bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Cholinium Ionic Liquids as Cheap and Reusable Catalysts for the Synthesis of Coumarins via Pechmann Reaction under Solvent‐Free Conditions.
Authors: Zhang Yuehua , Zhu Anlian , Li Qianqian , Li Lingjun , Zhao Yang , Wang Jianji 
Published: December 2014

AbstractA cheap and reusable cholinium ionic liquid efficiently catalyzes the Pechmann condensation reaction of phenol derivatives with β‐keto esters to form coumarin derivatives.
ChemInform Abstract: Two‐Step Synthesis of Multi‐Substituted Amines by Using an N‐Methoxy Group as a Reactivity Control Element.
Authors: Yoritate Makoto , Meguro Tatsuhiko , Matsuo Naoya , Shirokane Kenji , Sato Takaaki , Chida Noritaka 
Published: December 2014

AbstractThe development of a two‐step synthesis of multi‐substituted N‐methoxyamines from N‐methoxyamides is reported in which the N‐methoxy group ensures the success in this two‐step procedure.
ChemInform Abstract: Broensted Acid Catalyzed Benzylic C—H Bond Functionalization of Azaarenes: Nucleophilic Addition to Nitroso Compounds.
Authors: Gao Xu , Zhang Feng , Deng Guojun , Yang Luo 
Published: December 2014

AbstractAn efficient reaction of benzylic C‐H bonds on azaarenes is developed using the nucleophilic addition of nitrosoarenes to afford azaarene‐2‐aldimines in good yields.
ChemInform Abstract: Palladium‐Catalyzed Synthesis of Isoindoloquinazolinones via Dicarbonylation of 1,2‐Dibromoarenes.
Authors: Chen Jianbin , Neumann Helfried , Beller Matthias , Wu Xiao‐Feng 
Published: December 2014

AbstractThe first examples of a carbonylative synthesis of isoindoloquinazolinones are given (10 examples).
ChemInform Abstract: Access to Pyridyl‐Substituted 1,3,5‐Triazines from 4H‐Pyrido[1,3]oxazin‐4‐ones via a Cyclocondensation Process.
Authors: Le Falher Laetitia , Ben Ayad Omar , Ziyaret Ozge , Mamontov Alexander , Botuha Candice , Thorimbert Serge , Slowinski Franck 
Published: December 2014

AbstractA broad spectrum of the desired triazine derivatives is available from 4H‐pyrido[1,3]oxazin‐4‐one substrates and amidines (used either as free base or salt) and microwave irradiation is found to be optimal for the procedure.
ChemInform Abstract: A New Triterpene Saponin from the Tubers of Stachys sieboldii
Authors: Cho Hyeon Kyung , Kim Chung Sub , Woo Kyeong Wan , Lee Kang Ro 
Published: December 2014

Abstractisolation and structure elucidation of a new triterpene saponin, Sieboldii saponin A (I), along with five known compounds
ChemInform Abstract: A New Noreudesmane‐Type Sesquiterpenoid from Alpinia oxyphylla
Authors: Park Dong Hyun , Lee Jin Woo , Jin Qinghao , Jeon Won Kyung , Lee Mi Kyeong , Hwang Bang Yeon 
Published: December 2014

Abstractisolation, structure determination, and inhibitory effects of the new noreudesmane‐type sesquiterpenoid 4‐methoxy‐oxyphyllenone A (I) and fifteen known compounds on NO production in LPS‐induced RAW 264.7 cells
ChemInform Abstract: Toward the Stereoselective Synthesis of C1—C23 Fragment of Spirastrellolide B.
Authors: Rajesh Akkapalli , Sharma Gangavaram V. M. , Damera Krishna 
Published: December 2014

AbstractThe key steps of the synthesis of the title fragment (I) are cross metathesis and Bu4NF promoted oxa‐Michael reaction.
ChemInform Abstract: Synthesis of Four Diastereomers and Structural Revision of Tetradenolide.
Authors: Tokuda Maki , Kurogome Yuji , Katoh Rieko , Nohara Yukie , Hattori Yasunao , Makabe Hidefumi 
Published: December 2014

AbstractFour diastereomers (I), (II) of tetradenolide are prepared.
ChemInform Abstract: Synthesis, Characterization, and Tribological Properties of Two‐Dimensional Ti3C2.
Authors: Yang Jin , Chen Beibei , Song Haojie , Tang Hua , Li Changsheng 
Published: December 2014

AbstractTwo‐dimensional Ti3C2 is prepared by exfoliation of Ti3AlC2 powders (obtained by sintering of Ti, Al, and graphite at 1350 °C for 2 h under flowing Ar) with HF solution at room temperature for 20 h.
ChemInform Abstract: Formation of 4‐Hydroxyproline Derivatives via Intramolecular Cyclization of Amino Acids with Side Chain Epoxides
Authors: Krishnamurthy Suvratha , Arai Toru , Nishino Norikazu , Nakanishi Kanae , Kato Tamaki 
Published: December 2014

AbstractReview: 2 refs.
ChemInform Abstract: Synthesis and Characterization of N‐Substituted (S)‐1,2,3,4‐Tetrahydroisoquinoline‐3‐carboxamides and Thioamides as Organocatalysts for Asymmetric Aldol Reaction.
Authors: Drabina Pavel , Androvic Ladislav , Panov Illia , Harmand Lydie , Padelkova Zdenka , Sedlak Milos 
Published: December 2014

AbstractTitle compounds (I) are synthesized and tested as catalysts for aldol reaction of nitrobenzaldehyde (II) with acetone.
ChemInform Abstract: Pd(dba)2 vs Pd2(dba)3: An in‐Depth Comparison of Catalytic Reactivity and Mechanism via Mixed‐Ligand Promoted C—N and C—S Coupling Reactions.
Authors: Cong Mei , Fan Yuting , Raimundo Jean‐Manuel , Tang Jingjie , Peng Ling 
Published: December 2014

AbstractThe analogous mechanisms leading to the related performance of Pd(dba)2 and Pd2(dba)3, respectively, in catalyzing C—N and C—S coupling reactions are demonstrated with the aid of mixed ligand catalytic systems.
ChemInform Abstract: Stereoselective Transformations of α‐Trifluoromethylated Ketoximes to Optically Active Amines by Enzyme—Nanometal Cocatalysis: Synthesis of (S)‐Inhibitor of Phenylethanolamine N‐Methyltransferase.
Authors: Cheng Guilin , Wu Qi , Shang Zeyu , Liang Xinhua , Lin Xianfu 
Published: December 2014

AbstractThe asymmetric synthesis of α‐trifluoromethyl amides is accomplished with an enzyme‐nanometal cocatalyst.
ChemInform Abstract: Cu(II)‐Catalyzed Asymmetric Boron Conjugate Addition to α,β‐Unsaturated Imines in Water.
Authors: Kitanosono Taku , Xu Pengyu , Isshiki Satoshi , Zhu Lei , Kobayashi Shu 
Published: December 2014

AbstractThe copper‐catalyzed enantioselective β‐borylation of α,β‐unsaturated imines (I) with bis(pinacolato)diboron followed by oxidation of intermediate boryl imines leads to β‐hydroxy imines (II) in high yields and excellent e.e.‐values (<99% e.e.).
ChemInform Abstract: Catalytic Intermolecular Alkene Oxyamination with Nitrenes.
Authors: Dequirez Geoffroy , Ciesielski Jennifer , Retailleau Pascal , Dauban Philippe 
Published: December 2014

AbstractThe addition reaction of the nitrene, generated from the sulfonamide (II), to a variety of olefins in the presence of acetic acid is studied to provide an efficient oxyamination process with complete regioselectivity.
ChemInform Abstract: CH2Cl2 as Reagent in the Synthesis of Methylene‐Bridged 3,3′‐bis(oxazolidin‐2‐one) Derivatives under Ambient Conditions.
Authors: Liu Qingfeng , Zhang Yansen , Zhang Zhiguo , Liu Tongxin , Shi Lei , Zhang Guisheng 
Published: December 2014

AbstractHighly efficient and facile NaH‐catalyzed condensation of CH2Cl2 with cyclic carbamates to form corresponding aminal derivatives in a solvent mixture of CH2Cl2 and DMF under ambient temperature is developed.
ChemInform Abstract: Homocoupling of Aryl Halides Promoted by an NiCl2/bpy/Mg System in DMF.
Authors: Yamamoto Takakazu 
Published: December 2014

AbstractIt is possible to apply the presented approach (NiCl2‐bipy‐Mg mixture in DMF) to prepare π‐conjugated polymers by starting from bisbromoarenes.
ChemInform Abstract: Taming Living Carbocations in Catalytic Direct Conjugate Addition of Simple Alkenes to α,β‐Enones.
Authors: Lv Jian , Zhong Xingren , Luo Sanzhong 
Published: December 2014

AbstractThe use of a BINOL derived phosphonic acid ester salt as the catalyst facilitates the selective β‐proton elimination by suppressing cationic olefin polymerization in direct alkene addition to enones to afford vinyl‐type adducts in high yields.
ChemInform Abstract: Magnetic CuFe2O4 Nanoparticles: A Retrievable Catalyst for Oxidative Amidation of Aldehydes with Amine Hydrochloride Salts.
Authors: Suresh Kumar A. , Thulasiram B. , Bala Laxmi S. , Rawat Vikas S. , Sreedhar B. 
Published: December 2014

AbstractThe use of amines as their salts is crucial.
ChemInform Abstract: A General Metal Free Approach to α‐Ketoamides via Oxidative Amidation—Diketonization of Terminal Alkynes.
Authors: Deshidi Ramesh , Kumar Manjeet , Devari Shekaraiah , Shah Bhahwal Ali 
Published: December 2014

AbstractIn the presence of trimethylsilyl triflate and catalytic amounts of iodine, the first metal free oxidative amidation—diketonization of terminal alkynes leads to a wide variety of α‐ketoamides.
ChemInform Abstract: Synthesis of α‐Ketoamides from Aryl Methyl Ketones and N,N‐Dimethylformamide via Copper‐Catalyzed Aerobic Oxidative Coupling.
Authors: Zhou Mingxin , Song Qiuling 
Published: December 2014

AbstractOther amides such as N,N‐diethylformamide, N‐formylmorpholine and N‐formylpiperidine provide the corresponding products in low yields.
ChemInform Abstract: Convenient Access to Cycloalk‐2‐enone‐Derived N‐Sulfonyl Imines.
Authors: Hirner Sebastian , Westmeier Johannes , Gebhardt Sandra , Mueller Christian H. , von Zezschwitz Paultheo 
Published: December 2014

AbstractTosylation of cyclohept‐2‐enone occurs with complete conversion, but yields an inseparable mixture of the desired imine and its tautomer cyclohept‐1,3‐dienyltosyl amide.
ChemInform Abstract: Cu(OAc)2 Promoted Chan—Evans—Lam C—N Cross Coupling Reactions on the N‐ and N′‐Nitrogen Atoms of Sulfonimidamides with Aryl Boronic Acids.
Authors: Nandi Ganesh C. , Kota Sudhakar R. , Govender Thavendran , Kruger Hendrik G. , Arvidsson Per I. 
Published: December 2014

AbstractA convenient and mild procedure for the N‐arylation of sulfonimidamides with various boronic acids is presented.
ChemInform Abstract: Syntheses of Thiol and Selenol Esters by Oxidative Coupling Reaction of Aldehydes with RYYR (Y: S, Se) under Metal‐Free Conditions.
Authors: He Chunhuan , Qian Xuewei , Sun Peipei 
Published: December 2014

AbstractSimple, atom‐economical and environmentally friendly route for the formation of C‐S and C‐Se bond based on the direct oxidative cross‐couplings of aldehydes with disulfides or diselenides under metal‐free conditions is developed.
ChemInform Abstract: Visible Light Organophotoredox Catalysis: A General Approach to β‐Keto Sulfoxidation of Alkenes.
Authors: Keshari Twinkle , Yadav Vinod K. , Srivastava Vishnu P. , Yadav Lal Dhar S. 
Published: December 2014

AbstractA mild, simple, metal‐free, direct, and rapid protocol for difunctionalization of alkenes using thiophenols and atmospheric oxygen is presented.
ChemInform Abstract: “Amano” Lipase DF‐Catalyzed Efficient Synthesis of 2,2′‐Arylmethylene Dicyclohexane‐1,3‐dione Derivatives in Anhydrous Media.
Authors: Jiang Ling , Wang Bo , Li Rong‐Rong , Shen Sa , Yu Hong‐Wei , Ye Li‐Dan 
Published: December 2014

AbstractHigh yields, mild reaction conditions, simple work‐up procedure and eco‐friendliness are the key features of the new protocol.
ChemInform Abstract: Palladium‐Catalyzed ortho‐Halogenation of Diaryl Oxime Ethers.
Authors: Bhattarai Bijay T. , Adhikari Sarju , Kimball Elizabeth A. , Moore Jane N. , Shaughnessy Kevin H. , Snowden Timothy S. , Fronczek Frank R. , Dolliver Debra D. 
Published: December 2014

AbstractThe Pd‐catalyzed halogenation of diaryl ketoxime ethers provides predominantly the corresponding ortho monohalogenated products (II) and (IV).
ChemInform Abstract: Chemoselective Aerobic Photo‐Oxidation of 9H‐Fluorenes for the Synthesis of 9‐Fluorenones.
Authors: Kojima Masahiro , Oisaki Kounosuke , Kanai Motomu 
Published: December 2014

AbstractThe novel protocol allows the aerobic photo‐oxidation of various substituted fluorenes under mild conditions.
ChemInform Abstract: Gold‐Catalyzed C(sp3)—H/C(sp)—H Coupling/Cyclization/Oxidative Alkynylation Sequence: A Powerful Strategy for the Synthesis of 3‐Alkynyl Polysubstituted Furans.
Authors: Ma Yuanhong , Zhang Shuai , Yang Shiping , Song Feijie , You Jingsong 
Published: December 2014

AbstractA series of 1,3‐dicarbonyl substrates is treated with various terminal alkynes under optimized conditions A) to produce the title compounds in a completely regioselective manner.
ChemInform Abstract: Highly Chemo‐, Enantio‐, and Regioselective Synthesis of α,α‐Disubstituted Furanones by Cu‐Catalyzed Conjugate Addition.
Authors: Endo Kohei , Yakeishi Sayuri , Takayama Ryotaro , Shibata Takanori 
Published: December 2014

AbstractAsymmetric Cu‐catalyzed conjugate addition of organoaluminum reagents to unsaturated ketoesters results in fast chemo‐, regio‐, and enantioselective synthesis of furanones bearing an α‐chiral quaternary stereocenter.
ChemInform Abstract: Multicomponent Azide—Alkyne Cycloaddition Catalyzed by Impregnated Bimetallic Nickel and Copper on Magnetite.
Authors: Perez Juana M. , Cano Rafael , Ramon Diego J. 
Published: December 2014

AbstractThe new catalyst is prepared in one step from CuCl2, NiCl2·H2O as well as Fe3O4.
ChemInform Abstract: Synthesis of Fluorinated Heteroaromatics Through Formal Substitution of a Nitro Group by Fluorine under Transition‐Metal‐Free Conditions.
Authors: Guo Ran‐Ning , Cai Xian‐Feng , Shi Lei , Chen Zhang‐Pei , Zhou Yong‐Gui 
Published: December 2014

AbstractThe novel one‐pot method allows the conversion of 3‐nitroquinolines into the corresponding 3‐fluoro derivatives via a dearomatization/fluorination/rearomatization sequence.
ChemInform Abstract: Cyclisation of Benzo[b]thiophen‐3(2H)‐one 1,1‐Dioxide and 1,3‐Indanedione into Novel Methylene Bridged Polycyclic Diazocines and Their Rearrangement into Spirocyclic Compounds.
Authors: Cekavicus Brigita , Vigante Brigita , Rucins Martins , Plotniece Aiva , Pajuste Karlis , Petrova Marina , Belyakov Sergey , Duburs Gunars , Sobolev Arkadij 
Published: December 2014

AbstractSubstrates (I) react with hexamethylenetetramine in acidic reaction medium to form methylene bridged polycyclic diazocines (III).
ChemInform Abstract: One‐Pot, Three Component Synthesis of Novel 5H‐[1,3,4]Thiadiazolo[3,2‐a]pyrimidine‐6‐carboxylate Derivatives by Microwave Irradiation.
Authors: Zhao Bing , Xu Yu , Deng Qi‐Gang , Liu Zhuo , Wang Li‐Yan , Gao Yan 
Published: December 2014

AbstractA facile catalyst‐free procedure for the reaction of thiadiazole (I) with aldehydes and β‐ketoesters to form the title species in good yields is developed.
ChemInform Abstract: Synthesis of 1‐Benzyloxypyrazin‐2(1H)‐one Derivatives.
Authors: Mai Anh Hung , Pawar Sonalika , De Borggraeve Wim M. 
Published: December 2014

AbstractDifferent approaches are utilized for the synthesis of a large range of 1‐benzoyloxypyrazinone derivatives (33 examples) starting from amino acids (I) and (VI).
ChemInform Abstract: Silica‐Supported Tripod Triarylphosphines: Application to Palladium‐Catalyzed Borylation of Chloroarenes.
Authors: Iwai Tomohiro , Harada Tomoya , Tanaka Ryotaro , Sawamura Masaya 
Published: December 2014

AbstractThe presented system is applicable to one‐pot biaryl synthesis of biphenyl derivative (V) via Miyaura borylation—Suzuki coupling sequence.
ChemInform Abstract: Iridoid Glycosides from Lagotis alutacea.
Authors: Yang Li‐Juan , Zhang Na , Liu Na , Yang Xiao‐Dong 
Published: December 2014

AbstractThe new iridoid glycoside, lagotisoside F (I), and three known analogs are isolated and evaluated for their cytotoxic activities against HL‐60, MCF‐7, A549, SW480, and SMMC‐7721 cells.
ChemInform Abstract: A Concise Total Synthesis of Puberulic Acid, a Potent Antimalarial Agent.
Authors: Sennari Goh , Hirose Tomoyasu , Iwatsuki Masato , Omura Satoshi , Sunazuka Toshiaki 
Published: December 2014

AbstractPuberulic acid (I) is prepared from D‐(+)‐galactose in eight steps and with 54% overall yield.
ChemInform Abstract: Total Synthesis of Fluoxetine and Duloxetine Through an in situ Imine Formation/Borylation/Transimination and Reduction Approach.
Authors: Calow Adam D. J. , Fernandez Elena , Whiting Andrew 
Published: December 2014

AbstractAn efficient, catalytic, asymmetric route to both (R)‐fluoxetine (II) and (S)‐duloxetine (IV) through the asymmetric copper‐mediated β‐borylation of α,β‐unsaturated imines is developed.
ChemInform Abstract: Diversity‐Oriented Synthesis of Medicinally Important 1,2,3,4‐Tetrahydroisoquinoline‐3‐carboxylic Acid (Tic) Derivatives and Higher Analogues
Authors: Kotha Sambasivarao , Deodhar Deepak , Khedkar Priti 
Published: December 2014

AbstractReview: [103 refs.
Protective effect of bisphosphonates on endometrial cancer incidence in data from the Prostate, Lung, Colorectal and Ovarian (PLCO) cancer screening trial
Authors: Alford Sharon Hensley , Rattan Ramandeep , Buekers Thomas E. , Munkarah Adnan R. 
Published: December 2014

BACKGROUNDPreclinical studies have demonstrated antitumor effects of bisphosphonates. The objective of the current study was to determine the effect of exposure to bisphosphonate on the incidence of endometrial cancer.METHODSThe authors used data from the National Cancer Institute's Prostate, Lung, Colorectal and Ovarian (PLCO) Cancer Screening Trial, which collected data on all cancers. In year 5, all participants were asked to complete a self‐administered supplemental questionnaire (SQX) that included questions regarding bone medication use. For women without a cancer diagnosis at the time of the SQX, the authors identified whether a woman reported current or former use of a nitrogenous bisphosphonate (NBP), defined as ever‐use, and compared them with women never exposed to an NBP. Women with missing information were excluded as were women who reported undergoing a hysterectomy. Incidence rates and rate ratios were calculated with 95% confidence intervals (95% CIs). Cox proportional hazard ratios were also calculated and adjusted for covariates.RESULTSA total of 29,254 women were included in the current analysis; an additional 77 cases of endometrial cancer have been diagnosed since the SQX. The incidence rate for endometrial cancer among women exposed to NBPs was 8.7 per 10,000 person‐years versus 17.7 per 10,000 person‐years among never‐exposed women (rate ratio, 0.49; 95% CI, 0.30‐0.80). The effect was similar after adjusting for all the covariates in the Cox proportional hazards analysis, with a hazard ratio of 0.56 (95% CI, 0.34‐0.93).CONCLUSIONSThe results of the current study suggest that use of NBPs may have a protective effect on the incidence of endometrial cancer. However, additional studies are needed that include other potential confounders and a larger sample. Cancer 2015;121:441–447. © 2014 American Cancer Society.
Lanthanide‐Doped Nanocrystals: Strategies for Improving the Efficiency of Upconversion Emission and Their Physical Understanding
Authors: Kar Arik , Kundu Simanta , Patra Amitava 
Published: December 2014

AbstractThe fundamental understanding of lanthanide‐doped upconverted nanocrystals remains a frontier area of research because of potential applications in photonics and biophotonics. Recent studies have revealed that upconversion luminescence dynamics depend on host crystal structure, size of the nanocrystals, dopant concentration, and core–shell structures, which influence site symmetry and the distribution and energy migration of the dopant ions. In this review, we bring to light the influences of doping/co‐doping concentration, crystal phase, crystal size of the host, and core–shell structure on the efficiency of upconversion emission. Furthermore, the lattice strain, due to a change in the crystal phase and by the core–shell structure, strongly influences the upconversion emission intensity. Analysis suggests that the local environment of the ion plays the most significant role in modification of radiative and nonradiative relaxation mechanisms of overall upconversion emission properties. Finally, an outlook on the prospects of this research field is given.
Zero‐forcing and codebook based beamforming scheme for practical usage of multiuser MIMO‐OFDM with uplink channel sounding
Authors: Lee Byung Moo , Kim Youngok 
Published: December 2014

SummarySince the concept of the multiuser multiple input multiple output (MU‐MIMO) system has been introduced for enhancement of capacity and flexibility, it has been accepted in various wireless standards. To enjoy the benefits of the MU‐MIMO system, full or partial channel information is necessary at the transmitter, but how to use the full or partial feedback information in the practical system perspective has not been investigated well. In this paper, we analyze the interference of full usage concurrent transmission codebook based on the MU‐MIMO systems and also investigate the usage of channel information for a codebook based scheme and a zero‐forcing beamforming (ZFBF) scheme. Based on the analytic results, we propose two adaptive schemes for the practical usage perspective in MU‐MIMO‐OFDM systems. Firstly, we propose an adjustable uplink channel sounding scheme, which depends on the number of users in a given cell/sector in frequency division duplexing system, with ZFBF MU‐MIMO‐OFDM systems. Secondly, we propose an adaptive switching scheme, which depends on signal‐to‐noise ratio, between the codebook based scheme and the ZFBF scheme. The performance of the proposed scheme is evaluated with computer simulations, and the simulation results show that the proposed scheme provides the enhanced throughput over entire signal‐to‐noise‐ratio regions. Copyright © 2014 John Wiley & Sons, Ltd.
Dual‐hormone treatment with insulin and glucagon in patients with type 1 diabetes
Authors: Reiband H. K. , Schmidt S. , Ranjan A. , Holst J. J. , Madsbad S. , Nørgaard K. 
Published: December 2014

SummaryIntensive insulin treatment in type 1 diabetes reduces the incidence and slows the progression of microvascular and macrovascular complications; however, it is associated with an increased risk of hypoglycaemia and weight gain. In this review, we propose dual‐hormone treatment with insulin and glucagon as a method for achieving near normalization of blood glucose levels without increasing hypoglycaemia frequency and weight gain. We briefly summarize glucagon pathophysiology in type 1 diabetes as well as the current applications of glucagon for the treatment of hypoglycaemia. Until now, the use of glucagon has been limited by the need for reconstitution immediately before use, because of instability of the available compounds; however, stabile compounds are soon to be launched and will render long‐term intensive dual‐hormone treatment in type 1 diabetes possible. Copyright © 2014 John Wiley & Sons, Ltd.
A Click‐Functionalized Single‐Molecule Magnet Based on Cobalt(II) and Its Analogous Manganese(II) and Zinc(II) Compounds
Authors: Plenk Christian , Krause Jasmin , Rentschler Eva 
Published: December 2014

AbstractA mononuclear CoII single‐molecule magnet suitable for click chemistry was investigated. [M(oda)(aterpy)] complexes (oda2– = oxodiacetate, aterpy = 4′‐azido‐2,2′:6′,2″‐terpyridine) with M = MnII, ZnII, and CoII were synthesized as azide‐functionalized building blocks for the copper‐catalyzed azide–alkyne cycloaddition reaction. The required structural integrity of the complexes in solution was proven in great detail by using ESI‐MS and NMR spectroscopy. For the six‐coordinate [Co(oda)(aterpy)] complex, single‐molecule magnet behavior was confirmed with an effective energy barrier of 4.2 cm–1.