bluuebunny/crossref_metadata_2025_split huggingface dataset:
High-grade metamorphism of banded iron formations: the role of saline fluids in promoting the growth of pyroxene and garnet reaction textures along magnetite-quartz grain boundaries
Authors: George Paul M. , Harlov Daniel E. , Windley Brian F. , Satish-Kumar Madhusoodhan , Sajeev Krishnan , Zhai Ming-Guo 
Published: April 2024

AbstractMetamorphosed banded iron formation (BIF) in granulite-amphibolite facies, tonalitic orthogneisses from a series of locations in the Kolli Massif of southern India are described and analysed with regard to their lithologies, whole rock chemistry, mineral reaction textures, and mineral chemistry. On the basis of their mineral reaction textures along magnetite-quartz grain boundaries these BIFs are grouped according to their predominant silicate mineralogy: 1) amphibole; 2) orthopyroxene; 3) orthopyroxene–clinopyroxene; 4) orthopyroxene-clinopyroxene-garnet; 5) clinopyroxene-garnet-plagioclase; and 6) Fe-Mg silicates are absent. Two-pyroxene and garnet-pyroxene Fe-Mg exchange thermometry, coupled with thermodynamic pseudo-section modelling of whole rock data from one of the magnetite-quartz-orthopyroxene-clinopyroxene-bearing lithologies, indicates that the magnetite-quartz-orthopyroxene-clinopyroxene-garnet assemblages formed at ~900 to 1200 MPa and 750 to 900 °C under relatively low H2O activities. Magnetite-quartz-orthopyroxene reaction textures were experimentally replicated at 800 and 900 °C and 1000 MPa in a synthetic BIF using isolated magnetite grains in a quartz matrix to which was added a hypersaline Mg- and Al-bearing fluid (approximately 1% by mass), which permeated along all the grain boundaries. The fact that Fe-Mg silicate reaction textures did not form in one of the BIF samples, which had experienced the same P-T conditions as the other BIF samples, suggests that, unless a BIF initially incorporated Mg, Al, and Ca during formation with or was infiltrated from the surrounding rocks by Mg-, Al-, and Ca-bearing saline fluids, these silicate minerals could not and would not have formed from the inherent magnetite and quartz during granulite-facies and amphibolite-facies metamorphism.
Structural insights into the potential binding sites of Cathepsin D using molecular modelling techniques
Authors: Kamble Subodh A. , Barale Sagar S. , Mohammed Ali Abdulmawjood , Paymal Sneha B. , Naik Nitin M. , Sonawane Kailas D. 
Published: April 2024

AbstractAlzheimer’s disease (AD) is the most prevalent type of dementia caused by the accumulation of amyloid beta (Aβ) peptides. The extracellular deposition of Aβ peptides in human AD brain causes neuronal death. Therefore, it has been found that Aβ peptide degradation is a possible therapeutic target for AD. CathD has been known to breakdown amyloid beta peptides. However, the structural role of CathD is not yet clear. Hence, for the purpose of gaining a deeper comprehension of the structure of CathD, the present computational investigation was performed using virtual screening technique to predict CathD's active site residues and substrate binding mode. Ligand-based virtual screening was implemented on small molecules from ZINC database against crystal structure of CathD. Further, molecular docking was utilised to investigate the binding mechanism of CathD with substrates and virtually screened inhibitors. Localised compounds obtained through screening performed by PyRx and AutoDock 4.2 with CathD receptor and the compounds having highest binding affinities were picked as; ZINC00601317, ZINC04214975 and ZINCC12500925 as our top choices. The hydrophobic residues Viz. Gly35, Val31, Thr34, Gly128, Ile124 and Ala13 help stabilising the CathD-ligand complexes, which in turn emphasises substrate and inhibitor selectivity. Further, MM-GBSA approach has been used to calculate binding free energy between CathD and selected compounds. Therefore, it would be beneficial to understand the active site pocket of CathD with the assistance of these discoveries. Thus, the present study would be helpful to identify active site pocket of CathD, which could be beneficial to develop novel therapeutic strategies for the AD.
Effect of electric pulse treatment on silver recovery from spent solar panel sheet by acid-leaching
Authors: Takaya Yutaro , Imaizumi Yuto , Koita Taketoshi , Mauricio Cordova Udaeta Edwin , Tokoro Chiharu 
Published: April 2024

AbstractThe number of spent photovoltaic (PV) panels is expected to increase significantly in the coming decades. Crystalline silicon photovoltaic cells contain materials, such as silver, copper, aluminum, silicon, glass, and resins. Approximately 600 g/t of silver is used as a current collector, so-called finger wires, in photovoltaic modules; therefore, silver recovery is an important issue. To establish an effective recycling process for spent photovoltaic panels, a wire explosion method using high-voltage pulsed discharge was investigated to expose and separate silver selectively. In this study, acid-leaching experiments were conducted on spent ground photovoltaic panels with and without electric pulse treatment to verify the effect of the pulse treatment on acid-leaching of silver. Electric pulse treatment improved both the maximum silver recovery rate and leaching speed. Leaching experiments were also conducted using photovoltaic samples from three different silver exposure states. It can be concluded that silver recovery was strongly controlled by the exposure state and that the electric pulse treatment could effectively promote silver exposure of spent PV panels, even in the region where the silver wires were not energized.
The relationship between numerical magnitude processing and math anxiety, and their joint effect on adult math performance, varied by indicators of numerical tasks
Authors: Szczygieł Monika , Sarı Mehmet Hayri 
Published: April 2024

AbstractAccording to the hypothesis of Maloney et al. (Cognition 114(2):293–297, 2010. https://doi.org/10.1016/j.cognition.2009.09.013), math anxiety is related to deficits in numerical magnitude processing, which in turn compromises the development of advanced math skills. Because previous studies on this topic are contradictory, which may be due to methodological differences in the measurement of numerical magnitude processing, we tested Maloney et al.’s hypothesis using different tasks and their indicators: numerical magnitude processing (symbolic and non-symbolic comparison tasks: accuracy, reaction time, numerical ratio, distance and size effects, and Weber fraction; number line estimation task: estimation error), math anxiety (combined scores of learning, testing, math problem solving, and general math anxiety), and math performance. The results of our study conducted on 119 young adults mostly support the hypothesis proposed by Maloney et al. that deficiency in symbolic magnitude processing is related to math anxiety, but the relationship between non-symbolic processes and math anxiety was opposite to the assumptions. Moreover, the results indicate that estimation processes (but not comparison processes) and math anxiety are related to math performance in adults. Finally, high math anxiety moderated the relationship between reaction time in the symbolic comparison task, reaction time in the non-symbolic comparison task, numerical ratio effect in the symbolic comparison task, and math performance. Because the results of the joint effect of numerical magnitude processing and math anxiety on math performance were inconsistent, this part of the hypothesis is called into question.
Designing a reliable-sustainable supply chain network: adaptive m-objective ε-constraint method
Authors: Sepehri Arash , Tirkolaee Erfan Babaee , Simic Vladimir , Ali Sadia Samar 
Published: April 2024

AbstractIn the current era emphasizing sustainability and circularity, supply chain network design is a critical challenge for making reliable decisions. The optimization of facility location-allocation inventory problems (FLAIPs) holds the key to achieving dependable product delivery with reduced costs and carbon emissions. Despite the importance of these challenges, a substantial research gap exists regarding economic, reliability, and sustainability criteria for FLAIPs. This paper aims to fill this gap by introducing a multi-objective mixed-integer linear programming model, focusing on configuring a reliable sustainable supply chain network. The model addresses three key objectives: minimizing costs, minimizing emissions, and maximizing reliability. A notable contribution of this research lies in elaborating on five levels of a supply chain network catering to the delivery of multiple products across various periods. Another novelty is the simultaneous incorporation of economic, environmental, and reliability objectives in the network design—a facet rarely addressed in prior research. Results highlight that varying demand levels for each facility lead to altered trade-offs between objectives, empowering practitioners to make diverse decisions in facility location allocation. The proposed mathematical model undergoes validation through numerical examples and sensitivity analysis of parameters. The paper concludes by presenting theoretical and managerial implications, contributing valuable insights to the field of sustainable supply chains.
Bradyrhizobium ontarionense sp. nov., a novel bacterial symbiont isolated from Aeschynomene indica (Indian jointvetch), harbours photosynthesis, nitrogen fixation and nitrous oxide (N2O) reductase genes
Authors: Bromfield Eden S. P. , Cloutier Sylvie 
Published: April 2024

AbstractA novel bacterial symbiont, strain A19T, was previously isolated from a root-nodule of Aeschynomene indica and assigned to a new lineage in the photosynthetic clade of the genus Bradyrhizobium. Here data are presented for the detailed genomic and taxonomic analyses of novel strain A19T. Emphasis is placed on the analysis of genes of practical or ecological significance (photosynthesis, nitrous oxide reductase and nitrogen fixation genes). Phylogenomic analysis of whole genome sequences as well as 50 single-copy core gene sequences placed A19T in a highly supported lineage distinct from described Bradyrhizobium species with B. oligotrophicum as the closest relative. The digital DNA-DNA hybridization and average nucleotide identity values for A19T in pair-wise comparisons with close relatives were far lower than the respective threshold values of 70% and ~ 96% for definition of species boundaries. The complete genome of A19T consists of a single 8.44 Mbp chromosome and contains a photosynthesis gene cluster, nitrogen-fixation genes and genes encoding a complete denitrifying enzyme system including nitrous oxide reductase implicated in the reduction of N2O, a potent greenhouse gas, to inert dinitrogen. Nodulation and type III secretion system genes, needed for nodulation by most rhizobia, were not detected. Data for multiple phenotypic tests complemented the sequence-based analyses. Strain A19T elicits nitrogen-fixing nodules on stems and roots of A. indica plants but not on soybeans or Macroptilium atropurpureum. Based on the data presented, a new species named Bradyrhizobium ontarionense sp. nov. is proposed with strain A19T (= LMG 32638T = HAMBI 3761T) as the type strain.
Using Teacher Prompts to Increase Leadership Skills in Preschool Children
Authors: Dicarlo Cynthia F. , Dowell Margaret-Mary Sulentic , Fazio-Brunson Michelle , Gauthreaux Sarah W. 
Published: April 2024

Abstract

Background
Early childhood leadership leads to positive outcomes for young children, including social competence.

Objective
The purpose of the present study was to examine the leadership behavior exhibited by three preschool aged children and to determine if teacher prompting could increase the frequency of leadership behaviors exhibited by preschool children.

Methods
A single case research design was utilized; specifically, we employed a multiple baseline design across preschool children to measure child leadership behaviors and teacher prompting.

Results
Baseline observations revealed that children engaged in Parten’s original 1933 framework of both directing and following, reciprocally directing or sharing leadership, and directing the group at varying levels. Using Pigors (Leadership and domination among children, 9:140–157, 1933) definition of “guidance of others toward a desired goal,” Leadership Prompting Intervention was used to increase children’s leadership behaviors. Results indicated that both teachers increased their level of leadership prompting, and all three children increased the behaviors of directing the group.

Conclusions
Teacher prompting is a low cost, low labor-intensive intervention that can be easily integrated into the early childhood classroom routine to increase children’s leadership skills. This study adds to the limited research on early childhood leadership (ECL) by providing insight into how teacher prompts can influence children’s leadership behavior in a specific context and setting.
A new exposure protocol adapted for wild bees reveals species-specific impacts of the sulfoximine insecticide sulfoxaflor
Authors: Dewaele Justine , Barraud Alexandre , Hellström Sara , Paxton Robert J. , Michez Denis 
Published: April 2024

AbstractWild bees are crucial pollinators of flowering plants and concerns are rising about their decline associated with pesticide use. Interspecific variation in wild bee response to pesticide exposure is expected to be related to variation in their morphology, physiology, and ecology, though there are still important knowledge gaps in its understanding. Pesticide risk assessments have largely focussed on the Western honey bee sensitivity considering it protective enough for wild bees. Recently, guidelines for Bombus terrestris and Osmia bicornis testing have been developed but are not yet implemented at a global scale in pesticide risk assessments. Here, we developed and tested a new simplified method of pesticide exposure on wild bee species collected from the field in Belgium. Enough specimens of nine species survived in a laboratory setting and were exposed to oral and topical acute doses of a sulfoximine insecticide. Our results confirm significant variability among wild bee species. We show that Osmia cornuta is more sensitive to sulfoxaflor than B. terrestris, whereas Bombus hypnorum is less sensitive. We propose hypotheses on the mechanisms explaining interspecific variations in sensitivity to pesticides. Future pesticide risk assessments of wild bees will require further refinement of protocols for their controlled housing and exposure.
Fire Safety for Green Façades: Part 1: Basics, State-of-the-Art Research and Experimental Investigation of Plant Flammability
Authors: Engel Thomas , Werther Norman 
Published: April 2024

AbstractThis study is the first part of a larger investigation into the fire behaviour of green façades. In this study, the currently known international research status on this topic is presented and discussed. In addition, the flammability of green façades is investigated through 43 fire tests on a medium scale according to the SBI (Single Burning Item) test method EN 13823. The focus of the investigation was placed on climbing plants. A total of 25 different plant species were investigated. A comparison of the heat release rate of all the investigated vital plants shows similar behaviour. In the course of exposure, there are short peaks in the heat release rate. These peaks are “flare-ups” that occur when parts of the plants dry out due to exposure to the flame and then ignite. The plant species itself had no substantial influence on fire behaviour. Horizontal fire spread occurred to a very limited extent within the investigations of vital plants. They were self-extinguishing. The significant factor in the assessment of flammability is the moisture content of the plants. With dried plants, an abrupt heat release occurs at the beginning. Dried-out plants, as well as unmaintained plants with a high content of deadwood, represent the most critical case.
Graphical Abstract
Chemical and Thermal Exposure Risks in a Multi Compartment Training Structure
Authors: Horn Gavin P. , Stakes Keith , Neumann Danielle L. , Willi Joseph M. , Chaffer Ryan , Weinschenk Craig , Fent Kenneth W. 
Published: April 2024

AbstractProviding NFPA 1403 compliant live-fire training can present thermal and chemical exposure risk to instructors and students. To reduce risk, training academies, fire departments, instructors, and standards setting technical committees need more information on how different training fuels used in common training structures can impact the environment in which firefighter training occurs. This study utilized a traditional concrete training structure with multiple compartments to characterize training environments with three different fuel package materials [i.e., low density wood fiberboard, oriented strand board (OSB), and wood pallets]. Exposure risks for a fire instructor located on either the first or second floor were characterized using measurements of heat flux, air temperature and airborne concentrations of several contaminants including known, probable, or possible carcinogens. It was hypothesized that utilizing a training fuel package with solid wood pallets would result in lower concentrations of these airborne contaminants [aldehydes, polycyclic aromatic hydrocarbons (PAHs) and volatile organic compounds (VOCs)] than wood-based sheet goods containing additional resins and/or waxes. Additionally, it was hypothesized that these concentrations would be lower than in the single compartment Fire Behavior Lab presented in a companion manuscript. For all measured compounds other than hydrochloric acid, airborne concentrations were 10 to 100 times lower than in the Fire Behavior Lab. OSB-fueled fires produced the highest median concentrations of total PAHs and VOCs such as benzene, while the pallet fuel package produced the lowest median concentrations of these compounds. These trends generally followed the qualitative visual obscuration created by each fuel. Additional tests were conducted on the OSB-fueled fires with increased ventilation and an alternate means of reducing visibility through smoldering smoke barrels. This OSB experiment with increased ventilation resulted in the highest temperatures in the fire room but the lowest impact on visibility throughout the structure, as well as the lowest overall concentrations of contaminants in this study. In contrast, the smoldering straw-filled smoke barrel created a highly obscured environment (with minimal impact on thermal environment) and some of the highest concentrations of the targeted contaminants of any test. These data may be useful in balancing obscuration for training with potential exposure to thermal stressors and contaminants.
On the energy decomposition in variational phase-field models for brittle fracture under multi-axial stress states
Authors: Vicentini F. , Zolesi C. , Carrara P. , Maurini C. , De Lorenzis L. 
Published: April 2024

AbstractPhase-field models of brittle fracture are typically endowed with a decomposition of the elastic strain energy density in order to realistically describe fracture under multi-axial stress states. In this contribution, we identify the essential requirements for this decomposition to correctly describe both nucleation and propagation of cracks. Discussing the evolution of the elastic domains in the strain and stress spaces as damage evolves, we highlight the links between the nucleation and propagation conditions and the modulation of the elastic energy with the phase-field variable. In light of the identified requirements, we review some of the existing energy decompositions, showcasing their merits and limitations, and conclude that none of them is able to fulfil all requirements. As a partial remedy to this outcome, we propose a new energy decomposition, denoted as star-convex model, which involves a minimal modification of the volumetric-deviatoric decomposition. Predictions of the star-convex model are compared with those of the existing models with different numerical tests encompassing both nucleation and propagation.
Therapeutic potential of conduction system pacing as a method for improving cardiac output during ventricular tachycardia
Authors: Keene Daniel , Miyazawa Alejandra A. , Arnold Ahran D. , Naraen Akriti , Kaza Nandita , Mohal Jagdeep S. , Lefroy David C. , Lim Phang Boon , Ng Fu Siong , Koa-Wing Michael , Qureshi Norman A. , Linton Nick W. F. , Wright Ian , Peters Nicholas S. , Kanagaratnam Prapa , Shun-Shin Matthew J. , Francis Darrel P. , Whinnett Zachary I. 
Published: April 2024

Abstract
Background
Ventricular tachycardia (VT) reduces cardiac output through high heart rates, loss of atrioventricular synchrony, and loss of ventricular synchrony. We studied the contribution of each mechanism and explored the potential therapeutic utility of His bundle pacing to improve cardiac output during VT.

Methods
Study 1 aimed to improve the understanding of mechanisms of harm during VT (using pacing simulated VT). In 23 patients with left ventricular impairment, we recorded continuous ECG and beat-by-beat blood pressure measurements. We assessed the hemodynamic impact of heart rate and restoration of atrial and biventricular synchrony. Study 2 investigated novel pacing interventions during clinical VT by evaluating the hemodynamic effects of His bundle pacing at 5 bpm above the VT rate in 10 patients.

Results
In Study 1, at progressively higher rates of simulated VT, systolic blood pressure declined:
at rates of 125, 160, and 190 bpm, -22.2%, -42.0%, and -58.7%, respectively (ANOVA p < 0.0001). Restoring atrial synchrony alone had only a modest beneficial effect on systolic blood pressure (+ 3.6% at 160 bpm, p = 0.2117), restoring biventricular synchrony alone had a greater effect (+ 9.1% at 160 bpm, p = 0.242), and simultaneously restoring both significantly increased systolic blood pressure (+ 31.6% at 160 bpm, p = 0.0003). In Study 2, the mean rate of clinical VT was 143 ± 21 bpm. His bundle pacing increased systolic blood pressure by + 14.2% (p = 0.0023). In 6 of 10 patients, VT terminated with His bundle pacing.

Conclusions
Restoring atrial and biventricular synchrony improved hemodynamic function in simulated and clinical VT. Conduction system pacing could improve VT tolerability and treatment.

Graphical Abstract