bluuebunny/crossref_metadata_2025_split huggingface dataset:
Microstructure, thermal and radiation shielding properties of aluminium‐silicon‐boron alloy prepared by mechanical alloying
Authors: Yaykaşlı H. , Eskalen H. , Göğebakan M. , Sünbül A. , Kavun Y. 
Published: August 2024

AbstractThis study focused on developing microstructural, thermal, and radiation shielding changes in Al50Si25B25 powders using mechanical alloying techniques. Based on the x‐ray powder diffraction data, the crystallite size and microstrain of the 100‐hours milled powder were calculated as 0.25 nm and 50.33 %, respectively. The solubility of silicon in the α‐aluminium matrix increased with longer mechanical alloying duration. Transmission electron microscope analyses further showed that the alloy particulates had an average size of 3 μm and an average grain size of 0.226 nm. The radiation shielding properties of the Al50Si25B25 powders indicated that the Linear Attenuation Coefficient value increased from 0.0554±0.1689 cm−1 to 1.0632±0.2425 cm−1 with an increase in the thickness of the Al50Si25B25 alloy. This work successfully demonstrated the potential of mechanical alloying techniques to enhance the microstructural and thermal properties of Al50Si25B25 powders. It highlighted their effectiveness in providing radiation shielding capabilities when varying the thickness of the alloy.
Utilisation of dolomite dust with pure epoxy resin: Physical, mechanical and erosion wear analysis
Authors: Verma S. K. , Gupta A. , Gangil B. 
Published: August 2024

AbstractUtilization of inorganic waste, if included in composite material, can be beneficial in reducing the accumulation of waste, which could help in resolving problems of disposal. beside from that, incorporating waste into composite materials also reduces the overall cost of the composites as a whole. The study examines the impact of dolomite content on the mechanical properties of the composites. Increasing the amount of dolomite in the composite significantly weakens its flexural strength, falling from 42.4 MPa at 0 % dolomite to 28.7 MPa at 15 % dolomite. Composite tensile strength also decreases by up to 25.8 % with rising dolomite dust concentration. Additionally, dolomite increases interlaminar shear strength (ILSS), with EDH15 composites showing the highest improvement. Dolomite dust in epoxy‐based composites increases the hardness value from 85 HRL to 95 HRL with an increase in dolomite dust content. The erosion test perform on air jet tester shows lowest wear rate was achieved under the following conditions: 10 % dolomite dust weight, 30° impingement angle, 10 m s−1 impact velocity, and 150 μm erodent size. Furthermore, scanning electron microscopy was used to examine the damaged, eroded surfaces for assumed wear mechanisms.
Technical note: Determination of CQ$C_{Q}$ for a miniature x‐ray source using a soft x‐ray ionization chamber calibrated in NIST reference beam qualities
Authors: Watson Peter G. F. , Davis Stephen , Culberson Wesley S. 
Published: August 2024

AbstractBackgroundThe formalism proposed by Watson et al. allows users of the INTRABEAM (Carl Zeiss Medical AG, Jena, Germany) electronic brachytherapy system to accurately determine the absorbed dose to water, in the absence of a primary dosimetry standard. However, all published values are for PTW 34013 ionization chambers calibrated in a TW30 reference beam, traceable to PTB (Germany). For North American users, it would be advantageous to have data for chambers calibrated in a kV reference beam maintained by the National Institute of Standards and Technology (NIST).PurposeIn this work, we determine for a PTW 34013 chamber calibrated in three NIST‐traceable reference beams: M30, L40, and L50.MethodsUsing available photon spectra data for M30, L40, and L50 reference beam qualities, Monte Carlo simulations using EGSnrc were performed to calculate the ratio of the absorbed dose to the PTW 34013 chamber air cavity to air‐kerma () for these beams. From this ratio, as a function of depth in water was determined. The effect of the use of a buildup foil was also investigated. An uncertainty analysis considering both the Type A and Type B uncertainties in the calculation of was performed.ResultsThe largest difference in was found between L50 and TW30, with a relative decrease of 1.4% (no buildup) to 1.6% (buildup). For M30 and L40, the differences were minimal compared with measurement uncertainties.ConclusionsWe report values for three NIST‐traceable kV reference beams. This study reinforces the feasibility of adapting the Watson et al. methodology using different kV reference beams, facilitating the use of INTRABEAM in North America and ensuring the continuity and accuracy of dosimetry standards in intraoperative radiation therapy.
On the importance of diversity in ecological research
Authors: Brunn Melanie , Billings Sharon A. , Birke Jonas , Brockmüller Svenja , Nielsen Mathias W. , Kilian Salas Simone , Oelmann Yvonne 
Published: August 2024

Societal Impact StatementProtecting diversity is critical to maintaining functional and adaptive ecosystems. However, research groups that explore these relationships tend to lack diversity themselves. To address the challenges of our changing world, it is crucial to consider a wide range of perspectives and knowledge. We propose that just as greater diversity in ecosystems relates to a variety of functions and, consequently, enhances resilience, stability, and efficiency, a comparable diversity within research teams results in a broader spectrum of creative endeavors. Thus, it is important to re‐evaluate our scientific communities' openness toward greater diversity to meet the diverse problems of our changing world.SummaryEcosystems face multiple threats, jeopardizing natural and human well‐being. Biodiversity loss can increase ecosystem vulnerability to global change, risking abrupt and irreversible changes. Protecting biodiversity can prevent ecosystems from crossing tipping points, preserving their functions and resilience, which sustain life on our planet. In addressing these challenges, society demands creativity, innovation, and diverse perspectives. Yet, our societal structures often neglect the full range of voices and experiences, limiting problem‐solving. Understanding how research teams with diverse demographics may stimulate creative solutions to global change challenges may help. In this context, we emphasize examples from plant ecology, where the advantages of diverse ecosystems are well recognized, and we draw an analogy of these features to the innovation of research teams. In ecosystems, biodiversity can maximize productivity and function but can also serve as a protective “insurance” against disruptions. Similarly, in a time of multifaceted environmental changes, diverse research groups play a critical and analogous role, resembling the biodiversity within ecosystems. Diverse research teams not only bring complementary strengths, fostering creative problem‐solving by embracing various perspectives, but also drive scientific innovation by integrating a wide range of research topics (e.g., ecosystems, taxa, and conservation priorities). These human‐centered dynamics are congruent with the mechanisms in ecosystems, with a diversity of solutions promoting resilience, stability, and efficiency, all of which ultimately provide a counterbalancing effect on global change. Much like biodiverse ecosystems, a diverse spectrum of knowledge, and expertise within the scientific community can enrich a dynamic landscape of innovation.
A novel mutation Trp‐2027‐Gly in acetyl‐CoA carboxylase confers resistance to cyhalofop‐butyl in Chinese sprangletop (Leptochloa chinensis)
Authors: Jiang Minghao , Wang Xumiao , Hu Wei , Wang Zezhou , Guan Huaiji , Zhao Ning , Liao Min , Cao Haiqun 
Published: August 2024

AbstractBACKGROUNDChinese sprangletop [Leptochloa chinensis (L.) Nees] control is threatened by resistance to acetyl‐CoA carboxylase (ACCase)‐inhibiting herbicides. In this study, a L. chinensis population, HFLJ18, that survived cyhalofop‐butyl [aryloxyphenoxypropionate (APP) herbicide, CyB] treatment was collected from a rice field in Lujiang County, Anhui Province, China. This study aimed to evaluate the susceptibility of HFLJ18 to herbicides with different modes‐of‐action and investigate the potential mechanisms of resistance to CyB.RESULTSThe HFLJ18 population exhibited high levels of resistance to CyB (10.92‐fold) and showed resistance to the ACCase inhibitors metamifop (4.63‐fold) and fenoxaprop‐P‐ethyl (8.39‐fold), but was susceptible to clethodim, pinoxaden, florpyrauxifen‐benzyl, oxadiazon and pretilachlor. Target gene sequencing revealed a novel Trp‐to‐Gly substitution at codon position 2027 of ACCase in the resistant plants. Molecular docking revealed that the spatial structure of ACCase changed significantly following the substitution, as indicated by reduced H‐bonds. A newly derived cleaved amplified polymorphic sequence (dCAPS) marker was subsequently developed to detect the Trp‐2027‐Gly mutation in the ACCase of L. chinensis. Additionally, pretreatment with the cytochrome P450 (P450) inhibitor piperonyl butoxide (PBO) and the glutathione S‐transferase (GST) inhibitor 4‐chloro‐7‐nitrobenzoxadiazole (NBD‐Cl) did not reverse resistance to CyB, suggesting that nontarget‐site resistance mechanisms were not involved in CyB resistance in the HFLJ18 population.CONCLUSIONOverall, the resistance to CyB in the HFLJ18 population derived from the mutation of ACCase gene, and to the best of our knowledge, this is the first report of the ACCase Trp‐2027‐Gly mutation conferring resistance to ACCase‐inhibiting herbicides in grass species. © 2024 Society of Chemical Industry.
Command filtering‐based adaptive backstepping control for a class of discrete‐time uncertain nonlinear systems with mismatched disturbances
Authors: Sun Aoyu , Zhao Lin 
Published: August 2024

SummaryThis paper investigates the adaptive fuzzy backstepping control problem for uncertain discrete‐time nonlinear systems with mismatched disturbances. A novel adaptive fuzzy command filtered backstepping approach is proposed, which can overcome the noncausal problem by using the command filter. The filter errors generated by filter are removed by constructing error compensation mechanism. The fuzzy logic systems are used to approximate the uncertain nonlinear dynamics, and the unknown mismatched disturbances are actively attenuated by using adaptive control technique. Based on the proposed new weighed Lyapunov functions, all the signals in the close‐loop system are proved to be uniformly ultimately bounded. The viability of proposed method is demonstrated by simulation results.
Co3O4@SiO2 3D Monolith Catalysts, Additive Manufactured Structures for Propane Oxidation Reaction
Authors: Daza‐Gómez Lucy‐Caterine , Pérez Salas Karen Yesenia , Ruiz‐Huerta Leopoldo , García Peña Nidia G. , Maturano Rojas Viridiana , Redón Rocío 
Published: August 2024

AbstractIn this study, we successfully fabricated a three‐dimensional Co3O4@SiO2 3D Monolith catalyst. This process allowed for the effective and straightforward anchoring of Co3O4 nanoparticles onto SiO2 3D Monoliths. The active Co3O4 phase was primarily identified through XRD and XPS analyses, complemented by Co3O4 loading measurements (1.7 %). This innovative catalyst displayed remarkable proficiency in selectively converting propane to carbon dioxide. Additionally, it was demonstrated that the catalytic activity remained unimpaired even upon the catalyst's reuse in 5 successive reaction cycles. This performance was observed across various heating ramps, showcasing the catalyst's stability over time.
Study on the Pyrolysis and Incineration of Lewisite by Thermodynamic Equilibrium Calculation
Authors: Liu Xuefeng , Zhang Yuanpeng , Yang Lin , Song Weiwei , Wang Haitao 
Published: August 2024

AbstractLewisite is a representative chemical warfare agent that contains arsenic. Thermal decomposition is an essential method for Lewisite destruction, and appropriate destruction conditions can enhance the environmental friendliness of this method by minimizing the hazards of destruction products. In this study, the variation of Lewisite during pyrolysis and incineration was calculated, with particular emphasis on the evolution behaviors of arsenic and chloride with temperature, pressure, and molar ratio. The main products identified during pyrolysis were HCl(g), C, As, and AsCl3(g). Under anoxic conditions, AsCl3(g) and As were the dominant species. In oxygen‐enriched conditions, arsenic existed primarily as AsCl3(g), As2O5, As2O4, and AsOCl. Below 600 °C, arsenic predominantly existed in high valence forms such as As2O5. Above 600 °C, the binding capacity of chlorine and arsenic was stronger than that of oxygen, resulting in an AsCl3(g) molar fraction exceeding 75 % at 1200 °C. The primary chlorides in oxygen‐enriched conditions were Cl2(g), HCl(g), AsCl3(g), and Cl(g). Lower incineration temperatures (around 500 °C), sufficient oxygen conditions (molar ratio above 4 : 1), and positive pressures were conducive to reducing the toxicity of destruction products. The results are in good agreement with the experimental data.
Construction of a Double Z‐Scheme CuO/Cu2O/CuS/ZnO Quaternary Heterojunction Photocatalyst with Enhanced Solar‐Driven Photocatalytic Performance for Sulfamethoxazole Degradation
Authors: Zhu Wenli , Du Juan , Yang Qiaoling 
Published: August 2024

AbstractA novel CuO/Cu2O/CuS/ZnO quaternary heterojunction photocatalyst was constructed through a facile microwave technique. The structure, morphology and optical properties were characterized and explored. The photocatalytic activity of CuO/Cu2O/CuS/ZnO quaternary composite was assessed by antibiotic sulfamethoxazole under the simulated solar light irradiation. The quaternary composite manifested more excellent photocatalytic performance than the pristine ZnS and CuO/Cu2O. Moreover, the effects of ascorbic acid concentration on removal efficiency of sulfamethoxazole were discussed, revealing the importance of Cu2O in sulfamethoxazole removal. Particularly, as the ascorbic acid was 0.50 M, the total removal efficiency of sulfamethoxazole at an initial concentration of 20 mg/L was approximately 99.17 %, and the fitted pseudo‐first‐order kinetic rate constant reached 0.0380/min, which were 1.73 and 6.91 times of that in the absence of ascorbic acid, respectively. A double Z‐scheme charge transfer mechanism was confirmed by the reactive species trapping tests, which demonstrated that superoxide radicals and holes were the major reactive species responsible for sulfamethoxazol degradation. CuO/Cu2O/CuS/ZnO nanocomposite provided an interesting perspective for a highly efficient quaternary photocatalyst that could be employed for remediation antibiotics.
Enhanced CO2 Methanation over Nickel‐Based Unsupported Catalyst Synthesized by Chemical Precipitation Method
Authors: Kumar Choudhary Abhay , Yadav Sudeep , Kumar Gupta Pavan 
Published: August 2024

AbstractThis study investigated the catalytic CO2 methanation using nickel oxide (NiO) nanoparticles and nickel oxalate (NiC2O4) as catalysts. The NiC2O4 precursor was synthesized through a chemical precipitation reaction between nickel (II) nitrate hexahydrate (Ni(NO3)2.6H2O) and oxalic acid (H2C2O4.2H2O). Nickel oxide (NiO) nanoparticles were synthesized through thermal decomposition of NiC2O4 precursor at 450 °C in air. The samples were characterized by XRD, FTIR, BET, SEM, and EDX. The XRD and FTIR analyses revealed that the NiO nanoparticles were well‐crystallized having size 17.30 nm. The BET analysis of the NiO sample revealed mesoporous NiO nanoparticles with a specific surface area (SBET) of 29.08 m2/g and a narrow distribution of pore sizes. The catalytic performance of NiO and NiC2O4 catalysts studied for the CO2 methanation in tubular packed bed reactor at 150–550 °C and 1 atm. The reduced NiO nanoparticles exhibited more catalytic activity than the decomposed NiC2O4 catalyst. At 380 °C, 1 atm, and gas hourly space velocity (GHSV) of 9000 mL g−1 h−1, the reduced NiO nanoparticle catalyst showed high catalytic activity, with a maximum CO2 conversion of 85.54 %, 99 % CH4 selectivity, and 84.69 % CH4 yield. Furthermore, the NiO nanoparticle catalyst demonstrated excellent stability after 12 h of streaming at 380 °C.
Formation of Bis‐indolylmethanes from Symmetrical Triarylmethanes via Brønsted Acid Catalyzed C−C Bond Breaking Reaction
Authors: Uddin Nazir , Roy Sudipta , Roy Sayantan , Paul Dipankar , Basumatary Geetanjali , Dutta Gitish K. , Chatterjee Paresh Nath 
Published: August 2024

AbstractAn alternative approach to synthesize bis‐indolylmethanes (BIMs) via a unique p‐toluenesulfonic acid (PTSA) catalyzed dual Csp3−Csp2 bond‐breaking reaction has been reported here. In the reported protocol, 1,3,5‐trimethoxybenzene (TMB), an electron‐rich and sterically bulky arene, acts as a carbon‐based leaving group which can be recovered after the completion of the reaction. In this process, several BIMs of various indole derivatives can be synthesized from symmetrical triarylmethanes (TRAMs) containing bis‐TMB motifs. By modifying the reaction conditions, we could control the sequential bond cleavage of two Csp3−Csp2 bonds in starting TRAM.
New Quinazolinone‐Tethered 1,2,3‐Triazoles aSs Potent Antimicrobial Agents: Design, Synthesis, Biological Evaluation and in silico Docking Study
Authors: Patel Jeevan Lal , Sureddy Naveen Kumar , Chedupaka Raju , Papisetti Venkatesham , Mahapatra S. P. , Penta Santhosh 
Published: August 2024

AbstractNovel 1,2,3‐triazole acetamide linked quinazolinone derivatives were synthesized via click reaction, by reacting of 3‐methyl‐2‐(prop‐2‐yn‐1‐ylthio)quinazolin‐4(3H)‐one with various aryl azides as prominent fungal pathogen Candida albicans interactions. The prepared triazole compounds were characterized using mass spectrometry, 1H NMR, 13C NMR, and IR spectroscopic techniques. Compounds were screened for their in vitro antibacterial and antifungal activity against a variety of microorganisms namely, Bacillus subtilis, Enterococcus faecalis, Klebsiella pneumonia, Escherichia coli, Aspergillus fumigatus, Candida albicans, and Aspergillus clavatus. Quinazolinone linked p‐hydroxyphenyl, o, p‐dihydroxyphenyl and o‐dimethylamino phenyl triazoles showed a remarkable antibacterial activity against E. faecalis with MIC values of 3.20±0.01, 4.01±0.04, and 4.10±0.01 μg mL−1, and screened compounds p‐nitrophenyl substituted triazole, and p‐methylphenyl substituted triazole displayed a significant antifungal activity against C. albicans with MICs of 3.16±0.01, 4.06±0.03 μg mL−1, compared to itraconazole (MIC=3.32±0.02 μg mL−1). For further exploration of the anti‐fungal mechanism of action, molecular docking was carried out for these compounds in C. albicans active site as one of the important antifungal inhibitors (PDB: 1A19). Furthermore, the ADMET profile was evaluated for all the final triazole compounds in contrast to reference drugs moxifloxacin and itraconazole. In conclusion, we discovered a novel quinazolinone linked 1,2,3‐triazoles with promising antimicrobial activity and a favorable pharmacokinetic profile.
Green Synthesis, Characterization and Biological activity of Optimized Alfalfa‐Mediated Zirconium Nanoparticles
Authors: Shah Reza Mahdieh Ameri , Golnaraghi‐Ghomi Ahmadreza , Rasouli Alireza , Rasouli Asl Farzaneh , Dadashpour Mehdi , Sokhansanj Amin , Amin Habibi Mohammad , Vahidi Hossein , Bahrami Nia Maedeh , Ghasemi Mahdieh , Komeili Movahhed Tahereh 
Published: August 2024

AbstractNanoparticle green synthesis is an emerging scientific field that focuses on the production of nanoparticles by living cells. In this work, the potential of extracts of alfalfa leaves (Medicago sativa) as affordable and fabricated zirconium nanoparticles (ZrNPs) was evaluated for the first time. alfalfa alcoholic extract and zirconium precursor were used to produce ZrNPs, the production and characteristics of nanoparticles were measured using the Tyndall effect, UV‐vis, FT‐IR, EDX, DLS, and SEM tests, antioxidant and antibacterial properties, and toxicity Measurement of nanoparticles on breast cancer (MDA‐MB‐468) and human healthy cells (HFF) was investigated. The optimization of nanoparticle production was evaluated with ANN and GN algorithms. The analysis showed that nanoparticles have spherical‐like ZrNPs shapes with an average of 50 nm size. in addition, ZrNPs have significant cytotoxic effects against human breast cancer (MDA‐MB‐468) cells, and Human foreskin fibroblast (HFF) cells exhibited the highest resistance to ZrNPs. There was a significant agreement between the results of the designed ANN‐GA model and the experimental data. In this research, ZrNP was successfully created using alfalfa extract as a renewable source of stabilizing and reducing agents with an environmentally friendly approach, and they showed significant antioxidant, antibacterial, and anticancer properties.
Recent Advances in the Multicomponent Synthesis of Heterocycles using Thiosemicarbazide
Authors: Javahershenas Ramin , Han Jianlin , Kazemi Mosstafa , Jervis Peter J. 
Published: August 2024

AbstractThis review provides an overview of the recent advances in the synthesis of diverse heterocyclic compounds using thiosemicarbazide as a key building block via multicomponent reactions. Thiosemicarbazide is a versatile reagent that has gained significant attention in organic synthesis due to its ability to participate in diverse multicomponent reactions for the efficient and sustainable construction and assembly of novel bioactive molecules and pharmaceuticals. This review discusses the potential applications and future directions in this rapidly evolving area of research. It provides valuable insights into the innovative approaches for the synthesis of heterocycles using thiosemicarbazide, showcasing its significance in modern organic chemistry research. In summary, this review provides an overview of the current state of the art, highlighting the use of thiosemicarbazide in the synthesis of novel heterocyclic compounds reported between 2015 and early 2024.