bluuebunny/crossref_metadata_2025_split huggingface dataset:
Aqueous alteration of carbonaceous chondrites: Evidence for preaccretionary alteration—A review
Authors: BISCHOFF A. 
Published: February 2010

Abstract— In most groups of carbonaceous chondrites, minerals occur that are formed due to aqueous alteration in the nebula and/or within meteorite parent bodies. For determining the evolution of materials in the early solar system, it is of significant importance to clearly identify evidence for either nebular or planetary aqueous alteration. Therefore, results from the study of chondrites have fundamental implications for ideas concerning nebular dynamics, gas‐solid interactions in the nebula, and accretionary processes.Considering the topic of this review, it is important to define nebular and parent body processes. The solar nebula activity should include condensation processes of high‐ and low‐temperature components as well as processes of chemical fractionation and grain‐size sorting, mixing of solids and gas, and interactions between early formed solids with the remaining gas; but it should exclude processes that occurred in small uncompacted protoplanetary objects that may have been totally destroyed again before accretion of the final meteorite parent bodies. Therefore, the term “preaccretionary” instead of “nebula” is used in this paper to include all these processes that may have occurred in small precursor planetesimals.Currently, there is no doubt that parent body aqueous alteration is a fundamental process in the evolution of several groups of carbonaceous chondrites. However, due to textural and mineralogical observations and chemical analyses, strong arguments have been found also indicating preaccretionary aqueous alteration of distinct components in carbonaceous chondrites. In this paper, evidence for preaccretionary aqueous alteration in carbonaceous chondrites and their components taken from previous studies is discussed in detail.The strongest evidence for preaccretionary alteration comes from studies of CM chondrites. The survival of highly unequilibrated mineral assemblages in accretionary rims, and sharp contacts between chondrule glass and surrounding phyllosilicates, are only two important arguments for preaccretionary alteration features among many others discussed in the paper. Similar observations were also made in CR, CH and related chondrites. Due to the small abundance of water‐bearing phases in CO and CV chondrites, the origin of phyllosilicates in these groups is less clear. A preaccretionary origin of hydrous phases in Ca‐Al‐rich inclusions (CAIs) has also been suggested by several scientists. In CI chondrites, no strong indications for such processes have been found, mainly due to heavy brecciation and severe parent body alteration.
Ascent and eruption of a lunar high‐titanium magma as inferred from the petrology of the 74001/2 drill core
Authors: WEITZ Catherine M. , RUTHERFORD Malcolm J. , III James W. HEAD , McKAY David S. 
Published: February 2010

Abstract—An analysis of the orange glasses and crystallized beads from the 68 cm deep 74001/2 core has been conducted to understand the processes occurring during ascent and eruption of the Apollo 17 orange glass magma. Equilibrium between melt and metal blebs (Fe85Ni14Co1) within the core, along with Cr contents in olivine phenocrysts, suggest there was an oxidation of C and a reduction of the melt at an O fugacity of IW‐1.3 and 1320 °C to form CO gas at 200 bars or ∼4 km depth. This was followed by development of more oxidized conditions during ascent. Also during ascent, there was formation of euhedral, homogeneous Fo81olivine crystals and spinel crystals with higher Al and Mg contents than the smaller spinels in the crystallized beads. Both the metal blebs and Al‐rich spinels were trapped inside the Fo81olivine phenocrysts as they grew prior to eruption. The composition of the orange glasses are homogeneous throughout the core, except for a few distinct glasses at the top that appear to have been mixed in by micrometeorite reworking. A few glassy melt inclusions of orange glass composition trapped in the Fo81phenocrysts contain 600 ± 100 ppm S and ∼50 ppm Cl compared to the 200 ppm S and 50 ppm Cl in the orange glass melt when quenched. These inclusions therefore document the addition of 400 ppm S to the CO‐rich volcanic gas during the eruption.The size and distribution of different volcanic beads in the Apollo 17 deposit indicate a mode of eruption in which the orange glasses and partially crystallized beads formed further away from the volcanic vent where cooling rates were faster. Progressively larger and more numerous crystals in the black beads reflect slower cooling rates at higher optical densities in the volcanic plume. The development of a brown texture in the orange glasses at the bottom of the core, where the black beads dominate, is interpreted to result from devitrification by subsolidus heating either as the orange glasses fell back through the hot plume or after deposition on the surface. The change from domination by orange glasses to black beads in the core probably reflects a decrease in gas content over time, which consequently would increase the plume optical density and favor slower cooling rates.
Astronomical constraints on nebular temperatures: Implications for planetesimal formation
Authors: WOOLUM Dorothy S. , CASSEN Patrick 
Published: February 2010

Abstract—Motivated by recent observations of T‐Tauri stars and the interpretation of these observations in terms of the properties of circumstellar disks, we derive internal (midplane) temperatures for disks around mature (age ∼1 Ma) T‐Tauri stars. The estimates are obtained by combining published results for disk masses, sizes, accretion rates, and surface temperatures. For 26 stars (for which adequate data are available), we derive midplane temperatures at 1 AU primarily in the range 200–800 K, and 100–400 K at 2.5 AU. It is likely that the solar nebula, at the same stage of evolution, contained planetesimals and objects destined to become meteorite parent bodies. Observations of young stellar objects at earlier stages of evolution (age ∼0.1 Ma) imply that accretion rates were, on the average, at least two orders of magnitude greater than the 10−8M⊙/year rates typical for mature T‐Tauri stars. Such high values would result in midplane temperatures at or near the silicate vaporization temperature in the terrestrial planet region.If cooling of the solar nebula from such a hot epoch was responsible for establishing the pervasive elemental fractionation patterns found in chondritic meteorites, then objects in the asteroid belt must have grown rapidly (within 0.1 Ma) to sizes of ∼1 km, a conclusion consistent with current theories of planetesimal formation. However, the fact that primitive meteorite parent bodies escaped being melted by the decay of26Al then implies that further growth of at least some objects was essentially delayed for 2 Ma or more. Such a diminished growth rate appears to be consistent with simulations of the dynamics of solid bodies in the asteroid belt.Other hypotheses seem less attractive. One might assume that the final cooling occurred only after the decay of26Al (i.e., more than a million years after calcium‐aluminum rich inclusion formation), or that26Al was not ubiquitous in the early solar system. But the first of these conjectures is incompatible with astronomical observations of T‐Tauri systems, and the second appears to be contradicted by the evidence for26Al in diverse meteoritic components. The remaining alternative would then appear to be that, despite a lack of supporting evidence, chondritic fractionation patterns reflect the net effect of many local heating and cooling events and have nothing to do with global nebular cooling. We conclude that the most plausible hypothesis is that both nebular cooling and coagulation of solids to kilometer‐sized objects occurred rapidly and that a substantial number of planetesimals in the asteroid belt remained smaller than a few kilometers in radius for at least 2 Ma.
Amino acid survival in large cometary impacts
Authors: PIERAZZO E. , CHYBA C. F. 
Published: February 2010

Abstract— A significant fraction of the Earth's prebiotic volatile inventory may have been delivered by asteroidal and cometary impacts during the period of heavy bombardment. The realization that comets are particularly rich in organic material seemed to strengthen this suggestion. Previous modeling studies, however, indicated that most organics would be entirely destroyed in large comet and asteroid impacts. The availability of new kinetic parameters for the thermal degradation of amino acids in the solid phase made it possible to readdress this question.We present the results of new high‐resolution hydrocode simulations of asteroid and comet impact coupled with recent experimental data for amino acid pyrolysis in the solid phase. Differences due to impact velocity as well as projectile material have been investigated. Effects of angle of impacts were also addressed. The results suggest that some amino acids would survive the shock heating of large (kilometer‐radius) cometary impacts. At the time of the origins of life on Earth, the steady‐state oceanic concentration of certain amino acids (like aspartic and glutamic acid) delivered by comets could have equaled or substantially exceeded concentrations due to Miller‐Urey synthesis in a CO2‐rich atmosphere. Furthermore, in the unlikely case of a grazing impact (impact angle ∼5° from the horizontal), an amount of some amino acids comparable to that due to the background steady‐state production or delivery would be delivered to the early Earth.
Leonid outburst activity 1996: A broad structure and a first occurrence of a narrow peak of fainter meteors
Authors: LANGBROEK Marco 
Published: February 2010

Abstract— In 1996, a broad outburst structure of bright Leonid meteors similar to the 1995 and the 1994 displays (Jenniskens, 1996; Langbroek, 1996b) was observed. In addition, a second narrow outburst structure of fainter meteors, which will be reported and discussed in this paper, has with certainty been observed. This observation marks the first detection of such a narrow structure in the new series of Leonid outbursts. It has a similar exponential activity behaviour and similar emphasis on fainter meteors as shown by the 1866 and 1966 Leonid storm structures. Similar narrow peaks have been observed in 1965 and 1969 (Jenniskens, 1995, 1996).The broad 1996 structure of bright meteors peaked at November 17.31 ± 0.04 (λ 235°.28 ± 0.04 (2000.0)). The additional narrow structure peaked at November 17.20 ± 0.01 (λ 235°.172 ± 0.007). The occurrence of the narrow peak can best be explained as a first modest sign of presence of the meteoroid structure that should be responsible for the expected meteor storm activity of the Leonids in 1998–1999. The appearance 0.°085 before the node of 55P/Tempel‐Tuttle suggests that the expected 1998–1999 Leonid storms might peak just before passage through the node of the comet.
Distribution of lithium, beryllium, and boron in meteoritic chondrules
Authors: HANON Pascal , CHAUSSIDON Marc , ROBERT François 
Published: February 2010

Abstract— The distribution of Li, Be, and B was studied by ion microprobe mass spectrometry in 36 chondrules from the Semarkona, Bishunpur, Allende, Clovis #1, and Hedjaz meteorites. Within a single chondrule, Li‐Be‐B concentrations can vary up to one order of magnitude. For example, in a chondrule from Hedjaz, concentrations range from 0.3 to 2.4 ppm for Li, from <0.001 to 0.17 ppm for Be, and from 0.4 to 5.5 ppm for B. Among chondrules from Semarkona and Bishunpur, clear crystal‐mesostasis partitioning was observed in nine chondrules for Li, in nine chondrules for Be, and in three chondrules for B. The heterogeneities in the distribution of Li, Be, and B in chondrules from Semarkona and Bishunpur appear to be primary features that were inherited from the chondrules' precursors and not totally obscured during the chondrules' formation. A redistribution of B was nevertheless observed at the whole‐rock scale for Allende (B‐Al2O3 correlation) and Hedjaz (B–SiO2 correlation).At the scale of bulk chondrules, a robust correlation is observed for all studied meteorites between the B/Be and the B/Li ratios, which indicates that Li and Be are much less heterogeneously distributed in chondrites than B. Mean Li, Be, and B concentrations of chondrules ([Li] ≅ 0.83+0.86 ppm; [Be] ≅ 0.0430.027 ppm; [B] ≅ 0.89+3.71‐0.72 ppm) are consistent with those of Orgueil ([Li] ≅ 1.49 ppm; [Be] ≅ 0.0249 ppm; [B] ≅ 0.87 ppm), but the mean Li/Be ratio of chondrules (24.5+6.5‐9.1) is a factor of ∼4 depleted relative to Orgueil (Li/Be ratio of ∼78). Such a depletion is puzzling because no correlation between Li and Na or B has been found as would be expected to result from volatilization processes during chondrule melting and cooling. As a consequence, the exact abundance of solar system Li remains an open question.
The South Range Breccia Belt of the Sudbury Impact Structure: A possible terrace collapse feature
Authors: SCOTT Ronald G. , SPRAY John G. 
Published: February 2010

Abstract— The South Range Breccia Belt (SRBB) is an arcuate, 45 km long zone of Sudbury Breccia in the South Range of the 1.85 Ga Sudbury Impact Structure. The belt varies in thickness between tens of meters to hundreds of meters and is composed of a polymict assemblage of Huronian Supergroup (2.49–2.20 Ga), Nipissing Diabase (2.2 Ga), and Proterozoic granitoid breccia fragments ranging in size from a few millimeters to tens of meters. The SRBB matrix is composed of a fine‐grained (∼100 μm) assemblage of biotite, quartz, and ilmenite, with trace amounts of plagioclase, zircon, titanite, epidote, pyrite, chalcopyrite, pyrrhotite, and occasionally chlorite. The SRBB hosts the Frood‐Stobie, Vermilion, and Kirkwood quartz diorite offset dykes, the former being associated with one of the largest Ni‐Cu‐PGE sulphide deposits in the world.Optical petrography and whole‐rock geochemistry concur with previous studies that have suggested that the matrix of the SRBB is derived from comminution and at least partial frictional melting of the wall rock Huronian Supergroup lithologies. Rare earth element (REE) data from all sampled lithologies associated with the SRBB exhibit crustal signatures when normalized to C1 chondrite values. Additionally, REE data from the quartz diorites, disseminated sulphides in Sudbury Breccia, and a sample of an aphanitic biotite‐hornblende tonalite dyke exhibit flat slopes when compared to the mafic and felsic norites, quartz gabbro, and granophyre units of the Sudbury Igneous Complex (SIC), which suggests that these lithologies are representative of bulk SIC melt.We suggest that the SRBB was formed by high strain‐rate (>1 m/s), gravity‐driven seismogenic slip of the inner ring of the Sudbury Impact Structure during postimpact crustal readjustment (crater modification stage). Failure of the hanging wall may have facilitated the injection of bulk SIC melt into the SRBB, along with the Ni‐Cu‐PGE sulphides of the Frood‐Stobie deposit. Postimpact Penokean (1.9–1.7 Ga) tectonism, particularly northwest‐directed shearing along the South Range Shear Zone and associated thrust faulting, could account for the present subvertical orientation of the SRBB, and the apparent lack of a connection at depth with the SIC.
Bo Xian (LL3.9): Oxygen‐isotopic and mineralogical characterisation of separated chondrules
Authors: LI Chunlai , BRIDGES John C. , HUTCHISON Robert , FRANCHI Ian A. , SEXTON Arabelle S. , OUYANG Ziyuan , PILLINGER Colin T. 
Published: February 2010

Abstract— We report the results of a mineralogical and O‐isotopic study of 362 chondrules disaggregated from the Bo Xian chondrite. The range of mineral compositions (Fa = 0.8–31.2%, mean = 23.5%, mode = 27–28%) are consistent with a reclassification of this meteorite from LL4 to LL3.9. Chondrule diameters range from 0.20 to 3.40 mm (mean = 0.74 mm) in the disaggregated population. A lower mean diameter (0.64 mm) calculated from thin‐section measurements partly reflects the high proportion of chondrule fragments. The chondrule size distribution, which is approximately log‐normal, is consistent with size‐sorting mechanisms. This sorting could be linked to the fragmentation of many chondrules on the parent body. However, in detail, the variation in diameter of different chondrule types and a hiatus in the size distribution at 0.6 mm indicate that there may have been complex controls perhaps partly being determined by the chondrule formation mechanism. Seven percent of the sectioned chondrules (102) contain chemically fractionated mineral assemblages: cristobalite‐bearing and Al‐rich. This significant degree of chemical heterogeneity probably resulted from both igneous and volatility controls.Oxygen‐isotopic compositions were determined on mineral separates and 16 of the sectioned chondrules. Three separate isotopic exchange events have been identified. The dominant one is a low‐temperature hydrous gas‐solid exchange event between 16O‐rich solid and 16O‐poor gas reservoirs that lay along a slope 1.0 line on three‐isotope plots. Partial equilibration with the gas by feldspar and cristobalite, which exchanged more rapidly than olivine or pyroxene, led to formation of a slope 0.77 mixing line for Bo Xian and other LL chondrites. Mineralogy is the dominant control on the extent of this exchange; no relationship between isotopic composition and chondrule texture or size was identified. The feldspar separate and cristobalite‐rich chondrules have the most 16O‐poor compositions. Subsequently, thermal metamorphism in the parent body led to partial isotopic equilibration between the different mineral phases. A third exchange event, predating the other two events, is probably shown by one of the Al‐rich chondrules. This has an 16O‐rich composition, lying below the terrestrial fractionation line. Another Al‐rich chondrule has a normal ordinary chondrite isotopic composition. It is not clear whether the isotopic fractionation recorded in some Al‐rich chondrules can be achieved by the dominant gas‐solid exchange. Instead, the precursor O to the mineral phases may have become 16O‐rich during an earlier phase of mass‐independent fractionation.
Mineralogical characterization of primitive, type‐3 lithologies in Rumuruti chondrites
Authors: BISCHOFF A. 
Published: February 2010

Abstract— Rumuruti (R) chondrites constitute a new, well‐established chondrite group different from the carbonaceous, ordinary, and enstatite chondrites. Many of these samples are gas‐rich regolith breccias showing the typical light‐dark structure and consist of abundant fragments of various parent‐body lithologies embedded in a fine‐grained olivine‐rich matrix. Unequilibrated type‐3 lithologies among these fragments have frequently been mentioned in various publications. In this study, detailed mineralogical data on seven primitive fragments from the R‐chondrites Dar al Gani 013 and Hughes 030 are presented. The fragments range from ∼300 μ in size up to several millimeters. Generally, the main characteristics can be summarized as follows: (1) Unequilibrated type‐3 fragments have a well‐preserved chondritic texture with a chondrule‐to‐matrix ratio of ∼1:1. Chondrules and chondrule fragments are embedded in a fine‐grained olivine‐rich matrix. Thus, the texture is quite similar to that of type‐3 carbonaceous chondrites. (2) In all cases, matrix olivines in type‐3 fragments have a significantly higher Fa content (44–57 mol%) than olivines in other (equilibrated) lithologies (38–40 mol% Fa). (3) Olivines and pyroxenes occurring within chondrules or as fragments are highly variable in composition (Fa0–65 and Fs0–33, respectively) and, generally, more magnesian than those found in equilibrated R chondrites.Agglomerated material of the R‐chondrite parent body (or bodies) was highly unequilibrated. It is suggested that the material that accreted to form the parent body consisted of chondrules and chondrule fragments, mainly having Mg‐rich silicate constituents, and Fe‐rich highly oxidized fine‐grained materials. The dominating phase of this fine‐grained material may have been Fa‐rich olivine from the beginning. The brecciated whole rocks, the R‐chondrite regolith breccias, were not significantly reheated subsequent to brecciation or during lithification, as indicated by negligible degree of equilibration between matrix components and Mg‐rich olivines and pyroxenes in primitive type‐3 fragments.
The differentiation of eucrites: The role of in situ crystallization
Authors: BARRAT J. A. , BLICHERT‐TOFT J. , GILLET PH. , KELLER F. 
Published: February 2010

Abstract— We report on major and trace element analyses of 17 eucrites, including three cumulate eucrites (Binda, Moore County, and Serra de Magé), determined by, respectively, inductively‐coupled plasma atomic emission spectrometry and inductively‐coupled plasma mass spectrometry. The results obtained for Binda and Moore County are consistent with the model of Treiman (1997) for the formation of cumulate eucrites, which holds that these meteorites were produced from a eucritic melt. Our sample of Serra de Magé contains unusually large amounts of pyroxene and probably an accessory phase rich in heavy rare earth elements and is therefore not representative of this eucrite as known from literature data.Our results for the noncumulate eucrites Bereba, Bouvante, Cachari, Caldera, Camel Donga, Ibitira, Jonzac, Juvinas, Lakangaon, Millbillillie, Padvarninkai, Pasamonte, Sioux County, and Stannern are in good agreement with literature data. The observed decoupling between major and trace elements for noncumulate eucrites can be explained by in situ crystallization during the differentiation of an asteroidal magma ocean. This model can further account for both the Nuevo Laredo and the Stannern trends but has as a consequence that none of the analyzed eucrites represents a primary melt.
Infrared, ultraviolet, and electron paramagnetic resonance measurements on presolar diamonds: Implications for optical features and origin
Authors: BRAATZ A. , OTT U. , HENNING Th. , JÄGER C. , JESCHKE G. 
Published: February 2010

Abstract— Infrared (IR) and ultraviolet (UV) absorption spectra were obtained for diamonds from the Allende and Murchison meteorites. In addition, and for the first time, electron paramagnetic resonance spectra were measured. The IR and UV data confirm the suspicion of Russell et al. (1996) that N in presolar diamonds predominantly appears in the form of dispersed N atoms, as is the case for terrestrial type Ib diamonds.In accordance with other observations, our electron paramagnetic resonance measurements suggest a high H content in presolar diamonds. The presolar diamonds most likely originated in a H‐rich region, an environment in which nanometer‐sized diamonds may be more stable than graphite (Badziag et al., 1990). This adds to the evidence—previously based mainly on the twin microstructures of presolar diamonds (Daulton et al., 1996) and the absence of graphite with the same isotopic composition as presolar diamonds (Anders and Zinner, 1993)—for a homogeneous nucleation of presolar diamonds from a gas phase.Based on our results for detection of diamonds in space, we suggest searching for the N‐induced IR and UV absorption features of type Ib diamonds. Other characteristic diamond features that could also be used to detect diamonds in space are the (‐CHn) IR absorption features due to H‐coated diamonds, as they are described by Allamandola et al. (1993) and the IR multiphonon absorption features of the diamond lattice. The multiphonon features are very weak (Edwards, 1985), but their intensity increases somewhat with increasing temperature (Collins and Fan, 1954), so perhaps a search for them is not totally hopeless.