bluuebunny/crossref_metadata_2025_split huggingface dataset:
JEu me questionne : un programme désiré par les CSSS du Québec ?
Authors: Ladouceur Robert , Fournier Patricia-Maude , Lafond Sophie , Goulet Annie , Simoneau Hélène , Sévigny Serge , Giroux Isabelle 
Published: October 2014

JEu me questionne est le premier programme québécois d’intervention semi-autonome conçu pour venir en aide aux joueurs désirant exercer un meilleur contrôle sur leurs habitudes de jeu. Ce programme pourrait être offert dans les centres de santé et de services sociaux (CSSS), l’une des portes d’entrée pour les demandes de services en jeu problématique. Plusieurs CSSS du Québec qui offrent des services de première ligne à une clientèle variée intègrent déjà à leur offre de service un programme d’autotraitement pour les problèmes de consommation d’alcool. Un programme tel JEu me questionne correspond-il à un besoin et à un intérêt pour les CSSS ? L’étude vise à documenter la situation actuelle des services offerts en CSSS en matière de jeu et à vérifier la perception des administrateurs et des intervenants des CSSS à l’égard d’une éventuelle offre de ce programme dans leur milieu. Quatre-vingt-deux intervenants et seize administrateurs recrutés dans neuf CSSS du Québec ont rempli un questionnaire élaboré pour les besoins de l’étude. Les résultats montrent que près de 70 % des CSSS n’offrent pas de services d’intervention précoce pour les problèmes de jeu, redirigeant plutôt les demandeurs vers des ressources spécialisées. La majorité des répondants (65 %) affiche un intérêt pour offrir ce programme dans leur établissement et perçoit qu’il répondrait à un besoin des usagers. Pour réaliser cette offre, les répondants soulèvent l’importance d’une formation adéquate, la présence de ressources en quantité suffisante, la concertation des milieux cliniques et la promotion du service. Le manque de temps et de ressources humaines et financières représente le principal obstacle. Des solutions à ces contraintes sont discutées, dont la gestion centralisée de ce programme pour un meilleur accès aux joueurs.
Observational Study Fails to Demonstrate the Effectiveness of OMT in Decreasing Low Back Pain
Authors: Licciardone John C. 
Published: October 2014

Abstract

The Journal of the American Osteopathic Association (JAOA) encourages osteopathic physicians, faculty members and students at colleges of osteopathic medicine, and others within the health care professions to submit comments related to articles published in the JAOA and the mission of the osteopathic medical profession. The JAOA's editors are particularly interested in letters that discuss recently published original research.
Letters must be submitted online at http://www.osteopathic.org/JAOAsubmit. Letters to the editor are considered for publication in the JAOA with the understanding that they have not been published elsewhere and are not simultaneously under consideration by any other publication. All accepted letters to the editor are subject to editing and abridgment.
Although the JAOA welcomes letters to the editor, these contributions have a lower publication priority than other submissions. As a consequence, letters are published only when space allows.
Osteopathic Manipulative Treatment for Postural Orthostatic Tachycardia Syndrome
Authors: Goodkin Michael B. , Bellew Lawrence J. 
Published: October 2014

AbstractPostural orthostatic tachycardia syndrome (POTS) is associated with many symptoms including orthostatic intolerance, fatigue, palpitations, and cognitive dysfunction. Treatment, which typically consists of exercise, increased dietary sodium and fluids, compression garments, and medications for orthostatic intolerance, frequently produces unsatisfactory results. The authors report the case of a 26-year-old woman who presented with a 6-year history of severe fatigue, orthostatic intolerance, heat intolerance, cognitive dysfunction, and diffuse pain. She had previously injured her jaw on an obstacle course. Results of a standing test were consistent with POTS. After standard medical therapy was unsuccessful, the patient was referred for osteopathic manipulative treatment. At her 18-month follow-up, the patient's symptoms had improved dramatically. Physicians should consider osteopathic evaluation and manipulative treatment when caring for patients with POTS.J Am Osteopath Assoc.2014;114(11):874-877 doi: 10.7556/jaoa.2014.173
Waves in a Venus general circulation model
Authors: Sugimoto Norihiko , Takagi Masahiro , Matsuda Yoshihisa 
Published: October 2014

AbstractWaves in the Venus atmosphere are numerically investigated by extending a work of Sugimoto et al. (2014). Fast superrotating zonal flow of 120 m s−1 at the equator is reproduced and maintained by solar heating for more than 10 Earth years. The meridional distribution of the obtained fast zonal flow is quite consistent with observations at the cloud levels. In the cloud layer, baroclinic waves develop continuously with a life cycle of ~25 Earth days at midlatitudes, using available potential energy derived from a baroclinically unstable basic state. Rossby waves observed at the cloud top are generated by the baroclinic waves and induce spatio‐temporal variation of the superrotation with amplitude larger than 25 m s−1. Further, Kelvin waves with a period of ∼ 6.2 days appear in the equatorial region below ~50 km. Momentum and heat transports produced by these waves are discussed.
Assimilation of SMOS‐derived soil moisture in a fully integrated hydrological and soil‐vegetation‐atmosphere transfer model in Western Denmark
Authors: Ridler Marc‐Etienne , Madsen Henrik , Stisen Simon , Bircher Simone , Fensholt Rasmus 
Published: October 2014

AbstractReal surface soil moisture retrieved from the Soil Moisture and Ocean Salinity (SMOS) satellite is downscaled and assimilated in a fully integrated hydrological and soil‐vegetation‐atmosphere transfer (MIKE SHE SW‐ET) model using a bias aware ensemble transform Kalman filter (Bias‐ETKF). Satellite‐derived soil moisture assimilation in a catchment scale model is typically restricted by two challenges: (1) passive microwave is too coarse for direct assimilation and (2) the data tend to be biased. The solution proposed in this study is to disaggregate the SMOS bias using a higher resolution land cover classification map that was derived from Landsat thermal images. Using known correlations between SMOS bias and vegetation type, the assimilation filter is adapted to calculate biases online, using an initial bias estimate. Real SMOS‐derived soil moisture is assimilated in a precalibrated catchment model in Denmark. The objective is to determine if any additional gains can be achieved by SMOS surface soil moisture assimilation beyond the optimized model. A series of assimilation experiments were designed to (1) determine how effectively soil moisture corrections propagate downward in the soil column, (2) compare the efficacy of in situ versus SMOS assimilation, and (3) determine how soil moisture assimilation affects fluxes and discharge in the catchment. We find that assimilation of SMOS improved R2 soil moisture correlations in the upper 5 cm compared to a network of 30 in situ sensors for most land cover classes. Assimilation also brought modest gains in R2 at 25 cm depth but slightly degraded the correlation at 50 cm depth. Assimilation overcorrected discharge peaks.
Dynamic aspects of soil water availability for isohydric plants: Focus on root hydraulic resistances
Authors: Couvreur V. , Vanderborght J. , Draye X. , Javaux M. 
Published: October 2014

AbstractSoil water availability for plant transpiration is a key concept in agronomy. The objective of this study is to revisit this concept and discuss how it may be affected by processes locally influencing root hydraulic properties. A physical limitation to soil water availability in terms of maximal flow rate available to plant leaves (
) is defined. It is expressed for isohydric plants, in terms of plant‐centered variables and properties (the equivalent soil water potential sensed by the plant,
; the root system equivalent conductance,
; and a threshold leaf water potential,
). The resulting limitation to plant transpiration is compared to commonly used empirical stress functions. Similarities suggest that the slope of empirical functions might correspond to the ratio of
to the plant potential transpiration rate. The sensitivity of
to local changes of root hydraulic conductances in response to soil matric potential is investigated using model simulations. A decrease of radial conductances when the soil dries induces earlier water stress, but allows maintaining higher night plant water potentials and higher
during the last week of a simulated 1 month drought. In opposition, an increase of radial conductances during soil drying provokes an increase of hydraulic redistribution and
at short term. This study offers a first insight on the effect of dynamic local root hydraulic properties on soil water availability. By better understanding complex interactions between hydraulic processes involved in soil‐plant hydrodynamics, better prospects on how root hydraulic traits mitigate plant water stress might be achieved.
Impact of oxygen transport properties on the kinetic modeling of polypropylene thermal oxidation. II. Effect of oxygen diffusivity
Authors: François‐Heude Alexandre , Richaud Emmanuel , Guinault Alain , Desnoux Eric , Colin Xavier 
Published: October 2014

ABSTRACTThe kinetic model, established in a previous article (François‐Heude et al., J. Appl. Polym. Sci., in press) to predict the homogeneous oxidation in iPP films typically thinner than 100 µm, is now extended to simulate the oxidation profiles in thicker plates by coupling the oxygen diffusion and its consumption by the chemical reactions. In this perspective, oxygen transport properties (namely oxygen solubility, diffusivity, and permeability) are measured by permeametry on a reference iPP. These values are compared with an exhaustive compilation of literature data to evaluate their variability among the whole iPP family, which one has been reasonably ascribed to initial differences in polymer morphology, but also to evaluate their consistency, especially their temperature dependence between 20 and 140°C. Failing to simulate oxidation profiles, the kinetic model is then used as an inverse resolution method for estimating more satisfactory values of oxygen transport properties. It is thus evidenced that the crystallinity changes induced by thermal oxidation largely explains the dramatic decrease in oxygen penetration toward the sample core just after the induction period. A strategy aimed for introducing the relationship between the polymer crystalline morphology and oxygen transport properties into the kinetic model is given in the graphical abstract, although the effect of polymer polarity remains to be established prior to this implementation. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci.2015,132, 41562.
Adsorption of methylene blue on hemicellulose‐based stimuli‐responsive porous hydrogel
Authors: Sun Xiao‐Feng , Gan Zhou , Jing Zhanxin , Wang Haihong , Wang Duo , Jin Yinan 
Published: October 2014

ABSTRACTA stimuli‐responsive porous hydrogel was synthesized from wheat straw hemicellulose using CaCO3 as the porogen, and its application for the removal of methylene blue was studied. The porous structure of the prepared hydrogel was confirmed by SEM analysis. The effects of pH and polyelectrolyte on the swelling of the hydrogels were discussed, and the porous hydrogels showed excellent sensitivity to pH and salt. The deswelling kinetic study indicated that the hydrogels exhibited rapid shrinking in NaCl aqueous solutions. The methylene blue adsorption on the hydrogels was investigated, and the obtained adsorption data was fitted to the pseudo‐first‐order, pseudo‐second‐order and intra‐particle diffusion kinetics models, and the pseudo‐first‐order kinetic model could describe the adsorption process, and the adsorption process of methylene blue on the hydrogels was controlled by external film diffusion. This study reported that the hemicellulose‐based porous hydrogel is promising for water treatment. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 41606.
Form and Function in the Platyrrhine Skull: A Three‐Dimensional Analysis of Dental andTMJMorphology
Authors: Terhune Claire E. , Cooke Siobhán B. , Otárola‐Castillo Erik 
Published: October 2014

ABSTRACTCranial and temporomandibular joint (TMJ) form has been shown to reflect masticatory forces and mandibular range of motion, which vary in relation to feeding strategy. Similarly, the dentition, as the portion of the masticatory apparatus most directly involved in triturating food items, strongly reflects dietary profile. Fine control over condylar and mandibular movements guides the teeth into occlusion, while the topography and position of the dental arcade mediate mandibular movements. We hypothesize that masticatory, and particularly TMJ, morphology and dental form covary in predictable ways with one another and with diet. We employed three‐dimensional geometric morphometric techniques to examine inter‐specific variation in ten platyrrhine species. Landmarks were collected on six datasets describing the upper and lower molars, cranium, glenoid fossa, mandible, and mandibular condyle; two‐block partial least squares analyses were performed to assess covariation between cranial morphology, dentition, and diet. Significant relationships were identified between the molars and the cranium, mandible, and glenoid fossa. Some of these shape complexes reflect feeding strategy; for example, higher crowned/cusped dentitions, as found in primates consuming larger quantities of structural carbohydrates (e.g.,AlouattaandSaimiri), correspond to anteroposterior longer and deeper glenoid fossae. These results indicate strong covariance between dental and TMJ form, aspects of which are related to feeding behavior. However, other aspects of morphological variation display a strong phylogenetic signal; we must therefore examine further ways in which to control for phylogeny when examining covariation in interspecific masticatory form. Anat Rec, 298:29–47, 2015. © 2014 Wiley Periodicals, Inc.
High‐performance liquid chromatographic enantioseparation of amino alcohol analogues possessing 1,2,3,4‐tetrahydroisoquinoline skeleton on polysaccharide‐based chiral stationary phases
Authors: Grecsó Nóra , Ilisz István , Gecse Zsanett , Schönstein László , Fülöp Ferenc , Péter Antal 
Published: October 2014

AbstractThe stereoisomers of 1,2,3,4‐tetrahydroisoquinoline amino alcohol analogues and derivatives thereof were separated in normal‐phase mode on chiral stationary phases based on preprepared silica coated with cellulose tris‐(3,5‐dimethylphenyl carbamate), cellulose tris‐(3‐chloro‐4‐methylphenyl carbamate), cellulose tris‐(4‐methylbenzoate) or cellulose tris‐(4‐chloro‐3‐methylphenyl carbamate). On all the investigated chiral columns, the retention and the enantioseparation were influenced by the nature and the concentrations of the mobile phase components and additives, and also the temperature. Experiments were performed in the temperature range 10–50°C. Thermodynamic parameters were calculated from plots of lnα vs 1/T. On these polysaccharide‐based chiral columns, both enthalpy‐driven separations and entropy‐controlled enantioseparations were observed. The latter was advantageous with regard to the shorter retention and greater selectivity at high temperature. The sequence of elution of the stereoisomers was determined in all cases. Copyright © 2014 John Wiley & Sons, Ltd.
ChemInform Abstract: Revisiting the Crystal Structure of Rhombohedral Lead Metaniobate.
Authors: Olsen Gerhard Henning , Soerby Magnus Helgerud , Hauback Bjoern Christian , Selbach Sverre Magnus , Grande Tor 
Published: October 2014

AbstractThe crystal structure of rhombohedral PbNb2O6 is re‐examined by powder XRD and powder neutron diffraction in combination with ab initio DFT calculations.
ChemInform Abstract: One‐Pot Occurrence of Two Polymorphs of Rb2Sc[Si4O10]F and Their Structural, Spectroscopic and Computational Characterization.
Authors: Kahlenberg Volker , Manninger Tanja , Perfler Lukas , Toebbens Daniel M. 
Published: October 2014

AbstractSingle crystals of two forms of Rb2Sc[Si4O10]F within the same run are obtained from mixtures of Sc2O3, SiO2, and RbF (Pt tube, 1373 K, 2 h).
ChemInform Abstract: Crystal Structure and Orbital‐Singlet State of AgxVP2O7.
Authors: Onoda Masashige , Sakamoto Takuma 
Published: October 2014

AbstractPolycrystalline samples of AgxVP2O7 (0.7 ≤ x ≤ 0.9) are prepared by solid state reaction of mixtures of composition 2xAg3PO4, 4xVPO4, 3(1‐x)VPO5, and (3‐x)V(PO3)3 (sealed quartz tubes, 1073 K, 12 h).
ChemInform Abstract: Luminescence Properties of Ca3Ti2O7:Eu3+, Bi3+, R+ (R+: Li+, Na+, and K+) Red Emission Phosphor.
Authors: Cao Renping , Chen Guo , Yu Xiaoguang , Cao Chunyan , Chen Kangbin , Liu Pan , Jiang Shenhua 
Published: October 2014

AbstractThe title phosphors are prepared by solid state reaction using CaCO3, M2CO3 (M: Li, Na, K), TiO2, Eu2O3, and Bi2O3 as source materials (600 °C for 5 h and 1350 °C for 4 h in air).
ChemInform Abstract: The Dy—Ni—Si System as a Representative of the Rare Earth—Ni—Si Family: Its Isothermal Section and New Rare‐Earth Nickel Silicides.
Authors: Yuan Fang , Mozharivskyj Y. , Morozkin A. V. , Knotko A. V. , Yapaskurt V. O. , Pani M. , Provino A. , Manfrinetti P. 
Published: October 2014

AbstractSamples out of the Dy—Ni—Si system are prepared by arc melting of the elements followed by annealing at 870 (Dy‐rich corner) or 1070 K (200‐240 h) and investigated by X‐ray and microprobe analyses.
ChemInform Abstract: High Pressure‐High Temperature Synthesis of Lithium‐Rich Li3O(Cl, Br) and Li3‐xCax/2OCl anti‐Perovskite Halides.
Authors: Zhang Jianzhong , Han Jiantao , Zhu Jinlong , Lin Zhijun , Braga Maria H. , Daemen Luke L. , Wang Liping , Zhao Yusheng 
Published: October 2014

AbstractThe system (Li,Ca)—O—(Cl,Br) is investigated by synchrotron XRD under high pressure and temperature for the synthesis of lithium‐rich anti‐perovskite halides.
ChemInform Abstract: Synthesis and Crystal Chemistry of Microporous Titanates Kx(Ti,M)8O16 Where M: Sc—Ni.
Authors: Moetakef Pouya , Larson Amber M. , Hodges Brenna C. , Zavalij Peter , Gaskell Karen J. , Piccoli Philip M. , Rodriguez Efrain E. 
Published: October 2014

AbstractSingle crystals of potassium titanate hollandites K1.5Sc1.5Ti6.5O16, K1.4Ti8O16, K1.5V1.5Ti6.5O16, K1.5Cr1.5Ti6.5O16, K1.6Ni0.8Ti7.2O16, K1.4Mn1.4Ti6.6O16, K1.5Fe1.5Ti6.5O16, K1.5Co0.75Ti7.25O16, and K1.6Ni0.8Ti7.2O16 are prepared by a flux method from transition metal oxides and KCl in a molar ratio of 1:10 (alumina crucibles, 1473—1573 K, 12 h).
ChemInform Abstract: Synthesis and Characterization of the New Strontium Borogermanate Sr3‐x/2B2‐xGe4+xO14 (x = 0.32).
Authors: Petermueller Benedikt , Petschnig Lucas L. , Wurst Klaus , Heymann Gunter , Huppertz Hubert 
Published: October 2014

AbstractSmall, colorless crystals of the title compound are prepared by reaction of SrO, SrCO3, GeO2, and H3BO3 in a NaF/KF flux (Pt crucible, 1100 °C, 38 h).
ChemInform Abstract: Chromium Substitution in Mullite Type Bismuth Aluminate: Bi2CrxAl4‐xO9 with 0 ≤ x ≤ 2.0.
Authors: Debnath Tapas , Ullah Ahamed , Ruescher Claus H. , Hussain Altaf 
Published: October 2014

AbstractThe title compounds are prepared from stoichiometric mixtures of the metal nitrates dissolved in glycerin (120 °C, 12 h) followed by calcination in air (Pt crucible, 800 °C, 24 h).
ChemInform Abstract: A New Nb28 Cluster Based on Tungstophosphate, [{Nb4O6 (OH)4}{Nb6P2W12O61 }4]36‐.
Authors: Zhang Dongdi , Liang Zhijie , Xie Songqiang , Ma Pengtao , Zhang Chao , Wang Jingping , Niu Jingyang 
Published: October 2014

AbstractPale‐yellow block‐shaped crystals of Na12 [H24{Nb4O6 (OH)4}{Nb6P2W12O61 }4]·24H2O are prepared by addition of NaCl to mixtures of Nb6O19 dissolved in aqueous H2O2 solution, HCl, and K12[H2P2W12O48] (80 °C, 14% yield).
ChemInform Abstract: Perovskite‐Structure TlMnO3: A New Manganite with New Properties.
Authors: Yi Wei , Kumagai Yu. , Spaldin Nicola A. , Matsushita Yoshitaka , Sato Akira , Presniakov Igor A. , Sobolev Alexey V. , Glazkova Yana S. , Belik Alexei A. 
Published: October 2014

AbstractThe title compound is prepared from a stoichiometric mixture of Mn2O3 and Tl2O3 (Au capsules, 6 GPa, 1500 °C, 2 h) and characterized by powder and single crystal XRD, magnetic, specific heat, and electrical resistivity measurements, Moessbauer spectroscopy, and DFT calculations.
ChemInform Abstract: Thermal Stability of Hexagonal OsB2.
Authors: Xie Zhilin , Blair Richard G. , Orlovskaya Nina , Cullen David A. , Andrew Payzant E. 
Published: October 2014

AbstractHexagonal ReB2‐type OsB2 refractory ceramic powder is prepared by high energy ball milling of elemental Os and B powders.
ChemInform Abstract: Synergistic Stereoselective Organocatalysis with Indium(III) Salts.
Authors: Gualandi Andrea , Mengozzi Luca , Wilson Claire Margaret , Cozzi Pier Giorgio 
Published: October 2014

AbstractSeveral organocatalytic SN1‐type reactions from allylic, benzylic and benzhydrylic alcohols are promoted by In(III) salts.
ChemInform Abstract: Trisubstituted 2‐Trifluoromethyl Pyrrolidines via Catalytic Asymmetric Michael Addition/Reductive Cyclization.
Authors: Corbett Michael T. , Xu Qihai , Johnson Jeffrey S. 
Published: October 2014

AbstractOrganocatalytic addition of trifluoromethylketones to nitroolefins proceeds under mild conditions to form Michael adducts with very high diastereo‐ and enantioselectivities.
ChemInform Abstract: Highly Efficient Asymmetric Organocatalytic Michael Addition of α,α‐Disubstituted Aldehydes to Nitroolefins under Solvent‐Free Conditions.
Authors: He Junpeng , Chen Qiankun , Ni Bukuo 
Published: October 2014

AbstractA simple and easily accessible chiral diamine catalyst is employed for the addition of aldehydes (I) and (IV) to nitroolefins to form Michael adducts in high yields and with high levels of enantioselectivity.
ChemInform Abstract: Phosphoric Acid Mediated Tautomerism of Imines: Addition of a Secondary Enamine Intermediate to Aldehydes.
Authors: Davis Lindsey O. , Putri Marcella A. , Meyer Caitlin L. , Durant Christopher P. 
Published: October 2014

AbstractSecondary enamines generated in situ from imine (I) and diethylphosphate react with aldehydes to give cross‐aldol condensation products.
ChemInform Abstract: Lewis Acid‐Promoted Cyclization/Halogenation of Allenyl Ethenetricarboxylates and the Corresponding Amides: Stereoselective Synthesis of Haloalkenyl Five‐Membered Heterocycles.
Authors: Fukushima Yugo , Yamazaki Shoko , Ogawa Akiya 
Published: October 2014

AbstractReactions of allenyl ethenetricarboxylates (I) and the corresponding amides (III) with Lewis acids, such as AlCl3, AlBr3 and ZnX2 (X = Cl, Br, I) afford 3,4‐trans‐haloalkenyl lactones (III) and lactams (IV)/(V).
ChemInform Abstract: Oxidation of Allylic and Benzylic Alcohols to Aldehydes and Carboxylic Acids.
Authors: Koenning Daniel , Olbrisch Tobias , Sypaseuth Fanni D. , Tzschucke C. Christoph , Christmann Mathias 
Published: October 2014

AbstractOxidation of allylic and benzylic alcohols (I), (III) and (VII) to the corresponding carboxylic acids (V), (VI), and (IX) is achieved by merging a Cu‐catalyzed oxidation using dioxygen as a terminal oxidant with subsequent chlorite oxidation.
ChemInform Abstract: A 2‐Iodobenzamide Catalyst for Oxidation of Alcohols at Room Temperature.
Authors: Yakura Takayuki , Yamada Akihiro , Noda Narumi , Fujiwara Tomoya , Nambu Hisanori 
Published: October 2014

AbstractTreatment of primary and secondary alcohols with a catalytic amount of iodobenzamide in the presence of oxone yields the corresponding carbonyl compounds.
ChemInform Abstract: N1‐Selective Oxidative C—N Coupling of Azoles with Pyrroles Using a Hypervalent Iodine Reagent.
Authors: Morimoto Koji , Ohnishi Yusuke , Nakamura Akira , Sakamoto Kazuma , Dohi Toshifumi , Kita Yasuyuki 
Published: October 2014

AbstractNo explanation is given for the changed regioselectivity in the reaction of triazole (VIII) with unsubstituted indole (XV).