bluuebunny/crossref_metadata_2025_split huggingface dataset:
Total Ionizing Dose and Displacement-Damage Effects in Microelectronics
Authors: Foster Charles C. 
Published: February 2011

AbstractWhen exposed to radiation, the function of microelectronic devices is not only degraded by single-event phenomena but by cumulative effects. Most of the energy lost by radiation passing through semiconductors is through ionization. Buildup of charge in gate oxide layers and of interface and border traps due to ionization result in semipermanent damage to the device. These effects are known as total ionizing dose effects. A fraction of the energy of the radiation passing through semiconductors is lost to displacement of atoms from their sites in the crystal lattice structure. The buildup of displacement damage with radiation exposure causes gradual but permanent changes in device performance and limits device lifetime in a radiation environment. Displacement damage will be discussed in the context of non-ionizing energy loss.
Scale Effects in Cellular Metals
Authors: Onck P.R. 
Published: February 2011

AbstractScale effects in cellular metals can develop when the specimen size is of the order of the cell size. Decreasing the relevant specimen dimensions—height, width, and ligament size (the region between notches in notched specimens)—leads to material strengthening in shear, in indentation, and in notched specimens and to reduced strength and stiffness in uniaxial compression. Experimental size-effect studies were reviewed, and it was concluded from discrete modeling results that scale effects are caused by two different microstructural mechanisms: boundary-layer effects and constraint effects. The first mechanism is active in shear (strong boundary layers) and uniaxial compression (weak boundary layers) and vanishes for specimens larger than two cell sizes and seven cell sizes, respectively. The second mechanism is active in indentation and in notched specimens, leading to a strengthening behavior that is inversely proportional to indenter and ligament size.
In SituX-Ray Tomography Measurements of Deformation in Cellular Solids
Authors: Maire E. , Elmoutaouakkil A. , Fazekas A. , Salvo L. 
Published: February 2011

AbstractThe use of microtomography to study the structure and especially the deformation modes of cellular solids is reviewed in this article. First, the technique is described in detail. Examples illustrating the power of the coupling ofin situdeformation with three-dimensional (3D) imaging, drawn from the recent literature and the authors' own work, are then given. The most detailed example is the study of the deformation modes of several samples made of different aluminum foams. Four kinds of closed-cell foams were investigated, corresponding to different routes available today for their manufacture. The initial macrostructure was quantified using the 3D images combined with 3D granulometry, allowing retrieval of pertinent information about the cell size and the wall and strut thicknesses. The global behavior exhibited by the foams during thein situcompression experiments was shown to vary from one brand of material to another. Some of these variations can be explained by differences in the known microstructure and the measured macrostructure of the samples.
Cellular Ceramics: Intriguing Structures, Novel Properties, and Innovative Applications
Authors: Green David J. , Colombo P. 
Published: February 2011

AbstractCellular ceramics are a class of high-porosity materials that are used or are being considered for a wide range of technological applications. A critical aspect of this development is the materials science approach required to understand the relationships between the properties of these materials and their structure. Of particular interest are the parameters that control mechanical reliability, as ceramic materials are usually brittle. In addition, it is critical to understand the way in which processing methods can influence the cellular structure. This article emphasizes one particular group of cellular ceramics known as ceramic foams. Understanding these materials involves various interdisciplinary scientific challenges in characterizing structure, developing micromechanical models, experimentally measuring properties, developing new processing approaches, and optimizing performance.
Photonic Materials for Optical Communications
Authors: Hillmer Hartmut , Germann Roland 
Published: February 2011

AbstractAn overview of key materials for optical communications, including semiconductors, dielectrics, glasses, and organics, is presented in this issue of MRS Bulletin. Materials quality is in all cases crucial for advanced device and system performance. Materials properties and important problems are reviewed, and their impact on the performance of state-of-the-art optical devices is assessed and demonstrated by means of selected examples.
Material Properties of III–V Semiconductors for Lasers and Detectors
Authors: Tu Charles W. , K.L.Yu Paul 
Published: February 2011

AbstractWe describe how the material properties of III–V semiconductors, including bandgap, band structure, band offset, refractive index, absorption, and ionization coefficient, are exploited for lasers and photodetectors for fiber-optic communications. The material systems discussed for 1.3 μm and 1.55 μm light emission include the more traditional GaInAsP and AlGaInAs on InP, the more recently investigated GaInAs quantum dots and low-bandgap GaInNAs on GaAs as well as GaAsSb/GaAs Type II structures, and the potentially viable GaN/AlGaN from intersubband transitions (i.e., between quantized conduction-band energy levels). As an example of photodetector applications, GaInAsP/InP and wafer-fused GaInAs/Si are discussed in terms of gain and noise factor for use in avalanche photodiodes with separate absorption and multiplication regions.
Combined Densification and Thermo-Hydro-Mechanical Processing of Wood
Authors: Navi Parviz , Heger Frédéric 
Published: February 2011

AbstractThe process of heating and compressing wood to improve its properties or reform it to a new shape has been known for decades. Such improvements are usually accompanied by “shape memory,” where the deformation produced by compression is not permanent, and the material recovers when re-moistened and heated. The combination of densification and a thermo-hydro-mechanical (THM) treatment can transform wood into a new material with improved mechanical properties, decreased sensitivity to moisture, increased durability, and no shape-memory effects. This article presents the principles of combined densification and THM processing, the products and experimental results, the origin of the shape-memory effect and its elimination by THM treatment, and the potential use of THM-processed densified wood in construction applications.
Molecular Electronics: Theory and Device Prospects
Authors: Ghosh A.W. , Damle P.S. , Datta S. , Nitzan A. 
Published: February 2011

AbstractUnderstanding current flow through molecular conductors involves simulating the contact surface physics, the molecular chemistry, the device electrostatics, and the quantum kinetics of nonequilibrium transport, along with more sophisticated processes such as scattering and many-body effects.We summarize our current theoretical understanding of transport through such nanoscale devices. Our approach is based on self-consistently combining the nonequilibrium Green's function (NEGF) formulation of transport with an electronic structure calculation of the molecule.We identify the essential ingredients that go into such a simulation. While experimental data for many of the inputs required for quantitative simulation are still evolving, the general framework laid down in this treatment should still be applicable.We use these concepts to examine a few prototype molecular devices, such as wires, transistors, and resonant-tunneling diodes.
Electrical and Spectroscopic Characterization of Molecular Junctions
Authors: Kushmerick James G. , Allara David L. , Mallouk Thomas E. , Mayer Theresa S. 
Published: February 2011

AbstractThe design of future molecular electronic devices requires a firm understanding of the conduction mechanisms that determine their electrical characteristics. Progress toward this goal has been hindered by complications in controlling the exact configuration and makeup of fabricated molecular junctions, thus limiting the availability of quantitative experimental data for developing cohesive theories to model and predict molecular transport. This article summarizes recent research aimed at developing well-controlled systems for comparing molecular conduction and vibrational spectra using crossed-wire and in-wire metal–molecule–metal junctions. Systematic variations in molecular structure and metal–molecule contacts show strong quantitative agreement in device properties, while spectroscopic data provide evidence that the properties are due to the molecular junction. Further investigations using these and other molecular junction test beds will provide the needed experimental data to advance fundamental understanding of molecular transport and facilitate future molecular electronics applications.
Nanoceramics in Biomedical Applications
Authors: Ben-Nissan B. 
Published: February 2011

AbstractAn improved understanding of the interactions at the nanoscale level between the bioceramics in medical implants and the hard or soft tissues in the human body could contribute significantly to the design of new-generation prostheses and postoperative patient management strategies.Overall, the benefits of advanced ceramic materials in biomedical applications have been universally accepted, specifically in terms of their strength, biocompatibility, hydrophilicity, and wear resistance in articulating joints.The continuous development of new-generation implants utilizing nanocoatings with novel nanosensors and devices is leading to better compatibility with human tissue and improved well-being and longevity for patients. This article gives a short overview of bioceramics and reexamines key issues of concern for processing and applying nanoceramics as biomaterials.
Bio-Resorbable Nanoceramics for Gene and Drug Delivery
Authors: Kriven Waltraud M. , Kwak Seo-Young , Wallig Matthew A. , Choy Jin-Ho 
Published: February 2011

AbstractNanoscale ceramic particles, such as layered double hydroxides (LDHs), have been developed to deliver drugs or genes into biological cells. In this article, we describe the controlled-release properties of LDHs as drug delivery carriers, the formation of bio-LDH nanohybrids, theirin vivoandin vitrocytotoxicity tests, and their potential as anticancer gene delivery carriers. Unstable biomolecules can be intercalated into LDHs, displacing the interlayer anions; the drug or gene's negative charge is thus shielded, enabling penetration into the cell. In the slightly acidic environment of the cell, ceramic nanoplatelets of ∼100 nm diameter dissolve, thus releasing the intercalates in a controlled manner.
Synthesis, Analysis, and Electrical Property Measurements of Compound Nanotubes in the B-C-N Ceramic System
Authors: Golberg Dmitri , Bando Yoshio , Dorozhkin Pavel , Dong Zhen-Chao 
Published: February 2011

AbstractNanotubular structures in the B-C-N ceramic system represent an intriguing alternative to conventional carbon nanotubes.Because of the ability to widely vary the chemical composition of nanotubes within the B-C-N ternary phase diagram and to change the stacking of C-rich or BN-rich tubular shells in multiwalled structures, a wide horizon opens up for tuning nanostructure electrical properties.Pure carbon nanotubes are metals or narrow-bandgap semiconductors, depending on the helicity and diameter, whereas those of BN are insulators with a ∼5.0eV gap independent of these parameters.Thus, the relative B/C/N ratios and/or BN-rich and C-rich domain spatial arrangements, rather than tube helicity and diameter, are assumed to primarily determine the B-C-N nanotube electrical response.This characteristic is highly valuable for nanotechnology:while tube diameter and helicity are currently difficult to control, continuous doping of C with BN, or vice versa, proceeds relatively easily due to the isostructural nature of layered C and BN materials.In this article, recent progress in the synthesis, microscopic analysis, and electrical property measurements of a variety of compound nanotubes in the ceramic B-C-N system is documented and discussed.
The RABiTS Approach: Using Rolling-Assisted Biaxially Textured Substrates for High-Performance YBCO Superconductors
Authors: Goyal Amit , Paranthaman M. Parans , Schoop U. 
Published: February 2011

AbstractThis article provides an overview of the fabrication of epitaxial, biaxially aligned buffer layers on rolling-assisted biaxially textured substrates (RABiTS) as templates for YBCO films carrying high critical current densities.The RABiTS technique uses standard thermomechanical processing to obtain long lengths of flexible, biaxially oriented substrates with smooth surfaces.The strong biaxial texture of the metal is conferred to the superconductor by the deposition of intermediate metal and/or oxide layers that serve both as a chemical and a structural buffer.Epitaxial YBCO films with critical current densities exceeding 3 106A/cm2at 77K in self-field have been grown on RABiTS using a variety of techniques and demonstrate magnetic-field-dependent critical current values that are similar to those of epitaxial films on single-crystal ceramic substrates.The RABiTS architecture most commonly used consists of a CeO2(sputtered)/YSZ (sputtered)/Y203(e-beam)/Ni-W alloy.The desired texture of the base metal has been achieved in 100 m lengths and 10cm widths.Scaleable and cost-effective techniques are also being pursued to deposit the epitaxial multilayers.The results discussed here demonstrate that this technique is a viable route for the fabrication of long lengths of high-critical-current-density wire capable of carrying high currents in magnetic fields and at temperatures accessible by cooling with relatively inexpensive liquid nitrogen (up through the 77K range).
Research and Development of Biaxially Textured IBAD-GZO Templates for Coated Superconductors
Authors: Iijima Yasuhiro , Kakimoto Kazuomi , Yamada Yutaka , Izumi Teruo , Saitoh Takashi , Shiohara Yuh 
Published: February 2011

AbstractIon-beam-assisted deposition (IBAD) has been used to prepare biaxially textured templates necessary to realizing high superconducting performance in coated conductors.The IBAD method is characterized by the direct deposition of sharply aligned templates on nontextured metal substrates using fluorite-like oxide films (yttrium-stabilized zirconia, Gd2Zr2O7, etc.).Recent progress in vacuum technology for IBAD has made it possible to reproducibly fabricate long lengths (100 m) of IBAD-GZO templates.Continuous deposition of YBCO films on these templates has been achieved by pulsed laser deposition (PLD).Furthermore, a new approach to improving the texture of IBAD templates was found by using CeO2 films grown by PLD.Trifluoroacetate-based metalorganic deposition has also been used instead of PLD to produce superconducting layers on IBAD buffered tapes, aiming at a low-cost process.This article reviews progress in the research and development of biaxially textured templates produced using IBAD and their subsequent use in fabricating superconducting tapes and wires by means of several processes.
Evaporation-Induced Self-Assembly: Functional Nanostructures Made Easy
Authors: Brinker C. Jeffrey 
Published: February 2011

AbstractThe following article is an edited transcript based on the MRS Medalist presentation given by C. Jeffrey Brinker (Sandia National Laboratories and the University of New Mexico) on December 3, 2003, at the Materials Research Society Fall Meeting in Boston. Brinker received the Medal for “his pioneering application of principles of sol-gel chemistry to the self-assembly of functional nanoscale materials.” Nature combines hard and soft materials, often in hierarchical architectures, to obtain synergistic, optimized properties with proven, complex functionalities. Emulating natural designs in robust engineering materials using efficient processing approaches represents a fundamental challenge to materials chemists. This presentation reviews progress on understanding so-called evaporation-induced silica/surfactant self-assembly (EISA) as a simple, general means of preparing porous thin-film nanostructures. Such porous materials are of interest for membranes, low-dielectric-constant (low-k) insulators, and even ‘“nano-valves” that open and close in response to an external stimulus. EISA can also be used to simultaneously organize hydrophilic and hydrophobic precursors into hybrid nanocomposites that are optically or chemically polymerizable, patternable, or adjustable.
Novel Materials and Applications of Electronic Noses and Tongues
Authors: Gouma Perena , Sberveglieri Giorgio 
Published: February 2011

AbstractThis introductory article describes the content of the October 2004 issue ofMRS Bulletinfocusing on novel materials and applications of electronic noses and tongues.The articles in this issue review the state of the art in materials, devices, and data processing algorithms used in electronic olfaction and taste systems. The most common gas- and liquid-phase analyte detection tools are presented and compared with traditional chemical analysis instrumentation such as gas chromatography/mass spectroscopy systems. Metal oxides, polymer/polymer composites, and dyes are covered in these articles as key sensing materials. Resistive, optical, electrochemical, and other types of electronic nose and tongue systems are reviewed, and their use in diverse applications, including environmental and food-quality monitoring and medical diagnostics, is discussed.
An Optoelectronic Nose:“Seeing” Smells by Means of Colorimetric Sensor Arrays
Authors: Suslick Kenneth S. 
Published: February 2011

AbstractA new approach to general sensors for odors and volatile organic compounds (VOCs) using thin films of chemically responsive dyes as a colorimetric sensor array is described. This optoelectronic “nose,” by using an array of multiple dyes whose colors change based on the full range of intermolecular interactions, provides enormous discriminatory power among odorants in a simple device that can be easily digitally imaged. High sensitivities (ppb) have been demonstrated for the detection of biologically important analytes such as amines, carboxylic acids, and thiols. By the proper choice of dyes and substrate, the array can be made essentially nonresponsive to changes in humidity.
High-Performance Emerging Solid-State Memory Technologies
Authors: Goronkin Herb , Yang Yang 
Published: February 2011

AbstractThis article introduces the November 2004 issue of MRS Bulletin on the state of the art in solid-state memory and storage technologies.The memory business drives hundreds of billions of dollars in sales of electronic equipment per year. The incentive for continuing on the historical track outlined by Moore's law is huge, and this challenge is driving considerable investment from governments around the world as well as in private industry and universities. The problem is this: recognizing that current approaches to semiconductor-based memory are limited, what new technologies can be introduced to continue or even accelerate the pace of complexity? The articles in this issue highlight several commercially available memories, as well as memory technologies that are still in the research and development stages. What will become apparent to the reader is the huge diversity of approaches to this problem.
Overview of Phase-Change Chalcogenide Nonvolatile Memory Technology
Authors: Hudgens S. , Johnson B. 
Published: February 2011

AbstractPhase-change nonvolatile semiconductor memory technology is based on an electrically initiated, reversible rapid amorphous-to-crystalline phase-change process in multicomponent chalcogenide alloy materials similar to those used in rewriteable optical disks. Long cycle life, low programming energy, and excellent scaling characteristics are advantages that make phase-change semiconductor memory a promising candidate to replace flash memory in future applications. Phase-change technology is being commercialized by a number of semiconductor manufacturers. Fundamental processes in phase-change semiconductor memory devices, device performance characteristics, and progress toward commercialization of the technology are reviewed.
The Influence of Order on the Nucleation Barrier
Authors: Kelton K.F. , Greer A.L. , Herlach D.M. , Holland-Moritz D. 
Published: February 2011

AbstractWhile it is conventionally thought that liquids turn to solids at their “freezing” point, it is often the case that materials must be supercooled (cooled below the freezing temperature) before nucleation actually happens. There is growing evidence that coupled processes, including chemical–structural ordering and orientational–translational ordering, are among the factors that affect exactly when and how nucleation occurs in liquids and crystals. Recent density functional calculations have demonstrated that such coupled routes, which are not incorporated within the one-dimensional framework of the classical theory, can dramatically influence the overall nucleation process. Here, some recently observed cases in metal alloys are discussed, establishing a relationship between developing order in undercooled liquids and the nucleation barrier, the influence of magnetic ordering on nucleation in Co-based melts, and the role of interfacial structure and chemistry on the catalytic efficiency of inoculants for heterogeneous nucleation.
In Situ Transmission Electron Microscopy Studies of the Solid–Liquid Interface
Authors: Howe James M. , Saka Hiroyasu 
Published: February 2011

AbstractIn situtransmission electron microscopy (TEM) studies allow one to determine the structure, chemistry, and kinetic behavior of solid–liquid (S–L) interfaces with subnanometer spatial resolution. This article illustrates some important contributions ofin situTEM to our understanding of S–L interfaces in Al-Si alloys and liquid In particles in Al and Fe matrices.Four main areas are discussed:ordering in the liquid at a S–L interface, compositional changes across the interface, the kinetics and mechanisms of interface migration, and the contact angles and equilibrium melting temperature of small particles.Results from these studies reveal that (1)partially ordered layers form in the liquid at a Si{111} S–L interface in an Al–Si alloy, (2)the crystalline and compositional changes occur simultaneously across an Al S–L interface, (3)the Al interface is diffuse and its growth can be followed at velocities of a fewnm/s at extremely low undercoolings, and (4)the melting temperature of In particles less than ~ 10 nm in diameter can be raised or lowered in Al or Fe, depending on the contact angle that the S–L interface makes at the three-phase junction. These results illustrate the benefits of in situ TEM for providing fundamental insight into the mechanisms that control the behavior of S–L interfaces in materials.