bluuebunny/crossref_metadata_2025_split huggingface dataset:
Cation and anion substitutions in the humite minerals
Authors: Ribbe P. H. , Gibbs G. V. , Jones Norris W. 
Published: December 2006

SummaryThe humites are structurally analogous to olivine wherein the replacement of four oxygen by four (F,OH) anions in the slightly distorted, hexagonal close-packed array is balanced by the replacement of one tetrahedrally coordinated Si by a tetrahedral void, according to the general formula Mg2xSix-1O4x-4(F,OH)4 where x = 3, 5, 7, 9. In humites the key structural units are not ‘olivine and sellaite (or brucite) layers’, as previously assumed, but are zigzag chains of edge-sharing octahedra, just as in olivines. It is shown that for humites and olivines alike the unit cell parameters a, b, and d001/n and the cell volume (normalized to one-half the mean anion-anion distance along the normal to (001)) vary linearly with the average radius of the octahedrally coordinated cation in the chain.Substitutions of (F,OH) for O and vacancies for Si have second-order effects on the unit cell parameters, causing a linear decrease of the normalized cell volume with increase in F/O ratio in the synthetic series forsterite-humite-norbergite. Comparison of the crystal structures of forsterite and norbergite shows that the polyhedral distortions in norbergite are smaller than in forsterite in accord with the decreased number of shared edges: the fluorines in norbergite are bonded to three Mg atoms whereas all anions in forsterite are bonded to three Mg and one Si atom.
On the origin of translation lamellae in olivine
Authors: Gibb Fergus G. F. 
Published: December 2006

SummaryTranslation lamellae in olivine crystals are generally considered to be a result of mechanical deformation of pre-existing crystals but a recent hypothesis suggests that they may be formed during the latter stages of olivine crystallization in olivine-rich rocks due to the stresses imposed by mutual interference. Olivine crystals showing well-developed translation lamellae occur in the ultrabasic dykes of south-west Skye and it is demonstrated that these lamellae are unlikely to have been formed by mutual interference. Possible origins of the lamellae are considered and it is concluded that they are most likely to have been formed by tectonic deformation at elevated temperatures prior to the intrusion of the dykes.
Kaersutite from San Carlos, Arizona, with comments on the paragenesis of this mineral
Authors: Mason Brian 
Published: December 2006

SummaryA 230 g kaersutite xenocryst from basalt at San Carlos, Arizona, has the composition SiO2 40·10 %, TiO2 4·44, Al2O3 14·53, Fe2O3 3·24, FeO 10·05, MnO 0·14, MgO 11·00, CaO 11·06, Na2O 2·99, K2O 1·62, H2O + 0·73, H2O − 0·10; D = 3·28; α 1·680, β 1·700, γ 1·715; a 9·858 Å, b 18·063 Å, c 5·315 Å, β 105° 14′. Kaersutite occurring as xenocrysts in basic volcanic rocks and tuffs, and as a phase in garnet-pyroxene xenoliths from such rocks, is probably of upper mantle origin, and may be the important potassium-bearing phase in this region.
Temperature control and calibration in quench furnaces and some new temperature measurements in the system CaO–MgO–Al2O3–SiO2
Authors: Biggar G. M. , O'Hara M. J. 
Published: December 2006

SummaryTechniques associated with temperature control and measurement in quench furnaces are described and a study made of calibration problems. Systematic temperature errors as great as 30°C in published results from separate laboratories are explicable. A comprehensive redetermination of temperatures of invariant equilibria in systems containing CaO, MgO, Al2O3, SiO2, Na2O, Fe-O2, has been initiated and the results to date are presented, including approximate determinations of three invariant equilibria in the system CaO-MgO-Al2O3-SiO2 involving liquid, monticellite, spinel, and two of merwinite, periclase, and forsterite, which are important in the melting of magnesia refractories, and precise determinations of the three newly recognized invariant equilibria involving liquid, spinel, diopside, and two of forsterite, melilite, and anorthite.
Axinites from the contact skarns of the Meldon aplite, Devonshire, England
Authors: Nawaz Chaudhry M. , Howie R. A. 
Published: December 2006

SummaryChemical analyses, optical properties, and specific gravities are presented for nine axinites. A reciprocal substitution relationship is demonstrated between Mg and Mn2+, and a linear variation diagram is constructed between refractive indices and the (Fe2++Fe3++Mn2++Ti) ions calculated on the basis of 16(O,OH). The composition of these axinites is independent of the composition of their host rocks; their colour appears to be independent of the Fe2+/Mn2+ ratio for the range of iron and manganese values of the specimens investigated.
Further detail on the crystal structure of zussmanite
Authors: Lopes-Vieira A. , Zussman J. 
Published: December 2006

SummaryMineral data and a brief outline of the structure for zussmanite (ideal formulaKFe13Si17AlO42(OH)14)have been published previously. This paper describes the determination of the crystal structure and presents and discusses the results. The structure consists of rhombohedrally stacked layers of Fe-(O,OH) octahedra to each side of which are attached rings of six (Si,Al)-O tetrahedra. These composite layers are linked to one another by rings of three (Si,Al)-O tetrahedra, and by potassium atoms, the latter in positions analogous to those in a mica. There is some evidence of disorder of the layer stacking. Interatomic distances and angles, and valency balance, are discussed.
The chemistry and cell parameters of omphacites and related pyroxenes
Authors: Edgar A. D. , Mottana A. , Macrae N. D. 
Published: December 2006

SummaryIn an attempt to correlate the chemical compositions and cell sizes of omphacites and related pyroxenes, the cell dimensions of fifty-five analysed pyroxenes have been determined, or taken from the literature. Twenty-two of the chemical analyses are new, nineteen of them being done by electron microprobe. Approximately two-thirds of the total number of analyses may be considered first class, the remainder are of doubtful or unknown quality. Cell parameters, determined by X-ray powder diffraction methods, have errors of 0·1 % for the majority of samples, although for some samples taken from the literature errors are unknown.The majority of methods of recalculating omphacite analyses into their end-member molecules are unsuitable for correlation of cell constants with chemistry, mainly due to the impossibility of graphical representation of more than three end-member molecules, and to the non-stoichiometry of these molecules. Using a modification of Tröger's (1962) method of recalculating chloromelanite analyses the present analyses have been recalculated into the diopside-jadeite-acmite and diopside-jadeite-hedenbergite molecules and compared with their determined cell parameters. Because of the gradations in all parameters between these end-member molecules, determination of compositions based on the cell parameters (a, b, c, vol, orβ) can only be made within wide limits. However, using a method of projection of compositions from the acmite and hedenbergite apices to the diopside-jadeite join the ratios of diopside to jadeite can be determined for most samples to within ±5 mol%. As there are the most important constituents of most omphacites, this method permits an approximate estimation of omphacite compositions. From a knowledge of the cell sizes of the omphacite a rough indication of the conditions of formation of its host rock may also be obtained.
Phase relationships in the join Ca(OH)2–CaCO3–Ca3(PO4)2–H2O at 1000 bars
Authors: Biggar G. M. 
Published: December 2006

SummaryPhase equilibria involving calcite, apatite, portlandite, liquid, and vapour were determined at 1000 bars. Calcite, apatite, and portlandite melt at 654 °C to form a liquid of composition (wt %), Ca(OH)2 53 %, CaCO3 46 %, Ca3(PO4)2 1 %. With water present melting occurs at 635 °C to form a similar liquid with a low water content. The X-ray diffraction patterns of the equilibrium apatites were not significantly different from synthetic hydroxyapatite.
Relations between cell dimensions, chemical composition, and site preference of orthopyroxene
Authors: Smith J. V. , Stephenson D. A. , Howie R. A. , Hey M. H. 
Published: December 2006

SummaryCell dimensions have been measured from correctly indexed powder patterns of thirty natural and two synthetic orthopyroxenes. The natural specimens (mostly metamorphic) contain exsolved phases largely avoided during microprobe chemical analysis. Linear regression analysis between the cell dimensions and Mg, Al, Ca contents (ignoring minor elements) was quite unsatisfactory until a term in Mg2 was added. Two separate regression analyses for the ranges Mg 0–0·5 and 0·5–1 using only Mg, Al, and Ca were satisfactory. Olivine yielded satisfactory regressions for the whole range without a term in Mg2 (Louisnathan and Smith, 1968). The difference between olivine and pyroxene results from absence of site preference by Mg and Fe in olivine compared to strong preference in pyroxene revealed by electron density and Mössbauer studies (Bancroft, Burns, and Howie, 1967; Ghose and Hafner, 1967).The data were recalculated by means of a new best-fit procedure developed by Hey in which the errors in the chemical and physical parameters are considered simultaneously.Earlier measurements of a and b for plutonic pyroxenes are consistent within possible experimental uncertainties with those given here; however a and b data obtained by Kuno and by Hess on volcanic specimens are considerably higher by variable amounts. Although there are uncertainties in the Ca content and its effect on a and b, the larger dimensions probably result from lower site preference as indicated by Mössbauer studies.Prediction of Mg, Ca, and Al from just the cell dimensions is only moderately accurate even for metamorphic orthopyroxenes.
Epitaxic relations between coexisting pyroxenes
Authors: Tarney J. 
Published: December 2006

SummaryMany examples of epitaxic relations between coexisting pyroxenes are found in the picritic dykes that cut the Lewisian gneisses of the Lochinver area, Sutherland. In some dykes augite forms oriented overgrowths on the (100) face of orthopyroxene; in others orthopyroxene forms similar overgrowths on augite. A number of unusual variants of the first case are described together with a complex ‘induced’ twinning found in the augite overgrowths. Analyses of the coexisting pyroxenes suggest that the overgrowth relation has been facilitated by increased solid solution between the pyroxenes, so reducing the crystallographic misfit along the c-axis. However, crystallization of the pyroxenes in an ordered sequence rather than simultaneously also seems to have been an important factor.
Tavistockite and bialite discredited
Authors: Embrey P. G. , Fejer E. E. 
Published: December 2006

SummarySpecimens of tavistockite fall into two groups: true tavistockite from the George and Charlotte mine, Tavistock, Devon, and wavellite from the Stenna Gwyn mine, St. Austell, Cornwall. Both were sold as tavistockite by the discoverer, Richard Talling.Tavistockite proper is a fluorapatite, as shown by optical and X-ray examination, and the alumina and water in the original analysis are certainly derived from kaolinite with which the apatite is intimately associated.The published optical properties attributed to tavistockite were determined by E. S. Larsen on Stenna Gwyn material, and are those of wavellite.Re-examination of a portion of Buttgenbach's type bialite, which he related to tavistockite on optical grounds, shows it to be wavellite.
Thermal investigations on alunite and its mixtures with quartz and dickite
Authors: Kashkai M.-A. , Babaev I. A. 
Published: December 2006

SummaryThe thermal decomposition of alunite and of mixtures of alunite with dickite or quartz or both has been studied, and X-ray determinations of the products at various stages of the decomposition have been made. Between 600 and 700°C the product from alunite is a mixture of anhydrous alum and amorphous alumina; between 700 and 770°C the anhydrous alum breaks down into aluminium sulphate and alkali sulphate; then in the prominent 850°C endothermic reaction three-quarters of the sulphate is lost, leaving a mixture of alkali sulphate and γ-alumina. The area of the 850 °C endothermic peak may be used as a measure of the percentage of alunite in alunitized rocks (alunite-quartz-dickite mixtures).
A high-temperature X-ray study of the equilibrium forms of albite
Authors: Grundy H. D. , Brown W. L. 
Published: December 2006

SummaryComplete lattice parameters have been determined at a series of temperatures up to 950 °C using a furnace on a powder diffractometer for six synthetic supposed equilibrium albites, a nonequilibrium albite, two natural albites, and a heat-treated natural albite. The supposed equilibrium albites were prepared hydrothermally by MacKenzie (1957) for long periods of time and reached or nearly reached a state of no further change at their temperatures of synthesis between 500 and 1000 °C. A crystal of natural albite and three crystals of heat-treated natural albite were studied by high-temperature, single-crystal methods on a Buerger precession camera up to 1000 °C for comparison.The lattice angles for each albite decrease smoothly with increasing temperature; the a-axis and the volume increase smoothly with increasing temperature. The rates of change increase with increasing temperature. The c and in some cases the b-axes appear to decrease initially in the range 25–300 °C and then subsequently increase. The thermal dilatation is highly anisotropic—the change in a is about twice that in b and about six times that in c over the whole range 25–850 °C. The effect of a temperature rise on the lattice parameters of the albites is very similar to the effect of the substitution of potassium on the room-temperature parameters.Plots of α* against γ* for each albite at a sequence of temperatures up to 950 °C fall on nearly straight parallel lines, all albites becoming less oblique (triclinic) with increasing temperature. Of the equilibrium albites, only the one synthesized at 1000°C becomes monoclinic below the melting point. The ratio d010/d001 or c*/b* is a measure of order in the albites and does not vary with temperature. The similar behaviours of this ratio and of other lattice parameters as a function of the temperature of synthesis confirms the two-step ordering process in albite.
A comparison of gel and glass starting materials for phase equilibrium studies
Authors: Biggar G. M. , O'Hara M. J. 
Published: December 2006

SummaryA method of preparing compositions suitable for phase equilibrium studies in systems containing CaO-MgO-Al2O3-SiO2-Fe-O2-Na2O employing a gelling technique is described. The subsolidus assemblages obtained from the recrystallization of some of these gels and from the recrystallization of devitrified glasses of the same composition are compared. It is not yet clear whether either starting material has any advantage as the gels may retain early formed metastable phases and the glasses may fail to nucleate stable phases.
Relationships among 2:1 layer silicates
Authors: Whittaker E. J. W. 
Published: December 2006

SummaryThe relationships between the 2:1 layer silicates are discussed in terms of the charge balance between the ions occupying X, Y, and Z sites. This brings out the relationship of glauconite to the illites, and clarifies the reason for the ideal occupancy of the Y sites in montmorillonite. It not only shows hectorite, saponite, and sauconite to be tri-octahedral smectites, but also shows vermiculite to be a tri-octahedral analogue of the illites. Apparently anomalous differences in permitted compositions of the di-octahedral and tri-octahedral micas are explained in terms of mismatch between the tetrahedral and octahedral layers, and it is shown that ephesite is to be regarded as a tri-octahedral common mica, not an analogue of margarite. Anandite is the nearest known naturally occurring equivalent to a tri-octahedral analogue of margarite, but the true analogue is a barium magnesium mica synthesized by Frondel and Ito.
Physical properties of synthetic and natural pyroxenes in the system diopside–hedenbergite–acmite
Authors: Nolan J. 
Published: December 2006

SummaryUnit cell dimensions and refractive indices have been determined for synthetic pyroxenes in the system CaMgSi2O6-CaFeSi2O6-NaFeSi2O6, which have been crystallized and annealed on the nickel-bunsenite (Ni-NiO) oxygen buffer curve at 700 °C and a total pressure of 2 kb. The data presented confirms the many postulates that a complete solid solution series does exist in the subsolidus region of the ‘ternary’ system. The unit cell dimensions show an almost linear change with composition between the end members. The determined cell parameters for a series of analysed natural alkali pyroxenes have been compared with the data for the synthetic pyroxenes and close agreement was found between both sets of data. The variation of the unit cell dimensions and refractive indices has been examined in relation to the possible ionic substitutions taking place in the pyroxenes.
Olivine recrystallization textures
Authors: Ragan Donal M. 
Published: December 2006

SummaryMosaic olivine textures, with straight triple grain boundaries meeting at angles of 120°, are common in dunites. This is a well-known feature of annealed metals, and is the result of grain-boundary migration during recrystallization in which the system tends toward a state of minimum interfacial energies. Geometrically similar textures are present at the boundaries between such mosaic grains and strain-banded relict olivine grains. The unstrained mosaic grains make angular projections into the strained grains exactly at the junctions between the deformation bands. These are interpreted to be triple junctions with the two differently oriented bands acting as separate grains, and thus also due to recrystallization.
An X-ray investigation of the thermal decomposition of portlandite
Authors: Brett N. H. 
Published: December 2006

SummaryThe thermal decomposition of portlandite, Ca(OH)2, has been studied in air and in vacuum using X-ray single-crystal techniques. In air, the crystals were decomposed in situ on the goniometer arcs whilst X-ray reflections were simultaneously recorded. The transformation to CaO was not accompanied by topotaxy; this is attributed to the high nucleation rate of CaO crystallites in air. When Ca(OH)2 single crystals were decomposed under vacuum (and subsequently exposed to X-rays), some orientation of the CaO crystallites occurred. These results are compared with those of previous workers using electron-diffraction techniques. Decomposition of Ca(OH)2 single crystals commences at ∼ 450 °C in air and at ∼ 230 °C in a vacuum of 10−6 mmHg; reaction commences at crystal edges and surface defects, the reaction boundary moving inwards to the centre of the crystal. This observation is consistent with a homogeneous mechanism of decomposition.
On the oriented transformation of Ca(OH)2 to CaO
Authors: Datta N. , Chatterji S. , Jeffery J. W. , Mackay A. L. 
Published: December 2006

SummaryThe conversion of Ca(OH)2 to CaO has been studied by X-ray diffraction techniques. When Ca(OH)2 crystals are heated in vacuo the conversion is oriented, but not when they are heated at atmospheric pressure. This difference is attributed to the lowering of the decomposition temperature in vacuo and consequent lower thermal vibration.
Quantitative determination of water in granites by infra-red analysis
Authors: Aucott J. W. , Marshall M. 
Published: December 2006

SummaryTwo methods using nujol and hexachloro-butadiene mulls are described to analyse the water content of powdered granite samples. The nujol mull analyses were carried out on a Unicam SP 100 spectrometer using the silica content of the rock as an internal standard. The hexachlorobutadiene mull analyses were done by a twin-path Unicam SP 200 spectrometer, using hexachlorobutadiene as the internal standard. The broader and more pronounced V1 vibrational mode (3450 cm−1) is ratioed to a standard of known composition. Comparisons are also made between absorption due to free water (V1 = 3450 cm−1) and combined water (V3 = 3680 cm−1) in aplites, biotite granite, and chlorite schists.
The application of scanning electron beam anomalous transmission patterns in mineralogy
Authors: Jones M. P. , Gavrilovic J. 
Published: December 2006

SummaryIt is possible with a standard Geoscan microanalyser to produce back-scattered electron pictures that resemble Kikuchi patterns but which are produced by a different mechanism. These effects have been called scanning electron beam anomalous transmission (SEBAT) patterns and they are produced by the interaction of a parallel scanning beam of high-energy electrons with a crystalline sample. The patterns are excellent indicators of the crystallographic perfection and orientation of samples and can provide information about the lattice dimensions of solid, bulk specimens. The same specimens can, if necessary, be chemically analysed in the same instrument.In order to produce the patterns the electron beam must be deflected through a minimum angle of approximately 20° and, on existing instruments, the beam covers an area of about 2 × 2 mm during such a deflection. Minor modification of the authors' microanalyser has reduced the scanned area to 0·5 × 0·5 mm and attempts are being made to reduce this even further.In favourable circumstances the technique enables the mineralogist to determine, rapidly and easily, the crystallographic structure and orientation of large, bulk specimens. Examples are given of patterns that have been produced from cleaved, as grown, and polished mineral faces. The degree and nature of the crystallographic damage produced during mechanical polishing of a galena crystal are illustrated.
A metallographic and microprobe study of the Brenham pallasite
Authors: Axon H. J. , Yardley E. D. 
Published: December 2006

SummaryA metallographic study has been made of the macroscopic and microscopic features of the Brenham pallasite. The microprobe has been used to investigate the condition of kamacite inter-faces with second kamacite grains, olivine, schreibersite, troilite, and taenite and of taenite interfaces with olivine. The results indicate that grain-boundary migration of nickel may be important in these structures.
Comments on ‘Kaersutite from San Carlos, Arizona, with comments on the paragenesis of this mineral’ by Brian Mason
Authors: Prinz Martin , Nehru C. E. 
Published: December 2006

SummaryElectron probe analyses have been made of eight kaersutites from San Carlos, Arizona, and one from Kakanui, New Zealand; also of olivine, clinopyroxene, ilmenite, and spinel from San Carlos. There is not as yet adequate evidence that the kaersutite is an upper mantle phase.
Segregation and cation-ordering in sjögrenite and pyroaurite
Authors: Taylor H. F. W. 
Published: December 2006

SummaryA specimen from Långban, Sweden, was found to consist largely of sjögrenite in which segregation and ordering of the metal cations had occurred, yielding an intergrowth of regions of two main types with compositions probably of or near Mg2/3Fe1/3(OH)2(CO3)1/6(H2O)0·4 and Mg12/13Fe1/13(OH)2(CO3)1/26(H2O)0·8. To a smaller extent segregation had proceeded further, giving regions probably approximating to the end-member Mg(OH)2.H2O. It is suggested that the names sjögrenite and pyroaurite be used for the 2H- and 3R- polytypes of this structure irrespective of Mg:Fe ratio, segregation, or cation ordering.
Electron microprobe analyses of chlorine in hornblendes and biotites from the charnockitic rocks of Kondapalli, India
Authors: Leelanandam C. 
Published: December 2006

SummaryChlorine is estimated in nine hornblendes (0·13–1·12%) and nine biotites (0·19–0·62%) from the Kondapalli charnockites for the first time, using the electron microprobe. The data obtained suggest that these Kondapalli minerals are unexpectedly and unusually rich in Cl, which is well equilibrated in the five available coexisting hornblende-biotite pairs.