bluuebunny/crossref_metadata_2025_split huggingface dataset:
Investigation of group 13 elements as potential candidates for p-type dopants in the narrow-gap thermoelectric semiconductor α-SrSi2
Authors: Kunioka Haruno , Shiojiri Daishi , Takahashi Shinta , Hiratsuka Kota , Yamaguchi Masato , Hirayama Naomi , Imai Yoji , Imai Motoharu , Iida Tsutomu 
Published: April 2024

AbstractTo investigate the possibility of p-type doping of α-SrSi2, a promising as an eco-friendly thermoelectric material, the energy changes of substitutions of the Si site of α-SrSi2 by group 13 elements were evaluated using first-principles calculations. It is found that Ga doping was the most energetically favorable dopant while In is the most unfavorable. We examined the synthesis of Ga- and In-doped α-SrSi2 using the vertical Bridgeman method and investigated their thermoelectric properties. The Ga atoms were doped to α-SrSi2 successfully up to 1.0 at. %, while In atoms could not be doped as suggested by calculations. For experimental prepared Ga-doped samples, the carrier density was observed to increase with Ga doping, from 3.58 × 1019 cm−3 for undoped α-SrSi2 to 4.49 × 1020 cm−3 for a 1.0 at. % Ga-doped sample at 300 K. The temperature dependence of carrier concentrations was observed to change from negative to positive with increasing Ga content. In addition, the temperature dependence of the Seebeck coefficient was also observed to change from negative to positive with increasing Ga content. The results indicate that α-SrSi2 undergoes a semiconductor–metal transition with Ga doping. The power factor for the undoped sample was quite high, at 2.5 mW/mK2, while the sample with 0.3 at. % Ga had a value of 1.1 mW/mK2 at room temperature.
Evaluation of PVC@Silver Nanocomposite as Sensor for Low Limit Detection of Cadmium Ion By Surface Plasmon Resonance Based Method
Authors: Ali Safaa S. , Ebnalwaled A. A. , Mohamed Gehad G. , Hafez M. 
Published: April 2024

AbstractThis study explores the development of a PVC@Silver nanocomposite for enhanced detection of cadmium ions in water samples. Various characterization techniques confirmed the successful incorporation of silver nanoparticles into the polyvinyl chloride (PVC) matrix across different concentrations (1–4%). X-ray diffraction revealed the face-centered cubic crystalline structure of the silver nanoparticles, with the intensities of the (111), (200), (220), and (311) peaks increasing with higher Ag concentrations. The average crystallite sizes ranged from 26.1 nm (3% Ag) to 30.0 nm (2% Ag). Dynamic light scattering showed nanoparticle sizes of 24–43 nm, while zeta potential values of -24 to -40 mV indicated reasonable colloidal stability. Brunauer–Emmett–Teller (BET) surface area analysis demonstrated a decreasing surface area from 30.09 m2/g (1% Ag) to 25.27 m2/g (3% Ag), attributed to pore filling by silver nanostructures. Significantly, the PVC@Silver nanocomposite facilitated sensitive detection of Cd(II) ions using surface plasmon resonance (SPR), exhibiting an SPR angle shift of 26.30° with intensity values ranging from 10.80 (4% Ag) to 12.19 (3% Ag). UV–vis spectra revealed a prominent surface plasmon resonance band at 420–430 nm, indicating the presence of silver nanoparticles. The optical band gap varied from 4.51eV (1% Ag) to 4.12eV (4% Ag).
Divergence in diversity-area relationships between lawn and non-lawn plants in residential landscapes
Authors: Russo Kacey A. , Vasconcelos Vitor V. , Jones Jesse C. , Malakhova Olesya , Broadbent Eben N. , Colee James , Dale Adam G. , Qiu Jiangxiao , Taylor Nicholas W. , Wilber Wendy L. , Iannone Basil V. 
Published: April 2024

Abstract
Context
In residential landscapes, people acknowledge and manage larger, conventionally attractive plants differently than smaller, less conspicuous ones, possibly leading to a divergence in basic ecological patterns such as diversity-area relationships.

Objectives
We tested for divergences between lawn and non-lawn plants, and compared perceived and actual species richness in residential yards. We hypothesized that: (1) homeowner perception of plant species richness is more related to the actual species richness of non-lawn plants than lawn plants, and (2) alpha diversity will increase more rapidly, and beta diversity will decrease less rapidly for non-lawn plants than lawn plants with increasing spatial scale.

Methods
We recorded all plant species in four 5 × 5 m plots in the front and back yards of 30 residences within four neighborhoods of Gainesville, Florida, United States (N = 238 plots). We also surveyed residents regarding perceived plant species richness in their yards.

Results
We detected 386 non-lawn and 140 lawn species. Perceived plant species richness was positively related to non-lawn species richness and negatively related to lawn species richness, suggesting perception of species richness largely reflected that of non-lawn plants. Alpha diversity increased more rapidly, while beta diversity decreased less rapidly, for non-lawn plants than lawn plants with increasing spatial scale, although lawns had more species within individual yards.

Conclusions
Findings revealed a divergence in diversity-area relationships between different plant groups in residential landscapes. We should consider the ecological implications of unrecognized plant diversity, particularly in residential lawns, where management often strives to limit plant species richness.
Development of a Csy4-Processing TRV-Based CRISPR/Cas9 Genome Editing System in Nicotiana benthamiana
Authors: Luo Yanjie , Tang Xiaodong , Yu Cuihong , Qiu Yang , Nowak Julia S. , Lu Qing Shi , Tian Lining , Na Ren 
Published: April 2024

AbstractThe CRISPR/Cas9 system is a site-specific genome editing tool that has been widely used in various plant species. The plant virus-based gRNA (guide RNA) delivery system, which differs from the typical Agrobacterium-mediated transformation, is an attractive method to facilitate the application of CRISPR/Cas9. The virally delivered gRNA is usually driven by heterologous plant U6 or viral promoters (e.g., pea early-browning virus, PEBV; barley stripe mosaic virus, BSMV). However, heterologous promoters may have poor performance in some cases. In this paper, a feasible option to detach gRNA(s) from the virus genome is employed. Specifically, the Csy4-RNA processing system is used to release gRNA(s) from the tobacco rattle virus (TRV). The coding sequences of Cas9 and Csy4 nucleases are cloned into a single polycistronic expression cassette under an estrogen-inducible promoter in a binary vector, and the gRNA is cloned into the TRV genome flanked by two 20 bp Csy4 recognition sites. The results show that the Csy4-processing TRV-based delivery system works effectively in targeting single and multiple sites, nucleotide replacement, and large fragment deletion in Cas9-mediated genome editing via transient expression in Nicotiana benthamiana. The Csy4-TRV is a promising gRNA(s) processing and delivery system for CRISPR/Cas9 genome editing. This method can be easily adapted to other plant RNA viruses, facilitating the application of the CRISPR/Cas9 system in plants.
Intrinsic Harnack’s Inequality for a General Nonlinear Parabolic Equation in Non-divergence Form
Authors: Kurkinen Tapio , Siltakoski Jarkko 
Published: April 2024

Abstract
We prove the intrinsic Harnack’s inequality for a general form of a parabolic equation that generalizes both the standard parabolic p-Laplace equation and the normalized version arising from stochastic game theory. We prove each result for the optimal range of exponents and ensure that we get stable constants.
k-Positivity and Schmidt number under orthogonal group symmetries
Authors: Park Sang-Jun , Youn Sang-Gyun 
Published: April 2024

AbstractIn this paper, we present a new application of group theory to develop a systematical approach to efficiently compute the Schmidt numbers. The Schmidt number is a natural quantification of entanglement in quantum information theory, but computing its exact value is generally a challenging task even for very concrete examples. We exhibit a complete characterization of all orthogonally covariant k-positive maps. This result generalizes earlier results by Tomiyama (Linear Algebra Appl 69:169–177, 1985). Furthermore, we optimize duality relations between k-positivity and Schmidt numbers under group symmetries. This new approach enables us to transfer the results of k-positivity to the computation of the Schmidt numbers of all orthogonally invariant quantum states.
Philosophical Reflections on Teachers’ Ethical Dilemmas in a Global Pandemic
Authors: Gurr Sarah K. , Geron Tatiana , Forster Daniella J. , Levinson Meira 
Published: April 2024

AbstractThe COVID-19 pandemic raised not only overwhelming practical challenges but also deep ethical dilemmas for educators. There have been few efforts to connect these challenges to either ethical dilemmas teachers faced in pre-pandemic times or to philosophical analyses of complex normative terrain of teachers’ work. We facilitated eleven discussion groups with 101 educators from seven countries on the dilemmas they faced due to COVID-19. Analysis of these sessions reveals how the pandemic amplified, exacerbated and augmented pre-pandemic educational dilemmas in ways that recalibrated teachers’ core values and beliefs, and highlights the importance of engaging teachers in ethical dialogue.
The foundation for investigating factor XI as a target for inhibition in human cardiovascular disease
Authors: Ali Ahmed E. , Becker Richard C. 
Published: April 2024

AbstractAnticoagulant therapy is a mainstay in the management of patients with cardiovascular disease and related conditions characterized by a heightened risk for thrombosis. Acute coronary syndrome, chronic coronary syndrome, ischemic stroke, and atrial fibrillation are the most common. In addition to their proclivity for thrombosis, each of these four conditions is also characterized by local and systemic inflammation, endothelial/endocardial injury and dysfunction, oxidative stress, impaired tissue-level reparative capabilities, and immune dysregulation that plays a critical role in linking molecular events, environmental triggers, and phenotypic expressions. Knowing that cardiovascular disease and thrombosis are complex and dynamic, can the scientific community identify a common pathway or specific point of interface susceptible to pharmacological inhibition or alteration that is likely to be safe and effective? The contact factors of coagulation may represent the proverbial “sweet spot” and are worthy of investigation. The following review provides a summary of the fundamental biochemistry of factor XI, its biological activity in thrombosis, inflammation, and angiogenesis, new targeting drugs, and a pragmatic approach to managing hemostatic requirements in clinical trials and possibly day-to-day patient care in the future.
Single nucleotide polymorphisms of growth hormone gene in cattle and their association with growth traits: a systematic review
Authors: Bila Lubabalo , Malatji Dikeledi Petunia , Tyasi Thobela Louis 
Published: April 2024

AbstractGrowth traits in livestock animals are quantitative parameters, which are often controlled by many genes including growth hormone (GH) gene. However, the evidence of effect of GH gene on growth traits of cattle is poorly understood. Hence, the objective of the study was to systematically investigate the literature on single nucleotide polymorphisms (SNPs) of GH gene and their association with growth traits in cattle from four databases Google Scholar, PubMed, ScienceDirect, and Web of Science. The results indicated that fifteen (n = 15) articles with 27% of them from Indonesia qualified to be used in this study after screening. The results revealed five SNPs (1047T > C, 1180 C > T, 86,273,136 A/G, 3338 A > G and 4251 C > T) occurred across multiple investigated breeds with no common identified SNPs. Six articles observed a significant difference (p < 0.05) between growth traits and genotypes of identified SNPs. The findings showed that 7 articles (47%) investigated body weight (BW) with 6 (40%) of them found non-significant and 1 (7%) found a significant association with genotypes of the identified SNPs (3338 A > G). While 7 articles (47%) investigated weaning weight (WW) with 5 (33%) of them revealed a non-significant and 2 (13%) found a significant association with genotypes of identified SNPs (3338 A > G and 4251 C > T). This study shows that there is a lack of evidence on effect of growth hormone gene on growth traits in cattle. However, more studies are recommended for further validation of the identified SNPs and effect of growth hormone gene on growth traits in cattle.
Changes in biomarkers of the redox status in whole blood and red blood cell lysates in canine hypothyroidism
Authors: González-Arostegui L. G. , Muñoz-Prieto A. , García-López G. , Cerón J. J. , Tvarijonaviciute A. , Rubio C. P. 
Published: April 2024

AbstractHypothyroidism is the most commonly diagnosed endocrine disease in dogs. The objective of this study was to evaluate the changes in the redox status in canine hypothyroidism using whole blood (WB) and red blood cell (RBCs) lysates. For this purpose, a panel of five antioxidants and five oxidants biomarkers was measured in WB and RBCs lysates of 30 dogs with hypothyroidism, 26 dogs with non-thyroidal illnesses and 15 healthy dogs. The antioxidants measured were cupric reducing antioxidant capacity (CUPRAC), ferric reducing ability of plasma (FRAP), Trolox equivalent antioxidant capacity (TEAC), thiol and paraoxonase type-1 (PON-1). Oxidants measured include the total oxidant status (TOS), peroxide-activity (POX-Act), reactive oxygen-derived metabolites (d-ROMs), advanced oxidation protein products (AOPP) and thiobarbituric acid reactive substances (TBARS). WB showed a significant decrease of the antioxidants CUPRAC, TEAC and thiol, and also an increase in TBARS and a decrease in AOPP in dogs with hypothyroidism compared to healthy dogs. Meanwhile, RBCs lysates showed a significant increase in FRAP and PON-1 in dogs with hypothyroidism. The changes in the redox biomarkers in this study show that WB in canine hypothyroidism had a higher number of changes in biomarkers of the redox status than RBCs lysates, making it a promising sample type for the evaluation of the redox status in this disease. In addition, WB is easier and simpler to process than RBCs lysates and unlike serum, it does not have any hemolysis interference.
On the Occurrence of Extreme Rainfall Events Across Italy: Should We Update the Probability of Failure of Existing Hydraulic Works?
Authors: Moccia Benedetta , Ridolfi Elena , Mineo Claudio , Russo Fabio , Napolitano Francesco 
Published: April 2024

AbstractEvery year, extreme rainfall events cause human deaths and economic losses around the world. Risk reduction strategies may involve the implementation of structural measures that are widely extended and financial relevant. Despite the high reliance on these mitigation measures, there might occur instances of overload, i.e. events with intensities exceeding the design value of these structures, that may have catastrophic consequences. In this framework, it is crucial to improve hydraulic works management, thus, we introduce a procedure at rain gauge scale for revising design variables throughout their operational lifespan. This enables us to enhance the assessment of the probability of failure of these works. Finally, we investigate instances where design variables experience overload during the recording period, thus assessing the occurrence of rare yet possible events. To this aim we find the most-suitable probability distribution to describe daily rainfall maxima in Italy. Specifically, we test the performance of four widely used bi-parametrical distributions with different tail behaviour, by analysing an impressive dataset consisting of 2282 rain gauges observations from 1860 to 2022. Our results show that: (1) 78% of the empirical samples exhibits heavy-tail behaviour; (2) when the update procedure is applied, 64% of the samples shows a higher-than-expected probability of failure; (3) at least one case of overload associated to a 100-years return period is recorded in almost all regions. Based on our results, existing hydraulic works designed to safeguard populations and their activities from catastrophic events may face a higher risk of failure than initially expected.
Validation of self-applied unattended polysomnography using Somte V2 PSG (Somte) for diagnosis of obstructive sleep apnoea (OSA) in pregnant women in early to mid-gestation
Authors: Clements Frances , Makris Angela , Chung Yewon , Poh Jonathon , Marshall Nathaniel S. , Melehan Kerri , Shanmugalingam Renuka , Hennessy Annemarie , Vedam Hima 
Published: April 2024

Abstract
Purpose
Polysomnography (PSG) may be completed in the home environment (unattended), and when self-applied, allow the collection of data with minimal healthcare worker intervention. Self-applied, unattended PSG in the home environment using Somte PSG V2 (Somte) has not been validated in pregnant women in early to mid-gestation. We undertook a study to evaluate the accuracy of Somte compared to attended PSG. The agreement between apnoea hypopnea index (AHI) and respiratory disturbance index (RDI) scores in Somte and PSG in early to mid-gestation were assessed.

Methods
Pregnant women (≤ 24 weeks gestation) were scheduled for PSG and Somte within a 7-day window, in any order. Somte were self-applied and completed in the home. Somte were scored blinded to PSG result. AHI was the primary outcome of interest, though an AHI ≥ 5 or RDI ≥ 5 on PSG was considered diagnostic of Obstructive Sleep Apnoea (OSA). AHI, RDI, sensitivity, specificity, positive predictive value (PPV), negative predictive value (NPV) was calculated and receiver operating characteristic (ROC) curves were produced. Bland–Altman plots were used to determine agreement. Technical issues occurring during tests were explored.

Results
Twenty-four participants successfully completed both tests between March 2021 and January 2023. PSG were completed at around 14.1 weeks’ gestation (IQR 13.4, 15.7). The time interval between Somte and PSG was a median of 4 days (IQR 2, 7 (range 1–12)). Five (20.8%) women had OSA on PSG at AHI ≥ 5 and 10 (41.6%) women had OSA on PSG at RDI ≥ 5. Somte and PSG did not differ in the measurement of AHI ((1.8, 1.6, p = 0.09) or RDI (3.3, 3.5), p = 0.73).
At AHI ≥ 5, diagnostic test accuracy (area under the ROC curve) of Somte was 0.94, sensitivity 80.0%, specificity 94.7%, PPV and NPV were 80.0% and 94.7% respectively. At RDI ≥ 5, diagnostic test accuracy (area under the ROC curve) was 0.95, sensitivity 60.0%, specificity 93.0% and PPV and NPV were 85.7% and 76.4% respectively. The confidence limits of Bland–Altman plots were 6.37 to − 8.89 at cut off AHI ≥ 5 and 8.89 to − 10.43 at cut off RDI ≥ 5. Somte failed to start in four tests. Technical issues were reported in both Somte (n = 13, 54.2%) and PSG (n = 6, 25.0%).

Conclusion
Self-applied, unattended Somte may provide an acceptable substitute to attended PSG in the identification of OSA in pregnant women in early to mid-gestation in this small sample but may fail to detect cases of OSA, particularly when using RDI as the diagnostic marker.
Sequestration of Pb(II) using channel-like porous spheres of carboxylated graphene oxide-incorporated cellulose acetate@iminodiacetic acid: optimization and mechanism study
Authors: El-Monaem Eman M. Abd , Gomaa Hassanien , Omer Ahmed M. , El-Subruiti Gehan M. , Eltaweil Abdelazeem S. 
Published: April 2024

AbstractThe adsorption property of the costless green cellulose acetate (CA) was boosted by the dual modifications: inner modification by incorporating carboxylated graphene oxide (COOH-GO) into the CA spheres and outer modification by the surface modification of the COOH-GO@CA spheres by iminodiacetic acid (IDA) for removing Pb(II). The adsorption experiments of the Pb(II) proceeded in a batch mode to evaluate the adsorption property of the COOH-GO@CA@IDA spheres. The maximal Pb(II) adsorption capacity attained 613.30 mg/g within 90 min at pH = 5. The removal of Pb(II) reached its equilibrium within 20 min, and the removal % was almost 100% after 30 min at the low Pb(II) concentration. The Pb(II) adsorption mechanism was proposed according to the kinetics and isotherms studies; in addition, the zeta potential (ZP) measurements and X-ray Photoelectron Spectroscopy (XPS) analysis defined the adsorption pathways. By comparing the XPS spectra of the authentic and used COOH-GO@CA@IDA, it was deduced that the contributed chemical adsorption pathways are Lewis acid–base, precipitation, and complexation. The zeta potential (ZP) measurements demonstrated the electrostatic interaction participation in adsorbing the cationic Pb(II) species onto the negatively charged spheres (ZP = 14.2 mV at pH = 5). The unique channel-like pores of the COOH-GO@CA@IDA spheres suggested the pore-filling mechanism of Pb(II). The promising adsorption results and the superb recyclability character of COOH-GO@CA@IDA enable it to extend of the bench scale to the industrial scale.
Modeling and experimental analysis of CO2 methanation reaction using Ni/CeO2 monolithic catalyst
Authors: Parra-Marfil Adriana , Ocampo-Pérez Raúl , Aguilar-Madera Carlos Gilberto , Carrasco-Marín Francisco , Pérez-Cadenas Agustín Francisco , Bueno-López Agustín , Bailón-García Esther 
Published: April 2024

AbstractIn this study, the effect of the cell density of monolithic catalysts was investigated and further mathematically modeled on cordierite supports used in CO2 methanation. Commercial cordierite monoliths with 200, 400, and 500 cpsi cell densities were coated by immersion into an ethanolic suspension of Ni/CeO2 active phase. SEM–EDS analysis confirmed that, owing to the low porosity of cordierite (surface area < 1 m2 g−1), the Ni/CeO2 diffusion into the walls was limited, especially in the case of low and intermediate cell density monoliths; thus, active phase was predominantly loaded onto the channels’ external surface. Nevertheless, despite the larger exposed surface area in the monolith with high cell density, which would allow for better distribution and accessibility of Ni/CeO2, its higher macro-pore volume resulted in some introduction of the active phase into the walls. As a result, the catalytic evaluation showed that it was more influenced by increments in volumetric flow rates. The low cell density monolith displayed diffusional control at flow rates below 500 mL min−1. In contrast, intermediate and high cell density monoliths presented this behavior up to 300 mL min−1. These findings suggest that the interaction reactants-catalyst is considerably more affected by a forced non-uniform flow when increasing the injection rate. This condition reduced the transport of reactants and products within the catalyst channels and, in turn, increased the minimum temperature required for the reaction. Moreover, a slight diminution of selectivity to CH4 was observed and ascribed to the possible formation of hot spots that activate the reverse water–gas shift reaction. Finally, a mathematical model based on fundamental momentum and mass transfer equations coupled with the kinetics of CO2 methanation was successfully derived and solved to analyze the fluid dynamics of the monolithic support. The results showed a radial profile with maximum fluid velocity located at the center of the channel. A reactive zone close to the inlet was obtained, and maximum methane production (4.5 mol m−3) throughout the monolith was attained at 350 °C. Then, linear streamlines of the chemical species were developed along the channel.