bluuebunny/crossref_metadata_2025_split huggingface dataset:
Nanocatalysts for Solar Water Splitting and a Perspective on Hydrogen Economy
Authors: Grewe Tobias , Meggouh Mariem , Tüysüz Harun 
Published: September 2015

AbstractIn this review article, nanocatalysts for solar hydrogen production are the focus of discussion as they can contribute to the development of sustainable hydrogen production in order to meet future energy demands. Achieving this task is subject of scientific aspirations in the field of photo‐ and photoelectrocatalysis for solar water splitting where systems of single catalysts or tandem configurations are being investigated. In search of a suitable catalyst, a number of crucial parameters are laid out which need to be considered for material design, in particular for nanostructured materials that provide exceptional physical and chemical properties in comparison to their bulk counterparts. Apart from synthetic approaches for nanocatalysts, key parameters and properties of nanostructured photocatalysts such as light absorption, charge carrier generation, charge transport, separation and recombination, and other events that affect nanoscale catalysts are discussed. To provide a deeper understanding of these key parameters and properties, their contribution towards existing catalyst systems is evaluated for photo‐ and photoelectrocatalytic solar hydrogen evolution. Finally, an insight into hydrogen production processes is given, stressing the current development of sustainable hydrogen sources and presenting a perspective towards a hydrogen‐based economy.
Validated spectrofluorimetric method for the determination of clonazepam in pharmaceutical preparations
Authors: Ibrahim Fawzia , El‐Enany Nahed , Shalan Shereen , Elsharawy Rasha 
Published: September 2015

AbstractA simple, highly sensitive and validated spectrofluorimetric method was applied in the determination of clonazepam (CLZ). The method is based on reduction of the nitro group of clonazepam with zinc/CaCl2, and the product is then reacted with 2‐cyanoacetamide (2‐CNA) in the presence of ammonia (25%) yielding a highly fluorescent product. The produced fluorophore exhibits strong fluorescence intensity at ʎem = 383 nm after excitation at ʎex = 333 nm. The method was rectilinear over a concentration range of 0.1–0.5 ng/mL with a limit of detection (LOD) of 0.0057 ng/mL and a limit of quantification (LOQ) of 0.017 ng/mL. The method was fully validated and successfully applied to the determination of CLZ in its tablets with a mean percentage recovery of 100.10 ± 0.75%. Method validation according to ICH Guidelines was evaluated. Statistical analysis of the results obtained using the proposed method was successfully compared with those obtained using a reference method, and there was no significance difference between the two methods in terms of accuracy and precision. Copyright © 2015 John Wiley & Sons, Ltd.
Allenic Esters from Cyclopropenones by Lewis Base Catalysis: Substrate Scope, the Asymmetric Variant from the Dynamic Kinetic Asymmetric Transformation, and Mechanistic Studies
Authors: Wei Yin , Zhao Wen‐Tao , Yang Yuan‐Liang , Zhang Zhen , Shi Min 
Published: September 2015

AbstractThe Lewis base catalyzed reactions of cyclopropenones with a variety of nucleophiles (alcohols, phenols, or water) were systematically investigated. We demonstrated that this kind of reaction could be used to synthesize allenic esters in moderate to excellent yields. Furthermore, more synthetically interesting axially chiral allenes in moderate to good yields and ee values were obtained in the corresponding asymmetric reaction in the presence of multifunctional chiral phosphine catalyst. The reaction mechanism was disclosed by using NMR tracing experiments, MS, and DFT calculations. Notably, the asymmetric reaction was proved to be a dynamic kinetic asymmetric transformation based on the control experiments, and the detailed mechanism of this transformation revealed by theoretical investigations.
Co‐Metal Catalysts on SiO2‐TiO2 for Methanol Production from CO2 – Effect of Preparation Methods
Authors: Siwawut Jittawat , Namkhang Pornpan , Kongkachuichay Paisan 
Published: September 2015

AbstractThe effect of quantity, composition, and different impregnation sequences on the catalytic properties of Cu‐Zn‐Al/SiO2‐TiO2 in the CO2 hydrogenation for methanol production was investigated. The Cu‐Zn‐Al catalysts supported on SiO2 and TiO2 were prepared by incipient wetness impregnation. Then, their performances in CO2 hydrogenation were tested under defined conditions. The composition variation of Cu and Zn catalysts resulted in a high methanol production for Cu catalysts with a higher content of Cu, which was the active site for CO2 activation. Regarding the metal quantity of catalysts, a relatively low loading of co‐metal (Cu‐Zn‐Al) led to the maximum methanol yield when compared with higher loadings as a result of the largest surface area.
Effect of Process Parameters on Properties of Colloids in a Continuous‐Flow Microreactor System
Authors: Sonawane Shirish H. , Bari Mahendra L. , Suryawanshi Prashant L. , Narkhede Jitendra S. , Mishra Satyendra , Bhanvase Bharat A. 
Published: September 2015

AbstractThe effect of reactant concentration, flow rate, and surfactant type on the size and distribution of synthesized nanoparticles was studied. Two tubular microreactors made of polyvinyl chloride (PVC) and stainless steel (SS) were used for production of iron oxide nanoparticles from FeCl3 and NaBH4 as precursors by a chemical reduction route. The diameter of the microreactor and other process parameters were found to influence the size and size distribution of iron oxide nanoparticles. The axial dispersion in the PVC microreactor was less than in the SS microreactor due the large ratio of microreactor volume to flow rate. The formation of iron oxide was detected by Fourier transform infrared, X‐ray diffraction, and field emission scanning electron microscopy (FESEM). Synthesis of stable colloidal iron oxide nanoparticles with narrow size distribution in this continuous‐flow microreactor system was confirmed.
Electrochemical Study of Interfacially Synthesized Polycarbazole with Different Oxidants
Authors: Kumar Ashish , Tiwari Madhu , Prakash Rajiv 
Published: September 2015

AbstractThis work focused on the morphology‐controlled electrochemical impedance spectroscopic (EIS) studies of polycarbazole (PCz) in two different electrolytes. PCz is synthesized through controlled interfacial polymerization by using two different oxidizing agents, (NH4)2S2O8(APS) and KMnO4. Voltammetric and EIS studies were carried out to explore charge‐transfer properties in the vicinity of modified PCz/glassy carbon (GC) and PCz/Pt electrodes with different electrolytes that have different‐sized anions. It has been observed that PCz–APS exhibits enhanced electron‐transfer kinetics compared to PCz–KMnO4at either electrode (GC or Pt) in a supporting electrolyte with a smaller anion size. This is attributed to its favorable diffusion inside the porous polymer film, resulting in easy ion exchange at the electrode surface. The morphology‐controlled synthesis approach presented herein is extremely significant for chemical sensors, biosensors, and catalytic applications, owing to its high electroactivity.
Synthesis of Functionalized Mono‐, Bis‐, and Trisethynyltriptycenes for One‐Dimensional Self‐Assembly on Surfaces
Authors: Sirven Agnès M. , Garbage Romain , Qiao Yun , Kammerer Claire , Rapenne Gwénaël 
Published: September 2015

AbstractThis paper describes the synthesis of triptycene‐based building blocks that are able to interact through hydrogen bonds to form one‐dimensional self‐assembled motifs on surfaces. We designed 9,10‐diethynyltriptycene derivatives functionalized at the ethynyl end groups by a variety of hydrogen‐bonding groups for homomolecular recognition and complementary building blocks for heteromolecular recognition. We also present the synthesis of bis‐ and trisethynyltriptycenes with terminal alkyne functional groups available for on‐surface azide–alkyne cycloaddition reaction to expand the potential of the triptycene building block.
ChemInform Abstract: Synthesis and Crystal Structures of the Calcium Silicon Phosphides Ca2Si2P4, Ca3Si8P14and Ca3Si2P4.
Authors: Zhang Xiang , Yu Tongtong , Li Chunlong , Wang Shanpeng , Tao Xutang 
Published: September 2015

AbstractThe title compounds are prepared by solid state reactions of the elements with the same reactant ratio Ca:Si:P = 1:1:2 but at different reaction temperatures (graphite crucibles, 900, 1100, and 1150 °C, resp., 72 h).
ChemInform Abstract: High‐Level Doping of Nitrogen, Phosphorus, and Sulfur into Activated Carbon Monoliths and Their Electrochemical Capacitances.
Authors: Hasegawa George , Deguchi Takeru , Kanamori Kazuyoshi , Kobayashi Yoji , Kageyama Hiroshi , Abe Takeshi , Nakanishi Kazuki 
Published: September 2015

AbstractActivated carbon monoliths prepared from resorcinol‐formaldehyde gels by carbonization (1000 °C, 2 h) under N2 and CO2 are doped by N using urea, a mixture of NaNH2 and NH4Cl, or hexamethylenetetramine, by red P, and by S using a mixture of Na2S2O5 and Na2S2O7 whereby the activated carbon and the dopant are separated from each other within the reaction tubes (Pyrex or quartz tubes, 1.
ChemInform Abstract: Phase‐Vanishing Method with Acetylene Evolution and Its Utilization in Several Organic Syntheses.
Authors: Matake Ryosuke , Niwa Yuki , Matsubara Hiroshi 
Published: September 2015

AbstractA novel quadraphasic phase‐vanishing system is developed in which acetylene is released from calcium carbide and directly applied in Sonogashira coupling reactions, click reactions and three‐component carbonyl—amine—alkyne coupling reactions.
ChemInform Abstract: Lewis Acidity of Bis(perfluorocatecholato)silane: Aldehyde Hydrosilylation Catalyzed by a Neutral Silicon Compound.
Authors: Liberman‐Martin Allegra L. , Bergman Robert G. , Tilley T. Don 
Published: September 2015

AbstractThe novel Lewis acid catalyst bis(perfluorocatecholato)silane (BPS) is prepared and applied to the hydrosilylation of electron‐deficient aldehydes.
ChemInform Abstract: A Highly Active Palladium(II)—Bis(oxazoline) Catalyst for Suzuki—Miyaura, Mizoroki—Heck and Sonogashira Coupling Reactions in Aqueous Dimethylformamide.
Authors: Ibrahim Mansur B. , El Ali Bassam , Fettouhi Mohammed , Ouahab Lahcene 
Published: September 2015

AbstractAn efficient catalytic system for the title cross coupling reactions based on a novel palladium‐bis(oxazoline) complex is developed which exhibits exceptional air and moisture stability.
ChemInform Abstract: Arylation of Diethyl Malonate and Ethyl Cyanoacetate Catalyzed by Palladium/Di‐tert‐Butylneopentylphosphine.
Authors: Semmes Jeffrey G. , Bevans Stephanie L. , Mullins C. Haddon , Shaughnessy Kevin H. 
Published: September 2015

AbstractIt is demonstrated, that the title catalyst system renders possible the efficient arylation of substrates (I) and (V) with a wide variety of aryl bromides and chlorides.
ChemInform Abstract: Phosphine‐Mediated Addition of 1,2‐Dicarbonyls to Diazenes: An Umpolung Approach Toward N‐Acyl Hydrazone Synthesis.
Authors: Haugen Kasey C. , Rodriguez Kevin X. , Chavannavar Aditi P. , Oliver Allen G. , Ashfeld Brandon L. 
Published: September 2015

AbstractThe direct access to N‐acyl hydrazones is rendered possible by hexamethylphosphorous mediated condensation of various 1,2‐dicarbonyl compounds with dialkylazodicarboxylates.
ChemInform Abstract: Ligand‐Controlled Regioselective Copper‐Catalyzed Trifluoromethylation to Generate (Trifluoromethyl)allenes.
Authors: Ambler Brett R. , Peddi Santosh , Altman Ryan A. 
Published: September 2015

AbstractThe ability of bipyridyl‐derived ligands to control the regioselectivity of Cu‐catalyzed nucleophilic trifluoromethylation reactions of propargyl electrophiles to generate (trifluoromethyl)allenes is demonstrated for the first time.
ChemInform Abstract: Alkyl Aryl Ether Bond Formation with PhenoFluor.
Authors: Shen Xiao , Neumann Constanze N. , Kleinlein Claudia , Goldberg Nathaniel W. , Ritter Tobias 
Published: September 2015

AbstractStarting from aliphatic alcohols or phenols the title reaction has been elaborated providing challenging alkylaryl ethers which are difficult to access by conventional Mitsunobu conditions.
ChemInform Abstract: I2/Cu‐Mediated Self‐Sorting Domino Reaction of Aryl β‐Ketoesters into Symmetrical 2‐Carboalkoxy‐1,4‐enediones: Application to Synthesis of Pyrazine, β‐Carboline and Quinoxalines.
Authors: Satish Gandhesiri , Ilangovan Andivelu 
Published: September 2015

AbstractSymmetrical 1,4‐enediones (II) are obtained from aryl‐β‐ketoesters (I) by a self‐sorting domino reaction involving tandem iodination, self‐dimerization, and Krapcho dealkoxycarbonylation in one‐pot.
ChemInform Abstract: Synthesis of Cyclopropyl‐Substituted Furans by Broensted Acid Promoted Cascade Reactions.
Authors: Clark J. Stephen , Romiti Filippo , Hogg Kirsten F. , Hamid Malai Haniti S. A. , Richter Sven C. , Boyer Alistair , Redman Joanna C. , Farrugia Louis J. 
Published: September 2015

AbstractA high‐yielding, diastereoselective intramolecular reaction cascade reaction is developed creating three new bonds in a single step, thus providing 2,3,5‐substituted furans bearing a ring fused cyclopropyl substituent.
ChemInform Abstract: The Cyano Group as a Traceless Activation Group for the Intermolecular [3 + 2] Cycloaddition of Azomethine Ylides: A Five‐Step Synthesis of (.+‐.)‐Isoretronecanol.
Authors: Li Jundong , Zhao Huaibo , Jiang Xunjin , Wang Xiance , Hu Haiming , Yu Lei , Zhang Yandong 
Published: September 2015

AbstractThe 1,3‐dipolar cycloaddition of cyano substituted azomethine ylides with acyclic esters and subsequent reductive removal of the cyano group to form the resulting pyrrolidines offers a straightforward synthesis of pyrrolidines.
ChemInform Abstract: Transformation of N,N‐Dimethylaniline‐N‐oxides into N‐Methylindolines by a Tandem Polonovski—Mannich Reaction.
Authors: Nakashige Mika L. , Lewis Robert S. , Chain William J. 
Published: September 2015

AbstractA novel synthesis of N‐substituted indolines is achieved by Polonovsi—Mannich type cyclization of N,N‐dimethylaniline‐N‐oxides (I) having an ester or cyano substituted ortho‐methyl side chain.
ChemInform Abstract: Highly Regioselective Arylation of 1,2,3‐Triazole N‐Oxides with Sodium Arenesulfinates via Palladium‐Catalyzed Desulfitative Cross‐Coupling Reaction.
Authors: Zhu Jiayi , Chen Yu , Lin Feng , Wang Baoshuang , Huang Qing , Liu Liangxian 
Published: September 2015

AbstractFor the convenient and highly regioselective direct C5‐arylation of 1,2,3‐triazole oxides sodium arylsulfinates, diphenylphosphine oxide, and triphenylphosphine can be used as arylation agents.
ChemInform Abstract: Studies in Selective 6‐Membered Bromoether Formation via Bromonium and Thiiranium‐Induced Cyclizations.
Authors: Levinson Adam M. , Milner Phillip J. , Snyder Scott A. 
Published: September 2015

AbstractSeveral methods for the synthesis of brominated 2,2,6,6‐tertasubstituted tetrahydropyrans are explored.
ChemInform Abstract: Synthesis of [1,2,3]Triazolo[5,1‐]isoquinoline Derivatives via a Selective Cascade Cyclization Sequence of 1,2‐Bis(Phenylethynyl)benzene Derivatives.
Authors: Tao Shipeng , Hu Qinquan , Li Huan , Ma Shan , Chen Yunfeng 
Published: September 2015

AbstractThe regioselectivity is determined by the two substituents in the alkynes of 1,2‐diethynylbenzenes.
ChemInform Abstract: An Efficient Route to Novel Uracil‐Based Drug‐Like Molecules.
Authors: Babkov Denis A. , Chizhov Alexander O. , Khandazhinskaya Anastasia L. , Corona Angela , Esposito Francesca , Tramontano Enzo , Seley‐Radtke Katherine L. , Novikov Mikhail S. 
Published: September 2015

AbstractNumerous benzophenone‐derived uracil derivatives are prepared and evaluated towards their inhibition of the RNA‐dependent DNA‐polymerase activity of HIV‐1 reverse transcriptase.
ChemInform Abstract: Simple and Highly Efficient Synthesis of Indolo‐ and Pyrrolo[1,2‐a]quinoxalines Promoted by Molecular Iodine.
Authors: Ramamohan Mekala , Sridhar Regati , Raghavendrarao Kamaraju , Paradesi Naidu , Chandrasekhar Kothapally Bannoth , Jayaprakash Sarva 
Published: September 2015

AbstractThe N‐heterocyclic title compounds are furnished by the reaction of (aminophenyl)pyrroles and indoles with benzylamines in presence of I2.
ChemInform Abstract: Synthesis of an [(NHC)2Pd(SiMe3)2] Complex and Catalytic cis‐Bis(silyl)ations of Alkynes with Unactivated Disilanes.
Authors: Ansell Melvyn B. , Roberts Debbie E. , Cloke F. Geoffrey N. , Navarro Oscar , Spencer John 
Published: September 2015

AbstractThe reaction tolerates electronically and sterically challenging internal 1,2‐diarylacetylenes, 1‐alkyl‐2‐arylacetylenes including 1‐phenyl‐2‐trimethylsilylacetylene as well as terminal arylacetylenes, but no terminal alkylacetylenes, thus allowing for the (Z)‐selective synthesis of novel 1,2‐disilyl stilbene derivatives in high yield.
ChemInform Abstract: Gloeophyllins A—J, Cytotoxic Ergosteroids with Various Skeletons from a Chinese Tibet Fungus Gloeophyllum abietinum.
Authors: Han Jun‐Jie , Bao Li , Tao Qiao‐Qiao , Yao Yi‐Jian , Liu Xing‐Zhong , Yin Wen‐Bing , Liu Hong‐Wei 
Published: September 2015

AbstractTen new ergosteroids [e.g. (I) to (IV)] are isolated and their cytotoxicity is tested.
ChemInform Abstract: π‐Rich σ2P‐Heterocycles: d10‐Transition Metal Complexes of 1H‐1,3‐Benzazaphospholes with Unusual Coordination
Authors: Ghalib Mohammed , Heinicke Joachim W. , Jones Peter G. , Schulzke Carola 
Published: September 2015

AbstractReview: 13 refs.
ChemInform Abstract: Efficient Stereoselective Synthesis of Boron L‐amino Acid Derivatives Using Wittig and Borylation Reactions
Authors: Audi Hassib , Remond Emmanuelle , Eymin Marie‐Joelle , Tessier Arnaud , Malacea‐Kabbara Raluca , Juge Sylvain 
Published: September 2015

AbstractReview: 8 refs.
ChemInform Abstract: Excitation Wavelength Dependence of the Solvation Dynamics of 4′‐N,N‐Diethylamino‐3‐methoxyflavon in Ionic Liquids
Authors: Kimura Yoshifumi , Suda Kayo , Shibuya Mako , Yasaka Yoshiro , Ueno Masakatsu 
Published: September 2015

AbstractReview: 21 refs.
Inner Surface Chirality of Single‐Handed Twisted Carbonaceous Tubular Nanoribbons
Authors: Liu Dan , Li Baozong , Guo Yongmin , Li Yi , Yang Yonggang 
Published: September 2015

AbstractSingle‐handed twisted 4,4′‐biphenylene‐bridged polybissilsesquioxane tubular nanoribbons and single‐layered nanoribbons were prepared by tuning the water/ethanol volume ratio in the reaction mixture at pH = 11.6 through a supramolecular templating approach. The single‐layered nanoribbons were formed by shrinking tubular nanoribbons after the removal of the templates. In addition, solvent‐induced handedness inversion was achieved. The handedness of the polybissilsesquioxanes could be controlled by changing the ethanol/water volume ratio in the reaction mixture. After carbonization at 900 °C for 4.0 h and removal of silica, single‐handed twisted carbonaceous tubular nanoribbons and single‐layered nanoribbons with micropores in the walls were obtained.X‐ray diffraction and Raman spectroscopy analyses indicated that the carbon is predominantly amorphous. The circular dichroism spectra show that the twisted tubular nanoribbons exhibit optical activity, while the twisted single‐layered nanoribbons do not. The results shown here indicate that chirality is transferred from the organic self‐assemblies to the inner surfaces of the 4,4′‐biphenylene‐bridged polybissilsesquioxane tubular nanoribbons and subsequently to those of the carbonaceous tubular nanoribbons. Chirality 27:809–815, 2015. © 2015 Wiley Periodicals, Inc.
Preparative Enantioseparation of β‐Substituted‐2‐Phenylpropionic Acids by Countercurrent Chromatography With Substituted β‐Cyclodextrin as Chiral Selectors
Authors: Tong Shengqiang , Zhang Hu , Cheng Dongping 
Published: September 2015

AbstractPreparative enantioseparation of four β‐substituted‐2‐phenylpropionic acids was performed by countercurrent chromatography with substituted β‐cyclodextrin as chiral selectors. The two‐phase solvent system was composed of n‐hexane‐ethyl acetate‐0.10 mol L‐1 of phosphate buffer solution at pH 2.67 containing 0.10 mol L‐1 of hydroxypropyl‐β‐cyclodextrin (HP‐β‐CD) or sulfobutylether‐β‐cyclodextrin (SBE‐β‐CD). The influence factors, including the type of substituted β‐cyclodextrin, composition of organic phase, concentration of chiral selector, pH value of the aqueous phase, and equilibrium temperature were optimized by enantioselective liquid–liquid extraction. Under the optimum separation conditions, 100 mg of 2‐phenylbutyric acid, 100 mg of tropic acid, and 50 mg of 2,3‐diphenylpropionic acid were successfully enantioseparated by high‐speed countercurrent chromatography, and the recovery of the (±)‐enantiomers was in the range of 90–91% for (±)‐2‐phenylbutyric acid, 91–92% for (±)‐tropic acid, 85–87% for (±)‐2,3‐diphenylpropionic acid with purity of over 97%, 96%, and 98%, respectively. The formation of 1:1 stoichiometric inclusion complex of β‐substituted‐2‐phenylpropionic acids with HP‐β‐CD was determined by UV spectrophotometry and the inclusion constants were calculated by a modified Benesi‐Hildebrand equation. The results showed that different enantioselectivities among different racemates were mainly caused by different enantiorecognition between each enantiomer and HP‐β‐CD, while it might be partially caused by different inclusion capacity between racemic solutes and HP‐β‐CD. Chirality 27:795–801, 2015. © 2015 Wiley Periodicals, Inc.
Multifunctional Nitrogen‐Doped Carbon Nanodots for Photoluminescence, Sensor, and Visible‐Light‐Induced H2 Production
Authors: Yang Pengju , Zhao Jianghong , Wang Jian , Cui Huijuan , Li Li , Zhu Zhenping 
Published: September 2015

AbstractHerein, multifunctional N‐doped carbon nanodots (NCNDs) were prepared through the one‐step hydrothermal treatment of yeast. Results show that the NCNDs can be used as a new photocatalyst to drive the water‐splitting reaction under UV light. Moreover, the NCNDs can efficiently catalyze the hydrogen evolution reaction. Under visible‐light irradiation, Eosin Y‐sensitized NCNDs exhibit excellent activity for hydrogen evolution. The hydrogen evolution rate of NCNDs (without any modification and co‐catalyst) reaches 107.1 μmol h−1 (2142 μmol g−1 h−1). When Pt is loaded on the NCNDs, the hydrogen evolution rate reaches 491.2 μmol h−1 (9824 μmol g−1 h−1) under visible‐light irradiation. In addition, the NCNDs show excellent fluorescent properties and can be applied as a fluorescent probe for the sensitive and selective detection of Fe3+.
Effect of Thermal Treatment on the Textural Properties of CeO2 Powders Synthesized in Near‐ and Supercritical Alcohols
Authors: Slostowski Cédric , Marre Samuel , Babot Odile , Toupance Thierry , Aymonier Cyril 
Published: September 2015

AbstractCeO2 nanocrystals (NCs) have attracted increasing interest over the past few years, in particular for their use in catalytic reactions. Syntheses mediated by near‐ and supercritical alcohols have proven to be innovative ways to obtain CeO2 NCs with controlled crystallite sizes (from 3 to 8 nm depending on the alcohol) and surface functionalities, with alcohol moieties. When submitted to a thermal treatment at 500 °C, required to desorb/degrade surface organic species, these powders displayed different behaviors depending on the alcohol used during the synthesis. Cerium oxide powders synthesized in sc‐MeOH, sc‐EtOH and sc‐iPrOH undergo sintering during treatment at 500 °C, with a decrease of their specific surface area. Conversely, those synthesized in sc‐BuOH, nc‐PentOH and nc‐HexOH keep their initial crystallite sizes and morphology, but show a great enhancement of their specific surface area (up to 200 m2 g−1), which is unprecedented after such a thermal treatment.