bluuebunny/crossref_metadata_2025_split huggingface dataset:
A practical synthesis of novel hydroxyl‐substituted macrocyclic tri‐, tetra‐ and hexa‐mines
Authors: Guo‐Ping Xue , Yong Liu , Cheng‐Tai Wu 
Published: September 2010

AbstractMacrocyclic tri‐ and tetra‐amines containing a hydroxyl group in the ring have been preparad in moderate yields by a 1:l cyclocondensation of 1,3‐dichloro‐2‐propanol with the disodium salt of N‐tosylated diethylenetriamine and triethylenetetraamine. In the case of condensation of 1,3‐dichloro‐2‐propanol with the disodium salt of N‐tosylated diethylenetriamine, the 2:2 cyclocondensation product, dihydroxyl macrocyclic hexaamine, was also isolated.
Reactions of enamines with fluorinated acyl chlorides — Synthesis of fluorinated 1,3‐diketones and 1,3‐keto‐aldehydes
Authors: Hai‐Ying He , Yan‐Ling Qu , Cheng‐Xue Zhao 
Published: September 2010

AbstractThe reactions of enamines (1a–b, 4, 6) with fluorinated acyl chlorides (2a–d ) produced fluorinated 1,3‐diketones (3a–f) and 1,3‐keto‐aldehydes (7a–c) in good yields as well as byproducts fluorinated acylamides (5a–c). It is proposed that the reactions involve nucleophilic attack by the C‐atom and/or N‐atom of the enamines on acyl carbon of the fluorinated acyl chlorides.
Cu(OTf)2‐catalyzed ring‐opening of epoxides with anilines: A convenient synthesis of β‐amino alcohols
Authors: Xue‐Long Hou , Jie Wu , Li‐Xin Dai 
Published: September 2010

AbstractThe regioselective ring‐opening of epoxides with aniline and p‐chloroaniline catalyzed by copper(II) triflate provides the corresponding β‐amino alcohols in excellent yields.
Direct chiral high performance liquid chromatography separation of O‐ethyl O‐phenyl N‐isopropylphosphoroamidothioates
Authors: Gao Ru‐Yu , Huang Jun‐Min , Yang Guo‐Sheng , Yang Hua‐Zheng , Wang Qin‐Sun 
Published: September 2010

AbstractThe enantiomers of thirty‐nine O‐ethyl O‐phenyl N‐isopropyl phosphoroamidothioates have been separated by high performance liquid chromatography on a Pirkle model chiral stationary phase using ten mobile phase. Chromatographic data are presented for the separation of these organic phosphorus enantiomers on the chiral phase. The influences of molecular structures and compositions of mobile phases have been described.
Study on the chemisorption kinetics of Methylene Blue using SERS technique
Authors: Chen Wan‐Xi , Jiang Hua , Xu Zhu‐De , Lu Yun 
Published: September 2010

AbstractSERS technique wae used to study the chemiesorption kinetics of Methylene Blue (MB) on the HNO3‐etched silver surface. The adsorption kinetic parameters were deduced from different vibrational modes at a low concentration of 3.5 × 10−6 mol/L, and it showed that MB adsorbed uniformly (monolayerly) on silver surface. However, the adsorptive behavior turned anomalous at relatively higher concentrations and a possible explanation was suggested. In addition, the influence of Cl− ions on the adsorption states of MB was investigated, and it was shown that MB molecules, adsorbed on the silver surface, tended to transform the “lying‐down” state to the “end ‐ on” 4 state after CI− ions were added.
Chemometrics to chemical modeling: Novel molecular distance‐edge vector (λ) in alkanes and retention index of gas chromatography
Authors: Yin Chun‐Sheng , Pan Zhong‐Xiao , Yi Zhong‐Sfaeng , Li Zhi‐Iiang , Zhang Mao‐Sen 
Published: September 2010

AbstractSystematic studies are made on application of chemometrics to chemical modeling and/or molecular modeling as well as the regularity of retention index for gas chromatography (GC). A set of novel molecular graph theoretical parameters, called the molecular distance‐edge (MDE) vector (λ), is proposed ad found to be excellently correlated to retention index of GC for alkanes. The MDE parameters were tested by the multiple linear regression (MLR) estimation and production of the retention index of GC, and the results obtained are satisfactory.
Preparation of twelve 1‐methyl‐2‐formyl‐5‐substituted pyrroles and their hydrazones
Authors: He Hai‐Ying , Jiang Xi‐Kui 
Published: September 2010

AbstractPreparation of twelve 1‐methyl‐2‐formyl‐5‐substituted pyrroles (2a–1), with five of them as new compounds, is described. Their derivatives, i.e., 1‐methyl‐2‐formyl‐5‐substituted pyrrole phenyl hydrazones (3a–1) and 1‐methyl‐2‐formyl‐5‐substituted pyrrole (4‐nitrophenyl) hydrazones (4a–1) are all new compounds. They have also been prepared and further identified.
Supercritical fluids: Clean solvents for green chemistry
Authors: F'Oliakoff Martyn , George Michael W. , Howdle Steven M. , Bagratashvili Viktor N. , Han Bu‐Xing , Yan Hai‐Ke 
Published: September 2010

AbstractSupercritical fluids are becoming increasingly attractive as environmentally acceptable replacement for organic solvents in chemical reactions and material processing. This paper highlights some of the properties of supercritical fluids, especially supercritical CO2, which offer particular advantages for the handling of polymers, metal complexes and the environmentally more friendly synthesis and manufacture of chemicals. The paper includes same of the researches in University of Nottingham and a number of recent reviews which together provide a comprehensive introduction.
FTIR study of hydrogen bonding of stearic acid with ethanol, dimethyl sulfoxide, and acetonitrile in supercritical CO2
Authors: Mao Can , Lu Jie , Xu Qun , Chen Shi‐Juan , Ke Jie , Han Flu‐Xing , Yan Hai‐Ke 
Published: September 2010

AbstractFTIR spectroscopy was used to study the hydrogen bonding of stearic acid with ethanol, dimethyl sulfoxide (DMSO), and acetonitrile in supercritical CO2 at 318. 15 K, and 12.5 and 16.5 MPa. The concentration of the cosolvents range from 0–0.6 mol·L−1. The area percentage of absorption bands for hydrogen‐bonded and nonhydrogen‐bonded species was Obtained from the IR spectra. The acid and the cosolvents can form hydrogen bond even when their concentrations a very low. At fixed solute concentration, the extent of hydrogen bonding increases with cosolvent concentration. At higher ethanol concentrations, it seems that one stearic acid molecule can hydrogen bond with more than one ethanol molecules simultaneously. It is seen that the strength of the hydrogen bond formed by the acid and the cosolvents is in the order: DMSO ethanol acetonitrile.
Fluorocarbon‐ containing hydrophobically modified poly( N‐isopropylacrylamide)
Authors: Zhang Yun‐Xiang , Fang Qin , Fu Yu‐Qing , Da Ai‐Hua 
Published: September 2010

AbstractA fluorocarbon‐modified ply( N‐isopropylacrylamide) has been synthesized by copolymerization of N‐isopropyl acrylamide with a small amount of acrylate or methacrylate containing a perfluoroalkyl group. It was found that the hydrophilicity of macromolecular backbone is an important factor to the solution properties of the copolymers and that hydrophobic association between fluorocarbon group is stronger than that between the corresponding hydrocarbon analogies. The viscosity of some of the copolymer solutions was very sensitive to temperature. It was dilatant at higher fluorocarbon comonomer content ( 0. 20–1.0 mol%) and was Newtonian at very low fluorocarbon comonomer content (0.03–0.2 mol%). Evidence for hydrophobic association of the fluorocarbon groups was obtained from the effects of adding NaCl and surfactants on the solution viscosity. The LC‐ST properties of these copolymers were studied by DSC method and this was also found to be consistent with hydrophobic association between the fluorocarbons.
Green chemistry of chromate cleaner production
Authors: Zhang Yi , Li Zuo‐Hu , Qi Tao , Wang Zhi‐Kuan , Zheng Shi‐Li 
Published: September 2010

AbstractResearch topics and methods of green chemistry in chromate production are introduced in this paper. New original green chemical process of the heterogeneous reaction and separation system of liquid phase oxidation of chromite in molten salt of sodium hydroxide—one way separation in high concentration medium—metastable phase separation—carbonate recycle conversion has been developed. The green commercial process for comprehensive utilization of mineral resources—reactant recycle inside the process—zero emission was established.
Differential diffusion quantum Monte Carlo method: Determination of potential energy surfaces of molecules
Authors: Huang Hong‐Xin , Cao Ze‐Xing , Zeng Xian‐Biao , Li Ze‐Lin , Zeng Yue , Yang Zhi‐Jian 
Published: September 2010

AbstractA differential approach for self‐optimizing diffusion Monte Carlo calculation was proposed in this paper, which is a new algorithm combining three techniques such as optimizing, diffusion and correlation sampling. This method can be used to directly compute the energy differential between two system in the diffusion process, making the statistical error of calculation be reduced to Order of 10−‐5 hartree, and recover about more than 80% of the correlation. We employed this approach to set up a potential energy surface of a molecule, used a “rigid move” model, and utilized Jacobi transformation to make energy calculation for two configurations of a molecule having good positive correlation. So, an accurate energy differential could be obtained, and the potential energy surface with good quality can be depicted. In calculation, a technique called “post‐equilibrium remaining sample” was set up firstly, which can save about 50% of computation expense. This novel algorithm was used to study the potential as molecular spectroscopy and the energy variation in chemical reactions.
Asymmetric 1,3‐dipolar cycloaddition of nitrile oxides with optically active vinylboronic ester
Authors: Jiang Biao , Zhang Ao , Kan Ying 
Published: September 2010

AbstractPinanyldioxy styrylboronic ester (1) was employed for asymmetric 1,3‐dipolar cycloaddition with nitrile oxides, optically active Δ2‐isoxazolines (3) or 4‐hydroxy‐ Δ2‐isoxazolines (4) were obtained. The effect of different bases on the selectivity of the cycloaddition reaction was studied.
A straight synthesis of 2–(α‐substituted N‐tosylaminomethyl)‐2,5‐dihydrofurans by the reaction of N‐sulfonylimines with arsonium 4‐hydroxyl‐ cis ‐2‐butenylides
Authors: Li An‐Hu , Deng Wei‐Ping , Dai Li‐Xin , Hou Xue‐Long 
Published: September 2010

AbstractOn treatment of N‐tosylimines (1) and 4‐hydeoxyl‐ cis‐butenyl arsonium salt (5) with KOH in acetonitrile at room temperature, 2–(α‐substituted N‐tosylaminomethyl)‐2, 5‐dihydrofurans (4) were obtained in moderate yields. The arsonium salt (5) acts formally as an equivalent of 2,5‐dihydrofuran synon. A plausible mechanism was proposed for this new 5‐membered cyclization reaction.
Synthesis, characterization and crystal structures of manganese (II) complexes containing nitronyl nitroxide and its reduced derivative
Authors: Zhang Lei , Li Su‐Qi , Liao Dai‐Zheng , Jlang Zong‐Hui , Yan Shi‐Ping , Wang Geng‐Lin , Wang Zhi , Shen Pan‐Wen , Yao Xin‐Kan , Wang Hong‐Gen 
Published: September 2010

AbstractTwo novel adducts of formula Mn(hfaC)2(NITPhCLI)2 (1) and Mn(hfac)2(IMHPhCl)I2(NIT‐PhCl) 0.5H2O (2), where hfac = hexafluoroacetylacetonate, NITPhCI = 2–(3‐chlorophenyl)‐4,4,5,5‐tetramethylimidazolyl‐1‐oxyl‐3‐oxide, IMHPhCl = 2‐(3‐chlorophenyl)‐4, 4, 5, 5‐tetramethylimidazolyl‐3‐oxide, have been prepared by the reaction of Mn(hfac)2 2H2O with NITPhCI. Compound 1 is triclinic, space pup P‐1 with a = 1. 3003(3)nm, b= 1.3138(3)nm, c = 1.4931 (3)nm, α = 83.74(3),β= 77.77(3)., σ = 60.59(3)., V = 2.171(1)nm3, Z=2. Compound 2 is triclinic, Space group P‐1 with a = 1.2994(3) nm, b=1.4841(3) nm, c = 2.1031(4) nm, a = 92.30(3),β= 98.68(3), σ = 97.89(3), V = 3.964(2) nm3, Z=2. Each manganese atom is hexacoordinated in both compounds and compound 2 is organized‐ in chains by hydrogen bonds between neighboring pairs of NITPhCI and NITPhCI.
Cycloaddition of benzoheteroazepine III Reaction of 2,3‐dihydro‐1H‐15benzodiazepines with dichlorocarbene and stereo‐structures of products
Authors: Zhang Xin‐Yu , Xu Jia‐Xi , Jem Sheng 
Published: September 2010

AbstractReaction of 2, 3‐dihydro‐1H‐1. 5‐benzodiazepines with dichlorocarbene generated in situ using benzyltriethylammonium chloride (TEBA) as a phase transfer catalyst in chloroform‐aqueous sodium hydroxide mixture gave mainly 1,2‐cycloadducts, cis and trans‐1a, 3‐disubstituted‐1, 1‐dichloro‐1a, 2,3,4‐tetrahydro‐1H‐azirino[1,2‐a][1,5]benzodiazepines (2.3), and formylated 1,2‐cycloadducts, trans‐1a,3‐disubstituted‐1, 1‐dichloro‐4‐formyl‐1a, 2, 3, 4–1 H‐azirino[1, 2‐a][1, 5]benzodiacepines (4). The stereo‐structures of cycloadducts and the mechanism are also discussed.
Thermodynamic study of axial coordination reaction of zinc porphyrin with metal Schiff base and imidazole complex
Authors: Ruan Wen‐Juan , Zhu Zhi‐Ang , Bu Xian‐He , Zhang Zhi‐Hui , Chen Yun‐Ti 
Published: September 2010

AbstractA thermodynamic study is reported for the coordination reaction of ZnT ( m‐X)PP derivatives (X = NO2, Cl, OCH3, H or CH3) with various ligands L (L= imidazole (Im), 2‐methylimidazole (Melm), clotrimidazole (CIM), imidazol‐4‐carboxaldehyde (4‐CHOIm), unsymmetrical tetradentate copper Schiff base, Culm(p‐C1), Ch(p‐Br), and nickel Schiff base, Nilm(p‐CI)), in dichloromethane solvent. Conversion of the four‐coordinated ZnT( m‐X)PP to the five‐coordinated species is followed and isosbestic behavior is exhibited in the region among 450 and 700 nm. The reaction of a copper(II) or nickel(II) imidazolate Schiff base with ZnT( m‐X)PP results in the formation of an imidazolate bridged heterobinuclear complex. The stochiometric number is unity for all axial ligands. The equilibrium constants were determined using the β band of ZnT( m‐X)‐PP in the 293–308 K range by the method of Rose and Drago. It increases with decrease in temperature, and ΔH0 0, Δ09 0. The stronger the nucleophilic ability of the axial ligand is, the larger the stability of the axial coordination product is. Hammet linear relationships and isoequilibrium relationships exist in the system studied.
Synthesis and electroluminescent properties of naphthalimide derivatives
Authors: Yin Shou‐Cen , Xu Zheng , Huang Wen‐Qiang , Zhang Fu‐Qiang , Hou Yan‐Bing , Wang Yong‐Sheng , Xu Xu‐Rong 
Published: September 2010

AbstractNaphthalimide derivatives, N‐ethyl‐4‐acetylamino‐l,8‐naphthalimide (EAAN) and polymer with N‐propyl‐4‐acetylamino‐1,8‐naphthalimide (PAAN) side‐chain (P‐PAAN) were successfully synthesized. Electroluminescent devices of ITO/PVK(120nm)/EAAN(50nm)/Al(150nm) (I) and ITO/PVK+ P‐PhAN(10:1) (50nm)/Al( 150nm) (II) constructed with EAAN and P‐PAAN as the emitting layer were investigated, whereas the single‐layer devices of ITO/EAAN or P‐PAAN(50nm)/Al(150nm) (III) were not observed to have any e‐mission light. The emission results revealed that the exaction recombination formed by positive and negative charge carriers injected from electrodes of devices I and II was much more balanced than that of devices III, which implied that naphthalimide derivatives are a new type of electron‐transporting materials with high performance. The electron‐transporting properties of naphthalimide derivatives were also elucidated by investigation of the electroluminescent behaviors from both devices of ITO/PPV (80nm)/Al and ITO/PPV (80nm)/EAAN (20)nm)/Al hch fabricated with EAAN as the electron‐transporting layer.
Synthesis and magnetic interaction of μ‐2‐chloroterephthalato binuclear iron (II) complexes
Authors: Li Yan‐Tuan , Yan Cui‐Wei , Liao Dai‐Zheng 
Published: September 2010

AbstractFour μ‐2‐chloroterephthalato binuclear iron (II) complexes, namely [Fe2 (CTPHA) L4] (ClO4)2 where L stands for 4,4′‐dimethyl‐2,2′‐bipyridine (Me2‐bpy); 2,9‐dimethyl‐l, 10‐phenanthroline (Me2‐phen); 5‐chloro‐1, 10‐phenanthroline (Cl‐phen); 4, 7‐diphenyl‐1, 10‐phenanthroline (Ph2‐phen), respectively, and CTPHA represents 2‐chloroterephthalate dianion, have been synthesized and characterized. Based on the elemental analyses, molar conductance measurements and spectroscopic studies, extended CTPHA‐bridged structures consisting of two iron(II) ions, each in a distorted octahedral environment, are proposed for these complexes. [Fe2(CTPHA)‐(Me2,‐bpy)4] (CIO4)2 (1) and [Fe2(CT‐PHA). (Me2‐phen)4 ](CIO4)2 (2) complexes were characterized by variable temperature magnetic susceptibility (4–300 K) measurements and the observed data were successfully simulated by the equation based on the spin Hamiltonian operator, Ĥ = ‐ 2JŜ1, * Ŝ2, giving the exchange integrals J = ‐ 1.28 cm−1 for 1 and J = ‐ 1.85 cm‐1 for 2. These results indicate the presence of a weak antiferromagnetic spin‐exchange interaction between the metal ions within each molecule.
Studies on synthesis and magnetic resonance of lanthanide complexes with novel Schiff base derived from noncyclic polyether and β‐diketone
Authors: Wu Jing , Yao Ke‐Min , Hu Xiao‐Li , Shen Lian‐Fang , Yuan Han‐Zhen 
Published: September 2010

AbstractNine h( III) complexes with a novel Schiff base derived from diglycolamine and benzoylacetone (BZDA) have been synthesized and characterized. They can be formulated as [Ln2(BZDA)3(NO3)3](NO3)3‐nH2O (LnLa, Pr, Nd, Sm, n = 4; Ln = Gd, Tb, Er, Yb, Y, n = 7). Enamic form mechanism in this β‐diketone Schiff base and its Complexes were suggested and proved by IR, UV and NMR methods. The 13C spin‐lattice relaxation time T1 and the ratios of r(Ci‐In)/ r (cj‐in) were measured by a 500 MHz NMR instrument for elucidating the formation of the stable six‐membered chelate ring structure in these complexes. The EPR spectrum of the Gd( III) complex exhibits the “U” spectral feature and “zero field effect”. On the basis of them, the crystal field strength and the local symmetry around Gd 3+ in the complex have been discussed.
Synthesis of a pair of novel receptors and their properties of enantioselective recognition for amino acid zwitterions
Authors: Lu Guo‐Yuan , Liu Fang , He Wei‐Jiang , Wang Zhi‐Lin , Hu Hong‐Wen , Prados Pliar , Mendoza Javier De 
Published: September 2010

AbstractA pair of artificial enantiotopic receptors la and lb composed of (S,S) or (R,R) chiral bicyclic guanidinium, azacrown ether and (t‐butyldiphenylsilyloxy) methyl group for amino acid zwitterions have been synthesized. The liquid‐liquid competition experiments and 1 H NMR studies indicate that the receptor 1a with (S, S) configuration and 1b with (R,R) configuration selectively recognize L‐ and D‐aromatic amino acids & respectively.
HgCl2‐Catalyzed monobenzylation and monoallylation reactions of 1‐phenyl‐l‐alkynes
Authors: Ma Sheng‐Ming , Wang Ii‐Sha 
Published: September 2010

AbstractA general procedure for the HgCl2‐mediated monolithiation reaction of 1‐phenyl‐l‐alkynes was developed.
Ab initio study of sphere‐like mesogen properties
Authors: Fu‐Jiang Ding, , Liang‐Fu Zhang, , Tian‐Zhi Wu, , Li‐Kui Jiang, 
Published: September 2010

AbstractSphere‐like compound C8H17Si(OPhC12H25)3N (1) forms mesophases. In order to investigate the relationship between molecular structure and liquid crystal properties, structural studies are carried out on the model molecules of compound 1 and its substituted derivatives using ab initio calculations. The results show that the cyano or chloro substituted tribenzosilatrane compounds R Si(OPhR2)3N (R1,R2 = CN or Cl) have much bigger dipole moments or anisotropy of polarizability and more like sphere than the corresponding alkyl substituted compounds. Cyano or chloro substituted tribenzosilatranes would be better candidates for sphere‐like mesogens.
Studies of copper (II) complexes as catalysts for the hydrolysis of DNA
Authors: Rui Ren, , Pin Yang, 
Published: September 2010

AbstractHydrolysis of DNA is an important enzymatic reaction, but it is exceedingly difficult to mimic in the laboratory because of the stability of hydrolysis of DNA. In this paper, the cleavage activity of complexes formed between Cu(II) and four different amino acid or amino acid methyl ester on DNA is studied by gel electrophoresis. It is found that DNA could be cleaved by Cu(II)‐L‐His and Cu(II)‐L‐His methyl ester complexes and the efficiency of cleavage is largely dependent on the metal ion‐to‐ligand ratio. Further experiments show that the cleavage of DNA mediated by Cu(II)‐L‐His complexes occursvia a hydrolytic mechanism and the active chemical species that affects DNA cleavage is proposed to be MI2H+ and MI2H22+.
Crystal structure and fluorescence spectrum of the complex [Eu(III)(TTA)3(phen)]
Authors: Mao‐Lin Hu, , Zhen‐Yan Huang, , Ya‐Qian Cheng, , Shm Wang, , Juan‐Juan Lin, , Yi Hu, , Duan‐Jun Xu, , Yuan‐Zhi Xu, 
Published: September 2010

AbstractThe title complex Eu(III)(TTA)3(phen) (where TTA = thenoyltrifluoroacetone monoanion; phen = 1,10‐phenanthroline) has been synthesized in mixed solvents of acetone and ethanol (1:1 volume ratio) and its crystal structure has been determined by X‐ray diffraction. The complex crystals are triclinic, space group P 1 (# 2) with cell dimensions of a = 1.32.41 (2) nm, b = 1.5278(4) nm, c = 0.9755(3) nm, α = 92.49 (2)°, β = 102.57(2)°, γ = 91.62(2)°, V = 1.9268(8) nm3, Z = 2, μ (Mo Ka)= 18.77 cm−1, Dx=1.720 g/cm3. The coordination geometry of Eu atom is a distorted square antiprism, and the encapsulated structure that can meet the structural requirement of the typical europium luminescent sensor. The fluorescence spectrum suggests that the complex is a strong photoluminescent material.
Electron‐transfer fluorescence quenching processes in coaggregates between excited N‐alkylcarbazoles as electron donors and 2,4‐dinitrophenyl carboxylates or pentafluorophenyl carboxy‐lates as acceptors
Authors: Ji‐Liang Shi , Hu‐Nan Yi , Jia‐Yi Xu , Xi‐Kui Jiang 
Published: September 2010

AbstractElectron‐transfer processes facilitated by hydrophobic‐lipophilic interaction (HLI) between excited N‐alkylcarbazoles (1‐n, n = 4, 8, 12, 16) as electron donors and 2,4‐dinitrophenyl carboxylates (2‐n, n = 4, 8, 12, 16) or pentafluorophenyl carboxylates (3‐n, n = 4, 8, 12, 16) as electron acceptors have been investigated by means of fluorescence spectroscopy in aqueous or aquiorgano binary mixtures. The fluorescence quenching of ‐n* by 2‐n or ‐ n indicates that preassociation precedes the electron transfer. The extent of HLI‐driven coaggregation of the acceptor and the donor may be assessed from the B value of the equation I0/I = A + B [Q]. The chain‐length effect and possibly also a chain‐fold‐ability effect, as well as the solvent aggregating power (SAgP) effect have been observed. Comparison of roe quenching constants (B) for 1‐n*/2‐n combinations and 1‐n*/ 3‐n combinations shows that the order of increasing B values for the quenching processes is 3‐n < 2‐n.
Lamellar liquid crystal polymerization of sodium oleate/oleic acid/octadiene/water system
Authors: Rong Guo , Qing‐Hong Fu 
Published: September 2010

AbstractIn the lamellar liquid crystallization (LLC) phase of NaOL/ OLA/H2O system, the small angle X‐ray diffraction measurements show that the oleic add is solubilized in the oil layer at first and men into the amphiphile layer. The octadiene added is also located partly in the oil layer and partly in the amphiphile layer in the LLC. With the addition of octadiene as cross‐linking agent, roe LLC phase of NaOL/OLA/H2O system was polymerized under the initiation of AIBN with the protection of pure nitrogen at 60°C. Most of the double bond absorption of the monomers in IR spectra disappeared after polymerization. The polymerization takes place not only in the middle of the amphiphile layer between the double bonds of NaOL or OLA and those of octadiene, but also in the oil layer of LLC between the double bonds of OLA and those of octadiene. Interlayer spacing measurements on the copolymer proved d values decreased by about 1 ‐ 2 nm compared with those of the corresponding system before the polymerization, indicating a disruption of the ordered structure by the polymerization. The copolymer still has superior surface activity with the critical micellar concentration (CMC) decreased almost to the half of the value for the system before the polymerization.