bluuebunny/crossref_metadata_2025_split huggingface dataset:
Muscovite solid solutions in the system K2O-MgO-FeO-Al2O3-SiO2-H2O: an experimental study at 2 kbarPH2Oand comparison with natural Li-Free white micas
Authors: Monier Gilles , Robert Jean-Louis 
Published: December 2006

AbstractThis paper presents the results of an experimental study of muscovite solid solutions in the system K2O-M2+O-Al2O3-SiO2-H2O-(HF), withM2+= Mg2+or Fe2+in the temperature range 300-700°C under 2 kbarPH2O. Muscovite solid solutions can be described, in this system, as the result of two substitutions. One is the phengitic substitution (x), which preserves the pure dioctahedral character of the mica; the second is the biotitic substitution (y), which leads to trioctahedral micas and does not change the composition of the tetrahedral layer Si3Al. The general formula of muscovite in this system is K(Al2−x−2y∕3M2+x+y□1−y∕3)(Si3+xAl1−x)O10(OH,F)2. Both substitutionsxandyare more extensive at lower temperatures. The extent of solid solution decreases drastically with increasing temperature.ForT> 600°C, the phengitic substitution (x) becomes negligible, but some biotitic substitution (y) persists. This unsymmetrical decrease of the solid solution of muscovite with increasing temperature is similar to that previously observed in phlogopite, the micas with a tetrahedral layer composition of Si3Al being the most stable. The behaviour of muscovite solid solutions in the ferrous system is qualitatively identical to that observed in the magnesian one, but the extent of solid solution is smaller than with Mg2+. Fluorine neither changes the size nor the shape of the solid solution fields but increases their stability by about 50°C.A comparison of these experimental results with data on natural muscovites is presented. Most natural primary (magmatic) granitic muscovites lie very close to the muscovite end member, in agreement with their high-temperature origin. Low-temperature muscovites (300–400°C), typically muscovites from hydrothermally altered granitic rocks, can have highxandyvalues. The rate of the biotitic substitutionycan reach 0.6, which corresponds to an octahedral occupancy of 2.2 atoms per formula unit (based on 11 oxygens), consistent with the experimental data.
Obradovicite, a new complex arsenate-molybdate from Chuquicamata, Chile
Authors: Finney J. J. , Williams S. A. , Hamilton R. D. 
Published: December 2006

AbstractObradovicite, ideal formula H4CuFe2(AsO4) (MoO4)5 · 12H2O, occurs as fine pea-green clusters on quartz from Chuquicamata, Chile. Obradovicite is orthorhombic, space group Pcnm; a = 15.046, b = 14.848, c = 11.056 Å, Z = 4. The strongest powder pattern lines are (d Å, I, hkl) 10.565(8)(110), 8.906(10)(101), 7.424(8)(020), 5.733(5)(211), 3.761(3)(400), 3.686(4)(032), 3.466(3)(411), 3.344(4)(420). It is biaxial positive with α = 1.790, β = 1.798, γ = 1.811, 2Vz = 81°, a = Z, b = X, c = Y, with strong dispersion and pale yellow pleochroism. Specific gravity is 3.55 (meas.) or 3.68 (calc.) and the Mohs hardness is 2½ with no obvious cleavage. Obradovicite is similar to betpakdalite and sodium-betpakdalite except that it contains essential Cu and K (K > Na).
Erlianite, a new vanadium- and iron-bearing silicate mineral
Authors: Feng Xiancan , Yang Ruiying 
Published: December 2006

AbstractErlianite was found in the Harhada iron deposit along the Jining-Erlian railway, Inner Mongolia Autonomous Region, People's Republic of China. The occurrence formed at a high pressure and low temperature and the mineral occurs sparingly, mainly on fracture surfaces on which there is evidence of movement. It is associated with quartz, magnetite, siderite, albite, stilpnomelane, minnesotaite, deerite, etc.Erlianite is black with a brownish streak, silky lustre and occur as fibres, flakes, and lath-like aggregates. The grain size is 1–2 cm. It is not fluorescent. H = 3.7, D = 3.11. Cleavages on {001} and {100} are perfect; orthorhombic Pmmn or Pm21n with a = 23.20, b = 9.20, c = 13.18, Å and Z = 1. Strongest lines are 11.5(100)(200, 101), 3.05(50)(223,130), 2.89(60)(603,800,231,621), 2.61(60) (523,105,332,224), 2.52(50)(901,115,033,531), and 1.560(50) (12.0.5,14.2.0). Biaxial negative with α = 1.667, β = 1.674, γ = 1.679, 2V = 56–59°. Analysis gave SiO2 38.80, FeO 26.67, Fe2O3 21.26, V2O5 1.15, MgO 1.00, CaO 0.83, MnO 0.55, P2O5 0.051, K2O 0.079, Na2O 0.09, Al2O3 0.19, TiO2 0.38, H2O+ 7.65, H2O- 0.90, total 99.60%, leading to (Fe19.962+Fe2.193+Mg1.33Mn0.42)Σ23.90(Fe11.323+V0.68)Σ12(Si34.73Ti0.26Al0.20Fe0.813+)Σ36O90(OH,O)48 (one unit cell content for O = 138).The sample of the new mineral was discovered in 1977 during an investigation of an iron deposit which has been named ‘M14’. The methods used for studying this mineral included optical microscopy, X-ray powder diffraction, selected area electron diffraction analysis, wet chemical analysis, DTA, TGA, infra-red absorption and Mosbauer spectroscopy.
Moolooite, a naturally occurring hydrated copper oxalate from Western Australia
Authors: Clarke R. M. , Williams I. R. 
Published: December 2006

AbstractMoolooite, a naturally occurring hydrated copper oxalate has been identified in a sulphide-bearing quartz outcrop 12 km east of Mooloo Downs station homestead (25° 01′ 30″ S., 116° 06′ 30″ E.), Western Australia. It has apparently formed by the interaction of solutions derived from bird guano and weathering copper sulphides. Partial microchemical analysis indicates a composition corresponding to CuC2O4 · 0.44H2O. The infra-red spectrum is similar to that of the artificial compound with diagnostic absorption bands at 3490, 2975, 2935, 1980, 1940, 1660, 1365,1320, 830, 510, 390, and 315 cm−1. Powder X-ray diffraction patterns indicate a disordered structure with orthorhombic symmetry; a 5.35, b 5.63, c 2.56 Å, Z = 1. The strongest lines of the powder pattern are [d Å, I, hkl]: 3.88, 100, (110); 2.50, 30, (120); 2.33, 18, (011); 2.31, 25,(101); 2.14, 20, (111); 1.938, 18, (220); 1.787, 25, (121); 1.753, 30, (211); 1.216, 15, (112). Unindexed very weak diffuse lines on some patterns can be indexed assuming a supercell with a′ = a, b′ = 2b, c′ = 2c indicating the presence of ordered crystallites.Moolooite occurs as micro-concretionary crusts and powder in cracks and solution cavities resulting from sulphide oxidation. It is found associated with opaline silica, gypsum, broehantite, antlerite, atacamite, whewellite, sampleite, and libethenite. It is turquoise-green in colour with similar streak, lustre dull to waxy, calculated density 3.43 g/cm3. Moolooite is composed of aggregates of generally sub-micrometre sized equidimensional crystallites with α ∼ 1.57 and γ ∼ 1.95.By analogy with artificial copper oxalate, moolooite is constructed from infinite ribbon-like elementary structural units consisting of alternating Cu2+ and (C2O4)2− ions. These units are arranged en echelon in layers which are stacked with displacements so that octahedral coordination of copper ions is completed by oxygen atoms in adjacent layers. The minimal role played by water in the structure and composition of moolooite distinguish it from other oxalate minerals. Because of the zeolitic character of the water a general formula CuC2O4 · nH2O (0 ⩽ n ⩽ 1) appears to be appropriate.
Santafeite, a re-examination and new empirical formula
Authors: Dunn Pete J. , Peacor Donald R. 
Published: December 2006

AbstractSantafeite, known only from New Mexico, USA, is re-examined using single-crystal X-ray and microprobe techniques. The new idealized formula, consistent with space group requirements, is(Mn2+, Fe3+,Al,Mg)8(Mn4+, Mn2+)8 (Ca,Sr,Na)12[(VO4),(AsO4)]16(OH)20 · 8H2O.
Chrysotile and polygonal serpentine from the Balangero serpentinite
Authors: Mellini Marcello 
Published: December 2006

AbstractTransmission electron microscopy shows that normal chrysotile and polygonal serpentine occur together and in parallel association with balangeroite, within the slip-veins of the Balangero serpentinite. Chrysotile substitutes for balangeroite and it is later replaced by the polygonal serpentine.The chrysotile fibres are packed together according to a rod close-packing scheme, with defects. Lattice images of the polygonal serpentine confirm the structure model proposed by Middleton and Whittaker (1976), consisting of polygonally arranged fiat layers. This structural type is probably common for serpentine minerals and constitutes a fourth main type of layer configuration in 1:1 layer silicates.
Modelling of the relations between reaction enthalpy and the buffering of reaction progress in metamorphism
Authors: Ridley John 
Published: December 2006

AbstractA proportion of the heat added to a body of rock during prograde metamorphism will be absorbed in the chemical work of metamorphic recrystallization. When and where heat is so absorbed will affect the exact thermal histories of the rocks, and hence the metamorphic textures. This paper reports the results of modelling of the inter-relations between reaction progress and thermal histories in a rock column. The results suggest that volumes of rock undergoing reaction at any moment act as heat sinks and absorb heat from the surrounding rock, that reaction generally takes place close to the temperature at which nucleation took place, and that steady heating of a rock pile can give rise to a reaction history in which spurts of reaction are separated by ‘quiet’, non-reactive intervals.
The catalysis of mineral reactions by water and restrictions on the presence of aqueous fluid during metamorphism
Authors: Rubie David C. 
Published: December 2006

AbstractThe problems of characterizing inter-granular regions and of estimating rates of intergranular diffusion in metamorphic rocks are discussed. Inter-granular regions can be anhydrous, hydrated but under-saturated with H2O, or saturated with H2O, but only in the latter case can a free aqueous fluid phase be present. Estimates of intergranular diffusion coefficients (DIGR) at 550°C derived from a variety of published experimental work, vary from ∼ 10−8m2s−1for diffusion of species through an intergranular fluid film to ⩽ 4 × 10−24m2s−1for diffusion of SiO2or O in anhydrous grain boundaries in quartzite. Estimates ofDIGRfor hydrated grain boundaries vary from ∼ 10−13m2s−1to ∼ 10−21m2s−1; the concentration of H2O in the grain boundaries and the identity of the diffusing species (generally unknown) may be important controlling factors, and there exists the possibility of a spectrum of values between these two extremes.Using available kinetic data it is shown that a free aqueous fluid could never have been present in parts of the basement terrane of the Sesia Zone (Western Alps) during uplift from the eclogite facies, except possibly late in the cooling history. The breakdown of sodic pyroxene + quartz occurred in response to the localized infiltration of catalytic aqueous fluid, possibly over a time interval as short as 6–6000 a, and possibly under conditions remote from equilibrium. H2O-present conditions during a dehydration reaction in metapelites of the Adula nappe (central Alps) could also have been of short duration. These examples are consistent with a model in which basement rocks at deep crustal levels are dry for long periods of time and in which the development of equilibrium mineral assemblages and microstructures generally occurs over relatively short periods of time under transitory fluid-present conditions (caused by devolatilization and/or infiltration).
Synthetic Mn-Kilchoanite—a new development in polymorphism of melilite
Authors: Kimata Mitsuyoshi 
Published: December 2006

AbstractTwo compounds with the chemical composition Ca2.32Mn0.68Si2.00O7 were synthesized from a molten carbonating silicate with the melilite composition. The synthetic samples were subsequently characterized by X-ray powder diffraction, IR absorption and EPMA, and they proved to be the anhydrous phases isomorphous with kilchoanite Ca3Si2O7 and åkermanite Ca2MgSi2O7 respectively, and to be polymorphous with each other. Their crystallochemical properties suggest that Mn-åkermanite is a high-temperature structure type of Mn-kilchoanite. Substitution of Mn2+ with an intermediate ionic radius between those of Mg2+ and Ca2+ cations establishes the polymorphic relationship between åkermanite Ca2MgSi2O7 and kilchoanite Ca3Si2O7.
Relationships Between Late Caledonian Lamprophyric, Syenitic, and Granitic Magmas in a Differentiated Dyke, Southern Scotland
Authors: Macdonald R. , Rock N. M. S. , Rundle C. C. , Russell O. J. 
Published: December 2006

AbstractThe 2 km × 5 m Newmains Dyke in the Scottish Southern Uplands consists mainly of primitive (mg number > 70), at least partly mantle-derived lamprophyre (vogesite spessartite, SiO2 50–60%), with hornblende-pyroxene-rich cumulates (SiO2 < 50%) and small amounts of quartz syenitic to granite residua (60–73% SiO2). The lamprophyres and cumulates yield an Rb-Sr whole-rock isochron age of 395±9 Ma (MSWD 2.0), and (87Sr/86Sr)i 0.70514±5—identical values to the nearby Criffell granitic pluton. After some 65% hornblende + clinopyroxene fractionation of parent lamprophyre magma, a volatile phase separated and metasomatically enriched the country rock greywackes in K, Ba, and Rb. The remaining quartz syenitic liquids became contaminated by 87Sr from these greywackes, which have a mean (87Sr/86Sr)395 value of 0.70789±114. Further fractionation of the contaminated syenitic liquids gave the granitic rocks, which have (87Sr/86Sr)395 values of 0.7056–64. The dyke appears to demonstrate in situ some of the hidden processes previously invoked to explain the evolution of the Criffell pluton itself.
Some geochemical constraints upon models for the crystallization of the upper critical zone-main zone interval, northwestern Bushveld complex
Authors: Eales H. V. , Marsh J. S. , Mitchell A. A. , de Klerk W. J. , Kruger F. J. , Field M. 
Published: December 2006

AbstractRatios between elements Mg, Fe, Co, Cr, Ni, V, and Sc are consistently different in mafic rocks of the upper critical zone, and those above the Bastard unit. Within the 300 m section above the Merensky Reef, 87Sr/86Sr ratios increase from c.0.7063 to c.0.7087, irrespective of rock type. Decoupling of Mg/(Mg + Fe2+) ratios and the Ca contents of plagioclase, and wide variations in the proportions of anorthosite within the Bastard, Merensky, and Merensky Footwall units, are inconsistent with anorthosite formation by simple fractional crystallization of magma batches of limited volume. Conversely, significant differences in Sr-isotope ratios show that these anorthosites could not have shared a common parental liquid. These data are used to develop a model whereby (a) the 300 m column above the critical zone represents the mixing of liquids of isotopically and geochemically discrete upper critical and main zone lineages, (b) mafic layers of the Bastard, Merensky, and Merensky Footwall units crystallized from discrete injections of primitive, mafic liquid while (c) the leucocratic upper parts of these units crystallized during progressive hybridization of liquid residua, which remained after significant separation of mafic phases, with a supernatant column representing the liquid residua of earlier cycles, and (d) the buoyancy of plagioclase, and enlargement of the primary phase volume of plagioclase consequent upon an increase in An/Ab ratio of hybrid liquids, were significant factors in the generation of anorthositic layers.
Silicate stages mineralogy in the later fractionation of the Insch intrusion, NE Scotland
Authors: Wadsworth W. J. 
Published: December 2006

AbstractDespite poor exposures and lack of ‘stratigraphic’ control, there is consistent mineralogical and textural evidence that the Insch Upper Zone (UZ) represents a cumulate sequence developed from a single episode of progressive fractionation. This sequence has been subdivided on the basis of the phase layering, with cumulus plagioclase, pyroxenes and Fe-Ti oxides providing continuity from the Middle Zone (although the pyroxenes appear to be temporarily restricted to inter-cumulus status in the lower part of the UZ succession). The reappearance of cumulus olivine after its absence throughout the Middle Zone, marks the base of the UZ, and it is later joined by cumulus apatite, and then by alkali feldspar and zircon. Higher in the succession cumulus orthopyroxene, followed by olivine and Fe Ti oxide, eventually disappear. There is pronounced cryptic variation of the principal cumulus minerals (olivine Fo47−6, orthopyroxene En58−24, clinopyroxene Mg#63−6, plagio-clase An60−39 and the cumulus alkali feldspar is distinctly Ba-rich when it first appears. Comparison with the later fractionation stages of other layered intrusions shows broad similarities to the Bushveld and Skaergaard intrusions and closer similarities to the Fongen-Hyllingen body, which, like Insch, is a Caledonian synorogenic intrusion. The behaviour of the Insch pyroxenes, which show smoothly progressive Fe-enrichment despite their temporary absence as cumulus phases early in the UZ, together with the apparent range in cumulus plagioclase compositions in each sample, are taken to indicate that the cumulus mineral assemblages have been to some extent modified by re-equilibration with trapped inter-cumulus magma.
Evolution of the Miscibility Gap Between Muscovite and Biotite Solid Solutions with Increasing Lithium Content: An Experimental Study in the System K2O-Li2O-MgO-FeO-Al2O3-SiO2-H2O-HF at 600°C, 2 kbar PH2O: Comparison with Natural Lithium Micas
Authors: Monier Gilles , Robert Jean-Louis 
Published: December 2006

AbstractThis paper presents the results of an experimental study of the miscibility gap between trioctahedral and dioctahedral micas in the system K2O Li2O-MgO-FeO-Al2O3-SiO2-H2O-HF at 600°C under 2 kbar PH2O. The existence of this miscibility gap is known from previous experimental studies. The gap is large in the lithium-free system; its width reduces progressively with increasing Li content; for sufficient Li contents (Li > 0.6 atom per formula unit, based on 11 oxygens), a single Li-mica phase is obtained, intermediate between trioctahedral and dioctahedral micas. Any bulk composition located inside the miscibility gap gives an assemblage of two micas, one of the biotite-type and one of the muscovite-type. All the compositions located outside the gap, and, in particular, those belonging to the joins phlogopite-trilithionite and muscovite-zinnwaldite (or its magnesian equivalent) give a single mica phase, provided that the fluorine content is sufficient. The ratio Li/F ≈ 1 is a convenient suitable value. The types of micas and the evolutions of their compositions are well characterized by their interplanar distance d060. These experimental results allow the interpretation of most compositions of naturally occurring lithium micas, in the range 0 ⩽ Li ⩽ 1 a./f.u. Natural micas of biotite-type and muscovite-type are located on both sides of the miscibility gap and their compositions get closer with increasing Li content.
Babingtonite and Fe-rich Ca-A1 silicates from western Southland, New Zealand
Authors: Duggan M. B. 
Published: December 2006

AbstractBabingtonite is a common constituent of calcareous volcanic detritus in the interstices of pillow lavas from an outcrop of the Takitimu Group, western Southland, New Zealand, Associated minerals include Fe-rich prehnite (Fe/(Fe+Al) = 0.12–0.33), Fe-rich epidote (Ps24–53), grandite garnet (av. Andradite70 Grossular30), quartz, calcite, chlorite, and pumpellyite. Babingtonite shows little departure from its ideal composition other than minor Mg, Mn, and Al and a trace of Na.Textural evidence and microprobe data suggest that the babingtonite, Fe-rich epidote, calcite, and quartz formed from hydrothermal solutions by direct precipitation in open cavities and by replacement of higher temperature silicate phases (in particular plagioclase and basaltic glass) in a shallow marine volcanic environment. During subsequent burial and low-grade metamorphism babingtonite was partially replaced by prehnite, less Fe-rich epidote, grandite, and chlorite.
Johninnesite, a arsenosilicate from new sodium manganese the Kombat Mine, Namibia
Authors: Dunn Pete J. , Peacor Donald R. , Su Shu-Chun , Nelen Joseph A. , von Knorring Oleg 
Published: December 2006

AbstractJohninnesite, ideally Na2Mg4Mn12As5+2 Si12043(OH)6,, is triclinic, P1 or P1̄, with a = 10.44(2), b = 11.064(6), c = 9.62(1) Å, α = 107.43(7), β = 82.7(1), γ = 111.6(1)°, V = 894(2) Å3, and Z = 1. It occurs as yellow-brown fibrous aggregates, associated with rhodonite, kentrolite, and richterite, from the Kombat Mine in Namibia. Johninnesite has cleavages on {100} and {010}, density of 3.48 (meas.), 3.51 (calc.) g/cm3. It is biaxial negative, with 2Vx = 41.9°, α = 1.6742(4), β = 1.6968(3), γ = 1.6999(3); dispersion r > υ, distinct.
Benleonardite, a new mineral from the Bambolla mine, Moctezuma, Sonora, Mexico
Authors: Stanley C. J. , Criddle A. J. , Chisholm J. E. 
Published: December 2006

AbstractBenleonardite, ideally Ag8(Sb,As)Te2S3 with Sb > As, is a new mineral species that occurs in ore specimens collected from the dumps of the disused Bambolla mine, Moctezuma, Mexico. The associated minerals are acanthite, hessite, an unnamed Ag4TeS phase, pyrite, sphalerite, and native silver. Together with benleonardite, these form thin black crusts in fractures filled with quartz and dolomite in highly altered, tuffaceous, andesitic and rhyolitic rocks. Benleonardite is an opaque mineral and, in reflected plane-polarized light in air, it is weakly bireflectant from very pale light blue to slightly darker blue. It is not pleochroic. Luminance values (relative to the CIE illuminant C) for Ro and R′e computed from visible spectrum reflectance data for the most bireflectant grain, are 33.6 and 31.7% in air, and 18.3 and 16.5% in Zeiss oil (ND 1.515) respectively. Vickers micro-indentation hardness is 105–125 (VHN25). The X-ray powder diffraction pattern could be indexed on a tetragonal cell with a 6.603(5) and c 12.726(6) Å; for Z = 2, the calculated density is 7.79 g/cm2 for the average analysis. The strongest five lines in the X-ray powder pattern are [d in Å (I) (hkl): 12.7 (70) (001); 3.188 (30) (021,004); 2.936 (100) (022); 2.608 (35) (023); 2.158 (35) (124).
A computer simulation of the structure and elastic properties of MgSiO3 perovskite
Authors: Wall A. , Price G. D. , Parker S. C. 
Published: December 2006

AbstractThe structure and elastic properties of MgSiO3, a major mantle-forming phase, have been simulated using computer models which predict the minimum energy structure by using interatomic pair potentials to describe the net forces acting between the atoms. Four such interatomic potentials were developed in this study, and are compared with potential N1 of Miyamoto and Takeda (1984). The most successful potential (W3) was derived by fitting the short range potential parameters to both the experimentally obtained structural and elastic properties of MgSiO3 perovskite. The relative stabilities of some of the possible perovskite polymorphs, the orthorhombic, cubic, and tetragonal phases and hexagonal polytypes, were evaluated at 0 K and between 1 bar and 2 Mbar. The orthorhombic phase is found to be stable at all but the highest pressures, where the cubic phase may be stable. The temperature of the ortho-rhombic to cubic transition may decrease with increasing pressure. The energy of a stacking fault on (110) in the cubic phase was estimated using the ANNNI model and found to be about 1.95 J m−2 using potential W3. The distance of separation of partial dislocations of this type is predicted to increase with increasing pressure from 8.4 Å at 1 bar to 9.2 Å at 1 Mbar.