bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Lanthanide(III) Metal Complexes with Nitrogen Donor Ligands
Authors: Arora Kishor , Burman Kiran 
Published: June 2010

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Spin‐State Changes and Reactivity in Transition Metal Chemistry: Reactivity of Iron Tetracarbonyl
Authors: Besora Maria , Carreon‐Macedo Jose‐Luis , Cimas Alvaro , Harvey Jeremy N. 
Published: June 2010

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Inorganic and Organometallic Polymers
Authors: Gates Derek P. 
Published: June 2010

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Bioorthogonal Chemistry: Recent Progress and Future Directions
Authors: Lim Reyna K. V. , Lin Qing 
Published: June 2010

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Cyclothiomethylation of Primary Amines with Formaldehyde and Hydrogen Sulfide to Nitrogen‐ and Sulfur‐Containing Heterocycles
Authors: Akhmetova V. R. , Nadyrgulova G. R. , Niatshina Z. T. , Dzhemilev U. M. 
Published: June 2010

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: The Lanthanides: Physicochemical Properties Relevant for Their Biomedical Applications
Authors: Sturza Carmen Maria , Boscencu Rica , Nacea Veronica 
Published: June 2010

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Green Organotin Catalysts
Authors: Otera Junzo , Biesemans Monique , Pinoie Vanja , Poelmans Kevin , Willem Rudolph 
Published: June 2010

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Polyfluorinated Organoboron Compounds: Peculiar Reactivity in the Pd‐Catalyzed Cross‐Coupling Reactions
Authors: Adonin Nicolay Yu. , Bardin Vadim V. 
Published: June 2010

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Phenolic Oxidative Coupling in the Biomimetic Synthesis of Heterocyclic Lignans, Neolignans and Related Compounds
Authors: Spatafora Carmela , Tringali Corrado 
Published: June 2010

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Functions Containing a Heteroatom Different from Oxygen
Authors: Albini Angelo , Fasani Elisa 
Published: June 2010

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Fluorous Mixture Synthesis (FMS) of Drug‐Like Molecules and Enantiomers, Stereoisomers, and Analogues of Natural Products
Authors: Zhang Wei 
Published: June 2010

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: gem‐Difluorocyclopropanes as Key Building Blocks for Novel Biologically Active Molecules
Authors: Itoh Toshiyuki 
Published: June 2010

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Direct Azole Amination: C—H Functionalization as a New Approach to Biologically Important Heterocycles
Authors: Armstrong Alan , Collins James C. 
Published: June 2010

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Fragmentation Enables Complexity in the First Total Synthesis of Vinigrol
Authors: Lu Jin‐Yong , Hall Dennis G. 
Published: June 2010

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Stereoselective Synthesis of GABOB, Carnitine and Statine Phosphonates Analogues.
Authors: Ordonez Mario , Labastida‐Galvan Victoria , Lagunas‐Rivera Selene 
Published: June 2010

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Nucleophilicity of a Base‐Stabilized Borole Anion at the Boron Center
Authors: Yamashita Makoto 
Published: June 2010

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Pectic Oligosaccharides
Authors: Ralet M.‐C. 
Published: June 2010

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: In vitro Studies of Phenol Coupling Enzymes Involved in Vancomycin Biosynthesis
Authors: Li Dong Bo , Woithe Katharina , Geib Nina , Abou‐Hadeed Khaled , Zerbe Katja , Robinson John A. 
Published: June 2010

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Hydrogel—Polymer Electrolytes for Electrochemical Capacitors
Authors: Choudhury N. A. , Sampath S. , Shukla A. K. 
Published: June 2010

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Critical Material and Process Issues for CO2 Separation from Coal‐Powered Plants
Authors: Liu Wei , King David , Liu Jun , Johnson Brad , Wang Yong , Yang Zhenguo 
Published: June 2010

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Liquid Chromatography — Its Development and Key Role in Life Science Applications
Authors: Unger Klaus K. , Ditz R. , Machtejevas E. , Skudas R. 
Published: June 2010

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
ChemInform Abstract: Metalloproteins: Characterization Using CE
Authors: Richards Mark P. 
Published: June 2010

AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
Preparation of Resorcinarene‐Functionalized Gold Nanoparticles and Their Catalytic Activities for Reduction of Aromatic Nitro Compounds
Authors: Yao Yong , Sun Yan , Han Ying , Yan Chaoguo 
Published: June 2010

AbstractResorcinarene‐functionalized gold nanoparticles (AuNPs) were prepared conveniently in aqueous solution in the presence of amphiphilic tetramethoxyresorcinarene tetraaminoamide. The obtained AuNPs were characterized and analyzed by UV‐vis, FT‐IR, XRD and TEM, respectively. The results showed that the size of AuNPs and the standard deviations were all decreasing with the increase of resorcinarene concentration. In addition, the catalytic activity of the obtained AuNPs in the reduction of aromatic nitro compounds was also investigated. In aqueous solution the reaction follows a first order kinetics and the size of AuNPs has influence on the rate of reduction.
Contrast of Bonding and Characters for C6, B3N3, C6H6 and B3N3H6 Molecules
Authors: Xu Shuhong , Wang Chulei , Cui Yiping 
Published: June 2010

AbstractThrough integrative consideration of NICS, MO, MOC and NBO, we precisely investigated delocalization and bonding characters of C6, C6H6, B3N3 and B3N3H6 molecules. Firstly, we originally discovered and testified that C6 cluster was sp2 hybridization. Negative NICS values in 0 and 1 Å indicated that C6 had δ and Π aromaticity. Secondly, B3N3 with sp2 hybridization had obvious δ aromaticity. Finally, WBI values approved that there were delocalization in C6, C6H6 and B3N3 molecules, but B3N3H6 structure did not have delocalization with the WBI 1.0. Moreover, total WBI values of carbon, boron and nitrogen atoms were four, three and three, respectively. Namely, the electrons of B3N3H6 and B3N3 were localized in nitrogen atoms and they did not form delocalized bonding. In a word, bonding characters of carbon, boron and nitrogen atoms were dissimilar although the molecules composed of carbon, boron and nitrogen were regarded as isoelectronic structures.
(Solid+Liquid) Equilibria in the Quaternary System Na2B4O7‐MgB4O7‐K2B4O7‐H2O at 288 K
Authors: Song Shihua , Peng Jiang 
Published: June 2010

Abstract(Solid+Liquid) phase equilibria in the quaternary system Na2B4O7‐MgB4O7‐K2B4O7‐H2O at 288 K were studied experimentally using the method of isothermal solution saturation. Solubility of any single salt in the solution of the quaternary system was determined experimentally. Based on the experimental data achieved, the phase diagram and water content diagram of the quaternary system were constructed, respectively. In the phase equilibrium diagram of the quaternary system Na2B4O7‐MgB4O7‐K2B4O7‐H2O at 288 K, there are one invariant point E, three univariant curves E1E, E2E and E3E, and three fields of crystallization corresponding to Na2B4O7·10H2O, K2B4O7·4H2O and MgB4O7·9H2O. The experimental results show that potassium borate (K2B4O7·4H2O) have higher solubilities than the magnesium borate and sodium borate in the quaternary system Na2B4O7‐MgB4O7‐K2B4O7‐H2O at 288 K.
Synthesis, Crystal Structure, and DNA‐Binding Properties of a New Cd(II) Complex Involving 2‐(2‐1H‐Imidazolyl)‐1H‐Imdazolium Ligand
Authors: Li Yanping , Yang Pin 
Published: June 2010

AbstractA new Cd(II) complex of Cd(H3biim)2(NCS)2Cl2 [H3biim=2‐(2‐1H‐imidazolyl)‐1H‐imidazolium] was synthesized and characterized by elemental analyses, FT‐IR and X‐ray single crystal diffraction. In the X‐ray crystallography structure, the cadmium(II) ion is coordinated by two nitrogen atoms of two 2‐(2‐1H‐imidazolyl)‐ 1H‐imdazolium, two nitrogen atoms of two thiocyanate ions and two Cl−. The interaction of the complex with calf thymus DNA was investigated through electronic absorption spectroscopy, fluorescence spectroscopy, viscosity measurement, cyclic voltammetry and gel electrophoresis. These results show that the Cd(II) complex can electrostatically bind to the phosphate group of DNA backbone. Interestingly, we found that the complex can cleave the pBR322 DNA at pH=7.2 and 37°C.
Common Pathway for K562 Cells Endocytosis and Release of GaC‐Tf and Ga2‐Tf via a Transferrin Receptor
Authors: Li Yingqi , Liu Bin , Zhao Chungui , Yang Binsheng 
Published: June 2010

AbstractThere has been an increasing interest in the use of gallium in anticancer activity. However, whether the uptakes of two species of transferrin, including digallium transferrin (Ga2‐Tf) and the C‐terminal monogallium transferrin (GaC‐Tf) by cells, are different is not well understood. In this work the mechanism of both species passing in and out K562 cells has been established by using 125I‐labeled transferrin. There were about (1.5±0.08)×105 binding sites per cell surface. Both Ga2‐Tf and GaC‐Tf were recycled to the cell exterior with a protracted endocytic cycle compared to apotransferrin (apoTf). The cycling time from the internalization to release was calculated about t1/2= (3.15±0.055) min for apoTf, t1/2= (4.69±0.09) min for Ga2‐Tf and t1/2= (4.78±0.15) min for GaC‐Tf. The result implies that metal dissociating from transferrin in acidic endosomes was likely to be the key step. Both Ga2‐Tf and GaC‐Tf into K562 cells are transferrin receptor‐mediated process with a similar rate of endocytosis and release. Our present observations provide useful information for better targeted drugs in specific therapy.
Development of Pr(III) Selective Electrode Using 1,6,7,12‐Tetramine‐2,5,8,11‐tetraoxo‐1(12),6(7)‐di(biphenyl)‐dodecane (TATODBDD) as a Neutral Carrier
Authors: Chandra Sulekh , Singh Dev Raj 
Published: June 2010

AbstractA polyvinyl chloride (PVC) membrane based Pr(III) selective electrode was constructed using 1,6,7,12‐tetramine‐2,5,8,11‐tetraoxo‐1(12),6(7)‐di(biphenyl)dodecane (TATODBDD) as a neutral carrier. The sensor exhibits a Nernstian response for Pr(III) ions, a wide concentration range of 3.9×10−7−1.0×10−1 mol/L with a detection limit of 5.0×10−8 mol/L and slope of 19.5 mV/decade. The developed sensor revealed relatively good selectivity and high sensitivity for Pr(III) ions over the other lanthanide ions. The potentiometric response of the sensor is independent in the pH range 2.9–9.5. The advantages of sensor are low resistance, very fast response time (<10 s) with good selectivity. This sensor can be used up to 6 weeks without any divergences in potential response.
Transport of Tb3+ in Dispersion Supported Liquid Membrane System with Carrier P507
Authors: Pei Liang , Yao Binghua , Wang Liming , Zhao Nan , Liu Min 
Published: June 2010

AbstractThe Tb3+ transport in dispersion supported liquid membrane (DSLM) consisting of polyvinylidene fluoride membrane (PVDF) as the liquid membrane support and dispersion solution including HCl solution as the stripping solution and 2‐ethyl hexyl phosphonic acid‐mono‐2‐ethyl hexyl ester (P507) dissolved in kerosene as the membrane solution, has been studied. The effects of pH value, initial concentration of Tb3+ and different ionic strength in the feed phase, volume ratio of membrane solution and stripping solution, concentration of HCl solution, concentration of carrier, different stripping agents in the dispersion phase on transport of Tb3+ has also been investigated, respectively. As a result, the optimum transport conditon of Tb3+ was that concentration of HCl solution was 4.0 mol/L, concentration of P507 was 0.10 mol/L, and volume ratio of membrane solution and stripping solution was 1.0 in the dispersion phase, and pH value was 5.2 in the feed phase. Ionic strength had no obvious effect on transport of Tb3+. Under the optimum condition studied, when initial concentration of Tb3+ was 1.0×10−4 mol/L, the transport rate of Tb3+ was up to 95.2% during the transport time of 95 min. The kinetic equation was developed in terms of the law of mass diffusion and the theory of interface chemistry. The results were in good agreement with the literature data.
Templated Synthesis of Ordered Mesoporous Carbons with Tailored Structures and Morphologies
Authors: Wang Xiufang , Tian Yong 
Published: June 2010

AbstractDue to the excellent biocompatibility and the capability to load and release drugs, ordered mesoporous carbons (OMCs) have been highly prospective and valuable in drug delivery system. In this contribution, synthesis of OMCs with tailored pore sizes from 4.1 to 3.4 nm was achieved by employing SBA‐15 as template and furfuryl alcohol (FA) as carbon precursors. An array of OMCs with controlled structures and morphologies by incipient wetness with FA was analyzed by powder X‐ray diffraction (XRD), nitrogen adsorption, transmission electron microscopy (TEM), and Raman spectroscopy. The resulting carbon replicas retained the hexagonal symmetry of the silica templates SBA‐15 with p6mm space group, although the framework suffered shrinkage in the replicated process. The pore size distribution, uniformity and pore volume of the mesopores in the OMCs were affected by structural properties of the SBA‐15 templates as shown by N2 sorption and XRD pattern analysis. The process had the advantage that the textural parameters of the obtained OMCs were tunable simply by varying aging temperature of the silica template and the ratio of carbon precursor.
Tautomerism and Magnesium Chelation of HIV‐1 Integrase Inhibitors: A Theoretical Study
Authors: Liao Chenzhong , Nicklaus Marc C. 
Published: June 2010

AbstractThe tautomerism and corresponding transition states of four authentic HIV‐1 integrase (IN) inhibitor prototype structures, α,γ‐diketo acid, α,γ‐diketotriazole, dihydroxypyrimidine carboxamide and 4‐quinolone‐3‐carboxylic acid, were investigated at the B3LYP/6‐311++G(d,p) level in vacuum and in aqueous solvent models. To study the possible chelating modes of these tautomers with two magnesium ions—a process important for inhibition—we modeled an assembly of three formic acids, four water molecules and two Mg2+ ions as a template mimicking the binding site of IN. The DFT calculation results show that deprotonated enolized or phenolic hydroxy groups of specific tautomers in water lead to the most stable complexes, with the two magnesium ions separated by a distance of approximately 3.70 to 3.74 Å, and with each magnesium ion at the center of an octahedron. The drug candidate GS‐9137 (Gilead), based on the 4‐quinolone‐3‐carboxylic acid scaffold, and its analogues form similar but different chelating modes. When one water molecule in the complex is replaced by a methanol molecule, which mimics the terminal 3′‐OH of viral DNA, a good chelating complex is retained. This supports the hypothesis that, in the binding site of IN after 3′‐processing, the terminal 3′‐OH of viral DNA interacts with one Mg2+ by chelation.
Prognostic factors in cutaneous desmoplastic melanoma
Authors: Murali Rajmohan , Shaw Helen M. , Lai Kenneth , McCarthy Stanley W. , Quinn Michael J. , Stretch Jonathan R. , Thompson John F. , Scolyer Richard A. 
Published: June 2010

AbstractBACKGROUND:Desmoplastic melanoma (DM) is a rare subtype of melanoma that is characterized by malignant spindle cells separated by prominent, fibrocollagenous stroma. Primary melanomas either may be entirely desmoplastic or almost entirely desmoplastic (pure DM [pDM]) or may exhibit a desmoplastic component admixed with a nondesmoplastic component (combined DM [cDM]).METHODS:Patients who were diagnosed between 1993 and 2007 at a single institution with clinically localized, primary cutaneous melanoma (PCM) that contained a desmoplastic component and who underwent sentinel lymph node (SLN) biopsy were identified. Clinical and pathologic features of the primary tumors were correlated with DM type, SLN status, and patient outcome.RESULTS:Two hundred fifty‐two patients (167 men, 85 women) were identified (median age, 61 years). The median tumor thickness was 2.0 mm. One hundred twenty‐three patients (48.8%) had pDM, and 129 patients (51.2%) had cDM. Overall, 17 patients (6.7%) had positive SLN status, including 12 patients with cDM and 5 patients with pDM. Because of the low SLN‐positive rate, a statistically significant difference in SLN status between patients with cDM (8.5%) and patients with pDM (4.9%; P = .25) could not be demonstrated. Older patient age, being a man, positive SLN status, and increasing tumor thickness were associated significantly with poorer disease‐free survival (P < .05), although only the latter 2 variables were independently predictive. In addition, cDM type (P = .017) was associated significantly and independently with a shorter time to recurrence.CONCLUSIONS:In this largest study to date of patients with DM who underwent SLN biopsy, the SLN‐positive rate in patients with DM was lower than that in patients with conventional melanoma. The results indicated that DM type is associated significantly and independently with the time to recurrence and should be evaluated routinely in all patients with PCM. Cancer 2010. © 2010 American Cancer Society.