bluuebunny/crossref_metadata_2025_split huggingface dataset:
Ischemic Postconditioning After Routine Thrombus Aspiration During Primary Percutaneous Coronary Intervention: Rationale and Design of the POstconditioning Rotterdam Trial
Authors: Yetgin Tuncay , van Kranenburg Matthijs , ten Cate Tim , Duncker Dirk J. , de Boer Menko‐Jan , Diletti Roberto , van Geuns Robert‐Jan M. , Zijlstra Felix , Manintveld Olivier C. 
Published: September 2015

BackgroundWhether ischemic postconditioning (IPOC) immediately after routine thrombus aspiration (TA) reduces infarct size (IS) in patients with ST‐segment elevation myocardial infarction (STEMI) undergoing primary percutaneous coronary intervention (PPCI) has not been established.Study designThe POstconditioning Rotterdam Trial (PORT) is a dual‐center, prospective, open‐label, randomized trial with blinded endpoint evaluation enrolling 72 subjects with first‐time STEMI, and an occluded infarct‐related artery (IRA) without collaterals undergoing PPCI. Subjects are randomized 1:1 to a strategy of IPOC immediately after TA followed by stenting of the IRA or to conventional percutaneous coronary intervention (PCI), including TA followed by stenting of the IRA (controls). Cardiac magnetic resonance imaging (MRI) is performed at 3–5 days after STEMI and at 3 months. The primary endpoint is IS at 3 months measured by delayed enhancement MRI. Other secondary endpoints include MRI‐derived microvascular obstruction (MVO), left ventricular ejection fraction, myocardial salvage index, enzymatic IS, ST‐segment resolution, myocardial blush grade, microcirculatory resistance, inflammation markers, and clinical events through 3‐month follow‐up.ConclusionsPORT is testing the hypothesis that adding IPOC (against lethal reperfusion injury) to TA (against distal embolization and MVO) is cardioprotective and reduces ultimate IS in STEMI patients undergoing PPCI (Dutch Trial Register identifier: NTR4040). © 2015 Wiley Periodicals, Inc.
Photochemical Fluorination Reactions – A Promising Research Field for Continuous‐Flow Synthesis
Authors: Rehm Thomas H. 
Published: September 2015

AbstractThe unique properties of fluorine resulting from its tremendously high electronegativity make it a key player in the quest of enabling new and advanced qualities for chemical compounds and materials. With the advent of fluorinating reagents, a great diversity of synthetic methodologies has been developed to incorporate fluorine or fluorine‐containing groups into small molecules with high conversion and selectivity. Especially photochemically catalyzed fluorination reactions proved their potential for the synthesis of fluorine‐containing fine chemicals due to their mild reaction conditions. This tutorial review gives an overview of recently published synthesis strategies that use (visible‐) light‐absorbing catalysts for the activation of fluorinating reagents. A special focus lies on the use of continuous‐flow microreactors for photochemically catalyzed fluorination reactions due to the excellent utilization of this reactor equipment for photochemistry.
ChemInform Abstract: Nanoindentation, High‐Temperature Behavior, and Crystallographic/Spectroscopic Characterization of the High‐Refractive‐Index Materials TiTa2O7 and TiNb2O7.
Authors: Perfler Lukas , Kahlenberg Volker , Wikete Christoph , Schmidmair Daniela , Tribus Martina , Kaindl Reinhard 
Published: September 2015

AbstractColorless single crystals of TiTa2O7 and TiNb2O7 are prepared by melting stoichiometric mixtures of Nb2O5 or Ta2O5, and TiO2 at 1973 and 1873 K, respectively.
ChemInform Abstract: Hybrid Germanium Iodide Perovskite Semiconductors: Active Lone Pairs, Structural Distortions, Direct and Indirect Energy Gaps, and Strong Nonlinear Optical Properties.
Authors: Stoumpos Constantinos C. , Frazer Laszlo , Clark Daniel J. , Kim Yong Soo , Rhim Sonny H. , Freeman Arthur J. , Ketterson John B. , Jang Joon I. , Kanatzidis Mercouri G. 
Published: September 2015

AbstractAGeI3 (A: Cs+ (I), MeNH3+ (II), HC(NH2)2+ (III), CH3C(NH2)2+ (IV), C(NH2)3+ (V), Me3NH+ (VI), iPrNH3+ (VII)) polar hybrid inorganic/organic semiconductors are prepared from a solution of GeI4 in aqueous HI and H3PO2 by precipitation and crystallization through the addition of stoichiometric amounts of AI (stirring at 120 °C until half of the solution is evaporated, 25 °C, 24 h, 80‐90% yield).
ChemInform Abstract: Solar Hydrogen Production by Amorphous Silicon Photocathodes Coated with a Magnetron Sputter Deposited Mo2C Catalyst.
Authors: Morales‐Guio Carlos G. , Thorwarth Kerstin , Niesen Bjoern , Liardet Laurent , Patscheider Joerg , Ballif Christophe , Hu Xile 
Published: September 2015

AbstractA 5 nm Mo2C film is deposited on an amorphous Si photocathode by confocal magnetron co‐sputtering.
ChemInform Abstract: Synthesis and Electrochemical Investigation of Novel Phosphite Based Layered Cathodes for Li‐Ion Batteries.
Authors: Hameed A. Shahul , Reddy M. V. , Sarkar Nirjhar , Chowdari B. V. R. , Vittal Jagadese J. 
Published: September 2015

AbstractM2 [(VO)2(HPO3)2(C2O4)] (M: Li, Na, K) are prepared by hydrothermal reaction of an aqueous mixture of V2O5, H2C2O4, MOH, and H3PO3 (autoclave, 120 °C, 2 d, 80‐90% yield) followed by dehydration at 150 °C (200 °C for the Li compound) in vacuum.
ChemInform Abstract: Direct Synthesis of Hexagonal NaGdF4 Nanocrystals from a Single‐Source Precursor: Upconverting NaGdF4:Yb3+,Tm3+ and Its Composites with TiO2 for Near‐IR‐Driven Photocatalysis.
Authors: Chen Ying , Mishra Shashank , Ledoux Gilles , Jeanneau Erwann , Daniel Marlene , Zhang Jinlong , Daniele Stephane 
Published: September 2015

AbstractA single source precursor, NaGd(tfa)4(diglyme) is prepared from a THF solution of Na(tfa), Gd(tfa)3(H2O), and diglyme (room temperature, 5 h; 83% yield).
ChemInform Abstract: Solution‐Phase Conversion of Bulk Metal Oxides to Metal Chalcogenides Using a Simple Thiol—Amine Solvent Mixture.
Authors: McCarthy Carrie L. , Webber David H. , Schueller Emily C. , Brutchey Richard L. 
Published: September 2015

AbstractA solvent mixture of en together with Et‐SH, HS‐(CH2)2‐OH, or HS‐(CH2)2‐SH is used to dissolve Cu2O, ZnO, GeO2, As2O3, Ag2O, CdO, SnO, Sb2O3, PbO, and Bi2O3 at 25 °C.
ChemInform Abstract: Coffinite, USiO4, Is Abundant in Nature: So Why Is It So Difficult to Synthesize?
Authors: Mesbah Adel , Szenknect Stephanie , Clavier Nicolas , Lozano‐Rodriguez Janeth , Poinssot Christophe , Den Auwer Christophe , Ewing Rodney C. , Dacheux Nicolas 
Published: September 2015

AbstractConditions are established under which coffinite can be reproducibly synthesized.
ChemInform Abstract: A2MnU3O11 (A: K, Rb) and Li3.2Mn1.8U6O22: Three New Alkali‐Metal Manganese Uranium(VI) Oxides Related to Natrotantite.
Authors: Read Cory Michael , Morrison Gregory , Yeon Jeongho , Smith Mark D. , zur Loye Hans‐Conrad 
Published: September 2015

AbstractSingle crystals of the title compounds are prepared from molten chloride fluxes using U3O8, MnCl2, and KCl, RbCl, or LiCl as starting materials (alumina crucible, 900—950 °C, 12 h, 70 and 90% yield for Rb2MnU3O11 and K2MnU3O11, respectively).
ChemInform Abstract: Pb2PdO2(OH)2 and Pb2PdO(OH)4(H2O): Synthesis and Crystal Growth at Ambient Conditions.
Authors: Komarek Alexander Christoph , Merz Patrick , Guo Hanjie , Suard Emmanuelle , Chen Jin‐Ming , Felser Claudia , Jansen Martin 
Published: September 2015

AbstractThe crystal structures of the new compounds (III) and (IV) are determined by powder neutron diffraction and single crystal XRD.
ChemInform Abstract: Ba2 [Pd(HS2O7)2 (S3O10)2]: A Heteroleptic Polysulfatopalladate.
Authors: Bruns Joern , Kluener Thorsten , Wickleder Mathias S. 
Published: September 2015

AbstractOxidation of Pd with oleum (65% SO3) in the presence of BaCO3 (sealed glass ampoules, 180 °C) results in single crystals of Ba2 [Pd(HS2O7)2 (S3O10)2] which crystallize in the triclinic space group P$\bar 1$ (Z = 1, single crystal XRD) and show Pd2+ in a square‐planar coordination of O atoms from two [HS2O7] and two [S3O10] anions.
ChemInform Abstract: Diphenylprolinol Silyl Ether‐Derived Thioureas as Highly Efficient Catalysts for the Asymmetric Michael Addition of Aldehydes to Nitroalkenes.
Authors: He Chunyan , Ren Xiaochen , Feng Yingle , Chai Yonghai , Zhang Shengyong , Chen Weiping 
Published: September 2015

AbstractIt is found that the spatial placement of the C‐4 substituent on the pyrrolidine ring of the catalyst has high influence on the reactivity, diastereoselectivity, and enantioselectivity.
ChemInform Abstract: Generation of Cycloheptynes and Cyclooctynes via a Sulfoxide—Magnesium Exchange Reaction of Readily Synthesized 2‐Sulfinylcycloalkenyl Triflates.
Authors: Yoshida Suguru , Karaki Fumika , Uchida Keisuke , Hosoya Takamitsu 
Published: September 2015

AbstractCycloheptynes and cyclooctynes are efficiently generated via a sulfoxide—magnesium exchange reaction of readily synthesized 2‐sulfinylcycloalkenyl triflates.
ChemInform Abstract: Organic Inorganic Hybrid Cobalt Phthalocyanine/Polyaniline as Efficient Catalyst for Aerobic Oxidation of Alcohols in Liquid Phase.
Authors: Panwar Vineeta , Kumar Pawan , Ray Siddharth S. , Jain Suman L. 
Published: September 2015

AbstractThe heterogeneous title reaction exhibits superior activity compared to homogeneous cobalt phthalocyanine catalysts with added benefits of easy recovery and recycling.
ChemInform Abstract: Highly Diastereoselective Cobalt‐Mediated C(sp3)—C(sp2) Cross‐Coupling Reactions of Cyclic Halohydrins with (Hetero)Aryl Grignard Reagents.
Authors: Hammann Jeffrey M. , Haas Diana , Steib Andreas K. , Knochel Paul 
Published: September 2015

AbstractIn addition to the transformation of O‐Tbs‐protected 2‐bromo and 2‐iodopentan‐1‐ols or the corresponding hexan‐1‐ols, respectively, the title reaction is also applied to a heterocyclic pyrrolidine‐derived iodohdydrin.
ChemInform Abstract: Polyethylene Glycol Functionalized Magnetic Dicationic Ionic Liquids as a Novel Catalyst and Their Application in Ring Opening of Epoxides in Water.
Authors: Godajdar Bijan Mombeni , Mombeni Sare 
Published: September 2015

AbstractThe title compound is prepared starting from PEG‐400 and used as magnetic phase transfer catalyst in the synthesis of 1,2‐azidoalcohols (II) and (IV).
ChemInform Abstract: An Efficient, Mild, Solvent‐Free, One‐Pot Three‐Component Mannich Reaction Catalyzed by (C4H12N2)2 [BiCl6]Cl·H2O.
Authors: Lu Hongfei , Wu Runze , Cheng Helong , Nie Shipeng , Tang Yan , Gao Yuhua , Luo Zhibin 
Published: September 2015

AbstractThe reaction starts from aromatic ketones, (hetero)aryl or cycloalkyl aldehydes and primary or secondary alkyl amines or (hetero)aryl amines.
ChemInform Abstract: α‐Alkyl‐α‐aryl (Trimethyltin) Nitriles: Versatile Nucleophilic Intermediates in Aldol‐Like Reactions.
Authors: Qin Wenling , Long Sha , Bongini Alessandro , Panunzio Mauro 
Published: September 2015

AbstractTrimethyltin nitriles either generated in situ or introduced directly readily react with carbonyl compounds to yield β‐hydroxynitriles.
ChemInform Abstract: Trifluoromethylthiolation of Aryl Iodides and Bromides Enabled by a Bench‐Stable and Easy‐To‐Recover Dinuclear Palladium(I) Catalyst.
Authors: Yin Guoyin , Kalvet Indrek , Schoenebeck Franziska 
Published: September 2015

AbstractTrifluoromethylthiolation of aryl iodides and bromides in high yields is achieved by the robust dinuclear title catalyst.
ChemInform Abstract: Copper‐Catalyzed Intermolecular Trifluoromethylthiocyanation of Alkenes: Convenient Access to CF3‐Containing Alkyl Thiocyanates.
Authors: Liang Zhaoli , Wang Fei , Chen Pinhong , Liu Guosheng 
Published: September 2015

AbstractTogni reagent II (II) and isothiocyanate (III) represent a highly effective combination for the title reaction.
ChemInform Abstract: Cinchonidinium Acetate as a Convenient Catalyst for the Asymmetric Synthesis of cis‐Stilbenediamines.
Authors: Walvoord Ryan R. , Kozlowski Marisa C. 
Published: September 2015

AbstractThe scalable procedure provides cis‐stilbenediamines with moderate enatiomeric excess which may be improved via recrystallization.
ChemInform Abstract: Superacid‐Promoted Dual C—C Bond Formation by Friedel—Crafts Alkylation/Acylation of Cinnamate Esters: Synthesis of Indanones.
Authors: Ramulu Bokka Venkat , Niharika Pedireddi , Satyanarayana Gedu 
Published: September 2015

AbstractIn the case of cinnamic esters (I), the indanone is formed by cyclization of the more electron‐rich aryl moiety: arene reactant for (III), (V), (VII)/(VIII) and (IX) or cinnamic ester for (X) and (XII).
ChemInform Abstract: Cu(OAc)2‐Promoted Reaction of [60]Fullerene with Primary Amines or Diamines.
Authors: Lu Xin‐Wei , Xing Meng‐Lei , Miao Chun‐Bao , Li Jia‐Xing , Sun Xiao‐Qiang , Yang Hai‐Tao 
Published: September 2015

AbstractThe title reaction allows the concise preparation of aziridinofullerenes.
ChemInform Abstract: The Copper‐Catalyzed Asymmetric Construction of a Dispiropyrrolidine Skeleton via 1,3‐Dipolar Cycloaddition of Azomethine Ylides to α‐Alkylidene Succinimides.
Authors: Yang Wu‐Lin , Liu Yang‐Zi , Luo Shuai , Yu Xingxin , Fossey John S. , Deng Wei‐Ping 
Published: September 2015

AbstractA series of chiral dispiropyrrolidines (III), (V), and (VII) is readily prepared by a copper‐catalyzed 1,3‐dipolar cycloaddition of azomethine ylides (II) and (IV) to α‐alkylidene succinimides (I) and (VI), respectively.
ChemInform Abstract: A Cinchona Alkaloid Catalyzed Enantioselective Sulfa‐Michael/Aldol Cascade Reaction of Isoindigos: Construction of Chiral Bispirooxindole Tetrahydrothiophenes with Vicinal Quaternary Spirocenters.
Authors: Gui Yong‐Yuan , Yang Jian , Qi Liang‐Wen , Wang Xiao , Tian Fang , Li Xiao‐Nian , Peng Lin , Wang Li‐Xin 
Published: September 2015

AbstractThe first protocol for the asymmetric preparation of the highly congested title compounds by an organocatalytic cascade reaction is presented.
ChemInform Abstract: Suzuki—Miyaura Reactions of Halospirooxindole Derivatives.
Authors: El Bouakher Abderrahman , Allouchi Hassan , Abrunhosa‐Thomas Isabelle , Troin Yves , Guillaumet Gerald 
Published: September 2015

AbstractBased on the regioselective mono‐ and dibromination of spirofuroindoline (I) an efficient synthesis of mono‐ and diarylated products is developed.
ChemInform Abstract: Synthesis of Thiiranes by Rhodium‐Catalyzed Sulfur Addition Reaction to Reactive Alkenes.
Authors: Arisawa Mieko , Ichikawa Takuya , Yamaguchi Masahiko 
Published: September 2015

AbstractA rhodium complex derived from RhH(PPh3)4, dppe, and 4‐ethynyltoluene catalyzes the addition reaction of sulfur to norbornenes giving the corresponding thiiranes.
ChemInform Abstract: Pt‐Catalyzed Rearrangement of Oxaspirohexanes to 3‐Methylenetetrahydrofurans: Scope and Mechanism.
Authors: Malapit Christian A. , Chitale Sampada M. , Thakur Meena S. , Taboada Rosa , Howell Amy R. 
Published: September 2015

AbstractAn unprecedented rearrangement is detected during the attempt to open the cyclopropane ring in oxaspirohexanes for the preparation of psico‐nucleoside synthons.
ChemInform Abstract: Design, Synthesis, and Application of a Chiral Sulfinamide Phosphine Catalyst for the Enantioselective Intramolecular Rauhut—Currier Reaction.
Authors: Su Xiao , Zhou Wei , Li Yangyan , Zhang Junliang 
Published: September 2015

AbstractA novel class of chiral phosphine catalysts is introduced and successfully employed in the enantioselective intramolecular Rauhut‐Currier reaction.
ChemInform Abstract: Phosphine‐Free Palladium‐Catalyzed Direct Bisarylation of Pyrroles with Aryl Iodides on Water.
Authors: Cho Beom Shin , Bae Hyun Jung , Chung Young Keun 
Published: September 2015

AbstractA broad spectrum of 2,5‐diarylated pyrroles is readily available under mild conditions.
ChemInform Abstract: The Chemistry of Vicinal Tricarbonyls: An Expedient Route to Fully‐Substituted 3‐Aminopyrroles.
Authors: Truong Phong M. , Mandler Michael D. , Doyle Michael P. 
Published: September 2015

AbstractThe synthesis is based on the one‐pot four‐component reaction of a 2,3‐diketoester, a primary amine and an aryl aldehyde or formaldehyde.
ChemInform Abstract: PyBidine—NiCl2‐Catalyzed Asymmetric Addition of Alcohols and Peroxides to Isatin‐Derived Ketimines.
Authors: Arai Takayoshi , Tsuchiya Kento , Matsumura Eri 
Published: September 2015

AbstractMeOH (II) and peroxide (V) are found to be the optimal reactants for the title process in the presence of the chiral ligand PBPA.
ChemInform Abstract: Maleimide as an Efficient Nucleophilic Partner in the Aza‐Morita—Baylis—Hillman Reaction: Synthesis of Chiral 3‐Substituted‐3‐aminooxindoles.
Authors: Kumar Akshay , Sharma Vivek , Kaur Jasneet , Kumar Naveen , Chimni Swapandeep Singh 
Published: September 2015

AbstractAn organocatalytic enantioselective Aza‐Morita—Baylis—Hillman Reaction of maleimide derivatives with various N‐substituted isatin imine derivatives by employing chiral β‐isocupreidine as a catalyst is developed.
ChemInform Abstract: A Facile, Superacid‐Promoted Sequential Domino One‐Pot Dual C—C Bond Formation and Fischer Indole Synthesis: Rapid Access to 10‐Phenyl‐5,10‐dihydroindeno[1,2‐b]indoles.
Authors: Reddy Alavala Gopi Krishna , Satyanarayana Gedu 
Published: September 2015

AbstractTfOH‐mediated reaction between cinnamic esters (I) and arenes initially furnishes indanones, e.
ChemInform Abstract: Organocatalyzed CO2 Trapping Using Alkynyl Indoles.
Authors: Xin Zhuo , Lescot Camille , Friis Stig D. , Daasbjerg Kim , Skrydstrup Troels 
Published: September 2015

AbstractThis first organocatalyzed trapping of CO2 gives access to new heterocyclic structures.
ChemInform Abstract: Silver(I) NHC Mediated C—C Bond Activation of Alkyl Nitriles and Catalytic Efficiency in Oxazoline Synthesis.
Authors: Heath Rachael , Mueller‐Bunz Helge , Albrecht Martin 
Published: September 2015

AbstractThe reaction of Ag2O in refluxing MeCN with triazolium iodide leads to the formation of Ag‐NHC complexes via selective C—C bond cleavage and from C—CN bond activation.
ChemInform Abstract: BF3‐Mediated cis‐Selective Cycloaddition of O‐Silyloxime with Alkenes.
Authors: Morita Nobuyoshi , Kono Rina , Fukui Kenji , Miyazawa Asuka , Masu Hyuma , Azumaya Isao , Ban Shintaro , Hashimoto Yoshimitsu , Okamoto Iwao , Tamura Osamu 
Published: September 2015

AbstractO‐Silyloxime (I) reacts with alkenes (II) and Boc2O to the Boc‐protected isoxazolidin‐3‐carboxamides (IV) and (V) favouring the cis‐isomer (IV).
ChemInform Abstract: Novel, One‐Pot, Three‐Component, Regioselective Synthesis of Fluorine‐Containing Thiazole and Bis‐3H‐thiazole Derivatives Using Polyvinyl Pyridine as Heterogeneous Catalyst, and Evaluation of Their Antibacterial Activity.
Authors: Abbasi Shiran Jafar , Yahyazadeh Asieh , Mamaghani Manouchehr , Yamin Bohari M. , Albadi Jalal , Shirini Farhad , Rassa Mehdi 
Published: September 2015

AbstractEleven title compounds of type (IV) and four of type (VIII) are prepared by this new polyvinylpyridine‐catalyzed one‐pot, three‐component procedure.
ChemInform Abstract: A Green Synthesis of Substituted Coumarins Using Nano Graphene Oxide as Recyclable Catalyst.
Authors: Khodabakhshi Saeed , Marahel Farzaneh , Rashidi Alimorad , Abbasabadi Masoud Khaleghi 
Published: September 2015

AbstractGraphene oxide nanosheets are used as efficient catalyst in one‐pot syntheses of pyranocoumarins (IV) and biscoumarins (V).
ChemInform Abstract: Stereoselective Construction of Functionalized Tetracyclic and Pentacyclic Coumarinopyranpyrazole/Pyrimidinedione/Coumarin Scaffolds Using a Solid‐State Melt Reaction.
Authors: Bakthadoss Manickam , Kannan Damodharan , Sivakumar Nagappan , Malathi Palani , Manikandan Vasudevan 
Published: September 2015

AbstractA simple and novel protocol for the facile synthesis of complex angularly substituted tetracyclic and pentacyclic hybrid molecular frameworks containing a coumarinopyranpyrazole/pyrimidinedione and coumarin ring systems via a solid‐state melt reaction (SSMR) through a domino process is developed.
ChemInform Abstract: Pd/Pivalic Acid Mediated Direct Arylation of 2‐Pyrones and Related Heterocycles.
Authors: Pardo Leticia M. , Prendergast Aisling M. , Nolan Marie‐T. , O Muimhneachain Eoin , McGlacken Gerard P. 
Published: September 2015

AbstractAn oxidative direct intramolecular C‐H arylation of 2‐pyrone and 2‐pyridone derivatives bearing ortho‐halogenated benzyloxy groups is developed.
ChemInform Abstract: Knoevenagel‐Michael‐Cyclocondensation Tandem Reaction of Malononitrile, Various Aldehydes and Dimedone Catalyzed by Sulfonic Acid Functionalized Pyridinium Chloride as a New Ionic Liquid and Catalyst.
Authors: Zolfigol Mohammad Ali , Khazaei Ardeshir , Moosavi‐Zare Ahmad Reza , Afsar Javad , Khakyzadeh Vahid , Khaledian Omid 
Published: September 2015

AbstractSulfonic acid functionalized pyridinium chloride is prepared and used for the one‐pot synthesis of tetrahydrobenzo[b]pyran derivatives (IV) as a reusable catalyst under solvent‐free conditions.
ChemInform Abstract: Metal‐Free C(3)—H Arylation of Coumarins Promoted by Catalytic Amounts of 5,10,15,20‐Tetrakis(4‐diethylaminophenyl)porphyrin.
Authors: Kojima Masahiro , Oisaki Kounosuke , Kanai Motomu 
Published: September 2015

AbstractThis new, mild and environmentally friendly Meerwein arylation provides facile access to a broad variety of 3‐arylcoumarins in good yields.
ChemInform Abstract: Domino Acylation/Diels—Alder Synthesis of N‐Alkyl‐octahydroisoquinolin‐1‐one‐8‐carboxylic Acids under Low‐Solvent Conditions.
Authors: Slauson Stephen R. , Pemberton Ryan , Ghosh Partha , Tantillo Dean J. , Aube Jeffrey 
Published: September 2015

AbstractOptimized condition sequences render possible the approach to the desired isoquinoline structures and the analogous lactone (VII).
ChemInform Abstract: PhI(OCOCF3)2‐Mediated Cyclization of o‐(1‐Alkynyl)benzamides: Metal‐Free Synthesis of 3‐Hydroxy‐2,3‐dihydroisoquinoline‐1,4‐dione.
Authors: Yang Chao , Zhang Xiang , Zhang‐Negrerie Daisy , Du Yunfei , Zhao Kang 
Published: September 2015

AbstractThe title reaction can be carried out either under conditions A) or under a modified variant if the nitrogen of the starting benzamides (syntheses described) bears an alkyl group instead of ‐O‐Me (reaction mechanism).
ChemInform Abstract: Stereoselective Synthesis of Organosulfur Compounds Incorporating N‐Aromatic Heterocyclic Motifs and Quaternary Carbon Centers via a Sulfa‐Michael Triggered Tandem Reaction.
Authors: Qin Tianyou , Cheng Lu , Zhang Sean Xiao‐An , Liao Weiwei 
Published: September 2015

AbstractA novel sulfa‐Michael addition (SMA)‐triggered tandem reaction is developed by combining a SMA reaction with a simultaneous rearomatization process utilizing a less reactive carbonyl group as an intramolecular electrophilic partner.
ChemInform Abstract: The Reaction of 6‐Substituted 4‐Pyrone‐2‐carboxylic Acids with O‐Phenylenediamine. Synthesis and Structure of 3‐(1H‐1,5‐Benzodiazepin‐2(3H)‐ylidenemethyl)quinoxalin‐2(1H)‐ones.
Authors: Obydennov Dmitrii L. , Sosnovskikh Vyacheslav Ya. 
Published: September 2015

AbstractThe reactions of 4‐pyrone‐2‐carboxylic acid derivatives (I), (V), (X), and (XIII) with o‐phenylenediamine (II) or 2‐aminophenol (VIII) are described.
ChemInform Abstract: Ruthenium‐Catalyzed Silylation of 1,3‐Butadienes with Vinylsilanes
Authors: Szudkowska‐Fratczak Justyna , Marciniec Bogdan , Hreczycho Grzegorz , Kubicki Maciej , Pawluc Piotr 
Published: September 2015

Abstractleading to (E,E)‐dienylsilanes (III) as main products
ChemInform Abstract: Pd‐Catalyzed Carbonylative Access to Aroyl Phosphonates from (Hetero)aryl Bromides.
Authors: Lian Zhong , Yin Hongfei , Friis Stig D. , Skrydstrup Troels 
Published: September 2015

AbstractThis is the first transition‐metal catalyzed carbonylation with a phosphorus nucleophile.
ChemInform Abstract: Trapping Hemiacetals with Phosphono Substituted Palladium π‐Allyl Complexes for the Synthesis of Substituted Cyclic Ethers.
Authors: Sutivisedsak Nongnuch , Dawadi Surendra , Spilling Christopher D. 
Published: September 2015

AbstractIt is demonstrated, that hemiacetals or hydrates derived from aldehydes (I) and methanol or water undergo Pd‐catalyzed intramolecular trapping to form cyclic acetals (III) and (V).