bluuebunny/crossref_metadata_2025_split huggingface dataset:
Organic Cations Texture Zinc Metal Anodes for Deep Cycling Aqueous Zinc Batteries
Authors: Ma Guoqiang , Yuan Wentao , Li Xiaotong , Bi Tongqiang , Niu Linhuan , Wang Yue , Liu Mengyu , Wang Yuanyuan , Shen Zhaoxi , Zhang Ning 
Published: July 2024

AbstractManipulating the crystallographic orientation of zinc (Zn) metal to expose more (002) planes is promising to stabilize Zn anodes in aqueous electrolytes. However, there remain challenges involving the non‐epitaxial electrodeposition of highly (002) textured Zn metal and the maintenance of (002) texture under deep cycling conditions. Herein, a novel organic imidazolium cations‐assisted non‐epitaxial electrodeposition strategy to texture electrodeposited Zn metals is developed. Taking the 1‐butyl‐3‐methylimidazolium cation (Bmim+) as a paradigm additive, the as‐prepared Zn film ((002)‐Zn) manifests a compact structure and a highly (002) texture without containing (100) signal. Mechanistic studies reveal that Bmim+ featuring oriented adsorption on the Zn‐(002) plane can reduce the growth rate of (002) plane to render the final exposure of (002) texture, and homogenize Zn nucleation and suppress H2 evolution to enable the compact electrodeposition. In addition, the formulated Bmim+‐containing ZnSO4 electrolyte effectively sustains the (002) texture even under deep cycling conditions. Consequently, the combination of (002) texture and Bmim+‐containing electrolyte endows the (002)‐Zn electrode with superior cycling stability over 350 h under 20 mAh cm−2 with 72.6% depth‐of‐discharge, and assures the stable operation of full Zn batteries with both coin‐type and pouch‐type configurations, significantly outperforming the (002)‐Zn and commercial Zn‐based batteries in Bmim+‐free electrolytes.
A Cantaloupe‐Rind‐Inspired Nanostructured Textile Catalyst for Enhanced and Recoverable Performance in High‐Temperature Electrochemical Cells
Authors: Hidaka Shigekazu , Maegawa Yoshifumi , Goto Yasutomo , Okamoto Takumi , Higashi Shougo , Hikita Yasuyuki 
Published: July 2024

AbstractElectrodes with a maximal active site density are critical for high‐performance high‐temperature electrochemical cells (HTECs). One widely employed approach involves the use of porous nanostructures with a high surface‐to‐volume ratio. However, their active site densities inevitably decrease owing to particle aggregation induced at high temperatures, necessitating further development of electrode processing techniques. Taking Pt/yttria‐stabilized zirconia (YSZ) interface as a model system, a Pt nanostructured textile akin to the cantaloupe‐rind pattern with high mechanical integrity is fabricated. Application of an AC voltage to this textile electrode at an elevated temperature reduces the Pt particle size from submicron to 10–80 nm forming a nanocomposite with YSZ, accompanied by a 40‐fold increase in current density under high‐temperature water electrolysis conditions. Furthermore, the AC voltage application to a partially aggregated electrode restores its nano‐blended structure associated with the recovery of its activity. This technique is effective in counteracting particle aggregation on demand, providing an alternative approach to achieve high performance and extended lifetimes in HTECs.
Perovskite Nanocrystal Light‐Emitting Diodes with Ultralow Drive Voltage Realized by Auger‐Assisted Energy Up‐Conversion
Authors: Ohisa Satoru , Motomura Genichi , Mizoguchi Syoki , Fujisaki Yoshihide , Chiba Takayuki 
Published: July 2024

AbstractReducing the driving voltage is a long‐term and important challenge in the development of light‐emitting diodes (LEDs) because the light‐emission threshold voltage cannot be below the theoretical limit of the emitter's bandgap divided by the elementary charge. Here, green perovskite nanocrystal (PeNC) LEDs are inverted that emit light at ultralow voltages (below the theoretical limit) realized by efficient Auger‐assisted energy up‐conversion at the interface of the zinc oxide nanoparticles (ZnO NPs) electron injection layer and PeNC light‐emission layers. The up‐conversion utilizes the recombination energy of the charge‐transfer excitons. After modifying the interface by plasma treatment of the ZnO NPs and by inserting an organic interlayer between the ZnO NPs and PeNCs, the device performance is dramatically improved from that of the unmodified PeNC LED. The threshold voltage at which the emission spectrum can be observed is 1.55 V, substantially lower than 2.34 V (the PeNC emitter's bandgap divided by the elementary charge). Moreover, after mixing an organic aromatic semiconductor compound in the PeNC light‐emission layer, the carrier balance is regulated and the threshold voltage is further reduced to 1.30 V.
Advancing Sustainable Building Materials: Reducing Formaldehyde Emissions in Medium Density Fiber Boards with Lignin Nanoparticles
Authors: Dorieh Ali , Pahlavan Farideh , Hájková Kateřina , Hýsek Štěpán , Farajollah Pour Mohammad , H. Fini Elham 
Published: July 2024

AbstractThe pressing need to develop eco‐friendly polymer materials for building applications has led to increased interest in modifying existing polymer systems. In this study, a sustainable approach to augmenting urea‐formaldehyde (UF) resins, widely employed in wood‐based panels is introduced. Addressing this, formaldehyde‐scavenger demethylated lignin nanoparticles into UF resins, aiming to produce a green and enhanced medium‐density‐fiberboard (MDF) with minimal formaldehyde emissions is incorporated. The results indicate that increasing concentrations of demethylated lignin nanoparticles in the UF adhesive, there is not only a reduction in formaldehyde emissions from MDF composites but also a significant decrease in thickness swelling. The highest reduction in formaldehyde emission is observed in the MDF composite prepared with UF resin containing 7% lignin nanoparticles (UF‐7NL), with an emission of 2.9 mg/100 g, marking a substantial decrease of 74% compared to emission of 11.2 mg/100 g from neat resin. Importantly, this reduction does not compromise physical and mechanical properties of the MDF; they remain comparable to boards bonded with unmodified UF. Molecular modeling revealed that lignin effectively traps formaldehyde, incorporating it as ‐CH2OH groups, leading to a notable decrease in formaldehyde emission from MDF. This approach offers an eco‐friendly modification to a common polymer, showcasing lignin nanoparticles as innovative additives.
Inhalational Delivery of β‐glucan‐chitosan‐poly(lactic co‐glycolic) acid Nanoparticles Enhance Alveolar Macrophage Rifampin Concentrations for the Treatment of Tuberculosis
Authors: Kutscher Hilliard L. , Tamblin Maria , Karki Shanta , Chaves Lee , Baird Marissa , Parvin Afrin , Smith Evon , Dube Admire , Zhang Zhaoqi , Chakraborty Saptarshi , Kenney Patrick , Reynolds Jessica L. 
Published: July 2024

AbstractDespite multiple treatments for tuberculosis (TB), there are ≈10 million new cases and 1.5 million deaths annually, warranting the need for new therapeutics. Major clinical treatment issues include the length of treatment which is associated with patient non‐compliance; and poor cellular drug penetration leading to the generation of drug‐resistant strains. This study underscores the potential of β‐glucan‐chitosan (CS) poly(lactic co‐glycolic) acid (PLGA) nanoparticles as a promising immunostimulatory adjunct for TB treatment. To facilitate drug delivery to alveolar macrophage, a CS‐PLGA nanoparticle is developed containing rifampin in the core with β‐glucan as a surface ligand, to stimulate the immune system. Mice are administered a single dose of nanoparticles or free rifampin by oropharyngeal aspiration. Pharmacokinetic investigations reveal sustained release properties of rifampin in vivo, extending over a week. Furthermore, comprehensive analysis indicates stimulation of the innate immune system, as evidenced by cytokine profiling, while concurrently revealing no detrimental effects on the alveolar epithelium, as indicated by histological examination and albumin lung leak assessment. These findings collectively establish a strong foundation for the development of a novel adjuvant immunotherapy approach for TB.
Dielectric Barrier Plasma Discharge Exsolution of Nanoparticles at Room Temperature and Atmospheric Pressure
Authors: ul Haq Atta , Fanelli Fiorenza , Bekris Leonidas , Martin Alex Martinez , Lee Steve , Khalid Hessan , Savaniu Cristian D. , Kousi Kalliopi , Metcalfe Ian S. , Irvine John T. S. , Maguire Paul , Papaioannou Evangelos I. , Mariotti Davide 
Published: July 2024

AbstractExsolution of metal nanoparticles (NPs) on perovskite oxides has been demonstrated as a reliable strategy for producing catalyst‐support systems. Conventional exsolution requires high temperatures for long periods of time, limiting the selection of support materials. Plasma direct exsolution is reported at room temperature and atmospheric pressure of Ni NPs from a model A‐site deficient perovskite oxide (La0.43Ca0.37Ni0.06Ti0.94O2.955). Plasma exsolution is carried out within minutes (up to 15 min) using a dielectric barrier discharge configuration both with He‐only gas as well as with He/H2 gas mixtures, yielding small NPs (<30 nm diameter). To prove the practical utility of exsolved NPs, various experiments aimed at assessing their catalytic performance for methanation from synthesis gas, CO, and CH4 oxidation are carried out. Low‐temperature and atmospheric pressure plasma exsolution are successfully demonstrated and suggest that this approach could contribute to the practical deployment of exsolution‐based stable catalyst systems.
Gas Molecule Assisted All‐Inorganic Dual‐Interface Passivation Strategy for High‐Performance Perovskite Solar Cells
Authors: Zeng Fancong , Xu Lin , Xing Jiahe , Wu Yanjie , Zhang Yuhong , Zhang Huan , Hu Chencheng , Dong Biao , Bai Xue , Song Hongwei 
Published: July 2024

AbstractThe trap states at both the upper and bottom interfaces of perovskite layers significantly impact non‐radiative carrier recombination. The widely used solvent‐based passivation methods result in the disordered distribution of surface components, posing challenges for the commercial application of large‐area perovskite solar cells (PSCs). To address this issue, a novel NH3 gas‐assisted all‐inorganic dual‐interfaces passivation strategy is proposed. Through the gas treatment of the perovskite surface, NH3 molecules significantly enhanced the iodine vacancy formation energy (1.54 eV) and bonded with uncoordinated Pb2+ to achieve non‐destructive passivation. Meanwhile, the reduction of the film defect states is accompanied by a decrease in the work function, which promotes carrier transport between the interface. Further, a stable passivation layer is constructed to manage the bottom interfacial defects using inorganic potassium tripolyphosphate (PT), whose ─P═O group effectively mitigated the charged defects and lowered the carrier transport barriers and nucleation barriers of PVK, while the gradient distribution of K+ improved the crystalline quality of PVK film. Based on the dual‐interface synergistic effect, the optimal MA‐contained PSCs with an effective area of 0.1 cm2 achieved an efficiency of 24.51% and can maintain 90% of the initial value after aging (10−20% RH and 20 °C) for 2000 h.
Topological‐Insulator Nanocomposite and Graphite‐Like Tribo‐Charge‐Accumulating Fabric Enabling High‐performance Non‐Contact Stretchable and Textile‐Based Triboelectric Nanogenerators with Robust Charge Retention
Authors: Chou Syun‐Hong , Chen Yi‐Ting , Yan Zhi‐Xian , Lu Tzu‐Ching , Wu Tai‐Chen , Lu Ming‐Han , Ko Tien‐Yu , Peng Wei‐Chen , Chen Jiann‐Yeu , Hsu Fang‐Chi , Chen San‐Yuan , Chen Chih‐Yen , Lai Ying‐Chih 
Published: July 2024

AbstractTriboelectric nanogenerators (TENGs) have revealed fascinating potential in multifaceted wearables. However, their reliance on physical contact and separation from human bodies presents drawbacks for efficient energy collection, especially over large areas. Herein, the first stretchable non‐contact TENG textile is proposed using a topological insulator nanocomposite coating (triboelectric layer) and a graphite‐like fabric (tribo‐charges reservoir). This design encompasses the capture, transporting, and storage of tribo‐charges, leading to enhanced device performance (452 V, 1.96 mA m−2, and 179 mW m−2) and prolonged tribo‐charges retention time (5000 min). During non‐contact operation, the output remained at 382 V (318 µA m−2), 123 V (59 µA m−2), and 94 V (23 µA m−2) for separation distances of 0.1, 0.5, and 1 cm, respectively. Additionally, it exhibits excellent stretchability (>100% strain). Notably, its performance during non‐contact operation and mechanical freedom surpasses those of previous reports, enabling both wearable non‐contact biomechanical energy harvesting and deformable self‐powered proximity sensing. Its applicability is comprehensively examined for non‐contact harvesting of body‐motion energy in garments and driving electronics. Finally, its application as a self‐powered touchless interface for system‐level applications is demonstrated. These results provide new directions for developing non‐contact biomechanical energy harvesting and sensing, enabling advancements in autonomous wearables and Metaverse applications.
Valorization of Waste Biomass to Biofuels for Power Production and Transportation in Optimized Way: A Comprehensive Review
Authors: Jamil Farrukh , Inayat Abrar , Hussain Murid , Akhter Parveen , Abideen Zainul , Ghenai Chaouki , Shanableh Abdallah , Abdellatief Tamer M. M. 
Published: July 2024

Fossil fuels are primary sources for energy production. Increased dependence on fossil fuels has resulted in increased environmental issues demanding alternative sources. Bioenergy is becoming a popular alternative energy source due to its positive environmental impact and the availability of renewable sources. However, the availability of renewable energy sources in the energy sector currently contributes to about 14%. Biofuels are preferred due to its sustainability, eco‐friendly approach, and low‐cost raw materials, making it an efficient technique for energy production. This article provides the fundamental and applied concepts for on conversion processes of biomass to biofuels, such as combustion, pyrolysis, fermentation, gasification, and anaerobic digestion along with their role in the green economy. Different physical characteristics of biomass resources are important and contribute to determining their potential for producing biofuels. Herein, LCA, its techno‐economic importance, and the role of biomass in green economy are explained. Varying compositions and properties of different types of biomass resources, including lignocellulosic feedstocks, agriculture and forest residue, municipal solid waste, food waste, and animal manure as potential biomass resources, have been discussed. The article explains the strengths and weaknesses of different thermochemical conversion techniques and their current input toward scalar applications and commercialization.
Optimizing spiral‐wound pervaporation membrane modules through simulation: Unraveling the permeate spacer structure
Authors: Lu Xiaotian , Huang Jiachen , Pinelo Manuel , Chen Guoqiang , Wan Yinhua , Luo Jianquan 
Published: July 2024

AbstractFor low‐pressure pervaporation, the performance of spiral wound pervaporation membrane (SWM‐PV) module is significantly influenced by permeate spacer structure. This study addresses mass transport challenges in SWM‐PV modules, focusing on increased gas flow resistance and vacuum attenuation due to membrane envelope deformation in the permeate side channel. Employing fluid and structural simulation models to evaluate phase change and membrane deformation, we successfully optimized SWM‐PV module configurations for improved ethanol recovery. Our strategies included a mass transfer‐enhanced feed spacer to mitigate concentration polarization, a high‐strength permeate spacer to alleviate membrane deformation, and tailored membrane envelopes to balance packing density and mass transfer efficiency. These synergistic optimizations led to a 22.1% improvement in ethanol mass transfer coefficient and a 78.5% reduction in module's specific energy consumption. Our work reveals the importance of permeate spacer structure in optimizing SWM‐PV modules, offering clear guidance for the development of mass transfer‐enhanced SWM‐PV modules.
Height and integration in proximity networks among Tanzanian Hadza men
Authors: Fedurek Piotr , Danel Dariusz , Aktipis Athena , Berbesque J. Colette , Cronk Lee , Makambi E. Jerryson , Lehmann Julia , Mabulla Ibrahim , Koziel Slawomir 
Published: July 2024

AbstractIn recent years there has been much interest in investigating the extent to which social status or prestige are related to an individual's degree of integration in social networks. It has been shown that, among hunter‐gatherers, social characteristics of an individual based on social status or prestige, such foraging reputation, friendship popularity, and pro‐social reputation, can influence the extent to which an individual is embedded in a social network. However, little is known regarding the extent to which height, a physical trait that in Western societies is often associated with social status, is associated in integration in social networks among small‐scale hunter gatherers. Here, we investigated the relationship between height and a position an individual occupies in proximity networks among Hadza men (n = 30), hunter‐gatherers living in Northern Tanzania. The results of our study show that height is not related to the position an individual maintains in proximity networks. We argue that, in a relatively egalitarian small‐scale hunter‐gatherer societies such as the Hadza, social interactions driving proximity networks might be influenced by social traits, such as popularity and hunting reputation, rather than physical traits, such as height.
Autistic traits in youth with familial adenomatous polyposis: A Dutch–Canadian case–control study
Authors: Danieli Polina Perlman , Hoang Ny , Selvanayagam Thanuja , Yang Alvin , Breetvelt Elemi , Tabbers Merit , Cohen Christine , Aelvoet Arthur S. , Trost Brett , Ward Thomas , Semotiuk Kara , Durno Carol , Aronson Melyssa , Cohen Zane , Dekker Evelien , Vorstman Jacob 
Published: July 2024

AbstractThis study investigated the neurodevelopmental impact of pathogenic adenomatous polyposis coli (APC) gene variants in patients with familial adenomatous polyposis (FAP), a cancer predisposition syndrome. We hypothesized that certain pathogenic APC variants result in behavioral–cognitive challenges. We compared 66 FAP patients (cases) and 34 unaffected siblings (controls) to explore associations between APC variants and behavioral and cognitive challenges. Our findings indicate that FAP patients exhibited higher Social Responsiveness Scale (SRS) scores, suggesting a greater prevalence of autistic traits when compared to unaffected siblings (mean 53.8 vs. 47.4, Wilcoxon p = 0.018). The distribution of SRS scores in cases suggested a bimodal pattern, potentially linked to the location of the APC variant, with scores increasing from the 5′ to 3′ end of the gene (Pearson's r = 0.33, p = 0.022). While we observed a trend toward lower educational attainment in cases, this difference was not statistically significant. This study is the first to explore the connection between APC variant location and neurodevelopmental traits in FAP, expanding our understanding of the genotype–phenotype correlation. Our results emphasize the importance of clinical assessment for autistic traits in FAP patients, shedding light on the potential role of APC gene variants in these behavioral and cognitive challenges.
Matrix metalloproteinase‐11 regulates inverted papilloma epithelial cell migration and invasion
Authors: Panara Kush , Hui Tan Li , Keshari Deepa , Tong Charles C. L. , Palmer James N. , Adappa Nithin D. , Douglas Jennifer E. , Cohen Noam A. , Kohanski Michael A. 
Published: July 2024

AbstractBackgroundInverted papilloma (IP) is a benign tumor characterized by epithelial proliferation, which has the potential for malignant transformation. However, the mechanisms driving this transformation are poorly defined. Matrix metalloproteinase‐11 (MMP‐11), a regulator of the tumor microenvironment that degrades extracellular matrix, is upregulated in IP with dysplasia. Here, we aim to investigate the role of MMP‐11 in IP epithelial migration and invasion.MethodsHuman IP and contralateral normal sinus mucosa (control) samples were obtained. IP‐derived epithelial cultures and normal mucosa‐derived epithelial cultures were grown in air‒liquid interface, followed by immunostaining to assess MMP‐11 expression in IP. Migration and invasion assays were used to evaluate the role of an anti‐MMP‐11 antibody on IP and control epithelial cultures.ResultsIP‐derived cultures demonstrated strong MMP‐11 expression compared to controls. Treatment with anti‐MMP‐11 blocking antibody significantly reduced epithelial migration only in IP‐derived cells compared to non‐treated IP cells, as seen by incomplete wound closure and reduced transepithelial resistance. In addition, inhibition of MMP‐11 reduced IP epithelia's ability to invade through collagen‐coated transwells, suggesting that MMP‐11 plays a role in invasion.ConclusionWe established an in vitro model to study IP‐derived epithelial cells. MMP‐11 is uniquely expressed in IP epithelial cultures compared to control epithelial cultures. Inhibition of MMP‐11 limits IP epithelial migration and invasion to levels similar to that of normal sinus mucosa. MMP‐11 does not appear to have a functional role in normal sinus epithelium, suggesting that MMP‐11 has a role in malignant transformation of IP.
Jellyfish‐Inspired Polyurea Ionogel with Mechanical Robustness, Self‐Healing, and Fluorescence Enabled by Hyperbranched Cluster Aggregates
Authors: Zhang Zhipeng , Qian Lu , Zhang Bin , Ma Chunfeng , Zhang Guangzhao 
Published: July 2024

AbstractIonogels are promising for soft iontronics, with their network structure playing a pivotal role in determining their performance and potential applications. However, simultaneously achieving mechanical toughness, low hysteresis, self‐healing, and fluorescence using existing network structures is challenging. Drawing inspiration from jellyfish, we propose a novel hierarchical crosslinking network structure design for in situ formation of hyperbranched cluster aggregates (HCA) to fabricate polyurea ionogels to overcome these challenges. Leveraging the disparate reactivity of isocyanate groups, we induce the in situ formation of HCA through competing reactions, enhancing toughness and imparting the clustering‐triggered emission of ionogel. This synergy between supramolecular interactions in the network and plasticizing effect in ionic liquid leads to reduced hysteresis of the ionogel. Furthermore, the incorporation of NCO‐terminated prepolymer with dynamic oxime–urethane bonds (NPU) enables self‐healing and enhances stretchability. Our investigations highlight the significant influence of HCA on ionogel performance, showcasing mechanical robustness including high strength (3.5 MPa), exceptional toughness (5.5 MJ m−3), resistance to puncture, and low hysteresis, self‐healing, as well as fluorescence, surpassing conventional dynamic crosslinking approaches. This network design strategy is versatile and can meet the various demands of flexible electronics applications.