bluuebunny/crossref_metadata_2025_split huggingface dataset:
Synergetic efficiency of eco‐friendly inoculants on yield and yield parameters of Abyssinian field pea (Pisum sativum var. abyssinicum)
Authors: Meressa Aklil Gebremedhin , Teka Molla Hadiss , Gebru Daniel Berhe 
Published: August 2024

AbstractMany research findings stated that field pea was phenotypically diverse and symbiotically effective. However, limited studies were conducted on field pea (Pisum sativum var. abysinicum) regarding biological nitrogen fixation with local varieties and races. Therefore, the current study was conducted on the synergetic efficiency of locally available inoculums on yield and yield components of Dekoko. Randomized complete block design with three replications was used at farmers field level as an experimental design. The analysis of variance result revealed that, locally isolated Rhizobium inoculants significantly influence the agronomic parameters such as plant height, number of tillers, number of seeds, grain yield, and 1000‐seed weight at p < 0.05. The highest plant height (81.87 and 87.49 cm), pod number (19.53 and 20.93 NP/P), grain yield (633.2 and 790.2 kg ha−1) and 1000‐seed weight (97.33 and 92.42 g) were recorded from field condition. The rhizobial population count of the study sites varied, and experimental site number 1 had higher population count (2.33 × 108) compared to the second experimental site (1.23 × 108). Soils having various rhizobial population have different capability to fix atmospheric nitrogen. Since Ethiopian soils harbor rhizobial populations in the soil Rhizosphere. Therefore, the authors concluded that, prior to field experimentation, assessing the microbial diversity of the study area is a primary agenda.
Low‐Solvent‐Coordination Solvation Structure for Lithium‐Metal Batteries via Electric Dipole‐Dipole Interaction
Authors: Kang Cong , Zhu Jiaming , Kong Fanpeng , Xiao Xiangjun , Huo Hua , Ma Yulin , Xiong Yueping , Luo Ying , Lv Taolin , Xie Jingying , Yin Geping 
Published: August 2024

AbstractUnveiling inherent interactions among solvents, Li+ ions, and anions are crucial in dictating solvation‐desolvation kinetics at the electrode/electrolyte interface. Developing an electrolyte with a low ion‐transport barrier and minimal solvent coordination in its interfacial solvation structure is essential for forming an anion‐derived solid‐electrolyte interface, a key component for high‐performance Li‐metal batteries. In this study, we harness electric dipole‐dipole synergistic interactions to formulate an electrolyte with significantly reduced interfacial solvent coordination. Operando characterization and theoretical analysis reveal that 2‐fluoropyridine (FPy) with high dipole preferentially adsorbs onto the Li metal surface. The adsorbed FPy molecule squeezes succinonitrile in the primary solvation sheath through steric hindrance, leading to the formation of an inorganic‐rich interphase. Consequently, the introduction of FPy enhances the reversible capacity of the LiCoO2||Li cell, which maintains a capacity of 143 mAh g−1 after 500 cycles at a 1 C rate. Moreover, the cycle life of LiCoO2 batteries with a limited supply of lithium extends from 120 cycles to over 200 cycles. These findings offer a strategy that can be applied broadly to design interfacial solvation structures for various metal‐ion/metal‐based batteries.
Gold Coordination‐Accelerated Multi‐Resonance TADF Emission for Efficient Solution‐Processible Ultrapure Deep‐Blue OLEDs
Authors: Song Xiu‐Fang , Luo Sai , Li Nengquan , Wan Xintong , Miao Jingsheng , Zou Yang , Li Kai , Yang Chuluo 
Published: August 2024

AbstractMulti‐resonance (MR) type emitters have emerged as highly promising candidates for high‐resolution organic light‐emitting diodes (OLEDs). However, thermally activated delayed fluorescence (TADF) emissions with simultaneous short excited state lifetimes and ultrapure blue color (a CIEy close to 0.046 and an emission peak >440 nm) have rarely been obtained for MR emitters. Herein, we report a design of dual gold‐coordinated MR molecules to achieve efficient and short‐lived ultrapure blue TADF emission. The dinuclear Au(I) complex, namely iPrAuBN, shows a narrowband deep‐blue emission with a peak maximum of 448 nm and a full width at half maximum (FWHM) of 29 nm in doped film. The coordination with two Au atoms significantly shortens the delayed fluorescence lifetime to 7.8 μs in comparison to 60.6 μs for the parental organic analogue. Solution‐processed OLED doped with iPrAuBN demonstrates an ultrapure blue electroluminescence with a peak maximum of 442 nm, a FWHM of 19 nm, CIE coordinates of (0.154, 0.036), and a maximum external quantum efficiency of 14.8 %.
Coupling Manipulation of Interfacial Chemistry and Coordination Structure in Vanadium Oxides Enables Rapid Magnesium Ion Diffusion Kinetics
Authors: Wang Weixiao , Wang Wenwen , Xiong Fangyu , Meng Jiashen , Wu Jinsong , Yang Wei , Long Juncai , Chen Jinghui , Chen Jiajun , An Qinyou 
Published: August 2024

AbstractRechargeable magnesium batteries (RMBs) are a highly promising energy storage system due to their high volumetric capacity and intrinsic safety. However, the practical development of RMBs is hindered by the sluggish Mg2+ diffusion kinetics, including at the cathode‐electrolyte interface (CEI) and within the cathode bulk. Herein, we propose an efficient strategy to manipulate the interfacial chemistry and coordination structure in oligolayered V2O5 (L−V2O5) for achieving rapid Mg2+ diffusion kinetics. In terms of the interfacial chemistry, the specific exposed crystal planes in L−V2O5 possess strong electron donating ability, which helps to promote the degradation dynamics of C−F/C−S bonds in the electrolyte, thereby establishing the inorganic‐organic interlocking CEI layer for rapid Mg2+ diffusion. In terms of the coordination structure, the straightened V−O structure in L−V2O5 provides efficient ions diffusion path for accelerating Mg2+ diffusion in the cathode. As a result, the L−V2O5 delivers a high reversible capacity (355.3 mA h g−1 at 0.1 A g−1) and an excellent rate capability (161 mAh g−1 at 1 A g−1). Impressively, the interdigital micro‐RMBs is firstly assembled, exhibiting excellent flexibility and practicability. This work gives deeper insights into the interface and interior ions diffusion for developing high‐kinetics RMBs.
Polyvinylidene fluoride‐co‐hexafluoropropylene polymer gel electrolyte‐enabled dye‐sensitized solar cell for sustainable energy
Authors: Asghar Hafza , Riaz Tabinda , Mannan Hafiz Abdul 
Published: August 2024

AbstractDeveloped specifically to address leakage and stability concerns inherent in liquid electrolytes, this study presents a significant advancement in polymer gel electrolyte (PGE) formulation by combining potassium iodide (KI), ammonium iodide (AI) salts, and polyvinylidene fluoride‐co‐hexafluoropropylene (PVDF‐co‐HFP) as a host polymer. The tape casting method was employed to deposit the standard TiO2 paste as the photoanode and platinum paste as the counter electrode. N3 dye was incorporated, and PVDF‐co‐HFP was used as the PGE between the electrodes. The conductivity of PGE was measured by using a digitized conductivity meter. The quasi solid‐state solar cell (QS‐DSSC) assembled using single salts (KI, and AI), and mixed cations PGE was examined via photocurrent–voltage characteristics, and electrochemical impedance spectroscopy. The augmented ionic conductivity directly influences the efficiency of DSSCs. Notably, incorporating a mixed salt (KI + AI) within the PGE enhances ionic conductivity compared to single‐salt‐based counterparts. The resultant DSSCs using mixed salt PGE exhibit a Voc of 600 mV, Jsc of 1.01 mA/cm2, FF of 0.6089, and an efficiency of 0.369%, outperforming those using KI or AI. This highlights the perceptible advantages of employing this innovative electrolyte composition to enhance solar cell performance.
When Methodological Innovation Changes the Game: A 10‐Year Review of Environmental DNA (eDNA) Applied to Crayfish
Authors: Baudry Thomas , Vasselon Valentin , Delaunay Carine , Sweet Michael , Grandjean Frédéric 
Published: August 2024

ABSTRACTThe use of environmental DNA (eDNA) as a tool for monitoring represents a major innovative advance in environmental science, one that enables the detection of species without the need to observe or capture them. This article assesses the state of play of eDNA research targeting crayfish. We found a total of 41 peer‐reviewed articles published between 2014 and 2023 on both native and invasive species. Most studies focused on invasive species (or a native/invasive species co‐detection assessment) (65.8%). There was also a clear geographical bias across studies, with more than half conducted in Europe (51.2%) and a quarter in the United States (26.8%). In contrast, there were none conducted in Africa. The relatively large number of published studies has led to an interesting diversity of protocols designed or utilized, with most favouring the development of their own assays (69.33%). That said, filtration (as an eDNA capture method) was common (80.5%), along with the use of commercially available eDNA extraction kits (69.8%). The COI gene also appeared to be the preferred target region (89.33%). Such range of protocols is interesting, but is it optimal? Are the best protocols always being utilized? Or is the chance for novel application hampering our ability to explore larger trends across studies?
Croatian Brackish Karst Spring Lake Jezero Blaca in Pelješac Peninsula Reveals Interesting Truncatelloid Gastropods Assemblage
Authors: Jaszczyńska Aleksandra , Grego Jozef , Hofman Sebastian , Ozimec Roman , Osikowski Artur , Falniowski Andrzej 
Published: August 2024

ABSTRACTJezero Blaca is a unique spring lake situated at the northern coast of the Pelješac Peninsula near the village Duba Pelješka in South Dalmatia, Croatia. The lake supported by a karstic spring located near the Adriatic seashore is inhabited by unusually rich brackish water truncatelloid assemblage. The position of the lake near seashore evokes a model of sea invertebrate gradual adaptation to freshwater spring head allowing them to further invade the stygobiont karst conduits. Similar lakes could be the marine gateways of the extraordinarily rich Dinaric stygobiont fauna. The main aim of this study was to sample and barcode the aquatic snails found in this locality to check their species affiliation and describe conservation needs. The results confirmed that the locality hosts four interesting representatives of the gastropod superfamily Truncatelloidea, which has never been found syntopically so far. One of the species characterized by unique COI sequences and was described herein as Truncatella dalmatica new sp. The conservation need of this unique and understudied habitat type is discussed.
Maternal Exposure to Tap Water Disinfection By‐Products and Risk of Selected Congenital Heart Defects
Authors: Michalski Adrian M. , Luben Thomas J. , Zaganjor Ibrahim , Rhoads Anthony , Romitti Paul A. , Conway Kristin M. , Langlois Peter H. , Feldkamp Marcia L. , Nembhard Wendy N. , Reefhuis Jennita , Yazdy Mahsa M. , Lin Angela E. , Desrosiers Tania A. , Hoyt Adrienne T. , Browne Marilyn L. ,   The National Birth Defects Prevention Study
Published: August 2024

ABSTRACTBackgroundThe use of chlorine to treat drinking water produces disinfection by‐products (DBPs), which have been associated with congenital heart defects (CHDs) in some studies.MethodsUsing National Birth Defects Prevention Study data, we linked geocoded residential addresses to public water supply measurement data for DBPs. Self‐reported water consumption and filtration methods were used to estimate maternal ingestion of DBPs. We estimated adjusted odds ratios and 95% confidence intervals using logistic regression controlling for maternal age, education, body mass index (BMI), race/ethnicity, and study site to examine associations between CHDs and both household DBP level and estimated ingestion of DBPs.ResultsHousehold DBP exposure was assessed for 2717 participants (1495 cases and 1222 controls). We observed a broad range of positive, null, and negative estimates across eight specific CHDs and two summary exposures (trihalomethanes and haloacetic acids) plus nine individual DBP species. Examining ingestion exposure among 2488 participants (1347 cases, 1141 controls) produced similarly inconsistent results.ConclusionsAssessing both household DBP level and estimated ingestion of DBPs, we did not find strong evidence of an association between CHDs and DBPs. Despite a large study population, DBP measurements were available for less than half of participant addresses, limiting study power.
Ceramides involve sugarcane defense response to Sporisorium scitamineum
Authors: Li Jian , Wu Dan‐Xia , Fang Zhi‐Qiang , Xia Kuai‐Fei , Bao He‐Nan , Huang Li‐Qun , Li Yong‐Jia , Shen Wan‐Kuan , Zhang Ming‐Yong , Zeng Xuan 
Published: August 2024

AbstractSugarcane smut, a widespread and destructive disease induced by Sporisorium scitamineum, has a significant effect on sugarcane cultivation. Sphingolipids, crucial components of membranes, play a role in plant resistance regulation. However, the specific function of sphingolipids in sugarcane smut resistance has not been understood. This study revealed that following the S. scitamineum infection, ceramide (Cer) and hydroxyceramide (hCer) levels specifically increased in the sugarcane variety ROC22, along with significant alterations in plant hormone levels. Analysis of lipid composition in S. scitamineum‐sensitive and ‐resistant sugarcane varieties indicated that the resistant variety YT93‐159 had lower Cer and hCer levels compared to the sensitive variety ROC22. Additionally, YT93‐159 displayed an increased level of jasmonoyl‐isoleucine (JA‐Ile) and upregulated the expression of genes linked to the pathway of jasmonic acid (JA). Through experiments using the sugarcane protoplast system, it was observed that exogenous ceramide could influence the expression of genes associated with the salicylic acid and JA pathways. This research was the initial examination into the lipidomics‐based molecular mechanisms underlying sugarcane's resistance to S. scitamineum, offering a theoretical foundation for enhancing sugarcane resistance through genetic engineering.
Ferrocenyl Dithiophosphonate Ag(I) Complexes: Synthesis, Structures, Luminescence, and Electrocatalytic Water Splitting Tuned by Nuclearity and Ligands
Authors: Kumar Jangid Dilip , Dastider Saptarshi G. , Mandal Srayee , Kumar Pankaj , Kumari Priti , Kanta Haldar Krishna , Mondal Krishnakanta , Singh Dhayal Rajendra 
Published: August 2024

AbstractThe heterometallic [Ag(I)/Fe(II)] molecular electrocatalysts for hydrogen production were introduced here to recognize the mutual role of metallic nuclearity and ligand engineering. A series of ferrocenyl dithiophosphonate stabilized mononuclear [Ag(PPh3)2{S2PFc(OR)}] {where R=Me (1), Et (2), nPr (3), iPr (4), iAmyl (5); Fc=Fe (ɳ5‐C5H4) (ɳ5‐C5H5)} and dinuclear [Ag(PPh3){S2PFc(OR}]2 {where R=Et (2 a), and nPr (3 a)} complexes were synthesized and characterized by SCXRD, NMR (31P and 1H), ESI‐MS, UV‐Vis, and FT‐IR spectroscopy. The comparative electrocatalytic HER behavior of 1–5 and 2 a–3 a showed effective current density of 1 mA/cm2 with overpotentials ranging from 772 to 991 mV, demonstrating the influence of extended and branched carbon chains in dithiophosphonates and metallic (mono‐/di−) nuclearity, which correlates with documented tetra‐nuclear [Ag4(S2PFc(OnPr)4], 6. DFT study suggests the coordinated (μ1‐S) site of ligands is the reactivity center and the adsorption energy of intermediate [H*‐SM] varies with the engineering of ligand and nuclearity. A catalytic mechanism using mononuclear (1) and di‐nuclear (2 a) was proposed with the assistance of DFT. Each complex, being the first example of Ag(I) dithiophosphonates, exhibits intense photoluminescence with high quantum yields ranging from 33 % to 67 %. These results link the lower nuclearity structures to their physical and catalytic properties.
Validation of the Danish Version of the Overall Depression Severity and Impairment Scale (ODSIS): A Reliable Instrument for Assessing Depression Symptoms and Functional Impairment
Authors: Madsen Christina , Reinholt Nina , Arendt Mikkel , Eskildsen Anita , Bryde Anne , Hvenegaard Morten , Poulsen Stig , Arnfred Sidse 
Published: August 2024

ABSTRACTIntroductionIn psychotherapy, having a reliable tracking tool is vital for effective treatment. We have validated the Danish version of the ‘Overall Depression Severity and Impairment Scale’ (ODSIS), which is used in the Unified Protocol for Emotional Disorders (UP) and other cognitive behavioural therapies. This five‐item self‐rating scale is expected to correspond closely to the gold‐standard Beck Depression Inventory‐II (BDI‐II), but also to self‐rating scales addressing daily functioning and well‐being.MethodsInternal consistency is assessed using Cronbach's alpha and McDonald's omega. Criterion validity is explored through Pearson's correlation coefficient with BDI‐II, the Work and Social Adjustment Scale (WSAS), the Five‐Item World Health Organization Well‐Being Index (WHO‐5) and scatter plots, and an optimal cut‐off score is determined using a receiver operating characteristic curve. The study included 340 respondents: 234 from a recent clinical trial, 56 psychiatric patients from inpatient/outpatient units and 50 healthy volunteers.ResultsODSIS demonstrates strong internal consistency (Cronbach's alpha: 0.887–0.956, McDonald's omega: 0.888–0.957). Correlations with BDI‐II, WSAS and WHO‐5 highlight its strong criterion validity (BDI‐II: 0.847, WSAS: 0.751, WHO‐5: 0.771). The optimal cut‐off score (> 7.5) for detecting depression shows great sensitivity (0.862) and specificity (0.731).ConclusionThe Danish version of ODSIS proves to be a reliable instrument for quantification of a combination of depression level and functional impairment from the symptoms. Its high correlation with established BDI‐II makes it a brief and handy tool for repeated measurement in clinical and research settings.
Phylogeographic analysis reveals multiple origins of the desert shrub Reaumuria songarica in northern Xinjiang, involving homoploid and tetraploid hybrids
Authors: Fan Xingke , Yan Xia , Qian Chaoju , Awuku Ibrahim , Zhao Pengshu , Liao Yuqiu , Li Zhijun , Li Xinrong , Ma Xiao‐Fei 
Published: August 2024

AbstractHybrid speciation plays an important role in species diversification. The establishment of reproductive isolation is crucial for hybrid speciation, and the identification of diverse types of hybrids, particularly homoploid hybrid species, contributes to a comprehensive understanding of this process. Reaumuria songarica is a constructive shrub widespread in arid Central Asia. Previous studies have inferred that the R. songarica populations in the Gurbantunggut Desert (GuD) originated from homoploid hybridizations between its eastern and western lineages and may have evolved into an incipient species. To further elucidate the genetic composition of different hybrid populations and to determine the species boundary of this hybrid lineage, we investigated the overall phylogeographic structure of R. songarica based on variation patterns of five cpDNA and one nrITS sequences across 32 populations. Phylogenetic analyses demonstrated that within the GuD lineage, the Wuerhe population evolved directly from ancestral lineages, whereas the others originated from hybridizations between the eastern and western lineages. PCoA and genetic barrier analysis supported the subdivision of the GuD lineage into the southern (GuD‐S) and northern (GuD‐N) groups. Populations in the GuD‐S group had a consistent genetic composition and the same ancestral female parent, indicating that they belonged to a homoploid hybrid lineage. However, the GuD‐N group experienced genetic admixture of the eastern and western lineages on nrITS and cpDNA, with some populations inferred to be allopolyploid based on ploidy data. Based on cpDNA haplotypes, BEAST analyses showed that the GuD‐S and GuD‐N groups originated after 0.5 Ma. Our results suggest that multiple expansions and contractions of GuD, driven by Quaternary climatic oscillations and the Kunlun‐Yellow River tectonic movement, are important causes of the complex origins of R. songarica populations in northern Xinjiang. This study highlights the complex origins of the Junggar Basin flora and the underappreciated role of hybridization in increasing its species diversity.
Phylogeography of a herbal Pinellia ternata reveals repeated range expansions and inter/postglacial recolonization routes on the fragmented distribution pattern in China
Authors: Jiang Chunxue , Wu Ming , He Shanshan , Lu Yuxia , Zhao Cai 
Published: August 2024

AbstractMost plant phylogeographic studies in China have focused on the importance of genetic divergence and where should the shelter be located. Little attention has been paid to range expansion and recolonization routes in this region. In this study, two cpDNA fragments (psbK‐psbI and trnL‐F), two pairs of nuclear gene sequences (ITS and ETS), and nine pairs of SSR molecular markers were used, combined with Bayesian Skyline Plot method, gene barrier analysis, and species distribution models to explore the phylogeographical pattern, potential expansion routes and population dynamic history of Pinellia ternata from 22 population. The results showed that phylogeograhical pattern and genetic structure for P. ternata are effected by environmental heterogeneity and climate fluctuation, and it can be divided into two groups (Southwest group, Central and Eastern group) and thus there are at least two glacial refugia in China. Three expanding routes within groups were explored to contribute to the phylogeogrephic pattern of P. ternata based on the geographical distribution and network analysis of haplotypes. In a word, our study reveals repeated range expansions and inter/postglacial recolonization routes on the fragmented distribution pattern in China and resolves the refugia distributing in China and has also certain reference value for the protection of the medicinal plant P. ternata.
Effect of the ten‐year fishing ban on change of phytoplankton community structure: Insights from the Gan River
Authors: Ye Peng , Lu Xinwen , Xia Wenxin , Wang Yating , Zhou Chunhua , Liu Xiongjun , Ouyang Shan , Wu Xiaoping 
Published: August 2024

AbstractThe Yangtze River is one of the largest riverine ecosystems in the world and is a biodiversity hotspot. In recent years, this river ecosystem has undergone rapid habitat deterioration due to anthropogenic disturbances, leading to a decrease in freshwater biodiversity. Owing to these anthropogenic impacts, the Chinese government imposed a “Ten‐year fishing ban” (TYFB) in the Yangtze River and its tributaries. Ecological changes associated with this decision have not been documented to evaluate the level of success. This study evaluates the success of the TYFB by analyzing the changes in phytoplankton communities and comparing them to periods before the TYFB was imposed. A total of 325 phytoplankton species belonging to 7 phyla and 103 genera dominated by Chlorophyceae and Bacillariophyceae were identified. Species diversity according to the Shannon–Wiener ranged between 1.19 and 3.00. The results indicated that phytoplankton diversity increased, while both density and biomass decreased after the TYFB. The health of the aquatic ecosystem appeared to have improved after the TYFB, as indicated by the phytoplankton‐based index of biotic integrity. Significant seasonal and spatial differences were found among the number of species, density, and biomass of phytoplankton, where these differences were correlated with pH, water depth, chlorophyll‐a, permanganate index, transparency, copper, ammonia nitrogen, and total phosphorus based on redundancy analysis. Results from this study indicate that the TYFB played an important role in the restoration of freshwater ecosystem in the Yangtze River and its tributaries.