The Phase Behaviour of Acid Disposal Gases and the Potential Adverse Impact on Injection or Disposal Operations
Authors: Bennion D.B. , Thomas F.B. , Schulmeister B.E. , Imer D. , Shtepani E. , Becker L. 
Published: March 2010

Abstract
As increased volumes of acid gases (containing carbon dioxide and hydrogen sulphide) are processed, the technique of downhole re-injection of the concentrated acid gas for disposal of these unwanted fluids continues to become more popular. In many cases, bottomhole injection temperature and pressure conditions are such that the injected acid gas phase is a supercritical fluid that is miscible with the existing reservoir fluids and, thus, the potential for adverse relative permeability effects (due to thecreation of in situ immiscible liquid and vapour phases) is avoided. In other cases, however, combinations of lower reservoir temperatures and/or initially depleted disposal zone pressures, or blending of the acid gas with the in situ lean gas, can result in the formation of both liquid and vapour acid gas phases in the formation in the near-wellbore region. This can often cause very significant relative permeability effects, which may result in large reductions in injectivity of the acid gas on either a permanent or transient basis. This paper provides actual examples of such systems, as well as reviewing the design protocol that must be used to evaluate if potential phase behaviour problems can occur downhole during an acid gas disposal operation. This hasproven to be a key parameter in the successful evaluation of anacid gas disposal operation.

Introduction
In many acid gas injection operations, the bottomhole pressure condition is high enough that, over the entire life of the injection operation and at all possible blended compositions between the acid injection gas and the reservoir fluids, a monophasic condition is present. In some cases, when the initial reservoir pressure is low, initial injection commences in the "gas" phase region, and as pressure gradually increases, the phase condition of the fluids around the injection wells enters the two-phase region where a "liquid" acid gas phase is in thermodynamic equilibrium with an acid gas "vapour" phase. This may also occur when the acid gas blends with reservoir gas which may elevate the dew point pressure line upwards above the current injection pressure level, once again resulting in a condition of two-phase flow. The creation of these two immiscible phases (which have an interface and measurable interfacial tension between them) can, particularly in lower permeability formations, create significant adverse relative permeability effects which may result in large transient or permanent reductions in injectivity, possibly compromising the economics of the acid gas injection operation. Understanding the phase behaviour in such situations and how it interacts with the capillary pressure and relative permeability phenomena present within the matrix of the proposed injection zone is essential. Limited data is available in the literature on the properties of high temperature and pressure acid gas mixtures and their specific phase behaviour(1–8). This is also the case with data regarding the specific interaction of single and multiphase acid gas interactions with reservoir rock(9–11) and the effects of multiphase acid gas induced relative permeability effects(12). The motivation of this work was to obtain a dataset to expand the knowledge base in this area.