bluuebunny/crossref_metadata_2025_split huggingface dataset:
Optimizing mechanical performance in 3D printing through a benzoxazine monomer blend photosensitive resin formulation
Authors: Khankhuean Anchan , Sukthavorn Kankavee , Nootsuwan Nollapan , Veranitisagul Chatchai , Laobuthee Apirat 
Published: March 2024

AbstractThe objective of this study was to enhance the mechanical properties of 3D printed specimens in commercial photosensitive resin (PS‐resin) through blend‐thermosets using a benzoxazine monomer based on bisphenol A and a commercially available resin. Specifically, a benzoxazine‐based bisphenol A compound, 6,6‐(propane‐2,2‐diyl)bis(3‐cyclohexyl‐3,4‐dihydro‐2H‐benzo[e][1,3]oxazine), was successfully synthesized via the Mannich reaction. The synthesis involved paraformaldehyde, bisphenol A, and cyclohexylamine in a molar ratio of 4:1:2, respectively. To prepare the blend‐thermosets, a stereolithography 3D printer (SLA) was utilized, combining the PS‐resin with varying amounts of the benzoxazine (ranging from 0 to 8 parts per hundred of resin, phr). The printed specimens were then subjected to a polymerization process by heating them at various temperatures ranging from 120 to 160°C in a hot air oven for 2 h, allowing the benzoxazine to undergo ring‐opening reaction and form the thermoset structure. Characterization of all the materials obtained, including the PS‐resin, benzoxazine, and the blend‐thermosets before and after heating, was conducted using techniques such as FT‐IR and DSC. This work also showcased a sample technique for verifying the ring‐opening of the benzoxazine ring. Additionally, the mechanical properties of the blend‐thermosets were evaluated through tests for tensile strength, elongation at break, modulus, and hardness. The addition of merely 2 phr of benzoxazine monomers and subsequent curing at 120°C resulted in a notable improvement in the mechanical properties.
An intrinsic antistatic polyethylene glycol‐based solid–solid phase change material for thermal energy storage and thermal management
Authors: Wu Sha , Zhang Yumeng , Deng Mingyue , Liang Guangming , Ju Haiyan , Xiao Yao 
Published: March 2024

AbstractPolyethylene glycol (PEG) is an important and popular phase change material (PCM), but is not a good antistatic material, which would cause the accumulation of static electricity and electrostatic discharge when used for the thermal energy storage and thermal management of electrical devices. Herein, we prepared a PEG‐based solid–solid PCM (SSPCM) with good antistatic property by introducing an ionic liquid onto the macromolecular chains. This SSPCM is in solid state even at 90°C, avoiding the leakage issue of pure PEG. Its latent heat values in the melting and solidifying processes are 56.2 and 30.6 J g−1, respectively. Additionally, this SSPCM has good thermal stability and thermal reliability for thermal storage and thermal management according to thermogravimetric and thermal cycling tests. The volume‐ and surface resistivity of the SSPCM at ambient temperature are 108.87 Ω m and 108.92 Ω, respectively, showing good antistatic performance.
Neural basis underlying the association between thought control ability and happiness: The moderating role of the amygdala
Authors: Li Min , Yan Yuchi , Jia Hui , Gao Yixin , Qiu Jiang , Yang Wenjing 
Published: March 2024

AbstractThought control ability (TCA) plays an important role in individuals' health and happiness. Previous studies demonstrated that TCA was closely conceptually associated with happiness. However, empirical research supporting this relationship was limited. In addition, the neural basis underlying TCA and how this neural basis influences the relationship between TCA and happiness remain unexplored. In the present study, the voxel‐based morphometry (VBM) method was adopted to investigate the neuroanatomical basis of TCA in 314 healthy subjects. The behavioral results revealed a significant positive association between TCA and happiness. On the neural level, there was a significant negative correlation between TCA and the gray matter density (GMD) of the bilateral amygdala. Split‐half validation analysis revealed similar results, further confirming the stability of the VBM analysis findings. Furthermore, gray matter covariance network and graph theoretical analyses showed positive association between TCA and both the node degree and node strength of the amygdala. Moderation analysis revealed that the GMD of the amygdala moderated the relationship between TCA and happiness. Specifically, the positive association between TCA and self‐perceived happiness was stronger in subjects with a lower GMD of the amygdala. The present study indicated the neural basis underlying the association between TCA and happiness and offered a method of improving individual well‐being.
Cognitive bias modification for perfectionism and intolerance of uncertainty: A randomized controlled trial
Authors: Tör‐Çabuk Kübra , Koç Volkan 
Published: March 2024

AbstractThis study investigated the efficacy of combined cognitive bias modification (CBM) on perfectionism and intolerance of uncertainty. Fifty‐four university students scoring over 70.5 on the Brief Symptom Measure were randomly assigned to experimental and placebo control groups. The CBM intervention was administered online for 4 weeks. Assessments were given at baseline, after the 4‐week intervention, and 1 month post‐intervention. Results showed a statistically significant decrease in two dimensions of perfectionism, concern over mistakes and parental criticism, and intolerance of uncertainty of those in the experimental group, compared to those in the control group. The findings related to the interpretation of perfectionism revealed a significant interaction effect of time and direction of sentences for the experimental group. Lastly, the experimental group's interpretation bias scores for intolerance of uncertainty showed a statistically significant increase after the intervention compared to those in the control group. The study's findings provide preliminary support for the effectiveness of CBM on perfectionism and intolerance of uncertainty.
Novel photoresponsive molecularly imprinted polymers based on etched silicon core with enabling enhanced selectivity and sensitivity for the detection of sulfamethazine
Authors: Peng Wangui , Huang Weihong , Gao Minmin , Yang Wenming , Xu Wanzhen 
Published: March 2024

AbstractSulfamethymidine, a commonly employed sulfonamide, is introduced into the human body through the food chain, posing a threat to human health. Consequently, the development of a rapid and efficient detection technique is imperative. In this investigation, a photoresponsive sulfamethyridiazine‐imprinted polymer was synthesized to etch a silicon core, thereby effectively addressing the limitations encountered with conventional molecularly imprinted polymers including diminished binding capacity, restricted site accessibility and sluggish binding kinetics. The photosensitive monomer utilized in the molecularly imprinted polymers is 5[(4 (methylacryloxy) phenyl) diazene] isophthalic acid, which exhibits a stimulating reaction mechanism. The N=N bond undergoes photoisomerization, transitioning between trans and cis configurations. The adsorption experiment provides additional evidence that the hollow molecularly imprinted polymers exhibit a higher adsorption capacity, achieving a value of 0.192 mmol L−1. The experiments conducted to assess selectivity and repeatability confirm that the photoresponsive molecularly imprinted polymers exhibit a high level of selectivity and favorable repeatability. Following four cycles, the adsorption rate remains consistently at 64.3%. Additionally, the recoveries of the actual samples ranged from 95.6% to 99.7%. This finding presents a novel approach to detecting the concentration of trace pollutants in intricate substrates. © 2024 Society of Industrial Chemistry.
Defining the challenges and opportunities for using patient‐derived models in prostate cancer research
Authors: Brennen W. Nathaniel , Le Magnen Clémentine , Karkampouna Sofia , Anselmino Nicolas , Bock Nathalie , Choo Nicholas , Clark Ashlee K. , Coleman Ilsa M. , Dolgos Robin , Ferguson Alison M. , Goode David L. , Krutihof‐de Julio Marianna , Navone Nora M. , Nelson Peter S. , O'Neill Edward , Porter Laura H. , Ranasinghe Weranja , Sunada Takuro , Williams Elizabeth D. , Butler Lisa M. , Corey Eva , van Weerden Wytske M. , Taylor Renea A. , Risbridger Gail P. , Lawrence Mitchell G. 
Published: March 2024

AbstractBackgroundThere are relatively few widely used models of prostate cancer compared to other common malignancies. This impedes translational prostate cancer research because the range of models does not reflect the diversity of disease seen in clinical practice. In response to this challenge, research laboratories around the world have been developing new patient‐derived models of prostate cancer, including xenografts, organoids, and tumor explants.MethodsIn May 2023, we held a workshop at the Monash University Prato Campus for researchers with expertise in establishing and using a variety of patient‐derived models of prostate cancer. This review summarizes our collective ideas on how patient‐derived models are currently being used, the common challenges, and future opportunities for maximizing their usefulness in prostate cancer research.ResultsAn increasing number of patient‐derived models for prostate cancer are being developed. Despite their individual limitations and varying success rates, these models are valuable resources for exploring new concepts in prostate cancer biology and for preclinical testing of potential treatments. Here we focus on the need for larger collections of models that represent the changing treatment landscape of prostate cancer, robust readouts for preclinical testing, improved in vitro culture conditions, and integration of the tumor microenvironment. Additional priorities include ensuring model reproducibility, standardization, and replication, and streamlining the exchange of models and data sets among research groups.ConclusionsThere are several opportunities to maximize the impact of patient‐derived models on prostate cancer research. We must develop large, diverse and accessible cohorts of models and more sophisticated methods for emulating the intricacy of patient tumors. In this way, we can use the samples that are generously donated by patients to advance the outcomes of patients in the future.
Adherence to newer second‐line oral antidiabetic drugs among people with type 2 diabetes—A systematic review
Authors: Holdt‐Caspersen Nynne Sophie , Dethlefsen Claus , Vestergaard Peter , Hejlesen Ole , Hangaard Stine , Jensen Morten Hasselstrøm 
Published: March 2024

AbstractThe adherence to oral antidiabetic drugs (OADs) among people with type 2 diabetes (T2D) is suboptimal. However, new OADs have been marketed within the last 10 years. As these new drugs differ in mechanism of action, treatment complexity, and side effects, they may influence adherence. Thus, the aim of this study was to assess the adherence to newer second‐line OADs, defined as drugs marketed in 2012–2022, among people with T2D. A systematic review was performed in CINAHL, Cochrane Trials, Embase, PubMed, PsycINFO, and Scopus. Articles were included if they were original research of adherence to newer second‐line OADs and reported objective adherence quantification. The quality of the articles was assessed using JBI's critical appraisal tools. The overall findings were reported according to the preferred reporting items for systematic reviews and meta‐analyses (PRISMA) guidelines and summarized in a narrative synthesis. All seven included articles were European retrospective cohort studies investigating alogliptin, canagliflozin, dapagliflozin, empagliflozin, and unspecified types of SGLT2i. Treatment discontinuation and medication possession ratio (MPR) were the most frequently reported adherence quantification measures. Within the first 12 months of treatment, 29%–44% of subjects on SGLT2i discontinued the treatment. In terms of MPR, 61.7%–94.9% of subjects on either alogliptin, canagliflozin, dapagliflozin, empagliflozin or an unspecified SGLT2i were adherent. The two investigated adherence quantification measures, treatment discontinuation and MPR, suggest that adherence to the newer second‐line OADs may be better than that of older OADs. However, a study directly comparing older and newer OADs should be done to verify this.
Sources of MJO teleconnection errors in the ECMWF extended‐range forecasts
Authors: Vitart Frédéric , Balmaseda Magdalena A. 
Published: March 2024

AbstractThe European Centre for Medium‐range Weather Forecasts (ECMWF) extended‐range forecasts display large errors in the representations of Madden–Julian Oscillation (MJO) teleconnections over the North Atlantic with a strong underestimation of the impact of the MJO on the North Atlantic Oscillation (NAO) following an MJO in Phase 2–3. The origin of this error was investigated using a large set of re‐forecasts covering 20 years where part of the atmosphere was relaxed towards the ECMWF Reanalysis v5 (ERA5) reanalysis. These relaxation experiments show that relaxing the Tropics significantly improves the MJO teleconnections associated with Phase 2–3, with a reduction of about 50% in the amplitude error of the teleconnections. However, model errors outside the Tropics also play an important role. Results also suggest that errors in local processes reduce by about 20% the amplitude of the MJO teleconnections over the North Atlantic. Another example of a source of MJO teleconnection errors is the near surface over the Tibetan and Mongolian Plateaux. Nudging this area towards ERA5 improves the representation of the Pacific subtropical jet and the amplitude of MJO teleconnections associated with Phase 2–3 in the extended‐range re‐forecasts. Nudging the stratosphere exerts a comparatively weaker impact on the MJO teleconnections 11–15 days after an MJO in Phase 2–3. Overall, these experiments indicate that there are multiple sources of MJO teleconnection errors, making the representation of realistic MJO teleconnection by dynamical models a particularly challenging task.
Familial pulmonary cysts: A clue to diagnose Birt–Hogg–Dubé syndrome: A case report and literature review
Authors: Miao Jinrui , Gao Qian , Wang Zilin , Hou Gang 
Published: March 2024

AbstractBirt–Hogg–Dubé syndrome (BHD) is an inherited autosomal dominant condition caused by germline mutations in the FLCN gene, mapped to chromosome 17p11.2. Typical manifestations include pulmonary cysts, spontaneous pneumothorax, fibrofolliculomas, and kidney neoplasms. This report details the case of a 56‐year‐old female non‐smoker diagnosed with multiple pulmonary cysts, presenting with a history of recurrent spontaneous pneumothorax. A computed tomography (CT) scan of her daughter revealed similar pulmonary cysts, raising suspicion of BHD. Further abdominal enhanced CT revealed a left renal tumour and cutaneous fibrofolliculomas on her daughter's neck. Consequently, whole‐exome sequencing confirmed an FLCN germline mutation in the patient and three relatives, establishing a diagnosis of BHD. This case highlights the importance of familial pulmonary cysts as a clue for diagnosing BHD, providing crucial insights into comparable clinical presentations.
An adaptive observer based output feedback prescribed‐time control of a class of nonlinear systems with unknown parameters
Authors: Wang Yihao , Jiang Huaiyuan , Zhang Kang‐Kang 
Published: March 2024

SummaryIn this paper, an adaptive observer based output feedback prescribed‐time control is designed for a class of nonlinear systems with unknown parameters. According to the characteristics of the nonlinear systems, a novel adaptive observer is first designed. Then by imposing parametric Lyapunov equations, a time‐varying high‐gain observer based output feedback adaptive controller is constructed, by which, it is proven that the states of both the observer and the original system can be driven to zero within any prescribed time. Moreover, the control signal is proven uniformly bounded by a scalar. Two numerical examples are illustrated to verify the effectiveness of the proposed method.
Green synthesis of ZnFe2O4@BC nanocrystals using pomelo peel waste for photo‐Fenton degradation of dye under visible light
Authors: Zheng Yanping , Fan Jinhu , Cui Jingfeng , Yang Baoping 
Published: March 2024

AbstractIn this study, an economical ZnFe2O4@BC composite was successfully synthesized using pomelo peel biochar through a simple one‐pot thermal‐calcination roasting method. The combination of biochar and ZnFe2O4 was confirmed by FTIR, XRD, Raman, TEM, and XPS analysis, confirming that the successful insertion of carbon into the oxygen sites of the ZnFe2O4 lattice, forming C−O bonds. The incorporation of biochar resulted in a high specific surface area, providing more active sites for catalytic reactions, enhancing electron transport, effectively separating electron‐hole pairs, increasing light capturing capacity, and restraining the leaching of metals. The Zn vacancy acted as an electron acceptor, promoting electron transfer in the catalyst by reducing the lowest unoccupied orbital position. Additionally, various reaction parameters such as solution pH, iron content, catalyst dosage, and H2O2 volume were investigated to elucidate their effects on the degradation performance. This study proposes a novel method for synthesizing carbon‐coated metal oxide semiconductors, which shows great potential for environmental and energy‐related applications.
Study on the Reliability and Stability of Fatty Acid‐Paraffin Ternary Phase Change Materials as Energy‐saving Materials
Authors: Shi Yu , Zhao Yunchao , Zhang Yanmei , Fan Zhixuan , Jiang Dahua 
Published: March 2024

AbstractPCMs are an ideal energy storage material, widely used in construction and have gradually become a hot spot for research. To address the shortcomings and deficiencies of single PCM, this paper combined myristic acid (MA), palmitic acid (PA) and paraffin slice (48#, PS) to prepare a ternary system of PCM by using a melt blending method. The study found that the lowest eutectic point is reached when MA : PA : PS=43.4 : 18.6 : 38, with phase change temperature and enthalpy of phase change of 39.28 °C and 135.83 J/g, respectively, showing better superiority. Moreover, FT‐IR and XRD also indicated that no new functional groups appeared in this ternary PCM, no new substances were produced, and all were simple physical bonding. TG showed that MA‐PA‐PS does not decompose below 127.95 °C and has good thermal stability. Finally, it was indicated that its thermal reliability is good after 500 thermal cycles of MA‐PA‐PS. Therefore, as a new type of energy‐saving material, this ternary PCM has good reliability and superiority, and has good application prospects.
Thermoresponsive Behavior of Binary Waxes
Authors: Sisman Orhan , Sajzew Roman , Walden Sarah L. , Wondraczek Katrin , Galusek Dusan , Wondraczek Lothar 
Published: March 2024

AbstractIn this study, we investigated the thermoresponsive behavior of two different binary wax compositions of commercially available natural candles. The chemical nature of carbon bonds in the fatty acid chains of the natural wax component effectuate a different hygroscopic behavior, as confirmed by NMR analysis. The phase transitions of polymorphic stearin‐rapeseed and stearin‐coconut wax composites were tracked by DSC‐TGA and VT‐XRD. The reduction in the eutectic temperatures of wax composites during the second heating cycles of DSC measurements was correlated with the length of fatty acid chains in rapeseed and coconut waxes, as well as their co‐crystallization kinetics with stearin. Mechanical and hygroscopic behavior of the binary waxes were examined at elevated temperatures between 23 °C and 45 °C using QCM‐D. Voigt viscoelastic model was employed to reveal the soft and rigid textures of wax composites. The hydrophilic behavior of the rapeseed wax composite changed to hydrophobic when the co‐crystallized and individual stearin melted above 35 °C. Activation energies required for melting wax crystals were calculated to be 51±3 kJ mol−1 for pure rapeseed wax, 373 kJ mol−1 for co‐crystallized rapeseed and stearin waxes, and 244 kJ mol−1 for co‐crystallized coconut and stearin waxes, using Arrhenius method with the QCM‐D data.
Synthesis and Characterization of Spirooxindole β‐Ketothiolester and their Fluorescence Imaging on PC3 Cells
Authors: Sriram Babu Seenivasagaperumal , Savitha Devi Natarajan , Manjula Devi Ramamoorthy , Dhiraviam Kannan Narayanan , Sivakumar Shanmugam 
Published: March 2024

AbstractBiologically‐active near‐ultraviolet emitting spirooxindole‐pyrrolidine/pyrrolothiazole‐β‐ketothiolester have been synthesised via Chemo‐/regio‐/stereoselective manner. Excited‐state intramolecular proton transfer (ESIPT) of β‐ketothiolester exhibits excitation‐dependent emission with intermolecular hydrogen bonding ability with solvents. The emission could be tunable between 330 nm to 460 nm. Selected fluorescent compounds 4{4,2,1}, 4{12,2,2}, 5{4,2,1} and 5{12,2,2} shows cytotoxicity effect on PC3 cells, where the highest IC50 value (6 μM) was found for the probe 5{12,2,2}. The fluorescent behavior of 5{4,2,1} and 5{12,2,2} acted as an imaging molecule against cancer cells.
Construction of Petal‐Like CoO/CoP Heterostructures by Oxygen Vacancy Induced P‐doping for Efficient Overall Water Splitting
Authors: Ma Shihang , Zhu Wenchang , Feng Hongbin 
Published: March 2024

AbstractHydrogen energy has become a green, high‐efficiency new energy source due to its superior characteristics. Overall water splitting is considered as an effective method for hydrogen production. However, the synthesis of non‐noble metal‐based robust bi‐functional electrocatalysts for both oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) are still challenging. Here, the synthesis of petal‐like CoO/CoP heterostructures is reported by an oxygen vacancy induced P‐doping strategy. The oxygen defect sites of the defective Co3O4–x easily attract phosphorus atoms to enhance the P‐doping process, which induces the formation of a two‐dimensional CoO/CoP heterojunction structure. Due to the synergistic effect between CoP and CoO phases in the catalyst, the heterostructures can well drive the hydrogen and oxygen evolution reactions under alkaline conditions, and thus substantially promotes overall water splitting with a relatively low potential 1.64 V at 10 mA cm−2 without decay even after the durability test for 24 h.
Development of Silica‐Immobilized Material as Heterogeneous Hydrogen Bond Donor (HBD) Catalyst: Synthesis of Cyclic Carbonates from CO2 and Epoxides
Authors: Roy Shilpa , Das Koushik , Santra Sougata , Zyryanov Grigory V. , Halder Sandipan 
Published: March 2024

AbstractComposite silica materials have been developed by hydrothermal method and utilized as heterogeneous Hydrogen Bond Donor (HBD) catalysts, where the functionalized ketimine derivatives have been immobilized on the solid support. Such functional materials have been found to be efficient catalysts for the synthesis of cyclic carbonates through the installation of CO2 with epoxides. Characterization of these materials was systematically done using various spectroscopic and imaging techniques to confirm the presence of organic compounds on the silica surface. These composite materials exhibited significantly higher catalytic activity as compared to the other homogeneous methods. Additionally, this synthetic process was extremely convenient in terms of all the external parameters such as, solvent free condition at ambient reaction temperature with normal pressure of CO2, very low catalyst loading with proper regeneration and reusability of the catalyst. These facets have definitely made this technique greener and more sustainable.