bluuebunny/crossref_metadata_2025_split huggingface dataset:
An applied mineralogical investigation of concrete degradation in a major concrete road bridge
Authors: Macleod G. , Hall A. J. , Fallick A. E. 
Published: December 2006

AbstractA core of concrete taken from a major road bridge in the Strathclyde Region, Scotland, has been subjected to an applied mineralogical investigation, which involved stable isotope analysis, petrography, X-ray diffraction and scanning electron microscopy.The structure is actively undergoing severe degradation due to mineral growth which is related to chemical reactions between the concrete and pore fluid. The physical growth of minerals causes disfigurement and structural weakening.Pyrite and pyrrhotine hosted by dolerite aggregate appear to have been oxidized, providing sulphate for the deposition of ettringite and minor gypsum, in spheroidal cavities within the cement paste. The rainwater which passes through the structure mobilising sulphate from original gypsum in the paste and oxidizing the iron sulphides is also involved in the further leaching of elements from the cement paste and in the deposition of calcite. The isotopic values of calcites forming a crust on the concrete and a stalactite under the bridge are similar with δ13C= −19‰ PDB and δ18‰= +16‰ SMOW. We suggest that atmospheric carbon dioxide was the carbon source. The carbon isotopic fractionation of −12‰ from atmospheric carbon dioxide of δ13C= −7‰, (O'Neil and Barnes, 1971) can best be explained as due to a kinetic fractionation related to the hyper-basicity of the pore water. The equilibrium formation temperature of about 45°C calculated from the oxygen isotope values and assuming a δ18O value of meteoric water of −8‰ SMOW, is considered unreasonable. The exceptionally low δ18O values are attributed mainly to reaction kinetics and the calcite inheriting its oxygen, two-thirds from atmospheric carbon dioxide and one third from the meteoric formation water (O'Neil and Barnes, 1971). A δ18O value of atmospheric carbon dioxide of +41‰ SMOW and a δ18O value of meteoric water of −8‰ SMOW, lead to a calculated δ18O value for the calcites of +10‰ SMOW. The calcites analysed have a value of +16‰ and this may be due to partial re-equilibration towards a calculated value of +21‰ for calcite in equilibrium with the meteoric water at 20°C.
Geothermometry and Geobarometry—introduction
Authors: Yardley B. W. D. , Schumacher J. C. 
Published: December 2006

The following four papers are a representative subset of the talks that were given during a lively session at the 1989 Winter Meeting of the Mineralogical Society (19 and 20 December), organised by us on behalf of the Metamorphic Studies Group on the theme of ‘Geothermometry and Geobarometry’. The talks at the meeting fell broadly into three groups: those dealing with fundamental problems of obtaining the requisite compositional and thermodynamic data, case studies of the applications of thermometers and barometers, and discussions of the limitations of the approach imposed by kinetic factors.The first group of talks included contributions by T. J. B. Holland and J. Lieberman (co-authors M. Engi and R. G. Berman) dealing with perhaps the major hurdle in the way of reliable geothermometry and geobarometry: the question of activity-composition relationships for natural minerals. Holland took the examples of the pyroxenes and the plagioclase feldspars and showed, respectively, how Landau theory could be utilised to take account of ordering, and how Darken's quadratic formalism can take account of a structural break.
Empirical ferric iron corrections: necessity, assumptions, and effects on selected geothermobarometers
Authors: Schumacher John C. 
Published: December 2006

AbstractThe ferromagnesian silicate minerals, such as garnets, pyroxenes, micas, and amphiboles, appear in a variety of geothermometers and geobarometers. Where complete chemical analyses are available and regardless of bulk composition (metamorphosed pelitic or mafic), the aforementioned minerals commonly contain ferric iron. In mineral analyses using the electron microprobe, ferric and ferrous iron are not distinguished, and all the iron is treated as FeO. In ferric Fe-bearing minerals, this treatment results in (1) low analytical sums and (2) excess cations in the mineral formulae. Assuming ideal stoichiometry (ideal formula cations and oxygens) allows direct ferric estimates in garnets and pyroxenes; amphiboles require additional assumptions concerning site occupancies, and, for micas, no acceptable constraint exists for a ferric estimate. Based on ferric iron determinations for some metamorphic ferromagnesian silicates, the proportion of ferric to total iron increases at higher XMg values. The influence of ferric estimates on T and P calculations depends on the model used and on the extent the ferric estimate alters the relative proportions of end-members. Several examples suggest that, in general, if ferric estimates (or determinations) are made, they should be made for all the relevant minerals.
Geothermometry and geobarometry of high-grade rocks: a case study on garnet-pyroxene granulites in southern Sri Lanka
Authors: Faulhaber S. , Raith M. 
Published: December 2006

AbstractIn the central granulite belt of Sri Lanka, garnet-pyroxene granulites of granitic and gabbro-noritic composition are the most abundant rock types. The micro-structures and mineral chemistry data prove complete attainment of textural and large-scale chemical equilibrium during and following a phase of extreme penetrative deformation at conditions of the granulite facies (800–850 °C, 5 to 9 kbar). On a local scale, especially along the intergranular system, continued cation exchange decoupling from the early ceasing net-transfer reactions destroyed the near-peak metamorphic equilibrium. The extreme compositional variation of the coexisting ferro-magnesian phases (Fe/(Fe + Mg): gar 0.98−0.65, opx 0.92−0.40, cpx 0.88−0.28) and the near-isothermal conditions of equilibration throughout the studied area enabled examination of the effects of non-ideal mixing in garnet and pyroxenes on the equilibrium constants of reactions used in geothermobarometry, and tests on the quality of commonly applied thermometers/barometers and the validity of activity models adopted in the calibrations. The Sri Lankan data set reveals more or less pronounced compositional dependences for all of the tested gar-opx/gar-cpx Fe-Mg exchange thermometers and the opx + plg ⇌ gar + qtz barometers. Evidently the recommended solution models do not adequately describe the mixing properties of the involved ferro-magnesium mineral phases (garnet, orthopyroxene and clinopyroxene).
Thermal and kinetic constraints on the tectonic applications of thermobarometry
Authors: Crowley Peter D. 
Published: December 2006

AbstractMetamorphic petrology, and in particular quantitative thermobarometry, offer the possibility of identifying faults in metamorphic terrains by the metamorphic and/or thermobarometric breaks that occur across them. Furthermore, the sense of the thermobarometric break (e.g. warmer, deeper rocks on top of colder, shallower ones) and its magnitude could be useful tools for determining the sense and magnitude of the fault. The sensitivity of thermobarometry to tectonic variables such as fault throw and uplift rate, has been tested by a series of one-dimensional numerical re-equilibration models for both thrust and normal faults. In each of these models, the post-tectonic re-equilibration of a model garnet-biotite geothermometer is simulated by coupling one-dimensional numerical thermal and garnet diffusion models. After cooling and uplift, a thermobarometric temperature was calculated by using a near-rim garnet composition (5–10 µm from the rim) calculated by the re-equilibration model and biotite from the model matrix. The models varied the thermal structure of the model orogen prior to faulting, the depth of the fault, the structural throw of the fault, and the uplift rate following faulting.All models produced zoned garnet porphyroblasts that recorded P-T conditions that were different from those at the time of fault motion. Most of the models produced thermobarometric breaks that were in the same sense as the temperature break at the time of fault motion. Normal faults produced a normal thermobarometric gradient with higher temperatures recorded below the fault than above it. Many, but not all of the thrust models produced a thermobarometric inversion near the fault, with higher temperatures locally recorded above the fault than below it. However, the magnitude of thermobarometric break correlated poorly with the fault throw. Most models developed thermobarometric breaks that were much smaller than the breaks that existed at the time of fault motion. The size of the thermobarometric break was commonly of the same magnitude as would be generated from microprobe analytical error. The models suggest that for metamorphic rocks whose thermal peak does not exceed a narrowly defined closure temperature, thermobarometry faithfully recorded the P-T conditions of the metamorphic peak. The closure temperature increases slightly with increasing uplift rate, but overall is rather insensitive to the uplift rate or other tectonic variables. For rocks whose thermal peaks is above the closure temperature, however, the model thermobarometer recorded a temperature that was very close to the closure temperature.
Temperature-HF fugacity trends during crystallization of calcite carbonatite magma in the Fen complex, Norway
Authors: Andersen Tom , Austrheim Håkon 
Published: December 2006

AbstractCalcite carbonatite (søvite), associated apatite cumulates and contact metasomatic phlogopite-rocks in the Fen complex (S. Norway) contain coexisting apatite and phlogopite. Two distinct compositional groups are recognized: fluorapatite (XF= 0.5–0.8) coexists with hydroxy-phlogopite withXF= 0.11–0.26, whereas hydroxyapatite (XF= 0.34–0.44) coexists with low-F hydroxy-phlogopite (XF≈ 0.03). Apatite-biotite geothermometry suggests that the minerals equilibrated at igneous temperatures (less than 1200 toca.625 °C), and were not significantly disturbed by late low-temperature re-equilibration. This, combined with HF-barometry based on apatite-fluid and phlogopite-fluid F-OH exchange equilibria, makes it possible to recognize two crystallization trends at different levels of hydrogen fluoride fugacity. The existence of such trends reflects internal buffering of the HF fugacity by apatite and/or phlogopite. The recorded differences in HF fugacity suggest that two or more independent or semi-independent lines of magmatic descent gave rise to calcite carbonatite magma in the Fen complex. Combined apatite-phlogopite geothermometry and hydrogen fluoride barometry is a useful tool enabling us to see through post-magmatic alteration of carbonatites, and to establish primary magmatic controls even in cases where carbonate and iron-titanium oxide minerals have re-equilibrated at much lower temperatures.
Silicate mineralogy of the Behelvie cumulates, N E Scotland
Authors: Wadsworth W. J. 
Published: December 2006

AbstractUltramafic, troctolitic and gabbroic rocks at the northern end of the Belhelvie layered intrusion display progressive cryptic variation over a stratigraphic thickness of approximately 800 m in steeply-dipping cumulates, which young from W to E. This variation is shown by olivine (Fo87−77), orthopyroxene (En87−79), clinopyroxene (Ca45Mg48Fe7 to Ca44.5Mg45.5Fe10) and plagioclase (An81−75). The Belhelvie succession is believed to be equivalent to the poorly-exposed and structurally complex Insch Lower Zone. A laterally impersistent hypersthene-gabbro unit within the main sequence is re-interpreted as a downfaulted block of slightly more evolved cumulates. A repeat sequence of peridotites, troctolites and gabbros on the eastern side of the intrusion, and separated from the underlying main succession by a thin septum of country rock, is believed to represent a fresh influx of magma.
Zoned hibonites from Punalur, South India
Authors: Santosh M. , Sandiford M. , Reed S. J. B. 
Published: December 2006

AbstractZoned hibonites from a kalsilite, leucite, spinel, corundum, perovskite gneiss from the southern Indian granulite terrain near Punalur, Kerala, have rims that are the most Ti-rich yet recorded (0.83–0.87 Ti atoms per 19 O) and are essentially free of REE elements (ΣREE < 0.01 atoms per 19 O) while the cores are the most REE-rich compositions yet recorded (ΣREE = 0.55–0.65 atoms per 19 O). Within the limits of analytical uncertainty, the compositions of the hibonite can be related to the theoretical end-member CaAl12O19 by the substitutions REE R2+ ⇌ CaAl and R2+R4+ ⇌ Al2 with the REE-rich cores containing in excess of 50% of the REE R2+ Al11O19 end member. Minor substitution of Na for Ca occurs in the rims, while non-stoichiometry in both the cores and rims is indicated by partial 12-fold site occupancy. Ion-microprobe analysis of the REE-rich hibonites reveals strong enrichment in LREE with La/Lu c. 250 000.
The synthesis and composition of georgeite and its reactions to form other secondary copper(II) carbonates
Authors: Pollard A. M. , Thomas R. G. , Williams P. A. , Just J. , Bridge P. J. 
Published: December 2006

AbstractComparison of the infrared spectra of georgeite and a phase which can be reproducibily synthesised in the laboratory shows that the mineral is an amorphous analogue of malachite, Cu2CO3(OH)2. Synthetic studies also explain the chemical conditions under which georgeite may form, as well as those which can cause it to react to either malachite or chalconatronite. Parallels may be drawn between the laboratory observations and known mineral associations of georgeite.
Apophyllite and other zeolite-type minerals from the Whin Sill of the northern Pennines
Authors: Young B. , Dyer A. , Hubbard N. , Starkey R. E. 
Published: December 2006

AbstractApophyllite, analcite, chabazite, prehnite and stilbite are described from pectolite-, chlorite-, calcite- and quartz-bearing veins and joint coatings in the late Carboniferous quartz dolerite of the Whin Sill of the northern Pennines. These veins represent the final hydrothermal stages in the sill's emplacement and are not related to the widespread lead-zinc-barium-fluorite mineralization of the northern Pennine orefield. Thermogravimetric studies of apophyllites from the two Whin Sill occurrences reveal that at one locality the minreal is fluorapophyllite, at the other hydroxyapophyllite.
Sulphur isotope evidence for the origin of cave evaporites in Ogof y Daren Cilau, south Wales
Authors: Bottrell Simon H. 
Published: December 2006

AbstractGypsum evaporites are forming under desiccating conditions in relict cave passages in Mynydd Llangattwg, south Wales. Sulphur isotope compositions of these sulphates indicate that oxidation of diagenetic pyrite in the overlying Millstone Grit is the source of sulphate solutions, rather than dissolution of evaporitic sulphate in the limestones.
The petrochemistry of the Lower Proterozoic metamorphic rocks from the Dabieshan-Lianyungang area, the southeastern margin of the North China Platform
Authors: Longkang Sang 
Published: December 2006

AbstractBased on geological studies, 141 rock analyses and 5 trace element analyses of metabasites, the present paper deals with the rock association, chemical features, protolith formation and the original tectonic settings upwards through the Lower Proterozoic metamorphic strata in the Dabieshan-Lianyungang area, in the south-east of the North China Platform. The results of the study indicate that the lower and middle parts of the metamorphic strata comprise terrigenous clastics, phosphoritic and aluminous sedimentary formations which formed under stable continental margin conditions. In the middle-upper part a calc-alkaline volcano-sedimentary formation under the active continental margin was developed. The Lower Proterozoic meta-strata of sedimentary-volcanosedimentary origin from bottom upwards suggest that the tectonic evolution of the south-eastern margin of the North China Platform is a process from stabilization to mobilization. This process suggests a northward subduction of the Yangtze Plate under the North China Plate during the later part of the early Proterozoic.
Competitive diffusion-controlled growth of porphyroblasts
Authors: Carlson William D. 
Published: December 2006

AbstractIn a diffusion-controlled process of nucleation and growth, adjacent porphyroblasts compete with one another for nutrients. When the effects of this competition are evaluated quantitatively for garnet porphyroblasts in pelitic rocks from the Picuris Range of New Mexico (U.S.A.), significant correlations arise between crystal sizes and the volumes of the domains from which the crystals drew their nutrients. These correlations strengthen the conclusion drawn from earlier work on spatial dispositions, zoning patterns, and crystal size distributions that the kinetics of intergranular diffusion governed the crystallisation of these porphyroblasts.Computer simulations indicate that competition for nutrients during diffusion-controlled growth may have small but detectable effects on crystal size frequency distributions. Diffusional competition therefore introduces relatively minor inaccuracies into attempts to extract quantitative information on crystallisation processes from size distributions using models for the growth of isolated porphyroblasts. In contrast, the effects of diffusional competition on patterns of compositional zoning may be substantial, especially for porphyroblasts in rocks for which chemical inhomogeneity of the precursor leads to strongly clustered spatial dispositions. In such rocks, clustering may alter the patterns of compositional zoning in ways that obscure evidence for diffusion-controlled growth.
Coupled substitutions in goldfieldite–tetrahedrite minerals from the Iriki mine, Japan
Authors: Shimizu Masaaki , Stanley Chris J. 
Published: December 2006

AbstractChemical compositions of goldfieldite-tetrahedrite series minerals from the Iriki mine in Japan are reported for the frst time. The compositional variations of coexisting goldfieldite [atomic proportion Te > (Sb + As + Bi)], tellurian tetrahedrite [Sb > (Te + As + Bi)], and Te-free tetrahedrite from this locality are considered alongside data from the literature. These show that the substitution of (Sb, As)3+ for Te4+ in natural goldfieldite-tetrahedrite series minerals occurs by the following two mechanisms: (i) tetrahedrite, and goldfieldite, form a continuous solid-solution according to the coupled substitution of Cu+Te4+ for (Cu,Fe,Zn)2+(Sb,As)3+, and (ii) goldfieldite, and the ideal end-member, might also form a continuous solid-solution by the coupled substitution of ☐(vacancy)Te4+ for Cu+(Sb,As)3+. According to this work, the general formulae of tellurian tetrahedrite and goldfieldite are, therefore, respectively, , with x = 0 to 2 and , with y = 0 to 2.
Arsenic-silver incompatibility in fahlore
Authors: Ebel Denton S. , Sack Richard O. 
Published: December 2006

AbstractSilver-bearing zinc-iron tetrahedrite-tennantite and freibergit fahlores approximating the simplified formula (Ag,Cu)10(Fe,Zn)2(As,Sb)4S13 have been equilibrated with excess electrum (AuxAg1−x) and chalcopyrite + pyrite + iron-bearing sphalerite (CuFeS2 + FeS2 + Fe0.05Zn0.95S) in evacuated silica tubes at 300 °C, in reversed silver-copper exchange experiments with less than 0.1 mg NH4Cl added as a transport medium. A thermodynamic formulation and parameters describing As-Ag incompatibility at 400 °C (Ebel and Sack, 1989), which incorporate large temperature dependencies of standard-state properties and composition-ordering systematics, are shown to apply equally well to these 300 °C results. A generalised graphical model for this mineral assemblage is presented, describing fahlore composition as a function of temperature and the compositions of coexisting electrum and (Fe,Zn)S, which define the Ag(Cu)−1 and Fe(Zn)−1 exchange properties controlling fahlore compositions.
Phase relations of aenigmatite minerals in a syenitic ejectum, wonchi volcano, Ethiopia
Authors: Gaeta Mario , Mottana Annibale 
Published: December 2006

AbstractWonchi volcano (Ethiopia) is the second locality for wilkinsonite, the new mineral related to aenigmatite via the coupled substitution 2Fe3+ = TiFe2+. Wilkinsonite occurs as relics surrounded by rims of riebeckite and biotite in a syenitic ejectum which also contains microphenocrysts of aenigmatite. The two minerals do not represent an equilibrium pair. They both formed in the magma chamber under plutonic to hypabyssal conditions, but during two following stages of crystallisation separated by a major drop in ƒO2 conditions.
Petrogenetic implication of the Mössbauer hyperfine parameters of Fe3+-chromites from Sukinda (India) ultramafites
Authors: Mitra Sachinath , Pal Tapan , Pal Taraknath 
Published: December 2006

AbstractChromites from two horizons of the Sukinda area (India) marked as ‘grey ore’ and ‘brown ore’ zones have been studied by57Fe Mössbauer spectroscopy, which revealed that both chromite types are oxidised and have a type of disordered spinel structure in which octahedral sites are occupied by Fe2+ions.The spectra of the grey ore sample can be fitted to three doublets corresponding to Fe2+(A), Fe3+(A) and Fe2+(B) sites. This sample is less oxidised than the brown ore, in which progressive oxidation in the magmatic (?) stage led to the complete conversion of Fe2+inAsites to Fe3+. The spectra of the brown ore are characterised by two doublets correpsonding to two tetrahedral (A) sites of Fe3+with different next-nearest neighbour configurations and a third doublet for Fe2+at theBsite. The brown ores have higher chromium and Fe3+content and have lesser amounts of Ni and Al in comparison to the grey ores. Megascopically, the former shows larger crystal sizes. The high Fe3+content in the brown ore suggests that this type of chromite was formed in a region of highƒO2in the magmatic environment. This perhaps occurred at the part of the mantle where the temperature was higher and the rate of cooling was slower than that of the grey ores which crystallised in the magmatic melt.
Relict clinopyroxenes from within-plate metadolerites of the Petroi Metabasalt, the New England Fold Belt, Australia
Authors: Asthana Deepanker 
Published: December 2006

AbstractRelict clinopyroxenes from metadolerites of the Early Permian Petroi Metabasalt formation, studied by electron microprobe, show a limited compositional range near the diopside-augite boundary in the pyroxene quadrilateral. Clinopyroxene analyses from three metadolerites, grouped in approximately equal Fs contents, define an overall smooth trend between Fs10 and Fs16. This is typical of clinopyroxenes from mildly alkaline basic magmas. Pyroxene stoichiometry suggests high Fe3+ contents (0.04 to 0.20 a.f.u.), which with high Al (0.10 to 0.31 a.f.u.) and Ti (0.03 to 0.08 a.f.u.) implies that CaTiAl2O6 and CaFe3+AlSiO6 are important ‘other components’. Relative Alz in CaFe3+AlSiO6 decreases and consequently CaTiAl2O6 increases with progressive fractionation. This, with the Fe2+:Fe3+ ratios in the Petroi clinopyroxenes, suggests falling ƒO2 in the magma with fractionation. The ƒO2 controlled entry of Alz, Tiy and Nax into the clinopyroxenes and hence the Petroi clinopyroxene trend.