bluuebunny/crossref_metadata_2025_split huggingface dataset:
Nitrogen and argon release profiles in Luna 16 and Luna 24 regolith samples: The effects of regolith reworking
Authors: Assonov S. S. , Franchi I. A. , Pillinger C. T. , Semenova A. S. , Shukolyukov Yu. A. , Verchovsky A. B. , Iassevitch A. N. 
Published: January 2010

Abstract— Fines, microbreccias and agglutinates from the Luna 16 mature regolith 1635 and fines from the immature/submature Luna 24 regolith have been analysed for N and argon isotopes in order to understand the origin of isotopically distinct N released at different temperatures. All high‐resolution runs reveal a similarity in the release of 36Ar, 40Ar and N over a wide temperature interval. The similarity in the 40Ar and 36Ar releases and the near coincidence in the 1635 agglutinates implies that the implanted species were redistributed and homogenised during regolith processing such that, regardless of the huge difference in ion implantation energy between solar 36Ar and non‐solar 40Ar, their present distribution and their release temperatures are now essentially equal. A small amount of 40Ar released in the lower temperature steps with elevated 40Ar/36Ar is considered to be trapped after reworking.While such mixing and homogenisation may also be expected for N components of different origins, to date all known stepped runs regularly demonstrate a reproducible variation in δ15N, suggesting no homogenisation. We consider regolith N to be a mixture of several components trapped at different times, and some nitrogen that was not involved in the reworking. Relatively heavy N released around 500 °C appears to be the most pure form of the component trapped after reworking, probably from accreted meteoritic matter. Middle‐temperature isotopically lighter N appears to be a mixture of solar and non‐solar N largely homogenised, and therefore solar N can not be seen in its pure form. Bulk δ15N as well as formally deconvoluted δ15N thermal profiles imply that the non‐solar N has a variable δ15N value. Several non‐solar N sources are considered with their input resulting in increasing regolith δ15N with time. Because N from meteorites and interplanetary dust particles appear to be dominant, a mechanism is required to reduce the C/N ratio typical of meteoritic matter to that approaching the low value observed in the lunar regolith. Preferential loss of methane appears to be a viable explanation, following generation either by proton sputtering or in reducing vapour plumes.
Major element fractionation in chondrites by distillation in the accretion disk of a T Tauri Sun?
Authors: Hutchison Robert 
Published: January 2010

Abstract— Redistribution or loss of batches of condensate from a cooling protosolar nebula is generally thought to have led to the formation of the chemical groups of chondrites. This demands a nebula hot enough for silicate vaporization over 1–3 AU, the region where chondrites formed. Alternatively, heating of a protosolar accretion disk may have been confined to an annular zone at its inner edge, ˜0.06 AU from the protosun. Most infalling matter was accreted by the protosun, but a proportion was heated and carried outwards by an x‐wind. Shu et al. (1996, 1997) proposed that larger objects such as chondrules and calcium‐aluminum‐rich inclusions (CAIs) were returned to the disk at asteroidal distances by sedimentation from the x‐wind. Fine dust and gas were lost to space. The model implies that solids were not lost from the cold disk. The chemical compositions of the chondrite groups were produced by mixing different proportions of CAIs and chondrules with disk solids of CI composition. Heating at the inner edge of the disk was accompanied by particle irradiation, which synthesized nuclides including 26Al.The x‐wind model can produce CAIs, not chondrules, and allows survival of presolar grains >0.06 AU from the protosun. Normalization to Al and CI indicates that non‐carbonaceous chondrites may be disk material that gained a Si‐ and Mg‐enriched fraction. Carbonaceous chondrites are different; they appear to be CI that lost lithophile elements more volatile than Ca. Five carbonaceous chondrite groups also lost Ni and Fe but the CH group gained siderophiles. Elemental loss from CI is incompatible with the x‐wind model. Silicon and CI normalization confirms that the CM, CO, CK and CV groups may be CI that gained refractories as CAIs. The Si‐, Mg‐rich fraction may have formed by selective vaporization followed by precipitation on grains in the x‐wind. This fractional distillation mechanism can account for lithophile element abundances in non‐carbonaceous chondrite groups, but an additional process is required for the loss of Ca and Mn in the EL group and for fractionated siderophile abundances in the H, L and LL groups. Heated and recycled fractions were not homogenized across the disk so the chondrite groups were established in a single cycle of enhanced protosolar activity in lt;104 years, the time for a millimeter‐sized particle to drift into the Sun from 2 to 3 AU, due to gas‐drag.
443 Eros: Problems with the meteorite magnetism record in attempting an asteroid match
Authors: Wasilewski P. , Acuña M. H. , Kletetschka G. 
Published: January 2010

Abstract—The magnetometer experiment (MAG) onboard theNear‐Earth Asteroid Rendezvous (NEAR)‐Shoemakerspacecraft detected no global scale magnetization and established a maximum magnetization of 2.1 times 10−6Am2kg−1for asteroid 433 Eros. This is in sharp contrast with the estimated magnetization of other S‐class asteroids (Gaspra, ˜2.4 times 10−2Am2kg−1; Braille, ˜2.8 times 10−2Am2kg−1) and is below published values for all types of ordinary chondrites. This includes the L/LL types considered to most closely match 433 Eros based on preliminary interpretations of NEAR remote geochemical experiments.The ordinary chondrite meteorite magnetization intensity data was reviewed in order to assess the reasonableness of an asteroid‐meteorite match based on magnetic property measurements. Natural remanent magnetization (NRM) intensities for the ordinary chondrite meteorites show at least a 2 order of magnitude range within each of the H, L, and LL groups, all well above the 2.1 times 10−6Am2kg−1level for 433 Eros. The REM values (ratio of the NRM to the SIRM (saturation remanent magnetization)) range over 3 orders of magnitude for all chondrite groups indicating no clear relationship between NRM and the amount of magnetic material. Levels of magnetic noise in chondrite meteorites can be as much as 70% or more of the NRM. Consequently, published values of the NRM should be considered suspect unless careful evaluation of the noise sources is done. NASA Goddard SFC studies of per unit mass intensities in large (>10 000 g) and small (down to <1 g) samples from the same meteorite demonstrate magnetic intensity decreases as size increases. This would appear to be explained by demagnetization due to magnetic vector randomness at unknown scale sizes in the larger samples. This would then argue for some level of demagnetization of large objects such as an asteroid. The possibility that 433 Eros is an LL chondrite cannot be discounted.
Boltysh, another end‐Cretaceous impact
Authors: Kelley Simon P. , Gurov Eugene 
Published: January 2010

Abstract— The Chixculub impact occurred at the Cretaceous/Tertiary (K/T) boundary, and although several other Late Cretaceous and Paleogene impact craters have, at times, been linked with the K/T boundary, isotope geochronology has demonstrated that all have significantly different ages. The currently accepted age of the 24 km diameter Boltysh crater, a K‐Ar whole‐rock age, places it in the Coniacian at 88 ± 3 Ma. However, comprehensive Ar‐Ar dating of a range of melt samples yields a mean age of 65.17 ± 0.64 Ma, within errors of the K/T boundary. Several of the fresh samples exhibit signs of excess argon but this seems to be concentrated in rapidly crystallized glass‐rich samples.The Ar‐Ar age confirms an earlier fission track measurement and thus two dating techniques have yielded an age within errors of the K/T boundary for this crater. Crucially, although the ages of Boltysh and Chixculub are within errors, they may not have formed synchronously. Craters of 24 km diameter occur much more commonly than impacts of Chixculub dimensions, but their proximity does raise the important question of how many impacts there might have been close to the K/T boundary.
The basaltic shergottite Northwest Africa 856: Petrology and chemistry
Authors: JAMBON A. , BARRAT J. A. , SAUTTER V. , GILLET Ph. , GÖPEL C. , JAVOY M. , JORON J. L. , LESOURD M. 
Published: January 2010

Abstract— We report on the discovery of a new shergottite from South Morocco. This single stone weighing 320 g is referenced as Northwest Africa (NWA) 856 with Djel Ibone as a synonymous name. It is a fresh, fine‐grained basaltic rock consisting mainly of two pyroxenes (total ˜68 vol%: 45% pigeonite, En61‐16Wo9–22Fs26–68; 23% augite, En46‐26Wo34‐29Fs21–43) and plagioclase converted to maskelynite (˜23 vol%, Ab43–57Or1–5An54‐36). Accessory minerals include merrillite, Cl‐apatite, pyrrhotite, ilmenite, ulvöspinel, silica (stishovite and glass), amorphous K‐feldspar and baddeleyite. Amorphous mixtures of maskelynite and silica occur most commonly as median layers inside maskelynite laths. In addition, melt pockets (˜2 vol%) were recognized with relics of maskelynite, pyroxene and both dense silica glass and stishovite occurring as both grains and submicrometer needles. The compositions of the melt pockets are consistent with mixtures of maskelynite and pyroxenes with an average of ˜50 vol% maskelynite. The meteorite is highly fractured at all scales.The bulk composition of NWA 856 has been measured for 44 elements. It is an Al‐poor ferroan basaltic rock which strongly resembles Shergotty and Zagami in its major and trace element composition.The nearly flat rare earth element (REE) pattern (La/Lu)n = 0.9, is similar to that of Shergotty or Zagami and differs significantly from NWA 480, another Moroccan shergottite recently described. According to the U, Ba and Sr abundances, NWA 856 is not significantly weathered. The oxygen isotopes (δ18O = +5.03%, δ17O = +3.09%, and Δ17O = +0.47%) are in agreement with the martian origin of this meteorite.On the basis of grain size, pyroxene zoning and composition, abundance of silica inclusions associated with maskelynite, trace element abundances, REE pattern and oxygen isotopes, pairing with NWA 480 is excluded. The similarity with Shergotty and Zagami is striking. The only significant differences are a larger grain size, a greater abundance of silica and melt pockets, a slightly more restricted range of pyroxene compositions and the absence of significant mesostasis.
A model of the thermal processing of particles in solar nebula shocks: Application to the cooling rates of chondrules
Authors: DESCH S. J. , CONNOLLY H. C. 
Published: January 2010

Abstract— We present a model for the thermal processing of particles in shock waves typical of the solar nebula. This shock model improves on existing models in that the dissociation and recombination of H2 and the evaporation of particles are accounted for in their effects on the mass, momentum and energy fluxes. Also, besides thermal exchange with the gas and gas‐drag heating, particles can be heated by absorbing the thermal radiation emitted by other particles. The flow of radiation is calculated using the equations of radiative transfer in a slab geometry. We compute the thermal histories of particles as they encounter and pass through the shock.We apply this shock model to the melting and cooling of chondrules in the solar nebula. We constrain the combinations of shock speed and gas density needed for chondrules to reach melting temperatures, and show that these are consistent with shock waves generated by gravitational instabilities in the protoplanetary disk. After their melting, cooling rates of chondrules in the range 10–1000 K h−1 are naturally reproduced by the shock model. Chondrules are kept warm by the reservoir of hot shocked gas, which cools only as fast as the dust grains and chondrules themselves can radiate away the gas's energy. We predict a positive correlation between the concentration of chondrules in a region and the cooling rates of chondrules in that region. This correlation is supported by the unusually high frequency of (rapidly cooled) barred chondrules among compound chondrules, which must have collided preferentially in regions of high chondrule density. We discuss these and other compelling consistencies between the meteoritic record and the shock wave model of chondrule formation.
Calcium‐aluminum‐rich inclusions and amoeboid olivine aggregates from the CR carbonaceous chondrites
Authors: Aléon Jérôme , Krot Alexander N. , McKeegan Kevin D. 
Published: January 2010

Abstract— Calcium‐aluminum‐rich refractory inclusions (CAIs) in CR chondrites are rare (<1 vol%), fairly small (<500 μm) and irregularly‐shaped, and most of them are fragmented. Based on the mineralogy and petrography, they can be divided into grossite ± hibonite‐rich, melilite‐rich, and pyroxene‐anorthite‐rich CAIs. Other types of refractory objects include fine‐grained spinel‐melilite‐pyroxene aggregates and amoeboid olivine aggregates (AOAs). Some of the pyroxene‐anorthite‐rich CAIs have igneous textures, and most melilite‐rich CAIs share similarities to both the fluffy and compact type A CAIs found in CV chondrites. One major difference between these CAIs and those in CV, CM, and CO chondrites is that secondary mineral phases are rare.In situ ion microprobe analyses of oxygen‐isotopic compositions of 27 CAIs and AOAs from seven CR chondrites demonstrate that most of the CAIs are 16O‐rich (δ17O of hibonite, melilite, spinel, pyroxene, and anorthite < −22‰) and isotopically homogeneous within 3–4‰. Likewise, forsterite, spinel, anorthite, and pyroxene in AOAs have nearly identical, 16O‐rich compositions (−24‰ < δ17O < −20‰). In contrast, objects which show petrographic evidence for extensive melting are not as 16O‐rich (δ17O less than −18‰). Secondary alteration minerals replacing 16O‐rich melilite in melilite‐rich CAIs plot along the terrestrial fractionation line.Most CR CAIs and AOAs are mineralogically pristine objects that largely escaped thermal metamorphism and secondary alteration processes, which is reflected in their relatively homogeneous 16O‐rich compositions. It is likely that these objects (or their precursors) condensed in an 16O‐rich gaseous reservoir in the solar nebula. In contrast, several igneous CAIs are not very enriched in 16O, probably as a result of their having melted in the presence of a relatively 16O‐poor nebular gas. If the precursors of these CAIs were as 16O‐rich as other CR CAIs, this implies either temporal excursions in the isotopic composition of the gas in the CAI‐forming regions and/or radial transport of some CAI precursors into an 16O‐poor gas. The absence of oxygen isotope heterogeneity in the primary minerals of melilite‐rich CAIs containing alteration products suggests that mineralogical alteration in CR chondrites did not affect oxygen‐isotopic compositions of their CAIs.
Northwest Africa 482: A crystalline impact‐melt breccia from the lunar highlands
Authors: Daubar Ingrid J. , Kring David A. , Swindle Timothy D. , Jull A. J. Timothy 
Published: January 2010

Abstract—Northwest Africa 482 (NWA 482) is a crystalline impact‐melt breccia from the Moon with highlands affinities. The recrystallized matrix and the clast population are both highly anorthositic. Clasts are all related to the ferroan anorthosite suite, and include isolated plagioclase crystals and lithic anorthosites, troctolites, and spinel troctolites. Potassium‐, rare‐earth‐element‐, and phosphorus‐bearing (KREEP) and mare lithologies are both absent, constraining the source area of this meteorite to a highland terrain with little to no KREEP component, most likely on the far side of the Moon. Glass is present in shock veins cutting through the sample and in several large melt pockets, indicating a second impact event.There are two separate events recorded in the40Ar‐39Ar system: one at ∼3750 Ma, which completely reset the K‐Ar system, and one at ≲2400 Ma, which caused only partial degassing. These events could represent, respectively, crystallization of the impact‐melt breccia and later formation of the glass, or the formation of the glass and a later thermal event.The terrestrial age of the meteorite is 8.6 ± 1.3 ka. This age corresponds well with the modest amount of weathering in the rock, in the form of secondary phyllosilicates and carbonates. Based on terrestrial age and location, lithology, and chemistry, NWA 482 is unique among known lunar meteorites.
Thermophysical analysis of infrared observations of asteroids
Authors: Müller Thomas G. 
Published: January 2010

Abstract— Visual photometry, which measures reflected solar radiation, can be combined with infrared radiometry, which measures absorbed and re‐radiated solar energy, to determine key properties of small solar system objects. This method can be applied via thermophysical model concepts not only for albedo and diameter determination, but also for studies of thermal parameters like thermal inertia, surface roughness or emissivity. Hence, a detailed analysis of the asteroid surface is possible and topics like surface mineralogy, the density of the regolith or the presence of a rocky surface, lightcurve influences due to shape or albedo, porosity of the surface material, etc. can be addressed.The “radiometric technique” based on a recently developed thermophysical model is presented. The model was extensively tested against observations from the infrared space observatory, including spectroscopic and photometric measurements at infrared wavelengths between 2 and 200 μm of more than 40 asteroids. The possible model applications are discussed in terms of the different levels of knowledge for individual asteroids. The effects of the thermal parameters are illustrated and methods are presented as to how to separate different aspects. Possibilities and limitations are evaluated for the possible transfer of this model to near‐Earth asteroids. In the long run, this kind of study of near‐Earth asteroids may provide answers to questions about their surface properties which are crucial to develop mitigation scenarios.
Spinels and oxygen fugacity in olivine‐phyric and lherzolitic shergottites
Authors: GOODRICH Cyrena Anne , HERD Christopher D. K. , TAYLOR Lawrence A. 
Published: January 2010

Abstract— We examine the occurrences, textures, and compositional patterns of spinels in the olivine‐phyric shergottites Sayh al Uhaymir (SaU) 005, lithology A of Elephant Moraine A79001 (EET‐A), Dhofar 019, and Northwest Africa (NWA) 1110, as well as the Iherzolitic shergottite Allan Hills (ALH) A77005, in order to identify spinel‐olivine‐pyroxene assemblages for the determination of oxygen fugacity (using the oxybarometer of Wood [1991]) at several stages of crystallization. In all of these basaltic martian rocks, chromite was the earliest phase and crystallized along a trend of strict Cr‐Al variation. Spinel (chromite) crystallization was terminated by the appearance of pyroxene but resumed later with the appearance of ulvöspinel. Ulvöspinel formed overgrowths on early chromites (except those shielded as inclusions in olivine or pyroxene), retaining the evidence of the spinel stability gap in the form of a sharp core/rim boundary (except in ALH A77005, where subsolidus reequilibration diffused this boundary). Secondary effects seen in chromites include reaction with melt before ulvöspinel overgrowth, reaction with melt inclusions, reaction with olivine hosts (in ALH A77005), and exsolution of ulvöspinel or ilmenite. All chromites experienced subsolidus Fe/Mg reequilibration. Spinel‐olivine‐pyroxene assemblages representing the earliest stages of crystallization in each rock essentially consist of the highest‐Cr#, lowest‐fe# chromites not showing secondary effects plus the most magnesian olivine and equilibrium low‐Ca pyroxene. Assemblages representing the onset of ulvöspinel crystallization consist of the lowest‐Ti ulvöspinel, the most magnesian olivine in which ulvöspinel occurs as inclusions, and equilibrium low‐Ca pyroxene.The results show that, for early crystallization conditions, oxygen fugacity (fO2) increases from SaU 005 and Dhofar 019 (˜QFM ‐3.8), to EET‐A (QFM ‐2.8) and ALH A77005 (QFM ‐2.6), to NWA 1110 (QFM ‐1.7). Estimates for later conditions indicate that in SaU 005 and Dhofar 019 oxidation state did not change during crystallization. In EET‐A, there was an increase in fO2 that may have been due to mixing of reduced material with a more oxidized magma. In NWA 1110, there was a dramatic increase, indicating a non‐buffered system, possibly related to its high oxidation state. Differences in fO2 among shergottites are not primarily due to igneous fractionation but, rather, to derivation from (and possibly mixing of) different reservoirs.
Constraints on the structure of the martian interior determined from the chemical and isotopic systematics of SNC meteorites
Authors: JONES J. H. 
Published: January 2010

Abstract— The crystallization ages of martian (SNC) meteorites give evidence that martian volcanism has continued until recent times‐perhaps until the present. These meteorites also indicate that the mantle source regions of this volcanism are modestly to extremely depleted by terrestrial standards. These 2 observations produce a conundrum. How is it that such depleted source regions have produced basaltic magma for such a long time?This contribution attempts to quantify the radiogenic heat production in 2 distinct martian mantle source regions: those of the shergottites and nakhlites. Compared to the depleted upper mantle of the Earth (MORB), the nakhlite source region is depleted by about a factor of 2, and the shergottite source region is depleted by a factor of 6. According to current geophysical models, the nakhlite source contains the minimum amount of radioactive heat production to sustain whole‐mantle convection and basalt generation over geologic time. A corollary of this conclusion is that the shergottite source contains much too little radioactivity to produce recent (<200 Ma) basalts. A model martian interior with a deep nakhlite mantle that is insulated by a shallow shergottite mantle may allow basalt production from both source regions if the divide between the nakhlite‐shergottite mantles acts as a thermal boundary layer. Similarities between lunar and martian isotopic reservoirs indicate that the Moon and Mars may have experienced similar styles of differentiation.