bluuebunny/crossref_metadata_2025_split huggingface dataset:
Xocomecatlite, Cu3TeO4(OH)4, and tlalocite, Cu10Zn6(TeO3)(TeO4)2Cl(OH)25·27H2O, two new minerals from Moctezuma, Sonora, Mexico
Authors: Williams S. A. 
Published: December 2006

SummaryXocomecatlite and tlalocite were found at the Bambollita mine near Moctezuma, Sonora. Xocomecatlite is probably orthorhombic, and an indexed cell based on the powder data gave a 12.140 A, b 14.318, c 11.662. Based on this cell, the empirical contents are Cu36.6 Zn1.7 (TeO4)12.5 (OH)51.6 or Cu3TeO4(OH)4. Tellurate was found both microchemically and by spectrophotometry. Colour rich green (R.H.S. 132A) with pale streak, H = 4. Optically negative with α = 1.775, β = 1.900, γ = 1.920. G = 4.65.Tlalocite is optically orthorhombic but the cell could not be indexed; only powder data are presented. Chemical analysis showed both tellurite and tellurate and led to the formulaColour pale blue (R.H.S. 121A) with a whitish streak; H = 1, gummy and sectile. G = 4.55.Plotting stability fields for various Te species at 25°C in terms of Eh and pH showed that TeO42−.aq can exist in nature over a wide pH range, but only under extreme conditions of oxidation.
Thermal transformation of lepidomelane
Authors: Akizuki Mizuhiko , Konno Hiroshi , Yamauchi Noriyoshi , Sunagawa Ichiro 
Published: December 2006

SummaryLepidomelane, an iron-rich biotite, was heated in air or in vacuum, or by electron bombardment, and the processes of dehydration and transformation were studied by means of X-ray diffractometry, optical microscopy, and electron microscopy. By heat treatment, vacancies are at first formed by the evaporation of water molecules and alkali ions, and they move and condense to form holes, which act as preferential nucleation sites for new phases. Other preferential sites are edges of exposed silicate sheets along microcracks, and these are decorated by a newly formed maghemite- like mineral whose a is 10.20 Å (on a hexagonal cell), so that the sites can be clearly seen even under the reflection microscope. By heating at higher temperatures or prolonged heating, various phases, olivine, hematite, magnetite, and leucite are formed, depending upon the conditions of dehydration.
The phosphate mineralogy of et-Tabun cave, Mount Carmel, Israel
Authors: Goldberg P. S. , Nathan Y. 
Published: December 2006

SummaryPhosphates introduced into the et-Tabun cave as a result of human habitation, mainly as bone material, were partly dissolved by slightly acid solutions (organic acids derived from human or other animal activity). From these solutions, dahllite precipitated when the solutions came into contact with calcite. In the more weathered parts of the section, where little or no calcite occurs, the phosphate minerals formed are montgomeryite and crandallite.
Geochemical indicator of the efficiency of fractionation of the Skaergaard intrusion, East Greenland
Authors: Henderson Paul 
Published: December 2006

SummaryWhen magmatic fractionation involves the settling and removal of crystals from the body of magma, the efficiency of the fraetionation process may be defined as the degree of separation of the solid from the liquid phase. An expression is given that relates efficiency to the amount of mesostasis, or crystallized trapped liquid, in an igneous cumulate. The uranium contents of samples from a 349-m-long drill-core of part of the lower and hidden zones of the Skaergaard intrusion are used as a quantitative indicator of the amounts of mesostasis in the cumulates. There are marked changes in the amount of mesostasis over the length of the core and the average efficiency of fractionation was 85 %.
Microstructural interpretation of some fibrolitic sillimanite aggregates
Authors: Vernon R. H. 
Published: December 2006

SummaryFibrolitic sillimanite in some high-grade gneisses from Broken Hill, Australia, shows microstructural features suggestive of compatibility with the main coarser-grained assemblage, namely: framework-silicate interfaces either meet (110)-sillimanite/framework-silicate interfaces at approximately 90° or are attached to the ends of 'fibrolite' rods; framework-silicate interfaces are deflected by 'fibrolite' grains; and interfaces of inclusions of one framework silicate in another are deflected by 'fibrolite' grains, producing irregular, rather than rounded, inclusion shapes. These criteria suggest that the 'fibrolite' in some rocks is a compatible member of the main metamorphic assemblage. Its persistence as small grains may be due to a high proportion of relatively low-energy prismatic boundaries in the fibrolitic aggregates.
Clinopyroxenes and biotites from the Centre III igneous complex, Ardnamurchan, Argyllshire
Authors: Walsh J. N. 
Published: December 2006

SummaryMajor- and trace-element analyses of the clinopyroxenes and biotites from the ring-intrusions of Centre III in the Tertiary igneous complex of Ardnamurchan are presented. It is shown that there are systematic differences in mineral chemistry between the eucrites, the gabbros, and the dolerites, and in particular the clinopyroxenes show an iron enrichment trend that is similar to that found in fractionated tholeiitic intrusions. The minerals from the intcrmediate rocks, the tonalite and quartz monzonite in the centre of the complex, do not show the further iron enrichment expected if these rocks had formed by continued fractionation of basic magma. On the basis of the chemistry of the clinopyroxenes and biotites, the intermediate rocks are interpreted as hybrids formed by the remelting and assimilation of country rocks into basic magma.
The crystal structure of galeite, Na15(SO4)5F4Cl
Authors: Fanfani L. , Nunzi A. , Zanazzi P. F. , Zanzari A. R. 
Published: December 2006

SummaryThe crystal structure of galeite from Searles Lake (California) has been determined by means of X-ray diffraction data on a single crystal. A possible structure was derived from that of schairerite on the basis of chemical and lattice analogies and was confirmed by comparison of the observed diffractometric structure factors with the calculated ones. The refinement was performed by least-squares methods employing isotropic thermal parameters and assuming that atoms related by translational pseudosymmetry exhibit equal thermal parameters. The final R value is 0·09. The cell content is 3[Na15(SO4)5F4Cl]; the space group is P31m The lattice dimensions are a 12·197(4)Å, c 13·955(10) Å The marked subcell has P3m1 symmetry and a 7·042Å, c 13·955 Å. The crystal structure of galeite consists of a three-dimensional framework, formed by coordination octahedra around Na+ ions, including tetrahedral holes with sulphur atoms at the centres. The three-dimensional framework can be considered built up by five octahedral sheets (seven sheets can be recognized in schairerite and six in sulphohalite). The very close analogies occurring in the structures of galeite and schairerite are discussed.
Base metal enrichment in volcanic sublimates and secondary alteration products from Vesuvius and Vulcano
Authors: Angus J. G. , Davis G. R. 
Published: December 2006

SummaryA wide range of volcanic sublimates and alteration products from the Johnston-Lavis collection has been analysed for major elements plus copper, lead, and zinc. 'Aphthitalite' and 'natrikalite' from Mount Vesuvius and an 'alum' from the island of Vulcano all proved to be enriched in copper and selected analyses are tabulated. The process leading to copper and lead enrichment of the Vesuvian material may be vapour phase transport as chloride followed by sulphation on sublimation. It is suggested that the source of the copper found in the alum sample from Vulcano could be of interest to economic geologists.
Effect of pressure on reversible solid-solid transitions in nepheline and carnegieite
Authors: Cohen Lewis H. , Klement William 
Published: December 2006

SummaryDifferential thermal analysis of a rapidly reversible transition in carnegieite to 7 kbar shows the transition temperature increases from ⪝ 707°C (on heating) at I bar with initial slope ≈ 8·0 deg kbar−1 and anomalous curvature (d2T/dp2 > o), with hysteresis between heating and cooling signals that decreases with pressure. DTA of rapidly reversible transitions in nepheline shows the very subtle transition near 185°C (on heating) at 1 bar decreases with pressure to ≈ 170°C near 2-3 kbar and hardly varies in temperature up to 6 kbar; and the higher temperature transition increases from ≈ 872°C (on heating) at 1 bar with slope ≈ 25 deg kbar−1, to 5 kbar, with the hysteretic interval remaining essentially unchanged in the investigated range.
A metamorphosed, layered alpine-type peridotite in the Langavat Valley, South Harris, Outer Hebrides
Authors: Livingstone A. 
Published: December 2006

SummaryA layered aipine-type peridotite, of pre-Scourian age(?), has been metamorphosed in the granulite facies then partially retrogressed to greenschist facies assemblages. Following granulite facies metamorphism of the dunite-harzburgite peridotite, granitization and metasomatism modified the peridotite by adding calcium and generated olivine-tremolite rocks. Anthophyllite-rich rocks developed from localized orthopyroxene-rich zones. The main epoch of serpentinization followed after tremolite formation and removed a portion of the calcium previously added, but with negligible effect upon the original trace-element content. Between tremolite generation and the main period of serpentinization greenschist facies assemblages formed. The layered rocks possess a repetitive, chemical variation normally attributable to basic igneous processes, although they may have formed either by vein metasomatism or by metasomatism of a disrupted layered igneous series. Twelve rock and five mineral analyses are presented, and trace element data for twenty-one rocks.
Clinoptilolite from zeolitized tuffs of Azerbaidzhan
Authors: Kashkai M.-A. , Babaev I. A. 
Published: December 2006

SummaryA study has been made of a large clinoptilolite deposit in the Lesser Caucasus (Azerbaidzhan SSR). The geological conditions have been examined and a number of samples investigated by optical, electron-microscopic, chemical, X-ray, thermal, and infra-red methods. Based on these investigations and on comparison with previous literature, mineralogical, chemical, and geochemical conclusions are drawn and conditions for clinoptilolite genesis are considered.
The Mössbauer spectrum of a ferrian muscovite and its implications in the assignment of sites in dioctahedral micas
Authors: Goodman B. A. 
Published: December 2006

SummaryA muscovite that contains iron almost entirely in the ferric form has been studied by M6ssbauer spectroscopy. It is established that Fe3+ ions in the sites with cis hydroxyl groups have similar parameters in both muscovite and biotite. By assuming that Fe2+ ions will also have similar parameters for these sites in both minerals the M6ssbauer results of other workers have been reinterpreted. This new interpretation, which is in complete agreement with the X-ray structural analysis of Radoslovich (1960), indicates that in muscovite the sites with cis hydroxyl groups are filled in preference to those with trans hydroxyls. These sites are occupied primarily by trivalent ions. There is possibly a preference for divalent ions by the unique sites with trans hydroxyl groups, but occupation of these sites appears to occur only when the other sites have been filled.
The geochemistry of 'charnockites' and their constituent ferromagnesian minerals from the Precambrian of south-east Sri Lanka (Ceylon)
Authors: Jayawardena D. E. De S. , Carswell D. A. 
Published: December 2006

SummaryA chemical and petrographic study of charnockites and pyroxene/hornblende-bearing granulites has been undertaken, and the data used in an interpretation of the petrogenesis of these rocks. Major- and trace-element analyses of fourteen rocks are presented, together with majorelement analyses of seven orthopyroxenes, seven clinopyroxenes, two garnets, and three hornblendes. The compositions of the coexisting ferromagnesian minerals are used to obtain estimates of the likely pressure/temperature conditions of equilibration (5-7 kbar and 700±50°C of the various mineral assemblages.
A model for trace-element distribution in silicate structures
Authors: Iiyama J. T. , Volfinger M. 
Published: December 2006

SummaryThis paper presents an extended version of the local lattice deformation model of solid solutions (J. T. Iiyama, 1974b). It has been assumed previously that a foreign atom fixed in a crystal causes local lattice deformation, which prevents another foreign atom from occupying the deformed zone. The resulting entropy of the solid solution from this model can explain the particular behaviour of ion-exchange reactions observed with alkali and alkali-earth elements in feldspars and in muscovite. The present version assumes that the deformed zone does not prohibit foreign atoms, but that the number of foreign atoms acceptable in this region depends on the total numbers of foreign atoms already fixed in the crystal. The model is applied successfully to explain ion-exchange isotherms observed with Cs, Na, and Li in micas and permits an estimation of the apparent reaction constant of the ion exchange. This is otherwise impossible because of the lack of ideal dilute-solution behaviour in exchange isotherms even at the IO ppm range of the foreign element fixed into the crystal. It is demonstrated that the model can explain the particular behaviour of Li in sanidine.
The progressive crystallization and ordering of low-temperature dolomites
Authors: Schneider Hartmut 
Published: December 2006

SummaryThe progressive crystallization of dolomite has been investigated in the temperature range of 90 to 410°C by means of X-ray powder diffraction, electron microscopy, and infra-red spectroscopy.Short-time, low-temperature experiments (≤ 145°C yielded dolomites with a high defect density. In detail, lattice faults can be described as: Random succession of more or less ordered cation domains, producing a long-range mosaic-type disorder; cation ordering may take place along <101̄0> and <112̄0> tilting and dislocation of individual CO3 groups; and irregular interstratification of dolomite layers of different chemical compositions in the crystallographic c-directions.Dolomites produced in experiments of longer duration are composed of an interstratification of essentially two chemically different dolomite layers, of which the stacking sequence is more perfect than it is at lower crystallization degrees. Both components grow rapidly at the expense of dolomites of intermediate composition. Finally, long-term low-temperature (145°C) experiments produced two independent, coexistent dolomite phases. Within single dolomite layers cations now lie very close to their theoretical positions. CO3-tilting and dislocation decreases markedly.Hydrothermal runs at temperatures > c. 145°C yielded one single, nearly stoichiometrie, highly ordered dolomite phase. Finally, dolomites synthesized at temperatures > c. 200°C are of an ideal chemical composition and have perfect lattice ordering.
Petrogenetic significance of some new xenolithic alkaline rocks from East Africa
Authors: Rock N. M. S. 
Published: December 2006

SummaryNew occurrences of xenolithic alkaline rocks from three East African volcanoes are described. Micro-ijolites and alkali pyroxenites occur in the carbonate-rich tufts and lavas of Mount Elgon; kaersutite-rich pyroxenites and a suite of fenitized basement rocks in the caldera flows of Mount Meru, and apparently unique melanocratic hortonolite nepheline syenites in the central foyaite plug of Mount Kenya. The 87Sr/86Sr ratios indicate mantle origin, and all are enriched in trace elements such as Sr, Nb, and Zr. The xenoliths from Mount Kenya are cumulate equivalents of the glassy kenyte lavas of the mountain; the pyroxenites of Mount Elgon are also cumulates whose predominant titanaugite is of identical composition to that of the host lavas. The contrast between the 'dry' Elgon pyroxenites and the 'wet' amphibole-rich types from Mount Meru is believed to reflect different CO2/H2O ratios in the volatile phase accompanying the alkaline vulcanicity. Strongly alkaline, carbonate-rich suites such as that of Mount Elgon derive from fairly dry alkali-basaltic magma under high CO2 activity by dominant pyroxene fractionation, whereas the mildly alkaline lineage seen in some areas of Mount Meru forms under more hydrous conditions in which amphibole fractionation is important. Mount Meru in addition shows a transition to rock-types typical of the strongly alkaline lineage, and this is reflected in the occurrence of relatively amphibole-poor pyroxenites with the amphibole-rich types.
Genthelvite and the helvine group
Authors: Dunn Pete J. 
Published: December 2006

SummaryA plot of seventy-five new analyses of members of the helvine group and fifty-seven analyses from the literature indicates complete miscibility between the Fe and Zn members (danalite and helvine) and between the Fe and Mn members (danalite and genthelvite). The new analyses include essentially pure helvine and genthelvite (for both of which X-ray data are presented) and the nearest approach to pure danalite (86 at. % Fe). Two new localities for genthelvite, the rarest member, are reported.
Petrogenesis of migmatites in the Huntly-Portsoy area, north-east Scotland
Authors: Ashworth J. R. 
Published: December 2006

SummaryMigmatites are described from the Sillimanite-potash-feldspar Zone of the aureole around the Newer Basic suite of synorogenic intrusions. The lowest-grade migmatites are trondhjemitoid (characterized by the assemblage quartz-plagioclase-biotite) or muscovite-granitoid (quartz-plagioclase potash-feldspar-muscovite-sillimanite-biotite). With increasing grade, a transition occurs to cordierite-granitoid assemblages (quartz-plagioclase-potash-feldspar-cordierite-garnet-sillimanite-biotite), which persist to the highest grades observed, where there are also noritoid migmatites (quartz-plagioclase-orthopyroxene-cordierite-biotite). The trondhjemitoids are texturally simple because the minerals did not undergo dehydration reactions. Textural immaturity and consistently cotectic modal compositions indicate that their leucosomes originated as melts. Scatter of plagioclase compositions suggests that the partial melting occurred in small closed systems. The other migmatites have more fusible compositions, so it is deduced that they also underwent partial melting. Retrograde reaction textures are used to infer the sequence of reactions, involving muscovite and biotite, by which melting proceeded during prograde evolution. Whereas the fugacity of water probably varied among spatially associated trondhjemitoid leucosomes, in the muscovite-granitoids it was constrained to an approximately constant value, at given pressure and temperature, by the buffering effect of the mineral assemblage.
Distinct cooling histories of troctolites from the Freetown layered gabbro
Authors: Bowles John F. W. 
Published: December 2006

SummaryThe iron-titanium oxide minerals of three troctolites from the Freetown layered gabbro have been analysed using an electron microprobe. Comparisons of the analyses of the iron-titanium minerals with the data of Buddington and Lindsley (1964) provide temperature and oxygen fugacity information relating to particular magnetite-ilmenite grains. Magnetite-ilmenite grains occurring in different silicate environments within any one single troctolite rock have equilibrated at differing times in the cooling history of that rock and this enables part of that history to be established. The partial cooling histories established for the three specimens can be clearly distinguished, and are strongly influenced by the appropriate buffer reactions.
Narsarsukite: a new occurrence in peralkaline trachyte, south Greenland
Authors: Upton B. G. J. , Macdonald R. , Hill P. G. , Jefferies B. , Ford C. E. 
Published: December 2006

SummaryA flinty, spherulitic dyke of peralkaiine trachyte in a Precambrian dyke-swarm consists mainly of albite and aegirine. Within this, euhedral crystals of narsarsukite, Na2(Ti,Fe)Si4O10(F), occur as short prisms elongate parallel toc. This distinguishes them from all previously described narsarsukites, which have tabular habits. Minor phases present include micas, apatite, quartz, pectolite, nordite, and a thorium silicate. Probe analyses are presented for narsarsukite, aegirine, aibite, biotite, apatite, pectolite, nordite, and the thorium silicate.On mineralogical and geochemical grounds it is unlikely that the narsarsukite-bearing dyke is a differentiate of supposedly mantle-derived basalt-trachyte-comendite magmas in the region. The dyke is colinear with a comendite dyke exposed at lower altitude and it is suggested that the narsarsukite- bearing dyke developed as a rhcomorphic fenite generated by reaction between quartz diorite basement and fugitive alkaline solutions from the subjacent comendite.
Lithium tourmalines from the Meldon aplite, Devonshire, England
Authors: Chaudhry M. N. , Howie R. A. 
Published: December 2006

SummarySeven chemical analyses of pink or green tourmalines belonging to the elbalte-schorl series, along with their physical, optical, and X-ray data are presented. Linear variation diagrams showing the relationship between composition and refractive indices, specific gravities, and cell parameters are constructed. Relationship between colour and chemical composition is also discussed.
The chemical evolution of glauconite pellets as seen by microprobe determinations
Authors: Velde B. 
Published: December 2006

SummarySeven samples of pelletat glauconites with varying iron and potassium contents were investigated using the electron microprobe. In-sample variation of pelletal compositions is quite important, even for samples previously separated according to grain-size, density, and magnetic susceptibility. This observation should lead to a reconsideration of previous work based upon multigrain samples.During the evolution of pelletal material towards micaceous glauconite compositions it is apparent that iron can be added to as wellas subtracted from the bulk pelletal composition. This transfer appears to be effected when the pellet contains a multiphase mineral assemblage as well as during the evolution of a single-phase mixed layered mineral.A schematic phase diagram is presented which attempts to describe the phase changes as a function of K, Si, and Fe variables.
Mineralogy and petrology of some Tertiary leucite-rhönite basanites from central France
Authors: Magonthier M. C. , Velde D. 
Published: December 2006

SummaryThe composition of the various phases present in the rh6nite-bearing leucite basanites of the southern part of the Sillon Houiller district have been determined with the electron microprobe. Clinopyroxenes show strong progressive enrichment in Al2O3 and TiO2, maximum values being 13 % and 6 % respectively. These extreme compositions are comparable to others found in feldspathoidal lavas from other provinces, and can be explained by the low silica content of the liquids they crystallized from, and high cooling-rates. Rhönite composition is similar to those previously determined in various terrestrial occurrences. The chemical compositions of the lavas differ from those of basanites, and are intermediate as far as Ca, Al, and Si contents between basanites and melilite-bearing basic lavas. The presence of rhönite can be explained by bulk composition, but is not a consequence of a particularly high Fe and/or Ti content. Xenoliths are absent from these lavas, so that there is no petrographic indication of possible contamination. It is tentatively concluded that the high K/Na ratio is primary.