bluuebunny/crossref_metadata_2025_split huggingface dataset:
Spectroscopic investigations of green synthesized zinc oxide nanoparticles (ZnO NPs): antioxidant and antibacterial activity
Authors: Tiwari Ajay Kumar , Jha Saket , Tripathi Sharad Kumar , Shukla Rohit , Awasthi Ram Raseele , Bhardwaj Abhishek Kumar , Singh Abhimanyu Kumar , Dikshit Anupam 
Published: July 2024

AbstractIn the recent decade, zinc oxide nanoparticles (ZnO NPs) have been widely explored owing to their versatile properties and prodigious demands in the drug delivery, medical, energy storage, cosmetics, and the healthcare sectors. Therefore, the current work opts for an environmentally benign method to prepare ZnO NPs. The leaf extract of Calendula officinalis L. acts as a reducing agent for the metal ions; therefore, in the current research, ZnO NPs were prepared via green route by using Calendula officinalis leaf extract. Furthermore, the ZnO NPs were analysed with different spectroscopic techniques to confirm the structure and stability of nanomaterials. The prepared ZnO NPs were characterized by XRD, FE-SEM, FT-IR and UV–Vis studies. Also, the antioxidant and antimicrobial properties of the synthesized ZnO NPs were investigated. The XRD result of synthesized ZnO NPs showed the crystalline size 28.23 nm with wurtzite hexagonal structure along with the most intense peak (101). Following preliminary confirmations of the intended ZnO NPs, both big and small agglomerated forms were observed in the FE-SEM, which is often used to determine their exterior assembly. Further, the results of Fourier transform infrared spectroscopy (FT-IR) indicated the formation of pure ZnO NPs with an absorption peak of the Zn–O bond between 4000 cm−1 and 500 cm−1 and no discernible peak in the monitoring range. The UV–Vis spectrum of the green synthesized ZnO NPs were revealed two prominent absorption peaks at 355 nm and 370 nm with energy band gap of 2.986 eV. Using the 1, 1-di phenyl-2-picrylhydrazyl (DPPH) test, the antioxidant activity of the described ZnO NPs was assessed. It demonstrated how, ZnO NPs significantly increased their antioxidant activity by scavenging 1, 1-di phenyl-2-picrylhydrazyl (DPPH) free radicals. It could be seen that synthesis of the naturally occurring plant product ZnO NPs have been acting as an alternate of chemical antioxidant. The antimicrobial analysis was also performed with the help of disk diffusion method where three multi-drug resistant human pathogens namely Staphylococcus aureus, Klebsiella pneumoniae and E.coli were used. The Zone of Inhibition diameter values are 35.2 mm ± 0.9, 23.6 mm ± 0.1 and 13.5 mm ± 0.1, respectively, which showed that the ZnO NPs was highly effective against S. aureus. Thus, the green synthesis method of ZnO NPs using leaf extract of Calendula officinalis is evidence that it is superior and environmentally friendly method for the preparation of ZnO NPs and hence it can be utilized in various nano-medicine approaches.
Pyrolysis assessment of palm kernel shell waste valorization to sulfonated magnetic biochar from techno-economic and energy perspectives
Authors: Seow Yee Xuan , Tan Yie Hua , Kansedo Jibrail , Tan Inn Shi , Chin Bridgid Lai Fui , Mubarak Nabisab Mujawar , Mohiddin Mohd Nurfirdaus Bin , Yek Peter Nai Yuh , Chan Yen San , Abdullah Mohammad Omar 
Published: July 2024

AbstractMost agricultural activities generate a significant quantity of biomass waste that has not been fully utilized. This study utilized palm kernel shells as the primary material to produce sulfonated magnetic palm kernel shell biochar. The post-sulfonation magnetic palm kernel shell biochar had a greater particle size of around 137 nm compared to the pre-sulfonation biochar. This increase in size can be attributed to the presence of the − SO3H group. The biochar that underwent post-sulfonation was chosen for a techno-economic evaluation to ascertain its viability in terms of economics and energy efficiency. Soybean straw and coconut shell-derived biochar were chosen for the techno-economic assessment. The energy intake for soybean straws, coconut shells, and palm kernel shells derived from biochar is 48.85 MJ∙kg−1, 23.83 MJ∙kg−1, and 52.44 MJ∙kg−1, respectively. The energy output for soybean straws, coconut shells, and palm kernel shells derived biochar is determined to be 22.54 MJ∙kg−1, 23.68 MJ∙kg−1, and 31.55 MJ∙kg−1, respectively. The ultimate profit-to-cost ratios of soybean straws, coconut shells, and palm kernel shells derived biochar are 0.21, 4.92, and 1.11, respectively. The techno-economic assessment indicates that coconut shell-derived biochar production is favourable, primarily due to its attributes of low net energy balance, high porosity, and lower density. Both coconut shells and palm kernel shells derived biochar productions are economically viable and efficient due to their high profit-to-cost ratio. The microwave-assisted technology is proven efficient and demands less energy to generate an equivalent quantity of biochar compared to traditional furnaces.
Stable-isotope probing combined with amplicon sequencing and metagenomics identifies key bacterial benzene degraders under microaerobic conditions
Authors: Táncsics András , Bedics Anna , Banerjee Sinchan , Soares André , Baka Erzsébet , Probst Alexander J. , Kriszt Balázs 
Published: July 2024

AbstractThe primary aim of the present study was to reveal the major differences between benzene-degrading bacterial communities evolve under aerobic versus microaerobic conditions and to reveal the diversity of those bacteria, which can relatively quickly degrade benzene even under microaerobic conditions. For this, parallel aerobic and microaerobic microcosms were set up by using groundwater sediment of a BTEX-contaminated site and 13C labelled benzene. The evolved total bacterial communities were first investigated by 16S rRNA gene Illumina amplicon sequencing, followed by a density gradient fractionation of DNA and a separate investigation of “heavy” and “light” DNA fractions. Results shed light on the fact that the availability of oxygen strongly determined the structure of the degrading bacterial communities. While members of the genus Pseudomonas were overwhelmingly dominant under clear aerobic conditions, they were almost completely replaced by members of genera Malikia and Azovibrio in the microaerobic microcosms. Investigation of the density resolved DNA fractions further confirmed the key role of these two latter genera in the microaerobic degradation of benzene. Moreover, analysis of a previously acquired metagenome-assembled Azovibrio genome suggested that benzene was degraded through the meta-cleavage pathway by this bacterium, with the help of a subfamily I.2.I-type catechol 2,3-dioxygenase. Overall, results of the present study implicate that under limited oxygen availability, some potentially microaerophilic bacteria play crucial role in the aerobic degradation of aromatic hydrocarbons.
Hyperspectral Image Analysis Using Cloud-Based Support Vector Machines
Authors: Haut Juan M. , Franco-Valiente Jose M. , Paoletti Mercedes E. , Moreno-Álvarez Sergio , Pardo-Diaz Alfonso 
Published: July 2024

AbstractHyperspectral image processing techniques involve time-consuming calculations due to the large volume and complexity of the data. Indeed, hyperspectral scenes contain a wealth of spatial and spectral information thanks to the hundreds of narrow and continuous bands collected across the electromagnetic spectrum. Predictive models, particularly supervised machine learning classifiers, take advantage of this information to predict the pixel categories of images through a training set of real observations. Most notably, the Support Vector Machine (SVM) has demonstrate impressive accuracy results for image classification. Notwithstanding the performance offered by SVMs, dealing with such a large volume of data is computationally challenging. In this paper, a scalable and high-performance cloud-based approach for distributed training of SVM is proposed. The proposal address the overwhelming amount of remote sensing (RS) data information through a parallel training allocation. The implementation is performed over a memory-efficient Apache Spark distributed environment. Experiments are performed on a benchmark of real hyperspectral scenes to show the robustness of the proposal. Obtained results demonstrate efficient classification whilst optimising data processing in terms of training times.
Association between underweight status or low body mass index and the risk of developing superior mesenteric artery syndrome following scoliosis corrective surgery in pediatric patients: a review of the literature
Authors: Lamport Lyssa , DiMauro Jon-Paul , Johnson Stephani , Roberts Susan , Ziegler Jane 
Published: July 2024

AbstractSuperior mesenteric artery (SMA) syndrome is the compression of the third portion of the duodenum between the abdominal aorta and the superior mesenteric artery. Although multifactorial, the most frequent cause of SMA syndrome is significant weight loss and cachexia often induced by catabolic stress. SMA syndrome resulting from scoliosis surgery is caused by a reduction of the aortomesenteric angle and distance. Risk factors include rapid weight loss, malnutrition, and a rapid reduction in the mesenteric fat pad and are the most common causes of a decrease in the aortomesenteric angle and distance. Surgically lengthening the vertebral column can also lead to a reduction of the aortomesenteric distance, therefore, has been identified as a risk factor unique to spinal surgery. Despite a reported decline in SMA syndrome cases due to improved surgical techniques, duodenal compression is still a risk and remains a life-threatening complication of scoliosis surgery. This article is a cumulative review of the evidence of being underweight or having a low body mass index as risk factors for developing SMA syndrome following surgical scoliosis instrumentation and correction.
The influence of temperature and the magnetic field on Ni electrodeposition from citrate bath and its electrocatalytic performance towards hydrogen evolution reaction
Authors: Elsharkawy Safya , Kutyła Dawid , Boryczko Bożena , Żabiński Piotr 
Published: July 2024

AbstractThe demand for energy surpasses the available supply, leading to various economic, social, and environmental consequences. Hydrogen is one of the most clean and renewable source for energy. Therefore, the electrocatalytic hydrogen evolution reaction (HER) presents a promising eco-friendly approach for generating sustainable hydrogen energy. However, in alkaline conditions, HER encounters slow kinetics due to challenges associated with hydrogen adsorption and hydrolysis. In this article, thin Ni films were synthesized using the electrodeposition technique from citrate electrolyte. Their suitability as electrocatalysts for the hydrogen evolution reaction (HER) in a 1 M NaOH solution was estimated. This research investigates how the uniform magnetic field and temperature affect the process of nickel electrodeposition from a citrate bath and its subsequent influence on surface morphology and catalytic properties for the hydrogen evolution reaction (HER). Additionally, alterations in surface material wettability were examined based on changing the temperature during using the magnetic field for the electrodeposition process and shows how this effect on the catalytic performance towards HER. The outputs show that using the magnetic field for fabrication of Ni thin films at room temperature enhances the surface morphology and its catalytic performance for HER. However, the study reveals that using the temperature for Ni electrodeposition improves its catalytic performance independently of the magnetic field, whereas combining temperature with the magnetic field for Ni thin film fabrication diminishes their catalytic performance for the hydrogen evolution reaction (HER). The nickel thin film produced at 25 °C under the influence of a magnetic field, whether parallel or perpendicular, demonstrates the lowest overpotential of − 268 mV to achieve a current density of 10 mA cm−2. Additionally, it exhibits the smallest Tafel slope values of 106 mV dec−1 and 128 mV dec−1 for the parallel (Bǁ) and perpendicular (BꞱ) directions, respectively. However, the magnetic field effect diminishes at elevated temperatures. Nickel thin films prepared at 35 °C under the influence of perpendicular (BꞱ) and parallel (Bǁ) directions exhibit higher overpotential values of − 314 mV and − 322 mV, respectively.
Analysis of the Aquaponic System Sustainability via System Dynamics Modelling – FEW Nexus Approach
Authors: Francisco Erika Cristina , Freato Thiago Archangelo , Piolli Alessandro Luis , Poz Maria Ester Soares Dal 
Published: July 2024

AbstractAquaponic systems integrate aquaculture and hydroponics, recycling nutrient-enriched water from fish tanks to grow plants, significantly reducing carbon emissions, water use and production costs compared to other methods. It is considered a sustainable solution for food production, addressing issues such as climate change and eutrophication. Particularly valuable in family farming, it increases the diversity and quality of food, while reducing its environmental impact. However, despite its potential, aquaponics lacks recognition in public policies, making its widespread adoption difficult. Quantifying its benefits is crucial for strategic planning and the formulation of policies to support family farming and the transition to sustainability, in line with global objectives. Therefore, there is a need to comprehensively quantify the benefits of aquaponics, particularly in terms of the Food-Energy-Water (FEW) nexus, to support decision-making and policy formulation for sustainable agriculture. The nexus concept encompasses highly complex systems requiring robust tools capable of analysing the interrelationships between multiple components. Aiming to analyse the degree of sustainability of aquaponics systems on family property in the FEW nexus context, a System Dynamics Modelling (SDM) coupling Socio-economic and environmental indicators was developed. The results obtained demonstrated the efficiency of using SDM as an analysis and support tool for decision-making. Additionally, they prove the environmental viability of food production via aquaponic systems.
An overview of psychological factors in mobility choices: the impact on pro-environmental behavior
Authors: Pellegrini Marilina , Tagliabue Mariaelena 
Published: July 2024

AbstractDespite the current increased spread of modern mobility options in urban areas aimed at inducing changes in mobility choices, their integration into daily life remains sporadic, reducing their potential impact on the adoption of shared mobility services as a usual mode of transport. This paper provides a literature review of established models of psychological factors, including values, beliefs, and personal norms, particularly focused on pro-environmental behaviors influencing mobility choices and facilitating the adoption of more sustainable transportation habits, often supported by technological advancements. We started considering the recent increase in the complexity of cities and mobility needs, which induced policymakers to pay attention to the sustainability of people’s movements by promoting various kinds of shared mobility options. Then, we illustrated the most consolidated models of psychological factors linked to ecological behaviors, also summarizing the main results present in the literature regarding variables that influence mobility choices. The final goal was to highlight crucial aspects that should be considered to foster the effective use of new modes of transportation to help reduce the environmental impact caused by traffic.
Phosphorus removal by free water surface constructed wetlands for the wastewater treatment: bibliometric and bibliographic review
Authors: de Paula Renato Zimiani , Fontana Luciane , de Jesus Tatiane Araujo 
Published: July 2024

AbstractConstructed wetlands (CWs) are a widely used technology for the treatment of wastewater, with Free Water Surface Constructed Wetlands (FWS CWs) being the simplest configuration. However, there is currently no consensus on the Hydraulic Retention Time (HRT) that optimizes P removal efficiency. To address this issue, this study conducted a bibliometric review of 85 scientific articles published between 1997 and 2021 that investigated the relationship between P removal and the HRT in FWS CWs. Scientometric maps were constructed to identify key topics, and bibliometric surveys were used to refine and explore the relationship between P removal and HRT. The analysis found a high correlation between P removal and HRT across all scales of the FWS CW systems, ranging from moderate to very strong. Specifically, the regressions between P removal efficiency and HRT were 73%, 70%, and 67% for lab-scale, pilot-scale, and real-scale systems, respectively. Overall, the FWS CWs demonstrated strong P removal efficiency, with removal rates reaching 95%, making them a promising technology for the tertiary treatment of effluents with a focus on nutrient removal and recovery. Future studies that focus on the many parameters of CW, especially on how macrophytes management affects the nutrient removal performance of these systems, are necessary to enrich our knowledge of CWs and optimize the application of this technology to wastewater treatment.
Geospatial insights into groundwater contamination from urban and industrial effluents in Faisalabad
Authors: Quddoos Abdul , Muhmood Khalid , Naz Iram , Aslam Rana Waqar , Usman Syed Yasir 
Published: July 2024

AbstractGroundwater remains the most dependable resource for various essential uses such as drinking, cleansing, agricultural irrigation, and industrial applications. In urban areas, the dependency on groundwater to meet water demands is significant. However, this resource faces threats from overuse and poor management, leading to a degradation in quality primarily due to the unchecked release of industrial and household wastes. The escalation of industrial activities and rapid urban growth have amplified the volume of wastewater, adversely affecting the purity of freshwater sources within aquifers. This investigation focuses on evaluating the impact of industrial and urban effluents on groundwater quality in the city of Faisalabad. The main contributors to groundwater pollution include the indiscriminate disposal of industrial and urban effluents through unlined drains and the extensive application of chemical agents in agriculture, such as fertilizers, and pesticides. To understand the physiochemical properties of both, drain and groundwater, samples were collected at various distances 50 m, 100 m, and 150 m from drain outlets. This study utilized Geographic Information Systems (GIS) to accurately map and analyze the distribution and impact of contaminants. Parameters such as pH, electrical conductivity (EC), total dissolved solids (TDS), total hardness, bicarbonates, calcium and magnesium hardness, and chloride levels were examined. The findings indicated that contaminant levels were highest in drain water and increased in concentration the closer they were to the drainage sources, with the exception of pH levels. All samples exceeded the World Health Organization's (WHO) safe limits, deeming them unfit for use. This finding indicates widespread contamination, posing significant public health risks and highlighting the urgent need for improved waste management and water treatment practices in Faisalabad. It underscores the critical importance of implementing effective pollution control measures to safeguard public health and ensure water security in the region. However, a notable correlation was observed between the concentration of pollutants in drain water and key indicators such as EC, TDS, total hardness, and magnesium hardness, highlighting their role in deteriorating aquifer water quality. Moreover, groundwater samples collected 50 m from drains exhibited the highest pollutant concentrations compared to those taken further away, at 100 m and 150 m distances.
Implementing Australia’s first national cancer control plan to shape Australian cancer control policy for the next decade and beyond
Authors: Chaji Daniel , Malloy Lisa , Meredyth David , Milch Vivienne , Toms Cindy , Howlett Claire , Keefe Dorothy 
Published: July 2024

AbstractCancer outcomes in Australia are among the best in the world, but this is not the story for all Australians, with significant disparities in cancer outcomes and experiences among specific groups in Australian society. The Australian Government developed the Australian Cancer Plan (the Plan) as a national approach to improve cancer outcomes and experience for all. The Plan identifies six strategic objectives that require nationally coordinated effort, to achieve the Plan’s vision of world class cancer outcomes and experience for all Australians affected by cancer. The Plan emphasises person-centred approaches to cancer care, underpinned by a Health Equity in Cancer Outcomes Framework. As the Australian Government’s national cancer control agency, Cancer Australia is driving the Plan’s reform agenda through five implementation policy priorities: the development and establishment of an Australian Comprehensive Cancer Network; the development of a National Optimal Care Pathways Framework; the development of a National Comprehensive Cancer Data Framework and minimum dataset; the development of a National Genomics in Cancer Control Framework; and initiatives to improve cancer outcomes for Aboriginal and Torres Strait Islander people. These priorities will lay the foundation to deliver an integrated, accessible, and equitable cancer control system to deliver the Plan’s vision over the next decade.
The Prevalence of Mycobacterium Tuberculosis Infection in Saudi Arabia: A Systematic Review and Meta-analysis
Authors: Said Badria , Mohamed Amal H. , Eltyeb Ebtihal , Eltayeb Raga , Abdalghani Nagla , Siddig Bahja , Ahmed Amel Eltahir Banaga , Balla Eltom Ali Anwar , Alhazmi Abdulaziz H. 
Published: July 2024

AbstractThe prevalence of Tuberculosis (TB) serves as a pivotal metric, reflecting the TB burden within a specific demographic. It quantifies the number of individuals affected by either active TB disease or latent TB (LTBI). Such data is crucial for assessing the efficacy of TB control interventions and determining the demand for diagnostic and treatment services. This study aims to consolidate data on TB infection prevalence in Saudi Arabia from existing literature. Additionally, we stratify this prevalence based on age, professional involvement in healthcare, gender, and region. Our search was conducted in PubMed, Scopus, Cochrane Library, and Web of Science databases to determine relevant studies. The pooled prevalence of TB infection among the total population residing in Saudi Arabia was estimated using a random-effect meta-analysis approach and Comprehensive Meta-Analysis software. The protocol was registered in the PROSPERO International Prospective Register of Systematic Reviews, No: CRD42023400984. We included 21 studies, 11 of which were pooled in the analysis. The overall prevalence was 17%.Regarding the specific population, we found that the prevalence of TB in Saudi Arabia was 9.8% and 26.7% in the general population and the healthcare workers, respectively. Stratifying by age, the highest prevalence was observed in individuals over 50 years (33.0%), while the lowest was in the 10–19 age group (6.4%). In terms of gender, men had a higher prevalence (12.0%) compared to women (9.4%). The prevalence of TB in Riyadh was 6.4%, and 3.6% in Mecca and Medina. Among healthcare workers, nurses and physicians had a prevalence of 14.7% and 15.0%, respectively. Our study found a TB prevalence of 17.0% in Saudi Arabia, higher than the worldwide average of 12.0%. Men had a higher prevalence than women, and healthcare workers had a relatively low prevalence compared to other countries. Age was a significant risk factor, with the highest prevalence in individuals above 50 years. Standardized protocols for screening and diagnosis and targeted interventions are needed to combat TB effectively in the country.