bluuebunny/crossref_metadata_2025_split huggingface dataset:
Icelandic Coastal Sea Surface Temperature Records Constructed: Putting the Pulse on Air–Sea–Climate Interactions in the Northern North Atlantic. Part I: Comparison with HadISST1 Open-Ocean Surface Temperatures and Preliminary Analysis of Long-Term Patterns and Anomalies of SSTs around Iceland
Authors: Hanna Edward , Jónsson Trausti , Ólafsson Jon , Valdimarsson Hedinn 
Published: November 2006

Abstract
A new comprehensive record of long-term Icelandic sea surface temperature measurements, which have been updated and filled in with reference to air temperature records, is presented. The new SST series reveal important features of the variability of climate in Iceland and the northern North Atlantic. This study documents site histories and possible resulting inconsistencies and biases, for example, changes in observing sites and instruments.
A new 119-yr continuous time series for north Iceland SST is presented, which should prove particularly useful for investigating air–sea ice interactions around northern Iceland. As this is the only part of the country to be regularly engulfed by winter and/or spring sea ice, it is therefore highly sensitive to climatic change. The coastal series correlate well overall with independent Hadley Centre Sea Ice and SST dataset version 1 (HadISST1) series from the adjacent open ocean (mean r = 0.59), although correlations are generally higher in summer than winter and for south and east Iceland compared with the west and north. The seasonal temperature range is generally twice as large at the coastal sites because of differential effects of radiation, melting, mixing, and advection of warmer or colder air or water masses, as well as spatial resolution differences and smoothing in HadISST1.
The long-term climatological averages and graphs for the 10 SST stations and/or their composites reveal decadal variations and trends that are generally similar to Icelandic air temperature records: a cold late-nineteenth-century, rapid warming around the 1920s, an overall warm peak circa 1940, cooling until an “icy” period circa 1970, followed by warming. Regional differences between sites include relatively greater (lesser) long-term variations for the eastern and southern (western and northern) Icelandic coasts, suggesting greater variability and influence of ocean current advection in the southeast. Moreover, Vestmannaeyjar SST data reveal that the late-nineteenth-century cold period in the ocean was not confined to the cold currents off north and east Iceland but also affected the south coast markedly. The Stykkishólmur, Iceland, SST record is relatively noisy and shows very little decadal variation, which may largely be due to fjord ice in cold winters suppressing low temperatures. It is anticipated that researchers may find these Icelandic SST series of practical use as a historic measure of air–sea–climate interactions around Iceland.
Electrofluorescence of dye-tagged sepiolite
Authors: Middleton G. W. , Jennings B. R. 
Published: November 2006

AbstractIn electric fields, anisodiametric mineral particles in suspension orientate and align. When tagged with fluorescent molecules, the alignment is accompanied by changes in the intensities of the polarized components of the emitted fluorescence. By measuring these changes under specific experimental conditions, any non-random directional coincidence of the absorption and emission transition moments associated with the dye molecules can be evaluated and the spatial array of the dyes estimated. From such measurements, the binding of the optical brightening agent FBA1, a triazinylaminostilbene compound, to sepiolite has been studied.
Clays in paleoweathering processes: study of a typical weathering profile in the Hercynian basement in the Montes de Toledo (Spain)
Authors: Vicente M. A. , Molina E. , Espejo R. 
Published: November 2006

AbstractA series of weathered Paleozoic slates was studied in an area southwest of the Montes de Toledo mountain range where the weathered slates are overlain by a raña formation and show three weathering levels. The fresh slate (at 30 m depth) is composed of ferrous chlorite, mica, quartz and feldspars. In the lowest part of the weathering profile the ferrous chlorite begins to evolve to smectite, and in the intermediate level, all the chlorite has been transformed into smectite. In the upper level (in contact with the raña formation), the smectites evolve to kaolinite, and the micas, which are unaffected at greater depths, begin to evolve to vermiculite, and there has been segregation of the free iron oxyhydroxides producing red, ochre and white zones. Two principal weathering processes, separated in time but superimposed, have been identified.
Diagenetic modification of detrital muscovite: an example from the Great Limestone Cyclothem (Carboniferous) of Co. Durham, UK
Authors: Crowley S. F. 
Published: November 2006

AbstractDiagenetically modified muscovite grains occur as a frequent component of many Upper Palaeozoic and Mesozoic fluvial-deltaic sandstones and siltstones from Britain and the North Sea. Mineralogical, textural and chemical investigation of examples from the Great Limestone Cyclothem show that such grains consist simply of muscovite and kaolinite. No other sheet-silicate phases are involved. Diagenetic textures indicate that modified grains result from the displacive growth of kaolinite between opened cleavage sheets of detrital muscovite. Fabrics of this type should consequently be termed kaolinite-cemented. In contrast to similar sheet-silicate intergrowths reported from diagenetically altered biotite and chlorite, little or no alteration of muscovite is actually required to account for observed textures.
Octahedral occupancy and the chemical composition of diagenetic (low-temperature) chlorites
Authors: Hillier S. , Velde B. 
Published: November 2006

AbstractThe chemical composition of about 500 diagenetic chlorites, determined by electron microprobe, has been studied in six different sedimentary sequences spanning conditions from early diagenesis to low-grade metamorphism, in the temperature range 40–330°C. The range of Fe/(Fe + Mg) is almost complete and is positively correlated with Al. Five sequences show the same compositional variation. In each, the most siliceous chlorites have the lowest R2+, substantially more octahedral than tetrahedral Al, and the lowest octahedral totals. Conversely, the least siliceous have the highest R2+, nearly equal octahedral and tetrahedral Al, and octahedral totals close to that for an ideal trioctahedral mineral. A dioctahedral substitution Si[]R2−2(where [] represents a vacant octahedral site) which decreases with temperature, describes this variation. Low octahedral totals are, however, induced by the method of calculation and need not indicate vacancies; for published wet chemical analyses of metamorphic chlorites they may simply indicate oxidation of Fe. Intergrown dioctahedral phyllosilicates may partly account for apparent vacancies in diagenetic chlorites. Nevertheless, the correlation of composition with temperature and similarities to the temperature-related evolution of synthetic chlorites, suggest that diagenetic chlorites are compositionally distinct from, but metastable with respect to, fully trioctahedral metamorphic chlorites. Temperature-related trends are modified by bulk composition, complicating their potential use for low-temperature geothermometry.
Relationships between authigenic mineral transformation and variation in vitrinite reflectance during diagenesis: an example from the Tertiary of northern Kyushu, Japan
Authors: Miki T. , Nakamuta Y. , Aizawa J. 
Published: November 2006

AbstractThe Tertiary sequences in northern Kyushu, Japan, contain several types of zeolite and clay minerals together with carbonaceous materials. A correlation between authigenic mineral zones and vitrinite reflectance reveals the delay in mineral authigenesis relative to the increase in vitrinite reflectance compared with similar studies in other regions. This may be ascribed to causes such as high paleogeothermal gradient, and chemical composition of pore-waters and host sediment.
K-Ar dating of authigenic illite-smectite clay material: application to complex mixtures of mixed-layer assemblages
Authors: Mossmann J.-R. 
Published: November 2006

AbstractGenetically homogeneous clay fractions are not always available for K-Ar isotopic dating of authigenic sedimentary material, particularly when dating illitic mixed-layer clay minerals. Three populations of mixed-layer clay minerals have been recognized in Upper Triassic sandstones from the Paris Basin (France), their occurrences being related to the flow of allochthonous fluids across the stratigraphic sections of the basin during Mesozoic times. A method is described for interpreting the K-Ar mixture ages obtained on carefully selected fractions, resulting in constraints being able to be made on the timing of the movements of these fluids.
Clay minerals as indicators of diagenetic and anchimetamorphic grade in an overthrust belt, External Domain of southern Canadian Appalachians
Authors: Yang C. , Hesse R. 
Published: November 2006

AbstractLower Palaeozoic shales and slates in the External Domain of the southern Canadian Appalachians are composed predominantly of illite and chlorite with minor occurrences of I-S mixed-layer minerals (restricted to samples with illite crystallinity, IC > 0·62°Δ2Θ) and paragonite (restricted to samples with IC < 0·42°Δ2Θ). Inverted diagenesis has occurred in the NW part of the Chaudière Nappe, indicating pre-orogenic deep burial diagenesis at the original depositional site, whereas to the SE, the diagenetic pattern was affected by synorogenic heating. Within the east-dipping thrust-fold belt and the St Lawrence Lowlands, increasing grade towards the S suggests a gradual southward increase in post-tectonic burial depth. Narrow (3–5 km) thermal haloes around the Cretaceous Monteregian intrusions show limited effects on the country rocks.The percentage of 2M1 mica polytypes and bo increase with decreasing IC. Chlorite crystallinity (CC) increases with increasing IC. Good correlations between IC, %2M1, CC and bo of micas indicate that these parameters are reliable monitors of high-grade diagenesis and low-grade metamorphism in clay-rich sedimentary rocks. IC and CC improve with increasing grain size, illustrating the effect of grain size on IC and CC. Organic material affects IC more strongly in strata with lower permeability than in those with higher permeability. In the diagenetic zone, glycolation does not uniformly produce a narrowing of the 10 Å illite peak, but may also broaden it by up to 15%, probably due to the presence of Kalkberg-type mixed-layers.
Disorder induced by de-intercalation of DMSO from kaolinite
Authors: Heller-Kallai L. , Huard E. , Prost R. 
Published: November 2006

AbstractDe-intercalation of DMSO from well-crystallised kaolinites induced disorder. SEM, XRD and low-temperature IR were used to probe changes in morphology, layer stacking, and the environment of OH groups, respectively. The degree and type of disorder depended on the starting material and on the method of removing the intercalate. Rapid removal by heating at 250°C caused smaller changes than more prolonged heating at lower temperature, or washing with water.
Influence of potassium concentration on the swelling and compaction of mixed (Na,K) ion-exchanged montmorillonite
Authors: Denis J. H. , Keall M. J. , Hall P. L. , Meeten G. H. 
Published: November 2006

AbstractOedometer swelling and compaction tests up to a maximum pressure of 32 bars were made on the Wyoming montmorillonite SWy-1 with a range of mixed (Na,K) exchange ion compositions. The permeabilities and water diffusivities of the compacted clays were calculated using soil physics theory. Significant inhibition of swelling from that of the Na-montmorillonite is developed for K fractions in the range 0·30 < K+ < 0·56. However, the water diffusivity increases by a factor of approximately six as the K exchange fraction increases from 0 to 0·7. Permeabilities to water flow show a power-law dependence on the void ratio e.XRD measurements at controlled humidity yield equilibrium interlayer spacings which in general increase with both increasing relative humidity and increasing Na exchange fraction. The extent of swelling is strongly inhibited in clays having Na exchange fractions of 0·44 or less, in good agreement with the oedometer studies.
Amorphous hydroxyaluminium silicates formed under physiological saline conditions, and in CaCo3-buffered solutions. Stability and significance for Alzheimer plaque precipitates
Authors: Farmer V. C. , Palmieri F. , Violante A. , Violante P. 
Published: November 2006

AbstractIn an attempt to determine the nature and conditions of formation of the aluminium silicate precipitates present at the core of senile plaque in the brains of patients with Alzheimer's disease, aluminosilicate precipitates have been prepared and equilibrated for up to one year in physiological saline conditions at 40°C and a pH near 7·4. The structure and composition of these precipitates, and the associated concentrations of free silicic acid, were similar to those found in systems buffered with CaCO3at 20–25°C. Imogolite-like products with Si : Al ratios near 0·5 were obtained at silicic acid concentrations <100µm, and hydrous feldspathoid products with ratios ≥1·0 became dominant at silicic acid concentrations greater than ∼150µm. These products do not match senile plaque precipitates, which have Si : Al ratios ≥1·0, but form in an environment with <100µmSi. The relative stability of aluminium hydroxides, proto-imogolite allophane and hydrous feldspathoids are estimated from equilibrated silicic acid concentrations.
Kerolite-stevensite mixed-layers from the Madrid Basin, Central Spain
Authors: Martin de Vidales J. L. , Pozo M. , Alia J. M. , Garcia-Navarro F. , Rull F. 
Published: November 2006

AbstractStructural features of very highly disordered 2:1 trioctahedral phyllosilicates from the Madrid Basin have been studied. Application of Fourier methods to XRD patterns shows that these materials consist of random kerolite-stevensite mixed-layered phases (R = 0) with 50–80% kerolite layers, and have a very small particle size with a mean of three unit-cells stacked in the c* direction. IR spectrum deconvolution in OH-stretching and librational modes seems to indicate five different types of water. Specific surface measurements (N2, BET) indicate anomalous high values (240–320 m2/g). These results suggest important catalytic and surface chemistry applications.
A Kaolin-smectite interstratification sequence from a red and black complex
Authors: Bühmann C. , Grubb P. L. C. 
Published: November 2006

AbstractThe sequential development of kaolin by progressive alteration of smectite, involving kaolin-smectite interstratifications as a genetic link is described from a red and black complex. Mineral compositions were studied using XRD, DTA and XRF techniques. The basalt-derived soils are situated along a 600 m transect and grade in colour from dark grey (10 YR 3/1) to red (5 YR 3/3). The kaolin proportions in the interstratification increase almost linearly with increasing reddening up to ∼80%. Whole-soil chemical analyses exhibit no significant variations in the major element composition, but dithionite extractable Fe increases along the transect from 1% to 4·16%. Hematite and goethite are the only secondary iron phases. Topographic differences are slight but sub-surface bedrock contours plus appreciable variations in sand content between red and black soils could be genetically significant.
Pressure-induced cation exchange in bentonite/laponite mixtures
Authors: Paterson E. , Clark D. R. 
Published: November 2006

AbstractExchangeable cation associations in physical mixtures of bentonite and laponite have been examined using X-ray diffraction and a combination of electron microprobe analysis and multivariate statistical methods. The results suggest that cation exchange can occur in air-dry mixtures when pressure (∼64 kbar) is applied. Although no attempt is made to describe the mechanism of the reaction it appears to require the presence of adsorbed water.
The chemical composition and structure of a 14 Å intergradient mineral in a Korean Ultisol
Authors: Wada K. , Kakuto Y. , Wilson M. A. , Hanna J. V. 
Published: November 2006

AbstractAn intergradient 14 Å mineral showing X-ray diffraction features of “chloritized” vermiculite in a Korean Ultisol was studied. The structural formula of the whole 2:1 layer-silicate (14 Å mineral and mica) in the Na+-saturated 0·2–0·5 µm fraction was obtained by elemental, thermogravimetric and 29Si and 27Al nuclear magnetic resonance spectroscopic analyses in combination with extraction of the interlayer material from the 14 Å mineral by hot 1/3 m sodium citrate treatment. This formula showed: (1) the 2 : 1 layer contains nearly one Al3+ in four tetrahedral positions, and Al3+ is the dominant cation in the octahedral sheet; (2) K+, exchangeable Na+ and sodium citrate extractable 1 : 1 layer occupy the interlayer space of the 14 Å mineral in similar proportions. Very little interlayer K was replaced by Na+ during the citrate treatment. Possible schemes of alteration of the 2 : 1 layer to the 1 : 1 layer as its interlayer material are discussed.
Thermal analysis of pyridine-treated sepiolite and palygorskite
Authors: Shuali U. , Yariv S. , Steinberg M. , Müller-Vonmoos M. , Kahr G. , Rub A. 
Published: November 2006

AbstractThe thermal behaviour of sepiolite and palygorskite treated with pyridine (Py) was investigated by DTA, TG, DTG and EGA (by MS) under a flow of air and inert gases (N2 or Ar). The thermal analysis showed that the organic base was adsorbed by the clays, penetrating into the clay pores and replacing zeolitic and bound water. Its presence in the pores shifted the dehydroxylation peak to temperatures higher than the corresponding peak in the untreated clays. Under N2 and Ar, thermal desorption of Py from sepiolite was observed at 260 and 650°C whereas for palygorskite only traces of Py were detected in the evolved gases. In addition to desorption, reactions of pyrolysis and condensation to coke were detected by the evolution of ammonia, methane and hydrogen, respectively. In air, oxidation of the organic matter led to the appearance of exothermic peaks. The profile of the DTA curve and the temperatures of the most intense exothermic peaks were determined by the rate of the carbon oxidation.
Formation of synthetic analogues of double metal-hydroxy carbonate minerals under controlled pH conditions: II. The synthesis of desautelsite
Authors: Hansen H. C. B. , Taylor R. M. 
Published: November 2006

AbstractDesautelsite, a Mg(II)Mn(III) hydroxy carbonate first described in 1979 and represented by the general formula Mg(8−x)Mn(III)x(OH)16(CO3)x/2(in which 2 <x< 2·67), has been synthesized under controlled pH conditions (induced hydrolysis) and coprecipitation techniques. In the pH-stat syntheses, the desautelsite is formed by aerial oxidation of MnCO3in 0·05–0·15mMg(NO3)2solutions at ∼pH 9 and temperatures of 35°C where, in the absence of Mg, manganite would normally form. The synthesis product from this technique is generally more crystalline than that formed by the coprecipitation method. Composition, particle shape and aggregation may be controlled through variations of the Mg concentration, pH, aeration rate or temperature. Indirect evidence suggests Mn to be present in the +3 oxidation state in the desautelsite.
Ultra Microanalysis of Ferric Ion Using Triazene and Capillary Electrophoresis
Authors: Nishiwaki Keiji , Taga Atsushi , Yamaya Masako , Morita Yusuke , Suzuki Yukiko , Honda Susumu , Matsuo Keizo 
Published: November 2006

Abstract
The triazene compound {2,2′-[3-(4-methoxyphenyl)triaz-2-ene-1,1-diyl]diethanol} was utilized for the high sensitive and quantitative detection of ferric ion.
Electrically Detected Magnetic Resonance (EDMR) Measurements of Bulk Silicon Carbide (SiC) Crystals
Authors: Sato Toshiyuki , Yokoyama Hidekatsu , Ohya Hiroaki 
Published: November 2006

Abstract
Electrically detected magnetic resonance (EDMR) measurements of bulk silicon carbide (SiC) crystals, which have wide band-gaps, were conducted. A high-power ultraviolet light-emitting diode was used as a low-noise light source to excite excessive carriers. Under light irradiation, EDMR spectra of a 4H–SiC wafer (8-mm wide, 8-mm long) at an ESR frequency of 900 MHz was obtained with a g-value of 2.000 ± 0.003, indicating that the major recombination center was a vacancy. EDMR spectra were observed at all detection phases of magnetic field modulation. The spectrum observed at in-phase (0 degrees) was a single line; at out-of-phase (90 degrees), the different spectrum was observed.
Asymptotic analysis of the Askey-scheme I: from Krawtchouk to Charlier
Authors: Dominici Diego 
Published: November 2006

Abstract
We analyze the Charlier polynomials C
n(χ) and their zeros asymptotically as n → ∞. We obtain asymptotic approximations, using the limit relation between the Krawtchouk and Charlier polynomials, involving some special functions. We give numerical examples showing the accuracy of our formulas.
Comparison of serological and clinical findings in Turkish patients with cystic echinococcosis
Authors: Yolasigmaz A. , Reiterová K. , Turk M. , Reyhan E. , Bozdag A. , Karababa A. , Altintas Nuray , Altintas Nasmiye 
Published: November 2006

Abstract
Cystic echinococcosis (CE), caused by the cestode Echinococcus granulosus, is potentially dangerous for humans. The aim of this study was to examine serological and clinical findings regarding cysts localisation and individual responses in 54 patients with CE. The majority of patients in this study were females (63 %) and the average age was 46.3 years. Most of the patients lived in rural areas or kept a dog (46 %) for a long time. The most frequent symptoms were hypochondrial pain (48.9 %), epigastrial discomfort (27.7 %), vomiting (21.3 %), minor cough (12.8 %), urticaria (6.3 %), weakness (4.3 %), fever (2.1 %), side-or back-ache (4.3 %). However, 17 % of the patients showed no symptoms. In every case, the ultrasound (USG) and/or computer tomography (CT) investigations were positive. In most cases (53.2 % of the patients) a single cyst was found but 46.8 % of the patients had multiple cyst formations (from 2 to 9 cysts) located in the liver. Sporadic lung, splenetic, mesenterial, tibial and cerebral localisations were also found. The patients were individually treated with albendazol (10–15 mg/kg) five days prior and six months after the surgical treatment. Serum samples were investigated by the serological techniques: IHAT, ELISA and Western blot using hydatid fluid antigen. In the patient sera, the specific antibody levels were mostly increased after surgery. Different results were obtained only in two patients. In the first case, seroconversion was delayed. In the other case all ELISA results were negative, however, the Western blot analysis and surgery proved the presence of CE. The results suggest that the different antibody response of patients depends on the individual immune response. Multiple localization and various stages of CE cysts demonstrate the necessity of a complex approach for the confirmation of a correct diagnosis.