bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Regioselective Access to CF3S‐Substituted Dihydrofurans from Homopropargylic Alcohols with Trifluoromethanesulfenamide.
Authors: Chen Dao‐Qian , Gao Pin , Zhou Ping‐Xin , Song Xian‐Rong , Qiu Yi‐Feng , Liu Xue‐Yuan , Liang Yong‐Min 
Published: July 2015

AbstractThe title compounds are obtained from unprotected homopropargylic alcohols with high regioselectivity.
ChemInform Abstract: Sequential One‐Pot Approach for the Synthesis of Functionalized Phthalans via Heck‐Reduction—Cyclization (HRC) Reactions.
Authors: Krishna Jonnada , Niharika Pedireddi , Satyanarayana Gedu 
Published: July 2015

AbstractA straightforward procedure for the synthesis of 1,3‐dihydroisobenzofurans via intermolecular Mizoroki‐Heck coupling of bromo benzaldehydes with β‐aryl allylic alcohols, reduction, and cyclization is elaborated.
ChemInform Abstract: Synthesis of N‐Substituted (Z)‐3‐Arylbenzo[c]thiophen‐1(3H)‐imines by the Reaction of 1‐[Aryl(methoxy)methyl]‐2‐lithiobenzenes with Isothiocyanates Followed by Acid‐Mediated Cyclization.
Authors: Kobayashi Kazuhiro , Shigemura Yuuho , Ezaki Kosuke 
Published: July 2015

AbstractThe title transformation provides benzothiophenimines some of which are further hydrolized to the corresponding benzothiophenones.
ChemInform Abstract: Highly Selective Copper‐Catalyzed Asymmetric [3 + 2] Cycloaddition of Azomethine Ylides with Acyclic 1,3‐Dienes.
Authors: Gonzalez‐Esguevillas Maria , Pascual‐Escudero Ana , Adrio Javier , Carretero Juan C. 
Published: July 2015

AbstractDepending on the catalyst either exo‐ or endo‐products are obtained preferentially, usually with ≥98% d.e.
ChemInform Abstract: One‐Pot Total Synthesis of Streptindole, Arsindoline B and Their Congeners Through Tandem Decarboxylative Deaminative Dual‐Coupling Reaction of Amino Acids with Indoles.
Authors: Xiang Jiachen , Wang Jungang , Wang Miao , Meng Xianggao , Wu Anxin 
Published: July 2015

AbstractA simple procedure is elaborated for the synthesis of arundine (VIIIa), vibrindole A (VIIIb), streptindole (VIIId), arsindole B (VIIIe), and analogues (III) and (VI).
ChemInform Abstract: Hypervalent Iodine Mediated Alkene Difunctionalization of Vinylphenols: Diastereoselective Synthesis of Substituted Indoles and Indolizines.
Authors: Zhang Kai , Wang Hang , Zheng Jingfeng , Yu Lei , Ding Hanfeng 
Published: July 2015

AbstractThe title reaction allows the facile synthesis of 3‐substituted indoles and 2‐substituted indolizines with good yields and high diastereoselectivities.
ChemInform Abstract: Efficient Access to Enantiopure 1,3‐Disubstituted Isoindolines from Selective Catalytic Fragmentation of an Original Desymmetrized Rigid Overbred Template.
Authors: Pandey Ganesh , Varkhedkar Rajesh , Tiwari Divya 
Published: July 2015

AbstractThe preparation of the asymmetric substrate (I) is elaborated and its KOtBu‐catalyzed conversion into enantiopure cis‐1,3‐disubstituted isoindoline carboxylates.
ChemInform Abstract: Catalytic Asymmetric Arylation of 3‐Indolylmethanols: Enantioselective Synthesis of 3,3′‐Bis(indolyl)oxindoles with High Atom Economy.
Authors: Sun Xiao‐Xue , Du Bai‐Xiang , Zhang Hong‐Hao , Ji Lei , Shi Feng 
Published: July 2015

AbstractThe products are delivered in high reaction yields with moderate to high enantioselectivities.
ChemInform Abstract: Pd‐Catalyzed Direct C2‐Acylation and C2,C7‐Diacylation of Indoles: Pyrimidine as an Easily Removable C—H Directing Group.
Authors: Kumar Govindharaj , Sekar Govindasamy 
Published: July 2015

AbstractThe reaction proves successful using aryl, hetaryl, alkyl, and alkenyl aldehydes as acylation agents.
ChemInform Abstract: Copper(II) Chloride Assisted Aryl Exchange in Arylmethanes: A Simple and Efficient Route to Triarylmethane Derivatives.
Authors: Kothandapani Jagatheeswaran , Ganesan Asaithampi , Vairaprakash Pothiappan , Ganesan Subramaniapillai Selva 
Published: July 2015

AbstractCopper(II) chloride promotes aryl exchange reaction of substrates such as (I) and (IV) to form the unsymmetrical triarylmethane (III).
ChemInform Abstract: Organocatalytic Enantioselective Friedel—Crafts Reaction: An Efficient Access to Chiral Isoindolo‐β‐Carboline Derivatives.
Authors: Fang Fang , Hua Genghong , Shi Feng , Li Pengfei 
Published: July 2015

AbstractThe products are obtained in moderate to excellent yields and with high to excellent enantioselectivities.
ChemInform Abstract: Nano Zirconia Catalyzed One‐Pot Synthesis of Some Novel Substituted Imidazoles under Solvent‐Free Conditions.
Authors: Bajpai Shivam , Singh Sundaram , Srivastava Vandana 
Published: July 2015

AbstractThe efficient protocol starts from isatin derivatives, ammonium acetate, and aryl aldehydes.
ChemInform Abstract: Original Synthesis of Benzo[f]indole‐4,9‐dione Derivatives Using TDAE Strategy.
Authors: Nadji‐Boukrouche Aida R. , On Sopheak , Khoumeri Omar , Terme Thierry , Vanelle Patrice 
Published: July 2015

AbstractOne‐pot Sonogashira‐cyclization reaction of bromoquinone (I) and propargyl alcohol provides benzo[f]indole‐4,9‐diones (III) and (IV).
ChemInform Abstract: Microwave‐Assisted Direct Amidation of Ethyl 1‐Phenyl‐5‐hydroxy‐1H‐pyrazole‐4‐carboxylate.
Authors: Milosevic Mladena , Sterbal Ines , Fegus Urban , Baskovc Jernej , Prek Benjamin , Groselj Uros , Stanovnik Branko , Svete Jurij 
Published: July 2015

AbstractA simple microwave‐assisted direct amidation of the title carboxylate (I) is reported which is limited to primary aliphatic amines and most reactive cyclic secondary amines, such as pyrrolidine and piperidine.
ChemInform Abstract: Synthesis of Novel Organosiliconsulfur‐Containing Tetrasubstituted Imidazoles Sonocatalyzed by LaxSr1‐xFeyCo1‐yO3 Nanoperovskites.
Authors: Safa Kazem D. , Allahvirdinesbat Maryam , Namazi Hassan 
Published: July 2015

Abstract13 Tetrasubstituted imidazoles (IV) are prepared under ultrasonic irradiation.
ChemInform Abstract: I2‐Catalyzed Synthesis of Substituted Imidazoles from Vinyl Azides and Benzylamines.
Authors: Xiang Likui , Niu Yanning , Pang Xiaobo , Yang Xiaodong , Yan Rulong 
Published: July 2015

AbstractSubstituted imidazoles are obtained by a new and efficient I2‐catalyzed oxidative tandem cyclization of various simple vinyl azides and benzylamines.
ChemInform Abstract: Cp2ZrCl2‐Catalyzed Synthesis of 2‐Aminovinyl Benzimidazoles under Microwave Conditions.
Authors: Sun Qi , Wang Cheng‐Jun , Gong Shan‐Shan , Ai Yong‐Jian , Sun Hong‐Bin 
Published: July 2015

AbstractStarting from 1,2‐phenylenediamine derivatives and 3‐aminoacrolein substrates the facile and efficient title process is developed.
ChemInform Abstract: Synthesis of Oxazolidinones from Epoxides and Isocyanates Catalyzed by Rare‐Earth‐Metal Complexes.
Authors: Wang Peng , Qin Jie , Yuan Dan , Wang Yaorong , Yao Yingming 
Published: July 2015

AbstractThe reaction tolerates a diverse range of 1‐substituted and 1,2‐disubstituted epoxides, and in most cases it proceeds with good regioselectivity in favor of the 3,5‐disubstituted vs.
ChemInform Abstract: Ligand‐Free Copper Powder‐Catalyzed and KOtBu‐Accelerated Expeditious Synthesis of Substituted Benzoxazoles.
Authors: Ahmed Atiur , Singha Raju , Ray Jayanta K. 
Published: July 2015

AbstractThis convenient and efficient cyclization reaction of ortho‐iodoanilides allows the synthesis of benzoxazoles under ligand free conditions.
ChemInform Abstract: Cu‐Catalyzed Selective Cascade sp3 C—H Bond Oxidative Functionalization Towards Isoxazoline Derivatives.
Authors: Wang Gang‐Wei , Cheng Ming‐Xing , Ma Ran‐Song , Yang Shang‐Dong 
Published: July 2015

AbstractThe first Cu‐catalyzed cascade C—H bond functionalization of various ethylazaarenes is developed.
ChemInform Abstract: Synthesis of Novel Tryptamine‐Based Macrocycles Using an Ugi 4‐CR/Microwave Assisted Click‐Cycloaddition Reaction Protocol.
Authors: Chavez‐Acevedo Lizbeth , Miranda Luis D. 
Published: July 2015

AbstractThe macrocycles comprise a peptoid moiety, a 1,3‐substituted indole nucleus and a triazole ring.
ChemInform Abstract: Intramolecular Decarboxylative Coupling as the Key Step in Copper‐Catalyzed Domino Reaction: Facile Access to 2‐(1,3,4‐Oxadiazol‐2‐yl)aniline Derivatives.
Authors: Xu Cheng , Jia Feng‐Cheng , Cai Qun , Li Deng‐Kui , Zhou Zhi‐Wen , Wu An‐Xin 
Published: July 2015

Abstract(Oxadiazolyl)aniline derivatives (III) and (V) are obtained by a copper‐catalyzed domino reaction of simple and easily available isatins and hydrazides.
ChemInform Abstract: Stereoselective Domino Conjugate Addition of Grignard Reagents to Lactones Followed by Reaction with Activated Alkenes Catalyzed by Ferrocenyl Carbene Ligands.
Authors: Soradova Zuzana , Mazikova Jana , Meciarova Maria , Sebesta Radovan 
Published: July 2015

AbstractThe products are obtained in moderate yields and with good enantioselectivities.
ChemInform Abstract: Design, Synthesis, and Anticancer Activities of New Compounds Bearing the Quinone—Pyran—Lactone Tricyclic Pharmacophore.
Authors: Jiang Xue , Wang Meining , Song Shanshan , Xu Youjun , Miao Zehong , Zhang Ao 
Published: July 2015

AbstractTricyclic quinone‐pyran‐lactone skeleton derivatives [(VII) and (VIII)] are synthesized through a simple and effective four‐step procedure.
ChemInform Abstract: Rh‐Catalyzed Direct Cyclization of 1,4‐Naphthoquinone and 9,10‐Phenanthraquinone with Alkyne: Facile Access to 1,8‐Dioxapyrenes and 1,12‐Dioxaperylenes as Orange and Red‐Emitting Luminophores.
Authors: Wang Jing , Qin Dekun , Lan Jingbo , Cheng Yangyang , Zhang Shuai , Guo Qiang , Wu Jie , Wu Di , You Jingsong 
Published: July 2015

AbstractA facile and efficient method for the synthesis of 1,8‐dioxapyrenes and 1,12‐dioxaperylenes through Rh‐catalyzed direct cyclization of 1,4‐naphthoquinones and 9,10‐phenanthraquinones with alkynes is developed.
ChemInform Abstract: Cubic Perovskite ZnTiO3 Nanopowder as a Recyclable Heterogeneous Catalyst for the Synthesis of 1,6‐Naphthyridines in Water.
Authors: Ray Suman , Das Paramita , Banerjee Biplab , Bhaumik Asim , Mukhopadhyay Chhanda 
Published: July 2015

AbstractNaphthyridines (III) are simply, highly atom‐economically, and environmentally friendly synthesized in high yields using ZnTiO3 as catalyst.
ChemInform Abstract: An Intramolecular C—N Cross‐Coupling of β‐Enaminones: A Simple and Efficient Way to Precursors of Some Alkaloids of Galipea officinalis.
Authors: Dousova Hana , Horak Radim , Ruzickova Zdenka , Simunek Petr 
Published: July 2015

AbstractA simple and efficient method for the intramolecular, palladium catalyzed amination of both chloro‐ and bromo‐substituted 3‐amino‐1,5‐diphenylpent‐2‐en‐1‐ones (I) is developed furnishing 2‐aroylmethylidene‐1,2,3,4‐tetrahydroquinolines (II) as suitable precursors for the synthesis of alkaloids from Galipea officinalis.
ChemInform Abstract: A General Synthesis of Bis(o‐azaheteroaryl)methane Derivatives from N‐Oxides of Azines and Azoles.
Authors: Szpunar Magdalena , Loska Rafal 
Published: July 2015

AbstractThe Et3N‐mediated reaction of methyl esters (I) and (VI) with N‐oxides (II) leads to desired adducts (III) and (VII), which can be converted in BODIPY analogues (V) and (IX).
ChemInform Abstract: Cu‐Catalyzed Aerobic Oxidative Cyclizations of 3‐N‐Hydroxyamino‐1,2‐propadienes with Alcohols, Thiols, and Amines to Form α‐O‐,S‐, and N‐Substituted 4‐Methylquinoline Derivatives.
Authors: Sharma Pankaj , Liu Rai‐Shung 
Published: July 2015

AbstractA catalyzed aerobic oxidation of N‐hydroxyaminoallenes in the presence of a range of O‐, N‐, and S‐nucleophiles to afford 3‐substituted‐2‐en‐1‐ones is reported.
ChemInform Abstract: Indium‐Catalyzed C(sp3)—H Functionalization of 2‐Methylazaarenes Through Direct Benzylic Addition to Trifluoromethyl Ketones.
Authors: Jamal Zaini , Teo Yong‐Chua 
Published: July 2015

AbstractThe efficient protocol is not transferable to the benzylic addition to other types of ketone derivatives such as acetophenone and benzophenone.
ChemInform Abstract: Palladium‐Catalyzed Highly Efficient Synthesis of Functionalized Indolizines via Cross‐Coupling/Cycloisomerization Cascade.
Authors: Zhang Liangwei , Li Xiangdong , Liu Yuanhong , Zhang Dayong 
Published: July 2015

AbstractA wide range of 1,3‐disubstituted indolizines are obtained by Pd‐catalyzed reaction of 3‐(2‐pyridyl) propargyl carbonates with organoboronic acids.
ChemInform Abstract: A Convenient Synthesis of Pyridophenanthroline Derivatives under Catalyst Free Conditions.
Authors: Mu Xing‐Ye , Li Chao , Li Yu‐Ling , Liu Yun , Wang Xiang‐Shan 
Published: July 2015

Abstractvia three‐component reaction of aminoquinolines with piperidinedione (II) and aromatic aldehydes
ChemInform Abstract: Synthesis of New 1, 10‐Phenanthroline Analogues as Potent Antimicrobial Agents Using Montmorillonite K‐10 as Catalyst.
Authors: Pagadala Ramakanth , Chidurala Praveen , Jetti Venkateshwarlu , Meshram Jyotsna S. , Maddila Suresh , Jonnalagadda Sreekanth B. 
Published: July 2015

AbstractA series of new 1, 10‐phenanthroline derivatives (IV) are synthesized by four‐component domino reaction of 8‐hydroxyquinoline with aromatic aldehydes, acetoacetates and ammonium acetate under both conventional thermal or microwave irradiation conditions.
ChemInform Abstract: Cobalt(III)‐Catalyzed Directed C—H Coupling with Diazo Compounds: Straightforward Access Towards Extended π‐Systems.
Authors: Zhao Dongbing , Kim Ju Hyun , Stegemann Linda , Strassert Cristian A. , Glorius Frank 
Published: July 2015

AbstractFor the first time, an efficient and scalable cobalt‐catalyzed directed C—H functionalization with carbene precursors is presented.
ChemInform Abstract: Rh(III)‐Catalyzed Oxidative Annulation of 2‐Phenylimidazo[1,2‐a]pyridines with Alkynes: Mono versus Double C—H Activation.
Authors: Qi Zisong , Yu Songjie , Li Xingwei 
Published: July 2015

AbstractWhile in the presence of AgOAc as oxidant only imidazopyridines are obtained, AgBF4 leads to isoquinolinium salts via mono C—H activation.
ChemInform Abstract: Tetrabutylammonium‐Assisted Diastereoselective [6π]‐Photocyclization of Acrylanilides.
Authors: Yamada Shinji , Okuda Mai , Yamamoto Natsuo 
Published: July 2015

AbstractTetrabutylammonium bromide is remarkably effective for improving the diastereoselectivity for [6π]‐photocyclization reactions of acrylanilides to form predominantly trans‐dihydroquinolines.
ChemInform Abstract: Palladium‐Catalyzed Dicarbonylative Synthesis of Tetracycle Quinazolinones.
Authors: Shen Chaoren , Man Nikki Y. T. , Stewart Scott , Wu Xiao‐Feng 
Published: July 2015

AbstractStarting from 2‐bromobenzylamines, 2‐bromoanilines, and carbon monoxide the title transformation is effectively performed.
ChemInform Abstract: Al(H2PO4)3 as an Efficient and Recyclable Catalyst for the One‐Pot Synthesis of Naphthopyranopyrimidines.
Authors: Sajadikhah Seyed Sajad 
Published: July 2015

AbstractThe eco‐friendly reaction is successfully performed starting from 2‐naphthol, 6‐amino‐1,3‐dimethyl uracil, and a diverse range of aryl aldehydes, but fails using aliphatic aldehydes.
ChemInform Abstract: A POCl3‐Mediated Synthesis of Substituted Fused Azoacridones Derivatives.
Authors: Li Xi , Gao Chunmei , Yang Ti , Zhang Bin , Tan Chunyan , Liu Hongxia , Jiang Yuyang 
Published: July 2015

AbstractPyrimidine‐2,4‐diamines symmetrically or unsymmetrically N‐substituted with anthranilic acids are transformed according to a simple and efficient protocol.
ChemInform Abstract: Synthesis of Fused 9,10‐Dihydro‐6H‐azepino‐ and 9,10‐Dihydro‐6H‐[1,3]diazepino[1,2‐e]purines via Ring Closing Metathesis as Antilipid Peroxidation Agents.
Authors: Thalassitis Andreas N. , Hadjipavlou‐Litina Dimitra J. , Litinas Konstantinos E. 
Published: July 2015

AbstractNew compounds are tested as inhibitors of lipid peroxidation.
ChemInform Abstract: An Efficient Cascade Approach to Dibenzoxazepinones via Nucleophilic Aromatic Substitution and Smiles Rearrangement.
Authors: Liu Shihui , Hu Ying , Qian Pengfei , Hu Yanwei , Ao Guizhen , Chen Shaohua , Zhang Shilei , Zhang Yinan 
Published: July 2015

AbstractVarious substituted benzamides react with electron‐neutral and electron‐rich phenols to give dibenzoxazepinones.
ChemInform Abstract: Iron‐Catalyzed Asymmetric Hydrosilylation of 1,1‐Disubstituted Alkenes.
Authors: Chen Jianhui , Cheng Biao , Cao Minyi , Lu Zhan 
Published: July 2015

AbstractThe first enantioselective iron‐catalyzed anti‐Markovnikov hydrosilylation of 1,1‐disubstituted aryl alkenes is described.
ChemInform Abstract: Asymmetric Synthesis of α‐Hydroxymethylphosphonates and Phosphonic Acids via Hydrophosphonylation of Aldehydes with Chiral H‐Phosphonate.
Authors: Olszewski Tomasz K. 
Published: July 2015

AbstractThe scalable reaction is performed using aryl, hetaryl, and alkyl aldehydes and provides the corresponding α‐hydroxymethylphosphonates with high yield and high diastereomeric excess.
ChemInform Abstract: Room Temperature C—P Bond Formation Enabled by Merging Nickel Catalysis and Visible‐Light‐Induced Photoredox Catalysis.
Authors: Xuan Jun , Zeng Ting‐Ting , Chen Jia‐Rong , Lu Liang‐Qiu , Xiao Wen‐Jing 
Published: July 2015

AbstractThe dual‐catalytic reaction between diarylphosphine oxides and aryl iodides shows good functional group tolerance and allows the synthesis of various triarylphosphine oxides.
ChemInform Abstract: A Silver‐Initiated Free‐Radical Intermolecular Hydrophosphinylation of Unactivated Alkenes.
Authors: Li Zejiang , Fan Fenghua , Zhang Zengyan , Xiao Yingxia , Liu Dong , Liu Zhong‐Quan 
Published: July 2015

AbstractA variety of alkyldiphenylphosphine oxides [(III), (V), (VII), (IX), and (XI)], alkyl phosphinates (XIa), and alkyl phosphonates (XIb) are facilely prepared via addition of H—P(O) compounds with unactivated alkenes through a silver(I)‐triggered free radical intermolecular C—P bond formation.
ChemInform Abstract: Preparation of 2H‐5,6‐Dihydroselenines Using α‐Alkoxy Carbonylselenoacetamide.
Authors: Ohnuma Akira , Nagata Tomohiro , Komura Kenichi , Ando Hiromune , Ishihara Hideharu , Koketsu Mamoru 
Published: July 2015

Abstractand α,β‐unsaturated ketones
ChemInform Abstract: Synthesis and Selenation of Tandem Multicomponent Condensation Adducts.
Authors: Hua Guoxiong , Du Junyi , Fuller Amy L. , Arachchige Kasun S. A. , Cordes David B. , Slawin Alexandra M. Z. , Woollins J. Derek 
Published: July 2015

AbstractSome four‐component condensation adducts are readily obtained by one‐pot reaction of aryl carboxylic acids, aryl aldehydes, arylamines, and c‐hexylisocyanide and treated with Woollins′ reagent leading to the formation of a series of new selenoamides.
ChemInform Abstract: Copper‐Catalyzed Asymmetric Three‐Component Borylstannation: Enantioselective Formation of C—Sn Bond.
Authors: Jia Tao , Cao Peng , Wang Ding , Lou Yazhou , Liao Jian 
Published: July 2015

AbstractA simple one‐pot procedure using the chiral ligand (PPS) allows the synthesis of enantioenriched β‐boryl alkylstannanes through copper‐catalyzed borylstannation of the corresponding aryl substituted alkenes.
ChemInform Abstract: Alkynylation of Steroids via Pd‐Free Sonogashira Coupling.
Authors: Kotovshchikov Yury N. , Latyshev Gennadij V. , Lukashev Nikolay V. , Beletskaya Irina P. 
Published: July 2015

AbstractCu‐catalyzed Pd‐free Sonogashira is proposed as a straightforward and convenient route to valuable steroidal enynes using a biligand catalyst system based on Ph3P and TMEDA.
ChemInform Abstract: An Cost‐Effective and Safe Process of L‐cis‐4,5‐Methanoproline Amide, the Key Synthetic Intermediate of Saxagliptin, via an Improved Simmons—Smith Reaction.
Authors: Liu Feng , Ding Ding , Pan Xianhua , Yu Wansheng , Li Xiaojun , Chen Suke 
Published: July 2015

AbstractThe title compound (III) is obtained with excellent diastereoselectivity under optimized and improved Simmons—Smith reaction conditions.
ChemInform Abstract: IBr‐Catalyzed O‐Glycosylation of D‐Glucals: Facile Synthesis of 2,3‐Unsaturated‐O‐glycosides.
Authors: Sirion Uthaiwan , Saeeng Rungnapha , Siripru Onanong 
Published: July 2015

Abstract2,3‐Unsaturated glycosides (20 examples) are obtained with good α‐selectivity by Ferrier rearrangement of tri‐O‐acetyl‐D‐glucal (I) in the presence of various alcohols (II).
ChemInform Abstract: Total Synthesis of Each Enantiomer of Falcarinol (Ia) and Panaxjapyne A (Ib) via Asymmetric Catalytic Alkynylation of an Aldehyde.
Authors: Yang Yan‐Qing , Li Shuo‐Ning , Zhong Jiang‐Chun , Zhou Yun , Zeng Hao‐Zhe , Duan Hong‐Jie , Bian Qing‐Hua , Wang Min 
Published: July 2015

AbstractThe racemic mixtures (I) are synthesized and each enantiomer thereof are isolated and structurally characterized.
ChemInform Abstract: Dynamic Inclusion Complexes of Metal Nanoparticles Inside Nanocups.
Authors: Alarcon‐Correa Mariana , Lee Tung‐Chun , Fischer Peer 
Published: July 2015

AbstractA generic strategy towards the fabrication of dynamic 1:1 inclusion complexes of metal nanoparticles inside oxide nanocups with high yield (<70%) and regiospecificity (<90%) is demonstrated.
ChemInform Abstract: Deoxygenation of Biobased Molecules by Decarboxylation and Decarbonylation — A Review on the Role of Heterogeneous, Homogeneous and Bio‐Catalysis
Authors: Dawes Gwen J. S. , Scott Elinor L. , Le Notre Jerome , Sanders Johan P. M. , Bitter Johannes H. 
Published: July 2015

AbstractReview: 222 refs.
ChemInform Abstract: Quinoxaline, Its Derivatives and Applications: A State of the Art Review
Authors: Pereira Joana A. , Pessoa Ana M. , Cordeiro M. Natalia D. S. , Fernandes Ruben , Prudencio Cristina , Noronha Joao Paulo , Vieira Monica 
Published: July 2015

AbstractReview: [63 refs.
ChemInform Abstract: Recent Advanced in Bioactive Systems Containing Pyrazole Fused with a Five Membered Heterocycle
Authors: Raffa Demetrio , Maggio Benedetta , Raimondi Maria Valeria , Cascioferro Stella , Plescia Fabiana , Cancemi Gabriella , Daidone Giuseppe 
Published: July 2015

AbstractReview: 60 refs.
Preparation and Intramolecular CC Coupling Reaction for Bis‐benzimidazolium Salt
Authors: Liu Rui , Huo Ran , Bi Yue , Zhao Zhixiang , Liu Qingxiang 
Published: July 2015

AbstractBis‐benzimidazolium salt 1 was prepared via a series of reactions using 2,2′‐diphenol as starting material. Compound 2 was afforded through the intramolecular CC coupling reaction of 1 under the catalysis of Pd(OAc)2. The structure of 2 is characterized through X‐ray diffraction analyses, 1H NMR and 13C NMR. In 2, two boat‐like seven‐membered rings are contained, where the CC bond distance newly formed is 1.461(5) Å, and it is between regular CC single bond (1.54 Å) and CC double bond (1.34 Å). This shows that new CC bond has partial double‐bond character. In the crystal packing of 2, the 2D supramolecular layers are formed via CH···F hydrogen bond.
Separation of Amyl Alcohol Isomers in ZIF‐77
Authors: Bueno‐Perez Rocio , Gutiérrez‐Sevillano Juan J. , Dubbeldam David , Merkling Patrick J. , Calero Sofia 
Published: July 2015

AbstractThe separation of pentanol isomer mixtures is shown to be very efficient using the nanoporous adsorbent zeolitic imidazolate framework ZIF‐77. Through molecular simulations, we demonstrate that this material achieves a complete separation of linear from monobranched—and these from dibranched—isomers. Remarkably, the adsorption and diffusion behaviors follow the same decreasing trend, produced by the channel size of ZIF‐77 and the guest shape. This separation based on molecular branching applies to alkanes and alcohols and promises to encompass numerous other functional groups.