bluuebunny/crossref_metadata_2025_split huggingface dataset:
Les émotions de la cause animale
Authors: Traïni Christophe 
Published: July 2011

Résumé Le concept de dispositif de sensibilisation vise à assurer l’ancrage empirique de l’étude des supports matériels, des agencements d’objets, des mises en scène que les militants déploient afin de susciter des réactions affectives qui prédisposent ceux qui les éprouvent à s’engager ou à soutenir la cause défendue. En ce qui concerne la cause animale, l’analyse historique et idéal-typique permet d’expliciter dans quelle mesure ces dispositifs peuvent alimenter des registres émotionnels bien distincts. Le premier relève d’une logique « démopédique » qui exalte les visées pédagogiques des précepteurs de la cause animale, le second d’une logique de « l’attendrissement » qui porte des secouristes à remédier à la souffrance immédiate des bêtes dignes d’affection, le troisième d’une logique du « dévoilement » qui conduit des justiciers à dénoncer les activités effroyables qui se trament à l’abri du regard du public. La valorisation de l’un ou l’autre de ces registres émotionnels ne peut être exclusivement envisagée comme le résultat de calculs stratégiques. L’article examine dans quelle mesure les émotions valorisées par les militants prolongent des sensibilités forgées tout au long de leur propre histoire affective. Ce faisant, il s’agit de déjouer les visions réductrices du militantisme et des mobilisations qui résultent des présupposés utilitaristes et stratégiques du modèle dit du processus politique.
La projection : pour le meilleur et pour le pire
Authors: Brusset Bernard 
Published: July 2011

Résumé L’auteur relève, dans l’article de Freud sur la projection de 1922, l’oubli des idées antérieures du texte de 1910 sur Schreber, idées à partir desquelles Lacan a introduit la phase du miroir et la notion de forclusion. Le narcissisme spéculaire dans ses rapports avec l’imago maternelle, déjà repérable chez Freud, a été illustré par un cas clinique d’homosexualité publié par l’auteur en 2006. Après avoir situé l’induction de pensée chez Freud, il souligne l’importance du modèle de la projection primordiale dans le tri narcissique entre ce qui est constitutif de soi et étranger à soi. Il montre que la symétrie entre projection et introjection des auteurs kleiniens est mise en suspens par la transitionnalité winnicottienne qui lui est logiquement antérieure. Il considère la notion bionienne d’identification projective comme de seconde génération par rapport à celle de M. Klein.
Gustav Mahler : jalousie et rivalités
Authors: Coblence Françoise 
Published: July 2011

Résumé Le musicien viennois Mahler rencontre Freud une unique fois en août 1910, à la suite de ses difficultés conjugales avec Alma et de la liaison de celle-ci avec Gropius. La visite semble couronnée de succès, mais Mahler meurt quelques mois plus tard. Après Freud, la psychanalyse se penchera à de nombreuses reprises sur « le cas Mahler », non seulement pour analyser sa jalousie et son lien à sa mère, mais aussi le rôle joué dans son œuvre par les deuils à répétition et la rivalité fraternelle. Ces deux aspects de la jalousie, et quelques-unes des expressions de leurs conflits dans la musique de Mahler, sont évoqués ici.
Wilfred Bion, philosophe des sciences
Authors: Hochmann Jacques 
Published: July 2011

Résumé Bion a assimilé la démarche de connaissance à une expérience émotionnelle qui fait passer de ps (le chaos de la position schizoparanoïde) à pd (l’ordre de la position dépressive liée au choix d’un vertex). Ce travail essaie d’appliquer cette progression à la découverte de la pensée de Bion, en s’appuyant sur trois philosophes qui l’ont inspirée : Bradley, Braithwaite et Poincaré. On y voit comment Bion a tenté de donner un statut scientifique à la psychanalyse et d’appliquer la psychanalyse à une réflexion plus générale sur la philosophie des sciences.
Impact of Protocol Watch on Compliance With the Surviving Sepsis Campaign
Authors: Giuliano Karen K. , Lecardo Michele , Staul LuAnn 
Published: July 2011

Purpose
Clinical decision support systems are intended to improve patients’ care and outcomes, particularly when such systems are present at the point of care. Protocol Watch was developed as a bedside clinical decision support system to improve clinicians’ adherence to the Surviving Sepsis Campaign guidelines. This pre/post-intervention pilot study was done to evaluate the effect of Protocol Watch on compliance with 5 guidelines from the Surviving Sepsis Campaign.

Methods
Preintervention data on rates and time to complete the resuscitation and management bundles from the Surviving Sepsis Campaign and time to administer antibiotics were collected from intensive care units at 2 large teaching hospitals in the United States. Training on the Protocol Watch application was then provided to clinical staff in the units, and Protocol Watch was installed at all critical care beds in both hospitals. Data were collected on rates and time to completion for 5 Surviving Sepsis Campaign guidelines after installation of Protocol Watch, and univariate analyses were done to evaluate the effect of Protocol Watch on compliance with the guidelines.

Results
Implementation of Protocol Watch was associated with significant improvements in compliance with the resuscitation bundle (P = .01) and decreased time to administer antibiotics (P = .006). No significant changes were achieved for compliance with the management bundle or time to complete the resuscitation or management bundles.

Conclusions
Clinical decision support systems such as Protocol Watch may improve adherence to the Surviving Sepsis Campaign guidelines, which potentially may contribute to reduced morbidity and mortality for critically ill patients with sepsis.
Clear Visualization of Anterior Vitreous Incarceration into Cannulae during 25-Gauge Vitrectomy in Eyes with Asteroid Hyalosis
Authors: Shimada Hiroyuki , Nakashizuka Hiroyuki , Hattori Takayuki , Mori Ryusaburo , Mizutani Yoshihiro , Yuzawa Mitsuko 
Published: July 2011

Purpose To demonstrate anterior vitreous incarceration in the cannulae at 3 ports during 25-gauge vitrectomy in eyes with asteroid hyalosis. Methods In 6 eyes with asteroid hyalosis, 3-port 25-gauge pars plana vitrectomy was conducted using conventional 25-gauge cannula (4 eyes) or 25-gauge EdgePlus™ trocar/cannula system (2 eyes). The relationship between the cannulae and anterior vitreous was observed during surgery. Results The 3 ports were observed at the beginning of vitrectomy. At the infusion port, incarceration of anterior vitreous containing asteroid bodies between the cannula and the infusion tip was clearly observed in all 6 eyes, irrespective of the cannula used. When the incarcerated vitreous fibers were excised using a vitreous cutter, the infusion fluid flowed toward the center of the vitreous. At both the left and right ports, anterior vitreous containing asteroid bodies was incarcerated into the cannulae in all 6 eyes irrespective of the cannula used. The incarcerated vitreous fibers were excised. At the end of surgery, no vitreous prolapse was found at the 3 ports in all eyes. Conclusions When using the 25-gauge cannula system, incarceration of anterior vitreous fibers into the cannulae of 3 ports from the beginning of surgery was clearly depicted in eyes with asteroid hyalosis. Excising the incarcerated anterior vitreous fibers is useful to ensure good perfusion and prevent vitreous prolapse.
Performance Benefits of Spatially Distributed Versus Stacked Information on Integration Tasks
Authors: Jang Jooyoung , Schunn Christian D. 
Published: July 2011

SummaryUnderstanding the best way to present information has been an issue of interest to many researchers. Regardless of the content of the information, purely physical elements such as spatial organization may also influence performance. Across two studies with 111 undergraduates (78 in Study 1 and 33 in Study 2), we compared spatially distributed (i.e. when information sources are presented side‐by‐side) against stacked displays (i.e. when information sources are sitting on top of one another with only the top source fully visible). A distributed display time advantage was consistently observed. As potential explanations, a memory strategy selection hypothesis was examined along with other procedural alternative explanations. Copyright © 2011 John Wiley & Sons, Ltd.
Morphological Characterization of a Low‐Bandgap Crystalline Polymer:PCBM Bulk Heterojunction Solar Cells
Authors: Lu Haiyun , Akgun Bulent , Russell Thomas P. 
Published: July 2011

AbstractUnderstanding the morphology of polymer‐based bulk heterojunction (BHJ) solar cells is necessary to improve device efficiencies. Blends of a low‐bandgap silole‐containing conjugated polymer, poly[(4,4′‐bis(2‐ethylhexyl)dithieno[3,2‐b;2′,3′‐d]silole)‐2,6‐diyl‐alt‐(4,7‐bis(2‐thienyl)‐2,1,3‐benzothiadiazole)‐5,5′‐diyl] (PSBTBT) with [6,6]phenyl‐C61‐butyric acid methyl ester (PCBM) were investigated under different processing conditions. The surface morphologies and vertical segregation of the “As‐Spun”, “Pre‐Annealed”, and “Post‐Annealed” films were studied by scanning force microscopy, contact angle measurements, X‐ray photoelectron spectroscopy, near‐edge X‐ray absorption fine structure spectroscopy, dynamic secondary ion mass spectrometry, and neutron reflectivity. The results showed that PSBTBT was enriched at the cathode interface in the “As‐Spun” films and thermal annealing increased the segregation of PSBTBT to the free surface, while thermal annealing after deposition of the cathode increased the PCBM concentration at the cathode interface. Grazing‐incidence X‐ray diffraction and small‐angle neutron scattering showed that the crystallization of PSBTBT and segregation of PCBM occurred during spin coating, and thermal annealing increased the ordering of PSBTBT and enhanced the segregation of the PCBM, forming domains ∼10 nm in size, leading to an improvement in photovoltaic performance.
Stem cell culture engineering – process scale up and beyond
Authors: Sharma Shikha , Raju Ravali , Sui Siguang , Hu Wei‐Shou 
Published: July 2011

AbstractAdvances in stem cell research and recent work on clinical trials employing stem cells have heightened the prospect of stem cell applications in regenerative medicine. The eventual clinical application of stem cells will require transforming cell production from laboratory practices to robust processes. Most stem cell applications will require extensive ex vivo handling of cells, from isolation, cultivation, and directed differentiation to product cell separation, cell derivation, and final formulation. Some applications require large quantities of cells in each defined batch for clinical use in multiple patients; others may be for autologous use and require only small‐scale operations. All share a common requirement: the production must be robust and generate cell products of consistent quality. Unlike the established manufacturing process of recombinant protein biologics, stem cell applications will likely see greater variability in their cell source and more fluctuations in product quality. Nevertheless, in devising stem cell‐based bioprocesses, much insight could be gained from the manufacturing of biological materials, including recombinant proteins and anti‐viral vaccines. The key to process robustness is thus not only the control of traditional process chemical and physical variables, but also the sustenance of cells in the desired potency or differentiation state through controlling non‐traditional variables, such as signaling pathway modulators.
A simple LC‐MS/MS method to determine plasma and cerebrospinal fluid levels of albendazole metabolites (albendazole sulfoxide and albendazole sulfone) in patients with neurocysticercosis
Authors: González‐Hernández Iliana , Ruiz‐Olmedo María Isabel , Cárdenas Graciela , Jung‐Cook Helgi 
Published: July 2011

ABSTRACTThe development and validation of an LC‐MS/MS method for the simultaneous determination of albendazole metabolites (albendazole sulfoxide and albendazole sulfone) in human plasma are described. Samples of 200 μL were extracted with ether–dichloromethane–chloroform (60:30:10, v/v/v). The chromatographic separation was performed using a C18 column with methanol–formic acid 20 mmol/L (70:30) as the mobile phase. The method was linear in a range of 20–5000 ng/mL for albendazole sulfoxide and 10–1500 ng/mL for albendazole sulfone. For both analytes the method was precise (RSD < 12%) and accurate (RE <7%) with high recovery (>90%). The method was successfully applied to determine the plasma and cerebrospinal fluid levels of albendazole sulfoxide and albendazole sulfone in patients with subarachnoidal neurocysticercosis who received albendazole at 30 mg/kg per day for 7 days. This LC‐MS/MS method yielded a quick, simple and reliable protocol for determining albendazole sulfoxide and albendazole sulfone concentrations in plasma and cerebrospinal fluid samples and is applicable to therapeutic monitoring. Copyright © 2011 John Wiley & Sons, Ltd.
‘Often They Fall Through the Cracks’: Separated Children in Ireland and the Role of Guardians
Authors: Martin Shirley , Christie Alastair , Horgan Deirdre , O'Riordan Jacqui 
Published: July 2011

The Separated Children in Europe Programme's Statement of Good Practice (Save the Children and UNHCR, 2004) advises that every separated child should be allocated an independent guardian or adviser.  However, there is wide variation in how this advice has been interpreted across Europe, with some guardians being professional and others volunteers, with some focusing primarily on the legal status of separated children and others on the children's general care and wellbeing. In Ireland, there is no guardianship system designed specifically for separated children.  This paper analyses the legal and policy context of guardianship for separated children in Ireland and draws on research undertaken with 16 professionals who provide services for separated children.  The research findings highlight a number of key themes including: ‘cracks’ in the asylum process through which separated children and young people fall; conflicts between legalistic and holistic interpretations of guardianship; variations of informal and formal advocacy for separated children in practice; and the potential of guardians to facilitate children's ‘voices’ and ‘best interests’.  The article points to the fundamental tension between migration and child care policy that potentially undermines the development of a guardianship service for separated children. Copyright © 2011 John Wiley & Sons, Ltd.This paper analyses the legal and policy context of guardianship for separated children in Ireland
17O NMR and Computational Study of a Tetrasiliconiobate Ion, [H2+xSi4Nb16O56](14−x)−
Authors: Johnson Rene L. , Villa Eric M. , Ohlin C. A. , Rustad James R. , Casey William H. 
Published: July 2011

AbstractRates of oxygen‐isotope exchange were measured in the tetrasiliconiobate ion [H2+xSi4Nb16O56](14−x)− to better understand how large oxide ions interact with water. The molecule has 19 nonequivalent oxygen sites and is sufficiently complex to evaluate hypotheses derived from our previous work on smaller clusters. We want to examine the extent to which individual oxygen atoms react independently with particular attention given to the order of protonation of the various oxygen sites as the pH decreases from 13 to 6. As in our previous work, we find that the set of oxygen sites reacts at rates that vary over approximately 104 across the molecule at 6<pH<13 but with similar pH dependencies. There is NMR evidence of an intra‐ or intermolecular reaction at pH∼7, where new peaks began to slowly form without losing the 17O isotopic tag, and at pH ≤ 6 these new peaks formed rapidly. The oxygen atoms bonded to silicon atoms began to isotopically exchange at pH 9 and below. The 17O NMR peak positions also vary considerably with pH for some, but not all, nonequivalent oxygen sites. This variation could be only partly accounted by electronic calculations, which indicate that oxygen atoms should shift similarly upon protonation. Instead, we see that some sites change enormously with pH, whereas other, similarly coordinated oxygen atoms are less affected, suggesting that either some protons are exchanging so rapidly that the oxygen sites are seeing an averaged charge, or that counterions are modulating the effect of the coordinated protons.
Towards Libraries of Luminescent Lanthanide Complexes and Labels from Generic Synthons
Authors: Starck Matthieu , Kadjane Pascal , Bois Emmanuel , Darbouret Bruno , Incamps Anne , Ziessel Raymond , Charbonnière Loïc J. 
Published: July 2011

AbstractA synthetic approach is developed to obtain families of luminescent lanthanide complexes and markers from a generic family of precursors built from nonadentate coordination sites. The syntheses of the precursors, based on a directed regioselective nucleophilic aromatic substitution on polyfluoropyridines, are described. Functionalisation of the synthons on the aromatic moieties allowed the introduction of labelling functions and/or the extension of the electronic delocalisation, with concomitant changes in the spectroscopic properties. The synthesis of two such families of ligands and of some of their complexes of EuIII and TbIII are described, and the photo‐physical properties of the complexes were measured, revealing excellent luminescence quantum yields reaching unity in some cases. For some of these complexes, the emphasis was further put on the preparation of an N‐hydroxylsuccinimide (NHS) ester as activated function for labelling. The Tb and La complexes in the NHS activated form were synthesized and fully characterized. The labelling was first demonstrated on amino functionalized polymer beads and characterized by time‐resolved luminescence microscopy. In a second step, the activated Tb complex was used for the labelling of GFR44 monoclonal antibody, and was applied to the detection of carcinoembryonic antigene (CEA) within the frame of a time‐resolved fluoroimmunoassay. Comparison with a commercially available kit based on a europium cryptate as energy donor confirms the efficiency of Tb to act as an energy donor with an unoptimised 35 % increase of the detection efficiency.
Amplified Surface Plasmon Resonance Based DNA Biosensors, Aptasensors, and Hg2+ Sensors Using Hemin/G‐Quadruplexes and Au Nanoparticles
Authors: Pelossof Gilad , Tel‐Vered Ran , Liu Xiao‐Qing , Willner Itamar 
Published: July 2011

AbstractThiolated nucleic acid hairpin nanostructures that include in their stem region a “caged” G‐quadruplex sequence, and in their single‐stranded loop region oligonucleotide recognition sequences for DNA, adenosine monophosphate (AMP), or Hg2+ ions were linked to bare Au surfaces or to Au nanoparticles (NPs) linked to Au surfaces. The opening of the hairpin nanostructures associated with the bare Au surface by the complementary target DNA, AMP substrate, or Hg2+ ions, in the presence of hemin, led to the self‐assembly of hemin/G‐quadruplexes on the surface. The resulting dielectric changes on the surface exhibited shifts in the surface plasmon resonance (SPR) spectra, thus providing a readout signal for the recognition events. A similar opening of the hairpin nanostructures, immobilized on the Au NPs associated with the Au surface, by the DNA, AMP, or Hg2+ led to an ultrasensitive SPR‐amplified detection of the respective analytes. The amplification originated from the coupling between the localized surface plasmon associated with the NPs and the surface plasmon wave, an effect that cooperatively amplifies the SPR shifts that result from the formation of the hemin/G‐quadruplexes. The different sensing platforms reveal impressive sensitivities and selectivities toward the target analytes.
Simultaneous End‐On/Side‐On Coordination Modes of a Diphosphorus Tetrahedral Complex Imposed by Pre‐organization of Oligometallic CuI Acceptors
Authors: Welsch Stefan , Lescop Christophe , Balazs Gabor , Réau Régis , Scheer Manfred 
Published: July 2011

AbstractThe reaction of the [{CpMo(CO)2}2(μ,η2:η2‐P2)] (Cp=cyclopentadienyl) metallo‐ligand 2 with pre‐organized CuI bi‐ and trimetallic precursors afforded new coordination complexes with unprecedented coordination modes for a Mo2P2 complex. Variable‐temperature solution and solid‐state 31P NMR spectroscopy measurements were performed and X‐ray diffraction studies revealed an η2:η1 coordination mode for the Mo2P2 unit of 2 in the CuI bimetallic complexes 3 and 4. DFT calculations were carried out to highlight the bonding situation of this unprecedented coordination mode in the CuI bimetallic compound 3. It is built up from a side‐on coordination of the PP σ bond to one copper ion and from the interaction of the lone pair of one phosphorus atom with the second copper ion. The remaining available lone pair of the second phosphorus atom can be involved as well to interact with an additional metal centre, as evidenced in the CuI trimetallic compound 5 in which an η2:η1:η1 coordination mode of the ligand 2 is observed. Derivative 3 can be used as a molecular clip to obtain discrete π‐stacked dimers through a ligand exchange reaction between acetonitrile ligands and cyano‐capped π‐conjugated systems, indicating the stability of the new η2:η1 coordination mode.
Disclosure of Corporate Social Responsibility and Environmental Management: Evidence from China
Authors: Kuo Lopin , Yeh Chin‐Chen , Yu Hui‐Cheng 
Published: July 2011

ABSTRACTThis paper first evaluates the quality of corporate social responsibility (CSR) information disclosed in each report using content analysis. Results suggest that 41% of the sample firms fail to provide any information of the 42 CSR activities that allow outside stakeholders to understand their CSR actions; 42% offer text descriptions of their general CSR activities, but only 17% provide statistics about their achievements or other quantitative figures. Further, this paper also compares firms' environmental disclosure from the aspect of environmentally sensitive or ownership patterns. Results indicate that environmentally sensitive industries (ESIs) and state‐owned enterprises (SOEs) are significantly more committed to environmental information disclosure, particularly in ‘paying attention to energy saving/carbon reduction and development of circular economy’ and ‘promotion of research, new techniques, and methods of energy saving/carbon reduction’, both of which are under the energy saving/carbon reduction dimension. This paper attempts to provide some evidence related to Chinese firms coping with global warming. Copyright © 2011 John Wiley & Sons, Ltd and ERP Environment.
The Relationship Between Weight Loss and Health‐related Quality of Life in a Serbian Population
Authors: Vasiljevic Nadja , Ralevic Sonja , Kolotkin Ronette L. , Marinkovic Jelena , Jorga Jagoda 
Published: July 2011

AbstractWe examined changes in weight‐specific health‐related quality of life (HRQOL) and the relation to weight loss in a Serbian population undergoing diet‐induced weight loss treatment. HRQOL was assessed at intake and after 1 year using the Impact of Weight on Quality of Life‐Lite (IWQOL‐Lite) questionnaire. Study sample consists of 135 obese patients. After 1 year of diet therapy, patients experienced an average weight loss of ~12%, and significant improvements were noted in all IWQOL‐Lite domains (Physical Function, Self‐esteem, Sexual Life, Public Distress and Work). Amount of weight loss was closely linked to all domains (F = 27.49; p < 0.001), except Sexual Life (F = 2.08; p = 0.108). In patients with weight reductions of 5%–9.99%, there was a great improvement in physical function and self‐esteem. In those with ≥10% weight loss, there was improvement in all dimensions of IWQOL‐Lite. With the prevalence of obesity rising worldwide, including in Serbia, the positive effects of weight loss on weight‐specific HRQOL are encouraging. Copyright © 2011 John Wiley & Sons, Ltd and Eating Disorders Association.