Representing Reservoir Oil Using Recombination Techniques
Authors: Thomas F.B. , Shtepani E. , Imer D. , Bennion D.B. 
Published: March 2010

Abstract
The approach to reservoir optimization often begins with the appropriate characterization of the reservoir fluid. Deficiencies in sampling methods may lead to erroneous conclusions regarding the fluids in situ and, therefore, the exploitation strategies considered. Moreover, once sampled, the way in which fluids are recombined is often inadequate. Frequently, bottomhole samples are also problematic and must be analyzed correctly in order to infer the appropriate information about the reservoir system.
This paper discusses sampling and recombination methods that improve the representation of reservoir fluids. A number of examples are provided where standard approaches to characterization are inadequate and a protocol of recombination is presented. The benefits of the approach are shown. The impact of characterization is also shown relative to allowable production rates and adherence to regulatory edicts.

Introduction
Much of the engineering that is involved in the development and exploitation of reservoirs worldwide depends on representative fluid samples. Whether it is the measurement of PVT properties such as density (ρ), formation volume factor (βo), viscosity (μ), interfacial tension (IFT), gas-oil ratio (GOR) or compressibility (c), or the generation of relative permeability relationships or the assessment of enhanced oil recovery (EOR) strategies, each of these endeavors requires a representative reservoir fluid. Although it may seem that the method for the acquisition of a representative reservoir fluid would be straightforward, it is surprising to see the number of fluid characterizations that are incorrect due to an unrepresentative fluid sample. This deficiency then carries through to all of the analyses that are performed and consequently, the results of the engineering may be in error primarily due to the fluid with which the work commenced. Thus, it is important to establish a reliable protocol for the preparation of representative reservoir fluid.
Oil and gas reservoir opportunities are distributed amongst a number of different fluid types. The oils may be heavy oil containing very little gas and very heavy, high-density components, more conventional oils, containing components that are easily partitioned into the gas phase or, volatile oils where the difference between the gas phase and the liquid phase is much less pronounced. A typical reservoir fluid phase envelope is shown in Figure 1. While each fluid system will have its own unique phase envelope, Figure 1 should suffice for demonstration. Oil systems exist to the left of the critical point on the phase loop. As one moves to the right of the critical point, the classification of fluid moves to very rich condensates, to retrograde condensates, to wet gas and finally to dry gas.
The extremes on either side of the critical point are easy fluids to represent. Heavy oil has almost exclusively methane in the solution gas and C20+ in the liquid. There is very little "gray area" in classifying these fluids. Heavy oils do not normally have characterization difficulties since the solution gas is almost always at least 90% methane; in which case, recombination methods do not significantly impact the recombined oil properties. Dry gas has only gas-phase components and therefore these gases are easy to sample and to represent.