bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Highly Enantioselective Mukaiyama Aldol Reaction in Aqueous Conditions Using a Chiral Iron(II) Bipyridine Catalyst.
Authors: Ollevier Thierry , Plancq Baptiste 
Published: June 2012

AbstractThe Fe‐catalyzed Mukaiyama aldol reaction of aromatic silyl enol ethers with aldehydes proceeds in aqueous solvent to give the product β‐hydroxy ketones (III) and (V) with moderate to high diastereo‐ and enantioselectivities (up to 98% e.e.
ChemInform Abstract: Stereoselective Synthesis of 1‐Nitrobicyclo[3.1.0]hexanes and Fused Isoxazoline‐N‐oxides from Primary Nitro Compounds.
Authors: Kamimura Akio , Takeuchi Ryota , Ikeda Kosuke , Moriyama Takaaki , Sumimoto Michinori 
Published: June 2012

AbstractTreatment of nitroalkenes of type (III) with Ag2O, I2, and DBU allows a simple, new, and stereoselective access to nitrobicyclohexanes and/or fused isoxazoline‐N‐oxides.
ChemInform Abstract: C—H Functionalization of Tertiary Amines by Cross Dehydrogenative Coupling Reactions: Solvent‐Free Synthesis of α‐Aminonitriles and β‐Nitroamines under Aerobic Condition.
Authors: Alagiri Kaliyamoorthy , Prabhu Kandikere Ramaiah 
Published: June 2012

AbstractMoO2(acac)2 is an efficient catalyst for synthesis of α‐aminonitriles by oxidative cyanation of tertiary amines (I), (VI), and (XI), whilst vanadium pentoxide is a good catalyst for the aza‐Henry reaction of amines (Ib) and (VI) with nitroalkanes.
ChemInform Abstract: N‐Acyl DBN Tetraphenylborate Salts as N‐Acylating Agents.
Authors: Taylor James E. , Jones Matthew D. , Williams Jonathan M. J. , Bull Steven D. 
Published: June 2012

AbstractThe title salts (IVa)—(IVe) are efficient N‐acylating agents, which allow the convenient formation of a number of secondary and tertiary amides as well as acylated sulfonamides.
ChemInform Abstract: Deprotection of Dithioacetals with 30% Hydrogen Peroxide Catalyzed by Tantalum(V) Chloride—Sodium Iodide or Niobium(V) Chloride—Sodium Iodide.
Authors: Kirihara Masayuki , Noguchi Takuya , Okajima Nobuhiro , Naito Sayuri , Ishizuka Yuki , Harano Aiko , Tsukiji Hiroyuki , Takizawa Ryu 
Published: June 2012

AbstractA range of functional groups is inert and unaffected under these reaction conditions.
ChemInform Abstract: The Synthesis of Long‐Chain α‐Alkyl‐β‐hydroxy Esters Using Allylic Halides in a Frater—Seebach Alkylation.
Authors: Khan Ashna A. , Chee Stephanie H. , Stocker Bridget L. , Timmer Mattie S. M. 
Published: June 2012

AbstractThe improved Frater—Seebach methodology for the introduction of α‐substituents to chiral β‐hydroxy esters is also applicable to long‐chain allylic iodides resulting in better yields for the α‐alkylation compared to the appropriate saturated compounds.
ChemInform Abstract: Si‐Free Enolate Claisen Rearrangements of Enamido Substrates.
Authors: Harker Wesley R. R. , Carswell Emma L. , Carbery David R. 
Published: June 2012

AbstractThe protocol for the reaction of allyl esters (Ia)—(Ic) actually compliments a traditional silylation approach for arylacetate esters [cf.
ChemInform Abstract: Synthesis, Including Asymmetric Synthesis, of 3‐Oxabicyclo[3.1.0]hexanes and Bicyclo[3.1.0]hexanes by the 1,5‐CH Insertion of Cyclopropylmagnesium Carbenoids as the Key Reaction.
Authors: Satoh Tsuyoshi , Tsuru Takahiro , Ikeda Shotaro , Miyagawa Toshifumi , Momochi Hitoshi , Kimura Tsutomu 
Published: June 2012

AbstractOn treatment with iPr—MgCl, a variety of 1‐chlorocyclopropyl p‐tolyl sulfoxides bearing an ether functional group at the 2‐ or 4‐position of the alkyl side chain gives the bicyclic title compounds.
ChemInform Abstract: Polymer‐Supported Enantioselective Bifunctional Catalysts for Nitro‐Michael Addition of Ketones and Aldehydes.
Authors: Tuchman‐Shukron Lital , Miller Scott J. , Portnoy Moshe 
Published: June 2012

AbstractFor the substrates (II), (IVb), (VIa) the title reaction gives better yields and enantioselectivities with the presented organocatalyst, which is prepared for the first time for this reaction, than for all previously reported similar systems.
ChemInform Abstract: Highly Chemoselective Reduction of Carbonyl Groups in the Presence of Aldehydes.
Authors: Bastug Gulluzar , Dierick Steve , Lebreux Frederic , Marko Istvan E. 
Published: June 2012

AbstractThe method is based on the ability of diethylaluminium benzenethiolate to mediate the in situ reduction of ketones and esters in the presence of aldehydes intra‐ or intermolecularly.
ChemInform Abstract: Highly Regioselective AgNTf2‐Catalyzed Intermolecular Hydroamination of Alkynes with Anilines.
Authors: Zhang Xu , Yang Bin , Li Guangzhao , Shu Xin , Mungra Divyesh C. , Zhu Jin 
Published: June 2012

AbstractThe reaction of unsymmetrical alkynes with 1 equiv.
ChemInform Abstract: Ligand‐Accelerated Pd‐Catalyzed Ketone γ‐Arylation via C—C Cleavage with Aryl Chlorides.
Authors: Ziadi Asraa , Martin Ruben 
Published: June 2012

AbstractThe ring‐opening γ‐arylation tolerates a broad scope of aromatic and heteroaromatic chlorides and various substitutions on the cyclobutane backbone bearing an unprotected hydroxyl function at a tertiary carbon.
ChemInform Abstract: Facile Preparation of Aromatic Ketones from Aromatic Bromides and Arenes with Aldehydes.
Authors: Ushijima Sousuke , Dohi Souya , Moriyama Katsuhiko , Togo Hideo 
Published: June 2012

AbstractA novel environmentally benign method for the preparation of various aromatic ketones includes a simple experimental procedure and transition‐metal‐free conditions.
ChemInform Abstract: Ambient Schmittel Cyclization Promoted by Chemoselective Triazole‐Gold Catalyst.
Authors: Wang Qiaoyi , Aparaj Siddhita , Akhmedov Novruz G. , Petersen Jeffrey L. , Shi Xiaodong 
Published: June 2012

AbstractTriazole‐gold‐catalyzed Propargyl vinyl ether rearrangement according to A) followed by cyclization allows an access to the previously challenging benzannulated indenes at room temperature.
ChemInform Abstract: N‐Phenacylpyridinium Bromides in the One‐Pot Synthesis of 2,3‐Dihydrofurans.
Authors: Chuang Che‐Ping , Chen Kuang‐Po 
Published: June 2012

AbstractBenzylidene 1,3‐dicarbonyl compounds are generated in situ from aromatic aldehydes and 1,3‐dicarbonyl compounds and subjected to reaction with N‐phenacylpyridinium bromides.
ChemInform Abstract: Expedient One‐Step Synthesis of Nitrogen Stilbene Analogues by Transition Metal‐Free Hydroamination of Arylacetylenes with Pyrroles.
Authors: Dvorko Marina Yu. , Schmidt Elena Yu. , Glotova Tatyana E. , Shabalin Dmitrii A. , Ushakov Igor' A. , Kobychev Vladimir B. , Petrushenko Konstantin B. , Mikhaleva Al'bina I. , Trofimov Boris A. 
Published: June 2012

AbstractThe stereochemistry of the products, ranging from 100% (E) to 96% (Z), is controlled kinetically on the initial stages of the reaction and thermodynamically in the end of the process depending on the nature of substrates and the reaction conditions.
ChemInform Abstract: Synthesis of Spiro[furan‐3,3′‐indolin]‐2′‐ones by PET‐Catalyzed [3 + 2] Reactions of Spiro[indoline‐3,2′‐oxiran]‐2‐ones with Electron‐Rich Olefins.
Authors: Wang Lihong , Li Zhanshan , Lu Lianhong , Zhang Wei 
Published: June 2012

AbstractThe efficient photochemical approach proceeds by oxirane ring‐opening and subsequent cycloaddition with olefins using PET as a sensitizer.
ChemInform Abstract: Iodine‐Mediated Regioselective C2‐Amination of Indoles and a Concise Total Synthesis of (.+‐.)‐Folicanthine.
Authors: Li Ying‐Xiu , Wang Hai‐Xi , Ali Shaukat , Xia Xiao‐Feng , Liang Yong‐Min 
Published: June 2012

AbstractA highly efficient, atom‐economical, environmentally friendly and metal‐free direct C‐2 amination of indole derivatives with N‐tosylanilines is presented.
ChemInform Abstract: The Direct Asymmetric α Alkylation of Ketones by Broensted Acid Catalysis.
Authors: Song Liu , Guo Qi‐Xiang , Li Xing‐Cheng , Tian Juan , Peng Yun‐Gui 
Published: June 2012

AbstractThe direct alkylation of unmotified ketones with an activated alcohol proceeds successfully in the presence of phosphoric acid BPA to produce good to excellent e.e.
ChemInform Abstract: Chiral Monodentate Phosphines and Bulky Carboxylic Acids: Cooperative Effects in Palladium‐Catalyzed Enantioselective C(sp3)—H Functionalization.
Authors: Saget Tanguy , Lemouzy Sebastien J. , Cramer Nicolai 
Published: June 2012

AbstractSterically demanding electron‐rich, and air‐stable ligands of type (I) are successful in the title reaction.
ChemInform Abstract: Huisgen Click Cycloadditions from a Copper(II)‐Tren Precatalyst Without External Sacrificial Reductant.
Authors: Harmand Lydie , Lescure Marie‐Helene , Candelon Nicolas , Duttine Mathieu , Lastecoueres Dominique , Vincent Jean‐Marc 
Published: June 2012

AbstractTitle complexes such as (I) are suitable pre‐catalysts for the 1,3‐dipolar cycloaddition of organic azides to terminal alkynes.
ChemInform Abstract: Highly Convergent One‐Pot Four‐Component Regioselective Synthesis of 4H‐Benzo[f]chromenes via Annulation of β‐Oxodithioesters.
Authors: Samai Subhasis , Nandi Ganesh Chandra , Singh Maya Shankar 
Published: June 2012

AbstractThe InCl3‐catalyzed coupling of β‐naphthol with an aromatic aldehyde, a dithioester (III) and a primary alcohol creates four new bonds and one stereocenter in a single step.
ChemInform Abstract: Diastereoselective Synthesis of Substituted Tetrahydrothiopyrans via (3,5)‐Thionium—Ene Cyclization Reaction.
Authors: Bondalapati Somasekhar , Gogoi Paramartha , Indukuri Kiran , Saikia Anil K. 
Published: June 2012

AbstractThe reaction with aldehydes (IV) and (VI) leads to tricyclic compounds via concomitant intramolecular cyclization.
ChemInform Abstract: Direct Arylation under Catalysis of an Oxime‐Derived Palladacycle: Search for a Phosphane‐Free Method.
Authors: Zhang Guofu , Zhao Xiaobao , Yan Yunbing , Ding Chengrong 
Published: June 2012

AbstractConditions A) are used for the preparation of various phenanthridine structures as alkaloid analogues and for the arylation of the biologically interesting benzothiazole scaffold.
ChemInform Abstract: Efficient Synthesis of Aminomethylated Azaindoles and Corresponding Pyrrole‐Fused Derivatives by Copper‐Catalyzed Domino Multicomponent Coupling and Cyclization.
Authors: Hou Zengye , Suzuki Yamato , Oishi Shinya , Fujii Nobutaka , Ohno Hiroaki 
Published: June 2012

AbstractSince the introduction of an alkynyl group after formation of the azaindole skeleton [cf.
ChemInform Abstract: One‐Pot Crabbe Homologation‐Radical Cascade Cyclization with Memory of Chirality.
Authors: Mondal Shovan , Nechab Malek , Vanthuyne Nicolas , Bertrand Michele P. 
Published: June 2012

AbstractThe tandem Crabbe homologation—radical rearrangement of terminal enediynes (I), (IV) and (VI) leads, in a one‐pot procedure, to the enantioselective synthesis of six‐ and seven‐membered ring α‐aminoesters (III), (V), and (VII) bearing a quaternary stereocenter based on the phenomenon of memory of chirality.
ChemInform Abstract: An Efficient Regioselective Synthesis of Highly Functionalized 3‐Oxo‐2,3‐dihydro‐5H‐thiazolo[3,2‐a]pyrimidines via an Isocyanide‐Based Three‐Component Reaction.
Authors: Esmaeili Abbas Ali , Zangouei Mahdieh , Fakhari Ali Reza , Habibi Azizollah 
Published: June 2012

AbstractThe uncatalyzed one‐pot reaction offers a direct approach to title compounds (IV), which are of potential synthetic and pharmaceutical interest.
ChemInform Abstract: Microwave‐Promoted Michael Addition of Azaheterocycles to α,β‐Unsaturated Esters and Acid under Solvent‐Free Conditions.
Authors: Dubois Lilian , Acher Francine C. , McCort‐Tranchepain Isabelle 
Published: June 2012

AbstractMichael addition of N‐9 adenine (I) to tert‐butylacrylate or acrylic acid proceeds under phase‐transfer catalysis in the presence of DABCO to give N‐alkylated products (III).
ChemInform Abstract: Synthesis of [1,2,3]Triazolo[1,5‐a]quinoxalin‐4(5H)‐ones Through Copper‐Catalyzed Tandem Reactions of N‐(2‐Haloaryl)propiolamides with Sodium Azide.
Authors: Yan Jiajie , Zhou Fengtao , Qin Dongguang , Cai Tong , Ding Ke , Cai Qian 
Published: June 2012

AbstractThe reaction is effective starting from iodo and bromo substrates, tolerates aromatic and aliphatic substituents at the triple bond and different substituents at the nitrogen and on the aromatic ring.
ChemInform Abstract: Expedient Microwave‐Assisted Synthesis of Novel 6‐Substituted 5‐Alkoxy(benzyloxy)‐3,6‐dihydro‐2H‐1,3,4‐oxadiazin‐2‐ones.
Authors: Geffken Detlef , Hansen Finn K. , Khankischpur Mehdi , Mauz Tobias , Meurer Ronald 
Published: June 2012

AbstractThe novel type of heterocycle (II) is of interest in drug development.
ChemInform Abstract: Enantioselective Gold‐Catalyzed Synthesis of Polycyclic Indolines.
Authors: Cera Gianpiero , Chiarucci Michel , Mazzanti Andrea , Mancinelli Michele , Bandini Marco 
Published: June 2012

AbstractGold‐catalyzed hydroindolination/iminium trapping sequences lead to chemo‐, regio‐ and stereoselective construction of the tetracyclic dihydropyranylindolines [cf.
ChemInform Abstract: Isocyanide‐Based Four‐Component Synthesis of Ferrocenyl 1,5‐Disubstituted Tetrazoles.
Authors: Amanpour Tayebeh , Mirzaei Peiman , Bazgir Ayoob 
Published: June 2012

AbstractA novel successful method results in the synthesis of arylamino tetrazoles (IV) and (VII).
ChemInform Abstract: Structures of Two New Phenolic Glycosides, Kaempferiaosides A and B, and Hepatoprotective Constituents from the Rhizomes of Kaempferia parviflora.
Authors: Chaipech Saowanee , Morikawa Toshio , Ninomiya Kiyofumi , Yoshikawa Masayuki , Pongpiriyadacha Yutana , Hayakawa Takao , Muraoka Osamu 
Published: June 2012

AbstractNew compounds, kaempferiaosides A and B (I) are isolated together with 24 known compounds.
Spatiotemporal distribution of vasoactive intestinal polypeptide receptor 2 in mouse suprachiasmatic nucleus
Authors: An Sungwon , Tsai Connie , Ronecker Julie , Bayly Alison , Herzog Erik D. 
Published: June 2012

AbstractVasoactive intestinal polypeptide (VIP) signaling is critical for circadian rhythms. For example, the expression of VIP and its main receptor, VPAC2R, is necessary for maintaining synchronous daily rhythms among neurons in the suprachiasmatic nucleus (SCN), a master circadian pacemaker in animals. Where and when VPAC2R protein is expressed in the SCN and other brain areas has not been examined. Using immunohistochemistry, we characterized a new antibody and found that VPAC2R was highly enriched in the SCN and detectable at low levels in many brain areas. Within the SCN, VPAC2R was circadian, peaking in the subjective morning, and abundantly expressed from the rostral to caudal margins with more in the dorsomedial than ventrolateral area. VPAC2R was found in nearly all SCN cells including neurons expressing either VIP or vasopressin (AVP). SCN neurons mainly expressed VPAC2R in their somata and dendrites, not axons. Finally, constant light increased VIP and AVP expression, but not VPAC2R. We conclude that the circadian clock, not the ambient light level, regulates VPAC2R protein localization. These results are consistent with VPAC2R playing a role in VIP signaling at all times of day, broadly throughout the brain and in all SCN cells. J. Comp. Neurol. 520:2730–2741, 2012. © 2012 Wiley Periodicals, Inc.
Distribution of vesicular glutamate transporter 2 (VGluT2) in the primary visual cortex of the macaque and human
Authors: Garcia‐Marin Virginia , Ahmed Tunazzina H. , Afzal Yasmeen C. , Hawken Michael J. 
Published: June 2012

AbstractThe majority of thalamic terminals in V1 arise from lateral geniculate nucleus (LGN) afferents. Thalamic afferent terminals are preferentially labeled by an isoform of the vesicular glutamate transporter, VGluT2. The goal of our study was to determine the distribution of VGluT2‐ir puncta in macaque and human visual cortex. First, we investigated the distribution of VGluT2‐ir puncta in all layers of macaque monkey primary visual cortex (V1), and found a very close correspondence between the known distribution of LGN afferents from previous studies and the distribution of VGluT2‐immunoreactive (‐ir) puncta. There was also a close correspondence between cytochrome oxidase density and VGluT2‐ir puncta distribution. After validating the correspondence in macaque, we made a comparative study in human V1. In many aspects, the distribution of VGluT2‐ir puncta in human was qualitatively similar to that of the macaque: high densities in layer 4C, patches of VGluT2‐ir puncta in the supragranular layer (2/3), lower but clear distribution in layers 1 and 6, and very few puncta in layers 5 and 4B. However, there were also important differences between macaques and humans. In layer 4A of human, there was a sparse distribution of VGluT2‐ir puncta, whereas in macaque, there was a dense distribution with the characteristic honeycomb organization. The results suggest important changes in the pattern of cortical VGluT2 immunostaining that may be related to evolutionary differences in the cortical organization of LGN afferents between Old World monkeys and humans. J. Comp. Neurol. 521:130–151, 2013. © 2012 Wiley Periodicals, Inc.
A multisensory centrifugal neuron in the olfactory pathway of heliothine moths
Authors: Zhao Xin‐Cheng , Pfuhl Gerit , Surlykke Annemarie , Tro Jan , Berg Bente G. 
Published: June 2012

AbstractWe have characterized, by intracellular recording and staining, a unique type of centrifugal neuron in the brain olfactory center of two heliothine moth species; one in Heliothis virescens and one in Helicoverpa armigera. This unilateral neuron, which is not previously described in any moth, has fine processes in the dorsomedial region of the protocerebrum and extensive neuronal branches with blebby terminals in all glomeruli of the antennal lobe. Its soma is located dorsally of the central body close to the brain midline. Mass‐fills of antennal‐lobe connections with protocerebral regions showed that the centrifugal neuron is, in each brain hemisphere, one within a small group of neurons having their somata clustered. In both species the neuron was excited during application of non‐odorant airborne signals, including transient sound pulses of broad bandwidth and air velocity changes. Additional responses to odors were recorded from the neuron in Heliothis virescens. The putative biological significance of the centrifugal antennal‐lobe neuron is discussed with regard to its morphological and physiological properties. In particular, a possible role in multisensory processes underlying the moth's ability to adapt its odor‐guided behaviors according to the sound of an echo‐locating bat is considered. J. Comp. Neurol. 521:152–168, 2013. © 2012 Wiley Periodicals, Inc.
Introduction pathway and climate trump ecology and life history as predictors of establishment success in alien frogs and toads
Authors: Rago Alfredo , While Geoffrey M. , Uller Tobias 
Published: June 2012

AbstractA major goal for ecology and evolution is to understand how abiotic and biotic factors shape patterns of biological diversity. Here, we show that variation in establishment success of nonnative frogs and toads is primarily explained by variation in introduction pathways and climatic similarity between the native range and introduction locality, with minor contributions from phylogeny, species ecology, and life history. This finding contrasts with recent evidence that particular species characteristics promote evolutionary range expansion and reduce the probability of extinction in native populations of amphibians, emphasizing how different mechanisms may shape species distributions on different temporal and spatial scales. We suggest that contemporary changes in the distribution of amphibians will be primarily determined by human‐mediated extinctions and movement of species within climatic envelopes, and less by species‐typical traits.
Maintenance of genetic diversity in cyclic populations—a longitudinal analysis inMyodes glareolus
Authors: Rikalainen Kaisa , Aspi Jouni , Galarza Juan A. , Koskela Esa , Mappes Tapio 
Published: June 2012

AbstractConspicuous cyclic changes in population density characterize many populations of small northern rodents. The extreme crashes in individual number are expected to reduce the amount of genetic variation within a population during the crash phases of the population cycle. By long‐term monitoring of a bank vole (Myodes glareolus) population, we show that despite the substantial and repetitive crashes in the population size, high heterozygosity is maintained throughout the population cycle. The striking population density fluctuation in fact only slightly reduced the allelic richness of the population during the crash phases. Effective population sizes of vole populations remained also relatively high even during the crash phases. We further evaluated potential mechanisms contributing to the genetic diversity of the population and found that the peak phases are characterized by both a change in spatial pattern of individuals and a rapid accession of new alleles probably due to migration. We propose that these events act together in maintaining the high genetic diversity within cyclical populations.
Preparation, Structural Characterization, and Enhanced Electrical Conductivity of Pyrochlore‐type (Sm1–xEux)2Zr2O7 Ceramics
Authors: Xia X.‐L. , Liu Z.‐G. , Ouyang J.‐H. , Zheng Y. 
Published: June 2012

Abstract(Sm1–xEux)2Zr2O7 (0 ≤ x ≤ 1.0) samples are prepared by solid state reaction method using Sm2O3, Eu2O3, and ZrO2 as starting materials. The phase composition and microstructure of (Sm1–xEux)2Zr2O7 ceramics are investigated by X‐ray diffraction (XRD), scanning electron microscopy, high‐resolution transmission electron microscopy (HRTEM) coupled with selected area electron diffraction and Raman spectroscopy. XRD and TEM show that all the samples exhibit a single pyrochlore‐type structure. HRTEM observation indicates that the whole grain interior of Sm2Zr2O7 ceramic is a perfect crystal free of any dislocation. Raman spectroscopy reveals that the degree of structural disorder of (Sm1–xEux)2Zr2O7 ceramics increases gradually with increasing Eu content. The electrical conductivity of (Sm1–xEux)2Zr2O7 ceramics is investigated by impedance spectroscopy in the air and hydrogen atmospheres, respectively. The electrical conductivity of (Sm1–xEux)2Zr2O7 ceramics increases with increasing Eu content at identical temperature levels. Both the activation energy Eg and the pre‐exponential factor σ0g for the grain conductivity gradually increase with increasing Eu content. As the ionic conductivity shows no obvious change in both air and hydrogen atmospheres, the conduction of (Sm1–xEux)2Zr2O7 is purely ionic with negligible electronic conduction.
Residual Stress and Buckling Patterns of Free‐standing Yttria‐stabilized‐zirconia Membranes Fabricated by Pulsed Laser Deposition
Authors: Evans A. , Prestat M. , Tölke R. , Schlupp M. V. F. , Gauckler L. J. , Safa Y. , Hocker T. , Courbat J. , Briand D. , de Rooij N. F. , Courty D. 
Published: June 2012

AbstractThe residual stress and buckling patterns of free‐standing 8 mol.% yttria‐stabilized‐zirconia (8YSZ) membranes prepared by pulsed laser deposition and microfabrication techniques on silicon substrates are investigated by wafer curvature, light microscopy, white light interferometry, and nanoindentation. The 300 nm thin 8YSZ membranes (390 μm × 390 μm) deposited at 25 °C are almost flat after free‐etching, whereas deposition at 700 °C yields strongly buckled membranes with a compressive stress of –1,100 ± 150 MPa and an out‐of‐plane‐displacement of 6.5 μm. These latter membranes are mechanically stable during thermal cycling up to 500 °C. Numerical simulations of the buckling shape using the Rayleigh–Ritz‐method and a Young's modulus of 200 GPa are in good agreement with the experimental data. The simulated buckling patterns are used to extract the local stress distribution within the free‐standing membrane which consists of tensile and compressive stress regions that are below the failure stresses. This is important regarding the application in, e.g., microsolid oxide fuel cell membranes which must be thermomechanically stable during microfabrication and device operation.