bluuebunny/crossref_metadata_2025_split huggingface dataset:
Telomerization of Myrcene and Catalyst Separation by Thermomorphic Solvent Systems
Authors: Behr Arno , Johnen Leif , Vorholt Andreas J. 
Published: July 2010

AbstractTelomerization of common petrochemical 1,3‐dienes such as butadiene and isoprene have long been successful with different nucleophiles; however, the telomerization of the C10 hydrocarbon myrcene was not known until now. Herein, the first telomerization of the monoterpene myrcene with diethylamine is discussed, which provides an atom‐economical way of generating C20 amines in a single step. Variation of the palladium precursors and phosphorous ligands and optimization of solvent and additives led to the optimum catalyst system [Pd(MeCN)4](BF4)2/PPh3. By using a thermomorphic solvent system, the Pd complex can be easily separated with low leaching values.
ChemInform Abstract: Synthesis and Characterizations of Two Anhydrous Metal Borophosphates: M2IIIBP3O12 (M: Fe, In).
Authors: Zhang Wei‐Long , Lin Chen‐Sheng , Geng Lei , Li Ye‐Yu , Zhang Hao , He Zhang‐Zhen , Cheng Wen‐Dan 
Published: July 2010

AbstractThe title compounds are obtained quantitatively by reacting mixtures of M2O3 (M: Fe, In), H3BO3, and NH4H2PO4 in a molar ratio of 1:1:3 at 1153 K.
ChemInform Abstract: Probing the Structure, Stability and Hydrogen Storage Properties of Calcium Dodecahydro‐closo‐dodecaborate.
Authors: Stavila Vitalie , Her Jae‐Hyuk , Zhou Wei , Hwang Son‐Jong , Kim Chul , Ottley Leigh Anna M. , Udovic Terrence J. 
Published: July 2010

AbstractCompound (IV) crystallizes in the monoclinic space group C2/c with Z = 4 (powder XRD).
ChemInform Abstract: Investigation of the Structural Properties of an Extended Series of Lanthanide Bis‐hydroxychlorides Ln(OH)2Cl (Ln: Nd—Lu, Except Pm and Sm).
Authors: Zehnder Ralph A. , Clark David L. , Scott Brian L. , Donohoe Robert J. , Palmer Phillip D. , Runde Wolfgang H. , Hobart David E. 
Published: July 2010

AbstractThe title compounds are hydrothermally synthesized from LnCl3·6H2O in small amounts of H2O (autoclave, 220 °C, 21 d) and characterized by single crystal XRD, diffuse reflectance, FT‐IR, and FT‐Raman spectroscopy.
ChemInform Abstract: Lithium Storage Capability of Lithium Ion Conductor Li1.5Al0.5Ge1.5 (PO4)3.
Authors: Feng J. K. , Lu L. , Lai M. O. 
Published: July 2010

AbstractThe title compound with a NASICON structure is prepared by solid state reaction of stoichiometric amounts of Li2CO3, Al2O3, Ge, and NH4H2PO4 (Pt crucible, 700 and 950 °C, 2 h each) and characterized by XRD, cyclic voltammetry, AC impedance, DC conductivity measurements, and battery tests.
ChemInform Abstract: Synthesis, Characterization and Photocatalytic Properties of CaNb2O6 with Ellipsoid‐Like Plate Morphology.
Authors: Cho In‐Sun , Kim Dong Wook , Cho Chin Moo , An Jae‐Sul , Roh Hee‐Suk , Hong Kug Sun 
Published: July 2010

AbstractEllipsoid‐like two‐dimensional plates of the title compound are hydrothermally synthesized from EtOH solutions of Ca(NO3)2 and NbCl5 (pH 11 adjusted with NH4OH, autoclave, 200 °C, 24 h).
ChemInform Abstract: Development of a Building Block Strategy to Access Gigantic Nanoscale Heteropolyoxotungstates by Using SeO2‐3 as a Template Linker.
Authors: Yan Jun , Long De‐Liang , Cronin Leroy 
Published: July 2010

AbstractGigantic heteropolyoxotungstates are synthesized using the SeO32‐ group as both heterotemplate and linker.
ChemInform Abstract: Super Silyl Stereo‐Directing Groups for Complete 1,5‐syn and ‐anti Stereoselectivities in the Aldol Reactions of β‐Siloxy Methyl Ketones with Aldehydes.
Authors: Yamaoka Yousuke , Yamamoto Hisashi 
Published: July 2010

AbstractAldol reactions of β‐tris(trialkylsilyl)siloxy methyl ketones (I) with various aldehydes proceed in the presence of lithium hexamethyldisilazide with high syn‐selectivity.
ChemInform Abstract: Thermal Behavior of Bicyclo[2.2.2]octadiene‐Installed Precursors for 2H‐Anthra[2,3‐c]pyrroles and Anthra[2,3‐c]thiophene.
Authors: Uoyama Hiroki , Chenxin Cai , Tahara Hiroyuki , Shimizu Yusuke , Hagiwara Hideki , Hanasaki Yasuaki , Yamada Hiroko , Okujima Tetsuo , Uno Hidemitsu 
Published: July 2010

Abstract4,11‐Ethano‐4,11‐dihydro‐2H‐anthra[2,3‐c]pyrroles (IV) and the corresponding thiophene (VI) are prepared, and their thermogravimetric behavior is studied.
ChemInform Abstract: Chemoselective Conjugate Reduction of α,β‐Unsaturated Ketones Catalyzed by Rhodium Amido Complexes in Aqueous Media.
Authors: Li Xuefeng , Li Liangchun , Tang Yuanfu , Zhong Ling , Cun Linfeng , Zhu Jin , Liao Jian , Deng Jingen 
Published: July 2010

AbstractIn the presence of HCOONa, Rh2Cl4(C5Me5)2, and the diamine (AMI) α,β‐unsaturated ketones are found to undergo reduction of the C=C double bond with high selectivity.
ChemInform Abstract: Straightforward Access to α‐Methylamines Through Cross‐Metathesis.
Authors: Poulhes Florent , Sylvain Remy , Perfetti Patricia , Bertrand Michele P. , Gil Gerard , Gastaldi Stephane 
Published: July 2010

AbstractA two step procedure consisting of cross‐metathesis (olefins with methyl vinyl ketone) and reductive amination offers an efficient access to a variety of title compounds.
ChemInform Abstract: Reaction of Carboxylic Acids with Tetrachlorosilane.
Authors: Voronkov M. G. , Vlasov A. V. , Belousova L. I. , Grigor'eva O. Yu. , Vlasova N. N. 
Published: July 2010

AbstractThe reaction of carboxylic acids with SiCl4 can be recommended as a preparative route to corresponding acid chlorides only for weak acids (pKa < 4.7).
ChemInform Abstract: Catalytic Asymmetric Domino Michael—Henry Reaction: Enantioselective Access to Bicycles with Consecutive Quaternary Centers by Using Bifunctional Catalysts.
Authors: Rueping Magnus , Kuenkel Alexander , Froehlich Roland 
Published: July 2010

AbstractA bifunctional, cinchonidine‐based, thiourea catalyst is shown to catalyze the enantioselective domino Michael—Henry reaction of cyclohexadienone (I) with various β‐nitrostyrenes.
ChemInform Abstract: Copper(II)‐Catalyzed Conversion of Aryl/Heteroaryl Boronic Acids, Boronates, and Trifluoroborates into the Corresponding Azides: Substrate Scope and Limitations.
Authors: Grimes Kimberly D. , Gupte Amol , Aldrich Courtney C. 
Published: July 2010

AbstractA large variety of boronic acids, boronates and trifluoroborates bearing (het)aryl substituents reacts with sodium azide in the presence of Cu(OAc)2 to give the corresponding aryl azides.
ChemInform Abstract: Highly Efficient Asymmetric Three‐Component Vinylogous Mannich Reaction Catalyzed by a Chiral Scandium(III)‐N,N′‐dioxide Complex.
Authors: Zhang Qi , Hui Yonghai , Zhou Xin , Lin Lili , Liu Xiaohua , Feng Xiaoming 
Published: July 2010

AbstractVarious aldehydes can be converted to highly functionalized δ‐amino‐α,β‐unsaturated carboxylic esters with good to excellent enantioselectivity and complete regioselectivity.
ChemInform Abstract: A New Chemo‐Enzymatic Route to Chiral 2‐Hydroxy‐4‐phenylbutyrates by Combining Lactonase‐Mediated Resolution with Hydrogenation over Pd/C.
Authors: Chen Bing , Yin Hai‐Feng , Wang Zhen‐Sheng , Liu Jia‐Ying , Xu Jian‐He 
Published: July 2010

AbstractA new chemo‐enzymatic route to both enantiomers of 2‐hydroxy‐4‐phenylbutyric acid is reported.
ChemInform Abstract: An Efficient Synthesis of Sulfamides.
Authors: Guo Chuangxing , Dong Liming , Kephart Susan , Hou Xinjun 
Published: July 2010

AbstractIn connection with efforts concerning the synthesis of potential FKBP‐12 inhibitors in which the known ketoamide linker is replaced by sulfamide, various target compounds are prepared.
ChemInform Abstract: Pd‐Catalyzed Decarboxylative Arylation of Thiazole, Benzoxazole, and Polyfluorobenzene with Substituted Benzoic Acids.
Authors: Xie Kai , Yang Zhiyong , Zhou Xingjian , Li Xiujian , Wang Sizhou , Tan Ze , An Xiangyu , Guo Can‐Cheng 
Published: July 2010

AbstractThe process allows the preparation of the target compounds with high chemo‐ and regioselectivities.
ChemInform Abstract: Palladium‐Catalyzed ortho‐Arylation of O‐Phenylcarbamates with Simple Arenes and Sodium Persulfate.
Authors: Zhao Xiaodan , Yeung Charles S. , Dong Vy M. 
Published: July 2010

AbstractThe present oxidative cross‐coupling reaction proceeds by a Pd(0)/Pd(II) catalytic cycle involving C—H bond activation by carbamate‐assisted cyclopalladation, C—H bond functionalization by electrophilic metalation, reductive elimination and reoxidation of Pd(0).
ChemInform Abstract: Water‐Soluble Palladium and Gold Nanoparticles Functionalized by a New Phosphine with Zwitterionic Liquid Based on Imidazolium Sulfonate Linked Ethylene Glycol Moiety.
Authors: Akiyama Taichi , Ibata Chiharu , Fujihara Hisashi 
Published: July 2010

AbstractThe new phosphine (PHOS) is used to prepare stable metal nanoparticles in aqueous electrolyte.
ChemInform Abstract: Enantioselective Synthesis of Bicarbocyclic Structures with an All‐Carbon Quaternary Stereocenter Through Sequential Cross Metathesis and Intramolecular Rauhut—Currier Reaction.
Authors: Qiao Yuan , Kumar Sanjeev , Malachowski William P. 
Published: July 2010

AbstractA process consisting of Ru‐catalyzed cross‐coupling and an intramolecular Rauhut—Currier reaction is described to construct highly functionalized hydrindan skeletons containing an all‐carbon quaternary stereocenter in an angular position.
ChemInform Abstract: Regioselective and Stereoselective Cyclizations of Chloropolyols in Water: Rapid Synthesis of Hydroxytetrahydrofurans.
Authors: Kang Baldip , Chang Stanley , Decker Shannon , Britton Robert 
Published: July 2010

AbstractA wide range of the sterically defined mono‐, tri‐ and tetrasubstituted tetrahydrofurans is prepared in a simple microwave‐assisted reaction in water without any additives.
ChemInform Abstract: Expeditious Synthesis of Benzopyrans via Lewis Acid‐Catalyzed C—H Functionalization: Remarkable Enhancement of Reactivity by an ortho Substituent.
Authors: Mori Keiji , Kawasaki Taro , Sueoka Shosaku , Akiyama Takahiko 
Published: July 2010

Abstractortho‐Substitution to the alkoxy group enhances the reactivity of the substrates and leads to the higher yields of the corresponding products [cf.
ChemInform Abstract: Improved Procedure for the Enantioselective Synthesis of Dihydrooxazolo and Dihydrothiazolo Ring‐Fused 2‐Pyridones.
Authors: Chorell Erik , Edvinsson Sofie , Almqvist Fredrik 
Published: July 2010

AbstractThe synthesis includes dehydrative cyclization of serine derivatives (I) and condensation of the resulting oxazolines with Meldrum′s acid derivative (II).
ChemInform Abstract: Furan Ring Recyclization in 2‐Furfurylthieno[2,3‐b]pyridines: An Intramolecular N‐Alkylation of Pyrrole Ring under Acid Conditions.
Authors: Kosulina Darya Yu. , Vasilin Vladimir K. , Stroganova Tatyana A. , Kaklyugina Tatyana Ya. , Krapivin Gennady D. 
Published: July 2010

AbstractDepending on reaction conditions, the new heterocycles (V) and (VII) are formed from the 4‐unsubstituted derivative (IVa).
ChemInform Abstract: Four‐Component Domino Reaction Providing an Easy Access to Multifunctionalized Tricyclo[6.2.2.01.6]dodecane Derivatives.
Authors: Jiang Bo , Li Chao , Shi Feng , Tu Shu‐Jiang , Kaur Parminder , Wever Walter , Li Guigen 
Published: July 2010

AbstractThe reaction proceeds with complete control of stereoselectivity.
ChemInform Abstract: Efficient Synthesis of Benzimidazo[1,2‐a]pyrimidinone Derivatives via Catalyst‐Free Reactions of Baylis—Hillman Acetates, Alcohols, and Amines with 2‐Aminobenzimidazole.
Authors: Wang Yan , Shafiq Zahid , Liu Li , Wang Dong , Chen Yong‐Jun 
Published: July 2010

AbstractThe title compounds, e.g. (III) and (V), are prepared by an efficient and facile one‐pot process without the use of any catalyst or additive.
ChemInform Abstract: Rumphellclovane A, a Novel Clovane‐Related Sesquiterpenoid from the Gorgonian Coral Rumphella antipathies.
Authors: Chung Hsu‐Ming , Chen Yung‐Husan , Hwang Tsong‐Long , Chuang Li‐Fan , Wan Wei‐Hsien , Sung Ping‐Jyun 
Published: July 2010

AbstractTitle compound A (I) and (II) is isolated together with the natural clovane 2β‐hydroxyclovan‐9‐one (II).
ChemInform Abstract: Phase‐Transfer Catalyzed Enantioselective Epoxidation of Estra‐Λ5(10),9(11)‐diene Using Chiral Ammonium Salts Derived from Cinchona Alkaloids.
Authors: Yang Ya‐Xi , Li Zheng , Chen Guo‐Rong , Li Yuan‐Chao 
Published: July 2010

AbstractA series of chiral ammonium salts derived from cinchona alkaloids is synthesized and used as phase‐transfer catalyst to improve the epoxidation of title compound (I).
Osteosarcoma in very young children
Authors: Kager Leo , Zoubek Andreas , Dominkus Martin , Lang Susanna , Bodmer Nicole , Jundt Gernot , Klingebiel Thomas , Jürgens Heribert , Gadner Helmut , Bielack Stefan ,   for the COSS Study Group
Published: July 2010

AbstractBACKGROUND:This study was conducted to investigate presentation, treatment, and outcome in very young children with osteosarcoma.METHODS:The authors retrospectively analyzed the data of 2706 consecutive COSS patients with newly diagnosed osteosarcoma and identified 28 (1.0%) patients aged younger than 5 years at diagnosis. Demographic, diagnostic, tumor, treatment‐related variables, response, and survival data were analyzed.RESULTS:Of the 28 preschoolers, 27 presented with high‐grade central osteosarcoma of an extremity, and 1 had a secondary osteosarcoma of the orbit. This analysis focused on the 27 patients with extremity tumors. The size of the primary was large (≥one‐third of the involved bone) in 20 of 27 patients. Primary metastases were detected in 4 of 27 children. All patients received multiagent chemotherapy, and 11 of 18 analyzed tumors responded well (>90% necrosis) to neoadjuvant chemotherapy. Limb‐sparing surgery was performed in 9 cases, ablative procedures were performed in 15, and, in 3 cases, no local surgery was performed. With a median follow‐up of 4 years (6.2 years for survivors), 13 patients were alive. Four patients never achieved a complete remission, and 11 developed recurrences; 14 of these 15 patients died. Five‐year overall and event‐free survival probabilities were 51% (standard error of the mean [SE], 10%) and 48% (SE, 10%). Better survival was correlated with good response to chemotherapy and later time period of diagnosis.CONCLUSIONS:Osteosarcoma is extremely rare in preschool children. These patients often have large tumors that may require mutilating resections. Prognosis is in the range of that reported for older patients. Cancer 2010. © 2010 American Cancer Society.
Dysembryoplastic neuroepithelial tumors and cognitive outcome
Authors: Qaddoumi Ibrahim , Ellison David W. , Morris E. Brannon , Broniscer Alberto , Boop Frederick , Merchant Thomas , Palmer Shawna L. , Gajjar Amar 
Published: July 2010

AbstractBACKGROUND:Dysembryoplastic neuroepithelial tumors (DNETs) are benign glioneuronal tumors that occur in children. These tumors are characterized by seizures, lack of neurologic deficits, and a seemingly benign course after resection.METHODS:A retrospective review was conducted of data relating to 11 children diagnosed with DNETs between January 1988 and December 2007 at St. Jude Children's Research Hospital. This report documented the clinical features, neurocognitive function, and treatment outcomes in this institutional series.RESULTS:The patient cohort included 8 boys and 3 girls (median age at diagnosis, 10 years); all patients presented with seizures: 4 complex partial, 3 generalized tonic‐clonic, 2 absence, 1 partial simple, and 1 not classified. Of the 11 patients, 1 died of cardiac fibrosis, and tumors recurred or progressed in 4 (36%) patients. Seizure control was achieved in all patients but 1. Of the 9 patients who completed neuropsychologic testing, only 3 (33%) functioned at or above the expected level of same‐age peers.CONCLUSIONS:The high recurrence and progression rates of DNETs and the high rate of abnormal neurocognitive test results noted in the current study highlight the need for regular follow‐up and appropriate academic counseling of children with these tumors. Cancer 2010. © 2010 American Cancer Society
Cancer incidence in the multicenter aids cohort study before and during the HAART era
Authors: Seaberg Eric C. , Wiley Dorothy , Martínez‐Maza Otoniel , Chmiel Joan S. , Kingsley Lawrence , Tang Yiwei , Margolick Joseph B. , Jacobson Lisa P. ,   for the Multicenter AIDS Cohort Study (MACS)
Published: July 2010

AbstractBACKGROUND:The incidence of Kaposi sarcoma (KS) and non‐Hodgkin lymphoma (NHL) among human immunodeficiency virus (HIV)‐infected individuals declined after the introduction of highly active antiretroviral therapy (HAART) in the mid‐1990s, but the cancer risk associated with HIV infection during the HAART era remains to be clarified.METHODS:Cancer incidence among HIV‐infected and HIV‐uninfected participants in the Multicenter AIDS (acquired immunodeficiency syndrome) Cohort Study (MACS) between 1984 and 2007 was compared with the expected incidence using US population‐based data from the Surveillance, Epidemiology, and End Results (SEER) program. Age‐ and race‐adjusted cancer incidence rates were also compared HIV by status and over time within the MACS. Exact statistical methods were used for all analyses.RESULTS:A total of 933 incident cancers were observed during 77,320 person‐years of follow‐up. Compared with SEER, MACS HIV‐infected men had significantly (P < .05) elevated rates of KS (standardized incidence ratio [SIR], 139.10), NHL (SIR, 36.80), Hodgkin lymphoma (HL)(SIR, 7.30), and anal cancer (SIR, 25.71). Within MACS, HIV infection was found to be independently associated with each of these cancers across the entire follow‐up period, and KS (incidence rate ratio [IRR], 54.93), NHL (IRR, 11.18), and anal cancer (IRR, 18.50) were each found to be significantly elevated among HIV‐infected men during the HAART era. Among these men, the incidence of KS and NHL declined (IRR, 0.13 and 0.23, respectively), the incidence of anal cancer increased (IRR, 5.84), and the incidence of HL remained statistically unchanged (IRR, 0.75) from the pre‐HAART to the HAART era.CONCLUSIONS:Cancer risk remains elevated among HIV‐infected men who have sex with men, highlighting the continuing need for appropriate cancer screening in this population. Cancer 2010. © 2010 American Cancer Society.
Quality of cancer care among foreign‐born and US‐born patients with lung or colorectal cancer
Authors: Nielsen Signe Smith , He Yulei , Ayanian John Z. , Gomez Scarlett Lin , Kahn Katherine L. , West Dee W. , Keating Nancy L. 
Published: July 2010

AbstractBACKGROUND:Disparities in care have been documented for foreign‐born cancer patients in the United States. However, few data are available regarding patients with lung and colorectal cancer. In the current study, the authors assessed whether patient‐reported quality and receipt of recommended care differed between US‐born and foreign‐born cancer patients.METHODS:The authors collected surveys and medical records for a population‐based cohort including white, Hispanic, and Asian adults (2205 US‐born and 890 foreign‐born individuals) with lung or colorectal cancer diagnosed in California from 2003 through 2005. Logistic regression was used to assess the association between nativity and patient‐reported quality of care and receipt of recommended treatments (adjuvant chemotherapy for stage III colon cancer, adjuvant chemotherapy and radiotherapy for stage II/III rectal cancer, and curative surgery for stage I/II nonsmall cell lung cancer). The authors also assessed whether language explained any differences in care by nativity.RESULTS:Overall, 46% of patients reported excellent care, but foreign‐born patients were less likely than US‐born patients to report excellent quality of care (adjusted odds ratio [AOR], 0.80; 95% confidence interval [95% CI], 0.65‐1.00), a difference partly explained by the language of the survey, an indicator of English proficiency. Rates of recommended therapies ranged from 64% to 85%; foreign‐born patients were less likely to receive chemotherapy and radiotherapy for stage II/III rectal cancer (AOR, 0.35; 95% CI, 0.12‐0.99). Rates of other treatments did not differ significantly by nativity.CONCLUSIONS:Foreign‐born cancer patients reported lower quality of care and were less likely to receive some cancer therapies than patients born in the Unites States. Better coordination of care and communication regarding cancer treatments and expanded use of interpreters may lessen these disparities. Cancer 2010. © 2010 American Cancer Society.
Steroid hormone regulation of the voltage‐gated, calcium‐activated potassium channel expression in developing muscular and neural systems
Authors: Garrison Sheldon L. , Witten Jane L. 
Published: July 2010

AbstractA precise organization of gene expression is required for developing neural and muscular systems. Steroid hormones can control the expression of genes that are critical for development. In this study we test the hypothesis that the steroid hormone ecdysone regulates gene expression of the voltage‐gated calcium‐activated potassium ion channel, Slowpoke or KCNMA1. Late in adult development of the tobacco hawkmoth Manduca sexta, slowpoke
(msslo) levels increased contributing to the maturation of the dorsal longitudinal flight muscles (DLMs) and CNS. We show that critical components of ecdysteroid gene regulation were present during upreglation of msslo in late adult DLM and CNS development. Ecdysteroid receptor complex heterodimeric partner proteins, the ecdysteroid receptor (EcR) and ultraspiracle (USP), and the ecdysone‐induced early gene, msE75B, were expressed at key developmental time points, suggesting that ecdysteroids direct aspects of gene expression in the DLMs during these late developmental stages. We provide evidence that ecdysteroids suppress msslo transcription in the DLMs; when titers decline msslo transcript levels increase. These results are consistent with msslo being a downstream gene in an ecdysteroid‐mediated gene cascade during DLM development. We also show that the ecdysteroids regulate msslo transcript levels in the developing CNS. These results will contribute to our understanding of how the spatiotemporal regulation of slowpoke transcription contributes to tailoring cell excitability to the differing physiological and behavioral demands during development. © 2010 Wiley Periodicals, Inc. Develop Neurobiol 70: 884–896, 2010
Synthesis and Electrochemistry of Cyclopentadienyl Ferratricarbollides Substituted by Me and Ph Groups on the Cage Carbon Atoms
Authors: Holub Josef , Bakardjiev Mario , Štíbr Bohumil , Štěpnička Petr , Císařová Ivana 
Published: July 2010

AbstractNeutral tricarbollide tautomers of general formula 7‐tBuNH‐8,9‐R,R′‐nido‐7,8,9‐C3B8H9 (N1), where R,R′ = substituents on cage carbon atoms = H, Me, and Ph or their combinations, generated a series of very stable, twelve‐vertex ferratricarbollides of general structure [1‐Cp‐12‐tBuNH‐2,4‐R,R′‐closo‐1,2,4,12‐FeC3B8H8] (2, Cp = η5‐C5H5; yields 30–35 %) together with the isomeric complexes [1‐Cp‐10‐tBuNH‐2,4‐R,R′‐closo‐1,2,4,10‐FeC3B8H8] (3; yields 22–26 %) upon heating with [CpFe(CO)2]2 in mesitylene at reflux for 6 h. Individual compounds were isolated and purified by preparative TLC and characterized by conventional 11B and 1H NMR spectroscopy combined with two‐dimensional [11B‐11B]‐COSY and 1H‐{11B(selective)} NMR spectroscopic techniques). The structures of [1‐Cp‐12‐tBuNH‐2,4‐Me2‐1,2,4,12‐FeC3B8H8] (2c) and [1‐Cp‐12‐tBuNH‐2‐Ph‐1,2,4,12‐FeC3B8H9] (2d) were established by single‐crystal X‐ray diffraction analysis. Electrochemical studies revealed that the FeII/FeIII redox potentials are primarily affected by the type of the ferratricarbaborane cage and, to a lesser extent, by the Me and Ph substituents residing on the cage carbon atoms.