bluuebunny/crossref_metadata_2025_split huggingface dataset:
Trends of air pollution variations during pre-Diwali, Diwali and post-Diwali periods and health risk assessment using HAQI in India
Authors: Ghosh Buddhadev , Barman Harish Chandra , Padhy Pratap Kumar 
Published: July 2024

AbstractDuring 2019 to 2022, a comprehensive study was conducted across 71 stations spanning over 15 states in India to investigate air quality variations during the pre-Diwali, Diwali, and post-Diwali periods. The investigation, centred on the extensive use of firecrackers during festive times, revealed a short-term deterioration in air quality with long-lasting impacts. PM2.5 and PM10 levels were found to significantly increase during Diwali and the post-Diwali period compared to the pre-Diwali period. The levels of PM2.5 and PM10 experience respective increases of 44.66% and 11.03%, 29.12% and 05.41%, 52.63% and 23.38%, and 39.65% and 17.61% during Diwali period from 2019 to 2022, where 68.84% and 34.32%, 44.42% and 29.42%, and 48.70% and 25.22% in 2019, 2021 and 2022 in post-Diwali period compared to the pre-Diwali. The Mann–Kendall and Sen's slope analyses reveal statistically significant positive trends (increasing) in both PM10 and PM2.5 levels during the Diwali festival period. Notably, the study introduced the Health Hazard-based Air Quality Index (HAQI), which demonstrated higher values than the National Ambient Air Quality Index (NAAQI). Unlike NAAQI, which considers individual pollutant sub-index values, and considered highest one of sub-index values in AQI analysis. HAQI provides a more comprehensive assessment of health risks associated with exposure to multiple pollutants effects. In 2022, AQI and HAQI values during pre-Diwali were 114 and 146.18, during Diwali were 173 and 332.18, and post-Diwali were 191 and 414.14, respectively. These findings underscore the elevated risk during Diwali and the post-Diwali period due to heightened pollution levels, emphasizing the need for public awareness and potential mitigation strategies. The study calls attention to the importance of considering cumulative health impacts and suggests the adoption of HAQI for more informative air quality assessments.
Clumped Isotope Signatures of Abiotic Methane: The Role of the Combinatorial Isotope Effect
Authors: Labidi Jabrane , McCollom Thomas M. , Giunta Thomas , Sherwood Lollar Barbara , Leavitt William D. , Young Edward D. 
Published: July 2024

AbstractMethane clumped isotope signatures of abiogenesis may be diagnostic of the origin of methane on Earth and other planetary bodies. We performed synthesis of abiogenic methane in hydrothermal conditions between 130 and 300°C and determined δ13C, δD, Δ13CH3D, and Δ12CH2D2. The experiments were performed by heating water in the presence of Fe0 powder and CO. The reduction of water on metallic iron led to the formation of H2. CO was reacted with both H2 and H2O, generating both CH4 and CO2. Methane δ13C values are isotopically depleted by ∼25‰ relative to the CO starting material. This is consistent with carbon isotopic equilibrium between methane, carbon monoxide and carbon dioxide in our experiments. In contrast, D/H ratios are inconsistent with equilibrium isotopic fractionation, as illustrated by δD values of methane fractionated by ∼500‰ relative to starting H2O. This suggests that under our experimental conditions, hydrogen additions to carbon may be governed by kinetics. Δ13CH3D values track experimental temperature, with values between +1.5‰ and +5.0‰ for most samples. In contrast, Δ12CH2D2 values are displaced from equilibrium. We find exclusively negative Δ12CH2D2 values, showing deficits down to 40‰ relative to thermodynamic equilibrium. We interpret the data as evidence for distinct, kinetically induced D/H pools contributing to methane assembly, that is, a combinatorial effect. The cumulative D/H fractionations associated with CO hydrogenation explain the direction and magnitude of Δ12CH2D2 values during abiotic methane formation. We suggest that near equilibrium Δ13CH3D with negative Δ12CH2D2 signatures will help identify methane formed abiotically in nature.
Structural Variation Along the Southern Hikurangi Subduction Zone, Aotearoa New Zealand, From Seismic Reflection and Retro‐Deformation Analysis
Authors: Stevens D. E. , McNeill L. C. , Henstock T. J. , Barnes P. M. , Crutchley G. , Bangs N. , Henrys S. , Van Avendonk H. J. A. 
Published: July 2024

AbstractThe southern Hikurangi subduction zone exhibits significant along‐strike variation in convergence rate and obliquity, sediment thickness and, uniquely, the increasing proximity of southern Hikurangi to, and impingement on, the incoming continental Chatham Rise, an ancient Gondwana accretionary complex. There are corresponding changes in the morphology and structure of the Hikurangi accretionary prism. We combine widely spaced multichannel seismic reflection profiles with high resolution bathymetry and previous interpretations to characterize the structure and the history of the accretionary prism since 2 Ma. The southern Hikurangi margin can be divided into three segments. A northeastern segment (A) characterized by a moderately wide (∼70 km), low taper (∼5°) prism recording uninhibited outward growth in the last ∼1 Myr. Deformation resolvable in seismic reflection data accounts for ∼20 % of plate convergence, comparable with the central Hikurangi margin further North. A central segment (B) characterized by a narrow (∼30 km), moderate taper (∼8°) prism, with earlier (∼2‐∼1 Ma) shortening than segment A. Outward prism growth ceased coincidentally with development of major strike‐slip faults in the prism interior, reduced margin‐normal convergence rate, and the onset of impingement on the incoming Chatham Rise to the south. A southwestern segment (C) marks the approximate southern termination of subduction but widens to ∼50 km due to rapid outward migration of the deformation front via fault reactivation within the now‐underthrusting corner of the Chatham Rise. Segment C exhibits minimal shortening as margin‐normal subduction velocity decreases and plate motion is increasingly taken up by interior thrusts and strike‐slip faults.
Interhemispheric Asymmetry in the Seasonal Ionospheric Outflow
Authors: Nowrouzi N. , Walsh B. M. 
Published: July 2024

AbstractA comprehensive statistical study is conducted on O+ and H+ outflows obtained from the TEAMS/FAST data during the 23rd solar cycle (1996–2007). The study investigates interhemispheric asymmetry in ionospheric outflows during local summer, winter, and equinox seasons. Data are classified into two distinct periods: the pre‐storm and geomagnetic storm phases. Numerous statistical asymmetries are identified. The findings indicate that the dayside cusp consistently demonstrates more outflow rates of O+ and H+ in the northern hemisphere than southern hemisphere during geomagnetic storms in all seasons as well as during the pre‐storm period in the summer season with the exception of H+ during summer storms. Conversely, the nightside O+ and H+ outflow rates are higher in the southern hemisphere during pre‐storm and storm periods in the summer season. Additionally, the dawnside and duskside outflow rates of O+ and H+ are predominantly stronger in the southern hemisphere.
Evidence of Dislocation Mixed Climb in Quartz From the Main Central and Moine Thrusts: An Electron Tomography Study
Authors: Weidner Timmo , Mussi Alexandre , Castelnau Olivier , Kronenberg Andreas , Law Richard , Cordier Patrick 
Published: July 2024

AbstractIn this study we apply electron tomography to characterize 3D dislocation microstructures in two quartz mylonite specimens from the Moine and Main Central Thrusts, both of which accommodated displacements by dislocation creep in the presence of water. Both specimens show dislocation activity with dislocation densities of the order of 3–4 × 1012 m−2 and evidence of recovery from the presence of subgrain boundaries. 〈a〉 slip occurs predominantly on pyramidal and prismatic planes (〈a〉 basal glide is not active). [c] Glide is not significant. On the other hand, we observe a very high level of activation of 〈c + a〉 glide on the , , (n = 1,2) and even planes. Approximately 60% of all dislocations show evidence of climb with a predominance of mixed climb, a deformation mechanism characterized by dislocations moving in a plane intermediate between the glide and the climb planes. This atypical mode of deformation demonstrates comparable glide and climb efficiency under natural deformation conditions. It promotes dislocation glide in planes not expected for the quartz structure, probably by inhibiting lattice friction. Our quantitative characterization of the microstructure enables us to assess the strain that dislocations can generate. We show that glide systems indicated by the observed dislocations are sufficient to accommodate any arbitrary 3D strain by themselves. Although historically dislocation glide has been regarded as being primarily responsible for producing strain, activation of climb can also directly contribute to the finite strain. On the basis of this characterization, we propose a numerical modeling approach for attempting to characterize the local stress state that gave rise to the observed microstructure.
Ozone Formation Sensitivity to Precursors and Lightning in the Tropical Troposphere Based on Airborne Observations
Authors: Nussbaumer Clara M. , Kohl Matthias , Pozzer Andrea , Tadic Ivan , Rohloff Roland , Marno Daniel , Harder Hartwig , Ziereis Helmut , Zahn Andreas , Obersteiner Florian , Hofzumahaus Andreas , Fuchs Hendrik , Künstler Christopher , Brune William H. , Ryerson Tom B. , Peischl Jeff , Thompson Chelsea R. , Bourgeois Ilann , Lelieveld Jos , Fischer Horst 
Published: July 2024

AbstractTropospheric ozone (O3) is an important greenhouse gas that is also hazardous to human health. The formation of O3 is sensitive to the levels of its precursors NOx (≡NO + NO2) and peroxy radicals, for example, generated by the oxidation of volatile organic compounds (VOCs). A better understanding of this sensitivity will show how changes in the levels of these trace gases could affect O3 levels today and in the future, and thus air quality and climate. In this study, we investigate O3 sensitivity in the tropical troposphere based on in situ observations of NO, HO2 and O3 from four research aircraft campaigns between 2015 and 2023. These are OMO (Oxidation Mechanism Observations), ATom (Atmospheric Tomography Mission), CAFE Africa (Chemistry of the Atmosphere Field Experiment in Africa) and CAFE Brazil, in combination with simulations using the EMAC atmospheric chemistry—climate model. We use the metric α(CH3O2) together with NO to investigate the O3 formation sensitivity. We show that O3 formation is generally NOx‐sensitive in the lower and middle tropical troposphere and is in a transition regime in the upper troposphere. By distinguishing observations impacted by lightning or not we show that NO from lightning is the most important driver of O3 sensitivity in the tropics. NOx‐sensitive chemistry predominates in regions without lightning impact, with α(CH3O2) ranging between 0.56 and 0.82 and observed average O3 levels between 35 and 55 ppbv. Areas affected by lightning exhibit strongly VOC‐sensitive O3 chemistry with α(CH3O2) of about 1 and average O3 levels between 55 and 80 ppbv.
Uncertainty Quantification of a Machine Learning Subgrid‐Scale Parameterization for Atmospheric Gravity Waves
Authors: Mansfield L. A. , Sheshadri A. 
Published: July 2024

AbstractSubgrid‐scale processes, such as atmospheric gravity waves (GWs), play a pivotal role in shaping the Earth's climate but cannot be explicitly resolved in climate models due to limitations on resolution. Instead, subgrid‐scale parameterizations are used to capture their effects. Recently, machine learning (ML) has emerged as a promising approach to learn parameterizations. In this study, we explore uncertainties associated with a ML parameterization for atmospheric GWs. Focusing on the uncertainties in the training process (parametric uncertainty), we use an ensemble of neural networks to emulate an existing GW parameterization. We estimate both offline uncertainties in raw NN output and online uncertainties in climate model output, after the neural networks are coupled. We find that online parametric uncertainty contributes a significant source of uncertainty in climate model output that must be considered when introducing NN parameterizations. This uncertainty quantification provides valuable insights into the reliability and robustness of ML‐based GW parameterizations, thus advancing our understanding of their potential applications in climate modeling.
Exploring associations between the Phthalate Environmental Reproductive Health Literacy (PERHL) scale & biomarkers of phthalate exposure: A pilot study
Authors: Tomsho Kathryn S. , Quinn Marlee R. , Preston Emma V. , Adamkiewicz Gary , James-Todd Tamarra 
Published: July 2024

Abstract
Background
Perinatal exposure to phthalates is associated with adverse health impacts for parents and children. The field of environmental health literacy seeks to measure how environmental health information is conceptualized and used to inform behaviors. We assessed whether scores on the validated Phthalate Environmental Reproductive Health Literacy (PERHL) scale were associated with biomarkers of phthalate exposure.

Methods
42 members of the Environmental Reproductive and Glucose Outcomes (ERGO) cohort completed the PERHL scale and provided spot urine samples. Phthalate summary measures for model outcomes were created by calculating molar sums of specific gravity-corrected metabolite concentrations representing exposure to parent phthalate, Di(2-ethylhexyl)phthalate (DEHP), personal care product (PCP)-associated phthalates, and parent butyl-phthalates. Linear regression models were used to estimate the associations of the PERHL scale scores with phthalate summary measures, controlling for educational attainment (college degree or higher vs. no college degree), age (years), and race and ethnicity (non-Hispanic White vs. non-White).

Results
Higher scores on the PERHL Scale and subscales were generally associated with lower ΣDEHP, Σbutyl, and ΣPCP metabolite concentrations. A one-point increase in the ‘Protective Behavior/Risk Control’ subscale score was significantly associated with a −30.3% (95% CI: −50.1, −2.6) decrease in ΣDEHP, and a −30.6% (95% CI: −51.5, −0.63) decrease in Σbutyl metabolite concentrations.
Investigation of sorptive interactions between volatile organic compounds and supramolecules at dynamic oscillation using bulk acoustic wave resonator virtual sensor arrays
Authors: Wang Zilun , Zhao Zeyu , Jin Suhan , Bian Feilong , Chang Ye , Duan Xuexin , Men Xiangdong , You Rui 
Published: July 2024

AbstractSupramolecules are considered as promising materials for volatile organic compounds (VOCs) sensing applications. The proper understanding of the sorption process taking place in host-guest interactions is critical in improving the pattern recognition of supramolecules-based sensing arrays. Here, we report a novel approach to investigate the dynamic host-guest recognition process by employing a bulk acoustic wave (BAW) resonator capable of producing multiple oscillation amplitudes and simultaneously recording multiple responses to VOCs. Self-assembled monolayers (SAMs) of β-cyclodextrin (β-CD) were modified on four BAW sensors to demonstrate the gas-surface interactions regarding oscillation amplitude and SAM length. Based on the method, a virtual sensor array (VSA) type electronic nose (e-nose) can be realized by pattern recognition of multiple responses at different oscillation amplitudes of a single sensor. VOCs analysis was realized respectively by using principal component analysis (PCA) for individual VOC identification and linear discriminant analysis (LDA) for VOCs mixtures classification.
Muscle Excitability Scale for the assessment of spastic reflexes in spinal cord injury: development and evaluation
Authors: Kriz Jiri , Nasincova Zuzana , Gallusova Veronika , Vyskocil Tomas , Gregor Martin , Slaby Krystof , Sediva Kristyna 
Published: July 2024

Abstract
Study design
A psychometric study.

Objectives
To introduce a novel simple tool designed to evaluate the intensity of the phasic (dynamic) component of spastic motor behavior in spinal cord injury (SCI) people and to assess its reliability and validity.

Setting
The study was developed in the Spinal Cord Unit at University Hospital Motol and Paraple Centre in Prague, Czech Republic.

Methods
The Muscle Excitability Scale (MES) is designed to rate muscle motor response to exteroceptive and proprioceptive stimuli. The impairment rating ranges from zero muscle/muscle group spasm or clonus to generalized spastic response. The selected 0 to 4 scale allows for comparing the MES results with those of the Modified Ashworth Scale (MAS). After long-term use and repeated revisions, a psychometric analysis was conducted. According to the algorithm, two physiotherapists examined 50 individuals in the chronic stage after SCI.

Results
The inter-rater reliability of MES for both legs showed κ = 0.52. The intra-rater reliability of MES for both legs showed κ = 0.50. The inter-rater reliability of simultaneously assessed MAS for both legs was higher, with κ = 0.69. The intra-rater reliability of MAS for both legs showed κ = 0.72. Spearman’s rank correlation coefficient between MES and spasm frequency of Penn Spasm Frequency Scale (PSFS) was low, while the correlation coefficient between MES and the severity part of PSFS was moderate.

Conclusions
The MES is a complementary tool for assessing the dynamic component of spastic motor behavior in SCI people. It allows a more comprehensive clinical characterization of spastic reflexes when used along with the MAS.
Dysregulation of tRNA methylation in cancer: Mechanisms and targeting therapeutic strategies
Authors: Yuan Wenbin , Zhang Rui , Lyu Hao , Xiao Shuai , Guo Dong , Zhang Qi , Ali Declan William , Michalak Marek , Chen Xing-Zhen , Zhou Cefan , Tang Jingfeng 
Published: July 2024

AbstracttRNA is the RNA type that undergoes the most modifications among known RNA, and in recent years, tRNA methylation has emerged as a crucial process in regulating gene translation. Dysregulation of tRNA abundance occurs in cancer cells, along with increased expression and activity of tRNA methyltransferases to raise the level of tRNA modification and stability. This leads to hijacking of translation and synthesis of multiple proteins associated with tumor proliferation, metastasis, invasion, autophagy, chemotherapy resistance, and metabolic reprogramming. In this review, we provide an overview of current research on tRNA methylation in cancer to clarify its involvement in human malignancies and establish a theoretical framework for future therapeutic interventions targeting tRNA methylation processes.
Imaging nanomagnetism and magnetic phase transitions in atomically thin CrSBr
Authors: Tschudin Märta A. , Broadway David A. , Siegwolf Patrick , Schrader Carolin , Telford Evan J. , Gross Boris , Cox Jordan , Dubois Adrien E. E. , Chica Daniel G. , Rama-Eiroa Ricardo , J. G. Santos Elton , Poggio Martino , Ziebel Michael E. , Dean Cory R. , Roy Xavier , Maletinsky Patrick 
Published: July 2024

AbstractSince their first observation in 2017, atomically thin van der Waals (vdW) magnets have attracted significant fundamental, and application-driven attention. However, their low ordering temperatures, Tc, sensitivity to atmospheric conditions and difficulties in preparing clean large-area samples still present major limitations to further progress, especially amongst van der Waals magnetic semiconductors. The remarkably stable, high-Tc vdW magnet CrSBr has the potential to overcome these key shortcomings, but its nanoscale properties and rich magnetic phase diagram remain poorly understood. Here we use single spin magnetometry to quantitatively characterise saturation magnetization, magnetic anisotropy constants, and magnetic phase transitions in few-layer CrSBr by direct magnetic imaging. We show pristine magnetic phases, devoid of defects on micron length-scales, and demonstrate remarkable air-stability down the monolayer limit. We furthermore address the spin-flip transition in bilayer CrSBr by imaging the phase-coexistence of regions of antiferromagnetically (AFM) ordered and fully aligned spins. Our work will enable the engineering of exotic electronic and magnetic phases in CrSBr and the realization of novel nanomagnetic devices based on this highly promising vdW magnet.
The Escherichia coli chromosome moves to the replisome
Authors: Gras Konrad , Fange David , Elf Johan 
Published: July 2024

AbstractIn Escherichia coli, it is debated whether the two replisomes move independently along the two chromosome arms during replication or if they remain spatially confined. Here, we use high-throughput fluorescence microscopy to simultaneously determine the location and short-time-scale (1 s) movement of the replisome and a chromosomal locus throughout the cell cycle. The assay is performed for several loci. We find that (i) the two replisomes are confined to a region of ~250 nm and ~120 nm along the cell’s long and short axis, respectively, (ii) the chromosomal loci move to and through this region sequentially based on their distance from the origin of replication, and (iii) when a locus is being replicated, its short time-scale movement slows down. This behavior is the same at different growth rates. In conclusion, our data supports a model with DNA moving towards spatially confined replisomes at replication.
Realization of a two-dimensional Weyl semimetal and topological Fermi strings
Authors: Lu Qiangsheng , Reddy P. V. Sreenivasa , Jeon Hoyeon , Mazza Alessandro R. , Brahlek Matthew , Wu Weikang , Yang Shengyuan A. , Cook Jacob , Conner Clayton , Zhang Xiaoqian , Chakraborty Amarnath , Yao Yueh-Ting , Tien Hung-Ju , Tseng Chun-Han , Yang Po-Yuan , Lien Shang-Wei , Lin Hsin , Chiang Tai-Chang , Vignale Giovanni , Li An-Ping , Chang Tay-Rong , Moore Rob G. , Bian Guang 
Published: July 2024

AbstractA two-dimensional (2D) Weyl semimetal, akin to a spinful variant of graphene, represents a topological matter characterized by Weyl fermion-like quasiparticles in low dimensions. The spinful linear band structure in two dimensions gives rise to distinctive topological properties, accompanied by the emergence of Fermi string edge states. We report the experimental realization of a 2D Weyl semimetal, bismuthene monolayer grown on SnS(Se) substrates. Using spin and angle-resolved photoemission and scanning tunneling spectroscopies, we directly observe spin-polarized Weyl cones, Weyl nodes, and Fermi strings, providing consistent evidence of their inherent topological characteristics. Our work opens the door for the experimental study of Weyl fermions in low-dimensional materials.