bluuebunny/crossref_metadata_2025_split huggingface dataset:
Clinical relevance of aortic conduit and reservoir function
Authors: Assadi Hosamadin , Sawh Chris , Spohr Hilmar , Nelthorpe Faye , Nair Sunil , Hughes Marina , Ashman David , Ryding Alisdair , Matthews Gareth , Li Rui , Grafton-Clarke Ciaran , Mehmood Zia , Al-Mohammad Abdallah , Kasmai Bahman , Vassiliou Vassilios S , Garg Pankaj 
Published: August 2024

BackgroundAortic conduit and reservoir functions can be directly measured by four-dimensional flow (4D flow) cardiovascular magnetic resonance (CMR).MethodsTwenty healthy controls (10 young and 10 age-gender-matched old controls) and 20 patients with heart failure with preserved ejection fraction (HFpEF) were recruited. All had 4D flow CMR. Flow was quantified at the ascending and descending aorta levels. In addition, at the ascending aorta level, we quantified systolic flow displacement (FDs) and systolic flow reversal ratio (sFRR). The aortic conduit function was defined as the relative drop in systolic flow from the ascending to the descending aorta (∆Fs). Aortic reservoir function was defined as descending aortic diastolic stroke volume (DAo SVd).ResultsBoth ∆Fs (R=0.51, p=0.001) and DAo SVd(R=−0.68, p=0.001) were significantly associated with ageing. Native T1 (R=0.51, p=0.001) and extracellular volume (R=0.51, p=0.001) showed maximum association with ∆Fs. ∆Fs significantly increased in HFpEF versus age-gender-matched controls (41±8% vs 52±12%, p=0.02). In multiple regression, only ∆Fs and DAo SVdwere independent predictors of the estimated glomerular filtration rate (model R=0.77, p=0.0001). FDs was significantly associated with ∆Fs (R=0.4, p=0.01) and DAo SVd(R=−0.48, p=0.002), whereas sFRR was mainly associated with DAo SVd(R=−0.46, p=0.003).ConclusionBoth aortic conduit and reservoir function decline with age and this decline in aortic function is also independently associated with renal functional decline. Ascending aortic turbulent flow signatures are associated with loss of aortic conduit and reservoir functions. Finally, in HFpEF, aortic conduit and reservoir function demonstrate progressive decline.Trials registration numberNCT05114785.
Investigating the relationship between emotions and physical literacy in a quality physical education context
Authors: Woolley Adam , Houser Natalie , Kriellaars Dean 
Published: August 2024

Affective experiences have been shown to influence attitudes and future behaviors related to physical activity, but no studies have related these experiences to physical literacy or examined affective experiences in quality physical education (QPE). The aim of this study was to describe emotions experienced in a QPE context and relate those emotions to students’ physical literacy and self-esteem. A cross-sectional study of 145 4th and 5th grade students was surveyed after a single PE class on their emotional experiences (positive emotions: pride, enjoyment, and relief; negative, emotions: shame, anger, and boredom; aggregate emotional experience as the sum of positive and negative emotions) physical literacy (self-description and movement valuation) and self-esteem. In this QPE context, 73% of students reported only positive emotions, 26% mixed positive and negative emotions and 1% expressed only negative emotions. Pride and enjoyment were strongly co-occurring (89%). Among students expressing mixed emotions, 90% still yielded positive aggregate emotional experiences. Positive emotions have significant ( p < 0.001), moderate to strong positive correlations with physical literacy (rho = 0.65 pride, 0.50 enjoyment) and self-esteem (rho = 0.48 pride, 0.38 enjoyment), and negative emotions have significant ( p < 0.001), moderate negative correlations with physical literacy (rho = −0.47 shame, −0.30 anger, −0.32 boredom) and self-esteem (rho = −0.33 shame, −0.29 anger, −0.21 boredom). This study reveals strong positive emotional responses by students in a purported QPE context. The presence of mixed emotions with net positive aggregate experiences highlights the importance of consideration of both negative and positive emotions in movement contexts. Affective states have been proposed as key elements of physical literacy, and this study supports this through valence matched associations between both positive/negative affect with physical literacy and self-esteem.
Photon propagation in a charged Bose–Einstein condensate model
Authors: Nieves José F. , Sahu Sarira 
Published: August 2024

AbstractWe consider the propagation of photons in a model of a charged scalar Bose-Einstein (BE) condensate. We determine the dispersion relations of the collective modes, as well as the photon polarization tensor and the dielectric constant in the model. Two modes correspond to the transverse photon polarizations, with dispersion relations of the usual form for transverse photons in a plasma. The other two modes, denoted as the $$(\pm )$$

(
±
)

modes, are combinations of the longitudinal photon and the massive scalar field. Their dispersion relations behave very differently as functions of momentum. The $$(+)$$

(
+
)

mode dispersion relation increases steadily and remains greater than the momentum as the momentum increases. The dispersion relation of the $$(-)$$

(
-
)

mode decreases in a given momentum range, with the group velocity being negative in that range, while in another range it increases steadily but remains smaller than the momentum, akin to the situation in a medium with an index of refraction greater than 1. We consider the non-relativistic limit of the $$(\pm )$$

(
±
)

dispersion relations and discuss some aspects of the results. We also determine the wavefunctions of the $$(\pm )$$

(
±
)

modes, which are useful to obtain the corrections to the dispersion relations, e.g., imaginary parts due to the damping effects and/or the effects of scattering, due to the interactions with the excitations of the system. The results can be useful in various physical contexts that have been considered in the literature involving the electrodynamics of a charged scalar BE condensate.
(Invited) 1D Oxides for Energy, Environment, and Biomedical Applications: Are They as Good as They Appear?
Authors: Subramanian Vaidyanathan 
Published: August 2024

1D oxides demonstrate interesting optical, electronic, catalytic, and surface properties. They are interesting not only because they can be synthesized using cost effective methods but also appear to be useful in several technological processes. They are also amenable to doping, composite formation, and assembly as heterostructures with a variety of elements as well as pre-formed materials such as dyes, metals, and non-metals.
This talk will feature representative examples of 1D oxides and their composites in the field of energy, environment, and biomedical applications. Key findings using Titanium dioxide as the compound of focus will be highlighted. Research in this field from our group will be presented. Specific focus will be on the work involving former and current collaborators associated with India This presentation will also look into examples of work in the area that suggest not so promising benefits of these 1D oxides, thus raising the question of its actual benefits.
Ab Initio calculations of Low-Energy Quasiparticle Lifetimes in Bilayer Graphene
Authors: Spataru Catalin D. , Leonard Francois 
Published: August 2024

Motivated by recent experimental results
we calculate from first-principles the lifetime of low-energy quasiparticles in bilayer graphene (BLG). We take into account the scattering rate arising from electron-electron interactions within the GW approximation for the electron self-energy and consider several p-type doping levels ranging from 0 to ~ 2.4x1012 holes/cm2. In the undoped case we find that the average inverse lifetime scales linearly with energy away from the charge neutrality point, with values in good agreement with experiments. The decay rate is approximately three times larger than in monolayer graphene, a consequence of the enhanced screening in BLG.
In the doped case, the dependence of the inverse lifetime on quasiparticle energy acquires a non-linear component due to the opening of an additional decay channel mediated by acoustic plasmons.
This work was supported by the LDRD program at Sandia National Laboratories (SNL). SNL is a multimission laboratory managed and operated by National Technology and Engineering Solutions of Sandia, LLC., a wholly owned subsidiary of Honeywell International, Inc., for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-NA0003525.
The views expressed in the article do not necessarily represent the views of the U.S. Department of Energy or the United States Government.
(Invited) Two-Dimensional Layered Materials and Their Mixed-Dimensional Hybrids for Electrochemical Applications
Authors: Yao Fei 
Published: August 2024

Compared with their 3D counterparts, two-dimensional (2D) van der Waals (vdW) materials exhibit quantum confinement where charge carriers are spatially confined at the physical boundaries. Particularly, when mixing 2D materials with other low-dimensional (LD) materials, they exhibit enormous potential in electrochemical energy applications due to the unique properties arising from reduced dimensionality and, more importantly, material integration synergy.
In this work, 2D transition metal dichalcogenides (MoS2) and their mixed low-dimensional hybrids (MLDHs) are introduced with an emphasis on the hybrid structure construction using the one-step solvothermal synthesis technique and their electrochemical applications. Fundamental insight into the synergistic effect of the MLDHs integration in terms of active site exposure, surface area enlargement, electrical conductivity improvement, and structural phase engineering for advancing the development of Li-ion batteries (LIBs) and electrocatalytic hydrogen evolution reaction (HER) will also be discussed. Specifically, in the case of LIBs, 2D-based binary hybrids (i.e., MoS2/MXene) deliver a Li-ion storage capacity of 540 mA h g−1 at 100 mA g−1 and a stable cycle performance up to 300 cycles. In sharp contrast, the 2D-based ternary MLDHs (i.e., MoS2/MXene/CNT) exhibit a higher Li-ion storage capacity (1500 mAh g−1 at 100 mA g−1), outstanding cycle stability (up to 300 cycles) and excellent rate capability (500 mAh g−1 at 4000 mA g−1) as an anode of LIBs. In the case of HER, the MLDH heterostructures show an overpotential of 169 mV with a low Tafel slope of 51 mV/dec and can be cycled to 1000 cycles. Leveraging the unique microreactor platform based on the 2D vdW platform, a mechanistic understanding of charge transport dynamics at the electrified electrode and current collector interface will be highlighted.
The knowledge gained on how mixed-dimensional physics and chemistry will shed light on the design principle of the electrode materials for electrochemical energy storage and conversion and deepen the understanding of the process-structural-property-performance (PSPP) relationship of the vdW-based hybrid structures.
Atomically Precise Vacancy Lattices in Epitaxially Grown FeBr2 and CoBr2 on Au(111)
Authors: Maier Sabine 
Published: August 2024

The generation of extensive 2D periodic patterns of point defects in 2D materials, such as vacancy lattices, has been a challenging task until now. Here, we report on 2D transition metal dihalides grown epitaxially on Au(111) featuring periodically assembled halogen vacancies that result in alternating coordination of the transition metal ion and can function as antidot lattices. [1] Using low-temperature STM/ncAFM and LEED, we identified the structural properties of intrinsically patterned FeBr2 and CoBr2 monolayers grown epitaxially on Au(111). Density-functional theory indicates that Br-vacancies are favored due to low formation energies, and the formation of a vacancy lattice substantially reduces the lattice mismatch with the underlying Au(111). We demonstrate that interfacial strain engineering presents a versatile strategy for controlled patterning in 2D with atomic precision over several hundred nanometers to solve a longstanding challenge of growing atomically precise antidot lattices.
[1] https://doi.org/10.48550/arXiv.2305.06489
(Invited) Synthesis of Multi-Metallic Nanoparticles for Advanced Catalysts
Authors: Yamamoto Kimihisa 
Published: August 2024

Dendrimers are highly branched organic macromolecules with successive layers or “generations” of branch units surrounding a central core. Organic inorganic hybrid versions have also been produced, by trapping metal ions or metal clusters within the voids of the dendrimers. Their unusual, tree-like topology endows these nanometer-sized macromolecules with a gradient in branch density from the interior to the exterior, which can be exploited to direct the transfer of charge and energy from the dendrimer periphery to its core.
We show that PtCl4, SnCl2, FeCl3, and so on complexes to the imines groups of a spherical polyphenylazomethine dendrimer in a stepwise fashion according to an electron gradient, with complexation in a more peripheral generation proceeding only after complexation in generations closer to the core has been completed. By attaching an electron-withdrawing group to the dendrimer core, we are able to change the complexation pattern, so that the core imines are complexed last. By further extending this strategy, it should be possible to control the number and location of metal ions incorporated into dendrimer structures, which might and uses as tailored catalysts, building blocks, or fine-controlled clusters for advanced materials. The metal-assembly in a discrete dendrimer molecule can be converted to a size-regulated metal particle with a size smaller than 1 nm as a molecular reactor. Due to the well-defined number of metal clusters in the subnanometer region, its property is much different from that of bulk or general metal nanoparticles. The chemistry of nanocatalysts on the sub-nanometer scale is not yet well understood because precise multi-metallic nanoparticles are difficult to synthesize with control over size and composition. The template synthesis of multi-metallic sub-nanocalaysts is achieved using a phenylazomethine dendrimer as a macromolecular template.
On-Surface Synthesis of Macrocycles, Non-Planar Carbon Ribbons and Heteroatom-Doped Nanographenes
Authors: Maier Sabine 
Published: August 2024

On-surface synthesis via covalent coupling of adsorbed molecules on metal surfaces has attracted significant attention recently due to its potential to fabricate low-dimensional carbon materials with atomic precision. The bottom-up, atomically precise synthesis of carbon nanostructures enables the tailoring of their electronic properties at a molecular level. To understand and control the surface-chemistry-driven synthesis, many efforts have been made to design innovative precursors, explore novel reaction schemes, and utilize templating effects from the substrate.
My presentation focuses on high-resolution scanning probe microscopy experiments combined with density functional theory to demonstrate recent highlights on the assembly of surface-supported low-dimensional carbon structures on metal surfaces. First, the assembly and electronic structure of planar π-extended cycloparaphenylene macrocycles, representing the first nanographene with an all-armchair edge topology, will be presented [1]. The second part will discuss the bottom-up synthesis of covalently-linked non-planar carbon ribbons and their electronic properties depending on their adsorption geometry. Finally, I will conclude with the on-surface cyclomerization of oxygen heterocycles to understand the on-surface synthesis of furan and pyran derivatives from ketone-functionalized precursors on metal surfaces.
[1] Xiang, et al. Nature Chem., 2022 14, 871–876.
(Invited) The Evolving SiC Market and Impact on CMP Supply Chain
Authors: Rhoades Robert 
Published: August 2024

Silicon carbide (SiC) is a wide bandgap semiconductor with physical and electrical properties that provide superior performance in high-voltage or high-power applications. Compared to the more established silicon devices, SiC provides better thermal conductivity, ~10x higher breakdown voltage, faster switching speeds and lower resistivity. Even with the performance advantages, the adoption rate of SiC is slowed by high cost and the inherent difficulty of processing this material. SiC is extremely hard (just below diamond on the hardness scale) and chemically inert which makes processing boules into wafers rather difficult. This presentation will contrast some of the basic differences between process methods developed for silicon and other semiconductor materials versus those required for SiC.
Demand for high-quality single crystal SiC substrates continues to rise as the worldwide demand for electric vehicles, charging infrastructure, green energy production, and more efficient power devices in general requires more and more SiC devices. SiC wafer manufacturers are trying to ramp output as quickly as possible but technical difficulties of processing SiC are often a limiting factor. In spite of aggressive capital spending by many of the major players, the actual growth in substrate production has been constrained to around 15% CAGR even though demand would support a much faster ramp. As end use markets continue to evolve, ripple effects are also evident in the underlying supply chains, such as CMP pads and slurries.
(Invited) Core-Multi-Shell Design: Unlocking Multimodal Capabilities in Lanthanide-Based Nanoparticles
Authors: Liu Nan , Puccini Abigale , Homann Christian , Hemmer Eva 
Published: August 2024

The remarkable optomagnetic properties of the lanthanides (Ln) make Ln-based materials ideal for biomedical applications, including diagnostic (e.g., imaging, nanothermometry) and therapeutic (e.g., drug delivery, photodynamic therapy) approaches. This is due the unique electronic properties of the f-elements allowing for upconversion and near-infrared emission under near-infrared excitation as well as high magnetic moments. Yet, challenges remain, including low emission intensity and efficiency of small nanoparticles (NPs), and reliable, fast synthesis routes. As material chemists, we tackle these challenges with new designs of Ln-NPs by chemically controlled synthesis, application-oriented surface chemistry, and understanding of structure-property-relationships. We developed a straightforward and rapid microwave-assisted synthesis approach towards core-multi-shell Ln-NPs. Careful architecture design and choice of RE3+ dopant ions allow to tune the optical properties of the resultant nanoparticles, i.e., upconversion and near-infrared emission. This presentation will shed light on recent results with respect to microwave-assisted synthesis of Ln-NPs as well as structural and optomagnetic properties, seeking biomedical application.
For instance, multimodal bioimaging probes merging optical imaging, magnetic resonance imaging (MRI), and X-ray computed tomography (CT) capabilities have attracted considerable attention due to their potential biomedical applications. This includes nanoparticles that combine upconverting Er3+/Yb3+ and magnetic NaDyF4 for optical/T2-weighted MRI/CT multimodal capabilities. A known drawback of multimodal probes that merge the upconverting Er3+/Yb3+ ion pair with magnetic Dy3+ ions for T2-weighted MRI is the loss of upconversion emission due to Dy3+ poisoning. The synthesis of controlled nanoparticle architectures with tuned inner NaGdF4 shell thicknesses separating Dy3+ and Er3+/Yb3+ allow to shed light on this distance-dependent loss of upconversion due to Yb3+ → Dy3+ energy transfer. As a result, the Ln-NP architecture was tuned to not only restore but enhanced the upconversion emission. In addition to multimodal imaging, Ln-NPs are promising candidates for application in nanothermometry due to the distinct, temperature-induced changes in their spectral features. We seek the development of novel Ln-NP nanothermometers for new opportunities in the near-infrared biological transparency windows (1000 to 2000 nm), by doping RE3+ ions, such as Er3+ and Tm3+ as well as unconventional Pr3+, into core-multi-shell lanthanide-based nanoparticles.
Study on Electrochemical Characteristics of Crystal Structure Changes Effects of Silicon Anode Materials for Lithium Ion Batteries
Authors: Yang Minji , Kim Dong-Young , Shim Jae-Hyun 
Published: August 2024

Graphite is widely used as a representative anode material in commercialized lithium-ion secondary batteries. However, with a theoretical capacity of 370 mAh/g, it is difficult to manufacture high-capacity/high-density lithium-ion secondary batteries. Therefore, research is actively underway to find high-capacity substances to replace graphite. Silicon anode materials are currently attracting attention as next-generation high-capacity cathode materials. Silicon forms Li4.4Si when fully charged through an alloying/dealloying process with lithium during the reaction. Graphite is intercalation/deintercalation in reaction with lithium and LiC6 is formed when fully charged. That's why silicon has a theoretical capacity of 3800 mAh/g, about 10 times that of graphite.
However, silicon is a high-capacity electrode material that overcomes the theoretical capacity limit of graphite, and has the disadvantage of experiencing volume expansion of about 400% during repeated charge/discharge cycles. Problems such as material cracks due to volume expansion can affect the safety of the battery. Various studies are being conducted to solve silicon-related challenges to effectively utilize silicon materials. Previous studies have explored the use of binders or additives to mitigate volume expansion. In addition, various types of silicon materials such as Si alloy and SiOx are being developed to suppress volume expansion through matrix formation. Nevertheless, despite the development of silicon materials, structural changes in the charging and discharging process of silicon remain unclear.
This study aims to analyze the structural changes that occur during the charging and discharging process of silicon. The experiment evaluates the electrochemical characteristics of crystalline silicon and amorphous silicon and compares the behavior and structural changes during charging/discharging. The volumetric expansion measurements are performed with electrochemical characterization, and ex-situ X-ray diffraction (XRD) and transmission electron microscope (TEM) analyses are performed for comparison with crystal structural changes.
(Invited) Toward Ultrathin Flexible Quantum Dot Light-Emitting Diodes and Photodetectors for the Wearable Electronics
Authors: Choi Moon Kee 
Published: August 2024

Flexible optoelectronic devices, encompassing light-emitting diodes (LEDs) and photodetectors, capable of seamlessly transforming their shapes, represent a prominent trend in next-generation electronics. Quantum dots, widely employed as emitters and light absorption layers, are chosen for their high luminous performance, size-dependent color tunability, and excellent light absorption properties. Moreover, their solution processability and ultrathin form factor make them particularly appealing for the development of ultrathin wearable optoelectronic devices.
Here, we introduce ultrathin flexible quantum dot light-emitting diodes and photodetectors designed for wearable electronics. Utilizing intaglio transfer printing, we can produce high-definition red-green-blue quantum dot LEDs, suitable for integration into skin-attachable displays. Moreover, our ultrathin, self-powered, heavy-metal-free photodetectors, based on copper indium selenide nanoparticles, showcase outstanding optical performance (specific detectivity: 2.10 × 1012 Jones at zero-bias) and find application in wearable photoplethysmography (PPG) sensors.