bluuebunny/crossref_metadata_2025_split huggingface dataset:
Investigation of microstructural, micromorphology, and surface plasmon resonance characteristics in Ni/Al, Ni/Cu, and Ni/SS thin films
Authors: Mohammadi Saeedeh , Rezaee Sahar , Nia Borhan Arghavani , Boochani Arash , Ţălu Ştefan 
Published: April 2024

AbstractAs the first boundary between the environment and the material, the surface plays an important role in their interaction with each other, therefore, the use of appropriate tools and analysis to examine the mechanical properties and morphology of surfaces has particular importance in industry and research. In this research, a thin film of nickel was deposited on metal substrates made of aluminum, copper, and steel by using the RF magnetic cathode. Then, using a non‐contact atomic force microscope, the morphological properties of the nickel film with static parameters, Minkowski functionals (MF's), fractal, and multifractal were extracted to be analyzed and studied. After that, using parameters such as root mean square (RMS) roughness, skewness, and kurtosis, it was determined how the surface roughness, distribution, and probability density of particles on the film surface alters with the change of the substrate. Next, by examining and analyzing the Δα and Δf parameters obtained from the multifractal section, the morphology of the produced film on the metal substrates was investigated. Then, the change in the surface plasmon resonance (SPR) peak position is changed for the prepared film in the range of the absorption spectrum due to the substrate effect and the microstructural properties of the formed film.Highlights
Ni film has been deposited by Rf magnetron sputtering.
The effect of metal substrates on the topography, fractality, and optical properties was studied.
Minkowski functionals were used to investigate the surface morphology of the samples.
Substrate's material and the topography of the formed film can changed the surface plasmon resonance position.
Prevalence and genetic diversity of human rhinovirus among patients with acute respiratory infections in China, 2012−2021
Authors: Cui Aili , Xia Baicheng , Jiang Haoran , Li Qi , Sun Liwei , Xu Jin , Hu Kongxin , Xie Zhibo , Wang Yage , Zhu Runan , Huang Chaoyang , Li Zhong , Xu Jing , Wang Wenyang , Zhang Hui , Gao Zhenguo , Zhang Feng , Xie Hui , Zhang Yan 
Published: April 2024

AbstractTo understand the prevalence of rhinovirus (RV) among acute respiratory infection (ARI) patients, 10‐year ARI surveillance in multiple provinces of China were conducted during 2012−2021. Of 15 645 ARI patients, 1180 (7.54%) were confirmed to have RV infection and 820 (69.49%) were children under 5 years of age. RV typing was performed on the 527 VP1 gene sequences, and species A, B, and C accounted for 73.24%, 4.93%, and 21.82%, respectively. Although no significant difference in the proportions of age groups or disease severity was found between RV species, RV‐C was more frequently detected in children under 5 years of age, RV‐A was more frequently detected in elderly individuals (≥60), and the proportions of pneumonia in RV‐A and RV‐C patients were higher than those in RV‐B patients. The epidemic peak of RV‐A was earlier than that of RV‐C. A total of 57 types of RV‐A, 13 types of RV‐B, and 35 types of RV‐C were identified in RV‐infected patients, and two uncertain RV types were also detected. The findings showed a few differences in epidemiological and clinical features between RV species in ARI patients, and RV‐A and RV‐C were more prevalent than RV‐B.
How extreme hydrological events correspond to climate extremes in the context of global warming: A case study in the Luanhe River Basin of North China
Authors: Gao Ge , Li Jianzhu , Feng Ping , Liu Jia , Wang Yicheng 
Published: April 2024

AbstractThe consensus on climate warming is well‐established, and extreme values inherently encapsulate more information than averages. Against the backdrop of frequent extreme climate events, studying extreme values holds profound significance. This study aims to reveal the characteristics of extreme climate events and their role in triggering extreme hydrological events in the typical North China basin, that is, the Luanhe River Basin. Trends of 25 extreme climate indices during 1960–2018 are analysed using the Sen's slope and MK significance test to study the changing characteristics of extreme climate. Characteristics of extreme flood and dry events are examined, encompassing trend analyses at different time scales (seasonal, interannual, decadal) and concentration analysis. Finally, and most significantly, correlation analysis is conducted on extreme climate indices and features of extreme hydrological events, followed by principal component analysis of extreme climate indices, to precisely quantify the impact of extreme climate on the occurrence of extreme hydrological events. The results indicate a warming trend in extreme temperature indices, with a more significant rise in minimum temperatures compared to maximum temperatures. There is a significant decrease in precipitation, but precipitation at higher magnitudes is less affected by the overall reduction in total precipitation. Extreme dry events have markedly increased, particularly concentrated in winter with delayed occurrences, primarily induced by extreme temperature events, that is, warming effects. Conversely, extreme flood events have significantly decreased, mainly concentrated in summer and early autumn, predominantly caused by extreme precipitation and extreme high‐temperature events. The climate and hydrological conditions in the study area have become more extreme and complex. Severe river droughts may occur more frequently in winter, while extreme flooding may happen in summer. Therefore, it is necessary to pay more attention to these developments.
The effects of environmental factors on the synthesis of water‐soluble Monascus red pigments via submerged fermentation: a review
Authors: Li Ping , Zhou Yin , Wu Yingying , Jiang Xiao , Wang Xuan , Shi Xinyun , Wang Weiping 
Published: April 2024

AbstractMonascus pigments (MPs) have been used as natural food pigments for many years. There is a high demand for Monascus red pigments (MRPs) to enhance color and for antibacterial and cancer prevention therapies in food and medicine. Most MRPs are not water soluble, and the yield of water‐soluble MRPs is naturally low. On the other hand, water‐soluble MRP is more cost effective for application in industrial mass production. Therefore, it is important to improve the yield of water‐soluble MRPs. Environmental factors have a significant influence on the synthesis of water‐soluble MRPs, which is crucial for the development of industrial production of water‐soluble MRPs. This review introduces the biosynthetic pathways of water‐soluble MRPs and summarizes the effects of environmental factors on the yield of water‐soluble MRPs. Acetyl coenzyme A (acetyl‐CoA) is a precursor for MPs synthesis. Carbon and nitrogen sources and the carbon/nitrogen ratio can impact MP production by regulating the metabolic pathway of acetyl‐CoA. Optimization of fermentation conditions to change the morphology of Monascus can stimulate the synthesis of MPs. The appropriate choice of nitrogen sources and pH values can promote the synthesis of MRPs from MPs. Additives such as metal ions and non‐ionic surfactants can affect the fluidity of Monascus cell membrane and promote the transformation of MRPs into water‐soluble MRPs. This review will lay the foundation for the industrial production of water‐soluble MRPs. © 2024 Society of Chemical Industry.
Poly‐γ‐glutamic acid enhanced the yield and photosynthesis of soybeans by adjusting soil aggregates and water distribution
Authors: Jing Bo , Shi Wenjuan , Wang Ying 
Published: April 2024

AbstractBACKGROUNDPoly‐γ‐glutamic acid (γ‐PGA) is employed extensively in agriculture to enhance soil water retention; however, the underlying mechanism by which γ‐PGA improves soil structure and soybean productivity in arid regions remains poorly understood. A micro‐scale field experiment was conducted in the arid region of northwest China, employing five concentrations of γ‐PGA to investigate its impacts on soybean yield, photosynthesis, and water‐use efficiency, as well as soil aggregates and water distribution. The five levels of γ‐PGA were 0 (CK), 10 (P1), 20 (P2), 40 (P3), and 80 kg ha−1 (P4).RESULTSThe results demonstrated that the application of γ‐PGA significantly improved soybean yield, photosynthesis, and chlorophyll content. It resulted in a decrease in soil aggregate content with a maximum diameter of less than 0.053 mm and an increase in the stability of soil aggregates in the uppermost layer of the soil (0–30 cm). The application of γ‐PGA significantly increased soil water content, particularly in the uppermost layer of the soil, and effectively reduced water consumption and improving water use efficiency in soybeans. Overall, the P3 treatment exhibited the most pronounced improvement of soybean yield, photosynthesis, water‐use efficiency, as well as distribution of soil aggregates and water. The correlation matrix heatmap also revealed a strong correlation between improvement of soybean yield or photosynthesis at various γ‐PGA application levels and the enhancement of soil stability or soil water content.CONCLUSIONThe multivariate regression analysis revealed that an optimal application level of 46 kg ha−1 γ‐PGA could enhance effectively both yield and water use efficiency of soybean in the arid region of northwest China. © 2024 Society of Chemical Industry.
Rapid analysis of wheat gluten composition using a triple ELISA
Authors: Schuster Clemens , Huen Julien , Weiss Thomas , Scherf Katharina Anne 
Published: April 2024

AbstractBACKGROUNDGluten composition is an important quality parameter of wheat flour. Reversed‐phase high‐performance liquid chromatography (RP‐HPLC) is a state‐of‐the‐art method for its analysis. As this is a very labour‐intensive and time‐consuming procedure, alternative faster methods are desirable. Enzyme‐linked immunosorbent assay (ELISA) is a high‐throughput method often used for the analysis of gluten traces in gluten‐free products. In this proof‐of‐principle study, we introduce an experimental triple ELISA for the relative quantitation of gliadins, high‐molecular‐weight glutenin subunits (HMW‐GS) and low‐molecular‐weight glutenin subunits (LMW‐GS) of one wheat flour extract.RESULTSThe results of 80 common wheat flour samples obtained from the triple ELISA and RP‐HPLC were correlated. The results for gliadins (r = 0.69) and HMW‐GS (r = 0.81) showed a medium and high correlation, respectively. Only a very weak correlation of ELISA and RP‐HPLC results was observed for LMW‐GS (r = 0.49). Results for glutenins (r = 0.69) and gluten (r = 0.72) had a medium correlation. The gliadin/glutenin ratio (r = 0.47) and LMW‐GS/HMW‐GS ratio (r = 0.40) showed a weak or no correlation. The gliadin, LMW‐GS and gluten contents were lower and the HMW‐GS content was higher in the ELISA measurement compared to RP‐HPLC.CONCLUSIONThe quantitation of gliadins and HMW‐GS by the experimental triple ELISA showed comparable results to RP‐HPLC, whereas no strong correlation between the results from the two methods was found for LMW‐GS. Overall, the experimental triple ELISA is suitable for relative gluten quantitation, especially for the analysis of large sample sets. Further work will focus on improving the experimental procedure of the ELISA. © 2024 The Authors. Journal of The Science of Food and Agriculture published by John Wiley & Sons Ltd on behalf of Society of Chemical Industry.
Ultra‐Low‐Power Tunable Topological Photonic Filter on Hybrid Integrated Lithium Tantalite and Silicon Platform
Authors: Feng Chenglong , Zhang Yong , Shen Jian , Xu Zihan , Dong Yihang , Fu Xuecheng , Wang Ying , Sun Lu , Gan Xuetao , Su Yikai 
Published: April 2024

AbstractIntegrated tunable optical filters are essential components in photonic signal processors, telecom systems, sensors, and quantum optical devices. Two of the most important features of a tunable filter are its dimensions and power consumption. Herein, the design and experimental validation of an on‐chip optical filter composed of a 1D topological photonic crystal cavity based on a hybrid integrated lithium tantalite‐silicon platform is presented. The strong optical confinement of the boundary state allows the fabrication of a tunable filter with an ultra‐compact size of 1.14 × 75 µm2 is demonstrated. Moreover, lithium tantalite has excellent electro‐optic properties and enables ultra‐low‐power wavelength tuning of the topological boundary state. The measured power consumption and tuning efficiency of the device are 0.0218 nW pm−1 and 6.64 pm V−1, respectively. The anisotropy of thin‐film lithium tantalite is verified by evaluating its tuning efficiency at different optical angles. The device can compensate for thermally induced refractive index changes ≈20 °C, exhibiting operational robustness. High‐speed transmission experiments confirm the stability of the developed tunable filter. This optical filter implements a topological structure with a compact size and can potentially be applied in on‐chip quantum optics, nonlinear optics, and optical sensing.
Intelligent Laser Emitting and Mode Locking of Solid‐State Lasers Using Human‐Like Algorithms
Authors: Guo Pan , Fan Minyu , Li Hongru , Liu Kun , Pu Yongjie , Wang Sha 
Published: April 2024

AbstractSolid‐state lasers based on mode‐locked technology are widely studied for their strong ability of average or peak power scaling and wide wavelength coverage. However, it usually takes a long time and a lot of effort to manually align an ultrafast solid‐state laser to achieve laser emission and stable mode‐locking. Here, an approach based on intelligent human‐like algorithms is proposed for aligning a solid‐state ultrafast laser system. The intelligent system is based on multi‐algorithm fusion and can fully simulate the process of observation, analysis, decision, and action of an experienced experimenter in the adjustment of the laser alignment and mode‐locking. The intelligent adjustment starts from the state of no laser emission, adopts the neural network, the modified augmented random search (ARS) algorithm, random search, and sliding window strategy, and takes the fluorescence and speckle patterns as indications to realize the laser emission and stable mode‐locking automatically. Several validation experiments are conducted using this intelligent system, and the stable mode‐locked pulses can be achieved within 40 s. This technology provides an efficient solution to the ultrafast solid‐state laser that requires full automatic laser emitting and stable mode‐locking for the first time.
A Hybrid Architecture for Programmable Meta‐System Using a Few Active Elements
Authors: Wang Zheng Xing , Wu Jun Wei , Yang Han Qing , Zhou Qun Yan , Wang Si Ran , Xu Hui , Wu Li Jie , Quan Yinghui , Cheng Qiang , Cui Tie Jun 
Published: April 2024

AbstractDigital coding and programmable metasurfaces stand out as promising candidates in future wireless communications due to their low costs and fast‐action reprogrammable capability. However, 2 significant obstacles, namely integration and power consumption, must be addressed before large‐scale engineering application of the programmable metasurface. This work proposes an easy‐integration and energy‐saving meta‐system and demonstrates its application in wireless communications. The meta‐system features a hybrid architecture and consists of a programmable feed array and a metasurface lens. The feed array comprises 3 subarrays, in which active elements are doped with passive elements and interconnected configurations are used to efficiently reduce the number of active elements by one‐third. The meta‐lens acts as a passive phase shifter to enhance the beamforming performance, further reducing the number of active elements. Moreover, the meta‐system can switch between different modes to achieve various functions. In particular, the maximum power consumption of the meta‐system is only 54 mW, which can be considered nearly passive. A wireless communication experiment is presented, where the meta‐system simultaneously serves as the direct digital modulator and the transmitting antenna. Owing to the low cost, high integration, and nearly passive and programmable features, the meta‐system has remarkable potential for future applications in wireless communications.
Engineering Sulfur‐Containing Polymeric Fire‐Retardant Coatings for Fire‐Safe Rigid Polyurethane Foam
Authors: Fang Yang , Ma Zhewen , Wei Dewang , Yu Youming , Liu Lei , Shi Yongqian , Gao Jiefeng , Tang Long‐Cheng , Huang Guobo , Song Pingan 
Published: April 2024

AbstractWith the advantages of lightweight and low thermal conductivity properties, polymeric foams are widely employed as thermal insulation materials for energy‐saving buildings but suffer from inherent flammability. Flame‐retardant coatings hold great promise for improving the fire safety of these foams without deteriorating the mechanical‐physical properties of the foam. In this work, four kinds of sulfur‐based flame‐retardant copolymers are synthesized via a facile radical copolymerization. The sulfur‐containing monomers serve as flame‐retardant agents including vinyl sulfonic acid sodium (SPS), ethylene sulfonic acid sodium (VS), and sodium p‐styrene sulfonate (VSS). Additionally, 2‐hydroxyethyl acrylate (HEA) and 4‐hydroxybutyl acrylate are employed to enable a strong interface adhesion with polymeric foams through interfacial H‐bonding. By using as‐synthesized waterborne flame‐retardant polymeric coating with a thickness of 600 µm, the coated polyurethane foam (PUF) can achieve a desired V‐0 rating during the vertical burning test with a high limiting oxygen index (LOI) of >31.5 vol%. By comparing these sulfur‐containing polymeric fire‐retardant coatings, poly(VS‐co‐HEA) coated PUF demonstrates the best interface adhesion capability and flame‐retardant performance, with the lowest peak heat release rate of 166 kW m−2 and the highest LOI of 36.4 vol%. This work provides new avenues for the design and performance optimization of advanced fire‐retardant polymeric coatings.
Harmonizing Energies: The Interplay Between a Nonplanar SalEn‐Type Molecule and a TEMPO Moiety in a New Hybrid Energy‐Storing Redox‐Conducting Polymer
Authors: Vereshchagin Anatoliy A. , Volkov Alexey I. , Novoselova Julia V. , Panjwani Naitik A. , Yankin Andrei N. , Sizov Vladimir V. , Lukyanov Daniil A. , Behrends Jan , Levin Oleg V. 
Published: April 2024

AbstractRedox‐conducting polymers based on SalEn‐type complexes have attracted considerable attention due to their potential applications in electrochemical devices. However, their charge transfer mechanisms, physical and electrochemical properties remain unclear, hindering their rational design and optimization. This study aims to establish the influence of monomer geometry on the polymer's properties by investigating the properties of novel nonplanar SalEn‐type complexes, poly[N,N'‐bis(salicylidene)propylene‐2‐(hydroxy)diaminonickel(II)], and its analog with 2,2,6,6‐tetramethylpiperidinyl‐N‐oxyl (TEMPO)‐substituted bridge (MTS). To elucidate the charge transfer mechanism, operando UV–Vis spectroelectrochemical analysis, electrochemical impedance spectroscopy, and electron paramagnetic resonance are employed. Introducing TEMPO into the bridge moiety enhanced the specific capacity of the poly(MTS) material to 95 mA h g−1, attributed to TEMPO's and conductive backbone's charge storage capabilities. Replacement of the ethylenediimino‐bridge with a 1,3‐propylenediimino‐ bridge induced significant changes in the complex geometry and material's morphology, electrochemical, and spectral properties. At nearly the same potential, polaron and bipolaron particles emerged, suggesting intriguing features at the overlap point of the electroactivity potentials ranges of polaron–bipolaron and TEMPO, such as a disruption in the connection between TEMPO and the conjugation chain or intramolecular charge transfer. These results offer valuable insights for optimizing strategies to create organic materials with tailored properties for use in catalysis and battery applications.
Is a Simple Checklist Associated With Improvement in Gender Representation at the AAO‐HNSF Annual Meeting?
Authors: Yesantharao Lekha V. , Sriram Shreya , Litvack Jamie R. , Chandrasekhar Sujana S. , Galaiya Deepa J. 
Published: April 2024

AbstractObjectiveIn September 2017, the American Academy of Otolaryngology–Head and Neck Surgery (AAO‐HNS) added 2 questions querying panel organizers if gender/racial diversity was considered in selecting panel presenters, beginning with the 2018 Annual Meeting (AM). This study examines how this checklist impacted the gender diversity of panel presenters at the AAO‐HNS AM.Study DesignThis was a cross‐sectional investigation comparing female representation before and after the addition of questions inquiring about diversity in 2018.SettingA review of abstract submissions for the AMs from 2015 to 2021.MethodsAM Official Program Abstracts were used to obtain presenter names and specialty area for each panel. The percentage of female presenters, in total and stratified by specialty area, were compared before and after 2018 to quantify changes following the addition of the checklist.ResultsThere was a significant increase in the proportion of female panel presenters from 22.3% (total n = 1199) in 2015 to 2017 to 33.0% (total n = 1868) in 2018 to 2021 (P < .001) and in all panel specialties. The number of female moderated panels also significantly increased after checklist implementation from 22% to 38% (P < .001). Correspondingly, the number of panels with no female representation decreased from 42% in 2015 to 2017 to 23% in 2018 to 2021 (P < .001).ConclusionThe addition of a checklist asking panel organizers to consider diversity in selecting panelists was associated with an increased proportion of female presenters at the AM. This simple strategy can be implemented by all medical conferences to help close the gender gap.
Phosphine‐incorporated Metal‐Organic Framework for Palladium Catalyzed Heck Coupling Reaction
Authors: Chen Wenmiao , Shaikh Insha , Ahmed Fatma , Karkoub Sahar , AlRawashdeh Mamoun , Zhou Hongcai , Madrahimov Sherzod 
Published: April 2024

AbstractAs an emerging material with the potential to combine the high efficiency of homogeneous catalysts and high stability and recyclability of heterogeneous catalysts, metal‐organic frameworks (MOFs) have been viewed as one of the candidates to produce catalysts of the next generation. Herein, we heterogenized the highly active mono(phosphine)‐Pd complex on surface of UiO‐66 MOF, as a catalyst for Suzuki and Heck cross coupling reactions. The successful immobilization of these Pd‐monophosphine complexes on MOF surface to form UiO‐66‐PPh2–Pd was characterized and confirmed via comprehensive set of analytical methods. UiO‐66‐PPh2–Pd showed high activity and selectivity for both Suzuki and Heck Cross Coupling Reactions. This strategy enabled facile access to mono(phosphine) complexes which are challenging to design and require multistep synthesis in homogeneous systems, paving the way for future MOF catalysts applications by similar systems.