bluuebunny/crossref_metadata_2025_split huggingface dataset:
The rapakivi granites of S Greenland—crustal melting in response to extensional tectonics and magmatic underplating
Authors: Brown P. E. , Dempster T. J. , Harrison T. N. , Hutton D. H. W. 
Published: November 2011

ABSTRACTEarly Proterozoic rapakivi intrusions in S Greenland occur as thick sheets which have ramp–flat geometry and were intruded along the median planes of active ductile extensional shear zones. These shear zones and their intrusions were linked via transfer zones in a major three-dimensional framework. At high structural levels (c.6 km) the rapakivi intrusions developed thermal aureoles which overprint the regional assemblages, whereas at deeper levels in the regional structure they are contemporaneous with regional metamorphism. Thermobarometry on the regional and contact assemblages indicates low pressure granulite facies conditions (200–400 MPa, 650°-800°C) suggesting very high thermal gradients. The rapakivi suite and associated norites have low initial87Sr/86Sr together with positive εNdvalues, indicating the involvement of predominantly young crust and/or mantle component in the generation of the igneous suite. It is considered that the voluminous norites are closely related to the mafic melts which underplated the juvenile crust to trigger the generation of the monzonitic rapakivi suite. Taken together, the data are consistent with a model of Proterozoic lithospheric extension, thinning of relatively juvenile continental crust and compression of mantle isotherms, resulting in high crustal heat flow, mafic underplating, and crustal melting with emplacement of magmas along a linked network of extensional shear zones.
Genesis of the lower crustal garnet-orthopyroxene tonalites (S-type) of the Hidaka Metamorphic Belt, northern Japan
Authors: Shimura T. , Komatsu M. , Iiyama J. T. 
Published: November 2011

ABSTRACTThe Hidaka Metamorphic Belt (HMB) in Hokkaido, northern Japan, consists of tilted metamorphic layers of an island-arc type crust from lower (granulite facies) to upper (very low-grade metasedimentary) horizons. Abundant granitic rocks, mainly S-type tonalites of crustal origin, intrude various metamorphic layers and are classified into four depth types, namely upper, middle, lower and basal. The basal orthopyroxene-garnet (S-type) tonalities were intruded into granulite facies country rocks. Textural and compositional evidence from minerals in the basal tonalite indicates that the crystallisation sequence is Grt-Pl-Opx-Bt-Qtz-Crd-Kfs, and that crystallisation took place at about 600 MPa and 900°C-700°C.Some crystallisation experiments were carried out in an internally heated pressure vessel, using the basal tonalite, under the conditions of 300 and 600 MPa, 700-900°C, and with 0-20 wt% H2O, respectively. The results show that the primary S-type tonalite magma was at a temperature above 900°C and contained 3-4 wt% H2O at the beginning of crystallisation. In order to study the influence of normative orthoclase content on orthopyroxene crystallisation, some starting materials also included 15, 20 and 25% normative orthoclase, by adding KAlSi3O8gel to the rock powder. Normative orthoclase content has an influence on the subliquidus crystallisation limit of orthopyroxene.The changes inP-Tconditions and chemical composition of the magma during ascent would generate the sequence from the basal to upper S-type granite. Opx-free S-type granitic magma can be generated from lower crustal Grt-Opx S-type granitic magma, by differentiation with falling magmatic temperature.
Geochemistry and Rb-Sr geochronology of Mesozoic granites from Hong Kong
Authors: Sewell R. J. , Darbyshire D. P. F. , Langford R. L. , Strange P. J. 
Published: November 2011

ABSTRACTThe granites of Hong Kong comprise a variety of assemblages dominated by chemically evolved compositions. They are divided into two suites based on petrographic, geochemical, and age criteria. The oldest and most primitive intrusive units are deformed biotite-hornblende granodiorites and monzogranites of the Lamma Suite. These rocks are characterised by high CaO (1·4-2·7%), and low Nb and Y contents. The Lion Rock Suite (LRS) is dominated by relatively undeformed monzogranite with subordinate quartz syenite and comprises three subgroups. Granites of subgroup I are separated into coarse- and fine- to medium-grained lithologies. The fine- to medium-grained granites are predominantly fluorite-bearing with silica contents ranging from 75·5-78%. They are characterised by high total REE, Ga, F, Rb, Nb, and Y contents and yield a Rb-Sr whole-rock isochron age of 155 ± 6 Ma with an initial 87Sr/86Sr ratio of 0·7101 ± 0·0060 (MSWD = 4·6). Granites of subgroup II comprise a diverse range of compositions (SiO2 = 63–77%) and are characterised by highly variable trace element abundances. Coarse-grained granites yield an age of 148 ± 9 Ma with an initial 87Sr/86Sr ratio of 0·7060 ± 0·0006 (MSWD = 0·1). Granites of subgroup III are moderately to highly evolved (SiO2 = 72·5-77·9%) and the silica-rich compositions are marked by enrichment in Y, Nb, Rb and depletion in Ba and Sr. Rb-Sr whole-rock isochron ages for individual plutons vary from 138 ± 1 to 136 ± 1 and corresponding initial 87Sr/86Sr ratios are 0·7080 ± 0·0002 (MSWD = 1·2) and 0·7092 ± 0·0006 (MSWD = 0·4). Granites of the Lamma Suite and coarse-grained granites of LRS subgroup I are interpreted as synorogenic I-types, whereas those of LRS subgroups II and III are interpreted as late-orogenic to postorogenic, fractionated I-types. Fineto medium-grained granites of LRS subgroup I have distinctive A-type affinities and together with their association with quartz syenite indicate a transition from compressional to tensional tectonics.
The role of magma sources, oxidation states and fractionation in determining the granite metallogeny of eastern Australia
Authors: Blevin Phillip L. , Chappell Bruce W. 
Published: November 2011

ABSTRACTThe ore-element associations of granite-related ore deposits in the eastern Australian Palaeozoic fold belts can be related to the inferred relative oxidation state, halogen content and degree of fractional crystallisation within the associated granite suites. Sn mineralisation is associated with both S- and I-type granites that are reduced and have undergone fractional crystallisation. Cu and Au are associated with magnetite- and/or sphene-bearing, oxidised, intermediate I-type suites. Mo is associated with similar granites that are more fractionated and oxidised. W is associated with a variety of granite types and shows little dependence on inferred magma redox state. The observed ore deposit-granite type distribution in eastern Australia, and the behaviour of ore elements during fractionation, is consistent with models of ore element sequestering by sulphides and Fe-Ti phases (e.g. pyrrhotite, ilmenite, sphene, magnetite) whose stability is nominally fO2-dependent. Fractional crystallisation acts to amplify this process through the progressive removal of compatible elements and the concentration of incompatible elements into decreasing melt volumes. The halogen content is also important. S-type granites are poorer in Cl than I-types. Cl decreases and F increases in both S- and I-type granites with fractional crystallisation. Low Cl contents combined with low magma fO2 in themselves seem to provide an adequate explanation for the rarity of Mo, Cu, Pb and Zn type mineralisation with S-type granites. Although such properties of granite suites seem adequately to predict the associated ore-element assemblage to be expected in associated mineral deposits, additional factors determine whether or not there is associated economic mineralisation.
Controls on ore metal ratios in granite-related ore systems: an experimental and computational approach
Authors: Candela Philip A. 
Published: November 2011

ABSTRACTSize and composition (bulk metal ratios) of magmatic hydrothermal mineral deposits are affected by a number of chemical and physical processes including the nature of the source region and mode of emplacement. At shallow levels, rising plumes of vapour bubbles + melt, and the advection of water through interconnected vapour bubbles, allows access of the magmatic aqueous phase to the upper reaches of a magma chamber. These processes are operative at shallow levels where low water solubility and high molar volume for water make these processes more efficient.Partitioning experiments suggest that oxygen fugacity-dependent crystal/melt partitioning of ore metals leads to different efficiencies of removal of Cu, W, and Mo from silicate melts into ore-forming aqueous fluids. For example, the Mo/W ratio in magmatic hydrothermal deposits should increase as the oxygen fugacity of the magma increases. Further, Cu should behave as a crystal-compatible element in H2O-undersaturated, sulfide-saturated felsic magmas with fO2 NNO + 1 due to the strong partitioning of Cu from the melt into pyrrhotite.Cycling of oxidised, hydrated, sulfidised and Cl-enriched oceanic crust into mantle can give rise to magmas that contain S but are oxidised (≥NNO). The combination of high oxidation state, relatively hydrous but shallow conditions and a high Cl/H2O ratio leads to saturation with respect to H2O early during crystallisation, and loss of a large proportion of magmatic Cu to the aqueous phase. Ores formed from these oxidised magmas also possess high Mo/W ratios due to the effect of oxygen fugacity on the sequestering of Mo vs W.In less oxidised magmas, Cu and Mo are partitioned into sulfides and Ti-bearing phases, respectively, resulting in lower efficiencies of removal of Cu and Mo from melts into aqueous fluids. Further, the partitioning of W into crystallising phases is reduced, producing a more efficient removal of W into ore-forming fluids. This ultimately leads to mineral deposits with higher W/(Mo + Cu) ratios relative to deposits associated with more oxidised systems. Silicic, high-F magmas with fO2 = NNO can be found in tensional environments (e.g. rocks associated with the Climax-type deposits of the Colorado Mineral Belt). High HF/H2O activity ratios in the source regions yield melts that evolve an aqueous phase late during crystallisation, leading to relatively low ratios of compatible/incompatible elements in the melt at H2O saturation.
Feldspar crystallisation in felsic magmas: a review
Authors: Nekvasil Hanna 
Published: November 2011

ABSTRACTUnderstanding the controls on the evolution of natural feldspars is greatly assisted by coupling experimental determinations of feldspar/melt equilibria with thermodynamic modelling and the calculation of crystallisation paths. Such a combined approach permits the evaluation of the influence of intensive and extensive variables on feldspar compositions. Feldspar compositional paths are influenced only to a minor degree by pressure. The presence of H2O or other melt component incompatible in feldspar has a more major effect, not only in increasing the temperature interval over which feldspar crystallises, but also in decreasing the amount of Ab enrichment of the feldspar which occurs during crystallisation. The amount and behaviour of H2O in the magma has a pronounced influence on feldspar compositions when two feldspars are stable. Under conditions of high bulk H2O content or constant activity of H2O, plagioclase and alkali feldspar compositions evolve by increasing Ab content similar to the behaviour manifested in the simple binary systems. If the bulk H2O content is low, however, and the H2O content increases during crystallisation, plagioclase evolves by increasing Ab content until alkali feldspar is stabilised. From that point on, plagioclase compositions change mainly by decreasing Or content, while alkali feldspar evolves mainly by increasing Or content.
A two-parameter Margules method for modelling the thermodynamic mixing properties of albite-water melts
Authors: Blencoe James G. 
Published: November 2011

ABSTRACTA two-parameter Margules method has been developed for modelling the thermodynamic mixing properties and hypersolidus phase relations of albite-water (ab-w) melts. The method is based largely on phase-equilibrium and calorimetric data that are either currently available or readily obtainable; P-V-T data are not required.The new modelling method has been applied to calculate: (1) thermodynamic mixing properties for ab-w melts at 2-5 kbar, 815°C; and (2) hypersolidus phase relations for the ab-w system at 2·5 kbar. Results are uniformly positive—activity-composition relations are similar to those predicted by equations based on P-V-T data, excess enthalpies are in good agreement with data obtained from calorimetry, and calculated phase relations are fully compatible with phase-equilibrium data for ab-w melts acquired at 2·5 kbar.It is concluded that the Margules method for thermodynamic modelling of ab-w melts is a practical alternative to the P-V-T modelling method.
Crustal versus mantle sources of granitic magmas: a two-parameter model based on Nd isotopic studies
Authors: DePaolo Donald J. , Perry Frank V. , Baldridge W. Scott 
Published: November 2011

ABSTRACTTemporal and spatial variations in the Nd isotopic compositions of Tertiary caldera-forming rhyolite tuffs, and Cretaceous and Tertiary granites of the western U.S.A. are used as a basis for a model that accounts for the observed proportions of crustal versus mantle contributions to silicic magmas in terms of two parameters: the ambient crustal temperature and the rate of supply of basaltic magma from the mantle. The crustal contribution to silicic igneous rocks is measured in terms of the Neodymium Crustal Index (NCI). The relationships between crustal temperature, basalt supply and NCI are quantified using a model of a magma chamber undergoing continuous recharge, wall-rock assimilation and fractional crystallisation. From the model, a critical value of the ratio of basalt recharge-to-assimilation, (r/a)c, is deduced, which increases with decreasing crustal temperature. The r/a value must exceed (r/a)cto allow the volume of differentiated magma to increase, a prerequisite for developing large volumes of silicic magma. Strongly peraluminous (or S-type) magmas (NCI = 0·8–1), form under conditions of high crustal temperature and low basalt supply. Metaluminous or I-type granites form over a wide range of conditions (NCI = 0·1–1), generally where basalt supply is substantial. In individual long-lived volcanic centres, the large-volume high-silica ignimbrites are associated with the highest r/a and lowest NCI values, indicating that these magmas are typically differentiates of mantle-derived basaltic parents.
Some observations on the use of zircon U-Pb geochronology in the study of granitic rocks
Authors: Williams Ian S. 
Published: November 2011

ABSTRACTIn situ, microscale, U-Pb isotopic analyses of zircon using the SHRIMP ion microprobe demonstrate both the potential and the limitations of zircon U-Pb geochronology. Most zircons, whether from igneous or metamorphic rocks, need to be considered as mixed isotopic systems. In simple, young igneous rocks the mixing is principally between isotopically disturbed and undisturbed zircon. In polymetamorphic rocks, several generations of zircon growth can coexist, each with a different pattern of discordance. A similar situation exists for igneous rocks rich in inherited zircon, as these contain both melt-precipitated zircon and inherited components of several different ages. Microscale analysis by ion probe makes it possible to sample the record of provenance, age and metamorphic history commonly preserved within a single zircon population. It also indicates how the interpretation of conventionallymeasured bulk zircon isotopic compositions might be improved.
Structural interpretations of the Southern Uplands Terrane
Authors: Anderson T. Bernard 
Published: November 2011

ABSTRACTBounded by sutures and demonstrating a unique geological history and structure, the Lower Palaeozoic rocks of the Southern Uplands–Down–Longford form a definitive Caledonian suspect terrane. The geological history of the final closure of Iapetus is encrypted in their structural fabric.Across the terrane, NW-younging turbidites predominate but graptolites invariably indicate the presence of younger sediments to the SSE. This fundamental Southern Upland paradox is soluble only by recognizing many strike-parallel faults, dividing the terrane into more than thirty tracts, each with its own variant of the stratigraphy and structure, and each having a lateral extent far in excess of what might be expected from the probable mechanical strength of the composing sediments. Structural interpretations of the terrane's unique tectonostratigraphic pattern are critically reviewed and the accretionary prism model, modified by strong sinistral transpression from the late Llandovery onward, is preferred. Transpression was apparently triggered when the converging continents of Laurentia and Avalonia made solid contact, so establishing a mechanically effective coupling of sialic crustal elements beneath and across the closing Iapetus ocean basin.The geometry of the terrane's internal structural fabric is analysed. Tentative area-balancing calculations indicate a crustal shortening from a basin width of at least 1,000 km to the current terrane width of 75 km. Continuing sinistral transpression was expressed in fault reactivation and the development of a major shear zone. Late Palaeozoic strike-parallel extension produced W-facing half-grabens and the associated rotation may account for the easterly plunge of most fold axes.
Silurian subduction-related assembly of fault-defined tracts at the Laurieston Fault, Southern Uplands accretionary terrane, Scotland, U.K.
Authors: Akhurst M. C. , McMillan A. A. , Kimbell G. S. , Stone P. , Merriman R. J. 
Published: November 2011

ABSTRACTSubduction-related accretion of fault-defined tracts built up the Southern Uplands terrane during the final stages of closure of the Iapetus Ocean (Llandovery to Wenlock). Contrasts in depositional environment and pronounced differences in geochemical composition, provenance studies and metamorphic grade across the Laurieston Fault between the Gala and Hawick groups, suggests that it has a greater regional significance than most other tract-bounding structures. Initiated by underthrusting, and acting as a locus for subsequent sinistral strike-slip, the fault overlies a regional gravity anomaly gradient that is interpreted to be due, in part, to a concealed NW-ward dipping shallow basement surface. This is modelled as an open ramp in the NE that steepens to a near-vertical step along-strike to the SW. A change in structural geometry noted at the Laurieston Fault, with excision of accretionary tracts, is related to a period of oblique closure of the Iapetus Ocean. The youngest Gala Group tracts were accreted during a period of intense transpression to form a regional strike-slip duplex over the shallow basement ramp with termination of the tracts at the Laurieston Fault, its surface expression. The ramp acted as an obstacle to forward-breaking thrust progress, forcing the out-of-sequence thrusting and repetitive thrust imbrication noted in the eastern Southern Uplands. Upper Palaeozoic reactivation of this basement structure may have transferred strain between extensional Permian basins.
Volcanically mediated plankton blooms in the Central Belt of the Southern Uplands, Scotland, during the Llandovery
Authors: Rigby S. , Davies S. J. 
Published: November 2011

ABSTRACTAt Thirlestane Score and at four other localities in the Southern Uplands, graptolites of the LlandoverygemmatusZone occur in couplets of lithologies immediately above thin ‘high-U’ bentonites. Above the bentonites, abundant graptolites, especially siculae, and a straight-line survivorship trend implies high productivity coupled with environmentally mediated mortality: the population structure expected in the early part of a plankton bloom. In the overlying facies, fewer, larger individuals and a convex survivorship curve suggest reduced productivity and internally mediated mortality. This is consistent with the later stages of a bloom where resources were waning but the ecological structure of the system was better developed. It is likely that the introduction of trace-metals, Fe or Al, to the water column via volcanic ash increased primary productivity, suggesting that macronutrients were available in the Southern Uplands system, allowing a bloom to be stimulated by the addition of volcanic products. This process is observed in modern open oceanic systems and implies a temporal continuity of control on the plankton despite complete faunal turn-over since the Silurian. These interpretations are most consistent with an open ocean geotectonic setting for the region.
Late Ordovician brachiopod biofacies of the Girvan district, SW Scotland
Authors: Harper David A. T. 
Published: November 2011

ABSTRACTDiverse and abundant brachiopod faunas, associated with unstable outer shelf and slope environments, occur through the Upper Ardmillan Group (upper Caradoc–upper Ashgill) in the Girvan district of SW Scotland. Representatives of the deep-waterFoliomenafauna occur intermittently throughout the group, appearing in both the Whitehouse and Drummuck subgroups. This distinctive assemblage of small, thin-shelled brachiopods, includingDedzetina, Christiania, CyclospiraandFoliomenaitself, first appeared in South China during the early Caradoc but had colonised the Laurentian margins by the late Caradoc. Within the upper Caradoc–lower Ashgill Whitehouse Subgroup, theFoliomenafauna is interbedded with a variety of other less cosmopolitan deep-water assemblages including theOnniella–SkenidioidesandLingulella–Trimurellinaassociations. Shallower-water environments in the middle Ashgill Lower Drummuck Subgroup hosted theFardenia–Eopholidostrophiaassociation in sands, and theChristiania-Leptaenaassociation in muds and silts. The remarkable Lady Burn Starfish Beds in the upper part of the group contain a variety of brachiopod-dominated assemblages including theEochonetesandPlaesiomys-Schizophorellaassociations, transported from various shelf locations, within a very diverse mid-Ashgill biota. Nevertheless, elements of theFoliomenafauna persisted to near the top of the Drummuck Subgroup, occurring as rare assemblages in more muddy and silty facies. The upper Ashgill High Mains Formation contains abundant elements of the terminal OrdovicianHirnantiafauna includingEostropheodonta, HindellaandHirnantiaitself, but also some taxa more typical of the Laurentian Edgewood Province. As a whole, the changing brachiopod biofacies monitor environmental fluctuations, on part of the Laurentian margin, driven by mainly eustatic and tectonic events.