bluuebunny/crossref_metadata_2025_split huggingface dataset:
Use of green vegetable barriers as environmental noise attenuators: a case study in Irati, Parana
Authors: Spliethoff Jhenifer , Oliveira Filho Paulo Costa de , De Conto Juliana , Martins Kelly Geronazzo , Bonete Izabel Passos 
Published: May 2024

The present study aims to evaluate the potential of the Secondary Mixed Ombrophilous Forest as a vertical noise-attenuating green barrier. The methodology calls for the development of an analysis of proximity between sampling points of omnidirectional noise monitoring to be measured at various distances from the source from the beginning of the barrier and inside the forest. A sound source reproducing amplified pink noise was used. In this research, an experimental strategy was used to prove the influence of this type of green plant barrier as a noise attenuator as one enters the interior of a fragment of Mixed Ombrophilous Forest, carrying out successive measurements of the sound pressure level at distances from the proximity of the source and the distances from the edge towards the interior of the forest that can prove the significant attenuating function of this type of green vertical barrier. In fact, the analyses performed for LZeq A and Z (dB) confirm a significant correlation for distance from the source regardless of the sound amplitude for measurements performed outside the barrier (in front of the source, 6 m behind the source, 6 meters in front of the source), as noise attenuation occurs as the sound propagates. However, the analyses inside the barrier (at 12m, 18m and 24m) present a negative correlation for distance, confirming the hypothesis of the effectiveness of the attenuation by the vegetal barrier.
Tantangan Teologis dalam Memahami dan Mengatasi Ajaran Sesat Kontemporer: Tinjauan Terhadap Realitas Spiritual dan Peran Gereja
Authors: Arifianto Yonatan Alex , Nainggolan Richardo , Sujaka Adi 
Published: May 2024

: In the era of globalization and digitalization, the massive amount of information and religious content challenges the church and Christianity. The understanding of truth distorted by heretics who teach heretical teachings in the contemporary era is increasingly complex, threatening the stability of society, the harmony of the Body of Christ, as well as the foundation of religious belief and individual spirituality. The purpose of this paper emphasizes that the church can maintain the unity and integrity of the Christian faith and protect its congregation from destructive and misleading influences. Using a descriptive qualitative method with a literature study approach, it can be concluded that the theological challenge of Christianity in understanding and overcoming heretics who teach heresies in the contemporary era. In theological challenges in understanding and overcoming contemporary heresies as a review of spiritual reality and the role of the church. That is, the church and Christianity can analyze and understand the nature of contemporary heresy. Where heresy in a theological perspective on spiritual reality can have an impact on Christianity. so it is hoped that the role of the church in actualizing and the role of the church in overcoming heresy and providing in-depth education for church members.AbstrakDalam era globalisasi dan digitalisasi, yang massif akan informasi dan konten keagamaan menjadi tantangan akan gereja dan kekristenan. Pemahaman kebenaran yang diselewengkan oleh bidat yang mengajarkan ajaran sesat di era kontemporer semakin kompleks, mengancam stabilitas masyarakat, kerukunan Tubuh Kristus, serta fondasi keyakinan agama dan spiritualitas individu. Tujuan dari penulisan ini menekankan bahwa gereja dapat menjaga kesatuan dan integritas iman Kristen serta melindungi jemaatnya dari pengaruh yang merusak dan menyesatkan. Menggunkan metode kualitatif deskritif dengan pendekatan studi literature maka dapat disimpulkan bahwa Tantangan teologis kekristenan dalam memahami dan mengatasi para bidat yang mengajarkan ajaran sesat di era kontemporer. Dalam tantangan teologis dalam memahami dan mengatasi ajaran sesat kontemporer sebagai tinjauan terhadap realitas spiritual dan peran gereja. Yaitu gereja dan kekristenan dapat menganalisis dan mengerti akan hakikat ajaran sesat kontemporerdewasa ini. Di mana ajaran sesat dalam perspektif teologis terhadap realitas spiritual dapat berdampak bagi kekristenan. sehingga diharapakan peran gereja dalam mengaktualisasi dan peran gereja dalam mengatasi ajaran sesat dan memnerikan edukasi mendalam bagi warga gereja.
إثبات رؤية الله تعالى للمؤمنين يوم القيامة على ضوء السنة النبوية
Authors: عبدالستار فاضل رحيم الشواني  , الأستاذ الدكتور صالح معتوق  
Published: May 2024

يَهدف هذه دراسة الله تعالى للمؤمنين يوم القيامة على ضوء السنة النبوية وتَنبع أهمية البحث من خلال التركيز عليه تأكيد وإزالة الإشكال إلى بيان رؤية عن موضوع الرؤية، ومدى إمكانية حدوثها في الدّنيا والآخرة ، وقد انتهجت في الدّراسة المنهج التحليلي، وذلك بالرجوع إلى كتب العقيدة وجمع المسائل من بطونها وتفنيدها ، والعبرة في مسائل الخلاف بما كان موافقًا مع نصوص الكتاب والسنة ومأثورات السلف والتفسيرات السليمة للنصوص حسب القواعد السليمة وأصولها , وتدعيمها برأي الباحثة وترجيحه المسألة حسب التي يتم بحثها, وقد قَسَمْتُ موضوع البحث إلى ثلاثة فصول وأمَّا الخاتمة، تضمنت جُملة من النَّتائج التي تَمكنت من الوصول إليها بعد دراسة الموضوع والإلمام به من كلِّ جوانبه.
الجمعُ المُكَسَّرُ مفهومهُ وأوزانهُ ودلالاتُ ألفاظه
Authors: د. سائر بن عبد الله الحيسوني  
Published: May 2024

الحمد لله الذي أنزل القرآن بلسان عربيٍّ مبين؛ فتحدَّى ببلاغته الأوّلين والآخرين، والصلاة والسلام على أفصح العرب أجمعين الذي آتاه ربُّه جوامعَ الكَلِم؛ فكانت بلاغته نبراسَ الفصحاءِ، والمتأدبين، وعلى آل بيتِه الأطهار الطيَّبين، وأصحابه الغرّ الميامين، ومَن تبعهم بإحسانٍ إلى يوم الدين.
أما بعدُ:
فلا شكّ أنّ جمع التكسير يختلف عن جمعَي التصحيح؛ إذ يضاف إلى نهاية الاسم المفرد فيهما زيادة خاصة بهما دون تغيير في تركيبتهما الأصلية، وقد تتغير الأسماء –أحيانًا- كحبلى، وسماء، ومصطفى والقاضي؛ فنقول حبليات وسماوات ومصطفون والقاضون، والجمع المُكسر تتغير صورة مفرده لفظًا, أو تقديرًا من غير اعتماد قاعدة ثابتة، وهذا السبب الرئيس في تسميته بالجمع المُكَسَّر.
وجموع التكسير –خاصة- تتصف بصفة أخرى غير ثقل الجمع الذي فيها، وهي تعدّد الأبنية، والصيغ فيها، وهذا التعدد ناشئ من تعدد أبنية المفرد([1]).
والجمع المُكَسَّر بحر, لا ساحل له؛ لأنّ منه القياسيّ، ومنه السّماعيّ، والقياسيّ تكفلتْ ببيانه كتبُ الصرف, ومعاجمُ اللغة، والسّماعيّ لا ضابط له، ولا حاصر.
وجمع التكسير هو أعمّ الجموع, وأشملها, يدلّ على ذلك أنّ ما يُجمع بالواو والنون لك أن تجمعه بالتكسير، فكما تقول: زيدون، تقول: أزياد وزيود([2])، وكما تقول: هندات، تقول: أهناد وهنود([3])، وما لا يصحّ جمعه بالواو والنون، ولا بالألف والتاء يأتي على جمع التكسير، نحو: "درهم" يجمع: "دراهم"، ولا يجوز أن يجمع بالألف والتاء؛ لأنه مذكر، ولا يُجمَع بالواو والنون؛ لأنه ليس بمذكر عاقل؛ فدلّ ذلك على استغناء جمع التكسير عن جمعَي السلامة([4]).
ولأهمية الجمع المُكَسَّر؛ شرعتُ في إلقاء الضوء على جوانب مُهمّة فيه؛ إذ لفت انتباهي خلال استقرائي أوزان جموع القلّة، والكثرة، ودلالاتها اللفظيّة عدة أمور, أردتُ توضيحها في هذا البحث، وقد استقرَّ بي الأمر إلى اختيار دراسة علمية مستقلّة معنونًا إيَّاها بـ(الجَمْع المُكَسَّر أوزانه ودلالات ألفاظه) في إطار المنهج الوصفيّ المتّخذ من التحليل أداة له في ضوء كتابات القدماء, والمحدثين، واتّبعتُ في البحث الخطة الآتية:
الفصل الأول: مفهوم الجمع المُكسر عند القدماء والمحدثين، وفيه مبحثان.
المبحث الأول: مفهومه عند القدماء.
المبحث الثاني: مفهومه عند المحدثين.
الفصل الثاني: أنواع الجمع المُكسر, وأوزانه, وبعض دلالاته, وفيه مبحثان.
المبحث الأول: أنواع الجمع المُكسر, وأوزانه.
المبحث الثاني: بعض دلالات أبنية الجمع المُكسر.
وأُرْدِفَتْ هذه الفصول, والمباحثُ بخاتمةٍ وقائمةٍ بمصادرِ البحثِ، ومراجعه.

([1]) المقتضب للمبرد 2/201، وعلل النحو للوراق ص519.
([2]) الكتاب 3/395، وشرح الكتاب للسيرافي 4/146.
([3]) المقتضب 2/323.
([4]) الفوائد والقواعد للثمانيني ص130.
مفهوم النِعَمة والشكر والجحود في الإسلام
Authors: مهند حمدي محمود  
Published: May 2024

لقد أنعم الله تعالى على عباده بِنعَمٍ لا تُعدُّ ولا تحصى، ظاهرةً وباطنة، يعرفونها ويجهلون بعضها، إلا أنَّ الله تعالى ميّز عباده من بين كافة المخلوقات بأن جعل لهم عقلاً يتفكّرون به، وديناً يعيشونَ في كَنَفِه، وفضّلهم على كثيرٍ ممّا خلق.
ويشار إلى أنّ العلم بالنّعم غير حاصل للعباد فهي كثيرة ومتنوعة، ولا يمكن للإنسان أن يقدّر عددها أو مجالاتها، قال تعالى: ﴿ وَإِن تَعُدُّواْ نِعۡمَةَ ٱللَّهِ لَا تُحۡصُوهَآۗ إِنَّ ٱللَّهَ لَغَفُورٞ رَّحِيمٞ ﴾[النحل: 18]، وبالمقابل، يوجد مفهومين يقابلان النَعم كردّ فعلٍ من قِبَل الإنسان عليها، وهما: الشكر والجحود، فإذا شكر العبد ربّه على تلك النعم زادت وتعاظمت، وإذا جحد بها، زالت واختفت، قال تعالى: وَإِذۡ تَأَذَّنَ رَبُّكُمۡ لَئِن شَكَرۡتُمۡ لَأَزِيدَنَّكُمۡۖ وَلَئِن كَفَرۡتُمۡ إِنَّ عَذَابِي لَشَدِيدٞ (7) [إبراهيم: 7].
وعليه، يأتي هذا البحث ليوضح مفهوم النِّعَم وأنواعها، وأوجه ورودها في القرآن الكريم، ومن ثمّ استعراض مفهومَي الشكر والجحود وآثارهما على الإنسان.
CON MARCELO VIÑAR: “VIVIR LA VIDA VALE LA PENA… PERO… SERÍA TERRIBLE QUE EL HOMBRE FUERA INMORTAL”
Authors: Gorriti Jorge , Schutte Lourdes , Albuquerque Helena , Fabossi Paschotto Vânia 
Published: May 2024

La presente entrevista fue realizada el 14 de octubre de 2023 en el marco del XII Congreso de FLAPPSIP, que tuvo lugar en Santiago e Chile en el mes de Octubre del año 2023. Marcelo Viñar, Doctor en Medicina y Psicoanalista, nacido en 1937 en Uruguay, cuenta con una vastísima trayectoria y fue uno de los conferencistas centrales del mencionado Congreso. Aunque su presentación fue en torno a la adolescencia, elegimos conversar con él sobre otra etapa de la vida. [...]
Acculturation of Chinese Buddhism in Malaysia – A Critical Review from the Perspective of Cultural Neuroscience
Authors: Yusoff Nasir , A Aziz Mohd Azmarul 
Published: May 2024

The Chinese Buddhism is a group of ethnic minorities that has migrated to Malaya (Malaysia) decades ago. The migration of the first generation of the Chinese Buddhism ethnic community to Malaya marked the beginning of a cultural encounter between their original culture and that of the ethnic majority (Malay) in their new homeland. This review explores acculturation from a cultural neuroscience perspective, explaining the process of how acculturation occurs among the Chinese Buddhism ethnic minority based on the neuro-cultural interaction model. The cultural neuroscience perspective is discussed from the viewpoints of psychology, sociology, and cultural anthropology, drawing on previous cross-cultural neurological studies for reference. Chinese Buddhism from the east coast of Peninsular Malaysia serves as a reference model for developing the conceptual framework of cultural neuroscience. Chinese Buddhism community has shown the influence of Malay culture in various aspects of life such as food, clothes, and other social aspects.
Dolicoectatic Compression of the Optic Tract: A Case Report
Authors: Terry Ryan 
Published: May 2024

Dolichoectasia is an arterial disease that causes dilation or tortuosity of the impaired vessel. It most commonly affects the vertebrobasilar system and the internal carotid artery. Although most cases are asymptomatic, the condition may manifest by symptoms of headache, vertigo, visual disturbance, or signs of cranial nerve impairment.
PELATIHAN PEMBUATAN ECOPRINT MENGGUNAKAN TEKNIK POUNDING UNTUK MENINGKATKAN SOFTSKILL ANAK DI DESA REJOMULYO KECAMATAN TANJUNG BINTANG KABUPATEN LAMPUNG SELATAN
Authors: Rahmatika Zahra , Susanti Agus , Hijriyah Umi , Isti’ana Ais , Susilawati Beti 
Published: May 2024

Ecoprint merupakan teknik membuat motif berbahan dasar tumbuhan dari alam yang ramah lingkungan. Ecoprint sudah dikenal sejak dahulu, namun teknik dalam pembuatan ecoprint selalu mengalami perkembangan hingga saat ini motif yang dapat dihasilkan sangat menarik bahkan bernilai ekonomis. Bahan dasar ecoprint merupakan tumbuh-tumbuhan di alam, hal ini yang menjadikan alasan tim melakukan pelatihan pembuatan ecoprint dengan teknik pounding terhadap anak-anak di Desa Rejomulyo yang berkisaran umur 9-10 tahun sebagai bentuk apresiasi terhadap kekayaan alam yang ada di Desa Rejomulyo serta untuk menambah soft skill anak-anak di Desa Rejomulyo. Metode penelitian yang gunakan adalah deskriptif kualitatif. Objek dalam penelitian ini adalah penerapan ecoprint menggunakan teknik pounding. Subjek dalam penelitian ini adalah anak-anak di Desa Rejomulyo.Pada tahap persiapaan, tim pelatihan melakukan pengumpulan bahan baku yang akan digunakan untuk membuat ecoprint dengan teknik pounding. Pelaksanaan pelatihan dilakukan pada hari jumat tanggal 01 maret 2024, 16.00 WIB.Hasil pelatihan ecoprint dengan teknik pounding terhadap anak-anak di Desa Rejomulyo masih memerlukan pendalaman lebih lanjut, namun sudah cukup baik untuk pengalaman pertama mereka.Jadi rekam jejak kegiatan yang telah dilakukan terlihat bakat dan kreatifitas yang tinggi sebagai bentuk perwujudan dari soft skill anak di Desa Rejomulyo yang sudah cukup baik namun masih memerlukan mimbingan yang lebih lanjut.
Crystallization
Authors: Ulrich Joachim , Stelzer Torsten 
Published: January 2011

AbstractThis article provides an overview of crystallization that can be used by scientists and engineers, regardless of their familiarity with the operation. Key aspects of using crystallization for separation, purification, or other purposes are covered; especially noteworthy is the coverage relating product purity, morphology, polymorphs, solvates, and size distribution to the kinetic phenomena of crystal nucleation and growth. Current studies have shown that crystallizer variables such as mixing and the rate at which supersaturation is generated influence the purity of recovered crystals. Crystal morphology can be affected by variables modifying inherent growth kinetics of crystal faces or by changing interfacial or solution properties. Molecular modeling is a tool to understand and predict morphologies or changes of morphologies due to additives/impurities. Theory is mixed with empiricism in showing the role of operating variables (supersaturation, magma density, and agitation) in determining crystallization kinetics. Methods are illustrated for coupling crystallization kinetics with population balances on continuous and batch crystallizers to determine crystal size distributions. In addition, the bases of using selective removal functions (clear–liquor advance, classified fines removal, and classified product removal) to influence the characteristics of size distributions are presented. Qualitative characteristics of batch crystallizers are presented and the role nucleation plays in determining the general behavior of product size distributions from such system is described. Furthermore, a summary of industrial practice and equipment (solution and melt crystallization) is presented. Finally, brief reviews are given to the emerging importance of preferential crystallization, eutectic freeze crystallization as well as the crystallization of proteins.
Sodium Carbonate
Authors: Eggeman Tim 
Published: January 2011

AbstractSodium carbonate, also known as soda ash, is an alkali chemical refined from the mineral trona or naturally occurring sodium carbonate brines. The product is called natural soda ash. Synthetic soda ash is manufactured by several chemical processes. Production from trona and the Solvay synthetic process account for the vast majority of current capacity. The United States has the world's largest deposit of trona. Sodium carbonate is a moderate health hazard. The major use of soda ash is in the manufacture of glass. Other uses are the manufacture of chemicals, in detergent formulations, flue gas desulfurization, and in the production of paper and pulp
Inventory Inaccuracies In Supply Chains: How CanRFIDImprove The Performance?
Authors: Rekik Yacine 
Published: January 2011

AbstractInventory inaccuracy occurs when the information system (IS) inventory, that is, what, according to the IS, is available, does not match the physical inventory, that is, what is actually available. The IS inventory, contrary to popular belief and assumptions in most academic papers and in spite of the considerable amounts invested in information technology, is often inaccurate. In this article, we first describe the major factors generating inventory inaccuracy. Then, we present main solutions that allow tackling the inaccuracy issue. We also provide a framework that permits modeling the inventory inaccuracy issue and focus on the impact of an advanced identification system such as radio‐frequency identification (RFID) technology in improving the performance of a supply chain subject to inventory inaccuracies.
On the allocation of new lines in a competitive transit network with uncertain demand and scale economies
Authors: Li Zhi‐Chun , Lam William H. K. , Wong S. C. 
Published: January 2011

AbstractThis paper proposes a new model for investigating the allocation of new lines in a competitive transit network in which transit operations are subject to demand uncertainty and scale economies. Scale economies imply that the operating cost of each operator per unit of transit line decreases with the number of lines operated. The proposed model explicitly considers the interactions among three types of players: transit authority, transit operators, and transit passengers. The transit authority aims to maximize the total social welfare for a given confidence level (or probabilistic guarantee) by optimizing the allocation of new lines to bidding operators. For a given allocation scheme, each of the operators determines the associated frequencies and fares to maximize its own profit at a certain confidence level while accounting for the responses of transit passengers to their strategies. The proposed line allocation model is formulated as a robust 0–1 integer programming problem that can be solved by an implicit enumeration algorithm. A numerical example is presented to illustrate the effects on the transit system of the allocation of new lines, the scale economies, the level of variation in passenger demand, and the risk attitude of transit operators toward uncertainty. Copyright © 2011 John Wiley & Sons, Ltd.
Simulation‐based analysis of personal rapid transit systems: service and energy performance assessment of the Masdar City PRT case
Authors: Mueller Katharina , Sgouridis Sgouris P. 
Published: January 2011

SUMMARYMasdar City a zero‐emission model city, is implementing a fully automated on‐demand personal rapid transit (PRT) system for its intracity transportation needs. The car‐sized electric vehicles will run on an underground road network transporting passengers and freight throughout the city. A discrete‐event PRT simulation model (miPRT) is built to support the design and implementation of the first city application of this innovative system. Through simulation, we estimate the impact of different vehicle allocation algorithms, battery charging strategies and vehicle occupancy rates and anticipate the system's behavior under stress loads to rate its capacity limitations under travel demand surges due to special events as well as track close‐down scenarios. The simulation model assists in improving fleet utilization, energy consumption, and overall system costs. Beyond the specifics of this implementation, this paper provides a tool for testing wider adoption of the PRT concept. Copyright © 2011 John Wiley & Sons, Ltd.
Ruthenium Carbene Siloxide Complexes Immobilized on Silica: Synthesis and Catalytic Activity in Olefin Metathesis
Authors: Marciniec Bogdan , Rogalski Szymon , Potrzebowski Marek J. , Pietraszuk Cezary 
Published: January 2011

AbstractRuthenium alkylidene complexes, based on second generation Hoveyda–Grubbs catalysts, have been directly attached to silica through covalent Ru‐O‐Si bonds, characterized by using cross polarization magic angle spinning 13C NMR (CP MAS 13C NMR) spectroscopy, and proved active in selected metathetic transformations. The complexes can be easily recycled and subsequently reused. In the ring closing metathesis (RCM) reaction of diethyl diallyl malonate the heterogenized complex can be recycled up to 15 times.
The quality of stakeholder engagement in sustainability reporting: empirical evidence and critical points
Authors: Manetti Giacomo 
Published: January 2011

AbstractThe aim of the article is to investigate the quality of stakeholder engagement (SE) in sustainability reporting (SR). The first part analyses the role of SE in SR according to the literature: SE is a fundamental step of the reporting process because of its role in defining materiality and relevance of the information communicated. The second part of the paper is dedicated to an empirical analysis of a sample of sustainability reports. The analysis showed that what is really applied in a wide majority of the cases is a stakeholder management approach rather than an SE approach. In the light of the above, questions for the future are if SE is moving from being a simple way to consult and influence stakeholders to an effective instrument for involving them in the company's decision making, through a mutual commitment. Copyright © 2011 John Wiley & Sons, Ltd and ERP Environment.
Stability boundary analysis of the dynamic voltage restorer in weak systems with dynamic loads
Authors: Segundo‐Ramírez Juan , Medina Aurelio , Ghosh Arindam , Ledwich Gerard 
Published: January 2011

SUMMARYIn this contribution, a stability analysis for a dynamic voltage restorer (DVR) connected to a weak ac system containing a dynamic load is presented using continuation techniques and bifurcation theory. The system dynamics are explored through the continuation of periodic solutions of the associated dynamic equations. The switching process in the DVR converter is taken into account to trace the stability regions through a suitable mathematical representation of the DVR converter. The stability regions in the Thevenin equivalent plane are computed. In addition, the stability regions in the control gains space, as well as the contour lines for different Floquet multipliers, are computed. Besides, the DVR converter model employed in this contribution avoids the necessity of developing very complicated iterative map approaches as in the conventional bifurcation analysis of converters. The continuation method and the DVR model can take into account dynamics and nonlinear loads and any network topology since the analysis is carried out directly from the state space equations. The bifurcation approach is shown to be both computationally efficient and robust, since it eliminates the need for numerically critical and long‐lasting transient simulations. Copyright © 2011 John Wiley & Sons, Ltd.
Annual banned‐substance review: analytical approaches in human sports drug testing
Authors: Thevis Mario , Kuuranne Tiia , Geyer Hans , Schänzer Wilhelm 
Published: January 2011

AbstractThe timely update of the list of prohibited substances and methods of doping (as issued by the World Anti‐Doping Agency) is an essential aspect of international anti‐doping efforts and represents consensual agreement by expert panels regarding substances and the methods of performance manipulation in sports. The annual banned‐substance review for human doping controls critically summarizes recent innovations in analytical approaches; its purpose is to improve the quality of doping controls by reporting emerging and advancing methods that focus on detecting known and recently outlawed substances. This review surveys new and/or enhanced procedures and techniques of doping analysis together with information relevant to doping control that has been published in the literature between October 2009 and September 2010. Copyright © 2011 John Wiley & Sons, Ltd.
A New Route to Azadithiolato Complexes
Authors: Angamuthu Raja , Carroll Maria E. , Ramesh Maya , Rauchfuss Thomas B. 
Published: January 2011

AbstractThe reaction of [(MeC5H4)2Ti(SH)2] with cyclic imines with the formula (CH2NR)3 gives 2‐aza‐1,3‐dithiolato chelate complexes [(MeC5H4)2Ti{(SCH2)2NR}] (1, R = Ph; 2, R = Me; 3, R = CH2Ph). These compounds demonstrate that azadithiolate ligands can exist on mononuclear metal centers. The complexes were characterized by 1H NMR spectroscopy, ESI‐mass spectrometry, and X‐ray crystallography. Variable‐temperature 1H NMR studies reveal that the dithiolate ligands undergo ring inversion like other dithiatitanacyclohexanes. Treatment of [(MeC5H4)2Ti{(SCH2)2NPh}] (1) with [Fe(benzylideneacetone)(CO)3] afforded [Fe2{(SCH2)2NPh}(CO)6] in good yield.