bluuebunny/crossref_metadata_2025_split huggingface dataset:
Economic Impact of Truck–Machine Interference in Forest Biomass Recovery Operations on Steep Terrain
Authors: Zamora-Cristales Rene , Sessions John , Murphy Glen , Boston Kevin 
Published: December 2013

Abstract
In forest biomass recovery operations from harvest residues, processing equipment can work most productively if they can work without interference or waiting on trucks. A deterministic simulation model was developed to estimate the economic effect of truck–grinder interference in forest biomass processing and transport operations on steep terrain. Truck–machine interference can occur in situations where the grinder is waiting for trucks or vice versa. We analyzed how the number of available trucks and road characteristics affect grinder utilization and biomass delivery cost. Three cases based on different road characteristics were designed and applied to actual operations in order to illustrate how particular road features in relation to the spatial location of the grinder can affect the economics of the operation. An economic model was also developed to estimate the waiting cost of trucks and machinery due to truck–machine interferences. Grinder location in relation to available truck turnaround, turnouts, truck turning-around time, truck positioning time, and distance traveled on each road surface have a significant effect in forest residues processing and transport economics at the operational level. After the optimization was performed, the grinder utilization rate on a harvest unit with highly constrained road access reached 60 percent using six trucks. Waiting cost represented 15.15 percent of total grinding cost. On the medium constrained road access harvest unit, maximum grinder utilization reached 77 percent using five trucks. A loop road case resulted in a grinder utilization rate of 81 percent using five trucks.
Withdrawal Capacity of Plain, Annular Shank, and Helical Shank Nail Fasteners in Spruce-Pine-Fir Lumber
Authors: Luszczki Garrett E. , Clapp Joshua D. , Davids William G. , Lopez-Anido Roberto 
Published: December 2013

Abstract
This study examines the withdrawal load and energy capacity of three types of nail fasteners that are commonly used to attach sheathing to framing members: 8d common, annular ring shank, and helical shank. A baseline set of data was collected for single nails in accordance with test methods defined in ASTM D1761. Tests were performed until complete withdrawal occurred in order to quantify the total withdrawal energy. The average peak loads from testing were within 7 to 8 percent of predicted values. The annular and helical nails had much higher peak load capacity as expected, and the withdrawal energy was also greater. A new device was developed in order to subject multiple nails to withdrawal loading simultaneously. Reinforced sheathing was used to transfer load from the hydraulic actuator to the nails, which is more representative of actual structural response where there is load sharing among the nails. This device allowed direct comparison with the single nail results. Further, it also allowed the examination of a “stitched” nailing pattern, where fasteners are driven at alternating angles of ±60° measured from the framing member face. It was found that the stitched pattern resulted in 42 percent higher peak load capacity per fastener for 8d common nails, but for the helical and annular nails, peak load was similar to that achieved with a normal 90° drive angle. Withdrawal energy was 24 to 48 percent higher for all nail types using the stitched pattern.
Recovery of adrenal function in a patient with confirmed Addison's disease
Authors: Baxter M , Gorick S , Swords F M 
Published: December 2013

Summary
Addison's disease is a condition characterised by immune-mediated destruction of the adrenal glands leading to a requirement of lifelong replacement therapy with mineralocorticoid and glucocorticoid. We present a case of a 53-year-old man who presented at the age of 37 years with nausea, fatigue and dizziness. He was found to have postural hypotension and buccal pigmentation. His presenting cortisol level was 43 nmol/l with no response to Synacthen testing. He made an excellent response to conventional replacement therapy with hydrocortisone and fludrocortisone and then remained well for 16 years. On registering with a new endocrinologist, his hydrocortisone dose was revised downwards and pre- and post-dose serum cortisol levels were assessed. His pre-dose cortisol was surprisingly elevated, and so his dose was further reduced. Subsequent Synacthen testing was normal and has remained so for further 12 months. He is now asymptomatic without glucocorticoid therapy, although he continues on fludrocortisone 50 μg daily. His adrenal antibodies are positive, although his ACTH and renin levels remain elevated after treatment. Addison's disease is generally deemed to lead to irreversible cell-mediated immune destruction of the adrenal glands. For this reason, patients receive detailed counselling and education on the need for lifelong replacement therapy. To our knowledge, this is the third reported case of spontaneous recovery of the adrenal axis in Addison's disease. Recovery may therefore be more common than previously appreciated, which may have major implications for the treatment and monitoring of this condition, and for the education given to patients at diagnosis.

Learning points

Partial recovery from Addison's disease is possible although uncommon.

Patients with long-term endocrine conditions on replacement therapy still benefit from regular clinical and biochemical assessment, to revisit optimal management.

As further reports of adrenal axis recovery emerge, this may influence the counselling given to patients with Addison's disease in the future.
Simulations of Shocked Methane Including Self-consistent Semiclassical Quantum Nuclear Effects
Authors: Qi Tingting , Reed Evan J. 
Published: December 2013

ABSTRACTA methodology is described for atomistic simulations of shock-compressed materials that incorporates quantum nuclear effects on the fly. We introduce a modification of the multi-scale shock technique (MSST) that couples to a quantum thermal bath described by a colored noise Langevin thermostat. The new approach, which we call QB-MSST, is of comparable computational cost to MSST and self-consistently incorporates quantum heat capacities and Bose-Einstein harmonic vibrational distributions. As a first test, we study shock-compressed methane using the ReaxFF potential. The Hugoniot curves predicted from the new approach are found comparable with existing experimental data. We find that the self-consistent nature of the method results in the onset of chemistry at 40% lower pressure on the shock Hugoniot than observed with classical molecular dynamics. The temperature change associated with quantum heat capacity is determined to be the primary factor in this shift.
Probing Laser Induced Space Charge Fields with Rare Earth Dopants
Authors: Odhner Hosanna , Stone Greg , Dierolf Volkmar 
Published: December 2013

ABSTRACTSpectral shifts of the emission lines of Erbium ions in Lithium Niobate are used to determine the build-up of intrinsic electric fields under intense light irradiation. The observed spectral shifts can be translated into internal electric fields through a calibration using applied external fields. The studies show that a substantial field can be created locally (up to 150kV/mm) with observed occasional electric breakthroughs that have a corresponding field strength of up to 35kV/mm. In addition, a modification of some Erbium incorporation sites is observed suggesting its relationship with a defect that can by photo-ionized, such as Fe2+/Fe3+.
Study of the Size Dependence of Time-dependent Plastic Deformation of Gold Micro-pillars and Micro-spheres
Authors: Islam AZM Ariful , Klassen Robert J. 
Published: December 2013

ABSTRACTIn this study the length scale dependence of the operative mechanisms of time-dependent plastic deformation was studied using room temperature compression tests performed on Au micro-pillars and micro-spheres of 1.0 to 5.0 µm diameter. All the samples tested displayed deformation that had a component of random strain jumps. In the case of the Au micro-pillars, the frequency of the strain jumps showed a bilinear dependence upon pillar diameter with the frequency being larger, and more sensitive to diameter, when the pillar diameter was small (and τR was high). We suggest that this indicates a transition from deformation occurring by deformation on multiple slip planes to deformation occurring predominantly by single-plane dislocation slip when the pillar diameter is less than 2 µm.The strain jump frequency during the constant-load micro-pillar creep tests showed a linear dependence upon τR. Creep tests performed on the micro-spheres of 5.0 µm diameter displayed displacement jump frequency that was essentially independent of the applied load while the jump frequency increased with increasing load for the smaller 2.5 µm diameter micro-spheres. We suggest that this difference is related to the volume of the micro-sphere. When the volume is small, the component of the deformation that occurs by a stochastic dislocation glide process is increased and becomes strongly dependent upon the magnitude of the local shear stress.
Surface smoothing of glass substrate by irradiation of ionic liquid ion beams
Authors: Takeuchi Mitsuaki , Hamaguchi Takuya , Ryuto Hiromichi , Takaoka Gikan H 
Published: December 2013

ABSTRACTSurface smoothing of a barium borosilicate glass substrate by irradiation of ionic liquid ion beams were investigated. 1-ethyl-3-methylimidaolium tetrafluoroborate (EMIM-BF4) and 1-butyl-3-methylimidazolium hexafluorophosphate (BMIM-PF6) were used for the source liquid. Surface roughness represented as the arithmetic mean value decreased from 0.17 nm to 0.13 nm by the BMIM-PF6 negative ion beam. Secondary electron microscope (SEM) observation for the glass surface irradiated with the BMIM-PF6 negative ion beam showed a clear image without an electrical charge-up, though the EMIM-BF4 negative ion beam irradiated glass yielded a charged up image. X-ray photoelectron spectroscopy (XPS) analysis implied that the surface layer including cation-anion pair of BMIM-PF6 was deposited by the BMIM-PF6 negative ion beam irradiation, while an insulated surface with barium fluoride was formed by the EMIM-BF4 negative ion beam irradiation.
Electrophoretic deposition of TiO2 nanopillars from stable colloidal solution.
Authors: Jouenne Vincent , Duvail Jean-Luc , Brohan Luc , Richard-Plouet Mireille 
Published: December 2013

ABSTRACTTitanium dioxide nanoparticles were synthesized by solvothermal treatment in the presence of oleic acid and oleylamine. As Ti(IV) reactant, crystals of [Ti8O12 (H2O)24]Cl8, HCl, 7H2O were preferred because their hydrolysis and condensation can be controlled in ethanol/water solution. The organic surfactants allowed the control of the shape and they can be removed by an acid treatment of the particles. The TiO2 nanoparticles can then be re-dispersed in an ethanol-based charging solution. A fixed applied voltage promotes the electrophoretic deposition of the nanoparticles (<15 nm in size) into pores of anodized aluminium oxide (AAO) template.
Enhanced Light Trapping in Periodic Aluminum Nanorod Arrays as Cavity Resonator
Authors: Abdulrahman Rosure B. , Alagoz Arif S. , Karabacak Tansel 
Published: December 2013

ABSTRACTMetallic nanostructures can exhibit different optical properties compared to bulk materials mainly depending on their shape, size, and separation. We present the results of an optical modeling study on ordered arrays of aluminum (Al) nanorods with a hexagonal periodic geometry placed on an Al thin film. We used a finite-difference time-domain (FDTD) method to solve the Maxwell's equations and predict the reflectance of the nanorod arrays. The thickness of the base Al film was set to 100 nm, and diameter, height and nanorod center-to-center periodicity were varied. Incident light in the FDTD simulations was an EM-circular polarized plane wave and reflectance profiles were calculated in the wavelength range 200-1800 nm. In addition, we calculated spatial electric field intensity distributions around the nanorods for wavelengths 300, 500, and 700 nm. Our results show that average reflectance of Al nanorods can drop down to as low as ∼50%, which is significantly lower than the ∼90% reflectance of conventional flat Al film at similar wavelengths. In addition to the overall decrease in reflectance, Al nanorod arrays manifest multiple resonant modes (higher-order modes) indicated by several dips in their reflectance spectrums (i.e. multiple attenuation peaks in their absorption profiles). Positions of these dips in the reflectance spectrum and spatial EM field distribution vary with nanorod height and diameter. Multiple reflectance peaks are explained by cavity resonator effects. Spatial EM field distribution profiles indicate enhanced light trapping among the nanorods, which can be useful especially in optoelectronic and solar cell applications.
Nanostructurally Designed Ultra-hydrophilic Hard Ceramic Oxide Coatings for Orthopaedic Application
Authors: Namavar Fereydoon , Sabirianov Renat F. , Zhang Jiaming , Cheung Chin Li , Blatchley Charles , Miralami Raheleh , Sharp John G. , Garvin Kevin L. 
Published: December 2013

ABSTRACTThis paper addresses the application of engineered nanocrystalline ultrahydrophilic titanium oxide films to artificial orthopaedic implants. Titanium (Ti) is the material of choice for orthopaedic applications and has been used for over fifty years because of its known bio-compatibility. Recently it was shown that biocompatibility of Ti metal is due to the presence of a thin native sub-stoichiometric titanium oxide layer [1] which enhances the adsorption of mediating proteins on the surface thus enhancing cell adhesion and growth [2,3,4]. Improving the quality of surface oxide, i.e. fabricating stoichiometric oxides as well as nanoengineering the surface topology that matches the dimensions of adhesive proteins, is crucial for the increase of protein adsorption [2] and, as a result, the biocompatibility of Ti implant materials. We have fabricated ultrahydrophilic nano-crystalline transparent films of anatase phase of titania (TiO2) by ion beam assisted deposition (IBAD) processes in an ultrahigh vacuum system. Source material was 99.9% pure rutile TiO2. Various ion beam conditions were used to produce these coatings with different grain sizes (4 to 70 nm) that affect the wettability, roughness, and the mechanical and optical properties of the coating [5]. Our biological experiments have shown that biocompatibility of these ultrahydrophilic nanoengineered TiO2 coatings are superior to commonly used orthopaedic titanium and even hydroxyapatite.
Optical Characterization of Shock-Induced Chemistry in the Explosive Nitromethane using DFT and Time-Dependent DFT
Authors: Pellouchoud Lenson A. , Reed Evan J. 
Published: December 2013

ABSTRACTA thorough understanding of chemistry in extreme environments is a major challenge in experimental as well as theoretical work. With continual improvements in ultrafast optical measurements and new methods for simulations of shock-induced chemistry for timescales approaching a nanosecond, the opportunity is beginning to exist to connect experiments with simulations on the same timescale. In the present work, we compute the optical properties of the energetic material nitromethane (CH3NO2) for the first 100 picoseconds behind the detonation shock front in a molecular dynamics simulation. We compute optical spectra using the Kubo-Greenwood approach with DFT Kohn-Sham electronic states and compare with spectra computed by linear-response time-dependent density functional theory (TDDFT). The latter typically yields more accurate spectra for molecular systems. At optical wavelengths, the TDDFT method offers a correction of up to 25% in the real part of conductivity relative to the Kubo-Greenwood calculation. We also study the effects of thermal electronic excitations on the calculated spectra, and find no discernible change at optical wavelengths. In all of our calculations, we observe a non-monotonic change over time in the entire spectrum of optical properties as decomposition products evolve. The most optically relevant decomposition products are found to be NO, CNO, CNOH, water, and larger transient molecules. In particular, the disappearance of transient NO and CNO molecules (about 90 picoseconds behind the shock front) is coincident with a substantial decrease in conductivity across the optical spectrum.
N-Heterocyclic Carbene Chelated Metal Complexes as Polymerization Catalysts
Authors: El-Batta Amer A. 
Published: December 2013

ABSTRACTThe synthesis of titanium and zirconium complexes ligated by bidentate “salicylaldimine-like” N-heterocyclic carbenes (NHCs) is reported. These complexes are rare examples of group IV transition metal NHC adducts. In the presence of methylaluminoxane these complexes are useful initiators for the polymerization of ethylene and the copolymerization of ethylene with norbornene and 1-octene. Linear high density polyethylene could be produced. The Ti complexes are also utilized to yield highly syndiotactic polystyrene.
Martensitic Transformation in Submicron Cu-Al-Ni Pillar
Authors: Liu Lifeng , Zhou Yumei , Lv Lan 
Published: December 2013

ABSTRACTThe transformation plateau on the strain-stress curve is the characteristic of superelasticity of bulk shape memory alloys upon tension/compression loading. However, recent studies show that such transformation plateau is hard to see when the sample size of shape memory alloys decreases to submicrons. In order to see what happened in such small scale samples during loading, in-situ compression test has been done with single crystal Cu-14.2Al-4.0Ni (wt %) submicron pillars. Our in-situ observation during compression demonstrates that the stress-induced martensitic transformation indeed occurs in submicron pillars, but is not suppressed. Furthermore, the transformation proceeds in a sequential nucleation-growth-nucleation dominated mode, but not the transient way like that in bulk materials. As a result, the stress keeps increasing throughout the transformation and no obvious transformation plateau can be detected. However, the underlying reason for such contrast transformation behaviors between our submicron pillars and bulk materials still needs further investigation.
High Pressure Low Temperature Studies on 1-2-2 Iron-based Superconductors Using Designer Diamond Cells
Authors: Uhoya Walter O. , Tsoi Georgiy M. , Vohra Yogesh K. , Mitchell Jonathan, E. , Safa-Sefat Athena , Weir Samuel 
Published: December 2013

ABSTRACTHigh pressure low temperature electrical resistance measurements were carried out on a series of 122 iron-based superconductors using a designer diamond anvil cell. These studies were complemented by image plate x-ray diffraction measurements under high pressures and low temperatures at beamline 16-BM-D, HPCAT, Advanced Photon Source. A common feature of the 1-2-2 iron-based materials is the observation of anomalous compressibility effects under pressure and a Tetragonal (T) to Collapsed Tetragonal (CT) phase transition under high pressures. Specific studies on antiferromagnetic spin-density-wave Ba0.5Sr0.5Fe2As2 and Ba(Fe0.9Ru0.1)2As2 samples are presented to 10 K and 41 GPa. The collapsed tetragonal phase was observed at a pressure of 14 GPa in Ba0.5Sr0.5Fe2As2 at ambient temperature. The highest superconducting transition temperature in Ba0.5Sr0.5Fe2As2 was observed to be at 32 K at a pressure of 4.7 GPa. The superconductivity was observed to be suppressed on transformation to the CT phase in 122 materials.
Uncertainty Quantification Workflow for Mature Oil Fields: Combining Experimental Design Techniques and Different Response Surface Models
Authors: Ahmed Syed Jawwad , Recham Reda , Nozari Ali , Bughio Shamsudin , Schulze-Riegert Ralf , Salem Ryadh Ben 
Published: December 2013

Abstract
Simulation models for large complex reservoirs with a long production history are traditionally used in the framework of deterministic forecasts. The estimation of prediction uncertainties based on reservoir models with long run times is often impractical due to limited statistical data generated from direct full field reservoir simulation runs. Here, we use surrogate models to capture key performance indicators as a function of reservoir uncertainties. Monte Carlo sampling processes are applied for generating key parameter distributions and to identify representative simulation models for field development planning. Transparent workflow steps and a thorough validation exercise of the predictability of surrogate models is a prerequisite for obtaining prediction uncertainties based on proxy modeling results.
In this work we present a case study for estimating prediction uncertainties including history data of a large mature offshore oil field. A workflow is designed for a limited number of simulation runs which is expected to affect the stability of statistical reservoir performance indicators. Proxy models are introduced in that framework for analyzing sensitivities and to prepare a basis for extensive data sampling. Alternative proxy modeling techniques are used to cross validate results.
To assure an acceptable quality of the history match simulated field oil production rate and gas oil ratio as well as water cut and shut-in pressures in several wells are compared to their historical data. A quantitative measure for the simulation error is calculated for each case. Filtering techniques are applied for discriminating cases with a poor match quality. Sensitivities and correlation effects between field wide uncertainties and reservoir performance indicators are calculated. Representative full field simulation models representing P10, P50 and P90 for oil reserves are identified.
The uncertainty quantification workflow was validated for a mature field case study and serves as a basis for field development planning scenarios.