In-Line Measurement of H2S Content in Flow with a Multiphase Flow Meter - Case Study in a Giant Field under Sour Gas Re-Injection
Authors: Lindsell K. , Wang S. W. , Clarke J. , Jambayev A. , Ricquebourg J. , Kaipov Y. , Zakharov L. , Hollaender F. 
Published: November 2015

Abstract
A new approach in advanced multiphase metering methodology designed for use in sour fields, quantifying H2S content in flow and properly accounting for it in the different phase rate measurements is presented. Flow metering in sour fields is challenging due to the need for containment of produced fluids and the effect of fluid properties in the interpretation of the measurements. The addition of H2S measurement provides additional information for production and reservoir monitoring and also yields improvements in flow metering, accounting for variations in fluid properties used for multi-phase calculation.
Multiphase Flow Meters (MPFM) utilizing multi-energy gamma-ray fraction measurements are based on the ability of oil, gas, and water to absorb gamma rays of two different wavelengths. Adding an extra measurement at a third level of energy and leveraging the large contrast between the attenuation of sulfur and that of hydrocarbon and water components makes it possible to determine the mass fraction of H2S as an additional output.
This technique was applied in Tengiz field, Kazakhstan, characterized by a high H2S content. In order to maintain reservoir pressure, improve recovery and utilize produced associated gas, a sour gas miscible flood pilot was started in 2007. The monitoring of compositional variation in producers is critical in the understanding of solvent (sour gas) distribution and thus in managing production-injection patterns to optimize plant throughput.
Early field trials of the method were made comparing metered H2S content with surface PVT samples, confirming the accuracy of the methodology. The technology was then implemented systematically but strategically across the field. The in-line H2S measurement with automatic updates for variation in fluid properties was applied in two distinct areas: within the sour gas injection pilot area, where solvent levels vary, and outside the area where hydrocarbon composition is known to be homogeneous and constant. Long and short term tests with multi-rate well tests were conducted. Full datasets were collected from the MPFM to evaluate measurement stability and representativity under different flowing conditions and compared to results obtained without accounting for compositional changes.
The results show a stable, accurate and continuous measurement of H2S content in produced fluid and an enhanced measurements of water, oil and gas rates comparable with PVT results. The in-line H2S measurement based on multi-energy gamma ray measurements is the only continuous H2S measurement technology available in multiphase flow conditions. It can be retrofitted to existing MPFMs, allowing to get additional parameter and enhanced stability of flow rate measurements where properties of produced fluid vary continuously.
This paper will begin with a presentation of the theory, formulation and validation of the in-line H2S measurement and then go on to present a case history of the application in the Tengiz field, Kazakhstan for Tengizchevroil (TCO).