bluuebunny/crossref_metadata_2025_split huggingface dataset:
The Mesh Property of the Steel Involute Cylindrical Worm with a Plastic Involute Helical Gear
Authors: Liu Z. Y. , Huang C. C. , Hao Y. H. , Lin C. C. 
Published: November 2013

ABSTRACTWith the increasing use of plastic gears in substitution of conventional steel ones, a plastic involute helical gear has been introduced to engage with a steel involute worm thus forming a novel plastic-steel worm-gear pair. The geometry and kinematics of this kind of worm-gear pair has been established first to derive its meshing properties which have been further verified by the finite element simulation. And it turns out that the contact area of this worm-gear pair is a point or an ellipse instead of a line. Further, a discrete dynamic model has been applied to investigate the dynamic transmission of motion and power of this worm-gear pair through the dynamic mesh force and the driven plastic involute helical gear. And the effects of angular and distance assembling errors have also been included.
Psychiatric side effects of ketamine in hospitalized medical patients administered subanesthetic doses for pain control
Authors: Rasmussen Keith G. 
Published: November 2013

ObjectiveTo assess the psychiatric side effects of ketamine when administered in subanesthetic doses to hospitalized patients. It is hypothesized that such effects occur frequently.MethodsIn this retrospective study, the medical records of 50 patients hospitalized on medical and surgical units at our facility who had continuous intravenous infusions of ketamine for pain or mild sedation were reviewed. Patient progress in the days following the start of ketamine infusion was reviewed and response to ketamine was noted.ResultsTwenty-two percent of the patients were noted to have some type of psychiatric reaction to ketamine, including agitation, confusion, and hallucinations. These reactions were relatively short lived, namely, occurring during or shortly after the infusions. No association was found between patient response to ketamine and gender, age, or infusion rate.ConclusionAwareness of the psychiatric side effects of ketamine is an important consideration for clinicians administering this medication either for pain control or for depressive illness.
Rice and noodle consumption is associated with insulin resistance and hyperglycaemia in an Asian population
Authors: Zuñiga Yasmin L. M. , Rebello Salome A. , Oi Puay Leng , Zheng Huili , Lee Jeannette , Tai E. Shyong , Van Dam Rob M. 
Published: November 2013

High consumption of refined grains, particularly white rice, has been reported to be associated with a higher risk of type 2 diabetes. Therefore, in the present study, we evaluated the association between rice and noodle consumption and markers of glucose homeostasis, inflammation and dyslipidaemia in an Asian population. We carried out a population-based cross-sectional study in 2728 Singaporean Chinese men and women aged between 24 and 92 years. Rice and noodle intake was assessed using a validated FFQ and studied in relation to glycaemic (fasting glucose, glycated Hb, homeostasis model assessment (HOMA) index for insulin resistance (HOMA-IR) and HOMA index for β-cell function (HOMA-β)), inflammatory (plasma adiponectin and C-reactive protein (CRP)) and lipid (fasting TAG and HDL-cholesterol (HDL-C)) markers. We used multiple linear regression analyses with adjustment for total energy intake and sociodemographic, anthropometric (BMI and waist:hip ratio) and lifestyle factors. Higher rice consumption was found to be associated with higher fasting glucose concentrations (0·81 % higher values per portion increment; 95 % CI 0·09, 1·54) and HOMA-IR (4·62 %; 95 % CI 1·29, 8·07). Higher noodle consumption was also found to be significantly associated with higher fasting glucose concentrations (1·67 %; 95 % CI 0·44, 2·92), HOMA-IR (6·17 %; 95 % CI 0·49, 12·16) and fasting TAG concentrations (9·17 %; 95 % CI 3·44, 15·22). No significant association was observed between rice and noodle consumption and adiponectin, CRP and HDL-C concentrations or HOMA-β in the fully adjusted model. These results suggest that high consumption of rice and noodles may contribute to hyperglycaemia through greater insulin resistance and that this relationship is independent of adiposity and systemic inflammation.
Validation of bovine glycomacropeptide as an intestinal anti-inflammatory nutraceutical in the lymphocyte-transfer model of colitis
Authors: Ortega-González Mercedes , Capitán-Cañadas Fermín , Requena Pilar , Ocón Borja , Romero-Calvo Isabel , Aranda Carlos , Suárez María Dolores , Zarzuelo Antonio , Sánchez de Medina Fermín , Martínez-Augustin Olga 
Published: November 2013

Milk κ-casein-derived bovine glycomacropeptide (GMP) exerts immunomodulatory effects. It exhibits intestinal anti-inflammatory activity in chemically induced models of colitis. However, to validate its clinical usefulness as a nutraceutical, it is important to assess its effects in a model with a closer pathophysiological connection with human inflammatory bowel disease. Therefore, in the present study, we used the lymphocyte-transfer model of colitis in mice and compared the effects of GMP in this model with those obtained in the dextran sulphate sodium (DSS) model. GMP (15 mg/d) resulted in higher body-weight gain and a reduction of the colonic damage score and myeloperoxidase (MPO) activity inRag1− / −mice with colitis induced by the transfer of naïve T cells. The colonic and ileal weight:length ratio was decreased by approximately 25 %, albeit non-significantly. GMP treatment reduced the percentage of CD4+interferon (IFN)-γ+cells in mesenteric lymph nodes (MLN). The basal production of IL-6 by MLN obtained from the GMP-treated miceex vivowas augmented. However, concanavalin A-evoked production was similar. The colonic expression of regenerating islet-derived protein 3γ, S100A8, chemokine (C-X-C motif) ligand 1 and IL-1β was unaffected by GMP, while that of TNF-α and especially IFN-γ was paradoxically increased. In the DSS model, GMP also reduced the activity of colonic MPO, but it failed to alter weight gain or intestinal weight:length ratio. GMP augmented the production of IL-10 by MLN cells and was neutral towards other cytokines, except exhibiting a trend towards increasing the production of IL-6. The lower effect was attributed to the lack of the effect of GMP on epithelial cells. In conclusion, GMP exerts intestinal anti-inflammatory effects in lymphocyte-driven colitis.
CONNECTION AND COHERENCE BETWEEN AND AMONG EUROPEAN INSTRUMENTS IN THE PRIVATE INTERNATIONAL LAW OF OBLIGATIONS
Authors: Crawford Elizabeth B , Carruthers Janeen M 
Published: November 2013

AbstractThis article considers points of connection and coherence between and among the Rome I Regulation, the Rome II Regulation, and Regulation 1215, and relevant predecessor instruments. The degree of consistency in aim, design and detail of conflict of laws rules is examined, vertically (between/among consecutive instruments) and horizontally (across cognate instruments). Symbiosis between instruments is explored, as is the interrelationship between choice of court and choice of law. Disadvantaged parties, and the cohesiveness of their treatment under the Regulations, receive particular attention.
Metacercarial polymorphism and genetic variation of Paragonimus heterotremus (Digenea: Paragonimidae), and a re-appraisal of the taxonomic status of Paragonimus pseudoheterotremus
Authors: Doanh P.N. , Thaenkham U. , An P.T. , Hien H.V. , Horii Y. , Nawa Y. 
Published: November 2013

AbstractParagonimus heterotremus, which is an important pathogen for human paragonimiasis in Asia, is recognized as having the smallest metacercariae (maximum diameter < 300 μm) of any previously reported Paragonimus species. Recently, P. pseudoheterotremus has been described from Thailand as a new species having metacercariae (about 200 μm) slightly smaller than those of Thai P. heterotremus. In fact, the small size of P. pseudoheterotremus metacercariae is compatible with those of P. heterotremus from India and China. In this study in Vietnam, we found variably sized small metacercariae which are expected to consist of both P. heterotremus and P. pseudoheterotremus. Contrary to expectation, the adult flukes obtained by separate infection of experimental cats with different sized metacercariae were all identified as P. heterotremus, using both morphological and molecular characteristics. The molecular analyses of an extensive collection of P. heterotremus/P. pseudoheterotremus isolates from Asian countries also indicated that genetic distances between different populations of P. heterotremus are even larger than that between P. pseudoheterotremus and P. heterotremus. The haplotype network showed that all P. heterotremus and P. pseudoheterotremus isolates formed a P. heterotremus complex consisting of three groups with strong geographical origins. In addition, the Indian P. heterotremus group is the root of the other P. heterotremus and P. pseudoheterotremus populations. Based on the observed metacercarial polymorphisms and genetic variation in P. heterotremus,P. pseudoheterotremus should be considered a geographically isolated population of the P. heterotremus complex.
Learning a generative syntax from transparent syntactic atoms in the linguistic input
Authors: NINIO ANAT 
Published: November 2013

ABSTRACTWe examined parents' two-word utterances expressing core syntactic relations in order to test the hypothesis that they may enable children to derive the atoms of hierarchical syntax, namely, the asymmetrical Merge/Dependency relation between pairs of words, and, in addition, to identify variables serving generative syntactic rules. Using a large English-language parental corpus, we located all two-word utterances containing a verb and its subject, object, or indirect object. Analysis showed that parental two-word sentences contain transparent information on the binary dependency/merge relation responsible for syntactic connectivity. The syntactic atoms modelled in the two-word input contain natural variables for dependents, making generalization to other contexts an immediate possibility. In a second study, a large sample of children were found to use the same verbs in the great majority of their early sentences expressing the same core grammatical relations. The results support a learning model according to which children learn the basics of syntax from parental two-word sentences.
Crystal structure of a new HfO(OH)2 oxyhydroxide
Authors: Tarakina N.V. , Tyutyunnik A.P. , Baklanova Ya.V. , Maksimova L.G. , Denisova T.A. , Neder R.B. 
Published: November 2013

The crystal structure of a new hafnium oxyhydroxide obtained by an ion-exchange reaction from a Li2HfO3 precursor has been solved by a direct method and refined using Rietveld full profile fitting based on X-ray powder diffraction data. HfO(ОН)2 crystallizes in a P21/c monoclinic unit cell (a = 5.5578(5) Å, b = 9.0701(10) Å, c = 5.7174(5) Å, β = 119.746(5)°); its structure can be described as a framework formed by edge-sharing HfO6 octahedra connected to each other via vertices. In addition, an analysis of the atomic pair distribution function obtained using synchrotron radiation was used to confirm the model and to describe fine-structure features.
Structure Re-determination of LASSBio-294 – a cardioactive compound of the N-acylhydrazone class – using X-ray powder diffraction data
Authors: Costa Fanny N. , Ferreira Fabio Furlan , da Silva Tiago F. , Barreiro Eliezer J. , Lima Lídia M. , Braz Delson , Barroso Regina C. 
Published: November 2013

Many N-acylhydrazone derivatives synthetized in LASSBio® cannot be prepared as single crystals of sufficient size and/or quality for structure determination to be carried out using single crystal X-ray diffraction techniques. This article highlights the opportunity for determining crystal structures of this class of compounds directly from powder diffraction data. For this task, the crystal structure of LASSBio-294 was re-determined by means of conventional X-ray powder diffraction data and so, compared with the crystal structure already determined for single crystal data. LASSBio-294 is a cardioactive compound of the N-acylhydrazone class, which can become part of the therapeutic interventions designed to decrease exertional fatigue, and, consequently, improve the quality of life of patients suffering from chronic heart failure. Its final crystal structure was refined by means of the Rietveld method (Rietveld, 1967; 1969). This drug crystallizes in a monoclinic (P21/c) space group, with unit cell parameters a = 11.3413(3) Å, b = 12.3573(4) Å, c = 9.0158(3) Å, β = 89.821(2)°, V = 1263.55(7) Å3, Z = 4, Ź = 1 and ρcalc = 1.4419(1) g cm−3. The goodness-of-fit indicator and R-factors were, respectively: χ2 = 1.203, RBragg = 0.696%, Rwp = 5.59%, Rexp = 4.65% and Rp = 4.18%. The molecules in LASSBio-294 are H-bonded along the c-axis involving the atoms N(3)–H(8)···O(4).
Monitoring protein precipitates by in-house X-ray powder diffraction
Authors: Ståhl Kenny , Frankær Christian G. , Petersen Jakob , Harris Pernille 
Published: November 2013

Powder diffraction from protein powders using in-house diffractometers is an effective tool for identification and monitoring of protein crystal forms and artifacts. As an alternative to conventional powder diffractometers a single crystal diffractometer equipped with an X-ray micro-source can be used to collect powder patterns from 1 µl samples. Using a small-angle X-ray scattering (SAXS) camera it is possible to collect data within minutes. A streamlined program has been developed for the calculation of powder patterns from pdb-coordinates, and includes correction for bulk-solvent. A number of such calculated powder patterns from insulin and lysozyme have been included in the powder diffraction database and successfully used for search-match identification. However, the fit could be much improved if peak asymmetry and multiple bulk-solvent corrections were included. When including a large number of protein data sets in the database some problems can be foreseen due to the large number of overlapping peaks in the low-angle region, and small differences in unit cell parameters between pdb-data and powder data. It is suggested that protein entries are supplied with more searchable keywords as protein name, protein type, molecular weight, source organism etc. in order to limit possible hits.
Rietveld structural refinement of «A» type phosphostrontium carbonate hydroxyapatites
Authors: Jebri Sonia , Boughzala Habib , Bechrifa Ali , Jemal Mohamed 
Published: November 2013

Phosphostrontium carbonate hydroxyapatites having the general formula Sr10(PO4)6(OH)(2-2x)(CO3)x were prepared by solid gas reaction at different temperatures in the range 0 ≤ x ≤ 1. Infrared spectroscopy investigation reveals a carbonate groups substituting hydroxyl ions. Intensity bands increasing with the carbonate amount introduced in the lattice, while the one corresponding to hydroxyl decreases until disappearance. The Rietveld refinement of the structural model using X-ray powder diffraction patterns is used to determine the substitution rate. It was quantified by the refinement of the occupancy sites affected by the substitution. The crystallographic study shows the evolution of the atomic coordinate in the apatite due to the carbonate incorporation. The variation of the main interatomic distances and the bond angles was also discussed.
Structural and spectroscopic study of NaSbR(PO4)3 (R = Cr, Fe, In) phases
Authors: Aatiq Abderrahim , Tigha My Rachid 
Published: November 2013

Crystallographic structures of the three NaSbR(PO4)3 (R = Cr, Fe, In) phases were determined at room temperature from X-ray powder diffraction (XRD) data using the Rietveld analysis. The three compounds belong to the Nasicon structural family. The presence of the (303) reflection in all XRD spectra of NaSbR(PO4)3 shows clearly that all compounds crystallise in rhombohedral system with R3 space group. Na atoms are practically ordered within the two positions, 3a and 3b, of M1 sites. Structure refinements show also a partially-ordered distribution of Sb5+ and R3+ ions within the Nasicon framework. A Raman and Infrared spectroscopic study was used to obtain further structural information about the nature of bonding in NaSbR(PO4)3 (R = Cr, Fe, In) phases.
Nullifying the extinction effect in XRD characterization of fibre textures
Authors: Tomov I. , Vassilev S. 
Published: November 2013

To gain accuracy and, hence, physical reality of the data acquired by XRD measurements of fibre textures, a technique is elaborated to achieve experimental values, which are free of extinction effects. Its elaboration is based on combining basic definitions of the extinction theory and texture analysis. This technique is applicable to characterization of metal coatings that appear infinitely thick for X-rays. A nickel sample representing <100> + <221> texture components is used as a model. Resultant derived series of data on pole-density distribution of the {200} diffraction pole figure shows that the data corresponding to the main <100> texture component are strongly affected by extinction. On the contrary, due to definitions that require reduction of the intensity distribution to multiples of random density, the extinction-free values of the volume fraction of texture components do not differ substantially from those calculated by standard methods. Evidently, any of the standard methods for volume fraction measurements provides reasonable data if secondary extinction is even disregarded.
Metal hydride formation in palladium and palladium rich intermetallic compounds studied by in situ neutron diffraction
Authors: Kohlmann H. , Kurtzemann N. , Hansen T. C. 
Published: November 2013

In order to investigate the hydrogenation of intermetallic compounds, a gas pressure cell for in situ neutron powder diffraction based on a sapphire crystal tube was constructed. By proper orientation of the single crystal Bragg peaks of the container material can be avoided, resulting in a very low diffraction background. Using a laser heating and gas pressure controller, the hydrogenation (deuteration) of palladium and palladium rich intermetallics was studied in real time up to 8 MPa gas pressure and 700 K. Crystal structure parameters of palladium deuterides could be obtained under various deuterium gas pressures, corresponding to compositional ranges of 0.04≤x≤0.11 for the α-phase and 0.52≤x≤0.72 for the β-phase at 446 K. In situ neutron powder diffraction of the deuteration of a thallium lead palladium intermetallic Tl1-xPbxPd3 shows two superstructures of the cubic closest packing (ccp) to transform independently into a AuCu3 type structure. This proves a direct reaction to the deuterium filled AuCu3 type structure instead of a reaction cascade involving different ccp superstructures and thus gives new insights into the reaction pathways of palladium rich intermetallic compounds.
Growth kinetics of Cu2ZnSnS4 thin films and powders
Authors: Müller M. , Azanza Ricardo C. L. , Di Maggio R. , Scardi P. 
Published: November 2013

The growth kinetics of Cu2ZnSnS4 thin films and powders was studied using in-situ synchrotron data. Isothermal and isochronal measurements were performed at the MCX beamline of the Elettra synchrotron (Trieste, Italy). Diffraction line profile analysis was used to follow the changes in the domain size distribution during isothermal measurements, and the change in the mean volume of the domains was studied using the Johnson-Mehl-Avrami equation. The growth was found to be diffusion controlled from small dimensions while the nucleation rate is temperature dependent. An activation energy of 210 kJ/mol could be estimated. In case of the isochronal data, the evolution of inverse of the integral breadth of the diffraction peaks in dependence on temperature was studied using the Ozawa and Šatava equations. The activation energy determined for the growth process is between 112(2) and 145(5) kJ/mol.
X-ray powder diffraction and magnetic study of nominal Zn1-xNdxCr2Se4 – compounds (x = 0.05, 01)
Authors: Jendrzejewska Izabela , Zajdel Paweł , Maciążek Ewa , Sozańska Maria , Goryczka Tomasz 
Published: November 2013

Polycrystalline compounds in the Zn1-xNdxCr2Se4 system were prepared by solid state reaction using selenides (ZnSe, Cr2Se3) and pure elements (Nd, Se) as starting materials. The structural properties were determined by X-ray diffraction and the chemical composition confirmed by SEM-EDX. The observed symmetry is cubic, space group Fd3m, while the lattice parameter varies from 10.4955(7)Å to 10.4976(7)Å, and is larger than for the pure matrix. The solubility limit for the current synthesis route lies below x = 0.1. The magnetic moments, effective and saturation, increase with increasing amount of Nd ions. The Neel temperature TN and ΘCW drop, respectively, to 17.4K and 81K for x = 0.1, independently indicating that neodymium is incorporated into the spinel lattice and promotes antiferromagnetic coupling between the Cr3+ ions.
Incidence and prevalence ofToxoplasma gondiiinfection in women in France, 1980–2020: model-based estimation
Authors: NOGAREDA F. , LE STRAT Y. , VILLENA I. , DE VALK H. , GOULET V. 
Published: November 2013

SUMMARYToxoplasmosis is a worldwide zoonosis due toToxoplasma gondii, a ubiquitous protozoan parasite of warm-blooded animals including humans. In pregnant women, primary infection can cause congenital toxoplasmosis resulting in severe malformations in the newborn. Since 1978, public health authorities in France have implemented a congenital toxoplasmosis prevention programme, including monthly serological screening of all seronegative pregnant women, and treatment in case of seroconversion. However, this programme does not produce systematic surveillance data on incidence and prevalence. Our objective was to estimate the incidence and prevalence ofT. gondiiinfection, and the incidence of seroconversion during pregnancy in women in France. We used a catalytic model to estimate incidence and prevalence ofToxoplasmainfection between 1980 and 2020 in women of childbearing age. We used age- and time-specific seroprevalence data obtained from the National Perinatal Surveys (NPS) conducted in 1995, 2003 and 2010. We assumed that incidence depends both on age and calendar time, and can be expressed as the product of two unknown functions. We also estimated incidence of seroconversion during pregnancy in 2010 from the NPS and the National Surveillance of Congenital Toxoplasmosis (ToxoSurv). We combined data of 42208 women aged 15–45 years with serology available from the three NPS. For women aged 30 years the modelled incidence decreased from 7·5/1000 susceptible women in 1980 to 3·5/1000 in 2000. In 2010 the incidence was 2·4/1000. The predicted incidence and prevalence for 2020 was 1·6/1000 and 27%, respectively. The incidence of seroconversion during pregnancy in 2010 was estimated at 2·1/1000 susceptible pregnant women (95% CI 1·3–3·1) from the NPS and 1·9 (95% CI 1·8–2·1) from ToxoSurv. Incidence and prevalence ofToxoplasmainfection has decreased markedly during the last 30 years. This decrease may be explained by a lower exposure to the parasite by changes in food habits and by improved hygiene practices in meat production. Modelled estimations were consistent with estimates observed in other studies conducted previously in France. The catalytic modelling provides reliable estimates of incidence and prevalence ofToxoplasmainfection over time. This approach might be useful for evaluating preventive programme for toxoplasmosis.