bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Superconducting Phases in Potassium‐Intercalated Iron Selenides.
Authors: Ying Tianping , Chen Xiaolong , Wang Gang , Jin Shifeng , Lai Xiaofang , Zhou Tingting , Zhang Han , Shen Shijie , Wang Wanyan 
Published: June 2013

AbstractFrom a series of KxFe2Se2(NH3)y (x = 0.1—1.0) samples prepared by intercalation of K into β‐FeSe in liquid NH3, K0.3Fe2Se2(NH3)0.47 and K0.6Fe2Se2(NH3)0.37 are obtained as pure phases of the 44 K and 30 K superconducting systems, respectively.
ChemInform Abstract: Disorder‐Controlled Electrical Properties in the Ho2Sb1‐xBixO2 Systems.
Authors: Wang Peng L. , Kolodiazhnyi Taras , Yao Jinlei , Mozharivskyj Yurij 
Published: June 2013

AbstractSamples of the title phases are prepared over the whole composition range (x = 0—1.0) from mixtures of Ho, Sb, Bi, and Ho2O3 (pressed pellets, evacuated silica tubes, 800 °C, 48 h and 1000 °C, 20 h).
ChemInform Abstract: Ferromagnetism in the Half‐Heusler XCsBa Compounds from First‐Principles Calculations (X: C, Si, and Ge).
Authors: Lakdja Abdelaziz , Rozale Habib , Chahed Abbes , Benhelal Omar 
Published: June 2013

AbstractDFT calculations predict the title compounds to be half‐metallic ferromagnets with an integer magnetic moment of 1 μB.
ChemInform Abstract: Synthesis, Characterization of Co—Ni—Cu Trimetallic Alloy Nanocrystals and Their Catalytic Properties. Part 91.
Authors: Singh Supriya , Srivastava Pratibha , Singh Gurdip 
Published: June 2013

AbstractThe title alloy particles are prepared by addition of a solution of hydrazine and NaOH to a solution of the metal chlorides in ethylene glycol (60 °C, 1 h).
ChemInform Abstract: Disordered Co1.28Mn1.71O4 as a Visible‐Light‐Responsive Photocatalyst for Hydrogen Evolution.
Authors: Chen Zu Peng , Xing Jun , Jiang Ha Bo , Yang Hua Gui 
Published: June 2013

AbstractThe title compound is prepared by injecting a solution of NaBH4 and NaOH into an aqueous mixture of MnO2 and CoCl2.
ChemInform Abstract: Kinetically Controlling Phase Transformations of Crystalline Mercury Selenidostannates Through Surfactant Media.
Authors: Xiong Wei‐Wei , Li Pei‐Zhou , Zhou Tian‐Hua , Tok Alfred Iing Yoong , Xu Rong , Zhao Yanli , Zhang Qichun 
Published: June 2013

AbstractIt is found that the novel mercury selenidostannate (IV) undergoes a structural phase transition to the thermodynamically stable phase (V) under prolonged reaction time.
ChemInform Abstract: Synthesis, Crystal and Electronic Structures and Magnetic Properties of Li2SnMo3O8: A Novel Reduced Molybdenum Oxide Containing Mo3O13 Cluster Units.
Authors: Gall Philippe , Al Orabi Rabih Al Rahal , Guizouarn Thierry , Cuny Jerome , Fontaine Bruno , Gautier Regis , Gougeon Patrick 
Published: June 2013

AbstractSingle crystals of the quaternary title oxide are obtained by arc welding of a stoichiometric mixture of Li2MoO4, SnO2, MoO3, and Mo (Mo crucible 1650 °C, 72 h).
ChemInform Abstract: Diversity‐Oriented Enantioselective Synthesis of Highly Functionalized Cyclic and Bicyclic Alcohols.
Authors: Mao Bin , Fananas‐Mastral Martin , Lutz Martin , Feringa Ben L. 
Published: June 2013

AbstractA highly regio‐ and enantioselective Cu‐catalyzed hetero‐allylic asymmetric alkylation with functionalized Grignard reagents is developed.
ChemInform Abstract: Binap‐Silver Salts as Chiral Catalysts for the Enantioselective 1,3‐Dipolar Cycloaddition of Azomethine Ylides and Alkenes.
Authors: Mancebo‐Aracil Juan , Martin‐Rodriguez Maria , Najera Carmen , Sansano Jose M. , Costa Paulo R. R. , de Lima Evanoel Crizanto , Dias Ayres G. 
Published: June 2013

AbstractThe application of AgSbF6 in the Binap‐catalyzed enantioselective cycloaddition between azomethine ylides and alkenes is compared with previously reported analogous transformations mediated by AgClO4.
ChemInform Abstract: Diastereoselective Synthesis of β‐Heteroaryl syn‐α‐Methyl‐β‐amino Acid Derivatives via a Double Chiral Auxiliary Approach.
Authors: Bian Jianwei , Blakemore David , Warmus Joseph S. , Sun Jianmin , Corbett Matthew , Rose Colin R. , Bechle Bruce M. 
Published: June 2013

AbstractThe addition of chiral auxiliary (II) to heterocyclic tert‐butyl sulfinimines (I) proceeds with high diastereoselectivity (92—98% d.e.
ChemInform Abstract: Oxidative C—C Bond Cleavage of Aldehydes via Visible‐Light Photoredox Catalysis.
Authors: Sun Hongnan , Yang Chao , Gao Fei , Li Zhe , Xia Wujiong 
Published: June 2013

AbstractThe visible‐light mediated oxidative C—C bond cleavage of aldehydes (I) leads to the corresponding ketones (II).
ChemInform Abstract: Reduction of Alkenes Catalyzed by Copper Nanoparticles Supported on Diamond Nanoparticles.
Authors: Dhakshinamoorthy Amarajothi , Navalon Sergio , Sempere David , Alvaro Mercedes , Garcia Hermenegildo 
Published: June 2013

AbstractCopper nanoparticles supported on diamond nanoparticles are highly efficient and reusable heterogeneous catalysts for hydrogenation of styrene derivatives (I) and other alkenes to the corresponding alkane derivatives (20 examples).
ChemInform Abstract: A Formal Metal‐Free N‐Arylation via the Schmidt Reaction of Aromatic Aldehydes with an Azido Amine.
Authors: Gu Peiming , Sun Jian , Kang Xiao‐Yan , Yi Ming , Li Xue‐Qiang , Xue Ping , Li Rui 
Published: June 2013

Abstract12 examples of substituted aromatic aldehydes are reported to give the corresponding fully aryl‐migrated disubstituted formamides in good to excellent yields.
ChemInform Abstract: Concise Asymmetric Synthesis of Orthogonally Protected syn‐ and anti‐1,3‐Aminoalcohols.
Authors: Lee Jae Seung , Kim Dongeun , Lozano Lucia , Kong Suk Bin , Han Hyunsoo 
Published: June 2013

AbstractThe reaction of aldehydes (II) with novel chiral allylation reagent (I) leads to allyl carbonates (III), which are converted into orthogonally protected anti‐aminoalcohols (V) by an iridium‐catalyzed allylic amidation.
ChemInform Abstract: 1‐O‐Alkyl (Di)glycerol Ethers Synthesis from Methyl Esters and Triglycerides by Two Pathways: Catalytic Reductive Alkylation and Transesterification/Reduction.
Authors: Sutter Marc , Dayoub Wissam , Metay Estelle , Raoul Yann , Lemaire Marc 
Published: June 2013

AbstractTitle compounds (III) and (VI) are prepared from bio‐sourced methyl ethers (I) in both good yields and selectivities by two different pathways.
ChemInform Abstract: Synthesis of Hydrazine and Azapeptide Derivatives by Alkylation of Carbazates and Semicarbazones.
Authors: Garcia‐Ramos Yesica , Proulx Caroline , Lubell William D. 
Published: June 2013

AbstractInitial alkylation studies of carbazates (I) with propargyl bromide (IIa) using different bases show that superior conversion is achieved with fluorene derivative (Ib).
ChemInform Abstract: Synthesis of γ‐Azido‐β‐ureido Ketones and Their Transformation into Functionalized Pyrrolines and Pyrroles via Staudinger/Aza‐Wittig Reaction.
Authors: Fesenko Anastasia A. , Shutalev Anatoly D. 
Published: June 2013

AbstractHydrolysis of acetals of type (I) and (XII) followed by treatment with the sulfinic acid (III), α‐functionalized ketones, and urea or urea derivatives allows a simple and efficient access to γ‐azido‐β‐ureido ketones and/or their cyclic isomers.
ChemInform Abstract: One‐Step Method for the Synthesis of Aryl Olefins from Aryl Aldehydes and Aliphatic Aldehydes.
Authors: Borate Hanumant B. , Gaikwad Supriya H. , Kudale Ananada S. , Chavan Subhash P. , Pharande Shrikant G. , Wagh Vitthal D. , Sawant Vikram S. 
Published: June 2013

AbstractThe reaction of aromatic aldehydes with aliphatic ones in the presence of malononitrile proceeds via Knoevenagel products as intermediates (reaction mechanism).
ChemInform Abstract: Palladium‐Catalyzed Trifluoroethylation of Terminal Alkynes with 1,1,1‐Trifluoro‐2‐iodoethane.
Authors: Feng Yi‐Si , Xie Chuan‐Qi , Qiao Wen‐Long , Xu Hua‐Jian 
Published: June 2013

AbstractAn efficient Pd‐catalyzed 2,2,2‐trifluoroethylation reaction of terminal alkyl and aryl alkynes using readily available trifluoroiodoethane is developed.
ChemInform Abstract: Evidence for Metal—Ligand Cooperation in a Pd—PNF Pincer‐Catalyzed Cross‐Coupling.
Authors: Scharf Adam , Goldberg Israel , Vigalok Arkadi 
Published: June 2013

AbstractThe first Pd‐pincer complex bearing a fluorine atom (PPC) is prepared via dearomatization of a phosphine‐quinoline precursor (not shown).
ChemInform Abstract: Iron‐Catalyzed Aromatic Amination for Nonsymmetrical Triarylamine Synthesis.
Authors: Hatakeyama Takuji , Imayoshi Ryuji , Yoshimoto Yuya , Ghorai Sujit K. , Jin Masayoshi , Takaya Hikaru , Norisuye Kazuhiro , Sohrin Yoshiki , Nakamura Masaharu 
Published: June 2013

AbstractThe key to the success of this novel protocol is the use of in situ generated magnesium amides in the presence of a lithium halide, which dramatically increases the product yield.
ChemInform Abstract: One‐Pot Synthesis of Aryloxypropanediols from Glycerol: Towards Valuable Chemicals from Renewable Sources.
Authors: Truscello Ada M. , Gambarotti Cristian , Lauria Mirvana , Auricchio Sergio , Leonardi Gabriella , Shisodia Suresh U. , Citterio Attilio 
Published: June 2013

AbstractThe title compounds are obtained by a regioselective reaction of phenols and glycerol using diethyl carbonate as promoter.
ChemInform Abstract: Synthesis of α‐Alkylated β‐Ketoesters by Alkoxycarbonylation/Michael Addition Domino Reaction.
Authors: Wahl Benoit , Philipson Yann , Bonin Helene , Mortreux Andre , Sauthier Mathieu 
Published: June 2013

AbstractHighly functionalized α‐alkylated β‐ketoesters are prepared in a novel two‐step one‐pot domino alkoxycarbonylation and Michael addition reactions.
ChemInform Abstract: Preparation of Arylpropynamides and Their Reaction with Malonyl Acid Derivatives.
Authors: Petina Olga A. , Yakovlev Igor P. , Geffken Detlef 
Published: June 2013

AbstractMalonyl chloride reacts to give 2H‐pyranones, whereas monosubstituted derivatives give 1,3‐oxazin‐6‐ones under similar conditions.
ChemInform Abstract: Nickel‐Catalyzed Novel β,γ‐Unsaturated Nitrile Synthesis.
Authors: Tang Shan , Liu Chao , Lei Aiwen 
Published: June 2013

AbstractA novel route for the synthesis of β,γ‐unsaturated nitriles is developed using the Ni‐catalyzed direct Heck‐type coupling of alkenes with α‐cyanoalkyl bromides.
ChemInform Abstract: Synthesis of 6‐Substituted Salicylates via Biomimetic Aromatization Utilizing the Cross Metathesis of a Vinyl Dioxinone with Homoallylic Alcohols.
Authors: Blencowe Peter S. , Barrett Anthony G. M. 
Published: June 2013

AbstractIsopropyl alkyl and aryl salicylate esters (VI) and (X) are prepared by cross metathesis of vinyl dioxinone (II) with homoallylic alcohols (I) and (VII), resp., followed by oxidation and aromatization via generation and trapping of enedione‐ketenes.
ChemInform Abstract: Solvent‐Free Synthesis of α‐Amino Nitrile‐Derived Ureas.
Authors: Ventosa‐Andres Pilar , Gonzalez‐Vera Juan A. , Garcia‐Lopez M. Teresa , Herranz Rosario 
Published: June 2013

AbstractThe reaction of aminonitriles (I) with isocyanates leads to desired ureas (III) in high isolated yields, whilst crude ureas derived from aminonitriles (IV) are prone to a cyclization during chromatographic purification affording hydantoins (V).
ChemInform Abstract: Dilithium Tetrachlorocuprate(II) Catalyzed Oxidative Homocoupling of Functionalized Grignard Reagents.
Authors: Hua Si‐Kai , Hu Qiu‐Peng , Ren Jiangmeng , Zeng Bu‐Bing 
Published: June 2013

AbstractA practical method is demonstrated, which is applicable to alkyl, alkynyl, and aromatic magnesium halides.
ChemInform Abstract: Scope of the Desulfinylative Palladium‐Catalyzed Cross‐Coupling of Aryl Sulfinates with Aryl Bromides.
Authors: Ortgies Dirk H. , Barthelme Alexandre , Aly Sara , Desharnais Brigitte , Rioux Steven , Forgione Pat 
Published: June 2013

AbstractOptimized conditions are developed to provide the synthesis of biphenyls by Pd(0)‐catalyzed coupling.
ChemInform Abstract: Expedient Synthesis of Phenanthrenes via In(III)‐Catalyzed 6‐exo‐dig Cycloisomerization.
Authors: Kwon Yongseok , Cho Hyunkyung , Kim Sanghee 
Published: June 2013

AbstractNumerous functionalized phenanthrenes are obtained via In(III)‐catalyzed electrophile‐promoted nucleophilic cyclization of o‐propargylbiaryls.Various functionalized groups are tolerated on the alkynyl carbon.
ChemInform Abstract: DMAP‐Catalyzed [3 + 2] and [4 + 2] Cycloaddition Reactions Between [60]Fullerene and Unmodified Morita—Baylis—Hillman Adducts in the Presence of Ac2O.
Authors: Yang Hai‐Tao , Ren Wen‐Long , Miao Chun‐Bao , Dong Chun‐Ping , Yang Yang , Xi Hai‐Tao , Meng Qi , Jiang Yan , Sun Xiao‐Qiang 
Published: June 2013

AbstractDMAP and Ac2O‐mediated coupling of fullerene (I) with arylated and alkenylated Morita—Baylis—Hillman adducts is found to allow a new and easy access to cylopentene‐fused fullerenes.
ChemInform Abstract: Room‐Temperature Arylation of Arenes and Heteroarenes with Diaryliodonium Salts by Photoredox Catalysis.
Authors: Liu Yu‐Xia , Xue Dong , Wang Jia‐Di , Zhao Cong‐Jun , Zou Qing‐Zhu , Wang Chao , Xiao Jianliang 
Published: June 2013

AbstractAryl radicals, generated by Ru‐catalyzed photolytic cleavage of diaryliodonium salt, undergo efficient coupling with arenes and hetarenes to afford a wide range of biaryls.
ChemInform Abstract: α‐Lithiation—Electrophile Trapping of N‐Thiopivaloylazetidin‐3‐ol: Stereoselective Synthesis of 2‐Substituted 3‐Hydroxyazetidines.
Authors: Hodgson David M. , Pearson Christopher I. , Thompson Amber L. 
Published: June 2013

AbstractTreatment of the azetidinol (I) with sBuLi followed by reaction with various electrophiles results in stereoselective formation of 2,3‐trans‐substituted derivatives with exception of CD3OD which predominantly yields the cis‐product.
ChemInform Abstract: Ruthenium‐Triggered Ring Opening of Ethynylcyclopropanes: [3 + 2] Cycloaddition with Aldehydes and Aldimines Involving Metal Allenylidene Intermediates
Authors: Miyake Yoshihiro , Endo Satoshi , Moriyama Taichi , Sakata Ken , Nishibayashi Yoshiaki 
Published: June 2013

AbstractThe title reaction of ethynylcyclopropanes with aldehydes and aldimines gives the corresponding 2‐ethynyltetrahydrofurans or ‐pyrrolidines in high yields.
ChemInform Abstract: Hydroxorhodium/Chiral Diene Complexes as Effective Catalysts for the Asymmetric Arylation of 3‐Aryl‐3‐hydroxyisoindolin‐1‐ones.
Authors: Nishimura Takahiro , Noishiki Akira , Ebe Yusuke , Hayashi Tamio 
Published: June 2013

AbstractTitle reaction leads to isoindoline‐1‐ones bearing an α‐triaryl‐substituted stereogenic center in the presence of a hydroxorhodium/chiral diene catalyst.
ChemInform Abstract: Copper‐Promoted Decarboxylative Direct C3‐Acylation of N‐Substituted Indoles with α‐Oxocarboxylic Acids.
Authors: Yu Lin , Li Pinhua , Wang Lei 
Published: June 2013

AbstractIndole derivatives bearing a highly electron‐withdrawing cyano group or a free NH moiety failed to give the described acylation.
ChemInform Abstract: Sequential Deprotection—Cyclization Reaction: Stereoselective Synthesis of Azabicyclic β‐Enamino Ester Derivatives and (—)‐Indolizidine 209D.
Authors: Ponpandian Thanasekaran , Muthusubramanian Shanmugam 
Published: June 2013

AbstractThe key reaction in the present approach involves deprotection and subsequent ring closure of N‐Boc amino‐β‐ketoesters.
ChemInform Abstract: One‐Pot Synthesis of Disubstituted Imidazole Derivatives from α‐Azido Ketones Catalyzed by Potassium Ethylxanthate.
Authors: Chen Jun , Chen Wenteng , Yu Yongping , Zhang Guolin 
Published: June 2013

AbstractDimerization of aryl‐ or alkyl glyoxal imines generated in situ from α‐azido ketones in the presence of potassium ethylxanthate gives rise to new imidazole derivatives.
ChemInform Abstract: “All‐Water” One‐Pot Diverse Synthesis of 1,2‐Disubstituted Benzimidazoles: Hydrogen Bond Driven ′Synergistic Electrophile—Nucleophile Dual Activation′ by Water.
Authors: Kommi Damodara N. , Jadhavar Pradeep S. , Kumar Dinesh , Chakraborti Asit K. 
Published: June 2013

AbstractThe regiodefined synthesis of title compounds (IV) via a tandem arylaminoarylation‐reduction‐cyclization sequence is described.
ChemInform Abstract: Copper‐Catalyzed Synthesis of 2‐Arylbenzoxazoles in Tetrabutylammonium Bromide.
Authors: Ali Md Ashif , Suri Mamta , Punniyamurthy Tharmalingam 
Published: June 2013

AbstractThe cyclocondensation of 1‐bromo‐2‐iodobenzenes with benzamides is studied under conditions A).
ChemInform Abstract: Conjugate Addition versus Cycloaddition/Condensation of Nitro Compounds in Water: Selectivity, Acid—Base Catalysis, and Induction Period.
Authors: Guideri Luca , De Sarlo Francesco , Machetti Fabrizio 
Published: June 2013

AbstractThe reaction of nitroacetic esters or amides with electron‐deficient dipolarophiles in water affords selectively isoxazole derivatives as a result of cycloaddition‐condensation.
ChemInform Abstract: Copper(II) Triflate Promoted Multicomponent Catalytic Clubbing of Piperazinyl‐Thiazoloquinolines and Thiazolocoumarins as Antimicrobials.
Authors: Patel Rahul V. , Patel Jigar K. , Nile Shivraj H. , Park Se Won 
Published: June 2013

Abstract38 Title compounds of type (IV) and (VI) are prepared.
ChemInform Abstract: Palladium‐Catalyzed Cross‐Coupling of 1,4‐Disubstituted 5‐Iodo‐1,2,3‐triazoles with Organotin Reagents.
Authors: Carcenac Yvan , David‐Quillot Franck , Abarbri Mohamed , Duchene Alain , Thibonnet Jerome 
Published: June 2013

AbstractThe desired 5‐vinyl‐1,2,3‐triazoles can be prepared as synthetically important subunits in an efficient manner from title compounds (III).
ChemInform Abstract: Enantioselective Synthesis of 3,4‐Disubstituted cis‐ and trans‐1,2,5‐Thiadiazolidine‐1,1‐dioxides as Precursors for Chiral 1,2‐Diamines.
Authors: Schuettler Christian , Li‐Boehmer Zhen , Harms Klaus , von Zezschwitz Paultheo 
Published: June 2013

AbstractFor the first time the transformation in both cis‐ and trans‐thiadiazolines is achieved via diastereoselective hydride addition [(II) → (III)] and subsequent novel isomerization [(III) → (IV)].
ChemInform Abstract: Unusual Annulation Reaction of Electron‐Deficient Alkenes with Enamines: An Easy Access to Stereocontrolled 4‐Fluoroalkylated 3,4‐Dihydro‐2H‐pyrans.
Authors: Morigaki Atsunori , Tsukade Kazuki , Arimitsu Satoru , Konno Tsutomu , Kubota Toshio 
Published: June 2013

AbstractThe one‐pot reaction of enamines (I) and (VII) with enones (II) and (V) affords 4‐fluoroalkylated dihydropyrans as major products.
ChemInform Abstract: Palladium‐Catalyzed Cascade Reactions of 3‐Iodochromones with Aryl Iodides and Norbornadiene Leading to Annulated Xanthones.
Authors: Cheng Ming , Yan Jianwei , Hu Feng , Chen Hong , Hu Youhong 
Published: June 2013

AbstractThe reaction is proposed to proceed via an initial Heck reaction followed by a sp2‐sp3‐coupling, reductive elimination and a final retro‐Diels—Alder step.
ChemInform Abstract: Design, Synthesis and Biological Evaluation of Novel 7‐Mercaptocoumarin Derivatives as α1‐Adrenoceptor Antagonists.
Authors: Xie Sai‐Sai , Wang Xiao‐Bing , Li Jiang‐Yan , Kong Ling‐Yi 
Published: June 2013

AbstractStarting compound (I) is prepared in a 4‐step sequence from resorcinol.
ChemInform Abstract: Direct Site‐Selective Arylation of Enamides via a Decarboxylative Cross‐Coupling Reaction.
Authors: Gigant Nicolas , Chausset‐Boissarie Laetitia , Gillaizeau Isabelle 
Published: June 2013

AbstractThe mono‐ or difunctionalization by the new site‐selective arylation of enamides can be controlled by the electronic density of protecting group on the N‐atom.
ChemInform Abstract: A Versatile C—H Functionalization of Tetrahydroisoquinolines Catalyzed by Iodine at Aerobic Conditions.
Authors: Dhineshkumar Jayaraman , Lamani Manjunath , Alagiri Kaliyamoorthy , Prabhu Kandikere Ramaiah 
Published: June 2013

AbstractA novel iodine‐catalyzed oxidative cross‐coupling reaction of tetrahydroisoquinolines with various nucleophiles is described and a tentative reaction mechanism involving a radical intermediate is discussed briefly.
ChemInform Abstract: Molecular Iodine Catalyzed Cross‐Dehydrogenative Coupling Reaction Between Two sp3 C—H Bonds Using Hydrogen Peroxide.
Authors: Nobuta Tomoya , Tada Norihiro , Fujiya Akitoshi , Kariya Atsumasa , Miura Tsuyoshi , Itoh Akichika 
Published: June 2013

AbstractA variety of 1‐substituted N‐aryltetrahydroisoquinolines is synthesized by aza‐Henry and by oxidative Mannich reactions.
ChemInform Abstract: “Base Effect” in the Auto‐Tandem Palladium‐Catalyzed Synthesis of Amino‐Substituted 1‐Methyl‐1H‐α‐carbolines.
Authors: Yadav Ashok K. , Verbeeck Stefan , Hostyn Steven , Franck Philippe , Sergeyev Sergey , Maes Bert U. W. 
Published: June 2013

AbstractA regioselective auto‐tandem Pd‐catalyzed process consisting of intramolecular direct arylation and a consecutive intermolecular Buchwald‐Hartwig reaction is developed.
ChemInform Abstract: One‐Pot Three‐Component Synthesis of Functionalized Spirooxindoles in Gluconic Acid Aqueous Solution.
Authors: Guo Rui‐Yun , Wang Ping , Wang Guo‐Dong , Mo Li‐Ping , Zhang Zhan‐Hui 
Published: June 2013

AbstractThis is a general, efficient, and green method for the synthesis of the title compounds in high yields.
ChemInform Abstract: Efficient Access to 2,7‐Diarylated Pyrido[3,2‐d]pyrimidines Involving Regioselective Pallado‐dehalogenation and Suzuki Cross‐Coupling Reactions.
Authors: Tikad Abdellatif , Dehbi Oussama , Akssira Mohamed , Aadil Mina , Massip Stephane , Leger Jean‐Michel , Jarry Christian , Guillaumet Gerald , Routier Sylvain 
Published: June 2013

AbstractThe selective monodechlorination of substrate (I) to the 2,7‐dichloro derivative (II) is developed and mono‐ and bis‐coupling reactions of the latter are studied.
ChemInform Abstract: Multifold Bond Cleavage and Formation Between MeOH and Quinoxalines (or Benzothiazoles): Synthesis of Carbaldehyde Dimethyl Acetals.
Authors: Liu Yunkui , Jiang Bo , Zhang Wei , Xu Zhenyuan 
Published: June 2013

AbstractK2S2O8‐mediated treatment of various quinoxalines with MeOH allows a convenient, acid‐, aldehyde‐, and transition metal‐free access to carbaldehyde dimethyl acetals of type (III).
ChemInform Abstract: Palladium‐Catalyzed Oxidative Cycloaddition Through C—H/N—H Activation: Access to Benzazepines.
Authors: Wang Lei , Huang Jiayao , Peng Shiyong , Liu Hui , Jiang Xuefeng , Wang Jian 
Published: June 2013

AbstractBenzazepines are readily prepared by a one‐pot palladium‐catalyzed oxidative cycloaddition of isatins with various alkynes.
ChemInform Abstract: Synthesis of Novel Benzotriazoloazepine Derivatives.
Authors: Zhang Wei , Han Rong‐Bi , Zhang Wen‐Bin , Jiang Ri‐Shan , Piao Feng‐Yu 
Published: June 2013

AbstractBenzotriazoloazepine derivatives with different anticonvulsant activities are synthesized starting from 7‐methoxy‐2,3,4,5‐tetrahydro‐1H‐2‐benzo[c]azepin‐1‐one (I).
ChemInform Abstract: Chiral NHC/Cu(I)‐Catalyzed Asymmetric Hydroboration of Aldimines: Enantioselective Synthesis of α‐Amido Boronic Esters.
Authors: Zhang Shu‐Sheng , Zhao Yi‐Shuang , Tian Ping , Lin Guo‐Qiang 
Published: June 2013

AbstractThe transformation proceeds smoothly at room temperature providing the desired esters (III) with enantioselectivities up to 84%.
ChemInform Abstract: Bespoke Synthesis of Unsymmetrical Diaminoboranes by Alkaline Earth Catalysis.
Authors: Bellham Peter , Hill Michael S. , Kociok‐Koehn Gabriele , Liptrot David J. 
Published: June 2013

AbstractCa or Mg(NTms2)2 are found to be effective catalysts for the formation of unsymmetrical diaminoboranes (III), by dehydrocoupling of amine boranes (I) and protic amines (II).
ChemInform Abstract: Synthesis of Cyclic α‐Aminophosphonates Through Copper‐Catalyzed Enamine Activation.
Authors: Han Junbin , Paton Robert S. , Xu Bo , Hammond Gerald B. 
Published: June 2013

AbstractThe methodology represents a convenient approach to α‐phosphoryl‐substituted 5‐ and 6‐membered N‐heterocycles, which are of biological significance.
ChemInform Abstract: Collective Total Synthesis of Englerin A (Ia) and B (Ib), Orientalol E (Ic) and F (II), and Oxyphyllol (Id): Application of the Organocatalytic [4 + 3] Cycloaddition Reaction.
Authors: Wang Jie , Chen Shu‐Guang , Sun Bing‐Feng , Lin Guo‐Qiang , Shang Yong‐Jia 
Published: June 2013

AbstractThe key step of this synthesis of the title compounds (respectively their enantiomers) is an organocatalyzed asymmetric [4 + 3] cycloaddition yielding key intermediate (V).