bluuebunny/crossref_metadata_2025_split huggingface dataset:
Characterizing the Spatial Patterns of Global Fertilizer Application and Manure Production
Authors: Potter Philip , Ramankutty Navin , Bennett Elena M. , Donner Simon D. 
Published: April 2010

Abstract
Agriculture has had a tremendous impact on soil nutrients around the world. In some regions, soil nutrients are depleted because of low initial soil fertility or excessive nutrient removals through intense land use relative to nutrient additions. In other regions, application of chemical fertilizers and manure has led to an accumulation of nutrients and subsequent water quality problems. Understanding the current level and spatial patterns of fertilizer and manure inputs would greatly improve the ability to identify areas that might be sensitive to aquatic eutrophication or to nutrient depletion. The authors calculated spatially explicit fertilizer inputs of nitrogen (N) and phosphorus (P) by fusing national-level statistics on fertilizer use with global maps of harvested area for 175 crops. They also calculated spatially explicit manure inputs of N and P by fusing global maps of animal density and international data on manure production and nutrient content. Significantly higher application rates were found for both fertilizers and manures in the Northern Hemisphere, with maxima centered on areas with intensive cropland and high densities of livestock. Furthermore, nutrient use is confined to a few major hot spots, with approximately 10% of the treated land receiving over 50% of the use of both fertilizers and manures. The authors’ new spatial disaggregation of the rich International Fertilizer Industry Association (IFA) fertilizer-use dataset will provide new and interesting avenues to explore the impact of anthropogenic activity on ecosystems at the global scale and may also have implications for policies designed to improve soil quality or reduce nutrient runoff.
On the Enhanced Temporal Coherency of Radar Observations in Precipitation
Authors: Jameson A. R. , Kostinski A. B. 
Published: April 2010

Abstract
In this work, the authors present observations of enhanced temporal coherency beyond that expected using the observations of the standard deviation of the Doppler velocities and the assumption of a family of exponentially decaying autocorrelation functions. The purpose of this paper is to interpret these observations by developing the complex amplitude autocorrelation function when both incoherent and coherent backscatter are present. Using this expression, it is then shown that when coherent scatter is present, the temporal coherency increases as observed. Data are analyzed in snow and in rain. The results agree with the theoretical expectations, and the authors interpret this agreement as an indication that coherent scatter is the likely explanation for the observed enhanced temporal coherency. This finding does not affect decorrelation times measured using time series. However, when the time series is not available (as in theoretical studies), the times to decorrelation are often computed based upon the assumptions that the autocorrelation function is a member of the family of exponentially decaying autocorrelation functions and that the signal decorrelation is due solely to the Doppler velocity fluctuations associated with incoherent scatter. Such an approach, at times, may significantly underestimate the true required times to decorrelation thus leading to overestimates of statistical reliability of parameters.
The Role of the Middle Atmosphere in Simulations of the Troposphere during Northern Hemisphere Winter: Differences between High- and Low-Top Models
Authors: Sassi Fabrizio , Garcia R. R. , Marsh D. , Hoppel K. W. 
Published: April 2010

Abstract
This paper compares present-day simulations made with two state-of-the-art climate models: a conventional model specifically designed to represent the tropospheric climate, which has a poorly resolved middle atmosphere, and a configuration that is built on the same physics and numerical algorithms but represents realistically the middle atmosphere and lower thermosphere. The atmospheric behavior is found to be different between the two model configurations, and it is shown that the differences in the two simulations can be attributed to differences in the behavior of the zonal mean state of the stratosphere, where reflection of quasi-stationary resolved planetary waves from the lid of the low-top model is prominent; the more realistic physics in the high-top model is not relevant. It is also shown that downward propagation of zonal wind anomalies during weak stratospheric vortex events is substantially different in the two model configurations. These findings extend earlier results that a poorly resolved stratosphere can influence simulations throughout the troposphere.
Spatial Pattern and Zonal Shift of the North Atlantic Oscillation. Part II: Numerical Experiments
Authors: Luo Dehai , Zhong Linhao , Ren Rongcai , Wang Chunzai 
Published: April 2010

Abstract
In this part, the spatial evolution of an initial dipole anomaly in a prescribed jet is at first investigated by numerically solving linear and nonlinear models without forcing in order to examine how the spatial pattern of a dipole anomaly depends on the meridional distribution of a specified jet. It is shown that in a linear experiment an initial symmetric dipole anomaly in the meridional direction can evolve into a northeast–southwest (NE–SW) or northwest–southeast (NW–SE) tilted dipole structure if the core of this jet is in higher latitudes (the north) or in lower latitudes (the south). This is in agreement with the result predicted by the linear Rossby wave theory in slowly varying media. The conclusion also holds for the nonlinear and unforced experiment.
North Atlantic Oscillation (NAO) events are then reproduced in a fully nonlinear barotropic model with a wavemaker that mimics the Atlantic storm-track eddy activity. In the absence of topography the spatial tilting of the eddy-driven NAO pattern is found to be independent of the NAO phase. The eddy-driven NAO pattern for the positive (negative) phase can exhibit a NE–SW (NW–SE) tilting only when the core of a prescribed jet prior to the NAO is confined in the higher latitude (lower latitude) region. However, in the presence of the wavenumber-2 topography (two oceans and continents) in the Northern Hemisphere the spatial tilting of the eddy-driven NAO dipole anomaly can be dependent on the NAO phase. Even when the specified basic flow prior to the NAO is uniform, the eddy-driven positive (negative) NAO phase dipole anomaly can also show a NE–SW (NW–SE) tilting because the northward (southward) shift of the excited westerly jet can occur in the presence of topography. In addition, it is found that when the wavemaker is closer to the position of the initial NAO, the eddy-driven positive (negative) NAO phase pattern can display a whole eastward shift and a more distinct NE–SW (NW–SE) tilting. This thus explains why the first empirical orthogonal function of the NAO pattern observed during 1998–2007 exhibits a more pronounced NE–SW tilting than during 1978–97. It appears that the latitudinal shift of the jet, the large-scale topography, and the zonal position of the Atlantic storm-track eddy activity are three important factors for controlling the spatial tilting and zonal shift of eddy-driven NAO dipole anomalies.
Spatial Pattern and Zonal Shift of the North Atlantic Oscillation. Part I: A Dynamical Interpretation
Authors: Luo Dehai , Zhu Zhihui , Ren Rongcai , Zhong Linhao , Wang Chunzai 
Published: April 2010

Abstract
This paper presents a possible dynamical explanation for why the North Atlantic Oscillation (NAO) pattern exhibits an eastward shift from the period 1958–77 (P1) to the period 1978–97 (P2) or 1998–2007 (P3). First, the empirical orthogonal function analysis of winter mean geopotential heights during P1, P2, and P3 reveals that the NAO dipole anomaly exhibits a northwest–southeast (NW–SE) tilting during P1 but a northeast–southwest (NE–SW) tilting during P2 and P3. The NAO pattern, especially its northern center, undergoes a more pronounced eastward shift from P1 to P2. The composite calculation of NAO events during P1 and P2 also indicates that the negative (positive) NAO phase dipole anomaly can indeed exhibit such a NW–SE (NE–SW) tilting. Second, a linear Rossby wave formula derived in a slowly varying basic flow with a meridional shear is used to qualitatively show that the zonal phase speed of the NAO dipole anomaly is larger (smaller) in higher latitudes and smaller (larger) in lower latitudes during the life cycle of the positive (negative) NAO phases because the core of the Atlantic jet is shifted to the north (south). Such a phase speed distribution tends to cause the different movement speeds of the NAO dipole anomaly at different latitudes, thus resulting in the different spatial tilting of the NAO dipole anomaly depending on the phase of the NAO. The zonal displacement of the northern center of the NAO pattern appears to be more pronounced because the change of the mean flow between two phases of the NAO is more distinct in higher latitudes than in lower latitudes.
In addition, a weakly nonlinear analytical solution, based on the assumption of the scale separation between the NAO anomaly and transient synoptic-scale waves, is used to demonstrate that an eastward shift of the Atlantic storm-track eddy activity that is associated with the eastward extension of the Atlantic jet stream is a possible cause of the whole eastward shift of the center of action of the NAO pattern during P2/P3.
Vertical Velocity Statistics in Fair-Weather Cumuli at the ARM TWP Nauru Climate Research Facility
Authors: Kollias Pavlos , Albrecht Bruce 
Published: April 2010

Abstract
Fair-weather cumuli are fundamental in regulating the vertical structure of water vapor and entropy in the lowest 2–3 km of the earth’s atmosphere over vast areas of the oceans. In this study, a long record of profiling cloud radar observations at the Atmospheric Radiation Measurement Program (ARM) Climate Research Facility (ACRF) at Nauru Island is used to investigate cloud vertical air motion statistics over an 8-yr observing period. Appropriate processing of the observed low radar reflectivities provides radar volume samples that contain only small cloud droplets; thus, the Doppler velocities are used as air motion tracers. The technique is applied to shallow boundary layer clouds (less than 1000 m thick) during the 1999–2007 period when radar data are available. Using the boundary layer winds from the soundings obtained at the Nauru ACRF, the fair-weather cumuli fields are classified in easterly and westerly boundary layer wind regimes. This distinction is necessary to separate marine-forced (westerlies) from land-forced (easterlies) shallow clouds because of a well-studied island effect at the Nauru ACRF. The two regimes exhibit large diurnal differences in cloud fraction and cloud dynamics as manifested by the analysis of the hourly averaged vertical air motion statistics. The fair-weather cumuli fields associated with easterlies exhibit a strong diurnal cycle in cloud fraction and updraft strength and fraction, indicating a strong influence of land-forced clouds. In contrast over the fair-weather cumuli with oceanic origin, land-forced clouds are characterized by uniform diurnal cloudiness and persistent updrafts at the cloud-base level. This study provides a unique observational dataset appropriate for testing fair-weather cumulus mass flux and turbulence parameterizations in numerical models.
Diagnosis of Zonal Mean Relative Humidity Changes in a Warmer Climate
Authors: Wright Jonathon S. , Sobel Adam , Galewsky Joseph 
Published: April 2010

Abstract
The zonal mean relative humidity response to a doubling of CO2 in a climate model is examined using a global climate model and an offline tracer transport model. Offline tracer transport model simulations are driven by the output from two configurations of the climate model, one with 1979 concentrations of atmospheric greenhouse gases and one with doubled CO2. A set of last saturation tracers is applied within the tracer transport model to diagnose the dynamics responsible for features in the water vapor field. Two different methods are used to differentiate the effects of circulation and transport shifts from spatially inhomogeneous temperature changes. The first of these uses the tracer transport model and is achieved by decoupling the input temperature and circulation fields; the second uses the reconstruction of humidity from the last saturation tracers and is achieved by decoupling the tracer concentrations from their saturation specific humidities. The responses of the tropical and subtropical relative humidities are found to be largely dependent on circulation and transport changes, particularly a poleward expansion of the Hadley cell, a deepening of the height of convective detrainment, a poleward shift of the extratropical jets, and an increase in the height of the tropopause. The last saturation tracers are used to illustrate the influence of changes in transport pathways within the GCM on the zonal mean relative humidity, particularly in the tropical upper troposphere and subtropical dry zones. Relative humidity changes near the extratropical tropopause and in the lower troposphere are largely dependent on changes in the distribution and gradients of temperature. Increases in relative humidity near the extratropical tropopause in both hemispheres are coincident with increases in the occurrence of local saturation and high cloud cover.
Radiation and Dissipation of Internal Waves Generated by Geostrophic Motions Impinging on Small-Scale Topography: Application to the Southern Ocean
Authors: Nikurashin Maxim , Ferrari Raffaele 
Published: April 2010

Abstract
Recent estimates from observations and inverse models indicate that turbulent mixing associated with internal wave breaking is enhanced above rough topography in the Southern Ocean. In most regions of the ocean, abyssal mixing has been primarily associated with radiation and breaking of internal tides. In this study, it is shown that abyssal mixing in the Southern Ocean can be sustained by internal waves generated by geostrophic motions that dominate abyssal flows in this region. Theory and fully nonlinear numerical simulations are used to estimate the internal wave radiation and dissipation from lowered acoustic Doppler current profiler (LADCP), CTD, and topography data from two regions in the Southern Ocean: Drake Passage and the southeast Pacific. The results show that radiation and dissipation of internal waves generated by geostrophic motions reproduce the magnitude and distribution of dissipation previously inferred from finescale measurements in the region, suggesting that it is one of the primary drivers of abyssal mixing in the Southern Ocean.
Chaotic Advection in an Archipelago*
Authors: Rypina Irina I. , Pratt Lawrence J. , Pullen Julie , Levin Julia , Gordon Arnold L. 
Published: April 2010

Abstract
Techniques from dynamical systems theory have been applied to study horizontal stirring of fluid in the Philippine Archipelago. The authors’ analysis is based on velocity fields produced by two high-resolution (3 and 6 km) numerical models. Particular attention is paid to identifying robust surface flow patterns and associating them with dominant Lagrangian coherent structures (LCSs). A recurrent wind-driven dipole in the lee of the coastline is considered in detail. The associated LCSs form a template for stirring, exchange, and biological transport in and around the dipole. Chaotic advection is argued to provide a relevant framework for interpreting mesoscale horizontal stirring processes in an archipelago as a whole. Implications for the formation of filaments, the production of tracer variance, and the scale at which stirring leads to mixing are discussed in connection with an observed temperature record.
Status of the TRMM 2A12 Land Precipitation Algorithm
Authors: Gopalan Kaushik , Wang Nai-Yu , Ferraro Ralph , Liu Chuntao 
Published: April 2010

Abstract
This paper describes improvements to the Tropical Rainfall Measurement Mission (TRMM) Microwave Imager (TMI) land rainfall algorithm in version 7 (v7) of the TRMM data products. The correlations between rain rates and TMI 85-GHz brightness temperatures (Tb) for convective and stratiform rain are generated using 7 years of collocated TMI and TRMM precipitation radar (PR) data. The TMI algorithm for estimating the convective ratio of rainfall is also modified. This paper highlights both the improvements in the v7 algorithm and the continuing problems with the land rainfall retrievals. It is demonstrated that the proposed changes to the algorithm significantly lower the overestimation by TMI globally and over large sections of central Africa and South America. Also highlighted are the problems with the 2A12 land algorithm that have not been addressed in the version 7 algorithm, such as large regional and seasonal dependence of biases in the TMI rain estimates, and potential changes to the algorithm to resolve these problems are discussed.
Glauconite formation in lacustrine/palaeosol sediments, Isle of Wight (Hampshire Basin), UK
Authors: Huggett J. M. , Cuadros J. 
Published: April 2010

AbstractThe clay mineralogy and chemistry of a green lacustrine marl that has been pedogenically modified in the upper part was investigated in order to better understand the formation of low-temperature Fe-rich 10 Å clay. Twelve samples in a vertical sequence have been investigated using X-ray diffraction (XRD), chemical analysis, scanning electron microscopy (SEM) and laser particle size analysis. The clay assemblage has a range of overall illite-smectite (I-S) compositions (64–100%) resulting from several I-S phases that, for the sake of modelling, have been simplified to one to three I-S phases of increasing illitic content. Where the lacustrine marl has been pedogenically modified, the smectite-rich I-S is much reduced in abundance or absent and the 10 Å -rich component is both more abundant and more illitic. These assemblages are a consequence of illitization of detrital I-S in the lake and soil, and dissolution of other clays (kaolinite and chlorite) in the hypersaline lake. Interlayer K, octahedral Fe and octahedral + interlayer Mg increase with intensity of illitization (increase range 0.32–0.63, 0.68–1.67, 0.18–0.24 per O10(OH)2, respectively), first in the increasingly saline lake, and latterly as a result of wetting and drying in a gley soil. In the soil environment, reduction of Fe(III) to Fe(II) resulted in increased layer charge but, as by this stage very few smectite interlayers remained, this did not result in an equivalent increase in illite. Laser particle-size analysis, supported by SEM observation, shows the existence of a bimodal distribution of clay particle size (maxima at 0.2 and 1.5–1.8 μm) in which the finer fraction increases largely in the pedogenically affected samples, probably due to particle break-up caused by seasonal wetting and drying. This ‘dual action’ illitization, first in a hypersaline lake and latterly through wetting and drying, may be responsible for both the intensity of illitization and exceptionally high (for the Solent Group) Fe content of the authigenic illite. The chemical characteristics of the illitic I-S and the illite end-member correspond to glauconite. Hence, this is an example of onshore, non-pelletal glauconite formation.
Obesity is associated with an increased risk of monoclonal gammopathy of undetermined significance among black and white women
Authors: Landgren Ola , Rajkumar S. Vincent , Pfeiffer Ruth M. , Kyle Robert A. , Katzmann Jerry A. , Dispenzieri Angela , Cai Qiuyin , Goldin Lynn R. , Caporaso Neil E. , Fraumeni Joseph F. , Blot William J. , Signorello Lisa B. 
Published: April 2010

Abstract
Obesity and black race have been associated with excess risk of multiple myeloma. The association of obesity with monoclonal gammopathy of undetermined significance (MGUS) is unknown. Further, it is not known whether the increased risk of multiple myeloma and MGUS in blacks is related to socioeconomic status, genetic susceptibility, or both. We screened 1000 black and 996 white women (range, 40-79 years) of similar socioeconomic status for MGUS; the aim of the study was to assess MGUS risk in relation to obesity and race. A total of 39 (3.9%) blacks and 21 (2.1%) whites had MGUS. On multivariate analysis, obesity (odds ratio [OR] = 1.8; P = .04), black race (OR = 1.8; P = .04), and increasing age (> 55 vs < 43 years; OR = 2.5; P = .03) were independently associated with an excess risk of MGUS. Our findings support the hypothesis that obesity is etiologically linked to myelomagenesis. The 2-fold excess of MGUS among blacks compared with whites of similar socioeconomic status supports a role for susceptibility genes in MGUS.
Theoretical Analysis of Phase Diagrams and Mixing Heats of Systems of Ketone/1-Alcohol
Authors: Seki Takuma , Nakajima Ryo , Naoki Motosuke 
Published: April 2010

Abstract
Theoretical treatment of phase diagrams and mixing heats based on hydrogen-bond configuration has been expanded to hydrogen-bonded solutions containing molecules with proton acceptors but without proton donors. The crystal–liquid phase diagrams and the mixing heats of systems of ketone/1-alcohol were reproduced by the theory. Parameters determined from fitting enabled us to estimate the ratio of the number of acceptors associated with donors in the total number of acceptors and the relative contribution of association between molecules of different kinds.
Noncovalent Assembly of TEMPO Radicals Pair-wise Embedded on a DNA Duplex
Authors: Atsumi Hiroshi , Maekawa Kensuke , Nakazawa Shigeaki , Shiomi Daisuke , Sato Kazunobu , Kitagawa Masahiro , Takui Takeji , Nakatani Kazuhiko 
Published: April 2010

Abstract
We have synthesized and characterized a new G–G mismatch binding ligand containing a TEMPO radical. The two mismatch binding ligands cooperatively bound to the CGG/CGG triad and an apparent binding constant was in the order of 105 M−1. The tumbling of the ligand on a DNA duplex was ten times slower than that of the unbound ligand. Asymmetric addressability of two TEMPO radicals on DNA is shown.
Rhodium-catalyzed Dehydroborylation of Styrenes with Naphthalene-1,8-diaminatoborane [(dan)BH]: New Synthesis of Masked β-Borylstyrenes as New Phenylene–Vinylene Cross-coupling Modules
Authors: Iwadate Noriyuki , Suginome Michinori 
Published: April 2010

Abstract
Styrene derivatives underwent dehydroborylation with naphthalene-1,8-diaminatoborane [(dan)BH] in the presence of a cationic rhodium complex, giving β-borylstyrene derivatives in good yields. Thus prepared β-borylstyrenes bearing a chlorine or B(pin) group on their aromatic rings were utilized for the synthesis of highly conjugated molecules through stepwise cross-coupling, taking advantage of the dan group as an effective protective group for a boronyl group.