bluuebunny/crossref_metadata_2025_split huggingface dataset:
A possible role for light hydrocarbons in Pb/Zn mineral exploration
Authors: Ferguson J. 
Published: December 2006

AbstractA method of base metal exploration in sedimentary rocks which depends on detecting anomalous amounts of the light hydrocarbon gas methane in the host rocks has been applied in a number of orientation surveys in the British Isles and in Europe. The results of these studies are described, and the limitations of the method discussed. It is suggested that the principal difficulty lies in the extraction technique which is based on heating, and alternative methods are proposed. The preliminary results from these new methods are discussed and compared with those from the original study. A number of the samples analysed by the new methods are calcites of differing diagenetic origins. It is postulated that the differences in methane found in these samples may give a clue to the organic geochemistry of the rocks at the time when the calcites were deposited.
Calderite-rich garnets from metamorphosed manganese silicate rocks of the Sausar Group, India, and their derivation
Authors: Dasgupta Somnath , Bhattacharya P. K. , Banerjee H. , Fukuoka M. , Majumdar N. , Roy Supriya 
Published: December 2006

AbstractManganiferous garnets occur in metamorphosed Mn silicate-oxide and silicate-carbonate-oxide rocks of the Sausar Group, India. The garnets of the carbonatic rock show maximum calderite content (∼50 mole%). Increased Ca content in the bulk has been observed to be sympathetically related to the concentration of calderite, rather than the expected andradite component of the garnets. This is the consequence of the preferential partitioning of Ca in coexisting pyroxmangite and/or carbonate. Petrochemical characteristics of the diverse assemblages in response to the physical conditions of metamorphism show that the calderite solubility in manganiferous garnet is not only a function of pressure. Such characteristics only indicate that the mobile components in the bulk influenced the mineralogy of the assemblages at the ambient physical conditions of metamorphism, and this in turn controlled the calderite solubility in garnet.
Holmquistite-bearing amphibolite from Greenbushes, Western Australia
Authors: Frost M. T. , Tsambourakis G. , Davis J. 
Published: December 2006

AbstractHolmquistite idioblasts occur in a hornblende-titanite-quartz-plagioclase amphibolite, in contact with a lithium (spodumene) pegmatite at Greenbushes, Western Australia. Unit cell parameters, chemical data and the results of a mineralogical investigation of holmquistite and associated minerals in the amphibolite are given.
Primary allanite in andesitic rocks from the Poros Volcano, Greece
Authors: Mitropoulos P. 
Published: December 2006

AbstractPrimary allanite crystals occurring in andesitic rocks from Poros, NE Peloponnese, Greece were studied. Although the allanite shows high REE content, its presence does not affect the whole-rock REE content of the andesite. It is suggested that the formation of allanite crystals reflects the crystallization history of the andesitic rocks where allanite occurs. These andesitic rocks are the most basic rocks in which allanite has been reported.
Lower crustal granulite xenoliths in carbonatite volcanoes of the Western Rift of East Africa
Authors: Thomas C. W. , Nixon P. H. 
Published: December 2006

AbstractSporadic small garnet granulite and two-pyroxene granulite xenoliths found in the carbonatite tuffs and lavas near Fort Portal, South West Uganda, are chiefly silica-saturated and rich in Al2O3(> 20 wt. %) and Na2O (c.2 to 4 wt. %). ThreeREEpatterns are distinguished:LREEenriched—HREEdepleted with a positive Eu anomaly;LREEdepleted—HREErelatively enriched and flat; andLREEslightly enriched with a very weak Eu anomaly and high overallREE. The xenoliths are considered to represent original basaltic melts and fractional crystallisation products, varying with the dominance of the clinopyroxene, plagioclase or olivine crystallising phase. It is thought thatREEabundances were established before metamorphism.The clinopyroxenes are low-jadeitic augites, the orthopyroxenes, aluminous hypersthenes and the garnets, pyrope-almandine with constant grossularite. Plagioclase varies with increasing metamorphic grade from labradorite to andesine-oligoclase. Scapolite (meionite), alkali-feldspar, quartz, mica, amphibole, rutile and apatite are minor phases and some appear to be metasomatic.Calculated temperatures of metamorphic equilibration range from 580 to 800°C at pressures > 4 kbar for the two-pyroxene granulites and > 6 kbar for the garnet granulites. A known geophysical discontinuity marking a density change at 16 km in the Western Rift may be due to the presence of two-pyroxene granulite, calculated to become garnet-bearing at depths greater than 23 km. The absence of proven omphacite-bearing eclogite xenoliths (with no plagioclase) indicates that the greatest depth of crustal sampling by the carbonatite in the Fort Portal field is about 25 km which could be the depth of the Moho in this area.
Rare earth and uranium minerals present as daughter crystals in fluid inclusions, Mary Kathleen U-REE skarn, Queensland, Australia
Authors: Kwak T. A. P. , Abeysinghe P. B. 
Published: December 2006

AbstractAt least six separate rare earth and uranium-bearing daughter crystals occur in fluid inclusions hosted by andraditic garnet from the Mary Kathleen REE-U ore skarn, Queensland, Australia. The daughter minerals are particularly high in La, Nd and Ce which reflects the relatively high concentration of these in the bulk ore (La2O3 = 33.5%, Nd2O3 = 9.1% and Ce2O2 = 51.5% of the 2.6 wt. % REE common in the ore). The host garnets themselves contain up to 7600 ppm REE and 5 to 2700 ppm U. The energy-dispersive spectra (EDS) are consistent with the following minerals: a (Y, Ce, U, Ca, Fe, Nb, Ta) mineral; a (Ca, Fe, Ce) carbonate(?) mineral; a (Fe, Ca, Y, Ce, Nb, Ta) mineral; a possible carbonate of La, Mn and Nd; a chlorite of Mn and La as well as a possible chloride or oxychloride of K, Mg, Mn and La. Their occurrence infers that relatively high concentrations of REE and U prevailed in the original, oxidized, concentrated (30–70 wt. % total dissolved salts), high-temperature (550–670°) ore solutions. Their presence as daughter crystals may be due to the fact that CaCl2 is a dominant salt in the solutions and that the latter's solubility was sufficiently high to ‘salt out’ the less soluble REE-U components.
Rhodochrosite from Islay, Argyllshire and Dalroy, Inverness-shire, Scotland
Authors: Nicholson Keith 
Published: December 2006

AbstractRhodochrosite has been discovered as a minor component of two manganese deposits in Scotland. At Islay it occurs as coatings and veinlets on and within hollandite-pyrolusite-hematite-goethite mineralisation. Two foram microfossils were found within the carbonate which is considered to have formed from the interaction of organic-rich groundwater and seawater. The Dalroy rhodochrosite has the form of stromatactis-like cavity infill structures and veinlets in a mineralogically complex manganese-iron ore in which braunite, bustamite, manganoan ilmenite and pyrophanite have been identified. Intergrowths of rhodochrosite and native copper grains occur in a calcite matrix within the infill structures. These intergrowths are typically one micrometre across, but achieve diameters of up to 50 µm. The genesis of the Dalroy rhodochrosite is more problematical, although a hydrothermal source is most likely.
Chlorine-rich potassium hastingsite from West Ongul Island, Lützow–Holm Bay, East Antarctica
Authors: Suwa Kanenori , Enami Masaki , Horiuchi Tatsuro 
Published: December 2006

AbstractChlorine-rich potassium hastingsite occurs in a calcareous pegmatite, a replacement zone and an amphibolite lens within hornblende gneiss on West Ongul Island, Lützow-Holm Bay, East Antarctica. The amphibolite lens and hornblende gneiss were metamorphosed to the kyanite-sillimanite grade of the granulite facies during Proterozoic metamorphism. Chemical analysis (3.27 wt.% Cl), unit cell parameters and optical properties of the Cl-rich potassium hastingsite are given. Cl-rich (> 3 wt.%) calcic amphiboles reported from various rock types are mostly more than 0.9 in (Na+ K) content, more than 0.4 in K/(Na + K) ratio, more than 0.75 in Fe2+/(Fe2+ + Mg + Mn) ratio and more than 1.9 in AlIV content (total iron as FeO and O = 23). The unit cell volume of Cl-rich hastingsite is distinctly larger than that of Cl-poor hastingsite.
Fluid activity in the lower crust and upper mantle: mineralogical evidence bearing on the origin of amphibole and scapolite in ultramafic and mafic granulite xenoliths
Authors: Stolz A. J. 
Published: December 2006

AbstractXenoliths in an olivine nephelinite from the McBride Province, North Queensland, include Cr-diopside lherzolites, spinel and garnet websterites, felsic, 2-pyroxene and garnet granulites, and hornblendites. The spinel and garnet websterites are interpreted as crystal segregations from olivine basalt or alkali olivine basalt magma at ∼ 12 kbar followed by isobaric cooling (to approximately 900–1000°C) and subsolidus reequilibration. Garnet and 2-pyroxene granulites are mineralogically and texturally distinct and are considered to represent relatively large degrees of crystallization of basaltic magmas at comparable or slightly lower pressures (8–12 kbar). Mafic and ultramafic xenoliths have been modified to varying degrees following the relatively recent influx of a H2O- and CO2-bearing fluid. Variable amounts of amphibole and mica developed in response to the introduced fluid and it is argued that some hornblendites are the end-products of this process acting on spinel websterites. Felsic and 2-pyroxene granulite xenoliths display only minor evidence of increasedPH2O. Mineralogical and textural evidence indicates high-sulphur Ca-rich scapolite in several garnet granulites did not form in response to the increased fluid activities. It is proposed the scapolite was a primary cumulate phase precipitated from alkali basaltic magma under elevatedfo2andfso2conditions.
A new interpretation of round embayments in quartz crystals
Authors: Donaldson C. H. , Henderson C. M. B. 
Published: December 2006

AbstractThe surfaces of quartz crystals that were partially dissolved in superheated, H2O-saturated rhyolite melt are covered with hemispherical embayments; each embayment is judged to have formed where a gas bubble in the melt approached the crystal. ‘Flux-line attack’ and ‘upward-drilling’ of the refractory lining of glass tanks are analogous processes. As a bubble nears a dissolving solid it enters a compositional boundary layer in the melt, resulting in melt of variable surface tension surrounding the bubble. This unstable situation results in small-scale convection of the melt about the bubble (Marangoni convection) which can cause locally enhanced dissolution rate of the solid. It is suggested that this mechanism could cause round embayments to form in quartz phenocrysts in acid volcanic and sub-volcanic rocks. Criteria by which embayed phenocrysts formed by dissolution can be distinguished from those formed by unstable growth are reviewed briefly.
Experimental crystallization of chevkinite/perrierite from REE-enriched silicate liquids at high pressure and temperature
Authors: Green T. H. , Pearson N. J. 
Published: December 2006

AbstractChevkinite/perrierite crystallized from a series of REE-enriched compositions, ranging from basalt through andesite to rhyolite at pressures from 7.5 to 20 kbar and temperatures from 900–1050°C. The Al2O3 content increased with increasing pressure, but no other consistent composition change was observed with pressure and temperature variation in this range. The REE partition pattern consistently favoured light over heavy REE, with a regular decrease in partition coefficients (D) from La through to Lu. D values increase with decreasing temperature and decreasing REE content (i.e. Henry's Law does not apply, as REE are essential structural constituents of chevkinite/perrierite), but appear unaffected by pressure and fo2. Chevkinite/perrierite may be a significant fractionating phase in evolving silicic magmas, or a residual phase from low degrees of partial melting of granulites. In both these circumstances it will exert a major control on the REE content of derivative liquids.
Compositions of trioctahedral micas in the Cornubian batholith
Authors: Stone M. , Exley C. S. , George M. C. 
Published: December 2006

AbstractNew major and trace element chemical analyses of trioctahedral micas of the Cornubian batholith emphasize their enrichment in a ‘trace-alkali element’ association (Li, Rb, Cs, F, Nb, Mn) and their deficiency in a ‘femic element’ association (Zr, Ce, Th as well as Mg and Ti) compared with micas from many other granite suites, although there are similarities with some Hercynian granites and with rare metal pegmatites. The new data demonstrate a continuous series from siderophyllite through zinnwaldite to lepidolite, principally as a result of Li-R2+ substitution as indicated by Foster (1960), although a more complete replacement is (Li, Al) = (Fe2+, Fe3+, Ti). It is suggested that the ranges of these micas are based upon the Li content in the unit cell formula and the ratio of Li to R2+, in effect, a compromise between the ranges proposed by Foster (1960) and Rieder (1970). Microprobe analyses lack Li2O, but can be plotted on FeO-SiO2 and FeO-Al2O3-SiO2 diagrams (wt. or atom %) in order to locate compositions within the trioctahedral LiFe micas and to distinguish between lepidolite and muscovite.An examination of 55 new mica analyses shows that hornfels biotites are richer in Mg and that the Cornubian Type A granite (as classifed by Exley and Stone, 1982) micas are richer in Ti and Fe compared with those of Type B granites. Micas from microgranite dykes appear to be poorer in femic elements and richer in trace alkalis and F compared with their Type B granite hosts, consistent with their differentiation from the latter. Mica chemistry is consistent with the magmatic evolution of the A-B-microgranite sequence in the biotite granites, the transformation of Types B to D upon emplacement of E, the derivation of Types E from B by extreme differentiation or metasomatic transformation and mobilization, and the in situ differentiation of Types G from E.
Ecandrewsite, the zinc analogue of ilmenite, from Little Broken Hill, New South Wales, Australia, and the San Valentin Mine, Sierra de Cartegena, Spain
Authors: Birch W. D. , Burke E. A. J. , Wall V. J. , Etheridge M. A. 
Published: December 2006

AbstractEcandrewsite, the zinc analogue of ilmenite, is a new mineral which was first described from the Broken Hill lode in 1970 and discovered subsequently in ores from Little Broken Hill (New South Wales) and the San Valentin Mine, Spain. The name ‘ecandrewsite’ was used in a partial description of the mineral in ‘Minerals of Broken Hill’ (1982), thereby establishing the Little Broken Hill locality, specifically the Melbourne Rockwell Mine, as the type locality. Microprobe analysis of ecandrewsite from the type locality gave ZnO 30.42 (wt.%), FeO (total Fe) 11.37, MnO 7.64, TiO2 50.12, total 99.6%, yielding an empirical formula of (Zn0.59Fe0.24Mn0.17)1.00Ti0.99O3 based on 3 oxygen atoms. All compositions from Little Broken Hill and the San Valentin Mine are ferroan manganoan ecandrewsite. The strongest lines in the X-ray powder diffraction data are (d in Å, (hkil), I/Io):2.746, (104), 100; 2.545, (110), 80; 1.867, (024), 40; 3.734, (012), 30; 1.470, (3030), 30; 1.723, (116), 25. Ecandrewsite is hexagonal, space group RR3¯ assigned from a structural study, with a = 5.090(1), c = 14.036(2)Å, V = 314.6(3)Å3, Z = 6, D(calc.) = 4.99. The mineral is opaque, dark brown to black with a similar streak, and a submetallic lustre. In plane polarized light the reflection colour is greyish white with a pinkish tinge. Reflection pleochroism is weak, but anisotropism is strong with colours from greenish grey to dark brownish grey. Reflectance data in air between 470 and 650 nm are given. At the type locality, ecandrewsite forms disseminated tabular euhedral grains up to 250 × 50 µm, in quartz-rich metasediments. Associated minerals include almandine-spessartine, ferroan gahnite and rutile. The name is for E. C. Andrews, pioneering geologist in the Broken Hill region of New South Wales. Type material consisting of one grain is preserved in the Museum of Victoria (M35700). The mineral and name were approved by the IMA Commission on New Minerals and Mineral Names in 1979.
The structure of reyerite, (Na,K)2Ca14Si22Al2O58(OH)8.6H2O
Authors: Merlino Stefano 
Published: December 2006

AbstractThe crystal structure of reyerite, (Na,K)2Ca14Si22Al2O58(OH)8.6H2O, Z = 1, was refined in the space group P, a = 9.765, c = 19.067Å, to R = 0.064 for 1540 reflections. The structure is composed of the following structural units: (a) tetrahedral sheets S1, with composition (Si8O20)8−, characterized by six-membered rings of tetrahedra; (b) tetrahedral sheets S2, characterized by six-membered rings of tetrahedra, with six tetrahedra pointing in one direction and two pointing in the other direction—the apical oxygens of these two tetrahedra connect two inversion-related S2 sheets to build double sheets, with composition (Si14Al2O38)14− and ordered distribution of aluminum cations; (c) sheets O of edge-sharing calcium octahedra. The various structural units are connected through corner sharing according to the schematic sequence ……; the corresponding composition is [Ca14Si22Al2O58(OH)8]2−. The charge balance is restored by alkali cations which are placed, together with water molecules, in the cavities of the structure at the level of the double tetrahedral sheet.
Ion Microprobe Determination of Rare Earth Elements in Perovskite from Kimberlites and Alnöites
Authors: Mitchell Roger H. , Reed Stephen J. B. 
Published: December 2006

AbstractIon microprobe analysis ofperovskite from kimberlites and alnöites permits the accurate determination of La, Ce, Pr, Nd, Sm, Eu, Gd, Dy, Er and Yb at the part per million level. Other rare earth elements (REE) are subject to interferences in the mass spectrum caused by matrix-derived molecular ions and cannot easily be determined with comparable precision. Chondrite-normalized plots of the ion probe REE data are smooth curves, confirming the superiority of this technique over electron microprobe methods at the levels of REE abundance found in these perovskites. The perovskites analysed contain between 2.8 and 7.1 wt. % REE oxides and are highly enriched in the light REE, having La/Yb ratios of 577–3229. These La/Yb ratios are not representative of the parental magmas but result from REE fractionation during crystallization of the perovskite. Parental magma La/Yb ratios are estimated to be of the order of 120–650. The lower La/Yb ratios (80–200) found for whole-rock kimberlites are considered to result from contamination by relatively heavy REE-enriched crustal material.
Comparison of Cation Exchange in Ganophyllite and [Na + Al]-Substituted Tobermorite: Crystal-Chemical Implications
Authors: Komarneni Sridhar , Guggenheim Stephen 
Published: December 2006

AbstractGanophyllite and [Na+ + Al3+]-substituted tobermorite exhibited similar cation exchange properties and, in particular, selective cesium exchange. [Na+ + Al3+]-substituted tobermorite and ganophyllite showed a selective Cs exchange of 10.77 and 8.71 meq/100 g from 0.02N NaCl and of 11.08 and 9.04 meq/100 g from 0.02N CaCl2, respectively. The [Na+ + Al3+]-substituted tobermorite is structurally similar to ganophyllite: both are roughly analogous to 2:1 layer silicates, both have cross-linking tetrahedra across the interlayer region, and both have exchangeable cations located in zeolite-like sites in the interlayer region. The similarities in cation exchange properties imply that the residual charge configuration of the analogue 2 : 1 layer must be approximately equivalent also.
The Peralkaline Nepheline Syenites of the Junguni Intrusion, Chilwa Province, Malawi
Authors: Woolley Alan R. , Platt R. Garth 
Published: December 2006

AbstractThe mineralogy of the highly peralkaline Junguni nepheline syenite intrusion of the Chilwa alkaline province has been investigated. The rocks comprise alkali feldspar, very abundant nepheline, locally exceptionally abundant sodalite, sodic pyroxenes, scarce biotite, rare amphibole, and an extensive range of accessory minerals. Electron microprobe analyses indicate that the pyroxenes define an evolutionary trend from salite through aegirine-augite to aegirine, which is unusual in its broadness and ill-definition. This is explained by a series of overlapping trends produced by fluctuating Fe3+/Fe2+ ratios caused by variations in alkali content of the magma, probably produced by periodic alkali loss by surface de-gassing. Much of the sodalite occurs as a primary liquidus phase, but the paragenesis of certain ramifying sodalite veins is more problematical. It is possible that such ramifying masses are the product of coupled migration of alkalis and volatiles by diffusion in a gravitation field under pressure gradients generated by eruptive events, or by the formation of immiscible Na- and Cl-rich liquids. Both early calcic and late mangan-fluor eckermannitic/arfvedsonitic amphiboles occur. The micas vary from biotites with Mg: Fe ratios < 0·5 to almost pure annites; they are fluor-micas and characterized by high Mn contents. Analyses of niobian rutile, mangan ilmenite, ferroan pyrophanite, manganese-rich eucolite, låvenite, mangan-titan låtvenite, rosenbuschite, wöhlerite, pyrochlore, eudialyte and what is believed to be only the second occurrence of kupletskite are given. Many of these minerals are rich in Zr, Nb, Na and Mn and thus typical of the assemblages found in extreme agpaitic complexes such as Ilimaussaq and Lovozero.
The Role of Tholeiitic Magmatism in the English Lake District: Evidence from Dykes in Eskdale
Authors: Macdonald R. , Millward D. , Beddoe-Stephens B. , Laybourn-Parry J. 
Published: December 2006

AbstractMafic dykes occur in close association with, and both cut and are cut by, the Eskdale granite in the south-western Lake District. The dykes range compositionally from magnesian basalt to andesite and are divided into two groups: (1) high-Fe-Ti rocks of tholeiitic affinity forming most of the dykes and (2) a lower-Fe-Ti group, comparable in composition to the lavas of the Borrowdale Volcanic Group. The dykes extend the range of tholeiitic magmatism in the Lakes into late Ordovician, and possibly Silurian times, and indicate that published plate tectonic models partly based on the distribution of magma types are perhaps over-simplified. The Eskdale dykes form one end of a spectrum of Lake District compositions from tholeiitic to calc-alkaline. All the magma types may have shared a common mantle source, their final composition reflecting residence times in the crust or LIL-enriched mantle.