bluuebunny/crossref_metadata_2025_split huggingface dataset:
Implementation of a Markov Chain Monte Carlo Method to inorganic aerosol modeling of observations from the MCMA-2003 Campaign. Part II: Model application to the CENICA, Pedregal and Santa Ana sites
Authors: San Martini F. M. , Dunlea E. J. , Volkamer R. , Onasch T. B. , Jayne J. T. , Canagaratna M. R. , Worsnop D. R. , Kolb C. E. , Shorter J. H. , Herndon S. C. , Zahniser M. S. , Salcedo D. , Dzepina K. , Jimenez J. L. , Ortega J. M. , Johnson K. S. , McRae G. J. , Molina L. T. , Molina M. J. 
Published: April 2010

Abstract. A Markov Chain Monte Carlo model for integrating the observations of inorganic species with a thermodynamic equilibrium model was presented in Part I of this series. Using observations taken at three ground sites, i.e. a residential, industrial and rural site, during the MCMA-2003 campaign in Mexico City, the model is used to analyze the inorganic aerosol and ammonia data and predict gas phase concentrations of nitric and hydrochloric acid. In general the model is able to accurately predict the observed inorganic aerosol concentrations at all three sites. The agreement between the predicted and observed gas phase ammonia concentration is excellent. The NOz concentration calculated from the NOy, NO and NO2 observations is of limited use in constraining the gas phase nitric acid concentration given the large uncertainties in this measure of nitric acid and additional reactive nitrogen species. Focusing on the acidic period of 9–11 April identified by Salcedo et al. (2006), the model accurately predicts the aerosol phase observations during this period with the exception of the nitrate predictions after 10:00 a.m. (CDT) on 9 April, where the model underpredicts the observations by, on average, 20%. For periods when the aerosol chloride observations are consistently above the detection limit, the model is able to both accurately predict the aerosol chloride predictions and provide well-constrained HCl (g) concentrations. When the aerosols are aqueous, the most likely concentrations of HCl (g) are in the sub-ppbv range. The most likely predicted concentration of HCl (g) was found to reach concentrations of order 10 ppbv if the aerosols are dry. Finally, the atmospheric relevance of HCl (g) is discussed in terms of its indicator properties for the possible influence of chlorine-mediated photochemistry in Mexico City.
Pronounced signature of arctic surface ozone depletion events after polar sunrise on Δ17O in atmospheric nitrate
Authors: Morin S. , Savarino J. , Bekki S. , Gong S. , Bottenheim J. W. 
Published: April 2010

Abstract. We report in this paper the first measurements of the isotopic anomaly of oxygen in Arctic atmospheric inorganic nitrate. Data and samples were collected at Alert, Nunavut, Canada (82°30' N, 62°19' W) in spring 2004. Focusing on the polar sunrise period, characterized by the occurrence of severe boundary layer ozone depletion events (ODEs), our data show a significant correlation between the evolution of atmospheric ozone (O3) mixing ratios and Δ17O in nitrate Δ17O(NO−3)). This relationship can be expressed as: Δ17O(NO−3)/‰=0.15 O3/ (nmol mol−1) + 28.6, with R2=0.70 (n=12), for Δ17O(NO−3) ranging between 29 and 34. To quantitatively interpret this relationship, we derive from mechanisms at play in the arctic boundary layer isotopic mass-balance equations, which depend on the concentrations of reactive species and their isotopic characteristics. Changes in the relative importance of O3, RO2 and BrO in the oxidation of NOx during ODEs, and the large isotopic anomalies that O3 and BrO carry, are the driving force for the high variability in the measured Δ17O(NO−3). BrONO2 hydrolysis is found to be the major source of nitrate in the arctic boundary layer, in agreement with recent modeling studies. In addition, the isotopic fingerprint of the activity of ozone in a relatively stable compound appears somewhat promising in the perspective of using the isotopic composition of nitrate embedded in polar ice-cores as a paleo-indicator of the atmospheric ozone level that may yield an indirect proxy for the oxidative power of past atmospheres.
MIPAS level 2 operational analysis
Authors: Raspollini P. , Belotti C. , Burgess A. , Carli B. , Carlotti M. , Ceccherini S. , Dinelli B. M. , Dudhia A. , Flaud J.-M. , Funke B. , Höpfner M. , Lopez-Puertas M. , Payne V. , Piccolo C. , Remedios J. J. , Ridolfi M. , Spang R. 
Published: April 2010

Abstract. The MIPAS (Michelson Interferometer for Passive Atmospheric Sounding) instrument has been operating on-board the ENVISAT satellite since March 2002. In the first two years, it acquired in a nearly continuous manner high resolution (0.025 cm−1 unapodised) emission spectra of the Earth's atmosphere at limb in the middle infrared region. This paper describes the level 2 near real-time (NRT) and off-line (OL) ESA processors that have been used to derive level 2 geophysical products from the calibrated and geolocated level 1b spectra. The design of the code and the analysis methodology have been driven by the requirements for NRT processing. This paper reviews the performance of the optimised retrieval strategy that has been implemented to achieve these requirements and provides estimated error budgets for the target products: pressure/temperature, O3, H2O, CH4, HNO3, N2O and NO2, in the altitude measurement range from 6 to 68 km. From application to real MIPAS data, it was found that no change was needed in the developed code although an external algorithm was introduced to identify clouds with high opacity and to exclude affected spectra from the analysis. In addition, a number of updates were made to the set-up parameters and to auxiliary data. In particular, a new version of the MIPAS dedicated spectroscopic database was used and, in the OL analysis, the retrieval range was extended to reduce errors due to uncertainties in extrapolation of the profile outside the retrieval range and more stringent convergence criteria were implemented. A statistical analysis on the χ2 values obtained in one year of measurements shows good agreement with the a priori estimate of the forward model errors. On the basis of the first two years of MIPAS measurements the estimates of the forward model and instrument errors are in general found to be conservative with excellent performance demonstrated for frequency calibration. It is noted that the total retrieval error is limited by forward model errors which make useless a further reduction of random errors. However, such a reduction is within the capabilities of MIPAS measurements, which contain many more spectral signatures of the target species than what currently used. Further work is needed to reduce the amplitude of the forward model errors, so that the random error and the total error budget can be reduced accordingly. The importance of the Averaging kernels for a full characterisation of the target products is underlined and the equations are provided for their practical applications.
Methane emission from tropical savanna Trachypogon sp. grasses
Authors: Sanhueza E. , Donoso L. 
Published: April 2010

Abstract. Methane flux measurements from the soil-grass system were made during the wet season in unperturbed plots and plots where standing dry and green Trachypogon sp. grasses were clipped to just above the soil surface. Results support the surprising discovery that vegetation emits methane. The dry/green mixture of grasses produce methane at a rate of ~10 ng m−2 s−1, which extrapolated to the global savanna would produce an annual emission of ~5 Tg, much lower than the production recently suggested in the literature. On the other hand, during the wet season savanna soil consume CH4 at a rate of ~4.7 ng m−2 s−1, producing a global sink of ~1.3 Tg yr−1. Therefore, the tropical savanna soil-grass system would make a modest contribution to the global budget of methane.
Technical Note: an implementation of the dry removal processes DRY DEPosition and SEDImentation in the Modular Earth Submodel System (MESSy)
Authors: Kerkweg A. , Buchholz J. , Ganzeveld L. , Pozzer A. , Tost H. , Jöckel P. 
Published: April 2010

Abstract. We present the submodels DRYDEP and SEDI for the Modular Earth Submodel System (MESSy). Gas phase and aerosol dry deposition are calculated within DRYDEP, whereas SEDI deals with aerosol particle sedimentation. Dry deposition velocities depend on the near-surface turbulence and the physical and chemical properties of the surface cover (e.g. the roughness length, soil pH or leaf stomatal exchange). The dry deposition algorithm used in DRYDEP is based on the big leaf approach and is described in detail within this Technical Note. The sedimentation submodel SEDI contains two sedimentation schemes: a simple upwind zeroth order scheme and a first order approach.
What does reflection from cloud sides tell us about vertical distribution of cloud droplet sizes?
Authors: Marshak A. , Martins J. V. , Zubko V. , Kaufman Y. J. 
Published: April 2010

Abstract. Cloud development, the onset of precipitation and the effect of aerosol on clouds depend on the structure of the cloud profiles of droplet size and phase. Aircraft measurements of cloud profiles are limited in their temporal and spatial extent. Satellites were used to observe cloud tops not cloud profiles with vertical profiles of precipitation-sized droplets anticipated from CloudSat. The recently proposed CLAIM-3D satellite mission (cloud aerosol interaction mission in 3-D) suggests to measure profiles of cloud microphysical properties by retrieving them from the solar and infrared radiation reflected or emitted from cloud sides. Inversion of measurements from the cloud sides requires rigorous understanding of the 3-dimentional (3-D) properties of clouds. Here we discuss the reflected sunlight from the cloud sides and top at two wavelengths: one nonabsorbing to solar radiation (0.67 μm) and one with liquid water efficient absorption of solar radiation (2.1 μm). In contrast to the plane-parallel approximation, a conventional approach to all current operational retrievals, 3-D radiative transfer is used for interpreting the observed reflectances. General properties of the radiation reflected from the sides of an isolated cloud are discussed. As a proof of concept, the paper shows a few examples of radiation reflected from cloud fields generated by a simple stochastic cloud model with the prescribed vertically resolved microphysics. To retrieve the information about droplet sizes, we propose to use the probability density function of the droplet size distribution and its first two moments instead of the assumption about fixed values of the droplet effective radius. The retrieval algorithm is based on the Bayesian theorem that combines prior information about cloud structure and microphysics with radiative transfer calculations.
Investigations of the photochemical isotope equilibrium between O2, CO2 and O3
Authors: Shaheen R. , Janssen C. , Röckmann T. 
Published: April 2010

Abstract. Contrary to tropospheric CO2 whose oxygen isotopic composition follows a standard mass dependent relationship, i.e. δ17O~0.5 δ18O, stratospheric CO2 is preferentially enriched in 17O, leading to a strikingly different relation with δ17O~1.7δ18O. The isotope anomaly is likely inherited from O3 via photolytically produced O(1D) that undergoes isotope exchange with CO2 and the anomaly may well serve as a tracer of stratospheric chemistry if details of the exchange mechanism are understood. We have studied the photochemical isotope equilibrium in UV-irradiated O2-CO2 and O3-CO2 mixtures to quantify the transfer of the anomaly from O3 to CO2 at room temperature. By following the time evolution of the oxygen isotopic compositions of CO2 and O2 under varying initial isotopic compositions of both, O2/O3 and CO2, the isotope equilibria between the two reservoirs were determined. A very strong dependence of the isotope equilibrium on the O2/CO2-ratio was established. Equilibrium enrichments of 17O and 18O in CO2 relative to O2 diminish with increasing CO2 content, and this reduction in the equilibrium enrichments does not follow a standard mass dependent relation. When molecular oxygen exceeds the amount of CO2 by a factor of about 20, 17O and 18O in equilibrated CO2 are enriched by (142±4) and (146±4), respectively, at room temperature and at a pressure of 225 hPa, independent of the initial isotopic compositions of CO2 and O2 or O3. From these findings we derive a simple and general relation between the starting isotopic compositions and amounts of O2 and CO2 and the observed slope in a three oxygen isotope diagram. Predictions from this relation are compared with published laboratory and atmospheric data.
Satellite monitoring of different vegetation types by differential optical absorption spectroscopy (DOAS) in the red spectral range
Authors: Wagner T. , Beirle S. , Grzegorski M. , Platt U. 
Published: April 2010

Abstract. A new method for the satellite remote sensing of different types of vegetation and ocean colour is presented. In contrast to existing algorithms, our method analyses weak narrow-band reflectance structures (i.e. "fingerprint" structures) of vegetation in the red spectral range. It is based on differential optical absorption spectroscopy (DOAS), which is usually applied for the analysis of atmospheric trace gas absorptions. Since the spectra of atmospheric absorption and vegetation reflectance are simultaneously included in the analysis, the effects of atmospheric scattering and absorption are automatically corrected. The inclusion of the vegetation spectra also significantly improves the results of the trace gas retrieval. The global maps of the fitting coefficients for the vegetation spectra (indicating the fraction of the observed ground scene covered by vegetation) illustrate the seasonal cycle of different vegetation types. In addition to the vegetation distribution on land, they also show patterns of biological activity in the oceans. Our results indicate that improved sets of vegetation spectra might lead to more accurate and more specific identification of vegetation type in the future.
Reevaluation of mineral aerosol radiative forcings suggests a better agreement with satellite and AERONET data
Authors: Balkanski Y. , Schulz M. , Claquin T. , Guibert S. 
Published: April 2010

Abstract. Modelling studies and satellite retrievals do not agree on the amplitude and/or sign of the direct radiative perturbation from dust. Modelling studies have systematically overpredicted mineral dust absorption compared to estimates based upon satellite retrievals. In this paper we first point out the source of this discrepancy, which originates from the shortwave refractive index of dust used in models. The imaginary part of the refractive index retrieved from AERONET over the range 300 to 700 nm is 3 to 6 times smaller than that used previously to model dust. We attempt to constrain these refractive indices using a mineralogical database and varying the abundances of iron oxides (the main absorber in the visible). We first consider the optically active mineral constituents of dust and compute the refractive indices from internal and external mixtures of minerals with relative amounts encountered in parent soils. We then compute the radiative perturbation due to mineral aerosols for internally and externally mixed minerals for 3 different hematite contents, 0.9%, 1.5% and 2.7% by volume. These amounts represent low, central and high content of iron oxides in dust determined from the mineralogical database. Based upon values of the refractive index retrieved from AERONET, we show that the best agreement between 440 and 1020 nm occurs for mineral dust internally mixed with 1.5% volume weighted hematite. This representation of mineral dust allows us to compute, using a general circulation model, a new global estimate of mineral dust perturbation between −0.40 and −0.21 Wm−2. This range is determined from both optical properties and varying dust size distribution. The broadband shortwave effect varies from −0.78 to −0.53 Wm−2 and the longwave effect between +0.29 and +0.38 Wm−2. The 24-h average atmospheric heating by mineral dust during summer over the tropical Atlantic region (15° N–25° N; 45° W–15° W) is in the range +22 to +32 Wm−2 τ−1 which compares well with the 30±4 Wm−2 τ−1 measured by Li et al. (2004) over that same region. The refractive indices from Patterson et al. (1977) and from Volz (1973) overestimate by a factor of 2 the energy absorbed in the column during summer over the same region.
Modelling the direct effect of aerosols in the solar near-infrared on a planetary scale
Authors: Hatzianastassiou N. , Matsoukas C. , Fotiadi A. , Drakakis E. , Stackhouse P. W. , Koepke P. , Pavlakis K.G. , Hatzidimitriou D. , Vardavas I. 
Published: April 2010

Abstract. We used a spectral radiative transfer model to compute the direct radiative effect (DRE) of natural plus anthropogenic aerosols in the solar near-infrared (IR), between 0.85–10 µm, namely, their effect on the outgoing near-IR radiation at the top of atmosphere (TOA, ΔFTOA), on the atmospheric absorption of near-IR radiation (ΔFatmab) and on the surface downward and absorbed near-IR radiation (ΔFsurf, and ΔFsurfnet, respectively). The computations were performed on a global scale (over land and ocean) under all-sky conditions, using spectral aerosol optical properties taken from the Global Aerosol Data Set (GADS) supplemented by realistic data for the rest of surface and atmospheric parameters. The computed aerosol DRE, averaged over the 12-year period 1984–1995 for January and July, shows that aerosols produce a planetary cooling by increasing the scattered near-IR radiation back to space (by up to 6 Wm−2), they warm the atmosphere (by up to 7 Wm−2) and cool the surface (by up to 12 Wm−2). However, they can also slightly warm the Earth-atmosphere system or cool the atmosphere (by less than 1 Wm−2) over limited areas. The magnitude of the near-IR aerosol DRE is smaller than that of the combined ultraviolet (UV) and visible DRE, but it is still energetically important, since it contributes to the total shortwave (SW) DRE by 22–31%. On a global mean basis, the DREs ΔFTOA, ΔFatmab, ΔFsurf, and ΔFsurfnet are equal to about 0.48, 0.37, −1.03 and −0.85 Wm−2, i.e. their magnitude is similar to that of climate forcing associated with increasing concentrations of greenhouse gases. The aerosol induced near-IR surface cooling combined with the atmospheric warming, affects the thermal dynamics of the Earth-atmosphere system, by increasing the atmospheric stability, decreasing thus cloud formation, and precipitation, especially over desertification threatened regions such as the Mediterranean basin. This, together with the fact that the sign of near-IR aerosol DRE is sometimes opposite to that of UV-visible DRE, demonstrates the importance of performing detailed spectral computations to provide estimates of the climatic role of aerosols for the Earth-atmosphere system.
Seasonal variability of measured Ozone production efficiencies in the lower free troposphere of Central Europe
Authors: Zanis P. , Ganser A. , Zellweger C. , Henne S. , Steinbacher M. , Staehelin J. 
Published: April 2010

Abstract. In this study we present the seasonal variability of ozone production efficiencies (EN), defined as the net number of ozone molecules produced per molecule of nitrogen oxides (nitrogen oxide (NO) + nitrogen dioxide (NO2)=NOx) oxidized to NOz (total reactive nitrogen (NOy)-NOx) for a seven-year period (1998–2004) at the Swiss high-alpine research station Jungfraujoch (JFJ), 3580 m a.s.l. This dataset is a unique long-term data series of nitrogen levels in the free troposphere over Central Europe and hence it offers an excellent opportunity to perform such an analysis and provide further evidence to the photochemical origin of the ozone spring maximum at locations of the northern hemisphere distant from nearby pollution sources. Experimentally derived daily EN values have been selected for 571 days out of the 2557 days from 1998 to 2004, from which an average ozone production efficiency of 18.8±1.3 molecules of O3 produced per molecule of NOx oxidized was calculated. This value indicates the great potential and importance of photochemical ozone production in the free troposphere. The monthly means of experimentally derived daily EN values show a seasonal variation with lower values from May to August, which can be probably attributed to more efficient vertical transport of polluted air masses from the atmospheric boundary layer up to JFJ. In agreement, theoretically derived monthly EN values show similar seasonal variation. The ratio NOy/CO, a parameter to assess the aging process that has occurred in an air parcel, was used as a criterion to disaggregate the 571 selected days between undisturbed and disturbed free tropospheric (FT). The monthly means of experimentally derived EN values for the undisturbed FT conditions show a distinct seasonal cycle with higher values in the cold season from November to April. The EN values for undisturbed FT conditions are particularly higher than the respective monthly EN values for disturbed FT conditions from February to October. It should be noted that the monthly EN values of March (EN=35.8) and April (EN=34.9) are among the highest values throughout the year for undisturbed FT conditions at JFJ. These results highlight the key and possibly the dominant role for photochemistry in the observed build-up of tropospheric ozone in the winter-spring transition period.
Analysis of shallow failures triggered by the 14-16 November 2002 event in the Albaredo valley, Valtellina (Northern Italy)
Authors: Dapporto S. , Aleotti P. , Casagli N. , Polloni G. 
Published: April 2010

Abstract. On 14-16 November 2002 the North Italy was affected by an intense rainfall event: in the Albaredo valley (Valtellina) more than 200 mm of rain fell triggering about 50 shallow landslides, mainly soil slips and soil slip-debris flows. Landslides occurred above the critical rainfall thresholds computed by Cancelli and Nova (1985) and Ceriani et al. (1994) for the Italian Central Alps: in fact the cumulative precipitation at the soil slips initiation time was 230 mm (in two days) with a peak intensity of 15 mm/h. A coupled analysis of seepage and instability mechanisms is performed in order to evaluate the potential for slope failure during the event. Changes in positive and negative pore water pressures during the event are modelled by a finite element analysis of water flow in transient conditions, using as boundary condition for the nodes along the slope surface the recorded rainfall rate. The slope stability analysis is conducted applying the limit equilibrium method, using pore water pressure distributions obtained in the different time steps by the seepage analysis as input data for the calculation of the factor of safety.
Remote ENSO forcing versus local air-sea interaction in QTCM: a sensitivity study to intraseasonal variability
Authors: Gushchina D. , Dewitte B. , Illig S. 
Published: April 2010

Abstract. The skill of a newly designed global atmospheric model of intermediate complexity - QTCM (for quasi-equilibrium tropical circulation model) in simulating the teleconnections is investigated. The role of the ENSO remote forcing over the Pacific surrounding regions is emphasized from sensitivity experiments to critical parameters of the model. The role of the tropical intraseasonal variability (ITV) on the simulated ENSO teleconnection pattern is estimated using the methodology proposed by Lin et al. (2000) allowing to damp the energy of ITV in the model. The reduction of intraseasonal variability allows emphasizing the forced response of the atmosphere and eases the detection of local coupled atmosphere-ocean patterns. It was shown that the simulated ITV has an impact on the ENSO teleconnection pattern both in the mid-latitudes and in regions of ascending and descending branches of Walker circulation cells in the tropics.