bluuebunny/crossref_metadata_2025_split huggingface dataset:
The effect of temperature and pressure on the crystal structure of piperidine
Authors: Budd Laura E , Ibberson Richard M , Marshall William G , Parsons Simon 
Published: April 2015

Abstract

Background
The response of molecular crystal structures to changes in externally applied conditions such as temperature and pressure are the result of a complex balance between strong intramolecular bonding, medium strength intermolecular interactions such as hydrogen bonds, and weaker intermolecular van der Waals contacts. At high pressure the additional thermodynamic requirement to fill space efficiently becomes increasingly important.

Results
The crystal structure of piperidine-d11 has been determined at 2 K and at room temperature at pressures between 0.22 and 1.09 GPa. Unit cell dimensions have been determined between 2 and 255 K, and at pressures up to 2.77 GPa at room temperature. All measurements were made using neutron powder diffraction. The crystal structure features chains of molecules formed by NH…N H-bonds with van der Waals interactions between the chains. Although the H-bonds are the strongest intermolecular contacts, the majority of the sublimation enthalpy may be ascribed to weaker but more numerous van der Waals interactions.

Conclusions
Analysis of the thermal expansion data in the light of phonon frequencies determined in periodic DFT calculations indicates that the expansion at very low temperature is governed by external lattice modes, but above 100 K the influence of intramolecular ring-flexing modes also becomes significant. The principal directions of thermal expansion are determined by the sensitivity of different van der Waals interactions to changes in distance. The principal values of the strain developed on application of pressure are similarly oriented to those determined in the variable-temperature study, but more isotropic because of the need to minimise volume by filling interstitial voids at elevated pressure.
Factors Related to Complications Among Adult Patients With Intellectual Disabilities Hospitalized at an Academic Medical Center
Authors: Ailey Sarah H. , Johnson Tricia J. , Fogg Louis , Friese Tanya R. 
Published: April 2015

Abstract
People with intellectual disabilities (ID) represent a small but important group of hospitalized patients who have higher rates of complications than do patients without ID hospitalized for the same reasons. Complications are potentially avoidable conditions, such as healthcare-acquired infections, healthcare-acquired skin breakdown, falls, and medication errors and reactions. Addressing factors related to complications can focus efforts to improve hospital care. The purpose of this exploratory study was to analyze data from reviews of academic medical center charts (N  =  70) about complications and to examine patient and hospitalization characteristics in relation to complications among adult patients (age ≥ 18 years) with ID hospitalized for nonpsychiatric reasons. Adults with ID tended to be twice as likely to have complications (χ2  =  2.893, df  =  1, p  =  .09) if they had a surgical procedure and were nearly four times as likely to have complications (χ2  =  6.836, df  =  1, p  =  .009) if they had multiple chronic health conditions (three of the following: history of cerebral palsy, autism spectrum symptoms, aggressive behavior, respiratory disorder, and admission through the emergency department). Findings suggest preliminary criteria for assessing risk for complications among hospitalized people with ID and the need for attention to their specific needs when hospitalized.
The Role of the Private Sphere in US Healthcare Entitlements: Increased Spending, Weakened Public Mobilization, and Reduced Equity
Authors: Grogan Colleen M. 
Published: April 2015

AbstractThe private sphere has always been an important component in US healthcare entitlements. Since the ACA further embeds the role of private actors, how private actors make claims on the state, and how the state reacts to these claims, becomes even more important, because such claims significantly shape US healthcare entitlements. The extent and increase of private benefits and contracting with private health plans is explicated for each healthcare entitlement program. The politics of how private inclusion shapes healthcare entitlements is examined with three main implications: it (1) creates a dominant discourse of health care deficits and spending crises; (2) submerges the role of government and may diminish mobilization for claiming entitlements; and (3) reduces equity in the distribution of costs and benefits. I conclude by highlighting that there are simple policy designs to address these problems, but the political dynamics of private inclusion will likely work against such policy logics.
Free Will and Folly in As You Like It
Authors: Watt Gary 
Published: April 2015

AbstractThe testamentary will of a deceased person seldom features in Shakespeare’s comedies. What is more common is the performance of a will so stubborn and having such a bearing on the estate of the one subject to it that it may be said to exert a testamentary force. Comedy lies in the possibility of escape from a world of subjection to another’s will into a world of freedom to express a will of one’s own. In many of Shakespeare’s comedies escape takes the form of actual physical flight to a new domain – typically from court to country. The trajectory of this escape is from a hierarchical scheme of social status, to a horizontal plane of communal relations; from a traditional scheme in which property and power is handed down, to a scheme of trade in which they pass horizontally from hand-to-hand contractually. This paper will argue that
Illegal Search and Seizure, Due Process, and the Rights of the Accused: The Voices of Power in the Rhetoric of Los Angeles Police Chief William H. Parker
Authors: Gooch John Casey 
Published: April 2015

AbstractAs a rhetorical analysis, this paper considers “voices of power” in the discourse of William H. (“Bill”) Parker, former police chief of Los Angeles from 1950 until 1966. Specifically, it tells the story of a conflict between powerful voices, with Chief Parker on one side of a debate over the rights of the accused and the United States Supreme Court on the other. Three case studies serve as the basis for illustrating the Chief’s rhetorical strategies. In 1954, Parker’s responded to the majority opinion of the U.S. Supreme Court in
The Judge’s Voice: Literary and Legal Emblemata
Authors: Gaakeer Jeanne 
Published: April 2015

AbstractIn literary-legal discussions of the subject of “voice” in law the focus is often on the voices of defendants and victims, on the view that for a variety of reasons their voices are the ones most often diminished or even totally “unheard.” On the view that voice and speech are connected and that one’s voice is therefore important for one’s identity, I aim to look in this paper at the judge’s voice in law and literature. While the metaphor “the voice of the law” is traditionally taken to refer to judicial impartiality and/or a formalistic view of law as distant from the actions or disputes it is supposed to govern, I want to take the words literally and, on the view that getting a voice of one’s own as a judge requires more than institutional authority and power, ask questions including, but not limited to: What if the voice of the judge is oppressed or even silenced, e.g. by undue influence of a third party? What if the judge is unable to find the right voice when she experiences cognitive dissonances between her institutional voice and her conscience? What space is the judge allowed in the public sphere to speak her voice on cases pending or on societal developments? What space is the judge allowed to show her emotions inside the courtroom? I hope to illustrate my point with emblemata for further discussion in the form of European Human Rights Court decisions and literary works including Lowell B. Komie’s short story “Ash,” Ernst Wiechert’s novella “The judge,” and Kiran Desai’s novel
Representing the Unrepresentable: Making Law Anyway?
Authors: Ost François , Ost Isabelle 
Published: April 2015

Abstract“Representation crisis” is certainly an expression that is too imprecise, clichéd and all-embracing: of little use. However, we have to recognize that the theatrical and literary experiments that shook the classical notion of representation in the twentieth century have been fruitful, not only in the arts, but also in terms of their repercussions in the human sciences. Law is no exception to this. On the contrary, its eminently representative nature benefits from being examined in the mirror of the critical experiments provided by fiction. This is, in a very condensed form, the initial postulate that will underpin our hypothesis, which will consist in showing the usefulness of investigating the notion of representation in law through art and literary theory, as well as through examples drawn from concrete theatrical and fictional works, owing to the light theatre and fiction can shed on the fragile balance, the “representational” razor, on which the law rests.
A growth‐rate composition formula for the growth of E. coli on co‐utilized carbon substrates
Authors: Hermsen Rutger , Okano Hiroyuki , You Conghui , Werner Nicole , Hwa Terence 
Published: April 2015

AbstractWhen bacteria are cultured in medium with multiple carbon substrates, they frequently consume these substrates simultaneously. Building on recent advances in the understanding of metabolic coordination exhibited by Escherichia coli cells through cAMP‐Crp signaling, we show that this signaling system responds to the total carbon‐uptake flux when substrates are co‐utilized and derive a mathematical formula that accurately predicts the resulting growth rate, based only on the growth rates on individual substrates.
Should Happiness Be Taught in School? / Treba li sreću poučavati u školi?
Authors: Rijavec Majda 
Published: April 2015

AbstractWithin positive psychology, the concept of well-being (happiness) represents the main criteria for positive functioning and is generally considered the goal in life to be promoted. Research in this field is providing very strong evidence that happiness brings highly desirable life benefits, such as better health and longer life, successful relationships and better work performance. The most important reasons for teaching happiness in school are high prevalence of depression among young people worldwide, the small rise in life satisfaction in the last half a century, low students’ satisfaction with school in many countries, and the synergy between learning and positive emotion. A number of studies suggest that school-based positive psychology programmes are effective in improving positive traits and well-being, even though reliability of these findings is still questioned. The Model for Positive Education is presented in this paper as a possible area of future research. This is applied framework of implementing positive psychology as a whole-school approach targeting six well-being domains, including positive emotions, positive engagement, positive accomplishment, positive purpose, positive relationships, and positive health, with a focus on character strengths. Key words: happiness; positive education; positive psychology; school; well-being --- SažetakU okviru pozitivne psihologije pojam dobrobit predstavlja glavni kriterij pozitivnog funkcioniranja i općenito se smatra važnim životnim ciljem. Istraživanja u tom području daju vrlo jake dokaze da sreća dovodi do različitih životnih prednosti, kao što su bolje zdravlje i duži život, uspješni odnosi i bolji uspjeh na poslu. Najvažniji razlozi za poučavanje sreće u školi jesu raširenost depresije kod mladih ljudi diljem svijeta, mali porast životnog zadovoljstva u posljednjih pola stoljeća, učeničko nezadovoljstvo školom u mnogim zemljama i sinergija između učenja i pozitivnih emocija. Veći broj istraživanja ukazuje na to da su programi pozitivne psihologije u školi djelotvorni u razvijanju pozitivnih osobina i povećanju dobrobiti, ali pouzdanost je tih rezultata još uvijek upitna. U ovom radu prikazuje se model pozitivnog obrazovanja kao jedno od mogućih područja budućih istraživanja. To je okvir za primjenu pozitivnog obrazovanja na razini škole usmjeren na šest područja dobrobiti uključujući pozitivne emocije, pozitivnu uključenost, pozitivna postignuća, pozitivnu svrhu, pozitivne odnose i pozitivno zdravlje, s naglaskom na osobne snage. Ključne riječi: dobrobit; pozitivno obrazovanje; pozitivna psihologija; sreća; škola
Self-Regulation, Emotion Understanding and Aggressive Behaviour in Preschool Boys / Samokontrola, razumijevanje emocija i agresivno ponašanje dječaka predškolske dobi
Authors: Brajša-Žganec Andreja , Hanzec Ivana 
Published: April 2015

AbstractPrevious research has shown that children with greater self-regulation exhibit less aggressive behaviour in their everyday interactions with peers. Boys are usually more aggressive than girls, have lower self-regulation and understand primary emotions less. However, those who understand emotions better behave more prosocially. Therefore, the aim of the present study was to examine the relationship of self-regulation and emotion understanding with regard to aggressive behaviour in preschool boys. The participants in this study included 241 boys aged 3 to 7, their parents (both mothers and fathers) and preschool teachers. Self-regulation was measured by parental estimations of inhibitory control and attentional focusing. Aggressive behaviour was measured by teachers' estimations, while emotion understanding was assessed in individual interviews with the boys. The results showed that the boys who recognized and described primary emotions better and had high self-regulation showed less aggressive behaviour, while those who understood emotions less and had low self-regulation behaved more aggressively. The results were discussed in the light of importance of strengthening self-regulation and emotion understanding in preschool boys as a way of developing their social and emotional competence. Key words: aggressive behaviour; emotion understanding; preschool boys; self-regulation --- SažetakDosadašnja istraživanja pokazala su da djeca koja imaju bolju samokontrolu manifestiraju manje agresivnog ponašanja u svakodnevnim vršnjačkim interakcijama. Dječaci su agresivniji od djevojčica u predškolsko doba, imaju nižu samokontrolu i niže razumijevanje primarnih emocija. Međutim, oni koji bolje razumiju emocije, ponašaju se više prosocijalno. Cilj istraživanja bio je stoga provjeriti povezanost samokontrole i razumijevanja emocija s agresivnim ponašanjem dječaka predškolske dobi. U istraživanju su sudjelovali 241 dječak u dobi od 3 do 7 godina, njihovi roditelji (i majka i otac) i odgojiteljice. Samokontrola je mjerena roditeljskim procjenama inhibitorne kontrole i fokusa pažnje. Agresivno ponašanje mjereno je odgojiteljskim procjenama, a razumijevanje emocija pojedinačnim intervjuima s dječacima. Rezultati su pokazali da najmanje agresivnog ponašanja manifestiraju dječaci koji bolje prepoznaju i opisuju primarne emocije te imaju visoku samokontrolu, a najviše agresivnog ponašanja oni koji imaju lošije razumijevanje emocija i nisku samokontrolu. Rezultati su razmatrani u smjeru važnosti jačanja samokontrole i razumijevanja emocija u predškolsko doba za razvoj socijalne i emocionalne kompetencije dječaka.Ključne riječi: agresivno ponašanje; dječaci; predškolsko doba; razumijevanje emocija; samokontrola
New records of Merriam’s Shrew (Sorex merriami) from western North Dakota
Authors: Shaughnessy Jr. Michael J. , Woodman Neal 
Published: April 2015

Despite having a broad geographic distribution, Merriam’s Shrew (Sorex merriami Dobson 1890) is known from a relatively few, widely-scattered localities. In North Dakota, the species was known from only a single poorly-preserved specimen collected in 1913 near Medora. We recently collected two new specimens of Merriam’s Shrew from Billings and McKenzie counties in the western quarter of the state. These specimens confirm the presence of S. merriami in North Dakota and better define the northeastern edge of the species’ distribution.
A construção da identidade docente na educação a distância a partir do uso de tecnologias para a criação de vídeos
Authors: Piovesan Angelica de Fatima , Borges Fabricia Teixeira 
Published: April 2015

A combinação, educação e tecnologia nos possibilita investigar sobre a identidade docente. A educação a distância, mais especificamente, nos faz refletir sobre as possibilidades de usar a arte e a estética na construção dialógica docente-aluno. Para a produção deste artigo, utilizamos uma parte dos resultados obtidos na realização de um estudo de caso com um professor da educação presencial e a distância, no qual enfocamos, em um dos aspectos encontrados nas entrevistas, o que se refere à produção de vídeos, videopoemas e podcasts para a educação a distância e que contribuem para a construção da identidade do professor. Convidamos para participar desta pesquisa, um docente que atua na educação a distância, utilizando as tecnologias para a produção desses materiais de aula. Acreditamos que este professor tem como uma das suas características identitárias, a criação de personagens para atuar nos vídeos, podcasts, videopoemas ou mesmo nas vídeo-aulas, e que a sua atuação diante das telas é semelhante à de um ator nos cinemas ou no teatro. Mudando a forma de trabalhar do professor e possibilitando refletir sobre sua atuação como uma nova perspectiva de ser professor, é possível criar outra forma de pensar esse professor como personagem da EAD. Entendemos que o personagem pode ser criado em diferentes situações da vida cotidiana e pode ser visto como uma das identidades assumidas em determinados momentos e circunstâncias por cada pessoa.
Formação inicial de professor e prática reflexiva: um estudo no contexto das teorias motivacionais contemporâneas
Authors: Nascimento Marilene Batista da Cruz , Santos Bettina Steren dos , Guedes Josevânia Teixeira 
Published: April 2015

Esta pesquisa tem como objetivo discutir as inter-relações entre as teorias contemporâneas motivacionais no contexto da formação inicial de professores, visando compreender os significados e as peculiaridades desse cenário. Trata-se de um estudo teórico, de cunho bibliográfico, que evidencia as contribuições dos processos motivacionais para a formação docente. A motivação retrata um processo que antecede a ação humana, de forma intrínseca e extrínseca, e possibilita inferir que o saber docente não se reduz, exclusiva ou principalmente, a processos mentais, cujo suporte é a atividade cognitiva dos indivíduos, mas é também um saber social que se manifesta nas relações complexas entre docentes e estudantes. Por fim, concluiu-se que há uma relação intrínseca entre a ciência pedagógica, a prática reflexiva e a motivação como instrumento para uma formação diferente da que temos atualmente. Realidade essa que justifica a presença das teorias motivacionais na formação básica dos professores.
“A educação dos filhos”: pequenas porções de pedagogia para os pais pelo Monsenhor Álvaro Negromonte
Authors: Orlando Evelyn de Almeida 
Published: April 2015

Este artigo apresenta o discurso da Igreja direcionado às famílias sobre a educação dos filhos nos anos de 1950, a partir da voz de um dos seus representantes, o Monsenhor Álvaro Negromonte. Compreendido como parte de sua Biblioteca Pedagógica o manual A Educação dos Filhos faz parte de uma trilogia endereçada às famílias e se constitui na principal fonte deste trabalho. Corresponde ao segundo livro da trilogia e se constitui como uma espécie de Tratado Pedagógico cujo objetivo era orientar os pais na tarefa da educar os seus filhos. A análise do manual teve como âncora os conceitos de Bibliotecas Pedagógicas de Chartier (1994) e Sgarbi (2001) e Tratados pedagógicos tal como propõe pensar Carvalho (2001; 2006). Assim, este trabalho analisa um conjunto de saberes e práticas orientados pela Igreja Católica no sentido de formar as famílias a partir de impressos produzidos com finalidade pedagógica específica voltada para a educação dos filhos.
One Valley, Three Hands: The Bilateral Negotiations of the Deatnu Agreement and Its Impact on Sami People’s Rights
Authors: Selfors Áike Niillas Peder 
Published: April 2015

The salmon stocks of the Deatnu River, in the core area of Sápmi, the traditional lands of the Sami people, have been designated as critically endangered. In November 2011, Norway and Finland agreed to renegotiate the agreement that regulates salmon fishing in the Deatnu River. This article explores the safeguards under international human rights law that are available to the Sami people in the Deatnu Valley in connection with this renegotiation process. Since the Sami people are recognized as an indigenous people in both countries, the negotiations touch upon several core issues of indigenous peoples’ rights, amongst these: the principle of self-determination, the principle of non-discrimination, and indigenous issues related to international border regulations. The article shows that the ongoing negotiations’ structure and preparations, to all appearances, have violated the rights of the Sami people. Consequently, risking a dissemination of further violations of Sami people’s rights—both, in regards to the negotiation process, and in what may be the new Deatnu Agreement.Keywords: Deatnu; Finland; indigenous peoples; international border areas; international human rights; international negotiations; Norway; Sami; salmon(Published: March 2015)Citation: Á. N. Peder Selfors. “One Valley, Three Hands: The Bilateral Negotiations of the Deatnu Agreement and Its Impact on Sami People’s Rights.” Arctic Review on Law and Politics, Vol. 6, No. 1, 2015, pp. 52–73. http://dx.doi.org/10.3402/arctic.v6.59