+) = 0.57–0.61, Na/AlIV= 0.22–0.26. AFM imaging of {210} cleavage surfaces, showed a uniform corrugated morphology parallel to [001]; wavelength was 190–350 nm, mean 250 nm, amplitude 3 nm. A plan view resembles TEM images of (010)-parallel exsolution textures of orthoamphiboles. A second set of corrugations may crosscut the [001]-parallel ridges at 20–25°, akin to reported lamellar intergrowths developed parallel to both (010) and (120). Unequivocal evidence linking topography with lamellae is absent. In contrast to the conventional multi-layer reflector model, the ridged surface provides an additional origin for iridescence, acting as a diffraction grating. Included zircons, 50–10 μm, have Hf/Zr = 0.008–0.012, Hf+FeIIc. 0.16.207Pb/206Pb ages are from 2690 to 2770 Ma, averaging 2732±10 Ma. Coexisting, included Th-, La-, Ce-, Pr-, Nd-, Gd-, Y-monazites have207Pb/206Pb ages from 2680 to 2720 Ma, averaging 2707±12 Ma. The included crystals grew during a late Archaean metamorphism that produced overgrowths on zircons within gneisses to the north, but with Simiuttat grains showing a more complex history. The lamellae may have developed at the same time, or during a reheatingc. 2550 Ma, or in a subsequent Proterozoic metamorphism.
Application of MAS NMR spectroscopy to poorly crystalline minerals: viséite
Authors: Kim Yeongkyoo , James Kirkpatrick R. 
Published: December 2006

AbstractViséite is a poorly crystalline mineral which is difficult to study by X-ray diffraction pattern. NMR is a very useful technique to study such poorly crystalline minerals, and 31P, 27Al, and 29Si MAS NMR in conjunction with powder XRD results show that at least our Viséite sample is not a single phase with a structure analogous to that of analcime as previously reported. Rather, it is very disordered with a structure similar to that of crandallite and includes other phases including an undefined aluminophosphate, opal, and a framework aluminosilicate, probably a zeolite. The previously reported variations in the Si content of Viséite are probably due to variable amounts of opal and the framework aluminosilicate.
A neutron powder diffraction determination of the thermal expansion tensor of crocoite (PbCrO4) between 60 K and 290 K
Authors: Knight Kevin S. 
Published: December 2006

AbstractThe thermal expansion tensor of crocoite has been determined from high-resolution neutron time-of-flight powder diffraction data. The temperature dependence of the lattice constants between 4.5 K and 290 K have been fitted to a quasi-harmonic Einstein model, and the temperature dependence of the thermal expansion tensor has been calculated for 60 K ≤ T ≤ 290 K. The magnitudes of the principal expansivities and their orientation exhibit saturation behaviour for temperatures above 300 K. The predicted saturated expansion coefficients are α11= 33.1(1) × 10−6K−1, α22= 15.72(3) × 10−6K−1, α33= 3.36(1) × 10−6K−1, with α22parallel to b and α11lying at an angle of −37.86(5)° to c for theP21/nsetting of the crystal structure. The direction of maximum expansion is approximately parallel to bothand the least-squares line passing through the projection of the chromium atoms on (010). The direction of minimum expansion lies approximately parallel to [101]. No evidence was found for either a structural or magnetic phase transition between 4.5 K and 300 K.
The geometry and evolution of magma pathways through migmatites of the Halls Creek Orogen, Western Australia
Authors: Oliver N. H. S. , Barr T. D. 
Published: December 2006

AbstractIn the Halls Creek Orogen of north-western Australia, the distance of melt migration through migmatitic metasedimentary rocks and adjacent metabasites is partly constrained by relationships of leucosomes and small mafic magma veins to rock boundaries and structural elements. Stromatic leucosomes in metasediments are cut by a network of small extensional fractures and shear zones, oriented steeply during melt migration. These shear zones allowed cm- to 10 m-scale migration of felsic magma derived by in situ anatexis. In the adjacent metabasite layers, a similar shear array allowed injection of H2O-undersaturated mafic to ultramafic magma, locally dehydrating and chemically modifying these rocks. However, these mafic to ultramafic veinlets are too mafic to be explained by in situ anatexis, necessitating an external magma source. Also, the lack of felsic veinlets cutting metabasites, and mafic veinlets cutting metasediments, requires that vertical inter-connectivity of these fracture systems was restricted. We propose along-layer migration of mafic to ultramafic magma through the metabasite, assisted by horizontal connection of the shear zones. This migration occurred independantly of metre-scale felsic magma migration in the adjacent metasediments, even though these two deformation-assisted magma migration systems may have been operating at the same time.