bluuebunny/crossref_metadata_2025_split huggingface dataset:
ChemInform Abstract: Protic Anions [H(B12X12)]‐ (X: F, Cl, Br, I) that Act as Broensted Acids in the Gas Phase.
Authors: Jenne Carsten , Kessler Mathias , Warneke Jonas 
Published: June 2015

AbstractThe protic anions [H(B12X12)]‐ (X: F, Cl, Br, I) are investigated with respect to their ability to protonate neutral molecules in the gas phase by using a combination of tandem mass spectrometry and quantum‐chemical calculations.
ChemInform Abstract: Homocatenation of Aluminum: Alkane‐Like Structures of Li2Al2H6 and Li3Al3H8.
Authors: Gish J. Tyler , Popov Ivan A. , Boldyrev Alexander I. 
Published: June 2015

AbstractBased on the Coalescence Kick search program coupled with DFT calculations on the potential energy surfaces of Li2Al2H6 and Li3Al3H6 a new class of homocatenated LinAlnH2n+2 compounds is proposed in which Al abstracts an electron from Li and thus becomes valence isoelectronic with C, Si, and Ge.
ChemInform Abstract: Intricate Short‐Range Ordering and Strongly Anisotropic Transport Properties of Li1‐xSn2+xAs2.
Authors: Kovnir Kirill , et al.  
Published: June 2015

AbstractLi1‐xSn2+xAs2 (0.2 < x < 0.4) phases are prepared by stoichiometric solid state reaction of the elements (evacuated silica tubes, 973 K, 2 h; cooling to 423 K over 30 h).
ChemInform Abstract: Na4IrO4: Square‐Planar Coordination of a Transition Metal in d5 Configuration Due to Weak On‐Site Coulomb Interactions.
Authors: Kanungo Sudipta , Yan Binghai , Merz Patrick , Felser Claudia , Jansen Martin 
Published: June 2015

AbstractThe title compound is prepared via the azide/nitrate route employing a 10:2:3 mixture of NaN3, NaNO3, and IrO2 under Ar (pressed pellets, steel vessel with Ag inlay, 600 °C, 50 h).
ChemInform Abstract: X‐Ray Diffraction, Moessbauer Spectroscopy, Magnetic Susceptibility, and Specific Heat Investigations of Na4NpO5 and Na5NpO6.
Authors: Smith Anna L. , Hen Amir , Raison Philippe E. , Colineau Eric , Griveau Jean‐Christophe , Magnani Nicola , Sanchez Jean‐Pierre , Konings Rudy J. M. , Caciuffo Roberto , Cheetham Anthony K. 
Published: June 2015

AbstractThe structures of the title compounds are determined by Rietveld refinement of powder XRD data.
ChemInform Abstract: Interrupted Chalcogenide‐Based Zeolite‐Analogue Semiconductor: Atomically Precise Doping for Tunable Electro‐/Photoelectrochemical Properties.
Authors: Lin Jian , Dong Youzhen , Zhang Qian , Hu Dandan , Li Na , Wang Le , Liu Yang , Wu Tao 
Published: June 2015

AbstractThe zeolite‐analog semiconductors (Hpip)24 [In28Se54(H2O)4] ·4H2O (I) and (Hpip)24 [In26Bi2Se54(H2O)2] ·4H2O (II) (pip: piperidine) are prepared by solvothermal reaction of a 4.5:1:0.3 molar mixture of Se, In, and Bi (in the case of Bi doping) in a mixed solvent of pip and H2O (170 °C, 7 d).
ChemInform Abstract: Magnetic Orderings in Li2Cu(WO4)2 with Tungstate‐Bridged Quasi‐1D Spin‐1/2Chains.
Authors: Muthuselvam I. Panneer , Sankar Raman , Singh Viveka Nand , Rao G. Narsinga , Lee Wei‐Li , Guo Guang‐Yu , Chou Fang‐Cheng 
Published: June 2015

AbstractThe magnetic and electronic properties of the title compound are characterized by synchrotron powder XRD, magnetic measurements, and DFT calculations.
ChemInform Abstract: One‐Step Synthesis of a [20]Silafullerane with an Endohedral Chloride Ion.
Authors: Tillmann Jan , Wender Josef Heinrich , Bahr Ute , Bolte Michael , Lerner Hans‐Wolfram , Holthausen Max C. , Wagner Matthias 
Published: June 2015

AbstractDiscrete Si20 dodecahedra stabilized by an endohedral guest and valence saturation are prepared by a Cl‐‐induced disproportionation of Si2Cl6 in the presence of Bu3N.
ChemInform Abstract: MH4P6N12 (M: Mg, Ca): New Imidonitridophosphates with an Unprecedented Layered Network Structure Type.
Authors: Marchuk Alexey , Celinski Vinicius R. , Schmedt auf der Guenne Joern , Schnick Wolfgang 
Published: June 2015

AbstractIsotypic MH4P6N12 (M: Mg, Ca) compounds are prepared by high‐pressure/high‐temperature reactions of stoichiometric amounts of M3N2, HPN2, and P3N5 (multi‐anvil press, 8 GPa, 1000 °C, 2 h).
ChemInform Abstract: Synthesis and Proton Conductivity of a New Two‐Dimensional Layered Aluminophosphate [C9H14N]8 [H2O]4· [Al8P12O48H4].
Authors: Zhu Jingran , Yan Yan , Liu Jiancong , Song Xiaowei 
Published: June 2015

Abstract[Bn‐NHMe2]8(H2O)4 [Al8P12O48H4] is prepared by reaction of Al(O‐iPr)3, H3PO4, and Bn‐NMe2 in the presence of FeCl3 or CoCl2 in tetraethylene glycol and H2O under solvothermal conditions (autoclave, 130 °C, 5 d).
ChemInform Abstract: Facile Formation of Thermodynamically Unstable Novel Borohydride Materials by a Wet Chemistry Route.
Authors: Jaron Tomasz , Wegner Wojciech , Fijalkowski Karol J. , Leszczynski Piotr J. , Grochala Wojciech 
Published: June 2015

AbstractM[Y(BH4)4] (M: Li, Na, K, Rb, Cs) compounds are prepared by ball milling (20‐30 min) of a 1:1:3 molar mixture of anhydrous YCl3, (Bu4N)BH4, and LiBH4 (5 mol% excess) followed by extraction of (Bu4N)[Y(BH4)4] with CH2Cl2 (DCM) and CHCl3 and subsequent solvent evaporation.
ChemInform Abstract: Synthesis, Crystal Structure, and Luminescence Properties of a New Microporous Europium Silicate: Na3EuSi6O15·1.47H2O.
Authors: Liu Wei , Ji Ying , Liu Fuyang , Yang Min , Wang Ying , Zhao Xudong , Liu Xiaoyang 
Published: June 2015

AbstractNa3EuSi6O15·1.47H2O is prepared under high‐temperature and high‐pressure conditions using a Na:Eu:Si = 10:1:6 molar mixture of NaOH, Eu2O3, and SiO2 (autoclave, 750 MPa, 400 °C, 48 h).
ChemInform Abstract: Ba2GeS4 and Mg2SnS4: Synthesis, Structures, Optical Properties and Electronic Structures.
Authors: Wu Kui , Pan Shilie , Yang Zhihua 
Published: June 2015

AbstractBa2GeS4 (I) and Mg2SnS4 (II) are prepared by solid state reaction of stoichiometric amounts of BaS and GeS2 (1050 °C, 72 h) and MgS and SnS2 (850 °C, 72 h), respectively.
ChemInform Abstract: FeII Spin‐Crossover Phenomenon in the Pentadecanuclear {Fe9[Re(CN)8]6} Spherical Cluster.
Authors: Chorazy Szymon , Podgajny Robert , Nakabayashi Koji , Stanek Jan , Rams Michal , Sieklucka Barbara , Ohkoshi Shin‐ichi 
Published: June 2015

AbstractSingle crystals of title compound (IV) are grown by self‐assembly in a MeOH solution.
ChemInform Abstract: Base‐Promoted Silver‐Catalyzed Protodeboronation of Arylboronic Acids and Esters.
Authors: Liu Chun , Li Xinmin , Wu Yonghua 
Published: June 2015

AbstractThe method is highly efficient for the protodeboronation of a wide range of arylboronic acids and also for the efficient deprotection of bifunctional amine (IV) under mild reaction conditions.
ChemInform Abstract: Decomposition of Benzoylthioureas into Benzamides and Thiobenzamides under Solvent‐Free Conditions Using Iodine—Alumina as the Catalyst and Its Mechanistic Study by Density Functional Theory.
Authors: Nahakpam Lokendrajit , Chipem Francis A. S. , Chingakham Brajakishor S. , Laitonjam Warjeet S. 
Published: June 2015

AbstractFor benzoylthiourea substrates (I), bearing an electron‐donating group at the para‐position of the aryl group, the formation of benzamide (II) is favored.
ChemInform Abstract: Ruthenium(II)‐Catalyzed C—H Activation/Alkyne Annulation by Weak Coordination with O2 as the Sole Oxidant.
Authors: Warratz Svenja , Kornhaass Christoph , Cajaraville Ana , Niepoetter Benedikt , Stalke Dietmar , Ackermann Lutz 
Published: June 2015

AbstractThis is the first example of a ruthenium‐catalyzed alkyne annulation via C—H functionalization using oxygen as the oxidant giving isocoumarins and other pyran‐fused ring systems.
ChemInform Abstract: UV Light‐Mediated Difunctionalization of Alkenes Through Aroyl Radical Addition/1,4‐/1,2‐Aryl Shift Cascade Reactions.
Authors: Zheng Lewei , Huang Hongli , Yang Chao , Xia Wujiong 
Published: June 2015

AbstractThe aroyl radical in situ generated from a photocleavage reaction, is added to acrylamide compounds followed by cyclization to give oxindoles.
ChemInform Abstract: (Diacetoxyiodo)benzene‐Mediated Oxygenation of Benzylic C(sp3)‐H Bonds with N‐Hydroxyamides at Room Temperature.
Authors: Qian Peng‐Cheng , Liu Yu , Song Ren‐Jie , Hu Ming , Yang Xu‐Heng , Xiang Jian‐Nan , Li Jin‐Heng 
Published: June 2015

AbstractA new and general, catalyst‐free strategy for the formation of C(sp3)—O bonds is established by iodosobenzene diacetate‐mediated oxygenation of benzylic C(sp3)—H bonds with N‐hydroxyamides.
ChemInform Abstract: Ligand‐Free, Palladium‐Catalyzed Dihydrogen Generation from TMDS: Dehalogenation of Aryl Halides on Water.
Authors: Bhattacharjya Anish , Klumphu Piyatida , Lipshutz Bruce H. 
Published: June 2015

AbstractWhile nitro groups are reduced to amino groups during dehalogenations, ester, keto, aldehyde, amide and cyano groups remain unaffected.
ChemInform Abstract: Copper‐Catalyzed N‐Cyanation of Sulfoximines by AIBN.
Authors: Teng Fan , Yu Jin‐Tao , Zhou Zhou , Chu Haoke , Cheng Jiang 
Published: June 2015

AbstractA simple and environmentally benign protocol for the direct cyanation of sulfoximines to N‐cyanosulfoximines is presented.
ChemInform Abstract: AsCat and FurCat: New Pd Catalysts for Selective Room‐Temperature Stille Cross‐Couplings of Benzyl Chlorides with Organostannanes.
Authors: Ronson Thomas O. , Carney Jonathan R. , Whitwood Adrian C. , Taylor Richard J. K. , Fairlamb Ian J. S. 
Published: June 2015

AbstractSuccinimide‐based palladium complex catalysts with either triphenylarsenic or trifuranylphospine ligands are used for the coupling of organostannanes with benzyl halogenides at ambient temperature.
ChemInform Abstract: Pd(II)‐Catalyzed, Controllable C—H Mono‐/Diarylation of Aryl Tetrazoles: Concise Synthesis of Losartan.
Authors: Ding Yan‐Jun , Li Yan , Dai Sheng‐Yu , Lan Quan , Wang Xi‐Sheng 
Published: June 2015

AbstractThis is the first example of a tetrazole‐directed C—H arylation.
ChemInform Abstract: A Medium Fluorous Grubbs—Hoveyda 2nd Generation Catalyst for Phase Transfer Catalysis of Ring Closing Metathesis Reactions.
Authors: Kobayashi Yuki , Inukai Sae , Kondo Natsuki , Watanabe Tomoko , Sugiyama Yuya , Hamamoto Hiromi , Shioiri Takayuki , Matsugi Masato 
Published: June 2015

AbstractA fluorous Grubbs—Hoveyda metathesis catalyst supported on Teflon powder is prepared.
ChemInform Abstract: Nano CuFe2O4: An Efficient, Magnetically Separable Catalyst for Transesterification of β‐Ketoesters.
Authors: Gohain Mukut , Kumar Vinod , van Tonder Johannes H. , Swart Hendrik C. , Ntwaeaborwa Odireleng M. , Bezuidenhoudt Barend C. B. 
Published: June 2015

AbstractDomino reaction of 5‐alkoxy‐ or 5‐aminoisoxazoles (I) with 1,3‐dicarbonyl compounds under metal relay catalysis provides access to 2,4‐dicarbonylpyrrole derivatives in good to high yields.
ChemInform Abstract: One‐Step Synthesis of Dicarboxamides Through Pd‐Catalyzed Aminocarbonylation with Diamines as N‐Nucleophiles.
Authors: Carrilho Rui M. B. , Almeida Ana R. , Kiss Mercedesz , Kollar Laszlo , Skoda‐Foeldes Rita , Dabrowski Janusz M. , Moreno Maria Jose S. M. , Pereira Mariette M. 
Published: June 2015

AbstractA versatile and atom‐economical route to alkenyl and aryl dicarboxamides by catalytic aminocarbonylation is described.
ChemInform Abstract: Aqueous MW Eco‐Friendly Protocol for Amino Group Protection
Authors: Nardi M. , Cano N. Herrera , Costanzo P. , Oliverio M. , Sindona G. , Procopio A. 
Published: June 2015

Abstractwith Boc2O, Fmoc‐Cl, Ac‐Cl and Tos‐Cl
ChemInform Abstract: Water Mediated Reactions: TiO2 and ZnO Nanoparticle Catalyzed Multi Component Domino Reaction in the Synthesis of Tetrahydroacridinediones, Acridindiones, Xanthenones and Xanthenes.
Authors: Pugazhenthi Ilangovan , Ghouse Shaik Mohammed , Nawaz Khan Fazlur‐Rahman , Jeong Euh Duck , Bae Jong Seong , Kim Jong‐Pil , Chung Eun Hyuk , Kumar Yadavalli Suneel , Dasaradhan Changalraya 
Published: June 2015

AbstractThe new methodology offers a domino reaction strategy, high yield, simple operation, recyclability, and is eco‐friendly.
ChemInform Abstract: Synthesis of Enantiomerically Pure 2‐Heteroaromatic‐Substituted 1,2‐Amino Alcohols from Chiral tert‐Butanesulfinyl Aldimines.
Authors: Chen Yantao , Goldberg Frederick W. , Xiong Jian , Wang Shujun 
Published: June 2015

AbstractNine R/S pairs of heteroaromatic‐substituted amino alcohols are prepared by nucleophilic addition of heteroaromatic carbanions to chiral N‐(tert‐butylsulfinyl)imines.
ChemInform Abstract: α‐Hydroxyallylsilanes as Propionaldehyde Enolate Equivalents and Their Use Toward Iterative Aldol Reactions.
Authors: Ruiz Johal , Murthy Akondi Srirama , Roisnel Thierry , Chandrasekhar Srivari , Gree Rene 
Published: June 2015

AbstractSmooth and efficient reaction conditions for the transformation of protected β‐hydroxyacylsilanes into the corresponding aldehydes are developed.
ChemInform Abstract: Engineered‐Serine Hydroxymethyltransferase from Streptococcus thermophilus for the Synthesis of α,α‐Dialkyl‐α‐Amino Acids.
Authors: Hernandez Karel , Zelen Igor , Petrillo Giovanna , Uson Isabel , Wandtke Claudia M. , Bujons Jordi , Joglar Jesus , Parella Teodor , Clapes Pere 
Published: June 2015

AbstractA highly diastereoselective aldol addition of aldehydes to serine and alanine is established.
ChemInform Abstract: Copper‐Catalyzed Cyanomethylation of Allylic Alcohols with Concomitant 1,2‐Aryl Migration: Efficient Synthesis of Functionalized Ketones Containing an α‐Quaternary Center.
Authors: Bunescu Ala , Wang Qian , Zhu Jieping 
Published: June 2015

AbstractThe novel copper‐catalyzed coupling reaction of allylic alcohols with alkyl nitriles leads to ketones with the concomitant creation of an α‐quaternary center.
ChemInform Abstract: Copper‐Catalyzed Three‐Component Reactions of Phenols, Acyl Chlorides and Wittig Reagents for the Synthesis of β‐Aryloxyl Acrylates.
Authors: Zhang Yi , Liu Yunyun , Wan Jie‐Ping 
Published: June 2015

AbstractThe title compounds are obtained with high diversity involving the cascade formation of a new C=C bond and a C(sp2)—O bond using glucose as a green ligand.
ChemInform Abstract: Aqueous Sonogashira Coupling of Aryl Halides with 1‐Alkynes under Mild Conditions: Use of Surfactants in Cross‐Coupling Reactions.
Authors: Roberts Gina M. , Lu Wenya , Woo L. Keith 
Published: June 2015

AbstractAddition of inexpensive, commercially available and recyclable surfactants such as SDS and CTAB in the aqueous‐phase Sonagashira coupling of various aryl iodides and bromide with alkynes results in a substantial improvement of product yields.
ChemInform Abstract: Dialkylzinc‐Mediated Cross‐Coupling Reactions of Perfluoroalkyl and Perfluoroaryl Halides with Aryl Halides.
Authors: Kato Hisano , Hirano Keiichi , Kurauchi Daisuke , Toriumi Naoyuki , Uchiyama Masanobu 
Published: June 2015

AbstractA chemoselective perfluoroalkylation becomes possible by halogen—zinc exchange followed by coupling with a broad spectrum of aryl iodides and some bromides.
ChemInform Abstract: Copper‐Catalyzed Intermolecular and Regioselective Aminofluorination of Styrenes: Facile Access to β‐Fluoro‐N‐protected Phenethylamines.
Authors: Saavedra‐Olavarria Jorge , Arteaga Gean C. , Lopez Jhon J. , Perez Edwin G. 
Published: June 2015

AbstractA new copper‐catalyzed regioselective aminofluorination of styrenes under mild conditions is presented.
ChemInform Abstract: One‐Pot Synthesis of 3,5‐Disubstituted and Polysubstituted Phenols from Acyclic Precursors.
Authors: Qian Jinlong , Yi Wenbin , Huang Xin , Miao Yongbo , Zhang Junkai , Cai Chun , Zhang Wei 
Published: June 2015

AbstractA new strategy for the synthesis of differently substituted phenols is established through one‐pot Robinson annulation of α‐fluoro‐β‐ketoesters with α,β‐unsaturated ketones followed by in situ dehydrofluorination and tautomerization.
ChemInform Abstract: Copper‐Catalyzed Synthesis of Imides from Aldehydes or Alcohols and Amine Hydrochloride Salts.
Authors: Yu Hui , Zhang Yonghao 
Published: June 2015

AbstractAn efficient and practical method for the synthesis of imides by simple reaction of aldehydes or benzylic alcohols with amine hydrochloride salts is given.
ChemInform Abstract: Transition‐Metal‐Free Persulfuration to Construct Unsymmetrical Disulfides and Mechanistic Study of the Sulfur Redox Process.
Authors: Xiao Xiao , Feng Minghao , Jiang Xuefeng 
Published: June 2015

AbstractThe comproportionation between the low‐valence sulfur atom in a thiosulfate and a high‐valence S in a sulfinate efficiently affords asymmetric disulfides without additional oxidant.
ChemInform Abstract: Acid‐Promoted Direct Electrophilic Trifluoromethylthiolation of Phenols.
Authors: Jereb Marjan , Gosak Kaja 
Published: June 2015

AbstractBF3·OEt2 or TfOH are used as promoters in the electrophilic aromatic ring trifluoromethylthiolation of various substituted phenols.
ChemInform Abstract: Synthesis and Characterization of Hexaarylbenzenes with Five or Six Different Substituents Enabled by Programmed Synthesis.
Authors: Suzuki Shin , Segawa Yasutomo , Itami Kenichiro , Yamaguchi Junichiro 
Published: June 2015

AbstractA C—H activation followed by cross‐coupling and [4+2] cycloaddition allows the approach to the desired polyaryl systems.
ChemInform Abstract: Efficient Phosphine Ligands for the One‐Pot Palladium‐Catalyzed Borylation/Suzuki—Miyaura Cross‐Coupling Reaction.
Authors: Chen You , Peng Hui , Pi Yun‐Xiao , Meng Tong , Lian Ze‐Yu , Yan Meng‐Qi , Liu Yan , Liu Sheng‐Hua , Yu Guang‐Ao 
Published: June 2015

AbstractA novel phosphine ligand is synthesized and successfully applied in the synthesis of symmetrical and unsymmetrical biaryl compounds.
ChemInform Abstract: Copper‐Catalyzed Cross‐Coupling of Arylzirconium Reagents with Aryl and Heteroaryl Iodides.
Authors: Thapa Surendra , Basnet Prakash , Gurung Santosh K. , Giri Ramesh 
Published: June 2015

AbstractAn unprecedented Cu(I)‐catalyzed cross‐coupling of in situ generated arylzirconium reagents (II) with aryl and hetaryl iodides is reported.
ChemInform Abstract: A Novel Green Protocol for Ligand Free Suzuki—Miyaura Cross‐Coupling Reactions in WEB at Room Temperature.
Authors: Boruah Preeti Rekha , Ali Abdul Aziz , Saikia Bishwajit , Sarma Diganta 
Published: June 2015

AbstractWater extract of banana peel ash (WEB) is employed in ligand‐free Suzuki—Miyaura cross‐coupling reactions.
ChemInform Abstract: Rh(I)‐Catalyzed Cross‐Coupling of α‐Diazoesters with Arylsiloxanes.
Authors: Xia Ying , Liu Zhen , Feng Sheng , Ye Fei , Zhang Yan , Wang Jianbo 
Published: June 2015

AbstractThe first rhodium catalyzed Hiyama—type cross—coupling reaction between arylsiloxanes and diazoesters is developed and gives access to a wide range of α‐aryl esters (64 examples).
ChemInform Abstract: Enhancing Catalytic Activity Towards Heck‐Reaction by Using 4,5,9,10‐Tetra(arylimino)pyrenylidenyldipalladium Tetrachlorides.
Authors: Zhao Tong , Xing Qifeng , Song Kuifeng , Ban Qing , Liang Tongling , Liu Qingbin , Sun Wen‐Hua 
Published: June 2015

AbstractFour new binuclear 4,5,9,10‐tetra(arylimino)pyrenylidenyldipalladium tetrachlorides are synthesized and all promote the Heck cross‐coupling reaction with high activities.
ChemInform Abstract: Dual Gold‐Catalyzed Head‐to‐Tail Coupling of Iodoalkynes.
Authors: Mader Steffen , Molinari Lise , Rudolph Matthias , Rominger Frank , Hashmi A. Stephen K. 
Published: June 2015

AbstractOne alkyl‐substituted and some aryl‐containing gem‐diiodinated conjugated enynes are formed with moderate to good yield in the presence of dual‐activation catalyst shown in the scheme as the most optimal one (mechanism).
ChemInform Abstract: Lewis and Broensted Acid Induced (3 + 2)‐Annulation of Donor—Acceptor Cyclopropanes to Alkynes: Indene Assembly.
Authors: Rakhmankulov Eduard R. , Ivanov Konstantin L. , Budynina Ekaterina M. , Ivanova Olga A. , Chagarovskiy Alexey O. , Skvortsov Dmitriy A. , Latyshev Gennadij V. , Trushkov Igor V. , Melnikov Mikhail Ya. 
Published: June 2015

Abstract(3 + 2)‐Annulation of donor—acceptor cyclopropanes to alkynes induced by both Lewis and Broensted acids is developed.
ChemInform Abstract: Efficient Green Approach for the Synthesis of Spiro[indoline‐3,4′‐pyrazolo[3,4‐b]quinoline]diones Using [NMP]H2PO4 and Solvatochromic and pH Studies.
Authors: Kumari Sudesh , Sindhu Jayant , Khurana J. M. 
Published: June 2015

Abstract11 Title compounds of type (IV) are prepared by a three‐component one‐pot reaction using NMP·H3PO4 as a catalyst.
ChemInform Abstract: Formal [4 + 1] Cycloaddition of o‐Quinone Methides: Facile Synthesis of Dihydrobenzofurans.
Authors: Lei Xiantao , Jiang Chun‐Huan , Wen Xiaoan , Xu Qing‐Long , Sun Hongbin 
Published: June 2015

Abstract2‐Substituted dihydrobenzofurans are efficiently obtained by reaction of various sulfur ylides with o‐quinone methides, which are generated under mild reaction conditions
ChemInform Abstract: Palladium‐Catalyzed Phosphine‐Free Direct C—H Arylation of Benzothiophenes and Benzofurans Involving MIDA Boronates.
Authors: Wang Zhiwei , Li Yabo , Yan Beiqi , Huang Mengmeng , Wu Yangjie 
Published: June 2015

AbstractFor the first time, MIDA boronates (II) are used in C—H arylation reactions of heterocycles.
ChemInform Abstract: Palladium(0)‐Catalyzed Iminohalogenation of Alkenes: Synthesis of 2‐Halomethyl Dihydropyrroles and Mechanistic Insights into the Alkyl Halide Bond Formation.
Authors: Chen Chen , Hou Longlei , Cheng Mian , Su Jianhua , Tong Xiaofeng 
Published: June 2015

AbstractThe title reaction proceeds with the assistance of halide salts and provides facile access to synthetically useful 2‐halomethyl dihydropyrroles.
ChemInform Abstract: γ‐Aminoalcohol Rearrangement Applied to Pentahydroxylated Azepanes Provides Pyrrolidines Epimeric to HomoDMDP.
Authors: Jagadeesh Y. , Tran A. T. , Luo B. , Auberger N. , Desire J. , Nakagawa S. , Kato A. , Zhang Y. , Sollogoub M. , Bleriot Y. 
Published: June 2015

AbstractA short sequence is described for the conversion of azepanes (I) and (V) into pyrrolidines (IV) and (VIII), which are epimeric to α‐glucosidase inhibitor homoDMDP.
ChemInform Abstract: Synthesis of 3‐(1,2‐Dioxoethyl)‐ and 2,3‐Dicarbonyl‐Containing Pyrroles.
Authors: Galenko Alexey V. , Khlebnikov Alexander F. , Novikov Mikhail S. , Avdontceva Margarita S. 
Published: June 2015

AbstractThe copper‐catalyzed reaction of tricarbonyl compounds and azirines results in the formation of two substituted pyrroles.
ChemInform Abstract: DIAD as a Promoter for Cyanomethylation of Alkenes by Cu Catalysis.
Authors: Tang Shi , Li Shu‐Hua , Li Zhi‐Hao , Zhou Dong , Sheng Rui‐Long 
Published: June 2015

AbstractA novel DIAD‐promoted oxidative radical cyanomethylation of activated alkenes by inexpensive CuI is developed.
ChemInform Abstract: Simple Aza‐Conjugate Addition Methodology for the Synthesis of Isoindole Nitrones and 3,4‐Dihydroisoquinoline Nitrones.
Authors: Peacock Lucy R. , Chapman Robert S. L. , Sedgwick Adam C. , Mahon Mary F. , Amans Dominique , Bull Steven D. 
Published: June 2015

AbstractThe title compounds are obtained by reaction of aryl‐aldehydes containing ortho‐substituted α,β‐unsaturated carboxylic acid derivatives with hydroxylamine leading to reactive N‐hydroxy‐carbinolamine intermediates which undergo intramolecular aza‐conjugate addition reactions.
ChemInform Abstract: Three‐Component, Four‐Molecule, Ru‐Catalyzed Cascade Reactions of Indoles and Alkyl Bromides with Sodium Nitrite.
Authors: Qu Hongen , Li Jiuling , Li Huiliang , Wang Hengshan , Liu Liangxian 
Published: June 2015

Abstract(E)‐2,3′‐bi(3H‐indol)‐3‐one O‐alkyl oximes (III), (V) are regio‐ and stereoselectively obtained.
ChemInform Abstract: Diastereoselective Synthesis of Functionalized Carbazoles via a Sequential Diels—Alder/Ene Reaction Strategy.
Authors: Cowell Joseph , Abualnaja Matokah , Morton Stephanie , Linder Ruth , Buckingham Faye , Waddell Paul G. , Probert Michael R. , Hall Michael J. 
Published: June 2015

AbstractAn operationally simple one‐pot, three‐component, diastereoselective synthesis of saturated carbazoles and related pyridazino[3,4‐b]indoles, based on two sequential intermolecular pericyclic reactions, is described.