bluuebunny/crossref_metadata_2025_split huggingface dataset:
Thermodynamic modelling of gas hydrate dissociation conditions in porous medium in the presence of NaCl/methanol aqueous solution
Authors: Hashemzadeh Samira , Javanmardi Jafar , Rasoolzadeh Ali , Mohammadi Amir H. 
Published: August 2024

AbstractDue to the growing significance of the existence of gas hydrates in natural media like the ocean floor/permafrost regions and the extraction of natural gas from hydrate reservoirs using thermodynamic hydrate inhibitors, investigating the dissociation of gas hydrates in porous media in the presence of inhibitors is crucial. This work examines a broad range of laboratory data on the dissociation conditions of gas hydrates in the porous mediums when salt/alcohol aqueous solutions are present. The temperature of gas hydrate dissociation in the presence of pure water is calculated using the van der Waals–Platteeuw solid solution theory. The water activity in the porous medium is then calculated by taking into account a number of variables, including the radius of the porous medium, molar volume, shape factor, wetting angle, and surface tension. The Pitzer and Margules activity coefficient models are used to determine the water activity in the presence of salt and alcohol, respectively. Lastly, the gas hydrate dissociation temperature in a porous medium in the presence of salt and/or alcohol aqueous solution is determined by combining Piereon's model with an enthalpy‐based correlation that was proposed by Azimi et al. The selected package can consistently correlate the gas hydrate dissociation conditions in a porous medium in the presence of alcohol or salt aqueous solution. The average absolute deviation (AAD) of 0.67 K for the whole data bank (90 experimental data points) shows the precision of the model.
Asymptotics of block Toeplitz determinants with piecewise continuous symbols
Authors: Basor Estelle , Ehrhardt Torsten , Virtanen Jani A. 
Published: August 2024

AbstractWe determine the asymptotics of the block Toeplitz determinants as for matrix‐valued piecewise continuous functions with a finitely many jumps under mild additional conditions. In particular, we prove that
where , , and are constants that depend on the matrix symbol and are described in our main results. Our approach is based on a new localization theorem for Toeplitz determinants, a new method of computing the Fredholm index of Toeplitz operators with piecewise continuous matrix‐valued symbols, and other operator theoretic methods. As an application of our results, we consider piecewise continuous symbols that arise in the study of entanglement entropy in quantum spin chain models.
Regenerative Practices Show Promise in Dryland Cotton Systems
Authors: Singh Jasdeep , Ale Srinivasulu , DeLaune Paul B. 
Published: August 2024

AbstractRegenerative practices, such as no‐till and cover crops, are advocated for their positive impacts on soil health and the environment. Nevertheless, there are challenges associated with implementing these practices. The objective of this simulation study was to assess the potential for soil carbon sequestration, soil water storage, and cotton yield response when implementing regenerative practices in the water‐limited environment of the Texas Rolling Plains region. Earn 1 CEU in Sustainability by reading this article and taking the quiz.
Genome‐wide association analysis of resistance to anthracnose in the Middle American Diversity Panel of common bean (Phaseolus vulgaris L.)
Authors: Sinkala Willard , Hamabwe Swivia , Kuwabo Kuwabo , Mukuma Chikoti , Kamfwa Kelvin 
Published: August 2024

AbstractAnthracnose (ANTH) caused by Colletotrichum lindemuthianum is a major disease of common bean (Phaseolus vulgaris L.). The genetic basis of ANTH resistance in the Middle American Diversity Panel (MDP) is unknown. The objectives of this study were to identify (1) Middle American accessions resistant to races 7, 19, 51, 63, 167, and 1085 of C. lindemuthianum and (ii) genomic regions and positional candidate genes associated with resistance to these races. The MDP composed of 240 Middle American accessions was evaluated for resistance to races 7, 19, 51, 63, 167, and 1085. The MDP was genotyped with 211,763 single nucleotide polymorphisms (SNPs), and mixed linear model analysis was conducted to identify genomic regions associated with resistance to the six races. Seven accessions were highly resistant to all six races, and these can be used as sources of resistance to improve specific market classes in the Middle American gene pool. The genomic region (385,894 bp) on chromosome Pv04 was significantly associated with resistance to race 167. Genomic regions on Pv02 (41,570,325 bp), Pv07 (24,122,343 bp), and Pv11 (51,707,917 bp) were significantly associated with resistance to race 19. Disease resistance (R) genes with the nucleotide binding‐APAF resistance protein and CED‐4 domain were identified as positional candidate genes on Pv04 and Pv11. There were no SNPs significantly associated with resistance to races 7, 51, 63, and 1085. Pyramiding the identified genomic regions on Pv04, Pv07, and Pv11 could provide durable ANTH resistance in Middle American varieties for races 19 and 167.
Design and evaluation of a blockchain‐based system for increasing customer engagement in circular economy
Authors: Cerchione Roberto 
Published: August 2024

AbstractThe purpose of this study is to design, develop and evaluate a blockchain platform in the field of circular economy (CE). To achieve this aim, the research demonstrates the feasibility of designing a decentralised architecture and prototyping a distributed system to increase customer engagement in the transition toward CE. Building on previous research and leveraging on the design science research approach, the paper identifies the technical and managerial issues that must be addressed to adopt blockchain as an enabling technology in the CE domain. More in details, starting with the identification of circular sharing economy (CSE) processes, a conceptual framework was designed to evaluate how blockchain implementation has the potential to enhance the role of customers involved in CSE processes. As for the practical implications, the suggested conceptual framework reduces the knowledge gap between blockchain developers and corporate social responsibility specialists. To bridge the gap, it identifies future directions and practical guidelines for designing and implementing blockchain to support the digital and sustainable innovation of more circular firms and supply chains.
Millisecond‐scale behaviours of plankton quantified in vitro and in situ using the Event‐based Vision Sensor
Authors: Takatsuka Susumu , Miyamoto Norio , Sato Hidehito , Morino Yoshiaki , Kurita Yoshihisa , Yabuki Akinori , Chen Chong , Kawagucci Shinsuke 
Published: August 2024

AbstractThe Event‐based Vision Sensor (EVS) is a bio‐inspired sensor that captures detailed motions of objects, aiming to become the ‘eyes’ of machines like self‐driving cars. Compared to conventional frame‐based image sensors, the EVS has an extremely fast motion capture equivalent to 10,000‐fps even with standard optical settings, plus high dynamic ranges for brightness and also lower consumption of memory and energy. Here, we developed 22 characteristic features for analysing the motions of aquatic particles from the EVS raw data and tested the applicability of the EVS in analysing plankton behaviour. Laboratory cultures of six species of zooplankton and phytoplankton were observed, confirming species‐specific motion periodicities up to 41 Hz. We applied machine learning to automatically classify particles into four categories of zooplankton and passive particles, achieving an accuracy up to 86%. At the in situ deployment of the EVS at the bottom of Lake Biwa, several particles exhibiting distinct cumulative trajectory with periodicities in their motion (up to 16 Hz) were identified, suggesting that they were living organisms with rhythmic behaviour. We also used the EVS in the deep sea, observing particles with active motion and periodicities over 40 Hz. Our application of the EVS, especially focusing on its millisecond‐scale temporal resolution and wide dynamic range, provides a new avenue to investigate organismal behaviour characterised by rapid and periodical motions. The EVS will likely be applicable in the near future for the automated monitoring of plankton behaviour by edge computing on autonomous floats, as well as quantifying rapid cellular‐level activities under microscopy.
Spatio‐temporal metapopulation trends: The coconut crabs of Zanzibar
Authors: Sollmann Rahel , Caro Tim 
Published: August 2024

AbstractSpecies experience a variety of environmental and anthropogenic conditions across their ranges leading to spatial variation in population dynamics. Understanding population dynamics under different conditions is important but it is challenging to allocate limited effort to spatial and temporal subpopulation monitoring. Using GLMMs, we analyze survey data of a metapopulation of coconut crabs spanning 7 years and 15 sites in and near the Pemba archipelago, Zanzibar, to estimate trends in population size (based on catch per unit effort), weight and sex ratio at the meta‐ and subpopulation level and investigate anthropogenic drivers of these trends. We found that the overall metapopulation has remained stable in terms of size and composition over the survey period, but observed diverging trends in population size and sex ratio at some subpopulations. Formal protection of sites was associated with positive population trends. Of nine sites for which we could estimate site‐specific trends, three showed increasing and two decreasing trends, whereas four sites had stable subpopulations. Although anthropogenic factors affected the average weight, and the incidence of small and large individuals, we found no temporal trends in any weight‐related measures. Furthermore, there were no apparent patterns between weight‐related measures and subpopulation trends. The metapopulation was biased toward males, and exploitation appeared to be associated with declining trends in the proportion of females, likely an artifact of a strong decline in the proportion of females in one of only two exploited sites in the dataset. Educational campaigns implemented in 2020 at six sites were not related to higher population sizes in later surveys. The variable trends in subpopulation sizes and composition highlight the need for spatially replicated monitoring in metapopulations. The analyses further provide a detailed baseline for future subpopulation studies of this vulnerable species in one of its last remaining metapopulations in the Western Indian Ocean.
Cascading effects of mammal host community composition on tick vector occurrence at the urban human–wildlife interface
Authors: Bastard Jonathan , Gregory Nichar , Fernandez Pilar , Mincone Michaela , Card Olivia , VanAcker Meredith C. , Kross Sara , Diuk‐Wasser Maria A. 
Published: August 2024

AbstractHabitat fragmentation and host community composition are implicated as key drivers of changing tick populations and tick‐borne pathogen dynamics, altering infection risk through coupled socioecological pathways that mediate interactions between tick vectors, vertebrate hosts, and humans. Patterns of host diversity may be particularly idiosyncratic across urbanized landscapes, due to trade‐offs between extreme fragmentation that reduces habitat suitability and access, and human activities that artificially increase resource availability for wildlife. We used camera and hair trap surveys and tick sampling to identify links between landscape composition and configuration, the mammalian host community, and the presence of three tick vector species at a human–wildlife interface in New York City, an emerging area within an endemic region for several tick‐borne diseases. We found that human infrastructures, such as the presence of fences in yards, could affect mammal host community composition by changing the “hardness” of edges between urban greenspaces and residential areas. We identified yard‐ and broader landscape‐level features associated with the presence of urban mammal species, and identified cascading effects of host community composition on tick distribution in yards, suggesting management implications for the mitigation of human exposure to tick‐borne pathogens. In particular, we identified a possible role of ubiquitous mesomammals, such as raccoons (Procyon lotor), in transporting Amblyomma americanum ticks between parks and neighboring residential yards, and confirmed the key role of white‐tailed deer (Odocoileus virginianus) for introducing Ixodes scapularis ticks into yards. Our results challenge assumptions that biodiversity loss in human‐modified areas always increases the risk for tick‐borne diseases. Instead, we found many residential sites had higher mammal species richness and higher detection of low reservoir competent (“dilution”) hosts for Borrelia burgdorferi, such as opossums (Didelphis virginiana), than paired forested greenspaces. Our study highlights the importance of disentangling the mechanisms mediating tick‐borne disease hazard as a critical first step toward reducing urban tick‐borne disease risk.
Expansion of human γδ T cells in periphery: Lessons learned from development, infections, and compromised thymic function
Authors: Ravens Sarina , Tolosa Eva 
Published: August 2024

Abstractγδ T cells predominantly develop in the fetal period. Post birth they respond swiftly to environmental insults, pathogens and tumors, especially when other immune effector cells are less ready to function. Most of our understanding of γδ T‐cell development, peripheral adaptation, and function derives from murine studies. The recent advancement of immunological methods allows now to decipher human γδ T‐cell biology in patient cohorts and tissue samples, and to manipulate them using in vitro systems. In this review, we summarize γδ T‐cell development in the human thymus, their functional adaptation to the microbial environment from birth until old age, and their capacity to expand and fill up the peripheral niche under conditions of perturbations of conventional T‐cell development.
Photocatalyst‐Free Synthesis of Oxindoles and Isoquinolinediones via the Radical Reaction of N‐Arylacrylamides with Monoalkyl Cesium Oxalate Salts by Visible Light Catalysis
Authors: Zhao Chenyue , Xu Jinli , Cheng Dongping , Xu Xiaoliang 
Published: August 2024

AbstractA photocatalyst‐free cascade reaction of N‐alkyl‐N‐arylmethacrylamides with monoalkyl cesium oxalate salts is described. In the presence of visible light and (NH4)2S2O8, monoalkyl cesium oxalate salts undergo single‐electron oxidation/CO2 extrusion to generate alkyl radicals, followed by the addition and subsequent cyclization to give alkylated oxindoles. In addition, N‐alkyl‐N‐methacryloylbenzamides could be applied for the cascade reaction, providing a series of alkylated isoquinolinediones, which are completely different from the products obtained with monoalkyl oxalates as substrates.
Constructal design of cross‐flow heat exchanger with concave/convex fins
Authors: Mustafa Ahmed Waheed , Jawad Israa R. , Mohammed Ansam Adil 
Published: August 2024

AbstractA contractual design of cross‐flow heat exchanger with concave/convex fins under fixed pressure drop is presented in this paper. An array of heated concave and convex fins are placed in a fixed area, and they are cooled by incoming cross flow, which is moving towards the fins due to constant pressure drop. The distances from fin to fin, the fin base, and the fin surface curvature (concave and convex) are free to morph and are constrained by the fin length and the height of cross flow. Bejan's number ranges from 105 to 107. The ratio of fin base‐to‐fin length is changed from 0.1 to 0.3. The dimensionless mass, momentum, and energy equations for two‐dimensional, steady, and incompressible flow are solved based on the finite volume numerical method. Also, the scale analysis method is used to compare heat transfer densities from concave and convex fins. The numerical results showed that the maximal convective heat transfer density for convex fins is higher than that of the concave fins for all Bejan numbers. The augmentations in the maximal heat transfer density are 2.1% at Be = 105, 4% at Be = 106, and 12.5% at Be = 107. Also, this is confirmed by the scale analysis method.
Characterization of the in vitro penetration and first‐pass metabolism of genistein and daidzein using human and pig skin explants and Phenion full‐thickness skin models
Authors: Géniès Camille , Jeanjean Corinne , Najjar Abdulkarim , Schepky Andreas , Lange Daniela , Kühnl Jochen , Fabian Eric , Zifle Anne , Duplan Hélène , Hewitt NIcola J. , Jacques Carine 
Published: August 2024

AbstractOECD test guideline compliant skin penetration studies, which also comply with the SCCS basic criteria, are lacking for genistein and daidzein. Therefore, we have measured their penetration and metabolism using ex vivo explants of fresh (i.e., metabolically viable) pig skin, fresh and frozen human skin, and Phenion full‐thickness (FT) models. Preliminary studies using fresh pig skin helped to define the optimal experimental conditions. The dermal absorption of 10 nmoles/cm2 genistein and daidzein in ethanol was comparable in all four models. A first‐pass metabolism in skin to glucuronide and sulfate metabolites was demonstrated for both chemicals in all models except frozen human skin. The main difference between fresh skin models was the overall extent of metabolism and the relative ratio of each metabolite, for example, much lower sulfate conjugates were formed in pig skin incubations. The extent of parent chemical metabolized and the contribution of the glucuronide pathway were relatively lower in PhenionFT models than in fresh human skin, possibly due to a higher penetration rate in this model and differences in the expression of functional metabolizing enzymes. When metabolism in human skin was abolished by freezing, more radiolabelled chemical remained in the skin tissue but the overall dermal absorption was unchanged. In conclusion, this initial characterization study showed that all models tested indicated that genistein and daidzein extensively penetrated the skin when applied to skin in ethanol. All fresh skin models produced the same metabolites, with the known species difference in the sulfation pathway demonstrated in pig skin.
Effect of vehicle on the in vitro penetration and metabolism of genistein and daidzein in ex vivo skin explants and the Phenion full‐thickness skin model
Authors: Géniès Camille , Jeanjean Corinne , Najjar Abdulkarim , Schepky Andreas , Lange Daniela , Kühnl Jochen , Fabian Eric , Zifle Anne , Duplan Helene , Hewitt Nicola J. , Jacques Carine 
Published: August 2024

AbstractIn a read‐across assessment of the safety of genistein and daidzein in cosmetic products, additional information was required to account for differences in their systemic exposure after topical application in a typical body lotion formulation. Therefore, we measured the penetration and metabolism of two doses (3 and 30 nmoles/cm2) of genistein and daidzein applied in ethanol and in a body formulation to fresh pig skin, fresh and frozen human skin, and PhenionFT models. Both chemicals readily penetrated all skin models when applied in ethanol. The same sulfate and glucuronide metabolites were formed in fresh pig skin, fresh human skin, and PhenionFT models, which also all demonstrated that (a) these pathways could be saturated between 3 and 30 nmoles/cm2 and (b) the extent of metabolism of daidzein was lower than genistein. Although the relative amounts of radiolabeled chemical in human skin and medium compartments were altered by freezing, their overall bioavailability was not affected. The greatest impact on the bioavailability and distribution of both chemicals was observed when they were applied in the formulation. Most of the dose applied in the formulation was retained on the skin surface, especially at 30 nmoles/cm2 (60%–90%), resulting in much lower amounts in the medium and/or skin. In conclusion, all four skin models demonstrated first‐pass metabolism of genistein and daidzein and a marked alteration in their disposition by applying them in a body lotion formulation. This supports the use of fresh pig skin and PhenionFT models as alternatives to human skin for investigating skin metabolism and formulation effects for these two chemicals. The results were used to develop the dermal module of a PBPK model and dose setting for organ‐on‐chip experiments. They could also be used to refine internal exposure estimates in regulatory safety assessments.
Engineered hybrid iron‐cobalt metal oxide nanoparticles for effective adsorption of malachite green dye
Authors: Hussain Nasira , Shafaat Shanza , Sarfraz Ambreen , Usman Muhammad , Khan Muhammad Saqib , Khan Asad Muhammad , Khan Rafaqat Ali , Amin Bilal Ahmad Zafar , Bilal Muhammad , Shaikh Ahson Jabbar 
Published: August 2024

AbstractBACKGROUNDHybrid iron and cobalt metal oxide nanoparticles are well known; however, are not optimized in terms of size and stability. We engineered these hybrid nanoparticles using the co‐precipitation method and characterized them by various techniques, which are then used for the effective adsorption and removal of malachite green (MG) dye.RESULTSThe ideal conditions for synthesis are determined to be 50:50 ratio of Fe2O3 and CoO, pH of 11, temperature range of 40 °C–60 °C, and reactant addition time of 20 min. These hybrid nanoadsorbents effectively eliminated MG dye from aqueous solutions. Factors such as initial MG dye concentration, pH of the medium, contact time, temperature, and nanoadsorbent dose were optimized for the MG removal to achieve a maximum removal efficiency of 96.9%. Non‐linear fitting of data indicates that both Langmuir and Freundlich models provided the best fit, suggesting the presence of both monolayer and multilayer adsorption of MG on hybrid nanoparticles. The kinetics of MG dye removal are better controlled by the intraparticle diffusion (IPD) phenomenon. The adsorption of MG onto the hybrid nanoparticles was confirmed to be endothermic, with negative ΔG and positive ΔH values. The optimized synthetic conditions also positively impacted the hybrid nanoparticles which enhanced the adsorption and exhibited ferromagnetic behavior as compared to the superparamagnetic behavior reported in the literature, making them significantly important for dye removal applications.CONCLUSIONThese findings demonstrate the potential of optimized hybrid nanoparticles as effective nanoadsorbents for dye removal applications, with implications for further applications in photocatalysis and sensing. © 2024 Society of Chemical Industry (SCI).