bluuebunny/crossref_metadata_2025_split huggingface dataset:
HClO4 BONDING CHARACTERISTICS AGAINST FORMAL CHARGE PREDICTION AND HYPERVALENCE CONCEPT. SHOULD THESE CONCEPTS BE TAUGHT?
Authors: Sanchez Astrid 
Published: June 2024

Chemical bonding is a central topic in general chemistry courses. Lewis (1916) published a fundamental paper where he proposed a model based on localized electron pairs and as a consequence, gave rise to the octet rule. However, the discovery of xenon fluorides and compounds such as SF6 gave rise to the concept of “hypervalence” involving d orbitals in hybridization schemes. Currently, it has been demonstrated that d orbitals have a negligible participation in the bonds of such molecules and, in some cases octet rule is not violated.

This article proposes a discussion about the concepts we use in introductory chemistry lectures. Some models are useful and valuable from a pedagogical point of view, nevertheless, others are unnecessary and far from reality causing misconceptions and lack of interest, since it is hard to rationalize inconsistencies found.

HClO4 molecule was selected to demonstrate that hypervalence concept, molecular structure selection based on formal charge rules and participation of d orbitals on bonds are not appropriate approximations. Bond orders and atomic charges determined through Natural Bond Orbital calculations indicate bonds between Cl and O atoms are mainly simple with a high ionic character.
The Plasma Metabolome and Risk of Incident Kidney Stones
Authors: Ferraro Pietro Manuel , Li Yukun , Balasubramanian Raji , Curhan Gary C. , Taylor Eric N. 
Published: June 2024

Key Points

Information on metabolomic profiles in kidney stone formers is limited.This article describes investigations of associations between plasma metabolomic profiles and the risk of incident, symptomatic kidney stones.Three novel metabolites had negative associations with kidney stones: β-cryptoxanthin and two forms of sphingomyelin.

Background
Information on metabolomic profiles in kidney stone formers is limited. To examine independent associations between plasma metabolomic profiles and the risk of incident, symptomatic kidney stones in adults, we conducted prospective nested case-control studies in two large cohorts.

Methods
We performed plasma metabolomics on 1758 participants, including 879 stone formers (346 from the Health Professionals Follow-Up Study [HPFS] cohort, 533 from the Nurses' Health Study [NHS] II cohort) and 879 non–stone formers (346 from HPFS, 533 from NHS II) matched for age, race, time of blood collection, fasting status, and (for NHS II) menopausal status and luteal day of menstrual cycle for premenopausal participants. Conditional logistic regression models were used to estimate the odds ratio (OR) of kidney stones adjusted for body mass index; hypertension; diabetes; thiazide use; and intake of potassium, animal protein, oxalate, dietary and supplemental calcium, caffeine, and alcohol. A plasma metabolite–based score was developed in each cohort in a conditional logistic regression model with a lasso penalty. The scores derived in the HPFS (“kidney stones metabolite score [KMS]_HPFS”) and the NHS II (“KMS_NHS”) were tested for their association with kidney stone risk in the other cohort.

Results
A variety of individual metabolites were associated with incident kidney stone formation at prespecified levels of metabolome-wide statistical significance. We identified three metabolites associated with kidney stones in both HPFS and NHS II cohorts: β-cryptoxanthin, sphingomyelin (d18:2/24:1, d18:1/24:2), and sphingomyelin (d18:2/24:2). The standardized KMS_HPFS yielded an OR of 1.23 (95% confidence interval, 1.05 to 1.44) for stones in the NHS II cohort. The standardized KMS_NHS was in the expected direction but did not reach statistical significance in HPFS (OR, 1.16; 95% confidence interval, 0.97 to 1.39).

Conclusions
The findings of specific metabolites associated with kidney stone status in two cohorts and a plasma metabolomic signature offer a novel approach to characterize stone formers.
Digital Transformation and its Impact on Safety Culture During Organizational Change
Authors: Okechukwuyem Ojji Stephen 
Published: June 2024

In today's era of rapid technological advancements, organizations are increasingly embracing digital transformation as a pivotal strategy to enhance their competitiveness and operational efficiency. This paradigm shift towards digitalization entails the integration of advanced digital technologies into the fabric of organizational processes and systems. However, this transformative journey often unfolds in tandem with significant organizational change, reshaping not only operational workflows but also the very culture that underpins the workplace dynamics.

This research article delves into the complex interplay between digital transformation initiatives and the overarching safety culture within organizations undergoing profound organizational change processes. Recognizing that safety culture constitutes a cornerstone of organizational well-being and performance, this study seeks to elucidate the multifaceted implications of digitalization on safety practices, attitudes, and behaviors in the workplace.

Through a meticulous examination of the challenges, opportunities, and strategic imperatives inherent in the convergence of digital transformation and safety culture, this research endeavors to offer nuanced insights that can inform organizational decision-making and practice. By unpacking the intricacies of this nexus, the study aims to equip stakeholders with actionable knowledge and best practices conducive to nurturing a positive safety culture amidst the backdrop of digital transformation endeavors.
In essence, this research article serves as a beacon illuminating the path towards a harmonious integration of digital technologies and safety imperatives within the organizational milieu. By fostering a deeper understanding of the dynamics at play and delineating pragmatic strategies for navigating this terrain, the study endeavors to empower organizations to embark on their digital transformation journeys while safeguarding the well-being and resilience of their workforce.
A Model for Detection and Prevention of AndroRat in Mobile Devices
Authors: Benson Kine Apobari , Emmah Dr V. T. , Nwiabu Dr. N. D. 
Published: June 2024

Android operating systems has gained increasing popularity in smart phones and other mobile intelligent terminals in recent years. Unpleasantly, the accumulation development and open nature of the platform has also attracted a vast number of malware developers. This dissertation presents a model for detecting and preventing AndroRat, a notorious Remote Administration Tool (RAT), on android devices. The research systematically pursued predefined objectives, leading to the development of a robust detection framework that utilizes the Outlier Technique. This framework significantly enhances the accuracy of AndroRat identification. Moreover, the dissertation introduces a preventive mechanism based on Recurrent Neural Network (RNN), fortifying Android phones against potential threats posed by RATs. By achieving the outlined objectives, this research makes a noteworthy contribution to the field of mobile device security. It demonstrates a practical application of machine learning techniques in mitigating evolving cybersecurity threats. A dataset was gathered for constructing the model. Object Oriented Analysis and Design (OOAD) was used as the research methodology and python was used as the programming language. The implementation of the Python Programming Language in this system not only ensured efficient execution but also established a versatile and accessible platform, laying the groundwork for future enhancements and adaptations. The comparative analysis conducted against existing systems highlights the effectiveness and innovation embedded in the proposed model, affirming its potential as a valuable addition to the realm of AndroRat detection and prevention with an accuracy of 99.99%. This dissertation not only addresses current security challenges but also establishes a foundation for continued advancements in mobile device security through the integration of cutting-edge technologies.
PEMBELAJARAN ROBLEM BASED LEARNING DALAM PEMBELAJARAN PENDIDIKAN AGAMA ISLAM DI SEKOLAH
Authors: Jukhairin Muhammad , Saparudin  
Published: June 2024

Pendidikan memiliki tiga isu krusial yang meliputi pembaruan kurikulum, peningkatan mutu pengajaran, dan pengembangan strategi pembelajaran. Kurikulum perlu diperbarui agar responsif terhadap perubahan sosial, relevan dengan tuntutan masa kini, dan mampu mengakomodasi keragaman siswa serta perkembangan teknologi. Peningkatan kualitas pengajaran harus difokuskan untuk mencapai hasil pendidikan yang lebih bermutu. Pengembangan strategi pembelajaran yang efektif menjadi penting untuk memberdayakan potensi siswa secara optimal.
Dalam konteks Pendidikan Agama Islam, tujuannya adalah menyediakan, membentuk, dan membangun kecerdasan siswa dalam memahami pengetahuan, tingkah laku, hasil, dan mengasah kemampaun dasar siswa yang diperlukan di Tengah-tengah Masyarakat saat ini. Model pembelajaran yang berbasis masalah atau PBL merupakan suatu inovasi yang relevan dengan tuntutan abad ke-21. PBL mengacu pada karakteristik pembelajaran yang melatih siswa berpikir kritis, mengatasi masalah, berpikir sesuai dengan kenyataan, dan berinteraksi dengan lingkungan sekitarnya.
Metode penelitian yang dilakukan oleh peneliti adalah penelitian pustaka, yang mana data dan bahan yang digunakan berasal dari berbagai sumber literatur. PBL merupakan pendekatan pembelajaran yang berpusat pada siswa, dengan guru sebagai fasilitator. PBL mendorong siswa untuk aktif berpikir, mencari solusi untuk masalah, dan mengonstruksi pengetahuan mereka sendiri.
PBL memiliki beberapa langkah, termasuk klarifikasi konsep, merumuskan masalah, menganalisis masalah, mengumpulkan data, menguji hipotesis, dan menarik kesimpulan. Tujuannya adalah meningkatkan kemampuan siswa dalam berpikir kritis, analitis, sistematis, dan logis, serta mempromosikan sikap ilmiah, kemandirian belajar, dan keterampilan sosial. PBL memiliki manfaat seperti peningkatan pemahaman materi, peningkatan fokus pada pengetahuan relevan, pengembangan keterampilan kritis, sosial, dan belajar, serta motivasi siswa untuk belajar. Model ini mendorong siswa untuk aktif berpartisipasi dalam proses pembelajaran, mengembangkan pemahaman mereka sendiri, dan memecahkan masalah secara kreatif. PBL juga memfasilitasi pembelajaran berkelanjutan dan meningkatkan minat siswa dalam pembelajaran. Dengan demikian, PBL merupakan pendekatan pembelajaran yang relevan dan efektif untuk menghadapi tantangan pendidikan modern.
PENERAPAN STRATEGI PEMBELAJARAN POINT COUNTER POINT (PCP) DALAM MATA PELAJARAN FIQH DI KELAS VIII-A MTS NEGERI 1 PAMEKASAN
Authors: Rohmah Nurul Hidayatur , Arif Saiful 
Published: June 2024

ABSTRAK
Strategi pembelajaran merupakan upaya terencana dan tersusun termasuk juga dalam penggunaan metode dan pemanfaatan dari berbagai sumber daya yang ada dalam proses pembelajaran. Strategi Point Counter Point (PCP) merupakan suatu cara dalam proses pembelajaran yang memberikan kesempatan pada peserta didik untuk aktif dalam berargumen dari problem yang ada dalam pembelajaran. Dengan menggunakan penerapan pembelajaran seperti Point Counter Point (PCP) ini diharapkan siswa bisa memperluas gagasan, bertukar pikiran antar teman, dan sebagai tambahan strategi dalam kegiatan pembelajaran di kelas. Meskipun tidak menutup kemungkinan dalam penerapan strategi ini terdapat kelamahan dan kelebihan nya masing-masing.
Дизайн книжкових видань із використанням ШІ (практики американського та українського книговидання)
Authors: Водолазька Світлана Анатоліївна , Крайнікова Тетяна Степанівна 
Published: June 2024

У статті розглянуто юридичні та виробничі проблеми, можливості та перспективи застосування ШІ-систем у книжковому дизайні.
У серпні–грудні 2023 р. проведено якісні та кількісні дослідження американського та українського книжкових ринків (моніторинг за ключовими словами на Amazon.com, нестандартизовані експертні інтерв’ю, дискурс-аналіз інтернет-ресурсів).
Згідно із зібраними на сайті Amazon.com даними, у підготовці 261 видання, де для ілюстрування використано ШІ, найчастіше застосовано Midjourney AI, DALL-E 2 та DALL-E.
Наразі ШІ-системи (Midjourney, DALL-E, Leonardo A.I., Adobe Firefly та ін.) не здатні створювати бездоганний та унікальний дизайн «під ключ». Серед виробничих проблем: функціональна обмеженість ШІ-систем, фактична недостовірність, брак індивідуального стилю, емоційної виразності в згенерованих зображеннях, несталість образів (проблема «катастрофічного забування») та ін.
Крім того, ШІ-системи схильні до плагіату. Виявлено основні юридичні ризики застосування ШІ: навчання ШІ на чужому контенті без дозволів, використання неперевірених стокових фото, невизначена ситуація з авторством тощо, що призводить до звинувачень у плагіаті та репутаційних втрат.
Однак мультимодальні ШІ-системи невпинно вдосконалюються, пропонуючи дизайнерам усе більші інструментальні можливості. Використання ШІ-систем у книжковому дизайні дає змогу: аналізувати тренди, знаходити ідеї та образи, які резонують з аудиторією; масштабувати робочі навантаження; заощаджувати час та кошти.
Зроблено висновок про переважання можливостей над ризиками технології, тому колаборація дизайнерів та ШІ-систем ставатиме все тіснішою задля досягнення найкращих результатів. З огляду на відворотність подальшої інтеграції ШІ в редакційні процеси, артикульовано потребу масштабної фахової перепідготовки книжкових дизайнерів.
PENGARUH PENGETAHUAN KEWIRAUSAHAAN DAN EFIKASI DIRI TERHADAP MINAT BERWIRAUSAHA MAHASISWA PENDIDIKAN ADMINISTRASI PERKANTORAN FKIP UNS
Authors: Hidayat Azis Rahmat , Ninghardjanti Patni , Susantiningrum Susantiningrum 
Published: June 2024

<p><em> </em><em>The aims of the study are to determine: (1) the effect of entrepreneurial knowledge on interest in entrepreneurship (2) the effect of self-efficacy on interest in entrepreneurship (3) the influence of entrepreneurial knowledge and self-efficacy on interest in entrepreneurship. The research used quantitative proportional random sampling method with a total of 60 from 148 populations. Data collection by questionnaire. Analysis using multiple linear regression technique with analysis prerequisite test: normality test, linearity test and multicollinearity test. The results of the study: (1) there is a significant effect of entrepreneurial knowledge on entrepreneurial interest tcount is greater than the results of the t-test analysis obtained by the value of tcount (2.397)&gt; ttable (1.984) the significance value is less than 0.10 (0.000 &lt;0.10); (2) there is a significant effect of self-efficacy on students' interest in entrepreneurship, tcount is greater than the results of the t-test analysis, it is obtained that tcount (2.520) &gt; ttable (1.984) the significance value is less than 0.10 (0.006 &lt;0.10); (3) there is an influence of entrepreneurial knowledge and self-efficacy on interest in entrepreneurship. Fcount is greater than the value of Ftable (Fcount &gt; Ftable, which is 11.988 &gt; 3.92), the significance value is less than 0.10 (0.000 &lt; 0.10) . The entrepreneurial knowledge variable gave an effective contribution of 13.70% and a relative contribution of 48.22%, while the self-efficacy variable gave an effective contribution of 14.67% and a relative contribution of 51.6%</em></p>
Pengaruh pengawasan dan disiplin kerja terhadap semangat kerja pegawai Disdagnakerkop UKM Kabupaten Karanganyar
Authors: Aini Aisyah Nur , Murtini Wiedy , Ninghardjanti Patni 
Published: June 2024

<p><em>This research aims to determine: (1) whether there is an influence of supervision on employee work passion at Disdagnakerkop UKM Kabupaten Karanganyar; (2) whether there is an influence of work discipline on employee work passion at Disdagnakerkop UKM Kabupaten Karanganyar; and (3) whether there is an influence of supervision and work discipline on employee work passion at Disdagnakerkop UKM Kabupaten Karanganyar. Quantitative research approach with a correlational method. The research population is all employees, totaling 110 people. The sampling technique used is simple random sampling, with 86 employees as the sample. The data was collected using questionnaires, interviews, observations, and documentation. The data analysis technique used the prerequisite test and multiple linear regression analysis techniques using SPSS v25.0. The results of this study explained that: (1) there is a positive and significant effect of supervision on employee work passion (t<sub>count</sub> 2.868 &gt; tt<sub>able</sub> 1.988 and a significance of 0.005 &lt;0.05); (2) there is a positive and significant effect of work discipline on employee work passion (t<sub>count</sub> 4.423 &gt; tt<sub>able</sub> 1.988 and a significance of 0.000 &lt;0.05); (3) there is a positive and significant effect of supervision and work discipline on employee work passion (F<sub>count</sub> 31.060 &gt; F<sub>table</sub> 3.11 and a significance of 0.000 &lt;0.05).</em></p>
Penerapan i-pos dalam meningkatkan pelayanan pelanggan di PT Pos Indonesia Wilayah Surakarta
Authors: Nur Sabila Salma , Subarno Anton , Susantiningrum Susantiningrum 
Published: June 2024

<p><em>This study aimed to determine</em><em>: (1)</em><em> How</em><em> </em><em>is </em><em>I-POS application at PT. Pos Surakarta in improving customer service. (2) </em><em>W</em><em>hat</em><em> </em><em>obstacles exist in implementing I-POS to improve PT customer service? Pos Surakarta. (3) </em><em>What </em><em>efforts</em><em> </em><em>need to be made by PT. Pos Surakarta in overcoming obstacles to the implementation of I-POS.</em><em> </em><em>This study uses a qualitative</em><em> </em><em>method with a case study approach.</em><em> </em><em>Data sources are obtained from informants, places and events, documents, and archives</em><em>. </em><em>The sampling technique used purposive sampling and snowball sampling. Data collection techniques used are interviews, observation, and documentation. Validity test using source triangulation and method triangulation. The data analysis technique uses an interactive analysis model. </em><em>The results of the study</em><em>: (1)</em><em> </em><em>PT. Pos Surakarta has implemented I-POS to improve customer service, starting from</em><em> </em><em>collecting, processing, transportation, delivery,</em><em> </em><em>and</em><em> </em><em>reporting</em><em>,</em><em> with accurate and timely implementation</em><em>. (2) </em><em>The obstacles were an u</em><em>nstable network, errors and slowness, and an invalid I-Pos system.</em><em> </em><em>(3</em><em>) Solutions</em><em> to overcome obstacles</em><em> are done by </em><em>contacting the IT department to make repairs, developing </em><em>and </em><em>updat</em><em>ing</em><em> </em><em>the</em><em> I-Pos </em><em>system,</em><em> and reviewing the management information system</em><em> of </em><em> </em><em>I-Pos.</em><em></em></p>
Pelaksanaan pelayanan jemput bola pada PT BPR BKK Jateng Cabang Karanganyar
Authors: Widyaningrum Lufiana , Murwaningsih Tri , Rapih Subroto 
Published: June 2024

<p dir="ltr"><span>This study aims to determine (1) the implementation of the ball pick-up system service and (2) the results of the CIPP (Context, input, process, product) evaluation of the ball pick-up system service. This is an evaluation research with a qualitative descriptive approach using the CIPP (Context, input, process, product) evaluation model. The results of the study are as follows: 1) the implementation of the ball pick-up system service includes the procedure for implementing the ball shuttle service program, the facilities and infrastructure of the ball pick-up service program and the implementing officers of the ball shuttle service program, (2) The results of: a) context evaluation shows that PT BPR BKK Jateng Cabang Karanganyar already has guidelines for implementing the ball pick-up system service, the targets served are all communities around Karanganyar Regency b) input evaluation shows that the facilities and infrastructure are quite adequate, training has been attended by all employees implementing the ball shuttle service, c) process evaluation shows that employee competence is good enough in providing services to customers, there is already an evaluation carried out every month there are supporting and inhibiting factors for the implementation of the ball pick-up system service, d) product evaluation shows that customers have high loyalty to the company, the amount of savings and the number of customers has increased.</span></p><div><span><br /></span></div>
The efficacy of teaching modules in enhancing students' sense of physics: Newton's laws
Authors: Sari Annisa Maya , Purwaningsih Endang , Khusaini Khusaini 
Published: June 2024

Sensemaking plays a crucial role as a bridge for students' understanding and intuition with explanations, thus addressing knowledge gaps. This bridging function helps students build new knowledge and comprehend related content materials. However, when facing physics problems, most students tend to engage in "answer-making" by presenting answers in the form of mathematical equations. This phenomenon of engaging in "answer-making" eventually causes students to perceive that physics does not "make sense." In response to this concern, a valid teaching module on improving students' sense of physics has been developed. This study is a quasi-experiment with a one-group pretest-posttest design. The posttest outcomes reveal an enhancement in the students' sense of physics among 60 students from two schools in Malang and Batu after they used the teaching module on Newton's Laws. However, when examining each indicator of students' sense of physics, further efforts are still needed to enhance the level of students' sense of physics.
Adaptation of fire safety norms at an enterprise
Authors: Ushakova I. N. , Svistun A. L. 
Published: June 2024

Safe operation of enterprises in the metallurgical and foundry industries largely depends on ensuring fire safety. Therefore, at enterprises, the adaptation of fire safety norms is of great importance. Categorization of premises and buildings according to explosion and fire hazards is carried out. The article provides an example of calculating the categorization of a room where there is no release of radiant heat, sparks, and flames – a garage for storing vehicles. This facility can be located in the same room or building as foundry and metallurgical shops.