bluuebunny/crossref_metadata_2025_split huggingface dataset:
Acetylcholinesterase Biosensor Based on Poly (diallyldimethylammonium chloride)-multi-walled Carbon Nanotubes-graphene Hybrid Film
Authors: Sun Xia , Gong Zhili , Cao Yaoyao , Wang Xiangyou 
Published: October 2014

Abstract
In this paper, an amperometric acetylcholinesterase (AChE) biosensor for quantitative determination of carbaryl was developed. Firstly, the poly (diallyldimethy-lammonium chloride) -multi-walled carbon nanotubes-graphene hybrid film was modified onto the glassy carbon electrode (GCE) surface, then AChE was immobilized onto the modified GCE to fabricate the AChE biosensor. The morphologies and electrochemistry properties of the prepared AChE biosensor were investigated by using scanning electron microscopy, cyclic voltammetry and electrochemical impedance spectroscopy. All variables involved in the preparation process and analytical performance of the biosensor were optimized. Based on the inhibition of pesticides on the AChE activity, using carbaryl as model compounds, the biosensor exhibited low detection limit, good reproducibility and high stability in a wide range. Moreover, the biosensor can also be used for direct analysis of practical samples, which would provide a new promising tool for pesticide residues analysis.
Hydrothermal Synthesis and Characterization of Europium-doped Barium Titanate Nanocrystallites
Authors: García-Hernández Margarita , Chadeyron Geneviève , Boyer Damien , García-Murillo Antonieta , Carrillo-Romo Felipe , Mahiou Rachid 
Published: October 2014

Abstract
Barium titanate nanocrystallites were synthesized by a hydrothermal technique from barium chloride and tetrabutyl titanate. Single-crystalline cubic perovskite BaTiO3 consisting of spherical particles with diameters ranging from 10 to 30 nm was easily achieved by this route. In order to study the influence of the synthesis process on the morphology and the optical properties, barium titanate was also prepared by a solid-state reaction. In this case, only the tetragonal phase which crystallizes above 900° was observed. High-temperature X-ray diffraction measurements were performed to investigate the crystallization temperatures as well as the particle sizes via the Scherrer formula. The lattice vibrations were evidenced by infrared spectroscopy. Eu3+ was used as a structural probe, and the luminescence properties recorded from BaTiO3:Eu3+and elaborated by a solid-state reaction and hydrothermal process were compared. The reddish emission of the europium is increased by the nanometric particles.
Single-step Preparation of Nano-homogeneous NiO/YSZ Composite Anode for Solid Oxide Fuel Cells
Authors: Song Jung-Hoon , Park Mi Young , Park Hye Won , Lim Hyung-Tae 
Published: October 2014

Abstract
Homogeneous co-precipitation and hydrothermal treatment were used to prepare nano- and highly dispersed NiO/YSZ (yttria-stabilized zirconia) composite powders. Composite powders of size less than 100 nm were successfully prepared. This process did not require separate sintering of the YSZ and NiO to be used as the raw materials for solid oxide fuel cells. The performance of a cell fabricated using the new powders (max. power density ∼0.87 W/cm2) was higher than that of a cell fabricated using conventional powders (max. power density ∼0.73 W/cm2). Co-precipitation and hydrothermal treatment proved to be very effective processes for reducing cell production costs as well as improving cell performance.
Surface Texturing of TiO2 Film by Mist Deposition of TiO2 Nanoparticles
Authors: Qin Gang , Watanabe Akira 
Published: October 2014

Abstract
Unique and various microstructures of titanium oxide (TiO2) film including macroporous structure, chromatic veins and rings, have been easily fabricated by mist deposition method on silicon substrate with mild preparation conditions. Rutile phase TiO2 nanoparticles were directly used as starting material to prepare film and led to a simple preparation process. It was found that several different microstructures existed in the sample and changed with the varied positions from the center to the edge of the film when the concentration of the TiO2 suspension is 0.06 mol/l, the deposition time is 30 min, the flow rate is 1 l/min and the temperature is 150°C. The surface texturing shows apparent distinction as the concentration of the TiO2 suspension decreased to 0.03 mol/l and 0.01 mol/l.
Giant Magneto-impedance Effect in Composite Wires with Different Core Layer
Authors: Wang R. L. , Li X. , Kong X. H. , Guo Y. X. , Ruan J. Z. , Zhao Z. J. 
Published: October 2014

Abstract
Composite structure materials were potential sensing elements for magnetic sensors due to Giant magnetoimpedance (GMI) effect. Two kinds of composite wires with different magnetic/non-magnetic structures were fabricated by using electroless deposition methods and the magnetoimpedance properties were investigated. The maximum GMI ratio of 114% was acquired at 60 MHz in the composite wires with a ferromagnetic core, whereas, 116% of maximum GMI ratio was found in the composite wires with a conductive core at low frequency of 600 kHz. These results exhibit that the GMI ratio reaches the maximum when magnetoresistance ratio ΔR/R and magnetoinductance ratio ΔX/X make the comparative contributions to the total magnetoimpedance (MI). The obvious GMI effect obtained in the composite wires with conductive core frequency may provide a candidate for applications in magnetic sensors, especially at low frequencies.
The Effect of Fabrication Conditions for GDC Buffer Layer on Electrochemical Performance of Solid Oxide Fuel Cells
Authors: Song Jung-Hoon , Jung Myung Geun , Park Hye Won , Lim Hyung-Tae 
Published: October 2014

Abstract
A Gd-doped ceria (GDC) buffer layer is required between a conventional yttria-stabilized zirconia (YSZ) electrolyte and a La-Sr-Co-Fe-O3 (LSCF) cathode to prevent their chemical reaction. In this study, the effect of varying the conditions for fabricating the GDC buffer layer, such as sintering temperature and amount of sintering aid, on the solid oxide fuel cell (SOFC) performance was investigated. A finer GDC powder (i.e., ultra-high surface area), a higher sintering temperature (∼1290°C), and a larger amount of sintering aid (∼12%) resulted in improved densification of the buffer layer; however, the electrochemical performance of an anode-supported cell containing this GDC buffer layer was poor. These conflicting results are attributed to the formation of (Zr, Ce)O2 and/or excess cobalt grain boundaries (GBs) at higher sintering temperatures with a large amount of sintering aid (i.e., cobalt oxide). A cell comprising of a cobalt-free GDC buffer layer, which was fabricated using a low-temperature process, had lower cell resistance and higher stability. The results indicate that electrochemical performance and stability of SOFCs strongly depend on fabrication conditions for the GDC buffer layer.
Enhanced Photocatalytic Activity of ZnO/CuO Nanocomposites Synthesized by Hydrothermal Method
Authors: Chang Tongqin , Li Zijiong , Yun Gaoqian , Jia Yong , Yang Hongjun 
Published: October 2014

Abstract
In this paper, we have demonstrated a facile and low-cost synthesis of the ZnO/CuO nanocomposites by two-step hydrothermal methods. The photocatalytic properties of the as-synthesized ZnO/CuO nanocomposites have been evaluated by the photodegradation of methylene blue (MB) and methyleneorange (MO) under UV irradiation. Experimental results show that MB and MO can be degraded completely within 15 and 25 min by the ZnO/CuO nanocomposites and its photodegradation rate is 6 times faster than that of pure ZnO. This enhanced photocatalytic activity can be ascribed to the low recombination probability of photo-induced carriers due to the efficient charge transfer in the nanocomposites. The as-synthesized ZnO/CuO nanocomposite may be a promising candidate for dye photodegradation of wastewaters.
Superplastic Behavior of Alumina Composites Mediated by Carbon Nanotubes
Authors: Zhou Xiaobing , Li Lei , Shen Lu , Zhou Jie , Zhang Junwei , Mukherjee Amiya K. , Xiang Changshu , Tang Huiping , Huang Qing 
Published: October 2014

Abstract
The high temperature creep behavior of carbon nanotube (CNT)/alumina was mediated by the surface chemical functionalization used for synthesis of composite powders. Non-covalent functionalized carbon nanotubes make composites ductile, but covalent approach leads composites that are creep-resistant. Oxygen vacancy mechanism is proposed to account for this mediation effect in this communication.
Fabrication of Large-area 3-D Ordered Silver-coated Colloidal Crystals and Macroporous Silver Films Using Polystyrene Templates
Authors: Zhu Wen , Wu Yuanyuan , Wang Chengyin , Zhang Ming , Dong Guanxiu 
Published: October 2014

Abstract
The highly ordered silver-coated colloidal crystals arrays and macroporous silver films were derived through an electrostatics-induced adsorption effect using polystyrene (PS) as templates. Carboxyl-modified PS microspheres were prepared by emulsifier-free emulsion polymerization using methacrylic acid (MAA) as the functional monomer. PS microspheres were self-assembled into close packing colloidal crystals of facecentered cubic arrays to the substrate with vertical deposition method. These colloidal crystals were modified using dopamine (DA) to form poly-dopamine (PDA) during its oxidative polymerization. Through electrostatic interaction, the silver nanoparticles were deposited and adsorbed onto the surfaces of colloidal crystals templates by exposing [Ag(NH3)2]+ solution to infrared irradiation. Removal of the polymeric template by etching with methylbenzene solvent resulted in 3D ordered macroporous silver films. The structural and properties of the ordered silver-coated arrays and macroporous silver films were characterized by field emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), UV-vis spectroscopy and surface-enhanced Raman spectroscopy (SERS). The results indicate that the prepared silver-coated arrays and macroporous silver films possess the features of ordered multilayer arrangement, uniformity and repeatability as well as an ideal SERS effect.
Improving the Electrical Contact Property of Single-Walled Carbon Nanotube Arrays by Electrodeposition
Authors: Zhang Min 
Published: October 2014

Abstract
A parallel method for the fabrication of metal contacts on single-walled carbon nanotube (SWNT) arrays was presented and the electrical contact property was evaluated by a SWNT-field effect transistor structure. Copper and gold contacts were fabricated on both semiconducting SWNTs and metallic SWNTs by using a maskless electrodeposition process. The SWNT array remained a p-type semiconductor after the electrodeposition. The contact resistance between SWNT array and microelectrodes was reduced more than 50% by the established copper contacts. The source-drain current of the carbon nanotube field-effect transistor (CNT-FET) structure can be further increased from 7.9 μA to 9.2 μA when the copper contacts were replaced by gold ones, which is probably due to the better contact property to SWNT of gold contacts with fine grain size.
Controllable Synthesis of Fluorescent Carbon Dots and Their Detection Application as Nanoprobes
Authors: Yang Zhi , Li Zhaohui , Xu Minghan , Ma Yujie , Zhang Jing , Su Yanjie , Gao Feng , Wei Hao , Zhang Liying 
Published: October 2014

Abstract
Carbon dots (CDs), as a new member of carbon nanomaterial family, have aroused great interest since their discovery in 2004. Because of their outstanding water solubility, high sensitivity and selectivity to target analytes, low toxicity, favorable biocompatibility, and excellent photostability, researchers from diverse disciplines have come together to further develop the fundamental properties of CDs. Many methods for the production of CDs have been reported, therein, hydrothermal and solvothermal technology needs simple equipments, and microwave synthesis needs less reaction time, hence these methods become current common synthesis methods, in which many precursors have been applied to produce CDs. Due to their excellent fluorescence, CDs have made impressive strides in sensitivity and selectivity to a diverse array of salt ions, organic/biological molecules and target gases. The development of CDs as nanoprobes is still in its infancy, but continued progress may lead to their integration into environmental and biological applications. Hydrothermal, solvothermal, and microwave synthesis of fluorescent carbon dots and their detection applications as nanoprobes in salt ions, organic/biological molecules, and target gases will be reviewed.
Fabrication and Evaluation of Low-cost Cu2ZnSn(S,Se)4 Counter Electrodes for Dye-sensitized Solar Cells
Authors: Shen Jie , Zhang Dingwen , Li Junjie , Li Xiaodong , Sun Zhuo , Huang Sumei 
Published: October 2014

Abstract
We explore a simple and eco-friendly approach for preparing CZTS powders and a screen-printing process for Cu2ZnSn(S,Se)4 (CZTSSe) counter electrodes (CEs) in dye-sensitized solar cells (DSCs). Cu2ZnSnS4 (CZTS) nanoparticles have been synthesized via a hydrazine-free solvothermal approach without the assistance of organic ligands. CZTS has been prepared by directly drop-casting the CZTS ink on the cleaned FTO glass, while CZTSSe CEs have been fabricated by screen-printing CZTS pastes, followed by post selenization using Se vapor obtained from elemental Se pellets. The crystal structure, composition and morphology of the as-deposited CZTS nanoparticles and CZTSSe electrodes are characterized by X-ray diffractometer, energy dispersive spectrometer, field emission scanning electron microscopy and transmission electron microscopy. The electrochemical properties of CZTS, CZTSSe and Pt CE based DSCs are examined and analyzed by electrochemical impedance spectroscopy. The prepared CZTS and CZTSSe CEs exhibit a cellular structure with high porosity. DSCs fabricated with CZTSSe CEs achieve a power conversion efficiency of 5.75% under AM 1.5 G illumination with an intensity of 100 mW/cm2, which is higher than that (3.22%) of the cell using the CZTS CE. The results demonstrate that the CZTSSe CE possesses good electrocatalytic activity for the reduction of charge carriers in electrolyte. The comprehensive CZTSSe CE process is cheap and scalable. It can make large-scale electro-catalytic film fabrication cost competitive for both energy harvesting and storage applications.
Self-assembly Polyrotaxanes Nanoparticles as Carriers for Anticancer Drug Methotrexate Delivery
Authors: Zhang Longgui , Su Ting , He Bin , Gu Zhongwei 
Published: October 2014

Abstract
α-Cyclodextrin/poly(ethylene glycol) (α-CD/PEG) polyrotaxane nanoparticles were prepared via a self-assembly method. Anticancer drug methotrexate (MTX) was loaded in the nanoparticles. The interaction between MTX and polyrotaxane was investigated. The formation, morphology, drug release and in vitro anticancer activity of the MTX loaded polyrotaxane nanoparticles were studied. The results show that the MTX could be efficiently absorbed on the nanoparticles, and hydrogen bonds were formed between MTX and α-CDs. The typical channel-type stacking assembly style of polyrotaxane nanoparticles was changed after MTX was loaded. The mean diameter of drug loaded polyrotaxane nanoparticles were around 200 nm and the drug loading content was as high as about 20%. Drug release profiles show that most of the loaded MTX was released within 8 hours and the cumulated release rate was as high as 98%. The blank polyrotaxane nanoparticles were nontoxicity to cells. The in vitro anticancer activity of the MTX loaded polyrotaxane nanoparticles was higher than that of free MTX.
RhB Adsorption Performance of Magnetic Adsorbent Fe3O4/RGO Composite and Its Regeneration through A Fenton-like Reaction
Authors: Qin Yalin , Long Mingce , Tan Beihui , Zhou Baoxue 
Published: October 2014

Abstract
Adsorption is one of the most effective technologies in the treatment of colored matter containing wastewater. Graphene related composites display potential to be an effective adsorbent. However, the adsorption mechanism and their regeneration approach are still demanding more efforts. An effective magnetically separable absorbent, Fe3O4 and reduced graphene oxide (RGO) composite has been prepared by an in situ coprecipitation and reduction method. According to the characterizations of TEM, XRD, XPS, Raman spectra and BET analyses, Fe3O4 nanoparticles in sizes of 10–20 nm are well dispersed over the RGO nanosheets, resulting in a highest specific area of 296.2 m2/g. The rhodamine B adsorption mechanism on the composites was investigated by the adsorption kinetics and isotherms. The isotherms are fitting better by Langmuir model, and the adsorption kinetic rates depend much on the chemical components of RGO. Compared to active carbon, the composite shows 3.7 times higher adsorption capacity and thirty times faster adsorption rates. Furthermore, with Fe3O4 nanoparticles as the in situ catalysts, the adsorption performance of composites can be restored by carrying out a Fenton-like reaction, which could be a promising regeneration way for the adsorbents in the organic pollutant removal of wastewater.
Polymeric Hydrogel Nanocapsules: A Thermo and pH Dual-responsive Carrier for Sustained Drug Release
Authors: Nan Jingya , Chen Ying , Li Rutian , Wang Jifu , Liu Meihong , Wang Chunpeng , Chu Fuxiang 
Published: October 2014

AbstractHydrogel capsules show attractive prospects in drug delivery recently because of high drug loading and sustained release behavior. In this study we reported a simple and convenient route to fabricate poly (acrylic acid)-poly (N-isopropylacrylamide) (PAA-PNIPAm) hydrogel capsules by using hydroxypropylcellulose-poly (acrylic acid) (HPC-PAA) complexes as the templates. The capsules showed a high drug loading (∼280% to the weight of capsules) for Doxorubicin hydrochloride. The release of drug from the capsules was responsive to the temperature and pH of the surroundings, showing a low-rate but sustained release behavior favorable for low-toxic and long-term therapy. Together with the convenient preparation, high drug loading, dual responsivity as well as the sustained release feature, it is implied that this polymeric hydrogel capsule might be a promising candidate for new drug carriers.
Research Progress in Improving the Rate Performance of LiFePO4 Cathode Materials
Authors: Deng Sixu , Wang Hao , Liu Hao , Liu Jingbing , Yan Hui 
Published: October 2014

Abstract
Olivine lithium iron phosphate (LiFePO4) is considered as a promising cathode material for high power-density lithium ion battery due to its high capacity, long cycle life, environmental friendly, low cost, and safety consideration. The theoretical capacity of LiFePO4 based on one electron reaction is 170 mAh g−1 at the stable voltage plateau of 3.5 V vs. Li/Li+. However, the instinct drawbacks of olivine structure induce a poor rate performance, resulting from the low lithium ion diffusion rate and low electronic conductivity. In this review, we summarize the methods for enhancing the rate performance of LiFePO4 cathode materials, including carbon coating, elements doping, preparation of nanosized materials, porous materials and composites, etc. Meanwhile, the advantages and disadvantages of above methods are also discussed.
Magneto-Impedance Effect of Composite Wires Prepared by Chemical Plating under DC Current
Authors: Chen D. L. , Li X. , Pan H. L. , Luan H. Y. , Zhao Z. J. 
Published: October 2014

Abstract
CuBe composite wires of 100 μm in diameter coated with a layer of NiCoP were prepared by a chemical plating method under DC current (CPUDC). The influences of DC current on coating morphology, deposition rate, composition, giant magneto-impedance (GMI) effect and magnetic properties were investigated. It was shown that the circumferential domain structure of coating layer was induced by the DC current going through the wires. A maximum GMI ratio of 870% was obtained in the composite wire prepared under 150 mA and tested at 180 kHz. It is 30 times higher than that of the composite wire plated in the same condition by conventional chemical plating method, indicating that CPUDC is an easy and effective approach to obtain composite wires and its applications will be further extended on magnetic sensors.
Preparation of Palladium Supported on Ferric Oxide Nano-catalysts for Carbon Monoxide Oxidation in Low Temperature
Authors: Wang Fagen , Xu Yan , Zhao Kunfeng , He Dannong 
Published: October 2014

Abstract
Catalytic property of Pd/Fe2O3 catalysts on carbon monoxide (CO) oxidation at low temperature were investigated in this paper. Both the as-prepared and H2-pretreated Pd/Fe2O3 catalysts show catalytic performances on CO oxidation. The CO was completely converted at 333 K for the as-prepared sample, whereas at 313 K for H2-pretreated Pd/Fe2O3-573 catalyst. The catalytic performance of the Pd/Fe2O3 catalyst decreases with increased calcination temperature. This may be due to the increased crystallinity of the support and decreased metal-support interaction. Progressive deactivation of the catalysts during long-time reaction was associated with the formation of carbonates on the catalyst surface that inhibits CO activation or intermediate transformation.
Doping Induced Tailoring in the Morphology, Band-Gap and Ferromagnetic Properties of Biocompatible ZnO Nanowires, Nanorods and Nanoparticles
Authors: Iqbal Javed , Jan Tariq , Ronghai Yu , Naqvi Sajjad Haider , Ahmad Ishaq 
Published: October 2014

Abstract
The modification of nanostructured materials is of great interest due to controllable and unusual inherent properties in such materials. Single phase Fe doped ZnO nanostructures have been fabricated through simple, versatile and quick low temperature solution route with reproducible results. The amount of Fe dopant is found to play a significant role for the growth of crystal dimension. The effect of changes in the morphology can be obviously observed in the structural and micro-structural investigations, which may be due to a driving force induced by dipole-dipole interaction. The band gap of ZnO nanostructures is highly shifted towards the visible range with increase of Fe contents, while ferromagnetic properties have been significantly improved. The prepared nanostructures have been found to be nontoxic to SH-SY5Y Cells. The present study clearly indicates that the Fe doping provides an effective way of tailoring the crystal dimension, optical band-gap and ferromagnetic properties of ZnO nanostructure-materials with nontoxic nature, which make them potential for visible light activated photocatalyst to overcome environmental pollution, fabricate spintronics devices and biosafe drug delivery agent.
Controlling the Cassie-to-Wenzel Transition: an Easy Route towards the Realization of Tridimensional Arrays of Biological Objects
Authors: Ciasca G. , Papi M. , Chiarpotto M. , De Ninno A. , Giovine E. , Campi G. , Gerardino A. , De Spirito M. , Businaro L. 
Published: October 2014

Abstract
In this paper we provide evidence that the Cassie-to-Wenzel transition, despite its detrimental effects on the wetting properties of superhydrophobic surfaces, can be exploited as an effective micro-fabrication strategy to obtain highly ordered arrays of biological objects. To this purpose we fabricated a patterned surface wetted in the Cassie state, where we deposited a droplet containing genomic DNA. We observed that, when the droplet wets the surface in the Cassie state, an array of DNA filaments pinned on the top edges between pillars is formed. Conversely, when the Cassie-to-Wenzel transition occurs, DNA can be pinned at different height between pillars. These results open the way to the realization of tridimensional arrays of biological objects.