bluuebunny/crossref_metadata_2025_split huggingface dataset:
Reviews and syntheses: Potential and limitations of oceanic carbon dioxide storage via reactor-based accelerated weathering of limestone
Authors: Huysmans Tom , Meysman Filip J. R. , van de Velde Sebastiaan J. 
Published: February 2025

Abstract. To achieve climate stabilization, substantial emission reductions are needed. Emissions from industrial point sources can be reduced by applying carbon capture and storage (CCS) methods, which capture carbon dioxide (CO2) before it is released to the atmosphere. CCS applications typically target CO2 storage within geological reservoirs. Accelerated weathering of limestone (AWL) provides an alternative CCS approach, in which CO2 is stored as dissolved inorganic carbon in the ocean. At present, AWL technology remains at the pilot scale with no industrial implementation. Here, we review the proposed reactor designs for AWL, comparing them in terms of CO2 capture efficiency, CaCO3 dissolution efficiency, CO2 sequestration efficiency, and water usage. For this, we represent AWL as a four step process: (i) CO2 dissolution, (ii) CaCO3 dissolution, (iii) alkalinization (step only included in the case of buffered AWL), and lastly (iv) re-equilibration. AWL application is generally characterized by a large water usage and the need for large reactor sizes. Unbuffered AWL approaches show substantial degassing of CO2 back to the atmosphere after the process water is discharged. Buffered AWL compensates the unreacted CO2 by Ca(OH)2 addition, and hence prevents degassing, which substantially increases the CO2 sequestration efficiency. Yet, buffered AWL require a source of CO2-neutral Ca(OH)2. The need for process water can be reduced by increasing the CO2 fraction of the gas stream or increasing its pressure. Further optimization of the pulverized carbonate particles could reduce the amount of Ca(OH)2 needed to buffer the unreacted CO2. The anticipated CO2 sequestration efficiency of buffered AWL is comparable with that projected for large-scale CCS in geological reservoirs.
Analisis Prestasi SMA atau SMK Negeri di Bidang Ekstrakurikuler Futsal
Authors: Musthofa Ah. Ainul , Setyowati Sri , Widyana Ima , Khamidi Amrozi , Amalia Kaniati 
Published: February 2025

Penelitian ini bertujuan untuk mengetahui prestasi ekstrakurikuler futsal. Metode yang digunakan adalah metode penelitian deskriptif. Subjek penelitian adalah 9 Sekolah Menengah Atas atau Sekolah Menengah Kejuruan di Kota Gresik. Instrumen dari penelitian ini yaitu Observasi, Kuesioner, dan Dokumentasi. Hasil penelitian menunjukuan persentase perkembangan ekstrakurikuler futsal ditingkat SMAN atau SMKN Kota Gresik berkembang 5 sekolah 55,55%, belum berkembang 4 sekolah 44,44%. Setelah mendapatkan persenan data maka dapat perbandingan perkembangan ekstrakurikuler futsal ditingkat SMAN atau SMKN kota Gresik 5:4, adalah berkembang. Berdasarkan perolehan data perkembangan estrakurikuler futsal ditingkat SMAN atau SMKN Kota Gresik harus memperhatikan indikator yang baik seperti pelatih berkompeten, manajemen yang baik, fasilitas, metode latihan dan prestasi. Maka hasil data diperoleh dari sembilan sekolah ada 5 sekolah yang memiliki indikator yang baik. Sedangkan 4 sekolah dinyatakan belum ada perkembangan terlihat dari indikator yang belum memenuhi proses menunjangnya perkembangan ekstrakurikuler futsal.
Voor risico van de ondernemer
Authors: Tjong Tjin Tai T.F.E. 
Published: February 2025

Voor risico van de ondernemer. Bespreking van het proefschrift van mr. T.E. de Wijkerslooth-van der Linden
Het hier gerecenseerde proefschrift handelt over de invloed van de hoedanigheid van de ondernemer-rechtspersoon op foutaansprakelijkheid. Het gaat na langs welke dogmatische constructies de rechtspersoon als dader kan worden aangemerkt, en in hoeverre de elementen van aansprakelijkheid worden beïnvloed door de hoedanigheid van ondernemer.
Munvårdssystemen för sköra äldre – så kan de förbättras
Authors: Wårdh Inger , Komulainen Kaija , Ekstrand Kim , Pétursdóttir Helga , Hove Lene Hystad 
Published: February 2025

English summary
Nor Tannlegeforen Tid. 2025; 135: 100-6.
Background – The fraction of frail older individuals will increase significantly in the years to come in all Nordic countries (NC).
Aims – To describe the oral care systems (OCS) for frail older individuals in the different NC, strengths and weaknesses related to this systems and some general activities to improve the oral care.
Results – All NC have OCS for frail inhabitants but the individual cost of the OCS differs between the countries. The OCS are in short divided into a) dental professional care and b) help with daily oral hygiene performed by the care staff. The authors suggest 10 initiatives related to a or b or to a and b at the same time, which could improve the level of oral care for our frail older population.
Conclusion – There are challenges that reduce the effectiveness of the OCS for frail individuals in all NC. Most important are shortage of both prevention and treatment offered by the dental professionals, most often related to lack of contact between them and the frail older individuals as well as the level and insufficient support in daily oral hygiene by the care staff.
Electric powered toothbrush vs manual – which is more efficient?
Authors: Väyrynen Elina , Damgaard Christian , Almståhl Annica 
Published: February 2025

Headlines
For healthy subjects, electric powered toothbrushes are more effective than manual toothbrushes in plaque removal and reduction of gingival inflammation.
Electric powered toothbrushes are more effective than manual for children, and for a- dolescents with fixed orthodontics.
For persons with physical or intellectual disabilities powered and manual toothbrushes are equally effective.
For patients with periodontitis, implants, and caries there are few studies comparing the efficacy of electric powered versus manual toothbrushes.
THE ROLE OF AI IN PREDICTING MENTAL HEALTH DISORDERS: A CLINICAL PSYCHOLOGY PERSPECTIVE
Authors: Dr U.G.Lashari  , Somia Shabbir  , Dr Tazeem Shahbaz  , Hajra Waheed kayani  
Published: February 2025

Introduction/Importance of Study: Artificial Intelligence (AI) has recently become a powerful tool for different disciplines including healthcare. One of the new possibilities it opens up in clinical psychology is its ability to forecast mental health disorders. This paper aims to discover the healthcare professionals, artificial intelligence specialists, and psychologists’ perceptions about the use of AI in the forecast of mental health disorders.
Novelty Statement: This study aims to evaluate the current EU professional awareness, efficacy impression, and ethical and regulatory standpoint required for AI application on mental health prediction forecasts efficiently in a quantitative manner.
Material and Methods: The study design employed was cross-sectional in nature and data was gathered from 250 professionals with the use of a structured questionnaire instrument. The survey included questions about participants’ awareness of AI, its efficiency in their workplaces, their concerns about privacy and ethical issues as well as their opinion about strict regulation in this sphere. Data analysis tools that were used included descriptive statistics, correlation analysis as well as regression models.
Results and Discussion: A moderate level of awareness of AI is realized through low awareness of AI in mental health. A total of 11 participants were interviewed, self has been noted to have positive views about the use of AI but there is concern about privacy, trust, and the ethical use of artificial intelligence in diagnosing mental health disorders. A majority viewed that regulation on the use of AI in this area should be enhanced. What these results indicate is that although there might be numerous possibilities for having AI, there are crucial areas of concern in terms of trust, privacy, and accuracy.
Conclusion: The integration of AI into mental health has the benefit of reaching a large number of people, yet, the barriers need to be resolved, in terms of ethical issues, implementation of a clearer and transparent approach to be established, and trust from mental health professionals.
SQL: MA'LUMOTLAR BAZASI XAVFSIZLIGINI BOSHQARISH
Authors: Yo’ldoshev Ramazon Shokir o’g’li 
Published: February 2025

Ushbu maqolada Axborot tizimlari va texnalogiyalarini takomillashtirish va ma’lumotlarning xavfsizligini ta’minlash tog’risida tahlil qilinadi. Shu bilan birga foydalanuvchilarning ma’lumotlar bazasi xavfsizligini boshqarish, takomillashtirish va himoya qilish muhokama qilinadi.Tavsiyalar va Xulosa qismida Ma’lumotlar bazasini xavfsizligini boshqarish bo’yicha zarur chora tadbirlar taklif qilinadi.
Education as Morals in Dewey’s Philosophy
Authors: Friedman Robin 
Published: February 2025

This article explores Dewey's understanding of the nature of education through three seminal works written over a 32-year period. In Democracy and Education (1916) Dewey developed a concept of education which can be understood through two German words for education, Erziehung and Bildung. Through considering the approach to these concepts by two Dewey scholars, Gert Biesta and Dietrich Benner, the first section of this article seeks to explore Dewey's understanding of education and its relationship to democracy. The second section of the article carries the study forward to Dewey's Human Nature and Conduct (1922) to show how Dewey conceived of education even more broadly and equated it with morals. The concepts of Erziehung and Bildung also are important in this section, as they are expanded to show that, for Dewey, education was a guide in how to live. The third section of the article expands the concept of education still further to view education as philosophy. This section discusses Dewey's book Experience and Education (1938) which he wrote in light of his metaphysical study Experience and Nature (1925). Dewey expanded his understanding of education beyond both Erziehung and Bildung and beyond morals to develop an understanding of education as based upon a philosophical consideration of experience. The goal of the article is to show the breadth of Dewey's understanding of education and to show how his view of education forms the basis of a broad philosophical view of life.
Peculiarities of parental education in Russia (USSR) (1980s to present time): historical and pedagogical analysis
Authors: Chik Sergey 
Published: February 2025

The subject of the research is the pedagogical education of parents in Russia (USSR) (1980s to present time). The purpose of the article is to present in chronological order the main pedagogically significant events and facts, to identify key ideas and features of the implementation of pedagogical education of parents in different periods. There are three periods of parents education: the Soviet (from the 1980s to 1991), the post–Soviet (1992 - the end of the 2010s) and the modern (the end of 2010 to the present time). It is shown that the pedagogical education of parents in Russia has evolved from pedagogical universal education, popularization of Westernization, opposition to Westernization and traditional approaches, to familiarization with traditional Russian spiritual and moral values. Research methods: theoretical analysis of sources, comparative analysis, generalization. Research sources: normative legal acts in the field of education, upbringing, and the development of family relations, the works of teachers, psychologists, and publicists, the journal for parents "Family and School." During the Soviet period, official pedagogical universal education with a formal approach and party postulates, and separate practices based on Western ideas (attention to the feelings of the parent and positive child-parent communication) coexisted. The specific psychological and pedagogical knowledge needed by the parent did not fit well with the communist ideology. Testing and adapting Western ideas to the Soviet reality was difficult. In the post-Soviet period, educational programs implemented in schools and social protection institutions rely mainly on a traditional approach with a passive and often indifferent parent, but influencing the child. Western practices have not been fully understood and accepted by educators and psychologists. The modern period is characterized by the development of unified methodological and substantive approaches: the All-Russian conferences on family education and parental education "School of Gifted Parents" are held annually, the All-Russian competition of best practices in parental education, a project is being implemented in all regions of Russia to provide psychological, pedagogical, methodological and counseling services to parents, university psychological services are being created that provide psychological education of parents. Information and methodological support are being created, unified education programs for parents and specialists are being developed.
Proteomics of stress-induced cardiomyopathy: insights from differential expression, protein interaction networks, and functional pathway enrichment in an isoproterenol-induced TTC mouse model
Authors: Tian Liuyang , Liu Botao , Ren Ying , Cui Jian , Pang Zhihua 
Published: February 2025

Backgrounds
Takotsubo cardiomyopathy (TTC), also known as stress-induced cardiomyopathy, is a condition characterized by transient left ventricular dysfunction without coronary artery obstruction.

Methods
We utilized label-free quantitative proteomics to analyze protein expression in a murine model of TTC, induced by a high dose of isoproterenol (ISO) injection.

Results
We found that a single high dose of ISO injection in mice could induce stress-related cardiac dysfunction.The proteomic analysis revealed 81 differentially expressed proteins (DEPs) between the ISO and control groups—39 were upregulated, and 42 were downregulated. Key pathways enriched by Gene Ontology (GO) analysis included collagen fibril organization, cholesterol biosynthesis, and elastic fiber assembly. Kyoto Encyclopedia of Genes and Genomes (KEGG) pathway enrichment indicated significant changes in unsaturated fatty acid biosynthesis, glutathione metabolism, steroid biosynthesis, and ferroptosis. Key hub proteins identified by the protein-protein interaction (PPI) network included Ntrk2, Fdft1, Serpine1, and Cyp1a1. Gene set enrichment analysis (GSEA) showed upregulation in terpenoid backbone biosynthesis, oxidative phosphorylation, and ferroptosis, with downregulation in pathways such as systemic lupus erythematosus and Rap1 signaling.

Conclusions
This study employed high-throughput liquid chromatography-tandem mass spectrometry (LC-MS/MS) to identify key proteins associated with energy metabolism, oxidative stress, inflammation, and cell death in TTC. These findings provide new insights into the molecular mechanisms of stress-induced myocardial injury and may offer potential therapeutic targets for mitigating cardiovascular damage under stress conditions.
The Minimum Reduced Sombor Index of Unicyclic Graphs in Terms of the Girth
Authors: Nagarajan S. , Aswini B. 
Published: February 2025

Aims: The paper investigates the Reduced Sombor Index () for unicyclic graphs. Specifically, it aims to determine and characterize the unicyclic graphs that attain the minimum index among all unicyclic graphs of a given order.
Study Design: This is a theoretical mathematical study based on graph theory and topological indices. The study involves defining and analyzing the Reduced Sombor Index by comparing values across different unicyclic graphs. Lemmas and theorems are proved to establish the minimum index graph.
Methodology: Several graph transformation operations are analyzed. The study proves multiple lemmas that compare values before and after transformations by demonstrating whether a specific structural modification increases or decreases the value.
Results: The minimum value in unicyclic graphs is achieved only by cycle graphs. Several lemmas prove that adding pendant vertices or modifying graph structure increases RSO. The final theorem establishes that for any unicyclic graph of order n, with equality if and only if G is a cycle .
Conclusion: The study successfully characterizes unicyclic graphs with the minimum Reduced Sombor Index ). It establishes that cyclic graphs are the unique minimizers of the index among unicyclic graphs. Any structural modification leading to non-cycle unicyclic graphs increases . The findings contribute to chemical graph theory by refining how topological indices behave in molecular graph models.
Kevlar Aerogel‐Confined Functional Liquid‐Based Composite Membrane Enables Dynamic Uranium Capture
Authors: Sheng Zhizhi , Sun Ying , Hou Yinglai , Liu Zengwei , Lyu Jing , Li Lishan , Fan Zhaochuan , Zhang Xuetong 
Published: June 2024

AbstractSolid–liquid composite materials that confine a functional liquid within a porous solid have appeared in a wealth of emerging applications. However, creating dynamic liquid interfaces for efficient ion capture while stably retaining functional liquid in porous confinements is challenging. Here, an aerogel‐confined liquid‐based composite membrane (ALCM) for dynamic and highly efficient uranium capture is reported. As a proof of concept, Kevlar aerogel membrane is selected as the nanoporous solid, and calix[6]arene/tributyl phosphate (C6/TBP) is used as the guest liquid. The obtained ALCMs possess high stability, optimum adhesion between solid‐liquid interface, and high selectivity for uranyl ions (250–6510 times over other competing ions). Different dynamic interface regulating approaches are explored for ALCMs, and uranium extraction efficiency under alternating pressures can be up to 258.48 mg g−1 h−1, outperforming many reported uranium capture materials. This strategy can be applicable to develop a rich family of solid‐liquid composite materials and may spearhead a new paradigm for uranium capture from sustainable seawater resources.
Ag/AgCl‐Like Photogating of a COF‐on‐MOF Heterojunction in Organic Photoelectrochemical Transistor
Authors: Wang Zhen , Shi Xiao‐Mei , Chen Feng‐Zao , Fan Gao‐Chao , Zhao Wei‐Wei 
Published: June 2024

AbstractThe pursuit of high on‐to‐off ratio (IOn/IOff), as one of the important performances for organic electrochemical transistor (OECT) has been ongoing, but to date, limited solutions are available. The interaction between light and matter has been demonstrated as a rich source for advanced electronic applications. However, its potential in IOn/IOff modulation has not been fully explored. Herein, the challenge is addressed through the unique light‐material interplay, which is represented by organic photoelectrochemical transistor (OPECT) gated by photosensitive COF‐LZU1 on mixed‐ligand MOF (COF‐on‐MOF) upon appropriate exposure illumination. Notably, the interplay between light and COF‐on‐MOF can adjust the device physics, optimizing the IOn/IOff to its maximum and enhancing signal transduction. Toward bio‐application, via exonuclease‐assisted cyclic cleavage amplification and hybridization chain reaction, such a device is validated for highly sensitive detection capabilities for human T‐cell lymphotropic virus type II (HTLV‐II) DNA down to 0.003 fM. This study features the possibility of Ag/AgCl‐like photogating of organic transistors via light‐matter interplay.
Rapid Hole Generation via D–A Structure‐Dependent Built‐In Electric Field of Deacetylated Chitin‐PDI for Efficient Photocatalytic Oxidation
Authors: Shang Yaxin , Li Wenting , Ma Yuqing , Li Beibei , Xu Qing , Du Yan , Peng Yongzhen , Wang Yifei , Zhu Yongfa 
Published: June 2024

AbstractBreaking the trade‐off between broad spectrum response and efficient charge separation is a major challenge in the photocatalysis. Unlike the conventional practice of suppressing charge separation when shrinking the bandgap, a series of deacetylated chitin‐perylene diimide (DC‐PDI) donor–acceptor (D–A) photocatalysts is proposed with tunable charge distribution by modulating the C─N covalent bond content, expanding the spectral absorption range as the expanded D–A. The enlarged D–A structure achieves efficient photogenerated electron–hole separation by increasing the charge of the positive and negative charge centers, inducing larger dipole moments, generating 4.7 times higher built‐in electric field, and reducing the charge transfer barrier. Among them, the optimum DC/PDI (2:1) with enlarged D–A enables to capture the largest number of electrons for persulfate activation, and concurrently affords the highest hole generation efficiency with the deepest valence band (1.67 V). Such merits contribute to 1.2–2.8 times higher degradation rate and 1.1–1.6 times higher mineralization rate of organic pollutants in comparison with other counterparts. The mineralization rate can reach 100% in the engineered microreactor setup. This study elucidates the structure‐mechanism‐performance relationship of D–A modulation and charge separation/transport, guiding the rational molecular structure design for efficient photocatalytic oxidation.
Microenvironment‐Responsive Targeted Nanomedicine for a Collaborative Integration of Tumor Theranostics and Bone Defect Repair
Authors: Wang Wenxuan , Kang Weiwei , Zhang Xin , Zheng Xiaochun , Jin Yarong , Ma Zhuo , Wang Yuhang , Dai Rong , Ma Xun , Zheng Ziliang , Zhang Ruiping 
Published: June 2024

AbstractDespite advancements in breast cancer treatment, bone metastases remain a significant concern for advanced breast cancer patients. Current theranostics strategies face challenges in integrating tumor theranostics and bone formation. Herein, this work develops an activatable targeted nanomedicine AuMnCO@BSA‐N3 (AMCBN) to enable a novel collaborative integration of second near‐infrared (NIR‐II) fluorescence imaging guided precise theranostics for breast cancer bone metastases and osteogenic microenvironment remolding. This strategy employs a chemical coordination between noble metal complex and metal carbonyl (MnCO), with surface modification of azide groups to enhance tumor affinity through passive and active targeting. The initiated respondent behavior of AMCBN by tumor microenvironment accelerate the degradation of coordinated MnCO, resulting in a rapid release of multifunctional agents for efficient chemodynamic therapy (CDT)/gas synergistic therapy. Meanwhile, the exceptional bone‐binding properties enable the efficient and controlled release of Mn2+ ions and carbon monoxide (CO) in the bone microenvironment, thereby facilitating the expression of osteogenesis‐related proteins and establishing a novel synchronous theranostics process for tumor‐bone repair.
Rational Design of NIR‐II Emitting Conjugated Polymer Derived Nanoparticles for Image‐Guided Cancer Interventions
Authors: Gill Nikita , Srivastava Indrajit , Tropp Joshua 
Published: June 2024

AbstractDue to the reduced absorption, light scattering, and tissue autofluorescence in the NIR‐II (1000–1700 nm) region, significant efforts are underway to explore diverse material platforms for in vivo fluorescence imaging, particularly for cancer diagnostics and image‐guided interventions. Of the reported imaging agents, nanoparticles derived from conjugated polymers (CPNs) offer unique advantages to alternative materials including biocompatibility, remarkable absorption cross‐sections, exceptional photostability, and tunable emission behavior independent of cell labeling functionalities. Herein, the current state of NIR‐II emitting CPNs are summarized and structure–function–property relationships are highlighted that can be used to elevate the performance of next‐generation CPNs. Methods for particle processing and incorporating cancer targeting modalities are discussed, as well as detailed characterization methods to improve interlaboratory comparisons of novel materials. Contemporary methods to specifically apply CPNs for cancer diagnostics and therapies are then highlighted. This review not only summarizes the current state of the field, but offers future directions and provides clarity to the advantages of CPNs over other classes of imaging agents.