bluuebunny/crossref_metadata_2025_split huggingface dataset:
Unveiling the impact of corporate humanistic responsibility on sustainable employee well‐being: Exploring perceived support and shared experiences
Authors: Koon Vui‐Yee 
Published: May 2024

AbstractThe significance of employee well‐being within corporate social responsibility (CSR) is widely acknowledged. However, while CSR often emphasizes its societal dimension, its humanistic aspect frequently remains in the background, with limited exploration of its connection to employee well‐being from this perspective. This study seeks to fill this gap by examining the role of corporate humanistic responsibility (CHR) in enhancing employee well‐being, focusing on its influence through perceived organizational support (POS) and homogeneous experiences (HEs), employing an emerging‐enabling process approach. Data were gathered from 236 employees across 70 multinational corporations through a two‐time point survey. The findings indicate that both POS and HE positively mediate the relationship between CHR, life well‐being, and psychological well‐being. However, the sequential mediation did not yield significant impacts on workplace well‐being. The study concludes by discussing the findings, theoretical and practical implications, limitations, and future studies. Through this exploration, a deeper understanding of how CHR can enhance employee well‐being from a humanistic perspective is attained, offering valuable insights for academia and corporate sustainability endeavors.
An MRI study demonstrating consistent anatomic relation of central longitudinal artery and associated periosteal vessels with the medial femoral epicondyle and adductor tubercle—A visual landmark method for femoral tunnel placement in medial patellofemoral ligament reconstruction
Authors: Mandalia Vipul , Anaspure Rahul , Aboelmagd Sharief , Powell Roy , Manning William 
Published: May 2024

AbstractThe two most common techniques to determine femoral tunnel placement during medial patellofemoral ligament (MPFL) reconstruction are radiographic and by palpation. Their intra/interobserver reliability is widely debated. Both techniques rely on identifying bony landmarks such as the medial epicondyle (ME) and adductor tubercle (AT) during surgery. During MPFL reconstructive surgery, the central longitudinal vessels (CLVs) are seen consistently. The aim of this study was to investigate the anatomic relationship of CLV to ME and AT and to determine if CLV might be used as a landmark during MPFL reconstruction. A retrospective review of MRI scans in skeletally mature patients was undertake. There were two groups, a PFI group that consisted of patients with a diagnosis of patellofemoral instabiliy (PFI) and a non‐PFI group that underwent MRI scan for an alternative diagnosis. MRIs were measured for the CLV‐ME‐AT anatomy and relationship. Following exclusions, 50 patients were identified in each group. The CLV passed anterior to the AT and ME in all patients. ME morphology did not differ greatly between the groups except in the tubercle height, where there was statistically significant but not a clinically important difference (larger in the non‐PFI group, 2.95 vs. 2.52 mm, p = 0.002). The CLV to ME tip distance was consistent between the groups (PFI group 3.8 mm and non‐PFI group 3.9 mm). The CLV‐ME‐AT relationship remained consistent irrespective of patients' presenting pathology. The CLV consistently courses anterior to ME and AT. The CLV could be used as a vascular landmark assisting femoral tunnel placement during MPFL reconstruction.
Purchase spillovers from the metaverse to the real world: The roles of social presence, trialability, and customer experience
Authors: Mansoor Shafayet , Rahman Syed Mahmudur , Bowden Jana Lay‐Hwa 
Published: May 2024

AbstractThe promise of the metaverse as a collective, virtual, and shared social space is revolutionizing digital retail. This study provides groundbreaking insights into customer experience in immersive metaverse environments, as well as into how these experiences on metaverse platforms influence customers' real‐world consumption behaviors. Drawing upon data from metaverse platform users in the US, this study identifies the specific antecedents of a positive customer experience on metaverse platforms, including the role of social presence and trialability. Further, it demonstrates the potential for purchase spillovers from the metaverse to traditional retail channels, extending the omnichannel retail literature. In addition, it examines how early‐stage versus long‐term users of the metaverse shape users' intentions to revisit metaverse platforms. Based on our results, we offer a comprehensive model of customers' metaverse behaviors, which may be used to predict and enhance customers' purchase intentions across channels. Our results also demonstrate that the metaverse is not merely a parallel digital retail channel but instead an influential extension of the customers' real‐world consumption. From a managerial perspective, we offer metaverse operators and retail brand managers insights into how an engaging and immersive customer experience in the metaverse can be developed to support metaverse platform growth, and targeted brand strategies that translate into real‐world gain for both the brand and the customer. The findings suggest that metaverse platforms must deliver customer experiences at a very high level to prevent stagnation in metaverse usage intentions; therefore, managers can confidently continue investing in relevant strategies to fuel metaverse platform growth.
Chemical Composition of Extracts and Fractions from Miconia Ibaguensis (Melastomataceae) Leaves and Evaluation of Biological Activities
Authors: Sehnem Gabriela S. , Silva Julia A. , da C. Silva Tiara , Prado Diego G. , Santiago Mariana B. , O. Santos Anna Lívia , Martins Mário M. , Cunha Luis C. S. , Sousa Raquel M. F. , Romero Rosana , Bittar Vinicius P. , Borges Ana Luiza S. , Martins Carlos H. G. , Espindola Foued S. , de Oliveira Alberto 
Published: May 2024

AbstractThe study aimed to assess the chemical composition of Miconia ibaguensis leaves extracts and fractions obtained from the ethanolic extract (EE), along with evaluating their antifungal, antibacterial, antidiabetic, and antioxidant activities. The ethyl acetate fraction (EAF) exhibited potent antifungal activity against Candida spp (1.95–3.90 μg mL−1) and potent antioxidant activity in the DPPH (1.74±0.07 μg mL−1), FRAP (654.01±42.09 μmol ETrolox/gsample), and ORAC (3698.88±37.28 μmol ETrolox/gsample) methods. The EE displayed inhibition against the α‐amylase enzyme (8.42±0.05 μg mL−1). Flavonoids, hydrolysable tannins, triterpenoids, and phenolic acids, identified in the EE and fractions via (−)‐HPLC‐ESI‐MS/MS analysis, were found to contribute to the species′ biological activity potentially. These findings suggest promising avenues for further research and potential applications in pharmacology and natural products, offering new possibilities in the fight against global health issues.
A case of IgA pemphigus, with a poor response to dapsone, successfully treated with adalimumab
Authors: Al‐Zahawi Saman , Kamyab Kambiz , Balighi Kamran 
Published: May 2024

Key Clinical MessageIgA pemphigus is usually treated by Dapsone. Recalcitrant cases may be treated by Colchicine, Sulfapyridine, or Acitretin. Some patients with recurrent severe disease may not respond to the aforementioned medications. Our study highlights the role of TNFa inhibitor as an alternative modality in the treatment of recalcitrant IgA pemphigus.AbstractIgA pemphigus is a rare autoimmune blistering disease characterized by a pruritic, annular, vesiculopustular eruption. In IgA pemphigus, there are IgA autoantibodies targeting the keratinocyte cell surface adhesion molecules, causing cell‐to‐cell dehiscence and a flaccid vesiculopustular eruption, mainly in the axilla and groin. Dapsone, despite being the drug of choice for treating IgA pemphigus, is not effective in clearing lesions in a minority of patients and such rare cases of recalcitrant IgA pemphigus need alternative modalities of treatment. Here, we report the successful treatment of a 50‐year‐old male patient with an adalimumab injection who had a poor response to dapsone.
Fluorescent Composite Nano‐ and Microparticles Based on Xanthene Dyes and Iron Oxides
Authors: Muradova Aytan G. , Al‐Hilali Hasan A. , Andreeva Polina A. , Sharapaev Alexander I. , Khakimov Karim T. , Bai Xiumei , Finko Alexander V. 
Published: May 2024

AbstractModern industry actively uses metal structural materials to create innovative devices and components. In order to prevent emergency situations in production, nondestructive testing methods are used to detect defects on the surface of the material being developed. Among the methods of nondestructive testing, one can highlight the method of luminescent magnetic flaw detection, which allows identifying defects on the surface and under the surface of the test sample with minimal effort. It is known that in some cases, the magnetic‐powder method cannot achieve the required sensitivity due to the shape and location of defects themselves or due to certain conditions of object operation. To increase the visibility and sensitivity, magnetic nano‐ and microparticles can be conjugated with the dyes. Iron oxide nanoparticles (Fe3O4, γ‐Fe2O3) can be used as such magnetic particles, since they are quite easy to obtain and have low toxicity, high chemical stability, and a wide variety of magnetic properties. To ensure fluorescence of magnetic particles, a wide variety of fluorescent dyes associated with such particles are used. The dyes can include morin, naphthalimide derivatives, as well as semiconductor quantum dots. This article provides a review of fluorescent composite micro‐ and nanoparticles based on xanthene dyes (rhodamine, fluorescein, and pyronine). Such dyes are economically available luminophores, have good binding to the surface of magnetic particles, and therefore can be suitable for luminescent magnetic flaw detection. This review article discusses methods for producing composite nano‐ and microparticles of iron oxides with xanthene dyes and provides prospects of using composite nano‐ and microparticles in nondestructive testing methods.
A survey of ethofumesate resistant annual bluegrass (Poa annua) on US golf courses
Authors: Vukovic Vera , Mattox Clint M. , Kowalewski Alec R. , McNally Brandon C. , McElroy J. Scott , Patton Aaron J. 
Published: May 2024

AbstractAnnual bluegrass (Poa annuaL.) is the most troublesome weed on golf courses in the US. Many agronomic practices intended to promote high‐quality playing surfaces favor the growth and development of annual bluegrass, resulting in high weed pressure. One commonly used herbicide for annual bluegrass control on golf courses is ethofumesate, which is a very long chain fatty acid inhibitor. Annual bluegrass resistance to this herbicide is documented and confirmed in grass seed production systems, but potential resistance on golf courses was previously unknown. The objective of this study was to determine the frequency and magnitude of potential ethofumesate resistance from a sample of US golf courses. A dose‐response experiment was initiated at Purdue University using 30 annual bluegrass populations collected from Alabama, California, Indiana, and Oregon golf courses. Ten ethofumesate doses included 0, 0.5, 1.0, 2.5, 5.0, 7.5, 10.0, 15.0, 20.0, and 40.0 lb a.i. acre−1, with 1.0 to 2.0 a.i. acre−1as the standard label application rate for perennial ryegrass turf. A low level of resistance (R/S < 3) was found in several populations collected in each state. The mean effective dose necessary to kill 50% of the populations (ED50) was 5.1, 9.2, 3.5, and 3.4 lb a.i. acre−1for populations from Alabama, California, Indiana, and Oregon, respectively. The most resistant population originated from California, with an ED50of 13.2 lb a.i. acre−1. To reduce selection pressure from ethofumesate populations, golf course superintendents are encouraged to develop site‐specific weed control programs that rotate herbicide sites of action, as well as utilize diverse control tactics.
Mechanical Bond Induced Enhancement and Purification of Pyrene Emission in the Solid State
Authors: Zhang Shu , Zhou Ru , Zhang Ningjin , An Yi , Liu Zhiyang , Chen Xu‐Man , Li Quan 
Published: May 2024

AbstractTo address key concerns on solid‐state pyrene‐based luminescent materials, we propose a novel and efficient mechanical bond strategy. This strategy results in a transformation from ACQ to AIE effect and a remarkable enhancement of pyrene emission in the solid state. Moreover, an unusual purification of emission is also achieved. Through computational calculation and experimental characterisation, finally determined by X‐ray diffraction analysis, we prove that the excellent emissions result from mechanical bond induced refinement of molecular arrangements, including reduced π‐π stacking, well‐ordered packing and enhanced structural stability. This work demonstrates the potential of mechanical bond in the field of organic luminescent molecules, providing a new avenue for developing high‐performance organic luminescent materials.
Current role of cytopathology in the molecular and computational era: The perspective of young pathologists
Authors: Caputo Alessandro , Pisapia Pasquale , L'Imperio Vincenzo 
Published: May 2024

AbstractCytopathology represents a well established diagnostic approach because of its limited cost, reliability, and minimal invasiveness with respect to other methodologies. The evolving complexity of the different classifications systems and the implementation of ancillary techniques to refine the diagnosis is progressively helping in the risk of malignancy stratification, and the adoption of next‐generation sequencing techniques contributes to enrich this valuable tool with predictive information, which is always more essential in the tailored medicine era. The recent introduction of digital and computational pathology is further boosting the potentialities of cytopathology, aiding in the interpretation of samples to improve the cost effectiveness of large screening programs and the diagnostic efficiency within intermediate/atypical categories. Moreover, the adoption of artificial intelligence tools is promising to complement molecular investigations, representing a stimulating perspective in the cytopathology field. In this work, the authors tried to summarize the multifaceted nature of this complex and evolving field of pathology, synthesizing the most recent advances and providing the young pathologists’ perspective on this fascinating world.
The Heavy Atom Structure, “cis effect” on Methyl Internal Rotation, and 14N Nuclear Quadrupole Coupling of 1‐Cyanopropene from Quantum Chemical and Microwave Spectroscopic Analysis
Authors: Nguyen Truong Anh , Kleiner Isabelle , Schwell Martin , Nguyen Ha Vinh Lam 
Published: May 2024

AbstractThe microwave spectrum of 1‐cyanopropene (crotonitrile) was remeasured using two pulsed molecular jet Fourier transform microwave spectrometers operating from 2.0 to 40.0 GHz. The molecule exists in two isomer forms, E and Z, with respect to the orientation between the methyl and the cyano groups. The spectrum of the Z isomer is more intense. Due to internal rotation of the methyl group, doublets containing A and E torsional species were found for all rotational transitions. Hyperfine splittings arising from the 14N nuclear quadrupole coupling were resolved. The heavy atom structure of the Z isomer was determined by observation of 13C and 15N isotopologue spectra in natural abundances. The experimental results were supported by quantum chemistry. The complex spectral patterns were analyzed and fitted globally, and the barriers to methyl internal rotation are determined to be 478.325(28) cm−1 and 674.632(76) cm−1 for the Z and E isomers, respectively. The non‐bonded intramolecular electrostatic attraction between the methyl group and the 1‐cyano substituent overcomes steric hindrance, leading to higher stability of the Z isomer. The consequence is a slight opening of 3.2° of the C(1)‐C(2)‐C(3) angle and a radical decrease of the methyl torsional barrier in the Z isomer due to steric repulsion.
Gas‐Responsive and Gas‐Releasing Polymer Assemblies
Authors: Yang Cuiqin , Mu Gui‐Fang , Liang Xin , Yan Qiang 
Published: May 2024

AbstractIn order to explore the unique physiological roles of gas signaling molecules and gasotransmitters in vivo, chemists have engineered a variety of gas‐responsive polymers that can monitor their changes in cellular milieu, and gas‐releasing polymers that can orchestrate the release of gases. These have advanced their potential applications in the field of bio‐imaging, nanodelivery, and theranostics. Since these polymers are of different chain structures and properties, the morphology of their assemblies will manifest distinct transitions after responding to gas or releasing gas. In this review, we summarize the fundamental design rationale of gas‐responsive and gas‐releasing polymers in structure and their controlled transition in self‐assembled morphology and function, as well as present some perspectives in this prosperous field. Emerging challenges faced for the future research are also discussed.
Emotional Regulation as a Transdiagnostic Process of Emotional Disorders in Therapy: A Systematic Review and Meta‐Analysis
Authors: Antuña‐Camblor Celia , Gómez‐Salas Francisco J. , Burgos‐Julián Francisco A. , González‐Vázquez Anabel , Juarros‐Basterretxea Joel , Rodríguez‐Díaz Francisco Javier 
Published: May 2024

ABSTRACTContextSeveral studies have shown that emotional regulation (ER) is a transdiagnostic construct of emotional disorders. Therefore, if therapy improves ER, it would improve psychological distress.ObjectiveThis review assesses and compares the changes in ER due to psychological treatment in different therapies.MethodsA systematic review and meta‐analysis of RCTs published in the databases PubMed, PsycINFO and Web of Science was performed. It was registered in PROSPERO under the number CRD42023387317. Two independent experts in the field reviewed the articles.ResultsA total of 18 articles met the criteria for inclusion in the review. Analysis of these studies suggests that in unified protocol (UP), cognitive behaviour therapy, dialectical behaviour therapy (DBT) and mindfulness, there is evidence to support that a moderate effect occurs during treatment. Furthermore, in mindfulness and DBT, the effect was moderate in the follow‐up period, while in UP, it was high.LimitationsGiven the heterogeneity of the applied interventions and the methodological limitations found in the reviewed trials, the results should be interpreted with caution.ConclusionsUP, cognitive behaviour therapy, DBT and mindfulness can improve ER after therapy, while UP, DBT and mindfulness in the follow‐up period. Other therapies, such as SKY or Flotation REST, require more research.
QTL mapping reveals malt barley quality improvement in two dryland environments associated with extended grain fill and seminal root traits
Authors: Williams Jessica L. , Lamb Peggy F. , Lutgen Greg , Lachowiec Jennifer , Cook Jason P. , Jensen Joseph , Bourgault Maryse , Sherman Jamie D. 
Published: May 2024

AbstractTo achieve malt grade and receive full price, barley (Hordeum vulgare L.) crops must meet standards for certain quality traits including percent plump and protein. Terminal drought stress reduces quality and is projected to worsen in barley cultivation areas, underscoring the need for varieties that maintain good malt production with unreliable precipitation. The stay‐green trait extends the grain fill phase between heading and maturity and has been linked to stable quality under dry conditions. However, this relationship can be inconsistent and is not well understood. To effectively leverage a longer grain fill phenotype for drought adaptation, a better grasp of its genetics and environmental interaction is needed. Stay‐green root system differences have been observed and could be at play. We performed correlation and quantitative trait locus (QTL) analysis on grain fill duration, grain quality, and seminal root traits using a recombinant inbred line (RIL) population segregating for stay‐green. Agronomic data were collected in four field trials at two distinct semiarid locations, and roots were measured in a greenhouse assay. Earlier heading and later maturity led to improved quality in both locations and more consistent quality between locations. Earlier heading had a greater influence on quality in the drier environment, while later maturity was more impactful in the less dry environment. We observed co‐locations of seminal root trait QTLs with grain fill duration and grain quality. These QTLs lay the groundwork for further investigation into root phenotypes associated with stay‐green and the deployment of these traits in breeding for drought adaptation.
Barley residue biomass, nutrient content, and relationships with grain yield
Authors: Rogers Christopher W. , Adams Curtis B. , Marshall Juliet M. , Hatzenbuehler Patrick , Thurgood Garrett , Dari Biswanath , Loomis Grant , Tarkalson David D. 
Published: May 2024

AbstractDetermination of barley (Hordeum vulgare L.) nutrient uptake in residue biomass is important for agronomic, economic, and environmental decisions. Improved understanding of grain yield, residue biomass, nutrient uptake, and their relationships are needed. Research determined these factors in 2018 and 2019 from trials of four barley classes (spring animal feed, human food, and malt, as well as winter malt), using three common cultivars of each, at five locations in southern Idaho. Production environment created the largest difference in residue biomass and nutrient uptake. Barley harvest index ranged from 0.46 to 0.52 Mg Mg−1 across feed, food, and malt classes. Compared to previous estimates, nutrient concentrations from the combined dataset were greater than for N, less than for P, and greater than for K. Correlation of grain yields to nutrient uptake (excluding Cu and Fe) had r2 ranging from 0.68 to 0.89. At current prices, economic analysis indicated that fertilizer replacement costs for total residue biomass nutrients were greater than previous estimates and could greatly exceed current sale value. These relationships and value estimates can be used to improve prediction of barley residue biomass production and nutrient uptake to guide best management practices. The decision of how to utilize these metrics (on‐farm, regional, etc.) should be considered based on known variation in measured nutrient and residue data and considered in relation to the proposed task.
Boosting Effect of Sterically Protected Glucosyl Substituents in Formic Acid Dehydrogenation by Iridium(III) 2‐Pyridineamidate Catalysts
Authors: Trotta Caterina , Langellotti Vincenzo , Manco Immacolata , Rodriguez Gabriel Menendez , Rocchigiani Luca , Zuccaccia Cristiano , Ruffo Francesco , Macchioni Alceo 
Published: May 2024

Abstract[Cp*Ir(R‐pica)Cl] (Cp*=pentamethylcyclopentadienyl anion, pica=2‐picolineamidate) complexes bearing carbohydrate substituents on the amide nitrogen atom (R=methyl‐β‐D‐gluco‐pyranosid‐2‐yl, 1; methyl‐3,4,6‐tri‐O‐acetyl‐β‐D‐glucopyranosid‐2‐yl, 2) were tested as catalysts for formic acid dehydrogenation in water. TOFMAX values over 12000 h−1 and 50000 h−1 were achieved at 333 K for 1 and 2, respectively, with TON values over 35000 for both catalysts. Comparison with the simpler cyclohexyl‐substituted analogue (3) indicated that glucosyl‐based complexes are much better performing under the same experimental conditions (TOFMAX=5144 h−1, TON=5000 at pH 2.5 for 3) owing to a lower tendency to isomerize to the less active k2‐N,O isomer upon protonation. The 5‐fold increase in TOFMAX observed for 2 with respect to 1 is reasonably due to an optimal steric protection by the acetyl substituent, which may prevent unproductive inner‐sphere reactivity. These results showcase a powerful strategy for the inhibition of the common deactivation pathways of [Cp*Ir(R‐pica)X] catalysts for FA dehydrogenation, paving the way for the development of better performing hydrogen storage systems.