bluuebunny/crossref_metadata_2025_split huggingface dataset:
Explorations of the chemical constitution and aqueous solution status of caries-arresting silver(I)-diammine fluoride and silver(I)-fluoride products using high-resolution 19F NMR analysis. Spectroscopic and SEM investigations of their interactions with human saliva: evidence for the in vivo salivary-catalysed autoconstruction of Ag/AgCl-based nanoparticles (IV-SCAN)—part I
Authors: Hunwin Kayleigh , Page Georgina , Edgar Mark , Botana Adolfo , Armitage Rachel , Bhogadia Mohammed , Desai Unmesh , Duffin Steven , Duffin Marcus , Chan Wyman , Grootveld Martin 
Published: June 2024

IntroductionSilver(I)-diammine fluoride (SDF) and silver(I)-fluoride (SF) complexes have been successfully employed for the arrest of dental caries for many years. However, to date there are very few studies available reporting on the molecular structural compositional and solution status of these agents [typically applied as highly-concentrated 38% (w/v) solutions]. Here, we explored the solution status and chemical constitution of commercially-available SDF and SF products, and secondly investigated the multicomponent interplay of these products with biomolecules present in intact human whole-mouth salivary supernatants (WMSSs) in vitro.MethodsHigh-resolution 19F NMR analysis was employed to explore SDF and SF product solutions, and to determine WMSS fluoride (F−) concentrations, whereas ammonia (NH3) release form SDF was tracked by 1H NMR spectroscopy. SEM and thin-film FTIR-ATR analyses were employed to explore the atomic and molecular compositions of sequentially-generated AgCl deposits and chromophoric Ag/AgCl nanoparticles (CSNPs); the time-dependent generation of the latter was followed spectrophotometrically.Results19F NMR spectra of aqueous SF solutions contained a very broad F− signal (Δv1/2 70 Hz), demonstrating that much of its solvated F− content was rapidly exchanging with Ag(I) on the NMR timescale, but those of SDF had a much sharper resonance, similar to that of “free” F− (4 Hz). Moreover, further NMR results revealed that a popular SDF product contained high molar excesses of both F− and NH3. Treatment of WMSSs with SDF and SF generated an off-white precipitate, which slowly developed into CSNPs at 23°C; SEM demonstrated high contents of both silver and chloride in this material (ca.1:1 atomic content ratio). FTIR-ATR analysis found that the CSNPs formed contained a range of salivary biomolecules, which appear to encapsulate the Ag/AgCl core (significant thiocyanate contents were also found). In conclusion, NMR results acquired demonstrated that SF, but not SDF, product solutions feature rapidly-exchanging F− between its “free” and Ag(I)-bound forms, and that SDF contains large excesses of both F− and its NH3 ligands. Characterised AgCl deposits and CSNPs were sequentially produced from the interactions of these complexes with WMSS biomolecules.DiscussionIn view of their well-known microbicidal and cariostatic properties, the observed autobioconstruction of CSNPs involving salivary catalysis is of much therapeutic significance.
Oncological outcomes in minimally invasive vs. open distal pancreatectomy: a systematic review and network meta-analysis
Authors: Zhun Hong Wong Nicky , Wei Ting Yap Dominic , Lei Ng Sherryl , Yu Ning Ng Junie , James Juanita Jaslin , Wei Chieh Kow Alfred 
Published: June 2024

BackgroundAdvancements in surgical techniques have improved outcomes in patients undergoing pancreatic surgery. To date there have been no meta-analyses comparing robotic and laparoscopic approaches for distal pancreatectomies (DP) in patients with pancreatic adenocarcinoma (PDAC). This systematic review and network meta-analysis aims to explore the oncological outcomes of laparoscopic distal pancreatectomy (LDP), robotic distal pancreatectomy (RDP) and open distal pancreatectomy (ODP).MethodsA systematic search was conducted for studies reporting laparoscopic, robotic or open surgery for DP. Frequentist network meta-analysis of oncological outcomes (overall survival, resection margins, tumor recurrence, examined lymph nodes, administration of adjuvant therapy) were performed.ResultsFifteen studies totalling 9,301 patients were included in the network meta-analysis. 1,946, 605 and 6,750 patients underwent LDP, RDP and ODP respectively. LDP (HR: 0.761, 95% CI: 0.642–0.901, p = 0.002) and RDP (HR: 0.757, 95% CI: 0.617–0.928, p = 0.008) were associated with overall survival (OS) benefit when compared to ODP. LDP (HR: 1.00, 95% CI: 0.793–1.27, p = 0.968) was not associated with OS benefit when compared to RDP. There were no significant differences between LDP, RDP and ODP for resection margins, tumor recurrence, examined lymph nodes and administration of adjuvant therapy.ConclusionThis study highlights the longer OS in both LDP and RDP when compared to ODP for patients with PDAC.Systematic Review Registrationhttps://www.crd.york.ac.uk/, PROSPERO (CRD42022336417).
An intronic SNP affects skeletal muscle development by regulating the expression of TP63
Authors: Chen Yufen , Wang Zhen , Qu Xiaolu , Song Bangmin , Tang Yueting , Li Bugao , Cao Guoqing , Yi Guoqiang 
Published: June 2024

BackgroundPorcine skeletal muscle development is pivotal for improving meat production. TP63, a transcription factor, regulates vital cellular processes, yet its role in skeletal muscle proliferation is unclear.MethodsThe effects of TP63 on skeletal muscle cell viability and proliferation were investigated using both mouse and porcine skeletal muscle myoblasts. Selective sweep analysis in Western pigs identified TP63 as a potential candidate gene for skeletal muscle development. The correlation between TP63 overexpression and cell proliferation was assessed using quantitative real-time PCR (RT-qPCR) and 5-ethynyl-2’-deoxyuridine (EDU).ResultsThe study revealed a positive correlation between TP63 overexpression and skeletal muscle cell proliferation. Bioinformatics analysis predicted an interaction between MEF2A, another transcription factor, and the mutation site of TP63. Experimental validation through dual-luciferase assays confirmed that a candidate enhancer SNP could influence MEF2A binding, subsequently regulating TP63 expression and promoting skeletal muscle cell proliferation.ConclusionThese findings offer experimental evidence for further exploration of skeletal muscle development mechanisms and the advancement of genetic breeding strategies aimed at improving meat production traits.
Enhancing Water Management in Jordan: A Fresh Tomato Water Footprint Analysis
Authors: Hamaideh Arwa , Al-Zghoul Tharaa , Dababseh Nuha , Jamrah Ahmad 
Published: June 2024

Water footprint (WF) analysis is crucial for comprehending agricultural water usage patterns. This study aims to determine the total WF for tomatoes in Jordan from 1994 to 2023, covering both summer and winter seasons, to inform decision-making regarding tomato cultivation practices in the area. Despite inconsistencies in data recording, particularly regarding fertilizer application and sunshine, the WF serves as a valuable tool for estimating seasonal variations in water requirements and facilitating comparisons between different approaches to water usage for tomatoes. Comparative studies globally suggest variability in WFs due to factors such as climate, irrigation methods, and soil conditions influencing results. In this study, the CROPWAT 8.0 model was employed to analyze input data obtained from the Department of Statistics, NASA POWER, and local farmers near the Baqoura, Deir Alla, and Ghour Alsafi stations. The analysis aimed to determine the green WF (rainfall), blue WF (irrigation), and gray WF (water required to dilute pollutants) at these stations. The results revealed that the total WF during winter was approximately 7217.62, 8417.65, and 14061.42 m3/ton for the Baqoura, Deir Alla, and Ghour Alsafi stations. In summer, the respective values were around 3107.67, 6026.52, and 11847.35 m3/ton. Significant findings include ET green, evapotranspiration (ET) blue, crop water use (CWU) green and blue, and production yield for 2023. The nitrogen application per dunum was also calculated as 368 kg/30 dunum, equating to 123 kg/ha. The significance of these results lies in their potential to inform and optimize water management practices in tomato cultivation, promoting sustainability and resource efficiency.
Quality of Life for Patient with Hypertension in Al-Najaf Al-Ashraf City
Authors: Al-Shiblawi Firas Saad Khait , Çakmak Huri Seval Gönderen 
Published: June 2024

Background: Uncontrolled hypertension affects millions of people worldwide, whether they live in developed or developing countries. According to the WHO, there are around 1.13 billion people in the globe who suffer from hypertension. Every year, almost seven million individuals die as a result of hypertension.
Aim of study: The aim of this study is to evaluate quality of life in hypertension patients treated in al-Najaf teaching hospitals.
Methodology: Descriptive design cross-sectional study was used in the study. The population of the study consists of hypertension patients who are followed up in the Teaching Hospitals in Al-Najaf Al-Ashraf Province/Iraq. The sample of the study consisted of 120 patients who applied to the hospitals on February 1, 2022 and May 1, 2022 and met the research criteria. Study data were collected with Quality Of Life, the Socio demographic data form,
Results :The results of study showed that 35% of the patients were between the ages of 46-55 and 62.5% were female. It is seen that 25% of the evaluated patients are illiterate and 22.5% are high school graduates. 59.2% of the patients resided in the city and 73.3% of them had hypertension between 1-10 years. It was observed that the quality of life increased as the age of the patients increased and the highest quality of life was statistically higher in the 66-75 age range (p<0,05). It has been determined that the quality of life of individuals who do not work and who have a disease year of 21-30 years is high (p<0,05).
Conclusion: The median quality of life of patients differs radically by demographic factors like age, level of education, occupation, and length of disease. Patient awareness is significantly related to demographic variables such as age, education, occupation, and duration of disease.
Recommendation : The study recommended to Encourage patients to regular monitoring of blood pressure. And Educated them about anxiety and depression management to enhance their psychological status.
Upaya Pengoptimalan Laba dengan Metode Pencatatan dan Metode Penilaian Persediaan
Authors: Trianingsih Ria Ayu , Ashari Muhammad Hasyim 
Published: June 2024

The purpose of this research is to choose a method of recording and valuing inventory of finished goods that can increase profits at CV Istana Boneka Malang. The research approach used in this study is a quantitative approach. The analysis technique used is to use a comparison between perpetual and periodic inventory recording methods to determine the cost of goods sold and gross profit earned by the company. The results showed that the selection of the method of recording and valuation at CV Istana Boneka Malang that should be used is the inventory recording method using the LIFO inventory valuation method, where this method provides a higher gross profit than other valuation methods. However, as stated in Article 10 paragraph (6) of Law Number 36 of 2008 concerning Income Tax which states that the method that is fiscally permissible is the Average or FIFO inventory valuation method, CV Istana Boneka Malang can use the inventory recording method with the inventory valuation method. Average as a consideration of the method produces the highest gross profit after the LIFO inventory valuation method.
ПРАЦЮЄМО ДЛЯ ПЕРЕМОГИ: НАУКОВО-ПРАКТИЧНІ ЗАХОДИ ДЕРЖАВНОЇ НАУКОВО-ПЕДАГОГІЧНОЇ БІБЛІОТЕКИ УКРАЇНИ ІМЕНІ В.О. СУХОМЛИНСЬКОГО В РАМКАХ ВСЕУКРАЇНСЬКОГО ФЕСТИВАЛЮ НАУКИ – 2024
Authors: Berezivska Larysa , Romanova Ganna 
Published: June 2024

У науковому повідомленні охарактеризовано масові науково-практичні заходи, що проведені Державною науково-педагогічною бібліотекою України імені В.О. Сухомлинського в рамках Всеукраїнського фестивалю науки — 2024 в умовах повномасштабної російсько-української війни. Подано інформацію про організаторів, учасників, основні напрями роботи, ключові доповіді, результати та їх висвітлення у публікаціях фахових видань і ЗМІ.
Membangun Kedekatan Guru dan Murid Dalam Proses Pembelajaran
Authors: Basith Yudril 
Published: June 2024

This research aims to find out the importance of building close relationships between teachers and students in the learning process. This close relationship is one of the important factors in education that can have an impact on improving learning achievement, motivation and student involvement. This research uses the Systematic Literature Review (SLR) method. Data collection was taken from the source of scientific publication articles indexed in Google Scholar with the help of Harzing's Publish or Perish software application with the keyword “Teacher and student relationships” so that 500 papers were published in the 2001-2023 time period with a total of 13,659 citations, h-index 58, and g-index 93. Then the study focused on papers published in 2023 as many as 17 papers. Of the 17 papers, abstracts and related titles were read so that 6 papers were found that were relevant to the topic to be studied. Data analysis techniques in this study are planning, conducting and reporting. The study concludes that building close teacher-student relationships is essential in creating a comfortable, inclusive and supportive learning environment. This can be done by teachers with strategies to build emotional bonds, build a positive learning environment, personalized learning, and spiritual approaches, with humorous, dialogical, and interpersonal communication patterns. In building this closeness, there are several challenges and opportunities. Challenges that must be faced are personal differences and backgrounds, time constraints, effective communication, opportunities are knowing individuals deeply, listening and empathy, supporting and empowering, making connections with lesson content.
Thermodynamics of Pickup Ions in the Heliosphere
Authors: Livadiotis G. , McComas D. J. , Shrestha Bishwas. L. 
Published: June 2024

Abstract
The paper shows the thermodynamic nature of the evolution of the pickup ion (PUI) distributions through their incorporation and subsequent expansion as the solar wind moves outward through the heliosphere. In particular, the PUI expansive cooling is connected to thermodynamic polytropic processes and the thermodynamic kappa parameter. Previously, the characterization of the cooling was phenomenologically given by a “cooling index” α, which is the exponent involved in the power-law relationship between PUI speed and position. Here, we develop the relationship between the cooling and polytropic indices. Then, we show the connection between the cooling index and the thermodynamic parameter kappa. Finally, we verify the derived thermodynamic relations with direct heliospheric observations over varying distances from the Sun. Going forward, we suggest that studies of PUIs seeking to understand the underlying physics of these important particles rely on the thermodynamic parameter of kappa, and its association with the polytropic index, and not on an ad hoc cooling index.
ICM-SHOX. I. Methodology Overview and Discovery of a Gas–Dark Matter Velocity Decoupling in the MACS J0018.5+1626 Merger
Authors: Silich Emily M. , Bellomi Elena , Sayers Jack , ZuHone John , Chadayammuri Urmila , Golwala Sunil , Hughes David , Montaña Alfredo , Mroczkowski Tony , Nagai Daisuke , Sánchez-Argüelles David , Stanford S. A. , Wilson Grant , Zemcov Michael , Zitrin Adi 
Published: June 2024

Abstract
Galaxy cluster mergers are rich sources of information to test cluster astrophysics and cosmology. However, cluster mergers produce complex projected signals that are difficult to interpret physically from individual observational probes. Multi-probe constraints on the gas and dark matter (DM) cluster components are necessary to infer merger parameters that are otherwise degenerate. We present Improved Constraints on Mergers with SZ, Hydrodynamical simulations, Optical, and X-ray (ICM-SHOX), a systematic framework to jointly infer multiple merger parameters quantitatively via a pipeline that directly compares a novel combination of multi-probe observables to mock observables derived from hydrodynamical simulations. We report a first application of the ICM-SHOX pipeline to MACS J0018.5+1626, wherein we systematically examine simulated snapshots characterized by a wide range of initial parameters to constrain the MACS J0018.5+1626 merger geometry. We constrain the epoch of MACS J0018.5+1626 to the range 0–60 Myr post-pericenter passage, and the viewing angle is inclined ≈27°–40° from the merger axis. We obtain constraints for the impact parameter (≲250 kpc), mass ratio (≈1.5–3.0), and initial relative velocity when the clusters are separated by 3 Mpc (≈1700–3000 km s−1). The primary and secondary clusters initially (at 3 Mpc) have gas distributions that are moderately and strongly disturbed, respectively. We discover a velocity space decoupling of the DM and gas distributions in MACS J0018.5+1626, traced by cluster-member galaxy velocities and the kinematic Sunyaev–Zel'dovich effect, respectively. Our simulations indicate this decoupling is dependent on the different collisional properties of the two distributions for particular merger epochs, geometries, and viewing angles.
Probing Shocked Ejecta in SN 1987A with XRISM-Resolve: The Effects of the Gate Valve Closed
Authors: Sapienza Vincenzo , Miceli Marco , Bamba Aya , Orlando Salvatore , Lee Shiu-Hang , Nagataki Shigehiro , Ono Masaomi , Katsuda Satoru , Mori Koji , Sawada Makoto , Terada Yukikatsu , Giuffrida Roberta , Bocchino Fabrizio 
Published: June 2024

Abstract
Supernova (SN) 1987A is widely regarded as an excellent candidate for leveraging the capabilities of the freshly launched XRISM satellite. Recent researches indicate that the X-ray emission from SN 1987A will increasingly originate from its ejecta in the years to come. In a previous study, we thoroughly examined the proficiency of XRISM-Resolve in identifying signatures of shocked ejecta in SN 1987A, synthesizing the XRISM-Resolve spectrum based on a state-of-the-art magneto-hydrodynamic simulation. However, following the satellite’s launch, a technical issue arose with the XRISM instrument’s gate valve, which failed to open, thereby affecting observations with the Resolve spectrometer. Here, we update our analysis, reevaluating our diagnostic approach under the assumption that the gate valve remains closed. We find that, even with the reduced instrumental capabilities, it will be possible to pinpoint the ejecta contribution through the study of the line profiles in the XRISM-Resolve spectrum of SN 1987A.
An Independent Discovery of the 1946 Eruption of the Recurrent Nova T Coronae Borealis and an Early Prediction of a Future Outburst
Authors: Shears J. H. 
Published: June 2024

Abstract
One of the earliest independent discoveries of the 1946 eruption of the recurrent nova T CrB was by British amateur variable star observer, N.F.H. Knight, on 1946 February 9 at 05.40 UT. Correspondence between Knight and W.M. Lindley, the Director of the British Astronomical Association Variable Star Section, reveals what might be the first prediction of a future eruption in 2026–27.
Intervenir en institution et œuvrer à l’émergence d’une instance… d’appartenance groupale
Authors: Gaillard Georges 
Published: June 2024

Georges Gaillard , Intervenir en institution et œuvrer à l’émergence d’une instance d’appartenance groupale Nous interrogeons ici l’inflexion contemporaine du « faire groupe » dans les institutions de la mésinscription (et plus largement dans l’hypermodernité). Deux mouvements se combinent en effet désormais qui transforment les liens d’appartenance institutionnels et groupaux : le premier a trait à l’inscription du sujet dans une temporalité qui donne lieu à des dynamiques de désynchronisations qui amplifient les mouvements de fragmentations en cours ; le second, corrélé, relève du refus d’investir le déplaisir, pourtant indispensable au travail de soin et d’accompagnement (etc.), et simultanément au refus de jouer ses appartenances dans les liens d’équipe. Nous soutenons l’hypothèse que cette inscription se joue dorénavant préférentiellement dans le registre du momentané , et que cette « nouvelle » modalité doit être prise en compte dans ses incidences sur la vie des équipes et des institutions, notamment lors des « interventions de régulations » réalisées auprès de ces mêmes institutions. Il s’agit donc de contribuer à ouvrir le chantier qui s’impose désormais à notre attention, celui des « nouvelles » modalités de constitution des groupalités professionnelles.
Modernisation : la cacophonie managériale
Authors: Linhart Danièle 
Published: June 2024

Danièle Linhart , Modernisation : la cacophonie managériale L’individualisation imposée par les directions d’entreprise est censée répondre aux aspirations des salariés. Elle déstabilise pourtant leurs collectifs informels qui jouent un rôle décisif dans la socialisation et la capacité d’action collective. La modernisation managériale impose désormais une mise en concurrence des uns avec les autres et de chacun avec lui-même. Chacun est conduit à négocier tout seul son destin personnel dans l’entreprise et doit trouver à s’épanouir dans une organisation du travail qui reste pourtant inspirée par les principes fondamentaux du taylorisme dans un contexte d’informatisation systématique. Pour réussir, il faut alors apprendre à mobiliser les « bonnes émotions » en « bon subordonné », quitte à se cliver et entrer dans un processus de souffrance lié à de possibles conflits de valeurs.
Viewpoint: use your brain … in management too!
Authors: Jushko Natacha , Rousseau Anne 
Published: June 2024

Cet article se penche sur le pourquoi et le comment de la recherche et de l’enseignement du « management alternatif » au sein des écoles de commerce, à une époque marquée par le prétendu « capitalisme académique » (Ramboarisata et al., 2022). Dans un premier temps, s’appuyant sur la littérature consacrée au management responsable, il expose les principales caractéristiques de cette alternative de gestion qui vise à apporter des réponses durables et équitables aux défis contemporains majeurs en matière de pratiques managériales. La seconde partie interroge les implications concrètes de cette « autre » approche du management, en abordant une pratique managériale spécifique liée à la performance opérationnelle, le Lean management. Enfin, l’article conclut par une discussion sur l’urgence de ces transformations, adoptant une perspective critique et pragmatique, au-delà des déclarations d’intentions.
Marquage de l’intensité émotionnelle en français parlé : quand la syntaxe fait entendre sa voix
Authors: Lacheret-Dujour Anne 
Published: June 2024

Notre étude comportementale porte sur le rôle de la structuration syntaxique du message (ordre des mots et fonction du champ gauche) dans la perception des émotions en français. 80 phrases (40 négatives, 40 positives) ont été présentées à 44 sujets de langue maternelle française pour évaluer leur intensité émotionnelle. Pour chaque valence, la moitié des stimuli correspondait à des phrases syntaxiquement marquées par rapport à la phrase neutre SVO, l’autre moitié à leurs paraphrases non marquées. Les phrases négatives ont été évaluées comme étant plus intenses que celles positives, de même que les phrases marquées ont été jugées plus intenses que les non marquées. Ces résultats montrent que le biais de négativité observé dans le traitement d’images est également en jeu dans la perception de stimuli verbaux. Ils soulignent l’interface entre syntaxe et prosodie émotionnelle dans la parole silencieuse.