bluuebunny/crossref_metadata_2025_split huggingface dataset:
“Blessed are the cheese makers”
Authors: Carter Michael G. 
Published: April 2014

Editor’s note: Presidential Address delivered at Portland, Oregon on March 17, 2013 on the occasion of the AOS annual meeting. The submission was not edited, at the insistence of the author; this was granted as a prerogative restricted to his Presidential Address, for reasons that will be understood by a perusing of the subject matter. All infelicities are in keeping with the original submission.
Author’s note: In keeping with the theme of this Address the published text aims to reproduce exactly the words that were read out. The version presented here is based on a scanned image of the only copy of the original typescript with the author’s hand-written changes, retrieved from a member of the audience to whom it was given after the proceedings. Transliteration (with two corrections) follows the conventions of the Journal, and the source references have been moved into the footnotes. Bibliographical attributions are minimal: colleagues will easily distinguish between sweeping statements which could be documented if need be, and the private opinions of the writer.
Design of Polar Skyrmion‐Based Nanoelectronic Prototype Devices with Phase‐Field Simulations
Authors: Du Guanshihan , Zhou Linming , Huang Yuhui , Wu Yongjun , Tian He , Hong Zijian 
Published: July 2024

AbstractThe creation and manipulation of complex topological states like vortex and skyrmion in ferroelectric heterostructures have received significant attention recently across various fields, due to the rich physical insights, exotic properties, and wide potential applications. Although progress has been made in the synthesis, local manipulation, and dynamic motion of these tiny quasi‐particles, the design of skyrmion‐based nanoelectronic prototype devices is still lacking. Herein, using phase‐field simulations, the idea is to integrate the polar skyrmions in a PbTiO3/SrTiO3 superlattice system with a local charged tip/small electrode and a skyrmion counter to design several nanoelectronics prototype devices, such as the skyrmion switch and multistate memory. In this design, the topological charge of the system serves as the “bit”. Phase diagrams to display the change in topological charges are constructed under different operation conditions such as tip radius and applied potential. By varying the applied electric potential, up to ten topological states can be achieved. Asymmetric topological transitions are observed, where the change in topological charge is greater under negative potential due to different switching routes wi applied electric fields along different directions. It is hoped that this work will inspire further research in polar‐skyrmion‐based electronic devices.
Device‐Level in‐Sensor Olfactory Perception System Based on Array of PCBM‐MAPbI3 Heterostructure Transistors
Authors: Zhai Yongbiao , Duan Guangxiong , Hu Jiahui , Lv Ziyu , Ding Guanglong , Zhou Ye , Han Su‐Ting 
Published: July 2024

AbstractAlthough there are significant advancements in device‐level artificial tactile and visual perception systems based on in‐sensor computing paradigms, the development of hardware‐implemented neuromorphic olfactory system is still in its early stages. One of the primary challenges in this field is that most of the gas sensors lack the capability to fuse the sensing and computing functions in a single sensor. Through surface passivation and interface engineering, this work introduces a device‐level artificial olfactory system utilizing array of PCBM‐MAPbI3 heterostructure transistors. Noteworthly, the formation of metastable intermediate phase NH3PbI3•MA can occur at room temperature and can be used to store gas sensory information. Both gas pulse and electrical pulse can dynamically modulate the amount of this intermediate phase, and then change the channel conductance (weight), realizing the fusion of the sensing and synaptic functions in single device. Based on these excellent properties, the spatiotemporal information of gas diffusion can be encoded and processed simultaneously. As a result, an in‐sensor olfactory perception system is successfully demonstrated based on 5 × 5 PCBM‐MAPbI3 heterostructure transistor array, which can be used for detecting the distance and direction of the hazardous gas. This work paves the way for future application of real‐time and data‐intensive machine‐olfactory system.
Machine Learning‐Aided Design of Highly Conductive Anion Exchange Membranes for Fuel Cells and Water Electrolyzers
Authors: Zhang Qiuhuan , Yuan Yongjiang , Zhang Jiale , Fang Pengda , Pan Ji , Zhang Hao , Zhou Tao , Yu Qikun , Zou Xiuyang , Sun Zhe , Yan Feng 
Published: July 2024

AbstractAlkaline anion exchange membrane (AEM)‐based fuel cells (AEMFCs) and water electrolyzers (AEMWEs) are vital for enabling the efficient and large‐scale utilization of hydrogen energy. However, the performance of such energy devices is impeded by the relatively low conductivity of AEMs. The conventional trial‐and‐error approach to designing membrane structures has proven to be both inefficient and costly. To address this challenge, a fully connected neural network (FCNN) model is developed based on acid‐catalyzed AEMs to analyze the relationship between structure and conductivity among 180,000 AEM variations. Under machine learning guidance, anilinium cation‐type membranes are designed and synthesized. Molecular dynamics simulations and Mulliken charge population analysis validated that the presence of a large anilinium cation domain is a result of the inductive effect of N+ and benzene rings. The interconnected anilinium cation domains facilitated the formation of a continuous ion transport channel within the AEMs. Additionally, the incorporation of the benzyl electron‐withdrawing group heightened the inductive effect, leading to high conductivity AEM variant as screened by the machine learning model. Furthermore, based on the highly active and low‐cost monomers given by machine learning, the large‐scale synthesis of anilinium‐based AEMs confirms the potential for commercial applications.
Passive and Wireless, Ion‐Selective Sensor Arrays for Multimineral Comonitoring of Food
Authors: Li Lei , Ye Fan , Dia Kazi Khurshidi Haque , Escobar Alberto Ranier , Hasan Abeed , Qin Huiting , Lin Jialin , Tseng Peter 
Published: July 2024

AbstractIon consumption plays key roles in maintaining bodily homeostasis and health. Here passive wireless, multimineral comonitoring arrays are studied that may potentially be utilized for emerging applications in precision nutrition. RF biosensors targeting select minerals (calcium or magnesium demonstrated herein) are built from integrating ion‐selective membranes within a broadside‐coupled split ring resonator architecture. RF sensors are typically monitored one at a time and such platforms often are incapable of comeasuring multiple confounding components. To address this challenge, this sensor arrays are further directly integrated alongside a conformal, custom readout coil that optimizes multi‐RF sensor readout. Such optimized networks exhibit enhanced signal clarity, further facilitating coextraction of multiple ion components. A simple method of extracting multimineral concentrations from food even despite the imperfect selectivity of divalent ion‐selective membranes is introduced. This passive wireless, zero‐electronic ion‐monitoring platform integrates seamlessly on foodware or packaging, possessing many applications in food measurement.
HDAC8 Enhances the Function of HIF‐2α by Deacetylating ETS1 to Decrease the Sensitivity of TKIs in ccRCC
Authors: Qian Kang , Li Wei , Ren Shangqing , Peng Weilin , Qing Bei , Liu Xinlin , Wei Xiong , Zhu Liang , Wang Yapeng , Jin Xin 
Published: July 2024

AbstractDrug resistance after long‐term use of Tyrosine kinase inhibitors (TKIs) has become an obstacle for prolonging the survival time of patients with clear cell renal cell carcinoma (ccRCC). Here, genome‐wide CRISPR‐based screening to reveal that HDAC8 is involved in decreasing the sensitivity of ccRCC cells to sunitinib is applied. Mechanically, HDAC8 deacetylated ETS1 at the K245 site to promote the interaction between ETS1 and HIF‐2α and enhance the transcriptional activity of the ETS1/HIF‐2α complex. However, the antitumor effect of inhibiting HDAC8 on sensitized TKI is not very satisfactory. Subsequently, inhibition of HDAC8 increased the expression of NEK1, and up‐regulated NEK1 phosphorylated ETS1 at the T241 site to promote the interaction between ETS1 and HIF‐2α by impeded acetylation at ETS1‐K245 site is showed. Moreover, TKI treatment increased the expression of HDAC8 by inhibiting STAT3 phosphorylation in ccRCC cells is also found. These 2 findings highlight a potential mechanism of acquired resistance to TKIs and HDAC8 inhibitors in ccRCC. Finally, HDAC8‐in‐PROTACs to optimize the effects of HDAC8 inhibitors through degrading HDAC8 and overcoming the resistance of ccRCC to TKIs are synthesized. Collectively, the results revealed HDAC8 as a potential therapeutic candidate for resistance to ccRCC‐targeted therapies.
Realizing Sunlight‐Induced Efficiently Dynamic Infrared Emissivity Modulation Based on Aluminum‐Doped zinc Oxide Nanocrystals
Authors: Jia Yan , Liu Dongqing , Chen Desui , Jin Yizheng , Ge Yufei , Zhang Wenxia , Chen Chen , Cheng Baizhang , Wang Xinfei , Liu Tianwen , Li Mingyang , Zu Mei , Wang Zi , Cheng Haifeng 
Published: July 2024

AbstractDynamic manipulation of an object's infrared radiation characteristics is a burgeoning technology with significant implications for energy and information fields. However, exploring efficient stimulus–spectral response mechanism and realizing simple device structures remains a formidable challenge. Here, a novel dynamic infrared emissivity regulation mechanism is proposed by controlling the localized surface plasmon resonance absorption of aluminum‐doped zinc oxide (AZO) nanocrystals through ultraviolet photocharging/oxidative discharging. A straightforward device architecture that integrates an AZO nanocrystal film with an infrared reflective layer and a substrate, functioning as a photo‐induced dynamic infrared emissivity modulator, which can be triggered by weak ultraviolet light in sunlight, is engineered. The modulator exhibits emissivity regulation amount of 0.72 and 0.61 in the 3–5 and 8–13 µm ranges, respectively. Furthermore, the modulator demonstrates efficient light triggering characteristic, broad spectral range, angular‐independent emissivity, and long cyclic lifespan. The modulator allows for self‐adaptive daytime radiative cooling and nighttime heating depending on the ultraviolet light in sunlight and O2 in air, thereby achieving smart thermal management for buildings with zero‐energy expenditure. Moreover, the potential applications of this modulator can extend to rewritable infrared displays and deceptive infrared camouflage.
Anomalous Magnetoelectric Coupling in the Paramagnetic State of a Chiral and Polar Magnet
Authors: Xu Xianghan , Du Kai , Cheong Sang‐Wook , Cava R. J. 
Published: July 2024

AbstractChiral magnets are excellent platforms for studying intertwined spin, charge, orbit, and lattice degrees of freedom in solid‐state materials. In this work, the anomalous magnetoelectric behavior in a chiral magnet K2Co2(SO4)3 is demonstrated using comprehensive experimental probes. This material adopts a P213 chiral cubic structure at room temperature. Based on the results of high‐resolution synchrotron X‐ray diffraction, this study shows that the low‐temperature (<130 K) crystal structure is a P21 monoclinic phase, both polar and chiral. Magnetic and thermodynamic measurements reveal highly frustrated magnetic interactions and possible non‐collinear antiferromagnetic ordering at an extremely low temperature ≈0.6 K. Critically, anomalous magnetoelectric correlations are experimentally detected in its paramagnetic temperature regime, which can arise from the synergetic interplay between magnetoelastic and piezoelectric effects. These findings thus indicate that K2Co2(SO4)3 is a unique material, displaying multiple emergent structural and magnetic phenomena. This is attributed to both its overall crystallographic symmetry and the fact that its magnetic ions are located at low‐symmetry sites.
Non‐Ionic Perylene‐Diimide Polymer as Universal Cathode Interlayer for Conventional, Inverted, and Blade‐Coated Organic Solar Cells
Authors: Feng Luxin , Xiang Yanhe , Li Zhe , Li Qingyang , Dong Hongliang , Yan Shouke , Xu Bowei , Hou Jianhui 
Published: July 2024

AbstractAs a class of predominantly used cathode interlayers (CILs) in organic solar cells (OSCs), perylene‐diimide (PDI)‐based polymers exhibit intriguing characteristics of excellent charge transporting capacity and suitable energy levels. Despite that, PDI‐based CILs with satisfied film‐forming ability and adequate solvent resistance are rather rare, which not only limits the further advance of OSC performances but also hinders the practical use of PDI CILs. Herein, we designed and synthesized two non‐conjugated PDI polymers for achieving high power conversion efficiency (PCE) in diverse types of OSCs. The utilization of oligo (ethylene glycol) (OEG) linkage enhanced the n‐doping effect of PDI polymers, leading to an improved ability of the CIL to reduce work function and improve electron transporting capability. Moreover, the introduction of the non‐ionic OEG chain effectively improve the wetting property and solvent resistance of PDI polymers, so the PPDINN CIL can withstand diverse processing conditions in fabricating different OSCs, including conventional, inverted and blade‐coated devices. The binary OSC with conventional structure using PPDINN CIL showed a PCE of 18.6 %, along with an improved device stability. Besides, PPDINN is compatible with the large‐area blade‐coating technique, and a PCE of 16.6 % was achieved in the 1‐cm2 OSC where a blade‐coated PPDINN was used.
Boosting Stimulated Emission via a Hydrogen‐Bonded Co‐Crystallization Approach in Molecular Crystals
Authors: Ren Haoxuan , Hu Jiasong , Liu Ying‐Jie , Liu Yu , Xu Bin , Tian Wenjing 
Published: July 2024

AbstractStimulated emission (SE) of organic π‐conjugated molecule in solid state remains a significant challenge, mainly involving the mode of molecular stacking that invariably alters the photo‐physical processes. Herein, we successfully realized stimulated emission in molecular crystals using a hydrogen‐bonded co‐crystallization strategy. Two hydrogen‐bonded co‐crystals, obtained from 1,4‐bis‐p‐cyanostyrylbenzene (CNDSB) and two types of co‐formers, can boost stimulated emission and show decent amplified spontaneous emission (ASE), whereas the parent CNDSB crystal is not SE‐active. Crystal structural analysis demonstrated that the co‐crystallization eliminated excimer formation. The resulting higher kr and shorter excited lifetime led to a larger stimulated emission cross‐section, which benefited to the occurrence of ASE. Simultaneously, the uniaxial arrangements along the long axis of co‐crystal together contributed to highly polarized emission. This system presents very rare evidence of boosting stimulated emission by binary co‐crystallization, which enriches our insights into organic solid‐state lasers.
Twisted Structure and Multiple Charge‐Transfer Channels Endow Thermally Activated Delayed Fluorescence Devices with Small Efficiency Roll‐Off and Low Concentration Dependence
Authors: Zhu Yuan‐Ye , Xie Feng‐Ming , Li Hao‐Ze , Zhang Kai , Wang Han‐Yang , Shi Hao‐Nan , Zou Jianhua , Li Yan‐Qing , Tang Jian‐Xin 
Published: July 2024

AbstractDespite the rapid development of thermally activated delayed fluorescent (TADF) materials, developing organic light‐emitting diodes (OLEDs) with small efficiency roll‐off remains a formidable challenge. Herein, we have designed a TADF molecule (mClSFO) based on the spiro fluorene skeleton. The highly twisted structure and multiple charge‐transfer channels effectively suppress aggregation‐caused quenching (ACQ) and endow mClSFO with excellent exciton dynamic properties to reduce efficiency roll‐off. Fast radiative rate (kr) and rapid reverse intersystem crossing (RISC) rate (kRISC) of 1.6×107 s−1 and 1.07×106 s−1, respectively, are obtained in mClSFO. As a result, OLEDs based on mClSFO obtain impressive maximum external quantum efficiency (EQEmax) exceeding 20 % across a wide doping concentration range of 10–60 wt %. 30 wt % doped OLED exhibits an EQEmax of 23.1 % with a small efficiency roll‐off, maintaining an EQE of 18.6 % at 1000 cd m−2. The small efficiency roll‐off and low concentration dependence observed in the TADF emitter underscore its significant potential.
Fault‐tolerant control of unmanned marine vehicles with unknown parametric dynamics via integral sliding mode output feedback control
Authors: Hao Li‐Ying , Yang Xin , Zhang Yu‐Qing , Atajan Hudayberenov , Liu Yanli 
Published: July 2024

AbstractThis paper focuses on fault‐tolerant control (FTC) for unmanned marine vehicles (UMVs) subject to unknown parametric dynamics, thruster faults, and external disturbances. A novel FTC strategy based on the integral sliding mode output feedback method is proposed. Based on a high gain compensator and output information, a novel integral sliding mode fault‐tolerant controller is constructed to guarantee the dynamic positioning (DP) of UMVs. An attraction region that is related to the known positive constants with respect to dynamic uncertainties has been revealed for the first time. Finally, the closed‐loop stability can be guaranteed from the every initial time in despite of unknown parametric dynamics, thruster faults, and external disturbances. Simulation though a typical floating production ship model has verified the effectiveness of the proposed method.
Theoretical Understandings on Mechanisms of Hydrogenation Activities Using Graphene‐Based Single‐Atom Catalysts
Authors: Lv Chao , Chen De‐Li 
Published: July 2024

AbstractMetal single‐atom catalysts (SACs) have emerged as a promising class of catalysts in various fields, owing to their well‐defined active centers, tunable coordination environments, and high reaction selectivity. Among the diverse supports, graphene‐based SACs have garnered significant attention due to their exceptional properties in hydrogenation reactions. This review elucidates recent advancements in theoretical investigations of the electronic and geometric structures of metal SACs, with a focus on modulation strategies such as coordination number adjustment, heteroatom doping, defect site engineering, and frustrated Lewis pair construction. This review emphasizes atomic‐level insights into the hydrogenation reaction mechanism in thermocatalysis, including the activation of the H‐source molecules, hydrogen diffusion, and elementary reaction steps. Strategies for modulating the catalytic activity of SACs are summarized. Lastly, this review offers perspectives on the design of effective graphene‐based SACs from theoretical standpoint, paving the way for future research in this exciting field.
Optimisation and Characterisation of Improved Nanoemulsion Formulations Containing Ceramide 3
Authors: Xu Fan , Liu Yuxin , Zhu Jun , Zhan Xin , Dong Yinmao , Meng Hong , Li Shujing , He Yifan , Zhang Ze 
Published: July 2024

AbstractCeramide3 (Cer3) is one of the important components of stratum corneum (SC) lipids with good moisturizing and repairing properties. However, it suffers from (a) poor solubility, (b) easy crystallization and precipitation, and (c) strong polarity and difficulty in transdermal application. This study aimed to load Cer3 into nanoemulsions (NEs) to overcome these mentioned defects. The optimized NEs formulation was prepared by high pressure homogenization method and characterized by several methods. The optimized ceramide3 nanoemulsions (Cer3‐NEs) exhibited a good physico‐chemical stability over 3 months under different conditions, with droplet size of 103.1 nm, PDI of 0.178, zeta potential of −39.09 mV, pH of 6.20 and encapsulation efficiency of 96.39 %. Turbiscan results showed that formulations containing Cer3‐NEs have better stability than those containing free Cer3. The dermal delivery ability of Cer3‐NEs was assessed by Franz diffusion and confocal Raman spectroscopy (CRM). In vitro and in vivo penetration studies showed that Cer3‐NEs serum have almost 2–3 times higher retention in the skin and permeation in the receptor solution compared to serum with free Cer3. The findings show NE is a promising carrier of Cer3 for topical administration in the treatment of dryness and barrier damage due to higher stability and better skin permeability.
Power corrupts and being sure of felt power corrupts even more: Implications for immoral decisions and cheating
Authors: Toader Irina , Moreno Lorena , Briñol Pablo , Petty Richard E. 
Published: July 2024

AbstractFeeling powerful has been generally associated with cheating. We argue that being sure of felt power strengthens the ability of perceived power to influence cheating and guide immoral decisions. In three different studies, we predicted and found that confidence (measured or manipulated) moderated the impact of felt power (measured or manipulated) on making immoral decisions during the Covid‐19 pandemic and actual cheating behaviour. Results indicated that power predicted cheating especially when participants were sure of their felt power. For those with low confidence, felt power did not affect cheating. Among other implications, these studies specify when and for whom the undesired effects of felt power can emerge and how to undermine them.
Dr.Emb Appyter: A web platform for drug discovery using embedding vectors
Authors: Kim Songhyeon , Bong Hyunsu , Jeon Minji 
Published: July 2024

AbstractUsing embedding methods, compounds with similar properties will be closely located in latent space, and these embedding vectors can be used to find other compounds with similar properties based on the distance between compounds. However, they often require computational resources and programming skills. Here we develop Dr.Emb Appyter, a user‐friendly web‐based chemical compound search platform for drug discovery without any technical barriers. It uses embedding vectors to identify compounds similar to a given query in the embedding space. Dr.Emb Appyter provides various types of embedding methods, such as fingerprinting, SMILES, and transcriptional response‐based methods, and embeds numerous compounds using them. The Faiss‐based search system efficiently finds the closest compounds of query in the library. Additionally, Dr.Emb Appyter offers information on the top compounds; visualizes the results with 3D scatter plots, heatmaps, and UpSet plots; and analyses the results using a drug‐set enrichment analysis. Dr.Emb Appyter is freely available at https://dremb.korea.ac.kr.
Shifting the focus? From individual to collective‐level effects of cash transfers: A systematic review of the impacts on social capital
Authors: Grisolia Filippo , Dewachter Sara , Holvoet Nathalie 
Published: July 2024

AbstractContrary to the individual and household levels, analysis on the collective‐level effects of cash transfers (CTs) is largely lacking. To fill such gap, this paper conducted a systematic review of the evidence around CT impacts on social capital. Available studies suggest that CTs can stimulate bonding social capital (social participation, membership of organizations), while often generate issues like rising inter‐group tensions and social exclusion (bridging social capital). Overall, however, the existing evidence is scarce. The article invites CT‐implementing agencies to design interventions in accordance with the envisaged impacts—not only at the individual but also at the collective level.