bluuebunny/crossref_metadata_2025_split huggingface dataset:
Notizen: Zinnorganische Fluoride als Fluorierungsreagenzien für Chloride von Hauptgruppenelementen - Quantitatives Recycling des Fluorierungsreagenzes / Tinorganic Fluorides Function as Fluorinating Reagents for Chlorides of Main Group Elements - Quantitative Recycling of the Fluorinating Reagent
Authors: Roesky Herbert W. , Herzog Axel , Keller Klaus 
Published: February 2015

Abstract
PF3 is obtained in high purity by reacting PCl3 with Me3SnF. Alternative fluorinating reagents for this reaction are Ph3SnF and (i-C4H9)3SnF. The reaction with the isobutyl derivative is less complicated since the resulting chloride is a liquid in contrast to Ph3SnCl being a solid. PCl5, MeCOCl, SiCl4, Me3SiCl, and SOCl2 react with Me3SnF to give also the corresponding fluorides. The resulting chlorides are easily converted again to the fluorides. A quantitative recycling of the fluorinating reagent is therefore achieved.
Bis(triorganotelluronium)hexasulfide / Bis(triorganotelluronium)hexasulfides
Authors: Wieber Markus , Habersack Ralph 
Published: February 2015

Abstract
The reaction of triorganolelluronium chlorides R3TeCl (R = Me, Ph, 4-tBu-C6H4) with Na2Sx, (x = 4 - 6) yields the corresponding bis(triorganotelluronium) hexasulfides (R3Te)2S6 regardless of the employed sodium polysulfide or the size of the lelluronium cation. All compounds are thermally stable and insensitive to moisture or air. (Ph3Te)2S6 was structurally characterized by X-ray crystallography (monoclinic, space group P21/c). Each tellurium atom is connected to both ends of the hexasulfide chain.
Synthese und Struktur von Kalium-4,4-difluor-[1,3,2]dithiazetidinid-1,l,3,3-tetraoxid und Rubidium-4,4,5,5-tetrafluor-[1,3,2]dithiazolidinid-1,1,3,3-tetraoxid / Syntheses and Structure of Potassium-4,4-difluoro-[1,3,2]dithiazetidinide-1,1,3,3- tetraoxide and Rubidium-4,4,5,5-tetrafluoro-[ 1,3,2]dithiazolidinide-1,1,3,3-tetraoxide
Authors: Jüschke Ralf , Henkel Gerald , Sartori Peter 
Published: February 2015

Abstract
Reactions of perfluoroalkane-1,n-bis(sulfonylfluorides) (n = 1-2) (1-2) with liquid ammonia in tetrahydrofuran (TH F) lead to the cyclic ammonium imides 3-4. These cyclic imides 3-4 can easily be transform ed to other salts using the corresponding hydroxides. X -ray structure analyses (T = 150 K) were perform ed for the potassium 4,4-difluoro-[1,3,2]dithiazetidinide-1,1,3,3-tetraoxide 5 and rubidium -4,4,5,5-tetrafluoro-[1,3,2]dithiazolidinide-1,1,3,3-tetraoxide 6. Cylic imides of the type 3, 5 have not been reported previously. Their formation and their nmr-data are discussed.
Röntgenstrukturuntersuchungen an Elpasolith-verwandten Hexacyanokomplexen [N(CH3)4]2A[M(CN)6] (A = Rb, Tl; M = Cr, Fe) / X-Ray Structure Investigations of Elpasolite Related Hexacyano Complexes [N(CH3)4]2A[M(CN)6] (A = Rb, Tl; M = Cr, Fe)
Authors: Schwarten Martin , Ziegler Bernd , Witzei Michael , Babel Dietrich 
Published: February 2015

Abstract
Single crystals were prepared and X -ray structure determinations performed of the hexagonal com pounds (R3̄m, Z = 3) [N(CH3)4]2RbCr(CN)6 (a = 895.9, c = 2176.4 pm), [N (CH3)4],TlCr(CN)6 (a = 894.0, c = 2168.4 pm), [N(CH3)4],RbFe(CN)6 (a = 886.7, c = 2149.9 pm ) and of monoclinic [N(CH3)4]2TlFe(CN)6 (C2/c, Z = 4; a = 1511.4, b = 884.8, c = 1525.9 pm , β = 110.0°). The structure of the hexagonal complexes is closely related to that of cubic elpasolites, showing, however, orientational disorder of the tetramethylammonium groups. Within the monoclinic TIFe-compound this group has fixed orientation, which makes some of the Fe-CN-Tl bridges bent, contrary to the linear M-CN -A array within the hexagonal compounds. Details and relations are discussed with respect to similar hexacyano complexes.
Notizen: A New Lithium Amide with Bulky Substituents -Molecular Structure of N-Lithio-N-trimethylsilyl-9-amino- 9-borabicyclo[3.3.1]nonane; Competition between N-Li and BN(pp)π Interactions
Authors: Wrackmeyer Bernd , Schwarze Bernd , Weidinger Jürgen , Milius Wolfgang 
Published: February 2015

Abstract
N-Lithio-N-trimethylsilyl-9-amino-9-borabicyclo[3.3.1]nonane (2) was prepared from the reaction of N-trimethylsilyl-9-amino-9-borabicyclo-[3.3.1]nonane (1) with rert-butyl lithium; 2 crystallizes as a trim er with a planar N3Li3 ring. The nitrogen atoms are tetrahedrally coordinated, but should be treated as sp2 hybridised, because the BN double bond, typical of aminoboranes, is retained.
Verdampfungsverhalten von Lanthantrihalogeniden / Evaporation Behaviour of Lanthanum Trihalides
Authors: Oppermann H. , Morgenstern A. 
Published: February 2015

The evaporation of LaCl3, LaBr3 and Lal3 was investigated in closed tubes under argon atmosphere and correlated with data in the literature. The enthalpies and entropies of evaporation were derived from the temperature functions of pressure:
ΔH°(v, LaCl3, T) = 48,5 ± 2 kcal/mol, ΔS°(v, LaCl3, T) = 22,0 ± 3 cal/K-mol
ΔH°(v, LaBr3, T) = 48,0 ± 2 kcal/mol, ΔS°(v, LaBr3, T) = 24,0 ± 2 cal/K-mol
ΔH° (v , Lal3, T) = 49,5 ± 2 kcal/mol, ΔS°(v, Lal3,T) = 29,0 ± 2 cal/K-mol
Synthesis and Structural Characterization of [Me4N]2[W2O2(μ-S)(η2-S2)4]·MeCN, a Novel Oxo-thiotungstate(VI)
Authors: Rahman A. B. M. Shamsur , Boller H. , Klepp K. O. 
Published: February 2015

Orange red crystals of the new compound [Me4N]2[W2O2 (μ-S2)(η2 -S2)4] MeCN were obtained from the reaction of a solution of [Me4N]2[WOS3] in MeCN with solid AuCN at room temperature. They are monoclinic, space group P21/n, with a = 9.264(2), b = 17.736(3), c = 18.742(5) Å, ß = 95.19(1)°; Z = 4. The crystal structure was determined from single crystal diffractometer data (MoKα-radiation) and refined to R = 0.050 (2955 reflections, 221 variable parameters). It is characterized by binuclear complex anions [(S2)2OWSWO(S2)2]2- with close to C2 symmetry. Each metal center is surrounded by two end-on coordinating disulfide groups at distances ranging from 2.37 to 2.42 Å which together with a bridging sulfur atom (d̄w-s = 2.445 Å) occupy the equatorial positions of a pentagonal bipyramid whose apices are defined by a terminal oxygen atom (d̄w-o
~ 1 -725 Å) and one sulfur atom of the neighboring component at a distinctly larger distance (d̄w-s
~ 2.82 Å).
Infrared spectra of the complex (KBr powder) showed ν(W-O) and ν(W-S) of bridging W-S-W at 931 (vs) and 454 (m) cm - 1, respectively, ν(W-S) of the WS2 unit appeared in the range between 465 and 438 cm -1. The mass spectrum of the anion showed the molecular mass at m/z 688 for [W2O2 S9]- as well as peaks for other fragments.
Thermisches Verhalten von festem LaAlCl6 und chemischer Transport von LaCl3 mit AlCl3/Thermical Behaviour of Solid LaAlCl6 and Chemical Transport of LaCl3 with AlCl3
Authors: Oppermann H. , Quoc H. Dao , Morgenstern A. 
Published: February 2015

The thermodynamical data of solid aluminium lanthanum chloride LaAlCl6 have been obtained by determination of the decomposition equilibria from total pressure measurements. The melting diagram was determined by DTA. The chemical transport of LaCl3 with AlCl3 is suggesting the existence of the gaseous complex LaAl3Cl12. The data are:
ΔH(LaAlCl6
f,298) =-427,1 ±2,5 kcal/mol, S°(LaAlCl6,f,298) = 61 ±2,5 cal/K-mol,
Δ(LaAl3Cl12,g ,298) =-712 ± 7 kcal/mol, S°(LaAl3Cl12,g,298) = 205 ± 3 cal/K-mol.
Wechselwirkungen in Molekülkristallen, 166 [1, 2]. Polyiod-Moleküle I2C=CI2, (IC)4S, (IC)4NH, (IC)4N-CH3 und HCI3: Strukturbestimmung nach Kristallzüchtung oder durch Dichtefunktionaltheorie-Berechnung / Interaction in Molecular Crystals, 166 [1, 2], Polyiodo Molecules I2C=CI2, (IC)4S, (IC)4 NH, (IC)4N-CH and HCI3: Structure Determination Following Crystallization or by Density Functional Theory Calculation
Authors: Bock Hans , Holl Sven , Krenzel Volker 
Published: February 2015

Abstract
The structures of tri-and tetraiodo-substituted carbon compounds are determined either expe­rimentally by X-Ray Structure Analysis or, because crystallization of tetraiodothiophene could not be achieved, approximated by Density Functional Theory optimization of structural data from a donor/acceptor complex. The structures show noteworthy details such as a second po­lymorph of tetraiodoethene crystallized by sublimation or herringbone crystal packing patterns of tetraiodopyrrole derivatives. All molecular geometries are discussed and compared based on relativistic density functional theory calculations with 6 -31G* basis sets including iodine pseudopotentials. They reproduce even finer structural details due to van der Waals repulsion of the bulky iodo substituents. Natural Bond Orbital (NBO) charge distributions suggest positive partial charges at all iodine centers with the strongest polarization Cδ㊀ → Iδ㊉ in HCI3, which contains well over 97% iodine.
Orthoamide, LV [1]. C7H7N3O6 - Tris(diformylamino)methan („Formylaalen“) - ein Orthoameisensäureamid-Derivat mit sechs Formylgruppen / Orthoam ides, LV [1]. C7H7N3O6 - Tris(diformylamino)methane ( “Formylaalen”) - an Orthoformic Acid Amide Derivative with Six Formyl Groups
Authors: Kantlehner Willi , Ziegler Georg , Ciesielski Michael , Scherr Oliver , Vettel Markus 
Published: February 2015

Abstract
The preparation of tris(diformylamino)methane (3), a hitherto unknown derivative of orthoformic acid, is described. In the presence of a Lewis acid the orthoamide 3 formylates activated aromatic compounds.
Wechselwirkungen in Molekülkristallen, 168 [1,2]. σ-Donator/Akzeptor-Komplexe {HCl3···Xe⊖ }(X⊖ = Cl, Br⊖ , I⊖ ) von Triiodmethan in Tetraphenylphosphoniumhalogeniden / Interaction in Molecular Crystals, 168 [1, 2]. σ-Donor/Acceptor Complexes {HCl3 ···X⊖} (X⊖ = Cl⊖ , Br⊖ , I⊖ ) of Triiodomethane in Tetraphenylphosphonium Halides
Authors: Bock Hans , Holl Sven 
Published: February 2015

Abstract
Three donor/acceptor complexes between halide anion donors and the triiodomethane acceptor with tetraphenylphosphonium countercations, {(H5C6)4P⊕ X⊖ ··· I3CH)} (X⊖ = Cl⊖ , Br⊖, I⊖ ) could be crystallized and their structures determined at low temperature. Their crystal packing motifs are donor/acceptor layers of halide anion/triiodomethane patterns and phenyl/ phenyl interacting tetraphenylphosphonium cation chains. Structure comparison and discussion are based on literature-known analogous adducts with organoammonium salts as well as the phenyl/phenyl interactions in the numerous tetraphenylphosphonium salts registered in the Cambridge Structural Database. The results add novel facets to the selforganization phenomena observed on crystallization of halogen compounds and halide salts.
New Magnesium Compounds RE2Cu2Mg (RE = Y, La -Nd, Sm, Gd -Tm, Lu) with Mo2FeB2 Type Structure
Authors: Mishra Ratikanta , Hoffmann Rolf-Dieter , Pöttgen Rainer 
Published: February 2015

Abstract
The title compounds were synthesized by reaction of the elements in sealed tantalum tubes in a water-cooled sample chamber in a high-frequency furnace. These magnesium intermetallics crystallize with the tetragonal Mo2FeB2 type structure, space group P4/mbm. The lattice pa­ rameters of all compounds were refined from X-ray powder data. Single crystal X-ray data yielded a = 792.09(6), c = 396.31(8) pm, wR2 = 0.0396, 315 F2 values for La2Cu2Mg, a = 778.30(5), c = 384.04(5) pm, wR2 = 0.0954, 214 F2 values for Nd2Cu2Mg, and a = 762.65(5), c = 374.09(3) pm, wR2 = 0.0566, 186 F2 values for Y2Cu2Mg with 12 variable parameters for each refinement. The RE2Cu2Mg structures can be described as an intergrowth of distorted A1B2 and CsCl related slabs of compositions RECu2 and REMg. Chemical bonding in La2Cu2Mg was investigated on the basis of extended Hückel calculations and compared to isotypic La2Cu2ln. This structure was also refined from single crystal X-ray data: P4/mbm, a = 780.8(2), c = 400.1(2) pm, wR2 = 0.0351, 211 F2 values and 12 variable parameters.
Kinetics of the Substitution of Norbornadiene in Tetracarbonyl(norbomadiene)molybdenum(0) by 2,2'-Bipyridine
Authors: Kayran Ceyhan , Okan Eser 
Published: February 2015

Abstract
The kinetics of the thermal substitution of norbornadiene (nbd) by 2,2'-bipyridine (2,2'-bipy) in (CO)4Mo(C7H9) was studied by quantitative FT-IR and UV-VIS spectroscopy. The reaction rate exhibits first-order dependence on the concentration of the starting complex, and the observed rate constant depends on the concentration of both leaving nbd and entering 2,2'-bipy ligand. The mechanism was found to be consistent with the previously proposed one, where the rate determining step is the cleavage of one of the two Mo-olefin bonds. The reaction was performed at four different temperatures (35 -50 °C) and the evaluation of the kinetic data gives the activation parameters which now support states.
The Stannides RERhSn (RE = Ho - Yb) and ScTSn (T = Pd, Pt) - Structure Refinements and 119Sn Mössbauer Spectroscopy
Authors: Mishra Ratikanta , Pöttgen Rainer , Hoffmann Rolf-Dieter , Trill Henning , Mosel Bernd D. , Piotrowski Holger , Zumdick Markus F. 
Published: February 2015

Abstract
The stannides RERhSn (RE = Ho -Yb) and ScTSn (T = Pd, Pt) were prepared by reaction of the elements in sealed tantalum tubes in a high-frequency furnace, by arc-melting, or by a tin-flux technique in quartz tubes. The rhodium based stannides crystallize with the ZrNiAl type structure, space group P6̄2m. The four structures were refined from single crystal X-ray data: a = 754.5(3), c = 377.1(1) pm, wR2 = 0.0357, 233 F2 values for HoRhSn, a = 753.3(1), c = 372.16(8) pm, wR2 = 0.0721, 233 F2 values for ErRhSn, a = 753.7(3), c = 369.0(2) pm, wR2 = 0.0671,233 F2 values for TmRhSn, and a = 753.17(5), c = 366.53(4) pm, wR2 = 0.0566, 180 F2 values for YbRhSn with 14 parameters for each refinement. ScPdSn and ScPtSn adopt the HfRhSn type, a superstructure of ZrNiAl, space group P6̄2c: a = 747.5(1), c = 710.2(1) pm, for ScPdSn, and a = 738.37(9), c = 729.47(9) pm, wR2 = 0.0452,369 F2 values, 18 variables for ScPtSn. Structural motifs in these stannides are transition metal centered trigonal prisms formed by the rare earth and tin atoms. While these prisms are regular in the rhodium based stannides, significant distortions occur in ScPdSn and ScPtSn. The formation of the superstructure can be ascribed to packing reasons. The shortest interatomic distances occur between the transition metal (T) and tin atoms. These atoms form three-dimensional [FSn] networks in which the rare earth atoms fill distorted hexagonal channels. The series RERhSn displays a somewhat unique behavior. The a lattice parameter is more or less independent of the rare earth element, while the c lattice parameter shows the expected lanthanoid contraction. 119Sn Mössbauer spectroscopic data of the rhodium stannides show signals at isomer shifts varying from 1.77 to 1.82 mm/s subject to quadrupole splitting between 0.75 to 0.82 mm/s.
Group 12 Metal Complexes of 2-Formylpyrrole-(4PL1) and 2-Acetylpyrrole-N(4)-phenylthiosemicarbazone (4Pl2), as Examples form Different Donor Modes. Crystal and Molecular Structures of [Hg(4PL1- H)Br]2 and [Zn(4PL2)2Br2] · 2 EtOH
Authors: Carballo Rosa , Castiñeiras Alfonso , Pérez Teresa 
Published: February 2015

Abstract
The reactions of 4N-phenyl-2-[ 1 -(pyrrol-2-yl)methylidene]-hydrazine carbothioamide (4PL1) and 4N-phenyl-2-[l-(pyrrol-2-yl)ethylidene]-hydrazine carbothioamide (4PL2) with Group 12 metal halides afford complexes of types [M(L)2X2] [M = Zn, L = 4PL1 or 4PL2, X = Cl, Br or I; M = Cd, L = 4PL1, and X = Cl, or L = 4PL2 and X = Cl, Br or I] and [M(L)X2] [M = Cd, L = 4PL1, X = Br or I; M = Hg, L = 4PL1 or 4PL2, X = Cl, Br or I]. The new compounds were characterized by elemental analysis, FAB mass spectrometry, IR spectroscopy, and, in the case of sufficiently soluble compounds, 1H, 13C and, when appropriate, 113Cd or 199Hg NMR spectrometry. The structures of [Hg(4PL1-H)Br] and [Zn(4PL2)2Br2] · 2 EtOH were also studied by single-crystal X-ray diffractometry. In [Hg(4PL1-H)Br] crystallized from the mother liquor of its synthesis, 4PL1 behaves as a monodeprotonated S,N-bidentate ligand. Otherwise, with Hg(II), Zn(II) and Cd(II), 4PL1 and 4PL2 both behave as neutral S-monodentate ligands.
Thermisches und kalorisches Verhalten von festem LaAl3Br12 und chemischer Transport von LaBr3 mit AlBr3 / Thermical and Calorical Behaviour of Solid LaAl3Br12 and Chemical Transport of LaBr3 with AlBr3
Authors: Oppermann H. , Quoc H. Dao , Zhang-Preβe M. 
Published: February 2015

Abstract
The thermodynamical data of solid Lanthanum Aluminium Bromide LaAl3Br12 have been obtained by determination of the decomposition equilibria from total pressure measurements. For different compositions LaBr3/AlBr3, the barogram of the binary system LaBr3-AlBr3 was constructed and from this and DTA the melting diagram was determined. The chemical trans­ port of LaBr3 with AlBr3 is suggesting the existence of two gaseous complexes LaAl3Br12 and LaAl2Br9.
The data are:
ΔH°B(LaAl3Br12,f,298) =-587,2 ± 7 kcal/mol, S°(LaAl3Br12,f,298) = 179,3 ± 7 cal/K·mol;
ΔH°B(LaAl3Br12,g,298) =-548,7 ± 5 kcal/mol, S°(LaAl3Br12,g,298) = 239,4 ± 6 cal/K·mol;
ΔH°B(LaAl2Br9,g,298) =-619,7 ± 5,5 kcal/mol, S°(LaAl2Br9,g,298) = 212,0 ± 7 cal/K·mol.
From solution calorimetric measurements follows the enthalpy of formation of the solid com­plexes: ΔH°B(LaAl3Br12,f,298) =-590,9 ± 3 kcal/mol.
Thiolate Complexes of Gold(I) Based on a Tris(phosphine) Support
Authors: Wilton-Ely James D. E. T. , Mitzel Norbert W. , Hofreiter Stefan , Schmidbaur Hubert 
Published: February 2015

Abstract
Treatment of the ligand l,3,5-tris[(diphenylphosphanyl)methyl]trimethylbenzene (P3) with (tetrahydrothiophene)gold(I) chloride results in the symmetrical trigold complex [(P3)(AuCl)3]. In the presence of sodium methoxide, [(P3)(AuCl)3] reacts with thiocresol (HSC6H4Me-4) and 2-mercaptoquinoline (2-HSQn) to provide the complexes [(P3)(AuSC6H4Me-4)3] and [(P3)(AuSQn)3], respectively. Reaction of [(P3)(AuCl)3] with KSCN also yields the expected product [(P3)(AuSCN)3], however, treatment with 2-10 molar equivalents of NaSMe re­sults only in the unsymmetrical cationic complex [(P3)Au3(SMe)2]Cl. Reaction between [(P3)(AuOTf)3] (prepared in situ from [(P3)(AuCl)3] and AgOTf) and sodium sulfide yields the complex [(P3)Au3S]+OSO2CF3
- , the first example of a trigoldsulfonium unit coordinated to a tridentate phosphine. The tetrafluoroborate salt is obtained from [(P3)(AuCl)3] and Na2S·9 H2O in the presence of NaBF4. The structure of [(P3)(AuSMe)2]Cl has been determined and reveals that in the solid the two methylthiolate units bridge the three gold atoms, but the structure of the cation is fiuxional in solution according to NMR data.
Borane Activators for Nickel Catalysts for Olefin Polymerization
Authors: Lassahn Paul-Gerhard , Janiak Christoph , Oh Jae-Seung 
Published: February 2015

Abstract
Activation of Ni(acetylacetonate)2 and Ni(2-ethylhexanoate)2 with B(C6F5)3 and B(C6F5)3/ triethylaluminium leads to highly active catalyst systems for the vinyl polymerization of nor­bomene.
Improved Synthetic Route to Unsymmetrically Substituted Phosphinimino-phosphonium Salts. Crystal Structure of Tri-n-butyl- [tris(diethylamino)phosphinimino]phosphonium Chloride
Authors: Bartsch R. , Freytag M. , Goller S. , Jones R G. , Schmutzler R. 
Published: February 2015

Abstract
The title compound was prepared from tri-n-butyl-chlorophosphonium chloride and N-tri-methylsilyl-tris(diethylamino)-phosphinimine. A low temperature X-ray crystal structure de­termination revealed PN bond lengths of 156.1(2) and 158.0(2) pm, with a PNP angle of 149.36(17)°.
The Gold Sulfates MAu(S04)2 (M = Na, K, Rb)
Authors: Wickleder Mathias S. , Büchner Oliver 
Published: February 2015

Abstract
The evaporation of a solution of Au(OH)3 and Na2So4 in conc. sulfuric acid led to yellow single crystals of NaAu(SO4)2 (monoclinic, P21/n, Z = 2, a = 469.1, b = 845.9, c = 831.2 pm, β = 95.7°). Analogous procedures with K2SO4 or Rb2SO4 instead of Na2SO4 yielded single crystals of KAu(SO4)2 (monoclinic, C2/c, Z = 4, a = 1109.8, b = 724.2, c = 941.1 pm, β = 118.4°) and RbAu(S04)2, respectively, (triclinic, P1̄, Z = 1, a = 423.6, b = 497.5, c = 889.0 pm, a = 76.4°, β = 88.4°, γ = 73.5°). Although the crystal structures of the three sulfates are not isotypic they show similar structural features: The gold atoms are coordinated by four oxygen atoms in a square planar manner. These oxygen atoms belong to four SO4
2- ions which link the [AUO4] units to infinite chains according to 1
∞[Au(SO4)4/ 2]- . These chains are connected via the monovalent cations which show coordination numbers of 6 (Na+), 10 (K+) and 12 (Rb+), respectively.
Accuracy of Whole-Genome Prediction Using a Genetic Architecture-Enhanced Variance-Covariance Matrix
Authors: Zhang Zhe , Erbe Malena , He Jinlong , Ober Ulrike , Gao Ning , Zhang Hao , Simianer Henner , Li Jiaqi 
Published: February 2015

Abstract
Obtaining accurate predictions of unobserved genetic or phenotypic values for complex traits in animal, plant, and human populations is possible through whole-genome prediction (WGP), a combined analysis of genotypic and phenotypic data. Because the underlying genetic architecture of the trait of interest is an important factor affecting model selection, we propose a new strategy, termed BLUP|GA (BLUP-given genetic architecture), which can use genetic architecture information within the dataset at hand rather than from public sources. This is achieved by using a trait-specific covariance matrix (T), which is a weighted sum of a genetic architecture part (S matrix) and the realized relationship matrix (G). The algorithm of BLUP|GA (BLUP-given genetic architecture) is provided and illustrated with real and simulated datasets. Predictive ability of BLUP|GA was validated with three model traits in a dairy cattle dataset and 11 traits in three public datasets with a variety of genetic architectures and compared with GBLUP and other approaches. Results show that BLUP|GA outperformed GBLUP in 20 of 21 scenarios in the dairy cattle dataset and outperformed GBLUP, BayesA, and BayesB in 12 of 13 traits in the analyzed public datasets. Further analyses showed that the difference of accuracies for BLUP|GA and GBLUP significantly correlate with the distance between the T and G matrices. The new strategy applied in BLUP|GA is a favorable and flexible alternative to the standard GBLUP model, allowing to account for the genetic architecture of the quantitative trait under consideration when necessary. This feature is mainly due to the increased similarity between the trait-specific relationship matrix (T matrix) and the genetic relationship matrix at unobserved causal loci. Applying BLUP|GA in WGP would ease the burden of model selection.