bluuebunny/crossref_metadata_2025_split huggingface dataset:
Failed age-dependent maturation of the occipital condyle in patients with congenital occipitoatlantal instability and Down syndrome: a preliminary analysis
Authors: Browd Samuel R. , McIntyre J. Steele , Brockmeyer Douglas 
Published: October 2008

Object
Normative morphological data pertaining to the development of the occipital condyle have not been reported. The first goal of this study was to establish normative data characterizing the shape of the occipital condyle in healthy children. The second objective of the study was to compare these data with measurements collected in patients with congenital occipitoatlantal instability (COI) or Down syndrome (DS). The effectiveness of CT and plain radiography data was also compared.

Methods
The authors retrospectively reviewed data obtained in 39 patients (14 with DS/COI and 25 age-matched controls). Patients underwent plain lateral radiography and CT scanning of the cervical spine. Normalized measurements of the occipital condyle were obtained for both groups using plain radiography and CT imaging techniques.

Results
The curvature of the occipital condyle in healthy children increased by 60% from infancy to adolescence. Comparison of condylar morphology on plain lateral radiographs and CT scans in patients with DS/COI and in age-matched controls demonstrated a significant difference in mean normalized depth/length ratios. Comparison of curvature data obtained using plain lateral cervical radiography with measurements obtained using cervical CT scanning demonstrated a correlation coefficient of 0.63. However, intra- and interobserver reliability for plain radiographic analysis of the occipital condyle was poor (r2 = 0.40 and 0.44, respectively).

Conclusions
Patient with DS/COI who have occipitoatlantal instability fail to develop the curved architecture in the occipital condyle that occurs in age-matched controls over time. Sagittal 2D CT reconstructions accurately determine the precise structure of the occipital condyle, although the indications for CT scanning are limited. Because of the poor intra- and interrater reliability on static plain radiographs, dynamic flexion/extension cervical spine radiographs remain the study of choice by which to directly evaluate occipitocervical motion.
New records of phytoplankton for Bangladesh. 7. <i>Phacus</i> spp.
Authors: Khondker Moniruzzaman , Bhuiyan Rauf Ahmed , Yeasmin Jenat , Alam Munirul , Sack R Bradley , Huq Anwar , Colwell Rita R 
Published: November 2008

Thirteen species of Phacus hitherto not reported from Bangladesh have been described and illustrated. Freshwater ponds at southern districts of Pirojpur and Barisal revealed these presence of the species. Â Key words: Phytoplankton, New records, Bangladesh, Phacus, Ponds doi:10.3329/bjb.v37i1.1564 Bangladesh J. Bot. 37(1): 55-60, 2008 (June)
Antimicrobial activity of leaf extracts of <i>Eupatorium triplinerve</i> Vehl. against some human pathogenic bacteria and phytopathogenic fungi
Authors: Rahman Md Shafiqur , Junaid Mohammad 
Published: November 2008

Petroleum ether, carbon tetrachloride, chloroform, and ethyl acetate extracts of Eupatorium triplinerve Vehl. leaves were investigated for their antimicrobial activities against 11 human pathogenic bacteria and six phytopathogenic fungi. The crude extracts showed good activity against the organisms tested herein. The chloroform extract exhibited the largest zone of inhibition (22 mm in diam with 1000 Î¼g/disc extract) against Vibrio and the highest inhibition of fungal radial mycelial growth (73.5% with 100 Î¼g extract/ml medium) against Colletotrichum corchori. The chloroform extract exhibited the lowest MIC against Vibrio (250 Î¼g/ml) and C. corchori (62.5 Î¼g/ml). It appeared that E. triplinerve could be a potential natural source of new antimicrobial agent. Â Â Key words: Antimicrobial activity, Leaf extract, Eupatorium triplinerve doi:10.3329/bjb.v37i1.1570 Bangladesh J. Bot. 37(1): 89-92, 2008 (June)
Adverse Pregnancy Outcomes and Long-Term Mortality in Women
Authors: Crump Casey , Sundquist Jan , Sundquist Kristina 
Published: April 2024

ImportanceWomen with adverse pregnancy outcomes, such as preterm delivery or preeclampsia, have higher future risks of cardiometabolic disorders; however, little is known about their long-term mortality risks. A better understanding of such risks is needed to facilitate early identification of high-risk women and preventive actions.ObjectiveTo determine long-term mortality risks associated with 5 major adverse pregnancy outcomes in a large population-based cohort of women.Design, Setting, and ParticipantsThis national cohort study in Sweden used the Swedish Medical Birth Register, containing prenatal and birth information for nearly all deliveries in Sweden since 1973, to identify women who had a singleton delivery during 1973 to 2015. All 2 195 667 such women with information for pregnancy duration and infant birth weight were included in the study. Data were analyzed from March to September 2023.ExposureAdverse pregnancy outcomes (preterm delivery, small for gestational age, preeclampsia, other hypertensive disorders, and gestational diabetes), identified from nationwide birth records.Main Outcome and MeasuresAll-cause and cause-specific mortality through December 31, 2018. Cox regression was used to compute hazard ratios (HRs) for mortality associated with specific adverse pregnancy outcomes, adjusted for other maternal factors. Cosibling analyses assessed for confounding by shared familial (genetic or environmental) factors.ResultsIn 56 million person-years of follow-up to a median (IQR) age of 52 (42-61) years, 88 055 women (4%) died (median [IQR] age at death, 59 [50-67] years). All 5 adverse pregnancy outcomes were independently associated with increased mortality. Across the entire follow-up (≤46 years after delivery), adjusted HRs for all-cause mortality associated with specific adverse pregnancy outcomes were as follows: gestational diabetes, 1.52 (95% CI, 1.46-1.58); preterm delivery, 1.41 (95% CI, 1.37-1.44); small for gestational age, 1.30 (95% CI, 1.28-1.32); other hypertensive disorders, 1.27 (95% CI, 1.19-1.37); and preeclampsia, 1.13 (95% CI, 1.10-1.16). All HRs remained significantly elevated even 30 to 46 years after delivery. These effect sizes were only partially (0%-45%) reduced after controlling for shared familial factors in cosibling analyses. Women who experienced multiple adverse pregnancy outcomes had further increases in risk. Several major causes of death were identified, including cardiovascular and respiratory disorders and diabetes.Conclusions and RelevanceIn this large national cohort study, women who experienced any of 5 major adverse pregnancy outcomes had increased mortality risks that remained elevated more than 40 years later. Women with adverse pregnancy outcomes need early preventive evaluation and long-term follow-up for detection and treatment of chronic disorders associated with premature mortality.
Prevalence and Incidence of Fractures in Patients With Nonfunctional Adrenal Tumors
Authors: Lindh Jonatan D. , Patrova Jekaterina , Mannheimer Buster , Falhammar Henrik 
Published: April 2024

ImportanceIt is unclear whether nonfunctional adrenal tumors (NFATs) are associated with fractures.ObjectiveTo analyze fracture frequencies in individuals with NFATs.Design, Setting, and ParticipantsA national retrospective cohort study was conducted in patients with NFATs diagnosed in Sweden between January 1, 2005, and December 31, 2019, and control participants without adrenal tumors followed up until death or the end of 2019. Individuals with a diagnosis of adrenal hormonal excess or previous malignant tumors were excluded. Sensitivity analyses were performed in subgroups of individuals with a combination of gallbladder, biliary tract, and pancreas diseases (for whom it was assumed that controls would also have undergone computed tomography) and 3- and 12-month survival free of malignant tumors after the NFAT diagnosis. The data were analyzed from September to November 2023.ExposuresDiagnosis of NFATs.Main Outcomes and MeasuresMain study outcomes were prevalence and incidence of fractures after adjustment for sex, age, and comorbidities. Secondary outcomes were fragility fractures, fractures with fall on the same level, and fracture locations (distal arm and vertebral and hip fractures). Fracture incidence after adrenalectomy was also studied.ResultsAmong 20 390 patients, 12 120 (59.4%) were women, and the median (IQR) age was 66 (57-73) years; among 125 392 controls, 69 994 (55.8%) were women, and the median (IQR) age was 66 (57-73) years. Previous fractures were more common in patients diagnosed with NFATs compared with controls (4310 of 20 390 [21.1%] vs 20 323 of 125 392 [16.2%]; odds ratio [OR], 1.39; 95% CI, 1.34-1.45; adjusted OR [AOR], 1.27; 95% CI, 1.23-1.33). During the follow-up period (median [IQR], 4.9 [2.2-8.2] years), incident fractures were more common in patients with NFATs (3127 of 20 390 [15.3%] vs 16 086 of 125 392 [12.8%]; hazard ratio [HR], 1.40; 95% CI, 1.34-1.45; adjusted HR [AHR], 1.27; 95% CI, 1.22-1.33). An association between NFATs and vertebral fractures was found (AOR, 1.51; 95% CI, 1.33-1.72; AHR, 1.83; 95% CI, 1.60-2.09). In men younger than 50 years, NFATs were associated with fractures (AOR, 1.45; 95% CI, 1.21-1.74; AHR, 1.48; 95% CI, 1.20-1.82). There was no association among individuals who had undergone adrenalectomy (AHR, 1.12; 95% CI, 0.90-1.38). The association between NFATs and fractures remained significant and of similar magnitude in all sensitivity analyses.Conclusions and RelevanceIn this cohort study, NFATs were associated with fractures, particularly among younger men; thus, patients with NFATs should have bone health evaluation with appropriate treatment and monitoring, especially in younger men.
Implementation of a programmatic assessment model in radiation oncology medical physics training
Authors: Barbagallo Cathy , Osborne Kristy , Dempsey Claire 
Published: April 2024

AbstractPurposeIn 2019, a formal review and update of the current training program for medical physics residents/registrars in Australasia was conducted. The purpose of this was to ensure the program met current local clinical and technological requirements, to improve standardization of training across Australia and New Zealand and generate a dynamic curriculum and programmatic assessment model.MethodsA four‐phase project was initiated, including a consultant desktop review of the current program and stakeholder consultation. Overarching program outcomes on which to base the training model were developed, with content experts used to update the scientific content. Finally, assessment specialists reviewed a range of assessment models to determine appropriate assessment methods for each learning outcome, creating a model of programmatic assessment.ResultsThe first phase identified a need for increased standardized assessment incorporating programmatic assessment. Seven clear program outcome statements were generated and used to guide and underpin the new curriculum framework. The curriculum was expanded from the previous version to include emerging technologies, while removing previous duplication. Finally, a range of proposed assessments for learning outcomes in the curriculum were generated into the programmatic assessment model. These new assessment methods were structured to incorporate rubric scoring to provide meaningful feedback.ConclusionsAn updated training program for Radiation Oncology Medial Physics registrars/residents was released in Australasia. Scientific content from a previous program was used as a foundation and revised for currency with the ability to accommodate a dynamic curriculum model. A programmatic model of assessment was created after comprehensive review and consultation. This new model of assessment provides more structured, ongoing assessment throughout the training period. It contains allowances for local bespoke assessment, and guidance for supervisors by the provision of marking templates and rubrics.
Achievements in the Photomagnetic Effect of Cobalt‐Iron Prussian Blue Analogues
Authors: Yao Kangkang , Dong Chengwei , Cao Kaiyan , Zhang Yin , Yang Sen 
Published: April 2024

AbstractHarnessing light for magnetization control presents a promising approach with compelling merits such as non‐contact operation, ultrafast response, reversibility, high spatial resolution, tunability, and energy efficiency. Photoinduced metal‐to‐metal charge transfer (MMCT) is one key mechanism in achieving photo‐controlled magnetic properties, making relevant materials prime candidates for versatile switchable devices. Cobalt iron Prussian blue analogues (CoFePBA) are trailblazers in showcasing photomagnetic properties via MMCT and the numerous related studies on CoFePBA have significantly enhanced the understanding of photoinduced MMCT processes. Thus, this review embarks on a thorough examination of three decades of research on the photomagnetic of CoFePBA to deep into the art of the photocontrol of spin. In addition to an introduction to the structure and preparation of CoFePBA, the focus is on elucidating the underlying mechanisms and introducing strategies for its manipulation and control. Finally, the challenges and prospects at this moment are summarized and discussed.
Reversible Redox‐Driven Crystallization in a Paracyclophane Monolayer at a Solid–Liquid Interface
Authors: Li Zhi , Mali Kunal , Hapiot Philippe , De Feyter Steven , Attias André‐Jean , Mertens Stijn F. L. 
Published: April 2024

AbstractThe development and integration of cyclophanes into future functional materials require a detailed understanding of the physicochemical principles that underlie their properties, phase behavior, and in particular the relationship between structure and function. Here, electrochemically switchable crystallization of a ferrocene‐bearing 3D Janus tecton (M‐Fc) at the interface between highly oriented pyrolytic graphite (HOPG) and an electrolyte solution is demonstrated. The M‐Fc adlayer is successfully visualized under both ambient and electrochemical conditions using scanning tunneling microscopy. Voltammetric measurements show a surface‐confined redox process for the M‐Fc modified surface that drives the phase transition between a visible 2D ordered linear phase (M‐Fc0, with ferrocene in the neutral state) and an invisible gas‐like adsorption layer with high mobility when ferrocene is oxidized, M‐Fc+, and a “square scheme” mechanism explains the data. Analogous experiments in a ferrocene‐free tecton adlayer show no phase transition and confirm that the dynamics in M‐Fc are redox‐driven. On‐surface 3D nanoarchitectures are also demonstrated by forming inclusion complexes between M‐Fc and β‐cyclodextrin and device behavior through electrochemical scanning tunneling spectroscopy (STS). These results showcase the functional potential of this class of cyclophanes, which can find use in actuators, optical crystals, and other smart materials.
Defining New Benchmarks of Low CTAB‐Concentration‐Based Gold Nanorod Synthesis: The Underestimated Potential of Polymer‐Directed Anisotropic Growth
Authors: Lemich Sascha Benedict , Soltau Steffen , Weißpflog Maria , Schulze Verena R. , Feliu Neus , Hankiewicz Birgit , Abetz Volker 
Published: April 2024

AbstractThis work presents new anisotropic growth‐directing copolymers suitable for the seed‐mediated growth of gold nanorods (GNRs). Copolymers with different architectures are studied. They all contain dimethylaminomethyl methacrylate (DMAEMA) functionalized with 1‐bromohexadecane (BHD) as the vital component. For the synthesis of the different copolymers, the photo‐iniferter reversible addition–fragmentation chain transfer (photoRAFT) polymerization is used, where DMAEMA is combined with a lower critical solution temperature (LCST) polymer block for better solubility after the functionalization. The results show that the presented copolymers can induce anisotropic growth of gold nanoparticles. Additionally, the influence of the LCST of the water‐soluble block and the temperature of the growth solution on the GNR synthesis are investigated. Furthermore, the plasmonic behavior of the resulting GNRs solution is investigated at temperatures around the LCST of the copolymer.
Modulation of Sulfur Vacancies in ZnIn2S4/MXene Schottky Heterojunction Photocatalyst Promotes Hydrogen Evolution
Authors: Xu Minghua , Ruan Xiaowen , Meng Depeng , Fang Guozhen , Jiao Dongxu , Zhao Shengli , Liu Zheyang , Jiang Zhifeng , Ba Kaikai , Xie Tengfeng , Zhang Wei , Leng Jing , Jin Shengye , Ravi Sai Kishore , Cui Xiaoqiang 
Published: April 2024

AbstractThe sustainable production of hydrogen utilizing solar energy is a pivotal strategy for reducing reliance on fossil fuels. ZnIn2S4 (ZIS), as a typical metal sulfide semiconductor, has received extensive attention in photocatalysis. Although the introduction of sulfur (S) vacancies in ZIS to enhance photocatalytic hydrogen production by creating defect energy levels has been explored, detailed studies on the control and modulation of S‐vacancies in ZIS are sparce. This study demonstrates that while moderate levels of S‐vacancies can enhance hydrogen evolution, excessive vacancies may hinder the process, underscoring the importance of S‐vacancy modulation. Guided by theoretical calculations, We have designed and synthesized ZIS with modulated S‐vacancies to realize favorable hydrogen adsorption‐free energy and integrated in a Schottky‐heterojunction with MXene co‐catalysts for enhanced hydrogen evolution. The optimized hydrogen evolution performance of ZnIn2S4/MXene (ZMX) reaches 14.82 mmol g−1 h−1 under visible light irradiation, surpassing many reported ZnIn2S4‐based photocatalysts. The enhanced performance is ascribed to widened light absorption and enhanced carrier transportation realized by S‐vacancy modulation and the co‐catalytic effect. Femtosecond ultrafast absorption (fs‐TA) spectra and other in‐situ/ex‐situ characterizations further prove an efficient separation and transfer in an as‐prepared ZMX catalyst. These findings open up new perspectives for designing catalysts with vacancy modulation.
In Situ Construction of a Lithiophilic and Electronically Insulating Multifunctional Hybrid Layer Based on the Principle of Hydrolysis for a Stable Garnet/Li Interface
Authors: Wang Lingchen , Lu Yan , Zheng Chujun , Cai Mingli , Xu Fangfang , Wen Zhaoyin 
Published: April 2024

AbstractAdapting solid‐state Li‐metal batteries is an attractive way to pursue higher energy density and safety compared to liquid‐based ones. With high ionic conductivity and excellent stability with Li, Ta‐doped Li7La3Zr2O12 (LLZTO) is an effective option. However, the poor solid–solid interface contact induced by the lithiophobic Li2CO3 layer hinder its practical application. Herein, a versatile strategy is proposed based on the hydrolysis of sodium tetrafluoroborate (NaBF4), aiming to convert the Li2CO3 into multifunctional hybrid layer containing LiF, LiBO2, and NaF. Among them, LiF and LiBO2 serve as the primary Li ion conductors, the introduction of NaF with high surface energy not only enhances the interface wettability, but also further elevates the critical dendrite strength against Li dendrites. All three components serve as excellent electronic insulators, suppressing electron invasion at the interface and preventing Li dendrite growth in the solid electrolyte. As expected, the interfacial impedance of the NaBF4 treated symmetric cell is reduced to 6.0 Ω cm2, the critical current density (CCD) comes to 2.0 mA cm−2, and cycles over 3000 h at 0.3 mA cm−2 and 1500 h at 0.5 mA cm−2 respectively. Besides, the modified SSBs matched with LiFePO4 or LiNi0.6Co0.2Mn0.2O2 cathode show great long‐term cycling and rate performance.
Ultrahigh X‐Ray Imaging Spatial Resolution Enabled by an 0D Mn(II) Hybrid Scintillator
Authors: Xiao Shang‐Biao , Zhang Xiangzhou , Mao Xingchu , Yang Han‐Jiang , Chen Zhong‐Ning , Xu Liang‐Jin 
Published: April 2024

AbstractSpatial resolution of scintillator is crucial for high‐quality X‐ray imaging, especially in tiny and complicated electronic component. In this work, PrPP2MnBr4 single crystal is obtained by dual‐solvent evaporation method, which gives an unprecedented high spatial resolution of 104.3 lp/mm, representingstate of the art among non‐lead metal halides. The study also conducts the preparation of large area scintillation screen (10 cm × 10 cm) by solidifying melted salt PrPP2MnBr4, thus giving an excellent X‐ray imaging with spatial resolution of 53.5 lp mm−1, which demonstrates its application on large area detection.
Large‐Area Knittable, Wash‐Durable, and Healable Smart Fibers for Dual‐Modal Sensing Applications
Authors: Zhou Bo , Yuan Man , Lu Hao , Qiu Xiaoyan , Liu Jize , Zhao Zhong , Zhang Xinxing , Cai Guangming 
Published: April 2024

AbstractFiber‐based multimodal sensors with electrical/optical signals are highly desired for next‐generation wearable electronics. Despite the remarkable progress in this area, achieving large‐scale knittable, washable, and self‐healing performance in fiber‐based multimodal sensors simultaneously remains a great challenge. Here, a smart fiber capable of exhibiting piezoresistive/luminescent properties based on an H‐bonding connected multilayered core–shell nanostructure is developed. The core principle of this design involves constructing strong interfacial interactions between the fiber layers, which results in a sensor with high sensitivity (gauge factor = 12383500), exceptional water resistance, and robust self‐healing properties (tensile strength 30.9 MPa, healing efficiency 72.9%). Unlike traditional fiber‐based sensors where elaborate nanostructures are prone to shedding during knitting, this strategy enables the fiber sensors with excellent knittability to be patterned in the fabric, improving both optical and electrical sensitivities. This work is anticipated to make a significant contribution to the further development of wearable electronic products and visual human–computer interaction electronic devices.
Liquid‐Metal‐Based Soft Pressure Sensor and Multidirectional Detection by Machine Learning
Authors: Gul Osman , Kim Jeongnam , Kim Kyuyoung , Kim Hye Jin , Park Inkyu 
Published: April 2024

AbstractElectronic skin (e‐skin) is an emerging technology with promising applications in various fields, including human–machine interfaces, prosthetics, and robotics. Soft and flexible sensors are vital components for the e‐skin that can mimic human skin's sensing capabilities. Among soft sensors, liquid‐metal‐based sensors have gained attention owing to their unique properties, such as high electrical conductivity, stretchability, and elasticity. Herein, a novel approach is presented that enables multidirectional pressure sensing with a machine‐learning approach from the transient response of the liquid‐metal‐based soft pressure sensor for the e‐skins. In this study, a soft sensor is developed that utilizes liquid metal and has an array of microchannels on a dome‐shaped structure to detect pressures from multiple directions. The transient response from six microchannels of the sensor is used as the input for a convolutional neural network (CNN) to predict the direction (classification accuracy of 99.1%) and magnitude (regression error of 20.13%) of the applied pressures in real time. Finally, a potential application of the developed liquid‐metal‐based soft sensor as a human–machine interface device is demonstrated by using it to control an RC model car through multidirectional predictions (pressure direction and magnitude) through machine learning in real time.