bluuebunny/crossref_metadata_2025_split huggingface dataset:
Two New Families and a New Species of Myxosporeans (Myxozoa, Myxosporea) of the Mediterranean and Black Sea Fishes
Authors: Yurakhno V. 
Published: January 2012

Two New Families and a New Species of Myxosporeans (Myxozoa, Myxosporea) of the Mediterranean and Black Sea FishesDescriptions of two new families — Polysporoplasmidae fam. n. (Syn. Sphaerosporidae Davis, 1917 in Sitja-Bobadilla, Alvarez-Pellitero, 1995) and Gadimyxidae fam. n. (syn. Parvicapsulidae Schulman, 1953 in Kie et al., 2007), and one new species of myxosporeans —Gadimyxa ovalesp. n. — parasites of fishes of the Mediterranean and the Black Seas are presented. Species of the genus Gadimyxa is found for the first time in the Black Sea.
Sedentary Behaviors, Light-Intensity Physical Activity, and Healthy Aging
Authors: Shi Hongying , Hu Frank B. , Huang Tianyi , Schernhammer Eva S. , Willett Walter C. , Sun Qi , Wang Molin 
Published: June 2024

ImportanceSleep duration and moderate-to-vigorous physical activity (MVPA) are associated with healthy aging, but the associations of sedentary behaviors and light-intensity physical activity (LPA) with healthy aging are still unclear.ObjectiveTo examine the independent association of sedentary behaviors and LPA with healthy aging, and to estimate the theoretical association of replacing sedentary behavior with LPA, MVPA, or sleep with healthy aging.Design, Setting, and ParticipantsIn this cohort study using data from the Nurses’ Health Study, participants aged 50 years or older and free of major chronic diseases in 1992 were prospectively followed up for 20 years. Data were analyzed from January to May 2022.ExposuresThree measures for sedentary behaviors (hours watching television, sitting at work, and other sitting at home) and 2 measures for LPA (hours of standing or walking around at home [LPA-Home] and at work [LPA-Work]).Main Outcomes and MeasuresHealthy aging was defined as survival to at least age 70 years with maintenance of 4 health domains (ie, no major chronic diseases and no impairment in subjective memory, physical function, or mental health). The isotemporal substitution model was used to evaluate the potential impact on healthy aging of replacing 1 hour of 1 behavior with equivalent duration of another.ResultsAmong 45 176 participants (mean [SD] age, 59.2 [6.0] years), 3873 (8.6%) women achieved healthy aging. After adjustment for covariates including MVPA, each increment of 2 hours per day in sitting watching television was associated with a 12% (95% CI, 7%-17%) reduction in the odds of healthy aging. In contrast, each increase of 2 hours per day in LPA-Work was associated with a 6% (95% CI, 3%-9%) increase in the odds of healthy aging. Replacing 1 hour of sitting watching television with LPA-Home (OR, 1.08; 95% CI, 1.05-1.12), LPA-Work (OR, 1.10; 95% CI, 1.07-1.14), or MVPA (OR, 1.28; 95% CI, 1.23-1.34) was associated with increased odds of healthy aging. Among participants who slept 7 hours per day or less, replacing television time with sleep was also associated with increased odds of healthy aging.Conclusions and RelevanceIn this cohort study, longer television watching time decreased odds of healthy aging, whereas LPA and MVPA increased odds of healthy aging and replacing sitting watching television with LPA or MVPA, or with sleep in those who slept 7 hours per day or less, was associated with increased odds of healthy aging, providing evidence for rearranging 24-hour behavior to promote overall health.
3D Printed Sodiophilic Nb2CTx/Reduced Graphene Oxide Monoliths Enable Long Cycle Stability of Sodium Metal Anodes
Authors: Liu Yueyue , Wang Hui , Pan Denghui , Hou Jingrui , Yao Jingjing , Kong Dezhi , Xu Tingting , Shi Yumeng , Li Xinjian , Yang Hui Ying , Wang Ye , Wu Zhong‐Shuai 
Published: June 2024

AbstractAs a promising anode material for Na‐metal batteries, the practical application of Na metal is severely hindered due to the formation of the notorious dendrite and unstable solid‐electrolyte interface (SEI). To address these issues, a direct‐ink writing (DIW) 3D printing technology is proposed to construct an artificial 3D hierarchical porous sodiophilic Nb2CTx/reduced graphene‐oxide (Nb2CTx/rGO) aerogel monolith, which is employed as the matrix of Na metal anode. Benefiting from the homogeneous ion flux and exceptional sodiophilic features, the Nb2CTx nanoflakes embedded within the 3D scaffold regulate the uniform deposition of metallic Na with a stable SEI layer, achieving an ultralong cycle lifespan of 3000 h at 1 mA cm−2 with 1 mAh cm−2 and an impressive Coulombic efficiency of 99.68% over extended lifespan of 7064 h. Further, the in‐depth characterization analysis proves that the formed stable SEI layer consists of an inorganic NaF accumulated in the inner layer and loosely‐bound organic species in the outer layer. Remarkably, when integrated into a Na metal full cell, the reversible capacity reaches 90.22 mAh g−1 after 200 cycles at 100 mA g−1. The work provides a promising strategy to utilize Na metal anodes with long cycle lifespan for next‐generation sodium metal batteries.
Diatom Cribellum‐Inspired Hierarchical Metamaterials: Unifying Perfect Absorption Toward Subwavelength Color Printing
Authors: Xie Xiaohang , Huang Yuwei , Yang Zhiwei , Li Aobo , Zhang Xin 
Published: June 2024

AbstractDiatom exoskeletons, known as frustules, exhibit a unique multilayer structure that has attracted considerable attention across interdisciplinary research fields as a source of biomorphic inspiration. These frustules possess a hierarchical porous structure, ranging from millimeter‐scale foramen pores to nanometer‐scale cribellum pores. In this study, this natural template for nanopattern design is leveraged to showcase metamaterials that integrates perfect absorption and subwavelength color printing. The cribellum‐inspired hierarchical nanopatterns, organized in a hexagonal unit cell with a periodicity of 300 nm, are realized through a single‐step electron beam lithography process. By employing numerical models, it is uncovered that an additional induced collective dipole mode is the key mechanism responsible for achieving outstanding performance in absorption, reaching up to 99%. Analysis of the hierarchical organization reveals that variations in nanoparticle diameter and inter‐unit‐cell distance lead to shifts and broadening of the resonance peaks. It is also demonstrated that the hierarchical nanopatterns are capable of color reproduction with high uniformity and fidelity, serving as hexagonal pixels for high‐resolution color printing. These cribellum‐inspired metamaterials offer a novel approach to multifunctional metamaterial design, presenting aesthetic potential applications in the development of robotics and wearable electronic devices, such as smart skin or surface coatings integrated with energy harvesting functionalities.
Integrating 3D Printed Grinding Tools and Closed‐Loop Temperature Management for Optimal Surgical Outcomes
Authors: Wang Bixuan , Li Kunyang , Liu Gongyu , Xia Luying , Guan Wenning , Guo Juntong , Xu Jie , Nie Yi , Zhao Yongjie , He Yinfeng , Li Haonan 
Published: June 2024

AbstractGrinding is a commonly employed surgical technique for the partial removal of bone. However, the grinding process often generates excessive heat at the interface, leading to localized temperature raise. This can result in irreversible damage to not only the bone but also surrounding tissues, such as nerves. Existing devices rely on the continuous application of coolant to mitigate temperature rise. With the rate and location of coolant deposition being primarily empirical, the current process brings potential risks to patients. In this study, a novel grinding device capable of continuously monitoring grinding temperatures and applying coolant precisely when needed is designed. Utilizing additive manufacturing techniques, a customized grinding tool head equipped with embedded temperature sensors and coolant channels is successfully created. This innovation has enabled the development of an intelligent closed‐loop device that provides precise temperature control during surgery. The device effectively maintains the grinding surface temperature within the user‐defined range, with a latency of less than 1 s. Furthermore, the design ensures that the coolant spray outlets remain unobstructed by debris during grinding and effectively removes debris at the interface, reducing the risk of potential complications, such as bone hyperplasia.
Competing s‐p and p‐p Fluctuations in Charge‐Disproportionation of BaBiO3
Authors: Sarkar Sumit , Choudhary Ram Janay , Sharma Manju , Raghunathan Rajamani 
Published: June 2024

AbstractHere, the mechanism of charge‐disproportionation (CD) in BaBiO3 (BBO) using density functional theory under different crystal symmetries and by employing strain as an external perturbation is investigated. The competition between Bi 6sp–O 2p (s‐p) and O 2p–O 2p (p‐p) or Bi 6p–O 2p charge fluctuations decides the electronic ground state, CD, and bond‐disproportionation (BD) in BBO. An extended Hubbard Hamiltonian involving onsite (U) and long‐range (V) coulomb repulsion is also employed to ascertain the microscopic conditions for forming the lone pair on the bismuth site. A strong tensile strain increases p‐p fluctuation and drives the system into a strong negative‐CT character, while a strong compressive strain favors s‐p fluctuation leading to the enhanced positive‐CT character. This indicates that the change transfer energy of the bulk BBO can be tuned with external strain.
Heat‐Dissipation Design and 3D Printing of Ternary Silver Chalcogenide‐Based Thermoelectric Legs for Enhancing Power Generation Performance
Authors: Kim Keonkuk , Choo Seungjun , Lee Jungsoo , Ju Hyejin , Jung Soo‐ho , Jo Seungki , Lee So‐Hyeon , Baek Seongheon , Kim Ju‐Young , Kim Kyung Tae , Chae Han Gi , Son Jae Sung 
Published: June 2024

AbstractThermoelectric devices have received significant attention because of their potential for sustainable energy recovery. In these devices, a thermal design that optimizes heat transfer and dissipation is crucial for maximizing the power output. Heat dissipation generally requires external active or passive cooling devices, which often suffer from inevitable heat loss and heavy systems. Herein, the design of heat‐sink integrated thermoelectric legs is proposed to enhance heat dissipation without external cooling devices, realized by finite element model simulation and 3D printing of ternary silver chalcogenide‐based thermoelectric materials. Owing to the self‐induced surface charges of the synthesized AgBiSe2 (n‐type) and AgSbTe2 (p‐type) particles, these particle‐based colloidal inks exhibited high viscoelasticity, which enables the creation of complex heat‐dissipation architectures via 3D printing. Power generators made from 3D‐printed heat‐dissipating legs exhibit higher temperature differences and output power than traditional cuboids, offering a new strategy for enhancing thermoelectric power generation.
A rat model of multicompartmental traumatic injury and hemorrhagic shock induces bone marrow dysfunction and profound anemia
Authors: Kelly Lauren S. , Munley Jennifer A. , Pons Erick E. , Kannan Kolenkode B. , Whitley Elizabeth M. , Bible Letitia E. , Efron Philip A. , Mohr Alicia M. 
Published: June 2024

AbstractBackgroundSevere trauma is associated with systemic inflammation and organ dysfunction. Preclinical rodent trauma models are the mainstay of postinjury research but have been criticized for not fully replicating severe human trauma. The aim of this study was to create a rat model of multicompartmental injury which recreates profound traumatic injury.MethodsMale Sprague–Dawley rats were subjected to unilateral lung contusion and hemorrhagic shock (LCHS), multicompartmental polytrauma (PT) (unilateral lung contusion, hemorrhagic shock, cecectomy, bifemoral pseudofracture), or naïve controls. Weight, plasma toll‐like receptor 4 (TLR4), hemoglobin, spleen to body weight ratio, bone marrow (BM) erythroid progenitor (CFU‐GEMM, BFU‐E, and CFU‐E) growth, plasma granulocyte colony‐stimulating factor (G‐CSF) and right lung histologic injury were assessed on day 7, with significance defined as p values <0.05 (*).ResultsPolytrauma resulted in markedly more profound inhibition of weight gain compared to LCHS (p = 0.0002) along with elevated plasma TLR4 (p < 0.0001), lower hemoglobin (p < 0.0001), and enlarged spleen to body weight ratios (p = 0.004). Both LCHS and PT demonstrated suppression of CFU‐E and BFU‐E growth compared to naïve (p < 0.03, p < 0.01). Plasma G‐CSF was elevated in PT compared to both naïve and LCHS (p < 0.0001, p = 0.02). LCHS and PT demonstrated significant histologic right lung injury with poor alveolar wall integrity and interstitial edema.ConclusionsMulticompartmental injury as described here establishes a reproducible model of multicompartmental injury with worsened anemia, splenic tissue enlargement, weight loss, and increased inflammatory activity compared to a less severe model. This may serve as a more effective model to recreate profound traumatic injury to replicate the human inflammatory response postinjury.
Surface Molecular Engineering for Fully Textured Perovskite/Silicon Tandem Solar Cells
Authors: Chen Jun , Yang Shaofei , Jiang Long , Fan Ke , Liu Zhiliang , Liu Wentao , Li Wei , Huang Haitao , Zhang Hong , Yao Kai 
Published: June 2024

AbstractDeveloping large‐scale monolithic perovskite/silicon tandem devices based on industrial Czochralski silicon wafers will likely have to adopt double‐side textured architecture, given their optical benefits and low manufacturing costs. However, the surface engineering strategies that are widely used in solution‐processed perovskites to regulate the interface properties are not directly applicable to micrometric textures. Here, we devise a surface passivation strategy by dynamic spray coating (DSC) fluorinated thiophenethylammonium ligands, combining the advantages of providing conformal coverage and suppressing phase conversion on textured surfaces. From the viewpoint of molecular engineering, theoretical calculation and experimental results demonstrate that introducing trifluoromethyl group provide more effective surface passivation through strong interaction and energy alignment by forming a dipole layer. Consequently, the DSC treatment of this bifunctional molecule enables the tandem cells based on industrial silicon wafers to achieve a certified stabilized power conversion efficiency of 30.89 %. In addition, encapsulated devices display excellent operational stability by retaining over 97 % of their initial performance after 600 h continuous illumination.
Superionic Conduction in K3SbS4 Enabled by Cl‐Modified Anion Lattice
Authors: Chen Yudan , Wang Pengbo , Truong Erica , Ogbolu Bright , Jin Yongkang , Oyekunle Ifeoluwa , Liu Haoyu , Islam M. Mahinur , Poudel Tej , Huang Chen , Hung Ivan , Gan Zhehong , Hu Yan‐Yan 
Published: June 2024

AbstractAll‐solid‐state potassium batteries emerge as promising alternatives to lithium batteries, leveraging their high natural abundance and cost‐effectiveness. Developing potassium solid electrolytes (SEs) with high room‐temperature ionic conductivity is critical for realizing efficient potassium batteries. In this study, we present the synthesis of K2.98Sb0.91S3.53Cl0.47, showcasing a room‐temperature ionic conductivity of 0.32 mS/cm and a low activation energy of 0.26 eV. This represents an increase of over two orders of magnitude compared to the parent compound K3SbS4, marking the highest reported ionic conductivity for non‐oxide potassium SEs. Solid‐state 39K magic‐angle‐spinning nuclear magnetic resonance on K2.98Sb0.91S3.53Cl0.47 reveals an increased population of mobile K+ ions with fast dynamics. Ab initio molecular dynamics (AIMD) simulations further confirm a delocalized K+ density and significantly enhanced K+ diffusion. This work demonstrates diversification of the anion sublattice as an effective approach to enhance ion transport and highlights K2.98Sb0.91S3.53Cl0.47 as a promising SE for all‐solid‐state potassium batteries.
Interfacial Stabilization by Prelithiated Trithiocyanuric Acid as an Organic Additive in Sulfide‐Based All‐Solid‐State Lithium Metal Batteries
Authors: Braks Leonie , Zhang Jinsong , Forster Alexander , Fritz Patrick , Oh Jihoon , El Kazzi Mario , Choi Jang Wook , Coskun Ali 
Published: June 2024

AbstractSulfide‐based all‐solid‐state battery (ASSB) with a lithium metal anode (LMA) is a promising candidate to surpass conventional Li‐ion batteries owing to their inherent safety against fire hazards and potential to achieve a higher energy density. However, the narrow electrochemical stability window and chemical reactivity of the sulfide solid electrolyte towards the LMA results in interfacial degradation and poor electrochemical performance. In this direction, we introduce an organic additive approach, that is the mixing of prelithiated trithiocyanuric acid, Li3TCA, with Li6PS5Cl, to establish a stable interface while preserving high ionic conductivity. Including 2.5 wt % Li3TCA alleviates the decomposition of the electrolyte on the lithium metal interface, decreasing the Li2S content in the solid‐electrolyte interface (SEI) thus forming a more stable interface. In Li|Li symmetric cells, this strategy enables a rise in the critical current density from 1.0 to 1.9 mA cm−2 and stable cycling for over 750 hours at a high current density of 1.0 mA cm−2. This approach also enables Li|NbO‐NCM811 full cell to operate more than 500 cycles at 0.3 C.
The mechanical behavior of epoxy resin foams and the numerical simulation based on phenomenological strain rate‐dependent constitutive model and cellular structure
Authors: Ling Yijie , Chen Yichong , Yao Shun , Hu Dongdong , Xi Zhenhao , Zhao Ling 
Published: June 2024

AbstractEpoxy resin foams are lightweight materials commonly utilized as core materials in shipbuilding and aerospace applications. Mechanical properties and yielding behavior were the basis of the application of epoxy resin foams. In order to reveal the yield behavior and mechanical properties of epoxy resin foams. The compression and tension behavior of epoxy resin foams were investigated. The compression modulus and the tensile modulus increased with the strain rates and foams' density. Epoxy resin foams exhibited excellent toughness and the maximum elongation at break could reach 17.2%. The mechanical properties ( < 5%) of epoxy resin foams were successfully predicted through combining phenomenological strain rate‐dependent constitutive model for epoxy resin and cell structures. The yield point was represented through the elastic strain fraction. The compressive elastic strain fraction () was 0.908, and the tensile elastic strain fraction () was 0.884.
Occurrence, distribution and threats to mobulid rays in Brazil: A review and updated database
Authors: Bucair Nayara , Mendonça Sibele , Santos Paulo R.S. , Chelotti Luiza D. , Santander‐Neto Jones , Nunes Jorge L.S. , Charvet Patricia , Sampaio Claudio L.S. , Rincon Getulio , Gadig Otto B.F. , Dias June F. , Francini‐Filho Ronaldo B. 
Published: June 2024

Abstract
Mobulid rays are medium‐ to large‐sized pelagic‐dwelling planktivorous elasmobranchs that are circumglobally distributed. Brazil has a high diversity of Mobula species, with five of the nine globally valid species and one additional putative new species.
Brazil represents a substantial knowledge gap concerning the ecology, distribution and threats to mobulid rays. In global distribution analyses, several species have been underrepresented along the Brazilian coast.
The dataset is composed of information from peer‐reviewed and grey literature, as well as data from scientific expeditions, citizen science collaboration, social media and local news.
We found 6,450 records of manta and devil rays along the Brazilian coast, including Mobula tarapacana, Mobula mobular, Mobula thurstoni, Mobula hypostoma, Mobula birostris and the putative new species (Mobula cf. birostris).
Our results revealed alarmingly high captures, such as 4.5 tons of M. hypostoma in a single fishery cruise and 809 individuals of Mobula spp. from a single fleet during one year in the Southeastern region.
These findings evidence the fisheries' threats to mobulid species in Brazil and highlight previously unnoted species records, such as the occurrence of M. hypostoma on the entire Brazilian continental shelf, including estuaries and M. tarapacana in coastal regions.
Integrative information on the occurrence, distribution, and threats to mobulid rays on local and global scales is crucial to supporting strategies for their effective management and conservation.
Design of Coatings for Sulfur‐Based Cathode Materials in Lithium‐Sulfur Batteries: A review
Authors: Cai Dandan , Zheng Feng , Li Ying , Zhang Caizhi , Qin Ziwei , Li Wenxian , Liu Yang , Li Aijun , Zhang Jiujun 
Published: June 2024

AbstractLithium‐sulfur batteries (LSBs) are considered next‐generation energy storage and conversion solutions owing to their high theoretical specific capacity and the high abundance/low‐cost of sulfur‐based cathode materials. However, LSBs still encounter significant challenges, including the low conductivities of sulfur‐based materials, severe volumetric expansion of sulfur during the discharge process, and the persistent “shuttle effect” of polysulfides. In recent years, a tremendous amount of research has been conducted to address the above challenges by developing coating and compositing materials and corresponding fabrication strategies for sulfur‐based cathode materials. In this study, the surface coating, compositing materials, and fabrication methodologies of LSB cathodes are comprehensively reviewed in terms of advanced materials, structure/component characterization, functional mechanisms, and performance validation. Some technical challenges are analyzed in detail, and possible future research directions are proposed to overcome the challenges toward practical applications of lithium‐sulfur batteries.
Pattern‐centric transformation of omics data grounded on discriminative gene associations aids predictive tasks in TCGA while ensuring interpretability
Authors: Patrício André , Costa Rafael S. , Henriques Rui 
Published: June 2024

AbstractThe increasing prevalence of omics data sources is pushing the study of regulatory mechanisms underlying complex diseases such as cancer. However, the vast quantities of molecular features produced and the inherent interplay between them lead to a level of complexity that hampers both descriptive and predictive tasks, requiring custom‐built algorithms that can extract relevant information from these sources of data. We propose a transformation that moves data centered on molecules (e.g., transcripts and proteins) to a new data space focused on putative regulatory modules given by statistically relevant co‐expression patterns. To this end, the proposed transformation extracts patterns from the data through biclustering and uses them to create new variables with guarantees of interpretability and discriminative power. The transformation is shown to achieve dimensionality reductions of up to 99% and increase predictive performance of various classifiers across multiple omics layers. Results suggest that omics data transformations from gene‐centric to pattern‐centric data supports both prediction tasks and human interpretation, notably contributing to precision medicine applications.