bluuebunny/crossref_metadata_2025_split huggingface dataset:
Super‐Ionic Conductor Soft Filler Promotes Li+ Transport in Integrated Cathode–Electrolyte for Solid‐State Battery at Room Temperature
Authors: Yang Binbin , Deng Chenglong , Chen Nan , Zhang Fengling , Hu Kaikai , Gui Boshun , Zhao Liyuan , Wu Feng , Chen Renjie 
Published: April 2024

AbstractComposite polymer solid electrolytes (CPEs), possessing good rigid flexible, are expected to be used in solid‐state lithium‐metal batteries. The integration of fillers into polymer matrices emerges as a dominant strategy to improve Li+ transport and form a Li+‐conducting electrode–electrolyte interface. However, challenges arise as traditional fillers: 1) inorganic fillers, characterized by high interfacial energy, induce agglomeration; 2) organic fillers, with elevated crystallinity, impede intrinsic ionic conductivity, both severely hindering Li+ migration. Here, a concept of super‐ionic conductor soft filler, utilizing a Li+ conductivity nanocellulose (Li‐NC) as a model, is introduced which exhibits super‐ionic conductivity. Li‐NC anchors anions, and enhances Li+ transport speed, and assists in the integration of cathode–electrolyte electrodes for room temperature solid‐state batteries. The tough dual‐channel Li+ transport electrolyte (TDCT) with Li‐NC and polyvinylidene fluoride (PVDF) demonstrates a high Li+ transfer number (0.79) due to the synergistic coordination mechanism in Li+ transport. Integrated electrodes’ design enables stable performance in LiNi0.5Co0.2Mn0.3O2|Li cells, with 720 cycles at 0.5 C, and 88.8% capacity retention. Furthermore, the lifespan of Li|TDCT|Li cells over 4000 h and Li‐rich Li1.2Ni0.13Co0.13Mn0.54O2|Li cells exhibits excellent performance, proving the practical application potential of soft filler for high energy density solid‐state lithium‐metal batteries at room temperature.
Smart Solid‐State Interphases Enable High‐Safety and High‐Energy Practical Lithium Batteries
Authors: Wu Yu , Liu Yuan , Feng Xuning , Ma Zhuang , Xu Xiaodong , Ren Dongsheng , Han Xuebing , Li Yalun , Lu Languang , Wang Li , He Xiangming , Ouyang Minggao 
Published: April 2024

AbstractWith the electrochemical performance of batteries approaching the bottleneck gradually, it is increasingly urgent to solve the safety issue. Herein, all‐in‐one strategy is ingeniously developed to design smart, safe, and simple (3S) practical pouch‐type LiNi0.8Co0.1Mn0.1O2||Graphite@SiO (NCM811||Gr@SiO) cell, taking full advantage of liquid and solid‐state electrolytes. Even under the harsh thermal abuse and high voltage condition (100 °C, 3–4.5 V), the pouch‐type 3S NCM811||Gr@SiO cell can present superior capacity retention of 84.6% after 250 cycles (based pouch cell: 47.8% after 250 cycles). More surprisingly, the designed 3S NCM811||Gr@SiO cell can efficiently improve self‐generated heat T1 by 45 °C, increase TR triggering temperature T2 by 40 °C, and decrease the TR highest T3 by 118 °C. These superior electrochemical and safety performances of practical 3S pouch‐type cells are attributed to the robust and stable anion‐induced electrode‐electrolyte interphases and local solid‐state electrolyte protection layer. All the fundamental findings break the conventional battery design guidelines and open up a new direction to develop practical high‐performance batteries.
Work‐related asthma prevalence among US employed adults
Authors: Syamlal Girija , Dodd Katelynn E. , Mazurek Jacek M. 
Published: April 2024

AbstractBackgroundWork‐related asthma (WRA), a preventable occupational disease, can result in adverse health outcomes and employment disability, including decreased productivity, lost workdays, and job loss. Early identification of WRA cases and avoidance of further exposures is crucial for optimal management.ObjectiveWe estimate WRA prevalence among US workers by selected sociodemographic characteristics, industry, and occupation groups and assess the differences in adverse health outcomes, preventive care, and lost workdays between persons with WRA and those with non‐WRA.MethodsThe 2020 National Health Interview Survey (NHIS) data for working adults aged ≥18 years employed in the 12 months before the survey were analyzed. Prevalence, and adjusted prevalence ratios with 95% confidence intervals were estimated using multivariate logistic regression.ResultsOf the estimated 170 million US adults working in the past year, 13.0 million (7.6%) had asthma. Among workers with asthma, an estimated 896,000 (6.9%) had WRA. WRA prevalence was highest among males, workers aged ≥55 years, those with no health insurance, those living in the Midwest, and those employed in the accommodation, food, and other services industry, and in production, installation, transportation, and material moving occupations. Workers with WRA were significantly more likely to use preventive medication and rescue inhalers, and to experience adverse health outcomes and lost workdays than workers with non‐WRA.ConclusionEarly identification of WRA cases, assessment of workplace exposures, and implementation of targeted interventions that consider the hierarchy of controls are critical to preventing future WRA cases and associated adverse health consequences.
Biopolymer‐based intelligent packaging integrated with natural colourimetric sensors for food safety and sustainability
Authors: Chiu Ivy , Yang Tianxi 
Published: April 2024

AbstractIncreasing concerns about global food safety and security demands innovative solutions, particularly in food packaging technologies. This review paper investigates the advanced integration of natural colourimetric sensors with biopolymer‐based packaging materials, with a focus on developments over the past 5 years. These sensors change colour in response to environmental stimuli such as oxygen, temperature, pH and relative humidity, intuitively indicating food freshness and safety. The paper emphasizes the recent advancements in using natural colourants, such as alizarin, anthocyanins, betacyanins, chlorophyll, curcumin and shikonin. When combined with either natural or synthetic biopolymers, these colourants contribute to a sustainable and eco‐friendly approach to food packaging. Such technological advances could notably decrease the incidence of foodborne illnesses by signaling potential spoilage or contamination, while also addressing food wastage by providing clear indications of edibility. Although challenges remain in sensor longevity and widespread adoption, the prospects for biopolymer‐based food packaging with embedded natural colourimetric sensors are promising.
Icariin alleviates renal inflammation and tubulointerstitial fibrosis via Nrf2‐mediated attenuation of mitochondrial damage
Authors: Ding Nannan , Sun Shanyue , Zhou Shuting , Lv Zhimei , Wang Rong 
Published: April 2024

AbstractTubulointerstitial fibrosis is an inevitable consequence of all progressive chronic kidney disease (CKD) and contributes to a substantial health burden worldwide. Icariin, an active flavonoid glycoside obtained from Epimedium species, exerts potential antifibrotic effect. The study aimed to explore the protective effects of icariin against tubulointerstitial fibrosis in unilateral ureteral obstruction (UUO)‐induced CKD mice and TGF‐β1‐treated HK‐2 cells, and furthermore, to elucidate the underlying mechanisms. The results demonstrated that icariin significantly improved renal function, alleviated tubular injuries, and reduced fibrotic lesions in UUO mice. Furthermore, icariin suppressed renal inflammation, reduced oxidative stress as evidenced by elevated superoxide dismutase activity and decreased malondialdehyde level. Additionally, TOMM20 immunofluorescence staining and transmission electron microscope revealed that mitochondrial mass and morphology of tubular epithelial cells in UUO mice was restored by icariin. In HK‐2 cells treated with TGF‐β1, icariin markedly decreased profibrotic proteins expression, inhibited inflammatory factors, and protected mitochondria along with preserving mitochondrial morphology, reducing reactive oxygen species (ROS) and mitochondrial ROS (mtROS) overproduction, and preserving membrane potential. Further investigations demonstrated that icariin could activate nuclear factor erythroid 2‐related factor 2 (Nrf2)/heme oxygenase‐1 (HO‐1) pathway both in vivo and in vitro, whereas inhibition of Nrf2 by ML385 counteracted the protective effects of icariin on TGF‐β1‐induced HK‐2 cells. In conclusion, icariin protects against renal inflammation and tubulointerstitial fibrosis at least partly through Nrf2‐mediated attenuation of mitochondrial dysfunction, which suggests that icariin could be developed as a promising therapeutic candidate for the treatment of CKD.
A narrative review on therapeutic potential of naringenin in colorectal cancer: Focusing on molecular and biochemical processes
Authors: Zamanian Mohammad Yasin , Golmohammadi Maryam , Abdullaev Bekhzod , García María Olalla , Alazbjee Adeeb Abdulally Abdulhussien , Kumar Abhinav , Mohaamed Sameer S. , Hussien Beneen M. , Khalaj Fattaneh , Hodaei Seyede Mahsa , Shirsalimi Niyousha , Moriasi Gervason 
Published: April 2024

AbstractColorectal cancer (CRC) is a common and highly metastatic cancer affecting people worldwide. Drug resistance and unwanted side effects are some of the limitations of current treatments for CRC. Naringenin (NAR) is a naturally occurring compound found in abundance in various citrus fruits such as oranges, grapefruits, and tomatoes. It possesses a diverse range of pharmacological and biological properties that are beneficial for human health. Numerous studies have highlighted its antioxidant, anticancer, and anti‐inflammatory activities, making it a subject of interest in scientific research. This review provides a comprehensive overview of the effects of NAR on CRC. The study's findings indicated that NAR: (1) interacts with estrogen receptors, (2) regulates the expression of genes related to the p53 signaling pathway, (3) promotes apoptosis by increasing the expression of proapoptotic genes (Bax, caspase9, and p53) and downregulation of the antiapoptotic gene Bcl2, (4) inhibits the activity of enzymes involved in cell survival and proliferation, (5) decreases cyclin D1 levels, (6) reduces the expression of cyclin‐dependent kinases (Cdk4, Cdk6, and Cdk7) and antiapoptotic genes (Bcl2, x‐IAP, and c‐IAP‐2) in CRC cells. In vitro CDK2 binding assay was also performed, showing that the NAR derivatives had better inhibitory activities on CDK2 than NAR. Based on the findings of this study, NAR is a potential therapeutic agent for CRC. Additional pharmacology and pharmacokinetics studies are required to fully elucidate the mechanisms of action of NAR and establish the most suitable dose for subsequent clinical investigations.
Tracking the Dimensionality Transition from a Three Dimensional Single Crystal to a Two Dimensional Perovskite
Authors: Cohen Idan , Wierzbowska Małgorzata , Aizenshtein Ben , Etgar Lioz 
Published: April 2024

AbstractThis work carefully studied the transition from 3D perovskite to 2D perovskite. Our system includes single crystals (SCs) of MAPbBr3, which were dipped in a solution of barrier molecules. Three monoammonium cations and one di‐ammonium cation were studied. Absorbance and cathodoluminescence were used to follow the formation of low‐dimensional perovskite on the SC surface. Quantitative nuclear magnetic resonance and scanning electron microscopy assist in quantitatively tracking the exchange process. We followed the barrier molecules′ concentration during the exchange process and their penetration depth into the 3D single crystal. The short aliphatic chain penetrates much farther into the crystal (ca. 450 μm) than the long aliphatic chain barrier molecule. In contrast, the process time is the opposite: the long aliphatic chain requires 5 days to achieve an equilibrium state compared with 15 days for the short aliphatic chain. Ab initio calculations indicate that the exchange process initiates due to the methylammonium vacancies on the surface, and the process is inhibited by the interactions between the −NH3 group and the PbBr2 planes. This work sheds light on the kinetics and thermodynamics of the transition from 3D to 2D perovskites, which is important for stabilizing the hybrid perovskites.
Pt(II)‐Phenanthroline‐Ln(III)‐DOTA d–f Hybrids as Small‐Molecule Theranostics
Authors: Brito Beatriz , Price Thomas W. , Bañobre‐López Manuel , Gallo Juan , Stasiuk Graeme J. 
Published: April 2024

Abstract1,10‐Phenanthroline d‐ or f‐metal complexes can be utilised in biomedical applications such as imaging or therapeutics. Herein, we designed bimetallic d‐block metal‐phenanthroline f‐block metal‐1,4,7,10‐tetraazacyclododecane‐1,4,7,1,0‐tetraacetic acid (DOTA) conjugates as theranostic agents to simultaneously achieve both of these applications. Luminescence studies show the 1,10‐phenanthroline‐Eu(III)‐DOTA complexes displayed an off/on/off pH‐dependent switch, demonstrating their potential as pH‐responsive lanthanide luminescence probes. Relaxometry studies showed that the 1,10‐phenanthroline‐Gd(III)‐DOTA complexes present a r1 of 5.15±0.05 mM−1 s−1 and could thus be used as magnetic resonance (MR) contrast agents. Complexation of Pt(II) by the 1,10‐phenanthroline moiety resulted in quenching of the Eu(III) luminescence, but an enhancement of the Gd(III) relaxivity (r1=7.53±0.69 mM−1 s−1). Cell viability studies of the d–f hybrids in a cancer cell line showed the potential of these complexes as anticancer agents, as the IC50 for the Pt(II)/Gd(III) complex (IC50=24.9 μM) was lower than that of cisplatin (IC50=31.6 μM). As such, Pt(II)‐1,10‐phenanthroline‐Gd(III)‐DOTA complexes are promising theranostic agents for cancer therapy.
Children's bias beyond group boundaries: Perceived differences, outgroup attitudes and prosocial behaviour
Authors: Razpurker‐Apfeld Irene , Shamoa‐Nir Lipaz , Taylor Laura K. , Dautel Jocelyn B. 
Published: April 2024

AbstractThis study explored how children's perceptions of social group differences relate to attitudes and behaviour towards real‐world outgroups. We examined Arab‐Christian children living in Israel (N = 231, 52% female, average age 9.8 years) and randomly presented them with either Arab‐Muslim or Jewish outgroup targets. The children performed tasks measuring attitudes and prosocial behaviour towards the outgroup. Additionally, they were asked to describe the differences between their ingroup and the outgroup target. We found that children favoured the Arab‐Muslim outgroup over the Jewish outgroup, and perceived it as having fewer dimensions of difference from their ingroup. Fewer perceived dimensions of difference correlated with more positive attitudes. By the age of 12, however, perceiving more dimensions of difference was linked to increased compensatory prosocial behaviour towards the Jewish outgroup. The findings emphasize the dynamic interplay between cognitive development and intergroup experiences in understanding children's prosocial behaviour towards different outgroups.
Early warning methods of chemical agent channeling in polymer–surfactant flooding reservoirs
Authors: Du Qingjun , Zhao Dong , Wu Jintao , Hou Jian , Wei Zhijie , Shi Lina , Zhou Kang , Zheng Haoyu , Zhang Jian , Liu Yongge 
Published: April 2024

AbstractIn the chemical flooding process, the premature breakthrough of chemical agents in production wells results in a large waste of chemical agents and increases the volume and processing difficulty of the produced fluids. The early warning method of chemical agent channeling can predict the strength of agent channeling in advance. The practice of chemical flooding shows that the production performance can be used for early warning of chemical agent channeling. In this paper, we analyze the relationship between cumulative oil production and cumulative polymer production of production wells in polymer–surfactant flooding. Three types of curves according to the enhanced oil production characteristics of chemical flooding, including convex type, S‐type, and concave type. We use the drop speed of the water–oil ratio and the rapid‐decline speed of water cut as early warning indicators to predict the channeling coefficient. A Latin hypercube experimental design method is used to design a polymer–surfactant flooding scheme with the main control factors of the channeling coefficient and early warning indicators. Numerical simulation is used to calculate samples of the channeling coefficient and early warning indicators under various conditions. The drop speed of the water–oil ratio reference value model and the rapid‐decline speed of the water cut reference value model are determined with a multiple regression method. A prediction model for the chemical agent channeling coefficient is established using the deviation coefficient of an early warning index. The method is applied in the Ng54‐61 polymer–surfactant flooding pilot area in the west of the Gudong Seventh District, Shengli Oilfield, China, and the error between the predicted result and the actual value is less than 10%. This research is helpful in taking effective antichanneling measures and improving the oil recovery degree of chemical flooding reservoirs.
Unlocking photocatalytic NO removal potential in an S‐type UiO‐66‐NH2/ZnS(en)0.5 heterostructure
Authors: Dai Wenrui , Wang Chenxiang , Wang Yi , Sun Jieting , Ruan Hang , Xue Yuhua , Xiao Shuning 
Published: April 2024

AbstractThe contamination of nitric oxide presents a significant environmental challenge, necessitating the development of efficient photocatalysts for remediation. Conventional heterojunctions encounter obstacles such as large contact barriers, sluggish charge transport, and compromised redox capacity. Here, we introduce an innovative S‐type heterostructure photocatalyst, UiO‐66‐NH2/ZnS(en)0.5, designed specifically to overcome these challenges. The synthesis, employing a unique microwave solvothermal method, strategically aligns the lowest unoccupied molecular orbital of UiO‐66‐NH2 with the highest occupied molecular orbital of ZnS(en)0.5, fostering the formation of a stepped heterojunction. The resulting intimate interface contact generates a built‐in electric field, facilitating charge separation and migration, as evidenced by time‐resolved photoluminescence spectroscopy and photoelectrochemical tests. The abundant active sites in the porous UiO‐66‐NH2 counterpart provide adsorption and activation sites for nitrogen monoxide (NO) oxidation. Performance evaluation reveals exceptional photocatalytic NO removal, achieving 70% efficiency and 99% selectivity toward nitrates under simulated solar illumination. Evidence from X‐ray photoelectron spectroscopy and trapping experiments supports the effectiveness of the S‐type heterostructure, showcasing refined reactive oxygen species, particularly superoxide. Thus, this study introduces a new perspective on advanced NO oxidation and unlocks the potential of S‐scheme heterojunctions to refine reactive oxygen species for NO remediation.
Application of standardized methods to evaluate the environmental safety of polyvinyl alcohol disposed of down the drain
Authors: McDonough Kathleen , Hall Maura J. , Wilcox Ashley , Menzies Jennifer , Brill Jessica , Morris Brian , Connors Kristin 
Published: April 2024

Abstract
The purpose of this research was to use polyvinyl alcohol (PVOH) 18-88 as a case study to evaluate the environmental fate, ecotoxicity, and overall safety profile of water-soluble, nonmodified PVOH polymers used in detergent films. An OECD 303A Wastewater Treatment Plant Simulation Study was conducted with dissolved organic carbon as the analytical endpoint to evaluate the removal of PVOH 18-88 during wastewater treatment. During the plateau phase, high levels of removal due to biodegradation were observed (average 97.4 ± 7.1, range: 88%–116%). The OECD 303A study quantitatively verified that surface water is the dominant receiving compartment for PVOH 18-88 post wastewater treatment. Acute algae, invertebrate, and fish embryo (fish embryo acute toxicity test [FET]) ecotoxicity studies quanitified the 50% lethal/effect concentration (L/EC50) for PVOH 18-88. Due to the potential for the chorion to impact PVOH 18-88 bioavailability, both chorionated and dechorionated FET tests were conducted. L/EC50 &gt; 1000 mg/L for FET (chorionated and dechorionated), invertebrate, and algae were observed. The Sustainable Futures (US) and REACH (EU) frameworks were used to evaluate environmental risk. For the US assessment, the Exposure and Fate Assessment Screening Tool was used to predict the single day lowest flow over a 10-year period (1Q10) surface water concentration and the seven consecutive days of lowest flow over a 10-year period (7Q10) surface water concentration and compared with acute and chronic concentrations of concern. For the EU assessment, the European Union System for the Evaluation of Substances was used to predict local and regional exposure concentrations and compared to the predicted no effect concentration. For both regulatory assessments, the exposure concentrations were &gt;2 orders of magnitude below the effect concentrations. Integr Environ Assess Manag 2024;20:1693–1705. © 2024 The Authors. Integrated Environmental Assessment and Management published by Wiley Periodicals LLC on behalf of Society of Environmental Toxicology & Chemistry (SETAC).
Key Points
Polyvinyl alcohol (PVOH) 18-88 was used as a case study to evaluate the environmental fate, ecotoxicity, and overall safety profile of water-soluble, nonmodified PVOH polymers used in detergent films. Polyvinyl alcohol 18-88 was biodegraded extensively during wastewater treatment. Low ecotoxicity was observed with measured LC/EC50s &gt; 1000 mg/L. The US and EU environmental risk assessments predicted exposure concentrations were &gt;2 orders of magnitude below effect concentrations, providing significant assurance of safety for PVOH 18-88 as a representative test substance for nonmodified PVOH polymers used in detergent films.
Identifying and interpreting gendered violence: Visual literacy in an audience reception study of Issa López' Casi Divas
Authors: DeFeo Dayna Jean , García Rebeca Maseda , Kılıç Zeynep 
Published: April 2024

AbstractWe present an audience reception study of participant reactions to gender‐based violence in Issa López' 2008 film, Casi Divas, chosen for its nuanced depiction of women grappling with several violences. Over three focus groups with 15 adult participants, we used Galtung's conflict theory to explore what participants identified as violence, and how victims should respond to violence in various forms. We find that participants have a narrow definition of violence, seeing it as an individualized act and therefore neglecting to consider its cultural or structural foundations. The participants' responses to violence largely reflected neoliberal values of personal empowerment and choice, resilience, and “leaning in.” We recommend critical visual literacy as a tool in the educational context to identify and address violence, to fight inequity, and to establish emancipatory discourses.