bluuebunny/crossref_metadata_2025_split huggingface dataset:
Some Cosmological Roots of Modern Architecture
Authors: Klein Rudolf 
Published: August 2014

Abstract
This paper investigates the links between some oriental cosmologies and modern architecture, stemming from major non-Western religions, such as Buddhism, Islam and Judaism as well as from Einstein’s theories. It analyses both the direct impact of these concepts, influencing modernism at a theoretical level, and their indirect impact through historic non-Western architecture, mainly Buddhist and Islamic. While modernist theoreticians and architects frequently emphasised functional and technical priorities of modernism, I argue that modernism was far less rational than it is commonly thought, and that it was substantially influenced by non-Western thought, particularly in its early period.
This paper considers two main innovations of modernism resulting from oriental concepts of void: (1) the flat and undecorated façade, the avoidance of traditional ‘façade-discourse’, (2) the promotion of space as the main objective of architecture. The impact of Buddhist, Islamic, Judaic and the Einstenian cosmologies on modernism are considered
Surgical repair of a severely comminuted maxillary fracture in a dog with a titanium locking plate system
Authors: Illukka E. , Boudrieau R. J. 
Published: August 2014

SummaryA four-year old male Labrador Retriever was admitted with head trauma after being hit by a car. The dog had sustained multiple nasal, maxillary, and frontal bone fractures that resulted in separation of the maxilla from the base of the skull. A severely comminuted left zygomatic arch fracture was also present. These fractures were all repaired using a point contact, locking titanium plate system, in a single procedure that resulted in excellent postoperative occlusion and immediate function. Healing was uneventful. Full function and excellent cosmetic appearance were evident 13 months after surgery. This case illustrates the ease of repair and the success of treatment of severely comminuted maxillofacial fractures by conforming to basic biomechanical principles taken directly from the human experience and successfully applied to the dog; these included multiple plate application along the buttresses and trusses of the facial skeleton. The plate fixation was applied to bridge the multiple fractures along the most appropriate lines of stress. The small size of the plates, and the ability to easily contour them to adapt to the bone surface in threedimensions, allowed their placement in the most appropriate positions to achieve sufficient rigidity and lead to uncomplicated healing without any postoperative complications.
Working Memory, Situation Models, and Synesthesia
Authors: RADVANSKY GABRIEL A. , GIBSON BRADLEY S. , MCNERNEY M. WINDY 
Published: August 2014

Abstract
Research on language comprehension suggests a strong relationship between working memory span measures and language comprehension. However, there is also evidence that this relationship weakens at higher levels of comprehension, such as the situation model level. The current study explored this relationship by comparing 10 grapheme–color synesthetes who have additional color experiences when they read words that begin with different letters and 48 normal controls on a number of tests of complex working memory capacity and processing at the situation model level. On all tests of working memory capacity, the synesthetes outperformed the controls. Importantly, there was no carryover benefit for the synesthetes for processing at the situation model level. This reinforces the idea that although some aspects of language comprehension are related to working memory span scores, this applies less directly to situation model levels. This suggests that theories of working memory must take into account this limitation, and the working memory processes that are involved in situation model construction and processing must be derived.
Ethics Under Uncertainty: The Morality and Appropriateness of Utilitarianism When Outcomes Are Uncertain
Authors: KORTENK AMP KATHERINE V. , MOORE COLLEEN F. 
Published: August 2014

Abstract
Real-life moral dilemmas inevitably involve uncertainty, yet research has not considered how uncertainty affects utilitarian moral judgments. In addition, even though moral dilemma researchers regularly ask respondents, “What is appropriate?” but interpret it to mean, “What is moral?,” little research has examined whether a difference exists between asking these 2 types of questions. In this study, 140 college students read moral dilemmas that contained certain or uncertain consequences and then responded as to whether it was appropriate and whether it was moral to kill 1 to save many (a utilitarian choice). Ratings of the appropriateness and morality of the utilitarian choice were lower under uncertainty than certainty. A follow-up experiment found that these results could not be explained entirely by a change in the expected values of the outcomes or a desire to avoid the worst-case scenario. In addition, the utilitarian choice to kill 1 to save many was rated as more appropriate than moral. The results imply that moral decision making may depend critically on whether uncertainties in outcomes are admitted and whether people are asked about appropriateness or morality.
Cell‐Anchored Lead‐Free Piezoelectric KNN NPs Resisting Washout for Low‐Intensity Ultrasound Driven Neuromodulation
Authors: Zhang Yusheng , Jiang Junzhong , Xie Xianwei , Jiang Laiming , Wu Chengheng , Sun Jing , Zheng Ting , Fan Hongsong , Wu Jiagang 
Published: August 2024

AbstractPiezoelectric nanomaterials for wireless neuromodulation is a promising alternative to traditional electrical stimulation. However, the low‐avidity between piezoelectric nanomaterials and cellular membranes leads to low efficiency of electrical signal transmission, which requires high‐intensity thresholds of ultrasound stimulation (US). Here, lead‐free piezoelectric (K,Na)NbO3 (KNN) nanoparticles (NPs) with cholesterol coating (KNNC) are presented, in which Cholesterol can be accommodated in the membrane and make them append on the plasma membrane. Compared to non‐modified nanoparticles, cell‐anchored KNNC NPs highly resist convective washout owing to high affinity of cholesterol to biological membranes, which enables highly efficient wireless electrical stimulation to activate cell impulses under low‐intensity ultrasound. Meanwhile, after perfusion washing, the KNNC NPs distributed around the cells are washed away, while part of KNNC NPs remain on the surface of cell membrane still can induce significant Ca2+ influx under US, similar to the group without washing, indicating the KNNC NPs appended on the cell play a major role in wireless electrical stimulation. Furthermore, the highly efficient electrical transmission of KNNC enables neural differentiation of stem cells in regulating synaptic plasticity by modulating Ca2+ influx, demonstrating that KNNC NPs offer a perspective toward minimally invasive wireless neuromodulation therapies for neurological diseases.
Near‐Zero Segregation on Strongly Exciton Confined Mixed Halide Perovskites Quantum Dots via Octahedron Alloying Reconstruction Engineering
Authors: Lian Huiwang , Kuang Rongyi , Zhu Yunfei , Gao Meng , Gu Simin , Li Yang , Wang Jing 
Published: August 2024

AbstractThe state‐of‐the‐art mixed‐halide perovskite (MHP) quantum dots (QDs) open up promising applications in photovoltaic and optoelectronic communities, yet are limited by huge halide segregation. In contrast to the previous A‐site alloy method, customizing other octahedral units for replacing the fundamental optoelectronic unit of [PbX6]4− (X = Cl, Br, or I), the so‐called B‐site alloying strategy, is expected to inhibit halide segregation fully. Here, a halide octahedron alloying reconstruction engineering is reported to fabricate MHP QDs with near‐zero halide segregation due to their strongly confined excitons. This unprecedented regime is obtained at a water–oil interfacial reaction system using amino‐silane ion exchange accelerator and transition metal hydroxy‐halides salts, introducing abundant [MX6]4− (M = Zn, Ni, Co, Mn, and Cu) octahedron block and finally fabricating transition metal‐alloyed MAPbX3 QDs. Photo‐induced excitons in strongly dielectric‐confined Zn‐alloyed perovskite QDs are hardly thermally dissociated and transferred, as featured by ultra‐high exciton binding energy (Eb), fast fluorescence lifetimes (τavg), and near 100% photoluminescence quantum yield (PLQY). The fabricated mixed‐halide MAPb1‐xZnxX3 QDs with reduced Pb content over 40% exhibit near‐zero halide segregation, marking the emergence of a practical solution to the detrimental segregation problem, which paves the wave for emerging solar cells and lighting display applications.
Effect of Molecular Conformation on Intermolecular Interactions and Photovoltaic Performances of Giant Molecule Acceptors
Authors: Zhuo Hongmei , Li Xiaojun , Qin Shucheng , Zhang Jinyuan , Gong Yufei , Wu Yilei , Zou Tianwei , Chen Zekun , Yin Kaige , Yuan Meng , Li Jing , Meng Lei , Li Yongfang 
Published: August 2024

AbstractThe molecular conformation of giant molecule acceptors (GMAs) plays a significant role in regulating the intermolecular interactions and their photovoltaic performances in organic solar cells (OSCs). For the linear GMA GT‐l, the stronger homo‐molecular interaction causes its aggregation being weakly affected by the donor, thus forming an ordered molecular stacking and proper phase separation in its blend film. The star‐shaped GMA GT‐s‐based blend film shows a dominant hetero‐molecular interaction that suppresses the aggregation of the donor and acceptor, resulting in smaller phase separation and more uniform vertical phase distribution. While for another star‐shaped GMA GTs, the weakest hetero‐molecular interaction causes its blend film to form larger phase separation. Therefore, the GT‐l based OSC with PM6 as donor shows the highest charge mobilities, the fastest charge transfer (CT) process, reduced energy loss and less charge recombination, contributing to a higher power conversion efficiency (PCE) of 19.03%. Comparatively, the PCEs of the OSCs based on GTs and GT‐s are 18.05% and 17.58% respectively. Notably, all the three GMAs based OSCs show excellent thermal stability and long‐term storage stability. This study provides a facile strategy by tuning the linking unit and its connecting mode for designing highly efficient and stable organic photovoltaic materials.
Enhancement of Electromagnetic Wave Attenuation through Polarization Loss Induced by Hybridization of Rare‐Earth 4f and Mo‐4d Orbitals in Liquid Plasma
Authors: Wen Jiaming , Hui Shengchong , Chang Qing , Chen Geng , Zhang Limin , Fan Xiaomeng , Tao Kai , Wu Hongjing 
Published: August 2024

AbstractThe incorporation of large‐sized rare earth (RE) elements with high coordination characteristics into transition metal dichalcogenide (TMD) absorbers while preserving a high 1T phase content during post‐processing poses a significant challenge. To address this, a novel strategy involving the confinement of RE elements within the 1T‐MoS2 lattice via liquid plasma assistance, is proposed. This approach effectively mitigates the environmental impact on the 1T phase of MoS2, yielding a remarkable 1T phase content of 82.69% for Ce20‐D7 (20 wt.% Cerium trinitrate and 7 kV applied voltage). Combining experimental and theoretical investigations reveals that the multi‐orbital characteristics of RE elements facilitate hybridization between the RE‐4f and Mo‐4d orbitals on the MoS2 surface, leading to the occupation of weakly bound electrons in bonding orbitals with short‐distance motion, enhanced inter‐orbital electron‐electron interactions, and induced polarization loss. Notably, the results demonstrate that the Pr15‐D7 sample (15 wt.% praseodymium nitrate and 7 kV applied voltage) exhibits an effective absorption bandwidth (EAB) of 7.12 GHz at 2.6 mm, with a minimum reflection loss of ‐52.02 dB while the Ce20‐D7 sample achieves an EAB of 6.96 GHz at 2.7 mm. These findings provide valuable insights for the rational design and development of high‐performance TMD absorbers leveraging RE‐modified materials.
Biomimetic Tumor Cell Membrane‐Encapsulated Nanoparticles Combine NIR‐II Photothermal Therapy and Chemotherapy for Enhanced Immunotherapy in Triple‐Negative Breast Cancer
Authors: Xiong Wei , Cheng Ziyi , Chen Hongwei , Liang Huixian , Wang Miao , Chen Yan , Ying Junyu , Cai Yizhou , Chai Jinxuan , Dou Kun , Zheng Wuping , Zheng Shaojiang , Zhao Linlu 
Published: August 2024

AbstractTo advance the understanding and potential treatment strategies for triple‐negative breast cancer (TNBC), particularly focusing on its high metastatic propensity and uncertain molecular targets, a biomimetic tumor cell membrane‐encapsulated nanodelivery system is developed for enhanced immunotherapy. This system is assembled with the second near‐infrared (NIR‐II) photothermal agent, chemotherapeutic drug, and programmed death‐ligand 1 (PD‐L1) inhibitors camouflaged by TNBC cell membranes. An NIR‐II Ag2S quantum dots (QDs) is introduced for not only realizing pronounced imaging‐guided photothermal therapy (PTT), but also co‐activating immunogenic cell death (ICD) with chemotherapy. Homologous targeting and camouflage properties endowed the nanodelivery system with excellent biocompatibility and efficient delivery ability to the tumor site, demonstrating excellent synergistic therapeutic efficacy. The release of damage‐associated molecular patterns (DAMP) marked the induction of ICD, crucial for reshaping the immune microenvironment. Further integration of α‐PD‐L1 achieved a 56.5% immune checkpoint inhibition rate, synergistically amplifying immune response to ultimately activate key cytokines, thereby achieving pronounced anti‐tumor immunotherapy effects. Notably, this approach realized a considerable reduction of metastatic nodules by 51.2% in the TNBC lung metastasis model. The proposed nanodelivery system extended tumor remission and effectively reduced lung metastasis, paving the way for a reliable and promising approach in TNBC immunotherapy.
Diffusion of Carbon Quantum Dots on Lithium Liquid Metal for Artificial SEI
Authors: Liu Wenxin , Xie Tian , Wang Xianwen , Deng Wentao , Huang Lu , Khan Rashid , Wang Yan , Hou Hongshuai , Wang Dong , Wu Yingpeng 
Published: August 2024

AbstractThe unstable solid electrolyte interface (SEI) formed on the surface of Li metal can induce dendrite growth, resulting in capacity fading, battery short circuit, and other problems, thus hindering the practical application of Li metal battery. In order to obtain stable and effective SEI, it is an effective strategy to construct an ideal artificial SEI (ASEI) by regulating the composition and structure of the interface. Among the inorganic materials used in the construction of ASEI, carbon quantum dots (CQDs) stand out as promising material due to their small size and abundant active sites. Herein, benefiting from the fluidity, surface smoothness, and high reactivity of liquid metal, combined with the use of N‐doped CQDs as dispersing particles, a surface modification method to achieve uniform dispersion of particles within the liquid metal is proposed. This technique offers a low‐cost solution for achieving uniform dispersion of little quantities of N‐doped CQDs (single dose < 0.1 mg cm−2) while ensuring enhanced interface adhesion to realize the construction of dense, strong and uniform ASEI. The corresponding symmetrical cells show lower voltage polarization and outstanding cycling stability than the bare Li electrode.
Manipulating Interfacial Renovation via In Situ Formed Metal Fluoride Heterogeneous Protective Layer toward Exceptional Durable Sodium Metal Anodes
Authors: Guo Jia , Li Yue , Xu Kang , Huang Ziling , Hu Weijiang , Tan Yajun , Sun Chencheng , Yang Jun , Geng Hongbo 
Published: August 2024

AbstractSodium metal is regarded as an optimal anode material for high‐energy‐density sodium‐ion batteries (SIBs). However, during the processes of sodium deposition and stripping, the failure of the solid electrolyte interphase (SEI) film leads to the continuous accumulation of inactive sodium, thereby compromising the cycling reversibility of the battery. Here, a novel metal fluoride heterointerface layer is generated and constructed through in situ manipulation of the continuous reaction between TiF4 and metal Na. The reconstructed NaF/TiF3 interface layer, which tightly anchors the sodium metal, effectively suppresses the formation of sodium dendrites during the charge‐discharge process. The highly sodium‐philic TiF3 component exhibits strong binding with Na ions, while NaF reduces the Na+ diffusion energy barrier, significantly enhancing the reaction kinetics. Due to the successful artificial construction of this interface layer, the Na/TiF4 composite electrode demonstrates an exceptional ultra‐long cycling stability of 2370 h in symmetric cells (0.5 mAh cm−2). Density functional theory (DFT) calculations further validate the functionality of each component in the Na/TiF4 protective layer. When paired with NaNi1/3Fe1/3Mn1/3O2 cathode in a pouch cell, it exhibits stability up to 2000 cycles at current densities of 2 C and 4 C, with a maximum energy density output of 483.1 Wh kg−1 (power density: 320.8 W kg−1).
High‐Entropy Design Toward Ultrahigh Energy Storage Density Under Moderate Electric Field in Bulk Lead‐Free Ceramics
Authors: Zhao Hanyu , Cao Wenjun , Liang Cen , Wang Changyuan , Wang Chunchang , Cheng Zhenxiang 
Published: August 2024

AbstractElectrostatic capacitors with ultrahigh energy‐storage density are crucial for the miniaturization of pulsed power devices. A long‐standing challenge is developing dielectric materials that achieve ultrahigh recoverable energy density Wrec ≥ 10 J cm−3 under moderate electric fields (30 ≤ E ≤ 50 kV mm−1). Herein, a specific high‐entropy strategy is proposed to modulate the phase structure and interfacial polarization of medium‐entropy base materials using linear dielectrics. This strategy ensures a sufficient polar phase and a high enough electric field for complete polarization, thereby achieving ultrahigh Wrec by enhancing polarization strength. The validity of this strategy is demonstrated in the (Na0.282Bi0.282Ba0.036Sr0.28Nd0.08)TiO3‐xCa0.7Bi0.2TiO3 (NBBSNT‐xCBT) (x = 0–0.15) system. The CBT‐modulated samples exhibit a polyphase structure of R3c, P4bm, and Pm‐3m with reduced remnant polarization (Pr). Additionally, the addition of CBT effectively suppresses interfacial polarization, enhancing the maximum polarization (Pmax). These factors significantly improve the value of ∆P = Pmax − Pr. As a result, an ultrahigh Wrec of 10.5 J cm−3 with a high‐efficiency η of 80.3% is obtained in the x = 0.1 sample under a moderate electric field of 45 kV mm−1 for the first time. This work paves the way for achieving superior energy‐storage performance under moderate electric fields.
Facile Fabrication of Highly Crystallized, Air‐Stable, and Flexible Perovskite Micromesh Film Photodetector
Authors: Xiong Yuting , Chen Bo , Xu Xiuzhen , Dai Shijie , Zhan Yiqiang , Xu Xiaobin 
Published: August 2024

AbstractPerovskite materials such as organic‐inorganic MAPbX3 (X = Cl, I, Br) have attracted broad interests in photoelectric applications, such as image sensors and photovoltaics. Here, a facile and general approach, called soft‐print solvent‐assisted evaporation crystallization (SSEC) is reported, for fabrication of highly crystallized, air‐stable, and flexible perovskite micromesh films, including organic–inorganic (MAPbX3) and inorganic (CsPbX3) perovskite. Scanning and transmission electron microscopy (SEM/TEM) characterization reveals their high crystallinity without obvious grain boundaries. The photodetectors constructed based on MAPbI3 micromesh films exhibit a typical responsivity of ≈352 A W−1 and detectivity of ≈5.7 × 1013 Jones (at 650 nm in wavelength). The MAPbI3 micromesh film also shows good mechanical stability when bended at different bending radius, and after 800 bending cycles, they still exhibit highly reproducible photocurrent and on/off switching ratios. Furthermore, they are also air‐stable that they can survive for >20 days in high humid environments (65–75%) with <10% reduction in photocurrent. This work provides a facile and scalable approach for fabrication of highly crystallized, stable, and flexible perovskite micromesh films for a variety of optoelectronic applications with improved performance and durability.
A Compact, Portable Device for Microscopic Magnetic Imaging Based on Diamond Quantum Sensors
Authors: Shaji Alex , Rietwyk Kevin J. , Robertson Islay O. , Reineck Philipp , Broadway David A. , Tetienne Jean‐Philippe 
Published: August 2024

AbstractMagnetic imaging based on ensembles of diamond nitrogen‐vacancy quantum sensors has emerged as a useful technique for the spatial characterization of magnetic materials and current distributions. However, demonstrations have so far been restricted to laboratory‐based experiments using relatively bulky apparatus and requiring manual handling of the diamond sensing element, hampering broader adoption of the technique. Here a simple, compact device that can be deployed outside a laboratory environment and enables robust, simplified operation is presented. It relies on a specially designed sensor head that directly integrates the diamond sensor while incorporating a microwave antenna and all necessary optical components. This integrated sensor head is complemented by a small control unit and a laptop computer that displays the resulting magnetic image. The device is tested by imaging a magnetic sample, demonstrating a spatial resolution of 4 µm over a field of view exceeding 1 mm, and a best sensitivity of 45 µT per (5 µm)2 pixel. The portable magnetic imaging instrument may find use in situations where taking the sample to be measured to a specialist lab is impractical or undesirable.
Efficient Ionovoltaic Energy Harvesting via Water‐Induced p–n Junction in Reduced Graphene Oxide
Authors: Cho Yong Hyun , Jin Minho , Jin Huding , Han Junghyup , Yu Seungyeon , Li Lianghui , Kim Youn Sang 
Published: August 2024

AbstractWater motion‐induced energy harvesting has emerged as a prominent means of facilitating renewable electricity from the interaction between nanostructured materials and water over the past decade. Despite the growing interest, comprehension of the intricate solid–liquid interfacial phenomena related to solid state physics remains elusive and serves as a hindrance to enhancing energy harvesting efficiency up to the practical level. Herein, the study introduces the energy harvester by utilizing inversion on the majority charge carrier in graphene materials upon interaction with water molecules. Specifically, various metal electrode configurations are employed on reduced graphene oxide (rGO) to unravel its distinctive charge carriers that experience the inversion in semiconductor type upon water contact, and exploit this characteristic to leverage the efficacy of generated electricity. Through the strategic arrangement of the metal electrodes on rGO membrane, the open‐circuit voltage (Voc) and short‐circuit current (Isc) have exhibited a remarkable augmentation, reaching 1.05 V and 31.6 µA, respectively. The demonstration of effectively tailoring carrier dynamics via electrode configuration expands the practicality by achieving high power density and elucidating how the water‐induced carrier density modulation occurs in 2D nanomaterials.