bluuebunny/crossref_metadata_2025_split huggingface dataset:
ANALISIS PENETAPAN HAKIM TERHADAP PENOLAKAN ASAL USUL ANAK DALAM PRESPEKTIF MAQASHID SYARI’AH
Authors: Muna Nailul 
Published: February 2025

Pada penetapan Pengadilan Agama Wonosobo ditemukan adanya penetapan permohonan penetapan asal-usul anak Nomor: 448/Pdt.P/2021/Pa.Wsb. Majelis Hakim di Pengadilan Agama Wonosobo tidak mengabulkan seluruh permohonan, penetapan tersebut sepasang suami istri ingin mensahkan anak hasil pernikahan sirri tersebut sebagai anak sah mereka. Jenis penelitian ini adalah penelitian penelitian lapangan (filed research). Data primer yang digunakan adalah berkas perkara Pengadilan Agama wonosobo Nomor: 448/Pdt.P/2021/Pa.Wsb serta melakukan wawancara dengan para Hakim yang memutus perkara.Teknik pengumpulan data yaitu wawancara dan dokumentasi. sedangkan Teknik analisis menggunakan deskriptif-analisis. Hasil penelitian sebagai berikut: 1.) penetapan pengadilan Agama Wonosobo Nomor: 448/Pdt.P/2021/PA.Wsb dalam perkara permohonan asal-usul anak masih belum mampu memberikan keadilan dan manfaat bagi masyarakat pencari keadilan. Yaitu belum bisa memberikan perlindungan terutama kepada anak tersebut, padahal anak tersebut lahir dari akibat pernikahan sirri yang sah, hanya saja pernikahan sirri tersebut menurut Hukum Negara syarat dan rukun tidak terpenuhi, karena pria tersebut “masih menjadi suami orang lain” tetapi sudah cerai lisan. Larangan atau syarat semacam ini sebenarnya adalah larangan sementara, sebagaimana dijelaskan dalam Putusan MK No. 46/PUU-VIII/2010.2) bahwa “anak yang dilahirkan di luar perkawinan mempunyai hubungan perdata dengan ibunya dan keluarga ibunya harus dibaca anak yang lahir di luar perkawinan mempunyai hubungan perdata dengan ibu dan ayah biologisnya serta kedua keluarganya” dan dan dalam presektif Maqaṣid Syari’ah putusan ini dapat menyebabkan terganggunya lima pokok dasar menurut Imam Asy-Syatibi.
Teaching Translating of Poetry: A Collaborative Approach
Authors: Sundas Shabeer  , Zohaib ur Rehman  , Muhammad Idrees  
Published: February 2025

The application of collaborative approach has investigated as a literary genre to the students speaking Urdu in this study. The approach used in this study is applied to the translation of Robert Frost’s Stopping by Woods on a Snowy Evening into Urdu language. A group of students from different colleges are taken as participants in order to see the effectiveness of this approach. ACNCS criteria is also used additionally to asses the translated text’s quality in conveying the meaning in the target text as given in the source text. Results and qualitative analysis of the study concludes in improving the results by using the collaborative approach. Albeit, some limitations are there in this approach, but it can be used by other teachers in teaching literary texts as well as non-literary texts.
Keywords: Translation, collaborative approach, source text, target text, poetry
The Implementation of School Based Inclusive Curriculum in Teaching Learning English for Slow Learners
Authors: Tri Astuti Erwina 
Published: February 2025

This research was conducted in an attempt to analyze the teacher’s understanding of School Based Inclusive Curriculum, describe the implementation of School Based Inclusive Curriculum, also to describe the problems encountered by the English teachers in implementing School Based Inclusive Curriculum at SMP Muhammadiyah I Sleman in the academic year 2017/2018.The setting of the research was in seventh and eight grade, and there were two teachers as the subjects. The research used descriptive qualitative method with in three ways collected data by doing the observation, in-depth interview and documentation.This study revealed that the teachers under study needs to improve their understanding of School Based Inclusive Curriculum, their ability in designing English syllabus and lesson plan as well as their ability in implementing School Based Inclusive Curriculum in more contextualized learning activities.The implementation of School Based Inclusive Curriculum at SMP Muhammadiyah I Sleman was succeefully but there were still some weakness and some problems to be solved. And the problems encountered the teachers can be categorized into three types; those are 1) problem in planning, 2) problem in implementing Inclusive Curriculum, 3) problem in evaluation.
Simple Spectrophotometric Method for Determination of Capsaicin in Chilis and Spicy Sauces
Authors: González-Leal Maricela , López-de-Alba Pedro Luis , Miranda Saúl Verdugo , Moller José Alberto Duarte 
Published: February 2025

A simple extractive-spectrophotometric method for the determination of Capsaicin in chilis and spicy sauces was developed. A rapid method to determining capsaicin content of capsicum fruits is desirable so that plant breeders, growers, seed companies, and especially pepper processors must be able to quickly estimate the relative pungency of their raw products to have reasonable quality assurance in their finished products. The spectral behavior of Capsaicinoids (CAP) in the micellar system of surfactants was investigated. An analytical method is proposed for the determination of CAP based on the use of Adogen-464 in toluene and measurement of the absorbance of the organic extract at 286 nm. The calibration graph was linear from 4 to 44 mg mL-1 of CAP; the detection and quantification limits were 0.259 and 0.865 mg ml-1, respectively. The method was applied to analysis of Capsaicinoids in several commercial and natural food products.
Effects of Dalcroze Eurhythmics Exercise Versus Multicomponent Exercise on Physical and Cognitive Function, and Falls in Older Adults: The EPHYCOS Randomized Controlled Trial
Authors: Hars Mélany , Fernandez Natalia , Herrmann François , Rizzoli René , Ferrari Serge , Graf Christophe , Vuilleumier Patrik , Trombetti Andrea 
Published: May 2024

AbstractCurrently, robust evidence is lacking to support one exercise type over another in the prevention of physical and cognitive decline and falls among older adults, primarily because of the lack of comparative trials of proven interventions. Therefore, a 12‐month randomized, single‐blind, comparative effectiveness trial is conducted, in which 142 older adults at high risk for falls are randomized (1:1) to receive an evidence‐based Dalcroze Eurhythmics (DE) exercise program (once weekly, group‐based) or an evidence‐based multicomponent (MULTI) exercise program incorporating balance, functional, and strength training activities (twice weekly, group‐ and home‐based), for 12 months. The primary outcome is gait variability under dual‐task at 12 months. At 12 months, the DE group has significant improvements compared with MULTI group on gait under both dual‐task (adjusted β for stride variability: −2.3, 95%CI, −3.1 to −1.4; p < 0.001) and single‐task, and on a variety of secondary physical and cognitive/executive function outcomes. The adjusted hazard ratio for falls is 0.58 (95%CI, 0.37 to 0.93) for the DE group compared with MULTI group. In conclusion, DE exercise is more effective than MULTI exercise in improving physical and cognitive function and reducing falls in older adults. The mechanisms underlying DE exercise‐induced benefits remain to be fully elucidated.
Spatially Axial Boron Coordinated Single‐Atom Nanozymes with Boosted Multi‐Enzymatic Performances for Periodontitis Treatment
Authors: Liu Wendong , Shi Enyu , Wu Hao , Liang Yanjie , Chen Mingyue , Zhang Hongyan , Zhang Ruizhong , Li Xiyan , Wang Yinsong , Zhang Libing 
Published: May 2024

AbstractSingle‐atom nanozymes (SAzymes) have made significant strides in antibacterial treatment but fall short as natural enzyme and drug replacements due to limited catalytic performance. Here, a rational strategy is presented for incorporating spatially axial boron (B) ligands to effectively modulate the local coordination environment of planar Fe─N4 motifs (Fe─B/N─C SAzymes). With electronic modulation, the Fe─B/N─C SAzymes exhibit significantly enhanced oxidase‐, peroxidase‐, and catalase‐like activities. Theoretical calculations highlight that the spatially axial B ligands effectively adjust the charge distribution around the planar Fe─N4 active center, which facilitates the heterolysis of H2O2 and the desorption of O2, resulting in accelerated H2O2 decomposition. Furthermore, the intrinsic photothermal effect of Fe─B/N─C SAzymes enhances multienzyme‐like activities, rapidly generating abundant reactive oxygen species (ROS), and achieving chemodynamic/photothermal synergistic therapy for impressive disinfection against periodontal‐related pathogenic bacteria. These findings offer a distinctive viewpoint for optimizing the local coordination environment of SAzymes with axial ligand to enhance their catalytic performance and effectiveness in periodontitis therapy.
A Hydrogel Dressing Comprised of Silk Fibroin, Ag Nanoparticles, and Reduced Graphene Oxide for NIR Photothermal‐Enhanced Antibacterial Efficiency and Skin Regeneration
Authors: Yan Shaorong , Xu Shuo , Wang Yu , You Jun , Guo Chuanlong , Wu Xiaochen 
Published: May 2024

AbstractBacterial infection, inflammation, and excessive oxidative stress are the primary factors that contribute to delayed healing of skin wounds. In this study, a multifunctional wound dressing (SF/Ag@rGO hydrogel) is developed to promote the healing of infected skin wounds by combining the inherent antibacterial activity of Ag nanoparticles (NPs) with near‐infrared (NIR)‐assisted antibacterial therapy. Initially, L‐ascorbic acid is used as a reducing agent and PVP‐K17 as a stabilizer and dispersant, this facilitates the synthesis of reduced graphene oxide loaded with Ag NPs (Ag@rGO). Ag@rGO is then blended with a silk fibroin (SF) solution to form an instantly gelling SF/Ag@rGO hydrogel that exhibits rapid self‐healing, injectability, shape adaptability, NIR responsiveness, antioxidant, high tissue adhesion, and robust mechanical properties. In vitro and in vivo experiments show that the SF/Ag@rGO hydrogel demonstrates strong antioxidant and photothermal antibacterial capabilities, promoting wound healing through angiogenesis, stimulating collagen generation, alleviating inflammation, antioxidant, and promoting cell proliferation, indicating that the SF/Ag@rGO hydrogel dressing is an ideal candidate for clinical treatment of full‐thickness bacterial‐stained wounds.
Bio‐Inspired Sensory Receptors for Artificial‐Intelligence Perception
Authors: Bag Atanu , Ghosh Gargi , Sultan M. Junaid , Chouhdry Hamna Haq , Hong Seok Ju , Trung Tran Quang , Kang Geun‐Young , Lee Nae‐Eung 
Published: May 2024

AbstractIn the era of artificial intelligence (AI), there is a growing interest in replicating human sensory perception. Selective and sensitive bio‐inspired sensory receptors with synaptic plasticity have recently gained significant attention in developing energy‐efficient AI perception. Various bio‐inspired sensory receptors and their applications in AI perception are reviewed here. The critical challenges for the future development of bio‐inspired sensory receptors are outlined, emphasizing the need for innovative solutions to overcome hurdles in sensor design, integration, and scalability. AI perception can revolutionize various fields, including human–machine interaction, autonomous systems, medical diagnostics, environmental monitoring, industrial optimization, and assistive technologies. As advancements in bio‐inspired sensing continue to accelerate, the promise of creating more intelligent and adaptive AI systems becomes increasingly attainable, marking a significant step forward in the evolution of human‐like sensory perception.
Symmetry Reduction of Molecular Shape of Cationic Chromophores for High‐Performance Terahertz Generators
Authors: Yoon Ga‐Eun , Kim Dong‐Joo , Park Yu‐Jin , Kim Chaeyoon , Kim Seung‐Jun , Shin Bong‐Rim , Lee Yun‐Sang , Lee Chae‐Won , Park Jung‐Wook , Yu In Cheol , Yoon Woojin , Yun Hoseop , Kim Dongwook , Jazbinsek Mojca , Rotermund Fabian , Kwon O‐Pil 
Published: May 2024

AbstractThe symmetry reduction of molecular shape of cationic chromophores as a design strategy to develop organic terahertz (THz) generators is used. Electron donating group (EDG) with an asymmetric shape is introduced into two types of cationic styryl‐quinolinium chromophores, leading to the development of several novel non‐centrosymmetric crystals with high macroscopic optical nonlinearity. In contrast, when an EDG with a symmetric shape is introduced, centrosymmetric crystal structure is obtained in all investigated crystals. For THz wave generation, crystals based on asymmetrically shaped EDG exhibit several optimal crystal characteristics, including a plate‐shape morphology, a large size, and an in‐plane polar axis. Furthermore, over the entire range of molecular phonon vibrations, 0.5–4 THz, the steric hindrance group in the asymmetrically shaped EDG has a strong influence on the suppression of THz phonon vibrations, leading to a low THz absorption coefficient. The crystals based on asymmetrically shaped EDG generate an ≈40 times stronger THz electric field than the inorganic ZnTe crystal and very broad THz spectra, extending up to 16 THz. Thus, the symmetry reduction of the molecular shape of cationic chromophores through the introduction of an asymmetrically shaped EDG is an effective design approach for the development of novel organic THz crystals.
Modulating the Transmission of Light Using Asymmetric Janus Particles
Authors: Sullivan Patrick A. , Lee Ji‐Young , da Mota Achiles , Malampy Rachel C. , Mu Yijiang , Lee Daeyeon , Mosallaei Hossein , Wilson Daniel J. , Deravi Leila F. 
Published: May 2024

AbstractThe ability to manipulate the absorption, scattering, or reflectivity of light using synthetic materials has inspired innovations in nano‐ and micro‐materials for applications ranging from geoengineering to display optics. Asymmetric materials, like Janus particles, offer one solution to meet the needs of such technologies, as composition and geometry can be optimized to maximize directional optical properties in response to magnetic and/or electric fields, light, or electrostatic charge. In this work, a gram‐scale synthesis is applied to generate Janus matchstick particles comprising a gold head with a silica rod. Conditions are explored and optimized to elicit rotation of these matchstick particles under an alternating current (AC) electric field with varying field strength and frequency to maximize particle alignment. While only modest changes in transmission (≈8%) are observed over the visible spectral region with a bare silica rod, the application of an absorbing element increased transmission changes up to ≈23% demonstrating their utility as color‐changing materials. Experimental results are supported by theory and computation and highlight an important first step in activating directional optical effects in these materials which can be optimized for future adaptive technologies.
Air‐Stable 2D van der Waals MgTeMoO6 Exhibits Strong In‐plane Optical Anisotropy
Authors: Liu Wei , Du Zhipeng , Ahmed Belal , Zhao Yunqi , Zheng Jieyu , Song Xianyu , Wang Ziyi , Kuang Xiaojun , Luo Junhua , Zhao Sangen 
Published: May 2024

AbstractExploring 2D van der Waals (vdW) materials is of great importance to the various optoelectronics‐based applications. Herein, mono‐ and few‐layer nanoflakes of a novel 2D vdW MgTeMoO6 are prepared by facile mechanical exfoliation method. These nanoflakes remain highly stable when being exposed in air even for 1 month, which is unique compared to most of 2D materials. Temperature‐dependent Raman spectroscopy reveals that 2D MgTeMoO6 nanosheets exhibit stronger interlayer interaction than that of graphene. In situ, angle‐resolved polarized Raman spectroscopy investigation show evidences for the anisotropic photo–phonon interactions. Notably, strong in‐plane anisotropy for the second harmonic generation (SHG) independent of layer number is observed for 2D MgTeMoO6, making 2D MgTeMoO6 promising in polarization‐sensitive optoelectronic applications.
Functional Construction of a Novel Lanthanide MOF for Efficient Ratio Luminescence Detection of Ethanol Vapor
Authors: Sun Yiliang , Wang Xiaoyan , Liu Shiying , Yang Xiaoshan , Ren Xiaoyu , Liu Wei , Liu Weisheng 
Published: May 2024

AbstractIt is necessary to develop excellent sensors for volatile organic compounds (VOCs) detection from the perspective of environmental protection and human health. Luminescent lanthanide metal‐organic frameworks (MOFs) have many advantages such as porosity, luminescence, and structural controllability, making them very suitable as luminescent sensing materials. Based on a functional oriented strategy, novel Ln‐MOFs are successfully constructed and their structure and properties are characterized in detail. A series of vapor luminescence sensing tests have shown that Eu/Tb doped L1‐Eu0.1/Tb0.9 not only exhibits high selectivity for alcohols, especially ethanol vapor, but also has high sensitivity and extremely low detection limit (9.76 mg L−1). To the knowledge, there are no reports on ratio luminescence sensors based on Ln‐MOFs for ethanol vapor, especially those with such excellent performance. Crystal structure determination demonstrates that ethanol binds to the framework through multiple hydrogen bonding interactions, altering the energy transfer efficiency between Tb3+ and Eu3+ to achieve ratio luminescence detection. In addition, L1‐Eu0.1/Tb0.9 has good repeatability, the prepared thin film sensing material also demonstrates the advantages of portability and processability. This work can provide some experience for the development of VOCs sensing materials with better performance.
[2.2]Paracyclophanes: From Selective Functionalization to Optical Properties
Authors: Wu Shiqi , Felder Simon , Brom Jules , Pointillart Fabrice , Maury Olivier , Micouin Laurent , Benedetti Erica 
Published: May 2024

AbstractSince their discovery, [2.2]paracyclophane (pCp) and its derivatives have fascinated the scientific community due to their original molecular architecture and unusual electronic behavior. Over the years, significant efforts have been devoted to the development of substituted pCps for a variety of applications in different fields, ranging from organic synthesis and asymmetric catalysis to polymer chemistry and material science. This review describes a series of useful approaches that allow chemists to selectively decorate pCps, control the planar chirality that these molecules can display as soon as they are functionalized, and tune their photophysical behaviors. For each of these aspects of paracyclophane chemistry, selected examples of major advances are presented, and possible directions for future research are outlined. The application of pCp as central core for the development of uncommon 3D luminophores is finally highlighted. Emphasis is placed on the potential use of planar chiral luminescent paracyclophanes as antennas or ligands for the design of multifunctional lanthanide complexes, a quite underdeveloped but highly promising area for future research endeavors.
Dendrite‐Free Lithium‐Metal Batteries Enabled by 2D Lithophilic Conjugated Polymer on Separator
Authors: Wang Ke , Zhao Teng , Lv Ruixin , Tang Wangming , Yu Tianyang , Chen Guoshuai , Li Li , Wu Feng , Chen Renjie 
Published: May 2024

AbstractTacking issues of uncontrolled lithium dendrites formation with polymer‐based separator has a significant impact on the applications of lithium‐metal batteries. Here, porous poly(acrylonitrile) nanosheets (PPNS) enriched with conjugated C═C/C═N groups is designed on PP separator by spray‐coating. The conjugated molecular structure of PPNS affords high mechanical strength and thermal conductivity. Density functional theory (DFT) calculations confirm that polar N‐containing groups in PPNS derived from the cyclization of C≡N exhibit lithiophilic properties and effectively accelerate Li+ transport kinetics. Finite element simulation indicates PPNS with porous 2D nanosheet structure ensures a sufficient and uniform concentration of Li+ on the anode surface. Besides, a rich inorganic phase solid‐electrolyte interphase forms at the lithium metal interface under the induction of N‐containing groups, which further facilitates uniform lithium deposition. As a result, Li||LFP battery using PPNS@PP separator can stably cycle for 300 cycles at a high rate of 3C, with a capacity retention rate of 94.0%. Moreover, the Li||LFP pouch battery with PPNS@PP separator achieves steady cycling for 100 cycles at 0.2C, with a capacity retention rate of 95.7%.
Active Oxygenated Structure‐Intensified CO2 Capture Enables Efficient Electrochemical Ethylene Production Over Carbon Nanofibers
Authors: Zhang Tingting , Wang Jun , Shang Huishan , Zhang Bing , Huang Yanqiang , He Jing , Xiang Xu 
Published: May 2024

AbstractThe pursuit of high efficacy C−C coupling during the electrochemical CO2 reduction reaction remains a tremendous challenge owing to the high energy barrier of CO2 activation and insufficient coverage of the desired intermediates on catalytic sites. Inspired by the concept of capture‐coupled CO2 activation, we fabricated quinone‐grafted carbon nanofibers via an in situ oxidative carbonylation strategy. The quinone functionality of carbon nanofibers promotes the capture of CO2 followed by activation. At a current density of 400 mA cm−2, the Faradaic efficiency of ethylene reached 62.9 %, and a partial current density of 295 mA cm−2 was achieved on the quinone‐rich carbon nanofibers. The results of in situ spectroscopy and theoretical calculations indicated that the remarkable selectivity enhancement in ethylene originates from the quinone structure, rather than the electronic properties of Cu particles. The interaction of quinone with CO2 increases the local *CO coverage and simultaneously hinders the co‐adsorption of *H on Cu sites, which greatly reduces the energy barrier for C−C coupling and restrains subsequent *CO protonation. The modulation strategy involving specific oxygenated structure, as an independent degree of freedom, guides the design of functionalized carbon materials for tailoring the selectivity of desired products during the CO2 capture and reduction.
A Gold(I)–Acetylene Complex Synthesised using Single‐Crystal Reactivity
Authors: Johnson Chloe L. , Storm Daniel J. , Sajjad M. Arif , Gyton Matthew R. , Duckett Simon B. , Macgregor Stuart A. , Weller Andrew S. , Navarro Miquel , Campos Jesús 
Published: May 2024

AbstractUsing single‐crystal to single‐crystal solid/gas reactivity the gold(I) acetylene complex [Au(L1)(η2‐HC≡CH)][BArF4] is cleanly synthesized by addition of acetylene gas to single crystals of [Au(L1)(CO)][BArF4] [L1=tris‐2‐(4,4′‐di‐tert‐butylbiphenyl)phosphine, ArF=3,5‐(CF3)2C6H3]. This simplest gold‐alkyne complex has been characterized by single crystal X‐ray diffraction, solution and solid‐state NMR spectroscopy and periodic DFT. Bonding of HC≡CH with [Au(L1)]+ comprises both σ‐donation and π‐backdonation with additional dispersion interactions within the cavity‐shaped phosphine.