bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Stacking Faults in a Layered Cobalt Tellurium Phosphate Oxochloride.
Authors: Zimmermann Iwan , Johnsson Mats 
Published: March 2015

AbstractPurple single crystalline plates of Co2Te3(PO4)O6Cl are obtained from the solid state reaction of an equimolar mixture of CoCl2, CoO, TeO2, and (NH4)H2PO4 (evacuated silica tube, 550 °C, 70 h).
ChemInform Abstract: On the Ternary RExMg1‐xAl2 (RE: Gd—Tm), RE3Ag5.+‐.xMg11 .+‐.x, REAg4+xMg2‐x, RE4Ag10.3Mg12 and RE4Ag10+xMg3‐x (RE: Ce—Nd, Sm) Phases.
Authors: Verbovytskyy Yuriy , Goncalves Antonio Pereira 
Published: March 2015

AbstractTwenty ternary Mg based alloys (14 of them for the first time) are prepared by melting and annealing the elements (Al2O3 or graphite container, 1.
ChemInform Abstract: Mixed Pentele‐Chalcogen Cationic Chains from Aluminum and Gallium Halide Melts.
Authors: Eich Andreas , Bredow Thomas , Beck Johannes 
Published: March 2015

AbstractReactions of Te or Se with Bi or Sb in GaCl3 and AlI3 melts in the presence of SbCl3, BiCl3, or SbCl3 as weak oxidants yield the compounds (Sb2Te2)[GaCl4] (I), (Sb2Te2)I[AlI4] (II), (Bi2Te2)Cl[GaCl4] (III), (Bi2Se2)Cl[GaCl4] (IV), (Sb3Te4)[GaCl4] (V), and (SbTe4)[Ga2Cl7] (VI) with the one‐dimensional polymeric cations (Sb2Te2+)n, (Sb2Te22+)n, (Bi2Te22+)n, (Bi2Se22+)n, (Sb3Te4+)n, and (SbTe4+)n (evacuated glass ampoules, 50‐190 °C, 12‐21 d).
ChemInform Abstract: Solid‐State Crystal‐to‐Crystal Phase Transitions and Reversible Structure—Temperature Behavior of Phosphovanadomolybdic Acid, H5PV2Mo10O40.
Authors: Barats‐Damatov Delina , Shimon Linda J. W. , Feldman Yishay , Bendikov Tatyana , Neumann Ronny 
Published: March 2015

AbstractThe crystal packing and secondary structure of H5PV2Mo12O40 (prepared according to the literature) is analyzed by powder XRD and reveals 4 unique structures (36, 14, 8 units of crystal H2O, the latter in two modifications) and 3 reversible solid phase transitions between 25 and 55 °C depending on the loss of solvated H2O and concomitant contraction of the cell volume and increase of packing density.
ChemInform Abstract: Coexistence of 3d‐Ferromagnetism and Superconductivity in [(Li1‐xFex)OH](Fe1‐yLiy)Se.
Authors: Pachmayr Ursula , Nitsche Fabian , Luetkens Hubertus , Kamusella Sirko , Brueckner Felix , Sarkar Rajib , Klauss Hans‐Henning , Johrendt Dirk 
Published: March 2015

Abstract(Li0.795Fe0.205)OH (Fe0.915Li0.085)Se is hydrothermally prepared from a mixture of iron metal, selenourea, and LiOH in H2O (autoclave, 150 °C, 8 d) and characterized by powder and single crystal XRD, SEM, 57Fe‐Moessbauer spectroscopy, and DFT electronic structure calculations.
ChemInform Abstract: An Enhancement ZT and Spin State Transition of Ca3Co4O9 with Pb Doping.
Authors: Demirel S. , Altin E. , Oz E. , Altin S. , Bayri A. 
Published: March 2015

AbstractCa3‐xPbxCo4O9 (x = 0‐0.75) are prepared by solid state reaction of stoichiometric amounts of CaCO3, Co2O3, and PbO (Al2O3 crucible, 900 °C, 1 d) followed by calcination and sintering in O2 (900 °C, 72 h).
ChemInform Abstract: Structure and Magnetism in Hexagonal Tungsten Bronze Metal Oxides AM1/3W8/3O9 (A—K, Rb, Cs; M—Cr, Fe).
Authors: Ivanov S. A , Sahu J. R. , Voronkova V. I. , Mathieu R. , Nordblad P. 
Published: March 2015

AbstractPhase‐pure AM1/3W8/3O9 (A: K, Rb, Cs; M: CrIII, FeIII) are prepared by calcination and sintering of stoichiometric mixtures of Cr2O3, Fe2O3, alkali carbonates, and WO3 (800 °C, 12 h).
ChemInform Abstract: Coupling of Crystal Structure and Magnetism in the Layered, Ferromagnetic Insulator CrI3.
Authors: McGuire Michael A. , Dixit Hemant , Cooper Valentino R. , Sales Brian C. 
Published: March 2015

AbstractSingle crystals of CrI3 are grown by chemical vapor transport reaction of stoichiometric amounts of Cr and I2 in a temperature gradient (evacuated quartz tubes, 650 °C→500‐550 °C, several days).
ChemInform Abstract: A New Thermodynamic Parameter GCE for Identification of Glass Forming Compositions.
Authors: Ghazi Sarwat Syed , Ramya M. , Sabahut Ali Prince , Raj Baldev , Ravi K. R. 
Published: March 2015

AbstractA thermodynamic model (GCE) based on the chemical mixing enthalpy ΔHchem and the elastic enthalpy ΔHelastic is proposed for numerical identification of metallic glass forming compositions.
ChemInform Abstract: Molybdenum Phosphosulfide: An Active, Acid‐Stable, Earth‐Abundant Catalyst for the Hydrogen Evolution Reaction.
Authors: Kibsgaard Jakob , Jaramillo Thomas F. 
Published: March 2015

AbstractSurface‐sulfur modified MoP catalyst is prepared by drop casting aliquots of 0.25 M (NH4)6Mo7O24 and (NH4)2HPO4 solutions on a Ti foil support followed by drying, thermal reduction (5% H2/N2, 650 °C, 2 h), and thermal sulfidation (10% H2S/H2, 400 °C, 15 min).
ChemInform Abstract: Photocatalytic Water Oxidation by a Pyrochlore Oxide upon Irradiation with Visible Light: Rhodium Substitution into Yttrium Titanate.
Authors: Kiss Borbala , Didier Christophe , Johnson Timothy , Manning Troy D. , Dyer Matthew S. , Cowan Alexander J. , Claridge John B. , Darwent James R. , Rosseinsky Matthew J. 
Published: March 2015

AbstractA stable visible‐light driven photocatalyst (λ ≥ 450 nm) for H2O oxidation is prepared by Rh substitution into the pyrochlore Y2Ti2O7 to a maximum level of 2% by stoichiometric solid state reactions of Y2O3, TiO2, and Rh2O3 under air (Pt foil lined alumina boat, 1300 °C, 2 d).
ChemInform Abstract: Synthesis and Characterization of the Phosphates Na1+xMg1+xCr2‐x(PO4)3 (x = 0; 0.2) and NaZnCr2(PO4)3 with the α‐CrPO4 Structure.
Authors: Souiwa Khalifa , Hidouri Mourad , Toulemonde Olivier , Duttine Mathieu , Amara Mongi B. 
Published: March 2015

AbstractSingle crystals of Na1.2Mg1.2Cr1.8(PO4)3 are prepared by drying (353 K, 24 h) a 6N HNO3 solution of Na2CO3, Mg(NO3)2, Cr(NO3)3, (NH4)H2PO4, and MoO3 followed by a complex heating schedule (the formed Na2Mo2O7 is used as a flux in 3‐fold molar excess; Pt crucible, 473‐873 K, 24 h/stage; 1523 K, 1 h).
ChemInform Abstract: A New Decaoxidooctaborate(2‐) Anion, [B8O10(OH)6]2‐: Synthesis and Characterization of [Co(en)3][B5O6(OH)4] [B8O10(OH)6)]·5H2O (en = 1,2‐Diaminoethane).
Authors: Altahan Mohammed A. , Beckett Michael A. , Coles Simon J. , Horton Peter N. 
Published: March 2015

AbstractSingle crystals of [Co(en)3][B5O6(OH)4] [B8O10(OH)6]·5H2O are prepared by addition of B(OH)3 to a H2O/MeOH solution of [Co(en)3][OH]3 (gentle warming, 3 h; 41% yield).
ChemInform Abstract: Crystal Structures of New R3CoAl3Ge2 (R: Gd—Er) Quaternary Compounds and Magnetic Properties and Lattice Thermal Expansion of Gd3CoAl3Ge2.
Authors: He Wei , Zeng Weijing , Lin Guoqiang 
Published: March 2015

AbstractLn3CoAl3Ge2 (Ln: Gd—Er) quaternary compounds are prepared by arc melting of the elements followed by annealing (evacuated quartz tubes, 1023 K, 720 h).
ChemInform Abstract: Enantioselective Mannich Reaction of β‐Keto Esters with Aromatic and Aliphatic Imines Using a Cooperatively Assisted Bifunctional Catalyst.
Authors: Neuvonen Antti J. , Pihko Petri M. 
Published: March 2015

AbstractThe title reaction tolerates aliphatic and aromatic substituents on both reaction partners, affording products (III) as a mixture of inseparable diastereomers with low or without any diastereoselectivity.
ChemInform Abstract: Palladium‐Catalyzed Asymmetric Decarboxylative Cycloaddition of Vinylethylene Carbonates with Michael Acceptors: Construction of Vicinal Quaternary Stereocenters.
Authors: Khan Ajmal , Yang Lei , Xu Jing , Jin Long Yi , Zhang Yong Jian 
Published: March 2015

AbstractThe title reaction provides multifunctionalized tetrahydrofurans such as (III) and (V) bearing all‐carbon quaternary stereocenters in high yields with high relative and absolute stereocontrol.
ChemInform Abstract: Asymmetric [3 + 2]‐Cycloaddition of Morita—Baylis—Hillman Carbonates with Maleimides Catalyzed by Chiral Ferrocenylphosphines.
Authors: Tu Aiping , Hu Haiwen , Du Tieqi , Zhong Weihui 
Published: March 2015

AbstractNew, air‐stable chiral ferrocenylphosphines are designed, synthesized, and applied to promote the title cycloaddition reaction.
ChemInform Abstract: Asymmetric Reductive Aldol‐Type Reaction with Carbonyl Compounds Using Dialkyl Tartrate as a Chiral Ligand.
Authors: Isoda Motoyuki , Sato Kazuyuki , Tokura Yoriko , Tarui Atsushi , Omote Masaaki , Ando Akira 
Published: March 2015

Abstract(R,R)‐Diisopropyl tartrate is used as a source of chirality in the inter‐ or intramolecular reductive aldol‐type synthesis of β‐hydroxy esters, however, the chiral induction is rather poor.
ChemInform Abstract: Highly Enantioselective Phosphination and Hydrophosphonylation of Azomethine Imines: Using Chiral Squaramide as a Hydrogen Bonding Organocatalyst
Authors: Kong Ling‐Pei , Li Nai‐Kai , Zhang Shao‐Yun , Chen Xiang , Zhao Min , Zhang Ya‐Fei , Wang Xing‐Wang 
Published: March 2015

Abstract29 examples for phosphination and 12 examples for hydrophosphonylation
ChemInform Abstract: An in situ Directing Group Strategy for Chiral Anion Phase‐Transfer Fluorination of Allylic Alcohols.
Authors: Zi Weiwei , Wang Yi‐Ming , Toste F. Dean 
Published: March 2015

AbstractThe enantioselective fluorination of allylic alcohols relies on an in situ generated directing group which is crucial for achieving effective enantiocontrol.
ChemInform Abstract: Cycloadditions of Noncomplementary Substituted 1,2,3‐Triazines.
Authors: Anderson Erin D. , Duerfeldt Adam S. , Zhu Kaicheng , Glinkerman Christopher M. , Boger Dale L. 
Published: March 2015

AbstractCycloaddition reactions of substituted 1,2,3‐triazines with amidines, enamines and ynamines allow the synthesis of pyridine, pyrimidine and pyridazine derivatives.
ChemInform Abstract: A Simple, Mild and Environmentally Benign Procedure for the Cleavage of Carbon—Nitrogen Double Bonds Using NaBrO3 in the Presence of [bmim]HSO4.
Authors: Lumb Anshika , Rajeswari M. , Khurana Jitender M. 
Published: March 2015

AbstractThis method is applicable for a broad range of C—N double bond derivatives giving ketones or aldehydes in good yields
ChemInform Abstract: Versatile Iridicycle Catalysts for Highly Efficient and Chemoselective Transfer Hydrogenation of Carbonyl Compounds in Water.
Authors: Talwar Dinesh , Wu Xiaofeng , Saidi Ourida , Salguero Noemi Poyatos , Xiao Jianliang 
Published: March 2015

AbstractIridium catalysts (I) are found to be optimal for the reaction.
ChemInform Abstract: A New Method for Thiomethylation of Hydroxy‐1,4‐naphthoquinones with N‐Acetyl‐L‐cysteine; First Synthesis of Fibrostatins B, C, and D.
Authors: Sabutskii Yuri E. , Polonik Sergey G. , Denisenko Vladimir A. , Dmitrenok Pavel S. 
Published: March 2015

AbstractThis method was successfully used in the first synthesis of fibrostatins B, C, and D (not shown in scheme).
ChemInform Abstract: Ru/C: A Simple Heterogeneous Catalyst for the Amination of Azoles under Ligand Free Conditions.
Authors: Harsha Vardhan Reddy K. , Anil Kumar B. S. P. , Prakash Reddy V. , Uday Kumar R. , Nageswar Y. V. D. 
Published: March 2015

AbstractThe amination of 2‐haloazoles such as (I) and (VII) with a broad range of aminating reagents, is described affording the corresponding 2‐aminoazole derivatives in good yields.
ChemInform Abstract: trans‐Selective Radical Silylzincation of Ynamides.
Authors: Romain Elise , Fopp Carolin , Chemla Fabrice , Ferreira Franck , Jackowski Olivier , Oestreich Martin , Perez‐Luna Alejandro 
Published: March 2015

AbstractThe radical silylzincation of ynamides (I) and (IX) followed by quenching with NH4Cl and NH3 leads to desired β‐silylenamides (III) and (X), resp., with high trans‐selectivity.
ChemInform Abstract: Atom‐ and Step‐Economical Preparation of Reduced Knoevenagel Adducts Using CO as a Deoxygenative Agent.
Authors: Kolesnikov Pavel N. , Usanov Dmitry L. , Barablina Evgeniya A. , Maleev Victor I. , Chusov Denis 
Published: March 2015

AbstractThe rhodium catalyzed reactions of various aldehydes and cyclohexanone with active methylene compounds in the presence of carbon monoxide as deoxygenative agent provides reduced Knoevenagel adducts in moderate to good yields.
ChemInform Abstract: Rhodium‐Catalyzed Alkylation of C—H Bonds in Aromatic Amides with α,β‐Unsaturated Esters.
Authors: Shibata Kaname , Chatani Naoto 
Published: March 2015

AbstractThe regioselective alkylation of aromatic amides such as (I), (IV), (VII), and (IX) containing an 8‐aminoquinoline moiety as directing group with α,β‐unsaturated carbonyl compounds is described.
ChemInform Abstract: Room‐Temperature Chromium(II)‐Catalyzed Direct Arylation of Pyridines, Aryl Oxazolines, and Imines Using Arylmagnesium Reagents.
Authors: Kuzmina Olesya M. , Knochel Paul 
Published: March 2015

AbstractThe Tms‐group in (IV), (VI), and (X) prevents double arylation and can be further used to introduce a second aryl substituent.
ChemInform Abstract: Enantioselective Olefin Metathesis with Cyclometalated Ruthenium Complexes.
Authors: Hartung John , Dornan Peter K. , Grubbs Robert H. 
Published: March 2015

AbstractEnantioenriched complexes incorporating cyclometalated NHC ligands catalyze (Z)‐ and enantioselective asymmetric ring opening/cross metathesis reactions of norbornenes and cyclobutenes, and the difference in ring strain between these two compounds leads to different propagating species in the catalytic cycle.
ChemInform Abstract: Domino‐Hydroformylation/Aldol Condensation Catalysis: Highly Selective Synthesis of α,β‐Unsaturated Aldehydes from Olefins.
Authors: Fang Xianjie , Jackstell Ralf , Franke Robert , Beller Matthias 
Published: March 2015

AbstractExcellent chemoselectivity is observed in the intermolecular hydroformylation/cross‐aldol condensation reactions of aromatic and aliphatic aldehydes.
ChemInform Abstract: Cobalt‐Catalyzed Carboxylation of Propargyl Acetates with Carbon Dioxide.
Authors: Nogi Keisuke , Fujihara Tetsuaki , Terao Jun , Tsuji Yasushi 
Published: March 2015

AbstractAlkynyl group‐containing α‐monosubstituted and α,α‐disubstituted carboxylic acids are obtained with moderate to good yields.
ChemInform Abstract: Synthesis of α‐Functionalized Amides by a Ritter Reaction in the Presence of NaHSO4/SiO2.
Authors: Hayakawa Mamiko , Aoyama Tadashi , Kobayashi Toshiya , Takido Toshio , Kodomari Mitsuo 
Published: March 2015

AbstractThe reaction of (Ia) with (VIII) is also performed in chlorobenzene requiring significantly shorter reaction times, but yielding slightly to significantly less product.
ChemInform Abstract: Sulfoximine Assisted Pd(II)‐Catalyzed Bromination and Chlorination of Primary β‐C(sp3)—H Bond.
Authors: Rit Raja K. , Yadav M. Ramu , Ghosh Koushik , Shankar Majji , Sahoo Akhila K. 
Published: March 2015

AbstractNovel MPyS‐directing‐group‐assisted bromination and chlorination of primary β‐C(sp3)—H bonds of aliphatic acid derivatives is demonstrated for the first time.
ChemInform Abstract: Synthesis of α‐Peroxyesters via Organocatalyzed O—H Insertion of Hydroperoxides and Aryl Diazoesters.
Authors: Fisher Thomas J. , Mattson Anita E. 
Published: March 2015

AbstractHydrogen‐bond donors catalyze O‐H insertions of hydroperoxides and α‐aryl diazoesters to afford an unprecedented class of organic peroxides.
ChemInform Abstract: Enantioselective Construction of Functionalized Cyclopentanes by a Relay Ring‐Closing Metathesis and Chiral Amine (Thio)urea‐Promoted Michael Addition.
Authors: Zhang Yinan , Song Xixi , Chen Xiaobei , Song Aiguo , Zhang Shilei , Wang Wei 
Published: March 2015

AbstractIn some cases application of Grubbs first generation catalyst instead of Grubbs second generation catalyst upon the second addition of the catalyst increases the enantiomeric excess of the product.
ChemInform Abstract: Construction of Bicyclo[3.2.1]octanes with Four Stereogenic Centers by Organocatalytic Domino Michael/Aldol Reaction.
Authors: Lefranc A. , Gremaud L. , Alexakis A. 
Published: March 2015

AbstractA general and direct diastereo‐ and enantioselective organocatalyzed domino Michael/aldol reaction to form polysubstituted chiral bicyclo[3.2.1]octanes is developed.
ChemInform Abstract: Sc(OTf)3‐Catalyzed Transfer Diazenylation of 1,3‐Dicarbonyls with Triazenes via N—N Bond Cleavage.
Authors: Liu Cong , Lv Jian , Luo Sanzhong , Cheng Jin‐Pei 
Published: March 2015

AbstractThis simple transfer diazenylation reaction exhibits good functional group compatibility, and provides a convenient approach for the synthesis of highly functionalized azo compounds.
ChemInform Abstract: Catalytic Enantioselective Addition of Aryl Grignard Reagents to Ketones.
Authors: Fernandez‐Mateos Emilio , Macia Beatriz , Yus Miguel 
Published: March 2015

AbstractA range of starting ketones and aryl Grignards can be used under mild conditions in a one‐pot process to produce the desired tertiary alcohols with moderate to good yields and enantioselectivities.
ChemInform Abstract: Direct Carboxylation of Simple Arenes with CO2 Through a Rhodium‐Catalyzed C—H Bond Activation.
Authors: Suga Takuya , Mizuno Hajime , Takaya Jun , Iwasawa Nobuharu 
Published: March 2015

AbstractA novel method for direct carboxylation of simple arenes with 1 atm CO2 through a rhodium‐catalyzed C—H bond activation without the assistance of a directing group is developed.
ChemInform Abstract: Chemo‐, Regio‐ and Stereoselective Heck Arylation of Allylated Malonates: Mechanistic Insights by ESI‐MS and Synthetic Application Toward 5‐Arylmethyl‐γ‐lactones.
Authors: Oliveira Caio C. , Marques Marcelo V. , Godoi Marla N. , Regiani Thais , Santos Vanessa G. , dos Santos Emerson A. F. , Eberlin Marcos N. , Sa Marcus M. , Correia Carlos R. D. 
Published: March 2015

AbstractThe Heck arylation of allylated malonate (I) employing aryldiazonium salts (II) as the aryl‐transfer agents is described.
ChemInform Abstract: Synthesis of α‐Methylidene‐γ‐amino Acid Esters from Aldehydes via an Aminative Umpolung Strategy.
Authors: Xu Juan , Chen Jing , Yang Qin , Ding Lei , Liu Xuliang , Xu Dongfang , Zhao Baoguo 
Published: March 2015

AbstractIn situ prepared α‐imino anions react with Morita—Baylis—Hillman adducts to form the title compounds (III) and (VI).
ChemInform Abstract: Specific 1,2‐Hydride Shift in the Boron Trifluoride Catalyzed Reactions of Aromatic Aldehydes with Diazoacetonitrile: Simple Synthesis of β‐Ketonitriles.
Authors: Yang Zhanhui , Son Kwon‐Il , Li Siqi , Zhou Bingnan , Xu Jiaxi 
Published: March 2015

AbstractMild conditions and a short reaction time result in a successful preparation of the title compounds, required as important synthetic intermediates.
ChemInform Abstract: Catalytic Enantioselective Alkylation of Sulfenate Anions to Chiral Heterocyclic Sulfoxides Using Halogenated Pentanidium Salts.
Authors: Zong Lili , Ban Xu , Kee Choon Wee , Tan Choon‐Hong 
Published: March 2015

AbstractThe use of halogenated pentadinium chlorides as chiral organocatalysts allows a highly enantioselective alkylation of sulfenate anions derived from (II) to yield enantioenriched sulfoxides.
ChemInform Abstract: Iron‐Catalyzed [2 + 2 + 2] Cycloaddition of Trifluoromethyl Group Substituted Unsymmetrical Internal Alkynes.
Authors: Minakawa Maki , Ishikawa Tomoki , Namioka Junya , Hirooka Souichirou , Zhou Biao , Kawatsura Motoi 
Published: March 2015

AbstractThe title reaction affords the corresponding trifluoromethyl group substituted benzene derivatives in high yield with excellent selectivity.
ChemInform Abstract: Iron‐Catalyzed Coupling of Aryl Sulfamates and Aryl/Vinyl Tosylates with Aryl Grignards.
Authors: Agrawal Toolika , Cook Silas P. 
Published: March 2015

AbstractIn contrast to previous reports with aryl chlorides, the title coupling reaction with aryl sulfamates proceeds with low levels of the Grignard homocoupling side reaction.
ChemInform Abstract: Palladium and Copper‐Catalyzed Ligand‐Free Coupling of Phenylhydrazines in Water.
Authors: Chauhan Parul , Ravi Makthala , Singh Shikha , Raju Kanumuri S. R. , Bajpai Vikas , Kumar Brijesh , Wahajuddin Wahajuddin , Yadav Prem P. 
Published: March 2015

AbstractThe novel ligand‐free palladium‐catalyzed homo‐ and cross‐coupling reactions of water‐soluble phenylhydrazines yield biaryls.
ChemInform Abstract: Nickel‐Catalyzed Desulfitative Suzuki—Miyaura Cross‐Coupling of N,N‐Disulfonylmethylamines and Arylboronic Acids.
Authors: Chen Liangshun , Lang Hongyue , Fang Lei , Yu Jianjun , Wang Limin 
Published: March 2015

AbstractExtrusion of SO2 from the starting amines affords the aryl source for the coupling reaction.
ChemInform Abstract: A Metal‐Free One‐Pot Cascade Synthesis of Highly Functionalized Biaryl‐2‐carbaldehydes.
Authors: Challa Chandrasekhar , Vellekkatt Jamsheena , Ravindran Jaice , Lankalapalli Ravi S. 
Published: March 2015

AbstractA variety of biaryl‐2‐carbaldehydes (III) is readily prepared by reaction of dienes (I) with cinnamaldehydes in the presence of allylamine and TFA.
ChemInform Abstract: Room‐Temperature and Transition‐Metal‐Free Mizoroki—Heck‐Type Reaction. Synthesis of E‐Stilbenes by Photoinduced C—H Functionalization.
Authors: Guastavino Javier F. , Buden Maria E. , Rossi Roberto A. 
Published: March 2015

AbstractDetailed investigations concerning the reaction conditions are described: the preparation of the desired stilbenes works best without an extra solvent within a short time [i.e.
ChemInform Abstract: AZT‐Prolinamide: The Nucleoside Derived Pyrrolidine Catalysts for Asymmetric Aldol Reactions Using Water as Solvent.
Authors: Naresh Tumma , Kumar Togapur Pavan , Haribabu Kothapalli , Chandrasekhar Srivari 
Published: March 2015

AbstractNew nucleoside‐based chiral prolinamides are synthesized and applied in enantioselective aldol reaction of aldehydes with ketones to give β‐hydroxyl carbonyl compounds in high yields with good stereoselectivity.
ChemInform Abstract: Cyclization of η3‐Benzylpalladium Intermediates Derived from Carbene Insertion.
Authors: Gutman Eugene S. , Arredondo Vanessa , Van Vranken David L. 
Published: March 2015

Abstract1‐Arylindanes and 1‐aryltetralines (XI) are prepared by palladium catalyzed carbenylative cyclization reaction of aryl iodide derivatives and N‐tosylhydrazines.
ChemInform Abstract: Dual Gold Catalysis: Synthesis of Polycyclic Compounds via C—H Insertion of Gold Vinylidenes.
Authors: Wieteck Marcel , Tokimizu Yusuke , Rudolph Matthias , Rominger Frank , Ohno Hiroaki , Fujii Nobutaka , Hashmi A. Stephen K. 
Published: March 2015

AbstractThis method provides access to complex polycyclic compounds with quaternary carbon centers from non‐conjugated diynes.
ChemInform Abstract: Chiral Spirooxindole—Butenolide Synthesis Through Asymmetric N‐Heterocyclic Carbene‐Catalyzed Formal (3 + 2) Annulation of 3‐Bromoenals and Isatins.
Authors: Zheng Chenguang , Yao Weijun , Zhang Yucheng , Ma Cheng 
Published: March 2015

AbstractThe spirooxindole (VIIe) is converted to a more complex spirocyclic compound by annulation with benzyne precursors.
ChemInform Abstract: Manganese Ferrite Nanoparticle Catalyzed Tandem and Green Synthesis of Spirooxindoles.
Authors: Ghahremanzadeh Ramin , Rashid Zahra , Zarnani Amir‐Hassan , Naeimi Hossein 
Published: March 2015

AbstractA novel one‐pot three‐component reaction of isatins, anilinolactones, and malonitrile furnishes spirooxindoles with potential biological activity.
ChemInform Abstract: tert‐Butyl Hydroperoxide and Tetrabutylammonium Iodide‐ Promoted Free Radical Cyclization of α‐Azido‐N‐arylamides.
Authors: Li Dianjun , Yang Tonghao , Su Hailin , Yu Wei 
Published: March 2015

AbstractIt is demonstrated, that the reagent combination of tBuOOH and Bu4NI affects the oxidative cyclizations of α‐ethoxycarbonyl α‐azido‐N‐arylamides.
ChemInform Abstract: ipso‐Iodocyclization of para‐Substituted 4‐Aryl‐1‐alkenes Leading to 3‐Iodo‐1‐azaspiro[4.5]deca‐6,9‐diene‐2,8‐diones.
Authors: Wu Cui‐Yan , Deng Guo‐Bo , Hu Ming , Wei Wen‐Ting , Li Jin‐Heng 
Published: March 2015

AbstractThe corresponding reaction of an N‐acetyl instead of N‐methyl substituted 4‐aryl‐1‐alkene derivatives yields only trace amounts of product.
ChemInform Abstract: Formation of Persulfate from Sodium Sulfite and Molecular Oxygen Catalyzed by H5PV2Mo10O40 — Aerobic Epoxidation and Hydrolysis.
Authors: Rubinstein Amir , Carmeli Raanan , Neumann Ronny 
Published: March 2015

AbstractThe H5PV2Mo10O40 polyoxometalate catalyzes the electron transfer oxidation of sulphite to yield a sulphite radical.