bluuebunny/crossref_metadata_2025_split huggingface dataset:
Carbon neutrality: Operations management research opportunities
Authors: Zhang Qingyu , Wong Christina W. Y. , Klassen Robert 
Published: March 2024

AbstractClimate change, primarily driven by greenhouse gas emissions (GHGs), is a pressing environmental and societal concern. Carbon neutrality, or net zero, involves reducing carbon dioxide emissions, the most common GHG, and then balancing residual emissions through removing or offsetting. Particularly difficult challenges have emerged for firms seeking to reduce emissions from Scope 1 (internal operations) and Scope 3 (supply chain). Incremental changes are very unlikely to meet the objective of carbon neutrality. Synthesizing a framework that draws together both the means of achieving carbon neutrality and the scope of change helps to clarify opportunities for research by operations management scholars. Companies must assess and apply promising technologies, form new strategic relationships, and adopt novel practices while taking into account costs, risks, implications for stakeholders, and, most importantly, business sustainability. Research on carbon neutrality is encouraged to move beyond isolated discussions focused on specific tactics and embrace a more, though not fully, holistic examination. Research opportunities abound in both theoretical and empirical domains, such as exploring tradeoffs between different tactics, balancing portfolios, and investigating the strategic deployment of initiatives over time. As a research community, we are critically positioned to develop integrative insights at multiple levels, from individual processes to horizontal and vertical partnerships and ultimately to large‐scale systemic realignment and change.
Frontiers of Laser‐Based 3D Printing: A Perspective on Multi‐Photon Lithography
Authors: Zyla Gordon , Farsari Maria 
Published: March 2024

AbstractLasers are instrumental in enabling precise processing and fostering the development of new technologies. Particularly, ultrafast lasers, due to their unique interaction with matter, can achieve not only exceptional spatial precision but also meticulously determine the degree of modification. A prime example of this is laser‐based 3D printing through multi‐photon lithography (MPL). This approach remarkably enables the printing of true 3D structures at the micro‐ and nanoscale, without the need for masks or cumbersome tools, simply by using computer‐aided designs. Owing to these unique capabilities, MPL has emerged as a powerful manufacturing technique across various multidisciplinary fields. The ongoing growth in MPL's utilization has led to notable advancements in printing highly complex structures on different substrates, as well as improvements in resolution and throughput, and the development of novel photosensitive materials, which impressively facilitated MPL's expansion into broader fields over the last few years. In this perspective article, the aim is to highlight these advancements and recent trends in MPL. The current challenges of MPL will be explored, which need to be addressed to ensure its further integration into advanced Additive Manufacturing at the micro‐ and nanoscale. The future perspectives and opportunities of MPL as a laser‐based 3D printing approach will also be discussed.
Stress corrosion cracking susceptibility of a new nickel‐based alloy in different environments
Authors: Chen Zhenyu , Zhu Zhongliang , Khan Hasan I. , Chen Zhengzong , Zhang Naiqiang 
Published: March 2024

AbstractStress corrosion cracking (SCC) susceptibility of a new nickel‐based alloy C‐HRA‐2 under two types of superheated steam (SHS) (0.1 and 8 MPa) and supercritical water (SCW) (25 MPa) at 650°C was studied through slow strain rate tensile tests at a strain rate of 5 × 10−7 s−1. The results indicate that C‐HRA‐2 exhibits SCC susceptibility in both SHS and SCW, and the susceptibility increases with increasing pressure. Transgranular fracture (located inside) characterized by dimples/micropores and intergranular fracture (located at the edge) characterized by rock‐sugar‐like morphology was observed in all specimens. The brittleness of the alloy increases with the increase of medium pressure. A large number of cracks perpendicular to the loading axis were noticed on the gauge surface. The SCC mechanism of C‐HRA‐2 under steam and SCW is dynamic embrittlement.
Study of atmospheric corrosion of zinc in a tropical marine environment rich in H2S, resulting from the decomposition of Sargassum algae
Authors: Ahmed Mahado Said , Lebrini Mounim , Pellé Julien , Rioual Stephane , Amintas Olivia , Boulanger Carole , Lescop Benoit , Roos Christophe 
Published: March 2024

AbstractThe Martinique island, located in the Caribbean Sea, is subject to the stranding of Sargassum algae, which decompose and release toxic gases, such as hydrogen sulfide or ammonia. This study aims to investigate the atmospheric corrosion of zinc in these conditions. For this purpose, three sites in Martinique more or less impacted by Sargassum algae stranding were selected. Mass loss results after 1‐year exposure range from 1.9 µm for the site least impacted to 45.3 µm for the site most affected by Sargassum algae. This high value proves that the presence of Sargassum algae caused significant zinc degradation. The morphological structures and properties of the corrosion products obtained at the impacted and non‐impacted sites differ significantly. In the absence of Sargassum algae, “classical” corrosion products based on hydrozincite, simonkoleite, gordaite, and zinc hydroxylsulfate are observed. In the area close to the Sargassum seaweed stranding, the presence of elemental sulfur products, zinc hydroxylsulfate, and sphalerite is reported.
On a class of doubly nonlinear evolution equations in Musielak–Orlicz spaces
Authors: Akagi Goro , Schimperna Giulio 
Published: March 2024

AbstractThis paper is concerned with a parabolic evolution equation of the form , settled in a smooth bounded domain of , , and complemented with the initial conditions and with (for simplicity) homogeneous Dirichlet boundary conditions. Here, stands for a diffusion operator, possibly nonlinear, which may range in a very wide class, including the Laplacian, the ‐Laplacian for suitable , the “variable‐exponent” ‐Laplacian, or even some fractional order operators. The operator is assumed to be in the form with being measurable in and maximal monotone in . The main results are devoted to proving existence of weak solutions for a wide class of functions that extends the setting considered in previous results related to the variable exponent case where . To this end, a theory of subdifferential operators will be established in Musielak–Orlicz spaces satisfying structure conditions of the so‐called ‐type, and a framework for approximating maximal monotone operators acting in that class of spaces will also be developed. Such a theory is then applied to provide an existence result for a specific equation, but it may have an independent interest in itself. Finally, the existence result is illustrated by presenting a number of specific equations (and, correspondingly, of operators , ) to which the result can be applied.
The potential value of seasonal drought forecasts in the context of climate change: A case study of the African elephant conservation sector
Authors: Black Emily , Boult Victoria , Hirons Linda , Woolnough Steven 
Published: March 2024

AbstractThis study investigates meteorological drought in sub‐Saharan Africa within the context of elephant conservation. Prolonged drought significantly impacts elephants, leading to increased mortality rates and heightened human–elephant conflicts. We assess both the anticipated 21st century changes in impact‐relevant meteorological drought metrics and the efficacy of existing forecasting systems in predicting such droughts on seasonal time scales. The climate change element of our study uses the 6th Coupled Model Intercomparison Project (CMIP6) ensemble to evaluate projected change in 3‐month Standardized Precipitation Index (SPI3). We then carry out a quantitative assessment of seasonal forecast skill, utilizing 110 years of precipitation hindcasts generated by the European Centre for Medium Range Forecasting (ECMWF) system. Our findings indicate that persistent drought is projected to become more frequent over the 21st century in southern Africa, where the majority of elephants reside. Analysis of seasonal hindcasts indicates that, while the forecasts have greater skill than climatology, they remain highly uncertain. Previous work suggests that it may be possible to reduce this uncertainty by contextualizing forecasts within specific climate regimes. However, even with improved forecast skill, effective action hinges on the alignment of forecasts with the practical needs of conservation practitioners. Over the next decades, a co‐production approach will be critical for leveraging seasonal forecasts for climate change adaptation within the conservation sector.
Unconditional H2$$ {H}^2 $$‐stability of the Euler implicit/explicit SAV‐based scheme for the 2D Navier–Stokes equations with smooth or nonsmooth initial data
Authors: Chang Teng‐Yuan , Shiue Ming‐Cheng 
Published: March 2024

AbstractIn this article, we propose ‐unconditional stable schemes for solving time‐dependent incompressible Navier–Stokes equations with smooth or nonsmooth initial data, , . The ‐stability analysis is established by leveraging the scalar auxiliary variable (SAV) approach. When dealing with nonsmooth initial data, we utilize a limited number of iteration of the semi‐implicit scheme followed by the SAV scheme. The overall efficiency is greatly enhanced due to the minimal computational cost of the semi‐implicit scheme and the explicit treatment of the nonlinear term within the SAV approach. The proposed schemes investigate two types of scalar auxiliary variables: the energy‐based variable and the exponential‐based variable. Rigorous proofs of the ‐unconditional stability of both schemes have been provided. Notice that both proposed numerical schemes enjoy unconditional long time stability for smooth and nonsmooth initial data when . Numerical experiments have been conducted to demonstrate the theoretical results.
Processing water birds for food at the Island of Kökar in the Baltic Sea during the medieval and early modern period (ca. CE 1400–1700)
Authors: Kivikero Hanna , Eriksson Viktor 
Published: March 2024

AbstractFew studies have been made of the specific importance of waterfowl as food in the Baltic Sea during the late medieval and early modern period. This study shows the seasonal importance of water birds to island and coastal inhabitants living in the middle of the Baltic Sea during the late medieval and early modern periods (ca. CE 1400–1700) and practical implementations for interpretation of cut and chop marks. The paper is based on a bird bone assemblage retrieved from a remote ecclesial site on the island group of Kökar, which is part of the Åland Islands, as well as historical documents and local specialist knowledge. The site was established by Franciscan friars somewhere in the mid‐15th century. Documents indicate that the friars had landownership, income from taxing nearby fisheries, and the right to seal tithe. These assets were taken over by the crown in the mid‐16th century due to the Reformation and a parish church was established on the same site after the friary was dissolved. The bone assemblages from the site include birds, mammals, and fish. The material shows a relatively small number of chicken bones in relation to waterfowl, allowing one to look closer into the structural food economy around water birds for the area. The bones also show several cut and chop marks, which have been analyzed to explore the possible processing of these birds. The results show that fowling was concentrated to a couple of species most likely during spring when these species were abundant. The placement of the cut and chop marks indicates that a large number of birds were likely processed at the same time.
Computational studies on exothermic carbon–carbon bond cleavages
Authors: Nicolaides Athanassios , Tomioka Hideo 
Published: March 2024

AbstractStructural aspects of single CC bond dissociation energies are examined and it is shown that in certain cases a negative bond dissociation energy (BDE) implies a very weak bond and an unstable species prone to bond breaking resulting in dissociation or structural rearrangement. It is proposed that, in such cases, a better quantitative indicator for the strength of the bond is the activation energy required for its fission. o‐Phenelylene bis(nitrene) 1 is computed to have the most negative CC BDE for an observable species. Under cryogenic conditions, activation energy for the dissociation of this bond has been measured as only 2.8 kcal/mol, making it the weakest that we know of. An explanation based on the formation of two new bonds as responsible for this extremely weak bond is given.
Impact of open‐air processing on atmospheric pressure plasma deposition of poly(ethylene oxide) coatings for antifouling applications
Authors: Dekoster Tijs , Vos Rita , Jans Karolien , Van Roy Willem , Nisol Bernard , Duckert Bastien , Vanleenhove Anja , Delabie Annelies 
Published: March 2024

AbstractAtmospheric pressure plasma deposition (APPD) of poly(ethylene oxide) (PEO)‐like antifouling coatings provides an attractive way to reduce biofouling for reliable biosensor operation. Cold atmospheric pressure plasma jets are designed to operate in open air. This paper demonstrates the impact of open‐air processing on the composition and properties of PEO‐like coatings by APPD with vinyl ether precursors. The open‐air environment inhibits polymerization as indicated by low deposition rates, oxygen incorporation in the coatings, and instability of the coatings in water. The composition and stability of the coatings improve by appropriate nozzle design and by deposition in an environment with lower air content. The resulting PEO‐like coatings are stable and antifouling for an antibody solution and inhibit adhesion of human fibroblast cells.
Conserved proline residues prevent dimerization and aggregation in the β‐lactamase BlaC
Authors: Chikunova A. , Manley M. P. , Heijjer C. N. , Drenth C. S. , Cramer‐Blok A. J. , Ahmad M. Ud Din , Perrakis A. , Ubbink M. 
Published: March 2024

AbstractEvolution leads to conservation of amino acid residues in protein families. Conserved proline residues are usually considered to ensure the correct folding and to stabilize the three‐dimensional structure. Surprisingly, proline residues that are highly conserved in class A β‐lactamases were found to tolerate various substitutions without large losses in enzyme activity. We investigated the roles of three conserved prolines at positions 107, 226, and 258 in the β‐lactamase BlaC from Mycobacterium tuberculosis and found that mutations can lead to dimerization of the enzyme and an overall less stable protein that is prone to aggregate over time. For the variant Pro107Thr, the crystal structure shows dimer formation resembling domain swapping. It is concluded that the proline substitutions loosen the structure, enhancing multimerization. Even though the enzyme does not lose its properties without the conserved proline residues, the prolines ensure the long‐term structural integrity of the enzyme.
Integrating the analysis of human biopsies using post‐translational modifications proteomics
Authors: Bhardwaj Sonali , Bulluss Mitchell , D'Aubeterre Ana , Derakhshani Afshin , Penner Regan , Mahajan MaryAnn , Mahajan Vinit B. , Dufour Antoine 
Published: March 2024

AbstractProteome diversities and their biological functions are significantly amplified by post‐translational modifications (PTMs) of proteins. Shotgun proteomics, which does not typically survey PTMs, provides an incomplete picture of the complexity of human biopsies in health and disease. Recent advances in mass spectrometry‐based proteomic techniques that enrich and study PTMs are helping to uncover molecular detail from the cellular level to system‐wide functions, including how the microbiome impacts human diseases. Protein heterogeneity and disease complexity are challenging factors that make it difficult to characterize and treat disease. The search for clinical biomarkers to characterize disease mechanisms and complexity related to patient diagnoses and treatment has proven challenging. Knowledge of PTMs is fundamentally lacking. Characterization of complex human samples that clarify the role of PTMs and the microbiome in human diseases will result in new discoveries. This review highlights the key role of proteomic techniques used to characterize unknown biological functions of PTMs derived from complex human biopsies. Through the integration of diverse methods used to profile PTMs, this review explores the genetic regulation of proteoforms, cells of origin expressing specific proteins, and several bioactive PTMs and their subsequent analyses by liquid chromatography and tandem mass spectrometry.
Spontaneous Disentanglement and Thermalization
Authors: Buks Eyal 
Published: March 2024

AbstractThe problem of quantum measurement can be partially resolved by incorporating a process of spontaneous disentanglement into quantum dynamics. A modified master equation is proposed, which contains a nonlinear term giving rise to both spontaneous disentanglement and thermalization. It is found that the added nonlinear term enables limit cycle steady states, which are prohibited in standard quantum mechanics. This finding suggests that an experimental observation of such a limit cycle steady state can provide an important evidence supporting the spontaneous disentanglement hypothesis.
Design and multimodal locomotion plan of a hexapod robot with improved knee joints
Authors: Xu Kun , Qin Ripeng , Chen Cheng , Dong Guiyu , Chen Jiawei , Ding Xilun 
Published: March 2024

AbstractHexapod robots represent complex and highly redundant robotic systems capable of handling various tasks in extreme environments, such as planetary exploration and disaster response. To enhance the terrain adaptability and maneuverability of hexapod robots, we present a novel multimodal hexapod robot in this research. Our multimodal hexapod robot design incorporates knee joints with an improved multiparallel quadrilateral transmission mechanism, addressing singularity issues commonly encountered in legged robots. This enhancement not only improves the mechanical transmission characteristics of the knee joints but also increases the workspace of a single leg to achieve leg‐arm reuse functionality. In the presence of flat and structured terrain, the robot seamlessly switches to a wheeled locomotion mode, enabling swift traversal. Conversely, when faced with rough and unstructured terrain, it transitions into a legged mode, employing adaptive gait stability to navigate effectively. A novel operational mode in which the hexapod robot utilizes four legs for body support, while the remaining two legs are repurposed as arms is proposed. This innovative approach empowers the hexapod robot to perform dual‐arm manipulation without the need for additional degrees of freedom for the manipulator. To validate the effectiveness of our designed hexapod robot and multimodal motion planning algorithm, comprehensive experimental testing has been conducted, demonstrating the practicality and versatility of our system.
Toward Culturally Digitized Pedagogy: Informing Theory, Research, and Practice
Authors: McDaniel Dominique Skye 
Published: March 2024

AbstractThe article introduces and defines a theory of Culturally Digitized Pedagogy (CDP), an extension of asset pedagogies, namely culturally relevant and culturally sustaining pedagogies. The purpose of this framework is to add a critical lens for examining digital literacies and integrate culturally sustaining pedagogy principles with the reality of youth of Color's online lives. Research and practice need theories and pedagogies—such as youth digital literacies on social media—situating the conversation in new contexts and the possibilities these spaces cultivate for resisting monocultural and monolingual society by centering the asset‐orientation of youths' grassroots activism in online worlds. Thus, this paper introduces a conceptually grounded framework, culturally digitized pedagogy, which presents a pedagogical proposal aligned with contemporary educational practices and supported by current research. First, I describe the central argument of the article, forwarding a framework of culturally digitized pedagogy. Next, I frame culturally digitized pedagogy by discussing advancements it provides in current research. Then, I situate the unique activism of BIPOC youth. Last, I provide pedagogical interventions, grounded in the framework.
Investigation on Catalytic Cracking Performance of Metal Catalysts for 1,1,2‐TCE
Authors: Ge Xiang , Zhao Jigang , Yuan Xiangqian , Shen Haitao , Wu Shiyong 
Published: March 2024

AbstractPVDC played an irreplaceable role in the field of sealed packaging, and its polymer monomer, VDC, was in short supply. At present, the saponification of 1,1,2‐TCE and sodium hydroxide was used to generate VDC in industry, which was a process with great environmental pollution. Catalytic dehydrochlorination of 1,1,2‐TCE to produce VDC was a green process route, but the selection of catalysts had always been controversial. This study aimed to screen catalysts suitable for industrial applications. The cesium based catalysts with good catalytic performance were systematically characterized and evaluated, and the overall reaction process was calculated using DFT calculation. The experimental results indicated that the cesium chloride catalyst with a 3 % molar fraction had the best catalytic performance, achieving 55.27 % conversion of 1,1,2‐TCE and 76.85 % selectivity for VDC, respectively. The reaction paths and transition state of several catalysts were calculated by DFT method. It was revealed that the activation energy required for the reaction of CsCl catalyst was the lowest, at 130.61 kcal/mol, and the energy of the product VDC was the lowest, at −63.25 kcal/mol, making it the most stable. The calculation results were consistent with the experimental data, indicating that cesium chloride catalyst had the best reaction performance. Therefore, the subsequent research could focus on the method of improving the supported dispersity of cesium chloride catalyst and the development of core‐shell catalyst to lay the foundation for further industrialization.
N‐Pyridylureas as Masked Isocyanates Fort the Late‐Stage Diversification of Pyridine‐N‐Oxides
Authors: Baykova Svetlana O. , Baykov Sergey V. , Geyl Kirill K. , Tolstoy Peter M. , Boyarskiy Vadim P. 
Published: March 2024

AbstractA new method for the synthesis of pyridine‐ and quinoline‐N‐oxides containing a ureido or carbamoyl fragment in position 2 has been developed. This method concluded in the oxidation of relatively readily available substituted N,N‐dimethyl‐N′‐(pyridine‐2‐yl)ureas to the corresponding N‐oxides, followed by modification of the dimethylureide moiety. Being heated to 90 °C in the presence of amines in a solution of DMF or chlorobenzene, N‐oxide of N,N‐dimethyl‐N′‐(pyridine‐2‐yl)urea undergoes a transamination reaction without loss of the N‐oxide function. This produces N‐oxides of N‐alkyl/aryl‐N’‐(pyridine‐2‐yl)ureas in 24–99 % yields, (about 30 examples). Values of the NH protons chemical shifts are a good criterion for the selectivity of the reaction. The reaction is also applicable to N‐oxides of ureas substituted in the pyridine ring and to the quinoline congener. N‐Oxides of pyridine/quinoline‐containing carbamates can be similarly prepared by heating N‐oxides of N,N‐dimethyl‐N′‐(pyridine‐2‐yl)/(quinoline‐2‐yl)‐urea in an appropriate alcohol solution at 120 °C.