bluuebunny/crossref_metadata_2025_split huggingface dataset:
Bioenabled Nanophotonics
Authors: Chen Yeechi , Munechika Keiko , Ginger David S. 
Published: February 2011

AbstractBiological molecules such as oligonucleotides, proteins, or peptides can be used for the synthesis, recognition, and assembly of materials with nanoscale dimensions. Of particular interest are the fields of near-field optics and plasmonics. Many potential optical applications depend on the ability to control the relative positioning of organic dyes, plasmon-resonant metal nanoparticles, and semiconductor quantum dots with nanoscale precision. In this article, we describe some recent achievements in biological assembly and nanophotonics, and discuss potential uses of biological materials for assembling optically functional nanostructures. We emphasize the use of biological materials to build well-defined nanostructures for near-field plasmon-enhanced fluorescence.
In SituX-Ray Tomography Studies of Microstructural Evolution Combined with 3D Modeling
Authors: Buffière J.-Y. , Cloetens P. , Ludwig W. , Maire E. , Salvo L. 
Published: February 2011

AbstractSynchrotron x-ray microtomography is a characterization technique increasingly used to obtain 3D images of the interior of optically opaque materials with a spatial resolution in the micrometer range. As a nondestructive technique, it enables the monitoring of microstructural evolution duringin situexperiments. In this article, examples from three different fields of metals research illustrate the contribution of x-ray tomography data to modeling: deformation of cellular materials, metal solidification, and fatigue crack growth in Al alloys. Conventionally, tomography probes the 3D distribution of the x-ray attenuation coefficient within a sample. However, this technique is also being extended to determine the local crystallographic orientation in the bulk of materials (diffraction contrast tomography), a key issue for the modeling of microstructure in metals.
Materials Challenges and Applications of Solution-Processed Organic Field-Effect Transistors
Authors: Sirringhaus Henning , Ando Masahiko 
Published: February 2011

AbstractOrganic field-effect transistors (FETs) are currently the focus of significant academic research and industrial development interest, as they potentially offer unique advantages over their inorganic counterparts in terms of cost reductions, compatibility with low-temperature and printing-based manufacturing, and potentially even performance. The first generation of products incorporating organic FETs is presently being introduced to the market. This article provides an overview of strategies for achieving high field-effect mobilities in solution-processed organic semiconductor films. We provide an assessment of materials challenges to meet performance and reliability requirements for a range of display and circuit applications and present an overview of state-of-the-art application demonstrations in active-matrix addressing of flexible eletrophoretic, organic light-emitting diode, and liquid-crystal displays, as well as radio-frequency identification tagging. We discuss how the unique functional properties of organic semiconductors, which allow comparatively easy integration of information processing, information storage, light emission, and light detection functions, might enable multifunctional applications that are not easy to create with other material systems.
The Materials Science of Bone: Lessons from Nature for Biomimetic Materials Synthesis
Authors: Oyen Michelle L. 
Published: February 2011

AbstractThere has been considerable recent interest in natural bone as a material, due in part to its interesting combination of mechanical properties: bone is stiff and tough but lightweight. This unusual combination of properties results from a nanocomposite structure of approximately equal volumes of mineral and hydrated organic matter. Much recent effort has been focused on the structure, properties, and performance at different length scales relative to the hierarchical organization of bone. Historically, such bone research has emphasized clinical and medical aspects, including engineering materials for bone augmentation or replacement, bone–biomaterial interactions and interfaces, and more recently, scaffolds for bone tissue engineering. However, within the fast-growing biomimetics field, the bone extracellular matrix is taken as a model for materials development. Efforts have been made both to mimic the bony material itself as well as to mimic the process by which bone forms.
Bioinspired Materials for Self-Cleaning and Self-Healing
Authors: Youngblood Jeffrey P. , Sottos Nancy R. 
Published: February 2011

AbstractBiological systems have the ability to sense, react, regulate, grow, regenerate, and heal. Recent advances in materials chemistry and micro- and nanoscale fabrication techniques have enabled biologically inspired materials systems that mimic many of these remarkable functions. This issue of MRS Bulletin highlights two promising classes of bioinspired materials systems: surfaces that can self-clean and polymers that can self-heal. Self-cleaning surfaces are based on the superhydrophobic effect, which causes water droplets to roll off with ease, carrying away dirt and debris. Design of these surfaces is inspired by the hydrophobic micro- and nanostructures of a lotus leaf. Self-healing materials are motivated by biological systems in which damage triggers a site-specific, autonomic healing response. Self-healing has been achieved using several different approaches for storing and triggering healing functionality in the polymer. In this issue, we examine the most successful strategies for self-cleaning and self-healing materials and discuss future research directions and opportunities for commercial applications.
Biological and Synthetic Self-Cleaning Surfaces
Authors: Genzer Jan , Marmur Abraham 
Published: February 2011

AbstractIn this contribution, we briefly discuss how various physicochemical properties of surfaces affect the wettability and self-cleaning character of both naturally occurring and synthetic surfaces. Using a few selected examples from nature, we discuss the superhydrophobic effect and antifouling character of such surfaces and how these properties are associated with variations in surface chemical composition and topography. We also review a few special case studies aimed at adopting these biomimetic schemes to design and fabricate functional self-cleaning surfaces.
Autonomic Healing of Polymers
Authors: White Scott R. , Caruso Mary M. , Moore Jeffrey S. 
Published: February 2011

AbstractSelf-healing polymers have experienced rapid technological advancement over the past seven years. They have moved from a conceptual demonstration to practical application in this time frame and have grown from a single design to a generic paradigm for modern materials development. Potential applications of self-healing polymers are quite broad, including microelectronic substrates and encapsulants, polymeric paints and coatings, structural composites, and biomedical devices. In this article, we focus on polymeric systems that heal in an autonomic fashion, that is, automatically and without human intervention. The types of systems under development and the future of this paradigm in advanced materials are discussed.
In Situ Heating Transmission Electron Microscopy
Authors: Saka Hiroyasu , Kamino Takeo , Ara Shigeo , Sasaki Katsuhiro 
Published: February 2011

AbstractTemperature is one of the most important factors affecting the state and behavior of materials. In situ heating transmission electron microscopy (TEM) is a powerful tool for understanding such temperature effects, and recently in situ heating TEM has made significant progress in terms of temperature available and resolution attained. This article briefly describes newly developed specimen-heating holders, which are useful in carrying out in situ heating TEM experiments. It then focuses on three main applications of these specimen holders: solid–solid reactions, solid–liquid reactions (including highresolution observation of a solid–liquid interface, size dependence of the melting temperatures of one-, two- and three-dimensionally reduced systems, size dependence of the contact angle of fine metal liquid, and wetting of Si with liquid Au or Al) and solid–gas reactions. These results illustrate the benefit of in situ heating TEM for providing fundamental information on temperature effects on materials.
Electric and Magnetic Phenomena Studied byIn SituTransmission Electron Microscopy
Authors: Cumings John , Olsson Eva , Petford-Long Amanda K. , Zhu Yimei 
Published: February 2011

AbstractThere is a wide array of technologically significant materials whose response to electric and magnetic fields can make or break their utility for specific applications. Often, these electrical and magnetic properties are determined by nanoscale features that can be most effectively understood through electron microscopy studies. Here, we present an overview of the capabilities for transmission electron microscopy for uncovering information about electric and magnetic properties of materials in the context of operational devices. When devices are operated during microscope observations, a wealth of information is available about dynamics, including metastable and transitional states. Additionally, because the imaging beam is electrically charged, it can directly capture information about the electric and magnetic fields in and around devices of interest. This is perhaps most relevant to the growing areas of nanomaterials and nanodevice research. Several specific examples are presented of materials systems that have been explored with these techniques. We also provide a view of the future directions for research.
Whither Oxide Electronics?
Authors: Ramesh Ramamoorthy , Schlom Darrell G. 
Published: February 2011

AbstractIn this issue we have endeavored to answer the question, “Whither oxide electronics?” This issue provides a framework and perspective on the progress in the field of oxide electronics over the past several decades, as well as the challenges and opportunities in the years to come. Building on the foundations laid by the pioneers in the materials community and spurred by the discovery of high-temperature superconductivity, there has been both tremendous progress in understanding the complex science of oxide electronic materials and the discovery of other fascinating new phenomena, including colossal magnetoresistance, multiferrocity, and two-dimensional electron gases in correlated oxide systems. Thin-film heterostructures provide a pathway to create novel devices and combinations of physical phenomena. Indeed, the ability to synthesize and control oxide heterostructures using sophisticated deposition techniques has become a key enabler of the recent advances in this field. These oxides are beginning to enter mainstream products because of their higher performance, for example, ferroelectric memories and oxides with high dielectric constant for computers that run at higher speed and use less power.
Gate Oxides Beyond SiO2
Authors: Schlom Darrell G. , Guha Supratik , Datta Suman 
Published: February 2011

AbstractThis year marks a major materials milestone in the makeup of silicon-based field-effect transistors: in the microprocessors produced by leading manufacturers, the SiO2gate dielectric is being replaced by a hafnium-based dielectric. The incredible electronic properties of the SiO2/silicon interface are the reason that silicon has dominated the semiconductor industry and helped it grow to over $250 billion in annual sales, as reported by the Semiconductor Industry Association (SIA), San Jose, CA. The shrinkage of transistor dimensions (Moore's law) has led to tremendous improvements in circuit speed and computer performance. At the same time, however, it has also led to exponential growth in the static power consumption of transistors due to quantum mechanical tunneling through an ever-thinner SiO2gate dielectric. This has spurred an intensive effort to find an alternative to SiO2with a higher dielectric constant (K) to temper this exploding power consumption. This article reviews the high-Kmaterials revolution that is enabling Moore's law to continue beyond SiO2.
Electric-Field Control of Magnetism in Complex Oxide Thin Films
Authors: Spaldin Nicola A. , Ramesh R. 
Published: February 2011

AbstractIn this article, we review current research efforts to control the magnetic behavior of complex oxide thin films using electric fields. After providing fundamental definitions of magnetoelectric response, we survey materials, architectures, and mechanisms that exhibit promise for such electric-field control of magnetism. Finally, we mention ideas for future research and discuss prospects for the field.
ZnO-Based Semiconductors as Building Blocks for Active Devices
Authors: Kamiya Toshio , Kawasaki Masashi 
Published: February 2011

AbstractThis article provides a review of materials and devices of wide-bandgap oxide semiconductors based on ZnO, highlighting the nature of the chemical bond. The electronic structures of these materials are very different from those of conventional covalently bonded semiconductors, owing to the ionic nature of the chemical bonds. Therefore, one needs to design and optimize fabrication processes and structures of active devices containing such materials, taking into account the peculiar defect formation mechanisms. A variety of active devices that have clear advantages over the conventional ones have been demonstrated, for example, ultraviolet light-emitting diodes, quantum Hall devices, and transparent and flexible thin-film transistors with high electron mobility, paving the way for future applications. The reasons behind the successes identify future challenges in research on oxide semiconductors.
In-Contact Molecular Spectroscopy of Liquid Lubricant Films
Authors: Cann P.M. 
Published: February 2011

AbstractThe primary role of a lubricant is to control the friction and wear of rubbing surfaces to optimize the operation of a component by forming an interfacial film separating the surfaces. Lubrication research seeks to develop new lubricant formulations and to optimize component life and performance. To do this, we must understand the mechanisms of film formation and film properties and the way these relate to operating conditions. In many engineering components, the lubricant film is subjected to severe mechanical and thermal stresses as it passes through the loaded zone. These severe conditions can result in molecular alignment or conformational change and the formation of new chemical species, which will impact the lubrication performance of the fluid. The lubricant response within the contact is often transient and thus has proved difficult to study by conventional surface analytical methods. One alternative is to replace one of the surfaces by a transparent window and use molecular microspectroscopy (infrared or Raman) to analyze the film within the contact zone formed during rubbing. This article reviews the development and application of in-contact molecular spectroscopy for the study of lubricant properties within the rubbing interface for both conventional and biolubrication systems. This technique has been used to study molecular conformation, chemical composition, and pressure distribution in the high-pressure region of the contact zone. However, challenges remain, including detecting very thin films, obtaining depth profile information, and applying these methods more generally to biotribology.
Cracklike Processes within Frictional Motion: Is Slow Frictional Sliding Really a Slow Process?
Authors: Rubinstein Shmuel M. , Cohen Gil , Fineberg Jay 
Published: February 2011

AbstractThe dynamics of frictional motion have been studied for hundreds of years, yet many aspects of these important processes are not understood. First described by Coulomb and Amontons as the transition from static to dynamic friction, the onset of frictional motion is central to fields as diverse as physics, tribology, mechanics of earthquakes, and fracture. We review recent studies in which fast (real-time) visualization of the true contact area along a rough spatially extended interface separating two blocks of like material has revealed the detailed dynamics of how this transition takes place. The onset of motion is preceded by a discrete sequence of rapid cracklike precursors, which are initiated at shear levels that are well below the threshold for static friction. These precursors systematically increase in spatial extent with the applied shear force and leave in their wake a significant redistribution of the true contact area. Their cumulative effect is such that, just prior to overall sliding of the blocks, a highly inhomogeneous contact profile is established along the interface. At the transition to overall motion, these precursor cracks trigger both slow propagation modes and modes that travel faster than the shear wave speed. Overall frictional motion takes place only when either the slow propagation modes or additional shear cracks excited by these slow modes traverse the entire interface. Surprisingly, in the resulting stick–slip motion, the surface contact profile retains the profile built up prior to the first slipping event. These results suggest a fracture-based mechanism for stick–slip motion that is qualitatively different from other descriptions.
Conjugated Polymer Actuators
Authors: Smela Elisabeth 
Published: February 2011

AbstractConjugated polymer artificial muscles fill a unique niche in the electroactive polymer portfolio. They combine high strength, low voltage, and reasonable speed with versatile fabrication and design. This article reviews the actuation mechanism in these materials and presents some of the designs that have been developed for applications such as Braille displays, catheters, and bioMEMS devices.
Recent Developments in Artificial Molecular-Machine–Based Active Nanomaterials and Nanosystems
Authors: Huang Tony Jun 
Published: February 2011

AbstractArtificial molecular machines capable of converting chemical, electrochemical, and photochemical energy into mechanical motion represent a high-impact, fast-growing field of interdisciplinary research. These molecular-scale systems utilize a “bottom-up” technology centered upon the design and manipulation of molecular assemblies and are potentially capable of delivering efficient actuation at length scales dramatically smaller than traditional microscale actuators. As actuation materials, molecular machines have many advantages, such as high strain (40%–60%), high force and energy densities, and the capability to maintain their actuation properties from the level of a single molecule to the macroscale. These advantages have inspired researchers to develop molecular-machine–based active nanomaterials and nanosystems, including electroactive and photoactive polymers. This article will discuss the structures and properties of artificial molecular machines, as well as review recent progress on efforts to move molecular machines from solution to surfaces to devices.
A Super-Green Factory: The Sharp Kameyama Plant
Authors: Kusakabe Tetsuo 
Published: February 2011

Sharp Corporation is making a concerted effort to reduce environmental impacts to the greatest extent possible at its production facilities around the world, and it is applying its own original evaluation criteria to recognize those plants having an extremely high level of environmental performance as “SuperGreen Factories.”Our Kameyama plant, the frst such factory to be so recognized, is an integrated, start-to-fnish production facility for liquid-crystal display (LCD) televisions (TVs), from fabricating the LCD panel to assembling the fnished TV set (see Table I). Given that large amounts of energy are consumed to operate production equipment and to power air conditioning, we focused particular attention on environmental measures intended to reduce global warming and introduced an energy supply system that combines environmental friendliness and operational stability. As shown in Figure 1, this system is based on integrating different types of large-scale distributed power sources and consists of a gas-fred cogeneration system, a fuel cell system, and a photovoltaic power generating system. The power output of this system covers about one-third of the total electrical needs of the plant.
Nanoparticle Delivery: Targeting and Nonspecific Binding
Authors: Liu Rihe , Kay Brian K. , Jiang Shaoyi , Chen Shengfu 
Published: February 2011

AbstractTargeted cancer therapies focus on molecular and cellular changes that are specific to cancer and hold the promise of harming fewer normal cells, reducing side effects, and improving the quality of life. One major challenge in cancer nanotechnology is how to selectively deliver nanoparticles to diseased tissues while simultaneously minimizing the accumulation onto the nanoparticle of unwanted materials (e.g., proteins in the blood) during the delivery process. Once therapeutic nanoparticles have been created, very often they are linked or coated to other molecules that assist in targeting the delivery of nanoparticles to different cell types of the body. These linkers or coatings have been termed targeting ligands or “smart molecules” because of their inherent ability to direct selective binding to cell types or states and, therefore, confer “smartness” to nanoparticles. Likewise, “smartness” can be imparted to the nanoparticles to selectively repel unwanted entities in the body. To date, such smart molecules can consist of peptides, antibodies, engineered proteins, nucleic acid aptamers, or small organic molecules. This review describes how such smart molecules are discovered, enhanced, and anchored to nanoparticles, with an emphasis on how to minimize nonspecific interactions of nanoparticles to unintended targets.
Atomic Layer Deposition of Dielectrics on Ge and III–V Materials for Ultrahigh Performance Transistors
Authors: Wallace Robert M. , McIntyre Paul C. , Kim Jiyoung , Nishi Yoshio 
Published: February 2011

AbstractThe prospect of utilizing alternative transistor channel materials for ultrahigh performance transistors will require suitable gate dielectrics for surface-channel field-effect devices. With the utilization of deposited gate dielectrics in large-scale production for Si-based integrated circuits by atomic layer deposition, extending this technology to channel materials that exhibit high bulk mobility behavior is of interest. A review of the current status for atomic layer deposited high-κ dielectrics on Ge and III–V channel materials is presented.
Nanoporous Metals by Alloy Corrosion: Formation and Mechanical Properties
Authors: Weissmüller Jörg , Newman Roger C. , Jin Hai-Jun , Hodge Andrea M. , Kysar Jeffrey W. 
Published: February 2011

AbstractNanoporous metals prepared by the corrosion of an alloy can take the form of monolithic, millimeter-sized bodies containing approximately 1015nanoscale ligaments per cubic millimeter. The ligament size can reach down to the very limits of stability of nanoscale objects. The processes by which nanoporous metals are formed have continued to be fascinating, even though their study in relation to surface treatment, metal refinement, and failure mechanisms can be traced back to ancient times. In fact, the prospect of using alloy corrosion as a means of making nanomaterials for fundamental studies and functional applications has led to a revived interest in the process. The quite distinct mechanical properties of nanoporous metals are one of the focus points of this interest, as relevant studies probe the deformation behavior of crystals at the lower end of the size scale. Furthermore, the coupling of bulk stress and strain to the forces acting along the surface of nanoporous metals provide unique opportunities for controlling the mechanical behavior through external variables such as the electrical or chemical potentials.