bluuebunny/crossref_metadata_2025_split huggingface dataset:
Voltammetric determination of Nordiazepam at meniscus modified silver solid amalgam electrode
Authors: Samiec Petr , Navrátilová Zuzana 
Published: December 2014

Abstract
New electrochemical method for determination of Nordiazepam (NDZ) at meniscus modified silver solid amalgam electrode (m-AgSAE) was developed utilizing differential pulse voltammetry (DPV). The pH effect on the current response of NDZ was studied in the mixture of Britton-Robinson buffer (BR) and methanol (9:1) with optimum pH value of 10. The calibration dependences were examined under the optimal conditions and linearity in the range from 2 × 10−6 to 1 × 10−4 mol L−1 with limit of quantification of 1.7 × 10−6 mol L−1 were accomplished.
Mercury content in hairs of mother-child pairs in Slovakia as a biomarker of environmental exposure
Authors: Borošová Daniela , Slotová Katarína , Fabiánová Eleonóra 
Published: December 2014

Abstract
The mercury content in hairs was determined in the framework of the European funded projects COPHES and DEMOCOPHES to test the feasibility of an EU-HBM (Human Biomonitoring) approach generating comparable data. The aim of the Slovak participation in DEMOCOPHES was to obtain and contribute the Slovak data to the harmonization of Human Biomonitoring. Pre-analytical and analytical phase for mercury in hair measurements and activities developed for the harmonization analysis within COPHES/ DEMOCOPHES projects were conducted under a strict quality assurance program (QA/QC). Total mercury in hair was determined by thermal decomposition-gold amalgamation atomic absorption spectroscopy (AMA- 254 Advanced Mercury Analyzer.) Two interlaboratory comparison investigations (ICIs) and two external quality assessment schemes (EQUAS) were conducted before the beginning of the COPHES/DEMOCOPHES projects. The laboratory successfully completed both ICIs and EQUAS schemes and was allowed to analyze all DEMOCOPHES samples of the Slovak Republic. In summary, 129 mother-child pairs were recruited to pilot study of DEMOCOPHES in Slovakia from two different locations representing urban and rural environment. The analyzed data from Slovakia showed relationship between frequency of fish meals consumption (especially sea fish and sea food products) and mercury concentrations in hair of mothers and children. The exposure levels for a sampled population in Slovakia (children 0.092 (0.080-0.106) [μg.g-1], mother 0.130 (0.113-0.148) [μg.g-1]) are below the EU level (children 0.145 (0.139-0.151) [μg.g-1], mother 0.225 (0.216-0.234) [μg.g-1]) up to an order of magnitude lower than the limit medically important (FAO/WHO health-based guidance value of 2.3 μg.g-1 JECFA - Joint FAO/WHO Expert Committee on Food Additives).
Tetragonal or Hexagonal Symmetry in Modeling of Failure Criteria for Transversely Isotropic Materials
Authors: Ganczarski Artur , Adamski Michał 
Published: December 2014

Abstract
Present work deals with modeling of failure criteria for transversely isotropic materials. Analysis comprises two classes of symmetry: Tsai-Wu tetragonal and new Tsai-Wu based hexagonal. Detail analysis of both classes of symmetry with respect to their advantages as well as limitations is presented. Finally, simple comparison of differences between limit curves corresponding to cross sections by planes of transverse isotropy, orthotropy and shear plane is done.
Constitutive Modelling and Identification of Parameters of 316L Stainless Steel at Cryogenic Temperatures
Authors: Ryś Maciej 
Published: December 2014

Abstract
In this work, a macroscopic material model for simulation two distinct dissipative phenomena taking place in FCC metals and alloys at low temperatures: plasticity and phase transformation, is presented. Plastic yielding is the main phenomenon occurring when the yield stress is reached, resulting in nonlinear response of the material during loading. The phase transformation process leads to creation of two-phase continuum, where the parent phase coexists with the inclusions of secondary phase. An identification of the model parameters, based on uniaxial tension test at very low temperature, is also proposed.
Failure Analysis of a Femoral Hip Stem Made of Stainless Steel After Short Time of Exposure
Authors: Mierzejewska Żaneta Anna , Oksiuta Zbigniew 
Published: December 2014

Abstract
This paper describes a case study summarising the failure analysis of a stainless steel femoral stem, which failed prematurely within 36 months of exploitation in human body. In order to determine the mechanism of failure, a broken stem component were analyzed by means of macroscopic and microscopic obserwations and hardness measurements. Metallurgical obserwations revealed that the tested material does fulfill ASTM requirements. Scanning electron microscopy images revealed the presence of stress-induced cracking. The results of the hardness revealed significant nonuniformity from the surface towards the inner part of the stem. It is assumed that any discontinuity or defect on the fracture surface of the stem acted as preferential site for a crack nucleation and propagation by fatigue until the cross section of stem was not able to sustain a load generated by a patient.
Effect of Plasma Nitriding Process Conditions on Corrosion Resistance of 440B Martensitic Stainless Steel
Authors: Łępicka Magdalena , Grądzka-Dahlke Małgorzata 
Published: December 2014

Abstract
Martensitic stainless steels are used in a large number of various industrial applications, e.g. molds for plastic injections and glass moldings, automotive components, cutting tools, surgical and dental instruments. The improvement of their tribological and corrosion properties is a problem of high interest especially in medical applications, where patient safety becomes a priority. The paper covers findings from plasma nitrided AISI 440B (PN-EN or DIN X90CrMoV18) stainless steel corrosion resistance studies. Conventionally heat treated and plasma nitrided in N2:H2 reaction gas mixture (50:50, 65:35 and 80:20, respectively) in two different temperature ranges (380 or 450°C) specimens groups were examined. Microscopic observations and electrochemical corrosion tests were performed using a variety of analytical techniques. As obtained findings show, plasma nitriding of AISI 440B stainless steel, regardless of the process temperature, results in reduction of corrosion current density. Nevertheless, applying thermo-chemical process which requires exceeding temperature of about 400°C is not recommended due to increased risk of steel sensitization to intergranular and stress corrosion. According to the results, material ion nitrided in 450°C underwent leaching corrosion processes, which led to significant disproportion in chemical composition of the corroded and corrosion-free areas. The authors suggest further research into corrosion process of plasma nitrided materials and its degradation products.
Electrical Properties of Sunflower Achenes
Authors: Novák Ján , Vitázek Ivan 
Published: December 2014

Abstract
This work contains the results of measuring the electrical properties of sunflower achenes. The interest in electrical properties of biological materials resulted in engineering research in this field. The results of measurements are used for determining the moisture content, the surface level of liquid and grainy materials, for controlling the presence of pests in grain storage, for the quantitative determination of mechanical damage, in the application of dielectric heating, and in many other areas. Electrical measurements of these materials are of fundamental importance in relation to the analysis of quantity of absorbed water and dielectric heating characteristics. It is a well-known fact that electrical properties of materials, namely dielectric constant and conductivity, are affected by the moisture content of material. This fact is important for the design of many commercial moisturetesting instruments for agricultural products. The knowledge of dielectric properties of materials is necessary for the application of dielectric heating. The aim of this work was to measure conductivity, dielectric constant and loss tangent on samples of sunflower achenes, the electrical properties of which had not been sufficiently measured. Measurements were performed under variable moisture content and the frequency of electric field ranging from 1 MHz to 16 MHz, using a Q meter with coaxial probe. It was concluded that conductivity, dielectric constant and loss tangent increased with increasing moisture content, and dielectric constant and loss tangent decreased as the frequency of electric field increased.
Correlations between some physico-chemical properties of sunflower oil
Authors: Neagu Anişoara-Arleziana , Niţă Irina , Botez Elisabeta 
Published: December 2014

Abstract
The major objective of this study is to report physico-chemical properties of sunflower oil samples collected from different stages of the technological process for sunflower oil refining for food industry. The samples of oil were crude oil, washed oil, bleached oil and deodorized oil. The physico-chemical properties of sunflower oil experimentally determined were density, saponification value (SV), iodine value (IV), and acid value (AV). It was found that the density of sunflower oil remains approximately constant over the different stages of the manufacturing flow of cooking oil, except the crude oil. The acid value significantly decreases from crude oil (2.588) to deodorized oil (0.366). The iodine value and saponification value of the different samples of the sunflower oil corresponding to different stages of oil processing varies slightly. The capacity of different models to accurately correlate and/or predict the density of vegetable oil was tested. The density of sunflower oil can be accurately estimated from its SV and IV or with an empirical equation, when density data are available.
Physico-chemical characterisation of sea buckthorn extracts for cosmetic use
Authors: Chirila Elisabeta , Oancea Elena , Oancea Ioana Adina 
Published: December 2014

Abstract
The purpose of the paper is to present original results concerning characterization of different sea buckthorn (Hippophae rhamnoides L.) extracts and some original dermato-cosmetic products containing these extracts. Aqueous distillate from fruits and leafy branches, aqueous extract from seeds, fresh fruit juice and frozen fruit juice after 2 years of storage, ethanolic extracts of buds have been analyzed for the following parameters: total and organic acidity, oxidability, calcium and magnezium, pH, conductivity, oxidation-reduction potential (ORP). The investigated sea buckthorn extracts have important contribution in care and treatment of skin diseases; during many years of experience in this field great benefits have been observed. Taking into account also the results of previous studies of other researchers we consider that the ORP measurement of cosmetic mixtures could provide objective, cheap and reliable information about antioxidant activity of complex samples.
The quality control of some dermo-cosmetic products
Authors: Popescu Viorica , Soceanu Alina , Dobrinas Simona 
Published: December 2014

Abstract
This paper refers to the quality analysis of three dermo-cosmetic products: two face creams and a biphasic solution used for skin cleaning: a treatment cream for acne complexion, an anti-irritating soothing cream and a matifying purifying lotion. The following characteristics have been investigated: aspect, smell, colour, solubility, type of emulsion, stability test at certain temperatures (4°C and 40°C), pH, melting point, water, volatile substances and total fats contents, acidity, ester index, saponification index, iodine index, peroxide index, microbic carriage, metal traces (determined by ICP-MS method). All analysed dermo-cosmetic products have appropriate physico-chemical characteristics. The analyses made for determining the microbial charge have proven that the three dermo-cosmetic products do not contain any aerobic pathogen germens or micromicetes, Staphylococcus aureus and Escherichia Coli. The ICP-MS analysis has proven that the dermocosmetic products do not contain traces of Hg and Pb.
Mathematical Model of the Heald with Damping Element
Authors: Bílek Martin , Skřivánek Josef 
Published: December 2014

Abstract
This study focuses on the analysis of the existing design solution of shedding mechanism. It is characterised by a heald attachment into the heald shaft with a necessary design allowance. The preparation of a mathematical model for the new concept of the heald attaching to the heald shaft frame is explained in this study. A damping element for dissipating the energy created during the heald impact on the carrying wire of the heald shaft is currently used for the high-speed weaving loom. This system makes use of a damping element, fitted in the profile of the rod at an optimum distance from heald eye. This element provides for reduction of the heald velocity before its drop upon the supporting wire because the opposite section of the heald is pressed into the rubber element. The calculated results of the new concept of the heald attaching to the heald shaft frame are compared with the existing solution without application of the damping element.
Analysis of multivariate repeated measures data using a MANOVA model and principal components
Authors: Krzysko Mirosław , Smiałowski Tadeusz , Wołynski Waldemar 
Published: December 2014

Abstract
In this paper we consider a set of T repeated measurements on p characteristics on each of n individuals. The n individuals themselves may be divided and randomly assigned to K groups. These data are analyzed using a mixed effect MANOVA model, assuming that the data on an individual have a covariance matrix which is a Kronecker product of two positive definite matrices. Results are illustrated on a data set obtained from experiments with varieties of winter rye.
Microscopic changes in the kidneys of cows infected with Leptospira sp.
Authors: Ukhovskyi Vitalii , Borisevich Boris , Kulykova Vlada , Żmudzki Jacek , Jabłoński Artur 
Published: December 2014

Abstract
The article presents data on histopathological studies of the kidneys of cows, which either recovered or died from leptospirosis. Fragments of seven kidneys from slaughtered cows, positive for Leptospira antibodies in the microscopic agglutination test (MAT) (titres of 50 and higher) were used in the study. The MAT was conducted with eight serological groups of Leptospira: Canicola, Grippotyphosa, Hebdomadis, Icterohaemorrhagiae, Pomona, Sejroe, Tarassovi, and Australis. Microscopic changes in all morphological structures of the kidneys were presented. Micromorphological criteria, which can be used for post-mortem diagnosis of leptospirosis were established. They included: serous glomerulonephritis with granular dystrophy of podocytes, necrosis and collapse of the inner layer of Bowman's capsule, partial destruction of capsule and vascular glomeruli, granular and vacuolar degeneration and destruction of tubular epithelial cells, foci of interstitial oedema, and infiltrations predominantly with monocytes and isolated neutrophils. Microscopic changes in the kidneys suggest that the cows died from leptospirosis as a result of toxic shock syndrome.
Gastrointestinal helminths of raccoons (Procyon lotor) in western Poland (Lubuskie province) - with particular regard to Baylisascaris procyonis
Authors: Karamon Jacek , Kochanowski Maciej , Cencek Tomasz , Bartoszewicz Magdalena , Kusyk Paweł 
Published: December 2014

Abstract
The aim of the study was to estimate the prevalence of gastrointestinal parasites in raccoons with particular regard to zoonotic parasites. Fifty-five raccoons, hunted or found dead on roads, were examined. The small and large intestines were collected from all raccoons and, additionally, the stomach was collected from 43 animals. The samples were examined with the use of sedimentation and counting technique. The intestines and stomach were examined separately. Samples of raccoon faeces were collected from their environment localised in Słubice district, Lubuskie province (Poland). The samples were collected once a month in 2012. In total, 154 faecal samples were obtained and examined with the use of McMaster flotation technique. The following parasites were detected in the intestinal and stomach contents: tapeworms Mesocestoides sp. (67.3%), Echinostomatidae flukes (34.5%), and nematodes Capillaria sp. (25.5%). Moreover, Acanthocephala were found in the intestines of three raccoons. The highest intensity of infection were observed in case of Mesocestoides sp. Mesocestoides sp. and Echinostomatidae were found statistically more often in the intestines than in the stomach. In the case of these two parasites, there was positive correlation between the intensity of infection in the intestines and the presence of the same parasites in the stomach. Moreover, significantly higher prevalence and intensity of Mesocestoides sp. in males than in females were also observed. Faecal samples contained Baylisascaris procyonis eggs (mean 60 epg). These eggs were found in three samples collected in November and December. Furthermore, in some faecal samples eggs of flukes, Capillaria sp., Mesocystoides sp., and coccidian oocysts were found. It is one of rare reports concerning Baylisascaris procyonis in Poland confirming the presence of this dangerous parasite in Polish raccoon population.
Antimicrobial susceptibility pattern and SCCmec types of methicillin-resistant coagulase-negative staphylococci from subclinical bovine mastitis in Hatay, Turkey
Authors: Aslantaş Özkan , Yılmaz Mehmet Ali , Yılmaz Ebru Şebnem , Kurekci Cemil 
Published: December 2014

Abstract
Eighty-nine isolates of coagulase-negative staphylococci (CoNS) of eight species from subclinical bovine mastitis were screened for the phenotypic and genotypic methicilline-resistance. In addition, all methicillin-resistant (MR) isolates indicating the mecA gene were examined by PCR for the antimicrobial susceptibility patterns, and staphylococcal cassette chromosome mec (SCCmec) types were also determined by multiplex PCR. A total of 21 (23.6%) CoNS isolates were found to be resistant to oxacillin in broth microdilution assay. All isolates phenotypically resistant to oxacillin did not have the mecA gene, which was only found in 14.6% (13) of the isolates. Most MR-CoNS isolates were highly resistant to erythromycin (92.3%), fusidic acid (84.6%), penicillin (76.9%), and rifampycin (61.5%), and susceptible to mupirocin (100%), tetracycline (100%), vancomycin (100%), clindamycin (92.3%), and sulfamethoxazole-trimethoprim (69.2%). In conclusion, a high rate of antimicrobial resistance among MR-CoNS isolated from food producing animals emphasises the need for periodic surveillance of their resistance.
Confirmatory method for the determination of nitroimidazoles in milk by liquid chromatography - tandem mass spectrometry
Authors: Mitrowska Kamila , Antczak Maja , Posyniak Andrzej 
Published: December 2014

Abstract
A multiresidue method for the determination of seven nitroimidazoles and their hydroxy metabolites in milk was developed. Milk samples were extracted with acetonitrile and cleaned up on strong cation-exchange solid phase extraction cartridges. Evaporated to dryness first, the extracts obtained were then reconstituted in 0.1% formic acid and injected onto a liquid chromatography-tandem mass spectrometer (LC-MS/MS). The separation of analytes was achieved on gradient mode using a C18 column and a mobile phase consisting of 0.1% formic acid in acetonitrile and 0.1% formic acid in water. Multiple reaction monitoring mode was set for the MS/MS with positive electrospray ionisation. For quantification, the isotope dilution method was used with isotopically labeled analogues of the target analytes. The method was evaluated entirely in accordance with EU Commission Decision 2002/657/EC and all validation criteria were in the required ranges. The method can easily detect and confirm metronidazole, dimetridazole, ronidazole, ipronidazole, and their hydroxy metabolites below the recommended concentration level of 3 μg/kg. The decision limits and detection capabilities ranged from 0.11 μg/kg to 0.22 μg/kg and from 0.19 μg/kg to 0.37 μg/kg respectively. The overall recoveries were between 96.6% and 105.2% with a good coefficient of variation, less than 8.7% under within-laboratory reproducibility conditions.
Chloroorganic insecticides in the fat of different assortment of rainbow trout (Oncorhynchus mykiss) meat
Authors: Pietrzak-Fiećko Renata , Parol Jarosław 
Published: December 2014

Abstract
The aim of the study was to determine the content of chlorinated hydrocarbon residues in fat of different assortment of rainbow trout (Oncorhynchus mykiss). The research material consisted of 108 fish from six different producers. Thirty-six fish were analysed as fresh, 36 fish as frozen after six months storage, and 36 fish as traditionally smoked. Chromatographic determination of γ-HCH, DDT, DDD, and DDE was performed with an Agilent Technologies 6890N. The presence of the compounds was detected in all tested fat samples. The content of γ-HCH was five-fold higher in frozen fish (average 2.11 ng/g of fat) than in fresh and smoked fish (0.42 ng/g of fat and 0.43 ng/g of fat, respectively). Total DDT (ΣDDT) content was found higher after refrigerated storage but did not exceed acceptable levels, indicating that the fat in the meat of rainbow trout is an attractive nutritional compound with a low concentration of tested chemical pollutants.
Determination of natural and synthetic oestrogens in surface water using gas chromatography-mass spectrometry
Authors: Woźniak Barbara , Kłopot Alicja , Matraszek-Żuchowska Iwona , Sielska Katarzyna , Żmudzki Jan 
Published: December 2014

Abstract
A simple and sensitive gas chromatography method was developed to determine a group of oestrogens in surface water. In the first stage of analysis, enzymatic hydrolysis of oestrogen metabolites with glucuronidase AS-HP was performed. Free compounds were extracted from 200 mL of water sample on C18 SPE column (6 mL, 1000 mg). The evaporated extract was subjected to derivatisation with a mixture of MSTFA/NH4I/DTT (1000:2:5, v/w/w). The separation of the analytes on HP-5ms capillary column was conducted. The method was validated according to the Commission Decision 2002/657/EC. Recovery in spiked samples ranged from 90% to 120 % with standard deviation lower than 30% for all examined compounds. The decision limit and detection capability of five oestrogens were in the range of 0.3-0.6 ng L-1 and 0.5-0.9 ng L-1, respectively. Nineteen water samples collected from different sites of several Polish rivers and lakes were tested for the presence of oestrogens. Some target compounds such as 17α-oestradiol, 17β-oestradiol, oestrone, oestriol, and 17α-ethynyloestradiol were found in trace amounts in the analysed samples. The highest concentration observed for oestradiol reached 23 ng L-1.