bluuebunny/crossref_metadata_2025_split huggingface dataset:
Comparison of NCEP Multisensor Precipitation Estimates with Independent Gauge Data over the Eastern United States
Authors: Wootten Adrienne , Boyles Ryan P. 
Published: September 2014

AbstractGauge-calibrated radar estimates of daily precipitation are compared with daily observed values of precipitation from National Weather Service (NWS) Cooperative Observer Network (COOP) stations to evaluate the multisensor precipitation estimate (MPE) product that is gridded by the National Centers for Environmental Prediction (NCEP) for the eastern United States (defined as locations east of the Mississippi River). This study focuses on a broad evaluation of MPE across the study domain by season and intensity. In addition, the aspect of precipitation type is considered through case studies of winter and summer precipitation events across the domain. Results of this study indicate a north–south gradient in the error of MPE and a seasonal pattern with the highest error in summer and autumn and the lowest error in winter. Two case studies of precipitation are also considered in this study. These case studies include instances of intense precipitation and frozen precipitation. These results suggest that MPE is less able to estimate convective-scale precipitation as compared with precipitation variations at larger spatial scales. In addition, the results suggest that MPE is subject to errors related both to the measurement gauges and to the radar estimates used. Two case studies are also included to discuss the differences with regard to precipitation type. The results from these case studies suggest that MPE may have higher error associated with estimating the liquid equivalent of frozen precipitation when compared with NWS COOP network data. The results also suggest the need for more analysis of MPE error for frozen precipitation in diverse topographic regimes.
A Conceptual Model of Ocean Heat Uptake under Climate Change
Authors: Marshall David P. , Zanna Laure 
Published: September 2014

Abstract
A conceptual model of ocean heat uptake is developed as a multilayer generalization of Gnanadesikan. The roles of Southern Ocean Ekman and eddy transports, North Atlantic Deep Water (NADW) formation, and diapycnal mixing in controlling ocean stratification and transient heat uptake are investigated under climate change scenarios, including imposed surface warming, increased Southern Ocean wind forcing, with or without eddy compensation, and weakened meridional overturning circulation (MOC) induced by reduced NADW formation. With realistic profiles of diapycnal mixing, ocean heat uptake is dominated by Southern Ocean Ekman transport and its long-term adjustment controlled by the Southern Ocean eddy transport. The time scale of adjustment setting the rate of ocean heat uptake increases with depth. For scenarios with increased Southern Ocean wind forcing or weakened MOC, deepened stratification results in enhanced ocean heat uptake. In each of these experiments, the role of diapycnal mixing in setting ocean stratification and heat uptake is secondary. Conversely, in experiments with enhanced diapycnal mixing as employed in “upwelling diffusion” slab models, the contributions of diapycnal mixing and Southern Ocean Ekman transport to the net heat uptake are comparable, but the stratification extends unrealistically to the sea floor. The simple model is applied to interpret the output of an Earth system model, the Second Generation Canadian Earth System Model (CanESM2), in which the atmospheric CO2 concentration is increased by 1% yr−1 until quadrupling, where it is found that Southern Ocean Ekman transport is essential to reproduce the magnitude and vertical profile of ocean heat uptake.
Advanced Two-Moment Bulk Microphysics for Global Models. Part II: Global Model Solutions and Aerosol–Cloud Interactions*
Authors: Gettelman A. , Morrison H. , Santos S. , Bogenschutz P. , Caldwell P. M. 
Published: September 2014

Abstract
A modified microphysics scheme is implemented in the Community Atmosphere Model, version 5 (CAM5). The new scheme features prognostic precipitation. The coupling between the microphysics and the rest of the model is modified to make it more flexible. Single-column tests show the new microphysics can simulate a constrained drizzling stratocumulus case. Substepping the cloud condensation (macrophysics) within a time step improves single-column results. Simulations of mixed-phase cases are strongly sensitive to ice nucleation. The new microphysics alters process rates in both single-column and global simulations, even at low (200 km) horizontal resolution. Thus, prognostic precipitation can be important, even in low-resolution simulations where advection of precipitation is not important. Accretion dominates as liquid water path increases in agreement with cloud-resolving model simulations and estimates from observations. The new microphysics with prognostic precipitation increases the ratio of accretion over autoconversion. The change in process rates appears to significantly reduce aerosol–cloud interactions and indirect radiative effects of anthropogenic aerosols by up to 33% (depending on substepping) to below 1 W m−2 of cooling between simulations with preindustrial (1850) and present-day (2000) aerosol emissions.
On the Climatology of Precipitable Water and Water Vapor Flux in the Mid-Atlantic Region of the United States
Authors: Ryu Young-Hee , Smith James A. , Bou-Zeid Elie 
Published: September 2014

Abstract
The seasonal and diurnal climatologies of precipitable water and water vapor flux in the mid-Atlantic region of the United States are examined. A new method of computing water vapor flux at high temporal resolution in an atmospheric column using global positioning system (GPS) precipitable water, radiosonde data, and velocity–azimuth display (VAD) wind profiles is presented. It is shown that water vapor flux exhibits striking seasonal and diurnal cycles and that the diurnal cycles exhibit rapid transitions over the course of the year. A particularly large change in the diurnal cycle of meridional water vapor flux between spring and summer seasons is found. These features of the water cycle cannot be resolved by twice-a-day radiosonde observations. It is also shown that precipitable water exhibits a pronounced seasonal cycle and a less pronounced diurnal cycle. There are large contrasts in the climatology of water vapor flux between precipitation and nonprecipitation conditions in the mid-Atlantic region. It is hypothesized that the seasonal transition of large-scale flow environments and the change in the degree of differential heating in the mountainous and coastal areas are responsible for the contrasting diurnal cycle between spring and summer seasons.
Using Temporal Changes in Drought Indices to Generate Probabilistic Drought Intensification Forecasts
Authors: Otkin Jason A. , Anderson Martha C. , Hain Christopher , Svoboda Mark 
Published: September 2014

Abstract
In this study, the potential utility of using rapid temporal changes in drought indices to provide early warning of an elevated risk for drought development over subseasonal time scales is assessed. Standardized change anomalies were computed each week during the 2000–13 growing seasons for drought indices depicting anomalies in evapotranspiration, precipitation, and soil moisture. A rapid change index (RCI) that encapsulates the accumulated magnitude of rapid changes in the weekly anomalies was computed each week for each drought index, and then a simple statistical method was used to convert the RCI values into drought intensification probabilities depicting the likelihood that drought severity as analyzed by the U.S. Drought Monitor (USDM) would worsen in subsequent weeks. Local and regional case study analyses revealed that elevated drought intensification probabilities often occur several weeks prior to changes in the USDM and in topsoil moisture and crop condition datasets compiled by the National Agricultural Statistics Service. Statistical analyses showed that the RCI-derived probabilities are most reliable and skillful over the central and eastern United States in regions most susceptible to rapid drought development. Taken together, these results suggest that tools used to identify areas experiencing rapid changes in drought indices may be useful components of future drought early warning systems.
Socioeconomic Impact Assessment in Ex Ante Evaluations
Authors: Vidueira Pablo , Díaz-Puente José M. , Rivera María 
Published: September 2014

Background: Ex ante impact assessment has become a fundamental tool for effective program management, and thus, a compulsory task when establishing a new program in the European Union (EU). Objective: This article aims to analyze benefits from ex ante impact assessment, methodologies followed, and difficulties encountered. This is done through the case study on the rural development programs (RDPs) in the EU. Results regarding methodologies are then contrasted with the international context in order to provide solid insights to evaluators and program managing authorities facing ex ante impact assessment. Research design: All European RDPs from the period 2007 through 2013 (a total of 88) and their corresponding available ex ante evaluations (a total of 70) were analyzed focusing on the socioeconomic impact assessment. Results: Only 46.6% of the regions provide quantified impact estimations on socioeconomic impacts in spite of it being a compulsory task demanded by the European Commission (EC). Recommended methods by the EC are mostly used, but there is a lack of mixed method approaches since qualitative methods are used in substitution of quantitative ones. Two main difficulties argued were the complexity of program impacts and the lack of needed program information. Conclusions: Qualitative approaches on their own have been found as not suitable for ex ante impact assessment, while quantitative approaches—such as microsimulation models—provide a good approximation to actual impacts. However, time and budgetary constraints make that quantitative and mixed methods should be mainly applied on the most relevant impacts for the program success.
Formulating a New Three Energy Framework of Personality for Conflict Analysis and Resolution based on Triguna Concept of Bhagavad Gita
Authors: Modh Satish 
Published: September 2014

Theories of interpersonal conflict analysis and resolution originate from sociology, social psychology and political science. These theories took shape during twentieth century after World War I and World War II. Some of the prominent conflict resolution theories are Burton’s ‘human needs theory’, Roger Fisher’s ‘principled-negotiation’ and Lederach’s ‘Conflict transformation’. Conflict is an inevitable part of living because it is related to situations of scarce resources, division of functions, power relations and role-differentiation. In the organizational environment, awareness of each employee’s nature is critical to success. When such employees are self-aware, workplace conflict can be minimized and can become productive to the organization.  This study develops a new three energy framework of personality for conflict analysis and resolution. This framework is based on the ‘ guna’ concept of Bhagavad Gita, an ancient Hindu scripture. The term ‘ guna’ indicates the ‘inherent energy’ with which the human mind functions. These three energies are: Positive Energy ( sattva), Dynamic Energy ( rajas) and Potential Energy ( tamas). People work under influence of these three energies all the time and go through various physical, emotional and intellectual experiences. The quality and quantity of these experiences determines their personality, pattern of behaviours and conduct.
Palygorskite genesis through silicate transformation in Tunisian continental Eocene deposits
Authors: Jamoussi F. , Ben Aboud A. , López-Galindo A. 
Published: September 2014

AbstractThe mineralogical and geochemical characteristics of Eocene continental sediments in south central Tunisia (Chebket Bouloufa and Jebel Hamri) and in north central Tunisia (Jebel Lessouda and Jebel Rhéouis), which contain considerable amounts of palygorskite, were studied. The clay fraction of the sediments also comprises illite, kaolinite, Mg smectite and Al smectite, together with carbonates (calcite and/or dolomite), quartz, gypsum and feldspars, all of which are present in extremely variable proportions.The textural characteristics of the samples containing most palygorskite, as well as the chemical composition of the fibres and the contents of certain trace and rare earth elements suggest that the genesis of this fibrous clay is intimately linked to the diagenetic transformation of illite, mixedlayered minerals and/or Al smectite, as has also been observed in contemporaneous deposits in Morocco.
Clay minerals in the Namacotche Pegmatite Group from Zambezia Province, Mozambique: main constituents of late-stage secondary paragenesis
Authors: Sequeira Braga M. A. , Leal Gomes C. , Duplay J. , Paquet H. 
Published: September 2014

AbstractNamacotche gem-bearing pegmatites of Alto Ligonha pegmatite district are heterogeneous, strongly fractionated, and have large Li and Ta and extremely large Cs contents. Clay samples were collected in fracture infillings and dilation cavities with gemstones and were studied using X-ray diffraction (XRD), polarized light microscope, scanning electron microscopy-energy dispersive spectroscopy, high-resolution transmission electron microscopy and chemical analyses. The <2 μm fraction contains cookeite, illite, illite-smectite and suggested irregular mixed-layer cookeite-smectite, beidellite, montmorillonite, kaolinite and goethite.The XRD patterns of chlorite and their d values suggest the presence of ‘di-trioctahedral chlorite’ similar to cookeite-Ia polytype. Cookeite chemical analyses show that Li contents range from 0.82 to 1.08 atoms per half unit cell.A close relationship has been established between occurrences of gemstones and clay minerals. Some important textures and crystal chemistry are discussed.The main gemstones related to the Namacotche Pegmatite are: morganite (pink cesian beryl), kunzite (spodumene) and elbaite tourmaline. As the mechanisms responsible for the gemstone formation take place at low temperature, the clay minerals paragenesis cookeite ± cookeite-smectite interstratification ± beidellite + montmorillonite ± illite-smectite interstratification, represents a late-stage secondary paragenesis, generated by hydrothermal alteration.
Effect of sulfur hexafluoride gas and post-annealing treatment for inductively coupled plasma etched barium titanate thin films
Authors: Wang Cong , Li Yang , Yao Zhao , Kim Hong-Ki , Kim Hyung-Jun , Kim Nam-Young 
Published: September 2014

Abstract
Aerosol deposition- (AD) derived barium titanate (BTO) micropatterns are etched via SF6/O2/Ar plasmas using inductively coupled plasma (ICP) etching technology. The reaction mechanisms of the sulfur hexafluoride on BTO thin films and the effects of annealing treatment are verified through X-ray photoelectron spectroscopy (XPS) analysis, which confirms the accumulation of reaction products on the etched surface due to the low volatility of the reaction products, such as Ba and Ti fluorides, and these residues could be completely removed by the post-annealing treatment. The exact peak positions and chemicals shifts of Ba 3d, Ti 2p, O 1 s, and F 1 s are deduced by fitting the XPS narrow-scan spectra on as-deposited, etched, and post-annealed BTO surfaces. Compared to the as-deposited BTOs, the etched Ba 3d

5/2
, Ba 3d

3/2
, Ti 2p

3/2
, Ti 2p

1/2
, and O 1 s peaks shift towards higher binding energy regions by amounts of 0.55, 0.45, 0.4, 0.35, and 0.85 eV, respectively. A comparison of the as-deposited film with the post-annealed film after etching revealed that there are no significant differences in the fitted XPS narrow-scan spectra except for the slight chemical shift in the O 1 s peak due to the oxygen vacancy compensation in O2-excessive atmosphere. It is inferred that the electrical properties of the etched BTO film can be restored by post-annealing treatment after the etching process. Moreover, the relative permittivity and loss tangent of the post-annealed BTO thin films are remarkably improved by 232% and 2,695%, respectively.
Magnetic liposomes for colorectal cancer cells therapy by high-frequency magnetic field treatment
Authors: Hardiansyah Andri , Huang Li-Ying , Yang Ming-Chien , Liu Ting-Yu , Tsai Sung-Chen , Yang Chih-Yung , Kuo Chih-Yu , Chan Tzu-Yi , Zou Hui-Ming , Lian Wei-Nan , Lin Chi-Hung 
Published: September 2014

Abstract
In this study, we developed the cancer treatment through the combination of chemotherapy and thermotherapy using doxorubicin-loaded magnetic liposomes. The citric acid-coated magnetic nanoparticles (CAMNP, ca. 10 nm) and doxorubicin were encapsulated into the liposome (HSPC/DSPE/cholesterol = 12.5:1:8.25) by rotary evaporation and ultrasonication process. The resultant magnetic liposomes (ca. 90 to 130 nm) were subject to characterization including transmission electron microscopy (TEM), dynamic light scattering (DLS), X-ray diffraction (XRD), zeta potential, Fourier transform infrared (FTIR) spectrophotometer, and fluorescence microscope. In vitro cytotoxicity of the drug carrier platform was investigated through 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT) assay using L-929 cells, as the mammalian cell model. In vitro cytotoxicity and hyperthermia (inductive heating) studies were evaluated against colorectal cancer (CT-26 cells) with high-frequency magnetic field (HFMF) exposure. MTT assay revealed that these drug carriers exhibited no cytotoxicity against L-929 cells, suggesting excellent biocompatibility. When the magnetic liposomes with 1 μM doxorubicin was used to treat CT-26 cells in combination with HFMF exposure, approximately 56% cells were killed and found to be more effective than either hyperthermia or chemotherapy treatment individually. Therefore, these results show that the synergistic effects between chemotherapy (drug-controlled release) and hyperthermia increase the capability to kill cancer cells.
Ferromagnetism and optical properties of La1 − xAl
x
FeO3 nanopowders
Authors: Janbutrach Yutana , Hunpratub Sitchai , Swatsitang Ekaphan 
Published: September 2014

Abstract
La1 − x
Al
x
FeO3 (x = 0.0, 0.05, 0.1, 0.2, 0.3, 0.4, and 0.5) nanopowders were prepared by polymerization complex method. All prepared samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), and UV-vis spectrophotometry (UV-vis). The magnetic properties were investigated using a vibrating sample magnetometer (VSM). The X-ray results of all samples show the formation of an orthorhombic phase with the second phase of α-Fe2O3 in doped samples. The crystallite sizes of nanoparticles decreased with increasing Al content, and they are found to be in the range of 58.45 ± 5.90 to 15.58 ± 4.64 nm. SEM and TEM images show the agglomeration of nanoparticles with average particle size in the range of 60 to 75 nm. The FT-IR spectra confirm the presence of metal oxygen bonds of O-Fe-O and Fe-O in the FeO6 octahedra. The UV-vis spectra show strong absorption peaks at approximately 285 nm, and the calculated optical band gaps are found to be in the range of 2.05 to 2.09 eV with increasing Al content. The M-H loop of the pure sample is antiferromagnetic, whereas those of the doped samples tend to be ferromagnetic with increasing Al content. The magnetization, remanent magnetization, and coercive field of the Al-doped sample with x = 0.5 are enhanced to 1.665 emu/g, 0.623 emu/g, and 4,087.0 Oe, respectively.
Fe effect on the optical properties of TiO2:Fe2O3 nanostructured composites supported on SiO2 microsphere assemblies
Authors: Peña-Flores Jesús I , Palomec-Garfias Abraham F , Márquez-Beltrán César , Sánchez-Mora Enrique , Gómez-Barojas Estela , Pérez-Rodríguez Felipe 
Published: September 2014

Abstract
The effect of Fe ion concentration on the morphological, structural, and optical properties of TiO2 films supported on silica (SiO2) opals has been studied. TiO2:Fe2O3 films were prepared by the sol-gel method in combination with a vertical dip coating procedure; precursor solutions of Ti and Fe were deposited on a monolayer of SiO2 opals previously deposited on a glass substrate by the same procedure. After the dip coating process has been carried out, the samples were thermally treated to obtain the TiO2:Fe2O3/SiO2 composites at the Fe ion concentrations of 1, 3, and 5 wt%. Scanning electron microscopy (SEM) micrographs show the formation of colloidal silica microspheres of about 50 nm diameter autoensembled in a hexagonal close-packed fashion. Although the X-ray diffractograms show no significant effect of Fe ion concentration on the crystal structure of TiO2, the μ-Raman and reflectance spectra do show that the intensity of a phonon vibration mode and the energy bandgap of TiO2 decrease as the Fe+3 ion concentration increases.
The sheep KAP8-2 gene, a new KAP8 family member that is absent in humans
Authors: Gong Hua , Zhou Huitong , Dyer Jolon M , Hickford Jon GH 
Published: September 2014

Abstract
The keratin-associated proteins (KAPs) are fundamental components of hair and wool fibres, and are believed to in part be responsible for some of the properties of these fibres. KAPs can be divided into three groups: the high sulphur (HS) KAPs, the ultra-high sulphur (UHS) KAPs and the high glycine-tyrosine (HGT) KAPs. KAP8 is a HGT-KAP family and was believed to be coded for by a single gene in both humans and sheep. However, the recent identification of a KAP8-2 gene in goats led us to investigate whether a KAP8-2 gene exists in sheep.
A BLAST search of the Ovine Genome Assembly v2.0 using the coding sequence of caprine KRTAP8-2 identified a homologous region on sheep chromosome 1 (OAR1:123005473_123005664; E = e-101). This region was clustered with a number of previously identified KAP genes including (in order from the centromere) KRTAP11-1, KRTAP7-1, KRTAP8-1, KRTAP6-2, KRTAP6-1, KRTAP13-3 and KRTAP24-1. PCR-SSCP analysis of the notional gene revealed two dissimilar PCR-SSCP banding patterns, representing two DNA sequences. A single nucleotide difference 21 bp upstream of the TATA box was identified. The two sequences did not have great homology with known ovine KRTAP sequences, but high sequence identity was found with KRTAP8-2 from goats and reindeer. These results suggest that sheep possess a KAP8-2 gene and that this gene is polymorphic.
The notional KAP8-2 protein is comprised of 63 amino acid residues and is rich in glycine and tyrosine, but has a low cysteine content. In contrast to other HGT-KAPs, ovine KAP8-2 contains more acidic amino acid residues, and this would likely result in a lower isoelectric point (pI) of 6.3.