bluuebunny/crossref_metadata_2025_split huggingface dataset:
In Situ Fabrication of AgI/MIL‐101(Cr) Nanocomposite Catalyst With Enhancing Photocatalytic Degradation of Organic Dye Molecules From Wastewater
Authors: Zhang Qiuyun , He Maozhen , Wang Jialu , He Shijian , Deng Mei , Lei Yanhui , Zhang Xiaojuan , Cheng Jingsong , Liu Zhengjun , Zhang Yutao 
Published: February 2025

ABSTRACTThe construction and optimization of an effective photocatalyst for photodegradation of persistent recalcitrant organic remains challenging. In this work, MIL‐101(Cr)‐based nanocomposites (AgI@MCr) are proposed to be fabricated by a simple, green solvent, and room temperature in situ preparation strategy, achieving a highly efficient photocatalytic degradation of organic dye rhodamine B (RhB) molecule under visible light irradiation. Extensive characterization (XRD, FTIR, N2 adsorption–desorption, SEM and EDS, TG, XPS, UV–vis DRS, PL, transient photocurrent, and EIS) confirmed the composite material's structure, morphology, elemental composition, and optical characteristics. Among all the prepared nanocomposites, AgI@MCr‐2 demonstrates outstanding photocatalytic performance for RhB with a removal efficiency of 95.4% within 70 min, and a reaction kinetics of 0.0392 min−1, superior to pristine AgI or MIL‐101(Cr), and also shows excellent durability, retaining over 80% RhB degradation efficiency after four cycles. Remarkably, the significant enhancement is attributed to the built interfacial contact and synergistic effect between substances in the nanocomposite, high specific surface area, strong visible light–harvesting capacity, low bandgaps, and high electron–hole pair separation. In addition, a possible degradation route for the AgI@MCr nanocomposite is further proposed using various analysis techniques. This study provides valuable references for developing effective multicomponent MOF‐based photocatalytic composite materials for dyeing wastewater treatment and environmental remediation.
Enhancement of Phosphoric Acid‐Functionalized Graphene Oxide on SPEEK Membrane Performance
Authors: Li Juan , Liu Jiang , Wang Shuai , Xu Yao 
Published: February 2025

ABSTRACTSulfonated poly ether ether ketone (SPEEK) membrane has a great potential in the application of proton exchange membrane fuel cells owing to low cost. However, it suffers from limited proton conductivity. In this paper, quantum chemistry calculation and molecular dynamics simulation are employed to reveal the enhancing mechanism of phosphoric acid‐functionalized graphene oxide (GO) on proton conduction in the SPEEK membrane. The results reveal that the strong interaction between sulfonic acid group and phosphoric acid group leads to the dissociation of proton and the proton transfer pathway with a low energy barrier is formed. Meanwhile, it is found that the phosphoric acid‐functionalized GO can interact well with water molecule and membrane matrix so as to promote the transport of water molecules in the membrane.
Recent Progress in Chemical Vapor Deposition of 2D Magnetic Materials
Authors: Yuan Shuyang , Zhou Yanchang , Yin Lei , Wang Xintian , Jiang Sheng , Song Ziyi , Wen Yao , Cheng Ruiqing , He Jun 
Published: February 2025

AbstractMagnetic 2D materials have gotten significant attention due to their unique low‐dimensional magnetism and potential applications in advanced spintronics, providing an perfect platform for investigating magnetic properties at the 2D limit. The chemical vapor deposition (CVD), known for its simplicity and strong controllability, has become a key technique for fabricating ultrathin magnetic nanosheets. This article systematically reviews recent advancements in CVD‐grown magnetic 2D materials, focusing on the effects of growth parameters on material morphologies and properties, and analyzing the construction of heterostructures and their role in magnetic regulation. In addition, various magnetic characterization methods are introduced, and potential applications of these materials in spintronic devices are discussed. By summarizing current challenges, the article provides insights into future research directions, emphasizing the need to improve material stability, Curie temperature, and scalable synthesis to enable practical applications of 2D magnetic materials.
The history of anatomical engagement
Authors: Wessels Quenton , Taylor Adam M. 
Published: February 2025

AbstractThe public's fascination with anatomy has evolved over time and progressed from avoidance of the tainted yet saintly corpse, to their fascination with cabinets of curiosities. The current narrative review explores public engagement (PE), from its potential origins as cave paintings, to the rise of the disciplinarity of anatomy. Historical insights show how the public engaged in anatomy and with anatomy evolved alongside educational trends and advances ethics. Teaching modalities have shifted as resources have fallen out of favor, become unappealing, illegal or logistically challenging to deliver. Historical changes have resulted in newer approaches coming into the limelight, often moving from the anatomy classroom into the public eye. The public's curiosity with anatomy was satisfied through the organized violence of vivisections and dissections, cabinets of curiosity and permanent museums. Today, the driver of PE is research, education and motivation for learning in the hope of improving people's understanding of their bodies. PE has shifted from spectacles to active participation and collaboration. Looking forward, the authors also propose an adaptive interdisciplinary model for PE in anatomy.
Untersuchungen zur Rauigkeit und Tragfähigkeit von Verbundfugen zwischen normalfestem Beton und UHFB
Authors: Wilkening Marvin , Voß Sören , Schmidt Boso , Oettel Vincent 
Published: February 2025

AbstractVor 1980 in Deutschland errichtete Stahlbeton‐ und Spannbetonbrücken weisen häufig geringe Bügelbewehrungsgrade und rechnerische Querkraftdefizite auf. Eine Querschnittsergänzung der Brückenfahrbahnplatte mit faserbewehrtem ultrahochfestem Beton (UHFB) ist eine einfache, schnelle und wirtschaftliche Verstärkungsmöglichkeit, insbesondere wenn sie ohne eine fugenkreuzende Verbundbewehrung ausgeführt wird. Voraussetzung für ein quasimonolithisches Bauteilverhalten ist ein weitgehend schubsteifer Verbund zwischen dem normalfesten Beton (NB) der Brückenfahrbahnplatte und dem UHFB‐Aufbeton, was eine ausreichende Rauigkeit der UHFB‐NB‐Verbundfuge erfordert. Hierzu wurde ein Verfahren zur berührungslosen lokalen und großflächigen Bestimmung von Rauigkeitsparametern auf Basis von hochaufgelösten Messdaten eines 3D‐Streifenlichtscanners entwickelt, die Rauigkeit der Fugenoberflächen von kleinformatigen UHFB‐NB‐Schubversuchskörpern sowie von einem NB‐Balken mit UHFB‐Aufbetonergänzung ermittelt und die Wirksamkeit der Verstärkungsmaßnahme bei ausreichender Fugenrauigkeit durch kleinmaßstäbliche UHFB‐NB‐Schubversuche sowie Biege‐ und Querkraftversuche an einem NB‐Balken mit und ohne UHFB‐Aufbetonergänzung nachgewiesen. Bei den Balkenversuchen konnte durch die UHFB‐Verstärkung ein Wechsel des maßgebenden Versagensfalls von Querkraft zu Biegung bewirkt werden, was diese Verstärkungsmaßnahme für die Kompensation von Querkraftdefiziten prädestiniert.
Gespritzter UHFB zur Biegeverstärkung von Stahlbeton mit dünnen Schichten
Authors: Strotmann Andre , Jungwirth Jörg 
Published: February 2025

AbstractDer Bedarf an effizienten Verstärkungskonzepten für alternde Infrastrukturen nimmt in Deutschland zu, da die Verkehrslasten und deren Häufigkeit in den letzten Jahrzenten erheblich gestiegen sind. Des Weiteren verursacht der Chloridangriff im Laufe der Lebenszeit des Bauwerks Schäden, welche einen erhöhten Instandsetzungsbedarf nach sich ziehen. Ultra‐Hochleistungs‐Faserbeton (UHFB) bietet durch seine optimierten mechanischen Eigenschaften eine vielversprechende Lösung. Zusätzlich verbessert das Material die Dauerhaftigkeit des verstärkten Stahlbetons durch seine spezifischen Eigenschaften. An der Hochschule für angewandte Wissenschaften München konnte gezeigt werden, dass UHFB auch als Spritzbeton (UHFSB) unter Einsatz konventioneller Gerätetechnik verwendet werden kann, wobei er die typischen Materialeigenschaften von UHFB behält. Untersuchungen an UHFSB‐Stahlbeton‐Verbundbalken ergaben, dass die UHFSB‐Verstärkungsschicht die im vorgeschädigten Stahlbeton vorhandenen Makrorisse effektiv überbrücken und die Tragfähigkeit im Grenzzustand der Tragfähigkeit (GZT) erhöhen kann. Weitere Betrachtungen an UHFSB‐Stahlbeton‐Verbundbauteilen zeigen das Rissbildungs‐ und das Tragverhalten auf. In einem Pilotprojekt konnte die Anwendbarkeit des Konzepts unter realen Bedingungen gezeigt werden. Hierbei wurden Unterzüge an der Unterseite im Bereich der Biegezugeinwirkung verstärkt bzw. instand gesetzt.
Genetically Supported Causality Between Micronutrients and Sleep Behaviors: A Two‐Sample Mendelian Randomization Study
Authors: Zhang Ruijie , Luo Liyan , Zhang Lu , Lin Xinao , Wu Chuyan , Jiang Feng , Wang Jimei 
Published: February 2025

ABSTRACTBackgroundSleep behaviors, defined by the total duration of sleep and chronotype, significantly influence overall health. Compromised sleep quality, which is often manifested through reduced sleep duration and the prevalence of insomnia, has been found to be associated with micronutrient deficiencies. Nonetheless, the existence of a causal relationship between micronutrient levels and sleep behaviors remains to be established.MethodsA two‐sample Mendelian randomization (MR) analysis, utilizing data from genome‐wide association studies (GWAS), was employed to examine the associations between 15 micronutrients (copper; calcium; carotene; folate; iron; magnesium; potassium; selenium; vitamins A, B12, B6, C, D, and E; and zinc) and various sleep behaviors, including short and long sleep durations, insomnia, and chronotype. Furthermore, multivariable MR (MVMR) analysis was performed to address potential confounding due to the interrelationships among micronutrients and to discern potential causal relationships.ResultsThe MR analysis identified a causal association between folate levels and chronotype (odds ratio [OR] = 1.09; 95% confidence interval [CI]: 1.01–1.17; p = 0.02), indicating a tendency toward morningness. Conversely, vitamin B6 (OR = 0.91; 95% CI: 0.86–0.96; p = 1.05 × 10−3) and vitamin D (OR = 0.94; 95% CI: 0.88–1.00; p = 0.03) showed inverse associations with chronotype, indicative of a preference for eveningness. MVMR analysis confirmed the positive association between folate (OR = 1.286, 95% CI = 1.124–1.472, p < 0.001) and chronotype and a negative association with vitamin B6 (OR = 0.750, 95% CI = 0.648–0.868, p < 0.001). No causal relationships were established between micronutrient levels and either sleep duration or insomnia.ConclusionsElevated folate levels correlate with morning‐type preferences (“morning birds”), while higher concentrations of vitamin B6 are associated with evening‐type preferences (“evening owls”).
The Association Between Low Muscle Mass and the Risk of Depressive Symptoms: A Cross‐Sectional Study Based on the Chinese Longitudinal Health Longevity Survey (CLHLS)
Authors: Yang Yuting , Wang Yan , Chen Qiao , Li Ling , Jia Wangping 
Published: February 2025

ABSTRACTBackgroundMany studies have shown a strong link between sarcopenia and depression, and low muscle mass (LMM) is an important component in the diagnosis of sarcopenia; however, there have been no studies on the relationship between LMM and depressive symptoms in the Chinese elderly population. To estimate the potential relationship between LMM and depressive symptoms among older adults, a cross‐sectional analysis was conducted utilizing data from the Chinese Longitudinal Health Longevity Survey (CLHLS).MethodThe study sample comprised 11,711 individuals aged 65 years or older (mean age 83.0 ± 10.9) from the CLHLS database in 2018. We used the corrected appendicular skeletal muscle mass (ASM) prediction formula to assess muscle mass and the 10‐item Center for Epidemiological Studies‐Depression Scale (CES‐D‐10) to assess depressive symptoms. A multivariate logistic regression model and restricted cubic spline (RCS) curves were employed to investigate the association between LMM and depressive symptoms.ResultsThe study findings revealed a 1.16‐fold higher risk of depressive symptoms in the LMM group compared to the control group (adjusted odds ratio [aOR]: 1.16, 95% confidence intervals [95% CI]: 1.05–1.29, p < 0.001). Furthermore, for every one‐point decrease in LMM score below 7.87, the risk of depressive symptoms increased by 8%, with statistical significance. However, when the LMM score was greater than or equal to 7.87, the decrease in the LMM score did not significantly increase the risk of depressive symptoms.ConclusionOur study suggests LMM is a risk factor for depressive symptoms in the elderly Chinese population, and within a certain range, the risk of depressive symptoms increases as the LMM score decreases. Physical exercise may be an effective strategy to maintain optimal muscle mass and help the mental health of the elderly.
Framing Entrepreneurial Ideas for Sustainability: How Do Purpose‐Driven Startups Include the Sustainable Development Goals in Their Pitches?
Authors: Saari Ulla A. , Aagaard Annabeth , Achtenhagen Leona , Mäkinen Saku J. 
Published: February 2025

ABSTRACTThis paper investigates how entrepreneurs frame the sustainability of their business ventures when pitching their business prospects and sustainability approaches to investors. Drawing on framing theory, this research explores the classification and application of sustainability‐related frames employed in business pitches. A qualitative multiple case study methodology is applied to collect and analyze data from startup pitches presented at the startup event Slush, which is held annually in Finland. The sample consists of active startups and those that did not survive following the pitching event. The Need–Approach–Benefit–Competition (NABC) pitching model and the UN's Sustainable Development Goals serve as frameworks for systematically analyzing the content of the verbal pitch presentations. We disentangle how entrepreneurs formulate business ideas within frames related to sustainability themes on the micro, meso, and macro levels using cognitive, strategic, technological, and institutional frames. The resulting model distinguishes between different combinations of sustainability framing elements applied in startup pitches.
Merging of the Fukushima Health Management Survey With the National and Local Cancer Registry to Refine the Detection of Thyroid Cancer Cases After the 2011 Fukushima Daiichi Nuclear Power Plant Accident
Authors: Kimura‐Tsuchiya Reiko , Nagao Masanori , Saji Shigehira , Hayashi Fumikazu , Ohira Tetsuya , Shimura Hiroki , Furuya Fumihiko , Suzuki Satoru , Suzuki Satoshi , Ishikawa Tetsuo , Yokoya Susumu , Ohto Hitoshi , Yasumura Seiji 
Published: February 2025

ABSTRACTBackgroundAfter the Fukushima Daiichi Nuclear Power Plant accident in 2011, the Fukushima Health Management Survey (FHMS) was implemented in Fukushima Prefecture to promote long‐term health care. The FHMS included thyroid ultrasound examination (TUE) for individuals aged ≤ 18 years, including fetuses at the time of the accident. However, the FHMS may not have captured all cases of thyroid cancer because it only followed up with examinees. To address this gap, we aimed to merge individual‐level information from the FHMS with national and local cancer registries (CRs) to determine the limitations of the FHMS and CRs in capturing thyroid cancer cases.MethodsThe FHMS‐eligible residents' information was supplemented by merging and cross‐validating the FHMS and CR data using the Fukushima Prefectural Cancer Registry (FPCR), 2008–2015, and the National Cancer Registry (NCR), 2016–2018. For analysis, registered cases were classified into three groups: registered in both the CR and FHMS, or only in the CRs, or only in the FHMS. The characteristics of each case were evaluated in each database.ResultsIn the FHMS, 212 thyroid cancer cases were identified through 2018, with another 42 cases identified in the CRs. Of the 176 thyroid cancer cases registered until 2015, 28 (15.9%) were identified in the FHMS only and 13 (7.4%) in the FPCR only. Of the 78 additional cases identified since 2016, 29 (37.2%) were identified in the NCR only and 6 (7.7%) in the FHMS only. This indicates that the NCR captured the cases more efficiently than the FPCR.ConclusionMerging data from the FHMS and CRs at the individual level is necessary to capture thyroid cancer cases more accurately after the 2011 nuclear accident.
“Missed” Diagnosis of Mycosis Fungoides: A Case Report
Authors: Mathur Mahesh , Thakur Neha , Regmi Sandhya , Paudel Supriya , Karki Sambidha , Bhattarai Nabita 
Published: February 2025

ABSTRACTMycosis fungoides (MF) is the most common subtype of primary cutaneous T‐cell lymphoma characterized by malignant proliferation of T cells with epidermotropism in the skin. MF has an indolent course, presents as erythematous scaly patches or plaques, and may progress to generalized erythroderma, cutaneous tumors, or extracutaneous invasion. MF is often misdiagnosed at early stages due to nonspecific clinical findings. Patients with MF are at high risk for developing secondary malignancies, including hematological malignancies. We hereby report a case of MF misdiagnosed and associated with underlying diffuse large B‐cell lymphoma.
Challenges in Diagnosis and Management of Takayasu Arteritis: A Case Report Highlighting Vascular Complications and Delayed Recognition
Authors: Adhikari Bindira , Niraula Biraj , Dahal Polina , Suvedi Anil , Subedi Gaurav 
Published: February 2025

ABSTRACTTakayasu arteritis is a rare systemic inflammatory condition that primarily affects medium and large arteries, mainly in young Asian women with an estimated incidence of 1–2 per million. Diagnosis is challenging due to nonspecific early symptoms, resulting in an insidious clinical course until vascular complications arise. A 30‐year female presented with progressive easy fatigue over 4 years. She developed recent visual disturbances, headaches, and dizziness. Examination revealed unrecordable blood pressures and vascular bruits. Imaging revealed vascular involvement including stenosis of arch of aorta and its all branches. The available treatments can ease symptoms and slow progression, but the late diagnosis caused lifelong morbidity, with no procedure to resolve persistent fatigue. TA poses diagnostic challenges due to its nonspecific early symptoms and risk of severe vascular complications. This case highlights the importance of considering TA in young women with vague systemic inflammatory symptoms.
Deep Brain Stimulation in the Bed Nucleus of Stria Terminalis and Medial Forebrain Bundle in Two Patients With Treatment‐Resistant Depression and Generalized Anxiety Disorder—A Long‐Term Follow‐Up
Authors: Naesström Matilda , Blomstedt Patric , Johansson Viktoria 
Published: February 2025

ABSTRACTThis case report presents positive outcomes from deep brain stimulation (DBS) targeting the bed nucleus of the stria terminalis (BNST) in two patients with treatment‐resistant depression and generalized anxiety disorder. DBS effects in the medial forebrain bundle (MFB) area were unclear. Further research into DBS's efficacy when comorbid anxiety is present is required.
Rare Gastric Metastasis From Cervical Cancer: A Case Report
Authors: Hasan Fariha , Timsaal Yumna , Gandhi Tanay‐Veer , Shojaei Hadi , Schwartz Michael , Chaaya Adib 
Published: February 2025

ABSTRACTMGTs most commonly arise from malignant melanoma. MGTs from primary cervical cancers are an extremely rare clinical finding with only a limited number of cases reported in the literature to date. We present the case of a 41‐year‐old female who presented with complaints of dysphagia and fatigue with a history of advanced cervical cancer. Endoscopy results revealed an infiltrating metastatic mass, with biopsy findings consistent with squamous gastric carcinoma of metastatic origin. Despite being on parenteral nutrition, poor disease prognosis led to eventually being discharged to hospice.
A narrative review of artificial intelligence to optimize the use of fertilizers: A game changing opportunity
Authors: Saha Sarmistha , Bhardwaj Alok 
Published: February 2025

AbstractThe green revolution, which came after the industrial revolution, boosted the crop yields produced per unit of land, but it also increased the need for synthetic fertilizers and pesticides and lowered the water table and increased salinization. In order to improve farm productivity, soil fertility is crucial and for preserving soil fertility, boosting yields, and enhancing harvest quality, fertilizer is essential. The decline in the fertility of the soil is a key constraint in enhancing food production worldwide, and improper nutrient management is a significant cause of this problem. Agroecosystems will need to implement contemporary technologies in order to produce enough food and mitigate the detrimental effects of chemical fertilization on the environment. Hence, the agri‐food industry is progressively utilizing artificial intelligence (AI) to increase productivity, efficiency, and sustainability. AI uses computational models to process data and identifies patterns for predictions or decision‐making. This review emphasizes how AI technology could be used for the predictions of manure compositions for improvement of food safety and quality. We aimed to identify the role of AI and the supporting evidences of field studies to characterize the controlled combinations of fertilizers for the efficient crop production with lowest possible plant toxicity. Also, we discuss the constraints and challenges of AI in the food and agricultural sector. In conclusion, AI‐based approaches and field studies suggested that combining organic and inorganic fertilizers can synergistically improve crop growth and yield parameters.
Synthesis of Porphyrin Derivatives Bearing Six Carboxylic Acids for the Formation of Three‐Dimensional Hydrogen‐Bonded Network Structures
Authors: Lee Jeong Heon , Kim Younghun , Kim Gyurang , Jang Woo‐Dong 
Published: February 2025

Abstractwe synthesized a series of porphyrin derivatives with six carboxylic acid groups to explore their potential in forming hydrogen‐bonded networks (YSHs). By systematically varying the position and structure of these carboxylic acid groups, we observed distinct types of hydrogen‐bonded frameworks, including two‐ and three‐dimensional networks. Using single‐crystal X‐ray crystallography, we confirmed that these derivatives form YSHs with unique structural properties influenced by carboxylic acid positioning and π‐π interactions. The 1Zn derivative forms a robust 3D hydrogen‐bonded network stabilized by π‐π stacking interactions, while the 2Ni derivative, with no such stacking, exhibits reduced stability and collapses upon solvent removal. Structural variations like the terphenylene and biphenyl linkers in 3Zn and 4Zn lead to flexible frameworks, while the 5Zn dimer forms two distinct structures depending on the solvent environment. Our findings reveal that careful control over carboxylic acid orientation and linker structure enables the design of diverse hydrogen‐bonded networks with tunable stability and dimensionality. These insights advance our understanding of supramolecular assembly principles in porphyrin‐based materials and offer new pathways for developing high‐performance frameworks for applications in catalysis, sensing, and materials science.