bluuebunny/crossref_metadata_2025_split huggingface dataset:
Electrocatalysis
Authors: Katsaounis A. , Brosda S. , Vayenas C.G. 
Published: December 2007

AbstractThe sections in this article areIntroductionAdsorptionBasic Electrokinetic Principles and Experimental TechniquesElectrokinetic and Mass‐transport ControlThe Measurement ofIR‐free Electrocatalyst OverpotentialCyclic VoltammetryAC‐impedance SpectroscopyNormalization of Active SurfaceTheory of ElectrocatalysisOverpotentials and the Butler–Volmer EquationVolcano PlotsTransition State ApproachesQuantum Mechanics–based ModelsPromotional EffectsThe Hydrogen Oxidation/Evolution ReactionOxygen Reduction/Evolution ReactionOxidation of Small Organic MoleculesOther Important Electrocatalytic SystemsElectrochemical Promotion of Catalytic ReactionsPromotional Rules in Catalytic and Electrocatalytic SystemsConcluding Remarks
Electrochemical Machining
Authors: Davydov Alexei D. , Volgin Vladimir M. 
Published: December 2007

Abstract
The sections in this article are

Introduction

Definition and General Information

Advantages and Disadvantages

Electrode Processes

Anodic Processes

Cathodic Processes

Metal Removal Rate

Accuracy

Methods of Lowering the Effects of Void Fraction and Heating on the Distribution of Current Density Over the
WP
Surface

Methods Enhancing the Localization of Metal Dissolution

Prediction of Workpiece Shape and Tool‐electrode Design

Problem with Moving Boundary

The Direct Problem

The Inverse Problem

Quasi‐steady‐state Approximation

Calculation of Transfer Processes in the
IEG

Direct Problem: Evolution of
WP
Surface

The Inverse Problem: Correction of
TE
Surface

Local, One‐dimensional Approximation

Calculation of Transfer Processes in the
IEG

The Direct Problem: The Evolution of
WP
Surface

The Inverse Problem: The Correction of
TE
Surface

Automated Design of
ECM
Operations

ECM
Techniques and Applications

Electrochemical Sinking

Electrochemical Drilling

Electrochemical Deburring

Removing of Defective Layers

ECM
in Biomedical Engineering

Subsea Application

Electrochemical Micromachining (
ECMM
)

Hybrid Processes

Surface Layer Integrity after
ECM

Control of Electrolyte Composition and Environmental Problems

Conclusions
Aqueous Processing of Metals
Authors: Jari Aromaa D.Sc. 
Published: December 2007

Abstract
The sections in this article are

Electrowinning and Electrorefining

Basic Electrochemistry

Polarization Effects

Electrode Surface

Current Distribution

Cell Voltage and Energy Use

Factors Affecting Deposit Quality

Electrolysis Technology

Cell Construction

Current Feed

Permanent Anodes

Copper Production

Copper Electrorefining

Technology of Copper Refining

Energy Consumption

Additives

Sulfate‐based Copper Electrowinning

Halide‐based Copper Electrowinning

Nickel Production

Nickel Electrorefining

Electrorefining Nickel Metal Anodes

Electrorefining Sulfide Matte

Sulfate‐based Nickel Electrowinning

Chloride‐based Nickel Electrowinning

Nickel Electrolyte Purification

Zinc Production

Electrodeposition of Zinc

Energy Consumption

Zinc Electrowinning Practice

Noble Metals

Gold

Silver

Platinum‐group Metals

Other Metals

Lead

Cobalt

Tin

Cadmium
Principles, Functions, and Classification of Fuel Cells
Authors: Cappadonia Marcella , Stimmig Ulrich , Kordesch Karl V. , Tambasco de Oliveira Julio Cesar , Schmuki Patrik 
Published: December 2007

Abstract
The sections in this article are

Introduction

Principles of Fuel Cells

Functions

Setup

Efficiency

Classification of Fuel Cell Systems

Low Temperature Fuel Cells

Alkaline Fuel Cells (
AFC
)

Proton Exchange Membrane Fuel Cells (
PEMFCs
)

Phosphoric Acid Fuel Cells (
PAFC
)

High‐temperature Fuel Cells

Molten Carbonate Fuel Cells (
MCFCs
)

Solid Oxide Fuel Cells (
SOFC
)
Capacitance, Luminescence, and Related Optical Techniques
Authors: Nakato Yoshihiro 
Published: December 2007

Abstract
The sections in this article are

Capacitance

Space Charge Layer at a Semiconductor–Electrolyte Interface

Differential Capacitance of a Semiconductor–Electrolyte Interface

Measurement of Differential Capacitance

Mott–Schottky Plots and Flat Band Potentials

Luminescence from Semiconductor Electrodes

Photoluminescence and Electroluminescence

Measurements of Luminescence from Semiconductor Electrodes

DC
Methods

Pulsed Techniques

Bulk and Surface Luminescence

Other Optical Techniques

Time‐resolved Laser Spectroscopy

Transient Absorption Spectroscopy

Transient Grating Spectroscopy

In Situ Spectroscopic Investigation of Semiconductor Surfaces

Other Miscellaneous Techniques

Summary
The Photoelectrochemistry of Semiconductor/Electrolyte Solar Cells
Authors: Sharon Maheshwar 
Published: December 2007

Abstract
The sections in this article are

Introduction

Description of a
PEC
Cell

Types of
PEC
Cells

Aim of this Section

Semiconductor‐electrolyte Junction

What Kind of Force Exists in this Region?

Magnitude of Potential Developed at the Interface

Effect of Junction Illumination

Efficiency of Conversion of Light Energy into Electrical Energy

Factors Considered in Selecting a Semiconductor

Energy Levels in Redox Couples

How Do We Compare Redox Potential with Fermi Level of a Semiconductor?

Do the Energy Levels for Reduction and Oxidation Process Possess the Same Value?

Effect of Charge Distribution in the Electrolyte

Capacitance of the Space Charge Layer

Semiconductor‐electrolyte Junction Under Illumination

Gärtner's Model

Application of Gärtner Model

When α is Constant during Photocurrent Measurement

When ‘
w
' is Constant During Photocurrent Measurement

Effect of Counter‐Electrode

Effect of Surface States

Photodecomposition of Semiconductor

Materials for
PEC
Cell

Laser Scanning Technique for a Large Area Electrode

Summary

Acknowledgment
Solar Photoelectrochemical Generation of Hydrogen Fuel
Authors: Sharon Maheshwar , Licht Stuart 
Published: December 2007

Abstract
The sections in this article are

Introduction

Theoretical Consideration for Water Electrolysis

Photoelectrochemical Cell for Photoelectrolysis

Photoelectrolysis of Water

Energetics of Photodecomposition of Water

Multiple‐type
PEC
Cells

Bipolar Cell

Recent Developments

Conclusion

Acknowledgment
Standard, Formal, and Other Characteristic Potentials of Selected Electrode Reactions
Authors: Inzelt György 
Published: December 2007

Abstract
The sections in this article are

Group 1 Elements

Group 2 Elements

Group 3 Elements

Group 4 Elements

Group 5 Elements

Group 6 Elements

Group 7 Elements

Group 8 Elements

Group 9 Elements

Group 10 Elements

Group 11 Elements

Group 12 Elements

Group 13 Elements

Group 14 Elements

Group 15 Elements

Group 16 Elements

Group 17 Elements

Group 18 Elements

Acknowledgment
Technetium
Authors: Schultz Franklin A. , Duncan Cole T. , Rigsby Matthew A. 
Published: December 2007

Abstract
The sections in this article are

Introduction

Mononuclear Complexes

Oxo Complexes

Homoleptic and Mixed‐ligand Complexes

Binuclear Complexes

Oxo‐bridged Complexes

Metal–metal‐bonded Complexes
Rhenium
Authors: Schultz Franklin A. , Duncan Cole T. , Rigsby Matthew A. 
Published: December 2007

Abstract
The sections in this article are

Introduction

Mononuclear Complexes

Oxo Complexes

Homoleptic and Mixed‐ligand Complexes

Polynuclear Complexes

Oxo‐bridged Complexes

Metal–metal‐bonded Complexes

Supramolecular Arrays

Carbon Dioxide Fixation
Electrochemistry of Lead
Authors: Stroka Jadwiga , Maksymiuk Krzysztof , Galus Zbigniew 
Published: December 2007

AbstractThe sections in this article areDouble‐layer Properties ofPbElectrodesProperties of Solid ElectrodesProperties of Liquid ElectrodesAdsorption on Solid ElectrodesElectrochemical Properties and Kinetics of Lead and Lead CompoundsPb(II)/Pb(Hg) SystemStudies in the Presence of Inhibitors and Organic SolventsOther PhenomenaComplexes ofPb(II) and Related PhenomenaElectrochemical Processes of Liquid Lead in Molten SaltsVoltammetric Behavior of LeadSulfuric Acid SolutionsNitric Acid SolutionsPhosphoric Acid SolutionsSodium Hydroxide SolutionsDifferent Salt SolutionsVoltammetric Behavior of Several Lead CompoundsPbOPbO2PbchalcogenidesElectrodeposition and Underpotential Deposition of Lead on Solid SubstratesPlatinumGoldSilverCopperCarbonSiliconGermaniumOther MaterialsCorrosion and PassivationApplied ElectrochemistryLead‐acid BatteriesElectrocatalytic PropertiesPbPbO2Electrochemical SensorsPotentiometric SensorsAmperometric/Voltammetric Sensors
Comparison of Chemical and Electrochemical Methods in Organic Synthesis
Authors: Schäfer Hans J. 
Published: December 2007

AbstractThe sections in this article areIntroductionGeneral Aspects of Organic SynthesisThe Reactive Intermediates in Organic ElectrosynthesisSelection of Advantageous Electrochemical C,C‐Bond Forming Reactions and Functional Group InterconversionsC,C‐Bond FormationFunctional Group InterconversionsWorking Out An Electroorganic SynthesisEquipmentSome General Comments
Reduction of Oxygen‐containing Compounds
Authors: Kashimura Shigenori , Ishifune Manabu 
Published: December 2007

Abstract
The sections in this article are

Introduction

Cathodic Reduction of Alcohols

Cathodic Reduction of Ethers

Cathodic Reduction of Esters and Amides

Cathodic Reduction of Carboxylic Acid

Cathodic Reduction of Ketones, Aldehydes, and Carbon Dioxide
Electrogenerated Acids and Bases
Authors: Nielsen Merete Folmer 
Published: December 2007

Abstract
The sections in this article are

Electrogenerated Acids

General Concepts

Influence of the Solvent‐electrolyte System

In situ Versus Ex situ Formation of the
EGA

Comparison of
EGAs
with Conventional Acids

Charge‐consuming Reactions

EGA
Catalyzed Follow‐up Reaction of the Product of Anodic Oxidation

EGA
Induced Conversion of Substrate

Acid Catalyzed Reactions

Ring Opening of Epoxides

Reaction of Acetals, Ketones, and Aldehydes with Nucleophiles

1,4‐Addition to Enones

Functional Group Protection

Electrophilic Aromatic Substitution

Cyclizations

Diels–Alder Reactions

Electrogenerated Bases

General Concepts

In situ Versus Ex situ Formation of the
EGB

Kinetic Versus Thermodynamic Basicity

Efficiency of the Proton Transfer Reaction

Comparison of
EGBs
with Conventional Bases

Nitrogen Bases

Azo Compounds and Nitrogen Heteroaromatics as Probases

Amides as Probases

Oxygen Bases

Dioxygen as Probase

Phenols as Probases

Carbonyl Compounds as Probases

Carbon Bases

Activated Alkenes as Probases

Carbanions as
EGBs

Other Electrogenerated Carbon Bases

Reactions Consuming Stoichiometric Amounts of Base

Wittig Reactions

Addition to Aldehydes and Ketones

Alkylation of Activated Methylene Compounds

Cyanomethylation

Carboxylation

Cyclizations

Oxidative Conversions

Condensations

Miscellaneous Reactions

Base‐Catalyzed Reactions

Michael Additions

Reactions Involving Aldehydes and Ketones
Scanning Electrochemical Microscopy Applied to Biological Systems
Authors: Shiku Hitoshi , Ohya Hiroaki , Matsue Tomokazu 
Published: December 2007

Abstract
The sections in this article are

SECM

Feedback Mode

Generation/Collection Mode

Applications to Biological Systems

Enzymes

Antigen–Antibodies

Local Fluxes Through Biological Materials

Liquid–Liquid Interfaces, Liquid–Air Interfaces

Planar
BLMs

Cells, Tissues
Ion‐Selective Electrodes for Measurements in Biological Fluids
Authors: Bakker Eric , Meyerhoff Mark E. 
Published: December 2007

Abstract
The sections in this article are

Zero‐current Electrochemical Cells Incorporating Ion‐selective Membranes

Selectivity of Potentiometric Membrane Electrodes

Glass Electrodes

Solid‐state Electrodes

Liquid Membrane Electrodes

Ion‐exchangers

Neutral Ionophores

Charged Ionophores

Gas‐sensing Probes

Ion‐selective Electrode‐based Biosensors
Electrochemical Analysis of Nucleic Acids
Authors: Paleček Emil , Fojta Miroslav , Jelen František , Vetterl Vladimír 
Published: December 2007

AbstractThe sections in this article areIntroductionHistoryNucleic Acid SamplesElectrochemical Behavior ofNAComponentsAdsorption/Desorption BehaviorMercury ElectrodesSolid ElectrodesReduction and OxidationMicroanalysis of Nucleic Acid Components by Stripping TechniquesPrinciplesReactions of Pyrimidine and Purine Bases with the Electrode MercuryUnusual Bases and NucleosidesSparingly Soluble Compounds of Nucleic Acid Components with CopperAdsorption/Desorption Behavior ofNAsMercury Dropping ElectrodeAdsorption of Double‐stranded (Native)DNAAdsorption of Single‐stranded (Denatured)DNAAdsorption Kinetics at Mercury Dropping and Hanging ElectrodesElectrochemical Impedance Spectroscopy (EIS)Other TechniquesAdsorption ofNAson Other ElectrodesDNAAdsorption to Charged Lipid MembranesReduction and Oxidation ofNAson Different ElectrodesMercury ElectrodesReduction of Adenine and Cytosine ResiduesAnodic Signal of Guanine ResiduesCarbon ElectrodesOther Solid ElectrodesAnalysis of NAs by Different Electrochemical TechniquesRelations Between Structures and Electrochemical Responses ofDNADNAStructure on Electrode SurfacesDependence of thedsDNASignals at theHMDEon Potential Scanning DirectionOpening of theDNADouble Helix Around −1.2 V(RegionU)Opening ofdsDNAat AcidpHsin a Wider Potential RangeTInteractions ofNAswith Small MoleculesReversible (Noncovalent) InteractionsInorganic Cations and Simple Metal ComplexesOrganic Metal ChelatesOther NoncovalentDNABindersCovalent InteractionsElectroactive Markers ofNAsOther Nucleic Acid ModificationsDNAConductivityApplication of Electrodes inDNAConductivity StudiesAnalytical ApplicationsSensors forDNAHybridizationImmobilization ofDNAon the ElectrodeDetection of the Hybridization EventRedox Indicators Covalently Bound toDNAIndicator‐free Detection Systems. Intrinsic Electroactivity ofDNAChanges in Interfacial Properties andDNAConductivityBlocking and Interfacing the TransducerElectrocatalytic ReactionsDetection of Point MutationsSensors forDNADamageDetection ofDNAStrand BreaksDamage toDNABasesDetection of Damaging Agents Specifically Interacting withDNADNACleavage Controlled by Electrochemical ReactionsOther DeterminationsDetermination ofssDNAin an Excess ofdsDNADetermination ofRNATraces inDNASolutionsDetermination of ProteinsConclusionAddendumAcknowledgment
Carbon Fiber Microelectrodes for the invivo Measurement of Neurotransmitters: A Close Up Look at Neurochemical Activity in the Brain
Authors: Peters Jennifer L. , Kulagina Nadezhda V. , Yang Hua , Michael Adrian C. 
Published: December 2007

AbstractThe sections in this article areIntroductionA Mathematical Description of Extracellular NeurochemistryHistology of Microelectrode and Microdialysis Probe Tracks invivoMonitoring Electrically Evoked Dopamine Release with MicroelectrodesIn vivo Electrochemistry with Very High Spatial ResolutionMonitoring Spontaneous, as Opposed to Evoked, Dopamine ReleaseElectrochemical Sensors for invivo MeasurementConclusion
Potentiometric Measurements of Proteins
Authors: Pellett Jackson , Stankovich Marian 
Published: December 2007

Abstract
The sections in this article are

Introduction

What Electrochemical Studies Can Tell Us

Direct versus Indirect Electrochemistry

Materials

Mediator Titrant

Redox Indicators

Apparatus—Glassware Components for Anaerobiosis

Argon Line

The Cell Parts: Preparation of Auxiliary, Reference, and Working Electrodes

Methods—Setting up the Mediated Electron Transfer Experiment

The Coulometric Titration

The Potentiometric Titration

Data Analysis and Sample Systems

Coulometric Titration

Potentiometric Titration
Epitaxial Electrochemical Growth
Authors: Ward Michael D. 
Published: December 2007

Abstract
The sections in this article are

Introduction

Design Approaches for Epitaxial Organic Films

The Advantages of Electrochemistry and Atomic Force Microscopy

Atomic Force Microscopy in Electrochemical Cells

Real‐time Visualization of Electrochemical Growth

Growth of Molecular Overlayers

Electrochemical Annealing of Organic Overlayers

Rules of Epitaxy for Organic Films

Epitaxial Nucleation of an Overlayer

Definitions of Epitaxy

Lattice Modeling and Prediction of Epitaxy

Nucleation of Molecular Films

Related Articles
Redox‐active Dendrimers in Solution and as Films on Surfaces
Authors: Takada Kazutake , Goldsmith Jonas I. , Bernhard Stefan , Abruña Héctor D. 
Published: December 2007

AbstractThe sections in this article areIntroductionDendrimer Properties and ApplicationsRedox‐active DendrimersDendrimers with Electroactive Moieties in the CoreDendrimers with Cores Containing Transition Metal or Organometallic ComplexesDendrimers with Cores Containing Electroactive Organic SpeciesDendrimers with Electroactive Moieties in the Branches and Throughout the MoleculeDendrimers with Transition Metal Complexes in the BranchesDendrimers with Organic Redox‐active Moieties in the BranchesDendrimers with Redox‐active Moieties at PeripheryFerrocenyl‐modified DendrimersSilicon‐based DendrimersPoly(propylenimine) DendrimersPoly(aryl ether)‐based DendrimersOther Ferrocenyl‐modified DendrimersCobaltocenyl DendrimersFerrocenyl‐ and Cobaltocenyl‐containing DendrimersRuthenium Terpyridyl and Bipyridyl DendrimersCobalt Terpyridyl DendrimersIron Terpyridyl DendrimersTetrathiafulvalenyl DendrimersViologenyl DendrimersApplicationsLight HarvestingCatalysisOrganicLEDsOxygen CarriersMolecule‐sized GatesMolecular RecognitionMediatorsBiosensors
Electron Transfer and Transport in Ordered Enzyme Layers
Authors: Anne Agnès , Demaille Christophe , Moiroux Jacques , Savéeant Jean‐Michel , Bourdillon Christian 
Published: December 2007

Abstract
The sections in this article are

Introduction

Catalytic Currents from a Redox Enzyme and a One‐electron Mediator in Solution

Derivation of the Enzyme Kinetics from Cyclic Voltammetric Experiments

Molecular Recognition of an Enzyme by Artificial One‐electron Cosubstrates?

Monomolecular Layers of Enzyme

Antigen–Antibody Construction of an Immobilized Enzyme Monolayer and Kinetic Analysis of the Enzymatic Catalytic Reaction with the Cosubstrate in Solution

Application to the Kinetic Characterization of Biomolecular Recognition

Immobilization of Both the Enzyme and the Cosubstrate

Electron Transfer and Electron Transport in Integrated Systems

Spatially Ordered Multimonomolecular Layer Enzyme Coatings

Step‐by‐step Antigen–Antibody Construction of Multimonomolecular Layer Enzyme Coatings

Reaction Dynamics with the Cosubstrate in Solution: Evidence for Spatial Order

Inhibition by products: Proton Gradients

Perspectives
Voltammetry of the Reductive Desorption of Thiol Self‐assembled Monolayers from Electrode Surface
Authors: Kakiuchi Takashi 
Published: December 2007

AbstractThe sections in this article areVoltammetry of the Reductive Desorption ofSAMs: Experimental FeaturesReductive Desorption of AlkanethiolateSAMsModeling of the Reductive Desorption ProcessesCharacteristics of Theoretical Voltammograms Based on theBHIsothermContribution of Charging CurrentReductive Desorption of BinarySAMsMiscibilityMinimum Size of the Domains that can be Recognized as an Independent DomainMutual Solubility of the ThiolatesRate of the Replacement of Adsorbed Thiolates with Thiols in the Solution PhaseRate of the Surface Chemical ReactionsElectrochemical Engineering of BinarySAMsPartial Desorption and InsertionPreparation and Use of Artificially Phase‐separated BinarySAMsWettingSurface DiffusionConclusionsAppendix
Cutaneous allodynia in the migraine population
Authors: Lipton Richard B. , Bigal Marcelo E. , Ashina Sait , Burstein Rami , Silberstein Stephen , Reed Michael L. , Serrano Daniel , Stewart Walter F. ,   American Migraine Prevalence Prevention Advisory Group
Published: December 2007

AbstractObjectiveTo develop and validate a questionnaire for assessing cutaneous allodynia (CA), and to estimate the prevalence and severity of CA in the migraine population.MethodsMigraineurs (n = 11,388) completed the Allodynia Symptom Checklist, assessing the frequency of allodynia symptoms during headache. Response options were never (0), rarely (0), less than 50% of the time (1), ≥50% of the time (2), and none (0). We used item response theory to explore how well each item discriminated CA. The relations of CA to headache features were examined.ResultsAll 12 questions had excellent item properties. The greatest discrimination occurred with CA during “taking a shower” (discrimination = 2.54), wearing a necklace (2.39) or ring (2.31), and exposure to heat (2.1) or cold (2.0). The factor analysis demonstrated three factors: thermal, mechanical static, and mechanical dynamic. Based on the psychometrics, we developed a scale distinguishing no CA (scores 0–2), mild (3–5), moderate (6–8), and severe (≥9). The prevalence of allodynia among migraineurs was 63.2%. Severe CA occurred in 20.4% of migraineurs. CA was associated with migraine defining features (eg, unilateral pain: odds ratio, 2.3; 95% confidence interval, 2.0–2.4; throbbing pain: odds ratio, 2.3; 95% confidence interval, 2.1–2.6; nausea: odds ratio, 2.3; 95% confidence interval, 2.1–2.6), as well as illness duration, attack frequency, and disability.InterpretationThe Allodynia Symptom Checklist measures overall allodynia and subtypes. CA affects 63% of migraineurs in the population and is associated with frequency, severity, disability, and associated symptoms of migraine. CA maps onto migraine biology. Ann Neurol 2007
Preparation of novel amphiphilic copolymer microspheres and their drug‐release and glucose‐sensitive properties
Authors: Tang Yu , Li Chaoxing 
Published: December 2007

AbstractA novel amphiphilic copolymer was prepared by the copolymerization of N‐acryloyl‐3‐aminophenylboronic acid with β‐cyclodextrin containing maleic anhydride. The copolymer was fully characterized with 13C‐NMR, 1H‐NMR, IR, and scanning electron microscopy. The self‐assembling mechanism of the copolymer in H2O–CH3OH cosolvents was studied. Gliclazide as a model drug was loaded inside the copolymer microspheres, and the drug‐release behavior of the microspheres was studied. The results of in vitro oscillating release tests indicated that the microspheres responded to glucose rapidly in 30 min, and the microspheres exhibited self‐regulated on–off release behavior four to six times in 6 h between the solution with 3 g/L glucose and the medium without glucose; this met the clinical requirements of multidrug delivery. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008
Ultra‐Stable Peptide Scaffolds for Protein Engineering—Synthesis and Folding of the Circular Cystine Knotted Cyclotide Cycloviolacin O2
Authors: Leta Aboye Teshome , Clark Richard J. , Craik David J. , Göransson Ulf 
Published: December 2007

AbstractThe cyclic cystine knot motif, as defined by the cyclotide peptide family, is an attractive scaffold for protein engineering. To date, however, the utilisation of this scaffold has been limited by the inability to synthesise members of the most diverse and biologically active subfamily, the bracelet cyclotides. This study describes the synthesis and first direct oxidative folding of a bracelet cyclotide—cycloviolacin O2—and thus provides an efficient method for exploring the most potent cyclic cystine knot peptides. The linear chain of cycloviolacin O2 was assembled by solid‐phase Fmoc peptide synthesis and cyclised by thioester‐mediated native chemical ligation, and the inherent difficulties of folding bracelet cyclotides were successfully overcome in a single‐step reaction. The folding pathway was characterised and was found to include predominating fully oxidised intermediates that slowly converted to the native peptide structure.