bluuebunny/crossref_metadata_2025_split huggingface dataset:
Organics in cometary and interplanetary dust
Authors: Levasseur-Regourd A. Chantal , Lasue Jeremie 
Published: October 2008

AbstractWhile gaseous carbon-rich species in cometary comae (coming from the nuclei icy component) are extensively studied by spectroscopic remote observations, so-called CHONs dust particles, i. e. organic compounds coming from the nuclei refractory component, have mostly been studied by dust mass spectrometers flying through the comae of comets 1P/Halley and 81P/Wild 2. However, remote observations of the light scattered by dust in cometary comae and in the interplanetary medium, coupled with both numerical and experimental simulations, have recently allowed us to confirm that such particles harbor a significant fraction of absorbing material, presumably consisting of organic compounds (Levasseur-Regourd et al. PSS 2007, Lasue et al. A&A 2007).We estimate the fraction of absorbing material present in cometary dust for extensively observed comets (e.g., 1P/Halley, C/1995 O1 Hale-Bopp) and in the interplanetary dust (from zodiacal light observations). We also establish that, besides compact particles, fluffy aggregates are definitely present in these media. The properties (e.g., size distribution, morphology, composition) of the cometary and interplanetary dust particles, as inferred from light scattering data analysis, are compared with those of the IDPS collected in the upper Earth atmosphere and of the unique samples returned by the Stardust mission at Wild 2. The results are discussed in terms of the formation of comets in the protosolar nebula, and of the possible survival, at the epoch of late early bombardment, of cometary organics embedded in fluffy aggregates.
Organic molecules in saturnian E-ring particles. Probing subsurface oceans of Enceladus?
Authors: Postberg Frank , Kempf S. , Srama R. , Grün E. , Hillier J. K. , Green S. F. , McBride N. 
Published: October 2008

AbstractThe population of Saturn's outermost tenuous E-ring is dominated by tiny water ice particles, some of which contain organic or mineral impurities. Active cryo-volcanism on the moon Enceladus, embedded in the E-ring, has been known to be a major source of particles replenishing the ring since late 2005. Therefore, particles in the vicinity of Enceladus provide crucial information about the dynamic and chemical processes occurring far below the moon's icy surface.We present a compositional analysis of thousands of impact ionisation mass spectra of Saturn's E-ring particles, with sizes predominantly below 1 μm, detected by the Cosmic Dust Analyser onboard the Cassini spacecraft. Our findings imply that organic compounds are a significant component of icy particles ejected by Enceladus plumes. Our in situ measurements are supported by detections of other Cassini instruments. They hint at a dynamic interaction of a hot rocky core with liquid water below the icy surface, where the organic molecules are generated. Further insights are expected from two close Enceladus flybys to be performed by Cassini in 2008. Then, for the first time, we will obtain spectra of freshly ejected particles at the traversals through the cryo-volcanic plumes.
The composition of Europa's near-surface atmosphere
Authors: Wong Mau C. , Cassidy Tim , Johnson Robert E. 
Published: October 2008

AbstractThe presence of an undersurface ocean renders Europa as one of the few planetary bodies in our Solar System that has been conjectured to have possibly harbored life. Some of the organic and inorganic species present in the ocean underneath are expected to transport upwards through the relatively thin ice crust and manifest themselves as impurities of the water ice surface. For this reason, together with its unique dynamic atmosphere and geological features, Europa has attracted strong scientific interests in past decades.Europa is imbedded inside the Jovian magnetosphere, and, therefore, is constantly subjected to the immerse surrounding radiations, similar to the other three Galilean satellites. The magnetosphere-atmosphere-surface interactions form a complex system that provides a multitude of interesting geophysical phenomenon that is unique in the Solar System. The atmosphere of Europa is thought to have created by, mostly, charged particles sputtering of surface materials. Consequently, the study of Europa's atmosphere can be used as a tool to infer the surface composition. In this paper, we will discuss our recent model studies of Europa's near-surface atmosphere. In particular, the abundances and distributions of the dominant O2 and H2O species, and of other organic and inorganic minor species will be addressed.
Titan's surface inventory of organic materials estimated from Cassini RADAR observations
Authors: Lorenz Ralph D. 
Published: October 2008

AbstractCassini RADAR observations now permit an initial assessment of the inventory of two classes, presumed to be organic, of Titan surface materials: polar lake liquids and equatorial dune sands. Several hundred lakes or seas have been observed, of which dozens are each estimated to contain more hydrocarbon liquid than the entire known oil and gas reserves on Earth. Dark dunes cover some 20% of Titan's surface, and comprise a volume of material several hundred times larger than Earth's coal reserves. Overall, however, the identified surface inventories (> 3 × 104 km3 of liquid, and >2 × 105 km3 of dune sands) are small compared with estimated photochemical production on Titan over the age of the Solar System. The sand volume is too large to be accounted for simply by erosion in observed river channels or ejecta from observed impact craters. The lakes are adequate in extent to buffer atmospheric methane against photolysis in the short term, but do not contain enough methane to sustain the atmosphere over geologic time. Thus, unless frequent resupply from the interior buffers this greenhouse gas at exactly the right rate, dramatic climate change on Titan is likely in its past, present and future.
Structural, chemical and isotopic examinations of interstellar organic matter extracted from meteorites and interstellar dust particles
Authors: Busemann Henner , Alexander Conel M. O'D. , Nittler Larry R. , Stroud Rhonda M. , Zega Tom J. , Cody George D. , Yabuta Hikaru , Kilcoyne A.L. David 
Published: October 2008

AbstractMeteorites and Interplanetary Dust Particles (IDPs) are supposed to originate from asteroids and comets, sampling the most primitive bodies in the Solar System. They contain abundant carbonaceous material. Some of this, mostly insoluble organic matter (IOM), likely originated in the protosolar molecular cloud, based on spectral properties and H and N isotope characteristics. Together with cometary material returned with the Stardust mission, these samples provide a benchmark for models aiming to understand organic chemistry in the interstellar medium, as well as for mechanisms that secured the survival of these fragile molecules during Solar System formation. The carrier molecules of the isotope anomalies are largely unknown, although amorphous carbonaceous spheres, so-called nanoglobules, have been identified as carriers. We are using Secondary Ion Mass Spectrometry to identify isotopically anomalous material in meteoritic IOM and IDPs at a ~100-200 nm scale. Organics of most likely interstellar origin are then extracted with the Focused-Ion-Beam technique and prepared for synchrotron X-ray and Transmission Electron Microscopy. These experiments yield information on the character of the H- and N-bearing interstellar molecules: While the association of H and N isotope anomalies with nanoglobules could be confirmed, we have also identified amorphous, micron-sized monolithic grains. D-enrichments in meteoritic IOM appear not to be systematically associated with any specific functional groups, whereas 15N-rich material can be related to imine and nitrile functionality. The large 15N- enrichments observed here (δ15N > 1000 ‰) cannot be reconciled with models using interstellar ammonia ice reactions, and hence, provide new constraints for understanding the chemistry in cold interstellar clouds.
Presolar grains in the Solar System: Connections to stellar and interstellar organics
Authors: Nittler Larry R. 
Published: October 2008

AbstractA small fraction of primitive meteorites and interplanetary dust particles (IDPs) consists of grains of presolar stardust. These grains have extremely unusual isotopic compositions, relative to all other planetary materials, indicating that they condensed in the outflows and explosions of prior generations of stars (Clayton & Nittler 2004). Identified presolar grain types include silicate, oxide and carbonaceous phases. The latter include graphitic carbon, diamond and SiC. Although many of these phases do not have a direct connection to organic chemistry, this is not true of the graphitic spherules. Many of these, with isotopic compositions indicating an origin in C-rich asymptotic giant branch (AGB) star outflows, have a structure consisting of naonocrystalline cores surrounded by well-graphitized C (Bernatowicz et al. 1996). The cores include isotopically anomalous polycyclic aromatic hydrocarbons (Messenger et al. 1998) and represent a link between molecular chemistry and dust condensation in stellar outflows. Meteorites and IDPs also contain abundant isotopically anomalous organic matter, including distinct organic grains, some of which probably formed in stellar outflows and/or the interstellar medium (ISM) (Busemann et al. 2006, Floss et al. 2004). In some IDPs, deuterium- and 15N-enriched organic matter is closely associated with presolar silicate grains (Messenger et al. 2005, Nguyen et al. 2007), suggesting an association in the ISM prior to Solar System formation.
Formation of biomolecule precursors in space?
Authors: Geppert Wolf D. , Vigren Erik , Hamberg Mathias , Zhaunerchyk Vitali , Kaminska Magdalena , Thomas Richard D. , Österdahl Fabian , Hellberg Fredrik , Ehlerding Anneli , Danielsson Mathias , Larsson Mats 
Published: October 2008

AbstractThe possibility of an extraterrestrial origin of biomolecule building blocks has been a subject of intense discussions for many years. The detection of amino acids in meteorites opens the possibility of a delivery of biomolecules synthesized in the interstellar medium or star-forming regions to the primeval Earth. Whereas it can be doubted if more complex species like amino acids can survive the strong UV radiation in the early Solar System, this does not necessary hold for more primitive precursor molecules like nitriles. These compounds can also be synthesized very efficiently in methane-nitrogen dominated atmospheres like the one present on Titan and the early ages of Earth. This Contribution focuses on the formation and degradation processes of nitriles in interstellar clouds and planetary atmospheres and on their possible role in the generation of biomolecules.
PAHs in Astronomy - A Review
Authors: Salama Farid 
Published: October 2008

AbstractCarbonaceous materials play an important role in space. Polycyclic Aromatic Hydrocarbons (PAHs) are a ubiquitous component of organic matter in space. Their contribution is invoked in a broad spectrum of astronomical observations that range from the ultraviolet to the far-infrared and cover a wide variety of objects and environments from meteorites and interplanetary dust particles to outer Solar System bodies to the interstellar medium in the local Milky Way and in other galaxies. Extensive efforts have been devoted in the past two decades to experimental, theoretical, and observational studies of PAHs. A brief review is given here of the evidence obtained so far for the contribution of PAHs to the phenomena aforementioned. An attempt is made to distinguish the cases where solid evidence is available from cases where reasonable assumptions can be made to the cases where the presence - or the absence - of PAHs is purely speculative at this point.
Photoproduction of H3+ from gaseous methanol inside dense molecular clouds
Authors: Pilling S. , Andrade D. P. P. , Santos A. C. F. , Boechat-Roberty H. M. 
Published: October 2008

AbstractWe present experimental results obtained from photoionization and photodissociation processes of abundant interstellar methanol (CH3OH) as an alternative route for the production of H3+ in dense clouds. The measurements were taken at the Brazilian Synchrotron Light Laboratory (LNLS) employing soft X-ray and time-of-flight mass spectrometry. Mass spectra were obtained using the photoelectron-photoion coincidence techniques. Absolute averaged cross sections for the production of H3+ due to molecular dissociation of methanol by soft X-rays (C1s edge) were determined. The H3+'s photoproduction rate and column density were been estimated adopting a typical soft X-ray luminosity inside dense molecular and the observed column density of methanol. Assuming a steady state scenario, the highest column density value for the photoproduced H3+ was about 1011 cm2, which gives the ratio photoproduced/observed of about 0.05%, as in the case of dense molecular cloud AFGL 2591. Despite the small value, this represent a new and alternative source of H3+ into dense molecular clouds and it is not been considered as yet in interstellar chemistry models.
Simulation of organic interstellar dust in the laboratory
Authors: Duley Walt W. 
Published: October 2008

AbstractNew techniques for the generation and analysis of carbon nanoparticles (CNPs) have been developed and have resulted in the production of CNP samples whose infrared spectral properties are essentially identical to those observed in interstellar absorption and emission. These particles are of mixed aromatic/aliphatic composition. Spectra of CNPs containing 102–104atoms will be discussed in relation to spectra of interstellar materials. We find that infrared line widths in these samples are typically 10–30 cm−1, but can be as small as 2 cm−1. Simulation of the 3.28 μm feature is shown to yield important new insight into the nature of interstellar CNPs.
Laboratory analogues of hydrocarbonated interstellar nanograins
Authors: Pino T. , Cao A. T. , Carpentier Y. , Dartois E. , d'Hendecourt L. , Bréchignac Ph. 
Published: October 2008

AbstractCarbonaceous extraterrestrial matter is observed in a wide variety of astrophysical environments. The spectroscopic signatures revealed a large variety of chemical structure illustrating the rich carbon chemistry that occurs in space. In order to produce laboratory analogues of carbonaceous cosmic dust, a new chemical reactor has been built in the Laboratoire de Photophysique Moléculaire. It is a low pressure flat burner providing flames of premixed hydrocarbon / oxygen gas mixtures, closely following the model system used by the combustion community. In such a device the flame is a one-dimensional chemical reactor that offers a broad range of combustion conditions and sampling which allows production of many and various by-products. In the present work, we have studied: i) the infrared transmission spectra of thin film deposit samples whose nature ranges from strongly aromatic to strongly aliphatic materials; ii) the resonant two-photon photoionisation spectra of gas phase PAHs formed in the flame.
A self-perpetuating catalyst for the production of complex organic molecules in protostellar nebulae
Authors: Nuth Joseph A. , Johnson Natasha M. , Manning Steven 
Published: October 2008

AbstractWhen hydrogen, nitrogen and CO are exposed to amorphous iron silicate surfaces at temperatures between 500–900 K a carbonaceous coating forms via Fischer-Tropsch type reactions. Under normal circumstances such a coating would impede or stop further reaction. However, we find that this coating is a better catalyst than the amorphous iron silicates that initiate these reactions. Formation of a self-perpetuating catalytic coating on grain surfaces could explain the rich deposits of macromolecular carbon found in primitive meteorites and would imply that protostellar nebulae should be rich in organic material.
Tholins and their relevance for astrophysical issues
Authors: Quirico E. , Szopa C. , Cernogora G. , Lees V. , Derenne S. , McMillan P. F. , Montagnac G. , Reynard B. , Rouzaud J-N , Fray N. , Coll P. , Raulin F. , Schmitt B. , Minard B. 
Published: October 2008

AbstractTholins are polymeric hydrogenated carbon nitrides formed from N2:CH4 mixtures exposed to electrical discharges. They are complex disordered solids, and their structural chemistry and formation processes are not yet fully understood. Tholins have been widely adopted as useful analogs of reddish organic solids associated with planetary bodies or in interstellar space (e.g., Titan's aerosols, reddish surfaces of outer objects, interstellar organics, etc.) for fitting astronomical observations. However, there has been little evidence to date that they in fact constitute pertinent model materials, i. e. with chemical structure/composition similar to those presumed to be present in planetary or interstellar organic solids. In this contribution, we first review recent advances made regarding the determination of composition and structure of tholins produced in the laboratory. They point to a high chemical selectivity in the range of functional groups present, the control of unsaturation by nitrogen, and the highly disordered character of the structures. In a second section, we discuss the relationship between chemistry and the optical properties of tholins, and we point out the lack of a unique relationship between the shape and strength of the visible absorption bands and the chemical composition or structure of the model tholins. The tholins exhibit similarities with HCN “polymers”, that are suspected to be present in cometary refractory dust. This points to the existence of possible similar polymerisation processes, and it suggests they could also be used as analogs of N-rich cometary organics. Laboratory-based studies of cometary dust might offer new insights on the “chemical relevancy” of tholins, as combined micro-analytical techniques will allow direct comparison of chemical information between the materials produced. In a third section we present recent results pertaining to the search for such compounds in cometary grains (Stardust grains, interplanetary dust particles - IDPs). We show that some N-rich spots in stratospheric IDPs are rich in cyanide species, but no tholin-like compounds or polymeric HCN have been detected to date.
Quenched carbonaceous composite (QCC) as a carrier of the extended red emission and blue luminescence in the red rectangle
Authors: Wada S. , Mizutani Y. , Narisawa T. , Tokunaga A. T. 
Published: October 2008

AbstractFilmy-QCC is an organic material synthesized in the laboratory, and it exhibits red photoluminescence (PL). The peak wavelength of the PL ranges from 650 to 690 nm, depending on the mass distribution of polycyclic aromatic hydrocarbon (PAH) molecules, and the emission profile is a good match for that of the extended red emission in the Red Rectangle nebula. The quantum yield of the PL ranges from 0.009 to 0.04. When filmy-QCC is dissolved in cyclohexane, it exhibits blue PL in the wavelength range of 400–500 nm with a quantum yield of 0.12–0.16. The large width of the red PL and the large wavelength difference between the PL of the filmy-QCC as a solid film and in a solution indicate that there is a strong interaction between the components of filmy-QCC. The major components of filmy-QCC are PAHs up to 500 atomic mass units. Our laboratory data suggest that the blue luminescence observed in the Red Rectangle nebula is probably caused by small PAHs in a gaseous state, and the extended red emission is caused by larger PAHs in dust grains.
Laboratory analogs of carbonaceous matter: Soot and its precursors and by-products
Authors: Jäger Cornelia , Mutschke Harald , Llamas-Jansa Isabel , Henning Thomas , Huisken Friedrich 
Published: October 2008

AbstractCarbonaceous materials have been prepared in the laboratory by laser-induced pyrolysis of a mixture of hydrocarbons under different conditions and laser ablation of graphite in reactive gas atmospheres. We have investigated the soluble and insoluble parts of the condensed carbon powders with several spectroscopic and chromatographic methods in order to obtain information on the composition of the condensate. The results of these experiments have demonstrated that, at temperatures lower than 1700 K, the pyrolysis by-products are mainly PAHs, whereas at higher temperatures fullerenes and polyyne-based compounds are formed. The experimental findings point to different soot formation mechanisms with variable intermediates and end products. It has been found that soot extracts can contain more than 65 different polycyclic aromatic hydrocarbons (PAHs). Eventually, the study of the condensation pathways of soot particles and their precursors and by-products will permit the prediction of the spectral properties of carbonaceous matter in space.
Ion irradiation effects on sooting flames by-products
Authors: Brunetto R. , Pino T. , Dartois E. , Cao A. T. , d'Hendecourt L. , Strazzulla G. , Bréchignac Ph. 
Published: October 2008

AbstractCarbonaceous extraterrestrial matter is observed in a wide variety of astrophysical environments. Spectroscopic signatures reveal a large variety of chemical structure illustrating the rich carbon chemistry that occurs in space. In order to produce laboratory analogues of the carbonaceous cosmic dust, a new chemical reactor has been built in the Laboratoire de Photophysique Moléculaire. It is a low pressure flat burner providing flames of premixed hydrocarbon/oxygen gas mixtures, closely following the model system used by the combustion community. In such a device the flame is a one-dimensional chemical reactor offering a broad range of combustion conditions and sampling which allows production of many and various by-products. In the present work, we have studied the effect of ion irradiation (200-400 keV), at the Laboratorio di Astrofisica Sperimentale in Catania, on several samples, ranging from strongly aromatic to strongly aliphatic materials. Infrared and Raman spectra were monitored to follow the evolution of the films under study, and characterize the irradiation process-induced modifications.
Irradiation of mixed ices as a laboratory cometary model
Authors: Colin-Garcia Maria , Negrón-Mendoza Alicia , Ramos-Bernal Sergio , Chacon Elizabeth 
Published: October 2008

AbstractIcy bodies in space are being irradiated continuously by ionizing radiation. Therefore, the transformation of organic molecules trapped in extraterrestrial ices might have been possible. This work studied a bulk irradiation of a mixture of some constituents of cometary nuclei. The results show that the formation of different compounds, among them ammonia, carbon dioxide, amines, ureas, free amino acids, and oligomeric material, yields carboxylic acids, amino acids, and purines upon hydrolysis.
Photodesorption of ices – Releasing organic precursors into the gas phase
Authors: Öberg Karin I. , van Dishoeck Ewine F. , Linnartz Harold 
Published: October 2008

AbstractA long-standing problem in interstellar chemistry is how molecules can be maintained in the gas phase at the extremely low temperatures in space. Photodesorption has been suggested to explain the observed cold gas in cloud cores and disk mid-planes. We are studying the UV photodesorption of ices experimentally under ultra high vacuum and at astrochemically relevant temperatures (15 – 27 K) using a hydrogen discharge lamp (7-10.5 eV). The ice desorption during irradiation is monitored using reflection absorption infrared spectroscopy and the desorbed species using mass spectrometry. We find that both the UV photodesorption rates and mechanisms are highly molecule specific. CO photodesorbs without dissocation from the surface layer of the ice. N2, which lacks dipole allowed electronic transitions in the range of the lamp, does not photodesorb. CO2 desorbs through dissociation and subsequent recombination from the top few layers of the ice. At low temperatures (15 – 18 K) the derived photodesorption rates are ~ 10−3 for CO and CO2 and < 2 × 10−4 for N2 ice per incident photon.