bluuebunny/crossref_metadata_2025_split huggingface dataset:
Acid Mine Drainage from Gold Mining in South Africa: Remediation, Reuse, and Resource Recovery
Authors: Baloyi Jeffrey , Ramdhani Nishani , Mbhele Ryneth , Simate Geoffrey S. 
Published: July 2024

AbstractThis review critically examines the effects of AMD from the gold mines of South Africa and available options. We also critically analyse case studies, research gaps, and the challenges and opportunities presented by the AMD. Our assessment indicates the availability of potential technological advancements that might flip the paradigm in favour of less sludge being produced, lower operational costs, and more effective AMD treatment strategies. This has led to the development of long-term plans for AMD treatment technologies and the recovery of important minerals. There is currently a demand for integrated AMD technologies that take a holistic approach to long-term AMD treatment. Reusing water and recovering valuable resources like sulphuric acid, rare earth elements, and other metals have received a lot of attention. Continued study and implementation of such strategies will support sustainable gold mining, address the environmental damage caused by AMD, and optimize resource and revenue-generating potentials.
Deciphering Terroirs’ Code: Vineyard Site Selection for Phenolic Performance in ‘Kalecik Karası’ Grape Cultivar (V. vinifera L.)
Authors: Canturk Sevil , Kunter Birhan , Keskin Nurhan , Kaya Ozkan 
Published: July 2024

AbstractUnderstanding the complex interplay between environmental factors and grape quality is crucial for the viticulture industry, as it directly influences wine quality and the distinctiveness of products. This significance underpinned our comprehensive study, which aimed to dissect the relationships between ‘terroir’, including the altitude, regional climate, soil characteristics, vineyard management practice, and the composition of grapes in cv. ‘Kalecik Karası’ (Vitis vinifera L.). Six vineyard sites ranging from 115 to 1180 m altitude were studied. Total soluble solids (TSS, °Brix) titratable acidity, pH and color index of red grapes (CIRG) were evaluated as the main maturity indices and phenolic composition based on anthocyanin and tannin was analyzed. According to the results of the study, we deduced the critical importance of adopting region-specific viticultural practices tailored to the unique environmental conditions of each terroir. This approach not only optimizes grape quality but also accentuates the uniqueness of the wines produced, reflecting the inherent qualities of their origin. The highest altitude Nevşehir (1180 m) showed high levels of total and extractable anthocyanin highlighting the region’s favorable conditions for these compounds (355.26 mg kg−1 and 364.00 mg kg−1), while exhibiting the second lowest skin tannin (1979.40 mg kg−1 and 2180.78 mg kg−1) in both years. Particularly for cultivars like ‘Kalecik Karası’, our study demonstrated how specific terroirs could significantly affect their phenolic composition and, consequently, wine quality. By aligning viticultural practices with the distinct characteristics of each terroir, producers can enhance both the quality and distinctiveness of their wines. This emphasizes the necessity of ongoing research and adaptation in viticultural strategies to fully harness the potential of diverse grape varieties and terroirs, ensuring the production of high-quality wines that truly reflect their origin.
DDoS attack detection techniques in IoT networks: a survey
Authors: Pakmehr Amir , Aßmuth Andreas , Taheri Negar , Ghaffari Ali 
Published: July 2024

AbstractThe Internet of Things (IoT) is a rapidly emerging technology that has become more valuable and vital in our daily lives. This technology enables connection and communication between objects and devices and allows these objects to exchange information and perform intelligent operations with each other. However, due to the scale of the network, the heterogeneity of the network, the insecurity of many of these devices, and privacy protection, it faces several challenges. In the last decade, distributed DDoS attacks in IoT networks have become one of the growing challenges that require serious attention and investigation. DDoS attacks take advantage of the limited resources available on IoT devices, which disrupts the functionality of IoT-connected applications and services. This article comprehensively examines the effects of DDoS attacks in the context of the IoT, which cause significant harm to existing systems. Also, this paper investigates several solutions to identify and deal with this type of attack. Finally, this study suggests a broad line of research in the field of IoT security, dedicated to examining how to adapt to current challenges and predicting future trends.
Two species of realism
Authors: Raja Vicente , Sanches de Oliveira Guilherme 
Published: July 2024

AbstractDifferent species of realism have been proposed in the scientific and philosophical literature. Two of these species are direct realism and causal pattern realism. Direct realism is a form of perceptual realism proposed by ecological psychologists within cognitive science. Causal pattern realism has been proposed within the philosophy of model-based science. Both species are able to accommodate some of the main tenets and motivations of instrumentalism. The main aim of this paper is to explore the conceptual moves that make both direct realism and causal pattern realism tenable realist positions able to accommodate an instrumentalist stance. Such conceptual moves are (i) the rejection of veritism and (ii) the re-structuring of the phenomena of interest. We will then show that these conceptual moves are instances of the ones of a common realist genus we name pragmatist realism.
Investigation on effects of water-shale interaction on acoustic characteristics of organic-rich shale in Ordos Basin, China
Authors: Zhuang Yan , Liu Xiangjun , Chen Zhangxin , Liang Lixi , Zhang Shifeng , Xiong Jian , Zhang Tiantian 
Published: July 2024

AbstractThe water-shale interaction affect the shale structure, leading to wellbore instability and increasing drilling costs. The extent of structural changes within the shale can be determined non-destructively by analyzing its acoustic characteristics. Experiments were conducted to investigate the acoustic properties of shale from the Yanchang Formation in the Ordos Basin before and after exposure to brines of varying types, soaking times, and salinities. The study investigated the effects of brine type, soaking time, and salinity on shale’s acoustic properties, including changes in acoustic wave propagation speed, P/S wave velocity ratio, and both time-domain and frequency-domain amplitudes. The results indicate that although the type of brine has a limited impact on the water-shale interaction, KCl exhibits a significant inhibitory effect. However, the soaking time and the brine salinity have a significant impact on the acoustic properties of shale. As the soaking time increases, the decrease in wave velocity increases, the P/S wave velocity ratio increases, and the decrease in time-domain amplitude increases. The amplitude of the main frequency in the frequency domain signal also decreases with the increase of reaction time, which is consistent with the analysis results of the time domain signal. As the salinity of brine increases, the decrease in wave velocity decreases, the P/S wave velocity ratio decreases, and the decrease in time-domain amplitude decreases. The amplitude of the main frequency in the frequency domain signal also decreases with the increase of brine salinity, which is consistent with the analysis results of the time domain signal. This work establishes the relationship between water-shale interaction and acoustic characteristics, which can quantitatively evaluate the degree of interaction between water and shale without damaging shale. Furthermore, this research provides new insights and guidance for predicting drilling collapse cycles and optimizing drilling fluid compositions.
An experimental study of epoxy-based nanocomposite for chemical consolidation in a sandstone reservoir with high clay content
Authors: Banashooshtari Hooman , Khamehchi Ehsan , Rashidi Fariborz , Dargi Matin 
Published: July 2024

AbstractSand production poses a substantial challenge in the oil and gas field, particularly in formations lacking the requisite strength to withstand pressure differentials during extraction. Many wells produce much less than their capacity due to the need to mitigate sand production and prevent well completion and wellhead erosion. The choice of sand control method depends on various factors, such as reservoir conditions, operational methods, and economic considerations, encompassing both mechanical and chemical approaches. In response to this challenge, this study investigates the application of a novel polymer nanofluid for chemical consolidation in clay-rich sandstone reservoirs, an area of exploration yet to be fully tapped. The research aims to assess the potential of polymer nanofluids as a promising solution for sand control in clay-rich reservoirs, with the overarching goal of bolstering well productivity and mitigating the adverse impacts of sand production. Conducted at a laboratory scale, the experiments involved the injection of 1 Pore Volume of consolidation fluid into sandstone cores with 15% and 30% clay content. Subsequently, the cores were subjected to reservoir temperature and pressure conditions for a period of 24 h. The obtained results show a significant enhancement in compressive strength, exceeding 700 psi, facilitated by the polymer nanofluid. Furthermore, permeability restoration reached approximately 89%, a notable improvement compared to preceding studies. Moreover, the introduction of foam injection rendered the core surface water-wet, suggesting potential advantages for reservoir management. These findings illuminate the promise of polymer nanofluids as an effective tool for sand control in clay-rich sandstone reservoirs.
Effect of the low sulphur regulations of maritime fuels on ambient air quality: a case study in the Bosphorus strait
Authors: Ekmekçioğlu A. , Çelebi U. B. , Ünlügençoğlu K. , Kuzu S. L. 
Published: July 2024

Abstract
The maritime transportation sector poses a significant environmental risk due to its reliance on fossil fuels and its proximity to coastal areas. To address this issue, the International Maritime Organization, authorized by the IPCC, is responsible for reducing and preventing ship-borne emissions. The International Maritime Organization regularly updates emission prevention measures through annual MEPC meetings, particularly under the MARPOL 73/78 Convention, to adapt to changing conditions. In this study, we utilized a bottom-up approach to calculate the emissions of NOX, SO2, CO, and PM10 emitted by ships transiting through the Istanbul Bosphorus from 2014 to 2021. We employed the AERMOD air quality dispersion model to generate SO2 spatial distribution maps, focusing on the year 2014 with the highest pollutant release. The obtained results were compared with measurements from air quality monitoring stations, allowing us to evaluate the contribution of maritime SO2 emissions to overall Bosphorus pollution. Furthermore, we also examined the impact of low sulfur fuel usage after the sulphur was reduced from 3.5 to 0.5% by mass, in accordance with the regulations put into effect by IMO in 2020.
Der Blick auf die Kinder – Krisen und Konflikte im Elementar- und Primarbereich thematisieren
Authors: Peuke Julia , Overwien Bernd 
Published: July 2024

ZusammenfassungKrisen sind gegenwärtig nicht wegzudenken: Die Klimakrise, die Corona-Pandemie sowie Kriege und Konflikte gehören aufgrund unmittelbarer sowie medial erzeugter Betroffenheit auch zur Lebenswelt von jüngeren Kindern. Krisen führen zu Ängsten – sowohl bei Kindern als auch bei Erwachsenen. Die zentrale These des Beitrags besteht darin, dass es gilt, einen pädagogischen Umgang mit Krisen zu finden sowie (jüngeren) Kindern eine für sie angemessene Auseinandersetzung mit Krisen zu ermöglichen. Der Begriff „Krisen“ wird hierfür erläutert und es folgt ein Einblick in den aktuellen Forschungsstand zu Kindern und Krisen. Neben dem pädagogischen Umgang im Kindergarten sowie in der Grundschule wird die didaktisch aufbereitete Thematisierung von Krisen und Konflikten als Inhaltsfeld der politischen Bildung im Sachunterricht diskutiert. Hierbei geht es um das Verstehen von Zusammenhängen und die Auseinandersetzung mit der Krisen innewohnenden Ungewissheit. Darauf aufbauend folgen Überlegungen für weiterführende Forschungsarbeiten zur Thematik.
Drug-degrading bacteria isolated from the effluent water of a sewage plant
Authors: Mireisz T. , Horváth F. B. , Kashaija N. T. , Farkas R. , Boldizsár I. , Tóth E. 
Published: July 2024

AbstractEndocrine disruptors are potential environmental contaminants that can cause toxicity in aquatic ecosystems, so the Water Framework Directive has established limits for these compounds. During our research, 41 bacterial strains were isolated and identified from sewage effluent and tested for their degradation capacities for bisphenol A, 17β-estradiol, and nonylphenol. All the isolated bacteria belonged to the Gammaproteobacteria class of Pseudomonadota phylum (members of Citrobacter, Enterobacter, Escherichia, Klebsiella, Kluyvera, Leclercia, Raoultella, Shigella. Acinetobacter, Aeromonas, and Pseudomonas genera). During the experiments, only strains HF17, HF18 (Pseudomonas aeruginosa), and HF31 (Citrobacter freundii) were unable to grow on these compounds, all other bacterial strains could grow in the presence of the investigated endocrine disruptors. Based on the genomic analysis of the type strains, a set of genes involving aromatic compound degradation was detected, among the peripheral metabolic pathways, the quinate and benzoate degradation pathways proved to be widespread, among the central aromatic intermediates metabolism, the catechol branch of the beta-ketoadipate pathway was the most dominant. Pseudomonas fulva HF16 strain could utilize the investigated endocrine disruptors: bisphenol A by 34%, 17β-estradiol by 52%, and nonylphenol by 54%.
New distribution records of the Arctic bryozoan Uschakovia gorbunovi Kluge, 1946 in the Barents and Greenland Seas
Authors: Evseeva Olga Yu. , Dvoretsky Alexander G. 
Published: July 2024

Abstract
The bryozoan Uschakovia gorbunovi was initially characterized as a constituent member of benthic communities of the Kara and East-Siberian Seas. The academic literature reports this species in the Barents Sea, but without accurate information on sampling locations. Also, there are no previous records of this species in the northern Greenland Sea near Svalbard. Our analysis of benthic collections obtained during the past two decades revealed the occurrence of four distribution records of Uschakovia gorbunovi within the Barents and Greenland Sea specifying its distribution: one in the northwestern part of the area and three others in the waters surrounding Svalbard. The new distribution records may be related to inadequate sampling efforts or the expansion of this Arctic species into the Barents Sea, which may be due to either natural processes such as ocean currents, or introduction by mobile benthic species such as snow crabs.
Spatial Correlation Increase in Single‐Sensor Satellite Data Reveals Loss of Amazon Rainforest Resilience
Authors: Blaschke Lana L. , Nian Da , Bathiany Sebastian , Ben‐Yami Maya , Smith Taylor , Boulton Chris A. , Boers Niklas 
Published: July 2024

AbstractThe Amazon rainforest (ARF) is threatened by deforestation and climate change, which could trigger a regime shift to a savanna‐like state. Whilst previous work has suggested that forest resilience has declined in recent decades, that work was based only on local resilience indicators, and moreover was potentially biased by the employed multi‐sensor and optical satellite data and undetected anthropogenic land‐use change. Here, we show that the average correlation between neighboring grid cells' vegetation time series, which is referred to as spatial correlation, provides a more robust resilience indicator than local estimations. We employ it to measure resilience changes in the ARF, based on single‐sensor Vegetation Optical Depth data under conservative exclusion of human activity. Our results show an overall loss of resilience until around 2019, which is especially pronounced in the southwestern and northern Amazon for the time period from 2002 to 2011. The results from the reliable spatial correlation indicator suggest that in particular the southwest of the ARF has experienced pronounced resilience loss over the last two decades.
Electrical Resistivity Imaging of the Northeast Carpathian Volcanic Arc With 3‐D Magnetotellurics Reveals Shallow Hydrothermal System
Authors: Neukirch Maik , Minakov Alexander , Smirnov Maxim , Gaina Carmen , Munteanu Ioan , Panea Ionelia 
Published: July 2024

AbstractThe Carpathian belt is one of Europe's major metallogenic provinces, where magmatic ore mineralization is associated with the past subduction environment. The upper crust is mapped for the first time in the Northeast Carpathian Volcanic Arc using magnetotelluric data inversion. The obtained 3‐D electrical resistivity model is interpreted in conjunction with geological information and magnetic anomaly data. The model illustrates the deep magmatic plumbing system including kilometer‐scale plutonic bodies at a depth of 2–7 km. The model implies that the transport of magma and fluids in the uppermost crust was controlled by pre‐existing faults and décollement horizons. Present ore mineralization, mined since historical times, can be attributed to an electrically conductive conduit that is mapped from the surface to a depth of about 30 km. It is suggested that this conduit connected a shallow magmatic chamber to a deep source region in the southeast during late Miocene time. An observed northwest deflection of the deep magmatic conduit at a depth of more than 10 km may explain the spatial gap in the distribution of the Miocene volcanic activity along the Eastern Carpathians.
Source of the Observed Enhancements in Thermospheric ΣO/N2 During Two Solar Eclipses in 2023
Authors: Cantrall C. E. , Mrak S. , Paxton L. J. , Zhang Y. , Nikoukar R. , Schaefer R. K. , Yee J. H. 
Published: July 2024

AbstractTwo solar eclipse events in 2023 appeared to produce considerable enhancements in the thermospheric column density ratio of monatomic oxygen to molecular nitrogen (ΣO/N2) as measured by TIMED GUVI. We quantify potential sources for eclipse‐induced ΣO/N2 changes and find that the observed enhancements arise from the ionospheric O+ radiative recombination contribution to the OI 135.6 nm emission from which ΣO/N2 is derived. Variations in the solar Extreme Ultra Violet (EUV) and X‐ray spectrum, due to the difference between the disk spectrum and the coronal spectrum, are also considered but shown to have negligible contributions to the ΣO/N2 enhancements. After accounting for the radiative recombination contribution, we constrain the real thermospheric compositional change to the uncertainty level of the measurements of 5%–10%. These results are valuable for the interpretation of eclipse‐induced ΣO/N2 changes that will further first‐principle model comparisons and lead to a better understanding of the response of the thermosphere to localized variations in solar EUV and X‐ray forcing.
Understanding the global subnational migration patterns driven by hydrological intrusion exposure
Authors: Qiao Renlu , Gao Shuo , Liu Xiaochang , Xia Li , Zhang Guobin , Meng Xi , Liu Zhiyu , Wang Mo , Zhou Shiqi , Wu Zhiqiang 
Published: July 2024

AbstractAmid the escalating global climatic challenges, hydrological risks significantly influence human settlement patterns, underscoring the imperative for an in-depth comprehension of hydrological change’s ramifications on human migration. However, predominant research has been circumscribed to the national level. The study delves into the nonlinear effects of hydrological risks on migration dynamics in 46,776 global subnational units. Meanwhile, leveraging remote sensing, we procured globally consistent metrics of hydrological intrusion exposure, offering a holistic risk assessment encompassing hazard, exposure, and vulnerability dimensions, thus complementing previous work. Here, we show that exposure is the primary migration driver, surpassing socioeconomic factors. Surrounding disparities further intensified exposure’s impact. Vulnerable groups, especially the economically disadvantaged and elderly, tend to remain in high-risk areas, with the former predominantly migrating within proximate vicinities. The nonlinear analysis delineates an S-shaped trajectory for hydrological exposure, transitioning from resistance to migration and culminating in entrapment, revealing dependence on settlement resilience and adaptability.
Surface-induced water crystallisation driven by precursors formed in negative pressure regions
Authors: Sun Gang , Tanaka Hajime 
Published: July 2024

AbstractIce nucleation is a crucial process in nature and industries; however, the role of the free surface of water in this process remains unclear. To address this, we investigate the microscopic freezing process using brute-force molecular dynamics simulations. We discover that the free surface assists ice nucleation through an unexpected mechanism. The surface-induced negative pressure enhances the formation of local structures with a ring topology characteristic of Ice 0-like symmetry, promoting ice nucleation despite the symmetry differing from ordinary ice crystals. Unlike substrate-induced nucleation via water-solid interactions that occurs directly on the surface, this negative-pressure-induced mechanism promotes ice nucleation slightly inward the surface. Our findings provide a molecular-level understanding of the mechanism and pathway behind free-surface-induced ice formation, resolving the longstanding debate. The implications of our discoveries are of substantial importance in areas such as cloud formation, food technology, and other fields where ice nucleation plays a pivotal role.
Mst1-mediated phosphorylation of FoxO1 and C/EBP-β stimulates cell-protective mechanisms in cardiomyocytes
Authors: Maejima Yasuhiro , Nah Jihoon , Aryan Zahra , Zhai Peiyong , Sung Eun-Ah , Liu Tong , Takayama Koichiro , Moghadami Siavash , Sasano Tetsuo , Li Hong , Sadoshima Junichi 
Published: July 2024

AbstractThe molecular mechanisms by which FoxO transcription factors mediate diametrically opposite cellular responses, namely death and survival, remain unknown. Here we show that Mst1 phosphorylates FoxO1 Ser209/Ser215/Ser218/Thr228/Ser232/Ser243, thereby inhibiting FoxO1-mediated transcription of proapoptotic genes. On the other hand, Mst1 increases FoxO1-C/EBP-β interaction and activates C/EBP-β by phosphorylating it at Thr299, thereby promoting transcription of prosurvival genes. Myocardial ischemia/reperfusion injury is larger in cardiac-specific FoxO1 knockout mice than in control mice. However, the concurrent presence of a C/EBP-β T299E phospho-mimetic mutation reduces infarct size in cardiac-specific FoxO1 knockout mice. The C/EBP-β phospho-mimetic mutant exhibits greater binding to the promoter of prosurvival genes than wild type C/EBP-β. In conclusion, phosphorylation of FoxO1 by Mst1 inhibits binding of FoxO1 to pro-apoptotic gene promoters but enhances its binding to C/EBP-β, phosphorylation of C/EBP-β, and transcription of prosurvival genes, which stimulate protective mechanisms in the heart.