bluuebunny/crossref_metadata_2025_split huggingface dataset:
Customized Ultrathin Oxygen Vacancy‐Rich Bi2W0.2Mo0.8O6 Nanosheets Enabling a Stepwise Charge Separation Relay and Exposure of Lewis Acid Sites toward Broad‐Spectrum Photothermal Catalysis
Authors: Yi Jiayu , Yang Xin , Shen Lijuan , Xue Hun , Yang Min‐Quan , Qian Qingrong 
Published: August 2024

AbstractDesigning robust photocatalysts with broad light absorption, effective charge separation, and sufficient reactive sites is critical for achieving efficient solar energy conversion. However, realizing these aims simultaneously through a single material modulation approach poses a challenge. Here, a 2D ultrathin oxygen vacancy (Ov)‐rich Bi2W0.2Mo0.8O6 solid solution photocatalyst is designed and fabricated to tackle the dilemma through component and structure optimization. Specifically, the construction of a solid solution with ultrathin structure initially facilitates the separation of photoinduced electron–hole pairs, while the introduction of Ov strengthens such separation. In the meantime, the presence of Ov extends light absorption to the NIR region, triggering a photothermal effect that further enhances the charge separation and accelerates the redox reaction. As such, photoinduced charge carriers in the Ov‐Bi2W0.2Mo0.8O6 are separated step by step via the synergistic action of 2D solid solution, OV, and solar heating. Furthermore, the introduction of OV exposes surface metal sites that serve as reactive Lewis acid sites, promoting the adsorption and activation of toluene. Consequently, the designed Ov‐Bi2W0.2Mo0.8O6 reveals an enhanced photothermal catalytic toluene oxidation rate of 2445 µmol g−1 h−1 under a wide spectrum without extra heat input. The performance is 9.0 and 3.9 times that of Bi2WO6 and Bi2MoO6 nanosheets, respectively.
Bi‐Directional Modification to Quench Detrimental Redox Reactions and Minimize Interfacial Energy Offset for NiOX/Perovskite‐Based Solar Cells
Authors: Das Adhikari Ramkrishna , Baishya Himangshu , Patel Mayur Jagdishbhai , Yadav Deepak , Iyer Parameswar Krishnan 
Published: August 2024

AbstractThe quality of the buried heterojunction of nickel oxide (NiOX)/perovskite is crucial for efficient charge carrier extraction and minimizing interfacial non‐radiative recombination in inverted perovskite solar cells (PSCs). However, NiOX has limitations as a hole transport layer (HTL) due to energy level mismatch, low conduction, and undesirable redox reactions with the perovskite layer, which impede power conversion efficiency (PCE) and long‐term stability. In this study, para‐amino 2,3,5,6‐tetrafluorobenzoic acid (PATFBA) is proposed as a bifacial defect passivator to tailor the NiOX/perovskite interface. The acid group and adjacent fluorine atoms of PATFBA effectively passivate NiOX surface defects, thereby improving its Ni3+/Ni2+ ratio, hole extraction capability, and energy band alignment with perovskite, while also providing active sites for homogenous nucleation. Meanwhile, the amine and adjacent fluorine atomsstabilize the buried perovskite interface by passivating interfacial defects, resulting in higher crystalline perovskite films with supressed non‐radaitive recombination. Furthermore, the PATFBA buffer layer prevents redox reactions between Ni3+ and perovskite.These synergistic bi‐directional interactions lead to optimized inverted PSCs with a PCE of 20.51% compared to 16.89% for pristine devices and the unencapsulated PATFBA‐modified devices exhibit outstanding thermal and long‐term stability. This work provides a new engineering approach to buried interfaces through the synergy of functional groups.
Electron Reservoir Effect of Adjacent Fe Nanoclusters Boosts Atomic Fe Active Sites on Porous Carbon for the Both Electrocatalytic Oxygen Reduction and CO2 Reduction Reaction
Authors: He Jiaxin , Xu Li , Qin Chenchen , Zhang Jian , Liu Daomeng , Li Qingyi , Feng Ziyi , Wang Junzhong , Liu Peigen , Li Hongbao , Yang Zhengkun 
Published: August 2024

AbstractElectrochemical oxygen reduction reaction (ORR) and carbon dioxide reduction reaction (CO2RR) are greatly significant in renewable energy‐related devices and carbon‐neutral closed cycle, while the development of robust and highly efficient electrocatalysts has remained challenges. Herein, a hybrid electrocatalyst, featuring axial N‐coordinated Fe single atom sites on hierarchically N, P‐codoped porous carbon support and Fe nanoclusters as electron reservoir (FeNCs/FeSAs‐NPC), is fabricated via in situ thermal transformation of the precursor of a supramolecular polymer initiated by intermolecular hydrogen bonds co‐assembly. The FeNCs/FeSAs‐NPC catalyst manifests superior oxygen reduction activity with a half‐wave potential of 0.91 V in alkaline solution, as well as high CO2 to CO Faraday efficiency (FE) of surpassing 90% in a wide potential window from −0.40 to −0.85 V, along with excellent electrochemical durability. Theoretical calculations indicate that the electron reservoir effect of Fe nanoclusters can trigger the electron redistribution of the atomic Fe moieties, facilitating the activation of O2 and CO2 molecules, lowering the energy barriers for rate‐determining step, and thus contributing to the accelerated ORR and CO2RR kinetics. This work offers an effective design of electron coupling catalysts that have advanced single atoms coexisting with nanoclusters for efficient ORR and CO2RR.
High‐Strength MOF‐Based Polymer Electrolytes with Uniform Ionic Flow for Lithium Dendrite Suppression
Authors: Xu Mei , Liang Shuaitong , Shi Haiting , Miao Junping , Tian Feng , Cui Wenhui , Shao Ruiqi , Xu Zhiwei 
Published: August 2024

AbstractThe uneven formation of lithium dendrites during electroplating/stripping leads to a decrease in the utilization of active lithium, resulting in poor cycling stability and posing safety hazards to the battery. Herein, introducing a 3D continuously interconnected zirconium‐based metal‐organic framework (MOF808) network into a polyethylene oxide polymer matrix establishes a synergistic mechanism for lithium dendrite inhibition. The 3D MOF808 network maintains its large pore structure, facilitating increased lithium salt accommodation, and expands anion adsorption at unsaturated metal sites through its diverse large‐space cage structure, thereby promoting the flow of Li+. Infrared‐Raman and synchrotron small‐angle X‐ray scattering results demonstrate that the transport behavior of lithium salt ion clusters at the MOF/polymer interface verifies the increased local Li+ flux concentration, thereby raising the mobility number of Li+ to 0.42 and ensuring uniform Li+ flux distribution, leading to dendrite‐free and homogeneous Li+ deposition. Furthermore, nanoindentation tests reveal that the high modulus and elastic recovery of MOF‐based polymer electrolytes contribute to forming a robust, dendrite‐resistant interface. Consequently, in symmetric battery systems, the system exhibits minimal overpotential, merely 35 mV, while maintaining stable cycling for over 1800 h, achieving low–overpotential lithium deposition. Moreover, it retains redox stability under high voltages up to 5.3 V.
The Collaborative Literacy Coaching Framework for Transformation: Humanizing Prerequisites for Reflective Practitioners
Authors: Caylor Emily C. 
Published: August 2024

AbstractLiteracy coaching is a professional learning model designed to provide teachers with supportive partnerships as they enhance their literacy instruction (L'Allier et al., 2010). However, the enhancement of instruction requires teachers to make changes to long‐standing instructional practices. To prepare for change, teachers must have the psychological safety and time to explore their beliefs, values, and identities and how these intrapersonal factors support or hinder change (Dewey, 1933). Literacy coaches can guide teachers through this preparation by using The Collaborative Literacy Coaching Framework for Transformation, which focuses on the cultivation of relationships, the examination of intrapersonal factors, the acknowledgment of how these factors impact instruction, and the need to plan for change. I will share a detailed outline of this framework and share the stories of three teachers who were better prepared for change while working within it.
NRK at FoRC 2024 Subtask I: Exploiting BERT-Based Models for Multi-class Classification of Scholarly Papers
Authors: Nguyen Tuan Kiet , Dang Van Thin 
Published: August 2024

AbstractThis study presents the system developed by team NRK for SubTask I of the Field of Research Classification (FoRC) - NLSP 2024. The task focuses on single-label, multi-class classification of general scholarly papers. Our approach exploits the capabilities of various pre-trained BERTopology models, combined with a straightforward ensemble voting scheme to enhance classification performance. The proposed system achieved competitive results, ranking within the Top 5 on the final scoreboard.
The Art of Transformation: Enabling Organisational Change in Healthcare Through Design Thinking, Appreciative Inquiry, and Creative Arts-Based Visual Storytelling
Authors: Miller Evonne , Johnstone Sarah , Winter Abigail 
Published: August 2024

AbstractThis chapter tells the story of a complex organisational change to a healthcare service, splitting rehabilitation functions across two hospitals in the same region. The design project was developed to help the healthcare providers (clinicians, nurses, and allied health professionals) from both hospitals reach an understanding of the strengths that each hospital provided to its patients, with one large hospital in a busy metropolitan area and the other a small hospital in a rural area. Using arts-based design methods including design thinking, workshops, journey maps, and photovoice experiences from both providers and consumers, the HEAL team were able to help the rehabilitation service providers see the value in the requirements of the organisational change and the potential benefits in the new distributed service.
Graphics and Icons for Healthcare with a Focus on Cultural Appropriateness, Diversity, and Inclusion
Authors: Scharoun Lisa , Ryan Zoe , Miller Evonne 
Published: August 2024

AbstractThis chapter describes a project to re-work two existing posters used in Emergency Departments across Queensland. The posters depicted how to provide a urine sample, using both text and graphics. After user testing, the Princess Alexandra Hospital worked with the QUT Design Lab to redevelop the two posters (male and female) into one that used gestural drawing (rather than graphically explicit images) and specific colours to make the urine sample collection process simpler for all consumers.
The mode of delivery after operative fixation of pelvic ring fractures–a retrospective observational study
Authors: Mennen Anna H. M. , Posthuma Jelle J. , Kooijman Eline M. , Trietsch Marjolijn D. , De Vries Eefje N. , Bloemers Frank W. , Goslings J. Carel , Van Embden Daphne 
Published: August 2024

Abstract
Purpose
The purpose of this study is to investigate whether retained hardware after surgical treatment for a pelvic fracture prior to pregnancy affects the choice of delivery method. The study aims to provide insights into the rates of vaginal delivery and caesarean sections, understanding whether the mode of delivery was influenced by patient preference or the recommendations of obstetricians or surgeons, and examining the rate of complications during delivery and postpartum.

Methods
All women of childbearing age who underwent surgical fixation for a pelvic ring fracture between 1994 and 2021 were identified. A questionnaire was sent about their possible pregnancies and deliveries. Of the included patients, surgical data were collected and the fracture patterns were retrospectively classified. Follow-up was a minimum of 36 months.

Results
A total of 168 women with a pelvic fracture were identified, of whom 13 had a pregnancy after surgical stabilization. Eleven women had combined anterior and posterior fracture patterns and two had isolated sacral fractures. Four women underwent combined anterior and posterior fixation, the others either anterior or posterior fixation. Seven women had a total of 11 vaginal deliveries, and 6 women had 6 caesarean sections. The decision for vaginal delivery was often the wish of the mother (n = 4, 57%) while the decision to opt for caesarean section was made by the surgeon or obstetrician (n = 5, 83%). One woman in the vaginal delivery group suffered a postpartum complication possibly related to her retained pelvic hardware.

Conclusion
Women with retained hardware after pelvic ring fixation can have successful vaginal deliveries. Complications during labor or postpartum are rare. The rate of primary caesarean sections is high (46%) and is probably influenced by physician bias. Future research should focus on tools that can predict labor outcomes in this specific population, and larger multicenter studies are needed.

Level of evidence
Level III.
Attitude of aspiring orthopaedic surgeons towards artificial intelligence: a multinational cross-sectional survey study
Authors: Pawelczyk Johannes , Kraus Moritz , Eckl Larissa , Nehrer Stefan , Aurich Matthias , Izadpanah Kaywan , Siebenlist Sebastian , Rupp Marco-Christopher 
Published: August 2024

Abstract
Introduction
The purpose of this study was to evaluate the perspectives of aspiring orthopaedic surgeons on artificial intelligence (AI), analysing how gender, AI knowledge, and technical inclination influence views on AI. Additionally, the extent to which recent AI advancements sway career decisions was assessed.

Materials and methods
A digital survey was distributed to student members of orthopaedic societies across Germany, Switzerland, and Austria. Subgroup analyses explored how gender, AI knowledge, and technical inclination shape attitudes towards AI.

Results
Of 174 total respondents, 86.2% (n = 150) intended to pursue a career in orthopaedic surgery and were included in the analysis. The majority (74.5%) reported ‘basic’ or ‘no’ knowledge about AI. Approximately 29.3% believed AI would significantly impact orthopaedics within 5 years, with another 35.3% projecting 5–10 years. AI was predominantly seen as an assistive tool (77.8%), without significant fear of job displacement. The most valued AI applications were identified as preoperative implant planning (85.3%), administrative tasks (84%), and image analysis (81.3%). Concerns arose regarding skill atrophy due to overreliance (69.3%), liability (68%), and diminished patient interaction (56%). The majority maintained a ‘neutral’ view on AI (53%), though 32.9% were ‘enthusiastic’. A stronger focus on AI in medical education was requested by 81.9%. Most participants (72.8%) felt recent AI advancements did not alter their career decisions towards or away from the orthopaedic specialty. Statistical analysis revealed a significant association between AI literacy (p = 0.015) and technical inclination (p = 0.003). AI literacy did not increase significantly during medical education (p = 0.091).

Conclusions
Future orthopaedic surgeons exhibit a favourable outlook on AI, foreseeing its significant influence in the near future. AI literacy remains relatively low and showed no improvement during medical school. There is notable demand for improved AI-related education. The choice of orthopaedics as a specialty appears to be robust against the sway of recent AI advancements.

Level of evidence
Cross-sectional survey study; level IV.
Endoscopic ear surgery in the treatment of chronic otitis media with atelectasis
Authors: Iannella Giannicola , Pace Annalisa , Greco Antonio , De Virgilio Armando , Croce Enrica , Maniaci Antonino , Lechien Jerome R. , Gioacchini Federico Maria , Re Massimo , Cammaroto Giovanni , Perrone Tiziano , Cocuzza Salvatore , Magliulo Giuseppe 
Published: August 2024

Abstract
Purpose
Atelectasis otitis media (AtOM) is a chronic condition where the tympanic membrane (TM) becomes retracted towards the middle ear and the ossicular chain. Surgical treatment for this condition could be indicated based on stage of atelectasis, patient’s clinical condition and hearing loss. Over the years, AtOM has been treated with various types of tympanoplasty under microscopic view. The aim of this study is to present the results of endoscopic ear surgery in AtOM.

Methods
Forty-five patients who underwent endoscopic trans-canal tympanoplasty were included in the study. Preoperative features, intraoperative findings and postoperative outcomes were collected.

Results
Preoperatively, none of the study's patients were classified with a Sadè Grade I, whereas grades II, III and IV were 3 (6.6%), 23 (32.1%) and 19 (67.8%) respectively. The 3 patients with Sadè grade II showed a conductive hearing loss higher than 20 dB and a continuous ear fullness, therefore they were surgically treated. The postoperative graft success rate was estimated at 95.5%. During follow-up, 2 patients showed a TM perforation (at 6 and 12 months after surgery) whereas 1 patient experienced a recurrence of atelectasis in the TM (16 months after surgery). The overall success rate at the final follow-up was calculated at 88.8%. The average preoperative air-conduction threshold was 51.1 ± 21.5, which reduced to 34.6 ± 22.1 (p = 0.04) at follow-up. The preoperative air–bone gap decreased from 28 ± 7.2 to 11.8 ± 10 (p = 0.002) after surgery.

Conclusion
Atelectasis otitis media might be suitable for exclusive endoscopic surgical treatment, as it appears to exhibit a low recurrence rate and promising audiological outcomes.
Delayed facial nerve palsy after vestibular schwannoma resection: risk factors, extent and prognosis
Authors: Simon Miriam , Althaus Laurenz , Burggraf Manuel , Albrecht Angelika , Schipper Jörg , Kristin Julia 
Published: August 2024

Abstract
Introduction
Facial nerve palsies may develop during the postoperative period of microsurgical removal of vestibular schwannomas (VSs), even after normal facial function for days or weeks after surgery. The aim of this study was to identify the pathomechanism and predictive factors of delayed palsy.

Material and method
The clinical data of 193 patients who underwent vestibular schwannoma surgery between 2012 and 2021 were retrospectively analyzed. A total of 134 patients were included. The patients showed intact facial nerve function up to 24 h after surgery. All patients (n = 20) with palsy from postoperative day 4 were included and collectively referred to as delayed facial nerve palsy (DFNP). Various factors were checked using a binomial regression analysis.

Results
The mean age of patients with DFNP was 57.8 years (55% female, 45% male). 70% had VS with KOOS ≥ 3, and 60% underwent surgery via a translabyrinthine approach Among the 16 patients with DFNP-related neurotropic pathogens, 25% were seropositive for herpes simplex virus. Most patients (n = 9/20) experienced onset of palsy between postoperative days 6 and 10. Of the four variables included in the significance test, three were significant: KOOS ≥ 3 (p < .04), ipsilateral vestibular organ failure (p < .05), and age group (p < .03). After therapy, 100% of patients recovered almost complete facial nerve function.

Summary
The parameters mentioned above (KOOS classification and ipsilateral vestibular dysfunction) could be proven risk factors for the occurrence of DFNP.
Thalamic ventral-Oralis complex/rostral zona incerta deep brain stimulation for midline tremor
Authors: Scerrati Alba , Gozzi Andrea , Cavallo Michele Alessandro , Mantovani Giorgio , Antenucci Pietro , Angelini Chiara , Capone Jay Guido , De Bonis Pasquale , Morgante Francesca , Rispoli Vittorio , Sensi Mariachiara 
Published: August 2024

Abstract
Background
Midline Tremor is defined as an isolated or combined tremor that affects the neck, trunk, jaw, tongue, and/or voice and could be part of Essential Tremor (ET), or dystonic tremor. The clinical efficacy of deep brain stimulation for Midline Tremor has been rarely reported. The Ventral Intermediate Nucleus and Globus Pallidus Internus are the preferred targets, but with variable outcomes. Thalamic Ventral-Oralis (VO) complex and Zona Incerta (ZI) are emerging targets for tremor control in various etiologies.

Objective
To report on neuroradiological, neurophysiological targeting and long-term efficacy of thalamic Ventral-Oralis complex and Zona Incerta deep brain stimulation in Midline Tremor.

Methods
Three patients (two males and one female) with Midline Tremor in dystonic syndromes were recruited for this open-label study. Clinical, surgical, neurophysiological intraoperative testing and long-term follow-up data are reported.

Results
Intraoperative testing and reconstruction of volume of tissue activated confirmed the position of the electrodes in the area stimulated between the thalamic Ventral-Oralis complex and Zona Incerta in all patients.
All three patients showed optimal control of both tremor and dystonic features at short-term (6 months) and long-term follow-up (up to 6 years). No adverse events occurred.

Conclusion
In the syndromes of Midline Tremor of various origins, the best target for DBS might be difficult to identify. Our results showed that thalamic Ventral-Oralis complex/Zona Incerta may be a viable and safe option even in specific forms of tremor with axial distribution.
Future acceptance of automated insulin delivery systems in youths with type 1 diabetes: validation of the Italian artificial pancreas-acceptance measure
Authors: Franceschi Roberto , Pertile Riccardo , Marigliano Marco , Mozzillo Enza , Maffeis Claudio , Zaffani Silvana , Dusini Carlotta , Antonelli Annalisa , Candia Francesca Di , Maltoni Giulio , Cantarelli Erika , Minuto Nicola , Bassi Marta , Rabbone Ivana , Savastio Silvia , Passanisi Stefano , Lombardo Fortunato , Cherubini Valentino , Saltarelli Maria Alessandra , Tumini Stefano 
Published: August 2024

Abstract

Aim
The purpose of this study was to develop a questionnaire to examine the future acceptance of Automatic insulin delivery systems (AIDs), their perceived usefulness, ease of use, and trust in the device in subjects with type 1 diabetes (T1D).

Methods
A questionnaire in Italian, based on the Technology Acceptance Model, was developed to examine intention to use AIDs, considered as a measure of future acceptance, and its determinants to use the system. A total of 43 questions for children and 46 for parents were included, and a 5-point Likert scale was used.

Results
239 subjects with T1D using multiple daily injections (MDI) or sensor-augmented pump (SAP) and their parents completed the questionnaire. The completion rate was excellent, with almost 100% of items answered. The overall Cronbach’s coefficient for children and adolescents was 0.92 and 0.93 for parents, indicating excellent internal consistency in both groups. Parent-youth agreement was 0.699 (95% confidence interval: 0.689–0.709), indicating a good agreement between the two evaluations. Factor analysis identified measurement factors for the “artificial pancreas (AP)-acceptance labeled benefits and hassles of AIDs, and the internal consistency of the total scale was alpha = 0.94 for subjects with T1D and 0.95 for parents. The level of AP acceptance was more than neutral: 3.91 ± 0.47 and 3.99 ± 0.43 (p = 0.07) for youths and parents, respectively (possible score range 1 to 5, neutral score is 3.0). Parents reported higher scores in the benefit items than children-adolescents (p = 0.04).

Conclusions
We developed a new questionnaire based on the items available in the literature, and we demonstrated that the “AP-acceptance” reveals a meaningful factor structure, good internal reliability, and agreement between parent–young people evaluations. This measure could be a valuable resource for clinicians and researchers to assess AP acceptance in pediatric patients with T1D and their parents. This patient profiling approach could help to enroll candidates for AIDs with proper expectations and who most likely will benefit from the system.