bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Th(VO3)2(SeO3) and Ln(VO3)2(IO3) (Ln = Ce, Pr, Nd, Sm, and Eu): Unusual Cases of Aliovalent Substitution.
Authors: Eaton Teresa , Lin Jian , Cross Justin N. , Stritzinger Jared T. , Albrecht‐Schmitt Thomas E. 
Published: June 2014

AbstractTh(VO3)2(SeO3) and Ln(VO3)2(IO3) (Ln: Ce, Pr, Nd, Sm, and Eu) are prepared by hydrothermal synthesis using Th and Ln nitrates, V2O5, SeO2, I2O5, and H2O (autoclave, 230 (for Th) or 180 °C (for Ln), 3 d, 60% yield for the Th compound, 40, 55, and 40% for the Ce, Pr, Eu compounds, and 5, 10% for the Nd and Sm compound).
ChemInform Abstract: K6[Fe8.27(HPO3)12]: A New Mixed‐Valence Iron Phosphite.
Authors: Hamchaoui Farida , Alonzo Veronique , Rebbah Houria , Le Fur Eric 
Published: June 2014

AbstractThe title compound is prepared by hydrothermal synthesis using FeSO4, H3PO3, K2CO3, and H2O in a 0.2:1.5:0.8:28 molar ratio (autoclave, 453 K, 72 h).
ChemInform Abstract: Highly Enantioselective Synthesis of α‐Azido‐β‐hydroxy Methyl Ketones Catalyzed by a Cooperative Proline—Guanidinium Salt System.
Authors: Martinez‐Castaneda Angel , Kedziora Kinga , Lavandera Ivan , Rodriguez‐Solla Humberto , Concellon Carmen , del Amo Vicente 
Published: June 2014

AbstractThe first enantioselective synthesis of α‐azido‐β‐hydroxy ketones via direct intermolecular aldol reaction of azidoacetone and aromatic aldehydes is described.
ChemInform Abstract: Pd‐Catalyzed Kinetic Resolution of Cyclic Enol Ethers. An Enantioselective Route to Functionalized Pyrans.
Authors: Zirimwabagabo Jean‐Olivier , Harrity Joseph P. A. 
Published: June 2014

AbstractThe asymmetric Pd‐catalyzed [1,3]‐rearrangement of racemic cyclic enol ether (I) leads to enantioenriched cyclohexanone (II) and enantiopure enol ethers (I) (15 examples for analogues).
ChemInform Abstract: Chiral Amides via Copper‐Catalyzed Enantioselective Conjugate Addition.
Authors: Schoonen Anne K. , Fernandez‐Ibanez M. Angeles , Fananas‐Mastral Martin , Teichert Johannes F. , Feringa Ben L. 
Published: June 2014

AbstractA highly enantioselective one pot procedure for the synthesis of β‐substituted amides (IV) is developed starting from the corresponding α,β‐unsaturated esters (I).
ChemInform Abstract: Organocatalysis of Nucleophilic Substitution Reactions by the Combined Effects of Two Promoters Fused in a Molecule: Oligoethylene Glycol Substituted Imidazolium Salts.
Authors: Jadhav Vinod H. , Kim Ju‐Young , Chi Dae Yoon , Lee Sungyul , Kim Dong Wook 
Published: June 2014

AbstractA highly efficient promoter for the SN2 reaction of various substrates by enhancing the reactivity of alkali metal salts is presented.
ChemInform Abstract: Expedient Synthesis of C3‐Symmetric Hexasubstituted Benzenes via Nicholas Reaction/[2 + 2 + 2] Cycloaddition. New Platforms for Molecular Recognition.
Authors: Carrillo Romen , Martin Tomas , Lopez‐Rodriguez Matias , Pinacho Crisostomo Fernando 
Published: June 2014

AbstractThe new method is based on the Nicholas reaction giving dimer (II) and macrocycle (III) which is further converted into the target compound by decomplexation and [2 + 2 + 2] cycloaddition under microwave irradiation.
ChemInform Abstract: A General Method for N‐Methylation of Amines and Nitro Compounds with Dimethylsulfoxide.
Authors: Jiang Xue , Wang Chao , Wei Yawen , Xue Dong , Liu Zhaotie , Xiao Jianliang 
Published: June 2014

AbstractA novel, green, and practical method for the amine methylation is developed.
ChemInform Abstract: nBu4NI‐Catalyzed Oxidative Imidation of Ketones with Imides: Synthesis of α‐Amino Ketones.
Authors: Lv Yunhe , Li Yan , Xiong Tao , Lu Yu , Liu Qun , Zhang Qian 
Published: June 2014

AbstractThe first example of a Bu4NI‐catalyzed C—N cross‐coupling imidation reaction of sp3 C—H bonds in imides with TBHP as oxidant is reported.
ChemInform Abstract: One‐Pot, Two‐Step Direct Conversion of Alkenes to Amines Through Tandem Ozonolysis and Ammonia‐Borane in Water.
Authors: Tyagi Vipin , Gupta Ashok Kumar 
Published: June 2014

AbstractA simple, mild, and efficient one‐pot procedure for the conversion of alkenes to amines in environmentally friendly aqueous solution is developed.
ChemInform Abstract: Silica‐Functionalized CuI: An Efficient and Selective Catalyst for N‐Benzylation, Allylation, and Alkylation of Primary and Secondary Amines in Water.
Authors: Shamim Tahira , Kumar Vineet , Paul Satya 
Published: June 2014

AbstractThe employed catalyst can be recycled and reused for up to five runs without loss of activity.
ChemInform Abstract: Phosphane‐Ligated Ionic Palladium Complexes: Synthesis, Characterization and Application as Efficient and Reusable Precatalysts for the Homogeneous Carbonylative Sonogashira Reaction under CuI‐Free Conditions.
Authors: Zhang Jing , Wang Yongyong , Zhao Xiaoli , Liu Ye 
Published: June 2014

AbstractThe catalyst can be recycled and reused for 5 runs without a significant loss of activity.
ChemInform Abstract: Reductive Removal of Methoxyacetyl Protective Group Using Sodium Borohydride.
Authors: Gadekar Pradip K. , Hoermann Maryann , Corbo Faith , Sharma Rajiv , Sarveswari S. , Roychowdhury Abhijit 
Published: June 2014

AbstractA selective reductive deprotection of methoxyacetyl‐protected alcohols and thiols is presented.
ChemInform Abstract: A Convenient Regioselective Synthesis of Cyclopentadienones via Palladium‐Catalyzed [2 + 2 + 1] Cyclocarbonylation of Alkynes.
Authors: Xu Yanli , Zhao Jinwu , Chen Huoji , Wu Wanqing , Jiang Huanfeng 
Published: June 2014

AbstractThe analogues reaction of 1,2‐diphenylethyne (VII) with 4‐phenylbut‐3‐yn‐2‐one, 3‐phenylpropiolaldehyde, 3‐phenylpropiolic acid or 3‐phenylpropiolamide gave none or only trace amounts of the desired products.
ChemInform Abstract: Rh(III)‐Catalyzed C—H Activation with Allenes to Synthesize Conjugated Olefins.
Authors: Gong Tian‐Jun , Su Wei , Liu Zhao‐Jing , Cheng Wan‐Min , Xiao Bin , Fu Yao 
Published: June 2014

AbstractThe Rh(III)‐catalyzed C—H activation with allenes is applicable to olefin and arene C(sp2)—H bonds and is compatible to a variety of functional groups.
ChemInform Abstract: Chemoselective N‐Deacetylation under Mild Conditions.
Authors: Sultane Prakash R. , Mete Trimbak B. , Bhat Ramakrishna G. 
Published: June 2014

AbstractCompetition experiments between N‐acetyl protected 4‐methoxyaniline and N‐Cbz‐, N‐Boc‐, N‐Fmoc‐ or N‐Tos‐protected aniline, respectively, lead to chemoselective deacetylation of 4‐methoxyaniline and almost quantitative recovery of the competitive substrates.
ChemInform Abstract: Chemoselective Hydrogenation of Functionalized Nitroarenes and Imines by Using Carbon Nanofiber‐Supported Iridium Nanoparticles.
Authors: Motoyama Yukihiro , Taguchi Masahiro , Desmira Nelfa , Yoon Seong‐Ho , Mochida Isao , Nagashima Hideo 
Published: June 2014

AbstractThe catalyst consisting of carbon nanofibers with tubular graphite layers is reused five times without loss of activity.
ChemInform Abstract: Transformylating Amine with DMF to Formamide over CeO2 Catalyst.
Authors: Wang Yehong , Wang Feng , Zhang Chaofeng , Zhang Jian , Li Mingrun , Xu Jie 
Published: June 2014

AbstractThe acid‐base bifunctional property of the heterogeneous catalyst CeO2 is crucial and it is the only heterogeneous catalytic system reported to accomplish this reaction in good yields.
ChemInform Abstract: Palladium‐Catalyzed Regio‐ and Stereoselective Chlorothiolation of Terminal Alkynes with Sulfenyl Chlorides.
Authors: Iwasaki Masayuki , Fujii Tomoya , Yamamoto Arisa , Nakajima Kiyohiko , Nishihara Yasushi 
Published: June 2014

AbstractThe reaction proceeds with complete (Z)‐selectivity.
ChemInform Abstract: Copper‐Catalyzed C—H Bond Direct Chalcogenation of Aromatic Compounds Leading to Diaryl Sulfides, Selenides, and Diselenides by Using Elemental Sulfur and Selenium as Chalcogen Sources under Oxidative Conditions.
Authors: Shibahara Fumitoshi , Kanai Takafumi , Yamaguchi Eiji , Kamei Akika , Yamauchi Takayuki , Murai Toshiaki 
Published: June 2014

AbstractAn oxidative Cu‐catalyzed chalcogenation of aromatic compounds with elemental sulfur or selenium and air or oxygen as terminal oxidant is presented.
ChemInform Abstract: Base‐Mediated Synthesis of 1‐Aryl‐4‐(phenylsulfonyl)butan‐1‐ones from 1,2‐Bis(phenylsulfonyl)ethane and Ketones.
Authors: Xie Ye‐Xiang , Song Ren‐Jie , Liu Yu , Wang Zhi‐Qiang , Xiang Jian‐Nan , Li Jin‐Heng 
Published: June 2014

AbstractThis new and simple process gives access to primary sulfones by using 1,2‐bis(phenylsulfonyl)ethane as the sulfone source, for the first time.
ChemInform Abstract: Fe(OTf)3‐Catalyzed α‐Benzylation of Aryl Methyl Ketones with Electrophilic Secondary and Aryl Alcohols.
Authors: Pan Xiaojuan , Li Minghao , Gu Yanlong 
Published: June 2014

AbstractAryl methyl ketones can be used as nucleophiles in Fe(OTf)3‐catalyzed Friedel‐Crafts type reactions with benzhydrols to form the corresponding products (III) in good yields.
ChemInform Abstract: Expedient Access to Substituted 3‐Amino‐2‐cyclopentenones by Dirhodium‐Catalyzed [3 + 2]‐Annulation of Silylated Ketene Imines and Enoldiazoacetates.
Authors: Xu Xichen , Leszczynski John S. , Mason Savannah M. , Zavalij Peter Y. , Doyle Michael P. 
Published: June 2014

AbstractThe reaction of (I) to (IIIa) is scaled up.
ChemInform Abstract: Pictet—Spengler Reactions of Oxetan‐3‐ones and Related Heterocycles.
Authors: Beasley Benjamin O. , Alli‐Balogun Abimbola , Clarkson Guy J. , Shipman Michael 
Published: June 2014

AbstractPictet—Spengler cyclizations of 3‐oxetan‐3‐one or azetidin‐3‐one with tryptamine or tryptophan derivatives gives spirocyclic tetrahydro‐β‐carbolines.
ChemInform Abstract: Acyl Migration from N to C in Aziridine‐2‐carboxylic Esters.
Authors: Strumfs Boriss , Hermane Jekaterina , Belyakov Sergey , Trapencieris Peteris 
Published: June 2014

AbstractThe substituent in the ester group at the C2 position strongly influences the yields of the migration products.
ChemInform Abstract: Direct Access to Isoindolines Through Tandem Rh(III)‐Catalyzed Alkenylation and Cyclization of N‐Benzyltriflamides.
Authors: Mishra Neeraj Kumar , Park Jihye , Sharma Satyasheel , Han Sangil , Kim Mirim , Shin Youngmi , Jang Jinbong , Kwak Jong Hwan , Jung Young Hoon , Kim In Su 
Published: June 2014

AbstractTitle compounds (III), (V), and (X) are prepared via Rh‐catalyzed C—H bond functionalization directed by a triflamide moiety, followed by an intramolecular aza‐Mannich cyclization.
ChemInform Abstract: Enantioselective Construction of Vicinal All‐Carbon Quaternary Centers via Catalytic Double Asymmetric Decarboxylative Allylation.
Authors: Ghosh Santanu , Bhunia Subhajit , Kakde Badrinath N. , De Subhadip , Bisai Alakesh 
Published: June 2014

AbstractThe decarboxylation product (IIb) is a building block for the preparation of alkaloids like (‐)‐chimonanthine, (+)‐calycanthine, ent‐WIN 64821 and (‐)‐ditryptophenline.
ChemInform Abstract: Syntheses of 4‐, 5‐, 6‐, and 7‐Substituted Tryptamine Derivatives and the Use of a Bromine Atom as a Protecting Group.
Authors: Rene Olivier , Fauber Benjamin P. 
Published: June 2014

AbstractThe title compounds are prepared from chlorophenylhydrazines and 5‐chloropentan‐2‐one.
ChemInform Abstract: Enantioselective Hydroacylation of N‐Vinylindole‐2‐carboxaldehydes.
Authors: Ghosh Avipsa , Stanley Levi M. 
Published: June 2014

AbstractA rhodium‐catalyzed intramolecular hydroacylation of aldehydes (I) leads to chiral tricyclic indoles (II) with high enantioselectivity.
ChemInform Abstract: KI‐Catalyzed Arylation of Benzothiazoles from the Coupling of Aryl Aldehydes with Benzothiazoles in Neat Water.
Authors: Gao Yuyu , Song Qiuling , Cheng Guolin , Cui Xiuling 
Published: June 2014

AbstractA series of 2‐substituted benzothiazoles (III) and (V) (28 examples in all) is readily prepared by a KI‐catalyzed oxidative arylation of benzothiazoles (I) with corresponding aldehydes (II) and (IV), respectively.
ChemInform Abstract: Rhodium‐Catalyzed Intermolecular Hydroarylation of Internal Alkynes with N‐1‐Phenylbenzotriazoles.
Authors: Zhou Wang , Yang Youqing , Wang Zhiwei , Deng Guo‐Jun 
Published: June 2014

AbstractAttempts towards performing the reaction using 1‐phenyl‐indole or 1‐phenyl‐1,3‐benzodiazole instead of the 1‐phenyl‐1,2,3‐benzotriazole derivatives fail.
ChemInform Abstract: An Asymmetric Iodolactonization Reaction Catalyzed by a Zinc Bis‐proline—Phenol Complex.
Authors: Filippova Liudmila , Stenstroem Yngve , Hansen Trond Vidar 
Published: June 2014

AbstractThe application of Trost′s di‐nuclear zinc complex in catalytic asymmetric iodocyclizations of 5‐substituted 5‐hexenoic acid derivatives using NIS is demonstrated.
ChemInform Abstract: From Liquid to Solid‐State Fluorescence: Tricyclic Lactones Based on 4‐Hydroxy‐1,3‐thiazoles.
Authors: Calderon Ortiz Lorena K. , Wuerfel Hendryk , Taeuscher Eric , Weiss Dieter , Birckner Eckhard , Goerls Helmar , Beckert Rainer 
Published: June 2014

AbstractThe compounds′ fluorescence properties in solid state as well as in polar solvents (EtOH, DMSO) in absence and presence of NaOH and HCl are examined.
ChemInform Abstract: Efficient and Scalable Synthesis of 4‐Carboxy‐Pennsylvania Green Methyl Ester: A Hydrophobic Building Block for Fluorescent Molecular Probes.
Authors: Woydziak Zachary R. , Fu Liqiang , Peterson Blake 
Published: June 2014

AbstractThe improved reaction conditions allow the synthesis of multigram quantities of the title compound (VIII) in 28% overall yield.
ChemInform Abstract: Solvent‐Free Microwave‐Assisted Preparation of N‐(2‐(Pyridin‐2‐yl)‐ethyl)sulfonamides
Authors: Ghattas Paul , Carlin Joseph W. , Murkli Steven L. , Jacobs Danielle L. 
Published: June 2014

Abstractvia 1,4‐aza‐conjugate addition between sulfonamides and 2‐vinylpyridine
ChemInform Abstract: Comparative Study of Catalytic Potential of TBAB, BTEAC, and CTAB in One‐Pot Synthesis of 1,4‐Dihydropyridines under Aqueous Medium.
Authors: Ananda Kumar T. Durai , Mohan P. , Subrahmanyam C. V. S. , Satyanarayana K. 
Published: June 2014

AbstractEfficient synthesis of 1,4‐dihydropyridines via phase‐transfer catalyzed Hantzsch reactions are described.
ChemInform Abstract: Diastereoselective Synthesis of Highly Functionalized Quinolizines via a Pyridine‐Based Three‐Component Reaction and a DFT Investigation on the Reaction Mechanism.
Authors: Esmaeili Abbas Ali , Zarifi Farzaneh , Moradi Abbas , Izadyar Mohammad , Fakhari Ali Reza 
Published: June 2014

AbstractThis novel, one‐pot, three‐component reaction affords quinolizine derivatives via 1,4‐dipolar cycloaddition without using any catalyst or activation.
ChemInform Abstract: The Acid‐Catalyzed Synthesis of 7‐Azaindoles from 3‐Alkynyl‐2‐aminopyridines and Their Antimicrobial Activity.
Authors: Leboho Tlabo C. , van Vuuren Sandy F. , Michael Joseph P. , de Koning Charles B. 
Published: June 2014

AbstractA series of 7‐azaindoles is prepared by Sonogashira coupling of 3‐halopyridines (I) with alkynes followed by ring‐closure reaction of resulting 3‐alkynyl‐2‐aminopyridines (III) in the presence of TFA and TFAA.
ChemInform Abstract: Simple, Multicomponent, Ecofriendly, Microwave‐Mediated Route for the Synthesis of Antimicrobial 2‐Amino‐6‐aryl‐4‐(3H)‐pyrimidinones.
Authors: da Silva Ivangela E. A. , Braga Vanildo M. L. , Melo Mychely S. , dos S. Correia Maria Tereza , dos Anjos Janaina V. 
Published: June 2014

AbstractPyrimidinones (IVa) and (IVf) show significant activity against S.
ChemInform Abstract: Synthesis of 4‐Unsubstituted Dihydropyrimidines Having Acyl and Alkoxycarbonyl Groups at 5‐ and 6‐Positions by Cyclization—Elimination Reactions Using 1,3‐Diaza‐1,3‐butadienes.
Authors: Nishimura Yoshio , Cho Hidetsura 
Published: June 2014

AbstractThe reaction of 1,2‐disubstituted ethylenes with diazabutadiene (II) and subsequent elimination of a dimethylamino group gives access to novel N‐Boc protected dihydropyrimidines.
ChemInform Abstract: Design, Synthesis, and Antibacterial Evaluation of Some Novel 3′‐(Phenylamino)‐1′H‐spiro[indoline‐3,2′‐quinazoline]‐2,4′(3′H)‐dione Derivatives.
Authors: Mohammadi Ali A. , Askari Saber , Rohi Hamed , Soorki Ali Abolhasani 
Published: June 2014

AbstractA variety of new spiro(indoline‐quinazoline) derivatives (IV) (13 examples) are synthesized via an efficient one‐pot, three‐component reaction of isatins, isatoic anhydrides, and phenylhydrazine using alum as a nontoxic, easily available catalyst.
ChemInform Abstract: A Novel and Effective Approach to 4‐Fluoropyrimidines.
Authors: Sedenkova Kseniya N. , Averina Elena B. , Grishin Yuri K. , Kuznetsova Tamara S. , Zefirov Nikolay S. 
Published: June 2014

AbstractIt is demonstrated, that 4‐fluoropyrimidines can be synthesized in a two‐step process involving heterocyclization of gem‐bromofluorocyclopropanes followed by reduction of the resulting N‐oxides with PCl3.
ChemInform Abstract: C—S Bond‐Forming Reactions of Barbiturylbromide with Isothiocarbamides in Aqueous Media.
Authors: Sontakke Madhuri M. , Jichkar Atul A. , Dhonde Madhukar G. , Bhaskar Chandrakant S. , Berad Baliram N. 
Published: June 2014

AbstractThe C—S cross‐coupling proceeds without any catalyst, is very efficient, simple, general, and high yielding.
ChemInform Abstract: Synthesis of Bisindolylindeno[1,2‐b]quinoxaline and Bisindolylindeno[3,4‐b]pyrazine with Poly(N,N′‐dibromo‐N‐ethylnaphthyl‐2,7‐disulfonamide).
Authors: Khazaei Ardeshir , Massoudi Abdolhossien , Chegeni Mahdieh 
Published: June 2014

AbstractA simple and efficient method for the synthesis of the new title compounds [cf.
ChemInform Abstract: A Novel Protocol for Selective Synthesis of Monoclinic Zirconia Nanoparticles as a Heterogeneous Catalyst for Condensation of 1,2‐Diamines with 1,2‐Dicarbonyl Compounds.
Authors: Jafarpour Maasoumeh , Rezapour Elham , Ghahramaninezhad Mahboobe , Rezaeifard Abdolreza 
Published: June 2014

AbstractMonoclinic zirconia nanoparticles efficiently catalyze the condensation of various 1,2‐diamines with 1,2‐dicarbonyl compounds to provide an environmentally friendly alternative for the synthesis of quinoxaline and pyridopyrazine derivatives.
ChemInform Abstract: Expeditious Synthesis of C2‐ or N4‐Aryl‐1,4‐benzothiazin‐3‐one via Orthogonal Pd‐Catalyzed C‐Arylation and Cu‐Catalyzed N‐Arylation.
Authors: Huang Wei‐Sheng , Xu Rongsong , Dodd Rory , Shakespeare William C. 
Published: June 2014

AbstractEfficient reaction conditions for the regioselective N‐arylation as well as the regioselective C2‐arylation of 1,4‐benzothiazin‐3‐one are presented.
ChemInform Abstract: Stereoselective Synthesis of Either (E)‐ or (Z)‐Silyl Enol Ether from the Same Acyclic α,β‐Unsaturated Ketone Using Cationic Rhodium Complex‐Catalyzed 1,4‐Hydrosilylation.
Authors: Onodera Gen , Hachisuka Ryosuke , Noguchi Tomomi , Miura Hiroki , Hashimoto Toru , Takeuchi Ryo 
Published: June 2014

AbstractSilyl enol ethers are prepared by Rh‐catalyzed 1,4 hydrosilylation of α,β‐unsaturated ketones.
ChemInform Abstract: Highly Efficient One‐Pot Synthesis of α‐Aminophosphonates Catalyzed by Ytterbium Triflate in Water.
Authors: Shen MingGui , Shang ShiBin , Song ZhanQian , Wang Dan , Rao XiaoPing , Gao Hong , Wang Juan 
Published: June 2014

AbstractA highly efficient protocol for the synthesis of α‐aminophosphonates (IV) (15 examples) via three‐component, one‐pot reaction of aldehydes, primary amines, and diethyl phosphite is developed.
ChemInform Abstract: An Expedient Synthesis of Pyrrole‐2‐phosphonates via Direct Oxidative Phosphorylation and γ‐Hydroxy‐γ‐butyrolactams from Pyrroles.
Authors: Kim Se Hee , Kim Ko Hoon , Lim Jin Woo , Kim Jae Nyoung 
Published: June 2014

AbstractA convenient protocol for the synthesis of pyrrole‐2‐phosphonates via Ag‐catalyzed reaction of dialkyl phosphites with pyrrole is developed.
ChemInform Abstract: Four New 7,8‐Epoxycembranoids from a Chinese Soft Coral Lobophytum sp.
Authors: Zhao Min , Li Xiubao , Zhao Feng , Cheng Shimiao , Xiang Zheng , Dong Jianyong , Huang Kexin , Yan Pengcheng 
Published: June 2014

Abstractisolation, structural elucidation and inhibitory effect on lipopolysaccharide (LPS)‐induced nitric oxide (NO) production in mouse peritoneal macrophages
ChemInform Abstract: Regioselective One‐Pot Protection, Protection—Glycosylation and Protection—Glycosylation—Glycosylation of Carbohydrates: A Case Study with D‐Glucose.
Authors: Huang Teng‐Yi , Zulueta Medel Manuel L. , Hung Shang‐Cheng 
Published: June 2014

AbstractThe TmsOTf‐catalyzed reaction of tetrasilylated glucoside (I) with benzaldehyde leads to an intermediate benzylidene acetal diol, which is converted into triols (III) and (IV) by a reductive ring opening (11 further examples for the one‐pot protection).
ChemInform Abstract: Syntheses of 5′‐Amino‐2′,5′‐dideoxy‐2′,2′‐difluorocytidine Derivatives as Novel Anticancer Nucleoside Analogues.
Authors: Labroli Marc A. , Dwyer Michael P. , Shen Ruichao , Popovici‐Muller Janeta , Pu Qinglin , Richard Judson , Rosner Kristen , Paruch Kamil , Guzi Timothy J. 
Published: June 2014

AbstractA series of 5′‐amino derivatives of gemcitabine are synthesized in order to identify anticancer nucleoside analogues (no biological activity reported).
ChemInform Abstract: Late‐Stage β‐Epimerization. A Stereodivergent to Stereoconvergent Relay to the First Total Synthesis of (+)‐Murolic Acid.
Authors: Fernandes Rodney A. , Patil Pradnya H. , Chowdhury Asim K. 
Published: June 2014

AbstractThe target compound is synthesized in 17 steps and 15% overall yield.
ChemInform Abstract: Tandyukisin, a Novel Ketoaldehyde Decalin Derivative, Produced by a Marine Sponge‐Derived Trichoderma harzianum.
Authors: Yamada Takeshi , Mizutani Yuki , Umebayashi Yoshihide , Inno Naoko , Kawashima Maiko , Kikuchi Takashi , Tanaka Reiko 
Published: June 2014

AbstractThe compound (I) exhibits a moderate cytotoxicity against human cancer cell lines.
ChemInform Abstract: BiVO4—Ru/SrTiO3:Rh Composite Z‐Scheme Photocatalyst for Solar Water Splitting.
Authors: Jia Qingxin , Iwase Akihide , Kudo Akihiko 
Published: June 2014

AbstractA composite Z‐scheme water splitting photocatalyst that combines a H2 evolution photocatalyst (Rh‐doped Ru/SrTiO3) with an O2 evolving catalyst (BiVO4) is prepared by an impregnation method as well as a liquid—solid state reaction.
ChemInform Abstract: Understanding Boron Through Size‐Selected Clusters: Structure, Chemical Bonding, and Fluxionality
Authors: Sergeeva Alina P. , Popov Ivan A. , Piazza Zachary A. , Li Wei‐Li , Romanescu Constantin , Wang Lai‐Sheng , Boldyrev Alexander I. 
Published: June 2014

AbstractReview: 88 refs.
ChemInform Abstract: Exploring the Limits: A Low‐Pressure, Low‐Temperature Haber—Bosch Process
Authors: Vojvodic Aleksandra , Medford Andrew James , Studt Felix , Abild‐Pedersen Frank , Khan Tuhin Suvra , Bligaard T. , Noerskov J. K. 
Published: June 2014

AbstractReview: emphasis on catalyst requirements; 38 refs.
ChemInform Abstract: Catalytic Enantioselective 1,3‐Dipolar Cycloadditions of Azomethine Ylides for Biology‐Oriented Synthesis
Authors: Narayan Rishikesh , Potowski Marco , Jia Zhi‐Jun , Antonchick Andrey P. , Waldmann Herbert 
Published: June 2014

AbstractReview: 37 refs.