bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: The First Example for the Asymmetric Synthesis of Allenes by the Doering—LaFlamme Allene Synthesis with Enantiopure Cyclopropylmagnesium Carbenoids.
Authors: Momochi Hitoshi , Noguchi Takafumi , Miyagawa Toshifumi , Ogawa Naoki , Tadokoro Makoto , Satoh Tsuyoshi 
Published: November 2012

AbstractThe three‐step approach to the allenes involves reaction of α,β‐unsaturated carbonyl compounds with optically active sulfoxide (II) followed by reduction to give cyclopropane derivatives.
ChemInform Abstract: Copper‐Free Defluorinative Alkylation of Allylic Difluorides Through Lewis Acid‐Mediated C—F Bond Activation.
Authors: Yanai Hikaru , Okada Haruna , Sato Azusa , Okada Midori , Taguchi Takeo 
Published: November 2012

AbstractIt is discovered that the reaction of trialkylaluminums with difluorohomoallyl alcohols proceeds in the absence of Cu‐catalysts when dichloromethane is used as the solvent.
ChemInform Abstract: Base‐Catalyzed, Three‐Component Coupling of Aldehydes, Terminal Aryl Acetylenes, and Amines: Application to Synthesis of Propargylamines.
Authors: Patil Sachin S. , Patil Sachin V. , Bobade Vivek D. 
Published: November 2012

AbstractTetrabutylammonium hydroxide is reported as a useful promoter for the reaction of aldehydes, which can be carried out without a transition metal catalyst.
ChemInform Abstract: Enantioselective Copper‐Catalyzed Propargylic Substitution: Synthetic Scope Study and Application in Formal Total Syntheses of (+)‐Anisomycin and (‐)‐Cytoxazone.
Authors: Detz Remko J. , Abiri Zohar , le Griel Remi , Hiemstra Henk , van Maarseveen Jan H. 
Published: November 2012

AbstractA variety of propargylic esters is converted into the amine counterparts by reaction with primary or secondary amines in the presence of a Cu(I)/chiral pyridine bisoxazoline catalyst.
ChemInform Abstract: Silica Chloride Nano Particle Catalyzed Ring Opening of Epoxides by Aromatic Amines.
Authors: Karimian Ramin , Piri Farideh , Karimi Babak , Moghimi Abolghasem 
Published: November 2012

AbstractDepending on the oxirane products of type (III) or regioisomers of type (VII) are obtained.
ChemInform Abstract: Fluorous Tagging of DABCO Through Halogen Bonding: Recyclable Catalyst for the Morita—Baylis—Hillman Reaction.
Authors: Dordonne Sophie , Crousse Benoit , Bonnet‐Delpon Daniele , Legros Julien 
Published: November 2012

AbstractThe halogen‐bonded adduct between DABCO and two molecules of perfluorooctyl iodide efficiently promotes the Morita—Baylis—Hillmann reaction under mild conditions.
ChemInform Abstract: A PEG1000‐DAIL[CdCl3]‐Toluene Temperature‐Dependent Biphasic System that Regulates Homogeneously Catalyzed C—O Coupling of Organic Halides with Phenols and Alcohols under Ligand‐Free Conditions.
Authors: Hu Yu Lin , Ma Xiao Yun , Lu Ming 
Published: November 2012

AbstractThe product can be easily separated by decantation and the catalytic system can be recycled and reused without loss of catalytic activity.
ChemInform Abstract: Aerobic Oxidation of Secondary Benzylic Alcohols and Direct Oxidative Amidation of Aryl Aldehydes Promoted by Sodium Hydride.
Authors: Wang Xinbo , Wang David Zhigang 
Published: November 2012

AbstractOxidation of (het)aromatic secondary alcohols (I) and (IV) proceeds smoothly under the action of air/oxygen and NaH to give the corresponding ketones (II) and (V), respectively.
ChemInform Abstract: Comprehensive and Facile Entry into Substituted Amidines via the Condensation of N‐Pmc‐Substituted Thioamides with Amines Using Mukaiyama Reagent as a Thiophile.
Authors: Flemer Stevenson , Madalengoitia Jose S. 
Published: November 2012

AbstractA novel methodology for the synthesis of substituted amides is presented using The condensation step can be followed by removal of the protecting group i the presence of formic acid or TFA.
ChemInform Abstract: Efficient Dehydration of Aldoximes to Nitriles Catalyzed by a Lewis Acid Ionic Liquid.
Authors: Nakajima Mizuki , Qiao Kun , Kobayashi Nobuhisa , Bao Quanxi , Tomida Daisuke , Yokoyama Chiaki 
Published: November 2012

AbstractAn ionic liquid with Lewis acid sites in anion and cation is synthesized and shown to be an effective catalyst for the conversion of aliphatic and aromatic aldoximes (I) into the corresponding nitriles (II).
ChemInform Abstract: Oxidation of Disulfides with Selectfluor: Concise Syntheses of Thiosulfonates and Sulfonyl Fluorides.
Authors: Kirihara Masayuki , Naito Sayuri , Ishizuka Yuki , Hanai Honoka , Noguchi Takuya 
Published: November 2012

AbstractThe oxidation of disulfides (I) with Selectfluor in the presence of water produces the corresponding thiosulfonates (III), which further react with Selectfluor and water to provide sulfonyl fluorides (II).
ChemInform Abstract: Green and Practical Synthesis of Carbamates from Ureas and Organic Carbonates.
Authors: Guo Xiaoguang , Shan Jianpeng , Li Jian , Wang Liguo , Ma Yubo , Shi Feng , Deng Youquan 
Published: November 2012

AbstractA facile synthesis of carbamates (III) (14 examples) from ureas and organic carbonates using La2O3—SiO2 as catalyst is developed.
ChemInform Abstract: Magnetically Recoverable Pd/Fe3O4‐Catalyzed Hiyama Cross‐Coupling of Aryl Bromides with Aryl Siloxanes.
Authors: Sreedhar B. , Kumar A. Suresh , Yada Divya 
Published: November 2012

AbstractThe simple procedure in the presence of a magnetically recoverable catalyst allows the synthesis of biaryls via fluoride‐free aqueous cross‐coupling.
ChemInform Abstract: Synthesis of Biaryl Derivatives by Using Ruthenium‐Mediated [2 + 2 + 2] Cyclotrimerization and Suzuki—Miyaura Cross‐Coupling as Key Steps.
Authors: Kotha Sambasivarao , Seema Vittal , Mobin Shaikh M. 
Published: November 2012

AbstractThe title reaction produces m‐terphenyls of type (III).
ChemInform Abstract: Conjugated Polymer Stabilized Palladium Nanoparticles as a Versatile Catalyst for Suzuki Cross‐Coupling Reactions for Both Aryl and Heteroaryl Bromide Systems.
Authors: Islam Rafique Ul , Witcomb Michael J. , Scurrell Michael S. , van der Lingen Elma , Van Otterlo Willem , Mallick Kaushik 
Published: November 2012

AbstractThe preparation of a palladium‐polymer hydride material in which the metal nanoparticles are stabilized in a polymer matrix is described.
ChemInform Abstract: An Efficient and Convenient Protocol for the Synthesis of Diaminotriarylmethanes
Authors: Hou Jun‐Tao , Gao Jian‐Wu , Zhang Zhan‐Hui 
Published: November 2012

Abstractvia NbCl5‐catalyzed Bayer condensation of aromatic aldehydes and N,N‐dialkylaniline under solvent‐free conditions
ChemInform Abstract: Synthesis of Some New 1,4‐Distyrylbenzenes Using Immobilized Palladium Nanoparticles on Silica Functionalized Morpholine as a Recyclable Catalyst.
Authors: Niknam Khodabakhsh , Gharavi Alireza , Nezhad M. Reza Hormozi , Panahi Farhad , Sharbati Mohammad Taghi 
Published: November 2012

AbstractA new recyclable catalyst is utilized to promote the double Heck reaction of 1,4‐dihalobenzenes.
ChemInform Abstract: Chiral Squaramide‐Catalyzed Highly Enantioselective Michael Addition of 2‐Hydroxy‐1,4‐naphthoquinones to Nitroalkenes.
Authors: Yang Wen , Du Da‐Ming 
Published: November 2012

AbstractThe chiral squaramide allows formation of a wide range of functionalized naphthoquinones in high yields and excellent enantioselectivity.
ChemInform Abstract: Synthesis of Benzocycloheptanones Through Coupling of δ,ε‐Unsaturated Chromium Carbene Complexes and 2‐Alkynylbenzoyl Derivatives.
Authors: Patti Rajesh Kumar , Waynant Kristopher V. , Herndon James W. 
Published: November 2012

AbstractThe open‐chain Fischer carbenes (II) are suitable substrates for the construction of various title compounds where the seven‐membered ring and one of the benzene rings are formed in a single step.
ChemInform Abstract: Preparation of Functional Benzofurans, Benzothiophenes, and Indoles Using Ester, Thioester, and Amide via Intramolecular Wittig Reactions.
Authors: Syu Siang‐en , Lee Yu‐Ting , Jang Yeong‐Jiunn , Lin Wenwei 
Published: November 2012

AbstractThe synthesis starts directly from salicylic aldehyde derivatives and succeeds in a one‐pot procedure with comparable yields.
ChemInform Abstract: Synthesis of 1,2,5‐ and 1,2,3,5‐Substituted Pyrroles from Substituted Aziridines via Ag(I)‐Catalyzed Intramolecular Cyclization.
Authors: Kim Jun Hee , Lee Sang Bin , Lee Won Koo , Yoon Doo‐Ha , Ha Hyun‐Joon 
Published: November 2012

AbstractSequential ring opening of propargylic aziridines (I) and (IV) with acetic acid and Ag(I)‐catalyzed nucleophilic recyclization provides a novel access towards hydroxymethylpyrrole derivatives (II) and (V), resp., in moderate to good yields.
ChemInform Abstract: Enantioselective Pd(II)‐Catalyzed Aerobic Oxidative Amidation of Alkenes and Insights into the Role of Electronic Asymmetry in Pyridine‐Oxazoline Ligands.
Authors: McDonald Richard I. , White Paul B. , Weinstein Adam B. , Tam Chun Pong , Stahl Shannon S. 
Published: November 2012

AbstractBoth diastereomers can be obtained stereoselectively starting from chiral substrates and using the enantiomeric catalysts (I).
ChemInform Abstract: Unexpected Formation of (Z)‐3‐(Halomethylene)isoindolinones from gem‐Dihalovinylbenzonitriles: Efficient Synthesis of Enyne‐Containing Isoindolinones.
Authors: Wang Chengming , Sun Caiyun , Weng Fei , Gao Mingchun , Liu Bingxin , Xu Bin 
Published: November 2012

AbstractDirect treatment of substrates of type (I) with hydrogen peroxide and aqueous NaOH in EtOH is known to produce ortho‐gem‐dihalovinylbenzamides.
ChemInform Abstract: Reaction of Arynes with Amino Acid Esters.
Authors: Okuma Kentaro , Matsunaga Nahoko , Nagahora Noriyoshi , Shioji Kosei , Yokomori Yoshinobu 
Published: November 2012

AbstractSeveral racemic indolinones (V) are obtained by reaction of amino acid esters (IV) with in situ generated benzyne.
ChemInform Abstract: ZrCl4‐Mediated Regio‐ and Chemoselective Friedel—Crafts Acylation of Indole.
Authors: Guchhait Sankar K. , Kashyap Maneesh , Kamble Harshad 
Published: November 2012

AbstractIt is found that ZrCl4 efficiently promotes regio‐ and chemoselective acylation of indoles yielding a wide range of 3‐acylindoles.
ChemInform Abstract: Synthesis of the New Ring System Pyrrolizino[2,3‐b]indol‐4(5H)‐one.
Authors: Diana Patrizia , Stagno Antonina , Barraja Paola , Montalbano Alessandra , Carbone Anna , Parrino Barbara , Cirrincione Girolamo 
Published: November 2012

AbstractA variety of pyrrolizinoindolones (VIII) is synthesized as demonstrated for derivative (VIIIa).
ChemInform Abstract: Highly Selective Synthesis of Pyrazole and Spiropyrazoline Phosphonates via Base‐Assisted Reaction of the Bestmann—Ohira Reagent with Enones.
Authors: Verma Deepti , Mobin Shaikh , Namboothiri Irishi N. N. 
Published: November 2012

AbstractA number of new, biologically important pyrazole phosphonates is prepared.
ChemInform Abstract: An E‐Factor Minimized Solvent‐Free Protocol for the Preparation of 4,5‐Dihydro‐5‐(trifluoromethyl)‐1H‐pyrazoles.
Authors: Buriol Lilian , Frizzo Clarissa P. , Moreira Dayse N. , Prola Lizie D. T. , Marzari Mara R. B. , Muenchen Taiana S. , Zantta Nilo , Bonacorso Helio G. , Martins Marcos A. P. 
Published: November 2012

AbstractA series of fluorine‐containing 4,5‐dihydro‐1H‐pyrazoles (III) are obtained in a efficient and green synthesis using microwave irradiation and solvent‐free conditions.
ChemInform Abstract: Diversity‐Oriented Silver(I)‐Mediated Synthesis of Spiro‐2‐aminoimidazoles.
Authors: Pereshivko Olga P. , Peshkov Vsevolod A. , Ermolat'ev Denis S. , Van Hove Sofie , Van Hecke Kristof , Van Meervelt Luc , Van der Eycken Erik V. 
Published: November 2012

AbstractA series of variously substituted title compounds is synthesized starting with a three‐component coupling of ketones, aromatic amines, and terminal alkynes followed by a Ag(I)‐mediated tandem guanylation/intermolecular cyclization.
ChemInform Abstract: Potassium Hydroxide/Dimethyl Sulfoxide Promoted Intramolecular Cyclization for the Synthesis of Benzimidazol‐2‐ones.
Authors: Beyer Astrid , Reucher Christine M. M. , Bolm Carsten 
Published: November 2012

AbstractThe direct conversion of phenyl urea (IIIa) to (IVa) is not successful.
ChemInform Abstract: An Efficient One‐Pot Synthesis of Isoxazolyl Polyhydroquinolines via Hantzsch Condensation Using L‐Proline as Catalyst.
Authors: Rajanarendar E. , Reddy M. Nagi , Raju S. 
Published: November 2012

AbstractFor the first time L‐proline is used to promote a four component Hantzsch synthesis.
ChemInform Abstract: Red Fluorescent 4‐(Dicyanomethylene)‐2‐norbornenyl‐6‐ (1,1,7,7‐tetramethyljulolidyl‐9‐enyl)‐4H‐pyran (DCJNB) for Organic Light‐Emitting Diodes (OLEDs).
Authors: Lee Kum Hee , Kim Young Kwan , Yoon Seung Soo 
Published: November 2012

Abstractdesign and synthesis of the new red emitter DCJNB (III)
ChemInform Abstract: Intramolecular Alkene Carboamination Reactions for the Synthesis of Enantiomerically Enriched Tropane Derivatives.
Authors: Schultz Danielle M. , Wolfe John P. 
Published: November 2012

AbstractThe attempt to transform noncyclic alkenyl substrates into tropane derivatives fails.The method proceeds generally without racemization and can be applied to the preparation of the MK‐801 analogue (XIII) in optically active form.
ChemInform Abstract: Copper(II)‐Catalyzed Synthesis of Pyrimidines from Propargylic Alcohols and Amidine: A Propargylation—Cyclization—Oxidation Tandem Reaction.
Authors: Lin Min , Chen Qing‐zhen , Zhu Yu , Chen Xin‐liang , Cai Ji‐jun , Pan Ying‐ming , Zhan Zhuang‐ping 
Published: November 2012

AbstractThe reaction offers a novel approach towards the synthesis of 2,4‐disubstituted and 2,4,6‐trisubstituted title compounds from aromatic propargyl alcohols.
ChemInform Abstract: Convergent Domino Knoevenagel Hetero‐Diels—Alder and Domino Oxidation Hetero‐Diels—Alder Reactions Encountered in an Unexpected Formation of Novel 5‐Aryl‐1H‐pyrano[2,3‐d]pyrimidine‐2,4(3H,5H)‐diones and 5‐Aryl‐2,3‐dihydro‐2‐thioxo‐1H‐pyrano[2,3‐d]pyrimidin‐4(5H)‐ones.
Authors: Zidar Nace , Kikelj Danijel 
Published: November 2012

AbstractThe reaction can also be conducted under microwave conditions, resulting in shortened reaction times and apart from a few examples lower yields.
ChemInform Abstract: Synthesis and Biological Activity of Novel Barbituric and Thiobarbituric Acid Derivatives Against Non‐Alcoholic Fatty Liver Disease.
Authors: Chen Lijuan , et al. et al. 
Published: November 2012

AbstractThe title compounds (III) (44 examples) are evaluated for their effects on adipogenesis of 3T3‐L1 adipocytes by measuring the expression of adiponectin in vitro.
ChemInform Abstract: Vitamin B1 as a Metal‐Ion‐Free Natural Catalyst for Sustainable Quinoxaline Ring Condensation under Sonochemical Conditions.
Authors: Aghapoor Kioumars , Mohsenzadeh Farshid , Talebian Shiva , Tehrani Mohammad Jafar , Balavar Yadollah , Khanalizadeh Golriz , Darabi Hossein Reza 
Published: November 2012

AbstractA mild, efficient, and environmentally benign method for the synthesis of quinoxaline derivatives (III) using vitamin B1 as catalyst is described.
ChemInform Abstract: Preparation of 2‐Fluoro‐3‐aminophenylboronates via Directed ortho‐Metalation.
Authors: Zhichkin Paul E. , Krasutsky Sergiy G. , Beer Catherine M. , Rennells W. Martin , Lee Seung H. , Xiong Jin‐Ming 
Published: November 2012

AbstractN,N‐Diprotected anilines of type (III) undergo lithiation ortho to the fluorine substituent upon treatment with lithium tetramethylpiperidine.
ChemInform Abstract: Acid‐Catalyzed Reactions of 3‐(Naphthalen‐2‐yl)‐2,2‐bis(trimethylsilyl)oxiran. A New Synthesis of Functional‐Group‐Substituted Vinylsilanes.
Authors: Safa Kazem D. , Behmagham Farnaz , Ghorbanpour Khatereh 
Published: November 2012

AbstractLewis acid‐mediated reaction of title oxirane (I) with various nucleophiles proceeds with regioselective oxirane ring opening at the position α to the trimethylsilyl groups to give α‐functionalized β‐naphthalenylvinylsilanes, e.g. (IV)/(V), (VII) or (IX).
ChemInform Abstract: Multicomponent Reactions in a One‐Pot Synthesis of α‐Aminophosphonates and α‐Aminophosphonic Diamides with Antiinflammatory Properties.
Authors: Abdou Wafaa M. , Barghash Reham F. , Bekheit Mohamed S. 
Published: November 2012

AbstractSome of the new title compounds show considerable antiinflammatory properties.
ChemInform Abstract: Indium Triflate‐Catalyzed Coupling of Indoles with Acyl Phosphonates: Synthesis of Bis(indolyl)methane Phosphonates.
Authors: Dasbasi Teslima , Polat‐Cakir Sidika , Abdullah Meysun , Demir Ayhan S. 
Published: November 2012

AbstractIndium‐catalyzed coupling of acylphosphonates (I) with N‐methylindole (II) provides access to bis(indolyl)methane phosphonates (III) in good yields.
ChemInform Abstract: Three New Highly Acylated 3,4‐seco‐Grayanane Diterpenoids from the Fruits of Pieris formosa
Authors: Wu Zhao‐Yuan , Li Yuan‐Dan , Wu Gui‐Sheng , Luo Huai‐Rong , Li Hong‐Mei , Li Rong‐Tao 
Published: November 2012

Abstractstructure determination and biological activities of pierisformotoxins E‐G
ChemInform Abstract: A Synthesis of 2‐epi‐Fagomine Using Gold(I)‐Catalyzed Allene Cyclization.
Authors: Bates Roderick W. , Ng Pearly Shuyi 
Published: November 2012

AbstractA highly stereoselective Au(I)‐catalyzed cyclization of allene (IV) is the key step in the synthesis of 2‐epi‐fagomine (VI).
ChemInform Abstract: Trigonoines A and B, Two Novel Alkaloids from the Leaves of Trigonostemon lii.
Authors: Li Shi‐Fei , Di Ying‐Tong , He Hong‐Ping , Zhang Yu , Wang Yue‐Hu , Yin Jun‐Lin , Tan Cheng‐Jian , Li Shun‐Lin , Hao Xiao‐Jiang 
Published: November 2012

AbstractTrigonoines A (I) and B (II) do not show anti‐HBV activity but weak anti‐HIV activity.
ChemInform Abstract: The Synthesis of the 8‐C‐Substituted 2,6‐Diamino‐9‐[2‐(phosphonomethoxy)ethyl]purine (PMEDAP) Derivatives by Diverse Cross‐Coupling Reactions.
Authors: Sedlacek Ondrej , Brehova Petra , Pohl Radek , Holy Antonin , Janeba Zlatko 
Published: November 2012

AbstractVarious cross‐coupling reactions of purine derivative (I) with diverse types of organometallic reagents are employed for the preparation of a series of 8‐substituted purines.
ChemInform Abstract: An Economical Synthesis of D‐ and L‐Pyrimidine Arabino‐ and Ribonucleosides.
Authors: Lazrek Hassan B. , Ouzebla Driss , Faraj Abdesslem 
Published: November 2012

AbstractNatural phosphate doped with KI serves as an inexpensive and environmentally benign catalyst to mediate the stereoselective N‐glycosylation of nucleobases (I) with protected ribose or arabinose.
ChemInform Abstract: Asymmetric Synthesis of (‐)‐Chicanine Using a Highly Regioselective Intramolecular Mitsunobu Reaction and Revision of Its Absolute Configuration.
Authors: Harada Kenichi , Horiuchi Hiroki , Tanabe Kazuma , Carter Rich G. , Esumi Tomoyuki , Kubo Miwa , Hioki Hideaki , Fukuyama Yoshiyasu 
Published: November 2012

AbstractThe synthetic studies reveal that the structure proposed for (‐)‐chicanine is in fact that of its antipode (+)‐chicanine, whereas the (‐)‐isomer is represented by structure (I).
ChemInform Abstract: Simplextones A (Ia) and B (Ib), Unusual Polyketides from the Marine Sponge Plakortis simplex.
Authors: Liu Xiang‐Fang , Song Yun‐Long , Zhang Hong‐Jun , Yang Fan , Yu Hao‐Bing , Jiao Wei‐Hua , Piao Shu‐Juan , Chen Wan‐Sheng , Lin Hou‐Wen 
Published: November 2012

AbstractPreliminary studies reveal moderate cytotoxicity.
ChemInform Abstract: (Sr1‐xBax)FeO2 (0.4 ≤ x ≤ 1): A New Oxygen‐Deficient Perovskite Structure.
Authors: Kageyama Hiroshi , et al. et al. 
Published: November 2012

AbstractThe new oxygen‐deficient perovskites of title are prepared by reaction of (Sr1‐xBax)FeO3‐δ (x = 0.4, 0.5, 0.6, 0.7, 0.8, 0.9; δ ≤ 0.5; obtained from stoichiometric mixtures of SrCO3, BaCO3, and Fe2O3 at 1473 K in air for 48 h) with an excess of CaH2 at 593 K for 3—14 d (0.4 ≤ x ≤ 0.9) and NaH at 413 K for 3 d (x = 1.0).
ChemInform Abstract: Large‐Scale Synthesis of High‐Quality Metal Sulfide Semiconductor Quantum Dots with Tunable Surface‐Plasmon Resonance Frequencies.
Authors: Kanehara Masayuki , Arakawa Hisamitsu , Honda Tetsuya , Saruyama Masaki , Teranishi Toshiharu 
Published: November 2012

AbstractHigh‐quality CdS and Cu7S4 quantum dots are synthesized from cadmium or copper stearate in oleylamine and di‐octyl ether using N,N‐dibutylthiourea as an organic sulfur source.
ChemInform Abstract: A Rapid Solvothermal Synthesis of Cerium Oxide Hollow Spheres and Characterization.
Authors: Devaraju Murukanahally Kempaiah , Liu Xiangwen , Yin Shu , Sato Tsugio 
Published: November 2012

AbstractCeO2 hollow spheres are solvothermally synthesized under subcritical conditions from Ce(NO3)3 dissolved in a mixture of water, iPrOH, and polyvinyl alcohol (PVA500#) as a surfactant (autoclave, 350 °C, 10 min).
ChemInform Abstract: Synthesis and Structure of Bismuth(III)‐Containing Noncentrosymmetric Phosphates, Cs3KBi2M4(PO4)6Cl (M: Mn, Fe). Monoclinic (Cc) and Tetragonal (P43) Polymorphs Templated by Chlorine‐Centered Cl(Bi2Cs) Acentric Units.
Authors: West J. Palmer , Sulejmanovic Dino , Hwu Shiou‐Jyh , He Jian , VanDerveer Don , Johnson B. Keith 
Published: November 2012

AbstractSingle crystals of α‐Cs3KBi2Mn4 (PO4)6Cl (I), β‐Cs3KBi2Mn4 (PO4)6Cl (II), and α‐Cs3KBi2Fe4 (PO4)6Cl (III) are synthesized in reactive CsCl/KCl molten‐salt media from Bi2O3, Mn2O3 (Fe2O3), and P4O10 in a molar ratio of 1:1:1 (I) or 2:1:1 (II) (800 °C, 4 d, 10—30% yield).
ChemInform Abstract: Synthesis and Crystal Structures of New Oxyapatites BiCa4‐xLax(VO4)3‐x (GeO4)xO, x = 1—3.
Authors: Zhuravlev V. D. , Tyutyunnik A. P. , Zubkov V. G. , Perelyaeva L. A. , Baklanova I. V. , Blinova A. L. 
Published: November 2012

AbstractThe new compounds BiCa3La(VO4)2(GeO4)O, BiCa2La2(VO4) (GeO4)2O, and BiCaLa3(GeO4)3O are synthesized by the nitrate—citrate method and characterized by powder XRD, IR, and Raman spectroscopy.
ChemInform Abstract: Structure and Magnetic Ordering of the Anomalous Layered (2D) Ferrimagnet [NEt4]2MnII3(CN)8 and 3D Bridged‐Layered Antiferromagnet [NEt4]MnII3(CN)7 Prussian Blue Analogues.
Authors: Kareis Christopher M. , Her Jae‐Hyuk , Stephens Peter W. , Moore Joshua G. , Miller Joel S. 
Published: November 2012

AbstractCompounds (II) and [NEt4][Mn3(CN)8]·0.5H2O (III) are characterized by powder XRD and magnetic measurements.
ChemInform Abstract: Ru—BINAP‐Catalyzed Asymmetric Hydrogenation of Keto Esters in High Pressure Carbon Dioxide.
Authors: Turova Olga V. , Kuchurov Ilya V. , Starodubtseva Eugenia V. , Ferapontov Vladimir A. , Ikonnikov Nikolai S. , Zlotin Sergei G. , Vinogradov Maxim G. 
Published: November 2012

AbstractAn efficient, environmentally friendly method for the asymmetric hydrogenation of 4‐chloro‐3‐oxobutyrate (I) and acetylsuccinate (III) in CO2‐expanded ionic liquids is developed.
ChemInform Abstract: Superacid‐Catalyzed Friedel—Crafts Cyclization of Unactivated Alkenes.
Authors: Bonderoff Sara A. , West F. G. , Tremblay Martin 
Published: November 2012

AbstractThe reactions are catalyzed by trifluoromethane sulfonimides to afford 5‐ to 7‐membered cyclic systems.
ChemInform Abstract: Effect of Catalytic Alkali Metal Bromide on Hofmann‐Type Rearrangement of Imides.
Authors: Moriyama Katsuhiko , Ishida Kazuma , Togo Hideo 
Published: November 2012

AbstractA Hofmann‐type rearrangement of cyclic imides (I), (V), (VII), (X) and (XIII) via the oxidation of an alkali metal bromide is reported.
ChemInform Abstract: Calcium Amidoborane, a New Reagent for Chemoselective Reduction of α,β‐Unsaturated Aldehydes and Ketones to Allylic Alcohols.
Authors: Xu Weiliang , Wang Ruimin , Wu Guotao , Chen Ping 
Published: November 2012

AbstractCalcium amidoborane (CaAB) is shown to reduce α,β‐unsaturated aldehydes and ketones chemoselectivily to the corresponding allylic alcohols at room temperature.
ChemInform Abstract: The Phosphate—Carboxylate Mixed‐Anhydride Method: A Mild, Efficient Process for Ester and Amide Bond Construction.
Authors: McNulty James , Vemula Ramesh , Krishnamoorthy Venkatesan , Robertson Al 
Published: November 2012

AbstractThe value of the present method for preparation of ester‐ and amide‐based chiral auxiliaries is demonstrated.