bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Selective C4—F Bond Cleavage of Pentafluorobenzene: Synthesis of N‐Tetrafluoroarylated Heterocyclic Compounds.
Authors: Liu Cuibo , Wang Huan , Xing Xing , Xu You , Ma Jun‐An , Zhang Bin 
Published: December 2013

AbstractAromatic nucleophilic substitution of pentafluorobenzenes with a variety of N‐heterocycles offers a convenient synthesis of N‐tetrafluoroarylated derivatives.
ChemInform Abstract: Gold‐Catalyzed Cyclization of 1‐(Indol‐3‐yl)‐3‐alkyn‐1‐ols: Facile Synthesis of Diversified Carbazoles.
Authors: Zhang Zhen , Tang Xiangying , Xu Qin , Shi Min 
Published: December 2013

AbstractThe carbazoles are obtained either through 1,2‐alkyl migration of the metal carbene intermediates or a Wagner‐Meerwein‐type 1,2‐alkyl shift or through ring‐opening of the cyclopropyl group by nucleophilic attack of water or an alcohol.
ChemInform Abstract: Palladium‐Catalyzed Skeletal Rearrangement of Spirotricyclic Olefins: A Facile One‐Pot Strategy for the Synthesis of a Novel Motif with Cyclopentene Fused to Benzofuran and Pyrazolidine.
Authors: Prakash Praveen , Jijy Eliyan , Preethanuj Preethalayam , Pihko Petri M. , Chand Sarngadharan Sarath , Radhakrishnan Kokkuvayil V. 
Published: December 2013

AbstractThe first utilization of acyclic cyclopropane bearing spirocyclic olefines for the generation of stereospecific complex fused ring systems with an achiral catalyst is reported.
ChemInform Abstract: Sulphamic Acid‐Functionalized Magnetic Fe3O4 Nanoparticles as Recyclable Catalyst for Synthesis of Imidazoles under Microwave Irradiation.
Authors: Safari Javad , Zarnegar Zohre 
Published: December 2013

AbstractA three‐component, one‐pot synthesis of 2,4,5‐trisubstituted imidazoles by condensation of 1,2‐diketones, aromatic aldehydes, and ammonium acetate is developed.
ChemInform Abstract: Novel Pyrazoline Amidoxime and Their 1,2,4‐Oxadiazole Analogues: Synthesis and Pharmacological Screening.
Authors: Ningaiah Srikantamurthy , Bhadraiah Umesha K. , Keshavamurthy Shubakara , Javarasetty Chethan 
Published: December 2013

AbstractA series of pyrazoline amidoxime and pyrazolyl‐1,2,4‐oxadiazole derivatives are synthesized and screened for their in vitro antioxidant, antimicrobial and antiinflammatory activities.
ChemInform Abstract: Gold(III) Chloride‐Catalyzed 6‐endo‐trig Oxa‐Michael Addition Reactions for Diastereoselective Synthesis of Fused Tetrahydropyranones.
Authors: Ciesielski Jennifer , Leboeuf David , Stern Harry A. , Frontier Alison J. 
Published: December 2013

AbstractThe AuCl3‐catalyzed 6‐endo‐trig oxa‐Michael addition of cyclic β‐iodoallenoates is developed to give a diverse range of polycyclic tetrahydropyranones.
ChemInform Abstract: CuO—CeO2 Nanocomposite: A Highly Efficient Recyclable Catalyst for the Multicomponent Synthesis of 4H‐Benzo[b]pyran Derivatives.
Authors: Albadi Jalal , Mansournezhad Azam , Derakhshandeh Zahra 
Published: December 2013

AbstractAn efficient preparation of pyrano[2,3‐c]pyrazoles, erroneously named benzo[b]pyrans, is presented.
ChemInform Abstract: A New Quinoline‐Based Acylhydrazone for Highly Selective Fluorescence Recognition of Cu(II) and Sulfide in Aqueous Solution.
Authors: Tang Lijun , Zhou Pei , Qi Zhikai , Huang Zhenlong , Zhao Jia , Cai Mingjun 
Published: December 2013

AbstractThe title fluorescent compound (III) shows high selectivity to Cu2+ (“ON‐OFF” behavior) and the generated (III)‐Cu2+ complex exhibits excellent selectivity to sulfide ions (“OFF‐ON” behavior).
ChemInform Abstract: Synthesis and Bioevaluation of Novel 4‐Aminoquinoline‐tetrazole Derivatives as Potent Antimalarial Agents.
Authors: Chauhan Prem M. S. , et al. et al. 
Published: December 2013

AbstractThe title compounds are screened for their antimalarial activities against both chloroquine‐sensitive (3D7) and chloroquine‐resistant (K1) strains of Plasmodium falciparum and for their cytotoxicity against VERO cell lines.
ChemInform Abstract: Rhodium‐Catalyzed Oxidative Coupling of Aryl Hydrazones with Internal Alkynes: Efficient Synthesis of Multisubstituted Isoquinolines.
Authors: Liu Wenting , Hong Xiaohu , Xu Bin 
Published: December 2013

AbstractThe title reaction proceeds through a tandem C—C/C—N bond forming process and a N—N bond cleavage.
ChemInform Abstract: Multicomponent Synthesis of Antibacterial Dihydropyridin and Dihydropyran Embelin Derivatives.
Authors: Pena Rosalyn , Jimenez‐Alonso Sandra , Feresin Gabriela , Tapia Alejandro , Mendez‐Alvarez Sebastian , Machin Felix , Ravelo Angel G. , Estevez‐Braun Ana 
Published: December 2013

AbstractCoupling of embelin with aldehydes and the primary enaminones (III) provides a new, straightforward one‐pot approach to dihydropyridine derivatives of type (IV).
ChemInform Abstract: Synthesis and Preliminary Cytotoxicity Evaluation of New Diarylamides and Diarylureas Possessing 2,3‐Dihydropyrrolo[3,2‐b]quinoline Scaffold.
Authors: Kim Hyun‐Jin , El‐Gamal Mohammed I. , Lee Yong Sup , Oh Chang‐Hyun 
Published: December 2013

AbstractA series of the title compounds is synthesized and tested for the activity against several human cancer lines.
ChemInform Abstract: DABCO Catalyzed Highly Regioselective Synthesis of Fused Imidazo‐Heterocycles in Aqueous Medium.
Authors: Bangade Vikas M. , Reddy B. Chennakesava , Thakur Pramod B. , Babu B. Madhu , Meshram H. M. 
Published: December 2013

AbstractDABCO is demonstrated to be an efficient catalyst for the condensation of 2‐aminopyridines with phenacyl bromides to give imidazo[1,2‐a]pyridines in good yields.
ChemInform Abstract: Selective Addition of Amines to 5‐Trifluoromethyl‐2,4‐dichloropyrimidine Induced by Lewis Acids.
Authors: Richter Daniel T. , Kath John C. , Luzzio Michael J. , Keene Nandell , Berliner Martin A. , Wessel Matthew D. 
Published: December 2013

AbstractUsually the reaction of 2,4‐dichloro‐5‐trifluoromethylpyrimidine with amines results in the formation of a 1:1 mixture of two isomers.
ChemInform Abstract: Synthesis of 6,7‐Dichloropyrido[1,2‐a]benzimidazole‐8,9‐dione and Its Analogues and Their Reactions with Nucleophiles.
Authors: Batenko Nelli , Belyakov Sergey , Kiselovs Glebs , Valters Raimonds 
Published: December 2013

AbstractIt is demonstrated that chloranil reacts with 2‐aminoazines or analogous diazines to give o‐quinone derivatives.
ChemInform Abstract: Sc(OTf)3 Promoted Multicomponent Synthesis of Fluorescent Imidazo[1,2‐c]pyrazolo[3,4‐d]pyrimidine.
Authors: Agrebi Asma , Allouche Fatma , Chabchoub Fakher , El‐Kaim Laurent , Alves Sergio , Baleizao Carlos , Farinha Jose Paulo 
Published: December 2013

AbstractTwo simple protocols using Sc(OTf)3 as the catalyst are presented for the synthesis of the title‐compounds via three component condensation of pyrazolopyrimidines, aldehydes, and isocyanides.
ChemInform Abstract: Four Mechanisms in the Reactions of 3‐Aminopyrrole with 1,3,5‐Triazines: Inverse Electron Demand Diels—Alder Cycloadditions vs SNAr Reactions via Uncatalyzed and Acid‐Catalyzed Pathways.
Authors: De Rosa Michael , Arnold David , Hartline Douglas 
Published: December 2013

AbstractReaction conditions and substituents on the 1,3,5‐triazine substrate influence the product outcome of the title reactions.
ChemInform Abstract: Rhodium‐Catalyzed Highly Enantioselective Addition of Arylboronic Acids to Cyclic Aldimines: Practical Asymmetric Synthesis of Cyclic Sulfamidates.
Authors: Wang Hui , Xu Ming‐Hua 
Published: December 2013

AbstractThe asymmetric arylation of cyclic N‐sulfonyl aldimines (I) with aryl boronic acids (II) in the presence of a rhodium/N‐alkenylsulfinamide catalyst system provides 4‐aryl‐1,2,3‐benzoxathiazines (III) in excellent yields and enantioselectivities.
ChemInform Abstract: Regioselective Silylation of Pyranosides Using a Boronic Acid/Lewis Base Co‐catalyst System.
Authors: Lee Doris , Taylor Mark S. 
Published: December 2013

AbstractThe combination of a boronic acid and a Lewis base, both employed in substoichiometric amounts, allows for the regioselective silylation of cis‐diol groups in alkylpyranoside substrates.
ChemInform Abstract: Tetrafluorobromates for Urban Mining of Noble Metals: A Case Study on Iridium Metal.
Authors: Ivlev Sergey , Woidy Patrick , Kraus Florian , Gerin Ivan , Ostvald Roman 
Published: December 2013

AbstractThe products of the solid state reaction of Ir metal with MBrF4 (M: K, Rb, Cs) and Ba(BrF4)2 in nickel ampoules at 400 °C for 150 min are characterized by powder XRD and simultaneous thermogravimetric and differential thermal analyses.
The emerging technique of electromagnetic navigation bronchoscopy‐guided fine‐needle aspiration of peripheral lung lesions: Promising results in 50 lesions
Authors: Loo Florence L. , Halligan Allison M. , Port Jeffrey L. , Hoda Rana S. 
Published: December 2013

BACKGROUNDLiterature on the diagnostic yield of electromagnetic navigation bronchoscopy (ENB) with ENB‐guided fine‐needle aspiration (ENB‐FNA) in peripheral lung lesions (PLLs) that measure ≤ 2 cm is scarce. Data on the diagnostic yield of ENB‐FNA for PLLs when performed in conjunction with positron emission tomography‐computed tomography (PET‐CT), rapid on‐site evaluation (ROSE), ENB‐guided bronchial brushing (ENB‐BB), and ENB‐guided transbronchial biopsy (ENB‐TBx) is also limited. In this study, the authors evaluated their experience with ENB‐FNA performed in conjunction with all 4 modalities: PET‐CT, ROSE, ENB‐BB, and ENB‐TBx.METHODSENB‐FNA and other tests over a 2‐year‐period (from July 2011 to July 2013) were retrospectively reviewed.RESULTSThere were 50 PLLs from 40 patients, and the mean lesion size (available for 45 PLLs) was 2.6 cm: these included 24 PLLs that measured ≤ 2 cm and 21 PLLs that measured > 2.0 cm. The ENB‐FNA diagnosis was malignant in 17 lesions, atypical in 1 lesion, benign in 31 lesions, and nondiagnostic in 1 lesion. On the basis of lesion size, the diagnostic yield of PLLs was 87% in lesions ≤ 2 cm and 100% in lesions > 2.0 cm (P = 0.5; not significant). Follow‐up available in 49 of 50 PLLs from 39 patients had an overall diagnostic yield of 94% for ENB‐FNA. The diagnostic yield of PET‐CT (available in 31 of 50 PLLs) and of ENB‐BB and ENB‐TBx (available in 40 of 50 PLLs) in conjunction with ENB‐FNA was 61% and 95%, respectively. ROSE was performed in 46 of 50 PLLs: the overall sensitivity of ROSE and ENB‐FNA was 85% and 89.4%, respectively, and their specificity was 96.5% and 100%, respectively. There were no procedure‐related complications.CONCLUSIONSThe high overall diagnostic yield of 94% and fewer complications make ENB‐FNA a useful modality for the assessment of PLLs. In this study, ROSE was useful, whereas PET‐CT, ENB‐BB, and ENB‐TBx were not useful in the evaluation of PLLs. Cancer (Cancer Cytopathol) 2014;122:191–199. © 2013 American Cancer Society.
An efficient framework for parallel and continuous frequent item monitoring
Authors: Zhang Yu , Sun Yue , Zhang Jianzhong , Xu Jingdong , Wu Ying 
Published: December 2013

SUMMARYIn high‐speed network monitoring, the ever‐growing traffic calls for a high‐performance solution for the computation of frequent items. The increasing number of cores in the current commodity multi‐core processors opens up new opportunities in parallelization. In this paper, we present a novel precision integrated framework (PRIF) that exploits the great parallel capability of multi‐cores to speed up the famous frequent algorithm. PRIF equally distributes the input data stream into sub‐threads that use the optimized weighted frequent algorithm to track local frequent items. The items with frequency increments exceeding a pre‐defined threshold are sent to a merging thread which is able to return the global continuous ε‐deficient frequent items. The theoretical correctness and complexity analyses are presented. Experiments with real and synthetic traces confirm the theoretical analyses and demonstrate the excellent performance as well as the effects of parameters and data skewness. The results show that PRIF is able to provide continuous frequent items and near‐linear speedup at the cost of greater memory use. Copyright © 2013 John Wiley & Sons, Ltd.
Hierarchical Copper‐Decorated Nickel Nanocatalysts Supported on La2O3 for Low‐Temperature Steam Reforming of Ethanol
Authors: Liu Jyong‐Yue , Su Wei‐Nien , Rick John , Yang Sheng‐Chiang , Cheng Ju‐Hsiang , Pan Chun‐Jern , Lee Jyh‐Fu , Hwang Bing‐Joe 
Published: December 2013

AbstractCopper/nickel nanocatalysts with a unique morphology were prepared by thermal reduction of a perovskite LaNixCu1−xO3 precursor (x=1, 0.9, and 0.7). During thermal reduction, copper was first reduced and reacted with lanthanum to form metastable Cu5La and Cu13La. When the thermal reduction temperature was increased, the perovskite decomposed to Ni and La2O3, CuLa alloys disappeared, and Cu deposits on Ni nanoparticles were generated, thereby forming Cu/Ni nanocatalysts with hierarchical structures. Nanosized nickel, decorated with copper and supported on La2O3, could be produced at 520–550 °C. The steam reforming of ethanol was used as a model reaction to demonstrate the catalytic capability of the materials formed. The hierarchical structure of the Cu/Ni/La2O3 catalysts confers synergetic effects that greatly favor the dehydrogenation of ethanol and which break the CC bond to produce a higher yield of hydrogen at a low reaction temperature, whereas La2O3 provides the required stability during the reaction. The reaction at 290 °C achieved almost 100 % conversion with a hydrogen yield reaching 2.21 molH2 mol−1EtOH thus indicating that this special structural feature can achieve high activity for the SRE at low temperatures. The proposed synthesis of nanocatalysts appears to be a good way to generate oxide‐supported hierarchically structured nanoparticles that can also be applied to other reactions catalyzed by a heterogeneous metal oxide system.
Compressive image acquisition in modern CMOS IC design
Authors: Katic Nikola , Kamal Mahdad Hosseini , Schmid Alexandre , Vandergheynst Pierre , Leblebici Yusuf 
Published: December 2013

SummaryCompressive sampling (CS) offers bandwidth, power, and memory size reduction compared to conventional (Nyquist) sampling. These are very attractive features for the design of modern complementary metal‐oxide semiconductor (CMOS) image sensors, cameras, and camera systems. However, very few integrated circuit (IC) designs based on CS exist because of the missing link between the well‐established CS theory on one side, and the practical aspects/effects related to physical IC design on the other side. This paper focuses on the application of compressed image acquisition in CMOS image sensor integrated circuit design. A new CS scheme is proposed, which is suited for hardware implementation in CMOS IC design. All the main physical non‐idealities are explained and carefully modeled. Their influences on the acquired image quality are analyzed in the general case and quantified for the case of the proposed CS scheme. The presented methodology can also be used for different CS schemes and as a general guideline in future CS based CMOS image sensor designs. Copyright © 2013 John Wiley & Sons, Ltd.
Shared patterns of species turnover between seaweeds and seed plants break down at increasing distances from the sea
Authors: Gurgel Carlos F. D. , Wernberg Thomas , Thomsen Mads S. , Russell Bayden D. , Adam Paul , Waters Jonathan M. , Connell Sean D. 
Published: December 2013

AbstractWe tested for correlations in the degree of spatial similarity between algal and terrestrial plants communities along 5500 km of temperate Australian coastline and whether the strength of correlation weakens with increasing distance from the coast. We identified strong correlations between macroalgal and terrestrial plant communities within the first 100 km from shore, where the strength of these marine–terrestrial correlations indeed weakens with increasing distance inland. As such, our results suggest that marine‐driven community homogenization processes decompose with increasing distance from the shore toward inland. We speculate that the proximity to the marine environment produces lower levels of community turnover on land, and this effect decreases progressively farther inland. Our analysis suggests underlying ecological and evolutionary processes that give rise to continental‐scale biogeographic influence from sea to land.
Copper(I) and Silver(I) Complexes of 1,3‐Diphosphacyclobutadiene Sandwich Anions: Synthesis, Crystal Structures, and Solution and Solid‐State NMR Spectroscopic Characterization
Authors: Malberg Jennifer , Wiegand Thomas , Eckert Hellmut , Bodensteiner Michael , Wolf Robert 
Published: December 2013

Abstract1,3‐Diphosphacyclobutadiene complexes have previously been employed as metalloligands to a few transition metals such as tungsten, cobalt, rhodium, platinum, and gold. Here, we describe the synthesis and the structural and spectroscopic characterization of novel copper(I) and silver(I) complexes with the sandwich anions [Co(η4‐P2C2R2)2]– (R = tBu or tPent). Reactions of [K(thf)3{Co(P2C2tPent2)2}] and [K(thf)2{Co(P2C2tBu2)2}] with CuCl(PPh3)/PPh3 yielded mononuclear copper(I) complexes [Cu{Co(P2C2R2)2}(PPh3)2] [R = tPent (1), tBu (2)]. The salt [Cu(PMe3)4][Co(P2C2tPent2)2] (3), which consists of a [Cu(PMe3)4]+ cation and a noncoordinated [Co(P2C2tPent2)2]– anion, was obtained when [K(thf)3{Co(P2C2tPent2)2}] was treated with CuCl(PPh3) in the presence of an excess amount of PMe3. Salt metathesis of [K(thf)3{Co(P2C2tPent2)2}] with AgCl and AgSbF6 in the presence of PMe3 afforded novel silver(I) complexes [Ag{Co(P2C2tPent2)2}(PMe3)3] (4), [Ag{Co(P2C2tPent2)2}(PMe3)2] (5), and [Ag2{Co(P2C2tPent2)2}(PMe3)5]SbF6 (6). The molecular structures of 1, 2, 5, and 6 were determined by X‐ray crystallography. The solution behavior of 1–6 was analyzed by variable‐temperature 1H, 31P{1H}, and 13C{1H} NMR spectroscopy in [D8]THF. 31P solution and solid‐state NMR spectra, aided by two‐dimensional dipolar and/or J‐based correlation spectroscopy, support the proposed structures and allowed the compositions of polycrystalline precipitated products to be analyzed. Furthermore, characteristic 31P chemical shifts and indirect spin–spin coupling constants offer a clear distinction between different bonding patterns realized in this class of compounds.
Seed meals as source of fractions with different effects on pancreatic lipase activity
Authors: Shene Carolina , Spuler María José , Acevedo Francisca , Rubilar Mónica 
Published: December 2013

The effect of different fractions (lipids, solids soluble in aqueous ethanol (ES), soluble protein (SP), and the residue after the extractions) of yellow lupin (Lupinus luteus), linseed (Linum usitatissimum), and soybean (Glycine max) meals on in vitro porcine pancreatic lipase (PPL) activity was determined. PPL activity against emulsions prepared with the different SPs unprocessed or denaturated by heat, digested with pepsin and homogenized at high pressure was also evaluated. In general, the lipids, ES, and the residue fractions increased PPL activity (8.4–80.0%) whereas it was reduced by the SPs of lupin (25.3%) and linseed (30.8%) at a low concentration. Residual activity after incubating the enzyme with the SPs was found between 13 and 46% depending on the source and the incubating period. The rate at which PPL hydrolyzed emulsions in which lipid droplets were covered first by gum Arabic and then with the protein was influenced by the treatment of SP; less free fatty acids were released from emulsions containing the denaturated and digested SPs. PPL activity against emulsions that contained the homogenized SPs was higher (108–174%) than the activity against emulsions that contained the untreated SP.Practical applications: Lupin, linseed, and soybean meals contain various fractions that increase the activity of PPL; however the soluble proteins of lupin and linseed exert the opposite effect at low concentrations with the subsequent reduction of lipolysis products. Besides emulsions prepared with denaturated or protease digested seed proteins are hydrolyzed at low rates by PPL. This property of the seed proteins could find use in the developing of foods for weight control for instance plant‐based milks and creams. On the other hand, high pressure homogenization could be used as a treatment for decrease the negative effect of seed proteins on the activity of PPL.
Pyrene–Azobenzene Dyads and Their Photochemistry
Authors: Nachtigall Olaf , Lomoth Reiner , Dahlstrand Christian , Lundstedt Anna , Gogoll Adolf , Webb Matthew J. , Grennberg Helena 
Published: December 2013

AbstractThe facile synthesis of three new folding azobenzene‐pyrene systems 1–3, connected together by a serendipitously obtained and unpredicted ester linkage, is reported. Additional characterization of the photochemistry of these systems revealed variations in azobenzene photoisomerization (trans‐cis and cis‐trans) and quenching of pyrene fluorescence, as a result of intra‐excitation energy transfer from the pyrene chromophore to an azobenzene. Through the use of aryl substituent electronic effects to tune the absorption properties of the azobenzene relative to the pyrene, we show that efficient photo‐switching can be achieved when the trans‐azobenzene absorbance band is well separated from that of the pyrene (compound 1), whereas overlap of the corresponding absorbance bands in the cases of 2 and 3 significantly compromises trans‐cis isomerization by enhancing cis‐trans interconversion.
Functionalized Phospholipid Molecular Platform: Use for Production of Cationic Fluorescent Lipids
Authors: Berchel Mathieu , Haelters Jean‐Pierre , Afonso Damien , Maroto Alicia , Deschamps Laure , Giamarchi Philippe , Jaffrès Paul‐Alain 
Published: December 2013

AbstractFluorescent amphiphilic phospholipids (neutral or cationic) in which fluorescent probes are contained in the lipid domain were synthesized via phosphoramide intermediates possessing two distinct lipid chains. One of these lipid chains is ω‐functionalized with an azide or alkyne group, and this is subsequently used to introduce a fluorescent probe by Huisgen cycloaddition. Five different fluorescent probes (naphthalimide, dansyl, fluoresceine, Nile red, and coumarin) were considered in this study. These neutral and cationic fluorescent lipids were included at a 1 % molar ratio with a selected cationic lipid (KLN47) to produce liposomal solutions that were characterized by dynamic light scattering and zeta potential measurements.
Towards Stapling of Helical Alleno‐Acetylene Oligomers – Synthesis of an Enantiopure Bis(ethynylvinylidene)‐Substituted Cyclohexadeca‐1,3,9,11‐tetrayne
Authors: Müller I.‐E. Sophie , Bernet Bruno , Dengiz Cagatay , Schweizer W. Bernd , Diederich François 
Published: December 2013

AbstractWe are interested in developing strategies to bridge (“staple”) enantiomerically pure acyclic alleno‐acetylenic oligomers to enhance their conformational preferences for helical secondary structures, which are postulated to be at the origin of their exceptional chiroptical properties. We found that ring‐closing metathesis (RCM), which has been used for the stapling of peptide helices, failed with an acyclic alleno‐acetylene dimer decorated with lateral olefinic side chains. Instead, enyne RCM to an enantiomerically pure dienyne occurred. We switched to the introduction of diacetylene‐containing bridges and report here the 15‐step synthesis of a moderately strained, enantiomerically pure cyclohexa‐1,3,9,11‐tetrayne with an oxidative acetylenic coupling in the key step. The chiroptical properties of the new compounds are discussed.
Purification‐Free, Small‐Scale Synthesis of Isothiocyanates by Reagentless Fragmentation of Polymer‐Supported 1,4,2‐Oxathiazoles
Authors: Burkett Brendan A. , Fu Pincheng , Hewitt Russell J. , Ng Su Ling , Toh Joel D. W. 
Published: December 2013

AbstractThe synthesis of isothiocyanates (ITCs) by employing polymer‐supported 1,4,2‐oxathiazoles is described. The ITCs are obtained in moderate yields and high purity through a reagentless, thermal fragmentation of polymer‐supported 1,4,2‐oxathiazoles that are obtained by trapping nitrile oxides with polymer‐supported thiocarbonates.